### From: Mullins, Gladys K [ mailto:Gladys.K.Mullins@wv.gov ] Sent: Monday, February 25, 2013 11:45 AM To: Elizabeth Sabol; DEP FOIA; Ombler, Tonya K Cc: Mullins, Gladys K Subject: FW: 2013-01-127 - Elizabeth Sabol - January 28, 2013



### Please see attach information you requested. If you need anything else please let me know.

From: Chaney, David L Sent: Tuesday, February 05, 2013 3:20 PM To: Mullins, Gladys K Subject: RE: 2013-01-127 – Elizabeth Sabol – January 28, 2013



### Attached is the information the FOIA is requesting the Armour Creek Landfill (Solutia Inc.) for the
manganese the unit is wrong it should be ug/l see attached PDF report for 9/11 page 7 of 23 for Outlet 011. I have also attached the PDF TestAmerica Analytical Report for 12/2011 concerning Outfall 011 for 2,3,7,8-Tetrachlorodibenzo-p-dioxin fo r the concentration information.



### David L. Chaney Geologist III WV DEP 254 Industrial Drive Oak Hill, WV 25901 304

‐ 465

‐ 1919 Ext. 3053

From: DEP FOIA Sent: Monday, January 28, 2013 11:33 AM To: Ombler, Tonya K Cc: Kozak, Peggy J Subject: 2013-01-127 – Elizabeth Sabol – January 28, 2013



## 2013

‐ 01

‐ 127

– Elizabeth Sabol

– January 28, 2013

Re: Freedom of Information Act (FOIA) Request #2013

‐ 01

‐ 127

Attached, please find a FOIA from Elizabeth Sabol with Eastern Research Group. Please contact the requester at Elizabeth.sabol@erg.com to let them know whether or not you have the requested information and when they can view/copy/receive it. Please reference the above FOIA number and respond to depfoia@wv.gov with the amount invoiced and your mail code when complete.

Sarah Alford

Ext. 1641

### From: Elizabeth Sabol [ mailto:Elizabeth.Sabol@erg.com ] Sent: Monday, January 28, 2013 10:46 AM To: DEP FOIA Cc: swietlik.william@epa.gov ; Eleanor Codding; Kim Wagoner Subject: 2011 DMR Data Request - WV DEP Ms. Hoskins/Ms. Kozak,

EPA is requesting 2011 DMR data for two West Virginia facilities: Elke m Metals Company, in Alloy, WV (WV0000167) and Armour Creek Landfill, in Nitro, WV (WV0077020). I am writing to request clarification for these two facilities on behalf of EPA under Cont ract No. EP-C-12-021. Please see below for further background.
EPA, Office of Water (OW), reviews DMR data to fu lfill its review obligation under Section 304(b) of the Clean Water Act. The CWA requires EPA to annually re view and, if appropriate, revise its water pollution control technology-based regulations, called "effluent lim itations guidelines" or "effluent guidelines," that limit the discharge of pollutants to waters of the U.S. fr om various categories of industrial facilities. EPA is currently conducting its 2013 annual review of existi ng effluent guidelines and potential industrial guidelines which may need to be included (see http://www.epa.gov/guide/304m/ for further information). EPA will discuss this review and the re sults in its 2013 Effluent Guidelines Program Plan scheduled for publication in the Federal Register sometime in 2013 or 2014.

As part of the 2013 annual review, EPA is evaluati ng 2011 DMR data and needs further information to complete the review. Specifically, we would like to clarify the following for the two facilities:
(1) Elkem Metals Company, in Alloy, WV (WV0000167) - Confirm 2011 flow values and units for Outfalls 002, 004, 005, and 007. - Confirm 2011 concentration values and units for Outfalls 002, 004, 005, and 007 for the following pollutants: cadmium, lead, selenium, arsenic, he xavalent chromium, nickel, chromium, trivalent chromium, vanadium, antimony, and aluminum.
(2) Armour Creek Landfill, in Nitro, WV (WV0077020) - Confirm Outfall 011, 2011 2,3,7,8-Tetrachlorodiben zo-p-dioxin concentration, specifically the below detection indicator. - Confirm Outfall 011, manganese co ncentration for September 2011.

If you have any questions about EPA's request, plea se contact me directly at 610-344-0829. If you would like to speak directly with EPA regarding this reques t, you can contact William F. Swietlik of EPA's Office of Water/Engineering Analysis Division by phone at (202) 566-1129 or by email: swietlik.william@epa.gov

. Thank you, Elizabeth

Elizabeth A. Sabol Environmental Engineer Eastern Research Group, Inc. 14555 Avion Parkway, Suite 200 Chantilly, VA 20151 elizabeth.sabol@erg.com

# ANALYTICAL REPORT

TestAmerica Laboratories, Inc. TestAmerica Savannah 5102 LaRoche Avenue Savannah, GA 31404 Tel: (912)354-7858
TestAmerica Job ID: 680-72273-2 Client Project/Site: ACLF - Outlet 011 Monthly - SEP 2011
For: Potesta & Associates 7012 MacCorkle Avenue, S.E. Charleston, West Virginia 25304

Attn: Mr. Mike Light

Authorized for release by: 09/27/2011 03:32:48 PM Lidya Gulizia Project Manager II lidya.gulizia@testamericainc.com

cc: Lisa Sullivan

Results relate only to the items tested and the sample(s) as received by the laboratory. The test results in this report meet all 2003 NELAC and 2009 TNI requirements for accredited parameters, exceptions are noted in this report. This report may not be reproduced except in full, and with written approval from the laboratory. For questions please contact the Project Manager at the e-mail address or telephone number listed on this page. This report has been electronically signed and authorized by the signatory. Electronic signature is intended to be the legally binding equivalent of a traditionally handwritten signature. 

### Page 1 of 23 

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# Table of Contents Client: Potesta & Associates Project/Site: ACLF - Outlet 011 Monthly - SEP 2011 TestAmerica Job ID: 680-72273-2



### Page 2 of 23 

# Cover Page . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 

# Table of Contents . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2 

# Case Narrative . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3 

# Sample Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4 

# Method Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5 

# Definitions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6 

# Client Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7 

# Surrogate Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 10 

# QC Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 11 

# QC Association . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 18 

# Chronicle . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 20 

# Chain of Custody . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 21 

# Receipt Checklists . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 22 

# Certification Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 23 

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14880 Riverside Parkway West Sacramento, CA 95605 tel 916.373.5600 fax 916.372.1059 www.testamericainc.com 

## January 3, 2012

TestAmerica Project Number: G1L140412 PO/Contract: 4503741800
Mike Light Potesta & Associates Inc 7012 MacCorkle Avenue, SE Charleston, WV 25304

Dear Mr. Light,
This report contains the analytical result s for the sample received under chain of custody by TestAmerica on December 13, 2011. This sample is associated with your 0101-01-0081 project.
The test results in this report meet a ll NELAC requirements for parameters that accreditation is required or available. Any exceptions to NELAC requirements are noted in the case narrative. The case narra tive is an integral part of this report.
If you have any questions, please feel free to call me at (916) 374-4402.
Sincerely,

Jill Kellmann Project Manager

G1L140412 TestAmerica West Sacramento (916) 373 - 5600 1 of 100

# Table of Contents 

# TestAmerica West Sacramento Project Number G1L140412

Case Na rrative.................................................................................3
Sacramento Quality Assurance Program ........................................4
Sample Summary............................................................................5
Analytical Me thods Su mmary ..........................................................6

Method / Anal yst Summary .............................................................7
Sample Data Sheet s........................................................................8

WATER, 1613B, 2,3,7,8-TCDD Sample: 1

QC Data Associ ation Su mmary.......................................................9
Laboratory QC Reports .................................................................10

Raw Data Package ........................................................................12
Shipping and Receivi ng Document s.......................................95-100

# Table of Contents 

# TestAmerica West Sacramento Project Number G1L140412

Case Narrative
Sacramento Quality Assurance Program
Sample Summary
Analytical Methods Summary
Method / Analyst Summary
Sample Data Sheets

WATER, 1613B, 2,3,7,8-TCDD Sample: 1
QC Data Association Summary
Laboratory QC Reports
Raw Data Package
Shipping and Receiving Documents

G1L140412 TestAmerica West Sacramento (916) 373 - 5600 2 of 100

# Case Narrative TestAmerica West Sacramento Project Number G1L140412

There are no anomalies associated with this project.

G1L140412 TestAmerica West Sacramento (916) 373 - 5600 3 of 100

### TestAmerica Laboratories West Sacramento Certifications/Accreditations Certifying State Certificate # Certifying State Certificate # A2LA (DoD-ELAP) 2928-01 New Mexico NA Alaska UST-055 New York* 11666 Arizona AZ0708 Oregon* CA 200005 Arkansas 88-0691 Pennsylvania* 68-1272 California* 01119CA South Carolina 87014

Colorado NA Texas* T104704399-08-TX Connecticut PH-0691 UCMR CA00044

Florida* E87570 US Fish & Wildlife LE148388-0 Georgia 960 USDA Foreign Plant 37-82605 Guam 10-009r USDA Foreign Soil P330-09-00055 Hawaii NA Utah* QUAN1 Illinois* 002701 Virginia 178 Kansas* E-10375 Washington C581 Louisiana* 01944 West Virginia 9930C, 334 Michigan 9947 Wisconsin 998204680 Nevada CA44 Wyoming 8TMS-Q New Jersey* CA005 *NELAP accredited. A more detailed para meter list is available upon request. Updated 5/25/2011 

## QC Parameter Definitions QC Batch : The QC batch consists of a set of up to 20 field samples that behave similarly (i.e., same matrix) and are processed using the same procedures, reagents, and standards at the same time.


### Method Blank : An analytical control consisting of all reagents, which may include internal standards and surrogates, and is carried through the entire analytical procedure. The method blank is used to define the level of laboratory background contamination. 

### Laboratory Control Sample and Laboratory Control Sample Duplicate (LCS/LCSD): An aliquot of blank matrix spiked with known amounts of representative target analytes. The LCS (and LCSD as required) is carried through the entire an alytical process and is used to m onitor the accuracy of the analytical process independent of potential matrix effects. If an LCSD is performed, it may also be used to evaluate the precision of the process. 

### Duplicate Sample (DU): Different aliquots of the same sample are analyzed to evaluate the precision of an analysis. 

### Surrogates: Organic compounds not expected to be detected in field samples, which behave similarly to target analytes. These are added to every sample within a batch at a known concentration to determine the efficiency of the sample prep aration and analytical process. 

### Matrix Spike and Matrix Spike Duplicate (MS/MSD): An MS is an aliquot of a matrix fortified with known quantities of specific compounds and subjected to an entire analytical procedure in order to indicate the appropriateness of the method for a particular matrix. The percent recovery for the respective compound(s) is then calculated. The MSD is a second aliquot of the same matrix as the matrix spike, also spiked, in order to determine the precision of the method. 

### Isotope Dilution : For isotope dilution methods, isotopically labeled analogs (internal standards) of the native target analytes are spiked into the sample at time of extraction. These internal standards are used for quantitation, and monitor and correct for matrix effect s. Since matrix effects on method performance can be judged by the recovery of these analogs, there is little added benefit of performing MS/MSD for these methods. MS/MSD are only performed for client or QAPP requirements.


### Control Limits: The reported control limits are either based on laboratory historical data, method requirements, or project data quality objectives. The control limits represent the estimated uncertainty of the test results.

G1L140412 TestAmerica West Sacramento (916) 373 - 5600 4 of 100G1L140412 TestAmerica West Sacramento (916) 373 - 5600 5 of 100 

# Sample Summary
TestAmerica West Sacramento Project Number G1L140412

WO# MPND6



### Notes(s): Sample# Client Sample ID 1 OUTLET011 

### Sampling Date 12/12/2011 09:55AM

The analytical results of the samples listed above are presented on the following pages. All calculations are performed before rounding to avoid round-off errors in calculated results.
Results noted as "ND" were not detected at or above the stated limit.
This report must not be reproduced, except in full, without the written approval of the laboratory. 

### Received Date 12/13/2011 09:15 AM

Results for the following parameters are never reported on a dry weight basis: color, corrosivity, density, flashpoint, ignitability, layers, odor, paint filter test, pH, porosity, pressure, reactivity, redox potential, specific gravity, spot tests, solids, solubility, temperature, viscosity, and weight.G1L140412 TestAmerica West Sacramento (916) 373 - 5600 6 of 100 

### PARAMETER 

## ANALYTICAL METHODS SUMMARY

GlL140412



### ANALYTICAL METHOD

Dibenzodioxins and Dibenzofurans, HRGC/HRMS EPA-5 1613B-Tetras

References:



### EPA-5 "Method 1613: Tetra- through Octa- Chlorinated Dioxins and Furans by Isotope Dilution, HRGC/HRMS, Revision B", EPA, OCTOBER 1994G1L140412 TestAmerica West Sacramento (916) 373 - 5600 7 of 100 

# MEmOD I ANALYST SUMMARY

G1L140412



### ANALYTICAL**~ME~T~H~O~D________________________ AN~~AL~Y~S~T---------------------------** 


### EPA-5 1613B-Tetras Sonia Ouni



### References: ANALYST ID

006881

EPA-5 "Method 1613: Tetra- through Octa- Chlorinated Dioxins and Furans by 

### Isotope Dilution, HRGC/HRMS, Revision B", EPA, OCTOBER 1994G1L140412 TestAmerica West Sacramento (916) 373 - 5600 8 of 100 

### Lot

- Sample #

.... : Date Sampled

.... : Prep Date .•.. : Prep Batch # ..•. : Initial WgWol :

PARAMETER 2,3,7,8-TCDD 

### G1L140412- 001 12112/11 12/21/11 1355069 1021.31 mL

RESULT

ND

INTERNAL STANDARDS 13C-2,3,7,8-TCDD

SURROGATE 37CI4-2,3,7,8-TCDD

QUALIFIERS 

### Potesta & Associates Inc Sample 

### ID: OUTLET 011

Trace Level Organic Compounds



### EPA-5 1613B-Tetras

Work Order# •... : Date Received

.... : Analysis Date

.... : Instrument ID

.... : Analyst ID

.... : 

### MPND61AA 12113111 12/27/11 9D5 

### Sonia Ouni

REPORTING LIMIT
9.8

PERCENT RECOVERY 68

PERCENT RECOVERY
89 Matrix

.... : 

### WATER Dilution Factor:

ESTIMATED DETECTION LIMIT UNITS

1.8 pg!L



### RECOVERY LIMITS 31

- 137

RECOVERY LIMITS
42- 164

\\qsacsqll \QDSApps\SOG_Stnd\EDL_RL_Report.rpt 12/29/20 IIG1L140412 TestAmerica West Sacramento (916) 373 - 5600 9 of 100 

### SAMPLE#

001 

# QC 

# DATA ASSOCIATION SUMMARY

G1L140412



### Sample Preparation and Analysis Control Numbers

MATRIX

WATER ANALYTICAL 

### METHOD

EPA-5 1613B-Tetra LEACH BATCH # PREP BATCH #

1355069 MS RUN#G1L140412 TestAmerica West Sacramento (916) 373 - 5600 10 of 100 Lot- Sample#

.... : Date Sampled ..•• : Prep Date •••. : Prep Batch #

.... : Initial WgWol:

PARAMETER 2,3,7,8-TCDD 

### GlL210000- 069B 12/09/11 12/21/11 1355069 1000mL

RESULT

ND

INTERNAL STANDARDS 13C-2,3,7,8-TCDD

SURROGATE 37Cl4-2,3,7,8-TCDD

QUALIFIERS 

### Method Blank Report

Trace Level Organic Compounds



### EPA-5 1613B-Tetras

Work Order#

.... : Date Received

.... : Analysis Date

.... : Instrument ID

.... : Analyst ID

.... : 

### MPT231AA 12/15/11 12/23111 9D5 Sonia Ouni

REPORTING LIMIT
10

PERCENT RECOVERY
41

PERCENT RECOVERY
91 Matrix

.... : Dilution Factor: 

### WATER 1

ESTIMATED DETECTION LIMIT UNITS

3.2 pg/L

RECOVERY LIMITS
31

- 137

RECOVERY LIMITS
42- 164

\\qsacsqll \QDSApps\SOG_Stnd\EDL_RL_Report.rpt 12/29/2011G1L140412 TestAmerica West Sacramento (916) 373 - 5600 11 of 100 

### Client Lot #

... : LCS Lot-Sample# : Prep Date ...•.• : Prep Batch # ••. : Dilution Factor : Analyst ID •.•.. : Initial Wgt/Vol:

PARAMETER 

### 2,3,7,8-1r<:I>I> G1L140412 G1L210000- 069 12/21/11 1355069

Sonia Ouni 

### IOOOmL

SPIKE AMOUNT


### 200 

### 200

INTERNAL STANDARD 

### 13C-2,3, 7,8- TCDD

SURROGATE 

### 37CI4-2,3, 7,8- TCDD

Notes: LABORATORY CONTROL SAMPLE DATA REPORT

Trace Level Organic Compounds

Work Order#

... : 

### MPT231AC-LCS MPT231AD-LCSD Analysis Date

.. : 

### 12/23111

Instrument ID

.. : 

### 9D5 Method

..... :

MEASURED PERCENT AMOUNT UNITS RECOVERY 

### 209 pg/L 

### 104 217 pg/L 

### 109

PERCENT RECOVERY



### 36 43

PERCENT RECOVERY



### 90 86

Calculations are performed before rounding to avoid round-off errors in calculated results. Bold print denotes control parameters 

### Matrix .••...... : 

### WATER



### EPA-5 1613B-Tetr

RECOVERY LIMITS RPD RPDLIMITS 

### (73 -146) (73- 146) 3.9 (0- 50)

RECOVERY LIMITS 

### (25- 141) (25- 141)

RECOVERY LIMITS 

### (37- 158) (37- 158)

\ \qsacsqii\QDSApps\SOG

_ Std\SOG

_ Stnd _Icslcd _rev l.rpt 12/29/2011G1L140412 TestAmerica West Sacramento (916) 373 - 5600 12 of 100 

# Raw Data PackageG1L140412 TestAmerica West Sacramento (916) 373 - 5600 13 of 100 

# WATER, 16138, 2,3,7,8-TCDD, WWG1L140412 TestAmerica West Sacramento (916) 373 - 5600 14 of 100 

# ICVJVCV Summaries/ 

# Run LogsG1L140412 TestAmerica West Sacramento (916) 373 - 5600 15 of 100 

# Test America- West Sacramento 

# Test 

# America

Initial Calibration Checklist Dioxih Methods THE LEADER IN ENVIRONMENTAL TESTING



## ICALID

# (lz,~oJ !Lil, 

# ToV4. 1 

# 0021]\

# Jf.1~As)Jno/J**~()}**

Method ID

# ~D)**I~I3&J** 

# Toq> 21) 

# 0011A

Column ID 

# P**R~** STD ID·s 

## -n....!..l..::..lt=--o-( 

# £-,-A---, 

# o_J_c...,_)-

) 1


# oc Program 

# _O_G_OO

_______ _

- - ··-AD.afyied 

# By**--'-~_;_'.....:;.C_._.** ----- 

## Prepared 

## By

# --!-M~b 

# ______ _
Reviewed 

## By

___ 

# J_f(_B

____ _ Date Scanned



# -------
Instrument ID

# ----!...:~ 0::.._f

__ _ STD Solution 

## 1J

# 0"'~**(21~1** l2D J 

## ll- 

# JJ 221 J

# l'l,~)

Date Prepared _1'2_

... /!.._t_o..;___//

__ _



## Date Reviewed

__ \ 

# 2_,.j_2

.......

# ~1--0.:....:1 (:..___

## ~i~::~~----.~**~-~~~~:--~~i~~=-i ~~~~-'~.~:~~~;b::f~~~~::~:~~-:J~~·2,~:~.:~-r~~~;~~~-~:i.·~~,:~i~** **·.;~~~&~:~{~-~-~~j~~i~~~~llij~~~~~~~!~~3:li:** Curve summary 

## present? 

## ./ Hardcopies of cbiomatograms for 

## CS 1-CSS present? 

# / Copy oflog-file present?· 

# ./ Static resolution check present? 

# ./. Target file R T' s correct? 

# 7 %RSD 

## within method-specified limits?* · 

# .7 Signal-to-noise criteria met? 

# 7 Isotopic ratios 

## within limits?

## ~ Highpoint 

## free of saturation? ,/


## Are chromatographic windows correct?**~** 

## Manual reintegration•s checked and hardcopies included? 

# NA.

COMMENTS: 

# RT:
32.: 

# lj()

*Method 8290/f09/M0023A: %RSD 90% for natives,**~30%** 

### for labeled compounds; S/N2:_10

Method 1613B:**o/oRSD~** 

### 20% 

### natives, 90% labeled compounds; SIN 2:10 Method23: %R$D**~values** 

### specified 

### in Table 5, Method23; S/N2:2.5

N:\Hires\Forms\QA-384 Dioxins ICAL Checklisldoc 

## ./ 

## /**.~** ,/


### ./ 

# v v 

# v ./ 

# -v tVA

QA-384 7/25106 DAWG1L140412 TestAmerica West Sacramento (916) 373 - 5600 16 of 100 

### .vata file Smp Work Order

20DE119D5 1 CP1220 20DE119D5 2 ST1220 20DE119D5 3 ST1220A 20DE119D5 4 ST1220B 20DE119D5 5 ST1220C 20DE119D5 6 ST1220D 20DE119D5 7 ST1220E 20DE119D5 8 

### 20DE119D5 9 20DE119DS 10 20DE119D5 11 

### Sample ID

DB-5 CPSM 3732-16 CS-3 11DXN221 CS-2 11DXN220 CS-1 11DXN219 CS-5 11DXN223 CS-4 11DXN222 2nd Source 11DXN210

MG 12/20/11 FV-uL Method/Matrix Box Size 

# u

1.00000 1. 

### 00000 1.00000 1.00000 1.00000 1.00000 1. 

### 00000 1.00000 1. 

### 00000 1.00000 1. 

### 00000

# ~~~ \L

# c~e-ck~ .f
\d...-J..o-\l

Stn.AG1L140412 TestAmerica West Sacramento (916) 373 - 5600 17 of 100 

### ..... ata file Smp Work Order

20DE119D5 1 CP1220 20DE119D5 2 ST1220 20DE119D5 3 ST1220A 20DE119D5 4 ST1220B 20DE119D5 5 ST1220C 20DE119D5 6 ST1220D 20DE119D5 7 ST1220E 20DE119D5 8 

### 20DE119D5 9 20DE119D5 10 20DE119D5 11**·~** '• L**~** 

### Sample ID

DB-5 CPSM 3732-16 CS-3 11DXN221 CS-2 11DXN220 CS-1 11DXN219 CS-5 11DXN223 CS-4 11DXN222 2nd Source 11DXN210

MG 12/20/11 FV-uL Method/Matrix Box Size U

1.00000 1.00000 1.00000 1.00000 1. 

### 00000 1. 

### 00000 1.00000 1.00000 1.00000 1.00000 1.00000

# ~~~\L**c~e-cke_~ \~-**  ,l...o -\.\ 

## Sm.AG1L140412 TestAmerica West Sacramento (916) 373 - 5600 18 of 100PPM200292.98245PPM200342.97925PPM200392.97604PeakLocateExamination:20-DEC-2011:08:05File:20DE119D5Experiment:DIOXINRESFunction:1Reference:PFKVoltsPPMVoltsPPMVoltsPPM1.7145200.......0.31872000.1534200w1\#\\Jv\304.98245318.97925VoltsPPMVoltsPPMVoltsPPM0.84952000.2971'2000.1839200354.97925366.97925VoltsPPMVoltsPPMVolts0.3754200+-+0.28752000.1465rv4l\II\404.97604416.97604Volts+-+0.7217!'\,.r11f\330.97925Volts0.3945380.97604G1L140412 TestAmerica West Sacramento (916) 373 - 5600 19 of 100PeakLocateExamination:20-DEC-2011:08:06File:20DE119D5Experiment:DIOXINRESFunction:2Reference:PFK2000.1437318.94735318.97925319.01115!PPMVolts12000.3014II354.94375354.97925355.01475PPMVolts2000.4294PPMVolts200.......0.6886.IMr\I_j330_._94615PPM200-330.9792_5__331._0_1235.Volts0.1906366.94255366.97925367.01595PPMVolts2000.3234PPM200_342.94495PPM200380.93795PPM200342.97925380.97604Volts0.8131343.01355Volts0.51233J3.1.01414Volts0.1349392.93675392.97604393.01534404.93555404,97604405.01654416.93435416.97604417.01774G1L140412 TestAmerica West Sacramento (916) 373 - 5600 20 of 100PeakLocateExamination:20-DEC-2011:08:08File:20DE119D5Experiment:DIOXINRESFunction:3Reference:PFKPPMVolts2000.18873_67._Q_1595PPMVolts2000.3378404.93555404.97604405.01654PPMVolts200-0.3092AI'lAAI'\J'442_.__92854442.97284443.01714PPMVolts2000.47623a_o.9_37 9 5__J_60.9_1_60_1_381PPMVolts200,__....0.1615416.93435416.976044_l7.01_'774PPMVolts2000.2974454.92734454.97284455.01834PPM200392.93675PPM200392.97604L__l_l.I_I__\Volts0.5079393.01534Volts0.30921'_I___430.92974430.97284431.01594G1L140412 TestAmerica West Sacramento (916) 373 - 5600 21 of 100PPM200380.93795PPM200416.93435PPM200PeakLocateExarnination:20-DEC-2011:08:09File:20DE119D5Experirnent:DIOXINRESFunction:4Reference:PFKVoltsIPPMVoltsPPM0.51932000.4537200380.97604381.01414_392.93675:392.97604393.01534404.93555404.97604Volts0.1651IPPMVolts2000.2726PPM200I!416.97604417.01774II(I92·;J4430.97284I442.97284VoltsPPMVoltsPPM,.._.0.32482000.1230200.t\.fi'IJIL.\J'454.92734454.97284455.01834466.92614466.97284467.019541480.92157480.96967Volts0.34?0'405.01654Volts0.3667Volts0.1647481.01776G1L140412 TestAmerica West Sacramento (916) 373 - 5600 22 of 100PPM200430.92974PPM200466.92614PPM200504.91917PeakLocateExamination:20-DEC-2011:08:10File:20DE119D5Experiment:DIOXINRESFunction:5Reference:PFKVoltsPPMVoltsPPM0.3061200-0.3427200.fI''\A-IIl'\rI\IVolts0.3129I\,430.97284431.01594442.92854442.97284443.01714454.92734454.97284455.01834Volts0.1477466.97284467.01954Volts0.2549504.96967505.02016PPM200VoltsIIPPM0.1630200Volts0.2197480.92157480.96967481.0177611492.92037492.96967 493.01896PPMVolts2000.1535_5J.6.91797516.96967517.02136G1L140412 TestAmerica West Sacramento (916) 373 - 5600 23 of 100PPM200PPM200I-PPM200......I\I)\PeakLocateExamination:20-DEC-2011:13:26File:ENDRES20DE119D5Experirnent:DIOXINRESFunction:1Reference:PFKVoltsPPMVoltsPPMVoltsPPM1.5250200......0.36092000.1327200)\292304VoltsPPM0.8299200......{flJA.\II\342.97925354.97925-------.-·--VoltsPPM0.3747200392.97604404.97604Volts0.3074Volts0.2939PPM200PPM2003].8__J)79_25366.97925416.97604Volts0.2177Volts0.1522330.97925PPM200_____380.97604Volts0.7492Volts0.4102G1L140412 TestAmerica West Sacramento (916) 373 - 5600 24 of 100PPM200318.94735PPM200354.94375PPM200392.93675PeakLocateExamination:20-DEC-2011:13:26File:ENDRES20DE119D5Experiment:DIOXINRESFunction:2Reference:PFKVoltsPPMVoltsPPMVolts0.1104200-0.6849200-0.7637,,(\r\1\Ar\J\I\J)\..318.97925319.01115330.94615330.97925331.01235342.94495342.97925 343.01355VoltsPPMVoltsPPMVolts0.3095200-0.2072200-0.4924,1\,\fi\tlAf"\J\..Ij354.97925355.01475366.94255366.97925367.01595 380.93795380.97604381.01414VoltsPPMVoltsPPMVolts0.38832000.32692000.1378392.97604393.01534404.93555404.97604416.97604417.01774G1L140412 TestAmerica West Sacramento (916) 373 - 5600 25 of 100PPM200_366.94255PPM200404.93555PPM200442.92854PeakLocateExamination:20-DEC-2011:13:27File:ENDRES20DE119D5Experiment:DIOXINRESFunction:3Reference:PFKVolts0.1940PPMVolts2000.4427IPPM200-.I{TVolts0.4590II366.97925367.01595_Volts0.3400404._97604405.016_54Volts0.3002442.97284443.01714i1380.9379536_0.97604PPM200381.014:1..4Volts0.1654416.93435416.97604417.01774PPMVolts2000.2887454.92734454.97284455.01834I,II.A.392.97604393.01534IPPMVolts0.3100200IIIIIIII.92974430.97284431.01594G1L140412 TestAmerica West Sacramento (916) 373 - 5600 26 of 100IPPM200PeakLocateExamination:20-DEC-2011:13:27File:ENDRES20DE119D5Experiment:DIOXINRESFunction:4Reference:PFKVoltsPPMVoltsPPM,.._.0.46922000.4130200-,;v\MI)\.IJVolts0.3252J,)380.93795PPM200380.97604381.01414Volts0.1649416.93435416.97604417.01774PPMVolts2000.3197454.92734454.97284455.01834392.93675392.97604393.01534PPMVolts2000.2667430---430.97284431.01594PPMVolts200,.._.0.1348,,1tl./'466.92614466.97284467.01954404.93555404.97604405.01654PPMVolts200,.._.0.3538lrrI\.J442.92854442.97284443.01714PPMVolts200-0.1727480.92152481.Q:1._776G1L140412 TestAmerica West Sacramento (916) 373 - 5600 27 of 100PPM200!430.92974PPM200PeakLocateExamination:20-DEC-2011:13:28File:ENDRES20DE119D5Experirnent:DIOXINRESFunction:SReference:PFK430.97284Volts0.2863431.01594Volts0.1497PPMVolts200-0.3036rr.f\f\J442.92854442.97284 443.01714PPMVolts2000.1569PPM200-i\J\r1\454.92734454.97284PPM200466.92614466.97284 467.01954480.92157480.96967 481.01776492.92037 492.96967PPMVoltsPPMVolts2000.26102000.1467i504.91917504.96967.5.0_5_.02016516.91797516.96967517.02136Volts0.2964455.01834Volts0.2128493..J)_:l._89 6G1L140412 TestAmerica West Sacramento (916) 373 - 5600 28 of 100Page1of1Run:20DE119D5Analyte:1613Cal:1613122011905ST1220B:CS-111DXN219ST1220A:CS-211DXN220ST1220:CS-311DXN221ST1220D:CS-411DXN222ST1220C:CS-511DXN22320DE119DS20DE119D520DE119D520DE119DS20DE119D5S4S3S2S6ssNameMeanS.D.%'RSDRRF1 RRF2RRF3 RRF4RRF513C-1,2,3,4-TCDD- --%'13C-2,3,7,8-TCDF1.3420.0302.27%'1.3S1.381.361.311.312,3,7,8-TCDF0.846o.osoS.86%'0.840.920.860.800.81TotalTCDF0.846o.osoS.86%'0.840.920.860.800.8113C-2,3,7,8-TCDD0.9060.0131.41%'0.910.920.910.900.892,3,7,8-TCDD1.072O.OS14.80%'1.101.141.061.011.OSTotalTCDD1.072O.OS14.80%'1.101.141.061.011.OS37Cl-2,3,7,8-TCDD1.143O.OS24.57%'1.081.221.1S1.111.1413C-1,2,3,7,8-PeCDF0.9670.0272.83%'0.970.980.960.931.001,2,3,7,8-PeCDF1.1940.063S.31%1.2S1.261.181.121.1413C-2,3,4,7,8-PeCDF0.9SS0.04S4.69%'1.010.940.920.911.002,3,4,7,8-PeCDF1.1730.0816.90%1.211.301.1S1.101.11TotalF2PeCDF1.1830.071S.98%'1.231.281.171.111.13TotalF1PeCDF1.1830.071S.98%'1.231.281.171.11 1.1313C-1,2,3,7,8-PeCDD0.6380.0223.49%'0.630.630.610.640.671,2,3,7,8-PeCDD1.003O.OS7S.71%'1.061.060.980.940.97TotalPeCDD1.003O.OS7s.71%1.061.060.980.940.9713C-1,2,3,7,8,9-HxCDD- --%'13C-1,2,3,4,7,8-HxCDF0.9440.0131.38%0.940.960.920.960.941,2,3,4,7,8-HxCDF1.3730.0926.68%1.431.471.421.281.2713C-1,2,3,6,7,8-HxCDF1.2430.0846.76%1.271.2S1.3S1.221.121,2,3,6,7,8-HxCDF1.2800.0866.68%'1.351.401.231.211.2213C-2,3,4,6,7,8-HxCDF1.1180.0413.67%1.131.15 1.161.091.062,3,4,6,7,8-HxCDF1.2800.0816.36%1.371.361.261.211.2013C-1,2,3,7,8,9-HxCDF0.9590.049S.09%'0.961.001.010.930.891,2,3,7,8,9-HxCDF1.2600.0473.77%'1.331.261.271.21 1.23G1L140412 TestAmerica West Sacramento (916) 373 - 5600 29 of 100TotalHxCDF1.2950.0715.52%1.371.371.281.22 1.23I13C-1,2,3,4,7,8-HxCDD0.6570.0355.29%0.660.620.630.710.671,2,3,4,7,8-HxCDD1.1930.0927.70%1.271.311.16 1.121.1113C-1,2,3,6,7,8-HxCDD0.8420.0313.64%0.820.870.880.810.831,2,3,6,7,8-HxCDD1.1790.13011.0%1.341.301.121.071.061,2,3,7,8,9-HxCDD1.3940.16111.6%1.591.521.391.251.22TotalHxCDD1.2550.12710.2%1.401.381.22 1.14 1.1313C-1,2,3,4,6,7,8-HpCDF0.9350.0151.62%0.940.940.940.950.911,2,3,4,6,7,8-HpCDF1.5000.1177.79%1.611.621.491.39 1.3813C-1,2,3,4,7,8,9-HpCDF0.7870.0182.27%0.800.760.780.810.791,2,3,4,7,8,9-HpCDF1.4040.1067.54%1.511.53 1.381.311.31TotalHpCDF1.4560.1127.69%1.571.58 1.441.351.3513C-1,2,3,4,6,7,8-HpCDD0.8040.0192.32%0.810.810.800.820.771,2,3,4,6,7,8-HpCDD1.0360.0434.19%1.071.091.020.991.01TotalHpCDD1.0360.0434.19%1.071.091.020.991.0113C-OCDD0.6740.0162.32%0.680.660.660.680.69OCDF1.4000.0886.31%1.47 1.491.421.321.30OCDD1.1400.0786.85%1.201.23 1.141.081.OSG1L140412 TestAmerica West Sacramento (916) 373 - 5600 30 of 100 I: 1 

### Run #1 Filename 20DE119D5 S: 4 Acquired: 20-DEC-11 10:28:35 Run: 20DE119D5 Analyte: 1613 Processed: 20-DEC-11 12:36:20 Cal: 1613122011905 Comments: Sample text: ST1220B :CS-1 11DXN219

Name

13C-1,2,3,4-TCDD

13C-2,3,7,8-TCDF 2,3,7,8-TCDF Total TCDF

13C-2,3,7,8-TCDD 2,3,7,8-TCDD Total TCDD

37Cl-2,3,7,8-TCDD

13C-1,2,3,7,8-PeCDF 1,2,3,7,8-PeCDF 13C-2,3,4,7,8-PeCDF 2,3,4,7,8-PeCDF

Total F2 PeCDF Total F1 PeCDF

13C-1,2,3,7,8-PeCDD 1,2,3,7,8-PeCDD Total PeCDD

13C-1,2,3,7,8,9-HxCDD

13C-1,2,3,4,7,8-HxCDF 1,2,3,4,7,8-HxCDF 13C-1,2,3,6,7,8-HxCDF 1,2,3,6,7,8-HxCDF 13C-2,3,4,6,7,8-HxCDF 2,3,4,6,7,8-HxCDF 13C-1,2,3,7,8,9-HxCDF 1,2,3,7,8,9-HxCDF Total HxCDF

13C-1,2,3,4,7,8-HxCDD 1,2,3,4,7,8-HxCDD 13C-1,2,3,6,7,8-HxCDD 1,2,3,6,7,8-HxCDD 1,2,3,7,8,9-HxCDD Total HxCDD

13C-1,2,3,4,6,7,8-HpCDF 1,2,3,4,6,7,8-HpCDF 13C-1,2,3,4,7,8,9-HpCDF 1,2,3,4,7,8,9-HpCDF Total HpCDF Resp 

### RA RT

217541500 0.78 y 

### 19:04

293447000 0.79 ,y 

### 1234621 0.77 y
- n



### 197322900 0.78 y 

### 1086958 0.75 y

- n



### 1180110 1. 00 y 18:29 18:30

19:17 19:18

19:19

209998000 1.52 y 

### 24:09 6584610 1.54 y 24:11 218634100 1.54 y 

### 25:39 6599610 1.50 y 25:41

- n

- n



### 136524400 1.41 y 26:29 3618840 1.55 y 26:30

- n



### 164571200 1.34 y 32:46

155136800 0.50 y 

### 31:36 5529490 1.21 y 31:37 209106700 0.51 y 

### 31:43 7037090 1.23 y 

### 31:45 186202000 0.50 y 

### 32:17 6386480 1.23 y 32:18 158624900 0.50 y 

### 32:56 5289990 1.26 y 32:57

- n



### 108426200 1.33 y 

### 32:26 3445670 1.13 y 32:26 135169100 1.34 

### y 32:31 4515480 1.16 y 

### 32:31 4829470 1.19 y 

### 32:47

- n



### 154050500 0.45 y 

### 34:13 6218710 1.02 y 34:14 131561800 0.45 y 35:18 4956400 1.05 y 

### 35:19

- n 

### RRF

1. 3489 0.8415 0.8415

0.9071 1.1017 1.1017

1. 0850

0.9653 1.2542 1. 0050 1.2074 1.2304 1.2304

0.6276 1.0603 1.0603

0.9427 1.4257 1.2706 1.3461 1.1314 1.3719 0.9639 1.3340 1.3676

0.6588 1.2712 0.8213 1.3362 1. 5861 1.4002

0.9361 1.6147 0.7994 1.5069 1. 5651 100.00

100.00 0.50 0.50

100.00 0.50 0.50

0.50

100.00 2.50 100.00 2.50 2.50 5.00

100.00 2.50 2.50

100.00 Mod?

n

n
n
n

n
n
n

n

n
n

n


### n

n


### n

n
n
n



### n



### 100.00 n 2.50 n 100.00 n 2.50 n 100.00 n 2.50 n 100.00 n 2.50 n 10.00 n

100.00 n 2.50 n 100.00 n 2.50 n 2.50 n 7.50 n

100.00 n 2.50 n 

### 100.00 n 2.50 n 5.00 n Page 1 oG1L140412 TestAmerica West Sacramento (916) 373 - 5600 31 of 100 

### 13C-1,2,3,4,6,7,8-HpCDD 133442900 1.02 

### y 35:00 0.8109 100.00 n 

### 1,2,3,4,6,7,8-HpCDD 3582440 1.02 

### y 35:01 1. 0738 2.50 n 

### Total HpCDD - n 

### 1. 0738 2.50 n



### 13C-OCDD 224374000 0.86 

### y 37:25 0.6817 200.00 n 

### OCDF 8260070 0.90 

### y 37:32 1.4726 5.00 n 

### OCDD 6731210 0.93 

### y 37:25 1.2000 5.00 nG1L140412 TestAmerica West Sacramento (916) 373 - 5600 32 of 100 I: 1 

### Run #2 Filename 20DE119D5 S: 3 Acquired: 20-DEC-11 09:45:45 Run: 20DE119D5 Analyte: 1613 Processed: 20-DEC-11 12:36:22 Cal: 1613122011905 Comments: Sample text: ST1220A :CS-2 11DXN220

Name

13C-1,2,3,4-TCDD

13C-2,3,7,8-TCDF 2,3,7,8-TCDF Total TCDF

13C-2,3,7,8-TCDD 2,3,7,8-TCDD Total TCDD

37Cl-2,3,7,8-TCDD

13C-1,2,3,7,8-PeCDF 1,2,3,7,8-PeCDF 13C-2,3,4,7,8-PeCDF 2,3,4,7,8-PeCDF

Total F2 PeCDF Total F1 PeCDF

13C-1,2,3,7,8-PeCDD 1,2,3,7,8-PeCDD Total PeCDD

13C-1,2,3,7,8,9-HxCDD

13C-1,2,3,4,7,8-HxCDF 1,2,3,4,7,8-HxCDF 13C-1,2,3,6,7,8-HxCDF 1,2,3,6,7,8-HxCDF 13C-2,3,4,6,7,8-HxCDF 2,3,4,6,7,8-HxCDF 13C-1,2,3,7,8,9-HxCDF 1,2,3,7,8,9-HxCDF Total HxCDF

13C-1,2,3,4,7,8-HxCDD 1,2,3,4,7,8-HxCDD 13C-1,2,3,6,7,8-HxCDD 1,2,3,6,7,8-HxCDD 1,2,3,7,8,9-HxCDD Total HxCDD

13C-1,2,3,4,6,7,8-HpCDF 1,2,3,4,6,7,8-HpCDF 13C-1,2,3,4,7,8,9-HpCDF 1,2,3,4,7,8,9-HpCDF Total HpCDF

13C-1,2,3,4,6,7,8-HpCDD 1,2,3,4,6,7,8-HpCDD Resp RA 

### RT

210331700 0.77 y 19:04

290377000 0.79 y 18:29 5351970 0.78 y 18:30

- n



### 194505700 0.76 y 19:16 4445750 0.81 y 19:18

- n



### 5152320 1.00 y 19:18

206697800 1.52 y 24:09

26114100 1.47 y 24:10 198354500 1.50 y 25:39

25725300 1.50 y 25:41

- n

- n



### 133416500 1.39 y 26:28

14204160 1.52 y 26:30



### - n

155059500 1.32 y 32:46

148122300 0.51 y

21784140 1.25 y 193928600 0.51 y

27074900 1.25 y 177730600 0.51 y

24161200 1.25 y 154927800 0.50 y

19522620 1. 26 y
- n



### 95714900 1. 34 y 12527720 1.13 y 135079200 1.35 y

17555530 1.17 y 17566990 1. 

### 26 y



### - n

145495000 0.44 y

23600700 1. 

### 03 y 117821000 0.45 y

17969920 1. 

### 02 y


### - n

126041600 1.01 y

13721690 1. 02 y 31:36 31:36 31:43 31:44 32:16 32:17 32:56 32:56

32:25 32:26 32:30 32:31 32:46

34:13 34:13 35:18 35:18

35:00 35:00 

### RRF

1.3806

- 0.9216 0.9216

0.9248 1.1428 1.1428

1.2248

0.9827 1. 2634**0.9~31** 

### 1.2969 1.2798 1.2798

0.6343 1. 0646 1. 0646

0.9553 1.4707 1.2507 1.3961 1.1462 1. 3594 0.9992 1.2601 1.3716

0.6173 1. 3089 0.8711 1.2996 1. 5223 1.3764

0.9383 1.6221 0.7598 1.5252 1. 5787

0.8129 1. 

### 0887 100.00

100.00 2.00 2.00

100.00 2.00 2.00

2.00

100.00

10.00 100.00

10.00 10.00 20.00

100.00

10.00 10.00

100.00

100.00

10.00 100.00

10.00 100.00

10.00 100.00

10.00 40.00

100.00

10.00 100.00

10.00 10.00 30.00

100.00

10.00 100.00

10.00 20.00

100.00

10.00 Mod?

n



### n
n
n



### n
n
n

n



### n

n


### n


### n
n
n

n
n
n

n

n
n
n
n
n


### n
n
n
n

n
n
n
n


### n
n



### n

n
n
n
n

n
n 

### Page 2 oG1L140412 TestAmerica West Sacramento (916) 373 - 5600 33 of 100 

### Total HpCDD

13C-OCDD OCDF OCDD - n



### 203359100 0.85 

### y 37:24

30361400 0.95 

### y 37:31 25065800 0.90 

### y 37:24 1. 0887

0.6557 1.4930 1.2326 10.00

200.00

20.00 20.00 n

n
n
nG1L140412 TestAmerica West Sacramento (916) 373 - 5600 34 of 100 I: 1 

### Run #3 Filename 20DE119D5 S: 2 Acquired: 20-DEC-11 08:55:32 Run: 20DE119D5 Analyte: 1613 Processed: 20-DEC-11 12:36:24 Cal: 1613122011905 Comments: Sample text: ST1220 :CS-3 11DXN221

Name

13C-1,2,3,4-TCDD

13C-2,3,7,8-TCDF 2,3,7,8-TCDF Total TCDF

13C-2,3,7,8-TCDD 2,3,7,8-TCDD Total TCDD

37Cl-2,3,7,8-TCDD

13C-1,2,3,7,8-PeCDF 1,2,3,7,8-PeCDF 13C-2,3,4,7,8-PeCDF 2,3,4,7,8-PeCDF

Total F2 PeCDF Total F1 PeCDF

13C-1,2,3,7,8-PeCDD 1,2,3,7,8-PeCDD Total PeCDD

13C-1,2,3,7,8,9-HxCDD

13C-1,2,3,4,7,8-HxCDF 1,2,3,4,7,8-HxCDF 13C-1,2,3,6,7,8-HxCDF 1,2,3,6,7,8-HxCDF 13C-2,3,4,6,7,8-HxCDF 2,3,4,6,7,8-HxCDF 13C-1,2,3,7,8,9-HxCDF 1,2,3,7,8,9-HxCDF Total HxCDF

13C-1,2,3,4,7,8-HxCDD 1,2,3,4,7,8-HxCDD 13C-1,2,3,6,7,8-HxCDD 1,2,3,6,7,8-HxCDD 1,2,3,7,8,9-HxCDD Total HxCDD

13C-1,2,3,4,6,7,8-HpCDF 1,2,3,4,6,7,8-HpCDF 13C-1,2,3,4,7,8,9-HpCDF 1,2,3,4,7,8,9-HpCDF Total HpCDF

13C-1,2,3,4,6,7,8-HpCDD 1,2,3,4,6,7,8-HpCDD Resp 

### RA RT

187978100 0.77 

### y 19:04

255266000 0.80 

### y 18:30

22046860 0.79 

### y 18:31

- n



### 171011900 0.77 

### y 19:17

18061060 0.81 

### y 19:18

- n



### 21608000 1.00 

### y 19:18

180334900 1.55 

### y 24:09 106674000 1.55 

### y 24:11 173479400 1.51 

### y 25:40

99822800 1.51 

### y 25:41

- n
- n



### 115270000 1.40 

### y 26:29

56719300 1.51 

### y 26:31

- n



### 128134900 1.38 

### y 32:46

118332500 0.50 

### y 31:36

83968200 1.24 

### y 31:37 173493400 0.51 

### y 31:44 106453500 1.26 

### y 31:45 148509100 0.51 

### y 32:17

93226500 1.26 

### y 32:18 129225000 0.50 

### y 32:56

81843300 1.23 

### y 32:57

- n



### 80834600 1.33 

### y 32:26 46930200 1.12 

### y 32:26 112391000 1.33 

### y 32:31

63176500 1.17 

### y 32:31 67220100 1.15 

### y 32:47



## - n

120986400 0.45 

### y 34:13

90357500 1.04 

### y 34:14 100092600 0.45 

### y 35:19

68830600 1.03 

### y 35:19

- n



### 102970800 1.00 

### y 35:01

52559900 1.05 y 

### 35:01 RRF

1.3580 0.8637 0.8637

0.9097 1. 0561 1. 0561

1.1495

0.9593 1.1831 0. 

### 9229 1.1508 1.1673 1.1673

0.6132 0.9841 0. 9841

0.9235 1.4192 1.3540 1.2272 1.1590 1.2555 1. 0085 1.2667 1.2834

0.6309 1.1611 0.8771 1.1242 1. 3915 1.2236

0.9442 1.4937 0.7812 1.3753 1.4401

0.8036 1. 

### 0209 100.00

100.00

10.00 10.00

100.00

10.00 10.00

10.00

100.00

50.00 100.00

50.00 50.00 100.00

100.00

50.00 50.00

100.00

100.00

50.00 100.00

50.00 100.00

50.00 100.00

50.00 200.00

100.00

50.00 100.00

50.00 50.00 150.00

100.00

50.00 100.00

50.00 100.00

100.00

50.00 Mod?

n



### n
n
n

n
n
n

n

n
n
n


### n
n

n

n


### n
n

n

n
n
n
n
n
n
n
n
n

n


### n
n
n
n
n

n
n
n
n
n

n
n 

### Page 3 oG1L140412 TestAmerica West Sacramento (916) 373 - 5600 35 of 100 

### Total HpCDD

13C-OCDD OCDF OCDD - n



### 169190200 0.85 

### y 37:25 120040000 0.92 

### y 37:32

96724900 0.90 

### y 37:26 1. 0209

0.6602 1.4190 1.1434 50.00

200.00 100.00 100.00 n

n


### n
nG1L140412 TestAmerica West Sacramento (916) 373 - 5600 36 of 100 I: 1 

### Run #4 Filename 20DE119D5 S: 6 Acquired: 20-DEC-11 11:54:30 Run: 20DE119D5 Analyte: 1613 Processed: 20-DEC-11 12:36:25 Cal: 1613122011905 Comments: Sample text: ST1220D :CS-4 11DXN222

Name

13C-1 1 2 1 3 1 4-TCDD

13C-2 1 3 1 7 1 8-TCDF 2 1 3 1 7 1 8-TCDF Total TCDF

13C-2 1 3 1 7 1 8-TCDD 213 1 7 1 8-TCDD Total TCDD

37Cl-2 1 3 1 7 1 8-TCDD

13C-1121317 1 8-PeCDF 1 I 

### 2 1 

### 3 I 

### 7 I 

### 8- PeCDF

.**13C-2 314** **7~8-PeCDF** 

### 213141718-PeCDF

Total F2 PeCDF Total F1 PeCDF**13C-1 7~8-PeCDD**  

### 112131718-PeCDD Total PeCDD

13C-1 1 2 1 317,8,9-HxCDD

13C-1,2,3,4,7,8-HxCDF 1,2 1 3,4,7,8-HxCDF 13C-1,2 1 316,7,8-HxCDF 1 1 2 1 3,6,7 1 8-HxCDF 13C-2,3,4,6,7 1 8-HxCDF 2 1 3,4 1 6 1 7 1 8-HxCDF 13C-1,2 1 3,7,8,9-HxCDF 1,2 1 3 1 7,8,9-HxCDF Total HxCDF

13C-1,2 1 3 1 4,7 1 8-HxCDD 1 1 2,3,4,7 1 8-HxCDD 13C-1,2,3,6,7,8-HxCDD 1,2,3 1 6,7 1 8-HxCDD 1 1 2 1 3 1 7,8 1 9-HxCDD Total HxCDD

13C-1,2,3 1 4 1 6 1 7,8-HpCDF 1 1 2,3 1 416,7,8-HpCDF 13C-1,2,3,4,7,8,9-HpCDF 1,2,3 1 4 1 7,8,9-HpCDF Total HpCDF

13C-1,2 1 3,4,6,7,8-HpCDD 1,2,3,4,6,7,8-HpCDD Resp 

### RA RT

229552000 0.77 

### y 19:04

301446000 0.79 

### y 18:30

96064100 0.80 

### y 18:31

- n



### 205666300 0.77 

### y 19:17

83047700 0.78 

### y 19:18

- n



### 102358800 1.00 

### y 19:18

212709700 1.51 y 24:09 478099000 1.52 

### y 24:11 207812400 1.51 

### y 25:39 458408000 1.51 

### y 25:41

- n

- n



### 146882400 1.41 

### y 26:28 275118000 1.53 

### y 26:30



### - n

155801600 1.33 

### y 32:46

148861100 0.51 

### y 31:36 380658000 1.23 y 31:37 189863100 0.52 

### y 31:43 458373000 1.25 

### y 31:45 170071300 0.50 

### y 32:17 410741000 1.23 

### y 32:18 144991000 0.52 

### y 32:56 350160000 1.24 

### y 32:56

- n



### 110003400 1.32 y 32:26 245506000 1.13 

### y 32:26 125851300 1.31 y 32:31 269655000 1.16 y 32:31 294525000 1.15 

### y 32:47

- n



### 147488600 0.46 

### y 34:13 408865000 1.03 

### y 34:14 125520400 0.46 

### y 35:18 328581000 1.03 

### y 35:19

- n



### 127901600 1.00 

### y 35:00 252793000 1.06 

### y 35:01 RRF

1.3132 0.7967 0.7967

0.8959 1.0095 1. 0095

1.1148

0. 

### 9266 1.1238 0.9053 1.1029 1.1135 1.1135

0.6399 0.9365 0.9365

0.9555 1.2786 1.2186 1.2071 1.0916 1.2076 0.9306 1.2075 1.2236

0.7060 1.1159 0.8078 1.0713 1.2488 1.1443

0.9466 1. 

### 3861 0.8056 1. 3089 1. 3506

0.8209 0.9882 100.00

100.00

40.00 40.00

100.00

40.00 40.00

40.00

100.00 200.00 100.00 200.00 200.00 400.00

100.00 200.00 200.00

100.00 Mod?

n

n


### n
n

n
n
n

n



### n
n
n
n
n
n

n
n
n

n



### 100.00 n 200.00 n 100.00 n 200.00 n 100.00 n 200.00 n 100.00 n 200.00 n 800.00 n

100.00 200.00 100.00 200.00 200.00 600.00

100.00 200.00 100.00 200.00 400.00

100.00 200.00 n
n
n
n
n


### n

n
n
n
n
n

n
n 

### Page 4 oG1L140412 TestAmerica West Sacramento (916) 373 - 5600 37 of 100 

### Total HpCDD

13C-OCDD OCDF OCDD - n

211792900 0.87 

### y 37:25 557721000 0.92 y 37:32 455634000 0.89 

### y 37:25 0.9882

0.6797 1. 

### 3167 1. 

### 0757 200.00

200.00 400.00 400.00 n



### n
n
nG1L140412 TestAmerica West Sacramento (916) 373 - 5600 38 of 100 I: 1 

### Run #5 Filename 20DE119DS S: 5 Acquired: 20-DEC-11 11:11:39 Run: 20DE119DS Analyte: 1613 Processed: 20-DEC-11 12:36:27 Cal: 1613122011905 Comments: Sample text: ST1220C :CS-5 11DXN223

Name

13C-1,2,3,4-TCDD

13C-2,3,7,8-TCDF 2,3,7,8-TCDF Total TCDF

13C-2,3,7,8-TCDD 2,3,7,8-TCDD Total TCDD

37Cl-2,3,7,8-TCDD

13C-1,2,3,7,8-PeCDF 1,2,3,7,8-PeCDF 13C-2,3,4,7,8-PeCDF 2,3,4,7,8-PeCDF

Total F2 PeCDF Total Fl PeCDF

13C-1,2,3,7,8-PeCDD 1,2,3,7,8-PeCDD Total PeCDD

13C-1,2,3,7,8,9-HxCDD

13C-1,2,3,4,7,8-HxCDF 1,2,3,4,7,8-HxCDF 13C-1,2,3,6,7,8-HxCDF 1,2,3,6,7,8-HxCDF 13C-2,3,4,6,7,8-HxCDF 2,3,4,6,7,8-HxCDF 13C-1,2,3,7,8,9-HxCDF 1,2,3,7,8,9-HxCDF Total HxCDF

13C-1,2,3,4,7,8-HxCDD 1,2,3,4,7,8-HxCDD 13C-1,2,3,6,7,8-HxCDD 1,2,3,6,7,8-HxCDD 1,2,3,7,8,9-HxCDD Total HxCDD

13C-1,2,3,4,6,7,8-HpCDF 1,2,3,4,6,7,8-HpCDF 13C-1,2,3,4,7,8,9-HpCDF 1,2,3,4,7,8,9-HpCDF Total HpCDF

13C-1,2,3,4,6,7,8-HpCDD 1,2,3,4,6,7,8-HpCDD Resp RA RT

231600000 0.78 y 19:05

303183000 0.79 y 18:30 490514000 0.81 y 18:31

- n



### 206644200 0.77 y 19:17 433390000 0.80 

### y 19:18

- n



### 528682000 1.00 y 19:18

231464800 1.53 y 

### 24:09 2645650000 1.52 y 24:11

231209400 1.53 

### y 25:40 2561100000 1.52 y 25:41



### - n
- n



### 155939000 1.41 

### y 26:29 1508996000 1.52 y 26:31

- n



### 185109500 1.36 y 32:47

174836800 0.51 y 2222985000 1.24 y



### 207775600 0.51 y 2540040000 1.25 

### y

196223600 0.52 y 2360780000 1.24 

### y

164918500 0. 51 y 

### 2033128000 1.25 

### y
- n



### 123963200 1.33 

## y 1373192000 1.15 

### y

154242600 1.34 

### y 1637105000 1.17 

### y 1699926000 1.15 

### y
- n



### 168251000 0.47 y 2328290000 1.03 

### y

145650400 0.47 

### y 1901243000 1.04 y
- n



### 143026800 1.01 y 1440443000 1.05 y 

### 31:37 31:37 31:44 31:45 32:17 32:18 32:57 32:57

32:26 32:27 32:31 32:32 32:47

34:14 34:14 35:19 35:19

35:01 35:02 RRF

1.3091 0.8089 0.8089

0.8922 1. 0486 1. 0486

1.1414

0.9994 1.1430 0.9983 1.1077 1.1254 1.1254

0.6733 0.9677 0.9677

0.9445 1.2715 1.1224 1.2225 1. 0600 1.2031 0.8909 1.2328 1.2312

0.6697 1.1077 0.8333 1. 0614 1.2221 1.1287

0.9089 1. 3838 0.7868 1. 3053 1.3474

0. 

### 7727 1. 0071 Mod?

100.00 n



### 100.00 n 200.00 n 200.00 n

100.00 n 200.00 n 200.00 n

200.00 n

100.00 n 1000.00 n

100.00 n 1000.00 n 1000.00 n 2000.00 n

100.00 n 1000.00 n 1000.00 n

100.00

100.00 1000.00

100.00 1000.00

100.00 1000.00

100.00 1000.00 4000.00

100.00 1000.00

100.00 1000.00 1000.00 3000.00

100.00 1000.00

100.00 1000.00 2000.00

100.00 1000.00 n



### n

n


### n
n

n


### n
n
n


### n

n


### n

n


### n
n
n

n
n
n
n
n

n
n 

### Page 

## s oG1L140412 TestAmerica West Sacramento (916) 373 - 5600 39 of 100 

### Total HpCDD

13C-OCDD OCDF OCDD - n

256618000 0.88 

### y 37:25 3336020000 0.92 

### y 37:32 2694530000 0.89 

### y 37:26 1. 

### 0071

0.6932 1. 

### 3000 1.0500 1000.00

200.00 2000.00 2000.00 n

n


### n
nG1L140412 TestAmerica West Sacramento (916) 373 - 5600 40 of 100File:20DE119D5#1-530Acq:20-DEC-201108:12:41GCSample#1Text:CP1220:DB-5CPSM3732-16319.8965BSUB(1000,15,-3.0)100959085807570656055so4540353025201510IEI+VoltageSIRAutospec-UltimaEExp:DIOXINRES4.3E64.0E63.8E63.6E63.4E63.2E63.0E62.8E62.6E62.3E62.1E61.9B61.7E61.5E61.3E61.1B68.5B56.4B54.3BS2.1BS0O.OEO19:0619:12 19:1819:2419:30TimeG1L140412 TestAmerica West Sacramento (916) 373 - 5600 41 of 100 

### Quantitation Summary TestAmerica West Sacramento

Run text: ST1220E Sample text: ST1220E :2nd Source 11DXN210 Run #6 Filename: 20DE119D5 S: 7 I: 1 Results: 20DE119D51613 Acquired: 20-DEC-11 12:37:30 Processed: 20-DEC-11 13:18:16 Run: 20DE119D5 Analyte: 1613 Cal: 1613122011905

Factor 1:800.000 Factor 2:20.000 Sample size: 1.000

Name Resp RA 

### RT RRF



### 13C-1,2,3,4-TCDD 173521600 0.78 y 19:05

13C-2,3,7,8-TCDF 2,3,7,8-TCDF Total TCDF

13C-2,3,7,8-TCDD 2,3,7,8-TCDD Total TCDD

37Cl-2,3,7,8-TCDD

13C-1,2,3,7,8-PeCDF 1,2,3,7,8-PeCDF 13C-2,3,4,7,8-PeCDF 2,3,4,7,8-PeCDF

Total F2 PeCDF Total F1 PeCDF

13C-1,2,3,7,8-PeCDD 1,2,3,7,8-PeCDD Total PeCDD 245759000 0.78 y 22905900 0.81 y 22905900 0.81 y

168970800 0.77 

### y

20460790 0.81 y 20592063 2.81 n 18:30 1.34 18:30 0.85 18:30 0.85

19:17 0.91 19:18 1.07 18:30 1.07

42439200 1.00 y 19:18 1.14

179334100 1.52 y 24:09 0.97

60410700 1.49 y 24:10 1.19 174617100 1.50 y 25:39 0.95

56997000 1.50 y 25:41 1.17 117784376 1.49 y 24:10 1.18 315017 1.90 n 19:04 1.18

117425300 1.39 y 26:29 0.64

32616000 1.53 y 26:31 1.00 32771743 2.73 n 24:09 1.00

13C-1,2,3,7,8,9-HxCDD 129488600 1.34 y 32:46

13C-1,2,3,4,7,8-HxCDF 1,2,3,4,7,8-HxCDF 13C-1,2,3,6,7,8-HxCDF 1,2,3,6,7,8-HxCDF 13C-2,3,4,6,7,8-HxCDF 2,3,4,6,7,8-HxCDF 13C-1,2,3,7,8,9-HxCDF 1,2,3,7,8,9-HxCDF Total HxCDF

13C-1,2,3,4,7,8-HxCDD 1,2,3,4,7,8-HxCDD 13C-1,2,3,6,7,8-HxCDD 1,2,3,6,7,8-HxCDD 1,2,3,7,8,9-HxCDD Total HxCDD

13C-1,2,3,4,6,7,8-HpCDF 1,2,3,4,6,7,8-HpCDF 13C-1,2,3,4,7,8,9-HpCDF 1,2,3,4,7,8,9-HpCDF Total HpCDF 126772400 0.53 y 31:36 0.94 51153000 1.23 y 31:37 1.37 159794000 0.49 y 31:43 1.24

57455700 1.24 y 31:44 1.28 139748300 0.51 y 32:17 1.12

50454000 1.19 y 32:18 1.28 128136700 0.52 y 32:56 0.96

45639500 1.25 y 32:57 1.26 204801388 1.55 n 30:27 1.30

86458900 1.31 y 32:26 0.66 28987500 1.11 y 32:26 1.19 116414600 1.32 y 32:30 0.84

36814800 1.17 y 32:31 1.18 39469700 1.15 y 32:47 1.39 106175131 2.79 n 31:37 1.25

128734600 0.45 y 34:13 0.93

55576200 1.02 y**34:1~.5D** 

### 105840300 0.46 y 35:19 0.79

41400600 1.04 y 35:19 1.40 96976800 1.02 y 34:14 1.46 Cone

80.558

2110.821

220.221 

# flo-/_

220.221

2149.729

225.966 

## 1 

# rr/.

227.416

427.925

2138.226

564.491 2107.658

556.463 1124.552 3.009 

## 11 

# :r/_

11 

# r/_

2122.519

554. o51 

# 111/_
556.697

82.092

2073.592

587.715 1985.152

561.899 1931.242

564.334 2064.566

565.265 2280.318

2033.983

562.089 2135.151

536.650 558.201 1671.132

2126.959

575.584 2078.296

557.075 1132.659 

# 11! 

# j_

lfl/. 

# Ill-/_ 

# tni

..

Ill)_**to1/~** 111./. EDL

2.466 3.631 3.631

5.334 1.865 1.865

1.355

3.147 4.372 3.186 4.799 4.582 2.973

2.629 2.825 2.825

2.203 1.499 1.673 1.417 1.861 1.436 2.170 1.647 1.494

4.379 0.962 3.414 0.858 0.767 0.852

9.302 4.477 11.055

6.458 5.340 Page 1 o

Rec 

### M

105.5

107.5

107.0

106.9

105.4

106.1

103.7

99.3

96.6

103.2

101.7

106.8

106.3

103.9 n

n

n


### n

n
n
n

n

n

n


### n


### n

n


### n

n
n
n

n

n
n


### n. n'
n


### n 

### n, 

### n' n,

n


### n
n


### n
n
n

n


### n
n
n



### nG1L140412 TestAmerica West Sacramento (916) 373 - 5600 42 of 100 

### 13C-1,2,3,4,6,7,8-HpCDD 109972900 1.00 

### y 35:00 0.80 2112.174 

# 11 

# r)_ 6.567 105.6 n 

### 1,2,3,4,6,7,8-HpCDD 31748700 1.05 

### y 35:00 1.04 557.464 1.940 n 

### Total HpCDD 32752977 3.25 n 

### 34:14 1.04 575.098 1.940 n



### 13C-OCDD 175595100 0.85 

### y 37:25 0.67 4023.360 

# \o

# ~ -}_ 4.162 100.6 n 

### OCDF 66630300 0.92 

### y 37:31 1.40 1083.969 2.333 n 

### OCDD 55419200 0.89 

### y 37:25 1.14 1107.076 

# ill'/_ 3.160 nG1L140412 TestAmerica West Sacramento (916) 373 - 5600 43 of 100 

# Test America

THE LEADER IN ENVIRONMENTAL TESTING



## MethodiD 

# J{,)1f 1 

# /,)1£{/e)ro..r)

Column

# m___.z;..D~g....;;..~------­ STDID 

# STJl.£..1

Analyzed

# by~M..:...::·~G~. 

# -------- Std. Pkg. By---L..M.!..:.

........



# G;,_., • ..__ ______ _ Std. Pkg. Reviewed By

___**~l-_r\** 

# ___ _

DAILY STANDARD PACKAGE 

### Standard, CPSM, and Solvent Blank present? Copy of log-file and Beginning Static Resolution present? CPSM blow up present? Curve Summary present? Summary of Method criteria present or docwp.ented below? Daily standard within method specified limits?· Analyte retention times correct? Isotopic ratios within limits? CPSM**valley~** 

### method specified limits? • Are chromatographic windows correct? Samples analyzed 

### within 12 

### brs of daily standard? Manual reintegration's checked and hard copies included? Ending Standard present? Ending Static Resolutions present Absolute retention times for 13C12-1,2,3,4-TCDD and 13Cl2- 1,2,3,7,8,9-HxCDD are within+/- 15 seconds of the retention times in the Initial Calibration? (required for alll613B samples) 

# Test America- West Sacramento

Daily Calibration Checklist Dioxin Methods

Associated ICAL 

## J 

# LJ'l/1.10 //

# ~YJ) Instrument 

# m_VJ...&.L..P..:...f

_______ _
STD Solution 

# J/ YJI..NL.-1-}

Date Analyzed 

# li-z
?A 

# bl

.
Date Std. Pkg.

# Assembled,___l-z...~/~_1_~_.') ___ _ Date Std. Pkg. Reviewed \"L 

## ["2... 

## '"3/ I (



### INITIATED REVIEWED 

# ./ ,/ 

## / yl' 

## v' ../ 

# / II' 

# ./ / 

# / / 

# ./ / 

# ..// ../. 

## /**~** 

## t/ ./ 

## / v'

## N~ r-Jk 

# 1'\t\ 

# NP-r v/ 

# ../.

llC-11.1 

## Lf.:1C-OD

# f}:O~ r./'

J I I 

### f:tL-1 1 

### 1.11

## t.~-H1-CD.J 32:¥,

## CO~NTS=--------------------------------------------------------

* Method 8290ff09/M0023A:**(beginning)~** 20% from curve RRFs for native analytes,**~** 30% from curve RRFs for labeled compounds. 

### Method 8290ff09/M0023A:**(ending)~** 25% from curve RRFs for native analytes,**~** 35% from curve RRfs for labeled compounds. 

### Method 23: See Method 23 Daily Standard Criteria, Table 5. 

### Method 16138: See, Method 16138 or Method 16138 Tetras Daily Standard Criteria, 

### **Method 23/0023A CPSM Criteria: 25% valley between 2378 TCDF (DB-225)ri'CDD (DB-5) and 

### its closest eluters normalized to the smallest peak of the triplet

. 

### Method 1613B/8290!f09 CPSM Criteria: 25% valley between 2378 TCDF (D8-225)ri'CDD (DB-5) and its closest eluters normalized to the 2378 peak.



### N:\Hires\Forms\QA-231 Dioxin Daily Std 

### Checklist.doc QA-231 8/10/09 DWG1L140412 TestAmerica West Sacramento (916) 373 - 5600 44 of 100 

### Quantitation Summary TestAmerica West Sacramento

Run text: ST1223 Sample text: ST1223 :CS3 11DXN221 Run #7**Filen~me:** 

### 23DE119D5 S: 2 I: 1 Results: 23DE119D51613 Acquired: 23-DEC-11 11:57:53 Processed: 23-DEC-11 15:46:49 Run: 23DE119D5 Analyte: 1613 Cal: 1613122011905

Factor 1:20.000 Factor 2:1.000 Sample size: 1.000

Name Resp RA 

### RT 

### RRF

13C-1,2,3,4-TCDD 108144300 0.76 

### y 19:04 /

13C-2,3,7,8-TCDF 142643500 0.80 

### y 18:29 1.34 2,3,7,8-TCDF 13418460 0.82 y 

### 18:30 0.85 Total TCDF 13418460 0.82 

### y 18:30 0.85

13C-2,3,7,8-TCDD 99546200 0.76 y 

### 19:16 0.91 2,3,7,8-TCDD 10036590 0.82 y 

### 19:18 1.07 Total TCDD 10096411 3.21 n 18:29 1.07

37Cl-2,3,7,8-TCDD 12697820 1.00 y 

### 19:18 1.14

13C-1,2,3,7,8-PeCDF 1,2,3,7,8-PeCDF 13C-2,3,4,7,8-PeCDF 2,3,4,7,8-PeCDF

Total F2 PeCDF Total F1 PeCDF

13C-1,2,3,7,8-PeCDD 1,2,3,7,8-PeCDD Total PeCDD

13C-1,2,3,7,8,9-HxCDD

13C-1,2,3,4,7,8-HxCDF 1,2,3,4,7,8-HxCDF 13C-1,2,3,6,7,8-HxCDF 1,2,3,6,7,8-HxCDF 13C-2,3,4,6,7,8-HxCDF 2,3,4,6,7,8-HxCDF 13C-1,2,3,7,8,9-HxCDF 103707400 1.46 

### y 24:08 0.97 64557600 1.59 y 

### 24:10 1.19 104233600 1.49 y 

### 25:38 0.95

61622700 1.53 y 

### 25:40 1.17 127480382 2.58 n 22:06 1.18 103623 2.27 n 19:04 1.18

83336400 1.49 y 

### 26:27 0.64 35403700 1.47 y 

### 26:29 1.00 35521037 2.34 n 24:09 1.00

82208800 1. 32 y 

### 32:46 /

-

86536600 0.51 y 

### 31:36 0.94 55907900 1.21 

### y 31:36 1.37 114331200 0.51 

### y 31:43 1.24

64735200 1.22 

### y 31:44 1.28 98746700 0.52 

### y 32:16 1.12 57907000 1.21 

### y 32:17 1.28 93640300 0.53 

### y 32:56 0.96 1,2,3,7,8,9-HxCDF 54499400 1.23 

### y 32:56 1.26 Total HxCDF 233198690 1.52 n 30:26 1.30

13C-1,2,3,4,7,8-HxCDD 1,2,3,4,7,8-HxCDD 13C-1,2,3,6,7,8-HxCDD 1,2,3,6,7,8-HxCDD 1,2,3,7,8,9-HxCDD Total HxCDD

13C-1,2,3,4,6,7,8-HpCDF 1,2,3,4,6,7,8-HpCDF 13C-1,2,3,4,7,8,9-HpCDF 1,2,3,4,7,8,9-HpCDF Total HpCDF 54948800 1. 34 

### y 33778600 1.15 

### y 69429300 1. 34 y 

### 41521300 1.20 

### y 44145100 1.17 

### y 119445000 1.15 

### y 32:26 0.66 32:26 1.19 32:30 0.84 32:31 1.18 32:46 1.39 32:26 1.25

77771800 0.43 

### y 34:13 0.93 60716300 1.05 y 

### 34:13 1.50 71345700 0.45**y"~5T1~9** 

### 50897800 1.04 y 

### 35:19 1.40 112584708 1.05 y 

### 34:13 1.46 Cone

50.206

98.291 11.113 11.113

101.605 9.407 9.463

10.272

99.202 52.157 100.935

50.393 103.607 0.084

120.849

42.371 42.511

52.118

111.476

47.050 111.862

44.242 107.472

45.832 118.823

46.183 183.424

101.807

51.530 100.288

50.743 50.917 153.189

101.197

52.044 110.334

50.800 103.737 EDL

0.091 0.195 0.195

0.225 0.086 0.086

0.051

0.220 0.183 0.222 0.194 0.188 0.108

0.087 0.136 0.136

0.133 0.041 0.101 0.039 0.112 0.040 0.131 0.044 0.041

0.172 0.035 0.134 0.034 0.029 0.033

0.652 0.213 0. 775 0.277 0.2.42 Page 2 o

Rec

98.3

101.6

102.7

99.2

100.9

120.8

111.5

111.9

107.5

118.8

101.8

100.3

101.2

110.3 M



### n

n

n


### n

n


### n


### n

n

n


### n
n
n
n
n

n
n
n

n

n
n


### n
n


### n
n
n
n
n

n


### n
n

n


### n

n

n


### n
n
n
nG1L140412 TestAmerica West Sacramento (916) 373 - 5600 45 of 100 

### 13C-1,2,3,4,6,7,8-HpCDD 75541400 1.00 

### y 35:00 0.80 114.265 0.466 114.3 n 

### 1,2,3,4,6,7,8-HpCDD 36964100 1.06 

### y 35:01 1.04 47.243 0.175 n 

### Total HpCDD 37146563 1.05 

### y 34:28 1.04 47.477 0.175 n



### 13C-OCDD 116183400 0.82 

### y 37:24 0.67 209.654 0.220 104.8 n 

### OCDF 90667400 0.91 

### y 37:31 1.40 111.464 0.116 n 

### OCDD 72106700 0.95 

### y 37:25 1.14 108.851 0.174 nG1L140412 TestAmerica West Sacramento (916) 373 - 5600 46 of 100 

### Data file Smp Work Order Sample ID FV-uL Method/Matrix Box Size 

## u

23DE119DS 1 CP1223 DB-5 CPSM 3732-16 1.00000 23DE119D5 2 

# I ST1223 CS3 11DXN221 1.00000 23DE119D5 3 MPT3V-1-AA G1L210000-79B 20 8290/SOLID 62 10.00000 g 

### 23DE119D5 4 MPT23-1-AA G1L210000-69B 20 1613B/WATER 1. 

### 00000 L 23DE119D5 5 Needle "Z"ed 0.00000 23DE119DS 6 MPRTK-1-AA G1L190443-1 20 8290/SOLID 10.21000 g 

### 23DE119D5 7 MPQNA-1-AC G1L160524-1 20 8290/SOLID 10.06000 g 

### 23DE119D5 8 MPQNC-1-AC G1L160524-2 20 8290/SOLID 10.40000 g 

### 23DE119D5 9 MPQND-1-AC G1L160524-3 20 8290/SOLID 10.15000 g 

### 23DE119D5 10 MPQNE-1-AC G1L160524-4 20 8290/SOLID 10.01000 g 

### 23DE119D5 11 

### MPQNG-1-AC G1L160524-5 20 8290/SOLID 10.44000 g 

### 23DE119D5 12 MPQNH-1-AC G1L160524-6 20 8290/SOLID 10.82000 g 

### 23DE119D5 13 MPT3V-1-AC G1L210000-79C 20 8290/SOLID 10.00000 g 

### 23DE119D5 14 MPT3V-1-AD G1L210000-79L 20 8290/SOLID 10.00000 g 

### 23DE119DS 15 ST1223A CS3 11DXN221 1. 

### 00000 23DE119D5 16 1.00000 23DE119DS 17 1. 

### 00000 23DE119DS 18 1.00000 23DE119D5 19 MG 12/23/11 

## j

...

# ~ '"' 1.00000 

# 1(\.\9.**\~~'** 

# ..**~,, \...0~**  

# \')'

.---G1L140412 TestAmerica West Sacramento (916) 373 - 5600 47 of 100 

### Data file Smp Work Order Sample ID FV-uL Method/Matrix Box Size 

## u

23DE119D5 1 CP1223 DB-5 CPSM 3732-16 1.00000 23DE119D5 2 ST1223 CS3 11DXN221 1.00000 23DE119D5 3 MPT3V-l-AA G1L210000-79B 20 8290/SOLID 62 10.00000 

### g 23DE119D5 4 MPT23-l-AA G1L210000-69B 20 1613B/WATER 1.00000 L 23DE119D5 5 Needle "Z"ed 0.00000 23DE119D5 6 MPRTK-1-AA G1L190443-1 20 8290/SOLID 10.21000 

### g 23DE119D5 7 MPQNA-1-AC G1L160524-1 20 8290/SOLID 10.06000 

### g 23DE119DS 8 MPQNC-1-AC G1L160524-2 20 8290/SOLID 10.40000 

### g 23DE119DS 9 MPQND-1-AC G1L160524-3 20 8290/SOLID 10.15000 

### g 23DE119D5 10 MPQNE-1-AC G1L160524-4 20 8290/SOLID 10.01000 

### g 23DE119DS 11 MPQNG-1-AC G1Ll60524-5 20 8290/SOLID 10.44000 

### g 23DE119D5 12 MPQNH-1-AC G1L160524-6 20 8290/SOLID 10.82000 

### g 23DE119D5 13 MPT3V-1-AC GlL210000-79C 20 8290/SOLID 10.00000 

### g 23DE119D5 14 MPT3V-1-AD G1L210000-79L 20 8290/SOLID 10.00000 

### g 23DE119DS 15 ST1223A CS3 11DXN221 1.00000 23DE119DS 16 1.00000 23DE119D5 17 1.00000 23DE119D5 18 1.00000 23DE119D5 19 MG 12/23/11 

## j

...

# ~ "'' 1.00000 

# \\,\9. \ 't 

## "J 

# (1,'**\~~** \')-G1L140412 TestAmerica West Sacramento (916) 373 - 5600 48 of 100IPPM200Il292.98245PPM200......r\\j\J\---PPM200......Jrr\A.J'\l392.97604----PeakLocateExamination:23-DEC-2011:11:10File:23DE119D5Experiment:DIOXINRESFunction:1Reference:PFKVoltsPPM1.1509200VoltsPPM0.5100200---VoltsPPM0.2310I200Volts......0.2450304.98245__Volts0.1845Volts0.1771404.97604PPM200PPM200PPM200Volts......0.0966,MMIllIt,),,318.97925Volts._.0.1242IIJ"l,I..w366.97925416.97604Volts0.0968PPM200IPPM200Volts0.4680330.97_92_5_Volts......0.2454'380.97_604G1L140412 TestAmerica West Sacramento (916) 373 - 5600 49 of 1001PPM1,200........IMtjNPeakLocateExarnination:23-DEC-2011:11:12File:23DE119D5Experirnent:DIOXINRESFunction:2Reference:PFKVoltsPPMVoltsPPM0.0983200........0.4967200tH.\)1.Volts........0.5312jr\t.r\J.ljy318.94735318.97925011_:1..5_330.94615330.97925331.01235342.94495342.97925343.01355PPMVoltsPPMVoltsPPMVolts200........0.2099200........0.1391200........0.2967fH"MlJf\1J''J/')\JV354.94375354.97925355.01475366.94255366.97925367.01595380.93795380.97604381.01414PPMVoltsPPMVoltsPPMVolts2000.28382000.2037200........0.0879392.93675392.97604393.01534404.93555404.97604405.01654416.93435__416.97604417.01774I-L-- -G1L140412 TestAmerica West Sacramento (916) 373 - 5600 50 of 100PPMgoo..-.IM..lPeakLocateExamination:23-DEC-2011:11:13File:23DE119D5Experiment:DIOXINRESFunction:3Reference:PFKVoltsPPMVoltsPPM0.1337200+-t0.3614200.!I..\nl+-tlv,(\fi'\j.J\)v\J366.94255366.97925367.01595PPMVolts2000.2203404.93555404.97604405.01654PPMVolts200,..._.0.2292442.92854442.97284443.01714'I380.93795PPM200416.93435PPM200380.97604381.01414Volts0.1091416.97E)Q-4___i17.01774Volts0.2018454.92734454.97284455.01834392.93675392.97604PPM200..__.fli.\l\.Jf'430.92974430.97284Volts0.3440393.01534Volts0.1995431.01594G1L140412 TestAmerica West Sacramento (916) 373 - 5600 51 of 100f>PM001380.93795PPM200416.93435PPM200454.92734IIPeakLocateExamination:23-DEC-2011:11:13File:23DE119D5Experiment:DIOXINRESFunction:4Reference:PFKVoltsPPMVoltsPPMVolts0.3721200-0.34372000.2693IJl\})'\380.97604381.01414392.93675392.97604393.01534404.93555404.97604405__._Q_l65VoltsPPMVoltsPPMVolts0.1087200,__.0.1958200-0.2567tJJttWl11IY/fJ,\,u\l'\;416.97604417.01774430.92974430.97284431.01594442.92854442.97284443.01714VoltsPPMVoltsPPMVolts0.2043200,__.0.0893200-0.1177Jl1l'[£illNI!!''A/X\M454.97284455.018341466.92614466.97284467.01954!480.92157480.96967481.01776G1L140412 TestAmerica West Sacramento (916) 373 - 5600 52 of 100fPM200430.92974l?PM2ooPeakLocateExamination:23-DEC-2011:11:14File:23DE119D5430.97284_,lX\..IlExperiment:DIOXINRESFunction:5Reference:PFKVolts:PPMVolts0.22662000.2589431.015944AA.9.2S.54443.01714VoltsPPMVolts0.11002000.1061200_,0.2434_lIlI\1I5\.A454.92734454.97284455.01834PPM20011/mMlVolts0.1561f1h/IA.tY1I'J,I466.92614466.97284467.01954480.92157480.96967481.01776492.92037492.96967493.01896PPMVoltsPPMVolts2000.1701200_,0.1021rI-,Nv'\)v504.91917504.9696_?_5Q5.0201._65_16.96967517.02136G1L140412 TestAmerica West Sacramento (916) 373 - 5600 53 of 100Ii'krPrM2po!I1'ilI'IIII;•I"A-""l':f8o.97604fiSIRLMExarnination:23-DEC-2011:14:07File:23DE119DSExperirnent:DIOXINRESFunction:6(vrJv\\((\nyAA;IV\j'Jv!\AJ'-V\1\A./\J380.97604Volts0.3878.......-r\380.97604G1L140412 TestAmerica West Sacramento (916) 373 - 5600 54 of 100?ffiPPM200·•'j":;I.1I_Jj04_.9_825_1_SIRLMExamination:23-DEC-2011:14:08File:23DE119D5Experiment:DIOXINRESFunction:?Nu'Av\tl\A)v\IAf\Volts0.2917A.vr--AA-----------304.98251--_3_Q4.9.82_SJ._G1L140412 TestAmerica West Sacramento (916) 373 - 5600 55 of 100>Page1of1Run:23DE119DSAnalyte:1613Cal:16131220119058T1220B:C8-111DXN2198T1220A:C8-211DXN2208T1220:C8-311DXN2218T1220D:C8-411DXN2228T1220C:C8-511DXN22320DE119DS20DE119D520DE119DS20DE119DS20DE119DS8483828685NameMean8.D.%R8DRRF1RRF2RRF3RRF4RRFS13C-1121314-TCDD---%13C-2131718-TCDF1.3420.0302.27%1.351.381.361.311.312131718-TCDF0.8460.0505.86%0.840.920.860.800.81TotalTCDF0.8460.0505.86%0.840.920.860.800.8113C-2131718-TCDD0.9060.0131.41%0.910.920.910.900.892131718-TCDD1.0720.0514.80%1.101.141.061.011.05TotalTCDD1.0720.0514.80%1.101.141.061.011.OS37Cl-2131718-TCDD1.1430.0524.57%1.081.221.151.111.1413C-112131718-PeCDF0.9670.0272.83%0.970.980.960.931.00112131718-PeCDF1.1940.0635.31%1.251.261.181.121.1413C-213141718-PeCDF0.9550.0454.69%1.010.940.920.911.00213141718-PeCDF1.1730.0816.90%1.211.301.151.101.11TotalF2PeCDF1.1830.0715.98%1.231.281.171.111.13TotalF1PeCDF1.1830.0715.98%1.231.281.171.111.1313C-112131718-PeCDD0.6380.0223.49%0.630.630.610.640.6711:2131718-PeCDD1.0030.0575.71%1.061.060.980.940.97TotalPeCDD1.0030.0575.71%1.061.060.980.940.9713C-1121'3171819-HxCDD---%13C-112/3141718-HxCDF0.9440.0131.38%0.940.960.920.960.941.3730.0926.68%1.431.47 1.421.28 1.2713C-1121:31617I8-HxCDF1.2430.0846.76%1.271.251.351.221.1211213161718-HxCDF1.2800.0866.68"1.351.401.231.211.2213C-21314161718-HxCDF1.1180.0413.67%1.131.151.161.091.0621314161718-HxCDF1.2800.0816.36"1.371.361.261.211.2013C-11213171819-HxCDF0.9590.0495.09"0.961.001.010.930.8911213171819-HxCDF1.2600.0473.77"1.331.261.271.211.23G1L140412 TestAmerica West Sacramento (916) 373 - 5600 56 of 100TotalHxCDF1.2950.0715.52t1.371.371.28 1.221.2313C-1,2,3,4,7,8-HxCDD0.6570.0355.29t0.660.620.630.710.671,2,3,4,7,8-HxCDD1.1930.0927.70t1.271.31 1.161.121.1113C-1,2,3,6,7,8-HxCDD0.8420.0313.64t0.820.870.880.810.831,2,3,6,7,8-HxCDD1.1790.13011.0t1.341.301.121.071.061,2,3,7,8,9-HxCDD1.3940.16111.6t1.591.521.391.251.22TotalHxCDD1.2550.12710.2t1.401.381.22 1.141.1313C-1,2,3'.,4,6, 7,8-HpCDF0.9350.0151.62t0.940.940.940.950.911,2,3,4,6,7,8-HpCDF1.5000.1177.79t1.611.621.491.39 1.3813C-1,2,3,4,7,8,9-HpCDF0.7870.0182.27t0.800.760.780.810.791,2,3,4,7,8,9-HpCDF1.4040.1067.54t1.511.531.381.311.31TotalHpCDF1.4560.1127.69t1.571.58 1.441.35 1.3513C-1,2,3,.4,6, 7,8-HpCDD0.8040.0192.32%0.810.810.800.820.771,2,3,4,6,7,8-HpCDD1.0360.0434.19t1.071.091.020.991.01TotalHpCDD1.0360.0434.19%1.071.091.020.991.0113C-OCDD0.6740.0162.32t0.680.660.660.680.69OCDF1.4000.0886.31%1.471.491.421.321.30OCDD1.1400.0786.85t1.201.231.141.081.OSG1L140412 TestAmerica West Sacramento (916) 373 - 5600 57 of 100

# ~':- 

# ·stAmerlca ::--e

.. _-_- ;

-- ____ - ____ :_ ,- ___ ,_.,- ·----_ .i

:'THE LEADER IWENVIRONME.NT.AL." l'.ESTJ!iiG

Compound 

### OPR 

## VER % 

### ng/ml CS3

16138 Acceptance Criteria .13C-2",3, 7,8- TCDF 22-152 71-140 2,3,7,8-TCDF 75-158 8.4- 12.0 13C-2,3,7,8-TCDD 20-175 82 -121 2,3,7,8-TCDD 67- 158 7.8- 12.9 37CI4-2,3, 7,8- TCDD 31

- 191 7.9 -12.7 13C-1,2,3,7,8-PeCDF 21

- 192 76-130 1 ,2,3, 7,8-PeCDF 80- 134 41 -60 13C-2,3,4,7,8-PeCDF 13- 328 77 -130 2,3,4, 7,8-PeCDF 68-160 41-61 13C-1 ,2,3, 7,8-PeCDD 21-227 62-160 1 ,2-,3,7,8-PeCDD 70-142 39-65 13C-1,2,3,4,7,8-HxCDF 19- 202 76-131 1 ,2,3,4,7,8-HxCDF 72- 134 45-56 13C-1 ,2,3,6,7,8-HxCDF 21 -159 70-143 1,2,3,6,7,8-HxCDF 84- 130 44-57 13C-2,3,4,6,7,8-HxCDF 22-176 73-137 2,3,4,6,7,8-HxCDF 70- 156 44-57 13C-1,2,3,7,8,9-HxCDF 17-205 74-135 1 ,2,3,7,8,9-HxCDF 78- 130 45-56 13C-1 ,2,3,4,7,8-HxCDD 21 -193 85 -117 1 ,2,3,4,7,8-HxCDD 70-164 39-64 13C-1,2,3,6,7,S-HxCDD 25 -163 85 -118 1 ,2,3,6,7 ,8-HxCDD 76-134 39-64 1 ,2,3, 7 ,8,9-HxCDD 64-162 41-61 13C-1 ,2,3,4,6,7,8-HpCDF 21 -158 78-129 1 ,2,3,4,6,7 ,8-HpCDF 82-122 45-55 13C-1,2,3,4, 7 ,8,9-HpCDF 20 -186 77-129 1,2,3,4,7,8,9-HpCDF 78-138 43-58 13C-1,2,3,4,6,7,8-HpCDD 26-166 72-138 1,2,3,4,6,7,8-HpCDD 70- 140 43-58 13C-OCDD 13 -199 96-415 OCDF 63- 170 63-159 OCDD 78- 144 79-126

16138 Acceptance Criteria for Tetras Only Analysis

13C-2,3-,7,8-TCDF 26-126 76 -131 2,3, 7,8- TCDF 80- 147 8.6-11.6 13C-2,3,7,8-TCDD 25 -141 85 -117 2,3, 7,8- TCDD 73- 146 8.2-**12~3** 37-CI4-2,3, 7,8-TCDD 37-158 8.3 -12.1

Q:\FORMS\Qa-HR-1 00 16138 criteria.xls Page 1 of 1 

### West Sacramento Method 16138 Acceptance Criteria Based on Tables 6, 6A and 7 of the method



## VER ng/ml CS2

71-140 1.68-2.40 82 -121 1.56-2.58 1.58- 2..54 76-130 8.20-12.0

77-130 8.20- 12.2

62- 160 7.80-13.0

76 -131 9.00-11.2

70-143 8.80-11.4

73-137 8.80-11.4

74-135 9.00-11.2

85 -117 7.80-12.8

85 -118 7.80-12.8 8.20- 12.2 -18-129 9.00-11.0

77 -129 8.60- 11.6

72-138 8.60-11.6

96 -415 12.60-31.8 15.80-25.2

76 -131 1.72-2.32 85-117 1.64-2.46 1.66-2.42 

## VER ng/ml CS4

71-140 33.6-48 82-121 31.2-51.6 31.6-50.8

76-130 164-240 77-130 164-244 62-160 156-260 76 -131 180-224 70-143 176-228 73-137 176-228 74-135 180-224 85- 117 156-256 85 -118 156-256 164-244

.. 78-129 "180-220

77-129 172-232- 72-138 172-232 96-415 252-636 316-504

76 -131 34.4-46.4

85-117 32-.8-49.2 33.2-48.4 Field Samples 

### ng/ml

24-169

25-164

3.5-19.7 24-185

21 -178

25-181

26-152

26-123

28-136

29--147

32 -141

28-130

28-143

.26-138

23-140

34-313

29-140

31 -137

4.2 -16.4

QA-HR-100 06/2712011 ERSG1L140412 TestAmerica West Sacramento (916) 373 - 5600 58 of 100File:23DE119D5#1-530Acq:23-DEC-201111:15:15GCEI+VoltageSIRAutospec-UltimaESample#1Text:CP1223:DB-5CPSM3732-16Exp:DIOXINRES321.8936BSUB(1000,15,-3.0)10019:10,.......--959085v2.6E6802.5E6752.3E6702.2E6652.0E6601.9E6551.7E6501.5E6451.4E6402,3,7,8-TCDD1.2E63S1.1E6309.3E5257.7E5'206.2E5154.6E5103.1E551.5E5O.OEOTimeG1L140412 TestAmerica West Sacramento (916) 373 - 5600 59 of 100 

# TestAmerica

THE LEADER IN ENVIRONMENTAL TESTING



### Method 

# m----:1_, ,__;-1

# g~j-l b_/1_:..._R

# (:o......:.._+~il.J'__.:_) --
Column 

## ID.____:D;.....;E___;)::;__

______ _

STD 

## ID 

# fT } 1,;1.. 1..

Analyzed by 

# 8 .M,

Std. 

## Pkg. By 

# MJG.

Std. 

## Pkg. Reviewed By

# J~
DAILY STANDARD PACKAGE 

### Standard, CPSM, and Solvent Blank present? Copy of log-file and Beginning Static Resolution present? CPSM blow up present? Curve Summary present? Summary of Method criteria present or docurp.ented below? Daily standard within method specified limits?" Analyte retention times correct? Isotopic ratios within limits? CPSM valley < method specified limits?·• Are chromatographic windows correct? Samples analyzed within 12 brs of daily standard? Manual reintegration's checked andhardcopies included? Ending Standard present? Ending Static Resolutions present Absolute retention times for 13C12-1,2,3,4-TCDD and 13Cl2- 1,2,3,7,8,9-HxCDD are within+/- 15 seconds of the retention times in the Initial Calibration? (required for all1613B samples) 

# Test America- West Sacramento

Daily Calibration Checklist Dioxin Methods

Associated 

## ICAL J 

# {,(5 }'Lto

# /1~0~
Instrument

# ID_..L.;~P;.__f 

# _______ _

STD Solution }} 

# D"' tj 21 )

Date Analyzed 

# j?, 

# /z.a./n

Date Std. 

## Pkg. Assembled 

# r]., 

# /z.:t./1,

Date Std. 

## Pkg. Reviewed 

# (L/b'3j{l I 

## I INITIATED REVIEWED 

# ../, ,./**~** 

## / 

## ./ / 

# / / 

## ./ / 

## ./ c/ 

# ./ / 

# /**~** 

## ./ / 

## /, / 

## / ./ 

# ..AK ./ '/1..-D 

### ./



# "A 11-/lJilJ 

# NA / 

# v

- 

## / 

## c/ 11L-

## J,'J~, 

# 't- 

# rcJJD f**~=ot** 11e- -1. t

## ~ 1

## t~-R.,.c.D.D J 7..: 

## 'fl.

,

## CO~NTS:---------------------------------------------------------

* Method 8290!f09/M0023A: (beginning)**~** 20% from curve RRFs for native analytes,**~** 30% from curve RRFs for labeled compounds. Method 8290/T09/M0023A: (ending) S 25% from curve RRFs for native analytes, S 35% from curve RRFs for labeled compounds. Method 23: See Method 

### 23 Daily Standard Criteria, Table 5. Method 16138: See, Method 16138 or Method 16138 Tetras Daily Standard Criteria, **Method 23/0023A CPSM Criteria: 25% valley between 2378 TCDF (DB-225)trCDD (DB-5) and its closest eluters normalized to the smallest peak of the triplet

. Method 1613B/8290!f09 CPSM Criteria: 25% valley between 2378 TCDF (DB-225)/TCDD (DB-5) and its closest eluters normalized to the 2378 peak.



### N:\Hires\Forms\QA-231 Dioxin Daily Std Checklist.doc QA-231 8/10/09 DWG1L140412 TestAmerica West Sacramento (916) 373 - 5600 60 of 100 

### Quantitation Summary TestAmerica West Sacramento

Run text: ST1222 Sample text: ST1222 :CS3 11DXN221 Run #7 Filename: 22DE119D5 S: 2 I: 1 Results: 22DE119D51613 Acquired: 22-DEC-11 22:51:26 Processed: 23-DEC-11 11:44:28 Run: 22DE119D5 Analyte: 1613 Cal: 1613122011905

Factor 1:20.000 Factor 2:1.000 Sample size: 1.000

Name Resp 

### RA RT RRF

13C-1,2,3,4-TCDD 154368700 0.78 y 19:06

13C-2,3,7,8-TCDF 217382600 0.82 y 18:31 1.34 2,3,7,8-TCDF 20986430 0.78 y 18:32 0.85 Total TCDF 20986430 0.78 y 18:32 0.85

13C-2,3,7,8-TCDD 142438500 0.77 y 19:18 0.91 2,3,7,8-TCDD 14944790 0.81 y 19:19 1.07 Total TCDD 15054919 2.62 n 18:31 1.07

37Cl-2,3,7,8-TCDD 17798800 1.00 y 19:19 1.14

13C-1,2,3,7,8-PeCDF 1,2,3,7,8-PeCDF 13C-2,3,4,7,8-PeCDF 164071700 1.51 y 24:09 0.97 96058700 1.51 y 24:11 1.19 161095900 1.52 y 25:39 0.95 2,3,4,7,8-PeCDF 92649000 1.53 y 25:41 1.17

Total F2 PeCDF 189914834 0.81 n 23:31 1.18 Total F1 PeCDF 

## * * n NotFnd 1.18

13C-1,2,3,7,8-PeCDD 112366200 1.45 y 26:29 0.64 1,2,3,7,8-PeCDD 55722200 1.52 y 26:31 1.00 Total PeCDD 55966093 2.98 n 24:11 1.00

13C-1,2,3,7,8,9-HxCDD 124792800 1.38 y 32:46

13C-1,2,3,4,7,8-HxCDF 1,2,3,4,7,8-HxCDF 13C-1,2,3,6,7,8-HxCDF 1,2,3,6,7,8-HxCDF 13C-2,3,4,6,7,8-HxCDF 2,3,4,6,7,8-HxCDF 13C-1,2,3,7,8,9-HxCDF 1,2,3,7,8,9-HxCDF Total HxCDF

13C-1,2,3,4,7,8-HxCDD 1,2,3,4,7,8-HxCDD 13C-1,2,3,6,7,8-HxCDD 1,2,3,6,7,8-HxCDD 1,2,3,7,8,9-HxCDD Total HxCDD

13C-1,2,3,4,6,7,8-HpCDF 1,2,3,4,6,7,8-HpCDF 13C-1,2,3,4,7,8,9-HpCDF 1,2,3,4,7,8,9-HpCDF Total HpCDF 127946900 0.50 y 31:37 0.94 79210200 1.18 y 31:38 1.37 170787200 0.52 y 31:43 1.24 100513600 1.21 y 31:44 1.28 151329700 0.49 y 32:18 1.12

91088200 1.19 y 32:18 1.28 125878200 0.52 y 32:56 0.96

74357100 1.20 y 32:57 1.26 345366829 1.04 n 30:28 1.30

86432700 1.36 y 32:26 0.66 45475600 1.14 

### y 32:27 1.19 97686100 1.36 y 32:31 0.84 63910900 1.18 y 32:31 1.18 65875800 1.17 y 32:47 1.39 175500828 3.94 n 31:37 1.25

118190400 0.44 y 34:14 0.93

88841900 1.04 y 34:14 1.50 103732400 0.44 y 35:19 6.79

74216400 1.05 y 35:19 1.40 163058300 1.04 y 34:14 1.46 Cone

71.666

104.938

11.405 11.405

101.851 9.790 9.862

10.087

109.948

49.055 109.285

49.023 98.705 

## *

114.154

49.459 49.675

79.115

108.578

45.086 110.078

45.986 108.499

47.043 105.225

46.873 185.094

105.494

44.104 92.954 55.512 51.327 151.150

101.311

50.110 105.678

50.946 101.056 EDL

0.194 0.346 0.346

0.328 0.176 0.176

0.109

0.218 0.326 0.221 0.350 0.338 0.171

0.161 0.178 0.178

0.189 0.105 0.144 0.094 0.160 0.098 0.186 0.124 0.104

0.384 0.076 0.300 0.075 0.064 0.071

1. 061 0.168 1.260 0.236 0.198 Page 2 of

Rec 

### M

104.9

101.9

100.9

109.9

109.3

114.2

108.6

110.1

108.5

105.2

105.5

93.0

101.3

105.7 n



### n

n

n

n


### n
n

n

n

n


### n
n
n

n

n



### n
n



### y

n
n
n
n
n



### n
n
n


### n

n
n
n
n


### n



### n

n
n
n
n
nG1L140412 TestAmerica West Sacramento (916) 373 - 5600 61 of 100 

### 13C-1,2,3,4,6,7,8-HpCDD 105418300 0.99 

### y 35:00 0.80 105.044 0.587 105.0 

### n 1,2,3,4,6,7,8-HpCDD 55197200 1.05 

### y 35:01 1.04 50.553 0.324 

### n Total HpCDD 55433777 1.20 

### n 34:29 1.04 50.770 0.324 

### n

13C-OCDD 162821300 0.82 

### y 37:25 0.67 193.553 0.238 96.8 

### n OCDF 121169200 0.90 

### y 37:31 1.40 106.294 0.206 

### n OCDD 100007300 0.95 

### y 37:25 1.14 107.726 0.338 

### nG1L140412 TestAmerica West Sacramento (916) 373 - 5600 62 of 100 

### Quantitation Summary TestAmerica West Sacramento

Run text: ST1222 Sample text: ST1222 :CS3 11DXN221 Run #7 Filename: 22DE119D5 S: 2 I: 1 Results: 22DE119D51613 Acquired: 22-DEC-11 22:51:26 Processed: 23-DEC-11 11:44:28 Run: 22DE119D5 Analyte: 1613 Cal: 1613122011905

Factor 1:20.000 Factor 2:1.000 Sample size: 1.000

Name Resp 

### RA RT RRF

13C-1,2,3,4-TCDD 154368700 0.78 y 

### 19:06

13C-2,3,7,8-TCDF 2,3,7,8-TCDF Total TCDF

13C-2,3,7,8-TCDD 2,3,7,8-TCDD Total TCDD

37Cl-2,3,7,8-TCDD

13C-1,2,3,7,8-PeCDF 1,2,3,7,8-PeCDF 13C-2,3,4,7,8-PeCDF 2,3,4,7,8-PeCDF

Total F2 PeCDF Total F1 PeCDF

13C-1,2,3,7,8-PeCDD 1,2,3,7,8-PeCDD Total PeCDD 217382600 0.82 y 

### 18:31 1.34 20986430 0.78 

### y 18:32 0.85 20986430 0.78 

### y 18:32 0.85

142438500 0.77 y 

### 19:18 0.91

14944790 0.81 

### y 19:19 1.07 15054919 2.62 n 18:31 1.07

17798800 1.00 y 

### 19:19 1.14

164071700 1.51 y 

### 24:09 0.97

96058700 1.51 y 

### 24:11 1.19 161095900 1.52 y 

### 25:39 0.95

92649000 1.53 y 

### 25:41 1.17 189914834 0.81 n 23:31 1.18 

## * * n NotFnd 1.18

112366200 1.45 y 

### 26:29 0.64

55722200 1.52 y 

### 26:31 1.00 55966093 2.98 n 24:11 1.00

13C-1,2,3,7,8,9-HxCDD 112999712 1.43 n 32:46

13C-1,2,3,4,7,8-HxCDF 1,2,3,4,7,8-HxCDF 13C-1,2,3,6,7,8-HxCDF 1,2,3,6,7,8-HxCDF 13C-2,3,4,6,7,8-HxCDF 2,3,4,6,7,8-HxCDF 13C-1,2,3,7,8,9-HxCDF 1,2,3,7,8,9-HxCDF Total HxCDF

13C-1,2,3,4,7,8-HxCDD 1,2,3,4,7,8-HxCDD 13C-1,2,3,6,7,8-HxCDD 1,2,3,6,7,8-HxCDD 1,2,3,7,8,9-HxCDD Total HxCDD

13C-1,2,3,4,6,7,8-HpCDF 1,2,3,4,6,7,8-HpCDF 13C-1,2,3,4,7,8,9-HpCDF 1,2,3,4,7,8,9-HpCDF Total HpCDF 127946900 0.50 y 

### 31:37 0.94 79210200 1.18 y 

### 31:38 1.37 170787200 0.52 y 

### 31:43 1.24 100513600 1.21 y 

### 31:44 1.28 151329700 0.49 

### y 32:18 1.12

91088200 1.19 

### y 32:18 1.28 125878200 0.52 y 

### 32:56 0.96

74357100 1.20 

### y 32:57 1.26 345366829 1.04 n 30:28 1.30

86432700 1.36 y 

### 32:26 0.66 45475600 1.14 y 

### 32:27 1.19 97686000 1.36 

### y 32:31 0.84 63910900 1.18 

### y 32:31 1.18 65875800 1.17 

### y 32:47 1.39 175500828 3.94 n 31:37 1.25

118190400 0.44 y 

### 34:14 0.93

88841900 1.04 

### y 34:14 1.50 103732400 0.44 

### y 35:19 0.79

74216400 1.05 y 

### 35:19 1.40 163058300 1.04 y 

### 34:14 1.46

13C-1,2,3,4,6,7,8-HpCDD 105418300 0.99 y 

### 35:00 0.80 Cone

71.666

104.938

11.405 11.405

101.851 9.790 9.862

10.087

109.948

49.055 109.285

49.023 98.705 

## *

114.154

49.459 49.675

71.639

119.909

45.086 121.566

45.986 119.823

47.043 116.206

46.873 185.094

116.504

44.104 102.654

55.512 51.327 151.150

111.885

50.110 116.707

50.946 101. 056

116.007 EDL

0.194 0.346 0.346

0.328 0.176 0.176

0.109

0.218 0.326 0.221 0.350 0.338 0.171

0.161 0.178 0.178

0.205 0.105 0.156 0.094 0.173 0.098 0.202 0.124 0.104

0.416 0.076 0.324 0.075 0.064 0.071

1.148 0.168 1.364 0.236 0.198

0.635 Page 2 of

Rec 

### M

104.9

101.9

100.9

109.9

109.3

114.2

119.9

121.6

119.8

116.2

116.5

102.7

111.9

116.7

116.0 n

n


### n

n

n
n
n

n



### n
n
n
n
n

n

n


### n



### n

n

n


### n
n

n


### n
n
n
n
n

n
n
n
n
n


### n

n
n


### n

n


### n

nG1L140412 TestAmerica West Sacramento (916) 373 - 5600 63 of 100 

### 1,2,3,4,6,7,8-HpCDD 55197200 LOS 

### y 35:01 1.04 50.553 0.324 

### n Total HpCDD 55433777 1.20 

### n 34:29 1.04 50.770 0.324 

### n

13C-OCDD 162821300 0.82 y 37:25 0.67 213.753 0.257 106.9 

### n OCDF 121169200 0.90 y 37:31 1.40 106.294 0.206 

### n OCDD 100007300 0.95 y 37:25 1.14 107.726 0.338 

### nG1L140412 TestAmerica West Sacramento (916) 373 - 5600 64 of 100 

### Data file Smp Work Order Sample ID FV-uL Method/Matrix Box Size 

## u

22DE119D5 1 CP1222 08-5 CPSM 3732-16 1. 

### 00000 22DE119D5 2 STl222 

### CS3 11DXN221 1. 

### 00000 22DE119D5 3 S81222 Solvent Blank C-14 1. 

### 00000 22DE119D5 4 MPT23-1-AA G1L210000-69B 20 16138-Tetras/11 62 1.00000 L 22DE119D5 5 MPT23-1-AC G1L210000-69C 20 16138-Tetras/11 1.00000 L 22DE119D5 6 MPT23-1-AD G1L210000-69L 20 1613B-Tetras/1J 1. 

### 00000 L 22DE119D5 7 MPNW6-1-AA G1L140474-1 20 1613B/WATER 0.84984 L 22DE119D5 8 MPNWV-1-AA G1L140471-1 20 1613B/WATER 1. 

### 02501 L 22DE119D5 9 MPNWW-1-AA G1L140471-2 20 16138/WATER 1.01825 L 22DE119D5 10 MPK9H-1-AA G1L120423-1 20 16138/WATER 1.06542 L 22DE119D5 11 MPKQK-1-AA G1L090466-1 20 16138/WATER 1.04682 L 22DE119D5 12 MPMOH-1-AC G1L130476-2 20 8290/SOLID 61 10.09000 g 

### 22DE119D5 13 MPMOH-1-AD G1L130476-2S 20 8290/SOLID 10.17000 g 

### 22DE119D5 14 MPMOH-1-AE G1L130476-2D 20 8290/SOLID 10.15000 g 

### 22DE119D5 15 ST1222A CS3 11DXN221 1. 

### 00000 22DE119D5 16 

# re 

# viewtJ 1. 

### 00000 22DE119D5 17 1.00000 22DE119D5 18 1.00000 22DE119D5 19 AM 12/22/11 

# " 1.00000 

# "'.6 

# ,J'tl/;JG1L140412 TestAmerica West Sacramento (916) 373 - 5600 65 of 100 

### Data file Smp Work Order Sample ID FV-uL Method/Matrix Box Size 

## u

22DE119D5 1 CP1222 DB-5 CPSM 3732-16 1.00000 22DE119D5 2 ST1222 CS3 11DXN221 1.00000 22DE119D5 3 SB1222 Solvent Blank C-14 1.00000 22DE119D5 4 MPT23-1-AA G1L210000-69B 20 1613B-Tetras/i1 62 1. 

### 00000 L 22DE119D5 5 MPT23-1-AC G1L210000-69C 20 1613B-Tetras/i1 1.00000 L 22DE119D5 6 MPT23-1-AD G1L210000-69L 20 1613B-Tetras/i1 1.00000 L 22DE119D5 7 MPNW6-1-AA G1L140474-1 20 1613B/WATER 0.84984 L 22DE119D5 8 MPNWV-1-AA G1L140471-1 20 1613B/WATER 1.02501 L 22DE119D5 9 MPNWW-1-AA G1L140471-2 20 1613B/WATER 1.01825 L 22DE119D5 10 MPK9H-1-AA G1L120423-1 20 1613B/WATER 1. 

### 06542 L 22DE119D5 11 MPKQK-1-AA G1L090466-1 20 1613B/WATER 1.04682 L 22DE119D5 12 MPMOH-1-AC G1L130476-2 20 8290/SOLID 61 10.09000 g 

### 22DE119D5 13 MPMOH-1-AD G1L130476-2S 20 8290/SOLID 10.17000 g 

### 22DE119D5 14 MPMOH-1-AE G1L130476-2D 20 8290/SOLID 10.15000 g 

### 22DE119D5 15 ST1222A CS3 11DXN221 1. 

### 00000 22DE119D5 16

# review~) 1. 

### 00000 22DE119D5 17 1.00000 22DE119D5 18 1.00000 22DE119D5 19 AM 12/22/11

# ~ 1.00000 

# fo-6 

# rJt-1/;;G1L140412 TestAmerica West Sacramento (916) 373 - 5600 66 of 100PPM200......(p\r\_II_______2_2_2•!:)_8 2 4 5PPM200......(\J\;_j'\l-PPM200......392.97604PeakLocateExamination:22-DEC-2011:22:01File:22DE119D5Experiment:DIOXINRESFunction:1Reference:PFKVoltsPPMVolts3.2052200......0.5274\J\u\)'\304.98245VoltsPPMVolts1.33932000.446335_4_.9 751:2_5__VoltsPPMVolts0.6854200......0.4379404.97604PPM200PPM200PPM200318.97925416.97604Volts0.2617Volts0.2579Volts0.1917PPM200IIPPM200Volts......1.0913t.\\'wI\)\330.975)25Volts.--.0.6354twIM1\380.97604G1L140412 TestAmerica West Sacramento (916) 373 - 5600 67 of 100PeakLocateExamination:22-DEC-2011:22:03File:22DE119D5Experiment:DIOXINRESFunction:2Reference:PFKIPPMVolts2000.2642IIII'*------+----J'-'-1-...lb-----+-----1r·11cbrIYhb.=I318.94735318.97925319.01115"iPPMVolts200-0.4445J'./354.94375354.97925355.01475PPMVolts200-0.7604\!'''''\392.93675392.97604393.01534PPM200330.94615PPM200330.97925WI_\JIlVolts1.1283Volts0.2553LI.,366.94255 366.97925 367.01595PPMVolts2000.4741404.93555404.97604405.QJ.654PPMVolts200-1.3446tJ!\J\I'\342.94495342.97925343.01355PPMVolts200-0.8054IJ'\t\f380.93795380.97604381.01414PPMVolts2000.1854416.93435416.97604417.01774G1L140412 TestAmerica West Sacramento (916) 373 - 5600 68 of 100PeakLocateExamination:22-DEC-2011:22:05File:22DE119D5Experiment:DIOXINRESFunction:3Reference:PFK!PPMVolts!;2000.2677PPMVolts2000.8338IPPMVolts200._.....0.9192irl{'fIrIf\/v366.94255366.97925367.01595380.93795380.9760436_1.Q_14:JA392.97604393.01534PPMVoltsPPMVoltsPPMVolts2000.50512000.22182000.5304404.93555404.97604405.01654416.93435416.97604417.01774430.92974_43Q_.9728_4._431._Q_1594PPMVoltsPPMVolts200+--+0.53772000.4393,.r\j\.I442.92854442.97284443.01714454.92734454.97284_455.01834G1L140412 TestAmerica West Sacramento (916) 373 - 5600 69 of 100f,PPM''200380.93795PPM200416.93435PPM200454.92734,___.rtr\PeakLocateExamination:22-DEC-2011:22:06File:22DE119D5Experiment:DIOXINRESFunction:4Reference:PFKVoltsPPMVoltsPPM0.8672200,___.0.8857200I'\j\nt\./'\I\.J380.97604381.01414392.93675392.97604393.01534404.93555404.97604VoltsPPMVoltsPPM0.2251200..........0.4720200..........r\,'II'lN./\.J\Volts0.5572405.01654Volts0.6275Ij'\.II416.97604417.017741430.92974431.01594442.92854442.97284443.01714VoltsPPMVoltsPPMVolts0.5129200-0.19532000.2956454.97284455.01834466.92614466.97284467.01954480.92157480.96967481.01776G1L140412 TestAmerica West Sacramento (916) 373 - 5600 70 of 100PPM200430.92974PPM200466.92614PPM200504.91917PeakLocateExamination:22-DEC-2011:22:07File:22DE119D5Experiment:DIOXINRESFunction:5Reference:PFKVoltsPPMVoltsPPM0.53282000.6115200430.97284431.01594442.92854442._97284443.01714454.92734454.97284VoltsPPMVoltsPPM0.21992000.2856200,__....f\\Volts0.5117455.01834Volts0.3522.I'466.97284467.01954480.92157480.96967481.01776492.92037492.96967493.01896VoltsPPMVolts0.39652000.2231504.96967505.02016516.91797516.96967517.02136G1L140412 TestAmerica West Sacramento (916) 373 - 5600 71 of 100PPM200......f1J\.!'\292.98245PPM200342.97925PPM200.......'.f.J\392.97604PeakLocateExamination:23-DEC-2011:09:03File:ENDRES22DE119D5Experiment:DIOXINRESFunction:1Reference:PFKVoltsPPMVoltsPPMVoltsPPM1.0620200......0.19932000.0814200./nr,)'\304.98245318.97925VoltsPPMVoltsPPMVoltsPPM0.47372000.1609200......0.1146200354.97925366.97925VoltsPPMVoltsPPMVolts0.1989200.......0.1589200......0.0773i1u\1i1ijvIlnIfI)\lrl.Jul\.A404.9760441(:).97604_----Volts.......0.4084\.lj_\--Volts.......0.2075.IIr·.J'\380.97604G1L140412 TestAmerica West Sacramento (916) 373 - 5600 72 of 100IIiPPM200kj. JPeakLocateExamination:23-DEC-2011:09:04File:ENDRES22DE119D5Experiment:DIOXINRESFunction:2Reference:PFKVoltsPPMVoltsPPM..........0.0862200..........0.4173200..........lN!\)rV\AII\_;):\II\.I3113.94735318.97925319.01115 330.94615330.97925331.012351342.94495342.97925PPMVoltsPPMVoltsPPM2000.1594200..........0.1076200..........'"J:vvIVrI'.#_;JU'I:354.94375354.355.01475 366.94255366.97925367.01595380.93795380.97604PPMVoltsPPMVoltsPPM200..........0.2295200..........0.1684200..........¥\A.l'\M'\IJlI,,,fl'\AVolts0.4528343.01355Volts0.2459381.01414_Volts0.0711/'\J'\lAI392.93675392.97604393.01534404.93555404.97604405.01654416.93435416.9760441.7_.01774:_G1L140412 TestAmerica West Sacramento (916) 373 - 5600 73 of 100PPM200366.94255PPM200PeakLocate.Examination:23-DEC-2011:09:04File:ENDRES22DE119D5Experiment:DIOXINRESFunction:3Reference:PFKVoltsPPM-0.1214200366.97925367.01595380.93795380VoltsPPM-0.2006200-hiJ'J,,If-v\)Volts0.2944381.01414Volts0.0810PPM200.......I)v"\)93675PPM200392.9'760_1_.Mij.ru_r1·vL}J.r.LVIVolts0.2947393.015:34Volts0.1763404.93555404.97604405.0165493435416.97604417.01774430.92974430.97284431.01594PPMVoltsPPMVolts200+-+0.1893200+-+0.1586Mvr·I'JV\IIIf\(lj·)\\J442.92854442.97284443.01714454.92734454.97284455.01834G1L140412 TestAmerica West Sacramento (916) 373 - 5600 74 of 100PPM200380.93795PPM200416.93435PPM200PeakLocateExamination:23-DEC-2011:09:04File:ENDRES22DE119D5Experiment:DIOXINRESFunction:4Reference:PFKVoltsPPMVoltsPPM..........0.3056200..........0.2892200........../MMMw#Y\JnfJIIjr,f'\.r'J'I\380.Q_7Q04.3_92.93675392.97604393.01534404.93555404.97604VoltsPPMVoltsPPM..........0.0869200..........0.1653200..........!A1Ltt.fllMLrJrjrvl«jr')}'¥416.97604417.01774430.92974430.97284431.01594442.92854442.97284VoltsPPMVoltsPPM-0.1646200..........0.0666200..........t'Mh,litl'r1.111AIVdlkjIJ)\..Volts0.2107;I405.016541voit"sl0.22301443.01714Volts0.1001·---!454.92734454.97284455.01834466.92614466.97284467.01954480.92157480.96967___j_e_]._!.Q_J.7__7§_G1L140412 TestAmerica West Sacramento (916) 373 - 5600 75 of 100PPM200430.92974PPM200466.PPM200504.91917PeakLocateExamination:23-DEC-2011:09:05File:ENDRES22DE119D5Experiment:DIOXINRESFunction:5Reference:PFKVolts0.1916430.97284431.01594Volts0.0907466.97284__4:67.01954Volts0.1383504.9Q_967__5Q5.02016PPM20092854PPM200.........fl'fly·I\442.97284Volts0.2212443.01714Volts0.0957480.92157 480.96967 481.01776PPMVolts200.........0.0868INf'..'\A516.9_1]97_5_16.96967517.02136PPMVolts200.......0.2166MI.N''JJ'\---454.92734454.97284455.01834PPMVolts2000.12431492.92037493.01896G1L140412 TestAmerica West Sacramento (916) 373 - 5600 76 of 100Page1of1Run:22DE119DSAnalyte:1613Cal:16131220119058T1220B:C8-111DXN2198T1220A:C8-211DXN2208T1220:C8-311DXN2218T1220D:CS-411DXN2228T1220C:C8-511DXN22320DE119D520DE119D5 20DE119D520DE119D520DE119D5848382 8685NameMeanS.D.%RSDRRF1RRF2RRF3RRF4RRFS13C-1,2,3,4-TCDD---%13C-2,3,7,8-TCDF1.3420.0302.27%1.351.381.361.311.312,3,7,8-TCDF0.8460.0505.86%0.840.920.860.800.81TotalTCDF0.8460.0505.86%0.840.920.860.800.8113C-2,3,7,8-TCDD0.9060.0131.41%0.910.920.910.900.892,3,7,8-TCDD1.0720.0514.80%1.101.141.061.011.05TotalTCDD1.0720.0514.80%1.101.141.061.011.OS37Cl-2,3,7,8-TCDD1.1430.0524.57%1.081.22 1.151.111.1413C-1,2,3,7,8-PeCDF0.9670.0272.83%0.970.980.960.931.001,2,3,7,8-PeCDF1.1940.0635.31%1.251.26 1.181.121.1413C-2,3,4,7,8-PeCDF0.9550.0454.69%1.010.94 0.920.911.002,3,4,7,8-PeCDF1.1730.0816.90%1.211.301.151.101.11TotalF2PeCDF1.1830.0715.98%1.23 1.281.171.111.13TotalF1PeCDF1.1830.0715.98%1.231.281.171.111.1313C-1,2,3,7,8-PeCDD0.6380.0223.49%0.630.630.610.64 0.671,2,3,7,8-PeCDD1.0030.0575.71%1.061.060.980.94 0.97TotalPeCDD1.0030.0575.71%1.061.060.980.940.9713C-1,2,3,7,8,9-HxCDD- --%13C-1,2,3,4,7,8-HxCDF0.9440.0131.38%0.940.960.920.960.941,2,3,4,7,8-HxCDF1.3730.0926.68%1.431.471.421.281.2713C-1,2,3,6,7,8-HxCDF1.2430.0846.76%1.271.251.351.221.121,2,3,6,7,8-HxCDF1.2800.0866.68%1.351.401.231.211.2213C-2,3,4,6,7,8-HxCDF1.1180.0413.67%1.131.151.161.091.062,3,4,6,7,8-HxCDF1.2800.0816.36%1.371.361.261.211.2013C-1,2,3,7,8,9-HxCDF0.9590.0495.09%0.961.001.010.930.891,2,3,7,8,9-HxCDF1.2600.0473.77%1.331.261.271.211.23G1L140412 TestAmerica West Sacramento (916) 373 - 5600 77 of 100TotalHxCDF1.2950.0715.52%1.371.37 1.281.221.2313C-1,2,3,4,7,8-HxCDD0.6570.0355.29%0.660.620.630.710.671,2,3,4,7,8-HxCDD1.1930.0927.70%1.27 1.311.161.121.1113C-1,2,3,6,7,8-HxCDD0.8420.0313.64%0.820.870.880.810.831,2,3,6,7,8-HxCDD1.1790.13011.0%1.341.301.121.071.061,2,3,7,8,9-HxCDD1.3940.16111.6%1.591.521.391.251.22TotalHxCDD1.2550.12710.2%1.401.381.221.141.1313C-1,2,3,4,6,7,8-HpCDF0.9350.0151.62%0.940.940.940.950.911.5000.1177.79%1.611.621.491.391.3813C-1,2,3,4,7,8,9-HpCDF0.7870.0182.27%0.800.760.780.810.791,2,3,4,7,8,9-HpCDF1.4040.1067.54%1.511.531.38 1.311.31TotalHpCDF1.4560.1127.69%1.571.581.441.351.3513C-1,2,3,4,6,7,8-HpCDD0.8040.0192.32%0.810.810.800.820.771,2,3,4,6,7,8-HpCDD1.0360.0434.19%1.071.091.020.991.01TotalHpCDD1.0360.0434.19%1.071.091.020.991.0113C-OCDD0.6740.0162.32%0.680.660.660.680.69OCDF1.4000.0886.31%1.471.491.421.321.30OCDD1.1400.0786.85%1.201.231.141.081.05G1L140412 TestAmerica West Sacramento (916) 373 - 5600 78 of 100

# ~':. 

# ·stAtnerlcai 

# :; ·-e

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... :

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... ··**.~**

:'THE L:EADER IN· ENVIRONME.NT.At: T.ESTJJIIG

Compound OPR VER 

### % 

### nglml CS3

16138 Acceptance Criteria .13C-Z,3,7,8-TCDF 22-152 71-140 2,3,7,8-TCDF 75- 158 8.4- 12.0 13C-2,3,7,8-TCDD 20 -175 82- 121 2,3,7,8-TCDD 67-158 7.8- 12.9 37CI4-2,3, 7,8-TCDD 31

- 191 7.9 -12.7 13C-1,2,3,7,8-PeCDF 21 -192 76 -130 1,2,3, 7,8-PeCDF 80- 134 41-60 13C-2,3,4, 7 ,8-PeCDF 13-328 77-130 2,3,4, 7;8-PeCDF 68- 160 41-61 13C-1,2,3, 7,8-PeCDD 21-227 62-160 1,2,3,7,8-PeCDD 70-142 39-65 13C-1,2,3,4, 7 ,8-HxCDF 19-202 76 -131 1,2,3,4, 7 ,8-HxCDF 72- 134 45-56 13C-1,2,3,6,7,8-HxCDF 21 -159 70-143 1,2,3,6,7,8-HxCDF 84- 130 44-57 13C-2,3,4,6,7,8-HxCDF 22-176 73-137 2,3,4,6, 7,8-HxCDF 70-156 44-57 13C-1,2,3, 7 ,8,9-HxCDF 17-205 74 -135 1,2,3,7,8,9-HxCDF 78- 130 45-56 13C-1,2,3,4,7,8-HxCDD 21

- 193 85 -117 1,2,3,4,7,8-HxCDD 70- 164 39-64 13C-1,2,3,6,7,B-HxCDD 25 -163 85 -118 1,2,3,6,7,8-HxCDD 76-134 39-64 1,2,3, 7,8,9-HxCDD 64-162 41-61 13C-1,2,3,4,6,7 ,8-HpCDF 21 -158 78 -129 1,2,3,4,6, 7 ,8-HpCDF 82- 122 45-55 13C-1,2,3,4,7,8,9-HpCDF 20-186 77-129 1,2,3,4,7,8,9-HpCDF 78- 138 43-58 13C-1,2,3,4,6,7,8-HpCDD 26-166 72-138 1,2,3,4,6,7,8-HpCDD 70-140 43-58 13C-OCDD 13 -199 96-415
OCDF 63- 170 63- 159 OCDD 78- 144 79-126

16138 Acceptance Criteria for Tetras Only Analysis

13C-2,3,7,8-TCDF 26-126 76-131 2,3,7,8-TCDF 80-147 8.6- 11.6 13C-2,3, 7,8- TCDD 25-141 85 -117 2,3,7,8-TCDD 73- 146 a.2- 12:3 37CI4-2,3, 7,8- TCDD 37-158 8.3-12.1

Q:\FORMS\Qa-HR-100 16138 criteria.x/s Page 1 of 1 

### West Sacramento Method 16138 Acceptance Criteria Based on Tables 

### 6, 6A and 

### 7 of the method

VER 

### ng/ml

CS2

71-140 1.68-2.40 82 -121 1.56-2.58 1.58-2.54 76-130 8.20-12.0

77-130 8.20-12.2

62 -160 7.80-13.0

76 -131 9.00-11.2

70-143 8.80-11.4

73-137 8.80-11.4

74 -135 9.00-11.2

85 -117 7.80-12.8

85 -118 7.80-12.8 8.20-12.2 -78-129 9.00-11.0

77 -129 8.60- 11.6

72-138 8.60- 11.6

96-415 12.60-31.8 15.80-25.2

76 -131 1.72-2.32 85 -117 1.64-2.46 1.66-2.42 VER 

### ng/ml

CS4

71-140 33.6-48 82 -121 31.2-51.6 31.6-50.8

76-130 164-240 77-130 164-244 62-160 156-260 76 -131 180-224 70-143 176-228 73-137 176-228 74-135 180-224 85 -117 156-256 85 -118 156-256 164-244

. 78-129 "180-220

77-129 172-232 72-138 172-232 96-415 252-636 316-504

76 -131 34.4-46.4

85-117 32.8-49-.2 33.2-48.4 Fteld Samples 

### nglml

24-169

25 -164

3.5-19.7 24-185

21 -178

25 -181

26-152

26-123

28-136

29--147

32 -141

28-130

28 -143

.26-138

23-140

34-313

29-140

31 -137

4.2 -16.4

QA-HR-100 06/2712011 ERSG1L140412 TestAmerica West Sacramento (916) 373 - 5600 79 of 100iile:22DE119DS#1-530Acq:22-DEC-201122:08:48GCSample#1Text:CP1222:DB-5CPSM3732-16319.8965BSUB{1000,15,-3.0)EI+VoltageSIRAutospec-UltimaEExp:DIOXINRES3.9E6953.7E6903.SE6853.3E6803.1E6752.9E6702.7E6652.5E6602.3E6552.1E6SO1.9E6451.7E6401.SE6351.4E6301.2E6259.7E5207.7ES155.8ES103.9E551.9E50O.OEO19:0619:1219:1819:2419:3019:36TimeG1L140412 TestAmerica West Sacramento (916) 373 - 5600 80 of 100 

# Test America

THE LEADER IN ENVIRONMENTAL TESTING



## MeiliodiD

______

## ~I~~'~~~~~~~e!v~~~~~-------- Column 

## ID

_____ __:;;b...;::9'""'·5=---------

STD 

## ID

______ ___,S"-\:.....;_;:1

### J-:.....;~:....7!....--------------- 

## Analyzed by

____**~~"-~.;;_er** 

### _______ _


## Std. Pkg. By**I<~** 

## Std. Pkg. Reviewed By__,_M..:....:o • .....,G

..... ·

# ~----
DAILY STANDARD PACKAGE 

### Standard, CPSM, and Solvent Blank present? Copy of log- file and Beginning Static Resolution present? CPSM blow up present? Curve Summary present? Summary of Method criteria present or**doc~ented** 

### below? Daily standard within method specified limits?· Analyte retention times correct? Isotopic ratios within limits? CPSM valley.::;: method specified limitsf•
Are chromatographic windows correct? Samples analyzed 

### within 12 hrs of daily standard? Manual reintegration's checked and hardcopies included? Ending Standard present? Ending Static Resolutions present

.-·**-··-~** 

### Absolute retention times**forx~:CI2-1,2,3,4-TCDDmd** 

### 13C12- 1,2,3,7,8,9-HxCDD are within 

## •t-t: -' vf"tne retention times in 

### the Initial Calibration? (required for all1613B samples) 

# Test America- West Sacramento

Daily Calibration Checklist Dioxin Methods

Associated ICAL

## JP,;k~ 

# \ })-O\ \ 

# <\os

Instrument 

## ID

________**~~..:::D..:::;5'** 

## ________ _

STD Solution**---~r=b.-?>~1** I_O_X-'t-...:..\

### d.:...~'--\ _____ _ 

## Date Analyzed,__

__**=IJ-__..1..;;....~** 1"'-'1:....:.1..._\

____ __


## Date Std. Pkg.**Assembled,__..~..:F).;_,..J\c;:...J.-1c;:...l:,...'...:...\** 

## ___ _
Date Std. Pkg. Reviewed 

# /1./ t 

# 1 

# U)

INITIATED REVIEWED 

# I 

# ...// j 

## ./,

.I 

# /. j 

# //·
I 

# ..t I 

# /
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# ./

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# ./ I 

# /, I 

## ./ 

## I .../**N~** 

# M

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## ~~ ./ 

### ./ 

## \ 

# ../

'---1 I£\:**0~** 

## /

## CO~NTS=--------------------------------------------------------

* Method 8290!f09/M0023A: (beginning) S 20% from curve RRFs for native analytes, S 30% from curve RRFs for labeled compounds. 

### Method 8290/T09/M0023A: (ending) S 25% from curve RRFs for native analytes, :$35% from curve RRFs for labeled compounds. 

### Method 23: See Method 23 Daily Standard Criteria, Table 5. 

### Method 16138: See, Method 16138 or Method 1613B Tetras Daily Standard Criteria, 

## ** Method 23/0023A CPSM Criteria: 25% valley between 2378 TCDF (DB-225)!fCDD (DB-5) and its closest eluters normalized to the smallest peak of the triplet

. 

### Method 1613B/8290!f09 CPSM Criteria: 25% valley between 2378 TCDF (DB-225)!fCDD (DB-5) and its closest eluters normalized to the 2378 peak.



### N:\Hires\Forms\QA-231 Dioxin Daily 

### Std Checklist.doc 

### QA-231 8/10/09 DWG1L140412 TestAmerica West Sacramento (916) 373 - 5600 81 of 100 

### Quantitation Summary TestAmerica West Sacramento Page 1 o

Run text: ST1227 Sample text: ST1227 :CS3 11DXN221 Run #6 Filename: 27DE119D5 S: 2 I: 

### 1 Results: 27DE119D5TETRAS Acquired: 27-DEC-11 05:15:55 Processed: 27-DEC-11 13:15:34 Run: 27DE119D5 Analyte: TETRAS Cal: TETRAS1220119D5 Factor 1: 20.000 Factor 2: 1.000 Sample size: 1.000000

Name Resp RA RT RRF Cone EDL Rec M



### 13C-1,2,3,4-TCDD 60582600 0.78 y 19:04 

## ./



# - 28.13 n

13C-2,3,7,8-TCDF 93849100 0.86 y 18:29 1.34 115.44 0.13 115.4 n 2,3,7,8-TCDF 9315190 0.77 y 18:30 0.85 11.73 0.21 n

13C-2,3,7,8-TCDD 55262500 0.78 y 19:16 0.91 100.69 0.25 100.7 n 2,3,7,8-TCDD 5782230 0.81 y 19:17 1.07 9.76 0.12 n

37Cl-2,3,7,8-TCDD 6695060 1.00 y 19:17 1.14 9.67 0.08 96.7 nG1L140412 TestAmerica West Sacramento (916) 373 - 5600 82 of 100 

### Data file Smp Work Order Sample ID FV-uL 

### Method/Matrix Box Size 

## u

27DE119D5 1 CPJ.227 DB-5 CPSM 3732-16 1.00000 27DE119D5 2 ST1227 CS3 11DXN221 1. 

### 00000 27DE119D5 3 Needle "Z"ed 0.00000 27DE119D5 4 CPJ.227A DB-5 CPSM 3732-16 1.00000 27DE119D5 5 MPVQL-1-AAB G1L220000-070B(431-1MB) 20 16131;1-T/WATER 63 1.00000 L 27DE119D5 6 MPND6-1-AA G1L140412-1 20 1613B-T/WATER 62 1.02131 L 27DE119D5 7 SBJ.227 Solvent Blank C-14 1.00000 27DE119D5 8 

### MPPRM-1-AA G1L160409-1 20 1613B-T/WATER 62 1.04247 L 27DE119D5 9 MPRP9-1-AA G1L190431-1 20 1613B-T/WATER 63 1. 

### 02577 L 27DE119D5 10 MPVQL-1-ACC G1L220000-070C(431-1LCS) 20 1613B-T/WATER 1.00000 L 27DE119D5 11 MPVQL-1-ADL G1L220000-070L(431-1DCS) 20 1613B-T/WATER 1.00000 L 27DE119D5 12 1.00000 27DE119D5 13 1.00000 27DE119D5 14 1.00000 27DE119D5 15 MG,KSS 12/27/11

## J'~ 1.00000 

## l**~~.u.-**



# 0 ,,_,')'1**\'~9**G1L140412 TestAmerica West Sacramento (916) 373 - 5600 83 of 100 

### Data file Smp Work Order Sample ID FV-uL 

### Method/Matrix Box Size 

## u

27DE119D5 1 CP1227 DB-5 CPSM 3732-16 1.00000 27DE119D5 2 ST1227 

### CS3 l.lDXN22l. l..OOOOO 27DEl.l.9D5 3 Needle "Z"ed 0.00000 27DEl.l.9D5 4 CPl.227A DB-5 CPSM 3732-16 1.00000 27DEl.19D5 5 MPVQL-l.-AAB Gl.L220000-070B(43l.-l.MB) 20 l.6l.3B-T/WATER 63 l..OOOOO L 27DEl.19D5 6 MPND6-l.-AA Gl.Ll.404l.2-l 20 l.6l.3B-T/WATER 62 l.. 

### 02131 L 27DEl.19D5 7 SBl.227 Solvent Blank C-14 l.. 

### 00000 27DEl.l.9D5 8 

### MPPRM-l.-AA G1L160409-l 20 l.613B-T/WATER 62 l.. 

### 04247 L 27DE119D5 9 MPRP9-1-AA G1L190431-l 20 l.613B-T/WATER 63 1. 02577 L 27DE119D5 10 MPVQL-1-ACC G1L220000-070C(431-1LCS) 20 1613B-T/WATER 1.00000 L 27DE119D5 11 MPVQL-l.-ADL G1L220000-070L(431-l.DCS) 20 1613B-T/WATER 1.00000 L 27DE119D5 12 l.. 

### 00000 27DE119D5 13 1.00000 27DE119D5 14 1.00000 27DEl.19D5 15 MG,KSS 12/27/H 

# J'o 1.00000 

## l**~\,t.,**

## 0~ 

# • ,,.\l-1**\'~9**G1L140412 TestAmerica West Sacramento (916) 373 - 5600 84 of 100PPM200......fr\lr'lI'\292.98245PPM200.....I'\(liJ·\342.97925PPM20097604PeakLocateExamination:27-DEC-2011:04:29File:27DE119D5Experiment:DIOXINRESFunction:lReference:PFKVoltsPPMVoltsPPMVolts!PPM1.3110200......0.2330200,_.0.1058'200ll.l'r..l)\304.98245Jrl318.97925EVoltsPPMVoltsPPMVoltsPPM0.4401200......0.1562200.....0.1033200rl'..,i)'354.97925--_366.97925VoltsPPMVoltsPPMVolts0.19052000.1376200o-+0.0727-------404._9_7604416.97604Volts0.38043.3.0.97925Volts0.2089380.976Q_4G1L140412 TestAmerica West Sacramento (916) 373 - 5600 85 of 100PPM200-""'PPM200IIPPM200IPeakLocateExamination:27-DEC-2011:13:21File:27DE119D5ENDRESExperiment:DIOXINRESFunction:1Reference:PFKVoltsPPMVoltsPPMVoltsPPM......0.33682000.17932000.0805200IV{\jjI\292.98245_304_.98245318.97925VoltsPPMVoltsPPMVoltsPPM......0.4006200......0.1393200......0.0965200I342.97925354.97925366.97925VoltsPPMVoltsPPMVolts......0.16762000.1353200......0.0751INIJl392.976_Qi_404.97604416.97604Volts0.3398330.97925Volts0.1761380.97604G1L140412 TestAmerica West Sacramento (916) 373 - 5600 86 of 100Page1of1Run:27DE119D5I.Analyte:TETRASCal:TETRAS1220119D58T1220B:C8-111DXN2198T1220A:C8-211DXN2208T1220:C8-311DXN2218T1220D:C8-411DXN2228T1220C:C8-511DXN22320DE119D520DE119D520DE119D520DE119D520DE119D584838286 85NameMean8.D.%R8DRRF1RRF2RRF3RRF4 RRF513C-1,2,3,4-TCDD---%13C-2,3,7,8-TCDF1.3420.0302.27%1.351.381.361.311.312,3,7,8-TCDF0.8460.0505.86%0.840.920.860.800.8113C-2,3,7,8-TCDD0.9060.0131.41%0.910.920.910.900.892,3,7,8-TCDD1.0720.0514.80%1.101.141.061.011.0537Cl-2,3,7,8-TCDD1.1430.0524.57%1.081.22 1.151.111.14G1L140412 TestAmerica West Sacramento (916) 373 - 5600 87 of 100

## ~':. 

# ·st··t·A ·· · · ·•-- ··. ·**~:•··e** 

# . ...-.· om.ert.CO

:'THE LEADER IN· ENVIRONME.NIAt." T.ESTJiiiG

Compound 

### OPR 

## VER % 

### ng/ml CS3

16138 Acceptance Criteria .13C-Z,3,7,8-TCDF 22-152 71-140 2,3,7,8-TCDF 75-158 8.4- 12.0 13C-2,3,7,8-TCDD 20-175 82 -121 2,3,7,8-TCDD 67- 158 7.8-12.9 37CI4-2,3, 7,8- TCDD 31

- 191 7.9 -12.7 13C-1,2,3,7,8-PeCDF 21

- 192 76-130 1,2,3,7,8-PeCDF 80- 134 41 -60 13C-2,3,4, 7,8-PeCDF 13-328 77-130 2,3,4, 7,8-PeCDF 68- 160 41-61 13C-1,2,3, 7 ,8-PeCDD 21-227 62-160 1,2,3,7,8-PeCDD 70-142 39-65 13C-1,2,3,4,7,8-HxCDF 19-202 76 -131 1,2,3,4, 7 ,8-HxCDF 72- 134 45-56 13C-1,2,3,6,7,8-HxCDF 21 -159 70 -143 1,2,3,6,7,8-HxCDF 84-130 44-57 13C-2,3,4,6,7 ,8-HxCDF 22-176 73 -137 2,3,4,6,7,8-HxCDF 70·- 156 44-57 13C-1,2,3,7,8,9-HxCDF 17-205 74-135 1,2,3,7,8,9-HxCDF 78- 130 45-56 13C-1 ,2,3,4,7,8-HxCDD 21 -193 85 -117 1,2,3,4,7,8-HxCDD 70- 164 39-64 13C-1,2,3,6,7,S-HxCDD 25-163 85 -118 1,2,3,6,7 ,8-HxCDD 76-134 39-64 1,2,3, 7,8,9-HxCDD 64- 162 41-61 13C-1 ,2,3,4,6,7 ,8-HpCDF 21 -158 78 -129 1,2,3,4,6,7 ,8-HpCDF 82-122 45-55 13C-1 ,2,3,4, 7,8,9-HpCDF 20-186 77-129 1,2,3,4, 7 ,8,9-HpCDF 78-138 43-58 13C-1 ,2,3,4,6,7,8-HpCDD 26 -166 72 -138 1,2,3,4,6, 7 ,8-HpCDD 70- 140 43-58 13C-OCDD 13 -199 96-415 OCDF 63- 170 63-159 OCDD 78- 144 79- 126

16138 Acceptance Criteria for Tetras Only Analysis

13C-2,3,7,8-TCDF 26-126 76 -131 2,3,7,8-TCDF 80- 147 8.6-11.6 13C-2,3, 7,8- TCDD 25 -141 85 -117 2,3,7,8-TCDD 73- 146 8.2-12:3 37CI4-2,3, 7,8-TCDD 37-158 8.3 -12.1

Q:IFORMS\Qa-HR-100 16138 criteria.xls 

### · Page-1 of 

### 1 

### West Sacramento Method 16138 Acceptance Criteria Based on Tables 6, 6A and 7 of the method



## VER ng/ml CS2

71-140 1.68-2.40 82 -121 1.56-2.58 1.58-2.54 76-130 8.20-12.0

77-130 8.20- 12.2

62 -160 7.80-13.0

76 -131 9.00-11.2

70-143 8.80- 11.4 73-137 8.80- 11.4

74-135 9.00-11.2

85-117 7.80-12.8

85 -118 7.80-12.8 8.20- 12.2 -18-129 9.00-11.0

77-129 8.60- 11.6

72-138 8.60- 11.6

96-415 12.60-31.8 15.80-25.2

76 -131 1.72-2.32 85 -117 1.64-2.46 1.66-2.42 

## VER ng/ml

CS4

71-140 33.6-48 82 -121 31.2-51.6 31.6-50.8

76-130 164-240 77-130 164-244 62-160 156- 26() 76 -131 180-224 70-143 176-228 73-137 176-228 74-135 180-224 85 -117 156-256 85 -118 156-256 164-244

.. 78-129 "180-220

77-129 172-232 72-138 172- 232" 96-415 252-636 316-504

76 -131 34.4-46.4

85-117 32.8-49-.2 33.2-48.4 Field Samples 

### ng/ml

24-169

Z5 -164

3.5-19.7 24-185

21 -178

25 -181

26-152

26-123

28-136

29--147

32- 141

28 -130

28-143

.26-138

23-140

34-313

29-140

31 -137

4.2 -16.4

QA-HR-100 0612712011 ERSG1L140412 TestAmerica West Sacramento (916) 373 - 5600 88 of 100File:27DE119D5#1-530Acq:27-DEC-201106:41:37GCEI+VoltageSIRAutospec-UltimaESample#4Text:CP1227A:DB-5CPSM3732-16Exp:DIOXINRES319.8965S:4BSUB(l28,15,-3.0)1001.6E6951.5E6901.4E6851.3E6801.2E6751.2E6701.1E665l.OE6609.3E5558.5E5507.8E5457.0E5406.2E5352,3,7,8-TCDD5.4E5304.7E5253.9E5203.1E5152.3E5101.6E557.8E40O.OEO19:bo19:0619:1219:1819:19:3019:36TimeG1L140412 TestAmerica West Sacramento (916) 373 - 5600 89 of 100 

# Sample Extraction/Preparation Log Copies and ChecklistsG1L140412 TestAmerica West Sacramento (916) 373 - 5600 90 of 100TestAmericaWestSacramentoHighResolutionPrepLogDioxin/FuranWWExtractionInternalCOC:rlDeliveredtolnst.:ItlnstReceipt:Method:L 11613B-TetrasMatrix:IWATERBatch:1355069MSRun#:PrepDate:12121/2011Box#{pLExtraction:DBEXTRACTION:SoxhletandSepFunnelQC:01STANDARDTESTSETSAC:L1-I-DB-01)SZ6)'tlSZJExtractionTableSharedAI)QCBatch:_=-J..;..Jifll....;..;.__,.:SharesQCWith:!,/.1,v-!C!PrepReaaentsJReagentSupplierLot#DCMBakerTolueneBakerK"2."-tNS""<lHexaneBaker_ti0E04-H2S04Baker1\Jf.l20%DCM:HexaneNA'-fDU-32(_65%DCM:HexaneNAl1()2Z--32B1:1DCM:CyclohexaneNAI'JA75:20:5NAtJtl--DCM:Hexane:BenzeneSilicaGellwl1aA..nu1lt.fDLz-3:xrAcidAluminaIMPf?J[;u1Ci5%Carbon:SilicaGeltJlLtJASampleIDSuffWorkOrderExtractionHoldSamplesizeBottle+SampleEmptyBottleRnalVolumeAnalysisHoldSox/ExtAQExtRBRotovapTimeExpires*WeightWeight2ouLOtherTimeExpires11DIDIDIDG1L140412-,MPND61AA12111120121,t,tn,zq"v\113ot2o12'2..\.JzG1L140420-1MPNEW1AA1217/2012I.IJ.O/'326,.0\()\1/30/20127G1L160409-1MPPRM1AA12/8/2012G.'·{'..t/s-3?./\1L,\1130/2012/INA8G1L210000-69BMPT231AA12/8/2012Y}').,QA·'\.2/z"b/ll1/30/2012/\?.'ZZ,.GJL210000-69cMPT231AC12/8/2012,c)/\/\/\\.\1/30/2012l./"Z._S'""7G1l210ooo-69LMPT231AD12/8/2012t.ntt)1\n1\1n.,\1/30/2012,,-......;.-,;·<.•..;40:\FORMS\QA-546ATGLogDioxin_WWEE.xlsBatch:1355069Page1of212121/201110:28:12AMQA-5463/5/2010MAFG1L140412 TestAmerica West Sacramento (916) 373 - 5600 91 of 100•Seeattachedsheetforsamplevolumesrecordedfromscale-------------------------------------------------------------------------------------------------------------------------InternalStandardAllSamplesSpikeMixLCS/LCSD/MS/MS1v1,y1,I,-1--r zl1LiqLiqExtractionAnalyst/DateSoxhletExtractionAnalyst/DateOptionCAnalyst/DateWitnessedBy:-Tf-IIFBI )D2Analyst/DateAnalyst/DateI-ll--][ioHt:fjttll-IQ:\FORMS\QA-546ATGLogDioxln_WWEE.xlsBatch:1355069Page2of212/21/201110:28:12AMDate:.--,QA-5463/5/2010MAFG1L140412 TestAmerica West Sacramento (916) 373 - 5600 92 of 100 

# TestAmerica West Sacramento 

# Test America

Data Checklist HRGCMS/LRGCMS Analyses

Batch#: 1355069 

### THE LEADER IN 

### ENVIRONMENTAL TESTiNG


## Method ID: Dioxins/Furans, HRGC/HRMS (16138-Tetras Only



### DB-5 Data Analyst: 

## a 5 Date initiated: L?

- 

## zs 11 

### Reviewer:

### ~ Date reviewed:

## ----+0""'~(**u~fr-:.:lf:..__** 

# ___ _ QAJQC verification:

-Daily standard package(s) present? -Method Blank present? -LCS/DCS copy present and meets native

recovery criteria? -Internal standard recoveries within limits?* -lon ratios within 

## + 15% of theoretical values? -Other QC (Dup,MS;SD) within specs?** 

## Sample Analysis:

-Correct sample aliquot used? -All raw data present? -Standard target DL's used? If RL's are used

specify: -DL's belo_w.,@lS.......:,.-/-L_C_L_(_pl-e-as_e_c-ir-c-le-)?--
-AII positives reported at levels

greater than method blank DL's? -Correct RRF's used for method? -Internal standard amounts correct

for method? -Target analytes are not saturated? -Dilution/splitting of extract taken into account? -Have dilution calculations been verified? -Has a manual calculation for the sequence(s)

been verified? ' -Are retention times {RT) correct? -Manual integrations checked? Comments: (Use other side if necessary)

* Recovery limits: NCASI551: 40-120%*** Method 8290: 40-135%*** Method 1613: 25-150%*** 

### DB-225



## Initiated Reviewed DB-5 DB-5**~** 

## ----L- ,£--- 

### _L**~** 

### ./**~ ~**  

# --;;;-**~**

### ~ __JdA..



## Initiated Reviewed DB-5 DB-5 

# 7 __£_ ,/

.;&---- 

# 2**~**


### -,£-- 

## _L tL-- --...c..-

,L-- ,/'**~** 

### .L_ Ja_ 

# J1L eta_**~**
L__ .,/' 

# L- 

# -r JJL_**~**

Method 23: 40-130o/o***(CI4-CI6), 25-130o/o(C17-B), 70-130o/o(surr.) PCBs: 25-150% *** Method 8280: 40-120%*** DFLM01.0: 25-150% *** Method 1614 25-150%***

••• Lower recoveries are acceptable if I.S. SIN ;::.10:1 and DL's are <LCL for target analytes. 

## Initiated Reviewed DB-225 DB-225 (High Res Only) (High Res Only)



## Initiated Reviewed DB-225 DB-225 (High Res Only) (High Res Only)

**RPD limits: 50% 20% 50% 50% 50%

QA-371 07/99 MAFG1L140412 TestAmerica West Sacramento (916) 373 - 5600 93 of 100...RQCOS8LEV--rLEV--rTestAmericaLaboratories,Inc.EXTRACTIONBENCHWORKSHEETRunDate:12/22/11Time:12:17:32LEV-ryyBlankCheckMS/MSDLEV-ryyyyWeights/VolumesSpike&SurrogateWorksheetV1alcontainscorrectvolumeLabels,greenbars,worksheetscomputercorrect&allmatchyExpandedDeliverablecocCompletedBenchSheetCopied_ _AnomaliestoExtractionMethod***************************QCBATCH:1355069*PackageSubmittedtoAnalyticalGroup·BenchSheetCopiedperCOCExtractionist:403613BrentGinnConcentrationist:00662SElizabethNguyenReviewer/Date:NGUYENEI12/22/11EXTREXPRANLLOT#,MSRUN#/DUEWORKORDERTESTFLGSG1L140412-00112/11/12 12/29/11MPND6-1-AADCOMMENTS:G1L140420-00112/07/12 12/30/11MPNEW-1-AACOMMENTS:G1L160409-00112/08/12 12/30/11MPPRM-1-AADCOMMENTS:G1L210000-06912/08/120/00/00MPT23-1-AABCOMMENTS:G1L210000-06912/08/120/00/00MPT23-1-ACCCOMMENTS:G1L210000-06912/08/120/00/00MPT23-1-ADLCOMMENTS:RUSHC=CLPREXT·MTHMATR'!I:XDBL1WATERDBL1WATERDBL1WATERDBL1WATERDBL1WATERDBL1WATER**************************PREPDATE:12/21/119:00COMPDATE:12/22/111S:OODioxins/Furans,HRGC/HRMS(1613B-TetrasOnly)EXTRACTION:SoxhletandSepFwmelINIT/FINPH"SSOLVENTSWT/VOLINITJrnJ'TADJ2EXTRACTION'-voV-EXCHhNGESPIKESTANDARD/VOL·§.URROGATEID1021.31mLNANANADCM/TOL300.0C-1420.020.00uL1.0MLIS11DXN340941.0mLNANANADCM/TOL300.0C-1420.00uL20.01.OMLIS11DXN3401042.47mLNANANADCM/TOL300.0C-1420.020.00uL1.0MLIS11DXN3401000.0mLNANANADCM/TOL300.0C-1420.020.00uL1.0MLIS11DXN3401000.0mLNANANADCM/TOL300.0C-1420.0SOULNS11DXN26420.00uL1.0MLIS11DXN3401000.0mLNANANADCM/TOL300.0C-1420.0SOULNS11DXN26420.00uL1.0MLIS11DXN340REMEPA600D=EXP.DEL)CLIENTREQMS/MSDNUMBEROFWORKORDERSINBATCH:6'G1L140412 TestAmerica West Sacramento (916) 373 - 5600 94 of 100 

# Test America

THE LEADER IN ENVIRONMENTAL TESTING

## We~t 

## Sacramento
Preparation' Data Review Checklist

Prep Batch1es)

# ~~,**.~I'J** 

# b 

# q Test: 

# It 13t/3 L
._ Prep.Date: 

# J1 "2J r_u_ Holding Times: 

## }1.. 

# f:1 't'l- 

## NCM:

# y~ { 

# ,. "" Ill '1'2. \. '------""'



### A. Spike Witness/Batch setup Spike Reviewer Witness 

### 1. Holding times checked? NCMs filed as appropriate / 

# V' 2. QAS checked for QC instructions (LCS, LCSD, MS,MSD, etc) 

# ' v
3. Amount of samples in hood match amount of samples on bench 

# ,.- NA sheet. Sample IDS match. 4. Worksheets have been checked for required spiking 

# rcompounds 

# v
5. Spiking volumes are correctly documented 

### / .,/ 

### 6. Std ID numbers on spike labels match numbers on bench sheet 

## r NA
7. Expiration dates have been checked r 

# r 

# v 8. Calibration expiration dates on pipettors have been checked: ,;""" 

### NA 

## 9. Spiker and spike witness have signed and dated bench sheet / 

# \/"'
B. Weights and Volumes 

### 1. Recorded weights are in anticipated range NA 

## ./ 2. Balance upload or raw data for weights is included NA 

## v" 3. Weights and volumes have been transcribed correctly to LIMS. NA 

### v'
4. Weights are not targeted to meet exact weights. NA ,/


### 5. Each weight or volume measurement is a unique record (no NA dittos or line downs) 

## ./ C. Standards and Reagents 

### 1. Lot numbers for all reagents, including clean up stages, are NA recorded. 

# v 2. Are dates and analysts for cleanups recorded? NA 

# ./
3. Are correct IDs used for standards? Are expiration dates to NA 

# / day/month/year, when listed? D. Documentation 

### 1. Are all nonconformances documented appropriately? NA**~** 

## 2. QuantiMs entry correct, including dates and times. NA 

# "' 3. Are all fields completed? 

# . NA 

# v ' I



### Spike witness:

# l2~l~**Date:~** 

# tz 

# hi/;;

.

# f•z.l~~M 2"d Level Reviewer: 

# fYi, t)U 

### Date::



# . Comments:

q:\forms\checklists\qa-588 prep_review.doc 

### QA-588 Revised 1213012008 ERSG1L140412 TestAmerica West Sacramento (916) 373 - 5600 95 of 100 

# Shipping and Receiving DocumentsG1L140412 TestAmerica West Sacramento (916) 373 - 5600 96 of 100WestSacramento880RiversideParkwayTestAmericaChainofCustodyRecord...WestSacramento,CA95605phone916.374.4378fax916.372.1059TestAmericaLaboratories,Inc.ProjectManager:Solutia-MikeHouse/Potesta-COCNo:ClientContactMikeLightSiteContact:LisaSullivanDate:/:J.-1;;{-l.JPotesta&Assoc.,Inc.Tel/Fax:LabContact:LidyaGuliziaCarrier:FedEx___Lof____j____COCs7012MacCorkleAve.,SEAnalysisTurnaroundTimeJobNo.Charleston/WV/25304Calendar(C)orWorkDays(W)C(304)342-1400PhoneTATifdifTerentfromBelowStandard(304)343-9031FAX2weeksSDGNo.ProjectName:Solutia-ACLFAnnualProcessWaterSampleD1weekc:Site:Nitro,WVD2days..!!QP0#97-0010-009AD1day0B1SampleSampleSample#of::;,..:SampleIdentificationDateTimeTypeMatrixCont.::fSampleSpecificNotes:OutletOIIt1JS5GrabH202 XPreservationUsed:I=Ice,2=HCI:3=H2S04;4=HN03;S=NaOH;6=OtherPossibleHawrdIdentificationSampleDisposal(Afeemaeassessedifsamplesareretainedlongerthan1month)DNon-HazardDDSkinIrritantPoisonBDUnknownDDReturnToClientByLabDArchiveForMonthsSpeciallnstructions/QCRequirements&Comments:LeveI'[Jf'QAQcII_:II_:Receivedby:Company:Date/Time1A\)Company:rDate/TiMe:Receivedby:Company:Date/Time:I\.____);""\h.-.\-rr-N.\"JtotYnnRclinqehedby:Company:Dateffime:Receivedby:Company:Dateffime:-----------'eCG1L140412 TestAmerica West Sacramento (916) 373 - 5600 97 of 100 

# Test America LOT RECEIPT CHECKLIST TestAmerica West Sacramento

THE LEADER IN ENVIRONMENTAL TESTING



### CLIENT

_______ 

## P_O_T_E_S_T_A

______ _ JK PM,

___ _
LOT# (QUANTIMS ID)

____ 

### G_1 L_1_4_0_4_1_2

___ QUOTE#

___ 

### 5_0_59_3

___ LOCATION 

### W25C Checked ( ..!') DATE RECEIVED

___ 

### 121_1_31_1_1

__ TIME RECEIVED

____ 

### 09_1_5

___ _
DELIVERED BY 

## Ill FEDEX
0 GOLDENSTATE 0 UPS

0 iAL COURIER 0 TAL SF
SHIPPPING CONTAINER(S) 00NTRAC
0 EZ PARCEL 

# D CLIENT

0 TAL 

## Ill CLIENT OOTHER

ON/A 

# Ill

MULIT-COOLER(S) (If checked see multi-cooler form) 

# D

SINGLE COOLER INFORMATION N/A
CUSTODY SEAL STATUS 

## Ill INTACT 

## 0 BROKEN 0 N/A 

# D Ill

CUSTODY SEAL #(S) 

### ---------9_7_4_0_44

________ _ COC#(S)

___________ 

# N_A

__________ __ 

# D Ill

TEMPERATURE BLANK Observed:.

___ 

## O

___ Corrected:.

___ 

## 1;..._

__ SAMPLE TEMPERATURE -(TEMPERATURES ARE IN °C)
Observed: 

### 1' 1 • 1 Average 

### 1 Corrected Average LABORATORY THERMOMETER ID:

·------- 

### 1

IR UNIT: #4 

## 0 #Sill 

## 0 OTHER.

______ _ 

# D

JK 12/13/11
Initials Date



## ========================================================================================= pH MEASURED 0 YES 0 ANOMALY 

# eJ N/A LABELED BY.......................................................................................... 

## JS 

# JS LOGGED IN BY

....................................................................................... ___ _
SHORT HOLD TEST NOTIFICATION SAMPLE RECEIVING WETCHEM 

# IZJ N/A VOA-ENCORES 

# Ill N/A

0 METALS NOTIFIED OF FILTER/PRESERVE VIA VERBAL & 

### EMAIL 

# IZJ N/A 

# eJ COMPLETE SHIPMENT RECEIVED IN GOOD CONDITION WITH 0 N/A APPROPRIATE TEMPERATURES, CONTAINERS, PRESERVATIVES

0 CLOUSEAU 0 TEMPERATURE EXCEEDED (0 

# oc- 6 °C). 1 

## 0 N/A 

# Ill WET ICE 0 BLUE ICE 

# 0 GEL PACK 0 NO COOLING AGENTS USED



### JK Initials 

### 12/13/11
Date Notes.

________________________________________________ __

•1 Acceptable temperature range for State of Wisconsin samples is .s.4•C.

QA-185 10/09 RKE, Page 1G1L140412 TestAmerica West Sacramento (916) 373 - 5600 98 of 100 

# Test America Bottle Lot Inventory

Lot THE LEADER IN ENVIRONMENTAL TESTING 

### ID:

________ 

### G_1_L_14_0_4_12

______ _

1 2 3 4 5 6 7 8 9 10 11 12 VOA*
VOAh* VOAmeoh
AGB 2 

### AGBs
250AGB
250AGBs 250AGBn
500AGB AGJ 500AGJ 250AGJ
125AGJ

125AGJmeoh


### CGJ



## -- 500CGJ
250CGJ
125CGJ
PJ
PJn
500PJ
500PJn
500PJna
500PJzn/na
250PJ
250PJn
250PJna
250PJzn/na

Acetate Tube



### __ "CT
Encore
Folder/filter
PUF
Petri/Filter
XAD Trap Ziploc

1 2 3 4 5 

### 6 7 8 9 10 11 12 

### h 

## = hydrochloric acid s 

# = sulfuric acid na 

# = sodium hydroxide n 

# = nitric acid
Number of VOAs with air bubbles present 

### I total number of VOA's 13 14 15 16 17 18 19 20

13 14 15 16 17 18 19 20



### zn = 

### zinc acetate

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