From:   Michael.Pelan@lafarge‐na.com

To:    Keith Barnett/RTP/USEPA/US@EPA

Cc:   Craig.Campbell@lafarge‐na.com, Brian.Gasiorowski@lafarge‐na.com,  

Bill.Voshell@lafarge‐na.com, Paul.Rappleyea@lafarge‐na.com, Robert.Budnik@lafarge‐na.com   

Date:   04/01/2010 12:14 PM   

Subject: HCl Testing results ‐ Section 114 Request  

  

Keith:

Attached are the completed ERT Template spreadsheets for the HCl testing  

conducted at the Ravena and Alpena plants.  As you recall, Alpena Kiln 23

was substituted for Sugar Creek Kiln 3, as this kiln was not operating during  

the period required to collect these data.  Note that I have made a couple of  

minor format adjustments to the Alpena spreadsheet previously sent to you by  

URS, so please use the attached version.

I am also attaching a copy of the Stack Test report for the Ravena testing.

The Alpena testing's report will be finalized in the next 10 days and  

forwarded to you.

If you have any questions, please contact me.

Mike

(See attached file: RAV K1 HCl testing for Section 114 response Mar  

2010.xlsx)(See attached file: RAV K1 FINAL_Lafarge_Stack HCl_033010.pdf)

(See attached file: ALP K23 HCl testing for Section 114 response Mar  

2010.xlsx)(See attached file: RAV K1 HCl testing for Section 114 response Mar  

2010.xlsx)(See attached file: RAV K1 FINAL_Lafarge_Stack HCl_033010.pdf)(See  

attached file: ALP K23 HCl testing for Section 114 response Mar 2010.xlsx)
Worksheet Title: HCl Emission Test Results Template Using Method 321

Who Should Complete this Spreadsheet?

Company Name:

Facility Name: Alpena

Address: 1435 Ford Avenue

City: Alpena

State: Michigan

Kiln ID:

Kiln Type: Long Dry

In-line Raw Mill:

Control Device Configuration: 

Parameter

Sample #1Sample #2Sample #3

Test Average

Units

Units Other 

Description

Test Method Used Test Location Note

Select appropriate unit 

from list. If other is 

selected please describe 

units in column H at right. Enter the name of the Test Method used.

Indicate whether the test 

occurred upstream or 

downstream of a control 

device(s); list the control 

device(s)

If kiln has an in-line raw mill, 

indicate raw mill status during tests 

(i.e., raw mill on or raw mill off). 

Provide any other information 

supporting information you think is 

necessary about this test report. 

Sample Date (mm/dd/yyyy) 3/25/2010 3/25/2010 3/25/2010

HCl Concentration - as measured - dry basis 34.84 33.79 29.55 ppmvd 

Oxygen Concentration - dry basis 6.22 5.96 6.18 % (dry)

CO2 Concentration - dry basis 23.35 23.63 23.24 % (dry)

HCl Concentration - corrected to 7% oxygen 32.99 31.43 27.91 30.78 ppmvd @ 7% O2 Method 321 Downstream NA

Exhaust Stream %Moisture 5.87 5.56 5.25 %

Exhaust Flowrate 146090 144187 145502 SCFM

Exhaust Temperature ~ 400 ~ 400 ~ 400 degrees F Based on preliminary Velocity Traverse on 3/24/2010

Sample Date (mm/dd/yyyy)

HCl Concentration - as measured - dry basis N/A N/A N/A ppmvd 

Oxygen Concentration - dry basis N/A N/A N/A %

CO2 Concentration - dry basis N/A N/A N/A %

HCl Concentration N/A N/A N/A ppmvd @ 7% O2

Exhaust Stream %Moisture N/A N/A N/A %

Exhaust Flowrate N/A N/A N/A (select flowrate units)

Exhaust Temperature N/A N/A N/A (select temperature units)

Notes:

Fabric Filter

Enter HCl concentration value in dry 

parts per million volume (ppmvd). If the 

test results are below detection limit, 

please note the detection limit in 

brackets 

(e.g., [< 0.010]). 

Peach shaded cells indicate areas where the user will enter a response

No

K23

Facilities that use Method 321 to test for HCl

Lafarge North America

Enclosure 5c--ERT Spreadsheet Page 1 of 1
Worksheet Title: HCl Emission Test Results Template Using Method 321

Who Should Complete this Spreadsheet?

Company Name:

Facility Name: Ravena Cement Plant

Address: 1916 Route 9W, PO Box 3

City: Ravena

State: New York

Kiln ID:

Kiln Type: Wet

In-line Raw Mill:

Control Device Configuration: 

Parameter

Sample #1Sample #2Sample #3

Test Average

Units

Units Other 

Description

Test Method Used Test Location Note

Select appropriate unit 

from list. If other is 

selected please describe 

units in column H at right. Enter the name of the Test Method used.

Indicate whether the test 

occurred upstream or 

downstream of a control 

device(s); list the control 

device(s)

If kiln has an in-line raw mill, 

indicate raw mill status during tests 

(i.e., raw mill on or raw mill off). 

Provide any other information 

supporting information you think is 

necessary about this test report. 

Sample Date (mm/dd/yyyy) 3/12/2010 3/12/2010 3/12/2010

HCl Concentration - as measured - dry basis 30.2 26.9 33.5 ppmvd 

Oxygen Concentration - dry basis 4.9 4.9 4.9 %

CO2 Concentration - dry basis 18.6 18.3 17.9 %

HCl Concentration - corrected to 7% oxygen 26.2 23.4 29.1 26.2 ppmvd @ 7% O2 USEPA Method 321 Downstream NA

Exhaust Stream %Moisture 26.4 25.2 24.7 % Samples collected in stack 

Exhaust Flowrate 577,108 575,859 590,980 acfm breaching. See report text for details.

Exhaust Temperature 261,756 263,979 272,533 dscfm

Notes:

Oxygen measurements were conducted at two locations - in the stack

where the volumetric flow rate testing was conducted and in the

breaching, where the HCl testing was conducted. Oxygen data collected at the 

breaching location were used to correct HCl data to 7% O2. See report text for 

further details

No

Facilities that use Method 321 to test for HCl

Lafarge North America

Electrostatic Precipitators

Enter HCl concentration value in dry 

parts per million volume (ppmvd). If 

the test results are below detection 

limit, please note the detection limit 

in brackets 

(e.g., [< 0.010]). 

Kiln 1

Enclosure 5c--ERT Spreadsheet Page 1 of 1
SOURCE EMISSION TEST REPORT

Main Kiln Exhaust Source Emission Testing

Lafarge Building Materials, Inc.

Ravena, New York

March 30, 2010

filg QBRIENEJ GERE

www.obg.com
SOURCE EMISSION TEST REPORT

14198 45892

Main Kiln Exhaust

Source Emission Testing

Lafarge Building Materials, Inc.

Ravena, New York

PATRICK GRADY, PROJECT ASSOCIATE

O'Brien Gere Engineers, Inc.

DAVE OSTASZEWSKI, P.E., SENIOR MANAGING ENGINEER

O'Brien Gere Engineers, Inc.

360' Engineering and Project Delivery Solutions

www.obg.com
MAIN KILN EXHAUST SOURCE EMISSION TESTING

TABLE OF CONTENTS

Table of Contents

List of Tables

List of Appendices

1. Introduction and Background

1.1. Emissions Testing Program Participants

2. Source Description and Process Operating Data

2.1. Process Description

2.2. Sampling Location Description

2.3. Operating Parameters

3. Summary of Test Program

3.1. Test Program Summary

4. Sampling and Analytical Procedures

4.1. Test Methods

4.2. Gas Velocity and Volumetric lrlow Rate

4.3. Moisture Content

4.4. Oxygen and Carbon Dioxide Concentration

4.5. IICI Emissions

5. Summary of Test Results

5.1. Test Results

6. Quality Assurance/Quality Control

6.1. Equipment Calibration

6.2. Leak Checks

LIST OF TABLES

Summary of Source Emission Test Results

LIST OF APPENDICES

Facility Operating Data

Schematic of the Test Location

Reid Data and Calculations

Equipment Calibration Data

Enthalpy Analytical, Inc. Test Report

FINAL: March 30,1010

OBFHENSBERB IAurjrgt.U19314SS9;.Sour[C:-Eml!«or.\Oati\TM!Di>rli\Lalarje_final_Malri Kiln Static H[t_le>t.dooc ^^^^
MAIN KILN EXHAUST SOURCE EMISSION TESTING

1. INTRODUCTION AND BACKGROUND

O'Brien Cere was retained by I.afarge Building

Materials, Inc. {Lafarge) to conduct source emission

testing on the main kiln exhaust at the Lafarge

facility located in Ravena, New York. The objective

of the test program was to satisfy the hydrogen

chloride (IIC1) information Collection Request (ICR)

issued by the United States Environmental

Protection Agency (USEPA) on February 3, 2010.

Messrs. Brian Garrett and Mike Salvagno of O'Brien

Gere and Mr. Clint Thrasher of Enthalpy

Analytical, Inc. performed the field test program.

Mr. Paul Rappleyea was present to monitor process

conditions and collect facility data.

The remaining sections of this report include

summary of the source test program, process

description, sampling methods used, QA/QC

procedures followed for the testing equipment, and

summary of the test results.

1.1. EMISSIONS TESTING PROGRAM

PARTICIPANTS

Facility

Source Testing Companies

Name:

Address:

Contact:

O'Brien Gere

5000 Brittonfield Parkway

East Syracuse, New York

13057

David Ostaszewski

Telephone number: (315) 437-6100

Name:

Address:

Contact:

Telephone number:

Enthalpy Analytical, Inc.

2202 Ellis Road

Durham, North Carolina

27703

Bryan Tyler

(919)850-4392

Name:

Inc.

Site Address:

Contact:

Telephone number:

Lafarge Building

1916 Route 9W

Ravena, NY 12143

Paul Rappleyca

(5181756-5028

FINAL: March 30, 2010

I: J Fa rg 4198\4Sfl 92.Sc e- Eni Is si Dn\Do ARepoitiUaforge_f rca LMo! ri Ki)n Slaclt HCI_I e*I.doiit www.obg.com
MAIN KILN EXHAUST SOURCE EMISSION TESTING

2. SOURCE DESCRIPTION AND PROCESS OPERATING DATA

This section provides description of the Portland

Cement kilns tested, as well as operating

requirements and parameters maintained during

testing.

2.1. PROCESS DESCRIPTION

The Lafarge Ravena Facility is dedicated For

portland cement manufacturing and sales. Lafarge

operates two rotary kilns capable of firing coal and

petroleum coke. Both kilns are exhausted into an

electrostatic precipitator for participate emissions

control before being exhausted through common

stack to the atmosphere.

2.2. SAMPLING LOCATION DESCRIPTION

The kilns exhaust to atmosphere through common

circular stack approximately 260 indies in

diameter. Two test ports, spaced 180° apart are

located 122 feet [approximately 5.6 duct diameters)

downstream of the nearest flow disturbance and

186 feet (approximately 8.6 duct diameters)

upstream of the stack exhaust point. These ports

were used to conduct the volumetric flow rate

monitoring. The HC1 monitoring was not conducted

at this location due to the length of sample line

required to access this location. The long sample

line length resulted in difficulty achieving method

sample recovery QA criteria. Therefore, HCl

sampling was conducted in dedicated breaching to

the kiln exhaust stack. Schematics of test locations

are presented in Appendix B.

2.3. OPERATING PARAMETERS

The testing was conducted while one kiln was

online firing mixture of coal and petroleum coke

and operated at greater than 90 percent toad. Kiln

operations data was collected by facility personnel.

These data included clinker production rate, slurry

feed rate [liter/min), and fuel feed rate (ton/hr).

These facility process data are presented in

Appendix of this test report

FINAL; March 30, 2010

l:\Uljrge.l4198\4539Z. du rce- Im Isilo n\0 oci\Repor! s\t-J1J rge_f nal^Ma Fn K11 Slat C!_le« .do

OBRIENEQERE

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MAIN KILN EXHAUST SOURCE EMISSION TESTING

3. SUMMARY OF TEST PROGRAM

This section provides summary of the testing

scope of work conducted on the- main kiln exhaust

at the Lafarge facility.

3.1. TEST PROGRAM SUMMARY

Source emission testing was conducted to evaluate

emissions of HC1 from the main kiln exhaust located

at the Lafarge facility. Testing was completed on

March 12, 2010 by O'Brien Gere (volumetric flow

rate measurements) and Enthalpy Analytical, Inc.

(HCI FTIR monitoring) personnel.

Testing was conducted in triplicate during normal

process operating conditions as maintained by

facility personnel. Test durations were 60 minutes.

As previously mentioned in Section 2.3, one of the

two kilns was online during the test program. The

kiln fired mixture of coal and petroleum coke

during the testing and was operated at greater than

90 percent capacity.

As previously noted, HCI testing could not be

completed at the stack location due to the length of

sample line required to transport the sample from

the test port on the platform to the FTIR

instrument. The extended sample line length made

it difficult to consistently meet method spike

sample recovery criteria. Therefore, it was decided

on-site to obtain liCl samples in the dedicated

breaching to the kiln stack which could be reached

with much shorter sample line. To evaluate

potential pollutant stratification at this location, an

oxygen stratification check was conducted across

the ductwork. The results of this check indicated

that there was no significant stratification in the

ductwork and the location was acceptable for HCI

sampling. Note that oxygen data collected at this

location were used to correct HCI concentrations to

O2. Results of this testing can be found in

Appendix C.

FINAL: March 30, 2010

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QBIIIENDGERE

www.obg.com
MAIN KILN EXHAUST SOURCE EMISSION TESTING

4. SAMPLING AND ANALYTICAL PROCEDURES

This section provides description of the test

methods Utilized during the RATA program.

4.1. TEST METHODS

Emissions testing was conducted using USEPA

Reference Methods (RM) described in Title 40 CFR

Part 60, Appendix A.

RM 1: Sample and velocity traverses for

stationary sources

RM 2: Determination of stack gas velocity

and volumetric flow rate (Type-S

pitot tube)

RM 3/3A: Determination of oxygen and

carbon dioxide concentrations in

emissions from stationary sources

RM 4: Determination of moisture content

in stack gases

RM 321: Determination of HCI emissions

from stationary sources FT1R

Analyzer Procedure

4.2. GAS VELOCITY AND VOLUMETRIC FLOW

RATE

The gas velocity was determined using velocity

pressure data measured using stainless steel

Type-S pitot tube and manometer across the

diameter of the ductwork. The gas stream

temperature was monitored using Type

thermocouple attached to the pitot tube. Note that

there are only two test ports located 180 degrees

apart in the same plane available for reference

method sampling on the stack platform. Therefore,

velocity and temperature traverses were taken

across the duct in two directions, using the existing

ports. Note that this port layout and volumetric flow

rate procedure has been approved by New York

State Department of Environmental Conservation

(NYSDEC) in the past for previous compliance test

programs. USEPA RMs and were followed to

establish the equal areas to be measured in

identifying the gas velocity and volumetric flow

rate.

4.3. MOISTURE CONTENT

Moisture content was quantified utilizing

procedures identified in USEPA RM 4. sample of

gas was continuously collected using dry gas

meter stack sampling system condensed in series

of impingers. The moisture content of the gas was

measured as change in the volume of the water

collected in each impinger solution and the

increased weight of the desiccant during the

sampling period.

4.4. OXYGEN AND CARBON DIOXIDE

CONCENTRATION

Oxygen concentrations at the HCI sample location in

the stack breaching were determined in accordance

with USEPA RM 3A using California Analytical

Instruments Model 600 paramagnetic analyzer.

continuous gas sample was extracted from the

exhaust stack through sintered filter, stainless

steel probe, heated Teflon line and through

conditioning system used to remove moisture from

the gas stream. All material that came in contact

with the sample was constructed of either stainless

steel, glass, or Teflon.

The reference method analyzer outputs were

monitored using laptop computer and PCMCIA

card and recorded by data acquisition system

[DAS). The DAS reported oxygen data as 1-minute

averages for each test run. Oxygen emissions data

reported by the DAS was corrected for system zero

and span bias. Oxygen and carbon dioxide

concentrations at the stack location were

determined in conjunction with each test run in

accordance with USEPA RM procedures using an

Orsat apparatus.

4.5. HCL EMISSIONS

Concentrations of HCI were evaluated in accordance

with USEPA RM 321 procedures using an on-site

FTIR analyzer. Sample gas was extracted through

probe assembly and heat-traced line, through

sample gas dryer, and into the absorption cell of the

FTIR spectrometer. The heat traced line was

maintained at approximately 375Deg. F. The FTIR

instrument was MIDAC (Series 1-1301) mediumresolution Michelson interferometer spectrometer.

Further details of the FTIR sampling and analytical

instrumentation can be found in Appendix E.

FINAL. March 3D, 2010

www.obg.iom
MAIN KILN EXHAUST SOURCE EMISSION TESTING

5. SUMMARY OF TEST RESULTS

summary of the test results can be found in Table

1. Supporting field data and calculations can be

found in Appendix C. FTIR HC1 analytical results can

be found in Appendix E. brief discussion of the

test results is presented below.

5.1. TEST RESULTS

review of Table indicates that IICI

concentrations on wet basis ranged from

approximately 20.1 ppm to approximately 25.2

ppm, averaging approximately 22.5 ppm. 11 Cl

concentrations corrected to 7% percent oxygen

ranged from approximately 23.4 to approximately

29.1 ppm, averaging approximately 26.2 ppm.

lixcept as noted, there were no operational or

testing problems that impacted the test results and

all test data is believed to be representative of the

emissions encountered during the test program.

FINAL- March 30, 2010

l:\lorjrEt.iai9B\45a9:.Soiirte-Enilssion\[;oci\B!Borls\Li'jr6e_[injLMaiii Kiln Stalk www.obg.com
MAIN KILN EXHAUST SOURCE EMISSION TESTING

6. QUALITY ASSURANCE/QUALITY CONTROL

QA/QC were based OB the recommended QA/QC

procedures of the various sampling and analytical

methods that were used for the source test

program. This section summarizes the pertinent

QA/QC procedures that were employed during the

emissions testing program. Field equipment

calibration data can be found in Appendix and in

the Enthalpy Analytical Report located in Appendix

E.

6.1. EQUIPMENT CALIBRATION

Analyzers, dry gas meters, thermocouples, and pitot

tubes were calibrated in accordance with the

procedures outlined in the corresponding USEPA

test methods and/or the USEPA document entitled

Quality Assurance Handbook for Air Pollution

Measurement Systems: Volume HI Stationary

Source Specific Methods (EPA 600/R-94/038c).

Continuous emission monitoring analyzer response

time tests were conducted Oil each analyzer and the

entire measurement system, as applicable. Each

analyzer and the entire instrument measurement

system were challenged with EPA Protocol No. gas

standards (zero and mid gas) in accordance with

procedures specified in each respective test

method. The calibration gases were introduced to

the sampling system at the sample probe to expose

the calibration standards to as much of the

sampling system as possible. O2 concentrations

were bias corrected in accordance with USEPA RM

7E procedures.

Protocol calibration standards were prepared in

accordance with USEPA Traceahility Protocol for

Assay and Certification of Gaseous Calibration

Standards. The accuracy of these gases were +/-2%

or better. For those concentrations that exceed the

concentration range for commercially available EPA

Protocol standards, the highest analytical grade

commercially available (i.e. master blend)

standards were used. Copies of the calibration

certificates are included in Appendix of this final

source test report.

6.2. LEAK CHECKS

Pitot tube leak checks were conducted in

accordance with USEPA RM 2. Leak checks were

conducted on the moisture sampling trains prior to

and following each test run in accordance with

USEPA RM 4.

FINAL: March 30,1010

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□BniENEQEUE

wwvr.obg.com
360° Engineering and Project Delivery Solutions
Table

Summary of Source Testing Results

Main Kiln Exhaust

Lafarge Ravena Plant

Ravena, New York

Run Identification Run Kun Run Average

Run Date

Start/Stop Time

3/12/10 3/12/10 3/12/10

1036-1136 1201-1301 1403-1503

Exhaust Gas Conditions

Temperature (deg. F)

Moisture (volume %)

Oxygen (dry volume %)

Carbon Dioxide (dry volume %)

Volumetric Flow Rale

acfm

dscfm

HC1 Concentrations

ppm. wet

ppm, dry basis @7% O2

396.0

26.4

10.4

18.6

577,110

261,760

22.2

26.2

401.2

25.2

10.3

18.3

575,860

263,980

20.1

23.4

401.8

24.7

10.4

17.9

590,980

272,530

25.2

399.7

25.4

10.4

18.3

581,317

266,090

22.5

29.1 26.2

OBniEN GERE

www.obg.com

O'BrienS Gere
APPENDIX FACILITY OPERATING DATA

360c Engineering and Project Delivery Solutions

vrww-obg.com
Lafarge Building Materials Ravena NY

HCI Emission Test 31210 Run1

Date

[Y/M/D)

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

Time

10:36:00

10:37:00

10:38:00

10:39:00

10:40:00

10:41:00

10:42:00

10:43:00

10:44:00

10:45:00

10:46:00

10:47:00

10:48:00

10:49:00

10:50:00

10:51:00

10:52:00

10:53:00

10:54:00

10:55:00

10:56:00

10:57:00

10:58:00

10:59:00

11:00:00

11:01:00

11:02:00

11:03:00

11:04:00

11:05:00

11:06:00

11:07:00

11:08:00

11:09:00

11:10:00

11:11:00

11:12:00

11:13:00

11:14:00

11:15:00

11:16:00

11:17:00

11:18:00

11:19:00

Flow mmscfh

27.177

27.350

27.343

27.082

26.710

26.528

26.498

26.828

27.051

26.715

26.802

26.797

26.787

27.201

26.643

26.172

26.501

27.340

26.709

26.304

26.627

27.181

27.076

26.536

26.043

25.940

26.368

26.746

26.984

27.288

27.161

28.192

27.081

26.747

26.585

28.003

27.676

27.365

26.893

26.899

27.035

27.031

27.199

27.267

O2%

8.99

9.04

8.95

9.02

9.14

9.15

9.18

9.16

9.19

9.20

9.26

9.34

9.40

10.57

12.25

10.58

9.99

9.84

9.64

9.48

9.45

9.45

9.46

9.26

9.23

9.17

9.26

9.32

9.37

9.30

9.14

9.33

9.33

9.33

9.23

9.23

9.37

9.44

9.38

9.36

9.22

9.26

9.21

9.23

Temperature,

400.7

400.4

400.0

399.7

400.2

400.6

400.5

401.1

402.0

403.0

403.5

404.1

404.1

414.5

412.8

407.9

407.2

405.3

404.7

404.4

404.0

403.1

402.5

402.2

401.6

400.7

400.5

400.9

401.7

402.2

402.2

403.6

404.0

403.6

402.8

403.2

403.6

405.1

405.4

405.7

404.9

404.0

404.1

404.7

Clinker

production

Rate,

101.6

101.6

101.6

101.6

101.7

101.7

101.7

101.7

101.7

101.7

101.7

101.7

101.7

101.7

101.8

101.8

101.8

101.8

101.8

101.8

101.8

101.8

101.8

101.8

101.9

101.9

101.9

101.9

101.9

101.9

101.9

101.9

101.9

101.9

102.0

102.0

102.0

102.0

102.0

102.0

102.0

102.0

102.0

102.0

Slurry Feed

Liter/Minute

2,300

2,300

2,300

2,300

2.300

2,300

2,300

2,300

2,300

2,300

2,300

2,300

2,300

2,300

2,300

2,300

2,300

2,300

2,300

2,300

2,300

2,300

2,300

2,300

2,300

2,300

2,300

2,300

2,300

2,300

2,300

2,300

2,300

2,300

2,300

2,300

2,300

2,300

2,300

2,300

2,300

2,300

2,300

2,300

Fuel Feed Rate,

Tonne/hour

21.3

21.3

21.3

21.4

21.3

21.3

21.3

21.3

21.3

21.3

21.3

21.3

21.3

21.3

21.3

21.3

21.3

21.2

21.4

21.4

21.4

21.4

21.4

21.4

21.4

21.4

21.6

21.0

21.2

21.4

21.4

21.3

21.6

21.7

21.5

21.4

21.4

21.4

21.4

21.4

21.4

20.7

20.4

20.4
10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

11:20:00

11:21:00

11:22:00

11:23:00

11:24:00

11:25:00

11:26:00

11:27:00

11:28:00

11:29:00

11:30:00

11:31:00

11:32:00

11:33:00

11:34:00

11:35:00

11:36:00

Averages

26.577

26.312

27.033

27.471

27.147

27.044

27.518

27.320

27.224

26.949

26.752

26.497

26.289

26.931

26.709

26.534

26.998

26.914

9.19

9.30

9.16

9.15

9.30

9.31

9.25

9.28

9.23

9.27

9.35

9.35

9.17

9.27

9.27

9.36

9.34

9.381

404.6

404.3

404.0

403.4

403.2

403.2

403.9

404.6

404.5

404.2

404.4

404.4

403.6

403.2

403.8

405.2

405.9

403.659

102.1

102.1

102.1

102.1

102.1

102.1

102.1

102.1

102.1

102.1

102.2

102.2

102.2

102.2

102.2

102.2

2,300

2,300

2,300

2,300

2,300

2,300

2,300

2,300

2,300

2,300

2,300

2,300

2,300

2,300

2,300

2,300

20.7

20.8

20.8

21.0

21.3

21.3

21.3

21.3

21.3

21.3

21.3

21.6

21.4

21.5

21.7

21.5

All data polled at 10 second intervals, reported as 60 second averages

fuel 90% coal, 10% coke
Lafarge Building (Materials Ravona NY

HCI Emission Test 31210 Run

Date

(Y/M/D)

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

Time

12:01:00

12:02:00

12:03:00

12:04:00

12:05:00

12:06:00

12:07:00

12:08:00

12:09:00

12:10:00

12:11:00

12:12:00

12:13:00

12:14:00

12:15:00

12:16:00

12:17:00

12:18:00

12:19:00

12:20:00

12:21:00

12:22:00

12:23:00

12:24:00

12:25:00

12:26:00

12:27:00

12:28:00

12:29:00

12:30:00

12:31:00

12:32:00

12:33:00

12:34:00

12:35:00

12:36:00

12:37:00

12:38:00

12:39:00

12:40:00

12:41:00

12:42:00

12:43:00

12:44:00

Flow mmscfh

27.171

26.967

26.678

26.644

27.049

26.981

26.367

26.578

26.989

27.429

27.880

27.122

27.808

28.102

27.711

27.349

27.140

27.025

27.142

27.447

27.642

27.492

27.485

28.300

27.061

27.431

27.726

27.899

27.979

27.526

27.190

27.037

26.887

26.708

27.082

27.235

27.046

28.083

27.980

27.705

27.477

27.365

27.552

27.513

02%

9.28

9.30

9.23

9.28

9.33

9.23

9.20

9.10

9.01

9.07

9.06

9.11

9.04

9.04

9.14

9.12

9.06

9.09

9.18

9.02

8.94

8.99

9.07

9.03

9.04

9.02

9.10

8.99

9.16

9.14

9.18

9.31

9.43

9.33

9.42

9.25

9.21

9.28

9.25

9.26

9.17

9.12

9.14

9.24

Temperature,

404.3

405.1

404.7

404.3

404.2

403.6

403.1

403.4

403.5

404.9

403.2

402.0

401.7

402.0

402.5

403.2

404.2

405.6

405.8

404.9

400.7

400.9

401.4

402.8

402.4

403.4

405.0

406.0

405.9

404.8

404.2

404.3

404.6

405.1

405.5

405.3

405.7

405.7

406.0

405.6

404.7

403.3

402.8

402.9

Clinker

production

Rate,

102.5

102.5

102.5

102.5

102.5

102.5

102.5

102.5

102.6

102.6

102.6

102.6

102.6

102.6

102.6

102.6

102.6

102.6

102.7

102.7

102.7

102.7

102.7

102.7

102.7

102.7

102.7

1Q2.7

102.7

102.7

102.8

102.8

102.8

102.8

102.8

102.8

102.8

102.8

102.8

102.8

102.8

102.8

102.9

102.9

Slurry Feed

Liter/Minute

2,300

2,300

2.300

2,300

2,300

2,300

2,300

2,300

2,300

2,300

2,300

2,300

2,300

2,300

2,300

2,300

2,300

2,300

2,300

2,300

2,300

2,283

2,283

2,300

2,300

2,300

2,300

2,300

2,300

2,300

2,300

2,300

2,300

2,300

2,300

2,300

2,300

2,300

2,300

2,300

2,300

2,300

2,300

2,300

Fuel Feed Rate,

Tonne/hour

20.9

20.9

20.8

20.8

20.8

20.5

20.8

20.8

20.5

20.4

20.5

20.6

20.6

20.6

20.6

20.6

20.4

20.5

20.7

20.5

20.6

20.6

20.6

20.6

21.0

20.7

20.4

20.7

20.7

20.5

20.8

20.9

20.9

20.9

20.6

20.3

20.2

20.5

20.5

20.8

20.8

20.9

20.6

20.6
10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

12:45:00

12:46:00

12:47:00

12:48:00

12:49:00

12:50:00

12:51:00

12:52:00

12:53:00

12:54:00

12:55:00

12:56.00

12:57:00

12:58:00

12:59:00

13:00:00

13:01:00

Averages

27.202

27.332

27.569

27.345

27.329

27.472

27.160

27.099

27.381

27.795

28.086

27.873

27.665

27.636

27.638

27.452

27.805

27.390

9.25

9.31

9.32

9.26

9.43

9.32

9.26

9.33

9.28

9.28

9.33

9.24

9.22

9.41

9.51

9.42

9.42

9.206

403.5

405.4

406.3

406.0

406.3

406.6

406.3

405.9

405.6

405.0

405.0

404.9

404.6

404.9

405.5

405.8

405.6

404.402

102.9

102.9

102.9

102.9

102.9

102.9

102.9

102.9

102.9

102.9

102.9

102.9

103.0

103.0

103.0

103.0

103.0

2,300

2,300

2,300

2,300

2,300

2,300

2,300

2,300

2,300

2,300

2,300

2,300

2,300

2,300

2,300

2,300

2,300

20.7

20.7

20.6

20.5

20.4

20.5

20.7

21.0

21.0

21.0

21.0

21.0

21.0

21.0

21.0

21.0

20.9

All data polled at 10 second intervals, reported as 60 second averages

fuel 90% coal, 10% coke
Lafarga Building Materials Ravena NY

HCI Emission Test 31210 Run

Date

[Y/M/D)

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

Time

14:03:00

14:04:00

14:05:00

14:06:00

14:07:00

14:08:00

14:09:00

14:10:00

14:11:00

14:12:00

14:13:00

14:14:00

14:15:00

14:16:00

14:17:00

14:18:00

14:19:00

14:20:00

14:21:00

14:22:00

14:23:00

14:24:00

14:25:00

14:26:00

14:27:00

14:28:00

14:29:00

14:30:00

14:31:00

14:32:00

14:33:00

14:34:00

14:35:00

14:36:00

14:37:00

14:38:00

14:39:00

14:40:00

14:41:00

14:42:00

14:43:00

14:44:00

14:45:00

14:46:00

Flow mmscfh

27.446

27.796

27.904

27.718

27.533

27.904

27.344

27.263

27.405

27.552

27.837

27.935

27.831

27.897

27.655

28.499

28.246

27.397

27.122

27.243

27.598

27.588

27.517

27.224

26.930

26.952

27.374

27.740

27.691

27.400

27.626

27.338

27.406

27.590

28.040

28.163

28.103

28.253

28.127

27.868

27.887

27.750

27.590

27.628

02%

9.18

9.28

9.31

9.35

9.30

9.21

9.31

9.27

9.31

9.17

9.28

9.32

9.11

9.06

9.19

9.56

9.83

10.20

10.23

10.32

10.54

10.79

10.65

10.46

10.29

10.33

9.91

9.91

9.99

10.12

10.32

10.36

10.50

10.36

10.23

10.38

10.39

9.97

9.58

9.33

9.07

8.98

9.09

9.27

Temperature,

403.3

404.3

405.0

405.5

405.7

405.4

404.6

405.0

404.5

403.7

403.9

404.6

403.7

403.8

404.9

406.9

407.1

407.5

407.6

407.5

408.3

409.3

409.3

408.0

407.8

407.6

406.8

405.8

406.3

406.7

407.3

407.4

407.8

407.9

406.9

406.5

406.4

405.0

403.4

401.4

400.7

400.6

400.6

401.3

Clinker

production

Rate,

103.3

103.3

103.3

103.3

103.4

103.4

103.4

103.4

103.4

103.4

103.4

103.4

103.4

103.4

103.4

103.4

103.4

103.4

103.4

103.4

103.4

103.5

103.5

103.5

103.5

103.5

103.5

103.5

103.5

103.5

103.5

103.5

103.5

103.5

103.5

103.5

103.6

103.6

103.6

103.6

103.6

103.6

103.6

103.6

Slurry Feed

Liter/Minute

2,294

2,294

2.294

2,294

2,319

2,297

2,297

2,297

2,297

2,297

2,297

2,297

2,297

2,297

2,297

2,297

2,297

2,297

2,297

2,297

2.297

2,297

2,297

2,297

2,297

2,297

2,297

2,297

2,297

2,297

2.297

2,297

2.297

2,297

2,297

2,297

2,297

2,297

2,297

2.297

2,297

2,297

2,297

2,297

Fuel Feed Rate,

Tonne/hour

20.9

20.8

20.8

20.7

20.7

20.7

20.8

20.8

21.0

20.8

21.0

21.0

20.9

21.0

21.2

21.2

21.2

21.2

21.1

21.1

21.0

20.5

20.7

20.7

20.7

20.9

20.8

20.5

20.5

20.8

20.9

20.9

20.8

20.8

20.8

20.9

20.9

20.9

20.9

20.9

20.9

20.9

20.9

20.8
10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

10/3/12

14:47:00

14:48:00

14:49:00

14:50:00

14:51:00

14:52:00

14:53:00

14:54:00

14:55:00

14:56:00

14:57:00

14:58:00

14:59:00

15:00:00

15:01:00

15:02:00

15:03:00

27.474

27.497

28.069

28.198

28.118

28.050

27.977

27.898

28.230

28.457

28.068

27.400

27.297

28.248

29.157

28.197

27.956

9.25

9.16

9.30

9.23

9.13

9.16

9.27

9.45

9.38

9.32

9.28

9.15

9.16

9.02

9.10

9.17

9.24

401.6

400.6

400.6

400.7

400.0

400.5

400.9

401.1

401.0

400.8

399.6

398.6

398.6

398.6

400.4

400.1

398.8

103.6

103.7

103.7

103.7

103.7

103.7

103.7

103.7

103.7

103.7

103.8

103.8

103.8

103.8

103.8

103.8

103.8

2,297

2,297

2,297

2,297

2,297

2,297

2,297

2,297

2,297

2,297

2,297

2,297

2,297

2,297

2,297

2,297

2,297

20.7

20.6

20.6

20.6

20.6

20.5

20.4

20.4

20.1

20.3

20.3

20.3

20.3

20.0

20.2

20.3

20.5

Averages 27.757 9.613 404.028

All data polled at 10 second intervals, reported as 60 second averages

fuel 90% coal, 10% coke
APPENDIX SCHEMATIC OF THE TEST LOCATION

360* Ehglnaartng ard Project Delivery Solutions

www.obg.com
r....
Zli£±~
uwvrose point

LOCMHtHS

IBS'

av-r

/— KTOWM. 8H0K

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punww

8ROCHNB

LAFARQE BUILDINC MATERIALS, Ino.

EXHAUST STACK

HWYOW
APPENDIX FIELD DATA AND CALCULATIONS

360' Engineering and Project Delivery Solutions

www.obg.com
Parameter

Run Date

Start/Stop Time

Duration ofRun, Minutes

Pitot Calibration Factor, CF

Meter Gamma

Motor Delta H, inches of H2O

Stack Diameter, inches

Rectangular Width, inches

Rectangular Length, inches

Stack Area, sq.ft.

Barometric Pressure, inches of Hg

Static Pressure, inches of H2O

Drv Gas Mater Samnle Volume, VM1R3

Initial

Final

Difference

Avo. Stack Temperature, Ts(F)

Ave. Meter Temperature, Tm(F)

Ave. Run Delta H, inches of H2O

Ave. Square Root of Delta

Moisture Data

Volume of water collected, mis

Silica Gel, grama

Total Collected, mis

ORSATData

%O2

%CO2

%CO

Calculations

Vw(std). scfVm(std), dscf

Bws="

Md=

Ms=

Vs, ft/sec

Qs, acfin

Qs(std), dscfin

Test Data Summary and

LaFarge Inc

Kiln Exhaust

Ravena, NY

Run!

3/12/10

1036-1136

60

0.84

1.004

1.72

260

30

-1.2

767.311

808.363

41.052

396.0

73.3

1.72

0.3584

304

9.9

313.9

10.4

18.6

14.775

41.092

0.264

31.39

27.85

26.1

577,108

261,756

Calculations

Run2 Run3

3/12/10

1201-1301

60

0.84

1.004

1.72

260

30

-1.2

3/12/10

1403-1503

60

0.84

1.004

1.72

260

30

-1.2

808.578

847.634

847.756

890.057

39.056 42.301

401.2 401.8

77.0 78.4

1.72 1.72

0.3573 0.3667

270 280

12.4

278 292.4

10.3

18.3

10.4

17.9

13.085 13.763

38.818 41.939

0.252 0.247

31.34 31.28

27.98 28.00

26.0 26.7

575.859 590,980

263,979 272,533

Where:

Vw(std) volume of water vapor in gas,' standard conditions 0.04707*Vic

Vm(std) vol. of gas sampled, standard conditions 17.647 Vm gamma [Pb (dH/13.6)]/Tm(R)

Bws = water vapor in gas stream, proportion by volume Vw(stdy( Vm(std) Vw(std))

Md molecular weight of stack gas, dry basis (0.44 x%CO2) (0.32 x%O2) [0.28 (%N2 %CO)|

Ms =* molecular weight of stack gas, wet basis [Md x(l-Bws)] (18.0 xBwa)

Vs stack gas velocity 85.49 Cp (avg. Sq.Rt. dP) {Sq.Rt. (Ts(R)y(Ms Ps)]

Qs stack gas flow rate VsxAsx60

Qs(std) stack gas flow rate, standard conditions Qjx (1-Bws) (528/(Ts(R)) (Ps/29.92)
Field Data Summary

LaFarge Inc

Kiln Exhaust

Ravena, NY

Travcnc

Point

Al

Bl

Average

Start

Temp(F)

403

403

403

404

404

404

378

372

404

404

404

403

402

400

378

370

3%

Run!

Delta

0.15

0.15

0.14

0.13

0.13

0.11

0.00

0.06

0.16

0.16

0.17

0.15

0.14

0.13

0.10

0.10

0.13

Tm(F)

In

69

70

71

72

74

76

77

78

79

80

81

81

76

mil

t>y

69

69

69

70

70

71

71

71

73

74

74

71

SQRT

Dollar

0.3 B73

0.3873

0.3742

0.3606

0.3*506

0.3317

0.2828

0.2R2B

0.4000

0.4000

0.4123

0.3873

0.3742

0.3606

0.3162

3162

o.ooon

0.(1000

0.0000

o.oooo

0,0000

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

0.3584

Stuck

Tcmp(F)

4Ob

405

405

404

400

395

390

385

405

405

405

405

405

405

400

400

401

Run

Delia

0.16

0.16

0.15

0.15

0.14

0.12

0.10

0.10

0.16

0.16

0.15

0.14

0.12

0.10

0.08

0.08

0.13

Tn

In

Ib

76

76

78

80

81

81

82

82

83

03

84

out

iM

74

74

74

74

74

74

74

74

74

74

74

74

SQRT

Delia

0.4000

0.4000

0.3873

0.3873

0.3742

0.3464

0.3162

0.3162

0.4000

0.4000

0.3873

0.3742

0.3464

0.3162

0.2828

0.2828

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

0.3573

Stach

Temp(F)

406

406

405

406

405

404

394

394

406

406

404

403

403

400

395

392

402

Rim3

Delta

0.16

0.16

0.15

0.14

0.14

0.13

0.08

0.08

0,17

0,17

0.16

0.15

0.15

0.14

0.10

D.10

0.14

TmflO

In

75

75

75

77

78

82

83

B4

85

85

ae

86

81

out

l<\

74

74

75

75

76

76

76

77

77

7fl

78

76

SQRT

Dcll.P

0.401)1)

0.4000

0.3873

0,3742

0.3742

0.3606

0.2828

0.2828

0.4123

0.4123

0.4000

0.3873

0.3873

0.3742

0.3162

0.3162

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

(t.OOOO

0.0000

0.0000

0.0000

0.0000

0.0000

0.3667




OBRIENGGEFIE

Cllant

Location

Sourca

Orsat Data Sheet

Date

Operator

Barometrte ProMitro

Ambient Tsmpiraturs

Calibration Gas:

02

C02

IA.0

n.t

Pro-Tost

Calibration

Trial

Average

I1).?

UU2+U2 u2

n.t>

/JO

12.2.

Trial

Average

CO2

if.r

)9.L.

It.L

UO2+U2 u2

/P.¥

/o.i

lO.i4

Trial

Average

Trial

Average

CU2

a.

iffit

/g.H

(JO2

n.t

n.i

/9.0

UU2+O2 u2

1/i.S

/0t¥

/A

uo2+02 u2

//>.S

JDA

/&4

Post-Teat

Calibration

Trial

Average

JA9

UO2+U2 o2

JJL.I

12.3

/A.I

UKfUI R*te«IK(K 20.9- %O2

ftCO,

Fuel Type F. Range

Coal: Anchraclto and lignite . . 1.016 1.130

Dltuiulnoua 1.083 1.230

Oii: Distillate 1.260 1.413

Residual 1.210 1.370

Gas: Natural 1.600 1.836

Propane 1.434 1.586

Butane 1.405-1.553

Wood 1.000 1.120

Wood bark 1.003 1.130

Otuttf*
APPENDIX EQUIPMENT CALIBRATION DATA

360" Engineering and Project Delivery Solutions

www.Dbg.CDin


O'BRIEN GERE

Analyzer Response Time

Pollutant 02

Analyzer Serial No.

Date lull

P06050

Time

Run

Run

Run

Average

Upscale Response

Hi

Hk

HI

Hx

seconds

seconds

seconds

seconds

/7A

Analyzer I.D. CAI200

High Span Gas 21.22

Runl

Run

Run

Average

Downscale Response

seconds

seconds

seconds

seconds

Pollutant

Analyzer Serial No.

Date Time

Run

Run

Run

Average

Upscale Response

seconds

seconds

seconds

seconds

Analyzer I.D.

High Span Gas

Run

Run

Run

Average

Downscale Response

seconds

seconds

seconds

seconds
OBIilENGGERE

Daily Analyzer Calibration

Plant I.D.

Source I.D._

Pollutant

Lafarge Inc

Main Kiln Stack

O2

Analyzer Serial No.

Date 3/11/2010

P060S0

Time NA

Project No.

Personnel

Analyzer I.D.

Span Value

Test Method

B.Garrett

CAI200

21

3A

Zero Gas

Cylinder Value

(ppm or %)

0.0

Analyzer

Response

(ppm or %)

0.01

Calibration

Error

(% of Span)

+/-2%

0.0

System

Response

(ppm or %)

0.06

System

Bias

(% of Span)

+/-5%

0.2

Cylinder ID

Low Level Gas

Cylinder ID

Mid Level Gas

High Level Gas

12

Cylinder ID

21.22

Cylinder ID

12.18

CCI29819

21.14

CC834O

0.9

-0.4

12.24

NA

0.3

NA

Calibration Error (Analyzer Response Cylinder Value) 100

Span Value

System Bias (System Response Analyzer Response) 100

Span Value


|sl OBRIENGOERE «3=* ENGINEERS. INC

Post-Test Sample Probe Calibration Fonn

Probe ID P10-A

Visual Inspection

Do pftot Spa appear to be damaged?

Do thermoeoupto wires appear broken or shorted?

Do all components appear to be In good condition?

Post-Test Thermocouple Calibration

Referanoo Temperature °F

56.4

_np_

.no

Thermocouple Temperature °F

56.2

RsfartrxaThsmoceusta Rita SM8J4S0OM trocar

Olrferonoe'F

•0.2

Accapatable D«vla«on ♦/- 2 °F

Acceptable

Unacceptable

Date 03/16/10 Technician MAS

P10-A031810.xls

1=1 OBRIENSQERE

ENGINEERS INC

Post-Test Sample Probe Calibration Form

Probe ID P10-A

Visual Inspection

Do pilot tips appear to be damaged?

Do Biermocouple wires appear broken or shorted?

Do all components appear to be In good condiUon?

Post-Test Thermocouple Calibration

Reference Temperature °F

66.4

RrtWor«TNs7noctt«iaFn^E«:9MSOOMl/4»4B«h)0«UnlJodSli

no

no

Thermocouple Temperature °F

58.2

KM rwJQOnal HliUlUW CT OUtnOanM Qnu (OCnmOuy

Oltferonoe°F

•0.2

Accepatable Deviation +/. °F

Unacceptable

Date 03/18/10 Technician MAS

P10-A031810jtb
1PRAXAIR Praxair Distribution Mid-Atlantic LLC

US Shlmenvllle Road Bothtehom, PA 1801$ Phono: 610.317.1608 pox; 610.758.8384

CutionurA Order Informations

GTS WELCO WHSE FAIRLESS HI

ONE STEEL RD

MORRISVILLE PA 19067

Oaamtr. >***».• t6WW

Oanwr R&rfMf ,<Mn: VW4O4

Expiration Data:

Cylinder Number.

9.23

12.00

Balance

Certified Concentration:

8/21/2012

CC129819

CARBON DIOXIDE

OXYGEN

NITROGEN

Analytical Uncertainly:

±1%

±1%

8(17/1008

NICMO9E-A8

NA

AS HO

2000JW HOcuB.

NA

NA

Certification Information: Certification Dale: 8/21/2009

7. Oonot i» um ttindant *pmwra li tnt Sun ISO P8B.

(HOXVtMl (Of R«f«moc» Only)

Term: 3-J Months Expiration Date: 8/21/2012

01

Aiiafylteal Data: (fcRoferonco Standard, ZaZsm Gas, C°Oas Candktslo)

I. Compootnt: CARBON KOXH»e

RtqusilntConcaiWaGon- 9%

CaitfMConcontfMlont

UU MullpeM Calltoctlon:

N0N4SFBI6MIWRAHED

e/13rtOO9

Zl R: 17.02

fl: 17.02 Z:

Z: C: 182

UOM:

2. Convonfnl: OxVoEN Roojwitatf ConoontraOon

CatUnedConctntrotfecr

one

C: ft« Cone: t»

C: aw Cone: 9.2J

R: 17.02 Cone: 923

II*

II*

fiCM8430XnMTSE»)fl-lll

PAMWONETK

Utl MulUpoinl CtftttOoK

rh>IAnalyal*D*lti

Zl

R! 22.88

t:

UOM:

R:

Xs

C:

23

12

Ci

C:

R:

12.02

12

22.08

DMtl

Conei

Cm«

Cons:

Mt«n Tt«l Attiy:

ta\nm

12.02

12

12

12*

Analyzed by: Robin Morgan

Rofoj«nc»StaKj«dTyp» CU3

R«I.St<J CylntfH*. CCIM4M

R*f 8U. Com njn%

flelSWTr«MlWtlo6RM#: 2741

SteenilAnalinltOtla:

Zi

R:

■UOM:

R:

2:

C:

C:

C:

Rl

Oat*:

Cone:

Cones

Cone:

titan Tot Atttp 0%

RaCartnet Standard Typ« GUS

RtlSMCyMcr*: CCtUtM

RttSMCone 7197%

Rel.B(dT««aablat»8l»4#: Kit*

SicondAnafyalsOala:

Zt Hi

Hi Is

Z: C:

UOM:

Certified by:_i.

C:

C:

R:

Oalt:

Cone:

Cone;

Cone:

MgenTaatAMey: 0%

Mm>l«ram^ Th« »«l)rtlh wnoo»(inhjlihoi*bi»iro<OIS.W»teo.ho..art«lngou»eHhiiut»o(»»
1PRAXAIR Praxair Distribution Mid-Atlantic LLC

U5 Shlmersvlllo Read firth/shorn, PA 18015 Phone: 610.317.1608 Fax: 610.758.8384

CmtomtrA Otdtr Information:

OBREIN&GERE OnfcrAtoeir; 144266000

ChtsoauP. AViihr: 119748

Certf/Ied Concentration:

PlttDau: 2MB00S

PtrtHmAu: EVNtCDOXE148AS

WA

AS 690

20OOp«l 140 MR

NM

Expiration Date:

Cylinder Number

3/9/2012

CC834C Analytical Uncertainty:

17.8B CARBON DIOXIDE

21.22 ft OXYGEN

Balance NITROGEN

±r

HOxppm- WA

CertificationIitfimutloni' CortlficatlonData: 2/W2009

2DonoliaalN*sfinSifdirpr«Mural>lMtlMnieOP8<a.

(NOXValuufeiRtranfniOftly)

r«m: 36 Months BtprfWfon Date: 2/9O012

PA<^ 01

Analytical Data: (R'Reforence Standard. Z*Zem Gas, C«Gaa Candldatg)

1. Ccmpowml: CARBCN DIOXIDE

UK

SIBkCN3UUIUkUTeESNSOMI2

Utf MuKptfit Criterion:

Pint/

Z:

HI

Z:

UOMi

tally*

ta

l(Dal

Ri

Zl

C;

a:

18.02

18

1/1872009

Cs 18

Cl 19'

R: 16.02

Ottei

Conn

Cones

Cone

Mm Tilt Atuyt

unm

17.8S

17.85

17.85

17.8SW

2. CcmpMMl: 0XV8EN

Roquwud ConoMMllen:

Coniliad Oone«nuaOoa:

klMiumontUJKf:

11H

21.M*

Lttl MifltooW CUbnSon

PMUIMGHETK

titonon

FlratAnilyitoDilai

fc

fl: 22.72

UOHi

Ri 22.7Z

Zi

C: 21

C:

C:

Ri

21

21

22.74

Oitaj

Canei

Cone:

Conn:

MnnTottAiMys

worn

21.22

21.23

21.22

21.22

Analyzed by: Melissa Santana

Rttwtno* Slanted Typa

RtLStd.C|TntH«:

IWL8M.C«nB

CMS

CCI0M77

174»-

8iwad Anilyil* DtU;

Zi

As

Z:

UOMi ft

R:

Z:

Cl

C:

C:

R:

D*l«:

Cone:

Cams

Cane;

MimTntAitiy: OK

RAnnot minted iyp« CUIS

Rtl8M.CylMM#:

Rtt 8(4. Cone 1UIX

RrtSI4Tn«c«»a»to6RM»: H68t

BuondAntlyilaOlM!

Z:

Rt

Zi

UOM:

Ri

Zi

C:

Cs

C:<

Ri

Cent!

Cong;

Cone:

MaanmiMityi 0%

j/t. tlfj.01

p0T8^^ MHtowsbrttnUutlliiWonnifeniiicajnltutNnltMMttciaiatnaMkal

iMto ht»»v«rtih»flth.ltti[tyofOT8.VVWool lno.,«rt«ln»pg)l»l
APPENDIX ENTHALPY ANALYTICAL INC. REPORT

360' Engineering and Project Delivery Solutions

□BillENEGEHE

'.obg.com
O'Brien Gere Engineers, Inc. 5000 Brittonfield Parkway

Syracuse, NY 13221

LaFarge Cement

Kiln Exhaust

Ravena, NY

Project # 45692

Analytical Report

(0310-05)

EPA Method 321

Hydrogen Chloride

Enthalpy Analytical, Inc.

Phone: (919) 850 4392 Fax: (919) 850 9012 www.enthalpy.com

2202 Ellis Road Durham, NC 27703 5518
certify that to the best of my knowledge all analytical data presented in this report:

Have been checked for completeness

Are accurate, error-free, and legible

Have been conducted in accordance with approved protocol, and that all dev ialions and analytical

problems are summarized in the appropriate narrative(s)

This analytical report was prepared in Portable Document Format (.PDF) and contains 48 pages.

QA Review Performed by Valgena Respass

EA# 0310-05 Page of 48
FTIR Summary of Results

EA# 0310-05 Page of 48
Company

Analyst Initials

Parameters

Samples

O'Brien Gere

CJT

EPA Method 321

Client

Job#

PO#

Report Date

45692-Kiln Exhaust

0310-05

Verbal

3/19/2010

Compound- Sample ID Concentration (ppmv wet)

Hydrogen Chloride

Run

22.2

Kiln Exhaust Runs

Run

20.1

Run

25.2

EA# 0310-05 Page of 48
FTIR Results

EA# 0310-05 Page of 48
Company

Analyst Initials

Parameters

Run1

Run

Run

Run

Run

Run

Run

Run

Run

Run

Run

Run

Run

Run

Run

Run

Run

Run

Run1

Run

Run

Run

Run

Run

Run

Run

Run

Run

Run

Run1

Run

Run

Run

Run

Run

Run

Run

Run

Run

Run

Run

Run

Run

Run

ft Samples

O'Brien Gere

CJT

EPA Method 321

Date

3/12/2010 10:36

3/12/2010 10:37

3/12/2010 10:38

3/12/2010 10:39

3/12/2010 10:40

3/12/2010 10:41

3/12/2010 10:42

3/12/2010 10:43

3/12/2010 10:44

3/12/2010 10:45

3/12/2010 10:46

3/12/2010 10:47

3/12/2010 10:48

3/12/2010 10:49

3/12/2010 10:50

3/12/2010 10:51

3/12/2010 10:52

3/12/2010 10:53

3/12/2010 10:54

3/12/2010 10:55

3/12/2010 10:56

3/12/2010 10:57

3/12/2010 10:58

3/12/2010 10:59

3/12/201011:00

3/12/201011:01

3/12/201011:02

3/12/201011:03

3/12/201011:04

3/12/201011:05

3/12/201011:06

3/12/201011:07

3/12/201011:08

3/12/201011:09

3/12/201011:10

3/12/201011:11

3/12/201011:12

3/12/201011:13

3/12/2010 11:14

3/12/2010 11:15

3/12/201011:16

3/12/201011:17

3/12/201011:18

3/12/201011:19

Method

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

Client

Job*

PO#

Report Date

Filename

45692-

0310-05

Verbal

Klfn Exhaust

3/19/2010

Hydrogen

Chloride

DF

10 03 12 1036 02 958

10 03 12 1037 02 893

10 03 12 1038 04 688

10_03_12_1039_04 624

10 03 12 1040 06 482

10 03 12 1041 06 418

10_03_12_1042 08_213

10_03_12 1043 08 133

10 03 12 1044 10 053

10_03_12_1045_09_973

10 03 12 1046 11 769

10 03 12 1047 11 704

10 03 12 1048 13 562

10_03_12_1049_13_49«

10_03_12_1050_15_292

10 03~12 1051~15~21J

10 03 12 1052 16 94C

10 03 12 1053 16_851

10_03_12_1054 18 646

10_03 12 1055 18 566

10_03_12 1056 20 29S

10 03 12 1057 20 234

10_03_12_1058_21_967

10 03 12 1059 21 903

10_03J2~1100 23 636

10_03 12 1101 23_556

10 03 12 1102 25 351

10 03 12 1103 25 25S

10 03 12 1104 27J76

10 03 12 1105 27 080

10 03 12 1106 28 875

10 03 12 1107 28 796

10 03 12 1108 30 528

10 03 12 1109 30 464

10 03 12 1110 32 197

10_03_12_1111 32J33

10_03_12_1112_33_865

10 03 12 1113 33 801

10_03_12 1114 35_534

10 03 12 1115 35 454

10_03_12_1116_37_437

10 03 12 1117 37 357

10~03 12 1118 39~089

10 03 12 1119 39 025

(ppm)

17.3

15.1

13.9

13.7

15.7

17.1

18.5

20.1

21.4

22.4

23.9

18.9

14.9

18.8

22.3

25.5

26.4

27.0

27.5

28.1

28.7

24.6

25.3

20.4

20.9

24.8

25.9

24.3

19.9

19.6

23.3

25.0

24.7

23.7

24.8

24.9

25.3

26.2

21.1

21.5

18.6

17.3

17.2

21.3

SEC

(ppm)

0.507

0.476

0.453

0.451

0.478

0.491

0.508

0.533

0.549

0.557

0.587

0.491

0.437

0.498

0.561

0.615

0.637

0.646

0.660

0.667

0.671

0.603

0.609

0.521

0.530

0.602

0.617

0.589

0.518

0.517

0.576

0.604

0.597

0.575

0.598

0.603

0.615

0.625

0.539

0.536

0.489

0.476

0.461

0.525

EA# 0310-05 Page of 48
Company

Analyst Initials

Parameters

Run1

Run

Run

Run

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Run

Run

Run

Run

Run

Run

Run

Samples

O'Brien Gere

CJT

EPA Method 321

Date

3/12/201011:20

3/12/201011:21

3/12/201011:22

3/12/201011:23

3/12/2010 11:24

3/12/201011:25

3/12/201011:26

3/12/201011:27

3/12/2010 11:28

3/12/201011:29

3/12/201011:30

3/12/201011:31

3/12/201011:32

3/12/201011:33

3/12/201011:34

3/12/201011:35

Method

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05

0310-05

0310-05

0310-05

0310-05A

0310-05A

10

Client #4

Job#0

PO#V

Report Date 3i

Filename

03 12 1120 40 945

10 03 12 1121 41 600

10 03 12 1122 41 505

10 03 12 1123 43 300

10

10

93 12 1124 43 220

03 12 1125 44 953

10 03 12 1126 44 889

10

10

10

10_

10

10

10

10

10

03 12 1127 44 824

D3 12 1128_46_620

03 12 1129 46_556

33 12 1130 48 413

33_12_1131 48 333

33 12 1132 50 191

D3 12 1133 50 127

33 12 1134 51 922

33 12 1135 51 858

5692-Kiln Exhaust

31045

erba

'19/2010

DF

Hydrogen

Chloride

(ppm)

20.4

22.9

22.5

24.4

25.6

24.4

21.7

24.1

22.5

25.0

25.0

25.7

25.7

22.7

20.4

23.2

SEC

{ppm)

0.507

0.547

0.541

0.566

0.579

0.558

0.511

0.550

0.524

0.563

0.570

0.577

0.573

0.520

0.489

0.543

Average Cone, (ppm): 22.2 0.552

EA# 0310-05 Page of 48
Company

Analyst Initials

Parameters

Run

Run

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Run

Run

Run

Run

Run

Run

Run

Run

Run

Run

Run

Run

Run

Run

Run

Run

Run

Run

Run

Run

Run

Run

Run

Run

Run

Run

Run

Run

Run

Run

Run

Run

Run

Run

Run

Run

Samples

O'Brien Gere

CJT

EPA Method 321

Date

3/12/2010 12:01

3/12/2010 12:02

3/12/2010 12:03

3/12/2010 12:04

3/12/2010 12:05

3/12/2010 12:06

3/12/2010 12:07

3/12/2010 12:08

3/12/2010 12:09

3/12/2010 12:10

3/12/2010 12:11

3/12/2010 12:12

3/12/201012:13

3/12/201012:14

3/12/2010 12:15

3/12/2010 12:16

3/12/2010 12:17

3/12/2010 12:18

3/12/2010 12:19

3/12/2010 12:20

3/12/201012:21

3/12/2010 1222

3/12/2010 1223

3/12/2010 12:24

3/12/2010 1225

3/12/2010 1226

3/12/2010 1227

3/12/2010 12:28

3/12/2010 12:29

3/12/2010 12:30

3/12/2010 12:31

3/12/2010 12:32

3/12/2010 12:33

3/12/2010 12:34

3/12/2010 12:35

3/12/2010 12:36

3/12/2010 12:37

3/12/2010 12:38

3/12/201012:39

3/12/2010 12:40

3/12/2010 12:41

3/12/2010 12:42

3/12/2010 12:43

3/12/2010 12:44

Method

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05

0310-05A

0310-05A

0310-05A

0310-05

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05

0310-05

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05

0310-05A

0310-05A

0310-05A

0310-05A

0310-05

0310-05A

0310-05A

0310-05A

0310-05A

Client

Job#

PO#

Report Date

45692 Kiln Exhaust

0310-05

Verbal

3/19/2010

Filename DF

10_03 12 1201 02 443

10 03 12 1202 02 347

10 03 12_1203_04 205

10 03 12 1204 04 110

10 03 12 1205 05 780

10 03 12 1206 05 716

10 03 12 1207 07 511

10 03 12 1208 07 432

10_03_12_1209_09_164

10 03_12_1210_09 085

10_03_12_1211 10_880

10_03 12 1212 10 816

10 03 12 1213 12 486

10 03 12 1214 12 422

10 03 12 1215 14 217

10_03_12 1216 14 137

10 03 12 1217_16_058

10 03 12 1218_15_962

10 03 12 1219 17 726

10 03 12 1220 17 678

10 03 12 1221 19 411

10_03_12_1222_19_347

10 03 12_1223 21 079

10 03 12 1224 21 015

10 03 12 1225 22 748

10 03 12 1226 22_684

10 03 12 1227 24 417

10 03 12 1228 24 337

10_03_12_1229_26_132

10_03_12_1230_26_037

10 03 12 1231 25 973

10 03 12 1232 27_768

10 03 12 1233 27 704

10 03 12 1234 29 375

10 03 12 1235 29 310

10 03 12 1236 31 106

10_03_12_1237_31_026

10 03 12 1238 32 728

10 03 12 1239 32 664

10_03_12_1240_32_600

10 03 12 1241 34 457

10 03 12 1242 34 378

10 03 12 1243 36 235

10 03 12 1244 36 156

Hydrogen

Chloride

(ppm)

23.7

23.8

25.5

27.4

28.2

25.0

24.0

22.0

22.6

22.9

23.1

21.4

20.5

22.0

19.1

16.2

15.2

15.4

14.2

13.2

13.2

14.3

14.7

14.9

13.8

12.8

11.4

12.0

11.6

12.9

14.7

14.8

17.2

19.3

21.2

21.6

16.9

19.1

17.5

18.9

18.3

19.2

22.2

24.1

SEC

(ppm)

0.546

0.550

0.575

0.608

0.628

0.570

0.552

0.521

0.537

0.545

0.541

0.518

0.504

0.533

0.490

0.455

0.436

0.442

0.422

0.407

0.406

0.405

0.402

0.414

0.410

0.405

0.395

0.398

0.398

0.408

0.420

0.417

0.442

0.471

0.502

0.507

0.435

0.470

0.446

0.464

0.458

0.469

0.520

0.540

EA# 0310-05 Page of 48
Company

Analyst Initials

Parameters

Samples

Run

Run

Run

Run

Run

Run

Run

Run

Run

Run

Run

Run

Run

Run

Run

Run

O'Brien Gere

CJT

EPA Method 321

Date

3/12/2010 12:45

3/12/2010 12:46

3/12/201012:47

3/12/2010 12:48

3/12/2010 12:49

3/12/2010 12:50

3/12/2010 12:51

3/12/201O 12:52

3/12/2010 12:53

3/12/2010 12:54

3/12/2010 12:55

3/12/2010 12:56

3/12/2010 12:57

3/12/2010 12:58

3/12/201012:59

3/12/2010 13:00

Method

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

Client

Job#

PO#

Report Dale

Filename

45692 Kiln Exhaust

0310-05

Verba

3/19/2010

DF

10_03 12_1245_38_014

10 03 12 1246 37 950

10_03_12 1247 39 745

10.03 12 1248 39 665

10 03 12 1249 41 586

10 03 12 1250 41 490

10 03 12 1251 43 286

10 03 12 1252 43 206

10 03 12 1253 44 939

10 03 12 1254 44 875

10 03_12_1255_46_607

10 03 12 1256 46 528

10 03 12 1257 48 292

10_03_12_1258 48 243

10_03 12 1259 49 976

10 )3 12 1300 49 912

Hydrogen

Chloride

(ppm)

24.7

22.0

25.7

25.4

23.7

25.6

25.0

25.1

22.6

18.0

19.0

23.0

24.0

23.9

27.0

27.0

SEC

(ppm)

0.557

0.513

0.576

0.567

0.539

0.562

0.557

0.553

0.521

0.461

0.476

0.537

0.546

0.553

0.610

0.607

Average Cone, (ppm): 20.1 0495

EA# 0310-05 Page of 48
Company

Analyst Initials

Parameters

Samples

Run

Run

Run

Run

Run

Run

Run

Run

Run

Run

Run

Run

Run

Run

Run

Run

Run

Run

Run

Run

Run

Run

Run

Run

Run

Run

Run

Run

Run

Run

Run

Run

Run

Run

Run

Run

Run

Run

Run

Run

Run

Run

Run

Run

O'Brien Qere

CJT

EPA Method 321

Date

3/12/2010 14:03

3/12/2010 14:04

3/12/2010 14:05

3/12/201014:06

3/12/2010 14:07

3/12/2010 14:08

3/12/2010 14:09

3/12/2010 14:10

3/12/201014:11

3/12/2010 14:12

3/12/2010 14:13

3/12/2010 14:14

3/12/201014:15

3/12/2010 14:16

3/12/2010 14:17

3/12/2010 14:18

3/12/201014:19

3/12/2010 14:20

3/12/2010 14:21

3/12/2010 14:22

3/12/201014:23

3/12/2010 14:24

3/12/2010 14:25

3/12/2010 14:26

3/12/201014:27

3/12/2010 14:28

3/12/2010 14:29

3/12/2010 14:30

3/12/2010 14:31

3/12/2010 14:32

3/12/2010 14:33

3/12/2010 14:34

3/12/2010 14:35

3/12/201014:36

3/12/2010 14:37

3/12/2010 14:38

3/12/2010 14:39

3/12/2010 14:40

3/12/2010 14:41

3/12/2010 14:42

3/12/2010 14:43

3/12/2010 14:44

3/12/2010 14:45

3/12/2010 14:46

Method

0310-05A

0310-05A

0310-05A

0310-05

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05

0310-05A

0310-05A

0310-05A

0310-05

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05

0310-05

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

O31CM35A

0310-05A

0310-05A

Clienltf

Job*

PO#

Report Date

Filename

10 03 12

45692 Kiln Exhaust

0310-05

Verba

3/19/2010

DF

1403 01_945

10_03_12_1404_01_88

10 03 12 1405 03 739

10_03 12 1406_03_69

10 03 12 1407 05 486

10 03 12 1408 05 422

10 03 12 1409 07 280

10 03 12

10 03 12

1410 07 216

1411 09 012

10 03 12 1412 08 963

10J)3 12

10 03 12

10 03 12

10_03_12.

10_03 12

10_03_12_

10 03 12

_1413_10_82'

1414_10_757

"1415 12~553 _1416_12_489

1417 12_393

1418 14 158

1419 14 094

10 03~12^1420 15 826

10 03 12

10_03_12.

1421 15 747

"1422~17 542

10 03_12_1423_17 478

10_03_12~

10 03 12

10J)3_12_

10 03 12

10 03 12.

10 03 12

10 03 12

10 03 12

10 03 12

1424 19 336

1425 19_272

1426 21 067

_1427_20_988

.1428 22 689

1429_22_625

.1430_24_421

"i431~24~32e

_1432_26_027

10 03_12_1433_25_96Z

10 03 12 1434 27 946

10 03_12.

10 03 12

10 03 12

10_03_12_

10_03_12

10 03 12

10 03 12

J435_27 851

1436 27 787

1437 29 582

1438 29 502

1439 31 23£

1440 31J71

1441_31J)7€

10_03 12 1442_32_902

10 03 12

10 03_12_

1443 32 836

1444 34_697

10 03 12 1445_34_617

10 03 12 1446 36 47£

Hydrogen

Chloride

(ppm)

25.7

27.2

25.1

28.6

27.8

27.9

27.6

26.4

26.7

26.0

24.3

24.0

25.5

25.0

23.8

22.9

23.6

23.5

22.2

21.4

22.1

23.1

24.1

25.6

28.3

28.4

28.2

26.6

26.0

25.4

25.0

26.8

27.0

25.5

25.9

32.1

36.4

31.0

24.9

19.4

17.1

22.3

25.6

28.9

SEC

(ppm)

0.711

0.739

0.693

0.721

0.744

0.730

0.716

0.683

0.680

0.665

0.627

0.623

0.645

0.629

0.597

0.573

0.578

0.568

0.544

0.527

0.542

0.559

0.577

0.608

0.663

0.663

0.662

0.624

0.613

0.600

0.582

0.616

0.615

0.589

0.597

0.704

0.772

0.690

0.587

0.504

0.476

0.562

0.622

0.682

EA# 0310-05 Page 10 of 48
Company

Analyst Initials

Parameters

Samples

O'Brien Gere

CJT

EPA Melhod 321

Client

Job*

PO#

Report Date

45892-Kiln Exhaust

0310-05

Verbal

3/19/2010

Run

Run

Run

Run

Run

Run

Run

Run

Run

Run

Run

Run

Run

Run

Run

Run

Run

Date

3/12/201014:47

3/12/2010 14:48

3/12/2010 14:49

3/12/2010 14:50

3/12/201014:51

3/12/2010 14:52

3/12/201014:53

3/12/2010 14:54

3/12/2010 14:55

3/12/2010 14:56

3/12/2010 14:57

3/12/2010 14:58

3/12/2010 14:59

3/12/2010 15:00

3/12/2010 15:01

3/12/2010 15:02

3/12/2010 15:03

Method

0310-05A

0310-05A

0310-05A

0310-05

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

O31O-O5A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

Filename

10J)3 12 1447 36 411

10 03 12 1448 38 206

10 03 12 1449 38 126

10_03 12 1450 40 015

10 03 12 1451 39 951

10 03 12 1452 41 747

10_03_12_1453_41 652

10 03 12 1454 43~541

10_03 12 1455 43 477

10_03 12 1456 45 272

10 03 12 1457 45 208

10_03_12_1458_47 066

10_03_12_1459 47 018

10 03 12 1500 48 813

10_03 12 1501 48 765

10 03 12 1502 50 623

10 03 12 1503 53 762

OF

Hydrogen

Chloride

(PPm)

32.1

33.2

27.4

25.7

22.9

27.2

29.0

28.6

27.2

25.7

22.5

17.4

18.8

22.2

19.4

15.7

13.2

SEC

(ppm)

0.743

0.768

0.661

0.633

0.560

0.661

0.699

0.698

0.673

0.634

0572

0.496

0.519

0.566

0.515

0.468

0.440

Average Cone, (ppm): 25.2 0.623

EA# 0310-05 Page 11 of 48
FTIR Narrative Summary

EA# 0310-05 Page 12 of 48
Enthalpy Analytical Narrative Summary

Introduction

Clint Thrasher of Enthalpy Analytical, Inc. and O'Brien Gere staff performed Fourier

Transform Infrared (FTIR) spectroscopy testing on March 12, 2010 at the LaFarge Cement

plant in Ravena, New York. The source (the Kiln Exhaust) was tested by FTIR spectroscopy

tested for Hydrogen Chloride (HC1).

O'Brien Gere of Syracuse, New York retained Enthalpy Analytical, Inc. of Durham, North

Carolina to operate the FTIR instrument and analyze the data. Testing was based on the

procedures outlined in EPA Method 321 Measurement of Gaseous Hydrogen Chloride

Emissions at Portland Cement Kilns by Fourier Transform Infrared (FTIR) Spectroscopy.

Sampling Notes

Three one-hour runs were performed at the Kiln Exhaust.

Results

All data from the runs are listed in the Results section of this report. HC1 was detected above

its minimum detectable concentration (MDC) value in all sample spectra during all runs.

FTIR Extractive Sampling System

Sample gas was extracted through a probe assembly and heat-traced line, through sample gas

dryer, and into the absorption cell of the FTIR spectrometer. The heat-traced line was

maintained at approximately 375° F. pump connected to the FTIR cell outlet drew sample-gas

through the cell at flow rate of approximately liters per minute. The absorption cell was

maintained at 181° to prevent condensation in the cell and minimize analyte adhesion to the

walls and mirrors of the cell. The absorption cell path length was determined using certified

cylinder of ethylene sent directly to the FTIR. Results of the path length calculations are

presented in the "FTIR QA" Section of this report.

FTIR Instrument

The FTIR instrument used for this test was MIDAC (Series 1-1301) medium-resolution

Michelson interferometer spectrometer, designated as "Instrument L". The interferometer and

detector were assembled by MIDAC Corporation (Costa Mesa, California). The nominal

spectral resolution of the system was one half wavenumber (0.5 cm*'). The instrument was

equipped with nominal 10-meter path length White cell, potassium bromide (KBr)

beamsplitter, zinc selenide (ZnSe) non-hygroscopic windows, and mercury cadmium telluride

(MCT) liquid nitrogen-cooled detector. The inside walls of the cell were polished stainless steel

to minimize interaction of the sample with the cell walls, and the cell mirrors were ofbare gold.

The gas pressure in the FTIR sample cell was monitored with pressure transducer connected

directly to the sample cell. The heated sample cell was wrapped in an insulating blanket and the

temperatures were controlled with type thermocouples. All connections for the entire sampling

EA# 0310-05 Page 13 of 48
Enthalpy Analytical Narrative Summary (continued)

system were wrapped with electric heat tape and insulated to eliminate "cold spots." All

components were constructed of Type 316 stainless steel, SilcoSteel coated stainless steel, or

Teflon. The absorption cell volume is approximately 1.9 liters for Instrument L.

The FTIR system was operated via portable computer, data archive storage system (USB

Mass Storage Drive, 80 GB) was used for data backup. All inlerferograms, single beams,

absorbance spectra, and background single beams are stored and archived at Enthalpy

Analytical,

Inc.

Temp. Pres.

Controller

Gas Sample Collection

Nitrogen (N2) served as the background gas. For each day, sample gas was continuously purged

through the sampling systems and absorption cells. Spectra consisting of 50 co-added scans

were recorded approximately once every minute on the instrument. Before, during, and after

testing, certified calibration transfer standard (CTS) gas of ethylene was introduced to the

FTIR spectrometer and allowed to reach steady state. The absorption path length results fiom

these measurements are included in the "FTIR QA" section of this report.

Data Collection

All spectra were recorded at nominal resolution of 0.S cm'1. The absorption cell was

ENTHALPY ana iv tic 1. inc.

EA# 0310-05 Page 14 of 48
Enthalpy Analytical Narrative Summary (continued)

configured to allow many passes of the infrared beam to traverse the cell between the entrance

and exit windows. This provided for path length of approximately 8.8 meters. Sample spectra

were divided point-by-point by al28-scan background recorded using nitrogen. The single beam

spectrum was constantly monitored and new background was generated when residual and

absorbance spectra indicated component build-up on the optical surfaces or alignment-related

baseline shifts.

Spectral Analyses

Enthalpy staff used the program AutoquantProTM (hereafter "AQ," version 4.0.0.136, ©Midac

Corporation, 2007) to collect and analyze all the infrared field data. The program allows the

development and storage of analytical "methods" for analysis of spectral data (absorbance) files;

we developed one "method" for the task of determining the absorption path length and

separate "method" for determining the concentrations of the target compound. All the

information required to reproduce these analytical techniques is contained in the "Method Map"

section of this report.

The concentration uncertainty reported by AutoquantPro is called the Standard Error of the

Estimated Concentration, or SEC; it is also known as the Marginal Standard Deviation. The

uncertainties in the concentration are proportional to the square root of the sums of the

squares of the residual. After the residual spectrum is obtained, which we will call R. the error

variance for the case of single reference spectrum is calculated as:

_2

where is the number of observations. The SEC is given by:

SEC= °C

where is the spectrum and is the known concentration of the reference.

The 95% confidence interval is 1.96 times the SEC.

Spectra

The reference spectra used for these analyses were developed by Enthalpy Analytical, Inc., by

EPA, by MIDAC Corporation, and by the Department of Energy Pacific Northwest National

Laboratory (DOE/PNNL). All spectra used in the analysis and the corresponding analytical

regions are documented in the "Method Map" section of this report. For all data analysis, the

ENTHALPY analytical, inc.

EA# 0310-05 Page 15 of 48
Enthalpy Analytical Narrative Summary (continued)

apodization was triangular and the baseline correction was linear. All spectra were analyzed

using temperature and pressure corrections.

Quality Assurance

Calibration Transfer Standards and Absorption Path Lengths

Before the first and after the last test run, calibration transfer standard (CTS) gas (Custom Gas

XC024236B, 100 ppm ethylene, balance N2) was introduced to the FTIR system to determine its

effective absorption path length. This determination was based on comparisons of the "field"

CTS spectra to laboratory CTS spectrum recorded by MIDAC. Over the test period, all

calculated absorption path lengths determined for the instrument varied by less than 3% of the

mean path length, which was used in the final data analysis.

Matrix Spikes

Matrix spikes were successfully performed prior to and following each test run. The spike

gas standard was certified mixture of HC1 and SF6 (Spectra Gases CC-303666, 59.8 ppm

HC1, 3.01 ppm SF6, balance N2). The HC1 spike recoveries (see the "FTIR QA Spiking"

section) were within the limits allowed by EPA Method 321, which specifies that the spike

dilution factor (DF) should be less than 10%. However, due to variations in the native HC1

concentration, it was necessary to spike at higher DF (approximately 15%) in order to

overcome these variations. Also, spikes were performed while sampling ambient air before

the first and after the last sample spike; these "ambient spikes" demonstrated effective

delivery of HC1 through the sampling system in the absence of variable native concentrations.

Minimum Detectable Concentration (MDC)

EPA Method 320 and the equivalent ASTM Standard D6348-03 specify number of

analytical uncertainty parameters that the analyst may calculate to characterize the FTIR

system performance. The reported MOCs were calculated according to Section A2.2 of

ASTM Standard D6348-03.

Spectral Interferences

Enthalpy staff performed careful visual examinations of the sample spectra and the "residual"

spectra generated by spectrally subtracting known compounds from the sample spectra. The

goals of these examinations are 1) to confirm the accuracy of the reported analyte

concentrations and 2) to detect any additional compounds that might have been present in the

sample streams.

Data Storage

dedicated desktop computer controlled the FTIR spectrometer; the hard drive of the computer

served as the primary data storage media. During testing, Enthalpy staff created and maintained

backup and archive copies of the spectral data (interferograms, single beam spectra, and

ENTHALPY analytical, me.

EA# 0310-05 Page 16 of 48
Enthalpy Analytical Narrative Summary (continued)

absorbance spectra) on USB memory devices.

Data Reviews

Enthalpy subjects all the spectroscopic data and analytical results to three levels of review.

First, the field instrument operator inspects the instruments' outputs to ensure their

appropriate performance during the sampling runs. Second, another analyst who did not

perform the analyses examines the sample spectra and the quantitative analytical results, and

also spot-checks the analysis results by manually; these examinations include visual

comparisons of the sample and reference spectra such as those illustrated in the "Selected

Spectra" section. Finally, an independent reviewer checks the final report for consistency.

ENTHALPY ana lytical.inc.

EA# 0310-05 Page 17 of 48
FTIR QA

EA# 0310-05 Page 18 of 48
Company

Analyst Initials

Parameters

Samples

O'Brien Gere

CJT

EPA Method 321

Clients

Job*

PO#

Report Date

45692-Kiln Exhaust

0310-05

Verbal

3/19/2010

Path Length path

Date

3/10/2010 9:42

3/10/2010 9:42

3/10/2010 9:42

3/10/2010 9:42

3/10/20109:43

3/10/2010 9:43

3/10/2010 9:43

3/10/2010 9:43

3/10/2010 17:11

3/10/2010 17:12

3/10/2010 17:12

3/10/2010 17:12

3/10/2010 17:12

3/10/2010 17:13

3/10/201017:13

3/10/2010 17:13

3/11/20106:48

3/11/20106:46

3/11/2010 6:49

3/11/2010 6:49

3/11/2010 6:49

3/11/20106:50

3/11/20106:50

3/11/2010 6:50

3/11/201014:37

3/11/201014:37

3/11/201014:37

3/11/201014:38

3/11/201014:36

3/11/201014:38

3/11/201014:39

3/11/201014:39

Method

0310-05CTS

0310-05CTS

0310-05CTS

0310-05CTS

0310-05CTS

0310-05CTS

0310-05CTS

0310-05CTS

0310-05CTS

0310-05CTS

0310-05CTS

0310-05CTS

0310-05CTS

0310-05CTS

0310-05CTS

0310-05CTS

0310-05CTS

0310-05CTS

0310-05CTS

0310-05CTS

0310-05CTS

0310-05CTS

0310-05CTS

0310-05CTS

0310-05CTS

0310-05CTS

0310-05CTS

0310-05CTS

0310-05CTS

0310-05CTS

0310-05CTS

0310-05CTS

FlleName

10 03 10 0942 01 593

10_03 10 0942 18 061

10 03 10 0942 34 514

10 03 10 0942 50 998

10 03 10 0943 07 450

10_03_10_0943 23 934

10 03 10 0943 40 403

10_03_10_0943_56_855

Average (m)

10_03_10_1711_44_477

10 03 10 1712 01_836

10 03 10 1712 19 148

10 03 10 1712 36 460

10 03 10 1712 53 725

10 03_10_1713_11_037

10 03 10 1713 28 364

10_03_10_1713_45_739

Average (m)

10 03 11 0648 40 829

10 03 11 0648 58 079

10_03_11J)649 15_328

10 03 11 0649 32_562

10_03_11_0649_49_811

10_03_11_0650_07_077

10~03 11~0650~24~326 10_03_11_0650_41_576

Average (m)

10_03_11_1437 19_953

10~03T1i"i437 37 187

10 03 11 1437 54 499

10 03 11 1438 11 858

10 03 11 1438 29 154

10 03 11 1438 46 388

10 03 11 1439 03 700

10 03 11 1439 20 997

ethylene (ppm)

8.72

8.71

8.70

8.70

8.70

8.71

8.70

8.71

8.70

8.86

8.86

8.85

8.87

8.86

8.86

8.87

8.87

8.86

8.95

8.94

8.95

8.94

8.95

8.95

8.95

8.95

8.9S

8.52

8.54

8.55

8.56

8.55

8.56

8.56

8.57

SEC (p|

0.136

0.136

0.136

0.136

0.136

0.138

0.136

0.136

0.136

0.128

0.129

0.128

0.128

0.128

0.129

0.128

0.128

0.128

0.130

0.130

0.131

0.131

0.131

0.131

0.131

0.131

0.131

0.126

0.127

0.127

0.127

6.127

0.126

0.127

0.127

EA# 0310-05 Page 19 of 48
Company

Analyst Initials

Parameters

Samples

O'Brien Gere

CJT

EPA Method 321

Client

Job#

PO#

Report Date

45692 Kiln Exhaust

0310-05

Verbal

3/19/2010

Path Length path

Date

3/12/2010 7:55

3/12/2010 7:56

3/12/2010 7:56

3/12/2010 7:56

3/12/2010 7:57

3/12/2010 7:57

3/12/2010 7:57

3/12/2010 7:57

3/12/2010 16:49

3/12/2010 16:49

3/12/201016:49

3/12/2010 16:50

3/12/2010 16:50

3/12/2010 16:50

3/12/2010 16:51

3/12/2010 16:51

Method

0310-05CTS

0310-05CTS

0310-05CTS

0310-05CTS

0310-05CTS

0310-05CTS

0310-05CTS

0310-05CTS

0310-05CTS

0310-05CTS

0310-05CTS

0310-05CTS

0310-05CTS

0310-05CTS

0310-05CTS

0310-05CTS

FlleName

Average (m)

10_03 12 0755 56 627

10 03 12 0756 13 095

10 03 12 0756 29 626

10 03 12 0756 46 141

10 03_12_0757 02 641

10 03 12 0757 19 125

10 03 12 0757 35 625

10_03_12_0757_52_187

Average (m)

10 03 12 1649 24 855

10 03 12 1649 42 198

10 03 12 1649 59 416

10_03_12_1650_16_540

10_03_12_1650_33_681

10_03J2J650 50 914

10 03 12 1651 08 133

10_03_12_1651_25_257

Average (m)

Average Pathlength (m)

Max (m)

Mln (m)

Max Deviation

ethylene (ppm)

8.55

8.63

8.66

8.66

8.66

8.65

8.65

8.66

8.67

8.65

8.90

8.87

8.88

8.68

8.89

8.88

8.89

8.86

8.88

8.77

8.95

8.55

2.45%

SEC (ppm)

0.127

0.124

0.125

0.124

0.124

0.124

0.124

0.124

0.125

0.124

0.123

0.122

0.123

0.123

0.123

0.123

0.123

0.123

0.123

0.128

EA* 0310-05 Page 20 of 48
Company

Analyst Initials

Parameters

Samples

O'Brien Gere

CJT

EP/

Mfnimum

Date

3/12/2010 7:55

3/12/2010 7:56

3/12/2010 7:58

3/12/2010 7:56

3/12/2010 7:57

3/12/2010 7:57

3/12/2010 7:57

3/12/2010 7:57

Method 321

Client

Job#

PO#

Report Date

45692 Kiln Exhaust

0310-05

Verbal

3/19/2010

Detectable Concentration Default

Method

0310-05

0310-05A

0310-05A

0310-05

0310-05A

0310-05A

0310-05A

0310-05A

Filename

10_03_12_0755_56_627

10_03_12_0756 13 095

10 03 12 0756 29 626

10_03_12_0756 46 141

10 03 12 0757 02 641

10 03 12 0757 19 125

10 03 12 0757 35 625

10_03_12_0757_52_187

MDC(ppm):

DF HCI(ppm)

0.118

-0.0490

-0.00900

0.0310

-0.0550

0.0230

0.0460

-0.0510

0.0801

0.180

SEC (ppm)

0.0660

0.0690

0.0690

0.0860

0.0670

0.0670

0.0680

0.0640

EA# 0310-05 Page 21 of 48
FTIR QA Spiking

EA# 0310-05 Page 22 of 48
Company

Analyst Initials

Parameters

Samples

O'Brien Gere

CJT

EPA Method 321

Client

Jobtf

PO#

Report Date

45692-Kiln Exhaust

0310-05

Verbal

3/19/2010

Kiln Exhaust Spike

Sm -Spiked Data

Date

3/12/2010 10:20

3/12/2010 10:21

3/12/2010 10:21

3/12/201010:22

3/12/2010 10:23

3/12/2010 10:23

3/12/2010 10:24

3/12/2010 10:24

Method

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

Su •• Native Cone. Of analyte

Date

3/12/2010 10:13

3/12/2010 10:14

3/12/2010 10:15

3/12/2010 10:15

3/12/2010 10:16

3/12/2010 10:16

3/12/2010 10:17

3/12/2010 10:17

Sm

Su

DF

CS

Ce

Recovery (%)[

Method

0310-05A

O310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

Recovery (%)

Ce

34.3

29.2

15.3%

63.2

2.75

34.4

FileName

10 03 12 1020 45 156

10_03_12_1021_19_530

10_03 12 1021 53 826

10 03 12 1022 28 059

10 03 12 1023 02 370

10 03 12 1023 36 729

10_03 12 1024 11 009

10_03_12_1024_45_243

Avg. Cone, (ppm)

FileName

10 03 12 1013 53 637

10_03 12 1014 27 933

10_03 12 1015 02 275

10 03 12 1015 36 555

10 03 12 1016 10 898

10_03_12_1016_45 178

10 03 12 1017 19 521

10 03 12 1017 53 770

Avg. Cone. (ppm)|

Sm Su(1-DF)

DFxCs

DF Cs Su(1-DF)

ppm

ppm

ppm

ppm

ppm

98.8%|70-130%

HCi (ppm)

33.8

34.3

34.6

34.8

34.9

33.9

34.0

34.3

34.3

HCI (ppm)

28.2

28.8

29.5

29.3

29.3

30.0

29.3

29.3

29.2

SEC (ppm

0.902

0.911

0.909

0.911

0.905

0.882

0.881

0.883

SEC (ppm]

0.825

0.820

0.845

0.842

0.835

0.858

0.828

0.847

SF6 (ppm)

0.445

0.444

0.445

0.443

0.446

0.444

0.444

0.443

0.444 TM|

SF6 (ppm)

0.0210

0.0220

0.0220

0.0210

0.0200

0.0220

0.0230

0.0220

0.0216

Mean concentration of spiked analyte

Native concentration of analyte

Dilution Factor (Target

Cylinder of spiked gas

10%)

Cylinder of tracer gas (SF6)

Expected concentration )f analyte

SEC (ppm)

0.0370

0.0370

0.0360

0.0360

0.0370

0.0360

0.0360

0.0360

SEC (ppm)

0.0430

0.0430

0.0430

0.0420

0.0420

0.0430

0.0430

0.0430

EA# 0310-05 Page 23 of 48
Company

Analyst Initials

Parameters

Samples

O'Brien Gere

CJT

EPA Method 321

Client

Job#

Report Date

45692 Kiln Exhaust

0310-05

PO# Verbal

3/19/2010

Kiln Exhaust Spike

Direct Spike Cylinder- Using Cylinder

Date

3/10/201010:00

3/10/2010 10:01

3/10/2010 10:02

3/10/201010:02

3/10/2010 10:03

3/10/2010 10:03

3/10/2010 10:04

3/10/2010 10:04

Method

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

FileName

10_03 10 1000 55 716

10_03 10 1001 29 871

10_03_10_1002_03 949

10 03 10 1002 38 088

10_03_10J003 12 244

10_03 10 1003 46 383

10 03 10 1004 20 445

10_03_10_1004_54_584

Avg. Cone. (ppm)|

HCI (ppm)

62.7

62.8

63.0

63.1

63.2

63.6

63.7

63.6

63.2

SEC (ppm)

0.835

0.856

0.873

0.886

0.882

0.886

0.878

0.891

.1

SF6 (ppm)

2.76

2.75

2.75

2.75

2.75

2.75

2.76

2.76

2.75

SEC (ppm)

0.00300

0.00300

0.00300

0.00300

0.00300

0.00300

0.00300

0.00300

EA# 0310-05 Page 24 of 48
Company

Analyst Initials

Parameters

Samples

O'Brien Gere

CJT

EPA Method 321

Client 45692 Kiln Exhaust

Job #0310-05

PO# Verbal

Report Date 3/19/2010

Kiln Exhaust Spike

Sm -Spiked Data

Date

3/12/201011:47

3/12/201011:48

3/12/201011:49

3/12/2010 11:49

3/12/2010 11:50

3/12/201011:50

3/12/201011:51

3/12/2010 11:51

3/12/201011:52

Method

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

Su Native Cone. Of analyte

Date

3/12/2010 11:37

3/12/201011:37

3/12/201011:38

3/12/2010 11:38

3/12/2010 11:39

3/12/201011:39

3/12/201011:40

3/12/201011:41

Sm

Su

DF

CS

Ce

Recovery (%)[

Method

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

Recovery (%)

Ce

31.3

25.5

15.7%

63.2

2.75

31.4

99.4%|

FlleName

10 03 12 1147 52 901

10~03~12~1148 27~150 10_03_12 1149 01 446

10 03 12 1149 35 680

10 03 12J150_10_038

10 03 12 1150_44 381

10_03_12_1151_18_681

10 03 12 1151 52 895

10_03_12_1152_27J206

Avg. Cone, (ppm)

FlleName

10 03 12 1137 01 403

10_03_12 1137 35 715

10 03 12 1138 10 026

10 03 12 1138_44_275

10 03 12 1139 18 571

10 03 12 1139 52 805

10 03 12_1140_27_101

10_03_12_1141_01_334

Avg. Cone, (ppm)

Sm Su(1-DF)

DFxCs

DFxCs Su(1-DF)

ppm

ppm

ppm

ppm

ppm

|70 -130%

HCI (ppm)

28.8

30.4

31.5

32.0

32.1

30.6

31.2

32.7

32.6

31.3

HCI (ppm)

24.3

25.4

25.6

25.8

26.0

25.5

25.7

25.4

25.5

SEC (ppm)

0.603

0.647

0.649

0.664

0.855

0.835

0.642

0.669

0.668

SEC (ppm)

0.543

0.562

0.566

0.570

0.577

0.565

0.561

0.552

SF6 (ppm)

0.444

0.447

0.445

0.446

0.446

0.447

0.445

0.448

0.444

0.446

SF6 (ppm)

0.0110

0.0130

0.0100

0.0120

0.0120

0.0150

0.0140

0.0160

0.0129

Mean concentration of spiked analyte

Native concentration of analyte

Dilution Factor (Target <'

Cylinder of spiked gas

10%)

Cylinder of tracer gas (SF6)

Expected concentration of analyte

SEC (ppm)

0.0350

0.0340

0.0350

0.0350

0.0350

0.0350

0.0340

0.0350

0.0340

SEC (ppm)

0.0380

0.0390

0.0380

0.0390

0.0390

0.0400

0.0400

0.0400

EA# 0310-05 Page 25 of 48
Company

Analyst Initials

Parameters

Samples

O'Brien Gere

CJT

EPA Method 321

Clients

Job#

PO#

Report Date

45692 Kiln Exhaust

0310-05

Verbal

3/19/2010

Kiln Exhaust Spike

Direct Spike Cylinder- Using Cylinder

Date

3/10/201010:00

3/10/201010:01

3/10/2010 10:02

3/10/2010 10:02

3/10/2010 10:03

3/10/201010:03

3/10/2010 10:04

3/10/2010 10:04

Method

0310-05A

0310-05A

0310-05A

0310-05A

O310-O5A

0310-05A

0310-05A

0310-05A

FlleName

10 03 10 1000 55 716

10 03 10 1001 29 871

10 03 10 1002 03 949

10 03 10 1002 36 088

10 03 10 1003 12 244

10 03 10 1003 46 383

10 03 10 1004 20 445

10_03_10_1004_54_584

Avg. Cone. (ppm)|

HCI (ppm)

62.7

62.8

63.0

63.1

63.2

63.6

63.7

63.6

63.2

SEC (ppm)

0.835

0.856

0.873

0.886

0.882

0.886

0.878

0.891

SF6 (ppm)

2.76

2.75

2.75

2.75

2.75

2.75

2.76

2.76

2.75

SEC (ppm)

0.00300

0.00300

0.00300

0.00300

0.00300

0.00300

0.00300

0.00300

EA# 0310-05 Page 26 Of 48
Company

Analyst Initials

Parameters

Samples

O'Brien Gere

CJT

EPA Method 321

Client

Job#

P0#

Report Date

45692 Kiln Exhaust

0310-05

Verbal

3/19/2010

Kiln Exhaust Spike

Sm -Spiked Data

Date

3/12/2010 13:52

3/12/2010 13:52

3/12/2010 13:53

3/12/2010 13:54

3/12/2010 13:54

3/12/201013:55

3/12/2010 13:55

3/12/2010 13:56

Method

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

Su Native Cone. Of analyte

Date

3/12/2010 13:45

3/12/2010 13:46

3/12/2010 13:46

3/12/2010 13:47

3/12/2010 13:47

3/12/2010 13:48

3/12/2010 13:48

3/12/2010 13:49

Sm

Su

DF

CS

Ce

Recovery (%)[

Method

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

Recovery (%)

Ce

32.6

26.5

15.6%

63.2

2.75

32.3

FileName

10 03 12 1352 23 429

10_03 12 1352 57_663

10 03 12 1353 32 037

10 03 12 1354 06 349

10 03_12_1354 40 660

10_03_12 1355 14 894

10 03 12 1355 49 206

10_03_12_1356_23_455

Avg. Cone, (ppm)

FileName

10_03_12_1345_31_690

10 03 12 1346_05_939

10 03 12 1346~40~250 10 03 12 1347 14 609

10_03_12_1347 48 889

10 03 12 1348 23 170

10_03_12_1348_57_513

10_03_12_1349_31_855

Avg. Cone, (ppm)

Sm Su(1-DF)

DFxCs

DF Cs Su(1-DF)

ppm

ppm

ppm

ppm

ppm

103%|70-130%

HCI (ppm)

31.7

32.4

32.7

32.5

32.8

32.8

33.2

32.5

32.6

HCI (ppm)

27.9

27.6

23.6

25.7

28.1

27.3

26.3

25.7

26.5

SEC (ppm)

0.725

0.746

0.756

0.751

0.761

0.762

0.777

0.757

SEC (ppm)

0.653

0.654

0.577

0.616

0.656

0.638

0.627

0.619

SF6 (ppm)

0.459

0.457

0.456

0.457

0.454

0.454

0.453

0.450

0455

SF6 (ppm)

0.0130

0.0140

0.0150

0.0150

0.0160

0.0140

0.0160

0.0900

0.0241

Mean concentration of spiked analyte

Native concentration of analyte

Dilution Factor (Target

Cylinder of spiked gas

10%)

Cylinder of tracer gas (SF6)

Expected concentration of analyte

SEC (ppm)

0.0360

0.0350

0.0350

0.0360

0.0360

0.0360

0.0360

0.0370

SEC (ppm)

0.0410

0.0420

0.0420

0.0420

0.0420

0.0420

0.0420

0.0400

EA# 0310-05 Page 27 of 48
Company

Analyst Initials

Parameters

Samples

O'Brien Gere

CJT

EPA Method 321

Client 45692 Kiln Exhaust

Job# 0310-05

PO#

Report Date

Verbal

3/19/2010

Kiln Exhaust Spike

Direct Spike Cylinder- Using Cylinder

Date

3/10/2010 10:00

3/10/2010 10:01

3/10/201010:02

3/10/2010 10:02

3/10/2010 10:03

3/10/2010 10:03

3/10/2010 10:04

3/10/2010 10:04

Method

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

FileName

10_03 10 1000 55 716

10 03 10 1001 29 871

10_03 10 1002 03 949

10_03 10 1002 38 088

10 03 10 1003 12 244

10 03 10 1003 46 383

10 03 10 1004 20 445

10_03_10_1004_54_584

Avg. Cone. (ppm)|

HCI (ppm)

62.7

62.8

63.0

63.1

63.2

63.6

63.7

63.6

63.2

SEC (ppm)

0.835

0.856

0.873

0.886

0.882

0.886

0.878

0.891

SF6 (ppm)

2.76

2.75

2.75

2.75

2.75

2.75

2.76

2.76

2.75

SEC (ppm)

0.00300

0.00300

0.00300

0.00300

0.00300

0.00300

0.00300

0.00300

EA# 0310-05 Page 26 of 48
Company

Analyst Initials

Parameters

Samples

O'Brien Gere

CJT

EPA Method 321

Client

Job#

PO#

Report Date

45692 -Kiln Exhaust

0310-05

Verbal

3/19/2010

Kiln Exhaust Spike

Sm -Spiked Data

Date

3/12/2010 15:55

3/12/2010 15:56

3/12/2010 15:57

3/12/2010 15:57

3/12/2010 15:58

3/12/2010.15:58

3/12/2010 15:59

3/12/2010 15:59

Method

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

Su Native Cone. Of analyte

Date

3/12/2010 15:49

3/12/2010 15:50

3/12/2010 15:50

3/12/201015:51

3/12/2010 15:51

3/12/2010 15:52

3/12/2010 15:53

3/12/201015:53

Sm

Su

DF

CS

Ce

Recovery (%)[

Method

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

Recovery (%)

Ce

24.9

21.3

14.5%

63.2

2.75

27.4

RleName

10 03 12 1555 54 821

10_03_12_1556 29 179

10_03 12 1557 03 475

10 03 12 1557 37 771

10 03 12 1558 12 051

10 03 12 1558 46 284

10_03_12_1559 20 642

10_03_12_1559_54_875

Avg. Cone, (ppm)

FileName

10 03 12 1549 37 630

10_03_12 1550 11_879

10 03 12 1550 46 128

10_03_12_1551_20_439

10_03_12_1551_54 751

10 03 12~1552 29 046

10_03_12_1553_03_264

10_03_12_1553_37_529

Avg. Cone, (ppm)

Sm Su(1-DF)

DFxCs

DF Cs Su(1-DF)

ppm

ppm

ppm

ppm

ppm

72.4%|70-130%

HCI (ppm)

23.1

23.8

24.6

25.4

25.8

25.8

26.4

24.0

24.9

HCI (ppm)

19.3

20.5

21.2

21.8

22.0

21.9

21.8

21.9

21.3

SEC (ppm) SF6 (ppm)

0.819

0.845

0.867

0.889

0.910

0.909

0.926

0.851

0.428

0.427

0.427

0.427

0.426

0.425

0.428

0.427

0.427

SEC (ppm) SF6 (ppm)

0.717

0.753

0.785

0.799

0.801

0.793

0.804

0.801

0.0250

0.0280

0.0290

0.0290

0.0290

0.0260

0.0260

0.0260

0.0273

Mean concentration of spiked analyte

Native concentration of analyte

Dilution Factor (Target

Cylinder of spiked gas

10%)

Cylinder of tracer gas (SF6)

Expected concentration of analyte

SEC (ppm)

0.0390

0.0390

0.0390

0.0390

0.0360

0.0380

0.0390

0.0390

SEC (ppm)

0.0430

0.0430

0.0440

0.0440

0.0440

0.0430

0.0440

0.0440

EA# 0310-05 Page 29 of 46
Company

Analyst Initials

Parameters

Samples

O'Brien Gere

CJT

EPA Method 321

Client 45692 Kiln Exhaust

Job #0310-05

PO# Verbal

Report Date 3/19/2010

Kiln Exhaust Spike

Direct Spike Cytinder- Using Cylinder

Date

3/10/2010 10:00

3/10/2010 10:01

3/10/2010 10:02

3/10/201010:02

3/10/2010 10:03

3/10/2010 10:03

3/10/2010 10:04

3/10/2010 10:04

Method

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

FileName

10 03 10 1000 55 716

10 03 10 1001_29 871

10 03 10 1002 03 949

10.03 10 1002 38 068

10 03 10 1003 12 244

10_03_10_1003_46__383

10 03 10J004 20 445

10_03_10_1004_54_584

Avg. Cone. (ppm)|

HCI (ppm)

62.7

62.8

63.0

63.1

63.2

63.6

63.7

63.6

63.2

SEC (ppm)

0.835

0.856

0.873

0.886

0.882

0.886

0.878

0.891

.I

SF6 (ppm)

2.76

2.75

2.75

2.75

2.75

2.75

2.76

2.76

2.75

SEC (ppm)

0.00300

0.00300

0.00300

0.00300

0.00300

0.00300

0.00300

0.00300

EA# 0310-05 Page 30 of 48
Company

Analyst Initials

Parameters

Samples

O'Brien Gere

CJT

EPA Method 321

Client

Job#

PO#

Report Date

45692 Kiln Exhaust

0310-05

Verbal

3/19/2010

Ambient Spike

Sm -Spiked Data

Date

3/12/2010 8:30

3/12/2010 8:31

3/12/2010 8:31

3/12/2010 8:32

3/12/2010 8:32

3/12/2010 8:33

3/12/2010 8:34

3/12/2010 8:34

Method

0310-05A

0310-05A

0310-05A

O31O-05A

0310-05A

0310-05A

0310-05A

0310-05A

Su Native Cone. Of analyte

Date

3/12/2010 8:12

3/12/2010 8:12

3/12/2010 8:13

3/12/2010 8:13

3/12/2010 8:14

3/12/20108:14

3/12/2010 8:15

3/12/2010 8:15

Sm

Su

DF

CS

Ce

Recovery (%)|

Method

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

Recovery (%)

Ce

6.28

0.186

10.1%

63.2

2.75

6.58

FileName

10_03 12 0830 45 246

10JJ3 12 0831 18 261

10_03_12_0831_51_276

10_03_12_0832_24 197

10 03 12~0832 57 259

10J)3 12 0833 30 305

10 03 12 0834 03 398

10_03_12_0834_36_319

Avg. Cone, (ppm)

FileName

10_03 12 0812 01 915

10 03 12 0812 34 883

10 03 12 0813 07 929

10_03_12_0813_41 038

10 03 12 0814 14 146

10 03 12 0814 47 192

10 03 12 0815 20 301

10_03_12_0815_53_347

Avg. Cone. (ppm)|

Sm-Su(i-DF)

DFxCs

DFxCs Su(1-DF)

ppm

ppm

ppm

ppm

ppm

95.3%|70-130%

HCI (ppm)

6.11

6.29

6.30

6.26

6.34

6.36

6.39

6.21

6.28

HCI (ppm)

0.270

0.129

0.267

0.217

0.181

0.147

0.149

0.124

0.186

SEC (ppm)

0.196

0.192

0.189

0.194

0.196

0.189

0.189

0.198

SEC (ppm)

0.131

0.129

0.132

0.126

0.137

0.129

0.131

0.124

SF6 (ppm)

0.281

0.279

0.281

0.281

0.281

0.280

0.281

0.281

0.281

SF6 (ppm)

0.00100

0.00100

0.00100

0.00200

0.00100

0.00100

0.00100

0.00100

0.00113

Mean concentration of spiked analyte

Native concentration of analyte

Dilution Factor (Target 10%)

Cylinder of spiked gas

Cylinder of tracer gas (SF6)

Expected concentration of analyte

SEC (ppm)

0.00100

0.00100

0.00100

0.00100

0.00100

0.00100

0.00100

0.00100

SEC (ppm)

0.00100

0.00100

0.00100

0.00100

0.00100

0.00100

0.00100

0.00100

EA# 0310-05 Page 31 of 48
Company

Analyst Initials

Parameters

Samples

O'Brien Gere

CJT

EPA Method 321

Client 45692 Kiln Exhaust

Job #0310-05

PO#

Report Date

Verbal

3/19/2010

Ambient Spike

Direct Spike Cylinder

Date Method

3/10/2010 10:00

3/10/2010 10:01

3/10/2010 10:02

3/10/2010 10:02

3/10/2010 10:03

3/10/2010 10:03

3/10/2010 10:04

3/10/2010 10:04

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

FileName

10 03 10 1000 55 716

10 03 10 1001 29 871

10 03 10 1002 03 949

10 03 10 1002 38 088

10 03 10 1003 12 244

10_03_10 1003 46 383

10 03 10 1004 20 445

10_03_10_1004_54_584

Avg. Cone. (ppm)|

HCI (ppm)

62.7

62.8

63.0

63.1

63.2

63.6

63.7

63.6

63.2

SEC (ppm)

0.835

0.856

0.873

0.886

0.882

0.886

0.878

0.891

SF6 (ppm)

2.76

2.75

2.75

2.75

2.75

2.75

2.76

2.76

2.75

SEC (ppm)

0.00300

0.00300

0.00300

0.00300

0.00300

0.00300

0.00300

0.00300

EA# 0310-05 Page 32 of 48
Company

Analyst Initials

Parameters

Samples

O'Brien Gere

CJT

EPA Method 321

Report Date

Client 45692 Kiln Exhaust

Job #0310-05

PO# Verbal

3/19/2010

Ambient Spike

Sm -Spiked Data

Date

3/12/2010 16:41

3/12/2010 16:41

3/12/2010 16:42

3/12/2010 16:43

3/12/2010 16:43

3/12/201016:44

3/12/2010 16:44

3/12/2010 16:45

Method

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

Su Native Cone. Of analyte

Date

3/12/2010 16:34

3/12/2010 16:35

3/12/201016:35

3/12/2010 16:36

3/12/2010 16:36

3/12/2010 16:37

3/12/2010 18:37

3/12/2010 16:38

Sm

Su

DF

CS

Ce

Recovery (%)|

Method

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

Recovery (%) =

Ce

11.2

2.47

17.3%

63.2

2.75

13.0

FDeName

10 03 12 1641 21 386

10_03_12J641_55_744

10 03 12 1642 30 103

10~03 12~1643 04~461

10 03 12 1643 38 741

10 03 12 1644 13 099

10_03 12 1644 47 473

10_03_12_1645_21_785

Avg. Cone, (ppm)j

FileName

10 03 12 1634 29 525

10 03 12 1635 03 836

10 03 12 1635 38 132

10_03_12_1636_12_474

10 03 12 1636 46_755

10 03 12 1637 21 113

10 03 12 1637 55 424

10_03_12_1638_29_782

Avg. Cone. (ppm)|

Sm Su(1-DF)

DFxCs

DF Cs Su(1-DF)

ppm

ppm

ppm

ppm

ppm

83.7%|70-130%

HCI (ppm)

11.2

11.5

11.4

11.2

11.0

11.0

11.1

11.2

11.2

HCI (ppm)

2.44

2.47

2.50

2.42

2.46

2.53

2.43

2.49

2.47

SEC (ppm)

0.410

0.426

0.430

0.421

0.411

0.410

0.421

0.416

SEC (ppm)

0.162

0.164

0.162

0.169

0.156

0.166

0.168

0.163

SF6 (ppm)

0.475

0.475

0.474

0.473

0.473

0.474

0.473

0.473

0474

SF6 (ppm)

-0.00300

-0.00300

•0.00300

•0.00300

-0.00300

-O.00300

-0.00300

•0.00300

giMU'friiUM

Mean concentration of spiked analyte

Native concentration of analyte

Dilution Factor (Target

Cylinder of spiked gas

10%)

Cylinder of tracer gas (SF6)

Expected concentration of analyte

SEC (ppm)

0.00200

0.00200

0.00200

0.00200

0.00200

0.00200

0.00200

0.00200

SEC (ppm)

0.00200

0.00200

0.00200

0.00200

0.00200

0.00200

0.00200

0.00200

EA# 0310-05 Page 33 Of 48
Company

Analyst Initials

Parameters

Samples

O'Brien Gere

CJT

EPA Method 321

Client

Job#

PO#

Report Date

45692 Kiln Exhaust

0310-05

Verbal

3/19/2010

Ambient Spike

Direct Spike Cylinder* Using Cylinder

Date

3/10/2010 10:00

3/10/201010:01

3/10/201010:02

3/10/2010 10:02

3/10/2010 10:03

3/10/2010 10:03

3/10/201010:04

3/10/2010 10:04

Method

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

0310-05A

FileName

10 03 10 1000 55 716

10_03 10 1001 29 871

10_03 10 1002 03 949

10_03_10_1002_38_088

10 03 10 1003 12 244

10_03_10_1003 46 383

10 03 10 1004 20 445

10J>3_10_1004_54_584

Avg. Cone. (ppm)|

HCI (ppm)

62.7

62.8

63.0

63.1

63.2

63.6

63.7

63.6

63.2

SEC (ppm)

0.835

0.856

0.873

0.888

0.882

0.886

0.878

0.891

SF6 (ppm)

2.76

2.75

2.75

2.75

2.75

2.75

2.76

2.78

2.75

SEC (ppm)

0.00300

0.00300

0.00300

0.00300

0.00300

0.00300

0.00300

0.00300

EA# 0310-05 Page 34 of 48
FTIR Method Map

EA# 0310-05 Page 35 of 48
CTS Method Map:

Overrides: Path Length=100ppm

Method Name: 0310-05CTS

Method Path: I:\FTIR2010Ql\0310-05_OBG_LaFarge\methods\0310-05CTS\0310-

05CTS.aq4

Method Type: AutoQuant 4.0

Linear Analysis Mode

MethodParameters

Wavenumber range: 650.00-4500.00 cm-1

Default Pathlength 101.7000

Gain ==0.000000

Apodization Triangle

Phase Correction Mertz

Resolution 0.5 cm-1

Baseline Correction: Single Linear

Exclusion Criterion: 2500.000000

Compound: ethylene

Description:

Molecular Weight: 0.00

Alarms: Disabled

Primary Spectrum: ETYH5A.SPC

Reference Concentration: 206.6000 ppm-m

Reference Pathlength: 1.0000

Reference Pressure: 1.0000 atm

Reference Temperature: 121.00

Region #1: 870.00 -1040.00 cm-1

EA# 0310-05 Page 36 of 48
Sample Method Map:

Overrides: Path Length=8.77m

Method Name: 0310-05

Method Path: I:\FTIR2010Qi\0310-05_OBG_LaFarge\niethod8\0310-05A\0310-

05A.aq4

Method Type: AutoQuant4.0

Non-Linear Analysts Mode

MethodParameters

Wavenumber range: 650.00 4500.00 cm-1

Defeult Pathlength 7.7000

Gain 0.000000

Apodization Triangle

Phase Correction Mertz

Resolution 0.5 cm-1

Baseline Correction: Single Linear

Exclusion Criterion: 2500.000000

Compound: CO2

Description:

Molecular Weight: 0.00

Alarms: Disabled

Primary Spectrum: CO2_16.92%_9.064m.SPC

Reference Concentration: 153.3629 ppm-m

Reference Pathlength: 9.0640

Reference Pressure: 1.0250 atm

Reference Temperature: 121.03

Region #1: 897.02 1111.60 cm-1

Region #2: 2003.55 2162.64 cm-1

Compound: SF6

Description:

Molecular Weight: 0.00

Alarms: Disabled

Primary Spectrum: SF6_2.92ppm_8.977m_l 81 C.SPC

Reference Concentration: 26.2128 ppm-m

Reference Pathlength: 8.9770

Reference Pressure: 1.0261 atm

Reference Temperature: 180.95

Region#l: 901.95-971.86 cm-1

Compound: H2O

Description:

Molecular Weight: 0.00

Alarms: Disabled

Primary Spectrum: 09_01_23_1643_07_613.abs

Reference Concentration: 2250.0000 ppm-m

EA# 0310-05 Page 37 of 48
Reference Pathlength: 7.5000

Reference Pressure: 1.0154 atm

Reference Temperature: 121.10

Region #1: 1956.81 2157.79 cm-1

Region #2: 841.63 -1089.70 cm-1

Region #3: 3040.50 2501.27 cm-1

Compound: HC1

Description:

Molecular Weight: 0.00

Alarms: Disabled

Primary Spectrum: HCl_61.0ppm_9.698m_181CJatm.SPC

Reference Concentration: 590.4800 ppm-m

Reference Pathlength: 9.6800

Reference Pressure: 1.0016 atm

Reference Temperature: 180.88

Region #1: 2748.78 2825.17 cm-1

Spectrum: HCl_30.5ppm_9.698m_181C_latm.SPC

Reference Concentration: 295.2400 ppm-m

Reference Pathlength: 9.6800

Reference Pressure: 0.9976 atm

Reference Temperature: 181.10

Region #1: 2748.78 2825.17 cm-1

Spectrum: HC1_15.25ppm_9.698m_l 81C_latm.SPC

Reference Concentration: 147.6200 ppm-m

Reference Pathlength: 9.6800

Reference Pressure: 0.9970 atm

Reference Temperature: 180.73

Region #1: 2748.78 2825.17 cm-1

Spectrum: HCl_5.0ppm_9.698m_l 81 C_l atm.SPC

Reference Concentration: 48.4000 ppm-m

Reference Pathlength: 9.6800

Reference Pressure: 0.9987 atm

Reference Temperature: 181.03

Region #1: 2748.78 2825.17 cm-1

Compound: NH3

Description:

Molecular Weight: 0.00

Alarms: Disabled

Primary Spectrum: Ammonial0ppm(9.355m).SPC

Reference Concentration: 93.5500 ppm-m

Reference Pathlength: 9.3550

Reference Pressure: 0.9921 atm

Reference Temperature: 121.00

Region #1: 914.80 975.89 cm-1

EA# 0310-05 Page 38 of 48
Logbook Notes

EA# 0310-05 Page 39 of 48
174 Project No.

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Selected Spectra

EA# 0310-05 Page 46 of 48
Top: HCl Reference Spectrum

Bottom: Kiln Exhaust Sample Spectrum

EA# 0310-05 Page 47 of 48
This Is The Last Page

Of This Report.

EA# 0310-05 Page 48 of 48