13339 Hagers Ferry Road

Huntersville, NC 28078-7929

McGuire Nuclear Complex - MG03A2

Phone: 980-875-5245 Fax: 980-875-4349

Order Summary Report

Analytical Laboratory

Order Number: J10120055

Lab Contact: Jason C Perkins

Date: 1/2/2011

Customer Address: 3195 Pine Hall Rd

Customer Name(s): Bill Kennedy, Melonie Martin, Wayne Chapman, Tom Johnson

Mailcode: Belews Steam Station

Belews Creek, NC 28012

Phone: 980-875-5348

Report Authorized By:

(Signature)

Program Comments:

Belews Biweekly Smapling - 12/8

Ca and Se were detected in the trip blank and Se was also detedted in the filter blank. All actual samples had Ca and Se above

10 times the trip and filter blank concentrations so data is OK to report without qualifiers.

Data Flags & Calculations:

Any analytical tests or individual analytes within a test flagged with an "X" or "1" indicate a deviation from the method quality 

system or quality control requirement. All results are reported on a dry weight basis unless otherwise noted.

Data Package:

This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of 

the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except 

in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The 

order of individual sections within this report is as follows:

Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,

Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports & 

Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)

Certification:

The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina 

(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of 

specific methods. 

Analytical Laboratory 

Page 1 of 23
Sample ID's & Descriptions:

Sample ID Plant/Station

Collection 

Date and Time Collected By Sample Description

2010012854 BELEWS 08-Dec-10 10:02 AM ILLEGIBLE FGD PURGE EFF. 

2010012855 BELEWS 08-Dec-10 10:05 AM ILLEGIBLE EQ TANK EFF. 

2010012856 BELEWS 08-Dec-10 10:07 AM ILLEGIBLE BIOREACTOR 1 INF. 

2010012857 BELEWS 08-Dec-10 10:11 AM ILLEGIBLE BIOREACTOR 2 INF. 

2010012858 BELEWS 08-Dec-10 10:15 AM ILLEGIBLE BIOREACTOR 2 EFF. 

2010012859 BELEWS 01-Dec-10 2:00 PM C.KNOX Trip Blank 

2010012860 BELEWS 08-Dec-10 10:50 AM ILLEGIBLE FILTER BLANK 

7 Total Samples

Analytical Laboratory 

Page 2 of 23
COC and .pdf report are in agreement with sample totals 

and analyses (compliance programs and procedures).

All Results are less than the laboratory reporting limits.

All laboratory QA/QC requirements are acceptable.

The Vendor Laboratories have been qualified by the 

Analytical Laboratory

Yes No

Technical Validation Review

Checklist:

Yes No

Yes No

Report Sections Included:

Job Summary Report Sub-contracted Laboratory Results

Sample Identification Customer Specific Data Sheets, Reports, & Documentation

Technical Validation of Data Package Customer Database Entries

Analytical Laboratory Certificate of Analysis Test Case Narratives

Analytical Laboratory QC Report Chain of Custody

Reviewed By: Jenny A Herman Date: 12/31/2010

Yes

Electronic Data Deliverable (EDD) Sent Separately

Analytical Laboratory 

Page 3 of 23
Certificate of Laboratory Analysis

This report shall not be reproduced, except in full.

Order # J10120055

2010012854

Collection Date: 08-Dec-10 10:02 AM

Site: FGD PURGE EFF. 

Matrix: OTHER

Analyte Result Units Qualifiers RDL Method Analysis Date/Time

Sample #:

Analyst

MERCURY (COLD VAPOR) IN WATER

Mercury (Hg) 191 ug/L EPA 245.1 16-Dec-10 14:00 5 MHH7131

TOTAL RECOVERABLE METALS BY ICP

Aluminum (Al) 179 mg/L EPA 200.7 16-Dec-10 10:51 0.05 DJSULL1

Barium (Ba) 2.22 mg/L EPA 200.7 16-Dec-10 10:51 0.05 DJSULL1

Beryllium (Be) < 0.05 mg/L EPA 200.7 16-Dec-10 10:51 0.05 DJSULL1

Boron (B) 198 mg/L 0.5 EPA 200.7 16-Dec-10 10:51 DJSULL1

Calcium (Ca) 4850 mg/L 0.1 EPA 200.7 16-Dec-10 10:51 DJSULL1

Cobalt (Co) 0.208 mg/L 0.05 EPA 200.7 16-Dec-10 10:51 DJSULL1

Iron (Fe) 135 mg/L 0.1 EPA 200.7 16-Dec-10 10:51 DJSULL1

Magnesium (Mg) 767 mg/L 0.05 EPA 200.7 16-Dec-10 10:51 DJSULL1

Manganese (Mn) 8.32 mg/L 0.05 EPA 200.7 16-Dec-10 10:51 DJSULL1

Molybdenum (Mo) 0.082 mg/L 0.05 EPA 200.7 16-Dec-10 10:51 DJSULL1

Sodium (Na) 49.2 mg/L 0.5 EPA 200.7 16-Dec-10 10:51 DJSULL1

Tin (Sn) < 0.5 mg/L 0.5 EPA 200.7 16-Dec-10 10:51 DJSULL1

Titanium (Ti) 5.31 mg/L 0.05 EPA 200.7 16-Dec-10 10:51 DJSULL1

DISSOLVED METALS BY ICP-MS

Selenium (Se) 1660 ug/L EPA 200.8 27-Dec-10 14:22 10 KRICHAR

TOTAL RECOVERABLE METALS BY ICP-MS

Antimony (Sb) 28.0 ug/L EPA 200.8 21-Dec-10 13:35 10 KRICHAR

Arsenic (As) 273 ug/L EPA 200.8 21-Dec-10 13:35 10 KRICHAR

Cadmium (Cd) < 10 ug/L EPA 200.8 21-Dec-10 13:35 10 KRICHAR

Chromium (Cr) 374 ug/L 10 EPA 200.8 21-Dec-10 13:35 KRICHAR

Copper (Cu) 315 ug/L 10 EPA 200.8 21-Dec-10 13:35 KRICHAR

Lead (Pb) 356 ug/L 10 EPA 200.8 21-Dec-10 13:35 KRICHAR

Nickel (Ni) 370 ug/L 10 EPA 200.8 21-Dec-10 13:35 KRICHAR

Selenium (Se) 7000 ug/L 500 EPA 200.8 21-Dec-10 13:35 KRICHAR

Silver (Ag) < 10 ug/L 10 EPA 200.8 21-Dec-10 13:35 KRICHAR

Thallium (Tl) 11.2 ug/L 10 EPA 200.8 21-Dec-10 13:35 KRICHAR

Vanadium (V) 614 ug/L 10 EPA 200.8 21-Dec-10 13:35 KRICHAR

Zinc (Zn) 583 ug/L 20 EPA 200.8 21-Dec-10 13:35 KRICHAR

SELENIUM SPECIATION

Vendor Parameter Complete V_AS&C

TOTAL DISSOLVED SOLIDS

Vendor Parameter Complete V_PRISM

Analytical Laboratory 

Page 4 of 23
Certificate of Laboratory Analysis

This report shall not be reproduced, except in full.

Order # J10120055

2010012855

Collection Date: 08-Dec-10 10:05 AM

Site: EQ TANK EFF. 

Matrix: OTHER

Analyte Result Units Qualifiers RDL Method Analysis Date/Time

Sample #:

Analyst

MERCURY (COLD VAPOR) IN WATER

Mercury (Hg) 149 ug/L EPA 245.1 16-Dec-10 14:03 2.5 MHH7131

TOTAL RECOVERABLE METALS BY ICP

Aluminum (Al) 147 mg/L EPA 200.7 16-Dec-10 10:55 0.05 DJSULL1

Barium (Ba) 1.86 mg/L EPA 200.7 16-Dec-10 10:55 0.05 DJSULL1

Beryllium (Be) < 0.05 mg/L EPA 200.7 16-Dec-10 10:55 0.05 DJSULL1

Boron (B) 175 mg/L 0.5 EPA 200.7 16-Dec-10 10:55 DJSULL1

Calcium (Ca) 4500 mg/L 0.1 EPA 200.7 16-Dec-10 10:55 DJSULL1

Cobalt (Co) 0.163 mg/L 0.05 EPA 200.7 16-Dec-10 10:55 DJSULL1

Iron (Fe) 112 mg/L 0.1 EPA 200.7 16-Dec-10 10:55 DJSULL1

Magnesium (Mg) 683 mg/L 0.05 EPA 200.7 16-Dec-10 10:55 DJSULL1

Manganese (Mn) 7.25 mg/L 0.05 EPA 200.7 16-Dec-10 10:55 DJSULL1

Molybdenum (Mo) 0.068 mg/L 0.05 EPA 200.7 16-Dec-10 10:55 DJSULL1

Sodium (Na) 43.1 mg/L 0.5 EPA 200.7 16-Dec-10 10:55 DJSULL1

Tin (Sn) < 0.5 mg/L 0.5 EPA 200.7 16-Dec-10 10:55 DJSULL1

Titanium (Ti) 4.06 mg/L 0.05 EPA 200.7 16-Dec-10 10:55 DJSULL1

DISSOLVED METALS BY ICP-MS

Selenium (Se) 939 ug/L EPA 200.8 27-Dec-10 14:26 10 KRICHAR

TOTAL RECOVERABLE METALS BY ICP-MS

Antimony (Sb) 24.7 ug/L EPA 200.8 21-Dec-10 13:30 10 KRICHAR

Arsenic (As) 233 ug/L EPA 200.8 21-Dec-10 13:30 10 KRICHAR

Cadmium (Cd) < 10 ug/L EPA 200.8 21-Dec-10 13:30 10 KRICHAR

Chromium (Cr) 319 ug/L 10 EPA 200.8 21-Dec-10 13:30 KRICHAR

Copper (Cu) 266 ug/L 10 EPA 200.8 21-Dec-10 13:30 KRICHAR

Lead (Pb) 295 ug/L 10 EPA 200.8 21-Dec-10 13:30 KRICHAR

Nickel (Ni) 329 ug/L 10 EPA 200.8 21-Dec-10 13:30 KRICHAR

Selenium (Se) 5920 ug/L 500 EPA 200.8 21-Dec-10 13:30 KRICHAR

Silver (Ag) < 10 ug/L 10 EPA 200.8 21-Dec-10 13:30 KRICHAR

Thallium (Tl) < 10 ug/L 10 EPA 200.8 21-Dec-10 13:30 KRICHAR

Vanadium (V) 504 ug/L 10 EPA 200.8 21-Dec-10 13:30 KRICHAR

Zinc (Zn) 498 ug/L 20 EPA 200.8 21-Dec-10 13:30 KRICHAR

2010012856

Collection Date: 08-Dec-10 10:07 AM

Site: BIOREACTOR 1 INF. 

Matrix: OTHER

Analyte Result Units Qualifiers RDL Method Analysis Date/Time

Sample #:

Analyst

TOTAL RECOVERABLE METALS BY ICP

Aluminum (Al) 1.39 mg/L EPA 200.7 16-Dec-10 10:59 0.05 DJSULL1

Barium (Ba) 0.420 mg/L EPA 200.7 16-Dec-10 10:59 0.05 DJSULL1

Beryllium (Be) < 0.05 mg/L EPA 200.7 16-Dec-10 10:59 0.05 DJSULL1

Analytical Laboratory 

Page 5 of 23
Certificate of Laboratory Analysis

This report shall not be reproduced, except in full.

Order # J10120055

2010012856

Collection Date: 08-Dec-10 10:07 AM

Site: BIOREACTOR 1 INF. 

Matrix: OTHER

Analyte Result Units Qualifiers RDL Method Analysis Date/Time

Sample #:

Analyst

TOTAL RECOVERABLE METALS BY ICP

Boron (B) 175 mg/L EPA 200.7 16-Dec-10 10:59 0.5 DJSULL1

Calcium (Ca) 3880 mg/L EPA 200.7 16-Dec-10 10:59 0.1 DJSULL1

Cobalt (Co) < 0.05 mg/L EPA 200.7 16-Dec-10 10:59 0.05 DJSULL1

Iron (Fe) < 0.1 mg/L EPA 200.7 16-Dec-10 10:59 0.1 DJSULL1

Magnesium (Mg) 677 mg/L EPA 200.7 16-Dec-10 10:59 0.05 DJSULL1

Manganese (Mn) 3.53 mg/L EPA 200.7 16-Dec-10 10:59 0.05 DJSULL1

Molybdenum (Mo) < 0.05 mg/L EPA 200.7 16-Dec-10 10:59 0.05 DJSULL1

Sodium (Na) 43.0 mg/L EPA 200.7 16-Dec-10 10:59 0.5 DJSULL1

Tin (Sn) < 0.5 mg/L EPA 200.7 16-Dec-10 10:59 0.5 DJSULL1

Titanium (Ti) < 0.05 mg/L EPA 200.7 16-Dec-10 10:59 0.05 DJSULL1

DISSOLVED METALS BY ICP-MS

Selenium (Se) 646 ug/L EPA 200.8 27-Dec-10 14:29 10 KRICHAR

TOTAL RECOVERABLE METALS BY ICP-MS

Antimony (Sb) < 10 ug/L EPA 200.8 21-Dec-10 13:24 10 KRICHAR

Arsenic (As) < 10 ug/L 10 EPA 200.8 21-Dec-10 13:24 KRICHAR

Cadmium (Cd) < 10 ug/L 10 EPA 200.8 21-Dec-10 13:24 KRICHAR

Chromium (Cr) < 10 ug/L 10 EPA 200.8 21-Dec-10 13:24 KRICHAR

Copper (Cu) < 10 ug/L 10 EPA 200.8 21-Dec-10 13:24 KRICHAR

Lead (Pb) < 10 ug/L 10 EPA 200.8 21-Dec-10 13:24 KRICHAR

Nickel (Ni) 75.5 ug/L 10 EPA 200.8 21-Dec-10 13:24 KRICHAR

Selenium (Se) 616 ug/L 10 EPA 200.8 21-Dec-10 13:24 KRICHAR

Silver (Ag) < 10 ug/L 10 EPA 200.8 21-Dec-10 13:24 KRICHAR

Thallium (Tl) < 10 ug/L 10 EPA 200.8 21-Dec-10 13:24 KRICHAR

Vanadium (V) < 10 ug/L 10 EPA 200.8 21-Dec-10 13:24 KRICHAR

Zinc (Zn) < 20 ug/L 20 EPA 200.8 21-Dec-10 13:24 KRICHAR

SELENIUM SPECIATION

Vendor Parameter Complete V_AS&C

2010012857

Collection Date: 08-Dec-10 10:11 AM

Site: BIOREACTOR 2 INF. 

Matrix: OTHER

Analyte Result Units Qualifiers RDL Method Analysis Date/Time

Sample #:

Analyst

TOTAL RECOVERABLE METALS BY ICP

Aluminum (Al) 1.45 mg/L EPA 200.7 16-Dec-10 11:03 0.05 DJSULL1

Barium (Ba) 0.430 mg/L 0.05 EPA 200.7 16-Dec-10 11:03 DJSULL1

Beryllium (Be) < 0.05 mg/L 0.05 EPA 200.7 16-Dec-10 11:03 DJSULL1

Boron (B) 172 mg/L 0.5 EPA 200.7 16-Dec-10 11:03 DJSULL1

Calcium (Ca) 4000 mg/L 0.1 EPA 200.7 16-Dec-10 11:03 DJSULL1

Cobalt (Co) < 0.05 mg/L 0.05 EPA 200.7 16-Dec-10 11:03 DJSULL1

Analytical Laboratory 

Page 6 of 23
Certificate of Laboratory Analysis

This report shall not be reproduced, except in full.

Order # J10120055

2010012857

Collection Date: 08-Dec-10 10:11 AM

Site: BIOREACTOR 2 INF. 

Matrix: OTHER

Analyte Result Units Qualifiers RDL Method Analysis Date/Time

Sample #:

Analyst

TOTAL RECOVERABLE METALS BY ICP

Iron (Fe) 0.311 mg/L EPA 200.7 16-Dec-10 11:03 0.1 DJSULL1

Magnesium (Mg) 717 mg/L EPA 200.7 16-Dec-10 11:03 0.05 DJSULL1

Manganese (Mn) 3.63 mg/L EPA 200.7 16-Dec-10 11:03 0.05 DJSULL1

Molybdenum (Mo) < 0.05 mg/L EPA 200.7 16-Dec-10 11:03 0.05 DJSULL1

Sodium (Na) 44.7 mg/L EPA 200.7 16-Dec-10 11:03 0.5 DJSULL1

Tin (Sn) < 0.5 mg/L EPA 200.7 16-Dec-10 11:03 0.5 DJSULL1

Titanium (Ti) < 0.05 mg/L EPA 200.7 16-Dec-10 11:03 0.05 DJSULL1

TOTAL RECOVERABLE METALS BY ICP-MS

Antimony (Sb) < 10 ug/L EPA 200.8 21-Dec-10 13:19 10 KRICHAR

Arsenic (As) < 10 ug/L 10 EPA 200.8 21-Dec-10 13:19 KRICHAR

Cadmium (Cd) < 10 ug/L 10 EPA 200.8 21-Dec-10 13:19 KRICHAR

Chromium (Cr) < 10 ug/L 10 EPA 200.8 21-Dec-10 13:19 KRICHAR

Copper (Cu) < 10 ug/L 10 EPA 200.8 21-Dec-10 13:19 KRICHAR

Lead (Pb) < 10 ug/L 10 EPA 200.8 21-Dec-10 13:19 KRICHAR

Nickel (Ni) 15.4 ug/L 10 EPA 200.8 21-Dec-10 13:19 KRICHAR

Selenium (Se) 231 ug/L 10 EPA 200.8 21-Dec-10 13:19 KRICHAR

Silver (Ag) < 10 ug/L 10 EPA 200.8 21-Dec-10 13:19 KRICHAR

Thallium (Tl) < 10 ug/L 10 EPA 200.8 21-Dec-10 13:19 KRICHAR

Vanadium (V) < 10 ug/L 10 EPA 200.8 21-Dec-10 13:19 KRICHAR

Zinc (Zn) < 20 ug/L 20 EPA 200.8 21-Dec-10 13:19 KRICHAR

2010012858

Collection Date: 08-Dec-10 10:15 AM

Site: BIOREACTOR 2 EFF. 

Matrix: OTHER

Analyte Result Units Qualifiers RDL Method Analysis Date/Time

Sample #:

Analyst

MERCURY (COLD VAPOR) IN WATER

Mercury (Hg) < 1 ug/L EPA 245.1 16-Dec-10 02:05 1 MHH7131

TOTAL RECOVERABLE METALS BY ICP

Aluminum (Al) 1.46 mg/L EPA 200.7 16-Dec-10 11:07 0.05 DJSULL1

Barium (Ba) 0.434 mg/L 0.05 EPA 200.7 16-Dec-10 11:07 DJSULL1

Beryllium (Be) < 0.05 mg/L 0.05 EPA 200.7 16-Dec-10 11:07 DJSULL1

Boron (B) 163 mg/L 0.5 EPA 200.7 16-Dec-10 11:07 DJSULL1

Calcium (Ca) 4010 mg/L 0.1 EPA 200.7 16-Dec-10 11:07 DJSULL1

Cobalt (Co) < 0.05 mg/L 0.05 EPA 200.7 16-Dec-10 11:07 DJSULL1

Iron (Fe) < 0.1 mg/L 0.1 EPA 200.7 16-Dec-10 11:07 DJSULL1

Magnesium (Mg) 733 mg/L 0.05 EPA 200.7 16-Dec-10 11:07 DJSULL1

Manganese (Mn) 3.29 mg/L 0.05 EPA 200.7 16-Dec-10 11:07 DJSULL1

Molybdenum (Mo) < 0.05 mg/L 0.05 EPA 200.7 16-Dec-10 11:07 DJSULL1

Sodium (Na) 45.2 mg/L 0.5 EPA 200.7 16-Dec-10 11:07 DJSULL1

Analytical Laboratory 

Page 7 of 23
Certificate of Laboratory Analysis

This report shall not be reproduced, except in full.

Order # J10120055

2010012858

Collection Date: 08-Dec-10 10:15 AM

Site: BIOREACTOR 2 EFF. 

Matrix: OTHER

Analyte Result Units Qualifiers RDL Method Analysis Date/Time

Sample #:

Analyst

TOTAL RECOVERABLE METALS BY ICP

Tin (Sn) < 0.5 mg/L EPA 200.7 16-Dec-10 11:07 0.5 DJSULL1

Titanium (Ti) < 0.05 mg/L EPA 200.7 16-Dec-10 11:07 0.05 DJSULL1

TOTAL RECOVERABLE METALS BY ICP-MS

Antimony (Sb) < 5 ug/L EPA 200.8 21-Dec-10 13:14 5 KRICHAR

Arsenic (As) < 5 ug/L 5 EPA 200.8 21-Dec-10 13:14 KRICHAR

Cadmium (Cd) < 5 ug/L 5 EPA 200.8 21-Dec-10 13:14 KRICHAR

Chromium (Cr) < 5 ug/L 5 EPA 200.8 21-Dec-10 13:14 KRICHAR

Copper (Cu) < 5 ug/L 5 EPA 200.8 21-Dec-10 13:14 KRICHAR

Lead (Pb) < 5 ug/L 5 EPA 200.8 21-Dec-10 13:14 KRICHAR

Nickel (Ni) < 5 ug/L 5 EPA 200.8 21-Dec-10 13:14 KRICHAR

Selenium (Se) 26.7 ug/L 5 EPA 200.8 21-Dec-10 13:14 KRICHAR

Silver (Ag) < 5 ug/L 5 EPA 200.8 21-Dec-10 13:14 KRICHAR

Thallium (Tl) < 5 ug/L 5 EPA 200.8 21-Dec-10 13:14 KRICHAR

Vanadium (V) < 5 ug/L 5 EPA 200.8 21-Dec-10 13:14 KRICHAR

Zinc (Zn) < 10 ug/L 10 EPA 200.8 21-Dec-10 13:14 KRICHAR

SELENIUM SPECIATION

Vendor Parameter Complete V_AS&C

2010012859

Collection Date: 01-Dec-10 2:00 PM

Site: Trip Blank 

Matrix: OTHER

Analyte Result Units Qualifiers RDL Method Analysis Date/Time

Sample #:

Analyst

TOTAL RECOVERABLE METALS BY ICP

Aluminum (Al) < 0.005 mg/L EPA 200.7 16-Dec-10 10:27 0.005 DJSULL1

Barium (Ba) < 0.005 mg/L EPA 200.7 16-Dec-10 10:27 0.005 DJSULL1

Beryllium (Be) < 0.005 mg/L EPA 200.7 16-Dec-10 10:27 0.005 DJSULL1

Boron (B) < 0.05 mg/L 0.05 EPA 200.7 16-Dec-10 10:27 DJSULL1

Calcium (Ca) 0.014 mg/L 0.01 EPA 200.7 16-Dec-10 10:27 DJSULL1

Cobalt (Co) < 0.005 mg/L 0.005 EPA 200.7 16-Dec-10 10:27 DJSULL1

Iron (Fe) < 0.01 mg/L 0.01 EPA 200.7 16-Dec-10 10:27 DJSULL1

Magnesium (Mg) < 0.005 mg/L 0.005 EPA 200.7 16-Dec-10 10:27 DJSULL1

Manganese (Mn) < 0.005 mg/L 0.005 EPA 200.7 16-Dec-10 10:27 DJSULL1

Molybdenum (Mo) < 0.005 mg/L 0.005 EPA 200.7 16-Dec-10 10:27 DJSULL1

Sodium (Na) < 0.05 mg/L 0.05 EPA 200.7 16-Dec-10 10:27 DJSULL1

Tin (Sn) < 0.05 mg/L 0.05 EPA 200.7 16-Dec-10 10:27 DJSULL1

Titanium (Ti) < 0.005 mg/L 0.005 EPA 200.7 16-Dec-10 10:27 DJSULL1

TOTAL RECOVERABLE METALS BY ICP-MS

Antimony (Sb) < 1 ug/L EPA 200.8 21-Dec-10 13:08 1 KRICHAR

Arsenic (As) < 1 ug/L 1 EPA 200.8 21-Dec-10 13:08 KRICHAR

Analytical Laboratory 

Page 8 of 23
Certificate of Laboratory Analysis

This report shall not be reproduced, except in full.

Order # J10120055

2010012859

Collection Date: 01-Dec-10 2:00 PM

Site: Trip Blank 

Matrix: OTHER

Analyte Result Units Qualifiers RDL Method Analysis Date/Time

Sample #:

Analyst

TOTAL RECOVERABLE METALS BY ICP-MS

Cadmium (Cd) < 1 ug/L EPA 200.8 21-Dec-10 13:08 1 KRICHAR

Chromium (Cr) < 1 ug/L EPA 200.8 21-Dec-10 13:08 1 KRICHAR

Copper (Cu) < 1 ug/L EPA 200.8 21-Dec-10 13:08 1 KRICHAR

Lead (Pb) < 1 ug/L EPA 200.8 21-Dec-10 13:08 1 KRICHAR

Nickel (Ni) < 1 ug/L EPA 200.8 21-Dec-10 13:08 1 KRICHAR

Selenium (Se) 1.36 ug/L EPA 200.8 21-Dec-10 13:08 1 KRICHAR

Silver (Ag) < 1 ug/L EPA 200.8 21-Dec-10 13:08 1 KRICHAR

Thallium (Tl) < 1 ug/L EPA 200.8 21-Dec-10 13:08 1 KRICHAR

Vanadium (V) < 1 ug/L EPA 200.8 21-Dec-10 13:08 1 KRICHAR

Zinc (Zn) < 2 ug/L EPA 200.8 21-Dec-10 13:08 2 KRICHAR

SELENIUM SPECIATION

Vendor Parameter Complete V_AS&C

2010012860

Collection Date: 08-Dec-10 10:50 AM

Site: FILTER BLANK 

Matrix: OTHER

Analyte Result Units Qualifiers RDL Method Analysis Date/Time

Sample #:

Analyst

DISSOLVED METALS BY ICP-MS

Selenium (Se) 4.96 ug/L EPA 200.8 27-Dec-10 14:33 2 KRICHAR

Analytical Laboratory 

Page 9 of 23
 

December 19, 2010 

Jay Perkins 

Duke Energy Analytical Laboratory 

Mail Code MGO3A2 (Building 7405) 

13339 Hagers Ferry Rd. 

Huntersville, NC 28078 

(704) 875-5245 

Project: Belews – FGD WWTS (2010, Bi-Weekly Sampling) (LIMS # J10120055) 

Dear Mr. Perkins, 

Attached is the report associated with four (4) aqueous samples submitted for selenium 

speciation analysis on December 9, 2010. The samples were received on December 10, 

2010 in a sealed cooler at -0.4o

C. Selenium speciation analysis was performed via ion 

chromatography inductively coupled plasma dynamic reaction cell mass spectrometry 

(IC-ICP-DRC-MS). Any analytical issues associated with the analysis are addressed in 

the following report. 

If you have any questions, please feel free to contact me at your convenience. 

 Sincerely, 

 

 Russell Gerads 

 Vice President 

 Applied Speciation and Consulting, LLC 

Analytical Laboratory 

Page 10 of 23
Applied Speciation and Consulting, LLC 

Report prepared for: 

Jay Perkins 

Duke Energy Analytical Laboratory 

Mail Code MGO3A2 (Building 7405) 

13339 Hagers Ferry Rd. 

Huntersville, NC 28078 

Project: Belews – FGD WWTS (2010, Bi-Weekly Sampling) (LIMS # J10120055) 

December 19, 2010 

1. Sample Reception 

Four (4) aqueous samples in 125mL HDPE bottles (provided by Applied Speciation 

and Consulting) were submitted for selenium speciation analysis on December 9, 

2010. The samples were received on December 10, 2010 in a sealed container at -

0.4o

C. 

The samples were received in a laminar flow clean hood void of trace metals 

contamination and ultra-violet radiation. Upon reception, the samples were 

designated discrete sample identifiers. An aliquot of each sample was filtered 

(0.45μm) and these filtrates were stored in a secure, monitored cryofreezer 

(maintained at a temperature of -80o

C) until selenium speciation analysis could be 

performed via ion chromatography inductively coupled plasma dynamic reaction cell 

mass spectrometry (IC-ICP-DRC-MS). 

2. Sample Preparation 

All sample preparation is performed in laminar flow clean hoods known to be free 

from trace metals contamination. All applied water for dilutions and sample 

preservatives are monitored for contamination to account for any biases associated 

with the sample results. 

Selenium Speciation Analysis by IC-ICP-DRC-MS Prior to analysis, an aliquot of 

each sample was filtered with a syringe filter (0.45μm) and injected directly into a 

sealed autosampler vial. No further sample preparation was performed as any 

chemical alteration of the samples may shift the equilibrium of the system resulting in 

changes in speciation ratios. 

Analytical Laboratory 

Page 11 of 23
3. Sample Analysis 

All sample analysis is precluded by a minimum of a five-point calibration curve 

spanning the entire concentration range of interest. Calibration curves are performed 

at the beginning of each analytical day. All calibration curves, associated with each 

species of interest, are standardized by linear regression resulting in a response factor. 

All sample results are instrument blank corrected to account for any operational 

biases associated with the analytical platform. 

Prior to sample analysis, all calibration curves are verified using second source 

standards which are identified as initial calibration verification standards (ICV). 

Ongoing instrument performance is identified by the analysis of continuing 

calibration verification standards (CCV) and continuing calibration blanks (CCB) at a 

minimal interval of every ten analytical runs. 

Selenium Speciation Analysis by IC-ICP-DRC-MS All samples for selenium 

speciation analysis were analyzed by ion chromatography inductively coupled plasma 

dynamic reaction cell mass spectrometry (IC-ICP-DRC-MS) on December 15, 2010. 

An aliquot of each sample is injected onto an anion exchange column and mobilized 

by a basic (pH > 7) gradient. The eluting selenium species are then introduced into a 

radio frequency (RF) plasma where energy-transfer processes cause desolvation, 

atomization, and ionization. The ions are extracted from the plasma through a 

differentially-pumped vacuum interface and travel through a pressurized chamber 

(DRC) containing a specific reactive gas which preferentially reacts with interfering 

ions of the same target mass to charge ratios (m/z). A solid-state detector detects ions 

transmitted through the mass analyzer and the resulting current is processed by a data 

handling system. 

Retention times for each eluting species are compared to known standards for species 

identification. 

4. Analytical Issues 

The overall analyses went very well and no analytical issues were encountered. All 

quality control parameters associated with these samples were within acceptance 

limits. 

The estimated method detection limits (eMDLs) for selenite, selenate, and 

selenocyanate are generated from replicate analyses of the lowest standard in the 

calibration curve. Not all selenium species are present in preparation blanks; 

therefore, eMDL calculations based on preparation blanks are artificially biased low. 

The eMDL for methylseleninic acid and selenomethionine is calculated from the 

average eMDL of selenite, selenate, and selenocyanate. The calibration does not 

Analytical Laboratory 

Page 12 of 23
contain methylseleninic acid or selenomethionine due to impurities in these standards 

which would bias the results for other selenium species. 

If you have any questions or concerns regarding this report, please feel free to contact 

me. 

Sincerely, 

Russell Gerads 

Vice President 

Applied Speciation and Consulting, LLC 

Analytical Laboratory 

Page 13 of 23
Sample Results

Sample ID Se(IV) Se(VI) SeCN MeSe(IV) SeMe

Unkn

Spec

FGD Purge Eff 36.0 1740 ND (<0.77) ND (<1.2) ND (<1.2) 0 BioReactor 1 Inf 13.5 662 ND (<0.19) 1.66 ND (<0.29) 0 BioReactor 2 Eff 0.75 31.1 ND (<0.19) ND (<0.29) ND (<0.29) 0 

Metals Trip Blk ND (<0.039) ND (<0.097) ND (<0.038) ND (<0.058) ND (<0.058) 0 All results reflect the applied dilution and are reported in μg/LND = Not detected at the applied dilutionSeCN = SelenocyanateMeSe(IV) = Methylseleninic acidSeMe = SelenomethionineUnknown Se Species = Total concentration of all unknown Se species observed by IC-ICP-MSn = number of unknown Se species observed

Report Generated by: Russell Gerads

Applied Speciation and Consulting, LLC

Selenium Speciation Results for Duke Energy

Project Name: Belews - FGD WWTS (2010, Bi-Weekly Sampling)

Contact: Jay Perkins

Date: December 19, 2010

LIMS #J10120055
Quality Control Summary - Preparation Blank Summary

Analyte (μg/L) PBW1 PBW2 PBW3 PBW4 Mean StdDev eMDL* eMDL 10x eSe(IV) 0.000 0.000 0.000 0.000 0.000 0.000 0.004 0.039 Se(VI) 0.000 0.000 0.000 0.000 0.000 0.000 0.010 0.097 SeCN 0.000 0.000 0.000 0.000 0.000 0.000 0.004 0.038 MeSe(IV) 0.000 0.000 0.000 0.000 0.000 0.000 0.006 0.058 SeMe 0.000 0.000 0.000 0.000 0.000 0.000 0.006 0.058 eMDL = Estimated Method Detection Limit*Please see narrative regarding eMDL calculationsQuality Control Summary - Certified Reference MaterialsAnalyte (μg/L) CRM True Value Result RecoverySe(IV) ICV 9.57 9.24 96.5Se(VI) ICV 9.48 8.59 90.6SeCN ICV 8.92 8.35 93.7MeSe(IV) ICV 6.47 5.51 85.2SeMe ICV 9.32 9.00 96.5

Selenium Speciation Results for Duke Energy

Project Name: Belews - FGD WWTS (2010, Bi-Weekly Sampling)

Contact: Jay Perkins

LIMS #J10120055

Date: December 19, 2010

Report Generated by: Russell Gerads

Applied Speciation and Consulting, LLC
Quality Control Summary - Matrix Duplicates

Analyte (μg/L) Sample ID Rep 1 Rep 2 Mean RPDSe(IV) Batch QC 0.803 0.554 0.678 36.7*Se(VI) Batch QC ND (<0.48) ND (<0.48) NC NCSeCN Batch QC ND (<0.19) ND (<0.19) NC NCMeSe(IV) Batch QC ND (<0.29) ND (<0.29) NC NCSeMe Batch QC ND (<0.29) ND (<0.29) NC NCND = Not detected at the applied dilutionNC = Value was not calculated due to one or more concentrations below the eMDL *Sample concentration is within 10x the eMDLQuality Control Summary - Matrix Spike/ Matrix Spike DuplicateAnalyte (μg/L) Sample ID Spike Conc MS Result Recovery Spike Conc MSD Result Recovery RPDSe(IV) Batch QC 278.0 450.3 161.7 278.0 492.7 177.0 9.0Se(VI) Batch QC 252.3 279.8 110.9 252.3 285.5 113.2 2.0SeCN Batch QC 228.8 1.5 0.6** 228.8 0.8 0.4** 57.9**The low recovery is attributed to sample induced species conversion

Selenium Speciation Results for Duke Energy

Project Name: Belews - FGD WWTS (2010, Bi-Weekly Sampling)

Contact: Jay Perkins

LIMS #J10120055

Date: December 19, 2010

Report Generated by: Russell Gerads

Applied Speciation and Consulting, LLC
Analytical Laboratory 

Page 17 of 23
This data package contains the analytical results for the project identified above and includes a Case Narrative, Sample 

Results and Chain of Custody. Unless otherwise noted, all samples were received in acceptable condition and processed 

according to the referenced methods. 

Data qualifiers are flagged individually on each sample. A key reference for the data qualifiers appears at the end of this case 

narrative.

NC Certification No. 402

SC Certification No. 99012

NC Drinking Water Cert No. 37735

Case Narrative

12/20/2010

Duke Energy Corporation

Jay Perkins

13339 Hagers Ferry Road

Huntersville, NC 28078

Project: Belews - FGD WWTS (Bi-Weekly Sampling)

Project No.: J10120055

Lab Submittal Date: 12/09/2010

Prism Work Order: 0120298

Please call if you have any questions relating to this analytical report.

Respectfully,

PRISM LABORATORIES, INC.

VP Laboratory Services Reviewed By

Data Qualifiers Key Reference:

MDL Method Detection Limit

BRL Below Reporting Limit

RPD Relative Percent Difference

*

Results reported to the reporting limit. All other results are reported to the MDL with values between MDL and 

reporting limit indicated with a J.

This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.

449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543

Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 1 of 5

Analytical Laboratory 

Page 18 of 23
Sample Receipt Summary

12/20/2010

Prism Work Order: 0120298

Client Sample ID Lab Sample ID Matrix Date Sampled Date Received

2010012854/FGD Purge EFF 0120298-01 Water 12/08/10 12/09/10

Samples received in good condition at 1.0 degrees C unless otherwise noted.

This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.

449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543

Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 2 of 5

Analytical Laboratory 

Page 19 of 23
Laboratory Report

12/20/2010

Parameter Result Batch

ID

Report

Limit

Analysis

Date/Time

Dilution Method

Factor

Units MDL Analyst

13339 Hagers Ferry Road Project No.: J10120055

Project: Belews - FGD WWTS 

(Bi-Weekly Sampling)

Duke Energy Corporation

Huntersville, NC 28078

Attn: Jay Perkins

Sample Matrix: Water

Client Sample ID: 2010012854/FGD Purge E

Prism Sample ID: 0120298-01

Prism Work Order: 0120298

Time Collected: 12/08/10 10:02

Time Submitted: 12/09/10 15:50

General Chemistry Parameters

Total Dissolved Solids 16000 mg/L 50 8.7 1 *SM2540 C 12/14/10 14:00 JAB P0L0288

This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.

449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543

Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 3 of 5

Analytical Laboratory 

Page 20 of 23
12/20/10

Level II QC Report

13339 Hagers Ferry Road Project No: J10120055

Project: Belews - FGD WWTS 

(Bi-Weekly Sampling)

Duke Energy Corporation

Huntersville, NC 28078

Attn: Jay Perkins

Prism Work Order: 0120298

Time Submitted: 12/9/10 3:50:00PM

Result Limit

Reporting

Units Level

Spike

Result

Source

%REC

%REC

Limits RPD

RPD

 Analyte Limit Notes 

General Chemistry Parameters - Quality Control

Batch P0L0288 - NO PREP

Blank (P0L0288-BLK1) Prepared & Analyzed: 12/14/10 

Total Dissolved Solids BRL 50 mg/L

LCS (P0L0288-BS1) Prepared & Analyzed: 12/14/10 

Total Dissolved Solids 998 50 mg/L 1000 100 90-110

Sample Extraction Data

NO PREP

Lab Number Batch Initial Final Date

0120298-01 P0L0288 50 mL 50 mL 12/14/10

This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.

449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543

Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 4 of 5

Analytical Laboratory 

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Analytical Laboratory 

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