## ATTACHMENT HEADER SHEET
Attachment Number017 Attachment Name Attachment 17 Chemical #2(CaPZT) MVSDS



## Associated PMN Section Number N/A Does notcontain CBI



## Report Number CONS 110317786855351

### Attachment 17: Calcium Cobalt Lead Titanium Tungsten Oxide MSDS REPORT#

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### CONS110317786855351 

## MATERIAL SAFETY DATA SHEET
SECTION 1- PRODUCT INFORMATION Manufacturer's Name: Lockheed Martin Health 3 497 Electronics Parkway Flammability 0 Syracuse, N.Y. 13088 Reactivity 1 Emergency Telephone (315) 456-3723 8am-5pm -EST (315) 456-2917 24 Hours

Information Telephone: (315) 456-3723
Chemical Name: Calcium Cobalt Lead Titanium Tungsten Oxide Trade Name: PT, Lead Titanate, LM-91
SECTION 11I- HEALTH HAZARD IDENTIFICATION
EMERGENCY OVERVIEW Caution may cause eye, skin andrespiratory tract irritation. May cause damage to the nervous and immune systems, kidneys, blood and produce adverse reproductive effects. May cause cancer. ROUTES OFEXPOSURE Inhalation: Inhalation ofdust or fume may cause respiratory irritation. Ingestion: Ingestion ofdust may result from hand to mouth contact or ingestion ofdust SkinContact: Contact with skin may cause irritation. Skin Absorption: Not expected from dusts. Eye Contact: Dust or fume contact with eyes may cause irritation.
POTENTIALHEALTH EFFECTS SingleAcute Overexposure: May produce eye, skin andrespiratory tract irritation, effects on thenervous system and kidneys, gastrointestinal distress and anemia. Common symptoms area loss of appetite, nausea, vomiting, stomach cramps, constipation, anxiety, difficulty in sleeping, fatigue, moodiness, headache,joint ormuscle aches and decreased sexual drive. Extreme overexposure may lead to tremors, convulsions, paralysis, stupor, coma anddeath. Chronic, Prolonged or Repeated Children have enhanced absorption andretention ofingested lead and are Overexposure particularly sensitive to thechronic effects oflead, with slowed cognitive development and reduced growth. May produce effects onthe blood, nervous and immune systems, bloodpressure, kidneys as well as skin and pulmonary inflammatory tissue masses, rickets-like bone deformities, decreased sperm count and spontaneous abortion. Common symptoms are a loss ofappetite, metallic taste

### Attachment 17: Calcium Cobalt Lead Titanium Tungsten Oxide MSDS REPORT#

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### CONS110317786855351

in the mouth, anxiety, constipation, nausea, pallor, fatigue, weakness, insomnia, headache, nervous irritability, muscle andjoint painor soreness, fine tremors, numbness, dizziness, hyperactivity and abdominal pain. Maternal overexposure may produce lowbirth weight, birth defects and slowed postnatal neurobehavioral development in the offspring. Extreme overexposure may lead to vomiting, drowsiness, stupor, poor memory, restlessness, irritability, tremor, convulsions, coma and death. Muscular weakness may develop and progress to paralysis observed as "wrist-drop" and/or "foot-drop". Component Carcinogenicity Lead Compounds Inorganic IARC: Group 2A
- Probably Carcinogenic to Humans. NTP: Reasonably anticipated tobe a human carcinogen
ATSDR Toxicological Profile forLead at http://www.atsdr.cdc.gov/ToxProfiles/tp.asp?id=96&tid=22
EMERGENCY AND FIRST AID PROCEDURES Inhalation: Ifaperson breathes large amounts ofthis chemical, movethe exposed person to fresh air at once. Ifbreathing has stopped, perform artificial respiration. Keep the affected person warm and atrest. Get medical attention as soon as possible. Ingestion: Ifthis chemical has been swallowed, getmedical attention immediately. Skin Ifthis chemical contacts the skin, promptly flush thecontaminated skin with soap and water. Ifthis chemical penetrates the clothing, promptly remove theclothing and flush the skin with water. If irritationpersists after washing, get medical attention. Eye Ifthis chemical contacts theeyes, immediately wash (irrigate) the eyes with large amounts ofwater, occasionally lifting the lower and upper lids. Getmedical attention immediately.

NOTE TO PHYSICIAN: Damage to the central nervous system in general and the brain (encephalopathy) in particular is one ofthe mostsevere forms ofleadpoisoning. The most severe, often fatal, formofencephalopathy may be preceded by vomiting, a feeling ofdullness progressing to drowsiness and stupor, poor memory, restlessness, irritability, tremor, and convulsions. It may arise suddenly withthe onset ofseizures, followed bycoma, and death. There is a tendency for muscular weakness to develop at the sametime. This weakness mayprogress to paralysis often observed as acharacteristic "wrist drop" or "foot drop" andis a manifestation ofa disease to thenervous system called peripheral neuropathy. Those chronically intoxicated may have gingival lead lines, i.e. blue discoloration.
SECTION III- HAZARDOUS INGREDIENTS Material or Component C.A.S. # Weight % TLV-TWA mglm3 8hr PEL- TWA mg/m3 8hr Calcium cobalt lead titanium 1262279- 100 0.05(as Pb) 0.05(as Pb) tungsten oxide 31-1
This product is considered a lead compound. Please refer to the Code ofFederal Regulations CFRTitle 29 1910.1025 Lead Standard for industrial workers.

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### CONS110317786855351

SECTION IV
- PHYSICAL DATA BoilingPoint at760 mmn Hg: NA Specific Gravity (H20 =1): 7.0- 7.5 Melting Point: 1350C Solubility in H20 (g/l): 0.05 VaporPressure (mmn Hg): % NA Evaporation Rate: NA Volatiles by Volume: NA Molecular Weight 260-290 Appearance and Odor: Brown or Tan or Reddish Tan Powder, Odorless SECTION V
-FIRE AND EXPLOSION HAZARD DATA LEL: NA UEL: NA Flash Point Flammable NA Auto ignition Temperature NA Limits: Extinguishing NA Media Water, C02 andDry Chemical Special Fire Fighting Procedures: Wear full body protective clothing, full face piece andNIOSHIMSHA approved Positive pressure self-contained breathing apparatus. Unusual Fire andExplosion Hazards: Fume, vapor and/or dust may occur and are considered toxic and respiratory irritants. May react with strong oxidizing agents.
SECTION VI- REACTIVITY DATA Stability Stable to 800 C Incompatibilities: Strong Acids, Conditions to Avoid: Do not heat inthe presence ofstrong acids as dissolution oflead may occur. Hazardous Decomposition Products: Elevated temperatures (above 800 C) orfire may produce lead oxide fume, vapor or dust. Hazardous Polymerization: Will not occur.
SECTION VII- SPECIAL PROTECTION Respiratory Protection: ANIOSH! approved respirator withP100 filters shall be worn when airborne exposures may exceed OSHAIACGII{ permissible air concentrations. Protective Gloves: Latex or nitrile gloves required. Eye Protection: Safety glasses are recommended for protection against exposures to dusts. Protective Clothing: Fullbody clothing shouldbe wornto prevent potential exposure to skin. Iflead PEL or TLV is exceeded, protective clothing shall be provided inaccordance with OSHA Standard 29 CER 1910.1025. Ventilation: Sufficient mechanical ventilation (general and/or local exhaust) shall be provided to maintain exposures below permissible airconcentrations. SECTION VIII- SPILL OR LEAKPROCEDURES Steps to Take intheEvent ofa Spill or Release In the eventofa spill or leak, avoid inhalation ofdustor fume. Gloves, goggles and

### Attachment 17: Calcium Cobalt Lead Titanium Tungsten Oxide MSDS REPORT#

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### CONS110317786855351 respirators should be worn during clean-up. Small spills should be vacuumed using a high efficiency filter vacuum. Do not use dry sweeping or compressed air. Waste Disposal Method: Waste shall becollected and disposed ofin accordance with all local, state and federal regulations. Waste may also be recycled inaccordance with local, state and federal regulations.. Neutralizing Materials: NotApplicable SECTION IX
- SPECIAL PRECAUTIONS Food and drink shall notbe consumed in areas ofuse. Tobacco products and cosmetics shall notbe used in areas ofuse. Always wash thoroughly after handling. Dirty shoes and clothing should not leave the workplace. Store this product away from all foods and feeds. Do not reuse containers. Containers may retain productresidues. All labeled precautions mustbe observed. This product is intended for industrial useonly. Keep away from children. Store in dry area. Avoid contact with acids and bases. SECTIONX
- TRANSPORTATION INFORMATION UN Number
- UN2291I Proper Shipping Name
- Lead Compound, soluble, n.o.s. Hazard Class
- 6.1 Packing Group
- PG III SECTIONXI- DEFINITIONS TLV/TWA Threshold LimitValue
- TimeWeighted Average (American Conference of Governmental Industrial Hygienists) PEL Permissible Exposure Limit (Occupational Safety &Health Administration LEL Lower Explosive Limit UEL Upper Explosive Limit NA NotApplicable NE NotEstablished PREPARED BY: Lockheed Martin 497 Electronics Parkway Syracuse, New York 13088 MSDS RevisionDate: 1/2011 The information accumulated and set forth herein is believed to be accurate as ofthe date hereof. Lockheed Martin makes no warranty with respect thereto anddisclaims all liability from reliance thereon. Recipients are advised to confirm in advance that the information is current, applicable, and suitable for theirparticular circumstances.