### 13339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone: 980-875-5245 Fax: 980-875-4349 

# Order Summary Report

Analytical Laboratory

Order Number: J10120256

Lab Contact: Jason C Perkins 

### Date: 1/6/2011 Customer Address: 253 Plant Allen Road Customer Name(s): Don Scruggs, Robbin Jolly, Ray Lidke, Bill Kennedy

Belmont, NC 28012
Phone: 980-875-5348 Report Authorized By: (Signature) 

### Program Comments: FGD Test Burn #2 - 12/5 Data Flags & Calculations: Any analytical tests or individual analytes within a test flagged with an "X" or "1" indicate a deviation from the method quality system or quality control requirement. All results are reported on a dry weight basis unless otherwise noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions.The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Labor atory Certificate of Analysis, Analytical Laboratory QC Reports, Sub-contracted Laborator y Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods.

## Sample ID's & Descriptions: Sample ID Plant/Station Collection Date and Time Collected By Sample Description 2010013534 ALLEN 05-Dec-10 10:07 AM Jeff Womack FGD Purge Eff 2010013536 ALLEN 05-Dec-10 9:47 AM Jeff Womack EQ Tank Eff 2010013537 ALLEN 05-Dec-10 9:44 AM Jeff Womack BioReactor 1 Inf 2010013538 ALLEN 05-Dec-10 10:11 AM Jeff Womack BioReactor 2 Inf 2010013539 ALLEN 05-Dec-10 9:50 AM Jeff Womack BioReactor 2 Eff 2010013540 ALLEN 05-Dec-10 12:06 PM Jeff Womack Filter Blk 2010013541 ALLEN 22-Nov-10 1:45 PM L. Davis TRIP BLANK 7 Total Samples

### COC and .pdf report are in agreement with sample totals and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. All laboratory QA/QC requirements are acceptable. The Vendor Laboratories have been qualified by the Analytical Laboratory Yes No 

# Technical Validation Review Checklist:

Yes No
Yes No



## Report Sections Included: Job Summary Report Sub-contracted Laboratory Results Sample Identification Customer Specific Data Sheets, Reports, & Documentation Technical Validation of Data Package Customer Database Entries Analytical Laboratory Certificate of Analysis Test Case Narratives Analytical Laboratory QC Report Chain of Custody

Reviewed By: 

### Jenny A Herman Date: 

### 1/6/2011 Yes

Electronic Data Deliverable (EDD) Sent Separately

# Certificate of Laboratory Analysis This re port shall not be re produced, exce pt in full. 

## Order # J10120256

2010013534 Collection Date: 05-Dec-10 10:07 AM 

### Site: FGD Purge Eff Matrix: OTHER
Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

### Sample #:

Analyst MERCURY (COLD VAPOR) IN WATER Mercury (Hg) 21.8 ug/L EPA 245.1 16-Dec-10 14:55 2.5 MHH7131 TOTAL RECOVERABLE METALS BY ICP Boron (B) 181 mg/L EPA 200.7 14-Dec-10 15:00 0.5 DJSULL1 DISSOLVED METALS BY ICP-MS Selenium (Se) 125 ug/L EPA 200.8 27-Dec-10 15:16 10 KRICHAR TOTAL RECOVERABLE METALS BY ICP-MS Arsenic (As) 198 ug/L EPA 200.8 30-Dec-10 14:22 10 KRICHAR Chromium (Cr) 221 ug/L EPA 200.8 30-Dec-10 14:22 10 KRICHAR Copper (Cu) 240 ug/L EPA 200.8 30-Dec-10 14:22 10 KRICHAR Nickel (Ni) 368 ug/L EPA 200.8 30-Dec-10 14:22 10 KRICHAR Selenium (Se) 1720 ug/L EPA 200.8 30-Dec-10 14:22 10 KRICHAR Silver (Ag) < 10 ug/L EPA 200.8 30-Dec-10 14:22 10 KRICHAR Zinc (Zn) 508 ug/L EPA 200.8 30-Dec-10 14:22 20 KRICHAR TOTAL DISSOLVED SOLIDS Vendor Parameter Complete V_PRISM 

### 2010013536 Collection Date: 05-Dec-10 9:47 AM 

### Site: EQ Tank Eff Matrix: OTHER
Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

### Sample #:

Analyst MERCURY (COLD VAPOR) IN WATER Mercury (Hg) 15.3 ug/L EPA 245.1 16-Dec-10 14:57 2.5 MHH7131 TOTAL RECOVERABLE METALS BY ICP Boron (B) 119 mg/L EPA 200.7 14-Dec-10 15:04 0.5 DJSULL1 DISSOLVED METALS BY ICP-MS Selenium (Se) 86.0 ug/L EPA 200.8 27-Dec-10 15:20 10 KRICHAR TOTAL RECOVERABLE METALS BY ICP-MS Arsenic (As) 270 ug/L EPA 200.8 30-Dec-10 14:17 10 KRICHAR Chromium (Cr) 242 ug/L EPA 200.8 30-Dec-10 14:17 10 KRICHAR Copper (Cu) 299 ug/L EPA 200.8 30-Dec-10 14:17 10 KRICHAR Nickel (Ni) 436 ug/L EPA 200.8 30-Dec-10 14:17 10 KRICHAR Selenium (Se) 1800 ug/L EPA 200.8 30-Dec-10 14:17 10 KRICHAR Silver (Ag) < 10 ug/L EPA 200.8 30-Dec-10 14:17 10 KRICHAR Zinc (Zn) 518 ug/L EPA 200.8 30-Dec-10 14:17 20 KRICHAR

# Certificate of Laboratory Analysis This re port shall not be re produced, exce pt in full. 

## Order # J10120256

2010013537 Collection Date: 05-Dec-10 9:44 AM 

### Site: BioReactor 1 Inf Matrix: OTHER
Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

### Sample #:

Analyst TOTAL RECOVERABLE METALS BY ICP Boron (B) 95.7 mg/L EPA 200.7 14-Dec-10 15:08 0.5 DJSULL1 DISSOLVED METALS BY ICP-MS Selenium (Se) 95.6 ug/L EPA 200.8 27-Dec-10 15:24 10 KRICHAR TOTAL RECOVERABLE METALS BY ICP-MS Arsenic (As) < 10 ug/L EPA 200.8 30-Dec-10 13:58 10 KRICHAR Chromium (Cr) < 10 ug/L EPA 200.8 30-Dec-10 13:58 10 KRICHAR Copper (Cu) 12.0 ug/L EPA 200.8 30-Dec-10 13:58 10 KRICHAR Nickel (Ni) 23.5 ug/L EPA 200.8 30-Dec-10 13:58 10 KRICHAR Selenium (Se) 77.0 ug/L EPA 200.8 30-Dec-10 13:58 10 KRICHAR Silver (Ag) < 10 ug/L EPA 200.8 30-Dec-10 13:58 10 KRICHAR Zinc (Zn) < 20 ug/L EPA 200.8 30-Dec-10 13:58 20 KRICHAR 

### 2010013538 Collection Date: 05-Dec-10 10:11 AM 

### Site: BioReactor 2 Inf Matrix: OTHER
Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

### Sample #:

Analyst TOTAL RECOVERABLE METALS BY ICP Boron (B) 78.9 mg/L EPA 200.7 14-Dec-10 15:12 0.5 DJSULL1 TOTAL RECOVERABLE METALS BY ICP-MS Arsenic (As) < 10 ug/L EPA 200.8 30-Dec-10 13:53 10 KRICHAR Chromium (Cr) < 10 ug/L EPA 200.8 30-Dec-10 13:53 10 KRICHAR Copper (Cu) < 10 ug/L EPA 200.8 30-Dec-10 13:53 10 KRICHAR Nickel (Ni) 43.5 ug/L EPA 200.8 30-Dec-10 13:53 10 KRICHAR Selenium (Se) < 10 ug/L EPA 200.8 30-Dec-10 13:53 10 KRICHAR Silver (Ag) < 10 ug/L EPA 200.8 30-Dec-10 13:53 10 KRICHAR Zinc (Zn) < 20 ug/L EPA 200.8 30-Dec-10 13:53 20 KRICHAR 

### 2010013539 Collection Date: 05-Dec-10 9:50 AM 

### Site: BioReactor 2 Eff Matrix: OTHER
Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

### Sample #:

Analyst MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 1 ug/L EPA 245.1 16-Dec-10 14:48 1 MHH7131 TOTAL RECOVERABLE METALS BY ICP Boron (B) 69.8 mg/L EPA 200.7 14-Dec-10 15:16 0.5 DJSULL1 TOTAL RECOVERABLE METALS BY ICP-MS Arsenic (As) < 5 ug/L EPA 200.8 30-Dec-10 14:03 5 KRICHAR

# Certificate of Laboratory Analysis This re port shall not be re produced, exce pt in full. 

## Order # J10120256

2010013539 Collection Date: 05-Dec-10 9:50 AM 

### Site: BioReactor 2 Eff Matrix: OTHER
Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

### Sample #:

Analyst TOTAL RECOVERABLE METALS BY ICP-MS Chromium (Cr) < 5 ug/L EPA 200.8 30-Dec-10 14:03 5 KRICHAR Copper (Cu) < 5 ug/L EPA 200.8 30-Dec-10 14:03 5 KRICHAR Nickel (Ni) < 5 ug/L EPA 200.8 30-Dec-10 14:03 5 KRICHAR Selenium (Se) < 5 ug/L EPA 200.8 30-Dec-10 14:03 5 KRICHAR Silver (Ag) < 5 ug/L EPA 200.8 30-Dec-10 14:03 5 KRICHAR Zinc (Zn) < 10 ug/L EPA 200.8 30-Dec-10 14:03 10 KRICHAR 

### 2010013540 Collection Date: 05-Dec-10 12:06 PM 

### Site: Filter Blk Matrix: OTHER
Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

### Sample #:

Analyst DISSOLVED METALS BY ICP-MS Selenium (Se) < 2 ug/L EPA 200.8 27-Dec-10 16:03 2 KRICHAR 

### 2010013541 Collection Date: 22-Nov-10 1:45 PM 

### Site: TRIP BLANK Matrix: OTHER
Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

### Sample #:

Analyst TOTAL RECOVERABLE METALS BY ICP Boron (B) < 0.05 mg/L EPA 200.7 14-Dec-10 14:14 0.05 DJSULL1 TOTAL RECOVERABLE METALS BY ICP-MS Arsenic (As) < 1 ug/L EPA 200.8 30-Dec-10 13:49 1 KRICHAR Chromium (Cr) < 1 ug/L EPA 200.8 30-Dec-10 13:49 1 KRICHAR Copper (Cu) < 1 ug/L EPA 200.8 30-Dec-10 13:49 1 KRICHAR Nickel (Ni) < 1 ug/L EPA 200.8 30-Dec-10 13:49 1 KRICHAR Selenium (Se) < 1 ug/L EPA 200.8 30-Dec-10 13:49 1 KRICHAR Silver (Ag) < 1 ug/L EPA 200.8 30-Dec-10 13:49 1 KRICHAR Zinc (Zn) < 2 ug/L EPA 200.8 30-Dec-10 13:49 2 KRICHAR

### This data package contains the analytical results for the project identified above and includes a Case Narrative, Sample Results and Chain of Custody. Unless otherwise noted, all samples were received in acceptable condition and processed according to the referenced methods. Data qualifiers are flagged individually on each sample. A key reference for the data qualifiers appears at the end of this case narrative. NC Certification No. 402 SC Certification No. 99012 NC Drinking Water Cert No. 37735 

# Case Narrative 12/27/2010

Duke Energy Corporation Jay Perkins 13339 Hagers Ferry Road Huntersville, NC 28078 Project: Allen - FGD Alternative Fuels Test Burn #2 Daily Project No.: J10120256 Lab Submittal Date: 12/13/2010 Prism Work Order: 0120404

Please call if you have any questions relating to this analytical report. Respectfully, PRISM LABORATORIES, INC.



### VP Laboratory Services Reviewed By

Data Qualifiers Key Reference: 

### HT Sample received and analyzed outside of the hold time.

Method Detection Limit MDL Below Reporting Limit BRL Relative Percent Difference RPD 

## * Results reported to the reporting limit. All other results are reported to the MDL with values between MDL and reporting limit indicated with a J.

This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.

449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 

## Page 1 of 5

# Sample Receipt Summary 12/27/2010 

## Prism Work Order: 0120404 Client Sample ID Matrix Lab Sample ID Date Sampled Date Received 

### 0120404-01 12/05/10 2010013534/FGD Purge Eff 12/13/10 Water Samples received in good condition at 2.1 degrees C unless otherwise noted.

This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.

449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 

## Page 2 of 5

# Laboratory Report 12/27/2010

Result Parameter Batch ID Report Limit Analysis Date/Time Method Dilution Factor Units MDL Analyst 

### 13339 Hagers Ferry Road Project No.: J10120256 Project: Allen - FGD Alternative Fuels Test Burn #2 Daily Duke Energy Corporation
Huntersville, NC 28078 Attn: Jay Perkins Sample Matrix: Water Client Sample ID: 2010013534/FGD Purge E Prism Sample ID: 0120404-01 Prism Work Order: 0120404 Time Collected: 12/05/10 10:07 Time Submitted: 12/13/10 15:00

General Chemistry Parameters 9200 *SM2540 C P0L0357 1 50 12/16/10 14:00 JAB HT mg/L 8.7 Total Dissolved Solids

This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 

## Page 3 of 5

### 12/27/10 

## Level II QC Report

13339 Hagers Ferry Road Project No: J10120256 Project: Allen - FGD Alternative Fuels Test Burn #2 Daily Duke Energy Corporation Huntersville, NC 28078 Attn: Jay Perkins Prism Work Order: 0120404 Time Submitted: 12/13/10 3:00:00PM

Result Limit

Reporting Units Level Spike Result

Source %REC %REC Limits RPD RPD Limit Notes Analyte General Chemistry Parameters - Quality Control



### Batch P0L0357 - NO PREP Blank (P0L0357-BLK1) 

### Prepared & Analyzed: 12/16/10 Total Dissolved Solids mg/L BRL 50 LCS (P0L0357-BS1) 

### Prepared & Analyzed: 12/16/10 Total Dissolved Solids mg/L 998 50 1000 90-110 100 

### Sample Extraction Data NO PREP Lab Number Batch Date Initial Final P0L0357 0120404-01 12/16/10 50 50 mL mL

This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.

449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 

## Page 4 of 5Page 5 of 5