# EPA Reg. No. 7969-333 Vol. 3 (formerly 53263-28)

# e e 

# C Material to be added to a Mini-Jacket (in the case where an e-Jacket exists) Reg. No.**~3Z-6** 

# 3 -- 2-'6 

# Send to SIG: check box 

# IS] This material is :**~** 

# New stamped -accepted label**~** 

# NewCSF D 

# Notification D 

# Final Printed Label 

# o Other:

-------------- 

# Instructions: Attach this notice on top of the material. It must be clipped all together and there should be NO STAPLES in the material. Then give the material with this coversheet to staff in the Information Services Center (Room 

# 230). Reviewer's Name: 

# PitAJ 

# bGv;t/Y Phone: 

# 3 

# os-- 7sYG Division: 

# 12-5) Date: 

# s-/ 

# njot>

Current as of T uesday, May 16 , 2006

# UNITED ST 4j ES ENVIRONMENTAL**PRO TION**  

# AGENCY

Eliot I. Harrison Cognis Corporation c/o Lewis and Harrison 122 C Street, NW, Suite 740 Washington, DC 20001 Dear Mr
. 

### Harrison: Subject: Revised Ingredient Statement AgniqueMMF 

## MAR 

## 1 5 2006

EPA Registration No . 53263-28 Your Submission Dated October 11, 2005 The labeling referred to above, submitted in connection with registration under the Federal Insecticide, Fungicide, and Rodenticide Act, as amended, is acceptable. A stamped copy is enclosed for your records. Please submit one 

### (1) final printed copy for the above mentioned label before releasing the product for shipment.

Enclosure

DK: 305-7546: IRBIPM01

SYMBOL • 

### 7505C SURNAHB • 

### D. Kenny DATE • 

### 3/15/06 EPA Form 1320-1 (12-70) 

### Sincerely yours,
Daniel 

### C. Kenny Product Manager (01) Insecticide-Rodenticide Branch Registration Division (7505C)

CONClJRRENCES

OFFICIAL FILE COPY

# AGNIQUE® MMF MOSQUITO LARVICIDE & 

## PUPICIDE Monomolecular Surface Film for Control of Immature Mosqu itoes and Midges ACTIVE INGREDIENT: Poly(oxy-1.2·ethanediyl) . a-(C 1&- 10 branched and linear alkyl) -ro-hydroxy- .. . ..... ". 100% 

## KEEP OUT OF REACH OF CHILDREN 

## CAUTION See Back Panel for Add itional Precautions and Product Information 

### FIRST AID(TREATMENT) If ON SKIN : • Take off contaminated clothing
. OR • Rinse skin immediately with plenty of water for 15-20 CLOTHING: minutes
. • Call a poison control center or doctor for treatment advice , IF IN EYES: • Hold eye open and rinse slowly and gently with plenty of 

### I water for 15-20 minutes. I I • Remove contact lenses, if present, after the first 5 j I minutes, then continue rinsing eye . ! • Call a poison control center or doctor for treatment advice
. LHave the product container or label with you when calling a poison control

cen!er or doctor, or going for treatment.

EPA Reg
. No, 53263-28
Revised 3 · 13· 06 

# ACCEPTED MAR 15 2006 under the 

### Federal 

### Insedidde.**~,** and 

### Rodenddde Ad. as aInended, foe the 

### pestiddc Regi*red ODd« EPA Reg. No. 

## 53

# '2.' 3 ,.2$

EPA Establishment No
. ___ _ PRECAUTIONARY STATEMENTS HAZARDS TO HUMAN AND DOMESTIC ANIMALS CAUTION: Avoid contact with skin , eyes or clothing , Wash thoroughly with soap and water after handling , DIRECTIONS FOR USE It is a violation of Federal law to use this product in a manner inconsistent with its labeling. To be used in governmental mosquito control program , by professional pest control operators , by homeowners, or in other mosquito or midge control operations
. APPLICATION DIRECTIONS This product may be applied by both ground and aerial applications, To use, calculate the desired rate based on water surface area . The water depth is not 

# a a factor in rate determination
. Spray the desired rate of AGNIQUeC' MMF onto ,., the surface of the water
. No dilution is required and a fan spray is recommended
. The MMF will spread to cover hard to access areas, For large areas with dense vegetation it is recommended that application is made in several locations to assist in the spreading action , 

### Do not pour or inject a stream spray directly into water
.**AGNIQU~** MMF is not visible 

### on the surface of the water
. Excess MMF on the water surface will form a white globule
. APPLICATION 

## sITes This product is for the control of immature mosquitoes and midges in areas where they breed and develop
. This product may be used in habitats including potable water and irrigation waters, permanent and semi-permanent waters , irrigated croplands and pastures, and waters with outlets to narural water bodies
. The following habitats provide examples of where the product can be applied but is not intended to be all inclusive. Fresh and Brackish Water: fresh water and salt marshes , (containerized] ponds , lakes, stonn water, drainage systems and retention & detention basins, roadside ditches, grassy swales , flooded fields and pastures , potable water containers , reservoirs, irrigated croplands, temporary and semi-permanent woodland pools , tidal water, and other areas where water accumulates, Residential Areas : [Containerized] ponds , storm water basins. tree holes, rain barrels, landscape and ornamental ponds, tires , storm drains, stationary flower pots , pot holes , gutters, tarps, potable water containers and residential areas where water accumulates and provides ideal breeding habitats for mosquitoes or midges, Not for Homeowner U.e in the State of New York. Polluted Waters: Sewage lagoons, percolation ponds, animal waste effluent lagoons. septic ditches, waste treatment facility areas , etc,

Page 1 of 3

# eMOSQUITO HABITAT Fresh and Brackish Water* Poll uted Waters" MIDGE HABITAT ested Rate Ra eA Fresh and Polluted Waters 0
.5-1
.0 gall ons/acre (5 - 10 literlhectare) • The lower rate (0 .2 gallons/acre) is recommended when only pupae control is desired and in sites with no emergent vegetation and low organic content • Use higher rates when emergent or surface vegetation Is present
. due to the

wicldng action of the product
. The more vegetation or the drier the vegetation
. the higher the required rate.

... Use higher rates in polluted water habitats for effective control 

### "Rea lication is recommended eve _two**~eJcs** durilg the midge season {Note to Review: the following use diAK:tions will be prov i ded on product marl(eted to commercial andinstitutional users.} APPLICATION NOTES Rate of Kill : The rate of kill when using MMF is dependent on the species , the life stage, the habitat and the temperature
. Pupicidal action will typ ically result in 24 hours. Larvicidal action wi ll usually result in 24-96 hours. If the film is present, as indicated by the indicator oil, 

### control will be achieved
. Indicator Oil: AGNIQUee MMF is not visible on the surface of the water
. To check the habitat for the presence and persistence of the product, add a drop of AGNIQUE® MMF Ind icator Oil to several locations in the habitat. If the Indicator Oil forms a tight bead on the surface 

### of the water, then the MMF is present tor control. Persistence: The**AGNIQU~** MMF surface fi lm typ ically persiSts on the water's surface for 5 to 22 days
. Polluted waters will cause more rapid degradation of the film
. Higher application rates will prolong film life and extend the interval between retreatment. Species: Mosquitoes and midges that require little or no surfaca contact for breathing wi ll be affected by the product during the pupae and emerging adult life stages
. Wind : The high end of the dosage rate is recommended when spraying habitats where mu lti-directiona l winds of 10mph (16kmlhr) or greater are expected to persist. Whi le the film wi ll be pushed by the winds, it will re-spread quickly once the winds have subsided
. If persistent unidirectiona l winds 

### of 10 mph (16kmJhr) or greater are expected, the d isplacement of the surface film may resu lt in poor control
. Spray Tanks : Thorough ly clean and dry the spray system of contaminants such as petroleum oils , water, detergents and conventiona l toxicants prior to adding**AGNIQU~** MMF
. Detergents will destroy the film-form ing of the**AGNIQU~** MMF; other contam inants (water and oil) can result in the formation of an unsprayable paste
. Dilution :**AGNIQU~** MMF is typically applied 

### to the water's surface without dilution . However, if it is desired to spray higher volumes of liqU id
. AGNIQUr:- Revised**10 11~5**  MMF may be d iluted using a h igh shear injection system that d ilutes the MMF at the nozzle 

### to a maximum of 10% in water
. Do not add AGNIQUe- MMF to water in non-ag itated spray systems
. Conventional bypass recirculation will not provide adequate ag itation to effective ly miX MMF in water
. Expanding Waters : Sign ificant expansion ofthe habitat's surface due 

### to rain or tida l fluxes can be compensated for by using a dosage that is based on the largest expected surface area . Th is will ensure comp lete coverage , and eliminate the need for re-treatment of the flooded area. {Note to Relliew : the following use diIections will be provided on product marl<eted to household users} APPLICATION NOTES Rate of Kill : The rate of kill when using MMF is dependent on the species , the life stage, the habitat and the temperature
. Pupicidal action will typically result _ in 24 hours
. Larvicidal action w ill usually resu lt in 24-96 hours
. If the film is _ present, control will be ach ieved
. Persistence : The**AGNIQU~** MMF film typically persists on the water's surface for 5 to 22 days
. Polluted waters will cause more rapid degradation of the film
. H igher application rates will prolong fdm life and extend the interval between retreatment. Species : Mosquitoes and m idges that require l ittle or 

### no surface 

### contact for breathing wi ll be affected by the product during the pupae and emerg ing adu lt life stages
. Wind : The high end of the dosage rate is recommended when spraying habitats wheffi multi-directional winds of 10mph (16kmlhr) or greater are expected to persist. While the film wi ll be pushed by the winds , it will re-spread quickly once the winds have subsided
. If persistent unidirectional winds of 10 mph (16kmlhr) or greater are expected , the displacement of the surface film may resu lt in poor control. Dilution :**AGNIQU~** MMF is typically applied to the water's surface without dilution. Do not dilute product with water 

### or other products
. Expanding Waters: SignifJCanI expansion of the habitat's surface area due to rain or tidal fluxes can be compensated for by using a dosage that is based on _ the largest expected surface area . This will ensure comp/ete coverage, and eliminate the need for re-treatment of the flooded area .

Page 2 af 3.....,.._**.** ",."
.... . U' '''
. .... .**~**..n .w ""'''"1' •• • 0. - ... _ ...__ ..**~~**

## ...

# -.-..- ...........**~** Surface Area of Standing Water Suggested Quantity of AGNIQUee MMF
. 1 to 75 square feet Four full trigger applications of the spray bottle containing AGNIQUEe MMF* 75-100 square feet Six full trigger applications of the spray bottle containing**AGNIQU~** MMF* Every additional 100 square feet Four to six 

### full trigger applications ofthe spray bottle containing AGNIQUeMMF* 1 ,000 square feet 40 to 60 full trigger applications (1-1
.5 oz.) * The application rate can vary between 1 and 3
.0 oz. per 1000 sq . fl (0
. 1 to 0
.3 oz. 1100 SQ. ft
.)
. Maximum application rate is 3
.0 oz per 1000 SQ . ft
.

• •**_~_** ....... . . _ ......... . _ ............ .. .......... _ .....ow. __ 

## - _.. 

### .

# -.- -- --. .

### ... .. 

## _._. Surface Area of Standing Water Suggested Quantity of AGNIQUe- MMF 1 to 75 square feet One full trigger application of the spray bottle containing**AGNIQU~** MMF* 75-100 square feet Two fu ll trigger applications of

### the spray bottle containing**AGNIQU~** MMF* Every additional 100 square feet Two to three full trigger applications of the spray bottle containing**AGNIQU~** MMF* 1 ,000**~uare** feet 20-25 full trigger applications (1-1
.5 oz.) *The application rate can vary between 1 and 3
.0 oz. per 1000 sq . ft
. (0.1 to 0
.3 oz. 1100 SQ
. 

### ft.). Maximum application rate is 3
.0 oz per 1000 SQ
. ft
. {Note 10 Review: the following storage and disposal language Wl11 appear 011 household conta/ners.} STORAGE AND DISPOSAL If empty: Do not reuse this container. Place in trash or offer for recycl ing if available
. 00 not allow product to freeze
. If partly filled : Call your local solid waste agency or 1-800-CLEANUP for disposa l instructions
. Never place unused product down any indoor or outdoor drain
. {Note to Review : the foIIcwing ch8lt will be usedon containers largerthan 1 gallOll in size.} STORAGE AND DISPOSAL 

### 00 not contaminate water, food , or feed by storage or disposal. Pesticide Storage: Do not allow storage containers to rust. Rust contaminants may clog spray nozzles
. 

### 00 not allow product to freeze
. Pesticide Disposal: Wastes resulting from the use of this product may be disposed of on site or at an approved waste disposal facility
. Container Disposal: Triple rinse , then offer for recycling or recond ition ing or puncture and d ispose of in a sanitary landfi ll, or by other procedures approved 

### by state or local authorities
. Revised 10-11-05 NOTICE Cognis Corporation makes no warranty , express or implied of merchantability, fitness or otherwise concerning the use of this product other than as indicated on the label. User assumes all risks , storage or hand ling not in strict accordance with 

### the label. For information on th is pestiC ide product (includ ing health) concerns , medica l emergencies or pestiCide incidents, call the National Pesticide Telecommun ication Net work at 1-800-858-7378
. {-OR-} For assistance call 

### the__ Help Line 1-800-_ - __ Monday through Friday 7 am to 5 pm Centra l Time
. Stops Mosquitoes from Breeding _ Stop Mosquitoes Before they Start
.. Stops Mosqu ito Emergence Standing Water Treatment Spreads to cover hard to reach areas Can be used in habitats containing birds , 

### fish , pets and wildlife Use every two weeks or 

### as needed Biodegradable Peel Here for Directions See pu ll out label for additional use instructions 

### See pull out label for 

### Rrst Aid Treatment May be used in potable water Use on : [Containerized} ponds, pools , ditches, irrigation water, flood water areas, other areas where mosquitoes breed and develop Net (Contents) 

### (WT) _____ _ 

# c) 

# nIS Cogn is Corporation 4900 Este Avenue Cincinnati, OH 45232-1419 1-800-254-1029

Page 3 of3 

# -

# LEWIS & HARRISON COMultante In Government Aftelre 122 C Street. N.W. . Suite 7"0 Washington. D.C. 20001 telephone 202.393 .3903 faIC 202.393 .3906



### Dan Kenny, Product Manager 

### #

### 1 Insecticide Branch Registration Division (7505C) Office ofPesticide Programs Environmental Protection Agency 1801 South Bell Street Arlington, 

### VA 22202 

### re: Agnique MMF EPA Reg. No. 53263-28 Registrant: Cognis Corporation March 13,2006



### Revised Label and Confidential Statement ofFormula Dear Dan : As we discussed, please find revised five (5) copies ofa revised product label and Confidential Statement ofFonnula (CSF) for Agnique MMF. The revised label and CSF are in accordance with 

### Kerry Leifer' s review dated March 7, 2006. 

### Ifyou have any questions about this SUbmission, please contact me at (202) 393-3903, ext. 14.


### Sincerely,
Eliot Harrison Agent for Cognis



# - --------------- --_ . .. . .

## -- .. . .

## _ ..

# ?(Lof05;;f) AGNIQUE® MMF MOSQUITO LARVICIDE & PUPICIDE Monomolecular Surface Fil m for Control of Immature Mosquitoes and Midges ACTIVE INGREDIENT: Poly (oxy-1 ,2-ethanediyl), a-i !{O

### ~C**4_ hYdroXYI**  .......................... 100%

# C/~_2.0 KEEP OUT OF REACH OF CHILDREN 

# CAUTION See Back Panel for Additional Precautions and Product Information 

### FIRST AID (TREATMENT) IF ON SKIN • Take offcontaminated clothing. OR • Rinse skin immediately with plenty of water for 15-20 i ! I I CLOTHING: minutes
. I • Call a poison control center or doctor for treatment advice. I IF IN EYES: • Hold eye open and rinse slowly and gently with plenty of water for 15-20 minutes. • Remove contact lenses, if present, after the first 5 m inutes
. then continue rinsing eye . • Call a poison control center or doctor for treatment advice
. Have the product container or label with you when calling a poison control center or doctor, or going for treatment.

EPA Reg
. No. 53263-28 

# _

# ~ 15-fP-lf-JV-( tV! LA.-

# ~v~/'1I--r 

# -3)

# fL-
••• '2. 

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## •

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## • ••• • 

## • • • • • •

• •• • • •



## • • 

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• • • 

## •• • 

## • • 

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# 17; 

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## • • 

## ••• bPAbstablishment No
. 

# .. . ------- 

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# . .. .. • 

## • •• 

## •

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### •••• 

# L-11/3GL PRECAUTIONARY STATEM ENTS HAZARDS TO HUMAN AND DOMESTIC ANIMALS CAUTION: Avoid contact with skin , eyes or clothing
. Wash thoroughly with soap and water after handling
. DIRECTIONS FOR USE It is a violation of Federal law to use th is product in a manner inconsistent with its labeling. To be used in governmental mosquito control program , by professional pest control operators , by homeowners , or in other mosquito or midge control operations
. APPLICATION DIRECTIONS This product may be applied by both ground and aerial applications
. To use , calculate the desired rate based on water surface area. The water depth is not _ a factor in rate determination. Spray the desired rate of AGNIQUE® MMF onto ,., the surface of the water. No dilutioD is required and a fan spray is recommended. The MMF will spread to cover hard to access areas . For large areas with dense vegetation it is recommended that application is made in several locations to assist in the spreading action
. Do not pour or inject a stream spray directly into water. AGNIQUE®MMF is not visible on the surface of the water. Excess MMF on the water surface will form a white globule
. APPLICATION SITES This product is for the control of immature mosquitoes and midges in areas where they breed and develop. This product may be used in habitats including potable water and irrigation waters, permanent and semi-permanent waters , irrigated croplands and pastures, and waters with outlets to natural water bodies. The following habitats provide examples of where the product can be applied but is not intend ed to be all inclusive. Fresh and Brackish Water: fresh water and salt marshes , [containerized] ponds , lakes, storm water, drainage systems and retention & detention basins, roadside ditches, grassy swales, flooded fields and pastures , potable water containers , 

### At reservoirs, irrigated croplands , temporary and semi-permanent woodland pools, tidal ,., water, and other areas where water accumulates
. Residential Areas: [Containerized] ponds , storm water basins, tree holes , rain barrels , landscape and ornamental**pon~s ,**  tires, storm drains , stationary flower pots , pot holes , gutters , tarps, potable water containers and residential areas where water accumulates and provides ideal breeding habitats for mosquitoes or midges. Not for Homeowner Use in the State of New York. Polluted Waters: Sewage lagoons, percolation ponds , animal waste effluent lagoons, septic ditches , waste treatment facil ity areas , etc
.

Revised 10-11-05 Page 1 of 3

### " Note to Review : the fol/owing chart will be used on containers laroer than 1 oal/on in size:} MOSQUITO HABITAT Suggested Rate Range Fresh and Brackish Water* 0.2-1.0 gallons/acre (2 - 10 liters/hectare) Polluted Waters** 0
.35-1.0 gallons/acre (3.5-10 liters/hectare) MIDGE HABITAT Suggested Rate Rangel\ Fresh and Polluted Waters 0.5-1.0 gallons/acre (5 - 10 liter/hectare) * The lower rate (0.2 gallons/acre) is recommended when only pupae control is desired and in sites with no emergent vegetation and low organic content * Use higher rates when emergent or surface vegetation is present, due to the

wicking action of the product. The more vegetation or the drier the vegetation, the higher the required rate. ** Use higher rates in polluted water habitats for effective control 1\ Reapplication is recommended every two weeks during the midge season {Note to Review : the fol/owing use directions will be provided on product marketed to commercial and institutional users: } APPLICATION NOTES Rate of 

### Kill: The rate of kill when using MMF is dependent on the species, the life stage, the habitat and the temperature
. Pupicidal action will typically result in 24 hours
. Larvicidal action will usually result in 24-96 hours
. If the film is present, as indicated by the indicator oil, control will be achieved. Indicator Oil:**AGNIQU~** MMF is not visible on the surface of the water. To check the habitat for the presence and persistence of the product, add a drop of AGNIQUE® MMF Indicator Oil to several locations in the habitat. If the Indicator Oil forms a tight bead on the surface of the water, then the MMF is present for control. Persistence: The AGNIQUE® MMF surface film typically persists on the water's surface for 5 to 22 days. Polluted waters will cause more rapid degradation of the film. Higher application rates will prolong film life and extend the interval between retreatment. Species: Mosquitoes and midges that require little or no surface contact for breathing will be affected by the product during the pupae and emerging adult life stages. Wind: The high end of the dosage rate is recommended when spraying habitats where multi-directional winds of 10mph (16km/hr) or greater are expected to persist. While the film will be pushed by the winds, it will re-spread quickly once the winds have subsided. If persistent unidirectional winds of 10 mph (16km/hr) or greater are expected, the displacement of the surface film may result in poor control. , Spray Tanks: Thoroughly clean and dry the spray system of contaminants such as petroleum oils, water, detergents and conventional toxicants prior to adding AGNIQUE® MMF. Detergents will destroy the film-forming of the AGNIQUE® MMF; other contaminants (water and oil) can result in the formation of an unsprayable paste. Dilution : AGNIQUE® MMF is typically applied to the water's surface without dilution. However, if it is desired to spray higher volumes of liquid, AGNIQUE® Revised 10-11-05 : MMF may be diluted using a high shear injection system that dilutes the MMF at the nozzle to a maximum of 10% in water. Do not add AGNIQUE® MMF to water in non-agitated spray systems
. Conventional bypass recirculation will not provide adequate agitation to effectively mix MMF in water. Expanding Waters : Significant expansion of the hab itat's surface due to rain or tidal fluxes can be compensated for by using a dosage that is based on the largest expected surface area. This will ensure complete coverage, and el iminate the need for re-treatment of the flooded area . {Note to Review : the fol/owing use directions will be provided on product marketed to household users.} APPLICATION NOTES Rate of 

### Kill : The rate of kill when using MMF is dependent on the species, the life stage , the habitat and the temperature
. Pupicidal action will typically result

# a in 24 hours
. Larvicidal action will usually result in 24-96 hours. If the film is
. present, control will be achieved. Persistence : The AGNIQUE® MMF film typically persists on the water's surface for 5 to 22 days. Polluted waters will cause more rapid degradation of the film
. Higher application rates will prolong film life and extend the interval between retreatment. Species : Mosquitoes and midges that require little or no surface contact for breathing will be affected by the product during the pupae and emerging adult life stages. Wind: The high end of the dosage rate is recommended when spraying habitats where multi-directional winds of 10mph (16km/hr) or greater are expected to persist. While the film will be pushed by the winds, it will re-spread quickly once the winds have subsided. If persistent unidirectional winds of 10 mph (16km/hr) or greater are expected, the displacement of the surface film may result in poor control. Dilution : AGNIQUE® MMF is typically applied to the water's surface without dilution
. Do not dilute product with water or other products
. Expanding Waters: Significant expansion of the habitat's surface area due to 

# e rain or tidal fluxes can be compensated for by using a dosage that is based on the largest expected surface area . T.his will ensure complete coverage , and eliminate the need for re-treatment of the flooded area .

Page 2 of 3, 

# .

. .**-~**.... ,..... .... . ...... . ........ .... .. ...... ... "" " -" ..... 

## -- ---- 

## -_.. . 

## _

...

### _ ......_-- .. . 

## _

. ..

### - 

## -_. Surface Area of Standing Water Suggested Quantity of AGNIQUE® MMF 1 to 75 square feet Four full trigger applications of the spray bottle containing AGNIQUE® MMF* 75-100 square feet Six full trigger applications of the spray bottle containing AGNIQUE® MMF* Every additional 100 square feet Four to six full trigger applications of the spray bottle containing AGNIQUE® MMF* 1 ,000 square feet 40 to 60 full trigger applications (1-1
.5 oz .) * The application rate can vary between 1 and 3
.0 oz . per 1000 sq . ft. (0
. 1 to 0
.3 oz . 1100 sq. ft
.). Maximum application rate is 3
.0 oz per 1000 sq . 

### ft .

- - -- -- ..
_. - y - - - - - - . ..
_.- -- -_.- .- . - -- - -- Surface Area of Standing Water Suggested Quantity of AGNIQUE® MMF 1 to 75 square feet One full trigger application of the spray bottle containing AGNIQUE® MMF* 75-100 square feet Two full trigger applications of the spray bottle containing AGNIQUE® MMF* Every additional 100 square feet Two to three full trigger applications of the spray bottle containing AGNIQUE® MMF* 1,000 square feet 20-25 full trigger applications (1-1.5 oz .) *The application rate can vary between 1 and 3
.0 oz . per 1000 sq. ft
. (0.1 to 0
.3 oz . 1100 sq . ft.). Maximum application rate is 3
.0 oz per 1000 sq . 

### ft. {Note to Review : the following storage and disposal language will appear on household containers: } STORAGE AND DISPOSAL If empty: Do not reuse this container. Place in trash or offer for recycling if available
. Do not allow product to freeze
. If partly filled : Call your local solid waste agency or 1-800-CLEANUP for disposal instructions. Never place unused product down any indoor or outdoor drain
. {Note to Rev iew: the fol/owing chart will be used on containers larger than 1 gal/on in size:} STORAGE AND DISPOSAL Do not contaminate water
. food , or feed by storage or disposal. Pesticide Storage: Do not allow storage containers to rust. Rust contaminants may clog spray nozzles
. Do not allow product to freeze
. Pesticide Disposal: Wastes resulting from the use of this product may be disposed of on site or at an approved waste disposal facility
. Container Disposal: Triple rinse , then offer for recycling or reconditioning or puncture and dispose of in a sanitary landfill, or by other procedures approved by state or local authorities
. Revised 10-11-05 NOTICE Cognis Corporation makes no warranty , express or implied of merchantability, fitness or otherwise concern ing the use of th is product other than as indicated on the label. User assumes all risks , storage or handling not in strict accordance with the label. For information on this pesticide product (i ncluding health) concerns , medical emergencies or pesticide incidents, call the National Pesticide Telecommun ication Net work at 1-800-858-7378
. 

### {-OR-} For assistance call the __ Help Line 1-800-_- __ Monday through Frid ay 7 am to 5 pm Central Time
. Stops Mosquitoes from Breeding 

# e Stop Mosqu itoes Before they Start Stops Mosquito Emergence Stand ing Water Treatment Spreads to cover hard to reach areas Can be used in habitats containing birds , fish, pets and wildlife Use every two weeks or as needed Biodegradable Peel Here for Directions See pull out label for additional use instructions See pull out label for First Aid Treatment May be used in potable water Use on : [Containerized] ponds , pools , ditches , irrigation water, flood water areas , other areas where mosquitoes breed and develop Net (Contents) (WT) _____ _
Cognis Corporation 4900 Este Avenue Cincinnati , OH 45232-1419 1-800-254-1029

Page 30f3

# eUNITED STATES ENVIRONMENTAL PROTECTION AGENCY WASHINGTON, D
.C
. 20460



### March 7, 2006 OFFICE OF PREVENTION , PESTICIDES , AND TOXIC SUBSTANCES



### MEMORANDUM SUBJECT:

FROM:
TO: Review of Amendment to Change Nomenclature of Active Ingredient Agnique MMF Mosquito Larvacide & Pupicide EPA Reg. No
. 53263-28 DP# 323953 Kerry Leifer

# ~ Inert Ingredien e me ranch Registration Division ( 505C) Dan Kenny (PM-01 ) Insecticide-Rodenticide Branch Registration Division (7505C) In a submission dated October 11,2005, the registrant of Agnique MMF Mosquito Larvacide & Pupicide (EPA Reg. No. 53263-28), Cognis Corporation (through their agent, Lewis & Harrison), requested that the nomenclature associated with the product's active ingredient be revised from "poly(oxy-1 ,2-ethanediyl), a-isooctadecyl-whydroxy-It to "poly(oxy-1,2-ethanediyl), a-iso(C14_2o)-w-hydroxy-" and that the manufacturing process be modified to allow for the use of an additional source of starting material. These two requests are addressed below. 

### I. Revision of Active Ingredient Nomenclature The current approved Confidential Statement of Formula (CSF) for Agnique MMF Mosquito Larvacide & Pupicide (EPA Reg. No. 53263-28) dated August 27,1996, lists the active ingredient as "poly(oxy-1 ,2-ethanediyl), a-isooctadecyl-w-hydroxy-" with a Chemical Abstracts Service (CAS) Registry Number of 52292-17-8
. The product is formulated as 100% active ingredient. The most recent approved product label (accepted July 14, 2003) has an active ingredient declaration of "poly(oxy-1 ,2- ethanediyl), a-Isooctadecyl-w-hydroxyl" (sic) with the weight percentage of active ingredient being given as 100%. Poly(oxy-1 ,2-ethanediyl), a-isooctadecyl-w-hydroxy- is also referred to by the synonym POE isostearyl alcohol. The process by which POE isostearyl alcohol is manufactured involves the ethoxylation of isostearyl alcohol. The registrant has

## ! submitted analytical data on the composition of the isostearyl alcohol starting material used in the manufacture of the Agnique MMF active ingredient as well as the POE isostearyl alcohol active ingredient. Both the isostearyl alcohol starting material and the POE isostearyl alcohol active ingredient were analyzed using reversed-phase high performance liquid chromatography (RP-HPLC) separation followed by mass spectroscopy (MS) detection. The RP-HPLC/MS data included in the 

### 10/11/2005 submission indicate that the isostearyl alcohol starting material used in the manufacture of Agnique MMF is comprised of linear and branched forms of octadecanol (a C18 alcohol) as well as various amounts of other C16-C20 alcohols
. The POE isostearyl alcohol active ingredient also is comprised of ethoxylated C18 alcohols as well as various amounts of other C 16-C20 alcohol ethoxylates. II. Use of an Additional Source of Starting Material In the 

### 10/11/2005 submission, the registrant also seeks to use an additional source of starting material in addition to the isostearyl alcohol currently being utilized. The registrant is proposing to utilize NEODOL 67, a product manufactured by Shell Chemicals, in the manufacture of Agnique MMF. NEODOL 67 is described by Shell Chemicals as a "C 16 and C17 high purity primary alcohol" in its product datasheet (http://www.shellchemicals.com/chemicals/pdf/neodol/neodol 67
.pdf?section=our prod ucts). The registrant has provided RP-HPLC/MS data on NEODOL 67 with demonstrate consistency with the Shell Chemicals description and specifications of NEODOL 67
. Conclusion and Recommendations Based on the compositional analysis information submitted on both the isostearyl alcohol starting material and the POE isostearyl alcohol active ingredient, the most appropriate chemical nomenclature that should be used to describe this active ingredient is "poly(oxy-1,2-ethanediyl), a-(C16-20 branched and linear alkyl)-whydroxy-" and this name should appear on both the product's CSF and label as the active ingredient name. The CAS Reg. No. of 52292-17-8 that is listed on the proposed CSF dated October 11,2005 is specific to poly(oxy-1 ,2-ethanediyl), aisooctadecyl-w-hydroxy-" and should not be associated with poly(oxy-1 ,2-ethanediyl), a- (C16-20 branched and linear alkyl)-w-hydroxy-." A CAS Reg. No. that corresponds to poly(oxy-1 ,2-ethanediyl), a-(C16-20 branched and linear alkyl)-w-hydroxy- should be used. Based on the compositional analysis information submitted on NEODOL 67, the Shell Chemicals datasheet for NEODOL 67, and the compositional analysis provided on the NEODOL 67 ethoxylate, it has been concluded that the active ingredient formed from NEODOL 67 and ethylene oxide comports with the name "poly(oxy-1 ,2- ethanediyl), a-(C16-20 branched and linear alkyl)-w-hydroxy-" and that the composition of the active ingredient formed from NEODOL 67 and ethylene oxide would not significantly differ from the POE isostearyl alcohol active ingredient in Agnique MMF, therefore the use of NEODOL 67 in the manufacture of Agnique MMF is acceptable
. 20f2

# LEWIS & 

# HARRISON Consultants In Govarnmant Affairs 122 C Street, N.W., Suite 740 Washington, D.C. 20001 telephone 202.393.3903 fax 202.393.3906



### Daniel Kenny, Product Manager (01) Insecticide-Rodenticide Branch Registration Division (7505C) Office ofPesticide Programs Environmental Protection Agency 1801 South Bell Street Arlington, VA 22202 

### re: Agnique MMF, EPA Reg. No. 53263-28 Registrant: Cognis Corporation October 11, 2005



### Amendment to Change Nomenclature ofActive Ingredient PRIA Category R34 Dear Dan: As a follow-up to the May 19,2005 meeting and the June 11,2005 submission concerning Agnique MMF, I am formally submitting an amendment for this product. The amendmentproposes to revise thenomenclature ofthe active ingredient from poly (oxy-1.2-ethanediyl), a.-isooctadecyl-co-hydroxyl to poly (oxy-1,2-ethanediyl), a.-iso (C I4

_ 2o

### )-co-hydroxyl and would also allow the use ofalternate beginning materials in the manufacture ofthe active ingredient. Please note that the documents submitted on June 11, 2005 in support ofthis change are being resubmitted in the appropriate "86-5" format. In addition, five copies ofthe amended product label and a Confidential tatement ofFormula (C ) with the revised name ofthe active ingredient are enclosed. No other changes have been made to the product label or CSF. Ifyou have any questions regarding this submission, please contact me at (202) 393-3903, ext. 14. Sincerely,

# ~ Eliot Harrison Agent for CognisPlease read ills/rue/ions 011 reverse before comple lIf!iorm. Form Approved, OMB No . 2070-0060**A~oval** expires 05-31-98 

# EPA United States 

## D Registration OPP Identifier Number 

### Environmental Protection Agency 

## 0 Amendment 

# 296886 Washington, DC 20460 

## D Other 

### Application for Pesticide - Section 1 I. Company/Product Number 2 . EPA Product Manager 3 . Proposed Classification



### 53263-28 Daniel Kenny 4. Company/Product (Name) PM#

### ~None 

# D Restricted



### AGNIQUEMMF Team 31 5 . Name and Address ofApplicant (Inc/ude ZIP Code) 6 . Expedited Review. In accordance with FIFRA Section 3(cX3)(b)(l), my product is 

### Cognis Corporation similar or identical in composition and labeling to : 

### 4900 Este Avenue EPA Reg. No. 

### Cincinnati, OH 

# o Check if/his is a new addresss Product Name 

### Section - 

## n [8] Amendment - Explain below. D Final printed labels in response to Agency letter dated

_ _ _ 

# o Resubmission m response to Agency letter dated 

# o "Me Too" Application D Notification - Explain below. D Other - Explain below Explanation: Use additional page(s) is necessary. (For Section I and Section II.) 

### Change in the nomenclature for the active ingredient. Refer to cover letter for details. PRIA Category R34 Section -ill I. Material This Product Will Be Packaged In : Child-Resistant Packaging Unit Packaging Water Soluble Packaging 2. Type ofContainer Dyes- DYes DYes 

# o Metal 

# o No 

# o No D No D Plastic *CertijicatiOit must be If"Yes" No . pcr If"Yes" No . pc" 

# o Glass submitted Unit Packaging wgt. container Package wgt. Container 

# o Paper 

# D Othcr (Spccifiy) 3 . Location ofN t Cuntents Information 4 . Size(s) Retail Contamer 5 . Location ofLabel Directions D l .abel 

# o Container 

### 21 oz. 

# o On Label 

# D On labeling accompanying product 6. Manner 111 Whl h L abel l. Aflixed to PlOduct 

# o Lithograph 

# o Othcr 

# o Paper glued 

# o Stenciled 

### Section - IV I. Contact Point (Complete ilellls direc/l y below for idell/ijicalion of individual to be contacted . if lIecessary. to process this application) Name Title Telephone No. (Include Area Code) 

### Eliot L Harrison Agent for Cognis (202) 393-3903 Certification 6 . Date Application Received I certify that the statements (have made on this form and all attachments thereto are true, accurate and complete. (acknowledge 

### (Stamped) that any knowingly false or misleading statemcnt may be punishable by fine or imprisonment or both under applicable law. 2.

## s;'"""~~:v 

# V 3 . Title 

### Agent for Cog1!is 4 . Typed Name \ v 5. Date 

### Eliot 

### 1. Harrison October 11, 2005



## --- EPA Form 8570-( (Rev. 8-94) Previous editions are obsolete . . Whlte- EPA Fi le Copy (ongmal) Yellow- Applicant Copy

### CBI Cross-Reference Number 3 This cross-reference number is used in the study in place of the following pages at the indicated volume and page numbers
.

VOLUME PAGE NUMBERS

## ~**~~~ON** 1=.oR

## GEl£f~o~ HFAA

## RE~ERENCE**.** 1 24-25 Manufacturing Process 

### 1O(d)(1 )A) 

### DELETED PAGES: FORMULATION PROCESS

Page 22 0(24

### Page 23 of24

# . OLUME 1 OF 1

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### Characterization of the Active Ingredient in Agnique MMF , EPA Reg. No. 53263-28, and the Use of an Alternative Beginning Material in the Manufacturing Process DATA REQUIREMENT 

### OPPTS Guideline Numbers : 830.1550 830.1600 AUTHOR 

### Jianhua Mao, Ph.D
. Eliot Harrison STUDY COMPLETED ON 

### June 11, 2005 PERFORMING LABORATORY 

### Cognis Inc
. 4900 Este Avenue Cincinnati, OH



### Page 1 of27 

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# • Material to be added to a Mini-Jacket (in the case where an e-Jacket exists)



# Send to SIG: check box 

# D This material is : 

# .r-! New stamped-accepted label

# NewCSF o . Notification D Final Printed Label c Other:



# -------------- Instructions: Attach this notice on top of the**mater~al.** 

# It must be clipped all together and there should be NO STAPLES in the material. Then give the material with this coversheet to staff in the Information Services Center (Room. 230). 

# Reviewer's Name: 

# oJi?Iiv'**~ ~**  Phone: 

# ,/VJJtJ:fS9Pf 

# Division:

# -Red __ Date:

# <fJ5~**~/,** Current as of Wednesday , March 01 , 2006

# • UNITED STATES ENVIRONMENTAL PROTECTION



## JI 

## I 5 

## ? 0.8 Ms. Catherine Rice c/o Cognis 

### Corporation Lewis & 

### Harrison 122 C Street, N.W. Suite 740 Washington, DC 20001 WASHINGTON, D.C. 20460



### Subject: Addition ofCASRN to the Confidential Statement ofFormula Agnique MMF Mosquito Larvicide & 

### Pupicide EPA Reg. No. 53263-28 Your Submission date, May 18, 2006 Dear Ms. Rice: OFFICE OF PREVENTION, PESTICIDES AND TOXIC SUBSTANCES



### The Agency has received and reviewed your alternate confidential statement offormula for the above named product dated May 18, 2006 with the addition ofCASRN. The CSF is acceptable and has been placed in the Agency file. Ifthere are questions call me at 703 305- 5409. Sincerely, 

# /sl Dani Daniel Insecticide-Rodenticide Branch Registration Division 7505P

RecycledlRecyclabl•• Printed wfth Vegetable 011 Based Inks on 100% Recycled Paper (40% Postoonsumer)

# , LEWIS & 

# HARRJSON Consultants in Government Affair. 

### May 18, 2006 

# •

122 C Street, N
.W., Suite 740 Washington, D.C
. 20001 telephone 202.393.3903 fax 202.393
.3906



### Document Processing Desk (7505P) Office of Pesticide Programs (AMEND) US Environmental Protection Agency One Potomac Yard 2777 S Crystal Drive Arlington , VA 22202 ATTN: Daniel Kenny Product Manager, Team 7 RE: Cognis Corporation Agnique MMF 

### Mosquito Larvicide & 

### Pupicide (EPA Reg. No. 53263-28) Updated CSF to add CASRN Dear Mr
. Kenny: 

# •

Hand Delivered

On behalf of Cognis Corporation ("Cognis"), I am submitting an updated Confidential Statement of Formula (CSF) for the product, Agnique MMF 

### Mosquito Larvicide & 

### Pupicide (EPA Reg. No. 53263-28). The only difference between the approved CSF and the updated CSF is the addition of the CASRN to the active ingredient. This was requested in Kerry Leifer's review dated March 7 , 2006 (attached). If you have any questions or if I may be for further assistance, please contact me at 202-393-3903 ext.13 or bye-mail atcrice@lewisharrison .com

Catherine Rice Agent for Cognis Corporation •••• 

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# • • UNITED STATES ENVIRONMENTAL PROTECTION AGENCY WASHINGTON, D
.C
. 20460 OFFICE OF PREVENTION , PESTICIDES , AND TOXIC SUBSTANCES


### March 7, 2006 MEMORANDUM SUBJECT:

FROM:
TO: Review of Amendment to Change Nomenclature of Active Ingredient Agnique MMF Mosquito Larvacide 

## & Pupicide EPA Reg, No. 53263-28 DP# 323953 Kerry Leifer

# 1!.~. Inert

# Ingredien~**~e** me ranch Registration Division ( 505C) Dan Kenny (PM-01) Insecticide-Rodenticide Branch Registration Division (7505C) In a submission dated October 11, 2005, the registrant of Agnique MMF Mosquito Larvacide & Pupicide (EPA Reg. No. 53263-28), Cognis Corporation (through their agent, Lewis & Harrison), requested that the nomenclature associated with the product's active ingredient be revised from "poly(oxy-1 ,2-ethanediyl), a-isooctadecyl-whydroxy-" to "poly(oxy-1 ,2-ethanediyl), a-iso(C14-2o)-w-hydroxy-" and that the manufacturing process be modified to allow for the use of an additional source of starting material. These two requests are addressed below. 

### I. 

## Revision of Active Ingredient Nomenclature The current approved Confidential Statement of Formula (CSF) for Agnique MMF Mosquito Larvacide 

## & Pupicide (EPA Reg. No. 53263-28) dated August 27,1996, lists the active ingredient as "poly(oxy-1 ,2-ethanediyl), a-isooctadecyl-w-hydroxy-" with a Chemical Abstracts Service (CAS) Registry Number of 52292-17-8
. The product is formulated as 100% active ingredient. The most recent approved product label (accepted July 14, 2003) has an active ingredient declaration of "poly(oxy-1 ,2- ethanediyl), a-Isooctadecyl-w-hydroxyl" (sic) with the weight percentage of active ingredient being given as 100%
. 

### • ••• 

## • 

## •

•••• Poly(oxy-1 ,2-ethanediyl) , a-isooctadecyl-w-hydroxy- is also referred to by the-· :.: synonym POE isostearyl alcohol. The process by which POE isostearyl alcohol is ••• • manufactured involves the ethoxylation of isostearyl alcohol. The registrant has ...: 

# .. " 

## • • •••••• 

### • •

•••• 

## • •

•••• 

### •••• 

# · ., •••••• 

## • 

## •• • • •••••• 

## • •



## •• ••••• 

## • • •

### ••••

# • • submitted analytical data on the composition of the isostearyl alcohol starting material used in the manufacture of the Agnique MMF active ingredient as well as the POE isostearyl alcohol active ingredient. Both the isostearyl alcohol starting material and the POE isostearyl alcohol active ingredient were analyzed using reversed-phase high performance liquid chromatography (RP-HPLC) separation followed by mass spectroscopy (MS) detection
. The RP-HPLC/MS data included in the 

### 10/11/2005 submission indicate that the isostearyl alcohol starting material used in the manufacture of Agnique MMF is comprised of linear and branched forms of octadecanol (a C 1 8 

### alcohol) as well as various amounts of other C16-C20 alcohols
. The POE isostearyl alcohol active ingredient also is comprised of ethoxylated C 18 

### alcohols as well as various amounts of other C16 -C20 alcohol ethoxylates
. II. Use of an Additional Source of Starting Material In the 101-11/2005-submission, the registrant also see- ks to use an additional - - - source of starting material in addition to the isostearyl alcohol currently being utilized. The registrant is proposing to utilize NEODOL 67, a product manufactured by Shell Chemicals , in the manufacture of Agnique MMF
. NEODOL 67 is described by Shell Chemicals as a "C16 and C 17 

### high purity primary alcohol " in its product datasheet (http ://www
.shellchemicals
.com/chemicals/pdf/neodollneodoI 67
.pdf?section=our prod ucts). The registrant has provided RP-HPLC/MS data on NEODOL 67 with demonstrate consistency with the Shell Chemicals description and specifications of NEODOL 67
. Conclusion and Recommendations Based on the compositional analysis information submitted on both the isostearyl alcohol starting material and the POE isostearyl alcohol active ingredient, the most appropriate chemical nomenclature that should be used to describe this active ingredient is "poly(oxy-1,2-ethanediyl), a-(C16-20 branched and linear alkyl)-whydroxy-" and this name should appear on both the product's CSF and label as the active ingredient name . The CAS Reg
. No
. of 52292-17-8 that is listed on the proposed CSF dated October 11, 2005 is specific to poly(oxy-1 ,2-ethanediyl) , aisooctadecyl-w-hydroxy-" and should not be associated with poly(oxy- 1,2-ethanediyl),

_ a- (C16-20 branched and linear alkyl)-w-hydroxy- ." A A 

## ego o . hat c r pon 0



### 01 - ,2- h n 

### i 

### f), 1 - br nchad and 

### II r Ikyl -w-h r - h Id b Based on the compositional analysis information submitted on NEODOL 67, the Shell Chemicals datasheet for NEODOL 67, and the compositional analysis provided on the NEODOL 67 ethoxylate, it has been concluded that the active ingredient formed from NEODOL 67 and ethylene oxide comports with the name "poly(oxy-1 ,2- ethanediyl), a-(C16-20 branched and linear alkyl)-w-hydroxy-" and that the composLttGlii. of the active ingredient formed from NEODOL 67 and ethylene oxide would not •••• • significantly differ from the POE isostearyl alcohol active ingredient in Agnique**MM~:.** 

### :.: therefore the use of NEODOL 67 in the manufacture of Agnique MMF is acceptable
. .. 2of2 

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## • • • ••••;n"I'YIII"',t;""" on reverse before 

# EPA United States 

### Environmental Protection Agency Washington, DC 20460 Form 

# o Registration 

## I:8J Amendment 

# o Other: Application for Pesticide - Section I 2 . EPA 

### Daniel PM# 

### 01 ager res 05-31-98 opp Identifier Number 

# 297085

3 . Proposed Classification 

# r8J None 

# o Restricted 6 . 

### Expedited Review
. In accordance with FIFRA Section 3(c)(3) (b)(I), my product is similar or identical in composition and labeling to : EPA Reg
. No
. ___________ _ Product Name__________________________ ___ 

### Section - II Amendment - Explain below
. Final printed labels in response to Agency letter dated ____ _ Resubmission in response to Agency letter dated ____ __ 

# D "Me Too· Application Notification - below
. Other - below 

### Explanation : Use additional page(s) if necessary. (For Section I and Section II)
. 

### Addition of the CASRN to the Confidential Statement of Formula in response to Kerry Leifer's review dated March 7, 2006. No other changes are being proposed.



### *Certification must be submitted Section - III

If "Yes · No
. per Unit Packaging wgt. container Soluble Packaging
No
. per container 2 . Type of Container 

# D Metal 

# D Plastic 

# D Glass 

# D Paper 

# D Other (Specifiy) 3 . Location of Net Contents Information 

# D Label 

# D Container ize(s) Retail Container 5 . Location of 

# D On Label 6 . Manner in Which Label is Affixed to Product Lithograph Paper glued Stenciled Other ________________________________ _

Name



### Eliot I. Harrison, Lewis & 

### Harrison, 122 C St. NW Suite 7 Washi DC 20001 

### Section -IV Agent for Cognis Corp. Certification I certify that the statements I have made on this form and all attachments thereto are true , accurate and complete
. acknowledge that any knowingly false or misleading statement may be punishable by fine or imprisonment or both under law
. 2 . ""....>t"".

revious editions are 

### Agent for Cognis Corp. 5 . M 

### 2006 White- EPA File Code) 

### 202-393-3903 Received 

### (Stamped) 

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