Eastman Chemical Company 

Supplemental Submittal 

To Petition for Reconsideration, Amendment, and Administrative Stay of 

Commercial and Industrial Solid Waste Incineration Units (78 Fed. Reg. 9112) 

Background: Eastman Chemical Company (Eastman) operates three of the four coal-fired energy 

recovery units (ERUs) in the Commercial and Industrial Solid Waste Incineration Units (CISWI) final rule's 

coal-ERU subcategory. See generally Commercial and Industria/ Solid Waste Incineration Units: 

Reconsideratlon and Final Amendments, 78 Fed. Reg. 9112 (Feb. 7, 2013). 

On April 5, 2013, Eastman submitted a petition to EPA to reconsider, amend, and administratively stay 

the effective date of the offending provisions in EPA's CISWI final rule. To date, EPA has neither 

administratively granted nor denied Eastman's petition. 

On January 21, 2014, Eastman submitted to EPA a document to supplement our petition. Included in that 

submittal was additional NOx emissions data Eastman had collected from Boiler 20 for EPA's 

consideration and to demonstrate that the emission standard set for coal ERUs based on Eastman's 

Boiler 18 NOx emissions data cannot be complied with ""every day and under all operating conditions" by 

the top performer. Mossville Environmental Action Now v. EPA, 370 F.3d 1232, 1242 (D.C. Cir. 

2004)(Mossville); see also National Association of Clean WaterAgencies v. EPA, 734 F.3d 1115, 1134- 

1135 (D.C. Cir. 2013)(NACWA). 

Eastman selected Boiler 20 rather than Boiler 18 because it was operating during the period when we 

needed to collect the data and because we believe the three boilers 18, 19, and 20 are essentially 

identical and burn the same coal and industrial sludge. 

Subsequent to that submittal in followup discussions with the EPA rule-writer, EPA pointed out that when 

comparing all the data submitted by Eastman for the two boilers, that Boiler 18 appears to be the top 

performer and that they are unable to combine the data. Therefore, since the data Eastman has 

submitted for Boiler 18 includes only periods when the industrial sludge is co-fired with coal and only 

represents a narrow steam load, Eastman has collected additional data from Boiler 18 and is including 

that data in this submittal. 

Data Submittal: From April 17, 2014 through May 15, 2014, Eastman operated a temporary NOx CEMS 

on Boiler 18. The boiler was operated at various steam loads and includes only periods only coal was 

being fired. This data can be combined with data previously submitted for Boiler 18 to determine a MACT 

floor-based emission standard that the top performer (Boiler 18) can meet every day under all operating 

conditions. 

The raw hourly data is included in an attached Excel file titled "Eastman Boiler 18 NOx Data April-May 

2014.x1s" and a quality assurance document to accompany the data is included as Appendix A. 

Boiler 18 NOx Data Submittal 

June 13, 2014 

Page 1 of 3 
Appendix A 

NOx CEMS Qualitv Assurance Document 

Eastman Chemicat Company 

Supplemental Submittal to 

Petition for Reconsideration, Amendment, and Administrative Stay of 

Commercial and Industrial Solid Waste Incineration Units (78 Fed. Reg. 9112) 

Boiler 18 NOx Data Collection & Reportin 

A NOx analyzer was temporarily installed on an existing 02 dry-extractive CEMS equipped with a data 

acquisition and handling system (DAHS) and operated from April 17 — May 15, 2014. 

NOx and 02 CEMS data were collected by a data controller, which computed minute averages and 

hourly averages of ppm NOx, %02, and ppm NOx corrected to 7% 02. Minute and hourly average data 

were polled from the data controller by a personal computerand archived by the DAHS. 

Hourly average %02, ppm NOx, and ppm NOx corrected to 7% 02 data are reported from 4/17/14 to 

5/15/14, during normal operation at Boiler 18. AII data were collected while burning coal only. 

Boiler 18 NOx & 02 Data Quality Assurance 

Quality of NOx data were assured by : 

• Daily Calibration Drift testing (per 40 CFR 60 Appendix F& Performance Specification 2 in 40 

CFR 60 Appendix B) 

• Cylinder Gas Audit (per 40 CFR 60 Appendix F) 

Quality of 02 data were assured by : 

• Daily Calibration Drift testing (per Performance Specification 3 in 40 CFR 60 Appendix B) 

CEMS times are all Eastern Standard Time, because the CEMS maintains Standard Time throughout the 

year. 

Results of all quality assurance tests are included below. 

AII 1-min data, with flags, were exported from the DAHS, and block 1-hour averages were calculated for 

ppm NOx, % 02 & ppm NOx corrected to 7% 02 from the 1-min average data, after excluding all flagged 

(invalid for maintenance or calibration checks) 1-min data. 

Additionally, there were 7 time periods where the raw ppm NOx data appeared to be frozen within 0.1 

ppm. This probably resulted from a temporary, intermittent defect in data transmission or recording. AII 7 

instances were concentrated in a 6-day period abcut half-way through the monitoring period. The rest of 

the data were unaffected — daily cal checks were fully adequate —all "frozen" 1-min data were removed 

from the 1-hour averages for ppm NOx, % 02 & ppm NOx corrected to 7% 02. 

Boiler 18 NOx Data Submittal 

June 13, 2014 

Page 2 of 3 
The time periods with "frozen" ppm NOx are: 

Beginning 

04/29114 15:29 

05/02/14 14:04 

05/02/14 17:38 

05/03/14 03:20 

05/03/14 07:50 

05/03114 19:05 

05/04/14 17:45 

End 

04/30/14 05:45 

05/02/14 15:29 

05103/14 01:16 

05103/14 06:03 

05103/14 08:46 

05/03/14 21:08 

05/04/14 18:43 

Elapsed 

857 min (14:17) 

86 min (01:26) 

459 min (07:39) 

164 min (02:44) 

57 min (00:57) 

124 min (02:04) 

59 min (00:59) 

40 CFR Part 75 CEMS rules from 40 CRF 75.10(d)(1) were used to determine what 1-hour averages to 

include for ppm NOx, % 02 & ppm NOx corrected to 7% 02. A valid 1-hour block average is calculated 

using all valid 1-min averages within that clock hour, provided that there are more than 15 valid 1-min 

averages within the hour. 

Attachments 

Boiler 18 Temporary NOx CEMS Calibration Data 

NOx Cylinder Gas Audit Determination 

Calibration Detail (02) 

Boiler 18 NOx Data Submittal 

June 13, 2014 

Page 3 of 3 
Boiler 18 Temporary NOx CEMS Calibration [heck Oata 

Level NOxConcentration Gaa Ex tratlan 

Zere 0.0 ppm Nitmgen N/A 

Hi h 546.0 CC421761 12 30 3U20 

600 m NOxCEMSanal e value 

5.0% orspan NOxCEMSDaIIyCallbratlonDrlflRequlrement from40CFR60,AppendlxF,Se<tI0n4.1, 

and q0 CFR 60, Appendix 0, PedOrmance Spetlfi[a6on 2 SeRion 13.1 

NOx NOx NOx 

NOx NOx Calibration Calibration Calibration 

Reference Aclual Ori@ Dri@ Drift 

Calibratinn Value Response Values 

% nfs a 

Llmlt 

% ofs a 

Sdtus 

Paz Fail 

Event 

Oate Time Level Date Tme Descrl tiOn 

4/lT/3U14 14:23 Zero 0.0 1.2 03% 5.0% Pass 

4/12/203i 14[2T HIgM1 546.0 542.4 0.2% 5.0% Pass 

4/17/2014 14:44 eegin NOx analyeerOn-Ilne 

4/18/3014 8:15 Zero 0.0 1.5 0.3% 5.0% Pass 

4/10/2014 8:20 High 546.0 5N1.1 -0.3% 50% Pass 

4/19/2014 8:40 Zem 0.0 1.5 0.3°b 5.0% Pass 

4/19/2014 8:52 HIgM1 5960 536.5 -0.6°b 5.0% Pasz 

4/20/3014 8:16 Zero 0.0 1.6 0.3% 5.0% Pass 

4/20/2014 83o High 546.0 544.3 -0.3% 5.0% Pass 

J/E1/2014 8:04 Zero 0.0 2.2 0.4% 5.0•.6 Pass 

4/21/]U34 8:15 High 5460 549.2 0.5% 5.0°,6 Pass 

4/2112014 1500 SlarlCyllnderGas Audlt 

4131/2014 15:24 End CqlinderGasAVdit 

4132/2014 2:25 2ero 0.0 O.B 0.1% 5.0% Pass 

4122/2014 7:30 HIgM1 546.0 545.2 0.0% 5.0% Pass 

4/23/2014 255 2er0 0.0 1.5 0 3% 5.0% Pass 

4/2312015 2:59 High 5460 346.3 0.0% 5.0% Pass 

4/24/3014 8:1S Zem 0.0 1.5 0.3% 5.0% Pass 

4124/2014 9:21 High 546.0 515.6 -5.1% 5.0% Fail 4/24/2014 0:31Faildailyspancheck 

4/24/3014 8:26 Z¢ro 0.0 2.2 0.4% 5.0% Pass 

4/24/2014 8:41 High S46.0 541.5 -0.8% 50% Pass 4/2E/2014 8:41 Passdallycaschecksafterspanadf 

4125/2014 7A1 Zem OD 1.5 03% 5.0% Pass 

4/25/2014 7:55 Hlgb 546.0 528.8 -2.9% 5.0% Pass 

4/26/2014 813 Zero 00 1.7 0.3% S.P.6 Pass 

4126/2014 8:16 High 546.0 566.1 3.4% 5.0% Pass 

4/17/2014 7[19 Zero 0.0 13 0.3% 5.0% Pass 

4122/3014 2:33 High 3460 5293 5.5% 5.0% Fxil 4127/2014 7:33 Fail daily span check 

411713014 2:32 2ero 0.0 2.0 03% 5.0% Pass 

4/2212014 2:40 Nigh 5460 S423 -0.5% 5.0% Pass 4/32/1014 Z:qOPasstlallymschecksaflerspanadj 

4128/3014 932 Zero 0.0 1.0 0.2% 5.0% Pass 

4/3R/3U34 9:41 HigM1 546.0 535.8 1.6% 5.0% Pass 

4/29/2014 7:18 Zero 00 0.9 0.3% 5.0% Pasz 

4139/2014 7:11 Hlgh 546.0 564.0 10% 5.05% Pass 

4130/2014 858 Zero 0.0 1.2 0.3% 5.0% Pass 

4/30/2014 9:03 Hlgh 546.0 333.3 1.1% 5.0% Pass 

5/1/2014 7:0 5/1/2014 2:02 Sample handlingsystem mainienance & 

5/112034 855 S/1/2014 8:55NOxanalyterPMivoltageadfuslment 

5/1/3014 858 Zero 0.0 1-4 01% 50% Pass 

5/1/I014 9[02 High 546.0 5q4.8 0.2% 5.0% Pass 51112014 9:02 Fassdaily check aftermainlenance 

51I1I014 7:20 Zem 0.0 0.4 O.1°h 5.0% Pass 

51312014 2:28 Nlgh 546.0 5520 10% 5.0% Pass 

513/1014 942 tern 0.0 0.2 0.0% 5.0% Pass 

5/3/304 9:46 High 516.0 558.7 2.1% 5.0% Pass 

5/4/2014 846 Zero 0.0 0.4 0.1% 5.0% Pass 

5/4/2014 8:50 High 3460 558.2 3.1% 5.0% Pass 

51512014 919 2em 0.0 0.4 0.1% 5.0% Pass 

51512014 8:13 Hlgh 506.0 S38.5 -1.3% 5.0% Pass 

5/6/3014 245 Zero 0 0 0.3 0.1% 5.0°.6 Pass 

5/612019 7:49 High 546.0 535.6 -1.7% 5.0% Pass 

51713014 7:40 Zero 0.0 0.4 0.1% 5.0% Pass 

51212014 Z[JJ High 346.0 541.0 0.0% 50% Pass 

5/9/1014 252 Eem 0.0 0.4 0.1% 5.0% Pass 

5/8/2014 256 High 546.0 5303 -2.5% 5.0% Pass 

518/2014 1512 Zero D.0 0.8 0.1% 5.0% Pass 

5191201415:16 High S46.0 595.8 0.0% 5.0% Pass 

51912014 7:35 Zero 0.0 0.2 00% 5.0% Pass 

5/9/2014 7:39 High 546.0 555.8 1.6% 5.0% Pass 

5/10/2014 1003 ZerO 0.0 0.1 0.0% 5,0APass 

5/10/1U1J 30:07 Hlgh 546.0 550.1 0.7% 5.0% Pass 

5/11/2014 936 2em 0.0 OA 0.1% 5.0% Pass 

511112014 9:40 High 546.0 552.2 1.1°h 5.0% Pass 

511211014 224 Zem 0.0 0.8 0.1% 5.0°b Pasi 

5/1212014 7:28 High 546.0 551.1 09% 5.0% Pass 

5/13/I014 7:53 Zem 0.0 oA 0.1% 5.0% Pass 

5/13/2014 7:58 HigM1 S460 554.0 1.3% 5.0% Pass 

511413014 2:39 Zem 1 0.0 0.3 0.1% 5.0% Pass 

5/1412014 7:43 High 556.0 353.8 1.3% 5Mb Pass 

5p51E014 224 5/15/2014 2:24 9uller 18off-Ilne 
I ReviewedBy: ..... . ..... .. . 

Eastman Chemical Company Environmental Services Laboratory 

NOx Cylinder Gas Audit Determination 

S, pate. Reason for Test: 

 urce: _6~ Reason for Test 

------------ 

 -----

7--_~ !hjlialOjertiflcatjon '

_ 

' 

...... 

I Building: B-83 Test Aborted: N - I Primary Analyzer: I I EGO 42(;-HL 42CHL-75882 I Alternate Analyzer: 1~ — ---- -- 

_IVIonnor Moit NOx Span: 600 ppmv 

Level Cylinder NumEer I Eoncentraiion— Units Expiration Date Check 

Low ~TMU -€p~wamm ppmv OK 120-180 

High V4 b ppMV OK: 300-360 

Start Time: Finish Time: na m -n. 

Run 

Refererice 

Value 

ppmv 

Actual 

Value 

ppmv 

Low -1 139.4 7~1-1----F-,,,,~~c~~ -A,4T2 ~ 

High - 1 337.8 

Low - 

139.4 AT-A 

High — 2 

Low - 3 

337.8 

139.4 

- - ----- Average Values & CEMS Accuracy 

Low High 

High - 3 337.8 ppmv ppmv 

Average CEMS Response 

CEMS Accuracy (ppmv) 

GEMS Accuracy (percent) 

Limit <= 15% (or <= 5 ppmv) 

141.0 342.1 

1.6 4.3 

1% 1% 

PASS PASS 

Document Number THSE-ESL-CEM-5065- 3 Effective Date: June 14, 2010 
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