ATTACHMENT F

CHANGE COPY

Change Copy F - 1

08/31/11

RULE 67.16. GRAPHIC ARTS OPERATIONS (Effective 10/18/88:;

Rev. Adopted & Effective 5/15/96; Amended (date of adoption) & Effective 

(6 months after date of adoption) 

(a) APPLICABILITY

(1) This rule is applicable to all continuous web or single sheet fed graphic arts 

printing, processing, laminating or drying operations and digital printing operations.

(2) This rule is not applicable to printing operations on ceramic or circuit boards. 

These operations are subject to Rule 66.1.

(23) Graphic arts Ooperations subject to or exempt from this rule shall not be subject 

to Rule 66.1 or Rule 67.5.

(b) EXEMPTIONS

(1) The provisions of Sections (d) and (e) of this rule shall not apply to stationary 

sources which emit less than an average of 15 lbs (6.8 kg) of volatile organic compounds 

(VOCs) from all graphic arts operations per day of operation, excluding digital printing 

operations, for each calendar month. It is the responsibility of any person claiming an this 

exemption pursuant to Subsection (b)(1) to maintain daily or monthly records as specified 

in Section (f) of this rule necessary to establish average daily emissions and to make this 

information available to the District upon request. The average daily emission levels shall 

be determined by recording and taking into account the number of operational days per 

given month.

(2) The provisions of Sections (d) and (e) shall not apply to large digital printing 

operations provided that any facility claiming this exemption maintains applicable records 

as specified in Subsection (f)(4).
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(23) The provisions of Sections (d), (e), and (f) of this rule shall not apply to:

(i) All proofing systems.

(ii) Manufacture of:

(A) Solar control window film,

(B) Heat applied transfer decals,

(C) Ceramic decals manufactured for firing above 800°F, or

(D) Water slide decals.

(iii) Printing on ceramic or circuit boards. 

(viii) Embossing and foil stamping which do not use materials containing 

VOCs.

(v) Coating operations subject to Rule 67.5, Paper, Film and Fabric Coating 

Operations.

(viiv)Development process associated with the preparation of lithographic 

printing plates.

(iv) Blanket repair material applied from non-refillable aerosol containers of 

four ounces or less.

 (vi) Digital printing operations that are not large operations as defined in 

Subsection (c)(12).

(vii) Stripping of cured inks, coatings and adhesives. 

(viii) Research and development operations.

(ix) Preservative oils application using hand-held non-refillable aerosol 

containers.

(x) Cleaning of ultraviolet lamps and reflectors and electron beam processors.
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(c) DEFINITIONS (Rev. Effective 5/15/96)

For the purpose of this rule the following definitions shall apply:

(1) “Adhesive” means a substance that is used to bond one surface to another by 

attachment. 

(12) “Cleaning Material” means a VOC containing material used for cleaning 

hands, tools, printing presses, ink or coating application equipment and work area.

(123)"Coating" in the graphic arts operation means a layer of material applied to a 

substrate in a relatively unbroken film.

 (34)“Digital Printing Operation” means an operation that uses a printing device 

guided by a computer-driven machine to transfer an electronic image to a substrate through 

the use of inks, toners, or other graphic arts materials. Digital printing operation also 

includes associated surface preparation, solvent cleaning, and the cleaning of application 

equipment.

(5) “Precision Electro-optical Component” is an optical element used in an 

electro-optical device and is designed to sense, detect, or transmit light energy, including 

specific wavelengths of light energy and changes in light energy levels.

(246)"Exempt Compound" means the same as defined in Rule 2.

(Rev. Effective 5/15/96)

 (357) "Exterior Marking" means any outdoor sign printed, coated or laminated by 

any of the graphic arts methods.

(468)"Flexographic Printing" means a letterpress method utilizing flexible rubber 

or other elastomeric plate.

(579)"Fountain Solution" means the solution which is applied to the image plate to 

maintain the hydrophilic properties of the non-image areas.
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(6810) "Graphic Arts Operations" means all screen, gravure, letterpress, 

flexographic, and lithographic and digital printing processes operations, or related coating, 

or laminating processes including coating of flexible packaging materials for food or health 

care products and laboratory or experimental processes.

(79) "Graphic Arts Line" means printing application equipment, coating 

equipment, laminating equipment, flash-off areas, ovens, conveyors or other equipment 

operating in an uninterrupted series to produce graphic arts using graphic art materials.

(81011) "Graphic Arts Material" means any ink, coating, adhesive, fountain solutions,

or thinners, or retarders used in printing or related coating or laminating processes.

(91112) "Gravure Printing" means an intaglio process in which the ink is carried in 

minute etched or engraved wells on a roll or cylinder, with excess ink being removed from 

the surface by doctor blade.

(1213) “Large Commercial Digital Printing Operation” means commercial a 

commercial digital printing operation where a print capacity of any individual printer that 

uses solvent based inks is 1,000 ft2/hr or higher; or an operation where a print capacity of any 

individual printer that uses water based or UV inks is 10,000 ft2/hr or higher. with an 

equipment print capacity of 1,000 ft2/hr or higher which uses solvent based inks, or an 

operation with an equipment print capacity of 10,000 ft2/hr or higher which uses water based 

or UV inks.

(101314) "Lamination" means a process of composing two or more layers of material to 

form a single multiple layer sheet by using adhesive.

(111415)"Letterpress Printing" means a method where the image area is raised relative 

to the non-image area and the ink is transferred to the paper directly from the image surface.

(121516)"Lithographic Printing" means a plane-o-graphic method in which the image 

and non-image areas are on the same plane, and the ink is offset from a plate to a rubber 

blanket, and then from the blanket to the substrate.

(17) “ Preservative Oil” means any liquid material which does not contain any 

solids, and is applied to rollers or ink wells to prevent them from drying when the graphic 

arts equipment is stopped for an extended time or to provide lubrication, or both.
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(131618)"Printing" means any operation that imparts color, design, alphabet or 

numerals on a substrate.

(141719)"Printing Ink" means any fluid or viscous composition used in printing, 

impressing or transferring an image onto a substrate.

(151820)"Proofing System" means a system used only to check the quality or print 

color reproduction and editorial content and includes proof presses and/or off-press proofing 

lines.

(161921)"Publication Gravure" means a gravure printing on paper substrate which is 

subsequently used to form books, magazines, catalogues, brochures, directories, and 

newspaper supplements or other printed material.

(172022)"Screen Printing" means a process where the printing ink passes through a 

web or a fabric to which a refined form of stencil has been applied. The stencil openings 

determine the form and dimensions of imprint.

(182123)"Stationary Source" means the same as is defined in Rule 20.1.

(2224) “Thinner” means a solvent used to reduce viscosity of printing inks.

(192325)"Volatile Organic Compound (VOC)" means the same as defined in Rule 2.

for the purpose of this rule means any volatile compound containing at least one atom of 

carbon, excluding methane, carbon monoxide, carbon dioxide, carbonic acid, ammonium 

carbonate, metallic carbides and carbonates, and exempt compounds which may be emitted 

to the atmosphere during the application of and/or subsequent drying or curing of graphic arts 

materials or cleaning materials subject to this rule.

(2426) “VOC Content per Volume of Graphic Arts Materials, Less Water and 

Exempt Compounds” (excluding thinners) means the same as defined in Rule 2, “VOC 

Content per Volume of Coatings, Less Water and Exempt Compounds.”

(2527) “VOC Content per Volume of Thinner or Cleaning Material” means the 

same as defined in Rule 2, “VOC Content per Volume of Material.”
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(202628)"Web-fed" means an automatic system which supplies substrate from a 

continuous roll or from an extrusion process.

(d) STANDARDS

(1) Graphic Arts Materials and Fountain Solutions.

A person shall not conduct operate any printing or graphic arts operation process

unless the following materials are used:.

(i) Only gGraphic arts materials, except adhesives, containing less than 300 

grams of VOC per liter (2.5 lbs/gal) as applied, less water and exempt compounds.

are used; and

(ii) Adhesives containing not more than 150 grams of VOC per liter (1.25 

lb/gal), as applied, less water and less exempt compounds.

(iii) Only f Fountain solutions containing not more than 5% VOC 15% by 

volume, as applied, and no alcohols are used.; or

(iv) Fountain solutions containing not more than 8.5% VOC by volume

refrigerated to a temperature below 60oF.

(2) Cleanup of Equipment

A person shall not use materials containing VOCs for the cleanup of equipment used 

in graphic arts operations unless:

(i) The cleaning material solvent has a VOC content of less than 100 200

grams per liter of material; or

(ii) The total VOC vapor pressure of the cleaning material is 45 5 mm of Hg 

at 20°C or less.; or
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(iii) A system is used that totally encloses the component parts being cleaned 

during the washing, rinsing, and draining processes. ;or

(iv) The cleaning solvent is transferred through the application equipment, 

without exposure to air, into a container which has in place an apparatus or cover 

which completely covers the container and has no visible holes, breaks, openings or 

separations between adjoining components of the container or container cover. 

Containers may be equipped with vents provided such vents are necessary to comply 

with applicable fire and safety codes.

(e) CONTROL EQUIPMENT

(1) In lieu of complying with the provisions of Subsection (d)(1) or (d)(2), 

a person may use an air pollution control system which:

(i) Has been installed in accordance with an Authority to Construct; and

(ii) Includes an emission collection system which captures and transports 

organic gaseous emissions generated by an applicable graphic arts operation to an air 

pollution control device; and

(iii) Has a combined VOC emissions capture and control device efficiency of 

at least 85 percent by weight.

(2) A person subject to the requirements of this section shall submit to the Air 

Pollution Control Officer for approval an Operation and Maintenance (O&M) plan for the 

proposed emission control device and emission collection system. Such plan shall:

(i) Identify all key system operating parameters. Key system operating 

parameters are those necessary to ensure compliance with Subsection (e)(1)(iii), such 

as temperature, pressure, and/or flow rate.

(ii) Include proposed inspection schedules, anticipated ongoing maintenance, 

and proposed recordkeeping practices regarding the key system operating parameters.

(3) The Operation and Maintenance plan must be submitted to the Air Pollution 

Control Officer and receive written approval prior to operation of the air pollution control 

equipment. A person subject to the requirements of this section shall implement the plan 

on approval of the Air Pollution Control Officer.

(f) RECORDKEEPING
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Any person conducting applying a graphic arts operation subject to this rule materials shall 

maintain records in accordance with the following requirements:

(1) Maintain a current list of graphic arts materials, fountain solutions and cleaning 

materials used containing VOCs such as inks, adhesives, thinners, retarders, fountain 

solutions and cleaning materials in use which provides data necessary to evaluate 

compliance, including, but not limited to:

(i) Type of graphic arts materials, fountain solutions or cleaning materials

used;

(ii) Dilution ratio of mixed components, if applicable;

(iii) VOC content, less water and exempt compounds and/or vapor pressure of 

each graphic arts material (excluding thinner), as applied; volume percent of VOC in 

fountain solution; and VOC content of each thinner and cleaning material and/or total 

VOC vapor pressure, as used applied.

(2) Maintain daily or monthly records showing the amount of each graphic arts 

material, and each fountain solution and cleaning material used including, but not limited 

to, inks, adhesives, thinners, retarders, fountain solutions, and cleaning solutions.

(3) Any person using control equipment pursuant to Section (e) of this rule shall:

(i) For all graphic arts materials, fountain solutions and cleaning materials not 

in compliance with Subsection (d)(1) or (d)(2) of this rule, maintain daily records of 

the amount of each material used; and

(ii) Maintain daily records sufficient to document continuous compliance with 

Subsection (e)(1)(iii), including records of key system operating parameters as 

approved in the Operation and Maintenance plan.
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(4) Any person claiming an exemption pursuant to Subsection (b)(2) for large 

commercial digital printing operations shall:

(i) Maintain a current list of graphic arts materials and cleaning materials 

used;

(ii) Provide documentation containing the VOC content, less water and 

exempt compounds of each graphic arts material (excluding thinner), as applied and 

the VOC content of each thinner and cleaning material and/or total VOC vapor 

pressure, as used;

(iii) Keep monthly records of the type and amount of each graphic arts material 

and cleaning material used.

These All records shall be retained on site for at least three years and shall be made 

available to the District upon request.

(g) TEST METHODS

When more than one test method or set of test methods are specified in this Section, a 

violation of any requirement of this rule established by any one of the specified test methods or 

set of test methods shall constitute a violation of this rule.

(1) Measurements of VOC content of graphic arts materials subject to Section (d) 

of this rule shall be conducted and reported in accordance with the Environmental 

Protection Agency (EPA) Test Method 24 (40 CFR 60, Appendix A), dated 9/11/1995, or 

by the South Coast Air Quality Management District (SCAQMD) Method 304, dated 

2/1/1996, as applicable they it exists on (date of adoption)September 20, 1994, and ASTM 

Test Method D 4457-85 for determination of dichloromethane and 1,1,1-trichloroethane in 

paints and coatings by direct injection into a gas chromatograph.
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(2) Measurements of VOC content of rotogravure publication inks subject to 

Section (d) of this rule shall be conducted and reported in accordance with EPA Test 

Method 24A (40 CFR 60, Appendix A), dated 8/6/1993.as it exists on (date of 

adoption).September 20, 1994, and ASTM Test Method D 4457-85 for determination of 

dichloromethane and 1,1,1,-trichloroethane in paints and coatings by direct injection into a 

gas chromatograph.

(3) Measurements of VOC emissions subject to Section (e) of this rule shall be 

conducted in accordance with EPA Methods 18, and 25 or 25A (40 CFR 60, Appendix A) 

as they exist on (date of adoption) September 20, 1994. Test procedures shall be 

performed in accordance with a protocol approved by the Air Pollution Control Officer.

(3) The VOC content of cleaning materials shall be determined by the SCAQMD 

Method 313-91 (Determination of Volatile Organic Compounds by Gas 

Chromatography/Mass Spectrometry), dated 2/1/1993, or SCAQMD Method 308-91

(Quantification of Compounds by Gas Chromatography), dated 2/1/1993as they exist on 

(date of adoption).

(4) Measurements Calculations of total VOC vapor pressures of cleaning materials 

VOC containing compounds pursuant to Subsection (d)(2)(ii) of this rule shall be 

calculated using the District's "SD1-Procedure for Estimating the Vapor Pressure of a 

Solvent VOC Mixtures,", dated 6/20/1990.as it exists on (date of adoption) September 20, 

1994. If the vapor pressure of the liquid mixture is in excess of the limit specified in 

Subsection (d)(2)(ii), the vapor pressure shall be determined in accordance with ASTM 

Test Method D 2879-108397 (2007), "Vapor Pressure-Temperature Relationship and Initial 

Decomposition Temperature of Liquids by Isoteniscope", or its most current version.

(5) Measurements of VOC content pursuant to Subsection (d)(1)(ii) shall be 

conducted and reported in accordance with ASTM Standard Recommended Practices for 

General Gas Chromatography Procedures, E 260-85.

(5) The content of methyl acetate, acetone and parachlorobenzotrifluoride 

shall be determined in accordance with the ASTM Test Method D6133-02 (2008) 

(Standard Test Method for Acetone, p-Chlorobenzotrifluoride, Methyl Acetate or t-Butyl 
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Acetate Content of Solventborne and Waterborne Paints, Coatings, Resins, and Raw 

Materials by Direct Injection Into a Gas Chromatograph), or its most current version.

(6) Perfluorocarbon (PFC) compounds and other exempt compounds shall be 

assumed to be absent from a coating, cleaning, or surface preparation material subject to 

this rule unless a manufacturer of the material or a facility operator identifies the specific 

individual compound(s) and the amount(s) present in the material and provides an EPA and 

ARB approved test method which can be used to quantify the specific compounds.

(6) Measurements of exempt compounds content, other than except for those

determined in accordance with Subsection (g)(5), shall be conducted in accordance with 

the SCAQMD Test Method 303-91 (Determination of Exempt Compounds), dated

8/1/1996 as it exists on (date of adoption).

(7) The overall control efficiency of air pollution control equipment operated 

pursuant to Subsection (e)(1)(iii) shall be determined by multiplying the capture efficiency 

of the emission collection system by the control efficiency of the air pollution control 

device. The control efficiency of the air pollution control device shall be determined using 

EPA Test Methods 25A and/or 18 (40 CFR Part 60, Appendix A), both dated 9/25/1996,

and in accordance with a protocol approved by the Air Pollution Control Officer. Capture 

efficiency of an emission collection system pursuant to Subsection (e)(1)(iii) shall be 

determined according to EPA Test Methods 204 and 204A through 204 F (51 CFR 

Appendix M), dated 6/4/97, as applicable, and technical document, “Guidelines for 

Determining Capture Efficiency,” dated January 9, 1995. Subsequent to the initial 

compliance demonstration period, appropriate key system operating parameters as 

approved by the Air Pollution Control Officer may be used as indicators of the 

performance of the emission control system.

(8) Other test methods which are determined to be equivalent to the test methods 

specified in this rule and approved, in writing, by the Air Pollution Control Officer, 

California Air Resources Board, and EPA may be used in place of the test methods 

specified in this rule. 
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