## COMPLI ANCE TEST REPORT

BIG BEND STATI O N FACILITY ID NUMBER: 0570039 EMISSION UNIT ID NO: -002 UNIT 2
PARTICULATE MATTER, SULFUR DIOXI D E, and VISIBLE EMISSIO N S

December 15, 2005

Prepared For: Tampa Electric Company Big Bend Station

P.O. Box 111 Tampa, Florida 33601- 0111

Prepared By: Tampa Electric Company Environmental, Health & Safety Environmental Servic es Air Services Group

Envi ronme n tal Servi c es Ai r Servi c es Grou p 5010 Cau s e w ay Boul eva r d Tampa, Fl ori da 336 19- 6 1 30

## REPORT CERTIFICATION

I ha ve revi ewed the t e st perfor ma nce, associated quality assura nce activities, the resulta n t calculations, a n d the contents of this repor t , a n d certify that a ll proj ect quality obj ectives have been met. Th is r

e port is approved for submitta l.

Signature:__________________________ Raymond A

. McDarby, Jr. Senior Envi ronmenta l Technician Quality Assurance/Quality Control Specialist Air Services Group Environme n tal Health & Safety Tampa Elec tric Compa n y

The sampling and subseque nt da ta entry/reduction det a iled in this report were cond ucted at m y d i rection

, and I here by certif y

t h at t h is tes t report is authentic and accurate to t h e best of my knowledge.

Signature:__________________________ Jorge A. Varino Technician Test Team Lead Air Services Group Environme n tal Health & Safety Tampa Elec tric Compa n y

I ha ve revi ewed the t e sting deta ils and results subm itt e d in t h is r e port, and hereby certify that this test report is authenti c and accurate to the best of my k n owle dge.

Signature:__________________________ Davi d A

. S m ith Coordi nator – Air Services Group Environme n tal Health & Safety Tampa Elec tric Compa n y

## TABLE OF CONTENTS

SECTION PAGE NO.
1.0 SUMMARY OF RESULTS 1
2.0 SOURCE DESCRIPTION/TEST PROCEDURES 3
3.0 TEST RESULTS
SOOT BLOWING PARTICULATE TEST SUMMARY 6
NON SOOT BLOWING PARTICULATE TEST SUMMARY 7
SULFUR DIOXIDE INFORMATION SUMMARY 8
OPACITY DATA SUMMARY 9
HEAT INPUT CALCULATIONS 10
4.0 FIGURES
FIGURE 1 SAMPLING LOCATION DIAGRAM 12
APPENDICES
A. PARTICULATE MATTER CALCULATIONS
B. PARTICULATE MATTER LABORATORY ANALYTICAL DATA
C. BOILER/PRECIPITATOR OPERATIONAL DATA
D. PLANT CEMS DAHS PRINTOUTS
E. FUEL ANALYSIS
F. FIELD DATA SHEETS
G. SAMPLING EQUIPMENT CALIBRATIONS
H. CHAIN OF CUSTODY
I. TEST PARTICIPANTS

## 1.0 INTRODUCTION

On Decem ber 15, 2005, Ta mpa Electric Company’s, Environmental Services , Air
Services G r oup, performed source emission tests at the Big B end Station, Boiler No. 2, emissions unit I.D.# 0570039-002. Testing was conducted according to procedures stipulated by t he Fl orida Department of Environmental Protection (FDEP) for fossil fuel steam generators. Testing wa s conducted in accorda n ce with the Title V Permit #05700 39-021-AV, Conditions A.12.

1

## 2.0 DISCUSSION OF RESULTS

The particulate matter emission rate under both soot blowing, and non-soot blowing c onditions were derived from three United States Environmenta l Protection Agency (USEPA) Re f e rence Method 5B test runs. Under soot blowing conditions the average of the three test runs was 0.02 lb/mmBtu. Under nonsoot blowing conditions t he average of the three test runs was 0.02 lb/mmBtu.
The USEPA Consent Decree allowable em i ssion rate under eith er condition is
0.03 lb/mm B tu.

The Sulfur Dioxide (SO 2 

### ) emission rate was determined using data provided by
the Continuous Emis sions Monitoring Syst em’s (CEMS), Data Acquisition and Handling System (DAHS). The average em ission rate for the test period was
determined to be 0.0 l b /mmBtu, and 184 lb s/hr. The FDEP a llowable emission
rate is 6.5 lbs/mmBtu based on a two hour average, and 3277 lbs/hr based on scenario 3 as listed in condition A.9 of the permit.

Visible emissions wer e evaluated using a United Sc iences, Incorporated, Model
500C trans missometer (S/N 5001689), duri ng both soot blowing and non-soot blowing testing. The 1-hour average opac ity under soot blowin g conditions was 4%. The 1-hour average opacity under non- soot blowing conditions was 4%. The FDEP allowable emission rate is 20 percent opacity.

During the test performed on December 15, 2005, Boiler No. 2 w a s operated at an average heat input rate of 3936 mmBtu /hr. The average quantity of fuel burned was 160.3 tons per hour. Base d on the permitted maximum heat input rate of 3996 mmBtu/hr, the capacity factor for this test was determined to be
98%.

2

## 3.0 SOURCE DESCRIPT ION/TEST PROCEDURES

Big Bend Station is located on Big Bend Road, Ruskin, Florida at UTM
coordinates East 361.9 North 3075.0. The Boiler No. 2 particulate matter sampling location consists of a shared circ ular stack 29.83 feet in diameter wit h four sample ports loc a ted 90 degrees apar t on the st ack circum ference. These ports are l o cated downstr eam of the electrostatic precipitator and the FGD scrubber. The sampling ports were determined to be 8.74 diameters
downstream of the transition ductwork and 2.42 diameters upstream of the stack exit. Using these criteria, a total of 12 sampling points wer e chosen for particulate sampling as stipulated in t he USEPA Method 1 test procedure. During this test, Boiler No. 1 was not operating, and was isolated from the FGD module. A diagram of the stack sampling location is included in Figure 1 along with other pertinent information on the test site.

Boiler No. 2 is serviced by an electrostati c precipitator for the control of fl yash emissions, and a flue gas des ulfurization (FGD) system for control of sulfur
dioxide em issions. Generat or and precipitator operations dat a is inc l uded in Appendix C of this report.

Particulate sampling was perform ed according t o USEPA Method 5B
"Determination of Nonsulfuric Acid Partic ulate Matter from Stationary Sources".
Individual test run calcul ations are included as A ppendix A of this report. Particulate matter laboratory analysis may be found in Appendix B of this report.

Diluent gas sampling a nd analys is was performed according to USEPA Metho d 3B "Gas Analysis for Determination of Emission Rate Correction Factor, or
Exc e ss Air”. Gas analysis was perform ed on-site using an Orsat analyzer.

Sulfur Dio xide (SO 2 

### ) and Carbon Dioxide (CO 2 

### ) data were provided by the
Continuous Emissions M onitoring System (CEMS) , Data Acquisition and

3

### Handling System (DAHS). Aver ages were derived fro m the time frame of 11:22 through 19:43 on Dec e mber 15, 2005. This data is incl uded as Appen d ix D of this report.

Visible emissions were a ssessed using the installed Continuous O p acity Monitor (COM), and the CEMS DAHS.

4

## 4.0 TABULATED RESULTS

5

## BI G BEND STAT I O N PAR T ICU L ATE M A TTE R DATA SU M M A R Y

Run 2s Run 3s R un 4s V m(std ) 

### , scf 33.927 34.0 9 9 3 3.748

B ws 

### , ra tio 0.10917 0.118 67 0

. 11333

O 2 

### , % volume 11.5 11.5 1 1

M

d 

### , lb/ l b - mole 30.06 30.0 6 30.12

M

s 

### , lb/ l b - mole 28.74 28.6 3 28.75

Q s 

### , ac f/min 1436013.3 14472 50.2 144 9286.8

Q s(std ) 

### , d s cf/min 1143301.9 11384 27.3 114 4071.9

I, % 100.4 101 .3 99.8

C, lbs/ dscf 1.26E -06 9 .89E-07 7 .58E -07

E r 

### , lb/m mBtu 0.03 0.0 2 0.02

E m ission ra te (E r )

, lb / m m B t u , ca lculat e d a s : C x 97 80 d s cf/ m m B t u x ( 20.9/ ( 2 0

. 9-%O 2 )) 

### 100.50

1.0025E

- 0 6

0.02 30.080

28.706

1444183.46

1141933.66 

### Te s t S u m m ary 33.925

0.11372 3

11.33 

### Bo iler # 2 WE T-B O TTOM U T ILITY B O ILE R De ce m b e r 15, 2005

SOOT B L OW ING



### 6

## BI G BEND STAT I O N PAR T ICU L ATE M A TTE R DATA SU M M A R Y

Run 1 Run 2 R un 3 V m(std ) 

### , scf 34.797 34.0 4 8 3 3.794

B ws 

### , ra tio 0.11678 0.113 31 0

. 11907

O 2 

### , % volume 11.5 1 1 11.5

M

d 

### , lb/ l b - mole 30.06 30.0 4 30.06

M

s 

### , lb/ l b - mole 28.65 28.6 8 28.62

Q s 

### , ac f/min 1475873.9 14565 26.9 145 4119.6

Q s(std ) 

### , d s cf/min 1170759.6 11526 08.9 114 5707.4

I, % 100.5 99.9 99.8

C, lbs/ dscf 1.08E -06 9 .16E-07 9 .88E -07

E r 

### , lb/m mBtu 0.02 0.0 2 0.02

E m ission ra te (E r )

, lb / m m B t u , ca lculat e d a s : C x 97 80 d s cf/ m m B t u x ( 20.9/ ( 2 0

. 9-%O 2 )) 

### 9.9385E

- 0 7

0.02 

### NON - S OOT BLOWING

28.650

1462173.48

1156358.62

100.07 34.213

0.11638 8

11.33

30.053 

### Bo iler # 2 WE T-B O TTOM U T ILITY B O ILE R De ce m b e r 15, 2005

Te s t S u m m ary



### 7

## BIG BEND ST ATI O N SULFUR D I OXID E DAT A FROM CEMs

Te st Pe riod Inform a t ion Start Time 11:22:00 E a ster n St a n d a rd T i me ( E ST ) Stop T i me 19:43:00 E a ster n St a n d a rd T i me ( E ST ) Total Tim e 8 : 2 1 :0 0 Cor r espo ndin g to the ti m e f r ame f o r th e PM te st.

Sul f ur Di o x id e Da t a :

SO 2 

### CO 2 

### SO 2 

### SO 2 

### p p mvw %

, wet l b / mmB t u lbs/hr 14. 21 9. 12 0. 0 184

Calcu l ation D e tails SO 2 

### , lb/m mBtu = SO 2 

### , ppm vw x C f 

### x F c 

### x (100 / CO2 %

, w e t)
where: C f



### = 1.6635E-07 (l b/sc f ) /

ppm S O 2 

### F c



### = 1 800 sc f/mmBtu SO 2 

### , lbs/h r = S O 2 

### , lb/ mmBtu x He at Input, mm Btu/h r where: He a t I n pu t = 3 9 3 6 m mBtu/ h r, f r o m He a t I n pu t Calc ulation 

### Unit #2 W E T-B O TTOM UTI L ITY B O IL E R D e c e mber 15 , 2 0 0 5

CE M DATA RM - 19



### 8Facility: Bi g Bend S t ation Unit: Unit 2 Op e r at in g Con d ition s : Sootblowin g

R e c o rd # D A T E T IME O PA C I TY21 R e c o rd # D A T E T IM E O P A CITY 21 1 12/15/ 05 1256 00 3.9 0

0 3 1 12/ 15 / 0

5 1 32600 4.000 2 12/15/ 05 1257 00 4.3 0

0 3 2 12/ 15 / 0

5 1 32700 4.300 3 12/15/ 05 1258 00 4.3 0

0 3 3 12/ 15 / 0

5 1 32800 4.100 4 12/15/ 05 1259 00 4.6 0

0 3 4 12/ 15 / 0

5 1 32900 4.400 5 12/15/ 05 1300 00 4.5 0

0 3 5 12/ 15 / 0

5 1 33000 4.500 6 12/15/ 05 1301 00 4.8 0

0 3 6 12/ 15 / 0

5 1 33100 4.300 7 12/15/ 05 1302 00 4.2 0

0 3 7 12/ 15 / 0

5 1 33200 4.100 8 12/15/ 05 1303 00 4.1 0 0 3 8 12/ 15 / 0

5 1 33300 4.200 9 12/15/ 05 1304 00 4.4 0

0 3 9 12/ 15 / 0

5 1 33400 4.200 1 0 12/15/ 05 1305 00 4.3 0

0 4 0 12/ 15 / 0

5 1 33500 4.200 1 1 12/15/ 05 1306 00 4.8 0

0 4 1 12/ 15 / 0

5 1 33600 4.200 1 2 12/15/ 05 1307 00 4.9 0

0 4 2 12/ 15 / 0

5 1 33700 4.200 1 3 12/15/ 05 1308 00 4.6 0

0 4 3 12/ 15 / 0

5 1 33800 4.600 1 4 12/15/ 05 1309 00 4.5 0

0 4 4 12/ 15 / 0

5 1 33900 4.600 1 5 12/15/ 05 1310 00 4.3 0

0 4 5 12/ 15 / 0

5 1 34000 4.400 1 6 12/15/ 05 1311 00 4.1 0 0 4 6 12/ 15 / 0

5 1 34100 4.600 1 7 12/15/ 05 1312 00 4.5 0

0 4 7 12/ 15 / 0

5 1 34200 4.200 1 8 12/15/ 05 1313 00 4.5 0

0 4 8 12/ 15 / 0

5 1 34300 3.900 1 9 12/15/ 05 1314 00 4.9 0

0 4 9 12/ 15 / 0

5 1 34400 3.900 2

0 12/15/ 05 1315 00 5.0 0

0 5 0 12/ 15 / 0

5 1 34500 3.700 2 1 12/15/ 05 1316 00 4.5 0

0 5 1 12/ 15 / 0

5 1 34600 3.800 2 2 12/15/ 05 1317 00 4.5 0

0 5 2 12/ 15 / 0

5 1 34700 3.900 2 3 12/15/ 05 1318 00 4.6 0

0 5 3 12/ 15 / 0

5 1 34800 4.000 2 4 12/15/ 05 1319 00 4.4 0

0 5 4 12/ 15 / 0

5 1 34900 3.900 2 5 12/15/ 05 1320 00 4.4 0

0 5 5 12/ 15 / 0

5 1 35000 4.100 2 6 12/15/ 05 1321 00 4.7 0 0 5 6 12/ 15 / 0

5 1 35100 3.700 2 7 12/15/ 05 1322 00 4.8 0

0 5 7 12/ 15 / 0

5 1 35200 3.900 2 8 12/15/ 05 1323 00 5.0 0

0 5 8 12/ 15 / 0

5 1 35300 4.000 2 9 12/15/ 05 1324 00 4.3 0

0 5 9 12/ 15 / 0

5 1 35400 4.000 3

0 12/15/ 05 1325 00 4.1 0 0 6 0 12/ 15 / 0

5 1 35500 3.800

Te st A v e r a g e: 4 % Min i mu m On e M i n u t e A v era g e: 4 % Max i mu m On e M i n u t e Av era g e: 5 % Maxim u m Six Minute Ave r a g e: 5 % V isi b le Emissio n s De termi n a t ion from Opa c ity Mo nitor



### 9Facility: Bi g Bend S t ation Unit: Unit 2 Op e r at in g Con d ition s : No n-sootblow in g

R e c o rd # D A T E T IME O PA C I TY21 R e c o rd # D A T E T IM E O P A CITY 21 1 D A T E T IM E O PA C I TY21 31 12/ 15 / 0

5 1 15100 4.400 2 12/15/ 05 1122 00 4.4 0

0 3 2 12/ 15 / 0

5 1 15200 4.500 3 12/15/ 05 1123 00 4.4 0

0 3 3 12/ 15 / 0

5 1 15300 4.400 4 12/15/ 05 1124 00 4.5 0

0 3 4 12/ 15 / 0

5 1 15400 4.600 5 12/15/ 05 1125 00 4.0 0

0 3 5 12/ 15 / 0

5 1 15500 4.400 6 12/15/ 05 1126 00 3.9 0

0 3 6 12/ 15 / 0

5 1 15600 4.700 7 12/15/ 05 1127 00 4.1 0 0 3 7 12/ 15 / 0

5 1 15700 4.400 8 12/15/ 05 1128 00 4.2 0

0 3 8 12/ 15 / 0

5 1 15800 4.100 9 12/15/ 05 1129 00 4.6 0

0 3 9 12/ 15 / 0

5 1 15900 4.400 1 0 12/15/ 05 1130 00 4.7 0 0 4 0 12/ 15 / 0

5 1 20000 4.900 1 1 12/15/ 05 1131 00 4.5 0

0 4 1 12/ 15 / 0

5 1 20100 4.600 1 2 12/15/ 05 1132 00 4.4 0

0 4 2 12/ 15 / 0

5 1 20200 4.500 1 3 12/15/ 05 1133 00 4.4 0

0 4 3 12/ 15 / 0

5 1 20300 4.300 1 4 12/15/ 05 1134 00 4.8 0

0 4 4 12/ 15 / 0

5 1 20400 4.600 1 5 12/15/ 05 1135 00 4.4 0

0 4 5 12/ 15 / 0

5 1 20500 4.400 1 6 12/15/ 05 1136 00 4.2 0

0 4 6 12/ 15 / 0

5 1 20600 4.500 1 7 12/15/ 05 1137 00 4.2 0

0 4 7 12/ 15 / 0

5 1 20700 4.300 1 8 12/15/ 05 1138 00 4.2 0

0 4 8 12/ 15 / 0

5 1 20800 4.600 1 9 12/15/ 05 1139 00 4.4 0

0 4 9 12/ 15 / 0

5 1 20900 4.600 2

0 12/15/ 05 1140 00 4.7 0 0 5 0 12/ 15 / 0

5 1 21000 4.600 2 1 12/15/ 05 1141 00 4.5 0

0 5 1 12/ 15 / 0

5 1 21100 4.300 2 2 12/15/ 05 1142 00 4.3 0

0 5 2 12/ 15 / 0

5 1 21200 4.900 2 3 12/15/ 05 1143 00 4.3 0

0 5 3 12/ 15 / 0

5 1 21300 4.600 2 4 12/15/ 05 1144 00 4.2 0

0 5 4 12/ 15 / 0

5 1 21400 4.400 2 5 12/15/ 05 1145 00 4.3 0

0 5 5 12/ 15 / 0

5 1 21500 4.700 2 6 12/15/ 05 1146 00 4.1 0 0 5 6 12/ 15 / 0

5 1 21600 4.900 2 7 12/15/ 05 1147 00 4.3 0

0 5 7 12/ 15 / 0

5 1 21700 5.000 2 8 12/15/ 05 1148 00 4.7 0 0 5 8 12/ 15 / 0

5 1 21800 4.500 2 9 12/15/ 05 1149 00 4.6 0

0 5 9 12/ 15 / 0

5 1 21900 5.000 3

0 12/15/ 05 1150 00 4.4 0

0 6 0 12/ 15 / 0

5 1 22000 4.600

Te st A v e r a g e: 4 % Min i mu m On e M i n u t e A v era g e: 4 % Max i mu m On e M i n u t e Av era g e: 5 % Maxim u m Six Minute Ave r a g e: 5 % V isi b le Emissio n s De termi n a t ion from Opa c ity Mo nitor



### 10

## BIG BEND GENERATING STATION H E A T INPU T CALCU L ATIONS

Gr o ss Hea t Ra t e , P r evio us Mo nt h ( S e p t e mb er ) : 10159 K MBt u / M

Wh 1. 0159E +07 MMBt u / M

Wh

Me g aW att H o ur I n te g ra t o r Info rma t io n Init ia l Int e g rator Readin g : 458299 MWh Fina l Inte g rator Readin g : 461534 MWh T o t a l: 3235 MWh

T est Time Info rmat io n Te s t in g St a r t T i me: 11: 22 Te s t in g E n d T i me: 19: 43

Total Te s t Tim e : 8 .35 h ou rs

Calculate d He at I n put Avera g e Unit Lo a d

, MW = MWh / ho ur s: 387. 4 M W Hea t Input

, MMBt u /h = MMBt u /MW h x MW: 3936 mmBt u /hr

Fuel Consum ptio n Calculation

La boratory Sa mple ID: A A 81543 Bt u a s r

e c e ived : 12272 B t u / l b T o ns o f Fuel Co nsumed

, T o ns/ h r = ( m mBt u / h / B t u/ lb ) x 500: 160. 3 T o ns/ h o u r Unit # 2

De ce m b e r 15, 2005 W E T-B O TTOM UTILTIY B O ILE R



### 11

## 5.0 FIGURES

12EX HAUS T S T A C K 426.5 ’ EL. BIG BEND GENER A TI NG STA T ION

P A RTICUL A T E TR A VERSE POINTS

OUTLE T 

# N

PORT LOCATION PL AN

R EVIS E D : 10-Ja n-06 CS0W 1 (BOIL ERS 1 & 2) T EST L O C A T ION

ST A C K DIAME T ER S DO W N ST RE AM F R O M D I S T URB AN CE = 8

. 7 4

ST A C K DIAME T ER S U P ST R E AM F R O M D I S T URB AN CE = 2

. 4 2

ST A C K DIAME T ER = 29.917 FT. ID. ST A C K A R E A = 7 02.95 2 SQ. FT.

PORT LENGTH = 62 I N

. TRAVE RSE

POINT

1

2

3 % OF ST A C K DIAME T ER IN . F R OM ST A C K W A L L

4.4%

14.6%

29.6% 15.80 IN.

52.41 IN.

106.27 IN.

. 499 ’ E L

.

165 ’ E L

. 261.5 ’

FGD

PRESSURI ZED

ANN U L U S 72.5 ’



## A

B C D

9 ’ EL.

FIGURE 1

## APPENDIX A

PARTICULATE MATTER CALCULATIONS

### Environmental Services Air Services Group

40 CFR 60, Appendix A - Test Methods Reference Method 5/17 Particulate Test Calculations

Customer: Tampa Electric Company Facility: Big Bend Station Sampling Location: CS0W1 - Common Stack 1 - Wet Unit Under Test: Boiler #2 Operating Conditions: Soot Blowing Run Number: 1s Date: December 15, 2005

Sample Time, θ : 60 minutes Nozzle Diameter, D n 

### : 0.252 inches Barometric Pressure, P b 

### : 29.46 "Hg Nozzle Area, A n 

### : 0.000346 ft 2 

### Stack Pressure, P s 

### : 29.45 "Hg Average Orifice Meter, ∆ H: 1.068 "H 2 

### O Effective Stack Area, A s 

### : 702.952 ft 2 

### Sample Volume, V m 

### : 35.152 ft 3 

### Pitot Coefficient, Cp: 0.84 dimensionless 

### Average Meter Temp., T m 

### : 81.2 o 

### F Gas Analysis: 10.0 % CO 2 

### Average Stack Temp., T s 

### : 121.5 o 

### F 11.5 % O 2 

### Average √ ∆ p: 0.572 "H 2 

### O

0.0 % CO Condensate Volume, V lc 

### : 88.2 ml 78.5 % N 2 

### Meter Box Y: 1.002 dimensionless 

### F-factor, F d 

### , for fuel: 9780 dscf/MMBtu

Data Calculated from Source Measurements: V w ( std ) 

### = 4.714E-02 x V lc 

### 4.158 scf V m ( std ) 

### = 17.647 x V m 

### x Y x (P b 

### + ( ∆ H / 13.6)) / (T m 

### +460) 33.927 dscf B w s 

### = V w ( std ) 

### / (V m ( std ) 

### + V w ( std ) 

### ) 0.109 % FDA = 1.0 - B w s 

### 0.891 % M d 

### = (0.44 x %CO 2 

### ) + (0.32 x %O 2 

### ) + (0.28 x (%N 2 

### + % CO)) 30.06 lb./lb. mole M s 

### = (M d 

### x FDA) + (18.0 x B w s 

### ) 28.74 lb./lb. mole

v s 

### = 85.49 x C p 

### x ( √∆ p) x ( √ (T s 

### + 460) / (M s 

### x P s 

### )) 34.05 ft/second Q s 

### = v s 

### x A s 

### x 60 1436013.3 acf/minute Q s ( std ) 

### = Q s 

### x FDA x (528 / (T s 

### + 460)) x (P s 

### / 29.92)) 1143301.9 dscf/minute I = (T s + 460) x ((2.67E-03 x V lc ) + (V m(std) / 17.647)) x 100 / ( θ x P s x A n x v s x 60) 

### 100.4 %

Data from Laboratory Analysis: Total Particulate Weight From Laboratory Analysis: 0.019400 grams

Calculated Concentration and Emission Rate Data:

c s 

### = (15.432 x grams) / V m(std) 

### 0.009 grains/dscf grains/acf = c s 

### x 17.647 x P s 

### x (FDA / (T s 

### + 460) 0.007 grains/acf C = c s 

### / 7000 1.261E-06 lbs/dscf E R 

### = C x F d 

### x (20.9 /(20.9 - %O 2 

### ) 0.03 lbs/MMBtu

### Environmental Services Air Services Group

40 CFR 60, Appendix A - Test Methods Reference Method 5/17 Particulate Test Calculations

Customer: Tampa Electric Company Facility: Big Bend Station Sampling Location: CS0W1 - Common Stack 1 - Wet Unit Under Test: Boiler #2 Operating Conditions: Soot Blowing Run Number: 2s Date: December 15, 2005

Sample Time, θ : 60 minutes Nozzle Diameter, D n 

### : 0.252 inches Barometric Pressure, P b 

### : 29.44 "Hg Nozzle Area, A n 

### : 0.000346 ft 2 

### Stack Pressure, P s 

### : 29.42 "Hg Average Orifice Meter, ∆ H: 1.076 "H 2 

### O Effective Stack Area, A s 

### : 702.952 ft 2 

### Sample Volume, V m 

### : 35.255 ft 3 

### Pitot Coefficient, Cp: 0.84 dimensionless 

### Average Meter Temp., T m 

### : 79.7 o 

### F Gas Analysis: 10.0 % CO 2 

### Average Stack Temp., T s 

### : 121.8 o 

### F 11.5 % O 2 

### Average √ ∆ p: 0.575 "H 2 

### O

0.0 % CO Condensate Volume, V lc 

### : 97.4 ml 78.5 % N 2 

### Meter Box Y: 1.002 dimensionless 

### F-factor, F d 

### , for fuel: 9780 dscf/MMBtu

Data Calculated from Source Measurements: V w ( std ) 

### = 4.714E-02 x V lc 

### 4.591 scf V m ( std ) 

### = 17.647 x V m 

### x Y x (P b 

### + ( ∆ H / 13.6)) / (T m 

### +460) 34.099 dscf B w s 

### = V w ( std ) 

### / (V m ( std ) 

### + V w ( std ) 

### ) 0.119 % FDA = 1.0 - B w s 

### 0.881 % M d 

### = (0.44 x %CO 2 

### ) + (0.32 x %O 2 

### ) + (0.28 x (%N 2 

### + % CO)) 30.06 lb./lb. mole M s 

### = (M d 

### x FDA) + (18.0 x B w s 

### ) 28.63 lb./lb. mole

v s 

### = 85.49 x C p 

### x ( √∆ p) x ( √ (T s 

### + 460) / (M s 

### x P s 

### )) 34.31 ft/second Q s 

### = v s 

### x A s 

### x 60 1447250.2 acf/minute Q s ( std ) 

### = Q s 

### x FDA x (528 / (T s 

### + 460)) x (P s 

### / 29.92)) 1138427.3 dscf/minute I = (T s + 460) x ((2.67E-03 x V lc ) + (V m(std) / 17.647)) x 100 / ( θ x P s x A n x v s x 60) 

### 101.3 %

Data from Laboratory Analysis: Total Particulate Weight From Laboratory Analysis: 0.015300 grams

Calculated Concentration and Emission Rate Data:

c s 

### = (15.432 x grams) / V m(std) 

### 0.007 grains/dscf grains/acf = c s 

### x 17.647 x P s 

### x (FDA / (T s 

### + 460) 0.005 grains/acf C = c s 

### / 7000 9.892E-07 lbs/dscf E R 

### = C x F d 

### x (20.9 /(20.9 - %O 2 

### ) 0.02 lbs/MMBtu

### Environmental Services Air Services Group

40 CFR 60, Appendix A - Test Methods Reference Method 5/17 Particulate Test Calculations

Customer: Tampa Electric Company Facility: Big Bend Station Sampling Location: CS0W1 - Common Stack 1 - Wet Unit Under Test: Boiler #2 Operating Conditions: Soot Blowing Run Number: 3s Date: December 15, 2005

Sample Time, θ : 60 minutes Nozzle Diameter, D n : 0.252 inches Barometric Pressure, P b : 29.42 "Hg Nozzle Area, A n : 0.000346 ft 2 Stack Pressure, P s : 29.41 "Hg Average Orifice Meter, ∆ H: 1.083 "H 2 O Effective Stack Area, A s : 702.952 ft 2 Sample Volume, V m : 35.048 ft 3 Pitot Coefficient, Cp: 0.84 dimensionless Average Meter Temp., T m : 81.5 o F Gas Analysis: 10.5 % CO 2 Average Stack Temp., T s : 122.9 o F 11.0 % O 2 Average √ ∆ p: 0.576 "H 2 O

0.0 % CO Condensate Volume, V l c : 91.5 ml 78.5 % N 2 Meter Box Y: 1.002 dimensionless F-factor, F d , for fuel: 9780 dscf/MMBtu

Data Calculated from Source Measurements: V w ( std ) = 4.714E-02 x V l c 4.313 scf V m ( std ) = 17.647 x V m x Y x (P b + ( ∆ H / 13.6)) / (T m +460) 33.748 dscf B ws = V w ( std ) / (V m ( std ) + V w ( std ) ) 0.113 % FDA = 1.0 - B ws 0.887 % M d = (0.44 x %CO 2 ) + (0.32 x %O 2 ) + (0.28 x (%N 2 + % CO)) 30.12 lb./lb. mole M s = (M d x FDA) + (18.0 x B ws ) 28.75 lb./lb. mole

v s = 85.49 x C p x ( √∆ p) x ( √ (T s + 460) / (M s x P s )) 34.36 ft/second Q s = v s x A s x 60 1449286.8 acf/minute Q s ( std ) = Q s x FDA x (528 / (T s + 460)) x (P s / 29.92)) 1144071.9 dscf/minute I = (T s + 460) x ((2.67E-03 x V lc ) + (V m(std) / 17.647)) x 100 / ( θ x P s x A n x v s x 60) 99.8 %

Data from Laboratory Analysis: Total Particulate Weight From Laboratory Analysis: 0.011600 grams

Calculated Concentration and Emission Rate Data:

c s = (15.432 x grams) / V m(std) 0.005 grains/dscf grains/acf = c s x 17.647 x P s x (FDA / (T s + 460) 0.004 grains/acf C = c s / 7000 7.578E-07 lbs/dscf E R = C x F d x (20.9 /(20.9 - %O 2 ) 0.02 lbs/MMBtu

### Environmental Services Air Services Group

40 CFR 60, Appendix A - Test Methods Reference Method 5/17 Particulate Test Calculations

Customer: Tampa Electric Company Facility: Big Bend Station Sampling Location: CS0W1 - Common Stack 1 - Wet Unit Under Test: Boiler #2 Operating Conditions: Non-Soot Blowing Run Number: 1 Date: December 15, 2005

Sample Time, θ : 60 minutes Nozzle Diameter, D n : 0.252 inches Barometric Pressure, P b : 29.50 "Hg Nozzle Area, A n : 0.000346 ft 2 Stack Pressure, P s : 29.49 "Hg Average Orifice Meter, ∆ H: 1.125 "H 2 O Effective Stack Area, A s : 702.952 ft 2 Sample Volume, V m : 35.678 ft 3 Pitot Coefficient, Cp: 0.84 dimensionless Average Meter Temp., T m : 76.3 o F Gas Analysis: 10.0 % CO 2 Average Stack Temp., T s : 119.3 o F 11.5 % O 2 Average √ ∆ p: 0.588 "H 2 O

0.0 % CO Condensate Volume, V l c : 97.6 ml 78.5 % N 2 Meter Box Y: 1.002 dimensionless F-factor, F d , for fuel: 9780 dscf/MMBtu

Data Calculated from Source Measurements: V w ( std ) = 4.714E-02 x V l c 4.601 scf V m ( std ) = 17.647 x V m x Y x (P b + ( ∆ H / 13.6)) / (T m +460) 34.797 dscf B ws = V w ( std ) / (V m ( std ) + V w ( std ) ) 0.117 % FDA = 1.0 - B ws 0.883 % M d = (0.44 x %CO 2 ) + (0.32 x %O 2 ) + (0.28 x (%N 2 + % CO)) 30.06 lb./lb. mole M s = (M d x FDA) + (18.0 x B ws ) 28.65 lb./lb. mole

v s = 85.49 x C p x ( √∆ p) x ( √ (T s + 460) / (M s x P s )) 34.99 ft/second Q s = v s x A s x 60 1475873.9 acf/minute Q s ( std ) = Q s x FDA x (528 / (T s + 460)) x (P s / 29.92)) 1170759.6 dscf/minute I = (T s + 460) x ((2.67E-03 x V lc ) + (V m(std) / 17.647)) x 100 / ( θ x P s x A n x v s x 60) 100.5 %

Data from Laboratory Analysis: Total Particulate Weight From Laboratory Analysis: 0.017000 grams

Calculated Concentration and Emission Rate Data:

c s = (15.432 x grams) / V m(std) 0.008 grains/dscf grains/acf = c s x 17.647 x P s x (FDA / (T s + 460) 0.006 grains/acf C = c s / 7000 1.077E-06 lbs/dscf E R = C x F d x (20.9 /(20.9 - %O 2 ) 0.02 lbs/MMBtu

### Environmental Services Air Services Group

40 CFR 60, Appendix A - Test Methods Reference Method 5/17 Particulate Test Calculations

Customer: Tampa Electric Company Facility: Big Bend Station Sampling Location: CS0W1 - Common Stack 1 - Wet Unit Under Test: Boiler #2 Operating Conditions: Non-Soot Blowing Run Number: 2 Date: December 15, 2005

Sample Time, θ : 60 minutes Nozzle Diameter, D n : 0.252 inches Barometric Pressure, P b : 29.42 "Hg Nozzle Area, A n : 0.000346 ft 2 Stack Pressure, P s : 29.41 "Hg Average Orifice Meter, ∆ H: 1.090 "H 2 O Effective Stack Area, A s : 702.952 ft 2 Sample Volume, V m : 35.144 ft 3 Pitot Coefficient, Cp: 0.84 dimensionless Average Meter Temp., T m : 78.4 o F Gas Analysis: 10.0 % CO 2 Average Stack Temp., T s : 121.5 o F 11.0 % O 2 Average √ ∆ p: 0.579 "H 2 O

0.0 % CO Condensate Volume, V l c : 92.3 ml 79.0 % N 2 Meter Box Y: 1.002 dimensionless F-factor, F d , for fuel: 9780 dscf/MMBtu

Data Calculated from Source Measurements: V w ( std ) = 4.714E-02 x V l c 4.351 scf V m ( std ) = 17.647 x V m x Y x (P b + ( ∆ H / 13.6)) / (T m +460) 34.048 dscf B ws = V w ( std ) / (V m ( std ) + V w ( std ) ) 0.113 % FDA = 1.0 - B ws 0.887 % M d = (0.44 x %CO 2 ) + (0.32 x %O 2 ) + (0.28 x (%N 2 + % CO)) 30.04 lb./lb. mole M s = (M d x FDA) + (18.0 x B ws ) 28.68 lb./lb. mole

v s = 85.49 x C p x ( √∆ p) x ( √ (T s + 460) / (M s x P s )) 34.53 ft/second Q s = v s x A s x 60 1456526.9 acf/minute Q s ( std ) = Q s x FDA x (528 / (T s + 460)) x (P s / 29.92)) 1152608.9 dscf/minute I = (T s + 460) x ((2.67E-03 x V lc ) + (V m(std) / 17.647)) x 100 / ( θ x P s x A n x v s x 60) 99.9 %

Data from Laboratory Analysis: Total Particulate Weight From Laboratory Analysis: 0.014150 grams

Calculated Concentration and Emission Rate Data:

c s = (15.432 x grams) / V m(std) 0.006 grains/dscf grains/acf = c s x 17.647 x P s x (FDA / (T s + 460) 0.005 grains/acf C = c s / 7000 9.162E-07 lbs/dscf E R = C x F d x (20.9 /(20.9 - %O 2 ) 0.02 lbs/MMBtu

### Environmental Services Air Services Group

40 CFR 60, Appendix A - Test Methods Reference Method 5/17 Particulate Test Calculations

Customer: Tampa Electric Company Facility: Big Bend Station Sampling Location: CS0W1 - Common Stack 1 - Wet Unit Under Test: Boiler #2 Operating Conditions: Non-Soot Blowing Run Number: 3 Date: December 15, 2005

Sample Time, θ : 60 minutes Nozzle Diameter, D n : 0.252 inches Barometric Pressure, P b : 29.46 "Hg Nozzle Area, A n : 0.000346 ft 2 Stack Pressure, P s : 29.45 "Hg Average Orifice Meter, ∆ H: 1.088 "H 2 O Effective Stack Area, A s : 702.952 ft 2 Sample Volume, V m : 34.829 ft 3 Pitot Coefficient, Cp: 0.84 dimensionless Average Meter Temp., T m : 78.3 o F Gas Analysis: 10.0 % CO 2 Average Stack Temp., T s : 121.0 o F 11.5 % O 2 Average √ ∆ p: 0.578 "H 2 O

0.0 % CO Condensate Volume, V l c : 96.9 ml 78.5 % N 2 Meter Box Y: 1.002 dimensionless F-factor, F d , for fuel: 9780 dscf/MMBtu

Data Calculated from Source Measurements: V w ( std ) = 4.714E-02 x V l c 4.568 scf V m ( std ) = 17.647 x V m x Y x (P b + ( ∆ H / 13.6)) / (T m +460) 33.794 dscf B ws = V w ( std ) / (V m ( std ) + V w ( std ) ) 0.119 % FDA = 1.0 - B ws 0.881 % M d = (0.44 x %CO 2 ) + (0.32 x %O 2 ) + (0.28 x (%N 2 + % CO)) 30.06 lb./lb. mole M s = (M d x FDA) + (18.0 x B ws ) 28.62 lb./lb. mole

v s = 85.49 x C p x ( √∆ p) x ( √ (T s + 460) / (M s x P s )) 34.48 ft/second Q s = v s x A s x 60 1454119.6 acf/minute Q s ( std ) = Q s x FDA x (528 / (T s + 460)) x (P s / 29.92)) 1145707.4 dscf/minute I = (T s + 460) x ((2.67E-03 x V lc ) + (V m(std) / 17.647)) x 100 / ( θ x P s x A n x v s x 60) 99.8 %

Data from Laboratory Analysis: Total Particulate Weight From Laboratory Analysis: 0.015150 grams

Calculated Concentration and Emission Rate Data:

c s = (15.432 x grams) / V m(std) 0.0069 grains/dscf grains/acf = c s x 17.647 x P s x (FDA / (T s + 460) 0.0055 grains/acf C = c s / 7000 9.883E-07 lbs/dscf E R = C x F d x (20.9 /(20.9 - %O 2 ) 0.02 lbs/MMBtu

## APPENDIX B

PARTICULATE MATTER LABORATORY ANALYTICAL DATACustomerAir ServicesPlantBig BendUnit2Method5BStack Test Completion Date12/15/2005AnalystSample NumberAA81543ACETONE BEAKER1st weighingDate12/21/2005Time16:45% RH34.5%2nd weighingDate12/22/2005Time9:10% RH34.5%3rd weighingDate12/27/2005Time7:45% RH35.0%4th weighingDateTime% RH***Blank***Run 1Run 2Run 3Run 1SRun 2SRun 3SAcetone Container IDAIR30AIR24AIR49AIR28AIR112AIR31AIR110Acetone Rinse Vol.(Va), mls200.00002002002002002002001st Gross Wt., grams101.337297.4122107.496699.2002108.9876107.8083106.10172nd Gross Wt., grams101.337597.4113107.495599.1991108.9870107.8071106.10063rd Gross Wt., grams97.4108107.495199.1989108.9866107.8066106.10094th Gross Wt., gramsAvg. Gross Wt., grams101.3373597.41105107.4953099.19900108.98680107.80685106.10075Tare Wt., grams101.3358097.40500107.4914099.19400108.97770107.80175106.09780Acetone Blank Wt.,mg1.551.551.551.551.551.551.55Acetone Particulate Wt.,mg4.502.353.457.553.551.40Acetone Residue, mg/g0.0098Acetone Blank CriteriaOK to subtract acetone blankFILTER1st weighingDate12/19/2005Time8:50% RH39.5%Date12/20/2005Time14:00% RH41.5%3rd weighingDateTime% RH4th weighingDateTime% RHFilter/Thimble ID2022252022162022182022172022192022202022211st Gross Wt., grams0.26750.27930.27990.27900.27800.27740.27712nd Gross Wt., grams0.26770.27950.28000.27930.27820.27750.27733rd Gross Wt., grams4th Gross Wt., gramsAvg. Gross Wt., grams0.267600.279400.279950.279150.278100.277450.27720Tare Wt., grams0.267300.266900.268150.267450.266250.265700.26700Filter Particulate Wt.,mg12.5011.8011.7011.8511.7510.20Difference, milligrams0.3Total Sample Particulate Wt.,mg17.0014.1515.1519.4015.3011.60Start Here

## APPENDIX C

BOILER/PRECIPITATOR OPERATIONAL DATA

## APPENDIX D

PLANT CEMS DAHS PRINTOUTS

### Big Bend Unit 2 Compliance SO2 Data

Record# DATE TIME SO212 CO211

1 12/15/2005 11:22 13.8 8.7 2 12/15/2005 112300 13.8 8.8 3 12/15/2005 112400 13.5 8.8 4 12/15/2005 112500 13.7 8.9 5 12/15/2005 112600 14 8.9 6 12/15/2005 112700 13.9 8.8 7 12/15/2005 112800 13.5 8.8 8 12/15/2005 112900 13.9 8.9 9 12/15/2005 113000 14.2 9 10 12/15/2005 113100 14.2 9 11 12/15/2005 113200 14 9.1 12 12/15/2005 113300 13.9 9.1 13 12/15/2005 113400 13.2 9.1 14 12/15/2005 113500 13.1 9 15 12/15/2005 113600 13.1 9 16 12/15/2005 113700 13 9 17 12/15/2005 113800 13.2 9 18 12/15/2005 113900 12.8 9 19 12/15/2005 114000 13.1 9 20 12/15/2005 114100 13 9 21 12/15/2005 114200 13.4 9.1 22 12/15/2005 114300 13.5 9 23 12/15/2005 114400 13.7 9 24 12/15/2005 114500 14 9 25 12/15/2005 114600 13.9 8.9 26 12/15/2005 114700 13.5 9 27 12/15/2005 114800 13.8 9 28 12/15/2005 114900 14.4 9 29 12/15/2005 115000 14 9.1 30 12/15/2005 115100 14 9.1 31 12/15/2005 115200 13.2 9.1 32 12/15/2005 115300 12.5 8.9 33 12/15/2005 115400 13.1 8.9 34 12/15/2005 115500 13.5 9

Page 1 of 14

### Big Bend Unit 2 Compliance SO2 Data

Record# DATE TIME SO212 CO211 35 12/15/2005 115600 13.5 9 36 12/15/2005 115700 13.6 9.1 37 12/15/2005 115800 13.8 9 38 12/15/2005 115900 13.9 9.1 39 12/15/2005 120000 14.3 9.1 40 12/15/2005 120100 14.1 9 41 12/15/2005 120200 14.2 9 42 12/15/2005 120300 15 9 43 12/15/2005 120400 15.4 9 44 12/15/2005 120500 14.8 9 45 12/15/2005 120600 15.3 8.9 46 12/15/2005 120700 15.7 8.9 47 12/15/2005 120800 15.1 9.1 48 12/15/2005 120900 15 9.1 49 12/15/2005 121000 14.5 9 50 12/15/2005 121100 13.9 9 51 12/15/2005 121200 14.3 9 52 12/15/2005 121300 14.1 9 53 12/15/2005 121400 13.9 9 54 12/15/2005 121500 14 8.9 55 12/15/2005 121600 14.3 9 56 12/15/2005 121700 14.6 9 57 12/15/2005 121800 14.6 9 58 12/15/2005 121900 15 9.1 59 12/15/2005 122000 15.1 9.1 60 12/15/2005 122100 15.2 9.1 61 12/15/2005 122200 14.8 8.9 62 12/15/2005 122300 14.9 8.9 63 12/15/2005 122400 15.6 9 64 12/15/2005 122500 15.6 9.1 65 12/15/2005 122600 15.3 9.2 66 12/15/2005 122700 15.1 9.2 67 12/15/2005 122800 13.8 9.2 68 12/15/2005 122900 12.9 9.1 69 12/15/2005 123000 13.1 9.1 70 12/15/2005 123100 13.3 9.2 71 12/15/2005 123200 13.6 9.2

Page 2 of 14

### Big Bend Unit 2 Compliance SO2 Data

Record# DATE TIME SO212 CO211 72 12/15/2005 123300 13.3 9.2 73 12/15/2005 123400 13.1 9.1 74 12/15/2005 123500 12.6 9.1 75 12/15/2005 123600 12.8 9 76 12/15/2005 123700 12.8 9 77 12/15/2005 123800 13 9 78 12/15/2005 123900 13.5 9.1 79 12/15/2005 124000 13.5 9 80 12/15/2005 124100 13.9 9 81 12/15/2005 124200 14.2 9.1 82 12/15/2005 124300 14.6 9 83 12/15/2005 124400 14.3 8.9 84 12/15/2005 124500 12.8 8.8 85 12/15/2005 124600 12.1 8.3 86 12/15/2005 124700 12.2 8.6 87 12/15/2005 124800 12.5 8.6 88 12/15/2005 124900 12.4 8.5 89 12/15/2005 125000 12.4 8.6 90 12/15/2005 125100 13.3 8.9 91 12/15/2005 125200 13.3 8.9 92 12/15/2005 125300 13.5 9 93 12/15/2005 125400 13.9 8.9 94 12/15/2005 125500 14.4 8.8 95 12/15/2005 125600 15.2 9 96 12/15/2005 125700 14.4 9 97 12/15/2005 125800 14.1 9 98 12/15/2005 125900 14.2 9 99 12/15/2005 130000 14.3 9.1 100 12/15/2005 130100 14.4 9.2 101 12/15/2005 130200 14 9.2 102 12/15/2005 130300 13.6 9.1 103 12/15/2005 130400 13.8 9.1 104 12/15/2005 130500 13.5 9.1 105 12/15/2005 130600 14.2 9.1 106 12/15/2005 130700 14 9.1 107 12/15/2005 130800 13.7 9.1 108 12/15/2005 130900 14.5 9.1

Page 3 of 14

### Big Bend Unit 2 Compliance SO2 Data

Record# DATE TIME SO212 CO211 109 12/15/2005 131000 14.6 9.1 110 12/15/2005 131100 13.9 9.1 111 12/15/2005 131200 14.8 9 112 12/15/2005 131300 14.6 9.2 113 12/15/2005 131400 14.9 9.2 114 12/15/2005 131500 15.8 9.2 115 12/15/2005 131600 14.8 9.3 116 12/15/2005 131700 14.5 9.4 117 12/15/2005 131800 14.4 9.4 118 12/15/2005 131900 13.5 9.3 119 12/15/2005 132000 13.7 9.3 120 12/15/2005 132100 13.3 9.4 121 12/15/2005 132200 13.2 9.2 122 12/15/2005 132300 13 9.3 123 12/15/2005 132400 13.7 9.4 124 12/15/2005 132500 13.8 9.4 125 12/15/2005 132600 14.2 9.3 126 12/15/2005 132700 14.6 9.2 127 12/15/2005 132800 14.9 9.2 128 12/15/2005 132900 14.3 9.2 129 12/15/2005 133000 14.5 9.1 130 12/15/2005 133100 15 9.1 131 12/15/2005 133200 15.6 9.1 132 12/15/2005 133300 16.4 9.2 133 12/15/2005 133400 15.4 9.2 134 12/15/2005 133500 15.9 9.1 135 12/15/2005 133600 16.3 9.2 136 12/15/2005 133700 15.7 9.2 137 12/15/2005 133800 15.2 9.2 138 12/15/2005 133900 15.1 9.2 139 12/15/2005 134000 15.1 9.2 140 12/15/2005 134100 15 9.3 141 12/15/2005 134200 15.2 9.2 142 12/15/2005 134300 15.3 9.2 143 12/15/2005 134400 14.9 9.2 144 12/15/2005 134500 15.3 9.2 145 12/15/2005 134600 14.9 9.1

Page 4 of 14

### Big Bend Unit 2 Compliance SO2 Data

Record# DATE TIME SO212 CO211 146 12/15/2005 134700 15.2 9.1 147 12/15/2005 134800 15.6 9.1 148 12/15/2005 134900 15.3 9.1 149 12/15/2005 135000 15.7 9.2 150 12/15/2005 135100 15.8 9.2 151 12/15/2005 135200 15.7 9.3 152 12/15/2005 135300 14.6 9.3 153 12/15/2005 135400 14.8 9.3 154 12/15/2005 135500 14.4 9.2 155 12/15/2005 135600 14.4 9.2 156 12/15/2005 135700 14.2 9.1 157 12/15/2005 135800 13.9 9.1 158 12/15/2005 135900 13.9 9.1 159 12/15/2005 140000 14 9.2 160 12/15/2005 140100 14.8 9.3 161 12/15/2005 140200 14.7 9.3 162 12/15/2005 140300 15.2 9.2 163 12/15/2005 140400 15.4 9.3 164 12/15/2005 140500 15.1 9.2 165 12/15/2005 140600 15.2 9.1 166 12/15/2005 140700 15.4 9.1 167 12/15/2005 140800 15.1 9.3 168 12/15/2005 140900 14.9 9.3 169 12/15/2005 141000 14 9.3 170 12/15/2005 141100 13.5 9.2 171 12/15/2005 141200 13.1 9.2 172 12/15/2005 141300 12.9 9.1 173 12/15/2005 141400 12.9 9.1 174 12/15/2005 141500 13.9 9.2 175 12/15/2005 141600 13.7 9.3 176 12/15/2005 141700 13.9 9.3 177 12/15/2005 141800 14.2 9.3 178 12/15/2005 141900 14.5 9.2 179 12/15/2005 142000 14.7 9.2 180 12/15/2005 142100 15.2 9.1 181 12/15/2005 142200 16 9.1 182 12/15/2005 142300 16.2 9.4

Page 5 of 14

### Big Bend Unit 2 Compliance SO2 Data

Record# DATE TIME SO212 CO211 183 12/15/2005 142400 15.3 9.3 184 12/15/2005 142500 14.7 9.3 185 12/15/2005 142600 14.1 9.3 186 12/15/2005 142700 14.5 9.3 187 12/15/2005 142800 14.2 9.3 188 12/15/2005 142900 13.2 9.3 189 12/15/2005 143000 13.6 9.2 190 12/15/2005 143100 13.6 9.3 191 12/15/2005 143200 13.4 9.2 192 12/15/2005 143300 13.3 9.2 193 12/15/2005 143400 13.8 9.1 194 12/15/2005 143500 13.8 9.2 195 12/15/2005 143600 14.1 9.3 196 12/15/2005 143700 14 9.3 197 12/15/2005 143800 14.1 9.2 198 12/15/2005 143900 14.6 9.2 199 12/15/2005 144000 14.4 9.1 200 12/15/2005 144100 15 9.2 201 12/15/2005 144200 15.4 9.3 202 12/15/2005 144300 14.6 9.3 203 12/15/2005 144400 14.1 9.2 204 12/15/2005 144500 14.3 9.2 205 12/15/2005 144600 14.2 9.2 206 12/15/2005 144700 14.1 9.2 207 12/15/2005 144800 14 9.2 208 12/15/2005 144900 14.1 9.2 209 12/15/2005 145000 13.8 9.2 210 12/15/2005 145100 14.4 9.2 211 12/15/2005 145200 14.6 9.3 212 12/15/2005 145300 14.9 9.3 213 12/15/2005 145400 14.8 9.2 214 12/15/2005 145500 14.5 9.1 215 12/15/2005 145600 14.4 9.1 216 12/15/2005 145700 14.7 9.2 217 12/15/2005 145800 15.4 9.2 218 12/15/2005 145900 15.3 9.2 219 12/15/2005 150000 14.8 9.2

Page 6 of 14

### Big Bend Unit 2 Compliance SO2 Data

Record# DATE TIME SO212 CO211 220 12/15/2005 150100 14.4 9.1 221 12/15/2005 150200 13.9 9.1 222 12/15/2005 150300 13.5 9.2 223 12/15/2005 150400 13.7 9.1 224 12/15/2005 150500 14.1 9.3 225 12/15/2005 150600 14.3 9.3 226 12/15/2005 150700 14.3 9.2 227 12/15/2005 150800 14.2 9.2 228 12/15/2005 150900 14.4 9.2 229 12/15/2005 151000 14.7 9.1 230 12/15/2005 151100 14.8 9.2 231 12/15/2005 151200 15.4 9.2 232 12/15/2005 151300 15.2 9.2 233 12/15/2005 151400 15.2 9.3 234 12/15/2005 151500 15.1 9.1 235 12/15/2005 151600 14.9 9.1 236 12/15/2005 151700 14.2 9.2 237 12/15/2005 151800 14.6 9.3 238 12/15/2005 151900 13.1 9.3 239 12/15/2005 152000 12.8 9.2 240 12/15/2005 152100 13.6 9.2 241 12/15/2005 152200 13.2 9.2 242 12/15/2005 152300 13 9.2 243 12/15/2005 152400 13.2 9.2 244 12/15/2005 152500 13.6 9.2 245 12/15/2005 152600 13.6 9.2 246 12/15/2005 152700 13.8 9.1 247 12/15/2005 152800 14 9.2 248 12/15/2005 152900 13.5 9.2 249 12/15/2005 153000 14 9.2 250 12/15/2005 153100 14.4 9.2 251 12/15/2005 153200 14.5 9.3 252 12/15/2005 153300 14.6 9.2 253 12/15/2005 153400 14.4 9.2 254 12/15/2005 153500 14 9.2 255 12/15/2005 153600 13.7 9.1 256 12/15/2005 153700 13.4 9.2

Page 7 of 14

### Big Bend Unit 2 Compliance SO2 Data

Record# DATE TIME SO212 CO211 257 12/15/2005 153800 13.2 9.2 258 12/15/2005 153900 13.1 9.2 259 12/15/2005 154000 13.2 9.2 260 12/15/2005 154100 13.6 9.2 261 12/15/2005 154200 13.4 9.2 262 12/15/2005 154300 14.3 9.2 263 12/15/2005 154400 15 9.3 264 12/15/2005 154500 15.6 9.4 265 12/15/2005 154600 15.4 9.4 266 12/15/2005 154700 15.1 9.3 267 12/15/2005 154800 15.2 9.2 268 12/15/2005 154900 14.9 9.2 269 12/15/2005 155000 14.4 9.2 270 12/15/2005 155100 13.6 9.2 271 12/15/2005 155200 13.5 9.2 272 12/15/2005 155300 13.4 9.2 273 12/15/2005 155400 13.7 9.2 274 12/15/2005 155500 14.1 9.2 275 12/15/2005 155600 14.2 9.2 276 12/15/2005 155700 14.1 9.1 277 12/15/2005 155800 14 9.1 278 12/15/2005 155900 14.3 9.1 279 12/15/2005 160000 14.9 9.3 280 12/15/2005 160100 14.2 9.3 281 12/15/2005 160200 14.2 9.2 282 12/15/2005 160300 14.4 9.2 283 12/15/2005 160400 14.3 9.3 284 12/15/2005 160500 14.3 9.1 285 12/15/2005 160600 14.6 9.2 286 12/15/2005 160700 14.6 9.1 287 12/15/2005 160800 14.7 9.1 288 12/15/2005 160900 14.9 9.2 289 12/15/2005 161000 15.1 9.2 290 12/15/2005 161100 15.3 9.2 291 12/15/2005 161200 15.3 9.2 292 12/15/2005 161300 15.2 9.1 293 12/15/2005 161400 15.2 9.2

Page 8 of 14

### Big Bend Unit 2 Compliance SO2 Data

Record# DATE TIME SO212 CO211 294 12/15/2005 161500 15.7 9.2 295 12/15/2005 161600 16 9.2 296 12/15/2005 161700 15.3 9.1 297 12/15/2005 161800 16.1 9.2 298 12/15/2005 161900 16.3 9.3 299 12/15/2005 162000 14.9 9.2 300 12/15/2005 162100 15.1 9.2 301 12/15/2005 162200 14.6 9.2 302 12/15/2005 162300 14.5 9.3 303 12/15/2005 162400 14.5 9.1 304 12/15/2005 162500 14.5 9.1 305 12/15/2005 162600 14.6 9.1 306 12/15/2005 162700 15.2 9.2 307 12/15/2005 162800 14.9 9.2 308 12/15/2005 162900 14.9 9.2 309 12/15/2005 163000 15.4 9.1 310 12/15/2005 163100 15 9.1 311 12/15/2005 163200 14.8 9.1 312 12/15/2005 163300 15.6 9.2 313 12/15/2005 163400 15.3 9.2 314 12/15/2005 163500 15.3 9.3 315 12/15/2005 163600 14.9 9.2 316 12/15/2005 163700 14.3 9.2 317 12/15/2005 163800 14.1 9.2 318 12/15/2005 163900 13.6 9.1 319 12/15/2005 164000 13.2 9.1 320 12/15/2005 164100 13.3 9.1 321 12/15/2005 164200 14.3 9.2 322 12/15/2005 164300 14.7 9.3 323 12/15/2005 164400 14.6 9.3 324 12/15/2005 164500 15 9.3 325 12/15/2005 164600 15 9.3 326 12/15/2005 164700 14.6 9.2 327 12/15/2005 164800 14.9 9.2 328 12/15/2005 164900 14.6 9.1 329 12/15/2005 165000 14.8 9.1 330 12/15/2005 165100 15.2 9.1

Page 9 of 14

### Big Bend Unit 2 Compliance SO2 Data

Record# DATE TIME SO212 CO211 331 12/15/2005 165200 14.7 9.2 332 12/15/2005 165300 14.3 9.2 333 12/15/2005 165400 14.3 9.2 334 12/15/2005 165500 14.3 9.2 335 12/15/2005 165600 14.3 9.2 336 12/15/2005 165700 14.2 9.2 337 12/15/2005 165800 13.8 9.3 338 12/15/2005 165900 13.4 9.3 339 12/15/2005 170000 13 9.2 340 12/15/2005 170100 13 9.2 341 12/15/2005 170200 12.7 9.2 342 12/15/2005 170300 13.1 9.1 343 12/15/2005 170400 13.4 9.1 344 12/15/2005 170500 13.2 9.2 345 12/15/2005 170600 13.3 9.1 346 12/15/2005 170700 13.7 9.1 347 12/15/2005 170800 13.6 9.1 348 12/15/2005 170900 14.1 9.1 349 12/15/2005 171000 14.1 9.1 350 12/15/2005 171100 13.6 9.2 351 12/15/2005 171200 13.2 9.2 352 12/15/2005 171300 13.1 9.2 353 12/15/2005 171400 13.4 9.1 354 12/15/2005 171500 12.7 9.1 355 12/15/2005 171600 12.3 9 356 12/15/2005 171700 12.7 9.1 357 12/15/2005 171800 13.1 9 358 12/15/2005 171900 12.8 9 359 12/15/2005 172000 13 9 360 12/15/2005 172100 14.4 9 361 12/15/2005 172200 14.6 9 362 12/15/2005 172300 14.6 9 363 12/15/2005 172400 14.8 9.1 364 12/15/2005 172500 14.6 9.1 365 12/15/2005 172600 14.6 9.1 366 12/15/2005 172700 14.6 9.1 367 12/15/2005 172800 14.4 9

Page 10 of 14

### Big Bend Unit 2 Compliance SO2 Data

Record# DATE TIME SO212 CO211 368 12/15/2005 172900 14.2 9 369 12/15/2005 173000 13.8 9 370 12/15/2005 173100 14.2 9 371 12/15/2005 173200 14 9 372 12/15/2005 173300 13.3 9.1 373 12/15/2005 173400 13.4 9 374 12/15/2005 173500 13 9 375 12/15/2005 173600 14.3 9.1 376 12/15/2005 173700 13.7 9.1 377 12/15/2005 173800 13.6 9.1 378 12/15/2005 173900 13.8 9 379 12/15/2005 174000 13.6 9.1 380 12/15/2005 174100 13.2 9 381 12/15/2005 174200 13.4 9 382 12/15/2005 174300 13.3 9 383 12/15/2005 174400 12.8 9 384 12/15/2005 174500 13.2 9.1 385 12/15/2005 174600 13.2 9.1 386 12/15/2005 174700 12.7 9 387 12/15/2005 174800 12.9 9 388 12/15/2005 174900 12.7 9 389 12/15/2005 175000 12.9 9 390 12/15/2005 175100 14.2 9 391 12/15/2005 175200 14.5 9 392 12/15/2005 175300 14.2 9 393 12/15/2005 175400 14.7 9 394 12/15/2005 175500 14.6 9 395 12/15/2005 175600 14.2 9 396 12/15/2005 175700 14.3 9 397 12/15/2005 175800 14 9.1 398 12/15/2005 175900 13.8 9.1 399 12/15/2005 180000 13.4 9.1 400 12/15/2005 180100 13.2 9.1 401 12/15/2005 180200 13.4 9.1 402 12/15/2005 180300 13.8 9 403 12/15/2005 180400 13.8 9.1 404 12/15/2005 180500 13.6 9.1

Page 11 of 14

### Big Bend Unit 2 Compliance SO2 Data

Record# DATE TIME SO212 CO211 405 12/15/2005 180600 14.5 9 406 12/15/2005 180700 13.5 9.1 407 12/15/2005 180800 13.2 9 408 12/15/2005 180900 13.4 9 409 12/15/2005 181000 13.8 9 410 12/15/2005 181100 14.1 9.1 411 12/15/2005 181200 14.1 9.1 412 12/15/2005 181300 13.5 9.1 413 12/15/2005 181400 14.1 9.1 414 12/15/2005 181500 14 9.1 415 12/15/2005 181600 13.5 9 416 12/15/2005 181700 12.8 9 417 12/15/2005 181800 13 9 418 12/15/2005 181900 13.3 9 419 12/15/2005 182000 13.7 9 420 12/15/2005 182100 14.2 9.1 421 12/15/2005 182200 14.4 9.1 422 12/15/2005 182300 14.2 9.1 423 12/15/2005 182400 14.1 9 424 12/15/2005 182500 14.4 9 425 12/15/2005 182600 14.1 9.1 426 12/15/2005 182700 14.3 9 427 12/15/2005 182800 14.3 9 428 12/15/2005 182900 14.6 9.1 429 12/15/2005 183000 15.2 9.1 430 12/15/2005 183100 14.3 9.1 431 12/15/2005 183200 14.1 9.1 432 12/15/2005 183300 14.4 9.1 433 12/15/2005 183400 14.2 9.1 434 12/15/2005 183500 14 9.1 435 12/15/2005 183600 13.9 9 436 12/15/2005 183700 14.5 9.1 437 12/15/2005 183800 14.2 9.1 438 12/15/2005 183900 14.9 9.1 439 12/15/2005 184000 14.5 9 440 12/15/2005 184100 14.2 9 441 12/15/2005 184200 14.8 9

Page 12 of 14

### Big Bend Unit 2 Compliance SO2 Data

Record# DATE TIME SO212 CO211 442 12/15/2005 184300 15 9 443 12/15/2005 184400 15.2 9.1 444 12/15/2005 184500 15.4 9.1 445 12/15/2005 184600 15.8 9.2 446 12/15/2005 184700 14.9 9.1 447 12/15/2005 184800 14.5 9 448 12/15/2005 184900 14.6 9 449 12/15/2005 185000 14 9.1 450 12/15/2005 185100 13.6 9.1 451 12/15/2005 185200 13.5 9.1 452 12/15/2005 185300 13.5 9.1 453 12/15/2005 185400 13.9 9 454 12/15/2005 185500 13.8 9 455 12/15/2005 185600 14.3 9 456 12/15/2005 185700 14.2 9 457 12/15/2005 185800 14.6 9 458 12/15/2005 185900 14.8 9.1 459 12/15/2005 190000 14.8 9.1 460 12/15/2005 190100 15.1 9 461 12/15/2005 190200 14.7 9.1 462 12/15/2005 190300 14.1 9.1 463 12/15/2005 190400 14.1 9.1 464 12/15/2005 190500 14.3 9.1 465 12/15/2005 190600 14 9.1 466 12/15/2005 190700 13.8 9 467 12/15/2005 190800 13.6 9.1 468 12/15/2005 190900 13.7 9.1 469 12/15/2005 191000 13.4 9.1 470 12/15/2005 191100 13.5 9.1 471 12/15/2005 191200 13.9 9.1 472 12/15/2005 191300 13.6 9.1 473 12/15/2005 191400 14.2 9 474 12/15/2005 191500 14.3 9 475 12/15/2005 191600 14.4 9.1 476 12/15/2005 191700 14.9 9.2 477 12/15/2005 191800 14.9 9.2 478 12/15/2005 191900 14.7 9

Page 13 of 14

### Big Bend Unit 2 Compliance SO2 Data

Record# DATE TIME SO212 CO211 479 12/15/2005 192000 15 9 480 12/15/2005 192100 15.2 9.1 481 12/15/2005 192200 15.2 9.2 482 12/15/2005 192300 14.4 9.1 483 12/15/2005 192400 14 9 484 12/15/2005 192500 13 9.1 485 12/15/2005 192600 12.8 9.2 486 12/15/2005 192700 13.4 9.1 487 12/15/2005 192800 13.7 9.1 488 12/15/2005 192900 13.3 9.1 489 12/15/2005 193000 13.3 9.1 490 12/15/2005 193100 13 9 491 12/15/2005 193200 12.8 9.1 492 12/15/2005 193300 13.7 9.1 493 12/15/2005 193400 13.8 9.1 494 12/15/2005 193500 14.1 9.1 495 12/15/2005 193600 14.6 9 496 12/15/2005 193700 14.7 9.1 497 12/15/2005 193800 14.7 9.1 498 12/15/2005 193900 14.4 9.1 499 12/15/2005 194000 14.2 9.1 500 12/15/2005 194100 13.6 9.1 501 12/15/2005 194200 13.7 9 502 12/15/2005 19:43 13.8 9.1 A verages: 14.20888 9.12389

Page 14 of 14

## APPENDIX E

FUEL ANALYSIS

## Laboratory Services 5012 Causeway Blvd * Tampa Fl. 33619 * Ph (813)630-7378 * Fax (813)630-7360 * DOH #E54272
Report For: 

## Laboratory ID: AA81543

Date and Time Collected: Sampled By: 

### Sample Information
ASG Description: 

### Location Code: 01/12/2006 Report Date:

Big Bend 2 Compliance 

### TE_BB_2_COMP_COAL

Project Account Code: 12/16/2005 Date of Sample Receipt: Sample Collection Method:


### Laboratory Results 12/15/2005 7:00:00 PM

Result PARAMETER Qualifier Code Test Method Analyst Units Upper Limit MDL Violation Check Analysis Date & Time Lower Limit
Ash, as Received % 0.01 ASTM D-3174 MM 8.61 12/20/2005 9:42:00 AM Ash, Dry Basis % 0.01 ASTM D-3174 MM 9.47 12/20/2005 9:36:00 AM BTU, as Received BTU/Lb 100 ASTM D-5865 MM 12272 12/21/2005 2:16:00 PM BTU, Dry Basis BTU/Lb. 100 ASTM D-5865 MM 13501 12/21/2005 2:16:00 PM BTU, Moisture-Ash Free BTU/Lb. 100 ASTM D-5865 MM 14913 12/21/2005 2:16:00 PM Calculated Heat Inpu t, mmBtu/hr mmBtu/hr RAM 3936 01/12/2006 2:00:00 PM Particulate Wt., Acetone Beaker, Run 1 mg 0.0001 E PA Method 5B/1 7 RAM 4.5 01/12/2006 2:00:00 PM Particulate Wt., Acetone Beaker, Run 2 mg 0.0001 E PA Method 5B/1 7 RAM 2.35 01/12/2006 2:00:00 PM Particulate Wt., Acetone Beaker, Run 3 mg 0.0001 E PA Method 5B/1 7 RAM 3.45 01/12/2006 2:00:00 PM Particulate Wt., Acetone Beaker, Run 4 mg 0.0001 E PA Method 5B/1 7 RAM 7.55 01/12/2006 2:00:00 PM Particulate Wt., Acetone Beaker, Run 5 mg 0.0001 E PA Method 5B/1 7 RAM 3.55 01/12/2006 2:00:00 PM Particulate Wt., Acetone Beaker, Run 6 mg 0.0001 E PA Method 5B/1 7 RAM 1.40 01/12/2006 2:00:00 PM Particulate Wt., Filter/Thimble, Run 1 mg 0.0001 E PA Method 5B/1 7 RAM 12.50 01/12/2006 2:00:00 PM Particulate Wt., Filter/Thimble, Run 2 mg 0.0001 E PA Method 5B/1 7 RAM 11.80 01/12/2006 2:00:00 PM Particulate Wt., Filter/Thimble, Run 3 mg 0.0001 E PA Method 5B/1 7 RAM 11.70 01/12/2006 2:00:00 PM Particulate Wt., Filter/Thimble, Run 4 mg 0.0001 E PA Method 5B/1 7 RAM 11.85 01/12/2006 2:00:00 PM Particulate Wt., Filter/Thimble, Run 5 mg 0.0001 E PA Method 5B/1 7 RAM 11.75 01/12/2006 2:00:00 PM Particulate Wt., Filter/Thimble, Run 6 mg 0.0001 E PA Method 5B/1 7 RAM 10.20 01/12/2006 2:00:00 PM Particulate Wt., Total Sample, Run 1 mg 0.0001 E PA Method 5B/1 7 RAM 17.00 01/12/2006 2:00:00 PM Particulate Wt., Total Sample, Run 2 mg 0.0001 E PA Method 5B/1 7 RAM 14.15 01/12/2006 2:00:00 PM Particulate Wt., Total Sample, Run 3 mg 0.0001 E PA Method 5B/1 7 RAM 15.15 01/12/2006 2:00:00 PM Particulate Wt., Total Sample, Run 4 mg 0.0001 E PA Method 5B/1 7 RAM 19.40 01/12/2006 2:00:00 PM Particulate Wt., Total Sample, Run 5 mg 0.0001 E PA Method 5B/1 7 RAM 15.30 01/12/2006 2:00:00 PM Particulate Wt., Total Sample, Run 6 mg 0.0001 E PA Method 5B/1 7 RAM 11.60 01/12/2006 2:00:00 PM PM non-sootblowing, lbs/ mmBtu lb/mmBtu EPA RM-5/17 RAM 0.02 01/12/2006 2:00:00 PM PM sootblowing, lbs/mmBtu lb/mmBtu EPA RM-5/17 RAM 0.02 01/12/2006 2:00:00 PM
Pounds SO2 / Million BTU Lbs. SO2/MMBTU Calculated MM 4.59 12/21/2005 2:16:00 PM

SO2 emission rate, lbs/hr lbs/hr EPA - RM6C RAM 184 01/12/2006 2:00:00 PM
Sulfur, as Received % 0.02 ASTM D-4239 MM 2.96 12/20/2005 9:42:00 AM Sulfur, Dry Basis % 0.08 ASTM D-4239 MM 3.26 12/20/2005 9:35:00 AM

Report Number: -011206- 14 AA81543 Page 1 of 2 Laboratory Services certifies that the te st results in this report meet all require ments of the NELAC standards, unless indicat ed otherwise in the body of the report.

## Laboratory Services 5012 Causeway Blvd * Tampa Fl. 33619 * Ph (813)630-7378 * Fax (813)630-7360 * DOH #E54272

Result PARAMETER Qualifier Code Test Method Analyst Units Upper Limit MDL Violation Check Analysis Date & Time Lower Limit
Total Moisture % 0.1 ASTM D-3173 MM 9.1 12/20/2005 9:42:00 AM 

### Comments

Data Qualifier Codes Explanation:



### Robert Dorey, Manager, Laboratory Services Subcontracted Laboratories:

A ll results calculated on a wet to wet basis

, unless otherwise indicated.

Report Number: -011206- 14 AA81543 Page 2 of 2 Laboratory Services certifies that the te st results in this report meet all require ments of the NELAC standards, unless indicat ed otherwise in the body of the report.

## APPENDIX F

FIELD DATA SHEETS

## APPENDIX G

SAMPLING EQUIPMENT CALIBRATIONS

## SUMMARY OF E Q UIPMENT CALIBRATION S Bi g Bend Unit #2

EQUIPMENT CAL DATE METHOD RESULTS
CONSOLE (MB 06) USEPA RM 5 INITIA L 10/10/2005 (ORIFICE) 1.002 POST TEST 12/19/2005 1.011

NOZZLE MN48 INITIA L 10/06/2005 CALIPER 0.252 POST TEST 12/09/2005 MEASUREMENTS 0.252

PYROMETER (PY 06) 10/06/2005 ASTM THERMOMETER + 2 o 

### F
PITOT TUBE (PT 08) 10/17/2005 USEPA RM 2 C p 

### = 0.84

BAROMETER (BR 02) 12/09/2005 NWS COMPARISON + 0.01" Hg

### Environmental Services Air Services Group

Red Team Manufacturer: Thermo Anderson Calibration Date: Model Number:MST-C1 Barometric Pressure: 29.9 "Hg Instrument Code Number: ^MB06 Theoretical Critical Vacuum: 14.10 "Hg LabWorks Sample Number: Calibrated By:

Initial Final Total ∆ H Time Volume Volume Volume Inlet Outlet Inlet Outlet "H 2 

### O Minutes ft 3 

### ft 3 

### ft 3 

### oF oF oF oF 0.64 15 42.356 49.166 6.810 73 72 74 72 1.15 15 49.166 58.232 9.066 75 72 77 73 1.95 15 58.232 69.920 11.688 75 74 81 74 3.70 15 69.920 86.000 16.080 86 75 85 75

Orifice K' A ctual Serial Orifice Vacuum Initial Final Average Number Coefficient "Hg oF oF oF 48 0.3483 21.5 75 75 75.0 55 0.4660 20.0 75 75 75.0 63 0.5971 19.0 75 75 75.0 73 0.8177 16.0 75 75 75.0

Dry Gas Meter Calibration Calibration Volume Volume Volume Y ∆ H α Corrected Corrected Nominal Value QA/QC Value QA/QC Vm (std) , ft 3 Vcr (std) , ft 3 Vcr (std) , ft 3 

### (ratio) + 0.02 "H 2 

### O + 0.2

6.753 6.754 6.851 1.000 -0.002 1.759 -0.029 8.976 9.036 9.165 1.007 0.004 1.761 -0.027 11.556 11.578 11.744 1.002 -0.001 1.812 0.025 15.841 15.855 16.083 1.001 -0.002 1.819 0.031 Averages: 1.002 1.788

Date: Review/Approval:

For Calibration Y, the ratio of the reading of the calibration orifice to the dry gas meter, acceptable tolerance from average is + 0.02. For Calibration ∆ H α , the acceptable tolerance of individual values from the average is + 0.2.



### 12-Oct-05 Critical Orifice Readings Ambient Temperatures

CALCULATED DATA Critical Orifice The Critical Orifice Coefficient, K', should be in English units. 

### IMPORTANT Dry Gas Meter Readings Initial Temperatures Final Tempertures 10/10/2005

JAV

IMPORTANT For valid test results, the Actual Vacuum should be 1 to 2 "Hg greater than the Theoretical Critical Vacuum Shown above. 

### USEPA Reference Method 5

Dry Gas Meter Calibration

Critical Orifice Method Quarterly Calibration

### Environmental Services Air Services Group

Manufacturer: Thermo Anderson Calibration Date: Model Number:MST Barometric Pressure: 30.24 "Hg Instrument Code Number: MB06 Theoretical Critical Vacuum: 14.26 "Hg LabWorks Sample Number: Calibrated By: A ssociated Test: Team: RED

Initial Final Total ∆ H Time Volume Volume Volume Inlet Outlet Inlet Outlet "H 2 

### O Minutes ft 3 

### ft 3 

### ft 3 

### oF oF oF oF 1.15 10 87.727 93.679 5.952 63 69 65 72 1.15 10 93.679 99.673 5.994 65 72 68 75 1.15 10 99.673 105.698 6.025 68 75 69 77

Orifice K' A ctual Serial Orifice Vacuum Initial Final Average Number Coefficient "Hg oF oF oF 55 0.4660 21.0 71 71 71.0 55 0.4660 21.0 71 72 71.5 55 0.4660 21.0 72 72 72.0

Dry Gas Meter Calibration Calibration Volume Volume Volume Y ∆ H α Corrected Corrected Nominal Value QA/QC Value QA/QC Vm (std) , ft 3 Vcr (std) , ft 3 Vcr (std) , ft 3 

### (ratio) + 0.02 "H 2 

### O + 0.2

6.039 6.115 6.087 1.013 0.002 1.751 0.007 6.050 6.112 6.090 1.010 0.000 1.743 -0.001 6.055 6.110 6.093 1.009 -0.002 1.738 -0.006 Averages: 1.011 1.744 Prior Y: 1.002 % Difference: -0.87%

Review/Approval: Date: BB unit 2 compliance

IMPORTANT

IMPORTANT For valid test results, the Actual Vacuum should be 1 to 2 "Hg greater than the Theoretical Critical Vacuum Shown above. The Critical Orifice Coefficient, K', should be in English units.



### Ambient Temperatures Dry Gas Meter Readings Final Tempertures Initial Temperatures

Critical Orifice Readings 

### USEPA Reference Method 5

Dry Gas Meter Calibration

Critical Orifice Method

crd 12/19/2005 

### POST - TEST CALIBRATION CHECK

3-Jan-06 CALCULATED DATA

For Calibration Y, the ratio of the reading of the calibration orifice to the dry gas meter, acceptable tolerance from average is + 0.02. For Calibration ∆ H α , the acceptable tolerance of individual values from the average is + 0.2. 

### Critical Orifice

### Environmental Services A ir Services Group

QUARTERLY NOZZLE CALIBRATIONS Shared Resource STEEL NOZZLE SET

Calibration Date: 10/06/2005 Responsible Party: R.A. Barthelette Jr.

Nozzle Nozzle Diameter, D n Maximum 

### (cm) Average
I.D. D 1 

### D 2 

### D 3 Difference, " 

### D n 

### , inches
^SN01 0.300 0.300 0.300 0.000 0.118 ^SN04 0.320 0.320 0.320 0.000 0.126 ^SN05 0.380 0.380 0.380 0.000 0.150 ^SN06 0.500 0.500 0.500 0.000 0.197 ^SN09 0.700 0.700 0.700 0.000 0.276 ^SN10 0.755 0.755 0.750 0.002 0.297 ^SN12 0.990 0.990 0.985 0.002 0.389 ^SN15 0.420 0.420 0.420 0.000 0.165 ^SN16 0.500 0.500 0.500 0.000 0.197 ^SN19 0.710 0.710 0.710 0.000 0.280 ^SN22 0.935 0.935 0.930 0.002 0.367 ^SN30 0.795 0.795 0.795 0.000 0.313 ^SN36 0.475 0.480 0.480 0.002 0.188 ^SN37 0.520 0.525 0.520 0.002 0.205 ^SN38 0.640 0.640 0.635 0.002 0.251 ^SN46 0.480 0.485 0.480 0.002 0.190 ^SN47 0.515 0.515 0.515 0.000 0.203 ^SN48 0.640 0.640 0.640 0.000 0.252 ^SN50 0.795 0.790 0.795 0.002 0.312 ^SN58 0.615 0.615 0.615 0.000 0.242 ^SN68 0.630 0.630 0.630 0.000 0.248 ^SN69 0.950 0.950 0.950 0.000 0.374 ^SN70 1.560 1.560 1.555 0.002 0.614 ^SN71 1.560 1.555 1.560 0.002 0.614 ^SN72 0.955 0.955 0.955 0.000 0.376 ^SN73 1.280 1.280 1.280 0.000 0.504 ^SN74 1.245 1.245 1.245 0.000 0.490 Data Notations: All micometer readings are converted from cm to inches by multiplying by 0.393700787. Maximum Difference must be < 0.004".



### QA/QC Review by: 10-Oct-05

### Environmental Service s A ir Services Grou p

POST TEST NOZZLE CALIBRATION Shared Resource Calibration Date: 12/19/2005 

### Calibration Personnel: crd 

### Test Designation: BB unit 2 compliance



### Nozzle Nozzle Diameter, D n Maximum 

### (cm) Average Identifier D 1 

### D 2 

### D 3 Difference, " 

### D n 

### , inches

SN48 0.640 0.640 0.640 0.000 0.252

Data Notations: All micometer readings are converted from cm to inches by multiplying by 0.393700787. Maximum Difference must be < 0.004".



### Quarterly (pre-test) value for nozzle ID SN48 was 0.252

Difference (Pre-test/Post-test) is: 0.000

QA/QC Review by: 3-Jan-06

### Environmental Services A ir Services Group Pyrometer Calibration Red Team Pyrometer Under Tes t Pyrometer Number: ^PY06 Labworks Sample # 0 Calibration Date: 10/06/2005

Calibrator Information Calibrator Type/Manufacturer: Hart Scientific Calibrator Serial Number: A OA024 Date of Last Calibration: 03/11/2005 Calibration Personnel (Typed and Signature): R.A. Barthelette Jr.

Calibration Data

Calibration Reference Pyrometer Point Temperature Indication Difference

1 

### 400 401 -1 2 

### 212 211 1 3 

### 32 33 -1

Reference temperatures must encompass the expected range of measurement. These three points should be ~ 32 degrees, ~212 degrees, and ~ 400 degrees Farenheit. Difference is calculated as follows:

(reference temperature ) – (pyrometer indication )

Qaulity Control Data

Calibration Point Difference

1 

### Pass 2 

### Pass 3 

### Pass

Reviewer: 

### 11-Oct-05

### Environmental Services Air Services Group

_ _

s 

### PITOT TUBE CALIBRATION DATA SHEET

Pitot Tube ID # PT08 Calibration Date 10/17/2005 

### Operating Quarter/Year: 4 Shared Resource Openings Damaged?

___ Y

__ N Repaired?

___ Y ___ N ___ N/A

Labworks #: AA79435

Alpha and Beta Angle Determinations Acceptable Limits:

α 1 0.2 degrees 

### Pass Dt 0.48 < Dt > 0.95 cm

α 2 0.2 degrees 

### Pass α < 10 degrees β 1 0.0 degrees 

### Pass ( α 1 measured across top impact openings) β 2 0.3 degrees 

### Pass ( α 2 measured across bottom impact openings) β 1 < 5 degrees (alongside top impact openings) Gamma, Theta, Α
, Ζ
, and W Determination β 2 < 5 degrees (alongside bottom impact openings)

ψ 0.2 degrees Ζ < 0.32 cm ( Α sin ψ )
Α 2.35 cm W < 0.08 cm (Asin ο )
Ζ 0.008 cm 

### Pass Α distance between tips

ο angle of plane on side of pitots

ο 0.0 degrees ψ angle between tips W 0.000 cm 

### Pass

NOTES

All measurements are taken in accordance with the requirements of 40 CFR 60, Appendix A - Test Methods, Method 2, "Determination of stack gas velocity and volumetric flow rate (Type S pitot tube)". Measurement details are found in EPA/600/4-77/027b, "Quality Assurance Handbook for Air Pollution Measurement Systems: Stationary Source Specific Methods", sub-section 3.1.1, Procuement of Apparatus and Supplies.



### Comments: REMOVABLE

Calibrated by: Juan Ramirez

Q uality Assurance Review / Approval: 17-Oct-05

### Environmental Services Air Services Group

BAROMETER CALIBRATION Blue Team Instrument Number: ^BR02 Calibration Date: 12/09/2005 Calibration Personnel: Juan Ramirez Labworks #: Barometer Readin g Reference Readin g Difference T ime Inches Mercury Inches Mercury "H g 8:53 30.15 30.16 -0.01 9:53 30.18 30.18 0 10:53 30.20 30.17 0.03

Avera g e Difference: 0.006667

Note: Barometric readin g s must a g ree within ± 0.1 "H g

. Current Reference is National Weather Service, TIA. Current Conditions at Tampa International Airport Comments (Note any ad j ustments):

QA/QC Review by: 12-Dec-05

## APPENDIX H

CHAIN OF CUSTODY

## APPENDIX I

TEST PARTICIPANTS

## TEST PARTICIPANTS

AIR SERVICES GROUP ENVIRONMENTAL SERVICES
Charles Dufeny Environmental Technician
Juan Ramirez Environmental Technician Jorge Varino Technician
BIG BEND STATION

Karen Zwolak Senior Environmental Consultant