Exhaust Emissions Sampling Hanson Brick, Elgin, TX Kiln #1 Dry Scrubber Exhaust January 27, 2011 Armstrong Environmental, Inc. Project W-2658-11 Report Prepared For: Paul Anderson Hanson Brick 500 NE 14th Avenue Mineral Wells, TX 76067 Report Prepared February 17, 2011 By: Armstrong Environmental, Inc. 1748 Hlavek Rd. Decatur, Texas 76234 (214) 631-0021I. Introduction II. Summary III. Procedures N. Appendices TABLE OF CONTENTS A. Calculation Summaries B. Continuous Emission Monitor Summaries C. Field Data Sheets D. Equipment Calibrations E. Standard Gas Certifications F. Production Data G. Hydrogen Halides and Chlorine Analysis Summary I. Metals Analysis Summary

Page 1 2-5 6-9 10- 15 16-29 30-36 37-44 45-46 47 48-90 91 - 104I. INTRODUCTION A series oftests was performed on the exhaust associated with the Kiln #1 Dry Scrubber at the Hanson Brick facility in Elgin, TX on January 27, 2011. The purpose of this test series was to determine the exhaust emission rate ofHF, HCl, Cl2, Particulate and Metals. Testing followed procedures detailed in Title 40: Code of Federal Regulations

( 40:CFR). Sampling was perfom1ed by Lany Whicher and Tom Armstrong of Armstrong Environmental, Inc. using an Apex Method
5 sampling train, and a Teledyne Continuous 02 analyzer. Testing was performed according to the following schedule: Date Com_ponent Run Duration Start Time Finish Time 1/27/10 HF, HCl, C12 60 minutes 8:43AM 12:34 PM 1/27/10 Metals
60 minutes 1:18PM 5:14PM 1II. SUMMARY A series oftests was performed on the exhaust associated with the Kiln #1 Dry Scrubber at the Hanson Brick facility in Elgin, TX on January 27, 2011. Sampling was performed following procedures detailed in Title 40: Code of Federal Regulations. Results of this test series are summarized
in Tables 1 - 2. Production was maintained throughout testing at the following rates: 1. Brick Weight- 1552 grams/Brick 2. Brick/car

- 5200 3. Car/day- 18

2SUMMARY OF EMISSIONS TEST DATA Table

: 1 Plant

: Hanson Brick, Elgin, TX Location

: Kiln #1 Dry Scrubber Exhaust Operator

: L. Whicher.
T . Armstrong Test Date

: 27-Jan-11 Repetition

:

2

3 STACK GAS Temperature,

F 342.8
342

. 3 345

. 0 Velocity

, fps 19.82 18.99 18.88 Volume Flow, acfm 19983.4 19139.1 19034.5 scfm 12399.8 11742.8 11699.4 scfh 743987 704565 701964 Moisture

, %

5
. 67%

6
. 78%

6
. 30% C02

, %

3.25 2.75

2
. 50 02,%

17.11 17.03

17

. 52 SAMPLE Start Time, hrs:min 8:43AM 10:06 AM 11:30 AM Finish Time, hrs:min 9:47AM

11

: 11 AM 12:34 PM Sample Volume, scf 42.365 39.019

38

. 651 lsokinetic Ratio, % 102.0535

99

. 2533 98.67915 HYDROGEN FLUORIDE Sample Weight, mg 0.373 0.471 0.491 Concentration, ppm 0.373908

0
. 512631 0.539499 Concentration, ppm@ 7% 02 1.371325 1.841233 2.218652 Emissions

, lbs/hr

0
. 014444 0.018753

0
. 019663 Emissions

, gr/hr

12

. 06552 14.42828

14

. 98541 CHLORINE Sample Weight, mg (<0.025) (<0.025) (<0.025) Concentration, ppm (<0.007) (<0.008) (<0.008) Concentration, ppm @ 7% 02 (<0

. 026)
(<0

. 028)
(<0

. 032) Emissions, lbs/hr (<0.001) (<0.001) (<0.001) Emissions, gr/hr (<0.439) (<0.451) (<0.454) HYDROGEN CHLORIDE Sample Weight, mg 0.995 1.183 1.076 Concentration, ppm

0
. 546533

0 . 705514 0.647827 Concentration, ppm@ 7% 02 2.004435

2
. 534018 2.66414 Emissions, lbs/hr 0.038529 0.047101 0.04309 Emissions, gr/hr 17.47348

21

. 36118

19

. 54213 3Table 2 SUMMARY OF EMISSIONS TEST DATA Table:
2 Plant

: Hanson Brick, Elgin, TX Locat(on

: Kiln #1 Dry Scrubber Exhaust Operator

: L. Whicher, T. Armstrong Test Date

: 27-Jan-11 Repetition

: STACK GAS Temperature,

F 350.3 Velocity, fps
19.88 Volume Flow, acfm 20042.9 scfm 12342.6 seth 740554 Moisture,%
5.51% C02,%

2.50 02,%

16.85 SAMPLE Start Time, hrs:min 1:18PM Finish Time, hrs:min 2:22PM Sample Volume, scf 40.867 lsokinetic Ratio, % 98.90028 PARTICULATE Front Half Sample Weight, mg
7.55 Concentration, gr/scf 0.002851 Concentration, mg/dscm@ 7% 02 22.38946 Emissions, lbs/hr 0.301677 Emissions, gr/hr 136.815 Antimony Sample Weight, ug
6.00 Concentration, mg/dscm @ 7% 02 0.017793 Emissions, gr/hr 0.108727 Arsenic Sample Weight, ug (<2.20) Concentration, mg/dscm@ 7% 02 (<0.0065) Emissions, gr/hr (<0.0399) Berylium Sample Weight, ug (<1.00) Concentration, mg/dscm@ 7% 02 (<0.0030) Emissions, gr/hr (<0.0181) Cadmium Sample Weight, ug (<1.00) Concentration, mg/dscm @ 7% 02 <0.0030) Emissions

, gr/hr (<0.0181)

2 350.9 20.32 20483.9 12550.7 753040 5.90% 2.50 16.98 2:45PM 3 : 49PM 42.095 100.1831 7.55 0.002767 22.45713 0.297814 135.0632 (<5.00) (<0.0149) (<0.0894) (<2.1 0) (<0.0060) (<0

. 0376) (<0.90) (<0

. 0026) (<0

. 0161) 0.45 0.001296 0.00805 4

3 351.0 19.98 20143.0 12414.3 744859 5.36% 2.75 17.11 4:10PM 5:14PM 41.528 99.91998 8.94 0.003322 27.87901 0.353572 160.3501 (<5.00) (<0.0156) (<0.0897) (<2.20) (<0.0069) (<0.0395) (<1.00) (<0.0031) (<0.0179) 0.81 0.002526 0 . 014528Chromium Sample Weight, ug
5.80 Concentration, mg/dscm @ 7% 02 0.0172 Emissions, gr/hr 0.105103 Cobalt Sample Weight, ug (<1.00) Concentration, mg/dscm @ 7% 02 (<0.0030) Emissions, gr/hr (<0.0181) Lead Sample Weight, ug
2.50 Concentration, mg/dscm @ 7% 02 0.007414 Emissions, gr/hr 0.045303 Manganese Sample Weight, ug 226.60 Concentration, mg/dscm @ 7% 02 0.67198 Emissions, gr/hr

4
. 106261 Nickel Sample Weight, ug
5.70 Concentration, mg/dscm @ 7% 02 0.016903 Emissions, gr/hr 0.103291 Selenium Sample Weight, ug
4.10 Concentration, mg/dscm @ 7% 02
0 . 012159 Emissions, gr/hr

0 . 074297 Mercury Sample Weight, ug 17.22 Concentration, mg/dscm@ 7% 02 0.051066 Emissions, gr/hr 0.312047 Table 2 2 5 7.60 0.02188 0.135958 0.42 0 . 001209 0 . 007513 2.10 0.006046 0.037567 7.80 0.022456 0.139535 7.40 0.021304 0.13238 2.30 0.006622 0 . 041145 32.10 0.092415 0.574242
6.40 0 . 019958 0.114792 (<1

. 00) (<0

. 0031) (<0

. 0179) 2.30 0
. 007172 0.041253 35.00 0 . 109146 0
. 627769 3.80 0.01185 0.068158 3.20 0
. 009979 0 . 057396 19

. 82 0
. 061808 0
. 355497III. PROCEDURES The procedure for emissions sampling followed USEP A test methods as detailed in Title 40: Code of Federal Regulations

. The following methods were used: Method 2 3 3A 4 5 26A 29 Title Sample and Velocity Traverses for Stationary Sources Determination
of Stack Gas Velocity and Volumetric Flow Rate (Type S Pitot Tube) Gas Analysis for C02, 02, Excess Air and Dry Molecular Weight Determination
of Oxygen and Carbon Dioxide Concentrations

in Emissions from Stationary Sources (Instrumental Analyzer Procedure) Determination ofMoisture Content in Stack Gas Determination ofParticulate Emissions from Stationary Sources Determination ofHydrogen Halides and Halogen Emissions from Stationary Sources Determination
of Metals Emissions from Stationary Sources C02 was determined using PyRite Analyzers. Method 26A sampling was performed for 5 minutes at each of 12 points,
6 points per traverse, making

a total run duration of 60 minutes. The sampling train was configured
as follows: Glass Sample Nozzle Heated Glass lined probe Heated Teflon filter Impinger #1 - 100 mls 0.1 N H2S04 Impinger #2 - 100 mls 0.1 N H2S04 Impinger #3 - 100 **m~s** 0.1 N NaOH Impinger#4- 100 mls 0.1 NNaOH Impinger #5 - 200 grams silica Gel Analysis for HF and HCl was perfom1ed on the solution from the 1st and 2nd impingers. Analysis for Cl2 ,;r, , as perfonned on the solution from 3rd and 4th impingers. Analysis was perfom1ed using
a Dionex LC20 HPLC/Ion Chromatograph
by Am1strong Environnmeta1, Inc.

6Method 29 sampling was performed for 5 minutes at each of 12 points,
6 points per traverse, making

a total run duration of 60 minutes. The sampling train was configured
as follows: Glass Sample Nozzle Heated Glass lined probe Heated Quartz Fiber filter Impinger #1- 100 mls 5% HN03110% H202 Impinger #2 - 100 mls 5% HN0311 0% H202 Impinger #3- 100 mls 4% K.Mn04110% H2S04 Impinger #4 - 100 mls 4% K.Mn04/1 0% H2S04 Impinger #5 - 200 grams silica Gel The probe was washed with acetone and recovered, then washed with 0 . 1 N HN03, recovered separately. PM was determined from the probe wash and filter, then both were digested and analyzed for metals. Metals and mercury was determined from the probe wash, filter, and the solution from the 1st and 2nd impingers. Mercury was also analyzed in the solution from the 3rd and 4th impingers. Metals analyzed for were beryllium, antimony, arsenic, cadmium, chromium, cobalt, manganese, mercury, selenium and nickel. 02 was determined using
a Teledyne continuous 02 analyzer. The analyzer was calibrated with 9.01 %, and 20%02 in N2 EPA Protocol! gas standards

, zeroed with N2. Sampling was perfonned for five minutes at each of 12 points,
6 points per port. 7

# Figure 1 - Kiln #1 

# Dry Scrubber Exhaust

612inches

() 

# ' 1h 

# 423inches



# co Cyc l one C EMS and Sampling Traverse Point s

**~**



# ~\ //// 

# / \ 

# /1 2 3 4 

# 5 6\ ,//



# ,// Stack Diameter- 55 . 5 in c hes Point #1 - 2.4 inche s Point #2- 8.1 inches Point #3- 16.4 inches Point #4- 3 9.1 inches Point #5 - 4 7.4 inches Point #6- 53.1 inches

# \.0 

# Figure 2- GEM Configuration Heated Frobg Heated Filter 

# I Heated 

# Sample Line

'---- --.,r-, '._

j 

# Heated 

# S ampl e Pump


# Bias Calibration Span Line P rocess or

**{~**

**'** 

# \._/ Purnp 02 .1\na l yzer
F l ovv meter :alibration PointAppendixAEMISSION TEST SUMMARY PLANT: Hanson Brick, Elgin, TX DATE: 27-Jan-11 PLACE

: Kiln #1 Dry Scrubber Exhaust RUN#:

1 TEST DURATION (MINUTES)

:
60 LIQUID COLLECTED (mls) NOZZLE DIAMETER (INCH.)

: 0.4147 PARTICULATE WEIGHT (Front half mg)

: METER COEFFICIENT (Y)

: 0.995 PARTICULATE WEIGHT (Back half mg): PITOT COEFFICIENT (Cp)

: 0.84 STATIC PRESSURE (in. H20): GAS METER VOL.(Cu.Ft.)

: 41.652 PERCENT C02 BAROMETRIC PRESSURE 29.95 PERCENT02 PERCENT CO FOR CIRCULAR STACK
FOR RECTANGULAR STACK STACK DIAMETER (inch): 55.5 STACK LENGTH(inchs): STACK AREA (Sq.Ft.)

: 16.80016 STACK WIDTH(inchs)

: NOZZLE AREA (feet): 0.000938 STACK AREA (Sq.Ft.): ENTER THE STACK AREA SHOWN ABOVE: 16.8002 FLOWS SAMPLED VOLUME (STD. CU.FT.): VOLUME OF WATER VAPOR (STD. CU. FT.): FRACTIONAL MOISTURE CONTENT(%): DRY BASE: MOLECULAR WT. OF STACK GAS (DRY BASE): MOLECULAR WT

. OF STACK GAS (WET BASE): STACK PRESSURE (inch Hg): STACK GAS VELOCITY (ft/sec.): ACTUAL STACK GAS FLOW RATE (ACFM): STANDARD STACK GAS FLOW RATE (SCFH): ISOKINETIC RATIO(%): POINTS STACK T. DELTA
P SQUAR D.F DELTA H deg F 1 342 0.08 0.28284 1.20 2 345 0.09 0.3 1. 40 3 345 0.10 0.31623 1.55 4 345 0.09 0.3 1. 40 5 344 0.09 0.3 1.40 6 336 0.07 0.26458 1.10 7 335 0.08 0.28284 1.20 8 347 0.09 0.3 1.40 g 347 0.08 0.28284 1.20 10 348 0.08 0.28284 1.20 11 345 0.08 0.28284 1.20 12 334 0.05 0.22361 0.78 342.75 0.2849 1.2525 42.3652 2.5465 0.0567 79.6400 29.2044 28.5691 29

. 9228 19

. 8246 19983.4253 743986.768 102.0535 METER
T . INLET 46 59 62 64 65 66 56 68 69 71 72 73 64

. 2500 METER T. OUTLET 46 46 48 49 51 52 53 54 56 57 59 60 52.5833 54.1 0 0 -0.37 3.25 17.11 0 0 58.4167

-- li . 1. 'JEMISSIONTESTSUMMARYPLANT:HansonBrick,Elgin,TXDATE:27-Jan-11PLACE:Kiln#1DryScrubberExhaustRUN#:2TESTDURATION(MINUTES):60LIQUIDCOLLECTED(mls)NOZZLEDIAMETER(INCH.):0.4147PARTICULATEWEIGHT(Fronthalfmg):METERCOEFFICIENT(Y):0.995PARTICULATEWEIGHT(Backhalfmg):PITOTCOEFFICIENT(Cp):0.84STATICPRESSURE(in.H20):GASMETERVOL.(Cu.Ft.):39.762PERCENTC02BAROMETRICPRESSURE29.95PERCENT02PERCENTCOFORCIRCULARSTACKFORRECTANGULARSTACKSTACKDIAMETER(inch):55.5STACKLENGTH(inches):STACKAREA(Sq.Ft.):16.80016STACKWIDTH(inches):NOZZLEAREA(feet):0.000938STACKAREA(Sq.Ft.):ENTERTHESTACKAREASHOWNABOVE:16.8002FLOWSSAMPLEDVOLUME(STD.CU.FT.):VOLUMEOFWATERVAPOR(STD.CU.FT.):FRACTIONALMOISTURECONTENT(%):DRYBASE:MOLECULARWT.OFSTACKGAS(DRYBASE):MOLECULARWT.OFSTACKGAS(WETBASE):STACKPRESSURE(inchHg):STACKGASVELOCITY(ft/sec.):ACTUALSTACKGASFLOWRATE(ACFM):STANDARDSTACKGASFLOWRATE(SCFH):ISOKINETICRATIO(%):POINTSSTACKT.DELTAPSQUARD.FDELTAHdegF1341.0.070.264581..1.023440.080.282841.2033440.080.282841.2043430.282841.2053420.080.282841.2063370.060.244950.9373380.070.264581.1.083450.080.282841.2093460.080.282841.20103450.080.282841.20113440.070.264581.10123380.060.244950.93342.250.27201.130039.01942.83830.067880.220029.121228.367129.921318.987019139.1067704565.45399.2533METERT.INLET72787981828373848686888981.7500METERT.OUTLET63896567696977727374767772.583360.300-0.392.7517.030077.1667EMISSION TEST SUMMARY PLANT: Hanson Brick, Elgin, TX DATE: **27-Jan-~~** PLACE

: Kiln #1 Dry Scrubber Exhaust RUN#:

3 TEST DURATION (MINUTES):

60 LIQUID COLLECTED (mls) NOZZLE DIAMETER (INCH.)

: 0.4147 PARTICULATE WEIGHT (Front half mg): METER COEFFICIENT
(Y)

: 0.995 PARTICULATE WEIGHT (Back half mg)

: PITOT COEFFICIENT (Cp)

: 0.84 STATIC PRESSURE (in. H20): GAS METER VOL.(Cu.Ft.)

: 40.057 PERCENT C02 BAROMETRIC PRESSURE 29.95 PERCENT 02 PERCENT CO FOR CIRCULAR STACK
FOR RECTANGULAR STACK STACK DIAMETER (inch): 55.5 STACK LENGTH(inchs)

: STACK AREA (Sq.Ft.)

: 16.80016 STACK WIDTH(inchs)

: NOZZLE AREA (feet): 0.000938 STACK AREA (Sq. Ft.): ENTER THE STACK AREA SHOWN ABOVE: 16.8002 FLOWS SAMPLED VOLUME (STD. CU.FT.): VOLUME OF WATER VAPOR (STD. CU.FT.): FRACTIONAL MOISTURE CONTENT(%): DRY BASE: MOLECULARWT.
OF STACK GAS (DRY BASE): MOLECULAR WT. OF STACK GAS (WET BASE): STACK PRESSURE (inch Hg): STACK GAS VELOCITY (ft/sec.)

: ACTUAL STACK GAS FLOW RATE (ACFM): STANDARD STACK GAS FLOW RATE (SCFH): ISOKINETIC RATIO(%): POINTS STACKT. DELTA
P SQUAR D.F DELTA H deg F 1 335 0.07 0.26458 1.10 2 347 0.08 0.28284 1.20 3 347 0.08 0.28284 1.30 4 347 0.08 0.28284 1.30 5 347 0.07 0.26458 1.10 6 346 0.06 0.24495 0.97 7 341 0.08 0.28284 1.30 8 349 0.08 0.28284 1.30 9 350 0.08 0.28284 1.30 10 349 0.08 0.28284 1.30 11 347 0.07 0.26458 1.10 12 335 0.05 0.22361 0.81 345 0.2702 1.1733 38.6505 2.5983 0.0630 79.9800 29.1008 28.4016 29.9228 18

. 8832 19034.4742 701964.133 98.6791 METER T. INLET 79 88 90 91 92 92 85 93 93 94 94 95 90.5000 METER T. OUTLET 79 79 80 81 81 82 83 83 84 85 85 85 82.2500 55.2 0 0 -0.37 2.5 17.52 0 0 86

. 3750EMISSIONTESTSUMMARYPLANT:HansonBrick,Elgin,TXDATE:27-Jan-11PLACE:Kiln#1DryScrubberExhaustRUN#:4TESTDURATION(MINUTES):60LIQUIDCOLLECTED(mls)NOZZLEDIAMETER(INCH.):0.4147PARTICULATEWEIGHT(Fronthalfmg):METERCOEFFICIENT(Y):0.995PARTICULATEWEIGHT(Backhalfmg):PITOTCOEFFICIENT(Cp):0.84STATICPRESSURE(in.H20):GASMETERVOL.(Cu.Ft.):42.282PERCENTC02BAROMETRICPRESSURE29.95PERCENT02PERCENTCOFORCIRCULARSTACKFORRECTANGULARSTACKSTACKDIAMETER(inch):55.5STACKLENGTH(inchs):STACKAREA(Sq.Ft.):16.80016STACKWIDTH(inchs):NOZZLEAREA(feet):0.000938STACKAREA(Sq.Ft.):ENTERTHESTACKAREASHOWNABOVE:16.8002FLOWSSAMPLEDVOLUME(STD.CU.FT.):VOLUMEOFWATERVAPOR(STD.CU.FT.):FRACTIONALMOISTURECONTENT(%):DRYBASE:MOLECULARWT.OFSTACKGAS(DRYBASE):MOLECULARWT.OFSTACKGAS(WETBASE):STACKPRESSURE(inchHg):STACKGASVELOCITY(fUsee.):ACTUALSTACKGASFLOWRATE(ACFM):STANDARDSTACKGASFLOWRATE(SCFH):PARTICULATEFRONTHALFPARTICULATECONCENTRATION(GR./SCF):PARTICULATECONCENTRATION(LBS/SCF):PARTICULATEEMISSION(LBS/HR):ISOKINETICRATIO(%):POINTSSTACKT.DELTAPSQUARD.FDELTAHdegF13390.080.282841.3023510.080.282841.3033580.080.282841.3043550.080.282841.3053530.070.264581.1063420.060.244950.9773460.080.282841.3083530.090.31.4593540.090.31.45103550.090.31.45113560.090.31.45123410.080.282841.30350.250.28391.305840.86672.38170.055180.650029.074028.464129.922119.883720042.9362740553.5650.00294.07E-070.301798.9003METERT.INLET83899091919188898988888788.6667METERT.OUTLET83848484848388818180807982.583350.67.550-0.382.516.850085.62501'')•.!,...JEMISSIONTESTSUMMARYPLANT:HansonBrick,Elgin,TXDATE:27-Jan-11PLACE:Kiln#1DryScrubberExhaustRUN#:5TESTDURATION(MINUTES):60LIQUIDCOLLECTED(mls)NOZZLEDIAMETER(INCH.):0.4147PARTICULATEWEIGHT(Fronthalfmg):METERCOEFFICIENT(Y):0.995PARTICULATEWEIGHT(Backhalfmg):PITOTCOEFFICIENT(Cp):0.84STATICPRESSURE(in.H20):GASMETERVOL.(Cu.Ft.):43.165PERCENTC02BAROMETRICPRESSURE29.95PERCENT02PERCENTCOFORCIRCULARSTACKFORRECTANGULARSTACKSTACKDIAMETER(inch):55.5STACKLENGTH(inches):STACKAREA(Sq.Ft.):16.80016STACKWIDTH(inches):NOZZLEAREA(feet):0.000938STACKAREA(Sq.Ft.):ENTERTHESTACKAREASHOWNABOVE:16.8002FLOWSSAMPLEDVOLUME(STD.CU.FT.):VOLUMEOFWATERVAPOR(STD.CU.FT.):FRACTIONALMOISTURECONTENT(%):DRYBASE:MOLECULARWT.OFSTACKGAS(DRYBASE):MOLECULARWT.OFSTACKGAS(WETBASE):STACKPRESSURE(inchHg):STACKGASVELOCITY(ft/sec.):ACTUALSTACKGASFLOWRATE(ACFM):STANDARDSTACKGASFLOWRATE(SCFH):PARTICULATEFRONTHALFPARTICULATECONCENTRATION(GR./SCF):PARTICULATECONCENTRATION(LBS/SCF):PARTICULATEEMISSION(LBS/HR):ISOKINETICRATIO(%):POINTSSTACKT.DELTAPSQUARD.FDELTAHdegF13490.080.282841.3023570.090.31.4533560.090.31.4543550.090.31.4553530.090.31.4563440.070.264581.1073490.080.282841.3083530.090.31.4593550.090.31.45103540.090.31.45113530.080.282841.30123330.070.264581.10350.9166670.28981.354242.09482.64060.059080.520029.079228.425229.921320.321220483.9251753040.2440.00283.95E-070.2978100.1831METERT.INLET74848586878782878887878785.0833METERT.OUTLET74757576767777777878787876.583356.17.550-0.392.516.980080.8333-<''1_4PLANT DATE PLACE RUN# EMISSION TEST SUMMARY Hanson Brick, Elgin, TX 27-Jan-11 Kiln #1 Dry Scrubber Exhaust 6 TEST DURATION (MINUTES) NOZZLE DIAHETER (INCH.) METER COEFFICIENT (Y) PITOT COEFFICIENT (Cp) GAS METER VOL. (Cu.Ft.) BAROMETRIC PRESSURE

60 0.4147 0.995 0.84 42.391 29.95 LIQUID COLLECTED (mls) PARTICULATE WEIGHT (Front half mg PARTICULATE rffiiGHT (Back half mg) STATIC PRESSURE (in. H20) PERCENT C02 PERCENT 02 PERCENT CO FOR CIRCULAR STACK STACK DIAMETER (inch)

: STACK AREA (Sq. Ft . ) NOZZLE AREA (feet): 55.5 16.8002 0. 00094 FOR RECTANGULAR STACK STACK LENGTH(inchs) STACK WIDTH(inchs) STACK AREA (Sq. Ft.
) ENTER THE STACK AREA SHOWN ABOVE: 16.8002 FLOWS S}I.MPLED VOLUHE (STD. CU. FT

. ) : VOLUME OF WATER VAPOR (STD. CU.FT.): FRACTIONAL MOISTURE CONTENT (%): DRY BASE: MOLECULAR WT. OF STACK GAS (DRY BASE): MOLECULAR WT. OF STACK GAS (WET BASE): STACK PRESSURE (inch Hg): STACK GAS VELOCITY (ft/sec.): ACTUAL STACK GAS FLOW RATE (AC:FM)

: STANDARD STACK GAS FLOW RATE (SCFH): PARTICULATE FRONT HALF PARTICULATE CONCENTRATION (GR./SCF): PARTICULATE CONCENTRATION (LBS/SCF): PARTICULATE EMISSION (I,BS/HR): ISOKINETIC RATIO (%): POINTS STACK T. DELTA
P SQUAR D.P DELTA H deg F 1 345 0.08 0.28284

1. 30 2 354 0.09 0.3 1. 45 3 354 0.08 0.28284

1. 30 4 354 0.08 0.28284

1. 30 5 353 0.08 0.28284

1. 30 6 354 0.07 0. 26458 1.10 7 344 0.08 0.28284 1.30 8 356 0.09 0.3 1. 45 9 356 0.09 0.3 1.45 1 0 356 0.09 0.3 1. 45 11 355 0.08 0.28284

1. 30 1 2 331 0.07

0 . 26458 1.10 351 0.2855
1. 31 67 41.5281 2.3535 0.0536 80.1400 29.1244 28.5278 29.9287 19.9830 20143.007 744859.17 0.0033 4.75E-07 0.3536 99.9200 METER T. INLET 74 83 83 83 84 84 79 84 84 84 85 85 82.6667 HETER T. OUTLET 74 74 74 74 74 74 74 74 74 74 74 74 74.0000
50 8.94 0 -0.29 2.75 17.11 0 0 78.3333
15AppendixBSheet1Summaryof02AnalyzerCalibrationsandBiasPlant:HansonBrick,Elgin,TXSource:Kiln#1DryScrubberExhaustDate:1/27/2011AnalyzerCalibratrionDataCylinderAnalyzerAbsolute%SpanValueResponseDifferenceZeroGas00.050.050.25LowRange9.019.080.070.35MidRange2020.130.130.65SystemCalibrationBiasandDriftDataAnalyzerInitialValuesFinalValuesDriftAverageCalibrationSystemSystemSystemSystemCalibrationResponseCalibrationCalibrationCalibrationCalibrationValuesResponseBiasResponseBiasRun#1ZeroGas0.050.441.950.371.6-0.350.405Upscale9.089.150.359.2810.659.215Average02Concentration:17.14Corrected02Concentration:17.11491Run#2ZeroGas0.050.371.60.311.3-0.30.34Upscale9.089.2819.291.050.059.285Average02Concentration:17.25Corrected02Concentration:17.03288Run#3ZeroGas0.050.311.30.311.300.31Upscale9.089.291.059.351.350.39.32Average02Concentration:17.83Corrected02Concentration:17.52Run#4ZeroGas0.050.311.30.341.450.150.325Upscale9.089.351.359.160.4-0.959.255Average02Concentration:17.03Corrected02Concentration:16.85465Run#5ZeroGas0.050.341.450.341.4500.34Upscale9.089.160.49.140.3-0.19.15Average02Concentration:16.94Corrected02Concentration:16.97684Run#6ZeroGas0.050.341.450.441.950.50.39Upscale9.089.140.39.080-0.39.11Average02Concentration:16.95Corrected02Concentration:17.11073Page1if.LI1/27/11 Calibrations Date/Time
02 mm/dd/yy hh:mm:ss
% 01/27/11 07:41:06 20.81 01/27/11 07:42:06 8.80 01/27/11 07:43:06 19.61 01/27/11 07:44:06 14.84 01/27/11 07:45:06 0.55 01/27/11 07:46:06 

### 0.05 Zero N2 01/27/11 07:47:06 0.06 01/27/11 07:48:06 5.79 01/27/11 07:49:06 9.16 01/27/11 07:50:06 

### 9.08 9.0T% 02 01/27/11 07:51:06 12.91 01/27/11 07:52:06 20.26 01/27/11 07:53:06 

### 20.13 20%02 01/27/11 07:54:06 20.28 01/27/11 07:55:06 20.93 01/27/11 07:56:06

19

. 52 01/27/11 07:57:06 2.71 01/27/11 07:58:06 0.54 01/27/11 07:59:06 0.45 01/27/11 08:00:06 

### 0.44 Zero N2 Bias 01/27/11 08:01:06 1.57 01/27/11 08:02:06 10.45 01/27/11 08:03:06 

### 9.15 9.0f% 02 Bias 01/27/11 08:04:06 9.23 Page 1

(\
....
. 

# 17Date/Time
02 mm/dd/yy hh:mm:ss
% 01/27/11 08:42:06 Start Run #1 01/27/11 08:43:06 01/27/11 08:44:06 01/27/11 08:45:06 01/27/11 08:46:06 01/27/11 08:47:06 01/27/11 08:48:06 01/27/11 08:49:06 01/27/11 08:50:06 01/27/11 08:51 :06 01/27/11 08:52:06 01/27/11 08:53:06 01/27/11 08:54:06 01/27/11 08:55:06 01/27/11 08:56:06 01/27/11 08:57:06 01/27/11 08:58:06 01/27/11 08:59:06 01/27/11 09:00:06 01/27/11 09:01 :06 01/27/11 09:02:06 01/27/11 09:03:06 01/27/11 09:04:06 01/27/11 09:05:06 01/27/11 09:06:06 01/27/11 09:07:06 01/27/11 09:08:06 01/27/11 09:09:06 01/27/11 09:10:06 01/27/11 09:11:06 01/27/11 09:12:06 Port Change 01/27/11 09:13:06 01/27/11 09:14:06 01/27/11 09

: 15:06 01/27/11 09:16:06 Resume 01/27/11 09:17:06 01/27/11 09:18:06 01/27/11 09:19:06 01/27/11 09:20:06 01/27/11 09:21:06 01/27/11 09:22:06 01/27/11 09:23:06 01/27/11 09:24:06 01/27/11 09:25:06 01/27/11 09:26:06 17.20 17.36 17.20 16.96 16

. 80 17.19 17.15 16.99 17.10 18.07 18.63 17.68 16.57 16.50 16.72 16

. 78 16.65 16.64 16.55 16.70 16.70 16.67 16.59 16.48 16.57 16.66 16.72 16.73 16.88 16.77 17.26 20.48 20.65 17.54 17.23 17.40 17.54 17.57 17.47 17.55 17.85 17.72 17.56 17

. 38 17

. 05 1/27/11 Run #1 Page 1

1 0 01/27/11 Run #1 01/27/11 09:27:06 17.32 01/27/11 09:28:06 17.56 01/27/11 09:29:06 :7.08 01/27/11 09:30:06 16.99 01/27/11 09:31:06 18.15 01/27/11 09:32:06 18.69 01/27/11 09:33:06 18.06 01/27/11 09:34:06

17

. 05 01/27/11 09:35:06 16.97 01/27/11 09:36:06 17.26 01/27/11 09:37:06 17.23 01/27/11 09:38:06 17.18 01/27/11 09:39:06 17.01 01/27/11 09:40:06 17.09 01/27/11 09:41:06 17.02 01/27/11 09:42:06 17.11 01/27/11 09:43:06 16.86 01/27/11 09:44:06 16.74 01/27/11 09:45:06 16.79 01/27/11 09:46:06 16.96 Stop Run #1

17

. 14 01/27/11 09:47:06 16.96 01/27/11 09:48:06 19.71 01/27/11 09:49:06 3.63 01/27/11 09:50:06 0.51 01/27/11 09:51:06 0.37 Zero N2 01/27/11 09:52:06 2.09 01/27/11 09:53:06 9.51 01/27/11 09:54:06 9.28 9.01%02 Page 2

191/27/11 Run #2 Date/Time
02 mm/dd/yy hh:mm:ss
% 01/27/11 10:05

: 06 17

. 12 Start Run #2 01/27/1110:06:06

17

. 34 01/27/1110:07:06

17

. 32 01/27/1110:08:06 17.21 01/27/1110:09:06 17.19 01/27/1110:10

: 06 17

. 11 01/27/1110:11:06 18.32 01/27/1110:12:06 18.86 01/27/11 10

: 13

: 06
17

. 86 01/27/1110:14

: 06 16

. 82 01/27/1110:15:06

16

. 88 01/27/1110:16

: 06 16

. 89 01/27/1110:17:06 17.04 01/27/1110:18:06 16.94 01/27/1110:19

: 06 16

. 89 01/27/11 10:20

: 06 16

. 86 01/27/11 10:21 :06 16.80 01/27/11 10:22:06 16.78 01/27/11 10:23

: 06 16

. 77 01/27/11 10:24:06 16.83 01/27/11

1 **0:25:0~**

16

. 84 01/27/11 10:26:06 16.78 01/27/1110:27:06

16

. 70 01/27/1110:28:06

16

. 79 01/27/11 10:29:06 16.89 01/27/1110:30

: 06 16.91 01/27/11 10:31

: 06 16

. 68 01/27/1110:32:06 16.62 01/27/1110:33

: 06 16.82 01/27/1110:34:06

17

. 06 01/27/1110

: 35:06 17.10 Port Change 01/27/11 10:36

: 06 17

. 51 01/27/11 10:37

: 06
21

. 13 01/27/1110:38:06 21.28 01/27/1110:39

: 06 18

. 52 Resume 01/27/11 10:40

: 06 17.50 01/27/1110:41:06 17.20 01/27/11 10:42:06

17

. 19 01/27/11 10:43:06

17

. 33 01/27/11 10:44:06

17

. 53 01/27/11

1 0:45

: 06 17.51 01/27/1110:46

: 06 17.22 01/27/1110:47:06 17.25 01/27/11 10:48

: 06 17.39 01/27/11 10:49:06 17.75 Page
1i/27/11 Run #2 01/27/11 10:50:06 17.74 01/27/11 10:51 :06 18.51 01/27/1110:52:06 19.11 01/27/11 10:53:06 18.53 01/27/11 10:54:06 17.34 01/27/11 10:55:06 17.22 01/27/11 10:56:06 17.21 01/27/11 10:57:06 17.34 01/27/11 10:58:06

17

. 46 01/27/11 10:59:06 17.27 01/27/1111:00:06 17.23 01/27/11 11:01:06 16.87 01/27/11 11:02:06 17.03 01/27/11 11 :03:06 17.14 01/27/1111:04:06 17.27 01/27/11 11 :05:06 17.25 01/27/11 11:06:06 17.21 01/27/11 11 :07:06 16.99 01/27/11 11:08:06 17.12 01/27/11 11:09:06 17.30 01/27/1111:10:06 17.14 Stop Run #2 17.25 01/27/11 11:11:06 17.10 01/27/1111:12:06 20.73 01/27/1111:13:06 11.12 01/27/1111:14:06
0.64 01/27/11 11:15

: 06 0.31 Zero N2 01/27/1111:16:06
2.16 01/27/11 11:17:06 10.51 01/27/1111:18:06 10.03 01/27/1111:19:06 9.29 9.01% 02 Page 21/27/11 Run #3 Date/Time
02 mm/dd/yy hh:mm:ss
% 01/27/11 11

: 29

: 06 17.64 Start Run #3 01/27/11 11 :30:06
17

. 72 01/27/1111:31:06 18.85 01/27/11 11 :32

: 06 19.48 01/27/11 11:33:06 18.71 01/27/1111:34:06

17

. 58 01/27/11 11:35:06

17

. 38 01/27/1111:36:06

17

. 55 01/27/11 11:37:06

17

. 50 01/27/11 11 :38

: 06 17

. 53 01/27/11 11:39:06 17.40 01/27/1111:40:06 17.26 01/27/11 11:41:06 17.45 01/27/11 11:42:06 17.46 01/27/11 11:43:06 17.50 01/27/1111

: 44

: 06 17

. 49 01/27/11 11:45:06 17.41 01/27/11 11:46:06 17.41 01/27/1111

: 47

: 06 17

. 57 01/27/11 11:48:06 17.42 01/27/11 11:49:06 17.45 01/27/11 11:50:06 17.32 01/27/11 11:51:06

17

. 42 01/27/11 11:52:06

17

. 54 01/27/11 11 :53:06 17.68 01/27/11 11:54:06 17.80 01/27/11 11:55

: 06 17.99 01/27/11 11 :56:06
17

. 97 01/27/11 11 :57:06
18

. 03 01/27/1111:58:06

18

. 17 01/27/1111

: 59

: 06 18

. 17 Port Change 01/27/11 12:00:06

20

. 90 01/27/11 12:01

: 06 21.95 01/27/11 12:02

: 06 20

. 00 01/27/11 12

: 03

: 06 18.29 Resume 01/27/11 12:04:06 18.04 01/27/11 12:05:06 17.98 01/27/11 12:06:06

18

. 30 01/27/11 12:07:06 18.28 01/27/11 12:08:06

18

. 35 01/27/11 12:09:06 18.14 01/27/1112:10:06

18

. 01 01/27/11 12:11

: 06 18.90 01/27/11 12:12

: 06 19

. 79 01/27/1112:13:06

19

. 10 P!:ll1P

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11/27/11 Run #3 01/27/11 12:14:06 18.05 01/27/1112:15:06 17.80 01/27/11 12:16:06 17.92 01/27/11 12:17:06 17.74 01/27/1112:18:06 17.68 01/27/11 12:19:06 17.71 01/27/1112:20:06 17.39 01/27/1112:21:06 17.64 01/27/11 12:22:06 17.74 01/27/11 12:23:06 17.54 01/27/11 12:24:06 17.40 01/27/11 12:25:06 17.47 01/27/1112:26:06 17.56 01/27/11 12:27:06 17.50 01/27/1112:28:06 17.41 01/27/11 12:29:06 17.59 01/27/11 12:30:06 17.43 01127/11 12:31:06 17.55 01/27/11 12:32:06 17.72 01/27/1112:33:06 17.75 Stop Run #3 17.83 01/27/11 12:34:06 17.52 01/27/11 12:35:06 17.49 01/27/11 12:36:06 9.81 01/27/11 12:37:06 1.15 01/27/11 12:38:06 0.53 01/27/11 12:39:06 0.39 01 t?7t11

1 ?·A.n·nR 0.31 7P.rn N? 01/27/11 12:41:06 5.36 01/27/11 12:42:06 9.35 9.01%02 Page 2

2 •") ,., ,j1/27/11 Run #4 Date/Time
02 mm/dd/yy hh:mm:ss
% 01/27/1113:17:06 16.77 Start Run #4 01/27/1113:18:06 17.10 01/27/11 13:19:06 17.05 01/27/11 13:20:06 16.97 01/27/1113:21:06 16.86 01/27/1113:22:06 17.02 01/27/1113:23:06 17.16 01/27/11 13:24:06 17.07 01/27/11 13:25:06 16.98 01/27/11 13:26:06 16.94 01/27/1113:27:06 16.93 01/27/11 13:28:06 17.32 01/27/1113:29:06 17.16 01/27/11 13:30:06 16.89 01/27/1113:31:06 17.47 01/27/1113:32:06 18.55 01/27/1113:33:06 18.15 01/27/1113:34:06 17.16 01/27/1113:35:06 16.81 01/27/11 13:36:06 16.96 01/27/11 13:37:06 16.80 01/27/11 13:38:06 16.95 01/27/11 13:39:06 16.83 01/27/11 13:40:06 16.87 01/27/1113:41:06 16.47 01/27/11 13:42:06

16

. 53 01/27/11 13:43:06 16.83 01/27/11 13:44:06 16.80 01/27/1113:45:06

16

. 60 01/27/11 13:46:06 16.43 01/27/11 13:47:06

16

. 68 Port Change 01/27/11 13:48:06 18.89 01/27/11 13:49:06 20.97 01/27/11 13:50:06 19.32 01/27/11 13:51 :06 16.75 Resume 01/27/1113:52:06 16.70 01/27/11 13:53:06 17.00 01/27/11 13:54:06 16.98 01/27/1113:55:06

16

. 82 01/27/1113:56:06 16.56 01/27/1113:57:06 17.04 01/27/11 13:58:06 17.22 01/27/11 13:59:06 17.32 01/27/11 14:00:06 17.20 01/27/11 14:01:06 16.64 Page 11/27/11 Run #4 01/27/11 14:02:06 16.89 01/27/11 14:03:06 17.27 01/27/1114:04:06 17.33 01/27/1114:05:06 17.24 01/27/1114:06:06 16.89 01/27/1114

: 07:06 16.80 01/27/11 14:08:06 17.26 01/27/11 14:09:06 17.32 01/27/1114

: 10

: 06 17

. 10 01/27/1114:11:06 17.50 01/27/1114:12:06 18.60 01/27/1114:13

: 06 18.12 01/27/11 14:14:06 16.88 01/27/1114:15:06 16.58 01/27/11 14:16:06

16

. 64 01/27/1114:17:06 16.68 01/27/1114:18:06 16.64 01/27/1114:19:06 16.80 01/27/1114:20

: 06 16.81 01/27/11 14:21:06 16.75 01/27/11 14:22:06

16

. 89 Stop Run #4 17.03 01/27/1114:23:06

19

. 93 01/27/11 14:24:06 20.95 01/27/11 14:25:06 14.82 01/27/1114:26:06
1.67 01/27/11 14

: 27:06 0.44 01/27/1114:28:06
0.39 01/27/11 14:29:06 0.34 Zero N2 01/27/11 14:30

: 06 4.51 01/27/1114:31:06
9.11 01/27/11 14:32:06 9.16 9.01% 02 Page 21127/11 Run#5 Daternme
02 mm/dd/yy hh:mm:ss
% 01/27/1114:44:06 17.25489 Start Run #5 01/27/11 14:45:06 17.07081 01/27/11 14:46:06 17.03419 01/27/11 14:47:06 17.02149 01/27/1114:48:06 17.06593 01/27/1114:49:06 17.19923 01/27/11 14:50:06 17.25489 01/27/11 14:51 :06 17.43946 01/27/11 14:52:06 18.60792 01/27/1114:53:06 18.21339 01/27/11 14:54:06 17.21388 01/27/11 14:55:06 16.65333 01/27/11 14:56:06 16.66114 01/27/1114:57:06 16.80323 01/27/1114:58:06 16.81056 01/27/1114:59:06 16.72804 01/27/11 15:00:06 16.65285 01/27/11 15:01 :06 16.6216 01/27/1115:02:06 16.66456 01/27/1115:03:06 16.74415 01/27/11 15:04

: 06 16.82568 01/27/11 15:05:06 16.98193 01/27/11 15:06:06 16.70166 01/27/11 15:07:06 16.86377 01/27/11 15:08:06 16.93799 01/27/1115:09:06 16.97315 01/27/1115:10:06 16.94531 01/27/1115:11:06 16.93946 01/27/1115:12:06 17.06543 01/27/1115:13:06 17.13721 01/27/1115:14:06 17.23096 Port Change 01/27/11 15:15:06 17.16309 01/27/11 15:16:06 19.96045 01/27/1115:17:06 20.87842 01/27/1115:18:06 18.98292 Resume 01/27/11 15:19:06 16.91309 01/27/11 15:20:06 16.73633 01/27/1115:21:06 16.79005 01/27/11 15:22:06 16.8418 01/27/11 15:23:06 16.85352 01/27/11 15:24:06 16.98096 01/27/1115:25:06 16.78272 01/27/11 15:26:06 16.75147 01/27/11 15:27:06 16.84864 01/27/11 15:28:06 17.07667 Page 1

**~,** ., l;

, 2601/27/11 15:29:06 01/27/1115:30:06 01/27/1115:31:06 01/27/11 15:32:06 01/27/11 15:33:06 01/27/1115:34:06 01/27/1115:35:06 01/27/11 15:36:06 01/27/11 15

: 37

: 06 01/27/11 15:38:06 01/27/1115:39:06 01/27/11 15:40:06 01/27/1115:41:06 01/27/1115:42:06 01/27/11 15:43:06 01/27/1115:44:06 01/27/11 15:45:06 01/27/11 15:46:06 01/27/1115:47

: 06 01/27/1115:48

: 06 Stop Run #5 01/27/11 15:49:06 01/27/11 15:50:06 01/27/11 15:51 :06 01/27/1115:52:06 01/27/11 15:53:06 01/27/11 15

: 54:06 **0~ !27!~**  5:55

: 06 01/27/11 15:56:06 01/27/1115:57:06

17

. 06593 16.7837 16

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. 65285 16

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**~~~'I** u • 2 **~** ,, I1/27/'i
1 Run #6 Date/Time
02 mm/dd/yy hh:mm:ss
% 01/27/11 16:09:06 16.82 Start Run #6 01/27/11 16:10:06 17.01 01/27/1116:11:06 17.02 01/27/11 16:12:06 18.31 01/27/1116:13:06 18.32 01/27/11 16:14

: 06 17.38 01/27/1116:15:06 16.57 01/27/11 16:16:06

16

. 63 01/27/11 16:17:06

16

. 69 01/27/1116:18:06 16.64 01/27/11 16:19:06

16

. 68 01/27/11 16:20:06 16.73 01/27/11 16:21 :06 16.55 01/27/11 16:22:06 16.61 01/27/1116:23:06 16.82 01/27/11 16:24:06

16

. 90 01/27/11 16:25:06 16.70 01/27/11 16:26:06

16

. 60 01/27/11 16:27:06

16

. 70 01/27/11 16:28:06 16.80 01/27/11 16:29:06

17

. 02 01/27/11 16:30:06 17.01 01/27/11 16:31:06 16.91 01/27/11 16:32:06 16.97 01/27/11 16:33:06 17.18 01/27/11 16:34:06 17.44 01/27/11 16:35:06 17.19 01/27/1116:36:06

16

. 97 01/27/11 16:37:06

17

. 02 01/27/11 16:38:06 17.43 01/27/11 16:39:06

17

. 35 Port Change 01/27/11 16:40:06 18.51 01/27/11 16:41:06 20.58 01/27/11 16:42:06 20.21 01/27/11 16:43:06 17.60 Resume 01/27/11 16:44:06 17.12 01/27/1116:45:06

17

. 34 01/27/11 16:46:06 16.91 01/27/11 16:47:06 16.93 01/27/11 16:48:06 17.00 01/27/11 16:49:06 17.15 01/27/11 16:50:06 17.15 01/27/1116:51:06 17.05 01/27/11 16:52

: 06 18.14 01/27/11 16:53:06

18

. 29 Page 1

,. : u ... **~** 2 gr "'1/27/1iRun#601/27/1116:54:0617.3701/27/1116:55:0616.7001/27/1116:56:0616.6501127/1116:57:0616.6901/27/1116:58:0616.8301/27/1116:59:0616.7401/27/1117:00:0616.7101/27/1117:01:0616.6201/27/1117:02:0616.5201/27/1117:03:0616.6601/27/1117:04:0616.7101/27/1117:05:0616.5701/27/1117:06:0616.5801/27/1117:07:0616.4101/27/1117:08:0616.5601/27/1117:09:0616.5901/27/1117:10:0616.6401/27/1117:11:0616.6201/27/1117:12:0616.4901/27/1117:13:0616.89StopRun#616.9501/27/1117:14:0616.9501/27/1117:15:0619.3701/27/1117:16:0620.7701/27/1•117:17:0611.0201/27/1117:18:061.5701/27/1117:19:060.5801/2711117:20:060_44Zer0"!201/27/1117:21:061.9301/27/1117:22:068.8301/27/1117:23:069.01%02Page2:,..,'29Appendix
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# -t;AppendixD

# ter Box#: 3 rial#: AR3 

# !!!!! Armstrong Environmental Inc. EPA Method 5 522 Series Meter Box Calibration

Pre-Test Orifice Method English Meter Box Units, English 

# K' Factor Date: 

# ------------------------> Barometric Pressure: 

# ----------> Theoretical Critical Vacuum:--> 01/04/11 29.40 (in. Hg) 13.87 (in. Hg)

**~ORTANT** 

# For valid test results, the Actual Vacuum should be 1 to 2 in. Hg greater than the Theoretical Critical Vacuum shown above ,

**~ORTANT** 

# The Critical Orifice Coefficient, 

# K', must be entered in English units, (ft)'3.(deg R)'0.5/((in.Hg)'(min)). 

# !I!!!

--------------- DRY GAS METER READINGS ---------------- -CRITICAL ORIFICE READINGSVolume Volume Volume Initial Temps. Final Temps. Orifice 

# K' Orifice Actual --Ambient Temperature -- tlH Time Initial Final Total Inlet Outlet Inlet Oullet Serial# Coefficient Vacuum Initial Final Average H20) (min) (cu 

# ft) (cu II) 

# (cu 

# ft) (deg F) (deg F) (deg F) (deg F) (number) (see above) (in Hg) (deg F) (deg F) (deg F) 0 . 25 5.00 998.871 1000.420 1.549 65.0 65.0 65.0 65.0 0 . 52 5.00 0.420 2.658 2.238 65.0 65.0 66.0 65.0 0.96 5.00 2.658 5.696 3.038 66.0 66.0 67.0 66.0 1.50 5.00 5.696 9.588 3.892 67.0 66.0 68.0 66.0 2.95 5.00 9.588 14.971 5.383 68.0 66.0 71.0 66.0



# , ............. **,..*"'*""*""*••*..~~**"'*•••••*•**••••••••*•"'•*** 

# RESULTS 

# ********"'*•**"'******"'*****'********•••••*••••••••••• DRY GAS METER --- LUME VOLUME

· RRECTE[ CORRECTED

Vm(std) Vm(std)

(cu fl) (liters) 1.531 0.1 2.213 0.1 3.001 0.1 3.846 0.2 5.329 0.2 --------- ORIFICE--------- VOLUME VOLUME VOLUME CORRECTED CORRECTED NOMINAL

Vcr(std) Vcr(std) Vcr (cu ft) (liters) (cu 

# ft) 1.553 0.1 1.581 2.203 0.1 2.242 2.968 0.1 3.021 3. 796 0.1 3.865 5.270 0.2 5.365 

# Average 

# Y 

# -----> -- DRY GAS METERCALIBRATION FACTOR 

# y Value Variation (number) (number) 1.014 0.019 0.995 0.001 0.989 -0.006 0.987 -0.008 0.989 -0.006 

# 0.995

e: For Calibration FactorY, the ratio of the reading of the calibration meter to the dry gas meter, acceptable tolerance of individual values from the average is +-0.02.

(..1,)



# . -..: 40 48 55 63 73 0.243 22.0 68.0 0.344 21.0 68.0 0.464 19.0 68.0 0.593 17.5 68.0 0.824 14.0 68.0

--------- ORIFICE-- - ------

CALIBRATION FACTOR dH@ Value (in H20) 1.441 1.490 1.512 1.444 1.473 Variation (in H20)

-0.0307

0 . 018 0.040 -0.028 0.001 68.0 68.0 68.0 68.0 68.0 68.0 68.0 68.0 68.0 68.0



# 1.472 <---Average dH@

Date / 

# / • f( /; / t I CONVERSION FACTORS 

# 1 mm Hg' 0.13330 kPa 1 em 

# = 0.39370 inch 1 mm 

# = 0.03937 inch 1 cu ft 

# = 28.32 liters

-Average Temperatures--

DGM DGM Ambient Oullet Overall Temp

(deg R) (deg R) (deg R)

525.0 525.0 528.0 525 . 0 525.3 528.0 526.0 526.3 528.0 526.0 526.8 528.0 526.0 527.8 528.0Temperature Meter Calibrations Meter Box#:

3 Date: 01/04/11 Calibrated By: TA Emtech Thermo Probe Stack Oven Exit Auxiliary Checker Degrees
F Point 1

32 30 30 30 30 30 Point 2
212 210 210 211 211 211 Point 3
752 751 751 751 751 751 Degrees
R Point 1
492 490 490 490 490 490 Point 2
672 670 670 671 671 671 Point 3 1212 1211 1211 1211 1211 1211 Percent Difference Point 1 -0.4065 -0.4065 -0.4065 -0.4065 -0.4065 Point 2 -0.29762 -0.29762 -0.14881 -0.14881 -0.14881 Point 3 -0.08251 -0.08251 -0.08251 -0.08251 -0.08251

• .

'

l i 

### 38

# er Box# : 

# 3 i al# : AR3 

# !!II Armstrong Environmental Inc . EPA Method 5 522 Series Meter Box Calibration

Pre-Test Orifice Method English Meter Box Units, English K' Factor Date : 

# ----------------:> Barometric Pressure : ---> Theoretical Critical Vacuum:---> 02/08/11 29.43 (in . Hg) 13 . 88 (in , Hg)

' ORTANT For valid test results , the Actual Vacuum should be 1 to 2 in , Hg greater than the Theoretical Critical Vacuum shown above . ' ORTANT The Critical Or i fice Coeffic i ent , 

# K', must be entered i n English units , (ft)"3*(deg R)'0 . 5/((in . Hg)'(min)). 

# 1111

- - ----- DRY GAS METER READINGS------- -CRITICAL ORIFICE READINGSVolume Volume Volume Initial Temps . Final Temps. Orifice K' OrifiCe Actual --Ambient Temperature-- dH Time lniUal Final Total Inlet Outlet Inlet Outlet Serial# Coefficient Vacuum Initial Final Average -120) (min) (cu ft) (cu 

# ft) (cu ft) (deg F) (deg F) (deg F) (deg F) (number) (see above) (in Hg) (deg F) (deg F) (deg F) 0.25 5 . 00 265 . 800 267 . 334 1.534 61.0 61 . 0 62.0 61 . 0 0.52 5.00 267 . 334 269.560 2.226 62.0 62 . 0 66.0 63.0 0.95 5.00 269.660 272.580 3.020 65.0 63.0 67.0 64.0 1.50 5.00 272.580 276.467 3.887 66.0 65.0 69.0 65 . 0 2 . 95 5.00 276.467 281 . 834 5.367 68 . 0 66.0 73.0 67 . 0

**.,'frllrllll ..,**  **,oll' ll!**  **-.t-• "''** ••*** **•"** ***"""'l'l'a""**

**'*** **""'*-""** **-*** ***•~• .._.**  

# RESULTS ****"'*"'"'***'**"~~"*"'***•**"'***•***"'""***"**.,•*•*••-•***"'*** 

# JRY GAS METER - LUME VOLUME RRECTECCORRECTED

Vm(std) Vm(std)

(cu 

# ft) (liters) 1 . 529 0.1 2.212 0.1 2.995 0.1 3 . 849 0.2 5.311 0 . 2 ---ORIFICE---- VOLUME VOLUME VOLUME CORRECTED CORRECTED NOMINAL

Vcr(std) Vcr(std) Vcr (cu ft) 

# (liters) 

# (cu ft) 

# 1.551 0.1 1.584 2.201 0.1 2.247 2.965 0.1 3.027 3 . 793 0.1 3 . 872 5 . 266 0 . 2 5 . 376 

# Average Y 

# -----> - DRY GAS METERCALIBRATION FACTOR 

# y Value Variation (number) (number) 1 . 015 0.019 0.995 -0.001 0.990 -0.005 0 . 985 -0 . 010 0 . 991 -0.004 

# 0.995

e: For Calibration Factor Y. the ratio of the reading of the calibration meter to the dry gas meter, acceptable tolerance of Individual values from the average is +-0 . 02 .


# S I G N

**EO :~**  **,...** 

# -;r I _,/ V . ,.. -_ 

# 1

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# CJ:) 

# 40 48 55 63 73 0 . 243 22.0 70.0 0.344 21.0 70 . 0 0.464 19.0 70 . 0 0 . 593 17 . 5 70 . 0 0.824 14 . 0 70 . 0
----ORIFICE - --

CALIBRATION FACTOR dH@ Value Variation (in H20) (in H20) 1.456 -0.0219 1.501 0.023 1.507 0.029 1.450 -0 . 028 1.476 -0 . 002 70.0 70 . 0 70.0 70.0 70.0 70.0 70 . 0 70.0 70 . 0 70.0



# 1.478 <---Average dH@

Date : 

# z[ f 

# (II
f 

# I 

# CONVERSION FACTORS 1 mm Hg' 

# 1 em 

# = 1 mm 

# = 1 cuft= 0.13330 kPa 0.39370 inch 0.03937 inch

28.32 liters

-Average Temperatures--

DGM DGM Ambient Outlet Overall Temp

(degR) (deg R) (deg R)

521 . 0 521.3 530 . 0 522.5 523.0 530 . 0 523.5 524 . 8 630.0 525.0 526 . 3 530.0 526 . 5 528 . 5 530.0

## Temperature Meter Calibrations Meter Box#:



## 3 Date: 

## 02/08/11 Calibrated By: TA Emtech Thermo Probe Stack Oven

E xit Auxiliary Checker Degrees
F 

## Point
1

32 30 30 30 30 30 Point2

212 210 210 210 210 210 Point 3
752 750 750 750 750 750 Degrees
R 

## Point
1
492 490 490 490 490 490 Point 2
672 670 670 670 670 670 Point 3 1212 1210 1210 1210 1210 1210 Percent Difference 

## Point
1 -0.4065 -0.4065 -0.4065 -0.4065 -0.4065 Point2 -0.29762 -0.29762 -0.29762 -0.29762 -0.29762 Point 3 -0.16502 -0

. 16502 -0.16502 -0.16502 -0.16502



# 40Compony Name:
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11

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### v = Pts ± 0.053

11 Pitot tube/ probe number bt;' 6- meets or- exceeds all _s pee

i fica tions criteria and/or applicab1e design features*daand

is hereby assigned

a pitot tube calibration factor of 0.84.

•·

.

·· ·

' · .

. Signature

· 'VI

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. . ,, 41 I I i ICompe;ny Name:

Post Samole ,.., ........ **~...** _____J-'
... -i Date -----

oa te 2..{n,.Z
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v /..} f) /Jo 0 I 2- '2. 0 ( 0 **.97 ~**  Dt! tWto o ... **~q'to** \.. **~?,37~** (].vt? () v/ Pitot tube/probe number bU G- meets or exceeds all spec;ncanons **c~1t:ria and/o~**  **app~ica~le**

... **desi~n features~""and** 

is

**~" ~zi#a**  p1'o'" tube ca1lbration ToCL.Or 01 0.84.

/ /'

1 Sig:.aturo **~111** VU .,.See ';Q
: .... **~50,** Vo1. **~2.** No. 150, **H~t~oC** 2. **V~rify th~**  **r.:inimu~** 2 inch se:.back cf the **~he1"7.10c~up1e** and the **mini~ 3/~**  inch separl:ion **b~:we~r. ~he**  ;>i :ct :.:.tbe end **!h~ ~:z::ie**  as sho\o'T': !!'":: **~~e ~~P**  of **:~is** page.

Date /2{n/l1

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I !\. NOZZLE INSPECTION AND MEASUREMENT DATA SHEET Company Name bs{)" **~p-.fcfL** Date **Samp1ed_·~t/~z._1__,/_t/** __ Nozzle Number 71b r;{otSS .Presamole Inspection I hereby certify that the above referenced nozzle appears to round, sharp-edged, free of nicks and dents and is ju for use at this time. Last Previously **Measu~d** Nozzle Area **.~o~37~** ft2 Date Measured lfl-/1

f
date **~~t** 1 U I Postsamole Measurement Measure three diameters
as shown; measurement
is in inches; record belo\'J; perfonn calculations.

• 1._, l.f--'t ...... s- __ 2. **'~t£**
3.

I l.f/ Lj Ave rage D i amet er _

. _ i.f .:..: t ;_ tf ...;....;. l ___
_ Area = '11' o2 4 X 144 = data reduction.

- ·· • Maximum allowable difference between largest diameter and smallest diameter is 0.004 inches
., 'I li
; n_., oAppendix
EAIR UQUIDE

I "T- --

- ----

- 1¥ , CERTIFICATE
of ANALYSIS Interference-Free Multi-Component EPA Protocol Gases NOTE: Analytical uncertainty and NIST traceability are in compliance with EPA-600/R-97/121 Customer

: P.O

. Number

: Item Number: Notes: Assay Date: ALA-RGN-DALLAS/FW 31522 9-Apr-09 Component Oxygen Nitrogen Reference Standard(s) Employed For Analys

i s : S t d name Std II **GMIS~21 GMIS~21**  Analys

i s Information: Componon

t 1: Oxv o e n Anatvzer
In formation Manufa
c
i iK er : Teledyne Model Number

: 3000PA

Ze r o Serial Number: 1862 Refe

r ence Analytical Princip

l e : Para mag

, Candidate MPC Calibrated

: 03127109 Result ' ""- **U~** Analyst Signa

t ur e : **'-~~~** = Mix Assayed At: Air Liquide America Cone

. 21

. 9 Section
2 . 2 Procedure: G-1 Cyl. Number

: CC93937 Expiration Date: 8-Apr-12 U nit s % Requested Concentration 9% Balance St d . E r ror Comp. 0 . 1 02 - Shipping Order#: 32935988 329 3 5988 LP X 250323 CGA590 1900psig Transfer#: LOT#

: Valve Cyl. Pressure:• *Cylind
e r sh o uld no1 be used when gas pre ss ur e is below 150 psig Assay Concentration 9.01 ±0.07% Balance Ba

l ance CVI
. No
. Exp

. Da t e Sample No
. N 2 cc178365 3/27/2011

N
. A Fi r st T riad Ana

l sJs On
: 4/912009
Second T ri ad Analys is On: Trlal1

T rl a l2

T ria l3 Uni t s

Tria

l 1 Tnal2 Tria

l 3 U ni ts 0.80

0 . 77

0 .76

Zero 2 1. 6 0 21.58 21.49

Re f erence 9 . 26 9.36

9. 3 6 candidate 8 . 94 9.0 5 9.05 % Result Mean Resu

l t
9 . 0 1 %

Mean Result: Debra Jackson Calculated by: **-~-"'--**
**-- ---=**  **1...:::9** _ _ ___ _ __ Debra Jackson " .... li ·,,', 4 5 11426 Fairmont Pkwy, La Porte, TX, 77571 Phone

: (281)474-8400 Fax: (281)474-8419AJR UQUIDE

I ""t--- --------'"' CERTIFICATE
of ANALYSIS Interference-Free Multi-Component EPA Protocol Gases NOTE

: Analytical uncertainty and NIST traceability are in compliance with EPA-600/R-97/121 Customer: P.O. Number: Item Number: Notes: Assay Date: ALA-RGN-DALLAS/FW 31522 9-Apr-09 Component Oxygen Nitrogen Reference Standard(s) Employed For Analysis: S t d name Std # GMIS421 GMIS421 Analysis Information: Component

1: Oxvoo n Analyzer

l nf o.-malion Manufacli.Xer;

T e
l edyne Model N u mber: 3000PA

Ze r o Seria

l Number

: 1862

Re f ere nce Ana

l yt

i ca
l Princ

i ple
: Pa r amag

, Candidate MPC Calibca

t e d : 03/27/09 Resul

t Co n e. 21

. 9 Section 2.2 Procedure: G-1 Cyl. Number: CC233616 Expiration Date: 8-Apr-12 Units % Requested Concentration 20% Balance Std

. E rr o r Como

. 0
. 1 02 Shipping Order#: 32935988 32935988 LPX250321 CGA590 1900psig Transfer#: LOT#: Valve Cyl. Pressure:• •cylinder should not be used when gas pressure is be\ow 150 psig Assay Concentration 20.0 ±0.1% Balance Balance Cyl. No. Exp

. Da te Sampje No
. N2 cc178365 3/27/2011

N
. A F
i rs t Tr iad Analysis O n :
4 19120()9
Se<:ond
T ria d Analygs On
: Trial1

T rial2

T r ial3 UnitS

Tria

l 1 Triai2

T rial3 0.80 0.77 0.76

Ze r o 21.60

21

. 58 21.49

Re f e r e n ce 19.79 19.73 19.71
Cand

i date 2 0 . 04

1 9 . 97 19

. 9 5 % Result Mean Res\M: 19 .99 %

Mea n ResLAt: Calculated by: **~~**

Urits Debra Jackson .... . u d **~** 6 Mix Assayed At: Air Liquidc America 11426 Fairmont PJ..·wy, La Porte, TX, 77571 Phone :( 281)474-8400 Fax :( 281)474-8419Appendix
FElgin stack test production Elgin stack test production From: To: Subject: Date: "Anderson, Paul (Mineral Wells) NA" <Paui.Anderson@hanson.biz> "armst@ix.netcom.com" Elgin stack test production Jan28,201110:17AM

Page
1 of 1 Torn: The production information for the Elgin stack test is below. If you need any thing els let me know. Thanks for your help. Push rate: Car count: Brick Wt.: Paul Anderson Group Assets & Eng Mgr Hanson Brick 500 NE 14th Ave. Mineral Wells, TX 76067 Cell: 817 690 8132 Fax: 940 325 9788 paul.anderson@hanson.biz Hansonbrick.corn

18 cars/day 5200 brick/car 1552 grams/brick http://webmail.c.earthlink.net/wam/printable.jsp?msgid=4743&x=-260784951

.. ·•vu 47 1/28/2011

# Appendix
GSummary of Hydrogen Halides and Halogens Analysis Plant: Hanson Brick, Elgin, TX Location: Kiln #1 Scrubber Exhaust Date: Run# Run# 1/27/2011 Imp# 11&2 11 &2 11&2 11&2 11&2 11&2 Imp# 13&4 13&4 21&2 2 1 &2 31&2 31 &2 Volume Dilution 300 300 Average 300 300 Average 300 300 Average Volume Dilution 250 250 Average 250 250 Average 250 250 Average Fl-, ug/ml MDL, ug/ml HF, mg 1 1.22 0.07 0.385398 1 1.14 0.07 0;360126 0.372762 1 1.47 0.07 0.464373 1 1.51 0.07 0.477009 0.470691 1 1.54 0.07 0.486486 1 1.57 0.07 0.495963 0.491225 Cl-, ug/ml MDL, ug/ml Cl2, mg 1 <0.1
0.1 <0.025 1 <0.1
0.1 <0.025 <0.025 1 <0.1
0.1 <0.025 1 <0.1
0.1 <0.025 <0.025 1 <0.1
0.1 <0.025 1 <0.1
0.1 <0.025 <0.025 Cl-, ug/ml MDL, ug/ml HCI, mg 3.21 0.1 0.989964 3.24 0.1 0.999216 0.99459 3.71 0.1 1.144164 3.96 0.1 1.221264 1.182714 3.46 0.1 1.067064 3.52 0.1 1.085568 1.076316 •• y '-' 4 8Conditions 4.03 ug/ml Fl- ln H2S04 - 3.99 ug/ml Cl- in H2S04 Date 01/29/2011 Time 10=35:16 -25. 600m'v

256. ooomv Component Retention FlClFlClf" . .... ..................

: ;·'f""'"'"''''M .......................

. ... . .....
. .. _ .................

.. . - ......... - . .............. ...... .. .. ... . .......

.. . ......

. . .............

- ... . ... . ...................
... ..... .......

. ..... ....... ... ......... .... ..........

. .... .............

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, ll

\ I

,

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·i

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! ' '''

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.... ...................

. ....... . _ ...............

.. .............

.. ...... ...... ..... . _ ...........

.. ...................................................................................................

_ .......... .J Component Number Retention Area External Units 2

1 2 1.083 1.950 337.50
M 252.20
M 589.70 3.98 ug/ml 3.46 ug/ml 7.45
Area External 337.50 M 3.98 252.20 M 3.46 49Component FlClDate Time 4.03 ug/ml F- **!~** H2S04 3.99 ug/ml C- in H2S04 01/29/2011 **10~38:03** -·25. 600m\-'

256. OOOml./ Retention
r .... ..... ... - .. - ... : ; :r·· · · · .. . ..... ... ..... . ... . . . ................

. . . ..... ... ... . . . . ... . . ...................

.. . . . . .. . .. . . . . . ___ _ _ .. . ... .. .. - ... . ...........

. ......... ..... ... . . . . . ..... .. ... . ....... ... .. . . . . . .. . . . . . . . .... ... . ... . . . . . . .....
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:1:

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i i **·:~.** 1 j"'"'"

' " **=::.·~:: :::::::::::::~:::::::::.:::::** 

**~:.: ::::**  **::::::::mu::: tn=::l:~m~·**  1.1001

, . . ! - 1

\ 1. 933

!,

. ' · : **··": :::~**  **::::::: ::::-:ll**  **Tll!'** t"" " "

,_ ...... . I

I 3 1···· .. ! I I L . ..... 41 sl·· ··· I 6, . ... . .. .. I '

.

I 1 ..... ... ...........

: .... .. .... .. ....
. ...... .. .............................................

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.. ........

. . . .. ................ _.__
.. . ...........................

... .. ............

.. ...............................

. ... .......................

. ...1 Component Number Retention Area External units Fl-

1 1.100 335.00

**~'i** 3.95 ug/ml Cl-

2 1.933 2.59 .10 **~1** 4.12 ug/ml 2 594.10 8.07
Area External 335.00 M 3.95 259.10 M 4.12 50Conditions6.04ug/mlF!-nH2S045.99ug/mlCl-nH2S04Date01/29/2011Time:10:48:42-25.600mV256.000mVComponentRetentionAreaExternal•I:'jl'"IFlCl1:r1I:.J·!1,.........<1 .083!I516. 80M6•02I'•I1 . 9 5j.........:\;·.::::::::::::c.::::::::::::::::::::::::::::::::::::"i3 6 9 .50M 5 .76Ic-----------------------------13,.........Ii4f---ll""i61"""""""""I..I:!.........................:............................................................................-.......................................................................................................................................................................................JComponentNumberRetentionAreaExternalUnitsFl-11.08:3516..806.02ug/mlCl-21.950369.50f"l5.76ug/rnl2886.3011.785.1Conditions 6.04 ug/ml Fl- in H2S04 - 5.99 ug/ml Cl- in H2S04 Date 01/29/2011 Time 10:51=45 -25. 600m\ J

256

. OOOmV Component Retention

Area External FlClFlCl-

**··· ~**  ... .. .... ... ..... **:~r··** .. · ··--· · -· ·· ... .. .... .. ..... ..... . . ..... ..... ... ... ... .. . . . .... _ _ _ .. ..........
.. .. **~·~ ·-·**  **·-** .... ·· - · ·- · -- ·· .......
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l ·
:r

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I 1 • 0 8 3 1

**:;: ::**  **:::::: ::::::::::**  **::::::::**

**::: ::::::":::~"'"** 

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,. I

I, 1.933 1 :\.

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: :::::: ::: :. o: · :: : . : "" ' ' ' **:::::: :··~···** 

I **~**

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! ! 41 ....... .. ! i I 5j· · · ·· · · I I 61····

· ·.. .

I I i r ! ....... .... .........
. . . .. : ...... .... .......
. .. .... .... . . . . . ..... .. . . . ..... . . . ....... . . . . . . . ..... . ... - ... . ..... .. . ... .. .. .. ... . . .. . .. ..... .. .. . .. . .. .. . . .........

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. .. . .... . . . . . .. . ...............

. . . .........
. ... .. .. .. ... ...... ........
. .... ..! Component Number Retention Area External Units 2

1 2 1.083 1.933 520.30
M 366.75

1'1 887.05

6. Of3 ug/ml 5.94 ug/ml 12.02 520.30 M 6.08 366.75 M 5.94 . . . ; . 52

### Component

### FlClDate Time 

### Retention 8.06 ug/ml Fl- in H2S0 4 

### 7.98 ug/ml Cl- in H2S04 01/29/2011 11:19:39 -25. 600rn\/

256. or:>Om\J 

# r ..... . ... .. ... ... ] ... _ . ... .. .........

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### 1 .. 100 1.966 

### 759.10 M 474.05

f1 

### 1233.15

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### 15.44


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### 474

. 05 M
7 . 42 

# 53Conditions 8.06 ug/ml Fl- in H2S04 7.98 ug/ml Cl- in H2S04 Date

: 01/29/2011 Time 11:22:53 -25.600mV 256.000mV Component Retention

. **~""'' ~''"''**  **.,''''''**

.. . .. ,, .. ,,.,

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1 2 1.100 1.966 699.30 M 479.20 M 1178.50 7.56 ug/ml 8.08 ug/ml 15.63
Area External 699.30 M 7.56 479.20 M 8.08 54Conditions 2.01 ug/ml Fl- in H2S04 ! 2.0 ug/ml Cl- in H2S04 Date 01/29/2011 Time 11:44=43 -25. 600mV

256. OOOmV Component Rete n t i on, .......... - ..... . ........ .... ...........................................................

- ...... . ...... ..... . ............ ....................................... ............ ...........

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i i Component Number Retention Area Ext.er nal Units 2

1 2 1.083 :1..933 205.25

1'1 129.50 M 334.75

2 .. 43 ug/ml 1.71 ug/ml 4.13
Area External 205.25 M 2.43 129.50 M 1.71 

# s·s**c~0 :la~s** 

2 01 ug/ml Fl- **i~ H2S:~**  · 2.0 ug/ml in H2504 Date 01/29/2011 Time 11=47=44 -25. 600m'·.J

256. OOOm\J Component Rete n t i o r ....................... ::J: ..... ........... ........ ...... ........ ....... ........................

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. ..... ...........

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..... J Component Number Retention Area External Units 1

1 .. 083 201

.. 80 M

2 .. 38 ug/ml 2 1.916 123

.. 20 **~'1** 1.63 ug/m.l 2 325.00 4.01
Area External 201.80 M 2.38 123.20 M 1.63 56.-1-?)1•'/0UHTIH.JECTED0,000\_'·....·.\._·.,'•...\'•,\······•···....\...._............,t••••i··..L;l7 90<1;2Avgslopeofcurve:60.04Y-axisintercept:0.00Coeffoflinregr:0.95f\1().Ar·eaP1mount0.0.0000"0001;126.'/<--.000"'2506503990,,;::::,""......,,:.'\;368.1::::55990447912;57980C':F0.00063.175622320t<L..·45760.0411235..•..'.i . \

I .......... .

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.... ..., I 7 2 9

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. . > ::..! Avg slope of curve: 90.48 Y-axis intercept: 0.00 Coeff of lin regr: 0.87 f\j()

' Area. Amount. ():: 0.000 0.000 CF" 0 .000 j . . . 20:3.525 2.010 1.01 .256 2: 341 .660 4.,030 84.779 **3~** 518.550 6.040 es

.. 853 4: 729.200 8.060 90.4/:i.

1 2 4 5

58Component Date Time Retention H2S04 Fisld **Blen~** -2S .600m

1 J

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. . ....................... J Component Number Retention Area External Units 0
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. 00 Area ExternalComponentDate-01/2?/2011..600m\)256,,OC>Om\/RetE:nt.ion....................................................................................................,.....................................,..............................................................................!'i11""""'jL.......21'ji3J.........'ii!41"'"""'iISi........!III!IiI!',,.,.,'''''••0''UOo-o••-•oO•o•'''-''''"-'''OOoO,_,_,"'''''""oOoomon"'OOOOOUO"...oOOm,o"'''OOnOOOO"''"'"UO..UUOOOOOUU•onoonn"OOOOOUO..OO...ONUo"'iiii!IjiiIii61.........I'ilI:.i.........................:....................................................................................................................................................................................................................................................................JComponentNumberRetentionAreaExternalUnits00.000.00...\..'·.s0ExterndConditionsDateTimeHansonBrick,ElginTXKiln1ScrubberExhaustRun#1Imps1&2Volume300Dilution1/101/29/201112:12:47-25.600mV256.000mVComponentRetentionAreaExternalFlClFlCl-,.........................:=:r··--................................................................................................................................................................................................................._.....................................1i:iiI.::Jrif........··:.,1.0831123.SOM1.22i\.1.9661.''·211.........:i::::::::::::::::::::,;::::•••,........202.10M3•21I31.........!I41""'""iI!s!........I!i·-"""61I::tOOOOOUOOO0000000•"'00000000OOOOOOOOOOOU-00OOUOOOUOOOOOOOno..OOOO>OOUO..MOOOOOOOMO....OOOUOO...OMYOOn..o...OOOOOOOO.....,.,,,,,,,,,,,,,,MOONO00"0-00....0000000!OOOMONOOOOOOOONOOO.OOOO:OOOOOOOOOOOOM-OOOOOO-OOOOOOOOOOOOUOOOOOOOOUOOOOOOOMOO,OOOO..OOOOOOOOOOOMOOoOOOOONNoOMo0000000·0-000000000oOO...OOOO..OO..MoOo>OO.ONOOOW..O'o•O•..ComponentNumberRetentionAreaExternalUnits2121..083:1..966123.80M202"10325.901..22u.g/ml3.2:Lu.g/ml4.44...,'-'._'.6.1Conditions

- Hanson Brick, Elgin TY Kiln

1 Scrubber Exhaust Run #1 Imps

i & 2 Volume 300 Dilution 1/1 Date 01/29/2011 Time 12:15:33 -25.600mV 256.000mV Component Retention

Area External FlClFlClr ............. ..... .. :T ........ . ...... . .............................

.. ....... ... ........
.. - .. . ..... ... ... ........ . ... ........ .... .. .. - .. ................................
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.. .J Component Number Retention Area External Units 2

1 2 1.083 1.950 115.90

1"1 203.90 M 319.80 1.14 ug/ml 3.24 ug/rnl 4.39

62Conditions Date Time Hanson Brick, Elgin TY Kiln

1 **Scrubb~r** Exhaust Run #2 Imps
1 & 2 Volume 300 Dilution 1/1 01/29/2011 12:26:33 -25.600mV 256.000mV Component Retention FlClFlCl-

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1 2 1.100 1.966 148.45 M 233.20 M 381.65 1.47 ug/ml 3. 71 ug/rnl Area External 148.45 M 1.47 233.20 M 3.71 63Conditions

· Hanson Brick, Elgin TX Kiln

1 Scrubber Exhaust Run #2 Imps
1 & 2 Volume 300 Dilution 1/1 Date 01/29/2011 Time 12:29=19 -25. 600mV

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1 2 1.100 1.966 152.70 M 248.70 M 401.40 1.51 ug/ml 3.96 ug/ml 5.47
Area External 152.70 M 1.51 248.70 M 3.96 •• v

· . ' 64Conditions Date Time Hanson Brick, Elgin TX Kiln Run #3 Imps

1 & 2 Volume 300 Dilution 1/1 01/29/2011 12=41:10 -25.600mV 256.000mV Component Retention

Area External FlClFlCl-

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1 **Scrubbe~** Exhaust Run #3 Imps
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**~** Scrubber

**E;- ~-~~ust**  4.03 ug/ml Fl- in H2S04 3.99 ug/ml Cl- in H2S04 01/29/2011 12:55:18 -25.600mV 256.000mV Component Rete n t i o **~** .. . ...... .. ......... : l .....................

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1 2 1.083 1.950 339.90 M 247.40
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(' , . **~-·** .. Area External 907.55 N/A 278.10 N/A 212.B5 M 2.17 70Conditions Date Time 3.99 ug/ml Cl- in NaOH 01/29/2011 13:40:18 -25.600mV 256.000mV Component Retention

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# ·- · - - --• Chloride Standard Product Number 037159 Certificate of Analysis Lot Number 10021, Expiration of Certification February 2011 The Chloride Standard was developed to aid the analysis of anions by Jon Chromatography

(I C). The single-ion standard was prepared by the dissolution of high-purity salt in **~18.2** megohm deionized water, which was tested by IC for ionic contaminants. The bottle label states the nominal concentration value of the ionic component for informational purposes only. The ion concentration value was determined by Ion Chromatography. The system was standardized using the National Institute of Standards
& Technology (NIST)

, Standard Reference Material, SRM 3182 (Chloride Standard Solution)

. The actual concentration value determined for the single-ion is listed below. Chloride Standard Component Chloride Concentration (mg/L) 998 ± 3 The concentration value is based on proven reliable methods of analysis. The estimated uncertainties are two standard deviations of the concentration values. The concentration value is warranted to be stable for three months from the date of shipment. The preparation and analyses of the Chloride Standard was performed with extreme care by the DIONEX Corporation Consumables Manufacturing Department. Document No. 034184-25

20 May 1998

89 Dian ex Corporation 1226 Titan way P.O . Box3603 Sunnyvale, CA 94066-3603 (406 ) 737-0100 North America U . SJCanada (641) 295-1500 South America Brazil (55) 11 31315140 Europe Au s tria (43) 1 616 51 25 Benelux (31) 20 683 9766(32

) 3 353 4294 Denmark (45) 36 36 90 90 France (33) 1 39 30 0110 Germany (49) 6 1 26 991 0 Ireland (353) 1 6M 0064 Italy (39) 02 51 621267 Sweden (46)8 479 3380 Switzerland (41) 62 205 9965 United Kingdom (44) 1276 691722 www.dionex.com

Asia Pacific Auslralia (61) 2 9420 5233 China (852) 2428 3282 India (91) 22 2764 2135 Japan (81) 6 66651213 Korea (82) 2 2653 2580 Singapore (65) 62891190 Taiwan (886) 2 8751 6655

LPN 031316-ll610M 03109Fluoride

. Standard Product Number 037158 Certificate of Analysis Lot Number 101206 Expiration of Certification December 2011 The Fluoride Standard was developed
to aid the analysis of anions by Ion Chromatography (IC). The single-ion standard was prepared by the disso lution of high
- purity

s alt in ;:::18.2 megohm deionized water, which was tested by IC for ionic contaminants. The bottle label states the nominal concentration
va lue of the ionic component for informational purposes only. The ion concentration value was determined by Ion Chro

, matography. The system was standardized using the National Institute of Standards
& Technology (NIST), Standard Reference Material, SRM 3183 (Fluoride Standard Solution). The actual concentration value dete1mined for the component ion is listed below. Fluoride Standard Component Fluoride Concentration (mg/L) 1007 ±3 The concentration value is based on proven reliable methods of analysis. The estimated uncertainties are two standard deviations of the concentration values. The concentration value is warranted to be stable for three months from the date of shipment. The preparation and analyses of the Fluoride Standard was performed with extreme care by DIONEX Corporation Consumables Manufacturing Department. **Docum~nt** No
. 0341 !!3-18 13-Dec-02 O i onex Corporation 1228 Tiian Way P.O. Box3003 Sunnyvale, CA 9406&-3503 (408) 737·0700 NorthAmerice U . S/Canada (847) 295-7500 South America Br.!zll (55) 1137315140 Europe Auslrla (43) 1616 51 25 B<lne

l ux ( 3 1) 20 583 9763(32)3 353 4294 Oenma

r k(45) 3636 90 90 France (33) 139 30 011 0 **e~many**

( 49) 6126 9 91 0 I reland (353)
1 644 OO&t I taly ( 39 1 02 51 621267 SWeden (46)8 479 3360 Swi tnr land
( 4 1) 62 205 9956 Uniled Kinodorn (44) 1276 6 9 1 722 www.dionex.com

As

i o P aci fic **us~a ia**  ( 61) 2 9420 5 233 China (852) 2428 3282 India (91) 22 2764 2735 Japa n ( 8 1 ) 6 68851213 Korea (82) 2 2853 2580 Singapore (65) 62891190 T a iwan (886 ) 2 8751 6655
90 LPN 031311Hl610M ll3i1l9Appendix

ISummary of Metals Analysis Plant: Hanson Brick, Elgin, TX Date: 1/27/2011 Run #4 PW & Filter Imps 1 & 2 Imps 3 &4 Total Antimony, ug (<2.00)

6.00

6.00 Arsenic, ug (<0.90) (<1.30)
(<2.20) Berylium, ug (<0.40) (<0.60)
(<1.00) Cadmium, ug (<0.40) (<0.60)
(<1.00) Chromium, ug 3.20
2.60

5.80 Cobalt, ug (<0.40) (<0.60)
(<1.00) Lead,ug
1.40
1.10

2.50 Manganese, ug 4.20 222.40
226.60 Nickel, ug 3.40
2.30

5.70 Selenium, ug 2.50
1.60

4.10 Mercury, ug 0.120 12.90 4.20 17.22 Run#S PW & Filter Imps 1 & 2 Imps 3 &4 Total Antimony, ug (<2.00) <3.00)
(<5.00} Arsenic, ug (<0.90) (<1.20)
(<2.10) Berylium, ug (<0.40) <0.50}
(<0.90) Cadmium, ug 0.45 <0.50)

0.45 Chromium, ug 5.10
2.50

7.60 Cobalt, ug 0.42 (<0.50)

0.42 Lead,ug
1.20
0.90

2.10 Manganese, ug 4.40
3.40

7.80 Nickel, ug 5.20
2.20

7.40 Selenium, ug 2.30 (<1.00)

2.30 Mercury, ug (<0.01)
15.90 16.20 32.10 Run#6 PW & Filter Imps 1 & 2 Imps 3 &4 Total Antimony, ug (<2.00} (<3.00)
(<5.00) Arsenic, ug (<0.90) (<1.30)
(<2.20) Berylium, ug (<0.40) {<0.60)
(<1.00) Cadmium, ug 0.81 (<0.60)

0.81 Chromium, ug 3.40
3.00

6.40 Cobalt, ug (<0.40) (<0.60)
(<1.00) Lead, ug 1.00
1.30

2.30 Manganese, ug 12.90 22.10

35.00 Nickel, ug 2.10
1.70

3.80 Selenium, ug 2.20
1.00

3.20 Mercury, ug 0.02 15.20

4
. 6 19.82

. . ._; 91CHEMTEX Environmental

& Industrial H y giene Services 3082 25th Street, Port Arthur, Texas 77642

• (409) 983-4575 FAX (409) 982-1522 5544 Leopard Street, Corpus Christi, Texas 78408

• (361) 299-9900 FAX (361) 299-1155 138 S. Cities Service Hwy., Sulphur, Louisiana 70663

• (337) 626-2121 FAX (337) 626-2126 Client: Armstrong Envriomental, Inc 17 48 Hlavek Rd
. Decatur

, TX 76234 Attn: Mr. Tom Armstrong Phone: 1-214-631.0021 Email

: armst@ix.netcom

. com david.mckeown@hanson.biz CHEMTEXID Sample 10 ?11010758 Quartt Fiber Filter P11010759 Acetone P11010760

0 . 1N HN03 P11010763 Quartz Fiber Filter P11010764 Acetone P11010765 0.1N HN0 3 MDL: Method Detection Limit. Sample Volume (ml) 190 100 155 100 RESULTS OF ANALYSIS PROJECT LOCATION

: Elgin,TX Reporting Date: Sample Matrix: Date Collected: Collected by : Date Received: 02/16/11 Filters & Liquid (Acetone,

0
. 1N HN0
3 ) 01/27/11 Client 01/28/

1 1 Time Received:

01

: OOpm CHEMTEX File#

: P11 010758 Results'
MDL Paramat&r mg/t. mg/sample mg/L mg/sample Antimony <0.02 <0

. 002 0.02 0.002 Arsenic <0.009 <0.0009 0.009

0 . 0009 Beryllium <0.004 <0

. 0004 0.004

0 . 0004 Cadmium

<0

. 004 <0

. 0004

0 . 004

0 . 0004 Chrom

i um 0.032

0 . 0032 0.004 0.0004 Cobalt <0.004 <0.0004 0.004 0.0004 Lead

0 . 014

0 . 0014

0 . 004

0 . 0004 Manganese 0.042

0 . 0042 0.004 0.0004 Nickel 0.034 0.0034 0.004 0.0004 Selenium

0 . 025

0 . 0025 0.007

0 . 0007 Mercury 0.0012 0.00012 0.0001 0.00001 Antimony

<0

. 02 <0

. 002 0.02

0 . 002 Arsenic <0.009 <0.0009 0.009 0.0009 Beryllium <0.004 <0.0004 0.004 0.0004 Cadmium 0.0045 0.00045 0.004

0 . 0004 Chromium 0.051 0.0051 0.004 0.0004 Cobalt 0.0042 0.00042 0.004 0.0004 Lead 0.012 0.0012 0.004 0.0004 Manganese 0.044 0.0044

0 . 004 0.0004 Nickel 0.052 0.0052 0.004 0.0004 Selenium 0.023

0 . 0023 0.007

0 . 0007 Mercury

<0

. 0001 <0

. 00001

0 . 0001 0.00001 CHEMTEX, Port Arthur Is not NELAP accredited for the above anaiyte(s). Anatysis was subcontracted

to another NELAP accredited laboratory

. Report Is generated
at CHEMTEX, Port Arthur, TX. • :See Case Narration NOTICE/DISCLAIMER:

The snslytic:af tesulls., opinions or lnt@rpretatlons **contain~**
In this report ere bued upon lnfomatlon end ml!lteriell!lupplted
by the Client for Whose QXC/uslvc and conlldentrar usc lhh!l report hee been m11dra

. No por&on or entity other lh<'n Dle client may reley on this report.. Any s.uc:h reliance .....tw be unjuaUOed. An'/ penson other \har. the t ti &n\, \ha\ reeos thl5 report does so at his orh&r QIM'\ **rl&~** The eniJiytlcal resull5, op

i nions end/or interpri!laUons expressed herein represent tile 'best JrJdgemenl
ol Chemlex. based on lhelnformaUon end in•trucUons received lrom lhe client Chemlex makes no wammtyorrepresentaUon, express at implied, or any **~ope.** and exp,.ssly disclaims **~:srne** This report ahall not be reprvduced

, ln whole or In pert, \'ftthout the Wt1tten approVDI of **Cheml~** In no event ahl'll Chemlex b& **re~:.pon51b1t** for eny darnltge greeter than the amount that II recalved for tt'le enelysis per fonned.

1 of 11

Qual ,, . ., u

**:** 92CHEMTEX Environmental

& Industrial Hygiene Services 3082 25th Street, Port At1hur, Texas 77642

• (409) 983-4575 FAX (409) 982-1522 5544 Lt:opard Street, Corpus Christi, Texas 78408

• (361) 299-9900 FAX (361) 299-1155 138 S. Cities Service Hwy., Sulphur, Louisiana 70663

• (337) 626-2121 FAX (337) 626-2126 Client: Armstrong Envriomental, Inc 1748 Hlavek Rd
. Decatur, TX 76234 Attn: Mr. Tom Armstrong Phone: 1-214-631-0021 Email: armst@ix.netcom.com david.mckeown@hanson.biz CHEMTEX 10 Sample ID P11010768 Quartz Fiber Filter P11010769 Acetone P11010770 0.1N HN0 3 P11010773 Quartz Fiber Filter P11010774 Acetone P11010775 0.1N HN0 3 MDL

: Method Detection limit. Sample Volume (ml) 175 100 285 320 RESULTS OF ANALYSIS PROJECT LOCATION: Elgin,TX Reporting Date: Sample Matrix

: Date Collected: Collected by: Date Received: 02/16/11 Filters & Liquid (Acetone, 0.1N HN0

3 ) 01/27/11 Client 01/28/11 Time Received: 01:OOpm CHEMTEX File#: P11 010758 Results*
MDL Parameter mg/L mg/sample mg/L mglsample Antimony <0.02 <0.002 0.02 0.002 Arsenic <0.009 <0

. 0009 0.009 0.0009 Beryllium <0.004 <0.0004 0.004 0.0004 Cadmium 0.0081 0.00081 0.004 0.0004 Chromium 0.034

0 . 0034

0 . 004

0 . 0004 Cobalt <0.004 <0.0004 0.004 0.0004 Lead

0
. 010 0.0010 0.004 0.0004 Manganese

0 . 129 0.0129

0 . 004 0.0004 Nickel

0 . 021 0.0021 0.004 0.0004 Selenium 0.022 0.0022 0.007

0 . 0007 Mercury 0.0002 0.00002 0.0001 0.00001 Antimony

<0

. 02 <0.002 0.02 0.002 Arsenic

<0

. 009 <0.0009

0 . 009 0.0009 Beryllium <0.004 <0.0004 0.004 0.0004 Cadmium <0.004 <0

. 0004 0.004 0.0004 Chromium 0.014 0.0014 0.004 0.0004 Cobalt <0.004 <0.0004 0.004 0.0004 Lead

0
. 024

0
. 0024 0.004 0.0004 Manganese 0.545 0.0545 0.004 0.0004 Nickel 0.008 0.0008 0.004 0.0004 Selenium <0.007 <0.0007

0 . 007 0.0007 Mercury <0.0001 <0.00001 0.0001 0.00001 CHEMTEX, Port Arthur is not NELAP accredited for the above analyte(s). Analysis was subcontracted

to another NELAP accredited laboratory. Report is generated at CHEMTEX, Port Arthur, TX. • :See Case Narration NOTICE/DISCLAIMER:

The enalyticel re&ulle, opinions or lntorprelotiorts contlllned
In lhts tepgrt ere ba•ed upon 1nrormat1on ;nd malarial .supplied by lhe client ror v.hose I!Xdusive and ctmrtdenial uae lhis r&pol1 hes been made. No person or ontlty other then the client may rala.y on lhlS report

, Any 11uch **~llance** wtn be **u~u~Uried.** Any **pe~on** olher than the client the
I read& this roport does 50 al his or **hero~** risk
. The analytical results, opk"'lons ancVor interpretstfons expressed her(lln representlhe bestfudgement
or Chemlex

. based on the k'lfOnn,uon end lnsiNc.tlons received 1mm the cJie:nl. Chemtex ma"e5 no waFTBnty ot raprASet'119llon, axpress or Implied

. or any type, end expressly **~Jsc m;.**  sama ih/s report shall nol be reproduced,

In whole or ln pl!lrt, wilhoullhe W'l'lltan approval of Chemtex.
In no event ehell Chemtex be **rt~&ponstble** for any dam ego grealer ttlM lhe omoun! lhellt received for lhe analysl6 per formed.

2 of 11

Qual '·' 93CHEMTEX Environmental

& Industrial Hygiene Services 3082 25th Street, Port Arthur, Texas 77642

• (409) 983-4575 FAX (409) 982-1522 5544 Leopard Street, Corpus Christi, Texas 78408

• (361) 299-9900 FAX (361) 299-1155 138 S. Cities Service Hwy., Sulphur, Louisiana 70663

• (337) 626-2!21 FAX (337) 626-2!26 Reporting Date: 02/16/11 Client: Armstrong Envriomental, Inc 1748 Hlavek Rd.

Sample Matrix: Liquid( 5% HN03 10%H202) Decatur, TX 76234 Attn: Mr. Tom Armstrong Phone: 1-214-631-0021 Email: armst@lx.netcom.com david.mckeown@hanson.biz CHEMTEXID P11010761 P11010766 Sample 10 5% HN0;/10% H202 MDL: Method Detection Limit.

Date Collected: Collected by: Date Received: Time Received: CHEMTEX File#: RESULTS OF ANALYSIS PROJECT LOCATION: Elgin,TX Sample Volume Results• Parameter (ml) mg/L mg/sample Antimony 340 0.042 0.006 Arsenic 340 <0.009 <::0.0013 Beryllium 340 <0.004 <0.0006 Cadmium 340 <0.004 <o.ooos Chromium 340 0.018 0.0026 Cobalt 340 <0.004 <0.0006 Lead 340 0.0081 0.0011 Manganese 340 1.570 0.2224 Nickel 340 0.016 0.0023 Selenium 340 0.011 0.0016 Mercury 340 0.038 0.0129 Antimony 370 <0.02 <0.003 Arsenic 370 <0.009 <0.0012 Beryllium 370 <0.004 <0.0005 Cadmium 370 <0.004 <0.0005 Chromium 370 0.018 0.0025 Cobalt 370 <0.004 <0.0005 Lead 370 0.0067 0.0009 Manganese 370 0.025 0.0034 Nickel 370 0.016 0.0022 Selenium 370 <0.007 <0.0010 Mercury 370 0.043 0.0159 CHEMTEX, Port Arthur is not NELAP accredited for the above analyte(s). Analysis was subcontracted

to another NELAP accredited laboratory. Report is generated at CHEMTJ:::X, Port Arthur, TX. • :See Case Narration

01/27/11 Client 01/28/11 01:OOpm P11010758 mg/L 0.02 0.009 0.004 0.004 0.004 0.004 0.004 0.004 0.004 0.007 0.0001 0.02 0.009 0.004 0.004 0.004 0.004 0.004 0.004 0.004 0.007 0.0001 NOTICE/DISCLAIMER:

The analytical re5uiiS, **opinion:~** or lnterpretstion;: conLalned
In lhis **~por1e.re** based upon informslion end material supplied by the cUent lor whose exclusive and confidenUal use flle: Ulport has been mOO e . No person or entity ottlt!l' then the client may relay on tt\ts repcul

· Any tuch **~ance** ..WI be un}u&\lned. Any person o\hM lhan the client. U'lBt read9 lhle rtJPQrt does so ot nts or herO'MI risk. The analyticsl re5ull$, opinions and/or lnlerprfltation!l expressed herein 1eprnsenl tho best judgement or Chemte11:

, based on lhe information end in51nteUomll received from tie dlont

. Chern lox makes no W;.lrranty or repr•s&nlalon, exprass or lmplt&d,of any type, and expressly disdaims nme. This reports hell nol be reproduced,

In y,.hole or In par1, without the writien approval or Chemtox.
In no evenlshall Chemlex be rotpons\ble for gny damage grealer than the **~mounllhal**

II received ior lhe onely!lls per fonntd

.

3 of 11

MDL mg/sample 0.003 0.0013 0.0006 0.0006 0.0006 0.0005 0.0006 0.0006 0.0006 0.0010 0.00003 0.003 0.0012 0.0005 0.0005 0.0005 0.0005 0.0005 0.0005 0.0005 0.0010 0.00004 Qual 94CHEMTEX Environmental

& Industrial Hygiene Services 3082 25th Street, Port Arthur, Texas 77642

• (409) 983-4575 FAX (409) 982-1522 5544 Leopard Street, Corpus Christi, Texas 78408

• (361) 299-9900 FAX (361) 299-1 155 138 S. Cities Service Hwy .. Sulphur, Louisiana 70663

• (337) 626-2

I 2 I FAX (337) 626-2

I 26 Client: Armstrong Envriomental, Inc Reporting Date: 02/16/11 1748 Hlavek Rd.

Sample Matrix: Liquid( 5% HN03 10%H202) Decatur, TX 76234

Date Collected: 01/27/11 Collected by: Client Attn: Mr
. Tom Armstrong

Date Received: 01/28/11 Phone

: 1-214-631-0021

Time Received: 01:00pm Email: armst@ix.netcom.com
CHEMTEX File#

: P11010758 david .mckeown@hanson.
biz RESULTS OF ANALYSIS PROJECT LOCATION: Elgin,TX Sam piA Volume Results* CHEMTEX
ID Sample ID Parameter (ml) mg/L mglsample mg/L P11010771
5% HN0
3 /10% HP2 Antimony 345 <0.02 <0.003 0.02 Arsenic 345 <0.009 <0.0013 0.009 Beryllium 345 <0.004 <0.0006 0.004 Cadmium 345 <0.004 <0.0006 0.004 Chromium 345 0.021

0 . 0030

0 . 004 Cobalt 345 <0.004 <0.0006 0.004 Lead 345 0.009 0.0013 0.004 Manganese 345 0.157 0.0221 0.004 Nickel 345 0.012 0.0017 0.004 Selenium 345 <0.007 <0.0010

0 . 007 Mercury 345 0.044 0.0152 0.0001 P11010776
5% HNOa/1 0% H 2 0 2 Antimony 390 <0.02 <0.003 O.Q2 Arsenic 390 <0.009 <0.0012 0.009 Beryllium 390 <0.004 <0.0005

0 . 004 Cadmium 390 <0.004 <0.0005 0.004 Chromium 390

0 . 03 0.004

0 . 004 Cobalt 390 <0.004 <0.0005 0.004 Lead 390 0.0046 0.0006 0.004 Manganese 390 0.012 0.0016 0.004 Nickel 390 0.0098 0.0013 0.004 Selenium 390 0.007 0.0010 0.007 Mercury 390 <0.0001 <0.00001 0.0001 MDL: Method Detection Limit. CHEMTEX, Port Arthur is not NELAP accredited for the above analyte(s}

. Analysis was subcontracted

to another NELAP accredited laboratory. Report is generated at CHEMTEX, Port Arthur, TX. • :See Case Narration NOTICE/DISCLA.IMER:

The Zlnalytleal **re:~ult:~,** oplnkme or lnterpretstiom; corUalned
In this A!port are **bit:~ed** upon inrorrneUon end matettal supplied by the client ror v.hoee exduslve and conlldenUal use: this report hes been made. No pol'$on or entity othl!r than **th~** cllet'lt may reley on this reporl Any **s~.H;h** re6anoe will be unjusUned. Any person **oth~** lhan lhe cllenl.lhel ""'ds lhls report does so 81 h/6 or hera>w! rtsk. The onolytlcal result., opinions and/or Jnlerprelillons expressed **ho~Jn** '"P'"""IIht boSIJudgemenl

of **Chemle.~~.** based on the ln(onn&Uon and lnstrvcGons **rec~ved** rrom Ute cllenl Chrmtex mekea nowarrentyorreprasentalion, e>cpress or\mpHed. of enytype, and exprteQiydl,dalm' eame. This repon shall nol be lllproducad,

Ill whole or In part. wiU1oullhe wrillen epproval or Chemlmt.
In no **ev~nt** shall Chemtex ba responsible for any **dam~ge** areeler thtm the emovnt lhetll received tor the analy&ls per formed.

4 of 11

MDL mglsample 0.003 0.0013 0.0006 0.0006 0 . 0006 0.0006 0.0006 0.0006 0.0006 0 . 0010 0.00003 0.003 0.0012 0.0005 0.0005 0 . 0005 0.0005 0.0005 0.0005 0.0005 0.0009 0.00004 Qual 95CHEMTEX Environmental

& Industrial Hygiene Services 3082 25th Street, Por1 Arthur, Texas 77642

• (409) 983-4575 FAX (409) 982-1522 5544 Leopard Street, Corpus Christi, Texas 78408

• (361) 299-9900 FAX (361) 299-1155 138 S. Cities Service Hwy., Sulphur, louisiana 70663

• (337) 626-2121 FAX (337) 626-2126 Client: Armstrong Envriomental, Inc Reporting Date: 02/16/11 1748 Hlavek Rd.

Sample Matrix: Liquid (4% KMN04 10%H2S04) Decatur, TX 76234

Date Collected: Collected by: Attn: Mr. Tom Armstrong

Date Received: Phone: 1-214-631-0021

Time Received: Email: armst@ix

. netcom.com CHEMTEX File#: david.mckeown@hanson.biz RESULTS OF ANALYSIS PROJECT LOCATION: Elgin,TX Sample Volume Results• CHEMTEXID SampleiD Parameter (ml) mg/1. mg/samplt P11010762 4% KMn04/1 0% H2S04 Mercury 300 0.0140 0.00420 P11010767 4% KMnOJ10% H2S0
4 Mercury 300 0.0054 0.00162 P11010772 4% KMnOJ10% H2S04 Mercury 290 0.0046 0.00133 P11010777 4% KMn0
4 /10% H2S0
4 Mercury 350 <0.0001 <0.00002 MDL: Method DetecUon Limit. CHEMTEX, Port Arthur is not NELAP accredited for the above analyte(s). Analysis was subcontracted

to another NELAP accredited laboratory. Report is generated
at CHEMTEX, Port Arthur. TX. • :See Case Narration

01/27/11 Client 01/28/11 01:00pm P11010758 mg/1. 0.0001 0.0001 0.0001 0.0001 NOTICE/DISCLAIMER:

The enalyticl!l **~sul18,** opinions or lnlerpretellons oontalnQd
In ltlls report are **bl'&~** upon informslion and mattrlalsupplied

by the client Tor Y.tloSC! axclu&lve 11"16 conflde:nlilll use **lhi~** rtJ)or1 h86 been **me~o.** No person or entity othef than the client mfl.y relay on lhls report Any such reliMce wUI be unjusiJned. Any petllon o\h•r than the t:llent, th11t rea.:b this report does so el his or **h~r** own rtsk. The analytical resulls, opinions and/or lnterprelldons expressed herein represent the be.stjl.dgemenl
or Chemtex, based on the lnformallon and lnslrnctlons received from the client. Ch.:mle1i. mekee no warranty or representation, exprcs:s or Implied, of BfiY type, cand expressly disclaims sllm&. This **~port** shall not be reproduced,
ln whole or in part

, without the 'Mitten approval of Chemtex.
In no event &hell Chomtex be responsible for .any dem9Q& gra"ler than lhe amount thalll receiYed (or the snelysis per ronned

.

5 of 11

MDL Qual mg/sample 0.00003 0.00003 0.00003 0.00004

. _; 9 6CHEMTEXEnvironmental&IndustrialHygieneServices308225thStreet,PortArthur,Texas77642•(409)983-4575FAX(409)982-15225544LeopardStreet,CorpusChristi,Texas78408•(361)299-9900FAX(361)299-1155138S.CitiesServiceHwy.,Sulphur,Louisiana70663•(337)626-2121FAX(337)626-2126Client:ArmstrongEnvriomental,Inc1748HlavekRd.Decatur,TX76234Attn:Mr.TomArmstrongPhone:1-214-631-0021Email:armst@ix.netcom.comdavid.mckeown@hanson.bizCHEMTEXIDSample1DP11010759AcetoneP11010764AcetoneP11010769AcetoneP11010774AcetoneMDL:MethodDetectionLimit.RESULTSOFANALYSISPROJECTLOCATION:Elgln,TXReportingDate:SampleMatrix:DateCollected:Collectedby:DateReceived:TimeReceived:CHEMTEXFile#:Results'Parametermg/kgmg/sampleParticulateMatter49.27.3ParticulateMatter55.46.8ParticulateMatter50.66.9ParticLJiateMatter24.75.6•AnalysisperformedandreportgeneratedatCHEMTEX,PortArthur,TXQualifierDefinition:ParameterParticulateMatterLABORATORYQUALITYCONTROLDATAMethodBlank(mg/sample)Result<0.1MDL0.102/16/11Acetone01/27/11Client01/28/1101:00pmP11010758MDL.mg/sample0.10.10.10.1QualParameterParticulateMatterLABORATORYQUALITYCONTROLDATAMethodReferences/AnalysisDates&AnalystsMethodReferencePMMethos5(NIOSHMethod0500}DateAnalyzed/AnalyzedBy02/03/11TRSNOTICE/01SCLAIMER:Theanalytical"'"utts.oplnloosorlnlerpreta.UonscontainedInlhlsreporterebeseduponJnlonnalionendml!lterielbytheclientfor'Mloseexclusiveandconndenllalusethisreporthasbeoenmade.NoorentityotherthantneclientmayTt!layonlhls1'4tport.Anysuchreliance\IIIIIbeunjuatllled.Anypersonotherthanlhecliml,thetreedsthisreportdoessoethisorherownrisk.Theenetyticalresults,opinions1!nd/orrucprenedhereinrepreun\lhebes1judgementolChemlex,basedontheinfonnallonandInstructionsreceivedrromthecuenLChcml.exmakesnowarr.antyorrepresenteHon,expressorimplied,ofanyI).'PEI.andeKpresslydisdelmssame.Thisreportshallnotbereproduced,Inwholl'lorinpertwilhoullhewrittenapprovZIIorChem\ex,Innoevent&hetlCh(lmiBXheresponsibleforpnydem39egre9tertheamounllhatitreceivedrortiepn&ly&ispMtonned.6of11Qual97CHEMTEXEnvironmental&IndustrialHygieneServices308225thStreet,PortArthur,Texas77642•(409)983-4575FAX(409)9H2-15225544LeopardStreet,CorpusChristi,Texas7840!:!•(361)299-9900FAX(361)299-1155138S.CitiesServiceHwy,,Sulphur,Louisiana70663•(337)626-2121FAX(337)626-2126Client:ArmstrongEnvriomental,Inc1748HlavekRd.Decatur,TX76234Attn:Mr.TomArmstrongPhone:1-214-631-0021Email:armst@ix.netcom.comdavid.mckeown@hanson.bizCHEMTEXIDSampleIDP11010756QuartzFiberFilterP11010763QuartzFiberFilterP11010768QuartzFiberFilterP11010773QuartzFiberFilterMDL:MethodDetectionLimit.RESULTSOFANALYSISPROJECTLOCATION:Elgin,TXParameterParticulateMatter(Totaldust)ParticulateMatter(Totaldust)ParticulateMatter(Totaldust)ParticulateMatter(Totaldust)ReportingDate:SampleMatrix:DateCollected:Collectedby:DateReceived:TimeReceived:CHEMTEXFile#:Results*mg/sample0.250.752.04<0.01*AnalysisperformedandreportgeneratedatCHEMTEX,PortArthur,TX.ParameterTotalDustQualifierDefinition:LABORATORYQUALITYCONTROLDATAMethodBlank(mg/sample)Result<0.01MDLO.D102/16/11Liquid01/27/11Client01/28/1101:00pmP11010758MDLQualmg/sample0.010.010.010.01QualParameterTotalDustLABORATORYQUALITYCONTROLDATAMethodReferences/AnalysisDates&AnalystsMethodReferenceDateAnalyzed!AnalyzedByPMMethod5(NIOSHMethod0500)02/02/11TRSNOTiCE/DISCLAIMER:Theenelytlcplre.$ulls,oplnkmsorlnlerpretaUonsc;onlalncdinthl&reporterebasedupOnlnformauonondeupplledbylheclientC'!Xcluslveconflden11alusethisreportha.abeenm&de.Noper:wnorenUtyotherthanlheclientmeyrelayonlhi&report.Anysuchrelicm;ev.illbeunjuGtiRecl.Anyper.oonolhet'lhantheclient.thatreBdsthisll!portdoessoathis:orhero'Mlriak.TheanelyUcslresults,opinionssndlorlnterprelalionsexpressedhereinrepresMtthebes1JudgementofChemlex,basedontheinrorm.ellonandInstructionsreceivedfromthocUenl.Chemtex.meke&nowarrantyorrepresentation,expressorImplied,o(anytype,endexpresslydisclaimssAme.Thl.sreportshallnotbereproduced,in"-"oleorinpert,withoutthewrittenDpprov(llorChamtex.lnnoeventshallChemtexberesponsibleforenydamagegreaterthanfheamountthatitreceivedrorlheenelyslsperfarmed.7of1198CHEMTEX Environmental

& Industrial Hygiene Services 3082 25th Street, Pon Arthur, Texag 77642

• (409) 983-4575 FAX (409) 982-1522 5544 leopard Street, Corpus Christi, Texas 78408

• {361) 299-9900 FAX (361) 299-1155 138 S . Cities Service Hwy., Sulphur, louisiana 70663

• {337) 626-2121 FAX (337) 626-2126 Client: Armstrong Envriomental, Inc 17 48 Hlavek Rd. Decatur, TX 76234
Reporting Date: CHEMTEX File#: LABORATORY QUALITY CONTROL DATA 02/16/11 P11010758 Samples In this QC Batch: P11 01 0758-760,P11010763-765,P11010768-770,P11010773-775 Method Blank (mg/L) QC Batch ID Parameter Result MDL Qb11021122 Antimony <0.02 0.02 Arsenic <0.009 0.009 Beryllium <0.004

0 . 004 Cadmium <0.004 0.004 Chromium <0.004 0.004 Cobalt

<0

. 004 0.004 Lead <0.004 0.004 Manganese <0.004 0.004 Nickel <0.004 0.004 Selenium <0.007 0.007 LABORATORY QliALITY CONTROL DATA LCS and LCSD (mg/1) QC BatchiD Parameter Spk LCS LCS LCSO LCSD RPD RPD Added Result
% Rec Result "IoRee Limit Ob11021122 Antimony 1.000

0 . 980 98

1 . 005 101

3 20 Arsenic 1.000 1.029 103 1.037 104

20 Beryllium 1.000 1.024 102 1.027 103 0.3 20 Cadmium 1.000 1.017 102

1 . 020 102 0.3 20 Chromium 1.000 1.018 102

1 . 021 102 0.3 20 Cobalt 1.000

1 . 013 101 1.017 102 0.4 20 Lead 1.000 1.019 102

1 . 028 103

1 20 Manganese 1.000 1.020 102 1.024 102 0.4 20 Nickel 1.000 1.020 102 1.023 102 0.3 20 Selenium 1.000 1.036 104 1.044 104

20 Qualifier Definition: NOTICE/DISCLAIMER:

The Mllly\ical resulls, opinions orlnlerpnoiOUons conlaW.ed in lhis **r<opo~""'** b.,Gd upon lnfomoaUonand melerialsuppll«<

by lho cllonl lorv.llose **~txtluSive** an<f oonncten\Jal uoe !hi' report has been made

. No pe:Boo or entity other lh81'\ the cllenl may **r~ayon** this reporl Any such rananc• -Mil be unJustmed. Any **pet~on** olher than the cllont, that **~ads:** tills report does so al his or her o'Ml risk. The snalyttcal resutls, opfnions and/or lnl&rl)r9tallons expressed hertln represent the best Judgement or Chcmtex, based on the rnronnetloo end lntllllcliona received rrom the clienL Chemtax makes no w.rranty or represenlstion, expr99; or Implied, ol any type, and expre!sly **d~claims** same

. ThiS repof'\ tlheU not be reproduced,

In Yttlole or In pZirt, without the written approval of Chemlex.
In no DV11nt shall Chemtex be reepoMible for sny damage Qrt:atar th:en the amount thalli received for the anaiY8i' per formed

.

8 of 11
"IoRee Limit 80-120 80-120 80-120 80-120 80-120 80-120 80-120 80-120 80-120 80-120 Qual Qual

. : 99CHEMTEY Environmental

& Industrial Hygiene Services 3082 25th Street, Port Arthur, **Tcxa~** 77642

• (409) 9RJ-4575 FAX (409) 982-1522 5544 Leopard Street, Corpus Christi, Texas 7!!408

• (361) 299-9900 FAX (361) 299-1155 138 S. Cities Service Hwy., Sulphur, Louisiana 70663

• (337) 626-2121 FAX (337) 626-2126 Client: Armstrong Envriomental, Inc 1748 Hlavek Rd. Decatur, TX 76234
Reporting Date: CHEMTEX File#: LABORATORY QUALITY CONTROL DATA Samples In this QC Batch: P1101 0761,P11010766,P1101 0771 ,P11010776 Method Blank (mg/L) QC Batch ID Parameter Result MDL Qb11021123 Antimony <0.02 0.02 Arsenic <0.009 0.009 Beryllium <0.004 0,004 Cadmium <0.004 0.004 Chromium <0.004 0.004 Cobalt <0.004 0.004 Lead <0.004 0.004 Manganese <0.004 0.004 Nickel <0.004 0.004 Selenium <0.007 0.007 LABORATORY QUALITY CONTROL DATA LCS and LCSD (mg/1) QC Batch ID Parameter Spk LCS LCS LCSD LSCSD RPD RPD Added Result % Rec Result %Rec Limit Qb11021123 Antimony

1 . 000 1.004 100 1.052 105

5 20 Arsenic 1.000 1.038 104 1.059 106

2 20 Beryllium 1.000

1 . 035 104 1.045 105

20 Cadmium

1 . 000 1.031 103 1.079 108

5 20 Chromium 1.000 1.031 103 1.045 105

1 20 Cobalt

1 . 000 1.025 103 1.046 105

2 20 Lead

1 . 000 1.030 103 1.021 102

1 20 Manganese 1.000 1.031 103 1.033 103 0.2 20 Nickel 1.000 1.033 103 1.049 105

2 20 Selenium 1.000 1.050 105 1.057 106

20 Qualifier Definition: NOTICEJDISCLAIMER:

The anelytlc&lrt!!!JUIIJ

. oplnk>na or Interpretations conlained
In this report ere bZI!Jcd upon lnforma•on and matlt1191 .supplied by tho client torwho&e cxc:ILI!.Ive and ccnftdential use !his report has been mllde

. No person or entity olher than the ciiMI may relay on this report Any such **rt~ll~~.nce** will be unjustined. Any person ou-.er than lh& client, thai re9d& 1hl& report does so at his or her own rtsk.
. The analyiical resvlls, opinions and/or lnterprelallona fl)(preu9d **he~n** represC!nl !he bestjudgemenl

or Chemtex

. baaed on the lt'lfonnellon and lnstruc.llons recl!lved from f'le dlon!. Chern lex mak&S no warranty or **re~.sentaUon,** express or Implied. or any type. 8ftd expressly disclaims s a me
. This report shall nol ba reproduced,

in whole or In p8rt, -Mihoullhe wrltton opproval of Chemtex.
In no event ehall ChemliX be responsible for 11ny d.,mege grealer then the amount thalli receive.d for the anelysifi par fonned.

9 of 11 02/16/11 P11010758 %Rec Llmlt 80-120 80-120 80-120 80·120 80·120 80-120 80-120 80-120 80-120 80-120 Qual Qual 100CHEMTEX Environmental

& Industrial Hygiene Services
3082 25th Street, Port Arthur, Texas 77642

• (409) 983-4575 FAX (409) 91!2-1522 5544 Leopard Street, Corpus Christi, Texas 78408

• (361) 299-9900 FAX (361) 299-1155 138 S. Cities Service Hwy., Sulphur, Louisiana 70663

• (337) 626-2121 FAX (337) 626-2126 Reporting Date: Client: Armstrong Envriomental, Inc 1748 Hlavek Rd. CHEMTEX File#: Decatur, TX 76234 QC Bacth 10 Qb11020924 QC Bacth ID Qb11020924 Parameter QC Bacth ID : QC Sample ID: Mercury Parameter Mercury Parameter Mercury Sample Result Qb11020924 11020241.04 <0.0001 Qualifier Definition

: Spk LABORATORY QUALITY CONTROL DATA Method Blank (mgll) Result <0

. 0001 LCS MDL 0 . 0001 Qual LCS and LCSD (mg/L) LCS LCSD LCSO Added Result "IoRee Result %Ret 0.0050

0 . 0049 9B 0.0050 100 MS and MSD (mg/L) MS Spk MS MS MSO MSO Added Result
'lo Rec Result %Ret 0.005 0.0050 100 Method References/Analysis Dates & Analysts RPO RPO Limit 2.4 20 RPD RPD Limit 02/16/11 P11010758 "lo Rec Limit B0-120 o/o Rec Limit 75-125 Qual Qual ' Parameter
Method Reference
Date Analyzed/Analyzed

By Antimony
Method 29 I EPA 6010C 02/10/11 Arsenic
Method 29/ EPA 6010C 02/10/11 Beryllium
Method 29 I EPA 601 OC 02/10/11 Cadmium
Method 29 I EPA 6010C 02/10111 Chromium
Method 29/ EPA 6010C 02/10/11 Cobalt
Method 29/ EPA 6010C 02/10/11 Lead
Method 29 I EPA 6010C 02/10/11 Manganese
Method 29/ EPA 601 DC 02/10/11 Nickel
Method 29/ EPA 6010C 02/10/11 Selenium
Method 29/ EPA 6010C 02/10/11 Mercury
Method 29/ EPA 7470A 02/08/11 NOTICE/DJSCLAIMER:

The analytical rosuiLs, opinions or Interpretations contained
In this report are based upon rnronnatlon end mBterial suppned by lhe cllent ror v.hose exclusive and confidential use thl& report hae been mede

. No person or enllty otner than the client may relay on \his repon. Any such reV.ance vAll be unjustified. Any pen;on other then the client. thet r&eds this report does so at his or her oVwn r1sk. The un"lyUcal mull&, opinion a and/or lnterpratallons expressed herein repreaentlhe best Jvd'oement of Chemtex, based on tho lnformejon end inan.cttone receiYed from the **clit~nl** Chemtex mattes no wammty or repreeentation, axpNJu or lmpllad, of any type, end **expre~aly** di&cleims same

. This report ehsn not be reproduced,
In tM\ole: orin pBrl wlthov1 W"le wrltten approve! or ChemleK. In no evenl shall Chemtax be recponslble for eny dtJmf'De prtl&ter then lt'le amount !hal II received for lhe analysis per formed.

10 of 11

sc sc sc sc sc sc sc sc sc sc ss 101CHEMTEX Environmental

& Industrial Hygiene Services 3082 25th Street, Port Arthur, Texas 77642

• (409) 983-4575 FAX (409) 982-1522 5544 Leopard Street, Corpus Christi, Texas 78408

• (361) 299-9900 FAX (361) 299-1155 138 S. Cities Service Hwy., Sulphur, Louisiana 70663

• (337) 626-2121 FAX (337) 626-2126 Client: Armstrong Envriomental, Inc 1748 Hlavek Rd. Decatur, TX 76234 Case Narration Reporting Date: CHEMTEX File#: a) R e f:P 11 0107 5 8+759+760

. P11 01763+764+76

5 ,P 1 1010768+769+770

, P1 1 0 1 0773+774+ 77 5 . 02/16/11 P11010758 1. Samples are digested and made to 1 OOmL volume. This volume is used for metals analysis including mercury. 2. Results and Reporting Limits expressed
in mg/L are reported as such. 3 . Results and Reporting Limits expressed

in mg/sample are calculated from above mg/l values based on the sample volume 100ml (which is the volume after digestion). Ex: For the sample P11 01 0758+759+760, Mn-0.042mg/L
for which mg/Sample value would be =0

. 042.100=0.0042 1000 b) Ref:P11 01 0761.P11 01 0766.P11 01 0771.P11 010776. 1. A 100mL of sample is separated for the mercury analysis and the remaining sample is digested, made to 1 OOmL volume. This volume is used for metals analysis. 2. Results and Reporting Limits expressed

In mg/L are reported as such. 3 . Results and Reporting Limits expressed

in mg/sample are calculated from above mg/L values based on the total sample volume

. Ex: For the sample P11010761, Mn=1.57mg/L for which mg/Sample value would be =1.57*340*1 00 = 0.2224 1000*240 cl Ref:P11Q10762.P1101 0767.P11010772.P1101 0777. 1. Samples are digested and volume is made up to original volume.

It Is then analyzed for mercury. 2. Results and Reporting Limits expressed

in mg/L are reported as such. 3. Results and Reporting Limits expressed

in mg/sample are calculated from above mg/L values based on the total sample volume. Ex: For the sample P11 010762, Hg=0.014mg/L for which mg/Sample value would be =0.014*300

= 0 . 0042. 1000 rs*/CNR

Dr. C. N . Reddy, Ph

. D, CIH, ASP Director NOTICE/DISCLAIMER:

The anely1ical restdlsi, oplnlons: or lnterpllillotlons contained
In lhl1 reporl we based upon information and materi111l supplied by the clienl **rorv..tlose~:** exclusive and corildtnlfal Ule thl:s repor1 hal been m&de

. No p11rcon or enUty othti1rthan lhR client may relpY on thle: report Any sueh renance W\11 be unjudOed. Any person other than **lh~** client. thai reeds lhls report does so at his or her O'M'I rfsk. The anal)'11ca1 results, opinions and/or lnt-:rpretations expressed Mreh1 te:pn=sent
th · e be•l Judgement of ChemtelC, besecl on the lntonnatlon and lnstruction6 reeeived from tie cllenl ChamhiiX me'<es no **wam~ntv** or rept'eZ!enlellon

, txpreu orknplied, or any type, and expressly disclaims uma

. This rl!port shalt ncl be reproduced

, In **~ole** or In part
, wilhcullhe wrillen approv&l of Chemtex

. In no evenl **~htth** Chemtex be responalb

l o 1or any damage **g~aier** than \he amounl thzt It received for the EmBiysl& per formed.

11 of 11

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