# Kleinfelder, Inc.

6200 Harris Technology Blvd. Charlotte, NC 28269 

# Tampa Electric Company Mulberry, FL Project # 109381 

# Analytical Report (0310-129)

EPA CTM 033
Hydrogen Cyanide


# EPA SW-846 Method 0011
Formaldehyde


# EPA Method 26A
Hydrogen Chloride, Hydrogen Fl uoride, Chloride, and Fluoride


# EPA OTM 27

PM >2.5 and PM 2.5 

# EPA OTM 28

Condensible Particulate Matter



# Enthalpy Analytical, Inc.

Phone: (919) 850 - 4392 / Fax: (919) 850 - 9012 / www.enthalpy.com 2202 Ellis Road Durham, NC 27703 - 5518

### I certify that to the best of my knowledge a ll analytical data presented in this report:

 Have been checked for completeness

 Are accurate, error-free, and legible

 Have been conducted in accordance with approved prot ocol, and that all deviations and analytical problems are summarized in the appropriate narrative(s)

This analytical report was prepared in Portable Document Format (.PDF) and contains 221 pages.

# Summary of Results

### Compound Sample ID / Catch Weight (ug)

Unit 1 Run 1 Unit 1 Run 2 Unit 1 Run 3 Hydrogen Cyanide 41.8 ND 47.5 ND 46.3 ND

Impinger Spike Field Tr Blank Reagent Blank Hydrogen Cyanide 996 26.0 ND 17.4 ND Company

Analyst Parameters # Samples Kleinfelder, Inc. KHB EPA CTM 033 3 Runs, 2 Blanks, 1 Spike Client # Job # PO # Report Date 109381 0310-129 Verbal 4/30/2010

0310-129 res ctm033 4/30/2010

### Compound Sample ID / Catch Weight (ug)

Unit 1 Run 1 Unit 1 Run 2 Unit 1 Run 3 Formaldehyde 86.8 58.7 61.2

Matrix Spike Imp Spike Field Blank Formaldehyde 421 815 2.83 ND

Reagent Blank Sample Blank Formaldehyde 5.76 J 54.6 Company

Analyst Parameters # Samples Kleinfelder, Inc. KHB EPA SW-846 Method 0011 3 Runs, 3 Blanks, 2 Spikes Client # Job # PO # Report Date 109381 0310-129 Verbal 4/30/2010

0310-129 res m0011 4/30/2010

### Compound Sample ID / Catch Weight (ug)

Unit 1 Run 1 Unit 1 Run 2 Unit 1 Run 3 Hydrogen Fluoride 215 ND 223 ND 232 ND Hydrogen Chloride 210 ND 217 ND 227 ND

Acid Blank DI H2O Blank Hydrogen Fluoride 87.5 ND 10.4 ND 0 ND Hydrogen Chloride 85.4 ND 10.2 ND 0 ND Company

Analyst Parameters # Samples Kleinfelder, Inc. EO / KHB EPA Method 26A (H2SO4) 3 Runs, 2 Blanks Client # Job # PO # Report Date 109381 0310-129 Verbal 4/29/2010

0310-129 res m26a acid 4/29/2010

### Compound Sample ID / Catch Weight (ug)

Unit 1 Run 1 Unit 1 Run 2 Unit 1 Run 3 Chloride 198 ND 203 ND 187 ND

Base Blank DI H2O Blank Chloride 84.2 ND 9.90 ND 0 ND Company

Analyst Parameters # Samples Kleinfelder, Inc. EO / KHB EPA Method 26A (NaOH) 3 Runs, 2 Blanks Client # Job # PO # Report Date 109381 0310-129 Verbal 4/29/2010

0310-129 res m26a base 5/11/2010

### Compound Sample ID / Catch Weight (mg)

Unit 1 Run 1 Unit 1 Run 2 Unit 1 Run 3 PM >2.5 0.50 1.06 0.16 PM < 2.5 Fractions 47 mm Filter 10.7 9.64 10.1 Rinse 0.00 0.11 0.02
Net PM 2.5 

### 10.7 9.76 10.2

Total PM 11.2 10.8 10.3

Unit 1 Run 4 #REF! #REF! PM >2.5 0.00 # 1.06 0.16 PM < 2.5 Fractions 47 mm Filter 10.5 9.64 10.15 Rinse 0.40 0.11 0.02
Net PM 2.5 

### 10.9 9.76 10.17

Total PM 10.9 10.82 10.33

# Negative catch set to 0. Company

Analyst Parameters # Samples Kleinfelder, Inc. KTH EPA OTM 27 4 Runs, Blanks Client # Job # PO # Report Date 109381 0310-129 Verbal 4/28/2010

### Compound Sample ID / Condensible Particulate Matter (CPM) Weight (mg)

Unit 1 Run 1 Unit 1 Run 2 Unit 1 Run 3 Net Organic Catch 5.2 2.8 32.0 Corrected Inorganic 25.0 31.0 70.1 TB Corrected CPM 28.2 31.8 100.1

Unit 1 Run 4 0 0 Net Organic Catch 10.6 0.0 0.0 Corrected Inorganic 37.5 0.0 0.0 TB Corrected CPM 46.1 0.0 0.0

Train Blank Organic Catch 2.0 If Train Blank Corrected CPM is >2.0 mg, Inorganic Catch 2.4 then sample correction is 2.0 mg. CPM 4.4 Company

Analyst Parameters # Samples Kleinfelder, Inc. KTH EPA OTM 28 5 Runs, Blanks Client # Job # PO # Report Date 109381 0310-129 Verbal 4/28/2010

0310-129 res OTM-028 4/30/2010

# ResultsMDL 0.0143 (ug/mL)Lower Curve Limit 0.104 (ug/mL)LOQ 0.104 (ug/mL)Upper Curve Limit 2.08 (ug/mL)CompoundSampleIDLab ID# 1Lab ID# 2AnalysisMethodRetTime(min)RetTime(min)% DiffRetConc# 1(ug/mL)Conc# 2(ug/mL)% DiffConcAvgConc(ug/mL)DFVol(mL)CatchWeight(ug)QualUnit 1 Run 1 008-1301.D 008-1302.D HPLC50PG76.M NA NA NA 0.0143 0.0143 0.0 0.0143 5 585 41.8 NDLD / Unit 1 Run 1 055-7801.D 055-7802.D HPLC50PG76.M NA NA NA 0.0143 0.0143 0.0 0.0143 5 585 41.8 ND% Difference NAUnit 1 Run 2 009-1401.D 009-1402.D HPLC50PG76.M NA NA NA 0.0143 0.0143 0.0 0.0143 5 664 47.5 NDUnit 1 Run 3 010-1501.D 010-1502.D HPLC50PG76.M NA NA NA 0.0143 0.0143 0.0 0.0143 5 647 46.3 NDImpinger Spike 013-2001.D 013-2002.D HPLC50PG76.M 8.54 8.60 0.7 1.06 0.977 4.0 1.02 5 196 996Spike Amount (ug) 1,023Spike Recovery (%) 97.3%Field Tr Blank 011-1601.D 011-1602.D HPLC50PG76.M NA NA NA 0.0143 0.0143 0.0 0.0143 5 364 26.0 NDReagent Blank 012-1701.D 012-1702.D HPLC50PG76.M NA NA NA 0.0143 0.0143 0.0 0.0143 5 243 17.4 NDHydrogen CyanideCompanyAnalystParameters# SamplesKleinfelder, Inc.KHBEPA CTM 0333 Runs, 2 Blanks, 1 SpikeClient #Job #PO #Report Date1093810310-129Verbal4/30/20100310-129 res ctm0334/30/2010MDL 0.0143 (ug/mL)Lower Curve Limit 0.104 (ug/mL)LOQ 0.104 (ug/mL)Upper Curve Limit 2.08 (ug/mL)CompoundSampleIDLab ID# 1Lab ID# 2AnalysisMethodRetTime(min)RetTime(min)% DiffRetConc# 1(ug/mL)Conc# 2(ug/mL)% DiffConcAvgConc(ug/mL)DFVol(mL)CatchWeight(ug)QualHydrogen CyanideCompanyAnalystParameters# SamplesKleinfelder, Inc.KHBEPA CTM 0333 Runs, 2 Blanks, 1 SpikeClient #Job #PO #Report Date1093810310-129Verbal4/30/20100.1N NaOH - RB 007-0801.D 007-0802.D HPLC50PG76.M NA NA NA 0.0143 0.0143 0.0 0.0143 1 1.00 0.0143 NDMS / Run 1 056-7901.D 056-7902.D HPLC50PG76.M 8.42 8.44 0.2 1.14 1.10 1.7 1.12 1 0.525 0.588Spike Amount (ug) 0.520Native Amount (ug) 0.00Spike Recovery (%) 113%MSD / Run 1 057-8001.D 057-8002.D HPLC50PG76.M 8.45 8.42 0.3 1.13 1.08 2.1 1.11 1 0.525 0.580Spike Amount (ug) 0.520Native Amount (ug) 0.00Spike Recovery (%) 112%LCS 1 043-6001.D 043-6002.D HPLC50PG76.M 8.05 8.03 0.2 1.25 1.28 1.4 1.26 100 10.0 1,265Spike Amount (ug) 1,023Spike Recovery (%) 124%LCS 2 044-6101.D 044-6102.D HPLC50PG76.M 8.00 8.08 0.9 1.27 1.29 0.8 1.28 100 10.0 1,283Spike Amount (ug) 1,023Spike Recovery (%) 125%0310-129 res ctm0334/30/2010MDL 0.0110 (ug/mL) Lower Curve Limit 0.0747 (ug/mL) LOQ 0.0747 (ug/mL) Upper Curve Limit 15.0 (ug/mL) Compound

Sample ID Lab ID Analysis Method Ret Time (min) Conc (ug/mL) A liquot Factor Vol (mL) Catch Weight

(ug) Qual

Unit 1 Run 1 011-0401.D HPLC48PG86D.M 6.57 0.226 2 192 86.8 Unit 1 Run 1 Rep 011-0501.D HPLC48PG86D.M 6.58 0.227 2 192 87.1 % Difference 0.4%

Unit 1 Run 1 Dup 012-0601.D HPLC48PG86D.M 7.62 0.275 2 186 102 % Difference 17.6%

Unit 1 Run 2 013-0701.D HPLC48PG86D.M 6.52 0.169 2 174 58.7

Unit 1 Run 3 014-0801.D HPLC48PG86D.M 6.43 0.215 1 285 61.2

Matrix Spike 015-0901.D HPLC48PG86D.M 6.48 1.70 1 248 421 Spike Amount (ug) 809 Spike Recovery (%) 52.0%

Imp Spike 016-1001.D HPLC48PG86D.M 6.58 5.47 1 149 815 Spike Amount (ug) 809 Spike Recovery (%) 101%

Field Blank 017-1101.D HPLC48PG86D.M NA 0.0110 1 257 2.83 ND

Reagent Blank 018-1201.D HPLC48PG86D.M 6.54 0.0379 1 152 5.76 J

Sample Blank 019-1401.D HPLC48PG86D.M 6.77 0.172 1 318 54.6

MB 4/20/10 021-1601.D HPLC48PG86D.M NA 0.0110 1 148 1.63 ND

MB 4/28/10 025-2701.D HPLC48PG86D.M NA 0.0110 1 145 1.60 ND

RB/100% ACN 008-0901.D HPLC48PG86B.M NA 0.0110 1 1.00 0.0110 ND 008-0902.D HPLC48PG86B.M NA 0.0110 1 1.00 0.0110 ND

RB/100% ACN 002-0301.D HPLC48PG86D.M NA 0.0110 1 1.00 0.0110 ND Formaldehyde Company

Analyst Parameters # Samples Kleinfelder, Inc. KHB EPA SW-846 Method 0011 3 Runs, 3 Blanks, 2 Spikes Client # Job # PO # Report Date 109381 0310-129 Verbal 4/30/2010

0310-129 res m0011 4/30/2010MDL 0.0110 (ug/mL) Lower Curve Limit 0.0747 (ug/mL) LOQ 0.0747 (ug/mL) Upper Curve Limit 15.0 (ug/mL) Compound

Sample ID Lab ID Analysis Method Ret Time (min) Conc (ug/mL) A liquot Factor Vol (mL) Catch Weight

(ug) Qual Formaldehyde Company

Analyst Parameters # Samples Kleinfelder, Inc. KHB EPA SW-846 Method 0011 3 Runs, 3 Blanks, 2 Spikes Client # Job # PO # Report Date 109381 0310-129 Verbal 4/30/2010

MS / Run 2 022-2401.D HPLC48PG86D.M 7.40 2.77 1 128 355 Spike Amount (ug) 253 Native Amount (ug) 9.78 Spike Recovery (%) 136%

MSD / Run 2 023-2501.D HPLC48PG86D.M 7.36 2.59 1 122 316 Spike Amount (ug) 253 Native Amount (ug) 9.78 Spike Recovery (%) 121%

LCS 4/20/10 020-1501.D HPLC48PG86D.M 6.59 3.79 1 148 562 Spike Amount (ug) 809 Spike Recovery (%) 69.4%

LCS 4/28/10 024-2601.D HPLC48PG86D.M 7.35 2.32 1 145 337 Spike Amount (ug) 253 Spike Recovery (%) 133%

0310-129 res m0011 4/30/2010MDL 0.0200 (ug/mL)Lower Curve Limit 0.100 (ug/mL)LOQ 0.100 (ug/mL)Upper Curve Limit 14.8 (ug/mL)CompoundSampleIDLab ID# 1Lab ID# 2AnalysisMethodRetTime(min)RetTime(min)% DiffRetConc# 1(ug/mL)Conc# 2(ug/mL)% DiffConcAvgConc(ug/mL)AcidConversionFactorDFVol(mL)CatchWeight(ug)QualR1 A 008-0901.D 008-0902.D HPLC51PG84.M NA NA NA 0.0200 0.0200 0.0 0.0200 1.053 20 510 215 NDR2 A 011-1201.D 011-1202.D HPLC51PG84.M NA NA NA 0.0200 0.0200 0.0 0.0200 1.053 20 528 223 NDR3 A 012-1301.D 012-1302.D HPLC51PG84.M NA NA NA 0.0200 0.0200 0.0 0.0200 1.053 20 551 232 NDAcid Blank 013-1401.D 013-1402.D HPLC51PG84.M NA NA NA 0.0200 0.0200 0.0 0.0200 1.053 20 208 87.5 NDDI H2O Blank 014-1501.D 014-1502.D HPLC51PG84.M NA NA NA 0.0200 0.0200 0.0 0.0200 1.053 1 495 10.4 ND0.1N H2SO4/NaOH MB 007-0801.D 007-0802.D HPLC51PG84.M NA NA NA 0.0200 0.0200 0.0 0.0200 1.053 1 1.00 0.0211 NDMS R1 A 009-1001.D 009-1002.D HPLC51PG84.M 2.78 2.78 0.0 3.55 3.54 0.1 3.54 1.053 1 10.0 37.3Spike Amount (ug) 31.6Native Amount (ug) 0.00Spike Recovery (%) 118%MSD R1 A 010-1101.D 010-1102.D HPLC51PG84.M 2.78 2.78 0.0 3.53 3.54 0.1 3.54 1.053 1 10.0 37.2Spike Amount (ug) 31.6Native Amount (ug) 0.00Spike Recovery (%) 118%Hydrogen Fluoride as FluorideCompanyAnalystParameters# SamplesKleinfelder, Inc.EO / KHBEPA Method 26A (H2SO4)3 Runs, 2 BlanksClient #Job #PO #Report Date1093810310-129Verbal4/29/20100310-129 res m26a acid4/29/2010MDL 0.0200 (ug/mL)Lower Curve Limit 0.100 (ug/mL)LOQ 0.100 (ug/mL)Upper Curve Limit 14.8 (ug/mL)CompoundSampleIDLab ID# 1Lab ID# 2AnalysisMethodRetTime(min)RetTime(min)% DiffRetConc# 1(ug/mL)Conc# 2(ug/mL)% DiffConcAvgConc(ug/mL)AcidConversionFactorDFVol(mL)CatchWeight(ug)QualR1 A 008-0901.D 008-0902.D HPLC51PG84.M NA NA NA 0.0200 0.0200 0.0 0.0200 1.028 20 510 210 NDR2 A 011-1201.D 011-1202.D HPLC51PG84.M NA NA NA 0.0200 0.0200 0.0 0.0200 1.028 20 528 217 NDR3 A 012-1301.D 012-1302.D HPLC51PG84.M NA NA NA 0.0200 0.0200 0.0 0.0200 1.028 20 551 227 NDAcid Blank 013-1401.D 013-1402.D HPLC51PG84.M NA NA NA 0.0200 0.0200 0.0 0.0200 1.028 20 208 85.4 NDDI H2O Blank 014-1501.D 014-1502.D HPLC51PG84.M NA NA NA 0.0200 0.0200 0.0 0.0200 1.028 1 495 10.2 ND0.1N H2SO4/NaOH MB 007-0801.D 007-0802.D HPLC51PG84.M NA NA NA 0.0200 0.0200 0.0 0.0200 1.028 1 1.00 0.0206 NDMS R1 A 009-1001.D 009-1002.D HPLC51PG84.M 3.74 3.74 0.0 2.85 2.85 0.0 2.85 1.028 1 10.0 29.3Spike Amount (ug) 30.8Native Amount (ug) 0.00Spike Recovery (%) 94.9%MSD R1 A 010-1101.D 010-1102.D HPLC51PG84.M 3.74 3.74 0.0 2.85 2.86 0.1 2.85 1.028 1 10.0 29.3Spike Amount (ug) 30.8Native Amount (ug) 0.00Spike Recovery (%) 95.1%Hydrogen Chloride as ChlorideCompanyAnalystParameters# SamplesKleinfelder, Inc.EO / KHBEPA Method 26A (H2SO4)3 Runs, 2 BlanksClient #Job #PO #Report Date1093810310-129Verbal4/29/20100310-129 res m26a acid4/29/2010MDL 0.0200 (ug/mL)Lower Curve Limit 0.100 (ug/mL)LOQ 0.100 (ug/mL)Upper Curve Limit 14.8 (ug/mL)CompoundSampleIDLab ID# 1Lab ID# 2AnalysisMethodRetTime(min)RetTime(min)% DiffRetConc# 1(ug/mL)Conc# 2(ug/mL)% DiffConcAvgConc(ug/mL)DFVol(mL)CatchWeight(ug)QualR1 B015-1601.D 015-1602.D HPLC51PG84.M NA NA NA 0.0200 0.0200 0.0 0.0200 20 495 198 NDR2 B018-2101.D 018-2102.D HPLC51PG84.M NA NA NA 0.0200 0.0200 0.0 0.0200 20 507 203 NDR3 B019-2201.D 019-2202.D HPLC51PG84.M NA NA NA 0.0200 0.0200 0.0 0.0200 20 468 187 NDBase Blank 020-2301.D 020-2302.D HPLC51PG84.M NA NA NA 0.0200 0.0200 0.0 0.0200 20 211 84 NDDI H2O Blank 014-1501.D 014-1502.D HPLC51PG84.M NA NA NA 0.0200 0.0200 0.0 0.0200 1 495 9.9 ND0.1N H2SO4/NaOH MB 007-0801.D 007-0802.D HPLC51PG84.M NA NA NA 0.0200 0.0200 0.0 0.0200 1 1.00 0.0200 NDMS R1 B 016-1901.D 016-1902.D HPLC51PG84.M 3.74 3.74 0.1 2.81 2.80 0.1 2.81 1 10.0 28.1Spike Amount (ug) 30.0Native Amount (ug) 0.00Spike Recovery (%) 93.6%MSD R1 B 017-2001.D 017-2002.D HPLC51PG84.M 3.73 3.72 0.2 2.88 2.89 0.1 2.88 1 10.0 28.8Spike Amount (ug) 30.0Native Amount (ug) 0.00Spike Recovery (%) 96.2%ChlorideCompanyAnalystParameters# SamplesKleinfelder, Inc.EO / KHBEPA Method 26A (NaOH)3 Runs, 2 BlanksClient #Job #PO #Report Date1093810310-129Verbal4/29/20100310-129 res m26a base4/29/2010

### Conditional Test Method 039 (CTM-039) - Particulate Determination - Data Analysis

Analysis of Particulate Recovery

Sample ID Unit 1 Run 1 Unit 1 Run 2 Unit 1 Run 3 Unit 1 Run 4

47 mm Filter ID 2386 Dates 2388 Dates 2389 Dates 2390 Dates Final wt. (g) 1st 0.12250 4/24/10 0.12180 4/24/10 0.12373 4/24/10 0.12211 4/24/10 Final wt. (g) 2nd 0.12282 4/27/10 0.12156 4/27/10 0.12321 4/27/10 0.12239 4/27/10 Final Tare Weight (g) 0.11213 3/31/10 0.11192 3/31/10 0.11307 3/31/10 0.11194 3/31/10

Net filter catch (mg) 10.7 9.64 10.1 10.5

>2.5 PM Acetone Rinses Beaker number 3123 Dates 3122 Dates 3121 Dates 3126 Dates Final wt (g) 1st 1.91212 4/24/10 1.91083 4/24/10 1.90989 4/24/10 1.90860 4/24/10 Final wt (g) 2nd 1.91205 4/28/10 1.91073 4/28/10 1.90985 4/28/10 1.90858 4/28/10 Beaker tare (g) 1.91155 4/20/10 1.90967 4/20/10 1.90969 4/20/10 1.90862 4/20/10 Acetone vol (mL) 38 35 28 26 >2.5 PM Catch (mg) 0.50 1.06 0.16 -0.05

<2.5 PM Acetone Rinses Beaker number 3124 Dates 3125 Dates 3127 Dates 3128 Dates Final wt (g) 1st 1.91140 4/24/10 1.90552 4/24/10 1.91038 4/24/10 1.91245 4/24/10 Final wt (g) 2nd 1.91136 4/28/10 1.90544 4/28/10 1.91035 4/28/10 1.91237 4/28/10 Beaker tare (g) 1.91136 4/20/10 1.90532 4/20/10 1.91033 4/20/10 1.91197 4/20/10 Acetone vol (mL) 22 30 28 24 <2.5 PM Catch (mg) 0.00 0.11 0.02 0.40

Total particulate (mg) 11.2 10.8 10.3 10.9



### Reagent Blank Acetone Analysis
Blank beaker number 3129 Dates

Blank volume (mL) 202 Dates Final wt (g) 1st 1.91114 4/24/10 Beaker tare (g) 1.91134 4/20/10 Final wt (g) 2nd 1.91109 4/28/10 Max acetone residue (g) 0.0016 Acetone residue (g) -0.0002



### In-House Blank Acetone Analysis
Blank beaker number 3137 Dates

Blank volume (mL) 200 Dates Final wt (g) 1st 1.88286 4/28/10 A Beaker tare (g) 1.88223 4/20/10 Final wt (g) 2nd 1.88288 4/28/10 P Max acetone residue (g) 0.0016 Acetone residue (g) 0.0007 Company

Analyst Parameters # Samples Kleinfelder, Inc. KTH EPA OTM 27 4 Runs, Blanks Client # Job # PO # Report Date 109381 0310-129 Verbal 4/28/2010Analysis of Condensible Particulate RecoverySample ID Number Train BlankUnit 1 Run 1Unit 1 Run 2Unit 1 Run 3OrganicBeaker Number3134313031313132Initial MeCl2/Acetone Volume, mL 130290300270Lab MeCl2 Volume, mL165 Dates165Dates165Dates 165 DatesFinal Weight, g1.8809 4/28/10 A 1.8962 4/28/10 A 1.8913 4/28/10 A 1.9169 4/28/10 AReweigh, Final, g1.8809 4/28/10 P 1.8961 4/28/10 P 1.8912 4/28/10 P 1.9167 4/28/10 PBeaker Tare, g1.8789 4/20/10 1.8909 4/20/10 1.8885 4/20/10 1.8847 4/20/10Net Organic Catch, mg2.05.22.832.0InorganicBeaker Number3261Dates3257Dates3258Dates3259DatesFinal Weight, g1.9297 4/28/10 A 1.9707 4/28/10 A 1.9621 4/28/10 A 1.9937 4/28/10 AReweigh, Final, g1.9297 4/28/10 P 1.9707 4/28/10 P 1.9621 4/28/10 P 1.9936 4/28/10 PBeaker Tare, g1.9274 4/27/10 1.9213 4/27/10 1.9139 4/27/10 1.9144 4/27/10H2O FV, mL2404103601,070Resuspended Volume, mL 100.0100.0100.0100.0Removed Pre-aliquot, mL 0.50.50.50.5Pre-aliquot CF1.0021.0011.0011.000Removed Post-aliquot, mL 0.50.50.50.5Post-aliquot CF1.011.011.011.01Net Inorganic, mg2.449.748.579.6Ammonium Correction, mg 0.024.717.59.5Corrected Inorganic, mg2.425.031.070.1Condensible Particulate Matter, mg 4.430.233.8102.1TB Corrected CPM, mg28.231.8100.1-----------------------------------------------------------------Client Blank Analyses------------------------------------------------------------------Type BlankMeCl BlankType BlankH2O BlankType BlankAcetoneBeaker Number3135DatesBeaker Number3262Dates Beaker Number3129DatesTare weight, g1.8754 4/28/10 ATare weight, g1.9353 4/28/10 A Tare weight, g1.9113 4/28/10 ADry Residue Weight, g 1.8757 4/28/10 P Dry Residue Weight, g 1.9365 4/28/10 P Dry Residue Weight, g 1.9111 4/28/10 PReweigh, Final, g1.8756 4/20/10Reweigh, Final, g1.9365 4/27/10 Reweigh, Final, g 1.9111 4/20/10MeCl2 Residue, g0.0002Water Residue, g0.0012Acetone Residue, g -0.0002MeCl2 Volume, mL134Water Volume, mL204Acetone Volume, mL 200Max. MeCl2 Residue, g 0.0027Max. Water Residue, g 0.0020Max. Acetone Residue, g 0.0016---------------------------------------------------------------In-House Blank Analyses------------------------------------------------------------------Type BlankMeCl BlankType BlankH2O BlankType BlankAcetoneBeaker Number3136DatesBeaker Number3263Dates Beaker Number3137DatesTare weight, g1.8822 4/20/10Tare weight, g1.9272 4/27/10 Tare weight, g1.8822 4/20/10Dry Residue Weight, g 1.8848 4/28/10 A Dry Residue Weight, g 1.9285 4/28/10 A Dry Residue Weight, g 1.8829 4/28/10 AReweigh, Final, g1.8848 4/28/10 P Reweigh, Final, g1.9285 4/28/10 P Reweigh, Final, g 1.8829 4/28/10 PMeCl2 Residue, g0.0027Water Residue, g0.0012Acetone Residue, g 0.0007MeCl2 Volume, mL225Water Volume, mL250Acetone Volume, mL 200Max. MeCl2 Residue, g 0.0045Max. Water Residue, g 0.0025Max. Acetone Residue, g 0.0016CompanyAnalystParameters# SamplesKleinfelder, Inc.KTHEPA OTM 285 Runs, BlanksClient #Job #PO #Report Date1093810310-129Verbal4/28/2010Analysis of Condensible Particulate RecoverySample ID Number Train BlankUnit 1 Run 4OrganicBeaker Number31343133Initial MeCl2/Acetone Volume, mL 130230Lab MeCl2 Volume, mL165 Dates165DatesFinal Weight, g1.8809 4/28/10 A 1.8946 4/28/10 AReweigh, Final, g1.8809 4/28/10 P 1.8946 4/28/10 PBeaker Tare, g1.8789 4/20/10 1.8840 4/20/10Net Organic Catch, mg2.010.6InorganicBeaker Number3261Dates3260DatesFinal Weight, g1.9297 4/28/10 A 1.9762 4/28/10 AReweigh, Final, g1.9297 4/28/10 P 1.9762 4/28/10 PBeaker Tare, g1.9274 4/27/10 1.9270 4/27/10H2O FV, mL240350Resuspended Volume, mL 100.0100.0Removed Pre-aliquot, mL 0.50.5Pre-aliquot CF1.0021.001Removed Post-aliquot, mL 0.50.5Post-aliquot CF1.011.01Net Inorganic, mg2.449.5Ammonium Correction, mg 0.012.0Corrected Inorganic, mg2.437.5Condensible Particulate Matter, mg 4.448.1TB Corrected CPM, mg46.1-----------------------------------------------------------------Client Blank Analyses------------------------------------------------------------------Type BlankMeCl BlankType BlankH2O BlankType BlankAcetoneBeaker Number3135DatesBeaker Number3262Dates Beaker Number3129DatesTare weight, g1.8754 4/28/10 ATare weight, g1.9353 4/28/10 A Tare weight, g1.9113 4/28/10 ADry Residue Weight, g 1.8757 4/28/10 P Dry Residue Weight, g 1.9365 4/28/10 P Dry Residue Weight, g 1.9111 4/28/10 PReweigh, Final, g1.8756 4/20/10Reweigh, Final, g1.9365 4/27/10 Reweigh, Final, g 1.9111 4/20/10MeCl2 Residue, g0.0002Water Residue, g0.0012Acetone Residue, g -0.0002MeCl2 Volume, mL134Water Volume, mL204Acetone Volume, mL 200Max. MeCl2 Residue, g 0.0027Max. Water Residue, g 0.0020Max. Acetone Residue, g 0.0016---------------------------------------------------------------In-House Blank Analyses------------------------------------------------------------------Type BlankMeCl BlankType BlankH2O BlankType BlankAcetoneBeaker Number3136DatesBeaker Number3263Dates Beaker Number3137DatesTare weight, g1.8822 4/20/10Tare weight, g1.9272 4/27/10 Tare weight, g1.8822 4/20/10Dry Residue Weight, g 1.8848 4/28/10 A Dry Residue Weight, g 1.9285 4/28/10 A Dry Residue Weight, g 1.8829 4/28/10 AReweigh, Final, g1.8848 4/28/10 P Reweigh, Final, g1.9285 4/28/10 P Reweigh, Final, g 1.8829 4/28/10 PMeCl2 Residue, g0.0027Water Residue, g0.0012Acetone Residue, g 0.0007MeCl2 Volume, mL225Water Volume, mL250Acetone Volume, mL 200Max. MeCl2 Residue, g 0.0045Max. Water Residue, g 0.0025Max. Acetone Residue, g 0.0016CompanyAnalystParameters# SamplesKleinfelder, Inc.KTHEPA OTM 285 Runs, BlanksClient #Job #PO #Report Date1093810310-129Verbal4/28/2010MDL 0.09 (mg Ammonium) MDL 0.26 (mg Sulfate)
Blank titrant amount (Vtb) 0.04 [Set this equal to the In-House Blank Titration Volume and then white out this note]
NH4OH normality 0.1 Lot # Sigma Aldrich 318620

Sample ID. Volume Resuspended (mL) Titration Aliquot Vol (mL) Aliquot Factor (mL rec'd/aliq mL)

Train Blank 100 99.5 0.06 ND 1.01 0.26 ND 0.09 ND
Unit 1 Run 1 100 99.5 14.50 1.01 69.81 24.75
Unit 1 Run 2 100 99.5 10.25 1.01 49.29 17.48
Unit 1 Run 3 100 99.5 5.58 1.01 26.75 9.48
Unit 1 Run 4 100 99.5 7.03 1.01 33.75 11.96 Reagent Blank 100 99.5 0.02 ND 1.01 0.26 ND 0.09 ND
In House 100 99.5 0.04 ND 1.01 0.26 ND 0.09 ND SO4 Catch (mg) NH 4 OH
Titration Vol (mL) Ammonium equivalent (mg) Company

Analyst Parameters # Samples Kleinfelder, Inc. KTH EPA OTM 28 5 Runs, Blanks Client # Job # PO # Report Date 109381 0310-129 Verbal 4/28/2010

# Narrative Summary

# Enthalpy Analytical Narrative Summary

Company 

### Kleinfelder, Inc. Client # 

### 109381

Analyst 

### KHB Job # 

### 0310-129
Parameters 

### EPA CTM-033 PO # 

### Verbal

# Samples 

### 3 Runs, 2 Blanks, 1 Spike Report Date 

### April 30, 2010

Custody Jordan Laster received the samples on 4/16/10 after being relinquished by Kleinfelder, Inc. The samples were received at 2.3  C in good condition. The pH for each NaOH fraction was measured prior to analysis. The value was 14 for each sample. Prior to, during, and after analysis, the samples were kept under lock with access only to authorized personnel by Enthalpy Analytical, Inc.

Analysis The samples were analyzed for hydrogen cyanide using the analytical procedures in EPA Conditional Test Method 033, Sampling and Analysis for Hydrogen Cyanide Emissions from Stationary Sources.
The DIONEX Model 500, High Performance Liquid Chromatograph ("Grandmama") was equipped with a Dionex ED40 Electrochemical Detector and a Dionex Ion Pac AS7, 4 x 250 mm column (S/N 012759), for these analyses.

Calibration The calibration curve is included in the Calibration Curve Chromatograms section of this report and referenced in the Analysis Method column on the Detailed Results page.
The first page of the curve contains all method specific parameters (i.e., curve type, origin, weight, etc.) used to quantify the samples. The calibration curve section also includes a table with the Retention Tim e (RetTime), Level (Lvl), Amount (corresponding units), Area, Response Factor (Amt/Area) and the analyte Name. The calibration table is used to identify (by retention time) and quantify each target compound.
Chromatographic Conditions The acquisition method 1000.M is included in the Calibration Curve Chromatograms section of this report.

QC Notes The analyses of the field and reagent blanks received with these sam ples contained no hydrogen cyanide at concentrations greater than the MDL. The recovery value for hydrogen cyanide in the Impinger Spike was within 10% of the expected value.
The analysis of the laboratory reagent blank contained no hydrogen cyanide at a concentration greater than the MDL.

# Enthalpy Analytical Narrative Summary (continued)

QC Notes (continued) A Laboratory Duplicate (LD) analysis was performed on the sample Unit 1 Run 1. Duplicate matrix spikes were prepared using sample Unit 1 Run 1 and exhibited recovery values of 113% and 112%.
Prior to sample collection, the laboratory prepared aqueous spikes, each of which contained 1,023 μg of hydrogen cyanide. Two aqueous spikes were sent to the client and two were retaned at the laboratory and analyzed with the samples as LCS. The LCS exhibited recovery values of 124% and 125%.
All samples were analyzed within the 30-day holding time specifed by the method.
Reporting Notes The sample volumes measured and recored by the laboratory were used to determine the mass of hydrogen cyanide for each sample.
The results presented in this report are representative of the samples as provided to the laboratory.

Enthalpy Analytical, Inc. is accredited to perform this Method CTM033 for compliance purposes by the National Environmental Laboratory Accreditation Conference (NELAC) through the Louisiana Environmental Laboratory Accreditation Program (LELAP), certificate number 04010.

# Enthalpy Analytical Narrative Summary

Company 

### Kleinfelder, Inc. Client # 

### 109381

Analyst 

### KHB Job # 

### 0310-129
Parameters 

### EPA SW-846 Method 0011 PO # 

### Verbal

# Samples 

### 3 Runs, 2 Blanks, 2 Spikes Report Date 

### April 30, 2010

Custody Jordan Laster received the sam ples on 4/16/10 after being relinquished by Kleinfelder, Inc. The sam ples were received at -1.3  C in good condition. Prior to, during, and after analysis, the sam ples were kept under lock with access only to authorized personnel by Enthalpy Analytical, Inc.
Analysis The sam ples were analyzed for form aldehyde using the analytical procedures in EPA SW -846 Method 0011, Sam pling for Selected Aldehyde and Ketone Emissions from Stationary Sources.
The Agilent Model 1100, High Perf ormance Liquid Chrom atograph ("Groucho") was equipped with an U ltraviolet (UV) Detector operating at 360 nm and Restek Ultra C 18, 150 x 4 mm column (S/N 09070055T), for these analyses.

Calibration The calibration curve is included in the Calibration Curve Chromatograms of this report and referenced in the Analysis Method column on the Detailed Results page.
The first page of the curve contains all method specific parameters (i.e., curve type, origin, weight, etc.) used to quantify the sam ples. The calibration curve section also includes a table with the Retention Tim e (RetTime), Level (Lvl), Am ount (corresponding units), Area, Response Factor (Amt/Area) and the analyte Na me. The calibration table is used to identify (by retention time) and quantify each target compound.
Chromatographic Conditions The acquisition m ethod hplc48pg84@.m is included in the Calibration Curve Chromatograms section of this report.
QC Notes Formaldehyde was identified in the Reagent Blank at a concentration less than the LOQ. Form aldehyde wa s not identified in the laboratory reagent or method blanks.
The analysis of the Impinger Spike sample exhibited a recovery value of 101%. The analyses of the Matrix Spike sample exhibited a recovery value of 52%.

# Enthalpy Analytical Narrative Summary (continued) QC Notes (continued) Prior to sam ple collection, four spike solutions were prepared containing 809 μg of form aldehyde. Two spike solu tions were shipped to the client and two were retained by the lab to us e as LCSs. The analyses of the LCSs exhibited recovery values of 69.4% and 133%.
Sample Unit 1 Run 1 was split during preparation to generate duplicate sample Unit 1 Run 1 Dup . The percent difference value between original and duplicate results was 17.6%.
During sample preparation, Unit 1 Run 2 was split in half . The f irst half was analyzed as the sam ple and has an aliquot factor of two, as shown on the detailed results page. The other ha lf was split in thirds. Two of the thirds were used to prepare the Matr ix Spike and Matrix Spike Duplicate. One third was archived These spikes do not have an aliquot factor, and the native amount of the sample used in de termining their recoveries is 1/6 the calculated f inal result f or the sam ple itself . The two m atrix spike recoveries were 136% and 121%.
Reporting Notes The results presented in this report are representative of the sam ples as provided to the laboratory.

# Enthalpy Analytical Narrative Summary

Company 

### Kleinfelder, Inc. Client # 

### 109381

Analyst 

### EO / KHB Job # 

### 0310-129
Parameters 

### EPA Method 26A PO # 

### Verbal

# Samples 

### 3 Runs, 3 Blanks Report Date 

### April 29, 2010

Custody Jordan Laster received the sam ples on 4/16/10 after being relinquished by Kleinfelder, Inc. The sam ples were received at 15.7  C in good condition. Prior to, during, and after analysis, the sam ples were kept under lock with access only to authorized personnel by Enthalpy Analytical, Inc.

Analysis The sam ples were analyzed for hydrogen chloride (HCl), hydrogen fluoride (HF), chloride, and fluoride us ing the analytical procedures in EPA Method 26A, Determ ination of Hydrogen Halide and Halogen Emissions from Stationary Sources Isokinetic Method (40 CFR Part 60, Appendix A).
The sam ples were analyzed followi ng the procedures in Section 11.0, Analytical Procedures. All sam ples and standards are prepared, stored, and analyzed using high-density polyethylene containers.
The volume of the im pinger samples were m easured and recorded and used in calculating the catch weights.
The Metrohm 861 Com pact IC ("Smithers" S/N 1861002007189) was equipped with a Metrohm 861 Conductiv ity Detector and a Metrosep A Supp 5 - 110/4.0mm column (S/N # 905298).

Calibration The calibration curve is located in the back of this report and referenced in the Analysis Method column on the Detailed Results page.
The first page of the curve contains all method specific parameters (i.e., curve type, origin, weight, etc.) us ed to quantif y the sam ples. The calibration curve section also includes a table with the Retention Tim e (RetTime), Level (Lvl), Am ount (c orresponding units), Area, Response Factor (Amt/Area) and the analyte Na me. The calibration table is used to identify (by retention time) and quantify each target compound.

Chromatographic Conditions The acquisition m ethod Metrohm .M is included in the Calibration Curve Chromatograms section of this report.

QC Notes As required in Section 7.2.2, Absorbing Solution Blanks, clientprovided field and reagent blanks were analyzed. Additionally, quality control check samples were analyzed at the same time as the blanks and samples. All method required acceptance criteria were met.

# Enthalpy Analytical Narrative Summary (continued)

QC Notes (continued) The m atrix spikes perform ed on sam ples R1 A and R1 B in duplicate (MS and MSD) exhibited recovery values of 118% and 118% for HF, 94.9% and 95.1% for HCl, 106% and 108% for fluoride, and 93.6% and 96.2% for chloride.
All sam ple preparation and analytical holding tim es specif ied in the method were m et. In Section 13.2, Sam ple Stability, the specified analytical holding time is four weeks.
Reporting Notes The results presented in this report are representative of the sam ples as provided to the laboratory.

The H 2 

### SO 4 

### matrix samples were analyzed for Cl - 

### and F - 

### but are reported as HCl and HF. The results were converted using an acid conversion factor of 1.028 for HCl and 1.053 for HF.
Enthalpy Analytical, Inc. is accredited to perform this m ethod for compliance purposes by the National Environm ental Laboratory Accreditation Conference (NELAC) through the Louisiana Environmental Laboratory Accreditation Program (LELAP), certificate number 04010.

# Enthalpy Analytical Narrative Summary

Company 

### Kleinfelder, Inc. Client # 

### 109381

Analyst 

### ARM Job # 

### 0310-129
Parameters 

### EPA OTM 27 PO # 

### Verbal

# Samples 

### 3 Runs, Blank Report Date 

### April 28, 2010

Custody Jordan Laster received the samples on 4/16/10 after being relinquished by Kleinfelder, Inc. The samples were received at 16.6  C in good condition. Prior to, during, and after analysis, the samples were kept under lock with access only to authorized personnel by Enthalpy Analytical, Inc.

Analysis The samples were analyzed for PM 2.5 

### and PM greater than 2.5 microns using EPA Other Test Method (OTM) 27, Determination of PM 10 

### and PM 2.5 

### Emissions from Stationary Sources (Constant Sampling Rate Procedures).
The filters were placed in a desiccator for 24 hours. The filters were weighed at minimum 6-hour intervals until constant weights were achieved.

The volumes of the acetone rinse fractions were measured and recorded. The acetone rinse fractions were transferred to tare weighed alum inum beakers and allowed to evaporate to dryness under nitrogen in a vented chamber. The remaining residues were placed in a desiccator for 24 hours and then weighed at minimum 6-hour intervals until constant weights were achieved.
All samples were weighed on a Sartorius Model ME 5-F balance (SN 23104965) certified by Precision Weighing, Inc. through the end of October 2010.

QC Notes No corrections for the acetone blank were made to the results.

Reporting Notes The accuracy of gravimetric analyses is considered to be ±0.5 mg. Therefore, negative catch weights between 0 and -0.5 mg are set to zero and no investigation is undertaken. The negative weight for the >2.5 PM fraction of Unit 1 Run 4 was not used in the total particulate calculation.

The results presented in this report are representative of the samples as provided to the laboratory.

# Enthalpy Analytical Narrative Summary

Company 

### Kleinfelder, Inc. Client # 

### 109381

Analyst 

### KTH Job # 

### 0310-129
Parameters 

### EPA OTM 28 PO # 

### Verbal

# Samples 

### 5 Runs, Blanks Report Date 

### April 28, 2010

Custody Jordan Laster received the samples on 4/16/10 after being relinquished by Kleinfelder, Inc. The samples were received at 16.6  C in good condition. Prior to, during, and after analysis, the samples were kept under lock with access only to authorized personnel by Enthalpy Analytical, Inc.
Analysis The samples were analyzed for Particulate Matter using the analytical procedures in EPA Other Test Method (OTM) 28, Dry Inpinger Method for Determining Condensable Particulate Emissions from Stationary Sources.
The Teflon filters were folded into quarters and placed into a 40 m L VOA. 25 mLs of DIUF water was added to the VOA and sonicated for two minutes. The water extract was combined with the sample water fractions. This was repeated two times. A 25 mL aliquot of methylene chloride (MeCl 2 

### ) was then added to the filter and sonicated for two minutes. This was repeated two times. This MeCl 2 

### was combined with the client’s methylene chloride fractions.
The water fractions were extracted three times, each time using 30 mL of methylene chloride. A 0.5 mL aliquot was archived. The remainder was evaporated in a Teflon beaker at 104.7 °C until less than 5 m L remained; this was dried at room conditions. The residue was resuspended in 100 mL of DIUF water; another 0.5 mL aliquot labeled “post” was taken and archived. The remainder was titrated with 0.1N NH 4 

### OH and returned to the oven until less than 5 mL remained; drying was completed at room conditions. The residue was transferred with acetone and a Teflon policeman to a tare weighed aluminum beaker and placed inside a vented chamber under nitrogen. The beakers were then placed in a desiccator for 24 hours. The beakers were weighed at minimum 6-hour intervals until constant weights were achieved.
The organic fractions final volumes were taken. The client provided acetone and MeCl 2 

### were combined with the 90 mL of MeCl 2 

### (used to extract the water fraction) in tared aluminum beakers. The beaker samples were evaporated to dryness under nitrogen in a vented chamber and then placed in a desiccator for 24 hours. The samples were weighed at minimum 6-hour intervals until constant weights were achieved.

# Enthalpy Analytical Narrative Summary (continued)

Analysis (continued) The Train Blank was treated as a sample.
All samples were weighed on a Sartorius Model ME 5-F balance (SN 23104965) certified by Precision Weighing, Inc. through the end of October 2010.
QC Notes The method specifies blank corrections are accomplished by subtracting the particulate mass determined in the ‘Field Train Blank’ or 2 mg (whichever is less) from the sample weight. The train blank result was greater than 2.0 mg, so 2.0 has been used as the Train Blank (TB) Correction.
The inorganic results for the samples were corrected for the ammonium ions used to precipitate the sulfate, per the formula in the Method (Section 12.2.1).
Reporting Notes The accuracy of this gravimetric analyses is considered to be ±0.5 mg. Therefore, negative catch weights between 0 and -0.5 mg are set to zero and no investigation is undertaken. None of the catch results for this data set were negative.
The results presented in this report are representative of the samples as provided to the laboratory.

# General Reporting Notes

The following are general reporting notes that are a pplicable to all Enthalpy Analytical, Inc. data reports, unless specifically noted otherwise.

 The acronym MDL represents the Minim um Detection Lim it. Below this value the laboratory cannot determine the presence of the analyte of interest reliably.

 The acrony m LOQ represents the Lim it of Quantification. Below this value the laboratory cannot quantitate the analyte of interest within the criteria of the method.

 The acronym ND following a value indicates a non-detect or analytical result below the MDL.

 The letter J following a value indicates an analy tical r esult between the MDL and the LOQ. A J flag indicates that the laboratory can positively identify th e analyte of interest as present, but the value should be considered an estimate.

 The letter E following a value indicates an analy tical r esult exceeding 100% of the highest calibration point. The associated value should be considered as an estimate.

 The acronym DF represents Dilution Factor. This number represents dilution of the sam ple during the preparation and/or analy sis process. The analy ti cal result taken from a laboratory instrum ent is multiplied by the DF to determine the final undiluted sample results.

 The addition of MS to the Sam ple ID represents a Matrix Sp ike. An aliquot of an actual sam ple is spiked with a known amount of analyte so that a per cent recovery value can be determined. This shows what effect the sample matrix may have on the target analyte, i.e. whether or not anything in the sample matrix interferes with the analysis of the analyte(s).

 The addition of MSD to the Sam ple ID represents a Matrix Spike Duplicate. Prepared in the sam e manner as an MS, the use of duplicate m atrix spikes allows further confirmation of laboratory quality by showing the consistency of results gained by performing the same steps multiple times.

 The addition of LD to the Sam ple ID represents a Laborat ory Duplicate. The analy st prepares an additional aliquot of sam ple for testing and the resu lts of the duplicate analy sis are compared to the initial result. The result should have a difference value of within 10% of the initial result (if the results of the original analysis are greater than the LOQ).

 The addition of AD to the Sam ple ID represents an Alte rnate Dilution. The analy st prepares an additional aliquot at a different dilution factor (usu ally double the initial factor). This analy sis helps confirm that no additional compound is present and coel uting or sharing absorbance with the analyte of interest, as they would have a different res ponse/absorbance than the analyte of interest.

 The Sample ID LCS represents a Laboratory Control Sample. Clean matrix, similar to the client sample matrix, prepared and analy zed by the laborator y using the sam e reagents, spiking standards and procedures used for the client sam ples. The LCS is used to assess the control of the laboratory ’s analytical system. Whenever spikes are prepared for our client projects, two extra spikes are prepared. The extras (randomly chosen) are labeled with the asso ciated project number and kept in-house at the appropriate temperature conditions. When the project sam ples are received for analy sis, the LCSs are analyzed to confirm that the analy te could be recovered from the m edia, separate from the samples which were used on the project and which m ay have been affected by source matrix, sample collection and/or sample transport.

# General Reporting Notes

(continued)

 Significant Figures : Where the reported value is m uch greater than unity (1.00) in the units expressed, the number is rounded to a whole num ber of units, rather than to 3 significant figures. For example, a value of 10,456.45 ug catch is rounded to 10,456 ug. Ther e are five significant digits display ed, but no confidence should be placed on more than two significant digits.

 Manual Integration : The data sy stems used for processing w ill flag m anually integrated peaks with an “M”. There are several reasons a peak may be manually integrated. These reasons will be identified by the following two letter designations. The peak was not integrated by the software “NI” , the peak

was integrated incorrectly by the software “II” or the wrong peak was integrated by the software “WP” . These codes will accom pany the analy st’s m a nual integration stam p placed next to the compound name.

# Sample Custody

# Sample Chromatogramsmin 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\008-1301.D)1.4701.7452.1152.702

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.536 - - - Hydrogen Cyanide

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

===================================================================== Area Percent Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\008-1301.D Sample Name: Run 1*5 0310-129

===================================================================== Acq. Operator : KHB Seq. Line : 13 Acq. Instrument : Grandmama Location : - Injection Date : 4/29/2010 1:13:41 AM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/8/2010 9:49:36 AM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M Last changed : 4/29/2010 3:34:02 PM by ARM

=====================================================================

Instrument 3 4/30/2010 2:26:10 PM ARM Page 1 of 2min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\008-1302.D)1.4821.7582.0212.1242.712

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.536 - - - Hydrogen Cyanide

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

===================================================================== Area Percent Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\008-1302.D Sample Name: Run 1*5 0310-129

===================================================================== Acq. Operator : KHB Seq. Line : 13 Acq. Instrument : Grandmama Location : - Injection Date : 4/29/2010 1:28:57 AM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/8/2010 9:49:36 AM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M Last changed : 4/29/2010 3:34:02 PM by ARM

=====================================================================

Instrument 3 4/30/2010 2:26:16 PM ARM Page 1 of 2min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\055-7801.D)1.4771.5801.7701.8552.1172.704

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.536 - - - Hydrogen Cyanide

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

===================================================================== Area Percent Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\055-7801.D Sample Name: LD/Run 1*5 0310-129

===================================================================== Acq. Operator : KHB Seq. Line : 78 Acq. Instrument : Grandmama Location : - Injection Date : 4/30/2010 1:05:50 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/30/2010 12:54:42 PM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M Last changed : 4/29/2010 3:34:02 PM by ARM Sample Info : Lab Duplicate

=====================================================================

Instrument 3 4/30/2010 2:57:38 PM ARM Page 1 of 2min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\055-7802.D)1.4731.5811.7671.8482.1202.695

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.536 - - - Hydrogen Cyanide

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

===================================================================== Area Percent Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\055-7802.D Sample Name: LD/Run 1*5 0310-129

===================================================================== Acq. Operator : KHB Seq. Line : 78 Acq. Instrument : Grandmama Location : - Injection Date : 4/30/2010 1:21:12 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/30/2010 12:54:42 PM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M Last changed : 4/29/2010 3:34:02 PM by ARM Sample Info : Lab Duplicate

=====================================================================

Instrument 3 4/30/2010 2:57:44 PM ARM Page 1 of 2min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\009-1401.D)1.4711.7432.1072.709

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.536 - - - Hydrogen Cyanide

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

===================================================================== Area Percent Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\009-1401.D Sample Name: Run 2*5 0310-129

===================================================================== Acq. Operator : KHB Seq. Line : 14 Acq. Instrument : Grandmama Location : - Injection Date : 4/29/2010 1:44:14 AM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/8/2010 9:49:36 AM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M Last changed : 4/29/2010 3:34:02 PM by ARM

=====================================================================

Instrument 3 4/30/2010 2:26:22 PM ARM Page 1 of 2min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\009-1402.D)1.4701.7382.1052.703

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.536 - - - Hydrogen Cyanide

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

===================================================================== Area Percent Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\009-1402.D Sample Name: Run 2*5 0310-129

===================================================================== Acq. Operator : KHB Seq. Line : 14 Acq. Instrument : Grandmama Location : - Injection Date : 4/29/2010 1:59:31 AM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/8/2010 9:49:36 AM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M Last changed : 4/29/2010 3:34:02 PM by ARM

=====================================================================

Instrument 3 4/30/2010 2:26:28 PM ARM Page 1 of 2min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\010-1501.D)1.4781.7392.0972.716

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.536 - - - Hydrogen Cyanide

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

===================================================================== Area Percent Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\010-1501.D Sample Name: Run 3*5 0310-129

===================================================================== Acq. Operator : KHB Seq. Line : 15 Acq. Instrument : Grandmama Location : - Injection Date : 4/29/2010 2:14:53 AM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/8/2010 9:49:36 AM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M Last changed : 4/29/2010 3:34:02 PM by ARM

=====================================================================

Instrument 3 4/30/2010 2:26:37 PM ARM Page 1 of 2min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\010-1502.D)1.4831.7422.1052.710

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.536 - - - Hydrogen Cyanide

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

===================================================================== Area Percent Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\010-1502.D Sample Name: Run 3*5 0310-129

===================================================================== Acq. Operator : KHB Seq. Line : 15 Acq. Instrument : Grandmama Location : - Injection Date : 4/29/2010 2:30:09 AM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/8/2010 9:49:36 AM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M Last changed : 4/29/2010 3:34:02 PM by ARM

=====================================================================

Instrument 3 4/30/2010 2:29:37 PM ARM Page 1 of 2min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\013-2001.D)

A

r ea

: 21

5 4 .8

71.4871.7462.1102.2878.539 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.539 MM 2154.86670 4.90558e-4 1.05709 Hydrogen Cyanide

Totals : 1.05709

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\013-2001.D Sample Name: Imp Spk*5 0310-129

===================================================================== Acq. Operator : KHB Seq. Line : 20 Acq. Instrument : Grandmama Location : - Injection Date : 4/29/2010 4:47:38 AM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/8/2010 9:49:36 AM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M Last changed : 4/29/2010 3:34:02 PM by ARM

=====================================================================

Instrument 3 4/30/2010 2:31:01 PM ARM Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\013-2002.D)1.4941.7388.598 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.598 BB 1996.46399 4.89178e-4 9.76626e-1 Hydrogen Cyanide

Totals : 9.76626e-1

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\013-2002.D Sample Name: Imp Spk*5 0310-129

===================================================================== Acq. Operator : KHB Seq. Line : 20 Acq. Instrument : Grandmama Location : - Injection Date : 4/29/2010 5:02:54 AM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/8/2010 9:49:36 AM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M Last changed : 4/29/2010 3:34:02 PM by ARM

=====================================================================

Instrument 3 4/30/2010 2:30:37 PM ARM Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\011-1601.D)1.4801.7382.0902.273

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.536 - - - Hydrogen Cyanide

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

===================================================================== Area Percent Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\011-1601.D Sample Name: Field Tr Blk*5 0310-129

===================================================================== Acq. Operator : KHB Seq. Line : 16 Acq. Instrument : Grandmama Location : - Injection Date : 4/29/2010 2:45:25 AM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/8/2010 9:49:36 AM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M Last changed : 4/29/2010 3:34:02 PM by ARM Sample Info : Sample Blank

=====================================================================

Instrument 3 4/30/2010 2:29:47 PM ARM Page 1 of 2min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\011-1602.D)1.4841.741

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.536 - - - Hydrogen Cyanide

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

===================================================================== Area Percent Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\011-1602.D Sample Name: Field Tr Blk*5 0310-129

===================================================================== Acq. Operator : KHB Seq. Line : 16 Acq. Instrument : Grandmama Location : - Injection Date : 4/29/2010 3:00:41 AM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/8/2010 9:49:36 AM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M Last changed : 4/29/2010 3:34:02 PM by ARM Sample Info : Sample Blank

=====================================================================

Instrument 3 4/30/2010 2:29:57 PM ARM Page 1 of 2min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\012-1701.D)1.4801.737

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.536 - - - Hydrogen Cyanide

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

===================================================================== Area Percent Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\012-1701.D Sample Name: Reagent Blk*5 0310-129

===================================================================== Acq. Operator : KHB Seq. Line : 17 Acq. Instrument : Grandmama Location : - Injection Date : 4/29/2010 3:15:58 AM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/8/2010 9:49:36 AM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M Last changed : 4/29/2010 3:34:02 PM by ARM Sample Info : Sample Blank

=====================================================================

Instrument 3 4/30/2010 2:30:03 PM ARM Page 1 of 2min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\012-1702.D)1.4851.7422.1342.277

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.536 - - - Hydrogen Cyanide

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

===================================================================== Area Percent Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\012-1702.D Sample Name: Reagent Blk*5 0310-129

===================================================================== Acq. Operator : KHB Seq. Line : 17 Acq. Instrument : Grandmama Location : - Injection Date : 4/29/2010 3:31:14 AM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/8/2010 9:49:36 AM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M Last changed : 4/29/2010 3:34:02 PM by ARM Sample Info : Sample Blank

=====================================================================

Instrument 3 4/30/2010 2:30:10 PM ARM Page 1 of 2min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\007-0801.D)1.7382.271

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.536 - - - Hydrogen Cyanide

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

===================================================================== Area Percent Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\007-0801.D Sample Name: 0.1N NaOH - RB

===================================================================== Acq. Operator : KHB Seq. Line : 8 Acq. Instrument : Grandmama Location : - Injection Date : 4/28/2010 10:40:56 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/8/2010 9:49:36 AM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M Last changed : 4/29/2010 3:34:02 PM by ARM

=====================================================================

Instrument 3 4/29/2010 3:40:50 PM ARM Page 1 of 2min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\007-0802.D)1.6731.7402.272

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.536 - - - Hydrogen Cyanide

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

===================================================================== Area Percent Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\007-0802.D Sample Name: 0.1N NaOH - RB

===================================================================== Acq. Operator : KHB Seq. Line : 8 Acq. Instrument : Grandmama Location : - Injection Date : 4/28/2010 10:56:12 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/8/2010 9:49:36 AM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M Last changed : 4/29/2010 3:34:02 PM by ARM

=====================================================================

Instrument 3 4/29/2010 3:40:55 PM ARM Page 1 of 2min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\056-7901.D)

A

r ea

: 23

1 7 .5

51.4731.5801.7611.8452.1182.6918.419 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.419 MM 2317.55493 4.91779e-4 1.13972 Hydrogen Cyanide

Totals : 1.13972

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\056-7901.D Sample Name: MS/Run 1 0310-129

===================================================================== Acq. Operator : KHB Seq. Line : 79 Acq. Instrument : Grandmama Location : - Injection Date : 4/30/2010 1:36:28 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/30/2010 12:54:42 PM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M Last changed : 4/29/2010 3:34:02 PM by ARM Sample Info : Matrix Spike

=====================================================================

Instrument 3 4/30/2010 3:41:23 PM ARM Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\056-7902.D)1.4751.5851.7631.8502.1212.6938.438 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.438 BB 2243.35498 4.91244e-4 1.10203 Hydrogen Cyanide

Totals : 1.10203

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\056-7902.D Sample Name: MS/Run 1 0310-129

===================================================================== Acq. Operator : KHB Seq. Line : 79 Acq. Instrument : Grandmama Location : - Injection Date : 4/30/2010 1:51:44 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/30/2010 12:54:42 PM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M Last changed : 4/29/2010 3:34:02 PM by ARM Sample Info : Matrix Spike

=====================================================================

Instrument 3 4/30/2010 2:59:03 PM ARM Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\057-8001.D)1.4761.5901.7641.8572.1202.6988.450 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.450 BB 2295.54639 4.91624e-4 1.12855 Hydrogen Cyanide

Totals : 1.12855

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\057-8001.D Sample Name: MSD/Run 1 0310-129

===================================================================== Acq. Operator : KHB Seq. Line : 80 Acq. Instrument : Grandmama Location : - Injection Date : 4/30/2010 2:07:01 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/30/2010 12:54:42 PM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M Last changed : 4/29/2010 3:34:02 PM by ARM Sample Info : Matrix Spike Duplicate

=====================================================================

Instrument 3 4/30/2010 2:59:13 PM ARM Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\057-8002.D)1.4731.5891.7621.8562.1192.6948.423 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.423 BB 2204.25684 4.90948e-4 1.08217 Hydrogen Cyanide

Totals : 1.08217

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\057-8002.D Sample Name: MSD/Run 1 0310-129

===================================================================== Acq. Operator : KHB Seq. Line : 80 Acq. Instrument : Grandmama Location : - Injection Date : 4/30/2010 2:37:46 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/30/2010 12:54:42 PM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M Last changed : 4/29/2010 3:34:02 PM by ARM Sample Info : Matrix Spike Duplicate

=====================================================================

Instrument 3 4/30/2010 2:59:33 PM ARM Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\043-6001.D)1.6671.7392.2708.046 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.046 BB 2528.24194 4.93127e-4 1.24674 Hydrogen Cyanide

Totals : 1.24674

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\043-6001.D Sample Name: LCS 1*100 0410-22

===================================================================== Acq. Operator : KHB Seq. Line : 60 Acq. Instrument : Grandmama Location : - Injection Date : 4/30/2010 3:36:36 AM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/8/2010 9:49:36 AM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M Last changed : 4/29/2010 3:34:02 PM by ARM Sample Info : Lab Control Spike

=====================================================================

Instrument 3 4/30/2010 3:19:35 PM ARM Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\043-6002.D)

A

r ea

: 25

9 9 .3

11.6671.7341.8552.2598.026 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.026 MM 2599.30957 4.93532e-4 1.28284 Hydrogen Cyanide

Totals : 1.28284

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\043-6002.D Sample Name: LCS 1*100 0410-22

===================================================================== Acq. Operator : KHB Seq. Line : 60 Acq. Instrument : Grandmama Location : - Injection Date : 4/30/2010 3:51:52 AM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/8/2010 9:49:36 AM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M Last changed : 4/29/2010 3:34:02 PM by ARM Sample Info : Lab Control Spike

=====================================================================

Instrument 3 4/30/2010 3:19:48 PM ARM Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\044-6101.D)1.6641.7292.2558.001 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.001 BB 2579.91626 4.93424e-4 1.27299 Hydrogen Cyanide

Totals : 1.27299

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\044-6101.D Sample Name: LCS 2*100 0410-22

===================================================================== Acq. Operator : KHB Seq. Line : 61 Acq. Instrument : Grandmama Location : - Injection Date : 4/30/2010 4:07:15 AM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/8/2010 9:49:36 AM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M Last changed : 4/29/2010 3:34:02 PM by ARM Sample Info : Lab Control Spike

=====================================================================

Instrument 3 4/30/2010 3:38:00 PM ARM Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\044-6102.D)

A

r ea

: 26

1 8 .3

21.6641.7352.2618.075 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.075 MM 2618.32080 4.93637e-4 1.29250 Hydrogen Cyanide

Totals : 1.29250

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\044-6102.D Sample Name: LCS 2*100 0410-22

===================================================================== Acq. Operator : KHB Seq. Line : 61 Acq. Instrument : Grandmama Location : - Injection Date : 4/30/2010 4:22:30 AM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/8/2010 9:49:36 AM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M Last changed : 4/29/2010 3:34:02 PM by ARM Sample Info : Lab Control Spike

=====================================================================

Instrument 3 4/30/2010 3:38:15 PM ARM Page 1 of 1

# Calibration Curve Chromatograms===================================================================== Calibration Table

=====================================================================

Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM

Calculate : External Standard Based on : Peak Area

Rel. Reference Window : 10.000 % Abs. Reference Window : 0.300 min Rel. Non-ref. Window : 10.000 % Abs. Non-ref. Window : 0.300 min Use Multiplier & Dilution Factor with ISTDs Uncalibrated Peaks : not reported Partial Calibration : Yes, identified peaks are recalibrated Correct All Ret. Times: No, only for identified peaks

Curve Type : Linear Origin : Connected Weight : Linear (Amnt)

Recalibration Settings: Average Response : Average all calibrations Average Retention Time: Floating Average New 75%

Calibration Report Options : Printout of recalibrations within a sequence: Calibration Table after Recalibration Normal Report after Recalibration If the sequence is done with bracketing: Results of first cycle (ending previous bracket)

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Lvl Amount Area Amt/Area Ref Grp Name [min] Sig [ug/mL] -------|--|--|----------|----------|----------|---|--|--------------- 8.536 1 1 1.03500e-1 261.37402 3.95984e-4 Hydrogen Cyanide
2 5.07300e-1 1134.77325 4.47050e-4
3 9.90500e-1 2127.66284 4.65534e-4
4 1.54100 3112.55420 4.95092e-4
5 2.08000 4013.67810 5.18228e-4

===================================================================== Peak Sum Table

=====================================================================

***No Entries in table***

===================================================================== Method H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M

Instrument 3 4/29/2010 3:35:19 PM ARM Page 1 of 2===================================================================== Calibration Curves

=====================================================================

Amount[ug/mL] 0 1 2 Area

0 500 1000 1500 2000 2500 3000 3500 4000

1 2 3 4 5 Hydrogen Cyanide at exp. RT: 8.536 ADC1 A, ADC1 CHANNEL A Correlation: 0.99877 Residual Std. Dev.: 113.97999 Formula: y = mx + b
m: 1968.68232 b: 73.79855

x: Amount y: Area Calibration Level Weights:
Level 1 : 1 Level 2 : 0.204021 Level 3 : 0.104493 Level 4 : 0.067164 Level 5 : 0.04976

===================================================================== Method H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M

Instrument 3 4/29/2010 3:35:19 PM ARM Page 2 of 2min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\001-0201.D)1.6731.7362.0392.2768.577 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.577 BB 269.92654 3.72896e-4 1.00655e-1 Hydrogen Cyanide

Totals : 1.00655e-1

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\001-0201.D Sample Name: hplc50pg50 #1

===================================================================== Acq. Operator : KHB Seq. Line : 2 Acq. Instrument : Grandmama Location : - Injection Date : 4/28/2010 7:37:40 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/8/2010 9:49:36 AM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M Last changed : 4/29/2010 3:34:02 PM by ARM

=====================================================================

Instrument 3 4/29/2010 3:35:08 PM ARM Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\001-0202.D)

A

r ea

: 25

2 .

82

11.7338.522 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.522 MM 252.82149 3.72896e-4 9.42762e-2 Hydrogen Cyanide

Totals : 9.42762e-2

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\001-0202.D Sample Name: hplc50pg50 #1

===================================================================== Acq. Operator : KHB Seq. Line : 2 Acq. Instrument : Grandmama Location : - Injection Date : 4/28/2010 7:52:55 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/8/2010 9:49:36 AM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M Last changed : 4/29/2010 3:34:02 PM by ARM

=====================================================================

Instrument 3 4/29/2010 3:35:03 PM ARM Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\002-0301.D)1.4521.7362.2728.481 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.481 BB 1100.36694 4.73887e-4 5.21449e-1 Hydrogen Cyanide

Totals : 5.21449e-1

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\002-0301.D Sample Name: hplc50pg50 #2

===================================================================== Acq. Operator : KHB Seq. Line : 3 Acq. Instrument : Grandmama Location : - Injection Date : 4/28/2010 8:08:11 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/8/2010 9:49:36 AM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M Last changed : 4/29/2010 3:34:02 PM by ARM

=====================================================================

Instrument 3 4/29/2010 3:35:38 PM ARM Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\002-0302.D)1.7322.1032.2728.459 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.459 BB 1169.17957 4.75892e-4 5.56403e-1 Hydrogen Cyanide

Totals : 5.56403e-1

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\002-0302.D Sample Name: hplc50pg50 #2

===================================================================== Acq. Operator : KHB Seq. Line : 3 Acq. Instrument : Grandmama Location : - Injection Date : 4/28/2010 8:23:27 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/8/2010 9:49:36 AM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M Last changed : 4/29/2010 3:34:02 PM by ARM

=====================================================================

Instrument 3 4/29/2010 3:35:44 PM ARM Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\003-0401.D)1.4541.7408.431 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.431 BB 2165.91235 4.90647e-4 1.06270 Hydrogen Cyanide

Totals : 1.06270

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\003-0401.D Sample Name: hplc50pg50 #3

===================================================================== Acq. Operator : KHB Seq. Line : 4 Acq. Instrument : Grandmama Location : - Injection Date : 4/28/2010 8:38:44 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/8/2010 9:49:36 AM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M Last changed : 4/29/2010 3:34:02 PM by ARM

=====================================================================

Instrument 3 4/29/2010 3:35:51 PM ARM Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\003-0402.D)1.7418.393 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.393 BB 2089.41333 4.90013e-4 1.02384 Hydrogen Cyanide

Totals : 1.02384

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\003-0402.D Sample Name: hplc50pg50 #3

===================================================================== Acq. Operator : KHB Seq. Line : 4 Acq. Instrument : Grandmama Location : - Injection Date : 4/28/2010 8:54:00 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/8/2010 9:49:36 AM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M Last changed : 4/29/2010 3:34:02 PM by ARM

=====================================================================

Instrument 3 4/29/2010 3:35:57 PM ARM Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\004-0501.D)1.4551.6711.7448.371 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.371 BB 3034.00415 4.95599e-4 1.50365 Hydrogen Cyanide

Totals : 1.50365

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\004-0501.D Sample Name: hplc50pg50 #4

===================================================================== Acq. Operator : KHB Seq. Line : 5 Acq. Instrument : Grandmama Location : - Injection Date : 4/28/2010 9:09:17 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/8/2010 9:49:36 AM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M Last changed : 4/29/2010 3:34:02 PM by ARM

=====================================================================

Instrument 3 4/29/2010 3:36:08 PM ARM Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\004-0502.D)1.4421.7348.355 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.355 BB 3191.10425 4.96207e-4 1.58345 Hydrogen Cyanide

Totals : 1.58345

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\004-0502.D Sample Name: hplc50pg50 #4

===================================================================== Acq. Operator : KHB Seq. Line : 5 Acq. Instrument : Grandmama Location : - Injection Date : 4/28/2010 9:24:33 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/8/2010 9:49:36 AM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M Last changed : 4/29/2010 3:34:02 PM by ARM

=====================================================================

Instrument 3 4/29/2010 3:36:14 PM ARM Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\005-0601.D)1.4431.6581.7312.2578.306 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.306 BB 3990.75879 4.98561e-4 1.98964 Hydrogen Cyanide

Totals : 1.98964

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\005-0601.D Sample Name: hplc50pg50 #5

===================================================================== Acq. Operator : KHB Seq. Line : 6 Acq. Instrument : Grandmama Location : - Injection Date : 4/28/2010 9:39:50 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/8/2010 9:49:36 AM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M Last changed : 4/29/2010 3:34:02 PM by ARM

=====================================================================

Instrument 3 4/29/2010 3:36:21 PM ARM Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\005-0602.D)1.6741.7401.9562.2758.315 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.315 BB 4036.59741 4.98667e-4 2.01292 Hydrogen Cyanide

Totals : 2.01292

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\005-0602.D Sample Name: hplc50pg50 #5

===================================================================== Acq. Operator : KHB Seq. Line : 6 Acq. Instrument : Grandmama Location : - Injection Date : 4/28/2010 9:55:06 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/8/2010 9:49:36 AM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M Last changed : 4/29/2010 3:34:02 PM by ARM

=====================================================================

Instrument 3 4/29/2010 3:36:27 PM ARM Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\006-0701.D)1.6731.7471.8872.2878.387 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.387 BB 1864.51013 4.87849e-4 9.09599e-1 Hydrogen Cyanide

Totals : 9.09599e-1

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\006-0701.D Sample Name: hplc50pg50 #LCS

===================================================================== Acq. Operator : KHB Seq. Line : 7 Acq. Instrument : Grandmama Location : - Injection Date : 4/28/2010 10:10:24 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/8/2010 9:49:36 AM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M Last changed : 4/29/2010 3:34:02 PM by ARM

=====================================================================

Instrument 3 4/29/2010 3:36:34 PM ARM Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\006-0702.D)

A

r ea

: 18

3 1 .1

41.3881.5881.6741.7412.2758.357 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.357 MM 1831.14062 4.87482e-4 8.92649e-1 Hydrogen Cyanide

Totals : 8.92649e-1

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\006-0702.D Sample Name: hplc50pg50 #LCS

===================================================================== Acq. Operator : KHB Seq. Line : 7 Acq. Instrument : Grandmama Location : - Injection Date : 4/28/2010 10:25:39 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/8/2010 9:49:36 AM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M Last changed : 4/29/2010 3:34:02 PM by ARM

=====================================================================

Instrument 3 4/29/2010 3:39:33 PM ARM Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\003-1101.D)1.7398.315 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.315 BB 2011.98828 4.89323e-4 9.84511e-1 Hydrogen Cyanide

Totals : 9.84511e-1

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\003-1101.D Sample Name: hplc50pg50 #3

===================================================================== Acq. Operator : KHB Seq. Line : 11 Acq. Instrument : Grandmama Location : - Injection Date : 4/29/2010 12:12:36 AM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/8/2010 9:49:36 AM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M Last changed : 4/29/2010 3:34:02 PM by ARM

=====================================================================

Instrument 3 4/29/2010 3:36:48 PM ARM Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\003-1102.D)

A

r ea

: 21

0 4 .1

61.6731.7418.341 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.341 MM 2104.15771 4.90139e-4 1.03133 Hydrogen Cyanide

Totals : 1.03133

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\003-1102.D Sample Name: hplc50pg50 #3

===================================================================== Acq. Operator : KHB Seq. Line : 11 Acq. Instrument : Grandmama Location : - Injection Date : 4/29/2010 12:27:51 AM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/8/2010 9:49:36 AM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M Last changed : 4/29/2010 3:34:02 PM by ARM

=====================================================================

Instrument 3 4/29/2010 3:37:04 PM ARM Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\003-1801.D)1.7418.321 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.321 BB 2030.78601 4.89495e-4 9.94060e-1 Hydrogen Cyanide

Totals : 9.94060e-1

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\003-1801.D Sample Name: hplc50pg50 #3

===================================================================== Acq. Operator : KHB Seq. Line : 18 Acq. Instrument : Grandmama Location : - Injection Date : 4/29/2010 3:46:32 AM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/8/2010 9:49:36 AM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M Last changed : 4/29/2010 3:34:02 PM by ARM

=====================================================================

Instrument 3 4/29/2010 3:37:14 PM ARM Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\003-1802.D)1.6771.7518.375 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.375 BB 2210.80005 4.90998e-4 1.08550 Hydrogen Cyanide

Totals : 1.08550

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\003-1802.D Sample Name: hplc50pg50 #3

===================================================================== Acq. Operator : KHB Seq. Line : 18 Acq. Instrument : Grandmama Location : - Injection Date : 4/29/2010 4:01:47 AM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/8/2010 9:49:36 AM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M Last changed : 4/29/2010 3:34:02 PM by ARM

=====================================================================

Instrument 3 4/29/2010 3:37:21 PM ARM Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\003-2501.D)

A

r ea

: 19

8 9 .3

21.4601.6771.7471.9502.2758.753 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.753 MM 1989.31726 4.89110e-4 9.72995e-1 Hydrogen Cyanide

Totals : 9.72995e-1

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\003-2501.D Sample Name: hplc50pg50 #3

===================================================================== Acq. Operator : KHB Seq. Line : 25 Acq. Instrument : Grandmama Location : - Injection Date : 4/29/2010 7:20:23 AM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/8/2010 9:49:36 AM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M Last changed : 4/29/2010 3:34:02 PM by ARM

=====================================================================

Instrument 3 4/29/2010 3:37:45 PM ARM Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\003-2502.D)1.7508.776 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.776 BB 1963.49866 4.88862e-4 9.59881e-1 Hydrogen Cyanide

Totals : 9.59881e-1

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\003-2502.D Sample Name: hplc50pg50 #3

===================================================================== Acq. Operator : KHB Seq. Line : 25 Acq. Instrument : Grandmama Location : - Injection Date : 4/29/2010 7:35:39 AM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/8/2010 9:49:36 AM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M Last changed : 4/29/2010 3:34:02 PM by ARM

=====================================================================

Instrument 3 4/29/2010 3:37:51 PM ARM Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\003-3201.D)

A

r ea

: 19

7 3 .1

71.3371.4601.6731.7441.9532.8728.766 - Hydrogen Cyanide12.62012.79112.923

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.766 MM 1973.17029 4.88956e-4 9.64793e-1 Hydrogen Cyanide

Totals : 9.64793e-1

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\003-3201.D Sample Name: hplc50pg50 #3

===================================================================== Acq. Operator : KHB Seq. Line : 32 Acq. Instrument : Grandmama Location : - Injection Date : 4/29/2010 10:54:16 AM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/8/2010 9:49:36 AM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M Last changed : 4/29/2010 3:34:02 PM by ARM

=====================================================================

Instrument 3 4/29/2010 3:38:09 PM ARM Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\003-3202.D)1.5711.6761.7485.9508.791 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.791 BB 1956.64355 4.88796e-4 9.56399e-1 Hydrogen Cyanide

Totals : 9.56399e-1

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\003-3202.D Sample Name: hplc50pg50 #3

===================================================================== Acq. Operator : KHB Seq. Line : 32 Acq. Instrument : Grandmama Location : - Injection Date : 4/29/2010 11:09:32 AM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/8/2010 9:49:36 AM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M Last changed : 4/29/2010 3:34:02 PM by ARM

=====================================================================

Instrument 3 4/29/2010 3:38:18 PM ARM Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\003-3501.D)

A

r ea

: 19

8 3 .1

61.3831.4601.6731.7412.0262.2838.737 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.737 MM 1983.16333 4.89052e-4 9.69869e-1 Hydrogen Cyanide

Totals : 9.69869e-1

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\003-3501.D Sample Name: hplc50pg50 #3

===================================================================== Acq. Operator : KHB Seq. Line : 35 Acq. Instrument : Grandmama Location : - Injection Date : 4/29/2010 12:25:55 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/8/2010 9:49:36 AM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M Last changed : 4/29/2010 3:34:02 PM by ARM

=====================================================================

Instrument 3 4/29/2010 3:38:46 PM ARM Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\003-3502.D)1.2921.7412.0428.723 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.723 BB 1926.78931 4.88499e-4 9.41234e-1 Hydrogen Cyanide

Totals : 9.41234e-1

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\003-3502.D Sample Name: hplc50pg50 #3

===================================================================== Acq. Operator : KHB Seq. Line : 35 Acq. Instrument : Grandmama Location : - Injection Date : 4/29/2010 12:41:11 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/8/2010 9:49:36 AM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M Last changed : 4/29/2010 3:34:02 PM by ARM

=====================================================================

Instrument 3 4/29/2010 3:38:33 PM ARM Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\004-4301.D)1.6561.7348.449 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.449 BB 3046.42651 4.95649e-4 1.50996 Hydrogen Cyanide

Totals : 1.50996

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\004-4301.D Sample Name: hplc50pg50 #4

===================================================================== Acq. Operator : KHB Seq. Line : 43 Acq. Instrument : Grandmama Location : - Injection Date : 4/29/2010 6:56:52 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/8/2010 9:49:36 AM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M Last changed : 4/29/2010 3:34:02 PM by ARM

=====================================================================

Instrument 3 4/30/2010 2:21:53 PM ARM Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\004-4302.D)1.6511.7258.334 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.334 BB 3101.69263 4.95868e-4 1.53803 Hydrogen Cyanide

Totals : 1.53803

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\004-4302.D Sample Name: hplc50pg50 #4

===================================================================== Acq. Operator : KHB Seq. Line : 43 Acq. Instrument : Grandmama Location : - Injection Date : 4/29/2010 7:12:07 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/8/2010 9:49:36 AM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M Last changed : 4/29/2010 3:34:02 PM by ARM

=====================================================================

Instrument 3 4/30/2010 2:21:59 PM ARM Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\004-5001.D)

A

r ea

: 32

9 4 .8

11.6561.7368.054 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.054 MM 3294.80566 4.96577e-4 1.63612 Hydrogen Cyanide

Totals : 1.63612

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\004-5001.D Sample Name: hplc50pg50 #4

===================================================================== Acq. Operator : KHB Seq. Line : 50 Acq. Instrument : Grandmama Location : - Injection Date : 4/29/2010 10:30:49 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/8/2010 9:49:36 AM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M Last changed : 4/29/2010 3:34:02 PM by ARM

=====================================================================

Instrument 3 4/30/2010 2:22:21 PM ARM Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\004-5002.D)

A

r ea

: 33

1 0 .6

71.6511.7341.8432.2598.015 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.015 MM 3310.66772 4.96631e-4 1.64418 Hydrogen Cyanide

Totals : 1.64418

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\004-5002.D Sample Name: hplc50pg50 #4

===================================================================== Acq. Operator : KHB Seq. Line : 50 Acq. Instrument : Grandmama Location : - Injection Date : 4/29/2010 10:46:05 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/8/2010 9:49:36 AM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M Last changed : 4/29/2010 3:34:02 PM by ARM

=====================================================================

Instrument 3 4/30/2010 2:22:42 PM ARM Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\004-5701.D)1.6571.7351.8552.2717.996 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 7.996 BB 3246.41724 4.96407e-4 1.61154 Hydrogen Cyanide

Totals : 1.61154

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\004-5701.D Sample Name: hplc50pg50 #4

===================================================================== Acq. Operator : KHB Seq. Line : 57 Acq. Instrument : Grandmama Location : - Injection Date : 4/30/2010 2:04:51 AM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/8/2010 9:49:36 AM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M Last changed : 4/29/2010 3:34:02 PM by ARM

=====================================================================

Instrument 3 4/30/2010 2:22:50 PM ARM Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\004-5702.D)1.6641.7428.024 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.024 BB 3291.89136 4.96567e-4 1.63464 Hydrogen Cyanide

Totals : 1.63464

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\004-5702.D Sample Name: hplc50pg50 #4

===================================================================== Acq. Operator : KHB Seq. Line : 57 Acq. Instrument : Grandmama Location : - Injection Date : 4/30/2010 2:20:13 AM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/8/2010 9:49:36 AM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M Last changed : 4/29/2010 3:34:02 PM by ARM

=====================================================================

Instrument 3 4/30/2010 2:23:04 PM ARM Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\004-6401.D)1.6651.7468.335 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.335 BB 3212.47803 4.96285e-4 1.59430 Hydrogen Cyanide

Totals : 1.59430

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\004-6401.D Sample Name: hplc50pg50 #4

===================================================================== Acq. Operator : KHB Seq. Line : 64 Acq. Instrument : Grandmama Location : - Injection Date : 4/30/2010 5:38:54 AM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/8/2010 9:49:36 AM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M Last changed : 4/29/2010 3:34:02 PM by ARM

=====================================================================

Instrument 3 4/30/2010 2:23:12 PM ARM Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\004-6402.D)

A

r ea

: 32

5 3 .2

41.6561.7368.324 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.324 MM 3253.24146 4.96431e-4 1.61501 Hydrogen Cyanide

Totals : 1.61501

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\004-6402.D Sample Name: hplc50pg50 #4

===================================================================== Acq. Operator : KHB Seq. Line : 64 Acq. Instrument : Grandmama Location : - Injection Date : 4/30/2010 5:54:10 AM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/8/2010 9:49:36 AM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M Last changed : 4/29/2010 3:34:02 PM by ARM

=====================================================================

Instrument 3 4/30/2010 2:23:29 PM ARM Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\004-7101.D)1.6541.7348.396 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.396 BB 3107.08252 4.95889e-4 1.54077 Hydrogen Cyanide

Totals : 1.54077

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\004-7101.D Sample Name: hplc50pg50 #4

===================================================================== Acq. Operator : KHB Seq. Line : 71 Acq. Instrument : Grandmama Location : - Injection Date : 4/30/2010 9:12:45 AM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/8/2010 9:49:36 AM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M Last changed : 4/29/2010 3:34:02 PM by ARM

=====================================================================

Instrument 3 4/30/2010 2:23:36 PM ARM Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\004-7102.D)

A

r ea

: 31

9 6 .8

91.6551.7332.2588.391 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.391 MM 3196.88696 4.96228e-4 1.58639 Hydrogen Cyanide

Totals : 1.58639

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\004-7102.D Sample Name: hplc50pg50 #4

===================================================================== Acq. Operator : KHB Seq. Line : 71 Acq. Instrument : Grandmama Location : - Injection Date : 4/30/2010 9:28:02 AM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/8/2010 9:49:36 AM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M Last changed : 4/29/2010 3:34:02 PM by ARM

=====================================================================

Instrument 3 4/30/2010 2:23:50 PM ARM Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\004-7701.D)1.6641.7398.435 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.435 BB 3081.66040 4.95790e-4 1.52786 Hydrogen Cyanide

Totals : 1.52786

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\004-7701.D Sample Name: hplc50pg50 #4

===================================================================== Acq. Operator : KHB Seq. Line : 77 Acq. Instrument : Grandmama Location : - Injection Date : 4/30/2010 12:16:03 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/8/2010 9:49:36 AM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M Last changed : 4/29/2010 3:34:02 PM by ARM

=====================================================================

Instrument 3 4/30/2010 2:24:00 PM ARM Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\004-7702.D)1.6581.7358.415 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.415 BB 3274.68652 4.96507e-4 1.62590 Hydrogen Cyanide

Totals : 1.62590

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\004-7702.D Sample Name: hplc50pg50 #4

===================================================================== Acq. Operator : KHB Seq. Line : 77 Acq. Instrument : Grandmama Location : - Injection Date : 4/30/2010 12:31:19 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/8/2010 9:49:36 AM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M Last changed : 4/29/2010 3:34:02 PM by ARM

=====================================================================

Instrument 3 4/30/2010 2:24:17 PM ARM Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\004-8401.D)1.6611.7352.2698.437 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.437 BB 3363.30884 4.96808e-4 1.67092 Hydrogen Cyanide

Totals : 1.67092

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\004-8401.D Sample Name: hplc50pg50 #4

===================================================================== Acq. Operator : KHB Seq. Line : 84 Acq. Instrument : Grandmama Location : - Injection Date : 4/30/2010 4:24:49 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/30/2010 12:54:42 PM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M Last changed : 4/29/2010 3:34:02 PM by ARM

=====================================================================

Instrument 3 4/30/2010 4:42:50 PM ARM Page 1 of 1min 0 2 4 6 8 10 12 nC

50 100 150 200 250 300 350 400 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\004-8402.D)1.6601.7368.432 - Hydrogen Cyanide

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [nC*s] [ug/mL] -------|------|----------|----------|----------|--|------------------ 8.432 BB 3268.78979 4.96486e-4 1.62291 Hydrogen Cyanide

Totals : 1.62291

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\004-8402.D Sample Name: hplc50pg50 #4

===================================================================== Acq. Operator : KHB Seq. Line : 84 Acq. Instrument : Grandmama Location : - Injection Date : 4/30/2010 4:40:05 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Last changed : 4/30/2010 12:54:42 PM by KHB Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M Last changed : 4/29/2010 3:34:02 PM by ARM

=====================================================================

Instrument 3 4/30/2010 4:55:11 PM ARM Page 1 of 1Method Information

Method: H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Modified: 3/17/2010 at 9:48:43 AM

Column: Dionex Ionpac AS7 4 X 250mm Eluent: 0.5M Sodium Acetate/0.1M NaOH/0.5% v/v Ethylenediamine Flow rate: 1.0 mL/min

========================================================================= ANALOG DIGITAL CONVERTER

========================================================================= Signal 1

--------------------- Description: ADC1 CHANNEL A Source: Signal Unit: nC Units/Volt: 1000.000 Peakwidth (Data Rate): 0.133 Min (2.00 Hz) Stop Time: 14.01 Min Data Storage: All

Start Signal Source: External Device Will Start 35900

Timed Event Table:

<no events> method: H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M Modified on: 3/17/2010 at 9:48:43 AM

Grandmama 3/17/2010 9:49:42 AM KHB Page 1 of 1Sequence Table:

Method and Injection Info Part:

Line Location SampleName Method Inj SampleType InjVolume DataFile AutoBalance LimsID

==== ======== ==================== ==================== ======== ========== =========

1 Vial 7 0.1N NaOH - RB 1000 4 Sample

2 Vial 1 hplc50pg50 #1 1000 2 Sample

3 Vial 2 hplc50pg50 #2 1000 2 Sample

4 Vial 3 hplc50pg50 #3 1000 2 Sample

5 Vial 4 hplc50pg50 #4 1000 2 Sample

6 Vial 5 hplc50pg50 #5 1000 2 Sample

7 Vial 6 hplc50pg50 #LCS 1000 2 Sample

8 Vial 7 0.1N NaOH - RB 1000 2 Sample

9 Vial 81 CTM033-1*5 0410-125 1000 2 Sample

10 Vial 82 CTM033-2*5 0410-125 1000 2 Sample

11 Vial 3 hplc50pg50 #3 1000 2 Sample

12 Vial 4 hplc50pg50 #4 1000 2 Sample

13 Vial 8 Run 1*5 0310-129 1000 2 Sample

14 Vial 9 Run 2*5 0310-129 1000 2 Sample

15 Vial 10 Run 3*5 0310-129 1000 2 Sample

16 Vial 11 Field Tr Blk*5 0310-129 1000 2 Sample

17 Vial 12 Reagent Blk*5 0310-129 1000 2 Sample

18 Vial 3 hplc50pg50 #3 1000 2 Sample

19 Vial 4 hplc50pg50 #4 1000 2 Sample

20 Vial 13 Imp Spk*5 0310-129 1000 2 Sample

21 Vial 14 LCS 1*100 0310-129 1000 2 Sample

22 Vial 15 LCS 2*100 0310-129 1000 2 Sample

23 Vial 16 U1-1*5 0410-101 1000 2 Sample

24 Vial 17 U1-2*5 0410-101 1000 2 Sample

25 Vial 3 hplc50pg50 #3 1000 2 Sample

26 Vial 4 hplc50pg50 #4 1000 2 Sample

27 Vial 18 U1-3*5 0410-101 1000 2 Sample Sequence: H:\HPLC2010Q1\GRANDMAM\SEQUENCE\HPLC50PG76.S

Instrument 3 4/30/2010 3:50:31 PM ARM Page 1 of 5Line Location SampleName Method Inj SampleType InjVolume DataFile AutoBalance LimsID

==== ======== ==================== ==================== ======== ========== =========

28 Vial 19 U2-1*5 0410-101 1000 2 Sample

29 Vial 20 U2-2*5 0410-101 1000 2 Sample

30 Vial 21 U2-3*5 0410-101 1000 2 Sample

31 Vial 22 10N Rgt Blk*5 0410-101 1000 2 Sample

32 Vial 3 hplc50pg50 #3 1000 2 Sample

33 Vial 4 hplc50pg50 #4 1000 2 Sample

34 Vial 23 Field Blank*5 0410-101 1000 2 Sample

35 Vial 3 hplc50pg50 #3 1000 2 Sample

36 Vial 4 hplc50pg50 #4 1000 2 Sample

37 Vial 26 U1-HCN-NaOH-1*5 0410-22 1000 2 Sample

38 Vial 27 U1-HCN-PbAc-1*5 0410-22 1000 2 Sample

39 Vial 28 U1-HCN-NaOH-2*5 0410-22 1000 2 Sample

40 Vial 29 U1-HCN-PbAc-2*5 0410-22 1000 2 Sample

41 Vial 30 U1-HCN-NaOH-3*5 0410-22 1000 2 Sample

42 Vial 3 hplc50pg50 #3 1000 2 Sample

43 Vial 4 hplc50pg50 #4 1000 2 Sample

44 Vial 31 U1-HCN-PbAc-3*5 0410-22 1000 2 Sample

45 Vial 32 U2-HCN-NaOH-1*5 0410-22 1000 2 Sample

46 Vial 33 U2-HCN-PbAc-1*5 0410-22 1000 2 Sample

47 Vial 34 U2-HCN-NaOH-2*5 0410-22 1000 2 Sample

48 Vial 35 U2-HCN-PbAc-2*5 0410-22 1000 2 Sample

49 Vial 3 hplc50pg50 #3 1000 2 Sample

50 Vial 4 hplc50pg50 #4 1000 2 Sample

51 Vial 36 U2-HCN-NaOH-3*5 0410-22 1000 2 Sample

52 Vial 37 U2-HCN-PbAc-3*5 0410-22 1000 2 Sample

53 Vial 38 FB-NaOH*5 0410-22 1000 2 Sample

54 Vial 39 RB-NaOH*5 0410-22 1000 2 Sample

55 Vial 40 FS-NaOH*5 0410-22 1000 2 Sample

56 Vial 3 hplc50pg50 #3 1000 2 Sample

57 Vial 4 hplc50pg50 #4 1000 2 Sample Sequence: H:\HPLC2010Q1\GRANDMAM\SEQUENCE\HPLC50PG76.S

Instrument 3 4/30/2010 3:50:31 PM ARM Page 2 of 5Line Location SampleName Method Inj SampleType InjVolume DataFile AutoBalance LimsID

==== ======== ==================== ==================== ======== ========== =========

58 Vial 41 FB-PbAc*5 0410-22 1000 2 Sample

59 Vial 42 RB-PbAc*5 0410-22 1000 2 Sample

60 Vial 43 LCS 1*100 0410-22 1000 2 Sample

61 Vial 44 LCS 2*100 0410-22 1000 2 Sample

62 Vial 45 M26-1*5 0310-104 1000 2 Sample

63 Vial 3 hplc50pg50 #3 1000 2 Sample

64 Vial 4 hplc50pg50 #4 1000 2 Sample

65 Vial 46 M26-2*5 0310-104 1000 2 Sample

66 Vial 47 M26-3*5 0310-104 1000 2 Sample

67 Vial 48 M26-FB*5 0310-104 1000 2 Sample

68 Vial 49 M26-FS*5 0310-104 1000 2 Sample

69 Vial 50 M26-RB*5 0310-104 1000 2 Sample

70 Vial 3 hplc50pg50 #3 1000 2 Sample

71 Vial 4 hplc50pg50 #4 1000 2 Sample

72 Vial 51 LCS 1*100 0310-104 1000 2 Sample

73 Vial 52 LCS 2*100 0310-104 1000 2 Sample

74 Vial 53 LCS 1*100 0410-95 1000 2 Sample

75 Vial 54 LCS 2*100 0410-95 1000 2 Sample

76 Vial 3 hplc50pg50 #3 1000 2 Sample

77 Vial 4 hplc50pg50 #4 1000 2 Sample

78 Vial 55 LD/Run 1*5 0310-129 1000 2 Sample

79 Vial 56 MS/Run 1 0310-129 1000 2 Sample

80 Vial 57 MSD/Run 1 0310-129 1000 2 Sample

81 Vial 58 LCS 1*100 0310-129 1000 2 Sample

82 Vial 59 LCS 2*100 0310-129 1000 2 Sample

83 Vial 3 hplc50pg50 #3 1000 2 Sample

84 Vial 4 hplc50pg50 #4 1000 2 Sample

85 Vial 60 LD/R1 6N NaOH*5 0410-95 1000 2 Sample

86 Vial 61 MS/R1 6N NaOH 0410-95 1000 2 Sample

87 Vial 62 MSD/R1 6N NaOH 0410-95 1000 2 Sample Sequence: H:\HPLC2010Q1\GRANDMAM\SEQUENCE\HPLC50PG76.S

Instrument 3 4/30/2010 3:50:31 PM ARM Page 3 of 5Line Location SampleName Method Inj SampleType InjVolume DataFile AutoBalance LimsID

==== ======== ==================== ==================== ======== ========== =========

88 Vial 63 LD/R1 C4*5 0410-50 1000 2 Sample

89 Vial 64 MS/R1 C4 0410-50 1000 2 Sample

90 Vial 3 hplc50pg50 #3 1000 2 Sample

91 Vial 4 hplc50pg50 #4 1000 2 Sample

92 Vial 65 MSD/R1 C4 0410-50 1000 2 Sample

93 Vial 66 LD/U1 R1*5 0410-101 1000 2 Sample

94 Vial 67 MS/U1 R1 0410-101 1000 2 Sample

95 Vial 68 MSD/U1 R1 0410-101 1000 2 Sample

96 Vial 69 LD/U1-1*5 0410-22 1000 2 Sample

97 Vial 3 hplc50pg50 #3 1000 2 Sample

98 Vial 4 hplc50pg50 #4 1000 2 Sample

99 Vial 70 MS/U1-1 0410-22 1000 2 Sample

100 Vial 71 MSD/U1-1 0410-22 1000 2 Sample

101 Vial 72 LD/U2-1*5 0410-22 1000 2 Sample

102 Vial 73 MS/U2-1 0410-22 1000 2 Sample

103 Vial 74 MSD/U2-1 0410-22 1000 2 Sample

104 Vial 3 hplc50pg50 #3 1000 2 Sample

105 Vial 4 hplc50pg50 #4 1000 2 Sample

106 Vial 75 LD/M26-1*5 0310-104 1000 2 Sample

107 Vial 76 MS/M26-1 0310-104 1000 2 Sample

108 Vial 77 MSD/M26-1 0310-104 1000 2 Sample

109 Vial 78 U1,2 R1*5 0410-106 1000 2 Sample

110 Vial 79 U1,2 R2*5 0410-106 1000 2 Sample

111 Vial 3 hplc50pg50 #3 1000 2 Sample

112 Vial 4 hplc50pg50 #4 1000 2 Sample

113 Vial 80 U1,2 R3*5 0410-106 1000 2 Sample

114 Vial 81 U3 R1*5 0410-106 1000 2 Sample

115 Vial 82 U3 R2*5 0410-106 1000 2 Sample

116 Vial 83 U3 R3*5 0410-106 1000 2 Sample

117 Vial 84 RB*5 0410-106 1000 2 Sample Sequence: H:\HPLC2010Q1\GRANDMAM\SEQUENCE\HPLC50PG76.S

Instrument 3 4/30/2010 3:50:31 PM ARM Page 4 of 5Line Location SampleName Method Inj SampleType InjVolume DataFile AutoBalance LimsID

==== ======== ==================== ==================== ======== ========== =========

118 Vial 3 hplc50pg50 #3 1000 2 Sample

119 Vial 4 hplc50pg50 #4 1000 2 Sample Sequence: H:\HPLC2010Q1\GRANDMAM\SEQUENCE\HPLC50PG76.S

Instrument 3 4/30/2010 3:50:31 PM ARM Page 5 of 5

# Sample Chromatograms===================================================================== Acq. Operator : KHB Seq. Line : 4 Acq. Instrument : Groucho Location : Vial 11 Injection Date : 4/27/2010 5:22:46 PM Inj : 1 Inj Volume : 15 μl Acq. Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG84@.M Last changed : 4/7/2010 2:42:28 PM by KHB Analysis Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG86D.M Last changed : 4/29/2010 6:04:31 PM by ARM (modified after loading)

min 5 10 15 20 25 30 mAU

0 100 200 300 400 500 600 700 800 VWD1 A, Wavelength=360 nm (H:\HPLC 2010Q2\GROUCHO\DATA\APR\HPLC48PG102\011-0401.D)

A

r ea

: 10

9
.

11

30.8111.0351.4862.1103.6014.2904.9746.571 - Formaldehyde8.59810.837

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 4/29/2010 6:04:32 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: VWD1 A, Wavelength=360 nm

RetTime Type Area Amt/Area Amount Grp Name [min] mAU *s [ug/mL] -------|------|----------|----------|----------|--|------------------ 6.571 MM 109.11267 2.07188e-3 2.26069e-1 Formaldehyde

Totals : 2.26069e-1

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GROUCHO\DATA\APR\HPLC48PG102\011-0401.D Sample Name: Run 1 0310-129

Instrument 3 4/29/2010 6:08:54 PM ARM Page 1 of 1===================================================================== Acq. Operator : KHB Seq. Line : 5 Acq. Instrument : Groucho Location : Vial 11 Injection Date : 4/27/2010 5:59:25 PM Inj : 1 Inj Volume : 15 μl Acq. Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG84@.M Last changed : 4/7/2010 2:42:28 PM by KHB Analysis Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG86D.M Last changed : 4/29/2010 6:04:31 PM by ARM (modified after loading) Sample Info : Duplicate Injection

min 5 10 15 20 25 30 mAU

0 100 200 300 400 500 600 700 800 VWD1 A, Wavelength=360 nm (H:\HPLC 2010Q2\GROUCHO\DATA\APR\HPLC48PG102\011-0501.D)

A

r ea

: 10

9
.

49

90.8131.0571.2601.5172.1463.6334.3074.9916.581 - Formaldehyde8.59010.801

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 4/29/2010 6:04:32 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: VWD1 A, Wavelength=360 nm

RetTime Type Area Amt/Area Amount Grp Name [min] mAU *s [ug/mL] -------|------|----------|----------|----------|--|------------------ 6.581 MM 109.49865 2.07188e-3 2.26869e-1 Formaldehyde

Totals : 2.26869e-1

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GROUCHO\DATA\APR\HPLC48PG102\011-0501.D Sample Name: Run 1 0310-129

Instrument 3 4/29/2010 6:09:11 PM ARM Page 1 of 1===================================================================== Acq. Operator : KHB Seq. Line : 6 Acq. Instrument : Groucho Location : Vial 12 Injection Date : 4/27/2010 6:36:00 PM Inj : 1 Inj Volume : 15 μl Acq. Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG84@.M Last changed : 4/7/2010 2:42:28 PM by KHB Analysis Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG86D.M Last changed : 4/29/2010 6:09:28 PM by ARM (modified after loading) Sample Info : Duplicate Sample

min 5 10 15 20 25 30 mAU

0 100 200 300 400 500 600 700 800 VWD1 A, Wavelength=360 nm (H:\HPLC 2010Q2\GROUCHO\DATA\APR\HPLC48PG102\012-0601.D)

A

r ea

: 13

2 .

50

90.9051.0771.5462.1983.7174.5515.6827.623 - Formaldehyde9.19411.244

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 4/29/2010 6:09:28 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: VWD1 A, Wavelength=360 nm

RetTime Type Area Amt/Area Amount Grp Name [min] mAU *s [ug/mL] -------|------|----------|----------|----------|--|------------------ 7.623 MM 132.50926 2.07188e-3 2.74544e-1 Formaldehyde

Totals : 2.74544e-1

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GROUCHO\DATA\APR\HPLC48PG102\012-0601.D Sample Name: Run 1 Dup 0310-129

Instrument 3 4/29/2010 6:09:31 PM ARM Page 1 of 1===================================================================== Acq. Operator : KHB Seq. Line : 7 Acq. Instrument : Groucho Location : Vial 13 Injection Date : 4/27/2010 7:12:38 PM Inj : 1 Inj Volume : 15 μl Acq. Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG84@.M Last changed : 4/7/2010 2:42:28 PM by KHB Analysis Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG86D.M Last changed : 4/29/2010 6:09:36 PM by ARM (modified after loading)

min 5 10 15 20 25 30 mAU

0 100 200 300 400 500 600 700 800 VWD1 A, Wavelength=360 nm (H:\HPLC 2010Q2\GROUCHO\DATA\APR\HPLC48PG102\013-0701.D)

A

r ea

: 81 .

3 89

30.8801.0521.5102.1273.6094.2726.523 - Formaldehyde8.48910.729

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 4/29/2010 6:09:37 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: VWD1 A, Wavelength=360 nm

RetTime Type Area Amt/Area Amount Grp Name [min] mAU *s [ug/mL] -------|------|----------|----------|----------|--|------------------ 6.523 MM 81.38933 2.07188e-3 1.68629e-1 Formaldehyde

Totals : 1.68629e-1

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GROUCHO\DATA\APR\HPLC48PG102\013-0701.D Sample Name: Run 2 0310-129

Instrument 3 4/29/2010 6:09:55 PM ARM Page 1 of 1===================================================================== Acq. Operator : KHB Seq. Line : 8 Acq. Instrument : Groucho Location : Vial 14 Injection Date : 4/27/2010 7:49:19 PM Inj : 1 Inj Volume : 15 μl Acq. Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG84@.M Last changed : 4/7/2010 2:42:28 PM by KHB Analysis Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG86D.M Last changed : 4/29/2010 6:09:36 PM by ARM (modified after loading)

min 5 10 15 20 25 30 mAU

0 100 200 300 400 500 600 700 800 VWD1 A, Wavelength=360 nm (H:\HPLC 2010Q2\GROUCHO\DATA\APR\HPLC48PG102\014-0801.D)

A

r ea

: 10

3

. 68

80.8961.0681.5402.1493.5934.2094.9496.431 - Formaldehyde10.599

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 4/29/2010 6:09:37 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: VWD1 A, Wavelength=360 nm

RetTime Type Area Amt/Area Amount Grp Name [min] mAU *s [ug/mL] -------|------|----------|----------|----------|--|------------------ 6.431 MM 103.68850 2.07188e-3 2.14831e-1 Formaldehyde

Totals : 2.14831e-1

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GROUCHO\DATA\APR\HPLC48PG102\014-0801.D Sample Name: Run 3 0310-129

Instrument 3 4/29/2010 6:10:07 PM ARM Page 1 of 1===================================================================== Acq. Operator : KHB Seq. Line : 9 Acq. Instrument : Groucho Location : Vial 15 Injection Date : 4/27/2010 8:25:55 PM Inj : 1 Inj Volume : 15 μl Acq. Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG84@.M Last changed : 4/7/2010 2:42:28 PM by KHB Analysis Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG86D.M Last changed : 4/29/2010 6:09:36 PM by ARM (modified after loading)

min 5 10 15 20 25 30 mAU

0 100 200 300 400 500 600 700 800 VWD1 A, Wavelength=360 nm (H:\HPLC 2010Q2\GROUCHO\DATA\APR\HPLC48PG102\015-0901.D)

A

r ea

: 81

8

. 96

70.8891.0691.5282.1223.5354.2514.8756.484 - Formaldehyde8.38210.48411.457

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 4/29/2010 6:09:37 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: VWD1 A, Wavelength=360 nm

RetTime Type Area Amt/Area Amount Grp Name [min] mAU *s [ug/mL] -------|------|----------|----------|----------|--|------------------ 6.484 MM 818.96747 2.07188e-3 1.69681 Formaldehyde

Totals : 1.69681

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GROUCHO\DATA\APR\HPLC48PG102\015-0901.D Sample Name: Matrix Spike 0310-129

Instrument 3 4/29/2010 6:10:19 PM ARM Page 1 of 1===================================================================== Acq. Operator : KHB Seq. Line : 10 Acq. Instrument : Groucho Location : Vial 16 Injection Date : 4/27/2010 9:02:29 PM Inj : 1 Inj Volume : 15 μl Acq. Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG84@.M Last changed : 4/7/2010 2:42:28 PM by KHB Analysis Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG86D.M Last changed : 4/29/2010 6:09:36 PM by ARM (modified after loading)

min 5 10 15 20 25 30 mAU

0 100 200 300 400 500 600 700 800 VWD1 A, Wavelength=360 nm (H:\HPLC 2010Q2\GROUCHO\DATA\APR\HPLC48PG102\016-1001.D)

A

r ea

: 26

3 9 .0

70.8350.9161.0731.5652.1563.5686.578 - Formaldehyde10.76611.39013.971

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 4/29/2010 6:09:37 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: VWD1 A, Wavelength=360 nm

RetTime Type Area Amt/Area Amount Grp Name [min] mAU *s [ug/mL] -------|------|----------|----------|----------|--|------------------ 6.578 MM 2639.06616 2.07188e-3 5.46784 Formaldehyde

Totals : 5.46784

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GROUCHO\DATA\APR\HPLC48PG102\016-1001.D Sample Name: Imp Spike 0310-129

Instrument 3 4/29/2010 6:10:33 PM ARM Page 1 of 1===================================================================== Acq. Operator : KHB Seq. Line : 11 Acq. Instrument : Groucho Location : Vial 17 Injection Date : 4/27/2010 9:39:05 PM Inj : 1 Inj Volume : 15 μl Acq. Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG84@.M Last changed : 4/7/2010 2:42:28 PM by KHB Analysis Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG86D.M Last changed : 4/29/2010 5:46:03 PM by ARM (modified after loading) Sample Info : Sample Blank

min 5 10 15 20 25 30 mAU

0 100 200 300 400 500 600 700 800 VWD1 A, Wavelength=360 nm (H:\HPLC 2010Q2\GROUCHO\DATA\APR\HPLC48PG102\017-1101.D)0.8801.0671.5682.1444.5567.66311.077

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 4/29/2010 5:46:07 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: VWD1 A, Wavelength=360 nm

RetTime Type Area Amt/Area Amount Grp Name [min] mAU *s [ug/mL] -------|------|----------|----------|----------|--|------------------ 6.578 - - - Formaldehyde

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

===================================================================== Data File H:\HPLC2010Q2\GROUCHO\DATA\APR\HPLC48PG102\017-1101.D Sample Name: Field Blank 0310-129

Instrument 3 4/29/2010 5:46:41 PM ARM Page 1 of 2===================================================================== Acq. Operator : KHB Seq. Line : 12 Acq. Instrument : Groucho Location : Vial 18 Injection Date : 4/27/2010 10:15:50 PM Inj : 1 Inj Volume : 15 μl Acq. Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG84@.M Last changed : 4/7/2010 2:42:28 PM by KHB Analysis Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG86D.M Last changed : 4/29/2010 6:09:36 PM by ARM (modified after loading) Sample Info : Sample Blank

min 5 10 15 20 25 30 mAU

0 100 200 300 400 500 600 700 800 VWD1 A, Wavelength=360 nm (H:\HPLC 2010Q2\GROUCHO\DATA\APR\HPLC48PG102\018-1201.D)0.8151.0781.5672.1613.5706.543 - Formaldehyde10.472

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 4/29/2010 6:09:37 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: VWD1 A, Wavelength=360 nm

RetTime Type Area Amt/Area Amount Grp Name [min] mAU *s [ug/mL] -------|------|----------|----------|----------|--|------------------ 6.543 BB 18.28996 2.07188e-3 3.78947e-2 Formaldehyde

Totals : 3.78947e-2

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GROUCHO\DATA\APR\HPLC48PG102\018-1201.D Sample Name: Reagent Blank 0310-129

Instrument 3 4/29/2010 6:10:56 PM ARM Page 1 of 1===================================================================== Acq. Operator : KHB Seq. Line : 14 Acq. Instrument : Groucho Location : Vial 19 Injection Date : 4/27/2010 11:29:13 PM Inj : 1 Inj Volume : 15 μl Acq. Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG84@.M Last changed : 4/7/2010 2:42:28 PM by KHB Analysis Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG86D.M Last changed : 4/29/2010 6:11:11 PM by ARM (modified after loading) Sample Info : Sample Blank

min 5 10 15 20 25 30 mAU

0 100 200 300 400 500 600 700 800 VWD1 A, Wavelength=360 nm (H:\HPLC 2010Q2\GROUCHO\DATA\APR\HPLC48PG102\019-1401.D)0.8481.0911.6012.1913.6166.772 - Formaldehyde10.728

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 4/29/2010 6:11:12 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: VWD1 A, Wavelength=360 nm

RetTime Type Area Amt/Area Amount Grp Name [min] mAU *s [ug/mL] -------|------|----------|----------|----------|--|------------------ 6.772 BB 82.81754 2.07188e-3 1.71588e-1 Formaldehyde

Totals : 1.71588e-1

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GROUCHO\DATA\APR\HPLC48PG102\019-1401.D Sample Name: Sample Blank 0310-129

Instrument 3 4/29/2010 6:11:23 PM ARM Page 1 of 1===================================================================== Acq. Operator : KHB Seq. Line : 16 Acq. Instrument : Groucho Location : Vial 21 Injection Date : 4/28/2010 12:42:33 AM Inj : 1 Inj Volume : 15 μl Acq. Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG84@.M Last changed : 4/7/2010 2:42:28 PM by KHB Analysis Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG86D.M Last changed : 4/29/2010 5:46:03 PM by ARM (modified after loading) Sample Info : Method Blank

min 5 10 15 20 25 30 mAU

0 100 200 300 400 500 600 700 800 VWD1 A, Wavelength=360 nm (H:\HPLC 2010Q2\GROUCHO\DATA\APR\HPLC48PG102\021-1601.D)0.8441.0871.5933.545

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 4/29/2010 5:46:07 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: VWD1 A, Wavelength=360 nm

RetTime Type Area Amt/Area Amount Grp Name [min] mAU *s [ug/mL] -------|------|----------|----------|----------|--|------------------ 6.578 - - - Formaldehyde

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

===================================================================== Data File H:\HPLC2010Q2\GROUCHO\DATA\APR\HPLC48PG102\021-1601.D Sample Name: MB 4/20/10 0310-129

Instrument 3 4/29/2010 5:47:16 PM ARM Page 1 of 2===================================================================== Acq. Operator : KHB Seq. Line : 27 Acq. Instrument : Groucho Location : Vial 25 Injection Date : 4/28/2010 10:21:47 PM Inj : 1 Inj Volume : 15 μl Acq. Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG84@.M Last changed : 4/7/2010 2:42:28 PM by KHB Analysis Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG86D.M Last changed : 4/29/2010 5:48:14 PM by ARM (modified after loading) Sample Info : Method Blank

min 5 10 15 20 25 30 mAU

0 100 200 300 400 500 600 700 800 VWD1 A, Wavelength=360 nm (H:\HPLC 2010Q2\GROUCHO\DATA\APR\HPLC48PG102\025-2701.D)0.9110.9701.1941.7572.4574.10411.140

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 4/29/2010 5:48:15 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: VWD1 A, Wavelength=360 nm

RetTime Type Area Amt/Area Amount Grp Name [min] mAU *s [ug/mL] -------|------|----------|----------|----------|--|------------------ 7.291 - - - Formaldehyde

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

===================================================================== Data File H:\HPLC2010Q2\GROUCHO\DATA\APR\HPLC48PG102\025-2701.D Sample Name: MB 4/28/10 0310-129

Instrument 3 4/29/2010 5:48:59 PM ARM Page 1 of 2===================================================================== Acq. Operator : KHB Seq. Line : 9 Acq. Instrument : Groucho Location : Vial 8 Injection Date : 4/9/2010 2:42:40 AM Inj : 1 Inj Volume : 15 μl Acq. Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG84@.M Last changed : 4/7/2010 2:42:28 PM by KHB Analysis Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG86B.M Last changed : 4/9/2010 11:19:06 AM by KHB (modified after loading) Sample Info : Reagent Blank Acetonitrile

min 5 10 15 20 25 30 mAU

0 100 200 300 400 500 600 700 800 VWD1 A, Wavelength=360 nm (H:\HPL C2010Q2\GROUCHO\DATA\APR\0310-39B\008-0901.D)0.9611.413

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 4/9/2010 11:19:07 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: VWD1 A, Wavelength=360 nm

RetTime Type Area Amt/Area Amount Grp Name [min] mAU *s [ug/mL] -------|------|----------|----------|----------|--|------------------ 5.862 - - - Formaldehyde 7.737 - - - Acetaldehyde

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

===================================================================== Data File H:\HPLC2010Q2\GROUCHO\DATA\APR\0310-39B\008-0901.D Sample Name: RB/100% ACN

Instrument 3 4/9/2010 11:33:59 AM KHB Page 1 of 2===================================================================== Acq. Operator : KHB Seq. Line : 9 Acq. Instrument : Groucho Location : Vial 8 Injection Date : 4/9/2010 3:19:16 AM Inj : 2 Inj Volume : 15 μl Acq. Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG84@.M Last changed : 4/7/2010 2:42:28 PM by KHB Analysis Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG86B.M Last changed : 4/9/2010 11:19:06 AM by KHB (modified after loading) Sample Info : Reagent Blank Acetonitrile

min 5 10 15 20 25 30 mAU

0 100 200 300 400 500 600 700 800 VWD1 A, Wavelength=360 nm (H:\HPL C2010Q2\GROUCHO\DATA\APR\0310-39B\008-0902.D)0.9651.419

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 4/9/2010 11:19:07 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: VWD1 A, Wavelength=360 nm

RetTime Type Area Amt/Area Amount Grp Name [min] mAU *s [ug/mL] -------|------|----------|----------|----------|--|------------------ 5.862 - - - Formaldehyde 7.737 - - - Acetaldehyde

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

===================================================================== Data File H:\HPLC2010Q2\GROUCHO\DATA\APR\0310-39B\008-0902.D Sample Name: RB/100% ACN

Instrument 3 4/9/2010 11:34:09 AM KHB Page 1 of 2===================================================================== Acq. Operator : KHB Seq. Line : 3 Acq. Instrument : Groucho Location : Vial 2 Injection Date : 4/27/2010 4:46:06 PM Inj : 1 Inj Volume : 15 μl Acq. Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG84@.M Last changed : 4/7/2010 2:42:28 PM by KHB Analysis Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG86D.M Last changed : 4/29/2010 5:43:30 PM by ARM (modified after loading) Sample Info : Lab Blank Acetonitrile

min 5 10 15 20 25 30 mAU

0 100 200 300 400 500 600 700 800 VWD1 A, Wavelength=360 nm (H:\HPLC 2010Q2\GROUCHO\DATA\APR\HPLC48PG102\002-0301.D)0.9341.0791.560

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 4/29/2010 5:43:30 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: VWD1 A, Wavelength=360 nm

RetTime Type Area Amt/Area Amount Grp Name [min] mAU *s [ug/mL] -------|------|----------|----------|----------|--|------------------ 6.808 - - - Formaldehyde

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

===================================================================== Data File H:\HPLC2010Q2\GROUCHO\DATA\APR\HPLC48PG102\002-0301.D Sample Name: RB/100% ACN

Instrument 3 4/29/2010 5:44:30 PM ARM Page 1 of 2===================================================================== Acq. Operator : KHB Seq. Line : 24 Acq. Instrument : Groucho Location : Vial 22 Injection Date : 4/28/2010 8:31:56 PM Inj : 1 Inj Volume : 15 μl Acq. Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG84@.M Last changed : 4/7/2010 2:42:28 PM by KHB Analysis Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG86D.M Last changed : 4/29/2010 6:12:09 PM by ARM (modified after loading) Sample Info : Matrix Spike

min 5 10 15 20 25 30 mAU

0 100 200 300 400 500 600 700 800 VWD1 A, Wavelength=360 nm (H:\HPLC 2010Q2\GROUCHO\DATA\APR\HPLC48PG102\022-2401.D)

A

r ea

: 13

3 7 .2

10.9471.1921.4521.7562.4824.1534.9267.396 - Formaldehyde11.221

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 4/29/2010 6:12:10 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: VWD1 A, Wavelength=360 nm

RetTime Type Area Amt/Area Amount Grp Name [min] mAU *s [ug/mL] -------|------|----------|----------|----------|--|------------------ 7.396 MM 1337.20776 2.07188e-3 2.77054 Formaldehyde

Totals : 2.77054

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GROUCHO\DATA\APR\HPLC48PG102\022-2401.D Sample Name: MS/Run 2 0310-129

Instrument 3 4/29/2010 6:12:20 PM ARM Page 1 of 1===================================================================== Acq. Operator : KHB Seq. Line : 25 Acq. Instrument : Groucho Location : Vial 23 Injection Date : 4/28/2010 9:08:33 PM Inj : 1 Inj Volume : 15 μl Acq. Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG84@.M Last changed : 4/7/2010 2:42:28 PM by KHB Analysis Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG86D.M Last changed : 4/29/2010 6:12:09 PM by ARM (modified after loading) Sample Info : Matrix Spike Duplicate

min 5 10 15 20 25 30 mAU

0 100 200 300 400 500 600 700 800 VWD1 A, Wavelength=360 nm (H:\HPLC 2010Q2\GROUCHO\DATA\APR\HPLC48PG102\023-2501.D)

A

r ea

: 12

4 8 .40.9561.2021.4331.7602.4884.1584.8405.6087.362 - Formaldehyde11.065

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 4/29/2010 6:12:10 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: VWD1 A, Wavelength=360 nm

RetTime Type Area Amt/Area Amount Grp Name [min] mAU *s [ug/mL] -------|------|----------|----------|----------|--|------------------ 7.362 MM 1248.39954 2.07188e-3 2.58654 Formaldehyde

Totals : 2.58654

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GROUCHO\DATA\APR\HPLC48PG102\023-2501.D Sample Name: MSD/Run 2 0310-129

Instrument 3 4/29/2010 6:12:33 PM ARM Page 1 of 1===================================================================== Acq. Operator : KHB Seq. Line : 15 Acq. Instrument : Groucho Location : Vial 20 Injection Date : 4/28/2010 12:05:53 AM Inj : 1 Inj Volume : 15 μl Acq. Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG84@.M Last changed : 4/7/2010 2:42:28 PM by KHB Analysis Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG86D.M Last changed : 4/29/2010 5:46:03 PM by ARM (modified after loading) Sample Info : Lab Control Sample

min 5 10 15 20 25 30 mAU

0 100 200 300 400 500 600 700 800 VWD1 A, Wavelength=360 nm (H:\HPLC 2010Q2\GROUCHO\DATA\APR\HPLC48PG102\020-1501.D)0.8321.0781.5763.5646.594 - Formaldehyde10.57611.258

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 4/29/2010 5:46:07 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: VWD1 A, Wavelength=360 nm

RetTime Type Area Amt/Area Amount Grp Name [min] mAU *s [ug/mL] -------|------|----------|----------|----------|--|------------------ 6.594 BB 1831.14307 2.07188e-3 3.79392 Formaldehyde

Totals : 3.79392

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GROUCHO\DATA\APR\HPLC48PG102\020-1501.D Sample Name: LCS 4/20/10 0310-129

Instrument 3 4/29/2010 5:47:06 PM ARM Page 1 of 1===================================================================== Acq. Operator : KHB Seq. Line : 26 Acq. Instrument : Groucho Location : Vial 24 Injection Date : 4/28/2010 9:45:08 PM Inj : 1 Inj Volume : 15 μl Acq. Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG84@.M Last changed : 4/7/2010 2:42:28 PM by KHB Analysis Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG86D.M Last changed : 4/29/2010 5:48:14 PM by ARM (modified after loading) Sample Info : Lab Control Sample

min 5 10 15 20 25 30 mAU

0 100 200 300 400 500 600 700 800 VWD1 A, Wavelength=360 nm (H:\HPLC 2010Q2\GROUCHO\DATA\APR\HPLC48PG102\024-2601.D)0.9421.1911.7622.4714.1357.351 - Formaldehyde

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 4/29/2010 5:48:15 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: VWD1 A, Wavelength=360 nm

RetTime Type Area Amt/Area Amount Grp Name [min] mAU *s [ug/mL] -------|------|----------|----------|----------|--|------------------ 7.351 BB 1121.91760 2.07188e-3 2.32448 Formaldehyde

Totals : 2.32448

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GROUCHO\DATA\APR\HPLC48PG102\024-2601.D Sample Name: LCS 4/28/10 0310-129

Instrument 3 4/29/2010 5:48:52 PM ARM Page 1 of 1

# Calibration Curve Chromatograms===================================================================== Calibration Table

=====================================================================

Calib. Data Modified : Friday, April 09, 2010 11:17:27 AM

Calculate : External Standard Based on : Peak Area

Rel. Reference Window : 5.000 % Abs. Reference Window : 0.000 min Rel. Non-ref. Window : 5.000 % Abs. Non-ref. Window : 0.000 min Use Multiplier & Dilution Factor with ISTDs Uncalibrated Peaks : not reported Partial Calibration : Yes, identified peaks are recalibrated Correct All Ret. Times: No, only for identified peaks

Curve Type : Average Response/Amount Origin : Ignored Weight : Equal

Recalibration Settings: Average Response : Average all calibrations Average Retention Time: Floating Average New 75%

Calibration Report Options : Printout of recalibrations within a sequence: Calibration Table after Recalibration Normal Report after Recalibration If the sequence is done with bracketing: Results of first cycle (ending previous bracket)

Signal 1: VWD1 A, Wavelength=360 nm

RetTime Lvl Amount Area Amt/Area Ref Grp Name [min] Sig [ug/mL] -------|--|--|----------|----------|----------|---|--|--------------- 6.039 1 1 7.47000e-2 29.58253 2.52514e-3 Formaldehyde
2 7.15000e-1 321.21284 2.22594e-3
3 2.50000 1089.59088 2.29444e-3
4 5.00000 2856.31934 1.75050e-3
5 9.01000 4565.10059 1.97367e-3
6 15.00000 8053.14917 1.86263e-3 7.982 1 1 7.47000e-2 23.19861 3.22002e-3 Acetaldehyde
2 7.15000e-1 249.11855 2.87012e-3
3 2.50000 823.64679 3.03528e-3
4 5.00000 2169.08740 2.30512e-3
5 9.01000 3454.04468 2.60854e-3
6 15.00000 6113.48096 2.45359e-3

===================================================================== Peak Sum Table

=====================================================================

***No Entries in table***

===================================================================== Method H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG86B.M

Instrument 3 4/9/2010 11:18:13 AM KHB Page 1 of 2===================================================================== Calibration Curves

=====================================================================

Amount[ug/mL] 0 10 Area

0 1000 2000 3000 4000 5000 6000 7000

1 2 3 4 5 6 Formaldehyde at exp. RT: 6.039 VWD1 A, Wavelength=360 nm Correlation: 0.99851 Residual Std. Dev.: 479.32330 Formula: y = mx
m: 482.65230

x: Amount y: Area

Amount[ug/mL] 0 10 Area

0 1000 2000 3000 4000 5000

1 2 3 4 5 6 Acetaldehyde at exp. RT: 7.982 VWD1 A, Wavelength=360 nm Correlation: 0.99842 Residual Std. Dev.: 342.60343 Formula: y = mx
m: 368.86216

x: Amount y: Area

===================================================================== Method H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG86B.M

Instrument 3 4/9/2010 11:18:13 AM KHB Page 2 of 2===================================================================== Acq. Operator : KHB Seq. Line : 2 Acq. Instrument : Groucho Location : Vial 1 Injection Date : 4/8/2010 6:09:35 PM Inj : 1 Inj Volume : 15 μl Acq. Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG84@.M Last changed : 4/7/2010 2:42:28 PM by KHB Analysis Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG86B.M Last changed : 4/9/2010 11:17:42 AM by KHB

min 5 10 15 20 25 30 mAU

0 100 200 300 400 500 600 700 800 VWD1 A, Wavelength=360 nm (H:\HPL C2010Q2\GROUCHO\DATA\APR\0310-39B\001-0201.D)0.9631.4186.038 - Formaldehyde7.975 - Acetaldehyde10.24910.69511.53113.545

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Friday, April 09, 2010 11:17:27 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: VWD1 A, Wavelength=360 nm

RetTime Type Area Amt/Area Amount Grp Name [min] mAU *s [ug/mL] -------|------|----------|----------|----------|--|------------------ 6.038 BB 29.62583 2.07188e-3 6.13813e-2 Formaldehyde 7.975 BB 23.49199 2.71104e-3 6.36877e-2 Acetaldehyde

Totals : 1.25069e-1

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GROUCHO\DATA\APR\0310-39B\001-0201.D Sample Name: hplc48pg84 #1

Instrument 3 4/9/2010 11:18:30 AM KHB Page 1 of 1===================================================================== Acq. Operator : KHB Seq. Line : 2 Acq. Instrument : Groucho Location : Vial 1 Injection Date : 4/8/2010 6:46:14 PM Inj : 2 Inj Volume : 15 μl Acq. Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG84@.M Last changed : 4/7/2010 2:42:28 PM by KHB Analysis Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG86B.M Last changed : 4/9/2010 11:17:42 AM by KHB

min 5 10 15 20 25 30 mAU

0 100 200 300 400 500 600 700 800 VWD1 A, Wavelength=360 nm (H:\HPL C2010Q2\GROUCHO\DATA\APR\0310-39B\001-0202.D)0.9751.4316.039 - Formaldehyde7.984 - Acetaldehyde10.22810.66811.51113.519

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Friday, April 09, 2010 11:17:27 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: VWD1 A, Wavelength=360 nm

RetTime Type Area Amt/Area Amount Grp Name [min] mAU *s [ug/mL] -------|------|----------|----------|----------|--|------------------ 6.039 BB 29.53923 2.07188e-3 6.12019e-2 Formaldehyde 7.984 BB 22.90523 2.71104e-3 6.20970e-2 Acetaldehyde

Totals : 1.23299e-1

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GROUCHO\DATA\APR\0310-39B\001-0202.D Sample Name: hplc48pg84 #1

Instrument 3 4/9/2010 11:18:35 AM KHB Page 1 of 1===================================================================== Acq. Operator : KHB Seq. Line : 3 Acq. Instrument : Groucho Location : Vial 2 Injection Date : 4/8/2010 7:22:57 PM Inj : 1 Inj Volume : 15 μl Acq. Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG84@.M Last changed : 4/7/2010 2:42:28 PM by KHB Analysis Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG86B.M Last changed : 4/9/2010 11:17:42 AM by KHB

min 5 10 15 20 25 30 mAU

0 100 200 300 400 500 600 700 800 VWD1 A, Wavelength=360 nm (H:\HPL C2010Q2\GROUCHO\DATA\APR\0310-39B\002-0301.D)0.9631.4135.960 - Formaldehyde7.881 - Acetaldehyde10.12210.55511.38613.97615.34716.76218.83019.62220.75021.28926.759

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Friday, April 09, 2010 11:17:27 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: VWD1 A, Wavelength=360 nm

RetTime Type Area Amt/Area Amount Grp Name [min] mAU *s [ug/mL] -------|------|----------|----------|----------|--|------------------ 5.960 BB 321.01724 2.07188e-3 6.65111e-1 Formaldehyde 7.881 BB 249.59560 2.71104e-3 6.76664e-1 Acetaldehyde

Totals : 1.34177

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GROUCHO\DATA\APR\0310-39B\002-0301.D Sample Name: hplc48pg84 #2

Instrument 3 4/9/2010 11:18:40 AM KHB Page 1 of 1===================================================================== Acq. Operator : KHB Seq. Line : 3 Acq. Instrument : Groucho Location : Vial 2 Injection Date : 4/8/2010 7:59:41 PM Inj : 2 Inj Volume : 15 μl Acq. Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG84@.M Last changed : 4/7/2010 2:42:28 PM by KHB Analysis Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG86B.M Last changed : 4/9/2010 11:17:42 AM by KHB

min 5 10 15 20 25 30 mAU

0 100 200 300 400 500 600 700 800 VWD1 A, Wavelength=360 nm (H:\HPL C2010Q2\GROUCHO\DATA\APR\0310-39B\002-0302.D)0.9651.4145.941 - Formaldehyde7.853 - Acetaldehyde10.06910.49711.32313.27815.12216.57918.61419.39820.47421.01725.809

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Friday, April 09, 2010 11:17:27 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: VWD1 A, Wavelength=360 nm

RetTime Type Area Amt/Area Amount Grp Name [min] mAU *s [ug/mL] -------|------|----------|----------|----------|--|------------------ 5.941 BB 321.40845 2.07188e-3 6.65921e-1 Formaldehyde 7.853 BB 248.64151 2.71104e-3 6.74077e-1 Acetaldehyde

Totals : 1.34000

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GROUCHO\DATA\APR\0310-39B\002-0302.D Sample Name: hplc48pg84 #2

Instrument 3 4/9/2010 11:18:45 AM KHB Page 1 of 1===================================================================== Acq. Operator : KHB Seq. Line : 4 Acq. Instrument : Groucho Location : Vial 3 Injection Date : 4/8/2010 8:36:20 PM Inj : 1 Inj Volume : 15 μl Acq. Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG84@.M Last changed : 4/7/2010 2:42:28 PM by KHB Analysis Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG86B.M Last changed : 4/9/2010 11:17:42 AM by KHB

min 5 10 15 20 25 30 mAU

0 100 200 300 400 500 600 700 800 VWD1 A, Wavelength=360 nm (H:\HPL C2010Q2\GROUCHO\DATA\APR\0310-39B\003-0401.D)0.9641.4163.0965.901 - Formaldehyde7.793 - Acetaldehyde10.00010.41911.24012.36213.17715.02516.43218.43019.19120.22820.75426.110

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Friday, April 09, 2010 11:17:27 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: VWD1 A, Wavelength=360 nm

RetTime Type Area Amt/Area Amount Grp Name [min] mAU *s [ug/mL] -------|------|----------|----------|----------|--|------------------ 5.901 BB 1088.98560 2.07188e-3 2.25625 Formaldehyde 7.793 BB 821.97125 2.71104e-3 2.22840 Acetaldehyde

Totals : 4.48465

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GROUCHO\DATA\APR\0310-39B\003-0401.D Sample Name: hplc48pg84 #3

Instrument 3 4/9/2010 11:18:50 AM KHB Page 1 of 1===================================================================== Acq. Operator : KHB Seq. Line : 4 Acq. Instrument : Groucho Location : Vial 3 Injection Date : 4/8/2010 9:13:00 PM Inj : 2 Inj Volume : 15 μl Acq. Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG84@.M Last changed : 4/7/2010 2:42:28 PM by KHB Analysis Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG86B.M Last changed : 4/9/2010 11:19:06 AM by KHB (modified after loading)

min 5 10 15 20 25 30 mAU

0 100 200 300 400 500 600 700 800 VWD1 A, Wavelength=360 nm (H:\HPL C2010Q2\GROUCHO\DATA\APR\0310-39B\003-0402.D)0.9611.4123.0655.852 - Formaldehyde7.737 - Acetaldehyde9.93210.34711.16512.26213.08314.45115.77418.28919.05220.05920.57425.489

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 4/9/2010 11:19:07 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: VWD1 A, Wavelength=360 nm

RetTime Type Area Amt/Area Amount Grp Name [min] mAU *s [ug/mL] -------|------|----------|----------|----------|--|------------------ 5.852 BB 1090.19617 2.07188e-3 2.25876 Formaldehyde 7.737 BB 825.32233 2.71104e-3 2.23748 Acetaldehyde

Totals : 4.49624

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GROUCHO\DATA\APR\0310-39B\003-0402.D Sample Name: hplc48pg84 #3

Instrument 3 4/9/2010 11:19:11 AM KHB Page 1 of 1===================================================================== Acq. Operator : KHB Seq. Line : 5 Acq. Instrument : Groucho Location : Vial 4 Injection Date : 4/8/2010 9:49:38 PM Inj : 1 Inj Volume : 15 μl Acq. Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG84@.M Last changed : 4/7/2010 2:42:28 PM by KHB Analysis Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG86B.M Last changed : 4/9/2010 11:19:06 AM by KHB (modified after loading)

min 5 10 15 20 25 30 mAU

0 100 200 300 400 500 600 700 800 VWD1 A, Wavelength=360 nm (H:\HPL C2010Q2\GROUCHO\DATA\APR\0310-39B\004-0501.D)0.9661.4201.8603.0695.857 - Formaldehyde7.735 - Acetaldehyde9.90210.31611.12612.21713.02514.87716.21118.14818.88019.86520.38125.373

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 4/9/2010 11:19:07 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: VWD1 A, Wavelength=360 nm

RetTime Type Area Amt/Area Amount Grp Name [min] mAU *s [ug/mL] -------|------|----------|----------|----------|--|------------------ 5.857 BB 2848.55664 2.07188e-3 5.90188 Formaldehyde 7.735 BB 2164.07910 2.71104e-3 5.86690 Acetaldehyde

Totals : 11.76879

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GROUCHO\DATA\APR\0310-39B\004-0501.D Sample Name: hplc48pg84 #4

Instrument 3 4/9/2010 11:19:18 AM KHB Page 1 of 1===================================================================== Acq. Operator : KHB Seq. Line : 5 Acq. Instrument : Groucho Location : Vial 4 Injection Date : 4/8/2010 10:26:16 PM Inj : 2 Inj Volume : 15 μl Acq. Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG84@.M Last changed : 4/7/2010 2:42:28 PM by KHB Analysis Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG86B.M Last changed : 4/14/2010 4:48:16 PM by KHB (modified after loading)

min 5 10 15 20 25 30 mAU

0 100 200 300 400 500 600 700 800 VWD1 A, Wavelength=360 nm (H:\HPL C2010Q2\GROUCHO\DATA\APR\0310-39B\004-0502.D)0.9661.4211.8713.0695.856 - Formaldehyde6.7077.726 - Acetaldehyde9.88810.29911.10612.19513.00014.35215.98518.13618.86819.84620.35124.830

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 4/14/2010 4:48:17 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: VWD1 A, Wavelength=360 nm

RetTime Type Area Amt/Area Amount Grp Name [min] mAU *s [ug/mL] -------|------|----------|----------|----------|--|------------------ 5.856 BB 2864.08203 2.07188e-3 5.93405 Formaldehyde 7.726 VB 2174.09570 2.71104e-3 5.89406 Acetaldehyde

Totals : 11.82811

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GROUCHO\DATA\APR\0310-39B\004-0502.D Sample Name: hplc48pg84 #4

Instrument 3 4/14/2010 4:48:23 PM KHB Page 1 of 1===================================================================== Acq. Operator : KHB Seq. Line : 6 Acq. Instrument : Groucho Location : Vial 5 Injection Date : 4/8/2010 11:02:51 PM Inj : 1 Inj Volume : 15 μl Acq. Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG84@.M Last changed : 4/7/2010 2:42:28 PM by KHB Analysis Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG86B.M Last changed : 4/9/2010 11:19:06 AM by KHB (modified after loading)

min 5 10 15 20 25 30 mAU

0 100 200 300 400 500 600 700 800 VWD1 A, Wavelength=360 nm (H:\HPL C2010Q2\GROUCHO\DATA\APR\0310-39B\005-0601.D)0.9651.4143.0755.862 - Formaldehyde7.730 - Acetaldehyde9.88110.29211.09612.18212.98314.33115.62217.53618.26519.25019.75624.239

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 4/9/2010 11:19:07 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: VWD1 A, Wavelength=360 nm

RetTime Type Area Amt/Area Amount Grp Name [min] mAU *s [ug/mL] -------|------|----------|----------|----------|--|------------------ 5.862 BB 4603.03223 2.07188e-3 9.53695 Formaldehyde 7.730 BB 3478.30127 2.71104e-3 9.42981 Acetaldehyde

Totals : 18.96677

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GROUCHO\DATA\APR\0310-39B\005-0601.D Sample Name: hplc48pg84 #5

Instrument 3 4/9/2010 11:19:51 AM KHB Page 1 of 1===================================================================== Acq. Operator : KHB Seq. Line : 6 Acq. Instrument : Groucho Location : Vial 5 Injection Date : 4/8/2010 11:39:27 PM Inj : 2 Inj Volume : 15 μl Acq. Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG84@.M Last changed : 4/7/2010 2:42:28 PM by KHB Analysis Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG86B.M Last changed : 4/9/2010 11:19:06 AM by KHB (modified after loading)

min 5 10 15 20 25 30 mAU

0 100 200 300 400 500 600 700 800 VWD1 A, Wavelength=360 nm (H:\HPL C2010Q2\GROUCHO\DATA\APR\0310-39B\005-0602.D)0.9601.4101.8613.0674.0095.834 - Formaldehyde7.694 - Acetaldehyde9.85310.26011.06512.15013.22314.82116.10318.00918.73119.70020.19924.12825.462

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 4/9/2010 11:19:07 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: VWD1 A, Wavelength=360 nm

RetTime Type Area Amt/Area Amount Grp Name [min] mAU *s [ug/mL] -------|------|----------|----------|----------|--|------------------ 5.834 BB 4527.16895 2.07188e-3 9.37977 Formaldehyde 7.694 BB 3429.78809 2.71104e-3 9.29829 Acetaldehyde

Totals : 18.67806

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GROUCHO\DATA\APR\0310-39B\005-0602.D Sample Name: hplc48pg84 #5

Instrument 3 4/9/2010 11:19:59 AM KHB Page 1 of 1===================================================================== Acq. Operator : KHB Seq. Line : 7 Acq. Instrument : Groucho Location : Vial 6 Injection Date : 4/9/2010 12:16:01 AM Inj : 1 Inj Volume : 15 μl Acq. Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG84@.M Last changed : 4/7/2010 2:42:28 PM by KHB Analysis Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG86B.M Last changed : 4/9/2010 11:19:06 AM by KHB (modified after loading)

min 5 10 15 20 25 30 mAU

0 100 200 300 400 500 600 700 800 VWD1 A, Wavelength=360 nm (H:\HPL C2010Q2\GROUCHO\DATA\APR\0310-39B\006-0701.D)0 990.9631.4161.8583.0664.0085.843 - Formaldehyde7.706 - Acetaldehyde9.85710.26611.06712.15112.94714.57616.10118.02318.74519.71720.21922.03324.642

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 4/9/2010 11:19:07 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: VWD1 A, Wavelength=360 nm

RetTime Type Area Amt/Area Amount Grp Name [min] mAU *s [ug/mL] -------|------|----------|----------|----------|--|------------------ 5.843 VB 8018.26611 2.07188e-3 16.61292 Formaldehyde 7.706 BB 6072.08301 2.71104e-3 16.46166 Acetaldehyde

Totals : 33.07458

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GROUCHO\DATA\APR\0310-39B\006-0701.D Sample Name: hplc48pg84 #6

Instrument 3 4/9/2010 11:20:13 AM KHB Page 1 of 1===================================================================== Acq. Operator : KHB Seq. Line : 7 Acq. Instrument : Groucho Location : Vial 6 Injection Date : 4/9/2010 12:52:37 AM Inj : 2 Inj Volume : 15 μl Acq. Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG84@.M Last changed : 4/7/2010 2:42:28 PM by KHB Analysis Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG86B.M Last changed : 4/9/2010 11:19:06 AM by KHB (modified after loading)

min 5 10 15 20 25 30 mAU

0 100 200 300 400 500 600 700 800 VWD1 A, Wavelength=360 nm (H:\HPL C2010Q2\GROUCHO\DATA\APR\0310-39B\006-0702.D)0.8020.9651.4151.8593.0684.0025.835 - Formaldehyde7.696 - Acetaldehyde9.84910.25911.06212.14612.94214.27815.55117.43718.15519.11919.62024.603

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 4/9/2010 11:19:07 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: VWD1 A, Wavelength=360 nm

RetTime Type Area Amt/Area Amount Grp Name [min] mAU *s [ug/mL] -------|------|----------|----------|----------|--|------------------ 5.835 BB 8088.03223 2.07188e-3 16.75747 Formaldehyde 7.696 BB 6154.87891 2.71104e-3 16.68612 Acetaldehyde

Totals : 33.44359

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GROUCHO\DATA\APR\0310-39B\006-0702.D Sample Name: hplc48pg84 #6

Instrument 3 4/9/2010 11:20:07 AM KHB Page 1 of 1===================================================================== Acq. Operator : KHB Seq. Line : 8 Acq. Instrument : Groucho Location : Vial 7 Injection Date : 4/9/2010 1:29:16 AM Inj : 1 Inj Volume : 15 μl Acq. Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG84@.M Last changed : 4/7/2010 2:42:28 PM by KHB Analysis Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG86B.M Last changed : 4/9/2010 11:19:06 AM by KHB (modified after loading)

min 5 10 15 20 25 30 mAU

0 100 200 300 400 500 600 700 800 VWD1 A, Wavelength=360 nm (H:\HPL C2010Q2\GROUCHO\DATA\APR\0310-39B\007-0801.D)0.9581.4103.0635.831 - Formaldehyde7.689 - Acetaldehyde9.83210.23611.03512.90314.24015.88717.90218.62019.56920.06124.821

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 4/9/2010 11:19:07 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: VWD1 A, Wavelength=360 nm

RetTime Type Area Amt/Area Amount Grp Name [min] mAU *s [ug/mL] -------|------|----------|----------|----------|--|------------------ 5.831 BB 1204.60681 2.07188e-3 2.49581 Formaldehyde 7.689 BB 913.80304 2.71104e-3 2.47736 Acetaldehyde

Totals : 4.97316

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GROUCHO\DATA\APR\0310-39B\007-0801.D Sample Name: hplc48pg84 #SS

Instrument 3 4/9/2010 11:22:56 AM KHB Page 1 of 1===================================================================== Acq. Operator : KHB Seq. Line : 8 Acq. Instrument : Groucho Location : Vial 7 Injection Date : 4/9/2010 2:06:03 AM Inj : 2 Inj Volume : 15 μl Acq. Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG84@.M Last changed : 4/7/2010 2:42:28 PM by KHB Analysis Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG86B.M Last changed : 4/9/2010 11:19:06 AM by KHB (modified after loading)

min 5 10 15 20 25 30 mAU

0 100 200 300 400 500 600 700 800 VWD1 A, Wavelength=360 nm (H:\HPL C2010Q2\GROUCHO\DATA\APR\0310-39B\007-0802.D)0.9631.4133.0685.838 - Formaldehyde7.695 - Acetaldehyde9.84310.24911.04412.90414.22915.48617.82318.55119.49719.98524.352

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 4/9/2010 11:19:07 AM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: VWD1 A, Wavelength=360 nm

RetTime Type Area Amt/Area Amount Grp Name [min] mAU *s [ug/mL] -------|------|----------|----------|----------|--|------------------ 5.838 BV 1192.68018 2.07188e-3 2.47110 Formaldehyde 7.695 BB 906.35413 2.71104e-3 2.45716 Acetaldehyde

Totals : 4.92826

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GROUCHO\DATA\APR\0310-39B\007-0802.D Sample Name: hplc48pg84 #SS

Instrument 3 4/9/2010 11:23:05 AM KHB Page 1 of 1===================================================================== Acq. Operator : KHB Seq. Line : 2 Acq. Instrument : Groucho Location : Vial 1 Injection Date : 4/27/2010 4:09:25 PM Inj : 1 Inj Volume : 15 μl Acq. Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG84@.M Last changed : 4/7/2010 2:42:28 PM by KHB Analysis Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG86D.M Last changed : 4/29/2010 5:43:30 PM by ARM (modified after loading)

min 5 10 15 20 25 30 mAU

0 100 200 300 400 500 600 700 800 VWD1 A, Wavelength=360 nm (H:\HPLC 2010Q2\GROUCHO\DATA\APR\HPLC48PG102\001-0201.D)1.0231.4816.808 - Formaldehyde8.75811.11712.01913.86215.15116.65719.28420.18821.29427.017

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 4/29/2010 5:43:30 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: VWD1 A, Wavelength=360 nm

RetTime Type Area Amt/Area Amount Grp Name [min] mAU *s [ug/mL] -------|------|----------|----------|----------|--|------------------ 6.808 BB 1247.07935 2.07188e-3 2.58380 Formaldehyde

Totals : 2.58380

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GROUCHO\DATA\APR\HPLC48PG102\001-0201.D Sample Name: hplc48pg84 #3

Instrument 3 4/29/2010 5:44:07 PM ARM Page 1 of 1===================================================================== Acq. Operator : KHB Seq. Line : 13 Acq. Instrument : Groucho Location : Vial 1 Injection Date : 4/27/2010 10:52:29 PM Inj : 1 Inj Volume : 15 μl Acq. Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG84@.M Last changed : 4/7/2010 2:42:28 PM by KHB Analysis Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG86D.M Last changed : 4/29/2010 5:46:03 PM by ARM (modified after loading)

min 5 10 15 20 25 30 mAU

0 100 200 300 400 500 600 700 800 VWD1 A, Wavelength=360 nm (H:\HPLC 2010Q2\GROUCHO\DATA\APR\HPLC48PG102\001-1301.D)1.0671.5713.5426.557 - Formaldehyde8.51910.76511.63113.48814.55115.79316.03918.15519.04919.96124.718

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 4/29/2010 5:46:07 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: VWD1 A, Wavelength=360 nm

RetTime Type Area Amt/Area Amount Grp Name [min] mAU *s [ug/mL] -------|------|----------|----------|----------|--|------------------ 6.557 BB 1366.24646 2.07188e-3 2.83071 Formaldehyde

Totals : 2.83071

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GROUCHO\DATA\APR\HPLC48PG102\001-1301.D Sample Name: hplc48pg84 #3

Instrument 3 4/29/2010 5:47:23 PM ARM Page 1 of 1===================================================================== Acq. Operator : KHB Seq. Line : 17 Acq. Instrument : Groucho Location : Vial 1 Injection Date : 4/28/2010 1:19:12 AM Inj : 1 Inj Volume : 15 μl Acq. Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG84@.M Last changed : 4/7/2010 2:42:28 PM by KHB Analysis Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG86D.M Last changed : 4/29/2010 5:47:31 PM by ARM (modified after loading)

min 5 10 15 20 25 30 mAU

0 100 200 300 400 500 600 700 800 VWD1 A, Wavelength=360 nm (H:\HPLC 2010Q2\GROUCHO\DATA\APR\HPLC48PG102\001-1701.D)1.1441.7003.7416.845 - Formaldehyde8.60710.83111.75513.39614.60816.12618.37719.16820.02425.181

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 4/29/2010 5:47:31 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: VWD1 A, Wavelength=360 nm

RetTime Type Area Amt/Area Amount Grp Name [min] mAU *s [ug/mL] -------|------|----------|----------|----------|--|------------------ 6.845 BV 1467.89465 2.07188e-3 3.04131 Formaldehyde

Totals : 3.04131

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GROUCHO\DATA\APR\HPLC48PG102\001-1701.D Sample Name: hplc48pg84 #3

Instrument 3 4/29/2010 5:47:34 PM ARM Page 1 of 1===================================================================== Acq. Operator : KHB Seq. Line : 18 Acq. Instrument : Groucho Location : Vial 1 Injection Date : 4/28/2010 4:41:34 PM Inj : 1 Inj Volume : 15 μl Acq. Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG84@.M Last changed : 4/7/2010 2:42:28 PM by KHB Analysis Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG86D.M Last changed : 4/29/2010 5:47:42 PM by ARM (modified after loading)

min 5 10 15 20 25 30 mAU

0 100 200 300 400 500 600 700 800 VWD1 A, Wavelength=360 nm (H:\HPLC 2010Q2\GROUCHO\DATA\APR\HPLC48PG102\001-1801.D)1.1361.6763.5086.395 - Formaldehyde8.20210.44711.31413.03514.30215.69818.24219.12120.04625.982

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 4/29/2010 5:47:43 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: VWD1 A, Wavelength=360 nm

RetTime Type Area Amt/Area Amount Grp Name [min] mAU *s [ug/mL] -------|------|----------|----------|----------|--|------------------ 6.395 BB 1477.96533 2.07188e-3 3.06217 Formaldehyde

Totals : 3.06217

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GROUCHO\DATA\APR\HPLC48PG102\001-1801.D Sample Name: hplc48pg84 #3

Instrument 3 4/29/2010 5:47:47 PM ARM Page 1 of 1===================================================================== Acq. Operator : KHB Seq. Line : 20 Acq. Instrument : Groucho Location : Vial 1 Injection Date : 4/28/2010 6:05:15 PM Inj : 1 Inj Volume : 15 μl Acq. Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG84@.M Last changed : 4/7/2010 2:42:28 PM by KHB Analysis Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG86D.M Last changed : 4/29/2010 5:47:59 PM by ARM (modified after loading)

min 5 10 15 20 25 30 mAU

0 100 200 300 400 500 600 700 800 VWD1 A, Wavelength=360 nm (H:\HPLC 2010Q2\GROUCHO\DATA\APR\HPLC48PG102\001-2001.D)1.1951.7567.657 - Formaldehyde9.47111.59812.34913.91315.15916.47519.02019.90420.86326.113

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 4/29/2010 5:47:59 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: VWD1 A, Wavelength=360 nm

RetTime Type Area Amt/Area Amount Grp Name [min] mAU *s [ug/mL] -------|------|----------|----------|----------|--|------------------ 7.657 BV 1391.95471 2.07188e-3 2.88397 Formaldehyde

Totals : 2.88397

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GROUCHO\DATA\APR\HPLC48PG102\001-2001.D Sample Name: hplc48pg84 #3

Instrument 3 4/29/2010 5:48:02 PM ARM Page 1 of 1===================================================================== Acq. Operator : KHB Seq. Line : 28 Acq. Instrument : Groucho Location : Vial 1 Injection Date : 4/28/2010 10:58:27 PM Inj : 1 Inj Volume : 15 μl Acq. Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG84@.M Last changed : 4/7/2010 2:42:28 PM by KHB Analysis Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG86D.M Last changed : 4/29/2010 5:48:14 PM by ARM (modified after loading)

min 5 10 15 20 25 30 mAU

0 100 200 300 400 500 600 700 800 VWD1 A, Wavelength=360 nm (H:\HPLC 2010Q2\GROUCHO\DATA\APR\HPLC48PG102\001-2801.D)1.0351.1981.7594.1337.291 - Formaldehyde9.05211.13211.88013.36614.54415.72318.08718.92119.67324.430

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : 4/29/2010 5:48:15 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: VWD1 A, Wavelength=360 nm

RetTime Type Area Amt/Area Amount Grp Name [min] mAU *s [ug/mL] -------|------|----------|----------|----------|--|------------------ 7.291 BV 1379.03076 2.07188e-3 2.85719 Formaldehyde

Totals : 2.85719

===================================================================== *** End of Report *** Data File H:\HPLC2010Q2\GROUCHO\DATA\APR\HPLC48PG102\001-2801.D Sample Name: hplc48pg84 #3

Instrument 3 4/29/2010 5:48:21 PM ARM Page 1 of 1Sequence Table:

Method and Injection Info Part:

Line Location SampleName Method Inj SampleType InjVolume DataFile AutoBalance LimsID

==== ======== ==================== ==================== ======== ========== =========

1 Vial 8 RB/100% ACN HPLC48PG84@ 1 Sample

2 Vial 1 hplc48pg84 #1 HPLC48PG84@ 2 Sample

3 Vial 2 hplc48pg84 #2 HPLC48PG84@ 2 Sample

4 Vial 3 hplc48pg84 #3 HPLC48PG84@ 2 Sample

5 Vial 4 hplc48pg84 #4 HPLC48PG84@ 2 Sample

6 Vial 5 hplc48pg84 #5 HPLC48PG84@ 2 Sample

7 Vial 6 hplc48pg84 #6 HPLC48PG84@ 2 Sample

8 Vial 7 hplc48pg84 #SS HPLC48PG84@ 2 Sample

9 Vial 8 RB/100% ACN HPLC48PG84@ 2 Sample

10 Vial 31 MS/G235-110-2A 0310-125 HPLC48PG84@ 1 Sample

11 Vial 32 MSD/G235-110-2A 0310-125 HPLC48PG84@ 1 Sample

12 Vial 39 LCS 4/6/10 0310-39, 125 HPLC48PG84@ 1 Sample

13 Vial 40 MB 4/6/10 0310-39, 125 HPLC48PG84@ 1 Sample

14 Vial 3 hplc48pg84 #3 HPLC48PG84@ 1 Sample

15 Vial 33 MW-6 0310-39 HPLC48PG84@ 1 Sample

16 Vial 33 MW-6 0310-39 HPLC48PG84@ 1 Sample

17 Vial 34 MW-6 Dup 0310-39 HPLC48PG84@ 1 Sample

18 Vial 4 hplc48pg84 #4 HPLC48PG84@ 2 Sample

19 Vial 35 MW-7 0310-39 HPLC48PG84@ 1 Sample

20 Vial 36 MW-8 0310-39 HPLC48PG84@ 1 Sample

21 Vial 37 MW-14 0310-39 HPLC48PG84@ 1 Sample

22 Vial 38 MW-15 0310-39 HPLC48PG84@ 1 Sample

23 Vial 3 hplc48pg84 #3 HPLC48PG84@ 1 Sample Sequence: H:\HPLC2010Q1\GROUCHO\SEQUENCE\0310-39B.S

Instrument 3 4/9/2010 12:20:06 PM KHB Page 1 of 1Sequence Table:

Method and Injection Info Part:

Line Location SampleName Method Inj SampleType InjVolume DataFile AutoBalance LimsID

==== ======== ==================== ==================== ======== ========== =========

1 Vial 2 100% ACN HPLC48PG84@ 1 Sample

2 Vial 1 hplc48pg84 #3 HPLC48PG84@ 1 Sample

3 Vial 2 RB/100% ACN HPLC48PG84@ 1 Sample

4 Vial 11 Run 1 0310-129 HPLC48PG84@ 1 Sample

5 Vial 11 Run 1 0310-129 HPLC48PG84@ 1 Sample

6 Vial 12 Run 1 Dup 0310-129 HPLC48PG84@ 1 Sample

7 Vial 13 Run 2 0310-129 HPLC48PG84@ 1 Sample

8 Vial 14 Run 3 0310-129 HPLC48PG84@ 1 Sample

9 Vial 15 Matrix Spike 0310-129 HPLC48PG84@ 1 Sample

10 Vial 16 Imp Spike 0310-129 HPLC48PG84@ 1 Sample

11 Vial 17 Field Blank 0310-129 HPLC48PG84@ 1 Sample

12 Vial 18 Reagent Blank 0310-129 HPLC48PG84@ 1 Sample

13 Vial 1 hplc48pg84 #3 HPLC48PG84@ 1 Sample

14 Vial 19 Sample Blank 0310-129 HPLC48PG84@ 1 Sample

15 Vial 20 LCS 4/20/10 0310-129 HPLC48PG84@ 1 Sample

16 Vial 21 MB 4/20/10 0310-129 HPLC48PG84@ 1 Sample

17 Vial 1 hplc48pg84 #3 HPLC48PG84@ 1 Sample

18 Vial 1 hplc48pg84 #3 HPLC48PG84@ 1 Sample

19 Vial 19 Sample Blank 0310-129 HPLC48PG84@ 1 Sample

20 Vial 1 hplc48pg84 #3 HPLC48PG84@ 1 Sample

21 Vial 19 Sample Blank 0310-129 HPLC48PG84@ 1 Sample

22 Vial 20 LCS 4/20/10 0310-129 HPLC48PG84@ 1 Sample

23 Vial 21 MB 4/20/10 0310-129 HPLC48PG84@ 1 Sample

24 Vial 22 MS/Run 2 0310-129 HPLC48PG84@ 1 Sample

25 Vial 23 MSD/Run 2 0310-129 HPLC48PG84@ 1 Sample

26 Vial 24 LCS 4/28/10 0310-129 HPLC48PG84@ 1 Sample

27 Vial 25 MB 4/28/10 0310-129 HPLC48PG84@ 1 Sample Sequence: H:\HPLC2010Q2\GROUCHO\SEQUENCE\HPLC48PG102.S

Instrument 3 4/29/2010 5:40:45 PM ARM Page 1 of 2Line Location SampleName Method Inj SampleType InjVolume DataFile AutoBalance LimsID

==== ======== ==================== ==================== ======== ========== =========

28 Vial 1 hplc48pg84 #3 HPLC48PG84@ 1 Sample Sequence: H:\HPLC2010Q2\GROUCHO\SEQUENCE\HPLC48PG102.S

Instrument 3 4/29/2010 5:40:45 PM ARM Page 2 of 2

# Sample Chromatograms===================================================================== Acq. Operator : EO/KHB Seq. Line : 9 Acq. Instrument : Smithers Location : - Injection Date : 4/26/2010 3:08:20 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG84.M Last changed : 4/27/2010 3:26:01 PM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\008-0901.D)5.877

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------
2.797 - - - Fluoride 3.735 - - - Chloride

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

===================================================================== Area Percent Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs Data File U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\008-0901.D Sample Name: R1 A *20 0310-129

Instrument 1 4/27/2010 3:29:51 PM ARM Page 1 of 2===================================================================== Acq. Operator : EO/KHB Seq. Line : 9 Acq. Instrument : Smithers Location : - Injection Date : 4/26/2010 3:19:08 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG84.M Last changed : 4/27/2010 3:26:01 PM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\008-0902.D)5.873

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------
2.797 - - - Fluoride 3.735 - - - Chloride

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

===================================================================== Area Percent Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs Data File U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\008-0902.D Sample Name: R1 A *20 0310-129

Instrument 1 4/27/2010 3:29:59 PM ARM Page 1 of 2===================================================================== Acq. Operator : EO/KHB Seq. Line : 12 Acq. Instrument : Smithers Location : - Injection Date : 4/26/2010 4:13:08 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG84.M Last changed : 4/27/2010 3:26:01 PM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\011-1201.D)5.864

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------
2.797 - - - Fluoride 3.735 - - - Chloride

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

===================================================================== Area Percent Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs Data File U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\011-1201.D Sample Name: R2 A *20 0310-129

Instrument 1 4/27/2010 3:30:46 PM ARM Page 1 of 2===================================================================== Acq. Operator : EO/KHB Seq. Line : 12 Acq. Instrument : Smithers Location : - Injection Date : 4/26/2010 4:23:56 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG84.M Last changed : 4/27/2010 3:26:01 PM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\011-1202.D)5.866

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------
2.797 - - - Fluoride 3.735 - - - Chloride

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

===================================================================== Area Percent Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs Data File U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\011-1202.D Sample Name: R2 A *20 0310-129

Instrument 1 4/27/2010 3:30:54 PM ARM Page 1 of 2===================================================================== Acq. Operator : EO/KHB Seq. Line : 13 Acq. Instrument : Smithers Location : - Injection Date : 4/26/2010 4:34:44 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG84.M Last changed : 4/27/2010 3:26:01 PM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\012-1301.D)5.868

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------
2.797 - - - Fluoride 3.735 - - - Chloride

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

===================================================================== Area Percent Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs Data File U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\012-1301.D Sample Name: R3 A *20 0310-129

Instrument 1 4/27/2010 3:31:02 PM ARM Page 1 of 2===================================================================== Acq. Operator : EO/KHB Seq. Line : 13 Acq. Instrument : Smithers Location : - Injection Date : 4/26/2010 4:45:32 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG84.M Last changed : 4/27/2010 3:26:01 PM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\012-1302.D)5.881

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------
2.797 - - - Fluoride 3.735 - - - Chloride

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

===================================================================== Area Percent Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs Data File U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\012-1302.D Sample Name: R3 A *20 0310-129

Instrument 1 4/27/2010 3:31:09 PM ARM Page 1 of 2===================================================================== Acq. Operator : EO/KHB Seq. Line : 14 Acq. Instrument : Smithers Location : - Injection Date : 4/26/2010 4:56:20 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG84.M Last changed : 4/27/2010 3:26:01 PM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\013-1401.D)

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------
2.797 - - - Fluoride 3.735 - - - Chloride

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

===================================================================== Area Percent Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs Data File U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\013-1401.D Sample Name: Acid Blank *20 0310-129

Instrument 1 4/27/2010 3:31:16 PM ARM Page 1 of 2===================================================================== Acq. Operator : EO/KHB Seq. Line : 14 Acq. Instrument : Smithers Location : - Injection Date : 4/26/2010 5:07:07 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG84.M Last changed : 4/27/2010 3:26:01 PM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\013-1402.D)

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------
2.797 - - - Fluoride 3.735 - - - Chloride

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

===================================================================== Area Percent Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs Data File U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\013-1402.D Sample Name: Acid Blank *20 0310-129

Instrument 1 4/27/2010 3:31:24 PM ARM Page 1 of 2===================================================================== Acq. Operator : EO/KHB Seq. Line : 16 Acq. Instrument : Smithers Location : - Injection Date : 4/26/2010 5:39:31 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG84.M Last changed : 4/27/2010 3:26:01 PM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\015-1601.D)2.1254.3094.9285.864

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------
2.797 - - - Fluoride 3.735 - - - Chloride

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

===================================================================== Area Percent Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs Data File U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\015-1601.D Sample Name: R1 B *20 0310-129

Instrument 1 4/27/2010 3:31:47 PM ARM Page 1 of 2===================================================================== Acq. Operator : EO/KHB Seq. Line : 16 Acq. Instrument : Smithers Location : - Injection Date : 4/26/2010 5:56:18 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG84.M Last changed : 4/27/2010 3:26:01 PM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\015-1602.D)2.1284.3134.9305.873

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------
2.797 - - - Fluoride 3.735 - - - Chloride

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

===================================================================== Area Percent Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs Data File U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\015-1602.D Sample Name: R1 B *20 0310-129

Instrument 1 4/27/2010 3:31:54 PM ARM Page 1 of 2===================================================================== Acq. Operator : EO/KHB Seq. Line : 21 Acq. Instrument : Smithers Location : - Injection Date : 4/26/2010 8:03:28 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG84.M Last changed : 4/27/2010 3:26:01 PM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\018-2101.D)2.1254.2714.8695.752

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------
2.797 - - - Fluoride 3.735 - - - Chloride

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

===================================================================== Area Percent Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs Data File U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\018-2101.D Sample Name: R2 B *20 0310-129

Instrument 1 4/27/2010 3:32:34 PM ARM Page 1 of 2===================================================================== Acq. Operator : EO/KHB Seq. Line : 21 Acq. Instrument : Smithers Location : - Injection Date : 4/26/2010 8:20:15 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG84.M Last changed : 4/27/2010 3:26:01 PM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\018-2102.D)2.1264.2644.8645.735

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------
2.797 - - - Fluoride 3.735 - - - Chloride

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

===================================================================== Area Percent Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs Data File U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\018-2102.D Sample Name: R2 B *20 0310-129

Instrument 1 4/27/2010 3:32:41 PM ARM Page 1 of 2===================================================================== Acq. Operator : EO/KHB Seq. Line : 22 Acq. Instrument : Smithers Location : - Injection Date : 4/26/2010 8:37:04 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG84.M Last changed : 4/27/2010 3:26:01 PM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\019-2201.D)2.1264.2604.8525.720

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------
2.797 - - - Fluoride 3.735 - - - Chloride

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

===================================================================== Area Percent Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs Data File U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\019-2201.D Sample Name: R3 B *20 0310-129

Instrument 1 4/27/2010 3:32:48 PM ARM Page 1 of 2===================================================================== Acq. Operator : EO/KHB Seq. Line : 22 Acq. Instrument : Smithers Location : - Injection Date : 4/26/2010 8:53:51 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG84.M Last changed : 4/27/2010 3:26:01 PM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\019-2202.D)2.1284.2564.8425.705

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------
2.797 - - - Fluoride 3.735 - - - Chloride

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

===================================================================== Area Percent Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs Data File U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\019-2202.D Sample Name: R3 B *20 0310-129

Instrument 1 4/27/2010 3:32:56 PM ARM Page 1 of 2===================================================================== Acq. Operator : EO/KHB Seq. Line : 23 Acq. Instrument : Smithers Location : - Injection Date : 4/26/2010 9:10:40 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG84.M Last changed : 4/27/2010 3:26:01 PM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\020-2301.D)2.1364.898

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------
2.797 - - - Fluoride 3.735 - - - Chloride

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

===================================================================== Area Percent Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs Data File U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\020-2301.D Sample Name: Base Blank *20 0310-129

Instrument 1 4/27/2010 3:33:03 PM ARM Page 1 of 2===================================================================== Acq. Operator : EO/KHB Seq. Line : 23 Acq. Instrument : Smithers Location : - Injection Date : 4/26/2010 9:27:26 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG84.M Last changed : 4/27/2010 3:26:01 PM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\020-2302.D)2.1384.890

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------
2.797 - - - Fluoride 3.735 - - - Chloride

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

===================================================================== Area Percent Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs Data File U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\020-2302.D Sample Name: Base Blank *20 0310-129

Instrument 1 4/27/2010 3:33:10 PM ARM Page 1 of 2===================================================================== Acq. Operator : EO/KHB Seq. Line : 15 Acq. Instrument : Smithers Location : - Injection Date : 4/26/2010 5:17:55 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG84.M Last changed : 4/27/2010 3:26:01 PM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\014-1501.D)

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------
2.797 - - - Fluoride 3.735 - - - Chloride

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

===================================================================== Area Percent Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs Data File U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\014-1501.D Sample Name: DI H2O Blank 0310-129

Instrument 1 4/27/2010 3:31:31 PM ARM Page 1 of 2===================================================================== Acq. Operator : EO/KHB Seq. Line : 15 Acq. Instrument : Smithers Location : - Injection Date : 4/26/2010 5:28:42 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG84.M Last changed : 4/27/2010 3:26:01 PM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\014-1502.D)

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------
2.797 - - - Fluoride 3.735 - - - Chloride

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

===================================================================== Area Percent Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs Data File U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\014-1502.D Sample Name: DI H2O Blank 0310-129

Instrument 1 4/27/2010 3:31:40 PM ARM Page 1 of 2===================================================================== Acq. Operator : EO/KHB Seq. Line : 8 Acq. Instrument : Smithers Location : - Injection Date : 4/26/2010 2:46:45 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG84.M Last changed : 4/27/2010 3:26:01 PM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\007-0801.D)4.877

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------
2.797 - - - Fluoride 3.735 - - - Chloride

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

===================================================================== Area Percent Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs Data File U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\007-0801.D Sample Name: 0.1N H2SO4/NaOH MB

Instrument 1 4/27/2010 3:29:28 PM ARM Page 1 of 2===================================================================== Acq. Operator : EO/KHB Seq. Line : 8 Acq. Instrument : Smithers Location : - Injection Date : 4/26/2010 2:57:32 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG84.M Last changed : 4/27/2010 3:26:01 PM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\007-0802.D)

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------
2.797 - - - Fluoride 3.735 - - - Chloride

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

===================================================================== Area Percent Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs Data File U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\007-0802.D Sample Name: 0.1N H2SO4/NaOH MB

Instrument 1 4/27/2010 3:29:43 PM ARM Page 1 of 2===================================================================== Acq. Operator : EO/KHB Seq. Line : 10 Acq. Instrument : Smithers Location : - Injection Date : 4/26/2010 3:29:56 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG84.M Last changed : 4/27/2010 3:26:01 PM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\009-1001.D)2.782 - Fluoride3.737 - Chloride5.0945.2095.844

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------
2.782 BB 211.64490 1.67562e-2 3.54637 Fluoride 3.737 BB 112.34624 2.53577e-2 2.84884 Chloride

Totals : 6.39521

===================================================================== *** End of Report *** Data File U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\009-1001.D Sample Name: MS R1 A *20 0310-129

Instrument 1 4/27/2010 3:30:07 PM ARM Page 1 of 1===================================================================== Acq. Operator : EO/KHB Seq. Line : 10 Acq. Instrument : Smithers Location : - Injection Date : 4/26/2010 3:40:44 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG84.M Last changed : 4/27/2010 3:26:01 PM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\009-1002.D)2.783 - Fluoride3.738 - Chloride5.0955.2115.844

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------
2.783 BB 211.34271 1.67563e-2 3.54132 Fluoride 3.738 BB 112.25883 2.53579e-2 2.84665 Chloride

Totals : 6.38797

===================================================================== *** End of Report *** Data File U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\009-1002.D Sample Name: MS R1 A *20 0310-129

Instrument 1 4/27/2010 3:30:14 PM ARM Page 1 of 1===================================================================== Acq. Operator : EO/KHB Seq. Line : 11 Acq. Instrument : Smithers Location : - Injection Date : 4/26/2010 3:51:32 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG84.M Last changed : 4/27/2010 3:26:01 PM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\010-1101.D)2.783 - Fluoride3.737 - Chloride5.0945.2085.842

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------
2.783 BB 210.90742 1.67564e-2 3.53405 Fluoride 3.737 BB 112.30272 2.53578e-2 2.84775 Chloride

Totals : 6.38180

===================================================================== *** End of Report *** Data File U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\010-1101.D Sample Name: MSD R1 A *20 0310-129

Instrument 1 4/27/2010 3:30:22 PM ARM Page 1 of 1===================================================================== Acq. Operator : EO/KHB Seq. Line : 11 Acq. Instrument : Smithers Location : - Injection Date : 4/26/2010 4:02:20 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG84.M Last changed : 4/27/2010 3:26:01 PM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\010-1102.D)2.783 - Fluoride3.737 - Chloride5.0915.2095.8396.010

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------
2.783 BB 211.21500 1.67563e-2 3.53919 Fluoride 3.737 BB 112.60306 2.53571e-2 2.85528 Chloride

Totals : 6.39447

===================================================================== *** End of Report *** Data File U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\010-1102.D Sample Name: MSD R1 A *20 0310-129

Instrument 1 4/27/2010 3:30:38 PM ARM Page 1 of 1===================================================================== Acq. Operator : EO/KHB Seq. Line : 19 Acq. Instrument : Smithers Location : - Injection Date : 4/26/2010 6:56:17 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG84.M Last changed : 4/27/2010 3:26:01 PM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\016-1901.D)2.1252.773 - Fluoride3.740 - Chloride4.3124.9945.2455.867

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------
2.773 BB 189.25595 1.67620e-2 3.17230 Fluoride 3.740 BB 110.83923 2.53615e-2 2.81105 Chloride

Totals : 5.98335

===================================================================== *** End of Report *** Data File U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\016-1901.D Sample Name: MS R1 B *20 0310-129

Instrument 1 4/27/2010 3:32:02 PM ARM Page 1 of 1===================================================================== Acq. Operator : EO/KHB Seq. Line : 19 Acq. Instrument : Smithers Location : - Injection Date : 4/26/2010 7:13:05 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG84.M Last changed : 4/27/2010 3:26:01 PM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\016-1902.D)2.1242.774 - Fluoride3.735 - Chloride4.3034.9765.2265.8206.015

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------
2.774 BB 189.06126 1.67620e-2 3.16905 Fluoride 3.735 BB 110.58054 2.53622e-2 2.80456 Chloride

Totals : 5.97361

===================================================================== *** End of Report *** Data File U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\016-1902.D Sample Name: MS R1 B *20 0310-129

Instrument 1 4/27/2010 3:32:10 PM ARM Page 1 of 1===================================================================== Acq. Operator : EO/KHB Seq. Line : 20 Acq. Instrument : Smithers Location : - Injection Date : 4/26/2010 7:29:53 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG84.M Last changed : 4/27/2010 3:26:01 PM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\017-2001.D)2.1272.774 - Fluoride3.728 - Chloride4.2904.9525.1995.7786.038

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------
2.774 BB 193.77460 1.67607e-2 3.24780 Fluoride 3.728 BB 113.71087 2.53544e-2 2.88307 Chloride

Totals : 6.13087

===================================================================== *** End of Report *** Data File U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\017-2001.D Sample Name: MSD R1 B *20 0310-129

Instrument 1 4/27/2010 3:32:17 PM ARM Page 1 of 1===================================================================== Acq. Operator : EO/KHB Seq. Line : 20 Acq. Instrument : Smithers Location : - Injection Date : 4/26/2010 7:46:40 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG84.M Last changed : 4/27/2010 3:26:01 PM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\017-2002.D)2.1252.773 - Fluoride3.721 - Chloride4.2784.9325.1775.7486.049

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------
2.773 BB 194.02550 1.67606e-2 3.25199 Fluoride 3.721 BB 113.83198 2.53541e-2 2.88610 Chloride

Totals : 6.13809

===================================================================== *** End of Report *** Data File U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\017-2002.D Sample Name: MSD R1 B *20 0310-129

Instrument 1 4/27/2010 3:32:26 PM ARM Page 1 of 1

# Calibration Curve Chromatograms===================================================================== Calibration Table

=====================================================================

Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM

Calculate : External Standard Based on : Peak Area

Rel. Reference Window : 10.000 % Abs. Reference Window : 0.000 min Rel. Non-ref. Window : 10.000 % Abs. Non-ref. Window : 0.000 min Use Multiplier & Dilution Factor with ISTDs Uncalibrated Peaks : not reported Partial Calibration : Yes, identified peaks are recalibrated Correct All Ret. Times: No, only for identified peaks

Curve Type : Linear Origin : Connected Weight : Linear (Amnt)

Recalibration Settings: Average Response : Average all calibrations Average Retention Time: Floating Average New 75%

Calibration Report Options : Printout of recalibrations within a sequence: Calibration Table after Recalibration Normal Report after Recalibration If the sequence is done with bracketing: Results of first cycle (ending previous bracket)

Signal 1: ADC1 B, ADC1 B, Metrohm Signal 2: ADC1 A, ADC1 CHANNEL A

RetTime Lvl Amount Area Amt/Area Ref Grp Name [min] Sig [ug/mL] -------|--|--|----------|----------|----------|---|--|---------------
2.797 2 1 1.00000e-1 4.93494 2.02637e-2 Fluoride
2 9.99000e-1 61.49712 1.62447e-2
3 4.97500 309.78529 1.60595e-2
4 8.92000 544.06776 1.63950e-2
5 14.80000 859.88914 1.72115e-2 3.735 2 1 1.00000e-1 3.11882 3.20634e-2 Chloride
2 9.99000e-1 35.07049 2.84855e-2
3 4.97500 192.95622 2.57831e-2
4 8.92000 355.89272 2.50637e-2
5 14.80000 594.72375 2.48855e-2

===================================================================== Peak Sum Table

=====================================================================

***No Entries in table***

===================================================================== Method U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG84.M

Instrument 1 4/27/2010 3:26:29 PM ARM Page 1 of 2===================================================================== Calibration Curves

=====================================================================

Amount[ug/mL] 0 10 Area

0 100 200 300 400 500 600 700 800

1 2 3 4 5 Fluoride at exp. RT: 2.797 ADC1 A, ADC1 CHANNEL A Correlation: 0.99952 Residual Std. Dev.: 17.53606 Formula: y = mx + b
m: 59.85251 b: -6.14262e-1

x: Amount y: Area Calibration Level Weights:
Level 1 : 1 Level 2 : 0.1001 Level 3 : 0.020101 Level 4 : 0.011211 Level 5 : 0.006757

Amount[ug/mL] 0 10 Area

0 100 200 300 400 500

1 2 3 4 5 Chloride at exp. RT: 3.735 ADC1 A, ADC1 CHANNEL A Correlation: 0.99977 Residual Std. Dev.: 4.69415 Formula: y = mx + b
m: 39.87393 b: -1.24835

x: Amount y: Area Calibration Level Weights:
Level 1 : 1 Level 2 : 0.1001 Level 3 : 0.020101 Level 4 : 0.011211 Level 5 : 0.006757

===================================================================== Method U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG84.M

Instrument 1 4/27/2010 3:26:29 PM ARM Page 2 of 2===================================================================== Acq. Operator : EO/KHB Seq. Line : 2 Acq. Instrument : Smithers Location : - Injection Date : 4/26/2010 12:37:11 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG84.M Last changed : 4/27/2010 3:26:01 PM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\001-0201.D)2.776 - Fluoride3.740 - Chloride

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------
2.776 BB 4.55818 1.86185e-2 8.48667e-2 Fluoride 3.740 BB 3.04486 3.53611e-2 1.07670e-1 Chloride

Totals : 1.92536e-1

===================================================================== *** End of Report *** Data File U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\001-0201.D Sample Name: HPLC51pg84 #1

Instrument 1 4/27/2010 3:26:14 PM ARM Page 1 of 1===================================================================== Acq. Operator : EO/KHB Seq. Line : 2 Acq. Instrument : Smithers Location : - Injection Date : 4/26/2010 12:47:59 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG84.M Last changed : 4/27/2010 3:26:01 PM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\001-0202.D)2.775 - Fluoride3.738 - Chloride

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------
2.775 BB 4.85643 1.86185e-2 9.04196e-2 Fluoride 3.738 BB 3.10949 3.51474e-2 1.09290e-1 Chloride

Totals : 1.99710e-1

===================================================================== *** End of Report *** Data File U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\001-0202.D Sample Name: HPLC51pg84 #1

Instrument 1 4/27/2010 3:26:43 PM ARM Page 1 of 1===================================================================== Acq. Operator : EO/KHB Seq. Line : 62 Acq. Instrument : Smithers Location : - Injection Date : 4/27/2010 11:24:48 AM Inj : 1 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG84.M Last changed : 4/27/2010 3:26:01 PM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\001-6201.D)2.774 - Fluoride3.740 - Chloride

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------
2.774 BB 5.16734 1.86185e-2 9.62084e-2 Fluoride 3.740 BB 3.17709 3.49332e-2 1.10986e-1 Chloride

Totals : 2.07194e-1

===================================================================== *** End of Report *** Data File U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\001-6201.D Sample Name: HPLC51pg84 #1

Instrument 1 4/27/2010 3:26:51 PM ARM Page 1 of 1===================================================================== Acq. Operator : EO/KHB Seq. Line : 62 Acq. Instrument : Smithers Location : - Injection Date : 4/27/2010 11:35:35 AM Inj : 2 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG84.M Last changed : 4/27/2010 3:26:01 PM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\001-6202.D)2.772 - Fluoride3.738 - Chloride

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------
2.772 BB 5.15779 1.86185e-2 9.60305e-2 Fluoride 3.738 BB 3.14384 3.50374e-2 1.10152e-1 Chloride

Totals : 2.06182e-1

===================================================================== *** End of Report *** Data File U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\001-6202.D Sample Name: HPLC51pg84 #1

Instrument 1 4/27/2010 3:26:59 PM ARM Page 1 of 1===================================================================== Acq. Operator : EO/KHB Seq. Line : 3 Acq. Instrument : Smithers Location : - Injection Date : 4/26/2010 12:58:47 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG84.M Last changed : 4/27/2010 3:26:01 PM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\002-0301.D)2.777 - Fluoride3.738 - Chloride5.0505.833

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------
2.777 BB 59.29694 1.68808e-2 1.00098 Fluoride 3.738 BB 34.74036 2.59802e-2 9.02562e-1 Chloride

Totals : 1.90354

===================================================================== *** End of Report *** Data File U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\002-0301.D Sample Name: HPLC51pg84 #2

Instrument 1 4/27/2010 3:27:07 PM ARM Page 1 of 1===================================================================== Acq. Operator : EO/KHB Seq. Line : 3 Acq. Instrument : Smithers Location : - Injection Date : 4/26/2010 1:09:34 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG84.M Last changed : 4/27/2010 3:26:01 PM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\002-0302.D)2.778 - Fluoride3.740 - Chloride5.0515.835

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------
2.778 BB 60.25044 1.68781e-2 1.01691 Fluoride 3.740 BB 34.82093 2.59781e-2 9.04583e-1 Chloride

Totals : 1.92149

===================================================================== *** End of Report *** Data File U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\002-0302.D Sample Name: HPLC51pg84 #2

Instrument 1 4/27/2010 3:27:14 PM ARM Page 1 of 1===================================================================== Acq. Operator : EO/KHB Seq. Line : 63 Acq. Instrument : Smithers Location : - Injection Date : 4/27/2010 11:46:23 AM Inj : 1 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG84.M Last changed : 4/27/2010 3:26:01 PM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\002-6301.D)2.775 - Fluoride3.738 - Chloride5.0635.8306.044

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------
2.775 BB 63.30387 1.68699e-2 1.06793 Fluoride 3.738 BB 35.35503 2.59646e-2 9.17978e-1 Chloride

Totals : 1.98591

===================================================================== *** End of Report *** Data File U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\002-6301.D Sample Name: HPLC51pg84 #2

Instrument 1 4/27/2010 3:27:22 PM ARM Page 1 of 1===================================================================== Acq. Operator : EO/KHB Seq. Line : 63 Acq. Instrument : Smithers Location : - Injection Date : 4/27/2010 11:57:11 AM Inj : 2 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG84.M Last changed : 4/27/2010 3:26:01 PM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\002-6302.D)2.775 - Fluoride3.739 - Chloride5.0655.8356.040

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------
2.775 BB 63.13723 1.68703e-2 1.06514 Fluoride 3.739 BB 35.36566 2.59643e-2 9.18244e-1 Chloride

Totals : 1.98339

===================================================================== *** End of Report *** Data File U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\002-6302.D Sample Name: HPLC51pg84 #2

Instrument 1 4/27/2010 3:27:31 PM ARM Page 1 of 1===================================================================== Acq. Operator : EO/KHB Seq. Line : 4 Acq. Instrument : Smithers Location : - Injection Date : 4/26/2010 1:20:22 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG84.M Last changed : 4/27/2010 3:26:01 PM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\003-0401.D)2.782 - Fluoride3.734 - Chloride5.0235.7996.001

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------
2.782 BB 297.33667 1.67423e-2 4.97809 Fluoride 3.734 BB 191.81564 2.52423e-2 4.84186 Chloride

Totals : 9.81995

===================================================================== *** End of Report *** Data File U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\003-0401.D Sample Name: HPLC51pg84 #3

Instrument 1 4/27/2010 3:27:38 PM ARM Page 1 of 1===================================================================== Acq. Operator : EO/KHB Seq. Line : 4 Acq. Instrument : Smithers Location : - Injection Date : 4/26/2010 1:31:10 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG84.M Last changed : 4/27/2010 3:26:01 PM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\003-0402.D)2.784 - Fluoride3.737 - Chloride5.0265.8026.006

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------
2.784 BB 302.67523 1.67416e-2 5.06728 Fluoride 3.737 BB 192.07166 2.52420e-2 4.84828 Chloride

Totals : 9.91556

===================================================================== *** End of Report *** Data File U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\003-0402.D Sample Name: HPLC51pg84 #3

Instrument 1 4/27/2010 3:27:45 PM ARM Page 1 of 1===================================================================== Acq. Operator : EO/KHB Seq. Line : 64 Acq. Instrument : Smithers Location : - Injection Date : 4/27/2010 12:07:58 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG84.M Last changed : 4/27/2010 3:26:01 PM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\003-6401.D)2.781 - Fluoride3.735 - Chloride5.0395.8036.047

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------
2.781 BB 319.44144 1.67399e-2 5.34741 Fluoride 3.735 BB 193.91412 2.52405e-2 4.89449 Chloride

Totals : 10.24190

===================================================================== *** End of Report *** Data File U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\003-6401.D Sample Name: HPLC51pg84 #3

Instrument 1 4/27/2010 3:27:53 PM ARM Page 1 of 1===================================================================== Acq. Operator : EO/KHB Seq. Line : 64 Acq. Instrument : Smithers Location : - Injection Date : 4/27/2010 12:18:46 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG84.M Last changed : 4/27/2010 3:26:01 PM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\003-6402.D)2.781 - Fluoride3.736 - Chloride5.0405.8036.049

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------
2.781 BB 319.68784 1.67398e-2 5.35152 Fluoride 3.736 BB 194.02347 2.52404e-2 4.89723 Chloride

Totals : 10.24875

===================================================================== *** End of Report *** Data File U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\003-6402.D Sample Name: HPLC51pg84 #3

Instrument 1 4/27/2010 3:28:02 PM ARM Page 1 of 1===================================================================== Acq. Operator : EO/KHB Seq. Line : 5 Acq. Instrument : Smithers Location : - Injection Date : 4/26/2010 1:41:58 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG84.M Last changed : 4/27/2010 3:26:01 PM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\004-0501.D)2.791 - Fluoride3.738 - Chloride5.0195.7916.014

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------
2.791 BB 526.93762 1.67272e-2 8.81420 Fluoride 3.738 BB 354.15213 2.51674e-2 8.91310 Chloride

Totals : 17.72730

===================================================================== *** End of Report *** Data File U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\004-0501.D Sample Name: HPLC51pg84 #4

Instrument 1 4/27/2010 3:28:10 PM ARM Page 1 of 1===================================================================== Acq. Operator : EO/KHB Seq. Line : 5 Acq. Instrument : Smithers Location : - Injection Date : 4/26/2010 1:52:46 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG84.M Last changed : 4/27/2010 3:26:01 PM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\004-0502.D)2.790 - Fluoride3.735 - Chloride5.0165.7876.010

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------
2.790 BB 532.82129 1.67270e-2 8.91250 Fluoride 3.735 BB 354.25323 2.51674e-2 8.91564 Chloride

Totals : 17.82814

===================================================================== *** End of Report *** Data File U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\004-0502.D Sample Name: HPLC51pg84 #4

Instrument 1 4/27/2010 3:28:17 PM ARM Page 1 of 1===================================================================== Acq. Operator : EO/KHB Seq. Line : 65 Acq. Instrument : Smithers Location : - Injection Date : 4/27/2010 12:29:34 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG84.M Last changed : 4/27/2010 3:26:01 PM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\004-6501.D)2.788 - Fluoride3.735 - Chloride5.0255.7916.051

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------
2.788 BB 558.03223 1.67261e-2 9.33372 Fluoride 3.735 BB 357.56897 2.51666e-2 8.99880 Chloride

Totals : 18.33251

===================================================================== *** End of Report *** Data File U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\004-6501.D Sample Name: HPLC51pg84 #4

Instrument 1 4/27/2010 3:28:26 PM ARM Page 1 of 1===================================================================== Acq. Operator : EO/KHB Seq. Line : 65 Acq. Instrument : Smithers Location : - Injection Date : 4/27/2010 12:40:22 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG84.M Last changed : 4/27/2010 3:26:01 PM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\004-6502.D)2.787 - Fluoride3.734 - Chloride5.0235.7886.051

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------
2.787 BB 558.47992 1.67261e-2 9.34120 Fluoride 3.734 BB 357.59656 2.51666e-2 8.99949 Chloride

Totals : 18.34069

===================================================================== *** End of Report *** Data File U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\004-6502.D Sample Name: HPLC51pg84 #4

Instrument 1 4/27/2010 3:28:34 PM ARM Page 1 of 1===================================================================== Acq. Operator : EO/KHB Seq. Line : 6 Acq. Instrument : Smithers Location : - Injection Date : 4/26/2010 2:03:34 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG84.M Last changed : 4/27/2010 3:26:01 PM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\005-0601.D)2.798 - Fluoride3.735 - Chloride5.0125.7796.020

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------
2.798 BB 838.87366 1.67200e-2 14.02594 Fluoride 3.735 BB 591.53021 2.51320e-2 14.86632 Chloride

Totals : 28.89226

===================================================================== *** End of Report *** Data File U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\005-0601.D Sample Name: HPLC51pg84 #5

Instrument 1 4/27/2010 3:28:42 PM ARM Page 1 of 1===================================================================== Acq. Operator : EO/KHB Seq. Line : 6 Acq. Instrument : Smithers Location : - Injection Date : 4/26/2010 2:14:22 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG84.M Last changed : 4/27/2010 3:26:01 PM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\005-0602.D)2.799 - Fluoride3.736 - Chloride5.0145.7816.022

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------
2.799 BB 845.34424 1.67199e-2 14.13405 Fluoride 3.736 BB 592.30658 2.51319e-2 14.88579 Chloride

Totals : 29.01984

===================================================================== *** End of Report *** Data File U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\005-0602.D Sample Name: HPLC51pg84 #5

Instrument 1 4/27/2010 3:28:50 PM ARM Page 1 of 1===================================================================== Acq. Operator : EO/KHB Seq. Line : 66 Acq. Instrument : Smithers Location : - Injection Date : 4/27/2010 12:51:10 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG84.M Last changed : 4/27/2010 3:26:01 PM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\005-6601.D)2.796 - Fluoride3.735 - Chloride5.0125.7816.054

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------
2.796 BB 877.50427 1.67194e-2 14.67137 Fluoride 3.735 BB 597.36316 2.51315e-2 15.01260 Chloride

Totals : 29.68398

===================================================================== *** End of Report *** Data File U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\005-6601.D Sample Name: HPLC51pg84 #5

Instrument 1 4/27/2010 3:28:58 PM ARM Page 1 of 1===================================================================== Acq. Operator : EO/KHB Seq. Line : 66 Acq. Instrument : Smithers Location : - Injection Date : 4/27/2010 1:01:57 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG84.M Last changed : 4/27/2010 3:26:01 PM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\005-6602.D)2.797 - Fluoride3.735 - Chloride5.0115.7806.055

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------
2.797 BB 877.83441 1.67194e-2 14.67689 Fluoride 3.735 BB 597.69507 2.51314e-2 15.02093 Chloride

Totals : 29.69782

===================================================================== *** End of Report *** Data File U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\005-6602.D Sample Name: HPLC51pg84 #5

Instrument 1 4/27/2010 3:29:06 PM ARM Page 1 of 1===================================================================== Acq. Operator : EO/KHB Seq. Line : 7 Acq. Instrument : Smithers Location : - Injection Date : 4/26/2010 2:25:09 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG84.M Last changed : 4/27/2010 3:26:01 PM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\006-0701.D)2.782 - Fluoride3.737 - Chloride

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------
2.782 BB 247.18105 1.67493e-2 4.14010 Fluoride 3.737 BB 148.78517 2.52895e-2 3.76270 Chloride

Totals : 7.90280

===================================================================== *** End of Report *** Data File U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\006-0701.D Sample Name: HPLC51pg84 #LCS

Instrument 1 4/27/2010 3:29:13 PM ARM Page 1 of 1===================================================================== Acq. Operator : EO/KHB Seq. Line : 7 Acq. Instrument : Smithers Location : - Injection Date : 4/26/2010 2:35:58 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG84.M Last changed : 4/27/2010 3:26:01 PM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\006-0702.D)2.783 - Fluoride3.738 - Chloride

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------
2.783 BB 247.53497 1.67492e-2 4.14601 Fluoride 3.738 BB 148.67773 2.52896e-2 3.76000 Chloride

Totals : 7.90602

===================================================================== *** End of Report *** Data File U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\006-0702.D Sample Name: HPLC51pg84 #LCS

Instrument 1 4/27/2010 3:29:21 PM ARM Page 1 of 1===================================================================== Acq. Operator : EO/KHB Seq. Line : 17 Acq. Instrument : Smithers Location : - Injection Date : 4/26/2010 6:13:06 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG84.M Last changed : 4/27/2010 3:26:01 PM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\100-1701.D)2.788 - Fluoride3.750 - Chloride5.0545.8446.040

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------
2.788 BB 316.86337 1.67401e-2 5.30433 Fluoride 3.750 BB 193.20160 2.52411e-2 4.87662 Chloride

Totals : 10.18095

===================================================================== *** End of Report *** Data File U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\100-1701.D Sample Name: HPLC51pg84 #3

Instrument 1 4/27/2010 3:41:08 PM ARM Page 1 of 1===================================================================== Acq. Operator : EO/KHB Seq. Line : 17 Acq. Instrument : Smithers Location : - Injection Date : 4/26/2010 6:23:53 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG84.M Last changed : 4/27/2010 3:26:01 PM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\100-1702.D)2.787 - Fluoride3.750 - Chloride5.0565.8496.035

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------
2.787 BB 317.41611 1.67401e-2 5.31357 Fluoride 3.750 BB 193.56297 2.52408e-2 4.88568 Chloride

Totals : 10.19925

===================================================================== *** End of Report *** Data File U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\100-1702.D Sample Name: HPLC51pg84 #3

Instrument 1 4/27/2010 3:41:16 PM ARM Page 1 of 1===================================================================== Acq. Operator : EO/KHB Seq. Line : 29 Acq. Instrument : Smithers Location : - Injection Date : 4/26/2010 11:32:12 PM Inj : 1 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG84.M Last changed : 4/27/2010 3:26:01 PM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\100-2901.D)2.788 - Fluoride3.708 - Chloride4.9205.6386.112

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------
2.788 BB 317.66592 1.67400e-2 5.31774 Fluoride 3.708 BB 194.23117 2.52402e-2 4.90244 Chloride

Totals : 10.22018

===================================================================== *** End of Report *** Data File U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\100-2901.D Sample Name: HPLC51pg84 #3

Instrument 1 4/27/2010 3:41:25 PM ARM Page 1 of 1===================================================================== Acq. Operator : EO/KHB Seq. Line : 29 Acq. Instrument : Smithers Location : - Injection Date : 4/26/2010 11:43:00 PM Inj : 2 Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Last changed : 2/23/2010 8:12:27 AM by mgb Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG84.M Last changed : 4/27/2010 3:26:01 PM by ARM

min 2 3 4 5 6 7 8 μS/cm

0 20 40 60 80 100 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\100-2902.D)2.787 - Fluoride3.707 - Chloride4.9195.6376.110

===================================================================== External Standard Report

=====================================================================

Sorted By : Signal Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM Multiplier : 1.0000 Dilution : 1.0000 Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name [min] [μS/cm*s] [ug/mL] -------|------|----------|----------|----------|--|------------------
2.787 BB 318.14532 1.67400e-2 5.32575 Fluoride 3.707 BB 194.24059 2.52402e-2 4.90268 Chloride

Totals : 10.22843

===================================================================== *** End of Report *** Data File U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\100-2902.D Sample Name: HPLC51pg84 #3

Instrument 1 4/27/2010 3:41:32 PM ARM Page 1 of 1Method Information

Method: H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Modified: 2/23/2010 at 8:12:27 AM

========================================================================= ANALOG DIGITAL CONVERTER

=========================================================================  Signal 1

--------------------- Description: ADC1 CHANNEL A Source: Signal Unit: μS/cm Units/Volt: 100.000 Peakwidth (Data Rate): 0.027 Min (10.00 Hz) Stop Time: No Limit Data Storage: All

Start Signal Source: External Device Will Start 35900

Timed Event Table:
<no events> method: H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M Modified on: 2/23/2010 at 8:12:27 AM

Smithers 3/16/2010 1:54:21 PM KHB/EO Page 1 of 1Sequence Table:

Method and Injection Info Part:

Line Location SampleName Method Inj SampleType InjVolume DataFile AutoBalance LimsID

==== ======== ==================== ==================== ======== ========== =========

1 Vial 127 DI Rinse METROHM 4 Sample

2 Vial 1 HPLC51pg84 #1 METROHM 2 Sample

3 Vial 2 HPLC51pg84 #2 METROHM 2 Sample

4 Vial 3 HPLC51pg84 #3 METROHM 2 Sample

5 Vial 4 HPLC51pg84 #4 METROHM 2 Sample

6 Vial 5 HPLC51pg84 #5 METROHM 2 Sample

7 Vial 6 HPLC51pg84 #LCS METROHM 2 Sample

8 Vial 7 0.1N H2SO4/NaOH MB METROHM 2 Sample

9 Vial 8 R1 A *20 0310-129 METROHM 2 Sample

10 Vial 9 MS R1 A *20 0310-129 METROHM 2 Sample

11 Vial 10 MSD R1 A *20 0310-129 METROHM 2 Sample

12 Vial 11 R2 A *20 0310-129 METROHM 2 Sample

13 Vial 12 R3 A *20 0310-129 METROHM 2 Sample

14 Vial 13 Acid Blank *20 0310-129 METROHM 2 Sample

15 Vial 14 DI H2O Blank 0310-129 METROHM 2 Sample

16 Vial 15 R1 B *20 0310-129 METROHM 2 Sample

17 Vial 100 HPLC51pg84 #3 METROHM 2 Sample

18 Vial 101 HPLC51pg84 #4 METROHM 2 Sample

19 Vial 16 MS R1 B *20 0310-129 METROHM 2 Sample

20 Vial 17 MSD R1 B *20 0310-129 METROHM 2 Sample

21 Vial 18 R2 B *20 0310-129 METROHM 2 Sample

22 Vial 19 R3 B *20 0310-129 METROHM 2 Sample

23 Vial 20 Base Blank *20 0310-129 METROHM 2 Sample

24 Vial 21 R1 *20 0410-50 METROHM 2 Sample

25 Vial 22 MS R1 *20 0410-50 METROHM 2 Sample

26 Vial 23 MSD R1 *20 0410-50 METROHM 2 Sample

27 Vial 24 R2 *20 0410-50 METROHM 2 Sample Sequence: U:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC51PG84.S

Instrument 1 4/27/2010 2:45:12 PM ARM Page 1 of 3Line Location SampleName Method Inj SampleType InjVolume DataFile AutoBalance LimsID

==== ======== ==================== ==================== ======== ========== =========

28 Vial 25 R3 *20 0410-50 METROHM 2 Sample

29 Vial 100 HPLC51pg84 #3 METROHM 2 Sample

30 Vial 101 HPLC51pg84 #4 METROHM 2 Sample

31 Vial 102 HPLC51pg84 #LCS METROHM 2 Sample

32 Vial 103 0.1N H2SO4/NaOH MB METROHM 2 Sample

33 Vial 26 Acid Blank *20 0410-50 METROHM 2 Sample

34 Vial 27 DI H2O Blank 0410-50 METROHM 2 Sample

35 Vial 28 R1 *20 0410-120 METROHM 2 Sample

36 Vial 29 MS R1 *20 0410-120 METROHM 2 Sample

37 Vial 30 MSD R1 *20 0410-120 METROHM 2 Sample

38 Vial 31 R2 *20 0410-120 METROHM 2 Sample

39 Vial 32 R3 *20 0410-120 METROHM 2 Sample

40 Vial 33 R4 *20 0410-120 METROHM 2 Sample

41 Vial 110 HPLC51pg84 #3 METROHM 2 Sample

42 Vial 111 HPLC51pg84 #4 METROHM 2 Sample

43 Vial 34 R5 *20 0410-120 METROHM 2 Sample

44 Vial 35 R6 *20 0410-120 METROHM 2 Sample

45 Vial 36 Acid Blank *20 0410-120 METROHM 2 Sample

46 Vial 37 DI H2O Blank 0410-120 METROHM 2 Sample

47 Vial 38 U1R1 *20 0410-22 METROHM 2 Sample

48 Vial 39 MS U1R1 *20 0410-22 METROHM 2 Sample

49 Vial 40 MSD U1R1 *20 0410-22 METROHM 2 Sample

50 Vial 41 U1R2 *20 0410-22 METROHM 2 Sample

51 Vial 42 U1R3 *20 0410-22 METROHM 2 Sample

52 Vial 43 U2R1 *20 0410-22 METROHM 2 Sample

53 Vial 110 HPLC51pg84 #3 METROHM 2 Sample

54 Vial 111 HPLC51pg84 #4 METROHM 2 Sample

55 Vial 102 HPLC51pg84 #LCS METROHM 2 Sample

56 Vial 103 0.1N H2SO4/NaOH MB METROHM 2 Sample

57 Vial 44 U2R2 *20 0410-22 METROHM 2 Sample Sequence: U:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC51PG84.S

Instrument 1 4/27/2010 2:45:12 PM ARM Page 2 of 3Line Location SampleName Method Inj SampleType InjVolume DataFile AutoBalance LimsID

==== ======== ==================== ==================== ======== ========== =========

58 Vial 45 U2R3 *20 0410-22 METROHM 2 Sample

59 Vial 46 Acid Blank *20 0410-22 METROHM 2 Sample

60 Vial 47 DI H2O Blank 0410-22 METROHM 2 Sample

61 Vial 48 FB *20 0410-22 METROHM 2 Sample

62 Vial 1 HPLC51pg84 #1 METROHM 2 Sample

63 Vial 2 HPLC51pg84 #2 METROHM 2 Sample

64 Vial 3 HPLC51pg84 #3 METROHM 2 Sample

65 Vial 4 HPLC51pg84 #4 METROHM 2 Sample

66 Vial 5 HPLC51pg84 #5 METROHM 2 Sample Sequence: U:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC51PG84.S

Instrument 1 4/27/2010 2:45:12 PM ARM Page 3 of 3

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