## 13339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone: 980-875-5245 Fax: 980-875-4349 

# Order Summary Report

Analytical Laboratory

Order Number: J10120055

Lab Contact: Jason C Perkins


## Date: 1/2/2011 Customer Address: 3195 Pine Hall Rd Customer Name(s): Bill Kennedy, Melonie Martin, Wayne Chapman, Tom Johnson

Mailcode: Belews Steam Station Belews Creek, NC 28012

Phone: 980-875-5348
Report Authorized By: (Signature)



## Program Comments: Belews Biweekly Smapling - 12/8 Ca and Se were detected in the trip blank and Se was also detedted in the filter blank. All actual samples had Ca and Se above 10 times the trip and filter blank concentrations so data is OK to report without qualifiers. Data Flags & Calculations: Any analytical tests or individual analytes within a test flagged with an "X" or "1" indicate a deviation from the method quali ty system or quality control requirement. All results ar e reported on a dry weight basis unless otherwise noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimatio n of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, ex cept in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub-contracted Labora tory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Te st Case Narratives, C hain of Custody (COC)
Certification: The Analytical Laboratory holds the followi ng State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laborat ory for definitive information abou t the certification status of specific methods.

## Sample ID's & Descriptions:
Sample ID Plant/Station Collection Date and Time Collected By Sample Description 2010012854 BELEWS 08-Dec-10 10:02 AM ILLEGIBLE FGD PURGE EFF. 2010012855 BELEWS 08-Dec-10 10:05 AM ILLEGIBLE EQ TANK EFF. 2010012856 BELEWS 08-Dec-10 10:07 AM ILLEGIBLE BIOREACTOR 1 INF. 2010012857 BELEWS 08-Dec-10 10:11 AM ILLEGIBLE BIOREACTOR 2 INF. 2010012858 BELEWS 08-Dec-10 10:15 AM ILLEGIBLE BIOREACTOR 2 EFF. 2010012859 BELEWS 01-Dec-10 2:00 PM C.KNOX Trip Blank 2010012860 BELEWS 08-Dec-10 10:50 AM ILLEGIBLE FILTER BLANK 7 Total Samples

### COC and .pdf report are in agreement with sample totals and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. All laboratory QA/QC requirements are acceptable. The Vendor Laboratories have been qualified by the Analytical Laboratory Yes No 

# Technical Validation Review Checklist:

Yes No

Yes No



## Report Sections Included:
Job Summary Report Sub-contracted Laboratory Results Sample Identification Customer Specific Data Sheets, Reports, & Documentation Technical Validation of Data Package Customer Database Entries Analytical Laboratory Certificate of Analysis Test Case Narratives Analytical Laboratory QC Report Chain of Custody

Reviewed By: 

### Jenny A Herman Date: 

### 12/31/2010 Yes

Electronic Data Deliverable (EDD) Sent Separately

# Certificate of Laboratory Analysis This re p ort shall not be re p roduced, exce p t in full. 

## Order # J10120055

2010012854 Collection Date: 08-Dec-10 10:02 AM 

### Site: FGD PURGE EFF. Matrix: OTHER

Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

### Sam p le #:

Analyst MERCURY (COLD VAPOR) IN WATER Mercury (Hg) 191 ug/L EPA 245.1 16-Dec-10 14:00 5 MHH7131
TOTAL RECOVERABLE METALS BY ICP Aluminum (Al) 179 mg/L EPA 200.7 16-Dec-10 10:51 0.05 DJSULL1 Barium (Ba) 2.22 mg/L EPA 200.7 16-Dec-10 10:51 0.05 DJSULL1 Beryllium (Be) < 0.05 mg/L EPA 200.7 16-Dec-10 10:51 0.05 DJSULL1 Boron (B) 198 mg/L EPA 200.7 16-Dec-10 10:51 0.5 DJSULL1 Calcium (Ca) 4850 mg/L EPA 200.7 16-Dec-10 10:51 0.1 DJSULL1 Cobalt (Co) 0.208 mg/L EPA 200.7 16-Dec-10 10:51 0.05 DJSULL1 Iron (Fe) 135 mg/L EPA 200.7 16-Dec-10 10:51 0.1 DJSULL1 Magnesium (Mg) 767 mg/L EPA 200.7 16-Dec-10 10:51 0.05 DJSULL1 Manganese (Mn) 8.32 mg/L EPA 200.7 16-Dec-10 10:51 0.05 DJSULL1 Molybdenum (Mo) 0.082 mg/L EPA 200.7 16-Dec-10 10:51 0.05 DJSULL1 Sodium (Na) 49.2 mg/L EPA 200.7 16-Dec-10 10:51 0.5 DJSULL1 Tin (Sn) < 0.5 mg/L EPA 200.7 16-Dec-10 10:51 0.5 DJSULL1 Titanium (Ti) 5.31 mg/L EPA 200.7 16-Dec-10 10:51 0.05 DJSULL1
DISSOLVED METALS BY ICP-MS Selenium (Se) 1660 ug/L EPA 200.8 27-Dec-10 14:22 10 KRICHAR
TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) 28.0 ug/L EPA 200.8 21-Dec-10 13:35 10 KRICHAR Arsenic (As) 273 ug/L EPA 200.8 21-Dec-10 13:35 10 KRICHAR Cadmium (Cd) < 10 ug/L EPA 200.8 21-Dec-10 13:35 10 KRICHAR Chromium (Cr) 374 ug/L EPA 200.8 21-Dec-10 13:35 10 KRICHAR Copper (Cu) 315 ug/L EPA 200.8 21-Dec-10 13:35 10 KRICHAR Lead (Pb) 356 ug/L EPA 200.8 21-Dec-10 13:35 10 KRICHAR Nickel (Ni) 370 ug/L EPA 200.8 21-Dec-10 13:35 10 KRICHAR Selenium (Se) 7000 ug/L EPA 200.8 21-Dec-10 13:35 500 KRICHAR Silver (Ag) < 10 ug/L EPA 200.8 21-Dec-10 13:35 10 KRICHAR Thallium (Tl) 11.2 ug/L EPA 200.8 21-Dec-10 13:35 10 KRICHAR Vanadium (V) 614 ug/L EPA 200.8 21-Dec-10 13:35 10 KRICHAR Zinc (Zn) 583 ug/L EPA 200.8 21-Dec-10 13:35 20 KRICHAR
SELENIUM SPECIATION Vendor Parameter Complete V_AS&C
TOTAL DISSOLVED SOLIDS Vendor Parameter Complete V_PRISM

# Certificate of Laboratory Analysis This re p ort shall not be re p roduced, exce p t in full. 

## Order # J10120055

2010012855 Collection Date: 08-Dec-10 10:05 AM 

### Site: EQ TANK EFF. Matrix: OTHER

Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

### Sam p le #:

Analyst MERCURY (COLD VAPOR) IN WATER Mercury (Hg) 149 ug/L EPA 245.1 16-Dec-10 14:03 2.5 MHH7131
TOTAL RECOVERABLE METALS BY ICP Aluminum (Al) 147 mg/L EPA 200.7 16-Dec-10 10:55 0.05 DJSULL1 Barium (Ba) 1.86 mg/L EPA 200.7 16-Dec-10 10:55 0.05 DJSULL1 Beryllium (Be) < 0.05 mg/L EPA 200.7 16-Dec-10 10:55 0.05 DJSULL1 Boron (B) 175 mg/L EPA 200.7 16-Dec-10 10:55 0.5 DJSULL1 Calcium (Ca) 4500 mg/L EPA 200.7 16-Dec-10 10:55 0.1 DJSULL1 Cobalt (Co) 0.163 mg/L EPA 200.7 16-Dec-10 10:55 0.05 DJSULL1 Iron (Fe) 112 mg/L EPA 200.7 16-Dec-10 10:55 0.1 DJSULL1 Magnesium (Mg) 683 mg/L EPA 200.7 16-Dec-10 10:55 0.05 DJSULL1 Manganese (Mn) 7.25 mg/L EPA 200.7 16-Dec-10 10:55 0.05 DJSULL1 Molybdenum (Mo) 0.068 mg/L EPA 200.7 16-Dec-10 10:55 0.05 DJSULL1 Sodium (Na) 43.1 mg/L EPA 200.7 16-Dec-10 10:55 0.5 DJSULL1 Tin (Sn) < 0.5 mg/L EPA 200.7 16-Dec-10 10:55 0.5 DJSULL1 Titanium (Ti) 4.06 mg/L EPA 200.7 16-Dec-10 10:55 0.05 DJSULL1
DISSOLVED METALS BY ICP-MS Selenium (Se) 939 ug/L EPA 200.8 27-Dec-10 14:26 10 KRICHAR
TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) 24.7 ug/L EPA 200.8 21-Dec-10 13:30 10 KRICHAR Arsenic (As) 233 ug/L EPA 200.8 21-Dec-10 13:30 10 KRICHAR Cadmium (Cd) < 10 ug/L EPA 200.8 21-Dec-10 13:30 10 KRICHAR Chromium (Cr) 319 ug/L EPA 200.8 21-Dec-10 13:30 10 KRICHAR Copper (Cu) 266 ug/L EPA 200.8 21-Dec-10 13:30 10 KRICHAR Lead (Pb) 295 ug/L EPA 200.8 21-Dec-10 13:30 10 KRICHAR Nickel (Ni) 329 ug/L EPA 200.8 21-Dec-10 13:30 10 KRICHAR Selenium (Se) 5920 ug/L EPA 200.8 21-Dec-10 13:30 500 KRICHAR Silver (Ag) < 10 ug/L EPA 200.8 21-Dec-10 13:30 10 KRICHAR Thallium (Tl) < 10 ug/L EPA 200.8 21-Dec-10 13:30 10 KRICHAR Vanadium (V) 504 ug/L EPA 200.8 21-Dec-10 13:30 10 KRICHAR Zinc (Zn) 498 ug/L EPA 200.8 21-Dec-10 13:30 20 KRICHAR 

### 2010012856 Collection Date: 08-Dec-10 10:07 AM 

### Site: BIOREACTOR 1 INF. Matrix: OTHER

Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

### Sam p le #:

Analyst TOTAL RECOVERABLE METALS BY ICP Aluminum (Al) 1.39 mg/L EPA 200.7 16-Dec-10 10:59 0.05 DJSULL1 Barium (Ba) 0.420 mg/L EPA 200.7 16-Dec-10 10:59 0.05 DJSULL1 Beryllium (Be) < 0.05 mg/L EPA 200.7 16-Dec-10 10:59 0.05 DJSULL1

# Certificate of Laboratory Analysis This re p ort shall not be re p roduced, exce p t in full. 

## Order # J10120055

2010012856 Collection Date: 08-Dec-10 10:07 AM 

### Site: BIOREACTOR 1 INF. Matrix: OTHER

Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

### Sam p le #:

Analyst TOTAL RECOVERABLE METALS BY ICP Boron (B) 175 mg/L EPA 200.7 16-Dec-10 10:59 0.5 DJSULL1 Calcium (Ca) 3880 mg/L EPA 200.7 16-Dec-10 10:59 0.1 DJSULL1 Cobalt (Co) < 0.05 mg/L EPA 200.7 16-Dec-10 10:59 0.05 DJSULL1 Iron (Fe) < 0.1 mg/L EPA 200.7 16-Dec-10 10:59 0.1 DJSULL1 Magnesium (Mg) 677 mg/L EPA 200.7 16-Dec-10 10:59 0.05 DJSULL1 Manganese (Mn) 3.53 mg/L EPA 200.7 16-Dec-10 10:59 0.05 DJSULL1 Molybdenum (Mo) < 0.05 mg/L EPA 200.7 16-Dec-10 10:59 0.05 DJSULL1 Sodium (Na) 43.0 mg/L EPA 200.7 16-Dec-10 10:59 0.5 DJSULL1 Tin (Sn) < 0.5 mg/L EPA 200.7 16-Dec-10 10:59 0.5 DJSULL1 Titanium (Ti) < 0.05 mg/L EPA 200.7 16-Dec-10 10:59 0.05 DJSULL1
DISSOLVED METALS BY ICP-MS Selenium (Se) 646 ug/L EPA 200.8 27-Dec-10 14:29 10 KRICHAR
TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 10 ug/L EPA 200.8 21-Dec-10 13:24 10 KRICHAR Arsenic (As) < 10 ug/L EPA 200.8 21-Dec-10 13:24 10 KRICHAR Cadmium (Cd) < 10 ug/L EPA 200.8 21-Dec-10 13:24 10 KRICHAR Chromium (Cr) < 10 ug/L EPA 200.8 21-Dec-10 13:24 10 KRICHAR Copper (Cu) < 10 ug/L EPA 200.8 21-Dec-10 13:24 10 KRICHAR Lead (Pb) < 10 ug/L EPA 200.8 21-Dec-10 13:24 10 KRICHAR Nickel (Ni) 75.5 ug/L EPA 200.8 21-Dec-10 13:24 10 KRICHAR Selenium (Se) 616 ug/L EPA 200.8 21-Dec-10 13:24 10 KRICHAR Silver (Ag) < 10 ug/L EPA 200.8 21-Dec-10 13:24 10 KRICHAR Thallium (Tl) < 10 ug/L EPA 200.8 21-Dec-10 13:24 10 KRICHAR Vanadium (V) < 10 ug/L EPA 200.8 21-Dec-10 13:24 10 KRICHAR Zinc (Zn) < 20 ug/L EPA 200.8 21-Dec-10 13:24 20 KRICHAR
SELENIUM SPECIATION Vendor Parameter Complete V_AS&C 

### 2010012857 Collection Date: 08-Dec-10 10:11 AM 

### Site: BIOREACTOR 2 INF. Matrix: OTHER

Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

### Sam p le #:

Analyst TOTAL RECOVERABLE METALS BY ICP Aluminum (Al) 1.45 mg/L EPA 200.7 16-Dec-10 11:03 0.05 DJSULL1 Barium (Ba) 0.430 mg/L EPA 200.7 16-Dec-10 11:03 0.05 DJSULL1 Beryllium (Be) < 0.05 mg/L EPA 200.7 16-Dec-10 11:03 0.05 DJSULL1 Boron (B) 172 mg/L EPA 200.7 16-Dec-10 11:03 0.5 DJSULL1 Calcium (Ca) 4000 mg/L EPA 200.7 16-Dec-10 11:03 0.1 DJSULL1 Cobalt (Co) < 0.05 mg/L EPA 200.7 16-Dec-10 11:03 0.05 DJSULL1

# Certificate of Laboratory Analysis This re p ort shall not be re p roduced, exce p t in full. 

## Order # J10120055

2010012857 Collection Date: 08-Dec-10 10:11 AM 

### Site: BIOREACTOR 2 INF. Matrix: OTHER

Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

### Sam p le #:

Analyst TOTAL RECOVERABLE METALS BY ICP Iron (Fe) 0.311 mg/L EPA 200.7 16-Dec-10 11:03 0.1 DJSULL1 Magnesium (Mg) 717 mg/L EPA 200.7 16-Dec-10 11:03 0.05 DJSULL1 Manganese (Mn) 3.63 mg/L EPA 200.7 16-Dec-10 11:03 0.05 DJSULL1 Molybdenum (Mo) < 0.05 mg/L EPA 200.7 16-Dec-10 11:03 0.05 DJSULL1 Sodium (Na) 44.7 mg/L EPA 200.7 16-Dec-10 11:03 0.5 DJSULL1 Tin (Sn) < 0.5 mg/L EPA 200.7 16-Dec-10 11:03 0.5 DJSULL1 Titanium (Ti) < 0.05 mg/L EPA 200.7 16-Dec-10 11:03 0.05 DJSULL1
TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 10 ug/L EPA 200.8 21-Dec-10 13:19 10 KRICHAR Arsenic (As) < 10 ug/L EPA 200.8 21-Dec-10 13:19 10 KRICHAR Cadmium (Cd) < 10 ug/L EPA 200.8 21-Dec-10 13:19 10 KRICHAR Chromium (Cr) < 10 ug/L EPA 200.8 21-Dec-10 13:19 10 KRICHAR Copper (Cu) < 10 ug/L EPA 200.8 21-Dec-10 13:19 10 KRICHAR Lead (Pb) < 10 ug/L EPA 200.8 21-Dec-10 13:19 10 KRICHAR Nickel (Ni) 15.4 ug/L EPA 200.8 21-Dec-10 13:19 10 KRICHAR Selenium (Se) 231 ug/L EPA 200.8 21-Dec-10 13:19 10 KRICHAR Silver (Ag) < 10 ug/L EPA 200.8 21-Dec-10 13:19 10 KRICHAR Thallium (Tl) < 10 ug/L EPA 200.8 21-Dec-10 13:19 10 KRICHAR Vanadium (V) < 10 ug/L EPA 200.8 21-Dec-10 13:19 10 KRICHAR Zinc (Zn) < 20 ug/L EPA 200.8 21-Dec-10 13:19 20 KRICHAR 

### 2010012858 Collection Date: 08-Dec-10 10:15 AM 

### Site: BIOREACTOR 2 EFF. Matrix: OTHER

Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

### Sam p le #:

Analyst MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 1 ug/L EPA 245.1 16-Dec-10 02:05 1 MHH7131
TOTAL RECOVERABLE METALS BY ICP Aluminum (Al) 1.46 mg/L EPA 200.7 16-Dec-10 11:07 0.05 DJSULL1 Barium (Ba) 0.434 mg/L EPA 200.7 16-Dec-10 11:07 0.05 DJSULL1 Beryllium (Be) < 0.05 mg/L EPA 200.7 16-Dec-10 11:07 0.05 DJSULL1 Boron (B) 163 mg/L EPA 200.7 16-Dec-10 11:07 0.5 DJSULL1 Calcium (Ca) 4010 mg/L EPA 200.7 16-Dec-10 11:07 0.1 DJSULL1 Cobalt (Co) < 0.05 mg/L EPA 200.7 16-Dec-10 11:07 0.05 DJSULL1 Iron (Fe) < 0.1 mg/L EPA 200.7 16-Dec-10 11:07 0.1 DJSULL1 Magnesium (Mg) 733 mg/L EPA 200.7 16-Dec-10 11:07 0.05 DJSULL1 Manganese (Mn) 3.29 mg/L EPA 200.7 16-Dec-10 11:07 0.05 DJSULL1 Molybdenum (Mo) < 0.05 mg/L EPA 200.7 16-Dec-10 11:07 0.05 DJSULL1 Sodium (Na) 45.2 mg/L EPA 200.7 16-Dec-10 11:07 0.5 DJSULL1

# Certificate of Laboratory Analysis This re p ort shall not be re p roduced, exce p t in full. 

## Order # J10120055

2010012858 Collection Date: 08-Dec-10 10:15 AM 

### Site: BIOREACTOR 2 EFF. Matrix: OTHER

Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

### Sam p le #:

Analyst TOTAL RECOVERABLE METALS BY ICP Tin (Sn) < 0.5 mg/L EPA 200.7 16-Dec-10 11:07 0.5 DJSULL1 Titanium (Ti) < 0.05 mg/L EPA 200.7 16-Dec-10 11:07 0.05 DJSULL1
TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 5 ug/L EPA 200.8 21-Dec-10 13:14 5 KRICHAR Arsenic (As) < 5 ug/L EPA 200.8 21-Dec-10 13:14 5 KRICHAR Cadmium (Cd) < 5 ug/L EPA 200.8 21-Dec-10 13:14 5 KRICHAR Chromium (Cr) < 5 ug/L EPA 200.8 21-Dec-10 13:14 5 KRICHAR Copper (Cu) < 5 ug/L EPA 200.8 21-Dec-10 13:14 5 KRICHAR Lead (Pb) < 5 ug/L EPA 200.8 21-Dec-10 13:14 5 KRICHAR Nickel (Ni) < 5 ug/L EPA 200.8 21-Dec-10 13:14 5 KRICHAR Selenium (Se) 26.7 ug/L EPA 200.8 21-Dec-10 13:14 5 KRICHAR Silver (Ag) < 5 ug/L EPA 200.8 21-Dec-10 13:14 5 KRICHAR Thallium (Tl) < 5 ug/L EPA 200.8 21-Dec-10 13:14 5 KRICHAR Vanadium (V) < 5 ug/L EPA 200.8 21-Dec-10 13:14 5 KRICHAR Zinc (Zn) < 10 ug/L EPA 200.8 21-Dec-10 13:14 10 KRICHAR
SELENIUM SPECIATION Vendor Parameter Complete V_AS&C 

### 2010012859 Collection Date: 01-Dec-10 2:00 PM 

### Site: Trip Blank Matrix: OTHER

Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

### Sam p le #:

Analyst TOTAL RECOVERABLE METALS BY ICP Aluminum (Al) < 0.005 mg/L EPA 200.7 16-Dec-10 10:27 0.005 DJSULL1 Barium (Ba) < 0.005 mg/L EPA 200.7 16-Dec-10 10:27 0.005 DJSULL1 Beryllium (Be) < 0.005 mg/L EPA 200.7 16-Dec-10 10:27 0.005 DJSULL1 Boron (B) < 0.05 mg/L EPA 200.7 16-Dec-10 10:27 0.05 DJSULL1 Calcium (Ca) 0.014 mg/L EPA 200.7 16-Dec-10 10:27 0.01 DJSULL1 Cobalt (Co) < 0.005 mg/L EPA 200.7 16-Dec-10 10:27 0.005 DJSULL1 Iron (Fe) < 0.01 mg/L EPA 200.7 16-Dec-10 10:27 0.01 DJSULL1 Magnesium (Mg) < 0.005 mg/L EPA 200.7 16-Dec-10 10:27 0.005 DJSULL1 Manganese (Mn) < 0.005 mg/L EPA 200.7 16-Dec-10 10:27 0.005 DJSULL1 Molybdenum (Mo) < 0.005 mg/L EPA 200.7 16-Dec-10 10:27 0.005 DJSULL1 Sodium (Na) < 0.05 mg/L EPA 200.7 16-Dec-10 10:27 0.05 DJSULL1 Tin (Sn) < 0.05 mg/L EPA 200.7 16-Dec-10 10:27 0.05 DJSULL1 Titanium (Ti) < 0.005 mg/L EPA 200.7 16-Dec-10 10:27 0.005 DJSULL1
TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L EPA 200.8 21-Dec-10 13:08 1 KRICHAR Arsenic (As) < 1 ug/L EPA 200.8 21-Dec-10 13:08 1 KRICHAR

# Certificate of Laboratory Analysis This re p ort shall not be re p roduced, exce p t in full. 

## Order # J10120055

2010012859 Collection Date: 01-Dec-10 2:00 PM 

### Site: Trip Blank Matrix: OTHER

Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

### Sam p le #:

Analyst TOTAL RECOVERABLE METALS BY ICP-MS Cadmium (Cd) < 1 ug/L EPA 200.8 21-Dec-10 13:08 1 KRICHAR Chromium (Cr) < 1 ug/L EPA 200.8 21-Dec-10 13:08 1 KRICHAR Copper (Cu) < 1 ug/L EPA 200.8 21-Dec-10 13:08 1 KRICHAR Lead (Pb) < 1 ug/L EPA 200.8 21-Dec-10 13:08 1 KRICHAR Nickel (Ni) < 1 ug/L EPA 200.8 21-Dec-10 13:08 1 KRICHAR Selenium (Se) 1.36 ug/L EPA 200.8 21-Dec-10 13:08 1 KRICHAR Silver (Ag) < 1 ug/L EPA 200.8 21-Dec-10 13:08 1 KRICHAR Thallium (Tl) < 1 ug/L EPA 200.8 21-Dec-10 13:08 1 KRICHAR Vanadium (V) < 1 ug/L EPA 200.8 21-Dec-10 13:08 1 KRICHAR Zinc (Zn) < 2 ug/L EPA 200.8 21-Dec-10 13:08 2 KRICHAR
SELENIUM SPECIATION Vendor Parameter Complete V_AS&C 

### 2010012860 Collection Date: 08-Dec-10 10:50 AM 

### Site: FILTER BLANK Matrix: OTHER

Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

### Sam p le #:

Analyst DISSOLVED METALS BY ICP-MS Selenium (Se) 4.96 ug/L EPA 200.8 27-Dec-10 14:33 2 KRICHAR

# December 19, 2010 Jay Perkins Duke Energy Analytical Laboratory Mail Code MGO3A2 (Building 7405) 13339 Hagers Ferry Rd. Huntersville, NC 28078 (704) 875-5245 Project: Belews – FGD WWTS (2010, Bi-Weekly Sampling) (LIMS # J10120055)

Dear Mr. Perkins, Attached is the report associat ed with four (4) aqueous sa mples submitted for selenium speciation analysis on December 9, 2010. Th e samples were received on December 10, 2010 in a sealed cooler at -0.4 o 

# C. Selenium speciation analysis was performed via ion chromatography inductively coupled plasma dynamic reaction cell mass spectrometry (IC-ICP-DRC-MS). Any analytical issues asso ciated with the analysis are addressed in the following report. If you have any questions, please feel fr ee to contact me at your convenience.

Sincerely,

Russell Gerads Vice President Applied Speciation and Consulting, LLC

# Applied Speciation and Consulting, LLC Report prepared for: Jay Perkins Duke Energy Analytical Laboratory Mail Code MGO3A2 (Building 7405) 13339 Hagers Ferry Rd. Huntersville, NC 28078

Project: Belews – FGD WWTS (2010, Bi-Weekly Sampling) (LIMS # J10120055)

December 19, 2010

1. Sample Reception Four (4) aqueous samples in 125mL HDPE bottles (provided by Applied Speciation and Consulting) were submitted for seleni um speciation analysis on December 9, 2010. The samples were received on Decem ber 10, 2010 in a sealed container at - 0.4 o 

# C. The samples were received in a lamina r flow clean hood void of trace metals contamination and ultra-violet radiat ion. Upon reception, the samples were designated discrete sample identifiers. An aliquot of each sample was filtered (0.45μm) and these filtrates were stored in a secure, monitored cryofreezer (maintained at a temperature of -80 o 

# C) until selenium speciat ion analysis could be performed via ion chromatography inductive ly coupled plasma dynamic reaction cell mass spectrometry (IC-ICP-DRC-MS).

2. Sample Preparation All sample preparation is performed in laminar flow clean hoods known to be free from trace metals contamination. All a pplied water for dilutions and sample preservatives are monitored for contamina tion to account for any biases associated with the sample results. Selenium Speciation Analysis by IC-ICP-DRC-MS Prior to analysis , an aliquot of each sample was filtered with a syringe filt er (0.45μm) and inject ed directly into a sealed autosampler vial. No further sa mple preparation was performed as any chemical alteration of the samples may shift the equilibrium of the system resulting in changes in speciation ratios.

# 3. Sample Analysis All sample analysis is precluded by a minimum of a five-poi nt calibration curve spanning the entire concentrati on range of interest. Calibration curves are performed at the beginning of each analytical day. All calibration curves, associated with each species of interest, are sta ndardized by linear regression re sulting in a response factor. All sample results are instrument blank corrected to account for any operational biases associated with the analytical platform. Prior to sample analysis, all calibration curves are ve rified using second source standards which are identified as initial calibration verification standards (ICV). Ongoing instrument performance is iden tified by the analysis of continuing calibration verification standards (CCV) and continuing calibration blanks (CCB) at a minimal interval of every ten analytical runs. Selenium Speciation Anal ysis by IC-ICP-DRC-MS All samples for selenium speciation analysis were analyzed by ion chromatography inductively coupled plasma dynamic reaction cell mass spectrometry (IC-ICP-DRC-MS) on December 15, 2010. An aliquot of each sample is injected onto an anion exchange column and mobilized by a basic (pH > 7) gradient. The eluting selenium species are then introduced into a radio frequency (RF) plasma where energy- transfer processes cause desolvation, atomization, and ionization. The ions are extracted from the plasma through a differentially-pumped vacuum interface and travel through a pressurized chamber (DRC) containing a specific reactive gas whic h preferentially reacts with interfering ions of the same target mass to charge ratios (m/z). A solid-state detector detects ions transmitted through the mass analyzer and the resulting current is processed by a data handling system. Retention times for each eluting species are compared to known standards for species identification.

4. Analytical Issues The overall analyses went very well and no analytical issues were encountered. All quality control parameters associated with these samples were within acceptance limits.
The estimated method detection limits (eMDLs) for selen ite, selenate, and selenocyanate are generated from replicate analyses of the lowest standard in the calibration curve. Not all selenium speci es are present in preparation blanks; therefore, eMDL calculations based on preparat ion blanks are artificially biased low. The eMDL for methylseleninic acid and selenomethionine is calculated from the average eMDL of selenite, selenate, and selenocyanate. The calibration does not

# contain methylseleninic acid or selenomethionine due to impurities in these standards which would bias the results for other selenium species. If you have any questions or concerns regarding this report, please feel free to contact me. Sincerely,

Russell Gerads Vice President Applied Speciation and Consulting, LLCSample ResultsSample IDSe(IV) Se(VI) SeCN MeSe(IV) SeMeUnknown SeSpecies (n)FGD Purge Eff36.01740 ND (<0.77) ND (<1.2) ND (<1.2) 0 (0)BioReactor 1 Inf13.5662 ND (<0.19) 1.66 ND (<0.29) 0 (0)BioReactor 2 Eff0.7531.1 ND (<0.19) ND (<0.29) ND (<0.29) 0 (0)Metals Trip BlkND (<0.039) ND (<0.097) ND (<0.038) ND (<0.058) ND (<0.058) 0 (0)All results reflect the applied dilution and are reported in μg/LND = Not detected at the applied dilutionSeCN = SelenocyanateMeSe(IV) = Methylseleninic acidSeMe = SelenomethionineUnknown Se Species = Total concentration of all unknown Se species observed by IC-ICP-MSn = number of unknown Se species observedReport Generated by: Russell GeradsApplied Speciation and Consulting, LLCSelenium Speciation Results for Duke EnergyProject Name: Belews - FGD WWTS (2010, Bi-Weekly Sampling)Contact: Jay PerkinsDate: December 19, 2010LIMS #J10120055Quality Control Summary - Preparation Blank SummaryAnalyte (μg/L) PBW1 PBW2 PBW3 PBW4 Mean StdDev eMDL* eMDL 10x eMDL 50x eMDL 200xSe(IV) 0.000 0.000 0.000 0.000 0.000 0.000 0.004 0.039 0.20 0.78Se(VI) 0.000 0.000 0.000 0.000 0.000 0.000 0.010 0.097 0.48 1.9SeCN 0.000 0.000 0.000 0.000 0.000 0.000 0.004 0.038 0.19 0.77MeSe(IV) 0.000 0.000 0.000 0.000 0.000 0.000 0.006 0.058 0.29 1.2SeMe 0.000 0.000 0.000 0.000 0.000 0.000 0.006 0.058 0.29 1.2eMDL = Estimated Method Detection Limit*Please see narrative regarding eMDL calculationsQuality Control Summary - Certified Reference MaterialsAnalyte (μg/L) CRM True Value Result RecoverySe(IV) ICV 9.57 9.24 96.5Se(VI) ICV 9.48 8.59 90.6SeCN ICV 8.92 8.35 93.7MeSe(IV) ICV 6.47 5.51 85.2SeMe ICV 9.32 9.00 96.5Selenium Speciation Results for Duke EnergyProject Name: Belews - FGD WWTS (2010, Bi-Weekly Sampling)Contact: Jay PerkinsLIMS #J10120055Date: December 19, 2010Report Generated by: Russell GeradsApplied Speciation and Consulting, LLCQuality Control Summary - Matrix DuplicatesAnalyte (μg/L) Sample ID Rep 1 Rep 2 Mean RPDSe(IV) Batch QC 0.803 0.554 0.678 36.7*Se(VI) Batch QC ND (<0.48) ND (<0.48) NC NCSeCN Batch QC ND (<0.19) ND (<0.19) NC NCMeSe(IV) Batch QC ND (<0.29) ND (<0.29) NC NCSeMe Batch QC ND (<0.29) ND (<0.29) NC NCND = Not detected at the applied dilutionNC = Value was not calculated due to one or more concentrations below the eMDL*Sample concentration is within 10x the eMDLQuality Control Summary - Matrix Spike/ Matrix Spike DuplicateAnalyte (μg/L)Sample ID Spike Conc MS Result Recovery Spike Conc MSD Result Recovery RPDSe(IV)Batch QC 278.0 450.3 161.7 278.0 492.7 177.0 9.0Se(VI)Batch QC 252.3 279.8 110.9 252.3 285.5 113.2 2.0SeCNBatch QC 228.8 1.5 0.6** 228.8 0.8 0.4** 57.9**The low recovery is attributed to sample induced species conversionSelenium Speciation Results for Duke EnergyProject Name: Belews - FGD WWTS (2010, Bi-Weekly Sampling)Contact: Jay PerkinsLIMS #J10120055Date: December 19, 2010Report Generated by: Russell GeradsApplied Speciation and Consulting, LLC

### This data package contains the analytical results for the project identified above and includes a Case Narrative, Sample Results and Chain of Custody. Unless otherwise noted, all samples were received in acceptable condition and processed according to the referenced methods. Data qualifiers are flagged individually on each sample. A key reference for the data qualifiers appears at the end of this case narrative. NC Certification No. 402 SC Certification No. 99012 NC Drinking Water Cert No. 37735 

# Case Narrative
12/20/2010

Duke Energy Corporation Jay Perkins 13339 Hagers Ferry Road Huntersville, NC 28078 Project: Belews - FGD WWTS (Bi-Weekly Sampling) Project No.: J10120055 Lab Submittal Date: 12/09/2010 Prism Work Order: 0120298

Please call if you have any questions relating to this analytical report. Respectfully, PRISM LABORATORIES, INC.



### VP Laboratory Services Reviewed By

Data Qualifiers Key Reference:



### Method Detection Limit MDL Below Reporting Limit BRL

Relative Percent Difference RPD



## * Results reported to the reporting limit. All other results are reported to the MDL with values between MDL and reporting limit indicated with a J.

This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.

449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 

## Page 1 of 5

# Sample Receipt Summary 12/20/2010 

## Prism Work Order: 0120298 Client Sample ID Matrix Lab Sample ID Date Sampled Date Received 

### 0120298-01 12/08/10 2010012854/FGD Purge EFF 12/09/10 Water
Samples received in good condition at 1.0 degrees C unless otherwise noted.

This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.

449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 

## Page 2 of 5

# Laboratory Report
12/20/2010

Result Parameter Batch ID Report Limit Analysis Date/Time Method Dilution Factor Units MDL Analyst 

### 13339 Hagers Ferry Road Project No.: J10120055 Project: Belews - FGD WWTS (Bi-Weekly Sampling) Duke Energy Corporation

Huntersville, NC 28078 Attn: Jay Perkins Sample Matrix: Water Client Sample ID: 2010012854/FGD Purge E Prism Sample ID: 0120298-01 Prism Work Order: 0120298 Time Collected: 12/08/10 10:02 Time Submitted: 12/09/10 15:50

General Chemistry Parameters 16000 *SM2540 C P0L0288 1 50 12/14/10 14:00 JAB mg/L 8.7 Total Dissolved Solids

This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 

## Page 3 of 5

### 12/20/10 

## Level II QC Report

13339 Hagers Ferry Road Project No: J10120055 Project: Belews - FGD WWTS (Bi-Weekly Sampling) Duke Energy Corporation

Huntersville, NC 28078 Attn: Jay Perkins Prism Work Order: 0120298 Time Submitted: 12/9/10 3:50:00PM

Result Limit

Reporting Units Level Spike Result

Source %REC %REC Limits RPD RPD Limit Notes Analyte General Chemistry Parameters - Quality Control



### Batch P0L0288 - NO PREP Blank (P0L0288-BLK1) 

### Prepared & Analyzed: 12/14/10 Total Dissolved Solids mg/L BRL 50 LCS (P0L0288-BS1) 

### Prepared & Analyzed: 12/14/10 Total Dissolved Solids mg/L 998 50 1000 90-110 100



### Sample Extraction Data

NO PREP
Lab Number Batch Date Initial Final P0L0288 0120298-01 12/14/10 50 50 mL mL

This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.

449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 

## Page 4 of 5Page 5 of 5