**November 8, 2012 CA A**  **Section 114 - Poly**

**viny l Chloride and Copoly** **mers (PVC) Production Process Wastew ater**  **PVC General Company and Facility** 

**Information**

**Instructions**

Please complete this worksheet for your parent company and PVC production facility

.

**Parent Company General Information**

Parent Company

Name:

Address:

City:
Country: US

Size of Com pany

(approximate number of employees including all subsidiaries, branches, and related establishments owned):

**PVC Production Facility General Information**

Facility Name:

Facility Address:

Facility City:
Facility Technical Contact Name:

Technical Contact Telephone Number:

Technical Contact Email:

Number of employees attached to the PVC production facility: ~80 Houston 2801 Post Oak Boulevard Westlake Chemical Corporation

270-395-3302

jhobby@westlake.com Westlake PVC Corporation

230 Johnson Riley

Road

Calvert City

Jimmy Hobby**November 8, 2012 CA A**  **Section 114 - Poly**

**viny l Chloride and Copoly** **mers (PVC) Production Process Wastew ater** 

State: TX Zip Code: 77056

Size of Com pany

(approximate number of employees including all subsidiaries, branches, and related establishments owned): 2000

State: KY Zip Code: 42029**November 8, 2012 CA A**  **Section 114 - Poly**

**viny l Chloride and Copoly** **mers (PVC) Production Process Wastew ater**  **PVC Production Process Wastew ater Treatment Sy** **stem Information Update**

**Instructions**

2. Also complete the additional supplemental questions to Form C-1-c.

**FORM C-1-c PROCESS EQUIPMENT - WA** **STEWA TER STEA** **M STRIPPER**

Process Unit ID: P-1

Process Equipment ID: U-32 Wastewater Feed Rate (lb/hr): 60000 Feed Temperature (°F): 170 Feed Inlet Pressure (psia): 75 Liquid Loading Rate (liters/m2): 82 Steam Feed Rate (lb/hr): 3500 Steam to Feed Ratio (kg steam/liter of wastewater): 0.0583 Operating Temperature (°F): 220 Operating Pressure (psig): 2 Total Number of Stages: Overall Calculated Tray Efficiency: Stripping Factor: 0.999991 Flow configuration (countercurrent, cocurrent): countercurrent Number of Actual Trays: 20 Colum n Height (meters): 10.6

Year Equipm ent Installed: 1979 Equipm ent Currently

Regulated Under (cite regulations): 40 CFR 61 Sub F 1. A copy

of your facility's responses on Form C-1-c of the August 21, 2009 CAA section 114 request were included with the CAA Section 114 request letter dated November XX, 2012. Please review those previous responses and update if necessary below.**November 8, 2012 CA A**  **Section 114 - Poly**

**viny l Chloride and Copoly** **mers (PVC) Production Process Wastew ater** 

**Form C-1-c Supplemental Questions**

Please also provide the stripper feed rate in liters per hour, or liters for batch strippers:

If the above stripper feed rate or capacity does not equal the maximum design rate or capacity, please provide those values: 1. A copy

of your facility's responses on Form C-1-c of the August 21, 2009 CAA section 114 request were included with the CAA Section 114 request letter dated November XX, 2012. Please review those previous responses and update if necessaryPlease also provide the stripper feed rate in liters per hour, or liters for batch strippers: 27250 liters/hour liters

If the above stripper feed rate or capacity does not equal the maximum design rate or capacity, please provide those values:

34000 liters/hour (max design) liters (max design) 1. A copy

of your facility's responses on Form C-1-c of the August 21, 2009 CAA section 114 request were included with the CAA Section 114 request letter dated November XX, 2012. Please review those previous responses and update if necessary**November 8, 2012 CA A**  **Section 114 - Poly**

**viny l Chloride and Copoly** **mers (PVC) Production Process Wastew ater**  **PVC Production Process Wastew ater Stream Information** 

**Instructions**

1. Complete a row in Table 1 below for each PVC process wastewater stream generated within the PVC production facility that exits a piece of PVC production process equipment and is not treated by a PVC production process wastewater treatment system. 2. Complete a row in Table 2 below for each PVC process wastewater stream that exits a PVC production process wastewater treatment system. 3. In Table 4, please provide the source, flow rates, and the ID of the PVC process wastewater treatment system for each stream that enters a PVC process wastewater treatment system but that does not originate from the PVC production facility

.

**Table 1. Process Wastewater Streams Not Treated by a PVC Process Wastewater Treatment System 1**  **3**

P-1 W-9 P-1 W- 7

Dryer Centrifuges Thermal Oxidizer Scrubber **2**

**PVC Process Unit ID**  **Name of PVC Process Wastewater Stream PVC Process**  **Wastewater Stream ID** **Table 2. Process Wastewater Streams Exiting a PVC Process Wastewater Treatment System 1**  **2 3**  **4 5**  **6**

**Min** P-1 U-32 Steam Stripping Continuous W-6 60000

**Table 3. PVC Process Wastewater Destination Codes Table**

Wastewater treatment system Discharge without treatment by pipeline, sewer, or other conveyance to surface water Discharge to POTW , no treatment Discharge to PrOTW , no treatment Zero discharge or alternative disposal method Recycle to process Other

**Table 4. Non-PVC Production Process Wastewater Streams Entering a PVC Process Wastewater Treatment System 2**  **3**

**Min Ma** **x**

**PVC Process Wastewater Stream Flow Rate**

**1**

**Process Wastewater Stream Flow Rate (gallons per day)**  **Source of Process Wastewater Stream Destination Description**  **PVC Process Wastewater**  **Treatment System ID**  **PVC Process Unit ID**  **PVC Process Wastewater**  **Stream ID Is this**  **process wastewater**  **treatment system batch**  **or continuous operation?**  **Ty pe of Process**  **Wastewater Treatment System** **November 8, 2012 CA A**  **Section 114 - Poly**

**viny l Chloride and Copoly** **mers (PVC) Production Process Wastew ater** 

1. Complete a row in Table 1 below for each PVC process wastewater stream generated within the PVC production facility that exits a piece of PVC production process equipment and is not treated by a PVC production process wastewater treatment system. 2. Complete a row in Table 2 below for each PVC process wastewater stream that exits a PVC production process wastewater treatment system. 3. In Table 4, please provide the source, flow rates, and the ID of the PVC process wastewater treatment system for each stream that enters a PVC process wastewater treatment system but that does not originate from the PVC production facility

.

**Table 1. Process Wastewater Streams Not Treated by a PVC Process Wastewater Treatment System 4**  **5 6**  **7 8** 

**Min Ma** **x Av** **erage**

0 240000 65000 Estimated 365 7000 28800 14400 Estimated 365 **Flow Rate Determination**  **Me thod**  **PVC Process Wastewater Stream Flow Rate**

**(gallons per day) Operating Days Per**  **Year 7**  **8 9**  **10 11** 

**Ma x**  **Av erage**  180000 100000 Measured 365 WWT

**Code** WWT Provide nam e of the wastewater treatment system SW Provide nam e of outfall POTW RAW Provide nam e of POTW PrOTW RAW Provide nam e of PrOTW ZEROALT Describe method RECYC Describe where in the process the stream is recycled OTHER Describe

**Table 4. Non-PVC Production Process Wastewater Streams Entering a PVC Process Wastewater Treatment System 4**  **5 6**  **7**

**Av erage**  **Flow Rate**

**Determination Me** **thod PVC Process**  **Wastewater Treatment**  **System ID PVC Process Wastewater Stream Flow Rate** 

**(gallons per day) Flow Rate**  **Determination Me** **thod**

**Operating Days Per Year**  **Process Wastewater Stream Flow Rate**

**(gallons per day) Process Wastewater Destination Details to Provide in Column 12 of Table 1 and Column 11 of Table 2**  **PVC Process Wastewater Stream**  **Destination Code**

(Refer to Table 3 below) **Operating Days Per Year** 1. Complete a row in Table 1 below for each PVC process wastewater stream generated within the PVC production facility that exits a piece of PVC production process equipment and is not treated by a PVC production process wastewater treatment system.

3. In Table 4, please provide the source, flow rates, and the ID of the PVC process wastewater treatment system for each stream that enters a PVC process wastewater treatment system but that does not originate from the PVC production facility

.

**9 10** 

U-52, U-60, U-77, U-84 Process Dryers C-4 Thermal Oxidizer Scrubber **Originating PVC Process Equipment ID**  **Originating PVC Process Equipment Description** **12 13** 

Air Products W WTSystem Yes

Provide nam e of the wastewater treatment system

Describe where in the process the stream is recycled

**Process Wastewater Destination Details to Provide in Column 12 of Table 1 and Column 11 of Table 2**

**As sociated Destination**  **Information**

(Refer to Table 3 below) **Is this PVC process wastewater stream exposed to the atmosphere**  **at any point between the outlet of the PVC process wastewater**  **treatment system and its destination?** **11 12** 

WWT Air Products WWTSystem WWT Air Products WWTSystem **PVC Process Wastewater Stream Destination Code** 

(Refer to Table 3 below) **As sociated Destination Information** **Process Wastewater Destination Details to Provide in Column 12 of Table 1 and Column 11 of Table 2 14** 

**If your response in Column 3 is "Other" then please provide a description of the process wastewaetr treatment system** **13**

Yes Yes **Is this PVC process wastewater stream exposed to the atmosphere**  **at any point between the originating PVC process equipment**  **and its destination? If your response in Column 3 is "Other" then please provide a description of the process wastewaetr** **November 8, 2012 CA A**  **Section 114 - Poly**

**viny l Chloride and Copoly** **mers (PVC) Production Process Wastew ater**  **PVC Production Process Wastew ater Sampling and A** **naly sis Data** 

**Instructions**

1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system that was sampled and analyzed. Com plete one worksheet for each single stream (make copies of this worksheet if necessary). 2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of the "Stream Info" worksheet. 3. Complete columns 1 through 30. Enter the sample date, resin type, stream flow rate, basis for flow rate determination, stream temperature, sample type, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed. 4. Enter any

other HAP expected to be present (that are not listed in Table 10 to Subpart HHHHHHH of Part 63) in the table below. 4. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column. 5. Enter any

notes or additional information relevant to the sampling or analysis.

**Company Facility**  **PVC Process Wastewater Treatment Sy stem ID** 

**CA S No.**  **HA P** 

107211 Ethylene glycol 67561 Methanol 75070 Acetaldehyde 50000 Formaldehyde 51285 2,4-dinitrophenol 98862 Acetophenone 117817 Bis(2-ethylhexyl) phthalate (DEHP) 123319 Hydroquinone 108952 Phenol 79345 1,1,2,2-tetrachloroethane 106990 1,3-butadiene 540841 2,2,4-trimethylpentane 71432 Benzene 108907 Chlorobenzene **Resin Ty pe (suspension, dispersion, bulk, etc.) -->**  **Stream Flow Rate (gallons per minute) -->** 67663 Chloroform

126998 Chloroprene 98828 Cumene 75003 Ethyl chloride (Chloroethane) 100414 Ethylbenzene 107062 Ethylene dichloride (1,2-Dichloroethane) 75343 Ethylidene dichloride (1,1-Dichloroethane) 74873 Methyl chloride (Chloromethane) 75092 Methylene chloride 110543 n-Hexane 108883 Toluene 71556 Methyl chloroform (1,1,1-Trichloroethane) 79005 1,1,2-Trichloroethane 108054 Vinyl acetate 593602 Vinyl bromide (1)
75014 Vinyl chloride 75354 Vinylidene chloride (1,1-Dichloroethylene) 1330207 Xylenes (isomers and mixtures)

Note: For further informatio on the lab data qualifiers, please see the ETC and Trillium reports

Note: The M107 VCM data result was an extrapolated value that was lower than the lowest calibration standard value as per the Method.

Note: The reported value for "Xylenes (isomers and mixtures)" CAS 1330207 is the higher value of the mpXylene and o-Xylene results. The 1/27/13 sample value is the addition of the mp-Xylene and o-Xylene sample result numbers added together. Note: Steam Stripper temperature data for 1/31/2013 is missing. The temperature information was taken from a local temperature gauge as there is no automated (DCS) point for this parameter Note (1) Based on historical data for gases analyzed by SW-846 Method 8260B (SW-5030B Purge and Trap), the method quantitation limit (MQL) for Vinyl Bromide is estimated to be 1 ug/L. Due to the fact that calibration standards and verification standards were not readily available, estimated concentrations would be reported for Vinyl Bromide. Estimated concentrations are calculated based on the closest Internal Standard.**November 8, 2012 CA A**  **Section 114 - Poly**

**viny l Chloride and Copoly** **mers (PVC) Production Process Wastew ater**  **PVC Production Process Wastew ater Sampling and A** **naly sis Data** 

1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system that was sampled and analyzed. Com plete one worksheet for each single stream (make copies of this worksheet if necessary). 2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of the "Stream Info" worksheet. 3. Complete columns 1 through 30. Enter the sample date, resin type, stream flow rate, basis for flow rate determination, stream temperature, sample type, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed. 4. Enter any

other HAP expected to be present (that are not listed in Table 10 to Subpart HHHHHHH of Part 63) in the table below. 4. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column. 5. Enter any

notes or additional information relevant to the sampling or analysis.

Westlake Chemical Corporation Westlake PVC Corporation

P-1

13-008-0229

**An aly** **sis Method Concentrati**  **on (ppmw )**  **Non-Detect?**

SW -846-8015C 0.6 Y SW -846-8015C 13.2 N SW -846-8315A 0.275 N SW -846-8315A 0.314 N SW -846-8270D 0.00631 Y SW -846-8270D 0.00729 Y SW -846-8270D 0.0103 Y SW -846-8270D 0.3 Y SW -846-8270D 0.00349 Y SW -846-8260B 0.00046 N SW -846-8260B 0.00024 Y SW -846-8260B 0.00045 Y SW -846-8260B 0.00032 N SW -846-8260B 0.00004 Y **Sample Date -->** 01/07/13 **Resin Ty pe (suspension, dispersion, bulk, etc.) -->**  Suspension

**Stream Flow Rate (gallons per minute) -->**  71 **Flow Rate Determination Method -->**  Measured **Stream Temperature (degrees F) -->** 140

**An aly** **sis Date -->** 1/8/13-1/14/13 **Lab Report ID --> Lab Sample ID -->**  93428SW -846-8260B 0.0001 Y

SW -846-8260B 0.00033 Y SW -846-8260B 0.00005 Y SW -846-8260B 0.00012 Y SW -846-8260B 0.00005 Y SW -846-8260B 0.00028 Y SW -846-8260B 0.00011 Y SW -846-8260B 0.00023 Y SW -846-8260B 0.00041 Y SW -846-8260B 0.00167 Y SW -846-8260B 0.00004 Y SW -846-8260B 0.00013 Y SW -846-8260B 0.00004 Y SW -846-8260B 0.00006 Y SW -846-8260B 0.001 TIC EPA Method 107 2.8 Y SW -846-8260B 0.00007 Y SW -846-8260B 0.00012 Y

Note: For further informatio on the lab data qualifiers, please see the ETC and Trillium reports

Note: The M107 VCM data result was an extrapolated value that was lower than the lowest calibration standard value as per the Method.

Note: The reported value for "Xylenes (isomers and mixtures)" CAS 1330207 is the higher value of the mpXylene and o-Xylene results. The 1/27/13 sample value is the addition of the mp-Xylene and o-Xylene sample result numbers added together. Note: Steam Stripper temperature data for 1/31/2013 is missing. The temperature information was taken from a local temperature gauge as there is no automated (DCS) point for this parameter Note (1) Based on historical data for gases analyzed by SW-846 Method 8260B (SW-5030B Purge and Trap), the method quantitation limit (MQL) for Vinyl Bromide is estimated to be 1 ug/L. Due to the fact that calibration standards and verification standards were not readily available, estimated concentrations would be reported for Vinyl Bromide. Estimated concentrations are calculated based on the closest Internal1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system that was sampled and analyzed. Com plete one worksheet for each single stream (make copies of this worksheet if necessary). 2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of the "Stream Info" worksheet. 3. Complete columns 1 through 30. Enter the sample date, resin type, stream flow rate, basis for flow rate determination, stream temperature, sample type, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed.

4. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column.

13-010-0209

**Note(s) Concentrati** 

**on (ppmw )**  **Non-Detect? Note(s)** 

0.6 Y 32.6 N U 0.336 N UJ UJ 0.39 N J 0.0631 Y 0.0729 Y 0.103 Y UJ 0.3 Y UJ 0.0349 Y 0.00009 Y 0.00024 Y 0.00045 Y 0.00023 N J 0.00004 Y **1 2**  01/08/13 Suspension 64 Measured Measured 140 1/11/13-1/15/13

939030.0001 Y 0.00033 Y 0.00005 Y UJ 0.00012 Y 0.00005 Y 0.00028 Y 0.00011 Y UJ 0.00023 Y 0.00041 Y 0.00167 Y 0.00004 Y 0.00013 Y 0.00004 Y UJ 0.00006 Y 0.001 TIC U 2.8 Y U 0.00007 Y UJ 0.00012 Y13-010-0210 13-014-0204

**Concentrati on (ppmw** **) Non-Detect?**  **Note(s) Concentrati**  **on (ppmw )**  **Non-Detect?**

0.6 Y 0.6 Y 42.6 N 48.6 N 0.236 N UJ 0.248 N 0.275 N UJ 0.345 N 0.0631 Y 0.0631 Y 0.0729 Y 0.0729 Y 0.103 Y 0.103 Y 0.3 Y UJ 0.3 Y 0.0349 Y 0.0349 Y 0.00009 Y UJ 0.00055 N 0.00024 Y UJ 0.00024 Y 0.00045 Y UJ 0.00045 Y 0.00026 N J 0.00043 N 0.00004 Y UJ 0.00004 Y **3** 01/09/13 01/10/13 Suspension Suspension 49 56 Measured Measured 128 113.25 1/11/13-1/17/13 1/14/13-1/17/13

93906 945320.0001 Y UJ 0.0001 Y

0.00033 Y UJ 0.00033 Y 0.00005 Y UJ 0.00005 Y 0.00012 Y 0.00012 Y 0.00005 Y 0.00005 Y 0.00028 Y J 0.00028 Y 0.00011 Y UJ 0.00011 Y 0.00023 Y UJ 0.00023 Y 0.00041 Y UJ 0.00041 Y 0.00167 Y UJ 0.00167 Y 0.00004 Y UJ 0.00004 Y 0.00013 Y UJ 0.00013 Y 0.00004 Y UJ 0.00004 Y 0.00006 Y UJ 0.00006 Y 0.001 TIC 0.001 TIC 2.8 Y U 2.8 Y 0.00012 N 0.00007 Y 0.00012 Y UJ 0.00012 Y13-014-0205

**Note(s) Concentrati** 

**on (ppmw )**  **Non-Detect? Note(s)** 

0.6 Y 31.3 N UJ 4.62 N UJ J 0.244 N UJ 0.0631 Y 0.0729 Y 0.103 Y UJ 1.08 N JN 0.0349 Y J 0.00009 Y UJ 0.00024 Y UJ 0.00045 Y UJ J 0.00036 N J 0.00004 Y UJ **4 5**  01/11/13 Suspension 71 Measured Measured 124.5 1/14/13-1/21/13

945330.00025 N UJ 0.00033 Y UJ 0.00005 Y UJ 0.00012 Y 0.00005 Y 0.00028 Y J 0.00011 Y UJ 0.00023 Y UJ 0.00041 Y UJ 0.00167 Y UJ 0.00004 Y UJ 0.00013 Y UJ 0.00004 Y UJ 0.00006 Y UJ 0.001 TIC U 2.8 Y U 0.00007 Y 0.00012 Y UJ13-015-0211 13-015-0212

**Concentrati on (ppmw** **) Non-Detect?**  **Note(s) Concentrati**  **on (ppmw )**  **Non-Detect?**

0.6 Y 7.4 N 74.8 N 15.8 N 0.389 N J 1.53 N 0.299 N J 0.181 N 0.0595 Y 0.00631 Y 0.0706 N J 0.00729 Y 0.0973 Y 0.0103 Y 0.03 Y UJ 0.113 N 0.0329 Y 0.00349 Y 0.00009 Y 0.00009 Y 0.00024 Y 0.00024 Y 0.00045 Y 0.00045 Y 0.00024 N J 0.0003 N 0.00004 Y 0.00004 Y **6** 01/12/13 01/13/13 Suspension Suspension 50 79 Measured Measured 144 105 1/16/13-1/22/13 1/16/13-1/22/13

94745 947490.0001 Y 0.0001 Y

0.00033 Y 0.00033 Y 0.00005 Y 0.00005 Y 0.00012 Y 0.00012 Y 0.00005 Y 0.00005 Y 0.00028 Y 0.00028 Y 0.00011 Y 0.00011 Y 0.00023 Y 0.00023 Y 0.00041 Y 0.00041 Y 0.00167 Y 0.00167 Y 0.00004 Y 0.00004 Y 0.00013 Y 0.00013 Y 0.00004 Y 0.00004 Y 0.00006 Y 0.00006 Y 0.001 TIC 0.001 TIC 2.8 Y U 2.8 Y 0.00007 Y 0.00007 Y 0.00012 Y 0.00012 Y13-015-0213

**Note(s) Concentrati** 

**on (ppmw )**  **Non-Detect? Note(s)** 

0.6 Y 33.9 N J 0.617 N J UJ 0.376 N J 0.00631 Y 0.00729 Y 0.0103 Y JN 0.03 Y UJ 0.00349 Y 0.00009 Y 0.00024 Y 0.00045 Y J 0.00039 N J 0.00004 Y **7 8**  01/14/13 Suspension 68 Measured Measured 113.75 1/16/13-1/22/13

947500.0001 Y 0.00033 Y 0.00005 Y 0.00012 Y 0.00005 Y 0.00028 Y 0.00011 Y 0.00023 Y 0.00041 Y 0.00167 Y 0.00004 Y 0.00013 Y 0.00004 Y 0.00006 Y 0.001 TIC U 2.8 Y U 0.00007 Y 0.00012 Y13-017-0208 13-017-0209

**Concentrati on (ppmw** **) Non-Detect?**  **Note(s) Concentrati**  **on (ppmw )**  **Non-Detect?**

0.6 Y 0.6 Y 36.9 N 29.7 N 0.322 N J 3.34 N 0.407 N J 0.467 N 0.00316 Y 0.00316 Y 0.00365 Y 0.00751 N 0.00516 Y 0.00516 Y 0.015 Y UJ 0.015 Y 0.00175 Y 0.00175 Y 0.00009 Y 0.00009 Y 0.00024 Y 0.00024 Y 0.00045 Y 0.00045 Y 0.00004 Y 0.001 N 0.00004 Y 0.00004 Y **9**

Suspension Suspension 01/15/13 01/16/13

75 75 Measured Measured 109.75 125.5 1/18/13-1/22/13 1/18/13-1/23/13

95319 953210.0001 Y 0.0001 Y

0.00033 Y 0.00033 Y 0.00005 Y 0.00005 Y 0.00012 Y 0.00012 Y 0.00005 Y 0.00005 Y 0.00028 Y 0.00028 Y 0.00011 Y 0.00011 Y 0.00023 Y 0.00023 Y 0.00041 Y 0.00041 Y 0.00167 Y 0.00167 Y 0.00004 Y 0.00004 Y 0.00013 Y 0.00013 Y 0.00004 Y 0.00004 Y 0.00006 Y 0.00006 Y 0.001 TIC 0.001 TIC 2.8 Y U 2.8 Y 0.00007 Y 0.00007 Y 0.00012 Y 0.00012 Y13-018-0210

**Note(s) Concentrati** 

**on (ppmw )**  **Non-Detect? Note(s)** 

0.6 Y 44.5 N J 0.364 N J 0.383 N 0.00316 Y J 0.00365 Y J 0.00516 Y UJ 0.015 Y UJ 0.00175 Y 0.00009 Y 0.00024 Y 0.00045 Y U 0.0002 N J 0.00004 Y **10 11** 

Suspension 01/17/13

65 Measured Measured 128.5 1/21/13-1/23/13

955800.0001 Y 0.00033 Y 0.00005 Y UJ 0.00012 Y 0.00005 Y 0.00028 Y 0.00011 Y 0.00023 Y 0.00041 Y 0.00167 Y 0.00004 Y 0.00013 Y 0.00004 Y 0.00006 Y 0.001 TIC U 2.8 Y U 0.00007 Y 0.00012 Y13-021-0238 13-022-0208

**Concentrati on (ppmw** **) Non-Detect?**  **Note(s) Concentrati**  **on (ppmw )**  **Non-Detect?**

0.6 Y 0.6 Y 39.2 N 30.7 N 0.277 N 0.256 N 0.469 N 0.413 N 0.00631 Y 0.00631 Y 0.00729 Y 0.00729 Y 0.0103 Y 0.0103 Y 0.03 Y UJ 0.03 Y 0.00349 Y 0.00349 Y 0.00009 Y 0.00009 Y 0.00024 Y 0.00024 Y 0.00045 Y 0.00045 Y 0.00016 N J 0.00004 Y 0.00004 Y 0.00004 Y **12** 01/18/13 01/19/13 Suspension Suspension 50 52 Measured Measured 140.25 134.75 1/21/13-1/25/13 1/22/13-1/28/13

95938 961110.0001 Y 0.0001 Y

0.00033 Y 0.00033 Y 0.00005 Y 0.00005 Y 0.00012 Y 0.00012 Y 0.00005 Y 0.00005 Y 0.00028 Y 0.00028 Y 0.00011 Y 0.00011 Y 0.00023 Y 0.00023 Y 0.00041 Y 0.00041 Y 0.00167 Y 0.00167 Y 0.00004 Y 0.00004 Y 0.00013 Y 0.00013 Y 0.00004 Y 0.00004 Y 0.00006 Y 0.00006 Y 0.001 TIC 0.001 TIC 2.8 Y U 2.8 Y 0.00007 Y 0.00007 Y 0.00012 Y 0.00012 Y13-022-0209

**Note(s) Concentrati** 

**on (ppmw )**  **Non-Detect? Note(s)** 

0.6 Y 35.3 N 0.529 N 0.461 N 0.00631 Y 0.00729 Y 0.0103 Y UJ 0.03 Y UJ 0.00349 Y 0.00009 Y 0.00024 Y 0.00045 Y 0.00046 N J 0.00004 Y **13 14**  01/20/13 Suspension 45 Measured Measured 131 1/22/13-1/28/13

961130.00019 N J 0.00033 Y 0.00005 Y 0.00012 Y 0.00005 Y 0.00028 Y 0.00011 Y 0.00023 Y 0.00041 Y 0.00167 Y 0.00004 Y 0.00013 Y 0.00004 Y 0.00006 Y 0.001 TIC U 2.8 Y U 0.00007 Y 0.00012 Y13-022-0210 13-024-0229

**Concentrati on (ppmw** **) Non-Detect?**  **Note(s) Concentrati**  **on (ppmw )**  **Non-Detect?**

0.6 Y 5.5 N 32.2 N 48.7 N 3.97 N 0.255 N 0.991 N 0.308 N 0.00631 Y 0.00631 Y 0.00729 Y 0.00729 Y 0.0103 Y 0.0103 Y 0.03 Y UJ 0.03 Y 0.00349 Y 0.00349 Y 0.00009 Y UJ 0.00009 Y 0.00024 Y UJ 0.00024 Y 0.00045 Y UJ 0.00045 Y 0.00012 N J 0.00024 N 0.00004 Y UJ 0.00004 Y **15** 01/21/13 01/22/13 Suspension Suspension 52 51 Measured Measured 125.5 120 1/22/13-1/28/13 1/25/13-1/31/13

96115 967430.0001 Y UJ 0.0001 Y

0.00033 Y UJ 0.00033 Y 0.00005 Y UJ 0.00005 Y 0.00012 Y 0.00012 Y 0.00005 Y 0.00005 Y 0.00028 Y UJ 0.00028 Y 0.00011 Y UJ 0.00011 Y 0.00023 Y UJ 0.00023 Y 0.00041 Y UJ 0.00041 Y 0.00167 Y UJ 0.00167 Y 0.00004 Y UJ 0.00004 Y 0.00013 Y UJ 0.00013 Y 0.00004 Y UJ 0.00004 Y 0.00006 Y UJ 0.00006 Y 0.001 TIC 0.001 TIC 2.8 Y U 2.8 Y 0.00007 Y 0.00007 Y 0.00012 Y UJ 0.00012 Y13-024-0208

**Note(s) Concentrati** 

**on (ppmw )**  **Non-Detect? Note(s)** 

U 1.9 N U 25.5 N 3.63 N 0.14 N 0.00631 Y UJ 0.00729 Y 0.0103 Y UJ 0.156 N JN 0.00349 Y UJ 0.00009 Y 0.00024 Y 0.00045 Y J 0.001 N U 0.00004 Y **16 17**  01/23/13 Suspension 70 Measured Measured 138.5 1/25/13-1/31/13

967450.0001 Y 0.00033 Y 0.00005 Y 0.00012 Y UJ 0.00005 Y 0.00028 Y 0.00011 Y 0.00023 Y 0.00041 Y 0.00167 Y UJ 0.00004 Y 0.00013 Y 0.00004 Y 0.00006 Y 0.001 TIC U 2.8 Y U 0.00007 Y UJ 0.00012 Y13-028-0202

**Concentrati on (ppmw** **) Non-Detect?**  **Note(s) Concentrati**  **on (ppmw )**  **Non-Detect?**

4.9 N U 4.1 N 26.9 N 34.3 N 1.01 N 0.135 N 0.277 N 0.218 N 0.00631 Y 0.00631 Y 0.00729 Y 0.00729 Y 0.0103 Y 0.0103 Y 0.03 Y UJ 0.0349 Y 0.00349 Y 0.00349 Y 0.00009 Y 0.00009 Y 0.00024 Y 0.00024 Y 0.00045 Y 0.00045 Y 0.001 N U 0.00004 Y 0.00004 Y 0.00004 Y **18** 01/24/13 01/25/13

70 69 Suspension Suspension

Measured Measured 138.5 118.25 1/28/13-2/1/13 1/30/13-2/1/13 13-028-0201 97238 972410.0001 Y 0.0001 Y

0.00033 Y 0.00033 Y 0.00005 Y 0.00005 Y 0.00012 Y 0.00012 Y 0.00005 Y 0.00005 Y 0.00028 Y 0.00028 Y 0.00011 Y 0.00011 Y 0.00023 Y 0.00023 Y 0.00041 Y 0.00041 Y 0.00167 Y 0.00167 Y 0.00004 Y 0.00004 Y 0.00013 Y 0.00013 Y 0.00004 Y 0.00004 Y 0.00006 Y 0.00006 Y 0.001 TIC 0.001 TIC 2.8 Y U 2.8 Y 0.00007 Y 0.00007 Y 0.00012 Y 0.00012 Y13-029-0214

**Note(s) Concentrati** 

**on (ppmw )**  **Non-Detect? Note(s)** 

U 3.8 N U 31.8 N J 0.278 N J 0.476 N 0.00631 Y 0.00729 Y 0.0103 Y UJ 0.03 Y R 0.00349 Y 0.00009 Y 0.00024 Y 0.00045 Y 0.00004 Y 0.00004 Y **19 20**  01/26/13

60 Suspension

Measured Measured 117.75 1/29/13-2/4/13

974930.001 Y 0.00033 Y 0.00005 Y 0.00012 Y 0.00005 Y 0.00028 Y 0.00011 Y 0.00023 Y 0.00041 Y 0.00167 Y 0.00004 Y 0.00013 Y 0.00004 Y 0.00006 Y 0.001 TIC U 2.8 Y U 0.00007 Y 0.00012 Y13-029-0215 13-030-0268

**Concentrati on (ppmw** **) Non-Detect?**  **Note(s) Concentrati**  **on (ppmw )**  **Non-Detect?**

1.7 N U 3.7 N 30.8 N 33.8 N 0.327 N 0.475 N 0.51 N 0.534 N 0.00631 Y 0.00631 Y 0.00729 Y 0.00729 Y 0.0103 Y 0.0103 Y 0.03 Y R 0.03 Y 0.00349 Y 0.00349 Y 0.00009 Y 0.00009 Y 0.00024 Y R 0.00024 Y 0.00045 Y R 0.00045 Y 0.00004 Y 0.00004 Y 0.00004 Y 0.00004 Y **21** 01/27/13 01/28/13 Suspension Suspension 54 71 Measured Measured 125 129.25 1/29/13-2/4/13 2/1/13-2/4/13

97497 978200.0007 N J 0.0001 Y

0.00033 Y 0.00033 Y 0.00005 Y 0.00005 Y 0.00012 Y 0.00012 Y 0.00005 Y 0.00005 Y 0.00028 Y 0.00028 Y 0.00011 Y J 0.00011 Y 0.00023 Y 0.00023 Y 0.00041 Y 0.00282 N 0.00167 Y 0.00167 Y 0.00004 Y 0.00004 Y 0.00013 Y 0.00013 Y 0.00004 Y 0.00004 Y 0.00006 Y 0.00006 Y 0.001 TIC 0.001 TIC 2.8 Y U 2.8 Y 0.00011 N 0.00007 Y 0.0007 N J 0.00012 Y13-030-0269

**Note(s) Concentrati** 

**on (ppmw )**  **Non-Detect? Note(s)** 

U 3.9 N U 29.6 N 0.973 N 0.393 N 0.00631 Y 0.00729 Y 0.0103 Y R 0.03 Y UJ 0.00349 Y 0.00009 Y 0.00024 Y 0.00045 Y 0.00012 N J 0.00004 Y **22 23**  01/29/13 Suspension 48 Measured Measured 126.25 2/1/13-2/6/13

978240.0001 Y 0.00033 Y 0.00005 Y 0.00012 Y 0.00005 Y 0.00028 Y 0.00011 Y 0.00023 Y J 0.00234 N J 0.00167 Y 0.00004 Y 0.00013 Y 0.00004 Y 0.00006 Y 0.001 TIC U 2.8 Y U J 0.00007 Y 0.00012 Y2/4/13-2/16/13

13-032-0221 13-032-0222

**Concentrati on (ppmw** **) Non-Detect?**  **Note(s) Concentrati**  **on (ppmw )**  **Non-Detect?**

0.6 Y UJ 1 N 24.2 N J 27.1 N 0.462 N 0.255 N 0.375 N 0.35 N 0.00631 Y 0.00631 Y 0.00729 Y 0.00729 Y 0.0103 Y 0.0103 Y 0.03 Y UJ 0.03 Y 0.00349 Y 0.00349 Y 0.00009 Y 0.00009 Y 0.00024 Y 0.00024 Y 0.00045 Y 0.00045 Y 0.00004 Y 0.00014 N 0.00004 Y 0.00004 Y **24** 01/30/13 01/31/13 Suspension Suspension 71 60 Measured Measured 109.5 2/4/13-2/16/13

98149 981510.0001 Y 0.0001 Y

0.00033 Y 0.00033 Y 0.00005 Y 0.00005 Y 0.00012 Y UJ 0.00012 Y 0.00005 Y 0.00005 Y 0.00028 Y 0.00028 Y 0.00011 Y UJ 0.00011 Y 0.00023 Y 0.00023 Y 0.00167 N 0.00041 Y 0.00167 Y 0.00167 Y 0.00004 Y 0.00004 Y 0.00013 Y 0.00013 Y 0.00004 Y 0.00004 Y 0.00006 Y 0.00006 Y 0.001 TIC 0.001 TIC 2.8 Y U 2.8 Y 0.00007 Y 0.00007 Y 0.00012 Y 0.00012 Y13-035-0218

**Note(s) Concentrati** 

**on (ppmw )**  **Non-Detect? Note(s)** 

UJ 0.6 Y UJ J 33 N J 0.375 N 0.552 N 0.00631 Y 0.0173 N J 0.0103 Y UJ 0.03 Y UJ 0.00349 Y 0.00009 Y 0.00069 N J 0.00045 Y J 0.00019 N J 0.00004 Y **25 26**  02/01/13 Suspension 60 Measured Measured 102.75 2/4/13-2/16/13

983750.0001 Y 0.00033 Y 0.00005 Y 0.00012 Y 0.00005 Y 0.00028 Y 0.00011 Y 0.00023 Y 0.00041 Y 0.00167 Y 0.00004 Y 0.00013 Y 0.00004 Y 0.00006 Y 0.001 TIC U 2.8 Y U 0.00007 Y 0.00012 Y13-036-0225 13-036-0226

**Concentrati on (ppmw** **) Non-Detect?**  **Note(s) Concentrati**  **on (ppmw )**  **Non-Detect?**

0.6 Y 0.6 Y 21.8 N J 44 N 0.307 N 0.296 N 0.339 N 0.414 N 0.00631 Y 0.00631 Y 0.00729 Y 0.00729 Y 0.0103 Y 0.0103 Y 0.3 Y UJ 0.03 Y 0.00349 Y 0.00349 Y 0.00009 Y 0.00009 Y 0.00024 Y 0.012 Y 0.00045 Y 0.0225 Y 0.00004 Y 0.00004 Y 0.00004 Y 0.00004 Y **27** 02/02/13 02/03/13 Suspension Suspension 65 44 Measured Measured 120 128.25 2/6/13-2/27/13 2/6/13-2/27/13

98741 987430.00022 N J 0.0001 Y

0.00033 Y 0.00033 Y 0.00005 Y 0.00005 Y 0.00012 Y 0.00012 Y 0.00005 Y 0.00005 Y 0.00028 Y 0.00028 Y 0.00011 Y 0.00011 Y 0.00023 Y 0.00023 Y 0.00041 Y 0.00041 Y 0.00167 Y 0.00167 Y 0.00004 Y 0.00004 Y 0.00013 Y 0.00013 Y 0.00004 Y 0.00004 Y 0.00006 Y 0.00006 Y 0.001 TIC 0.001 TIC 2.8 Y U 2.8 Y 0.00007 Y 0.00007 Y 0.00012 Y 0.00012 Y**Note(s) Concentrati**  **on (ppmw )**  **Non-Detect? Note(s)** 

2 N J 21.4 N J 0.36 N 0.451 N 0.00631 Y 0.00729 Y 0.0103 Y UJ 0.03 Y UJ 0.00349 Y 0.00009 Y 0.00024 Y 0.00045 Y 0.00004 Y 0.00004 Y **28 29**  02/04/13 Suspension 55 Measured Measured 136 2/6/13-2/27/13 13-036-0227 987450.0001 Y 0.00033 Y 0.00005 Y 0.00012 Y 0.00005 Y 0.00028 Y 0.00011 Y 0.00023 Y 0.00041 Y 0.00167 Y 0.00004 Y 0.00013 Y 0.00004 Y 0.00006 Y 0.001 TIC U 2.8 Y U 0.00007 Y 0.00012 Y13-038-0244

**Concentrati on (ppmw** **) Non-Detect?**  **Note(s) Concentrati**  **on (ppmw )**  **Non-Detect?**

0.6 Y 34.3 N J 7.37 N 0.474 N 0.0631 Y 0.0729 Y 0.103 Y 3 Y UJ 0.0349 Y 0.00009 Y 0.00024 Y 0.00045 Y 0.00019 N J 0.00004 Y **30** 02/05/13 Suspension 70 Measured 140.25 2/8/13-2/27/13

993700.0001 Y

0.00033 Y 0.00005 Y 0.00012 Y 0.00005 Y 0.00028 Y 0.00011 Y 0.00023 Y 0.00041 Y 0.00167 Y 0.00004 Y 0.00013 Y 0.00004 Y 0.00006 Y 0.001 TIC 2.8 Y U 0.00007 Y 0.00012 Y**Note(s) Concentrati**  **on (ppmw )**  **Non-Detect? Note(s)**  **31 32** **Concentrati**

**on (ppmw )**  **Non-Detect? Note(s)**  **Concentrati on (ppmw** **) Non-Detect?**  **33 Note(s)**  **Concentrati on (ppmw** **) Non-Detect?**  **Note(s) 34**  **35 Concentrati** 

**on (ppmw )**  **Non-Detect? Note(s)**  **Concentrati on (ppmw** **) Non-Detect?**  **36 Note(s)**  **Concentrati on (ppmw** **) Non-Detect?**  **Note(s) 37**  **38 Concentrati** 

**on (ppmw )**  **Non-Detect? Note(s)**  **Concentrati on (ppmw** **) Non-Detect?**  **39 Note(s)**  **Concentrati on (ppmw** **) Non-Detect?**  **Note(s) 40**  **41 Concentrati** 

**on (ppmw )**  **Non-Detect? Note(s)**  **Concentrati on (ppmw** **) Non-Detect?**  **42 Note(s)**  **Concentrati on (ppmw** **) Non-Detect?**  **Note(s) 43**  **44 Concentrati** 

**on (ppmw )**  **Non-Detect? Note(s)**  **Concentrati on (ppmw** **) Non-Detect?**  **45 Note(s)**  **Concentrati on (ppmw** **) Non-Detect?**  **Note(s) 46**  **47 Concentrati** 

**on (ppmw )**  **Non-Detect? Note(s)**  **Concentrati on (ppmw** **) Non-Detect?**  **48 Note(s)**  **Concentrati on (ppmw** **) Non-Detect?**  **Note(s) 49**  **50 Concentrati** 

**on (ppmw )**  **Non-Detect? Note(s)**  **Concentrati on (ppmw** **) Non-Detect?**  **51 Note(s)**  **Concentrati on (ppmw** **) Non-Detect?**  **Note(s) 52**  **53 Concentrati** 

**on (ppmw )**  **Non-Detect? Note(s)**  **Concentrati on (ppmw** **) Non-Detect?**  **54 Note(s)**  **Concentrati on (ppmw** **) Non-Detect?**  **Note(s) 55**  **56 Concentrati** 

**on (ppmw )**  **Non-Detect? Note(s)**  **Concentrati on (ppmw** **) Non-Detect?**  **57 Note(s)**  **Concentrati on (ppmw** **) Non-Detect?**  **Note(s) 58**  **59 Concentrati** 

**on (ppmw )**  **Non-Detect? Note(s)**  **60**