# 3

GLP10-01-01 Interim Report 20: Analysis for PFOA in Soils Collected from BP Property Wells in July 2011 

# Study Title 3M Environmental Laboratory Analytical Protocol GLP 10-01-01: Analysis of Perfluorooctanoic Acid (PFOA) in Groundwater, Soil and Sediment for t he 3M Decatur Phase 3 Site-Related Monitoring Program 

# Data Requirement EPA TSCA Good Laboratory Practice Standards 40 CFR Part 792



# Study Director Jaisimha Kesari P.E., DEE Weston Solutions, Inc. 1400 Weston Way West Chester, PA 19380 

# Phone: 610-701-3761 

# Principal Analytical Investigator

Cleston C. Lange, Ph.D. 3M Environmental Laboratory 

# Interim Report Completion Date

Upon Signing 

# Performing Laboratory 3M Environmental Health and Safety Operations

Environmental Laboratory 3M Center, Bldg 260-05-N-17 St. Paul, MN 55144 

# Project Identification GLP10-01-01-20 Total Number of Pages

120

# Study: GLP10-01-01, Interim Report 20 Analysis for PFOA in Soils from BP Property Wells, July 2011 This page has been reserved for specific country re quirements.

# Study: GLP10-01-01, Interim Report 20 Analysis for PFOA in Soils from BP Property Wells, July 2011


# T ABLE OF 

# C ONTENTS GLP Compliance Statement ..........................
................................................... ......................................... 3 Quality Assurance Statement .......................
................................................... .......................................... 4 Table of Contents .................................
................................................... ................................................... 5 List of Tables ....................................
................................................... ................................................... ..... 6 1 Study Information .................................
................................................... ............................................ 7 2 Summary ...........................................
................................................... ............................................... 8 3 Introduction ......................................
................................................... ................................................. 9 4 Test, Control and Reference Substances ............
................................................... ........................... 9 5 Test System .......................................
................................................... ............................................. 10 6 Method Summary ....................................
................................................... ....................................... 10 6.1 Methods ...........................................
................................................... .................................. 10 6.2 Sample Collection .................................
................................................... ............................. 10 6.3 Sample Preparation ................................
................................................... ........................... 10 6.4 Percent Soil Moisture Determination ...............
................................................... ................. 11 6.5 LC/MS/MS Analysis .................................
................................................... .......................... 11 7 Analytical Results ................................
................................................... ........................................... 12 7.1 Calibration .......................................
................................................... ................................... 12 7.1 Limits of Quantitation (LOQs) ...........
................................................... ................................. 13 7.2 Continuing Calibration ............................
................................................... ........................... 13 7.3 Blanks ............................................
................................................... ..................................... 14 7.4 Laboratory Control Spikes (LCSs) ..................
................................................... .................. 14 7.5 Laboratory Matrix Spikes (LMSs) ...................
................................................... .................. 14 7.6 Percent Moisture Determinations ...................
................................................... .................. 15 7.7 Individual Sample Results .........................
................................................... ........................ 15

# Study: GLP10-01-01, Interim Report 20 Analysis for PFOA in Soils from BP Property Wells, July 2011
8 Conclusion ........................................
................................................... .............................................. 17 9 Data/Sample Retention .............................
................................................... ..................................... 17 10 List of Attachments ...............................
................................................... .......................................... 17 11 Signatures ........................................
................................................... ............................................... 18



# L IST OF 

# T

ABLES Table 1. PFOA Results for Soils from BP Groundwate r Well Locations, July 2011 ....................... ....... 8 Table 2. LMS Recovery for Soils from BP Groundwate r Well Locations, July 2011 ....................... ...... 8 Table 3. Control and Reference Substances ........
................................................... ................................ 9 Table 4. Instrument Information ..................
................................................... ......................................... 11 Table 5. Gradient Liquid Chromatography Conditions(ETS-8-053)....................................... .............. 12 Table 6. Mass Transitions ........................
................................................... ............................................ 12 Table 7. PFOA Calibration Summary ................
................................................... .................................. 13 Table 8. LCS Results (PFOA, linear + branched isom er) ............................................... ...................... 14 Table 9. Percent Moistures for Soils from BP Groun dwater Well Locations, July 2011 .................. .... 15 Table 10. Individual Sample Results for DAL SS BPM W121 0 0000........................................ ........... 15 Table 11. Individual Sample Results for DAL SS BPMW 121 0 0000......................................... ........... 16 Table 12. Individual Sample Results for DAL SS BPMW 47 0 0000 ......................................... ............. 16

# Study: GLP10-01-01, Interim Report 20 Analysis for PFOA in Soils from BP Property Wells, July 2011 

# 1 Study Information
Sponsor 3M Company Sponsor Representative Gary A. Hohenstein Environmental Manager Special Projects, EHS Operations Bldg 224-5W-03 St. Paul, MN 55144 Phone: (651) 737-3570 gahohenstein@mmm.com Study Director Jaisimha Kesari, P.E., DEE Weston Solutions, Inc. 1400 Weston Way West Chester, PA 19380 Study Analytical Testing Facility 3M EHS Operations Environmental Laboratory Building 260-5N-17 St. Paul, MN 55144 Study Personnel (3M Environmental Laboratory) Cleston C. Lange, Ph.D., Principal Analytical Inves tigator William K. Reagen, Ph.D., Laboratory Manager Marlene Heying Laboratory Technician (Pace Analytic al, Professional Services) Study Dates Study Initiation: March 08, 2010 Interim Analytical Initiation: January 15, 2011 Interim Analytical Completion: January 20, 2011 Interim Report Completion: Date of Signing Location of Archives All original raw data and analytical reports have b een archived at the 3M Environmental Laboratory according to 40 CFR Part 792. The analy tical reference standard reserve samples are archived at the 3M Environmental Labora tory according to 40 CFR Part 79

# Study: GLP10-01-01, Interim Report 20 Analysis for PFOA in Soils from BP Property Wells, July 2011 

# 2 Summary This interim report 20 of study GLP10-01-01 provide s the determined concentration results for perfluorooctanoic acid (PFOA) measured in two soils collected from groundwater well locations on the B P property adjacent to the 3M Decatur, AL facility. Samples were received into the laboratory electroni c LIM system under related project GLP10-01-01-20. One s oil travel blanks (trip blanks, containing approximately 10-30 grams of a control soil TCR-842 , accompanied the sample bottles to and from the site. Sample preparation included removing and acc urately weighing soil aliquots from each sample bot tle and extracting them per method ETS-8-053. For the trip blank, three aliquots were removed and extracted. The first and second replicates served as sample and sample duplicate, the third replicate was fortified with nominal 1.00 ng of PFOA (linear isom er) as a laboratory matrix spike (LMS) sample. Forthe two soil samples, four aliquots were removed from e ach and extracted. The first and second aliquots served as sample and sample duplicate, the third an d fourth aliquot served as LMSs fortified at nomina l 5.00 ng and 50.0 ng of PFOA (linear isomer), respec tively. Matrix matched calibration standards and laboratory control spike (LCS) were also prepared b y fortifying a control soil with known quantities o f PFOA (linear) and extracted in parallel with the sa mples. Quantitative analysis of the soil extracts was performed by a sensitive LC/MS/MS method. The perc ent moisture of each soil was determined and the results reported on a dry soil weight basis. The a verage PFOA concentrations and relative percent difference (RPD) values are summarized in Table 1 . The recoveries of fortified PFOA (linear isomer) from LMS samples are summarized in Table 2
. Table 1. PFOA Results for Soils from BP Groundwate r Well Locations, July 2011 3M LIMS ID Sample ID Avg. PFOA Concentration (ng/g; dry weight) RPD 

# GLP10-01-01-20-001 DAL SS TRIP 0 0000 BLQ N/A 

# GLP10-01-01-20-002 DAL SS BPMW121 0 0000 1.53 24% 

# GLP10-01-01-20-003 DAL SS BPMW47 0 0000 0.917 3.1% LMS results were within acceptance criteria of 100 + 30% Concentration values are shown at 3 significant fig ures, but more precise data was used for data calcu lations. N/A; not applicable BLQ; LC/MS/MS analyte response was below the respon se for the nominal 0.200 ng/g soil standard that de fined the LLOQ.


# Table 2. LMS Recovery for Soils from BP Groundwate r Well Locations, July 2011
3M LIMS ID Sample ID PFOA Spike Concentration (ng/g; dry weight) PFOA

Recovery (%) 

# GLP10-01-01-20-001 LMS DAL SS TRIP 0 0000 Lab Matri x Spike 0.903 99.8% GLP10-01-01-20-002 low DAL SS BPMW121 0 0000 Lab Ma trix Spike Low 4.38 100% GLP10-01-01-20-002 High DAL SS BPMW121 0 0000 Lab M atrix Spike High 44.8 102% GLP10-01-01-20-003 Low DAL SS BPMW47 0 0000 Lab Mat rix Spike Low 4.33 97.3% GLP10-01-01-20-003 High DAL SS BPMW47 0 0000 Lab Ma trix Spike High 47.8 102% LMS samples were fortified with PFOA (linear isomer ). Concentration values are shown at 3 significant fig ures, but more precise data was used for data calcu lations.

# Study: GLP10-01-01, Interim Report 20 Analysis for PFOA in Soils from BP Property Wells, July 2011


# 3 Introduction The soil analyses reported herein were conducted as part of the Phase 3 Environmental Monitoring and Assessment Program for the 3M facility located in Decatur, Alabama. The objective of the overall program is to gain information regarding co ncentrations of perfluorooctanoic acid (PFOA) in various environmental media such as groundwater, so il and sediment that are associated with and near the Decatur facility. Reported herein are the results from analysis of two soils collected groundwater well locations on the BP property locat ed adjacent to the 3M Decatur facility. The wells were BP well MW-47 and BP well MW-121. The samples were collected by Weston Solutions, Inc. personnel in July 2011 and shipped to the 3M Enviro nmental Laboratory for quantitative analysis of PFOA. One soil travel blank (trip blank) which acc ompanied the sample bottle shipment to and from the site was also analyzed and reported herein. This report describes the sample shipment, receipt, extraction and quantitative LC/MS/MS analysis procedures conducted for determination of PFOA in t he soil samples received. Additionally included in this report are the assessment of the analytical precision and accuracy for the reported PFOA concentration results. 

# 4 Test, Control and Reference Substances This study does not have a test substance in the cl assic sense of a GLP study because this study was purely analytical in nature. The reference and control substances are listed in Table 3
. Table 3. Control and Reference Substances Test Substance PFOA (linear isomer) PFOA (linear + branched isomers) M4-PFOA M8-PFOA Chemical Name Perfluoro-n-Octanoic Acid Ammonium Perfluorooctanoate 13 

# C 4 

# -PFOA 13 

# C 8 

# -PFOA Chemical Formula n-C 8 

# F 15 

# O 2 

# H C 8 

# F 15 

# O 2 

# NH 4 13 

# C 4 12 

# C 4 

# F 15 

# O 2 

# H 13 

# C 8 

# F 15 

# O 2 

# H Use Calibration & LMSs LCSs Surrogate Internal Standard (IS) Source Oakwood 3M Wellington Laboratories Wellington Labor atories Expiration Date 01/17/2018 02/27/2017 12/07/2013 9/28/2013 Storage Conditions Frozen Frozen Frozen Frozen Chemical Lot 3440 332 MPFOA1210 M8PFC-C-0910 lot 092310 TCR Number TCR07-0041-1/1 TCR-123 TCR08-0042-9/9 TCR10-0048-3/ 16, -4/16 Physical Description White Powder White Powder Methanol Solution [a] 

# IS Mix in Methanol Solution [a] 

# Purity 99.1% 95% 100% 100% [a] Stable isotope labeled materials are provided a s methanol solutions by the commercial vendor (sour ce); the vendor’s reported concentration is used for calculating concentration s when provided.

# Study: GLP10-01-01, Interim Report 20 Analysis for PFOA in Soils from BP Property Wells, July 2011 

# 5 Test System There was not a test system, test substance or cont rol substance used in the classic sense of a GLP study. Because of that, there was also no dosing. This study is being conducted for analysis of environmental soil samples collected from groundwat er well locations on the BP property adjacent to the 3M Decatur, AL site in July 2011. 

# 6 Method Summary 6.1 Methods Soil extractions and quantitative LC/MS/MS analysiswere performed following method ETS-8-053.0. Analysis was conducted as analytical run 110719a on July 19, 2011. 

# 6.2 Sample Collection On July 7, 2011 two 250 -mL HDPE NalgeneTM sample bo ttles and one travel blank (trip blanks) containing approximately 25 grams of a control soil in a sealed 250 mL HDPE bottles, were sent from the 3M Environmental Laboratory to Weston Solu tions, Inc. field personnel for collection of soils from BP groundwater well locations at Decatur , AL. Following the soil/sediment sample collections into the sample bottles, the samples we re returned back to the laboratory for analysis. Samples were received at the laboratory with sample chains of custody numbers #16807 on July 18, 2011 and were logged into project GLP10-01-01-2 0 in the 3M laboratory information management system (LIMS). Samples were stored refr igerated until they could be extracted and analyzed. Soil samples from Decatur, AL are regulated and wer e appropriately shipped in accordance with USDA/APHIS soil permit number P330-09-00125. Sample nomenclature followed the form DAL-xx-xx-xx- xxxx where the first string defines the Decatur Alabama (DAL) project area, the second string defin es the sample media (i.e., SS = soil sample, TRIP = trip blank), the third string defined the sample we ll identity, the fourth string defines the sample type (0 = primary sample, DB = field duplicate, etc.), and th e fifth string indicates the sampling depth range ( e.g. 0000 indicates 0.0 to 0.5 ft interval soil sample). 

# 6.3 Sample Preparation Each soil extraction involved removal of a 1 cubic centimeter (1 cc; 1 mL) soil aliquot (typically ~ 1 gram) from each sample bottle using a fixed volume 1 cc s poon, transferring it to a 15 mL conical centrifuge tube, followed by accurate weight determination of the aliquot on a 5-place balance. Then, a known quantity of internal standard (IS; nominal 3.0 ng) and surrogate (nominal 3.0 ng) were added to each s oil aliquot. Surrogate recoveries were not reported he rein and are for on-going method validation purpose s to evaluate surrogate recovery in field samples. F or LMS preparations, an additional known quantity of PFOA (linear isomer) was also added. Each 1 cc soi l aliquot was extracted by addition of 8 mL of a 4: 1 acetonitrile:water solution followed by sonication for approximately 1 hour and then centrifugation to remove solids. The supernatant of each centrifuged extract was transferred to an autovial for LC/MS/MS analysis. For this study, the samples were analyzed on July 1 9, 2011 as analytical run s110719a. Calibration standards were prepared by spiking know n quantities of PFOA (linear isomer) into 1-cubic centimeter (1 cc, 1 mL) aliquots of 3M Environmenta l Laboratory control soil TCR-842 (aliquot ID 11002-46). The nominal mass of 1 cc of control soi l TCR-842 is 1.0 gram (dry). The nominal calibrati on standard range prepared and analyzed was 0.200 ng/g to 500 ng/g.

# Study: GLP10-01-01, Interim Report 20 Analysis for PFOA in Soils from BP Property Wells, July 2011 Laboratory control spike (LCS) samples were prepare d with the sample extraction; prepared at two levels (nominal 3.0 ng/g and 30 ng/g), each level was prepared in triplicate. The LCSs were prepared using control soil TCR-842, same as calibration sta ndards, and were fortified with PFOA (linear plus branched isomer reference material). 

# 6.4 Percent Soil Moisture Determination The percent moisture of soils was used to calculatethe dry weight of the wet soils weighed during sample preparations for PFOA analysis, and was dete rmined by gravimetric analysis. Dry weights were determined for separate weighings than the weighing s used for extractions. To determine the percent moisture, duplicate aliquots of each soil sample we re removed and the accurate “wet” weight determined for each. All aliquots were dried at >100°C until no further mass loss occurred from wat er evaporation, at which time the accurate dried weights were deter mined. The difference in mass, attributed to water evaporation, was used to calculate the percent mois ture of the original soil. The averaged percent moisture result for each was then used to calculatethe soil PFOA concentration on a dry weight basis. 

# 6.5 LC/MS/MS Analysis The analysis of soil extracts for PFOA was performe d by LC/MS/MS as described in method ETS-8-053.0. The relative percent difference (RPD) of the duplicate sample results was used as a measure of the analytical precision. The determine d recovery of fortified PFOA from LMS samples was used as a measure of analytical accuracy. Surr ogate recoveries were not reported herein and are for on-going method validation purposes to eval uate surrogate recovery in field samples. Those results will be included in a separate method validation report addendum for method ETS-8- 053. Details of the specific instrument parameters, the liquid chromatography gradient program, and the specific mass transitions analyzed are detailed in the raw data, and are briefly described below in Table 4 , Table 5and Table 6
. Table 4. Instrument Information Instrument Name ETS-Stan Analytical Method ID ETS-8-053.0 Liquid Chromatograph Agilent 1100 with Binary Pump Guard column Pre-Autosampler; Prism RP (2.1 x 50 mm, 5 μ m) Extraction column Betasil C18 (2.1 x 100 mm, 5 μ m Analytical column Oasis HLB (3 x 20 mm, 25 μ m); 30°C Injection Volume 25 μ L Mass Spectrometer API 4000 Ion Source TurboIon Spray Polarity Negative Software Analyst 1.4.2

# Study: GLP10-01-01, Interim Report 20 Analysis for PFOA in Soils from BP Property Wells, July 2011 Table 5. Gradient Liquid Chromatography Conditions (ETS-8-053) Step Number Total Time

[min] Flow Rate

[mL/min] Percent A

[2 mm Aqueous Ammonium Acetate] Percent B [ Acetonitrile] 1 0.0 0.400 97.0 3.0 2 3.0 0.400 97.0 3.0 3 3.5 0.400 70.0 30.0 4 17.0 0.400 40.0 60.0 5 17.5 0.400 10.0 90.0 6 19.5 0.400 10.0 90.0 7 20.0 0.400 97.0 3.0 8 23.0 0.400 97.0 3.0 

# Table 6. Mass Transitions

Analyte Mass Transitions Monitored PFOA 413>169, 413>219, 413>369 13 

# C 4 

# -PFOA (Surrogate) 417>169, 417>219, 417>372 13 

# C 8 

# -PFOA (IS) 421>172, 421>223, 421>376 Note: Multiple mass transitions are summed to give the instrument response for that analyte. 

# 7 Analytical Results All concentration results are rounded to three sign ificant figures according to EPA rounding rules. Because of rounding, values may vary slightly from those found in the raw data. Laboratory matrix spikes (LMS) meeting the method acceptance criteria of 100 ± 30%, demonstrate that the method was appropriate. The spiked concentrations at nomi nal 5.00 ng were the most adequate with respect to the PFOA measured in the samples. 

# 7.1 Calibration Calibration standards were prepared by spiking vary ing known quantities of PFOA (linear isomer) and surrogate, and a fixed quantity of internal standard, into separate 1-cubic centimeter (1 cc, 1 mL) aliquots of 3M Environmental Laboratory matrix soil TCR-842 (nominal 1.0 gram per mL). A total of eleven (11) soil matrix calibration standards rangi ng from nominal PFOA concentration 0.200 ng to 500 ng were prepared for the definitive analysis. Following the analysis of calibration standards, th e nominal concentration of each standard was plotted versus t he measured analyte peak area/IS peak area response ratio. A quadratic equation with 1/x weig hting was used to fit the calibration response data
. Calibration curves were not forced through zero. C alculating the determined standard concentration using the resultant calibration curve and comparing to the known concentration confirmed accuracy of each curve point within 100 ± 30% (+35% at the LLOQ). The correlation coefficient (r) was greater than 0.999, and coefficient of determination (r 2 

# ) was greater than 0.990. Calibration results for PFOA are summarized in Table 7
. Because soil weights vary significantly for a 1 cc (1 mL) soil sample, depending on soil type and mois ture content, the instrument response was calibrated for the known amount of PFOA added to each 1 cc soil

# Study: GLP10-01-01, Interim Report 20 Analysis for PFOA in Soils from BP Property Wells, July 2011 calibration standard prior to extraction, then corrected for soil mass and moisture content. Becausea 1cc aliquot of control soil TCR-842 weighed nominal 1.0 gram (dry weight), the nominal concentration range of the calibration set was essentially 0.200 ng/g to 500 ng/g. However, because the sample soil s vary in moisture content and soil composition and d ensity, 1 cc aliquots typically weigh more than 1.0 gram. Therefore, the final measured results from t he analysis were adjusted for the accurate determined dry weight of each 1 cc sample aliquot extracted. Table 7. PFOA Calibration Summary
Analytical Run PFOA (ng/mL) **r**

STD 1 STD 2 STD 3 STD 4 STD 5 STD 6 STD 7 STD 8 STD 9 STD 10 STD

11 STD

12 

# Actual 0.200 0.500 0.750 1.00 2.50 5.00 10.0 25.0 50.0 100 200 500 N/A s110719a 0.174 0.471 0.727 0.909 2.81 5.17 10.9 27 51.3 96.5 196 503 0.9996 Average Recovery **87.1% 94.3% 96.9% 90.9% 112% 103% 109% 108% 103% 96 .5% 98.2% 101%**  N/A


# 7.1 Limits of Quantitation (LOQs) The lower limit of quantitation (LLOQ) was the lowest non-zero calibration standard in the curve that met the linearity and accuracy requirement for a low st andard (100 +35%) and for which the area counts were at least 2X that of the average response deter mined for the method blank injected just prior to t he calibration standards . The LLOQ for this study wa s the nominal 0.200 ng calibration standard (nomina l 0.200 ng/g in soil TCR-842), and was the lowest pre pared calibration standard. All sample analyte responses less than the response of the 0.200 ng ca libration standard were reported as BLQ (below the limits of quantitation). The upper limit of quanti tation (ULOQ) was the nominal 500 ng calibration standard. 

# 7.2 Continuing Calibration During the course of each analysis, continuing cali bration verifications (CCVs) were performed by regu lar injection of a mid-level calibration standard after approximately every 15th sample injected in the analytical run. The back calculated concentration results were used to confirm that the instrument response and the initial calibration curve were sti ll in control. All CCVs flanking reported data met the method criteria of 100% ± 30% accuracy.

# Study: GLP10-01-01, Interim Report 20 Analysis for PFOA in Soils from BP Property Wells, July 2011 

# 7.3 Blanks Three types of blanks were analyzed during this ana lysis: method blanks were prepared with blank matrix soil TCR-842 and were spiked with IS and sur rogate; travel blanks (trip blanks) prepared from aliquots of soil TCR-842 sealed in s ample bottle t hat accompanied the bottle order to and from the sampling site; and solvent blanks containing extraction solvent. The different blank results were reviewed to evaluate potential contamination during shipment and sampling, and to evaluate method performance parameters such as injector carry over and to establish the LLOQ. 

# 7.4 Laboratory Control Spikes (LCSs) Laboratory control spikes were prepared by spiking known quantities of PFOA (linear + branched isomers) into 1 cc aliquots of soil TCR-842, fortif ied with nominal 3.0 ng/g and 30 ng/g of PFOA (lin ear + branched isomer). The linear + branched isomer qua ntitation using a linear PFOA calibration curve provided a measure of accuracy in quantifying the s um of potential linear + branched PFOA isomers that may be associated with environmental samples. Each LCS level was prepared in triplicate. The results for the LCS analyses are shown in Table 8 . The method acceptance criteria of 100 ± 30% was met for all LCSs. The LCS recoveries were calculated using the following equation:


# 100% * ion Concentrat Spike LCS)

of ion Concentrat d (Determine Recovery LCS =
Table 8. LCS Results (PFOA, linear + branched isom er) **Measured PFOA (ng) Sample ID 3.0 ng LCS**  **30 ng LCS** 

# Actual Conc. (ng/g) 3.00 30.0 LCS 1 (run s110313a) 

# 2.70 26.3 LCS 2 (run s110313a) 

# 2.46 25.8 LCS 3 (run s1103137a) 

# 2.46 26.2 **n 3 3**  **Average 2.54 26.1**  **Standard Deviation 0.14**  **0.26 RSD**  **5.5% 1.0%**  **Average LCS Recovery 84.7% 87.0%**  

# 7.5 Laboratory Matrix Spikes (LMSs) Laboratory matrix spikes (LMSs) were generated by s piking a known quantity of PFOA (linear isomer) to an aliquot of each soil sample and then preparing t he sample the same as regular non-spiked samples. For this study, LMSs were spiked at two levels in a nticipation one level would be an appropriate level relative to the endogenous PFOA levels in the soils . The LMS recoveries for PFOA from samples ranged from 97.3% to 102%. The LMS recovery result s are summarized in Table 2 , and the individual sample results are shown in Table 10. The PFOA recovery calculations for LMS samples used the following equation:


# 100% * ion Concentrat Spike Sample) Field of ion Concentrat Determined LMS of ion Concentrat d (Determine Recovery LMS −



# =

# Study: GLP10-01-01, Interim Report 20 Analysis for PFOA in Soils from BP Property Wells, July 2011 

# 7.6 Percent Moisture Determinations The percent moisture was determined for each soil s ample. Duplicate aliquots of each were taken and accurately weighed to determine the “wet” weight. Then each aliquot was dried at > 100°C until no further loss in mass occurred due to water evaporat ion, after which the dry weight was accurately determined. The average percent moisture and RPD of the duplicate determinations for each soil are reported in Table 9 . The percent moisture was calculated by the following equation:


# 100% * Mass Wet Soil Original Mass)

Soil Dried Mass Wet Soil (Original Moisture Percent −



# =
Table 9. Percent Moistures for Soils from BP Groun dwater Well Locations, July 2011 LIMS ID Sample ID Moisture Content (%, w/w) [a] 

# Relative Percent

Difference [a] 

# GLP10-01-01-20-001 DAL SS TRIP 0 0000 2.89% 15% 

# GLP10-01-01-20-002 DAL SS BPMW121 0 0000 12.5% 5.9% 

# GLP10-01-01-20-003 DAL SS BPMW47 0 0000 12.4% 5.9% [a] Result determined as the average result for dup licate soil aliquots removed from each sample bottl e.


# 7.7 Individual Sample Results Table 10. Individual Sample Results for DAL SS TRI P 0 0000 [Control Soil TCR-842] DAL SS TRIP 0 0000 PFOA

GLP10-01-01-20-001 Primary Result (ng/g; dry wt.) BLQ* Replicate Result (ng/g; dry wt.) BLQ* Avg. Result (ng/g; dry wt.) BLQ* RPD (%) NA Low-LMS Result (ng/g; dry wt.) 0.901 Actual Low-LMS Spike (ng/g; dry wt.) 0.903 Low-LMS Spike Recovery (%) 99.8% BLQ; Analyte response was below the lower limit of quantitation; less than nominal 0.200 ng/g NA: result was not applicable as the both the sampl e and sample duplicate were <LLOQ. Values of BLQ were treated as zero concentration fo r recovery calculations. LMSs were fortified with PFOA (linear isomer)

# Study: GLP10-01-01, Interim Report 20 Analysis for PFOA in Soils from BP Property Wells, July 2011 Table 11. Individual Sample Results for DAL SS BPMW 121 0 0000 DAL SS BPMW121 0 0000 PFOA

GLP10-01-01-20-002 Primary Result (ng/g; dry wt.) 1.71 Replicate Result (ng/g; dry wt.) 1.34 Avg. Result (ng/g; dry wt.) 1.53 RPD (%) 24% Low-LMS Result (ng/g; dry wt.) 5.89 Actual Low-LMS Spike (ng/g; dry wt.) 4.38 Low-LMS Spike Recovery (%) 100% High-LMS Result (ng/g; dry wt.) 47.3 Actual High-LMS Spike (ng/g; dry wt.) 44.8 High-LMS Spike Recovery (%) 102% LMSs were fortified with PFOA (linear isomer)

Table 12. Individual Sample Results for DAL SS BPMW 47 0 0000 DAL SS BPMW47 0 0000 PFOA

GLP10-01-01-20-003 Primary Result (ng/g; dry wt.) 0.931 Replicate Result (ng/g; dry wt.) 0.903 Avg. Result (ng/g; dry wt.) 0.917 RPD (%) 3.1% Low-LMS Result (ng/g; dry wt.) 5.13 Actual Low-LMS Spike (ng/g; dry wt.) 4.33 Low-LMS Spike Recovery (%) 97.3% High-LMS Result (ng/g; dry wt.) 49.8 Actual High-LMS Spike (ng/g; dry wt.) 47.8 High-LMS Spike Recovery (%) 102% LMSs were fortified with PFOA (linear isomer)

# Study: GLP10-01-01, Interim Report 20 Analysis for PFOA in Soils from BP Property Wells, July 2011


# 8 Conclusion Soils from the two BP groundwater well locations c ollected in July 2011 were successfully analyzed for PFOA following 3M Environmental Laboratory meth od ETS-8-053.0 and conducted as 3M study GLP10-01-01-20. The average PFOA concentration res ults for the soil samples are summarized in Table 1 and associated sample LMS recoveries are summarize d in Table 2 . The soil trip blank that accompanied the sample bottles to the site and then accompanied samples back to the laboratory was sufficiently devoid of PFOA, indicating that no contamination of the samples occurred during sample shipment and storage. The accuracy of the results based on LMS recoveries were within acceptance criteria of 100 + 30%; all LMS results were between 97.3% and 102% recovery. The analytical method uncertainty was determined from statistical examination of the LCS results and was + 6.5% at the 95% confidence limit, as determined in Table 14
. Table 14. Analytical Method Uncertainty 

# Sample ID PFOA Recovery (%) LCS-110719-01 3 ng LCS in TCR-842 

# 90.0% LCS-110719-02 3 ng LCS in TCR-842 

# 82.0% LCS-110719-03 3 ng LCS in TCR-842 

# 82.0% LCS-110719-04 30 ng LCS in TCR-842 

# 87.7% LCS-110719-05 30 ng LCS in TCR-842 

# 86.0% LCS-110719-06 30 ng LCS in TCR-842 

# 87.3% Average 85.8% Standard Deviation 3.2% Analytical Method Uncertainty (2 x Std. Dev.); 95% confidence 6.5%


# 9 Data/Sample Retention All soil samples and associated project data (hardc opy and electronic) will be archived as project GLP 10- 01-01-20 according to 3M Environmental Laboratory s tandard operating procedures.


# 10 List of Attachments Attachment A: Preparation Forms, Raw Data and Chromatograms

# Study: GLP10-01-01, Interim Report 20 Analysis for PFOA in Soils from BP Property Wells, July 2011


# Attachment A Preparation Forms, Raw Data and Chromatograms

# S M Environmeiita fLaborator y

Far m Sm' S - A- PW

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Decatu r Soi lSamplin g
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fo r soi lsamplin g wa s prepare da s follows :

• Onesoi ltri p blank

ina25 0mLNalgen ebottle , close dandseale dwit htape , andlabele da s Trip Blank
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contain s o f

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# Recorde dBy : Gabrie lP
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# 7 - 7- "

# O ^f-/^^/ / -Fll-UtUt ) , Soi l Extractio n Stieet Soil s Extracted-?/-7/28M —
Sampl e I D
1 EC-110719-0 1 EC-110719-0 2 EC-110719-0 3 EC-110719-0 4 EC-110719-0 5 eC-110719-0 6 EC-110719-0 7 EC-110719-0 8 EC-110719-0 9 EC-110719-1 0 EC-110719-1 1 EC-110719-1 2 LCS-110719-0 1 LCS-110719-0 2 LCS-110719-0 3 LCS-110719-D 4 LCS-110719-0 5 LCS-110719-0 6 IVlB-110719-0 1 IVIB-110719-02 MB-110719-0 3 MB-110719-0 4 MB-110719-0 5 MB-110719-0 6 GLPlO-01-01-20-00 1 GLPlO-01-01-20-00 1 Du p GLPlO-01-01-20-00 1 IM S GLPlO-01-01-20-00 2 GLPlO-01-01-20-00 2 Du p GLPlO-01-01-20-00 2 lo w GLPlO-01-01-20-00 2 Hig h GLPlO-01-01-20-00 3 GLPlO-01-01-20-00 3 Du p GLPlO-01-01-20-00 3 Lo

w GLPlO-01-01-20-00 3 Hig h Sampl e Descriptio n
2 0. 2 n q Extracte d Curv e Poin t 0. 5 n q Extracte d Curv e Poin t 0.7 5 n q Extracte d Curv e Poin t 1 n q Extracte d Curv e Poin t 2. 5 n q Extracte d Cun/e Poin t 5 n q Extracte d Curv e Poin t 1 0 n q Extracte d Curv e Poin t 2 5 n q Extracte d Curv e Poin t 5 0 n q Extracte d Curv e Poin t 10 0 n q Extracte d Curv e Poin t 20 0 n q Extracte d Curv e Poin t 50 0 n q Extracte d Curv e Poin t 3 nq LC S i n TCR-84 2 3 nq LC S i n TCR-84 2 3 nq LC S i n TCR-84 2 3 0 n q LC S i n TCR-84 2 3 0 n q LC S i n TCR-84 2 3 0 n q LC S i n TCR-84 2 Metho d Blan k

w/ o I S Metho d Blan k

w/o I S Metho d Blan k

w/ o I S Metho d Blan k

w / I S Metho d Blan k

w / I S Metho d Blan k

w / I S DA LS S TRI P 0 000 0 DA LS S TRI P 0 000 0 Duplicat e DA LS S TRI P 0 000 0 Lab Matri xSpik e DA LS S BPMW/121 0 000 0 DA LS S BPMW121 0 000 0 Duplicat e DA LS S BPMW12 1 0 000 0 La b Matri xSpike Low DA LS S BPMW12 1 0 000 0 La b Matri xSpike Hig h DA LS S BPMW47 0 000 0 DA LS S BPMW47 0 000 0 Duplicat e DA LS S BPMW4 7 0 000 0 La b Matri xSpike Lo w DA LS S BPMW4 7 0 000 0 La b Matri xSpike Hig h Soi l lUatrl xI D
3 1 1 005-9 3 1 1 005-9 3 1 1 005-9 3 11005-9 3 1 1 005-9 3 11005-9 3 1 1 005-9 3 11005-9 3 1 1 005-9 3 11005-9 3 1 1 005-9 3 1 1 005-9 3 1 1 005-9 3 1 1 005-9 3 1 1 005-9 3 1 1 005-9 3 1 1 005-9 3 1 1 005-9 3 1 1 005-9 3 1 1 005-9 3 1 1 005-9 3 1 1 005-9 3 1 1 005-9 3 1 1 005-9 3 

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Use d (g ) 4 1.146 6 1.1544 1.159 6 1.141 5 1.1343 1.1360 1.085 8 1.1094 1.1335 1.085 7 1.1077 1.0940 1.1033 1.1072 1.132 9 1.1492 1.141 1 1.115 7 1.148 0 1.149 6 1.136 8 1.1345 1.1477 1.140 8 1.138 6 1.16B 1 1.140 6 1.1737 1.189 7 1.3032 1.276 0 1.3364 1.328 0 1.3182 1.194 9 Spik e I D

5 11002-22 6 1 1 002-22 6 11002-22 6 1 1 002-22 6 11002-22 5 1 1 002-22 5 11002-22 5 1 0 006-13 2 1 0 006-13 2 1 0 006-13 2 1 0 006-13 2 1 0 006-13 2 1 1 005-3 4 11005-3 4 1 1 005-3 4 1 0 006-15 0 1 0 006-15 0 1 0 006-15 0 '»Ji!MM»iSsK S 

## ':~imm^mKM m .••«««^MW?;"
. 

## , •'^*m»:^m ^

. ..-^-^a^.j - •ifri^^wr-j s 1 1 002-22 6 

## •M^t^mf A 11002-22 5 1 0 006-13 2 

## «?",-;;• •: 11002-22 5 1 0 006-13 2 Spik e

Volum e (uL ) 6 1 0 2 5 37. 5 5 0 12. 6 2 5 5 0 12. 5 2 5 5 0 10 0 25 0 1 5 1 5 1 5 1 5 1 5 1 5

••«««» » 

## ;"ii*» ^ ^«M« W <mmm » -»-*«« s •'^»-a » 

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## ^MH M \^M V 2 5 2 5 NW- A 

## • 4 ^ 2 5 2 5 Interna l Standar d I D 7 1 1 002-24 2 11002-24 2 1 1 002-24 2 11002-24 2 1 1 002-24 2 11002-24 2 1 1 002-24 2 11002-24 2 1 1 002-24 2 1 1 002-24 2 1 1 002-24 2 1 1 002-24 2 11002-24 2 1 1 002-24 2 11002-24 2 1 1 002-24 2 11002-24 2 1 1 002-24 2 

## ^m ^ - . i <ap»*-^";: i 

## mm » ',» i 1 1 002-24 2 11002-24 2 1 1 002-24 2 11002-24 2 1 1 002-24 2 1 1 002-24 2 1 1 002-24 2 11002-24 2 1 1 002-24 2 1 1 002-24 2 1 1 002-24 2 11002-24 2 1 1 002-24 2 1 1 002-24 2 Interna l

Standar d Volum e (uL ) 8 1 5 1 5 1 5 1 5 1 5 1 5 1 5 1 5 1 5 1 5 1 5 1 5 1 5 1 5 1 5 1 5 1 5 1 5 

## ••^mm m ;««fi ^ •,v»»^ ^ 

### 1 5 1 5 1 5 1 5 1 5 1 5 1 5 1 5 1 5 1 5 1 5 1 6 1 5 1 5 Surrogat e

Spik e I D 9 1 1 002-23 2 11002-23 2 1 1 002-23 2 11002-23 2 1 1 002-23 1 11002-23 1 1 1 002-23 1 11002-23 1 1 1 002-23 1 1 0 006-13 3 1 0 006-13 3 1 0 006-13 3 1 1 002-23 1 1 1 002-23 1 11002-23 1 1 1 002-23 1 11002-23 1 1 1 002-23 1 #?*'•»*» • 

## •?mms ^ Ximm^ s 1 1 002-23 1 11002-23 1 1 1 002-23 1 1 1 002-23 1 1 1 002-23 1 11002-23 1 11002-23 1 1 1 002-23 1 1 1 002-23 1 11002-23 1 11002-23 1 1 1 002-23 1 1 1 002-23 1 11002-23 1 Surrogat e

Spik e Volum e (uL ) 1 0 1 0 2 5 37. 5 5 0 12. 5 2 5 5 0 12 5 25 0 1 0 2 0 5 0 1 5 1 5 1 5 1 5 1 5 1 5 

## «««« ' •^^^^* > j^ss-z w 1 5 1 5 1 5 1 5 1 5 1 5 1 5 1 5 1 5 1 5 1 5 1 5 1 5 1 5 Ad d Extractio n Solven t (mL ) 1 1 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8

, 8 8 8 8 8 8 8 8 8 8 Sonicat e

1 h r 1 2 mm h mm h mm h mm h mm h mm h mm h mm h mm h mm h mm h mm h mm h mm h mm h mm h mm h mm h mm h mm h mm h mm h mm h mm h mm h mm h mm h mm h mm h mm h mm h mm h mm h mm h mm h Centrifug e

1 3 mm h mm h mm h mm h mm h mm h mm h mm h mm h mm h mm h mm h mm h mm h mm h mm h mm h mm h mm h mm h mm h mm h mm h mm h mm h mm h mm h mm h mm h mm h mm h mm h mm h mm h mm h Comment s 1 4

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### Pipett e ID : 340227 7 -^v ^ Pipett e ID : 382441 4 / ^ ' Co l 7 &8 : Pipett e ID : 340227 7 

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^ / Co l9 & 10 : Pipett e ID : TAVi m Pipett e ID ; 38244

_ 

## < ^ ^ Co l11 : Extractio n Solven tID : 1 0 006-16 8 Co l12 : SonicalorlD : QEJ10059500 3 Co l13 : Centrifug e ID : 152143 0 10min(ai3000RP M 

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## ^Z/^/ /

## GLP10-01-0 1



# y? ^ % Moisture Determinatio n

Sampl e I D
1 GLPlO-01-01-20-00 1 GLPlO-01-01-20-00 1 Du p GLPlO-01-01-20-00 2 GLPlO-01-01-20-00 2 Du p GLPlO-01-01-20-00 3 GLPlO-01-01-20-00 3 Du p Sampi e Descriptio n
2 DALS S TRi P 0 000 0 DALS S TRi P 0 000 0 Duplicate DALSSBPH/IW12 1 0 000 0 DALS S BPH/1W12 1 0 000 0 Duplicate DALS S BPMW47 0 000 0 DALS S BPMW47 0 000 0 Duplicate Weigh to f Weighin g Dis h (g ) 3 1.3087 1.3027 1.3090 1.307 4 1.301 1 1.3057 Initia l

Weigh t(soi l + Dish ) (g ) 4 • 2.348 7 2.305 9 2.372 5 2.603 9 2.352 6 2.406 3 1s t

Determinatio n Weigh t(soi l + Dish ) (g ) 5 2.316 3 2.279 0 2.243 0 2.4365 2.218 7 2.2735 Differenc e

(g ) 6 0.032 4 0.026 9 0.129 5 0.1674 0.133 9 0.132 8 2n d

Determinatio n Weigh t(soi l + Dish ) (g ) 7 2.316 3 2.279 1 2.243 0 2.4364 2.218 8 2.274 3 Differenc e

(g ) 8 0.000 0 -0.000 1 0.000 0 0.000 1 -0.000 1 -0.000 8 % Moistur e *

1 1 3.1 2 2.6 7 12. 2 12. 9 12. 7 12. 0 Averag e %

Moistur e 1 2 2.8 9 12. 5 12. 4 RP D (

% Moisture ) 1 3 15. 3 5. 9 5. 9
Colum n 3 : Balance ID : Initial/Date : Colum n 4 : Balance ID : Tem p ofOve n ('C) : Ove n Time/Date In : Initial/Date : 90 0 7/18/201 1 mm h 90 0 107. 3 4:1 7 p m mm h 7/18/1 1 mm h 7/18/1 1 Colum n 5 : Tem p o fOve n CC) : 10 1 Ove n Time/Date Out : 7/21/201 1 14:34 Ove n Time/Date In : 7/21/201114:4 4 Balance ID : 90 0 Initial/Date : ^^-^-^-^^^~~ " '^^/'^/ /

' Th e lastrecorde d weigh ti s use d fo rth e calculatio n of% moisture
. olum n 7 : Tem p ofOve n ("C) : Ove n Time/Date Out : Ove n Time/Date In : N/

A Balance ID : Initial/Date : /

\ 100. 7 4:50p m 7/21/1 1

90 0 

# 7^/-/ /

Ove n ID : OV- 1 Prob e ID : Prob e #1 , RI D #1 4

Pag e 1 of1

## GLP10-01-01-0 8 % Moistur e Determinatio n

Sampl e I D
1 GLPlO-01-01-20-00 1 GLPlO-01-01-20-00 1 Du p GLPlO-01-01-20-00 2 GLPlO-01-01-20-00 2 Du p GLPlO-01-01-20-00 3 GLPlO-01-01-20-00 3 Du p Sampl e Descriptio n
2 DALSS TRI P 0 000 0 DALS S TRI P 0 000 0 Duplicate DALSSBPMW12 1 0 000 0 DALS S BPMW12 1 0 000 0 Duplicate DALS S BPMW47 0 000 0 DALS S BPMW47 0 000 0 Duplicat e Weigh to f Weighin g Dis h (g ) 3 1.3087 1.3027 1.3090 1.307 4 1.301 1 1.3057 Initia l

Weigh t(sol i + Dlsh)(g ) 4 2.348 7 2.305 9 2.372 5 2.603 9 2.352 6 2.406 3 1s t

Determinatio n Weigh t(soi l + Dlsh)(g ) 5

••

, I 

## Differenc e

(g ) 6



# . . ' '

.

. . • 2n d

Determinatio n Weigh t(soi l + Dish ) (g ) 7

••

• ;

• 

# * ' Differenc e

(g ) 8

r



# , • % Moistur e *

1 1

• 

# ' Averag e %

Moistur e 1 2 RP D (

% Moisture ) 1 3

Colum n 3 : Balance ID : Initial/Date : Colum n 4 : Balance ID : Tem p o fOve n ('C) : Ove n Time/Dat e In : Initial/Date : Ove n ID : OV- 1 Prob e ID : Prob e #1 , RT D #1 4 

# ^° ° 

# /'-S o 7/18/201 1 J^f'Py^ ^ 90 0 107. 3 4:1 7 p m mm h 7/18/1 1 Colum n 5 : Tem p ofOve n (X) : Ove n Time/Date Out : Ove n Time/Date In : Balance ID : Initial/Date :

* Th e lastrecorde d weigh ti s use d fo rth e calculatio n o f% moisture
. Colum n 7 :

Tem p ofOve n fC) : Ove n Time/Date Out : Ove n Time/Date In : N/

A Balance ID : Initial/Date :

Pag e 1 of1

# ENVIRONMENTALLABORATORY 

# INTERNA LCHAIN-OF-CUSTOD Y Sampl e Interna l Transfe r
Sampl e se tI D # Lims # N/ A GLP10-01-01-2 0 Sampl e Description : Decatu rSoil s INTERNA LCHAI N O F CUSTOD Y 3 M Sampl e ID s Out : storag e I D Init/dat e 

# ::^J^)i*f ^ In : storag e I D



# a/^ - / Init/d a Comments/lnlt/dat e GLPlO-01-01-20-00 1 A/^- / 

# ;;^7'f'/
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# ± ^ ^ ^ GLPlO-01-01-20-00 3

Pag e 1 o f1

# ENVIRONMENTA LLABORATOR Y 

# INTERNA LCHAIN-OF-CUSTOD Y Sampl e Interna l Transfe r
Sampl e se tI D # Lims # N/ A GLP10-01-01-2 0 Sampl e Description : Decatu rSoil s INTERNA LCHAI N O F CUSTOD Y 3 M Sampl e ID s Out : storag e I D



# /^^/ - .^^^^ ^

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# /^/< ^ - / GLPlO-01-01-20-00 2 ^ 

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# SINGL E COMPONEN TPREPARATIO N LO G 

# M
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Compoun d Nam e MPFBA MPFHx A M8PF0A M9PFN A M6PFD A M7PFUn A MPFDo A M3PFHxS M8PF0 S M8F0S A CorrecUo

n Facto r 0.99 5 0.997 0.99 8 0.99 8 0.99 8 0.99 8 0.99 8 0.94 6 0.95 7 0.998
. ^f

Concentration (ug/mL ) 5.0 0 5.0 0 5.0 0 5.0 0 5.0 0 5.0 0 5.0 0 5.0 0 5.0 0 

# "tim

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) 5.00 5.0 0 5.0 0 5.00 5.00 5.0 0 5.00 5.00 5.00 5.0 0 

# l^i c S/i3/i\ Corrected Concentration (Ug/mL ) 4.9 8 4.9 9 4.9 9 4.9 9 4.9 9 4.9 9 4.9 9 4.7 3 4.7 9 4.9 9 Reviewe dby : Signature , / j Dat e 

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# DATAREVIE WSUMMARYFOR M

Date : 7/27/2011 Dat aAnalyst : mmh Study# : GLP10-01-01-2 0 Description : Decatu r Soil s Batch : s i10719 a Result s Table : sll0719a.rd b Instrument : StanV166030 S Method(s) : ETS-8-053. 0 Dat aRevie w Sign-Of f Analys t Revjrfvan dAccepf

i 

# Nam e/ Date V/2 ^

- 9 ' 

## o f

Manua lIntegration s

Technica lan dManua lIntegratio nRe : Nam e/ Date : /V< , 

# •?'Z7- W

Comment s /

Justifications :

Analyte : PFO A Comments/Justifications : Acceptabl eLinear

Range : InternalStandard : LOQ : 0.20 0n g N A 0.20 0n g t o 50 0n g M8PF0 A 

# 1 Analyte : MPFO A Comments/Justifications : Acceptabl eLinear

Range : InternalStandard : LOQ : 0.20 0n g I 0.20 0n g t o 49 9 n g M8PFO A 

# 1 1 MB-110719-0 6 Metho dBlan k w/ I S wa s spike dtwic ewithsurrogate .

Analyte : N/A Comments/Justifications : Acceptabl eLinear

Range : InternalStandard : LOQ : N/A N/A N/A N/A 

# 1
Analyte : N/A Comments/Justifications : Acceptabl eLinear

Range : InternalStandard : LOQ : N/A N/A N/A N/A 

# 1
Analyte : Comments / Acceptabl e N/A

Justifications : Linear Range : InternalStandard : LOQ : N/A N/A N/A N/A



# Pag e 1 of1

# Stan : API4000 : V166030 5 pag e1/ 1 DAT E7/19/1 1 ANALYST : mm

h STUDYNUMBER;GLP10-01-01-20Matrix : Decatu r Soil s Injectionvolume : 25 uLElectrode : Turb o ionspra y Mobil ePhase : (A

Mm M ammoniu

macetat e(B ) acetonitrile TN-A

- o r standar dnumbe r (A) 11002-21 2(B ) TNll-0155-4/ 8

Guar d(pre-autosampler ) columnPrismR P Size : 2. 1 m

mX5 0m mType : C1 2Spher esize : 5 Par t number : 32105-05213 0Lot number : 9660Seria

lnumbe r 0311510V 1 Analyticalcolumn1 Oasi s HL B Size : 3 X20m

mType : N

ASpher

esize : 25 u

m Par t number : 18600203 9 seria lnumber : 006A30055105 03 Analyticalcolumn2BetasilCI S Size : 2. 1 m

mX10 0m mType : CI 8 Spher esize : 5 Par t number : 70105-10213 0Lot number : 1055 9 Seria

lnumbe r 0701663 T

Printed : Tuesday , July19,201 1 5:45 P M

### *ET S StanV166030 5

Acquisitio nInformatio n Aoquisitio n^fethcd : Created : Las t Modified : Carment : Synchronizatio nMode : fluto-Dquilibration: Acquisitio nDuration : Nuirte r O f Scans : Eferiod s I nFile : Acquisitio nModule : Softwar eversio n Agilen t I C Pur p Metho dPropertie s Punp Model : Miniiru nPressur e(psi ) I^xinu nPressur e(psi ) CeadVolui E(ul) : ^fexi^umFlo w Banp {ml/min^) : ^fexinll nPressur eBanp Ste p Table : Ste p Tota lTiiie(min ) C 0.0 0 1 3.0 0 23.5 0 

# 3 

# n.o o 4 17.5 0 5 19.5 0 6 20.0 0 7 23.0 0 Left Carpressibility ; Righ t Carpressibility : Left DeadVolun e(pi) : Righ t Bsa dVolim e(ul ) Left Strok eVolui E(u l (psi/sec) :
Fle w Rat e(pl/min ) 40 0 40 0 40 0 40 0 40 0 40 0 40 0 40 0 50. 0 115. 0 40. 0 40. 0 

# : Righ t Strok eVolut e(pi) : Left Solvent : Righ t Solvent : A l

B2 Agilen t Autosaitple r

Propertie s Autosaitple r

Model : Syring eSiz e(pi) : Injectio nVolur e(pi) : Dra w Spee d(pl/min) : Ejec t Spee d(pl/min) : Needl eLeve l(irni) : Tarperatur eContro l Setpoin t ( 4 - 4 0C) : Was hi s no t use d ET S 8-5 3 2 3 mi nPEQA-2.da m Tuesda ySeptaiibe r

2 1 201 0 Thursda yApri l2 1 201 1 10 : 19 : 2 3 A M [fetho dfo r

PEC R2 3 minut egradien t I £Syn c Of f 23min0se o 191 7 1 Acquisitio n^fetho d Analys t 1.4. 2 Agilen t 110 0I C Binar yPurr

p 0. 0 5801. 0 40. 0 100. 0 290. 0
A(% ) B (%) 97. 03. 0 97. 03. 0 70. 030. 0 40. 060. 0 10. 090. 0 10. 09o; o 97. 03. 0 97. 03. 0

-1. 0 -1. 0

Agilen t 110 0Thenn o Autosairple r 10 0 25.0 0 200. 0 200. 0 0.0 0 Eiiable d 1 0
Us eCustc mInjecto r

Prograrr Agilen t Colu mOvenPropertie s lef t Toiperatur e("C) : Righ t Teirperatur e(°C ) 30.0 0 Tarperatur eToleranc e+/

- (°C) : Star t Acquisitio nToleranc e+/

- (°C) : Tiir eTabl e Colti mSwitciuji g Valv e (Used) Installe d Positio nfo r

firs t sanpl ei nth ebatch ; N o
30.0 0 1.0 0 0.5 0 Righ t Us esamepositio nfo r al lsanple s i nth ebatc h Tota lTiiTe(min ) O.O C l«f t 5.0 C Ri.^ t

Perio d1 : Scan s i nPeriod : Relativ eStar t

Tine : Ejq^eriirent s i nPeriod : Perio d1 Eb^riiren t ScanType : Polarity : Sca nMode : Io nSource : Resolutio nQl : Resolutio nQ3 ; Intensit yIhres. : Settlin g Tine : M RE^iise : Valv ePositio n

191 7 0.0 0mse c 1 1 : ME W

### (MRM ) 

### Negativ e N/ A Turb o Spra y Uni t Uni t 0.0 0cp s 0.000 0mse c 5.007 0mse c 14 : 03 : 1 7 m

Printing Date : Tuesday , Jul y19 , 201 1 Printing Time : 5:44:2 9 P M Pag e 1 o f 2

### •ET S Sta nV166030 5

Ma : N

o Ste p Size : 0.0 0am i Q lttes s (amu

) Q 3 Mas s {aim

) CUell(nisec ) Parai r Star t Ste p 413.O C 369.0 075.0 0CE-14.0 0-14.0 0 OC P-9.0 0-9.0 0
Q l^fas s (amj ) Q

3 Mas s {amu } Cwel l(msec ) Parai r Star t Ste p 413.0 0219.O C 75.0 0CE-24.0 0-24.0 0 CX E-15.0 0-15.0 0
Q lMas s (amu

) Q 3 tfes s (amu

) Dwel l(msec ) E^rar r Star t Ste p 413.0 0169.0 075.0 0C E-28.0 0-28.0 0 O S -9.0 0-9.0 0
Q lI«^ s (amu

) Q 3 Mas s (aim) Dwel l(nBec ) Parair Star t Ste p 417.0 0372.0 075.0 0C E-14.0 0-14.0 0 O S -9.0 0-9.0 0
Q lMas s (aim) Q

3 Nbs s (aim) Dwel l(msec ) Parai r Star t Sto p 421.0 0376.0 075.0 0C E-14.0 0-14.0 0 CX E-9.0 0-9.0 0
Q l^fes s (aim) Q

3 ^tls s (aim) Dwel l(msec ) E^rair Star t Ste p 417.0 0219.0 075.0 0C E-14.0 0-14.0 0 OC I-7.0 0-7.0 0
Q l^^s s (aim) Q

3 ^fas s (aim) Dwel l(msec ) Parar r Star t Ste p 417.0 0169.0 075.0 0C E-14.0 0-14.0 0 CX E-7.0 0-7.0 0
Q lMas s (arm) Q3 Mas s (aim) Dwel l(msec ) Parair Star t Ste p 421.0 0223.0 075.0 0C E-14.0 0-14.0 0 O I-7.0 0-7.0 0
Q lVlas s (arm) Q

3 Mas s (arm) Dwel l(msec ) Parart Star t Ste p 421.0 0172.0 075.0 0C E-14.0 0-14.0 0 Of f -9.0 0-9.0 0 Paranete r

Tabl e(Eteric d1 Experinen t 1) : CA D CU R GS l GS2 IS : TE M ih e D P EI 6.0 0

35.0 0 45.0 0 60.0 0 -4500.0 0 450.0 0 C N -40.0 0 -10.0 0

Printin g Date : Tuesday , Jul y19 , 201 1 Pag e 2 o f 2
Printin g Time : 5:44:2 9 P M

### *ET S StanV166030 5

Projec t Sampl e

1 2 3 4 5 6 7 8 ' 9 

# l o "1 1 1 2 1 3 14 ' 1 5 '1' 6 1 7 1 8 1 9 ' 2 0 2 1 2 2 2 3 2 4 2 5 2 6 27 ' '2 8 '2 9 ' 3 0 '3 1 3 2 3 3 3 4 35 ' 3 6 '3 7 3 8 '3 9 4 0 41 ' 4 2 4 3 4 4 4 5 '4 6 4 7 4 8 4 9 5 0 5 1 5 2 5 3 ' 5 4 5 5 5 6 5 7 58 ' 5 9 6 0 6" l \\Winsnas01a\b2\Project*Lab_lnstrumen tData\Stan\Sta n Dat a FileSProjects^fluorochemicalsisoi l Batch:s110719 a Tab: £

Sampl e «,„„, „ i n ' '^<=' ' ' V'^ ' Nam e Sampl e I D ^^^ ^ Positio n
s 110719a00 1 ,1 0 006-16 8 solven tblan k s 110719a00 2 ,1 0 006-16 8 solven tblan k s 110719a00 3 1 0 006-16 8 solven tblan k s110719a00 4 1 0 006-16 8 solven tblan k s110719a00 5 1 0 006-16 8 solven tblan k s 110719a00 6 1 0 006-16 8 solven tblan k s110719a00 7 1 0 006-16 8 solven tblan k s 110719a00 8 EC-110719-0 9 5 0 n g War m u p standar d s 110719a00 9 EC-110719-0 9 5 0 n g War m u p standar d s 110719a01 0 EC-110719-0 9 5 0 n g War m u p standar d s 110719a01 1 1 0 006-16 8 solven tblan k s110719a01 2 1 0 006-16 8 solven tblan k s110719a01 3 1 0 006-16 8 solven tblan k s 110719a01 4 1 0 006-16 8 solven tblan k s i 10719a015 i 1 0 006-16 8 solven tblan k s110719a01 6 iffi- l 10719-0 1 0. 2 n g Extracte d Curv e R)in t s110719a01 7 EC-110719-0 2 0. 5 n g Extracte d Curv e Rjin t s i 10719a01 8 EC-110719-0 3 0.7 5 n g Bitracte d Curv e Poin t s110719a019!EC-110719-0 4 1 n g Extracte d Curv e Fbin t s110719a02 0 iEC-110719-0 5 2. 5 n g Extracte d Curv e Poin t s110719a02 1 EC-110719-0 6 5 n g Bctracte d Curv e Ftoin t s110719a02 2 EC-110719-0 7 1 0 n g Extracte d Curv e Rain t s 110719a02 3 EC-110719-0 8 2 5 n g B<tracte d Curv e Fbin t s110719a02 4 'EC-110719-0 9 5 0 n g Extracte d Curv e Poin t s110719a02 5 EC-110719-1 0 10 0 n g Extracte d Curv e Rain t s110719a02 6 EC-110719-1 1 20 0 n g Extracte d Curv e ftjint s110719a02 7 EC-110719-1 2 50 0 n g Extracte d Curv e RDin t s110719a02 8 1 0 006-16 8 solven tblan k s110719a02 9 1 0 006-16 8 solven tblan k s110719a03 0 1 0 006-16 8 solven tblan k s110719a03 1 1 0 006-16 8 solven tblan k s110719a03 2 MB-110719-0 1 Metho d Blankw/ o I S s110719a03 3 lMB-110719-0 2 Metho d Blankw/ o I S s110719a03 4 :MB-110719-0 3 Metho d Blankw/ o I S s110719a03 5 MB-110719-0 4 Metho d Blankw/I S s110719a03 6 MB-110719-0 5 Metho d Blankw/I S .s110719a03 7 'MB-110719-0 6 Metho d Blankw/I S s110719a03 8 'LCS-110719-0 1 3 n g LC S i n TCR-84 2 s110719a03 9 LCS-110719-0 2 3 n g LC S i n TCR-84 2 s110719a04 0 'LCS-110719-0 3 3 n g LC S i n TCR-84 2 .s110719a04 1 LCS-110719-0 4 3 0 n g LC S i n TCR-84 2 s110719a04 2 .LCS-110719-0 5 3 0 n g LC S i n TCR-84 2 s110719a04 3 LCS-110719-0 6 3 0 n g LC S i n TCR-84 2 s110719a04 4 1 0 006-16 8 solven tblan k s110719a04 5 ,EC-110719-0 5 2. 5 n g Extracte d Curv e Poin t s110719a04 6 ' 1 0 006-16 8 solven tblan k s110719a04 7 GLPlO-01-01-20-00 1 DA LS S TRI P 0 000 0 s110719a04 8 GLPlO-01-01-20-00 1 Du p DA LS S TRIP 0 000 0 Duplicat e s110719a04 9 GLPlO-01-01-20-00 1 LM S DA LS S TRIP 0 000 0 La b Matri xSpik e Sl10719a05 0 GLPlO-01-01-20-00 2 DA LS S BPMW12 1 0 000 0 s110719a05 1 GLPlO-01-01-20-00 2 Du p DA LS S BPMW12 1 0 000 0 Duplicat e s110719a05 2 GLPlO-01-01-20-00 2 lo wDA LS S BPMW12 1 0 000 0 La b Matri xSpik e Lo w s110719a05 3 GLPlO-01-01-20-00 2 Hig h DA LS S BPMW12 1 0 000 0 La b Matri xSpik e H g s110719a05 4 GLPlO-01-01-20-00 3 DA LS S BPMW4 7 0 000 0 s110719a05 5 GLPlO-01-01-20-00 3 Du p DA LS S BPMW4 7 0 000 0 Duplicat e s110719a05 6 GLPlO-01-01-20-00 3 Lo wDA LS S BPMW4 7 0 000 0 La b Matri xSpik e Lo w s110719a05 7 GLPlO-01-01-20-00 3 Hig h DA LS S BPIV1W4 7 0 000 0 La b Matri xSpik e Hig h s110719a05 8 1 0 006-16 8 solven tblan k s110719a05 9 EC-110719-0 6 5 n g Bctracte d Curv e Fbin t s110719a06 0 1 0 006-16 8 solven tblan k s110719a06 1 1 0 006-16 8 solven tblan k 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 9 1

9 1 9 1 9 1 9 1 9 1 9 1 9 9 9 9 1 9 1 9 1 9 1 9 2 1 2 3 4 5 6 7 8 9 1 0 B y1 0 !1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 1

1 2 9 2 9 2 9 2 9 3 1 3 1 4 1 5 1 6 1 7 1 8 1 9 2 0 2 1 2 2 2 3 2 4 9 3 5 9 4 2 5 2 6 2 7 2 8 2 9 3 0 3 1 3 2 3 3 3 4 3 5 9 4 6 9 5 9 5 ampl e Set:SET0 1 AcqMethod:ET S 8-5 3 2 3 m

•1 " " • « . r-. ' Ini.Volum e DataRle
. ,^| ,
s i 10719 a s i 10719 a s i 10719 a s i 10719 a s i 10719 a s i 10719 a s i 10719 a s110719 a s i 10719 a s110719 a s110719 a s110719 a s110719 a s110719 a s110719 a s i 10719 a s110719 a s i 10719 a s i 10719 a s110719 a s i 10719 a s i 10719 a s110719 a s110719 a s i 10719 a s110719 a s110719 a s110719 a s110719 a s110719 a s i 10719 a s110719 a s110719 a s i 10719 a 25.00 0

25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 • 25.00 0 s i 10719 a 25.00 0 s110719 a s110719 a s i 10719 a 25.00 0

25.00 0 25.00 0 s i 10719 a 25.00 0 s i 10719 a 25.00 0 s110719 a 25.00 0 si10719 a 25.00 0 s i 10719 a 25.00 0 s i 10719 a 25.00 0 s110719 a s110719 a si10719 a s i 10719 a 25.00 0

25.00 0 25.00 0 25.00 0 s110719 a 25.00 0 si10719 a s i 10719 a r25.00 0

''25.00 0 s i 10719 a 25.00 0 s110719 a si10719 a s i 10719 a s110719 a s i 10719 a s110719 a s i 10719 a s110719 a si10719 a 25.00 0

25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 n PF0A-2.d i

Printing Date : Tuesday , Jul y19 , 201 1 Printing Time : 5:44:0 8 P M Pag e 1 o f 1 

# s110719a032-03 7 were th e LCS s an d s1107019a038-s110719a4 3 were th e metho d blanks , results tabl e wil l be update d t o reflec tth e actua l sampl e injected , mm h 7/20/1 1 

# yr-^-"^^.^^ /

### *ET S Stan V166030 5

Project : \\Winsnas01a\b2\Project^Lab_lnstrumen tData\Stan\Sta n Dat a File£\ProjectSfluorochemicalSso i Sampl e Sampl e _, , _

Nam e Sampl e I D 1 s110719a00 1 1 0 006-16 8 solven tblan k 2 s i 10719a00 2 1 0 006-16 8 solven tblan k 3 s 110719a00 3 1 0 006-16 8 solven tblan k 4 s110719a004,10006-168solventblan k 5 s110719a00 5 1 0 006-16 8 solven tblan k 6 ,s110719a00 6 1 0 006-16 8 solven tblan k 7 s 110719a00 7 -1 0 006-16 8 solven tblan k 8 s 110719a00 8 EC-110719-0 9 5 0 n g War m u p standar d 9 s i 10719a00 9 EC-110719-0 9 5 0 n g War m u p standar d 1 0 s110719a01 0 EC-110719-0 9 5 0 n g War m u p standar d 1 1 s110719a01 1 1 0 006-16 8 solven tblan k 1 2 's110719a01 2 1 0 006-16 8 solven tblan k 1 3 s110719a01 3 1 0 006-16 8 solven tblan k 1 4 s i 10719a01 4 1 0 006-16 8 solven tblan k 1 5 s110719a01 5 1 0 006-16 8 solven tblan k 1 6 ;s110719a016 , EC-110719-0 1 0. 2 n g Extracte d Curv e Fbin t 1 7 s110719a01 7 1 EC-110719-0 2 0. 5 n g B<tracte d Curv e Poin t 1 8 s110719a01 8 1 EC-110719-0 3 0.7 5 n g Bctracte d Curv e Fbin t 1 9 's110719a01 9 lEC-110719-0 4 1 n g Extracte d Curv e RDin t ,2 0 ;s110719a02 0 ,EC-110719-0 5 2. 5 n g B(tracte d Curv e Rain t 2 1 |s110719a02 1 EC-110719-0 6 5 n g Extracte d Curv e Rjin t 2 2 ,s i 10719a02 2 1 EC-110719-0 7 1 0 n g B<tracte d Curv e Poin t 2 3 5110719302 3 jEC-110719-0 8 2 5 n g Extracte d Curv e Poin t 2 4 .s110719a02 4 ; EC-110719-0 9 5 0 n g Extracte d Curv e Poin t 2 5 is110719a02 5 'EC-110719-1 0 10 0 n g Extracte d Curv e Poin t 2 6 ;s110719a02 6 'EC-110719-1 1 20 0 n g Extracte d Curv e Poin t 2 7 s110719a02 7 lEC-110719-1 2 50 0 n g Bctracte d Curv e Roin t .2 8 s110719a02 8 1 0 006-16 8 solven tblan k 2 9 ;s110719a02 9 1 0 006-16 8 solven tblan k 3 0 's110719a03 0 1 0 006-16 8 solven tblan k 3 1 ,s110719a03 1 1 0 006-16 8 solven tblan k 3 2 s110719a03 2 |MB-110719-0 1 Metho d Blankw/ o I S 3 3 s110719a03 3 MB-110719-0 2 Metho d Blankw/ o I S 3 4 s110719a03 4 MB-110719-0 3 Metho d Blankw/ o I S 3 5 ,s110719a035;MB-110719-0 4 Metho d Blankw/I S 3 6 s 110719a03 6 , MB-110719-0 5 Metho d Blan k w/ I S 3 7 's i 10719a03 7 ,MB-110719-0 6 Metho d Blankw / I S 3 8 ,s110719a03 8 LCS-110719-0 1 3 n g LC S i n TCR-84 2 3 9 ;s110719a03 9 LCS-110719-0 2 3 n g LC S i n TCR-84 2 4 0 s110719a04 0 ; LCS-110719-0 3 3 n g LC S i n TCR-84 2 4 1 s110719a04 1 LCS-110719-0 4 3 0 n g LC S i n TCR-84 2 4 2 :s110719a042iLCS-110719-0 5 3 0 n g LC S i n TCR-84 2 4 3 s110719a04 3 LCS-110719-0 6 3 0 n g LC S i n TCR-84 2 4 4 s 110719a04 4 1 0 006-16 8 solven tblan k 4 5 5110719304 5 ;B>110719-0 5 2. 5 n g Extracte d Curv e Poin t •4 6 ;s110719a046'1 0 006-16 8 solven tblan k 4 7 s110719a04 7 iGLP10-01-01-20-00 1 DA LS S TRIP O 000 0 4 8 s110719a04 8 :GLP10-01-01-20-00 1 Du p DA LS S TRIP 0 000 0 Duplicat e 4 9 .s110719a049iGLP10-01-01-20-00 1 LM S DA LS S TRIP 0 000 0 La b Matri xSpik e 5 0 s110719a05 0 'GLPlO-01-01-20-00 2 DA LS S BPMW12 1 0 000 0 5 1 :Sl10719a05 1 GLPlO-01-01-20-00 2 Du p DA LS S BPMW12 1 0 000 0 Duplicat e 5 2 :s110719a05 2 'GLPlO-01-01-20-00 2 lo wDA LS S BPMW12 1 0 000 0 La b Matri xSpik e Lo w 5 3 s110719a05 3 GLPI0-01-01-20-00 2 Hig h DA LS S BFMW12 1 0 000 0 La b Matri xSpik e H g 5 4 's110719a05 4 GLPlO-01-01-20-00 3 DA LS S BPtv1W47 0 000 0 5 5 s110719a05 5 |GLP10-01-01-20-00 3 Du p DA LS S BPMW4 7 0 000 0 Duplicat e 5 6 s110719a05 6 'GLPlO-01-01-20-00 3 Lo wDA LS S BPMW4 7 0 000 0 La b Matri xSpik e Lo w 5 7 ,s110719a05 7 |GLP10-01-01-20-00 3 Hig h DA LS S BHV1W47 0 000 0 La b Matri xSpik e Hig h 5 8 's110719a05 8 i10006-168solventblan k 5 9 s i 10719a05 9 ]EC- 1 10719-0 6 5 n g Extracte d Curv e Poin t 6 0 :s110719a060,10006-168solventblan k 6 1 s110719a06 1 .1 0 006-16 8 solven tblan k Batch:s11 (
Rac k Cod e 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 1 0 B y1 0 )719 a Tab: £

Via l Positio n 9 1 9 1 9 1 9 1 9 1 9 1 9 1 9 9 9 9 1 9 1 9 1 9 1 9 2 1 2 3 4 5 6 7 8 9 1 0 1 1 1 2 9 2 9 2 9 2 9 3 1 3 1 4 1 5 1 6 1 7 1 8 1 9 2 0 2 1 2 2 2 3 2 4 9 3 5 9 4 2 5 2 6 2 7 2 8 2 9 3 0 3 1 3 2 3 3 3 4 3 5 9 4 6 9 5 9 5 ampl e Set: v

Dat a Fil e
s i 10719 a s i 10719 a s i 10719 a s110719 a s110719 a s110719 a s110719 a s110719 a s i 10719 a s110719 a s110719 a s i 10719 a s110719 a si10719 a s110719 a s110719 a s110719 a s110719 a s110719 a si10719 a s i 10719 a s i 10719 a s i 10719 a s i 10719 a s i 10719 a s i 10719 a s i 10719 a s110719 a s110719 a s110719 a s110719 a s110719 a s110719 a s110719 a s110719 a s110719 a s110719 a s110719 a s110719 a s110719 a s110719 a s110719 a s i 10719 a s110719 a s110719 a s110719 a s i 10719 a s i 10719 a s110719 a s110719 a s110719 a s110719 a s i 10719 a s i 10719 a s110719 a s i 10719 a si10719 a s110719 a s110719 a s110719 a s110719 a 3ET0 1 AcqMethod:ET S 8-5 3 2 3 mi n PF0A-2.d i

Inj.Volum e ; (Ml ) 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 ': 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 25.00 0 : 25.00 0 25.00 0 25.00 0 ; 25.00 0 25.00 0 25.00 0 25.00 0 ;

• 25.00 0 25.00 0 i l 25.00 0 •

! 25.00 0 ! 25.00 0 " 25.00 0 ! 25.00 0 ; 25.00 0 25.00 0 25.00 0 ; 25.00 0 \ 25.00 0 25.00 0 ! 25.00 0 ; 25.00 0 25.00 0 ; 25.00 0 25.00 0 ; 25.00 0 ( 25.00 0 25.00 0 25.00 0 25.00 0 ; 25.00 0 25.00 0 ; 25.00 0 ; 25.00 0 25.00 0 25.00 0 i 25.00 0 i 25.00 0 1 25.00 0 t 25.00 0 25.00 0 25.00 0 ! Printing Date : Tuesday , Jul y19 , 201 1 Printing Time : 5:44:0 8 P M Pag e 1 o f 1

## *Sta n V166030 5

*3 MEnvironmenta l La b Result s Name : sll0719a.rd b

1 2 3 4 5 6 7 8 9 1 0 1 1 1 2 1 3 M 1 5 1 6 1 7 I S 1 9 2 0 2 1 2 2 2 3 2 4 2 5 2 6 2 7 " 2 8 2 9 3 0 3 1 3 2 3 3 3 4 3 5 3 6 3 7 3 8 3 9 4 0 4 1 4 2 4 3 4 4 4 5 4 6 4 7 4 8 4 9 5 0 5 1 5 2 5 3 5 4 55 ~ 5 6 5 7 5 8 5 9 6 0 6 1 6 2 6 3 6 4 6 5 6 6 Sampl e Nam e 

# ' s110719a00 1 s110719a00 2 Sl10719a00 3 Sl10719a00 4 s110719a00 5 s110719a00 6 5ll0719a00 7 s1l0719a00 8 Sl10719a00 9 Sl10719a01 0 Sl10719a01 1 s110719a01 2 s1107igaO1 3 s110719a01 4 s110719a01 5 Sli07l5adl 6 s110719a01 7 Sl10719a01 8 s110719a01 9 s110719a02 0 Sl10719a02 1 s110719a02 2 Sl10719a02 3 Sll0719a02 4 s110719a02 5 s110719a02 6 s1l0719a02 7 s1107i9a"02 8 s110719a02 9 Sl10719a03 0 Sl10719a03 1 s110719a03 2 s1l6719ad3 3 s1107iga03 4 s110719a03 5 s110719a03 6 Sl10719a03 7 s1l0719a03 8 s110719a03 9 s110719aO4 O Sl10719a04 1 s110719a04 2 s110719aO4 3 Sl10719a04 4 s1l0719a04 5 s110719a04 6 Sll0719a04 7 Sl10719a04 8 s110719a04 9 'sil67T9a05 d s1l0719a05 l Sll0719a05 2 Sll0719a05 3 Sl10719a05 4 s110719a05 5 Sl10719a05 6 Sl10719a05 7 Sll0719a05 8 s1l0719a05 9 Sl10719a06 0 s1l0719a06 l Sl10719a00 1 Sll0719a00 2 s110719a00 3 Sll0719a00 4 s110719a00 5 Samplal O

1 0 006-16 8 solven tblan k 1 0 006-16 8 solven tblan k 1 0 006-16 8 solven tblan k 1 0 006-16 8 solven tblan k 1 0 006-16 8 solven tblan k 1 0 006-16 8 solven tblan k t o 006-16 8 solven tblan k EC-110719-0 9 5 0 n g Wam l u p standar d EC-110719-0 9 S

O n g Wam i u p standar d EC-110719-0 9 5 0 n g Wam i u p standar d 1 0 006-16 8 solven tblan k 1 0 006-16 8 solven tblan k 1 0 006-16 8 solven tblan k 1 0 006-16 8 solven tblan k 1 0 006-16 8 solven tblan k EC-110719-0 1 0.2 n g Extracte d Cuiv e Poin t E0110719-0 2 0. 5 n g Extracte d Cun e Poin t EC-110719-0 3 0.7 5 n g Extracte d Curve Poin t EC-110719-0 4 1 n g Extracte d Curve Poin t EC-110719^) 5 2. 5 n g Extracte d Curve Poin t E O l 10719-0 6 5 n g Extracte d Curve Poin t EC-110719-0 7 1 0 n g Extracte d Curve Poin t EC-110719-0 8 2 5 n g Extracte d Curve Poin t EC-110719-0 9 5 0 n g Extracte d Cun « Poin t EC-110719-1 0 10 0 n g Extracte d Cun e Poin t EC-110719-1 1 20 0 n g Extracte d Curve Poin t EC-110719-1 2 50 0 n g Extracte d Cun e Poin t 1 0 006-16 8 solven tblan k 1 0 006-16 8 solven tblan k 1 0 006-16 8 solven tblan k 1 0 006-16 6 solven tblan k LCS-110719-0 1 3 n g LC S i n TCR-e4 2 LCS-110719-0 2 3 n g LC S i n TCR-e4 2 LCS-110719-0 3 3 n g LC S i n TCR-84 2 LCS-110719-0 4 3 0 n g LC S i n TCR-84 2 LCS-110719-0 5 3 0 n g LC S i n TCR-84 2 LCS-110719-0 6 3 0 n g LC S i n TCR-84 2 MB-110719-0 1 Metho d Blan k ««/ o I S MB-110719-0 2 Metho d Blan k w/ o I S MB-110719-0 3 Metho d Blan k w/ o I S MB-110719-0 4 Metho d Blan k w / I S MB-110719-0 5 Metho d Blan k w / I S MB-110719-0 6 Metho d Blan k w / I S 1 0 006-16 8 solven tblan k EC-110719J) 5 2. 5 n g Extracte d Curi e Poin t 1 0 006-16 8 solven tblan k GLPlO-01-01-20-00 1 DA LS S TRI P 0 OOO O GLP10-O1-O1-2O-0O 1 Du p DA LS S TRI P 0 000 0 Duplicat e GLPlO-01-01-20-00 1 LM S DA LS S TRI P 0 000 0 La b Matri xSpik e GLPlO-01-01-20-00 2 DA LS S BPMW12 1 0 000 0 GLPlO-01-01-20-00 2 Du p DA LS S BPMW12 1 0 000 0 Duplicat e GLPlO-01-01-20-00 2 lo wDA LS S BPMW12 1 0 000 0 La b Matri xSpik e Lo w GLPlO-01-01-20-00 2 Hig h DA LS S BPMW12 1 0 000 0 La b Matri xSpik e Hig h GLPlO-Ol-01-20-00 3 DA LS S BPMW4 7 0 000 0 GLPlO-01-01-20-00 3 Du p DA LS S BPMW4 7 0 OOO O Duplicat e GLP10^)1-O1-20-O0 3 Lo wDA LS S BPMW4 7 0 OOO O La b Matri xSpik e Lo w GLP1tX]1-01-20-00 3 Hig h DA LS S BPMW4 7 0 OOO O La b Matri xSpik e Hig h 1 0 006-16 8 solven tblan k EC-110719-0 6 5 n g Extracte d Cur wPoin t 1 0 006-16 8 solwn tblan k 1 0 006-16 8 solven tblan k 1 0 006-16 8 solven tblan k 1 0 006-16 8 solven tblan k t o 006-16 8 Solen tblan k t o 006-16 8 solven tblan k 1 0 006-16 8 solven tblan k Analyt e Paa k Nam e MPFO A MPFO A MPFO A MPFO A MPFO A MPFO A MPFO A MPFO A MPFO A MPFO A MPFO A MPFO A MPFO A MPFO A MPFO A MPFO A MPFO A MPFO A MPFO A MPFO A MPFO A MPi=6 A MPFO A MPFO A MPFO A MPFO A "MPFOA MPFO A MPFO A MPFO A MPFO A MPFO A MPFO A MPFO A MPFO A MPFO A MPFO A MPFO A MPFO A MPFO A MPFO A MPFO A MPFO A iijP'FO A MPFO A MPFO A MPFO A MPFO A MPFO A MPFO A MPFO A MPFO A MPFO A MPFO A MPFO A MPFO A MPFO A MPFO A MPFO A MPFO A MPFO A PFO A PFO A PFO A PFO A PFO A Sampl e Typ e

Doubl e Blan k Doubl e Blan k Doubl e Blan k Doubl e Blan k Doubl e Blan k Doubl e Blan k troubl e Blan k Unknow n Unknow n Unknow n Doubl e Blan k Doubl e Blan k Doubl e Blan k Doubl e Blan k Doubl e Blan k Standar d Standar d Standar d Standan j Standan l Standar d Standan l Standar d Standar d Standan l Standar d Standar d Doubl e Blan k Doubl e Blan k Doubl e Blan k Doubl e Blan k Unknow n Unknow n Unknow n Unknow n Unknow n Unknow n Doubl e Blan k Doubl e Blan k Doubl e Blan k Unknow n Unknow n Unknow n Doubl e Blan k Qualit yContro l Doubl e Blan k Unknow n Unknow n Unknow n Unknow n Unknow n Unknow n Unknow n Unknow n Unknow n Unknow n Unknow n Doubl e Blan k Oualit yContro l Doubl e Blan k Doubl e Blan k Doubl e Blan k Doubl e Blan k Doubl e Blan k Doubl e Blan k Doubl e Blan k Us e

Recor d



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E Analyt e Concentratio n (ng/mL | 0.0 0 0.0 0 0.0 0 0.0 0 0.0 0 0.0 0 0.0 0 N/ A N/ A (•I/ A 0.0 0 0.0 0 0.0 0 0.0 0 0.0 0 0.20 0 0.50 0 0.75 0 1.0 0 2.5 0 5.0 0 10. 0 25. 0 50. 0 99. 8 200
. 499
. 0.0 0 0.0 0 0.0 0 0.0 0 N/ A N/ A N/fi
. 

### N/ A rsl/ A 

### N/ A 0.0 0 0.0 0 

### OO O N/ A hJ/ A 11/A 0.6 b 

### 2.5 0 0.0 0 N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A Ivl/ A• 0.0 0 5.0 0 0.0 0 0.0 0 0.0 0 0.0 0 0.0 0 0.0 0 0.0 0 _*"'5^ „ Analyt e Pea l

STeTrnTnl*"'"count. ;
9.70 1 181 4 9.68 9 74 2 9.62 9 9.38 9 9.49 7 9.50 9 0.00 0 9.59 3 9.56 9 959 3 9.59 3 960 5 9.61 7 948 5 9.80 9 ^9.56 9 9.64 1 9.65 3 9.64 1 9.65 3 9.64 1 964 1 9.65 3 9.64 1 9.62 9 9.64 1 9.62 9 9.64 1 9.61 7 9.65 3 9.64 1 9.61 7 9.65 3 9.67 7 9.66 5 9.65 3 9.65 3 54 7

33 8 35 8 51 2 0 1064047 5 1026967 7 1048423 9 249 8 152 5 58 2 49 0 9 3 70868 13297 8 19458 2 25704 2 64935 1 114482 8 229559 4 544342 2 1020839 7 2147396 0 3132103 5 5050936 2 2630 6 444 0 179 0 174 1 71977 4 69616 7 68619 4 69267 0 66618 4 69000 3 0.00 0 i O 9.67 7 9.68 9 961 7 959 3 78 2

67 1 68544 6 69342 2 9,62 9 1132278 8 9,64 1 962 9 9,61 7 9.65 3 9.64 1 9.64 1 9,62 9 9,64 1 9.60 5 9.60 5 9.60 5 9.66 9 9.61 7 9,61 7 9,38 9 9,62 9 9,66 5 9,40 1 956 9 9,58 1 9,56 9 9 83 3 9,65 3 69 4

60447 1 84 3 68900 2 71805 0 69116 4 67541 6 64678 8 68721 0 64132 5 70198 2 66009 0 69229 0 64079 0 53 0 116197 3 39 4 45 9 85 5 40 2 67 6 8989 7 4639 1 I S Pea k

Nam e M8PFO A M8PFO A MSPFO A MSPFO A MBPFO A MSPFO A MSPFO A MSPFO A MSPFO A MSPFO A MSPFO A MSPFO A MSPFO A MSPFO A MSPFO A MSPFO A MSPFO A MSPFO A MSPFO A MBPFO A MSPFO A MSPFO A MSPFO A MSPFO A MSPFO A MSPFO A MSPFO A "MSPFO A 

### MSPFO A MSPFO A MSPFO A MSPFO A M8F>FC5 A MSPFO A MSPFO A MSPFO A MSPFO A MSPFO A MSPFO A 

### MSPFO A MSPFO A MSPFO A MBPFO A MBPFO A MBPFO A MBPFO A MSPFO A MSPFO A MSPFO A MSPFO A MSPFO A MSPFO A MSPFO A MSPFO A MSPFO A MSPFO A MSPFO A MSPFO A MSPFO A MSPFO A MSPFO A MSPFO A MSPFO A MSPFO A MSPFO A MSPFO A I S Pea k

Afe a (counts ) 23 1 15 8 18 3 17 2 13 2 7 3 6 4 78478 2 79727 2 79772 5 18 4 14 0 17 6 21 6 7 5 85962 5 87334 7 B6031 9 87692 3 B5081 3 B2764 2 B0724 8 B3120 2 7S537 3 79131 5 68291 9 53643 4 17 5 12 2 4 5 27 4 S2393 1 82839 2 80468 1 811B6 B 78617 1 83227 0 45 1 0 19 2 81041 9 84187 9 B1789 2 6 B B3732 5 30 0 66372 9 81257 3 83810 2 79409 1 78451 3 80469 5 772B4 6 79544 6 80386 0 S4542 2 76090 6 51 2 81923 0 13 6 11 1 23 1 15 8 1B3 17 2 13 2 I S

Concantnitto n (ng/mL | N/ A N/ A N/ A t* A N/ A N/ A (^A 3,0 0 3,0 0 3,0 0 i^ A I^ A N/ A N/ A N/ A 3,0 0 3,0 0 3,0 0 3,0 0 30 0 3,0 0 30 0 3,0 0 3.0 0 3,0 0 3,0 0 3,0 0 r^ A N/ A N/ A N/ A 3,0 0 3,0 0 3,0 0 30 0 30 0 3,0 0 N/ A t«J/ A ig/ A 3,0 0 3,0 0 

### 30 O Ni A 30 0 N/ A 3,0 0 3,0 0 3,0 0 3,0 0 3,0 0 3,0 0 3,0 0 3,0 0 

### 30 0 3,0 0 3,0 0 

### N/ A 30 0 r^ A N/ A N/ A N/ A (•J/ A 

### N/ A N/ A I S

Retentio n Tim e (min ) 96 2 9,4 0 9,5 2 9,5 6 93 3 9,5 9 9,5 0 9,5 9 9,5 7 9,5 9 9,6 2 9,4 3 9,5 B 9,5 3 95 3 9,5 8 9,6 4 96 4 9,6 4 9,6 5 9,6 4 96 4 9,6 5 9,6 4 9,6 3 9,6 4 9,6 3 9,8 0 9,5 1 9,6 2 9 , B O 96 2 96 5 9,6 8 9,6 5 9,6 4 9,6 4 96 5 OO O 9,7 0 96 2 9,5 9 9,6 3 9,3 8 9,6 3 9,6 2 9,6 5 9,6 4 9,6 3 9,6 3 9,6 4 9,6 1 9,6 1 96 2 95 8 96 2 96 2 97 0 9,6 3 9,8 1 9,4 1 96 2 9,4 0 9,5 2 9,6 6 9,3 3 Calculate d

Concentratio n (ng/mL ) N/ A N/ A N/ A N/ A N/ A N/ A N/ A 51, 4 48, 7 49, 7 W A N/ A N/ A N/ A N/ A 0,20 3 0,46 0 0,73 1 0,97 B 2,7 1 5,0 0 10, 4 24, 3 49, 2 107 , 191 , 503 , N/ A N/ A N/ A N/ A 3,1 2 2,9 9 3,0 4 3,0 4 3,0 2 2,9 5 N/ A N/ A N/ A 3,0 1 2,9 3 5,8 6 r^ A 2,5 6 N/ A 2,8 4 31 5 2,9 4 3,0 3 2.9 3 3.0 4 2.9 5 3.1 5 2.8 8 2.9 1 3.0 0 N/ A 5,1 3 N/ A N/ A N/ A N/ A N/ A N/ A N/ A Accurac y

(« l
l* A Isl/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A Ivl/ A N/ A N/ A N/ A 101 , 91, 9 97, 5 97, 8 108 , 100 , 104
. 97, 3 98, 3 107
. 95. 6 101
. N/ A N/ A N/ A rj/ A N/ A tJ/A N/ A N/ A r^ A f^ A N/ A N/ A N/ A N/ A N/ A N/ A r«i/ A 102
. t^ A N/ A N/ A N/ A N/ A N/ A ig/ A N/ A N/ A isl/ A N/ A rg/A N/ A 10 3 N/ A N/ A N/ A N/ A N/ A N/ A I^ A Ftecor d

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# n D 

# • n D 

# n E D Fil e Nam e s1l07l9a,wii r sl10719a,wif f Sl107l9a,wil l s110719a,wil T S110719a , wi n s i 10719a , Witt s110719a,wi n s110719a,wil l sl10719a,wff l Sl10719a,wil f s110719a,wii r sl10719a,wi1 T sl10719a,wif f s1107l9a,wif f sll0719a,wit T s1107l9a,wii r sll0719a,wif f sl10719a,wii r s110719a,wif f sll0719a,wi1 T sl10719a,wil t siii3719a,wif f s i 10719a , wif f s i 10719a , wi n s i 10719a , wi n s i 10719a , wi n sllT)719a,wii t s i 10719a , wil l sll0719a,wil T s110719a,wi( r s110719a,wit T s110719a,wi( r Sllb7i9a,wi f sll0719a,wit r Sl10719a,wii r Sll0719a,wif f sl10719a,wti r •sii07T9a,wfl t s110719a,wii r Sll0719a,wii r sll0719a,v»ii r s i 10719a , wil l sll0719a,wH f sil67i9a,wl S sll0719a,wit T sll0719a,wil l s110719a.wit f Sl10719a,wi n s110719a,wil T rs"lld7i9a,wi f sl10719a,wil l Sll0719a,wli r Sl10719a,wif f st10719a,wif f s1107l9a,wit r s1107l9a,wi( ( s i 10719a , wiff Sl107l9a,wif f s i 10719a , wiff s i 10719a , wiff Sll0719a,wif f s110719a,wlf l Sl10719a,wif f s110719a,wif f Sll0719a,wif f Sll0719a,wif f 

## i

Printin g Date : Wednesday , Jul y27 , Printin g Time : 10:32:2 2 A M Pag e 1 o f 2 

# : ? ^
/ 

# '>\ 9 

# a 4 ^

## •Sta n V1S6030 5

*3 MEnvironmenta l La b Result s Name : sll07l9a.rd b

6 7 6 8 6 9 7 0 7 1 7 2 7 3 7 4 75 " ' 7 6 7 7 7 8 7 9 8 0 8 1 6 2 S3 8 4 8 5 8 6 8 7 8 8 8 9 9 0 9 1 9 2 9 3 ' 9 4 9 5 9 6 9 7 9 8 9 9 10 0 10 1 10 2 10 3 10 4 10 5 10 6 10 7 10 8 10 9 

### u o 

## Trr~ i 11 2 11 3 11 4 11 5 11 6 11 7 11 8 11 9 12 0 12 1 12 2 Sampi e Nam e
Sl10719a00 6 Sl10719a00 7 Sl10719a00 8 Sll0719a00 9 5l10719a01 0 Sl10719a01 1 Sl10719a0l 2 Sl10719a01 3 Sll0719a01 4 Sl10719a01 5 Sl10719a01 6 Sl10719a01 7 Sll07l9a01 8 Sl10719a01 9 Sl10719a02 0 Sl10719a02 1 Sl10719a02 2 Sll0719a02 3 Sl10719a02 4 Sl10719a02 5 Sl10719a02 6 Sl10719a02 7 S110719a02 8 Sll0719a02 9 Sl10719a03 0 Sll0719a03 1 Sll0719a03 2 5l10719a03 3 Sl10719a03 4 Sl10719a03 5 Sll0719a03 6 Sl10719a03 7 Sl10719a03 8 Sl107l9a03 9 Sl10719a04 0 Sl10719a04 1 Sll0719a04 2 Sl107l9a04 3 Sl10719a04 4 Sl107l9a04 5 Sl107l9a04 6 Sll0719a04 7 Sl107l9a04 8 Sl107l9a04 9 Sl10719a05 0 Sl107l9a05 1 Sll0719a05 2 Sl10719a05 3 Sl10719a05 4 Sl10719a05 5 Sl10719a05 6 Sl10719a05 7 Sl10719a05 8 Sl10719a05 9 Sl10719a06 0 Sll0719a06 1 Sampl e I D

1 0 006-16 6 solven tblan k 1 0 006-16 8 solven tblan k EC-110719-0 9 5 0 n g Wanr l u p standar d EC-110719-0 9 5 0 n g Wam i u p standar d EC-110719-0 9 5 0 n g Wan n u p standar d 1 0 006-16 8 solven tblan k 1 0 006-16 8 soNen tblan k 1 0 006-16 8 soNen tblan k 1 0 006-16 8 solven tblan k 1 0 006-16 8 solven tblan k EC-110719-0 1 0,2 n g Extracte d Cun « Poin t EC-110719-0 2 0, 5 n g Extracte d Cun e Poin t EC-110719-0 3 0,7 5 rig Extracte d Curv e Poin t EC-110719-0 4 1 n g Extracte d Curv e Poin t EC-110"719-d 6 2, 5 n g Extracte d Curve Point " EC-110719-0 6 5 n g Extracte d Curv e Poin t EC-110719-0 7 1 0 n g Exiracte d Curve Poin t EC-110719-0 8 2 5 n g Extracte d Curve Poin t EC-110719-0 9 5 0 n g Extracte d Cun e Poin t EC-110719-1 0 10 0 n g Extracte d Curv e Poin t EC-110719-1 1 20 0 n g Extracte d Curve Poin t EC-110719-1 2 50 0 n g Extracte d Curv e Poin t 1 0 006-16 8 solven tblan k 1 0 006-16 8 solven tblan k 1 0 006^16 8 solven tblan k 1 0 006-16 8 solven tblan k LCS-110719-0 1 3 n g LC S i n TCR-B4 2 LOS-110719-0 2 3 n g LC S i n TCR-S4 2 LOS-110719-0 3 3 n g LC S i n TCR.S4 2 LCS-110719-0 4 3 0 n g LC S i n TCR-84 2 LCS-110719-0 5 3 0 n g LC S I n TCR-84 2 LOS-110719-0 6 3 0 n g LC S i n TCR-84 2 MB-110719-0 1 Metho d Blan k w/ o I S MB-110719-0 2 Metho d Blan k w/ o I S MB-110719-0 3 Metho d Blan k w/ o I S MB-110719-0 4 Metho d Blan k w / I S MB-110719-0 5 Metho d Blan k w / I S MB-110719-0 6 Metho d Blan k w / I S 1 0 006-16 8 solven tblan k EC-110719-0 6 2, 6 n g Extracte d Curve Poin t 1 0 006-16 8 solven tblan k GLPl(H)l-01-20-00 1 DA LS S TRI P 0 OOO O GLPlO-01-01-20-00 1 Du p DA LS S TRI P 0 OOO O Duplicat e GLPlO-01-01-20-00 1 LM S DA LS S TRI P 0 OOO O La b Matri xSpik e GLPlO-01-01-20-00 2 DA LS S BPMW12 1 0 OOO O GLPlO-Ol-01-20-00 2 Du p DA LS S BPMW12 1 0 OOO O Duplicat e GLPlO-OI-Ot-20-00 2 lo wDA LS S BPMW12 1 0 OOO O La b Matri xSpik e Lo w GLP1O-01-O1-2O-0O2 Hig h DA LS S BPMW12 1 0 OOO O U b Matri xSpik e Hig h GLP1(MI1-01-20-00 3 DA LS S BPMW4 7 0 OOO O GLPlO-01-01-20-00 3 Du p DA LS S BPMW4 7 0 OOO O Duplicat e GLPlO-01-01-20-00 3 Lo wDA LS S BPMW4 7 0 OOO O La b Matri xSpik e Lo w GLPlO-01-01-20-00 3 Hig h DA LS S BPMW4 7 0 OOO O La b Matri xSpik e Hig h 1 0 006-16 8 solven tblan k EC-110719-0 6 5 n g Extracte d Curv e Poin t 1 0 006-16 B solven tblan k 1 0 006-16 8 solven tblan k /Xnatyt e Pee k Nam e PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PF"6 A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A rpFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A Pi^O A PFO A PFO A PFO A PFO A PFO A PF"OA PFO A PFO A PFO A PFO A PFO A Sampl e Typ e

Doubl e Blan k (doubl e Blan k Unknow n Unknow n Unknow n Doubl e Blan k Doubl e Blan k Doubl e Blan k Doubl e Blan k Doubl e Blan k Standan l Standar d Standar d Standar d Standan l Standar d Standan l Standar d Standar d Standar d Standar d Standar d Doubl e Blan k Doubl e Blan k [joubl e Blan k Doubl e Blan k Unknow n Unknow n Unknow n Unknow n Unknow n Unknow n Doubl e Blan k Doubl e Blan k Doubl e Blan k Unknow n Unknow n Unknow n Doubl e Blan k Qualit yContro l Doubl e Blan k Unknow n Unknow n Unknow n Unknow n Unknow n Unknow n Unkniw n Unknow n Unknow n Unknow n Unknow n Doubl e Blan k Qualit yContro l Doubl e Blan k Doubl e Blan k Us e

Recor d



## E E E E E E E E E E E E

E

E Analyt e Concentratio n (ng/mL ) 0,0 0 0,0 0 N/ A IJ/A N/ A 0,0 0 0,0 0 OO O 0,0 0 0,0 0 0,20 0 0,50 0 0,75 0 1,0 0 2,5 0 5,0 0 lO O 25, 0 50 0 100, " 200 , 500 , 0,0 0 0,0 0 0,0 0 0,0 0 N/ A N/ A N/ A t«l/ A N/ A N/ A 0,0 0 0,0 0 0,0 0 N/ A N/ A N/ A 0,0 0 2,5 0 0,0 0 N/ A rg/ A N/ A N/ A ig/A N/ A N/ A N/ A N/ A N/ A N/ A 0,0 0 5,0 0 0,0 0 0,0 0 

# :

o^-iS?

_iAnalyt o Pea k STdTni*" " (count
. 9,65 3 960 5 9,59 3 968 1 9,59 3 9,59 3 9,61 7 958 1 9,59 3 9,60 3 9,58 1 965 3 9,65 3 9,64 1 "9,665 9,65 3 965 3 9,65 3 965 3 "9,62 9 " " " 965 3 9,64 1 9,65 3 9,62 9 9,66 3 964 1 9,62 7 9,65 5 9,66 9 9,66 1 966 1 9,65 1 9,63 1 9,63 3 9,63 5 9,61 9 9,61 2 9,66 5 9,65 3 9,62 9 9,62 9 9,66 5 9,62 9 964 2 9,62 9 9,64 9 960 9 961 1 961 9 958 1 9,61 7 961 7 9,59 3 9,62 9 9,66 3 9,66 5 1901 1

516 4 1745376 7 1744233 8 17217B6 5 1786 2 1054 8 972 7 812 2 704 9 9945 1 21428 6 30694 1 38259 9 1074199 " 169483 1 3B6074 1 969145 7 1710907 6 3157692 B 5210467 3 8450937 3 4263 7 1216 6 1070 2 716 3 100213 2 92097 9 89581 2 922576 5 B77161 2 942913 7 2470 0 2766 8 2632 9 2744 9 3773 0 3554 0 619 3 99199 6 389 8 2794 3 2677 5 39B32 4 64"245"2 51075 1 238535 9 1731990 9 40856 6 39882 5 221314 6 1682432 7 867 0 187932 5 478 7 529 9 I S Pea k

Itom o MSPFO A MSPFO A MSPFO A MSPFO A MSPFO A MSPFO A MSPFO A MSPFO A MBPFO A 

### iuiepFO A^ MBPFO A MSPFO A MBPFO A MSPFO A MBPFO A MBPFO A MSPFO A MBPFO A MSPFO A MSPFO A MSPFO A MSPFO A MSPFO A MSPFO A MSPFO A MSPFO A MSPFO A MSPFO A MSPFO A MSPFO A MSPFO A MSPFO A MSPFO A MSPFO A MBPFO A MBPFO A MSPFO A MBPFO A MBPFO A MBPFO A MBPFO A MSPFO A MBPFO A MBPFO A MSPFO A MBPFO A MSPFO A MSPFO A MSPFO A MSPFO A MSPFO A MSPFO A MSPFO A MSPFO A MSPFO A MSPFO A I S Pea k

A n a (counts ) 7 3 6 4 78478 2 79727 2 79772 5 16 4 14 0 17 6 21 6 7 5 85962 5 87334 7 B6031 9 87692 3 B50B1 3 B2764 2 80724 6 B3120 2 78537 3 7913f 5 68291 9 53643 4 17 5 12 2 4 5 27 4 82393 1 62839 2 80468 1 81186 8 78617 1 63227 0 45 1 0 19 2 81041 9 84187 9 81789 2 6 6 83732 5 30 0 86372 9 61257 3 63810 2 79409 1 76451 3 80469 5 77284 6 79544 6 B0386 0 S4542 2 76090 6 51 2 81923 0 13 6 11 1 I S

Concentratio n (ng/mL ) r^ A t* A 3,0 0 30 0 3,0 0 N/ A N/ A 

### r^ A N/ A N/ A 30 0 3,0 0 3,0 0 3,0 0 3,0 0 3,0 0 3,0 0 3,0 0 3,0 0 3,0 0 3,0 0 3,0 0 N/ A 

### rt/ A I^ A N/ A 3,0 0 30 0 3,0 0 3,0 0 3,0 0 3,0 0 N/ A N/ A N/ A 3,0 0 30 0 30 0 N/ A 3,0 0 N/ A 30 0 3,0 0 3,0 0 3,0 0 3,0 0 30 0 3,0 0 3,0 0 30 0 3,0 0 30 0 N/ A 30 0 N/ A N/ A I S

Retentio n Tim e (min ) 9,5 9 9,5 0 9,5 9 95 7 9,5 9 96 2 94 3 95 8 95 3 9,5 3 95 8 9,6 4 9,6 4 9,6 4 9,6 5 9,6 4 9,6 4 9,6 5 9,6 4 9,6 3 96 4 9,6 3 96 0 9,5 1 96 2 98 0 96 2 96 5 9,6 8 9,6 5 96 4 9,6 4 9,6 6 0,0 0 9,7 0 9,6 2 9,6 9 9,6 3 9,3 8 9,6 3 9,6 2 9,6 5 9,6 4 96 3 96 3 96 4 9,6 1 96 1 9,6 2 95 8 96 2 9,6 2 9,7 0 9,6 3 |9,8' 1 9,4 1 Calculate d

Concentratio n (ng/mL ) N/ A N/ A 52, 4 51, 6 50, 6 N/ A N/ A l* A N/ A N/ A 6,17 4 0,47 1 0,72 7 0,90 9 2,8 1 "5,17"""" " 10, 9 27, 0 51, 3 "96:s " 196 , 503 , N/ A N/ A N/ A N/ A 2,7 0 2,4 6 2,4 6 26, 3 26, 8 26, 2 tg/ A N/ A fvl/ A < 0 0,011 9 0,0087 7 It/ A 2,6 3 N/ A < 0 < 0 0,99 8 1,7 6 1,4 0 6,7 2 52, 6 1,0 9 1,0 5 5,9 2 52, 1 

### rt/ A 5,1 8 

### Ivi/ A N/ A Accurac y

N/ A N/ A f«J/ A N/ A N/ A It/ A N/ A N/ A N/ A N/ A 87, 1 94, 3 96, 9 90, 9 112 , 103 , 109 , 108 , 103 , "96, 5 98, 2 101 , N/ A N/ A "N/ A N/ A It/ A N/ A N/ A N/ A N/ A It/ A N/ A N/ A N/ A N/ A N/ A 

### rt/ A N/ A 105 , N/ A tt/ A N/ A N/ A N/ A N/ A ft/ A N/ A N/ A 'N/ A N/ A N/ A N/ A 104 , N/ A N/ A Recor d

Modifie d 

## D E D D Fil e Nam e sll0719a,wif f sll0719a,wif f sll0719a,wif f s i 10719 a wiff 

## •isiiotioawii f1 D E E E E E E E E D 

# n n n n n n n E 

# n E E E E E E E E E E E E E K 

# n n E D D E E E E E E E D D D 

# n E E Sl10719a,wif f s1l0719a,wif f sll0719a,wif f sll0719a,wif f s110719a,wif f 

### slld7i9a,wif f sll0719a,wif f sll0719a,wif f sll0719a,wif f sll0719a,wif f sll0719a,wif f sll0719a,wif f sl10719a,wif f s1107l9a,wif f sl10719a,wif f sl10719a,wH T sl10719a,wtf f s110719a,wif f s110719a,wif f s i 10719a , wiff sl10719a,wif f s110719a,wif f s110719a,wif f s110719a,wif f s110719a,wif f sll0719a,wif f sll0719a,wif f Sll0719a,wif f Sl10719a,wif f s i 10719a , wiff sll0719a,wif f Sll0719a,wif f 51l07l9a,wif f Sll0719a,wi n sl10719a,wif l Sll0719a,wif f Sll0719a,wif f sll07iga,wif f Sl107l9a,wif f sll0719a,wif f sl10719a,wif f sl10719a,wif f sl10719a,wif f s110719a,wif f 

### siib719a,wiff s110719a,wif f sll0719awif f Sl107l9a,wif f Sll0719a,wif f s i 10719a , wiff sll0719a,wif f



## Printin g Date : Printin g Time : Wednesday , Jul y27 , 201 1

10:32:2 2 A M Pag e 2 o f 2

## •Sta nV166030 5

•3 MEnvironmenta l La b Result s Name : sll0719a.rd b



# 7 0 8 0 9 0 100 Analyt e Cone
. /

I S Cone
.
Printin g Date : Wednesday , Jul y27 , 201 1 Printin g Time : 10:33:0 3 A M Pag e 1 o f 1

## *Sta n V166030 5

*3 MEnvironmenta l La b 

# •s110719a.rd b (MPFOA) : "Quadratie " Regressio n (" 1 / x " weighting) : y= -0.0015 2 x'^ 2 + 0.81 6 x+ 0.027 2 ( r= 0.9994 ) Result s Name : sll0719a.rd b



# < C O 0 3 

# < 95 : 90 : 85 : 80 : 75

- 70

- 65

- 60 : 55 : 50

- 45 : 40 : 35 : 30

- 25

- 20

- 15

- 10 : 5- : 0

- 1 0 2 0 3 0 4 0 5 0 6 0 7 0 8 0 9 0 Analyte Cone . / IS Cone . 

# 10 0 11 0 12 0 13 0 14 0 

# 15 0 16 0

Printin g Date : Wednesday , Jul y27 , 201 1 Printin g Time : 10:33:1 8 A M Pag e 1 o f 1

## •Sta n V166030 5

*3 MEnvironmenta l La b 

# Result s Name : sll0719a.rd b SampleName : "sllOTigaOO VSampleID : "1 0006-16 8 soh^ertblanl^ ' File : ••s110719a,wiff " Pea k Name : "PFOA " M3Ss{es} : "4130/369. 0amu.413.0/219. D amu,413.0/169. 0amu " Comment " Annotation : ~ npl eIndex : 1

Doubl eBlan k D.0 0ng/m L26e5

- M/ A 7/19/201 1 S:31i3 7 P

M2.6e5- | Sampl eType ; Concen t radon ; Calculate dCon e Acq
. Date : Acq
. Tine : Modified : N o Proc . Algorithm : IntelllQua n Nois e Peccentage : s o Base . Sub . Window : 1 . 0 0 Peak-Split . Factor : 4 Repor t Larges t Peak : H o Min . Pea k Height : 0.0 0 Min . Pea k Width : 0.0 0 Smoothin g width : 3 R T window : 30. 0 s e Expecte d RT : 9.5 8 m i Us e Relativ e RT : N o Int . Type : Retentio nTime : Area : Height : Star t Time : En d Time : Bas e T o B , 9.56 9 8 5 5 CO I S.iietO0 2 9.53 3 9.59 3 

# I SampleName : "s110719a002 " Sanpl eID : "1 0006-16 8 solvent blank " File : ''s110719a.wifl " Peak Name : "PFOA " Mass(es) : "413.0/369. 0amu,413.0/219. 0amu.413.CV169. 0amu " Comment ~ Annotation:" " Sanpl eIndex : 2 Sampl eType : Doubl eBlan k Concentration : 0.0 0ng/mL
___ Calculate dConc : N/ AJ.oeo i Acq
. Date : 'J/19/201 1 Acq , Time : 5:55:4 7 P M3.4e5

- Modified : N o Proc
. Algorithm : IntelliQua n• Nois ePercentage : 5 0 Base
. Sub
. Window : 1.0 0r Peak-Split
. Factor : 4 Repor t Larges t

Peak : N

o Min
. Pea k

Height : 0.0 0 Min
. Pea k

Width : 0.0 0 Smoothin g Width : 3 B TWindow : 30. 0se t Expecte dRT : 9.5 S ni l Us eRelativ eRT : N o Bas eTo Bas e Height : Star t Time : En d Time : 

### 2.12ei-00 2 9.53 3 9.59 3

0.9 B 

# -JL 16 6 33 4 

# I Sa^^>\ eName : "s110719a003 " Sanpl eID : "I D 006-16 B solvent blank " File : "s110719a.wif r Peak Name : "PFOA " M8ss(es) : "413.0/369. 0amu,413.0/219. 0amu.413.0/169. 0amu " Comment' " Annotation:" " Sampl eIndex : 3 Sampl eType : Doubl eBlan k Concentration : 0.0 0ng/n L Calculate dConc : N/ A Acq
. Date : 7/19/201 1 Acq
. Time : 6:19:5 5 P M 3.0e5

- MQII I n 

### cp s se c poi n 

# = & 

# t 3.2e 5 3,0e 5 2.Be5 2,6e 5 2.4= 5 2.2e 5 2.0e 5 l.ee S 1.6e5 1.4e5 1.2e5 I.OeS

3.2e 5

Modified : N o Proc , Algorithm : IntelllQua n- Nois ePercentage : 5 0 MQII Base
. Sub
. Window : 1.OO mi n Peak-split
. Factor : 4 Repor t Larges t

Peak : N

o Min
. Peak

Height : 0.0 0cp s Min
. Peak

width : 0.0 0se c Smoothin g Width : 3 B TWindow : 30. 0se c Expecte dBT : 9.5 8 mi n Ds eEelativ eRT : N o Int
. Type : Bas eT o Bas e Retentio nTime : 9.56 9 mi n Area : S7 8 count s Height : S.20e*00 2cp s Star t Tine : 9.S4 S mi n En dTime : 9.S8 1 mi n poi n s



### i f fr 

## fe 2.6e 5 2.4e 5 2.2e 5 2.0e 5

1.4e5 1 0 1 2 1 4 1 6 1 8 2 0 2 2 83 4 100 0 118 7 133 4 150 0 166 7 183 3 Time , mi n 

### ISampl eName : "sll0719a004 " SampleID : "1 0006-16 6 solvent blank " File : "sll0719a.wi r Pea k Name : "PFOA " Mass(es) : "413.0/369. 0a • Comment' " /^notation : '" • sampl eIndex : 4 Sampl eType : Doubl eBlan k Concentration : 0. 00ng/m Calculate dConc : N/ A Acq
. Date : 7/19/201 1 Acq
. Time : 6:44:0 4 P M Modified : Ye a Proc
. Algorithm : IntelllQua n- M < Nois ePercentage : S O Base
. Sub
. window : 1.0 0mi n Peak-Split
. Factor : 3 Repor t Larges t Peak : N o Min . Pea k Height : 0.0 0 c p Min . Pea k width : O.O O s e Smoothin g Width : 3 p ' R T Window : 30. 0 se e Expecte d RT : 9.B 3 mi n Us e Relativ e RT : N o u,413,0/169. 0 amu "

Int
. Type : Retentio nTime ; Area : Height : Star t Time : En dTime : Valle y 9
. 83 3 8989 7 CO ' 1.19e*00 4 9.70 1 9
. 91 7

1 01 21 4 1 6 I B 2 02 2 66 7 83 4 100 0116 7 133 4 150 0166 7 163 3

Time , mi n


# Printin g Date : Wednesday , Jul y27 , 201 1 Printin g Time : 10:36:2 5 A M Pag e 1 o f 4 6

# *Sta nV166030 5 *3 MEnvironmenta lLab Result s Name : sll07l9a.rd b 

# I Sarrpl e Name : "s110719a00S " Sanpl e ID : "1 0 006-16 8 solven tblanJi TFile : "s110719a.wif r Pea k Name : "PFOA " Mass(es) : "413.0/369. 0 amu,413.0/219. 0 amu,413.0/169. 0 amu ' Comment" " Annotation:" " Sampl e Index : 5 Sanpl e Type : Doubl e Blan k Concentration : o.o o ng/m L Calculate d Conc : N/ A Acq . Date : 7/19/201 1 g , Acq . Tine : 7:08:1 5 P M Modified : Proc . Algorithm : Nois e Percentage : Base . Sub . Windo w Peak-Split . Fact o H o ntelllQ u 5 0 1.0 0 4 Repor t Larges t Peak : H o Min . Pea k Height : Min . Pea k Width : Smoothin g Width : R T Window : Expecte d RT : Us e Relativ e RT : Int . Type : Retentio nTime : MQI I mi n
0.0 0 cp s 0,0 0 se c

• 3 30. 0 9.5 8 H o Valle y 9.65 3 Area : 4639 1 C O Height : 5 Star t Time : En d Time : 43e+00 3 9.52 1 9.78 5 mi n

mi n lint s cp s mi n mi n point s



# a ^ 5.5e 4
5.De 4

4.0e 4

3.0e 4
2.5e 4
2.0e 4
1.5e 4

I Sampl e Name : "s i 10719a00 rSampl e ID : "1 0 006-16 8 solven tWank " File:"fi110719a.wif r Pea k Name : "PFOA " Mass(es) ; "413.0/369. 0 amu,413.0/219. 0 amu.413.0/169. 0 amu " I Commen t~ Annotation:" " 1 0 1 2 1 4 1 6 B3 4 100 0 116 7 133 4 Time , mi n

Sampl e Index : Sampl e Type : Concentration : Calculate d Conc : Acq . Time : Doubl e Blan k 0,0 0 ng/n L N/ A 7/19/201 1 7:56:3 1 P M Ye s Modified : Proc . Algorithn : IntelliQua i Nois e Percentage : 5 0 Base . Sub . Window : 1.o o Peak-Split . Factor : o Repor t Larges t Peak : N o Min . Pea k Height : o.o o Min . Pea k Width : o.o o Smoothin g Width : 3 R T Window : 30. 0 I Expecte d RT : 9.6 1 I Us e Relativ e RT : N o Int , Type : Retentio nTime : Area : Star t Time : En d Time : Valle y 9.60 5 516 4 c c 9,52 1 9.62 9 mi n

unt s cp s fflin Bi n 

# &

s 7000, 0

500D. O 4000. 0

.0 - 1-1 6 

### ^W*VA*- ^ 

# [ Sampl e Name : "8ll0719a006 " Sampl e ID : "1 0 006-16 8 solven tblanl^ ' File : "s i 10719a. w Pea k Name : "PFOA " Mass(es) : "413.0/369. 0 amu.413.0/219. 0 amu.413.0/169. 0 amu " Commen t~ Annotation : — Sampl e Index : Sampl e Type : Concentration : Calculate d Conc : Acq . Date : Acq . Time : Modified : Proc . Algorithm : Nois e Percentag e 6 Doubl e Blan k 0.0 0 ng/m L N/ A 7/19/201 1 7:32:2 4 P M N o IntelllQua n- M Q 5 0 Base . Sub . window : i.o o mi n Peak-Split . Fac t sr : 4 Repor t Larges t Peak : N o Min . Pea k Heigh t Min . Pea k width : Smoothin g Width : B T Window : Expecte d RT : Us e Relativ e RT : Int . Type : Retentio n Time : Area : Height : Star t Time : En d Tine : 0.0 0 cp s 0.0 0 se c 3 p o 30. 0 se c 9.5 8 mi n N o Valle y 9.65 3 mi n ,901 1 count s 2.S4e+00 3 cp s 9.49 7 mi n 9.71 3 mi n

6000.0 - 40DO.0 - 2000.0 - 0.0 - [^13,2 3 ^13.4 5 \ ^14.7 1

Sampl e Name : "sll0719a00B " Sampl e ID : ~EC-110719^ 9 5 0 n g War m u p standard " File : "s i 10719a.wi r Pea k Name : "PFOA " Mass(es) ; "413.0/369. 0 amu.413.0/219. 0 amu.413.0/169. 0 amu " Comnwnt: " /^notation:'" ' sampl e Index : B sampl e Type : Onknow n concentration : N/ A Calculate d Conc : 52. 4 ng/m L Acq . Date : 7/19/201 1 Acq . Time : 8:20:3 9 P M Modified : N o Proc . Algorithm : IntelllQua n - MQI I Nois e Percentage : 5 0 Base . Sub . window : i.o o mi n Peak-Split . Factor : 4 Repor t Larges t Peak : H o Min . Pea k Height : o.o o cp a Min . Pea k Width : o.o o ae c Smoothin g Width : 3 point s R T Window : Expecte d RT : Us e Relativ e RT ; int . Type : Retentio n Time : 30. 0 se c 9.5 8 mi n N o Valle y 9.59 3 Bi n Area : 1745376 7 coun t Height : Star t Time : En d Time ; .39e+oo e cp s 9.41 3 mi n 10.14 5 mi n

1 0 1 2 14 1 6 634 100 0 116 7 133 4 Time , mi n


# Printin g Date : Printin g Time ; Wednesday , Jul y27 ,

10:36:2 7 A M Pag e2o f 4 6

## *Sta n V166030 5 

# *3 MEnvironmenta lLab Result s Name : sll0719a.rd b 

# I Sampl e Name : "s1107l9a009 " Sampl e ID : "EC-110719-0 9 5 0 n g War m u p standard " File : "sl10719a,wif r Pea k Name : "PFOA " Hass(es) : "413.0/369. 0 amu.413.0/219. 0 amu,413.D/169. D amu " Comment" " Annotation:" " Sampl e Index : 9 Sampl e Type : Unknow ng c a Concentration : N/ A Calculate d Conc : 51. S ng/ m Acq . Date : 7/19/a0l l Acq . Time : 8:44:5 5 P M2.2e6

- Modifled : N o Proc . Algorithm : Intelli Q Nois e Percentage : Base , Sub . window : Peak-split . Factor : Repor t Larges t Peak : Min . Pea k Height : Min . Pea k width : Smoothin g width ; R T Window : 3 Expecte d BT : Us e Relativ e BT : N o Int . Type : Valle y Retentio nTime : 9.58 1 ni n Area : 1744233 8 count : Height : a.39e-»00 6 cp s star t Time : 9.41 3 ni n En d Tine : 10.12 1 mi n

Sampl e Type : Concentration : Calculate d Conc : Acq . Date : Acq . Time : Modified : Proc . Algorithm : Nois e Percentag e Doubl e Bla n 0.0 0 N/ A 7/19/201 1 9:33:1 7 P M N o IntelllQua n 5 0 Base . Sub . Window ; 1.0 0 Peak-Split . Factor : 4 Repor t Larges t Peak : N o Min . Pea k Heigh t Min . Pea k width ; Smoothin g Width : R T Window : Expecte d BT : ua e Relativ e RT : Int . Type : Retentio nTime ; Area : Height : Star t Time : En d Time : 0.0 0 0.0 0 3 30. 0 S 9.S B m H o Valle y 9.59 3 m 1786 2 cou n 2.19e-f00 3 c 9.44 9 m 9.79 7 m Sampl e Name : "sll0719a010 " Sampl e ID : "EC-110719-0 9 5 0 n g War m u p standard " Rle;"6l10719a.wif r Pea k Name : "PFOA " Mass(es) : "4130/369. 0 aim,413.0/219. 0 amu.413.0/16g. O amu " Comment" " Annotation:" " 

### 2.3e 6 2.2e 6 2.1e 6 2,De6 1.9e6 Sam p Sam p e lnde > e Typ e Concentration : Cal c Acq . Acq . late d conc : Date : Time : Modified : Pro c Algo r Nois e Perce r Bas e Pea k thm :

tag e 1 0 Unknow n H/ A 50. 8 7/19/201 1 9:09:0 6 P M N o IntelllQua n s o Sub . Window : i.o o Split . Factor : 4 Repor t Larges t Peak : M o Min . Pea k Height ; Min . Pea k Width ; Smoothin g Width : R T Window : Expecte d RT : •s e Relativ e RT ; Int . Type ; Retentio n Time : Area : 17 2 Height : 2 Star t Time : En d Tine : 0 0 3 30. 0 9.5 8 N o Valle y 9.59 3 1786 5 .3oe-f00 6 9.40 1 10.12 1 0 0 C

se c mi n

ni n count s cp s mi n mi n cp s se c point s 1.8 (



### 1.7e6

- 1.6e6

- 1.5e6 ' 1.4e 6 1.3e6

- 1.2e 8 1.1e6 1.0e6 g.OeS

6.0e5 ' 7,0e 5 6.De5

- 5,De5

- 4.0e5

- 3.0e 5 2.0e5

- I.OeS

0. 0

Sarr^leName:"s110719a011 " Sampl e ID : "1 0 006-16 8 solven tblank " File : "s110719a.wifr ' 

# • Pea k

Name : "PFOA " Mass(es) : "413.0/369. 0 amu.413.0/2l9.0amu,413.O/169. 0 amu ' Comment" " Annotation:" " Sanpl e Index : 1 1 Doubl e Bla n ng/m L Sampl e Name : "s110719aOi rSanpl e ID : "1 0 006-16 8 solven tblanl^ ' File : "sl10719a.wif r 

### Peak Name : "PFOA " Mass(es) : "413,0/369. 0a • Comment" " Annotation:" " Sampl eIndex : 1 2 Sampl eType : Doubl eBlan k Concentration : 0.0 0ng/mL Calculate dConc : K/ A u.413,0/2ig. O amu,413,0/169. 0 amu "

Acq . Date : Acq . Time : Modified ; Proc . Algorithn : Nois e Percentag e 7/I9/2Q1 1 9:57:2 8 P M Ye s IntelllQua n- 5 0 Base . Sub . Window : 1.0 0 m Peak-Split . Factor : 2 Repor t Larges t Peak : N o Min . Pea k Heigh t Min . Pea k Width : Smoothin g width ; R T Window : Expecte d RT : Us e Relativ e RT : Int . Type ; Retentio n Time : Area ; Height : Star t Time : En d Time : MQI I
n
0.0 0 cp a 0.0 0 ae c 3 30. 0 se c 9.6 2 mi n N o Valle y 9.61 7 mi n 0S4 8 count s 1.17et00 3 cp s 9.52 1 mi n 9.76 1 Bi n point s


# fr



# 1 7500

- 7000

-

6000

-

5000

- 4500

- 4000

- 3500

- 3000

- 2500

- 2000

- 1500

- 1000

- 

### I LI ..Jl4 ( ^ I 

# fm> H

Printin g Date : Wednesday , Jul y27 , 201 1 Printin g Time : 10:36:2 9 A M Pag e3 o f 4 6

## *Sta n V166030 5 

# *3 MEnvironmenta lLab Result s Name : sll0719a.rd b

I Sampl e Name : "s1l0719a013 " Sanpl e ID : "1 0 006-16 8 soNen tblank " File : "6l10719a.wifl ~ Pea k Name : "PFOA " Mass(es) : "413.0/369. 0 amu,413.0/219. 0 amu.413.0/169. 0 I Comment" " Annotation:" " Sampl e Index : sampl e Type : Concentration : Calculate d Conc : Acq . Date : Acq . Tine : Modified : Proc . Algorithm : In ! Hois e Percentage : Base . Sub . Window : Peak-Split . Factor : Repor t Larges t Pea k Min . Pea k Height : Min . Pea k Width : Smoothin g Width : B T Window : Expecte d RT : Us e Relativ e RT : Int . Type : Retentio nT : Area : Height : Star t Tine : En d Time ; Doubl e Blan k 0.0 0 ng/ i H/ A 7/19/201 1 10:21:3 7 P M

Modified : R T Window ; Expecte d RT : Us e Relativ e B T int . Type ; Retentio nTime : Area : Height : Star t Time ; En d Tine ; Ye s 30. 0 9.6 1 No Manua l 9. 6 0 3 704 9 c c 7.79et00 2 9.46 1 9.70 1 se c

mi n

mi n unt s mi n mi n 

# • Sampl e Name : "s110719a014 " Sanpl e ID : "1 0 006-16 8 solven tblanl^ ' File ; "s110719a,wi r PeakNanw : "PFOA " Mass(es) : "413,0/369. 0 amu.413.0/2l9. D amu.413.0/169. 0 amu " Commen tTM Annotation : TM Sampl e Index : 1 4 sampl e Type ; Concentration : Calculate d Conc : Acq . Date : Acq . Time : Modified : Proc . Algorithm : Hois e Percentag e Doubl e B l 0.0 0 N/ A 7/19/201 1 10:45:4 6 Ye s an k

ng/m L

P M IntelllQua n- MQI I 5 0 Baae . Sub . window : l.o i Peak-Split . Fac t sr : 2 Repor t Largea t Peak ; H o Min . Pea k Heigh t Min . Pea k width : Smoothin g width : R T Window : Expecte d BT : Us e Relativ e BT : Int . Type : Retentio n Time : Area ; Height : Star t Time : En d Time : mi n
0. 0 0 cp s 0.0 0 se c 3 30. 0 9.5 9 H O Valle y 9.59 3 812 2 C O .7064-00 3 9.47 3 9.67 7 poi n

se c mi n

ni n unt s cp a mi n mi n s



# s

j j P 850 0 800 0

600 0 550 0 500 0 450 0 400 0

300 0 250 0 200 0 150 0 100 0 500

- 1.00 , 

# \Ww W

1667 183 3



# • SampleName : -s110719a015 " Sampl eID : "1 0 006-16 8 solven t blank " File : -s110719a.wit r Peak Name : "PFOA " Mass(e$) : "413.0/369. 0 amu.413.0/219. 0 amu.413.0/169, 0 Comment " Annotation:" " Sampl eIndex : 1 5 Sampl eType : Doubl eBlan k Concentration : o.0 0 ng/m L Calculate dConc : N/ A Acq . Date : 7/19/201 1 Acq . Time : 11:09:5 5 P M 0.20 0 0.17 4 7/19/201 1 11:34:0 4 P M Ye s IntelllQua n 5 0 1.0 0 ak : N o

0.0 0 0.0 0 3 30. 0 E 9.S 8 m ng/m L

ng/m L

- MQI I mi n
cp s point s ! C I n 1.5e 4

1.4e 4
1.3e 4
1.2e 4
1.1e 4
1.0e 4 Sampl e Name : "sl10719a016* ' Sanpl e ID : "EC-11071fr^3 1 0. 2 n g Extracte d Curv e Poin rFile : "s110719a.wif f Pea k Name : "PFOA " M8ss<es} : "413.0/369. 0 amu,413.0/219. 0 anui.413.0/169. 0 amu " Comment " Annotation : ~ Sampl eIndex : 1 6 Sampl eType : Standar dgg { Concentration : Calculate dconc : Acq , Date : Acq , Time : Modified :

Algorithm : Nois e Percentag e Base . Sub . windo i Peak-Split , Factor : Repor t Largea t Pea k Pea k Height : Pea k Width : Smoothin g Width : Expecte dBT : Ua eRelativ eRT : N o Type : valle y SDtHl.O

Retentio nTime : 9.58 1 mi n^ Area : 9945 1 count s & annn D Height : i.4ae-t-O0 4 cp a^ a r t Time : 9.42 5 mi n' M EndTime : 9,79 7 mi no 7000. 0
6000.0

- 5000. 0
4000. 0
3000. 0
2000. 0
1000. 0 

# ^ %WUH,"/.i<WWJ»4 / 

# *^HM':
.
133 4 150 0 166 7 183 3


# Printin g Date : Wednesday , Jul y27 , Printin g Time : 10:36:3 0 A M 

# Pag e4 o f 46

## *Sta n V166030 5 

# *3 MEnvironmenta lLab Result s Name : sll07i9a.rd b

I Sanpl e Name ; "sll0719aOi rSanpl e ID : "EC-110719-0 2 0.5n g Extracte d Cure o Poin fRle : "s110719a.wiff " Pea k Name : "PFOA " Mass(es) : "413.0/369. 0 8mu.413.0/219. 0 amu,413,0/169. 0 amu " I Comment" " Annotation:" " Sampl e Index : Sampl e Type : Concentration : Calculate d Conc : Acq . Date : Acq . Time : Modified : Proc . Algorithm : Nois e Percentag e 1 7 standar d 0.50 0 ng/m L 0. 4 7 1 ng/m L 7/19/201 1 11:58:2 0 P M Ye s IntelllQua n- MQI I S O Baae . Sub . window : i.o o mi n Peak-Split . Fact e r : 3 Repor t Larges t Peak : N o Min . Pea k Heigh t Min . Pea k Width : Smoothin g Width : R T Window : Expecte d RT : Us e Relativ e BT : Int . Type : Retentio nTine : 0.0 0 cp s 0.0 0 ae c 3 point s 30. 0 se c 9.6 5 mi n H o Valle y 9.65 3 mi n Area : 21428 6 count s Height : star t Time : En d Time : .ooe+00 4 cp s 9.50 9 mi n 9.91 7 ni n

O.OI K II Sampl e Index : Sampl e Type : Concentration : Calculate d Con c Acq . Date : Acq . Time : I B standar d 0.75 0 0.72 7 7/20/20 1 12:22:3 0 ng/m L

ng/m L A M elllQu j

N o I Sampl e Name : "S i 10719a018 - Sanpl e ID : "EC-110719-0 3 0.7 5 n g Eirtracte d Curv e Poin TFile : "sll0719a.Mf r Pea k Name : "PFOA " Uass(e$} : "413.0/369. 0 arTXi.413.0/219. 0 amu,413.0/169. 0 amu " I Comment" " Annotation:" "

4.2e4 4.0e4 3.6e4

- 3.6e4

- 3.4e4 3.2e4 3.0e4 2.8e4 2.6e4 2.4e4

- 2.2e4

- 2.De 4 1.8e4

- 1.6e 4 Modified ; Proc
. Algorithm ; Hois ePercentage : Base
. Sub
. Window : Peak-Split
. Factor : Repor t Largea t

Peak : Min
. Pea k

Height : 0 Min
. Pea k

Width : 0 Smoothin g Width : 3 R TWindow : 30. 0 Expecte dRT : 9.6 5 Us eRelativ eRT : N o point s

In t Ret
. Heigh t Type ; Bas eTo Bas e Time : 9.65 3 mi n 30694 1 count s 4.12e'»00 4 Cp a : 9.53 3 mi n

10.12 1 mi n

1. 4

16.4 8 1 7 5 4
\

20.5 8 

# r Sampl e Name : "sl10719a019 " Sampl e ID : "EC-110719-0 4 1 n g Ertracte d Curv e Poin TFile : "sl10719a.wi r Pea k Name : "PFOA " MaS5(es) : "413,0/369. 0 amu.413.0/219, 0 amu.413.0/169, 0 anuj " Comment" " Annotation:" " Sanpl e Index : Sanpl e Type : Concentration : calculate d Conc : Acq
. Date : Acq
. Time : 0.90 9 7/20/201 1 12:4 6 :4 7 A M Modified : Proc . Algorithm : IntelllQu i Nois e Percentage : Baae . Sub . Window : Peak-Split . Repor t Largea t Pea k Min . Pea k Height : Min . Pea k Width : Smoothin g width : R T Window : Expecte d RT : Us e Relativ e RT : Sampl e Name : "s i 10719a020 " Sanpl e ID : "EC-11071W1 5 2. 5 n g Extracte d Cun/ e Poin rRle : "s i 10719a.wi r Pea k Name : "PFOA " Mass(es} : "413.0/369. 0 amu,413.0/219. 0 amu,413.0/169. 0 amu " Comment" " Annotation:" " Sampl e Index : Sampl e Type : Concentration ; Calculate d con c Acq . Date : Acq . Time : Modified ; Proc . Algorith m 2 0 Standar d 2. 5 0 ng/m L 2.8 1 ng/m L 7/20/201 1 1:11:0 0 A M N o IntelllQua n- M Q Nois ePercentage : s o Base
. Sub
. window : 1.o o mi n Peak-Split
. Factor : 4 Repor t Larges t

Peak : N

o Min
. Pea k

Height : 0.0 0 cp s Min
. Pea k

Width : 0.0 0 se c Smoothin g width : 3 poi n R TWindow : 30. 0 se e Expecte d RT : 9.5 8 mi n Us e Relativ e BT : M o Int . Type ; Bas e T o Bas e Eetentio n Time : 9.66 5 mi n Area : 107419 9 count s Height : l. 4 8e-»oo s cp s Star t Time : 9.48 5 ni n En d Time : lO.20 6 mi n 1.4e 5
1.3e5

- 1.2e 5
1.1e 5
1,0e5

- 9.0e4 '

6.0e 4
5.0e4

- 4.0e4
3.0e4
2.0e4

- 1.0e 4 0.0 ' 1. U


# - 1

16 8 33 4 50 1 66 7 63 4 100 0 116 7 133 4 150 0 166 7 183 3 Time , mi n


# Printin g Date ; Printin g Time : Wednesday , Jul y27 , 201 1

10:36:3 2 A M Pag e 5 o f 4 6

# *Sta nV166030 5 *3 M Environmenta lLab Result s Name : sll0719a.rd b

• SampleName : "sl10719a02 r SampleID:-EC-110719-0 6 5 ng Exacte dCuw ePoinf IPeak Name : "PFOA " Mas${es) : "413.0/369. 0amu,413,0^219, 0amu.413.0/169. 0amu " • Comment" " Annotation : " " Sampl eIndex : 2 1 Sampl eType : Standar d Concentration : 5,0 0ng/mL76B 5 Calculate dConc : 5,1 7 ng/m L-i.ooo

Acq
. Date : 7/20/201 1 2.5e5

- Acq
. Time : 1:35:1 0A H 2.4e5

- Modified : N o 23e5 ' Proc
. Algorithn : IncelliQua n- MQII Noia ePercentage : 5 02.2e5 ' Base
. Sub
. Window : j.o o mi n. , _ Peak-Split
. Factor : 4 ^'^ ^ Eepor t Larges t

Peak : N

o 2.0e5

- Min
. Pea k

Height : 0.0 0cp s Min
. Pea k

Width : 0.0 0se c 1,9e5

- : Smoothin g Width ; 3 point s .0.5
. ! B TWindow : 30. 0se c iExpecte dRT : 9.5 8 mi n1.7e5 ' Us eRelativ eRT : N o , „ ^ 1.6e5 ' j Int
. Type : Valle y1_5e5
. Retentio nTime : 9.65 3 ni n„ Area : 189483 1 count s g- 1.4e5

- Height : 2.62e*oo 5 cp s > : , . , . Star t Time : 9.43 7 mi nf ^••' " EndTime : 10.12 1 mi ni1.2e5 l.le S I.OeS 9.0e4 8.0e4 7.0e4 6.0e4

- 5,0e4 4.0e4 3,0e4 2.0e4 1.0e 4 1.1 6 

# A
. . 24 16 8 33 4

• SampleName : "s110719a023 " SampleID : "EC-11D719-0 8 2 5 n g ExtractedCun/ ePoin f • Peak Name : "PFOA " Mass(es) : "413.0/369. 0amu,413.0/219. 0amu,413.0/169. 0amu " Sanpl eIndex : 2 3 Sanpl eType : Standar d Concentration : 25. 0ng/n L1.3e6

- calculate dconc : 27, 0ng/mL Acq , Date : 7/30/201 1 1-3«6 Acq , Time : 2:23:3 2A M ^2e6

- Modified ; N o 1,2e6 Proc
. Algorithm : IntelllQua n- MQII Nois ePercentage : 5 0^^^

- Base , Sub
. Window : l.O D mi n^^e6 • Peak-Split
. Factor : 4 Repor t Larges t

Peak ; N

o 1.0e6 ' Min
. Pea k

Height ; 0.0 0cp s -_^

- Min
. Pea k

Width : 0.0 0se c 9.M S Smoothin g Width : 3 point s 9.0e 5 R TWindow : 30. 0se c Expecte dRT : 9.5 8 ni n8.5e 5 Ua eRelativ eRT : N o flOeS Int
. Type : Valle y7.5e 5 Retentio nTime : 9.65 3 mi n^ Area : 969145 7 count s & '•"" ' Height : i.3ie-f00 6 cp s ^6 5e 5 Star t Time : 9.47 3 mi n' 5 En dTine : 10.15 7 mi n£6.0e5

-

~ 5.5e 5 5,0e5

- 4.5e5

- 4.0e5

- 3,5e 5 30e 5 2,5e 5 2,0e 5 1.5e5 I.OeS 5.0e 4 0. 0
. , . , .

16 8 33 4 Fiie:"a110719a.wi r
9.6 5



# [ ^ ^
. E 6 8 1 0 50 1 66 7 83 4 File:"s110719a.wi r

9.6 6



## L 6 8 1 0 50 1 667 B3

4 , -^"-v

- . - 1 21 4 1 6 1 B 202 2 10001167 133 4 15001667 183 3 Time , mi n

1 21 4 1 6 1 8 202 2 10001167 133 4 15001667 183 3 Time , m n ISampl eNan%:"sl10719a02 r Sanpl eID : "EC-110719^ 7 1 0ng ExtractedCurvePdn f 1 Peak Name ; "PFOA " Mass(es) : "413.0/369 0amu.413.0/219. 0amu,413.0/169. 0amu " • Comment" " Annotation:" " Sampl eIndex : 2 3 Sanpl eType : Standar d Concentration : 10. 0ng/mL calculate dconc : 10. 9 ng/mL52e 5 Acq
. Date : 7/20/201 1 Acq
. Time : 1:59:2 0A M5.0e 5

4.8e 5 Modified : N o Proc
. Algorithn : IntelllQuan
. - MQII4.6e 5 Noia ePercentage : 5 o Base
. Sub , Window : 1.0 0mi n** " Peak-Split
. Factor : 4 4.2e 5 Repor t Larges t

Peak : H

o Min
. Pea k

Height : 0.0 0cp s ^-Oe S Min , Pea k

Width : 0.0 0se c 33^ 5 Smoothin g Width : 3 point s R TWindow : 30. 0se e3-6e5 Expecte dRT ; 9.5 8 ni n-. 5 Us eRelativ eRT : N o 3.2e 5 Int
. Type : Bas eT o Bas e,n^ c Retentio nTime : 9.65 3 mi ng ^'^ ^ Area : 3B6074 1 count s fr 28e 5 Height : S.36e-f00 5 cp s ^ Star t Time : 9.47 3 mi n'i S 2.6e 5 EndTime : 10.31 4 mi n| 24e 5 2.2e 5 2.0e 5 1,Be5

- 1.6e5

- 1.4e5

- 1.2e5

- 1.0e5

- 8.0e4

- 6.0e4

- 4,0e4

- 2.0e4

- 24

16 8 33 4

• SampleName : "Bn0719a024

- Sarrpl eID : "EC-110719-09 5 0ng ExtractedCurvePoinf IPeak Name : "PFOA " Ma5s(es} : "413.0/369. 0amu.413.0/219. 0amu,413.0/169. 0amu " 1 Comment" " Annotation:" " Sampl eIndex : 24 Sampl eType : Standar d Concentration : 50. 0ng/m L2.2e 6 Calculate dConC : 51. 3 ng/m L Acq
. Date : 7/20/201 1 2.1e 6 Acq
. Time : 2:47:4 9 A M 2.0e6

- Modified : N o Proc
. Algorithn : IntelllQua n- MQI I1.9e6

- Hois ePercentage : 5 o Base
. Sub , Window : 1,0 0mi n1.8e6

- Peak-Spllt
. Factor : 4 Repor t Larges t

Peak : N

o 1.7e6

- Mln
. Pea k

Height : 0.0 0cp s Min
. Pea k

Width ; 0.0 0ae c 1.6e6

- Snoothin g width : 3 point s R TWindow : 30. 0se e1.5e6

- Expecte dRT : 9.5 8 mi n Us eRelativ eRT : H o ^^'^^ ' Int
. Type ; Valle y Retentio nTime : 9.65 3 mi n„ ,56 6 Area : 171D907 6 count s gHeight : 2.22e+oo 6 cp s > : 1 ie 6 Star t Time : 9.46 1 mi n% En dTime : 10.15 7 mi nJ• ) oe 6 B 9.0e 5 8.0e 5 7.0e 5 6.0e 5 5.0e 5 4.0e 5 3.0e 5 2.0e 5 l.Oe S 24

16 8 33 4 File:"sl10719a.wif r
9,6 5



# \ 6 8 1 0 50 1 66 7 83 4 File:"s110719a-wiff

'

9.6 ^



# \ 6 8 1 0 50 1 66 7 83 4 .^•^ ^ 

### 1 21 4 1 6 1 8 202 2 10001167 133 4 15001667 183 3 Time , mi n

1 21 4 1 8 1 8 202 2 10001167 133 4 15001667 183 3 Time , mi n


# Printin g Date : Wednesday , Jul y27 , Printin g Time : 10:36:3 4 A M Pag e6 o f 4 6

## *Sta n V166030 5 

# *3 M Environmenta lLab Result s Name : sll0719a.rd b 

# [ Sampl e Name : "s1l0719a02S ' Sampl e ID : 'EC-110719-1 0 100 n g Extracte d Cun/ e Poin TFUe : 's1107l9a.wTf r Pea k Name : "PFOA " Mass(es) : "413.0/389. 0 amu,413.0/219. 0 amu,413.0/169, 0 amu " Comment" " Annotation:" " Sampl e Index : 2 5 Sampl e Type : Standar d Concentration : loo . calculate d Conc : 96. 5 Acq . Date : 7/20/201 1 ng/m L ng/m L Acq . Time ; 3:12:0 1 A M Modified : H o Proc . Algorithm : IntelllQua n- MQI I Nois e Percentage : 5 0 Base . Sub . window : i.o o Peak-Split . Factor : 4 Repor t Larges t Peak : N o ni n
Min . Pea k Height : o.o o cp s Min . Pea k Width : o.o o se c Smoothin g Width : 3 R T Window : 30. 0 Expecte d RT : 9.5 8 Us e Relativ e RT : H o Int . Type : Valle y Retentio nTime : 9.62 9 Area : 3157092 8 c Height : 3.96e»00 6 Star t Time : 9.44 9 En d Time : 10.14 5 poi n se c mi n

mi n unt s cp s mi n mi n 

# ^

£ 3.6e 6 3.4e 6 3.2e 6

2 8e 6 2.6e 6 2.4e 6

2.0e 6 1.Be 6

1-0e6

- S.Oe S 6.0e 5 4.0e 5 2.0e5

-

ng/m L ng/m L 

# I Sanpl eName ; "sl10719a02 r San^ eID : "EC-110719-1 2 50 0 ng ExtractedCuiv ePoin TFile : "s110719a.»fi r Peak Name : "PFOA " Mass(es) : "413.0/369, 0 amu.413.0/219, 0 amu,413.0/169. 0 amu " CofTwnent" " Annotation:" " Sanpl eIndex : 27 Sampl eType ; S t a : Concentration ; Calculate dConc : Acq
. Date : 7/ 2 Acq
. Time : 4:00:3 0 A M Modified : N o Proc
. Algorithm : IntelliQua i Noia ePercentage : s o Base
. Sub
. Window : 1.0 0 Peak-Split
. Factor : 4 Repor t Larges t

Peak : N

o Min
. Pea k

Height : 0.0 0 Min
. Pea k

Width : O.O O Smoothin g width : 3 R TWindow : 30. 0 1 Expecte dRT : 9.5 8 I Us eRelativ eRT : H o Int
. Type : Valle y Retentio nTime : 9.64 1 i Area : 8450937 3 CO I Height : 8.25e-»00 ei star t Time ; 9.44 9 i EndTime : 10.19 4 i

2.5e 6 2.0e 6 1.5e6 1.0e6

- 5.0e5

- 0.0 - 

# I Sampl eName : "s110719a026 " Sanpl eID : "EC-110719-1 1 20 0 n g ExtractedCun/

ePoin T Peak Name : "PFOA " Mass(es) : "413.0/369. 0 amu.413.0/219, 0 amu,413.0/169. 0 amu ' Comment" " Annotation:" " Sampl eIndex : 26 Sampl eType : Standar d Concentration : 200
. ng/m L Calculate dConc : 196
. ng/m L Acq
. Date : 7/20/201 1 Acq
. Time : 3:36:1 7 A M 5.5e6 ' Modified : H o Proc . Algorithm : IntelllQua n - MQI I Nois e Percentage : 5 0 Baae . Sub . Window ; 1.0 0 Peak-Split . Factor ; 4 Repor t Largea t Peak ; N o ni n
Min . Pea k Height : o.o o cp s Min . Pea k Width : o.o o se c Smoothin g Width : 3 R T Window ; 30. 0 Expecte d RT : 9.5 8 Us e Relativ e RT : K o Int . Type : Valle y Retentio n Time : 9.65 3 Area : S210467 3 c Height : S.96e-f00 6 star t Time : 9.46 1 En d Time : 10.19 4 point s mi n

aunt s cp s mi n mi n 

# S

S



# r Sarrpl e Name : "sll0719a02e " Sampl e ID : "1 0 006-16 8 solven tblanl TFile ; "s i 10719a.wi r Pea k Name : "PFOA " Mass(es) : "413.0/369. 0 amu,413.0/219. 0 amu,413.Q/169. 0 amu ' Commen t~ /^notation : ~ Sampl eIndex : 2 8 Sampl eType : Doubl eBlan k Concentration : o.o o ng/m L Calculate dConc ; N/ A Acq
. Date ; 7/ 2 0/201 1 7000 ' Acq . Time ; 4:24;4 1 A M Modified : Ye a Proc . Algorithm : IntelllQua n Noia e Percentage ; 5 0 Base . Sub . window : 1.0 0 i Peak-split . Factor : 1 Repor t Largea t Peak : H o Min . Pea k Height : o.o o Hln . Pea k width : 0.0 0 Smoothin g Width : 3 R T Window : 30, 0 se i Expecte d BT : 9,5 8 mi ] Us e Relativ e RT : N o 6500

-

int . Type : Retentio n Time : Area ; Height : Star t Time : En d Time : Valle y 9.65 3 4263 7 C 6.00e+0D 3 9.52 1 9.80 9

150 0 166 7



# Printin g Date ; Printin g Time ; Wednesday , Jul y27 , 201 1

10:36:3 5 A M 

# Pag e7 o f 4 6

## *Sta n V166030 5 

# *3 M Environmenta lLa b Result s Name : sll07l9a.rd b 

# I Sarrpl eName : "s110719a029 " Sanpl eID : "1 0 006-16 8 solvent blan) ^ File ; "s110719a,wit r Pealc Name ; "PFOA " Mass(es) : "413.0/369. 0 amu.413.0/219. 0 amu,413.0/169. 0 amu " Comment

~ Annotation:" " sampl eIndex : 2 9 Sampl eType : Doubl eBlan k Concentration : 0,o o ng / Calculate dConc : N/ A Acq . Date ; 7/20/201 1 Acq
. Time : Modified : Proc . Algorithm : Noia e Percentag e H o IntelllQua n 5 0 Base . Sub . Window : 1.0 0 Peak-Split . Factor : 4 Repor t Largea t Peak : H o Min . Pea k Heigh t Min . Pea k Width : Smoothin g Width : R T Window : Expecte d RT : Ua e Relativ e RT : Int . Type : Retentio nTime : Area : Height : Star t Time : En d Tine : 0.0 0 0.0 0 3 n MQ I

n
cp a ae c 30. 0 se c 9.5 8 m N o n

Bas e T o Bas e 9.62 9 m 216 5 cou n n

s .66e-f00 3 cp s 9.53 3 m 9.78 5 m n

n po i Sampl e Name : "s i 10719a030 " Sampl e ID : "1 0 006-16 8 solven tblank " File : ~s110719a.wi r Pea k Name : "PFOA " Mass(es) : "41 3 0/369. 0 amu.413.0/219. 0 amu,4l3.0/169. 0 amu " Commen t~ Annotation:" " Sampl eIndex ; 3 0 Sampl eType ; Doubl eBlan k Concentration : Calculate d Conc : Acq . Date ; Acq . Time : 0.0 0 N/ A 7/20/201 1 5:13:0 2 A M ng/m L

Modified : Ye a Proc . Algorithm : IntelllQua n Nois e Percentage : 5 0 Base . Sub . Window ; 1.0 0 Peak-Split . Factor : 2 Repor t Larges t Peak ; N o Min . Pea k Height : o.o o Min . Pea k Width : o.o o Smoothin g Width : 3 R T Window : 30. 0 s e Expecte d RT ; 9.6 5 m i Us eRelativ eBT : M o cp s

se c point s

Int
. Type : Betentio n' Area : Height : star t Tin e EndTime ; Valle y 9.65 3 mi n 1070 2 count s 1.ooe+00 3 cp s 9.52 1 ni n 9.8S 1 ni n 3000 - 2500 - 2000 - 1500 - 1000 - 1.1 6 12.5 2 ^12.6 1

.12.9 4 16.5 8



# ' ^w£i^l£ ) 

# I Sanpl eName : "s i 10719a03l " Sanpl eID : "1 0 006-16 8 solvent blanl ^ File ; "s110719a.wi r Peak Nanne : "PFOA " Mass(es} : "413.0/369. 0 amu.413.0/219. 0 annu,413.0/169. 0 amu ^ Comment" " Annotation:" " Sampl eIndex : 3 1 Sampl eType ; Doubl eBlan k Concentration : 0.0 0 ng/m L Calculate dconc : N/ A Acq
. Date : 7/20/201 1 650 0 Acq . Time : 5:37 : 1 2 A M Modified : Ye s 600 0 Proc . Algorithm : IntelllQua n- MQI I Nois e Percentage : 5 0 Base . Sub , window : 1,0 0 mi n 550 0 Peak-Split . Factor : 1 Repor t Larges t Peak : N o Min . Pea k Height : 0.0 0 cp s 500 0 Min . Pea k Width : 0.0 0 se c Smoothin g Width : 3 • point s B T Window : 30. 0 se c 450 0 Expecte d RT : 9. 5 8 mi n Us e Relativ e RT : N o Type : Area : Height : . a9e-f00 2 9.53 3 9.77 3

2500 - 2000 - 150 0 

# «m»/JWif» '

2 4 6 8 1 0 1 2 1 4 1 6 16 8 33 4 50 1 66 7 83 4 100 0 116 7 133 4 Tin^
. mi n Sampl e Inde x Sampl e Type : Concentratio r Calculate d C c Acq . Date : Acq . Tine ; Modified : R T Window : Expecte d RT : Us e Relativ e Int . Type : 3 2 Unknow n H/ A nc ; 2.7 0 n g 7/20/201 1 6:01:2 5 A M Ye s 30. 0 se c 9.5 8 mi n RT : N o Manua l Retentio n Time : 9.62 7 mi n Area : Height : 100213 2 count s l,15e-»00 5 cp s I Sampl e Name : "s110719a032 " Sanpl e ID : "LCS-110719-0 1 3 n g LC S I n TCR-842 " Rle : "6ll0719a.wif f Pea k Name : "PFOA " Mass(es) : "413.0/369. 0 amu,413.0/219. 0 amu,413.0/169. 0 amu " I Commen t~ Annotation : ~
1.15e5 1.10e5 1.05e5 I.OOe S g.S0e 4 9.00e4 e.50e4 B.00e 4 7.50e4 7.00e4

- 6.50e4 \6.00e4 IS.50e

4
: 5.00e4 4.50e4 4.00e4 3.50e4 3.00e4 2.50e4

- 2.00e4

- 1.50e4

- 1.00e 4 5000,0 0 0.00



# Printin g Date : Wednesday , Jul y27 , 201 1 Printin g Time : 10:36:3 7 A M Pag e 8 o f 4 6

# *Sta nV166030 5 *3 M Environmenta lLa b Result s Name : sll0719a.rd b



# • SampleName:"s110719a033 " Sanpl eID: ' Peak Name : "PFOA " Mass(es) : "413.0/369, 0 Comment" " Annotation:" " Sampl eIndex : 3 3 Sampl eType : Unknow n Concentration : H/ A Calculate dConc : 2.4 6 ng/m L Acq
. Date : 7/20/201 1 Acq
. Time : 6:2S:4 0A M Modified : R T Window : Expecte d RT : Us e Relativ e RT : Int . Type : Retentio nTime : Ye a 30. 0 9.5 8 N o Manua l 9.65 5 Area : 92097 9 c Height : 1 Star t Time : En d Time : 136*00 5 9.12 5 10.09 7 

### 1,10e5 : 1.05e5

- 1.00e5 9.S0e 4 9.00e4 8.50e4 B.00e 4 7.50e4 7.00e4 ' 6,50e4

- I6D0e4 f 5,50e4 S 5,DDe4

- 4.50e4 4.00e4 3.50e4 3.00e 4 2.50e4

- 2.00e4 1.50e 4 1.00e 4 5000.00 : 0.00

- y^- ^ 

# I SampleName ; "sll0719a035 " Sarrpl eID; ' Peak Name ; "PFOA " Mass{es) ; "4130/369
. Comment" " /Annotation:" " Sampl eIndex ; 3 5 Sampl eType : unknow n Concentration : N/ A Calculate dConc : 26. 3 ng/m L Acq . Date ; 7/20/201 1 Acq . Tine : 7:14:0 5 A M Ye a
N o 

### Modified : R TWindow : Expecte dRT : Us eRelativ eBT : Int
. Type : Manua l Betentio nTime : 9.66 1 Area : 922575 5 o Height : l.05e*00 6 Star t Tine : 9.07 7 En dTime : 10.14 5 'LCS-110719-0 4 3 0 n g LC S i n TCR-842 " File : "s110719a.wif r D amu.413.0/219. 0 amu,413.0/169. 0 amu "



### 1.00e6 9.S0e5 9.00e5

- 8.S0e5 8.00e 5 7.50e 5 7.00e5

- 6.50e 5 6.00e 5 5,50e5

- 5.00e S 4.50e 5 4.00e 5 3,50e5

- 3.00e 5 2.50e5

- 2.00e 5 1.50e5 : I.OOe S 5,00e4

- 0.00 

# ] I Sampl e Name : "s110719a034 " Sampl e ID : "LCS-110719-0 3 3 n g LC S i n TCR-B42 " File : "s110719a.wifl " Pea k Name ; "PFOA " Mass(es) : "413.0/369. 0 amu,413,0/219. 0 amu.413.0/169. 0 amu " I Comment " Annotation : " Sampl e Index : 3 4 Sampl e Type : Unknow n Concentration : N/ A Calculate d Conc : 2,4 6 ng/m L Acq . Date ; 7/20/201 1 Acq . Time : 6:49:5 0 A M Modified : Ye s R T Window : 30. 0 ae c Expecte d RT : 9.5 8 mi n Us e Relativ e RT ; N o Int . Type : Manua l Retentio n Time : 9.66 9 mi n Area : 89581 2 count s Height ; 1.05e-»OO S cp s Star t Tine ; 9.13 7 mi n En d Time : 10.07 3 mi n 

# 1

t 1 I.OSeS
1,00e5

- 9.50e4 < 9.b0e4

- 8.50O4

- 8,00e4

- 7.50e4

- 7.00e4

- 6,50e 4 6,00e4

- 5,50e4

- 5.00e4

- 4.50e4

- 4.00e4

- 3.50e4

- 3,00e4

- 2.50e4

- 2.000 4 1,50e 4 1.00e 4 5000.0 0 0 00

- 1.1 9

\ Sampl e Name : "sll0719a036 - Sanpl e ID : "LCS-110719-0 5 3 0 n g LC S i n TCR-842 " File : "s110719a.wi r Pea k Name : "PFOA " Mass{es) : "413.0/369. 0 amu,413.0/219. 0 amu,413.0/169. 0 amu " I Comment" " Annotation ; '" " 

### Sampl eIndex : 3 6 Sampl eType : Unknown Concentration : N/ A Calculate dConc : 25. 8 Acq . Date : Acq . Time : Modified : R T Window : Expecte d RT ; Ua e Relativ e R T Int . Type : Retentio n Time : 7/20/201 1 7:38:1 6 A M Ye a 30. 0 se c 9.5 8 mi n N o Manua l 9.66 1 mi n Area : 877161 2 count s Height : Star t Time : En d Time : 9.74e-f00 5 cp a 9.10 1 mi n 10.17 0 mi n 

### 9.5e5

- 9.0e5

- 8.5e5

- 8.0e5

- 7,5e 5 7.0e5

- 6.5e5

- e.OeS

5.5e 5 5,0e5

- 4.5e 5 4.0e 5 3.5e 5 3.0e 5 2.5e S 2.0e S I.SeS

1.0e5 5.0e4 0. 0 

# 1

Printin g Date : Wednesday , Jul y27 , 201 1 Printin g Time : 10:36:3 8 A M Pag e9 o f 4 6

## *Sta nV166030 5 

# *3 M Environmenta lLab Result s Name : sll0719a.rd b 

# I Sarrpl eName : "s110719a037 " Sanpl eID ; Peak Name : "PFOA " Mass(es) : "413.0/369 , Comment ~ Annotation; " Sampl eIndex : 3 7 Sampl eType : Unknown Concentration : N/ A Calculate dConc ; 26. 2ng/n L Acq
. Date : 7/20/201 1 Acq
. Time : 8:02:3 7 A M Modified : Ye s R Twindow : 30. 0se c Expecte dRT : 9.5 8 mi n Us eRelativ eRT : N o Int
. Type : Manua l Retentio nTine : 9,65 1 ni n Area : 942913 7 count s Height : 1. 08e+ 006 cp s star t Time : 9.08 9 mi n En dTine : 10,14 5 mi n LCS-110719-0 6 3 D n g LC S i n TCR-84 rFile : "sl10719a,wifr "

, 0 annu,413.0/219. 0 amu,413.0/169. 0 amu "



### 1.05e6

- 1.00e6

- 9,50e5

- 9.00e5

- B.SOe S e-00e 5 7,50e 5 7.00e 5 S.SOe S e.OOe S 5.50e 5 5.00e5

- 4.50e 5 4.00e5

- 3.50e 5 3-00e5 2.50e5 ' 2-00e 5 1.50e5 I.OOe S 5.00e4

- 0.00J

- 

# 1 1 SampleName : "sll0719a039 " SampleID: " Peak Name ; "PFOA " Mass(es) : "413.0/369. 0 Comment '" • Annotation: " Sampl eIndex : mpl e Type ; Concentration : Calculate d Conc : Acq . Time : Modified : R T Window : Expecte d BT : Us e Relativ e BT : Int . Type : Retentio nTine ; Area : Height : Star t Tine ; En d Time : Doubl e Blan k 0. 0 0 ng/m L M/ A 7/20/201 1 8:SO:5 1 A M Ye s

H o Manua l 9.63 3 mi n 2766 8 count s 

### 3.01e-f00 3 cp s 9.13 7 mi n 9.94 1 mi n 9000

- 8500

- 8000 7500

- 7000 6500 12,33
. 

# I Sampl eName : ~s110719a038 " SampleID : Peak Nanw : "PFOA " Mass(es) : "413.0/369
. Comment " Annotation:" " Sampl eIndex : 3 8 Sampl eType : Doubl eBlan k Concentration ; O.O O ng/mL Calculate dconc : N/ A Acq
. Date ; 7/20/201 1 Acq
. Tine : 8:26:3 9 A H UB-110719-0 1 Metho d Blankw/ o IS " File : "s110719a.wi r

. 0 amu.413.0/219. 0 amu.413.0/169. 0 amu "

Modified : R T Window : Expecte d RT : Us e Relativ e R T Int . Type : Retentio n Tine : Area : Height : Star t Tine : En d Time : Ye s 30. 0 9.5 8 N o Manua l 9.63 1 2470 0 c 3 S8e-f00 3 9.19 7 9,85 7 

### 1.10o4

- 1.05e 4 1.00e4

- 9500.00

- 9000.00

- 6500.00

- 8000.00

- 7500.00

- 7000.00

- 6500.00

- §

- 6000.0 0 I " 5500,00 I5000.00 4500.00

- 4000.00

- 3500.00

- 3000,0 0 2500,0 0 2000-00 1500.00 1000.0 0 500.00

- 0.00

- 

# Sm^m^M-J

166 7 183 3 

# I SampleName : "s i10719a040 " Sarrpl eID : Peak Name : "PFOA " Mass(es) : "413.0/369
. Comment" " Annotation : TM Sampl eIndex : 4 0 "MB-110719-0 3 Metho d Blankw/ o IS " File ; "6l10719a.wiff " 0 amu.413.0/219. 0 amu.413.0/169. 0 amu " Sampl e Type : Concentration ; Calculate d Con c Acq . Date : Acq . Time : Modified : R T Window : Expecte d RT ; Ua e Relativ e R T Int . Type : Retentio n Time : Area : Height : Star t Time : En d Time : Doubl e Blan k 0.0 0 ng/m L N/ A 7/20/201 1 9:15:0 3 A H Ye a 30. 0 ae c 9.5 8 mi n N o Manua l 9.63 5 mi n 2632 9 count s 2.57e*00 3 Cp s 9.14 9 min ' 9.80 9 mi n 900 0 850 0

750 0 700 0 650 0 600 0 5500 -

- 500 0 t4500 -
^ 4000 - 3500 - 3000 - 2500 - 2000 - 1500 - 

### 1000

- 500 ' 

# A' ^ .,1,66^ 27 1 ^- ^

33 4 50 1 6S 7 83 4 100 0 11S 7 133 4 150 0 Time , mi n


# Printin g Date : Wednesday , Jul y27 , 201 1 Printin g Time : 10:36:4 0A M Pag e1 0o f 4 6

## *Sta nV166030 5 

# *3 M Environmenta lLab Result s Name : sll0719a.rd b 

# I Sarrpl eName ; ~s110719a041 " SampleID; " Peak Name : "PFOA " Mass(es) ; "4130/369. 0 Comment TMAnnotation:" " Sampl eIndex : 4 1 Sampl eType : Unknow n Concentration : N/ A Calculate dconc : < o Acq
. Date : 7/20/201 1 Acq
. Time : 9:39:1 7 A H Modified : R T Window : Expecte d RT : Us e Relativ e RT : 

### Ye s 30, 0 9.5 8 N o Int
. Type : Retentio nT Area : Height : Star t Time : EndTime : Manua l 9.61 9 mi n 2744 9 count s 3.0Be-fO0 3 Cp a 9.19 7 mi n 9.77 3 ni n 950 0 900 0 8500 : 8000 - 7500 - 7000 - 6500 - 6000 - 5500 - 5000 - 4500 - 4000 - 3500 - 3000 - 2500 - 2000 - 150 0 100 0 500 - 

# •\J i %4^*VM W

Sampl e Name : "sl10719a043 " Sampl e ID; ' Pea k Name : "PFOA " Mass(es) : "4130/369
. 

### Comment ~ Annotation:" " Sampl eIndex : 83 4 10001167 133 4 Time , mi n

sampl e Type : Concen t ra t i on : Calculate d Conc ; Acq . Date : Acq . Time : Modified : R T Window : Expecte d RT : Us e Relativ e RT : Int . Type : Retentio nTime : Area : 3 Height ; Star t Time : En d Time : Unknow n 

### N/ A 0.0087 7 ni 7/20/201 1 10:27:4 3 A

M Ye a

N o Manua l 9,66 5 mi n 3554 0 count s 3 .65e<»00 3 cp s 9.18 5 mi n 9.83 3 mi n 'MB-110719-0 6 Metho d Blankw / IS " File ; "s110719a.wif r D amu.413.0/219, 0 amu,413.0/169, 0 amu "



### 1.10e4

- 1-05e4

- 1,00e4 ' 9500.00 9000-00

- 6500-00

- 8000.00

- 7500.0 0 7000.00

- 6500.0 0 f

- 6000,0 0 r 5500.00 \5000.00 4500.00

- 4000.0 0 3500.00 3000.00 2500.00

- 2000.0 0 1500.00 1000.00

- 500.00 0.00 

# Ai r I 6. 1 S J 

# I SanpleNan!w:"s110719a042 " Sanpl e ID : "MS-110719-0 5 Metho d Blankw/IS " File:"sll0719a-witr ' Pea k Name : -pFOA " Mass(es) : "413.0/369. 0 amu.413.0/219. 0 amu.413.0/169. 0 Comment" " /Annotation : ~ Sampl e Index : Sampl e Type : Concentration : Calculate d Conc : Acq . Date : Acq . Time : Modified : R T Window : Expecte d RT : Us e Relativ e R T 4 2 Unknow n N/ A 0.011 9 7/20/201 1 10:03:2 8 Ye s 30, 0 9.5 8 N o 

### Int
. Type ; Manua l Retentio nTime : 9.61 2 Area : 3773 0co i Height : 3,17e-f00 3 star t Time : 9,13 7 EndTime : 9.79 7

ISampl eName ; "sll0719a044 " Sanpl eID : "1 0006-16 8 solvent blanl TFile : "s i10719a.wif

r IPeak Name ; "PFOA " Mass(es) ; "413.0/369. 0amu.413.0/219, 0amu.413.0/169. 0amu " IComment

" Annotation : " " sampl eIndex : 4 4 sampl eType : Doubl eBlan k Concentration : 0,0 0ng/mL Calculate dConc : N/ A Acq
. Date : 7/20/201 1 Acq
. Tine : 10:51:5 7 A M Modified : N o Proc . Algorithm : IntelllQua n Nois e Percentage : S O Base . Sub . window : i.o o Peak-Split . Factor : 4 Repor t Largea t Peak : N o Min . Pea k Height ; o.o o Min . Pea k Width : 0,0 0 Smoothin g Width : 3 B T Window : 30. 0 si Expecte d RT : 9.5 8 m . Us e Relativ e RT ; N o cp s

Int . Type : Retentio n Time : Area : Height : star t Time : En d Time : Bas e T o Bas e 9.65 3 ni n 619 3 count s 

### 7.9ee+00 2cp s 9.49 7 mi n 9.77 3 mi n 8000 : 7500 : 7000

- 650 0 6000

- 5500

- 5000 450 0 4000 3500

- 3000 250 0 2000

- 1500

- 1000

- 500

- 1.1

2 

# n 

# ^ w

# u«*o* *

Printin g Date : Wednesday , Jul y27 , 201 1 Printin g Time : 10:36:4 2A M Pag e1 1 o f 4 6

## *Sta n V166030 5 

# *3 MEnvironmenta lLab Result s Name : sll07l9a.rd b
Sampl e Name : "s110719a045 " Sanpl e ID : "EC-110719-0 5 2. 5 n g Extracte d Cun/ e Poin fFile : "sll0719a.wit r Pea k Name : "PFOA " Mass(es) : "413.0^69. 0 amu,413.0/219. 0 arTXJ.413.0/169. 0 amu " •Comment" " /Annotation ; Sanpl eIndex : 4 5 9,6 3 1,3e5 Sanpl e Type : Q C Concentration : 2.S O Calculate d Conc : 2.6 3 Acq . Date : 7/20/201 1 ng/m L ng/m L Acq , Time : 11:16:1 2 A M Modified : H o Proc . Algorithm : IntelllQua n - MQI I Nois e Percentage : 5 0 Baae . Sub . window : i.o o Peak-Split . Factor : 4 Repor t Larges t Peak : N o Min . Pea k Height : o.o o Min . Pea k Width : o.o o Smoothin g Width : 3 mi n
cp a se c poi n R T Window : 30. 0 ae c Expecte d RT : 9.5 8 rain Ds e Relativ e RT : N o Int . Type : Bas e T o Bas e Retentio nTime : 9.62 9 mi n Area ; 99199 6 count s Height : 1
. 37 e+ 00 S cp s star t Time : 9.48 5 mi n EndTime : 10
. 14 5 mi n

Int . Type : Retentio nTime : Area : Height ; Star t Time : En d Tine : Bas e T o Bas e 9.66 5 mi n 2794 3 count s 3.92et00 3 cp s 9.50 9 mi n 9.82 1 mi n 

# I Sanpl e Narrw : "s11D719a04 rSampl e ID : "GLPl0-01-01-20-00 1 DA LS S TRI P 0 OOOO " File ; •s110719a.wif r Pea k Name : "PFOA " Mass{es) ; "413.0/369. 0 amu.413.0/219. 0 amu.413,0/169, 0 amu ' Comment " /Annotation:" " Sampl e Index : 4 7 Sampl e Type : Unknow n Concentration : H/ A Calculate d Conc : < 0 Acq
. Date : 7/20/201 1 Acq
. Tine : 12:04:4 2 P M Modified : N o Proc
. Algorithm : IntelllQua n Nois ePercentage : 5 0 Base
. Sub
. window : i.o o Peak-Split
. Factor : 4 Repor t Larges t

Peak : N

o Min
. Pea k

Height : 0.0 0 Min
. Pea k

Width : 0.0 0 Smoothin g width ; 3 R TWindow ; 30. 0 s e Expecte dRT : 9.5 8 m i Us eRelativ eRT : H o 

# I Sampl e Name : "s i 10719a046 " Sanpl e ID : "1 0 006-16 8 solven tblank " File ; "s i 10719a.vwf r Pea k Name ; "PFOA " Mass<es) : "413,0/369, 0 amu,413,0/219. 0 amu,413,0/169. 0 amu ' Commen t• " Annotation:" " Sampl e Index : 4 6 Doubl e Blan k 0.0 0 ng/m L N/ A 7/20/201 1 600 0 11:40:2 7 A

M Sampl e Typ e Concentration : Calculate d con c Acq . Date : Acq . Time : Modified : Ye s Proc . Algorithm : IntelllQua n - MQI I Nois e Percentage : Baae , Sub . window : Peak-Split
. Factor : Repor t Largea t

Pea k Min
. Pea k

Height ; 1.0 0

Min . Pea k widt h Smoothin g widt h R T Window ; Expecte d RT : Us e Relativ e R T Int . Type : Retentio n Tine : Area ; Height : star t Tine : En d Time : 0 3 30. 0 9.6 3 K o Valle y 9.62 9 0 0
se c

mi n

mi n 3 8 9 8 count s 6.71e+00 2 9.54 5 9.77 3 cp a

Bi n mi n

Sanpl e Namn : "sll0719a048 " Sanpl e ID : "GLP10-01-01-2(M}0 1 Du p DA LS S TRI P 0 000 0 Duplicate ' Pea k Name : "PFOA " Mass(es) : "413.0/369. 0 amu.413.0/219. 0 amu.413.0/169. 0 amu" ^ Comment" " Annotafion:" " Sampl eIndex : 4 8 Sampl eType : Unknow n Concentration : N/ A calculate dConc : < o Acq
. Date : 7/20/2 0 Acq , Time : 12:28:5 ' Modified : N o Proc . Algorithm : I n Nois e Percentage : Baae . Sub . window : Peak-Split . Factor : Repor t Larges t Pea k Min . Pea k Height : 1 Min . Pea k width : Smoothin g Width : R T Window : 30. 0 Expecte d RT : 9.5 6 Ua e Relativ e RT : » o Int . Type : Bas e T o B , Retentio n Time : 9.62 9 Area : 2677 5 Height : 3.74e-f0 0 3 cp a Star t Time : 9.54 5 mi n En d Time : 9.S4 5 mi n

100 0 116 7 Time , mi n


# Printin g Date : Wednesday , Jul y27 , Printin g Time : 10:36:4 3 A M Pag e 1 2 o f 4 6

## *Sta n V166030 5 

# Result s Name : sll0719a.rd b

*3 MEnvironmenta lLa b

• SampleName : "sl10719a049 " Sampl eID : "GLP10^J1-0 1 • Peak Name : "PFOA " Mass(es) : "413.0/369. 0amu,413.0 Q 1 Comment

~ Annotation:" " Sanpl eIndex : 4 9 Sanpl eType : Onknow n Concentration : N/ A5.0o4 Calculate dConc : 0.99 ang/mL Acq
. Date : 7/20/201 1 4.8o4 Acq
. Time : 12:53:1 3 P M^- ^ Modified : Ye a R TWindow : 30. 0ae c Expecte dRT : 9.5 8 mi n Ds eRelativ eRT : H o Int
. Type : Manua l Retentio nTime : 9.64 2ni n Area : 39832 4 count s Height : 4.95e-»00 4 cp a Star t Time : 9.13 7 Bi n En dTime : 10.24 2mi n 4.4e4 4.2e4 4.0e4 3.8e4 3.6e4

- 3.4e4 3-2e 4 3.0e4 2,8e4

" , 2,6e4 w 2.4e4 1 2,2o4 2.0c4 1.8e 4 1.6e 4 1.4e 4 1.2e4

- 1.0e 4 8000. 0 6000. 0 4000.0

- 2000, 0

• SarTpleName:"s110719a051 " SampleID; "GLP10-01-0 1 IPeak Name : "PFOA " Mass(es) : "413,0^69. 0amu.413,D C sampl eIndex : 5 1 Sampl eType : Unknown Concentration : N/ A6.5e4

- Calculate dConc : 1.4 0ng/mL Acq
. Date : 7/20/20 H Acq
. Time : 1:41:4 2P M6.0e4 Modified : Ye s R Twindow : 30. 0se e Expecte dBT : 9.5 8 mi n Us eRelativ eRT : N o Int
. Type : Manua l Retentio nTime : 9.64 9 mi n Area : 51075 1 count s Height : e.49e-fO0 4 cp s star t Tine ; 9.16 1 ni n EndTine : 10.24 2ni n 5.5c4 5.0e4 4.5e4

- 4.0e4

- £3.5e4

- 1 3.0e4

- 2.5e4

- 2.0e4

- 1.5e 4 1.0e 4 5000, 0 2CH)0 1 LM

S DA LS S TRI P0OOO O La b Matri xSpike " 9. 0amu,413.0/169, 0amu " 9
.

1



### 1.02. ,

20-00 19. 0a 1 8



### - « 7.0 1 

# L^
. y^ ^ FUe:"s110719a.wiff

5 4

12.5 2

24 6 8 1 01 21 4 16 8 33 4 50 1 66 7 83 4 10001167 Time , mi n 2Du p DA LS S BPMW12 1 0OOO

O Duplk^ate " mu,413.0/169.0amu " 9 ,

1.1 4 File;"sl10719a.wif r
55

12.3 8 

# * 

# .W ^

24 6 8 1 01 21 4 16 8 33 4 50 1 66 7 83 4 10001167 Time, mi n 1 6

133 4



# - ^ 1 6 133 4 1 8 20

15001667

/^VMM,,.^*^^^^^^ ^ 1 8 2 0 15001667 ^*V.w-* ^

2 2 163 3

2 2 163 3 • SampleName : "sll0719aD50 " SampleID : "GLPl0-01-01-20-00 2DA LS S BPMW12 1 00000 " File : "s110719a.wi r IPeak Name : "PFOA " Mass{es) : "413.0/369. 0amu,413.0/219. 0amu.413.0/169, 0amu " 1 Comment

" Annotation : ~ Sampl eIndex : 5 0 Sampl eType : Unknowngg j Concentration : N/ AH»;-4J Calculate dConc ; 1.7 6 ng/mLo.SM

Acq
. Date : 7/20/201 1 Acq
. Time : 1:17,2 5 P M8,0e4

- Modifled : Ye s R TWindow : 30, 0se c Expecte dRT : 9.5 8 mi n Us eRelativ eRT : N o Int
. Type : Manua l Retentio nTime : 9.62 9 mi n Area : 64245 2count s Height : 8.57e-f00 4 cp s Star t Time : 9.11 3 mi n EndTime : 10.09 7 mi n 7.5e4

- 7.0e4

- 6.5e4 8.0e4

- 5.5e4 5,0e4

^4.5e4
. 1 4.0e4 ' 3.5e4 3.0e4

- 2.5e4

- 2.0e4 1.5e 4 1.0e4

- 5000.0

- 0. 0 1.1 9



# . A
. 24 6 8 1 01 2 16 8 33 4 50 1 66 7 63 4 1000 Time , mi n 13.00 1 4 1167

• SampleName : "sll0719a05 r SampleID : "GLPlO-01-01-20-002lo w DA LS S BPMW12 1 0OOO

O La b Matri xSpik eLow" File : "s110719a.wif r IPeak Name : "PFOA " Mass(es) : "413.0A369. 0amu,413.0/219. 0amu.413.0/169. 0amu " 1 Comment " Annotation : ~ Sampl eIndex : 5 2 Sampl eType : Unknowngg ^ Concentration : N/ A- j Calculate dConc ; 6.7 2ng/mL•^•"" ' Acq
. Date : 7/20/201 1 Acq
. Time : 2:05:5 4 P M28e 5 Modified : Ye s B TWindow : 30, 0ae c Expecte dRT : 9.5 8 mi n Us eRelativ eRT : N o Int
. Type : Manua l Betentio nTime : 9.60 9 mi n Area : 238535 9 count s Height : 3.05e»00 5 cp a Star t Time : 9.12 5 mi n EndTime : 10.10 9 mi n 2.6e 5 2.4e 5 2.2e 5 2.0e 5 1.8e5 1 1.6e5 1 1.4e5 1.2o5

- 1.0e5

- B.0e4

- 6.0e4

- 4,0e4 2,0e4 

## '•. ^"
. ^J ^

24 6 6 1 01 2 16 8 33 4 50 1 66 7 63 4 1000 Time , mi n 1 4 1167 

# ^y^^^'^^^z ^

1 6 1 8 20 133 4 15001667



### __35S—clLH-jil ^2

7 1 6 1 8 2 0 133 4 15001667 2 2 183 3

2 2 183 3



# Printin g Date : Wednesday , Jul y27 , Printin g Time : 10:36:4 5 A M Pag e1 3 o f 4 6

## *Sta nV166030 5 

# *3 M Environmenta lLab Result s Name : sll0719a.rd b

1 ISampl eName : "sll0719a053 " Sanpl eID : "GLPlO-01-01-20-00 2Hig hDALS S BPMW12 1 0 000 0La b Matri xSpik eHigh " File:"sll0719a.wrfr

IPea k Name : "PFOA " Mass(es) : "413.0/369. 0amu.413,DQ19. 0amu.413.0/169. 0amu " 1 Comment" " Annotation:" " Sampl eIndex : S 3 Sampl eType : Unknow ngg ^ Concentration : N/ A Calculate dConc : 52. 8 ng/m L Acq
. Date : 7/2o/aoi i2.1e6

- Acq
. Tine : 2:30:1 1 P M 2.0e6

- Modlfied : Ye s R TWindow : 30. 0 ae c 1.9e6

- Expecte dRT : 9,5 8 mi n U a eRelativ eRT : N o i.oeo

Int
. Type : Manua l''•^"^ ' Retentio nTime : 9.61 1 mi ni6e 6 Area : 1731990 9 count s Height : 2.2le-t00 6 cp s l5e6

- Star t Time : 9.05 3 mi n En dTime : 10.18 2mi n14e6

- 

### 1.3c6

- aV2e6

- ^1.1e6 1 1.0e6 9.0e 5 8.0e 5 7.0e 5 6.0e 5 S.OeS

4.0e 5 3,0e 5 2.0e 5 1.0e 5 

# A
_

24 6 8 1 0 1 2 1 4 1 6 16 8 33 4 50 1 66 7 83 4 100 0 116 7 133 4 Time , nni

n
• SampleName:"sl10719a055 " Sampl eID : "GLP10-01-O1-2CM}0 3 Du p DA LS S BPMW4 7 0 000 0Duplicate " File : "8110719 awifT ' 1 Pea k Name : "PFOA " Mass{es) : "413.0^169. 0amu.413.0/219. 0amu.413.0/169. 0amu " 1 Comment " Annotation; " Sampl eIndex : 5 5 Sampl eType ; Unknow n9 5 8 Concentration : N/ Aj calculate dConc : l.O S ng/m L5.2e4

- Acq
. Date ; 7/20/2oi i50e4

- Acq
. Time : 3:18:3 9 P M 4.8e 4 Modified : Ye s . „ . R TWindow : 30. 0 se c Expecte dRT : 9.5 8 mi n4.4e4 ' U s eRelativ eRT : N o 4.2e 4
' : Int
. Type : Manua l4 0e 4 iRetentio nTine : 9.58 1 ni n : Area : 39882 5 count s 3.8e 4 Height : 5.2Se-f00 4 Cp a-- ^ ; Star t Time : 9.00 5 mi nJ.t>e 4 En dTime : 9.96 5 mi n3.4e 4 3.2e4 ' 3.0e4

- 

### 1 2.6e4

-

-- & 2.6e4

- 

## 1 ^•*"'' ' 2.2e4

- 2.0e4

- 1.6e4

- 1.8e 4 1.4e 4 l,2e 4 1.0e 4 flOOO.O 6000.0

- 4OO0.0

- 2000.0

- 12,4 9

1,1 8 / i 

# \\l \ 1.00. , / Ll3.0 1 ''i^
. 

# i JV-**.,...^ ^

. ..r l.,-- - _ Akv.- ^•v^-A--^.^....vM^

• 2 4 6 8 I' O 1 2 1 4 1 6

16 6 33 4 50 1 66 7 83 4 100 0 116 7 133 4 1 Time , mi n 

### 1 6 2 0 2 2 1500168 7 183 3

^17.4 8 19,3 9 

# ^M^V \ ^''"^•'---•*-.- — 1 8 2 0 2 2 150 0166 7 183 3 ISampl eName ; "s110719a054' ' Sanpl eID : "GLPlO-01-01-20-00 3 DALS S BPMW4 7 0 OOOO " File : "s110719a,wif r 1 Pea k Name : "PFOA " Mass(es} : "413.0/369. 0amu.413.0/219. 0amu.413.0/169. 0amu ' 1 Commen t

" Annotation : ~ Sampl eIndex : 5 4 Sampl eType : Unknow n Concentration : N/ A Calculate dConc : 1.0 9 ng/m L5.2e4

- Acq
. Date : 7/20/201 1
_ Acq
. Tine : 2:54:2 7 P M ^" ^

4.8e 4 Modified : Ye a R TWindow : 30. 0 ae c ''-6e 4 Expecte dRT : 9.5 8 mi n44^ 4 U a eRelativ eRT ; N o 4.2e 4 Int
. Type : Manua l Retentio nTime : 9.61 9 mi n^'"" ^ Area ; 40856 6 count s 3.8o 4 Height : 5.2Be-f00 4 cp s star t Time : 9.10 1 mi n^-^" ^ En dTime : 10.13 3 mi n34^ 4 3.2e 4 3.0e 4 

### 1 2.8e4

- f 2.6e4 1 2,4e4 2.2o 4 2.0e4 ' 1.8e 4 1.6e 4 1.4e 4 1.2e 4 1,0e 4 8000.0 ' 8000,0

- 4000.0

- 2000.0

- 

# 1 

# A 1 \ 

# J^_y ^'^_W*'^>A^'
. 24 6 8 1 0 1 2 1 4 1 6 1 8 2 0 

### 2 2 16 8 33 4 50 1 66 7 83 4 100 0 116 7 133 4 150 0 166 7 183 3 | Time , mi n
• Sampl eName : "sll0719a056

- Sampl eID : "GLPl0-01-01-20-00 3 Lo w DALS S BPMW4 7 0 OOO O La b Matri xSpik eLow " File : "sl10719a,wi r IPea k Name : "PFOA " Mass(es) ; "413.0/369. 0amu.413.0/219, 0amu.413.0/169. 0amu " 1 Commen t

~ Annotation : ~ Sampl eIndex : 5 6 Sanpl eType : Unknow n93 2 Concentration : M/ A-^a^ K Calculate dConc : 5.9 2 ng/m L.i.uea

Acq
. Date : 7/20/201 1 Acq
. Tine : 3:42:5 2P M 28e5

- Modified : N o Proc
. Algorithm : IntelllQua n- MQI I2.6e5

- Nois ePercentage : S o Base
. Sub
. window : i.o o mi n Peak-Split

- Factor : 4 2.4e5

- Bepor t Largea t

Peak : N o Min
. Pea k

Height : o.O O cp s Min
. Pea k

Width : O.o o se c 2.2e5

- Smoothin g Width : 3 point s R TWindow : 30. 0 ae c - - ^ Expecte dRT : 9.5 8 mi n- ^" " U s eRelativ eRT ; N o 1.8e 5 Int
. Type : Valle y Retentio nTime : 9.61 7 mi n„ Area : 221314 6 count s & 1.6e5

- Height : 3,04e-.00 5 cp s > ; star t Time : 9.44 9 mi nH En dTime : 10.14 5 mi na1.4eS ' 1.2e 5
1.0e 5
8.0e 4
6.0e 4 4,0e 4 2,0e 4 1.2 1 .•7A ^



### AM y^ ^16.43 ^17.U17,4 1 24 6 8 1 0 1 2 1 4 1 6 1 8 2 0 

### 2 2 16 8 33 4 50 1 66 7 83 4 100 0 116 7 133 4 150 0 166 7 183 3 ] Time , mi n


# Printin g Date : Printin g Time : Wednesday , Jul y27 ,

10:36:4 6 A M 

# Pag e1 4 o f 4 6

## *Sta nV166030 5 

# *3 MEnvironmenta lLab Result s Name : sll07l9a.rd b 

# I Sanpl e Name : "sl10719a057 " Sarrpl e ID ; "GLP1D-01-01-20-00 3 Hig h DA LS S BPMW4 7 0 OOO O La b Matri xSpik e High " File ; "s110719a.wif r Pea k Name : "PFOA " Mass(es) : "413,0/369. 0 amu.413.0/219. 0 amu,413.0/169. 0 amu " Comment" ' Annotation : ~ Sampl e Index : 5 7 Sanpl e Type : Unknow n Concentration : N/ A Calculate d Conc : 52. 1 n Acq
. Date : 7/20/201 1 Acq
. Time : 4:07:0 4 P M Modified : N o Proc
. Algorithm : IntelllQua n Hois ePercentage : S O Base
. Sub
. Window : 1
. 0 0 Peak-Split
. Factor : 4 Repor t Larges t

Peak : N

o Min
. Pea k

Height : o.o o Min
. Pea k

Width : o.o o Smoothin g Width : 3 R TWindow : 30. 0 a e Expecte dRT : 9.5 8 m i UaeRelativ eRT : N o Int
. Type : Valle y Betentio nTine : 9.61 7 m l Area : 1682432 7 cou n Height : 2.3l e Star t Time : 9.43 7 EndTime : 10.12 1 ae c point s

0 6 2.3e6- ] 2.2e6

- 2.1e6

- 2.0e6

- 1.9e 6 1.8e 6 1.7e 6 1.6e 6 1.5o6

- 1.4o6

- 1.3e6 ' 1.2e 6 1.1e6

- 1.0e 6 9.0e 5 8.0e 5 7.0e 5 6.0e 5 S.Oe S 4,0e S 3.0e 5 2.0e 5 I.Oe S 9 . 2



# , . , I I Sampl e Name : "s110719a058 " Sampl e ID : "1 0 006-16 8 solven tblank " File : "s i 10719a.wiTT Pea k Name : "PFOA " Mass{es) : "413.0/369. 0 amu,413.0/219. 0 amu,413,0/169. 0 amu ' Comment" " Annotation: " Sanpl e Index : 5 8 Sampl e Type : Doubl e Blan k Concentration : o.o o ng/m L8500 ' Calculate dConc : N/ A Acq
. Date : 7/20/201 1 Acq
. Time : 4:31:2 0 P M 800 0 Modified : Proc . Algorithm : Nois e Percentage : Base . Sub . windo w Peak-Split . Fact o N o IntelllQua n- 5 0 : 1.0 0 n r : 4 Repor t Larges t Peak : N o Min . Pea k Height : Min . Pea k Width : Smoothin g Width : R T Window : Expecte d RT : Ds e Relativ e RT : int . Type : Retentio n Time : Area : Height : 9 Star t Tine : En d Time ; MQI I
n 0,0 0 cp s 0.0 0 se c 3 30. 0 se c 9.5 8 mi n N o Bas e T o Bas e 9.59 3 mi n 8 6 7 0 count s .8464-00 2 cp s 9,53 3 mi n 9.80 9 mi n point s 

# %

^ 75D O 700 0 650 0 600 0 550 0 500 0 450 0 400 0 350 0



# I Sanpl e Name : "sl10719a059 " Sanpl e ID ; "EC-110719-0 6 5 n g Extracte d Curv e Poin rFile ; "sl10719a.wi r Pea k Name ; "PFOA " Massfes) : "413.0/369. 0 amu.413.0/219, 0 amu,413,Q/169. 0 amu " Comment" " Annotation:" " Sampl e Index : 5 9 Sampl eType : QC Q Concentration : 5.o o ng/m L calculate dConc : E.1 8 ng/m L Acq
. Date : 7/20/201 1 Acq
. Time : 4:55:3 8 P M Modified : Proc
. Algorithn : Nois ePercentage : Base
. Sub
. Window : Peak-Split
. Facto i Repor t Larges t

Pe i Min
. Pea k

Height ; Min
. Pea k

Width : Smoothin g width : R TWindow : Expecte d RT : Da e Relativ e RT : IntelllQua n- 5 0 1.0 0 I

cp s

ae c

Int . Type : Retentio nTim e Height : Star t Ti l En d Tim e Bas e T o Bas e 9.63 9 mi n 187932 5 count s 2.546-^00 5 Cp s 9.44 9 mi n 10.13 3 mi n 2,5e 5 2.4e5 ' 2.3e5 < 2.2e 5 2.1e 5 2.0e 5 1.9e5 ' 1.6e5 - 1.7e 5 1.6e 5 1.5e 5 1.4e 5 1.3e 5 1.2e 5 l.leS 1.0e 5 9.0e 4 8,0e 4 7.0e 4 6.0e 4 5.0e 4 4.0e 4 3.0e 4 2.0e 4 1.0e 4 0. 0 I Sampl e Name : "s i 10719a060 " Sampl e ID : "1 0 006-16 8 soNen tblanl TFile : "s i 10719a-wif r Pea k Name : "PFOA " Mass(es) : -413.0/369. 0 arT«j,413.0/219. 0 amu,413.0/169. 0 amu ' I Commen t~ Annotation : ~ Sampl e Index : Sampl e Type : Concentration : Calculate d Conc ; Acq . Date : Acq . Time : Modified : Proc . Algorithm : Nois e Percentag e 6 0 Doubl e Blan k 0.0 0 ng/m L N/ A 7/20/201 1 5:19:5 3 P M Ye s IntelllQua n- 7 0 Base . Sub . window : i.o o m Peak-Split . Fac t sr : 3 Repor t Larges t Peak : N o Min . Pea k Heigh t Min . Pea k Width : Smoothin g Width : R T Window : Expecte d RT : Us e Relativ e RT : Int . Type : Retentio n Tine : Area : Height : star t Time : En d Time : MQI I
n
0.0 0 cp a 0.0 0 ae c 3 30. 0 ae c 9.6 5 mi n N o Bas e T o Baa e

. 9.65 3 ni n 4 78 7 count s 9.22e+00 2 Cp a 9.49 7 mi n 9.71 3 mi n point a



# Printin g Date : Wednesday , Jul y27 , 201 1 Printin g Time : 10:36:4 8 A M Pag e1 5 o f 4 6

## *Sta n V166030 5

*3 MEnvironmenta l La b Result s Name : sll0719a.rd b

I Sampl e Name : "sl10719a061 ' Sanpl e ID : "1 0 006-16 8 sohen tblank " File : "sll0719a.wif r Pea k Name : "PFOA " Mass(es) : "413.0/369. 0 amu,413.0/219. 0 a(iKi.413.0/169. 0 amu " I Commen t" * Annotation:" " ampl e Index : 6 1 sam p l e Type : Concentration : Cal c Acq . Acq . iilate d Conc : Date ; Time : Modified : Pro c Nol s Bas e Pea k Rep o Min . Min . Smo o Algorithm : B Percentag e Doubl e Blan k 0.0 0 N/ A 7/20/201 1 5:44:0 8 PI
Ye s intelliQu a 5 0 Sub . Window : 1.0 0 Split . Factor : 4 r t Larges t Peak : H o Pea k Heigh t Pea k Width : thin g Width : R T Window : Expecte d RT : Ua e Int . Bet e Are a Relativ e RT : Type : ntlo nTime : Height : Sta r En d , Time : rime : 0. 0 0. 0 3 30. 0 9.6 7 N o Bas e T o B e 9.66 5 529 9 CO ^ .32e-'00 2 9.56 9 9.80 9 ng/m L

n-
m MQI I
n
cp a ae c
ae c mi n

s e mi n int s cp s mi n roln poin t 

# 1

p i 700 0
6500

-

SSD O

400 0
3500

- 3000 '
250 0
200 0
150 0
1000

- 500

- 

# ^ * 1 6 7 ,2,4 9 4-9 7 I Sampl e Name ; "s110719a001 " Sarrpl e ID : "1 0 006-16 8 solven tblank " File ; "sl10719a.wifr ' Pea k Name : "MPFOA " Massfes) : '417.0/372. 0 amu " I Commen t" Annotation ; ~ Sampl e Index : Sampl e Type : Concentration ; Calculate d Con c Acq . Date : Acq . Tine : 1 Doubl e Blan k 0.0 0 ng/n L N/ A 7/19/201 1 5:31:3 7 P M 

### Modified : N o Proc
. Algorithm : IntelllQua n- IQ A Min
. Pea k

Height : O.o o cp a Min . Pea k Widt h Smoothin g Widt h R T Window : Expecte d RT : Ua e Relativ e R T Int . Type ; Retentio n Time : Area : Height : Star t Time : En d Tine : 0.0 0 3 30. 0 9.5 7 N o Valle y 9.70 1 181 4 2.21e-f0 0 9.52 1 9.89 3



# f Sanpl e Name : "s110719a002 " Sarrpl e ID : "1 0 006-16 8 so^en tblank " File ; "s110719a.wifr ' Pea k Name : "MPFOA " Mass{es} ; "417.0/372. 0 amu " Comment" " Annotation:' " Sampl e Index : 2 Sampl e Type : Concentration : Calculate d Conc : Acq . Date : Acq . Time : Modified : Proc . Algorithm : Min . Pea k Heigh t Min . Pea k Width : Smoothin g Width : R T Window : Expecte d RT : Us e Relativ e RT : int . Type : Retentio nTime : Area : Height : star t Time : En d Time : Doubl e Blan k 0.0 0 M/ A ng/n L 7/19/aoi l 5:55:4 7 N o P M IntelllQua n- IQ A o.o o o.o o 3 30. 0 9.5 7 

### No Valle y 9.68 9 74 2 c ..69e-f00 2 9.60 5 9.B2 1 cp s

se c point a ae c ni n

ni n ount s cp s ni n mi n 

# • Sampl e Name : "sll0719a003 " Sanpl e ID ; "1 0 006-16 8 solven tblank " File : "sl10719a.wifr ' Pea k Name : "MPFOA " Mass(es) ; "417,0/372. 0 amu " Commen t" " Annotation:" " Sampl e Index ; 3 Samp1 e Type ; Doubl e B1an k Concentration : 0.0 0 ng/m L Calculate d conc : N/ A Acq
. Date : 7/19/201 1 Acq
. Time : 6:19:5 5 PM Modified : Proc . Algorithm : Min . Pea k Height : Min . Pea k Width : Smoothin g Width : R T Window : Expecte d RT ; Us e Relativ e RT : Int . Type : Retentio n Time : Area : Height : I Star t Time : En d Time : M o IntelllQua n- IQ A 0.0 0 0.0 0 3 30. 0 9.5 7 N o Valle y 9.62 9 54 7 C .20e-f00 2 9.58 1 9.73 7 cp a

ae c point s se c mi n

mi n aunt s cp s mi n mi n



## Printin g Date ; Printin g Time ; Wednesday , Jul y 27 , 201 1

10:36:4 9 A M Pag e1 6 o f 4 6

# *Sta nV166030 5 *3 M Environmenta lLab Result s Name : sll0719a.rd b
rsanpl e Name : "s i 10719a004 " Sarrpl e ID : "1 0 006-16 8 solven tblank " File ; "s110719a.wi r Pea k Name : "MPFOA " Mass(es) : "417.0/372. 0 amu"^ I Comment" " Annotation ; " ampl e Index : 4 6.5 6
20 0 Sampl e Type : Concentration : Calculate d Conc : Acq . Date : Acq . Time : Modified : Proc . Algorithm : Min , Pea k Heigh t Min . Pea k width ; Smoothin g Width : R T window ; Expecte d HT : Ua e Relativ e HT : Int . Type : Retentio nTime : Area : Height : star t Time : En d Tine ; Doubl e Blan k 0.0 0 N/ A 7/19/20 : 6:44:0 4 H o ng / 1 P M IntelllQua n- 0.0 0 0.0 0 3 30. 0 9.5 7 N o Valle y 9.38 9 cp s

se c poin t se c mi n

ni n 33 8 count s 7.41e-v00 1 9.30 5 9.44 9 cp s

mi n mi n 21 0



# r Sampl e Nanw : "s i 10719a006 ~ Sarrpl e ID ; "1 0 006-16 6 solven tblank " File : "s i 10719a.wi r Pea k Name : "MPFOA " Mass(es) ; "417.0/372. 0 amu " Comment " Annotation: " Sampl eIndex : Sampl eType : Concentration : Calculate dConc : Acq
. Date : Acq
. Time : Doubl eBlan k 0.0 0 ng/m L N/ A 7/19/201 1 7:32:2 4 P M Modified : proc . Algorithm ; Min . Pea k Heigh t Min . Pea k width : Smoothin g Width : R T Window : Expecte d RT : Us e Relativ e RT : Int . Type ; Retentio nTime : Area : Height : star t Time : En d Time : N o IntelllQua n- IQ A 0.0 0 3 30. 0 9.5 7 N o Valle y 9,50 9 51 2 c .lle-»00 2 9.34 1 9.54 5 point a

se c mi n

mi n cp s mi n mi n 21 0

20 0

18 0 17 0 16 0 IS O 14 0 13 0 Sampl e Name : "s110719a005 " Sanpl e ID : "1 0 006-16 6 solven tblank " File ; "s i 107iga.wiff " Pea k Name : "MPFOA " Mass(es) ; "417.0^72, 0 amu ' Comment" " Annotation:" " Sampl eIndex : 5 Sanpl eType : Doubl eBlan k Concentration : 0.0 0 ng/m L Calculate dConc : N/ A Acq
. Date : 7/19/201 1 Acq
. Time ; 7:08:1 5 P M Modified : N o Proc
. Algorithm ; IntelllQua n- IQ A Min . Pea k Height : Min . Pea k width : Smoothin g width : R T Window : Expecte d RT : Ua e Relativ e RT : Int . Type : Retentio n Time ; Area : Height : 8 Star t Time : En d Time : 0,0 0 3 9.5 7 N o Valle y 9.49 7 cp a

ae c poi n ae c mi n

mi n 35 8 count s .OOetOO l 9.40 1 9.62 9 cp s

mi n ni n

Sanpl e Name : "sl10719a007 " Sampl e ID : "1 0 006-16 8 solven tblanl TFile : "sll0719a.wi r Pea k Name ; "MPFOA " Mass(es) : "417.0/372. 0 amu " Comrrwnt" " Annotation:" " Sampl eIndex ; Sampl eType : Concentration ; Calculate dCon c Acq
. Date : Acq
. Time : Modified : Doubl e Blan k 0.0 0 ng/m L H/ A 7/19/201 1 7:56:3 1 P M



# Printin g Date : Wednesday , Jul y27 , 201 1 Printin g Time : 10:36:5 1 A M 

# Pag e1 7 o f 4 6

## *Sta nV166030 5 

# *3 M.Environmenta lLab Result s Name : sll0719a.rd b 

# I Sarrpl eNanw : "s110719a008 " Sanpl eID : "EC-110719-09 5 0 n g War mu p standard " File:"s1l07l9a.wifr ' Peak Name ; "MPFOA " MasB(es) : "417.0/372. 0 ami ' Comment

• " Annotation:" " Sampl eIndex : e Sampl eType : Unknown Concentra t

ion : H/

A Calculate dConc ; Si. 4 ng/m L Acq
. Date : 7/19/201 1 Acq
. Time : 8:20:3 9 P M

Min . Pea k Height : Min . Pea k Width : Smoothin g Width : R T Window : Expecte d RT ; Us e Relativ e RT : 0.0 0 0.0 0 3 30. 0 9.5 7 N o cp s

se c poin t se c mi n
Int
. Type : Valle y Retentio nTime : 9.59 3 mi n Area : 1064047 5 count s Height : l, 4 7e-t0o s cp a star t Time : 9.36 S mi n EndTime : 10,18 2 mi n



# I Sampl e Name ; "s110719a010 " Sampl e ID : "EC-110719-0 9 5 0 n g War m u p Pea k Name : "MPFOA " Mass(cs) : "417.0/372. 0 amu " Comment" ' Annotation;" " Sampl e Index : 1 0 Sampl e Type : Concentration : calculate d Conc : Acq . Date : Acq . Time : Modified ; Proc . Algorithm : Min . Pea k Heigh t Min . Pea k Width : Smoothin g Width : R T Window : Expecte d RT : Us e Relativ e RT : Int . Type : Retentio nTine : Unknow n N/ A 49. 7 7/19/20 1 9:09:0 6 N o ng/m L 1 P M IntelllQua n- IQ A 0.0 0 0.0 0 3 30. 0 9.S 7 N o valle y 9.59 3 Area : 1048423 9 Height : Star t Time : En d Time : 1.4Se-f00 6 9.37 7 10,09 7 cp s

point s se c mi n

mi n count s mi n mi n Sanpl e Name : "s110719a009 " Sarrpl e tD : "EC-110719-0 9 5 0 n s War m u p standard " File : "sll0719a.wtf r Pea k Name ; "MPFOA " Mass(es) ; "417.0/372. 0 amu " Comment:" " Annotation;" " Sampl e Index : 9 Sampl e Type : Unknow n concentration : N/ A Calculate d Conc : 4 8. 7 ng/n L Acq . Date : 7/19/20i i 13^ 6 Acq . Time : 8:44:5 £ P M Modified : Proc . Algorithm ; Min . Pea k Height : Min . Pea k width : Smoothin g Width : R T Window : Expecte d RT : Us e Relativ e RT : N o IntelliQua n- IQ A 0.0 0 ae c 3 point a 30, 0 ae c 9.5 7 mi n N o Int . Type : Valle y Retentio n Time : 9.56 9 Area : 1026967 7 c < Height : l.37et00 6 star t Time : 9.35 3 En d Time : 10 . 12 1

Sampl e Nanw ; "s110719a0i rSanpl e ID : "1 0 006-16 8 solven tblank " File : "s i 10719a.wit r Pea k Name ; "MPFOA " Mass<es) : "417.0/372. 0 amu * Comment' " Annotation:" ' Sampl e Index : 1 1 Doubl e Blan k 0. 0 0 ng/m L N/ A 7/19/201 1 9:33:1 7 P M Sampl e Type : Concen t ra t Ion : Calculate d Con c Acq . Time : Modified : Proc . Algorithm ; Min . Pea k Height : Min . Pea k Width : Smoothin g Width : R T Window ; Expecte d RT : Us e Relativ e RT : IntelllQua n•

N o Int . Type : Valle y Retentio n Time ; 9.59 3 mi n Area : 2 4 9 8 count s Height : 3.4ee+oa 2 cp s Star t Time : 9.49 7 mi n En d Time : 9.B2 i mi n



# Printin g Date : Printin g Time : Wednesday , Jul y27 , 201 1

10:36:5 3 A M Pag e 1 8 o f 4 6

## *Sta nV166030 5 

# *3 MEnvironmenta lLab Result s Name : sll07l9a.rd b

I Sarrpl e Name : "s110719a0l2 " Sanpl e ID ; "1 0 006-16 8 solven tblank " File ; "sll0719a.wiff " Pea k Name : "MPFOA " Mass{es) : "417.0/372. 0 amu " I Comment : ~ Annotation : " * sampl e Index : Sampl e Type : Concentration : Calculate d Conc : Acq . Date : Acq . Time : Modified ; Proc . Algorithm : Min . Pea k Heigh t Min . Pea k Width : Smoothin g Width : R T Window : Expecte d RT ; Us e Relativ e RT : Int . Type : Retentio nTime ; Area : Height : star t Time ; En d Time : 1 2 Doubl e Blan k 0.0 0 N/ A 7/19/20 1 ng/m L
9:57:2 8 P M N o IntelllQi . 0.0 0 3 30. 0 9.5 7 N o Valle y 9.60 5 a n-

cp a se c poin ' rain

mi n 152 5 count s 

### l.B6e*00 2 9.44 9 9.76 1 cp s

mi n mi n IQ A

s



# _ 20 0

19 0 18 0 17 0

15 0 [ Sampl e Name ; -s110719a013 ' Sampl e ID : "1 0 006-168soNen tblank " File : -sll0719a.wi r Pea k Name : "MPFOA " Mass(es} : "417.0/372. 0 amu " I Commen t~ Annotation ; ~ Sampl e Index : sampl e Type : Concentration ; Calculate d Conc : Acq . Date : Acq . Time : Modified : Proc . Algorithm : Min . Pea k Height : Min . Pea k Width ; Smoothin g Width ; R T Window : Expecte d RT : Us e Relativ e RT : Doubl e Blan k 0.0 0 ng/n L N/ A 7/19/201 1 10:21:3 7 P M 

### N o itelliQua n- IQ

A 0.0 0cp a

I Sanpl e Nanw ; "s i I0719a014 " Sanpl e ID : "1 0 006-16 8 solven tblank " Rle : "s110719a.wi r Pea k Name : "MPFOA " Mass(es) ; "417.0/372, 0 amu " I Commen tTM Annotation:" " 

### Valle y 9.61 7 5 8 2 CO I 

### .14e'>00 2

Sampl e Index ; Sampl e Type ; Concentration : Calculate d Conc : Acq . Date : Acq . Time : Modified ; Proc . Algorithm : Min , Pea k Heigh t Min . Pea k Width : Smoothin g Width : R T Window : Expecte d RT : Us e Relativ e RT ; Int . Type : Retentio nTime : Area : Height : Star t Time : En d Time : 1 4 Doubl e Blan k 0.0 0 N/ A 7/19/201 ) 10:45:4 6 H o ng/m L

P M IntelllQua n- IQ A 0.0 0 0.0 0 3 30. 0 9.5 7 N o Valle y 9.48 5 49 0 C C ..41e-f00 2 9.46 1 9.64 1 ae c

point s ae c mi n

ni n unt a cp a mi n mi n 

# • Sampl e Name : "s i l0719a01S " Sampl e ID : "1 0 006-16 8 solven tblank " Rle : " s Pea k Name : "MPFOA " Mass(es) : "417.0/372. 0 amu " Commen t~ Annotation:" " Sanpl e Index : 1 5



### Doubl eBlan k

ng/mL Sampl eTyp e Concentration : Calculate dCon c Acq
. Date : Acq
. Time : Modified : H o Proc
. Algorithm : IntelllQua n N/ A 7/19/201 1 11:09:5 5 P

M 25 0



### Min
. Pea k

Height : Min
. Pea k

width : 0,0 0 Smoothin g width : 3 R TWindow : 30. 0 Expecte dRT : 9.5 7 Us eRelativ eRT : N o cp a polnt i

Int . Type : Retentio n T i Area : Height : star t Time : En d Tine : m e : Valle y 9.80 9 mi n 9 3 count s e.69e-f00 i cp s 9.7B S mi n 9.83 3 mi n



# Printin g Date : Wednesday , Jul y27 , Printin g Time : 10:36:5 4 A M Pag e1 9 o f 4 6

# *Sta nV166030 5 *3 MEnvironmenta lLab Result s Name : sll07l9a.rd b

• Sampl eName : "sll0719a016 " Sampl eID:-EC-110719-0 1 0, 2n g IPea k Name : "MPFOA " Mass(es) : "417.0^72. 0amu "
• Comment " Annotation:" " Sanpl eIndex : 1 6 Sanpl eType : Standar d Concentration : 0.20 0ng/m L Calculate dConC : 0.20 3 ng/m L Acq
. Date : 7/19/201 1 1.00e4

- Acq
. Time : 11:34:0 4 P M 9500.00 ' Modified : N o Proc
. Algorithm : IntelllQua n- IQ A9000.00 ' Min
. Pea k

Height ; 0.0 0cp s Min
. Pea k

width : o.o o se c 8500.00

- Smoothin g width : 3 point a R TWindow : 30, 0se e8OOO.00 ' Expecte dRT : 9.5 7 mi n U a eRelativ eRT : N o 7500.00

- Int
. Type : Valle y7000.00 ' Retentio nTime ; 9.56 9 mi n Area : 7086 8 count s 6500.0 0 Height : i.05et-00 4 cp s Star t Time : 9.42 5 ni n6000.00 ' En dTime : 9.92 9 mi n„ 

### &ssoo.o o S 5000.0 0

- 4500.0 0 4000.0 0 3500.0 0 3000.00

- 2500.0 0 2000.0 0 1500.0 0 1000.0 0 500.0 0 0.0 0 Extracte dCurv ePoin f Rle : "sll0719a.wifr '

9.5 7

3.9 0^4.7 3 7,0 6 8.3 1 • 11.5 3 1 3 24 6 8 1 01 2 16 8 33 4 50 1 66 7 83 4 100 0 Time , mi n
• Sanpl eName : 'sll0719a018 ~ Sarrpl eID ; "EC-110719-0 3 0,7 5 n g Extracte dCurv ePoin TFile : "sll0719a.wif r ; • Pea k

Name:-MPFOA " Mass(es) : "417.0^72, 0amu " 1 Commen t

~ Annotation:" " sampl eIndex : 1 8

, Sampl eType : standar d Concentration : 0.75 0ng/m L Calculate dConc : 0.73 1 ng/m L26e 4 Acq
. Date : 7/20/201 1 Acq
. Tine : 12:22:3 0A M2.5e 4 Modified : N O 2'^* ^ Proc
. Algorithm : IntelllQua n- IQ A2.3e 4 Min
. Pea k

Height : 0.0 0cp a Min
. Pea k

width : 0.0 0ae c ^'^* ^ Smoothin g width : 3 point s 21e 4 R TWindow : 30. 0se e Expecte dRT : 9.5 7 mi n2.0e4

- u s eRelativ eRT : N o 19e4

- Int
. Type : Valle y1.6e4

- RetentIo nTime : 9.65 3 mi n Area : 19458 2count s l.'e4

- Helght : 2.e9e-f00 4 cp s 1.6e4

- Star t Time : 9.46 1 mi n En dTime : 10.08 5 mi n„ l-5«4

- o 1.4e4

- 

### f 1-3e4

-Inte 1.1e4

- 1.0e 4 9000. 0 8000. 0 7000. 0 6000.0

- 5000. 0 4000. 0 3000. 0 2000. 0 1000. 0 

### ^„ 0. 0 9.6 5

1 24 6 8 1 01 2 16 8 33 4 50 1 66 7 83 4 100 0 Time , rrv n 05.13.4 4 15^3 6 16.7 9

1 4 1 6 116 7 133 4

1 4 1 6 116 7 133 4 19,64^;8V ^ 1 6 2 0 150 0166 7

1 8 2 0 150 0166 7 22.52-
. 2 2 183 3

2 2 183 3 • Sampl eNarrw ; "s i10719a0i r Sanpl eID ; "EC-110719-0 20, 5 n g Extracte dCurv ePoin T IPea k Name : "MPFOA " Mass(es) : "417.0^72. 0amu "
• Commen t

" Annotation: " Sampl eIndex : 1 7 Sampl eType : Standar d Concentration : 0.50 0ng/n L Calculate dConc ; 0.46 0ng/m L17- 4 Acq
. Date : 7/19/201 1 i.'M

- Acq
. Time : 11:58:2 0P M 1.6e 4 Modified : N o Proc
. Algorithm : IntelllQua n- IQ A1 5e4 ' Min
. Pea k

Height ; 0.0 0cp s Min
. Pea k

Width : 0.0 0se c Smoothin g Width : 3 point s 1.4e 4 R TWindow : 30. 0ae c Expecte dRT : 9.5 7 mi n1.3e 4 U s eRelativ eRT : N o Int
. Type : Valle y1.2e 4 Retentio nTime : 9.64 1 mi n Area : 13297 8 count s 1.1e 4 Height : 1.77e-»00 4 cp s Star t Time : 9.46 1 mi nMie A En dTime : 10.07 3 mi n„ ^9000. 0 1 BOOO.O

- £ 7000. 0 6000. 0 5000.0

- 4D00.0 ' 3000. 0 2000. 0 1000, 0 0. 0 24

16 8 33 4

• Sanrpl eNancys : "sll0719a019 " Sanpl eID : "EC-110719-0 4 1 n g Extracte dCure ePoin T 1 Pea k Name : "MPFOA " Mass(es) : "417.0^72. 0amu " 1 Commen t

" " Annotation : " " Sampl eIndex : 1 9 Sampl eType : standar d Concentration : I.o o ng/m L36e 4 Calculate dConc : 0.97 8 ng/m L Acq
. Date : 7/20/201 1 Acq
. Time : 12:46:4 7 A M •*" ' Modified : N o 3.2e 4 Proc
. Algorithm : IntelllQua n- IQ A Min
. Pea k

Height ; 0.0 0cp s 20^ 4 Min
. Pea k

width : 0.0 0se c Smoothin g Width : 3 point s R TWindow : 30. 0ae c ^'^ ^ Expecte dRT : 9.5 7 mi n U s eRelativ eRT : N o 2.6e 4 Int
. Type : Valle y24e 4 Retentio nTime : 9,64 1 mi n Area : 25704 2count s Height : 3.63e-t-00 4 cp a2.2e 4 Star t Time : 9.40 1 mi n En dTime ; 10.19 3 mi n- 2.0e 4 

# &

_ ^1.8e 4 

### 1 

### 1.6e 4 1.4e 4 1.2e 4 1.0e 4 8000. 0 6000, 0 4000. 0 2000. 0
24

16 8 33 4 Rlo:"sll0719a.wiff '

9.8 4



# _,.. . I, . , 6 8 1 01 21 4 1 6 50 1 66 7 63 4 100 0116 7 133 4 Time , mi n File;"6ll07l9a.wif f

9.6 4



# \ 6 6 1 01 21 4 1 6 50 1 66 7 83 4 100 0116 7 133 4 Time , mi n 1 8 2 02 2 150 0166 7 183 3

1 8 2 02 2 150 0166 7 183 3



# Printin g Date : Wednesday , Jul y27 , Printin g Time : 10:36:5 6 A M Pag e20o f 4 6

# *Sta nV166030 5 *3 M Environmenta lLa b Result s Name : sll0719a.rd b
ISanpl eName ; "s110719a020 " SarrplelD : ~EC-110719-O52.5ng ExtractedCurv ePoin TFil e IPeak Name ; "MPFOA" Mass(es) ; "417,0072. 0amu " B Comment" " Annotation: " Sampl eIndex ; 20 Sampl eType : Standar d Concentration : 2.5 0ng/m L Calculate dConc : 2.7 ing/m La,ue4 ' Acq
. Date : 7/20/201 1 Acq
. Tine : 1:11:0 0A M B.Se4

- Modlfled : N o 8 0e 4 Proc
. Algorithm ; IntelllQua n- IQ A Min
. Pea k

Height : 0.0 0cp s - Min
. Pea k

Width : 0.0 0se c '•^" ' Smoothin g width : 3 point s R TWindow : 30. 0se c 7.0e4 Expecte dRT : 9.5 7 mi n Ua eRelativ eRT : H o 6.5e4 ' Int
. Type : Valle y Retentio nTime : 9.65 3 mi n""" ^ Area : 64935 1 count s Height : 9.i6e-t00 4 cp s 5.5e4 Star t Time : 9.46 1 mi n EndTime : 10.14 5 mi n_5.0e4 o 

## • f 

## ^5^

- 1 4.0e4

- 3,5e4

- 3.0e4

- 2.5e4

- 2.0e4

- 1.Se4

- 1.0e4

- 5000.0

- 24 6

16 8 33 4 50 1 IPeak Name:-MPFOA " Mass(es) : "417.0072. 0amu " IComment" " /^notation: " Sampl eIndex : 2 2 Sampl eType : Standar d Concentration : lO. o ng/m L Calculate dConc : 10. 4 ng/m L Acq
. Date : 7/20/201 1 3DeS

Acq
. Time : 1:59:2 0A M Modified : H o 2.8eS

Proc
. Algorithm : IntelllQua n- IQ A Min
. Pea k

Height : o.o o cp s Min
. Pea k

width : o.o o se c 2.6e5

- Smoothln g Width : 3 point s R TWindow : 30. 0ae c 24e5

- Expecte dRT : 9.5 7 mi n Ua eRelativ eRT : N o 2.2c5

- Int
. Type : Valle y Retentio nTime ; 9.64 1 mi n Area : 229559 4 count s 2.0e5

- Height : 3.i8e-'00 5 cp s Star t Time : 9.42 5 mi n, g^g En dTime : 10.15 7 ni n„ ^1.6e5 c 

### 1 1.4e5 1.2e5 I.OeS 6.0e4 6.0e4 4.0e4 2.0e4
24 6

16 8 33 4 50 1 "sl10719a.wi r
9.6 6

,9.8 7 

# \ 8 1 01 21 4 1 6 1 6 2 02 2 667 83 4 10001167 133 4 ISO D 1667 183 3 Time , rr^ n "s110719a.wi r

9.6 5

L
. 

### 8 1 01 21 4 1 6 1 8 2 02 2 66 7 63 4 10001167 133 4 15001667 183 3

Time , mi n • Sampl eName : "s110719a021 " Sanpl eID : "EC-110719-0 6 5 ng ExtractedCuroePoin T IPeak Name ; "MPFOA" Mass(es) : "417.0/372. 0amu " B Comment

" Annotation; " Sampl eIndex : 2 1 Sampl eType : Standar d Concentration ; 5,0 0ng/mL Calculate dConc ; 5.0 0ng/m L1 c.' ; Acq
. Date : 7/20/201 1 1.5e5

- Acq
. Tine : 1:35:1 0A M 1.4e5 Modified : N o Proc
. Algorithm : IntelllQua n- IQ A Min
. Pea k

Height : 0.0 0cp a1.3e5 Min
. Pea k

Width : 0.0 0ae c Smoothin g Width : 3 point a R TWindow : 30. 0ae c 1.2e5 Expecte dRT : 9.5 7 ni n Us eRelativ eRT : N o 1Ie 5 Int
. Type : Valle y Retentio nTime : 9.64 1 mi n10e 5 Area : 114482 8 count s Height : 1.5ee-»00 5 cp s Star t Time : 9.42 5 mi n9.0e4 En dTime : 10.24 2mi n- "

- 8.0e4 

# t 1 7.0e4 6.0e4 5.O04

- 4.0e4

- 3.0e4 2,0e4

- 1.0e4

- 24

16 8 33 4

• Sampl eName : "sll0719aD23

- SampleID : "EC-11071^ 8 2 5 ng ExtractedCurv ePoin T IPeak Nan» : "MPFOA" Mass(es):"417.0O72.0amu

Sampl eIndex : 2 3 Sampl eType : Standar d Concentration : 25. 0ng/mL Calculate dConc : 24. 3 ng/m L Acq
. Date : 7/20/201 1 7.0e 5 Acq
. Time : 2:23:3 2A H Modified : N o 6.Se 5 Proc
. Algorithm : IntelllQua n- IQ A Min
. Pea k

Height ; 0.0 0cp s Min
. Pea k

width : 0.0 0se c 6.De 5 Smoothin g Width : 3 point s R TWindow : 30. 0se c Expecte dRT : 9.5 7 mi n5.5e 5 Us eRelativ eRT : N o Int
. Type : Valle y^-^" ^ Retentio nTime : 9.65 3 mi n Area : 544342 2count s . , . Height : 7.39e*00 S cp a star t Time : 9.44 9 mi n EndTime : 10.16 9 mi n„ ^Q^ J 

# > ; g 3.5e 5 3.0e 5 2.Se S 2.0e 5 1.5e5 I.OeS S.0e 4
24

16 8 33 4 File:"s110719a.wif T

9.64



# y 6 a1 0 50 1 66 7 83 4

9,6 5



# y 6 8 1 0 50 1 66 7 83 4 1 21 4 1 6 10001167 133 4 Time , mi n

1 21 4 1 6 10001167 133 4 Time , rrin 1 8 2 02 2 15001667 183 3

1 8 202 2 15001667 183 3



# Printin g Date : Wednesday , Jul y27 , 201 1 Printin g Time : 10:36:5 7 A M Pag e2 1 o f 4 6

# *Sta nV166030 5 *3 M Environmenta lLa b Result s Name : .sll0719a.rd b 

# ( Sampl e Name : "s110719a024 " Sampl e ID : "EC-110719-0 9 5 0 n g Extracte d Curv e Poin T Pea k Name : "MPFOA " Mass(es) : "417.0/372. 0 amu ' Cortiment " Annotation: " Sampl e Index : 2 4



### standar d ng/m L

ng/mL Sampl e Type : Concentration : Calculate d Conc : Acq . Date ; Acq . Time : Modified : Proc . Algorithm : Min . Pea k Heigh t Min . Pea k Width ; Smoothin g width ; R T Window : Expecte d RT : Us e Relativ e RT : Int . Type : Retentio nTime : Standar d 50. 0 49. 2 7/20/201 1 2:47:4 9 A M N O IntelliQu a 0.0 0 0.0 0 3 P 30. 0 9.5 7 H o Valle y 9.64 1 Area : 1020839 7 C O Height : star t Time : En d Time : 1.36e-f00 6 9.41 3 10.18 1

I Sanpl e Name : "s110719a026 " Sampl e ID ; "EC-110719-1 1 20 0 n g Extracte d Cun/ e Poin TFile ; "s110719a.wif r Pea k Name : "MPFOA " Mass(es) ; "417.0/372. 0 amu " 1 Comnwn t ~ /^notation : ~ sampl e Index : Sampl e Type : Concentration : Calculate d Conc : Acq . Date : Acq . Time : Modified : Proc . Algorithm : Min . Pea k Heigh t Min . Pea k width : Smoothin g width : R T Window : Expecte d RT : Ua e Relativ e RT : 2 6 Standar d 191 . 7/20/201 1 ng/m L

ng/m L 3:36:1 7 A M N o intelllQ u 0.0 0 0.0 0 s n- IQ A

cp a ae c 3 point s 30. 0 9.5 7 N o ae c

mi n 

### Int
. Type : Valle y Retentio nTime : 9.64 1 mi n Area ; 3132103 5 count s Height ; 3.5ee-v00 ecp s Star t Time ; 9.40 1 mi n En dTime : ID.20 6 mi n I Sampl e Name : "sn0719aO2S " Sanpl e ID : "EC-110719-1 D 10 0 n g Extracte d Curv e Poin TFile : "sn0719a.wif f Pea k Name : "MPFOA " Mass(es) : "417.0/372. 0 amu " I Commen t~ /Annotation:" " Sampl e Index : Sampl e Type : Concentration : Calculate d Con c Acq . Date : Acq . Time : 2 5 Standar d 99. 8 ng/m L : 107 . ng/m L 7/20/201 1 3:12:0 1 A M

0 0 0 9 0 0 0 0 0 5 7 Modified : H o Proc . Algorithm : IntelllQua n • Min . Pea k Height : Min . Pea k width : Smoothin g width : R T Window ; Expecte d RT : Ua e Relativ e RT : N o Int . Type : Valle y Retentio n Time ; 9.62 9 mi n 

### Area : 21 4 7396 0COunt S Height : 2.7oe*oo ecp s Star t Time : 9,38 9 mi n En dTime : 10,23 0mi n

Sampl e Index : Sampl e Type : Concentration ; Calculate d Conc ; Acq . Date ; Acq . Tine ; Modified : Proc . Algorithm : Min . Pea k Heigh t Min . Pea k width : Smoothin g width : R T Window : Expecte d HT : Us e Relativ e RT : 2 7 Standar d 499 . 503 . ng/m L

ng/m L 7/20/201 1 4:00:3 0 A M N O IntelllQua n- IQ A 0.0 0 3 30. 0 9.5 7 N o cp s

se c point s se c mi n 4,4e 6

4:0e 6

3.6e 6 

### Int
. Type : Valle y Retentio nTime : 9,62 9 mi n Area : S050935 2count s Height : 4.8ie'f00 6 cp s star t Time : 9,40 1 mi n En dTime : 10.23 0mi n 

# [ Sampl e Name ; "s110719a027 " Sarrpl e ID : "EC-110719-1 2 50 0 n g Extracte d Cuw e Poin TFile : "s110719a.wif r Pea k Name ; "MPFOA " Mass(es) ; "417.0/372. 0 amu " Comment " /Annotation : ~



# Printin g Date : Wednesday , Jul y27 , Printin g Time : 10:36:5 9 A M Pag e 2 2 o f 4 6

## *Sta nV166030 5 

# *3 MEnvironmenta lLa b Result s Name : sllQ7l9a.rd b

I Sampl e Name : "sllO719a028 " Sarrpl e ID : "1 0 006-16 8 solven tblank " "File:"sli0719a,wif r I Pea k Name : "MPFOA " Mass(es) : "417.0/372. 0 amu "
• Comrrwnt' " Annotation : Sampl eIndex : Sampl eType : Concentration : Calculate dcon c Acq
. Date : Acq
. Time : Modified ; Proc , Algorithm : I Min . Pea k Height : Min . Pea k Width : Smoothin g Width : 2 8 Doubl e Blan k 0.0 0 ng/ m N/ A 7/20/201 1 4 : 24:4 1 A M

R T Window : 30 , 0 Expecte d RT : 9.5 7 Us e Relativ e RT ; N o N o telllQua n - IQ A 0.0 0 c p s 0.0 0 se c point s se c

Int . Type : Retentio nTine : Area : Height : Star t Time : En d Tine : valle y 9.64 1 ni n 2630 6 count s 3.49e*00 3 Cp s 9.46 1 mi n 9.97 7 mi n



# I Sarrpl eName : "sll0719a030 " Sanpl eID : "1 0 006-16 8 solven t blank " File ; "sl10719a,wiTr Peak Name : "MPFOA " Mass{es) : "417.0/372. 0 amu " Comment

TMAnnotation; " Sampl eIndex ; 3 0 Sampl eType : Doubl eBlan k Concentration : 0. 0 0ng/m L Calculate dConc : N/ A Acq
. Date : 7/ 2 0/ 2 01 1 Acq
. Time : 5:13:0 2 A M Modified : Proc . Algorithn : Min . Pea k Height : Min . Pea k Width : Smoothin g Width : R T Window : Expecte d RT : Us e Relativ e RT : N o ntelliQua n- IQ A 0.0 0 0.0 0 3 30. 0 9.5 7 N o cp s

se c point s se c mi n
Int
. Type : Valle y Retentio nTime : 9.65 3 Area : 179 0 c i Height : 3 .47e-f00 2 Star t Time : 9.54 5 En dTime : 9.7S 1 Sampl e Name : "8l10719a029 " Sampl e ID : "1 0 006-16 8 solven tblanl TFile ; "s i 10719a,wiff " Pea k Name : "MPFOA " Mass(es) : "417.0/372. 0 amu " Comment:'" ' Annotation : • " Sampl e Index : 2 9 Doubl e Blan k : 0. 0 0 ng/m L 550

- Sampl e Type ; Concentration : Calculate d Conc : Acq . Date : Acq . Time : Modified : Proc . Algorithm : Min , Pea k Heigh t Min . Pea k width : Smoothin g Width : R T Window ; Expecte d HT ; Us e Relativ e RT : Int . Type : Retentio n Time : Area : Height : Star t Time : En d Time : Doubl e Blan k 0.0 0 N/ A ng/m L 7/20/201 1 4:48:5 3 A M N o IntelllQua n- IQ A 0.0 0 3 30. 0 9.5 7 N o Valle y 9.61 7 444 0 C 5,38e-f002 9.52 1 9,82 1 cp a

point a se c mi n

ni n unt s cp s mi n mi n

1 0 1 2 63 4 1000 Time , mi

n 1167 133 4 Sampl eName : "sll0719a03 r SampleID : Peak Name : "MPFOA" Mass(es) : "417.0/372, 0 Comment

~ Annotation:" " sampl eIndex : 3 i sampl eType : Doubl eBlan k Concentration : 0.0 0 ng/n L Calculate dConc : N/ A Acq
. Date : 7/20/201 1 Acq
. Tine : 5:37:1 2 A M 006-16 8 solven tblanI TFile :

amu " •s110719a.wi r

Modified : Proc . Algorithm : Min . Pea k Heigh t Min . Pea k Width : Smoothin g Width : R T Window ; Expecte d RT : Ua e Relativ e RT : Int . Type : Retentio n Time : Area ; Height ; star t Tine : En d Tine : N o IntelllQua n - IQ A 0.0 0 0.0 0 3 30. 0 9.5 7 N O Valle y 9.64 1 174 1 C .33e-tOo a 9.41 3 9.76 1 cp s

point a se c ni n

ni n Dunt s cp s mi n mi n

83 4 100 0 Time , mi

n


# Printin g Date : Wednesday , Jul y27 , 201 1 Printin g Time : 10:37:0 1 A M Pag e2 3 o f 4 6

## *Sta n V166030 5 

# *3 MEnvironmenta lLab Result s Name : sll0719a.rd b

• SampleName:"sll0719a03 r Sanpl eID : "LCS-110719-0 1 3 ngLCSinTCR-84 r IPeak Name ; "MPFOA " Mass(es) : "417.0^72. 0amu ' Sampl eIndex : 3 2 sampl eType : Unknown Concentration ; N/ Al.OOeS

Calculate dConc ; 3.1 2ng/m L Acq
. Date ; 7/20/201 1 9.50e4 Acq
. Time : 6:01:2 5 A M 9.00e4

- Modified : N o Proc
. Algorithm : IntelllQua n- IQ A8 50e4 Min
. Pea k

Height : o.o o cp a Min
. Pea k

Width : 0.0 0se c »- - . Smoothin g Width : 3 point s o.uue< i R TWindow : 3 0. 0se c Expecte dRT : 9.5 7 mi n'•^''" ^ Us eRelativ eRT : N o 7.00e4 Int
. Type : Valle y Retentio nTime : 9.61 7 mi n650e 4 Area : 71977 4 count s Height : i.ooe-foo s cp s 600e 4 Star t Tine : 9.40 1 mi n En dTime : 10.15 7 mi n„ 5.5De 4 2 f 5.00e 4 1 4,50e4 4.0De 4 3.50O 4 3.00e4 2.S0e4 2.00e4

- 1.50e4

- 1.00e4

- 5000.00

- 0.00

- 3.7 1

24 16 8 33 4 ISampleName : "sl10719a034 " SampleID:-LCS-110719-D 3 3 ng LC S i nTCR-842 " IPeakNan« : "MPFOA" Mass(es):"417.0/3720amu " ICommentTMAnnotation: TM Sampl eIndex : 3 4 sampl eType : Unknown Concentration : H/ A Calculate dConc ; 3.0 4 ng/n L9.0e4 Acq
. Date : 7/20/201 1 Acq
. Tine : 6:49:5 0A M B.5e

4 Modified : M o Proc
. Algorithm : IntelllQua n- IQ AB.De4

- Mln
. Peak

Height : 0.0 0cp s Min
. Pea k

Width : 0.0 0se c 7,Se4

- Smoothln g width : 3 point s R TWindow : 30, 0se c 7 064

- Expecte dRT : 9.5 7 mi n Us eRelativ eRT : N o

, Int
. Type ; Valle y [ Retentio nTime : 9.67 7 mi n6De4

- Area : 68619 4 count s Height ; 9.25et00 4 cp s 5.5e4 star t Time : 9.47 3 mi n En dTine : 10.19 4 ni n„ gj, ^11



### 3.5e4 3.0e4 2.5e4 2,0e4 1.Se 4 1.0e 4 5000. 0
0. 0 

### 24

16 8 33 4 File:"sll0719a.wif f
9,6 3

i11.0 1 6 8 50 1 66 7 Flle;"fill0719a.wif

r

9
.



### 6 8 50 1 66 7 1 01 21 4 1 6 1 8 2 02 2

83 4 10001167 133 4 ISD O 1667 183 3 Time, mi n

5 7

1 

### 1 01 21 4 1 6 1 8 2 02 2 83 4 10001167 133 4 ISO O 1687 183 3 Time , mi n • Sampl eName : "sl1D719a033 " SampleID : "LCS-110719^) 23 ng LC S i nTCR-64 r 1 Peak Name : "MPFOA" Mass(es) : "417.0/372. 0amu " • Comment

• " /^notation : " Sampl eIndex : 3 3 Sampl eType : Unknown Concentration : N/ A1 nn- 5 Calculate dConc : 2.9 9 ng/mLi.uue a Acq
. Date : 7/20/201 1 Acq
. Time : 6:25:4 0A M s.auo t Modified : N o 9.00e4 Proc
. Algorithm : IntelllQua n- IQ A Min
. Pea k

Height : 0.0 0cp s 8.50e4

- Min
. Pea k

width : 0.0 0se c Smoothin g width : 3 point s . 8,0De4

- R TWindow : 30. 0ae c Expecte dRT : 9.5 7 mi n7.50e4

- Us eRelativ eRT : N o 7.00e4 Int
. Type : Valle y Retentio nTime : 9.65 3 mi n6.50o4 Area : 69616 7 count s Height : l.oie-f00 5 cp s g 00e4 Star t Time : 9.42 5 mi n EndTime : 10.16 9 mi n„ 550e 4

. f 5.00O 4 1 4.S0e4 4.00e4 3,5De 4 3.00e4 2.50e4 2.00e4 1.50e 4 1.00e 4 5000.00 0.00 24

16 8 33 4

• SampleName ; -s110719a035

- Sanpl eID ; "LCS-110719-04 3 0ng LCS I nTCR-842 " IPeak Name ; "MPFOA

- Mass(es) ; "417.0^372. 0amu " Sampl eIndex : 3 5 Sampl eType : Unknow n Concentration : N/ A Calculate dConc : 3.0 4 ng/mL9Oe4 Acq
. Date : 7/20/201 1 Acq
. Time : 7:14:0 5 A M Modified : N o Proc
. Algorithm ; IntelllQua n- IQ A8.0e4

- Mln
. Pea k

Height : O.o o cp s Min
. Pea k

width : o.o o se c 75^ 4 Smoothin g width : 3 point s R TWindow : 30, 0se C - - , Expecte dRT : 9,5 7 mi n'"" * UaeRelativ eRT : K o 65e 4 Int
. Type : Valle y Retentio nTime ; 9.66 5 mi n6.De 4 Area : 69267 0count s Height ; 9.34e-t00 4 cp s 55o 4 Star t Time ; 9.44 9 mi n ="""•' • "•' " " " 1 5,0. 4 1 " 4.5e4

• S 4.0e 4 3.Se 4 3.0e 4 2.Se 4 2.De 4 1.5e 4 1.0e 4 SOOO.O 0. 0 

### 24

16 8 33 4 Rle;"s110719a.wif r

6 8 SO I66 7 File:"s110719a.wi r

6 8 50 1 66 7 9.6 5



# \ 1 0 63 4



### 9.6 R



# y 1 0 83 4 

### 1 21 4 1 6 10001167 133 4 Time , mi n

1 21 4 1 6 10001167 133 4 Time
. mJ n 1 8 202 2 15001667 183 3

I B 2 02 2 ISO O 1667 183 3 

# " Printin g Date : Wednesday , Jul y27 , 201 1 Printin g Time : 10:37:0 2A M Pag e24 o f 4 6

## *Sta n V15G030 5 

# *3 M Environmenta lLab Result s Name : sll0719a.rd b
Sampl e Name : "s11D719a037 " Sarrpl e ID ; '•LCS-110719-0 6 3Dn g LC S i n TCR-842 " File : "sl10719a,wi r Pea k Name : "MPFOA " Mass{es) : "417.0/372. 0 amu " 

### Commen t ~ Annotation: " Sampl e Index : 3 7 Sampl e Type ; unknow n Concentration : N/ A Calculate dConc : 2.9 5 ng/m L Acq . Date : 7/20/201 1 Acq . Time : 8:02:2 7 A M Modified : H o Proc
. Algorithm : IntelllQua n- I Q Min
. Pea k

Height : 0.0 0cp s Min
. Pea k

width : 0.0 0se c Smoothin g Width ; 3 point s 30. 0se c

m i n 

# I SafTpI o Name ; "sll0719a036 " Sanpl e ID : "LCS-110719-0 5 3 0 n g LC S i n TCR-842 " File ; "sll0719a.wif r Pea k Name : "MPFOA " Mass(es) : "417.0/372. 0 amu " Comment" " Annotation : ~ Sampl e Index : 3 6 sampl e Type : Unknow n Concentration : N/ A Calculate d Conc : 3.0 2 ng/m L Acq
. Date : 7/20/201 1 Acq
. Time : 7:38:1 6 AM Modified : N o Proc
. Algorithm : IntelllQua n- IQ A Min
. Pea k

Height ; O.o o cp s Min
. Pea k

Width : 0.0 0se c Smoothin g Width : 3 point s R TWindow : 30. 0se c Expecte dRT : 9.5 7 mi n U s eRelativ eRT : N o Int
. Type : Retentio nTi m Area ; Height : Star t Time : E n dTime : Valle y 9.65 3 mi n 66618 4 count s 8.88e+00 4 Cp a 9.46 1 mi n 10.18 2mi n 8,Se 4 8.0e 4 7.5e 4 7,0e 4 6.5e 4 6.00 4 5.5e4

- 5.0C 4 4.Se 4 4.0e4

- 3.5e 4 3,0e4

- 2-5e4

- 2.0e4

- 1.5e4

- 1.0e4

- 5000.0

- 9
. 

# s



# i 

# 1 Sanpl e Name : "6l10719a038 ' Sarrpl e ID ; "MB-110719-0 1 Metho d Blankw/ o IS " File : "s110719a-wi r Pea k Name : "MPFOA " Mass(es) ; "417.0/372. 0 amu " Comment" " Annotation:" " Sampl e Index : 3 8 Sampl eType : Doubl eBlan k Concentration : O.O O ng/m L Calculate dconc : N/ A Acq
. Date : 7/SO/201 1 280

- Acq
. Time : 8:26:3 9 A H Modified : N o R TWindow : Expecte dRT : U s eRelativ eR T Int
. Type : Retentio nTime : Area : Height : Star t Time : En dTime : : 9 a 30. 0 9.5 7 N o Valle y 9.65 3 100 3 c 93e-^00 4 9.43 7 10.20 6 6.5e 4 e.0o 4 7-5e 4 7-0e 4 6-50 4 6tl« 4 5.5e 4 5.0e 4 4.5t4

- 4.De4

- 3.5e4

- 3.De 4 2.5c 4 2.0e 4 1.5. 4 1.0e 4 5000. 0 9.6 5



# i 16 8 

# I Sampl e Name : "sl10719a039 " Sanpl e ID : "MB-110719-0 2 Metho d Blankw/ o IS " File : "s110719a.wif r Pea k Name : "MPFOA " Mass(es) : "417.0/372. 0 amu " Comment" " /Annotation:" " Sampl e Index : 3 9 Sampl e Type : Doubl e Blan k Concentration : 0.0 0 ng/m L Calculate d Conc ; N/ A Acq
. Date ; 7/20/201 1 Acq
. Time : 8:50:5 1 A M Modified : Proc
. Algorithm : Min
. Pea k

Heigh t Min
. Pea k

Width : Smoothin g width : R TWindow : Expecte dHT : u s eRelativ eRT : Int
. Type : Retentio nTime : Area : N o IntelllQua n 0.0 0C [ 0.0 0S 3 p o 30. 0a 9.5 7 m N o Valle y 9.67 7 m 7 8 2cou n Height : 9.10e*00 1 c i Star t Time : En dTime : 9.55 7 m 9.80 9 m



# Printin g Date : Wednesday , Jul y27 , Printin g Time : 10:37:0 4 A M Pag e2 5 o f 4 6

## *Sta nV166030 5 

# *3 MEnvironmenta lLab Result s Name : sll0719a.rd b 

# I Sampl e Name ; •Bll0719a040 " Sampl e ID : "MB-110719-0 3 Metho d Blankw/ o IS " File ; "s110719a.wi r Pea k Name : "MPFOA " Mass{es) ; "417.0/372. 0 amu " Commen t~ Annotation : ~ sampl e Index : 4 0 Sampl e Type : Concentration : Calculate d Conc : Acq . Date : Acq . Time : Modified : Proc . Algorithm : Min . Pea k Heigh t Min . Pea k Width : Smoothin g Width : R T Window ; Expecte d RT : Ua e Relativ e RT : Int . Type ; Retentio nTime : Area : Height ; star t Time : En d Time ; Doubl e Blan k 0.0 0 N/ A ng/m L 7/20/201 1 9:15:0 3 N o A M IntelllQua n- : 0.0 0 0.0 0 3 30. 0 9.5 7 N o Valle y 9.68 9 67 1 c 8.37e-»00 1 9.60 5 9.85 7 ae c

poin t se c mi n

mi n ount a cp s mi n ni n IQ A

a



## 8 . 

# t

Int . Type : Retentio nTim e Height : Star t Time : En d Time : 

# r Sanpl eName ; "sll0719a042

- Sanpl eID : "MB-110719-05 MethodBlan k w / IS ' File : ~s110719a.wifr' Peak Name : "MPFOA" Mass(es) : "417.0/372. 0 amu ' Comment" " Annotation;" ' Sanpl eIndex : 4 2 Sanpl eType : Unknow n Concentration : N/ A Calculate dConc : 2.9 3 Acq
. Date : 7/20/201 1 Acq
. Time : 10:03:2 8 A M Modified : Proc . Algorithm : Min . Pea k Height ; Min . Pea k Width : Smoothin g Width : R T Window : Expecte d RT : Us e Relativ e RT : Valle y 9.59 3 mi n 69342 2 count s 9.51e*00 4 cp s 10.20 6 Sampl e Name ; "s110719a041 " Sanpl e ID : "M8-110719-0 4 Metho d Blankw / IS " File : "s110719a-wifl " Pea k Name : "MPFOA " Mass{es) : "417.0/372. 0 amu ' Comnwnt" " Annotation:" " Sanpl e Index : 4 1 Sampl eType ; Unknow n Concentration : K/ A Calculate dConc : 3.0 1 ng/m L Acq
. Date : 7/20/201 1 Acq
. Time : 9:39:1 7 A M Modified : N o proc . Algorithm : IntelllQua n- IQ A Min
. Pea k

Height : 0.0 0 cp a Min
. Pea k

width : 0.0 0 se c Smoothin g width : 3 point s R TWindow ; 30. 0 se c Expecte dRT : 9.5 7 mi n Us eRelativ eRT : H o Int . Ret e Are a Type : ntio n Tim e Height : Sta r En d ; Time : Time : Valle y 9.61 7 68544 6 C 9 40e-t-00 4 9.43 7 10.04 9

Sampl e Name ; '8l10719a043 " Sampl e ID : "MB-110719-0 6 Metho d Blankw / IS " File : "sll0719a.wif r Pea k Name : "MPFOA " Mass{es) ; "417.0072, 0 amu " Comment" " /^notation:" " Sampl e Index : 4 3 Sampl e Type : unknow n Concentration : N/ A Calculate d Conc : 5.8 6 ng/m L Acq . Date : 7/20/201 1 Acq . Time : 10:27:4 3 A M Modified : N o Proc . Algorithm : IntelllQua n- IQ A Min . Pea k Height : O.o o cp a Min . Pea k Width : o.o o se c Smoothin g Width : 3 point a R T Window : 30. 0 se e Expecte d RT : 9.5 7 mi n Us e Relativ e RT : N o Int . Type ; Valle y Retentio n Time : 9.62 9 ni n Area ; 132278 8 count s Height ; 1. 7 7e+ 0 0 5 cp s Star t Time : 9.44 9 ni n En d Tine : 10.10 9 mi n „



# Printin g Date : Wednesday , Jul y27 , 201 1 Printin g Time : 10:37:0 5 A M 

# Pag e2 6 o f 4 6

## *Sta nV166030 5

*3 MEnvironmenta l La b 

# Result s Name : sll0719a.rd b

I Sampl e Name : "s110719a044 " Sampl e ID : "1 0 006-16 8 solven tblank " File ; "8110719a,wiff ' Pea k Name : "MPFOA " Mass<es} : "417.0/372. 0 amu " I Comment" " /Vnnotation : " Sampl e Index : Sampl e Type : Concentration : Calculate d Conc : Acq . Date : Acq . Time : Doubl e Blan k 0.0 0 ng/n L N/ A 7/20/201 1 10:51:5 7 A M Modified ; N o 

### Proc
. Algorithm : IntelllQua n- IQ A Min
. Pea k

Height : 0.0 0 cp a Min . Pea k Width : Smoothin g width : R T Window : Expecte d RT : Ua e Relativ e RT : int . Type : Retentio nTine : Area ; 0.0 0 3 30. 0 9,5 7 N o Valle y 9.64 1 se c

poi n mi n

mi n 6 94 count a Height : l.62e-t00 2 Star t Tine : En d Time : 9.59 3 9.72 5 cp a

mi n mi n



# 1 Sanpl e Name : "s110719a046 " Sampl e ID : "10006-168solventblanl^ ' File : "sll0719a.wif r Pea k Name : "MPFOA " Mass(es) ; "417.0/372. 0 amu " Comment" " Annotation : ~ Sampl e Index : 4 6 Sampl e Type ; Concentration ; calculate d Conc : Acq . Date : Acq . Time : Modified : Proc . Algorithm : Min . Pea k Heigh t Min . Pea k width : Smoothin g width : R T Window : Expecte d RT : Us e Relativ e RT : Int . Type : Retentio nTine : Area : Height : Star t Time ; En d Time : Doubl e Blan k 0.0 0 N/ A ng/m L 7/20/201 1 11:40:2 7 N o A M IntelllQua n - IQ A 0.0 0 0.0 0 3 30. 0 9.5 7 N O Valle y 9.61 7 84 3 C 7.30et00 1 9.38 9 9.73 7 cp s

se c point s se c mi n

mi n unt s cp s mi n mi n Sampl e Name : "sl10719a045 " Sanpl e ID : "EC-110719-0 S 2, S n g Extracte d Curv e Poin fFile : "s110719a.wif r Pea k Name : "MPFOA " Mass{es) : "417.0/372. 0 amu " Comment" " Annotation:" " Sampl e Index : Sampl e Type : Concentration : Calculate d Conc : Acq . Date : Acq . Time : 4 S Q C 2.5 0 ng/m L 2.5 6 ng/m L 7/20/201 1 11:16:1 2 A M Modified : N o Proc . Algorithm : IntelllQua n - IQ A Min . Pea k Height : o.o o cp s Min . Pea k width : Smoothin g width : R T Window : Expecte d RT : Ua e Relativ e RT : Int . Type : Retentio n Time ; Area : 60447 1 count s Height : 8.08e*0O 4 cp s star t Time ; 9.44 9 mi n En d Time ; 10.07 3 mi n 0.0 0 3 30. 0 9.5 7 N o Valle y 9.62 9 se c

poin t se c mi n

mi n

Sampl e Index ; Sampl e Type : Concentratio n calculate d Co i Acq . Date : Acq . Time : Modified : Proc . Algorithm ; I Min . Pea k Height : Min . Pea k Width : Smoothin g Width : R T Window : Expecte d RT : Ua e Relativ e RT : 4 7 Unknow n N/ A 2.8 4 n< 7/20/201 1 12:04:4 2 P M N o ItelliQua n - IQ A o . 0 0 cp a 0.0 0 ae c 3 0. 0 ae c 9.5 7 mi n N o 

### int
. Type : Valle y Retentio nTime ; 9.65 3 mi n Area : 6B9OO 2count s 

### Height : 9.7ie-f00 4 cp s Star t Time : 9.44 9 mi n EndTime : 10,09 7 mi n Sampl e Name : "s i 10719a047 - Sampl e ID : "GLPlO-01-01-20-00 1 DA LS S TRI P 0 OOOO " File : "s1l0719a.wi r Pea k Name ; "MPFOA " Mass{es) ; "417.0/372. 0 amu " Comment" " Annotation:" "



# Printin g Date : Wednesday , Jul y27 , Printin g Time : 10:37:0 7 A M Pag e2 7 o f 4 6

## •Sta nV166030 5 *3 M Environmenta lLab Result s Name : sll0719a.rd b

I Sampl e Name : "s110719a048 " Sarrpl e ID : "GLPlO-01-01-20-00 1 Du p DA LS S TRI P 0 OOO O Duplicate " File : "s110719a.wiff ' Pea k Name ; "MPFOA " Mass(es) ; "417,0^72, 0 amu " I Comment" " Annotation;" " Sampl e Index : Sanpl e Type : Concentration : Calculate d Conc : Acq . Date : Acq . Time : Modified : Proc . Algorithm ; Min . Pea k Heigh t Min . Pea k Width : Smoothin g Width : R T Window : Expecte d RT : Ua e Relativ e RT : Int . Type : Retentio nTine ; 4 8 Unknow n N/ A 3.1 5 7/20/20 1 12:28:5 9 N o ng/m L

P M IntelllQua n - IQ A : 0.0 0 0.0 0 3 30. 0 9.5 7 No Valle y 9.64 1 cpa

ae c point s ae c mi n

mi n Area : 71805 0 count s Height : star t Time : En d Time : 9.8Oe+O0 4 9.43 7 10.15 7 cp

a mi n mi n 9.Se4

-

9.De4

- 8.5e4 ' 8,0e4

- 7.5t A 7.0e < 6,5« 4 6.0e 4 5.5e 4 5.De4

- 4.5e 4 4.C)e 4 3.5e 4 30o 4 2.5e 4 2.0e 4 1.5e 4 1.0e 4 5000. 0

o.o J 9 . 34



# i 

# f Sanpl eName : "s i 10719a050 " Sanpl eID : "GLP1[H11-01-2WJ02 DA LS S BPMW12 1 0 OOOO " File : "s i 10719a.wtf f Peak Name ; "MPFOA " Mass(es) ; "417.0/372. 0 amu ' Comment" " Annotation:" " Sanpl eIndex : 5 0 Sanpl eType ; Unknow n Concentration : N/ A Calculate dConc : 3.0 3 ng/mL Acq , Date : 7/20/201 1 Acq . Time : 1:17:2 5 P M Modified ; N o Proc . Algorithm : IntelllQua n - IQ A Min . Pea k Height : O.o o cp s Min . Pea k Width ; 0.0 0 ae c Smoothin g Width : 3 point s R T Window ; 30. 0 se c Expecte d RT ; 9.5 7 ni n Us e Relativ e RT : N o Int . Type : Valle y Retentio nTine : 9.62 9 ni n Area : 67541 6 count a Height : 9. 4 3e-fO0 4 cp a star t Time : 9.41 3 mi n En d Time : lO.ls i mi n „ 

# I Sampl e Name : "sl10719a049 " Sanpl e ID : "GLP l WH-01-20-00 1 LM S DA LS S TRI P 0 000 0 La b Matri xSpike " File ; "s11D719a.wiff ' Pea k Name ; "MPFOA " Mass(es) : "417.0/372. 0 amu " Comment" " Annotation:" " Sampl e Index : 4 9 Sampl eType : Unknow ng gj Concentration : N/ A Calculate dConc : 2.9 4 ng/m ] Acq
. Date : 7/20/201 1 Acq
. Time ; 12:53:1 3 P H Modified ; N o Proc
. Algorithm : IntelllQua n- IQ A Min
. Pea k

Height : 0.0 0 cp a Min , Pea k

Width : 0.0 0 ae c Smoothin g Width : 3 point a R TWindow : 30. 0 ae c Expecte dRT : 9.5 7 mi n Us eRelativ eRT : N o Int . Type : Retentio n T i Area : Height : Star t Time : En d Time : m e Valle y 9.64 1 mi n 69115 4 count s 9.25et00 4 cp s 9.44 9 mi n 10.16 9 mi n 9.0e4 B.Se 4 60e 4 7.Se 4 7-0e 4 6-5e 4 6.0e4 S.5e 4 S.0e 4 4.Se4 4.0e4 3-5e4

- 3.0e4 2-5e4

- 2-0e 4 1.5e 4 1.0e4 ' 5000. 0 0. 0

Sanpl e Index : Sanpl e Type : Concentration : Calculate d con c Acq . Date : Acq . Time : 5 1 Unknow n N/ A 2.9 3 7/20/201 1 1:41:4 2 P M I Sanpl e Name : "s1l0719a051 " Sanpl e ID ; "GLPl0-01-01-20-00 2 Du p DM
. S S BPMW12 1 0 OOO O Duplicate " File : "sl10719a-wi r Pea k Name : "MPFOA " Mass(es) : "417.0/372. 0 amu " I Comment" " Annotation:" "
9.0e4 8.Se 4 8.De 4 7.5e4 7.0e4 6.5e4 6.0e4 5.5e4 5.0e4 4.5e4 4.0e4 3.5e4 Modified : N o Proc . Algorithm : IntelllQua n - IQ A Min . Pea k Height : 0.0 0 cp a Min . Pea k Width : 0,0 0 se c Smoothin g Width : 3 point a R T Window : 30. 0 se e Expecte d RT ; 9.5 7 mi n Us e Relativ e RT : N o Int . Type : Retentio n T i Area : Height : Star t Tine : En d Time : m e Valle y 9.64 1 64678 8 C C 9.03e-»00 4 9.43 7 10.09 7 mi n

unt a cp s mi n

3,0e 4

2.Se 4 2-0e 4 l,5o 4 1.0e 4 5000.0

- 0, 0



## Printin g Date : Wednesday , Jul y 27 , 201 1 Printin g Time : 10:37:0 9 A M Pag e 2 8 o f 4 6

## *Sta nV166030 5 

# *3 MEnvironmenta lLab Result s Name : sll07l9a.rd b 

# I Sampl e Name : "snD719aOS2 " Sanpl e ID : "GL P 10-01-01-20-00 2 lo wDA LS S BPMW12 1 0 OOO O La b Matr a Spik e Low " FUe : "s1l07l9a.wif r Pea k Name : "MPFOA " Mass{es) : "417.0/372. 0 amu " Comment:" ' Annotation : '" • Sampl e Index : 5 2 Sampl eType : Unknowngg l Concentration : N/ A Calculate dConC : 3.0 4 ng/mL Acq
. Date : 7/20/201 1 Acq
. Time : 2:05:5 4 P M Modified : N o Proc
. Algorithm : IntelllQua n- IQ : Min
. Pea k

Height : o.o o cp s Min
. Pea k

Width : O.o o se c Smoothin g Width : 3 point a R TWindow : 30, 0 ae c Expecte dRT : 9.5 7 mi n UaeRelativ eRT : N o Int . Type : Retentio nT i Area : Height : star t Time : En d Time : H

e Valle y

9.60 5 ni n 68721 0 count s 9.2ae>»00 4 cp s 9.38 9 mi n 10,10 9 mi n g.De4

- 8.5e4 < 6.0e4

- 7.Se4 : 7.0e4

- 6,5e4

- 6,0e4

- 5.5e 4 S.0e4

- 4.5e4

- 4.0e4

- 3.5e 4 3,0e4

- 2.5e4

- 2.0e4 1.5e 4 1.0e 4 5000.0

- 0. 0 

# • SampleName ; "fi11D719a053 " Sanpl eID ; "GLP1D-01-01-2D-0D 2 Hig hDA LS S BPMW12 1 0 OOO O La b Matri x Spik eHigh" File : "s110719a,wi r Pea k Name : "MPFOA

" Mass{es) : "417,0/372. 0 amu " Comment " Annotation:" " Sampl eIndex : 5 3 Sampl eType : Unknown Concentration ; N/ A Calculate dConC : 2.9 5 ng/mL Acq
. Date : 7/20/201 1 Acq
. Time : 2:30:1 1 P M Modified : N o Proc . Algorithm : IntelllQua n - IQ A Min . Pea k Height ; 0.0 0 cp s Min . Pea k Width : Smoothin g Width : R T Window : Expecte d RT : Us e Relativ e RT : Int . Type : Retentio n Time : Area : 6 4 Height : 8 Star t Time : En d Time : 0.0 0 3 30. 0 9.5 7 H o Valle y 9.60 5 32 5 37e-^0 0 9.38 9 10.09 7

83 4 100 0 Time, mi n •Sanpl e Name : "s i 10719a054 " Sanpl e ID : "GLP10-01-01-2(M)0 3 DA LS S BPMW4 7 0 OOOO " File ; "s i 10719a,wiff ' I Pea k Name : "MPFOA " Mass(es) : "417.0/372. 0 amu " I Comnwn t ~ Annotation:" " Sampl e Index : 5 4 Sanpl e Type : Unknow n Concentration : N/ A Calculate d ConC : 3.1 5 ng/m ] Acq . Date : 7/20/201 1 Acq . Tine : 2:54:2 7 P M Modified : N o Proc . Algorithm ; IntelllQua n- IQ A Min . Pea k Height : 0.0 0 cp a Min . Pea k Width : 0.0 0 ae c Smoothin g Width : 3 point a R T Window : 30. 0 se e Expecte d RT ; 9.5 7 ni n Ua e Relativ e RT : N o Int . Type : Valle y Retentio nTine : 9.60 5 mi n Area : 70198 2 count a Height : 9.53e-»oo 4 cp s Star t Time : 9.42 5 mi n En d Time : 10.09 7 mi n 9.5e 4 g.0e4 8,5e 4 8.0e 4 7.5e4 7.0e4

- 6.5e 4 6.0e 4 5.5e 4 5,0e 4 4,5e4 4.0e4 3.5e 4 3.0e 4 2.5e4 2.0e4

- 1.5e 4 1.0e 4 5000. 0 0. 0 5 5 • Comment" " Annotation : Sampl eIndex : Sampl e Type : Concen t ra t ion ; Calculate d con c Acq . Date ; Acq . Time ; Modified : Proc . Algorithm ; Min . Pea k Height : Min . Pea k Width ; Smoothin g Width : R T Window : Expecte d RT : Ds e Relativ e RT : IntelllQu i 0.0 0 0.0 0



### N o Int
. Type : Valle y Retentio nTime : 9.56 9 Area : 65009 0 C I Height : sta r Time : EndTime : 9.34 1 10.0 4 9 I Sampl e Name : "s i 10719a055 " Sampl e ID ; "GLPlO-01-01-20-00 3 Du p DA LS S BPMW4 7 0 OOO O Duplicate " I Pea k Name : "MPFOA " Mass(es) : "417.0/372. 0



# Printin g Date : Wednesday , Jul y27 , 201 1 Printin g Time : 10:37:1 0 A M Pag e 2 9 o f 4 6

## *Sta n V166030 5

*3 M Environmenta lLab Result s Name : sll0719a.rd b
fSampI e Name : "s110719a056 " Sanpl e ID : "GLPlO-01-01-20-00 3 Lo wDA LS S BPMW4 7 0 OOO O La b Matri xSpik e Low " File : "Bll0719a-wi r Pea k Name ; "MPFOA " Mass(es} ; "417.0/372. 0 amu " I Commen t~ Annotation ; TM Sampl e Index : Sampl e Type : Concentration : Calculate d Conc : Acq , Date : Acq . Time : Modified : Proc . Algorithm : Min . Pea k Heigh t Min . Pea k Width : Smoothin g Width : R T Window : Expecte d RT : Us e Relativ e RT : Int . Type : 5 6 Unknow n N/ A 2.9 1 7/20/20 1 3:43:5 2 N o ng/m L 1 P M IntelllQua n - IQ A 0.0 0 0.0 0 3 30. 0 9.5 7 N O Valle y Area : 69229 0 c Height ; star t Time : En d Tine : p.5ie-fO0 4 9.37 7 10.03 7 cp s

se c point s se c mi n

mi n mi n 

# 1

pc 9.So 4 9.0e 4 8Se 4 8.De 4

7.0e 4

5.0e 4 4.5e 4



# I Sanpl e Name : "s1l0719aOSB " Sanpl e ID : "1 0 006-16 8 solven tblank " File : "s110719a.wiff ' Pea k Name : "MPFOA " Mass(es) : "417.0/372. 0 amu " Commen t~ Annotation: " Sampl e Index : 5 8 Sampl e Type : Concentration : Calculate d Conc : Acq . Date : Acq . Time : Modified : Proc . Algorithm : Min . Pea k Heigh t Min . Pea k Width : Smoothin g Width ; R T window : Expecte d RT : Us e Relativ e HT : Doubl e Blan k 0.0 0 n g N/ A 7/20/201 1 4:31:2 0 P M N O IntelllQua n- 0.0 0 cp a 0.0 0 se c 3 poi n 30. 0 se c 9.5 7 mi n N o 

### Int
. Type : Valle y Retentio nTime : 9.38 9 mi n Area ; 53 0 count s Height : 9.5le*00 lcp s Star t Time : 9.26 9 mi n En dTime : 9.49 7 mi n I Sampl e Name ; "s i 10719a05 rSanpl e ID : "GL P 10-€1-01-20-00 3 Hig h DA LS S BPMW4 7 0 OOO O Pea k Name : "MPFOA " Mass(es) : '417.0/372. 0 amu " I Commen t" Annotation : " " Sampl e Index : Sampl e Type : Concentration : Calculate d Conc ; Acq . Date : Acq . Time : Modified : Proc . Algorithm : Min . Pea k Heigh t Min . Pea k width ; Smoothin g Width ; R T Window : Expecte d RT : Us e Relativ e RT : Int . Type ; Retentio n Time : 5 7 Unknow n N/ A 3.0 0 ng/n L 7/20/201 1 4:07:0 4 N O P M IntelllQua n- IQ A 0.0 0 0.0 0 3 30. 0 9.5 7 H o Valle y 9.61 7 Area : 64079 0 c Height : Star t Time : En d Time : a,64e-f00 4 9.37 7 10.09 7 cp s

se c point s se c mi n

mi n ount s cp a mi n mi n

1 Commen t ~ Annotation: " sampl e Index : sampl e Type : Concentration : Calculate d Conc : Acq . Date : Acq . Time : Modified : Proc . Algorithm : Min . Pea k Heigh t Min . Pea k width ; Smoothin g width : R T Window : Expecte d RT : Us e Relativ e RT : 5 9 Q C 5,0 0 5.1 3 ng/m L

ng/n L 7/20/201 1 4:55:3 8 N o P M IntelllQua n- IQ A 0.0 0 0.0 0 3 30. 0 9.5 7 H o cp s

se c point s se c mi n
Int
. Type : Valle y Retentio nTime : 9.62 9 Area : 116197 3 CO I Height : i.55e-t00 5 star t Time : 9.43 7 En dTime ; 10.12 1 

# [ Sampl e Name : "s11O719a059 " Sanpl e ID ; "EC-110719-0 6 5 n g Extracte d Curv e Poin fFile ; "s110719a,wiff ' Pea k Name : "MPFOA " Mass(es) ; "417.0/372. 0 amu "



## Printin g Date : Wednesday , Jul y 27 , 201 1 Printin g Time : 10:37:1 2 A M Pag e 3 0 o f 4 6

## *Sta n V166030 5

*3 M Environmenta lLa b Result s Name : sll0719a.rd b 

# I Sanpl e Name : "s i 10719a060 " Sanpl e ID : "1 0 006-16 8 solven tblanl TFile : "s i 10719a.wiff ' Pea k Name ; "MPFOA " Mass(es) : "417.0/372. 0 amu " Commen t~ Annotation:" " Sampl e Index ; 6 0 Sanpl e Type : Concentration : Calculate d Conc : Acq . Date : Acq . Time : Modified : Proc . Algorithm : Min . Pea k Heigh t Min . Pea k Width ; Smoothin g Width ; H T Window : Expecte d RT : Us e Relativ e RT : Int . Type : Retentio n Time : Area : Height : Star t Time : En d Time : Doubl e B 0.0 0 K/ A 7/20/20 ] 5:19:5 3 N o lan k

ng / 1 P M
IntelllQua n - 0.0 0 0.0 0 3 30. 0 9.5 7 N o Valle y 9.66 5 cp s

ae c poin t ae c mi n

mi n 3 94 count s 1.43etO0 2 9.60 5 9.70 1 cp a

mi n mi n



# r Sanpl e Name : "s110719a00 rSanpl e ID : "1 0 006-16 8 solven tblanl TFile : "s1107iga.wi r Pea k Name : "M8PF0/\(ls rMassfes) : "421.0/376. 0 amu ' Commen t• " Annotation;" " Sampl e Index : 1 Sampl e Type : Doubl e Blank nn- j Concentration : 1.0 0 ng/m L Calculate dconc : N/ A Acq
. Date : 7/19/201 1 Acq
. Time : 5:31:3 7 P M Modified ; Proc . Algorithn : Min . Pea k Height : Min . Pea k Width : Smoothin g Width : R T Window : Expecte d RT : Ds e Relativ e RT : Int . Type : Retentio n Time : Area : Height : 5 Star t Time : En d Time : N o :ntelliQua n - IQ A 0.0 0 0.0 0 3 30. 0 9.5 7 N o Valle y 9.6 2 23 1 C 97e-f00 1 9.5 7 9.7 0 cp s

se c point s se c mi n

mi n aunt s cp a mi n mi n Sampl e Name : "s i 10719a061 " Sampl e ID ; "1 0 006-16 8 solven tblank " File ; "s i 10719a,wi r Pea k Name : "MPFOA " Mass(es) ; "417.0/372. 0 amu " Commen t~ Annotation ; ~ sampl e Index : Sampl e Type : Concentration : Calculate d Conc : Acq . Date : Acq . Time : Modified ; Proc . Algorithn : Min . Pea k Heigh t Min . Pea k Width : Smoothin g Width : R T Window : Expecte d RT : Ua e Relativ e RT : Int . Type : Retentio n Tine : Area ; Height : star t Time : En d Time : 6 1 Doubl e Blan k 0.0 0 N/ A 7/20/20 1 5:44:0 8 N o ng/n L

P M
IntelllQua n - IQ A 0.0 0 0.0 0 3 30. 0 9.5 7 N o Valle y 9.40 1 45 9 c 1.32e-.^00 2 9.32 9 9.50 9 cp a

se c point a se c ni n

mi n ount s cp s mi n mi n

Sanpl e Name ; -s110719a002 ' Sanpl e ID ; "1 0 006-16 8 solven tblank " File : "sll0719a.vri r Pea k Name : -M8PFO/VJ(1S) " Mass(es} : "421.0/376. 0 amu " Comment" " Annotation;" " Sanpl e Index ; Sampl e Type ; Concentration : Calculate d Conc : Acq . Date : Acq . Time : Modified : Proc . Algorithm : Min . Pea k Height : Min . Pea k Width : Smoothin g Width : R T Window ; Expecte d RT : Us e Relativ e RT : Int . Type : Retentio n Time : Area : Height : star t Time : En d Time : Doubl e Blan k 1.0 0 ng/m L N/ A 7/19/201 1 5:55:4 7 P M N o IntelllQua n - IQ A

I cp s

6 . 90e-f00 1 9.3 5 9.5 0



## Printin g Date : Wednesday , Jul y 27 , Printin g Time : 10:37:1 4 A M Pag e 3 1 o f 4 6

## *Sta n V166030 5

*3 MEnvironmenta l La b Result s Name : sll0719a.rd b

I Sampl e Name : "s i 10719a003 " Sarrpl e ID : "1 0 006-16 8 solven tblank " File : "s i 10719a.wiff " Pea k Name ; "M8PF0A(IS) " Mass(es) : "421.0/376. 0 amu ' I Comment" " Annotation : ~ Doubl e Blank 1.0 0 ng/n L Sampl e Index : Sampl e Type : Concentratio n Calculate d Conc : N/ A Acq . Date : 7/19/201 1 Acq . Tine : 6:19:5 5 P M Modified : No Proc
. Algorithm ; IntelllQua n- IQ A Min
. Pea k

Height : O.O O cp s Min . Pea k Width : Smoothin g Width : R T Window : Expecte d RT : Ua e Relativ e RT : Int . Type : Retentio n Time ; Area : Height : 5 Star t Time : En d Time : 0.0 0 3 30. 0 9.5 7 N o Valle y 9.5 2 18 3 39e-fO O 9.4 4 9.5 6



# r Sampl e Name ; "s11D719a005 " Sampl e ID ; "1 0 006-16 8 solven tblank " File : "s110719a.wi r Pea k Name : "MePFOA(IS) - Mass(es) : "421.0/376. 0 amu ' Comn»ent:" " Annotation:" " Sampl e Index ; 5 Sampl e Type : Doubl e Blan k ConcentratIon : 1.0 0 ng/m L Calculate d Conc : N/ A Acq , Date : 7/19/201 1 Acq . Time : 7:08:1 5 P M Modified : N o Proc . Algorithm : IntelllQuan - IQ A Min . Peak Height : Min . Peak Width : Smoothing Width : R T Window : Expecte d RT : Us e Relativ e RT : Int . Type : Retentio n Time : Area : Height : 4 Star t Time : En d Time : 0.0 0 0.0 0 3 30. 0 9.5 7 N o Valle y 9.3 3 13 2 C 4Se-f00 1 9.3 1 9.4 3 cp s

se c point s se c mi n

mi n 3 unt a cp s mi n mi n Sampl e Name : "S i 10719a004 " Sampl e ID : "1 0 006-16 8 solven tblank" ' File:"sl10719a.wiff ' Pea k Name ; "M8PF0/>L(IS} " Mass(es) : "4210/376. 0 amu ' Commen t~ Annotation ; * " Sampl e Index : Sampl e Type : Concentration : Calculate d Conc : Acq . Date : Acq . Time : Modified : Proc . Algorithm : Min , Pea k Heigh t Min . Pea k Width : Smoothin g Width : R T Window : Expecte d RT : Us e Relativ e RT : Int . Type : Retentio n Time : Area : Height : Star t Time : En d Time : 4 Doubl e Blan k 1.0 0 N/ A ng/m L 7/19/201 1 6:44:0 4 Ye s P M
IntelllQua n - IQ A 0.0 0 0.0 0 3 30. 0 9.5 7 N o Valle y 9.5 6 17 2 C 5.80e-f00 1 9,5 0 9.6 1 cp a

se c point a ae c mi n

mi n ount a cp s mi n ni n

Sampl e Name : "s i 107193006 " Sanpl e ID : "1 0 006-16 8 solven tblank " File ; "sll0719a.wi r Pea k Name : "M8PF0A(1S) " Mass(es) : "421.0/376, 0 amu ' Comment' " Annotation;" " Sampl e Index : 6 Sampl e Type : Doubl e Blan k Concentration : 1.0 0 ng/m L^j Calculate dConc : N/ A Acq
. Date : 7/19/201 1 1 2 Acq
. Time : 7:32:2 4 P M Modified : Proc . Algorithm : Min . Pea k Heigh t Min . Pea k width ; Smoothin g width ; R T Window : Expecte d RT : us e Relativ e RT : Int . Type : Retentio n Time : Area ; Height : 1 Star t Time : En d Time : N o IntelllQua n - IQ A 0.0 0 0.0 0 3 30. 0 9.5 7 N o Valle y 9.5 9 cp s

se c point s se c mi n

mi n 7 3 count s .40e+OD l 9.5 7 9.6 4 cp s

mi n mi n

16 8 33 4 50 1 1 0 1 2 1 4 1 6 1 8 2 0 83 4 100 0 116 7 133 4 ISO O 166 7 Time , mi n


## Printin g Date : Wednesday , Jul y 27 , Printin g Time : 10:37:1 5 A M Pag e 3 2 o f 4 6

## *Sta nV166030 5 

# *3 MEnvironmenta lLa b Result s Name : sll07l9a.rd b 

# I Sampl e Name ; "s i 10719a00 rSampl e ID : "1 0 006-16 8 solven tblank " Pea k Name : "M6PF0A(IS) " Mass(os) : "421.0^76. 0 amu ' Comment" " Annotation : " ampl e Index : 7 sampl e Type : Concentration : Calculate d Conc : Acq . Date : Acq . Time : Modified : Proc . Algorithm : Min . Pea k Heigh t Min . Pea k Width : smoothin g Width : R T Window : Expecte d RT : Us e Relativ e RT : Int . Type : Retentio nTime : Area : Height : Star t Tine : En d Time : Doubl e Blan k 1.0 0 N/ A 7/19/201 1 ng/m L
7:56:3 1 P M Ye s IntelllQ u 0.0 0 3 30, 0 9.5 7 N o Valle y 9.5 0 a n- IQ A

cp a ae c point a ae c mi n

mi n 6 4 count s 2.90e«-00 1 9.4 7 9.5 7 cp a

mi n mi n

I Sanpl e Nanw : "sll0719a00 rSanpl e ID : "EC-110719-0 9 5 0 n g War m u p standard " File ; ~sl10719a.w) r Pea k Name : "M8PF0/MIS) " Ma5s(es) : "421.0/376. 0 amu " I Commen t~ Annotation ; ~ Sanpl eIndex : 9 Sampl eType : Onknown Concentration : 3.0 0 ng/m L Calculate dConc : H/ A Acq
. Date : 7/19/201 1 Acq
. Time : 8:44:5 5 P M Modified : N o Proc
. Algorithm : IntelllQua n- IQ A Min
. Pea k

Height ; 0.0 0 cp s Min
. Pea k

Width : 0.0 0 se c Smoothin g Width : 3 point s H TWindow : 30. 0 se c Expecte dRT : 9.5 7 mi n Us eRelativ eRT : N o Int
. Type : Valle y Retentio nTime : 9.5 7 mi n Area : 7 9 72 7 2count s Height : i.ioe-» 0 0 5 cp s St a En dTime : m i n 9.9 8 l.lOeS- ] I.OSeS I.OOeS

9.50e4 9.00e4

- e.50e4 8.00e4 7.S0e4 : 7.00o4 6.50e4

-
» 6.00e4

^5.50e4 I5.00e4

- 4.50e4 4.00e4 3,50e4

- 3.0De4 ' 2.5De 4 2.00e4 1.50e 4 1.00e4 ' 5000.00 ' 0.00 Sampl e Nanne:"sl10719a008 ' Sanpl e ID : "EC-110719-0 9 S O n g War m u p standard " nie;"sl10719a.wtf r Pea k Name : "M8PF0A(IS rMass(es) : "421.0/376. 0 amu " Comment:" " Annotation:" " Sampl eIndex : 8 Sampl eType : Unknow n Concentration : 3,o o ng/m L Calculate dConc : N/ A Acq
. Date ; 7/19/201 1 Acq
. Time : 8:20:3 9 P M Modified : N o Proc . Algorithm : IntelllQua n - IQ A Min . Pea k Height : 0.0 0 cp s Min . Pea k width : Smoothin g Width : R T Window : Expecte d RT : Us e Relativ e RT : 0.0 0 3 30. 0 9.5 7 N o se c

poin t se c mi n
Int . Type : Valle y Retentio n Tine : 9.5 9 Area : 78478 2COi Height : i.oae-f00 5 Star t Time : 9.3 7 En dTime : 10. 1 1.05e 5 I.OOe S 9.50e4

- 9.00e4 8.50e4 8.00e4 7.50e4

- 7.00e4 6.50e4 6.00e4 

# i \5.S0e4

- : 5,D0e

4 4,50e4 4.00e4 ' 3.S0e 4 3-0Oe 4 2.50e4 2.D0e 4 1.50e 4 1.00e 4 5000.0 0 0.0 0

I Sampl e Name : "s110719a010 " Sampl e ID : "EC-110719-0 9 5 0 n g War m u p standard " File : "s110719a.wif r Pea k Name ; "M8PF0A(lS rMass(es) : "421.0/376. 0 amu * IComment " Annotation : ~ Sampl eIndex : 1 0 Sampl eType : Unknow n Concentration : 3.0 0 ng/ n Calculate dConc : N/ A Acq
. Date ; 7/19/201 1 Acq
. Time : 9:09:0 6 P M Modified : N o Proc
. Algorithm : IntelllQua n- IQ A Min
. Pea k

Height : o.o o cp s Min . Pea k Widt h Smoothin g Widt h R T Window : Expecte d RT : us e Relativ e R T Int . Type : Retentio n Time : 0.0 0 3 3 0 . 0 9.5 7 M O Valle y 9.5 9 se c poi n se c mi n

mi n Area : 79772 5 count s Height ; Star t Tine : En d Time : 1.14e-»00 5 9.3 7 10. 0 cp s

mi n mi n

116 7 1334 1.10e 5 I.OSeS
l.OOe S 9.50e 4 9.00e 4 6.50e 4 8.00e 4 7.50e 4 7-0Oe 4 6.50e 4 \6-00e 4 i5.50e4

- \5.00e 4 4.50e 4 4.00e 4 3.50e 4 3.00e4 ' 2.50e 4 2.00e 4 1.50e 4 1.00e 4 5000.0 0 0.0 0



# Printin g Date : Wednesday , Jul y27 , 201 1 Printin g Time : 10:37:1 7 A M 

# Pag e3 3 o f 4 6

## *Sta nV166030 5 

# *3 M Environmenta lLab Result s Name : sll07l9a.rd b



# • Sampl e Name : "s110719a011 " Sanpl e ID : "1 0 006-16 8 solven tblank " File:"s110719a.wifr ' Pea k Name : "M8PF0A(IS) " Massfes) : "421.0/376. 0 Comment" " Annotation:" " Sanpl e Index : 1 1 Doubl e Blan k 1.0 0 ng/m L »/ A 7/19/201 1 9:33:1 7 P M Sanpl e Typ e Concentration : Calculate d Conc : Acq . Time : 

### Modified ; N o Proc
. Algorithm : IntelllQua n- IQ A Min
. Pea k

Height : O.o o cp s Min
. Pea k

Width : O.O

O se c Snoothin g Width : 3 point s R TWindow : 30. o se c Expecte dRT : 9.5 7 mi n Ua eRelativ eRT : N o Int . Type : Retentio nT l Area : Height : Star t Time : En d Tine : n e ; Valle y 9.6 2 ni n 18 4 count s 5.77e*00 1 cp s 9.5 8 ni n 9. 6 9 mi n Sampl e Name : "s11D719a012 " Sanpl e ID ; "1 0 006-16 6 solven tblank " File : "s i 10719a.wiff " Pea k Name : "M8PF0A(IS) " Mass(es) : "421.0/376. 0 amu ' Comment " /Annotation:" " Sampl e Index : 1 2 Sampl e Type : Doubl e Blan k Concentration : 1.0 0 ng/n L Calculate d Conc : N/ A Acq . Date ; 7/19/201 1 14 Acq . Time : 9:57:2 8 P M Modified : Proc . Algorithm : Min . Pea k Heigh t Min . Pea k width : Smoothin g width ; R T Window : Expecte d RT : Us e Relativ e RT : Int . Type : Retentio n Time : Area : Height : 4 Star t Time : En d Tine : Ye s IntelllQua n- IQ A 0.0 0 0,0 0 3 30. 0 9.5 7 N o Valle y 9.4 3 14 0 c .90e-f00 1 9.3 4 9.4 9 cp s

ae c point s ae c ni n

mi n ount s cp s mi n mi n

150 0 166 7 

# r Sarrpl e Name ; "s110719a013 ' Sanpl e ID : "1 0 00&-16 8 solven tblank " Rle ; 'sl10719a.wi r Pea k Name ; "M8PF0A|(IS) " Mass(es) ; "421.0/376. 0 amu ' Comnwnt" " Annotation:" " Sampl e Index ; Sampl e Type : Concentration : Calculate d conc : Acq
. Date : Acq
. Time : Modified : Proc . Algorithm : Min . Pea k Heigh t Min . Pea k Width : Smoothin g Width : R T window : Expecte d RT ; Us e Relativ e RT : Int . Type : Valle y Retentio nTime ; 9.5 8 Area : 17 6 Height : 6.2ie-t0 0 Star t Time : 9.5 6 En d Time ; 9.6 4 Sampl e Name : "sll0719a0l4 " Sanpl e ID : "1 0 006-16 8 solven tblank " File : "s i 10719a
. Pea k Name : "M6PF0A(IS) " Mass(es) : "421.0/376. 0 amu " Comment:" " Annotation;" " Sampl e Index : 1 4 Doubl e Blan k 1.0 0 ng/m L N/ A 7/19/201 1 125

- 10:45:4 6 P M Sampl e Typ e Concentration : Calculate d Con c Acq . Date ; Acq . Time ; Modified : Ye s Proc , Algorithm ; IntelllQua n- IQ A Pea k Height : 0.0 0 cp s 

### 11 5
Min . Pea k width : Smoothin g width ; R T Window : Expecte d RT : Ua e Relativ e RT : 0.0 0 30. 0 ae c 9.5 7 mi n N o Int . Type : Valle y Retentio n Time : 9.5 3 mi n Area : 21 6 count s Height : 7.i5e+oo i cp s star t Time : 9.4 9 mi n En d Time : 9.6 2 mi n



### 16 8 33 4 8 1 0 1 2 50 1 66 7 83 4 100 0 Time , n^ n 

### 166 7 183 3



# Printin g Date : Printin g Time : Wednesday , Jul y27 ,

10:37:1 8 A M 

# Pag e3 4 o f 4 6

## •Sta nV166030 5 

# *3 M Environmenta lLab Result s Name : sll0719a.rd b



# • Sampl e Name : "s110719a015 " Sanpl e ID : "1 0 006-16 8 solven tblank " Pea k Name : "M6PF0A(IS rMass(es) : "421.0/376. 0 amu ' Comment" " Annotation:" ' Sampl e Index : I S



### Doubl eBlan k 1.0 0ng/m L N/ A 7/19/201 1 1 5 11:09: 5 5 P

H sampl eTyp e Concentration : Calculate dcon c Acq
. Date : Acq
. Time : Modified ; Ye s Proc
. Algorithm : IntelllQua n Min
. Pea k

Height : o.o o Min . Pea k Width : Smoothin g Width : R T Window : Expecte d RT : Us e Relativ e RT : Int . Type : Retentio nTime : Area : Height : 4 Star t Time : En d Time : 0.0 0 3 30. 0 9.5 7 N o Valle y 9.5 3 7 5 c 20et-oo i 9.5 1 9,5 9 Sampl e Name : "s110719a016 " Sanpl e ID : "EC-110719-0 1 0. 2 n g Extracte d Cun/ o Poin fFile : "s110719a,wif r Pea k Name : "M8PF0A(IS) " Mass(es) : "421,0/376, 0 amu " Comment" ' Annotation:" ' Sanpl e Index : Sanpl e Type : Concentration : Calculate d ConC : Acq . Date : Acq . Time : Modified : Proc . Algorithm : Min . Pea k Heigh t Min . Pea k Width : Snoothin g Width : R T Window : Expecte d RT ; Us e Relativ e RT : Int . Type : Retentio n Tine : 1 6 Standar d 3,0 0 N/ A 7/19/201 ] 11:34:0 4
ve s IntelllQ u 0,0 0 0.0 0 3 30. 0 9.5 7 N o Valle y 9.5 8 nq /

P M

a n- cp s se c poin t se c ni n

ni n Area : 85962 5 count s Height : Star t Time : En d Time : i.2oe-t-oo s 9.4 0 10. 0 cp s

ni n ni n

I Sanpl e Name ; "s1l0719a017 " Sampl e ID ; "EC-110719-0 2 O. S n g Extracte d Curv e Poin fFile : "s110719a.vififf " Pea k Name ; "M8PFOA(IS) " Ma5s(es} : "421.0/376 0 amu " I Comment" " Annotation:" " 

### Sampl e Index : Sampl e Type : Concentration ; Calculate d Conc : Acq . Date : Acq . Time : Modified : Proc . Algorithm : Min . Peak Height : Min . Peak Width : Smoothing Width : RT Window ; Expecte d RT : Us e Relative RT : Int . Type : Retentio nTime : Area : Height : Star t Time : En d Time : N/ A 7/19/201 1 11:58:2 0P

M ItelliQua n- IQ

A 0.0 0ae c Ipoint a

Valle y 9.6 4 17334 7 CO 1.22e<f0O 5 

### 1.20e5

- 1.15e5 l.lOeS

1.05e5 1.00e5 9.50e4 9.00e4 6,50e4 8.00e4 7.50e4 7.00e4 I

- 6.S0e4 r 6.00e4 I5.50e4 5-00e 4 4.50e4

- 4.00e4

- 3,50e4 3,00e4 2.50e4 2.00e4 1.5De 4 1.00e 4 5000.00

- 0.00 I Sampl e Name : "s110719a018 " Sampl e ID ; "EC-110719-0 3 0,7 5 n g ExtractedCurv e Poin fFile : "s110719a.wif r Pea k Name ; "M8PFOA(IS) " Mass(es) : "421.0/376. 0 amu " 

### IComment" " Annotation:" " Sampl eIndex ; 1 8 Sampl eType ; Concentratio n Calculate dC

i Acq
. Date : Acq
. Time : Modified : Proc . Algorithm ; Min . Peak Heigh t Min . Peak Width : Smoothing Width : RT Window : Expecte d RT : Us e Relative RT : Int . Type : Retentio nTime ; Area : Height : star t Tin e En d Time :



# Printin g Date : Wednesday , Jul y27 , Printin g Time : 10:37:2 0 A M Pag e 3 5 o f 4 6

# •Sta nV166030 5 •3 M Environmenta lLa b Result s Name : sll0719a.rd b

• Sanpl eName : ~s110719a019 " Sampl eID ; "EC-110719-0 4 1 n g Extracte dCurv ePoin f 1 Pea k Name : "M8PF0A(IS) " Mass{es) ; "421.0^76. 0amu " B Comment: " Annotation;" " Sampl eIndex : 1 9 Sampl eType : Standar d Concentration : 3.0 0ng/n L Calculate dconc : N/ A1.20e5

- Acq
. Date : 7/20/201 1 Acq
. Time : 12:46:4 7 A M1.15e5

- Modifled : Ye al-IOe S Proc
. Algorithm : IntelllQua n• IQ A1 OSeS

Min
. Pea k

Height : 0.0 0cp s Min
. Pea k

Width : 0.0 0se c LOOeS

Smoothin g Width : 3 point s R Twindow : 30. 0se e9.S0e4

- Expecte dRT : 9.5 7 mi n9DDe4

- U s eRelativ eRT : N o e.50e 4 Int
. Type ; Valle y Retentio nTime : 9,6 4 mi n6.00e4

- Area : 87692 3 count s 7 tn- a Height : l.23e-»00 S cp s /.bOe4 ' Star t Time : 9,4 4 mi n7 00e4 ' En dTime : 10. 0mi n„ 3

- 6.5De 4 f 6.00e 4 1 5.50e 4 5.00e 4 4.50e4 ' 4.00e 4 3.50e 4 3.00e 4 2-5De 4 2-00e 4 1.50e 4 1.00e 4 5000.0 0 24

16 8 33 4

• Sanpl eName : "sll0719a021 " Sampl eID : -EC-110719-0 6 5 n g Extracte dCure ePoin T IPea k Name:-M8PF0A(lS r Mass(es) : "421.0/376. 0amu " 1 Comment" " Annotation : ~ Sampl eIndex : 2 1 Sampl eType ; Standar d Concentration ; 3.0 0ng/m L Calculate dConc : N/ A.15e 5 Acq
. Date : 7/20/201 1 Acq
. Time : 1:35:1 0A M
_I.IOe S Modified ; N o I.OSe S Proc
. Algorithm : IntelllQua n- IQ A Min
. Pea k

Height : 0,0 0cp s I.OOe S Min
. Pea k

width : 0.0 0se c smoothin g Width : 3 point s '*-°" " R TWindow ; 30. 0se c 9 00e 4 Expecte dRT ; 9.5 7 mi n U s eRelativ eRT : N o 8.50e 4 Int
. Type : Valle y8.00e 4 Retentio nTine : 9.6 4 mi n Area : 82764 2count s 7.50e4

- Helght : 1.19e-f00 5 cp s ^ Star t Tine : 9.4 3 mi n En dTime : 10. 2mi n„ 6.50e 4

^6,00o4

- g 5.50e4

-

~ 5.00e4

- 4.50e4

- 4,00e4

- 3,50e4

- 3.D0e 4 2,50e 4 2.00e 4 1.S0e 4 1.00e 4 

### sooo.o o 24

16 8 33 4 Filc:"s110719a.wifl

9.6 4



# y 6 8 1 01 21 4 1 6 1 8 2 02 2 50 1 66 7 83 4 100 0116 7 133 4 1S0 O 166 7 183 3 Time , n^ n File:"s110719a.wi r

9.6 4

L
. 8 8 1 01 21 4 1 6 1 8 2 02 2 50 1 66 7 83 4 100 0116 7 133 4 150 0166 7 183 3 Time , mi n • Sampl eName : "sll0719a020 " Sampl eID : "EC-110719-0 5 2. 5 n g Extracte dCurv ePoin f Fil e IPea k Name : •M8PFOA(IS) " Mass(es) ; "421.0/376, 0amu " B Commen t

" /Vnnotation:" " Sampl eIndex : 2 0 Sampl eType : Standar d Concentration : 3.0 0ng/m L Calculate dConc : N/ A, ,55 , Acq
. Date : 7/20/201 1 Acq
. Tine ; 1:11:0 0A M l.lOeS

Modified : N o I.OSeS

Proc
. Algorithn : IntelllQua n- IQ A Min
. Pea k

Height : 0.0 0cp s I.OOe S Min
. Pea k

Width : 0.0 0se c - „ . Smoothin g Width : 3 point s ^"^"" ^ R TWindow : 30. 0se c 9 00e4 ' Expecte dRT : 9.5 7 mi n U s eRelativ eRT : N o 8.50e4 ' Int
. Type : Valle y8,00e4 ' Retentio nTime : 9.6 5 ni n Area ; 85081 3 count s 7.50e 4 Height ; I.l9et00 5 cp s ,0-^
. Star t Tine : 9.4 6 ni n En dTine ; 10. 1 ni n^6.5De 4 

### J6.00e4 iS.S0e 4

~ 5,00e 4 4.S0e 4 4.00e 4 3.50e 4 3.OO0 4 2.SDe 4 2.00e 4 1.50e 4 1-00e 4 5000.0 0 24 6

16 8 33 4 50 1 ISampl eName ; "s1107iga022 " Sanpl eID : ~EC-110719-O 7 lOngExtractedCurv ePoin f File ; IPea k Name : "MBPFOA(IS) " Mass{es) ; "421.0^76. 0amu " Sampl eIndex : 2 2 Sampl eType : Standar d Concentration : 3.0 0ng/m L Calculate dConc : N/ A1.15e 5 Acq
. Date : 7/20/201 1 1m- l Acq
. Time : 1:59:2 0A M I.IUC O

I.OSe S Modified : N o Proc
. Algorithm : IntelllQua n- IQ AI.OOe S Min
. Pea k

Height ; 0.0 0cp s Min
. Pea k

Width : 0.0 0ae c 9.5De 4 Smoothin g Width : 3 point a R TWindow : 30. 0se e9.00e 4 Expecte dRT ; 9.5 7 mi n0cn- A U s eRelativ eRT : N o 8.50e 4 8 00e 4 Int
. Type : Valle y Retentio nTine : 9.6 4 mi n75De 4 Area : 80724 8 count a Height : I.i7e-f00 5 cp s 7.D0e 4 star t Time : 9.4 3 mi n En dTime : 10. 1 mi n„ 6.50e 4 

### 1 6.00e 4 1 5,50o 4

- 5.00e 4 4,50e 4 4.00e 4 3.50e 4 3.00e 4 2.S0e 4 2.00e 4 1.50e 4 1.00e 4 5000.0 0 

# «« « 24 8

16 8 33 4 50 1 "s110719a.wif r

9.6 S



# \ 8 1 0 66 7 83 4 -sll0719a.wif r

9.6 ^



# y 8 1 0 66 7 63 4 1 21 4 1 6 100 0116 7 133 4 Time , mi n

1 21 4 1 6 100 0116 7 133 4 Time , mi n 1 8 2 02 2 150 0166 7 183 3

1 8 2 02 2 150 0166 7 183 3



# Printin g Date : Wednesday , Jul y27 , 201 1 Printin g Time : 10:37:2 2A M Pag e3 6 o f 46

## *Sta nV166030 5 

# *3 M Environmenta lLab Result s Name : sll0719a.rd b

rSanpl e Name : "sl10719aO23 " Sanpl e ID ; "EC-110719-0 8 2 5 n g Extracte d Cun/ e Poin fFMe ; "sl1D719a.wif r Pea k Name : "M8PF0A{IS) " Mass(es) : "421.0/376. 0 amu " I Commen t" " Annotation:" " Sampl e Index : Sampl e Type : Concentration : Calculate d Conc ; Acq , Date ; Acq . Tine : Modified : Proc . Algorithn : Min . Pea k Heigh t Min . Pea k Width : Smoothin g Width : R T Window : Expecte d RT : Ua e Relativ e RT : Int . Type : Retentio n Time : 2 3 Standar d 3.0 0 ng/m L M/ A 7/20/201 1 2:23:3 2 A M N o IntelllQua n - 0,0 0 cp s 0,0 0 se c 3 poin ' 30. 0 ae c 9.5 7 mi n N o Valle y 9.6 5 mi n Area : 83120 2 count s Height : Star t Tine : En d Time ; 1.12e+00 5 cp s 9.4 3 mi n 10. 2 mi n IQ A

a



# 1

• t 

# 1 I.IOeS
I.OSeS
I.OOeS
9 00e4

-

B.00e4

- 7.50e4

-

6.50e4

- 6.00e4

- 5.S0e4

- 5.00e4

- 4.S0e4

- 4.00e4

- 3,5De4

- 3.00e4

- 2.50e4

- 2.00e4

- 1.50e4

- 1.00e4

- 5000.00

-

Min . Pea k Width : Smoothin g Width : R T Window : Expecte d RT : Us e Relativ e RT : Int . Type : Retentio n Time : Area : 7 9 Height : 1 Star t Time : En d Tine ; 0.0 0 3 30. 0 9.5 7 N o Valle y 9.6 3 .31 5 C 07e-»00 5 9.4 0 10. 1 se c

poi n se c ni n

ni n ount s cp s ni n mi n 

# I Sanpl e Name : "s i 10719a024 " Sanpl e ID : "EC-110719-0 9 S O n g Extracte d Cuw e Poin fFile : "s110719a.wif r Pea k Name : "M8PF0AJ(IS) " Mass{es) ; "421.0^376. 0 amu " Comment" " Annotation:" "



# f Sanpl e Name : "s110719a02S " Sampl e ID : "EC-110719-1 0 10 0 n g Extracte d Cun/ e Poin fFile : "6l10719a,WFi r Pea k Name : "M8PFOA{IS) " Mass(es) : "421.0/376. 0 amu ' Commen t" " Annotation : " " Sampl e Index : 2 5 sampl e Type : standar d Concentration : 3.0 0 ng/m L Calculate d Conc : N/ A Acq
. Date : 7/20/201 1 Acq
. Time : 3:12:0 1 A M 

### Modified : N o Proc . Algorithm : IntelliQuan - IQ A Min . Peak Height ; 0.0 0 cp s Sampl e Index : Sampl e Type : Concentration : Calculate d Conc : Acq . Date : Acq . Time : Modified : Proc . Algorithm : Min . Pea k Heigh t Min . Pea k Width : Smoothin g Width : R T Window : Expecte d RT ; Us e Relativ e RT : Int . Type : Retentio n Tine : Area : 7 Height : Star t Tine : En d Time : 2 4 Standar d 3.0 0 ng/m L N/ A 7/20/201 1 2:47:4 9 A H N o IntelllQua n - IQ A 0.0 0 cp s 0.0 0 se c 3 point s 30. 0 se c 9.5 7 mi n N o Valle y 9.6 4 mi n 1537 3 count s l.lle-tOO S cp s 9.4 5 mi n 10. 1 mi n a



# t 1 I.OSe S 

### rooe s 9.50e 4 g.0De 4 8.S0e 4

7.SOe 4 7.00o 4 6.50c 4 6.00e 4 5.5064

- 5.00e4

- 4.50O4

- 4.00e4

- 3.50e4

- 3,00e4

- 2.S0e 4 2.00e4

- 1.50e4

-



### Sampl e Type : Concen t rat ion : Calculate d co m Acq . Date : Acq . Time : Standard 3.0 0 N/ A 7/20/201 1 3:36:1 7 A

M Modified : N o Proc
. Algorithn ; IntelliQua n- IQ A Min
. Pea k

Height : 0.0 0cp a Min
. Pea k

Width : 0.0 0ae c Smoothin g Width : 3 point a R TWindow ; 30. 0ae c Expecte dRT : 9.5 7 mi n Us eRelativ eRT ; N o Int
. Type : Valle y Retentio nTime : 9.6 4 mi n Area : 68291 9 count s Height : 8.6le-t- 00 4cp s Star t Tine : 9.4 1 mi n EndTime : 10, 1 mi n I Sampl e Name ; "s110719a026 " Sampl e ID : "EC-110719-1 1 20 0 n g Extracte d Curv e Poin fFile : "s110719a.wit f I Pea k

Name : "MBPFOA(IS) " Mass(e5) ; "421.0/376. 0 amu " B Comment" " Annotation:" " Sampl e Inde x



# Printin g Date : Wednesday , Jul y27 , 201 1 Printin g Time : 10:37:2 4 A M Pag e3 7 o f 46

## *Sta n V166030 5 

# *3 MEnvironmenta lLab Result s Name : sll0719a.rd b

I Sampl e Name : "s110719a02 rSanpl e ID : "EC-110719-1 2 50 0 n g Extracte d Curv e Poin fFile : "sll0719a.wi r Pea k Name ; "M8PF0A(1S) " Mass(es) : "421.0/376. 0 amu ' I Commen t" ' Annotation:" " Sampl e Index : Sampl e Type : Concentration : Calculate d Conc : Acq . Date : Acq . Tine : Modified ; Proc . Algorithn ; Min . Pea k Heigh t Min . Pea k Width : Smoothin g Width : R T Window : Expecte d RT : Us e Relativ e RT ; Int . Type : Retentio nTime : 2 7 Standar d 3.0 0 N/ A 7/20/201 : ng/m L
4:00:3 0 A M N o IntelllQ u : 0.0 0 0.0 0 3 30. 0 9.5 7 N O Valle y 9.6 3 Area : 53643 4 C O Height : Star t Time : En d Time : 6.12e»00 4 9.4 1 10. 1 a n- IQ A

cp a se c point a se c mi n

unt s cp s mi n mi n 

# 1 

# & 5.5e 4

5.0e 4

4.5e 4

4.0e 4

3.5e 4

3.0e 4



# f Sanpl e Name : "sll0719a029 " Sampl e ID : "1 0 006-16 8 solven tblank " File : "s i 10719a.wiff " Pea k Name : "M8PFOA(IS) " Mass(es) : "421.0/376. 0 amu ' Comment" " Annotation : — Sampl e Index : 2 9 Sampl e Type : Doubl e Blan k Concentration : 1.0 0 ng/m L Calculate d Conc : N/ A1 6 Acq
. Date : 7/20/201 1 Acq
. Time : 4:48:5 3 A M Modified : N o Proc . Algorithm : I Min . Pea k Height : Min . Pea k Width : Smoothin g Width : R T Window : 30. 0 Expecte d RT : 9.5 7 Us e Relativ e RT : N o telllQua n- IQ A 0. 0 0 cp a 0.0 0 se c 

### point a

int . Type : Retentio nTime : Area : Height : Star t Time : En d Time : Valle y 9.5 1 12 2 C C 4.40e-f00 1 9.4 7 9.5 8 ni n unt s cp s mi n mi n 

# I Sampl e Name : "s110719a028 " Sanpl e ID : "1 0 006-16 8 sclen tblanl fFile : "sll0719a.wif r Pea k Name ; "MSPFOAflS) " Mass(es) : "421.0/376. 0 amu " Comment" " Annotation;" " Sampl e Index : 2 8 Sampl e Type : Doubl e Blan k Concentration : i.o o ng/m L Calculate d Conc : N/ A 

### Acq
. Date : 7/20/201 1 Acq
. Tine ; 4;24:41A M Modified : Proc . Algorithm : Min . Pea k Heigh t Min . Pea k width : Snoothin g Width : R T Window : Expecte d RT : Us e Relativ e RT ; Int . Type : Retentio n Tine : Area ; Ye a Intelli Q 0.0 0 0.0 0 3 30. 0 9.5 7 N o Valle y 9.8 0 a n-

cp a se c poi n se c mi n

mi n 17 5 count a Height : 7.05e*oo i Star t Tine : En d Time ; 9.7 7 9.8 7 cp a

mi n mi n

Sampl e Name : "s110719aD30 " Sanpl e ID : "1 0 006-16 8 solven tblank " Pea k Name : "M8PFOA(IS) - Mass(es) : "421.0/376. 0 amu ' Comment" " Annotation:" " Sampl e Index ; 3 0 Doubl e Blan k 1,0 0 ng/m L 1 3 Sampl e Typ e Concen t ra t ion ; Calculate d conc : Acq . Date :
Modified : Proc . Algorithn : Min . Pea k Height ; Min . Pea k Width : Smoothin g Width : R T Window ; Expecte d RT : Ua e Relativ e RT : Int . Type : Retentio n Time : Area : Height : : Star t Time : En d Time : M/ A

Ye s 

### 12 5

IntelliQua n- IQ A 0. 0 0 cp s 0.0 0 se c 3 point s 30. 0 se c 9.5 7 mi n



# Printin g Date : Wednesday , Jul y27 , Printin g Time : 10:37:2 5 A M 

# Pag e3 8 o f 4 6

## *Sta n V166030 5 

# *3 MEnvironmenta lLa b Result s Name : sll0719a.rd b 

# I Sarrpl e Name : "s1107l9a031 " Sampl e ID ; "1 0 006-16 8 solven tblanl ^ File ; "s i 10719a,wifl " Pea k Name : "M8PF0A(IS) " Massfes) : "421.0/376. 0 amu ' Commen t* " Annotation:" " Sampl e Index : 3 1 Sampl e Type : Concentration : Calculate d Conc : Acq . Date : Acq . Time : Modified : Proc . Algorithm : Min , Pea k Heigh t Min . Pea k Width : Smoothin g Width : R T Window : Expecte d RT : Us e Relativ e RT : Int . Type ; Retentio nTine : Area ; Height : Star t Time : En d Time ; Doubl e Blan k 1.0 0 N/ A 7/20/20 1 ng/m L
5:37:1 2 A M Ve s IntelliQua n- IQ A 0.0 0 0.0 0 3 30. 0 9.5 7 N o Valle y 9.8 0 27 4 C C 8.78e-f00 1 9.7 1 9.8 6 cp s

se c point s se c mi n

mi n unt a cp s mi n mi n



# T Sanpl e Name ; "s110719a033 " Sampl e ID : "LCS-110719-0 2 3 n g LC S i n TCR-842 " File : "s110719a.wif f Pea k Name : -M8PF0A{IS) " Mass(es) : "421.0/37 6 0 amu " Cortiment" " Annotation:" " Sampl e Name ; "sl10719a03 rSanpl e ID : -LCS-110719-0 1 3 n g LC S i n TCR-842 " File ; "s110719a.wi r Pea k Name ; "M8PFOA(IS) " Mass(e5) ; "421.0/376. 0 amu " Comment " Annotation:" " Sampl e Index : Sanpl e Type ; Concen t ratIon : Calculate d Conc : Acq . Date : Acq . Time : Modified : Proc . Algorithm : Min . Pea k Height : Min . Pea k width : Smoothin g width : R T Window ; Expecte d RT : Us e Relativ e RT : 3 2 Unknow n 3 .0 0 ] N/ A 7/20/201 1 6:01:2 5 A M

N o Int . Type ; Retentio n Time : Area : Height ; Star t Tim e En d Tine ; Valle y 9.6 2 mi n 82393 1 count s 1.19e*00 5 cp s 9.3 9 mi n 10. 1 mi n

N/ A 7/20/201 1 6:25:4 0 A M sampl e Index : sampl e Type : Concentration : Calculate d Conc : Acq . Date ; Acq . Tine ; Modified : Ye s Proc . Algorithm : IntelliQua n- IQ A Min . Pea k Height : 0.0 0 cp s Min . Pea k width : 0.0 0 se c Smoothin g width : 3 point s R T window : 30, 0 se c Expecte d RT : 9.5 7 mi n Us e Relativ e RT : N o Int , Type : Retentio nT Height : Star t Time : En d Time ; Valle y

> : 9.6 5 mi n 82839 2 count s 1.20e-r00 5 Cp s 

### 1.20eS 1.15e5

- l.lOeS

l.DSeS

I.OOeS

9.50e4 9.00e4 8.50e4 8.00e4

- 7.50e4 7.00e4 I6,50e4 ? 6,00e4 : \5.50e4 5.00e4 4,50e 4 4.00e 4 3.50e4 3.00e4 2.50e4 2.00e4 1.50B 4 

### 1.00e 4 5000.0 0 0.0 0 1.15e 5 l.lOe S I.OSe S l.DOe S 

### 9.S0e 4 9.00e4 8-50e 4 8.00e4 7.50e4 7.00e4 j ^6,50e4 

### I6.00e4 I S.5De4 -

' S.00o 4 

### 4.5De 4 4.00e4 3,50e4 3.00e4 2,50e4 2-00e4 l.S0e 4 1.00e 4 SOtHl.OO

0.0 0

I Sampl e Name : "s110719a034 " Sampl e ID : "LCS-110719-0 3 3 n g LC S i n TCR-e4 rFile ; "s110719a.wi r Pea k Name : "M8PF0A(IS) " Mass(es) : "421.0^76 0 amu " I Comment" " Annotation:" " 

### Sampl eIndex ; 3 4 Sampl eType : Unknown Concentration : 3
. o o i Calculate dConc : N/ A Acq
. Date ; 7/20/201 1 Acq . Tine : 6:49:5 0 A M Modified : Proc.-Algorithm : Min . Pea k Height : Min . Pea k Width : Smoothin g Width : R T Window : Expecte d RT : Ua e Relativ e RT : Int . Type : Retentio n Time ; Area : 8 C Height : ] Star t Tine ; En d Tine : Ye a IntelllQua n- 0.0 0 0.0 0 3 30. 0 9.5 7 N O Valle y 9.6 8 468 1 C .06e-»00 5 9.5 0 10. 1 cp s

se c poin t se c mi n

mi n aunt s cp s mi n mi n I.OSeS
I.OOe S 9.50e 4 9.00e 4 e.50e 4 8.00e 4 7.506 4 7.00e4

- 6.50e 4 6.00e 4
>; 5.S0o 4 I 5.00e 4

' 4.S0e 4 4.00e 4 3.50e 4 3.0Oe 4 2.S0e 4 2.00e 4 1.50e 4 1.00e4

- SOOO.O O 0.0 0



# Printin g Date ; Printin g Time : 

# Wednesday , Jul y27 , 201 1

10:37:2 7 A M 

# Pag e3 9 o f 4 6

## *Sta n V166030 5 

# *3 MEnvironmenta lLab Result s Name : sll0719a.rd b

I Sampl e Name : "sl10719aO35 " Sampl e ID : "LCS-110719^) 4 3 0 n g LC S i n TCR-84 rFile : "s110719a.wif r Pea k Name ; "M8PF0AJ(1S) " Mass(es} ; "421.0/376 0 amu " I Comment' " Annotation ; " 

### Sampl eIndex : 3 5 Sampl eType : Unknow n Concentration : 3.0 0ng/mL Calculate dConc ; N/ A Acq
. Date : 7/20/201 1 Acq
. Tine : 7:14:0 5 A M Modified : Ye s Proc
. Algorithm ; IntelliQua n- IQ A Min
. Pea k

Height : 0,0 0cp a Min
. Pea k

Width : 0.0 0ae c Smoothin g Width : 3 point s R TWindow : 30. 0se c Expecte d RT : us e Relativ e Int . Type : R T
Retentio n Tine ; Area : Height : Star t Time : En d Time : 9.5 7 ; N o Valle y 9.6 5 m

m n

n 31186 8 count s 1.12e-*00 5 9.4 6 10. 1 cp s

n n n n 

### l.lOeS

I.OSeS

l.OOeS

9.50e4

- 9.00e4

- e.S0e4

- 6.00e4

- 7.S0e4

- 7.00e4 6.S0e4

- g . 6.0Oe4

- ^S.50e4

- f S,00e4

- 4,S0e4

- 4.00e4

- 3.S0e4

- 3.00e4

- 2.50e4

- 2.00e4

- 1.50e4

- 1.00e 4 5000.00

- 0,00

- 16 8 33 4 

# r Sanpl eName : "s i10719a03 r Sanpl eID : "LCS-110719-0 6 3 0ng LCS i nTCR-84 yFile ; "s i10719a.wiff

Peak Name : "M8PF0A(IS) " Ma5s(es) : '421.0/376. 0amu " Comment ~ Annotation ; ~ sanpl eIndex : 3 7 Sampl eType : Unknow n Concentration : 3.0 0ng/m Calculate dConc : N/ A Acq
. Date : 7/20/201 1 Acq
. Time : 8:02:2 7 A M Modified : Ye s Proc . Algorithm : IntelllQua n - Min . Pea k Height ; 0.0 0 Min . Pea k width : 0.0 0 Smoothin g width : 3 H T Window : 3 0. 0 Expecte d RT : 9.5 7 Us e Relativ e RT : N o Int . Type : Valle y Retentio n Time : 9.6 4 cp s se c poi n se c mi n

mi n Area ; 83227 0 count s Height : l.08e-f00 5 Star t Time : 9.4 1 En d Time : 10. 1 cp s mi n mi n I.OSe S

I.OOe S 9.SDe 4 9.00e 4 6.50e 4 8.00e4

- 7.50e 4 7.00e 4 6.50e 4 6.00e 4 5.50e 4 5.00e 4 4.50c 4 4.00C 4 3.50e 4 3.00e 4 2.S0e 4 2.006 4 1.S0e 4 1.00e 4 SOOO.OO


### o.oo J 

### 9 . 

### M

H . , . , . , . , . , . , , 

# • SampleName : "sll0719a036 " Sarrpl eID : "LCS-110719-05 3 0ng LCS i nTCR-842 " File : "s11D719a.wir Peak Name ; "M8PF0A{IS) " Mass(es) : "421.0/376. 0amu " Comment" " Annotation:" " Sampl eIndex : 3 6 Sampl eType : Unknown Concentration : 3.0 0ng/m L Calculate dConc ; N/ A Acq
. Date : 7/20/201 1 Acq
. Time : 7:38:1 6 A M Modified : Ye s Proc . Algorithm : IntelllQua n - Min . Pea k Height : o.o o Min . Pea k Width : o.o o Smoothin g Width : 3 H T Window : 30. 0 Expecte d RT : 9.5 7 Ua e Relativ e RT : N o Int . Type : Valle y Retentio n Time : 9.6 4 Area : 78617 1 c Height ; l.08ei-00 5 Star t Tine : 9.4 9 En d Tine : 10. 3 cp s se c poi n se c mi n

mi n aunt s cp s ni n ni n

•Sampl e Name:"s110719a038 " Sanpl e ID ; "MB-110719-0 1 Metho d Blankw/ o IS " File : "s110719a.wifr ' I Pea k

Name : "M8PFO/V1S) " Massfes) : "421.0/376. 0 amu " I Commen t~ Annotation : " " 

### Sampl e Index : 3 8 Sampl e Type : Doubl e Blan k Concentration : 1.0 0 ng/mL . . - Calculate d Conc : N/ A Acq . Date : 7/20/201 1 Acq . Time : 8:26:3 9 A M, „ Modified : Proc . Algorithm : Min . Pea k Heigh t Min . Pea k width : Smoothin g width ; R T Window : Expecte d RT : Us e Relativ e RT : int . Type : Retentio n Time : Area ; Ye s IntelliQua n - IQ A 0.0 0 0.0 0 3 30. 0 9.5 7 N o Valle y 9.6 5 45 1 c Height : 7.i5e-t-oo i star t Time : En d Tine : 9.5 3 9.7 7 cp s

se c point s se c ni n

ni n ount s cp a mi n mi n



# Printin g Date : Wednesday , Jul y27 , 201 1 Printin g Time : 10:37:2 9 A M Pag e40o f 46

## *Sta n V166030 5 

# *3 M Environmenta lLa b Result s Name : sll07l9a.rd b 

# I Sampl e Name ; "s i 10719a039 " Sampl e ID : "MB-11D719-0 2 Metho d Blan k w/ o IS " File : "s110719a.wit f Pea k Name : "M8PF0A(1S) " Ma5s(es) ; "421.0/376. 0 amu " Comment:" " Annotation : ' " Sampl e Index : 3 9 Doubl eBlan k 1.0 0ng/m L N/ A 7/20/201 1 8:50:5 1 A

M Sampl e Type : Concentration : Calculate d Conc ; Acq . Time : Modified :



# r Sampl e Name : "s110719a04 rSampl e ID : "MB-110719-0 4 Pea k Name ; "MBPFOAJllS rMass(es) : "421.0/376. 0 ami ' Comment" " Annotation:" " Sampl eIndex : 4 1 Sampl eType : Unknown Concentration : 3.0 0 ng/m L Calculate dConc : N/ A Acq
. Date : 7/2O/201 1 Acq
. Time : 9:39:1 7 A M Modified : Ye s Proc
. Algorithm : IntelliQua n
Smoothin g Width : H T Window: • Expecte d RT : Ua e Relativ e RT : Int . Type ; Retentio nTime : 3 point s 3 0. O se c 9.5 7 mi n N o Valle y 9.6 2 mi n Area : 81041 9 count s Height : 1 Star t Tine : En d Time : .13e-t00 5 cp s 9.3 9 mi n 10. 2 mi n I.IOe S 1.05e 5 I.OOe S g.50e 4 9.00e4

- 6.50e 4 B.00e 4 7.S0e4

- 7.00e 4 6.S0e 4 6.00e4 < 5.50e 4 S.00e 4 4.SDe4

- 4.00e 4 3.S0e4

- 3.00e4

- 2.50e4 ' 2.00e 4 1.50e 4 1.00e 4 SOOO.O O 0.00 ' 

# ( Sampl eName : "s110719a040 " Sanpl eID ; "MB-110719-0 3 Metho dBlankw/ o IS " File : "s1l0719a.win " Pea k Name ; "M8PF0A11S) " Mass(es) : "421.0/376. 0amu " Comment" " Annotation:'" ' Sampl eIndex : 4 0 Sampl eType : Doubl eBlan k Concentration : J.o o ng/n L Calculate dConC : N/ A Acq
. Date : 7/20/201 1 Acq
. Time : 9:15:0 3 A M Modified : Pro c Algorithm : Min . Pea k Height : Min . Pea k width : Smoothin g Width : R T Window : Expecte d RT ; Us e Relativ e RT : Int . Type : Retentio n Tine : Area ; Height : 7 Star t Time : En d Time : Ye a IntelliQua n- IQ A 0.0 0 0.0 0 3 30. 0 9.5 7 N o Valle y 9.7 0 19 2 C I5e-f00 i 9.6 7 9.7 6 cp s point s se c mi n

mi n aunt s cp s mi n mi n

Sampl e Name ; "s i 10719aO4 rSampl e ID : "MB-110719-0 5 Metho d B Pea k Name ; -MBPFOA<IS rMass(es) : "421.0/376. 0 amu " Comment" " Annotation:" " Sampl eIndex : 4 2 Sampl eType ; • Unknow n Concentration : 3.0 0 ng/m : Calculate dconc : N/ A Acq
. Date : 7/ZO/201 1 Acq
. Time : 10:03:2 8 A M kw/lS " File:"sl10719a.wiff "

Modified ; Ye s Proc
. Algorithn : IntelllQua n- IQ A Min
. Pea k

Height : o.o o cp s Min . Pea k Width : Smoothin g Width : R T Window : Expecte d RT ; Us e Relativ e RT : Int . Type : Retentio n Tine : Area : 8 Height : Star t Tine : En d Time : 0.0 0 3 30. 0 9.5 7 N O Valle y 9.5 9 187 9 .16e-f0 0 9.3 7 10. 1 1.1Se 5 I.IOeS

I.DSe S I.OOe S 9.S0e 4 9.00e4

- B.S0e4

- 8.00e 4 7.5De 4 7.00e 4 6.50e 4 \6.00e 4 \5.50e 4
: S.00e 4 4.50e 4 4.00e 4 3.S0e 4 3.00e 4 2.S0e 4 2.00e 4 1.50e 4 1.00e 4 5000.0 0 0.00

-



# Printin g Date : Printin g Time : Wednesday , Jul y27 , 201 1

10:37:3 1 A M Pag e4 1 o f 4 6

## •Sta n V1G6030 5

*3 MEnvironmenta l La b 

# Result s Name : sll0719a.rd b 

# I SampleName : "s110719a043 " SampleID : "MB-110719-06 MethodBlankw / IS " File : "s110719a.wifr' Peak Name : "MaPFOA{IS) " Mass(es) : "421.0/376. 0amu " Comment" " Annotation:" " Sampl eIndex : 4 3 Sampl eType : Unknow n Concentration : 3.o o ng/m ; Calculate dConc : M/ A Acq
. Date : 7/20/201 1 Acq
. Time : 10:27:4 3 A M 

# I Sampl eName : "sll0719a044 " Sanpl eID : "1 0006-16 8 solvent blank* ' File ; "8ri07"l9a.wiff " Peak Name ; "MePFOA(IS) " Mass(es) : "421.0^76. 0amu ' Comment" " Annotation;" " Sampl eIndex : 4 4 Sampl eType : Doubl eBlan k Concentration : i.o o ng/m L Calculate dConc : N/ A Acq . Date : 7/20/201 1 160

- Acq . Time : 10:51:5 7 A M Modified : No Proc
. Algorithm : IntelliQua n- IQ A Modified : Ye s Proc
. Algorithm : IntelliQua n- IQ A Min
. Peak

Height : 0,0 0cp s Min . Pea k widt h Smoothin g widt h R T window : Expecte d RT : Us e Relativ e R T Int . Type : Retentio nTine : Area : Height : Star t Time : En d Time : 0.0 0 3 30, 0 9.5 7 N o Valle y 9.6 3 se c poi n se c mi n

mi n 1789 2 count s i.iie+oo s 9.4 1 10. 2 cp a

mi n mi n 

### 1. 1 Oe

S 1.05e5

- I.OOe S 9.50e4

- 9.00e4

- 8.50e4

- 8.00e4 7.S0e 4 7.00e4 6-50e 4
^&00e4

, & 5.50e 4 IS.00e 4 4.50e4 4-00e4 3.50e4 ' 3.00e4 2.50e4

- 2.00e4 1.50e4

- 1.D0e 4 5000.00

- 0.00

Sanpl eIndex ; 4 5 Sanpl eType : Q C Concentration : 3.0 0ni Calculate dConc : N/ A Acq
. Date ; 7/20/201 1 Acq
. Time : 11:16:1 2A M Modified : Proc . Algorithm : Min . Pea k Heigh t Min . Pea k Width : Smoothin g Width : R T Window : Expecte d RT : Us e Relativ e RT : Int . Type : Retentio nTime : N o IntelliQua n- 0.0 0 0.0 0 3 30. 0 9.5 7 N o Valle y 9.6 3 cp s

se c poi n se c mi n

mi n Area : 83732 5 count s Height : star t Time : En d Time : 1.15e-t-00 5 9.4 5 10. 1 cp s

mi n mi n 

### I.IOe S

I.OSeS I.OOe S g.S0e 4 9.00e4 8.50e4

- B.00e 4 7.50e4 7.0Qe 4 6.50e4 f 6.00e4 r 5.50e 4 

### I5.00e4 4.S0e4 4.00e4 3.SDe 4 3.00e4 2.50e4 2.00e4 1.50e4

- 1.00e 4 5000.00

- 0.00 Min . Pea k Min . Pea k Smoothin g R T Windo w Heigh t

Width : Width : Expecte d RT : Us e Hela t Int . Typ e Retentio n Area ; Height : v e RT :

Tine :
Star t Time : En d Time : 

### 4
. 90e'<-00 1 cp s



# I Sampl eName : "s i10719a046 " Sanpl eID : "1 0006-16 8 solvent blank " File:"s110719a.wifr ' Peak Name : "M8PF0A(IS) " Masstes) : "421.0/376. 0amu ' Comment" " /Annotation;" ~ Sanpl eIndex : 4 6 Sampl e Type : Concentration ; Calculate d Conc : Acq . Date : Acq : Time : Modified : Proc . Algorithm : Min . Pea k Heigh t Min . Pea k Width : Smoothin g Width : R T Window : Expecte d RT ; Us e Relativ e RT : Int . Type : Retentio n Time : Area : Height : Star t Time : En d Time : Doubl e Blan k 1.0 0 N/ A 7/20/20 1 11:40:2 7 Ye s ng/m L

A M IntelliQua n- IQ A 0.0 0 0.0 0 3 30. 0 9.5 7 N o Valle y 9.6 2 30 0 C ..13e-f00 2 9.5 7 9.7 0 cp s

se c point s se c mi n

mi n aunt s cp s mi n mi n



# Printin g Date : Printin g Time : Wednesday , Jul y27 , 201 1

10:37:3 3 A M Pag e4 2o f 4 6

# •Sta nV16S030 5 *3 M Environmenta lLab Result s Name : sll07l9a.rd b
ISampleName:"8l10719a04 r SampleID ; "GLP10-01-D1-20-00 1 DA LS S TRI P00000 " File : "s110719a.wif r IPeak Name : "M8PFOA(IS) " Mass(es) ; "421.0/376. 0amu " B Comment" " /Annotation : " " Sampl eIndex : 4 7 Sampl eType : Unknowngg 5 Concentration : 3,0 0ng/mL1.20eS

Calculate dConc ; N/ A Acq
. Date : 7/20/201 1 1.15e5 Acq
. Time : 12:04:4 2P H l-IOeS

Modlfied : N o 105- 5 Proc
. Algorithm : IntelllQua n- IQ A Min
. Pea k

Height : 0.0 0cp a10Oe S Min
. Pea k

Width ; O.O

O ae c Smoothin g Width ; 3 point a9.50e4

- R TWindow : 30. 0ae c Expecte dRT : 9.5 7 ni n9-00e4

- Us eRelativ eRT : N o 850e 4 Int
. Type : Valle y8.00e4

- Retentlo nTine : 9.6 5 ni n Area ; 86372 9 count s 7.50e4

- Height : l.2le+00 5 cp s Star t Tine : 9.4 3 ni n7.00e4

- EndTime ; 10. 1 mi n^^^^
_
^B.OOe

A 

### S S.50e4

- 5.00e4

- 4.50e4

- 4.00e4

- 3,50e4

- 3,00e4

- 2.S0e4

- 2.00e4

- l-50e4

- 1.00e4

- 5000.00

- 

# i

24 6 8 1 01 21 4 1 6 I B 2 022 16 8 33 4 50 1 66 7 83 4 10001167 133 4 15001667 183 3 ISampleName : "s110719a049 " SampleID : "GLPKHll-01-20-00 1 LM S DA LS S TRI P0OOO O La b Matri xSpike " Time , mi

n File:"s1107l9a,wifr

IPeak Name : "M8PF0A(IS) " Mass(es) : "421.0^76. 0amu " IComment" " Annotation : TM sampl eIndex : 4 9 sampl eType : Unknow ngg 3 Concentration : 3.o o ng/mL Calculate dConc : N/ A^lOeS

Acq
. Date ; 7/20/201 1 Acq
. Tine : 12:53:1 3 P M 1.05e5

- Modified : Ye s l.OOeS

Proc
. Algorithm : IntelliQua n- IQ A Min
. Pea k

Height : 0.0 0cp s 9.50e4

- Min
. Pea k

width : 0.0 0se c Smoothin g width : 3 point s 9.00e4

- R TWindow : 30, 0se c ac.n ^ Expecte dRT : 9.5 7 ni n8.50e4

- Us eRelativ eRT : N o 8 00e4

- Int
. Type : Valle y7 50e4

- Retentio nTime : 9.6 3 mi n Area : 83810 2count s 700e4

- Helght : I.l4e-t00 5 cp a Star t Time : 9,4 6 mi n6.50e4 EndTime ; 10. 2mi n^ g- 6.00e4 f " 5,S0e4 1 5.00e4 4.S0e4 4.00e4 3.S0e4 3.00e4 2.50e4 2.00e4 1.50e 4 1.00e 4 5000.0 0 i



### 24 6 8 1 01 21 4 1 6 1 8 2 02 2 16 8 33 4 50 1 667 83 4 10001167 133 4 15001667 183 3 Time , mr n mSampleName ; -sll0719aO48 " Sanpl eID ; "GLPlO-01-01-20-00 1 Du p DA LS S TRI P0OOO O Duplkiate " File : "s110719a,wifr

- • Peak Name : "M8PF0A(IS r

Mass(es) : "421.0/378. 0amu " mComment" " /Annotation: TM Sampl eIndex : 4 8 Sampl eType : Unknowngg ^ Concentration : 3.0 0ng/n LI.IOeS- n Calculate dConc : N/ A Acq
. Date ; 7/20/201 1 I.OSeS Acq
. Time : 12:28:5 9 P M I.OOe

S Modified : N o aiin. A Proc
. Algorithm : IntelliQua n- IQ A9.5De

4 Min
. Pea k

Height ; 0.0 0cp s Min
. Pea k

Width : 0.0 0se c a.D0e4

- Smoothin g Width : 3 point ao ^nA R TWindow : 30. 0ae c B.suef l Expecte dRT : 9.S 7 mi n8 00- 4 Us eRelativ eRT : H o o.uuc*
.

7 50e4

- Int
. Type : Valle y Retentio nTime : 9.6 4 mi n7 00e4

- Area : 81257 3 count s Height : l.loe-f00 5 cp s 6 50e4 Star t Time : 9.4 3 mi n En dTime : 10. imi n„ 8,00e4

- ^5.50e4ntan 

### 4.50e4 4.00e4 3.S0e 4 3.00e4 2.50e4 2.00e4 1.S0e 4 1.00e 4 SOOO.O O 

# L

24 6 8 1 01 21 4 1 6 16 8 33 4 S0 1 66 7 83 4 10001167 133 4 Time , mi n • SampleName:"s110719a050" Sampl eID : "GLP10-01-01-20-D02DA LS S BPMW12 1 00000 " File : "s110719a.vn1T' IPeak Name : "M8PF0/^tS) " Mass(es) : "421.0/376. 0amu " HComment

/annotation : sampl eIndex : 5 o Sampl eType : Unknowngp g Concentration : 3.0 0ng/mLirv ; e^ Calculate dConc ; N/ A^•'" " Acq
. Date ; 7/20/201 1 *nn- e Acq
. Time ; 1:17:2 5 P M^•°°^ ^ Modified : Ye s 9,50e4 Proc
. Algorithm : IntelliQua n- IQ A Min
. Pea k

Height ; o.o o cp s 9.D0e 4 Min
. Pea k

width ; 0.0 0se c acn- i Smoothin g width ; 3 point s e,50e4 R TWindow : 30. 0ae c Expecte dRT : 9.5 7 mi n""" " Ds eRelativ eRT : N o ^^^ ^ Int
. Type : Valle y Retentio nTime : 9.6 3 mi n(.««< « Area ; 79409 1 count s o «n- a Height ; i.07e»00 5 cp s B.sue A star t Time : 9.4 4 mi n En dTine : 10. 2mi n„ """"" ^ R

- 

### "
. S.S0e 4



# . ^ 1 S.00e 4 S 

### " " 4.S0e4 4.00e4 3.S0e 4 3.00e4 2.50e4 2.00e4 1.50e 4 1.00o 4 5000.0 0 

# L

24 6 8 1 01 21 4 1 6 16 8 33 4 50 1 66 7 83 4 10001167 133 4 Time , mi n 1 8 202 2 15001667 1B3 3

1 8 202 2 15001667 1B3 3



# Printin g Date ; Printin g Time : Wednesday , Jul y27 ,

10:37:3 4 A M Pag e 4 3 o f 4 6

# *Sta nV166030 5 *3 M Environmenta lLab Result s Name : sll0719a.rd b

I Sampl e Name ; "s i 10719a051 " Sampl e ID : "GLPlO-01-01-20-00 2 Du p DA LS S BPMW12 1 0 OOO O Duplicate " File ; "s i 10719a,wifr ' Pea k Nanw : "M8PF0A(IS) " Mass(es) : "421.0/376. 0 amu " I Comment' " Annotation;" " Sampl e Index : sampl e Type : Concentration ; Calculate d Conc : Acq . Date : Acq . Tine : Modified : Proc . Algorithm : Min . Pea k Heigh t Min . Pea k Width ; Smoothin g Width ; R T Window : Expecte d RT : Us e Relativ e RT : Int . Type : Retentio nTime : 5 1 Unknow n 3.0 0 N/ A ng/m L 7/20/201 1 1:41:4 2 P M Ye a IntelllQua n- IQ A 0.0 0 0.0 0 3 30. 0 9.5 7 N o Valle y Area : 78451 3 c Height : Star t Tine : En d Tine : 1.06e-*00 5 9.4 3 10. 1 cp s

ae c point a ae c ni n

3unt a cp s mi n ni n 

# s.

pg 1.05c5 ^

9.50e4

- 9.00e4

-

7.50e4

-

6.00e4 ' 5.50e4

- 5.00e4

- 4.50e4

- 4.00e4

- 3,S0e4

- 3.00e4

- 2.50e4

- 2.00e4

- 1.S0e4

- 1.00e4

- 5DOO.00

- 

# r Sanpl eNanw : -sll0719aOS3 " SampleID : "GLPlO-01-01-20-002 Hig hDA LS S 8PMW12 1 0 OOO O La b Matri x Spik eHigh " File : "s1107l9a.wif r Pea k Name : "M8PF0/yiS) " Mass(es) ; "421.0/376. 0 amu " Comment" " /^notation ; ' " sampl eIndex : 5 3 Sampl eType : Unknow n concentration : 3.0 0 ng/m L Calculate dConc : N/ A Acq . Date : 7/20/201 1 Acq . Time : 2:30:1 1 P M Modified : Ye a Proc . Algorithm : IntelllQua n- : Min . Pea k Height : 0.0 0 cp s Min . Pea k width : 0.0 0 se c Smoothin g width : 3 point i R T Window : 3 0. 0 se e Expecte d RT : 9.5 7 mi n Us e Relativ e RT : N o Int . Type ; Valle y Retentio nTime : 9.6 1 mi n Area ; 77 2 84 6 count s Height ; l.03e<'00 5 cp a

. Time : En dTime : 9.3 2 10
. 1 I.OOeS

9.50e4 9.00e4

- 8.50e4 8.00e4 7.50e4 7.00e4 6.50e4 6.00e4 5.50e4 S.00e 4 4.50e4 4.00e4

- 3.50e4 3.00e4 2.S0e4 2.00e4 l.S0e 4 1.00e4

- 5000.0 0 0.00 

# • Sampl eName : "s110719a052 " Sampl eID ; "GLPlO-01-01-20-002 lo w DA LS S BPMW12 1 0 OOO O La b Matri x Spik eLow" File ; "s11D719a.wvf r Peak Name ; "M8PF0A(1S} " Mass(es) ; "421.0/376. 0 amu " Comment

~ Annotation ; ~ Sampl eIndex : 5 2 Sampl eType : Unknow n Concentration : 3.0 0 ng/m Ll.lOe S Calculate dConc ; N/ A Acq
. Date : 7/2o/2oi l I.OSeS

Acq
. Time : 2:05:5 4 P M I.OOe S 9.50e 4 9.00e 4 8.50e 4 8.D0e4 : 7.S0e4

- 7.00e4 6.50e4

-
^6,00e4

^S.50e

4 

### I5.00e 4 4.5De 4 4.00e4 3.S0e 4 3.00e 4 2.SOe 4 2.00e4 1,S0e4

- 1.00e4 ' 5000.00 0,00

- Modified : Proc . Algorithn : Min . Pea k Heigh t Min . Pea k Width : Smoothin g Width : R T Window : Expecte d RT ; Ua e Relativ e RT : Int . Type : Retentio n Tine ; Area : 8 Height : star t Time : En d Time : Ye s IntelliQua n- 0.0 0 0.0 0 3 30. 0 9.5 7 N O Valle y 9.6 1 cp a

se c poi n ae c mi n

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mi n mi n

Sampl e Index : Sanpl e Type ; Concentration : Calculate d Conc : Acq . Date : Acq . Time : Modified : Proc . Algorithm : Min . Pea k Heigh t Min . Pea k Width : Smoothin g Width : R T Window ; Expecte d RT : Us e Relativ e RT ; Int . Type : Retentio n Time : Area : 7 Height : Star t Time : En d Time : 5 4 Unknow n 3.0 0 ng/m L N/ A 7/20/201 1 2:54:2 7 P M Ye s IntelliQua n- IQ A : 0. 0 0 cp s 0.0 0 se c 3 point a 30. 0 se c 9.5 7 mi n N o Valle y 9.6 3 ni n 9544 6 count s i.o9e-tOo s cp a 9.4 0 mi n 10. 2 mi n 

# ^

• t I.OOeS
9.50e4

- 9.00e4

- 6.50e4

- 8.00e4

- 7.5De4

- 7.00e4

- 6,S0e4

- 6.00e4

- 5.50e4

- 5.00e4

- 4.5De4

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- 3.50e 4 3.00e 4 2.50c 4 2.00e 4 l.S0e 4 1.00e4

- 5000.0 0 0.0 0



# Printin g Date : Wednesday , Jul y27 , Printin g Time : 10:37:3 6 A M Pag e4 4 o f 4 6

## •Sta n V166030 S 

# *3 MEnvironmenta lLab Result s Name : sll0719a.rd b

• Sanpl e Name : "s110719a0S5 " Sampl e I Pea k Name;-MBPFOA(ls r Mass(es) ; B Comment" " Annotation;" " Sampl e Index : 5 5 Sampl e Type : Unknow n Concentration : 3.0 0 ng / Calculate d Conc : N/ A Acq . Date : 7/20/301 1 Acq . Time : 3:18:3 9 P M Modified ; Ye s Proc . Algorithn : IntelliQua n- Min . Pea k Height : o.o o cp a Min . Pea k Width : O.o o ae c Snoothin g Width : 3 poin t R T window : 30. 0 ae c Expecte d RT : 9.5 7 mi n Us e Relativ e RT : N o Int . Type : Valle y Retentio nTime : 9.5 8 mi n Area : 80386 0 count s Height : i.ioe-t-00 5 cp s Star t Time : 9.3 4 mi n En d Time : 10. 1 mi n ID : GLP1O-O1-O1-20-D0 3 Du p DA L 421.0/376 0 amu "

m L

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S



# 1 I.IOcS i

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B.50e 4 6.00e 4 7.50e 4 7 nnm A

• 6S0e4- ' 6.0De4

- 5.50e4

- 5.00e4

- 4,50e4

- 4.00e4

- 3.50e4

- 3.00e4

- 2.50e4

- 2.00e4

- 1.50e4

- 1.00e4

- 5000.00

- S S BPMW4 7 0 OOO O Duplicate " File : ~s1107iga.wi r

I Sampl e Name ; "s110719a05 rSampl e ID ; "GLP l 0-01-01-20-00 3 Hig h DA LS S BPMW4 7 0 OOO O La b Matri xSpik e High " File : "s i 10719 a wif T Pea k Name : "M8PFOA{lS) " Mass(es) ; "421.0/376. 0 amu " 

### Comment " Annotation:" " Sampl eIndex ; 5 7 Sampl eType ; Unknown Concentration : 3.0 0i Calculate dConc : N/ A Acq
. Date : 7/20/201 1 Acq . Time : 4:07:0 4 P M Modified ; Proc . Algorithn : Min . Pea k Heigh t Min . Pea k Width : Smoothin g Width : R T Window ; Expecte d RT : Us e Relativ e RT : Int . Type : Retentio nTine : N o IntelliQua n- : 0.0 0 0.0 0 3 30. 0 9.5 7 N O Valle y 9.6 2 Area : 76090 6 c Height : Star t Tine : En d Time : 1.04e-»O0 5 9.4 1 10. 2 cp a

ae c poi n se c ni n

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9.S0e 4 g.00e 4 8.50e 4 8.00e4

- 7,S0e 4 7.OO0 4 6.S0e 4 6.00e 4 I
- S.S0e 4 

### i " S.0004

- i 4.S0e4

- 4.00e4

- 3.50e4

- 3.00e4

- 2.50e4

- 2-00e4

- 1.50o 4 1.00e4

- 5000.0 0 0.0 0 » r - I Sampl e Name ; "sl10719a056 " Sampl e ID ; "GLPl0-01-01-20-00 3 Lo wDA LS S BPMW4 7 0 OOO O La b Matri xSpik e Low " File : "s110719a.wifr ' Pea k Name ; "MBPF0A{IS) " Mass(es) ; "421.0^76. 0 amu " sampl e Index : sampl e Type : Concentration : Calculate d Conc : Acq . Date : Acq . Time : Modified : Proc . Algorithn : Min . Pea k Heigh t Min . Pea k Width : Smoothin g Width : R T Window : Expecte d RT : Us e Relativ e RT : Int . Type : Retentio n Tine : 5 6 Unknow n 3.0 0 ng/m L N/ A 7/20/201 1 3:42:5 2 P M N o IntelliQua n- IQ A 0.0 0 cp a 0.0 0 ae c 3 point a 30. 0 ae c 9.5 7 mi n N o Valle y 9.6 2 mi n Height : Star t Time ; En d Time : 1.166*00 5 cp s 9.4 0 mi n 10. 1 mi n 

# 1



# * 1.15e5- j I.IOeS
1.05e5

-

9.50e4

- 9 00e4

- 8.50e4

- 6.DOe4

-

6,S0e4

- 6.00e4

- 5.50e4

- 5.00e4

- 4.50e 4 4,00e4

- 3.50e4

- 3,00e 4 2.50e 4 2.00e 4 1.50e 4 1.00e 4 5000.0 0 0.0 0

Sampl e Index ; Sampl e Type : Concentration ; Calculate d Conc : Acq . Date : Acq . Time : Modified : Proc . Algorithm : Min . Pea k Heigh t Min . Pea k Width : Smoothin g Width : R T Window : Expecte d RT : Us e Relativ e RT : Int . Type : Retentio n Time : Area : Height : Star t Time : En d Time : 5 8 Doubl e Blan k 1.0 0 N/ A ng/n L 7/20/201 1 4:31:2 0 N o PM IntelliQua n - I Q : 0.0 0 0.0 0 3 30. 0 9.5 7 N o Valle y 9.7 0 cp a

ae c point a se c mi n

mi n 51 2 count s 9.37e-*00 1 9.5 3 9.8 0 cp s

mi n mi n



# Printin g Date : Wednesday , Jul y27 , 201 1 Printin g Time : 10:37:3 8 A M Pag e4 5 o f 4 6

## *Sta nV166Q30 5 

# *3 M Environmenta lLab Result s Name : sll0719a.rd b

I Sampl e Name : "sll0719a059 " Sampl e ID : "EC-110719-0 6 5 n g Extracte d Curv e Poin fFile : "s110719a.witr ' Pea k Name ; "M8PFOA(lS) " Mass(es) ; "421.0/376. 0 amu * I Comment" " Annotation : TM Sampl e Index : Sampl e Type : Concentration : Calculate d Conc : Acq . Date : Acq . Time : Modified : Proc . Algorithn : Min . Pea k Heigh t Min . Pea k Width : Snoothin g Width : R T Window : Expecte d RT ; Us e Relativ e RT : Int . Type : 5 9 Q C 3.0 0 N/ A 7/20/20 1 4:55:3 8 ng/n L

1 PM N o IntelllQua n- IQ A 0.0 0 0.0 0 3 30. 0 9.5 7 N o Valle y Retentio nTine : 9.6 3 Area : 81923 0 c Height : Star t Time : En d Time : i.ioe-t00 5 9.4 3 10. 1 cp a

se c point s ae c ni n

ni n aunt s cp a ni n ni n 

# i I.OOe S

9.S0e 4 9.00e 4 8.S0e4 ' 8,00e 4 7,S0e4

- 7.00e 4 6.S0e 4 6.00e 4 S.SDe 4 5.00e 4 4.50e 4 4.00e 4 3,50e 4 3 0004 2.S0e 4 2,00e 4 1.50o4

- 1.00e 4 5000.00

-

I Sanpl e Nanw : "s i 10719a061 " Sarrpl e ID : "1 0 006-16 8 solven tblank " File : "s110719a.wif r Pea k Name : "MePF0A<lS) " Mass(es) : "421.0/376. 0 amu " I Comment " Annotation : ~ Sampl e Index : Sampl e Type : Concentration : Calculate d Conc : Acq . Date : Acq . Time : Modified : Proc . Algorithm : Min . Pea k Heigh t Min . Pea k width : Smoothin g width : H T Window : Expecte d RT : Ds e Relativ e RT : Int . Type : Retentio nTime : Area : Height : Star t Time : En d Tine : 6 1 Doubl e Blan k 1.0 0 N/ A 7/20/20 ] 5:44:0 8 Ye s ng/m L 1 P M IntelliQua n- IQ A 0.0 0 0.0 0 3 30. 0 9.5 7 N o Valle y 9.4 1 11 1 c 2.90e-f00 1 9.3 2 9.4 6 cp s

se c point s se c mi n

mi n ount s cp s mi n mi n



# Printin g Date : Wednesday , Jul y27 , Printin g Time : 10:37:4 0A M Pag e4 6 o f 4 6