## From: Michael.Pelan@lafarge

‐ na.com

To: Keith Barnett/RTP/USEPA/US@EPA

Cc: Craig.Campbell@lafarge

‐ na.com, Brian.Gasiorowski@lafarge

‐ na.com,

Bill.Voshell@lafarge

‐ na.com, Paul.Rappleyea@lafarge

‐ na.com, Robert.Budnik@lafarge

‐ na.com

Date: 04/01/2010 12:14 PM

Subject: HCl Testing results

‐ Section 114 Request

Keith:

Attached are the completed ERT Template spreadsheets for the HCl testing

conducted at the Ravena and Alpena plants. As you recall, Alpena Kiln 23

was substituted for Sugar Creek Kiln 3, as this kiln was not operating during

the period required to collect these data. Note that I have made a couple of

minor format adjustments to the Alpena spreadsheet previously sent to you by

URS, so please use the attached version.

I am also attaching a copy of the Stack Test report for the Ravena testing.

The Alpena testing's report will be finalized in the next 10 days and

forwarded to you.

If you have any questions, please contact me.

Mike

(See attached file: RAV K1 HCl testing for Section 114 response Mar

2010.xlsx)(See attached file: RAV K1 FINAL_Lafarge_Stack HCl_033010.pdf)

(See attached file: ALP K23 HCl testing for Section 114 response Mar

2010.xlsx)(See attached file: RAV K1 HCl testing for Section 114 response Mar

2010.xlsx)(See attached file: RAV K1 FINAL_Lafarge_Stack HCl_033010.pdf)(See

attached file: ALP K23 HCl testing for Section 114 response Mar 2010.xlsx)Worksheet Title: HCl Emission Test Results Template Using Method 321

Who Should Complete this Spreadsheet?

Company Name:

Facility Name: Alpena

Address: 1435 Ford Avenue

City: Alpena

State: Michigan

Kiln ID:

Kiln Type: Long Dry

In-line Raw Mill:

Control Device Configuration:

Parameter Sample #1

Sample #2

Sample #3

Test Average Units Units Other Description Test Method Used Test Location Note

Select appropriate unit

from list. If other is

selected please describe

units in column H at right. Enter the name of the Test Method used. Indicate whether the test

occurred upstream or

downstream of a control

device(s); list the control

device(s) If kiln has an in-line raw mill,

indicate raw mill status during tests

(i.e., raw mill on or raw mill off).

Provide any other information

supporting information you think is

necessary about this test report.

Sample Date (mm/dd/yyyy) 3/25/2010 3/25/2010 3/25/2010

HCl Concentration - as measured - dry basis 34.84 33.79 29.55 ppmvd

Oxygen Concentration - dry basis 6.22 5.96 6.18 % (dry)

CO2 Concentration - dry basis 23.35 23.63 23.24 % (dry)

HCl Concentration - corrected to 7% oxygen 32.99 31.43 27.91 30.78 ppmvd @ 7% O2 Method 321 Downstream NA

Exhaust Stream %Moisture 5.87 5.56 5.25 %

Exhaust Flowrate 146090 144187 145502 SCFM

Exhaust Temperature ~ 400 ~ 400 ~ 400 degrees F Based on preliminary Velocity Traverse on 3/24/2010

Sample Date (mm/dd/yyyy)

HCl Concentration - as measured - dry basis N/A N/A N/A ppmvd

Oxygen Concentration - dry basis N/A N/A N/A %

CO2 Concentration - dry basis N/A N/A N/A %

HCl Concentration N/A N/A N/A ppmvd @ 7% O2

Exhaust Stream %Moisture N/A N/A N/A %

Exhaust Flowrate N/A N/A N/A (select flowrate units)

Exhaust Temperature N/A N/A N/A (select temperature units)

Notes: Fabric Filter

Enter HCl concentration value in dry

parts per million volume (ppmvd). If the

test results are below detection limit,

please note the detection limit in

brackets

(e.g., [< 0.010]).

Peach shaded cells indicate areas where the user will enter a response No K23 Facilities that use Method 321 to test for HCl

Lafarge North America

Enclosure 5c--ERT Spreadsheet Page 1 of 1Worksheet Title: HCl Emission Test Results Template Using Method 321

Who Should Complete this Spreadsheet?

Company Name:

Facility Name: Ravena Cement Plant

Address: 1916 Route 9W, PO Box 3

City: Ravena

State: New York

Kiln ID:

Kiln Type: Wet

In-line Raw Mill:

Control Device Configuration:

Parameter Sample #1

Sample #2

Sample #3

Test Average Units Units Other Description Test Method Used Test Location Note

Select appropriate unit

from list. If other is

selected please describe

units in column H at right. Enter the name of the Test Method used. Indicate whether the test

occurred upstream or

downstream of a control

device(s); list the control

device(s) If kiln has an in-line raw mill,

indicate raw mill status during tests

(i.e., raw mill on or raw mill off).

Provide any other information

supporting information you think is

necessary about this test report.

Sample Date (mm/dd/yyyy) 3/12/2010 3/12/2010 3/12/2010

HCl Concentration - as measured - dry basis 30.2 26.9 33.5 ppmvd

Oxygen Concentration - dry basis 4.9 4.9 4.9 %

CO2 Concentration - dry basis 18.6 18.3 17.9 %

HCl Concentration - corrected to 7% oxygen 26.2 23.4 29.1 26.2 ppmvd @ 7% O2 USEPA Method 321 Downstream NA

Exhaust Stream %Moisture 26.4 25.2 24.7 % Samples collected in stack

Exhaust Flowrate 577,108 575,859 590,980 acfm breaching. See report text for details.

Exhaust Temperature 261,756 263,979 272,533 dscfm

Notes:

Oxygen measurements were conducted at two locations - in the stack

where the volumetric flow rate testing was conducted and in the

breaching, where the HCl testing was conducted. Oxygen data collected at the

breaching location were used to correct HCl data to 7% O2. See report text for

further details No Facilities that use Method 321 to test for HCl

Lafarge North America

Electrostatic Precipitators

Enter HCl concentration value in dry

parts per million volume (ppmvd). If

the test results are below detection

limit, please note the detection limit

in brackets

(e.g., [< 0.010]). Kiln 1

Enclosure 5c--ERT Spreadsheet Page 1 of 1

### SOURCE**EMISSION TEST** **REPORT**

# Main**Kiln Exhaust** **Source Emission** **Testing Lafarge** **Building Materials,** **Inc.**

## Ravena,**New York** **March 30,** **2010 filg** **QBRIENEJ GERE** **www.obg.com SOURCE** **EMISSION TEST** **REPORT 14198** **45892**

# Main**Kiln Exhaust** **Source Emission** **Testing Lafarge** **Building Materials,** **Inc. Ravena,** **New York** **PATRICK GRADY,** **PROJECT ASSOCIATE** **O'Brien Gere** **Engineers, Inc.** **DAVE OSTASZEWSKI,** **P.E., SENIOR** **MANAGING ENGINEER** **O'Brien Gere** **Engineers, Inc.** **360' Engineering** **and Project** **Delivery Solutions** **www.obg.com MAIN** **KILN EXHAUST** **SOURCE EMISSION** **TESTING**

## TABLE OF**CONTENTS Table** **of Contents** **List of** **Tables List** **of Appendices** **1. Introduction** **and Background** **1.1. Emissions** **Testing Program** **Participants**

### 2.**Source Description** **and Process** **Operating Data** **2.1. Process** **Description**

### 2.2.**Sampling Location** **Description 2.3.** **Operating Parameters** 

### 3.**Summary of** **Test Program** **3.1. Test** **Program Summary** 

### 4.**Sampling and** **Analytical Procedures** **4.1. Test** **Methods 4.2.** **Gas Velocity** **and Volumetric** **lrlow Rate** **4.3. Moisture** **Content**

### 4.4.**Oxygen and** **Carbon Dioxide** **Concentration 4.5.** **IICI Emissions** **5. Summary** **of Test** **Results 5.1.** **Test Results** **6. Quality** **Assurance/Quality Control** 

### 6.1.**Equipment Calibration** **6.2. Leak** **Checks**

### LIST**OF TABLES** **Summary of** **Source Emission** **Test Results** **LIST OF** **APPENDICES Facility** **Operating Data** **Schematic of the** **Test Location** **Reid Data** **and Calculations** **Equipment Calibration** **Data Enthalpy** **Analytical, Inc.** **Test Report** **FINAL: March** **30,1010 OBFHENSBERB** **IAurjrgt.U19314SS9;.Sour[C:-Eml!«or.\Oati\TM!Di>rli\Lalarje_final_Malri Kiln** **Static H[t_le>t.dooc** **^^^^ MAIN** **KILN EXHAUST** **SOURCE EMISSION** **TESTING 1.** **INTRODUCTION AND** **BACKGROUND O'Brien** **Cere was** **retained by** **I.afarge Building** **Materials, Inc.** **{Lafarge) to** **conduct source** **emission testing** **on the** **main kiln** **exhaust at** **the Lafarge** 

### facility**located in** **Ravena, New** **York. The** **objective of the** **test program** **was to satisfy** **the hydrogen** **chloride (IIC1)** **information Collection** **Request (ICR)** **issued by** **the United** **States Environmental** **Protection Agency** **(USEPA) on** **February 3,** **2010. Messrs.** **Brian Garrett** **and Mike** **Salvagno of** **O'Brien Gere** **and Mr.** **Clint Thrasher** **of Enthalpy** 

### Analytical,**Inc. performed** **the field** **test program.** **Mr. Paul** **Rappleyea was** **present to** **monitor process** **conditions and** **collect facility** **data. The** **remaining sections of** **this report** **include**

### summary**of the** **source test** **program, process** **description, sampling** **methods used,** **QA/QC procedures** **followed for** **the testing** **equipment, and** **summary of the** **test results.** **1.1. EMISSIONS** **TESTING PROGRAM** **PARTICIPANTS Facility** **Source Testing** **Companies Name:** **Address: Contact:** **O'Brien Gere** **5000 Brittonfield** **Parkway East** **Syracuse, New** **York 13057** **David Ostaszewski** **Telephone number:** **(315) 437-6100** **Name: Address:** **Contact: Telephone** **number: Enthalpy** **Analytical, Inc.** **2202 Ellis** **Road Durham,** **North Carolina** **27703 Bryan** **Tyler (919)850-4392** **Name: Inc.** **Site Address:** **Contact: Telephone** **number: Lafarge** **Building 1916** **Route 9W** **Ravena, NY** **12143 Paul** **Rappleyca (5181756-5028** **FINAL: March** **30, 2010** **I: J Fa rg** **4198\4Sfl 92.Sc** **e- Eni** **Is si Dn\Do** **ARepoitiUaf orge_f** **rca LMo!** **ri Ki)n** **Slaclt HCI_I** **e*I.doiit****www.obg.com MAIN** **KILN EXHAUST** **SOURCE EMISSION** **TESTING 2.** **SOURCE DESCRIPTION** **AND PROCESS** **OPERATING DATA** **This section** **provides description** **of the** **Portland Cement** **kilns tested,** **as well as** **operating requirements** **and parameters** **maintained during** **testing. 2.1.** **PROCESS DESCRIPTION** **The Lafarge** **Ravena Facility** **is dedicated** **For portland** **cement manufacturing** **and sales.** **Lafarge operates** **two rotary** **kilns capable** **of firing** **coal and** 

### petroleum**coke. Both** **kilns are** **exhausted into** **an electrostatic** **precipitator for** **participate emissions** **control before** **being exhausted** **through common** 

### stack**to the** **atmosphere. 2.2.** **SAMPLING LOCATION** **DESCRIPTION**

### The**kilns exhaust** **to atmosphere** **through common** **circular stack** **approximately 260** **indies in** **diameter. Two** **test ports,** **spaced 180° apart** **are located** **122 feet** **[approximately 5.6** **duct diameters)** 

### downstream**of the nearest** **flow disturbance** **and 186** **feet (approximately** **8.6 duct** **diameters) upstream** **of the** **stack exhaust** **point. These** **ports were** **used to** **conduct the** **volumetric flow** **rate**

### monitoring.**The HC1** **monitoring was** **not conducted** **at this** **location due** **to the** **length of** **sample line** **required to** **access this** **location. The** **long sample** **line length resulted** **in difficulty** **achieving method** **sample recovery** **QA criteria.** **Therefore, HCl** 

### sampling**was conducted** **in dedicated** **breaching to** **the kiln** **exhaust stack.** **Schematics of** **test locations** 

### are**presented in** **Appendix B.** **2.3. OPERATING** **PARAMETERS The** **testing was** **conducted while** **one kiln** **was**

### online**firing mixture** **of coal** **and petroleum** **coke and** **operated at** **greater than** **90 percent** **toad. Kiln** **operations data** **was collected** **by facility** **personnel.**

### These**data included** **clinker production** **rate, slurry** **feed rate** **[liter/min), and** **fuel feed** **rate (ton/hr).** **These facility** **process data** **are presented** **in Appendix** **of this test** **report FINAL;** **March 30,** **2010 l:\Uljrge.l4198\4539Z.** **du rce-** **Im Isilo** **n\0 oci\Repor!** **s\t-J1J rge_f** **nal^Ma Fn** **K11 Slat** **C!_le« .do** **OBRIENEQERE www.obg.eom** **MAIN KILN** **EXHAUST SOURCE** **EMISSION TESTING** **3. SUMMARY** **OF TEST** **PROGRAM This** **section provides** **summary of** **the testing** **scope of** **work conducted** **on the-** **main kiln** **exhaust**

### at**the Lafarge** **facility. 3.1.** **TEST PROGRAM** **SUMMARY Source** **emission testing** **was conducted** **to evaluate** **emissions of** **HC1 from** **the main** **kiln exhaust** **located at** **the Lafarge** **facility. Testing** **was completed** **on**

### March**12, 2010** **by O'Brien** **Gere (volumetric** **flow rate** **measurements) and** **Enthalpy Analytical,** **Inc. (HCI** **FTIR monitoring)** **personnel. Testing** **was conducted** **in triplicate** **during normal** **process operating** **conditions as** **maintained by** **facility personnel.** **Test durations** **were 60** **minutes. As** **previously mentioned** **in Section** **2.3, one** **of the two** **kilns was** **online during** **the test** **program. The** **kiln fired** **mixture of** **coal and** **petroleum coke** 

### during**the testing** **and was** **operated at** **greater than** **90 percent** **capacity.**

### As**previously noted,** **HCI testing** **could not** **be completed** **at the** **stack location** **due to** **the length** **of sample** **line required** **to transport** **the sample** **from the** **test port** **on the** **platform to** **the FTIR** 

### instrument.**The extended** **sample line** **length made** **it difficult** **to consistently** **meet method** **spike sample** **recovery criteria.** **Therefore, it** **was decided** 

### on-site**to obtain** **liCl samples** **in the** **dedicated breaching** **to the** **kiln stack** **which could** **be reached** **with much** **shorter sample** **line. To** **evaluate potential** **pollutant stratification** **at this** **location, an** **oxygen stratification** **check was** **conducted across** 

### the**ductwork. The** **results of** **this check** **indicated that** **there was** **no significant** **stratification in** **the ductwork** **and the** **location was** **acceptable for** **HCI sampling.** **Note that** **oxygen data** **collected at** **this location** **were used** **to correct** **HCI concentrations** **to**

### O2.**Results of** **this testing** **can be** **found in** **Appendix C.** **FINAL: March** **30, 2010** **l:\lafaije .14198\4bS9iiojTte-£miiilon\Cim\B** **Epo m\Lala.ie_Final_Ma** **In Kiln** **Sfstk HCI Jr.!.** **dot. QBIIIENDGERE** **www.obg.com MAIN** **KILN EXHAUST** **SOURCE EMISSION** **TESTING 4.** **SAMPLING AND** **ANALYTICAL PROCEDURES** **This section** **provides description** **of the** **test**

### methods**Utilized during** **the RATA** **program. 4.1.** **TEST METHODS** **Emissions testing** **was conducted** **using USEPA** **Reference Methods** **(RM) described** **in Title** **40 CFR** **Part 60,** **Appendix A.** **RM 1:** **Sample and** **velocity traverses** **for stationary** **sources**

### RM**2: Determination** **of stack gas** **velocity and** **volumetric flow** **rate (Type-S** **pitot tube)** **RM 3/3A:** **Determination of** **oxygen and** **carbon dioxide** **concentrations in** 

### emissions**from stationary** **sources RM** **4: Determination** **of moisture** **content in** **stack gases** **RM 321:** **Determination of** **HCI emissions** **from stationary** **sources FT1R** **Analyzer Procedure** **4.2. GAS** **VELOCITY AND** **VOLUMETRIC FLOW** **RATE The** **gas velocity** **was determined** **using velocity** **pressure data** **measured using** **stainless steel** **Type-S pitot** **tube and** **manometer across** **the diameter** **of the ductwork.** **The gas** **stream temperature** **was monitored** **using Type** **thermocouple attached** **to the** **pitot tube. Note** **that there** **are only** **two test** **ports located** **180 degrees** 

### apart**in the** **same plane** **available for** **reference method** **sampling on** **the stack platform. Therefore,** **velocity and** **temperature traverses** **were taken** **across the** **duct in** **two directions,** **using the** **existing**

### ports.**Note that** **this port** **layout and** **volumetric flow** **rate procedure** **has been approved** **by New** **York State** **Department of** **Environmental Conservation** **(NYSDEC) in** **the past for** **previous compliance** **test programs.** **USEPA RMs and** **were followed** **to**

### establish**the equal** **areas to** **be measured** **in identifying** **the gas** **velocity and** **volumetric flow** **rate. 4.3.** **MOISTURE CONTENT** **Moisture content** **was quantified** **utilizing procedures** **identified in** **USEPA RM** **4. sample** **of gas** **was continuously** **collected using** **dry gas** 

### meter**stack sampling** **system condensed** **in series** **of impingers.** **The moisture** **content of** **the gas was** **measured as** **change in** **the volume** **of the** **water collected** **in each** **impinger solution** **and the** 

### increased**weight of** **the desiccant** **during the** **sampling period.** **4.4. OXYGEN** **AND CARBON** **DIOXIDE CONCENTRATION** **Oxygen concentrations** **at the** **HCI sample** **location in** **the stack breaching** **were determined** **in accordance** 

### with**USEPA RM** **3A using** **California Analytical** **Instruments Model** **600 paramagnetic** **analyzer. continuous** **gas sample** **was extracted** **from the** 

### exhaust**stack through** **sintered filter,** **stainless steel** **probe, heated** **Teflon line** **and through** **conditioning system** **used to** **remove moisture** **from the** **gas stream.** **All material** **that came** **in contact** 

### with**the sample** **was constructed** **of either** **stainless steel,** **glass, or** **Teflon. The** **reference method** **analyzer outputs** **were**

### monitored**using laptop** **computer and** **PCMCIA card** **and recorded** **by data** **acquisition system** **[DAS). The** **DAS reported** **oxygen data** **as 1-minute** 

### averages**for each** **test run.** **Oxygen emissions** **data reported** **by the** **DAS was** **corrected for** **system zero** 

### and**span bias.** **Oxygen and** **carbon dioxide** **concentrations at** **the stack location** **were determined** **in conjunction** **with each test** **run in** **accordance with** **USEPA RM** **procedures using** **an Orsat** **apparatus. 4.5.** **HCL EMISSIONS**

### Concentrations**of HCI** **were evaluated** **in accordance** **with USEPA** **RM 321** **procedures using** **an on-site** 

### FTIR**analyzer. Sample** **gas was** **extracted through** **probe assembly** **and heat-traced** **line, through** 

### sample**gas dryer,** **and into** **the absorption** **cell of the** **FTIR spectrometer.** **The heat** **traced line** **was**

### maintained**at approximately** **375Deg. F.** **The FTIR** **instrument was** **MIDAC (Series** **1-1301) medium** **resolution Michelson** **interferometer spectrometer.** 

### Further**details of the** **FTIR sampling** **and analytical** **instrumentation can** **be found** **in Appendix** **E. FINAL.** **March 3D,** **2010 www.obg.iom** **MAIN KILN** **EXHAUST SOURCE** **EMISSION TESTING** **5. SUMMARY** **OF TEST** **RESULTS summary** **of the test** **results can** **be found** **in Table** **1. Supporting** **field data** **and calculations** **can be** **found in** **Appendix C.** **FTIR HC1** **analytical results** **can be** **found in** **Appendix E.** **brief discussion** **of the**

### test**results is** **presented below.** **5.1. TEST** **RESULTS review** **of Table** **indicates that** **IICI concentrations** **on wet** **basis ranged** **from approximately** **20.1 ppm** **to approximately** **25.2 ppm,** **averaging approximately** **22.5 ppm.** **11 Cl** **concentrations corrected** **to 7%** **percent oxygen** 

### ranged**from approximately** **23.4 to** **approximately 29.1** **ppm, averaging** **approximately 26.2** **ppm.**

### lixcept**as noted, there** **were no** **operational or** **testing problems** **that impacted** **the test** **results and** 

### all**test data** **is believed** **to be** **representative of** **the emissions** **encountered during** **the test** **program. FINAL-** **March 30,** **2010 l:\lorjrEt.iai9B\45a9:.Soiirte-Enilssion\[;oci\B!Borls\Li'jr6e_[injLMaiii** **Kiln Stalk** **www.obg.com MAIN** **KILN EXHAUST** **SOURCE EMISSION** **TESTING**

### 6.**QUALITY ASSURANCE/QUALITY** **CONTROL QA/QC** **were based** **OB the** **recommended QA/QC** **procedures of the** **various sampling** **and analytical** **methods that** **were used** **for the** **source test** **program. This** **section summarizes** **the pertinent** **QA/QC procedures** **that were** **employed during** **the emissions** **testing program.** **Field equipment** 

### calibration**data can** **be found in** **Appendix and** **in the** **Enthalpy Analytical** **Report located** **in Appendix** **E. 6.1.** **EQUIPMENT CALIBRATION** 

### Analyzers,**dry gas meters,** **thermocouples, and** **pitot tubes** **were calibrated** **in accordance** **with the** 

### procedures**outlined in** **the corresponding** **USEPA test** **methods and/or** **the USEPA** **document entitled** **Quality Assurance** **Handbook for** **Air Pollution** **Measurement Systems:** **Volume HI** **Stationary Source** **Specific Methods** **(EPA 600/R-94/038c).** **Continuous emission** **monitoring analyzer** **response time** **tests were** **conducted Oil** **each analyzer** **and the** **entire measurement** **system, as** **applicable. Each** 

### analyzer**and the** **entire instrument** **measurement system** **were challenged** **with EPA** **Protocol No.** **gas**

### standards**(zero and** **mid gas)** **in accordance** **with procedures** **specified in** **each respective** **test method.** **The calibration** **gases were** **introduced to** **the sampling** **system at** **the sample** **probe to** **expose the** **calibration standards** **to as** **much of** **the sampling** **system as** **possible. O2** **concentrations were** **bias corrected** **in accordance** **with USEPA** **RM 7E** **procedures.**

### Protocol**calibration standards** **were prepared** **in accordance** **with USEPA** **Traceahility Protocol** **for Assay** **and Certification** **of Gaseous** **Calibration Standards.** **The accuracy** **of these gases** **were +/-2%** 

### or**better. For** **those concentrations** **that exceed** **the concentration** **range for** **commercially available** **EPA Protocol** **standards, the** **highest analytical** **grade**

### commercially**available (i.e.** **master blend)** **standards were** **used. Copies** **of the** **calibration**

### certificates**are included** **in Appendix** **of this** **final source** **test report.** **6.2. LEAK** **CHECKS Pitot** **tube leak** **checks were** **conducted in** 

### accordance**with USEPA** **RM 2.** **Leak checks** **were conducted** **on the** **moisture sampling** **trains prior** **to and** **following each** **test run** **in accordance** **with USEPA** **RM 4.** **FINAL: March** **30,1010 l:\L3iaiec.l419E\453W.Soijric-Eriifciran\DD.i\Reporls\ljHarie_Flnsl_Nlaln** **Kiln Slstfc** **HCIJeit.iJoi. □BniENEQEUE** **wwvr.obg.com 360°** **Engineering and** **Project Delivery** **Solutions**

### Table**Summary of** **Source Testing** **Results Main** **Kiln Exhaust** 

### Lafarge**Ravena Plant** **Ravena, New** **York Run** **Identification Run** **Kun Run** **Average**

### Run**Date Start/Stop** **Time 3/12/10** **3/12/10 3/12/10** **1036-1136 1201-1301** **1403-1503 Exhaust** **Gas Conditions** **Temperature (deg.** **F)**

### Moisture**(volume %)** **Oxygen (dry** **volume %)** **Carbon Dioxide** **(dry volume** **%) Volumetric** **Flow Rale** **acfm dscfm** 

### HC1**Concentrations ppm.** **wet**

### ppm,**dry basis** **@7% O2** **396.0**

### 26.4**10.4**

### 18.6**577,110 261,760** **22.2 26.2** **401.2 25.2** 

### 10.3**18.3 575,860** **263,980 20.1** 

### 23.4**401.8 24.7** **10.4**

### 17.9**590,980 272,530** **25.2 399.7** 

### 25.4**10.4 18.3** **581,317 266,090** 

### 22.5**29.1 26.2** 

### OBniEN**GERE www.obg.com** **O'BrienS Gere** **APPENDIX FACILITY** **OPERATING DATA** **360c Engineering** **and Project Delivery** **Solutions vrww-obg.com** 

### Lafarge**Building Materials** **Ravena NY** 

### HCI**Emission Test** **31210 Run1** **Date [Y/M/D)** **10/3/12**

### 10/3/12**10/3/12 10/3/12** 

### 10/3/12**10/3/12**

### 10/3/12**10/3/12 10/3/12** **10/3/12**

### 10/3/12**10/3/12**

### 10/3/12**10/3/12**

### 10/3/12**10/3/12 10/3/12** 

### 10/3/12**10/3/12 10/3/12** 

### 10/3/12**10/3/12 10/3/12** **10/3/12 10/3/12** **10/3/12 10/3/12** 

### 10/3/12**10/3/12**

### 10/3/12**10/3/12 10/3/12** **10/3/12**

### 10/3/12**10/3/12**

### 10/3/12**10/3/12**

### 10/3/12**10/3/12 10/3/12** **10/3/12**

### 10/3/12**10/3/12**

### 10/3/12**Time 10:36:00** 

### 10:37:00**10:38:00**

### 10:39:00**10:40:00 10:41:00** 

### 10:42:00**10:43:00 10:44:00** 

### 10:45:00**10:46:00**

### 10:47:00**10:48:00 10:49:00** 

### 10:50:00**10:51:00 10:52:00** **10:53:00 10:54:00** 

### 10:55:00

### 10:56:00**10:57:00 10:58:00** 

### 10:59:00**11:00:00 11:01:00** **11:02:00**

### 11:03:00**11:04:00 11:05:00** **11:06:00 11:07:00** **11:08:00 11:09:00** **11:10:00**

### 11:11:00**11:12:00 11:13:00** 

### 11:14:00**11:15:00 11:16:00** 

### 11:17:00**11:18:00**

### 11:19:00

### Flow**mmscfh 27.177** 

### 27.350**27.343 27.082** **26.710 26.528** **26.498 26.828** **27.051 26.715** **26.802**

### 26.797**26.787 27.201** **26.643 26.172** **26.501 27.340** **26.709**

### 26.304**26.627 27.181** **27.076 26.536** **26.043 25.940** 

### 26.368

### 26.746**26.984 27.288** **27.161 28.192** 

### 27.081**26.747 26.585** 

### 28.003**27.676 27.365** **26.893**

### 26.899**27.035**

### 27.031**27.199**

### 27.267**O2% 8.99** 

### 9.04**8.95**

### 9.02

### 9.14**9.15**

### 9.18**9.16 9.19** **9.20 9.26** **9.34**

### 9.40**10.57 12.25** 

### 10.58**9.99**

### 9.84

### 9.64**9.48**

### 9.45**9.45 9.46** **9.26 9.23** **9.17**

### 9.26**9.32**

### 9.37**9.30 9.14** **9.33**

### 9.33**9.33 9.23** **9.23 9.37** 

### 9.44

### 9.38**9.36**

### 9.22**9.26 9.21** **9.23**

### Temperature,**400.7**

### 400.4**400.0 399.7** **400.2**

### 400.6

### 400.5**401.1 402.0** **403.0**

### 403.5**404.1**

### 404.1**414.5 412.8** **407.9**

### 407.2

### 405.3**404.7 404.4** 

### 404.0

### 403.1**402.5 402.2** 

### 401.6**400.7 400.5** 

### 400.9**401.7**

### 402.2**402.2**

### 403.6**404.0 403.6** **402.8 403.2** **403.6**

### 405.1**405.4**

### 405.7**404.9 404.0** 

### 404.1**404.7**

### Clinker**production Rate,** **101.6**

### 101.6**101.6**

### 101.6**101.7**

### 101.7**101.7 101.7** **101.7**

### 101.7**101.7**

### 101.7**101.7 101.7** 

### 101.8**101.8**

### 101.8**101.8 101.8** **101.8**

### 101.8**101.8 101.8** 

### 101.8**101.9**

### 101.9

### 101.9**101.9**

### 101.9**101.9 101.9** **101.9**

### 101.9

### 101.9**102.0**

### 102.0**102.0 102.0** 

### 102.0**102.0**

### 102.0**102.0 102.0** 

### 102.0

### Slurry**Feed Liter/Minute** **2,300**

### 2,300**2,300**

### 2,300**2.300**

### 2,300**2,300 2,300** **2,300 2,300** **2,300**

### 2,300

### 2,300**2,300 2,300** **2,300 2,300** 

### 2,300

### 2,300**2,300**

### 2,300**2,300**

### 2,300**2,300 2,300** **2,300**

### 2,300**2,300 2,300** 

### 2,300**2,300 2,300** 

### 2,300

### 2,300**2,300**

### 2,300

### 2,300**2,300 2,300** **2,300 2,300** **2,300**

### 2,300**2,300 Fuel** **Feed Rate,** 

### Tonne/hour**21.3**

### 21.3**21.3**

### 21.4**21.3**

### 21.3**21.3 21.3** **21.3 21.3** 

### 21.3**21.3**

### 21.3**21.3 21.3** **21.3 21.3** **21.2**

### 21.4**21.4 21.4** 

### 21.4

### 21.4**21.4**

### 21.4**21.4**

### 21.6

### 21.0**21.2**

### 21.4**21.4**

### 21.3**21.6 21.7** **21.5 21.4** 

### 21.4**21.4 21.4** 

### 21.4**21.4**

### 20.7**20.4 20.4** 

### 10/3/12**10/3/12**

### 10/3/12**10/3/12**

### 10/3/12

### 10/3/12**10/3/12**

### 10/3/12**10/3/12**

### 10/3/12**10/3/12 10/3/12** **10/3/12 10/3/12** **10/3/12**

### 10/3/12**10/3/12 11:20:00** 

### 11:21:00**11:22:00 11:23:00** 

### 11:24:00**11:25:00 11:26:00** **11:27:00 11:28:00** 

### 11:29:00

### 11:30:00**11:31:00**

### 11:32:00

### 11:33:00**11:34:00 11:35:00** **11:36:00 Averages** **26.577 26.312** 

### 27.033**27.471 27.147** **27.044**

### 27.518**27.320 27.224** 

### 26.949**26.752 26.497** **26.289**

### 26.931**26.709**

### 26.534**26.998 26.914** 

### 9.19**9.30 9.16** **9.15 9.30** **9.31 9.25** **9.28 9.23** 

### 9.27**9.35**

### 9.35**9.17 9.27** 

### 9.27**9.36 9.34** **9.381**

### 404.6**404.3**

### 404.0**403.4**

### 403.2**403.2**

### 403.9**404.6 404.5** 

### 404.2

### 404.4**404.4 403.6** **403.2**

### 403.8**405.2**

### 405.9**403.659**

### 102.1**102.1 102.1** **102.1**

### 102.1**102.1 102.1** **102.1 102.1** 

### 102.1**102.2**

### 102.2**102.2 102.2** **102.2 102.2** 

### 2,300**2,300**

### 2,300**2,300**

### 2,300**2,300 2,300** **2,300 2,300** 

### 2,300**2,300**

### 2,300**2,300 2,300** **2,300**

### 2,300**20.7**

### 20.8**20.8**

### 21.0

### 21.3**21.3 21.3** **21.3 21.3** 

### 21.3**21.3 21.6** **21.4 21.5** **21.7**

### 21.5

### All**data polled at** **10 second** **intervals, reported** **as 60** **second averages** **fuel 90%** **coal, 10%** **coke**

### Lafarge**Building (Materials** **Ravona NY** **HCI Emission** **Test 31210** **Run**

### Date**(Y/M/D) 10/3/12** 

### 10/3/12

### 10/3/12**10/3/12 10/3/12** **10/3/12**

### 10/3/12**10/3/12**

### 10/3/12**10/3/12 10/3/12** **10/3/12 10/3/12** 

### 10/3/12**10/3/12**

### 10/3/12**10/3/12 10/3/12** **10/3/12 10/3/12** **10/3/12 10/3/12** 

### 10/3/12**10/3/12 10/3/12** **10/3/12 10/3/12** **10/3/12**

### 10/3/12**10/3/12 10/3/12** **10/3/12**

### 10/3/12**10/3/12 10/3/12** 

### 10/3/12

### 10/3/12**10/3/12 10/3/12** **10/3/12 10/3/12** **10/3/12 10/3/12** 

### 10/3/12

### Time**12:01:00 12:02:00** 

### 12:03:00**12:04:00 12:05:00** 

### 12:06:00**12:07:00 12:08:00** 

### 12:09:00**12:10:00**

### 12:11:00**12:12:00 12:13:00** 

### 12:14:00**12:15:00**

### 12:16:00

### 12:17:00**12:18:00 12:19:00** **12:20:00 12:21:00** 

### 12:22:00**12:23:00 12:24:00** 

### 12:25:00

### 12:26:00**12:27:00 12:28:00** 

### 12:29:00**12:30:00**

### 12:31:00**12:32:00 12:33:00** **12:34:00 12:35:00** **12:36:00 12:37:00** **12:38:00**

### 12:39:00

### 12:40:00**12:41:00 12:42:00** **12:43:00**

### 12:44:00**Flow mmscfh** **27.171**

### 26.967**26.678**

### 26.644**27.049 26.981** 

### 26.367**26.578 26.989** **27.429**

### 27.880**27.122**

### 27.808**28.102 27.711** **27.349 27.140** **27.025**

### 27.142**27.447 27.642** 

### 27.492

### 27.485**28.300**

### 27.061**27.431 27.726** **27.899 27.979** **27.526**

### 27.190**27.037 26.887** **26.708 27.082** **27.235**

### 27.046**28.083**

### 27.980**27.705 27.477** 

### 27.365**27.552**

### 27.513**02% 9.28** **9.30**

### 9.23**9.28**

### 9.33**9.23**

### 9.20**9.10**

### 9.01**9.07**

### 9.06**9.11 9.04** 

### 9.04**9.14**

### 9.12**9.06**

### 9.09**9.18 9.02** **8.94 8.99** 

### 9.07**9.03 9.04** **9.02**

### 9.10**8.99 9.16** **9.14**

### 9.18**9.31**

### 9.43**9.33 9.42** **9.25 9.21** **9.28**

### 9.25**9.26 9.17** **9.12 9.14** 

### 9.24**Temperature, 404.3** **405.1 404.7** **404.3**

### 404.2**403.6 403.1** **403.4**

### 403.5**404.9**

### 403.2**402.0 401.7** **402.0 402.5** 

### 403.2**404.2 405.6** **405.8**

### 404.9**400.7 400.9** 

### 401.4**402.8 402.4** **403.4**

### 405.0**406.0**

### 405.9**404.8 404.2** 

### 404.3

### 404.6**405.1 405.5** **405.3 405.7** **405.7**

### 406.0**405.6 404.7** 

### 403.3**402.8**

### 402.9**Clinker production** **Rate, 102.5** 

### 102.5**102.5 102.5** 

### 102.5**102.5 102.5** 

### 102.5**102.6**

### 102.6**102.6**

### 102.6**102.6 102.6** 

### 102.6**102.6 102.6** 

### 102.6**102.7 102.7** **102.7 102.7** **102.7 102.7** 

### 102.7**102.7 102.7** **1Q2.7**

### 102.7**102.7 102.8** 

### 102.8**102.8 102.8** **102.8 102.8** 

### 102.8

### 102.8**102.8**

### 102.8**102.8 102.8** **102.9 102.9** 

### Slurry**Feed Liter/Minute** **2,300**

### 2,300**2.300**

### 2,300**2,300 2,300** **2,300 2,300** 

### 2,300**2,300**

### 2,300**2,300 2,300** 

### 2,300**2,300**

### 2,300

### 2,300**2,300**

### 2,300**2,300 2,300** 

### 2,283

### 2,283**2,300**

### 2,300**2,300 2,300** **2,300**

### 2,300**2,300 2,300** 

### 2,300**2,300 2,300** **2,300**

### 2,300**2,300**

### 2,300**2,300 2,300** 

### 2,300**2,300 2,300** **2,300 Fuel** **Feed Rate,** **Tonne/hour 20.9** 

### 20.9**20.8 20.8** 

### 20.8**20.5 20.8** **20.8 20.5** 

### 20.4**20.5 20.6** **20.6 20.6** 

### 20.6**20.6 20.4** 

### 20.5**20.7 20.5** 

### 20.6**20.6 20.6** 

### 20.6**21.0 20.7** **20.4**

### 20.7**20.7**

### 20.5**20.8**

### 20.9**20.9**

### 20.9**20.6 20.3** 

### 20.2**20.5 20.5** 

### 20.8**20.8 20.9** 

### 20.6**20.6**

### 10/3/12**10/3/12 10/3/12** 

### 10/3/12**10/3/12**

### 10/3/12

### 10/3/12**10/3/12 10/3/12** **10/3/12**

### 10/3/12**10/3/12 10/3/12** 

### 10/3/12**10/3/12 10/3/12** **10/3/12**

### 12:45:00**12:46:00 12:47:00** **12:48:00**

### 12:49:00

### 12:50:00**12:51:00**

### 12:52:00**12:53:00**

### 12:54:00**12:55:00**

### 12:56.00**12:57:00 12:58:00** 

### 12:59:00

### 13:00:00**13:01:00 Averages** **27.202**

### 27.332**27.569**

### 27.345**27.329**

### 27.472**27.160 27.099** 

### 27.381**27.795**

### 28.086**27.873 27.665** 

### 27.636**27.638 27.452** **27.805**

### 27.390**9.25 9.31** **9.32 9.26** **9.43**

### 9.32**9.26**

### 9.33**9.28**

### 9.28**9.33 9.24** **9.22 9.41** 

### 9.51**9.42 9.42** 

### 9.206

### 403.5**405.4 406.3** **406.0 406.3** **406.6 406.3** **405.9**

### 405.6

### 405.0**405.0 404.9** **404.6 404.9** 

### 405.5**405.8**

### 405.6**404.402 102.9** 

### 102.9**102.9 102.9** 

### 102.9**102.9 102.9** **102.9 102.9** 

### 102.9**102.9 102.9** 

### 103.0**103.0 103.0** 

### 103.0

### 103.0

### 2,300**2,300 2,300** **2,300**

### 2,300**2,300 2,300** **2,300 2,300** 

### 2,300**2,300**

### 2,300**2,300 2,300** 

### 2,300**2,300 2,300** 

### 20.7**20.7 20.6** **20.5**

### 20.4**20.5**

### 20.7**21.0**

### 21.0

### 21.0

### 21.0**21.0 21.0** 

### 21.0**21.0**

### 21.0**20.9 All** **data polled** **at 10** **second intervals,** **reported as** **60 second** **averages**

### fuel**90% coal,** **10% coke** 

### Lafarga**Building Materials** **Ravena NY** **HCI Emission** **Test 31210** **Run**

### Date**[Y/M/D) 10/3/12** 

### 10/3/12**10/3/12 10/3/12** 

### 10/3/12**10/3/12 10/3/12** 

### 10/3/12**10/3/12 10/3/12** **10/3/12**

### 10/3/12**10/3/12 10/3/12** **10/3/12**

### 10/3/12**10/3/12 10/3/12** 

### 10/3/12**10/3/12**

### 10/3/12**10/3/12 10/3/12** **10/3/12**

### 10/3/12

### 10/3/12**10/3/12 10/3/12** **10/3/12 10/3/12** 

### 10/3/12**10/3/12 10/3/12** 

### 10/3/12**10/3/12 10/3/12** 

### 10/3/12**10/3/12**

### 10/3/12

### 10/3/12**10/3/12 10/3/12** **10/3/12 10/3/12** 

### Time**14:03:00**

### 14:04:00

### 14:05:00**14:06:00 14:07:00** 

### 14:08:00**14:09:00 14:10:00** 

### 14:11:00

### 14:12:00**14:13:00 14:14:00** **14:15:00**

### 14:16:00**14:17:00**

### 14:18:00

### 14:19:00**14:20:00 14:21:00** **14:22:00 14:23:00** 

### 14:24:00

### 14:25:00**14:26:00 14:27:00** 

### 14:28:00

### 14:29:00**14:30:00 14:31:00** **14:32:00**

### 14:33:00

### 14:34:00**14:35:00 14:36:00** 

### 14:37:00**14:38:00 14:39:00** **14:40:00 14:41:00** 

### 14:42:00**14:43:00 14:44:00** **14:45:00**

### 14:46:00**Flow mmscfh** **27.446**

### 27.796**27.904**

### 27.718**27.533 27.904** 

### 27.344

### 27.263

### 27.405**27.552**

### 27.837**27.935**

### 27.831**27.897 27.655** 

### 28.499**28.246**

### 27.397**27.122 27.243** **27.598 27.588** 

### 27.517**27.224**

### 26.930**26.952 27.374** 

### 27.740**27.691 27.400** 

### 27.626

### 27.338**27.406**

### 27.590

### 28.040**28.163 28.103** **28.253 28.127** 

### 27.868**27.887 27.750** **27.590 27.628** **02%**

### 9.18**9.28 9.31** 

### 9.35**9.30 9.21** 

### 9.31**9.27 9.31** **9.17**

### 9.28**9.32**

### 9.11**9.06 9.19** **9.56**

### 9.83**10.20 10.23** 

### 10.32**10.54 10.79** **10.65**

### 10.46

### 10.29**10.33 9.91** **9.91 9.99** 

### 10.12**10.32**

### 10.36

### 10.50**10.36**

### 10.23**10.38 10.39** 

### 9.97**9.58 9.33** 

### 9.07**8.98 9.09** **9.27**

### Temperature,**403.3 404.3** 

### 405.0**405.5**

### 405.7**405.4**

### 404.6**405.0 404.5** 

### 403.7

### 403.9**404.6 403.7** 

### 403.8**404.9**

### 406.9

### 407.1**407.5 407.6** **407.5 408.3** 

### 409.3**409.3**

### 408.0**407.8**

### 407.6

### 406.8**405.8**

### 406.3**406.7**

### 407.3**407.4**

### 407.8

### 407.9**406.9 406.5** **406.4 405.0** 

### 403.4

### 401.4**400.7**

### 400.6**400.6**

### 401.3**Clinker**

### production**Rate,**

### 103.3**103.3 103.3** 

### 103.3**103.4**

### 103.4**103.4**

### 103.4**103.4 103.4** 

### 103.4**103.4**

### 103.4**103.4**

### 103.4**103.4 103.4** 

### 103.4**103.4**

### 103.4**103.4 103.5** **103.5 103.5** 

### 103.5**103.5 103.5** 

### 103.5**103.5**

### 103.5**103.5**

### 103.5

### 103.5**103.5 103.5** **103.5**

### 103.6**103.6 103.6** **103.6 103.6** 

### 103.6**103.6 103.6** 

### Slurry**Feed Liter/Minute** **2,294**

### 2,294**2.294**

### 2,294

### 2,319**2,297**

### 2,297

### 2,297**2,297 2,297** 

### 2,297

### 2,297**2,297**

### 2,297**2,297**

### 2,297**2,297**

### 2,297**2,297 2,297** **2.297**

### 2,297

### 2,297**2,297 2,297** 

### 2,297**2,297**

### 2,297**2,297 2,297** **2.297**

### 2,297

### 2.297**2,297**

### 2,297**2,297 2,297** **2,297 2,297** **2.297 2,297** 

### 2,297**2,297 2,297** 

### Fuel**Feed Rate,** **Tonne/hour 20.9** 

### 20.8**20.8**

### 20.7**20.7 20.7** 

### 20.8**20.8 21.0** **20.8**

### 21.0**21.0 20.9** **21.0 21.2** 

### 21.2**21.2**

### 21.2

### 21.1**21.1 21.0** 

### 20.5

### 20.7**20.7 20.7** 

### 20.9**20.8 20.5** 

### 20.5**20.8 20.9** 

### 20.9**20.8 20.8** **20.8**

### 20.9**20.9 20.9** 

### 20.9**20.9**

### 20.9**20.9 20.9** **20.8**

### 10/3/12

### 10/3/12**10/3/12 10/3/12** 

### 10/3/12**10/3/12**

### 10/3/12**10/3/12**

### 10/3/12**10/3/12**

### 10/3/12**10/3/12 10/3/12** 

### 10/3/12**10/3/12 10/3/12** **10/3/12**

### 14:47:00**14:48:00**

### 14:49:00**14:50:00**

### 14:51:00**14:52:00 14:53:00** 

### 14:54:00**14:55:00**

### 14:56:00**14:57:00**

### 14:58:00**14:59:00 15:00:00** 

### 15:01:00**15:02:00 15:03:00** **27.474**

### 27.497**28.069 28.198** 

### 28.118**28.050 27.977** 

### 27.898

### 28.230**28.457 28.068** **27.400 27.297** 

### 28.248**29.157**

### 28.197**27.956 9.25** 

### 9.16**9.30 9.23** **9.13**

### 9.16**9.27 9.45** **9.38**

### 9.32**9.28**

### 9.15**9.16 9.02** **9.10 9.17** 

### 9.24**401.6 400.6** 

### 400.6**400.7**

### 400.0**400.5 400.9** **401.1**

### 401.0**400.8 399.6** 

### 398.6**398.6 398.6** 

### 400.4**400.1 398.8** **103.6 103.7** 

### 103.7**103.7**

### 103.7**103.7 103.7** **103.7**

### 103.7**103.7 103.8** **103.8**

### 103.8**103.8 103.8** **103.8 103.8** **2,297**

### 2,297**2,297**

### 2,297**2,297**

### 2,297**2,297 2,297** **2,297**

### 2,297**2,297 2,297** **2,297**

### 2,297**2,297**

### 2,297**2,297 20.7** 

### 20.6**20.6**

### 20.6**20.6**

### 20.5**20.4 20.4** 

### 20.1

### 20.3**20.3 20.3** 

### 20.3**20.0 20.2** **20.3 20.5** 

### Averages**27.757 9.613** **404.028 All** **data polled** **at 10** **second intervals,** **reported as** **60 second** **averages fuel** **90% coal,** **10% coke** **APPENDIX SCHEMATIC** **OF THE** **TEST LOCATION** **360*****Ehglnaartng ard** **Project Delivery Solutions** **www.obg.com r....** **Zli£±~ uwvrose** **point LOCMHtHS** **IBS' av-r** **/— KTOWM.** **8H0K y—** **punww 8ROCHNB** 

### LAFARQE**BUILDINC MATERIALS,** **Ino. EXHAUST** **STACK HWYOW** **APPENDIX FIELD** **DATA AND** **CALCULATIONS 360'** **Engineering and** **Project Delivery** **Solutions www.obg.com** **Parameter Run** **Date Start/Stop** **Time Duration** **of Run,** **Minutes Pitot** **Calibration Factor,** **CF Meter** **Gamma Motor** **Delta H,** **inches of** **H2O Stack** **Diameter, inches** **Rectangular Width,** **inches Rectangular** **Length, inches** **Stack Area,** **sq.ft. Barometric** **Pressure, inches** **of Hg** **Static Pressure,** **inches of** **H2O Drv Gas** **Mater Samnle** **Volume, VM1R3** **Initial Final** **Difference Avo.** **Stack Temperature,** **Ts(F) Ave.** **Meter Temperature,** **Tm(F) Ave.** **Run Delta** **H, inches** **of H2O** **Ave. Square** **Root of Delta** **Moisture Data** **Volume of** **water collected,** **mis Silica** **Gel, grama** **Total Collected,** **mis ORSATData** **%O2 %CO2** **%CO Calculations** **Vw(std). scf** **Vm(std), dscf** **Bws=" Md=** **Ms= Vs,** **ft/sec Qs,** **acfin Qs(std),** **dscfin**

### Test**Data Summary** **and LaFarge** **Inc**

### Kiln**Exhaust Ravena,** **NY Run!** **3/12/10 1036-1136** **60 0.84** **1.004 1.72** **260 30** **-1.2 767.311** **808.363 41.052** **396.0 73.3** **1.72 0.3584** **304 9.9** **313.9 10.4** **18.6 14.775** **41.092 0.264** **31.39 27.85** **26.1 577,108** **261,756**

### Calculations**Run2 Run3** **3/12/10 1201-1301** **60 0.84** **1.004 1.72** **260 30** **-1.2 3/12/10** **1403-1503 60** **0.84 1.004** **1.72 260** **30 -1.2** **808.578 847.634** **847.756 890.057** **39.056 42.301** **401.2 401.8** **77.0 78.4** **1.72 1.72** **0.3573 0.3667** **270 280** **12.4 278** **292.4 10.3** **18.3 10.4** **17.9 13.085** **13.763 38.818** **41.939 0.252** **0.247 31.34** **31.28 27.98** **28.00 26.0** **26.7 575.859** **590,980 263,979** **272,533 Where:** **Vw(std) volume** **of water** **vapor in** **gas,' standard** **conditions 0.04707** ***Vic Vm(std)** **vol. of** **gas sampled,** **standard conditions** **17.647 Vm** **gamma [Pb** **(dH/13.6)]/Tm(R) Bws =** **water vapor** **in gas** **stream, proportion** **by volume** **Vw(stdy( Vm(std)** **Vw(std)) Md** **molecular weight** **of stack** **gas, dry** **basis (0.44** **x%CO2) (0.32** **x%O2) [0.28** **(%N2 %CO)|** **Ms =** ***molecular weight** **of stack** **gas, wet** **basis [Md** **x(l-Bws)] (18.0** **xBwa) Vs** **stack gas** **velocity 85.49** **Cp (avg.** **Sq.Rt. dP)** **{Sq.Rt. (Ts(R)y(Ms** **Ps)] Qs** **stack gas** **flow rate** **VsxAsx60 Qs(std)** **stack gas** **flow rate,** **standard conditions** **Qjx (1-Bws)** **(528/(Ts(R)) (Ps/29.92)** 

### Field**Data Summary** **LaFarge Inc** **Kiln Exhaust** **Ravena, NY** **Travcnc Point** **Al Bl** **Average Start** **Temp(F) 403** **403 403** **404 404** **404 378** **372 404** **404 404** **403 402** **400 378** **370 3%** **Run! Delta** **0.15 0.15** **0.14 0.13** **0.13 0.11** **0.00 0.06** **0.16 0.16** **0.17 0.15** **0.14 0.13** **0.10 0.10** **0.13 Tm(F)** **In 69** **70 71** **72 74** **76 77** **78 79** **80 81** **81 76** **mil t>y** **69 69** **69 70** **70 71** **71 71** **73 74** **74 71** **SQRT Dollar** **0.3 B73** **0.3873 0.3742** **0.3606****0.3*506****0.3317 0.2828** **0.2R2B 0.4000** **0.4000 0.4123** **0.3873 0.3742** **0.3606 0.3162** **3162 o.ooon** **0.(1000 0.0000** **o.oooo 0,0000** **0.0000 0.0000** **0.0000 0.0000** **0.0000 0.0000** **0.0000 0.0000** **0.3584 Stuck** **Tcmp(F) 4Ob** **405 405** **404 400** **395 390** **385 405** **405 405** **405 405** **405 400** **400 401** **Run Delia** **0.16 0.16** **0.15 0.15** **0.14 0.12** **0.10 0.10** **0.16 0.16** **0.15 0.14** **0.12 0.10** **0.08 0.08** **0.13 Tn** **In**

### Ib**76 76** **78 80** **81 81** **82 82** **83 03** **84 out** 

### iM**74 74** **74 74** **74 74** **74 74** **74 74** **74 74** **SQRT Delia** **0.4000 0.4000** **0.3873 0.3873** **0.3742 0.3464** **0.3162 0.3162** **0.4000 0.4000** **0.3873 0.3742** **0.3464 0.3162** **0.2828 0.2828** **0.0000 0.0000** **0.0000 0.0000** **0.0000 0.0000** **0.0000 0.0000** **0.0000 0.0000** **0.0000 0.0000** **0.0000 0.3573** **Stach Temp(F)** **406 406** **405 406** **405 404** **394 394** **406 406** **404 403** **403 400** **395 392** **402 Rim3** **Delta 0.16** **0.16 0.15** **0.14 0.14** **0.13 0.08** **0.08 0,17** **0,17 0.16** **0.15 0.15** **0.14 0.10** **D.10 0.14** **TmflO In** **75 75** **75 77** **78 82** **83 B4** **85 85** **ae 86** **81 out** **l<\ 74** **74 75** **75 76** **76 76** **77 77** **7fl 78** **76 SQRT** **Dcll.P 0.401)1)** **0.4000 0.3873** **0,3742 0.3742** **0.3606 0.2828** **0.2828 0.4123** **0.4123 0.4000** **0.3873 0.3873** **0.3742 0.3162** **0.3162 0.0000** **0.0000 0.0000** **0.0000 0.0000** **0.0000 0.0000** **(t.OOOO 0.0000** **0.0000 0.0000** **0.0000 0.0000** **0.3667**

### OBRIENGGEFIE**Cllant Location** **Sourca**

### Orsat**Data Sheet** **Date Operator** **Barometrte ProMitro** **Ambient Tsmpiraturs** **Calibration Gas:** **02 C02** 

### IA.0**n.t Pro-Tost** **Calibration Trial** 

### Average**I1).? UU2+U2** **u2**

### n.t>**/JO 12.2.** **Trial**

## Average**CO2**

### if.r**)9.L. It.L** **UO2+U2 u2** 

### /P.¥

### /o.i**lO.i4 Trial** 

### Average**Trial**

### Average**CU2**

### a.**iffit**

### /g.H**(JO2**

### n.t**n.i /9.0** **UU2+O2 u2** **1/i.S**

### /0t¥**/A**

### uo2+02**u2 //>.S** 

### JDA

## /&4**Post-Teat Calibration** **Trial**

### Average**JA9 UO2+U2** **o2 JJL.I** **12.3 /A.I** **UKfUI****R*te«IK(K****20.9- %O2** **ftCO, Fuel** **Type F.** **Range Coal:** **Anchraclto and** **lignite . .** **1.016 1.130** **Dltuiulnoua 1.083** **1.230 Oii:** **Distillate 1.260** **1.413 Residual** **1.210 1.370** **Gas: Natural** **1.600 1.836** **Propane 1.434** **1.586 Butane** **1.405-1.553 Wood** **1.000 1.120** **Wood bark** **1.003 1.130** **Otuttf***

## APPENDIX**EQUIPMENT CALIBRATION** **DATA 360"** **Engineering and** **Project Delivery** **Solutions www.Dbg.CDin** 

# O'BRIEN**GERE**

# Analyzer**Response Time** **Pollutant 02** **Analyzer Serial** **No.**

# Date**lull P06050** 

### Time**Run**

### Run

### Run**Average Upscale** **Response**

# Hi**Hk HI** **Hx seconds** **seconds seconds** 

### seconds

### /7A**Analyzer I.D.** **CAI200 High** **Span Gas** 

### 21.22**Runl Run** **Run**

### Average**Downscale Response** **seconds seconds** **seconds seconds** 

### Pollutant**Analyzer Serial** **No. Date** **Time Run** **Run**

### Run

### Average**Upscale Response** **seconds seconds** **seconds seconds** 

### Analyzer**I.D. High** **Span Gas** **Run**

### Run

### Run**Average Downscale** **Response seconds** 

### seconds**seconds**

### seconds

# OBIilENGGERE

# Daily**Analyzer Calibration** **Plant I.D.** **Source I.D._** 

### Pollutant**Lafarge Inc** 

### Main**Kiln Stack** **O2**

### Analyzer**Serial No.** **Date 3/11/2010** **P060S0 Time** **NA**

### Project**No.**

### Personnel**Analyzer I.D.** 

### Span**Value Test** **Method B.Garrett** 

### CAI200**21 3A** 

### Zero**Gas Cylinder** **Value (ppm** **or %)** **0.0**

### Analyzer**Response (ppm** **or %)** 

### 0.01

### Calibration**Error**

### (%**of Span)** **+/-2% 0.0** **System**

### Response

### (ppm**or %)** 

### 0.06**System**

### Bias**(% of** **Span) +/-5%** **0.2 Cylinder** **ID**

### Low**Level Gas** **Cylinder ID** 

### Mid**Level Gas** **High Level** **Gas 12** **Cylinder ID** 

### 21.22**Cylinder ID** 

### 12.18**CCI29819**

### 21.14**CC834O**

### 0.9**-0.4 12.24** 

### NA

### 0.3**NA**

### Calibration**Error (Analyzer** **Response Cylinder** **Value) 100** **Span Value** **System Bias** **(System Response** **Analyzer Response)** **100**

### Span**Value**

## |sl**OBRIENGOERE «3=** ***ENGINEERS. INC** **Post-Test Sample** **Probe Calibration** **Fonn Probe** **ID P10-A** **Visual Inspection** **Do pftot** **Spa appear** **to be** **damaged? Do** **thermoeoupto wires** **appear broken** **or shorted?** **Do all** **components appear** **to be** **In good** **condition? Post-Test** **Thermocouple Calibration** **Referanoo Temperature** **°F 56.4** **_np_ .no** **Thermocouple Temperature** **°F 56.2** **RsfartrxaThsmoceusta Rita** **SM8J4S0OM trocar** **Olrferonoe'F •0.2** **Accapatable D«vla«on** **♦/- 2 °F** **Acceptable Unacceptable** **Date 03/16/10** **Technician MAS** **P10-A031810.xls**

## 1=1**OBRIENSQERE ENGINEERS** **INC Post-Test** **Sample Probe** **Calibration Form** **Probe ID** **P10-A Visual** **Inspection Do** **pilot tips** **appear to** **be damaged?** **Do Biermocouple** **wires appear** **broken or** **shorted? Do** **all components** **appear to** **be In** **good condiUon?** **Post-Test Thermocouple** **Calibration Reference** **Temperature °F** **66.4 RrtWor«TNs7noctt«iaFn^E«:9MSOOMl/4»4B«h)0«UnlJodSli** **no no** **Thermocouple Temperature** **°F 58.2** **KM rwJQOnal** **HliUlUW CT** **OUtnOanM Qnu** **(OCnmOuy Oltferonoe°F** **•0.2 Accepatable** **Deviation +/.** **°F Unacceptable** **Date 03/18/10** **Technician MAS** **P10-A031810jtb**

# 1PRAXAIR**Praxair Distribution** **Mid-Atlantic LLC** **US Shlmenvllle** **Road Bothtehom,** **PA 1801$** **Phono: 610.317.1608** **pox; 610.758.8384** **CutionurA Order** **Informations GTS** **WELCO WHSE** **FAIRLESS HI** **ONE STEEL** **RD MORRISVILLE** **PA 19067** **Oaamtr. >** *».•****t6WW Oanwr** **R&rfMf ,<Mn:** **VW4O4 Expiration** **Data: Cylinder** **Number. 9.23** **12.00 Balance** **Certified Concentration:** **8/21/2012 CC129819** **CARBON DIOXIDE** **OXYGEN NITROGEN** **Analytical Uncertainly:** **±1% ±1%** **8(17/1008 NICMO9E-A8** **NA AS** **HO 2000JW** **HOcuB. NA** **NA Certification** **Information: Certification** **Dale: 8/21/2009** **7. Oonot** **i» um** **ttindant*****pmwra li** **tnt Sun** **ISO P8B.** **(HOXVtMl (Of** **R«f«moc» Only)** **Term: 3-J** **Months Expiration** **Date: 8/21/2012** **01 Aiiafylteal** **Data: (fcRoferonco** **Standard, ZaZsm** **Gas, C°Oas** **Candktslo) I.** **Compootnt: CARBON** **KOXH»e RtqusilntConcaiWaGon-** **9% CaitfMConcontfMlont** **UU MullpeM** **Calltoctlon: N0N4SFBI6MIWRAHED** **e/13rtOO9 Zl** **R: 17.02** **fl: 17.02** **Z: Z:** **C: 182** **UOM:**

### 2.**Convonfnl: OxVoEN** **Roojwitatf ConoontraOon** **CatUnedConctntrotfecr one** **C: ft«** **Cone: t»** **C: aw** **Cone: 9.2J** **R: 17.02** **Cone: 923** **II*****II*****fiCM8430XnMTSE»)fl-lll PAMWONETK** **Utl MulUpoinl** **CtftttOoK****rh>IAnalyal*D*lti****Zl R!** **22.88 t:** **UOM: R:** **Xs C:** **23 12** **Ci C:** **R: 12.02** **12 22.08** **DMtl Conei** **Cm« Cons:** **Mt«n Tt«l** **Attiy: ta\nm** **12.02 12** **12 12** ***Analyzed by:** **Robin Morgan** **Rofoj«nc»StaKj«dTyp» CU3** **R«I.St<J****CylntfH*.****CCIM4M****R*f****8U. Com** **njn% flelSWTr«MlWtlo6RM#:** **2741 SteenilAnalinltOtla:** **Zi R:** **■UOM: R:** **2: C:** **C: C:** **Rl****Oat*:****Cone: Cones** **Cone: titan** **Tot Atttp** **0% RaCartnet** **Standard Typ«** **GUS****RtlSMCyMcr*:****CCtUtM RttSMCone** **7197% Rel.B(dT««aablat»8l»4#:** **Kit*****SicondAnafyalsOala: Zt** **Hi Hi** **Is Z:** **C: UOM:** **Certified by:_i.** **C: C:** **R: Oalt:** **Cone: Cone;** **Cone: MgenTaatAMey:** **0% Mm>l«ram^** **Th« »«l)rtlh** **wnoo»(inhjlihoi*bi»iro<OIS.W»teo.ho..art«lngou»eHhiiut»o(»»**

# 1PRAXAIR**Praxair Distribution** **Mid-Atlantic LLC** 

## U5**Shlmersvlllo Read** **firth/shorn, PA** **18015 Phone:** **610.317.1608 Fax:** **610.758.8384 CmtomtrA** **Otdtr Information:** **OBREIN&GERE OnfcrAtoeir;** **144266000 ChtsoauP.** **AViihr: 119748** 

### Certf/Ied**Concentration: PlttDau:** **2MB00S PtrtHmAu:** **EVNtCDOXE148AS WA** **AS 690** **20OOp«l 140** **MR NM** **Expiration Date:** **Cylinder Number** **3/9/2012 CC834C** **Analytical Uncertainty:** **17.8B CARBON** **DIOXIDE 21.22** **ft OXYGEN** **Balance NITROGEN** **±r HOxppm-** **WA**

## CertificationIitfimutloni'**CortlficatlonData: 2/W2009** **2DonoliaalN*sfinSifdirpr«Mural>lMtlMnieOP8<a.****(NOXValuufeiRtranfniOftly) r«m:** **36 Months BtprfWfon** **Date: 2/9O012** **PA<^ 01** **Analytical Data:** **(R'Reforence Standard.** **Z*Zem****Gas, C«Gaa** **Candldatg)**

### 1.**Ccmpowml: CARBCN** **DIOXIDE UK** **SIBkCN3UUIUkUTeESNSOMI2 Utf** **MuKptfit Criterion:** **Pint/ Z:** **HI Z:** **UOMi tally** ***ta l(Dal** **Ri Zl** **C; a:** **18.02 18** **1/1872009 Cs** **18 Cl** **19' R:** **16.02 Ottei** **Conn Cones** **Cone Mm** **Tilt Atuyt** **unm 17.8S** **17.85 17.85** **17.8SW 2.** **CcmpMMl: 0XV8EN** **Roquwud ConoMMllen:** **Coniliad Oone«nuaOoa:** **klMiumontUJKf: 11H** **21.M*****Lttl MifltooW** **CUbnSon PMUIMGHETK** **titonon FlratAnilyitoDilai** **fc fl:** **22.72 UOHi** **Ri 22.7Z** **Zi C:** **21 C:** **C: Ri** **21 21** **22.74 Oitaj** **Canei Cone:** **Conn: MnnTottAiMys** **worn 21.22** **21.23 21.22** **21.22 Analyzed** **by: Melissa** **Santana Rttwtno** ***Slanted Typa** **RtLStd.C|TntH«: IWL8M.C«nB** **CMS CCI0M77** **174»- 8i** **wad Anilyil** ***DtU; Zi** **As Z:** **UOMi ft** **R: Z:** **Cl C:** **C: R:** **D*l«:****Cone: Cams** **Cane; MimTntAitiy:** **OK RAnnot** **minted iyp«** **CUIS Rtl8M.CylMM#:** **Rtt 8(4.** **Cone 1UIX** **RrtSI4Tn«c«»a»to6RM»: H68t** **BuondAntlyilaOlM! Z:** **Rt Zi** **UOM: Ri** **Zi C:** **Cs C:<** **Ri Cent!** **Cong; Cone:** **MaanmiMityi 0%** 

## j/t.**tlfj.01 p0T8^^** **MHtowsbrttnUutlliiWonnifeniiicajnltutNnltMMttciaiatnaMkal**

### iMto**ht»»v«rtih»flth.ltti[tyofOT8.VVWool lno.,«rt«ln»pg)l»l** **APPENDIX ENTHALPY** **ANALYTICAL INC.** **REPORT 360'** **Engineering and** **Project Delivery** **Solutions □BillENEGEHE** **'.obg.com**

# O'Brien**Gere Engineers,** **Inc. 5000** **Brittonfield Parkway** **Syracuse, NY** **13221**

# LaFarge**Cement Kiln** **Exhaust Ravena,** **NY Project** **# 45692**

# Analytical**Report (0310-05)** **EPA Method** **321 Hydrogen** **Chloride**

# Enthalpy**Analytical, Inc.** **Phone: (919)** **850 4392** **Fax: (919)** **850 9012** **www.enthalpy.com 2202** **Ellis Road** **Durham, NC** **27703 5518** 

### certify**that to** **the best** **of my** **knowledge all** **analytical data** **presented in** **this report:** **Have been** **checked for** **completeness Are** **accurate, error-free,** **and legible** 

### Have**been conducted** **in accordance** **with approved** **protocol, and** **that all** **dev ialions** **and analytical** **problems are** **summarized in** **the appropriate** **narrative(s)**

### This**analytical report** **was prepared** **in Portable** **Document Format** **(.PDF) and** **contains 48** **pages. QA** **Review Performed** **by Valgena** **Respass EA#** **0310-05 Page** **of 48** 

# FTIR**Summary of** **Results EA#** **0310-05 Page** **of 48** 

### Company**Analyst Initials** **Parameters Samples** **O'Brien Gere** **CJT EPA** **Method 321** **Client Job#** 

### PO#**Report Date** 

### 45692-Kiln**Exhaust 0310-05** **Verbal 3/19/2010** 

### Compound-**Sample ID** **Concentration (ppmv** **wet) Hydrogen** **Chloride Run** **22.2 Kiln** **Exhaust Runs** **Run 20.1** **Run 25.2** **EA# 0310-05** **Page of** **48**

# FTIR**Results EA#** **0310-05 Page** **of 48** 

### Company**Analyst Initials** **Parameters Run1** **Run Run** **Run Run** **Run Run** **Run Run** **Run Run** **Run Run** **Run Run** **Run Run** **Run Run1** **Run Run** **Run Run** **Run Run** **Run Run** **Run Run** **Run1 Run** **Run Run** **Run Run** **Run Run** **Run Run** **Run Run** **Run Run** **Run ft** **Samples O'Brien** **Gere CJT** 

### EPA**Method 321** **Date**

### 3/12/2010**10:36 3/12/2010** **10:37 3/12/2010** **10:38**

### 3/12/2010**10:39 3/12/2010** **10:40 3/12/2010** **10:41 3/12/2010** **10:42**

### 3/12/2010**10:43 3/12/2010** **10:44 3/12/2010** **10:45**

### 3/12/2010**10:46 3/12/2010** **10:47 3/12/2010** **10:48 3/12/2010** **10:49**

### 3/12/2010**10:50**

### 3/12/2010**10:51 3/12/2010** **10:52**

### 3/12/2010**10:53 3/12/2010** **10:54 3/12/2010** **10:55 3/12/2010** **10:56 3/12/2010** **10:57**

### 3/12/2010**10:58 3/12/2010** **10:59 3/12/201011:00** **3/12/201011:01**

### 3/12/201011:02

### 3/12/201011:03**3/12/201011:04 3/12/201011:05** **3/12/201011:06 3/12/201011:07** **3/12/201011:08**

### 3/12/201011:09**3/12/201011:10 3/12/201011:11** 

### 3/12/201011:12**3/12/201011:13 3/12/2010** **11:14 3/12/2010** **11:15 3/12/201011:16** **3/12/201011:17**

### 3/12/201011:18**3/12/201011:19**

### Method**0310-05A 0310-05A** **0310-05A 0310-05A** **0310-05A 0310-05A** **0310-05A 0310-05A** **0310-05A 0310-05A** **0310-05A 0310-05A** **0310-05A 0310-05A** **0310-05A 0310-05A** **0310-05A 0310-05A** **0310-05A 0310-05A** **0310-05A 0310-05A** **0310-05A 0310-05A** **0310-05A 0310-05A** **0310-05A 0310-05A** **0310-05A 0310-05A** **0310-05A 0310-05A** **0310-05A 0310-05A** **0310-05A 0310-05A** **0310-05A 0310-05** **0310-05A 0310-05A** **0310-05A 0310-05A** **0310-05A 0310-05A** **Client Job** *

### PO#**Report Date** **Filename 45692-** **0310-05 Verbal** **Klfn Exhaust** **3/19/2010 Hydrogen** **Chloride DF** **10 03** **12 1036** **02 958** **10 03 12** **1037 02** **893 10** **03 12** **1038 04** **688 10_03_12_1039_04** **624 10** **03 12** **1040 06** **482 10 03** **12 1041** **06 418** **10_03_12_1042 08_213** **10_03_12 1043 08** **133 10** **03 12** **1044 10 053** **10_03_12_1045_09_973 10** **03 12** **1046 11** **769 10** **03 12** **1047 11** **704 10** **03 12** **1048 13** **562 10_03_12_1049_13_49«** **10_03_12_1050_15_292**

## 10**03~12 1051~15~21J** **10 03** **12 1052** **16 94C** **10 03** **12 1053** **16_851 10_03_12_1054** **18 646** **10_03 12** **1055 18** **566 10_03_12** **1056 20** **29S 10 03** **12 1057** **20 234** **10_03_12_1058_21_967 10 03** **12 1059** **21 903** 

## 10_03J2~1100**23 636** **10_03 12** **1101 23_556** **10 03** **12 1102** **25 351** **10 03** **12 1103** **25 25S** **10 03** **12 1104** **27J76 10 03** **12 1105** **27 080** **10 03** **12 1106** **28 875** **10 03 12** **1107 28 796** **10 03 12** **1108 30** **528 10 03 12** **1109 30** **464 10** **03 12** **1110 32** **197 10_03_12_1111** **32J33 10_03_12_1112_33_865** **10 03** **12 1113** **33 801** **10_03_12 1114** **35_534 10** **03 12** **1115 35 454** **10_03_12_1116_37_437 10** **03 12** **1117 37** **357**

## 10~03**12 1118 39~089** **10 03** **12 1119** **39 025** **(ppm) 17.3** **15.1 13.9** **13.7 15.7** **17.1 18.5** **20.1 21.4** **22.4 23.9** **18.9 14.9** **18.8 22.3** **25.5 26.4** **27.0 27.5** **28.1 28.7** **24.6 25.3** **20.4 20.9** **24.8 25.9** **24.3 19.9** **19.6 23.3** **25.0 24.7** **23.7 24.8** **24.9 25.3** **26.2 21.1** **21.5 18.6** **17.3 17.2** **21.3 SEC** 

### (ppm)**0.507 0.476** **0.453 0.451** **0.478 0.491** **0.508 0.533** **0.549 0.557** **0.587 0.491** **0.437 0.498** **0.561 0.615** **0.637 0.646** **0.660 0.667** **0.671 0.603** **0.609 0.521** **0.530 0.602** **0.617 0.589** **0.518 0.517** **0.576 0.604** **0.597 0.575** **0.598 0.603** **0.615 0.625** **0.539 0.536** **0.489 0.476** **0.461 0.525** **EA# 0310-05** **Page of** **48 Company** **Analyst Initials** 

### Parameters**Run1 Run** **Run Run** **Run Run** **Run Run** **Run Run** **Run Run** **Run Run** **Run Run** **Samples O'Brien** **Gere CJT** **EPA Method** **321 Date** 

### 3/12/201011:20**3/12/201011:21 3/12/201011:22** 

### 3/12/201011:23**3/12/2010 11:24** **3/12/201011:25 3/12/201011:26** **3/12/201011:27 3/12/2010** **11:28**

### 3/12/201011:29**3/12/201011:30 3/12/201011:31** **3/12/201011:32 3/12/201011:33** 

### 3/12/201011:34**3/12/201011:35**

### Method**0310-05A 0310-05A** **0310-05A 0310-05A** **0310-05A 0310-05A** **0310-05A 0310-05A** **0310-05A 0310-05A** **0310-05 0310-05** **0310-05 0310-05** **0310-05A 0310-05A** **10 Client** **#4 Job#0** **PO#V Report** **Date 3i** **Filename 03 12** **1120 40** **945 10 03** **12 1121** **41 600** **10 03** **12 1122** **41 505** **10 03** **12 1123** **43 300** **10 10** **93 12 1124** **43 220** **03 12** **1125 44** **953 10** **03 12** **1126 44** **889 10** **10 10** 

### 10_**10 10** **10 10** **10 03** **12 1127** **44 824** **D3 12** **1128_46_620 03** **12 1129** **46_556 33** **12 1130** **48 413** **33_12_1131 48** **333 33** **12 1132 50** **191 D3** **12 1133** **50 127** **33 12** **1134 51** **922 33** **12 1135** **51 858** **5692-Kiln Exhaust** **31045 erba** **'19/2010 DF** **Hydrogen Chloride** **(ppm) 20.4** **22.9 22.5** **24.4 25.6** **24.4 21.7** **24.1 22.5** **25.0 25.0** **25.7 25.7** **22.7 20.4** **23.2 SEC** 

### {ppm)**0.507 0.547** **0.541 0.566** **0.579 0.558** **0.511 0.550** **0.524 0.563** **0.570 0.577** **0.573 0.520** **0.489 0.543** **Average Cone,** **(ppm): 22.2** **0.552 EA#** **0310-05 Page** **of 48** **Company Analyst** **Initials**

### Parameters**Run Run** **Run Run** **Run Run** **Run Run** **Run Run** **Run Run** **Run Run** **Run Run** **Run Run** **Run Run** **Run Run** **Run Run** **Run Run** **Run Run** **Run Run** **Run Run** **Run Run** **Run Run** **Run Run** **Run Run** **Run Run** **Run Run** **Samples O'Brien** **Gere CJT** **EPA Method** **321 Date** **3/12/2010 12:01** 

### 3/12/2010**12:02 3/12/2010** **12:03 3/12/2010** **12:04 3/12/2010** **12:05 3/12/2010** **12:06 3/12/2010** **12:07 3/12/2010** **12:08 3/12/2010** **12:09 3/12/2010** **12:10**

### 3/12/2010**12:11 3/12/2010** **12:12 3/12/201012:13** **3/12/201012:14 3/12/2010** **12:15 3/12/2010** **12:16 3/12/2010** **12:17 3/12/2010** **12:18 3/12/2010** **12:19**

### 3/12/2010**12:20 3/12/201012:21** **3/12/2010 1222** 

### 3/12/2010**1223 3/12/2010** **12:24 3/12/2010** **1225 3/12/2010** **1226 3/12/2010** **1227 3/12/2010** **12:28 3/12/2010** **12:29 3/12/2010** **12:30 3/12/2010** **12:31 3/12/2010** **12:32 3/12/2010** **12:33 3/12/2010** **12:34 3/12/2010** **12:35 3/12/2010** **12:36 3/12/2010** **12:37 3/12/2010** **12:38**

### 3/12/201012:39**3/12/2010 12:40** **3/12/2010 12:41** **3/12/2010 12:42** **3/12/2010 12:43** **3/12/2010 12:44** **Method 0310-05A** **0310-05A 0310-05A** **0310-05A 0310-05A** **0310-05A 0310-05A** **0310-05A 0310-05A** **0310-05A 0310-05A** **0310-05A 0310-05A** **0310-05 0310-05A** **0310-05A 0310-05A** **0310-05 0310-05A** **0310-05A 0310-05A** **0310-05A 0310-05A** **0310-05 0310-05** **0310-05A 0310-05A** **0310-05A 0310-05A** **0310-05A 0310-05A** **0310-05A 0310-05A** **0310-05A 0310-05** **0310-05A 0310-05A** **0310-05A 0310-05A** **0310-05 0310-05A** **0310-05A 0310-05A** **0310-05A Client** **Job# PO#** **Report Date** **45692 Kiln** **Exhaust 0310-05** **Verbal 3/19/2010** **Filename DF** **10_03 12** **1201 02** **443 10** **03 12** **1202 02** **347 10** **03 12_1203_04** **205 10** **03 12** **1204 04** **110 10** **03 12** **1205 05** **780 10 03** **12 1206** **05 716** **10 03 12** **1207 07** **511 10** **03 12** **1208 07 432** **10_03_12_1209_09_164 10** **03_12_1210_09 085** **10_03_12_1211 10_880** **10_03 12** **1212 10** **816 10** **03 12** **1213 12 486** **10 03** **12 1214** **12 422** **10 03 12** **1215 14 217** **10_03_12 1216** **14 137** **10 03** **12 1217_16_058** **10 03** **12 1218_15_962** **10 03** **12 1219** **17 726** **10 03 12** **1220 17** **678 10** **03 12 1221** **19 411 10_03_12_1222_19_347** **10 03** **12_1223 21** **079 10** **03 12** **1224 21** **015 10** **03 12** **1225 22** **748 10 03** **12 1226** **22_684 10** **03 12** **1227 24** **417 10** **03 12** **1228 24 337** **10_03_12_1229_26_132 10_03_12_1230_26_037** **10 03 12** **1231 25** **973 10** **03 12** **1232 27_768** **10 03** **12 1233** **27 704** **10 03** **12 1234** **29 375** **10 03** **12 1235** **29 310** **10 03 12** **1236 31** **106 10_03_12_1237_31_026** **10 03 12** **1238 32** **728 10 03** **12 1239** **32 664** **10_03_12_1240_32_600 10** **03 12** **1241 34** **457 10** **03 12** **1242 34** **378 10** **03 12** **1243 36** **235 10** **03 12** **1244 36** **156 Hydrogen** **Chloride (ppm)** **23.7 23.8** **25.5 27.4** **28.2 25.0** **24.0 22.0** **22.6 22.9** **23.1 21.4** **20.5 22.0** **19.1 16.2** **15.2 15.4** **14.2 13.2** **13.2 14.3** **14.7 14.9** **13.8 12.8** **11.4 12.0** **11.6 12.9** **14.7 14.8** **17.2 19.3** **21.2 21.6** **16.9 19.1** **17.5 18.9** **18.3 19.2** **22.2 24.1** **SEC**

### (ppm)**0.546 0.550** **0.575 0.608** **0.628 0.570** **0.552 0.521** **0.537 0.545** **0.541 0.518** **0.504 0.533** **0.490 0.455** **0.436 0.442** **0.422 0.407** **0.406 0.405** **0.402 0.414** **0.410 0.405** **0.395 0.398** **0.398 0.408** **0.420 0.417** **0.442 0.471** **0.502 0.507** **0.435 0.470** **0.446 0.464** **0.458 0.469** **0.520 0.540** **EA# 0310-05** **Page of** **48 Company** 

### Analyst**Initials Parameters** 

### Samples**Run Run** **Run Run** **Run Run** **Run Run** **Run Run** **Run Run** **Run Run** **Run Run** 

### O'Brien**Gere CJT** 

### EPA**Method 321** **Date**

### 3/12/2010**12:45 3/12/2010** **12:46 3/12/201012:47** 

### 3/12/2010**12:48 3/12/2010** **12:49 3/12/2010** **12:50 3/12/2010** **12:51 3/12/201O** **12:52 3/12/2010** **12:53 3/12/2010** **12:54**

### 3/12/2010**12:55 3/12/2010** **12:56 3/12/2010** **12:57 3/12/2010** **12:58 3/12/201012:59** **3/12/2010 13:00** **Method 0310-05A** **0310-05A 0310-05A** 

### 0310-05A**0310-05A 0310-05A** **0310-05A 0310-05A** **0310-05A 0310-05** **0310-05A 0310-05A** **0310-05A 0310-05A** **0310-05A 0310-05A** **Client Job#** 

### PO#**Report Dale** **Filename 45692** **Kiln Exhaust** **0310-05 Verba** 

### 3/19/2010**DF 10_03** **12_1245_38_014 10 03** **12 1246** **37 950** **10_03_12 1247** **39 745** **10.03 12** **1248 39** **665 10** **03 12** **1249 41** **586 10** **03 12** **1250 41** **490 10 03** **12 1251** **43 286** **10 03 12** **1252 43** **206 10 03** **12 1253** **44 939** **10 03** **12 1254** **44 875** **10 03_12_1255_46_607** **10 03** **12 1256** **46 528** **10 03** **12 1257** **48 292** **10_03_12_1258 48** **243 10_03** **12 1259** **49 976** **10 )3** **12 1300** **49 912** **Hydrogen Chloride** **(ppm) 24.7** **22.0 25.7** **25.4 23.7** **25.6 25.0** **25.1 22.6** **18.0 19.0** **23.0 24.0** **23.9 27.0** **27.0 SEC** **(ppm) 0.557** **0.513 0.576** **0.567 0.539** **0.562 0.557** **0.553 0.521** **0.461 0.476** **0.537 0.546** **0.553 0.610** **0.607 Average** **Cone, (ppm):** **20.1 0495** **EA# 0310-05** **Page of** **48 Company** 

### Analyst**Initials Parameters** **Samples Run** **Run Run** **Run Run** **Run Run** **Run Run** **Run Run** **Run Run** **Run Run** **Run Run** **Run Run** **Run Run** **Run Run** **Run Run** **Run Run** **Run Run** **Run Run** **Run Run** **Run Run** **Run Run** **Run Run** **Run Run** **Run Run** **Run O'Brien** **Qere CJT** 

### EPA**Method 321** **Date 3/12/2010** **14:03**

### 3/12/2010**14:04 3/12/2010** **14:05 3/12/201014:06** **3/12/2010 14:07** 

### 3/12/2010**14:08 3/12/2010** **14:09 3/12/2010** **14:10 3/12/201014:11** **3/12/2010 14:12** **3/12/2010 14:13** 

### 3/12/2010**14:14 3/12/201014:15** **3/12/2010 14:16** **3/12/2010 14:17** **3/12/2010 14:18** **3/12/201014:19 3/12/2010** **14:20 3/12/2010** **14:21 3/12/2010** **14:22 3/12/201014:23** **3/12/2010 14:24** **3/12/2010 14:25** **3/12/2010 14:26** **3/12/201014:27 3/12/2010** **14:28 3/12/2010** **14:29 3/12/2010** **14:30 3/12/2010** **14:31 3/12/2010** **14:32**

### 3/12/2010**14:33 3/12/2010** **14:34**

### 3/12/2010**14:35 3/12/201014:36** 

### 3/12/2010**14:37 3/12/2010** **14:38 3/12/2010** **14:39 3/12/2010** **14:40 3/12/2010** **14:41 3/12/2010** **14:42 3/12/2010** **14:43 3/12/2010** **14:44 3/12/2010** **14:45**

### 3/12/2010**14:46 Method** **0310-05A 0310-05A** **0310-05A 0310-05** **0310-05A 0310-05A** **0310-05A 0310-05A** **0310-05A 0310-05A** **0310-05A 0310-05A** **0310-05A 0310-05A** **0310-05A 0310-05A** **0310-05A 0310-05A** **0310-05A 0310-05A** **0310-05A 0310-05** **0310-05A 0310-05A** **0310-05A 0310-05** **0310-05A 0310-05A** **0310-05A 0310-05A** **0310-05A 0310-05A** **0310-05A 0310-05** **0310-05 0310-05A** **0310-05A 0310-05A** **0310-05A 0310-05A** **0310-05A O31CM35A** **0310-05A 0310-05A** **Clienltf Job** ***PO# Report** **Date Filename** **10 03** **12 45692** **Kiln Exhaust** **0310-05 Verba** **3/19/2010 DF** **1403 01_945** **10_03_12_1404_01_88 10 03** **12 1405** **03 739** **10_03 12** **1406_03_69 10** **03 12** **1407 05** **486 10** **03 12** **1408 05** **422 10** **03 12** **1409 07** **280 10 03** **12 10 03** **12 1410** **07 216** **1411 09** **012 10 03** **12 1412** **08 963** **10J)3 12** **10 03** **12 10** **03 12** **10_03_12. 10_03** **12 10_03_12_** **10 03** **12 _1413_10_82'** **1414_10_757**

# "1415**12~553 _1416_12_489** **1417 12_393** **1418 14 158** **1419 14** **094**

## 10**03~12^1420 15** **826 10 03** **12 10_03_12.** **1421 15** **747**

## "1422~17**542 10** **03_12_1423_17 478** 

# 10_03_12~**10 03** **12 10J)3_12_** **10 03** **12 10** **03 12.** **10 03** **12 10** **03 12** **10 03 12** **10 03 12** **1424 19** **336 1425** **19_272 1426** **21 067** **_1427_20_988 .1428** **22 689** **1429_22_625 .1430_24_421** 

# "i431~24~32e**_1432_26_027 10** **03_12_1433_25_96Z 10** **03 12** **1434 27** **946 10** **03_12. 10** **03 12** **10 03** **12 10_03_12_** **10_03_12 10** **03 12** **10 03** **12 J435_27** **851 1436** **27 787** **1437 29** **582 1438** **29 502** **1439 31** **23£ 1440** **31J71 1441_31J)7€** **10_03 12** **1442_32_902 10** **03 12** **10 03_12_** **1443 32 836** **1444 34_697** **10 03** **12 1445_34_617** **10 03** **12 1446** **36 47£** **Hydrogen Chloride** 

### (ppm)**25.7 27.2** **25.1 28.6** **27.8 27.9** **27.6 26.4** **26.7 26.0** **24.3 24.0** **25.5 25.0** **23.8 22.9** **23.6 23.5** **22.2 21.4** **22.1 23.1** **24.1 25.6** **28.3 28.4** **28.2 26.6** **26.0 25.4** **25.0 26.8** **27.0 25.5** **25.9 32.1** **36.4 31.0** **24.9 19.4** **17.1 22.3** **25.6 28.9** **SEC**

### (ppm)**0.711 0.739** **0.693 0.721** **0.744 0.730** **0.716 0.683** **0.680 0.665** **0.627 0.623** **0.645 0.629** **0.597 0.573** **0.578 0.568** **0.544 0.527** **0.542 0.559** **0.577 0.608** **0.663 0.663** **0.662 0.624** **0.613 0.600** **0.582 0.616** **0.615 0.589** **0.597 0.704** **0.772 0.690** **0.587 0.504** **0.476 0.562** **0.622 0.682** **EA# 0310-05** **Page 10** **of 48** **Company Analyst** **Initials**

### Parameters**Samples O'Brien** **Gere CJT** 

### EPA**Melhod 321** **Client Job** *

### PO#**Report Date** **45892-Kiln Exhaust** **0310-05 Verbal** 

### 3/19/2010**Run Run** **Run**

### Run**Run Run** **Run Run** **Run Run** **Run Run** **Run Run** **Run Run** **Run Date** **3/12/201014:47**

### 3/12/2010**14:48 3/12/2010** **14:49 3/12/2010** **14:50**

### 3/12/201014:51**3/12/2010 14:52** 

### 3/12/201014:53**3/12/2010 14:54** **3/12/2010 14:55** **3/12/2010 14:56** **3/12/2010 14:57** **3/12/2010 14:58** 

### 3/12/2010**14:59 3/12/2010** **15:00 3/12/2010** **15:01**

### 3/12/2010**15:02 3/12/2010** **15:03**

### Method**0310-05A 0310-05A** **0310-05A 0310-05** **0310-05A 0310-05A** **0310-05A 0310-05A** **0310-05A O31O-O5A** **0310-05A 0310-05A** **0310-05A 0310-05A** **0310-05A 0310-05A** **0310-05A Filename** **10J)3 12** **1447 36** **411 10** **03 12** **1448 38** **206 10 03** **12 1449** **38 126** 

### 10_03**12 1450** **40 015** **10 03** **12 1451** **39 951** **10 03** **12 1452** **41 747** **10_03_12_1453_41 652** 

## 10**03 12 1454** **43~541 10_03** **12 1455** **43 477** **10_03 12** **1456 45** **272 10** **03 12** **1457 45** **208 10_03_12_1458_47** **066 10_03_12_1459** **47 018** **10 03** **12 1500** **48 813** **10_03 12 1501** **48 765** **10 03** **12 1502** **50 623** **10 03 12** **1503 53 762** **OF Hydrogen** **Chloride (PPm)** **32.1 33.2** **27.4 25.7** **22.9 27.2** **29.0 28.6** **27.2 25.7** **22.5 17.4** **18.8 22.2** **19.4 15.7** **13.2 SEC** **(ppm) 0.743** **0.768 0.661** **0.633 0.560** **0.661 0.699** **0.698 0.673** **0.634 0572** **0.496 0.519** **0.566 0.515** **0.468 0.440** **Average Cone,** **(ppm): 25.2** **0.623 EA#** **0310-05 Page** **11 of 48** 

# FTIR**Narrative Summary** **EA# 0310-05** **Page 12** **of 48** 

# Enthalpy**Analytical Narrative** **Summary Introduction** **Clint Thrasher** **of Enthalpy** **Analytical, Inc.** **and O'Brien** **Gere staff** **performed Fourier** **Transform Infrared** **(FTIR) spectroscopy** **testing on** **March 12,** **2010 at** **the LaFarge** **Cement plant** **in Ravena,** **New York.** **The source** **(the Kiln** **Exhaust) was** **tested by** **FTIR spectroscopy** **tested for** **Hydrogen Chloride** **(HC1).**

### O'Brien**Gere of** **Syracuse, New** **York retained** **Enthalpy Analytical,** **Inc. of** **Durham, North** 

## Carolina**to operate** **the FTIR** **instrument and** **analyze the** **data. Testing** **was based** **on the** **procedures outlined** **in EPA** **Method 321** **Measurement of** **Gaseous Hydrogen** **Chloride**

## Emissions**at Portland** **Cement Kilns** **by Fourier** **Transform Infrared** **(FTIR) Spectroscopy.** 

## Sampling**Notes Three** **one-hour runs** **were performed** **at the** **Kiln Exhaust.** **Results**

### All**data from** **the runs** **are listed** **in the** **Results section** **of this** **report. HC1** **was detected** **above**

## its**minimum detectable** **concentration (MDC)** **value in** **all sample** **spectra during** **all runs.** 

## FTIR**Extractive Sampling** **System Sample** **gas was** **extracted through** **a probe assembly** **and heat-traced** **line, through** **sample gas** 

### dryer,**and into** **the absorption** **cell of** **the FTIR** **spectrometer. The** **heat-traced line** **was maintained** **at approximately** **375° F.** **pump connected** **to the** **FTIR cell** **outlet drew** **sample-gas**

### through**the cell** **at flow** **rate of** **approximately liters** **per minute.** **The absorption** **cell was** 

## maintained**at 181°** **to prevent** **condensation in** **the cell** **and minimize** **analyte adhesion** **to the** **walls and** **mirrors of** **the cell.** **The absorption** **cell path** **length was** **determined using** **certified cylinder** **of ethylene** **sent directly to** **the FTIR.** **Results of** **the path** **length calculations** **are presented** **in the** **"FTIR QA"** **Section of** **this report.** 

## FTIR**Instrument The** **FTIR instrument** **used for** **this test** **was MIDAC** **(Series 1-1301)** **medium-resolution**

### Michelson**interferometer spectrometer,** **designated as "Instrument** **L". The** **interferometer and** **detector were** **assembled by** **MIDAC Corporation** **(Costa Mesa,** **California). The** **nominal**

## spectral**resolution of** **the system** **was one** **half wavenumber** **(0.5****cm*').****The instrument** **was equipped** **with nominal** **10-meter path** **length White** **cell, potassium** **bromide (KBr)** **beamsplitter, zinc** **selenide (ZnSe)** **non-hygroscopic windows,** **and mercury** **cadmium telluride** **(MCT) liquid** **nitrogen-cooled detector.** **The inside** **walls of** **the cell** **were polished** **stainless steel** **to minimize** **interaction of** **the sample** **with the** **cell walls,** **and the** **cell mirrors** **were of** **bare gold.** **The gas** **pressure in** **the FTIR** **sample cell** **was monitored** **with pressure** **transducer connected** 

### directly**to the** **sample cell.** **The heated** **sample cell** **was wrapped** **in an** **insulating blanket** **and the** **temperatures were** **controlled with** **type thermocouples. All connections** **for the** **entire sampling** **EA# 0310-05** **Page 13** **of 48** 

## Enthalpy**Analytical Narrative** **Summary (continued)** **system were** **wrapped with** **electric heat** **tape and** **insulated to** **eliminate "cold** **spots." All** 

### components**were constructed** **of Type** **316 stainless** **steel, SilcoSteel** **coated stainless** **steel, or** 

## Teflon.**The absorption** **cell volume** **is approximately** **1.9 liters** **for Instrument** **L. The** **FTIR system** **was operated** **via portable** **computer, data** **archive storage** **system (USB** **Mass Storage** **Drive, 80** **GB) was** **used for** **data backup.** **All inlerferograms,** **single beams,** 

### absorbance**spectra, and** **background single** **beams are** **stored and** **archived at** **Enthalpy Analytical,** **Inc. Temp.** **Pres. Controller** 

## Gas**Sample Collection** **Nitrogen (N2)** **served as** **the background** **gas. For** **each day,** **sample gas** **was continuously** **purged through** **the sampling** **systems and** **absorption cells.** **Spectra consisting** **of 50** **co-added scans** **were recorded** **approximately once** **every minute** **on the** **instrument. Before,** **during, and** **after**

## testing,**certified calibration** **transfer standard** **(CTS) gas** **of ethylene** **was introduced** **to the** **FTIR spectrometer** **and allowed** **to reach** **steady state.** **The absorption** **path length** **results fiom** 

### these**measurements are** **included in** **the "FTIR** **QA" section** **of this** **report.**

## Data**Collection**

## All**spectra were** **recorded at** **nominal resolution** **of 0.S** **cm'1. The** **absorption cell** **was**

## ENTHALPY**ana iv** **tic 1.** **inc. EA#** **0310-05 Page** **14 of** **48**

## Enthalpy**Analytical Narrative** **Summary (continued)** **configured to** **allow many** **passes of** **the infrared** **beam to** **traverse the** **cell between** **the entrance** **and exit** **windows. This** **provided for** **path length** **of approximately** **8.8 meters.** **Sample spectra** **were divided** **point-by-point by** **al28-scan background** **recorded using nitrogen.** **The single** **beam spectrum** **was constantly** **monitored and** **new background** **was generated** **when residual** **and**

### absorbance**spectra indicated** **component build-up** **on the** **optical surfaces** **or alignment-related** **baseline shifts.** 

## Spectral**Analyses Enthalpy** **staff used** **the program** **AutoquantProTM (hereafter** **"AQ," version** **4.0.0.136, ©Midac** **Corporation, 2007)** **to collect** **and analyze** **all the** **infrared field** **data. The** **program allows** **the development** **and storage** **of analytical** **"methods" for** **analysis of** **spectral data** **(absorbance) files;** 

### we**developed one** **"method" for** **the task** **of determining** **the absorption** **path length** **and separate** **"method" for** **determining the** **concentrations of** **the target** **compound. All** **the information** **required to** **reproduce these** **analytical techniques** **is contained** **in the** **"Method Map"** **section of** **this report.** 

### The**concentration uncertainty** **reported by** **AutoquantPro is** **called the** **Standard Error** **of the** **Estimated Concentration,** **or SEC;** **it is** **also known** **as the Marginal** **Standard Deviation.** **The**

### uncertainties**in the** **concentration are** **proportional to** **the square** **root of** **the sums** **of the** **squares of** **the residual.** **After the** **residual spectrum** **is obtained,** **which we** **will call** **R. the error** 

### variance**for the** **case of** **single reference** **spectrum is** **calculated as:** **_2**

### where**is the** **number of** **observations. The** **SEC is** **given by:** 

# SEC=**°C where** **is the** **spectrum and** **is the** **known concentration** **of the** **reference.**

### The**95% confidence** **interval is** **1.96 times** **the SEC.** 

## Spectra**The reference** **spectra used** **for these** **analyses were** **developed by** **Enthalpy Analytical,** **Inc., by** **EPA, by** **MIDAC Corporation,** **and by** **the Department** **of Energy** **Pacific Northwest** **National Laboratory** **(DOE/PNNL). All** **spectra used** **in the** **analysis and** **the corresponding** **analytical**

### regions**are documented** **in the** **"Method Map"** **section of** **this report.** **For all** **data analysis,** **the**

## ENTHALPY**analytical, inc.** **EA# 0310-05** **Page 15** **of 48** 

## Enthalpy**Analytical Narrative** **Summary (continued)** **apodization was** **triangular and** **the baseline** **correction was** **linear. All** **spectra were** **analyzed using** **temperature and** **pressure corrections.** 

## Quality**Assurance Calibration** **Transfer Standards** **and Absorption** **Path Lengths** 

## Before**the first** **and after** **the last** **test run,** **calibration transfer standard** **(CTS) gas** **(Custom Gas** **XC024236B, 100** **ppm ethylene,** **balance N2)** **was introduced** **to the** **FTIR system** **to determine** **its**

### effective**absorption path** **length. This** **determination was** **based on** **comparisons of** **the "field"** **CTS spectra** **to laboratory** **CTS spectrum** **recorded by** **MIDAC. Over** **the test** **period, all** 

### calculated**absorption path** **lengths determined** **for the** **instrument varied** **by less** **than 3%** **of the** **mean path** **length, which** **was used** **in the** **final data** **analysis. Matrix** **Spikes**

### Matrix**spikes were** **successfully performed** **prior to** **and following** **each test** **run. The** **spike gas** **standard was** **certified mixture** **of HC1** **and SF6** **(Spectra Gases** **CC-303666, 59.8** **ppm HC1,** **3.01 ppm** **SF6, balance** **N2). The** **HC1 spike** **recoveries (see** **the "FTIR** **QA Spiking"** **section) were** **within the** **limits allowed** **by EPA** **Method 321,** **which specifies** **that the** **spike**

### dilution**factor (DF)** **should be** **less than** **10%. However,** **due to** **variations in** **the native** **HC1 concentration,** **it was** **necessary to** **spike at** **higher DF** **(approximately 15%)** **in order** **to**

### overcome**these variations.** **Also, spikes** **were performed** **while sampling** **ambient air** **before**

## the**first and** **after the** **last sample** **spike; these** **"ambient spikes"** **demonstrated effective** **delivery of** **HC1 through** **the sampling** **system in** **the absence** **of variable** **native concentrations.** **Minimum Detectable** **Concentration (MDC)** **EPA Method** **320 and the** **equivalent ASTM** **Standard D6348-03** **specify number** **of analytical** **uncertainty parameters** **that the** **analyst may** **calculate to** **characterize the** **FTIR**

### system**performance. The** **reported MOCs** **were calculated** **according to** **Section A2.2** **of ASTM** **Standard D6348-03.** **Spectral Interferences** **Enthalpy staff** **performed careful** **visual examinations** **of the** **sample spectra** **and the** **"residual" spectra** **generated by** **spectrally subtracting** **known compounds** **from the** **sample spectra.** **The**

### goals**of these** **examinations are** **1) to** **confirm the** **accuracy of** **the reported** **analyte concentrations** **and 2)** **to detect any** **additional compounds** **that might** **have been** **present in** **the sample** **streams. Data** **Storage**

### dedicated**desktop computer** **controlled the** **FTIR spectrometer;** **the hard** **drive of** **the computer** 

### served**as the** **primary data** **storage media.** **During testing,** **Enthalpy staff** **created and** **maintained backup** **and archive** **copies of** **the spectral** **data (interferograms,** **single beam** **spectra, and** 

## ENTHALPY**analytical, me.** **EA# 0310-05** **Page 16** **of 48** 

## Enthalpy**Analytical Narrative** **Summary (continued)** **absorbance spectra)** **on USB** **memory devices.** **Data Reviews** 

### Enthalpy**subjects all** **the spectroscopic** **data and** **analytical results** **to three** **levels of** **review.**

## First,**the field** **instrument operator** **inspects the** **instruments' outputs** **to ensure** **their appropriate** **performance during** **the sampling** **runs. Second,** **another analyst** **who did** **not perform** **the analyses** **examines the** **sample spectra** **and the** **quantitative analytical** **results, and** 

## also**spot-checks the** **analysis results** **by manually;** **these examinations** **include visual** **comparisons of** **the sample** **and reference** **spectra such** **as those** **illustrated in** **the "Selected** **Spectra" section.** **Finally, an** **independent reviewer** **checks the** **final report** **for consistency.** 

# ENTHALPY**ana lytical.inc.** **EA# 0310-05** **Page 17** **of 48** 

# FTIR**QA EA#** **0310-05 Page** **18 of** **48 Company** 

### Analyst**Initials Parameters** 

### Samples**O'Brien Gere** **CJT**

### EPA**Method 321** **Clients Job** *

### PO#**Report Date** **45692-Kiln Exhaust** **0310-05 Verbal** **3/19/2010**

# Path**Length path** **Date 3/10/2010** **9:42 3/10/2010** **9:42 3/10/2010** **9:42 3/10/2010** **9:42 3/10/20109:43** **3/10/2010 9:43** **3/10/2010 9:43** 

### 3/10/2010**9:43 3/10/2010** **17:11 3/10/2010** **17:12 3/10/2010** **17:12 3/10/2010** **17:12 3/10/2010** **17:12 3/10/2010** **17:13**

### 3/10/201017:13**3/10/2010 17:13** **3/11/20106:48 3/11/20106:46** **3/11/2010 6:49** 

### 3/11/2010**6:49 3/11/2010** **6:49 3/11/20106:50** **3/11/20106:50 3/11/2010** **6:50 3/11/201014:37** 

### 3/11/201014:37**3/11/201014:37 3/11/201014:38** 

### 3/11/201014:36**3/11/201014:38 3/11/201014:39** **3/11/201014:39 Method** **0310-05CTS 0310-05CTS** **0310-05CTS 0310-05CTS** **0310-05CTS 0310-05CTS** **0310-05CTS**

### 0310-05CTS**0310-05CTS 0310-05CTS** **0310-05CTS 0310-05CTS** **0310-05CTS 0310-05CTS** **0310-05CTS 0310-05CTS** **0310-05CTS 0310-05CTS** **0310-05CTS 0310-05CTS** 

### 0310-05CTS**0310-05CTS 0310-05CTS** **0310-05CTS 0310-05CTS** 

### 0310-05CTS**0310-05CTS 0310-05CTS** **0310-05CTS 0310-05CTS** **0310-05CTS 0310-05CTS** **FlleName 10** **03 10** **0942 01** **593 10_03** **10 0942** **18 061** **10 03** **10 0942** **34 514** **10 03** **10 0942** **50 998** **10 03** **10 0943** **07 450** **10_03_10_0943 23 934** **10 03** **10 0943** **40 403** **10_03_10_0943_56_855 Average** **(m) 10_03_10_1711_44_477** **10 03** **10 1712** **01_836 10** **03 10** **1712 19** **148 10** **03 10** **1712 36 460** **10 03** **10 1712** **53 725** **10 03_10_1713_11_037** **10 03** **10 1713** **28 364** **10_03_10_1713_45_739 Average** **(m) 10** **03 11** **0648 40** **829 10** **03 11** **0648 58 079** **10_03_11J)649 15_328** **10 03** **11 0649** **32_562 10_03_11_0649_49_811** **10_03_11_0650_07_077**

## 10~03**11~0650~24~326 10_03_11_0650_41_576** **Average (m)** **10_03_11_1437 19_953** 

# 10~03T1i"i437**37 187** **10 03** **11 1437** **54 499** **10 03** **11 1438** **11 858** **10 03** **11 1438** **29 154** **10 03** **11 1438** **46 388** **10 03** **11 1439** **03 700** **10 03** **11 1439** **20 997** **ethylene (ppm)** **8.72 8.71** **8.70 8.70** **8.70 8.71** **8.70 8.71** **8.70 8.86** **8.86 8.85** **8.87 8.86** **8.86 8.87** **8.87 8.86** **8.95 8.94** **8.95 8.94** **8.95 8.95** **8.95 8.95** **8.9S 8.52** **8.54 8.55** **8.56 8.55** **8.56 8.56** **8.57 SEC** **(p| 0.136** **0.136 0.136** **0.136 0.136** **0.138 0.136** **0.136 0.136** **0.128 0.129** **0.128 0.128** **0.128 0.129** **0.128 0.128** **0.128 0.130** **0.130 0.131** **0.131 0.131** **0.131 0.131** **0.131 0.131** **0.126 0.127** **0.127 0.127** 

### 6.127**0.126 0.127** **0.127 EA#** **0310-05 Page** **19 of** **48 Company** 

### Analyst**Initials Parameters** 

### Samples**O'Brien Gere** **CJT EPA** **Method 321** **Client**

### Job#**PO# Report** **Date 45692** **Kiln Exhaust** **0310-05 Verbal** **3/19/2010**

# Path**Length path** **Date 3/12/2010** **7:55 3/12/2010** **7:56 3/12/2010** **7:56 3/12/2010** **7:56 3/12/2010** **7:57**

### 3/12/2010**7:57 3/12/2010** **7:57 3/12/2010** **7:57 3/12/2010** **16:49 3/12/2010** **16:49 3/12/201016:49** **3/12/2010 16:50** **3/12/2010 16:50** **3/12/2010 16:50** **3/12/2010 16:51** **3/12/2010 16:51** **Method 0310-05CTS** **0310-05CTS 0310-05CTS** **0310-05CTS 0310-05CTS** **0310-05CTS 0310-05CTS** **0310-05CTS 0310-05CTS** **0310-05CTS 0310-05CTS** **0310-05CTS 0310-05CTS** **0310-05CTS 0310-05CTS** **0310-05CTS FlleName** **Average (m)** **10_03 12** **0755 56** **627 10** **03 12** **0756 13** **095 10** **03 12** **0756 29 626** **10 03** **12 0756** **46 141** **10 03_12_0757** **02 641** **10 03** **12 0757** **19 125** **10 03** **12 0757** **35 625** **10_03_12_0757_52_187 Average** **(m) 10** **03 12** **1649 24** **855 10** **03 12** **1649 42** **198 10** **03 12** **1649 59** **416 10_03_12_1650_16_540** **10_03_12_1650_33_681**

### 10_03J2J650**50 914** **10 03** **12 1651** **08 133** **10_03_12_1651_25_257 Average** **(m) Average** **Pathlength (m)** **Max (m)** **Mln (m)** **Max Deviation** **ethylene (ppm)** **8.55 8.63** **8.66 8.66** **8.66 8.65** **8.65 8.66** **8.67 8.65** **8.90 8.87** **8.88 8.68** **8.89 8.88** **8.89 8.86** **8.88 8.77** **8.95 8.55** **2.45% SEC** **(ppm) 0.127** **0.124 0.125** **0.124 0.124** **0.124 0.124** **0.124 0.125** **0.124 0.123** **0.122 0.123** **0.123 0.123** **0.123 0.123** **0.123 0.123** **0.128 EA** ***0310-05 Page** **20 of** **48 Company** **Analyst Initials** **Parameters Samples** 

### O'Brien**Gere CJT** 

### EP/

## Mfnimum**Date 3/12/2010** **7:55 3/12/2010** **7:56 3/12/2010** **7:58**

### 3/12/2010**7:56 3/12/2010** **7:57 3/12/2010** **7:57 3/12/2010** **7:57**

### 3/12/2010**7:57 Method** **321 Client** **Job#**

### PO#**Report Date** **45692 Kiln** **Exhaust 0310-05** 

### Verbal**3/19/2010**

## Detectable**Concentration Default** **Method 0310-05** **0310-05A 0310-05A** **0310-05 0310-05A** **0310-05A 0310-05A** **0310-05A**

### Filename**10_03_12_0755_56_627 10_03_12_0756** **13 095** **10 03** **12 0756 29** **626**

### 10_03_12_0756**46 141** **10 03** **12 0757** **02 641** **10 03 12 0757** **19 125** **10 03** **12 0757** **35 625 10_03_12_0757_52_187** **MDC(ppm): DF** **HCI(ppm) 0.118** **-0.0490 -0.00900** **0.0310 -0.0550** **0.0230 0.0460** **-0.0510 0.0801** **0.180 SEC** **(ppm) 0.0660** **0.0690 0.0690** **0.0860 0.0670** **0.0670 0.0680** **0.0640 EA#** **0310-05 Page** **21 of** **48**

# FTIR**QA Spiking** **EA# 0310-05** **Page 22** **of 48** **Company**

### Analyst**Initials Parameters** 

### Samples**O'Brien Gere** **CJT EPA** **Method 321** **Client Jobtf** **PO# Report** **Date 45692-Kiln** **Exhaust 0310-05** **Verbal 3/19/2010** 

# Kiln**Exhaust Spike** **Sm -Spiked** **Data Date** 

### 3/12/2010**10:20 3/12/2010** **10:21 3/12/2010** **10:21**

### 3/12/201010:22**3/12/2010 10:23** **3/12/2010 10:23** **3/12/2010 10:24** 

### 3/12/2010**10:24 Method** **0310-05A 0310-05A** 

### 0310-05A**0310-05A**

### 0310-05A**0310-05A 0310-05A** **0310-05A**

### Su**•• Native** **Cone. Of** **analyte Date** **3/12/2010 10:13** **3/12/2010 10:14** **3/12/2010 10:15** **3/12/2010 10:15** 

### 3/12/2010**10:16 3/12/2010** **10:16 3/12/2010** **10:17 3/12/2010** **10:17 Sm** **Su DF** **CS Ce** 

## Recovery**(%)[ Method** **0310-05A O310-05A** **0310-05A 0310-05A** **0310-05A 0310-05A** 

### 0310-05A**0310-05A Recovery** **(%) Ce** **34.3 29.2** **15.3% 63.2** **2.75 34.4** **FileName 10** **03 12** **1020 45** **156**

### 10_03_12_1021_19_530**10_03 12** **1021 53** **826 10** **03 12** **1022 28** **059 10** **03 12** **1023 02** **370 10** **03 12** **1023 36** **729 10_03** **12 1024** **11 009** **10_03_12_1024_45_243 Avg.** **Cone, (ppm)** **FileName 10** **03 12** **1013 53** **637 10_03** **12 1014** **27 933** **10_03 12** **1015 02** **275 10** **03 12** **1015 36** **555 10** **03 12** **1016 10** **898**

### 10_03_12_1016_45**178 10** **03 12** **1017 19** **521 10** **03 12** **1017 53 770** 

## Avg.**Cone. (ppm)|** **Sm Su(1-DF)** **DFxCs DF** **Cs Su(1-DF)** **ppm ppm** **ppm ppm** **ppm 98.8%|70-130%** **HCi (ppm)** **33.8 34.3** **34.6 34.8** **34.9 33.9** **34.0 34.3** **34.3 HCI** **(ppm) 28.2** **28.8 29.5** **29.3 29.3** **30.0**

### 29.3**29.3 29.2** **SEC (ppm** **0.902 0.911** **0.909 0.911** **0.905 0.882** **0.881 0.883** **SEC (ppm]** **0.825 0.820** **0.845 0.842** **0.835 0.858** **0.828 0.847** **SF6 (ppm)** **0.445 0.444** **0.445 0.443** **0.446 0.444** **0.444 0.443** 

## 0.444**TM| SF6** **(ppm) 0.0210** **0.0220 0.0220** **0.0210 0.0200** **0.0220 0.0230** **0.0220 0.0216** 

### Mean**concentration of spiked** **analyte Native** **concentration of** **analyte Dilution** **Factor (Target** **Cylinder of** **spiked gas** **10%) Cylinder** **of tracer** **gas (SF6)** **Expected concentration** **)f analyte** **SEC (ppm)** **0.0370 0.0370** **0.0360 0.0360** **0.0370 0.0360** **0.0360 0.0360** **SEC (ppm)** **0.0430 0.0430** **0.0430 0.0420** **0.0420**

### 0.0430**0.0430 0.0430** **EA# 0310-05** **Page 23** **of 48** **Company**

### Analyst**Initials Parameters** 

### Samples**O'Brien Gere** **CJT**

### EPA**Method 321** **Client Job#** **Report Date** **45692 Kiln** **Exhaust 0310-05** **PO# Verbal** **3/19/2010**

# Kiln**Exhaust Spike** **Direct Spike** **Cylinder- Using** **Cylinder Date** **3/10/201010:00 3/10/2010** **10:01 3/10/2010** **10:02**

### 3/10/201010:02**3/10/2010 10:03** **3/10/2010 10:03** **3/10/2010 10:04** **3/10/2010 10:04** **Method 0310-05A** **0310-05A**

### 0310-05A**0310-05A 0310-05A** **0310-05A 0310-05A** **0310-05A FileName** **10_03 10** **1000 55** **716 10_03** **10 1001** **29 871** 

### 10_03_10_1002_03**949 10** **03 10** **1002 38** **088 10_03_10J003** **12 244** **10_03 10** **1003 46** **383 10** **03 10** **1004 20** **445 10_03_10_1004_54_584** 

## Avg.**Cone. (ppm)|** **HCI (ppm)** **62.7 62.8** **63.0 63.1** **63.2 63.6** **63.7 63.6** **63.2 SEC** **(ppm) 0.835** **0.856**

### 0.873**0.886 0.882** **0.886 0.878** **0.891**

# .1**SF6 (ppm)** **2.76 2.75** **2.75 2.75** **2.75 2.75** **2.76 2.76** **2.75 SEC** **(ppm) 0.00300** **0.00300 0.00300** **0.00300 0.00300** **0.00300 0.00300** **0.00300 EA#** **0310-05 Page** **24 of** **48 Company** **Analyst Initials** **Parameters Samples** **O'Brien Gere** **CJT EPA** **Method 321** **Client 45692** **Kiln Exhaust** **Job #0310-05** 

### PO#**Verbal Report** **Date 3/19/2010** 

# Kiln**Exhaust Spike** **Sm -Spiked** **Data Date** 

### 3/12/201011:47

### 3/12/201011:48**3/12/201011:49 3/12/2010** **11:49 3/12/2010** **11:50 3/12/201011:50** **3/12/201011:51 3/12/2010** **11:51 3/12/201011:52** **Method 0310-05A** **0310-05A 0310-05A** 

### 0310-05A**0310-05A 0310-05A** **0310-05A 0310-05A** **0310-05A**

### Su**Native Cone.** **Of analyte** **Date 3/12/2010** **11:37 3/12/201011:37** **3/12/201011:38 3/12/2010** **11:38**

### 3/12/2010**11:39 3/12/201011:39** 

### 3/12/201011:40**3/12/201011:41 Sm** **Su DF** **CS Ce** 

## Recovery**(%)[ Method** **0310-05A 0310-05A** **0310-05A 0310-05A** **0310-05A 0310-05A** **0310-05A 0310-05A** **Recovery (%)** **Ce 31.3** 

### 25.5**15.7% 63.2** **2.75 31.4** **99.4%| FlleName** **10 03** **12 1147** **52 901** 

# 10~03~12~1148**27~150 10_03_12** **1149 01** **446 10** **03 12** **1149 35** **680**

### 10**03 12J150_10_038** **10 03** **12 1150_44** **381 10_03_12_1151_18_681** **10 03** **12 1151** **52 895** **10_03_12_1152_27J206 Avg.** **Cone, (ppm)** **FlleName 10** **03 12** **1137 01** **403 10_03_12** **1137 35 715 10** **03 12** **1138 10** **026 10** **03 12** **1138_44_275 10** **03 12** **1139 18** **571 10** **03 12** **1139 52** **805 10** **03 12_1140_27_101** **10_03_12_1141_01_334 Avg.** **Cone, (ppm)** **Sm Su(1-DF)** **DFxCs DFxCs** **Su(1-DF) ppm** **ppm ppm** **ppm ppm** 

## |70**-130% HCI** **(ppm) 28.8** **30.4 31.5** **32.0 32.1** **30.6 31.2** **32.7 32.6** **31.3 HCI** **(ppm) 24.3** **25.4 25.6** **25.8 26.0** **25.5 25.7** **25.4 25.5** **SEC (ppm)** **0.603 0.647** **0.649 0.664** **0.855 0.835** **0.642 0.669** **0.668 SEC** **(ppm) 0.543** **0.562 0.566** **0.570 0.577** **0.565 0.561** **0.552 SF6** **(ppm) 0.444** **0.447 0.445** **0.446 0.446** **0.447 0.445** **0.448 0.444** **0.446 SF6** **(ppm) 0.0110** **0.0130 0.0100** **0.0120 0.0120** **0.0150 0.0140** **0.0160 0.0129** **Mean concentration** **of spiked** **analyte Native concentration of** **analyte Dilution** **Factor (Target** **<' Cylinder** **of spiked** **gas 10%)** **Cylinder of** **tracer gas** **(SF6) Expected** **concentration of** **analyte SEC** **(ppm) 0.0350** **0.0340 0.0350** **0.0350 0.0350** **0.0350 0.0340** **0.0350 0.0340** **SEC (ppm)** **0.0380 0.0390** **0.0380 0.0390** **0.0390 0.0400** **0.0400 0.0400** **EA# 0310-05** **Page 25** **of 48** **Company**

### Analyst**Initials Parameters** **Samples O'Brien** **Gere CJT** **EPA Method** **321 Clients** **Job#**

### PO#**Report Date** **45692 Kiln** **Exhaust 0310-05** **Verbal 3/19/2010** 

## Kiln**Exhaust Spike** **Direct Spike** **Cylinder- Using** **Cylinder Date** **3/10/201010:00 3/10/201010:01** **3/10/2010 10:02** **3/10/2010 10:02** **3/10/2010 10:03** **3/10/201010:03 3/10/2010** **10:04 3/10/2010** **10:04 Method** **0310-05A 0310-05A** **0310-05A 0310-05A** **O310-O5A 0310-05A** **0310-05A 0310-05A** **FlleName 10** **03 10** **1000 55** **716 10** **03 10** **1001 29** **871 10** **03 10** **1002 03** **949 10** **03 10** **1002 36** **088 10** **03 10** **1003 12** **244 10** **03 10** **1003 46** **383 10** **03 10** **1004 20** **445 10_03_10_1004_54_584** 

## Avg.**Cone. (ppm)|** **HCI (ppm)** **62.7 62.8** **63.0 63.1** **63.2 63.6** **63.7 63.6** **63.2 SEC** **(ppm) 0.835** **0.856 0.873** **0.886 0.882** **0.886 0.878** **0.891 SF6** **(ppm) 2.76** **2.75 2.75** **2.75 2.75** **2.75 2.76** **2.76 2.75** **SEC (ppm)** **0.00300 0.00300** **0.00300 0.00300** **0.00300 0.00300** **0.00300 0.00300** **EA# 0310-05** **Page 26** **Of 48** **Company Analyst** **Initials**

### Parameters**Samples O'Brien** **Gere CJT** **EPA Method** **321 Client** **Job#**

### P0#**Report Date** **45692 Kiln** **Exhaust 0310-05** **Verbal 3/19/2010** 

## Kiln**Exhaust Spike** **Sm -Spiked** **Data Date** **3/12/2010 13:52** 

### 3/12/2010**13:52 3/12/2010** **13:53 3/12/2010** **13:54 3/12/2010** **13:54 3/12/201013:55** **3/12/2010 13:55** **3/12/2010 13:56** **Method 0310-05A** **0310-05A 0310-05A** **0310-05A 0310-05A** **0310-05A 0310-05A** **0310-05A Su** **Native Cone.** **Of analyte** **Date 3/12/2010** **13:45 3/12/2010** **13:46 3/12/2010** **13:46 3/12/2010** **13:47 3/12/2010** **13:47 3/12/2010** **13:48 3/12/2010** **13:48 3/12/2010** **13:49 Sm** **Su DF** **CS Ce** 

## Recovery**(%)[ Method** **0310-05A 0310-05A** **0310-05A 0310-05A** **0310-05A 0310-05A** **0310-05A 0310-05A** **Recovery (%)** **Ce 32.6** **26.5 15.6%** **63.2 2.75** **32.3 FileName** **10 03** **12 1352** **23 429** **10_03 12** **1352 57_663** **10 03** **12 1353** **32 037** **10 03** **12 1354** **06 349** **10 03_12_1354** **40 660** **10_03_12 1355** **14 894** **10 03** **12 1355** **49 206** **10_03_12_1356_23_455 Avg.** **Cone, (ppm)** **FileName 10_03_12_1345_31_690** **10 03** **12 1346_05_939** 

## 10**03 12** **1346~40~250 10** **03 12** **1347 14** **609 10_03_12_1347** **48 889** **10 03** **12 1348** **23 170** **10_03_12_1348_57_513 10_03_12_1349_31_855** **Avg. Cone,** **(ppm) Sm** **Su(1-DF) DFxCs** **DF Cs** **Su(1-DF) ppm** **ppm ppm** **ppm ppm** **103%|70-130% HCI** **(ppm) 31.7** **32.4 32.7** **32.5 32.8** **32.8 33.2** **32.5 32.6** **HCI (ppm)** **27.9 27.6** **23.6 25.7** **28.1 27.3** **26.3 25.7** **26.5 SEC** **(ppm) 0.725** **0.746 0.756** **0.751 0.761** **0.762 0.777** **0.757 SEC** **(ppm) 0.653** **0.654 0.577** **0.616 0.656** **0.638 0.627** **0.619 SF6** **(ppm) 0.459** **0.457 0.456** **0.457 0.454** **0.454 0.453** **0.450 0455** **SF6 (ppm)** **0.0130 0.0140** **0.0150 0.0150** **0.0160 0.0140** **0.0160 0.0900** **0.0241 Mean** **concentration of** **spiked analyte** **Native concentration** **of analyte** **Dilution Factor** **(Target Cylinder** **of spiked** **gas 10%)** **Cylinder of** **tracer gas** **(SF6) Expected** **concentration of** **analyte SEC** **(ppm) 0.0360** **0.0350 0.0350** **0.0360 0.0360** **0.0360 0.0360** **0.0370 SEC** **(ppm) 0.0410** **0.0420 0.0420** **0.0420 0.0420** **0.0420 0.0420** **0.0400 EA#** **0310-05 Page** **27 of** **48 Company** 

### Analyst**Initials Parameters** **Samples O'Brien** **Gere CJT** 

### EPA**Method 321** **Client 45692** **Kiln Exhaust** **0310-05 Job#** 

### PO#**Report Date** **Verbal 3/19/2010** 

## Kiln**Exhaust Spike** **Direct Spike** **Cylinder- Using** **Cylinder Date** **3/10/2010 10:00** **3/10/2010 10:01** **3/10/201010:02 3/10/2010** **10:02 3/10/2010** **10:03 3/10/2010** **10:03 3/10/2010** **10:04 3/10/2010** **10:04 Method** **0310-05A 0310-05A** **0310-05A 0310-05A** **0310-05A 0310-05A** **0310-05A 0310-05A** **FileName 10_03** **10 1000** **55 716** **10 03** **10 1001** **29 871** **10_03 10** **1002 03** **949 10_03** **10 1002** **38 088** **10 03** **10 1003** **12 244** **10 03** **10 1003** **46 383** **10 03** **10 1004** **20 445** **10_03_10_1004_54_584**

## Avg.**Cone. (ppm)|** **HCI (ppm)** **62.7 62.8** **63.0 63.1** **63.2 63.6** **63.7 63.6** **63.2 SEC** **(ppm) 0.835** **0.856 0.873** **0.886 0.882** **0.886 0.878** **0.891 SF6** **(ppm) 2.76** **2.75 2.75** **2.75 2.75** **2.75 2.76** **2.76 2.75** **SEC (ppm)** **0.00300 0.00300** **0.00300 0.00300** **0.00300 0.00300** **0.00300 0.00300** **EA# 0310-05** **Page 26** **of 48** **Company Analyst** **Initials Parameters** 

### Samples**O'Brien Gere** **CJT**

### EPA**Method 321** **Client Job#** 

### PO#**Report Date** **45692 -Kiln** **Exhaust 0310-05** 

### Verbal**3/19/2010**

# Kiln**Exhaust Spike** **Sm -Spiked** **Data Date** **3/12/2010 15:55** **3/12/2010 15:56** 

### 3/12/2010**15:57 3/12/2010** **15:57 3/12/2010** **15:58 3/12/2010.15:58** **3/12/2010 15:59** **3/12/2010 15:59** **Method 0310-05A** **0310-05A 0310-05A** **0310-05A 0310-05A** **0310-05A 0310-05A** **0310-05A**

### Su**Native Cone.** **Of analyte** **Date 3/12/2010** **15:49 3/12/2010** **15:50 3/12/2010** **15:50 3/12/201015:51** **3/12/2010 15:51** **3/12/2010 15:52** **3/12/2010 15:53** **3/12/201015:53 Sm** **Su DF** **CS Ce** 

## Recovery**(%)[ Method** **0310-05A 0310-05A** **0310-05A 0310-05A** **0310-05A 0310-05A** **0310-05A 0310-05A** **Recovery (%)** **Ce 24.9** **21.3 14.5%** **63.2 2.75** **27.4 RleName** **10 03** **12 1555** **54 821** 

### 10_03_12_1556**29 179** **10_03 12** **1557 03** **475 10** **03 12** **1557 37** **771 10** **03 12** **1558 12** **051 10** **03 12** **1558 46 284** **10_03_12_1559 20** **642 10_03_12_1559_54_875** **Avg. Cone, (ppm)** **FileName 10** **03 12** **1549 37** **630 10_03_12** **1550 11_879** **10 03** **12 1550** **46 128** **10_03_12_1551_20_439 10_03_12_1551_54** **751**

## 10**03 12~1552 29** **046 10_03_12_1553_03_264** **10_03_12_1553_37_529 Avg.** **Cone, (ppm)** **Sm Su(1-DF)** **DFxCs DF** **Cs Su(1-DF)** **ppm ppm** **ppm ppm** **ppm 72.4%|70-130%** **HCI (ppm)** **23.1 23.8** **24.6 25.4** **25.8 25.8** **26.4 24.0** **24.9 HCI** **(ppm) 19.3** **20.5 21.2** **21.8 22.0** **21.9 21.8** **21.9 21.3** 

### SEC**(ppm) SF6** **(ppm) 0.819** **0.845 0.867** **0.889 0.910** **0.909 0.926** **0.851 0.428** **0.427 0.427** **0.427 0.426** **0.425 0.428** **0.427 0.427** **SEC (ppm)** **SF6 (ppm)** **0.717 0.753** **0.785 0.799** **0.801 0.793** **0.804 0.801** **0.0250 0.0280** **0.0290 0.0290** **0.0290 0.0260** **0.0260 0.0260** 

### 0.0273**Mean concentration** **of spiked analyte** 

### Native**concentration of** **analyte Dilution** **Factor (Target** **Cylinder of** **spiked gas** **10%) Cylinder** **of tracer** **gas (SF6)** **Expected concentration** **of analyte** **SEC (ppm)** **0.0390 0.0390** **0.0390 0.0390** **0.0360 0.0380** **0.0390 0.0390** **SEC (ppm)** **0.0430 0.0430** **0.0440 0.0440** **0.0440 0.0430** **0.0440 0.0440** **EA# 0310-05** **Page 29** **of 46** **Company Analyst** **Initials Parameters** 

### Samples**O'Brien Gere** **CJT EPA** **Method 321** **Client 45692** **Kiln Exhaust** **Job #0310-05** **PO# Verbal** **3/19/2010 Report** **Date**

# Kiln**Exhaust Spike** **Direct Spike** **Cytinder- Using** **Cylinder Date** **3/10/2010 10:00** **3/10/2010 10:01** 

### 3/10/2010**10:02 3/10/201010:02** **3/10/2010 10:03** **3/10/2010 10:03** **3/10/2010 10:04** **3/10/2010 10:04** **Method 0310-05A** **0310-05A 0310-05A** **0310-05A 0310-05A** **0310-05A 0310-05A** **0310-05A FileName** **10 03** **10 1000** **55 716** **10 03** **10 1001_29** **871 10** **03 10** **1002 03** **949 10.03** **10 1002** **38 068** **10 03** **10 1003** **12 244** 

### 10_03_10_1003_46__383**10 03** **10J004 20** **445 10_03_10_1004_54_584** 

## Avg.**Cone. (ppm)|** **HCI (ppm)** **62.7 62.8** **63.0 63.1** **63.2 63.6** **63.7 63.6** **63.2 SEC** **(ppm) 0.835** **0.856 0.873** **0.886 0.882** **0.886 0.878** **0.891**

# .I**SF6 (ppm)** **2.76 2.75** **2.75 2.75** **2.75 2.75** **2.76 2.76** **2.75 SEC** **(ppm) 0.00300** **0.00300 0.00300** **0.00300 0.00300** **0.00300 0.00300** **0.00300 EA#** **0310-05 Page** **30 of** **48 Company** **Analyst Initials** **Parameters Samples** 

### O'Brien**Gere CJT** **EPA Method** **321 Client** **Job# PO#** **Report Date** **45692 Kiln** **Exhaust 0310-05** **Verbal 3/19/2010** 

# Ambient**Spike Sm** **-Spiked Data** **Date 3/12/2010** **8:30 3/12/2010** **8:31**

### 3/12/2010**8:31 3/12/2010** **8:32 3/12/2010** **8:32 3/12/2010** **8:33 3/12/2010** **8:34 3/12/2010** **8:34 Method** **0310-05A 0310-05A** **0310-05A O31O-05A** **0310-05A 0310-05A** **0310-05A 0310-05A** 

### Su**Native Cone.** **Of analyte** **Date 3/12/2010** **8:12 3/12/2010** **8:12 3/12/2010** **8:13**

### 3/12/2010**8:13 3/12/2010** **8:14 3/12/20108:14** **3/12/2010 8:15** **3/12/2010 8:15** **Sm Su** **DF CS** **Ce**

## Recovery**(%)| Method** **0310-05A 0310-05A** **0310-05A 0310-05A** **0310-05A 0310-05A** **0310-05A 0310-05A** **Recovery (%)** **Ce 6.28** **0.186 10.1%** **63.2 2.75** **6.58 FileName** **10_03 12** **0830 45** **246 10JJ3** **12 0831** **18 261** **10_03_12_0831_51_276 10_03_12_0832_24** **197**

## 10**03 12~0832** **57 259** **10J)3 12** **0833 30** **305 10** **03 12** **0834 03 398** **10_03_12_0834_36_319 Avg.** **Cone, (ppm)** **FileName 10_03** **12 0812** **01 915** **10 03** **12 0812** **34 883** **10 03** **12 0813** **07 929** **10_03_12_0813_41 038** **10 03** **12 0814** **14 146** **10 03** **12 0814** **47 192** **10 03** **12 0815** **20 301** **10_03_12_0815_53_347**

## Avg.**Cone. (ppm)|** **Sm-Su(i-DF) DFxCs** **DFxCs Su(1-DF)** **ppm ppm** **ppm ppm** **ppm 95.3%|70-130%** **HCI (ppm)** **6.11 6.29** **6.30 6.26** **6.34 6.36** **6.39 6.21** **6.28 HCI** **(ppm) 0.270** **0.129 0.267** **0.217 0.181** **0.147 0.149** **0.124 0.186** **SEC (ppm)** **0.196 0.192** **0.189 0.194** **0.196 0.189** **0.189 0.198** **SEC (ppm)** **0.131 0.129** **0.132 0.126** **0.137 0.129** **0.131 0.124** **SF6 (ppm)** **0.281 0.279** **0.281 0.281** **0.281 0.280** **0.281 0.281** **0.281 SF6** **(ppm) 0.00100** **0.00100 0.00100** **0.00200 0.00100** **0.00100 0.00100** **0.00100 0.00113** **Mean concentration** **of spiked** **analyte Native** **concentration of** **analyte Dilution** **Factor (Target** **10%)**

### Cylinder**of spiked** **gas Cylinder** **of tracer** **gas (SF6)** **Expected concentration** **of analyte** **SEC (ppm)** **0.00100 0.00100** **0.00100 0.00100** **0.00100 0.00100** **0.00100 0.00100** **SEC (ppm)** **0.00100 0.00100** **0.00100 0.00100** **0.00100 0.00100** **0.00100 0.00100** 

### EA#**0310-05 Page** **31 of** **48 Company** **Analyst Initials** **Parameters Samples** **O'Brien Gere** **CJT EPA** **Method 321** **Client 45692** **Kiln Exhaust** **Job #0310-05** **PO# Report** **Date Verbal** **3/19/2010**

# Ambient**Spike Direct** **Spike Cylinder** **Date Method** **3/10/2010 10:00** **3/10/2010 10:01** **3/10/2010 10:02** **3/10/2010 10:02** **3/10/2010 10:03** **3/10/2010 10:03** **3/10/2010 10:04** **3/10/2010 10:04** **0310-05A 0310-05A** **0310-05A 0310-05A** **0310-05A 0310-05A** **0310-05A 0310-05A** **FileName 10** **03 10** **1000 55** **716 10** **03 10 1001** **29 871** **10 03** **10 1002** **03 949** **10 03** **10 1002 38** **088 10** **03 10** **1003 12** **244 10_03_10** **1003 46** **383 10** **03 10** **1004 20** **445 10_03_10_1004_54_584** 

## Avg.**Cone. (ppm)|** **HCI (ppm)** **62.7 62.8** **63.0 63.1** **63.2 63.6** **63.7 63.6** **63.2 SEC** **(ppm) 0.835** **0.856 0.873** **0.886 0.882** **0.886 0.878** **0.891 SF6** **(ppm) 2.76** **2.75 2.75** **2.75 2.75** **2.75 2.76** **2.76 2.75** **SEC (ppm)** **0.00300 0.00300** **0.00300 0.00300** **0.00300 0.00300** **0.00300 0.00300** **EA# 0310-05** **Page 32** **of 48** **Company**

### Analyst**Initials Parameters** **Samples O'Brien** **Gere CJT** **EPA Method** **321 Report** **Date Client** **45692 Kiln** **Exhaust Job** **#0310-05 PO#** **Verbal 3/19/2010** 

# Ambient**Spike Sm** **-Spiked Data** **Date 3/12/2010** **16:41 3/12/2010** **16:41 3/12/2010** **16:42 3/12/2010** **16:43 3/12/2010** **16:43 3/12/201016:44** **3/12/2010 16:44** **3/12/2010 16:45** **Method 0310-05A** **0310-05A 0310-05A** **0310-05A 0310-05A** **0310-05A 0310-05A** **0310-05A Su** **Native Cone.** **Of analyte** **Date**

### 3/12/2010**16:34 3/12/2010** **16:35 3/12/201016:35** 

### 3/12/2010**16:36 3/12/2010** **16:36 3/12/2010** **16:37 3/12/2010** **18:37 3/12/2010** **16:38 Sm** **Su DF** 

### CS**Ce**

## Recovery**(%)| Method** **0310-05A 0310-05A** **0310-05A 0310-05A** **0310-05A 0310-05A** **0310-05A 0310-05A** **Recovery (%) =** **Ce 11.2** **2.47 17.3%** **63.2 2.75** **13.0 FDeName** **10 03** **12 1641** **21 386** **10_03_12J641_55_744 10** **03 12** **1642 30** **103**

## 10~03**12~1643 04~461** **10 03** **12 1643 38** **741 10** **03 12** **1644 13** **099 10_03** **12 1644** **47 473** **10_03_12_1645_21_785**

## Avg.**Cone, (ppm)j** **FileName 10** **03 12** **1634 29** **525**

### 10**03 12** **1635 03** **836 10** **03 12** **1635 38** **132 10_03_12_1636_12_474** **10 03** **12 1636** **46_755 10** **03 12** **1637 21** **113 10** **03 12** **1637 55** **424 10_03_12_1638_29_782** 

## Avg.**Cone. (ppm)|** **Sm Su(1-DF)** **DFxCs DF** **Cs Su(1-DF)** **ppm ppm** **ppm ppm** **ppm 83.7%|70-130%** **HCI (ppm)** **11.2 11.5** **11.4 11.2** **11.0 11.0** **11.1 11.2** **11.2 HCI** **(ppm) 2.44** **2.47 2.50** **2.42 2.46** **2.53 2.43** **2.49 2.47** **SEC (ppm)** **0.410 0.426** **0.430 0.421** **0.411 0.410** **0.421 0.416** **SEC (ppm)** **0.162 0.164** **0.162 0.169** **0.156 0.166** **0.168 0.163** **SF6 (ppm)** **0.475 0.475** **0.474 0.473** **0.473 0.474** **0.473 0.473** **0474 SF6** **(ppm) -0.00300** **-0.00300 •0.00300** **•0.00300 -0.00300** **-O.00300 -0.00300** **•0.00300 giMU'friiUM** **Mean concentration** **of spiked analyte** **Native concentration** **of analyte** **Dilution Factor** **(Target Cylinder** **of spiked** **gas 10%)** **Cylinder of** **tracer gas** **(SF6) Expected** **concentration of** **analyte SEC** **(ppm) 0.00200** **0.00200 0.00200** **0.00200 0.00200** **0.00200 0.00200** **0.00200 SEC** **(ppm) 0.00200** **0.00200 0.00200** **0.00200 0.00200** **0.00200 0.00200** **0.00200 EA#** **0310-05 Page** **33 Of** **48 Company** **Analyst Initials** **Parameters Samples** **O'Brien Gere** **CJT EPA** **Method 321** **Client Job#** **PO# Report** **Date 45692** **Kiln Exhaust** **0310-05 Verbal** **3/19/2010**

## Ambient**Spike Direct** **Spike Cylinder** ***Using Cylinder** **Date 3/10/2010** **10:00 3/10/201010:01** **3/10/201010:02 3/10/2010** **10:02 3/10/2010** **10:03 3/10/2010** **10:03 3/10/201010:04** **3/10/2010 10:04** **Method 0310-05A** **0310-05A 0310-05A** **0310-05A 0310-05A** **0310-05A 0310-05A** **0310-05A FileName** **10 03** **10 1000** **55 716** **10_03 10** **1001 29** **871 10_03** **10 1002** **03 949** **10_03_10_1002_38_088 10** **03 10** **1003 12** **244 10_03_10_1003** **46 383** **10 03** **10 1004** **20 445** **10J>3_10_1004_54_584**

## Avg.**Cone. (ppm)|** **HCI (ppm)** **62.7 62.8** **63.0 63.1** **63.2 63.6** **63.7 63.6** **63.2 SEC** **(ppm) 0.835** **0.856 0.873** **0.888 0.882** **0.886 0.878** **0.891 SF6** **(ppm) 2.76** **2.75 2.75** **2.75 2.75** **2.75 2.76** **2.78 2.75** **SEC (ppm)** **0.00300 0.00300** **0.00300 0.00300** **0.00300 0.00300** **0.00300 0.00300** **EA# 0310-05** **Page 34** **of 48** 

# FTIR**Method Map** **EA# 0310-05** **Page 35** **of 48** 

### CTS**Method Map:** 

### Overrides:**Path Length=100ppm** **Method Name:** **0310-05CTS**

### Method**Path: I:\FTIR2010Ql\0310-05_OBG_LaFarge\methods\0310-05CTS\0310-** **05CTS.aq4**

### Method**Type: AutoQuant** **4.0 Linear** **Analysis Mode** 

### MethodParameters**Wavenumber range:** **650.00-4500.00 cm-1** **Default Pathlength** **101.7000 Gain** **==0.000000 Apodization** **Triangle**

### Phase**Correction Mertz** **Resolution 0.5** **cm-1**

### Baseline**Correction: Single** **Linear**

### Exclusion**Criterion: 2500.000000** **Compound: ethylene** 

### Description:**Molecular Weight:** **0.00 Alarms:** **Disabled**

### Primary**Spectrum: ETYH5A.SPC** **Reference Concentration:** **206.6000 ppm-m** 

### Reference**Pathlength: 1.0000** **Reference Pressure:** **1.0000 atm** **Reference Temperature:** **121.00 Region** **#1: 870.00** **-1040.00 cm-1** **EA# 0310-05** **Page 36** **of 48** 

### Sample**Method Map:** 

### Overrides:**Path Length=8.77m** **Method Name:** **0310-05**

### Method**Path: I:\FTIR2010Qi\0310-05_OBG_LaFarge\niethod8\0310-05A\0310-** **05A.aq4**

### Method**Type: AutoQuant4.0** 

### Non-Linear**Analysts Mode** **MethodParameters Wavenumber** **range: 650.00** **4500.00 cm-1** 

### Defeult**Pathlength 7.7000** **Gain 0.000000** 

### Apodization**Triangle Phase** **Correction Mertz** **Resolution 0.5** **cm-1**

### Baseline**Correction: Single** **Linear**

### Exclusion**Criterion: 2500.000000** **Compound: CO2** 

### Description:**Molecular Weight:** **0.00 Alarms:** **Disabled**

### Primary**Spectrum: CO2_16.92%_9.064m.SPC** **Reference Concentration:** **153.3629 ppm-m** **Reference Pathlength:** **9.0640 Reference** **Pressure: 1.0250** **atm**

### Reference**Temperature: 121.03** 

### Region**#1: 897.02** **1111.60 cm-1** **Region #2:** **2003.55 2162.64** **cm-1 Compound:** **SF6 Description:** **Molecular Weight:** **0.00**

### Alarms:**Disabled**

### Primary**Spectrum: SF6_2.92ppm_8.977m_l** **81 C.SPC** **Reference Concentration:** **26.2128 ppm-m** 

### Reference**Pathlength: 8.9770** 

### Reference**Pressure: 1.0261** **atm Reference** **Temperature: 180.95** **Region#l: 901.95-971.86** **cm-1 Compound:** **H2O**

### Description:

### Molecular**Weight: 0.00** **Alarms: Disabled** **Primary Spectrum:** **09_01_23_1643_07_613.abs Reference** **Concentration: 2250.0000** **ppm-m EA#** **0310-05 Page** **37 of** **48**

### Reference**Pathlength: 7.5000** **Reference Pressure:** **1.0154 atm** 

### Reference**Temperature: 121.10** **Region #1:** **1956.81 2157.79** **cm-1 Region** **#2: 841.63** **-1089.70 cm-1** **Region #3:** **3040.50 2501.27** **cm-1 Compound:** **HC1 Description:** 

### Molecular**Weight: 0.00** **Alarms: Disabled** 

### Primary**Spectrum: HCl_61.0ppm_9.698m_181CJatm.SPC** **Reference Concentration:** **590.4800 ppm-m** **Reference Pathlength:** **9.6800 Reference** **Pressure: 1.0016** **atm Reference** **Temperature: 180.88** 

### Region**#1: 2748.78** **2825.17 cm-1** **Spectrum: HCl_30.5ppm_9.698m_181C_latm.SPC** **Reference Concentration:** **295.2400 ppm-m** 

### Reference**Pathlength: 9.6800** **Reference Pressure:** **0.9976 atm** **Reference Temperature:** **181.10 Region** **#1: 2748.78** **2825.17 cm-1** **Spectrum: HC1_15.25ppm_9.698m_l** **81C_latm.SPC Reference** **Concentration: 147.6200** **ppm-m**

### Reference**Pathlength: 9.6800** **Reference Pressure:** **0.9970 atm** **Reference Temperature:** **180.73**

### Region**#1: 2748.78** **2825.17 cm-1** **Spectrum: HCl_5.0ppm_9.698m_l** **81 C_l** **atm.SPC**

### Reference**Concentration: 48.4000** **ppm-m**

### Reference**Pathlength: 9.6800** **Reference Pressure:** **0.9987 atm** **Reference Temperature:** **181.03**

### Region**#1: 2748.78** **2825.17 cm-1** **Compound: NH3** 

### Description:**Molecular Weight:** **0.00 Alarms:** **Disabled Primary** **Spectrum: Ammonial0ppm(9.355m).SPC** 

### Reference**Concentration: 93.5500** **ppm-m Reference** **Pathlength: 9.3550** **Reference Pressure:** **0.9921 atm** **Reference Temperature:** **121.00**

### Region**#1: 914.80** **975.89 cm-1** **EA# 0310-05** **Page 38** **of 48** 

# Logbook**Notes EA#** **0310-05 Page** **39 of** **48**

# 174**Project No.** 

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# Selected**Spectra EA#** **0310-05 Page** **46 of** **48**

### Top:**HCl Reference** **Spectrum Bottom:** **Kiln Exhaust** **Sample Spectrum** **EA# 0310-05** **Page 47** **of 48** 

# This**Is The** **Last Page** **Of This** **Report. EA#** **0310-05 Page** **48 of** **48**