From: Mullins, Gladys K [mailto:Gladys.K.Mullins@wv.gov] 

Sent: Monday, February 25, 2013 11:45 AM 

To: Elizabeth Sabol; DEP FOIA; Ombler, Tonya K 

Cc: Mullins, Gladys K 

Subject: FW: 2013-01-127 - Elizabeth Sabol - January 28, 2013 

Please see attach information you requested.  If you need anything else please let me know.

From: Chaney, David L 

Sent: Tuesday, February 05, 2013 3:20 PM 

To: Mullins, Gladys K 

Subject: RE: 2013-01-127 – Elizabeth Sabol – January 28, 2013 

Attached is the information the FOIA is requesting the Armour Creek Landfill (Solutia Inc.) for the

manganese the unit is wrong it should be ug/l see attached PDF report for 9/11 page 7 of 23 for Outlet

011.  I have also attached the PDF TestAmerica Analytical Report for 12/2011 concerning Outfall 011 for 

2,3,7,8-Tetrachlorodibenzo-p-dioxin for the concentration information. 

David L. Chaney

Geologist III

WV DEP

254 Industrial Drive  

Oak Hill, WV 25901

304‐465‐1919 Ext. 3053

From: DEP FOIA 

Sent: Monday, January 28, 2013 11:33 AM 

To: Ombler, Tonya K 

Cc: Kozak, Peggy J 

Subject: 2013-01-127 – Elizabeth Sabol – January 28, 2013 

2013‐01‐127 – Elizabeth Sabol – January 28, 2013

Re:      Freedom of Information Act (FOIA) Request #2013‐01‐127

Attached, please find a FOIA from Elizabeth Sabol with Eastern Research Group.  

Please contact the requester at Elizabeth.sabol@erg.com to let them know whether or

not you have the requested information and when they can view/copy/receive it.  

Please reference the above FOIA number and respond to depfoia@wv.gov with the

amount invoiced and your mail code when complete.

Sarah Alford

Ext. 1641
From: Elizabeth Sabol [mailto:Elizabeth.Sabol@erg.com] 

Sent: Monday, January 28, 2013 10:46 AM 

To: DEP FOIA 

Cc: swietlik.william@epa.gov; Eleanor Codding; Kim Wagoner 

Subject: 2011 DMR Data Request - WV DEP 

Ms. Hoskins/Ms. Kozak, 

 

EPA is requesting 2011 DMR data for two West Virginia facilities: Elkem Metals Company, in Alloy, WV 

(WV0000167) and Armour Creek Landfill, in Nitro, WV (WV0077020). I am writing to request clarification 

for these two facilities on behalf of EPA under Contract No. EP-C-12-021. Please see below for further 

background. 

 

EPA, Office of Water (OW), reviews DMR data to fulfill its review obligation under Section 304(b) of the 

Clean Water Act. The CWA requires EPA to annually review and, if appropriate, revise its water pollution 

control technology-based regulations, called "effluent limitations guidelines" or "effluent guidelines," that 

limit the discharge of pollutants to waters of the U.S. from various categories of industrial facilities. EPA is 

currently conducting its 2013 annual review of existing effluent guidelines and potential industrial 

guidelines which may need to be included (see http://www.epa.gov/guide/304m/ for further 

information). EPA will discuss this review and the results in its 2013 Effluent Guidelines Program Plan 

scheduled for publication in the Federal Register sometime in 2013 or 2014. 

 

As part of the 2013 annual review, EPA is evaluating 2011 DMR data and needs further information to 

complete the review. Specifically, we would like to clarify the following for the two facilities: 

 

(1) Elkem Metals Company, in Alloy, WV (WV0000167) 

- Confirm 2011 flow values and units for Outfalls 002, 004, 005, and 007. 

- Confirm 2011 concentration values and units for Outfalls 002, 004, 005, and 007 for the following 

pollutants: cadmium, lead, selenium, arsenic, hexavalent chromium, nickel, chromium, trivalent 

chromium, vanadium, antimony, and aluminum. 

 

(2) Armour Creek Landfill, in Nitro, WV (WV0077020) 

- Confirm Outfall 011, 2011 2,3,7,8-Tetrachlorodibenzo-p-dioxin concentration, specifically the below 

detection indicator. 

- Confirm Outfall 011, manganese concentration for September 2011. 

 

If you have any questions about EPA's request, please contact me directly at 610-344-0829. If you would 

like to speak directly with EPA regarding this request, you can contact William F. Swietlik of EPA's Office 

of Water/Engineering Analysis Division by phone at (202) 566-1129 or by email: 

swietlik.william@epa.gov. 

 

Thank you, 

Elizabeth 

 

Elizabeth A. Sabol 

Environmental Engineer 

Eastern Research Group, Inc. 

14555 Avion Parkway, Suite 200 

Chantilly, VA 20151 

elizabeth.sabol@erg.com
ANALYTICAL REPORT

TestAmerica Laboratories, Inc.

TestAmerica Savannah

5102 LaRoche Avenue

Savannah, GA 31404

Tel:(912)354-7858

TestAmerica Job ID: 680-72273-2

Client Project/Site: ACLF - Outlet 011 Monthly - SEP 2011

For:

Potesta & Associates

7012 MacCorkle Avenue, S.E.

Charleston, West Virginia 25304

Attn: Mr. Mike Light

Authorized for release by:

09/27/2011 03:32:48 PM

Lidya Gulizia

Project Manager II

lidya.gulizia@testamericainc.com

cc: Lisa Sullivan

Results relate only to the items tested and the sample(s) as received by the laboratory.

The test results in this report meet all 2003 NELAC and 2009 TNI requirements for accredited

parameters, exceptions are noted in this report. This report may not be reproduced except

in full, and with written approval from the laboratory. For questions please contact

the Project Manager at the e-mail address or telephone number listed on this page.

This report has been electronically signed and authorized by the signatory. Electronic signature

is intended to be the legally binding equivalent of a traditionally handwritten signature.

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Table of Contents

Client: Potesta & Associates

Project/Site: ACLF - Outlet 011 Monthly - SEP 2011

TestAmerica Job ID: 680-72273-2

Page 2 of 23

Cover Page . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1

Table of Contents . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2

Case Narrative . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3

Sample Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4

Method Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5

Definitions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6

Client Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7

Surrogate Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 10

QC Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 11

QC Association . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 18

Chronicle . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 20

Chain of Custody . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 21

Receipt Checklists . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 22

Certification Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 23

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Case Narrative

Client: Potesta & Associates TestAmerica Job ID: 680-72273-2

Project/Site: ACLF - Outlet 011 Monthly - SEP 2011

Job ID: 680-72273-2

Laboratory: TestAmerica Savannah

Narrative

Job Narrative

680-72273-2

Receipt 

All samples were received in good condition within temperature requirements.

GC/MS VOA 

No analytical or quality issues were noted.

GC/MS Semi VOA 

Method(s) 625: The %RPD of laboratory control standard duplicate (LCSD) for preparation batch 214813 exceeded control limits. The 

results have been flagged and data reported. 

Method(s) 625: The laboratory control sample (LCS), the laboratory control sample duplicate (LCSD), matrix spike, and matrix spike dupe 

(MSD) for batch 214813 exceeded control limits in the acid fraction for the following analytes: 2,4 dimethylphenol. This compound is within 

control limits in the base portion.

Method(s) 625: The following sample(s) contained one acid and/or one base surrogate outside acceptance limits: Outlet 011 

(680-72273-3). The laboratory's SOP allows one acid surrogate and/or one base surrogate to be outside acceptance limits; therefore, 

re-extraction/re-analysis was not performed. These results have been reported and qualified.

No other analytical or quality issues were noted.

Metals 

No analytical or quality issues were noted.

General Chemistry 

No analytical or quality issues were noted.

Comments

No additional comments. 

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Sample Summary

Client: Potesta & Associates TestAmerica Job ID: 680-72273-2

Project/Site: ACLF - Outlet 011 Monthly - SEP 2011

Lab Sample ID Client Sample ID Matrix Collected Received

680-72273-3 Outlet 011 Water 09/12/11 11:15 09/13/11 09:30

680-72273-4 Trip Blank Water 09/12/11 00:00 09/13/11 09:30

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Method Summary

Client: Potesta & Associates TestAmerica Job ID: 680-72273-2

Project/Site: ACLF - Outlet 011 Monthly - SEP 2011

Method Method Description Protocol Laboratory

624 Volatile Organic Compounds (GC/MS) 40CFR136A TAL SAV

625 Semivolatile Organic Compounds (GC/MS) 40CFR136A TAL SAV

200.7 Rev 4.4 Metals (ICP) 40CFR136A TAL SAV

420.1 Phenolics, Total Recoverable MCAWW TAL SAV

SM 2540D Solids, Total Suspended (TSS) SM TAL SAV

SM 4500 Cl- E Chloride, Total SM TAL SAV

SM 4500 H+ B pH SM TAL SAV

Protocol References:

40CFR136A = "Methods for Organic Chemical Analysis of Municipal Industrial Wastewater", 40CFR, Part 136, Appendix A, October 26, 1984 and 

subsequent revisions.

MCAWW = "Methods For Chemical Analysis Of Water And Wastes", EPA-600/4-79-020, March 1983 And Subsequent Revisions.

SM = "Standard Methods For The Examination Of Water And Wastewater",

Laboratory References:

TAL SAV = TestAmerica Savannah, 5102 LaRoche Avenue, Savannah, GA 31404, TEL (912)354-7858

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Definitions/Glossary

Client: Potesta & Associates TestAmerica Job ID: 680-72273-2

Project/Site: ACLF - Outlet 011 Monthly - SEP 2011

Qualifiers

GC/MS Semi VOA

Qualifier Description * RPD of the LCS and LCSD exceeds the control limitsQualifier * LCS or LCSD exceeds the control limits X Surrogate is outside control limits F MS or MSD exceeds the control limits

General Chemistry

Qualifier Description

HF Field parameter with a holding time of 15 minutes

Qualifier

Glossary

These commonly used abbreviations may or may not be present in this report. ☼ Listed under the "D" column to designate that the result is reported on a dry weight basisAbbreviation

%R Percent Recovery

DL, RA, RE, IN Indicates a Dilution, Reanalysis, Re-extraction, or additional Initial metals/anion analysis of the sample

EDL Estimated Detection Limit

EPA United States Environmental Protection Agency

MDL Method Detection Limit

ML Minimum Level (Dioxin)

ND Not detected at the reporting limit (or MDL or EDL if shown)

PQL Practical Quantitation Limit

RL Reporting Limit

RPD Relative Percent Difference, a measure of the relative difference between two points

TEF Toxicity Equivalent Factor (Dioxin)

TEQ Toxicity Equivalent Quotient (Dioxin)

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Client Sample Results

Client: Potesta & Associates TestAmerica Job ID: 680-72273-2

Project/Site: ACLF - Outlet 011 Monthly - SEP 2011

Client Sample ID: Outlet 011 Lab Sample ID: 680-72273-3

Date Collected: 09/12/11 11:15 Matrix: Water

Date Received: 09/13/11 09:30

Method: 624 - Volatile Organic Compounds (GC/MS)

Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac

Acrylonitrile <20 20 ug/L 09/14/11 20:17 1

Analyte

Benzene <1.0 1.0 ug/L 09/14/11 20:17 1

Carbon tetrachloride <1.0 1.0 ug/L 09/14/11 20:17 1

Chlorobenzene <1.0 1.0 ug/L 09/14/11 20:17 1

Ethylbenzene <1.0 1.0 ug/L 09/14/11 20:17 1

Toluene <1.0 1.0 ug/L 09/14/11 20:17 1

Trichloroethene <1.0 1.0 ug/L 09/14/11 20:17 1

Vinyl chloride <1.0 1.0 ug/L 09/14/11 20:17 1

 % Recovery Qualifier Limits Prepared Analyzed Dil Fac

4-Bromofluorobenzene 109 71 - 121 09/14/11 20:17 1

Surrogate

Dibromofluoromethane 100 77 - 129 09/14/11 20:17 1

Toluene-d8 (Surr) 95 79 - 119 09/14/11 20:17 1

Method: 625 - Semivolatile Organic Compounds (GC/MS)

Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac

1,2-Dichlorobenzene <9.9 * 9.9 ug/L 09/15/11 13:45 09/19/11 23:26 1

Analyte

1,3-Dichlorobenzene <9.9 * 9.9 ug/L 09/15/11 13:45 09/19/11 23:26 1

2,4,6-Trichlorophenol <9.9 * 9.9 ug/L 09/15/11 13:45 09/20/11 19:26 1

1,4-Dichlorobenzene <9.9 * 9.9 ug/L 09/15/11 13:45 09/19/11 23:26 1

2,4-Dichlorophenol <9.9 * 9.9 ug/L 09/15/11 13:45 09/20/11 19:26 1

2,4-Dimethylphenol <9.9 * 9.9 ug/L 09/15/11 13:45 09/20/11 19:26 1

2,4-Dinitrophenol <50 * 50 ug/L 09/15/11 13:45 09/20/11 19:26 1

Hexachlorobenzene <9.9 * 9.9 ug/L 09/15/11 13:45 09/19/11 23:26 1

4,6-Dinitro-2-methylphenol <50 * 50 ug/L 09/15/11 13:45 09/20/11 19:26 1

2,4-Dimethylphenol <9.9 * 9.9 ug/L 09/15/11 13:45 09/19/11 23:26 1

Pentachlorophenol <50 * 50 ug/L 09/15/11 13:45 09/20/11 19:26 1

2-Chlorophenol <9.9 * 9.9 ug/L 09/15/11 13:45 09/20/11 19:26 1

 % Recovery Qualifier Limits Prepared Analyzed Dil Fac

2,4,6-Tribromophenol 40 34 - 132 09/15/11 13:45 09/20/11 19:26 1

Surrogate

2-Fluorobiphenyl 67 38 - 121 09/15/11 13:45 09/19/11 23:26 1

2-Fluorophenol 26 X 35 - 110 09/15/11 13:45 09/20/11 19:26 1

Nitrobenzene-d5 66 44 - 119 09/15/11 13:45 09/19/11 23:26 1

Terphenyl-d14 71 10 - 165 09/15/11 13:45 09/19/11 23:26 1

Phenol-d5 27 27 - 119 09/15/11 13:45 09/20/11 19:26 1

Method: 200.7 Rev 4.4 - Metals (ICP) - Total Recoverable

Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac

Copper <20 20 ug/L 09/15/11 10:24 09/19/11 19:37 1

Analyte

Iron 24000 50 ug/L 09/15/11 10:24 09/19/11 19:37 1

Lead <10 10 ug/L 09/15/11 10:24 09/19/11 19:37 1

Manganese 940 10 ug/L 09/15/11 10:24 09/19/11 19:37 1

Zinc <20 20 ug/L 09/15/11 10:24 09/19/11 19:37 1

General Chemistry

Result Qualifier NONE NONE Unit D Prepared Analyzed Dil Fac

pH 7.40 HF SU 09/13/11 16:51 1

Analyte

Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac

Phenolics, Total Recoverable <0.050 0.050 mg/L 09/22/11 14:00 09/22/11 16:07 1

Analyte

Chloride 30 1.0 mg/L 09/22/11 12:30 1

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Client Sample Results

Client: Potesta & Associates TestAmerica Job ID: 680-72273-2

Project/Site: ACLF - Outlet 011 Monthly - SEP 2011

Client Sample ID: Outlet 011 Lab Sample ID: 680-72273-3

Date Collected: 09/12/11 11:15 Matrix: Water

Date Received: 09/13/11 09:30

Result Qualifier RL RL Unit D Prepared Analyzed Dil Fac

Total Suspended Solids 56 5.0 mg/L 09/14/11 14:57 1

Analyte

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Client Sample Results

Client: Potesta & Associates TestAmerica Job ID: 680-72273-2

Project/Site: ACLF - Outlet 011 Monthly - SEP 2011

Client Sample ID: Trip Blank Lab Sample ID: 680-72273-4

Date Collected: 09/12/11 00:00 Matrix: Water

Date Received: 09/13/11 09:30

Method: 624 - Volatile Organic Compounds (GC/MS)

Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac

Acrylonitrile <20 20 ug/L 09/14/11 18:52 1

Analyte

Benzene <1.0 1.0 ug/L 09/14/11 18:52 1

Carbon tetrachloride <1.0 1.0 ug/L 09/14/11 18:52 1

Chlorobenzene <1.0 1.0 ug/L 09/14/11 18:52 1

Ethylbenzene <1.0 1.0 ug/L 09/14/11 18:52 1

Toluene <1.0 1.0 ug/L 09/14/11 18:52 1

Trichloroethene <1.0 1.0 ug/L 09/14/11 18:52 1

Vinyl chloride <1.0 1.0 ug/L 09/14/11 18:52 1

 % Recovery Qualifier Limits Prepared Analyzed Dil Fac

4-Bromofluorobenzene 96 71 - 121 09/14/11 18:52 1

Surrogate

Dibromofluoromethane 94 77 - 129 09/14/11 18:52 1

Toluene-d8 (Surr) 96 79 - 119 09/14/11 18:52 1

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Surrogate Summary

Client: Potesta & Associates TestAmerica Job ID: 680-72273-2

Project/Site: ACLF - Outlet 011 Monthly - SEP 2011

Method: 624 - Volatile Organic Compounds (GC/MS)

Matrix: Water Prep Type: Total/NA

Lab Sample ID Client Sample ID (71-121) (77-129) (79-119)

BFB DBFM TOL

680-72273-3 109 100 95

Percent Surrogate Recovery (Acceptance Limits)

Outlet 011

680-72273-4 Trip Blank 96 94 96

LCS 680-214797/12 Lab Control Sample 101 104 102

LCSD 680-214797/13 Lab Control Sample Dup 98 92 96

MB 680-214797/14 Method Blank 94 95 97

Surrogate Legend

BFB = 4-Bromofluorobenzene

DBFM = Dibromofluoromethane

TOL = Toluene-d8 (Surr)

Method: 625 - Semivolatile Organic Compounds (GC/MS)

Matrix: Water Prep Type: Total/NA

Lab Sample ID Client Sample ID (38-121) (44-119) (10-165)

FBP NBZ TPH

680-72273-3 67 66 71

Percent Surrogate Recovery (Acceptance Limits)

Outlet 011

680-72273-3 MS Outlet 011 72 72 73

680-72273-3 MSD Outlet 011 66 66 62

LCS 680-214813/3-A Lab Control Sample 84 85 85

LCSD 680-214813/4-A Lab Control Sample Dup 78 81 83

MB 680-214813/2-A Method Blank 77 77 89

Surrogate Legend

FBP = 2-Fluorobiphenyl

NBZ = Nitrobenzene-d5

TPH = Terphenyl-d14

Method: 625 - Semivolatile Organic Compounds (GC/MS)

Matrix: Water Prep Type: Total/NA

Lab Sample ID Client Sample ID (34-132) (35-110) (27-119)

TBP 2FP PHL

680-72273-3 40 26 X 27

Percent Surrogate Recovery (Acceptance Limits)

Outlet 011

680-72273-3 MS Outlet 011 65 58 50

680-72273-3 MSD Outlet 011 50 45 41

LCS 680-214813/3-A Lab Control Sample 93 91 77

LCSD 680-214813/4-A Lab Control Sample Dup 90 94 80

MB 680-214813/2-A Method Blank 83 88 80

Surrogate Legend

TBP = 2,4,6-Tribromophenol

2FP = 2-Fluorophenol

PHL = Phenol-d5

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QC Sample Results

Client: Potesta & Associates TestAmerica Job ID: 680-72273-2

Project/Site: ACLF - Outlet 011 Monthly - SEP 2011

Method: 624 - Volatile Organic Compounds (GC/MS)

Lab Sample ID: MB 680-214797/14 Client Sample ID: Method Blank

Matrix: Water Prep Type: Total/NA

Analysis Batch: 214797

Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac

Acrylonitrile <20 20 ug/L 09/14/11 15:06 1

MB MB

Analyte

Benzene <1.0 1.0 ug/L 09/14/11 15:06 1

Carbon tetrachloride <1.0 1.0 ug/L 09/14/11 15:06 1

Chlorobenzene <1.0 1.0 ug/L 09/14/11 15:06 1

Ethylbenzene <1.0 1.0 ug/L 09/14/11 15:06 1

Toluene <1.0 1.0 ug/L 09/14/11 15:06 1

Trichloroethene <1.0 1.0 ug/L 09/14/11 15:06 1

Vinyl chloride <1.0 1.0 ug/L 09/14/11 15:06 1

 % Recovery Qualifier Limits Prepared Analyzed Dil Fac

4-Bromofluorobenzene 94 71 - 121 09/14/11 15:06 1

MB MB

Surrogate

Dibromofluoromethane 95 77 - 129 09/14/11 15:06 1

Toluene-d8 (Surr) 97 79 - 119 09/14/11 15:06 1

Lab Sample ID: LCS 680-214797/12 Client Sample ID: Lab Control Sample

Matrix: Water Prep Type: Total/NA

Analysis Batch: 214797

Spike

Added Result Qualifier Unit % Rec

% Rec.

Limits

Acrylonitrile 400 601 ug/L 150 10 - 183

Analyte D

LCS LCS

Benzene 20.0 19.7 ug/L 99 37 - 151

Carbon tetrachloride 20.0 18.0 ug/L 90 70 - 140

Chlorobenzene 20.0 21.4 ug/L 107 37 - 160

Ethylbenzene 20.0 23.0 ug/L 115 37 - 162

Toluene 20.0 20.4 ug/L 102 47 - 150

Trichloroethene 20.0 21.8 ug/L 109 71 - 157

Vinyl chloride 20.0 20.6 ug/L 103 1 - 251

 % Recovery Qualifier Limits

4-Bromofluorobenzene 71 - 121

Surrogate

101

LCS LCS

Dibromofluoromethane 104 77 - 129

Toluene-d8 (Surr) 102 79 - 119

Lab Sample ID: LCSD 680-214797/13 Client Sample ID: Lab Control Sample Dup

Matrix: Water Prep Type: Total/NA

Analysis Batch: 214797

Spike

Added Result Qualifier Unit % Rec

% Rec.

Limits RPD Limit

Acrylonitrile 400 396 ug/L 99 10 - 183 41 50

Analyte D

LCSD LCSD RPD

Benzene 20.0 19.6 ug/L 98 37 - 151 1 30

Carbon tetrachloride 20.0 16.2 ug/L 81 70 - 140 11 30

Chlorobenzene 20.0 20.2 ug/L 101 37 - 160 6 30

Ethylbenzene 20.0 20.6 ug/L 103 37 - 162 11 30

Toluene 20.0 19.8 ug/L 99 47 - 150 3 30

Trichloroethene 20.0 19.8 ug/L 99 71 - 157 10 30

Vinyl chloride 20.0 16.5 ug/L 82 1 - 251 22 50

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QC Sample Results

Client: Potesta & Associates TestAmerica Job ID: 680-72273-2

Project/Site: ACLF - Outlet 011 Monthly - SEP 2011

Method: 624 - Volatile Organic Compounds (GC/MS) (Continued)

Lab Sample ID: LCSD 680-214797/13 Client Sample ID: Lab Control Sample Dup

Matrix: Water Prep Type: Total/NA

Analysis Batch: 214797

 % Recovery Qualifier Limits

4-Bromofluorobenzene 71 - 121

Surrogate

98

LCSD LCSD

Dibromofluoromethane 92 77 - 129

Toluene-d8 (Surr) 96 79 - 119

Method: 625 - Semivolatile Organic Compounds (GC/MS)

Lab Sample ID: MB 680-214813/2-A Client Sample ID: Method Blank

Matrix: Water Prep Type: Total/NA

Analysis Batch: 215125 Prep Batch: 214813

Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac

1,2-Dichlorobenzene <10 10 ug/L 09/15/11 13:45 09/19/11 22:59 1

MB MB

Analyte

1,3-Dichlorobenzene <10 10 ug/L 09/15/11 13:45 09/19/11 22:59 1

1,4-Dichlorobenzene <10 10 ug/L 09/15/11 13:45 09/19/11 22:59 1

Hexachlorobenzene <10 10 ug/L 09/15/11 13:45 09/19/11 22:59 1

2,4-Dimethylphenol <10 10 ug/L 09/15/11 13:45 09/19/11 22:59 1

 % Recovery Qualifier Limits Prepared Analyzed Dil Fac

2-Fluorobiphenyl 77 38 - 121 09/19/11 22:59 1

MB MB

Surrogate

09/15/11 13:45

Nitrobenzene-d5 77 44 - 119 09/15/11 13:45 09/19/11 22:59 1

Terphenyl-d14 89 10 - 165 09/15/11 13:45 09/19/11 22:59 1

Lab Sample ID: MB 680-214813/2-A Client Sample ID: Method Blank

Matrix: Water Prep Type: Total/NA

Analysis Batch: 215125 Prep Batch: 214813

Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac

2,4,6-Trichlorophenol <10 10 ug/L 09/15/11 13:45 09/20/11 01:39 1

MB MB

Analyte

2,4-Dichlorophenol <10 10 ug/L 09/15/11 13:45 09/20/11 01:39 1

2,4-Dinitrophenol <50 50 ug/L 09/15/11 13:45 09/20/11 01:39 1

4,6-Dinitro-2-methylphenol <50 50 ug/L 09/15/11 13:45 09/20/11 01:39 1

2,4-Dimethylphenol <10 10 ug/L 09/15/11 13:45 09/20/11 01:39 1

Pentachlorophenol <50 50 ug/L 09/15/11 13:45 09/20/11 01:39 1

2-Chlorophenol <10 10 ug/L 09/15/11 13:45 09/20/11 01:39 1

 % Recovery Qualifier Limits Prepared Analyzed Dil Fac

2,4,6-Tribromophenol 83 34 - 132 09/20/11 01:39 1

MB MB

Surrogate

09/15/11 13:45

2-Fluorophenol 88 35 - 110 09/15/11 13:45 09/20/11 01:39 1

Phenol-d5 80 27 - 119 09/15/11 13:45 09/20/11 01:39 1

Lab Sample ID: LCS 680-214813/3-A Client Sample ID: Lab Control Sample

Matrix: Water Prep Type: Total/NA

Analysis Batch: 215125 Prep Batch: 214813

Spike

Added Result Qualifier Unit % Rec

% Rec.

Limits

1,2-Dichlorobenzene 100 79.9 ug/L 80 32 - 129

Analyte D

LCS LCS

1,3-Dichlorobenzene 100 79.1 ug/L 79 1 - 172

1,4-Dichlorobenzene 100 77.7 ug/L 78 20 - 124

Hexachlorobenzene 100 93.0 ug/L 93 1 - 152

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QC Sample Results

Client: Potesta & Associates TestAmerica Job ID: 680-72273-2

Project/Site: ACLF - Outlet 011 Monthly - SEP 2011

Method: 625 - Semivolatile Organic Compounds (GC/MS) (Continued)

Lab Sample ID: LCS 680-214813/3-A Client Sample ID: Lab Control Sample

Matrix: Water Prep Type: Total/NA

Analysis Batch: 215125 Prep Batch: 214813

Spike

Added Result Qualifier Unit % Rec

% Rec.

Limits

2,4-Dimethylphenol 100 57.3 ug/L 57 32 - 119

Analyte D

LCS LCS

 % Recovery Qualifier Limits

2-Fluorobiphenyl 38 - 121

Surrogate

84

LCS LCS

Nitrobenzene-d5 85 44 - 119

Terphenyl-d14 85 10 - 165

Lab Sample ID: LCS 680-214813/3-A Client Sample ID: Lab Control Sample

Matrix: Water Prep Type: Total/NA

Analysis Batch: 215125 Prep Batch: 214813

Spike

Added Result Qualifier Unit % Rec

% Rec.

Limits

2,4,6-Trichlorophenol 100 94.8 ug/L 95 37 - 144

Analyte D

LCS LCS

2,4-Dichlorophenol 100 85.6 ug/L 86 39 - 135

2,4-Dinitrophenol 100 <50 ug/L 37 1 - 191

4,6-Dinitro-2-methylphenol 100 61.4 ug/L 61 1 - 181

2,4-Dimethylphenol 100 <10 * ug/L 8 32 - 119

Pentachlorophenol 100 88.5 ug/L 89 14 - 176

2-Chlorophenol 100 86.3 ug/L 86 23 - 134

 % Recovery Qualifier Limits

2,4,6-Tribromophenol 34 - 132

Surrogate

93

LCS LCS

2-Fluorophenol 91 35 - 110

Phenol-d5 77 27 - 119

Lab Sample ID: LCSD 680-214813/4-A Client Sample ID: Lab Control Sample Dup

Matrix: Water Prep Type: Total/NA

Analysis Batch: 215125 Prep Batch: 214813

Spike

Added Result Qualifier Unit % Rec

% Rec.

Limits RPD Limit

1,2-Dichlorobenzene 100 36.3 * ug/L 36 32 - 129 75 40

Analyte D

LCSD LCSD RPD

1,3-Dichlorobenzene 100 35.2 * ug/L 35 1 - 172 77 40

1,4-Dichlorobenzene 100 35.7 * ug/L 36 20 - 124 74 40

Hexachlorobenzene 100 49.0 * ug/L 49 1 - 152 62 40

2,4-Dimethylphenol 100 29.9 * ug/L 30 32 - 119 63 40

 % Recovery Qualifier Limits

2-Fluorobiphenyl 38 - 121

Surrogate

78

LCSD LCSD

Nitrobenzene-d5 81 44 - 119

Terphenyl-d14 83 10 - 165

Lab Sample ID: LCSD 680-214813/4-A Client Sample ID: Lab Control Sample Dup

Matrix: Water Prep Type: Total/NA

Analysis Batch: 215125 Prep Batch: 214813

Spike

Added Result Qualifier Unit % Rec

% Rec.

Limits RPD Limit

2,4,6-Trichlorophenol 100 50.5 * ug/L 50 37 - 144 61 40

Analyte D

LCSD LCSD RPD

2,4-Dichlorophenol 100 45.8 * ug/L 46 39 - 135 60 40

2,4-Dinitrophenol 100 <50 * ug/L 3 1 - 191 172 40

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QC Sample Results

Client: Potesta & Associates TestAmerica Job ID: 680-72273-2

Project/Site: ACLF - Outlet 011 Monthly - SEP 2011

Method: 625 - Semivolatile Organic Compounds (GC/MS) (Continued)

Lab Sample ID: LCSD 680-214813/4-A Client Sample ID: Lab Control Sample Dup

Matrix: Water Prep Type: Total/NA

Analysis Batch: 215125 Prep Batch: 214813

Spike

Added Result Qualifier Unit % Rec

% Rec.

Limits RPD Limit

4,6-Dinitro-2-methylphenol 100 <50 * ug/L 19 1 - 181 105 40

Analyte D

LCSD LCSD RPD

2,4-Dimethylphenol 100 <10 * ug/L 3 32 - 119 96 40

Pentachlorophenol 100 <50 * ug/L 36 14 - 176 84 40

2-Chlorophenol 100 47.4 * ug/L 47 23 - 134 58 40

 % Recovery Qualifier Limits

2,4,6-Tribromophenol 34 - 132

Surrogate

90

LCSD LCSD

2-Fluorophenol 94 35 - 110

Phenol-d5 80 27 - 119

Lab Sample ID: 680-72273-3 MS Client Sample ID: Outlet 011

Matrix: Water Prep Type: Total/NA

Analysis Batch: 215125 Prep Batch: 214813

Sample

Result

Sample

Qualifier

Spike

Added Result Qualifier Unit % Rec

% Rec.

Limits

1,2-Dichlorobenzene 0.000 99.4 70.1 ug/L 71 32 - 129

Analyte D

MS MS

1,3-Dichlorobenzene 0.000 99.4 69.4 ug/L 70 1 - 172

1,4-Dichlorobenzene 0.000 99.4 68.2 ug/L 69 20 - 124

Hexachlorobenzene 0.000 99.4 88.9 ug/L 89 1 - 152

2,4-Dimethylphenol <9.9 * 99.4 53.9 ug/L 54 32 - 119

 % Recovery Qualifier Limits

2-Fluorobiphenyl 38 - 121

Surrogate

72

MS MS

Nitrobenzene-d5 72 44 - 119

Terphenyl-d14 73 10 - 165

Lab Sample ID: 680-72273-3 MS Client Sample ID: Outlet 011

Matrix: Water Prep Type: Total/NA

Analysis Batch: 215125 Prep Batch: 214813

Sample

Result

Sample

Qualifier

Spike

Added Result Qualifier Unit % Rec

% Rec.

Limits

2,4,6-Trichlorophenol <9.9 * 99.4 73.4 ug/L 74 37 - 144

Analyte D

MS MS

2,4-Dichlorophenol <9.9 * 99.4 64.1 ug/L 64 39 - 135

2,4-Dinitrophenol <50 * 99.4 58.1 ug/L 58 1 - 191

4,6-Dinitro-2-methylphenol <50 * 99.4 83.7 ug/L 84 1 - 181

2,4-Dimethylphenol <9.9 * 99.4 <9.9 F ug/L 0 32 - 119

Pentachlorophenol <50 * 99.4 71.5 ug/L 72 14 - 176

2-Chlorophenol <9.9 * 99.4 63.9 ug/L 64 23 - 134

 % Recovery Qualifier Limits

2,4,6-Tribromophenol 34 - 132

Surrogate

65

MS MS

2-Fluorophenol 58 35 - 110

Phenol-d5 50 27 - 119

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QC Sample Results

Client: Potesta & Associates TestAmerica Job ID: 680-72273-2

Project/Site: ACLF - Outlet 011 Monthly - SEP 2011

Method: 625 - Semivolatile Organic Compounds (GC/MS) (Continued)

Lab Sample ID: 680-72273-3 MSD Client Sample ID: Outlet 011

Matrix: Water Prep Type: Total/NA

Analysis Batch: 215125 Prep Batch: 214813

Sample

Result

Sample

Qualifier

Spike

Added Result Qualifier Unit % Rec

% Rec.

Limits RPD Limit

1,2-Dichlorobenzene <9.9 99.6 60.3 ug/L 61 32 - 129 15 40

Analyte D

MSD MSD RPD

1,3-Dichlorobenzene <9.9 99.6 59.0 ug/L 59 1 - 172 16 40

1,4-Dichlorobenzene <9.9 99.6 59.0 ug/L 59 20 - 124 14 40

Hexachlorobenzene <9.9 99.6 74.7 ug/L 75 1 - 152 17 40

2,4-Dimethylphenol <9.9 * 99.6 40.9 ug/L 41 32 - 119 28 40

 % Recovery Qualifier Limits

2-Fluorobiphenyl 38 - 121

Surrogate

66

MSD MSD

Nitrobenzene-d5 66 44 - 119

Terphenyl-d14 62 10 - 165

Lab Sample ID: 680-72273-3 MSD Client Sample ID: Outlet 011

Matrix: Water Prep Type: Total/NA

Analysis Batch: 215125 Prep Batch: 214813

Sample

Result

Sample

Qualifier

Spike

Added Result Qualifier Unit % Rec

% Rec.

Limits RPD Limit

2,4,6-Trichlorophenol <9.9 * 99.6 55.3 ug/L 56 37 - 144 28 40

Analyte D

MSD MSD RPD

2,4-Dichlorophenol <9.9 * 99.6 50.3 ug/L 51 39 - 135 24 40

2,4-Dinitrophenol <50 * 99.6 <50 ug/L 40 1 - 191 37 40

4,6-Dinitro-2-methylphenol <50 * 99.6 62.6 ug/L 63 1 - 181 29 40

2,4-Dimethylphenol <9.9 * 99.6 <10 F ug/L 0 32 - 119 NC 40

Pentachlorophenol <50 * 99.6 53.1 ug/L 53 14 - 176 30 40

2-Chlorophenol <9.9 * 99.6 51.2 ug/L 51 23 - 134 22 40

 % Recovery Qualifier Limits

2,4,6-Tribromophenol 34 - 132

Surrogate

50

MSD MSD

2-Fluorophenol 45 35 - 110

Phenol-d5 41 27 - 119

Method: 200.7 Rev 4.4 - Metals (ICP)

Lab Sample ID: MB 680-214790/1-A Client Sample ID: Method Blank

Matrix: Water Prep Type: Total Recoverable

Analysis Batch: 215201 Prep Batch: 214790

Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac

Copper <20 20 ug/L 09/15/11 10:23 09/19/11 18:26 1

MB MB

Analyte

Iron <50 50 ug/L 09/15/11 10:23 09/19/11 18:26 1

Lead <10 10 ug/L 09/15/11 10:23 09/19/11 18:26 1

Manganese <10 10 ug/L 09/15/11 10:23 09/19/11 18:26 1

Zinc <20 20 ug/L 09/15/11 10:23 09/19/11 18:26 1

Lab Sample ID: LCS 680-214790/2-A Client Sample ID: Lab Control Sample

Matrix: Water Prep Type: Total Recoverable

Analysis Batch: 215201 Prep Batch: 214790

Spike

Added Result Qualifier Unit % Rec

% Rec.

Limits

Copper 250 242 ug/L 97 85 - 115

Analyte D

LCS LCS

Iron 1000 979 ug/L 98 85 - 115

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QC Sample Results

Client: Potesta & Associates TestAmerica Job ID: 680-72273-2

Project/Site: ACLF - Outlet 011 Monthly - SEP 2011

Method: 200.7 Rev 4.4 - Metals (ICP) (Continued)

Lab Sample ID: LCS 680-214790/2-A Client Sample ID: Lab Control Sample

Matrix: Water Prep Type: Total Recoverable

Analysis Batch: 215201 Prep Batch: 214790

Spike

Added Result Qualifier Unit % Rec

% Rec.

Limits

Lead 500 510 ug/L 102 85 - 115

Analyte D

LCS LCS

Manganese 500 515 ug/L 103 85 - 115

Zinc 500 497 ug/L 99 85 - 115

Method: 420.1 - Phenolics, Total Recoverable

Lab Sample ID: MB 680-215483/3-A Client Sample ID: Method Blank

Matrix: Water Prep Type: Total/NA

Analysis Batch: 215487 Prep Batch: 215483

Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac

Phenolics, Total Recoverable <0.050 0.050 mg/L 09/22/11 14:00 09/22/11 16:07 1

MB MB

Analyte

Lab Sample ID: LCS 680-215483/4-A Client Sample ID: Lab Control Sample

Matrix: Water Prep Type: Total/NA

Analysis Batch: 215487 Prep Batch: 215483

Spike

Added Result Qualifier Unit % Rec

% Rec.

Limits

Phenolics, Total Recoverable 0.250 0.237 mg/L 95 75 - 125

Analyte D

LCS LCS

Method: SM 2540D - Solids, Total Suspended (TSS)

Lab Sample ID: MB 680-214709/1 Client Sample ID: Method Blank

Matrix: Water Prep Type: Total/NA

Analysis Batch: 214709

Result Qualifier RL RL Unit D Prepared Analyzed Dil Fac

Total Suspended Solids <5.0 5.0 mg/L 09/14/11 14:52 1

MB MB

Analyte

Lab Sample ID: LCS 680-214709/2 Client Sample ID: Lab Control Sample

Matrix: Water Prep Type: Total/NA

Analysis Batch: 214709

Spike

Added Result Qualifier Unit % Rec

% Rec.

Limits

Total Suspended Solids 100 101 mg/L 101 80 - 120

Analyte D

LCS LCS

Lab Sample ID: LCSD 680-214709/3 Client Sample ID: Lab Control Sample Dup

Matrix: Water Prep Type: Total/NA

Analysis Batch: 214709

Spike

Added Result Qualifier Unit % Rec

% Rec.

Limits RPD Limit

Total Suspended Solids 100 104 mg/L 104 80 - 120 3 25

Analyte D

LCSD LCSD RPD

Lab Sample ID: 680-72273-3 DU Client Sample ID: Outlet 011

Matrix: Water Prep Type: Total/NA

Analysis Batch: 214709

Sample

Result

Sample

Qualifier Result Qualifier Unit RPD Limit

Total Suspended Solids 56 59.5 mg/L 7 25

Analyte D

DU DU RPD

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QC Sample Results

Client: Potesta & Associates TestAmerica Job ID: 680-72273-2

Project/Site: ACLF - Outlet 011 Monthly - SEP 2011

Method: SM 4500 Cl- E - Chloride, Total

Lab Sample ID: MB 680-215460/9 Client Sample ID: Method Blank

Matrix: Water Prep Type: Total/NA

Analysis Batch: 215460

Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac

Chloride <1.0 1.0 mg/L 09/22/11 11:35 1

MB MB

Analyte

Lab Sample ID: LCS 680-215460/6 Client Sample ID: Lab Control Sample

Matrix: Water Prep Type: Total/NA

Analysis Batch: 215460

Spike

Added Result Qualifier Unit % Rec

% Rec.

Limits

Chloride 50.0 53.0 mg/L 106 85 - 115

Analyte D

LCS LCS

Lab Sample ID: 680-72273-3 MS Client Sample ID: Outlet 011

Matrix: Water Prep Type: Total/NA

Analysis Batch: 215460

Sample

Result

Sample

Qualifier

Spike

Added Result Qualifier Unit % Rec

% Rec.

Limits

Chloride 30 50.0 77.3 mg/L 94 85 - 115

Analyte D

MS MS

Lab Sample ID: 680-72273-3 MSD Client Sample ID: Outlet 011

Matrix: Water Prep Type: Total/NA

Analysis Batch: 215460

Sample

Result

Sample

Qualifier

Spike

Added Result Qualifier Unit % Rec

% Rec.

Limits RPD Limit

Chloride 30 50.0 77.4 mg/L 95 85 - 115 0 30

Analyte D

MSD MSD RPD

Method: SM 4500 H+ B - pH

Lab Sample ID: LCS 680-214637/4 Client Sample ID: Lab Control Sample

Matrix: Water Prep Type: Total/NA

Analysis Batch: 214637

Spike

Added Result Qualifier Unit % Rec

% Rec.

Limits

pH 7.00 7.030 SU 100 63 - 158

Analyte D

LCS LCS

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QC Association Summary

Client: Potesta & Associates TestAmerica Job ID: 680-72273-2

Project/Site: ACLF - Outlet 011 Monthly - SEP 2011

GC/MS VOA

Analysis Batch: 214797

Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch

680-72273-3 Outlet 011 Total/NA Water 624

680-72273-4 Trip Blank Total/NA Water 624

LCS 680-214797/12 Lab Control Sample Total/NA Water 624

LCSD 680-214797/13 Lab Control Sample Dup Total/NA Water 624

MB 680-214797/14 Method Blank Total/NA Water 624

GC/MS Semi VOA

Prep Batch: 214813

Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch

680-72273-3 Outlet 011 Total/NA Water 625

680-72273-3 MS Outlet 011 Total/NA Water 625

680-72273-3 MSD Outlet 011 Total/NA Water 625

LCS 680-214813/3-A Lab Control Sample Total/NA Water 625

LCSD 680-214813/4-A Lab Control Sample Dup Total/NA Water 625

MB 680-214813/2-A Method Blank Total/NA Water 625

Analysis Batch: 215125

Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch

680-72273-3 Outlet 011 Total/NA Water 625 214813

680-72273-3 MS Outlet 011 Total/NA Water 625 214813

680-72273-3 MS Outlet 011 Total/NA Water 625 214813

680-72273-3 MSD Outlet 011 Total/NA Water 625 214813

680-72273-3 MSD Outlet 011 Total/NA Water 625 214813

LCS 680-214813/3-A Lab Control Sample Total/NA Water 625 214813

LCS 680-214813/3-A Lab Control Sample Total/NA Water 625 214813

LCSD 680-214813/4-A Lab Control Sample Dup Total/NA Water 625 214813

LCSD 680-214813/4-A Lab Control Sample Dup Total/NA Water 625 214813

MB 680-214813/2-A Method Blank Total/NA Water 625 214813

MB 680-214813/2-A Method Blank Total/NA Water 625 214813

Analysis Batch: 215279

Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch

680-72273-3 Outlet 011 Total/NA Water 625 214813

Metals

Prep Batch: 214790

Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch

680-72273-3 Outlet 011 Total Recoverable Water 200.7

LCS 680-214790/2-A Lab Control Sample Total Recoverable Water 200.7

MB 680-214790/1-A Method Blank Total Recoverable Water 200.7

Analysis Batch: 215201

Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch

680-72273-3 Outlet 011 Total Recoverable Water 200.7 Rev 4.4 214790

LCS 680-214790/2-A Lab Control Sample Total Recoverable Water 200.7 Rev 4.4 214790

MB 680-214790/1-A Method Blank Total Recoverable Water 200.7 Rev 4.4 214790

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QC Association Summary

Client: Potesta & Associates TestAmerica Job ID: 680-72273-2

Project/Site: ACLF - Outlet 011 Monthly - SEP 2011

General Chemistry

Analysis Batch: 214637

Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch

680-72273-3 Outlet 011 Total/NA Water SM 4500 H+ B

LCS 680-214637/4 Lab Control Sample Total/NA Water SM 4500 H+ B

Analysis Batch: 214709

Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch

680-72273-3 Outlet 011 Total/NA Water SM 2540D

680-72273-3 DU Outlet 011 Total/NA Water SM 2540D

LCS 680-214709/2 Lab Control Sample Total/NA Water SM 2540D

LCSD 680-214709/3 Lab Control Sample Dup Total/NA Water SM 2540D

MB 680-214709/1 Method Blank Total/NA Water SM 2540D

Analysis Batch: 215460

Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch

680-72273-3 Outlet 011 Total/NA Water SM 4500 Cl- E

680-72273-3 MS Outlet 011 Total/NA Water SM 4500 Cl- E

680-72273-3 MSD Outlet 011 Total/NA Water SM 4500 Cl- E

LCS 680-215460/6 Lab Control Sample Total/NA Water SM 4500 Cl- E

MB 680-215460/9 Method Blank Total/NA Water SM 4500 Cl- E

Prep Batch: 215483

Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch

680-72273-3 Outlet 011 Total/NA Water Distill/Phenol

LCS 680-215483/4-A Lab Control Sample Total/NA Water Distill/Phenol

MB 680-215483/3-A Method Blank Total/NA Water Distill/Phenol

Analysis Batch: 215487

Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch

680-72273-3 Outlet 011 Total/NA Water 420.1 215483

LCS 680-215483/4-A Lab Control Sample Total/NA Water 420.1 215483

MB 680-215483/3-A Method Blank Total/NA Water 420.1 215483

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Lab Chronicle

Client: Potesta & Associates TestAmerica Job ID: 680-72273-2

Project/Site: ACLF - Outlet 011 Monthly - SEP 2011

Client Sample ID: Outlet 011 Lab Sample ID: 680-72273-3

Date Collected: 09/12/11 11:15 Matrix: Water

Date Received: 09/13/11 09:30

Batch

Type

Batch

Method Run

Dilution

Factor

Batch

Number

Prepared

Prep Type Or Analyzed Analyst Lab

Total/NA Analysis 624 1 214797 09/14/11 20:17 JG TAL SAV

Total/NA Prep 625 214813 09/15/11 13:45 RBS TAL SAV

Total/NA Analysis 625 1 215125 09/19/11 23:26 CRH TAL SAV

Total/NA Analysis 625 1 215279 09/20/11 19:26 CRH TAL SAV

Total Recoverable Prep 200.7 214790 09/15/11 10:24 RAM TAL SAV

Total Recoverable Analysis 200.7 Rev 4.4 1 215201 09/19/11 19:37 BCB TAL SAV

Total/NA Analysis SM 4500 H+ B 1 214637 09/13/11 16:51 MSJ TAL SAV

Total/NA Analysis SM 2540D 1 214709 09/14/11 14:57 MSJ TAL SAV

Total/NA Analysis SM 4500 Cl- E 1 215460 09/22/11 12:30 JR TAL SAV

Total/NA Prep Distill/Phenol 215483 09/22/11 14:00 CN TAL SAV

Total/NA Analysis 420.1 1 215487 09/22/11 16:07 CN TAL SAV

Client Sample ID: Trip Blank Lab Sample ID: 680-72273-4

Date Collected: 09/12/11 00:00 Matrix: Water

Date Received: 09/13/11 09:30

Batch

Type

Batch

Method Run

Dilution

Factor

Batch

Number

Prepared

Prep Type Or Analyzed Analyst Lab

Total/NA Analysis 624 1 214797 09/14/11 18:52 JG TAL SAV

Laboratory References:

TAL SAV = TestAmerica Savannah, 5102 LaRoche Avenue, Savannah, GA 31404, TEL (912)354-7858

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Login Sample Receipt Checklist

Client: Potesta & Associates Job Number: 680-72273-2

Login Number: 72273

Question Answer Comment

Creator: Barnett, Eddie T

List Source: TestAmerica Savannah

List Number: 1

Radioactivity either was not measured or, if measured, is at or below N/A

background

The cooler's custody seal, if present, is intact. True

The cooler or samples do not appear to have been compromised or True

tampered with.

Samples were received on ice. True

Cooler Temperature is acceptable. True

Cooler Temperature is recorded. True

COC is present. True

COC is filled out in ink and legible. True

COC is filled out with all pertinent information. True

Is the Field Sampler's name present on COC? N/A

There are no discrepancies between the sample IDs on the containers and True

the COC.

Samples are received within Holding Time. True

Sample containers have legible labels. True

Containers are not broken or leaking. True

Sample collection date/times are provided. True

Appropriate sample containers are used. True

Sample bottles are completely filled. True

Sample Preservation Verified. True

There is sufficient vol. for all requested analyses, incl. any requested True

MS/MSDs

VOA sample vials do not have headspace or bubble is <6mm (1/4") in True

diameter.

Multiphasic samples are not present. True

Samples do not require splitting or compositing. True

Residual Chlorine Checked. N/A

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Certification Summary

Client: Potesta & Associates TestAmerica Job ID: 680-72273-2

Project/Site: ACLF - Outlet 011 Monthly - SEP 2011

Laboratory Authority Program EPA Region Certification ID

TestAmerica Savannah A2LA DoD ELAP 0399-01

TestAmerica Savannah A2LA ISO/IEC 17025 399.01

TestAmerica Savannah Alabama State Program 4 41450

TestAmerica Savannah Arkansas Arkansas DOH 6 N/A

TestAmerica Savannah Arkansas State Program 6 88-0692

TestAmerica Savannah California NELAC 9 3217CA

TestAmerica Savannah Colorado State Program 8 N/A

TestAmerica Savannah Connecticut State Program 1 PH-0161

TestAmerica Savannah Delaware State Program 3 N/A

TestAmerica Savannah Florida NELAC 4 E87052

TestAmerica Savannah Georgia Georgia EPD 4 N/A

TestAmerica Savannah Georgia State Program 4 803

TestAmerica Savannah Guam State Program 9 09-005r

TestAmerica Savannah Hawaii State Program 9 N/A

TestAmerica Savannah Illinois NELAC 5 200022

TestAmerica Savannah Indiana State Program 5 N/A

TestAmerica Savannah Iowa State Program 7 353

TestAmerica Savannah Kentucky Kentucky UST 4 18

TestAmerica Savannah Kentucky State Program 4 90084

TestAmerica Savannah Louisiana NELAC 6 LA100015

TestAmerica Savannah Louisiana NELAC 6 30690

TestAmerica Savannah Maine State Program 1 GA00006

TestAmerica Savannah Maryland State Program 3 250

TestAmerica Savannah Massachusetts State Program 1 M-GA006

TestAmerica Savannah Michigan State Program 5 9925

TestAmerica Savannah Mississippi State Program 4 N/A

TestAmerica Savannah Montana State Program 8 CERT0081

TestAmerica Savannah Nebraska State Program 7 TestAmerica-Savannah

TestAmerica Savannah New Jersey NELAC 2 GA769

TestAmerica Savannah New Mexico State Program 6 N/A

TestAmerica Savannah New York NELAC 2 10842

TestAmerica Savannah North Carolina North Carolina DENR 4 269

TestAmerica Savannah North Carolina North Carolina PHL 4 13701

TestAmerica Savannah Pennsylvania NELAC 3 68-00474

TestAmerica Savannah Puerto Rico State Program 2 GA00006

TestAmerica Savannah Rhode Island State Program 1 LAO00244

TestAmerica Savannah South Carolina State Program 4 98001

TestAmerica Savannah Tennessee State Program 4 TN02961

TestAmerica Savannah Texas NELAC 6 T104704185-08-TX

TestAmerica Savannah USDA USDA SAV 3-04

TestAmerica Savannah Vermont State Program 1 87052

TestAmerica Savannah Virginia NELAC Secondary AB 3 460161

TestAmerica Savannah Virginia State Program 3 302

TestAmerica Savannah Washington State Program 10 C1794

TestAmerica Savannah West Virginia West Virginia DEP 3 94

TestAmerica Savannah West Virginia West Virginia DHHR (DW) 3 9950C

TestAmerica Savannah Wyoming State Program 8 8TMS-Q

Accreditation may not be offered or required for all methods and analytes reported in this package. Please contact your project manager for the laboratory’s 

current list of certified methods and analytes.

TestAmerica Savannah Page 23 of 23

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880 Riverside Parkway West Sacramento, CA 95605 tel 916.373.5600 fax 916.372.1059 www.testamericainc.com

January 3, 2012 

TestAmerica Project Number: G1L140412 

PO/Contract: 4503741800 

Mike Light 

Potesta & Associates Inc 

7012 MacCorkle Avenue, SE 

Charleston, WV 25304 

 

Dear Mr. Light, 

This report contains the analytical results for the sample received under chain of 

custody by TestAmerica on December 13, 2011. This sample is associated with 

your 0101-01-0081 project. 

The test results in this report meet all NELAC requirements for parameters that 

accreditation is required or available. Any exceptions to NELAC requirements are 

noted in the case narrative. The case narrative is an integral part of this report. 

If you have any questions, please feel free to call me at (916) 374-4402. 

Sincerely, 

Jill Kellmann 

Project Manager 

G1L140412 TestAmerica West Sacramento (916) 373 - 5600 1 of 100
Table of Contents

TestAmerica West Sacramento Project Number G1L140412 

 Case Narrative.................................................................................3 

 Sacramento Quality Assurance Program ........................................4 

 Sample Summary............................................................................5 

 Analytical Methods Summary ..........................................................6 

 Method / Analyst Summary .............................................................7 

 Sample Data Sheets........................................................................8 

 WATER, 1613B, 2,3,7,8-TCDD 

 Sample: 1 

 QC Data Association Summary.......................................................9 

 Laboratory QC Reports .................................................................10 

 Raw Data Package........................................................................12 

 Shipping and Receiving Documents.......................................95-100 
Table of Contents

TestAmerica West Sacramento Project Number G1L140412 

 Case Narrative 

 Sacramento Quality Assurance Program 

 Sample Summary 

 Analytical Methods Summary 

 Method / Analyst Summary 

 Sample Data Sheets 

 WATER, 1613B, 2,3,7,8-TCDD 

 Sample: 1 

 QC Data Association Summary 

 Laboratory QC Reports 

 Raw Data Package 

 Shipping and Receiving Documents 

G1L140412 TestAmerica West Sacramento (916) 373 - 5600 2 of 100
Case Narrative

TestAmerica West Sacramento Project Number G1L140412

There are no anomalies associated with this project. 

G1L140412 TestAmerica West Sacramento (916) 373 - 5600 3 of 100
TestAmerica Laboratories West Sacramento Certifications/Accreditations 

Certifying State Certificate # Certifying State Certificate # 

A2LA (DoD-ELAP) 2928-01 New Mexico NA 

Alaska UST-055 New York* 11666 

Arizona AZ0708 Oregon* CA 200005 

Arkansas 88-0691 Pennsylvania* 68-1272 

California* 01119CA South Carolina 87014 

Colorado NA Texas* T104704399-08-TX 

Connecticut PH-0691 UCMR CA00044 

Florida* E87570 US Fish & Wildlife LE148388-0 

Georgia 960 USDA Foreign Plant 37-82605 

Guam 10-009r USDA Foreign Soil P330-09-00055 

Hawaii NA Utah* QUAN1 

Illinois* 002701 Virginia 178 

Kansas* E-10375 Washington C581 

Louisiana* 01944 West Virginia 9930C, 334 

Michigan 9947 Wisconsin 998204680 

Nevada CA44 Wyoming 8TMS-Q 

New Jersey* CA005 

*NELAP accredited. A more detailed parameter list is available upon request. Updated 5/25/2011

QC Parameter Definitions 

QC Batch: The QC batch consists of a set of up to 20 field samples that behave similarly (i.e., same matrix) 

and are processed using the same procedures, reagents, and standards at the same time. 

Method Blank: An analytical control consisting of all reagents, which may include internal standards and 

surrogates, and is carried through the entire analytical procedure. The method blank is used to define the level 

of laboratory background contamination.

Laboratory Control Sample and Laboratory Control Sample Duplicate (LCS/LCSD): An aliquot 

of blank matrix spiked with known amounts of representative target analytes. The LCS (and LCSD as 

required) is carried through the entire analytical process and is used to monitor the accuracy of the analytical 

process independent of potential matrix effects. If an LCSD is performed, it may also be used to evaluate the 

precision of the process.

Duplicate Sample (DU): Different aliquots of the same sample are analyzed to evaluate the precision of an 

analysis.

Surrogates: Organic compounds not expected to be detected in field samples, which behave similarly to 

target analytes. These are added to every sample within a batch at a known concentration to determine the 

efficiency of the sample preparation and analytical process.

Matrix Spike and Matrix Spike Duplicate (MS/MSD): An MS is an aliquot of a matrix fortified with 

known quantities of specific compounds and subjected to an entire analytical procedure in order to indicate the 

appropriateness of the method for a particular matrix. The percent recovery for the respective compound(s) is 

then calculated. The MSD is a second aliquot of the same matrix as the matrix spike, also spiked, in order to 

determine the precision of the method.

Isotope Dilution: For isotope dilution methods, isotopically labeled analogs (internal standards) of the native 

target analytes are spiked into the sample at time of extraction. These internal standards are used for 

quantitation, and monitor and correct for matrix effects. Since matrix effects on method performance can be 

judged by the recovery of these analogs, there is little added benefit of performing MS/MSD for these methods. 

MS/MSD are only performed for client or QAPP requirements.

Control Limits: The reported control limits are either based on laboratory historical data, method 

requirements, or project data quality objectives. The control limits represent the estimated uncertainty of the 

test results.

G1L140412 TestAmerica West Sacramento (916) 373 - 5600 4 of 100
G1L140412 TestAmerica West Sacramento (916) 373 - 5600 5 of 100

Sample Summary 

TestAmerica West Sacramento Project Number G1L140412 

WO# 

MPND6 

Notes(s): 

Sample# Client Sample ID 

1 OUTLET011 

Sampling Date 

12/12/2011 09:55AM 

The analytical results of the samples listed above are presented on the following pages. 

All calculations are performed before rounding to avoid round-off errors in calculated results. 

Results noted as "ND" were not detected at or above the stated limit. 

This report must not be reproduced, except in full, without the written approval of the laboratory. 

Received Date 

12/13/2011 09:15 AM 

Results for the following parameters are never reported on a dry weight basis: color, corrosivity, density, flashpoint, 

ignitability, layers, odor, paint filter test, pH, porosity, pressure, reactivity, redox potential, specific gravity, spot tests, 

solids, solubility, temperature, viscosity, and weight. 
G1L140412 TestAmerica West Sacramento (916) 373 - 5600 6 of 100

PARAMETER 

ANALYTICAL METHODS SUMMARY 

GlL140412 

ANALYTICAL 

METHOD 

Dibenzodioxins and Dibenzofurans, HRGC/HRMS EPA-5 1613B-Tetras 

References: 

EPA-5 "Method 1613: Tetra- through Octa- Chlorinated Dioxins and 

Furans by Isotope Dilution, HRGC/HRMS, Revision B", 

EPA, OCTOBER 1994 
G1L140412 TestAmerica West Sacramento (916) 373 - 5600 7 of 100

MEmOD I ANALYST SUMMARY 

G1L140412 

ANALYTICAL 

~ME~T~H~O~D________________________ AN~~AL~Y~S~T---------------------------

EPA-5 1613B-Tetras Sonia Ouni 

References: 

ANALYST 

ID 

006881 

EPA-5 "Method 1613: Tetra- through Octa- Chlorinated Dioxins and 

Furans by Isotope Dilution, HRGC/HRMS, Revision B", 

EPA, OCTOBER 1994 
G1L140412 TestAmerica West Sacramento (916) 373 - 5600 8 of 100

Lot - Sample # .... : 

Date Sampled .... : 

Prep Date .•.. : 

Prep Batch # ..•. : 

Initial WgWol : 

PARAMETER 

2,3,7,8-TCDD 

G1L140412- 001 

12112/11 

12/21/11 

1355069 

1021.31 mL 

RESULT 

ND 

INTERNAL STANDARDS 

13C-2,3,7,8-TCDD 

SURROGATE 

37CI4-2,3,7,8-TCDD 

QUALIFIERS 

Potesta & Associates Inc 

Sample ID: OUTLET 011 

Trace Level Organic Compounds 

EPA-5 1613B-Tetras 

Work Order# •... : 

Date Received .... : 

Analysis Date .... : 

Instrument ID .... : 

Analyst ID .... : 

MPND61AA 

12113111 

12/27/11 

9D5 

Sonia Ouni 

REPORTING 

LIMIT 

9.8 

PERCENT 

RECOVERY 

68 

PERCENT 

RECOVERY 

89 

Matrix .... : WATER 

Dilution Factor: 

ESTIMATED 

DETECTION LIMIT UNITS 

1.8 pg!L 

RECOVERY 

LIMITS 

31 - 137 

RECOVERY 

LIMITS 

42- 164 

\\qsacsqll \QDSApps\SOG_Stnd\EDL_RL_Report.rpt 12/29/20 II 
G1L140412 TestAmerica West Sacramento (916) 373 - 5600 9 of 100

SAMPLE# 

001 

QC DATA ASSOCIATION SUMMARY 

G1L140412 

Sample Preparation and Analysis Control Numbers 

MATRIX 

WATER 

ANALYTICAL 

METHOD 

EPA-5 1613B-Tetra 

LEACH 

BATCH # 

PREP 

BATCH # 

1355069 

MS RUN# 
G1L140412 TestAmerica West Sacramento (916) 373 - 5600 10 of 100

Lot- Sample# .... : 

Date Sampled ..•• : 

Prep Date •••. : 

Prep Batch # .... : 

Initial WgWol: 

PARAMETER 

2,3,7,8-TCDD 

GlL210000- 069B 

12/09/11 

12/21/11 

1355069 

1000mL 

RESULT 

ND 

INTERNAL STANDARDS 

13C-2,3,7,8-TCDD 

SURROGATE 

37Cl4-2,3,7,8-TCDD 

QUALIFIERS 

Method Blank Report 

Trace Level Organic Compounds 

EPA-5 1613B-Tetras 

Work Order# .... : 

Date Received .... : 

Analysis Date .... : 

Instrument ID .... : 

Analyst ID .... : 

MPT231AA 

12/15/11 

12/23111 

9D5 

Sonia Ouni 

REPORTING 

LIMIT 

10 

PERCENT 

RECOVERY 

41 

PERCENT 

RECOVERY 

91 

Matrix .... : 

Dilution Factor: 

WATER 

1 

ESTIMATED 

DETECTION LIMIT UNITS 

3.2 pg/L 

RECOVERY 

LIMITS 

31 - 137 

RECOVERY 

LIMITS 

42- 164 

\\qsacsqll \QDSApps\SOG_Stnd\EDL_RL_Report.rpt 12/29/2011 
G1L140412 TestAmerica West Sacramento (916) 373 - 5600 11 of 100

Client Lot # ... : 

LCS Lot-Sample# : 

Prep Date ...•.• : 

Prep Batch # ••. : 

Dilution Factor : 

Analyst ID •.•.. : 

Initial Wgt/Vol: 

PARAMETER 

2,3,7,8-1r<:I>I> 

G1L140412 

G1L210000- 069 

12/21/11 

1355069 

Sonia Ouni 

IOOOmL 

SPIKE 

AMOUNT 

200 

200 

INTERNAL STANDARD 

13C-2,3, 7,8-TCDD 

SURROGATE 

37CI4-2,3, 7,8-TCDD 

Notes: 

LABORATORY CONTROL SAMPLE DATA REPORT 

Trace Level Organic Compounds 

Work Order# ... : MPT231AC-LCS 

MPT231AD-LCSD 

Analysis Date .. : 12/23111 

Instrument ID .. : 9D5 Method ..... : 

MEASURED PERCENT 

AMOUNT UNITS RECOVERY 

209 pg/L 104 

217 pg/L 109 

PERCENT 

RECOVERY 

36 

43 

PERCENT 

RECOVERY 

90 

86 

Calculations are performed before rounding to avoid round-off errors in calculated results. 

Bold print denotes control parameters 

Matrix .••...... : WATER 

EPA-5 1613B-Tetr 

RECOVERY 

LIMITS RPD RPDLIMITS 

(73 -146) 

(73- 146) 3.9 (0- 50) 

RECOVERY 

LIMITS 

(25- 141) 

(25- 141) 

RECOVERY 

LIMITS 

(37- 158) 

(37- 158) 

\ \qsacsqii\QDSApps\SOG _ Std\SOG _ Stnd _Icslcd _rev l.rpt 12/29/2011 
G1L140412 TestAmerica West Sacramento (916) 373 - 5600 12 of 100

Raw Data Package 
G1L140412 TestAmerica West Sacramento (916) 373 - 5600 13 of 100

WATER, 16138, 

2,3,7,8-TCDD, WW 
G1L140412 TestAmerica West Sacramento (916) 373 - 5600 14 of 100

ICVJVCV Summaries/ 

Run Logs 
G1L140412 TestAmerica West Sacramento (916) 373 - 5600 15 of 100

Test America- West Sacramento Test America 

Initial Calibration Checklist 

Dioxih Methods THE LEADER IN ENVIRONMENTAL TESTING 

ICALID (lz,~oJ !Lil, ToV4.1 0021]\ Jf.1~As)Jno/J ~()} 

Method ID ~D) I~I3&J Toq> 21) 0011A 

Column ID P R~ 

STD ID·s -n....!..l..::..lt=--o-( £-,-A---, o_J_c...,_)-

) 1 

oc Program _O_G_OO _______ _ 

- - ··-AD.afyied By --'-~_;_'.....:;.C_._. -----

Prepared By --!-M~b ______ _ 

Reviewed By ___ J_f(_B ____ _ 

Date Scanned -------

Instrument ID ----!...:~ 0::.._f__ _ 

STD Solution 1J 0"'~ (21~1 l2D J ll-JJ 221J l'l,~) 

Date Prepared _1'2_ ... /!.._t_o..;___// __ _ 

Date Reviewed __ \ 2_,.j_2 ....... ~1--0.:....:1 (:..___ 

~i~::~~----.~ ~-~~~~:--~~i~~=-i ~~~~-'~.~:~~~;b::f~~~~::~:~~-:J~~·2,~:~.:~-r~~~;~~~-~:i.·~~,:~i~ ·.;~~~&~:~{~-~-~~j~~i~~~~llij~~~~~~~!~~3:li: 

Curve summary present? ./ 

Hardcopies of cbiomatograms for CS 1-CSS present? / 

Copy oflog-file present?· ./ 

Static resolution check present? ./. 

Target file R T' s correct? 7 

%RSD within method-specified limits?* · .7 

Signal-to-noise criteria met? 7 

Isotopic ratios within limits? ~ 

Highpoint free of saturation? ,/ 

Are chromatographic windows correct? ~ 

Manual reintegration•s checked and hardcopies included? NA. 

COMMENTS: 

RT: 

32.: lj() 

*Method 8290/f09/M0023A: %RSD 90% for natives, ~30% for labeled compounds; S/N2:_10 

Method 1613B: o/oRSD~ 20% natives, 90% labeled compounds; SIN 2:10 

Method23: %R$D ~values specified in Table 5, Method23; S/N2:2.5 

N:\Hires\Forms\QA-384 Dioxins ICAL Checklisldoc 

./ 

/ 

.~ ,/ 

./ 

v 

v 

v 

./ 

-v 

tVA 

QA-384 7/25106 DAW 
G1L140412 TestAmerica West Sacramento (916) 373 - 5600 16 of 100

.vata file Smp Work Order 

20DE119D5 1 CP1220 

20DE119D5 2 ST1220 

20DE119D5 3 ST1220A 

20DE119D5 4 ST1220B 

20DE119D5 5 ST1220C 

20DE119D5 6 ST1220D 

20DE119D5 7 ST1220E 

20DE119D5 8 

20DE119D5 9 

20DE119DS 10 

20DE119D5 11 

Sample ID 

DB-5 CPSM 3732-16 

CS-3 11DXN221 

CS-2 11DXN220 

CS-1 11DXN219 

CS-5 11DXN223 

CS-4 11DXN222 

2nd Source 11DXN210 

MG 12/20/11 

FV-uL Method/Matrix Box Size u 

1.00000 

1. 00000 

1.00000 

1.00000 

1.00000 

1.00000 

1. 00000 

1.00000 

1. 00000 

1.00000 

1. 00000 

~~~ \L c~e-ck~ .f 

\d...-J..o-\l 

Stn.A 
G1L140412 TestAmerica West Sacramento (916) 373 - 5600 17 of 100

..... ata file Smp Work Order 

20DE119D5 1 CP1220 

20DE119D5 2 ST1220 

20DE119D5 3 ST1220A 

20DE119D5 4 ST1220B 

20DE119D5 5 ST1220C 

20DE119D5 6 ST1220D 

20DE119D5 7 ST1220E 

20DE119D5 8 

20DE119D5 9 

20DE119D5 10 

20DE119D5 11 

·~ '• L ~ 

Sample ID 

DB-5 CPSM 3732-16 

CS-3 11DXN221 

CS-2 11DXN220 

CS-1 11DXN219 

CS-5 11DXN223 

CS-4 11DXN222 

2nd Source 11DXN210 

MG 12/20/11 

FV-uL Method/Matrix Box Size U 

1.00000 

1.00000 

1.00000 

1.00000 

1. 00000 

1. 00000 

1.00000 

1.00000 

1.00000 

1.00000 

1.00000 

~~~\L c~e-cke_~ 

\~- ,l...o -\.\ 

Sm.A 
G1L140412 TestAmerica West Sacramento (916) 373 - 5600 18 of 100 PPM 200 292.98245 PPM 200 342.97925 PPM 200 392.97604 Peak Locate Examination:20-DEC-2011:08:05 File:20DE119D5 Experiment:DIOXINRES Function:1 Reference:PFK Volts PPM Volts PPM Volts PPM 1.7145 200 ....... 0.3187 200 0.1534 200 w 1\ # \ \ J v\ 304.98245 318.97925 Volts PPM Volts PPM Volts PPM 0.8495 200 0. 2971' 200 0.1839 200 354.97925 366.97925 Volts PPM Volts PPM Volts 0.3754 200 +-+ 0.2875 200 0.1465 rv 4 l \ II \ 404.97604 416.97604 
G1L140412 TestAmerica West Sacramento (916) 373 - 5600 19 of 100 Peak Locate Examination:20-DEC-2011:08:06 File:20DE119D5 Experiment:DIOXINRES Function:2 Reference:PFK 200 0.1437 318.94735 318.97925 319.01115 !PPM Volts 1200 0.3014 I I 354.94375 354.97925 355.01475 PPM Volts 200 0.4294 PPM Volts 200 ....... 0.6886 . I M r \ I _j 330_._94615 PPM 200 - 330. 9792_5__ 331._0_1235. Volts 0.1906 366.94255 366.97925 367.01595 PPM Volts 200 0.3234 PPM 200 _342. 94495 PPM 200 380.93795 PPM 200 342

38

392.93675 392.97604 393.01534 404.93555 404,97604 405.01654 416.93435 41
G1L140412 TestAmerica West Sacramento (916) 373 - 5600 20 of 100 Peak Locate Examination:20-DEC-2011:08:08 File:20DE119D5 Experiment:DIOXINRES Function:3 Reference:PFK PPM Volts 200 0.1887 3_67 ._Q_1595 PPM Volts 200 0.3378 404.93555 404.97604 405.01654 PPM Volts 200 - 0.3092 AI 'lA AI '\ J ' 442_.__92854 442.97284 443.01714 PPM Volts 200 0.4762 3 a_o . 9_3 7 9 5 __J_60. 9_1_60_1_ 381 PPM Volts 200 ,__.... 0.1615 416.93435 416.97604 4_l7. 01_'774 PPM Volts 200 0.2974 454.92734 454.97284 455.01834 PPM 200 392.93675 PPM 200 392

L

.I_ 

1' _

430.92974 430
G1L140412 TestAmerica West Sacramento (916) 373 - 5600 21 of 100 PPM 200 380.93795 PPM 200 416.93435 PPM 200 Peak Locate Exarnination:20-DEC-2011:08:09 File:20DE119D5 Experirnent:DIOXINRES Function:4 Reference:PFK Volts I PPM Volts PPM 0.5193 200 0.4537 200 380.97604 381. 01414_ 392.93675 :392.97604 393.01534 404.93555 40

Volts 0.1651 I PPM Volts 200 0.2726 PPM 200 I ! 416.97604 417.01774 II ( I 92·;J4 430.97284 

44

Volts PPM Volts PPM ,.._. 0.3248 200 0.1230 200 .t \ .fi 'IJI L. \ J ' 454.92734 454.97284 455.01834 466.92614 466.97284 467.01954 1480.92157 48
G1L140412 TestAmerica West Sacramento (916) 373 - 5600 22 of 100 PPM 200 430.92974 PPM 200 466.92614 PPM 200 504.91917 Peak Locate Examination:20-DEC-2011:08:10 File:20DE119D5 Experiment:DIOXINRES Function:5 Reference:PFK Volts PPM Volts PPM 0.3061 200 - 0.3427 200 .f I' '\A 

I l '\ r I \ I 

430.97284 431.01594 442.92854 442.97284 443.01714 454.92734 45

Volts 0.1477 466.97284 467.01954 Volts 0.2549 504.96967 505.02016 PPM 200 Volts I I PPM 0.1630 200 

480.92157 480. 96967 481.017761 1492. 9203 7 49

PPM Volts 200 0.1535 _5J.6. 91797 516.96967 517.02136 
G1L140412 TestAmerica West Sacramento (916) 373 - 5600 23 of 100 PPM 200 PPM 200 I - PPM 200 ...... I \ I ) \ Peak Locate Examination:20-DEC-2011:13:26 File:ENDRES20DE119D5 Experirnent:DIOXINRES Function:1 Reference:PFK Volts PPM Volts PPM Volts PPM 1.5250 200 ...... 0.3609 200 0.1327 200 ) \ 292 304 Volts PPM 0.8299 200 ...... {fl J A. \ II \ 342.97925 -------. -·-- 354.97925 Volts PPM 0.3747 200 392.97604 404.97604 Volts 0.3074 Volts 0.2939 PPM 200 PPM 200 3 ].8__J) 7 9_2 5 366.97925 416.97604 Volts 0.2177 Volts 0.1522 

PPM 200 _____ 
G1L140412 TestAmerica West Sacramento (916) 373 - 5600 24 of 100 PPM 200 318.94735 PPM 200 354.94375 PPM 200 392.93675 Peak Locate Examination:20-DEC-2011:13:26 File:ENDRES20DE119D5 Experiment:DIOXINRES Function:2 Reference:PFK Volts PPM Volts PPM 

0.1104 200 - 0.6849 200 - 

,,( \ r 

1 \A r 

J \ I 

J ) 

318.97925 319.01115 330.94615 330.97925 331.01235 342.94495 342.9

Volts PPM Volts PPM 

0.3095 200 - 0.2072 200 

, 1\ , 

fi \ tl Af "\ J 

.I j 354.97925 355.01475 366.94255 366.97925 367.01595 380.93795 380.9

Volts PPM Volts PPM 

0.3883 200 0.3269 200 

392.97604 393.01534 404.93555 404.97604 416.9
G1L140412 TestAmerica West Sacramento (916) 373 - 5600 25 of 100 PPM 200 _366. 94255 PPM 200 404.93555 PPM 200 442.92854 Peak Locate Examination:20-DEC-2011:13:27 File:ENDRES20DE119D5 Experiment:DIOXINRES Function:3 Reference:PFK Volts 0.1940 PPM Volts 200 0.4427 I PPM 200 -.I {T 

I I 366.97925 367. 01595_ Volts 0.3400 404 ._97604 405. 016_54 Volts 0.3002 442.97284 443.01714 i 1380.93795 36_0. 97604 PPM 200 381.014:1..4 Volts 0.1654 416.93435 416.97604 417.01774 PPM Volts 200 0.2887 454.92734 454.97284 455.01834 I ,I I .A. 392.9

I PPM 

200 

I I 

I I I I I .92974 430.9
G1L140412 TestAmerica West Sacramento (916) 373 - 5600 26 of 100 I PPM 200 Peak Locate Examination:20-DEC-2011:13:27 File:ENDRES20DE119D5 Experiment:DIOXINRES Function:4 Reference:PFK Volts PPM Volts PPM ,.._. 0.4692 200 0.4130 200 

-

,;v \ 

I ) 

I J 

J ,) 

380.93795 

PPM 

200 

380.97604 381.01414 

Volts 

0.1649 

416. 93435 416.97604 417.01774 

PPM Volts 

200 0.3197 

454.92734 454.97284 455.01834 

392.93675 392.97604 393.01534 

PPM Volts 

200 0.2667 

430 ---430.97284 431.01594 

PPM Volts 

200 ,.._. 0.1348 

,, 

1 

tl 

./' 

466.92614 466.97284 467.01954 

404.93555 404.9

PPM 

200 ,.

rr 

I 

J 

442.92854 442.9

PPM 

200 

- 

480.92152 
G1L140412 TestAmerica West Sacramento (916) 373 - 5600 27 of 100 PPM 200 !430. 92974 PPM 200 Peak Locate Examination:20-DEC-2011:13:28 File:ENDRES20DE119D5 Experirnent:DIOXINRES Function:S Reference:PFK 430.97284 Volts 0.2863 431.01594 Volts 0.1497 PPM Volts 200 - 0.3036 rr .f \ f \ J 442.92854 442.97284 443.01714 PPM Volts 200 0.1569 PPM 200 

J 

r1 

454.92734 454.9

PPM 200 466.92614 466.97284 467.01954 480.92157 480.96967 481.01776 492.92037 492.9

PPM Volts PPM Volts 200 0.2610 200 0.1467 i 504.91917 504.96967 . 5.0_5_.02016 516.91797 516.96967 517.02136 
G1L140412 TestAmerica West Sacramento (916) 373 - 5600 28 of 100 P

Run: 20DE119D5 Analyte: 1613 Cal: 1613122011905 ST1220B :CS-1 11DXN219 ST1220A :CS-2 11DXN220 ST1220 :CS-3 11DXN221 ST1220D :CS-4 11DXN222 ST1220C :CS-5 11DXN223 20DE119DS 20DE119D5 20DE119D5 20DE119DS 20DE119D5 S4 S3 S2 S6 ss Name Mean S. D. %'RSD RRF1 RRF2 RRF3 RRF4 RRF5 13C-1,2,3,4-TCDD - - - %' 13C-2,3,7,8-TCDF 1.342 0.030 2.27 %' 1.3S 1.38 1.36 1.31 1.31 2,3,7,8-TCDF 0.846 o.oso S.86 %' 0.84 0.92 0.86 0.80 0.81 Total TCDF 0.846 o.oso S.86 %' 0.84 0.92 0.86 0.80 0.81 13C-2,3,7,8-TCDD 0.906 0.013 1.41 %' 0.91 0.92 0.91 0.90 0.89 2,3,7,8-TCDD 1. 072 O.OS1 4.80 %' 1.10 1.14 1.06 1. 01 1. OS Total TCDD 1.072 O.OS1 4.80 %' 1.10 1.14 1. 06 1.01 1. OS 37Cl-2,3,7,8-TCDD 1.143 O.OS2 4.57 %' 1. 08 1.22 1.1S 1.11 1.14 13C-1,2,3,7,8-PeCDF 0.967 0.027 2.83 %' 0.97 0.98 0.96 0.93 1.00 1,2,3,7,8-PeCDF 1.194 0.063 S.31 % 1.2S 1.26 1.18 1.12 1.14 13C-2,3,4,7,8-PeCDF 0.9SS 0.04S 4.69 %' 1. 01 0.94 0.92 0.91 1.00 2,3,4,7,8-PeCDF 1.173 0.081 6.90 % 1.21 1.30 1.1S 1.10 1.11 Total F2 PeCDF 1.183 0.071 S.98 %' 1.23 1.28 1.17 1.11 1.13 Total F1 PeCDF 1.183 0.071 S.98 %' 1.23 1.28 1.17 1.11 1.13 13C-1,2,3,7,8-PeCDD 0.638 0.022 3.49 %' 0.63 0.63 0.61 0.64 0.67 1,2,3,7,8-PeCDD 1. 003 O.OS7 S.71 %' 1. 06 1. 06 0.98 0.94 0.97 Total PeCDD 1.003 O.OS7 s. 71 % 1. 06 1.06 0.98 0.94 0.97 13C-1,2,3,7,8,9-HxCDD - - - %' 13C-1,2,3,4,7,8-HxCDF 0.944 0.013 1.38 % 0.94 0.96 0.92 0.96 0.94 1,2,3,4,7,8-HxCDF 1.373 0.092 6.68 % 1.43 1.47 1.42 1.28 1.27 13C-1,2,3,6,7,8-HxCDF 1.243 0.084 6.76 % 1.27 1.2S 1.3S 1.22 1.12 1,2,3,6,7,8-HxCDF 1.280 0.086 6.68 %' 1.35 1.40 1.23 1.21 1.22 13C-2,3,4,6,7,8-HxCDF 1.118 0.041 3.67 % 1.13 1.15 1.16 1.09 1.06 2,3,4,6,7,8-HxCDF 1.280 0.081 6.36 % 1.37 1.36 1.26 1.21 1.20 13C-1,2,3,7,8,9-HxCDF 0.959 0.049 S.09 %' 0.96 1.00 1. 01 0.93 0.89 1,2,3,7,8,9-HxCDF 1.260 0.047 3.77 %' 1.33 1.26 1.27 1.21 1.23 
G1L140412 TestAmerica West Sacramento (916) 373 - 5600 29 of 100 Total HxCDF 1.295 0.071 5.52 % 1.37 1.37 1. 28 1.22 1.23 I 13C-1,2,3,4,7,8-HxCDD 0.657 0.035 5.29 % 0.66 0.62 0.63 0.71 0.67 1,2,3,4,7,8-HxCDD 1.193 0.092 7.70 % 1.27 1.31 1.16 1.12 1.11 13C-1,2,3,6,7,8-HxCDD 0.842 0.031 3.64 % 0.82 0.87 0.88 0.81 0.83 1,2,3,6,7,8-HxCDD 1.179 0.130 11.0 % 1.34 1.30 1.12 1.07 1.06 1,2,3,7,8,9-HxCDD 1.394 0.161 11.6 % 1.59 1.52 1.39 1.25 1.22 Total HxCDD 1.255 0.127 10.2 % 1.40 1.38 1.22 1.14 1.13 13C-1,2,3,4,6,7,8-HpCDF 0.935 0.015 1.62 % 0.94 0.94 0.94 0.95 0.91 1,2,3,4,6,7,8-HpCDF 1.500 0.117 7.79 % 1.61 1. 62 1.49 1.39 1.38 13C-1,2,3,4,7,8,9-HpCDF 0.787 0.018 2.27 % 0.80 0.76 0.78 0.81 0.79 1,2,3,4,7,8,9-HpCDF 1.404 0.106 7.54 % 1.51 1.53 1.38 1.31 1.31 Total HpCDF 1.456 0.112 7.69 % 1.57 1.58 1.44 1.35 1.35 13C-1,2,3,4,6,7,8-HpCDD 0.804 0.019 2.32 % 0.81 0.81 0.80 0.82 0.77 1,2,3,4,6,7,8-HpCDD 1.036 0.043 4.19 % 1.07 1.09 1. 02 0.99 1. 01 Total HpCDD 1. 036 0.043 4.19 % 1. 07 1. 09 1. 02 0.99 1.01 13C-OCDD 0.674 0.016 2.32 % 0.68 0.66 0.66 0.68 0.69 OCDF 1.400 0.088 6.31 % 1.47 1.49 1.42 1.32 1. 30 OCDD 1.140 0.078 6.85 % 1.20 1.23 1.14 1. 08 1. OS 
G1L140412 TestAmerica West Sacramento (916) 373 - 5600 30 of 100

Run #1 Filename 20DE119D5 S: 4 I: 1 

Acquired: 20-DEC-11 10:28:35 

Run: 20DE119D5 Analyte: 1613 

Processed: 20-DEC-11 12:36:20 

Cal: 1613122011905 

Comments: 

Sample text: ST1220B :CS-1 11DXN219 

Name 

13C-1,2,3,4-TCDD 

13C-2,3,7,8-TCDF 

2,3,7,8-TCDF 

Total TCDF 

13C-2,3,7,8-TCDD 

2,3,7,8-TCDD 

Total TCDD 

37Cl-2,3,7,8-TCDD 

13C-1,2,3,7,8-PeCDF 

1,2,3,7,8-PeCDF 

13C-2,3,4,7,8-PeCDF 

2,3,4,7,8-PeCDF 

Total F2 PeCDF 

Total F1 PeCDF 

13C-1,2,3,7,8-PeCDD 

1,2,3,7,8-PeCDD 

Total PeCDD 

13C-1,2,3,7,8,9-HxCDD 

13C-1,2,3,4,7,8-HxCDF 

1,2,3,4,7,8-HxCDF 

13C-1,2,3,6,7,8-HxCDF 

1,2,3,6,7,8-HxCDF 

13C-2,3,4,6,7,8-HxCDF 

2,3,4,6,7,8-HxCDF 

13C-1,2,3,7,8,9-HxCDF 

1,2,3,7,8,9-HxCDF 

Total HxCDF 

13C-1,2,3,4,7,8-HxCDD 

1,2,3,4,7,8-HxCDD 

13C-1,2,3,6,7,8-HxCDD 

1,2,3,6,7,8-HxCDD 

1,2,3,7,8,9-HxCDD 

Total HxCDD 

13C-1,2,3,4,6,7,8-HpCDF 

1,2,3,4,6,7,8-HpCDF 

13C-1,2,3,4,7,8,9-HpCDF 

1,2,3,4,7,8,9-HpCDF 

Total HpCDF 

Resp RA RT 

217541500 0.78 y 19:04 

293447000 0.79 ,y 

1234621 0.77 y 

- n 

197322900 0.78 y 

1086958 0.75 y 

- n 

1180110 1. 00 y 

18:29 

18:30 

19:17 

19:18 

19:19 

209998000 1.52 y 24:09 

6584610 1.54 y 24:11 

218634100 1.54 y 25:39 

6599610 1.50 y 25:41 

- n 

- n 

136524400 1.41 y 26:29 

3618840 1.55 y 26:30 

- n 

164571200 1.34 y 32:46 

155136800 0.50 y 31:36 

5529490 1.21 y 31:37 

209106700 0.51 y 31:43 

7037090 1.23 y 31:45 

186202000 0.50 y 32:17 

6386480 1.23 y 32:18 

158624900 0.50 y 32:56 

5289990 1.26 y 32:57 

- n 

108426200 1.33 y 32:26 

3445670 1.13 y 32:26 

135169100 1.34 y 32:31 

4515480 1.16 y 32:31 

4829470 1.19 y 32:47 

- n 

154050500 0.45 y 34:13 

6218710 1.02 y 34:14 

131561800 0.45 y 35:18 

4956400 1.05 y 35:19 

- n 

RRF 

1. 3489 

0.8415 

0.8415 

0.9071 

1.1017 

1.1017 

1. 0850 

0.9653 

1.2542 

1. 0050 

1.2074 

1.2304 

1.2304 

0.6276 

1.0603 

1.0603 

0.9427 

1.4257 

1.2706 

1.3461 

1.1314 

1.3719 

0.9639 

1.3340 

1.3676 

0.6588 

1.2712 

0.8213 

1.3362 

1. 5861 

1.4002 

0.9361 

1.6147 

0.7994 

1.5069 

1. 5651 

100.00 

100.00 

0.50 

0.50 

100.00 

0.50 

0.50 

0.50 

100.00 

2.50 

100.00 

2.50 

2.50 

5.00 

100.00 

2.50 

2.50 

100.00 

Mod? 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

100.00 n 

2.50 n 

100.00 n 

2.50 n 

100.00 n 

2.50 n 

100.00 n 

2.50 n 

10.00 n 

100.00 n 

2.50 n 

100.00 n 

2.50 n 

2.50 n 

7.50 n 

100.00 n 

2.50 n 

100.00 n 

2.50 n 

5.00 n 

Page 1 o 
G1L140412 TestAmerica West Sacramento (916) 373 - 5600 31 of 100

13C-1,2,3,4,6,7,8-HpCDD 133442900 1.02 y 35:00 0.8109 100.00 n 

1,2,3,4,6,7,8-HpCDD 3582440 1.02 y 35:01 1. 0738 2.50 n 

Total HpCDD - n 1. 0738 2.50 n 

13C-OCDD 224374000 0.86 y 37:25 0.6817 200.00 n 

OCDF 8260070 0.90 y 37:32 1.4726 5.00 n 

OCDD 6731210 0.93 y 37:25 1.2000 5.00 n 
G1L140412 TestAmerica West Sacramento (916) 373 - 5600 32 of 100

Run #2 Filename 20DE119D5 S: 3 I: 1 

Acquired: 20-DEC-11 09:45:45 

Run: 20DE119D5 Analyte: 1613 

Processed: 20-DEC-11 12:36:22 

Cal: 1613122011905 

Comments: 

Sample text: ST1220A :CS-2 11DXN220 

Name 

13C-1,2,3,4-TCDD 

13C-2,3,7,8-TCDF 

2,3,7,8-TCDF 

Total TCDF 

13C-2,3,7,8-TCDD 

2,3,7,8-TCDD 

Total TCDD 

37Cl-2,3,7,8-TCDD 

13C-1,2,3,7,8-PeCDF 

1,2,3,7,8-PeCDF 

13C-2,3,4,7,8-PeCDF 

2,3,4,7,8-PeCDF 

Total F2 PeCDF 

Total F1 PeCDF 

13C-1,2,3,7,8-PeCDD 

1,2,3,7,8-PeCDD 

Total PeCDD 

13C-1,2,3,7,8,9-HxCDD 

13C-1,2,3,4,7,8-HxCDF 

1,2,3,4,7,8-HxCDF 

13C-1,2,3,6,7,8-HxCDF 

1,2,3,6,7,8-HxCDF 

13C-2,3,4,6,7,8-HxCDF 

2,3,4,6,7,8-HxCDF 

13C-1,2,3,7,8,9-HxCDF 

1,2,3,7,8,9-HxCDF 

Total HxCDF 

13C-1,2,3,4,7,8-HxCDD 

1,2,3,4,7,8-HxCDD 

13C-1,2,3,6,7,8-HxCDD 

1,2,3,6,7,8-HxCDD 

1,2,3,7,8,9-HxCDD 

Total HxCDD 

13C-1,2,3,4,6,7,8-HpCDF 

1,2,3,4,6,7,8-HpCDF 

13C-1,2,3,4,7,8,9-HpCDF 

1,2,3,4,7,8,9-HpCDF 

Total HpCDF 

13C-1,2,3,4,6,7,8-HpCDD 

1,2,3,4,6,7,8-HpCDD 

Resp RA RT 

210331700 0.77 y 19:04 

290377000 0.79 y 18:29 

5351970 0.78 y 18:30 

- n 

194505700 0.76 y 19:16 

4445750 0.81 y 19:18 

- n 

5152320 1.00 y 19:18 

206697800 1.52 y 24:09 

26114100 1.47 y 24:10 

198354500 1.50 y 25:39 

25725300 1.50 y 25:41 

- n 

- n 

133416500 1.39 y 26:28 

14204160 1.52 y 26:30 

- n 

155059500 1.32 y 32:46 

148122300 0.51 y 

21784140 1.25 y 

193928600 0.51 y 

27074900 1.25 y 

177730600 0.51 y 

24161200 1.25 y 

154927800 0.50 y 

19522620 1. 26 y 

- n 

95714900 1. 34 y 

12527720 1.13 y 

135079200 1.35 y 

17555530 1.17 y 

17566990 1. 26 y 

- n 

145495000 0.44 y 

23600700 1. 03 y 

117821000 0.45 y 

17969920 1. 02 y 

- n 

126041600 1.01 y 

13721690 1. 02 y 

31:36 

31:36 

31:43 

31:44 

32:16 

32:17 

32:56 

32:56 

32:25 

32:26 

32:30 

32:31 

32:46 

34:13 

34:13 

35:18 

35:18 

35:00 

35:00 

RRF 

1.3806 -

0.9216 

0.9216 

0.9248 

1.1428 

1.1428 

1.2248 

0.9827 

1. 2634 

0.9~31 

1.2969 

1.2798 

1.2798 

0.6343 

1. 0646 

1. 0646 

0.9553 

1.4707 

1.2507 

1.3961 

1.1462 

1. 3594 

0.9992 

1.2601 

1.3716 

0.6173 

1. 3089 

0.8711 

1.2996 

1. 5223 

1.3764 

0.9383 

1.6221 

0.7598 

1.5252 

1. 5787 

0.8129 

1. 0887 

100.00 

100.00 

2.00 

2.00 

100.00 

2.00 

2.00 

2.00 

100.00 

10.00 

100.00 

10.00 

10.00 

20.00 

100.00 

10.00 

10.00 

100.00 

100.00 

10.00 

100.00 

10.00 

100.00 

10.00 

100.00 

10.00 

40.00 

100.00 

10.00 

100.00 

10.00 

10.00 

30.00 

100.00 

10.00 

100.00 

10.00 

20.00 

100.00 

10.00 

Mod? 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

Page 2 o 
G1L140412 TestAmerica West Sacramento (916) 373 - 5600 33 of 100

Total HpCDD 

13C-OCDD 

OCDF 

OCDD 

- n 

203359100 0.85 y 37:24 

30361400 0.95 y 37:31 

25065800 0.90 y 37:24 

1. 0887 

0.6557 

1.4930 

1.2326 

10.00 

200.00 

20.00 

20.00 

n 

n 

n 

n 
G1L140412 TestAmerica West Sacramento (916) 373 - 5600 34 of 100

Run #3 Filename 20DE119D5 S: 2 I: 1 

Acquired: 20-DEC-11 08:55:32 

Run: 20DE119D5 Analyte: 1613 

Processed: 20-DEC-11 12:36:24 

Cal: 1613122011905 

Comments: 

Sample text: ST1220 :CS-3 11DXN221 

Name 

13C-1,2,3,4-TCDD 

13C-2,3,7,8-TCDF 

2,3,7,8-TCDF 

Total TCDF 

13C-2,3,7,8-TCDD 

2,3,7,8-TCDD 

Total TCDD 

37Cl-2,3,7,8-TCDD 

13C-1,2,3,7,8-PeCDF 

1,2,3,7,8-PeCDF 

13C-2,3,4,7,8-PeCDF 

2,3,4,7,8-PeCDF 

Total F2 PeCDF 

Total F1 PeCDF 

13C-1,2,3,7,8-PeCDD 

1,2,3,7,8-PeCDD 

Total PeCDD 

13C-1,2,3,7,8,9-HxCDD 

13C-1,2,3,4,7,8-HxCDF 

1,2,3,4,7,8-HxCDF 

13C-1,2,3,6,7,8-HxCDF 

1,2,3,6,7,8-HxCDF 

13C-2,3,4,6,7,8-HxCDF 

2,3,4,6,7,8-HxCDF 

13C-1,2,3,7,8,9-HxCDF 

1,2,3,7,8,9-HxCDF 

Total HxCDF 

13C-1,2,3,4,7,8-HxCDD 

1,2,3,4,7,8-HxCDD 

13C-1,2,3,6,7,8-HxCDD 

1,2,3,6,7,8-HxCDD 

1,2,3,7,8,9-HxCDD 

Total HxCDD 

13C-1,2,3,4,6,7,8-HpCDF 

1,2,3,4,6,7,8-HpCDF 

13C-1,2,3,4,7,8,9-HpCDF 

1,2,3,4,7,8,9-HpCDF 

Total HpCDF 

13C-1,2,3,4,6,7,8-HpCDD 

1,2,3,4,6,7,8-HpCDD 

Resp RA RT 

187978100 0.77 y 19:04 

255266000 0.80 y 18:30 

22046860 0.79 y 18:31 

- n 

171011900 0.77 y 19:17 

18061060 0.81 y 19:18 

- n 

21608000 1.00 y 19:18 

180334900 1.55 y 24:09 

106674000 1.55 y 24:11 

173479400 1.51 y 25:40 

99822800 1.51 y 25:41 

- n 

- n 

115270000 1.40 y 26:29 

56719300 1.51 y 26:31 

- n 

128134900 1.38 y 32:46 

118332500 0.50 y 31:36 

83968200 1.24 y 31:37 

173493400 0.51 y 31:44 

106453500 1.26 y 31:45 

148509100 0.51 y 32:17 

93226500 1.26 y 32:18 

129225000 0.50 y 32:56 

81843300 1.23 y 32:57 

- n 

80834600 1.33 y 32:26 

46930200 1.12 y 32:26 

112391000 1.33 y 32:31 

63176500 1.17 y 32:31 

67220100 1.15 y 32:47 

- n 

120986400 0.45 y 34:13 

90357500 1.04 y 34:14 

100092600 0.45 y 35:19 

68830600 1.03 y 35:19 

- n 

102970800 1.00 y 35:01 

52559900 1.05 y 35:01 

RRF 

1.3580 

0.8637 

0.8637 

0.9097 

1. 0561 

1. 0561 

1.1495 

0.9593 

1.1831 

0. 9229 

1.1508 

1.1673 

1.1673 

0.6132 

0.9841 

0. 9841 

0.9235 

1.4192 

1.3540 

1.2272 

1.1590 

1.2555 

1. 0085 

1.2667 

1.2834 

0.6309 

1.1611 

0.8771 

1.1242 

1. 3915 

1.2236 

0.9442 

1.4937 

0.7812 

1.3753 

1.4401 

0.8036 

1. 0209 

100.00 

100.00 

10.00 

10.00 

100.00 

10.00 

10.00 

10.00 

100.00 

50.00 

100.00 

50.00 

50.00 

100.00 

100.00 

50.00 

50.00 

100.00 

100.00 

50.00 

100.00 

50.00 

100.00 

50.00 

100.00 

50.00 

200.00 

100.00 

50.00 

100.00 

50.00 

50.00 

150.00 

100.00 

50.00 

100.00 

50.00 

100.00 

100.00 

50.00 

Mod? 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

Page 3 o 
G1L140412 TestAmerica West Sacramento (916) 373 - 5600 35 of 100

Total HpCDD 

13C-OCDD 

OCDF 

OCDD 

- n 

169190200 0.85 y 37:25 

120040000 0.92 y 37:32 

96724900 0.90 y 37:26 

1. 0209 

0.6602 

1.4190 

1.1434 

50.00 

200.00 

100.00 

100.00 

n 

n 

n 

n 
G1L140412 TestAmerica West Sacramento (916) 373 - 5600 36 of 100

Run #4 Filename 20DE119D5 S: 6 I: 1 

Acquired: 20-DEC-11 11:54:30 

Run: 20DE119D5 Analyte: 1613 

Processed: 20-DEC-11 12:36:25 

Cal: 1613122011905 

Comments: 

Sample text: ST1220D :CS-4 11DXN222 

Name 

13C-1 12 13 14-TCDD 

13C-2 13 17 18-TCDF 

2 13 17 18-TCDF 

Total TCDF 

13C-2 13 17 18-TCDD 

213 17 18-TCDD 

Total TCDD 

37Cl-2 13 17 18-TCDD 

13C-1121317 18-PeCDF 

1 I 2 1 3 I 7 I 8- PeCDF . 

13C-2 314 7~8-PeCDF 

213141718-PeCDF 

Total F2 PeCDF 

Total F1 PeCDF 

13C-1 7~8-PeCDD 

112131718-PeCDD 

Total PeCDD 

13C-1 12 1317,8,9-HxCDD 

13C-1,2,3,4,7,8-HxCDF 

1,2 13,4,7,8-HxCDF 

13C-1,2 1316,7,8-HxCDF 

1 12 13,6,718-HxCDF 

13C-2,3,4,6,718-HxCDF 

2 13,4 16 17 18-HxCDF 

13C-1,2 13,7,8,9-HxCDF 

1,213 17,8,9-HxCDF 

Total HxCDF 

13C-1,2 13 14,7 18-HxCDD 

1 12,3,4,718-HxCDD 

13C-1,2,3,6,7,8-HxCDD 

1,2,3 16,7 18-HxCDD 

1 12 13 17,8 19-HxCDD 

Total HxCDD 

13C-1,2,3 14 16 17,8-HpCDF 

1 12,3 1416,7,8-HpCDF 

13C-1,2,3,4,7,8,9-HpCDF 

1,2,3 14 17,8,9-HpCDF 

Total HpCDF 

13C-1,2 13,4,6,7,8-HpCDD 

1,2,3,4,6,7,8-HpCDD 

Resp RA RT 

229552000 0.77 y 19:04 

301446000 0.79 y 18:30 

96064100 0.80 y 18:31 

- n 

205666300 0.77 y 19:17 

83047700 0.78 y 19:18 

- n 

102358800 1.00 y 19:18 

212709700 1.51 y 24:09 

478099000 1.52 y 24:11 

207812400 1.51 y 25:39 

458408000 1.51 y 25:41 

- n 

- n 

146882400 1.41 y 26:28 

275118000 1.53 y 26:30 

- n 

155801600 1.33 y 32:46 

148861100 0.51 y 31:36 

380658000 1.23 y 31:37 

189863100 0.52 y 31:43 

458373000 1.25 y 31:45 

170071300 0.50 y 32:17 

410741000 1.23 y 32:18 

144991000 0.52 y 32:56 

350160000 1.24 y 32:56 

- n 

110003400 1.32 y 32:26 

245506000 1.13 y 32:26 

125851300 1.31 y 32:31 

269655000 1.16 y 32:31 

294525000 1.15 y 32:47 

- n 

147488600 0.46 y 34:13 

408865000 1.03 y 34:14 

125520400 0.46 y 35:18 

328581000 1.03 y 35:19 

- n 

127901600 1.00 y 35:00 

252793000 1.06 y 35:01 

RRF 

1.3132 

0.7967 

0.7967 

0.8959 

1.0095 

1. 0095 

1.1148 

0. 9266 

1.1238 

0.9053 

1.1029 

1.1135 

1.1135 

0.6399 

0.9365 

0.9365 

0.9555 

1.2786 

1.2186 

1.2071 

1.0916 

1.2076 

0.9306 

1.2075 

1.2236 

0.7060 

1.1159 

0.8078 

1.0713 

1.2488 

1.1443 

0.9466 

1. 3861 

0.8056 

1. 3089 

1. 3506 

0.8209 

0.9882 

100.00 

100.00 

40.00 

40.00 

100.00 

40.00 

40.00 

40.00 

100.00 

200.00 

100.00 

200.00 

200.00 

400.00 

100.00 

200.00 

200.00 

100.00 

Mod? 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

100.00 n 

200.00 n 

100.00 n 

200.00 n 

100.00 n 

200.00 n 

100.00 n 

200.00 n 

800.00 n 

100.00 

200.00 

100.00 

200.00 

200.00 

600.00 

100.00 

200.00 

100.00 

200.00 

400.00 

100.00 

200.00 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

Page 4 o 
G1L140412 TestAmerica West Sacramento (916) 373 - 5600 37 of 100

Total HpCDD 

13C-OCDD 

OCDF 

OCDD 

- n 

211792900 0.87 y 37:25 

557721000 0.92 y 37:32 

455634000 0.89 y 37:25 

0.9882 

0.6797 

1. 3167 

1. 0757 

200.00 

200.00 

400.00 

400.00 

n 

n 

n 

n 
G1L140412 TestAmerica West Sacramento (916) 373 - 5600 38 of 100

Run #5 Filename 20DE119DS S: 5 I: 1 

Acquired: 20-DEC-11 11:11:39 

Run: 20DE119DS Analyte: 1613 

Processed: 20-DEC-11 12:36:27 

Cal: 1613122011905 

Comments: 

Sample text: ST1220C :CS-5 11DXN223 

Name 

13C-1,2,3,4-TCDD 

13C-2,3,7,8-TCDF 

2,3,7,8-TCDF 

Total TCDF 

13C-2,3,7,8-TCDD 

2,3,7,8-TCDD 

Total TCDD 

37Cl-2,3,7,8-TCDD 

13C-1,2,3,7,8-PeCDF 

1,2,3,7,8-PeCDF 

13C-2,3,4,7,8-PeCDF 

2,3,4,7,8-PeCDF 

Total F2 PeCDF 

Total Fl PeCDF 

13C-1,2,3,7,8-PeCDD 

1,2,3,7,8-PeCDD 

Total PeCDD 

13C-1,2,3,7,8,9-HxCDD 

13C-1,2,3,4,7,8-HxCDF 

1,2,3,4,7,8-HxCDF 

13C-1,2,3,6,7,8-HxCDF 

1,2,3,6,7,8-HxCDF 

13C-2,3,4,6,7,8-HxCDF 

2,3,4,6,7,8-HxCDF 

13C-1,2,3,7,8,9-HxCDF 

1,2,3,7,8,9-HxCDF 

Total HxCDF 

13C-1,2,3,4,7,8-HxCDD 

1,2,3,4,7,8-HxCDD 

13C-1,2,3,6,7,8-HxCDD 

1,2,3,6,7,8-HxCDD 

1,2,3,7,8,9-HxCDD 

Total HxCDD 

13C-1,2,3,4,6,7,8-HpCDF 

1,2,3,4,6,7,8-HpCDF 

13C-1,2,3,4,7,8,9-HpCDF 

1,2,3,4,7,8,9-HpCDF 

Total HpCDF 

13C-1,2,3,4,6,7,8-HpCDD 

1,2,3,4,6,7,8-HpCDD 

Resp RA RT 

231600000 0.78 y 19:05 

303183000 0.79 y 18:30 

490514000 0.81 y 18:31 

- n 

206644200 0.77 y 19:17 

433390000 0.80 y 19:18 

- n 

528682000 1.00 y 19:18 

231464800 1.53 y 24:09 

2645650000 1.52 y 24:11 

231209400 1.53 y 25:40 

2561100000 1.52 y 25:41 

- n 

- n 

155939000 1.41 y 26:29 

1508996000 1.52 y 26:31 

- n 

185109500 1.36 y 32:47 

174836800 0.51 y 

2222985000 1.24 y 

207775600 0.51 y 

2540040000 1.25 y 

196223600 0.52 y 

2360780000 1.24 y 

164918500 0. 51 y 

2033128000 1.25 y 

- n 

123963200 1.33 y 

1373192000 1.15 y 

154242600 1.34 y 

1637105000 1.17 y 

1699926000 1.15 y 

- n 

168251000 0.47 y 

2328290000 1.03 y 

145650400 0.47 y 

1901243000 1.04 y 

- n 

143026800 1.01 y 

1440443000 1.05 y 

31:37 

31:37 

31:44 

31:45 

32:17 

32:18 

32:57 

32:57 

32:26 

32:27 

32:31 

32:32 

32:47 

34:14 

34:14 

35:19 

35:19 

35:01 

35:02 

RRF 

1.3091 

0.8089 

0.8089 

0.8922 

1. 0486 

1. 0486 

1.1414 

0.9994 

1.1430 

0.9983 

1.1077 

1.1254 

1.1254 

0.6733 

0.9677 

0.9677 

0.9445 

1.2715 

1.1224 

1.2225 

1. 0600 

1.2031 

0.8909 

1.2328 

1.2312 

0.6697 

1.1077 

0.8333 

1. 0614 

1.2221 

1.1287 

0.9089 

1. 3838 

0.7868 

1. 3053 

1.3474 

0. 7727 

1. 0071 

Mod? 

100.00 n 

100.00 n 

200.00 n 

200.00 n 

100.00 n 

200.00 n 

200.00 n 

200.00 n 

100.00 n 

1000.00 n 

100.00 n 

1000.00 n 

1000.00 n 

2000.00 n 

100.00 n 

1000.00 n 

1000.00 n 

100.00 

100.00 

1000.00 

100.00 

1000.00 

100.00 

1000.00 

100.00 

1000.00 

4000.00 

100.00 

1000.00 

100.00 

1000.00 

1000.00 

3000.00 

100.00 

1000.00 

100.00 

1000.00 

2000.00 

100.00 

1000.00 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

Page s o 
G1L140412 TestAmerica West Sacramento (916) 373 - 5600 39 of 100

Total HpCDD 

13C-OCDD 

OCDF 

OCDD 

- n 

256618000 0.88 y 37:25 

3336020000 0.92 y 37:32 

2694530000 0.89 y 37:26 

1. 0071 

0.6932 

1. 3000 

1.0500 

1000.00 

200.00 

2000.00 

2000.00 

n 

n 

n 

n 
G1L140412 TestAmerica West Sacramento (916) 373 - 5600 40 of 100 File:20DE119D5 #1-530 Acq:20-DEC-2011 08:12:41 GC Sample#1 Text:CP1220 :DB-5 CPSM 3732-16 319.8965 BSUB(1000,15,-3.0) 100 95 90 85 80 75 70 65 60 55 so 45 40 35 30 25 20 15 10 I EI+ Voltage SIR Autospec-Ultim

Exp:DIOXINRES 

0 

19:06 19:12 19:18 19:24 19:30 
G1L140412 TestAmerica West Sacramento (916) 373 - 5600 41 of 100

Quantitation Summary TestAmerica West Sacramento 

Run text: ST1220E Sample text: ST1220E :2nd Source 11DXN210 

Run #6 Filename: 20DE119D5 S: 7 I: 1 Results: 20DE119D51613 

Acquired: 20-DEC-11 12:37:30 Processed: 20-DEC-11 13:18:16 

Run: 20DE119D5 Analyte: 1613 Cal: 1613122011905 

Factor 1:800.000 Factor 2:20.000 Sample size: 1.000 

Name Resp RA RT RRF 

13C-1,2,3,4-TCDD 173521600 0.78 y 19:05 

13C-2,3,7,8-TCDF 

2,3,7,8-TCDF 

Total TCDF 

13C-2,3,7,8-TCDD 

2,3,7,8-TCDD 

Total TCDD 

37Cl-2,3,7,8-TCDD 

13C-1,2,3,7,8-PeCDF 

1,2,3,7,8-PeCDF 

13C-2,3,4,7,8-PeCDF 

2,3,4,7,8-PeCDF 

Total F2 PeCDF 

Total F1 PeCDF 

13C-1,2,3,7,8-PeCDD 

1,2,3,7,8-PeCDD 

Total PeCDD 

245759000 0.78 y 

22905900 0.81 y 

22905900 0.81 y 

168970800 0.77 y 

20460790 0.81 y 

20592063 2.81 n 

18:30 1.34 

18:30 0.85 

18:30 0.85 

19:17 0.91 

19:18 1.07 

18:30 1.07 

42439200 1.00 y 19:18 1.14 

179334100 1.52 y 24:09 0.97 

60410700 1.49 y 24:10 1.19 

174617100 1.50 y 25:39 0.95 

56997000 1.50 y 25:41 1.17 

117784376 1.49 y 24:10 1.18 

315017 1.90 n 19:04 1.18 

117425300 1.39 y 26:29 0.64 

32616000 1.53 y 26:31 1.00 

32771743 2.73 n 24:09 1.00 

13C-1,2,3,7,8,9-HxCDD 129488600 1.34 y 32:46 

13C-1,2,3,4,7,8-HxCDF 

1,2,3,4,7,8-HxCDF 

13C-1,2,3,6,7,8-HxCDF 

1,2,3,6,7,8-HxCDF 

13C-2,3,4,6,7,8-HxCDF 

2,3,4,6,7,8-HxCDF 

13C-1,2,3,7,8,9-HxCDF 

1,2,3,7,8,9-HxCDF 

Total HxCDF 

13C-1,2,3,4,7,8-HxCDD 

1,2,3,4,7,8-HxCDD 

13C-1,2,3,6,7,8-HxCDD 

1,2,3,6,7,8-HxCDD 

1,2,3,7,8,9-HxCDD 

Total HxCDD 

13C-1,2,3,4,6,7,8-HpCDF 

1,2,3,4,6,7,8-HpCDF 

13C-1,2,3,4,7,8,9-HpCDF 

1,2,3,4,7,8,9-HpCDF 

Total HpCDF 

126772400 0.53 y 31:36 0.94 

51153000 1.23 y 31:37 1.37 

159794000 0.49 y 31:43 1.24 

57455700 1.24 y 31:44 1.28 

139748300 0.51 y 32:17 1.12 

50454000 1.19 y 32:18 1.28 

128136700 0.52 y 32:56 0.96 

45639500 1.25 y 32:57 1.26 

204801388 1.55 n 30:27 1.30 

86458900 1.31 y 32:26 0.66 

28987500 1.11 y 32:26 1.19 

116414600 1.32 y 32:30 0.84 

36814800 1.17 y 32:31 1.18 

39469700 1.15 y 32:47 1.39 

106175131 2.79 n 31:37 1.25 

128734600 0.45 y 34:13 0.93 

55576200 1.02 y 34:1~.5D 

105840300 0.46 y 35:19 0.79 

41400600 1.04 y 35:19 1.40 

96976800 1.02 y 34:14 1.46 

Cone 

80.558 

2110.821 

220.221 flo-/_ 

220.221 

2149.729 

225.966 1 rr/. 

227.416 

427.925 

2138.226 

564.491 

2107.658 

556.463 

1124.552 

3.009 

11 :r/_ 

11 r/_ 

2122.519 

554. o51 111/_ 

556.697 

82.092 

2073.592 

587.715 

1985.152 

561.899 

1931.242 

564.334 

2064.566 

565.265 

2280.318 

2033.983 

562.089 

2135.151 

536.650 

558.201 

1671.132 

2126.959 

575.584 

2078.296 

557.075 

1132.659 

11! j_ 

lfl/. 

Ill-/_ 

tni .. 

Ill)_ 

to1/~ 

111./. 

EDL 

2.466 

3.631 

3.631 

5.334 

1.865 

1.865 

1.355 

3.147 

4.372 

3.186 

4.799 

4.582 

2.973 

2.629 

2.825 

2.825 

2.203 

1.499 

1.673 

1.417 

1.861 

1.436 

2.170 

1.647 

1.494 

4.379 

0.962 

3.414 

0.858 

0.767 

0.852 

9.302 

4.477 

11.055 

6.458 

5.340 

Page 1 o 

Rec M 

105.5 

107.5 

107.0 

106.9 

105.4 

106.1 

103.7 

99.3 

96.6 

103.2 

101.7 

106.8 

106.3 

103.9 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n. 

n' 

n 

n 

n, 

n' 

n, 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 
G1L140412 TestAmerica West Sacramento (916) 373 - 5600 42 of 100

13C-1,2,3,4,6,7,8-HpCDD 109972900 1.00 y 35:00 0.80 2112.174 

11 r)_ 

6.567 105.6 n 

1,2,3,4,6,7,8-HpCDD 31748700 1.05 y 35:00 1.04 557.464 1.940 n 

Total HpCDD 32752977 3.25 n 34:14 1.04 575.098 1.940 n 

13C-OCDD 175595100 0.85 y 37:25 0.67 4023.360 

\o ~ -}_ 

4.162 100.6 n 

OCDF 66630300 0.92 y 37:31 1.40 1083.969 2.333 n 

OCDD 55419200 0.89 y 37:25 1.14 1107.076 ill'/_ 3.160 n 
G1L140412 TestAmerica West Sacramento (916) 373 - 5600 43 of 100

Test America 

THE LEADER IN ENVIRONMENTAL TESTING 

MethodiD J{,)1f1 /,)1£{/e)ro..r) 

Column m___.z;..D~g....;;..~------­

STDID STJl.£..1 

Analyzed by~M..:...::·~G~. -------- Std. Pkg. By---L..M.!..:. ........ G;,_., • ..__ ______ _ 

Std. Pkg. Reviewed By ___ ~l-_r\ ___ _ 

DAILY STANDARD PACKAGE 

Standard, CPSM, and Solvent Blank present? 

Copy of log-file and Beginning Static Resolution present? 

CPSM blow up present? 

Curve Summary present? 

Summary of Method criteria present or docwp.ented below? 

Daily standard within method specified limits?· 

Analyte retention times correct? 

Isotopic ratios within limits? 

CPSM valley~ method specified limits? • 

Are chromatographic windows correct? 

Samples analyzed within 12 brs of daily standard? 

Manual reintegration's checked and hard copies included? 

Ending Standard present? 

Ending Static Resolutions present 

Absolute retention times for 13C12-1,2,3,4-TCDD and 13Cl2-

1,2,3,7,8,9-HxCDD are within+/- 15 seconds of the retention 

times in the Initial Calibration? (required for alll613B samples) 

Test America- West Sacramento 

Daily Calibration Checklist 

Dioxin Methods 

Associated ICAL J LJ'l/1.10 // ~YJ) 

Instrument m_VJ...&.L..P..:...f _______ _ 

STD Solution J/ YJI..NL.-1-} 

Date Analyzed li-z ?A bl . Date Std. Pkg. Assembled,___l-z...~/~_1_~_.') ___ _ 

Date Std. Pkg. Reviewed \"L ["2... '"3/ I ( 

INITIATED REVIEWED 

./ ,/ 

/ yl' 

v' ../ 

/ II' 

./ / 

/ / 

./ / 

..// ../. 

/ ~ 

t/ ./ 

/ v' 

N~ r-Jk 

1'\t\ NP-r 

v/ ../. 

llC-11.1 Lf.:1C-OD f}:O~ r./' 

J I I 

f:tL-111.11 t.~-H1-CD.J 32:¥, 

CO~NTS=--------------------------------------------------------

* Method 8290ff09/M0023A: (beginning)~ 20% from curve RRFs for native analytes, ~ 30% from curve RRFs for labeled 

compounds. 

Method 8290ff09/M0023A: (ending)~ 25% from curve RRFs for native analytes, ~ 35% from curve RRfs for labeled 

compounds. 

Method 23: See Method 23 Daily Standard Criteria, Table 5. 

Method 16138: See, Method 16138 or Method 16138 Tetras Daily Standard Criteria, 

**Method 23/0023A CPSM Criteria: 25% valley between 2378 TCDF (DB-225)ri'CDD (DB-5) and its closest eluters normalized to the 

smallest peak of the triplet . 

Method 1613B/8290!f09 CPSM Criteria: 25% valley between 2378 TCDF (D8-225)ri'CDD (DB-5) and its closest eluters normalized to the 

2378 peak. 

N:\Hires\Forms\QA-231 Dioxin Daily Std Checklist.doc QA-231 8/10/09 DW 
G1L140412 TestAmerica West Sacramento (916) 373 - 5600 44 of 100

Quantitation Summary TestAmerica West Sacramento 

Run text: ST1223 Sample text: ST1223 :CS3 11DXN221 

Run #7 Filen~me: 23DE119D5 S: 2 I: 1 Results: 23DE119D51613 

Acquired: 23-DEC-11 11:57:53 Processed: 23-DEC-11 15:46:49 

Run: 23DE119D5 Analyte: 1613 Cal: 1613122011905 

Factor 1:20.000 Factor 2:1.000 Sample size: 1.000 

Name Resp RA RT RRF 

13C-1,2,3,4-TCDD 108144300 0.76 y 19:04 / 

13C-2,3,7,8-TCDF 142643500 0.80 y 18:29 1.34 

2,3,7,8-TCDF 13418460 0.82 y 18:30 0.85 

Total TCDF 13418460 0.82 y 18:30 0.85 

13C-2,3,7,8-TCDD 99546200 0.76 y 19:16 0.91 

2,3,7,8-TCDD 10036590 0.82 y 19:18 1.07 

Total TCDD 10096411 3.21 n 18:29 1.07 

37Cl-2,3,7,8-TCDD 12697820 1.00 y 19:18 1.14 

13C-1,2,3,7,8-PeCDF 

1,2,3,7,8-PeCDF 

13C-2,3,4,7,8-PeCDF 

2,3,4,7,8-PeCDF 

Total F2 PeCDF 

Total F1 PeCDF 

13C-1,2,3,7,8-PeCDD 

1,2,3,7,8-PeCDD 

Total PeCDD 

13C-1,2,3,7,8,9-HxCDD 

13C-1,2,3,4,7,8-HxCDF 

1,2,3,4,7,8-HxCDF 

13C-1,2,3,6,7,8-HxCDF 

1,2,3,6,7,8-HxCDF 

13C-2,3,4,6,7,8-HxCDF 

2,3,4,6,7,8-HxCDF 

13C-1,2,3,7,8,9-HxCDF 

103707400 1.46 y 24:08 0.97 

64557600 1.59 y 24:10 1.19 

104233600 1.49 y 25:38 0.95 

61622700 1.53 y 25:40 1.17 

127480382 2.58 n 22:06 1.18 

103623 2.27 n 19:04 1.18 

83336400 1.49 y 26:27 0.64 

35403700 1.47 y 26:29 1.00 

35521037 2.34 n 24:09 1.00 

82208800 1. 32 y 32:46 / -

86536600 0.51 y 31:36 0.94 

55907900 1.21 y 31:36 1.37 

114331200 0.51 y 31:43 1.24 

64735200 1.22 y 31:44 1.28 

98746700 0.52 y 32:16 1.12 

57907000 1.21 y 32:17 1.28 

93640300 0.53 y 32:56 0.96 

1,2,3,7,8,9-HxCDF 54499400 1.23 y 32:56 1.26 

Total HxCDF 233198690 1.52 n 30:26 1.30 

13C-1,2,3,4,7,8-HxCDD 

1,2,3,4,7,8-HxCDD 

13C-1,2,3,6,7,8-HxCDD 

1,2,3,6,7,8-HxCDD 

1,2,3,7,8,9-HxCDD 

Total HxCDD 

13C-1,2,3,4,6,7,8-HpCDF 

1,2,3,4,6,7,8-HpCDF 

13C-1,2,3,4,7,8,9-HpCDF 

1,2,3,4,7,8,9-HpCDF 

Total HpCDF 

54948800 1. 34 y 

33778600 1.15 y 

69429300 1. 34 y 

41521300 1.20 y 

44145100 1.17 y 

119445000 1.15 y 

32:26 0.66 

32:26 1.19 

32:30 0.84 

32:31 1.18 

32:46 1.39 

32:26 1.25 

77771800 0.43 y 34:13 0.93 

60716300 1.05 y 34:13 1.50 

71345700 0.45 y"~5T1~9 

50897800 1.04 y 35:19 1.40 

112584708 1.05 y 34:13 1.46 

Cone 

50.206 

98.291 

11.113 

11.113 

101.605 

9.407 

9.463 

10.272 

99.202 

52.157 

100.935 

50.393 

103.607 

0.084 

120.849 

42.371 

42.511 

52.118 

111.476 

47.050 

111.862 

44.242 

107.472 

45.832 

118.823 

46.183 

183.424 

101.807 

51.530 

100.288 

50.743 

50.917 

153.189 

101.197 

52.044 

110.334 

50.800 

103.737 

EDL 

0.091 

0.195 

0.195 

0.225 

0.086 

0.086 

0.051 

0.220 

0.183 

0.222 

0.194 

0.188 

0.108 

0.087 

0.136 

0.136 

0.133 

0.041 

0.101 

0.039 

0.112 

0.040 

0.131 

0.044 

0.041 

0.172 

0.035 

0.134 

0.034 

0.029 

0.033 

0.652 

0.213 

0. 775 

0.277 

0.2.42 

Page 2 o 

Rec 

98.3 

101.6 

102.7 

99.2 

100.9 

120.8 

111.5 

111.9 

107.5 

118.8 

101.8 

100.3 

101.2 

110.3 

M 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 
G1L140412 TestAmerica West Sacramento (916) 373 - 5600 45 of 100

13C-1,2,3,4,6,7,8-HpCDD 75541400 1.00 y 35:00 0.80 114.265 0.466 114.3 n 

1,2,3,4,6,7,8-HpCDD 36964100 1.06 y 35:01 1.04 47.243 0.175 n 

Total HpCDD 37146563 1.05 y 34:28 1.04 47.477 0.175 n 

13C-OCDD 116183400 0.82 y 37:24 0.67 209.654 0.220 104.8 n 

OCDF 90667400 0.91 y 37:31 1.40 111.464 0.116 n 

OCDD 72106700 0.95 y 37:25 1.14 108.851 0.174 n 
G1L140412 TestAmerica West Sacramento (916) 373 - 5600 46 of 100

Data file Smp Work Order Sample ID FV-uL Method/Matrix Box Size u 

23DE119DS 1 CP1223 DB-5 CPSM 3732-16 1.00000 

23DE119D5 2 I ST1223 CS3 11DXN221 1.00000 

23DE119D5 3 MPT3V-1-AA G1L210000-79B 20 8290/SOLID 62 10.00000 g 

23DE119D5 4 MPT23-1-AA G1L210000-69B 20 1613B/WATER 1. 00000 L 

23DE119D5 5 Needle "Z"ed 0.00000 

23DE119DS 6 MPRTK-1-AA G1L190443-1 20 8290/SOLID 10.21000 g 

23DE119D5 7 MPQNA-1-AC G1L160524-1 20 8290/SOLID 10.06000 g 

23DE119D5 8 MPQNC-1-AC G1L160524-2 20 8290/SOLID 10.40000 g 

23DE119D5 9 MPQND-1-AC G1L160524-3 20 8290/SOLID 10.15000 g 

23DE119D5 10 MPQNE-1-AC G1L160524-4 20 8290/SOLID 10.01000 g 

23DE119D5 11 MPQNG-1-AC G1L160524-5 20 8290/SOLID 10.44000 g 

23DE119D5 12 MPQNH-1-AC G1L160524-6 20 8290/SOLID 10.82000 g 

23DE119D5 13 MPT3V-1-AC G1L210000-79C 20 8290/SOLID 10.00000 g 

23DE119D5 14 MPT3V-1-AD G1L210000-79L 20 8290/SOLID 10.00000 g 

23DE119DS 15 ST1223A CS3 11DXN221 1. 00000 

23DE119D5 16 1.00000 

23DE119DS 17 1. 00000 

23DE119DS 18 1.00000 

23DE119D5 19 MG 12/23/11 

j ... ~ '"' 

1.00000 

1(\.\9. \~~' .. ~,, \...0~ \')' 

.---
G1L140412 TestAmerica West Sacramento (916) 373 - 5600 47 of 100

Data file Smp Work Order Sample ID FV-uL Method/Matrix Box Size u 

23DE119D5 1 CP1223 DB-5 CPSM 3732-16 1.00000 

23DE119D5 2 ST1223 CS3 11DXN221 1.00000 

23DE119D5 3 MPT3V-l-AA G1L210000-79B 20 8290/SOLID 62 10.00000 g 

23DE119D5 4 MPT23-l-AA G1L210000-69B 20 1613B/WATER 1.00000 L 

23DE119D5 5 Needle "Z"ed 0.00000 

23DE119D5 6 MPRTK-1-AA G1L190443-1 20 8290/SOLID 10.21000 g 

23DE119D5 7 MPQNA-1-AC G1L160524-1 20 8290/SOLID 10.06000 g 

23DE119DS 8 MPQNC-1-AC G1L160524-2 20 8290/SOLID 10.40000 g 

23DE119DS 9 MPQND-1-AC G1L160524-3 20 8290/SOLID 10.15000 g 

23DE119D5 10 MPQNE-1-AC G1L160524-4 20 8290/SOLID 10.01000 g 

23DE119DS 11 MPQNG-1-AC G1Ll60524-5 20 8290/SOLID 10.44000 g 

23DE119D5 12 MPQNH-1-AC G1L160524-6 20 8290/SOLID 10.82000 g 

23DE119D5 13 MPT3V-1-AC GlL210000-79C 20 8290/SOLID 10.00000 g 

23DE119D5 14 MPT3V-1-AD G1L210000-79L 20 8290/SOLID 10.00000 g 

23DE119DS 15 ST1223A CS3 11DXN221 1.00000 

23DE119DS 16 1.00000 

23DE119D5 17 1.00000 

23DE119D5 18 1.00000 

23DE119D5 19 MG 12/23/11 

j ... ~ "'' 

1.00000 

\\,\9. \ 't "J (1,' \~~ \')-
G1L140412 TestAmerica West Sacramento (916) 373 - 5600 48 of 100 I PPM 200 I l 292.98245 PPM 200 ...... r\ \ j \ J \ --- PPM 200 ...... J rr \A .J '\ l 392.97604 ---- Peak Locate Examination:23-DEC-2011:11:10 File:23DE119D5 Experiment:DIOXINRES Function:1 Reference:PFK Volts PPM 1.1509 200 Volts PPM 0.5100 200 --- Volts PPM 0.2310 I 200 Volts ...... 0.2450 304.98245__ Volts 0.1845 Volts 0.1771 404.97604 PPM 200 PPM 200 PPM 200 Volts ...... 0.0966 ,MM Ill It ,) ,, 318.97925 Volts ._. 0.1242 IIJ "l, I .. w 366.97925 416.97604 Volts 0.0968 PPM 200 I PPM 200 
G1L140412 TestAmerica West Sacramento (916) 373 - 5600 49 of 100 1 PPM 1 ,200 ........ I M tj N Peak Locate Exarnination:23-DEC-2011:11:12 File:23DE119D5 Experirnent:DIOXINRES Function:2 Reference:PFK Volts PPM Volts PPM 0.0983 200 ........ 0.4967 200 t H. \ ) 1. 

j 

r 

J .l jy 318.94735 318.97925 011_:1..5 _330. 94615 330.97925 331.01235 342.94495 342

PPM Volts PPM Volts PPM 

200 ........ 0.2099 200 ........ 0.1391 200 

fH"M 

J f\1 J

J /' 

) \ JV 354.94375 354.97925 355.01475 366.94255 366.97925 367.01595 380.93795 380

PPM Volts PPM Volts PPM 

200 0.2838 200 0.2037 200 

392.93675 392.97604 393.01534 404.93555 404.97604 405.01654 416. 93435 __ 416

I 

-L - - -
G1L140412 TestAmerica West Sacramento (916) 373 - 5600 50 of 100 PPM goo ..-. I M . . l Peak Locate Examination:23-DEC-2011:11:13 File:23DE119D5 Experiment:DIOXINRES Function:3 Reference:PFK Volts PPM Volts PPM 0.1337 200 +-t 0.3614 200 .!I .. nl \ 

l

,( 

fi' \ j .J \ ) v\ J 366.94255 366.97925 367.01595 PPM Volts 200 0.2203 404.93555 404.97604 405.01654 PPM Volts 200 ,..._. 0.2292 442.92854 442.97284 443.01714 ' I 380.93795 PPM 200 416.93435 PPM 200 380.97604 381.01414 Volts 0.1091 416. 97E)Q-4 __ _i17. 01774 Volts 0.2018 454.92734 454.97284 455.01834 392.93675 392

PPM 200 

f

l 

Jf' 430.92974 430
G1L140412 TestAmerica West Sacramento (916) 373 - 5600 51 of 100 f>PM 00 1380.93795 PPM 200 416.93435 PPM 200 454.92734 I I Peak Locate Examination:23-DEC-2011:11:13 File:23DE119D5 Experiment:DIOXINRES Function:4 Reference:PFK Volts PPM Volts PPM 

0.3721 200 - 0.3437 200 

I Jl \ })' \ 380.97604 381.01414 392.93675 392.97604 393.01534 404.93555 404

Volts PPM Volts PPM 

0.1087 200 ,__. 0.1958 200 

tJ J

l 11 IY /fJ ,\, 

l '\ ; 416.97604 417.01774 430.92974 430.97284 431.01594 442.92854 442

Volts PPM Volts PPM 

0.2043 200 ,__. 0.0893 200 

Jl1l' N [£ill I ! !'' A/ X 

454.97284 455.01834 1466.92614 466.97284 467.01954 !480. 92157 480
G1L140412 TestAmerica West Sacramento (916) 373 - 5600 52 of 100 fPM 200 430.92974 l?PM 2oo Peak Locate Examination:23-DEC-2011:11:14 File:23DE119D5 430.97284 _, lX\. .I l Experiment:DIOXINRES Function:5 Reference:PFK Volts :PPM Volts 0.2266 200 0.2589 431.01594 4AA. 9.2S.54 443.01714 Volts PPM Volts 0.1100 200 0.1061 200 

_l 

l 

1 

454.92734 454

PPM 200 11

l 

f1 h/ 

A.tY1 I' J, 

466.92614 466.97284 467.01954 480.92157 480.96967 481.01776 492.92037 492

PPM Volts PPM Volts 200 0.1701 200 _, 0.1021 r I -,Nv '\ )v 504.91917 504. 9696_? _ 5Q5. 0201._6 5_16. 96967 517.02136 
G1L140412 TestAmerica West Sacramento (916) 373 - 5600 53 of 100 I i k ' r PrM 2po ! I 1 ' i l I 'I I II;• I " A -"" l':f8o. 97604 f i SIRLM Exarnination:23-DEC-2011:14:07 File:23DE119DS Experirnent:DIOXINRES Function:6 (v rJ v \ \ ( ( \n y AA ; IV \j'J v J'-V\ 1\ A./\ J 

380.97604 
G1L140412 TestAmerica West Sacramento (916) 373 - 5600 54 of 100 ? f f i PPM 200 ·• ' j " : ; I .1 I _Jj04_. 9_825_1_ SIRLM Examination:23-DEC-2011:14:08 File:23DE119D5 Experiment:DIOXINRES Function:? N u ' A v \ tl \ A)v \ IAf\ 

A. v 

- ---- -- -- -- 304.98251 
G1L140412 TestAmerica West Sacramento (916) 373 - 5600 55 of 100 > Pag

Run: 23DE119DS Analyte: 1613 Cal: 1613122011905 8T1220B :C8-1 11DXN219 8T1220A :C8-2 11DXN220 8T1220 :C8-3 11DXN221 8T1220D :C8-4 11DXN222 8T1220C :C8-5 11DXN223 20DE119DS 20DE119D5 20DE119DS 20DE119DS 20DE119DS 84 83 82 86 85 Name Mean 8. D. %R8D RRF1 RRF2 RRF3 RRF4 RRFS 13C-1 12 13 14-TCDD - - - % 13C-2 13 17 18-TCDF 1.342 0.030 2.27 % 1.35 1.38 1.36 1.31 1.31 2 13 17 18-TCDF 0.846 0.050 5.86 % 0.84 0.92 0.86 0.80 0.81 Total TCDF 0.846 0.050 5.86 % 0.84 0.92 0.86 0.80 0.81 13C-2 13 17 18-TCDD 0.906 0.013 1.41 % 0.91 0.92 0.91 0.90 0.89 2 13 17 18-TCDD 1.072 0.051 4.80 % 1.10 1.14 1.06 1.01 1.05 Total TCDD 1.072 0.051 4.80 % 1.10 1.14 1.06 1.01 1. OS 37Cl-2 13 17 18-TCDD 1.143 0.052 4.57 % 1. 08 1.22 1.15 1.11 1.14 13C-1 12 13 17 18-PeCDF 0.967 0.027 2.83 % 0.97 0.98 0.96 0.93 1.00 1 12 13 17 18-PeCDF 1.194 0.063 5.31 % 1.25 1.26 1.18 1.12 1.14 13C-2 13 14 17 18-PeCDF 0.955 0.045 4.69 % 1. 01 0.94 0.92 0.91 1.00 2 13 14 17 18-PeCDF 1.173 0.081 6.90 % 1.21 1.30 1.15 1.10 1.11 Total F2 PeCDF 1.183 0.071 5.98 % 1.23 1.28 1.17 1.11 1.13 Total F1 PeCDF 1.183 0.071 5.98 % 1.23 1.28 1.17 1.11 1.13 13C-112 13 17 18-PeCDD 0.638 0.022 3.49 % 0.63 0.63 0.61 0.64 0.67 11:2 1 3 1 7 1 8- PeCDD 1.003 0.057 5.71 % 1. 06 1. 06 0.98 0.94 0.97 Total PeCDD 1.003 0.057 5.71 % 1.06 1. 06 0.98 0.94 0.97 13C-1 12 1 '3 1 7 1 8 1 9-HxCDD - - - % 13C-1 12/3 14 17 18-HxCDF 0.944 0.013 1.38 % 0.94 0.96 0.92 0.96 0.94 1.373 0.092 6.68 % 1.43 1.47 1.42 1.28 1.27 13C-11 21:31 617 I 8-HxCDF 1.243 0.084 6.76 % 1.27 1.25 1.35 1.22 1.12 1 12 13 16 17 18-HxCDF 1.280 0.086 6.68 " 1.35 1.40 1.23 1.21 1.22 13C-2 13 14 16 17 18-HxCDF 1.118 0.041 3.67 % 1.13 1.15 1.16 1.09 1.06 2 13 14 16 17 18-HxCDF 1.280 0.081 6.36 " 1.37 1.36 1.26 1.21 1.20 13C-1 12 13 17 18 19-HxCDF 0.959 0.049 5.09 " 0.96 1. 00 1. 01 0.93 0.89 1 12 13 17 18 19-HxCDF 1.260 0.047 3.77 " 1.33 1. 26 1.27 1.21 1.23 
G1L140412 TestAmerica West Sacramento (916) 373 - 5600 56 of 100 Total HxCDF 1.295 0.071 5.52 t 1.37 1.37 1.28 1.22 1.23 13C-1,2,3,4,7,8-HxCDD 0.657 0.035 5.29 t 0.66 0.62 0.63 0. 71 0.67 1,2,3,4,7,8-HxCDD 1.193 0.092 7.70 t 1.27 1.31 1.16 1.12 1.11 13C-1,2,3,6,7,8-HxCDD 0.842 0.031 3.64 t 0.82 0.87 0.88 0.81 0.83 1,2,3,6,7,8-HxCDD 1.179 0.130 11.0 t 1.34 1.30 1.12 1.07 1.06 1,2,3,7,8,9-HxCDD 1.394 0.161 11.6 t 1.59 1.52 1.39 1.25 1.22 Total HxCDD 1.255 0.127 10.2 t 1.40 1. 38 1.22 1.14 1.13 13C-1, 2,3 '.,4, 6, 7, 8-HpCDF 0.935 0.015 1.62 t 0.94 0.94 0.94 0.95 0.91 1,2,3,4,6,7,8-HpCDF 1.500 0.117 7.79 t 1.61 1. 62 1.49 1.39 1.38 13C-1,2,3,4,7,8,9-HpCDF 0.787 0.018 2.27 t 0.80 0.76 0.78 0.81 0.79 1,2,3,4,7,8,9-HpCDF 1.404 0.106 7.54 t 1.51 1.53 1.38 1.31 1.31 Total HpCDF 1.456 0.112 7.69 t 1.57 1.58 1.44 1.35 1.35 13C-1, 2, 3 ,.4, 6, 7, 8-HpCDD 0.804 0.019 2.32 % 0.81 0.81 0.80 0.82 0. 77 1,2,3,4,6,7,8-HpCDD 1. 036 0.043 4.19 t 1.07 1.09 1.02 0.99 1.01 Total HpCDD 1. 036 0.043 4.19 % 1. 07 1.09 1.02 0.99 1. 01 13C-OCDD 0.674 0.016 2.32 t 0.68 0.66 0.66 0.68 0.69 OCDF 1.400 0.088 6.31 % 1.47 1.49 1.42 1.32 1. 30 OCDD 1.140 0.078 6.85 t 1.20 1.23 1.14 1. 08 1. OS 
G1L140412 TestAmerica West Sacramento (916) 373 - 5600 57 of 100

::--e ~':- ·stAmerlca .. _-_- ; --____ -____ :_ ,- ___ ,_.,- ·----_ .i 

:'THE LEADER IWENVIRONME.NT.AL." l'.ESTJ!iiG 

Compound OPR VER 

% ng/ml 

CS3 

16138 Acceptance Criteria 

.13C-2",3, 7,8-TCDF 22-152 71-140 

2,3,7,8-TCDF 75-158 8.4- 12.0 

13C-2,3,7,8-TCDD 20-175 82 -121 

2,3,7,8-TCDD 67- 158 7.8- 12.9 

37CI4-2,3, 7,8-TCDD 31 - 191 7.9 -12.7 

13C-1,2,3,7,8-PeCDF 21 - 192 76-130 

1 ,2,3, 7,8-PeCDF 80- 134 41 -60 

13C-2,3,4,7,8-PeCDF 13- 328 77 -130 

2,3,4, 7,8-PeCDF 68-160 41-61 

13C-1 ,2,3, 7,8-PeCDD 21-227 62-160 

1 ,2-,3,7,8-PeCDD 70-142 39-65 

13C-1,2,3,4,7,8-HxCDF 19- 202 76-131 

1 ,2,3,4,7,8-HxCDF 72- 134 45-56 

13C-1 ,2,3,6,7,8-HxCDF 21 -159 70-143 

1,2,3,6,7,8-HxCDF 84- 130 44-57 

13C-2,3,4,6,7,8-HxCDF 22-176 73-137 

2,3,4,6,7,8-HxCDF 70- 156 44-57 

13C-1,2,3,7,8,9-HxCDF 17-205 74-135 

1 ,2,3,7,8,9-HxCDF 78- 130 45-56 

13C-1 ,2,3,4,7,8-HxCDD 21 -193 85 -117 

1 ,2,3,4,7,8-HxCDD 70-164 39-64 

13C-1,2,3,6,7,S-HxCDD 25 -163 85 -118 

1 ,2,3,6,7 ,8-HxCDD 76-134 39-64 

1 ,2,3, 7 ,8,9-HxCDD 64-162 41-61 

13C-1 ,2,3,4,6,7,8-HpCDF 21 -158 78-129 

1 ,2,3,4,6,7 ,8-HpCDF 82-122 45-55 

13C-1,2,3,4, 7 ,8,9-HpCDF 20 -186 77-129 

1,2,3,4,7,8,9-HpCDF 78-138 43-58 

13C-1,2,3,4,6,7,8-HpCDD 26-166 72-138 

1,2,3,4,6,7,8-HpCDD 70- 140 43-58 

13C-OCDD 13 -199 96-415 

OCDF 63- 170 63-159 

OCDD 78- 144 79-126 

16138 Acceptance Criteria for Tetras Only Analysis 

13C-2,3-,7,8-TCDF 26-126 76 -131 

2,3, 7,8-TCDF 80- 147 8.6-11.6 

13C-2,3,7,8-TCDD 25 -141 85 -117 

2,3, 7,8-TCDD 73- 146 8.2- 12~3 

37-CI4-2,3, 7,8-TCDD 37-158 8.3 -12.1 

Q:\FORMS\Qa-HR-1 00 16138 criteria.xls Page 1 of 1 

West Sacramento 

Method 16138 Acceptance Criteria 

Based on Tables 6, 6A and 7 of the method 

VER 

ng/ml 

CS2 

71-140 

1.68-2.40 

82 -121 

1.56-2.58 

1.58- 2..54 

76-130 

8.20-12.0 

77-130 

8.20- 12.2 

62- 160 

7.80-13.0 

76 -131 

9.00-11.2 

70-143 

8.80-11.4 

73-137 

8.80-11.4 

74-135 

9.00-11.2 

85 -117 

7.80-12.8 

85 -118 

7.80-12.8 

8.20- 12.2 

-18-129 

9.00-11.0 

77 -129 

8.60- 11.6 

72-138 

8.60-11.6 

96 -415 

12.60-31.8 

15.80-25.2 

76 -131 

1.72-2.32 

85-117 

1.64-2.46 

1.66-2.42 

VER 

ng/ml 

CS4 

71-140 

33.6-48 

82-121 

31.2-51.6 

31.6-50.8 

76-130 

164-240 

77-130 

164-244 

62-160 

156-260 

76 -131 

180-224 

70-143 

176-228 

73-137 

176-228 

74-135 

180-224 

85- 117 

156-256 

85 -118 

156-256 

164-244 

.. 78-129 

"180-220 

77-129 

172-232-

72-138 

172-232 

96-415 

252-636 

316-504 

76 -131 

34.4-46.4 

85-117 

32-.8-49.2 

33.2-48.4 

Field Samples 

ng/ml 

24-169 

25-164 

3.5-19.7 

24-185 

21 -178 

25-181 

26-152 

26-123 

28-136 

29--147 

32 -141 

28-130 

28-143 

.26-138 

23-140 

34-313 

29-140 

31 -137 

4.2 -16.4 

QA-HR-100 

06/2712011 ERS 
G1L140412 TestAmerica West Sacramento (916) 373 - 5600 58 of 100 File:23DE119D5 #1-530 Acq:23-DEC-2011 11:15:15 GC EI+ Voltage SIR Autospec-UltimaE Sample#1 Text:CP1223 :DB-5 CPSM 3732-16 Exp:DIOXINRES 321.8936 BSUB(1000,15,-3.0) 100 19:10 , ....... -- 95 90 85 v 

80 

75 

70 

65 60 

55 

50 

45 

40 2,3,7,8-TCDD 

3S 

30 

25 

' 20 

15 

10 

5 
G1L140412 TestAmerica West Sacramento (916) 373 - 5600 59 of 100

TestAmerica 

THE LEADER IN ENVIRONMENTAL TESTING 

Method m----:1_, ,__;-1 g~j-l b_/1_:..._R (:o......:.._+~il.J'__.:_) --

Column ID.____:D;.....;E___;)::;__ ______ _ 

STD ID fT } 1,;1.. 1.. 

Analyzed by 8 .M, 

Std. Pkg. By MJG. 

Std. Pkg. Reviewed By J~ DAILY STANDARD PACKAGE 

Standard, CPSM, and Solvent Blank present? 

Copy of log-file and Beginning Static Resolution present? 

CPSM blow up present? 

Curve Summary present? 

Summary of Method criteria present or docurp.ented below? 

Daily standard within method specified limits?" 

Analyte retention times correct? 

Isotopic ratios within limits? 

CPSM valley < method specified limits?·• 

Are chromatographic windows correct? 

Samples analyzed within 12 brs of daily standard? 

Manual reintegration's checked andhardcopies included? 

Ending Standard present? 

Ending Static Resolutions present 

Absolute retention times for 13C12-1,2,3,4-TCDD and 13Cl2-

1,2,3,7,8,9-HxCDD are within+/- 15 seconds of the retention 

times in the Initial Calibration? (required for all1613B samples) 

Test America- West Sacramento 

Daily Calibration Checklist 

Dioxin Methods 

Associated ICAL J {,(5 }'Lto /1~0~ 

Instrument ID_..L.;~P;.__f _______ _ 

STD Solution }} D"' tj 21 ) 

Date Analyzed j?, /z.a./n 

Date Std. Pkg. Assembled r]., /z.:t./1, 

Date Std. Pkg. Reviewed (L/b'3j{l 

I I 

INITIATED REVIEWED 

../, ,./ 

~ / 

./ / 

/ / 

./ / 

./ c/ 

./ / 

/ ~ 

./ / 

/, / 

/ ./ 

..AK ./ '/1..-D ./ 

"A 11-/lJilJ NA 

/ v - / c/ 

11L- J,'J~, 't-rcJJD f ~=ot 

11e--1. t ~ 1 t~-R.,.c.D.D J 7..: 'fl. , 

CO~NTS:---------------------------------------------------------

* Method 8290!f09/M0023A: (beginning) ~ 20% from curve RRFs for native analytes, ~ 30% from curve RRFs for labeled 

compounds. 

Method 8290/T09/M0023A: (ending) S 25% from curve RRFs for native analytes, S 35% from curve RRFs for labeled 

compounds. 

Method 23: See Method 23 Daily Standard Criteria, Table 5. 

Method 16138: See, Method 16138 or Method 16138 Tetras Daily Standard Criteria, 

**Method 23/0023A CPSM Criteria: 25% valley between 2378 TCDF (DB-225)trCDD (DB-5) and its closest eluters normalized to the 

smallest peak of the triplet . 

Method 1613B/8290!f09 CPSM Criteria: 25% valley between 2378 TCDF (DB-225)/TCDD (DB-5) and its closest eluters normalized to the 

2378 peak. 

N:\Hires\Forms\QA-231 Dioxin Daily Std Checklist.doc QA-231 8/10/09 DW 
G1L140412 TestAmerica West Sacramento (916) 373 - 5600 60 of 100

Quantitation Summary TestAmerica West Sacramento 

Run text: ST1222 Sample text: ST1222 :CS3 11DXN221 

Run #7 Filename: 22DE119D5 S: 2 I: 1 Results: 22DE119D51613 

Acquired: 22-DEC-11 22:51:26 Processed: 23-DEC-11 11:44:28 

Run: 22DE119D5 Analyte: 1613 Cal: 1613122011905 

Factor 1:20.000 Factor 2:1.000 Sample size: 1.000 

Name Resp RA RT RRF 

13C-1,2,3,4-TCDD 154368700 0.78 y 19:06 

13C-2,3,7,8-TCDF 217382600 0.82 y 18:31 1.34 

2,3,7,8-TCDF 20986430 0.78 y 18:32 0.85 

Total TCDF 20986430 0.78 y 18:32 0.85 

13C-2,3,7,8-TCDD 142438500 0.77 y 19:18 0.91 

2,3,7,8-TCDD 14944790 0.81 y 19:19 1.07 

Total TCDD 15054919 2.62 n 18:31 1.07 

37Cl-2,3,7,8-TCDD 17798800 1.00 y 19:19 1.14 

13C-1,2,3,7,8-PeCDF 

1,2,3,7,8-PeCDF 

13C-2,3,4,7,8-PeCDF 

164071700 1.51 y 24:09 0.97 

96058700 1.51 y 24:11 1.19 

161095900 1.52 y 25:39 0.95 

2,3,4,7,8-PeCDF 92649000 1.53 y 25:41 1.17 

Total F2 PeCDF 189914834 0.81 n 23:31 1.18 

Total F1 PeCDF * * n NotFnd 1.18 

13C-1,2,3,7,8-PeCDD 112366200 1.45 y 26:29 0.64 

1,2,3,7,8-PeCDD 55722200 1.52 y 26:31 1.00 

Total PeCDD 55966093 2.98 n 24:11 1.00 

13C-1,2,3,7,8,9-HxCDD 124792800 1.38 y 32:46 

13C-1,2,3,4,7,8-HxCDF 

1,2,3,4,7,8-HxCDF 

13C-1,2,3,6,7,8-HxCDF 

1,2,3,6,7,8-HxCDF 

13C-2,3,4,6,7,8-HxCDF 

2,3,4,6,7,8-HxCDF 

13C-1,2,3,7,8,9-HxCDF 

1,2,3,7,8,9-HxCDF 

Total HxCDF 

13C-1,2,3,4,7,8-HxCDD 

1,2,3,4,7,8-HxCDD 

13C-1,2,3,6,7,8-HxCDD 

1,2,3,6,7,8-HxCDD 

1,2,3,7,8,9-HxCDD 

Total HxCDD 

13C-1,2,3,4,6,7,8-HpCDF 

1,2,3,4,6,7,8-HpCDF 

13C-1,2,3,4,7,8,9-HpCDF 

1,2,3,4,7,8,9-HpCDF 

Total HpCDF 

127946900 0.50 y 31:37 0.94 

79210200 1.18 y 31:38 1.37 

170787200 0.52 y 31:43 1.24 

100513600 1.21 y 31:44 1.28 

151329700 0.49 y 32:18 1.12 

91088200 1.19 y 32:18 1.28 

125878200 0.52 y 32:56 0.96 

74357100 1.20 y 32:57 1.26 

345366829 1.04 n 30:28 1.30 

86432700 1.36 y 32:26 0.66 

45475600 1.14 y 32:27 1.19 

97686100 1.36 y 32:31 0.84 

63910900 1.18 y 32:31 1.18 

65875800 1.17 y 32:47 1.39 

175500828 3.94 n 31:37 1.25 

118190400 0.44 y 34:14 0.93 

88841900 1.04 y 34:14 1.50 

103732400 0.44 y 35:19 6.79 

74216400 1.05 y 35:19 1.40 

163058300 1.04 y 34:14 1.46 

Cone 

71.666 

104.938 

11.405 

11.405 

101.851 

9.790 

9.862 

10.087 

109.948 

49.055 

109.285 

49.023 

98.705 

* 

114.154 

49.459 

49.675 

79.115 

108.578 

45.086 

110.078 

45.986 

108.499 

47.043 

105.225 

46.873 

185.094 

105.494 

44.104 

92.954 

55.512 

51.327 

151.150 

101.311 

50.110 

105.678 

50.946 

101.056 

EDL 

0.194 

0.346 

0.346 

0.328 

0.176 

0.176 

0.109 

0.218 

0.326 

0.221 

0.350 

0.338 

0.171 

0.161 

0.178 

0.178 

0.189 

0.105 

0.144 

0.094 

0.160 

0.098 

0.186 

0.124 

0.104 

0.384 

0.076 

0.300 

0.075 

0.064 

0.071 

1. 061 

0.168 

1.260 

0.236 

0.198 

Page 2 of 

Rec M 

104.9 

101.9 

100.9 

109.9 

109.3 

114.2 

108.6 

110.1 

108.5 

105.2 

105.5 

93.0 

101.3 

105.7 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

y 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 
G1L140412 TestAmerica West Sacramento (916) 373 - 5600 61 of 100

13C-1,2,3,4,6,7,8-HpCDD 105418300 0.99 y 35:00 0.80 105.044 0.587 105.0 n 

1,2,3,4,6,7,8-HpCDD 55197200 1.05 y 35:01 1.04 50.553 0.324 n 

Total HpCDD 55433777 1.20 n 34:29 1.04 50.770 0.324 n 

13C-OCDD 162821300 0.82 y 37:25 0.67 193.553 0.238 96.8 n 

OCDF 121169200 0.90 y 37:31 1.40 106.294 0.206 n 

OCDD 100007300 0.95 y 37:25 1.14 107.726 0.338 n 
G1L140412 TestAmerica West Sacramento (916) 373 - 5600 62 of 100

Quantitation Summary TestAmerica West Sacramento 

Run text: ST1222 Sample text: ST1222 :CS3 11DXN221 

Run #7 Filename: 22DE119D5 S: 2 I: 1 Results: 22DE119D51613 

Acquired: 22-DEC-11 22:51:26 Processed: 23-DEC-11 11:44:28 

Run: 22DE119D5 Analyte: 1613 Cal: 1613122011905 

Factor 1:20.000 Factor 2:1.000 Sample size: 1.000 

Name Resp RA RT RRF 

13C-1,2,3,4-TCDD 154368700 0.78 y 19:06 

13C-2,3,7,8-TCDF 

2,3,7,8-TCDF 

Total TCDF 

13C-2,3,7,8-TCDD 

2,3,7,8-TCDD 

Total TCDD 

37Cl-2,3,7,8-TCDD 

13C-1,2,3,7,8-PeCDF 

1,2,3,7,8-PeCDF 

13C-2,3,4,7,8-PeCDF 

2,3,4,7,8-PeCDF 

Total F2 PeCDF 

Total F1 PeCDF 

13C-1,2,3,7,8-PeCDD 

1,2,3,7,8-PeCDD 

Total PeCDD 

217382600 0.82 y 18:31 1.34 

20986430 0.78 y 18:32 0.85 

20986430 0.78 y 18:32 0.85 

142438500 0.77 y 19:18 0.91 

14944790 0.81 y 19:19 1.07 

15054919 2.62 n 18:31 1.07 

17798800 1.00 y 19:19 1.14 

164071700 1.51 y 24:09 0.97 

96058700 1.51 y 24:11 1.19 

161095900 1.52 y 25:39 0.95 

92649000 1.53 y 25:41 1.17 

189914834 0.81 n 23:31 1.18 

* * n NotFnd 1.18 

112366200 1.45 y 26:29 0.64 

55722200 1.52 y 26:31 1.00 

55966093 2.98 n 24:11 1.00 

13C-1,2,3,7,8,9-HxCDD 112999712 1.43 n 32:46 

13C-1,2,3,4,7,8-HxCDF 

1,2,3,4,7,8-HxCDF 

13C-1,2,3,6,7,8-HxCDF 

1,2,3,6,7,8-HxCDF 

13C-2,3,4,6,7,8-HxCDF 

2,3,4,6,7,8-HxCDF 

13C-1,2,3,7,8,9-HxCDF 

1,2,3,7,8,9-HxCDF 

Total HxCDF 

13C-1,2,3,4,7,8-HxCDD 

1,2,3,4,7,8-HxCDD 

13C-1,2,3,6,7,8-HxCDD 

1,2,3,6,7,8-HxCDD 

1,2,3,7,8,9-HxCDD 

Total HxCDD 

13C-1,2,3,4,6,7,8-HpCDF 

1,2,3,4,6,7,8-HpCDF 

13C-1,2,3,4,7,8,9-HpCDF 

1,2,3,4,7,8,9-HpCDF 

Total HpCDF 

127946900 0.50 y 31:37 0.94 

79210200 1.18 y 31:38 1.37 

170787200 0.52 y 31:43 1.24 

100513600 1.21 y 31:44 1.28 

151329700 0.49 y 32:18 1.12 

91088200 1.19 y 32:18 1.28 

125878200 0.52 y 32:56 0.96 

74357100 1.20 y 32:57 1.26 

345366829 1.04 n 30:28 1.30 

86432700 1.36 y 32:26 0.66 

45475600 1.14 y 32:27 1.19 

97686000 1.36 y 32:31 0.84 

63910900 1.18 y 32:31 1.18 

65875800 1.17 y 32:47 1.39 

175500828 3.94 n 31:37 1.25 

118190400 0.44 y 34:14 0.93 

88841900 1.04 y 34:14 1.50 

103732400 0.44 y 35:19 0.79 

74216400 1.05 y 35:19 1.40 

163058300 1.04 y 34:14 1.46 

13C-1,2,3,4,6,7,8-HpCDD 105418300 0.99 y 35:00 0.80 

Cone 

71.666 

104.938 

11.405 

11.405 

101.851 

9.790 

9.862 

10.087 

109.948 

49.055 

109.285 

49.023 

98.705 

* 

114.154 

49.459 

49.675 

71.639 

119.909 

45.086 

121.566 

45.986 

119.823 

47.043 

116.206 

46.873 

185.094 

116.504 

44.104 

102.654 

55.512 

51.327 

151.150 

111.885 

50.110 

116.707 

50.946 

101. 056 

116.007 

EDL 

0.194 

0.346 

0.346 

0.328 

0.176 

0.176 

0.109 

0.218 

0.326 

0.221 

0.350 

0.338 

0.171 

0.161 

0.178 

0.178 

0.205 

0.105 

0.156 

0.094 

0.173 

0.098 

0.202 

0.124 

0.104 

0.416 

0.076 

0.324 

0.075 

0.064 

0.071 

1.148 

0.168 

1.364 

0.236 

0.198 

0.635 

Page 2 of 

Rec M 

104.9 

101.9 

100.9 

109.9 

109.3 

114.2 

119.9 

121.6 

119.8 

116.2 

116.5 

102.7 

111.9 

116.7 

116.0 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 

n 
G1L140412 TestAmerica West Sacramento (916) 373 - 5600 63 of 100

1,2,3,4,6,7,8-HpCDD 55197200 LOS y 35:01 1.04 50.553 0.324 n 

Total HpCDD 55433777 1.20 n 34:29 1.04 50.770 0.324 n 

13C-OCDD 162821300 0.82 y 37:25 0.67 213.753 0.257 106.9 n 

OCDF 121169200 0.90 y 37:31 1.40 106.294 0.206 n 

OCDD 100007300 0.95 y 37:25 1.14 107.726 0.338 n 
G1L140412 TestAmerica West Sacramento (916) 373 - 5600 64 of 100

Data file Smp Work Order Sample ID FV-uL Method/Matrix Box Size u 

22DE119D5 1 CP1222 08-5 CPSM 3732-16 1. 00000 

22DE119D5 2 STl222 CS3 11DXN221 1. 00000 

22DE119D5 3 S81222 Solvent Blank C-14 1. 00000 

22DE119D5 4 MPT23-1-AA G1L210000-69B 20 16138-Tetras/11 62 1.00000 L 

22DE119D5 5 MPT23-1-AC G1L210000-69C 20 16138-Tetras/11 1.00000 L 

22DE119D5 6 MPT23-1-AD G1L210000-69L 20 1613B-Tetras/1J 1. 00000 L 

22DE119D5 7 MPNW6-1-AA G1L140474-1 20 1613B/WATER 0.84984 L 

22DE119D5 8 MPNWV-1-AA G1L140471-1 20 1613B/WATER 1. 02501 L 

22DE119D5 9 MPNWW-1-AA G1L140471-2 20 16138/WATER 1.01825 L 

22DE119D5 10 MPK9H-1-AA G1L120423-1 20 16138/WATER 1.06542 L 

22DE119D5 11 MPKQK-1-AA G1L090466-1 20 16138/WATER 1.04682 L 

22DE119D5 12 MPMOH-1-AC G1L130476-2 20 8290/SOLID 61 10.09000 g 

22DE119D5 13 MPMOH-1-AD G1L130476-2S 20 8290/SOLID 10.17000 g 

22DE119D5 14 MPMOH-1-AE G1L130476-2D 20 8290/SOLID 10.15000 g 

22DE119D5 15 ST1222A CS3 11DXN221 1. 00000 

22DE119D5 16 

re viewtJ 

1. 00000 

22DE119D5 17 1.00000 

22DE119D5 18 1.00000 

22DE119D5 19 AM 12/22/11 

" 

1.00000 

"'.6 ,J'tl/;J 
G1L140412 TestAmerica West Sacramento (916) 373 - 5600 65 of 100

Data file Smp Work Order Sample ID FV-uL Method/Matrix Box Size u 

22DE119D5 1 CP1222 DB-5 CPSM 3732-16 1.00000 

22DE119D5 2 ST1222 CS3 11DXN221 1.00000 

22DE119D5 3 SB1222 Solvent Blank C-14 1.00000 

22DE119D5 4 MPT23-1-AA G1L210000-69B 20 1613B-Tetras/i1 62 1. 00000 L 

22DE119D5 5 MPT23-1-AC G1L210000-69C 20 1613B-Tetras/i1 1.00000 L 

22DE119D5 6 MPT23-1-AD G1L210000-69L 20 1613B-Tetras/i1 1.00000 L 

22DE119D5 7 MPNW6-1-AA G1L140474-1 20 1613B/WATER 0.84984 L 

22DE119D5 8 MPNWV-1-AA G1L140471-1 20 1613B/WATER 1.02501 L 

22DE119D5 9 MPNWW-1-AA G1L140471-2 20 1613B/WATER 1.01825 L 

22DE119D5 10 MPK9H-1-AA G1L120423-1 20 1613B/WATER 1. 06542 L 

22DE119D5 11 MPKQK-1-AA G1L090466-1 20 1613B/WATER 1.04682 L 

22DE119D5 12 MPMOH-1-AC G1L130476-2 20 8290/SOLID 61 10.09000 g 

22DE119D5 13 MPMOH-1-AD G1L130476-2S 20 8290/SOLID 10.17000 g 

22DE119D5 14 MPMOH-1-AE G1L130476-2D 20 8290/SOLID 10.15000 g 

22DE119D5 15 ST1222A CS3 11DXN221 1. 00000 

22DE119D5 16 

review~) 1. 00000 

22DE119D5 17 1.00000 

22DE119D5 18 1.00000 

22DE119D5 19 AM 12/22/11 

~ 1.00000 

fo-6 

rJt-1/;; 
G1L140412 TestAmerica West Sacramento (916) 373 - 5600 66 of 100 PPM 200 ...... ( p \ r \ _I I_ _ _____2_2_ 2 • !:)_ 8 2 4 5 PPM 200 ...... ( \ J \ ; _j '\l - PPM 200 ...... 392.97604 Peak Locate Examination:22-DEC-2011:22:01 File:22DE119D5 Experiment:DIOXINRES Function:1 Reference:PFK Volts PPM Volts 3.2052 200 ...... 0.5274 \ J \ u \ )' \ 304.98245 Volts PPM Volts 1.3393 200 0.4463 3 5_4_. 9 7 51:2_5 __ Volts PPM Volts 0.6854 200 ...... 0.4379 404.97604 PPM 200 PPM 200 PPM 200 318.97925 416.97604 Volts 0.2617 Volts 0.2579 Volts 0.1917 PPM 200 I I PPM 200 
G1L140412 TestAmerica West Sacramento (916) 373 - 5600 67 of 100 Peak Locate Examination:22-DEC-2011:22:03 File:22DE119D5 Experiment:DIOXINRES Function:2 Reference:PFK I PPM Volts 200 0.2642 I I I I '*------+----J'-'-1-...lb-----+-----1 r ·11 cb r I Yhb.= I 318.94735 318.97925 319.01115 

i " 

PPM Volts 

200 - 0.4445 

J ' ./ 

354.94375 354.97925 355.01475 

PPM Volts 

200 - 0. 7604 

\ 

!'' '''\ 

392.93675 392.97604 393.01534 

PPM 

200 

330.94615 

PPM 

200 

330.97925 

WI _\ 

J I l 

Volts 

1.1283 

Volts 

0.2553 

L I ., 

366.94255 366.97925 367.01595 

PPM Volts 

200 0.4741 

404.93555 404.97604 405. QJ.654 

PPM 

200 

J! 

J 

I 

342.94495 342

PPM 

200 

J 

t 

f 

380.93795 380

PPM 

200 

416.93435 416
G1L140412 TestAmerica West Sacramento (916) 373 - 5600 68 of 100 Peak Locate Examination:22-DEC-2011:22:05 File:22DE119D5 Experiment:DIOXINRES Function:3 Reference:PFK !PPM Volts! ;200 0.2677 PPM Volts 200 0.8338 I PPM 

200 

i 

{'

I r 

/v 366.94255 366.97925 367.01595 380.93795 380.97604 36_1. Q_14:JA 392

PPM Volts PPM Volts PPM 

200 0.5051 200 0.2218 200 

404.93555 404.97604 405.01654 416.93435 416.97604 417.01774 430.92974 _43Q

PPM Volts PPM Volts 200 +--+ 0.5377 200 0.4393 ,.r \ j \ .I 442.92854 442.97284 443.01714 454.92734 454. 97284_ 455.01834 
G1L140412 TestAmerica West Sacramento (916) 373 - 5600 69 of 100 f,PPM ' '200 380.93795 PPM 200 416.93435 PPM 200 454.92734 ,___. rt r \ Peak Locate Examination:22-DEC-2011:22:06 File:22DE119D5 Experiment:DIOXINRES Function:4 Reference:PFK Volts PPM Volts PPM 0.8672 200 ,___. 0.8857 200 I '\ j \n t \ ./ '\ I \ .J 380.97604 381.01414 392.93675 392.97604 393.01534 404.93555 40

Volts PPM Volts PPM 0.2251 200 .......... 0.4720 200 

r \, II 'l N 

./ \ . J 

I j' \ .I I 416.97604 417.01774 1430.92974 431.01594 442.92854 44

Volts PPM Volts PPM 

0.5129 200 - 0.1953 200 

454.97284 455.01834 466.92614 466.97284 467.01954 480.92157 48
G1L140412 TestAmerica West Sacramento (916) 373 - 5600 70 of 100 PPM 200 430.92974 PPM 200 466.92614 PPM 200 504.91917 Peak Locate Examination:22-DEC-2011:22:07 File:22DE119D5 Experiment:DIOXINRES Function:5 Reference:PFK Volts PPM Volts PPM 0.5328 200 0.6115 200 430.97284 431.01594 442.92854 442 ._97284 443.01714 454.92734 454

Volts PPM Volts PPM 0.2199 200 0.2856 200 

.. f 

.I 

466.97284 467.01954 480.92157 480.96967 481.01776 492.92037 492

Volts PPM Volts 0.3965 200 0.2231 504.96967 505.02016 516.91797 516.96967 517.02136 
G1L140412 TestAmerica West Sacramento (916) 373 - 5600 71 of 100 PPM 200 ...... f1 J \ .! '\ 292.98245 PPM 200 342.97925 PPM 200 ....... ' .f .J \ 392.97604 Peak Locate Examination:23-DEC-2011:09:03 File:ENDRES22DE119D

Experiment:DIOXINRES Function:1 Reference:PFK Volts PPM Volts PPM Volts PPM 1.0620 200 ...... 0.1993 200 0.0814 200 ./ n r,)' \ 304.98245 318.97925 Volts PPM Volts PPM Volts PPM 0.4737 200 0.1609 200 ...... 0.1146 200 354.97925 366.97925 Volts PPM Volts PPM Volts 0.1989 200 ....... 0.1589 200 ...... 0.0773 i 1 u \ 1i1 i j v I l n If I ) \ lrl.J ul\.A 404.97604 41(:).97604_ ---- 
G1L140412 TestAmerica West Sacramento (916) 373 - 5600 72 of 100 I I i PPM 200 kj . J Peak Locate Examination:23-DEC-2011:09:04 File:ENDRES22DE119D

Experiment:DIOXINRES Function:2 Reference:PFK Volts PPM Volts PPM .......... 0.0862 200 .......... 0.4173 200 

lN ! 

) r V\A I I 

_;) :\ I I 

I 3113.94735 318.97925 319.01115 330.94615 330.97925 331.01235 1342.94495 34

PPM Volts PPM Volts PPM 200 0.1594 200 .......... 0.1076 200 

'" J :vv IV r I' .#_ ;JU 

:354.94375 354. 355.01475 366.94255 366.97925 367.01595 380.93795 38

PPM Volts PPM Volts PPM 200 .......... 0.2295 200 .......... 0.1684 200 

¥\ 

l' \ I M '\ 

I ,,, fl '\A 

/ '\ J '\ lA I 392.93675 392.97604 393.01534 404.93555 404.97604 405.01654 416.93435 41
G1L140412 TestAmerica West Sacramento (916) 373 - 5600 73 of 100 PPM 200 366.94255 PPM 200 Peak Locate .Examination:23-DEC-2011:09:04 File:ENDRES22DE119D

Experiment:DIOXINRES Function:3 Reference:PFK Volts PPM - 0.1214 200 366.97925 367.01595 380.93795 3 80 Volts PPM - 0.2006 200 -hiJ' J ,, I f -v\ ) Volts 0.2944 381.01414 Volts 0.0810 PPM 200 

I )v 

) 93675 PPM 200 39

.r 

_r 

}J .r .LV 

404.93555 404.97604 405.01654 93435 416.97604 417.01774 430.92974 43

PPM Volts PPM Volts 200 +-+ 0.1893 200 +-+ 0.1586 Mv r· I' JV \ II (lj· If\ ) \\ J 442.92854 442.97284 443.01714 454.92734 454.97284 455.01834 
G1L140412 TestAmerica West Sacramento (916) 373 - 5600 74 of 100 PPM 200 380.93795 PPM 200 416.93435 PPM 200 Peak Locate Examination:23-DEC-2011:09:04 File:ENDRES22DE119D

Experiment:DIOXINRES Function:4 Reference:PFK Volts PPM Volts PPM .......... 0.3056 200 .......... 0.2892 200 

/MM Mw # Y\J nf J 

j r ,f 

.r ' J ' I 

380 .Q_7Q04 .3_92.93675 392.97604 393.01534 404.93555 404

Volts PPM Volts PPM .......... 0.0869 200 .......... 0.1653 200 

!A 1Ltt 

r J r j r v l « jr' ) }'¥ 416.97604 417.01774 430.92974 430.97284 431.01594 442.92854 442

Volts PPM Volts PPM 

- 0.1646 200 .......... 0.0666 200 

t' Mh, 

l 'r 1.1 11 

IV 

dl k j 

I J) \ .. 

!454. 92734 454.97284 455.01834 466.92614 466.97284 467.01954 480.92157 480
G1L140412 TestAmerica West Sacramento (916) 373 - 5600 75 of 100 PPM 200 430.92974 PPM 200 466. PPM 200 504.91917 Peak Locate Examination:23-DEC-2011:09:05 File:ENDRES22DE119D

Experiment:DIOXINRES Function:5 Reference:PFK Volts 0.1916 430.97284 431.01594 Volts 0.0907 466.97284 __ 4:67. 01954 Volts 0.1383 504. 9Q_967 __ 5Q5. 02016 PPM 200 92854 PPM 200 ......... fl 'fl y· I \ 442.97284 Volts 0.2212 443.01714 Volts 0.0957 480.92157 480.96967 481.01776 PPM Volts 200 ......... 0.0868 IN f' . . '\A 516. 9_1]97 _5_16. 96967 517.02136 PPM 

200 

N

J J 

454.92734 45

PPM 

200 

1492.92037 
G1L140412 TestAmerica West Sacramento (916) 373 - 5600 76 of 100 Pa

Run: 22DE119DS Analyte: 1613 Cal: 1613122011905 8T1220B :C8-1 11DXN219 8T1220A :C8-2 11DXN220 8T1220 :C8-3 11DXN221 8T1220D :CS-4 11DXN222 8T1220C :C8-5 11DXN223 20DE119D5 20DE119D5 20DE119D5 20DE119D5 20DE119D5 84 83 82 86 85 Name Mean S. D. %RSD RRF1 RRF2 RRF3 RRF4 RRFS 13C-1,2,3,4-TCDD - - - % 13C-2,3,7,8-TCDF 1.342 0.030 2.27 % 1.35 1.38 1. 36 1.31 1.31 2,3,7,8-TCDF 0.846 0.050 5.86 % 0.84 0.92 0.86 0.80 0.81 Total TCDF 0.846 0.050 5.86 % 0.84 0.92 0.86 0.80 0.81 13C-2,3,7,8-TCDD 0.906 0.013 1.41 % 0.91 0.92 0.91 0.90 0.89 2,3,7,8-TCDD 1.072 0.051 4.80 % 1.10 1.14 1.06 1. 01 1.05 Total TCDD 1.072 0.051 4.80 % 1.10 1.14 1. 06 1. 01 1. OS 37Cl-2,3,7,8-TCDD 1.143 0.052 4.57 % 1. 08 1.22 1.15 1.11 1.14 13C-1,2,3,7,8-PeCDF 0.967 0.027 2.83 % 0.97 0.98 0.96 0.93 1.00 1,2,3,7,8-PeCDF 1.194 0.063 5.31 % 1.25 1.26 1.18 1.12 1.14 13C-2,3,4,7,8-PeCDF 0.955 0.045 4.69 % 1.01 0.94 0.92 0.91 1. 00 2,3,4,7,8-PeCDF 1.173 0.081 6.90 % 1.21 1.30 1.15 1.10 1.11 Total F2 PeCDF 1.183 0.071 5.98 % 1.23 1.28 1.17 1.11 1.13 Total F1 PeCDF 1.183 0.071 5.98 % 1.23 1. 28 1.17 1.11 1.13 13C-1,2,3,7,8-PeCDD 0.638 0.022 3.49 % 0.63 0.63 0.61 0.64 0.67 1,2,3,7,8-PeCDD 1. 003 0.057 5. 71 % 1. 06 1. 06 0.98 0.94 0.97 Total PeCDD 1. 003 0.057 5.71 % 1. 06 1. 06 0.98 0.94 0.97 13C-1,2,3,7,8,9-HxCDD - - - % 13C-1,2,3,4,7,8-HxCDF 0.944 0.013 1.38 % 0.94 0.96 0.92 0.96 0.94 1,2,3,4,7,8-HxCDF 1.373 0.092 6.68 % 1.43 1.47 1.42 1.28 1.27 13C-1,2,3,6,7,8-HxCDF 1.243 0.084 6.76 % 1.27 1.25 1.35 1.22 1.12 1,2,3,6,7,8-HxCDF 1.280 0.086 6.68 % 1.35 1.40 1.23 1.21 1.22 13C-2,3,4,6,7,8-HxCDF 1.118 0.041 3.67 % 1.13 1.15 1.16 1. 09 1. 06 2,3,4,6,7,8-HxCDF 1.280 0.081 6.36 % 1.37 1.36 1. 26 1.21 1. 20 13C-1,2,3,7,8,9-HxCDF 0.959 0.049 5.09 % 0.96 1. 00 1. 01 0.93 0.89 1,2,3,7,8,9-HxCDF 1.260 0.047 3.77 % 1.33 1.26 1.27 1.21 1.23 
G1L140412 TestAmerica West Sacramento (916) 373 - 5600 77 of 100 Total HxCDF 1.295 0.071 5.52 % 1. 37 1.37 1.28 1.22 1. 23 13C-1,2,3,4,7,8-HxCDD 0.657 0.035 5.29 % 0.66 0.62 0.63 0. 71 0.67 1,2,3,4,7,8-HxCDD 1.193 0.092 7.70 % 1.27 1.31 1.16 1.12 1.11 13C-1,2,3,6,7,8-HxCDD 0.842 0.031 3.64 % 0.82 0.87 0.88 0.81 0.83 1,2,3,6,7,8-HxCDD 1.179 0.130 11.0 % 1.34 1.30 1.12 1. 07 1. 06 1,2,3,7,8,9-HxCDD 1.394 0.161 11.6 % 1.59 1.52 1.39 1.25 1.22 Total HxCDD 1.255 0.127 10.2 % 1.40 1.38 1.22 1.14 1.13 13C-1,2,3,4,6,7,8-HpCDF 0.935 0.015 1. 62 % 0.94 0.94 0.94 0.95 0.91 1.500 0.117 7.79 % 1.61 1. 62 1.49 1.39 1.38 13C-1,2,3,4,7,8,9-HpCDF 0.787 0.018 2.27 % 0.80 0.76 0.78 0.81 0.79 1,2,3,4,7,8,9-HpCDF 1.404 0.106 7.54 % 1.51 1. 53 1.38 1.31 1.31 Total HpCDF 1.456 0.112 7.69 % 1.57 1.58 1.44 1.35 1. 35 13C-1,2,3,4,6,7,8-HpCDD 0.804 0.019 2.32 % 0.81 0.81 0.80 0.82 0.77 1,2,3,4,6,7,8-HpCDD 1. 036 0.043 4.19 % 1. 07 1. 09 1. 02 0.99 1. 01 Total HpCDD 1.036 0.043 4.19 % 1. 07 1. 09 1. 02 0.99 1.01 13C-OCDD 0.674 0.016 2.32 % 0.68 0.66 0.66 0.68 0.69 OCDF 1.400 0.088 6.31 % 1.47 1.49 1.42 1. 32 1. 30 OCDD 1.140 0.078 6.85 % 1. 20 1. 23 1.14 1. 08 1. 05 
G1L140412 TestAmerica West Sacramento (916) 373 - 5600 78 of 100

~':. ·stAtnerlcai :; ·-e ... · .. ;·· ... : ..... : .. ,···.'_.,· ... ·· .~ 

:'THE L:EADER IN· ENVIRONME.NT.At: T.ESTJJIIG 

Compound OPR VER 

% nglml 

CS3 

16138 Acceptance Criteria 

.13C-Z,3,7,8-TCDF 22-152 71-140 

2,3,7,8-TCDF 75- 158 8.4- 12.0 

13C-2,3,7,8-TCDD 20 -175 82- 121 

2,3,7,8-TCDD 67-158 7.8- 12.9 

37CI4-2,3, 7,8-TCDD 31 - 191 7.9 -12.7 

13C-1,2,3,7,8-PeCDF 21 -192 76 -130 

1,2,3, 7,8-PeCDF 80- 134 41-60 

13C-2,3,4, 7 ,8-PeCDF 13-328 77-130 

2,3,4, 7;8-PeCDF 68- 160 41-61 

13C-1,2,3, 7,8-PeCDD 21-227 62-160 

1,2,3,7,8-PeCDD 70-142 39-65 

13C-1,2,3,4, 7 ,8-HxCDF 19-202 76 -131 

1,2,3,4, 7 ,8-HxCDF 72- 134 45-56 

13C-1,2,3,6,7,8-HxCDF 21 -159 70-143 

1,2,3,6,7,8-HxCDF 84- 130 44-57 

13C-2,3,4,6,7,8-HxCDF 22-176 73-137 

2,3,4,6, 7,8-HxCDF 70-156 44-57 

13C-1,2,3, 7 ,8,9-HxCDF 17-205 74 -135 

1,2,3,7,8,9-HxCDF 78- 130 45-56 

13C-1,2,3,4,7,8-HxCDD 21 - 193 85 -117 

1,2,3,4,7,8-HxCDD 70- 164 39-64 

13C-1,2,3,6,7,B-HxCDD 25 -163 85 -118 

1,2,3,6,7,8-HxCDD 76-134 39-64 

1,2,3, 7,8,9-HxCDD 64-162 41-61 

13C-1,2,3,4,6,7 ,8-HpCDF 21 -158 78 -129 

1,2,3,4,6, 7 ,8-HpCDF 82- 122 45-55 

13C-1,2,3,4,7,8,9-HpCDF 20-186 77-129 

1,2,3,4,7,8,9-HpCDF 78- 138 43-58 

13C-1,2,3,4,6,7,8-HpCDD 26-166 72-138 

1,2,3,4,6,7,8-HpCDD 70-140 43-58 

13C-OCDD 13 -199 96-415 

OCDF 63- 170 63- 159 

OCDD 78- 144 79-126 

16138 Acceptance Criteria for Tetras Only Analysis 

13C-2,3,7,8-TCDF 26-126 76-131 

2,3,7,8-TCDF 80-147 8.6- 11.6 

13C-2,3, 7,8-TCDD 25-141 85 -117 

2,3,7,8-TCDD 73- 146 a.2- 12:3 

37CI4-2,3, 7,8-TCDD 37-158 8.3-12.1 

Q:\FORMS\Qa-HR-100 16138 criteria.x/s Page 1 of 1 

West Sacramento 

Method 16138 Acceptance Criteria 

Based on Tables 6, 6A and 7 of the method 

VER 

ng/ml 

CS2 

71-140 

1.68-2.40 

82 -121 

1.56-2.58 

1.58-2.54 

76-130 

8.20-12.0 

77-130 

8.20-12.2 

62 -160 

7.80-13.0 

76 -131 

9.00-11.2 

70-143 

8.80-11.4 

73-137 

8.80-11.4 

74 -135 

9.00-11.2 

85 -117 

7.80-12.8 

85 -118 

7.80-12.8 

8.20-12.2 

-78-129 

9.00-11.0 

77 -129 

8.60- 11.6 

72-138 

8.60- 11.6 

96-415 

12.60-31.8 

15.80-25.2 

76 -131 

1.72-2.32 

85 -117 

1.64-2.46 

1.66-2.42 

VER 

ng/ml 

CS4 

71-140 

33.6-48 

82 -121 

31.2-51.6 

31.6-50.8 

76-130 

164-240 

77-130 

164-244 

62-160 

156-260 

76 -131 

180-224 

70-143 

176-228 

73-137 

176-228 

74-135 

180-224 

85 -117 

156-256 

85 -118 

156-256 

164-244 

. 78-129 

"180-220 

77-129 

172-232 

72-138 

172-232 

96-415 

252-636 

316-504 

76 -131 

34.4-46.4 

85-117 

32.8-49-.2 

33.2-48.4 

Fteld Samples 

nglml 

24-169 

25 -164 

3.5-19.7 

24-185 

21 -178 

25 -181 

26-152 

26-123 

28-136 

29--147 

32 -141 

28-130 

28 -143 

.26-138 

23-140 

34-313 

29-140 

31 -137 

4.2 -16.4 

QA-HR-100 

06/2712011 ERS 
G1L140412 TestAmerica West Sacramento (916) 373 - 5600 79 of 100 iile:22DE119DS #1-530 Acq:22-DEC-2011 22:08:48 GC Sample#1 Text:CP1222 :DB-5 CPSM 3732-16 319.8965 BSUB{1000,15,-3.0) EI+ Voltage SIR Autospec-Ulti

Exp:DIOXINRES 

95 

90 

85 

80 

75 70 

65 

60 

55 

SO 

45 40 

35 

30 

25 

20 

15 

10 

5 

0 

19:06 19:12 19:18 19:24 19:30 
G1L140412 TestAmerica West Sacramento (916) 373 - 5600 80 of 100

Test America 

THE LEADER IN ENVIRONMENTAL TESTING 

MeiliodiD ______ ~I~~'~~~~~~~e!v~~~~~--------

Column ID _____ __:;;b...;::9'""'·5=---------

STD ID ______ ___,S"-\:.....;_;:1 J-:.....;~:....7!....---------------

Analyzed by ____ ~~"-~.;;_er _______ _ 

Std. Pkg. By I<~ 

Std. Pkg. Reviewed By__,_M..:....:o • .....,G ..... · ~----

DAILY STANDARD PACKAGE 

Standard, CPSM, and Solvent Blank present? 

Copy of log-file and Beginning Static Resolution present? 

CPSM blow up present? 

Curve Summary present? 

Summary of Method criteria present or doc~ented below? 

Daily standard within method specified limits?· 

Analyte retention times correct? 

Isotopic ratios within limits? 

CPSM valley.::;: method specified limitsf• 

Are chromatographic windows correct? 

Samples analyzed within 12 hrs of daily standard? 

Manual reintegration's checked and hardcopies included? 

Ending Standard present? 

Ending Static Resolutions present .-· -··-~ 

Absolute retention times forx~:CI2-1,2,3,4-TCDDmd 13C12-

1,2,3,7,8,9-HxCDD are within •t-t: -' vf"tne retention 

times in the Initial Calibration? (required for all1613B samples) 

Test America- West Sacramento 

Daily Calibration Checklist 

Dioxin Methods 

Associated ICAL JP,;k~ \ })-O\ \ <\os 

Instrument ID ________ ~~..:::D..:::;5' ________ _ 

STD Solution ---~r=b.-?>~1 I_O_X-'t-...:..\ d.:...~'--\ _____ _ 

Date Analyzed,__ __ =IJ-__..1..;;....~ 1"'-'1:....:.1..._\ ____ __ 

Date Std. Pkg. Assembled,__..~..:F).;_,..J\c;:...J.-1c;:...l:,...'...:...\ ___ _ 

Date Std. Pkg. Reviewed /1./ t 1 U) 

INITIATED REVIEWED 

I ...// 

j ./, 

.I /. 

j //· 

I ..t 

I / 

I ./ 

I ./ 

I /, 

I ./ 

I .../ 

N~ M 

NA ~~ 

./ ./ 

\ 

'---1 I£\: 0~ / ../ 

CO~NTS=--------------------------------------------------------

* Method 8290!f09/M0023A: (beginning) S 20% from curve RRFs for native analytes, S 30% from curve RRFs for labeled 

compounds. 

Method 8290/T09/M0023A: (ending) S 25% from curve RRFs for native analytes, :$35% from curve RRFs for labeled 

compounds. 

Method 23: See Method 23 Daily Standard Criteria, Table 5. 

Method 16138: See, Method 16138 or Method 1613B Tetras Daily Standard Criteria, 

** Method 23/0023A CPSM Criteria: 25% valley between 2378 TCDF (DB-225)!fCDD (DB-5) and its closest eluters normalized to the 

smallest peak of the triplet . 

Method 1613B/8290!f09 CPSM Criteria: 25% valley between 2378 TCDF (DB-225)!fCDD (DB-5) and its closest eluters normalized to the 

2378 peak. 

N:\Hires\Forms\QA-231 Dioxin Daily Std Checklist.doc QA-231 8/10/09 DW 
G1L140412 TestAmerica West Sacramento (916) 373 - 5600 81 of 100

Quantitation Summary TestAmerica West Sacramento Page 1 o 

Run text: ST1227 Sample text: ST1227 :CS3 11DXN221 

Run #6 Filename: 27DE119D5 S: 2 I: 1 Results: 27DE119D5TETRAS 

Acquired: 27-DEC-11 05:15:55 Processed: 27-DEC-11 13:15:34 

Run: 27DE119D5 Analyte: TETRAS Cal: TETRAS1220119D5 

Factor 1: 20.000 Factor 2: 1.000 Sample size: 1.000000 

Name Resp RA RT RRF Cone EDL Rec M 

13C-1,2,3,4-TCDD 60582600 0.78 y 19:04 ./ - 28.13 n 

13C-2,3,7,8-TCDF 93849100 0.86 y 18:29 1.34 115.44 0.13 115.4 n 

2,3,7,8-TCDF 9315190 0.77 y 18:30 0.85 11.73 0.21 n 

13C-2,3,7,8-TCDD 55262500 0.78 y 19:16 0.91 100.69 0.25 100.7 n 

2,3,7,8-TCDD 5782230 0.81 y 19:17 1.07 9.76 0.12 n 

37Cl-2,3,7,8-TCDD 6695060 1.00 y 19:17 1.14 9.67 0.08 96.7 n 
G1L140412 TestAmerica West Sacramento (916) 373 - 5600 82 of 100

Data file Smp Work Order Sample ID FV-uL Method/Matrix Box Size u 

27DE119D5 1 CPJ.227 DB-5 CPSM 3732-16 1.00000 

27DE119D5 2 ST1227 CS3 11DXN221 1. 00000 

27DE119D5 3 Needle "Z"ed 0.00000 

27DE119D5 4 CPJ.227A DB-5 CPSM 3732-16 1.00000 

27DE119D5 5 MPVQL-1-AAB G1L220000-070B(431-1MB) 20 16131;1-T/WATER 63 1.00000 L 

27DE119D5 6 MPND6-1-AA G1L140412-1 20 1613B-T/WATER 62 1.02131 L 

27DE119D5 7 SBJ.227 Solvent Blank C-14 1.00000 

27DE119D5 8 MPPRM-1-AA G1L160409-1 20 1613B-T/WATER 62 1.04247 L 

27DE119D5 9 MPRP9-1-AA G1L190431-1 20 1613B-T/WATER 63 1. 02577 L 

27DE119D5 10 MPVQL-1-ACC G1L220000-070C(431-1LCS) 20 1613B-T/WATER 1.00000 L 

27DE119D5 11 MPVQL-1-ADL G1L220000-070L(431-1DCS) 20 1613B-T/WATER 1.00000 L 

27DE119D5 12 1.00000 

27DE119D5 13 1.00000 

27DE119D5 14 1.00000 

27DE119D5 15 MG,KSS 12/27/11 J'~ 1.00000 

l ~~.u.- 0 ,,_,')'1 \'~9 
G1L140412 TestAmerica West Sacramento (916) 373 - 5600 83 of 100

Data file Smp Work Order Sample ID FV-uL Method/Matrix Box Size u 

27DE119D5 1 CP1227 DB-5 CPSM 3732-16 1.00000 

27DE119D5 2 ST1227 CS3 l.lDXN22l. l..OOOOO 

27DEl.l.9D5 3 Needle "Z"ed 0.00000 

27DEl.l.9D5 4 CPl.227A DB-5 CPSM 3732-16 1.00000 

27DEl.19D5 5 MPVQL-l.-AAB Gl.L220000-070B(43l.-l.MB) 20 l.6l.3B-T/WATER 63 l..OOOOO L 

27DEl.19D5 6 MPND6-l.-AA Gl.Ll.404l.2-l 20 l.6l.3B-T/WATER 62 l.. 02131 L 

27DEl.19D5 7 SBl.227 Solvent Blank C-14 l.. 00000 

27DEl.l.9D5 8 MPPRM-l.-AA G1L160409-l 20 l.613B-T/WATER 62 l.. 04247 L 

27DE119D5 9 MPRP9-1-AA G1L190431-l 20 l.613B-T/WATER 63 1. 02577 L 

27DE119D5 10 MPVQL-1-ACC G1L220000-070C(431-1LCS) 20 1613B-T/WATER 1.00000 L 

27DE119D5 11 MPVQL-l.-ADL G1L220000-070L(431-l.DCS) 20 1613B-T/WATER 1.00000 L 

27DE119D5 12 l.. 00000 

27DE119D5 13 1.00000 

27DE119D5 14 1.00000 

27DEl.19D5 15 MG,KSS 12/27/H J'o 1.00000 

l ~\,t., 0~ • ,,.\l-1 \'~9 
G1L140412 TestAmerica West Sacramento (916) 373 - 5600 84 of 100 PPM 200 ..... .f r\ l r 'l I '\ 292.98245 PPM 200 ..... I' \ (li J ·\ 342.97925 PPM 200 97604 Peak Locate Examination:27-DEC-2011:04:29 File:27DE119D5 Experiment:DIOXINRES Function:l Reference:PFK Volts PPM Volts PPM Volts !PPM 1.3110 200 ...... 0.2330 200 ,_. 0.1058 '200 ll. l ' r .. l ) \ 304.98245 Jr l 318.97925 E Volts PPM Volts PPM Volts PPM 0.4401 200 ...... 0.1562 200 ..... 0.1033 200 rl' .. , i )' 354.97925 -- _3 66. 97925 Volts PPM Volts PPM Volts 0.1905 200 0.1376 200 o-+ 0.0727 ------- 404 ._9_7604 416.97604 
G1L140412 TestAmerica West Sacramento (916) 373 - 5600 85 of 100 PPM 200 -""' PPM 200 II PPM 200 I Peak Locate Examination:27-DEC-2011:13:21 File:27DE119D5ENDRES Experiment:DIOXINRES Function:1 Reference:PFK Volts PPM Volts PPM Volts PPM ...... 0.3368 200 0.1793 200 0.0805 200 IV { \ jj I \ 292. 98245_ 3 04_. 98245 318.97925 Volts PPM Volts PPM Volts PPM ...... 0.4006 200 ...... 0.1393 200 ...... 0.0965 200 I 342.97925 354.97925 366.97925 Volts PPM Volts PPM Volts ...... 0.1676 200 0.1353 200 ...... 0.0751 IN I Jl 392. 976_Qi_ 404.97604 416.97604 
G1L140412 TestAmerica West Sacramento (916) 373 - 5600 86 of 100 Pag

Run: 27DE119D5 I. Analyte: TETRAS Cal: TETRAS1220119D5 8T1220B :C8-1 11DXN219 8T1220A :C8-2 11DXN220 8T1220 :C8-3 11DXN221 8T1220D :C8-4 11DXN222 8T1220C :C8-5 11DXN223 20DE119D5 20DE119D5 20DE119D5 20DE119D5 20DE119D5 84 83 82 86 85 Name Mean 8. D. %R8D RRF1 RRF2 RRF3 RRF4 RRF5 13C-1,2,3,4-TCDD - - - % 13C-2,3,7,8-TCDF 1.342 0.030 2.27 % 1.35 1. 38 1. 36 1.31 1.31 2,3,7,8-TCDF 0.846 0.050 5.86 % 0.84 0.92 0.86 0.80 0.81 13C-2,3,7,8-TCDD 0.906 0.013 1.41 % 0.91 0.92 0.91 0.90 0.89 2,3,7,8-TCDD 1.072 0.051 4.80 % 1.10 1.14 1.06 1.01 1.05 37Cl-2,3,7,8-TCDD 1.143 0.052 4.57 % 1.08 1.22 1.15 1.11 1.14 
G1L140412 TestAmerica West Sacramento (916) 373 - 5600 87 of 100

~':. ·st··t·A ·· · · ·•-- ··. · ~:•··e . ...-.· om.ert.CO 

:'THE LEADER IN· ENVIRONME.NIAt." T.ESTJiiiG 

Compound OPR VER 

% ng/ml 

CS3 

16138 Acceptance Criteria 

.13C-Z,3,7,8-TCDF 22-152 71-140 

2,3,7,8-TCDF 75-158 8.4- 12.0 

13C-2,3,7,8-TCDD 20-175 82 -121 

2,3,7,8-TCDD 67- 158 7.8-12.9 

37CI4-2,3, 7,8-TCDD 31 - 191 7.9 -12.7 

13C-1,2,3,7,8-PeCDF 21 - 192 76-130 

1,2,3,7,8-PeCDF 80- 134 41 -60 

13C-2,3,4, 7,8-PeCDF 13-328 77-130 

2,3,4, 7,8-PeCDF 68- 160 41-61 

13C-1,2,3, 7 ,8-PeCDD 21-227 62-160 

1,2,3,7,8-PeCDD 70-142 39-65 

13C-1,2,3,4,7,8-HxCDF 19-202 76 -131 

1,2,3,4, 7 ,8-HxCDF 72- 134 45-56 

13C-1,2,3,6,7,8-HxCDF 21 -159 70 -143 

1,2,3,6,7,8-HxCDF 84-130 44-57 

13C-2,3,4,6,7 ,8-HxCDF 22-176 73 -137 

2,3,4,6,7,8-HxCDF 70·- 156 44-57 

13C-1,2,3,7,8,9-HxCDF 17-205 74-135 

1,2,3,7,8,9-HxCDF 78- 130 45-56 

13C-1 ,2,3,4,7,8-HxCDD 21 -193 85 -117 

1,2,3,4,7,8-HxCDD 70- 164 39-64 

13C-1,2,3,6,7,S-HxCDD 25-163 85 -118 

1,2,3,6,7 ,8-HxCDD 76-134 39-64 

1,2,3, 7,8,9-HxCDD 64- 162 41-61 

13C-1 ,2,3,4,6,7 ,8-HpCDF 21 -158 78 -129 

1,2,3,4,6,7 ,8-HpCDF 82-122 45-55 

13C-1 ,2,3,4, 7,8,9-HpCDF 20-186 77-129 

1,2,3,4, 7 ,8,9-HpCDF 78-138 43-58 

13C-1 ,2,3,4,6,7,8-HpCDD 26 -166 72 -138 

1,2,3,4,6, 7 ,8-HpCDD 70- 140 43-58 

13C-OCDD 13 -199 96-415 

OCDF 63- 170 63-159 

OCDD 78- 144 79- 126 

16138 Acceptance Criteria for Tetras Only Analysis 

13C-2,3,7,8-TCDF 26-126 76 -131 

2,3,7,8-TCDF 80- 147 8.6-11.6 

13C-2,3, 7,8-TCDD 25 -141 85 -117 

2,3,7,8-TCDD 73- 146 8.2-12:3 

37CI4-2,3, 7,8-TCDD 37-158 8.3 -12.1 

Q:IFORMS\Qa-HR-100 16138 criteria.xls · Page-1 of 1 

West Sacramento 

Method 16138 Acceptance Criteria 

Based on Tables 6, 6A and 7 of the method 

VER 

ng/ml 

CS2 

71-140 

1.68-2.40 

82 -121 

1.56-2.58 

1.58-2.54 

76-130 

8.20-12.0 

77-130 

8.20- 12.2 

62 -160 

7.80-13.0 

76 -131 

9.00-11.2 

70-143 

8.80- 11.4 

73-137 

8.80- 11.4 

74-135 

9.00-11.2 

85-117 

7.80-12.8 

85 -118 

7.80-12.8 

8.20- 12.2 

-18-129 

9.00-11.0 

77-129 

8.60- 11.6 

72-138 

8.60- 11.6 

96-415 

12.60-31.8 

15.80-25.2 

76 -131 

1.72-2.32 

85 -117 

1.64-2.46 

1.66-2.42 

VER 

ng/ml 

CS4 

71-140 

33.6-48 

82 -121 

31.2-51.6 

31.6-50.8 

76-130 

164-240 

77-130 

164-244 

62-160 

156- 26() 

76 -131 

180-224 

70-143 

176-228 

73-137 

176-228 

74-135 

180-224 

85 -117 

156-256 

85 -118 

156-256 

164-244 

.. 78-129 

"180-220 

77-129 

172-232 

72-138 

172- 232" 

96-415 

252-636 

316-504 

76 -131 

34.4-46.4 

85-117 

32.8-49-.2 

33.2-48.4 

Field Samples 

ng/ml 

24-169 

Z5 -164 

3.5-19.7 

24-185 

21 -178 

25 -181 

26-152 

26-123 

28-136 

29--147 

32- 141 

28 -130 

28-143 

.26-138 

23-140 

34-313 

29-140 

31 -137 

4.2 -16.4 

QA-HR-100 

0612712011 ERS 
G1L140412 TestAmerica West Sacramento (916) 373 - 5600 88 of 100 File:27DE119D5 #1-530 Acq:27-DEC-2011 06:41:37 GC EI+ Voltage SIR Autospec-UltimaE Sample#4 Text:CP1227A :DB-5 CPSM 3732-16 Exp:DIOXINRES 319.8965 S:4 BSUB(l28,15,-3.0) 100 

95 

90 

85 

80 

75 

70 

65 

60 

55 

50 

45 40 

35 2,3,7,8-TCDD 

30 

25 

20 

15 

10 

5 

0 

19:bo 19:06 19:12 19:18 19: 19:30 
G1L140412 TestAmerica West Sacramento (916) 373 - 5600 89 of 100

Sample Extraction/Preparation Log 

Copies and Checklists 
G1L140412 TestAmerica West Sacramento (916) 373 - 5600 90 of 100 TestAmerica West Sacramento High Resolution Prep Log Dioxin/Furan WW Extraction Internal COC: rl Delivered to lnst.: It lnst Receipt: Method: L 1 1613B-Tetras Matrix: I WATER Batch: 1355069 MS Run#: Prep Date: 12121/2011 Box# {p L Extraction: DB EXTRACTION: Soxhlet and Sep Funnel QC: 01 STANDARD TEST SET SAC: L1 - I - DB - 01 )SZ6 )'tlSZJ Extraction Table Shared A I) QC Batch:_=-J..;..Jifll....;..;.__,.: Shares QC With: ! ,/ .1 , v - !C! P

Reagent 

DCM 

Toluene 

Hexane 

H2S04 

20% DCM:Hexa

65% DCM:Hexa

1 :1 DCM:Cyclohex

75:20:5 

DCM:Hexane:Benz

Silica Gel 

Acid Alumina 

5% Carbon:Silica 

Sample ID Suff Work Order Extraction Hold Sample size Bottle+ Sample Empty Bottle Rnal Volume Analysis Hold Sox

Time Expires * Weight Weight 2ouL Other Time Expires 11

G1L140412 - , MPND61AA 1211112012 1 , t,tn,zq "v \ 113ot2o12 G1L140420- 1 MPNEW1AA 1217/2012 I. IJ.O /'326,.0 \ ()\ 1/30/2012 

G1L160409 - 1 MPPRM1AA 12/8/2012 G.'·{'..t /s-3?./ \ 1L ,\ 1130/2012 

G1L210000 - 69 B MPT231AA 12/8/2012 Y}').,Q A ·' \. 2/z"b/ll 1/30/2012 / 

GJL210000 - 69 c MPT231AC 12/8/2012 ,c) /\ /\ /\ \. \ 1/30/2012 l ./ 

G1l210ooo - 69 L MPT231AD 12/8/2012 t.ntt) 1 \ n 1\1 n. , \ 1/30/2012 

- . ..... ;.- ,;·<.•..;4 0:\FORMS\QA-546 ATG Log Dioxin_WWEE.xls Batch: 1355069 Page 1 of 2 12121/201110:28:12AM 
G1L140412 TestAmerica West Sacramento (916) 373 - 5600 91 of 100 • See attached sheet for sample volumes recorded from scale ------------------------------------------------------------------------------------------------

Internal Standard All Samples Spike Mix LCS/LCSD/MS/MS 1 v 1 , y 1 , I , - 1 - - r z l 1 Liq Liq Extraction Analyst/Date Soxhlet Extraction Analyst/Date Option C Analyst/Date Witnessed By: -Tf -I IFB I ) D2 Analyst/Date Analyst/Date I - ll --][ioHt:fjttll- I Q:\FORMS\QA-546 ATG Log Dioxln_WWEE.xls Batch: 1355069 Page 2 of2 12/21/2011 10:28:12 AM Date

.--, 
G1L140412 TestAmerica West Sacramento (916) 373 - 5600 92 of 100

TestAmerica West Sacramento Test America 

Data Checklist 

HRGCMS/LRGCMS Analyses 

Batch#: 1355069 

THE LEADER IN ENVIRONMENTAL TESTiNG 

Method ID: Dioxins/Furans, HRGC/HRMS (16138-Tetras Only 

DB-5 

Data Analyst: a 5 

Date initiated: L? - zs 11 

Reviewer: ~ 

Date reviewed: ----+0""'~( u~fr-:.:lf:..__ ___ _ 

QAJQC verification: 

-Daily standard package(s) present? 

-Method Blank present? 

-LCS/DCS copy present and meets native 

recovery criteria? 

-Internal standard recoveries within limits?* 

-lon ratios within + 15% of theoretical values? 

-Other QC (Dup,MS;SD) within specs?** 

Sample Analysis: 

-Correct sample aliquot used? 

-All raw data present? 

-Standard target DL's used? If RL's are used 

specify: -DL's belo_w.,@lS.......:,.-/-L_C_L_(_pl-e-as_e_c-ir-c-le-)?--

-AII positives reported at levels 

greater than method blank DL's? 

-Correct RRF's used for method? 

-Internal standard amounts correct 

for method? 

-Target analytes are not saturated? 

-Dilution/splitting of extract taken into account? 

-Have dilution calculations been verified? 

-Has a manual calculation for the sequence(s) 

been verified? ' 

-Are retention times {RT) correct? 

-Manual integrations checked? 

Comments: (Use other side if necessary) 

* Recovery limits: 

NCASI551: 40-120%*** 

Method 8290: 40-135%*** 

Method 1613: 25-150%*** 

DB-225 

Initiated Reviewed 

DB-5 DB-5 

~ ----L-

,£--- _L 

~ ./ 

~ ~ 

~ --;;;-

~ __JdA.. 

Initiated Reviewed 

DB-5 DB-5 

7 __£_ 

,/ 

.;&----

~ 2 

-,£-- _L 

tL-- --...c..-

,L-- ,/' 

~ .L_ 

Ja_ J1L 

eta_ ~ 

L__ .,/' 

L- -r 

JJL_ ~ 

Method 23: 40-130o/o***(CI4-CI6), 25-130o/o(C17-B), 70-130o/o(surr.) 

PCBs: 25-150% *** 

Method 8280: 40-120%*** 

DFLM01.0: 25-150% *** 

Method 1614 25-150%*** 

••• Lower recoveries are acceptable if I.S. SIN ;::.10:1 and DL's are <LCL for target analytes. 

Initiated Reviewed 

DB-225 DB-225 

(High Res Only) (High Res Only) 

Initiated Reviewed 

DB-225 DB-225 

(High Res Only) (High Res Only) 

**RPD limits: 

50% 

20% 

50% 

50% 

50% 

QA-371 07/99 MAF 
G1L140412 TestAmerica West Sacramento (916) 373 - 5600 93 of 100 ... RQCOS8 LEV --r LEV --r TestAmerica Laboratories, Inc. EXTRACTION BENCH WORKSHEET 

LEV -r y y Blank Check MS/MSD LEV -r y y y y Weights/Volumes Spike & Surrogate Worksheet V1al contains correct volume Labels, greenbars, worksheets computer correct & all match y Expande

coc Com

Bench S

_ _ Anomalies to Extraction Method ************************ * * * QC BATCH: 1355069 * Package 

·Bench S

Extractionist: 403613 Brent Ginn Concentrationist: 00662S Elizabeth Nguyen Reviewer /Date: NGUYENE I 12/22/11 EXTR EXPR ANL LOT#,MSRUN#/ DUE WORK ORDER TEST FLGS G1L140412-001 12/11/12 12/29/11 MPND6-1-AA D COMMENTS: G1L140420-001 12/07/12 12/30/11 MPNEW-1-AA COMMENTS: G1L160409-001 12/08/12 12/30/11 MPPRM-1-AA D COMMENTS: G1L210000-069 12/08/12 0/00/00 MPT23-1-AAB COMMENTS: G1L210000-069 12/08/12 0/00/00 MPT23-1-ACC COMMENTS: G1L210000-069 12/08/12 0/00/00 MPT23-1-ADL COMMENTS: RUSH C = CLP R EXT· MTH MATR'!I:X DB L1 WATER DB L1 WATER DB L1 WATER DB L1 WATER DB L1 WATER DB L1 WATER * * ************************ PREP DATE

COMP DATE

Dioxins/Furans, HRGC/HRMS (1613B-Tetras Only

EXTRACTION: Soxhlet and Sep Fwmel INIT/FIN PH"S SOLVENTS WT/VOL INIT JrnJ'T ADJ2 EXTRACTION'-voV-EXCHhNGE 

V

1021.31mL NA NA NA DCM/TOL 300.0 C-14 

20.00uL 

941.0mL NA NA NA DCM/TOL 300.0 C-14 20.00uL 

1042.47mL NA NA NA DCM/TOL 300.0 C-14 

20.00uL 

1000.0mL NA NA NA DCM/TOL 300.0 C-14 

20.00uL 

1000.0mL NA NA NA DCM/TOL 300.0 C-14 

20.00uL 

1000.0mL NA NA NA DCM/TOL 300.0 C-14 

20.00uL 

R E M EPA 600 D = EXP.DEL) CLIENT REQ MS/MSD NUMBER OF WORK ORDERS IN BATCH: 6 ' 
G1L140412 TestAmerica West Sacramento (916) 373 - 5600 94 of 100

Test America 

THE LEADER IN ENVIRONMENTAL TESTING 

We~t Sacramento 

Preparation' Data Review Checklist 

Prep Batch1es) ~~, .~I'J b q Test: It 13t/3 L ._ 

Prep.Date: J1 "2J r_u_ Holding Times: }1.. f:1 't'l- NCM: y~ { ,. "" Ill '1'2. \. '------""' 

A. Spike Witness/Batch setup Spike Reviewer Witness 

1. Holding times checked? NCMs filed as appropriate / V' 

2. QAS checked for QC instructions (LCS, LCSD, MS,MSD, etc) ' v 

3. Amount of samples in hood match amount of samples on bench ,.- NA sheet. Sample IDS match. 

4. Worksheets have been checked for required spiking rcompounds v 

5. Spiking volumes are correctly documented / .,/ 

6. Std ID numbers on spike labels match numbers on bench sheet r NA 

7. Expiration dates have been checked r r v 

8. Calibration expiration dates on pipettors have been checked: ,;""" NA 

9. Spiker and spike witness have signed and dated bench sheet / \/"' 

B. Weights and Volumes 

1. Recorded weights are in anticipated range NA ./ 

2. Balance upload or raw data for weights is included NA v" 

3. Weights and volumes have been transcribed correctly to LIMS. NA v' 

4. Weights are not targeted to meet exact weights. NA ,/ 

5. Each weight or volume measurement is a unique record (no NA dittos or line downs) ./ 

C. Standards and Reagents 

1. Lot numbers for all reagents, including clean up stages, are NA recorded. v 

2. Are dates and analysts for cleanups recorded? NA ./ 

3. Are correct IDs used for standards? Are expiration dates to NA day/month/year, when listed? / 

D. Documentation 

1. Are all nonconformances documented appropriately? NA ~ 

2. QuantiMs entry correct, including dates and times. NA "' 3. Are all fields completed? . 

' NA I v 

Spike witness: l2~l~ Date:~ tz hi/;; . 2"d Level Reviewer: fYi, t)U Date:: . 

f•z.l~~M 

Comments: 

q:\forms\checklists\qa-588 prep_review.doc QA-588 Revised 1213012008 ERS 
G1L140412 TestAmerica West Sacramento (916) 373 - 5600 95 of 100

Shipping and Receiving 

Documents 
G1L140412 TestAmerica West Sacramento (916) 373 - 5600 96 of 100 West Sacramento 880 Riverside Parkway 

Chain of Custody Record 

West Sacramento, CA 95605 phone 916.374.4378 fax 916.372.1059 

Project Manager: Solutia-Mike House/Potesta- 

Client Contact Mike Light Site Contact: Lisa Sullivan Date: / :J.-1 ;;{-l.J Potesta & Assoc., Inc. Tel/Fax: Lab Contact: Lidya Gulizia Carrier: Fed Ex 

7012 MacCorkle Ave., SE Analysis Turnaround Time 

Charleston/WV/25304 Calendar (C) or Work Days (W) C (304) 342-1400 Phone TAT if difTerent from Below Standard (304) 343-9031 FAX 2 weeks 

Project Name: Solutia-ACLF Annual Process Water Sample D 1 week c: Site: Nitro, WV D 2 days ..!! Q P 0 # 97-0010-009A D 1 day 0 B 1 Sample Sample Sample #of ::; ,..: Sample Identification Date Time Type Matrix Cont. ::f 

OutletOII t1JS5 Grab H20 2 X Preservation Used: I= Ice, 2= HCI: 3= H2S04; 4=HN03; S=NaOH; 6= Other Possible Hawrd Identification Sample Disposal (A fee mae assessed if samples are 

D Non-Hazard D D Skin Irritant Poison B D Unknown D D Return To Client By Lab D 

Speciallnstructions/QC Requirements & Comments: Le ve I '[Jf' Q A Q c 

Received by: Company: 

A\) Company: r Date/TiMe: Received by: Company: 

I\.____); "" \h.-. \ -rr-N . \"J totYn n Rclinqehed by: Company: Dateffime: Received by: Company: 

- ---------- 'eC 
G1L140412 TestAmerica West Sacramento (916) 373 - 5600 97 of 100

Test America LOT RECEIPT CHECKLIST 

TestAmerica West Sacramento 

THE LEADER IN ENVIRONMENTAL TESTING 

CLIENT _______ P_O_T_E_S_T_A ______ _ PM, ___ JK _ 

LOT# (QUANTIMS ID) ____ G_1 L_1_4_0_4_1_2 ___ QUOTE# ___ 5_0_59_3 ___ LOCATION W25C 

Checked ( ..!') 

DATE RECEIVED ___ 121_1_31_1_1 __ TIME RECEIVED ____ 09_1_5 ___ _ 

DELIVERED BY Ill FEDEX 

0 GOLDENSTATE 0 UPS 

0 iAL COURIER 0 TAL SF 

SHIPPPING CONTAINER(S) 

00NTRAC 

0 EZ PARCEL 

D CLIENT 

0 TAL Ill CLIENT 

OOTHER 

ON/A 

Ill 

MULIT-COOLER(S) (If checked see multi-cooler form) D 

SINGLE COOLER INFORMATION N/A 

CUSTODY SEAL STATUS Ill INTACT 0 BROKEN 0 N/A D Ill 

CUSTODY SEAL #(S) ---------9_7_4_0_44 ________ _ 

COC#(S) ___________ N_A __________ __ D Ill 

TEMPERATURE BLANK Observed:. ___ O ___ Corrected:. ___ 1;..._ __ 

SAMPLE TEMPERATURE -(TEMPERATURES ARE IN °C) 

Observed: 1' 1 • 1 Average 1 Corrected Average 

LABORATORY THERMOMETER ID: ·-------

1 

IR UNIT: #4 0 #Sill 0 OTHER. ______ _ D 

JK 12/13/11 

Initials Date 

========================================================================================= 

pH MEASURED 0 YES 0 ANOMALY eJ N/A 

LABELED BY.......................................................................................... JS 

LOGGED JS IN BY ....................................................................................... ___ _ 

SHORT HOLD TEST NOTIFICATION SAMPLE RECEIVING 

WETCHEM IZJ N/A 

VOA-ENCORES Ill N/A 

0 METALS NOTIFIED OF FILTER/PRESERVE VIA VERBAL & EMAIL IZJ N/A 

eJ COMPLETE SHIPMENT RECEIVED IN GOOD CONDITION WITH 0 N/A 

APPROPRIATE TEMPERATURES, CONTAINERS, PRESERVATIVES 

0 CLOUSEAU 0 TEMPERATURE EXCEEDED (0 oc- 6 °C). 1 0 N/A 

Ill WET ICE 0 BLUE ICE 0 GEL PACK 0 NO COOLING AGENTS USED 

JK 

Initials 

12/13/11 

Date Notes. ________________________________________________ __ 

•1 Acceptable temperature range for State of Wisconsin samples is .s.4•C. 

QA-185 10/09 RKE, Page 1 
G1L140412 TestAmerica West Sacramento (916) 373 - 5600 98 of 100

Test America Bottle Lot Inventory 

Lot 

THE LEADER IN ENVIRONMENTAL TESTING ID: ________ G_1_L_14_0_4_12 ______ _ 

1 2 3 4 5 6 7 8 9 10 11 12 

VOA* 

VOAh* 

VOAmeoh 

AGB 2 

AGBs 

250AGB 

250AGBs 

250AGBn 

500AGB 

AGJ 

500AGJ 

250AGJ 

125AGJ 

125AGJmeoh 

CGJ --

500CGJ 

250CGJ 

125CGJ 

PJ 

PJn 

500PJ 

500PJn 

500PJna 

500PJzn/na 

250PJ 

250PJn 

250PJna 

250PJzn/na 

Acetate Tube 

__ "CT 

Encore 

Folder/filter 

PUF 

Petri/Filter 

XAD Trap 

Ziploc 

1 2 3 4 5 6 7 8 9 10 11 12 

h = hydrochloric acid s = sulfuric acid na = sodium hydroxide n = nitric acid 

Number of VOAs with air bubbles present I total number of VOA's 

13 14 15 16 17 18 19 20 

13 14 15 16 17 18 19 20 

zn = zinc acetate 

QA-185 10/09 RKE, Page 2 
G1L140412 TestAmerica West Sacramento (916) 373 - 5600 99 of 100 _.;· .. ., ..... '·om: (304• .. t 'JnA Quina ·J· 1. · \.. • ..•. ,._• Potesta &As&ociilte&. !nc .• "' ... · · • t012. MacCo•iii.Av.· .. "h'·'· .. wv 2""· \4 . . . '...... ' -..,._ t . . ••. Jl1201108050225 .... -.------ iHIP TO: (911, :t7J.5INJI Bill SENDER Jill K.;l{mann • : ' TestAriert:i ... .. .?. · 880 Riv&r!tide Par"· • · • {. j ··' :f-est Sar"1mento, . · ,; · .ns .- ( ,. -.. , --If' ... -- .- .. •. ,. ShipOite: 12DEC11 -- AcNJti. 15.0 lB CAD: 1311338&11'ET3210 ., . J ' ' 

"7'1ii111111111.1111!1•1111

Rift 0101-97-0010.009A ' . '"· • 

Invoice##"· .. PO## Dept* t . 7978 3178 7427 .. XH BLUA 50FGlA359Fif5f• '-.. 

: '\ 

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TUE -13 

PRIORITY -. 

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G1L140412 TestAmerica West Sacramento (916) 373 - 5600 100 of 100

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