# EMISSIONS TEST REPORT

BIG BEND STATION FACILITY ID NUMBER: 0570039 EMISSION UNIT ID NO: -004

PARTICULATE MATTER, AMMONI A SLIP,SULFUR DIOXIDE, NITROGEN OXIDE, AND VISIBLE EMISSIONS EVALUATION April 16, 2008

Prepared For: Tampa Electric Company Big Bend Station

P.O. Box 111 Tampa, Florida 33601-0111

Prepared By: Tampa Electric Company Environmental, Health & Safety Air Services Group

Air Services Group 5010 Causeway Boulevard Tampa, Florida 33619- 6130

## REPORT CERTIFICATION

The sampling and subseque nt data entry/reduction detailed in this report was conducted at my direction, and I here by certify that this test report is authentic and accurate to the best of my knowledge.

Signature:__________________________ Jorge A. Varino Environmental Technician Test Team Lead Air Services Group Environmental Health & Safety Tampa Electric Company

I have reviewed the test performa nce, associated quality assurance activities, the resultant calculations, and the contents of this report, and certify that all project quality obj ectives have been met. Th is report is approved for submittal.

Signature:__________________________ Raymond A. McDarby, Jr. Senior Environmental Technician Quality Assurance/Quality Control Specialist Air Services Group Environmental Health & Safety Tampa Electric Company

I have reviewed the testing details and results submitted in this report, and hereby certify that this test report is authenti c and accurate to the best of my knowledge.

Signature:__________________________ David A. Smith Coordinator – Air Services Group

Environmental Health & Safety Tampa Electric Company

## TABLE OF CONTENTS

SECTION PAGE 1.0 INTRODUCTION 1

2.0 DISCUSSION OF RESULTS / EXECUTIVE SUMMARY 2

3.0 SOURCE DESCRIPTION / TEST PROCEDURES 4

4.0 TEST RESULTS

PARTICULATE MATTER TEST SUMMARY 7

AMMONIA SLIP TEST SUMMARY 8

SULFUR DIOXIDE AND NITR OGEN OXIDES 11-SEP-2007 9

VISIBLE EMISSIONS DATA FR OM OPACITY MONITOR 10

HEAT INPUT CALCULATIONS 11

5.0 FIGURES

PARTICULATE SAMPLING TRAVERSE POINTS 13

APPENDICES A PARTICULATE MATTER TEST DATA A-1 RUN CALCULATIONS A-2 LABORATORY ANALYTICAL DATA A-3 CALIBRATION DATA A-4 FIELD DATA SHEETS A-5 CHAIN OF CUSTODY

B AMMONIA SLIP TEST DATA B-1 FTIR SPECTROMETER DATA B-2 FTIR QUALITY ASSURANCE B-3 CYLINDER GAS CERTIFICATES OF ANALYSIS

C CONTINUOUS EMISSI ONS MONITORING DATA

D OPERATIONS DATA

E FUEL INFORMATION E-1 BUNKERING INFORMATION E-2 FUEL ANALYSIS

F TEST PARTICIPANTS

### 1 

## 1.0 INTRODUCTION
On April 16, 2008, Tampa Electric Com pany’s Environmental, Health, & Safety, Air Services Group, performed particulate matter (PM) and ammonia slip tests at the Big Bend Station (Facilit y ID No.: 0570039), Boiler No. 4, (E.U. ID No.: -004). Particulate Matter (PM) testing was conducted according to procedures stipulated by the Florida Department of Environmental Protection (FDEP) for fossil fuel steam generator s, and requirements in Title V Permit # 0570039-028-
AV, Compliance determination procedures and methods , §B.26 through §B.30. Ammonia Slip testing was conducted in accordance with FDEP Air Construction (AC) Permit 0570039-020-AC (as modified in permit 0570039-026-AC),

COMPLIANCE DETERMINATION , §A.19.

### 2 

## 2.0 DISCUSSION OF RESULTS
Executive Summary Tampa Electric Company Big Bend Station Dry-Bottom Tangentially Fired Utility Boiler Emission Unit ID -004

Coal/Petroleum Coke/Polk Residual Compliance Parameter Test Result FDEP Permit Limit April 16, 2008 Particulate, lb/mmBtu 0.01 0.01 Particulate, lbs/hr 32.2 43.3 Ammonia, ppmv 1 10 SO 2 

### , lb/mmBtu 0.31 0.82 1


### SO 2 

### , lbs/hr 1312 3551 1


### NO X 

### , lb/mmBtu 0.08 0.10 2


### NO X 

### , lbs/hr 315 433 2,5 

### VE, % opacity 7 20 3 

### Heat Input, mmBtu/hr 4182 4330 4 

### Unit Load (% of permit) 97% 90 – 100%

1 Based on a 30-day rolling average.

2 Based on a heat input weighted 30-day rolling average.
3 6-minute average.

4 Permitting Note: The heat input has been placed in the permit to identify the capacity of the unit for purposes of confirming that emissions testing is conducted within the 90 – 100% of the unit’s rated capacity (or to limit future operat ion to 110% of the test load), to establish appropriate emission limits and to aid in determining future rule applicability.

5 This limit is based on a heat input of 4330 mmBtu/hr.


### The average particulate matter emissions were derived by performing three, 2-

hour United States Envir onmental Protection Agency (USEPA) reference method 5B test runs. The average emission rates were calculated as 0.01 lb/mmBtu, and 32.2 lbs/hr. The FDEP Title V permitt ed emission rates are 0.01 lb/mmBtu and 43.3 lbs/hr (§ B.5.i (a) & (b)).

The average ammonia slip concentration was derived from three 1-hour USEPA

reference method 320 test runs. The av erage concentration was calculated as 1 ppmv. The FDEP AC permitted concentration is 10 ppmv (§ A.17.).

### 3 

### During the particulate matter test the Sulfur Dioxide (SO 2 

### ) emission rates were

determined to be 0.31 lb/mmBtu and 1312 lb s/hr. The FDEP Title V permitted

emission rate is 0.82 lb/mmBtu and 3551 lbs/hr, based on a 30-day rolling average (§ B.7 (a) & (b)).

During the particulate matter test the nitrogen dioxide (NO 2 

### ) emission rates (as total oxides) were determined to be 0. 08 lb/mmBtu and 315 lbs/hr. The FDEP AC permitted emission rate is 0.10 lb /mmBtu and 433 lbs/hr, based on a 30-day rolling average (§A.16).

Visible emissions were determined to be 7%, maximum 6-minute average, during

a one-hour test conducted under soot bl owing conditions. The FDEP Title V permitted emission rate is 20 percent opacity (6-minute average) except for one 6-minute period per hour of not more than 27 (twenty-seven) percent (§B.6).

During the particulate matter test per formed on April 16, 2008 Boiler No. 4 was operated at an average heat input rate of 4182 mmBtu/hr and an average load of 435 megawatts. The average quantity of fuel burned was 177.7 tons per hour.

### 4 

## 3.0 SOURCE DESCRIPTION/TEST PROCEDURES
Big Bend Station is located on Big Bend Road, Ruskin, Florida at UTM

coordinates East 361.9 No rth 3075.0. Boiler No. 4 source sampling location

consists of a circular sta ck 28.83 feet in diam eter with four sample ports located 90 degrees apart on the stack circumference. Upstream and downstream gas

flow disturbances were determined to be 8.51 and 2.99 stack di ameters from the test ports, respectively. Using these cr iteria, a total of 24 sampling points were chosen for particulate sampling for each stack, as stipulat ed in the U.S. EPA Method 1 test procedure. A diagram of the stack sampling location is included in Figure 1 along with other pertinent information on the test site.

Boiler No. 4 is serviced by an electrostatic precipitator for the control of flyash emissions, a selective catalytic reducti on (SCR) system for control of nitrogen oxides emissions, an ammonia injection system to control sulfur trioxide formation, and a flue gas desulfurization (FGD) system for control of sulfur

dioxide emissions.

On April 16, 2008, the boiler was fired with a solid fuel matrix comprised of 86% coal, 11% petroleum coke, and 4% Polk residual.

Particulate sampling was performed according to USEPA Method 5-B

"Determination of Nonsulfuric Acid Partic ulate Matter from Stationary Sources".

Particulate matter was collected on a hi gh purity, glass micro fiber filter measuring 8.26 cm in diameter.

Ammonia slip testing was performed using USEPA Method 320 “Measurement of Vapor Phase Organic and Inorganic Emissions by Extractive Fourier Transform Infrared (FTIR) Spectroscopy”. Spec tra and test performance was reviewed by RJK Consulting for appropriateness, completeness, and quality control.

### 5 

### Sulfur Dioxide and Nitrogen Ox ide data was supplied by the installed Continuous Emissions Monitoring systems (CEMs), Data Acquisition and Handling System (DAHS) as one minute averages for the duration of the particulate matter test.

Visible emissions compliance was asse ssed using the installed Continuous Opacity Monitor (COM) as recorded by the DAHS as one minute averages during the soot blowing portion of the particulate matter test.

### 6 

## 4.0 TEST RESULTS

## BIG BEND STATIO N PARTICULATE MATTER DATA SUMMAR Y

Run 1 Run 2 * 

### Run 3 T est Summar y V m(std) 

### , scf 71.214 69.969 70.733 70.639

B ws 

### , ratio 0.13008 0.13077 0.13351 0.131454

O 2 

### , % volume 9 9 10 9.33

M

d 

### , lb/lb - mole 29.99 29.99 29.84 29.941

M

s 

### , lb/lb - mole 28.43 28.42 28.26 28.372

Q s 

### , acf/min 2082370.2 2059851.3 2086088.4 2076103.26

Q s(std) 

### , dscf/min 1633686.4 1608263.3 1623989.7 1621979.79

I, % 99.5 99.4 99.5 99.47

C, lbs/dscf 4.26E-07 2.76E-07 2.90E-07 3.3040E-07

E m 

### , lbs/hr 41.7 26.6 28.2 32.2

E r 

### , lb/mmBtu 0.007 0.005 0.005 0.01

Mass emissions (E m ), lbs/hr, calculated as: C x Q s ( std ) x 60 minutes/hour Emission rate (E r ), lb/mmBtu, calculated as: C x 9780 dscf/mmBtu x (20.9/(20.9-%O 2 ))

* Run 2 was a soot blowing run 

### Unit #4 DRY-BOTTOM TANGENTIALLY FIRED BOILER April 16, 2008

7

## BIG BEND STATIO N AMMONIA SLIP DAT A

Run NH 3 

### Number Start Stop ppm 1 10:16 11:18 0.994 2 11:54 12:55 0.826 3 13:26 14:32 0.757 Average: 1 Test Times Unit #4 DRY-BOTTOM TANGENTIALLY FIRED BOILE R April 16, 2008

8

## BIG BEND STATIO N SULFUR DIOXIDE and NITROGEN OXIDES DAT A

Outlet SO 2 

### Data Average SO 2 

### Concentration, ppmvw: 114.15 Average CO 2 

### Concentration, % volume wet: 10.873
Calculated SO 2 

### Emission Rate, lb/mmBtu: 0.31
Calculated SO 2 

### Emission Rate, lbs/hr: 1312



### Unit #4 NO x 

### Data Average NO x 

### concentration, ppmvw: 38.91 Average CO 2 

### Concentration, % volume wet: 11.098
Calculated NO x 

### Emission Rate, lb/mmBtu: 0.08
Calculated NO x 

### Emission Rate, lbs/hr: 315

SO2 Emission Rate, lb(s)/mmBtu is calculated as: SO2 ppmvw x 1.660E-07 x Fc x (100 / CO2vw) NOx Emission Rate, lb/mmBtu is calculated as: NOx ppmvw x 1.194E-07 x Fc x (100 / CO2vw) Emission Rates in lbs/hr are calculated as: Emission Rate, lb/mmBtu x Heat Input, mmBtu/hr Average Concentration values were taken from 7:55 to 15:37 EST. Heat Input Calculated for this test was 4182 mmBtu/hr 

### Unit #4 DRY-BOTTOM TANGENTIALLY FIRED BOILE R April 16, 2008

9

## BIG BEND STATIO N V ISIBLE EMISSIONS DATA FROM OPACITY MONITO R

Record# DATE T IME OPACITY4 Record# DATE T IME OPACITY4 1 04/16/2008 11:01 6.41 31 04/16/2008 11:31 5.74 2 04/16/2008 11:02 6.18 32 04/16/2008 11:32 6.13 3 04/16/2008 11:03 6.34 33 04/16/2008 11:33 6.25 4 04/16/2008 11:04 6.28 34 04/16/2008 11:34 6.38 5 04/16/2008 11:05 6.10 35 04/16/2008 11:35 6.53 6 04/16/2008 11:06 6.59 36 04/16/2008 11:36 6.39 7 04/16/2008 11:07 6.26 37 04/16/2008 11:37 6.52 8 04/16/2008 11:08 6.97 38 04/16/2008 11:38 6.57 9 04/16/2008 11:09 6.49 39 04/16/2008 11:39 6.60 10 04/16/2008 11:10 6.38 40 04/16/2008 11:40 6.47 11 04/16/2008 11:11 6.24 41 04/16/2008 11:41 6.62 12 04/16/2008 11:12 5.99 42 04/16/2008 11:42 6.59 13 04/16/2008 11:13 5.81 43 04/16/2008 11:43 6.35 14 04/16/2008 11:14 5.89 44 04/16/2008 11:44 6.28 15 04/16/2008 11:15 6.12 45 04/16/2008 11:45 6.55 16 04/16/2008 11:16 6.45 46 04/16/2008 11:46 6.25 17 04/16/2008 11:17 6.87 47 04/16/2008 11:47 7.02 18 04/16/2008 11:18 6.85 48 04/16/2008 11:48 7.28 19 04/16/2008 11:19 6.78 49 04/16/2008 11:49 7.17 20 04/16/2008 11:20 6.67 50 04/16/2008 11:50 6.62 21 04/16/2008 11:21 6.78 51 04/16/2008 11:51 6.73 22 04/16/2008 11:22 6.66 52 04/16/2008 11:52 6.49 23 04/16/2008 11:23 6.28 53 04/16/2008 11:53 7.17 24 04/16/2008 11:24 6.32 54 04/16/2008 11:54 7.29 25 04/16/2008 11:25 6.42 55 04/16/2008 11:55 7.15 26 04/16/2008 11:26 6.06 56 04/16/2008 11:56 7.10 27 04/16/2008 11:27 5.51 57 04/16/2008 11:57 7.04 28 04/16/2008 11:28 5.51 58 04/16/2008 11:58 7.34 29 04/16/2008 11:29 5.54 59 04/16/2008 11:59 7.23 30 04/16/2008 11:30 5.83 60 04/16/2008 12:00 7.60

T est Avera g e: 6.501 % Minimum One Minute Avera g e: 5.510 % Maximum One Minute Avera g e: 7.600 %

Maximum Six Minute Avera g e: 7.243 % 

### Unit #4 DRY-BOTTOM TANGENTIALLY FIRED BOILE R SOOTBLOWING CONDITIONS

10

## BIG BEND STATIO N HEAT INPUT CALCULATION S

Gross Heat Rate, Previous Month ( March ) : 9613 KMBtu/MWh 9.6130E+06 mmBtu/MWh

Testing Start Time: 7:55

Testing End Time: 15:37

Total Test Time: 7.70 hours

Average Unit Load, MWe: 435 MW Heat Input, mmBtu/h = mmBtu/MWh x MW: 4182 mmBtu/hr

Laboratory Sample ID: AA90279 Btu as received: 11769 

### Btu/lb Tons of Fuel Consumed, Tons/hr = (mmBtu/h / Btu/lb) x 500: 177.7 Tons/hour 

### Unit #4

T est Time Information

Calculated Heat Input

Fuel Consumption Calculation DRY-BOTTOM TANGENTIALLY FIRED BOILE R April 16, 2008

11

### 12 

## 5.0 FIGURES

### 13 FIGURE 1 EXHAUST STACK 239 FT BIG BEND GENERATING ST A TION

PARTICULATE TRAVERSE POINTS

71 FT

SAMPLING PLATFORM

ESP OUTLET UPPER

LOWER
ESP OUTLET 499 FT

260 FT

189 FT 

# N A

B C D

PORT LOCATION PLAN

REVISED 12-30- BOILER NO. 4 TEST LOCATION

STACK DIAMETERS DOWNSTREAM FROM DISTURBANCE = 3.0

STACK DIAMETERS UPSTREAM FROM DISTURBANCE = 10.0

STACK DIAMETERR = 24.0 FT. ID. STACK AREA = 452.389 SQ FT.

PORT LENGTH’S = 17 IN. TRAVERSE POINT

1

2

3

4

5

6 % OF STACK DIAMETER IN. FROM STACK WALL

2.1%

6.7%

11.8%

17.7%

25.0%

35.6% 6.05 IN.

19.30 IN.

33.98 IN.

50.98 IN.

72.00 IN.

102.53 IN.

# APPENDIX A

PARTICULATE MATTER TEST DATA

# A-1

RUN CALCULATIONS

### Environmental, Health, & Safety Air Services Group

40 CFR 60, Appendix A - Test Methods Reference Method 5/17 Particulate Test Calculations

Customer: Tampa Electric Company Facility: Big Bend Station Sampling Location: Common Stack 3 (CS003)
Unit Under Test: Boiler Number 4 Operating Conditions: Base Loaded
Run Number: 1 Date: April 16, 2008

Sample Time, θ : 120 minutes Nozzle Diameter, D n : 0.209 inches Barometric Pressure, P b : 29.98 "Hg Nozzle Area, A n : 0.000238 ft 2
Stack Pressure, P s : 29.92 "Hg Average Orifice Meter, Δ H: 1.179 "H 2 O Effective Stack Area, A s : 652.945 ft 2 Sample Volume, V m : 73.228 ft 3
Pitot Coefficient, Cp: 0.84 dimensionless Average Meter Temp., T m : 84.5 o F Gas Analysis: 10.2 % CO 2 Average Stack Temp., T s : 125.4 o F
9.0 % O 2 Average √ Δ p: 0.892 "H 2 O
0.0 % CO Condensate Volume, V l c : 225.9 ml
80.8 % N 2 Meter Box Y: 0.998 dimensionless F-factor, F d , for fuel: 9780 dscf/MMBtu

Data Calculated from Source Measurements:
V w ( std ) = 4.714E-02 x V l c 10.649 scf
V m ( std ) = 17.647 x V m x Y x (P b + ( Δ H / 13.6)) / (T m +460) 71.214 dscf
B ws = V w ( std ) / (V m ( std ) + V w ( std ) ) 0.130 %
FDA = 1.0 - B ws 0.870 %
M d = (0.44 x %CO 2 ) + (0.32 x %O 2 ) + (0.28 x (%N 2 + % CO)) 29.99 lb./lb. mole
M s = (M d x FDA) + (18.0 x B ws ) 28.43 lb./lb. mole

v s = 85.49 x C p x ( √Δ p) x ( √ (T s + 460) / (M s x P s )) 53.15 ft/second
Q s = v s x A s x 60 2082370.2 acf/minute
Q s ( std ) = Q s x FDA x (528 / (T s + 460)) x (P s / 29.92)) 1633686.4 dscf/minute
I = (T s + 460) x ((2.67E-03 x V lc ) + (V m(std) / 17.647)) x 100 / ( θ x P s x A n x v s x 60) 99.5 %

Data from Laboratory Analysis: Total Particulate Weight From Laboratory Analysis: 0.01375 grams

Calculated Concentration and Emission Rate Data:

c s = (15.432 x grams) / V m(std) 0.003 grains/dscf grains/acf = c s x 17.647 x P s x (FDA / (T s + 460) 0.002 grains/acf
C = c s / 7000 4.257E-07 lbs/dscf
E M = C x Q s(std) x 60 41.7 lbs/hr
E R = C x F d x (20.9 /(20.9 - %O 2 ) 0.007 lbs/MMBtu

### Environmental, Health, & Safety Air Services Group

40 CFR 60, Appendix A - Test Methods Reference Method 5/17 Particulate Test Calculations

Customer: Tampa Electric Company Facility: Big Bend Station Sampling Location: Common Stack 3 (CS003)
Unit Under Test: Boiler Number 4 Operating Conditions: Base Loaded, Sootblowing
Run Number: 2 - S
Date: April 16, 2008

Sample Time, θ : 120 minutes Nozzle Diameter, D n : 0.209 inches Barometric Pressure, P b : 29.95 "Hg Nozzle Area, A n : 0.000238 ft 2
Stack Pressure, P s : 29.88 "Hg Average Orifice Meter, Δ H: 1.164 "H 2 O Effective Stack Area, A s : 652.945 ft 2 Sample Volume, V m : 73.191 ft 3
Pitot Coefficient, Cp: 0.84 dimensionless Average Meter Temp., T m : 93.3 o F Gas Analysis: 10.2 % CO 2 Average Stack Temp., T s : 127.0 o F
9.0 % O 2 Average √ Δ p: 0.881 "H 2 O
0.0 % CO Condensate Volume, V l c : 223.3 ml
80.8 % N 2 Meter Box Y: 0.998 dimensionless F-factor, F d , for fuel: 9780 dscf/MMBtu

Data Calculated from Source Measurements:
V w ( std ) = 4.714E-02 x V l c 10.526 scf
V m ( std ) = 17.647 x V m x Y x (P b + ( Δ H / 13.6)) / (T m +460) 69.969 dscf
B ws = V w ( std ) / (V m ( std ) + V w ( std ) ) 0.131 %
FDA = 1.0 - B ws 0.869 %
M d = (0.44 x %CO 2 ) + (0.32 x %O 2 ) + (0.28 x (%N 2 + % CO)) 29.99 lb./lb. mole
M s = (M d x FDA) + (18.0 x B ws ) 28.42 lb./lb. mole

v s = 85.49 x C p x ( √Δ p) x ( √ (T s + 460) / (M s x P s )) 52.58 ft/second
Q s = v s x A s x 60 2059851.3 acf/minute
Q s ( std ) = Q s x FDA x (528 / (T s + 460)) x (P s / 29.92)) 1608263.3 dscf/minute
I = (T s + 460) x ((2.67E-03 x V lc ) + (V m(std) / 17.647)) x 100 / ( θ x P s x A n x v s x 60) 99.4 %

Data from Laboratory Analysis: Total Particulate Weight From Laboratory Analysis: 0.00875 grams

Calculated Concentration and Emission Rate Data:

c s = (15.432 x grams) / V m(std) 0.002 grains/dscf grains/acf = c s x 17.647 x P s x (FDA / (T s + 460) 0.002 grains/acf
C = c s / 7000 2.757E-07 lbs/dscf
E M = C x Q s(std) x 60 26.6 lbs/hr
E R = C x F d x (20.9 /(20.9 - %O 2 ) 0.005 lbs/MMBtu

### Environmental, Health, & Safety Air Services Group

40 CFR 60, Appendix A - Test Methods Reference Method 5/17 Particulate Test Calculations

Customer: Tampa Electric Company Facility: Big Bend Station Sampling Location: Common Stack 3 (CS003)
Unit Under Test: Boiler Number 4 Operating Conditions: Base Loaded
Run Number: 3 Date: April 16, 2008

Sample Time, θ : 120 minutes Nozzle Diameter, D n : 0.209 inches Barometric Pressure, P b : 29.93 "Hg Nozzle Area, A n : 0.000238 ft 2
Stack Pressure, P s : 29.86 "Hg Average Orifice Meter, Δ H: 1.184 "H 2 O Effective Stack Area, A s : 652.945 ft 2 Sample Volume, V m : 73.812 ft 3
Pitot Coefficient, Cp: 0.84 dimensionless Average Meter Temp., T m : 91.7 o F Gas Analysis: 9.0 % CO 2 Average Stack Temp., T s : 126.6 o F
10.0 % O 2 Average √ Δ p: 0.889 "H 2 O

0.0 % CO Condensate Volume, V l c : 231.2 ml
81.0 % N 2 Meter Box Y: 0.998 dimensionless F-factor, F d , for fuel: 9780 dscf/MMBtu

Data Calculated from Source Measurements:
V w ( std ) = 4.714E-02 x V l c 10.899 scf
V m ( std ) = 17.647 x V m x Y x (P b + ( Δ H / 13.6)) / (T m +460) 70.733 dscf
B ws = V w ( std ) / (V m ( std ) + V w ( std ) ) 0.134 %
FDA = 1.0 - B ws 0.866 %
M d = (0.44 x %CO 2 ) + (0.32 x %O 2 ) + (0.28 x (%N 2 + % CO)) 29.84 lb./lb. mole
M s = (M d x FDA) + (18.0 x B ws ) 28.26 lb./lb. mole

v s = 85.49 x C p x ( √Δ p) x ( √ (T s + 460) / (M s x P s )) 53.25 ft/second
Q s = v s x A s x 60 2086088.4 acf/minute
Q s ( std ) = Q s x FDA x (528 / (T s + 460)) x (P s / 29.92)) 1623989.7 dscf/minute
I = (T s + 460) x ((2.67E-03 x V lc ) + (V m(std) / 17.647)) x 100 / ( θ x P s x A n x v s x 60) 99.5 %

Data from Laboratory Analysis: Total Particulate Weight From Laboratory Analysis: 0.00930 grams

Calculated Concentration and Emission Rate Data:

c s = (15.432 x grams) / V m(std) 0.0020 grains/dscf grains/acf = c s x 17.647 x P s x (FDA / (T s + 460) 0.0016 grains/acf
C = c s / 7000 2.899E-07 lbs/dscf
E M = C x Q s(std) x 60 28.2 lbs/hr
E R = C x F d x (20.9 /(20.9 - %O 2 ) 0.005 lbs/MMBtu

# A-2

LABORATORY ANALYTICAL DATACustomerAir ServicesPlantBig BendUnit4Method5-BStack Test Completion Date04/16/2008AnalystSSSample NumberACETONE BEAKER1st weighingDate04/23/2008Time16:40% RH51.0%2nd weighingDate04/24/2008Time16:10% RH51.0%3rd weighingDateTime% RH4th weighingDateTime% RH***Blank***Run 1Run 2Run 3Run 1SRun 2SRun 3SAcetone Container IDAIR IGAIR IHAIR IIAIR IJAcetone Rinse Vol.(Va), mls150.0000150Enter Container ID150Enter Container ID150Enter Container ID1st Gross Wt., grams107.6255107.2168111.6954106.81882nd Gross Wt., grams107.6253107.2169111.6951106.81873rd Gross Wt., grams4th Gross Wt., gramsAvg. Gross Wt., grams107.62540107.21685Enter Gross Wts.111.69525Enter Gross Wts.106.81875Enter Gross Wts.Tare Wt., grams107.62550107.20540111.68930106.81250Acetone Blank Wt.,mg-0.10-0.10-0.10-0.10Acetone Particulate Wt.,mg11.556.056.35Acetone Residue, mg/g-0.0008Acetone Blank CriteriaOK to subtract acetone blankFILTER1st weighingDate04/23/2008Time16:50% RH51.0%Date04/24/2008Time16:15% RH51.0%3rd weighingDateTime% RH4th weighingDateTime% RHFilter/Thimble ID2030812030842030822030831st Gross Wt., grams0.25080.25160.25380.25442nd Gross Wt., grams0.25090.25180.25400.25453rd Gross Wt., grams4th Gross Wt., gramsAvg. Gross Wt., grams0.250850.25170Enter Gross Wts.0.25390Enter Gross Wts.0.25445Enter Gross Wts.Tare Wt., grams0.250850.249500.250650.25205Filter Particulate Wt.,mg2.203.252.40Difference, milligrams0Total Sample Particulate Wt.,mg13.759.308.75Start Here

# A-3

CALIBRATION DATA

## Environmental, Health, & Safet y Air Services Group

SUMMARY OF E Q UIPMENT CALIBRATION S

EQUIPMENT CAL DATE METHOD RESULTS

CONSOLE (MB 06) INITIA L 02/01/2008 USEPA RM 5 0.998 POST TEST 05/06/2008 (ORIFICE) 0.993

NOZZLE (SN37) INITIA L 02/01/2008 CALIPER 0.209 POST TEST 04/17/2008 MEASUREMENTS 0.210

PYROMETER (PY 10) 02/01/2008 ASTM THERMOMETER + 2 o 

### F

PITOT TUBE (PT 08) 02/01/2008 USEPA RM 2 C p 

### = 0.84

BAROMETER (BR 07) 03/03/2008 NWS COMPARISON + 0.01" Hg

### Environmental Services Air Services Group

Red Team Manufacturer: Thermo Anderson Calibration Date: Model Number:MST-C1 Barometric Pressure: 30.14 "Hg Instrument Code Number: ^MB06 Theoretical Critical Vacuum: 14.22 "Hg LabWorks Sample Number: Calibrated By:

Initial Final Total Δ H Time Volume Volume Volume Inlet Outlet Inlet Outlet "H 2 

### O Minutes ft 3 

### ft 3 

### ft 3 

### oF oF oF oF
0.60 15 535.666 542.550 6.884 77 81 80 82 1.15 15 509.900 518.920 9.020 77 79 78 81 1.95 15 524.000 535.666 11.666 78 81 77 82 3.70 15 542.463 558.450 15.987 80 82 74 81

Orifice K' A ctual Serial Orifice Vacuum Initial Final Average Number Coefficient "Hg oF oF oF 48 0.3455 23.0 72 72 72.0 55 0.4592 21.5 72 72 72.0 63 0.5877 19.7 72 72 72.0 73 0.8022 16.9 72 72 72.0

Dry Gas Meter Calibration Calibration Volume Volume Volume Y Δ H α Corrected Corrected Nominal Value QA/QC Value QA/QC

Vm (std) , ft 3 Vcr (std) , ft 3 Vcr (std) , ft 3 

### (ratio) + 0.02 "H 2 

### O + 0.2

6.788 6.772 6.776 0.998 0.000 1.631 -0.146 8.926 9.001 9.006 1.008 0.010 1.774 -0.003 11.551 11.520 11.527 0.997 -0.001 1.834 0.057 15.905 15.724 15.734 0.989 -0.009 1.868 0.092 Averages: 0.998 1.777

Review/Approval:

For Calibration Y, the ratio of the reading of the calibration orifice to the dry gas meter, acceptable tolerance from average is + 0.02.
For Calibration Δ H α , the acceptable tolerance of individual values from the average is + 0.2.



### 4-Feb-08 Critical Orifice Readings Ambient Temperatures

CALCULATED DATA Critical Orifice The Critical Orifice Coefficient, K', should be in English units. 

### IMPORTANT Dry Gas Meter Readings Initial Temperatures Final Tempertures 02/01/2008

GDB

IMPORTANT For valid test results, the Actual Vacuum should be 1 to 2 "Hg greater than the Theoretical Critical Vacuum Shown above. 

### USEPA Reference Method 5

Dry Gas Meter Calibration

Critical Orifice Method Quarterly Calibration

### Environmental Services Air Services Group

Manufacturer: THERMO Calibration Date: Model Number:MST Barometric Pressure: 30.01 "Hg Instrument Code Number: MB06 Theoretical Critical Vacuum: 14.16 "Hg LabWorks Sample Number: Calibrated By: A ssociated Test: Team: RED

Initial Final Total Δ H Time Volume Volume Volume Inlet Outlet Inlet Outlet "H 2 

### O Minutes ft 3 

### ft 3 

### ft 3 

### oF oF oF oF

1.2 10 739.400 745.417 6.017 68 74 68 75 1.2 10 745.417 751.455 6.038 68 75 69 76 1.2 10 751.455 757.495 6.040 69 76 69 77

Orifice K' A ctual Serial Orifice Vacuum Initial Final Average Number Coefficient "Hg oF oF oF 55 0.4593 22.5 72 72 72.0 55 0.4593 22.5 72 72 72.0 55 0.4593 22.5 72 72 72.0

Dry Gas Meter Calibration Calibration Volume Volume Volume Y Δ H α Corrected Corrected Nominal Value QA/QC Value QA/QC

Vm (std) , ft 3 Vcr (std) , ft 3 Vcr (std) , ft 3 

### (ratio) + 0.02 "H 2 

### O + 0.2

6.013 5.976 6.006 0.994 0.001 1.884 0.003 6.026 5.976 6.006 0.992 -0.001 1.882 0.000 6.019 5.976 6.006 0.993 0.000 1.879 -0.003 Averages: 0.993 1.882 Prior Y: 0.998 % Difference: 0.53%

Review/Approval: Date: IMPORTANT

IMPORTANT For valid test results, the Actual Vacuum should be 1 to 2 "Hg greater than the Theoretical Critical Vacuum Shown above. The Critical Orifice Coefficient, K', should be in English units.



### Ambient Temperatures Dry Gas Meter Readings Final Tempertures Initial Temperatures

Critical Orifice Readings 

### USEPA Reference Method 5

Dry Gas Meter Calibration

Critical Orifice Method

SEG 05/06/2008 

### POST - TEST CALIBRATION CHECK

7-May-08 CALCULATED DATA

For Calibration Y, the ratio of the reading of the calibration orifice to the dry gas meter, acceptable tolerance from average is + 0.02.
For Calibration Δ H α , the acceptable tolerance of individual values from the average is + 0.2. 

### Critical Orifice

### Environmental Service s A ir Services Grou p

QUARTERLY NOZZLE CALIBRATIONS Shared Resource STEEL NOZZLE SET Calibration Date: 02/01/2008 Responsible Party: RJN

Nozzle Nozzle Diameter, D n Maximum 

### (cm) Average

I.D. D 1 

### D 2 

### D 3 Difference, " 

### D n 

### , inches

^SN01 0.292 0.286 0.293 0.003 0.114 ^SN04 0.322 0.323 0.323 0.000 0.127 ^SN05 0.379 0.380 0.378 0.001 0.149 ^SN06 0.494 0.496 0.499 0.002 0.195 ^SN09 0.686 0.689 0.686 0.001 0.270 ^SN10 0.754 0.750 0.750 0.002 0.296 ^SN12 0.985 0.979 0.982 0.002 0.387 ^SN15 0.419 0.416 0.414 0.002 0.164 ^SN16 0.501 0.501 0.499 0.001 0.197 ^SN19 0.711 0.706 0.712 0.002 0.279 ^SN22 0.934 0.935 0.932 0.001 0.368 ^SN30 0.792 0.792 0.794 0.001 0.312 ^SN36 0.467 0.474 0.473 0.003 0.186 ^SN37 0.527 0.530 0.533 0.002 0.209 ^SN38 0.628 0.632 0.633 0.002 0.248 ^SN46 0.479 0.479 0.478 0.000 0.188 ^SN47 0.514 0.511 0.508 0.002 0.201 ^SN48 0.636 0.638 0.634 0.002 0.250 ^SN50 0.788 0.784 0.784 0.002 0.309 ^SN58 0.610 0.616 0.618 0.003 0.242 ^SN68 0.622 0.625 0.625 0.001 0.246 ^SN69 0.950 0.950 0.951 0.000 0.374 ^SN70 1.561 1.558 1.553 0.003 0.613 ^SN71 1.554 1.557 1.555 0.001 0.612 ^SN72 0.953 0.954 0.950 0.002 0.375 ^SN73 1.280 1.280 1.280 0.000 0.504 ^SN74 1.230 1.231 1.230 0.000 0.484 Data Notations: All micometer readings are converted from cm to inches by multiplying by 0.393700787. Maximum Difference must be < 0.004".



### QA/QC Review by:

### Environmental, Health, & Safet y A ir Services Grou p

POST TEST NOZZLE CALIBRATION Shared Resource Calibration Date: 04/17/2008 

### Calibration Personnel: SEG 

### Test Designation: BB UNIT 4 04-16-08



### Nozzle Nozzle Diameter, D n Maximum 

### (in) Average
Identifier D 1 

### D 2 

### D 3 Difference, " 

### D n 

### , inches

SN37 0.208 0.210 0.211 0.003 0.210

Quarterly (pre-test) value for nozzle ID SN37 was 0.209

Difference (Pre-test/Post-test) is: -0.001

QA/QC Review by: Date: 18-Apr-08

### Environmental Services A ir Services Group Pyrometer Calibration Red Team Pyrometer Under Tes t Pyrometer Number: ^PY10 Labworks Sample # 0 Calibration Date: 02/01/200 8

Calibrator Information Calibrator Type/Manufacturer: Hart Scientific Calibrator Serial Number: A OA024 Date of Last Calibration: 04/17/200 7 Calibration Personnel (Typed and Si g nature): SEG-RJN

Calibration Data

Calibration Reference Pyromete r Point Temperature Indication Difference

1 

### 400 401 -1
2 

### 212 214 -2
3 

### 32 34 -2

Reference temperatures must encompass the expected range of measurement. These three point s should be ~ 32 degrees, ~212 degrees, and ~ 400 degrees Farenheit

. Difference is calculated as follows:

(reference temperature ) – (pyrometer indication )

Qaulity Control Data

Calibration Point Difference

1 

### Pass
2 

### Pass
3 

### Pass

Reviewer: 

### 4-Feb-08

### Environmental Services Air Services Group

_ _

s 

### PITOT TUBE CALIBRATION DATA SHEET

Pitot Tube ID # PT08
Calibration Date 02/01/2008 

### Operating Quarter/Year: 1/08 Shared Resource Openings Damaged?

___ Y

__ N Repaired?

___ Y ___ N ___ N/A

Labworks #: 0

Alpha and Beta Angle Determinations Acceptable Limits:

α 1 1.3 degrees 

### Pass Dt 0.48 < Dt > 0.95 cm

α 2 0.7 degrees 

### Pass α < 10 degrees β 1 1 degrees 

### Pass ( α 1 measured across top impact openings) β 2 0.8 degrees 

### Pass ( α 2 measured across bottom impact openings)
β 1 < 5 degrees (alongside top impact openings) Gamma, Theta, Α

, Ζ

, and W Determination β 2 < 5 degrees (alongside bottom impact openings)

ψ 0.6 degrees Ζ < 0.32 cm ( Α sin ψ )

Α 2.366 cm W < 0.08 cm (Asin ο )

Ζ 0.025 cm 

### Pass Α distance between tips

ο angle of plane on side of pitots

ο 0.9 degrees ψ angle between tips
W 0.037 cm 

### Pass

NOTES

All measurements are taken in accordance with the requirements of 40 CFR 60, Appendix A - Test Methods, Method 2, "Determination of stack gas velocity and volumetric flow rate (Type S pitot tube)". Measurement details are found in EPA/600/4-77/027b, "Quality Assurance Handbook for Air Pollution Measurement Systems: Stationary Source Specific Methods", sub-section 3.1.1, Procuement of Apparatus and Supplies.



### Comments: REMOVABLE

Calibrated by: RJN - SEG

Q uality Assurance Review / Approval: 8-Feb-08

### Environmental Services Air Services Group

BAROMETER CALIBRATION Blue Team Instrument Number: ^BR07 Calibration Date: 03/03/2008 Calibration Personnel: SEG Labworks #: Barometer Readin g Reference Readin g Difference T ime Inches Mercury Inches Mercury "H g 9:00 29.98 29.99 -0.01 10:00 29.99 30.00 -0.01 11:00 30.01 30.01 0

Avera g e Difference: -0.00667

Note: Barometric readin g s must a g ree within ± 0.1 "H g

. Current Reference is National Weather Service, TIA. Current Conditions at Tampa International Airport Comments (Note any ad j ustments):

QA/QC Review by: Date: 5-Mar-08

# A-4

FIELD DATA SHEETS

# A-5

CHAIN OF CUSTODY

# APPENDIX B

AMMONIA SLIP TEST DATA

# B-1

FTIR SPECTROMETER DATAFTIR Spectra Data

Spectrum Date Time CO2high NH3low WaterH SF6 Temp (C) Pressure (Atm) Native & Spik e RAW_000001.LAB 04/16/2008 18:02.2 6.42267 -0.222405 7.221828 -0.04095 149.655655 0.920825 RAW_000002.LAB 04/16/2008 20:23.6 9.924471 0.930104 13.343903 -0.033865 149.715393 0.909531 RAW_000003.LAB 04/16/2008 22:45.9 9.913221 0.834846 13.999398 -0.022392 149.762192 0.909217 RAW_000004.LAB 04/16/2008 25:07.3 9.883389 0.774887 13.556105 -0.015518 149.788177 0.908532 RAW_000005.LAB 04/16/2008 27:28.7 10.097291 0.876105 13.305135 -0.01438 149.788925 0.906142 RAW_000006.LAB 04/16/2008 29:50.1 9.926772 0.916572 13.232128 -0.012813 149.769608 0.902125 RAW_000007.LAB 04/16/2008 32:11.3 9.982235 0.986921 13.044967 -0.01255 149.736191 0.898693 RAW_000008.LAB 04/16/2008 34:32.8 9.843963 0.995862 13.073009 -0.011701 149.756393 0.894403 RAW_000009.LAB 04/16/2008 36:54.2 9.780414 1.049453 13.113932 -0.011059 149.773331 0.890257 RAW_000010.LAB 04/16/2008 39:15.6 9.622236 1.026999 13.109247 -0.01316 149.7659 0.881643 RAW_000011.LAB 04/16/2008 41:37.0 9.678854 1.026962 13.195051 -0.011867 149.783325 0.878549 RAW_000012.LAB 04/16/2008 43:58.4 9.750513 1.047014 13.236468 -0.014193 149.779694 0.870446 RAW_000013.LAB 04/16/2008 46:19.8 9.088415 1.007224 12.837161 0.067176 149.780746 0.868351 RAW_000014.LAB 04/16/2008 48:41.2 8.714352 2.291816 12.449215 0.150986 149.813263 0.858588 RAW_000015.LAB 04/16/2008 51:02.6 8.680241 2.605523 12.491087 0.146335 149.808975 0.854455 RAW_000016.LAB 04/16/2008 53:24.1 8.711643 2.859069 12.717141 0.147711 149.818634 0.849893 RAW_000017.LAB 04/16/2008 55:45.5 8.724985 3.062617 12.605613 0.152321 149.788925 0.845371 RAW_000018.LAB 04/16/2008 58:06.9 8.579633 3.191221 12.87761 0.155749 149.794861 0.840559 RAW_000019.LAB 04/16/2008 00:28.3 8.550853 3.495358 12.993779 0.15763 149.814911 0.834895 RAW_000020.LAB 04/16/2008 02:49.8 8.441948 3.666163 13.014504 0.164726 149.821609 0.834027 RAW_000021.LAB 04/16/2008 05:11.3 8.342506 3.68569 13.120272 0.165824 149.803772 0.827274 RAW_000022.LAB 04/16/2008 07:32.7 8.420682 3.771177 13.13011 0.170267 149.813431 0.827096 RAW_000023.LAB 04/16/2008 09:54.1 8.958726 2.151108 14.202064 0.015736 149.797836 0.819446 RAW_000024.LAB 04/16/2008 12:15.6 8.996492 1.355241 14.424451 -0.015188 149.806747 0.819408 RAW_000025.LAB 04/16/2008 14:37.0 9.031155 1.200271 14.417549 -0.015826 149.826065 0.817454 Run 1 RAW_000026.LAB 04/16/2008 16:58.4 9.024655 1.143034 14.279161 -0.014599 149.828293 0.817368 RAW_000027.LAB 04/16/2008 19:19.9 9.014448 1.127968 14.291634 -0.015394 149.815506 0.81589 RAW_000028.LAB 04/16/2008 21:41.3 9.007536 1.125537 14.398283 -0.014758 149.786331 0.815494 RAW_000029.LAB 04/16/2008 24:02.7 8.98331 1.033306 14.248319 -0.012583 149.808762 0.815255 RAW_000030.LAB 04/16/2008 26:24.1 9.107387 1.089381 14.357441 -0.014112 149.805267 0.812489 RAW_000031.LAB 04/16/2008 28:45.6 9.02184 1.037918 14.360231 -0.013253 149.814178 0.813932 RAW_000032.LAB 04/16/2008 31:07.0 8.984239 1.018787 14.218565 -0.014047 149.822342 0.813833 RAW_000033.LAB 04/16/2008 33:28.4 9.049927 0.987042 14.305475 -0.013379 149.824661 0.81293 RAW_000034.LAB 04/16/2008 35:49.8 9.040611 0.98198 14.30839 -0.013627 149.808975 0.811431 RAW_000035.LAB 04/16/2008 38:11.2 9.061719 0.956745 14.23245 -0.013336 149.803772 0.814229 RAW_000036.LAB 04/16/2008 40:32.6 8.966486 0.950063 14.361905 -0.012745 149.822983 0.810017 RAW_000037.LAB 04/16/2008 42:54.0 8.948038 0.937773 14.289865 -0.013547 149.794861 0.812435 RAW_000038.LAB 04/16/2008 45:15.5 8.919256 0.913931 14.382204 -0.013369 149.798584 0.810538 RAW_000039.LAB 04/16/2008 47:36.9 8.936645 0.926785 14.335858 -0.014048 149.832001 0.811335 RAW_000040.LAB 04/16/2008 49:58.1 8.902864 0.880329 14.354276 -0.014901 149.834961 0.811754 RAW_000041.LAB 04/16/2008 52:19.6 8.998301 0.880425 14.462942 -0.01525 149.839432 0.810334 RAW_000042.LAB 04/16/2008 54:41.0 9.122546 0.90283 14.374412 -0.013569 149.833511 0.810311 RAW_000043.LAB 04/16/2008 57:02.4 8.980686 0.89597 14.451427 -0.014954 149.797089 0.811406 RAW_000044.LAB 04/16/2008 59:23.8 8.959296 0.891261 14.40134 -0.014511 149.827545 0.809072 RAW_000045.LAB 04/16/2008 01:45.3 9.028937 0.902281 14.540405 -0.013676 149.832001 0.807414 RAW_000046.LAB 04/16/2008 04:06.7 9.069253 0.875391 14.529091 -0.014413 149.798584 0.811284 RAW_000047.LAB 04/16/2008 06:28.2 8.963059 0.863797 14.56187 -0.012765 149.811951 0.808429 RAW_000048.LAB 04/16/2008 08:49.6 9.005709 0.877961 14.587825 -0.014236 149.821487 0.80721 RAW_000049.LAB 04/16/2008 11:11.1 9.066612 0.854646 14.561018 -0.015749 149.825317 0.810911 RAW_000050.LAB 04/16/2008 13:32.5 8.944441 0.825561 14.585882 -0.013653 149.803772 0.808359 RAW_000051.LAB 04/16/2008 15:53.9 8.888511 0.8089 14.619593 -0.014969 149.823837 0.809271 RAW_000052.LAB 04/16/2008 18:15.3 8.934932 0.828534 14.521395 -0.01478 149.829025 0.809116 Spike RAW_000053.LAB 04/16/2008 21:32.3 8.33701 1.66069 13.303414 0.160838 149.481079 0.81559 RAW_000054.LAB 04/16/2008 23:53.7 8.327865 3.092314 13.203794 0.176956 149.527496 0.814562 RAW_000055.LAB 04/16/2008 26:15.0 8.229729 3.487999 13.119716 0.177309 149.583191 0.813718 RAW_000056.LAB 04/16/2008 28:36.2 8.414388 3.251417 13.253302 0.176743 149.656143 0.816387 RAW_000057.LAB 04/16/2008 30:57.6 8.288373 3.602317 13.010835 0.18154 149.729507 0.814945 RAW_000058.LAB 04/16/2008 33:19.1 8.321112 3.315722 13.213754 0.176227 149.748825 0.814757 RAW_000059.LAB 04/16/2008 35:40.6 8.182879 3.538252 13.173924 0.179943 149.748077 0.811293 RAW_000060.LAB 04/16/2008 38:02.0 8.162624 3.340873 13.049235 0.181544 149.779266 0.816052 RAW_000061.LAB 04/16/2008 40:23.5 8.190329 3.325573 13.370565 0.174869 149.803772 0.812569 RAW_000062.LAB 04/16/2008 42:45.0 8.124681 3.578391 13.066764 0.183485 149.84462 0.814748

Page 1 of 3FTIR Spectra Data

Spectrum Date Time CO2high NH3low WaterH SF6 Temp (C) Pressure (Atm) RAW_000063.LAB 04/16/2008 45:06.4 8.158008 3.429207 13.231134 0.177558 149.814011 0.812597 RAW_000064.LAB 04/16/2008 47:27.9 8.603742 2.444428 14.206522 0.071648 149.814178 0.808601 RAW_000065.LAB 04/16/2008 49:49.3 8.967648 1.191479 14.93893 -0.013228 149.82309 0.806323 RAW_000066.LAB 04/16/2008 52:10.8 8.939358 0.980747 15.068863 -0.013299 149.836456 0.806938 Run 2 RAW_000067.LAB 04/16/2008 54:32.3 8.941041 0.886072 15.156666 -0.012693 149.839432 0.807013 RAW_000068.LAB 04/16/2008 56:53.7 8.8687 0.862365 15.129745 -0.014507 149.853531 0.806865 RAW_000069.LAB 04/16/2008 59:15.1 8.8495 0.806092 15.130766 -0.013384 149.830521 0.80724 RAW_000070.LAB 04/16/2008 01:36.6 8.850271 0.824145 14.979201 -0.010937 149.83046 0.806615 RAW_000071.LAB 04/16/2008 03:58.0 8.789531 0.841403 15.1915 -0.012652 149.854279 0.806072 RAW_000072.LAB 04/16/2008 06:19.5 8.815805 0.822073 15.33386 -0.01285 149.838684 0.805692 RAW_000073.LAB 04/16/2008 08:41.0 8.909381 0.824685 15.419788 -0.0127 149.842392 0.803286 RAW_000074.LAB 04/16/2008 11:02.5 8.891197 0.81505 15.351435 -0.011972 149.84462 0.807756 RAW_000075.LAB 04/16/2008 13:23.9 8.896706 0.800381 15.318623 -0.0133 149.871368 0.807728 RAW_000076.LAB 04/16/2008 15:45.4 8.99583 0.794843 15.336422 -0.013471 149.868622 0.807354 RAW_000077.LAB 04/16/2008 18:06.8 8.957484 0.77765 15.402215 -0.012456 149.84314 0.80751 RAW_000078.LAB 04/16/2008 20:28.3 8.968444 0.820456 15.461992 -0.013221 149.869873 0.806975 RAW_000079.LAB 04/16/2008 22:49.8 8.991832 0.784095 15.274679 -0.013595 149.867645 0.804731 RAW_000080.LAB 04/16/2008 25:11.2 8.967879 0.73346 15.268505 -0.010845 149.84166 0.809937 RAW_000081.LAB 04/16/2008 27:32.6 8.975321 0.712502 15.237598 -0.013112 149.836456 0.807236 RAW_000082.LAB 04/16/2008 29:54.0 9.045939 0.781624 15.134692 -0.013507 149.828964 0.806412 RAW_000083.LAB 04/16/2008 32:15.5 9.130036 0.754974 15.242465 -0.013699 149.838669 0.8094 RAW_000084.LAB 04/16/2008 34:36.9 9.039807 0.75376 15.329527 -0.013706 149.832703 0.808278 RAW_000085.LAB 04/16/2008 36:58.4 9.040081 0.771433 15.345853 -0.016029 149.851303 0.807076 RAW_000086.LAB 04/16/2008 39:19.8 8.910507 0.754976 15.528635 -0.012211 149.847595 0.808256 RAW_000087.LAB 04/16/2008 41:41.2 8.969222 0.783906 16.921853 -0.01323 149.851303 0.808704 RAW_000088.LAB 04/16/2008 44:02.6 8.856577 0.775152 16.01176 -0.012651 149.832748 0.809269 RAW_000089.LAB 04/16/2008 46:24.1 8.827176 0.764346 15.731183 -0.013526 149.831955 0.807954 RAW_000090.LAB 04/16/2008 48:45.6 8.909887 0.727984 15.499696 -0.01336 149.851303 0.808948 RAW_000091.LAB 04/16/2008 51:06.9 8.81224 0.741913 15.979791 -0.01297 149.84314 0.807545 RAW_000092.LAB 04/16/2008 53:28.4 8.802985 0.773918 15.712347 -0.011921 149.834229 0.808216 RAW_000093.LAB 04/16/2008 55:49.9 8.923106 0.720353 15.602754 -0.012619 149.867645 0.807716 Spike RAW_000094.LAB 04/16/2008 58:11.3 8.632266 0.805324 15.151698 0.06123 149.843887 0.811511 RAW_000095.LAB 04/16/2008 00:32.7 8.253308 2.179832 14.20049 0.179096 149.835709 0.812923 RAW_000096.LAB 04/16/2008 02:54.1 8.357959 2.944437 14.479696 0.181322 149.833481 0.815944 RAW_000097.LAB 04/16/2008 05:15.6 8.235892 3.288169 14.624151 0.178105 149.86264 0.812283 RAW_000098.LAB 04/16/2008 07:37.1 7.77237 2.913347 18.331682 0.173644 149.852798 0.812989 RAW_000099.LAB 04/16/2008 09:58.6 7.984188 2.934803 16.446328 0.181266 149.86319 0.814314 RAW_000100.LAB 04/16/2008 12:20.0 8.227268 3.391556 14.684724 0.181888 149.878052 0.813652 RAW_000101.LAB 04/16/2008 14:41.4 8.30305 3.487098 14.74623 0.176304 149.848343 0.810238 RAW_000102.LAB 04/16/2008 17:02.9 8.117041 3.352212 15.327398 0.180033 149.823837 0.815458 RAW_000103.LAB 04/16/2008 19:24.4 8.119653 3.29695 15.433854 0.175421 149.836456 0.814021 RAW_000104.LAB 04/16/2008 21:45.8 8.823428 1.798296 16.575137 0.016719 149.846848 0.808922 RAW_000105.LAB 04/16/2008 24:07.3 8.84234 1.002267 16.550357 -0.011872 149.889938 0.810775 Run 3 RAW_000106.LAB 04/16/2008 26:28.7 8.838819 0.828006 16.194348 -0.01182 149.91127 0.807867 RAW_000107.LAB 04/16/2008 28:50.2 8.93342 0.83215 15.837617 -0.013184 149.873596 0.80922 RAW_000108.LAB 04/16/2008 31:11.6 8.928634 0.793135 16.278919 -0.013471 149.851303 0.811635 RAW_000109.LAB 04/16/2008 33:33.1 8.985911 0.742211 15.651795 -0.014511 149.837936 0.808094 RAW_000110.LAB 04/16/2008 35:54.6 9.05822 0.734248 15.60622 -0.012999 149.840942 0.809062 RAW_000111.LAB 04/16/2008 38:16.1 9.025742 0.796091 16.318522 -0.012551 149.875076 0.810573 RAW_000112.LAB 04/16/2008 40:37.5 8.998074 0.803434 15.835216 -0.012529 149.834976 0.808966 RAW_000113.LAB 04/16/2008 42:59.0 9.041813 0.788348 15.567588 -0.012749 149.84166 0.809133 RAW_000114.LAB 04/16/2008 45:20.4 9.007972 0.76202 15.72093 -0.013489 149.842392 0.808317 RAW_000115.LAB 04/16/2008 47:41.8 9.040778 0.743722 15.503444 -0.012258 149.864136 0.808781 RAW_000116.LAB 04/16/2008 50:03.5 8.990995 0.773139 15.614745 -0.013384 149.868393 0.809126 RAW_000117.LAB 04/16/2008 52:25.0 8.98869 0.705326 15.390011 -0.012082 149.848343 0.808042 RAW_000118.LAB 04/16/2008 54:46.4 9.118503 0.721988 15.160486 -0.012677 149.886215 0.808127 RAW_000119.LAB 04/16/2008 57:08.0 9.088731 0.702671 15.123646 -0.013304 149.846115 0.807484 RAW_000120.LAB 04/16/2008 59:29.4 9.098653 0.705072 15.026493 -0.012889 149.858734 0.80773 RAW_000121.LAB 04/16/2008 01:50.9 9.101123 0.722395 15.106719 -0.013526 149.855026 0.807913 RAW_000122.LAB 04/16/2008 04:12.3 9.124623 0.716504 15.038227 -0.014957 149.840942 0.806308 RAW_000123.LAB 04/16/2008 06:33.8 9.111096 0.688863 15.041131 -0.013937 149.833481 0.806795 RAW_000124.LAB 04/16/2008 08:55.3 9.071419 0.672908 15.066456 -0.013188 149.817886 0.806133

Page 2 of 3FTIR Spectra Data

Spectrum Date Time CO2high NH3low WaterH SF6 Temp (C) Pressure (Atm) RAW_000125.LAB 04/16/2008 11:16.8 8.999988 0.693047 15.166069 -0.014377 149.836456 0.807592 RAW_000126.LAB 04/16/2008 13:38.3 9.044293 0.650284 15.159632 -0.014723 149.871613 0.805438 RAW_000127.LAB 04/16/2008 15:59.8 9.093983 0.668229 15.127452 -0.014888 149.851303 0.806096 RAW_000128.LAB 04/16/2008 18:21.2 9.181802 0.656073 15.126946 -0.013936 149.872101 0.805957 RAW_000129.LAB 04/16/2008 20:42.7 9.132194 0.662361 15.0602 -0.013663 149.88176 0.80576 RAW_000130.LAB 04/16/2008 23:04.2 9.177374 0.655419 15.017955 0.003545 149.891068 0.805651 RAW_000131.LAB 04/16/2008 25:25.7 9.049343 0.657582 15.073037 -0.004251 149.864685 0.805122 RAW_000132.LAB 04/16/2008 27:47.2 8.948938 0.665231 14.872834 -0.011692 149.866165 0.804154 RAW_000133.LAB 04/16/2008 30:08.6 9.118864 0.662931 14.947148 -0.014176 149.892166 0.803314 RAW_000134.LAB 04/16/2008 32:30.1 9.028403 0.677617 14.78889 -0.011878 149.907013 0.807651 Spike RAW_000135.LAB 04/16/2008 34:51.6 8.769226 0.600103 14.61901 0.011904 149.912216 0.804559 RAW_000136.LAB 04/16/2008 37:13.1 8.240243 2.26852 13.469857 0.186948 149.902283 0.814414 RAW_000137.LAB 04/16/2008 39:34.6 8.269079 3.277285 13.377994 0.186248 149.887695 0.811445 RAW_000138.LAB 04/16/2008 41:56.1 8.196585 3.555176 13.386974 0.187014 149.875076 0.812236 RAW_000139.LAB 04/16/2008 44:17.6 8.175859 3.671331 13.437275 0.182406 149.851303 0.808399 RAW_000140.LAB 04/16/2008 46:39.1 8.286628 3.710598 13.321657 0.185351 149.933014 0.810974 RAW_000141.LAB 04/16/2008 49:00.5 8.213108 3.754919 13.393924 0.187064 149.891418 0.811832 RAW_000142.LAB 04/16/2008 51:22.0 8.229706 3.779234 13.306081 0.187285 149.866165 0.811213 RAW_000143.LAB 04/16/2008 53:43.5 8.249259 3.749969 13.342017 0.186192 149.886581 0.809003 RAW_000144.LAB 04/16/2008 56:05.0 8.369832 3.446852 13.632353 0.143079 149.869141 0.806846 RAW_000145.LAB 04/16/2008 58:26.4 8.990529 1.351731 14.76841 -0.014982 149.906265 0.804144 RAW_000146.LAB 04/16/2008 00:47.9 8.782218 0.920477 14.735093 -0.013163 149.873596 0.803417 RAW_000147.LAB 04/16/2008 03:09.4 8.952729 0.888108 14.731834 -0.014211 149.891068 0.798478 RAW_000148.LAB 04/16/2008 05:30.9 8.983061 0.76374 14.712698 -0.013635 149.862457 0.803185 RAW_000149.LAB 04/16/2008 07:52.4 9.007051 0.742365 14.797943 -0.015579 149.905533 0.80193 RAW_000150.LAB 04/16/2008 10:13.9 9.084533 0.791595 14.79716 -0.014763 149.918152 0.80265 RAW_000151.LAB 04/16/2008 12:35.3 9.026057 0.756558 14.941617 -0.013776 149.968658 0.798074 RAW_000152.LAB 04/16/2008 14:56.8 8.941693 0.751067 14.959743 -0.014466 150.022873 0.802219

Page 3 of 3

# B-2

FTIR QUALITY ASSURANCECOMPOUND SPIKING INFORMATION SHEET: BB#4 ComplianceAll conc. in PPM All Flow in LIT/MinSpike Label Spike Gas Spike Gas Total Flow Spike Gas Spike Gas SF56 Gas Exptd SF6In Conc. Flow Rate Rate FR % of Tot Flow Conc. In Conc. Sample Conc.Unit 4 Initial 50 0.5 8 6.25 4.1625 3 0.171681818Unit 4 #1 50 0.5 8 6.25 4.070116148 3 0.173417667Unit 4 #2 50 0.5 8 6.25 3.910541148 3 0.174495407Unit 4 #3/Final 50 0.5 8 6.25 3.836883296 3 0.17510963Expt SampleTCell Flush Wait min prior Native sample cal line length sample line lengthTime to Cell [mTime [min] / after spike dilution correction [meters] [meters]0.4184142 0.5625 1.07900562 0.9375 6.096 6.0960.4184142 0.5625 1.07900562 0.9375 6.096 6.0960.4184142 0.5625 1.07900562 0.9375 6.096 6.0960.4184142 0.5625 1.07900562 0.9375 6.096 6.096Note: Tank Certified Concentrations : Ammonia 50.00 PPM SF6 3.0 PPMSample lines are assumed as 3/8 OD [ 9/32" ID]Calibration lines are assumed as 1/4 OD [ 3/32" ID]Cell volume is assumed as 1.5 litersAverage Native NH3 SF6 NH3 Spike Initial SF6 Spike Initial NH3% Recovery SF6% Recovery0.93 -0.034 1.007 0.067 61.99% 39.03%0.835 -0.022 2.292 0.151 62.60% 87.95%0.775 -0.016 2.606 0.146 73.62% 85.04%0.876 -0.014 2.859 0.148 79.68% 86.21%0.917 -0.013 3.063 0.152 83.11% 88.54%0.987 -0.013 3.191 0.156 84.37% 90.87%0.996 -0.012 3.495 0.158 91.23% 92.03%1.049 -0.011 3.666 0.165 91.64% 96.11%1.027 -0.013 3.686 0.166 91.58% 96.69%1.027 -0.012 3.771 0.17 91.49% 99.02%1.047 -0.014Average of Last 391.57%1.0375 -0.015818182Average Native Run 1 NH3 Spike Run1 SF6 Run 1 NH3% Recovery SF6% RecoveryNH3 SF61.661 0.161 40.81% 92.84%0.945116148 -0.014082333 3.092 0.177 75.97% 102.07%3.488 0.177 85.70% 102.07%3.251 0.177 79.87% 102.07%3.602 0.182 88.50% 104.95%3.316 0.176 81.47% 101.49%3.538 0.18 86.93% 103.80%3.341 0.182 82.09% 104.95%3.326 0.175 81.72% 100.91%3.578 0.183 87.91% 105.53%3.429 0.178 84.25% 102.01%Average of Last 384.62%Average Native Run 2 NH3 Spike Run 2 SF6 Run 2 NH3% Recovery SF6% RecoveryNH3 SF62.18 0.179 55.75% 102.58%0.785541148 -0.013004593 2.944 0.181 75.28% 103.73%3.288 0.178 84.08% 102.01%2.913 0.174 74.49% 99.72%2.935 0.181 75.05% 103.73%3.392 0.182 86.74% 104.30%3.487 0.176 89.17% 100.86%3.352 0.18 85.72% 103.15%Average of Last 387.21%Average Native Run 3/Final NH3 Spike Run 3/Final SF6 Run 3/Final NH3% Recovery SF6% RecoveryNH3 SF60.6 0.012 15.64% 6.85%0.711883296 -0.01239037 2.269 0.187 59.14% 106.79%3.277 0.186 85.41% 106.22%3.555 0.187 92.65% 106.79%3.671 0.182 95.68% 103.93%3.711 0.185 96.72% 105.65%3.755 0.187 97.87% 106.79%3.779 0.187 98.49% 106.79%3.75 0.186 97.74% 106.22%Average of Last 398.03%

# B-3

CYLINDER GAS CERTIFICATES OF ANALYSIS

## Single- Certified 

## Calibration Sta~ldard

2 ~ba?.,76~ 77fiA F~Y 9nR

. 75A

. 7701



## CERTIFICATE OF ACCURACY: Certified Master Class Calibration 

## Standard 

## - -

Product Information Proiect ~0.07-7145 1 

### -002 

### item No.: 070200001 SOPAL P.0 No.: 

### E-NO3625

Cylinde~ Number: ALMO 1 8879 Cylinder Size AL Certification Date: 28Mar2007 Expiration Date: 27Mar2008 

### CERTIFiED CONCENTRATIONConcentration Customer

--
TAMPA ELECTRIC COMPANY CHARLES DUFENY 501 0 CAUSEWAY BLVD TAMPA, FL 33619

Accuracv Component Nc (Moles) 

### -- (+/-%)-

AMMONIA NITROGEN 

### TRACEABILITY 

### -

Traceable To

Scott Reference Standard 9.8 PPh.7 2 BALANCE

APPROVED BY:

### SPECIFICATIONS Blend Certified Requested Certified Tolerance Accuracy Concentration Concentration Result Result Component Name {Moles! (Moles) (tt- %I I+/- %)

amr1 l w. Id. I'FI 9 B P-VI 2 C 2 03 TJIF.CKEI 6.2; EAL



### TRACEABILITY

Traceable To Scorr Refdt~ncd Standard 

### PHYSICAL PROPERTIE-S_

Cylrnder Sue: AL Pressure: 2000 PSlG Expiration Date: 27Mar2008



### SPECIAL 

### HANDLING INSTRUCTIONS

Do not use or store cyl~nder at or below the stated dew point temperature. Posslble condensation of heavier components could result In the event the cyl~nder has been exposed to twnperatures aT or below the dew pornt, place cylinder In heated area for 24 hours and then roll cylinder for 15 mlnutes to re-mix.

Use of calibration standards at or below dew point temperature may result in calibration error.

Page 2 of 2--- -. 

# REFERENCE CLASS 

# ,a. Scott 

# Specialty Gases Dua 

## E- Certified 

## Calibraii'on Standard

CERTIFICATE OF ACCURACY: Reference 

## Class Calibration 

### Standard

-

Product Information Customer

-- Project No.: 01 -03623-001 Item No.: 01 020001 290QAL TAMPA ELECTRIC COMPANY P.O. NO.: E-NO3625 CHARLES DUFENY 501 0 CAUSEWAY BLVD Cyl~nder Number: ALMO575 1 7 TAMPA, FL 33679 Cylinder Size: AL Cert Ifcation Date- 03Apr2007 Exp~ration Date: 02Apr2009 

### CERTIFIED CONCENTRATION Concentration Accuracy CDmponent Name [Moles) (+ 1-94]

ETHYLENE 20.03 PPM 1 NITROGEN BALANCE 

# 1
TRACEABILITY

Description Traceability Type Traceable To



### BLEND PROCESS TRACEABILITY WEIGHT NlST ANALYTICAL TRACEABILITY GAS STANDARDS SFlS



### I 

# I

APPROVED BY: DATE:

Page 1 of 2

. . .

. . . -

. . -.

-

### TRACEABILITY

Process Traceability

Method Tr~~ability To GRAVIMETRIC BLENDING NlST

Analytical Traceability

TypelSRM No. 

### 51~atio n-De Cylinder Number Conc+ratian SRS CSTD 03AprZ007 ALM045095 50.00 PPM

Instrumentation Component
ETHYLENE



### PHYSICAL PROPERTIES

Cylinder Size: AL Date La-st. Calibrated Analytical Principle 03Apr2007 GC-FID

Pressure: 2000 PSlG Expiration Date: 02Apr2009 Analytical Method
fld



### SPECIAL HANDLING INSTRUCTIONS

Do not use or store cylinder at or below the stated dew point temperature. Possible condensation of heavier components could result. In the event the cylinder has been exposed to temperatures at or below the dew point, place cylinder in heated area for 24 hours and then roll cylinder for 15 minutes to re-mix.

Use of calibration standards at or below dew point temperature may result in calibration error.

Page 2 of 2 Blend 

### SPECIFICATIONS Blend Process Analytical Requested Gravirnetric Analyzed Tolerance Accuracy Accuracy Interlocking Concentration Concentration Concentration Result Result Result Result Component Name (Moles1 (Moles1 (Molasl (+I- 461 (+ 1- 46) I+!- %1 ( +I- %)



### - 

# -

# APPENDIX C

CONTINUOUS EMISSIONS MONITORING DATANOx and SO2 DAHS Raw Data



### Date Time NOX4 CO24 SO2_S3 CO2_S3 04/16/2008 7:55 26.5 12.14 106.8 11.27 04/16/2008 7:56 25.7 12.14 101.9 11.23 04/16/2008 7:57 25.1 12.2 106.8 11.26 04/16/2008 7:58 24.6 12.2 108.2 11.24 04/16/2008 7:59 23.5 12.2 106.5 11.14 04/16/2008 8:00 23.8 12.08 109.6 11.15 04/16/2008 8:01 24.7 12.01 112.5 11.26 04/16/2008 8:02 25.7 12.14 113.9 11.28 04/16/2008 8:03 25.8 12.24 113.1 11.33 04/16/2008 8:04 25.7 12.31 106.9 11.23 04/16/2008 8:05 24.7 12.21 112.7 11.1 04/16/2008 8:06 24.8 12.07 116.3 11.25 04/16/2008 8:07 25.7 12.12 114.6 11.23 04/16/2008 8:08 26.4 12.2 112.1 11.13 04/16/2008 8:09 26.4 12.11 111.2 11.09 04/16/2008 8:10 27 12.03 105.3 11.06 04/16/2008 8:11 27.6 12 94.1 11.13 04/16/2008 8:12 28.3 11.97 85 11.11 04/16/2008 8:13 28.1 12.01 88.7 11.17 04/16/2008 8:14 27.5 12.09 90.4 11.09 04/16/2008 8:15 27.8 12.09 94.2 11.1 04/16/2008 8:16 27.9 12.06 100.5 11.16 04/16/2008 8:17 27.6 12.08 104.2 11.1 04/16/2008 8:18 27.3 12.07 103.1 11.28 04/16/2008 8:19 48.2 11.55 94.8 11.3 04/16/2008 8:20 43.2 7.21 94.9 11.25 04/16/2008 8:21 13.5 1.52 98.9 11.18 04/16/2008 8:22 9.8 0.2 102.2 11.14 04/16/2008 8:23 7.3 0.05 105.2 11.13 04/16/2008 8:24 6.1 0.14 101.4 11.22 04/16/2008 8:25 5.1 0.16 99.5 11.26 04/16/2008 8:26 4.2 0 97.3 11.15 04/16/2008 8:27 3.8 0.02 102 11.17 04/16/2008 8:28 46.2 5.05 108.1 11.18 04/16/2008 8:29 64.8 10.22 109.1 11.18 04/16/2008 8:30 64.5 11.04 106.5 11.08 04/16/2008 8:31 65.7 11.09 105.6 11.09 04/16/2008 8:32 65.5 11.16 109.6 11.19 04/16/2008 8:33 65.7 11.21 94.2 11.26 04/16/2008 8:34 65.8 11.22 85.2 11.21 04/16/2008 8:35 160.6 11.23 89.9 11.27 04/16/2008 8:36 335.3 11.06 94.3 11.18 04/16/2008 8:37 334.6 11.1 92.6 11.09

Page 1 of 11NOx and SO2 DAHS Raw Data



### Date Time NOX4 CO24 SO2_S3 CO2_S3 04/16/2008 8:38 334.9 11.33 92.5 11.05 04/16/2008 8:39 331.2 11.36 91.1 11.15 04/16/2008 8:40 332.1 11.38 91 11.09 04/16/2008 8:41 331.7 11.38 94 11.15 04/16/2008 8:42 331 11.39 97 11.14 04/16/2008 8:43 293.3 11.36 101.5 11.22 04/16/2008 8:44 76.8 12.01 108.7 11.25 04/16/2008 8:45 32.6 12.73 105.3 11.27 04/16/2008 8:46 27.9 12.86 101.7 11.24 04/16/2008 8:47 27.8 12.77 100.4 11.32 04/16/2008 8:48 27.1 12.66 100.9 11.28 04/16/2008 8:49 26.8 12.57 106.5 11.24 04/16/2008 8:50 26.6 12.43 105.7 11.22 04/16/2008 8:51 33.1 12.43 107.2 11.17 04/16/2008 8:52 338.3 11.98 106.3 11.22 04/16/2008 8:53 51.2 7.61 106.8 11.24 04/16/2008 8:54 2.8 1.38 107.6 11.22 04/16/2008 8:55 1.5 0.33 107.6 11.15 04/16/2008 8:56 1.1 0.08 108.9 11.13 04/16/2008 8:57 1.2 0.08 114 11.17 04/16/2008 8:58 0.9 0.05 121.1 11.27 04/16/2008 8:59 44.8 2.52 115.5 11.27 04/16/2008 9:00 63.7 9.37 92.3 11.19 04/16/2008 9:01 63.9 11 85.4 11.18 04/16/2008 9:02 64 11.15 82.5 11.16 04/16/2008 9:03 64.3 11.21 86.5 11.11 04/16/2008 9:04 64.2 11.23 89.1 11.1 04/16/2008 9:05 64.3 10.92 92.9 11.19 04/16/2008 9:06 64 10.82 94.9 11 04/16/2008 9:07 40.4 9.86 96.1 10.82 04/16/2008 9:08 0.8 2.63 104.2 10.82 04/16/2008 9:09 0.6 0.43 103.7 10.88 04/16/2008 9:10 0.6 0.15 105 10.82 04/16/2008 9:11 0.6 0.11 105.7 10.91 04/16/2008 9:12 0.6 0.08 109.5 10.86 04/16/2008 9:13 0.5 0.01 108.4 10.83 04/16/2008 9:14 2.1 0.08 111.1 10.86 04/16/2008 9:15 57.2 3.74 111.7 10.89 04/16/2008 9:16 64.1 9.75 109.4 10.83 04/16/2008 9:17 63.8 10.69 111.1 10.96 04/16/2008 9:18 63.7 10.78 111.7 10.96 04/16/2008 9:19 64.2 10.83 117.2 10.96 04/16/2008 9:20 64.2 10.85 117 10.92

Page 2 of 11NOx and SO2 DAHS Raw Data



### Date Time NOX4 CO24 SO2_S3 CO2_S3 04/16/2008 9:21 64.2 10.85 111.1 10.9 04/16/2008 9:22 137.6 10.87 94.1 10.91 04/16/2008 9:23 317.5 10.83 84.3 10.96 04/16/2008 9:24 322.3 10.88 89.4 10.99 04/16/2008 9:25 321.9 10.96 89.6 10.94 04/16/2008 9:26 324.8 11.01 93.4 10.96 04/16/2008 9:27 324.4 11.03 95.3 10.98 04/16/2008 9:28 321.3 10.97 101.1 11.02 04/16/2008 9:29 323.1 10.94 101.2 11.02 04/16/2008 9:30 14.2 6.34 103.7 10.99 04/16/2008 9:31 2.3 0.9 104.4 11.02 04/16/2008 9:32 5.7 0.27 103.3 10.98 04/16/2008 9:33 27.1 6.29 97.2 10.9 04/16/2008 9:34 29.2 11.4 100.7 10.9 04/16/2008 9:35 29.2 12.24 102.9 10.86 04/16/2008 9:36 30.2 12.26 103 10.83 04/16/2008 9:37 30.2 12.15 107 10.86 04/16/2008 9:38 30.1 12.07 112.4 10.92 04/16/2008 9:39 30.2 12.05 112.2 10.81 04/16/2008 9:40 29.6 11.87 115.6 10.77 04/16/2008 9:41 29.4 11.79 104.8 10.82 04/16/2008 9:42 29.4 11.82 100.6 10.76 04/16/2008 9:43 29.9 11.82 107.1 10.84 04/16/2008 9:44 29.7 11.83 109 10.89 04/16/2008 9:45 29.5 11.85 108.8 11 04/16/2008 9:46 29.1 11.99 109.7 11.03 04/16/2008 9:47 28 12.07 110.1 11.01 04/16/2008 9:48 26.8 12.06 103.7 10.93 04/16/2008 9:49 25.8 11.98 102.4 10.96 04/16/2008 9:50 26.5 11.87 101.7 10.87 04/16/2008 9:51 27 11.9 109.3 10.79 04/16/2008 9:52 28.1 11.76 112 10.9 04/16/2008 9:53 28.8 11.81 114.8 10.97 04/16/2008 9:54 28.8 11.93 121.9 11.06 04/16/2008 9:55 28 12.05 120.8 11.08 04/16/2008 9:56 27.2 12.07 115.9 10.97 04/16/2008 9:57 26.8 12.02 106.7 10.87 04/16/2008 9:58 27.5 11.94 94.4 10.89 04/16/2008 9:59 27.9 11.91 92.3 10.85 04/16/2008 10:00 28.7 11.85 99.4 10.83 04/16/2008 10:01 29.3 11.82 106.6 10.94 04/16/2008 10:02 14.3 9.5 37.7 4.51 04/16/2008 10:03 0.4 1.83 27 1.03

Page 3 of 11NOx and SO2 DAHS Raw Data



### Date Time NOX4 CO24 SO2_S3 CO2_S3 04/16/2008 10:04 0.6 0.24 95 8.47 04/16/2008 10:05 11.7 1.08 95.5 10.72 04/16/2008 10:06 29.8 8.42 98.2 10.76 04/16/2008 10:07 31.1 11.65 100.6 10.72 04/16/2008 10:08 32 11.94 109.1 10.83 04/16/2008 10:09 32.3 11.91 113.4 10.91 04/16/2008 10:10 32.4 11.96 111 10.78 04/16/2008 10:11 31.9 11.92 114.3 10.85 04/16/2008 10:12 31.3 11.86 114.2 10.88 04/16/2008 10:13 30.3 11.87 111.2 10.98 04/16/2008 10:14 29.6 11.95 111.5 10.94 04/16/2008 10:15 28.8 11.92 114.7 10.86 04/16/2008 10:16 28.9 11.88 116.7 10.87 04/16/2008 10:17 28.8 11.91 114.7 10.76 04/16/2008 10:18 28.6 11.84 112.6 10.82 04/16/2008 10:19 28.7 11.74 114.3 10.87 04/16/2008 10:20 28.6 11.84 117.6 10.91 04/16/2008 10:21 28.2 11.86 123.5 11 04/16/2008 10:22 27.7 11.91 113.4 11.02 04/16/2008 10:23 27 12.01 98.5 10.94 04/16/2008 10:24 27.3 11.87 101.3 10.98 04/16/2008 10:25 27.7 11.9 100.1 10.95 04/16/2008 10:26 27.7 11.96 99.9 10.98 04/16/2008 10:27 27.9 11.95 98.2 10.93 04/16/2008 10:28 28.4 11.85 98.6 10.96 04/16/2008 10:29 29.1 11.93 100.8 10.96 04/16/2008 10:30 29.3 11.96 103.5 10.84 04/16/2008 10:31 28.7 11.83 108 10.87 04/16/2008 10:32 29.2 11.78 106.7 10.82 04/16/2008 10:33 29.5 11.8 112.9 10.82 04/16/2008 10:34 29.8 11.83 118.5 10.98 04/16/2008 10:35 30 11.89 113.2 10.87 04/16/2008 10:36 30 11.86 107.4 10.87 04/16/2008 10:37 30.5 11.88 112 10.81 04/16/2008 10:38 30.4 11.79 115.8 10.85 04/16/2008 10:39 30 11.75 118.8 10.95 04/16/2008 10:40 29.9 11.85 114.4 10.85 04/16/2008 10:41 29.9 11.89 122 10.88 04/16/2008 10:42 29.2 11.79 122.3 10.88 04/16/2008 10:43 27.9 11.83 112 10.83 04/16/2008 10:44 27.5 11.81 110.9 10.8 04/16/2008 10:45 28.6 11.77 110.1 10.87 04/16/2008 10:46 28.9 11.75 114.7 10.83

Page 4 of 11NOx and SO2 DAHS Raw Data



### Date Time NOX4 CO24 SO2_S3 CO2_S3 04/16/2008 10:47 29.3 11.77 115.8 10.8 04/16/2008 10:48 29.8 11.8 118.8 10.72 04/16/2008 10:49 29.4 11.69 117.2 10.78 04/16/2008 10:50 28.8 11.74 110.6 10.73 04/16/2008 10:51 28.3 11.73 108.8 10.73 04/16/2008 10:52 28.5 11.67 110.9 10.63 04/16/2008 10:53 29.5 11.58 112.9 10.74 04/16/2008 10:54 30.4 11.53 111.4 10.78 04/16/2008 10:55 31.7 11.7 109 10.61 04/16/2008 10:56 31.3 11.66 113.7 10.65 04/16/2008 10:57 30.7 11.56 122.8 10.75 04/16/2008 10:58 29.8 11.67 117.9 10.81 04/16/2008 10:59 28.8 11.7 119.8 10.81 04/16/2008 11:00 27.5 11.75 121.5 10.88 04/16/2008 11:01 26.1 11.77 128.1 10.9 04/16/2008 11:02 24.8 11.85 130.2 10.83 04/16/2008 11:03 24.1 11.9 129.5 10.88 04/16/2008 11:04 24 11.9 116.3 10.84 04/16/2008 11:05 23.5 11.9 101.1 10.85 04/16/2008 11:06 23.4 11.83 97.2 10.92 04/16/2008 11:07 24.2 11.83 98.5 10.9 04/16/2008 11:08 24.6 11.82 103 10.96 04/16/2008 11:09 24.3 11.82 105.9 10.95 04/16/2008 11:10 23.9 11.92 106.3 10.9 04/16/2008 11:11 23.1 11.96 114.4 10.88 04/16/2008 11:12 22.9 11.94 119 10.9 04/16/2008 11:13 22.7 11.98 123.2 10.98 04/16/2008 11:14 22.1 11.98 127 11 04/16/2008 11:15 22.8 11.93 129.5 10.91 04/16/2008 11:16 22.9 11.9 129 10.8 04/16/2008 11:17 23.5 11.77 128 10.92 04/16/2008 11:18 24.3 11.83 122.2 10.96 04/16/2008 11:19 24.8 11.97 119.5 10.93 04/16/2008 11:20 25.1 11.93 120.1 10.84 04/16/2008 11:21 25.3 11.87 124.2 10.92 04/16/2008 11:22 25.3 11.88 133.2 11.06 04/16/2008 11:23 25.8 12.04 135.8 11.08 04/16/2008 11:24 25.6 12.09 130.5 11.01 04/16/2008 11:25 26.5 12.04 127.7 10.92 04/16/2008 11:26 27.1 12.01 129.8 10.99 04/16/2008 11:27 27 11.99 128.1 11.07 04/16/2008 11:28 27.9 12.04 131.3 11.05 04/16/2008 11:29 27.7 12.03 134.6 11.01

Page 5 of 11NOx and SO2 DAHS Raw Data



### Date Time NOX4 CO24 SO2_S3 CO2_S3 04/16/2008 11:30 27.3 12.06 133.7 10.86 04/16/2008 11:31 27.9 11.94 136.1 10.93 04/16/2008 11:32 28.8 11.84 121.1 10.88 04/16/2008 11:33 29.7 11.72 106.9 11 04/16/2008 11:34 31 11.74 100.7 11.01 04/16/2008 11:35 31.2 11.9 98.3 10.84 04/16/2008 11:36 30.7 11.83 104 10.84 04/16/2008 11:37 30 11.83 105.5 10.78 04/16/2008 11:38 29.8 11.82 106.7 10.78 04/16/2008 11:39 30.6 11.67 105.1 10.76 04/16/2008 11:40 32.1 11.68 111.2 10.78 04/16/2008 11:41 32.1 11.73 119.2 10.87 04/16/2008 11:42 32.9 11.85 123.1 10.82 04/16/2008 11:43 32.9 11.85 119.6 10.67 04/16/2008 11:44 31.9 11.83 113.4 10.72 04/16/2008 11:45 31.7 11.8 117.6 10.74 04/16/2008 11:46 31.3 11.61 118.7 10.81 04/16/2008 11:47 30.9 11.69 117.7 10.81 04/16/2008 11:48 30 11.78 122.9 10.91 04/16/2008 11:49 28.8 11.87 125.1 10.9 04/16/2008 11:50 27.8 11.93 122.2 10.83 04/16/2008 11:51 27.1 11.9 113.5 10.86 04/16/2008 11:52 27 11.89 115.5 10.93 04/16/2008 11:53 26.9 11.9 117.2 10.87 04/16/2008 11:54 27.5 11.84 124.2 10.89 04/16/2008 11:55 29.1 11.86 123.9 10.95 04/16/2008 11:56 29.4 11.99 125.2 10.89 04/16/2008 11:57 28.3 11.94 135.3 10.84 04/16/2008 11:58 27.5 11.8 134.8 10.77 04/16/2008 11:59 27.7 11.76 127 10.79 04/16/2008 12:00 27.9 11.71 120.2 10.71 04/16/2008 12:01 27.8 11.69 116.4 10.76 04/16/2008 12:02 27.5 11.69 118.5 10.87 04/16/2008 12:03 27.1 11.73 123.5 10.85 04/16/2008 12:04 27.1 11.82 119.5 10.8 04/16/2008 12:05 27 11.79 122.3 10.79 04/16/2008 12:06 27.1 11.78 133 10.9 04/16/2008 12:07 27.5 11.94 135.3 10.98 04/16/2008 12:08 27.1 12 132.3 10.91 04/16/2008 12:09 26 11.97 126.9 10.82 04/16/2008 12:10 25.8 11.85 107.2 10.79 04/16/2008 12:11 26 11.78 98.6 10.7 04/16/2008 12:12 26.4 11.76 103.9 10.8

Page 6 of 11NOx and SO2 DAHS Raw Data



### Date Time NOX4 CO24 SO2_S3 CO2_S3 04/16/2008 12:13 26.9 11.62 112.8 10.89 04/16/2008 12:14 27.1 11.79 113 10.88 04/16/2008 12:15 26.7 11.95 113.5 10.85 04/16/2008 12:16 25.4 11.91 111.5 10.88 04/16/2008 12:17 25.1 11.81 117 10.85 04/16/2008 12:18 24.9 11.76 117.7 10.86 04/16/2008 12:19 25.3 11.8 113.8 10.89 04/16/2008 12:20 25.9 11.85 111.4 10.87 04/16/2008 12:21 26.3 11.9 116 10.81 04/16/2008 12:22 26.3 11.82 120.5 10.91 04/16/2008 12:23 26.9 11.82 118.6 10.95 04/16/2008 12:24 26.9 11.93 124 10.84 04/16/2008 12:25 27.1 11.87 126.6 10.9 04/16/2008 12:26 26.7 11.94 131.8 10.89 04/16/2008 12:27 26.5 11.91 133.7 10.92 04/16/2008 12:28 26.4 11.99 130.1 10.97 04/16/2008 12:29 26.3 11.98 133.2 11.03 04/16/2008 12:30 25.2 11.87 130.4 10.99 04/16/2008 12:31 24.7 11.98 130.9 10.95 04/16/2008 12:32 24.7 12 130 10.9 04/16/2008 12:33 24 11.95 133.1 10.95 04/16/2008 12:34 24.1 11.84 128.4 10.85 04/16/2008 12:35 24.8 11.78 122.6 10.9 04/16/2008 12:36 25.7 11.85 100.6 10.9 04/16/2008 12:37 26.1 11.88 98.6 10.91 04/16/2008 12:38 26.3 11.87 102.7 10.87 04/16/2008 12:39 26.9 11.88 107.8 10.97 04/16/2008 12:40 27.3 11.91 113.7 10.88 04/16/2008 12:41 27.1 11.97 120.9 10.88 04/16/2008 12:42 27.6 11.88 119.1 10.98 04/16/2008 12:43 27.4 11.83 115.1 10.84 04/16/2008 12:44 28.3 11.8 114.8 10.86 04/16/2008 12:45 28.4 11.84 112.9 10.94 04/16/2008 12:46 28.2 11.84 109.1 10.94 04/16/2008 12:47 28.4 11.95 113.9 11.03 04/16/2008 12:48 28 12.05 115.8 10.97 04/16/2008 12:49 27.3 12.08 118.9 10.92 04/16/2008 12:50 27.1 11.92 122.2 10.96 04/16/2008 12:51 27.5 11.95 128.3 11.08 04/16/2008 12:52 27.4 11.93 135.3 11.05 04/16/2008 12:53 27.9 11.97 133.2 10.98 04/16/2008 12:54 28.1 12.07 120 10.93 04/16/2008 12:55 27.9 12.01 119.2 10.98

Page 7 of 11NOx and SO2 DAHS Raw Data



### Date Time NOX4 CO24 SO2_S3 CO2_S3 04/16/2008 12:56 27.8 11.94 116 10.87 04/16/2008 12:57 27.7 11.87 120.6 10.94 04/16/2008 12:58 27.8 11.83 119.7 10.95 04/16/2008 12:59 28.9 11.93 120.3 10.91 04/16/2008 13:00 29.2 12.01 126.1 10.92 04/16/2008 13:01 28.7 12.01 115.8 10.88 04/16/2008 13:02 29.4 11.91 110 10.74 04/16/2008 13:03 30 11.76 114.6 10.79 04/16/2008 13:04 31.5 11.68 119.5 10.83 04/16/2008 13:05 32.1 11.81 125.3 10.83 04/16/2008 13:06 31.6 11.85 129.9 10.85 04/16/2008 13:07 31.1 11.85 126.3 10.86 04/16/2008 13:08 30.3 11.86 108.7 10.88 04/16/2008 13:09 30 11.85 99.5 11.02 04/16/2008 13:10 29.7 11.84 98.8 11 04/16/2008 13:11 29.7 11.84 102.3 11.01 04/16/2008 13:12 29.4 11.93 101.6 11.07 04/16/2008 13:13 28.4 12.07 107.9 11.08 04/16/2008 13:14 27.8 12.1 109.4 11.06 04/16/2008 13:15 26.6 12.09 112.9 10.94 04/16/2008 13:16 26.4 12.08 113.4 10.91 04/16/2008 13:17 25.8 11.96 120.2 10.82 04/16/2008 13:18 26.8 11.77 123.4 10.78 04/16/2008 13:19 28.1 11.86 121.9 10.8 04/16/2008 13:20 29.3 11.9 112.5 10.77 04/16/2008 13:21 29.3 11.85 115.2 10.85 04/16/2008 13:22 29.4 11.79 118.1 11.01 04/16/2008 13:23 30.1 11.89 121.2 10.93 04/16/2008 13:24 30.5 11.96 123.3 10.79 04/16/2008 13:25 30.5 11.91 128.8 10.82 04/16/2008 13:26 30 11.81 128.9 10.67 04/16/2008 13:27 30.5 11.7 127.8 10.81 04/16/2008 13:28 31.6 11.66 116.7 10.84 04/16/2008 13:29 31.7 11.79 117.4 10.85 04/16/2008 13:30 32 11.79 117.5 10.85 04/16/2008 13:31 31.1 11.91 119.8 10.88 04/16/2008 13:32 30 11.89 122.7 10.99 04/16/2008 13:33 29.4 11.93 117.2 10.85 04/16/2008 13:34 29.7 11.88 114.3 10.83 04/16/2008 13:35 30 11.76 114.4 10.7 04/16/2008 13:36 30.2 11.75 116.8 10.73 04/16/2008 13:37 30.2 11.66 127.6 10.93 04/16/2008 13:38 30.5 11.77 127.1 10.95

Page 8 of 11NOx and SO2 DAHS Raw Data



### Date Time NOX4 CO24 SO2_S3 CO2_S3 04/16/2008 13:39 29.5 11.95 130.8 10.92 04/16/2008 13:40 28.6 11.87 133.7 10.88 04/16/2008 13:41 28.1 11.91 129.4 10.82 04/16/2008 13:42 27.8 11.85 122.3 10.8 04/16/2008 13:43 28.1 11.82 124.2 10.84 04/16/2008 13:44 28.4 11.79 125.6 10.79 04/16/2008 13:45 29 11.77 132.6 10.85 04/16/2008 13:46 29.7 11.79 135.7 10.86 04/16/2008 13:47 28.9 11.89 140.7 10.93 04/16/2008 13:48 28.2 11.87 135.6 10.87 04/16/2008 13:49 27.7 11.86 119.2 10.83 04/16/2008 13:50 27.6 11.81 115 10.66 04/16/2008 13:51 28 11.67 118.4 10.63 04/16/2008 13:52 28.8 11.53 122.7 10.66 04/16/2008 13:53 29 11.51 128.8 10.7 04/16/2008 13:54 29.3 11.67 135 10.81 04/16/2008 13:55 29 11.82 124 10.78 04/16/2008 13:56 28 11.87 100.6 10.8 04/16/2008 13:57 27.6 11.76 98.3 10.8 04/16/2008 13:58 27.1 11.75 99.5 10.8 04/16/2008 13:59 27.1 11.7 105.5 10.84 04/16/2008 14:00 27.4 11.76 108.5 10.81 04/16/2008 14:01 27.7 11.81 111.1 10.88 04/16/2008 14:02 27.3 11.89 117.3 10.74 04/16/2008 14:03 26.9 11.78 125.6 10.95 04/16/2008 14:04 26.3 11.78 118.8 10.85 04/16/2008 14:05 25.8 11.83 114.1 10.83 04/16/2008 14:06 25.7 11.77 117.5 10.7 04/16/2008 14:07 26.1 11.69 116.6 10.7 04/16/2008 14:08 26.7 11.75 114.7 10.69 04/16/2008 14:09 27.1 11.67 119.5 10.77 04/16/2008 14:10 27.1 11.7 124.4 10.83 04/16/2008 14:11 26.8 11.77 120.7 10.77 04/16/2008 14:12 26.4 11.74 115.3 10.69 04/16/2008 14:13 26.3 11.72 119.3 10.73 04/16/2008 14:14 25.7 11.76 120.5 10.71 04/16/2008 14:15 25.2 11.73 125.9 10.72 04/16/2008 14:16 25.8 11.64 132.5 10.79 04/16/2008 14:17 25.8 11.69 138 10.76 04/16/2008 14:18 25.8 11.68 133.4 10.71 04/16/2008 14:19 25.7 11.68 117.3 10.76 04/16/2008 14:20 25.4 11.64 105.2 10.74 04/16/2008 14:21 25.1 11.63 105.7 10.76

Page 9 of 11NOx and SO2 DAHS Raw Data



### Date Time NOX4 CO24 SO2_S3 CO2_S3 04/16/2008 14:22 25 11.73 106.1 10.73 04/16/2008 14:23 24.7 11.78 109.9 10.72 04/16/2008 14:24 24.5 11.71 116.8 10.8 04/16/2008 14:25 24.6 11.7 119.6 10.87 04/16/2008 14:26 25.2 11.82 116.3 10.85 04/16/2008 14:27 25 11.83 110.4 10.73 04/16/2008 14:28 24.2 11.78 114.4 10.67 04/16/2008 14:29 24.3 11.68 117.1 10.8 04/16/2008 14:30 24.3 11.77 121.8 10.8 04/16/2008 14:31 24 11.77 126 10.84 04/16/2008 14:32 23.5 11.82 131.1 10.81 04/16/2008 14:33 23.1 11.78 133.1 10.82 04/16/2008 14:34 22.9 11.77 133.7 10.78 04/16/2008 14:35 23.3 11.74 129.7 10.91 04/16/2008 14:36 24 11.73 122.6 10.82 04/16/2008 14:37 23.9 11.81 111.2 10.82 04/16/2008 14:38 24.1 11.8 109.3 10.73 04/16/2008 14:39 23.8 11.67 116.9 10.81 04/16/2008 14:40 23.9 11.7 122.4 10.81 04/16/2008 14:41 24.1 11.83 120.3 10.74 04/16/2008 14:42 24 11.73 117.4 10.79 04/16/2008 14:43 24.5 11.73 119.7 10.87 04/16/2008 14:44 24.9 11.83 119.3 10.79 04/16/2008 14:45 24.8 11.82 125.8 10.77 04/16/2008 14:46 24.1 11.73 128.6 10.89 04/16/2008 14:47 23.6 11.86 132.1 10.9 04/16/2008 14:48 23.4 11.87 130.5 10.89 04/16/2008 14:49 23.4 11.91 123.4 10.85 04/16/2008 14:50 23 11.86 120.7 10.78 04/16/2008 14:51 23.7 11.81 123.1 10.79 04/16/2008 14:52 24.2 11.74 122.3 10.73 04/16/2008 14:53 24.8 11.77 128.2 10.82 04/16/2008 14:54 25.1 11.75 135.6 10.86 04/16/2008 14:55 24.4 11.85 138.4 10.93 04/16/2008 14:56 24.7 11.87 132.6 10.82 04/16/2008 14:57 24.2 11.88 127.9 10.82 04/16/2008 14:58 24.1 11.73 122.1 10.74 04/16/2008 14:59 24.9 11.64 107 10.69 04/16/2008 15:00 26 11.61 99.1 10.79 04/16/2008 15:01 26.8 11.72 107.2 10.77 04/16/2008 15:02 26.5 11.79 115.7 10.78 04/16/2008 15:03 25.8 11.73 119.3 10.76 04/16/2008 15:04 26 11.7 115.6 10.74

Page 10 of 11NOx and SO2 DAHS Raw Data



### Date Time NOX4 CO24 SO2_S3 CO2_S3 04/16/2008 15:05 26.3 11.77 109 10.76 04/16/2008 15:06 26.3 11.79 115.9 10.82 04/16/2008 15:07 26.2 11.79 116 10.87 04/16/2008 15:08 26.4 11.82 121.7 10.7 04/16/2008 15:09 26.4 11.7 130.2 10.8 04/16/2008 15:10 26.6 11.75 131 10.89 04/16/2008 15:12 26.1 11.91 125.1 10.84 04/16/2008 15:13 25.7 11.88 127.4 10.9 04/16/2008 15:14 25 11.89 132.3 11 04/16/2008 15:15 24.8 11.94 136.6 10.98 04/16/2008 15:16 24.6 11.93 136.4 10.91 04/16/2008 15:17 24.8 11.88 137.4 10.82 04/16/2008 15:18 25.4 11.83 128.8 10.78 04/16/2008 15:19 26.4 11.82 130.6 10.85 04/16/2008 15:20 26.4 11.78 132.4 10.9 04/16/2008 15:21 26.4 11.86 131.8 10.79 04/16/2008 15:22 26.8 11.78 133.9 10.82 04/16/2008 15:23 27 11.81 112.9 10.85 04/16/2008 15:24 27.1 11.81 106.2 10.8 04/16/2008 15:25 27.3 11.79 107.4 11 04/16/2008 15:26 28 11.84 108.7 10.98 04/16/2008 15:27 27.8 11.92 114 10.92 04/16/2008 15:28 27.7 11.96 114.8 10.93 04/16/2008 15:29 27.6 11.91 118.7 10.92 04/16/2008 15:30 27.8 11.88 123.6 10.87 04/16/2008 15:31 28.9 11.84 136.2 10.89 04/16/2008 15:32 28.9 11.88 134.1 10.89 04/16/2008 15:33 28.8 11.94 125.2 10.91 04/16/2008 15:34 28.3 11.9 123.6 10.9 04/16/2008 15:35 28.2 11.88 127.1 10.9 04/16/2008 15:36 28.1 11.85 127.2 10.88 04/16/2008 15:37 28.4 11.89 131.2 10.94 NOX4 CO24 SO2_S3 CO2_S3 A vera g es: 38.9108 11.098 114.153 10.873

Page 11 of 11

# APPENDIX D

OPERATIONS DATAPI Load DataPlant Information Source: bbnd-1pisrvStart Time: 04/16/2008 8:55End Time: 04/16/2008 15:37Time Interval: 1 minTagName: 4spuw501g4AAHF901Q-PV 4AAHP901A 4AAHT901A 4AAHF902Q-PV 4AAHP903A 4AAHT902ATagExplanation: Unit Load NH3 Flow NH3 Pressure NH3 Temp SO3 Injection SO3 Pressure SO3 TempTagUnits: MweRun Average: 434.9985948 251.8433854 15.2382769 60.530128116-Apr-08 08:55:00 434.4073792 273.6228638 14.81388855 52.6554413 75.12216187 12.21241474 53.984371216-Apr-08 08:56:00 435.1443481 272.927948 14.79816628 52.7345276 75.10751343 12.21152306 53.995620716-Apr-08 08:57:00 436.833313 272.2330627 14.78021336 52.8136139 75.09286499 12.21063042 54.006874116-Apr-08 08:58:00 437.9479065 271.5381775 14.76225948 52.8927002 75.07821655 12.20973873 54.018123616-Apr-08 08:59:00 437.8314514 270.8432922 14.75266075 52.9717903 75.06356812 12.20884705 54.029373216-Apr-08 09:00:00 434.8054199 270.148407 14.7555933 53.0508766 74.93151093 12.20795441 54.040622716-Apr-08 09:01:00 434.5835876 269.4534912 14.75852489 53.0785561 74.79745483 12.20706272 54.051876116-Apr-08 09:02:00 435.3978577 268.758606 14.76145744 53.0785561 74.66340637 12.20617104 54.063125616-Apr-08 09:03:00 435.3389282 269.3173523 14.76438999 53.0785561 74.52935791 12.20527935 54.074375216-Apr-08 09:04:00 433.1358643 270.2575989 14.76732159 53.0785561 74.39530182 12.20438671 54.085624716-Apr-08 09:05:00 433.3453064 271.197876 14.77025414 53.0785561 74.26125336 12.20349503 54.096878116-Apr-08 09:06:00 434.0787048 272.1381531 14.77318668 53.0785561 74.1272049 12.20260334 54.108127616-Apr-08 09:07:00 434.2475281 273.0784302 14.77611828 53.0785561 73.9931488 12.2017107 54.119377116-Apr-08 09:08:00 434.116272 274.0186768 14.77905083 53.0785561 73.85910034 12.20081902 54.130626716-Apr-08 09:09:00 433.8292542 274.9589539 14.78198338 53.0785561 73.72505188 12.20041275 54.1418816-Apr-08 09:10:00 433.9274292 275.899231 14.78491497 53.0785561 73.59099579 12.21409702 54.163841216-Apr-08 09:11:00 434.4601135 276.8394775 14.78784752 53.0785561 73.45694733 12.2277813 54.210807816-Apr-08 09:12:00 434.7341614 277.7797546 14.79078007 53.0785561 73.32289886 12.24146557 54.257774416-Apr-08 09:13:00 435.321106 278.7200317 14.79371166 53.0785561 73.18884277 12.25514984 54.304737116-Apr-08 09:14:00 436.7185974 277.9354248 14.79664421 53.0785561 73.05479431 12.26883411 54.351703616-Apr-08 09:15:00 437.1976624 276.9591675 14.79957676 53.0785561 72.92074585 12.28251839 54.398670216-Apr-08 09:16:00 435.8541565 275.9828796 14.80250931 53.0785561 72.78668976 12.29620266 54.445632916-Apr-08 09:17:00 434.8429871 275.0066223 14.8054409 53.0785561 72.71313477 12.30988693 54.492599516-Apr-08 09:18:00 434.0418701 274.4445801 14.80837345 53.1308098 72.77009583 12.32357025 54.53956616-Apr-08 09:19:00 434.245697 274.8490601 14.80069828 53.184864 72.82706451 12.33725452 54.586528816-Apr-08 09:20:00 434.3196106 275.25354 14.78544617 53.2389221 72.8840332 12.3509388 54.633495316-Apr-08 09:21:00 434.9169312 275.6579895 14.77019501 53.2929764 72.94100189 12.36462307 54.680461916-Apr-08 09:22:00 434.9345398 276.0624695 14.75494289 53.3470306 72.99797058 12.37830734 54.727424616-Apr-08 09:23:00 435.4662476 276.4669495 14.73969173 53.4010849 73.05493927 12.39199162 54.774391216-Apr-08 09:24:00 435.348877 276.8714294 14.72443962 53.455143 73.11190796 12.40567589 54.821353916-Apr-08 09:25:00 433.8937073 276.9872437 14.70918846 53.5091972 73.16887665 12.41936016 54.868320516-Apr-08 09:26:00 433.639679 277.0768433 14.69393635 53.5632515 73.22584534 12.43304443 54.91528716-Apr-08 09:27:00 433.9448547 277.1664429 14.67868519 53.6173096 73.2828064 12.44672871 54.962249816-Apr-08 09:28:00 434.9279175 277.2560425 14.66343307 53.6713638 73.33977509 12.46041298 55.067268416-Apr-08 09:29:00 435.3770447 277.3456421 14.64818096 53.7254181 73.39674377 12.47291279 55.175338716-Apr-08 09:30:00 436.0056152 277.4352112 14.6329298 53.7794724 73.45371246 12.479496 55.2834129Page 1 of 10PI Load DataTagName: 4spuw501g4AAHF901Q-PV 4AAHP901A 4AAHT901A 4AAHF902Q-PV 4AAHP903A 4AAHT902ATagExplanation: Unit Load NH3 Flow NH3 Pressure NH3 Temp SO3 Injection SO3 Pressure SO3 TempTagUnits: Mwe16-Apr-08 09:31:00 436.331604 277.5248108 14.61767769 53.8335304 73.48944092 12.48607826 55.391483316-Apr-08 09:32:00 435.2528076 277.6144104 14.60242653 53.8875847 73.52039337 12.49266052 55.499557516-Apr-08 09:33:00 434.6467896 277.70401 14.58717442 53.9416389 73.55135345 12.49924278 55.607627916-Apr-08 09:34:00 433.5993652 277.7936096 14.57192326 53.995697 73.58230591 12.505826 55.715702116-Apr-08 09:35:00 433.3421326 277.5805054 14.55667114 54.0497513 73.61326599 12.51240826 55.823772416-Apr-08 09:36:00 433.3170471 277.2917175 14.55340672 54.1038055 73.64422607 12.51899052 55.931846616-Apr-08 09:37:00 434.1410522 277.0029602 14.6100769 54.163063 73.67517853 12.52557278 56.03991716-Apr-08 09:38:00 435.4431763 276.7141724 14.66674805 54.2518005 73.70613861 12.53215599 56.147991216-Apr-08 09:39:00 435.3312683 276.425415 14.72341824 54.3405342 73.73709106 12.53873825 56.256061616-Apr-08 09:40:00 436.0808716 275.4485168 14.78008938 54.4292717 73.76805115 12.54532051 56.364135716-Apr-08 09:41:00 437.2157898 272.7311401 14.83675957 54.5180054 73.79901123 12.55190277 56.472206116-Apr-08 09:42:00 437.8204041 270.0137634 14.83809948 54.6067429 73.82996368 12.55848598 56.580276516-Apr-08 09:43:00 437.5081177 267.2963867 14.83753204 54.6954765 73.86092377 12.56506824 56.688350716-Apr-08 09:44:00 436.2639771 264.57901 14.83696365 54.784214 73.89187622 12.57165051 56.796421116-Apr-08 09:45:00 434.6598816 263.9679565 14.83639622 54.8729477 73.9228363 12.57823277 56.904495216-Apr-08 09:46:00 435.2298584 264.059021 14.83582783 54.9616852 73.95378876 12.58481598 57.012565616-Apr-08 09:47:00 435.8157654 264.1500549 14.83526039 55.0504189 73.98474884 12.59139824 57.120639816-Apr-08 09:48:00 436.5198669 264.2411194 14.83469296 55.1391525 74.01570892 12.5979805 57.228710216-Apr-08 09:49:00 436.62323 264.3321838 14.83412457 55.22789 74.04666138 12.60456276 57.336784416-Apr-08 09:50:00 435.592865 264.4232483 14.83355713 55.3166237 74.08218384 12.61114597 57.41907516-Apr-08 09:51:00 433.5228271 264.5143127 14.83298874 55.4053612 74.15880585 12.61772823 57.475589816-Apr-08 09:52:00 434.3546753 264.6053772 14.8324213 55.4940948 74.23543549 12.62431049 57.532104516-Apr-08 09:53:00 435.8598938 264.6964111 14.83185291 55.5828323 74.3120575 12.63089275 57.588619216-Apr-08 09:54:00 436.7198792 264.7874756 14.83128548 55.671566 74.3886795 12.62589169 57.645130216-Apr-08 09:55:00 435.5856018 264.87854 14.83071709 55.7603035 74.46530151 12.61667728 57.701644916-Apr-08 09:56:00 434.3400879 264.9696045 14.83014965 55.8490372 74.54192352 12.60746384 57.758159616-Apr-08 09:57:00 434.3071899 265.0606689 14.82958126 55.9377747 74.61854553 12.59824944 57.814674416-Apr-08 09:58:00 434.5862427 265.1517029 14.82901382 56.0265083 74.69516754 12.58903599 57.871189116-Apr-08 09:59:00 433.8515625 265.2427673 14.82844543 56.1152458 74.77178955 12.57982159 57.927716-Apr-08 10:00:00 434.4571228 265.3436584 14.827878 56.2039795 74.84841919 12.57060814 57.984214816-Apr-08 10:01:00 434.0628662 265.4615173 14.82730961 56.292717 74.9250412 12.56139374 58.040729516-Apr-08 10:02:00 434.4468079 265.5793762 14.82738304 56.3320694 75.00166321 12.55218029 58.097244316-Apr-08 10:03:00 435.1800537 265.6972351 14.82755566 56.3590775 75.07828522 12.54296589 58.153755216-Apr-08 10:04:00 435.3957214 265.8150635 14.82772732 56.3860893 75.15490723 12.53375244 58.210269916-Apr-08 10:05:00 434.7780151 265.9329224 14.82789993 56.4130974 75.23152924 12.52453804 58.266784716-Apr-08 10:06:00 434.9612427 266.0507813 14.82807159 56.4401054 75.30815125 12.51532459 58.323299416-Apr-08 10:07:00 434.7479248 266.1686401 14.82824326 56.4671135 75.38478088 12.50611019 58.379810316-Apr-08 10:08:00 434.995575 266.286499 14.82841587 56.4941254 75.46140289 12.49689674 58.436325116-Apr-08 10:09:00 433.7548828 266.4043579 14.82858753 56.5211334 75.5380249 12.48768234 58.465911916-Apr-08 10:10:00 434.7388916 266.5221863 14.82876015 56.5481415 75.61464691 12.47846889 58.45217916-Apr-08 10:11:00 435.4642334 266.6400452 14.82893181 56.5751495 75.59101105 12.46925449 58.43844616-Apr-08 10:12:00 435.9233398 266.7579041 14.82910442 56.6021614 75.55194092 12.46004105 58.424713116-Apr-08 10:13:00 435.0026245 266.8757629 14.82927608 56.6291695 75.51287842 12.45082664 58.410980216-Apr-08 10:14:00 436.3188171 266.7134705 14.83594704 56.6561775 75.47381592 12.44171238 58.397243516-Apr-08 10:15:00 436.4285583 265.7807312 14.8442421 56.6831856 75.43475342 12.43278313 58.3835106Page 2 of 10PI Load DataTagName: 4spuw501g4AAHF901Q-PV 4AAHP901A 4AAHT901A 4AAHF902Q-PV 4AAHP903A 4AAHT902ATagExplanation: Unit Load NH3 Flow NH3 Pressure NH3 Temp SO3 Injection SO3 Pressure SO3 TempTagUnits: Mwe16-Apr-08 10:16:00 435.0532532 264.8480225 14.85253716 56.7101974 75.39569092 12.42385387 58.369777716-Apr-08 10:17:00 434.7377014 263.9152832 14.86083221 56.7372055 75.35662842 12.41492558 58.356044816-Apr-08 10:18:00 434.2568359 262.9825745 14.86912727 56.7642136 75.31755829 12.40599632 58.342311916-Apr-08 10:19:00 435.1564941 261.6954346 14.87742233 56.7912216 75.27849579 12.39706707 58.328578916-Apr-08 10:20:00 434.6903687 260.0032959 14.88571739 56.8182335 75.23943329 12.38813782 58.31484616-Apr-08 10:21:00 436.7900696 258.3111572 14.8940134 56.8452415 75.20037079 12.37920856 58.301113116-Apr-08 10:22:00 437.1142578 256.6190186 14.90230846 56.8828697 75.16130829 12.37028027 58.287380216-Apr-08 10:23:00 435.8831482 254.9268799 14.91060352 56.9231567 75.12224579 12.36135101 58.273647316-Apr-08 10:24:00 436.7323914 253.2347412 14.91889858 56.9634399 75.08318329 12.35242176 58.259910616-Apr-08 10:25:00 436.0942383 252.2230988 14.92719364 57.0037231 75.04411316 12.34349251 58.246177716-Apr-08 10:26:00 436.5689087 251.3161469 14.9354887 57.0440063 75.00505066 12.33456326 58.232444816-Apr-08 10:27:00 436.2366638 250.4091949 14.94378376 57.0842934 74.96598816 12.32563496 58.218711916-Apr-08 10:28:00 435.8391724 249.502243 14.95207977 57.1245766 74.92692566 12.3167057 58.204978916-Apr-08 10:29:00 433.9617615 248.5952911 14.96037483 57.1648598 74.88786316 12.30777645 58.196510316-Apr-08 10:30:00 433.0309448 248.980957 14.96866989 57.2051468 74.84880066 12.2988472 58.196510316-Apr-08 10:31:00 433.1894226 249.5102539 14.97696495 57.24543 74.80603027 12.28991795 58.196510316-Apr-08 10:32:00 433.7600098 250.0395355 14.98526001 57.2857132 74.76269531 12.28098965 58.196510316-Apr-08 10:33:00 434.2459717 250.5688324 14.99355507 57.3260002 74.71936035 12.27206039 58.196510316-Apr-08 10:34:00 433.8117065 251.0981293 15.00185013 57.3662834 74.67602539 12.26313114 58.196510316-Apr-08 10:35:00 432.8156738 251.6274261 15.01014614 57.4065666 74.63269043 12.25420189 58.196510316-Apr-08 10:36:00 433.2783203 252.1567078 15.0184412 57.4468498 74.58934784 12.24527264 58.196510316-Apr-08 10:37:00 434.7285461 252.6860046 15.02669239 57.4871368 74.54601288 12.23634434 58.196510316-Apr-08 10:38:00 433.942688 253.2153015 15.03366947 57.52742 74.50267792 12.22741508 58.196510316-Apr-08 10:39:00 435.3312683 253.7445831 15.04064751 57.5677032 74.45934296 12.21838284 58.196510316-Apr-08 10:40:00 436.1104736 254.27388 15.04762459 57.6079903 74.416008 12.20326328 58.196510316-Apr-08 10:41:00 437.741272 253.5801239 15.05460262 57.6482735 74.37267303 12.18814468 58.196510316-Apr-08 10:42:00 438.5900269 249.2172089 15.0615797 57.7055321 74.32933807 12.17302513 58.196510316-Apr-08 10:43:00 436.8308411 244.8543091 15.06855774 57.7670326 74.28599548 12.15790653 58.196510316-Apr-08 10:44:00 436.0904236 242.8804779 15.07553482 57.8285294 74.24266052 12.14278698 58.196510316-Apr-08 10:45:00 434.7209167 245.0332794 15.0825119 57.8900299 74.19932556 12.12766838 58.196510316-Apr-08 10:46:00 433.4967651 247.1860657 15.08948994 57.9515305 74.1559906 12.11254883 58.196510316-Apr-08 10:47:00 433.7116089 249.3388672 15.09646702 58.013031 74.11265564 12.09743023 58.196510316-Apr-08 10:48:00 434.5106506 249.5893402 15.10344505 58.0745316 74.06932068 12.08231068 58.196510316-Apr-08 10:49:00 435.8914795 248.8886566 15.11042213 58.1360321 74.02598572 12.06719208 58.186157216-Apr-08 10:50:00 437.4866333 247.5280304 15.11740017 58.1975327 73.98264313 12.05207253 58.159149216-Apr-08 10:51:00 437.3119202 243.7814026 15.12437725 58.2590332 73.95729828 12.03695393 58.132137316-Apr-08 10:52:00 435.9952393 240.0347748 15.13135433 58.3205338 73.93470764 12.02183437 58.105129216-Apr-08 10:53:00 435.1392212 236.3598328 15.13833237 58.3820343 73.91212463 12.00671577 58.078121216-Apr-08 10:54:00 434.6555176 236.9141083 15.14530945 58.4435349 73.88954163 11.99159622 58.051113116-Apr-08 10:55:00 434.1049805 237.4683838 15.15228748 58.5050354 73.86695862 11.97647762 58.024101316-Apr-08 10:56:00 434.4927673 238.0226593 15.15926456 58.5665359 73.84437561 11.96135807 57.997093216-Apr-08 10:57:00 435.8924866 238.5769348 15.1662426 58.6280365 73.8217926 11.94623947 57.970085116-Apr-08 10:58:00 436.3769836 238.4505463 15.17321968 58.689537 73.79920959 11.93111992 57.943077116-Apr-08 10:59:00 435.8806152 237.229187 15.18019772 58.7429886 73.77662659 11.91600037 57.916065216-Apr-08 11:00:00 433.8816528 236.0078278 15.1871748 58.7699966 73.75404358 11.90088177 57.8890572Page 3 of 10PI Load DataTagName: 4spuw501g4AAHF901Q-PV 4AAHP901A 4AAHT901A 4AAHF902Q-PV 4AAHP903A 4AAHT902ATagExplanation: Unit Load NH3 Flow NH3 Pressure NH3 Temp SO3 Injection SO3 Pressure SO3 TempTagUnits: Mwe16-Apr-08 11:01:00 433.5389099 235.3529205 15.19415188 58.7970047 73.73146057 11.88576221 57.862049116-Apr-08 11:02:00 432.3251953 239.796051 15.20031834 58.8240166 73.70886993 11.87447166 57.83504116-Apr-08 11:03:00 430.9823914 244.2391815 15.19107628 58.8510246 73.68628693 11.87211132 57.808029216-Apr-08 11:04:00 432.1726074 248.682312 15.18183327 58.8780327 73.66370392 11.86975098 57.781021116-Apr-08 11:05:00 434.0838318 249.8466797 15.17259121 58.9050407 73.64112091 11.86739159 57.754013116-Apr-08 11:06:00 434.495636 249.605835 15.1633482 58.9320488 73.6185379 11.86503124 57.72700516-Apr-08 11:07:00 434.3878174 249.3649902 15.15410519 58.9590607 73.5959549 11.86267185 57.699993116-Apr-08 11:08:00 435.6174011 249.1241608 15.1464138 58.9860687 73.57337189 11.86031151 57.672985116-Apr-08 11:09:00 436.6005859 248.883316 15.15267467 59.0130768 73.55078888 11.85795212 57.661594416-Apr-08 11:10:00 436.3190613 248.6424866 15.15893555 59.0400848 73.52820587 11.85559177 57.675327316-Apr-08 11:11:00 434.4191284 248.4016418 15.16519642 59.0670929 73.50562286 11.85323238 57.689060216-Apr-08 11:12:00 433.5612183 248.1608124 15.17145824 59.0941048 73.48303223 11.85087204 57.702793116-Apr-08 11:13:00 433.7723389 247.9199677 15.17771912 59.1211128 73.46044922 11.8485117 57.71652616-Apr-08 11:14:00 434.9726868 247.1419983 15.18397999 59.1481209 73.43786621 11.84615231 57.730262816-Apr-08 11:15:00 434.9373169 246.0530396 15.19024086 59.1751289 73.4152832 11.84379196 57.743995716-Apr-08 11:16:00 435.8195801 244.9640808 15.19650269 59.202137 73.3927002 11.84143257 57.757728616-Apr-08 11:17:00 437.200531 243.8751373 15.19521046 59.2291489 73.37011719 11.83907223 57.771461516-Apr-08 11:18:00 437.0148926 242.7861786 15.17761803 59.2561569 73.34753418 11.83671284 57.785194416-Apr-08 11:19:00 435.6720581 242.1770935 15.16002655 59.283165 73.32495117 11.83435249 57.798927316-Apr-08 11:20:00 435.3909302 242.1544952 15.14243507 59.310173 73.30236816 11.83199215 57.812660216-Apr-08 11:21:00 435.7661743 242.131897 15.1248436 59.3371849 73.27978516 11.82959843 57.826393116-Apr-08 11:22:00 434.7249756 242.1092987 15.10725117 59.364193 73.25719452 11.82719803 57.84012616-Apr-08 11:23:00 435.0337219 242.0867004 15.08965969 59.391201 73.23461151 11.82479668 57.853858916-Apr-08 11:24:00 435.4940186 242.0641174 15.07206821 59.4182091 73.2120285 11.82239532 57.867595716-Apr-08 11:25:00 435.489624 242.0415192 15.05447578 59.4452209 73.1894455 11.81999493 57.881328616-Apr-08 11:26:00 434.3173828 242.0189209 15.03688431 59.472229 73.16686249 11.81759357 57.895061516-Apr-08 11:27:00 434.0342407 241.9963226 15.01929283 59.4992371 73.14427948 11.81519318 57.908794416-Apr-08 11:28:00 434.1410522 242.2457733 15.00170135 59.5262451 73.12169647 11.81279182 57.922527316-Apr-08 11:29:00 434.6595154 243.0393066 14.98410892 59.553257 73.09911346 11.81039143 57.94134916-Apr-08 11:30:00 434.7887878 243.83284 14.96651745 59.580265 73.07653046 11.80799007 57.968357116-Apr-08 11:31:00 435.1166687 244.6263733 14.94892597 59.6072731 73.05236053 11.80558968 57.99536916-Apr-08 11:32:00 433.0864563 245.4199066 14.93133354 59.6342812 73.02793884 11.80318832 58.02237716-Apr-08 11:33:00 433.4426575 246.2134552 14.91201591 59.661293 73.00352478 11.80078793 58.049385116-Apr-08 11:34:00 434.4642639 247.0069885 14.89058876 59.6883011 72.97911072 11.79838657 58.076393116-Apr-08 11:35:00 435.8806152 247.8005219 14.86916065 59.7153091 72.95469666 11.79598618 58.10340516-Apr-08 11:36:00 435.8907776 248.5940552 14.84773254 59.7423172 72.93028259 11.79358482 58.130413116-Apr-08 11:37:00 436.1828308 249.3875885 14.82630539 59.7693291 72.90586853 11.79118443 58.157421116-Apr-08 11:38:00 435.8251038 249.4323578 14.80487728 59.7963371 72.88145447 11.78878307 58.184429216-Apr-08 11:39:00 435.7290955 249.3619232 14.78344917 59.8233452 72.85704041 11.78638268 58.21144116-Apr-08 11:40:00 434.3851929 249.2914886 14.76202202 59.8503532 72.83262634 11.78398132 58.238449116-Apr-08 11:41:00 432.9355774 249.2210693 14.74059391 59.8773613 72.80821228 11.78158092 58.265457216-Apr-08 11:42:00 434.2936401 250.4544983 14.71916676 59.9043732 72.78379059 11.77917957 58.292465216-Apr-08 11:43:00 436.0375671 251.7328949 14.69773865 59.9313812 72.75937653 11.77677822 58.319477116-Apr-08 11:44:00 435.2470398 253.0112915 14.67631054 59.9583893 72.73496246 11.77437782 58.346485116-Apr-08 11:45:00 434.7144165 254.2896881 14.65488338 59.9853973 72.7105484 11.77197647 58.3734932Page 4 of 10PI Load DataTagName: 4spuw501g4AAHF901Q-PV 4AAHP901A 4AAHT901A 4AAHF902Q-PV 4AAHP903A 4AAHT902ATagExplanation: Unit Load NH3 Flow NH3 Pressure NH3 Temp SO3 Injection SO3 Pressure SO3 TempTagUnits: Mwe16-Apr-08 11:46:00 434.3928223 255.5680847 14.63345528 60.0124054 72.68613434 11.77288532 58.400501316-Apr-08 11:47:00 433.3381653 256.8464661 14.61202812 60.0394173 72.66172028 11.77480125 58.427513116-Apr-08 11:48:00 432.7735901 260.2093506 14.59060001 60.0664253 72.63730621 11.77671623 58.454521216-Apr-08 11:49:00 433.07901 264.6946106 14.56917191 60.0934334 72.61289215 11.77863216 58.471176116-Apr-08 11:50:00 431.913208 269.1799011 14.54774475 60.1204414 72.58847809 11.7805481 58.471176116-Apr-08 11:51:00 432.7982483 273.6651917 14.52631664 60.1474495 72.60902405 11.78246307 58.471176116-Apr-08 11:52:00 432.7914734 278.1504517 14.50488853 60.1744614 72.63648987 11.78437901 58.471176116-Apr-08 11:53:00 434.3579712 277.5270386 14.59636211 60.2014694 72.66395569 11.78629494 58.471176116-Apr-08 11:54:00 437.2306519 275.6264038 14.68974876 60.2284775 72.69142914 11.78820992 58.471176116-Apr-08 11:55:00 438.4613342 273.7257996 14.78313541 60.2554855 72.71889496 11.79012585 58.471176116-Apr-08 11:56:00 438.6194153 271.8251648 14.87652206 60.2824936 72.74636078 11.79204178 58.471176116-Apr-08 11:57:00 437.2142944 269.4992371 14.99156475 60.3095055 72.7738266 11.79395676 58.471176116-Apr-08 11:58:00 436.4671021 265.7757568 15.12432671 60.3365135 72.80129242 11.79587269 58.471176116-Apr-08 11:59:00 436.4717102 262.1139526 15.25225067 60.3572197 72.82875824 11.79778862 58.471176116-Apr-08 12:00:00 436.396759 262.0924377 15.2399025 60.3572197 72.85622406 11.7997036 58.471176116-Apr-08 12:01:00 435.0919189 262.0709229 15.22755432 60.3572197 72.88369751 11.80161953 58.471176116-Apr-08 12:02:00 435.1211548 262.049408 15.21520519 60.3572197 72.91116333 11.80353546 58.471176116-Apr-08 12:03:00 435.0613098 262.0278931 15.20285702 60.3572197 72.93862915 11.80545044 58.471176116-Apr-08 12:04:00 437.0655823 262.0063782 15.19050789 60.3572197 72.96609497 11.80736637 58.471176116-Apr-08 12:05:00 438.1196899 261.9848633 15.17815971 60.3572197 72.99356079 11.8092823 58.471176116-Apr-08 12:06:00 437.3983459 259.4915466 15.19631958 60.3572197 73.02102661 11.81119728 58.471176116-Apr-08 12:07:00 437.7727661 255.5671844 15.21499729 60.3572197 73.04850006 11.81331253 58.471176116-Apr-08 12:08:00 435.8303528 251.642807 15.23367405 60.3572197 73.07596588 11.81721783 58.471176116-Apr-08 12:09:00 436.2947998 247.7184448 15.25235176 60.3572197 73.1034317 11.82112408 58.481529216-Apr-08 12:10:00 435.605957 243.7940674 15.27102852 60.3572197 73.13089752 11.82502937 58.508537316-Apr-08 12:11:00 434.2902527 243.0948639 15.28970623 60.3572197 73.16577148 11.82893562 58.535545316-Apr-08 12:12:00 434.664978 242.3956604 15.30838394 60.3572197 73.20178223 11.83284187 58.562557216-Apr-08 12:13:00 435.1112366 241.6964722 15.3270607 60.3572197 73.23779297 11.83674717 58.589565316-Apr-08 12:14:00 434.6522217 240.9972687 15.34573841 60.3572197 73.27380371 11.84065342 58.616573316-Apr-08 12:15:00 434.9267578 240.2980652 15.36441517 60.3572197 73.30981445 11.84455967 58.643581416-Apr-08 12:16:00 434.881134 239.5988617 15.38309288 60.3572197 73.3458252 11.84846497 58.670589416-Apr-08 12:17:00 434.3313904 238.8996735 15.40176964 60.3572197 73.38183594 11.85237122 58.697601316-Apr-08 12:18:00 436.7283325 238.20047 15.42044735 60.3572197 73.41784668 11.85627651 58.724609416-Apr-08 12:19:00 435.9979248 237.192627 15.43912506 60.3726692 73.45386505 11.86018276 58.751617416-Apr-08 12:20:00 435.682251 235.7526703 15.45780182 60.4388809 73.48987579 11.86408901 58.778625516-Apr-08 12:21:00 436.033844 234.3127136 15.47647953 60.5050926 73.52588654 11.86799431 58.805633516-Apr-08 12:22:00 436.7140198 232.872757 15.49515629 60.5713043 73.56189728 11.87190056 58.832645416-Apr-08 12:23:00 436.0026855 231.4328156 15.513834 60.637516 73.59790802 11.87580681 58.859653516-Apr-08 12:24:00 436.3587341 229.9928589 15.53251076 60.7037277 73.63391876 11.8797121 58.886661516-Apr-08 12:25:00 436.0233154 228.5529022 15.52234554 60.7699394 73.6699295 11.88401031 58.913669616-Apr-08 12:26:00 432.976593 227.1129456 15.49664879 60.8361511 73.70594025 11.88860893 58.940677616-Apr-08 12:27:00 432.081543 225.7521515 15.47095203 60.9023628 73.74195099 11.89320755 58.967689516-Apr-08 12:28:00 433.2088623 226.6867218 15.44525528 60.9685745 73.77796173 11.89780617 58.994697616-Apr-08 12:29:00 434.8688049 227.6213074 15.41955853 61.0347862 73.8139801 11.90240479 59.011352516-Apr-08 12:30:00 435.2862854 228.5558929 15.39386177 61.1009979 73.84999084 11.9070034 59.0113525Page 5 of 10PI Load DataTagName: 4spuw501g4AAHF901Q-PV 4AAHP901A 4AAHT901A 4AAHF902Q-PV 4AAHP903A 4AAHT902ATagExplanation: Unit Load NH3 Flow NH3 Pressure NH3 Temp SO3 Injection SO3 Pressure SO3 TempTagUnits: Mwe16-Apr-08 12:31:00 433.7262878 229.5953827 15.36816502 61.1672096 73.85372925 11.91160202 59.011352516-Apr-08 12:32:00 434.2936401 231.1021576 15.34246826 61.2334213 73.85250854 11.91620064 59.011352516-Apr-08 12:33:00 433.942688 232.6089478 15.31677151 61.2996368 73.85128784 11.92079926 59.011352516-Apr-08 12:34:00 433.8384094 234.1157227 15.29107475 61.3658485 73.85006714 11.92539787 59.011352516-Apr-08 12:35:00 433.8969116 235.6225128 15.265378 61.4320602 73.84884644 11.92999649 59.011352516-Apr-08 12:36:00 433.1186829 237.1292877 15.23968124 61.4623337 73.84762573 11.93459511 59.011352516-Apr-08 12:37:00 434.5530701 238.6360626 15.21398449 61.4893417 73.84640503 11.93919373 59.011352516-Apr-08 12:38:00 434.1334229 240.1428528 15.18828773 61.5163536 73.84518433 11.94379234 59.011352516-Apr-08 12:39:00 432.7113037 241.6496277 15.16259098 61.5433617 73.84396362 11.94839096 59.011352516-Apr-08 12:40:00 432.2003479 243.1564178 15.13689423 61.5703697 73.84274292 11.95298958 59.011352516-Apr-08 12:41:00 433.9078064 244.3762054 15.16378784 61.5973778 73.84152222 11.9575882 59.011352516-Apr-08 12:42:00 433.7860718 244.1610565 15.2132206 61.6243858 73.84030151 11.96218681 59.011352516-Apr-08 12:43:00 435.422821 243.9458923 15.2626543 61.6513977 73.83908081 11.96678543 59.011352516-Apr-08 12:44:00 436.353241 243.7307434 15.31208706 61.6784058 73.83786011 11.97138405 59.011352516-Apr-08 12:45:00 436.7131958 243.5155945 15.35137177 61.7054138 73.8366394 11.97583771 59.011352516-Apr-08 12:46:00 435.4263611 243.3004456 15.36021233 61.7324219 73.8354187 11.9760952 59.011352516-Apr-08 12:47:00 434.6446228 243.0852814 15.36905289 61.7594299 73.834198 11.97635269 59.011352516-Apr-08 12:48:00 434.5072937 242.8701324 15.37789249 61.7864418 73.83297729 11.97661018 59.011352516-Apr-08 12:49:00 434.2885742 242.6549835 15.38673306 61.8134499 73.83175659 11.97686768 59.023647316-Apr-08 12:50:00 434.0037231 242.4398346 15.39557362 61.8404579 73.83053589 11.97712517 59.055728916-Apr-08 12:51:00 436.7503967 242.2246704 15.40441322 61.867466 73.84254456 11.97738266 59.087806716-Apr-08 12:52:00 437.162384 242.0095215 15.41325378 61.894474 73.85658264 11.97764015 59.119884516-Apr-08 12:53:00 435.191925 241.7943726 15.42209435 61.9214859 73.87062073 11.97789764 59.151962316-Apr-08 12:54:00 433.0250854 241.5792236 15.43093395 61.948494 73.88465881 11.97815418 59.184040116-Apr-08 12:55:00 433.6222534 241.3640747 15.43977451 61.975502 73.8986969 11.97841167 59.216117916-Apr-08 12:56:00 435.3617859 241.1489105 15.44861412 62.0070648 73.91273499 11.97866917 59.248195616-Apr-08 12:57:00 434.7361755 240.9337616 15.45745468 62.0390396 73.92677307 11.97892666 59.280273416-Apr-08 12:58:00 434.5601196 240.7186127 15.46629524 62.0710144 73.94081116 11.97918415 59.312351216-Apr-08 12:59:00 434.629364 240.5034637 15.47513485 62.1029892 73.95484924 11.97944164 59.34442916-Apr-08 13:00:00 434.6495056 240.2882996 15.48397541 62.134964 73.96888733 11.97969913 59.376506816-Apr-08 13:01:00 434.2292175 240.0731506 15.49281597 62.1669426 73.98292542 11.97995663 59.408584616-Apr-08 13:02:00 436.2332764 239.8580017 15.50165558 62.1989174 73.9969635 11.98021412 59.440662416-Apr-08 13:03:00 437.6320496 239.6428528 15.51049614 62.2308922 74.01100159 11.98047161 59.472740216-Apr-08 13:04:00 436.556366 239.4276886 15.5193367 62.262867 74.02503967 11.9807291 59.50481816-Apr-08 13:05:00 434.3485718 239.2125397 15.52817631 62.2948418 74.03907776 11.9809866 59.536895816-Apr-08 13:06:00 433.2133179 239.8158112 15.53701687 62.3268204 74.05311584 11.98124409 59.568973516-Apr-08 13:07:00 433.1695557 240.645462 15.54885006 62.3587952 74.06716156 11.98150158 59.601051316-Apr-08 13:08:00 434.8060303 241.4750977 15.57401848 62.39077 74.08119965 11.98175907 59.633129116-Apr-08 13:09:00 434.605011 242.3047485 15.5991869 62.4227448 74.09523773 11.98201656 59.665206916-Apr-08 13:10:00 435.6647949 243.1343842 15.62435436 62.4547195 74.10927582 11.98871422 59.697284716-Apr-08 13:11:00 435.7287903 242.8682556 15.64952278 62.4866943 74.14394379 11.99654865 59.729362516-Apr-08 13:12:00 434.6690369 242.5025177 15.67469025 62.5186729 74.18178558 12.00438213 59.761440316-Apr-08 13:13:00 434.570343 242.1367645 15.69985867 62.5506477 74.21962738 12.01221657 59.793518116-Apr-08 13:14:00 434.6812439 241.7710266 15.72502708 62.5826225 74.25746918 12.020051 59.824916816-Apr-08 13:15:00 435.1380005 241.4052887 15.75019455 62.6145973 74.29531097 12.02788544 59.8544464Page 6 of 10PI Load DataTagName: 4spuw501g4AAHF901Q-PV 4AAHP901A 4AAHT901A 4AAHF902Q-PV 4AAHP903A 4AAHT902ATagExplanation: Unit Load NH3 Flow NH3 Pressure NH3 Temp SO3 Injection SO3 Pressure SO3 TempTagUnits: Mwe16-Apr-08 13:16:00 434.0342407 241.0395355 15.77536297 62.6465721 74.3331604 12.03571987 59.88397616-Apr-08 13:17:00 433.8223877 240.6737976 15.80053139 62.6785507 74.3710022 12.04355431 59.913505616-Apr-08 13:18:00 433.8587646 240.3080444 15.82569885 62.7105255 74.40884399 12.05138874 59.943035116-Apr-08 13:19:00 434.9757996 239.9423065 15.85086727 62.7425003 74.44668579 12.05922318 59.972564716-Apr-08 13:20:00 435.5482483 239.5765686 15.87603569 62.7744751 74.48452759 12.06705761 60.002094316-Apr-08 13:21:00 435.4282227 239.2108154 15.90120316 62.8152046 74.52236938 12.07489204 60.031623816-Apr-08 13:22:00 435.2010193 238.8450775 15.92637157 62.8673859 74.56021118 12.08272552 60.061153416-Apr-08 13:23:00 435.7992249 238.3765869 15.95153904 62.9195671 74.59806061 12.09055996 60.09068316-Apr-08 13:24:00 436.0648804 237.325882 15.96228409 62.9717484 74.6359024 12.09839439 60.120212616-Apr-08 13:25:00 435.4533386 236.275177 15.96778393 63.0239296 74.6737442 12.10622883 60.149742116-Apr-08 13:26:00 435.4606323 235.2244568 15.97328281 63.0761108 74.711586 12.11406326 60.179271716-Apr-08 13:27:00 436.0298462 234.1737518 15.97878265 63.1282883 74.7494278 12.1218977 60.208801316-Apr-08 13:28:00 435.039093 233.1230469 15.98428249 63.1804695 74.78726959 12.12973213 60.238330816-Apr-08 13:29:00 434.3394165 232.0723419 15.98978233 63.2326508 74.82511139 12.13756657 60.267856616-Apr-08 13:30:00 433.2451172 232.1931305 15.99528122 63.284832 74.86296082 12.145401 60.297386216-Apr-08 13:31:00 434.3241577 232.5206604 16.00078201 63.3370132 74.85900879 12.15323544 60.326915716-Apr-08 13:32:00 433.243103 232.848175 16.0062809 63.3891945 74.84863281 12.16106892 60.356445316-Apr-08 13:33:00 433.5264587 233.175705 16.01177979 63.4413719 74.83825684 12.16890335 60.385974916-Apr-08 13:34:00 434.0490112 233.5032349 16.01728058 63.4935532 74.82788086 12.17673779 60.415504516-Apr-08 13:35:00 434.7831116 233.8307495 16.02277946 63.5457344 74.81750488 12.18270016 60.450008416-Apr-08 13:36:00 433.9864197 234.1582794 16.02827835 63.5979156 74.80712891 12.1885643 60.506671916-Apr-08 13:37:00 433.9345398 234.4858093 16.03377914 63.6500969 74.79675293 12.19442844 60.563331616-Apr-08 13:38:00 433.6928101 234.813324 16.03927803 63.7022781 74.78637695 12.20029259 60.619995116-Apr-08 13:39:00 433.3004761 234.9768524 16.04477882 63.7544556 74.77600098 12.20615578 60.676654816-Apr-08 13:40:00 433.7406616 235.0232239 16.05027771 63.8066368 74.765625 12.21201992 60.733318316-Apr-08 13:41:00 434.9515991 235.0695953 16.0557766 63.8588181 74.75524902 12.21788406 60.789981816-Apr-08 13:42:00 436.262085 235.1159668 16.06127739 63.9109993 74.74487305 12.22374821 60.846641516-Apr-08 13:43:00 436.3038025 234.724762 16.06677628 63.9613953 74.73449707 12.22961235 60.903305116-Apr-08 13:44:00 435.7704163 234.174469 16.07227516 64.0016785 74.72412109 12.23547554 60.959964816-Apr-08 13:45:00 434.7592468 233.6241608 16.07777596 64.0419617 74.71374512 12.24133968 61.016628316-Apr-08 13:46:00 436.5238647 233.0738525 16.08327484 64.0822449 74.70336914 12.24720383 61.07328816-Apr-08 13:47:00 436.2750244 232.5235443 16.08877563 64.1225357 74.69299316 12.25306797 61.129951516-Apr-08 13:48:00 435.9187622 231.9732361 16.06996346 64.1628189 74.68261719 12.25893116 61.18661516-Apr-08 13:49:00 436.4724426 231.4229279 16.03378868 64.2031021 74.67224121 12.2647953 61.243274716-Apr-08 13:50:00 436.0433655 230.8726196 15.99761295 64.2433853 74.66186523 12.27065945 61.299938216-Apr-08 13:51:00 435.2854919 230.3223114 15.96143818 64.2836685 74.66841888 12.27652359 61.356597916-Apr-08 13:52:00 434.4343567 229.7720032 15.92526245 64.3239517 74.67757416 12.28238773 61.413261416-Apr-08 13:53:00 434.6598511 229.2216949 15.88908768 64.3642426 74.68672943 12.28825092 61.469921116-Apr-08 13:54:00 435.4151917 228.671402 15.85291195 64.4045258 74.6958847 12.29411507 61.523124716-Apr-08 13:55:00 435.3465271 228.1210938 15.81673622 64.444809 74.70503998 12.29997921 61.550132816-Apr-08 13:56:00 434.3699341 227.5707855 15.78056145 64.4850922 74.71419525 12.30584335 61.577140816-Apr-08 13:57:00 433.605835 229.6492767 15.74438572 64.5253754 74.72335052 12.31170654 61.604152716-Apr-08 13:58:00 432.2946777 233.2497101 15.7148304 64.5656586 74.7325058 12.31757069 61.631160716-Apr-08 13:59:00 433.016449 236.8501434 15.71175289 64.6059418 74.74166107 12.32343483 61.658168816-Apr-08 14:00:00 433.4447021 239.4274292 15.70867538 64.6462326 74.75081635 12.32459545 61.6851768Page 7 of 10PI Load DataTagName: 4spuw501g4AAHF901Q-PV 4AAHP901A 4AAHT901A 4AAHF902Q-PV 4AAHP903A 4AAHT902ATagExplanation: Unit Load NH3 Flow NH3 Pressure NH3 Temp SO3 Injection SO3 Pressure SO3 TempTagUnits: Mwe16-Apr-08 14:01:00 434.3851929 238.935318 15.70559788 64.6865158 74.75997162 12.32575607 61.712184916-Apr-08 14:02:00 434.0552368 238.4432068 15.70252037 64.726799 74.76912689 12.32691574 61.739196816-Apr-08 14:03:00 434.5846252 237.9510956 15.75179577 64.7630997 74.77828217 12.32807636 61.766204816-Apr-08 14:04:00 434.5515442 237.4589844 15.8128252 64.7768326 74.78743744 12.32923698 61.793212916-Apr-08 14:05:00 434.6186829 236.9668884 15.87385464 64.7905655 74.79659271 12.33039761 61.820220916-Apr-08 14:06:00 435.9538574 236.4747772 15.93488312 64.8042984 74.80574799 12.33155823 61.84722916-Apr-08 14:07:00 437.2676086 235.982666 15.99591255 64.8180313 74.81490326 12.33271885 61.874240916-Apr-08 14:08:00 437.635437 235.4905548 15.99972916 64.8317642 74.82405853 12.33387852 61.901248916-Apr-08 14:09:00 438.9372864 234.7046509 15.98447514 64.8454971 74.83321381 12.33503914 61.92825716-Apr-08 14:10:00 438.3526306 233.8669281 15.96922112 64.85923 74.84236908 12.33619976 61.95526516-Apr-08 14:11:00 436.534729 233.0291901 15.95396805 64.872963 74.84941101 12.33736038 61.982273116-Apr-08 14:12:00 434.5409851 232.191452 15.93871403 64.8866959 74.85612488 12.338521 62.00928516-Apr-08 14:13:00 433.5317688 231.353714 15.92346001 64.9004364 74.86283875 12.33968163 62.03629316-Apr-08 14:14:00 434.9345398 231.9495392 15.90820599 64.9141693 74.86955261 12.34084129 62.061752316-Apr-08 14:15:00 433.9707031 232.7983246 15.89295197 64.9279022 74.87626648 12.34200191 62.075485216-Apr-08 14:16:00 434.0032043 233.64711 15.8776989 64.9416351 74.88298035 12.34316254 62.089218116-Apr-08 14:17:00 433.3186646 234.4959106 15.86244488 64.955368 74.88969421 12.34397602 62.10295116-Apr-08 14:18:00 435.3312683 235.344696 15.84719086 64.969101 74.89640808 12.34216309 62.116687816-Apr-08 14:19:00 436.4073181 236.1934967 15.83193684 64.9828339 74.90312195 12.3403492 62.130420716-Apr-08 14:20:00 435.6235352 237.0422821 15.81668282 64.9965668 74.90983582 12.33853626 62.144153616-Apr-08 14:21:00 434.0952759 237.8910828 15.80142975 65.0102997 74.91654968 12.33672333 62.157886516-Apr-08 14:22:00 433.0118713 238.7398682 15.78617573 65.0240326 74.92326355 12.33490944 62.171619416-Apr-08 14:23:00 433.0957947 239.427124 15.7775774 65.0376968 74.92997742 12.3330965 62.185352316-Apr-08 14:24:00 434.0318909 239.9031525 15.77161121 65.050972 74.93669128 12.33128262 62.199089116-Apr-08 14:25:00 435.3411865 240.3791656 15.76564503 65.0642471 74.94340515 12.32946968 62.21282216-Apr-08 14:26:00 436.6771545 240.8551788 15.75967884 65.0775223 74.95011902 12.32765675 62.226554916-Apr-08 14:27:00 436.2824402 241.331192 15.7537117 65.0907974 74.95684052 12.32584286 62.240287816-Apr-08 14:28:00 436.1531677 241.8072052 15.74774551 65.1040726 74.96355438 12.32402992 62.254020716-Apr-08 14:29:00 435.1925659 242.2832184 15.74177933 65.1173477 74.97026825 12.32221603 62.267753616-Apr-08 14:30:00 433.1036987 242.7592468 15.73581314 65.1306229 74.97698212 12.3204031 62.281486516-Apr-08 14:31:00 433.4858093 243.197113 15.7203207 65.143898 74.96359253 12.31859016 62.295223216-Apr-08 14:32:00 434.2953491 243.1010284 15.70106316 65.1571732 74.94711304 12.31677628 62.308956116-Apr-08 14:33:00 436.1575012 243.0049591 15.68180561 65.1704559 74.93063354 12.31496334 62.322689116-Apr-08 14:34:00 437.6812134 242.9088745 15.66254807 65.1837311 74.91415405 12.31314945 62.337970716-Apr-08 14:35:00 436.2010498 242.8127899 15.64900303 65.1970062 74.89767456 12.31133652 62.364978816-Apr-08 14:36:00 435.9092407 243.0323639 15.63703728 65.2102814 74.88119507 12.30952358 62.391986816-Apr-08 14:37:00 434.8735046 243.8381348 15.62507153 65.2235565 74.86471558 12.30770969 62.418998716-Apr-08 14:38:00 433.6095276 244.6439056 15.61310673 65.2368317 74.84823608 12.30589676 62.446006816-Apr-08 14:39:00 433.6141052 245.4496765 15.60114098 65.2501068 74.83175659 12.30408287 62.473014816-Apr-08 14:40:00 434.4309692 246.2554626 15.58545494 65.263382 74.8152771 12.30226994 62.500022916-Apr-08 14:41:00 435.7801514 247.0612335 15.5575428 65.2766571 74.79878998 12.30109787 62.527030916-Apr-08 14:42:00 435.7179565 247.8670044 15.52963066 65.2899323 74.78231049 12.30697918 62.554042816-Apr-08 14:43:00 435.5449219 248.6727905 15.50171852 65.3032761 74.76583099 12.31286049 62.581050916-Apr-08 14:44:00 435.8653564 249.4785614 15.47380638 65.317009 74.7493515 12.3187418 62.608058916-Apr-08 14:45:00 433.901062 250.2843323 15.44589424 65.3307419 74.73287201 12.32462406 62.635067Page 8 of 10PI Load DataTagName: 4spuw501g4AAHF901Q-PV 4AAHP901A 4AAHT901A 4AAHF902Q-PV 4AAHP903A 4AAHT902ATagExplanation: Unit Load NH3 Flow NH3 Pressure NH3 Temp SO3 Injection SO3 Pressure SO3 TempTagUnits: Mwe16-Apr-08 14:46:00 431.5426331 251.0901184 15.41798306 65.3444748 74.71639252 12.33050537 62.66207516-Apr-08 14:47:00 431.6590576 256.1773682 15.39007092 65.3582077 74.69991302 12.33638668 62.689086916-Apr-08 14:48:00 431.7606201 262.3349915 15.36215878 65.3719406 74.68343353 12.34226799 62.71609516-Apr-08 14:49:00 434.1001892 263.8719482 15.33424664 65.3856735 74.66695404 12.3481493 62.74310316-Apr-08 14:50:00 434.6000671 262.9208069 15.3063345 65.3994064 74.65047455 12.35403156 62.770111116-Apr-08 14:51:00 435.5601807 261.969696 15.31736565 65.4131393 74.65727234 12.35991287 62.797119116-Apr-08 14:52:00 435.1201782 261.0185547 15.34137726 65.4268723 74.66764832 12.36579418 62.82413116-Apr-08 14:53:00 434.6263123 260.0674133 15.36538887 65.4406128 74.67802429 12.37167549 62.851139116-Apr-08 14:54:00 434.8359375 259.1163025 15.38940144 65.4543457 74.68840027 12.3775568 62.879680616-Apr-08 14:55:00 434.3360901 259.4258423 15.41341305 65.4680786 74.69877625 12.38343906 62.919834116-Apr-08 14:56:00 436.8847656 260.0184021 15.43742466 65.4818115 74.70915222 12.38932037 62.959991516-Apr-08 14:57:00 436.4177246 260.6109619 15.46143627 65.4955444 74.7195282 12.39520168 63.00014516-Apr-08 14:58:00 435.6152954 261.2035217 15.48544884 65.5092773 74.72990417 12.40108299 63.040298516-Apr-08 14:59:00 436.4721985 261.7960815 15.48716831 65.5230103 74.74028015 12.4069643 63.080455816-Apr-08 15:00:00 435.2984009 262.3886414 15.45038128 65.5367432 74.75065613 12.41284657 63.120609316-Apr-08 15:01:00 435.2206421 262.9812012 15.4135952 65.5504761 74.7610321 12.41872787 63.160762816-Apr-08 15:02:00 434.2391357 263.573761 15.37680912 65.564209 74.77140808 12.42460918 63.200920116-Apr-08 15:03:00 434.6383362 264.1663208 15.34002304 65.5799103 74.78178406 12.42892647 63.241073616-Apr-08 15:04:00 434.0901794 264.7588806 15.30323696 65.6067429 74.79216003 12.43072796 63.281227116-Apr-08 15:05:00 434.0350342 265.3514099 15.26645088 65.6335754 74.80253601 12.4325304 63.321384416-Apr-08 15:06:00 436.8982239 265.9439697 15.2296648 65.6604156 74.81291199 12.43433189 63.361537916-Apr-08 15:07:00 435.8693237 266.5365295 15.19287872 65.6872482 74.82328796 12.43613338 63.401691416-Apr-08 15:08:00 434.2478638 267.1290894 15.15609264 65.7140808 74.83366394 12.43793488 63.441844916-Apr-08 15:09:00 434.9160156 267.7216492 15.11930656 65.740921 74.84403992 12.43973637 63.482002316-Apr-08 15:10:00 434.4587708 268.314209 15.08252048 65.7677536 74.85441589 12.44153786 63.522155816-Apr-08 15:11:00 433.9008484 268.860321 15.04573441 65.7945938 74.84733582 12.4433403 63.562309316-Apr-08 15:12:00 435.3187866 268.8953857 15.00894833 65.8214264 74.83757019 12.44514179 63.602466616-Apr-08 15:13:00 434.5072937 268.9304504 14.97216225 65.848259 74.82780457 12.44694328 63.642620116-Apr-08 15:14:00 434.3595581 268.9655151 14.93537521 65.8750992 74.81803894 12.44874477 63.682773616-Apr-08 15:15:00 434.8124695 269.0005493 14.89858913 65.9019318 74.80827332 12.45054626 63.722930916-Apr-08 15:16:00 434.6334839 269.035614 14.86180305 65.9287643 74.79850769 12.45234871 63.763084416-Apr-08 15:17:00 435.5151672 269.0706787 14.82501698 65.9556046 74.78874207 12.4541502 63.776817316-Apr-08 15:18:00 435.7738037 269.1057434 14.82966137 65.9824371 74.77897644 12.45595169 63.790550216-Apr-08 15:19:00 433.8206177 269.1408081 14.84811592 66.0092773 74.76921082 12.45775318 63.804283116-Apr-08 15:20:00 434.9914551 269.1758728 14.86656952 66.0361099 74.75944519 12.45955467 63.818016116-Apr-08 15:21:00 435.9111328 269.2109375 14.88502407 66.0629425 74.74967957 12.46135616 63.83174916-Apr-08 15:22:00 436.2628479 269.2460022 14.90347862 66.0897827 74.73991394 12.46315861 63.845485716-Apr-08 15:23:00 434.0539551 269.2810669 14.92593765 66.1166153 74.73014832 12.4649601 63.859218616-Apr-08 15:24:00 434.5645142 269.3161316 14.95071507 66.1434479 74.72038269 12.46471882 63.872951516-Apr-08 15:25:00 435.3734131 269.3511963 14.97549248 66.1702881 74.71061707 12.46337891 63.886684416-Apr-08 15:26:00 437.6091919 269.386261 15.00027084 66.1971207 74.70085144 12.46203804 63.900417316-Apr-08 15:27:00 437.0577393 269.2433472 15.02504826 66.1854172 74.69108582 12.46069813 63.914150216-Apr-08 15:28:00 435.3792114 268.8512268 15.04982567 66.1716843 74.68132019 12.45935822 63.927883116-Apr-08 15:29:00 433.1975098 268.459137 15.07460308 66.1579514 74.67155457 12.45801735 63.941616116-Apr-08 15:30:00 434.6284485 268.0670471 15.09938145 66.1442184 74.66178894 12.45667744 63.955349Page 9 of 10PI Load DataTagName: 4spuw501g4AAHF901Q-PV 4AAHP901A 4AAHT901A 4AAHF902Q-PV 4AAHP903A 4AAHT902ATagExplanation: Unit Load NH3 Flow NH3 Pressure NH3 Temp SO3 Injection SO3 Pressure SO3 TempTagUnits: Mwe16-Apr-08 15:31:00 435.7937012 267.6749573 15.12415886 66.1304855 74.65995789 12.45533657 63.969085716-Apr-08 15:32:00 435.8847656 267.2828369 15.14893627 66.1167526 74.65934753 12.45399666 63.982818616-Apr-08 15:33:00 434.4614868 266.8907471 15.17371368 66.1030197 74.65873718 12.45265579 63.996551516-Apr-08 15:34:00 433.8053589 266.4986572 15.19849205 66.0892868 74.65812683 12.45131588 64.010284416-Apr-08 15:35:00 434.519165 266.1065369 15.22326946 66.0755539 74.65751648 12.44997501 64.024017316-Apr-08 15:36:00 434.5734253 265.714447 15.24804688 66.061821 74.65690613 12.4486351 64.037750216-Apr-08 15:37:00 433.9528503 265.3223572 15.27282429 66.0480804 74.65629578 12.44729424 64.0377502Page 10 of 10

# APPENDIX E

FUEL INFORMATION

# E-1

BUNKERING INFORMATIONTONS BUNKEREDPERCENT BLENDStandardPet CokePolk ResidStandardPet CokePolk Resid04/15/200818:05-18:25A Scale5096780B Scale58661Total109512880130384.0%9.8%6.1%04/15/200820:15-20:20A Scale12620B Scale13123Total25743030085.7%14.3%0.0%04/16/20080:35-0:57A Scale435589B Scale440559Total87511318100687.0%11.2%1.8%04/16/20085:11-5:25A Scale3604812B Scale36845Total728931283387.4%11.2%1.4%04/16/200810:39-10:55A Scale38850B Scale3995626Total7871062691985.6%11.5%2.8%04/16/200817:05-17:40A Scale5537463B Scale47253Total102512763121584.4%10.5%5.2%OVERALL TONS BUNKERED & % BLEND4767610199557685.5%10.9%3.6%

# E-2

FUEL ANALYSIS

## Laboratory Services
5012 Causeway Blvd * Tampa Fl. 33619 * Ph (813)630-7378 * Fax (813)630-7360 * DOH #E54272 Report For: 

## Laboratory ID: AA90279

Date and Time Collected: Sampled By: 

### Sample Information

ASG Description: 

### Location Code: 05/27/2008 Report Date:

Big Bend 4 Compliance 

### TE_BB_4_COMP_COAL

Project Account Code:
09/12/2007 Date of Sample Receipt: Sample Collection Method: 

### Laboratory Results 09/11/2007 12:00:00 AM

Result PARAMETER Qualifier Code Test Method Analyst Units Upper Limit MDL Violation Check Analysis Date & Time Lower Limit

60 Mesh Residual Moisture, Coal % ASTM D-5142 KAPXJ 4.28 0 9/19/2007 11:26:00 A M

Ash, as Received % 0.01 ASTM D-3174 KAPXJ 8.91 0 9/20/2007 11:10:00 A M

Ash, Dry Basis % 0.01 ASTM D-3174 KAPXJ 9.95 0 9/20/2007 11:10:00 A M

BTU, as Received BTU/Lb 100 ASTM D-5865 KAPXJ 11769 0 9/20/2007 11:09:00 A M

BTU, Dry Basis BTU/Lb. 100 ASTM D-5865 KAPXJ 13139 0 9/20/2007 11:09:00 A M

BTU, Moisture-Ash Free BTU/Lb. 100 ASTM D-5865 KAPXJ 14591 0 9/20/2007 11:10:00 A M

Carbon, as Received % 0.5 ASTM D-5373 KASZS 66.81 09/26/2007 9:46:00 AM

Carbon, Dry Basis % 0.5 ASTM D-5373 KASZS 74.59 09/26/2007 9:46:00 AM

Chlorine as Cl, as Received % 0.01 ASTM4208/300 KASZS 0.15 09/26/2007 9:51:00 AM

Chlorine as Cl, Dry Basis % 0.01 ASTM4208/300 KASZS 0.17 09/26/2007 9:51:00 AM

Hydrogen, as Received % 0.14 ASTM D-5373 KASZS 4.33 09/26/2007 9:46:00 AM

Hydrogen, Dry Basis % 0.14 ASTM D-5373 KASZS 4.83 09/26/2007 9:46:00 AM

Nitrogen, as Received % 0.10 ASTM D-5373 KASZS 1.41 09/26/2007 9:46:00 AM

Nitrogen, Dry Basis % 0.10 ASTM D-5373 KASZS 1.57 09/26/2007 9:46:00 AM

NOx emission rate, lb/mmB tu lb/mmBtu EPA RM-7E KARAM 0.07 09/19/2007 9:06:00 AM

NOx emission rate, lbs/hr lbs/hr EPA RM-7E KARAM 305 09/19/2007 9:06:00 AM

Oxygen, as Received % ASTM D-5373 KASZS 5.04 09/26/2007 9:46:00 AM

Oxygen, Dry Basis % Calculated KASZS 5.63 09/26/2007 9:46:00 AM

Particulate Wt., Acetone Beaker, Run 1 mg 0.0001 E PA Method 5B/1 7 KARAM 15.45 09/19/2007 9:06:00 AM

Particulate Wt., Acetone Beaker, Run 2 mg 0.0001 E PA Method 5B/1 7 KARAM 14.80 09/19/2007 9:06:00 AM

Particulate Wt., Acetone Beaker, Run 3 mg 0.0001 E PA Method 5B/1 7 KARAM 15.25 09/19/2007 9:06:00 AM

Particulate Wt., Filter/Thimble, Run 1 mg 0.0001 E PA Method 5B/1 7 KARAM 4.25 09/19/2007 9:06:00 AM

Particulate Wt., Filter/Thimble, Run 2 mg 0.0001 E PA Method 5B/1 7 KARAM 2.65 09/19/2007 9:06:00 AM

Particulate Wt., Filter/Thimble, Run 3 mg 0.0001 E PA Method 5B/1 7 KARAM 3.15 09/19/2007 9:06:00 AM

Particulate Wt., Total Sample, Run 1 mg 0.0001 E PA Method 5B/1 7 KARAM 19.70 09/19/2007 9:06:00 AM

Particulate Wt., Total Sample, Run 2 mg 0.0001 E PA Method 5B/1 7 KARAM 17.45 09/19/2007 9:06:00 AM

Report Number: Page 1 of 2 "General Report" AA90279-052708-09
All of the results presented in this r eport pertain to results for sample AA90279

## Laboratory Services
5012 Causeway Blvd * Tampa Fl. 33619 * Ph (813)630-7378 * Fax (813)630-7360 * DOH #E54272

Result PARAMETER Qualifier Code Test Method Analyst Units Upper Limit MDL Violation Check Analysis Date & Time Lower Limit
Particulate Wt., Total Sample, Run 3 mg 0.0001 E PA Method 5B/1 7 KARAM 18.40 09/19/2007 9:06:00 AM

PM, lb/mmBtu lb/mmBtu EPA RM-5/17 KARAM 0.01 09/19/2007 9:06:00 AM

Pounds SO2 / Million BTU Lbs. SO2/MMBTU Calculated KAPXJ 4.71 0 9/19/2007 12:57:00 P M

SO2 emission rate, lbs/hr lbs/hr EPA - RM6C KARAM 1445 09/19/2007 9:06:00 AM

SO2 emission rate, lbs/mmBtu lbs/mmBtu EPA - RM6C KARAM 0.34 09/19/2007 9:06:00 AM

Sulfur, as Received % 0.02 ASTM D-4239 KAPXJ 2.92 0 9/20/2007 11:09:00 A M

Sulfur, Dry Basis % 0.08 ASTM D-4239 KAPXJ 3.26 0 9/20/2007 11:09:00 A M

Total Moisture % 0.1 ASTM D-3173 KAPXJ 10.43 0 9/20/2007 11:08:00 A M


### Comments

Ray McDarby,

Manager, Laboratory Services All results calculated on a wet to wet basis, unless otherwise indicated.
Should there be any questions regar ding this report, please contact:

(813) 630-7878 For Peggy Penner,

Report Number: Page 2 of 2 "General Report" AA90279-052708-09
All of the results presented in this r eport pertain to results for sample AA90279

# APPENDIX F

TEST PARTICIPANTS

## TEST PARTICIPANTS

ENVIRONMENTAL, HEALTH, & SAFETY AIR SERVICES GROUP – TEST TEAM Jorge Varino Environmental Technician – Team Lead Gary Barber Associate Technician Scott Given Associate Technician Ryan Newell Associate Technician

RM-320 FTIR Gary Barber Associate Technician

PROCESS DATA Julie Ward Associate Engineer – Environmental, Health, & Safety R.A. McDarby Senior Environmental Technician

FUEL ANALYSIS Patrice Jackson Envi ronmental Technician Sam Soth Environmental Technician

PARTICULATE LABORATORY Sam Soth Environmental Technician

SUPPORTING DATA COLLECTION AND ANALYSIS R.A. McDarby Senior Environmental Technician

PROJECT QUALITY OBJECTIVES & REPORTING R.A. McDarby Senior Environmental Technician Robert J. Kricks, Ph.D. Principal – RJK Consulting (Spectra & Method)

TEST COORDINATION Julie Ward Associate Engineer – Environmental, Health, & Safety David A. Smith Coordinator – Air Services Group