MATERIAL SAFETY DATA SHEET

Product Trade Name: 19N

Revision Date: 03-Jan-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: 19N

Synonyms: None

Chemical Family: Blend

Application: Non-Emulsifier

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Quaternary ammonium

compounds

30 - 60% Not applicable Not applicable

Methanol 67-56-1 30 - 60% 200 ppm 200 ppm (S)

Isopropanol 67-63-0 5 - 10% 200 ppm 400 ppm

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye and skin burns. May cause respiratory irritation. May cause

headache, dizziness, and other central nervous system effects. May be fatal if

swallowed. May cause blindness. May be absorbed through the skin. Repeated

overexposure may cause liver and kidney effects. Flammable.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

19N

Page 1 of 6

HESI100001
Notes to Physician Not Applicable

5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 76

Flash Point/Range (C): 24

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards May be ignited by heat, sparks or flames. Closed containers may explode in fire.

Use water spray to cool fire exposed surfaces. Decomposition in fire may produce

toxic gases. Runoff to sewer may cause fire or explosion hazard.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 3, Flammability 3, Reactivity 0

HMIS Ratings: Flammability 3, Reactivity 0, Health 3

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Wear self-contained breathing apparatus in

enclosed areas.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Remove ignition sources and work with nonsparking tools. Contain spill with sand or other inert materials. Scoop up and

remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse. Ground and bond containers

when transferring from one container to another.

Storage Information Store away from oxidizers. Keep from heat, sparks, and open flames. Keep container

closed when not in use. Product has a shelf life of 12 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Positive pressure self-contained breathing apparatus if methanol is released.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

19N

Page 2 of 6

HESI100002
9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Amber

Odor: Alcohol

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 0.92

Density @ 20 C (lbs./gallon): 7.66

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): -40

Freezing Point/Range (C): -40

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Oxides of nitrogen. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation Causes severe respiratory irritation. May cause central nervous system depression

including headache, dizziness, drowsiness, incoordination, slowed reaction time,

slurred speech, giddiness and unconsciousness.

Skin Contact Causes severe skin irritation. May cause skin burns. May be absorbed through the

skin and produce effects similar to those caused by inhalation and/or ingestion.

Eye Contact Causes severe eye irritation May cause eye burns.

Ingestion Causes burns of the mouth, throat and stomach. May be fatal or cause blindness if

swallowed. May cause central nervous system depression including headache,

dizziness, drowsiness, muscular weakness, incoordination, slowed reaction time,

fatigue blurred vision, slurred speech, giddiness, tremors and convulsions.

19N

Page 3 of 6

HESI100003
Aggravated Medical Conditions Skin disorders. Eye ailments.

Chronic Effects/Carcinogenicity Prolonged or repeated exposure may cause eye, blood, lung, liver, kidney, heart,

central nervous system and spleen damage.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Slowly biodegradable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Flammable Liquid, Corrosive, N.O.S., 3, (8), UN2924, III, (24.4 C)

(Contains Methanol, Aryl Quaternary of Fatty Amines)

NAERG 132

Canadian TDG

19N

Page 4 of 6

HESI100004
Flammable Liquid, Corrosive, N.O.S.(Contains Methanol, Aryl Quaternary of Fatty Amines), 3, (8), UN2924, III, (24.4 C)

ADR

UN2924,Flammable Liquid, Corrosive, N.O.S.(Contains Methanol, Aryl Quaternary of Fatty Amines), 3, (8), III

Air Transportation

ICAO/IATA

UN2924,Flammable Liquid, Corrosive, N.O.S., 3, (8), III

(Contains Methanol, Aryl Quaternary of Fatty Amines Solution)

Sea Transportation

IMDG

UN2924,Flammable Liquid, Corrosive, N.O.S.(Contains Methanol, Aryl Quaternary of Fatty Amines), 3, (8), III, (24.4 C)

EmS F-E, S-C

Other Shipping Information

Labels: Flammable Liquid

Corrosive

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Methanol//67-56-1

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 1813 Gallons based on Methanol (CAS: 67-56-1).

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Ignitability D001

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

19N

Page 5 of 6

HESI100005
WHMIS Hazard Class B2 Flammable Liquids

E Corrosive Material

D1A Very Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

19N

Page 6 of 6

HESI100006
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: ABF

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: ABF

Synonyms: None

Chemical Family: Fluoride

Application: Additive

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Ammonium bifluoride 1341-49-7 60 - 100% 2.5 mg/m3 2.5 mg/m3

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory burns. May be harmful if swallowed. May

damage bones.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

ABF

Page 1 of 6

HESI100007
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Use water spray to cool fire exposed surfaces. Decomposition in fire may produce

toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 3, Flammability 0, Reactivity 0

HMIS Ratings: Health 3, Flammability 0, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid creating or inhaling dust. Wash

hands after use. Launder contaminated clothing before reuse.

Storage Information Store away from acids. Store away from alkalis. Store in a cool, dry location.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Localized ventilation should be used to control dust

levels.

Respiratory Protection HEPA Respirator.

Hand Protection Butyl rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid

Color: White

Odor: Acrid

pH: 1

ABF

Page 2 of 6

HESI100008
9. PHYSICAL AND CHEMICAL PROPERTIES

Specific Gravity @ 20 C (Water=1): 1.5

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): 43.7

Boiling Point/Range (F): 463

Boiling Point/Range (C): 239

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: 0

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): 57.05

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong acids. Strong alkalis.

Hazardous Decomposition

Products

Ammonia. Hydrogen fluoride.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation Causes severe respiratory irritation.

Skin Contact Causes severe burns.

Eye Contact Causes severe eye burns.

Ingestion Causes burns of the mouth, throat and stomach. May cause damage to bones and

teeth.

Aggravated Medical Conditions Skin disorders. Eye ailments.

Chronic Effects/Carcinogenicity Prolonged or repeated exposure may result in fluorosis. Symptoms include nausea,

vomiting, loss of appetite, diarrhea, and/or constipation. Fluorosis also results in

bone density increase.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

ABF

Page 3 of 6

HESI100009
Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging This bag may contain residue of a hazardous material. Some authorities may

regulate such containers as hazardous waste. Dispose of container according to

national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

UN1727,Ammonium Hydrogendifluoride, Solid, 8, II

RQ (Ammonium Bifluoride - 45.4 kg.)

NAERG 154

Canadian TDG

Ammonium Hydrogendifluoride, Solid, 8, UN1727, II

ADR

UN1727,Ammonium Hydrogendifluoride, Solid, 8, II

Air Transportation

ABF

Page 4 of 6

HESI100010
ICAO/IATA

UN1727,Ammonium Hydrogendifluoride, Solid, 8, II

RQ (Ammonium Bifluoride - 45.4 kg.)

Sea Transportation

IMDG

UN1727,Ammonium Hydrogendifluoride, Solid, 8, II

RQ (Ammonium Bifluoride - 45.4 kg.)

EmS F-A, S-B

Other Shipping Information

Labels: Corrosive

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 100 Pounds based on Ammonium bifluoride (CAS:

1341-49-7).

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class E Corrosive Material

D1B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

ABF

Page 5 of 6

HESI100011
Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

ABF

Page 6 of 6

HESI100012
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: ACETIC ACID

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: ACETIC ACID

Synonyms: None

Chemical Family: Organic acid

Application: Acid

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Acetic acid 64-19-7 30 - 60% 10 ppm 10 ppm

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory burns. May be harmful if swallowed.

Combustible.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

ACETIC ACID

Page 1 of 6

HESI100013
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 109

Flash Point/Range (C): 42

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): 5.4

Flammability Limits in Air - Upper (%): 16

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Use water spray to cool fire exposed surfaces. Decomposition in fire may produce

toxic gases. Do not allow runoff to enter waterways.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 2, Reactivity 0

HMIS Ratings: Health 2, Flammability 2, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Neutralize with lime slurry, limestone, or soda

ash. Contain spill with sand or other inert materials. Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse.

Storage Information Store away from alkalis. Store away from oxidizers. Store in a cool well ventilated

area. Keep container closed when not in use.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Organic vapor/acid gas respirator.

Hand Protection Impervious rubber gloves.

Skin Protection Full protective chemical resistant clothing.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Clear

Odor: Acrid

ACETIC ACID

Page 2 of 6

HESI100014
9. PHYSICAL AND CHEMICAL PROPERTIES

pH: 2.9

Specific Gravity @ 20 C (Water=1): 1.05

Density @ 20 C (lbs./gallon): 8.75

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 244

Boiling Point/Range (C): 117

Freezing Point/Range (F): 62

Freezing Point/Range (C): 16

Vapor Pressure @ 20 C (mmHg): 11.7

Vapor Density (Air=1): Not Determined

Percent Volatiles: 100

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): 60.6

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong alkalis.

Hazardous Decomposition

Products

Toxic fumes. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation Causes severe respiratory irritation.

Skin Contact Causes severe burns.

Eye Contact May cause eye burns.

Ingestion Causes burns of the mouth, throat and stomach.

Aggravated Medical Conditions Skin disorders.

Chronic Effects/Carcinogenicity Prolonged, excessive exposure may cause erosion of the teeth.

Other Information None known.

Toxicity Tests

Oral Toxicity: LD50: 3310 mg/kg (Rat)

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

ACETIC ACID

Page 3 of 6

HESI100015
Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Readily biodegradable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

UN2790,Acetic Acid Solution, 8, III

RQ (Acetic Acid - 5683 kg.)

NAERG 153

Canadian TDG

Acetic Acid Solution, 8, UN2790, III

ADR

UN2790,Acetic Acid Solution, 8, III

Air Transportation

ICAO/IATA

UN2790,Acetic Acid Solution, 8, III

RQ (Acetic Acid - 5683 kg.)

ACETIC ACID

Page 4 of 6

HESI100016
Sea Transportation

IMDG

UN2790,Acetic Acid Solution, 8, III

RQ (Acetic Acid - 5683 kg.)

EmS F-A, S-B

Other Shipping Information

Labels: Corrosive

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 1587 Gallons based on Acetic acid (CAS: 64-19-7).

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Ignitability D001

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class B3 Combustible Liquids

E Corrosive Material

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

ACETIC ACID

Page 5 of 6

HESI100017
Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

ACETIC ACID

Page 6 of 6

HESI100018
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: ACTIVATOR IT

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: ACTIVATOR IT

Synonyms: None

Chemical Family: Carbohydrate

Application: Catalyst

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Carbohydrates 60 - 100% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview No significant hazards expected. Airborne dust may be explosive.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Under normal conditions, first aid procedures are not required.

Notes to Physician Not Applicable

ACTIVATOR IT

Page 1 of 5

HESI100019
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Organic dust in the presence of an ignition source can be explosive in high

concentrations. Good housekeeping practices are required to minimize this

potential.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 0, Flammability 0, Reactivity 0

HMIS Ratings: Health 0, Flammability 0, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

None known.

Procedure for Cleaning /

Absorption

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid creating or inhaling dust.

Storage Information Store away from oxidizers. Store in a cool, dry location.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Not normally needed. But if significant exposures are possible then the following

respirator is recommended:

Dust/mist respirator. (95%)

Hand Protection Normal work gloves.

Skin Protection Normal work coveralls.

Eye Protection Safety glasses.

Other Precautions None known.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid

Color: White

Odor: Odorless

ACTIVATOR IT

Page 2 of 5

HESI100020
9. PHYSICAL AND CHEMICAL PROPERTIES

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 1.5

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: 0

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): 20

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): 342.34

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation None known.

Skin Contact None known.

Eye Contact May cause mild eye irritation.

Ingestion None known

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

ACTIVATOR IT

Page 3 of 5

HESI100021
Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Readily biodegradable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

ACTIVATOR IT

Page 4 of 5

HESI100022
Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

None

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law Does not apply.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law Does not apply.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class Un-Controlled

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

ACTIVATOR IT

Page 5 of 5

HESI100023
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: ACTIVATOR W

Revision Date: 05-Jan-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: ACTIVATOR W

Synonyms: None

Chemical Family: Alcohol

Application: Accelerator

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Alcohols, C12-14-secondary,

ethoxylated

84133-50-6 30 - 60% Not applicable Not applicable

Methanol 67-56-1 30 - 60% 200 ppm 200 ppm (S)

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause headache, dizziness, and

other central nervous system effects. May be fatal if swallowed. May cause

blindness. May be absorbed through the skin. Repeated overexposure may cause

liver and kidney effects. Flammable.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

ACTIVATOR W

Page 1 of 6

HESI100024
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 54

Flash Point/Range (C): 12.2

Flash Point Method: TCC

Autoignition Temperature (F): 725

Autoignition Temperature (C): 385

Flammability Limits in Air - Lower (%): 6

Flammability Limits in Air - Upper (%): 36.5

Fire Extinguishing Media Carbon Dioxide, Dry Chemicals, Foam.

Special Exposure Hazards May be ignited by heat, sparks or flames. Use water spray to cool fire exposed

surfaces. Closed containers may explode in fire. Decomposition in fire may produce

toxic gases. Runoff to sewer may cause fire or explosion hazard.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 3, Flammability 3, Reactivity 0

HMIS Ratings: Health 3, Flammability 3, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Wear self-contained breathing apparatus in

enclosed areas.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Remove ignition sources and work with nonsparking tools. Contain spill with sand or other inert materials. Scoop up and

remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse. Ground and bond containers

when transferring from one container to another.

Storage Information Store away from oxidizers. Keep from heat, sparks, and open flames. Keep container

closed when not in use.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Positive pressure self-contained breathing apparatus if methanol is released.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

ACTIVATOR W

Page 2 of 6

HESI100025
9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Clear colorless

Odor: Alcohol

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 0.92

Density @ 20 C (lbs./gallon): 7.66

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 180

Boiling Point/Range (C): 82

Freezing Point/Range (F): -24

Freezing Point/Range (C): -31

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Miscible

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Formaldehyde. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. May cause central nervous system depression

including headache, dizziness, drowsiness, incoordination, slowed reaction time,

slurred speech, giddiness and unconsciousness.

Skin Contact May cause skin irritation. May be absorbed through the skin and contribute to the

symptoms listed under ingestion. May cause skin defatting with prolonged exposure.

Eye Contact May cause moderate eye irritation.

Ingestion May be fatal or cause blindness if swallowed. May cause headache, dizziness,

nausea, vomiting, gastrointestinal irritation and central nervous system depression.

Aggravated Medical Conditions Skin disorders. Eye ailments.

ACTIVATOR W

Page 3 of 6

HESI100026
Chronic Effects/Carcinogenicity Prolonged or repeated exposure may cause eye, blood, lung, liver, kidney, heart,

central nervous system and spleen damage.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Methanol Solution, 3, UN1230, II, (12.2 C)

(Contains Methanol)

RQ (Methanol - 2273 kg.)

NAERG 131

Canadian TDG

ACTIVATOR W

Page 4 of 6

HESI100027
Methanol Solution(Contains Methanol), 3, UN1230, II, (12.2 C)

ADR

UN1230,Methanol Solution(Contains Methanol), 3, II

Air Transportation

ICAO/IATA

UN1230,Methanol Solution, 3, II

(Contains Methanol Solution)

RQ (Methanol - 2273 kg.)

Sea Transportation

IMDG

UN1230,Methanol Solution(Contains Methanol), 3, II, (12.2 C)

RQ (Methanol - 2273 kg.)

EmS F-E, S-D

Other Shipping Information

Labels: Flammable Liquid

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Methanol//67-56-1

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 1613 Gallons based on Methanol (CAS: 67-56-1).

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Ignitability D001

California Proposition 65 The California Proposition 65 regulations apply to this product.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

ACTIVATOR W

Page 5 of 6

HESI100028
Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class B2 Flammable Liquids

D1A Very Toxic Materials

D1B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

ACTIVATOR W

Page 6 of 6

HESI100029
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: ADOMITE REGAIN

Revision Date: 03-Jan-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: ADOMITE REGAIN

Synonyms: None

Chemical Family: Modified Starch

Application: Fluid Loss Additive

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Diatomaceous earth 61790-53-2 1 - 5% 10 mg/m3 15 mg/m3

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. Airborne dust may be explosive.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

ADOMITE REGAIN

Page 1 of 5

HESI100030
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media All standard firefighting media.

Special Exposure Hazards Organic dust in the presence of an ignition source can be explosive in high

concentrations. Good housekeeping practices are required to minimize this

potential. Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 1, Reactivity 0

HMIS Ratings: Flammability 1, Reactivity 0, Health 1

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid creating or inhaling dust.

Storage Information Store away from oxidizers. Store in a cool, dry location.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Dust/mist respirator. (95%)

Hand Protection Normal work gloves.

Skin Protection Normal work coveralls.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid

Color: Light yellow

Odor: Starch

pH: Not Determined

Specific Gravity @ 20 C (Water=1): Not Determined

ADOMITE REGAIN

Page 2 of 5

HESI100031
9. PHYSICAL AND CHEMICAL PROPERTIES

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Partially soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause mild respiratory irritation. May cause allergic respiratory reaction.

Skin Contact May cause skin irritation.

Eye Contact May cause eye irritation.

Ingestion None known

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

ADOMITE REGAIN

Page 3 of 5

HESI100032
Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Readily biodegradable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Not restricted

Canadian TDG

Not restricted

ADR Not restricted

Air Transportation

ICAO/IATA Not restricted

Sea Transportation

IMDG Not restricted

Other Shipping Information

Labels: None

ADOMITE REGAIN

Page 4 of 5

HESI100033
15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory Product contains one or more components not listed on inventory.

WHMIS Hazard Class Un-Controlled

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

ADOMITE REGAIN

Page 5 of 5

HESI100034
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: AF-61

Revision Date: 03-Jan-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: AF-61

Synonyms: None

Chemical Family: Blend

Application: Emulsifier

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Heavy aromatic petroleum

naphtha

64742-94-5 30 - 60% 5 mg/m3 5 mg/m3

Naphthalene 91-20-3 1 - 5% 10 ppm 10 ppm

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause headache, dizziness, and

other central nervous system effects. May be harmful if swallowed. Combustible.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Get medical attention! If vomiting occurs, keep head lower than hips to prevent

aspiration.

Notes to Physician Not Applicable

AF-61

Page 1 of 6

HESI100035
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 151

Flash Point/Range (C): 66

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 2, Reactivity 0

HMIS Ratings: Flammability 2, Reactivity 0, Health 2

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors.

Storage Information Store away from oxidizers. Store in a cool well ventilated area. Keep container

closed when not in use.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Organic vapor respirator.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Dark brown

Odor: Aromatic hydrocarbon

pH: 4.15

AF-61

Page 2 of 6

HESI100036
9. PHYSICAL AND CHEMICAL PROPERTIES

Specific Gravity @ 20 C (Water=1): 0.959

Density @ 20 C (lbs./gallon): 7.987

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): > 1

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Insoluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Hydrogen chloride. Oxides of nitrogen. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. May cause central nervous system depression

including headache, dizziness, drowsiness, incoordination, slowed reaction time,

slurred speech, giddiness and unconsciousness.

Skin Contact May cause skin irritation.

Eye Contact May cause eye irritation.

Ingestion Aspiration into the lungs may cause chemical pneumonitis including coughing,

difficulty breathing, wheezing, coughing up blood and pneumonia, which can be fatal.

Aggravated Medical Conditions Skin disorders. Eye ailments.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

AF-61

Page 3 of 6

HESI100037
Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Slowly biodegradable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Not restricted

DOT (Bulk)

Combustible Liquid, N.O.S.,Combustible Liquid, NA1993, III

(Contains Petroleum Naphtha)

Canadian TDG

Not restricted

ADR Not restricted

Air Transportation

ICAO/IATA Not restricted

Sea Transportation

AF-61

Page 4 of 6

HESI100038
IMDG Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 The California Proposition 65 regulations apply to this product.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class B3 Combustible Liquids

D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

AF-61

Page 5 of 6

HESI100039
Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

AF-61

Page 6 of 6

HESI100040
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: AF-70

Revision Date: 03-Jan-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: AF-70

Synonyms: None

Chemical Family: Blend

Application: Emulsifier

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Ethylene glycol 107-21-1 10 - 30% 100 mg/m3 50 ppm

Heavy aromatic petroleum

naphtha

64742-94-5 10 - 30% 5 mg/m3 5 mg/m3

Acetic acid 64-19-7 10 - 30% 10 ppm 10 ppm

Naphthalene 91-20-3 1 - 5% 10 ppm 10 ppm

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory burns. May cause headache, dizziness, and

other central nervous system effects. May be absorbed through the skin. May be

harmful if swallowed. Repeated overexposure may cause liver and kidney effects.

May cause birth defects. Combustible.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes Immediately flush eyes with large amounts of water for at least 30 minutes. Seek

prompt medical attention.

Ingestion If swallowed, do NOT induce vomiting. Give victim two glasses of water, Call a

physician immediately. Never give anything by mouth to an unconscious person.

AF-70

Page 1 of 6

HESI100041
Notes to Physician Not Applicable

5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 147

Flash Point/Range (C): 63.9

Flash Point Method: TCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases. Vapors are heavier than air and may

accumulate in low areas. Vapors may travel along the ground to be ignited at distant

locations.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 3, Flammability 2, Reactivity 0

HMIS Ratings: Flammability 2, Reactivity 0, Health 3

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Remove ignition sources and work with non-sparking tools. Isolate spill and stop

leak where safe. Contain spill with sand or other inert materials. Scoop up and

remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse. Ground and bond containers

when transferring from one container to another.

Storage Information Keep from heat, sparks, and open flames. Store in a cool well ventilated area. Keep

container closed when not in use. Store at temperatures below 140 F (60 C).

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Not normally needed. But if significant exposures are possible then the following

respirator is recommended:

Organic vapor/acid gas respirator.

Hand Protection Neoprene gloves. Nitrile gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

AF-70

Page 2 of 6

HESI100042
Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Clear to Amber

Odor: Acetic acid

pH: 5.5 - 6.5

Specific Gravity @ 20 C (Water=1): 0.947 - 0.959

Density @ 20 C (lbs./gallon): 7.89 - 7.99

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): -10

Freezing Point/Range (C): -23.3

Vapor Pressure @ 20 C (mmHg): 5.2 @38C

Vapor Density (Air=1): > 1

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Insoluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers. Strong alkalis.

Hazardous Decomposition

Products

Oxides of nitrogen. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. May cause central nervous system depression

including headache, dizziness, drowsiness, incoordination, slowed reaction time,

slurred speech, giddiness and unconsciousness.

Skin Contact May cause skin burns. May be absorbed through the skin and produce nervous

system effects.

Eye Contact May cause eye burns. May cause permanent eye damage.

AF-70

Page 3 of 6

HESI100043
Ingestion Aspiration into the lungs may cause chemical pneumonitis including coughing,

difficulty breathing, wheezing, coughing up blood and pneumonia, which can be fatal.

May cause metabolic acidosis. May cause kidney damage. May be harmful if

swallowed.

Aggravated Medical Conditions Skin disorders. Eye ailments.

Chronic Effects/Carcinogenicity Prolonged or repeated exposure may cause kidney damage. Prolonged or repeated

exposure may cause liver, heart, blood and brain damage. Prolonged or repeated

exposure may cause reproductive system damage. Prolonged or repeated exposure

may cause embryo and fetus toxicity.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Slowly biodegradable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

AF-70

Page 4 of 6

HESI100044
DOT

Corrosive Liquid, Acidic, Organic, N.O.S., 8, UN3265, III

(Contains Acetic Acid)

NAERG 153

Canadian TDG

Corrosive Liquid, Acidic, Organic, N.O.S.(Contains Acetic Acid), 8, UN3265, III

ADR

UN3265,Corrosive Liquid, Acidic, Organic, N.O.S.(Contains Acetic Acid), 8, III

Air Transportation

ICAO/IATA

UN3265,Corrosive Liquid, Acidic, Organic, N.O.S., 8, III

(Contains Acetic Acid Solution)

Sea Transportation

IMDG

UN3265,Corrosive Liquid, Acidic, Organic, N.O.S.(Contains Acetic Acid), 8, III

Other Shipping Information

Labels: Corrosive

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Fire Hazard

Chronic Health Hazard

EPA SARA (313) Chemicals Naphthalene//91-20-3

Ethylene Glycol//107-21-1

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 636 Gallons based on Naphthalene (CAS: 91-20-3).

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 The California Proposition 65 regulations apply to this product.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

AF-70

Page 5 of 6

HESI100045
Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class B3 Combustible Liquids

D1B Toxic Materials

D2A Very Toxic Materials

E Corrosive Material

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

AF-70

Page 6 of 6

HESI100046
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: ALDACIDE® G ANTIMICROBIAL

Revision Date: 14-Oct-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: ALDACIDE® G ANTIMICROBIAL

Synonyms: None

Chemical Family: Aldehyde

Application: Biocide

Manufacturer/Supplier Halliburton Energy Services, Inc.

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Glutaraldehyde 111-30-8 10 - 30% 0.05 ppm Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview Keep out of reach of children. May cause eye burns. May cause irreversible eye

damage. May cause severe skin irritation. May be harmful if swallowed. May be

harmful if inhaled. May cause allergic skin reaction.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention.

Eyes Immediately flush eyes with large amounts of water for at least 30 minutes. Seek

prompt medical attention.

Ingestion Do NOT induce vomiting. Give nothing by mouth. Obtain immediate medical

attention.

Notes to Physician Probable mucosal damage may contraindicate the use of gastric lavage. No

specific antidote. Treat symptomatically.

ALDACIDE® G ANTIMICROBIAL

Page 1 of 6

HESI100047
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): > 527

Autoignition Temperature (C): > 275

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 3, Flammability 1, Reactivity 0

HMIS Ratings: Health 3, Flammability 1, Physical Hazard 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Use only competent persons for cleanup.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Do not swallow.

Wash hands after use. Launder contaminated clothing before reuse.

Storage Information Store away from acids. Store away from alkalis. Keep container closed when not in

use. Product has a shelf life of 12 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation. If vapors are strong enough to be irritating to the

nose or eyes, the TLV is probably being exceeded and special ventilation or

respiratory protection maybe required.

Respiratory Protection Full Facepiece Respirator with Organic vapor cartridge with particulate prefilter.

Hand Protection Nitrile gloves. Butyl rubber gloves.

Skin Protection Butyl coated apron or clothing.

Eye Protection Splashproof chemical monogoggles or safety glasses with side shields in conjunction

with a face shield. Do NOT wear contact lenses.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

ALDACIDE® G ANTIMICROBIAL

Page 2 of 6

HESI100048
9. PHYSICAL AND CHEMICAL PROPERTIES

Color: Clear light yellow

Odor: Sharp

pH: 3.1-4.5

Specific Gravity @ 20 C (Water=1): 1.064

Density @ 20 C (lbs./gallon): 8.87

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 213

Boiling Point/Range (C): 100.5

Freezing Point/Range (F): -4 to 23

Freezing Point/Range (C): -5 to -20

Vapor Pressure @ 20 C (mmHg): 0.2

Vapor Density (Air=1): 0.8

Percent Volatiles: 100

Evaporation Rate (Butyl Acetate=1): 0.9

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: -0.333

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Avoid temperatures greater than 100 F (38 C).

Incompatibility (Materials to

Avoid)

Strong acids. Strong alkalis.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation Harmful if inhaled. Causes severe respiratory irritation. Vapors given off by heated

product may be harmful. May cause allergic respiratory reaction. Inhalation of vapors

may result in skin sensitization.

Skin Contact May cause skin irritation. May cause skin burns on prolonged contact. Harmful if

absorbed through the skin. Prolonged or widespread contact may result in the

absorption of potentially harmful amounts of material. This product contains

ingredients which may produce an allergic skin reaction. It should be treated as a

skin sensitizer.

Eye Contact May cause eye burns. May cause permanent eye damage. High vapor concentration

will cause irritation.

Ingestion Causes burns of the mouth, throat and stomach. Harmful if swallowed. Aspiration

into the lungs may cause chemical pneumonitis including coughing, difficulty

breathing, wheezing, coughing up blood and pneumonia, which can be fatal.

Aggravated Medical Conditions Skin disorders. Lung disorders. Liver disorders.

ALDACIDE® G ANTIMICROBIAL

Page 3 of 6

HESI100049
Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: LD50: 320 mg/kg (Rat)

Dermal Toxicity: LD50: > 2000 mg/kg (Rabbit)

Inhalation Toxicity: LC50: 0.28-0.39 mg/l/4 hr (Rat)

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Readily biodegradable

Bio-accumulation Not expected to bioaccumulate.

 Ecotoxicological Information

Acute Fish Toxicity: May be highly toxic to aquatic life.

LC50: (96 hour) 13 mg/l (Lepomis macrochirus)

Acute Crustaceans Toxicity:TLM48: 0.11 mg/l (Acartia tonsa)

TLM48: 29.73 mg/l (Daphnia magna)

Acute Algae Toxicity: EC50: 8.1 mg/l (Skeletonema costatum)

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted by surface modes.

ALDACIDE® G ANTIMICROBIAL

Page 4 of 6

HESI100050
Canadian TDG

Not restricted by surface modes.

ADR

 Not restricted by surface modes.

Air Transportation

ICAO/IATA

 Not restricted by surface modes.

UN3334, Aviation Regulated Liquid, N.O.S (Contains Glutaraldehyde), 9

Sea Transportation

IMDG

 Not restricted by surface modes.

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

Federal Insecticide, Fungicide

and Rodenticide Act:

Label in accordance with Federal Insecticide, Fungicide, and Rodenticide Act

(FIFRA) requirements.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class D1B Toxic Materials

D2B Toxic Materials

E Corrosive Material

ALDACIDE® G ANTIMICROBIAL

Page 5 of 6

HESI100051
16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

ALDACIDE® G ANTIMICROBIAL

Page 6 of 6

HESI100052
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: ALCHEK

Revision Date: 05-Jan-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: ALCHEK

Synonyms: None

Chemical Family: Organic acid

Application: Scale Inhibitor

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Hydroxyacetic acid 79-14-1 60 - 100% 3 ppm Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory burns. May be harmful if swallowed.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

ALCHEK

Page 1 of 6

HESI100053
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Reacts with metals to generate flammable hydrogen gas. Decomposition in fire may

produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 3, Flammability 0, Reactivity 0

HMIS Ratings: Health 3, Flammability 0, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Neutralize to pH of 6-8. Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse.

Storage Information Store away from alkalis. Store in a cool well ventilated area. Keep container closed

when not in use. Product has a shelf life of 36 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Organic vapor/acid gas respirator.

Hand Protection Impervious rubber gloves.

Skin Protection Full protective chemical resistant clothing.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Clear amber

Odor: Mild burnt sugar

ALCHEK

Page 2 of 6

HESI100054
9. PHYSICAL AND CHEMICAL PROPERTIES

pH: 0.5

Specific Gravity @ 20 C (Water=1): 1.25

Density @ 20 C (lbs./gallon): 10.41

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 234

Boiling Point/Range (C): 112

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: 30

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Miscible

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: 0.0776

Molecular Weight (g/mole): 76.05

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers. Strong alkalis. Sulfuric acid. Ammonium compounds. Amines.

Isocyanates. Contact with metals.

Hazardous Decomposition

Products

Flammable hydrogen gas. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation Causes severe respiratory irritation.

Skin Contact May cause skin burns.

Eye Contact May cause eye burns.

Ingestion Causes burns of the mouth, throat and stomach. May cause abdominal pain,

vomiting, nausea, and diarrhea.

Aggravated Medical Conditions Skin disorders.

Chronic Effects/Carcinogenicity Prolonged, excessive exposure may cause erosion of the teeth.

Other Information None known.

Toxicity Tests

Oral Toxicity: LD50: 4240 mg/kg (Rat)

Dermal Toxicity: Not determined

ALCHEK

Page 3 of 6

HESI100055
Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Readily biodegradable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Corrosive Liquid, Acidic, Organic, N.O.S., 8, UN3265, II

(Contains Glycolic Acid)

NAERG 153

Canadian TDG

Corrosive Liquid, Acidic, Organic, N.O.S.(Contains Glycolic Acid), 8, UN3265, II

ADR

UN3265,Corrosive Liquid, Acidic, Organic, N.O.S.(Contains Glycolic Acid), 8, II

Air Transportation

ICAO/IATA

UN3265,Corrosive Liquid, Acidic, Organic, N.O.S., 8, II

(Contains Glycolic Acid Solution)

ALCHEK

Page 4 of 6

HESI100056
Sea Transportation

IMDG

UN3265,Corrosive Liquid, Acidic, Organic, N.O.S.(Contains Glycolic Acid), 8, II

EmS F-A, S-B

Other Shipping Information

Labels: Corrosive

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Corrosivity D002

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law Does not apply.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law Does not apply.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class E Corrosive Material

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

ALCHEK

Page 5 of 6

HESI100057
Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

ALCHEK

Page 6 of 6

HESI100058
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: ALUMINUM CHLORIDE SOLUTION

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: ALUMINUM CHLORIDE SOLUTION

Synonyms: None

Chemical Family: Inorganic Salt

Application: Additive

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Aluminum chloride 10 - 30% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory burns. May be harmful if swallowed.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

ALUMINUM CHLORIDE SOLUTION

Page 1 of 6

HESI100059
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 0, Reactivity 0

HMIS Ratings: Health 2, Flammability 0, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Neutralize to pH of 6-8. Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse.

Storage Information Store away from alkalis. Store in a cool well ventilated area. Keep container closed

when not in use. Product has a shelf life of 24 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Dust/mist respirator. (95%)

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Light yellow-green

Odor: Mild acidic

pH: 1

ALUMINUM CHLORIDE SOLUTION

Page 2 of 6

HESI100060
9. PHYSICAL AND CHEMICAL PROPERTIES

Specific Gravity @ 20 C (Water=1): 1.27

Density @ 20 C (lbs./gallon): 10.58

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 212

Boiling Point/Range (C): 100

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): 23

Vapor Density (Air=1): Not Determined

Percent Volatiles: 73

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): 10.58

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong alkalis. Mild steel. Cyanides.

Hazardous Decomposition

Products

Hydrogen chloride.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation Causes severe respiratory irritation.

Skin Contact Causes severe skin irritation. May cause skin burns.

Eye Contact Causes severe eye irritation which may damage tissue. May cause eye burns.

Ingestion Causes burns of the mouth, throat and stomach.

Aggravated Medical Conditions Skin disorders.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: LD50: 7100 mg/kg (rat)

Dermal Toxicity: LD50: > 7940 mg/kg (Rabbit)

Inhalation Toxicity: Not determined

ALUMINUM CHLORIDE SOLUTION

Page 3 of 6

HESI100061
Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

UN2581,Aluminum Chloride Solution, 8, III

NAERG 154

Canadian TDG

Aluminum Chloride Solution, 8, UN2581, III

ADR

UN2581,Aluminum Chloride Solution, 8, III

Air Transportation

ICAO/IATA

UN2581,Aluminum Chloride Solution, 8, III

Sea Transportation

ALUMINUM CHLORIDE SOLUTION

Page 4 of 6

HESI100062
IMDG

UN2581,Aluminum Chloride Solution, 8, III

EmS F-A, S-B

Other Shipping Information

Labels: Corrosive

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Corrosivity D002

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class E Corrosive Material

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

ALUMINUM CHLORIDE SOLUTION

Page 5 of 6

HESI100063
Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

ALUMINUM CHLORIDE SOLUTION

Page 6 of 6

HESI100064
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: AMMONIUM FLUORIDE - 35% SOLUTION

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: AMMONIUM FLUORIDE - 35% SOLUTION

Synonyms: None

Chemical Family: Fluoride

Application: Additive

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Ammonium fluoride 12125-01-8 30 - 60% 2.5 mg/m3 2.5 mg/m3

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May be harmful if swallowed. May

damage bones.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

AMMONIUM FLUORIDE - 35% SOLUTION

Page 1 of 6

HESI100065
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Use water spray to cool fire exposed surfaces. Do not allow runoff to enter

waterways. Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 3, Flammability 0, Reactivity 1

HMIS Ratings: Health 3, Flammability 0, Reactivity 1

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse.

Storage Information Store away from acids. Store in a cool well ventilated area. Keep container closed

when not in use.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Ammonia respirator. Positive pressure self-contained breathing apparatus in

enclosed areas.

Hand Protection Butyl rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Colorless to slight yellow

AMMONIUM FLUORIDE - 35% SOLUTION

Page 2 of 6

HESI100066
9. PHYSICAL AND CHEMICAL PROPERTIES

Odor: Odorless

pH: 7-7.8

Specific Gravity @ 20 C (Water=1): 1.11

Density @ 20 C (lbs./gallon): 9.26

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 180 - 240

Boiling Point/Range (C): 82 - 116

Freezing Point/Range (F): -9

Freezing Point/Range (C): -23

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): 37

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong acids.

Hazardous Decomposition

Products

Ammonia. Hydrogen fluoride. Ammonium bifluoride.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation.

Skin Contact May cause skin irritation.

Eye Contact May cause eye irritation.

Ingestion May cause damage to bones and teeth.

Aggravated Medical Conditions Skin disorders.

Chronic Effects/Carcinogenicity Prolonged or repeated exposure may result in fluorosis. Symptoms include nausea,

vomiting, loss of appetite, diarrhea, and/or constipation. Fluorosis also results in

bone density increase.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

AMMONIUM FLUORIDE - 35% SOLUTION

Page 3 of 6

HESI100067
Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

UN3287,Toxic Liquid, Inorganic, N.O.S.(Contains Ammonium Fluoride), 6.1, III

RQ (Ammonium Fluoride - 45.4 kg.)

NAERG 151

Canadian TDG

Toxic Liquid, Inorganic, N.O.S.(Contains Ammonium Fluoride), 6.1, UN3287, III

ADR

UN3287,Toxic Liquid, Inorganic, N.O.S.(Contains Ammonium Fluoride), 6.1, III

Air Transportation

AMMONIUM FLUORIDE - 35% SOLUTION

Page 4 of 6

HESI100068
ICAO/IATA

UN3287,Toxic Liquid, Inorganic, N.O.S., 6.1, III

(Contains Ammonium Fluoride Mixture)

RQ (Ammonium Fluoride - 45.4 kg.)

Sea Transportation

IMDG

UN3287,Toxic Liquid, Inorganic, N.O.S.(Contains Ammonium Fluoride), 6.1, III

RQ (Ammonium Fluoride - 45.4 kg.)

EmS F-A, S-A

Other Shipping Information

Labels: Poison

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 33 Gallons based on Ammonium fluoride (CAS:

12125-01-8).

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class D1B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

AMMONIUM FLUORIDE - 35% SOLUTION

Page 5 of 6

HESI100069
Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

AMMONIUM FLUORIDE - 35% SOLUTION

Page 6 of 6

HESI100070
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: ANHIB II INHIBITOR

Revision Date: 03-Jan-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: ANHIB II INHIBITOR

Synonyms: None

Chemical Family: Blend

Application: Corrosion Inhibitor

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Ammonium bisulfite 10192-30-0 10 - 30% Not applicable Not applicable

Isopropanol 67-63-0 5 - 10% 200 ppm 400 ppm

Trimethylammonium chloride 593-81-7 1 - 5% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause headache, dizziness, and

other central nervous system effects. May be harmful if swallowed. Repeated

overexposure may cause liver and kidney effects. Flammable.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

ANHIB II INHIBITOR

Page 1 of 6

HESI100071
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 74

Flash Point/Range (C): 23

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards May be ignited by heat, sparks or flames. Use water spray to cool fire exposed

surfaces. Closed containers may explode in fire. Decomposition in fire may produce

toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 3, Reactivity 0

HMIS Ratings: Flammability 3, Reactivity 0, Health 2

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Remove ignition sources and work with nonsparking tools. Contain spill with sand or other inert materials. Scoop up and

remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse. Ground and bond containers

when transferring from one container to another.

Storage Information Store away from oxidizers. Store in a cool well ventilated area. Keep from heat,

sparks, and open flames. Keep container closed when not in use. Product has a

shelf life of 24 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Organic vapor respirator.

In high concentrations, supplied air respirator or a self-contained breathing

apparatus.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

ANHIB II INHIBITOR

Page 2 of 6

HESI100072
Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Red

Odor: Pungent

pH: 4.2-4.8

Specific Gravity @ 20 C (Water=1): 1.16

Density @ 20 C (lbs./gallon): 9.66

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): 89

Vapor Density (Air=1): Not Determined

Percent Volatiles: 8

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Oxides of nitrogen. Oxides of sulfur. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. May cause central nervous system depression

including headache, dizziness, drowsiness, incoordination, slowed reaction time,

slurred speech, giddiness and unconsciousness.

Skin Contact May cause moderate skin irritation.

Eye Contact May cause moderate eye irritation.

Ingestion May cause abdominal pain, vomiting, nausea, and diarrhea. Irritation of the mouth,

throat, and stomach.

Aggravated Medical Conditions Skin disorders.

ANHIB II INHIBITOR

Page 3 of 6

HESI100073
Chronic Effects/Carcinogenicity Repeated overexposure may cause liver and kidney effects.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Slowly biodegradable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Flammable Liquid, N.O.S., 3, UN1993, III, (23.3 C)

(Contains Isopropanol)

NAERG 128

Canadian TDG

Flammable Liquid, N.O.S.(Contains Isopropanol), 3, UN1993, III, (23.3 C)

ANHIB II INHIBITOR

Page 4 of 6

HESI100074
ADR

UN1993,Flammable Liquid, N.O.S.(Contains Isopropanol), 3, III

Air Transportation

ICAO/IATA

UN1993,Flammable Liquid, N.O.S., 3, III

(Contains Isopropanol Solution)

Sea Transportation

IMDG

UN1993,Flammable Liquid, N.O.S.(Contains Isopropanol), 3, III, (23.3 C)

EmS F-E, S-E

Other Shipping Information

Labels: Flammable Liquid

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Isopropanol//67-63-0

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 1921 Gallons based on Ammonium bisulfite (CAS:

10192-30-0).

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Ignitability D001

California Proposition 65 The California Proposition 65 regulations apply to this product.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory Product contains one or more components not listed on inventory.

ANHIB II INHIBITOR

Page 5 of 6

HESI100075
WHMIS Hazard Class B2 Flammable Liquids

D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

ANHIB II INHIBITOR

Page 6 of 6

HESI100076
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: AQF-2 FOAMING AGENT

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: AQF-2 FOAMING AGENT

Synonyms: None

Chemical Family: Blend

Application: Foaming Agent

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Ethylene glycol monobutyl

ether

111-76-2 10 - 30% 20 ppm 50 ppm

Diethylene glycol 111-46-6 5 - 10% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause headache, dizziness, and

other central nervous system effects. May be harmful if swallowed. Combustible.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

AQF-2 FOAMING AGENT

Page 1 of 6

HESI100077
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 142

Flash Point/Range (C): 61

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 2, Reactivity 0

HMIS Ratings: Health 1, Flammability 2, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Remove ignition sources and work with nonsparking tools. Contain spill with sand or other inert materials. Scoop up and

remove. Do NOT spread spilled product with water.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse.

Storage Information Store away from oxidizers. Store in a cool well ventilated area. Keep container

closed when not in use. Keep from freezing. Product has a shelf life of 36 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Organic vapor respirator.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Clear light yellow

AQF-2 FOAMING AGENT

Page 2 of 6

HESI100078
9. PHYSICAL AND CHEMICAL PROPERTIES

Odor: Bland

pH: 6.5-8.5 (10%)

Specific Gravity @ 20 C (Water=1): 1.038

Density @ 20 C (lbs./gallon): 8.65

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): < 1

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Oxides of sulfur. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. May cause central nervous system depression

including headache, dizziness, drowsiness, incoordination, slowed reaction time,

slurred speech, giddiness and unconsciousness.

Skin Contact May cause skin irritation.

Eye Contact May cause moderate eye irritation.

Ingestion Irritation of the mouth, throat, and stomach. May cause abdominal pain, vomiting,

nausea, and diarrhea. May cause central nervous system depression including

headache, dizziness, drowsiness, muscular weakness, incoordination, slowed

reaction time, fatigue blurred vision, slurred speech, giddiness, tremors and

convulsions.

Aggravated Medical Conditions Skin disorders.

Chronic Effects/Carcinogenicity Prolonged or repeated exposure may cause fetal damage and testicular effects.

AQF-2 FOAMING AGENT

Page 3 of 6

HESI100079
Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

DOT (Bulk)

NA1993, Combustible Liquid, N.O.S., Combustible Liquid, III

(Contains Ethylene Glycol Monobutyl Ether)

Canadian TDG

Not restricted

AQF-2 FOAMING AGENT

Page 4 of 6

HESI100080
ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

Other Shipping Information

Labels: Combustible

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Glycol Ethers//111-76-2

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class B3 Combustible Liquids

D2B Toxic Materials

AQF-2 FOAMING AGENT

Page 5 of 6

HESI100081
16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

AQF-2 FOAMING AGENT

Page 6 of 6

HESI100082
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: Arctic SandWedgeTM

Revision Date: 05-Jan-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: Arctic SandWedgeTM

Synonyms: FDP-S732-04

Chemical Family: Blend

Application: Conductivity Enhancer

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Heavy aromatic petroleum

naphtha

64742-94-5 5 - 10% 5 mg/m3 5 mg/m3

Isopropanol 67-63-0 30 - 60% 200 ppm 400 ppm

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause headache, dizziness, and

other central nervous system effects. Repeated overexposure may cause liver and

kidney effects. Flammable. May be harmful if swallowed.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse. Destroy or properly dispose of contaminated shoes.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Get medical attention! If vomiting occurs, keep head lower than hips to prevent

aspiration.

Notes to Physician Not Applicable

Arctic SandWedgeTM

Page 1 of 6

HESI100083
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 66

Flash Point/Range (C): 18

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): 2

Flammability Limits in Air - Upper (%): 12.7

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards May be ignited by heat, sparks or flames. Use water spray to cool fire exposed

surfaces. Closed containers may explode in fire. Decomposition in fire may produce

toxic gases. Do not allow runoff to enter waterways.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 3, Reactivity 0

HMIS Ratings: Health 2, Flammability 3, Physical Hazard 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Wear self-contained breathing apparatus in

enclosed areas.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Remove ignition sources and work with nonsparking tools. Contain spill with sand or other inert materials. Scoop up and

remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse. Ground and bond containers

when transferring from one container to another.

Storage Information Store away from oxidizers. Keep from heat, sparks, and open flames. Keep container

closed when not in use. Product has a shelf life of 24 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection If engineering controls and work practices cannot keep exposure below occupational

exposure limits or if exposure is unknown, wear a NIOSH certified, European

Standard EN 149, or equivalent respirator when using this product. Selection of and

instruction on using all personal protective equipment, including respirators, should

be performed by an Industrial Hygienist or other qualified professional.

Organic vapor respirator.

Hand Protection Use Viton or 4H gloves. Butyl rubber gloves. Nitrile gloves.

Skin Protection Rubber apron.

Arctic SandWedgeTM

Page 2 of 6

HESI100084
Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Dark brown

Odor: Bland

pH: 8

Specific Gravity @ 20 C (Water=1): 0.9

Density @ 20 C (lbs./gallon): 7.52

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: 68

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Insoluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause central nervous system depression including headache, dizziness,

drowsiness, incoordination, slowed reaction time, slurred speech, giddiness and

unconsciousness.

May cause respiratory irritation.

Skin Contact May cause skin irritation. May be absorbed through the skin and produce effects

similar to those caused by inhalation and/or ingestion.

Eye Contact Causes severe eye irritation which may damage tissue.

Arctic SandWedgeTM

Page 3 of 6

HESI100085
Ingestion May cause abdominal pain, vomiting, nausea, and diarrhea. Aspiration into the lungs

may cause chemical pneumonitis including coughing, difficulty breathing, wheezing,

coughing up blood and pneumonia, which can be fatal. May cause central nervous

system depression including headache, dizziness, drowsiness, muscular weakness,

incoordination, slowed reaction time, fatigue blurred vision, slurred speech,

giddiness, tremors and convulsions.

Aggravated Medical Conditions Skin disorders.

Chronic Effects/Carcinogenicity Repeated overexposure may cause liver and kidney effects.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Arctic SandWedgeTM

Page 4 of 6

HESI100086
UN1993,Flammable Liquid, N.O.S.(Contains Isopropanol, Heavy Aromatic Naphtha), 3, II, (18.9 C)

NAERG 128

Canadian TDG

Flammable Liquid, N.O.S.(Contains Isopropanol, Heavy Aromatic Naphtha), 3, UN1993, II, (18.9 C)

ADR

UN1993,Flammable Liquid, N.O.S.(Contains Isopropanol, Heavy Aromatic Naphtha), 3, II

Air Transportation

ICAO/IATA

UN1993,Flammable Liquid, N.O.S., 3, II

(Contains Isopropanol, Heavy Aromatic Naphtha Solution)

Sea Transportation

IMDG

UN1993,Flammable Liquid, N.O.S.(Contains Isopropanol, Heavy Aromatic Naphtha), 3, II, (18.9 C)

EmS F-E, S-E

Other Shipping Information

Labels: Flammable Liquid

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Ignitability D001

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Arctic SandWedgeTM

Page 5 of 6

HESI100087
Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class B2 Flammable Liquids

D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

Arctic SandWedgeTM

Page 6 of 6

HESI100088
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: Aromatic 100

Revision Date: 03-Jan-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: Aromatic 100

Synonyms: None

Chemical Family: Aromatic hydrocarbon

Application: Solvent

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Cumene 98-82-8 1 - 5% 50 ppm 50 ppm

Xylene 1330-20-7 1 - 5% 100 ppm 100 ppm

1,2,4 Trimethylbenzene 95-63-6 30 - 60% 25 ppm Not applicable

Light aromatic solvent 64742-95-6 60 - 100% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause headache, dizziness, and

other central nervous system effects. May be harmful if swallowed. Combustible.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin Remove contaminated clothing and launder before reuse.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Get medical attention! If vomiting occurs, keep head lower than hips to prevent

aspiration.

Notes to Physician Not Applicable

Aromatic 100

Page 1 of 6

HESI100089
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 108

Flash Point/Range (C): 42

Flash Point Method: Not Determined

Autoignition Temperature (F): 880

Autoignition Temperature (C): 471

Flammability Limits in Air - Lower (%): 1.9

Flammability Limits in Air - Upper (%): 12.6

Fire Extinguishing Media Carbon Dioxide, Dry Chemicals, Foam.

Special Exposure Hazards Use water spray to cool fire exposed surfaces. Closed containers may explode in

fire. Decomposition in fire may produce toxic gases. Vapors are heavier than air and

may accumulate in low areas. Vapors may travel along the ground to be ignited at

distant locations.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 2, Reactivity 0

HMIS Ratings: Flammability 2, Reactivity 0, Health 1

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Wear self-contained breathing apparatus in

enclosed areas.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Remove ignition sources and work with nonsparking tools. Contain spill with sand or other inert materials. Scoop up and

remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse. Ground and bond containers

when transferring from one container to another.

Storage Information Store away from oxidizers. Keep from heat, sparks, and open flames.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Organic vapor respirator.

In high concentrations, supplied air respirator or a self-contained breathing

apparatus.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Aromatic 100

Page 2 of 6

HESI100090
Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Clear Colorless

Odor: Aromatic hydrocarbon

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 0.87

Density @ 20 C (lbs./gallon): 7.30

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 318-338

Boiling Point/Range (C): 159-170

Freezing Point/Range (F): -76

Freezing Point/Range (C): -60

Vapor Pressure @ 20 C (mmHg): 0.4

Vapor Density (Air=1): 4.2

Percent Volatiles: 100

Evaporation Rate (Butyl Acetate=1): 0.3

Solubility in Water (g/100ml): Insoluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): 0.9 @25C

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Toxic fumes. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. May cause central nervous system depression

including headache, dizziness, drowsiness, incoordination, slowed reaction time,

slurred speech, giddiness and unconsciousness.

Skin Contact Prolonged or repeated contact may cause slight skin irritation.

Eye Contact May cause mild eye irritation.

Ingestion Irritation of the mouth, throat, and stomach. May cause abdominal pain, vomiting,

nausea, and diarrhea. Aspiration into the lungs may cause chemical pneumonitis

including coughing, difficulty breathing, wheezing, coughing up blood and

pneumonia, which can be fatal.

Aromatic 100

Page 3 of 6

HESI100091
Aggravated Medical Conditions Skin disorders. Eye ailments.

Chronic Effects/Carcinogenicity Prolonged or repeated exposure may cause central nervous system and brain

effects.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Petroleum Distillates, N.O.S., 3, UN1268, III, (42.2 C)

NAERG 128

Canadian TDG

Petroleum Distillates, N.O.S., 3, UN1268, III, (42.2 C)

Aromatic 100

Page 4 of 6

HESI100092
ADR

UN1268,Petroleum Distillates, N.O.S., 3, III

Air Transportation

ICAO/IATA

UN1268,Petroleum Distillates, N.O.S., 3, III

Sea Transportation

IMDG

UN1268,Petroleum Distillates, N.O.S., 3, III, (42.2 C)

EmS F-E, S-E

Other Shipping Information

Labels: Flammable Liquid

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Xylene//1330-20-7

Cumene//98-82-8

1,2,4-Trimethylbenzene//95-63-6

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 158 Gallons based on Xylene (CAS: 1330-20-7).

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Ignitability D001

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

Aromatic 100

Page 5 of 6

HESI100093
WHMIS Hazard Class B3 Combustible Liquids

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

Aromatic 100

Page 6 of 6

HESI100094
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: AS-10 ANTI-SLUDGING AGENT

Revision Date: 05-Jan-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: AS-10 ANTI-SLUDGING AGENT

Synonyms: None

Chemical Family: Organic acid

Application: Anti-sludging Agent

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Dodecylbenzene sulfonic acid 27176-87-0 30 - 60% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory burns. May cause headache, dizziness, and

other central nervous system effects. May be harmful if swallowed. May be absorbed

through the skin. May cause allergic skin reaction. Repeated overexposure may

cause liver and kidney effects.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Treat symptomatically.

AS-10 ANTI-SLUDGING AGENT

Page 1 of 6

HESI100113
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not DeterminedMin: > 180

Flash Point/Range (C): Not DeterminedMin: > 82

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards May deflagarate or explode in a fire due to heat and/or confinement. Evacuate area.

Fight fire from a safe distance and from a protected location. Decomposition in fire

may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 1, Reactivity 0

HMIS Ratings: Health 2, Flammability 1, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Neutralize to pH of 6-8. Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse.

Storage Information Store away from alkalis. Store away from oxidizers. Keep from heat, sparks, and

open flames. Keep container closed when not in use. Product has a shelf life of 24

months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Organic vapor/acid gas respirator with a dust/mist filter.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

AS-10 ANTI-SLUDGING AGENT

Page 2 of 6

HESI100114
9. PHYSICAL AND CHEMICAL PROPERTIES

Color: Dark brown

Odor: Characteristic

pH: < 1

Specific Gravity @ 20 C (Water=1): 1.083

Density @ 20 C (lbs./gallon): 9.02

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): -25

Freezing Point/Range (C): -31

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers. Strong alkalis.

Hazardous Decomposition

Products

Oxides of sulfur. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation Causes severe respiratory burns. May cause Central Nervous System effects.

Excessive inhalation causes headache, dizziness, nausea and incoordination.

Skin Contact Harmful if absorbed through the skin. Causes severe burns. May cause an allergic

skin reaction.

Eye Contact Causes severe eye burns.

Ingestion Causes burns of the mouth, throat and stomach.

Aggravated Medical Conditions Skin disorders. Lung disorders.

Chronic Effects/Carcinogenicity Prolonged or repeated exposure may cause liver, kidney and lung effects.

Other Information None known.

Toxicity Tests

Oral Toxicity: LD50: > 2000 mg/kg (Rat)

AS-10 ANTI-SLUDGING AGENT

Page 3 of 6

HESI100115
Dermal Toxicity: LD50: > 2000 mg/kg (Rabbit)

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Corrosive Liquid, Acidic, Organic, N.O.S., 8, UN3265, III

(Contains Dodecylbenzenesulfonic Acid)

RQ (Dodecylbenzene sulfonic acid - 1134 kg)

NAERG 153

Canadian TDG

Corrosive Liquid, Acidic, Organic, N.O.S.(Contains Dodecylbenzenesulfonic Acid), 8, UN3265, III

ADR

UN3265,Corrosive Liquid, Acidic, Organic, N.O.S.(Contains Dodecylbenzenesulfonic Acid), 8, III

Air Transportation

ICAO/IATA

UN3265,Corrosive Liquid, Acidic, Organic, N.O.S., 8, III

AS-10 ANTI-SLUDGING AGENT

Page 4 of 6

HESI100116
(Contains Dodecylbenzenesulfonic Acid Solution)

RQ (Dodecylbenzene sulfonic acid - 1134 kg)

Sea Transportation

IMDG

UN3265,Corrosive Liquid, Acidic, Organic, N.O.S.(Contains Dodecylbenzenesulfonic Acid), 8, III

RQ (Dodecylbenzene sulfonic acid - 1134 kg)

EmS F-A, S-B

Other Shipping Information

Labels: Corrosive

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

Fire Hazard

EPA SARA (313) Chemicals Not applicable.

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 277 Gallons based on Dodecylbenzene sulfonic

acid (CAS: 27176-87-0).

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Corrosivity D002

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class E Corrosive Material

B3 Combustible Liquids

D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

AS-10 ANTI-SLUDGING AGENT

Page 5 of 6

HESI100117
Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

AS-10 ANTI-SLUDGING AGENT

Page 6 of 6

HESI100118
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: AS-5 ANTI-SLUDGING AGENT

Revision Date: 05-Jan-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: AS-5 ANTI-SLUDGING AGENT

Synonyms: None

Chemical Family: Blend

Application: Anti-sludging Agent

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Dodecylbenzene sulfonic acid 27176-87-0 60 - 100% Not applicable Not applicable

Isopropanol 67-63-0 10 - 30% 200 ppm 400 ppm

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory burns. May cause headache, dizziness, and

other central nervous system effects. May be harmful if swallowed. May be absorbed

through the skin. May cause allergic skin reaction. Repeated overexposure may

cause liver and kidney effects. Flammable.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

AS-5 ANTI-SLUDGING AGENT

Page 1 of 6

HESI100095
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 95

Flash Point/Range (C): 35

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards May be ignited by heat, sparks or flames. Closed containers may explode in fire.

Use water spray to cool fire exposed surfaces. Decomposition in fire may produce

toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 3, Flammability 3, Reactivity 0

HMIS Ratings: Health 3, Flammability 3, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Wear self-contained breathing apparatus in

enclosed areas.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Remove ignition sources and work with nonsparking tools. Contain spill with sand or other inert materials. Scoop up and

remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse. Ground and bond containers

when transferring from one container to another.

Storage Information Store away from alkalis. Store away from oxidizers. Keep from heat, sparks, and

open flames. Keep container closed when not in use. Product has a shelf life of 24

months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Organic vapor/acid gas respirator with a dust/mist filter.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

AS-5 ANTI-SLUDGING AGENT

Page 2 of 6

HESI100096
9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Dark brown

Odor: Alcohol

pH: 1

Specific Gravity @ 20 C (Water=1): 1.03

Density @ 20 C (lbs./gallon): 8.58

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): 36

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers. Strong alkalis.

Hazardous Decomposition

Products

Oxides of sulfur. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation Causes severe respiratory irritation. May cause central nervous system depression

including headache, dizziness, drowsiness, incoordination, slowed reaction time,

slurred speech, giddiness and unconsciousness.

Skin Contact Causes severe burns. May cause an allergic skin reaction. May be absorbed through

the skin and produce effects similar to those caused by inhalation and/or ingestion.

Eye Contact May cause eye burns.

Ingestion Causes burns of the mouth, throat and stomach. May cause central nervous system

depression including headache, dizziness, drowsiness, muscular weakness,

incoordination, slowed reaction time, fatigue blurred vision, slurred speech,

giddiness, tremors and convulsions.

Aggravated Medical Conditions Skin disorders. Eye ailments.

AS-5 ANTI-SLUDGING AGENT

Page 3 of 6

HESI100097
Chronic Effects/Carcinogenicity Repeated overexposure may cause liver and kidney effects.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Resistant

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Flammable Liquid, Corrosive, N.O.S., 3, (8), UN2924, III, (35 C)

(Contains Isopropanol, Dodecylbenzenesulfonic Acid)

NAERG 132

Canadian TDG

Flammable Liquid, Corrosive, N.O.S.(Contains Isopropanol, Dodecylbenzenesulfonic Acid), 3, (8), UN2924, III, (35 C)

AS-5 ANTI-SLUDGING AGENT

Page 4 of 6

HESI100098
ADR

UN2924,Flammable Liquid, Corrosive, N.O.S.(Contains Isopropanol, Dodecylbenzenesulfonic Acid), 3, (8), III

Air Transportation

ICAO/IATA

UN2924,Flammable Liquid, Corrosive, N.O.S., 3, (8), III

(Contains Isopropanol, Dodecylbenzenesulfonic Acid Solution)

Sea Transportation

IMDG

UN2924,Flammable Liquid, Corrosive, N.O.S.(Contains Isopropanol, Dodecylbenzenesulfonic Acid), 3, (8), III, (35 C)

EmS F-E, S-C

Other Shipping Information

Labels: Flammable Liquid

Corrosive

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Isopropanol//67-63-0

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 155 Gallons based on Dodecylbenzene sulfonic

acid (CAS: 27176-87-0).

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Ignitability D001

 Corrosivity D002

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

AS-5 ANTI-SLUDGING AGENT

Page 5 of 6

HESI100099
WHMIS Hazard Class B2 Flammable Liquids

E Corrosive Material

D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

AS-5 ANTI-SLUDGING AGENT

Page 6 of 6

HESI100100
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: AS-7 ANTI-SLUDGING AGENT

Revision Date: 26-Nov-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: AS-7 ANTI-SLUDGING AGENT

Synonyms: None

Chemical Family: Blend

Application: Anti-sludging Agent

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Alkyl sulfonate salt 12068-08-5 30 - 60% Not applicable Not applicable

Alkyl sulfonate salt 30 - 60% Not applicable Not applicable

Morpholine 110-91-8 1 - 5% 20 ppm 20 ppm

Methanol 67-56-1 5 - 10% 200 ppm 200 ppm (S)

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory burns. May cause headache, dizziness, and

other central nervous system effects. May be fatal if swallowed. May cause

blindness. May be absorbed through the skin. Repeated overexposure may cause

liver and kidney effects. Flammable.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

AS-7 ANTI-SLUDGING AGENT

Page 1 of 6

HESI100101
Notes to Physician Not Applicable

5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 90

Flash Point/Range (C): 32

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): 6.7

Flammability Limits in Air - Upper (%): 36

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards May be ignited by heat, sparks or flames. Use water spray to cool fire exposed

surfaces. Closed containers may explode in fire. Decomposition in fire may produce

toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 3, Flammability 3, Reactivity 0

HMIS Ratings: Health 0, Flammability 3, Reactivity 3

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Wear self-contained breathing apparatus in

enclosed areas.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Remove ignition sources and work with nonsparking tools. Contain spill with sand or other inert materials. Scoop up and

remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse. Ground and bond containers

when transferring from one container to another.

Storage Information Store away from oxidizers. Store in a cool well ventilated area. Keep container

closed when not in use.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Positive pressure self-contained breathing apparatus if methanol is released.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

AS-7 ANTI-SLUDGING AGENT

Page 2 of 6

HESI100102
9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Clear amber

Odor: Strong

pH: 7.1

Specific Gravity @ 20 C (Water=1): 1.04

Density @ 20 C (lbs./gallon): 8.66

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): 190

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Disperses

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: 0.61

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Oxides of nitrogen. Oxides of sulfur. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation Causes severe respiratory irritation. May cause central nervous system depression

including headache, dizziness, drowsiness, incoordination, slowed reaction time,

slurred speech, giddiness and unconsciousness.

Skin Contact May cause skin burns. May be absorbed through the skin and contribute to the

symptoms listed under ingestion.

Eye Contact Causes severe eye irritation May cause eye burns.

Ingestion Causes burns of the mouth, throat and stomach. May be fatal or cause blindness if

swallowed. May cause central nervous system depression including headache,

dizziness, drowsiness, muscular weakness, incoordination, slowed reaction time,

fatigue blurred vision, slurred speech, giddiness, tremors and convulsions.

AS-7 ANTI-SLUDGING AGENT

Page 3 of 6

HESI100103
Aggravated Medical Conditions Skin disorders. Eye ailments.

Chronic Effects/Carcinogenicity Prolonged or repeated exposure may cause eye, blood, lung, liver, kidney, heart,

central nervous system and spleen damage. May contain ethylene oxide in the

headspace of the drum. Ethylene oxide is a cancer and reproductive hazard.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:TLM96: 10-33 ppm (Crangon crangon)

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Flammable Liquid, Corrosive, N.O.S., 3, (8), UN2924, III, (32.2 C)

(Contains Methanol, Amine Salt)

NAERG 132

AS-7 ANTI-SLUDGING AGENT

Page 4 of 6

HESI100104
Canadian TDG

Flammable Liquid, Corrosive, N.O.S.(Contains Methanol, Amine Salt), 3, (8), UN2924, III, (32.2 C)

ADR

UN2924,Flammable Liquid, Corrosive, N.O.S.(Contains Methanol, Amine Salt), 3, (8), III

Air Transportation

ICAO/IATA

UN2924,Flammable Liquid, Corrosive, N.O.S., 3, (8), III

(Contains Methanol, Amine Salt)

Sea Transportation

IMDG

UN2924,Flammable Liquid, Corrosive, N.O.S.(Contains Methanol, Amine Salt), 3, (8), III, (32.2 C)

EmS F-E, S-C

Other Shipping Information

Labels: Flammable Liquid

Corrosive

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Methanol//67-56-1

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 8325 Gallons based on Methanol (CAS: 67-56-1).

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Ignitability D001

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

AS-7 ANTI-SLUDGING AGENT

Page 5 of 6

HESI100105
Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class B2 Flammable Liquids

E Corrosive Material

D1A Very Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

AS-7 ANTI-SLUDGING AGENT

Page 6 of 6

HESI100106
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: AS-9 ANTI-SLUDGING AGENT

Revision Date: 03-Jan-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: AS-9 ANTI-SLUDGING AGENT

Synonyms: None

Chemical Family: Blend

Application: Anti-sludging Agent

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Dipropylene glycol 25265-71-8 10 - 30% Not applicable Not applicable

Alkylbenzenesulfonic acid 30 - 60% Not applicable Not applicable

Morpholine 110-91-8 10 - 30% 20 ppm 20 ppm

1-Methoxy-2-propanol 107-98-2 10 - 30% 100 ppm Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye and skin burns. May cause respiratory irritation. May cause

headache, dizziness, and other central nervous system effects. May be harmful if

swallowed. May be absorbed through the skin. May cause allergic skin reaction.

Repeated overexposure may cause liver and kidney effects. Combustible.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

AS-9 ANTI-SLUDGING AGENT

Page 1 of 6

HESI100107
Notes to Physician Not Applicable

5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 138

Flash Point/Range (C): 58

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Use water spray to cool fire exposed surfaces. Closed containers may explode in

fire. Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 2, Reactivity 0

HMIS Ratings: Flammability 2, Reactivity 0, Health 2

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Neutralize to pH of 6-8. Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse.

Storage Information Store away from alkalis. Store away from oxidizers. Keep container closed when not

in use. Product has a shelf life of 24 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Organic vapor/acid gas respirator with a dust/mist filter.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

AS-9 ANTI-SLUDGING AGENT

Page 2 of 6

HESI100108
9. PHYSICAL AND CHEMICAL PROPERTIES

Color: Dark brown

Odor: Amine

pH: 0.78

Specific Gravity @ 20 C (Water=1): 1.07

Density @ 20 C (lbs./gallon): 8.91

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong alkalis. Strong oxidizers.

Hazardous Decomposition

Products

Oxides of sulfur. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation Causes severe respiratory irritation. May cause central nervous system depression

including headache, dizziness, drowsiness, incoordination, slowed reaction time,

slurred speech, giddiness and unconsciousness.

Skin Contact Causes severe burns. May be absorbed through the skin and produce effects similar

to those caused by inhalation and/or ingestion. May cause an allergic skin reaction.

Eye Contact May cause eye burns.

Ingestion Causes burns of the mouth, throat and stomach.

Aggravated Medical Conditions Skin disorders. Eye ailments.

Chronic Effects/Carcinogenicity Prolonged or repeated exposure may cause liver, kidney and lung effects.

Other Information None known.

Toxicity Tests

AS-9 ANTI-SLUDGING AGENT

Page 3 of 6

HESI100109
Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Flammable Liquid, Corrosive, N.O.S., 3, (8), UN2924, III, (58.9 C)

(Contains Propylene Glycol Monomethyl Ether, Dodecylbenzenesulfonic Acid)

NAERG 132

Canadian TDG

Flammable Liquid, Corrosive, N.O.S.(Contains Propylene Glycol Monomethyl Ether, Dodecylbenzenesulfonic Acid), 3,

(8), UN2924, III, (58.9 C)

ADR

UN2924,Flammable Liquid, Corrosive, N.O.S.(Contains Propylene Glycol Monomethyl Ether, Dodecylbenzenesulfonic

Acid), 3, (8), III

Air Transportation

AS-9 ANTI-SLUDGING AGENT

Page 4 of 6

HESI100110
ICAO/IATA

UN2924,Flammable Liquid, Corrosive, N.O.S., 3, (8), III

(Contains Propylene Glycol Monomethyl Ether, Dodecylbenzenesulfonic Acid Solution)

Sea Transportation

IMDG

UN2924,Flammable Liquid, Corrosive, N.O.S.(Contains Propylene Glycol Monomethyl Ether, Dodecylbenzenesulfonic

Acid), 3, (8), III, (58.9 C)

EmS F-E, S-C

Other Shipping Information

Labels: Flammable Liquid

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Glycol Ethers//107-98-2

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Ignitability D001

 Corrosivity D002

California Proposition 65 The California Proposition 65 regulations apply to this product.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class B2 Flammable Liquids

E Corrosive Material

D2B Toxic Materials

AS-9 ANTI-SLUDGING AGENT

Page 5 of 6

HESI100111
16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

AS-9 ANTI-SLUDGING AGENT

Page 6 of 6

HESI100112
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: BA-20 BUFFERING AGENT

Revision Date: 05-Jan-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: BA-20 BUFFERING AGENT

Synonyms: None

Chemical Family: Organic acid

Application: Buffer

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Ammonium acetate 631-61-8 60 - 100% Not applicable Not applicable

Acetic acid 64-19-7 10 - 30% 10 ppm 10 ppm

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye and skin burns. May cause respiratory irritation. May be harmful if

swallowed.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

BA-20 BUFFERING AGENT

Page 1 of 5

HESI100125
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not DeterminedMin: > 212

Flash Point/Range (C): Not DeterminedMin: > 100

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media All standard firefighting media.

Special Exposure Hazards Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 1, Reactivity 1

HMIS Ratings: Health 2, Flammability 1, Reactivity 1

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Neutralize to pH of 6-8. Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse.

Storage Information Store away from alkalis. Store in a cool well ventilated area. Keep container closed

when not in use.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Organic vapor/acid gas respirator with a dust/mist filter.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Colorless

Odor: Slight vinegar

pH: 5.45

BA-20 BUFFERING AGENT

Page 2 of 5

HESI100126
9. PHYSICAL AND CHEMICAL PROPERTIES

Specific Gravity @ 20 C (Water=1): 1.102

Density @ 20 C (lbs./gallon): 9.18

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 215

Boiling Point/Range (C): 101

Freezing Point/Range (F): -24

Freezing Point/Range (C): -31

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Miscible

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong alkalis.

Hazardous Decomposition

Products

Ammonia. Oxides of nitrogen. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation.

Skin Contact Causes severe burns. May cause an allergic skin reaction.

Eye Contact May cause severe eye irritation. May cause eye burns.

Ingestion Causes burns of the mouth, throat and stomach.

Aggravated Medical Conditions Skin disorders.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

BA-20 BUFFERING AGENT

Page 3 of 5

HESI100127
Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Readily biodegradable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT Not restricted

Canadian TDG

Not restricted

ADR Not restricted

Air Transportation

ICAO/IATA Not restricted

Sea Transportation

IMDG Not restricted

Other Shipping Information

Labels: None

BA-20 BUFFERING AGENT

Page 4 of 5

HESI100128
15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 798 Gallons based on Ammonium acetate (CAS:

631-61-8). EPA Reportable Spill Quantity is 3810 Gallons based on Acetic acid

(CAS: 64-19-7).

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class E Corrosive Material

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

BA-20 BUFFERING AGENT

Page 5 of 5

HESI100129
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: BA-2 BUFFERING AGENT

Revision Date: 03-Jan-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: BA-2 BUFFERING AGENT

Synonyms: None

Chemical Family: Acid

Application: Buffer

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Sulfamic acid 5329-14-6 60 - 100% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye burns. May cause skin and respiratory irritation. May be harmful if

swallowed.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

BA-2 BUFFERING AGENT

Page 1 of 6

HESI100119
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases. Do not allow runoff to enter

waterways.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 0, Reactivity 0

HMIS Ratings: Flammability 0, Reactivity 0, Health 2

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid creating or inhaling dust. Wash

hands after use. Launder contaminated clothing before reuse.

Storage Information Store away from alkalis. Store in a cool, dry location.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Dust/mist respirator. (95%)

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid

Color: White

Odor: Odorless

pH: 1.18

Specific Gravity @ 20 C (Water=1): 2.125

BA-2 BUFFERING AGENT

Page 2 of 6

HESI100120
9. PHYSICAL AND CHEMICAL PROPERTIES

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): 68.5

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): 97.1

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong alkalis. Strong oxidizers. Chlorine. Sulfides. Nitrites. Nitrates. Carbonates of

alkalis.

Hazardous Decomposition

Products

Oxides of sulfur. Oxides of nitrogen. Ammonia. Carbon monoxide and carbon

dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation.

Skin Contact May cause skin irritation.

Eye Contact Causes severe eye burns. May cause permanent eye damage.

Ingestion May cause abdominal pain, vomiting, nausea, and diarrhea. Irritation of the mouth,

throat, and stomach.

Aggravated Medical Conditions Lung disorders.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: LD50: 3160 mg/kg (Rat)

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

BA-2 BUFFERING AGENT

Page 3 of 6

HESI100121
Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Readily biodegradable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging This bag may contain residue of a hazardous material. Some authorities may

regulate such containers as hazardous waste. Dispose of container according to

national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Sulfamic Acid, 8, UN2967, III

NAERG 154

Canadian TDG

Sulfamic Acid, 8, UN2967, III

ADR

UN2967,Sulfamic Acid, 8, III

Air Transportation

ICAO/IATA

UN2967,Sulfamic Acid, 8, III

Sea Transportation

BA-2 BUFFERING AGENT

Page 4 of 6

HESI100122
IMDG

UN2967,Sulfamic Acid, 8, III

EmS F-A, S-B

Other Shipping Information

Labels: Corrosive

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law Does not apply.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law Does not apply.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class E Corrosive Material

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

BA-2 BUFFERING AGENT

Page 5 of 6

HESI100123
Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

BA-2 BUFFERING AGENT

Page 6 of 6

HESI100124
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: BA-40L BUFFERING AGENT

Revision Date: 05-Jan-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: BA-40L BUFFERING AGENT

Synonyms: None

Chemical Family: Carbonate

Application: Buffer

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Potassium carbonate 584-08-7 30 - 60% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye and skin burns. May cause respiratory irritation. May be harmful if

swallowed.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

BA-40L BUFFERING AGENT

Page 1 of 6

HESI100130
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 0, Reactivity 1

HMIS Ratings: Health 2, Flammability 0, Reactivity 1

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse.

Storage Information Store away from acids. Store in a cool well ventilated area. Keep container closed

when not in use.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Dust/mist respirator. (95%)

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Clear colorless

Odor: Odorless

pH: 13 - 14

BA-40L BUFFERING AGENT

Page 2 of 6

HESI100131
9. PHYSICAL AND CHEMICAL PROPERTIES

Specific Gravity @ 20 C (Water=1): 1.496

Density @ 20 C (lbs./gallon): 12.46

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 266

Boiling Point/Range (C): 130

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong acids. Contact with acids and lime dust will cause the formation of potassium

hydroxide and sodium hydroxide.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation Causes severe respiratory burns. May cause chemical pneumonia.

Skin Contact Causes severe skin irritation. May cause skin burns. May cause an allergic skin

reaction.

Eye Contact Causes severe eye irritation May cause eye burns.

Ingestion Causes burns of the mouth, throat and stomach.

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

BA-40L BUFFERING AGENT

Page 3 of 6

HESI100132
Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

BA-40L BUFFERING AGENT

Page 4 of 6

HESI100133
Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law Does not apply.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law Does not apply.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class E Corrosive Material

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

BA-40L BUFFERING AGENT

Page 5 of 6

HESI100134
BA-40L BUFFERING AGENT

Page 6 of 6

HESI100135
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: BA-50 BUFFERING AGENT

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: BA-50 BUFFERING AGENT

Synonyms: None

Chemical Family: Acid

Application: Buffer

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Boric acid 10043-35-3 60 - 100% 2 mg/m3 Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. Potential reproductive hazard.

Contains a material which may cause embryo/fetotoxicity based on animal data.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

BA-50 BUFFERING AGENT

Page 1 of 5

HESI100136
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media All standard firefighting media.

Special Exposure Hazards Not applicable.

Special Protective Equipment for

Fire-Fighters

Not applicable.

NFPA Ratings: Health 0, Flammability 0, Reactivity 0

HMIS Ratings: Health 0, Flammability 0, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid creating or inhaling dust.

Storage Information Store in a cool, dry location.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Dust/mist respirator. (95%)

Hand Protection Normal work gloves.

Skin Protection Normal work coveralls.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions None known.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid

Color: White

Odor: Odorless

pH: 5.1

Specific Gravity @ 20 C (Water=1): 1.84

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): Not Determined

BA-50 BUFFERING AGENT

Page 2 of 5

HESI100137
9. PHYSICAL AND CHEMICAL PROPERTIES

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): 69.619

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong alkalis. Potassium. Anhydrides.

Hazardous Decomposition

Products

None known.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause mild respiratory irritation.

Skin Contact May cause skin irritation.

Eye Contact May cause eye irritation.

Ingestion May cause headache, dizziness, nausea, vomiting, gastrointestinal irritation and

central nervous system depression.

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity Prolonged or repeated exposure may cause reproductive system damage. Prolonged

or repeated exposure may cause embryo and fetus toxicity.

Other Information None known.

Toxicity Tests

Oral Toxicity: LD50: 3160 mg/kg (Rat)

Dermal Toxicity: LD50: > 2000 mg/kg (Rabbit)

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

BA-50 BUFFERING AGENT

Page 3 of 5

HESI100138
Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

Other Shipping Information

BA-50 BUFFERING AGENT

Page 4 of 5

HESI100139
Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law Does not apply.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law Does not apply.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class Un-Controlled

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

BA-50 BUFFERING AGENT

Page 5 of 5

HESI100140
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: BARSOL D-100

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: BARSOL D-100

Synonyms: None

Chemical Family: Aliphatic hydrocarbon

Application: Solvent

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Trimethyl benzenes 25551-13-7 10 - 30% 25 ppm 25 ppm

Cumene 98-82-8 5 - 10% 50 ppm 50 ppm

Light aromatic solvent 64742-95-6 60 - 100% Not applicable Not applicable

Xylene 1330-20-7 5 - 10% 100 ppm 100 ppm

Ethyl benzene 100-41-4 1 - 5% 100 ppm 100 ppm

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause headache, dizziness, and

other central nervous system effects. May be harmful if swallowed. Repeated

overexposure may cause liver and kidney effects. Potential carcinogen. Combustible.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Get medical attention! If vomiting occurs, keep head lower than hips to prevent

aspiration.

BARSOL D-100

Page 1 of 6

HESI100141
Notes to Physician Not Applicable

5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 106

Flash Point/Range (C): 41

Flash Point Method: PMCC

Autoignition Temperature (F): 880

Autoignition Temperature (C): 471

Flammability Limits in Air - Lower (%): 0.9

Flammability Limits in Air - Upper (%): 7

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Use water spray to cool fire exposed surfaces. Closed containers may explode in

fire. Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 2, Reactivity 0

HMIS Ratings: Health 1, Flammability 2, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Wear self-contained breathing apparatus in

enclosed areas.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Remove ignition sources and work with nonsparking tools. Contain spill with sand or other inert materials. Scoop up and

remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse.

Storage Information Store away from oxidizers. Keep from heat, sparks, and open flames. Keep container

closed when not in use.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Organic vapor respirator.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

BARSOL D-100

Page 2 of 6

HESI100142
9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Clear to water white

Odor: Aromatic hydrocarbon

pH: 7

Specific Gravity @ 20 C (Water=1): 0.87

Density @ 20 C (lbs./gallon): 7.25

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 306

Boiling Point/Range (C): 152

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): 10

Vapor Density (Air=1): Not Determined

Percent Volatiles: 100

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Insoluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): 120

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Aldehydes. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. May cause central nervous system depression

including headache, dizziness, drowsiness, incoordination, slowed reaction time,

slurred speech, giddiness and unconsciousness.

Skin Contact May cause skin defatting with prolonged exposure. May cause skin irritation.

Eye Contact May cause eye irritation.

Ingestion Aspiration into the lungs may cause chemical pneumonitis including coughing,

difficulty breathing, wheezing, coughing up blood and pneumonia, which can be fatal.

Aggravated Medical Conditions Skin disorders. Eye ailments.

Chronic Effects/Carcinogenicity Repeated overexposure may cause liver and kidney effects. Contains petroleum

distillates which have been shown to cause skin cancer in laboratory animals.

BARSOL D-100

Page 3 of 6

HESI100143
Other Information None known.

Toxicity Tests

Oral Toxicity: LD50: > 5000 mg/kg (Rat)

Dermal Toxicity: LD50: > 3160 mg/kg (Rabbit)

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

UN1268,Petroleum Distillates, N.O.S., 3, III, (41.1 C)

NAERG 128

Canadian TDG

Petroleum Distillates, N.O.S., 3, UN1268, III, (41.1 C)

ADR

BARSOL D-100

Page 4 of 6

HESI100144
UN1268,Petroleum Distillates, N.O.S., 3, III

Air Transportation

ICAO/IATA

UN1268,Petroleum Distillates, N.O.S., 3, III

Sea Transportation

IMDG

UN1268,Petroleum Distillates, N.O.S., 3, III, (41.1 C)

EmS F-E, S-E

Other Shipping Information

Labels: Flammable Liquid

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Ethyl Benzene//100-41-4

Xylene//1330-20-7

Cumene//98-82-8

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 275 Gallons based on Xylene (CAS: 1330-20-7).

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Ignitability D001

California Proposition 65 The California Proposition 65 regulations apply to this product.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

BARSOL D-100

Page 5 of 6

HESI100145
WHMIS Hazard Class B2 Flammable Liquids

D1B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

BARSOL D-100

Page 6 of 6

HESI100146
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: BC-140

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: BC-140

Synonyms: None

Chemical Family: Blend

Application: Crosslinker

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Ethylene glycol 107-21-1 10 - 30% 100 mg/m3 50 ppm

Monoethanolamine 141-43-5 10 - 30% 3 ppm 3 ppm

Boric acid 10043-35-3 10 - 30% 2 mg/m3 Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause headache, dizziness, and

other central nervous system effects. May be harmful if swallowed. May cause birth

defects. Repeated overexposure may cause liver and kidney effects.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

BC-140

Page 1 of 6

HESI100147
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 0, Reactivity 0

HMIS Ratings: Health 2, Flammability 0, Physical Hazard 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse.

Storage Information Store away from oxidizers. Store in a cool well ventilated area. Keep container

closed when not in use. Product has a shelf life of 36 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Organic vapor respirator.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Dark green

Odor: Mild

BC-140

Page 2 of 6

HESI100148
9. PHYSICAL AND CHEMICAL PROPERTIES

pH: 7.28

Specific Gravity @ 20 C (Water=1): 1.17 - 1.2

Density @ 20 C (lbs./gallon): 9.75 - 10.0

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers. Dehydrating agents.

Hazardous Decomposition

Products

Toxic fumes. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. May cause central nervous system depression

including headache, dizziness, drowsiness, incoordination, slowed reaction time,

slurred speech, giddiness and unconsciousness.

Skin Contact May cause skin irritation.

Eye Contact May cause severe eye irritation.

Ingestion Irritation of the mouth, throat, and stomach. May cause abdominal pain, vomiting,

nausea, and diarrhea. May cause heart, kidney and brain disorders.

Aggravated Medical Conditions Skin disorders. Eye ailments. Liver and kidney disorders.

Chronic Effects/Carcinogenicity Prolonged or repeated exposure may cause kidney damage. Prolonged or repeated

exposure may cause liver, heart, blood and brain damage. Prolonged or repeated

exposure may cause reproductive system damage. Prolonged or repeated exposure

may cause embryo and fetus toxicity.

Other Information None known.

BC-140

Page 3 of 6

HESI100149
Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

BC-140

Page 4 of 6

HESI100150
ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Ethylene Glycol//107-21-1

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 1674 Gallons based on Ethylene glycol (CAS: 107-

21-1).

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class D1A Very Toxic Materials

D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

BC-140

Page 5 of 6

HESI100151
Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

BC-140

Page 6 of 6

HESI100152
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: BC-140 X2

Revision Date: 05-Jan-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: BC-140 X2

Synonyms: None

Chemical Family: Blend

Application: Initiator

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Monoethanolamine 141-43-5 10 - 30% 3 ppm 3 ppm

Boric acid 10043-35-3 30 - 60% 2 mg/m3 Not applicable

Ethylene glycol 107-21-1 10 - 30% 100 mg/m3 50 ppm

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause headache, dizziness, and

other central nervous system effects. May be harmful if swallowed. May cause birth

defects.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

BC-140 X2

Page 1 of 6

HESI100153
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 0, Reactivity 0

HMIS Ratings: Health 1, Flammability 0, Physical Hazard 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors.

Storage Information Store away from oxidizers. Store in a cool well ventilated area. Keep container

closed when not in use. Product has a shelf life of 36 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection If engineering controls and work practices cannot keep exposure below occupational

exposure limits or if exposure is unknown, wear a NIOSH certified, European

Standard EN 149, or equivalent respirator when using this product. Selection of and

instruction on using all personal protective equipment, including respirators, should

be performed by an Industrial Hygienist or other qualified professional.

Organic vapor respirator.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

BC-140 X2

Page 2 of 6

HESI100154
9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Dark

Odor: Strong offensive

pH: 7.28

Specific Gravity @ 20 C (Water=1): 1.22

Density @ 20 C (lbs./gallon): 10.16

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Not Determined

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers. Dehydrating agents.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide. Toxic fumes.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause central nervous system depression including headache, dizziness,

drowsiness, incoordination, slowed reaction time, slurred speech, giddiness and

unconsciousness.

Skin Contact May cause skin irritation.

Eye Contact May cause severe eye irritation.

Ingestion May cause abdominal pain, vomiting, nausea, and diarrhea. May cause heart, kidney

and brain disorders.

Aggravated Medical Conditions Skin disorders. Eye ailments. Liver disorders.

BC-140 X2

Page 3 of 6

HESI100155
Chronic Effects/Carcinogenicity Prolonged or repeated exposure may cause kidney damage. Prolonged or repeated

exposure may cause reproductive system damage. Prolonged or repeated exposure

may cause liver, heart, blood and brain damage. Prolonged or repeated exposure

may cause embryo and fetus toxicity.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT Not restricted

Canadian TDG

Not restricted

BC-140 X2

Page 4 of 6

HESI100156
ADR Not restricted

Air Transportation

ICAO/IATA Not restricted

Sea Transportation

IMDG Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Ethylene Glycol//107-21-1

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 1674 Gallons based on Ethylene glycol (CAS: 107-

21-1).

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class D2A Very Toxic Materials

E Corrosive Material

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

BC-140 X2

Page 5 of 6

HESI100157
Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

BC-140 X2

Page 6 of 6

HESI100158
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: BC-200

Revision Date: 05-Jan-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: BC-200

Synonyms: None

Chemical Family: Blend

Application: Crosslinker

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Diesel 68476-34-6 30 - 60% 100 mg/m3 Not applicable

Borate salts 30 - 60% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause headache, dizziness, and

other central nervous system effects. May be harmful if swallowed. Potential

carcinogen. Combustible.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Get medical attention! If vomiting occurs, keep head lower than hips to prevent

aspiration.

Notes to Physician Not Applicable

BC-200

Page 1 of 6

HESI100159
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 148

Flash Point/Range (C): 64

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Use water spray to cool fire exposed surfaces. Closed containers may explode in

fire. Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 2, Reactivity 0

HMIS Ratings: Health 2, Flammability 2, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Wear self-contained breathing apparatus in

enclosed areas.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Remove ignition sources and work with nonsparking tools. Contain spill with sand or other inert materials. Scoop up and

remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse.

Storage Information Store away from oxidizers. Keep from heat, sparks, and open flames. Keep container

closed when not in use. Product has a shelf life of 6 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Organic vapor respirator with a dust/mist filter.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

BC-200

Page 2 of 6

HESI100160
9. PHYSICAL AND CHEMICAL PROPERTIES

Color: Tan

Odor: Diesel

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 1.20

Density @ 20 C (lbs./gallon): 10.00

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): 1

Percent Volatiles: 48

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Insoluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. May cause central nervous system depression

including headache, dizziness, drowsiness, incoordination, slowed reaction time,

slurred speech, giddiness and unconsciousness.

Skin Contact May cause skin irritation. May be absorbed through the skin and produce effects

similar to those caused by inhalation and/or ingestion.

Eye Contact May cause eye irritation.

Ingestion Aspiration into the lungs may cause chemical pneumonitis including coughing,

difficulty breathing, wheezing, coughing up blood and pneumonia, which can be fatal.

May cause central nervous system depression including headache, dizziness,

drowsiness, muscular weakness, incoordination, slowed reaction time, fatigue

blurred vision, slurred speech, giddiness, tremors and convulsions.

Aggravated Medical Conditions Skin disorders.

BC-200

Page 3 of 6

HESI100161
Chronic Effects/Carcinogenicity Contains petroleum distillates which have been shown to cause skin cancer in

laboratory animals.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

DOT (Bulk)

Diesel Fuel Solution, Combustible Liquid, NA1993, III

Canadian TDG

Not restricted

BC-200

Page 4 of 6

HESI100162
ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 The California Proposition 65 regulations apply to this product.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class B3 Combustible Liquids

D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

BC-200

Page 5 of 6

HESI100163
Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

BC-200

Page 6 of 6

HESI100164
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: BC-200 UC

Revision Date: 05-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: BC-200 UC

Synonyms: None

Chemical Family: Blend

Application: Crosslinker

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Hydrotreated light petroleum

distillate

10 - 30% 200 mg/m3 Not applicable

Crystalline silica, quartz 14808-60-7 1 - 5% 0.025 mg/m3 10 mg/m3

%SiO2 + 2

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May be harmful if swallowed.

Breathing crystalline silica can cause lung disease, including silicosis and lung

cancer. Crystalline silica has also been associated with scleroderma and kidney

disease.

This product contains quartz, cristobalite, and/or tridymite which may become

airborne without a visible cloud. Avoid breathing dust. Avoid creating dusty

conditions. Use only with adequate ventilation to keep exposures below

recommended exposure limits. Wear a NIOSH certified, European Standard EN

149, or equivalent respirator when using this product. Review the Material Safety

Data Sheet (MSDS) for this product, which has been provided to your employer.

Combustible.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

BC-200 UC

Page 1 of 7

HESI100165
Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes Immediately flush eyes with large amounts of water for at least 15 minutes. Get

immediate medical attention.

Ingestion Get medical attention! If vomiting occurs, keep head lower than hips to prevent

aspiration.

Notes to Physician Not Applicable

5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 182

Flash Point/Range (C): 83

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Carbon Dioxide, Dry Chemicals, Foam.

Special Exposure Hazards Use water spray to cool fire exposed surfaces. Closed containers may explode in

fire. Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 2, Reactivity 0

HMIS Ratings: Health 2, Flammability 2, Physical Hazard 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Remove ignition sources and work with non-sparking tools. Isolate spill and stop

leak where safe. Contain spill with sand or other inert materials. Scoop up and

remove.

7. HANDLING AND STORAGE

Handling Precautions Wash hands after use. Launder contaminated clothing before reuse. Avoid contact

with eyes, skin, or clothing. Avoid breathing mist. This product contains quartz,

cristobalite, and/or tridymite which may become airborne without a visible cloud if this

product becomes dry. Avoid breathing or creating dust. Use only with adequate

ventilation to keep exposures below recommended exposure limits. Wear a NIOSH

certified, European Standard EN 149, or equivalent respirator when using dried

product.

Storage Information Store away from oxidizers. Store in a cool well ventilated area. Keep from heat,

sparks, and open flames. Keep container closed when not in use.

BC-200 UC

Page 2 of 7

HESI100166
8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use approved industrial ventilation and local exhaust as required to maintain

exposures below applicable exposure limits listed in Section 2.

Respiratory Protection If engineering controls and work practices cannot keep exposure below occupational

exposure limits or if exposure is unknown, wear a NIOSH certified, European

Standard EN 149, or equivalent respirator when using this product. Selection of and

instruction on using all personal protective equipment, including respirators, should

be performed by an Industrial Hygienist or other qualified professional.

Not normally needed. But if significant exposures are possible then the following

respirator is recommended:

Organic vapor respirator with a dust/mist filter.

Hand Protection Impervious rubber gloves.

Skin Protection Normal work coveralls.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Red

Odor: Odorless

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 1.21

Density @ 20 C (lbs./gallon): 10.1

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): -27

Freezing Point/Range (C): -33

Vapor Pressure @ 20 C (mmHg): 0.1

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Insoluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide. Amorphous silica may transform at elevated

temperatures to tridymite (870 C) or cristobalite (1470 C).

BC-200 UC

Page 3 of 7

HESI100167
Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. If heated: May cause central nervous system

depression including headache, dizziness, drowsiness, incoordination, slowed

reaction time, slurred speech, giddiness and unconsciousness.

Inhaled crystalline silica in the form of quartz or cristobalite from occupational

sources is carcinogenic to humans (IARC, Group 1). There is sufficient evidence in

experimental animals for the carcinogenicity of tridymite (IARC, Group 2A).

Breathing silica dust may cause irritation of the nose, throat, and respiratory

passages. Breathing silica dust may not cause noticeable injury or illness even

though permanent lung damage may be occurring. Inhalation of dust may also have

serious chronic health effects (See "Chronic Effects/Carcinogenicity" subsection

below).

Skin Contact Causes drying of the skin. May cause skin irritation.

Eye Contact May cause moderate to severe eye irritation.

Ingestion Irritation of the mouth, throat, and stomach. Aspiration into the lungs may cause

chemical pneumonitis including coughing, difficulty breathing, wheezing, coughing up

blood and pneumonia, which can be fatal.

Aggravated Medical Conditions Skin disorders. Individuals with respiratory disease, including but not limited to

asthma and bronchitis, or subject to eye irritation, should not be exposed to quartz

dust.

Chronic Effects/Carcinogenicity Silicosis: Excessive inhalation of respirable crystalline silica dust may cause a

progressive, disabling, and sometimes-fatal lung disease called silicosis. Symptoms

include cough, shortness of breath, wheezing, non-specific chest illness, and

reduced pulmonary function. This disease is exacerbated by smoking. Individuals

with silicosis are predisposed to develop tuberculosis.

Cancer Status: The International Agency for Research on Cancer (IARC) has

determined that crystalline silica inhaled in the form of quartz or cristobalite from

occupational sources can cause lung cancer in humans (Group 1 - carcinogenic to

humans) and has determined that there is sufficient evidence in experimental

animals for the carcinogenicity of tridymite (Group 2A - possible carcinogen to

humans). Refer to IARC Monograph 68, Silica, Some Silicates and Organic Fibres

(June 1997) in conjunction with the use of these minerals. The National Toxicology

Program classifies respirable crystalline silica as "Known to be a human carcinogen".

Refer to the 9th Report on Carcinogens (2000). The American Conference of

Governmental Industrial Hygienists (ACGIH) classifies crystalline silica, quartz, as a

suspected human carcinogen (A2).

There is some evidence that breathing respirable crystalline silica or the disease

silicosis is associated with an increased incidence of significant disease endpoints

such as scleroderma (an immune system disorder manifested by scarring of the

lungs, skin, and other internal organs) and kidney disease.

Contains petroleum distillates which have been shown to cause skin cancer in

laboratory animals.

BC-200 UC

Page 4 of 7

HESI100168
Other Information For further information consult "Adverse Effects of Crystalline Silica Exposure"

published by the American Thoracic Society Medical Section of the American Lung

Association, American Journal of Respiratory and Critical Care Medicine, Volume

155, pages 761-768 (1997).

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Refer to IARC Monograph 68, Silica, Some Silicates and Organic Fibres (June

1997).

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

DOT (Bulk)

Combustible Liquid, N.O.S., Combustible Liquid, NA1993, III

(Contains Petroleum Distillates)

BC-200 UC

Page 5 of 7

HESI100169
Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 The California Proposition 65 regulations apply to this product.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class B3 Combustible Liquids

D2A Very Toxic Materials

Crystalline silica

BC-200 UC

Page 6 of 7

HESI100170
16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

BC-200 UC

Page 7 of 7

HESI100171
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: BC-200G

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: BC-200G

Synonyms: None

Chemical Family: Not applicable

Application: Crosslinker

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Dipropylene glycol

monomethyl ether

34590-94-8 30 - 60% 100 ppm (S) 100 ppm (S)

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause headache, dizziness, and

other central nervous system effects. May be harmful if swallowed. Combustible.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Get medical attention! If vomiting occurs, keep head lower than hips to prevent

aspiration.

Notes to Physician Aspiration may cause severe lung damage. Evacuate stomach in a way which

avoids aspiration.

BC-200G

Page 1 of 6

HESI100172
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 185Min: > 150

Flash Point/Range (C): Not DeterminedMin: > 65

Flash Point Method: TCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): 1.1

Flammability Limits in Air - Upper (%): 3

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Use water spray to cool fire exposed surfaces. Closed containers may explode in

fire. Decomposition in fire may produce toxic gases. Vapors are heavier than air and

may accumulate in low areas. Vapors may travel along the ground to be ignited at

distant locations.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 2, Reactivity 0

HMIS Ratings: Health 1, Flammability 2, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Evacuate all persons from the area. Use only

competent persons for cleanup.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse.

Storage Information Store away from oxidizers. Store in a cool well ventilated area. Product has a shelf

life of 6 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Organic vapor respirator.

In high concentrations, supplied air respirator or a self-contained breathing

apparatus.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

BC-200G

Page 2 of 6

HESI100173
9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Light gray

Odor: Ether

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 1.300

Density @ 20 C (lbs./gallon): 10.83

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not DeterminedMin: > 400

Boiling Point/Range (C): Not DeterminedMin: > 204

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): 0.52

Vapor Density (Air=1): 5.1

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Disperses

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Oxides of nitrogen. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. May cause central nervous system depression

including headache, dizziness, drowsiness, incoordination, slowed reaction time,

slurred speech, giddiness and unconsciousness.

Skin Contact May cause skin irritation.

Eye Contact May cause eye irritation.

Ingestion Aspiration into the lungs may cause chemical pneumonitis including coughing,

difficulty breathing, wheezing, coughing up blood and pneumonia, which can be fatal.

Aggravated Medical Conditions Skin disorders.

Chronic Effects/Carcinogenicity May cause testicular toxicity.

BC-200G

Page 3 of 6

HESI100174
Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

DOT (Bulk)

Combustible Liquid, N.O.S., Combustible Liquid, NA1993, III

(Contains Dipropylene Glycol Monomethyl Ether)

Canadian TDG

Not restricted

BC-200G

Page 4 of 6

HESI100175
ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Glycol Ethers//34590-94-8

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class B3 Combustible Liquids

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

BC-200G

Page 5 of 6

HESI100176
Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

BC-200G

Page 6 of 6

HESI100177
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: BE-3S BACTERICIDE

Revision Date: 23-Jan-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: BE-3S BACTERICIDE

Synonyms: None

Chemical Family: Blend

Application: Biocide

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

2-Monobromo-3-

nitrilopropionamide

1113-55-9 1 - 5% Not applicable Not applicable

2,2 Dibromo-3-

nitrilopropionamide

10222-01-2 60 - 100% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye burns. May cause skin and respiratory irritation. May be fatal if

swallowed. May cause allergic skin reaction.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Get medical attention if irritation persists. Remove

contaminated clothing and launder before reuse.

Eyes Immediately flush eyes with large amounts of water for at least 20 minutes. Seek

prompt medical attention.

Ingestion If swallowed, call a physician immediately. Only induce vomiting at the instruction of

a physician. Never give anything by mouth to an unconscious person. Rinse mouth

with water many times. Get immediate medical attention.

Notes to Physician Not Applicable

BE-3S BACTERICIDE

Page 1 of 6

HESI100178
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): > 212

Flash Point/Range (C): > 100

Flash Point Method: CC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Carbon Dioxide, Dry Chemicals, Foam. Use water spray to cool fire exposed

surfaces.

Special Exposure Hazards Decomposition in fire may produce toxic gases. Organic dust in the presence of an

ignition source can be explosive in high concentrations. Good housekeeping

practices are required to minimize this potential.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 3, Flammability 0, Reactivity 0

HMIS Ratings: Health 3, Flammability 0, Physical Hazard 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid creating or inhaling dust. Wear

appropriate respirator when opening containers. Wash hands after use. Launder

contaminated clothing before reuse.

Storage Information Keep container closed when not in use. Store in a cool, dry location. Store in a well

ventilated area. Store away from oxidizers. Store away from reducing agents. Store

away from direct sunlight.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Organic vapor respirator with a dust/mist filter.

Hand Protection Impervious rubber gloves. Polyvinylchloride gloves. Nitrile gloves. Neoprene gloves.

Skin Protection Rubber apron. Long-sleeve shirt, long pants, and shoes plus socks.

Eye Protection Dust proof goggles.

Other Precautions Eyewash fountains and safety showers must be easily accessible. Rubber boots

BE-3S BACTERICIDE

Page 2 of 6

HESI100179
9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Powder

Color: White to yellow

Odor: Slight Pungent

pH: 4.7-4.9

Specific Gravity @ 20 C (Water=1): 2.204-2.216

Density @ 20 C (lbs./gallon): 19.73-19.83

Bulk Density @ 20 C (lbs/ft3): 10.5

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): .934

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Partially soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers. Reducing agents.

Hazardous Decomposition

Products

Oxides of nitrogen. Bromine. Hydrogen bromide. Methyl and ethyl bromide.

Cyanogen bromide. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation Causes severe respiratory irritation. May be harmful if inhaled.

Skin Contact Causes severe skin irritation. This product contains ingredients which may produce

an allergic skin reaction. It should be treated as a skin sensitizer.

Eye Contact Causes severe eye irritation May cause eye burns. May cause permanent eye

damage.

Ingestion May be fatal if swallowed.

Aggravated Medical Conditions Skin disorders. Respiratory disorders. Eye ailments.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

BE-3S BACTERICIDE

Page 3 of 6

HESI100180
Other Information None known.

Toxicity Tests

Oral Toxicity: LD50: 235 mg/kg, 178 mg/kg (rat) LD50: 201 mg/kg (rat)

Dermal Toxicity: LD50: > 2000 mg/kg (Rabbit)

Inhalation Toxicity: LC50: 0.32 mg/l/4 hr. (Rat)

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Resistant

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: May be toxic to aquatic life. TLM96: 2.3 mg/l (Oncorhynchus mykiss) TLM96: 3.4

mg/l (Cyprinodon variegatus) TLM96: 2.3 mg/l (Lepomis macrochirus)

Acute Crustaceans Toxicity:TLM: 0.72 ppm (Mysidopsis bahia) LC50: 0.37 ppm (Crassostrea virginica)

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Toxic Solid, Organic, N.O.S., 6.1, UN2811, II

(2, 2-Dibromo-3-Nitrilopropionamide), Marine Pollutant

NAERG 154

Canadian TDG

Toxic Solid, Organic, N.O.S.(2, 2-Dibromo-3-Nitrilopropionamide), 6.1, UN2811, II, Marine Pollutant

ADR

BE-3S BACTERICIDE

Page 4 of 6

HESI100181
UN2811,Toxic Solid, Organic, N.O.S.(2, 2-Dibromo-3-Nitrilopropionamide), 6.1, II, Marine Pollutant

Air Transportation

ICAO/IATA

UN2811,Toxic Solid, Organic, N.O.S., 6.1, II

(2, 2-Dibromo-3-Nitrilopropionamide) , Marine Pollutant

Sea Transportation

IMDG

UN2811,Toxic Solid, Organic, N.O.S.(2, 2-Dibromo-3-Nitrilopropionamide), II

, Marine Pollutant

EmS F-A, S-A

Other Shipping Information

Labels: Toxic

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory Product contains one or more components not listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals 2,2-Dibromo-3-nitrilopropionamide//10222-01-2

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

Federal Insecticide, Fungicide

and Rodenticide Act:

Label in accordance with Federal Insecticide, Fungicide, and Rodenticide Act

(FIFRA) requirements.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law Does not apply.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law Does not apply.

Canadian Regulations

Canadian DSL Inventory Product contains one or more components not listed on inventory.

WHMIS Hazard Class D1A Very Toxic Materials

D2B Toxic Materials

D1B Toxic Materials

BE-3S BACTERICIDE

Page 5 of 6

HESI100182
16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

BE-3S BACTERICIDE

Page 6 of 6

HESI100183
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: BE-6 MICROBIOCIDE

Revision Date: 13-Nov-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: BE-6 MICROBIOCIDE

Synonyms: None

Chemical Family: Not applicable

Application: Biocide

Manufacturer/Supplier Halliburton Energy Services, Inc.

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

2-Bromo-2-nitro-1,3-

propanediol

52-51-7 60 - 100% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye burns. May cause skin and respiratory irritation. May be harmful if

swallowed. May cause allergic skin reaction.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists. Remove

contaminated clothing and launder before reuse.

Eyes Immediately flush eyes with large amounts of water for at least 30 minutes. Seek

prompt medical attention.

Ingestion Do NOT induce vomiting. Give nothing by mouth. Obtain immediate medical

attention.

Notes to Physician None known.

BE-6 MICROBIOCIDE

Page 1 of 6

HESI100184
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 199

Flash Point/Range (C): >93

Flash Point Method: SFCC ASTM D-3828

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Carbon Dioxide, Dry Chemicals, Foam. Use water spray to cool fire exposed

surfaces.

Special Exposure Hazards Decomposition in fire may produce toxic gases. Organic dust in the presence of an

ignition source can be explosive in high concentrations. Good housekeeping

practices are required to minimize this potential.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 3, Flammability 1, Reactivity 2

HMIS Ratings: Health 3, Flammability 1, Physical Hazard 2 , PPE: X

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Scoop up and remove. Flush area with water.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid creating or inhaling dust. Wash

hands after use. Launder contaminated clothing before reuse.

Storage Information Store away from oxidizers. Store in a cool, dry location. Store at temperature below

77 F (25 C). Store in a well ventilated area. Use good housekeeping in storage and

work areas to prevent accumulation of dust. Close container when not in use.

Product has a shelf life of 24 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Not normally needed. But if significant exposures are possible then the following

respirator is recommended:

Organic vapor respirator with a dust/mist filter.

Hand Protection Neoprene gloves. Nitrile gloves. Polyvinylchloride gloves.

Skin Protection Normal work coveralls.

Eye Protection Dust proof goggles.

Other Precautions Eyewash fountains and safety showers must be easily accessible. Rubber boots

BE-6 MICROBIOCIDE

Page 2 of 6

HESI100185
9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid Powder

Color: White

Odor: Characteristic

pH: 5 - 7

Specific Gravity @ 20 C (Water=1): 1.1

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): > 266

Boiling Point/Range (C): > 130

Freezing Point/Range (F): 266

Freezing Point/Range (C): 130

Vapor Pressure @ 20 C (mmHg): 0.0005

Vapor Density (Air=1): > 1

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): > 1

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: 0.18

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers. Contact with alkalis. Contact with metals. Amines.

Hazardous Decomposition

Products

Oxides of nitrogen. Bromine. Hydrogen bromide. Carbon monoxide and carbon

dioxide. Formaldehyde.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation.

Skin Contact May cause severe skin irritation. May cause skin defatting with prolonged exposure.

May cause skin burns on prolonged contact.

Eye Contact May cause eye burns.

Ingestion Causes burns of the mouth, throat and stomach. May be fatal if swallowed.

Aggravated Medical Conditions Skin disorders. Eye ailments. Gastrointestinal disorders.

Chronic Effects/Carcinogenicity Twenty milligrams per kilogram of 1, 3-Propanediol, 2-bromo-2-nitro-, given orally

daily for 90 days, to male and female rats, is well tolerated. Doses of 80 and 160

mg/kg produces gastrointestinal lesions, respiratory distress, and some deaths.

BE-6 MICROBIOCIDE

Page 3 of 6

HESI100186
Other Information None known.

Toxicity Tests

Oral Toxicity: LD50: 180-400 mg/kg (Rat)

LD50: 270 mg/kg (Mouse)

Dermal Toxicity: LD50: 1600 mg/kg (Rat)

LD50: 4750 mg/kg (Mouse)

Inhalation Toxicity: LC50: 800 mg/m3/4 hr. (Rat)

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability THOD (100 ppm Conc.): 60 mg

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: TLM96: 41 ppm (Oncorhynchus mykiss)

TLM96: 36 ppm (Lepomis macrochirus)

 LC50 (96): 58 ppm (Pimephales promelas)

Acute Crustaceans Toxicity:TLM48: 1.4 ppm (Daphnia magna)

 TLM96: 5.9 ppm (Americamysis bahia)

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information LC50: (48 hour) Crassostrea gigas 1.7 ppm

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

UN3241, 2-Bromo-2-Nitropropane-1,3-Diol , 4.1, III

BE-6 MICROBIOCIDE

Page 4 of 6

HESI100187
NAERG 133

Canadian TDG

2-Bromo-2-Nitropropane-1,3-Diol , 4.1, UN3241, III

ADR

UN3241, 2-Bromo-2-Nitropropane-1,3-Diol , 4.1, III

Air Transportation

ICAO/IATA

UN3241, 2-Bromo-2-Nitropropane-1,3-Diol , 4.1, III

Sea Transportation

IMDG

UN3241, 2-Bromo-2-Nitropropane-1,3-Diol , 4.1, III

EmS F-J, S-G

Other Shipping Information

Labels: Flammable Solid

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Fire Hazard

Reactive Hazard

Chronic Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Ignitability D001

Federal Insecticide, Fungicide

and Rodenticide Act:

Label in accordance with Federal Insecticide, Fungicide, and Rodenticide Act

(FIFRA) requirements.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law Does not apply.

BE-6 MICROBIOCIDE

Page 5 of 6

HESI100188
NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law Does not apply.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class B4 Flammable Solids

D1B Toxic Materials

D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

BE-6 MICROBIOCIDE

Page 6 of 6

HESI100189
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: Benchmark +/ZDB Cleanup Solution

Revision Date: 05-Jan-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: Benchmark +/ZDB Cleanup Solution

Synonyms: None

Chemical Family: Blend

Application: Solvent

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Hydrotreated light petroleum

distillate

64742-47-8 60 - 100% 200 mg/m3 Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May be harmful if swallowed.

Combustible.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin Wash with soap and water. Get medical attention if irritation persists. Remove

contaminated clothing and launder before reuse.

Eyes Immediately flush eyes with large amounts of water for at least 15 minutes. Get

immediate medical attention.

Ingestion Get medical attention! If vomiting occurs, keep head lower than hips to prevent

aspiration.

Notes to Physician Not Applicable

Benchmark +/ZDB Cleanup Solution

Page 1 of 6

HESI100190
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 170

Flash Point/Range (C): 77

Flash Point Method: PMCC

Autoignition Temperature (F): > 475

Autoignition Temperature (C): > 246

Flammability Limits in Air - Lower (%): 1.3

Flammability Limits in Air - Upper (%): 8.1

Fire Extinguishing Media Carbon Dioxide, Dry Chemicals, Foam.

Special Exposure Hazards Decomposition in fire may produce toxic gases. Use water spray to cool fire exposed

surfaces. Closed containers may explode in fire. Vapors are heavier than air and

may accumulate in low areas. Vapors may travel along the ground to be ignited at

distant locations.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 2, Reactivity 0

HMIS Ratings: Health 2, Flammability 2, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Remove ignition sources and work with non-sparking tools. Isolate spill and stop

leak where safe. Contain spill with sand or other inert materials. Scoop up and

remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse. Material is slippery underfoot.

Ground and bond containers when transferring from one container to another.

Storage Information Store away from oxidizers. Store in a cool well ventilated area. Keep container

closed when not in use. Keep from heat, sparks, and open flames. Product has a

shelf life of 24 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Not normally needed. But if significant exposures are possible then the following

respirator is recommended:

Organic vapor respirator with a dust/mist filter.

Hand Protection Impervious rubber gloves. Nitrile gloves. Viton gloves Polyvinylchloride gloves.

Skin Protection Normal work coveralls.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

Benchmark +/ZDB Cleanup Solution

Page 2 of 6

HESI100191
9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Milky to pale yellow

Odor: Mild hydrocarbon

pH: 6.5 - 7.5

Specific Gravity @ 20 C (Water=1): 1.05

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 392

Boiling Point/Range (C): 200

Freezing Point/Range (F): 20

Freezing Point/Range (C): -6.7

Vapor Pressure @ 20 C (mmHg): < 0.13

Vapor Density (Air=1): 5.6

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): < 0.1

Solubility in Water (g/100ml): Insoluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. May cause chemical pneumonia. If heated: May

cause central nervous system depression including headache, dizziness,

drowsiness, incoordination, slowed reaction time, slurred speech, giddiness and

unconsciousness.

Skin Contact Causes drying of the skin. May cause skin irritation.

Eye Contact May cause moderate to severe eye irritation.

Ingestion Irritation of the mouth, throat, and stomach. Aspiration into the lungs may cause

chemical pneumonitis including coughing, difficulty breathing, wheezing, coughing up

blood and pneumonia, which can be fatal.

Aggravated Medical Conditions Skin disorders.

Benchmark +/ZDB Cleanup Solution

Page 3 of 6

HESI100192
Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT Not restricted

DOT (Bulk)

Petroleum Distillates, N.O.S., Combustible Liquid, UN1268, III

Classified in accordance with 49 CFR 172.101(d)(4)

Canadian TDG

Not restricted

Benchmark +/ZDB Cleanup Solution

Page 4 of 6

HESI100193
ADR Not restricted

Air Transportation

ICAO/IATA Not restricted

Sea Transportation

IMDG Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law Does not apply.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law Does not apply.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class D2B Toxic Materials

B3 Combustible Liquids

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Benchmark +/ZDB Cleanup Solution

Page 5 of 6

HESI100194
Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

Benchmark +/ZDB Cleanup Solution

Page 6 of 6

HESI100195
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: BF-1

Revision Date: 03-Jan-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: BF-1

Synonyms: None

Chemical Family: Organic acid

Application: Buffer

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Hydroxyacetic acid 79-14-1 60 - 100% 3 ppm Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory burns. May be harmful if swallowed.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

BF-1

Page 1 of 6

HESI100196
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Reacts with metals to generate flammable hydrogen gas. Decomposition in fire may

produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 3, Flammability 0, Reactivity 0

HMIS Ratings: Flammability 0, Reactivity 0, Health 3

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Neutralize to pH of 6-8. Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse.

Storage Information Store away from alkalis. Store in a cool well ventilated area. Keep container closed

when not in use. Product has a shelf life of 36 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Organic vapor/acid gas respirator.

Hand Protection Impervious rubber gloves.

Skin Protection Full protective chemical resistant clothing.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Clear amber

Odor: Mild burnt sugar

BF-1

Page 2 of 6

HESI100197
9. PHYSICAL AND CHEMICAL PROPERTIES

pH: 0.5

Specific Gravity @ 20 C (Water=1): 1.27

Density @ 20 C (lbs./gallon): 10.6

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 234

Boiling Point/Range (C): 112

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: 30

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Miscible

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: 0.0776

Molecular Weight (g/mole): 76.05

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers. Strong alkalis. Sulfuric acid. Ammonium compounds. Amines.

Isocyanates. Contact with metals.

Hazardous Decomposition

Products

Flammable hydrogen gas. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation Causes severe respiratory irritation.

Skin Contact May cause skin burns.

Eye Contact May cause eye burns.

Ingestion Causes burns of the mouth, throat and stomach. May cause abdominal pain,

vomiting, nausea, and diarrhea.

Aggravated Medical Conditions Skin disorders.

Chronic Effects/Carcinogenicity Prolonged, excessive exposure may cause erosion of the teeth.

Other Information None known.

Toxicity Tests

Oral Toxicity: LD50: 4240 mg/kg (Rat)

Dermal Toxicity: Not determined

BF-1

Page 3 of 6

HESI100198
Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Corrosive Liquid, Acidic, Organic, N.O.S., 8, UN3265, II

(Contains Glycolic Acid)

NAERG 153

Canadian TDG

Corrosive Liquid, Acidic, Organic, N.O.S.(Contains Glycolic Acid), 8, UN3265, II

ADR

UN3265,Corrosive Liquid, Acidic, Organic, N.O.S.(Contains Glycolic Acid), 8, II

Air Transportation

ICAO/IATA

UN3265,Corrosive Liquid, Acidic, Organic, N.O.S., 8, II

(Contains Glycolic Acid Solution)

BF-1

Page 4 of 6

HESI100199
Sea Transportation

IMDG

UN3265,Corrosive Liquid, Acidic, Organic, N.O.S.(Contains Glycolic Acid), 8, II

EmS F-A, S-B

Other Shipping Information

Labels: Corrosive

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Corrosivity D002

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law Does not apply.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law Does not apply.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class E Corrosive Material

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

BF-1

Page 5 of 6

HESI100200
Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

BF-1

Page 6 of 6

HESI100201
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: CALCIUM CHLORIDE - POWDER

Revision Date: 16-Nov-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: CALCIUM CHLORIDE - POWDER

Synonyms: None

Chemical Family: Inorganic Salt

Application: Accelerator

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Calcium chloride, dihydrate 10035-04-8 60 - 100% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May be harmful if swallowed.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

CALCIUM CHLORIDE - POWDER

Page 1 of 5

HESI100202
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media All standard firefighting media.

Special Exposure Hazards Not applicable.

Special Protective Equipment for

Fire-Fighters

Not applicable.

NFPA Ratings: Health 1, Flammability 0, Reactivity 0

HMIS Ratings: Health 1, Flammability 0, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid creating or inhaling dust.

Storage Information Store in a cool, dry location.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Dust/mist respirator. (95%)

Hand Protection Normal work gloves.

Skin Protection Normal work coveralls.

Eye Protection Dust proof goggles.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid

Color: White

Odor: Odorless

pH: 10

Specific Gravity @ 20 C (Water=1): 2.1 - 2.5

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): 51

CALCIUM CHLORIDE - POWDER

Page 2 of 5

HESI100203
9. PHYSICAL AND CHEMICAL PROPERTIES

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): 42

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): 147.02

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

None known.

Hazardous Decomposition

Products

None known.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation.

Skin Contact May cause skin irritation. May cause skin burns on prolonged contact.

Eye Contact May cause severe eye irritation. May cause corneal injury.

Ingestion Causes burns of the mouth, throat and stomach.

Aggravated Medical Conditions Skin disorders.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: LD50: 1000 mg/kg (Rat)

Dermal Toxicity: LD50: > 5000 mg/kg (Rabbit)

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

CALCIUM CHLORIDE - POWDER

Page 3 of 5

HESI100204
Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not applicable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

Other Shipping Information

Labels: None

CALCIUM CHLORIDE - POWDER

Page 4 of 5

HESI100205
15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law Does not apply.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law Does not apply.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

CALCIUM CHLORIDE - POWDER

Page 5 of 5

HESI100206
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: CALCIUM CHLORIDE LIQUID

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: CALCIUM CHLORIDE LIQUID

Synonyms: None

Chemical Family: Inorganic Salt

Application: Additive

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Calcium chloride 10043-52-4 30 - 60% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May be harmful if swallowed.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists. Remove

contaminated clothing and launder before reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

CALCIUM CHLORIDE LIQUID

Page 1 of 5

HESI100207
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media All standard firefighting media.

Special Exposure Hazards Not applicable.

Special Protective Equipment for

Fire-Fighters

Not applicable.

NFPA Ratings: Health 1, Flammability 0, Reactivity 0

HMIS Ratings: Health 1, Flammability 0, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors.

Storage Information Store in a cool well ventilated area. Keep container closed when not in use.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Dust/mist respirator. (95%)

Hand Protection Impervious rubber gloves.

Skin Protection Normal work coveralls.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Clear

Odor: Odorless

pH: 5.2

Specific Gravity @ 20 C (Water=1): 1.36

Density @ 20 C (lbs./gallon): 11.33

Bulk Density @ 20 C (lbs/ft3): Not Determined

CALCIUM CHLORIDE LIQUID

Page 2 of 5

HESI100208
9. PHYSICAL AND CHEMICAL PROPERTIES

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): 39.5

Freezing Point/Range (C): 4

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): 58.44

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Amphoteric metals such as aluminum, magnesium, lead, tin, or zinc.

Hazardous Decomposition

Products

None known.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation.

Skin Contact May cause severe skin irritation. May cause skin burns on prolonged contact.

Eye Contact Causes severe eye irritation May cause eye burns.

Ingestion Causes burns of the mouth, throat and stomach.

Aggravated Medical Conditions Skin disorders.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

CALCIUM CHLORIDE LIQUID

Page 3 of 5

HESI100209
Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

Other Shipping Information

Labels: None

CALCIUM CHLORIDE LIQUID

Page 4 of 5

HESI100210
15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law Does not apply.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law Does not apply.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

CALCIUM CHLORIDE LIQUID

Page 5 of 5

HESI100211
I ( c T+?Y?!?l!t! PAGE 01 OF 05 

c nxCALCIUM CHLORIDExx 

nxCALCIUM CHLORIDEXX 

XXCALCIUM CHLORIDEXS 

I MATERIAL SAFETY DATA SHEET 

--------------__-------------------------------------------------------------- 

( FISHER SCIENTIFIC EMERGENCY CONTACTS DATE: 03126187 

CHEMICAL DIVISION GASTON L. PILLORI PO NBR: 6545832 

1 REAGENT LANE (201) 796-7100 ACCT: 294775-01 

FAIR LAWN NJ 07410 INDEX: 32-8708-40240 

(201) 796-7100 

'L 

CAT NO: C79500 

THE INFORMATION BELOW IS BELIEVED TO BE ACCURATE AND REPRESENTS THE BEST 

FORMATION CURRENTLY AVAILABLE TO US. HOWEVER, WE MAKE NO WARRANTY OF 

MERCHANTABILITY OR ANY OTHER WARRANTY, EXPRESS OR IMPLIED, WITH RESPECT TO 

SUCH INFORMATION, AND WE ASSUME NO LIABILITY RESULTING FROM ITS USE. USERS 

SHOULD MAKE THEIR OWN INVESTIGATIONS TO DETERMINE THE SUITABILITY OF THE 

INFORMATION FOR THEIR PARTICULAR PURPOSES. 

------------------------------------------------------------------------------ 

SUBSTANCE IDENTIFICATION 

CAS-NUMBER 10043-52-4 

SUBSTANCE: XXCALCIUM CHLORIDE*% 

TRADE NAMES/SYNONYMS: CALCIUM DICHLORIDE; CALCOSAN; LIQUIDOW; URAMINE MC; 

c-70; C-78; C-79; C-614 

CHEMICAL FAMILY: 

INORGANIC SALT 

MOLECULAR FORMULA: CA-CL2 MOL WT: 110.99 

CERCLA RATINGS (SCALE O-3): HEALTH=3 FIRE=0 REACTIVITY=1 PERSISTENCE=0 

--------_-----_--------------------------------------------------------------- 

COMPONENTS AND CONTAMINANTS 

PERCENT: 100 COMPONENT: CALCIUM CHLORIDE 

OTHER CONTAMINANTS: NONE 

EXPOSURE LIMITS: 

NONE ESTABLISHED -------_-_----------__________I_________-------------------------------------- 

PHYSICAL DATA 

DESCRIPTION: CUBIC CRYSTALS, GRANULES OR FUSED MASSES, VERY HYGROSCOPIC 

AND ODORLESS BOILING POINT: >2912 F (1600 C) 

MELTING POINT: 1431 F (777 C) SPECIFIC GRAVITY: 2.1 

PH: STRONG ACID IN SOL. SOLUBILITY IN WATER: 74.5% @ 20 C 

“SOLVENT SOLUBILITY: ALCOHOL, ACETONE, ACETIC ACID 

HESI100212
xxCALCIUM CHLORIDEx* PAGE 02 OF 05 

------------------------------------------------------------------------------ 

FIRE AND EXPLOSION DATA 

FIRE AND EXPLOSION HAZARD: 

NEGLIGIBLE FIRE/SLIGHT EXPLOSION HAZARD WHEN EXPOSED TO HEAT, FLAME OR SHOCK. 

FLASH POINT: NONCOMBUSTIBLE 

FIREFIGHTING MEDIA: 

DRY CHEMICAL, CARBON DIOXIDE, WATER SPRAY OR FOAM 

(1984 EMERGENCY RESPONSE GUIDEBOOK, DOT P 5800.3). 

FOR LARGER FIRES, USE WATER SPRAY, FOG OR ALCOHOL FOAM 

(1984 EMERGENCY RESPONSE GUIDEBOOK, DOT P 5800.3). 

FIREFIGHTING: 

NO ACUTE HAZARD. MOVE CONTAINER FROM FIRE AREA IF POSSIBLE. AVOID BREATHING 

VAPORS OR DUSTS; KEEP UPWIND. 

TOXICITY 

1000 MG/KG ORAL-RAT LD50; 1384 MG/KG ORAL-RABBIT LDLO; 500 MG/KG 

INTRAPERITONEAL-RAT LDLO; 161 MG/KG INTRAVENOUS-RAT LDLO; 25 MG/KG 

INTRAMUSCULAR-RAT LD50; 280 MG/KG INTRAPERITONEAL-MOUSE LD50; 110 MG/KG 

INTRAPERITONEAL-DOG LDLO; 274 MG/KG SUBCUTANEOUS-DOG LDLO; 274 MG/KG 

INTRAVENOUS-DOG LDLO; 249 MG/KG SUBCUTANEOUS-CAT LDLO; MUTAGENIC DATA (RTECS); 

TUMORIGENIC DATA (RTECS); CARCINOGEN STATUS: NONE. 

CALCIUM CHLORIDE IS CORROSIVE TO THE EYES, SKIN, AND MUCOUS MEMBRANES. 

------------------------------------------------------------------------------ 

HEALTH EFFECTS AND FIRST AID 

INHALATION: 

CORROSIVE. 

ACUTE EXPOSURE- INHALATION OF ACIDIC FUMES OR MIST NAY CAUSE COUGHING, CHOKING, HEADACHE, DIZZINESS, WEAKNESS, HYPOTENSION, AND DELAYED 

PULMONARY EDEMA WITH CHEST TIGHTNESS, APNEA, FROTHY SPUTUM, 

AND CYANOSIS. DYSPNEA AND HEMOPTYSIS ARE POSSIBLE FOR 

SEVERAL WEEKS AFTER EXPOSURE. 

CHRONIC EXPOSURE- REPEATED OR PROLONGED EXPOSURE TO ACID FUMES MAY CAUSE 

EROSION OF TEETH FOLLOWED BY JAW NECROSIS. BRONCHIAL 

IRRITATION WITH COUGH AND FREQUENT ATTACKS OF BRONCHIAL 

PNEUMONIA MAY OCCUR. GASTROINTESTINAL DISTURBANCES ARE 

ALSO POSSIBLE. SEE ANIMAL MUTAGENIC, AND TUMORIGENIC 

REFERENCES IN TOXICITY SECTION. 

FIRST AID: REMOVE FROM EXPOSURE AREA TO FRESH AIR IMMEDIATELY. IF BREATHING 

HAS STOPPED, GIVE ARTIFICIAL RESPIRATION. MAINTAIN AIRWAY AND BLOOD 

PRESSURE AND ADMINISTER OXYGEN IF AVAILABLE. KEEP AFFECTED PERSON WARM AND 

AT REST. ADMINISTRATION OF OXYGEN SHOULD BE PERFORMED BY QUALIFIED 

PERSONNEL. GET MEDICAL ATTENTION IMMEDIATELY. 

HESI100213
c 

SKIN CONTACT: 

CORROSIVE. 

#xCALCIUM CHLORIDEx* 

l. 

PAGE 03 OF 05 

ACUTE EXPOSURE- DIRECT CONTACT MAY CAUSE SEVERE PAIN AND BROWNISH OR YELLOW 

STAINS. BURNS MAY BE DEEP WITH SHARP EDGES AND HEAL SLOWLY WITH SCAR 

TISSUE FORMATION. 

CHRONIC EXPOSURE- REPEATED OR PROLONGED EXPOSURE TO LOW LEVELS MAY CAUSE 

DERMATITIS. 

FIRST AID- REMOVE CONTAMINATED CLOTHING AND SHOES, DIRECTING A STREAM OF 

WATER UNDER CLOTHING WHILE IT IS BEING REMOVED. WASH AFFECTED AREA WITH 

SOAP OR MILD DETERGENT AND LARGE AMOUNTS OF WATER UNTIL NO EVIDENCE OF 

CHEMICAL REMAINS (APPROXIMATELY 15-20 MINUTES). IN CASE OF BURNS, COVER 

AREA WITH STERILE, DRY DRESSING. BANDAGE SECURELY, BUT NOT TOO TIGHTLY. 

GET MEDICAL ATTENTION. 

EYE CONTACT: 

CORROSJVE. 

ACUTE EXPOSURE- VAPORS ARE IRRITATING AND MAY CAUSE PROFUSE LACRIMATION. 

DIRECT CONTACT MAY CAUSE IRRITATION, BURNS, AND PERMANENT CORNEAL DAMAGE. 

CHRONIC EXPOSURE- REPEATED OR PROLONGED CONTACT WITH VAPORS MAY CAUSE 

CONJUNCTIVITIS. 

FIRST AID- WASH EYES IMMEDIATELY WITH LARGE AMOUNTS OF WATER, OCCASIONALLY 

LIFTING UPPER AND LOWER LIDS, UNTIL NO EVIDENCE OF CHEMICAL REMAINS (AT 

LEAST 15-20 MINUTES). FOR TREATMENT OF BURNS, APPLY STERILE BANDAGES 

LOOSELY WITHOUT MEDICATION. GET MEDICAL ATTENTION. 

INGESTION: 

CORROSIVE. 

ACUTE EXPOSURE- INGESTION MAY CAUSE SEVERE BURNING PAIN IN THE MOUTH, 

PHARYNX, AND ABDOMEN FOLLOWED BY VOMITING AND DIARRHEA OF 

DARK PRECIPITATED BLOOD. THE BLOOD PRESSURE MAY FALL SHARPLY 

AND BROWNISH OR YELLOWISH STAINS MAY BE FOUND AROUND THE 

MOUTH AND THROAT. ASPHYXIA MAY OCCUR FROM EDEMA OF THE 

GLOTTIS. 

FIRST AID- IF VICTIM IS CONSCIOUS AND NOT CONVULSIVE GIVE HIM LARGE 

QUANTITIES OF WATER IMMEDIATELY TO DILUTE THE ACID. DO NOT INDUCE 

VOMITING. IF RESPIRATION IS DEPRESSED, GIVE OXYGEN. GET MEDICAL ATTENTION 

IMMEDIATELY. 

--__________________---------------------------------------------------------- 

REACTIVITY 

REACTIVITY: 

-STABLE AT NORMAL PRESSURES UP TO THE BOILING POINT, AT SOME POINT >1600 C. 

INTENSE EXOTHERMIC REACTION WITH WATER. 

INCOMPATIBILITIES: 

REACTS EXPLOSIVELY WITH ZINC, AND WITH 2-FURAN PERCARBOXYLIC ACID ON HEATING. 

REACTS INCANDESCENTLY WITH BORIC OXIDE AND CALCIUM OXIDE. 

RAPIDLY ATTACKS BROMINE TRIFLUORIDE. 

~~DECOMPOSITION: 

NOT APPLICABLE: BOILS AWAY UNCHANGED AT SOME POINT >1600 C. 

HESI100214
POLYMERIZATION: 

xxCALCIUM CHLORIDEXX PAGE 04 OF 05 

MAY CATALYZE EXOTHERMIC POLYMERIZATION OF METHYL VINYL ETHER. 

CONDITIONS TO AVOID 

TEMPERATURES IN THE VICINITY OF THE BOILING POINT, WHERE DECOMPOSITION OCCURS. 

AVOID HEATING TO THE BOILING POINT, WHERE DECOMPOSITION OCCURS. CONTACT WITH 

OR STORAGE WITH INCOMPATIBLE MATERIALS (ALSO SEE POLYMERIZATION AND REACTIVITY 

SECTIONS). 

SPILL AND LEAK PROCEDURES 

OCCUPATIONAL SPILL: 

ABSORB WITH VERMICULITE OR OTHER SUITABLE MATERIAL, SCOOP UP ANS PLACE IN A 

SUITABLE CONTAINER (FIBER BOARD OR PLASTIC) FOR LATER DISPOSAL. 

--~~~~~-~~--~--~---------------------------------------~--------~-~~----~~---- 

PROTECTIVE EQUIPMENT 

VENTILATION: 

PROVIDE GENERAL DILUTION VENTILATION. 

RESPIRATOR: 

HIGH LEVELS- HIGH-EFFICIENCY PARTICULATE RESPIRATOR WITH A FULL FACEPIECE. 

SUPPLIED-AIR RESPIRATOR WITH A FULL FACEPIECE, HELMET, OR HOOD. 

SELF-CONTAINED BREATHING APPARATUS WITH A FULL FACEPIECE. 

FIRE FIGHTING- SELF-CONTAINED BREATHING APPARATUS WITH A FULL FACEPIECE, 

OPERATED IN PRESSURE-DEMAND OR OTHER POSITIVE PRESSURE MODE. 

CLOTHING: 

EMPLOYEE MUST WEAR APPROPRIATE PROTECTIVE CLOTHING AND EQUIPMENT TO PREVENT 

ANY POSSIBILITY OF SKIN CONTACT WITH THIS SUBSTANCE. 

GLOVES: 

EMPLOYEE MUST WEAR APPROPRIATE PROTECTIVE GLOVES TO PREVENT CONTACT WITH THIS 

SUBSTANCE. 

EYE PROTECTION: 

EMPLOYEE MUST WEAR SPLASH-PROOF OR DUST-RESISTANT SAFETY GOGGLES AND A 

FACESHIELD TO PREVENT CONTACT WITH THIS SUBSTANCE. 

WHERE THERE IS ANY POSSIBILITY THAT AN EMPLOYEE’S EYES MAY BE EXPOSED TO 

--THIS SUBSTANCE, THE EMPLOYER SHALL PROVIDE AN EYE-WASH FOUNTAIN WITHIN THE 

IMMEDIATE WORK AREA FOR EMERGENCY USE. 

AUTHORIZED - ALLIED FISHER SCIENTIFIC 

CREATION DATE: 05107185 REVISION DATE: 06114185 

-ADDITIONAL INFORMATIONs--THE INFORMATION BELOW IS BELIEVED TO BE ACCURATE AND REPRESENTS THE BEST 

“INFORMATION CURRENTLY AVAILABLE TO US. HOWEVER, WE MAKE NO WARRANTY OF 

MERCHANTABILITY OR ANY OTHER WARRANTY, EXPRESS OR IMPLIED, WITH RESPECT TO 

HESI100215
l-l- 

-l 

HESI100216
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: CARBO HSP PROPPANT

Revision Date: 03-Jan-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: CARBO HSP PROPPANT

Synonyms: None

Chemical Family: Mineral

Application: Proppant

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Aluminum oxide 1344-28-1 60 - 100% 10 mg/m3 10 mg/m3

Crystalline silica, cristobalite 14464-46-1 1 - 5% 0.025 mg/m3 1/2 x 10 mg/m3

 %SiO2 + 2

More restrictive exposure limits may be enforced by some states, agencies, or other authorities.

3. HAZARDS IDENTIFICATION

Hazard Overview CAUTION! - ACUTE HEALTH HAZARD

May cause eye and respiratory irritation.

DANGER! - CHRONIC HEALTH HAZARD

Breathing crystalline silica can cause lung disease, including silicosis and lung

cancer. Crystalline silica has also been associated with scleroderma and kidney

disease.

This product contains quartz, cristobalite, and/or tridymite which may become

airborne without a visible cloud. Avoid breathing dust. Avoid creating dusty

conditions. Use only with adequate ventilation to keep exposures below

recommended exposure limits. Wear a NIOSH certified, European Standard EN

149, or equivalent respirator when using this product. Review the Material Safety

Data Sheet (MSDS) for this product, which has been provided to your employer.

CARBO HSP PROPPANT

Page 1 of 7

HESI100217
4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Under normal conditions, first aid procedures are not required.

Notes to Physician Not Applicable

5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media All standard firefighting media.

Special Exposure Hazards Not applicable.

Special Protective Equipment for

Fire-Fighters

Not applicable.

NFPA Ratings: Health 0, Flammability 0, Reactivity 0

HMIS Ratings: Flammability 0, Reactivity 0, Health 0*

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

None known.

Procedure for Cleaning /

Absorption

Collect using dustless method and hold for appropriate disposal. Consider possible

toxic or fire hazards associated with contaminating substances and use appropriate

methods for collection, storage and disposal.

7. HANDLING AND STORAGE

Handling Precautions This product contains quartz, cristobalite, and/or tridymite which may become

airborne without a visible cloud. Avoid breathing dust. Avoid creating dusty

conditions. Use only with adequate ventilation to keep exposure below

recommended exposure limits. Wear a NIOSH certified, European Standard En 149,

or equivalent respirator when using this product. Material is slippery when wet.

Storage Information Use good housekeeping in storage and work areas to prevent accumulation of dust.

Close container when not in use.

CARBO HSP PROPPANT

Page 2 of 7

HESI100218
8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use approved industrial ventilation and local exhaust as required to maintain

exposures below applicable exposure limits listed in Section 2.

Respiratory Protection Wear a NIOSH certified, European Standard EN 149, or equivalent respirator when

using this product.

Hand Protection Normal work gloves.

Skin Protection Wear clothing appropriate for the work environment. Dusty clothing should be

laundered before reuse. Use precautionary measures to avoid creating dust when

removing or laundering clothing.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions None known.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid

Color: Dark green

Odor: Odorless

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 3.56

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): 110

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Insoluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Hydrofluoric acid.

Hazardous Decomposition

Products

Amorphous silica may transform at elevated temperatures to tridymite (870 C) or

cristobalite (1470 C).

Additional Guidelines Not Applicable

CARBO HSP PROPPANT

Page 3 of 7

HESI100219
11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation Inhaled crystalline silica in the form of quartz or cristobalite from occupational

sources is carcinogenic to humans (IARC, Group 1). There is sufficient evidence in

experimental animals for the carcinogenicity of tridymite (IARC, Group 2A).

Breathing silica dust may cause irritation of the nose, throat, and respiratory

passages. Breathing silica dust may not cause noticeable injury or illness even

though permanent lung damage may be occurring. Inhalation of dust may also have

serious chronic health effects (See "Chronic Effects/Carcinogenicity" subsection

below).

Skin Contact None known.

Eye Contact May cause eye irritation.

Ingestion None known

Aggravated Medical Conditions Individuals with respiratory disease, including but not limited to asthma and

bronchitis, or subject to eye irritation, should not be exposed to quartz dust.

Chronic Effects/Carcinogenicity Silicosis: Excessive inhalation of respirable crystalline silica dust may cause a

progressive, disabling, and sometimes-fatal lung disease called silicosis. Symptoms

include cough, shortness of breath, wheezing, non-specific chest illness, and

reduced pulmonary function. This disease is exacerbated by smoking. Individuals

with silicosis are predisposed to develop tuberculosis.

Cancer Status: The International Agency for Research on Cancer (IARC) has

determined that crystalline silica inhaled in the form of quartz or cristobalite from

occupational sources can cause lung cancer in humans (Group 1 - carcinogenic to

humans) and has determined that there is sufficient evidence in experimental

animals for the carcinogenicity of tridymite (Group 2A - possible carcinogen to

humans). Refer to IARC Monograph 68, Silica, Some Silicates and Organic Fibres

(June 1997) in conjunction with the use of these minerals. The National Toxicology

Program classifies respirable crystalline silica as "Known to be a human carcinogen".

Refer to the 9th Report on Carcinogens (2000). The American Conference of

Governmental Industrial Hygienists (ACGIH) classifies crystalline silica, quartz, as a

suspected human carcinogen (A2).

There is some evidence that breathing respirable crystalline silica or the disease

silicosis is associated with an increased incidence of significant disease endpoints

such as scleroderma (an immune system disorder manifested by scarring of the

lungs, skin, and other internal organs) and kidney disease.

Other Information For further information consult "Adverse Effects of Crystalline Silica Exposure"

published by the American Thoracic Society Medical Section of the American Lung

Association, American Journal of Respiratory and Critical Care Medicine, Volume

155, pages 761-768 (1997).

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

CARBO HSP PROPPANT

Page 4 of 7

HESI100220
Primary Irritation Effect: Not determined

Carcinogenicity Refer to IARC Monograph 68, Silica, Some Silicates and Organic Fibres (June

1997).

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not applicable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Not restricted

Canadian TDG

Not restricted

ADR Not restricted

Air Transportation

ICAO/IATA Not restricted

Sea Transportation

IMDG Not restricted

Other Shipping Information

CARBO HSP PROPPANT

Page 5 of 7

HESI100221
Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Aluminum Oxide//1344-28-1

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 The California Proposition 65 regulations apply to this product.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class D2A Very Toxic Materials

Crystalline silica

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

CARBO HSP PROPPANT

Page 6 of 7

HESI100222
***END OF MSDS***

CARBO HSP PROPPANT

Page 7 of 7

HESI100223
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: CARBON DIOXIDE, LIQUIFIED

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: CARBON DIOXIDE, LIQUIFIED

Synonyms: None

Chemical Family: Not applicable

Application: Fluid

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Carbon dioxide 124-38-9 60 - 100% 5000 ppm 5000 ppm

3. HAZARDS IDENTIFICATION

Hazard Overview May cause freeze burns. Reduces oxygen available for breathing.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin For exposure to liquid, immediately warm frostbite area with warm water (not to

exceed 105 F or 41 C). In case of massive exposure, remove clothing while

showering with warm water. Get medical attention.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion If swallowed, induce vomiting immediately by giving two glasses of water and sticking

fingers down throat; never give anything to an unconscious person. Get medical

attention.

Notes to Physician Not Applicable

CARBON DIOXIDE, LIQUIFIED

Page 1 of 6

HESI100224
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media All standard firefighting media.

Special Exposure Hazards Not applicable.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 0, Flammability 0, Reactivity 0

HMIS Ratings: Health 0, Flammability 0, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Evacuate all persons from the area.

Environmental Precautionary

Measures

None known.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Ventilate area.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing.

Storage Information Store in a well ventilated area.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Not normally necessary.

In high concentrations, supplied air respirator or a self-contained breathing

apparatus.

Hand Protection Impervious rubber gloves.

Skin Protection Normal work coveralls.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions None known.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Colorless

Odor: Odorless

CARBON DIOXIDE, LIQUIFIED

Page 2 of 6

HESI100225
9. PHYSICAL AND CHEMICAL PROPERTIES

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 1.01

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): 8.45

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: 100

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): 44.01

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

None known.

Hazardous Decomposition

Products

None known.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation Reduces oxygen available for breathing. May cause increase in respiration rate.

Skin Contact Contact of material on skin may result in frostbite.

Eye Contact Contact with liquid causes frostbite.

Ingestion Causes burns of the mouth, throat and stomach.

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

CARBON DIOXIDE, LIQUIFIED

Page 3 of 6

HESI100226
Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

UN2187,Carbon Dioxide, Refrigerated Liquid, 2.2

NAERG 120

Canadian TDG

Carbon Dioxide, Refrigerated Liquid, 2.2, UN2187

ADR

UN2187,Carbon Dioxide, Refrigerated Liquid, 2.2

Air Transportation

ICAO/IATA

UN2187,Carbon Dioxide, Refrigerated Liquid, 2.2

CARBON DIOXIDE, LIQUIFIED

Page 4 of 6

HESI100227
Sea Transportation

IMDG

UN2187,Carbon Dioxide, Refrigerated Liquid, 2.2

EmS F-C, S-V

Other Shipping Information

Labels: Non-Flammable Gas

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Sudden Release of Pressure Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class A Compressed Gas

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

CARBON DIOXIDE, LIQUIFIED

Page 5 of 6

HESI100228
Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

CARBON DIOXIDE, LIQUIFIED

Page 6 of 6

HESI100229
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: CAT-1

Revision Date: 19-Mar-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: CAT-1

Synonyms: None

Chemical Family: Inorganic

Application: Catalyst

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Sodium hypochlorite 7681-52-9 10 - 30% Not applicable Not applicable

Sodium hydroxide 1310-73-2 0 - 2% 2 mg/m3 2 mg/m3

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye and skin burns. May cause respiratory irritation. May be harmful if

swallowed.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes Immediately flush eyes with large amounts of water for at least 20 minutes. Seek

prompt medical attention.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

CAT-1

Page 1 of 6

HESI100236
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases. Reacts with metals to generate

flammable hydrogen gas.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 3, Flammability 0, Reactivity 1

HMIS Ratings: Health 3, Flammability 0, Reactivity 1

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Remove ignition sources and work with nonsparking tools. Contain spill with sand or other inert materials. Scoop up and

remove. Hypochlorite can be broken down by covering it with a reducing agent such

as sodium sulfite or sodium thiosulfate.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse.

Storage Information Store away from acids. Store away from reducing agents. Store in a cool well

ventilated area. Store away from direct sunlight. Keep container closed when not in

use. Store between 59 F (15 C) and 84 F (29 C). Keep from freezing. Product has a

shelf life of 6 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Acid gas respirator with a dust/mist filter. In high concentrations, supplied air

respirator or a self-contained breathing apparatus.

Hand Protection Impervious rubber gloves. Nitrile gloves. Neoprene gloves. Viton gloves Butyl rubber

gloves.

Skin Protection Rubber apron.

Eye Protection Splashproof chemical monogoggles or safety glasses with side shields in conjunction

with a face shield.

CAT-1

Page 2 of 6

HESI100237
Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Clear light yellow

Odor: Pungent

pH: 13

Specific Gravity @ 20 C (Water=1): 1.14

Density @ 20 C (lbs./gallon): 9.5

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 85

Boiling Point/Range (C): 29

Freezing Point/Range (F): 7.5

Freezing Point/Range (C): -13.6

Vapor Pressure @ 20 C (mmHg): 17.5

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Avoid contact with hydrochloric acid. Can react to release chlorine gas. Contact with

certain metals produces hydrogen gas.

Incompatibility (Materials to

Avoid)

Strong acids. Reducing agents. Contact with metals. Ammonium compounds.

Organic matter. Nitrogen. Cyanides. Alcohols.

Hazardous Decomposition

Products

Hydrogen chloride. Chlorine. Hypochlorous acid. Flammable hydrogen gas.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation Causes severe respiratory irritation.

Skin Contact Causes severe skin irritation. May cause skin burns. May cause an allergic skin

reaction.

Eye Contact Causes severe eye irritation May cause eye burns.

Ingestion Causes burns of the mouth, throat and stomach. May be fatal if swallowed.

Aggravated Medical Conditions Skin disorders. Lung disorders.

CAT-1

Page 3 of 6

HESI100238
Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: LD50: 8910 mg/kg (Rat)

Dermal Toxicity: LD50: 1350 mg/kg (Rabbit)

Inhalation Toxicity: LC50: > 10500 mg/l 1-hour (rat)

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Readily biodegradable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: TLM48: 0.07 mg/l (Oncorhynchus mykiss) TLM96: 5.9 mg/l (Pimephales promelas)

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

UN1791,Hypochlorite Solution, 8, III

RQ (Sodium Hypochlorite - 454 kg.)

NAERG 154

Canadian TDG

Hypochlorite Solution, 8, UN1791, III

CAT-1

Page 4 of 6

HESI100239
ADR

UN1791,Hypochlorite Solution, 8, III

Air Transportation

ICAO/IATA

UN1791,Hypochlorite Solution, 8, III

(10% Available Chlorine)

RQ (Sodium Hypochlorite - 454 kg.)

Sea Transportation

IMDG

UN1791,Hypochlorite Solution, 8, III

RQ (Sodium Hypochlorite - 454 kg.)

EmS F-A, S-B

Other Shipping Information

Labels: Corrosive

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 105 Gallons based on Sodium hypochlorite (CAS:

7681-52-9).

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Corrosivity D002

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class E Corrosive Material

CAT-1

Page 5 of 6

HESI100240
16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

CAT-1

Page 6 of 6

HESI100241
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: CAT-3 ACTIVATOR

Revision Date: 09-Feb-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: CAT-3 ACTIVATOR

Synonyms: None

Chemical Family: Blend

Application: Activator

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

EDTA/Copper chelate 10 - 30% Not applicable 1 mg/m3

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause headache, dizziness, and

other central nervous system effects. May be harmful if swallowed.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion If swallowed, induce vomiting immediately by giving two glasses of water and sticking

fingers down throat; never give anything to an unconscious person. Get medical

attention.

Notes to Physician Not Applicable

CAT-3 ACTIVATOR

Page 1 of 6

HESI100242
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not DeterminedMin: > 185

Flash Point/Range (C): Not DeterminedMin: > 85

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media All standard firefighting media.

Special Exposure Hazards Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 0, Reactivity 0

HMIS Ratings: Health 1, Flammability 0, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors.

Storage Information Store away from oxidizers. Store in a cool well ventilated area. Keep container

closed when not in use. Product has a shelf life of 24 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Ammonia respirator with a dust/mist filter.

Hand Protection Impervious rubber gloves.

Skin Protection Normal work coveralls.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Clear blue

Odor: Ammonia

pH: 8.5-9.5

Specific Gravity @ 20 C (Water=1): 1.06

Density @ 20 C (lbs./gallon): 8.83

CAT-3 ACTIVATOR

Page 2 of 6

HESI100243
9. PHYSICAL AND CHEMICAL PROPERTIES

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): 20

Freezing Point/Range (C): - 6.7

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Oxides of nitrogen. Ammonia. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. May cause central nervous system depression

including headache, dizziness, drowsiness, incoordination, slowed reaction time,

slurred speech, giddiness and unconsciousness.

Skin Contact May cause skin irritation.

Eye Contact May cause eye irritation.

Ingestion May cause central nervous system depression including headache, dizziness,

drowsiness, muscular weakness, incoordination, slowed reaction time, fatigue

blurred vision, slurred speech, giddiness, tremors and convulsions.

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

CAT-3 ACTIVATOR

Page 3 of 6

HESI100244
Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

CAT-3 ACTIVATOR

Page 4 of 6

HESI100245
IMDG

 Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law Does not apply.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law Does not apply.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

CAT-3 ACTIVATOR

Page 5 of 6

HESI100246
Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

CAT-3 ACTIVATOR

Page 6 of 6

HESI100247
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: CAT-3WB

Revision Date: 03-Jan-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: CAT-3WB

Synonyms: None

Chemical Family: Blend

Application: Activator

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

EDTA/Copper chelate 10 - 30% Not applicable 1 mg/m3

Methanol 67-56-1 10 - 30% 200 ppm 200 ppm (S)

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause headache, dizziness, and

other central nervous system effects. May be harmful if swallowed. May be absorbed

through the skin. Repeated overexposure may cause liver and kidney effects.

Combustible.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

CAT-3WB

Page 1 of 6

HESI100248
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 128

Flash Point/Range (C): 53

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Use water spray to cool fire exposed surfaces. Closed containers may explode in

fire. Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 2, Reactivity 0

HMIS Ratings: Flammability 2, Reactivity 0, Health 2

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Wear self-contained breathing apparatus in

enclosed areas.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse.

Storage Information Store away from oxidizers. Store in a cool well ventilated area. Keep from heat,

sparks, and open flames. Keep container closed when not in use. Product has a

shelf life of 24 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Positive pressure self-contained breathing apparatus if methanol is released.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

CAT-3WB

Page 2 of 6

HESI100249
9. PHYSICAL AND CHEMICAL PROPERTIES

Color: Clear blue

Odor: Mild ammonia

pH: 8.5-9.5

Specific Gravity @ 20 C (Water=1): 1.05

Density @ 20 C (lbs./gallon): 8.75

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Oxides of nitrogen. Ammonia. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. May cause central nervous system depression

including headache, dizziness, drowsiness, incoordination, slowed reaction time,

slurred speech, giddiness and unconsciousness.

Skin Contact May cause skin irritation. May be absorbed through the skin and produce effects

similar to those caused by inhalation and/or ingestion.

Eye Contact May cause eye irritation.

Ingestion May be fatal or cause blindness if swallowed. May cause central nervous system

depression including headache, dizziness, drowsiness, muscular weakness,

incoordination, slowed reaction time, fatigue blurred vision, slurred speech,

giddiness, tremors and convulsions.

Aggravated Medical Conditions Skin disorders. Eye ailments.

CAT-3WB

Page 3 of 6

HESI100250
Chronic Effects/Carcinogenicity Prolonged or repeated exposure may cause eye, blood, lung, liver, kidney, heart,

central nervous system and spleen damage.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Flammable Liquid, N.O.S., 3, UN1993, III, (53 C)

(Contains Methanol)

NAERG 128

Canadian TDG

Flammable Liquid, N.O.S.(Contains Methanol), 3, UN1993, III, (53 C)

CAT-3WB

Page 4 of 6

HESI100251
ADR

UN1993,Flammable Liquid, N.O.S.(Contains Methanol), 3, III

Air Transportation

ICAO/IATA

UN1993,Flammable Liquid, N.O.S., 3, III

(Contains Methanol Solution)

Sea Transportation

IMDG

UN1993,Flammable Liquid, N.O.S.(Contains Methanol), 3, III, (53 C)

EmS F-E, S-E

Other Shipping Information

Labels: Flammable Liquid

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Copper and Compounds//67989-88-2

Methanol//67-56-1

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 5790 Gallons based on Methanol (CAS: 67-56-1)

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class B3 Combustible Liquids

D2B Toxic Materials

CAT-3WB

Page 5 of 6

HESI100252
16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

CAT-3WB

Page 6 of 6

HESI100253
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: CAT-4

Revision Date: 03-Jan-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: CAT-4

Synonyms: None

Chemical Family: Amine

Application: Activator

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Diethylenetriamine 111-40-0 30 - 60% 1 ppm (S) Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory burns. May be harmful if swallowed. May be

absorbed through the skin. May cause allergic skin reaction.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse. Destroy or properly dispose of contaminated shoes.

Eyes Immediately flush eyes with large amounts of water for at least 30 minutes. Seek

prompt medical attention.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

CAT-4

Page 1 of 6

HESI100254
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): > 215

Flash Point/Range (C): > 102

Flash Point Method: PMCC

Autoignition Temperature (F): 743

Autoignition Temperature (C): 395

Flammability Limits in Air - Lower (%): 4.4

Flammability Limits in Air - Upper (%): 16.1

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 1, Reactivity 0

HMIS Ratings: Health 2, Flammability 1, Physical Hazard 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse.

Storage Information Store away from oxidizers. Store away from acids. Store in a cool well ventilated

area. Keep container closed when not in use. Product has a shelf life of 24 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection If engineering controls and work practices cannot keep exposure below occupational

exposure limits or if exposure is unknown, wear a NIOSH certified, European

Standard EN 149, or equivalent respirator when using this product. Selection of and

instruction on using all personal protective equipment, including respirators, should

be performed by an Industrial Hygienist or other qualified professional.

Organic vapor respirator.

Hand Protection Nitrile gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

CAT-4

Page 2 of 6

HESI100255
9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Light yellow

Odor: Amine

pH: 8.5-9

Specific Gravity @ 20 C (Water=1): 1.1348

Density @ 20 C (lbs./gallon): 9.41

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): < -20

Freezing Point/Range (C): < -29

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Miscible

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers. Strong acids. Copper and copper alloys.

Hazardous Decomposition

Products

Oxides of nitrogen. Ammonia. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. May cause central nervous system depression

including headache, dizziness, drowsiness, incoordination, slowed reaction time,

slurred speech, giddiness and unconsciousness.

Skin Contact Causes severe burns. May be absorbed through the skin and produce effects similar

to those caused by inhalation and/or ingestion. May cause an allergic skin reaction.

Eye Contact May cause eye burns.

Ingestion Causes burns of the mouth, throat and stomach. May cause abdominal pain,

vomiting, nausea, and diarrhea.

Aggravated Medical Conditions Skin disorders.

CAT-4

Page 3 of 6

HESI100256
Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: LD50: 1080 mg/kg (Rat)

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Slowly biodegradable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Not restricted

Canadian TDG

Not restricted

ADR Not restricted

CAT-4

Page 4 of 6

HESI100257
Air Transportation

ICAO/IATA Not restricted

Sea Transportation

IMDG Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class E Corrosive Material

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

CAT-4

Page 5 of 6

HESI100258
Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

CAT-4

Page 6 of 6

HESI100259
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: CAT-OS-1

Revision Date: 05-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: CAT-OS-1

Synonyms: None

Chemical Family: Acetate

Application: Activator

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Cobalt acetate 71-48-7 5 - 10% 0.02 mg/m3 Not applicable

Ammonium acetate 631-61-8 10 - 30% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May affect thyroid, lungs, heart, and kidneys. May cause birth defects. Potential

carcinogen. May cause eye, skin, and respiratory irritation. May be harmful if

swallowed. May cause allergic skin and respiratory reaction.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

CAT-OS-1

Page 1 of 6

HESI100230
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not DeterminedMin: > 200

Flash Point/Range (C): Not DeterminedMin: > 93

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 1, Reactivity 0

HMIS Ratings: Health 1, Flammability 1, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse.

Storage Information Store away from oxidizers. Store away from acids. Keep container closed when not

in use.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Dust/mist respirator. (95%)

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Dark purple

Odor: Mild vinegar

pH: 8 - 8.5

Specific Gravity @ 20 C (Water=1): 1.0837

CAT-OS-1

Page 2 of 6

HESI100231
9. PHYSICAL AND CHEMICAL PROPERTIES

Density @ 20 C (lbs./gallon): 9.0

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): 2-18

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers. Strong acids.

Hazardous Decomposition

Products

Ammonia. Oxides of nitrogen. Metal oxides. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. May cause allergic respiratory reaction.

Skin Contact May cause skin irritation. May cause an allergic skin reaction.

Eye Contact May cause eye irritation.

Ingestion Causes abdominal pain, nausea, vomiting, flushing of the face and ears, mild

hypotension, rash, and ringing in the ears. May have cumulative toxic action where

elimination cannot keep pace with absorption. May affect the blood and blood

system.

Aggravated Medical Conditions Liver and kidney disorders.

Chronic Effects/Carcinogenicity This product is a suspected carcinogen. Prolonged or repeated exposure may cause

kidney, lung and blood effects. Prolonged or repeated exposure may cause heart

damage. Prolonged or repeated exposure may cause damage to the thyroid gland.

May cause birth defects.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

CAT-OS-1

Page 3 of 6

HESI100232
Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

CAT-OS-1

Page 4 of 6

HESI100233
IMDG

 Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Cobalt and Compounds

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class D2A Very Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

CAT-OS-1

Page 5 of 6

HESI100234
Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

CAT-OS-1

Page 6 of 6

HESI100235
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: CCA-H2S

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: CCA-H2S

Synonyms: None

Chemical Family: Amine

Application: Hydrogen Sulfide Scavenger

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Hexamethylenetetramine 100-97-0 60 - 100% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause allergic skin and

respiratory reaction. May be absorbed through the skin. May be harmful if swallowed.

Flammable.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin Wash with soap and water. Get medical attention if irritation persists. Remove

contaminated clothing and launder before reuse.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician None known.

CCA-H2S

Page 1 of 6

HESI100260
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 482

Flash Point/Range (C): 250

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases. Organic dust in the presence of an

ignition source can be explosive in high concentrations. Good housekeeping

practices are required to minimize this potential.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 1, Reactivity 0

HMIS Ratings: Health 1, Flammability 1, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid creating or inhaling dust. Wash

hands after use.

Storage Information Store in a dry location. Store in a cool well ventilated area. Keep from heat, sparks,

and open flames. Keep container closed when not in use. Product has a shelf life of

36 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Dust/mist respirator. (95%)

Hand Protection Nitrile gloves.

Skin Protection Normal work coveralls.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions None known.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid

CCA-H2S

Page 2 of 6

HESI100261
9. PHYSICAL AND CHEMICAL PROPERTIES

Color: White

Odor: Mild amine

pH: 8.5

Specific Gravity @ 20 C (Water=1): Not Determined

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): 46

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): 2.63

Vapor Density (Air=1): 4.9

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): 81

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers. Strong acids. Anhydrides. Isocyanates. Acrylates. Ketones.

Aldehydes. Alcohols. Amphoteric metals such as aluminum, magnesium, lead, tin, or

zinc.

Hazardous Decomposition

Products

Aldehydes. Phenol. Hydrogen cyanide. Ammonia. Hydrocarbons. Carbon monoxide

and carbon dioxide. Toxic fumes.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause allergic respiratory reaction. May cause respiratory irritation.

Skin Contact May cause an allergic skin reaction. May be absorbed through the skin and

contribute to the symptoms listed under ingestion. May cause skin irritation.

Eye Contact May cause eye irritation.

Ingestion Irritation of the mouth, throat, and stomach. May cause abdominal pain, vomiting,

nausea, and diarrhea.

Aggravated Medical Conditions Skin disorders.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

CCA-H2S

Page 3 of 6

HESI100262
Oral Toxicity: LD50: 9200 mg/kg (Rat)

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: TLM96: 49800 mg/l (Pimephales promelas)

Acute Crustaceans Toxicity:TLM48: 3600 mg/l (Daphnia magna)

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

UN1328,Hexamethylenetetramine, 4.1, III

NAERG 133

Canadian TDG

Hexamethylenetetramine, 4.1, UN1328, III

ADR

UN1328,Hexamethylenetetramine, 4.1, III

Air Transportation

CCA-H2S

Page 4 of 6

HESI100263
ICAO/IATA

UN1328,Hexamethylenetetramine, 4.1, III

Sea Transportation

IMDG

UN1328,Hexamethylenetetramine, 4.1, III

EmS F-A, S-G

Other Shipping Information

Labels: Flammable Solid

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Ignitability D001

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law Does not apply.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law Does not apply.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class B4 Flammable Solids

D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

CCA-H2S

Page 5 of 6

HESI100264
Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

CCA-H2S

Page 6 of 6

HESI100265
HESI100266
HESI100267
HESI100268
HESI100269
HESI100270
HESI100271
HESI100272
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: CERAMAX V

Revision Date: 03-Jan-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: CERAMAX V

Synonyms: None

Chemical Family: Resin coated ceramic

Application: Proppant

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Mullite 1302-93-8 30 - 60% 5 mg/m3 (R) 15 mg/m3

 (T)

Mineral 30 - 60% 10 mg/m3 15 mg/m3

 (T)

More restrictive exposure limits may be enforced by some states, agencies, or other authorities.

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye and respiratory irritation.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

CERAMAX V

Page 1 of 5

HESI100273
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media All standard firefighting media.

Special Exposure Hazards Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 0, Reactivity 0

HMIS Ratings: Flammability 0, Reactivity 0, Health 1

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing.

Storage Information Store in a cool, dry location. Use good housekeeping in storage and work areas to

prevent accumulation of dust. Close container when not in use. Store away from

direct sunlight.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Not normally needed. But if significant exposures are possible then the following

respirator is recommended:

Dust/mist respirator. (95%)

Hand Protection Normal work gloves.

Skin Protection Normal work coveralls.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions None known.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid

Color: Brown to Gray

Odor: Odorless

CERAMAX V

Page 2 of 5

HESI100274
9. PHYSICAL AND CHEMICAL PROPERTIES

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 3.0-3.2

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Insoluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide. Aldehydes. Phenol. Hydrogen cyanide.

Ammonia. Benzo(A)pyrene. Other organic materials.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause irritation (upper respiratory) which includes soreness of the nose and

throat, coughing and sneezing.

Skin Contact May cause skin irritation. May cause a rash and itching of the skin.

Eye Contact May cause eye irritation.

Ingestion None known

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

CERAMAX V

Page 3 of 5

HESI100275
Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Not restricted

Canadian TDG

Not restricted

ADR Not restricted

Air Transportation

ICAO/IATA Not restricted

Sea Transportation

IMDG Not restricted

Other Shipping Information

CERAMAX V

Page 4 of 5

HESI100276
Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class Un-Controlled

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

CERAMAX V

Page 5 of 5

HESI100277
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: CERAMIC PROP

Revision Date: 03-Jan-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: CERAMIC PROP

Synonyms: None

Chemical Family: Mineral

Application: Proppant

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Crystalline silica, cristobalite 14464-46-1 10 - 30% 0.025 mg/m3 1/2 x 10 mg/m3

 %SiO2 + 2

Aluminum silicate 1302-76-7 60 - 100% Not applicable 15 mg/m3

More restrictive exposure limits may be enforced by some states, agencies, or other authorities.

3. HAZARDS IDENTIFICATION

Hazard Overview CAUTION! - ACUTE HEALTH HAZARD

May cause eye and respiratory irritation.

DANGER! - CHRONIC HEALTH HAZARD

Breathing crystalline silica can cause lung disease, including silicosis and lung

cancer. Crystalline silica has also been associated with scleroderma and kidney

disease.

This product contains quartz, cristobalite, and/or tridymite which may become

airborne without a visible cloud. Avoid breathing dust. Avoid creating dusty

conditions. Use only with adequate ventilation to keep exposures below

recommended exposure limits. Wear a NIOSH certified, European Standard EN

149, or equivalent respirator when using this product. Review the Material Safety

Data Sheet (MSDS) for this product, which has been provided to your employer.

CERAMIC PROP

Page 1 of 6

HESI100278
4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Get medical attention if irritation persists.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Under normal conditions, first aid procedures are not required.

Notes to Physician Not Applicable

5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media All standard firefighting media.

Special Exposure Hazards Not applicable.

Special Protective Equipment for

Fire-Fighters

Not applicable.

NFPA Ratings: Health 0, Flammability 0, Reactivity 0

HMIS Ratings: Flammability 0, Reactivity 0, Health 0*

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

None known.

Procedure for Cleaning /

Absorption

Collect using dustless method and hold for appropriate disposal. Consider possible

toxic or fire hazards associated with contaminating substances and use appropriate

methods for collection, storage and disposal.

7. HANDLING AND STORAGE

Handling Precautions Not Determined

Storage Information Use good housekeeping in storage and work areas to prevent accumulation of dust.

Close container when not in use.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use approved industrial ventilation and local exhaust as required to maintain

exposures below applicable exposure limits listed in Section 2.

CERAMIC PROP

Page 2 of 6

HESI100279
Respiratory Protection Wear a NIOSH certified, European Standard EN 149, or equivalent respirator when

using this product.

Hand Protection Normal work gloves.

Skin Protection Wear clothing appropriate for the work environment. Dusty clothing should be

laundered before reuse. Use precautionary measures to avoid creating dust when

removing or laundering clothing.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions None known.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid

Color: Gray to tan

Odor: Odorless

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 3.1

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): 114

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Insoluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Hydrofluoric acid.

Hazardous Decomposition

Products

Amorphous silica may transform at elevated temperatures to tridymite (870 C) or

cristobalite (1470 C).

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

CERAMIC PROP

Page 3 of 6

HESI100280
Inhalation Inhaled crystalline silica in the form of quartz or cristobalite from occupational

sources is carcinogenic to humans (IARC, Group 1). There is sufficient evidence in

experimental animals for the carcinogenicity of tridymite (IARC, Group 2A).

Breathing silica dust may cause irritation of the nose, throat, and respiratory

passages. Breathing silica dust may not cause noticeable injury or illness even

though permanent lung damage may be occurring. Inhalation of dust may also have

serious chronic health effects (See "Chronic Effects/Carcinogenicity" subsection

below).

Skin Contact None known.

Eye Contact May cause eye irritation.

Ingestion None known

Aggravated Medical Conditions Individuals with respiratory disease, including but not limited to asthma and

bronchitis, or subject to eye irritation, should not be exposed to quartz dust.

Chronic Effects/Carcinogenicity Silicosis: Excessive inhalation of respirable crystalline silica dust may cause a

progressive, disabling, and sometimes-fatal lung disease called silicosis. Symptoms

include cough, shortness of breath, wheezing, non-specific chest illness, and

reduced pulmonary function. This disease is exacerbated by smoking. Individuals

with silicosis are predisposed to develop tuberculosis.

Cancer Status: The International Agency for Research on Cancer (IARC) has

determined that crystalline silica inhaled in the form of quartz or cristobalite from

occupational sources can cause lung cancer in humans (Group 1 - carcinogenic to

humans) and has determined that there is sufficient evidence in experimental

animals for the carcinogenicity of tridymite (Group 2A - possible carcinogen to

humans). Refer to IARC Monograph 68, Silica, Some Silicates and Organic Fibres

(June 1997) in conjunction with the use of these minerals. The National Toxicology

Program classifies respirable crystalline silica as "Known to be a human carcinogen".

Refer to the 9th Report on Carcinogens (2000). The American Conference of

Governmental Industrial Hygienists (ACGIH) classifies crystalline silica, quartz, as a

suspected human carcinogen (A2).

There is some evidence that breathing respirable crystalline silica or the disease

silicosis is associated with an increased incidence of significant disease endpoints

such as scleroderma (an immune system disorder manifested by scarring of the

lungs, skin, and other internal organs) and kidney disease.

Other Information For further information consult "Adverse Effects of Crystalline Silica Exposure"

published by the American Thoracic Society Medical Section of the American Lung

Association, American Journal of Respiratory and Critical Care Medicine, Volume

155, pages 761-768 (1997).

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Refer to IARC Monograph 68, Silica, Some Silicates and Organic Fibres (June

1997).

CERAMIC PROP

Page 4 of 6

HESI100281
Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not applicable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Not restricted

Canadian TDG

Not restricted

ADR Not restricted

Air Transportation

ICAO/IATA Not restricted

Sea Transportation

IMDG Not restricted

Other Shipping Information

Labels: None

CERAMIC PROP

Page 5 of 6

HESI100282
15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 The California Proposition 65 regulations apply to this product.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class D2A Very Toxic Materials

Crystalline silica

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

CERAMIC PROP

Page 6 of 6

HESI100283
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: CERAMIC PROP PLUS

Revision Date: 03-Jan-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: CERAMIC PROP PLUS

Synonyms: None

Chemical Family: Silicate

Application: Proppant

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Aluminum silicate 1302-76-7 30-70 Not applicable 15 mg/m3

Crystalline silica, cristobalite 14464-46-1 <1 0.025 mg/m3 1/2 x 10 mg/m3

 %SiO2 + 2

Phenol / formaldehyde resin 9003-35-4 1 - 5% Not applicable Not applicable

More restrictive exposure limits may be enforced by some states, agencies, or other authorities.

3. HAZARDS IDENTIFICATION

Hazard Overview CAUTION! - ACUTE HEALTH HAZARD

May cause eye and respiratory irritation. May cause allergic skin and respiratory

reaction.

DANGER! - CHRONIC HEALTH HAZARD

Breathing crystalline silica can cause lung disease, including silicosis and lung

cancer. Crystalline silica has also been associated with scleroderma and kidney

disease.

This product contains quartz, cristobalite, and/or tridymite which may become

airborne without a visible cloud. Avoid breathing dust. Avoid creating dusty

conditions. Use only with adequate ventilation to keep exposures below

recommended exposure limits. Wear a NIOSH certified, European Standard EN

149, or equivalent respirator when using this product. Review the Material Safety

Data Sheet (MSDS) for this product, which has been provided to your employer.

CERAMIC PROP PLUS

Page 1 of 7

HESI100284
4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Get medical attention if irritation persists.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media All standard firefighting media.

Special Exposure Hazards Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 0, Reactivity 0

HMIS Ratings: Health 1*, Flammability 0, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Collect using dustless method and hold for appropriate disposal. Consider possible

toxic or fire hazards associated with contaminating substances and use appropriate

methods for collection, storage and disposal.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. This product contains quartz, cristobalite,

and/or tridymite which may become airborne without a visible cloud. Avoid breathing

dust. Avoid creating dusty conditions. Use only with adequate ventilation to keep

exposure below recommended exposure limits. Wear a NIOSH certified, European

Standard En 149, or equivalent respirator when using this product. Material is

slippery when wet.

Storage Information Store in a cool, dry location. Use good housekeeping in storage and work areas to

prevent accumulation of dust. Close container when not in use.

CERAMIC PROP PLUS

Page 2 of 7

HESI100285
8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use approved industrial ventilation and local exhaust as required to maintain

exposures below applicable exposure limits listed in Section 2.

Respiratory Protection Wear a NIOSH certified, European Standard EN 149, or equivalent respirator when

using this product.

Hand Protection Normal work gloves.

Skin Protection Wear clothing appropriate for the work environment. Dusty clothing should be

laundered before reuse. Use precautionary measures to avoid creating dust when

removing or laundering clothing.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid

Color: Cream to light gray

Odor: Phenolic

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 2.60-3.70

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): 95

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Insoluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Hydrofluoric acid.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide. Aldehydes. Phenol. Hydrogen cyanide.

Ammonia. Benzo(A)pyrene. Other organic materials. Amorphous silica may

transform at elevated temperatures to tridymite (870 C) or cristobalite (1470 C).

Additional Guidelines Not Applicable

CERAMIC PROP PLUS

Page 3 of 7

HESI100286
11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause allergic respiratory reaction. Inhaled crystalline silica in the form of quartz

or cristobalite from occupational sources is carcinogenic to humans (IARC, Group 1).

There is sufficient evidence in experimental animals for the carcinogenicity of

tridymite (IARC, Group 2A).

Breathing silica dust may cause irritation of the nose, throat, and respiratory

passages. Breathing silica dust may not cause noticeable injury or illness even

though permanent lung damage may be occurring. Inhalation of dust may also have

serious chronic health effects (See "Chronic Effects/Carcinogenicity" subsection

below).

Skin Contact May cause skin irritation. May cause a rash and itching of the skin.

Eye Contact May cause eye irritation.

Ingestion None known

Aggravated Medical Conditions Individuals with respiratory disease, including but not limited to asthma and

bronchitis, or subject to eye irritation, should not be exposed to quartz dust.

Chronic Effects/Carcinogenicity Silicosis: Excessive inhalation of respirable crystalline silica dust may cause a

progressive, disabling, and sometimes-fatal lung disease called silicosis. Symptoms

include cough, shortness of breath, wheezing, non-specific chest illness, and

reduced pulmonary function. This disease is exacerbated by smoking. Individuals

with silicosis are predisposed to develop tuberculosis.

Cancer Status: The International Agency for Research on Cancer (IARC) has

determined that crystalline silica inhaled in the form of quartz or cristobalite from

occupational sources can cause lung cancer in humans (Group 1 - carcinogenic to

humans) and has determined that there is sufficient evidence in experimental

animals for the carcinogenicity of tridymite (Group 2A - possible carcinogen to

humans). Refer to IARC Monograph 68, Silica, Some Silicates and Organic Fibres

(June 1997) in conjunction with the use of these minerals. The National Toxicology

Program classifies respirable crystalline silica as "Known to be a human carcinogen".

Refer to the 9th Report on Carcinogens (2000). The American Conference of

Governmental Industrial Hygienists (ACGIH) classifies crystalline silica, quartz, as a

suspected human carcinogen (A2).

There is some evidence that breathing respirable crystalline silica or the disease

silicosis is associated with an increased incidence of significant disease endpoints

such as scleroderma (an immune system disorder manifested by scarring of the

lungs, skin, and other internal organs) and kidney disease.

Other Information For further information consult "Adverse Effects of Crystalline Silica Exposure"

published by the American Thoracic Society Medical Section of the American Lung

Association, American Journal of Respiratory and Critical Care Medicine, Volume

155, pages 761-768 (1997).

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

CERAMIC PROP PLUS

Page 4 of 7

HESI100287
Primary Irritation Effect: Not determined

Carcinogenicity Refer to IARC Monograph 68, Silica, Some Silicates and Organic Fibres (June

1997).

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not applicable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Not restricted

Canadian TDG

Not restricted

ADR Not restricted

Air Transportation

ICAO/IATA Not restricted

Sea Transportation

IMDG Not restricted

Other Shipping Information

CERAMIC PROP PLUS

Page 5 of 7

HESI100288
Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 The California Proposition 65 regulations apply to this product.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory Product contains one or more components not listed on inventory.

WHMIS Hazard Class D2A Very Toxic Materials

Crystalline silica

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

CERAMIC PROP PLUS

Page 6 of 7

HESI100289
CERAMIC PROP PLUS

Page 7 of 7

HESI100290
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: CL-18 CROSSLINKER

Revision Date: 03-Jan-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: CL-18 CROSSLINKER

Synonyms: None

Chemical Family: Blend

Application: Crosslinker

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Organic titanate 10 - 30% Not applicable Not applicable

Isopropanol 67-63-0 5 - 10% 200 ppm 400 ppm

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause headache, dizziness, and

other central nervous system effects. May be harmful if swallowed. May be absorbed

through the skin. May cause allergic skin reaction. Repeated overexposure may

cause liver and kidney effects. Flammable.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

CL-18 CROSSLINKER

Page 1 of 6

HESI100291
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 81

Flash Point/Range (C): 27

Flash Point Method: TCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): 2

Flammability Limits in Air - Upper (%): 12.7

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards May be ignited by heat, sparks or flames. Use water spray to cool fire exposed

surfaces. Closed containers may explode in fire. Decomposition in fire may produce

toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 3, Flammability 3, Reactivity 1

HMIS Ratings: Flammability 3, Reactivity 1, Health 3

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Wear self-contained breathing apparatus in

enclosed areas.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Remove ignition sources and work with nonsparking tools. Contain spill with sand or other inert materials. Scoop up and

remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse. Ground and bond containers

when transferring from one container to another.

Storage Information Store away from oxidizers. Store in a cool well ventilated area. Keep from heat,

sparks, and open flames. Keep container closed when not in use. Product has a

shelf life of 24 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Organic vapor respirator.

In high concentrations, supplied air respirator or a self-contained breathing

apparatus.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

CL-18 CROSSLINKER

Page 2 of 6

HESI100292
Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Cream to light yellow

Odor: Alcohol

pH: 8

Specific Gravity @ 20 C (Water=1): 1.12

Density @ 20 C (lbs./gallon): 9.33

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Miscible

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Oxides of nitrogen. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation Causes severe respiratory irritation. May cause central nervous system depression

including headache, dizziness, drowsiness, incoordination, slowed reaction time,

slurred speech, giddiness and unconsciousness.

Skin Contact May cause skin irritation. May be absorbed through the skin and produce effects

similar to those caused by inhalation and/or ingestion. May cause an allergic skin

reaction.

Eye Contact May cause severe eye irritation.

CL-18 CROSSLINKER

Page 3 of 6

HESI100293
Ingestion Irritation of the mouth, throat, and stomach. May cause abdominal pain, vomiting,

nausea, and diarrhea. May cause central nervous system depression including

headache, dizziness, drowsiness, muscular weakness, incoordination, slowed

reaction time, fatigue blurred vision, slurred speech, giddiness, tremors and

convulsions.

Aggravated Medical Conditions Skin disorders.

Chronic Effects/Carcinogenicity Repeated overexposure may cause liver and kidney effects.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Slowly biodegradable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Flammable Liquid, N.O.S., 3, UN1993, III, (27 C)

CL-18 CROSSLINKER

Page 4 of 6

HESI100294
(Contains Isopropanol)

NAERG 128

Canadian TDG

Flammable Liquid, N.O.S.(Contains Isopropanol), 3, UN1993, III, (27 C)

ADR

UN1993,Flammable Liquid, N.O.S.(Contains Isopropanol), 3, III

Air Transportation

ICAO/IATA

UN1993,Flammable Liquid, N.O.S., 3, III

(Contains Isopropanol Solution)

Sea Transportation

IMDG

UN1993,Flammable Liquid, N.O.S.(Contains Isopropanol), 3, III, (27 C)

EmS F-E, S-E

Other Shipping Information

Labels: Flammable Liquid

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Isopropanol//67-63-0

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Ignitability D001

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

CL-18 CROSSLINKER

Page 5 of 6

HESI100295
Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class B2 Flammable Liquids

D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

CL-18 CROSSLINKER

Page 6 of 6

HESI100296
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: CL-22 UC

Revision Date: 05-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: CL-22 UC

Synonyms: None

Chemical Family: Blend

Application: Crosslinker

Manufacturer/Supplier Halliburton Energy Services, Inc.

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Potassium formate 590-29-4 30 - 60% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

CL-22 UC

Page 1 of 6

HESI100297
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media All standard firefighting media.

Special Exposure Hazards Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 0, Reactivity 0

HMIS Ratings: Health 1, Flammability 0, Physical Hazard 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Material is slippery underfoot.

Storage Information Store in a cool well ventilated area. Keep container closed when not in use.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Local exhaust ventilation should be used in areas without good cross ventilation.

Respiratory Protection If engineering controls and work practices cannot keep exposure below occupational

exposure limits or if exposure is unknown, wear a NIOSH certified, European

Standard EN 149, or equivalent respirator when using this product. Selection of and

instruction on using all personal protective equipment, including respirators, should

be performed by an Industrial Hygienist or other qualified professional.

Not normally needed. But if significant exposures are possible then the following

respirator is recommended:

Dust/mist respirator. (95%)

Hand Protection Neoprene gloves. Rubber gloves. Vinyl gloves.

Skin Protection Rubber apron.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions Eyewash fountains and safety showers must be easily accessible. Rubber boots

CL-22 UC

Page 2 of 6

HESI100298
9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Tan

Odor: Slight

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 1.41

Density @ 20 C (lbs./gallon): 11.75

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not DeterminedMin: > 212

Boiling Point/Range (C): Not DeterminedMin: > 100

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Slightly soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None known.

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye and skin contact.

Inhalation May cause respiratory irritation.

Skin Contact Prolonged or repeated contact may cause skin irritation.

Eye Contact May cause eye irritation.

Ingestion Irritation of the mouth, throat, and stomach. Large doses may cause nausea,

vomiting and diarrhea.

Aggravated Medical Conditions Skin disorders.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

CL-22 UC

Page 3 of 6

HESI100299
Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

CL-22 UC

Page 4 of 6

HESI100300
ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 The California Proposition 65 regulations apply to this product.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class Un-Controlled

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

CL-22 UC

Page 5 of 6

HESI100301
Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

CL-22 UC

Page 6 of 6

HESI100302
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: CL-22M CROSSLINKER

Revision Date: 05-Jan-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: CL-22M CROSSLINKER

Synonyms: None

Chemical Family: Blend

Application: Crosslinker

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Ulexite 1319-33-1 30 - 60% Not applicable Not applicable

Diesel 68476-34-6 30 - 60% 100 mg/m3 Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause headache, dizziness, and

other central nervous system effects. May be harmful if swallowed. Combustible.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Get medical attention! If vomiting occurs, keep head lower than hips to prevent

aspiration.

Notes to Physician Not Applicable

CL-22M CROSSLINKER

Page 1 of 6

HESI100303
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 148

Flash Point/Range (C): 64

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Use water spray to cool fire exposed surfaces. Closed containers may explode in

fire. Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 2, Reactivity 0

HMIS Ratings: Health 2, Flammability 2, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Wear self-contained breathing apparatus in

enclosed areas.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse.

Storage Information Store away from oxidizers. Keep from heat, sparks, and open flames. Keep container

closed when not in use. Product has a shelf life of 6 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Organic vapor respirator with a dust/mist filter.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Brown

CL-22M CROSSLINKER

Page 2 of 6

HESI100304
9. PHYSICAL AND CHEMICAL PROPERTIES

Odor: Diesel

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 1.15

Density @ 20 C (lbs./gallon): 9.6

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: 48.00

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Insoluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Oxides of nitrogen. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. May cause central nervous system depression

including headache, dizziness, drowsiness, incoordination, slowed reaction time,

slurred speech, giddiness and unconsciousness.

Skin Contact May cause skin irritation.

Eye Contact May cause eye irritation.

Ingestion Aspiration into the lungs may cause chemical pneumonitis including coughing,

difficulty breathing, wheezing, coughing up blood and pneumonia, which can be fatal.

Aggravated Medical Conditions Skin disorders.

Chronic Effects/Carcinogenicity Contains petroleum distillates which have been shown to cause skin cancer in

laboratory animals.

Other Information None known.

Toxicity Tests

CL-22M CROSSLINKER

Page 3 of 6

HESI100305
Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Not restricted

DOT (Bulk)

Diesel Fuel Solution, Combustible Liquid, NA1993, III

Canadian TDG

Not restricted

ADR Not restricted

Air Transportation

ICAO/IATA Not restricted

CL-22M CROSSLINKER

Page 4 of 6

HESI100306
Sea Transportation

IMDG Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class B3 Combustible Liquids

D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

CL-22M CROSSLINKER

Page 5 of 6

HESI100307
Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

CL-22M CROSSLINKER

Page 6 of 6

HESI100308
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: CL-23 CROSSLINKER

Revision Date: 03-Jan-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: CL-23 CROSSLINKER

Synonyms: None

Chemical Family: Blend

Application: Crosslinker

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Ammonium chloride 12125-02-9 1-27 10 mg/m3 10 mg/m3

Zirconium complex 30 - 60% 5 mg/m3 Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May be harmful if swallowed.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

CL-23 CROSSLINKER

Page 1 of 5

HESI100309
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): > 200

Flash Point/Range (C): > 93

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 0, Reactivity 0

HMIS Ratings: Flammability 0, Reactivity 0, Health 2

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid breathing mist. Wash hands after use. Launder contaminated clothing before

reuse. Avoid contact with eyes, skin, or clothing.

Storage Information Store away from alkalis. Store in a cool well ventilated area. Keep container closed

when not in use. Store away from oxidizers.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Not normally necessary.

However, if significant exposures are likely then wear a Ammonia respirator with a

dust/mist filter.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Clear

CL-23 CROSSLINKER

Page 2 of 5

HESI100310
9. PHYSICAL AND CHEMICAL PROPERTIES

Odor: Mild sweet-sour

pH: 7

Specific Gravity @ 20 C (Water=1): 1.178

Density @ 20 C (lbs./gallon): 9.81

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 216

Boiling Point/Range (C): 102

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Miscible

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong alkalis. Strong oxidizers. Contact with metals. Avoid halogens.

Hazardous Decomposition

Products

Oxides of nitrogen. Ammonia. Chlorides.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation.

Skin Contact May cause skin irritation.

Eye Contact Concentrations greater than ten percent: Causes eye irritation.

Ingestion Causes burns of the mouth, throat and stomach. May cause metabolic acidosis.

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

CL-23 CROSSLINKER

Page 3 of 5

HESI100311
Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Not restricted

Canadian TDG

Not restricted

ADR Not restricted

Air Transportation

ICAO/IATA Not restricted

Sea Transportation

IMDG Not restricted

Other Shipping Information

CL-23 CROSSLINKER

Page 4 of 5

HESI100312
Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Ammonium Chloride//12125-02-9

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 5649 Gallons based on Ammonium chloride (CAS:

12125-02-9).

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class Un-Controlled

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

CL-23 CROSSLINKER

Page 5 of 5

HESI100313
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: CL-24 CROSSLINKER

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: CL-24 CROSSLINKER

Synonyms: None

Chemical Family: Blend

Application: Crosslinker

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Zirconium complex 60 - 100% 5 mg/m3 5 mg/m3

Propanol 71-23-8 10 - 30% 100 ppm 200 ppm

Glycerine 56-81-5 10 - 30% 10 mg/m3 15 mg/m3

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause headache, dizziness, and

other central nervous system effects. May be harmful if swallowed. May be absorbed

through the skin. May cause allergic skin reaction. Repeated overexposure may

cause liver and kidney effects. Flammable.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Activated charcoal or gastric lavage may be advisable for significant ingestion.

CL-24 CROSSLINKER

Page 1 of 6

HESI100314
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 84

Flash Point/Range (C): 28

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards May be ignited by heat, sparks or flames. Fight fire from a safe distance and from a

protected location. Use water spray to cool fire exposed surfaces. Closed containers

may explode in fire. Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 3, Reactivity 0

HMIS Ratings: Health 2, Flammability 3, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Remove ignition sources and work with nonsparking tools. Contain spill with sand or other inert materials. Scoop up and

remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse. Ground and bond containers

when transferring from one container to another.

Storage Information Store away from oxidizers. Store away from acids. Keep from heat, sparks, and open

flames. Keep container closed when not in use. Product has a shelf life of 12 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Organic vapor respirator.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

CL-24 CROSSLINKER

Page 2 of 6

HESI100315
9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Yellow

Odor: Alcohol

pH: 7-9

Specific Gravity @ 20 C (Water=1): 1.091

Density @ 20 C (lbs./gallon): 9.09

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 210

Boiling Point/Range (C): 98

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers. Strong acids.

Hazardous Decomposition

Products

Ammonia. Amines. Olefins. Oxides of nitrogen. Other organic materials. Carbon

monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. May cause central nervous system depression

including headache, dizziness, drowsiness, incoordination, slowed reaction time,

slurred speech, giddiness and unconsciousness.

Skin Contact May be absorbed through the skin and produce effects similar to those caused by

inhalation and/or ingestion. May cause an allergic skin reaction. May cause skin

irritation.

Eye Contact May cause moderate eye irritation.

Ingestion May be harmful if swallowed. May cause abdominal pain, vomiting, nausea, and

diarrhea. May cause central nervous system depression including headache,

dizziness, drowsiness, muscular weakness, incoordination, slowed reaction time,

fatigue blurred vision, slurred speech, giddiness, tremors and convulsions.

CL-24 CROSSLINKER

Page 3 of 6

HESI100316
Aggravated Medical Conditions Skin disorders. Lung disorders. Liver and kidney disorders.

Chronic Effects/Carcinogenicity Repeated overexposure may cause liver and kidney effects.

Other Information None known.

Toxicity Tests

Oral Toxicity: LD50: > 11,000 mg/kg (Rat)

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: TLM96: > 10000 mg/l (Pimephales promelas)

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

UN1274,n-Propanol Solution, 3, III, (28.9 C)

NAERG 129

Canadian TDG

n-Propanol Solution, 3, UN1274, III, (28.9 C)

CL-24 CROSSLINKER

Page 4 of 6

HESI100317
ADR

UN1274,n-Propanol Solution, 3, III

Air Transportation

ICAO/IATA

UN1274,n-Propanol Solution, 3, III

Sea Transportation

IMDG

UN1274,n-Propanol Solution, 3, III, (28.9 C)

EmS F-E, S-D

Other Shipping Information

Labels: Flammable Liquid

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Ignitability D001

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

CL-24 CROSSLINKER

Page 5 of 6

HESI100318
WHMIS Hazard Class B2 Flammable Liquids

D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

CL-24 CROSSLINKER

Page 6 of 6

HESI100319
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: CL-28M CROSSLINKER

Revision Date: 05-Jan-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: CL-28M CROSSLINKER

Synonyms: None

Chemical Family: Mineral

Application: Crosslinker

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Borate salts 30 - 60% Not applicable Not applicable

Crystalline silica, quartz 14808-60-7 1 - 5% 0.025 mg/m3 10 mg/m3

%SiO2 + 2

3. HAZARDS IDENTIFICATION

Hazard Overview CAUTION! - ACUTE HEALTH HAZARD

May cause eye irritation.

DANGER! - CHRONIC HEALTH HAZARD

Breathing crystalline silica can cause lung disease, including silicosis and lung

cancer. Crystalline silica has also been associated with scleroderma and kidney

disease.

This product contains quartz, cristobalite, and/or tridymite which may become

airborne without a visible cloud. Avoid breathing dust. Avoid creating dusty

conditions. Use only with adequate ventilation to keep exposures below

recommended exposure limits. Wear a NIOSH certified, European Standard EN

149, or equivalent respirator when using this product. Review the Material Safety

Data Sheet (MSDS) for this product, which has been provided to your employer.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

CL-28M CROSSLINKER

Page 1 of 6

HESI100320
Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media All standard firefighting media.

Special Exposure Hazards Not applicable.

Special Protective Equipment for

Fire-Fighters

Not applicable.

NFPA Ratings: Health 1, Flammability 0, Reactivity 0

HMIS Ratings: Health 1*, Flammability 0, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

None known.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions This product contains quartz, cristobalite, and/or tridymite which may become

airborne without a visible cloud. Avoid breathing dust. Avoid creating dusty

conditions. Use only with adequate ventilation to keep exposure below

recommended exposure limits. Wear a NIOSH certified, European Standard En 149,

or equivalent respirator when using this product. Material is slippery when wet.

Storage Information Keep container closed when not in use. Product has a shelf life of 24 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use approved industrial ventilation and local exhaust as required to maintain

exposures below applicable exposure limits listed in Section 2.

Respiratory Protection Wear a NIOSH certified, European Standard EN 149, or equivalent respirator when

using this product.

CL-28M CROSSLINKER

Page 2 of 6

HESI100321
Hand Protection Normal work gloves.

Skin Protection Wear clothing appropriate for the work environment. Dusty clothing should be

laundered before reuse. Use precautionary measures to avoid creating dust when

removing or laundering clothing.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions None known.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Gray to tan

Odor: Odorless

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 1.26

Density @ 20 C (lbs./gallon): 10.5

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 212

Boiling Point/Range (C): 100

Freezing Point/Range (F): 32

Freezing Point/Range (C): 0

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Insoluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Hydrofluoric acid.

Hazardous Decomposition

Products

Amorphous silica may transform at elevated temperatures to tridymite (870 C) or

cristobalite (1470 C).

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

CL-28M CROSSLINKER

Page 3 of 6

HESI100322
Inhalation Inhaled crystalline silica in the form of quartz or cristobalite from occupational

sources is carcinogenic to humans (IARC, Group 1). There is sufficient evidence in

experimental animals for the carcinogenicity of tridymite (IARC, Group 2A).

Breathing silica dust may cause irritation of the nose, throat, and respiratory

passages. Breathing silica dust may not cause noticeable injury or illness even

though permanent lung damage may be occurring. Inhalation of dust may also have

serious chronic health effects (See "Chronic Effects/Carcinogenicity" subsection

below).

Skin Contact May cause mild skin irritation.

Eye Contact May cause eye irritation.

Ingestion May cause abdominal pain, vomiting, nausea, and diarrhea.

Aggravated Medical Conditions Individuals with respiratory disease, including but not limited to asthma and

bronchitis, or subject to eye irritation, should not be exposed to quartz dust.

Chronic Effects/Carcinogenicity Silicosis: Excessive inhalation of respirable crystalline silica dust may cause a

progressive, disabling, and sometimes-fatal lung disease called silicosis. Symptoms

include cough, shortness of breath, wheezing, non-specific chest illness, and

reduced pulmonary function. This disease is exacerbated by smoking. Individuals

with silicosis are predisposed to develop tuberculosis.

Cancer Status: The International Agency for Research on Cancer (IARC) has

determined that crystalline silica inhaled in the form of quartz or cristobalite from

occupational sources can cause lung cancer in humans (Group 1 - carcinogenic to

humans) and has determined that there is sufficient evidence in experimental

animals for the carcinogenicity of tridymite (Group 2A - possible carcinogen to

humans). Refer to IARC Monograph 68, Silica, Some Silicates and Organic Fibres

(June 1997) in conjunction with the use of these minerals. The National Toxicology

Program classifies respirable crystalline silica as "Known to be a human carcinogen".

Refer to the 9th Report on Carcinogens (2000). The American Conference of

Governmental Industrial Hygienists (ACGIH) classifies crystalline silica, quartz, as a

suspected human carcinogen (A2).

There is some evidence that breathing respirable crystalline silica or the disease

silicosis is associated with an increased incidence of significant disease endpoints

such as scleroderma (an immune system disorder manifested by scarring of the

lungs, skin, and other internal organs) and kidney disease.

Other Information For further information consult "Adverse Effects of Crystalline Silica Exposure"

published by the American Thoracic Society Medical Section of the American Lung

Association, American Journal of Respiratory and Critical Care Medicine, Volume

155, pages 761-768 (1997).

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

CL-28M CROSSLINKER

Page 4 of 6

HESI100323
Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Not restricted

Canadian TDG

Not restricted

ADR Not restricted

Air Transportation

ICAO/IATA Not restricted

Sea Transportation

IMDG Not restricted

Other Shipping Information

Labels: None

CL-28M CROSSLINKER

Page 5 of 6

HESI100324
15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 The California Proposition 65 regulations apply to this product.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory Product contains one or more components not listed on inventory.

WHMIS Hazard Class D2A Very Toxic Materials

Crystalline silica

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

CL-28M CROSSLINKER

Page 6 of 6

HESI100325
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: CL-29 CROSSLINKER

Revision Date: 14-Jul-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: CL-29 CROSSLINKER

Synonyms: None

Chemical Family: Blend

Application: Crosslinker

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Tetraethylenepentamine 112-57-2 5 - 10% Not applicable Not applicable

Lactic acid 10326-41-7 5 - 10% Not applicable Not applicable

Zirconium complex 10 - 30% 5 mg/m3 5 mg/m3

Formic acid 64-18-6 10 - 30% 5 ppm 5 ppm

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory burns. May be harmful if swallowed. May cause

allergic skin reaction.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

CL-29 CROSSLINKER

Page 1 of 6

HESI100326
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not DeterminedMin: > 200

Flash Point/Range (C): Not DeterminedMin: > 93

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media All standard firefighting media.

Special Exposure Hazards Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 0, Reactivity 0

HMIS Ratings: Health 2, Flammability 0, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Neutralize to pH of 6-8. Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse.

Storage Information Store away from alkalis. Store away from oxidizers. Store in a cool well ventilated

area. Keep container closed when not in use. Product has a shelf life of 24 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Organic vapor/acid gas respirator.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Yellow-orange

Odor: Pungent

pH: 4.3

CL-29 CROSSLINKER

Page 2 of 6

HESI100327
9. PHYSICAL AND CHEMICAL PROPERTIES

Specific Gravity @ 20 C (Water=1): 1.18

Density @ 20 C (lbs./gallon): 9.83

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 242

Boiling Point/Range (C): 116

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): 0

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: May Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong alkalis. Strong oxidizers.

Hazardous Decomposition

Products

Oxides of nitrogen. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation Causes severe respiratory irritation. May cause lungs to fill with fluids.

Skin Contact Causes severe skin irritation. May cause skin burns. May cause an allergic skin

reaction.

Eye Contact May cause eye burns.

Ingestion Causes burns of the mouth, throat and stomach.

Aggravated Medical Conditions Skin disorders.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

CL-29 CROSSLINKER

Page 3 of 6

HESI100328
Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Corrosive Liquid, Acidic, Organic, N.O.S., 8, UN3265, III

(Contains Formic Acid, Tetraethylenepentamine)

NAERG 153

Canadian TDG

Corrosive Liquid, Acidic, Organic, N.O.S.(Contains Formic Acid, Tetraethylenepentamine), 8, UN3265, III

ADR

UN3265,Corrosive Liquid, Acidic, Organic, N.O.S.(Contains Formic Acid, Tetraethylenepentamine), 8, III

Air Transportation

ICAO/IATA

UN3265,Corrosive Liquid, Acidic, Organic, N.O.S., 8, III

(Contains Formic Acid, Tetraethylenepentamine Solution)

CL-29 CROSSLINKER

Page 4 of 6

HESI100329
Sea Transportation

IMDG

UN3265,Corrosive Liquid, Acidic, Organic, N.O.S.(Contains Formic Acid, Tetraethylenepentamine), 8, III

EmS F-A, S-B

Other Shipping Information

Labels: Corrosive

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Formic Acid//64-18-6

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 1797 Gallons based on Formic acid (CAS: 64-18-6).

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class E Corrosive Material

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

CL-29 CROSSLINKER

Page 5 of 6

HESI100330
Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

CL-29 CROSSLINKER

Page 6 of 6

HESI100331
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: CL-31 CROSSLINKER

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: CL-31 CROSSLINKER

Synonyms: None

Chemical Family: Blend

Application: Crosslinker

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Potassium metaborate 13709-94-9 30 - 60% Not applicable Not applicable

Potassium hydroxide 1310-58-3 < 5 2 mg/m3 Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory burns. May be harmful if swallowed.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician None known.

CL-31 CROSSLINKER

Page 1 of 6

HESI100332
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not DeterminedMin: > 200

Flash Point/Range (C): Not DeterminedMin: > 93

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Product should not burn, but precautions should be taken during a fire to avoid

corrosive hazard.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 3, Flammability 0, Reactivity 1

HMIS Ratings: Health 3, Flammability 1, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Neutralize to pH of 6-8. Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse.

Storage Information Store away from acids. Store away from oxidizers. Store in a well ventilated area.

Product has a shelf life of 24 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Dust/mist respirator. (95%)

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Clear

Odor: Characteristic

CL-31 CROSSLINKER

Page 2 of 6

HESI100333
9. PHYSICAL AND CHEMICAL PROPERTIES

pH: > 13.5

Specific Gravity @ 20 C (Water=1): 1.31

Density @ 20 C (lbs./gallon): 10.91

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): 5-10

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None known.

Incompatibility (Materials to

Avoid)

Strong oxidizers. Strong acids.

Hazardous Decomposition

Products

Boric acid. Potassium hydroxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation Causes severe respiratory irritation.

Skin Contact Causes severe skin irritation. May cause skin burns.

Eye Contact Causes severe eye irritation May cause eye burns.

Ingestion Irritation of the mouth, throat, and stomach. May cause abdominal pain, vomiting,

nausea, and diarrhea.

Aggravated Medical Conditions Skin disorders. Eye ailments.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: LD50: 3310 mg/kg (Rat)

Dermal Toxicity: Not determined

CL-31 CROSSLINKER

Page 3 of 6

HESI100334
Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

UN1814,Potassium Hydroxide Solution, 8, III

NAERG 154

Canadian TDG

Potassium Hydroxide Solution, 8, UN1814, III

ADR

UN1814,Potassium Hydroxide Solution, 8, III

Air Transportation

ICAO/IATA

UN1814,Potassium Hydroxide Solution, 8, III

CL-31 CROSSLINKER

Page 4 of 6

HESI100335
Sea Transportation

IMDG

UN1814,Potassium Hydroxide Solution, 8, III

EmS F-A, S-B

Other Shipping Information

Labels: Corrosive

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 3652 Gallons based on Potassium hydroxide (CAS:

1310-58-3).

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Corrosivity D002

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class E Corrosive Material

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

CL-31 CROSSLINKER

Page 5 of 6

HESI100336
Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

CL-31 CROSSLINKER

Page 6 of 6

HESI100337
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: CL-37 CROSSLINKER

Revision Date: 05-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: CL-37 CROSSLINKER

Synonyms: None

Chemical Family: Blend

Application: Crosslinker

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Triethanolamine zirconate 101033-44-7 60 - 100% 5 mg/m3 5 mg/m3

Propanol 71-23-8 10 - 30% 100 ppm 200 ppm

Glycerine 56-81-5 10 - 30% 10 mg/m3 15 mg/m3

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause headache, dizziness, and

other central nervous system effects. May be harmful if swallowed. May be absorbed

through the skin. May cause allergic skin reaction. Repeated overexposure may

cause liver and kidney effects. Flammable.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Activated charcoal or gastric lavage may be advisable for significant ingestion.

CL-37 CROSSLINKER

Page 1 of 6

HESI100338
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 84

Flash Point/Range (C): 28

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards May be ignited by heat, sparks or flames. Fight fire from a safe distance and from a

protected location. Use water spray to cool fire exposed surfaces. Closed containers

may explode in fire. Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 3, Reactivity 0

HMIS Ratings: Health 2, Flammability 3, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Remove ignition sources and work with nonsparking tools. Contain spill with sand or other inert materials. Scoop up and

remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse. Ground and bond containers

when transferring from one container to another.

Storage Information Store away from oxidizers. Store away from acids. Keep from heat, sparks, and open

flames. Keep container closed when not in use. Product has a shelf life of 12 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Organic vapor respirator.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

CL-37 CROSSLINKER

Page 2 of 6

HESI100339
9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Yellow

Odor: Alcohol

pH: 7-9

Specific Gravity @ 20 C (Water=1): 1.091

Density @ 20 C (lbs./gallon): 9.09

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 210

Boiling Point/Range (C): 98

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers. Strong acids.

Hazardous Decomposition

Products

Olefins. Oxides of nitrogen. Other organic materials. Carbon monoxide and carbon

dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. May cause central nervous system depression

including headache, dizziness, drowsiness, incoordination, slowed reaction time,

slurred speech, giddiness and unconsciousness.

Skin Contact May cause skin irritation. May be absorbed through the skin and produce effects

similar to those caused by inhalation and/or ingestion. May cause an allergic skin

reaction.

Eye Contact May cause moderate eye irritation.

Ingestion May be harmful if swallowed. May cause abdominal pain, vomiting, nausea, and

diarrhea. May cause central nervous system depression including headache,

dizziness, drowsiness, muscular weakness, incoordination, slowed reaction time,

fatigue blurred vision, slurred speech, giddiness, tremors and convulsions.

CL-37 CROSSLINKER

Page 3 of 6

HESI100340
Aggravated Medical Conditions Skin disorders. Lung disorders. Liver and kidney disorders.

Chronic Effects/Carcinogenicity Repeated overexposure may cause liver and kidney effects.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

UN1274,n-Propanol Solution, 3, III, (28.9 C)

NAERG 129

Canadian TDG

n-Propanol Solution, 3, UN1274, III, (28.9 C)

CL-37 CROSSLINKER

Page 4 of 6

HESI100341
ADR

UN1274,n-Propanol Solution, 3, III

Air Transportation

ICAO/IATA

UN1274,n-Propanol Solution, 3, III

Sea Transportation

IMDG

UN1274,n-Propanol Solution, 3, III, (28.9 C)

EmS F-E, S-D

Other Shipping Information

Labels: Flammable Liquid

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Ignitability D001

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

CL-37 CROSSLINKER

Page 5 of 6

HESI100342
WHMIS Hazard Class B2 Flammable Liquids

D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

CL-37 CROSSLINKER

Page 6 of 6

HESI100343
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: CL-38 CROSSLINKER

Revision Date: 03-Jan-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: CL-38 CROSSLINKER

Synonyms: None

Chemical Family: Blend

Application: Crosslinker

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Dipropylene glycol

monomethyl ether

34590-94-8 30 - 60% 100 ppm 100 ppm

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause headache, dizziness, and

other central nervous system effects. May be harmful if swallowed. Combustible.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Get medical attention! If vomiting occurs, keep head lower than hips to prevent

aspiration.

Notes to Physician Aspiration may cause severe lung damage. Evacuate stomach in a way which

avoids aspiration.

CL-38 CROSSLINKER

Page 1 of 6

HESI100344
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 185

Flash Point/Range (C): 85

Flash Point Method: TCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): 1.1

Flammability Limits in Air - Upper (%): 3

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Use water spray to cool fire exposed surfaces. Closed containers may explode in

fire. Decomposition in fire may produce toxic gases. Vapors are heavier than air and

may accumulate in low areas. Vapors may travel along the ground to be ignited at

distant locations.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 2, Reactivity 0

HMIS Ratings: Flammability 2, Reactivity 0, Health 1

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Evacuate all persons from the area. Use only

competent persons for cleanup.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse.

Storage Information Store away from oxidizers. Store in a cool well ventilated area. Product has a shelf

life of 6 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Organic vapor respirator.

In high concentrations, supplied air respirator or a self-contained breathing

apparatus.

Hand Protection Impervious rubber gloves.

Skin Protection Normal work coveralls.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

CL-38 CROSSLINKER

Page 2 of 6

HESI100345
9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Light gray

Odor: Ether

pH: 10

Specific Gravity @ 20 C (Water=1): 1.30

Density @ 20 C (lbs./gallon): 10.83

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 177Min: > 350

Boiling Point/Range (C): 350Min: > 177

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): 0.55

Vapor Density (Air=1): 5.1

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Disperses

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. May cause central nervous system depression

including headache, dizziness, drowsiness, incoordination, slowed reaction time,

slurred speech, giddiness and unconsciousness.

Skin Contact May cause skin irritation.

Eye Contact May cause eye irritation.

Ingestion Aspiration into the lungs may cause chemical pneumonitis including coughing,

difficulty breathing, wheezing, coughing up blood and pneumonia, which can be fatal.

Aggravated Medical Conditions Skin disorders.

Chronic Effects/Carcinogenicity May cause testicular toxicity.

CL-38 CROSSLINKER

Page 3 of 6

HESI100346
Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Not restricted

DOT (Bulk)

Combustible Liquid, N.O.S., Combustible Liquid, NA1993, III

(Contains Dipropylene Glycol Monomethyl Ether)

Canadian TDG

Not restricted

ADR Not restricted

CL-38 CROSSLINKER

Page 4 of 6

HESI100347
Air Transportation

ICAO/IATA Not restricted

Sea Transportation

IMDG Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Glycol Ethers//34590-94-8

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class B3 Combustible Liquids

D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

CL-38 CROSSLINKER

Page 5 of 6

HESI100348
Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

CL-38 CROSSLINKER

Page 6 of 6

HESI100349
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: CL-40TM CROSSLINKER

Revision Date: 03-Jan-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: CL-40TM CROSSLINKER

Synonyms: None

Chemical Family: Blend

Application: Crosslinker

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Triisopropanolamine 122-20-3 10 - 30% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye irritation.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin Get medical attention if irritation persists. Wash with soap and water.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion If swallowed, induce vomiting immediately by giving two glasses of water and sticking

fingers down throat; never give anything to an unconscious person. Get medical

attention.

Notes to Physician Not Applicable

CL-40TM CROSSLINKER

Page 1 of 5

HESI100350
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not DeterminedMin: > 200

Flash Point/Range (C): Not DeterminedMin: > 93

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media All standard firefighting media.

Special Exposure Hazards Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 0, Reactivity 0

HMIS Ratings: Flammability 0, Reactivity 0, Health 1

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Contain spill with sand or other inert materials. Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid creating or inhaling dust.

Storage Information Store away from oxidizers. Product has a shelf life of 24 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Not normally needed. But if significant exposures are possible then the following

respirator is recommended:

Organic vapor/acid gas respirator.

Hand Protection Nitrile gloves. Polyvinylchloride gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: to Light straw Clear

Odor: Slight Ammonia

pH: 8.5 - 9.5

Specific Gravity @ 20 C (Water=1): 1.14 - 1.24

CL-40TM CROSSLINKER

Page 2 of 5

HESI100351
9. PHYSICAL AND CHEMICAL PROPERTIES

Density @ 20 C (lbs./gallon): 9.5-10.33

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 242

Boiling Point/Range (C): 117

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: May Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Oxides of nitrogen. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. Excessive inhalation causes headache, dizziness,

nausea and incoordination.

Skin Contact Prolonged or repeated contact may cause skin irritation.

Eye Contact May cause eye irritation.

Ingestion May be harmful if swallowed. May cause abdominal pain, vomiting, nausea, and

diarrhea.

Aggravated Medical Conditions Skin disorders.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

CL-40TM CROSSLINKER

Page 3 of 5

HESI100352
Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Not restricted

Canadian TDG

Not restricted

ADR Not restricted

Air Transportation

ICAO/IATA Not restricted

Sea Transportation

IMDG Not restricted

Other Shipping Information

CL-40TM CROSSLINKER

Page 4 of 5

HESI100353
Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory Product contains one or more components not listed on inventory.

WHMIS Hazard Class D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

CL-40TM CROSSLINKER

Page 5 of 5

HESI100354
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: CLA-STA FS ADDITIVE

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: CLA-STA FS ADDITIVE

Synonyms: None

Chemical Family: Blend

Application: Clay Stabilizer

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Ammonium chloride 12125-02-9 10 - 30% 10 mg/m3 10 mg/m3

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May be harmful if swallowed.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

CLA-STA FS ADDITIVE

Page 1 of 6

HESI100355
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not DeterminedMin: > 200

Flash Point/Range (C): Not DeterminedMin: > 93

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Carbon Dioxide, Dry Chemicals, Foam.

Special Exposure Hazards Use water spray to cool fire exposed surfaces. Decomposition in fire may produce

toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 1, Reactivity 0

HMIS Ratings: Health 2, Flammability 1, Physical Hazard 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse.

Storage Information Store away from oxidizers. Store in a cool well ventilated area. Keep container

closed when not in use.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection If engineering controls and work practices cannot keep exposure below occupational

exposure limits or if exposure is unknown, wear a NIOSH certified, European

Standard EN 149, or equivalent respirator when using this product. Selection of and

instruction on using all personal protective equipment, including respirators, should

be performed by an Industrial Hygienist or other qualified professional.

Organic vapor/acid gas respirator with a dust/mist filter.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

CLA-STA FS ADDITIVE

Page 2 of 6

HESI100356
9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Clear light straw

Odor: Mild amine

pH: 6.5-7.5

Specific Gravity @ 20 C (Water=1): 1.062

Density @ 20 C (lbs./gallon): 8.85

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 212

Boiling Point/Range (C): 100

Freezing Point/Range (F): -1

Freezing Point/Range (C): -19

Vapor Pressure @ 20 C (mmHg): < 20

Vapor Density (Air=1): < 1

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): < 1

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers. Contact with metals. Amphoteric metals such as aluminum,

magnesium, lead, tin, or zinc.

Hazardous Decomposition

Products

Oxides of nitrogen. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation.

Skin Contact May cause moderate skin irritation.

Eye Contact Causes severe eye irritation which may damage tissue.

Ingestion Irritation of the mouth, throat, and stomach. May cause abdominal pain, vomiting,

nausea, and diarrhea.

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

CLA-STA FS ADDITIVE

Page 3 of 6

HESI100357
Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Slowly biodegradable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:TLM96: > 1000 ppm (Crangon crangon)

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

CLA-STA FS ADDITIVE

Page 4 of 6

HESI100358
ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory Product contains one or more components not listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Ammonium Chloride//12125-02-9

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 5649 Gallons based on Ammonium chloride (CAS:

12125-02-9).

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory Product contains one or more components not listed on inventory.

WHMIS Hazard Class D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

CLA-STA FS ADDITIVE

Page 5 of 6

HESI100359
Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

CLA-STA FS ADDITIVE

Page 6 of 6

HESI100360
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: CLA-STA XP ADDITIVE

Revision Date: 03-Jan-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: CLA-STA XP ADDITIVE

Synonyms: None

Chemical Family: Blend

Application: Clay Stabilizer

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Polyepichlorohydrin, trimethyl

amine quaternized

51838-31-4 30 - 60% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May be harmful if swallowed.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

CLA-STA XP ADDITIVE

Page 1 of 5

HESI100361
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not DeterminedMin: > 200

Flash Point/Range (C): Not DeterminedMin: > 93

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Product is not expected to burn unless all the water is boiled away. Decomposition

in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 1, Reactivity 0

HMIS Ratings: Flammability 1, Reactivity 0, Health 2

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors.

Storage Information Store away from oxidizers. Store in a cool well ventilated area. Keep container

closed when not in use.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Organic vapor respirator with a dust/mist filter.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Clear amber

Odor: Amine

pH: 4-8

CLA-STA XP ADDITIVE

Page 2 of 5

HESI100362
9. PHYSICAL AND CHEMICAL PROPERTIES

Specific Gravity @ 20 C (Water=1): 1.13

Density @ 20 C (lbs./gallon): 9.41

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): 40-55

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Oxides of nitrogen. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation.

Skin Contact May cause skin irritation.

Eye Contact May cause severe eye irritation.

Ingestion Irritation of the mouth, throat, and stomach. May cause abdominal pain, vomiting,

nausea, and diarrhea.

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

CLA-STA XP ADDITIVE

Page 3 of 5

HESI100363
Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:TLM96: 300 ppm (Mysidopsis Bahia)

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Not restricted

Canadian TDG

Not restricted

ADR Not restricted

Air Transportation

ICAO/IATA Not restricted

Sea Transportation

IMDG Not restricted

Other Shipping Information

CLA-STA XP ADDITIVE

Page 4 of 5

HESI100364
Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law Does not apply.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law Does not apply.

Canadian Regulations

Canadian DSL Inventory Product contains one or more components not listed on inventory.

WHMIS Hazard Class D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

CLA-STA XP ADDITIVE

Page 5 of 5

HESI100365
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: CLAY CONTROL NEM

Revision Date: 03-Jan-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: CLAY CONTROL NEM

Synonyms: None

Chemical Family: Blend

Application: Clay Stabilization Agent

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Polyamine 30 - 60% Not applicable Not applicable

Ethylene glycol 107-21-1 10 - 30% 100 mg/m3 50 ppm

Ammonium chloride 12125-02-9 1 - 5% 10 mg/m3 10 mg/m3

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause headache, dizziness, and

other central nervous system effects. May be harmful if swallowed. May cause birth

defects.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

CLAY CONTROL NEM

Page 1 of 6

HESI100366
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not DeterminedMin: > 150

Flash Point/Range (C): Not DeterminedMin: > 65

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 1, Reactivity 0

HMIS Ratings: Flammability 1, Reactivity 0, Health 2

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse.

Storage Information Store away from alkalis. Store away from oxidizers. Store in a cool well ventilated

area. Keep container closed when not in use. Product has a shelf life of 36 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Organic vapor/acid gas respirator with a dust/mist filter.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Clear light yellow

Odor: Mild amine

pH: 3-5.5

CLAY CONTROL NEM

Page 2 of 6

HESI100367
9. PHYSICAL AND CHEMICAL PROPERTIES

Specific Gravity @ 20 C (Water=1): 1.07

Density @ 20 C (lbs./gallon): 8.91

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 212

Boiling Point/Range (C): 100

Freezing Point/Range (F): -2

Freezing Point/Range (C): -19

Vapor Pressure @ 20 C (mmHg): 48.3

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers. Strong alkalis. Dehydrating agents.

Hazardous Decomposition

Products

Oxides of nitrogen. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. May cause central nervous system depression

including headache, dizziness, drowsiness, incoordination, slowed reaction time,

slurred speech, giddiness and unconsciousness.

Skin Contact Causes severe skin irritation.

Eye Contact May cause severe eye irritation.

Ingestion Causes burns of the mouth, throat and stomach. May cause heart, kidney and brain

disorders.

Aggravated Medical Conditions Skin disorders. Eye ailments. Liver disorders.

Chronic Effects/Carcinogenicity Prolonged or repeated exposure may cause kidney damage. Prolonged or repeated

exposure may cause reproductive system damage. Prolonged or repeated exposure

may cause liver, heart, blood and brain damage. Prolonged or repeated exposure

may cause embryo and fetus toxicity.

Other Information None known.

Toxicity Tests

CLAY CONTROL NEM

Page 3 of 6

HESI100368
Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Slowly biodegradable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Not restricted

Canadian TDG

Not restricted

ADR Not restricted

Air Transportation

ICAO/IATA Not restricted

Sea Transportation

CLAY CONTROL NEM

Page 4 of 6

HESI100369
IMDG Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Ethylene Glycol//107-21-1

Ammonium Chloride//12125-02-9

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 55494 Gallons based on Ammonium chloride (CAS:

12125-02-9).

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class D2A Very Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

CLAY CONTROL NEM

Page 5 of 6

HESI100370
Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

CLAY CONTROL NEM

Page 6 of 6

HESI100371
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: CLAYFIX-II MATERIAL

Revision Date: 05-Jan-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: CLAYFIX-II MATERIAL

Synonyms: None

Chemical Family: Organic Salt

Application: Additive

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Alkylated quaternary chloride 30 - 60% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May be fatal if swallowed.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention.

Eyes Immediately flush eyes with large amounts of water for at least 15 minutes. Get

immediate medical attention.

Ingestion If swallowed, call a physician immediately. Only induce vomiting at the instruction of

a physician. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

CLAYFIX-II MATERIAL

Page 1 of 6

HESI100389
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not DeterminedMin: > 200

Flash Point/Range (C): Not DeterminedMin: > 93

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases. Use water spray to cool fire exposed

surfaces.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 3, Flammability 1, Reactivity 0

HMIS Ratings: Health 3, Flammability 1, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Do NOT consume

food, drink, or tobacco in contaminated areas. Wash hands after use. Launder

contaminated clothing before reuse.

Storage Information Store away from oxidizers. Store in a cool well ventilated area. Keep container

closed when not in use. Product has a shelf life of 24 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Organic vapor/acid gas respirator with a dust/mist filter.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Clear light amber

Odor: Mild amine

CLAYFIX-II MATERIAL

Page 2 of 6

HESI100390
9. PHYSICAL AND CHEMICAL PROPERTIES

pH: 4- 9

Specific Gravity @ 20 C (Water=1): 1.0153

Density @ 20 C (lbs./gallon): 8.46

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 212

Boiling Point/Range (C): 100

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): 5-10

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Chlorine. Hydrogen chloride. Oxides of nitrogen. Carbon monoxide and carbon

dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation.

Skin Contact May cause skin irritation.

Eye Contact May cause eye burns.

Ingestion May be fatal if swallowed.

Aggravated Medical Conditions Skin disorders. Eye ailments.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: LD50: 220 mg/kg (Rat)

Dermal Toxicity: Not determined

CLAYFIX-II MATERIAL

Page 3 of 6

HESI100391
Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Slowly biodegradable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:TLM96: 10.5 ppm (Mysidopsis bahia)

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Toxic Liquid, Organic, N.O.S., 6.1, UN2810, III

(Contains Tetramethylammonium Chloride)

NAERG 153

Canadian TDG

Toxic Liquid, Organic, N.O.S.(Contains Tetramethylammonium Chloride), 6.1, UN2810, III

ADR

UN2810,Toxic Liquid, Organic, N.O.S.(Contains Tetramethylammonium Chloride), 6.1, III

Air Transportation

ICAO/IATA

UN2810,Toxic Liquid, Organic, N.O.S., 6.1, III

(Contains Tetramethylammonium Chloride Solution)

CLAYFIX-II MATERIAL

Page 4 of 6

HESI100392
Sea Transportation

IMDG

UN2810,Toxic Liquid, Organic, N.O.S.(Contains Tetramethylammonium Chloride), 6.1, III

EmS F-A, S-A

Other Shipping Information

Labels: Toxic

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class D1B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

CLAYFIX-II MATERIAL

Page 5 of 6

HESI100393
Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

CLAYFIX-II MATERIAL

Page 6 of 6

HESI100394
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: Clayfix 3

Revision Date: 05-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: Clayfix 3

Synonyms: None

Chemical Family: Salt Solution

Application: Additive

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Sodium chloride 7647-14-5 10 - 30% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May be harmful if swallowed.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion If swallowed, give at least 3-4 glasses of water, but do not induce vomiting. Do not

give anything by mouth to an unconscious or convulsing person. Get medical

attention.

Notes to Physician Not Applicable

Clayfix 3

Page 1 of 6

HESI100372
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): > 212

Flash Point/Range (C): > 93

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media All standard firefighting media.

Special Exposure Hazards Not applicable.

Special Protective Equipment for

Fire-Fighters

Not applicable.

NFPA Ratings: Health 1, Flammability 0, Reactivity 0

HMIS Ratings: Health 1, Flammability 0, Physical Hazard 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing.

Storage Information Store in a cool, dry location. Keep container closed when not in use.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection If engineering controls and work practices cannot keep exposure below occupational

exposure limits or if exposure is unknown, wear a NIOSH certified, European

Standard EN 149, or equivalent respirator when using this product. Selection of and

instruction on using all personal protective equipment, including respirators, should

be performed by an Industrial Hygienist or other qualified professional.

Not normally needed. But if significant exposures are possible then the following

respirator is recommended:

Dust/mist respirator. (95%)

Hand Protection Impervious rubber gloves.

Skin Protection Normal work coveralls.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions None known.

Clayfix 3

Page 2 of 6

HESI100373
9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Clear to hazy

Odor: Odorless

pH: 6.3 - 7.1

Specific Gravity @ 20 C (Water=1): 1.18

Density @ 20 C (lbs./gallon): 9.83

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): 747 (100C)

Vapor Density (Air=1): Not Determined

Percent Volatiles: 77.99

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong acids. Strong oxidizers. Bromine trifluoride. Sulfuric acid.

Hazardous Decomposition

Products

None known.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation.

Skin Contact May cause skin irritation.

Eye Contact May cause eye irritation.

Ingestion In large amounts: May cause abdominal pain, vomiting, nausea, and diarrhea. May

affect the heart and cardiovascular system.

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Clayfix 3

Page 3 of 6

HESI100374
Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not applicable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

Clayfix 3

Page 4 of 6

HESI100375
ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law Does not apply.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law Does not apply.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class Un-Controlled

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Clayfix 3

Page 5 of 6

HESI100376
Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

Clayfix 3

Page 6 of 6

HESI100377
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: CLAYFIX LIQUID

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: CLAYFIX LIQUID

Synonyms: None

Chemical Family: Blend

Application: Clay Stabilization Agent

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Ammonium chloride 12125-02-9 10 - 30% 10 mg/m3 10 mg/m3

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May be harmful if swallowed.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

CLAYFIX LIQUID

Page 1 of 6

HESI100378
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 0, Reactivity 0

HMIS Ratings: Health 2, Flammability 0, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse.

Storage Information Store away from alkalis. Store in a cool well ventilated area. Keep container closed

when not in use.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Organic vapor/acid gas respirator with a dust/mist filter.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Clear light amber

Odor: Mild amine

pH: 7.5

CLAYFIX LIQUID

Page 2 of 6

HESI100379
9. PHYSICAL AND CHEMICAL PROPERTIES

Specific Gravity @ 20 C (Water=1): 1.06

Density @ 20 C (lbs./gallon): 8.86

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 216

Boiling Point/Range (C): 102

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): 25

Vapor Density (Air=1): <1

Percent Volatiles: <50

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): 109.6

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong alkalis.

Hazardous Decomposition

Products

Oxides of nitrogen. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation.

Skin Contact Causes severe skin irritation.

Eye Contact May cause severe eye irritation.

Ingestion Causes burns of the mouth, throat and stomach.

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: LD50: > 5000 mg/kg (Rat)

Dermal Toxicity: LD50: > 2000 mg/kg (Rabbit)

Inhalation Toxicity: Not determined

CLAYFIX LIQUID

Page 3 of 6

HESI100380
Primary Irritation Effect: Draize Rating (Eye): 9/110 (Rabbit) Minimally Irritation Draize Rating (Skin): 0.1/8.0

(Rabbit) Non-Irritating

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Slowly biodegradable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

CLAYFIX LIQUID

Page 4 of 6

HESI100381
Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Ammonium Chloride//12125-02-9

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 5263 Gallons based on Ammonium chloride (CAS:

12125-02-9).

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

CLAYFIX LIQUID

Page 5 of 6

HESI100382
***END OF MSDS***

CLAYFIX LIQUID

Page 6 of 6

HESI100383
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: CLAYFIX MATERIAL

Revision Date: 03-Jan-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: CLAYFIX MATERIAL

Synonyms: None

Chemical Family: Inorganic Salt

Application: Clay Stabilizer

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Ammonium chloride 12125-02-9 60 - 100% 10 mg/m3 10 mg/m3

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May be harmful if swallowed.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists. Remove

contaminated clothing and launder before reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

CLAYFIX MATERIAL

Page 1 of 5

HESI100384
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 0, Reactivity 0

HMIS Ratings: Flammability 0, Reactivity 0, Health 1

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid creating or inhaling dust.

Storage Information Store away from alkalis. Store away from acids. Store in a cool, dry location. Product

has a shelf life of 60 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Localized ventilation should be used to control dust

levels.

Respiratory Protection Dust/mist respirator. (95%)

Hand Protection Impervious rubber gloves.

Skin Protection Normal work coveralls.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid

Color: White

Odor: Odorless

pH: 4.3-5.5

Specific Gravity @ 20 C (Water=1): 1.567

CLAYFIX MATERIAL

Page 2 of 5

HESI100385
9. PHYSICAL AND CHEMICAL PROPERTIES

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): 55

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): 37

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): 53.46

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong alkalis. Carbonates of alkalis. Contact with lead. Silver salts.

Hazardous Decomposition

Products

Ammonia. Oxides of nitrogen. Hydrogen chloride.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. Coughing, chest pains, and breathing difficulty may

occur.

Skin Contact May cause skin irritation.

Eye Contact May cause severe eye irritation.

Ingestion Irritation of the mouth, throat, and stomach. May cause abdominal pain, vomiting,

nausea, and diarrhea.

Aggravated Medical Conditions Skin disorders. Lung disorders.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: LD50: 1650 mg/kg (Rat)

Dermal Toxicity: Not determined

CLAYFIX MATERIAL

Page 3 of 5

HESI100386
Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Not restricted

Canadian TDG

Not restricted

ADR Not restricted

Air Transportation

ICAO/IATA Not restricted

Sea Transportation

IMDG Not restricted

Other Shipping Information

CLAYFIX MATERIAL

Page 4 of 5

HESI100387
Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Ammonium Chloride//12125-02-9

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 5000 Pounds based on Ammonium chloride (CAS:

12125-02-9).

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class Un-Controlled

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

CLAYFIX MATERIAL

Page 5 of 5

HESI100388
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: ClaySurfTM-EZ

Revision Date: 05-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: ClaySurfTM-EZ

Synonyms: None

Chemical Family: Organic Salt

Application: Clay Control

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Alkylated quaternary chloride 30 - 60% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May be fatal if swallowed.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention.

Eyes Immediately flush eyes with large amounts of water for at least 15 minutes. Get

immediate medical attention.

Ingestion If swallowed, call a physician immediately. Only induce vomiting at the instruction of

a physician. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

ClaySurfTM-EZ

Page 1 of 6

HESI100395
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): > 200

Flash Point/Range (C): > 93

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases. Use water spray to cool fire exposed

surfaces.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 3, Flammability 1, Reactivity 0

HMIS Ratings: Health 3, Flammability 1, Physical Hazard 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Do NOT consume

food, drink, or tobacco in contaminated areas. Wash hands after use. Launder

contaminated clothing before reuse.

Storage Information Store away from oxidizers. Store in a cool well ventilated area. Keep container

closed when not in use. Product has a shelf life of 24 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection If engineering controls and work practices cannot keep exposure below occupational

exposure limits or if exposure is unknown, wear a NIOSH certified, European

Standard EN 149, or equivalent respirator when using this product. Selection of and

instruction on using all personal protective equipment, including respirators, should

be performed by an Industrial Hygienist or other qualified professional.

Organic vapor/acid gas respirator with a dust/mist filter.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

ClaySurfTM-EZ

Page 2 of 6

HESI100396
9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Clear light amber

Odor: Mild amine

pH: 3.5 (10%)

Specific Gravity @ 20 C (Water=1): 1.027

Density @ 20 C (lbs./gallon): 8.56

Bulk Density @ 20 C (lbs/ft3): 64

Boiling Point/Range (F): 212

Boiling Point/Range (C): 100

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): 5-10

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Chlorine. Hydrogen chloride. Oxides of nitrogen. Carbon monoxide and carbon

dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation.

Skin Contact May cause skin irritation.

Eye Contact May cause eye burns.

Ingestion May be fatal if swallowed.

Aggravated Medical Conditions Eye ailments. Skin disorders.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

ClaySurfTM-EZ

Page 3 of 6

HESI100397
Oral Toxicity: LD50: 220 mg/kg (Rat)

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Slowly biodegradable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:TLM96: 10.5 ppm (Mysidopsis bahia)

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

UN2810,Toxic Liquid, Organic, N.O.S.(Contains Tetramethylammonium Chloride), 6.1, III

NAERG 153

Canadian TDG

Toxic Liquid, Organic, N.O.S.(Contains Tetramethylammonium Chloride), 6.1, UN2810, III

ADR

UN2810,Toxic Liquid, Organic, N.O.S.(Contains Tetramethylammonium Chloride), 6.1, III

Air Transportation

ClaySurfTM-EZ

Page 4 of 6

HESI100398
ICAO/IATA

UN2810,Toxic Liquid, Organic, N.O.S., 6.1, III

(Contains Tetramethylammonium Chloride Solution)

Sea Transportation

IMDG

UN2810,Toxic Liquid, Organic, N.O.S.(Contains Tetramethylammonium Chloride), 6.1, III

EmS F-A, S-A

Other Shipping Information

Labels: Toxic

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 2381 gallons based on Sodium dodecylbenzene

sulfonate (CAS: 25155-30-0)

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class D1B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

ClaySurfTM-EZ

Page 5 of 6

HESI100399
Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

ClaySurfTM-EZ

Page 6 of 6

HESI100400
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: CoalStim - Part A

Revision Date: 05-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: CoalStim - Part A

Synonyms: None

Chemical Family: Organic acid Anhydride

Application: Additive

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Acetic anhydride 108-24-7 60 - 100% 5 ppm 5 ppm

Acetic acid 64-19-7 30 - 60% 10 ppm 10 ppm

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory burns. May be harmful if swallowed.

Combustible. Reacts violently with water.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse. Destroy or properly dispose of contaminated shoes.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

CoalStim - Part A

Page 1 of 6

HESI100401
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 103

Flash Point/Range (C): 39

Flash Point Method: PMCC

Autoignition Temperature (F): 630

Autoignition Temperature (C): 332

Flammability Limits in Air - Lower (%): 3

Flammability Limits in Air - Upper (%): 19

Fire Extinguishing Media Water must not be used with open containers. Carbon Dioxide, Dry Chemicals,

Foam.

Special Exposure Hazards May be ignited by heat, sparks or flames. Closed containers may explode in fire.

Decomposition in fire may produce toxic gases. Reaction with water may be highly

exothermic.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 3, Flammability 2, Reactivity 2

HMIS Ratings: Health 2, Flammability 3, Reactivity 2

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Neutralize to pH of 6-8. Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse.

Storage Information Store away from alkalis. Store away from oxidizers. Store away from water. Keep

from heat, sparks, and open flames. Keep container closed when not in use.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Organic vapor/acid gas respirator.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber boots. Full protective chemical resistant clothing.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

CoalStim - Part A

Page 2 of 6

HESI100402
9. PHYSICAL AND CHEMICAL PROPERTIES

Color: Clear colorless

Odor: Pungent acrid

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 1.05

Density @ 20 C (lbs./gallon): 8.74

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 259

Boiling Point/Range (C): 126

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): 11.7

Vapor Density (Air=1): 3.5

Percent Volatiles: 100

Evaporation Rate (Butyl Acetate=1): 0.97

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame. Do not allow water to get into container

because of violent reaction.

Incompatibility (Materials to

Avoid)

Strong alkalis. Strong oxidizers. Reacts with water.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation Causes severe respiratory irritation.

Skin Contact Causes severe burns.

Eye Contact Causes severe eye burns.

Ingestion Causes burns of the mouth, throat and stomach.

Aggravated Medical Conditions Eye ailments. Skin disorders.

Chronic Effects/Carcinogenicity Prolonged, excessive exposure may cause erosion of the teeth.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

CoalStim - Part A

Page 3 of 6

HESI100403
Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Readily biodegradable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

UN2920,Corrosive Liquid, Flammable, N.O.S.(Contains Acetic Anhydride, Acetic Acid) , 8, (3), II, (39.4 C)

NAERG 132

Canadian TDG

Corrosive Liquid, Flammable, N.O.S.(Contains Acetic Anhydride, Acetic Acid) , 8, (3), UN2920, II, (39.4 C)

ADR

UN2920,Corrosive Liquid, Flammable, N.O.S.(Contains Acetic Anhydride, Acetic Acid) , 8, (3), II

Air Transportation

ICAO/IATA

CoalStim - Part A

Page 4 of 6

HESI100404
UN2920,Corrosive Liquid, Flammable, N.O.S., 8, (3), II

(Contains Acetic Anhydride, Acetic Acid Solution)

Sea Transportation

IMDG

UN2920,Corrosive Liquid, Flammable, N.O.S.(Contains Acetic Anhydride, Acetic Acid) , 8, (3), II, (39.4 C)

EmS F-E, S-C

Other Shipping Information

Labels: Corrosive

Flammable Liquid

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 1409 Gallons based on Acetic acid (CAS: 64-19-7).

EPA RCRA Hazardous Waste

Classification

Ignitability D001

 Corrosivity D002

 If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class B3 Combustible Liquids

E Corrosive Material

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

CoalStim - Part A

Page 5 of 6

HESI100405
Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

CoalStim - Part A

Page 6 of 6

HESI100406
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: CoalStim - Part B

Revision Date: 05-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: CoalStim - Part B

Synonyms: None

Chemical Family: Blend

Application: Additive

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Branched ethoxylated

nonylphenol

68412-54-4 1 - 5% Not applicable Not applicable

Ethylene glycol 107-21-1 5 - 10% 100 mg/m3 50 ppm

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause headache, dizziness, and

other central nervous system effects. May cause allergic skin reaction. May cause

birth defects.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

CoalStim - Part B

Page 1 of 6

HESI100407
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not DeterminedMin: > 200

Flash Point/Range (C): Not DeterminedMin: > 93

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 0, Reactivity 0

HMIS Ratings: Health 1, Flammability 0, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors.

Storage Information Store away from oxidizers. Store in a cool well ventilated area. Keep container

closed when not in use.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Organic vapor/acid gas respirator with a dust/mist filter.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: White

Odor: Odorless

pH: 2.5-4.5

Specific Gravity @ 20 C (Water=1): 1

CoalStim - Part B

Page 2 of 6

HESI100408
9. PHYSICAL AND CHEMICAL PROPERTIES

Density @ 20 C (lbs./gallon): 8.33

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Disperses

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. Excessive inhalation causes headache, dizziness,

nausea and incoordination.

Skin Contact May cause skin irritation. May cause an allergic skin reaction.

Eye Contact May cause eye irritation.

Ingestion Harmful if swallowed. May cause kidney damage. May affect the heart and

cardiovascular system. May cause brain disorders.

Aggravated Medical Conditions Liver disorders. Eye ailments. Skin disorders.

Chronic Effects/Carcinogenicity Prolonged or repeated exposure may cause embryo and fetus toxicity. Prolonged or

repeated exposure may cause reproductive system damage.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

CoalStim - Part B

Page 3 of 6

HESI100409
Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

CoalStim - Part B

Page 4 of 6

HESI100410
Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Ethylene Glycol//107-21-1

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 10004 Gallons based on Ethylene glycol (CAS: 107-

21-1).

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

CoalStim - Part B

Page 5 of 6

HESI100411
Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

CoalStim - Part B

Page 6 of 6

HESI100412
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: CoalStim - Part C

Revision Date: 05-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: CoalStim - Part C

Synonyms: None

Chemical Family: Polysaccharide

Application: Breaker

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Hemicellulase enzyme 9012-54-8 5-15 Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview Airborne dust may be explosive. May cause allergic respiratory reaction. May cause

eye and respiratory irritation.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Under normal conditions, first aid procedures are not required.

Notes to Physician Not Applicable

CoalStim - Part C

Page 1 of 6

HESI100413
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not DeterminedMin: > 200

Flash Point/Range (C): Not DeterminedMin: > 93

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Lower (oz./ft3): 0.125

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media All standard firefighting media.

Special Exposure Hazards Organic dust in the presence of an ignition source can be explosive in high

concentrations. Good housekeeping practices are required to minimize this

potential.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 1, Reactivity 0

HMIS Ratings: Health 1, Flammability 1, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid creating or inhaling dust.

Storage Information Product has a shelf life of 12 months. Store away from oxidizers. Store in a cool, dry

location.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Dust/mist respirator. (95%) Not normally needed. But if significant exposures are

possible then the following respirator is recommended:

Hand Protection Normal work gloves.

Skin Protection Normal work coveralls.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions None known.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid

CoalStim - Part C

Page 2 of 6

HESI100414
9. PHYSICAL AND CHEMICAL PROPERTIES

Color: White

Odor: Odorless

pH: 7

Specific Gravity @ 20 C (Water=1): 1.5

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): 42

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause mild respiratory irritation. May cause allergic respiratory reaction.

Skin Contact None known.

Eye Contact May cause mild eye irritation.

Ingestion None known

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: LD50: 29700 mg/kg (Rat)

CoalStim - Part C

Page 3 of 6

HESI100415
Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Readily biodegradable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:TLM96: > 3300 ppm (Crangon crangon)

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

CoalStim - Part C

Page 4 of 6

HESI100416
IMDG

 Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

None

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law Does not apply.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law Does not apply.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class Un-Controlled

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

CoalStim - Part C

Page 5 of 6

HESI100417
***END OF MSDS***

CoalStim - Part C

Page 6 of 6

HESI100418
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: CoalStim - Part D

Revision Date: 05-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: CoalStim - Part D

Synonyms: None

Chemical Family: Oxidant

Application: Breaker

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Sodium persulfate 7775-27-1 60 - 100% 0.1 mg/m3 Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause allergic skin and respiratory reaction. May cause eye irritation. Oxidizer.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

CoalStim - Part D

Page 1 of 6

HESI100419
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Oxidizer. May ignite combustibles. Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 0, Reactivity 1

HMIS Ratings: Health 1, Flammability 0, Reactivity 1

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid creating or inhaling dust. Avoid dust

accumulations.

Storage Information Store away from combustibles. Store in a cool well ventilated area. Keep container

closed when not in use.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Localized ventilation should be used to control dust

levels.

Respiratory Protection Dust/mist respirator. (95%)

Hand Protection Butyl rubber gloves.

Skin Protection Rubber apron.

Eye Protection Dust proof goggles.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid

Color: White

Odor: Odorless

pH: 6

CoalStim - Part D

Page 2 of 6

HESI100420
9. PHYSICAL AND CHEMICAL PROPERTIES

Specific Gravity @ 20 C (Water=1): 2.47

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): 84.3

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): 35

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): 238.1

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Avoid contact with readily oxidizable materials.

Incompatibility (Materials to

Avoid)

Avoid halogens. Contact with acids. Strong alkalis. Combustible materials.

Hazardous Decomposition

Products

Oxides of sulfur. Oxygen. Sulfuric acid.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause allergic respiratory reaction.

Skin Contact May cause an allergic skin reaction.

Eye Contact May cause eye irritation.

Ingestion Irritation of the mouth, throat, and stomach.

Aggravated Medical Conditions Lung disorders.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: LD50: 895 mg/kg (Rat)

Dermal Toxicity: LD50: > 10000 mg/kg (Rabbit)

Inhalation Toxicity: Not determined

CoalStim - Part D

Page 3 of 6

HESI100421
Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Readily biodegradable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging This bag may contain residue of a hazardous material. Some authorities may

regulate such containers as hazardous waste. Dispose of container according to

national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

UN1505,Sodium Persulfate, 5.1, III

NAERG 140

Canadian TDG

Sodium Persulfate, 5.1, UN1505, III

ADR

UN1505,Sodium Persulfate, 5.1, III

Air Transportation

ICAO/IATA

UN1505,Sodium Persulfate, 5.1, III

CoalStim - Part D

Page 4 of 6

HESI100422
Sea Transportation

IMDG

UN1505,Sodium Persulfate, 5.1, III

EmS F-A, S-Q

Other Shipping Information

Labels: Oxidizer

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Fire Hazard

Reactive Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Ignitability D001

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class C Oxidizing Materials

D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

CoalStim - Part D

Page 5 of 6

HESI100423
Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

CoalStim - Part D

Page 6 of 6

HESI100424
SANTROLMaterial Safety Data Sheet

Super HSTM, Super LCTM, Super TFTM, Super DCTM, PolarProp

Tempered HSTM, Tempered LCTM, Tempered TFTM, Tempered DCTM

Super PacTM, Super HTTM, OptiPropTM

Page 1

Section I

Product Type: Oil/gas well proppant

Application: Hydraulic Fracturing

Manufacturer's Name Telephone Number

Santrol, Inc. (281) 431-0670

2727 FM 521

Fresno, TX 77545 Date 10/02/02

Section II - Hazardous Ingredients

Hazardous components CAS # OSHA PEL ACGIH TLV Percent

Silicon Dioxide (Quartz) 14808-60-7 0.10 mg/M3  0.10 mg/M3 Balance

Respirable Respirable

P/F Resin 900303504 N/K N/K 1-5

Hexamethylenetetramine 1009-7-0 N/K N/K <2

Hazard Rating Scale:1 Product:

0-Minimal 3-Serious Health: 1

1-Slight 4-Severe Fire: 0

2-Moderate Reactivity: 0

Special: None

Canada Hazardous Products Act

Ingredients Disclosure List

Chemical Name % Item No French Version Cas#

None N/A N/A N/A N/A

WHIMIS CLASS D, DIV 2A, 2B

CEPA Listed on DSL or otherwise in compliance with CEPA

NPRI CEPA subsection 16 (1) None required

U.S DOT Not Regulated

Section 313 Supplier Notification

This product contains the following toxic chemicals subject to the reporting requirements of section 313 of the

Emergency Planning and Community Right-To-Know Act of 1986 and of 40 CFR 372. :

CAS# Chemical Name % by Weight

None None

HESI100425
SANTROLMaterial Safety Data Sheet

Super HSTM, Super LCTM, Super TFTM, Super DCTM, PolarProp

Tempered HSTM, Tempered LCTM, Tempered TFTM, Tempered DCTM

Super PacTM, Super HTTM, OptiPropTM

Page 2

Section III - Physical/Chemical Characteristics

Boiling Point: N/A oF Specific Gravity (H2O=1): 2.53 - 2.60

Vapor Pressure (mmHg):N/A at 20oC Melting Point: N/A

Vapor Density (Air=1): N/A Evaporation Rate (Butyl Acetate=1): N/A

Solubility in Water: Insoluble

Appearance and Odor: Appearance of yellow sand, mild phenolic resin odor.

Section IV - Fire and Explosion Hazard Data

Flash Point: oF (TCC) Not Known

Flammable Limits in air, % : None , except dusting conditions Lower: N/K Upper: N/K

Extinguishing Media: Use water spray, alcohol foam, CO2 or Dry Chemical. 

Special Fire Fighting Procedures: Fire Fighters should wear self contained breathing apparatus. 

Unusual Fire and Explosion Hazards: Dust explosions may occur when finely divided particles are mixed with air in

the presence of an ignition source. See Hazardous decomposition products,

Sec. V and Toxicity, Sec. IX.

Section V - Reactivity Data

Stability: Stable Polymerization will not occur.

Conditions to avoid: 

Materials to avoid: Oxidizers

Hazardous decomposition products: May liberate ammonia, formaldehyde, carbon monoxide, carbon dioxide, and

unidentified compounds in smoke.

Section VI - Health Hazard Data

Primary Routes of exposure: Swallowing, skin or eye contact, inhalation.

Emergency and First Aid Procedures:

Inhalation: Remove to fresh air. Rest in half upright position. Seek medical attention if necessary.

Eye contact: Immediately flush eyes with running water for at least 15 minutes. Get immediate medical

attention.

Skin contact: Wash skin thoroughly with of soap and water. Seek medical attention if irritation persists.

HESI100426
SANTROLMaterial Safety Data Sheet

Super HSTM, Super LCTM, Super TFTM, Super DCTM, PolarProp

Tempered HSTM, Tempered LCTM, Tempered TFTM, Tempered DCTM

Super PacTM, Super HTTM, OptiPropTM

Page 3

Swallowed: Dilute by drinking large quantities of water. After dilution, induce vomiting. Obtain immediate

medical attention.

OSHA Hazard Communication Standard 29 CFR1910.1200

See above standard. This material presents possible health hazards

SARA Title III

Delayed Health Hazard

TSCA Section 8(b)

All reportable chemical substances are listed on the TSCA inventory.

Section VII - Precautions for Safe Handling and Use

Steps to Be Taken in Case Material is Spilled or Released:

Surfaces will become slippery due to the round sand particles. Sweep up spilled material to prevent falls. 

Comply with all applicable Governmental regulations on spill reporting and handling and disposal of waste.

Precautions to Be Taken in Handling and Storing:

Keep away from heat and flames. Store in a cool, dry place. 

Repair and Maintenance Precautions:

Do not cut, grind, weld, or drill on or near this container.

Other Precautions:

Containers, even those that have been emptied, will retain product residue and vapors. Always obey hazard

warnings and handle empty containers as if they were full.

Section VIII - Control Measures

Respiratory Protection: NIOSH-Approved respirator for dust in the absence of adequate environmental controls at

the point of use.

Ventilation: Local mechanical exhaust ventilation capable of maintaining emissions at the point of use

below the PEL.

Eye Protection: Eye Goggles

Protective Clothing: Long-sleeved shirt, full length trousers and safety shoes.

Other Precautions: None

Section IX - Toxicity Data

Oral: This material is not toxic when administered orally to rats under the Federal Hazardous Substance

Act (FHSA) criteria.

Dermal:This Material is not an irritant when applied to the skin of rabbits under the FHSA criteria. This substance is

not lethal when applied to the skin of rabbits under the FHSA criteria.

Inhalation: The phenolic (P/F) coating on the sand is not toxic to rats by inhalation under the FHSA criteria.

Silica Sand: Contains free silica. Avoid breathing dust from this product. Prolonged exposure may

cause delayed lung injury (silicosis). Excessive inhalation of dust may result in respiratory disease,

including silicosis, pneumoconiosis and pulmonary fibrosis. The international Agency for Research

On Cancer (IARC) has determined that silica inhaled in the form of quartz in certain industrial

circumstances, is carcinogenic to humans but that carcinogenicity may be dependent on inherant

characteristics of the crystalline silica or on external factors affecting its biological activity or

HESI100427
SANTROLMaterial Safety Data Sheet

Super HSTM, Super LCTM, Super TFTM, Super DCTM, PolarProp

Tempered HSTM, Tempered LCTM, Tempered TFTM, Tempered DCTM

Super PacTM, Super HTTM, OptiPropTM

Page 4

distribution of its polymorphs, Group 1. Refer to IARC monograph 68 (published in June 1997).

NTP rating: crystalline silica is classified as reasonably anticipated to be a human carcinogen.

Formaldehyde gas is given off when heated. Formaldehyde is a potential cancer hazard as listed on

the OSHA A2 list - suspected human carcinogens, ACGIN. The target organs are the eyes and the

lungs.

Santrol expressly disclaims all express or implied warranties of merchantability and fitness for a particular purpose, with respect tot he product or information provided

herein.

All information appearing herein is based upon data obtained from recognized technical sources. While the information is believed to be accurate, Santrol, Inc. makes

no representations as to its accuracy or sufficiency. Conditions of use are beyond Santrol's control and therefore users are responsible to verify this data under their

own operating conditions to determine whether the product is suitable for their particular purposes and they assume all risks of their use of, or reliance upon,

information contained herein. This information relates only to the product designated herein, and does not relate to its use in combination with any other material or in

any other process.

HESI100428
HESI100429
HESI100430
HESI100431
HESI100432
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: D-AIR 3000L

Revision Date: 03-Jan-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: D-AIR 3000L

Synonyms: None

Chemical Family: Blend

Application: Defoamer

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Alkenes 60 - 100% Not applicable Not applicable

Silica, amorphous

precipitated

67762-90-7 10 - 30% 10 mg/m3 10 mg/m3

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye and skin irritation. May cause headache, dizziness, and other central

nervous system effects. May be harmful if swallowed.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Get medical attention! If vomiting occurs, keep head lower than hips to prevent

aspiration.

Notes to Physician Not Applicable

D-AIR 3000L

Page 1 of 5

HESI100433
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not DeterminedMin: > 250

Flash Point/Range (C): Not DeterminedMin: > 121

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 1, Reactivity 0

HMIS Ratings: Flammability 1, Reactivity 0, Health 2

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

None known.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors.

Storage Information Store away from oxidizers. Keep container closed when not in use. Product has a

shelf life of 24 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Not normally necessary.

Hand Protection Impervious rubber gloves.

Skin Protection Normal work coveralls.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions None known.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Opaque

Odor: Hydrocarbon

pH: 5.5-7.9

Specific Gravity @ 20 C (Water=1): 0.92

D-AIR 3000L

Page 2 of 5

HESI100434
9. PHYSICAL AND CHEMICAL PROPERTIES

Density @ 20 C (lbs./gallon): 7.66

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Insoluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause central nervous system depression including headache, dizziness,

drowsiness, incoordination, slowed reaction time, slurred speech, giddiness and

unconsciousness.

Skin Contact May cause mild skin irritation.

Eye Contact May cause mild eye irritation.

Ingestion May cause abdominal pain, vomiting, nausea, and diarrhea. Aspiration into the lungs

may cause chemical pneumonitis including coughing, difficulty breathing, wheezing,

coughing up blood and pneumonia, which can be fatal.

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

D-AIR 3000L

Page 3 of 5

HESI100435
Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Not restricted

Canadian TDG

Not restricted

ADR Not restricted

Air Transportation

ICAO/IATA Not restricted

Sea Transportation

IMDG Not restricted

D-AIR 3000L

Page 4 of 5

HESI100436
Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law Does not apply.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law Does not apply.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

D-AIR 3000L

Page 5 of 5

HESI100437
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: ER-25

Revision Date: 22-Jan-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: ER-25

Synonyms: None

Chemical Family: Resin

Application: Resin

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Dipropylene glycol

monomethyl ether

34590-94-8 60 - 100% 100 ppm 100 ppm

Butyl glycidyl ether 2426-08-6 1 - 5% 3 ppm 50 ppm

Bisphenol A / Epichlorohydrin

resin

25068-38-6 10 - 30% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause headache, dizziness, and

other central nervous system effects. May be harmful if swallowed. May be absorbed

through the skin. May cause allergic skin reaction. Combustible.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

ER-25

Page 1 of 6

HESI100438
Notes to Physician Not Applicable

5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 166

Flash Point/Range (C): 74.4

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): < 0.4

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Use water spray to cool fire exposed surfaces. Closed containers may explode in

fire. Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 2, Reactivity 0

HMIS Ratings: Health 2, Flammability 2, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse.

Storage Information Keep from heat, sparks, and open flames. Keep container closed when not in use.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Organic vapor respirator.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

ER-25

Page 2 of 6

HESI100439
9. PHYSICAL AND CHEMICAL PROPERTIES

Color: Clear light

Odor: Mild

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 0.997

Density @ 20 C (lbs./gallon): 8.31

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 327 - 374

Boiling Point/Range (C): 164 - 190

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): 0.80

Vapor Density (Air=1): 4

Percent Volatiles: < 0.5

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Partially soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong acids. Strong alkalis. Do not expose to amines.

Hazardous Decomposition

Products

Aldehydes. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. May cause central nervous system depression

including headache, dizziness, drowsiness, incoordination, slowed reaction time,

slurred speech, giddiness and unconsciousness.

Skin Contact May cause skin irritation. May be absorbed through the skin and produce effects

similar to those caused by inhalation and/or ingestion. May cause an allergic skin

reaction.

Eye Contact Causes severe eye irritation which may damage tissue.

Ingestion May cause central nervous system depression including headache, dizziness,

drowsiness, muscular weakness, incoordination, slowed reaction time, fatigue

blurred vision, slurred speech, giddiness, tremors and convulsions.

Aggravated Medical Conditions Skin disorders. Eye ailments.

ER-25

Page 3 of 6

HESI100440
Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Resistant

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT Not restricted

DOT (Bulk)

Combustible Liquid, N.O.S., Combustible Liquid, NA1993, III

(Contains Dipropylene Glycol Monomethyl Ether. Butyl Glycidyl Ether)

Canadian TDG

Not restricted

ER-25

Page 4 of 6

HESI100441
ADR Not restricted

Air Transportation

ICAO/IATA Not restricted

Sea Transportation

IMDG Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Glycol Ethers//34590-94-8

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 The California Proposition 65 regulations apply to this product.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class B3 Combustible Liquids

D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

ER-25

Page 5 of 6

HESI100442
Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

ER-25

Page 6 of 6

HESI100443
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: ES-5 PROPLOK SURFACTANT

Revision Date: 10-Sep-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: ES-5 PROPLOK SURFACTANT

Synonyms: None

Chemical Family: Blend

Application: Surfactant

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Phosphate ester 60 - 100% Not applicable Not applicable

Methanol 67-56-1 10 - 30% 200 ppm 200 ppm (S)

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause headache, dizziness, and

other central nervous system effects. May be fatal if swallowed. May cause

blindness. May be absorbed through the skin. Repeated overexposure may cause

liver and kidney effects. Flammable.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion If swallowed, induce vomiting immediately by giving two glasses of water and sticking

fingers down throat; never give anything to an unconscious person. Get medical

attention.

Notes to Physician Not Applicable

ES-5 PROPLOK SURFACTANT

Page 1 of 6

HESI100444
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 78

Flash Point/Range (C): 25

Flash Point Method: SETA

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): 6

Flammability Limits in Air - Upper (%): 36.5

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards May be ignited by heat, sparks or flames. Use water spray to cool fire exposed

surfaces. Closed containers may explode in fire. Decomposition in fire may produce

toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 3, Flammability 3, Reactivity 0

HMIS Ratings: Health 3, Flammability 3, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Wear self-contained breathing apparatus in

enclosed areas.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Remove ignition sources and work with nonsparking tools. Contain spill with sand or other inert materials. Scoop up and

remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse. Ground and bond containers

when transferring from one container to another.

Storage Information Store away from oxidizers. Store away from alkalis. Keep from heat, sparks, and

open flames. Keep container closed when not in use.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Positive pressure self-contained breathing apparatus if methanol is released.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

ES-5 PROPLOK SURFACTANT

Page 2 of 6

HESI100445
9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Clear colorless

Odor: Alcohol

pH: 2-3

Specific Gravity @ 20 C (Water=1): 1.068

Density @ 20 C (lbs./gallon): 8.90

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: 15

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): 150-300

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers. Strong alkalis.

Hazardous Decomposition

Products

Oxides of phosphorus. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation Causes severe respiratory irritation. May cause central nervous system depression

including headache, dizziness, drowsiness, incoordination, slowed reaction time,

slurred speech, giddiness and unconsciousness.

Skin Contact May cause severe skin irritation. May be absorbed through the skin and produce

effects similar to those caused by inhalation and/or ingestion.

Eye Contact May cause severe eye irritation. May cause eye burns.

Ingestion May be fatal or cause blindness if swallowed. May cause central nervous system

depression including headache, dizziness, drowsiness, muscular weakness,

incoordination, slowed reaction time, fatigue blurred vision, slurred speech,

giddiness, tremors and convulsions.

Aggravated Medical Conditions Skin disorders. Eye ailments.

ES-5 PROPLOK SURFACTANT

Page 3 of 6

HESI100446
Chronic Effects/Carcinogenicity Prolonged or repeated exposure may cause eye, blood, lung, liver, kidney, heart,

central nervous system and spleen damage.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Flammable Liquid, Corrosive, N.O.S., 3, (8), UN2924, III, (25.6 C)

(Contains Methanol, Phosphoric Acid Ester)

NAERG 132

Canadian TDG

Flammable Liquid, Corrosive, N.O.S.(Contains Methanol, Phosphoric Acid Ester), 3, (8), UN2924, III, (25.6 C)

ES-5 PROPLOK SURFACTANT

Page 4 of 6

HESI100447
ADR

UN2924,Flammable Liquid, Corrosive, N.O.S.(Contains Methanol, Phosphoric Acid Ester), 3, (8), III

Air Transportation

ICAO/IATA

UN2924,Flammable Liquid, Corrosive, N.O.S., 3, (8), III

(Contains Methanol, Phosphoric Acid Ester Solution)

Sea Transportation

IMDG

UN2924,Flammable Liquid, Corrosive, N.O.S.(Contains Methanol, Phosphoric Acid Ester), 3, (8), III, (25.6 C)

EmS F-E, S-C

Other Shipping Information

Labels: Flammable Liquid

Corrosive

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Methanol//67-56-1

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 3745 Gallons based on Methanol (CAS: 67-56-1).

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Ignitability D001

 Corrosivity D002

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

ES-5 PROPLOK SURFACTANT

Page 5 of 6

HESI100448
WHMIS Hazard Class B2 Flammable Liquids

E Corrosive Material

D1B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

ES-5 PROPLOK SURFACTANT

Page 6 of 6

HESI100449
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: EXPEDITE 225 CLEAN-UP SOLUTION

Revision Date: 03-Jan-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: EXPEDITE 225 CLEAN-UP SOLUTION

Synonyms: None

Chemical Family: Glycol Ether

Application: Solvent

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Acetic acid 64-19-7 5 - 10% 10 ppm 10 ppm

Ethylene glycol monobutyl

ether

111-76-2 30 - 60% 20 ppm 50 ppm

3. HAZARDS IDENTIFICATION

Hazard Overview May cause headache, dizziness, and other central nervous system effects. May be

harmful if swallowed. May be absorbed through the skin. May cause eye, skin, and

respiratory irritation.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

EXPEDITE 225 CLEAN-UP SOLUTION

Page 1 of 6

HESI100450
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): >200

Flash Point/Range (C): 98.9

Flash Point Method: PMCC

Autoignition Temperature (F): 446

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards May be ignited by heat, sparks or flames. Use water spray to cool fire exposed

surfaces. Closed containers may explode in fire. Decomposition in fire may produce

toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 1, Reactivity 0

HMIS Ratings: Flammability 1, Reactivity 0, Health 2

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Wear self-contained breathing apparatus in

enclosed areas.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse.

Storage Information Store away from oxidizers. Keep container closed when not in use.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Local exhaust ventilation should be used in areas without good cross ventilation.

Use in a well ventilated area.

Respiratory Protection Organic vapor respirator.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

EXPEDITE 225 CLEAN-UP SOLUTION

Page 2 of 6

HESI100451
9. PHYSICAL AND CHEMICAL PROPERTIES

Color: Clear Green

Odor: Vinegar

pH: 3.0

Specific Gravity @ 20 C (Water=1): 0.96

Density @ 20 C (lbs./gallon): 8.0

Bulk Density @ 20 C (lbs/ft3): 7.91

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers. Peroxides. Amphoteric metals such as aluminum, magnesium,

lead, tin, or zinc.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause central nervous system depression including headache, dizziness,

drowsiness, incoordination, slowed reaction time, slurred speech, giddiness and

unconsciousness.

May cause respiratory irritation.

Skin Contact May be absorbed through the skin and contribute to the symptoms listed under

ingestion. May cause skin irritation.

Eye Contact May cause eye irritation.

Ingestion May cause abdominal pain, vomiting, nausea, and diarrhea. May produce nervous

system effects such as feeling of weakness, unsteady walk, and dilation of blood

vessels.

Aggravated Medical Conditions Eye ailments. Skin disorders.

Chronic Effects/Carcinogenicity Prolonged or repeated exposure may cause fetal damage and testicular effects.

EXPEDITE 225 CLEAN-UP SOLUTION

Page 3 of 6

HESI100452
Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Slowly biodegradable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Not restricted

Canadian TDG

Not restricted

ADR Not restricted

Air Transportation

EXPEDITE 225 CLEAN-UP SOLUTION

Page 4 of 6

HESI100453
ICAO/IATA Not restricted

Sea Transportation

IMDG Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Glycol Ethers//111-76-2

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class D1A Very Toxic Materials

D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

EXPEDITE 225 CLEAN-UP SOLUTION

Page 5 of 6

HESI100454
Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

EXPEDITE 225 CLEAN-UP SOLUTION

Page 6 of 6

HESI100455
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: EXPEDITE 225 COMPONENT A

Revision Date: 05-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: EXPEDITE 225 COMPONENT A

Synonyms: None

Chemical Family: Blend

Application: Resin

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Epoxy resin 60 - 100% Not applicable Not applicable

Butyl glycidyl ether 2426-08-6 10 - 30% 3 ppm (S,SEN) 50 ppm

Butyl lactate 138-22-7 5 - 10% 5 ppm Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview Combustible. May cause eye and skin irritation. May cause headache, dizziness, and

other central nervous system effects. May be harmful if swallowed. May be absorbed

through the skin. May cause allergic skin reaction. Potential carcinogen.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

EXPEDITE 225 COMPONENT A

Page 1 of 6

HESI100456
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 166

Flash Point/Range (C): 74

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 3, Flammability 2, Reactivity 0

HMIS Ratings: Health 3, Flammability 2, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Wash hands after use. Launder

contaminated clothing before reuse.

Storage Information Store away from oxidizers. Keep from heat, sparks, and open flames. Keep container

closed when not in use. Product has a shelf life of 6 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Organic vapor respirator.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Clear light yellow

Odor: Mild

EXPEDITE 225 COMPONENT A

Page 2 of 6

HESI100457
9. PHYSICAL AND CHEMICAL PROPERTIES

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 1.16

Density @ 20 C (lbs./gallon): 9.66

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Insoluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Toxic fumes. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. May cause central nervous system depression

including headache, dizziness, drowsiness, incoordination, slowed reaction time,

slurred speech, giddiness and unconsciousness.

Skin Contact May cause severe skin irritation. May be absorbed through the skin and produce

effects similar to those caused by inhalation and/or ingestion. May cause an allergic

skin reaction.

Eye Contact May cause severe eye irritation.

Ingestion Irritation of the mouth, throat, and stomach. May cause abdominal pain, vomiting,

nausea, and diarrhea.

Aggravated Medical Conditions Skin disorders.

Chronic Effects/Carcinogenicity This product contains a potential carcinogen.

Other Information None known.

Toxicity Tests

EXPEDITE 225 COMPONENT A

Page 3 of 6

HESI100458
Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

DOT (Bulk)

Resin Solution, Combustible Liquid, UN1866, III

Classified in accordance with 49 CFR 172.101(d)(4)

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

EXPEDITE 225 COMPONENT A

Page 4 of 6

HESI100459
ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class B3 Combustible Liquids

D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

EXPEDITE 225 COMPONENT A

Page 5 of 6

HESI100460
Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

EXPEDITE 225 COMPONENT A

Page 6 of 6

HESI100461
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: EXPEDITE 225 COMPONENT B

Revision Date: 05-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: EXPEDITE 225 COMPONENT B

Synonyms: None

Chemical Family: Blend

Application: Hardener

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Phosphate ester 5 - 10% Not applicable Not applicable

Modified cycloaliphatic amine

adduct

Mixture 30 - 60% Not applicable Not applicable

Methanol 67-56-1 30 - 60% 200 ppm 200 ppm (S)

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause headache, dizziness, and

other central nervous system effects. May be fatal if swallowed. May cause

blindness. May be absorbed through the skin. May cause allergic skin reaction.

Repeated overexposure may cause liver and kidney effects. Flammable.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

EXPEDITE 225 COMPONENT B

Page 1 of 6

HESI100462
Notes to Physician Not Applicable

5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 55

Flash Point/Range (C): 12.8

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards May be ignited by heat, sparks or flames. Use water spray to cool fire exposed

surfaces. Closed containers may explode in fire. Decomposition in fire may produce

toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 3, Flammability 3, Reactivity 0

HMIS Ratings: Health 3, Flammability 3, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Wear self-contained breathing apparatus in

enclosed areas.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Remove ignition sources and work with nonsparking tools. Contain spill with sand or other inert materials. Scoop up and

remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse. Ground and bond containers

when transferring from one container to another.

Storage Information Store at temperatures between 32 and 200 F (0 and 93 C). Do not freeze. Store

away from oxidizers. Keep from heat, sparks, and open flames. Keep container

closed when not in use. Product has a shelf life of 6 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Positive pressure self-contained breathing apparatus if methanol is released.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

EXPEDITE 225 COMPONENT B

Page 2 of 6

HESI100463
Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Dark amber

Odor: Ammonia

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 1.06

Density @ 20 C (lbs./gallon): 8.83

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): 4.6

Solubility in Water (g/100ml): Partially soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers. Strong acids. Strong alkalis.

Hazardous Decomposition

Products

Oxides of nitrogen. Oxides of phosphorus. Acids. Aldehydes. Bromine. Hydrogen

bromide. Ketones. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause central nervous system depression including headache, dizziness,

drowsiness, incoordination, slowed reaction time, slurred speech, giddiness and

unconsciousness.

May cause liver damage. May cause kidney damage.

Skin Contact May cause an allergic skin reaction. May cause severe skin irritation. May be

absorbed through the skin and produce nervous system effects.

Eye Contact May cause eye burns.

EXPEDITE 225 COMPONENT B

Page 3 of 6

HESI100464
Ingestion May be fatal or cause blindness if swallowed. May cause central nervous system

depression including headache, dizziness, drowsiness, muscular weakness,

incoordination, slowed reaction time, fatigue blurred vision, slurred speech,

giddiness, tremors and convulsions.

Aggravated Medical Conditions Skin disorders. Eye ailments.

Chronic Effects/Carcinogenicity Prolonged or repeated exposure may cause eye, blood, lung, liver, kidney, heart,

central nervous system and spleen damage.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

EXPEDITE 225 COMPONENT B

Page 4 of 6

HESI100465
UN1866,Resin Solution, 3, II, (12.8 C)

NAERG 127

Canadian TDG

Resin Solution, 3, UN1866, II, (12.8 C)

ADR

UN1866,Resin Solution, 3, II

Air Transportation

ICAO/IATA

UN1866,Resin Solution, 3, II

Sea Transportation

IMDG

UN1866,Resin Solution, 3, II, (12.8 C)

EmS F-E, S-E

Other Shipping Information

Labels: Flammable Liquid

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Methanol//67-56-1

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 1524 Gallons based on Methanol (CAS: 67-56-1).

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Ignitability D001

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

EXPEDITE 225 COMPONENT B

Page 5 of 6

HESI100466
PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory Product contains one or more components not listed on inventory.

WHMIS Hazard Class B2 Flammable Liquids

D1A Very Toxic Materials

D1B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

EXPEDITE 225 COMPONENT B

Page 6 of 6

HESI100467
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: EXPEDITE 350 CLEAN-UP SOLUTION

Revision Date: 03-Jan-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: EXPEDITE 350 CLEAN-UP SOLUTION

Synonyms: None

Chemical Family: Glycol Ether

Application: Solvent

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Acetic acid 64-19-7 5 - 10% 10 ppm 10 ppm

Ethylene glycol monobutyl

ether

111-76-2 30 - 60% 20 ppm 50 ppm

3. HAZARDS IDENTIFICATION

Hazard Overview May cause headache, dizziness, and other central nervous system effects. May be

harmful if swallowed. May be absorbed through the skin. May cause eye, skin, and

respiratory irritation.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

EXPEDITE 350 CLEAN-UP SOLUTION

Page 1 of 6

HESI100468
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): >200

Flash Point/Range (C): 98.9

Flash Point Method: PMCC

Autoignition Temperature (F): 446

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards May be ignited by heat, sparks or flames. Use water spray to cool fire exposed

surfaces. Closed containers may explode in fire. Decomposition in fire may produce

toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 1, Reactivity 0

HMIS Ratings: Flammability 1, Reactivity 0, Health 2

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Wear self-contained breathing apparatus in

enclosed areas.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse.

Storage Information Store away from oxidizers. Keep container closed when not in use.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Local exhaust ventilation should be used in areas without good cross ventilation.

Use in a well ventilated area.

Respiratory Protection Organic vapor respirator.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

EXPEDITE 350 CLEAN-UP SOLUTION

Page 2 of 6

HESI100469
9. PHYSICAL AND CHEMICAL PROPERTIES

Color: Clear Green

Odor: Vinegar

pH: 3.0

Specific Gravity @ 20 C (Water=1): 0.96

Density @ 20 C (lbs./gallon): 8.0

Bulk Density @ 20 C (lbs/ft3): 7.91

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers. Peroxides. Amphoteric metals such as aluminum, magnesium,

lead, tin, or zinc.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause central nervous system depression including headache, dizziness,

drowsiness, incoordination, slowed reaction time, slurred speech, giddiness and

unconsciousness.

May cause respiratory irritation.

Skin Contact May be absorbed through the skin and contribute to the symptoms listed under

ingestion. May cause skin irritation.

Eye Contact May cause eye irritation.

Ingestion May cause abdominal pain, vomiting, nausea, and diarrhea. May produce nervous

system effects such as feeling of weakness, unsteady walk, and dilation of blood

vessels.

Aggravated Medical Conditions Eye ailments. Skin disorders.

Chronic Effects/Carcinogenicity Prolonged or repeated exposure may cause fetal damage and testicular effects.

EXPEDITE 350 CLEAN-UP SOLUTION

Page 3 of 6

HESI100470
Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Slowly biodegradable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Not restricted

Canadian TDG

Not restricted

ADR Not restricted

Air Transportation

EXPEDITE 350 CLEAN-UP SOLUTION

Page 4 of 6

HESI100471
ICAO/IATA Not restricted

Sea Transportation

IMDG Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Glycol Ethers//111-76-2

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class D1A Very Toxic Materials

D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

EXPEDITE 350 CLEAN-UP SOLUTION

Page 5 of 6

HESI100472
Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

EXPEDITE 350 CLEAN-UP SOLUTION

Page 6 of 6

HESI100473
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: EXPEDITE 350 COMPONENT A

Revision Date: 05-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: EXPEDITE 350 COMPONENT A

Synonyms: None

Chemical Family: Not determined

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Bisphenol A / Epichlorohydrin

resin

25068-38-6 30 - 60% Not applicable Not applicable

Methanol 67-56-1 10 - 30% 200 ppm 200 ppm (S)

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause headache, dizziness, and

other central nervous system effects. May cause blindness. May be absorbed

through the skin. Flammable.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin Remove contaminated clothing and launder before reuse. Wash with soap and

water. Get medical attention if irritation persists. Remove contaminated shoes and

discard.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion If swallowed, induce vomiting immediately by giving two glasses of water and sticking

fingers down throat; never give anything to an unconscious person. Get medical

attention.

Notes to Physician Not Applicable

EXPEDITE 350 COMPONENT A

Page 1 of 6

HESI100474
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 52

Flash Point/Range (C): 11

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): 6

Flammability Limits in Air - Upper (%): 36

Flammability Limits in Air - Upper (oz./ft3): 36

Fire Extinguishing Media Carbon Dioxide, Dry Chemicals, Foam.

Special Exposure Hazards May be ignited by heat, sparks or flames. Use water spray to cool fire exposed

surfaces. Closed containers may explode in fire. Decomposition in fire may produce

toxic gases. Runoff to sewer may cause fire or explosion hazard. Vapors are

heavier than air and may accumulate in low areas. Vapors may travel along the

ground to be ignited at distant locations.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 3, Reactivity 0

HMIS Ratings: Health 2, Flammability 3, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Wear self-contained breathing apparatus in

enclosed areas.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Remove ignition sources and work with nonsparking tools. Contain spill with sand or other inert materials. Scoop up and

remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse. Ground and bond containers

when transferring from one container to another.

Storage Information Store away from oxidizers. Keep from heat, sparks, and open flames. Keep container

closed when not in use. Product has a shelf life of 6 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Positive pressure self-contained breathing apparatus if methanol is released.

Hand Protection Butyl rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

EXPEDITE 350 COMPONENT A

Page 2 of 6

HESI100475
Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Clear light amber

Odor: Alcohol

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 1.12

Density @ 20 C (lbs./gallon): 9.33

Bulk Density @ 20 C (lbs/ft3): 69.82

Boiling Point/Range (F): 149Min: > 149

Boiling Point/Range (C): 65Min: > 65

Freezing Point/Range (F): 77

Freezing Point/Range (C): 25

Vapor Pressure @ 20 C (mmHg): < 96

Vapor Density (Air=1): > 1

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): > 1

Solubility in Water (g/100ml): Insoluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong acids. Strong alkalis. Do not expose to amines. Prolonged contact with

aluminum, lead, or zinc may liberate flammable hydrogen. Certain coatings, plastics,

and rubbers. Strong oxidizers.

Hazardous Decomposition

Products

Formaldehyde. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. May cause central nervous system depression

including headache, dizziness, drowsiness, incoordination, slowed reaction time,

slurred speech, giddiness and unconsciousness.

Skin Contact May cause skin defatting with prolonged exposure. May cause an allergic skin

reaction. May cause skin irritation. May be absorbed through the skin and produce

effects similar to those caused by inhalation and/or ingestion.

Eye Contact May cause moderate eye irritation.

EXPEDITE 350 COMPONENT A

Page 3 of 6

HESI100476
Ingestion May be fatal or cause blindness if swallowed. May cause central nervous system

depression including headache, dizziness, drowsiness, muscular weakness,

incoordination, slowed reaction time, fatigue blurred vision, slurred speech,

giddiness, tremors and convulsions.

Aggravated Medical Conditions Eye ailments. Skin disorders.

Chronic Effects/Carcinogenicity Prolonged or repeated exposure may cause eye, blood, lung, liver, kidney, heart,

central nervous system and spleen damage. Prolonged or repeated exposure may

cause embryo and fetus toxicity.

Other Information None known.

Toxicity Tests

Oral Toxicity: LD50: > 2000 mg/kg (Rat)

Dermal Toxicity: LD50: > 2000 mg/kg (Rabbit)

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

EXPEDITE 350 COMPONENT A

Page 4 of 6

HESI100477
DOT

UN1866,Resin Solution, 3, II, (11 C)

NAERG 127

Canadian TDG

Resin Solution, 3, UN1866, II, (11 C)

ADR

UN1866,Resin Solution, 3, II

Air Transportation

ICAO/IATA

UN1866,Resin Solution, 3, II

Sea Transportation

IMDG

UN1866,Resin Solution, 3, II, (11 C)

EmS F-E, S-E

Other Shipping Information

Labels: Flammable Liquid

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Methanol//67-56-1

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 6635 Gallons based on Methanol (CAS: 67-56-1).

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Ignitability D001

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

EXPEDITE 350 COMPONENT A

Page 5 of 6

HESI100478
MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class B2 Flammable Liquids

D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

EXPEDITE 350 COMPONENT A

Page 6 of 6

HESI100479
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: EXPEDITE 350 COMPONENT B

Revision Date: 05-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: EXPEDITE 350 COMPONENT B

Synonyms: None

Chemical Family: Amine

Application: Hardener

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

4,4`-Diaminodiphenyl sulfone 80-08-0 30 - 60% Not applicable Not applicable

Glycol ether 30 - 60% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May be harmful if swallowed. May

cause allergic skin reaction.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin Wash with soap and water. Get medical attention if irritation persists. Remove

contaminated clothing and launder before reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

EXPEDITE 350 COMPONENT B

Page 1 of 6

HESI100480
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): > 200

Flash Point/Range (C): > 93

Flash Point Method: TCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 1, Reactivity 0

HMIS Ratings: Health 1, Flammability 1, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Wash hands after use. Launder

contaminated clothing before reuse.

Storage Information Store away from oxidizers. Store in a dry location. Product has a shelf life of 6

months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Not normally needed. But if significant exposures are possible then the following

respirator is recommended:

Organic vapor respirator.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Amber

EXPEDITE 350 COMPONENT B

Page 2 of 6

HESI100481
9. PHYSICAL AND CHEMICAL PROPERTIES

Odor: Sweet hydrocarbon

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 1.147

Density @ 20 C (lbs./gallon): 9.554

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Partially soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None known.

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Oxides of nitrogen. Oxides of sulfur. Peroxides. Carbon monoxide and carbon

dioxide. Toxic fumes.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. May reduce the blood's ability to transport oxygen

(methemaglobinemia).

Skin Contact May cause skin irritation. May cause an allergic skin reaction.

Eye Contact May cause eye irritation.

Ingestion May be harmful if swallowed.

Aggravated Medical Conditions Respiratory disorders. Skin disorders.

Chronic Effects/Carcinogenicity Repeated overexposure may cause liver and kidney effects.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

EXPEDITE 350 COMPONENT B

Page 3 of 6

HESI100482
Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

EXPEDITE 350 COMPONENT B

Page 4 of 6

HESI100483
Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Glycol Ethers//111-77-3

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory Product contains one or more components not listed on inventory.

WHMIS Hazard Class D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

EXPEDITE 350 COMPONENT B

Page 5 of 6

HESI100484
Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

EXPEDITE 350 COMPONENT B

Page 6 of 6

HESI100485
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: EXPEDITE 550

Revision Date: 03-Jan-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: EXPEDITE 550

Synonyms: None

Chemical Family: Blend

Application: Resin

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Furfuryl alcohol 98-00-0 1-15 10 ppm 50 pm (S)

Ethylene glycol monobutyl

ether

111-76-2 14-29 20 ppm 50 ppm

Isopropanol 67-63-0 1 - 5% 200 ppm 400 ppm

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause headache, dizziness, and

other central nervous system effects. May be harmful if swallowed. May cause

allergic skin reaction. Flammable.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

EXPEDITE 550

Page 1 of 6

HESI100486
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 122

Flash Point/Range (C): 50

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): 1.8

Flammability Limits in Air - Upper (%): 16.3

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases. Vapors are heavier than air and may

accumulate in low areas. Vapors may travel along the ground to be ignited at distant

locations.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 2, Reactivity 0

HMIS Ratings: Flammability 2, Reactivity 0, Health 2

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse.

Storage Information Store away from oxidizers. Keep from heat, sparks, and open flames. Keep container

closed when not in use. Store at temperature below 68 F (20 C).

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Organic vapor respirator with a dust/mist filter.

Hand Protection Impervious rubber gloves. Nitrile gloves. Butyl rubber gloves. Neoprene gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

EXPEDITE 550

Page 2 of 6

HESI100487
9. PHYSICAL AND CHEMICAL PROPERTIES

Color: Dark brown

Odor: Furan

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 1.08

Density @ 20 C (lbs./gallon): 9.05

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not DeterminedMin: > 226

Boiling Point/Range (C): Not DeterminedMin: > 108

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): 1

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): 5

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): 1300 - 2000

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Hazardous polymerization will occur when product comes in contact with strong

acids or oxidizing agents.

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers. Strong acids.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. May cause central nervous system depression

including headache, dizziness, drowsiness, incoordination, slowed reaction time,

slurred speech, giddiness and unconsciousness.

Skin Contact May cause skin irritation. Harmful if absorbed through the skin.

Eye Contact May cause severe eye irritation.

Ingestion Irritation of the mouth, throat, and stomach. May cause abdominal pain, vomiting,

nausea, and diarrhea. May produce nervous system effects such as feeling of

weakness, unsteady walk, and dilation of blood vessels.

Aggravated Medical Conditions Skin disorders. Eye ailments.

Chronic Effects/Carcinogenicity Prolonged or repeated skin exposure may cause dermatitis.

EXPEDITE 550

Page 3 of 6

HESI100488
Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Slowly biodegradable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Resin Solution, 3, UN1866, III, (50 C)

NAERG 127

Canadian TDG

Resin Solution, 3, UN1866, III, (50 C)

ADR

UN1866,Resin Solution, 3, III

EXPEDITE 550

Page 4 of 6

HESI100489
Air Transportation

ICAO/IATA

UN1866,Resin Solution, 3, III

Sea Transportation

IMDG

UN1866,Resin Solution, 3, III, (50 C)

EmS F-E, S-E

Other Shipping Information

Labels: Flammable Liquid

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Fire Hazard

EPA SARA (313) Chemicals Isopropanol//67-63-0

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Ignitability D001

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class B3 Combustible Liquids

D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

EXPEDITE 550

Page 5 of 6

HESI100490
Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

EXPEDITE 550

Page 6 of 6

HESI100491
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: EXPEDITE 550 CLEAN-UP SOLUTION

Revision Date: 03-Jan-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: EXPEDITE 550 CLEAN-UP SOLUTION

Synonyms: None

Chemical Family: Glycol Ether Blend

Application: Solvent

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Sodium hydroxide 1310-73-2 1 - 5% 2 mg/m3 2 mg/m3

Ethylene glycol monobutyl

ether

111-76-2 10 - 30% 20 ppm 50 ppm

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye burns. May cause skin and respiratory irritation. May cause

headache, dizziness, and other central nervous system effects. May be harmful if

swallowed. May be absorbed through the skin. Combustible.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

EXPEDITE 550 CLEAN-UP SOLUTION

Page 1 of 6

HESI100492
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): >200

Flash Point/Range (C): >93.3

Flash Point Method: DIN 51758

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards May be ignited by heat, sparks or flames. Use water spray to cool fire exposed

surfaces. Closed containers may explode in fire. Decomposition in fire may produce

toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 3, Flammability 2, Reactivity 0

HMIS Ratings: Flammability 2, Reactivity 0, Health 3

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Wear self-contained breathing apparatus in

enclosed areas.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse.

Storage Information Store away from oxidizers. Keep from heat, sparks, and open flames. Keep container

closed when not in use.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Organic vapor respirator.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

EXPEDITE 550 CLEAN-UP SOLUTION

Page 2 of 6

HESI100493
9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Colorless

Odor: Mild

pH: 11.85

Specific Gravity @ 20 C (Water=1): 0.99

Density @ 20 C (lbs./gallon): 8.23

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Amphoteric metals such as aluminum, magnesium, lead, tin, or zinc. Strong

oxidizers. Peroxides.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation Causes severe respiratory irritation. May cause central nervous system depression

including headache, dizziness, drowsiness, incoordination, slowed reaction time,

slurred speech, giddiness and unconsciousness.

Skin Contact May be absorbed through the skin and contribute to the symptoms listed under

ingestion. May cause skin irritation. May cause skin burns on prolonged contact.

Eye Contact Causes severe eye burns which may not be immediately painful or visible.

Ingestion May cause abdominal pain, vomiting, nausea, and diarrhea. May produce nervous

system effects such as feeling of weakness, unsteady walk, and dilation of blood

vessels.

Aggravated Medical Conditions Eye ailments. Skin disorders.

EXPEDITE 550 CLEAN-UP SOLUTION

Page 3 of 6

HESI100494
Chronic Effects/Carcinogenicity Prolonged or repeated exposure may cause fetal damage and testicular effects.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Slowly biodegradable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Not restricted

Canadian TDG

Not restricted

ADR Not restricted

EXPEDITE 550 CLEAN-UP SOLUTION

Page 4 of 6

HESI100495
Air Transportation

ICAO/IATA Not restricted

Sea Transportation

IMDG Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Glycol Ethers//111-76-2

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class B3 Combustible Liquids

D1A Very Toxic Materials

D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

EXPEDITE 550 CLEAN-UP SOLUTION

Page 5 of 6

HESI100496
Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

EXPEDITE 550 CLEAN-UP SOLUTION

Page 6 of 6

HESI100497
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: FDP-S663-02

Revision Date: 03-Jan-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: FDP-S663-02

Synonyms: None

Chemical Family: Blend

Application: Resin

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Furfuryl alcohol 98-00-0 1-15 10 ppm 50 pm (S)

Ethylene glycol monobutyl

ether

111-76-2 14-29 20 ppm 50 ppm

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause headache, dizziness, and

other central nervous system effects. May be harmful if swallowed. May cause

allergic skin reaction. Combustible.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

FDP-S663-02

Page 1 of 6

HESI100498
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 171

Flash Point/Range (C): 77

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): 1.8

Flammability Limits in Air - Upper (%): 16.3

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases. Vapors are heavier than air and may

accumulate in low areas. Vapors may travel along the ground to be ignited at distant

locations.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 2, Reactivity 0

HMIS Ratings: Flammability 2, Reactivity 0, Health 2

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse.

Storage Information Store away from oxidizers. Keep from heat, sparks, and open flames. Keep container

closed when not in use. Store at temperature below 68 F (20 C).

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Organic vapor respirator with a dust/mist filter.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Dark brown

FDP-S663-02

Page 2 of 6

HESI100499
9. PHYSICAL AND CHEMICAL PROPERTIES

Odor: Furan

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 1.177

Density @ 20 C (lbs./gallon): 9.80

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not DeterminedMin: > 226

Boiling Point/Range (C): Not DeterminedMin: > 108

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): 1

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): 5

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): 1300 - 2000

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Hazardous polymerization will occur when product comes in contact with strong

acids or oxidizing agents.

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers. Strong acids.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. May cause central nervous system depression

including headache, dizziness, drowsiness, incoordination, slowed reaction time,

slurred speech, giddiness and unconsciousness.

Skin Contact May cause skin irritation. Harmful if absorbed through the skin.

Eye Contact May cause eye irritation.

Ingestion Irritation of the mouth, throat, and stomach. May cause abdominal pain, vomiting,

nausea, and diarrhea. May produce nervous system effects such as feeling of

weakness, unsteady walk, and dilation of blood vessels.

Aggravated Medical Conditions Skin disorders. Eye ailments.

Chronic Effects/Carcinogenicity Prolonged or repeated skin exposure may cause dermatitis.

Other Information None known.

FDP-S663-02

Page 3 of 6

HESI100500
Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Slowly biodegradable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Not restricted

DOT (Bulk)

Combustible Liquid, N.O.S., Combustible Liquid, NA1993, III

(Contains Furfuryl Alcohol, Ethylene Glycol Monobutyl Ether)

Canadian TDG

Not restricted

ADR Not restricted

Air Transportation

FDP-S663-02

Page 4 of 6

HESI100501
ICAO/IATA Not restricted

Sea Transportation

IMDG Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Fire Hazard

EPA SARA (313) Chemicals Not applicable.

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class B3 Combustible Liquids

D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

FDP-S663-02

Page 5 of 6

HESI100502
Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

FDP-S663-02

Page 6 of 6

HESI100503
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: FDP-S667C-02

Revision Date: 20-Oct-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: FDP-S667C-02

Synonyms: None

Chemical Family: Organic hydrocarbon

Application: Solvent

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Paraffinic solvent 60 - 100% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause headache, dizziness, and

other central nervous system effects. May be harmful if swallowed. Potential

carcinogen. Combustible.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Get medical attention! If vomiting occurs, keep head lower than hips to prevent

aspiration.

Notes to Physician Not Applicable

FDP-S667C-02

Page 1 of 6

HESI100504
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 176

Flash Point/Range (C): 80

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): 0.5

Flammability Limits in Air - Upper (%): 4.9

Fire Extinguishing Media Carbon Dioxide, Dry Chemicals, Foam.

Special Exposure Hazards Use water spray to cool fire exposed surfaces. Closed containers may explode in

fire. Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 1, Reactivity 0

HMIS Ratings: Health 1, Flammability 1, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse.

Storage Information Store away from oxidizers. Store in a cool well ventilated area. Keep from heat,

sparks, and open flames. Keep container closed when not in use. Product has a

shelf life of 24 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Not normally needed. But if significant exposures are possible then the following

respirator is recommended:

Organic vapor respirator with a dust/mist filter.

Hand Protection Impervious rubber gloves.

Skin Protection Normal work coveralls.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

FDP-S667C-02

Page 2 of 6

HESI100505
9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Clear colorless

Odor: Hydrocarbon

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 0.813

Density @ 20 C (lbs./gallon): 6.68

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 392

Boiling Point/Range (C): 200

Freezing Point/Range (F): -49

Freezing Point/Range (C): -45

Vapor Pressure @ 20 C (mmHg): 0.3

Vapor Density (Air=1): 7.1

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Insoluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): 3.04

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. May cause chemical pneumonia. May cause

central nervous system depression including headache, dizziness, drowsiness,

incoordination, slowed reaction time, slurred speech, giddiness and

unconsciousness.

Skin Contact Causes drying of the skin. May cause skin irritation.

Eye Contact May cause eye irritation.

Ingestion Irritation of the mouth, throat, and stomach. Aspiration into the lungs may cause

chemical pneumonitis including coughing, difficulty breathing, wheezing, coughing up

blood and pneumonia, which can be fatal. May cause central nervous system

depression including headache, dizziness, drowsiness, muscular weakness,

incoordination, slowed reaction time, fatigue blurred vision, slurred speech,

giddiness, tremors and convulsions.

FDP-S667C-02

Page 3 of 6

HESI100506
Aggravated Medical Conditions Skin disorders.

Chronic Effects/Carcinogenicity Contains petroleum distillates which have been shown to cause skin cancer in

laboratory animals.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

DOT (Bulk)

Petroleum Distillates, N.O.S., Combustible Liquid, UN1268, III

Classified in accordance with 49 CFR 172.101(d)(4)

FDP-S667C-02

Page 4 of 6

HESI100507
Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law Does not apply.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law Does not apply.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class B3 Combustible Liquids

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

FDP-S667C-02

Page 5 of 6

HESI100508
Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

FDP-S667C-02

Page 6 of 6

HESI100509
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: FDP-S704-03

Revision Date: 05-Jan-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: FDP-S704-03

Synonyms: None

Chemical Family: Not determined

Application: Non-ionic Surfactant

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Amine 60 - 100% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause eye and skin burns. May

cause respiratory irritation. May be harmful if swallowed.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention.

Eyes Immediately flush eyes with large amounts of water for at least 15 minutes. Get

immediate medical attention.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Treatment should be directed at preventing absorption, administering to symptoms

as they occur, and providing supportive therapy.

FDP-S704-03

Page 1 of 5

HESI100510
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not DeterminedMin: > 200

Flash Point/Range (C): Not DeterminedMin: > 93

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 1, Reactivity 0

HMIS Ratings: Health 2, Flammability 1, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid breathing vapors. Avoid contact with eyes, skin, or clothing. Wash hands after

use. Launder contaminated clothing before reuse. Material is slippery underfoot.

Storage Information Store away from oxidizers. Store away from acids. Store in a cool well ventilated

area. Keep container closed when not in use.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Not normally needed. But if significant exposures are possible then the following

respirator is recommended:

Organic vapor respirator.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Clear

FDP-S704-03

Page 2 of 5

HESI100511
9. PHYSICAL AND CHEMICAL PROPERTIES

Odor: Pungent

pH: 6.5 - 8

Specific Gravity @ 20 C (Water=1): 1.0927

Density @ 20 C (lbs./gallon): 9.1

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): < 0.01

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): 0.04

Viscosity, Dynamic @ 20 C (centipoise): 105 - 255

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Do not expose to heat or store at temperatures above 120 F (49 C).

Incompatibility (Materials to

Avoid)

Strong oxidizers. Strong acids.

Hazardous Decomposition

Products

Oxides of nitrogen. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation.

Skin Contact Causes severe skin irritation. May cause skin burns.

Eye Contact Causes severe eye irritation May cause eye burns.

Ingestion Irritation of the mouth, throat, and stomach. May cause abdominal pain, vomiting,

nausea, and diarrhea. Aspiration can be a hazard if this material is swallowed.

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

FDP-S704-03

Page 3 of 5

HESI100512
Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT Not restricted

Canadian TDG

Not restricted

ADR Not restricted

Air Transportation

ICAO/IATA Not restricted

Sea Transportation

IMDG Not restricted

Other Shipping Information

FDP-S704-03

Page 4 of 5

HESI100513
Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law Does not apply.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law Does not apply.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

FDP-S704-03

Page 5 of 5

HESI100514
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: FDP-S706-03

Revision Date: 05-Jan-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: FDP-S706-03

Synonyms: None

Chemical Family: Blend

Application: Additive

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Ethylene glycol 107-21-1 5 - 10% 100 mg/m3 50 ppm

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause headache, dizziness, and

other central nervous system effects. May cause allergic skin reaction. May cause

birth defects.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

FDP-S706-03

Page 1 of 5

HESI100515
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not DeterminedMin: > 200

Flash Point/Range (C): Not DeterminedMin: > 93

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 0, Reactivity 0

HMIS Ratings: Health 1, Flammability 0, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors.

Storage Information Store away from oxidizers. Store in a cool well ventilated area. Keep container

closed when not in use.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Not normally needed. But if significant exposures are possible then the following

respirator is recommended:

Organic vapor/acid gas respirator with a dust/mist filter.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: White

Odor: Mild

FDP-S706-03

Page 2 of 5

HESI100516
9. PHYSICAL AND CHEMICAL PROPERTIES

pH: 2.5-4.5

Specific Gravity @ 20 C (Water=1): 1.0

Density @ 20 C (lbs./gallon): 8.33

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Miscible

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. Excessive inhalation causes headache, dizziness,

nausea and incoordination.

Skin Contact May cause skin irritation. May cause an allergic skin reaction.

Eye Contact May cause eye irritation.

Ingestion Harmful if swallowed. May cause heart, kidney and brain disorders.

Aggravated Medical Conditions Liver disorders. Eye ailments. Skin disorders.

Chronic Effects/Carcinogenicity Prolonged or repeated exposure may cause kidney damage. Prolonged or repeated

exposure may cause embryo and fetus toxicity.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

FDP-S706-03

Page 3 of 5

HESI100517
Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT Not restricted

Canadian TDG

Not restricted

ADR Not restricted

Air Transportation

ICAO/IATA Not restricted

Sea Transportation

IMDG Not restricted

Other Shipping Information

Labels: None

FDP-S706-03

Page 4 of 5

HESI100518
15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Ethylene Glycol//107-21-1

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 10004 Gallons based on Ethylene glycol (CAS: 107-

21-1).

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 The California Proposition 65 regulations apply to this product.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

FDP-S706-03

Page 5 of 5

HESI100519
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: FDP-S714-04

Revision Date: 05-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: FDP-S714-04

Synonyms: None

Chemical Family: Organic Salt

Application: Stabilizer

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

1,2,3-Propanetricarboxyloc

acid, 2-hydroxy-, trisodium

salt, dihydrate

6132-04-3 60 - 100% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. Airborne dust may be explosive.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water.

Eyes Immediately flush eyes with large amounts of water for at least 15 minutes. Get

immediate medical attention.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

FDP-S714-04

Page 1 of 6

HESI100520
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not DeterminedMin: > 200

Flash Point/Range (C): Not DeterminedMin: > 93

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases. Organic dust in the presence of an

ignition source can be explosive in high concentrations. Good housekeeping

practices are required to minimize this potential.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 1, Reactivity 0

HMIS Ratings: Health 1, Flammability 1, Physical Hazard 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

None known.

Procedure for Cleaning /

Absorption

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid creating or inhaling dust.

Storage Information Store away from oxidizers. Keep from excessive heat. Keep container closed when

not in use. Product has a shelf life of 60 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection If engineering controls and work practices cannot keep exposure below occupational

exposure limits or if exposure is unknown, wear a NIOSH certified, European

Standard EN 149, or equivalent respirator when using this product. Selection of and

instruction on using all personal protective equipment, including respirators, should

be performed by an Industrial Hygienist or other qualified professional.

Not normally needed. But if significant exposures are possible then the following

respirator is recommended:

Dust/mist respirator. (95%)

Hand Protection Nitrile gloves.

Skin Protection Normal work coveralls.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

FDP-S714-04

Page 2 of 6

HESI100521
9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid Powder

Color: White

Odor: Odorless

pH: 7.5-9.5 (5%)

Specific Gravity @ 20 C (Water=1): 1.7

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): 302

Freezing Point/Range (C): 150

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): 72

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Temperature over 200 F (93 C).

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. May cause allergic respiratory reaction.

Skin Contact May cause mild skin irritation.

Eye Contact May cause eye irritation.

Ingestion Large doses may cause nausea, vomiting and diarrhea.

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

FDP-S714-04

Page 3 of 6

HESI100522
Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability BOD(5 Day): 364 mg/g, COD: 480 mg/g, TOD: 544 mg/g

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

FDP-S714-04

Page 4 of 6

HESI100523
ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

None

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law Does not apply.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law Does not apply.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class Un-Controlled

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

FDP-S714-04

Page 5 of 6

HESI100524
Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

FDP-S714-04

Page 6 of 6

HESI100525
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: FDP-S717-04

Revision Date: 05-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: FDP-S717-04

Synonyms: None

Chemical Family: Alcohol Blend

Application: Crosslinker

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Zirconium complex 30 - 60% 5 mg/m3 5 mg/m3

Methanol 67-56-1 30 - 60% 200 ppm 200 ppm (S)

Glycerine 56-81-5 5 - 10% 10 mg/m3 15 mg/m3

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause headache, dizziness, and

other central nervous system effects. May be harmful if swallowed. May cause

blindness. May be absorbed through the skin. Repeated overexposure may cause

liver and kidney effects. Flammable.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Drink one drinking glass (6 ounces) of a 40% alcoholic beverage (ethanol). Seek

medical attention.

Notes to Physician Not Applicable

FDP-S717-04

Page 1 of 6

HESI100526
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 52

Flash Point/Range (C): 11

Flash Point Method: TCC

Autoignition Temperature (F): 725

Autoignition Temperature (C): 385

Flammability Limits in Air - Lower (%): 6

Flammability Limits in Air - Upper (%): 36.5

Fire Extinguishing Media Carbon Dioxide, Dry Chemicals, Foam.

Special Exposure Hazards Use water spray to cool fire exposed surfaces. Closed containers may explode in

fire. Decomposition in fire may produce toxic gases. May be ignited by heat, sparks

or flames. Runoff to sewer may cause fire or explosion hazard. Vapors are heavier

than air and may accumulate in low areas. Vapors may travel along the ground to be

ignited at distant locations.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 3, Reactivity 0

HMIS Ratings: Health 2, Flammability 3, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Wear self-contained breathing apparatus in

enclosed areas.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Remove ignition sources and work with nonsparking tools. Contain spill with sand or other inert materials. Scoop up and

remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse. Ground and bond containers

when transferring from one container to another.

Storage Information Store away from oxidizers. Keep from heat, sparks, and open flames. Keep container

closed when not in use. Store at temperature below 68 F (20 C).

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Positive pressure self-contained breathing apparatus if methanol is released.

Hand Protection Neoprene gloves. Use Viton or 4H gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

FDP-S717-04

Page 2 of 6

HESI100527
Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Amber

Odor: Alcohol

pH: 9.5 (1%)

Specific Gravity @ 20 C (Water=1): 0.958

Density @ 20 C (lbs./gallon): 7.98

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 148

Boiling Point/Range (C): 64

Freezing Point/Range (F): -144

Freezing Point/Range (C): -98

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: 74

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause central nervous system depression including headache, dizziness,

drowsiness, incoordination, slowed reaction time, slurred speech, giddiness and

unconsciousness.

May cause respiratory irritation.

Skin Contact May cause skin irritation. May be absorbed through the skin and produce effects

similar to those caused by inhalation and/or ingestion. May cause skin defatting with

prolonged exposure.

Eye Contact May cause moderate eye irritation.

FDP-S717-04

Page 3 of 6

HESI100528
Ingestion May cause central nervous system depression including headache, dizziness,

drowsiness, muscular weakness, incoordination, slowed reaction time, fatigue

blurred vision, slurred speech, giddiness, tremors and convulsions. May be fatal or

cause blindness if swallowed.

Aggravated Medical Conditions Eye ailments. Skin disorders.

Chronic Effects/Carcinogenicity Prolonged or repeated exposure may cause eye, blood, lung, liver, kidney, heart,

central nervous system and spleen damage.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Resistant

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

FDP-S717-04

Page 4 of 6

HESI100529
UN1230,Methanol Solution, 3, (6.1), II, (11 C)

RQ (Methanol - 5683 kg.)

NAERG 131

Canadian TDG

Methanol Solution, 3, (6.1), UN1230, II, (11 C)

ADR

UN1230,Methanol Solution, 3, (6.1), II

Air Transportation

ICAO/IATA

UN1230,Methanol Solution, 3, (6.1), II

RQ (Methanol - 5683 kg.)

Sea Transportation

IMDG

UN1230,Methanol Solution, 3, (6.1), II, (11 C)

RQ (Methanol - 5683 kg.)

EmS F-E, S-D

Other Shipping Information

Labels: Flammable Liquid

Toxic

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Methanol//67-56-1

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 1253 gallons based on Methanol (CAS: 67-56-1).

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Ignitability D001

FDP-S717-04

Page 5 of 6

HESI100530
California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class D1B Toxic Materials

B2 Flammable Liquids

D2A Very Toxic Materials

D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

FDP-S717-04

Page 6 of 6

HESI100531
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: FDP-S718-04

Revision Date: 05-Jan-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: FDP-S718-04

Synonyms: None

Chemical Family: Blend

Application: Crosslinker

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Glycerine 56-81-5 5 - 10% 10 mg/m3 15 mg/m3

Methanol 67-56-1 30 - 60% 200 ppm 200 ppm (S)

Propanol 71-23-8 5 - 10% 100 ppm 200 ppm

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause headache, dizziness, and

other central nervous system effects. May be harmful if swallowed. May cause

blindness. May be absorbed through the skin. Repeated overexposure may cause

liver and kidney effects. Flammable.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Drink one drinking glass (6 ounces) of a 40% alcoholic beverage (ethanol). Seek

medical attention.

Notes to Physician Not Applicable

FDP-S718-04

Page 1 of 6

HESI100532
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 52

Flash Point/Range (C): 11

Flash Point Method: TCC

Autoignition Temperature (F): 725

Autoignition Temperature (C): 385

Flammability Limits in Air - Lower (%): 6

Flammability Limits in Air - Upper (%): 36.5

Fire Extinguishing Media Carbon Dioxide, Dry Chemicals, Foam.

Special Exposure Hazards Use water spray to cool fire exposed surfaces. Closed containers may explode in

fire. Decomposition in fire may produce toxic gases. May be ignited by heat, sparks

or flames. Runoff to sewer may cause fire or explosion hazard. Vapors are heavier

than air and may accumulate in low areas. Vapors may travel along the ground to be

ignited at distant locations.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 3, Reactivity 0

HMIS Ratings: Health 2, Flammability 3, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Wear self-contained breathing apparatus in

enclosed areas.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Remove ignition sources and work with nonsparking tools. Contain spill with sand or other inert materials. Scoop up and

remove.

7. HANDLING AND STORAGE

Handling Precautions Wash hands after use. Launder contaminated clothing before reuse. Ground and

bond containers when transferring from one container to another. Avoid contact with

eyes, skin, or clothing. Avoid breathing vapors.

Storage Information Store away from oxidizers. Keep from heat, sparks, and open flames. Keep container

closed when not in use. Store at temperature below 68 F (20 C).

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Positive pressure self-contained breathing apparatus if methanol is released.

Hand Protection Neoprene gloves. Use Viton or 4H gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

FDP-S718-04

Page 2 of 6

HESI100533
9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Light yellow to amber

Odor: Alcohol

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 0.958

Density @ 20 C (lbs./gallon): 7.98

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 148

Boiling Point/Range (C): 64

Freezing Point/Range (F): -144

Freezing Point/Range (C): -98

Vapor Pressure @ 20 C (mmHg): 48.5

Vapor Density (Air=1): Not Determined

Percent Volatiles: 67

Evaporation Rate (Butyl Acetate=1): 5.9

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): 6.37

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause central nervous system depression including headache, dizziness,

drowsiness, incoordination, slowed reaction time, slurred speech, giddiness and

unconsciousness.

May cause respiratory irritation.

Skin Contact May cause skin irritation. May be absorbed through the skin and produce effects

similar to those caused by inhalation and/or ingestion. May cause skin defatting with

prolonged exposure.

Eye Contact May cause moderate eye irritation.

Ingestion May cause central nervous system depression including headache, dizziness,

drowsiness, muscular weakness, incoordination, slowed reaction time, fatigue

blurred vision, slurred speech, giddiness, tremors and convulsions. May be fatal or

cause blindness if swallowed.

FDP-S718-04

Page 3 of 6

HESI100534
Aggravated Medical Conditions Eye ailments. Skin disorders.

Chronic Effects/Carcinogenicity Prolonged or repeated exposure may cause eye, blood, lung, liver, kidney, heart,

central nervous system and spleen damage.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Resistant

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

UN1993,Flammable Liquid, N.O.S.(Contains Methanol, Propanol), 3, II, (11 C)

NAERG 128

Canadian TDG

Flammable Liquid, N.O.S.(Contains Methanol, Propanol), 3, UN1993, II, (11 C)

FDP-S718-04

Page 4 of 6

HESI100535
ADR

UN1993,Flammable Liquid, N.O.S.(Contains Methanol, Propanol), 3, II

Air Transportation

ICAO/IATA

UN1993,Flammable Liquid, N.O.S., 3, II

(Contains Methanol, Propanol Solution)

Sea Transportation

IMDG

UN1993,Flammable Liquid, N.O.S.(Contains Methanol, Propanol), 3, II, (11 C)

EmS F-E, S-E

Other Shipping Information

Labels: Flammable Liquid

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Methanol//67-56-1

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 1582 gallons based on Methanol (CAS: 67-56-1).

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Ignitability D001

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

FDP-S718-04

Page 5 of 6

HESI100536
WHMIS Hazard Class B2 Flammable Liquids

D1B Toxic Materials

D2A Very Toxic Materials

D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

FDP-S718-04

Page 6 of 6

HESI100537
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: FDP-S721-04

Revision Date: 05-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: FDP-S721-04

Synonyms: None

Chemical Family: Blend

Application: Additive

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Propylene glycol 57-55-6 5 - 10% 10 mg/m3 15 mg/m3

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

FDP-S721-04

Page 1 of 5

HESI100538
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not DeterminedMin: > 200

Flash Point/Range (C): Not DeterminedMin: > 93

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 0, Reactivity 0

HMIS Ratings: Health 1, Flammability 0, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing.

Storage Information Store away from oxidizers. Store in a cool well ventilated area. Keep container

closed when not in use. Store at temperatures between 50 and 100 F (10 and 37.8

C). Do not freeze.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Not normally necessary.

Hand Protection Impervious rubber gloves.

Skin Protection Normal work coveralls. Rubber apron.

Eye Protection Safety glasses.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: White to Off white

Odor: Ester

FDP-S721-04

Page 2 of 5

HESI100539
9. PHYSICAL AND CHEMICAL PROPERTIES

pH: 3

Specific Gravity @ 20 C (Water=1): 1.1

Density @ 20 C (lbs./gallon): 9.16

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 212

Boiling Point/Range (C): 100

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: 56

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Not Determined

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong alkalis.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation.

Skin Contact May cause skin irritation.

Eye Contact May cause eye irritation.

Ingestion None known

Aggravated Medical Conditions Unknown

Chronic Effects/Carcinogenicity Not determined

Other Information None known.

Toxicity Tests

Oral Toxicity: LD50: > 2000 mg/kg (Rat)

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

FDP-S721-04

Page 3 of 5

HESI100540
Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: LC50 (48): > 100 mg/l

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

FDP-S721-04

Page 4 of 5

HESI100541
Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

None

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law Does not apply.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory Product contains one or more components not listed on inventory.

WHMIS Hazard Class Un-Controlled

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

FDP-S721-04

Page 5 of 5

HESI100542
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: FDP-S757-04

Revision Date: 05-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: FDP-S757-04

Synonyms: None

Chemical Family: Blend

Application: Conductivity Enhancer

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Heavy aromatic petroleum

naphtha

64742-94-5 5 - 10% 5 mg/m3 5 mg/m3

Methanol 67-56-1 1 - 5% 200 ppm 200 ppm (S)

Isopropanol 67-63-0 30 - 60% 200 ppm 400 ppm

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause headache, dizziness, and

other central nervous system effects. Repeated overexposure may cause liver and

kidney effects. Flammable. May be harmful if swallowed. May cause blindness. May

be absorbed through the skin.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse. Destroy or properly dispose of contaminated shoes.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Get medical attention! If vomiting occurs, keep head lower than hips to prevent

aspiration.

FDP-S757-04

Page 1 of 6

HESI100543
Notes to Physician Not Applicable

5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 66

Flash Point/Range (C): 18

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): 2

Flammability Limits in Air - Upper (%): 12.7

Fire Extinguishing Media Carbon Dioxide, Dry Chemicals, Foam.

Special Exposure Hazards May be ignited by heat, sparks or flames. Use water spray to cool fire exposed

surfaces. Closed containers may explode in fire. Decomposition in fire may produce

toxic gases. Do not allow runoff to enter waterways.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 3, Reactivity 0

HMIS Ratings: Health 2, Flammability 3, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Wear self-contained breathing apparatus in

enclosed areas.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Remove ignition sources and work with nonsparking tools. Contain spill with sand or other inert materials. Scoop up and

remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse. Ground and bond containers

when transferring from one container to another.

Storage Information Store away from oxidizers. Keep from heat, sparks, and open flames. Keep container

closed when not in use. Product has a shelf life of 24 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Organic vapor respirator.

Positive pressure self-contained breathing apparatus if methanol is released.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

FDP-S757-04

Page 2 of 6

HESI100544
Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Dark brown

Odor: Bland

pH: 7.5-9.8

Specific Gravity @ 20 C (Water=1): 0.903

Density @ 20 C (lbs./gallon): 7.52

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): < -40

Freezing Point/Range (C): < -40

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Insoluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause central nervous system depression including headache, dizziness,

drowsiness, incoordination, slowed reaction time, slurred speech, giddiness and

unconsciousness.

May cause respiratory irritation.

Skin Contact May cause skin irritation. May be absorbed through the skin and produce effects

similar to those caused by inhalation and/or ingestion.

Eye Contact Causes severe eye irritation which may damage tissue.

FDP-S757-04

Page 3 of 6

HESI100545
Ingestion May cause abdominal pain, vomiting, nausea, and diarrhea. Aspiration into the lungs

may cause chemical pneumonitis including coughing, difficulty breathing, wheezing,

coughing up blood and pneumonia, which can be fatal. May cause central nervous

system depression including headache, dizziness, drowsiness, muscular weakness,

incoordination, slowed reaction time, fatigue blurred vision, slurred speech,

giddiness, tremors and convulsions. May be fatal or cause blindness if swallowed.

Aggravated Medical Conditions Skin disorders. Eye ailments.

Chronic Effects/Carcinogenicity Prolonged or repeated exposure may cause eye, blood, lung, liver, kidney, heart,

central nervous system and spleen damage.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

FDP-S757-04

Page 4 of 6

HESI100546
DOT

UN1993,Flammable Liquid, N.O.S.(Contains Isopropanol, Heavy Aromatic Naphtha), 3, II, (18.9 C)

NAERG 128

Canadian TDG

Flammable Liquid, N.O.S.(Contains Isopropanol, Heavy Aromatic Naphtha), 3, UN1993, II, (18.9 C)

ADR

UN1993,Flammable Liquid, N.O.S.(Contains Isopropanol, Heavy Aromatic Naphtha), 3, II

Air Transportation

ICAO/IATA

UN1993,Flammable Liquid, N.O.S., 3, II

(Contains Isopropanol, Heavy Aromatic Naphtha Solution)

Sea Transportation

IMDG

UN1993,Flammable Liquid, N.O.S.(Contains Isopropanol, Heavy Aromatic Naphtha), 3, II, (18.9 C)

EmS F-E, S-E

Other Shipping Information

Labels: Flammable Liquid

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Isopropanol//67-63-0

Methanol//67-56-1

EPA CERCLA/Superfund

Reportable Spill Quantity

The EPA Reportable Spill Quantity is well above quantities required for any expected

use of this product.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Ignitability D001

FDP-S757-04

Page 5 of 6

HESI100547
California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class B2 Flammable Liquids

D2B Toxic Materials

D1A Very Toxic Materials

D1B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

FDP-S757-04

Page 6 of 6

HESI100548
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: FDP-S769-05

Revision Date: 03-Jan-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: FDP-S769-05

Synonyms: None

Chemical Family: Blend

Application: Iron Reducing Agent

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Hydrochloric acid 7647-01-0 10 - 30% 2 ppm 5 ppm

Stannous chloride, dihydrate 10025-69-1 30 - 60% Not applicable 2 mg/m3

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory burns. May be harmful if swallowed.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Treat symptomatically.

FDP-S769-05

Page 1 of 6

HESI100549
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not DeterminedMin: > 200

Flash Point/Range (C): Not DeterminedMin: > 93

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media All standard firefighting media.

Special Exposure Hazards May form explosive mixtures with strong alkalis. Decomposition in fire may produce

toxic gases. Use water spray to cool fire exposed surfaces.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 3, Flammability 1, Reactivity 1

HMIS Ratings: Flammability 1, Reactivity 1, Health 3

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Neutralize to pH of 6-8. Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse.

Storage Information Store away from alkalis. Store in a cool well ventilated area. Keep container closed

when not in use. Product has a shelf life of 24 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Acid gas respirator with a dust/mist filter.

Hand Protection Impervious rubber gloves. Nitrile gloves. Neoprene gloves. Polyvinylchloride gloves.

Skin Protection Full protective chemical resistant clothing.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists. Do NOT wear

contact lenses.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Clear light yellow

FDP-S769-05

Page 2 of 6

HESI100550
9. PHYSICAL AND CHEMICAL PROPERTIES

Odor: Acidic

pH: < 1

Specific Gravity @ 20 C (Water=1): 1.60

Density @ 20 C (lbs./gallon): 13.32

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): > 212

Boiling Point/Range (C): > 100

Freezing Point/Range (F): Not DeterminedMax: < -22

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): > 1

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None known.

Incompatibility (Materials to

Avoid)

Strong alkalis.

Hazardous Decomposition

Products

Flammable hydrogen gas. Chlorine. Stannic oxide

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation Causes severe respiratory irritation.

Skin Contact Causes severe burns.

Eye Contact Causes severe eye burns.

Ingestion Causes burns of the mouth, throat and stomach.

Aggravated Medical Conditions Skin disorders.

Chronic Effects/Carcinogenicity Prolonged or repeated exposure may cause lung damage. Prolonged, excessive

exposure may cause erosion of the teeth. Chronic overexposure to inorganic tin

compounds has resulted in Stannosis, a benign pneumoconiosis (dusty lung).

Chronic overexposure has not been associated with progressive fibrosis or

decreased pulmonary lung function. Stannosis has not been associated with illness

or decreased life expectancy.

Other Information None known.

Toxicity Tests

FDP-S769-05

Page 3 of 6

HESI100551
Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Corrosive Liquid, Acidic, Inorganic, N.O.S., 8, UN3264, II

(Stannic Chloride, Hydrochloric Acid)

NAERG 154

Canadian TDG

Corrosive Liquid, Acidic, Inorganic, N.O.S.(Stannic Chloride, Hydrochloric Acid), 8, UN3264, II

ADR

UN3264,Corrosive Liquid, Acidic, Inorganic, N.O.S.(Stannic Chloride, Hydrochloric Acid), 8, II

Air Transportation

ICAO/IATA

FDP-S769-05

Page 4 of 6

HESI100552
UN3264,Corrosive Liquid, Acidic, Inorganic, N.O.S., 8, II

(Contains Stannic Chloride, Hydrochloric Acid Solution)

Sea Transportation

IMDG

UN3264,Corrosive Liquid, Acidic, Inorganic, N.O.S.(Stannic Chloride, Hydrochloric Acid), 8, II

EmS F-A, S-B

Other Shipping Information

Labels: Corrosive

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Stannous Chloride Dihydrate (10025-69-1)

Hydrogen Chloride//7647-01-0

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 2942 Gallons of product base on Hydrochloric acid

(CAS: 7647-01-0)

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Corrosivity D002

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class E Corrosive Material

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

FDP-S769-05

Page 5 of 6

HESI100553
Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

FDP-S769-05

Page 6 of 6

HESI100554
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: FDP-S781-05

Revision Date: 03-Jan-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: FDP-S781-05

Synonyms: None

Chemical Family: Blend

Application: Friction Reducer

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Hydrotreated light petroleum

distillate

64742-47-8 10 - 30% 200 mg/m3 Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye and skin irritation. May cause headache, dizziness, and other central

nervous system effects. May be harmful if swallowed.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin Wash with soap and water. Get medical attention if irritation persists. Remove

contaminated clothing and launder before reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Get medical attention! If vomiting occurs, keep head lower than hips to prevent

aspiration.

Notes to Physician Not Applicable

FDP-S781-05

Page 1 of 6

HESI100555
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): > 200

Flash Point/Range (C): > 93

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases. Use water spray to cool fire exposed

surfaces.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 1, Reactivity 0

HMIS Ratings: Flammability 1, Reactivity 0, Health 1

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse. Material is slippery underfoot.

Storage Information Store away from oxidizers. Keep container closed when not in use. Store in a cool,

dry location. Store in a well ventilated area. Keep from freezing.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Not normally needed. But if significant exposures are possible then the following

respirator is recommended:

Organic vapor respirator.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

FDP-S781-05

Page 2 of 6

HESI100556
9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: White to Light yellow

Odor: Sweet hydrocarbon

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 1.03

Density @ 20 C (lbs./gallon): 8.58

Bulk Density @ 20 C (lbs/ft3): 64.2

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: 70

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Oxides of nitrogen. Carbon monoxide and carbon dioxide. Chlorine.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. In high air concentrations:

May cause central nervous system depression including headache, dizziness,

drowsiness, incoordination, slowed reaction time, slurred speech, giddiness and

unconsciousness.

Skin Contact May cause skin irritation.

Eye Contact May cause moderate eye irritation.

Ingestion Aspiration into the lungs may cause chemical pneumonitis including coughing,

difficulty breathing, wheezing, coughing up blood and pneumonia, which can be fatal.

Aggravated Medical Conditions None known.

FDP-S781-05

Page 3 of 6

HESI100557
Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Not restricted

Canadian TDG

Not restricted

ADR Not restricted

FDP-S781-05

Page 4 of 6

HESI100558
Air Transportation

ICAO/IATA Not restricted

Sea Transportation

IMDG Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class Un-Controlled

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

FDP-S781-05

Page 5 of 6

HESI100559
Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

FDP-S781-05

Page 6 of 6

HESI100560
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: FDP-S784-05

Revision Date: 03-Jan-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: FDP-S784-05

Synonyms: None

Chemical Family: Blend

Application: Surfactant

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

1,2,4 Trimethylbenzene 95-63-6 0 - 1% 25 ppm Not applicable

Naphthalene 91-20-3 0 - 1% 10 ppm 10 ppm

Heavy aromatic petroleum

naphtha

64742-94-5 10 - 30% 5 mg/m3 5 mg/m3

Ethanol 64-17-5 30 - 60% 1000 ppm 1000 ppm

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause headache, dizziness, and

other central nervous system effects. May be harmful if swallowed. Flammable.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin Wash with soap and water. Get medical attention if irritation persists. Remove

contaminated clothing and launder before reuse.

Eyes Check for and remove contact lenses if present. In case of contact, or suspected

contact, immediately flush eyes with plenty of water for at least 15 minutes and get

medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

FDP-S784-05

Page 1 of 6

HESI100561
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 57

Flash Point/Range (C): 14

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): 3.3

Flammability Limits in Air - Upper (%): 19

Fire Extinguishing Media Carbon Dioxide, Dry Chemicals, Foam.

Special Exposure Hazards Use water spray to cool fire exposed surfaces. Closed containers may explode in

fire. Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 3, Reactivity 0

HMIS Ratings: Health 2, Flammability 3, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Wear self-contained breathing apparatus in

enclosed areas.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Remove ignition sources and work with non-sparking tools. Isolate spill and stop

leak where safe. Contain spill with sand or other inert materials. Scoop up and

remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse. Ground and bond containers

when transferring from one container to another.

Storage Information Keep from heat, sparks, and open flames. Keep container closed when not in use.

Store in a cool well ventilated area.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Organic vapor respirator.

Hand Protection Impervious rubber gloves. Viton gloves

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

FDP-S784-05

Page 2 of 6

HESI100562
9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Amber

Odor: Alcohol

pH: 6 - 9.5

Specific Gravity @ 20 C (Water=1): .918

Density @ 20 C (lbs./gallon): 7.65

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 173.1

Boiling Point/Range (C): 78.4

Freezing Point/Range (F): -76.9

Freezing Point/Range (C): -60.51

Vapor Pressure @ 20 C (mmHg): 40 (etoh)

Vapor Density (Air=1): > 10

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): < 3.3

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Oxides of nitrogen. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. May cause central nervous system depression

including headache, dizziness, drowsiness, incoordination, slowed reaction time,

slurred speech, giddiness and unconsciousness.

Skin Contact May cause skin irritation.

Eye Contact May cause eye irritation.

Ingestion Irritation of the mouth, throat, and stomach. May cause abdominal pain, vomiting,

nausea, and diarrhea. Aspiration into the lungs may cause chemical pneumonitis

including coughing, difficulty breathing, wheezing, coughing up blood and

pneumonia, which can be fatal.

Aggravated Medical Conditions Skin disorders. Eye ailments.

FDP-S784-05

Page 3 of 6

HESI100563
Chronic Effects/Carcinogenicity

The International Agency for Research on Cancer (IARC) has evaluated naphthalene

and determined it to be a possible carcinogen to humans (Group 2B, based on

sufficient evidence in experimental animals and inadequate evidence in humans).

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: May be toxic to aquatic life.

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Flammable Liquid, N.O.S., 3, UN1993, II, (14 C)

(Contains Ethanol)

NAERG 128

FDP-S784-05

Page 4 of 6

HESI100564
Canadian TDG

Flammable Liquid, N.O.S.(Contains Ethanol), 3, UN1993, II, (14 C)

ADR

UN1993,Flammable Liquid, N.O.S.(Contains Ethanol), 3, II

Air Transportation

ICAO/IATA

UN1993,Flammable Liquid, N.O.S., 3, II

(Contains Ethanol Solution)

Sea Transportation

IMDG

UN1993,Flammable Liquid, N.O.S.(Contains Ethanol), 3, II, (14 C)

EmS F-E, S-E

Other Shipping Information

Labels: Flammable Liquid

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Naphthalene//91-20-3

1,2,4-Trimethylbenzene//95-63-6

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 658 Gallons based on Naphthalene (CAS: 91-20-3).

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Ignitability D001

California Proposition 65 The California Proposition 65 regulations apply to this product.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

FDP-S784-05

Page 5 of 6

HESI100565
Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class D2B Toxic Materials

B2 Flammable Liquids

D2A Very Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

FDP-S784-05

Page 6 of 6

HESI100566
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: FDP-S786-05

Revision Date: 03-Jan-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: FDP-S786-05

Synonyms: None

Chemical Family: Polysaccharide

Application: Gelling Agent

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Guar gum 9000-30-0 60 - 100% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause allergic respiratory

reaction. Airborne dust may be explosive.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Under normal conditions, first aid procedures are not required.

Notes to Physician Not Applicable

FDP-S786-05

Page 1 of 5

HESI100567
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not DeterminedMin: > 200

Flash Point/Range (C): Not DeterminedMin: > 93

Flash Point Method: Not Determined

Autoignition Temperature (F): 430

Autoignition Temperature (C): 221

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Lower (oz./ft3): 0.8

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases. Organic dust in the presence of an

ignition source can be explosive in high concentrations. Good housekeeping

practices are required to minimize this potential.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 0, Reactivity 0

HMIS Ratings: Flammability 0, Reactivity 0, Health 1

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

None known.

Procedure for Cleaning /

Absorption

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid creating or inhaling dust.

Storage Information Store in a cool, dry location.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Not normally needed. But if significant exposures are possible then the following

respirator is recommended:

Dust/mist respirator. (95%)

Hand Protection Normal work gloves.

Skin Protection Normal work coveralls.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions None known.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid

Color: Light tan

FDP-S786-05

Page 2 of 5

HESI100568
9. PHYSICAL AND CHEMICAL PROPERTIES

Odor: Bean

pH: 8.5

Specific Gravity @ 20 C (Water=1): 2

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): 36

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Forms gel

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None known.

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause allergic respiratory reaction. May cause respiratory irritation.

Skin Contact May cause mild skin irritation.

Eye Contact May cause eye irritation.

Ingestion None known

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

FDP-S786-05

Page 3 of 5

HESI100569
Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Readily biodegradable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Not restricted

Canadian TDG

Not restricted

ADR Not restricted

Air Transportation

ICAO/IATA Not restricted

Sea Transportation

IMDG Not restricted

Other Shipping Information

FDP-S786-05

Page 4 of 5

HESI100570
Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

None

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law Does not apply.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law Does not apply.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class Un-Controlled

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

FDP-S786-05

Page 5 of 5

HESI100571
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: FDP-S798-05

Revision Date: 03-Jan-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: FDP-S798-05

Synonyms: None

Chemical Family: Inorganic

Application: Additive

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Sodium perborate

tetrahydrate

10486-00-7 60 - 100% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause severe eye irritation. May cause skin and respiratory irritation. May be

harmful if swallowed.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin Wash with soap and water. Get medical attention if irritation persists. Remove

contaminated clothing and launder before reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

FDP-S798-05

Page 1 of 5

HESI100572
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases. Releases oxygen at high

temperatures.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 0, Reactivity 1

HMIS Ratings: Flammability 0, Reactivity 1, Health 2

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid creating or inhaling dust.

Storage Information Store away from combustibles. Store in a cool, dry location.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Dust/mist respirator. (95%)

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Dust proof goggles.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Powder

Color: White

Odor: Odorless

pH: 10 (1.5%)

Specific Gravity @ 20 C (Water=1): 0.82

FDP-S798-05

Page 2 of 5

HESI100573
9. PHYSICAL AND CHEMICAL PROPERTIES

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): 45

Boiling Point/Range (F): 266

Boiling Point/Range (C): 130

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): 320

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): 153.86

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Avoid contact with organic materials.

Incompatibility (Materials to

Avoid)

Contact with water. Organic matter. All flammables, especially petroleum products,

asphalt & other volatile flammables. Strong acids. Metal salts such as aluminum

chloride.

Hazardous Decomposition

Products

Oxygen.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation Causes irritation of the mouth, nose, and throat.

Skin Contact May cause skin irritation.

Eye Contact May cause severe eye irritation.

Ingestion May cause abdominal pain, vomiting, nausea, and diarrhea.

Aggravated Medical Conditions Skin disorders. Lung disorders. Eye ailments.

Chronic Effects/Carcinogenicity Prolonged or repeated exposure may cause gastrointestinal effects and muscular

dysfunction.

Other Information None known.

Toxicity Tests

Oral Toxicity: LD50: 2567 mg/kg (Rat)

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

FDP-S798-05

Page 3 of 5

HESI100574
Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Ames Test: Positive

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: TLM24: 160-320 mg/l (Oncorhynchus mykiss)

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Not restricted

Canadian TDG

Not restricted

ADR Not restricted

Air Transportation

ICAO/IATA Not restricted

Sea Transportation

IMDG Not restricted

Other Shipping Information

Labels: None

FDP-S798-05

Page 4 of 5

HESI100575
15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law Does not apply.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law Does not apply.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

FDP-S798-05

Page 5 of 5

HESI100576
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: FDP-S812A-05

Revision Date: 03-Jan-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: FDP-S812A-05

Synonyms: None

Chemical Family: Blend

Application: Crosslinker

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Diethanolamine 111-42-2 10 - 30% 2 mg/m3 Not applicable

Triethanolamine 102-71-6 30 - 60% 5 mg/m3 Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause severe eye irritation. May cause skin and respiratory irritation. May be

harmful if swallowed.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin Get medical attention if irritation persists. Wash with soap and water.

Eyes Immediately flush eyes with large amounts of water for at least 15 minutes. Get

immediate medical attention.

Ingestion If swallowed, induce vomiting immediately by giving two glasses of water and sticking

fingers down throat; never give anything to an unconscious person. Get medical

attention.

Notes to Physician Not Applicable

FDP-S812A-05

Page 1 of 5

HESI100577
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): > 300

Flash Point/Range (C): > 149

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media All standard firefighting media.

Special Exposure Hazards Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 0, Reactivity 0

HMIS Ratings: Flammability 0, Reactivity 0, Health 1

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Contain spill with sand or other inert materials. Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid creating or inhaling dust.

Storage Information Store away from alkalis.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Not normally needed. But if significant exposures are possible then the following

respirator is recommended:

Organic vapor/acid gas respirator.

Hand Protection Nitrile gloves. Polyvinylchloride gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Amber

Odor: Mild amine

pH: 8.3 (0.2%)

Specific Gravity @ 20 C (Water=1): 1.24

FDP-S812A-05

Page 2 of 5

HESI100578
9. PHYSICAL AND CHEMICAL PROPERTIES

Density @ 20 C (lbs./gallon): 9.5-10.33

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): 4

Freezing Point/Range (C): -20

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: May Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong alkalis.

Hazardous Decomposition

Products

Sulfuric acid. Oxides of sulfur.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation.

Skin Contact May cause moderate skin irritation.

Eye Contact May cause moderate to severe eye irritation.

Ingestion May be harmful if swallowed. Large doses may cause nausea, vomiting and

diarrhea.

Aggravated Medical Conditions Skin disorders. Eye ailments.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

FDP-S812A-05

Page 3 of 5

HESI100579
Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Not restricted

DOT (Bulk)

Environmentally Hazardous Substance, Liquid, N.O.S. (contains Diethanolamine), 9, UN3082, III

RQ (Diethanolamine) 45.4 KG

Canadian TDG

Not restricted

ADR Not restricted

Air Transportation

ICAO/IATA Not restricted

Sea Transportation

IMDG Not restricted

FDP-S812A-05

Page 4 of 5

HESI100580
Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals Diethanolamine//111-42-2

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 67 Gallons based on Diethanolamine (CAS: 111-42-

2).

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

FDP-S812A-05

Page 5 of 5

HESI100581
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: FDP-S812B-05

Revision Date: 03-Jan-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: FDP-S812B-05

Synonyms: None

Chemical Family: Carbonate

Application: Buffer

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Triethanolamine 102-71-6 10 - 30% 5 mg/m3 Not applicable

Potassium hydroxide 1310-58-3 5 - 10% 2 mg/m3 Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye and skin burns. May cause respiratory irritation. May be harmful if

swallowed.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin Remove contaminated clothing and launder before reuse. In case of contact,

immediately flush skin with plenty of soap and water for at least 15 minutes. Get

medical attention.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

FDP-S812B-05

Page 1 of 6

HESI100582
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 0, Reactivity 1

HMIS Ratings: Flammability 0, Reactivity 1, Health 2

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Neutralize to pH of 6-8. Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse.

Storage Information Store away from acids. Store in a cool well ventilated area. Keep container closed

when not in use.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Dust/mist respirator. (95%)

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Light amber

Odor: Odorless

pH: 11.1

FDP-S812B-05

Page 2 of 6

HESI100583
9. PHYSICAL AND CHEMICAL PROPERTIES

Specific Gravity @ 20 C (Water=1): 1.26 +/- 0.05

Density @ 20 C (lbs./gallon): 12.46

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): < -4

Freezing Point/Range (C): < -20

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong acids. Strong oxidizers. Contact with acids and lime dust will cause the

formation of potassium hydroxide and sodium hydroxide.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause chemical pneumonia. Causes severe respiratory burns.

Skin Contact Causes severe skin irritation. May cause skin burns.

Eye Contact Causes severe eye irritation May cause eye burns.

Ingestion Causes burns of the mouth, throat and stomach.

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

FDP-S812B-05

Page 3 of 6

HESI100584
Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Potassium Hydroxide Solution, 8, UN1814, III

NAERG 154

Canadian TDG

Potassium Hydroxide Solution, 8, UN1814, III

ADR

UN1814,Potassium Hydroxide Solution, 8, III

Air Transportation

ICAO/IATA

UN1814,Potassium Hydroxide Solution, 8, III

Sea Transportation

IMDG

UN1814,Potassium Hydroxide Solution, 8, III

FDP-S812B-05

Page 4 of 6

HESI100585
EmS F-A, S-B

Other Shipping Information

Labels: Corrosive

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 635 Gallons based on Potassium hydroxide (CAS:

1310-58-3).

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class E Corrosive Material

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

FDP-S812B-05

Page 5 of 6

HESI100586
***END OF MSDS***

FDP-S812B-05

Page 6 of 6

HESI100587
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: FDP-S815-05

Revision Date: 03-Jan-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: FDP-S815-05

Synonyms: None

Chemical Family: Blend

Application: Liquid Gel Concentrate

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Paraffinic solvent 30 - 60% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause headache, dizziness, and

other central nervous system effects. May cause allergic respiratory reaction. May be

harmful if swallowed. Potential carcinogen. Combustible.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Activated charcoal or gastric lavage may be advisable for significant ingestion.

FDP-S815-05

Page 1 of 6

HESI100588
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 120

Flash Point/Range (C): 49

Flash Point Method: TCC

Autoignition Temperature (F): 660

Autoignition Temperature (C): 349

Flammability Limits in Air - Lower (%): 0.7

Flammability Limits in Air - Upper (%): 7

Fire Extinguishing Media Carbon Dioxide, Dry Chemicals, Foam.

Special Exposure Hazards Use water spray to cool fire exposed surfaces. Closed containers may explode in

fire. Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 2, Reactivity 0

HMIS Ratings: Flammability 2, Reactivity 0, Health 1

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Remove ignition sources and work with nonsparking tools. Contain spill with sand or other inert materials. Scoop up and

remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse.

Storage Information Store away from oxidizers. Store in a cool well ventilated area. Keep from heat,

sparks, and open flames. Keep container closed when not in use. Product has a

shelf life of 24 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Not normally needed. But if significant exposures are possible then the following

respirator is recommended:

Organic vapor respirator with a dust/mist filter.

Hand Protection Impervious rubber gloves.

Skin Protection Normal work coveralls.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

FDP-S815-05

Page 2 of 6

HESI100589
9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Translucent Yellow

Odor: Hydrocarbon

pH: 6.5 - 7.5

Specific Gravity @ 20 C (Water=1): 0.87

Density @ 20 C (lbs./gallon): 7.25

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 392

Boiling Point/Range (C): 200

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): 70@37.8C

Vapor Density (Air=1): Not Determined

Percent Volatiles: 50-60

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Insoluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide. Hydrogen fluoride.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. May cause allergic respiratory reaction. May cause

chemical pneumonia. May cause central nervous system depression including

headache, dizziness, drowsiness, incoordination, slowed reaction time, slurred

speech, giddiness and unconsciousness.

Skin Contact May cause skin irritation. May cause an allergic skin reaction. May cause skin

defatting with prolonged exposure.

Eye Contact May cause eye irritation.

FDP-S815-05

Page 3 of 6

HESI100590
Ingestion Irritation of the mouth, throat, and stomach. Aspiration into the lungs may cause

chemical pneumonitis including coughing, difficulty breathing, wheezing, coughing up

blood and pneumonia, which can be fatal. May cause central nervous system

depression including headache, dizziness, drowsiness, muscular weakness,

incoordination, slowed reaction time, fatigue blurred vision, slurred speech,

giddiness, tremors and convulsions.

Aggravated Medical Conditions Skin disorders.

Chronic Effects/Carcinogenicity Contains petroleum distillates which have been shown to cause skin cancer in

laboratory animals.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

FDP-S815-05

Page 4 of 6

HESI100591
DOT

Petroleum Distillates, N.O.S., 3, UN1268, III, (49 C)

NAERG 128

Canadian TDG

Petroleum Distillates, N.O.S., 3, UN1268, III, (49 C)

ADR

UN1268,Petroleum Distillates, N.O.S., 3, III

Air Transportation

ICAO/IATA

UN1268,Petroleum Distillates, N.O.S., 3, III

Sea Transportation

IMDG

UN1268,Petroleum Distillates, N.O.S., 3, III, (49 C)

EmS F-E, S-E

Other Shipping Information

Labels: Flammable Liquid

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Ignitability D001

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law Does not apply.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law Does not apply.

Canadian Regulations

FDP-S815-05

Page 5 of 6

HESI100592
Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class B3 Combustible Liquids

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

FDP-S815-05

Page 6 of 6

HESI100593
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: FDP-S816-05

Revision Date: 05-Jan-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: FDP-S816-05

Synonyms: None

Chemical Family: Organic Salt

Application: Additive

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Alkylated quaternary chloride 30 - 60% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May be fatal if swallowed.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention.

Eyes Immediately flush eyes with large amounts of water for at least 15 minutes. Get

immediate medical attention.

Ingestion If swallowed, call a physician immediately. Only induce vomiting at the instruction of

a physician. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

FDP-S816-05

Page 1 of 6

HESI100594
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): > 200

Flash Point/Range (C): > 93

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases. Use water spray to cool fire exposed

surfaces.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 3, Flammability 1, Reactivity 0

HMIS Ratings: Health 3, Flammability 1, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Do NOT consume

food, drink, or tobacco in contaminated areas. Wash hands after use. Launder

contaminated clothing before reuse.

Storage Information Store away from oxidizers. Store in a cool well ventilated area. Keep container

closed when not in use. Product has a shelf life of 24 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Organic vapor/acid gas respirator with a dust/mist filter.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Clear light amber

Odor: Mild amine

FDP-S816-05

Page 2 of 6

HESI100595
9. PHYSICAL AND CHEMICAL PROPERTIES

pH: 3.5 (10%)

Specific Gravity @ 20 C (Water=1): 1.027

Density @ 20 C (lbs./gallon): 8.97

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 212

Boiling Point/Range (C): 100

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): 5-10

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Chlorine. Hydrogen chloride. Oxides of nitrogen. Carbon monoxide and carbon

dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation.

Skin Contact May cause skin irritation.

Eye Contact May cause eye burns.

Ingestion May be fatal if swallowed.

Aggravated Medical Conditions Eye ailments. Skin disorders.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: LD50: 220 mg/kg (Rat)

Dermal Toxicity: Not determined

FDP-S816-05

Page 3 of 6

HESI100596
Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Slowly biodegradable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:TLM96: 10.5 ppm (Mysidopsis bahia)

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

UN2810,Toxic Liquid, Organic, N.O.S.(Contains Tetramethylammonium Chloride), 6.1, III

NAERG 153

Canadian TDG

Toxic Liquid, Organic, N.O.S.(Contains Tetramethylammonium Chloride), 6.1, UN2810, III

ADR

UN2810,Toxic Liquid, Organic, N.O.S.(Contains Tetramethylammonium Chloride), 6.1, III

Air Transportation

ICAO/IATA

UN2810,Toxic Liquid, Organic, N.O.S., 6.1, III

(Contains Tetramethylammonium Chloride Solution)

Sea Transportation

FDP-S816-05

Page 4 of 6

HESI100597
IMDG

UN2810,Toxic Liquid, Organic, N.O.S.(Contains Tetramethylammonium Chloride), 6.1, III

EmS F-A, S-A

Other Shipping Information

Labels: Toxic

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 2381 gallons based on Sodium dodecylbenzene

sulfonate (CAS: 25155-30-0)

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class D1B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

FDP-S816-05

Page 5 of 6

HESI100598
Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

FDP-S816-05

Page 6 of 6

HESI100599
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: FDP-S819-05

Revision Date: 05-Jan-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: FDP-S819-05

Synonyms: None

Chemical Family: Blend

Application: Surfactant

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Isopropanol 67-63-0 10 - 30% 200 ppm 400 ppm

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause headache, dizziness, and

other central nervous system effects. May be harmful if swallowed. May be absorbed

through the skin. Repeated overexposure may cause liver and kidney effects.

Flammable.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes Check for and remove contact lenses if present. In case of contact, or suspected

contact, immediately flush eyes with plenty of water for at least 15 minutes and get

medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person. Get

medical attention! If vomiting occurs, keep head lower than hips to prevent

aspiration.

FDP-S819-05

Page 1 of 6

HESI100600
Notes to Physician Not Applicable

5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 70

Flash Point/Range (C): 21.1

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): 2

Flammability Limits in Air - Upper (%): 12.7

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards May be ignited by heat, sparks or flames. Use water spray to cool fire exposed

surfaces. Closed containers may explode in fire. Decomposition in fire may produce

toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 3, Reactivity 0

HMIS Ratings: Health 2, Flammability 3, Physical Hazard 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Wear self-contained breathing apparatus in

enclosed areas.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Remove ignition sources and work with nonsparking tools. Contain spill with sand or other inert materials. Scoop up and

remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse. Ground and bond containers

when transferring from one container to another.

Storage Information Store away from oxidizers. Keep from heat, sparks, and open flames. Keep container

closed when not in use. Product has a shelf life of 24 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

FDP-S819-05

Page 2 of 6

HESI100601
Respiratory Protection If engineering controls and work practices cannot keep exposure below occupational

exposure limits or if exposure is unknown, wear a NIOSH certified, European

Standard EN 149, or equivalent respirator when using this product. Selection of and

instruction on using all personal protective equipment, including respirators, should

be performed by an Industrial Hygienist or other qualified professional.

Organic vapor respirator.

In high concentrations, supplied air respirator or a self-contained breathing

apparatus.

Hand Protection Impervious rubber gloves. Nitrile gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Light amber

Odor: Alcohol

pH: 8.7

Specific Gravity @ 20 C (Water=1): 0.918

Density @ 20 C (lbs./gallon): 7.65

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 310

Boiling Point/Range (C): 154

Freezing Point/Range (F): < 0

Freezing Point/Range (C): < -17.8

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: 50-75

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Partially soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers. Iodine pentafluorethylene Strong acids. Strong alkalis.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

FDP-S819-05

Page 3 of 6

HESI100602
11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause central nervous system depression including headache, dizziness,

drowsiness, incoordination, slowed reaction time, slurred speech, giddiness and

unconsciousness.

May cause respiratory irritation.

Skin Contact May cause mild skin irritation. May cause skin defatting with prolonged exposure.

May be absorbed through the skin and produce effects similar to those caused by

inhalation and/or ingestion.

Eye Contact May cause moderate to severe eye irritation.

Ingestion Irritation of the mouth, throat, and stomach. May cause abdominal pain, vomiting,

nausea, and diarrhea. May cause central nervous system depression including

headache, dizziness, drowsiness, muscular weakness, incoordination, slowed

reaction time, fatigue blurred vision, slurred speech, giddiness, tremors and

convulsions.

Aggravated Medical Conditions Eye ailments. Skin disorders.

Chronic Effects/Carcinogenicity Repeated overexposure may cause liver and kidney effects.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

FDP-S819-05

Page 4 of 6

HESI100603
13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

UN1219,Isopropanol Solution, 3, II, (21.1 C)

NAERG 129

Canadian TDG

Isopropanol Solution, 3, UN1219, II, (21.1 C)

ADR

UN1219,Isopropanol Solution, 3, II

Air Transportation

ICAO/IATA

UN1219,Isopropanol Solution, 3, II

Sea Transportation

IMDG

UN1219,Isopropanol Solution, 3, II, (21.1 C)

EmS F-E, S-D

Other Shipping Information

Labels: Flammable Liquid

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

FDP-S819-05

Page 5 of 6

HESI100604
EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Ignitability D001

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class B2 Flammable Liquids

D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

FDP-S819-05

Page 6 of 6

HESI100605
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: FDP-S825-06

Revision Date: 05-Jan-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: FDP-S825-06

Synonyms: None

Chemical Family: Anionic Polymer

Application: Friction Reducer

Manufacturer/Supplier Halliburton Energy Services, Inc.

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Ammonium bisulfate 7783-20-2 10 - 30% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye and skin irritation.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Get medical attention! If vomiting occurs, keep head lower than hips to prevent

aspiration.

Notes to Physician Not Applicable

FDP-S825-06

Page 1 of 5

HESI100606
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not DeterminedMin: > 300

Flash Point/Range (C): Not DeterminedMin: > 148

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 0, Flammability 0, Reactivity 0

HMIS Ratings: Health 0, Flammability 0, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove. Do NOT spread spilled product with water.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors.

Storage Information Store away from oxidizers. Store in a cool well ventilated area. Keep container

closed when not in use.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Not normally needed. But if significant exposures are possible then the following

respirator is recommended:

Organic vapor respirator.

Hand Protection Impervious rubber gloves.

Skin Protection Normal work coveralls.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions None known.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: White

Odor: Mild

FDP-S825-06

Page 2 of 5

HESI100607
9. PHYSICAL AND CHEMICAL PROPERTIES

pH: 5.5 - 7.0

Specific Gravity @ 20 C (Water=1): 1.2 - 1.3

Density @ 20 C (lbs./gallon): 10.02 - 10.86

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 248

Boiling Point/Range (C): 120

Freezing Point/Range (F): < 5

Freezing Point/Range (C): < -15

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): 100 - 200

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide. Oxides of nitrogen.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation None known.

Skin Contact May cause mild skin irritation.

Eye Contact May cause mild eye irritation.

Ingestion None known

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: LD50: 7500 mg/kg (Rat)

Dermal Toxicity: Not determined

FDP-S825-06

Page 3 of 5

HESI100608
Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT Not restricted

Canadian TDG

Not restricted

ADR Not restricted

Air Transportation

ICAO/IATA Not restricted

Sea Transportation

IMDG Not restricted

Other Shipping Information

Labels: None

FDP-S825-06

Page 4 of 5

HESI100609
15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

None

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class Un-Controlled

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

FDP-S825-06

Page 5 of 5

HESI100610
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: FDP-S827-06

Revision Date: 05-Jan-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: FDP-S827-06

Synonyms: None

Chemical Family: Phosphorus compounds

Application: Corrosion Inhibitor

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Phosphine 60 - 100% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause respiratory irritation. May cause allergic skin reaction.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

FDP-S827-06

Page 1 of 5

HESI100611
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 356

Flash Point/Range (C): 180

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases. Organic dust in the presence of an

ignition source can be explosive in high concentrations. Good housekeeping

practices are required to minimize this potential.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 1, Reactivity 0

HMIS Ratings: Health 2, Flammability 1, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing.

Storage Information Store in a dry location. Store in a cool well ventilated area. Keep container closed

when not in use. Product has a shelf life of 24 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Not normally needed. But if significant exposures are possible then the following

respirator is recommended:

Dust/mist respirator. (95%)

Hand Protection Impervious rubber gloves.

Skin Protection Normal work coveralls.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Powder

FDP-S827-06

Page 2 of 5

HESI100612
9. PHYSICAL AND CHEMICAL PROPERTIES

Color: White

Odor: Mild

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 1.194

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 383-401

Boiling Point/Range (C): 195-205

Freezing Point/Range (F): 173-179

Freezing Point/Range (C): 78.5-81.5

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): 9

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Insoluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: 2.587-5.69

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Oxides of nitrogen. Carbon monoxide and carbon dioxide. Phosphines.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause mild respiratory irritation. May cause Central Nervous System effects.

Skin Contact Prolonged or repeated contact may cause skin irritation. May cause an allergic skin

reaction.

Eye Contact None known.

Ingestion May cause central nervous system effects.

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: LD50: > 5000 mg/kg (Rat)

FDP-S827-06

Page 3 of 5

HESI100613
Dermal Toxicity: LD50: > 3000 mg/kg (Rabbit)

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not readily biodegradable.

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: TLM96: > 5000 mg/l (Golden orfe)

Acute Crustaceans Toxicity:EC50(48 Hour): 0.6 mg/l (Daphnia magna)

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT Not restricted

Canadian TDG

Not restricted

ADR Not restricted

Air Transportation

ICAO/IATA Not restricted

Sea Transportation

IMDG Not restricted

Other Shipping Information

FDP-S827-06

Page 4 of 5

HESI100614
Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

None

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law Does not apply.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law Does not apply.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class Un-Controlled

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

FDP-S827-06

Page 5 of 5

HESI100615
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: FDP-S828-06

Revision Date: 05-Jan-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: FDP-S828-06

Synonyms: None

Chemical Family: Polysaccharide

Application: Gelling Agent

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Guar gum 9000-30-0 60 - 100% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause allergic respiratory

reaction. Airborne dust may be explosive.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Under normal conditions, first aid procedures are not required.

Notes to Physician Not Applicable

FDP-S828-06

Page 1 of 5

HESI100616
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): > 200

Flash Point/Range (C): > 94

Flash Point Method: Not Determined

Autoignition Temperature (F): 430

Autoignition Temperature (C): 221

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Lower (oz./ft3): 0.8

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases. Organic dust in the presence of an

ignition source can be explosive in high concentrations. Good housekeeping

practices are required to minimize this potential.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 1, Reactivity 0

HMIS Ratings: Health 1, Flammability 1, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

None known.

Procedure for Cleaning /

Absorption

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid creating or inhaling dust.

Storage Information Store in a cool, dry location.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Not normally needed. But if significant exposures are possible then the following

respirator is recommended:

Dust/mist respirator. (95%)

Hand Protection Normal work gloves.

Skin Protection Normal work coveralls.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions None known.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Powder

FDP-S828-06

Page 2 of 5

HESI100617
9. PHYSICAL AND CHEMICAL PROPERTIES

Color: Off white

Odor: Bean

pH: 6.5-7.5 (1%)

Specific Gravity @ 20 C (Water=1): 1.30

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): 29.07

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None known.

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause allergic respiratory reaction. May cause respiratory irritation.

Skin Contact May cause mild skin irritation.

Eye Contact May cause eye irritation.

Ingestion None known

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

FDP-S828-06

Page 3 of 5

HESI100618
Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Slowly biodegradable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT Not restricted

Canadian TDG

Not restricted

ADR Not restricted

Air Transportation

ICAO/IATA Not restricted

Sea Transportation

IMDG Not restricted

Other Shipping Information

FDP-S828-06

Page 4 of 5

HESI100619
Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law Does not apply.

Canadian Regulations

Canadian DSL Inventory Product contains one or more components not listed on inventory.

WHMIS Hazard Class Un-Controlled

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

FDP-S828-06

Page 5 of 5

HESI100620
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: FDP-S829-06

Revision Date: 05-Jan-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: FDP-S829-06

Synonyms: None

Chemical Family: Salt Solution

Application: Additive

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Sodium chloride 7647-14-5 10 - 30% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May be harmful if swallowed.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion If swallowed, give at least 3-4 glasses of water, but do not induce vomiting. Do not

give anything by mouth to an unconscious or convulsing person. Get medical

attention.

Notes to Physician Not Applicable

FDP-S829-06

Page 1 of 5

HESI100621
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): > 212

Flash Point/Range (C): > 93

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media All standard firefighting media.

Special Exposure Hazards Not applicable.

Special Protective Equipment for

Fire-Fighters

Not applicable.

NFPA Ratings: Health 1, Flammability 0, Reactivity 0

HMIS Ratings: Health 1, Flammability 0, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing.

Storage Information Store in a cool, dry location. Keep container closed when not in use.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Not normally needed. But if significant exposures are possible then the following

respirator is recommended:

Dust/mist respirator. (95%)

Hand Protection Impervious rubber gloves.

Skin Protection Normal work coveralls.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions None known.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Clear to hazy

Odor: Odorless

pH: 9.1

Specific Gravity @ 20 C (Water=1): 1.18

FDP-S829-06

Page 2 of 5

HESI100622
9. PHYSICAL AND CHEMICAL PROPERTIES

Density @ 20 C (lbs./gallon): 9.83

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): 747 (100C)

Vapor Density (Air=1): Not Determined

Percent Volatiles: 77.99

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong acids. Strong oxidizers. Bromine trifluoride. Sulfuric acid.

Hazardous Decomposition

Products

None known.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation.

Skin Contact May cause skin irritation.

Eye Contact May cause eye irritation.

Ingestion In large amounts: May cause abdominal pain, vomiting, nausea, and diarrhea. May

affect the heart and cardiovascular system.

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

FDP-S829-06

Page 3 of 5

HESI100623
Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not applicable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT Not restricted

Canadian TDG

Not restricted

ADR Not restricted

Air Transportation

ICAO/IATA Not restricted

Sea Transportation

IMDG Not restricted

Other Shipping Information

Labels: None

FDP-S829-06

Page 4 of 5

HESI100624
15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law Does not apply.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law Does not apply.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class Un-Controlled

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

FDP-S829-06

Page 5 of 5

HESI100625
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: FDP-S839-06

Revision Date: 05-Jan-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: FDP-S839-06

Synonyms: None

Chemical Family: Blend

Application: Crosslinker

Manufacturer/Supplier Halliburton Energy Services, Inc.

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Potassium formate 590-29-4 30 - 60% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

FDP-S839-06

Page 1 of 6

HESI100626
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media All standard firefighting media.

Special Exposure Hazards Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 0, Reactivity 0

HMIS Ratings: Health 1, Flammability 0, Physical Hazard 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Material is slippery underfoot.

Storage Information Store in a cool well ventilated area. Keep container closed when not in use.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Local exhaust ventilation should be used in areas without good cross ventilation.

Respiratory Protection If engineering controls and work practices cannot keep exposure below occupational

exposure limits or if exposure is unknown, wear a NIOSH certified, European

Standard EN 149, or equivalent respirator when using this product. Selection of and

instruction on using all personal protective equipment, including respirators, should

be performed by an Industrial Hygienist or other qualified professional.

Not normally needed. But if significant exposures are possible then the following

respirator is recommended:

Dust/mist respirator. (95%)

Hand Protection Neoprene gloves. Rubber gloves. Vinyl gloves.

Skin Protection Rubber apron.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions Eyewash fountains and safety showers must be easily accessible. Rubber boots

FDP-S839-06

Page 2 of 6

HESI100627
9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Tan

Odor: Slight

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 1.41

Density @ 20 C (lbs./gallon): 11.75

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not DeterminedMin: > 212

Boiling Point/Range (C): Not DeterminedMin: > 100

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Slightly soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None known.

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye and skin contact.

Inhalation May cause respiratory irritation.

Skin Contact Prolonged or repeated contact may cause skin irritation.

Eye Contact May cause eye irritation.

Ingestion Irritation of the mouth, throat, and stomach. Large doses may cause nausea,

vomiting and diarrhea.

Aggravated Medical Conditions Skin disorders.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

FDP-S839-06

Page 3 of 6

HESI100628
Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT Not restricted

Canadian TDG

Not restricted

ADR Not restricted

Air Transportation

ICAO/IATA Not restricted

Sea Transportation

FDP-S839-06

Page 4 of 6

HESI100629
IMDG Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 The California Proposition 65 regulations apply to this product.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class Un-Controlled

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

FDP-S839-06

Page 5 of 6

HESI100630
***END OF MSDS***

FDP-S839-06

Page 6 of 6

HESI100631
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: FDP-S847-06

Revision Date: 05-Jan-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: FDP-S847-06

Synonyms: None

Chemical Family: Polymer

Application: Viscosifier

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Polylactide resin 90 - 100% 10 mg/m3 15 mg/m3

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion If swallowed, induce vomiting immediately by giving two glasses of water and sticking

fingers down throat; never give anything to an unconscious person. Get medical

attention.

Notes to Physician Not Applicable

FDP-S847-06

Page 1 of 6

HESI100632
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Carbon Dioxide, Dry Chemicals, Foam.

Special Exposure Hazards Decomposition in fire may produce toxic gases. Organic dust in the presence of an

ignition source can be explosive in high concentrations. Good housekeeping

practices are required to minimize this potential.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 1, Reactivity 0

HMIS Ratings: Health 1, Flammability 1, Physical Hazard 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresSpills of this product are very slippery. Use appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Slippery when wet. Avoid creating or

inhaling dust. Avoid dust accumulations.

Storage Information Store away from oxidizers. Store in a cool, dry location. Use good housekeeping in

storage and work areas to prevent accumulation of dust. Close container when not

in use. Store between 40.5 F (4.7 C) and 120.5 F (49 C).

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection If engineering controls and work practices cannot keep exposure below occupational

exposure limits or if exposure is unknown, wear a NIOSH certified, European

Standard EN 149, or equivalent respirator when using this product. Selection of and

instruction on using all personal protective equipment, including respirators, should

be performed by an Industrial Hygienist or other qualified professional.

Not normally needed. But if significant exposures are possible then the following

respirator is recommended:

Dust/mist respirator. (95%)

Hand Protection Normal work gloves.

Skin Protection Normal work coveralls.

Eye Protection Wear safety glasses or goggles to protect against exposure.

FDP-S847-06

Page 2 of 6

HESI100633
Other Precautions None known.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Powder

Color: White to yellow

Odor: Sweet

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 1.25

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Insoluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Temperature over 440 F (240 C).

Incompatibility (Materials to

Avoid)

Strong oxidizers. Strong alkalis.

Hazardous Decomposition

Products

Toxic fumes. Aldehydes. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause mild respiratory irritation.

Skin Contact Prolonged or repeated contact may cause slight skin irritation.

Eye Contact May cause eye irritation.

Ingestion Irritation of the mouth, throat, and stomach. Large doses may cause nausea,

vomiting and diarrhea.

Aggravated Medical Conditions None known.

FDP-S847-06

Page 3 of 6

HESI100634
Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: LD50: > 5000 mg/kg (Rat)

Dermal Toxicity: LD50: > 2000 mg/kg (Rabbit)

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Biodegradable

Bio-accumulation Will not bio-accumulate.

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: EC50: >1100 mg/l

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT Not restricted

Canadian TDG

Not restricted

ADR Not restricted

FDP-S847-06

Page 4 of 6

HESI100635
Air Transportation

ICAO/IATA Not restricted

Sea Transportation

IMDG Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

None

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law Does not apply.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law Does not apply.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class Un-Controlled

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

FDP-S847-06

Page 5 of 6

HESI100636
Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

FDP-S847-06

Page 6 of 6

HESI100637
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: FDP-S855-07

Revision Date: 05-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: FDP-S855-07

Synonyms: None

Chemical Family: Blend

Application: Surfactant

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Isopropanol 67-63-0 10 - 30% 200 ppm 400 ppm

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause headache, dizziness, and

other central nervous system effects. May be harmful if swallowed. May be absorbed

through the skin. Repeated overexposure may cause liver and kidney effects.

Flammable.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin Remove contaminated clothing and launder before reuse. In case of contact,

immediately flush skin with plenty of soap and water for at least 15 minutes. Get

medical attention.

Eyes Check for and remove contact lenses if present. In case of contact, or suspected

contact, immediately flush eyes with plenty of water for at least 15 minutes and get

medical attention immediately after flushing.

Ingestion Get medical attention! If vomiting occurs, keep head lower than hips to prevent

aspiration. Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk

and seek medical attention. Never give anything by mouth to an unconscious

person.

FDP-S855-07

Page 1 of 6

HESI100638
Notes to Physician Not Applicable

5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 70

Flash Point/Range (C): 21.1

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): 2

Flammability Limits in Air - Upper (%): 12.7

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Use water spray to cool fire exposed surfaces. Closed containers may explode in

fire. Decomposition in fire may produce toxic gases. May be ignited by heat, sparks

or flames.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 3, Reactivity 0

HMIS Ratings: Health 2, Flammability 3, Physical Hazard 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Wear self-contained breathing apparatus in

enclosed areas.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Scoop up and remove. Contain spill with sand or other inert materials. Isolate spill

and stop leak where safe. Remove ignition sources and work with non-sparking

tools.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse. Ground and bond containers

when transferring from one container to another.

Storage Information Store away from oxidizers. Keep from heat, sparks, and open flames. Keep container

closed when not in use. Product has a shelf life of 24 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

FDP-S855-07

Page 2 of 6

HESI100639
Respiratory Protection If engineering controls and work practices cannot keep exposure below occupational

exposure limits or if exposure is unknown, wear a NIOSH certified, European

Standard EN 149, or equivalent respirator when using this product. Selection of and

instruction on using all personal protective equipment, including respirators, should

be performed by an Industrial Hygienist or other qualified professional.

Organic vapor respirator.

In high concentrations, supplied air respirator or a self-contained breathing

apparatus.

Hand Protection Nitrile gloves. Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Light amber

Odor: Alcohol

pH: 8.7

Specific Gravity @ 20 C (Water=1): 0.924

Density @ 20 C (lbs./gallon): 7.70

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 310

Boiling Point/Range (C): 154

Freezing Point/Range (F): < 0

Freezing Point/Range (C): < -17.8

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: 50-75

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Partially soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Iodine pentafluorethylene Strong acids. Strong alkalis. Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

FDP-S855-07

Page 3 of 6

HESI100640
11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause central nervous system depression including headache, dizziness,

drowsiness, incoordination, slowed reaction time, slurred speech, giddiness and

unconsciousness.

May cause respiratory irritation.

Skin Contact May cause skin defatting with prolonged exposure. May be absorbed through the

skin and produce effects similar to those caused by inhalation and/or ingestion. May

cause mild skin irritation.

Eye Contact May cause moderate to severe eye irritation.

Ingestion Irritation of the mouth, throat, and stomach. May cause abdominal pain, vomiting,

nausea, and diarrhea. May cause central nervous system depression including

headache, dizziness, drowsiness, muscular weakness, incoordination, slowed

reaction time, fatigue blurred vision, slurred speech, giddiness, tremors and

convulsions.

Aggravated Medical Conditions Eye ailments. Skin disorders.

Chronic Effects/Carcinogenicity Repeated overexposure may cause liver and kidney effects.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

FDP-S855-07

Page 4 of 6

HESI100641
13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

UN1219,Isopropanol Solution, 3, II, (21.1 C)

NAERG 129

Canadian TDG

Isopropanol Solution, 3, UN1219, II, (21.1 C)

ADR

UN1219,Isopropanol Solution, 3, II

Air Transportation

ICAO/IATA

UN1219,Isopropanol Solution, 3, II

Sea Transportation

IMDG

UN1219,Isopropanol Solution, 3, II, (21.1 C)

EmS F-E, S-D

Other Shipping Information

Labels: Flammable Liquid

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory Product contains one or more components not listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

FDP-S855-07

Page 5 of 6

HESI100642
EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Ignitability D001

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory Product contains one or more components not listed on inventory.

WHMIS Hazard Class D2B Toxic Materials

B2 Flammable Liquids

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

FDP-S855-07

Page 6 of 6

HESI100643
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: FDP-S863A-07

Revision Date: 05-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: FDP-S863A-07

Synonyms: None

Chemical Family: Blend

Application: Resin

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Epoxy resin 5 - 10% Not applicable Not applicable

Potassium chloride 7447-40-7 1 - 5% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause allergic skin reaction.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

FDP-S863A-07

Page 1 of 6

HESI100644
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): >210

Flash Point/Range (C): 99

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Use water spray to cool fire exposed surfaces. Closed containers may explode in

fire. Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 0, Reactivity 0

HMIS Ratings: Health 1, Flammability 0, Physical Hazard 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Wear self-contained breathing apparatus in

enclosed areas.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Wash hands after use. Launder

contaminated clothing before reuse. Avoid breathing mist.

Storage Information Store away from oxidizers. Store in a cool well ventilated area. Keep container

closed when not in use.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection If engineering controls and work practices cannot keep exposure below occupational

exposure limits or if exposure is unknown, wear a NIOSH certified, European

Standard EN 149, or equivalent respirator when using this product. Selection of and

instruction on using all personal protective equipment, including respirators, should

be performed by an Industrial Hygienist or other qualified professional.

Organic vapor respirator.

Supplied air respirator

Hand Protection Polyvinylchloride gloves. Nitrile gloves.

Skin Protection PVC coated apron or clothing. Rubber boots.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

FDP-S863A-07

Page 2 of 6

HESI100645
Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Milky

Odor: Mild aromatic

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 1.07

Density @ 20 C (lbs./gallon): 8.91

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers. Strong acids. Strong alkalis.

Hazardous Decomposition

Products

Toxic fumes. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation.

Skin Contact May cause skin irritation. May cause an allergic skin reaction.

Eye Contact Causes severe eye irritation which may damage tissue.

Ingestion Irritation of the mouth, throat, and stomach. A burning feeling in the Stomach May

cause abdominal pain, vomiting, nausea, and diarrhea.

Aggravated Medical Conditions Skin disorders. Eye ailments. Respiratory disorders.

FDP-S863A-07

Page 3 of 6

HESI100646
Chronic Effects/Carcinogenicity May cause testicular toxicity. Contains epichlorohydrin which has been reported to

produce cancer in laboratory animals. Epidemiological studies present "weak"

evidence of cancer risk to humans.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not readily biodegradable.

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

FDP-S863A-07

Page 4 of 6

HESI100647
ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 The California Proposition 65 regulations apply to this product.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

FDP-S863A-07

Page 5 of 6

HESI100648
Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

FDP-S863A-07

Page 6 of 6

HESI100649
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: FDP-S863B-07

Revision Date: 05-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: FDP-S863B-07

Synonyms: None

Chemical Family: Blend

Application: Hardener

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Polyamine Polymer Proprietary 1 - 5% Not applicable Not applicable

Potassium chloride 7447-40-7 1 - 5% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes Immediately flush eyes with large amounts of water for at least 15 minutes. Get

immediate medical attention.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

FDP-S863B-07

Page 1 of 6

HESI100650
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): > 210

Flash Point/Range (C): > 93

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media All standard firefighting media.

Special Exposure Hazards Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 0, Reactivity 0

HMIS Ratings: Health 1, Flammability 0, Physical Hazard 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse.

Storage Information Store in a cool well ventilated area. Keep container closed when not in use.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection If engineering controls and work practices cannot keep exposure below occupational

exposure limits or if exposure is unknown, wear a NIOSH certified, European

Standard EN 149, or equivalent respirator when using this product. Selection of and

instruction on using all personal protective equipment, including respirators, should

be performed by an Industrial Hygienist or other qualified professional.

Not normally needed. But if significant exposures are possible then the following

respirator is recommended:

Positive pressure self-contained breathing apparatus.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

FDP-S863B-07

Page 2 of 6

HESI100651
9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Golden to Yellow

Odor: Ammonia

pH: 7

Specific Gravity @ 20 C (Water=1): 1.07

Density @ 20 C (lbs./gallon): 8.9

Bulk Density @ 20 C (lbs/ft3): 66.7

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong acids. Strong alkalis. Sodium nitrite Peroxides. Strong oxidizers.

Hazardous Decomposition

Products

Ammonia. Carbon monoxide and carbon dioxide. Oxides of nitrogen. Chlorine.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation.

Skin Contact May cause skin irritation. May cause an allergic skin reaction.

Eye Contact May cause moderate eye irritation.

Ingestion Irritation of the mouth, throat, and stomach. May cause abdominal pain, vomiting,

nausea, and diarrhea.

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

FDP-S863B-07

Page 3 of 6

HESI100652
Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

FDP-S863B-07

Page 4 of 6

HESI100653
ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory Product contains one or more components not listed on inventory.

WHMIS Hazard Class Un-Controlled

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

FDP-S863B-07

Page 5 of 6

HESI100654
Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

FDP-S863B-07

Page 6 of 6

HESI100655
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: FDP-S869-07

Revision Date: 11-Mar-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: FDP-S869-07

Synonyms: None

Chemical Family: Polysaccharide

Application: Viscosifier

Manufacturer/Supplier Halliburton Energy Services, Inc.

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Xanthan gum 11138-66-2 60 - 100% 10 mg/m3 15 mg/m3

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye irritation. Airborne dust may be explosive.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Under normal conditions, first aid procedures are not required.

Notes to Physician Not Applicable

FDP-S869-07

Page 1 of 6

HESI100656
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 950

Flash Point/Range (C): 510

Flash Point Method: Not Determined

Autoignition Temperature (F): 400

Autoignition Temperature (C): 204

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Lower (oz./ft3): 0.04 - 0.4

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases. Organic dust in the presence of an

ignition source can be explosive in high concentrations. Good housekeeping

practices are required to minimize this potential.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 0, Flammability 1, Reactivity 0

HMIS Ratings: Health 0, Flammability 1, Physical Hazard 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

None known.

Procedure for Cleaning /

Absorption

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Slippery when wet. Avoid creating or inhaling dust.

Storage Information Product has a shelf life of 6 months. Store away from oxidizers. Store in a cool, dry

location.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection If engineering controls and work practices cannot keep exposure below occupational

exposure limits or if exposure is unknown, wear a NIOSH certified, European

Standard EN 149, or equivalent respirator when using this product. Selection of and

instruction on using all personal protective equipment, including respirators, should

be performed by an Industrial Hygienist or other qualified professional.

Not normally needed. But if significant exposures are possible then the following

respirator is recommended:

Dust/mist respirator. (95%)

Hand Protection Normal work gloves.

Skin Protection Normal work coveralls.

Eye Protection Wear safety glasses or goggles to protect against exposure.

FDP-S869-07

Page 2 of 6

HESI100657
Other Precautions None known.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Powder

Color: White to yellow

Odor: Slight

pH: 5.5-8.5

Specific Gravity @ 20 C (Water=1): 1.6

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): 52.4

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): 1,000,000

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May impede respiration.

Skin Contact None known.

Eye Contact May cause mild eye irritation.

Ingestion None known

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

FDP-S869-07

Page 3 of 6

HESI100658
Other Information None known.

Toxicity Tests

Oral Toxicity: LD50: > 5000 mg/kg (Rat)

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability BOD(5 Day): 200 mg/g COD: 1600 mg/g

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: TLM96: 320-560 ppm (Oncorhynchus mykiss)

Acute Crustaceans Toxicity:TLM96: > 75000 ppm (Mysidopsis bahia)

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Not restricted

Canadian TDG

Not restricted

ADR Not restricted

Air Transportation

FDP-S869-07

Page 4 of 6

HESI100659
ICAO/IATA Not restricted

Sea Transportation

IMDG Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

None

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law Does not apply.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law Does not apply.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class Un-Controlled

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

FDP-S869-07

Page 5 of 6

HESI100660
Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

FDP-S869-07

Page 6 of 6

HESI100661
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: FE-1A ACIDIZING COMPOSITION

Revision Date: 05-Jan-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: FE-1A ACIDIZING COMPOSITION

Synonyms: None

Chemical Family: Organic acid Anhydride

Application: Additive

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Acetic anhydride 108-24-7 60 - 100% 5 ppm 5 ppm

Acetic acid 64-19-7 30 - 60% 10 ppm 10 ppm

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory burns. May be harmful if swallowed.

Combustible. Reacts violently with water.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse. Destroy or properly dispose of contaminated shoes.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

FE-1A ACIDIZING COMPOSITION

Page 1 of 6

HESI100662
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 103

Flash Point/Range (C): 39

Flash Point Method: PMCC

Autoignition Temperature (F): 630

Autoignition Temperature (C): 332

Flammability Limits in Air - Lower (%): 3

Flammability Limits in Air - Upper (%): 19

Fire Extinguishing Media Carbon Dioxide, Dry Chemicals, Foam. Water must not be used with open

containers.

Special Exposure Hazards May be ignited by heat, sparks or flames. Closed containers may explode in fire.

Decomposition in fire may produce toxic gases. Reaction with water may be highly

exothermic.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 3, Flammability 2, Reactivity 2

HMIS Ratings: Health 3, Flammability 2, Physical Hazard 2

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Neutralize to pH of 6-8. Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse.

Storage Information Store away from alkalis. Store away from oxidizers. Store away from water. Keep

from heat, sparks, and open flames. Keep container closed when not in use. Product

has a shelf life of 60 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Organic vapor/acid gas respirator.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber boots. Full protective chemical resistant clothing.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

FE-1A ACIDIZING COMPOSITION

Page 2 of 6

HESI100663
9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Clear colorless

Odor: Pungent acrid

pH: < 2

Specific Gravity @ 20 C (Water=1): 1.0753

Density @ 20 C (lbs./gallon): 8.962

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 259

Boiling Point/Range (C): 126

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): 11.7

Vapor Density (Air=1): 3.5

Percent Volatiles: 100

Evaporation Rate (Butyl Acetate=1): 0.97

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame. Do not allow water to get into container

because of violent reaction.

Incompatibility (Materials to

Avoid)

Strong alkalis. Strong oxidizers. Reacts with water.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation Causes severe respiratory irritation.

Skin Contact Causes severe burns.

Eye Contact Causes severe eye burns.

Ingestion Causes burns of the mouth, throat and stomach.

Aggravated Medical Conditions Skin disorders. Eye ailments.

Chronic Effects/Carcinogenicity Prolonged, excessive exposure may cause erosion of the teeth.

Other Information None known.

Toxicity Tests

FE-1A ACIDIZING COMPOSITION

Page 3 of 6

HESI100664
Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Readily biodegradable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

UN2920,Corrosive Liquid, Flammable, N.O.S.(Contains Acetic Anhydride, Acetic Acid) , 8, (3), II, (39.4 C)

NAERG 132

Canadian TDG

Corrosive Liquid, Flammable, N.O.S.(Contains Acetic Anhydride, Acetic Acid) , 8, (3), UN2920, II, (39.4 C)

ADR

UN2920,Corrosive Liquid, Flammable, N.O.S.(Contains Acetic Anhydride, Acetic Acid) , 8, (3), II

Air Transportation

FE-1A ACIDIZING COMPOSITION

Page 4 of 6

HESI100665
ICAO/IATA

UN2920,Corrosive Liquid, Flammable, N.O.S., 8, (3), II

(Contains Acetic Anhydride, Acetic Acid Solution)

Sea Transportation

IMDG

UN2920,Corrosive Liquid, Flammable, N.O.S.(Contains Acetic Anhydride, Acetic Acid) , 8, (3), II, (39.4 C)

EmS F-E, S-C

Other Shipping Information

Labels: Corrosive

Flammable Liquid

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 1409 Gallons based on Acetic acid (CAS: 64-19-7).

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Ignitability D001

 Corrosivity D002

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class B3 Combustible Liquids

E Corrosive Material

FE-1A ACIDIZING COMPOSITION

Page 5 of 6

HESI100666
16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

FE-1A ACIDIZING COMPOSITION

Page 6 of 6

HESI100667
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: FE-2

Revision Date: 03-Jan-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: FE-2

Synonyms: None

Chemical Family: Organic acid

Application: Iron Control Agent

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Citric acid 77-92-9 60 - 100% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. Airborne dust may be explosive.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

FE-2

Page 1 of 5

HESI100668
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): 1832

Autoignition Temperature (C): 1000

Flammability Limits in Air - Lower (%): 8

Flammability Limits in Air - Upper (%): 65

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases. Organic dust in the presence of an

ignition source can be explosive in high concentrations. Good housekeeping

practices are required to minimize this potential.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 1, Reactivity 0

HMIS Ratings: Flammability 1, Reactivity 0, Health 2

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid creating or inhaling dust.

Storage Information Store away from alkalis. Store away from oxidizers. Store in a cool, dry location.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Dust/mist respirator. (95%)

Hand Protection Impervious rubber gloves.

Skin Protection Normal work coveralls.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid

Color: White

Odor: Odorless

pH: 1.8

Specific Gravity @ 20 C (Water=1): 1.665

FE-2

Page 2 of 5

HESI100669
9. PHYSICAL AND CHEMICAL PROPERTIES

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: 0

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): 192.13

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong alkalis. Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation.

Skin Contact May cause skin irritation.

Eye Contact May cause severe eye irritation.

Ingestion Irritation of the mouth, throat, and stomach. May cause abdominal pain, vomiting,

nausea, and diarrhea.

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: LD50: 11700 mg/kg (Rat)

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

FE-2

Page 3 of 5

HESI100670
Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Biodegradable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:TLM96: 100-330 ppm (Crangon crangon)

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Not restricted

Canadian TDG

Not restricted

ADR Not restricted

Air Transportation

ICAO/IATA Not restricted

Sea Transportation

IMDG Not restricted

Other Shipping Information

FE-2

Page 4 of 5

HESI100671
Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law Does not apply.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law Does not apply.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class E Corrosive Material

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

FE-2

Page 5 of 5

HESI100672
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: FE-2A

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: FE-2A

Synonyms: None

Chemical Family: Organic acid

Application: Additive

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Citric acid 77-92-9 30 - 60% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

FE-2A

Page 1 of 5

HESI100673
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not DeterminedMin: > 210

Flash Point/Range (C): Not DeterminedMin: > 98

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 1, Reactivity 1

HMIS Ratings: Health 1, Flammability 1, Physical Hazard 1

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors.

Storage Information Store away from oxidizers. Store away from alkalis. Keep container closed when not

in use. Product has a shelf life of 60 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Not normally needed. But if significant exposures are possible then the following

respirator is recommended:

Dust/mist respirator. (95%)

Hand Protection Impervious rubber gloves.

Skin Protection Normal work coveralls.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Light yellow

Odor: Mild sweet

pH: 2.2

FE-2A

Page 2 of 5

HESI100674
9. PHYSICAL AND CHEMICAL PROPERTIES

Specific Gravity @ 20 C (Water=1): 1.24

Density @ 20 C (lbs./gallon): 10.33

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 219

Boiling Point/Range (C): 103

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): 11.16

Vapor Density (Air=1): 9.6

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Miscible

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers. Strong alkalis.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation.

Skin Contact May cause skin irritation.

Eye Contact Causes severe eye irritation which may damage tissue.

Ingestion Irritation of the mouth, throat, and stomach.

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

FE-2A

Page 3 of 5

HESI100675
Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Readily biodegradable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

FE-2A

Page 4 of 5

HESI100676
Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law Does not apply.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law Does not apply.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class E Corrosive Material

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

FE-2A

Page 5 of 5

HESI100677
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: FE-3A

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: FE-3A

Synonyms: None

Chemical Family: Not applicable

Application: Iron Control Agent

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Organic salt 60 - 100% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. Potential carcinogen.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention.

Eyes Immediately flush eyes with large amounts of water for at least 15 minutes. Get

immediate medical attention.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

FE-3A

Page 1 of 6

HESI100678
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): 1060

Autoignition Temperature (C): 571

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media All standard firefighting media.

Special Exposure Hazards Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 0, Reactivity 0

HMIS Ratings: Health 2, Flammability 0, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid creating or inhaling dust. Wash

hands after use. Launder contaminated clothing before reuse.

Storage Information Store in a cool, dry location.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Dust/mist respirator. (95%)

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Powder

Color: White

Odor: Aminoacetate

pH: 11 (1%)

Specific Gravity @ 20 C (Water=1): 1.78

FE-3A

Page 2 of 6

HESI100679
9. PHYSICAL AND CHEMICAL PROPERTIES

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): 42.46

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): 4.3

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): 275.12

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers. Strong alkalis.

Hazardous Decomposition

Products

Oxides of nitrogen. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. Coughing, chest pains, and breathing difficulty may

occur.

Skin Contact May cause mild skin irritation.

Eye Contact Causes moderate eye irritation. May cause eye burns.

Ingestion Irritation of the mouth, throat, and stomach.

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity Contains nitrilotriacetic acid or its salts, which is listed as a suspect carcinogen of the

urinary tract and kidneys by NTP, based on feeding studies with laboratory animals.

According to the ACGIH guidelines, NTA would "not be considered an occupational

carcinogen of any significance." IARC cancer review classification: 2B (Possibly

Carcinogenic to Humans)

Other Information None known.

Toxicity Tests

Oral Toxicity: LD50: 1450 mg/kg (Rat)

FE-3A

Page 3 of 6

HESI100680
Dermal Toxicity: LD50: > 10000 mg/kg (Rabbit)

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Readily biodegradable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: TLM96: 98 mg/l (Oncorhynchus mykiss) TLM96: 312 mg/l (Lepomis macrochirus)

Acute Crustaceans Toxicity:EC50: (48 hour) 780 mg/l (Daphnia magna)

Acute Algae Toxicity: EC50 (96 hour): 780 mg/l (Clorella vulgaris)

EC50 (96 hour): 331 mg/l (Navicula)

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

FE-3A

Page 4 of 6

HESI100681
Sea Transportation

IMDG

 Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 The California Proposition 65 regulations apply to this product.

MA Right-to-Know Law Does not apply.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law Does not apply.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class E Corrosive Material

D2A Very Toxic Materials

D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

FE-3A

Page 5 of 6

HESI100682
Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

FE-3A

Page 6 of 6

HESI100683
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: FE-5A

Revision Date: 03-Dec-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: FE-5A

Synonyms: None

Chemical Family: Organic acid

Application: Iron Reducing Agent

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Thioglycolic acid 68-11-1 60 - 100% 1 ppm Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory burns. May be harmful if swallowed. May cause

allergic skin reaction. May be absorbed through the skin.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician None known.

FE-5A

Page 1 of 6

HESI100684
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 230

Flash Point/Range (C): 110

Flash Point Method: PMCC

Autoignition Temperature (F): 550

Autoignition Temperature (C): 288

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases. Use water spray to cool fire exposed

surfaces.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 3, Flammability 1, Reactivity 1

HMIS Ratings: Health 3, Flammability 1, Reactivity 1

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Neutralize to pH of 6-8. Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse.

Storage Information Store away from oxidizers. Store away from alkalis. Store away from acids. Store in a

dry location. Store in a cool well ventilated area. Keep container closed when not in

use. Product has a shelf life of 12 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Organic vapor/acid gas respirator.

Hand Protection Impervious rubber gloves.

Skin Protection Full protective chemical resistant clothing.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Clear colorless

FE-5A

Page 2 of 6

HESI100685
9. PHYSICAL AND CHEMICAL PROPERTIES

Odor: Irritating

pH: 1.04

Specific Gravity @ 20 C (Water=1): 1.28

Density @ 20 C (lbs./gallon): 10.66

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 221

Boiling Point/Range (C): 105

Freezing Point/Range (F): 2.3

Freezing Point/Range (C): -16.5

Vapor Pressure @ 20 C (mmHg): 10

Vapor Density (Air=1): Not Determined

Percent Volatiles: 100

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: 0.059

Molecular Weight (g/mole): 92.11

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers. Strong acids. Strong alkalis. Contact with metals.

Hazardous Decomposition

Products

Hydrogen sulfide. Oxides of sulfur. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation Causes severe respiratory burns.

Skin Contact Causes severe burns. May be absorbed through the skin and produce effects similar

to those caused by inhalation and/or ingestion. May cause an allergic skin reaction.

Eye Contact May cause eye burns.

Ingestion Causes burns of the mouth, throat and stomach. May cause weakness, dyspnea, or

coma.

Aggravated Medical Conditions Skin disorders. Eye ailments.

Chronic Effects/Carcinogenicity Prolonged or repeated skin exposure may cause dermatitis.

Other Information None known.

Toxicity Tests

Oral Toxicity: LD50: 54-73 mg/kg (Rat)

FE-5A

Page 3 of 6

HESI100686
Dermal Toxicity: LD50: 848 mg/kg (Rabbit)

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

UN1940,Thioglycolic Acid, 8, II

NAERG 153

Canadian TDG

Thioglycolic Acid, 8, UN1940, II

ADR

UN1940,Thioglycolic Acid, 8, II

Air Transportation

ICAO/IATA

FE-5A

Page 4 of 6

HESI100687
UN1940,Thioglycolic Acid, 8, II

Sea Transportation

IMDG

UN1940,Thioglycolic Acid, 8, II

EmS F-A, S-B

Other Shipping Information

Labels: Corrosive

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Corrosivity D002

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class E Corrosive Material

D1B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

FE-5A

Page 5 of 6

HESI100688
Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

FE-5A

Page 6 of 6

HESI100689
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: Fe-8M

Revision Date: 05-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: Fe-8M

Synonyms: None

Chemical Family: Blend

Application: Iron Reducing Agent

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Hydrochloric acid 7647-01-0 10 - 30% 2 ppm 5 ppm

Stannous chloride, dihydrate 10025-69-1 60 - 100% Not applicable 2 mg/m3

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory burns. May be harmful if swallowed.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Treat symptomatically.

Fe-8M

Page 1 of 6

HESI100690
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not DeterminedMin: > 200

Flash Point/Range (C): Not DeterminedMin: > 93

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media All standard firefighting media.

Special Exposure Hazards May form explosive mixtures with strong alkalis. Decomposition in fire may produce

toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 3, Flammability 1, Reactivity 1

HMIS Ratings: Health 3, Flammability 1, Reactivity 1

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Neutralize to pH of 6-8. Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse.

Storage Information Store away from alkalis. Store in a cool well ventilated area. Keep container closed

when not in use. Product has a shelf life of 24 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Acid gas respirator with a dust/mist filter.

Hand Protection Impervious rubber gloves.

Skin Protection Full protective chemical resistant clothing.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Clear light yellow

Odor: Acidic

Fe-8M

Page 2 of 6

HESI100691
9. PHYSICAL AND CHEMICAL PROPERTIES

pH: < 1

Specific Gravity @ 20 C (Water=1): 1.72

Density @ 20 C (lbs./gallon): 14.16

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not DeterminedMax: < -22

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None known.

Incompatibility (Materials to

Avoid)

Strong alkalis.

Hazardous Decomposition

Products

Flammable hydrogen gas. Chlorine.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation Causes severe respiratory irritation.

Skin Contact Causes severe burns.

Eye Contact Causes severe eye burns.

Ingestion Causes burns of the mouth, throat and stomach.

Aggravated Medical Conditions Skin disorders.

Chronic Effects/Carcinogenicity Prolonged or repeated exposure may cause lung damage. Prolonged, excessive

exposure may cause erosion of the teeth.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Fe-8M

Page 3 of 6

HESI100692
Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

UN3264,Corrosive Liquid, Acidic, Inorganic, N.O.S.(Stannic Chloride, Hydrochloric Acid), 8, II

NAERG 154

Canadian TDG

Corrosive Liquid, Acidic, Inorganic, N.O.S.(Stannic Chloride, Hydrochloric Acid), 8, UN3264, II

ADR

UN3264,Corrosive Liquid, Acidic, Inorganic, N.O.S.(Stannic Chloride, Hydrochloric Acid), 8, II

Air Transportation

ICAO/IATA

UN3264,Corrosive Liquid, Acidic, Inorganic, N.O.S., 8, II

(Contains Stannic Chloride, Hydrochloric Acid Solution)

Fe-8M

Page 4 of 6

HESI100693
Sea Transportation

IMDG

UN3264,Corrosive Liquid, Acidic, Inorganic, N.O.S.(Stannic Chloride, Hydrochloric Acid), 8, II

EmS F-A, S-B

Other Shipping Information

Labels: Corrosive

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Stannous Chloride Dihydrate (10025-69-1)

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 2942 Gallons of product base on Hydrochloric acid

(CAS: 7647-01-0)

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Corrosivity D002

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class E Corrosive Material

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Fe-8M

Page 5 of 6

HESI100694
Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

Fe-8M

Page 6 of 6

HESI100695
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: FERCHEK A REDUCING AGENT

Revision Date: 03-Jan-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: FERCHEK A REDUCING AGENT

Synonyms: None

Chemical Family: Blend

Application: Iron Reducing Agent

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Hydroxylamine hydrochloride 5470-11-1 30 - 60% Not applicable Not applicable

Silica, amorphous - fumed 7631-86-9 1 - 5% 2 mg/m3 10 mg/m3

Citric acid 77-92-9 30 - 60% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May be harmful if swallowed. May

cause allergic skin and respiratory reaction. Airborne dust may be explosive.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

FERCHEK A REDUCING AGENT

Page 1 of 5

HESI100696
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not DeterminedMin: > 180

Flash Point/Range (C): Not DeterminedMin: > 82

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases. Organic dust in the presence of an

ignition source can be explosive in high concentrations. Good housekeeping

practices are required to minimize this potential.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 0, Reactivity 0

HMIS Ratings: Flammability 0, Reactivity 0, Health 2

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid creating or inhaling dust. Wash

hands after use. Launder contaminated clothing before reuse.

Storage Information Store away from oxidizers. Store in a cool, dry location. Keep from heat, sparks, and

open flames. Product has a shelf life of 24 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Dust/mist respirator. (95%)

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Dust proof goggles.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid

Color: Brown

Odor: Characteristic

FERCHEK A REDUCING AGENT

Page 2 of 5

HESI100697
9. PHYSICAL AND CHEMICAL PROPERTIES

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 1.083

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): 46

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Partially soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers. Contact with metals.

Hazardous Decomposition

Products

Hydrogen chloride. Oxides of nitrogen. Ammonium hydroxide. Carbon monoxide and

carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. May cause allergic respiratory reaction.

Skin Contact May cause skin irritation. May cause an allergic skin reaction.

Eye Contact May cause eye irritation.

Ingestion Irritation of the mouth, throat, and stomach. May cause abdominal pain, vomiting,

nausea, and diarrhea.

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

FERCHEK A REDUCING AGENT

Page 3 of 5

HESI100698
Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Not restricted

Canadian TDG

Not restricted

ADR Not restricted

Air Transportation

ICAO/IATA Not restricted

Sea Transportation

IMDG Not restricted

Other Shipping Information

FERCHEK A REDUCING AGENT

Page 4 of 5

HESI100699
Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory Product contains one or more components not listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory Product contains one or more components not listed on inventory.

WHMIS Hazard Class D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

FERCHEK A REDUCING AGENT

Page 5 of 5

HESI100700
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: FERCHEK FERRIC IRON INHIBITOR

Revision Date: 03-Jan-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: FERCHEK FERRIC IRON INHIBITOR

Synonyms: None

Chemical Family: Not applicable

Application: Iron Reducing Agent

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Isoascorbic acid, sodium salt 6381-77-7 60 - 100% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye and respiratory irritation. Airborne dust may be explosive.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Under normal conditions, first aid procedures are not required.

Notes to Physician Not Applicable

FERCHEK FERRIC IRON INHIBITOR

Page 1 of 5

HESI100701
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): 1184

Autoignition Temperature (C): 640

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Lower (oz./ft3): 0.28

Flammability Limits in Air - Upper (%): Not Determined

Flammability Limits in Air - Upper (oz./ft3): 0.5

Fire Extinguishing Media All standard firefighting media.

Special Exposure Hazards Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 0, Reactivity 0

HMIS Ratings: Flammability 0, Reactivity 0, Health 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

None known.

Procedure for Cleaning /

Absorption

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid creating or inhaling dust.

Storage Information Store away from oxidizers. Store in a cool, dry location.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Dust/mist respirator. (95%)

Hand Protection Normal work gloves.

Skin Protection Normal work coveralls.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions None known.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid

Color: White

Odor: Odorless

pH: 5.5-8

Specific Gravity @ 20 C (Water=1): 1.65

FERCHEK FERRIC IRON INHIBITOR

Page 2 of 5

HESI100702
9. PHYSICAL AND CHEMICAL PROPERTIES

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): 62

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause mild respiratory irritation.

Skin Contact None known.

Eye Contact May cause mild eye irritation.

Ingestion None known

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

FERCHEK FERRIC IRON INHIBITOR

Page 3 of 5

HESI100703
Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Readily biodegradable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Not restricted

Canadian TDG

Not restricted

ADR Not restricted

Air Transportation

ICAO/IATA Not restricted

Sea Transportation

IMDG Not restricted

Other Shipping Information

Labels: None

FERCHEK FERRIC IRON INHIBITOR

Page 4 of 5

HESI100704
15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

None

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law Does not apply.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law Does not apply.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class Un-Controlled

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

FERCHEK FERRIC IRON INHIBITOR

Page 5 of 5

HESI100705
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: FOAMER NEM

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: FOAMER NEM

Synonyms: None

Chemical Family: Blend

Application: Foaming Agent

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Ethanol 64-17-5 1 - 5% 1000 ppm 1000 ppm

Inner salt of alkyl amines 5 - 10% Not applicable Not applicable

Isopropanol 67-63-0 10 - 30% 200 ppm 400 ppm

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause headache, dizziness, and

other central nervous system effects. May be harmful if swallowed. Repeated

overexposure may cause liver and kidney effects. Flammable.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

FOAMER NEM

Page 1 of 6

HESI100706
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 76

Flash Point/Range (C): 24

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): 2

Flammability Limits in Air - Upper (%): 12

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards May be ignited by heat, sparks or flames. Use water spray to cool fire exposed

surfaces. Closed containers may explode in fire. Decomposition in fire may produce

toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 3, Reactivity 0

HMIS Ratings: Health 2, Flammability 3, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Wear self-contained breathing apparatus in

enclosed areas.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Remove ignition sources and work with nonsparking tools. Contain spill with sand or other inert materials. Scoop up and

remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse. Ground and bond containers

when transferring from one container to another.

Storage Information Store away from oxidizers. Keep from heat, sparks, and open flames. Keep container

closed when not in use. Product has a shelf life of 24 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Organic vapor respirator.

In high concentrations, supplied air respirator or a self-contained breathing

apparatus.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

FOAMER NEM

Page 2 of 6

HESI100707
Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Dark amber

Odor: Strong characteristic

pH: 9.5

Specific Gravity @ 20 C (Water=1): 0.96

Density @ 20 C (lbs./gallon): 8.06

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): -6

Freezing Point/Range (C): -22

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: 60

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Emulsifies, forms colloids

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Oxides of sulfur. Fumes of aromatic hydrocarbons.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. May cause central nervous system depression

including headache, dizziness, drowsiness, incoordination, slowed reaction time,

slurred speech, giddiness and unconsciousness.

Skin Contact May cause skin irritation.

Eye Contact May cause severe eye irritation.

FOAMER NEM

Page 3 of 6

HESI100708
Ingestion Irritation of the mouth, throat, and stomach. May cause abdominal pain, vomiting,

nausea, and diarrhea. May cause central nervous system depression including

headache, dizziness, drowsiness, muscular weakness, incoordination, slowed

reaction time, fatigue blurred vision, slurred speech, giddiness, tremors and

convulsions.

Aggravated Medical Conditions Skin disorders. Eye ailments.

Chronic Effects/Carcinogenicity Repeated overexposure may cause liver and kidney effects.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

FOAMER NEM

Page 4 of 6

HESI100709
UN1219,Isopropanol Solution, 3, II, (22.2 C)

NAERG 129

Canadian TDG

Isopropanol Solution, 3, UN1219, II, (22.2 C)

ADR

UN1219,Isopropanol Solution, 3, II

Air Transportation

ICAO/IATA

UN1219,Isopropanol Solution, 3, II

Sea Transportation

IMDG

UN1219,Isopropanol Solution, 3, II, (22.2 C)

EmS F-E, S-D

Other Shipping Information

Labels: Flammable Liquid

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Diethanolamine//111-42-2

Isopropanol//67-63-0

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 620 Gallons based on Diethanolamine (CAS: 111-

42-2).

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Ignitability D001

California Proposition 65 The California Proposition 65 regulations apply to this product.

MA Right-to-Know Law One or more components listed.

FOAMER NEM

Page 5 of 6

HESI100710
NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class B2 Flammable Liquids

D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

FOAMER NEM

Page 6 of 6

HESI100711
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: FORMIC ACID 90%

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: FORMIC ACID 90%

Synonyms: None

Chemical Family: Organic acid

Application: Solvent

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Formic acid 64-18-6 60 - 100% 5 ppm 5 ppm

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye and skin burns. May cause respiratory irritation. May cause

headache, dizziness, and other central nervous system effects. May be harmful if

swallowed. Repeated overexposure may cause liver and kidney effects.

Combustible.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

FORMIC ACID 90%

Page 1 of 6

HESI100712
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 121

Flash Point/Range (C): 49

Flash Point Method: Not Determined

Autoignition Temperature (F): 1114

Autoignition Temperature (C): 601

Flammability Limits in Air - Lower (%): 18

Flammability Limits in Air - Upper (%): 57

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases. Do not allow runoff to enter

waterways.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 3, Flammability 2, Reactivity 0

HMIS Ratings: Health 3, Flammability 2, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Neutralize to pH of 6-8. Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse.

Storage Information Store away from alkalis. Store away from oxidizers. Keep container closed when not

in use. Product has a shelf life of 12 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Acid gas respirator.

In high concentrations, supplied air respirator or a self-contained breathing

apparatus.

Hand Protection Impervious rubber gloves.

Skin Protection Full protective chemical resistant clothing.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

FORMIC ACID 90%

Page 2 of 6

HESI100713
9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Clear colorless

Odor: Sharp

pH: 1

Specific Gravity @ 20 C (Water=1): 1.2

Density @ 20 C (lbs./gallon): 10.0

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 215

Boiling Point/Range (C): 101

Freezing Point/Range (F): 50

Freezing Point/Range (C): 10

Vapor Pressure @ 20 C (mmHg): 23

Vapor Density (Air=1): Not Determined

Percent Volatiles: 100

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Miscible

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): 46.03

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers. Strong alkalis.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation Causes severe respiratory irritation. May cause central nervous system depression

including headache, dizziness, drowsiness, incoordination, slowed reaction time,

slurred speech, giddiness and unconsciousness.

Skin Contact Causes severe burns.

Eye Contact May cause eye burns. May cause permanent eye damage.

Ingestion Causes burns of the mouth, throat and stomach. May cause abdominal pain,

vomiting, nausea, and diarrhea. May cause kidney damage.

Aggravated Medical Conditions Skin disorders.

Chronic Effects/Carcinogenicity Repeated overexposure may cause liver and kidney effects.

FORMIC ACID 90%

Page 3 of 6

HESI100714
Other Information None known.

Toxicity Tests

Oral Toxicity: LD50: 1100 mg/kg (Rat)

Dermal Toxicity: Not determined

Inhalation Toxicity: LC50: 15000 mg/m3/15 min. (Rat)

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Readily biodegradable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

UN1779,Formic Acid, 8, (3), II

RQ (Formic Acid - 2273 kg.)

NAERG 153

Canadian TDG

Formic Acid, 8, (3), UN1779, II

FORMIC ACID 90%

Page 4 of 6

HESI100715
ADR

UN1779,Formic Acid, 8, (3), II

Air Transportation

ICAO/IATA

UN1779,Formic Acid, 8, (3), II

RQ (Formic Acid - 2273 kg.)

Sea Transportation

IMDG

UN1779,Formic Acid, 8, (3), II

RQ (Formic Acid - 2273 kg.)

EmS F-A, S-B

Other Shipping Information

Labels: Corrosive

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 555 Gallons based on Formic acid (CAS: 64-18-6).

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Ignitability D001

 Corrosivity D002

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

FORMIC ACID 90%

Page 5 of 6

HESI100716
WHMIS Hazard Class E Corrosive Material

B3 Combustible Liquids

D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

FORMIC ACID 90%

Page 6 of 6

HESI100717
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: FR-26LC

Revision Date: 05-Jan-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: FR-26LC

Synonyms: None

Chemical Family: Blend

Application: Friction Reducer

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Hydrotreated light petroleum

distillate

64742-47-8 10 - 30% 200 mg/m3 Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye and skin irritation. May cause headache, dizziness, and other central

nervous system effects. May be harmful if swallowed.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Get medical attention! If vomiting occurs, keep head lower than hips to prevent

aspiration.

Notes to Physician Not Applicable

FR-26LC

Page 1 of 6

HESI100724
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not DeterminedMin: > 200

Flash Point/Range (C): Not DeterminedMin: > 93

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases. Use water spray to cool fire exposed

surfaces.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 1, Reactivity 0

HMIS Ratings: Health 1, Flammability 1, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse.

Storage Information Store away from oxidizers. Store in a cool well ventilated area. Keep container

closed when not in use.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Organic vapor respirator.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Hazy light tan

FR-26LC

Page 2 of 6

HESI100725
9. PHYSICAL AND CHEMICAL PROPERTIES

Odor: Sweet hydrocarbon

pH: 8.7

Specific Gravity @ 20 C (Water=1): 1.09

Density @ 20 C (lbs./gallon): 9.08

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: 1.3

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Oxides of nitrogen. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. May cause central nervous system depression

including headache, dizziness, drowsiness, incoordination, slowed reaction time,

slurred speech, giddiness and unconsciousness.

Skin Contact May cause moderate skin irritation.

Eye Contact May cause moderate eye irritation.

Ingestion Aspiration into the lungs may cause chemical pneumonitis including coughing,

difficulty breathing, wheezing, coughing up blood and pneumonia, which can be fatal.

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

FR-26LC

Page 3 of 6

HESI100726
Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Slowly biodegradable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: TLM96: 100-1000 ppm (Lepomis macrochirus)

Acute Crustaceans Toxicity:TLM96: 100-330 ppm (Crangon crangon)

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Not restricted

Canadian TDG

Not restricted

ADR Not restricted

Air Transportation

ICAO/IATA Not restricted

Sea Transportation

FR-26LC

Page 4 of 6

HESI100727
IMDG Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law Does not apply.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law Does not apply.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

FR-26LC

Page 5 of 6

HESI100728
***END OF MSDS***

FR-26LC

Page 6 of 6

HESI100729
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: FR-38

Revision Date: 05-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: FR-38

Synonyms: None

Chemical Family: Blend

Application: Friction Reducer

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Acetic acid 64-19-7 1 - 5% 10 ppm 10 ppm

Ammonium bisulfate 7783-20-2 10 - 30% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye and skin irritation.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

FR-38

Page 1 of 5

HESI100730
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media All standard firefighting media.

Special Exposure Hazards Not Determined

Special Protective Equipment for

Fire-Fighters

Not Determined

NFPA Ratings: Health 1, Flammability 1, Reactivity 0

HMIS Ratings: Health 1, Flammability 1, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors.

Storage Information Store away from acids. Store away from alkalis. Keep container closed when not in

use.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Not normally necessary.

Hand Protection Impervious rubber gloves.

Skin Protection Normal work coveralls.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions None known.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: White

Odor: Odorless

pH: 3-4.1

Specific Gravity @ 20 C (Water=1): 1.19

FR-38

Page 2 of 5

HESI100731
9. PHYSICAL AND CHEMICAL PROPERTIES

Density @ 20 C (lbs./gallon): 9.9

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None known.

Incompatibility (Materials to

Avoid)

Strong oxidizers. Strong alkalis.

Hazardous Decomposition

Products

Oxides of sulfur. Oxides of nitrogen. Hydrogen chloride. Ammonia. Carbon monoxide

and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation None known.

Skin Contact May cause mild skin irritation.

Eye Contact May cause mild eye irritation.

Ingestion None known

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

FR-38

Page 3 of 5

HESI100732
Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

FR-38

Page 4 of 5

HESI100733
Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory Product contains one or more components not listed on inventory.

WHMIS Hazard Class Un-Controlled

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

FR-38

Page 5 of 5

HESI100734
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: FR-46

Revision Date: 05-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: FR-46

Synonyms: None

Chemical Family: Polymer

Application: Friction Reducer

Manufacturer/Supplier Halliburton Energy Services, Inc.

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Ammonium bisulfate 7783-20-2 10 - 30% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye and skin irritation. May be harmful if swallowed.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Get medical attention! If vomiting occurs, keep head lower than hips to prevent

aspiration.

Notes to Physician Not Applicable

FR-46

Page 1 of 6

HESI100735
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): > 200

Flash Point/Range (C): > 93

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical. Use water spray to cool fire exposed

surfaces.

Special Exposure Hazards Decomposition in fire may produce toxic gases. Vapors are heavier than air and may

accumulate in low areas. Vapors may travel along the ground to be ignited at distant

locations.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 1, Reactivity 0

HMIS Ratings: Health 1, Flammability 1, Physical Hazard 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Scoop up and remove. Isolate spill and stop leak where safe. Contain spill with sand

or other inert materials. Do NOT spread spilled product with water.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors.

Storage Information Store away from oxidizers. Store in a cool well ventilated area. Keep container

closed when not in use.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection If engineering controls and work practices cannot keep exposure below occupational

exposure limits or if exposure is unknown, wear a NIOSH certified, European

Standard EN 149, or equivalent respirator when using this product. Selection of and

instruction on using all personal protective equipment, including respirators, should

be performed by an Industrial Hygienist or other qualified professional.

Not normally needed. But if significant exposures are possible then the following

respirator is recommended:

Organic vapor respirator.

Hand Protection Impervious rubber gloves.

Skin Protection Normal work coveralls.

Eye Protection Wear safety glasses or goggles to protect against exposure.

FR-46

Page 2 of 6

HESI100736
Other Precautions None known.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Milky white

Odor: Slight

pH: 5.5-7.0

Specific Gravity @ 20 C (Water=1): 1.2-1.3

Density @ 20 C (lbs./gallon): 10.4

Bulk Density @ 20 C (lbs/ft3): 78

Boiling Point/Range (F): 248

Boiling Point/Range (C): 120

Freezing Point/Range (F): < 5

Freezing Point/Range (C): < -15

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: ~ 55

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): 100-200

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers. Strong acids.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide. Oxides of nitrogen.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation.

Skin Contact May cause mild skin irritation.

Eye Contact May cause mild eye irritation.

Ingestion May be harmful if swallowed.

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

FR-46

Page 3 of 6

HESI100737
Other Information None known.

Toxicity Tests

Oral Toxicity: LD50: 7500 mg/kg (Rat)

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

FR-46

Page 4 of 6

HESI100738
ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

None

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class Un-Controlled

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

FR-46

Page 5 of 6

HESI100739
Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

FR-46

Page 6 of 6

HESI100740
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: FR-48

Revision Date: 05-Jan-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: FR-48

Synonyms: None

Chemical Family: Blend

Application: Friction Reducer

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Contains no hazardous

substances

Mixture 60 - 100% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye and skin irritation.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

FR-48

Page 1 of 5

HESI100741
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): > 200

Flash Point/Range (C): > 93.3

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 1, Reactivity 0

HMIS Ratings: Health 1, Flammability 1, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing.

Storage Information Store away from oxidizers. Store in a cool well ventilated area. Keep container

closed when not in use.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Not normally necessary.

Hand Protection Impervious rubber gloves.

Skin Protection Normal work coveralls.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions None known.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Milky white

Odor: Mild

pH: 3.5-5.0

Specific Gravity @ 20 C (Water=1): 1.15-1.25

FR-48

Page 2 of 5

HESI100742
9. PHYSICAL AND CHEMICAL PROPERTIES

Density @ 20 C (lbs./gallon): 9.6-10.4

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): 23

Freezing Point/Range (C): -15

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Oxides of nitrogen. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation None known.

Skin Contact May cause mild skin irritation.

Eye Contact May cause mild eye irritation.

Ingestion None known

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

FR-48

Page 3 of 5

HESI100743
Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Not restricted

Canadian TDG

Not restricted

ADR Not restricted

Air Transportation

ICAO/IATA Not restricted

Sea Transportation

IMDG Not restricted

Other Shipping Information

Labels: None

FR-48

Page 4 of 5

HESI100744
15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

None

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 The California Proposition 65 regulations apply to this product.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory Product contains one or more components not listed on inventory.

WHMIS Hazard Class Un-Controlled

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

FR-48

Page 5 of 5

HESI100745
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: FR-48W

Revision Date: 05-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: FR-48W

Synonyms: None

Chemical Family: Blend

Application: Cement Additive

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Ethylene glycol 107-21-1 0-4 100 mg/m3 50 ppm

Aluminum chloride, basic 1327-41-9 1 - 5% 2 mg/m3 2 mg/m3

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause headache, dizziness, and

other central nervous system effects. May be harmful if swallowed. May cause birth

defects.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

FR-48W

Page 1 of 6

HESI100746
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): > 200

Flash Point/Range (C): > 93

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 0, Reactivity 0

HMIS Ratings: Health 2, Flammability 0, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors.

Storage Information Store away from oxidizers. Store in a cool, dry location. Keep container closed when

not in use.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Organic vapor respirator with a dust/mist filter.

Hand Protection Impervious rubber gloves. Nitrile gloves. Nitrile gloves. Neoprene gloves.

Skin Protection Normal work coveralls.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Milky white

Odor: Odorless

pH: 4.45 (10%)

Specific Gravity @ 20 C (Water=1): 1.22

Density @ 20 C (lbs./gallon): 10.04

FR-48W

Page 2 of 6

HESI100747
9. PHYSICAL AND CHEMICAL PROPERTIES

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 212

Boiling Point/Range (C): 100

Freezing Point/Range (F): -4

Freezing Point/Range (C): -20

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None known.

Incompatibility (Materials to

Avoid)

Strong oxidizers. Strong acids.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. May cause central nervous system depression

including headache, dizziness, drowsiness, incoordination, slowed reaction time,

slurred speech, giddiness and unconsciousness.

Skin Contact May cause skin irritation.

Eye Contact May cause eye irritation.

Ingestion May cause abdominal pain, vomiting, nausea, and diarrhea. May cause heart, kidney

and brain disorders.

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity Prolonged or repeated exposure may cause kidney damage. Prolonged or repeated

exposure may cause central nervous system and brain effects. Prolonged or

repeated exposure may cause embryo and fetus toxicity.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

FR-48W

Page 3 of 6

HESI100748
Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

FR-48W

Page 4 of 6

HESI100749
IMDG

 Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Ethylene Glycol//107-21-1

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 18195 Gallons based on Ethylene glycol (CAS: 107-

21-1).

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 The California Proposition 65 regulations apply to this product.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory Product contains one or more components not listed on inventory.

WHMIS Hazard Class D2A Very Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

FR-48W

Page 5 of 6

HESI100750
Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

FR-48W

Page 6 of 6

HESI100751
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: FR-5

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: FR-5

Synonyms: None

Chemical Family: Blend

Application: Friction Reducer

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Kerosene 8008-20-6 60 - 100% 200 mg/m3 Not applicable

Ethylene glycol 107-21-1 1 - 5% 100 mg/m3 50 ppm

Isopropanol 67-63-0 10 - 30% 200 ppm 400 ppm

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye and respiratory irritation. May cause headache, dizziness, and other

central nervous system effects. May be harmful if swallowed. Repeated

overexposure may cause liver and kidney effects. May cause birth defects.

Flammable.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

FR-5

Page 1 of 6

HESI100718
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 68

Flash Point/Range (C): 20

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards May be ignited by heat, sparks or flames. Use water spray to cool fire exposed

surfaces. Closed containers may explode in fire. Decomposition in fire may produce

toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 3, Reactivity 1

HMIS Ratings: Health 1, Flammability 3, Reactivity 1

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Wear self-contained breathing apparatus in

enclosed areas.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Remove ignition sources and work with nonsparking tools. Contain spill with sand or other inert materials. Scoop up and

remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse. Ground and bond containers

when transferring from one container to another.

Storage Information Store away from oxidizers. Keep from heat, sparks, and open flames. Keep container

closed when not in use.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Organic vapor respirator.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

FR-5

Page 2 of 6

HESI100719
9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Amber

Odor: Mild kerosene

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 0.82

Density @ 20 C (lbs./gallon): 6.89

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Disperses

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. May cause central nervous system depression

including headache, dizziness, drowsiness, incoordination, slowed reaction time,

slurred speech, giddiness and unconsciousness.

Skin Contact May cause skin defatting with prolonged exposure. May cause skin irritation.

Eye Contact May cause eye irritation.

Ingestion Irritation of the mouth, throat, and stomach. May cause abdominal pain, vomiting,

nausea, and diarrhea. Aspiration into the lungs may cause chemical pneumonitis

including coughing, difficulty breathing, wheezing, coughing up blood and

pneumonia, which can be fatal. May cause heart, kidney and brain disorders.

Aggravated Medical Conditions Skin disorders. Eye ailments.

FR-5

Page 3 of 6

HESI100720
Chronic Effects/Carcinogenicity Repeated, excessive exposure may cause kidney and blood effects. Prolonged or

repeated exposure may cause liver, heart, blood and brain damage. Prolonged or

repeated exposure may cause embryo and fetus toxicity. Contains kerosene, a

suspect animal skin carcinogen. A skin painting study with kerosene in mice has

produced positive skin tumors.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Resistant

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

UN1993,Flammable Liquid, N.O.S.(Contains Isopropanol, Kerosene), 3, II, (20 C)

NAERG 128

FR-5

Page 4 of 6

HESI100721
Canadian TDG

Flammable Liquid, N.O.S.(Contains Isopropanol, Kerosene), 3, UN1993, II, (20 C)

ADR

UN1993,Flammable Liquid, N.O.S.(Contains Isopropanol, Kerosene), 3, II

Air Transportation

ICAO/IATA

UN1993,Flammable Liquid, N.O.S., 3, II

(Contains Isopropanol, Kerosene Solution)

Sea Transportation

IMDG

UN1993,Flammable Liquid, N.O.S.(Contains Isopropanol, Kerosene), 3, II, (20 C)

EmS F-E, S-E

Other Shipping Information

Labels: Flammable Liquid

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Ethylene Glycol//107-21-1

Isopropanol//67-63-0

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 18142 Gallons based on Ethylene glycol (CAS: 107-

21-1).

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Ignitability D001

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

FR-5

Page 5 of 6

HESI100722
PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class B2 Flammable Liquids

D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

FR-5

Page 6 of 6

HESI100723
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: FR-56

Revision Date: 05-Jan-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: FR-56

Synonyms: None

Chemical Family: Blend

Application: Friction Reducer

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Hydrotreated light petroleum

distillate

64742-47-8 10 - 30% 200 mg/m3 Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye and skin irritation. May cause headache, dizziness, and other central

nervous system effects. May be harmful if swallowed.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin Wash with soap and water. Get medical attention if irritation persists. Remove

contaminated clothing and launder before reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Get medical attention! If vomiting occurs, keep head lower than hips to prevent

aspiration.

Notes to Physician Not Applicable

FR-56

Page 1 of 6

HESI100752
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): > 200

Flash Point/Range (C): > 93

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases. Use water spray to cool fire exposed

surfaces.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 1, Reactivity 0

HMIS Ratings: Health 1, Flammability 1, Physical Hazard 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse. Material is slippery underfoot.

Storage Information Store away from oxidizers. Keep container closed when not in use. Store in a cool,

dry location. Store in a well ventilated area. Keep from freezing.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Not normally needed. But if significant exposures are possible then the following

respirator is recommended:

Organic vapor respirator.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

FR-56

Page 2 of 6

HESI100753
9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: White to Light yellow

Odor: Sweet hydrocarbon

pH: Not Determined

Specific Gravity @ 20 C (Water=1): 1.03

Density @ 20 C (lbs./gallon): 8.58

Bulk Density @ 20 C (lbs/ft3): 64.2

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): - 20

Freezing Point/Range (C): - 29

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: 70

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Oxides of nitrogen. Carbon monoxide and carbon dioxide. Chlorine.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. In high air concentrations:

May cause central nervous system depression including headache, dizziness,

drowsiness, incoordination, slowed reaction time, slurred speech, giddiness and

unconsciousness.

Skin Contact May cause skin irritation.

Eye Contact May cause moderate eye irritation.

Ingestion Aspiration into the lungs may cause chemical pneumonitis including coughing,

difficulty breathing, wheezing, coughing up blood and pneumonia, which can be fatal.

Aggravated Medical Conditions None known.

FR-56

Page 3 of 6

HESI100754
Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT Not restricted

Canadian TDG

Not restricted

ADR Not restricted

FR-56

Page 4 of 6

HESI100755
Air Transportation

ICAO/IATA Not restricted

Sea Transportation

IMDG Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class Un-Controlled

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

FR-56

Page 5 of 6

HESI100756
Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

FR-56

Page 6 of 6

HESI100757
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: GasPerm 1000TM

Revision Date: 04-Mar-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: GasPerm 1000TM

Synonyms: None

Chemical Family: Blend

Application: Surfactant

Manufacturer/Supplier Halliburton Energy Services, Inc.

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Isopropanol 67-63-0 10 - 30% 200 ppm 400 ppm

Terpenes and Terpenoids, sweet

orange-oil

68647-72-3 10 - 30% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause headache, dizziness, and

other central nervous system effects. May be harmful if swallowed. May be absorbed

through the skin. Repeated overexposure may cause liver and kidney effects. May

cause allergic skin reaction. Flammable.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes Check for and remove contact lenses if present. In case of contact, or suspected

contact, immediately flush eyes with plenty of water for at least 15 minutes and get

medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person. Get

medical attention! If vomiting occurs, keep head lower than hips to prevent

aspiration.

GasPerm 1000TM

Page 1 of 6

HESI100758
Notes to Physician Not Applicable

5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 70

Flash Point/Range (C): 21.1

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): 2

Flammability Limits in Air - Upper (%): 12.7

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards May be ignited by heat, sparks or flames. Use water spray to cool fire exposed

surfaces. Closed containers may explode in fire. Decomposition in fire may produce

toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 3, Reactivity 0

HMIS Ratings: Health 2, Flammability 3, Physical Hazard 0 , PPE: H

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Wear self-contained breathing apparatus in

enclosed areas.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Remove ignition sources and work with nonsparking tools. Contain spill with sand or other inert materials. Scoop up and

remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Avoid breathing

mist. Wash hands after use. Launder contaminated clothing before reuse. Ground

and bond containers when transferring from one container to another.

Storage Information Store away from oxidizers. Keep from heat, sparks, and open flames. Keep container

closed when not in use. Terpene containing products should be stored in phenoliclined metal, stainless steel, PET, or fluorinated plastic containers. Product has a shelf

life of 24 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

GasPerm 1000TM

Page 2 of 6

HESI100759
Respiratory Protection If engineering controls and work practices cannot keep exposure below occupational

exposure limits or if exposure is unknown, wear a NIOSH certified, European

Standard EN 149, or equivalent respirator when using this product. Selection of and

instruction on using all personal protective equipment, including respirators, should

be performed by an Industrial Hygienist or other qualified professional.

Organic vapor respirator.

In high concentrations, supplied air respirator or a self-contained breathing

apparatus.

Hand Protection Impervious rubber gloves. Nitrile gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Light amber

Odor: Citrus

pH: 8.7

Specific Gravity @ 20 C (Water=1): 0.918

Density @ 20 C (lbs./gallon): 7.65

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 310

Boiling Point/Range (C): 154

Freezing Point/Range (F): < 0

Freezing Point/Range (C): < -17.8

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: 50-75

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Partially soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers. Iodine pentafluorethylene Strong acids. Strong alkalis.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

GasPerm 1000TM

Page 3 of 6

HESI100760
11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. May cause central nervous system depression

including headache, dizziness, drowsiness, incoordination, slowed reaction time,

slurred speech, giddiness and unconsciousness.

Skin Contact May cause mild skin irritation. May cause skin defatting with prolonged exposure.

May cause an allergic skin reaction. May be absorbed through the skin and produce

effects similar to those caused by inhalation and/or ingestion.

Eye Contact May cause severe eye irritation.

Ingestion Irritation of the mouth, throat, and stomach. May cause abdominal pain, vomiting,

nausea, and diarrhea. May cause central nervous system depression including

headache, dizziness, drowsiness, muscular weakness, incoordination, slowed

reaction time, fatigue blurred vision, slurred speech, giddiness, tremors and

convulsions. Aspiration into the lungs may cause chemical pneumonitis including

coughing, difficulty breathing, wheezing, coughing up blood and pneumonia, which

can be fatal.

Aggravated Medical Conditions Eye ailments. Skin disorders.

Chronic Effects/Carcinogenicity Repeated overexposure may cause liver and kidney effects.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Inherently biodegradable

Bio-accumulation Not expected to bioaccumulate.

 Ecotoxicological Information

Acute Fish Toxicity: May be toxic to aquatic life.

Acute Crustaceans Toxicity:May be toxic to aquatic life.

Acute Algae Toxicity: Not determined

GasPerm 1000TM

Page 4 of 6

HESI100761
Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

UN1993,Flammable Liquid, N.O.S.(Contains Isopropanol, Terpene Hydrocarbons), 3, II, (21.1 C)

NAERG 128

Canadian TDG

Flammable Liquid, N.O.S.(Contains Isopropanol, Terpene Hydrocarbons), 3, UN1993, II, (21.1 C)

ADR

UN1993,Flammable Liquid, N.O.S.(Contains Isopropanol, Terpene Hydrocarbons), 3, II

Air Transportation

ICAO/IATA

UN1993,Flammable Liquid, N.O.S., 3, II

(Contains Isopropanol, Terpene Hydrocarbons Solution)

Sea Transportation

IMDG

UN1993,Flammable Liquid, N.O.S.(Contains Isopropanol, Terpene Hydrocarbons), 3, II, (21.1 C)

EmS F-E, S-E

Other Shipping Information

Labels: Flammable Liquid

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory Product contains one or more components not listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

GasPerm 1000TM

Page 5 of 6

HESI100762
EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Ignitability D001

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory Product contains one or more components not listed on inventory.

WHMIS Hazard Class B2 Flammable Liquids

D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

GasPerm 1000TM

Page 6 of 6

HESI100763
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: GBW-30 BREAKER

Revision Date: 05-Jan-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: GBW-30 BREAKER

Synonyms: None

Chemical Family: Polysaccharide

Application: Breaker

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Hemicellulase enzyme 9012-54-8 5-15 Not applicable Not applicable

Carbohydrates 85-85 Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye and respiratory irritation. May cause allergic respiratory reaction.

Airborne dust may be explosive.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Under normal conditions, first aid procedures are not required.

Notes to Physician Not Applicable

GBW-30 BREAKER

Page 1 of 6

HESI100769
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not DeterminedMin: > 200

Flash Point/Range (C): Not DeterminedMin: > 93

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Lower (oz./ft3): 0.125

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media All standard firefighting media.

Special Exposure Hazards Organic dust in the presence of an ignition source can be explosive in high

concentrations. Good housekeeping practices are required to minimize this

potential.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 1, Reactivity 0

HMIS Ratings: Health 1, Flammability 1, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid creating or inhaling dust.

Storage Information Store away from oxidizers. Store in a cool, dry location. Product has a shelf life of 12

months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Not normally needed. But if significant exposures are possible then the following

respirator is recommended:

Dust/mist respirator. (95%)

Hand Protection Normal work gloves.

Skin Protection Normal work coveralls.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions None known.

GBW-30 BREAKER

Page 2 of 6

HESI100770
9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Powder

Color: White

Odor: Odorless

pH: 7

Specific Gravity @ 20 C (Water=1): 1.5

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): 42

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause mild respiratory irritation. May cause allergic respiratory reaction.

Skin Contact None known.

Eye Contact May cause mild eye irritation.

Ingestion None known

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

GBW-30 BREAKER

Page 3 of 6

HESI100771
Toxicity Tests

Oral Toxicity: LD50: 29700 mg/kg (Rat)

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Readily biodegradable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:TLM96: > 3300 ppm (Crangon crangon)

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Not restricted

Canadian TDG

Not restricted

ADR Not restricted

Air Transportation

ICAO/IATA Not restricted

GBW-30 BREAKER

Page 4 of 6

HESI100772
Sea Transportation

IMDG Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

None

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law Does not apply.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law Does not apply.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class Un-Controlled

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

GBW-30 BREAKER

Page 5 of 6

HESI100773
***END OF MSDS***

GBW-30 BREAKER

Page 6 of 6

HESI100774
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: GBW-3 BREAKER

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: GBW-3 BREAKER

Synonyms: None

Chemical Family: Polysaccharide

Application: Breaker

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Carbohydrates 95-99 Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye and respiratory irritation. May cause allergic respiratory reaction.

Airborne dust may be explosive.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Under normal conditions, first aid procedures are not required.

Notes to Physician Not Applicable

GBW-3 BREAKER

Page 1 of 5

HESI100764
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not DeterminedMin: > 200

Flash Point/Range (C): Not DeterminedMin: > 93

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media All standard firefighting media.

Special Exposure Hazards Organic dust in the presence of an ignition source can be explosive in high

concentrations. Good housekeeping practices are required to minimize this

potential.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 1, Reactivity 0

HMIS Ratings: Health 1, Flammability 1, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

None known.

Procedure for Cleaning /

Absorption

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid creating or inhaling dust.

Storage Information Store away from oxidizers. Store in a cool, dry location. Product has a shelf life of 12

months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Not normally needed. But if significant exposures are possible then the following

respirator is recommended:

Dust/mist respirator. (95%)

Hand Protection Normal work gloves.

Skin Protection Normal work coveralls.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions None known.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid

Color: White to off white

GBW-3 BREAKER

Page 2 of 5

HESI100765
9. PHYSICAL AND CHEMICAL PROPERTIES

Odor: Odorless

pH: 7

Specific Gravity @ 20 C (Water=1): 1.5

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): 42

Boiling Point/Range (F): 320

Boiling Point/Range (C): 160

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: 0

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause mild respiratory irritation. May cause allergic respiratory reaction.

Skin Contact None known.

Eye Contact May cause mild eye irritation.

Ingestion None known

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: LD50: 29700 mg/kg (Rat)

Dermal Toxicity: Not determined

GBW-3 BREAKER

Page 3 of 5

HESI100766
Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Readily biodegradable

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:TLM96: > 3300 ppm (Crangon crangon)

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

GBW-3 BREAKER

Page 4 of 5

HESI100767
Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

None

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law Does not apply.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law Does not apply.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class Un-Controlled

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

GBW-3 BREAKER

Page 5 of 5

HESI100768
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: GEL-STA L STABILIZER

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: GEL-STA L STABILIZER

Synonyms: None

Chemical Family: Blend

Application: Stabilizer

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Sodium thiosulfate 7772-98-7 30 - 60% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Under normal conditions, first aid procedures are not required.

Notes to Physician Not Applicable

GEL-STA L STABILIZER

Page 1 of 5

HESI100775
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Water fog, carbon dioxide, foam, dry chemical.

Special Exposure Hazards Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 0, Flammability 0, Reactivity 0

HMIS Ratings: Health 0, Flammability 0, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors.

Storage Information Store in a cool well ventilated area. Keep container closed when not in use. Product

has a shelf life of 24 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Dust/mist respirator. (95%)

Hand Protection Normal work gloves.

Skin Protection Normal work coveralls.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions None known.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Clear to hazy

Odor: Mild sulfur

pH: 8

Specific Gravity @ 20 C (Water=1): 1.27

Density @ 20 C (lbs./gallon): 10.58

GEL-STA L STABILIZER

Page 2 of 5

HESI100776
9. PHYSICAL AND CHEMICAL PROPERTIES

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): 224

Boiling Point/Range (C): 106

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Miscible

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Oxides of sulfur.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation.

Skin Contact May cause skin irritation.

Eye Contact May cause eye irritation.

Ingestion None known

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

GEL-STA L STABILIZER

Page 3 of 5

HESI100777
Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

Other Shipping Information

GEL-STA L STABILIZER

Page 4 of 5

HESI100778
Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

None

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class Un-Controlled

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

GEL-STA L STABILIZER

Page 5 of 5

HESI100779
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: GEL-STA STABILIZER

Revision Date: 04-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: GEL-STA STABILIZER

Synonyms: None

Chemical Family: Sulfate

Application: Stabilizer

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Sodium thiosulfate 7772-98-7 60 - 100% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

GEL-STA STABILIZER

Page 1 of 5

HESI100780
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media All standard firefighting media.

Special Exposure Hazards Decomposition in fire may produce toxic gases.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 1, Flammability 0, Reactivity 0

HMIS Ratings: Health 1, Flammability 0, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Avoid creating and breathing dust.

Environmental Precautionary

Measures

None known.

Procedure for Cleaning /

Absorption

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid creating or inhaling dust.

Storage Information Store in a cool, dry location.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Not normally needed. But if significant exposures are possible then the following

respirator is recommended:

Dust/mist respirator. (95%)

Hand Protection Normal work gloves.

Skin Protection Normal work coveralls.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions None known.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid

Color: White

Odor: Odorless

pH: 8.6

Specific Gravity @ 20 C (Water=1): 1.69

GEL-STA STABILIZER

Page 2 of 5

HESI100781
9. PHYSICAL AND CHEMICAL PROPERTIES

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): 27

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): 42

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): 248.2

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials to

Avoid)

Avoid halogens. Contact with acids. Contact with lead.

Hazardous Decomposition

Products

Oxides of sulfur. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation Vapors given off by heated product may be harmful.

Skin Contact May cause skin irritation.

Eye Contact May cause eye irritation.

Ingestion None known

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are

chronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

GEL-STA STABILIZER

Page 3 of 5

HESI100782
Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

 Not restricted

Canadian TDG

Not restricted

ADR

 Not restricted

Air Transportation

ICAO/IATA

 Not restricted

Sea Transportation

IMDG

 Not restricted

GEL-STA STABILIZER

Page 4 of 5

HESI100783
Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class D2B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

GEL-STA STABILIZER

Page 5 of 5

HESI100784
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: HAI-150E

Revision Date: 03-Jan-2008

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: HAI-150E

Synonyms: None

Chemical Family: Blend

Application: Corrosion Inhibitor

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Contains no hazardous

substances

Mixture 60 - 100% Not applicable Not applicable

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation.

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation

develops or if breathing becomes difficult.

Skin Get medical attention if irritation persists. Wash with soap and water.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes

and get medical attention if irritation persists.

Ingestion Under normal conditions, first aid procedures are not required.

Notes to Physician Not Applicable

HAI-150E

Page 1 of 5

HESI100797
5. FIRE FIGHTING MEASURES

Flash Point/Range (F): Not Determined

Flash Point/Range (C): Not Determined

Flash Point Method: Not Determined

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media All standard firefighting media.

Special Exposure Hazards Organic dust in the presence of an ignition source can be explosive in high

concentrations. Good housekeeping practices are required to minimize this

potential.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 0, Flammability 0, Reactivity 0

HMIS Ratings: Health 0, Flammability 0, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment.

Environmental Precautionary

Measures

None known.

Procedure for Cleaning /

Absorption

Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid creating or inhaling dust.

Storage Information Store away from oxidizers. Store in a dry location.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls A well ventilated area to control dust levels.

Respiratory Protection Not normally needed. But if significant exposures are possible then the following

respirator is recommended:

Dust/mist respirator. (95%)

Hand Protection Normal work gloves.

Skin Protection Normal work coveralls.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions None known.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid

Color: Brown

Odor: Coffee bean

HAI-150E

Page 2 of 5

HESI100798
9. PHYSICAL AND CHEMICAL PROPERTIES

pH: Not Determined

Specific Gravity @ 20 C (Water=1): Not Determined

Density @ 20 C (lbs./gallon): Not Determined

Bulk Density @ 20 C (lbs/ft3): 8.7

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): Not Determined

Freezing Point/Range (C): Not Determined

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid None known.

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause mild respiratory irritation.

Skin Contact May cause mild skin irritation.

Eye Contact May cause mild eye irritation.

Ingestion None known

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity Generally Recognized As Safe (GRAS)

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

HAI-150E

Page 3 of 5

HESI100799
Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

Not restricted

Canadian TDG

Not restricted

ADR Not restricted

Air Transportation

ICAO/IATA Not restricted

Sea Transportation

IMDG Not restricted

Other Shipping Information

Labels: None

HAI-150E

Page 4 of 5

HESI100800
15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

None

EPA SARA (313) Chemicals This product does not contain a toxic chemical for routine annual "Toxic Chemical

Release Reporting" under Section 313 (40 CFR 372).

EPA CERCLA/Superfund

Reportable Spill Quantity

Not applicable.

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as

defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law Does not apply.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law Does not apply.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class Un-Controlled

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

HAI-150E

Page 5 of 5

HESI100801
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: HAI-404

Revision Date: 05-Jan-2010

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: HAI-404

Synonyms: None

Chemical Family: Blend

Application: Corrosion Inhibitor

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Chloromethylnaphthalene

quinoline quaternary amine

15619-48-4 5 - 10% Not applicable Not applicable

Methanol 67-56-1 10 - 30% 200 ppm 200 ppm (S)

Aldehyde 10 - 30% Not applicable Not applicable

Isopropanol 67-63-0 10 - 30% 200 ppm 400 ppm

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause headache, dizziness, and

other central nervous system effects. May be fatal if swallowed. May cause

blindness. May be absorbed through the skin. Repeated overexposure may cause

liver and kidney effects. Flammable.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

HAI-404

Page 1 of 6

HESI100802
Notes to Physician Not Applicable

5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 62

Flash Point/Range (C): 16.7

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Carbon Dioxide, Dry Chemicals, Foam.

Special Exposure Hazards May be ignited by heat, sparks or flames. Use water spray to cool fire exposed

surfaces. Closed containers may explode in fire. Decomposition in fire may produce

toxic gases. Runoff to sewer may cause fire or explosion hazard.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 3, Reactivity 0

HMIS Ratings: Health 2, Flammability 3, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Wear self-contained breathing apparatus in

enclosed areas.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Remove ignition sources and work with nonsparking tools. Contain spill with sand or other inert materials. Scoop up and

remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse. Ground and bond containers

when transferring from one container to another.

Storage Information Product has a shelf life of 24 months. Store away from oxidizers. Keep from heat,

sparks, and open flames. Keep container closed when not in use.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Positive pressure self-contained breathing apparatus if methanol is released.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

HAI-404

Page 2 of 6

HESI100803
Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Dark brown

Odor: Alcohol

pH: 2-4

Specific Gravity @ 20 C (Water=1): 0.979

Density @ 20 C (lbs./gallon): 8.16

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): < -30

Freezing Point/Range (C): < -34.4

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): 2-25

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Ammonia. Oxides of nitrogen. Oxides of phosphorus. Hydrocarbons. Carbon

monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. May cause central nervous system depression

including headache, dizziness, drowsiness, incoordination, slowed reaction time,

slurred speech, giddiness and unconsciousness.

Skin Contact May cause skin irritation. May be absorbed through the skin and produce effects

similar to those caused by inhalation and/or ingestion.

Eye Contact May cause eye irritation.

HAI-404

Page 3 of 6

HESI100804
Ingestion May be fatal or cause blindness if swallowed. May cause central nervous system

depression including headache, dizziness, drowsiness, muscular weakness,

incoordination, slowed reaction time, fatigue blurred vision, slurred speech,

giddiness, tremors and convulsions. May cause liver and kidney damage.

Aggravated Medical Conditions Skin disorders. Eye ailments.

Chronic Effects/Carcinogenicity Prolonged or repeated exposure may cause eye, blood, lung, liver, kidney, heart,

central nervous system and spleen damage.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

HAI-404

Page 4 of 6

HESI100805
UN1993,Flammable Liquid, N.O.S.(Contains Isopropanol, Methanol), 3, II, (16.7 C)

NAERG 128

Canadian TDG

Flammable Liquid, N.O.S.(Contains Isopropanol, Methanol), 3, UN1993, II, (16.7 C)

ADR

UN1993,Flammable Liquid, N.O.S.(Contains Isopropanol, Methanol), 3, II

Air Transportation

ICAO/IATA

UN1993,Flammable Liquid, N.O.S., 3, II

(Contains Isopropanol, Methanol Solution)

Sea Transportation

IMDG

UN1993,Flammable Liquid, N.O.S.(Contains Isopropanol, Methanol), 3, II, (16.7 C)

EmS F-E, S-E

Other Shipping Information

Labels: Flammable Liquid

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Methanol//67-56-1

Isopropanol//67-63-0

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 3608 Gallons based on Methanol (CAS: 67-56-1).

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Ignitability D001

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

HAI-404

Page 5 of 6

HESI100806
MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

Canadian Regulations

Canadian DSL Inventory All components listed on inventory.

WHMIS Hazard Class B2 Flammable Liquids

D1A Very Toxic Materials

D1B Toxic Materials

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS

Not applicable

Additional Information For additional information on the use of this product, contact your local Halliburton

representative.

For questions about the Material Safety Data Sheet for this or other Halliburton

products, contact Chemical Compliance at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy

or completeness. The information is obtained from various sources including the

manufacturer and other third party sources. The information may not be valid under

all conditions nor if this material is used in combination with other materials or in any

process. Final determination of suitability of any material is the sole responsibility of

the user.

***END OF MSDS***

HAI-404

Page 6 of 6

HESI100807
 

MATERIAL SAFETY DATA SHEET

Product Trade Name: HAI-404MTM

Revision Date: 05-Jan-2009

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Trade Name: HAI-404MTM

Synonyms: None

Chemical Family: Blend

Application: Corrosion Inhibitor

Manufacturer/Supplier Halliburton Energy Services

P.O. Box 1431

Duncan, Oklahoma 73536-0431

Emergency Telephone: (281) 575-5000

Prepared By Chemical Compliance

Telephone: 1-580-251-4335

e-mail: fdunexchem@halliburton.com

2. COMPOSITION/INFORMATION ON INGREDIENTS

SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA

Aldehyde 10 - 30% Not applicable Not applicable

Chloromethylnaphthalene

quinoline quaternary amine

15619-48-4 5 - 10% Not applicable Not applicable

Methanol 67-56-1 10 - 30% 200 ppm 200 ppm (S)

Isopropanol 67-63-0 10 - 30% 200 ppm 400 ppm

3. HAZARDS IDENTIFICATION

Hazard Overview May cause eye, skin, and respiratory irritation. May cause headache, dizziness, and

other central nervous system effects. May be fatal if swallowed. May cause

blindness. May be absorbed through the skin. Repeated overexposure may cause

liver and kidney effects. Flammable.

4. FIRST AID MEASURES

Inhalation If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably

mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention.

Skin In case of contact, immediately flush skin with plenty of soap and water for at least 15

minutes. Get medical attention. Remove contaminated clothing and launder before

reuse.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water

for at least 15 minutes and get medical attention immediately after flushing.

HAI-404MTM

Page 1 of 6

HESI100808
Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek

medical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

5. FIRE FIGHTING MEASURES

Flash Point/Range (F): 69

Flash Point/Range (C): 20.6

Flash Point Method: PMCC

Autoignition Temperature (F): Not Determined

Autoignition Temperature (C): Not Determined

Flammability Limits in Air - Lower (%): Not Determined

Flammability Limits in Air - Upper (%): Not Determined

Fire Extinguishing Media Carbon Dioxide, Dry Chemicals, Foam.

Special Exposure Hazards May be ignited by heat, sparks or flames. Use water spray to cool fire exposed

surfaces. Closed containers may explode in fire. Decomposition in fire may produce

toxic gases. Runoff to sewer may cause fire or explosion hazard.

Special Protective Equipment for

Fire-Fighters

Full protective clothing and approved self-contained breathing apparatus required for

fire fighting personnel.

NFPA Ratings: Health 2, Flammability 3, Reactivity 0

HMIS Ratings: Health 2, Flammability 3, Reactivity 0

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse appropriate protective equipment. Wear self-contained breathing apparatus in

enclosed areas.

Environmental Precautionary

Measures

Prevent from entering sewers, waterways, or low areas.

Procedure for Cleaning /

Absorption

Isolate spill and stop leak where safe. Remove ignition sources and work with nonsparking tools. Contain spill with sand or other inert materials. Scoop up and

remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after

use. Launder contaminated clothing before reuse. Ground and bond containers

when transferring from one container to another.

Storage Information Store away from oxidizers. Keep from heat, sparks, and open flames. Keep container

closed when not in use. Product has a shelf life of 24 months.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas

without good cross ventilation.

Respiratory Protection Positive pressure self-contained breathing apparatus if methanol is released.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.

HAI-404MTM

Page 2 of 6

HESI100809
Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid

Color: Dark brown

Odor: Alcohol

pH: 3.72

Specific Gravity @ 20 C (Water=1): 0.988

Density @ 20 C (lbs./gallon): 8.23

Bulk Density @ 20 C (lbs/ft3): Not Determined

Boiling Point/Range (F): Not Determined

Boiling Point/Range (C): Not Determined

Freezing Point/Range (F): < -20

Freezing Point/Range (C): < -20

Vapor Pressure @ 20 C (mmHg): Not Determined

Vapor Density (Air=1): Not Determined

Percent Volatiles: Not Determined

Evaporation Rate (Butyl Acetate=1): Not Determined

Solubility in Water (g/100ml): Soluble

Solubility in Solvents (g/100ml): Not Determined

VOCs (lbs./gallon): Not Determined

Viscosity, Dynamic @ 20 C (centipoise): Not Determined

Viscosity, Kinematic @ 20 C (centistrokes): Not Determined

Partition Coefficient/n-Octanol/Water: Not Determined

Molecular Weight (g/mole): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerization: Will Not Occur

Conditions to Avoid Keep away from heat, sparks and flame.

Incompatibility (Materials to

Avoid)

Strong oxidizers.

Hazardous Decomposition

Products

Ammonia. Oxides of nitrogen. Oxides of phosphorus. Hydrocarbons. Carbon

monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Inhalation May cause respiratory irritation. May cause central nervous system depression

including headache, dizziness, drowsiness, incoordination, slowed reaction time,

slurred speech, giddiness and unconsciousness.

Skin Contact May cause skin irritation. May be absorbed through the skin and produce effects

similar to those caused by inhalation and/or ingestion.

Eye Contact May cause eye irritation.

HAI-404MTM

Page 3 of 6

HESI100810
Ingestion May be fatal or cause blindness if swallowed. May cause central nervous system

depression including headache, dizziness, drowsiness, muscular weakness,

incoordination, slowed reaction time, fatigue blurred vision, slurred speech,

giddiness, tremors and convulsions. May cause liver and kidney damage.

Aggravated Medical Conditions Skin disorders. Eye ailments.

Chronic Effects/Carcinogenicity Prolonged or repeated exposure may cause eye, blood, lung, liver, kidney, heart,

central nervous system and spleen damage.

Other Information None known.

Toxicity Tests

Oral Toxicity: Not determined

Dermal Toxicity: Not determined

Inhalation Toxicity: Not determined

Primary Irritation Effect: Not determined

Carcinogenicity Not determined

Genotoxicity: Not determined

Reproductive /

Developmental Toxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Not determined

Bio-accumulation Not Determined

 Ecotoxicological Information

Acute Fish Toxicity: Not determined

Acute Crustaceans Toxicity:Not determined

Acute Algae Toxicity: Not determined

Chemical Fate Information Not determined

Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state, and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

DOT

UN1993,Flammable Liquid, N.O.S.(Contains Isopropanol, Methanol), 3, II, (20.6 C)

HAI-404MTM

Page 4 of 6

HESI100811
NAERG 128

Canadian TDG

Flammable Liquid, N.O.S.(Contains Isopropanol, Methanol), 3, UN1993, II, (20.6 C)

ADR

UN1993,Flammable Liquid, N.O.S.(Contains Isopropanol, Methanol), 3, II

Air Transportation

ICAO/IATA

UN1993,Flammable Liquid, N.O.S., 3, II

(Contains Isopropanol, Methanol Solution)

Sea Transportation

IMDG

UN1993,Flammable Liquid, N.O.S.(Contains Isopropanol, Methanol), 3, II, (20.6 C)

EmS F-E, S-E

Other Shipping Information

Labels: Flammable Liquid

15. REGULATORY INFORMATION

US Regulations

US TSCA Inventory All components listed on inventory or are exempt.

EPA SARA Title III Extremely

Hazardous Substances

Not applicable

EPA SARA (311,312) Hazard

Class

Acute Health Hazard

Chronic Health Hazard

Fire Hazard

EPA SARA (313) Chemicals This product contains toxic chemical(s) listed below which is(are) subject to the

reporting requirements of Section 313 of Title III of SARA and 40 CFR Part 372:

Methanol//67-56-1

EPA CERCLA/Superfund

Reportable Spill Quantity

EPA Reportable Spill Quantity is 2612 Gallons based on Methanol (CAS: 67-56-1).

EPA RCRA Hazardous Waste

Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as

defined by the US EPA, because of:

Ignitability D001

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

HAI-404MTM

Page 5 of 6

HESI100812