# EPA Registration Jacket 87284

‐ 1

# PYX. )mGULATORYCONSULTING, AC.

4110 136 1h 

### St. NW

Gig Harbor, WA 98332



### COURIER DELIVERY



### Shaja 

## B. Joyner (PM 20)

Document Processing Desk (FNL LBL)



### Office of Pesticide Programs (7504P)

U.S. Environmental Protection Agency

Room S-4900, One Potomac Yard

2777 S. Crystal Drive



### Arllngtoo, V A 22202



### RE: Willowood Propiconazoie, LLC Decemher21,2010

Willowood Propiconazole Technical (EPA File Symbol 87284-1)



### Submission of Final Product Labeling

Dear Dr. Joyner, Phone: 253-853-7369



### Fax: 253-853-5516

www.PyxisRC.com



### On behalf of WiJlowood Propiconazoie, LLC please find the enclosed final product labeling for

Willowood Propiconazoie Technical.

In support of this submission, we submit the following documents:

I. 

### Completed Application for Registration (EPA Form 8570-1)



### 2. Two (2) copies of the Willowood Propiconazole Technical final product labeling

3. Letter of Authorization

Please fee! free to contact me by phone at (253)**853~7369** 

### or by email atAnn@PyxisRC.comifyou have

any questions or need any additional information.

Sincerely,

# a..1,~

Ann M. Tillman

Enclosures , , > ) , )



## , ,

,

) 

## "

, ) )



## , ,

. " »



## ,

)J , ) ) 

## , , , > , • , >



## ,

"



## , ,

> "



## ,

, 

## , ) 

### .,

# '" ,., 

# " ,

, .. II nURf.lO**~,** 

# ......•.

United 51110' 

# §

Registration opp Id.nlifi" Numb.r 

# &EPA Environmental Protection Agency Amendment

Wnhlngton, DC 20460 

### .f 

## Other

Application for Pesticide

R 

## Section I

1, Comp.nyIProduc! Numbe, 2. EPA Product Menager 3, Propol8d Cf.uific.lion



### '87234-.1 S. Joyner 

# DNone 

# o

R"lricled

4. Company/Product (Nomoi PM,

Willowood Ptopiconazole, LLClWiliowood Propiconazole Technical 

### 20

5. Nome and Addr

.. s 01 Applic.ml ("'crudll ZIP Cod., 

### 6. Expedited Reveiw. In accordance with FIFRA Section 3(c)(3)

Willowood PropiConazole, LLC Ibj(i), mv product is similar or identical (n composition and (abellng

clo**Pyxj~** Regulatory Consulting. Inc. 

### to: 4110 13'61h SI. NW

Gig Harbor, WA98332 

### EPA Reg. No. 

# D

Ch,ck ff thfll /Q' n.w ,ddr'$S 

### Product Name



## Section

R 

## II



# 0 Amendment

- Exploin b.low. 

# l:::::J Fin.1 printed l.b.ls in rep.onus to 

### 12/10/2010 Agoncy lettar dat.d 

# C ROlubminion in rupon

.. to Agancy I.tt.r dated 

# 0 "M. Too" Applioetion.



# 0 Notific8tlon· Explain balow. 

# 0 Other· Explein bolow.

Explanation: Ure edditional pag.(11 If noc

.... ry. IFor •• ctlon I and Section 11.1

Submission of final prinJed labet



## Section

- III

1. Mllerlal ThJ. Product Will Be Peckeged In:

Child·Resistent P.ck.ging Unit Packaging Wat.r Soluble Packoging 2. Type of Contoin.r 

# By" BY" 

# El Y., 

# Er''''

No No No Plntic

Glus



### • CsrtificIItJon mUSr If -Yo- No. por If "Y.s" No. p.r Pap.r

Unit Pock aging wgt. contain.r Packag. wgt con1a1nsr Other (Specify! 

### btl 

### $ubmitt«l



# ,

3. Looatl(.', of NO! ConlOn" Informelion 4. Size(sJ R.toil Contain.r 

# 15.

Location of L.b.1 Oir.ctions 

# Il U Contain.r 

# t:::::1

On Lab.1

L.b,1 .• On**~.b.llno** K;ComlMnylng pr<>el"CI

6. Minner in Which Lab,1 il Affixed to Product UUthograph 

# 0 Oth.r 

## ,

, ) J , " , Paper p;U.d 

# ,

St.nci ed



## • Section

- IV 

## , ,



# ,

, 

## "

1. Contoct Point**(Comp~t'** Items direcfly below for fdentificwtiofl of ffldividutl! fa be coflfwcfed, if fI'C-.nary. to procc,$!J1t!i.J**:Jpp1iC8tiofl.!~ -~**  

### , )" NDfl., TItle T .'/ephoM No. 1f""lulle**AI~.** Code}

Ann Tillman Agent 

### (2S3:)

# :~53"**736~,** ':



# -

Certification ' , ; , 

# I**~.** Oste :'-'ppIMltion

I c.rtify th" the et.tem.nts I h.vo mlKlo on this form.nd ,llattachm.nte th.reto ar. tru., eccurata and complt;t.,).' ).**R~"Yed'** I acknowl.dge th.t any knowlinglly f.lse or misl.eding Itat.m.nt may be punilhebl. by Jine or imprieorvTlent or**(SP,"'.F~J:t1** both under applicabl.l.w.

2. Sign.twi 

# 12 3. TItI. "



## ,

# JhM~ , " Agent

... Typed N

....... 5, Oat • 

# )c2 

# /ol..o 

# /J {)

Ann Tillman



# .. EPA F",:m 8570·' IRev. 3-941 Pr • ...,oul .dltlonl ar. ob.oleta, wtJha • EPA 

### Fa. Copy**I~J** 

### Vdow • 

### APfII<*d CopyWILLOWOODPROPICONAZOLETECHNICALFORUSEINFORMULATINGFUNGICIDESONLYACTIVEINGREDIENT:Propiconazole:1-[(2-(2,4-dichlorophenyl)-4-propyJ-1,3-dioxolao-2-yJjmelhylj-1Hi,2,4--traizole......................................................99.0%OTHERINGREDIENTS.............................,........1.0%TOTAl........................100.0%KEEPOUTOFREACHOFCHILDRENWarning/AvisoSiuslednoentiendelaetiqueta,busqueaalguienparaqueselaexp!lqueausleden"'....""".....\"1"'"V""".u"....''''-,... ..,...."""'"'-"P""''''''''''vu'""'<>,.FIRSTAIDIfineyes:•Holdeyeopenandrinseslowlyandgentlywithwaterfor15-20minutes.•Removecontactlenses,ifpresent,afterthefirst5minutes,thencontinuerinsing.•CallaPoisonControlCenterordoctorfortreatmentadvice.Ifonskinor•Takeoffcontaminatedclothing.clothing:•Rinseskinimmediatelywithplentyofwaterfor15minutes.•CallaPoisonControlCenterordoctorfortreatmentadvice.If•Callapoisoncontrolcenterordoctorimmediatelyfortreatmentswallowed:advice.•Havepersonsipaglassofwaterifabletoswallow.•Donolinducevomitingunlesstoldtodosobythepoisoncontrolcenterordoctor.•Do notgiveanythingbymouthtoanunconsciousIfinhaled:•Movepersontofreshair.•Ifpersonisnotbreathing,call911oranambulance,thengiveartificialrespiration,preferablybymouth-to-mouth,ifpossible.•Callapoisoncontrolcenterordoctorforfurthertreatmentadvice.ForMedicalEmergenciescall24HoursaDay1-800-8587378.HavetheproductcontainerorlabelwithyouwhencallingaPoisonControlCenterordoctororIqoinqfortreatment.EPAReg.No.87284-1EPAEst.No.Manufacturedfor:WillowoodPropiconazole,LLC1600NWGardenValleyBlvd.Roseburg,OR97471NetContents:STJi.-f-EMENTSI).ANIMALSWARNING.Causesbuteye""irritailon.Harmfulifswallowed.Donotgetineyesoronclothing.Wearprotectiveeyewear(goggles,faceshieldorsafetyglasses).Washthoroughlyafterhandlingandbeforeeating,drinking,chewinggum,usingtobacco,orusingthetoilet.Removeandwashcontaminatedclothingbeforereuse.ENVIRONMENTALHAZARDSThisproductistoxictofish.Donotdischargeeffluentcontainingthisproductdirectlyintolakes,streams,ponds,estuaries,oceansorpublicwatersunlessinaccordancewiththereqUirementsofaNationalPollutantDischargeEliminationSystem(NPDES)permitandthepermittingauthorityhasbeennotifiedinwritingpriortodischarge.Donotdischargeeffluentcontainingthisproducttosewersystemswithoutpreviouslynotifyingthelocalsewagetreatmentplantauthority.Forguidance,contactyourStateWaterBoardorRegionalOfficeoftheEnvironmentalProtectionAgency.DIRECTIONSFORUSEItisaviolationofFederallawtousethisproductinamannerinconsistentwithitslabeling.Thisproductmayonlybeusedtoformulateend-useproductswiththefollowinguses:(1)Almonds,BananaandPlantain,BerryCropGroup,Carrots,CeleryandLeafPetioleSubgroup,Cereals(Barley,Oats,Rye,Triticale,Wheat),Citrus(Nonbearing),Corn(Field,Pop,Sweet,SeedCropFoliarTreatment),Cranberries(OR,WA,WIonly),Filberts,GrassesgrownforSeed(ID,MN,NE,ORandWAonly),Onions(drybulbandgreen),Peanuts,Pecans,PeppermintandSpearmint,PineappleW'only),Pistachio,Rice,Sorghum,Soybeans,StoneFruit,Strawberry,SugarBet,'SugarcaneSeedPieceDip,TreeNuts,TurfandOmamental,WildRice(MNonly);(2)'''usesforwhichUSEPAhasacceptedtherequireddataand/orcitationsofdatathattheformulatorhassubmittedinsupportofregistration;and (3)usesforexperimentalpurposesthatareincompliancewithU.S.EPAreqUirements.STORAGEANDDISPOSALDonotcontaminatewater,foodorfeedbystorageordisposa!.PESTICIDESTORAGE:Storeinoriginalcontainertightlyclosedandinasafeplace.PESTICIDEDISPOSAl:Disposeofwastesresultingfromtheuseofthisproductonsiteoratanapprovedwasted'lsposalfacility.CONTAINERDISPOSAL:Nonrefillablecontainer.Do notreuseorrefillthiscontainer.Offerthedrumforrecycling,ifavailable.Cleancontainerpromptlyafteremptying.TriplerinseasfollOWS:Emptytheremainingcontentsintoapplicationequipmentoramixtank.Fillthecontainer1/4fuJIwithwater.Replaceandtightenclosures.Tipcontaineronitssideandrollitbackandforth,ensuringatleastonecompleterevolution,for30seconds.Standthecontaineronitsendandtipitbackandforthseveraltimes.Turnthecontaineroverontoitsotherendandtipitbackandforthseveraltimes.Emptyther'insateintoapplicaflonequipmentoramixtankorstorerinsateforlateruseordisposal.Repeatthisproceduretwomoretimes.Pressurerinseasfollows:Emptytheremainingcontentsintoapplicationequipmentoramixtank.Holdthecontainerupsidedownoverapplicationequipmentormixtankorcollectrinsateforlateruseordisposal.Insertpressurerinsingnozzleinthesideofthecontainerandrinseatabout40psiforatleast30seconds.Drainfor10secondsaftertheflowbeginstodrip.WARRANTYSTATEMENTIMPORTANTNOTICE-Sellerwarrantsthatthisproductconformstothechemicaldescriptionandisreasonablyfitforpurposesstatedonthelabelwhenusedinaccordancewiththedirectionsandinstructionsundernormalconditionsofuse;butneitherthiswarranty/1or-any'otherwarrantyofmerChantabilityorfitnessforaparticularpurpose,expressorimplied,extendstotheusecontrarytolabelinstructions,orunderconditionsnotreasonablyforeseeabletoseller,andtotheextentconsistentwithapplicablelaw,buyerassumestheriskofanysuchuse.WILLOWOODPROPICONAZOLETECHNICALFORUSEINFORMULATINGFUNGICIDESONLYACTIVEINGREDIENT:Propiconazole:t-1(2-(2,4-dichlorophenyl}-4-propyl-t,3-dioxolan-2-yIJmelhyl]-1Ht,2.4-lraizoJe..........."..............,',...............99.0%OTHERINGREDIENTS.....................".......................1.0%TOTAL..................................__...............100.0%KEEPOUTOFREACHOFCHILDRENWarning/AvisoSiuslednoenliendelaeliqueta,busqueaalguienparaqueS8JaexpliqueausledendetaUe.(I(youdonotunders;tandthelabel,findsomeonetoexplaini\loyouindetail).FIRSTAIDIfineyes:•Holdeyeopenandrinseslowlyandgentlywithwalerfor15-20minutes.•Removeconlacllenses,ifpresent,afterthefirst5minutes,thencontinuerinsing.•CallaPoisonControlCenterordoctorfortreatmentadvice.Ifonskinor•Takeoff.contaminatedclothing,clothing:•Rinseskinimmediatelywithplentyofwaterfort5-20minutes.•CallaPoisonControlCenterordoctorfortreatmentadvice.If•Callapoisoncontrolcenterordoctorimmediatelyfortreatmentswallowed:advice.•Havepersonsipaglassofwaterifabletoswallow.•Donotinducevom·ltingunlesstoldtodosobythepoisoncontrolcenterordoctor.•Donotgive8flythingbymouthtoanunconsciousoerson.Ifinhaled:•Movepersontofreshair.•Ifpersonisnotbreathing,call911oranambulance,thengiveartificialrespiration,preferablybymouth-to-mouth,ifpossible.•Callapoisoncontrolcenterordoctorforfurthertreatmentadvice.ForMedicalEmergenciescall24HoursaDay1-800-858-7378.HavetheproductcontainerorlabelwithyouwhencallingaPoisonControlCenterordoctororQoinQfortreatment.EPAReg.No.87284-tManufacturedfor:WillowoodPropiconazole,LLC1600NWGardenValleyBlvd.Roseburg,OR9747tEPAEstNo.NetContents:-'.ST1'\TE';lENTSTQANIMALSWARNING.Causessobstal'1lialbutfemporaryeyeirritation.Harmfulifswallowed.Donotgetineyesoronclothing.Wearprotectiveeyewear(goggles,faceshieldorsafetyglasses).Washthoroughlyafterhandlingandbeforeeating,drinking,chewinggum,usingtobacco,orusingthetoile\.Removeandwashcontaminatedclothingbeforereuse.ENVIRONMENTALHAZARDSThisproductistoxictofish.Donotdischargeeffluentcontainingthisproductdirectlyintolakes,streams,ponds,estuaries,oceansorpublicwatersunlessinaccordancewiththerequirementsofaNationalPollutantDischargeEliminationSystem(NPDES)permitandthepermittingauthorityhasbeennotifiedinwritingpriortodischarge.Donotdischargeeffluentcontainingthisproducttosewersystemswithoutpreviouslynotifyingthelocalsewagetreatmentplantauthority.Forguidance,contactyourStateWaterBoardorRegionalOfficeoftheEnvironmentalProtectionAgency.DIRECTIONSFORUSEItisaviolationofFederallawtousethisproductinamannerinconsistentwithitslabeling.Thisproductmayonlybeusedtoformulateend-useproductswiththefollowinguses:(t)Almonds,BananaandPlantain,BerryCropGroup,Carrots,CeleryandLeafPetioleSubgroup,Cereals(Barley,Oats,Rye,Triticale,Wheat),Citrus(Nonbearing),Corn(Field,Pop,Sweet,SeedCropFoliarTreatment),Cranberries(OR,WA,WIonly),Filberts,GrassesgrownforSeed(10,MN,NE,ORandWAonly),Onions(drybulbandgreen),Peanuts,Pecans,PeppermintandSpearmint,Pineapple(1--"only),Pistachio,Rice,Sorghum,Soybeans,StoneFruit,Strawberry,SugarBet.SugarcaneSeedPieceDip,TreeNuts,TurfandOrnamental,WildRice(MNonly);(2)-usesforwhichuSEPAhasacceptedtherequ'IIBddataand/orcitationsofdatathattheformulatorhassubmittedinsupportofregistration;and(3)usesforexperimentalpurposesthatarein-compliancewithU.S.EPArequirements.STORAGEANDDISPOSALDonotcontaminatewater,foodorfeedbystorageordisposal.PESTICIDESTORAGE:Storeinoriginal containertightlyclosedandinasafeplace.PESTICIDEDiSPOSAL:Disposeofwastesresultingfromtheuseofthisproductonsiteoratanapprovedwastedisposalfacility.CONTAINERDISPOSAL:Nonrefillablecontainer.Donotreuseorrefillthiscontainer.Offerthedrumforrecycling,ifavailable.Cleancontainerpromptlyafteremptying.TriplerinseasfollOWS:Emptytheremainingcontentsintoapplicationequipmentoramixtank.Fillthecontainertl4fullwithwater.Replaceandtightenclosures.Tipcontaineronitssideandrollitbackandforth,ensuringatleastonecompleterevolution, for30seconds.Standthecontaineronitsendandtipitbackandforthseveraltimes.Turnthecontaineroverontoitsotherendandtipitbackandforthseveraltimes.Emptytherinsateintoapplicationequipmentoramixtankorstorerinsateforlateruseordisposal.Repeatthisproceduretwomoretimes.Pressurerinseasfollows:Emptytheremainingcontentsintoapplicationequipmentoramixtank.Holdthecontainerupsidedownoverapplicationequipmentormixtankorcollectrinsateforlateruseordisposal.Insertpressurerinsingnozzleinthesideofthecontainerandrinseatabout40psiforatleast30seconds.Drainfor10secondsaftertheflowbeginstodrip,WARRANTYSTATEMENTIMPORTANTNOTICE-Sellerwarrantsthatthisproductconformstothechemicaldescriptionandisreasonablyfitforpurposesstatedonthelabelwhenusedinaccordancewiththedirectionsandinstructionsundernormalconditionsofuse;butneitherthiswarrantynoranyotherwarrantyofmerchantab!iityorfitnessforaparticularpurpose,expressorimplied,extendstotheusecontrarytolabelinstructions,orunderconditionsnotreasonablyforeseeabletoseller,andtotheextentconsistentwithapplicablelaw,buyerassumestheriskofanysuchuse.

# WILLOWOOD PROPICONAZOLE, LLC

4110 136" St. NW Phone: 253-853-7369

Gig Harbor, WA 98332

November 9, 2009

Document Processing Desk (COADR)

Office of Pesticide Programs (7504P)

U.S. Environmental Protection Agency

Room**S~4900,** 

## One Potomac Yard

2777 S. 

## Crystal Drive

Arlington, VA 22202



## To Wbom It 

## May Concern:

RE: Letter of Authorization Fax: 253-853-5516

Please let this letter serve to notify you that Pyxis Regulatory Consulting, Inc. (contact



## information below) is authorized to represent Willowood Propiconazole, LLC (Co. No. pending)

as authorized agent before the U.S. Environmental Protection Agency in all matters regarding

our pesticide registrations and applications for registrations pursuant to the Federal Insecticide,

Fungicide and Rodenticide Act (FIFRA), 7 USC Section 136 

## et seq. Direct all official



## correspondence from EPA 

## to:

Agent:

Pyxis Regulatory Consulting, Inc.

4110 136" St. NW

Gig Harbor, WA 98332

T: (253) 853-7369

F: (253) 853-5516

info@PyxisRC.com



## If you have any questions, please do not hesitate to contact me.



## "

, 

# , Sincerely,

, 

## "

# ~~7- Brian Heinze. 

# b

President

Willowood Propiconazole, LLC

cc; Pyxis Regulatory Consulting, Inc. 

## "

, 

## , 

# ,

J"

, 

## "**r;--~,** 

# Material to

.. J9 added to an e·**~acketlJacket**



# R N Zl12'8 'i 

# -1 

# ego O.

______**~** 

# __ __ D· Lf3'-!O'l7

1. 0 

# Placement within the e-Jacket/jacket: 

# i Default: (chronological, top 

# = newest)

o 

# File Location: (PDF page number, i.e., "before page



# 45")

2. 0 

# Send to Data Extraction contractors this material:

# ~ Newly stamped accepted label

o Notification

o NewCSF

o Other:

__________ ---"

__

3. Attach this coversheet to the top of the material or jacket. It

must be well organized and clipped together, NOT STAPLED.

Then give the material with this coversheet to staff in the

Information Services Center (Room S-4900).



# Reviewer's Name: 

# _..;..L_i S.;:..Q-'--.'J=" ...;;.G..:..:n=e"".5

_____ _



# Division: 

# "ED

Date:

____ .::.J

# '2.:....J/~\ 3.:::.....J..../.:....2_O...::.i 

# 0

______ _

Created September 8, 2008

## U.S. ENVIRONMENTAL

PROTECTION AGENCY EPA Registration. Date of**",.;,.,~~D** sr"r(>.., 

## Office**o~** 

## Pesticide Programs Number: Issuance: 

# "



# .... '"**"~.** Registration Division (7505P)



## \:j Ariel Rios Building 

## 87284-1 

# '.

'" 1200 Pennsylvania Ave., NW 

# DEC 10 2010

Ioj, PRo-1t: 

## Washington, D.C. 20460

NOTICE OF PESTICIDE: Term of Issuance:

----'L. 

## Registration Conditional

_ Reregistration Name of Pesticide Product:

(under FIFRA, as amended) 

## Willowood Propiconazole Technical

Name and Address of Registrant (include ZIP Code):

Willowood Propiconazole, LLC



## 1600 NW Garden Valley BLVD., Suite 130

Roseburg, OR 97471

Note: Changes in labeling diffurillg in substance from that accepted in connection with this registration must be submitted to and

accepted by the Registration Division prior to use of tile label in commerce. In any correspondence on this product always refer to

the above EPA registration number.

On the basis of information furnished by the registrant, the above named pesticide is hereby registcred/reregistered under the

Federal Insecticide, Fungicide and Rodenticide Act. Registration is in no way to be construed as an endorsement or

recommendation of this product by the Agency. In order to protect health and the environment, \he Administrator, on his motion,

may at any time suspend or cancel the registration of a pesticide in accordance with the Act. The acccptance of any name in

connection with the registration ofa product under this Act is not to be construed as giving the registrant a right to exclusive use of

the name or to its use if it has been covered by others.



## This product is conditionally registered in accordance with FIFRA sec. 3 (c) (7) 

## (A)

provided that you:



## I. Submit/cite all data required for the registration! reregistration of your product when

the Agency requires all registrants of similar products to submit data; and submit

acceptable responses required for reregistration of your product under FIFRA section 4.



## 2. Make the following label change: Change the EPA Registration Number to**87284~1.**



## 3. Provide the following as conditions of registration:



## a. OPPTS number 830.6317

- storage stability

- due Aprtl 1,2012

b. OPPTS number 830.6320

- corrosion characteristics due April 1,2012



## 4. Submit one 

## (1) copy of the revised final printed label before the product is released

for shipment.

(Continued) 

# Jf

of

## APp~OVing Offici,l, 

## Date:



# DEC 10 

# 2010

haja

# ~r!J{~anager 20

Fungicide Branch

Registration Division (7504P)

EPA Form b70 6



## -

## Continued from first page EPA Registration. Number 87284-1

If these conditions are not complied with, the registration will be subject to cancellation

in accordance with FIFRA sec. 6(e). Your release for shipment of the product constitutes

acceptance of these conditions.

A stamped copy of the label is enclosed for your records. If you have any questions,

contact Lisa Jones of my team at (703) 308-9424 or jones.lisa@epa.gov.

Enclosure: Stamped copy of label Sincerely,

# U.:.M~**~1jf{.!:irr v/~** 

Product Manager (20)

Fungicidt: Branch

Registration Division (7504P)

November 3, 2010 Product chemistry review

October 5,2010 Acute toxicity review

# WILLOWOOD PROPICONAZOLE TECHNICAL

FOR USE IN FORMULATING FUNGICIDES ONLY

ACTIVE INGREDIENT:

Propiconazole: 1-[(2-(2.4-dichlorophenyl)-4-propyl-1 ,3-dioxolan-2-yIJmethyIJ-1 

### H-1 ,2,4-

traizole

......... , ................... ,"

......................... "'

... "

.................................... "

................. , ..... 99.00/0

OTHER INGREDIENTS....

................ . ...................................................... 1.0%



### TOTAL.

.................. ,. .. "

...... "

.. ........... . ........... ,,'

.......... , ....... 100.0%)



# KEEP OUT OF REACH OF CHILDREN



# Warning/Aviso

Si usted no entiende la etiqueta, busque a alguien para que S8 fa explique a usted en detalle.

(If you do not understand the label, find someone to explain it to you in detail)



# FIRST AID

IF IN EYES: • Hold eye open and rinse slowly and gently with water for 15 -20 minutes.

• Remove contact lenses, If present, after the first 5 minutes. then continue

rinsing.

• Call a Poison Control Center or doctor for treatment advice.

IF ON SKIN OR • Take off contaminated clothing.

CLOTHING: • Rinse skin immediately with plenty of water for 15 -20 minutes.

• Call a Poison Control Center or doctor for treatment advice.

I F SWALLOWED • Call a poison control center or doctor immediately for treatment advice.

• Have person sip a glass of water if able to swallow.

• Do not induce vomiting unless told to do so by the poison control center or

doctor.

• Do not give allY thing by.mouth to an unconscious;person.

IF INHALED 

# • Move person to fresh air.



# • If person is not breathing, call 911 or an ambulance, then give artificial

respiration, preferably by mouth-to-mouth, if possible.

• Call a poison control center or doctor for further treatment advice.

For Medical Emergencies call 24 Hours a Day 1-800-858-7378. Have the product conta'lner or label with 

# I you when calling a Poison Control Center or doctor or going for treatment.

EPA Reg. No. 87284-

Manufactured for:

Willowood Propiconazole, LLC

1600 NW Garden Valley Blvd.

Roseburg, OR 97471

Willowood Propiconazole Technical Label EPA Est. No.

Net Contents:



# ACCEPTED

with COMltlENT8



## In EPA Letter Dated:



# DEClO 2010

Uliltkr the Fedt"t:¥ IA."¢eticide,

FWlpc,hie, am! ltodClltlcide Act,**~** Jlmended, fnr lJ1C peslicide**regilt"'J!'~d** lJ.rn!.et .EPA lkg. No.



### 1

### PRECAUTIONARY STATEMENTS

HAZARD TO HUMANS AND DOMESTIC ANIMALS

WARNING. Causes substantial but temporary eye irritation. Harmful if swallowed. Do not 

### get in eyes

or on clothing. Wear protective eyewear (goggles, face shield or safety glasses). Wash thoroughly after

handling and before eating, drinking, chewing gum, using tobacco, or using the toilet. Remove and wash

contaminated clothing before reuse.



### ENVIRONMENTAL HAZARDS

This product is toxic to fish. Do not discharge effluent containing this product directly into lakes, streams,



### ponds, estuaries, oceans or public waters unless in accordance with the requirements of a National

Pollutant Discharge Elimination System (NPDES) permit and the permitting authority has been notified in

writing prior to discharge. Do not discharge effluent containing this product to sewer systems without

previously notifying the local sewage treatment plant authority, For guidance, contact your State Water

Board or Regional Office of the Environmental Protection Agency.



### DIRECTIONS FOR USE

It is a violation of Federat law to use this product in a manner inconsistent with its labeting,

This product may only be used to formulate end-use products with the following uses:

(1) Almonds, Banana and Plantain, Berry Crop Group, Carrots, Celery and Leaf Petiole Subgroup,

Cereals (Barley, Oats, Rye, Triticale, Wheat), Citrus (Non-bearing), Corn (Field, Pop, Sweet,

Seed Crop Foliar Treatment), Cranberries (OR, WA, WI only), Filberts, Grasses grown for Seed



### (10, MN, NE, OR and WA only), Onions (dry bulb and green), Peanuts, Pecans, Peppermint and

Spearmint, Pineapple (HI only), Pistachio, Rice, Sorghum, Soybeans, Stone Fruit, Strawberry,

Sugar Beet, Sugarcane Seed Piece Dip, Tree Nuts, Turf and Ornamental, Wild Rice (MN only)

(2) uses for which US EPA has accepted the required data and/or citations of data that the

formulator has submitted in support of registration; and

(3) uses for experimental purposes that are in compliance with U.S, EPA requirements.



## STORAGE AND DISPOSAL

Do not contaminate water, food or feed by storage or disposal.

PESTICIDE STORAGE: Store in original container tightly closed and in a safe place.

PESTICIDE DISPOSAL: Dispose of wastes resulting from the use of this product on site or at an

approved waste disposal facility.

CONTAINER DISPOSAL: Nonrefillable conta'iner, Do not reuse or refill this conta'iner. Offer the drum for

recycling, if available. Clean container promptly after emptying. Triple rinse as follows: Empty the

remaining contents into application equipment or a mix tank. Fill the container 1/4 

### full with water. Replace

and tighten closures. Tip container on its side and roll it back and forth, ensuring at least one complete

revolution, for 30 seconds. Stand the container on its end and tip it back and forth several times. Turn the

container over onto its other end and tip it back and forth several times. Empty the rinsate into application

equipment or a mix tank or store rinsate for later use or disposal. Repeat this procedure two more times.

Pressure rinse as follows: Empty the remaining contents into application equipment or a mix tank,

Hold the container upside down over application equipment or mix tank or collect rinsate for later use or

disposal. Insert pressure rinsing nozzle in the side of the container and rinse at about 40 psi for at least

30 seconds. Drain for 10 seconds after the flow 

### begins to drip.



### WARRANTY STATEMENT

IMPORTANT NOTICE -Seller warrants that this product conforms to the chemical description and is

reasonably fit for purposes stated on the label when used in accordance with the directions and

instructions under normal conditions of use; but neither this warranty nor any other**war~nty** 

### of

merchantability or fitness for a particular purpose, express or implied, extends to the use contrary to label

instructions, or under conditions not reasonably foreseeable to seller, and to the extent consistent with

applicable law, buyer assumes the risk of any such use.

Willowood Propiconazole Technical Label 

### 2

## UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

WASHINGTON, D.C. 20460

OCT 5, 2010



## MEMORANDUM OFFICE OF CHEMICAL SAFETY AND

POLLUTION PREVENTION



## Subject: Name of Pesticide Product:

EPA File Symbol: Willowood Propiconazole Technical

87284-R

DP Barcode: 379845

Decision No.: 434097

Action Code: R310

PC Code: 122101 Propiconazole



## From:

To: Masih Hashim, ToxicologistITeam Leader

Technical Review Branch (TRB)

Registration Division (7505P)

Lisa Jones, RM Team 20

Fungicide Branch

Registration Division (7505P)

Applicant: Willowood Propiconazole, LLC

Roseburg, OR 97471

FORMULATION FROM LABEL:

Active IngredientCs):



## 122101 Propiconazole (CAS No. 60207-90-1)

Inert Ingredient(s)/impurity:

Page 1 of3 

## Total: 

## % 

## bywt.

99.0



## ---.LQ

100.0%

### Propiconazole (PC Code 122101)

EPA File Symbol 87284-R



## ACTION REQUESTED: To determine if the cited and proposed products are similar.

RECOMMENDATIONS: The cited and proposed products (#83851-6 and #87284-R) are

substantially similar in toxicity. TRB has no objection to bridging data between them. The Signal

Word is Warning.

The acute toxicity profile for Propiconazole Technical, EPA File Symbol 83851-A, is as follows:

Acute oral toxicity III 

## cited-acceptable MRID 47240707

Acute dermal toxicity 

## IV cited-acceptable MRID 47240708

Acute inhalation toxicity 

## IV cited-acceptable MRlD 47240709

Primary eye irritation II 

## cited-acceptable MRID 47240710

Primary skin irritation 

## IV cited-acceptable MRID 47240711

Dermal sensitization neg cited-acceptable MRlD 47240712

Follovving are the precautionary and fIrst aid statements for this product:

PRODUCT ID #: 87284-1 (for formulation use only)

PRODUCT NAME: Willowood Propiconazole Technical

PRECAUTIONARY STATEMENTS

SIGNAL WORD: WARNING

Hazards to Humans and Domestic Animals:

Causes substantial but temporary eye injury. Harmful if swallowed. Do not get in eyes or on

clothing. Wear protective eyewear*. Wash thoroughly with soap and water after handling and

before eating, drinking, chewing gum, or using tobacco. Remove and 

## wash contaminated

clothing before reuse.

*(goggles, face shield, or safety glasses)

Page 20f3Propiconazole (PC Code 122101)

EPA File Symbol 87284-R



## First Aid:

If in eyes: Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove

contact lenses, if present, after the first 5 minutes, then continue rinsing. Call a poison control

center or doctor for treatment advice.

If swallowed: Call a poison control center or doctor inunediately for treatment advice. Have

person sip a glass of water if able to swallow. Do not induce vomiting unless told to by a poison

control center or doctor. Do not give anything to an unconscious person.

Have the product container or label with you when calling a poison control center or doctor or

going for treatment. You may also contact 1-800-xxx-xxxx for emergency medical treatment

information.

The CSF (dated May 17, 2010) for the proposed product should be reviewed and accepted by

the TRB Chemistry Team.

Additional first aid statements are acceptable (if any).

Page 3 

## on

### DATA EVALUATION RECORD

PROPICONAZOLE

(Willowood Propiconazole Technical)



## STUDY TYPES: Product Identity and Composition (OPPTS**830.15~** 

### Description of Materials Used to Produce the Produ,



### Description of Production Process (830.1620)

Primaiy Reviewer;

Eric B. Lewis, M.S. 

### Discussion of Formation oflmpurities (OPPTS 830.1670)

Preliminary Analysis (OPPTS 830.1700)

Certified Limits (OPPTS 830.1750)

Enforcement Analytical Method (OPPTS 830.1800)

Physical and Chemical Characteristics (OPPTS 830.6302-830.7950)

MRIDs 481039-01 through 481039-05

Prepared for

Registration Division



### Office of Pesticide Programs

U.S. Environmental Protection Agency

One Potomac Yard



### 2777 South Crystal Drive

Arlington, VA 22202

Prepared by



### Toxicology and Hazard Assessment Group

Environmental Sciences Division

Oak Ridge National Laboratory



### Oak Ridge, TN 37831

Task Order No. I-I

Signature:



### Date:

Secondary Reviewers:

Sylvia Milanez, Ph.D., D.A.RT. 

### Signature:

Date:

Robert H. Ross, M.S., Group Leader Signature:



### Date:

Quality Assurance:

Kimberly G. Slusher. M.S.



## Disclaimer

This review may have been altered subsequent to the contractor's signatures above.

Oak Ridge National Laboratory managed and operated by UT-Battelle, LLC.\ for the U.S. Department of Energy

under Contract No. DE-AC05-000R22725.

### Date: November 3, 2010**SUBJEC\J~'** 

### FE\prOduct Chemistry Review of Willowwood Propiconazole TGAI/MUP

### ~**~~\"\{) ,~**  

# "

" 

### FROM: \ in ira airola 

# CAl

_, 

# II

I

## ~ 'efoductChemistryTeam 

# bl75'JV' 11 \ 01 L)

Technical Review Branch 1 Registration Division (7505P)

TO: Erik KrafU Lisa Jones PM 20

Herbicide Branch 1 RD (7505P)

DP BARCODE: D379844

DECISION No.: 434097

Registration Number 

### 1 File Symbol No.: 87284-R

PRODUCT NAME: Willowood Propiconazole Technical

CAS No. 60207-90-1

Molecular weight 342.2

PCC: 122101

REGISTRANT: Willowood Propiconazole, LLC

USE: Herbicide

FOOD USE: Yes [XJ No [ J

MRID Numbers: 481039-01 through 481039-05

INTRODUCTION:

Willowood Propiconazole Technical'ls a TGAI/MUP to be incorporated into EUPs to be used as

herbicides. Group A and Group B data were submitted for the product. Willowood Propiconazole

Technical is substantially similar to Amtide Propiconazole Technical Fungicide (EPA Reg. No. 83851-1).

The primary review for Propiconazole TGAI/MUP was conducted by Oak Ridge National Laboratory Oak

Ridge, TN 37831

SUMMARY OF FINDINGS

1. The registrant has submitted a Confidential Statement of Formula for a basic formulation (dated

5/17/2010) 

### ofWillowood Propiconazole Technical. The proposed nominal concentration of the active

ingredient is 99.0%, based on the five-batch analysis. The product chemistry data submitted

corresponding to guideline 830.1550 (product identity & 

### composition) satisfy the requirements of

40CFR§15B.155 [MRID No. 481039-01J.

2. Certified limits were provided for the active ingredient. The lower certified limit was established by using

the standard certified limits proposed in guideline reference 830.1750. The upper certified limit for the AI

is tOO%. Upper certified limits were proposed for the 'Impurities based on the five-batch analysis. The

product chemistry data submitted corresponding to guideline 830.1750 (certified limits) satisfy the data

requirements of 40CFR§ 158.175 [MRID 481039-01, CSFJ.

3. MSDSs were submitted for all starting materials (except

. The product chemistry data submitted

corresponding to guideline reference 830.1600 (description of material used to produce the product)

satisfy the data requirements of 40CFR§ 158.160 [MRID No. 481039-01 [.

### BARCODE: 0379844; Reg. No./FILE SYMBOL No.: 87284-R; PRODUCT: WiUowood Propiconazole

Technical

. Sufficient details of the process were provided. The product chemistry data submitted

corresponding to guideline reference 830.1620 (description of production process) satisfy the .data

requirements for 40CFR§158.162 [MRID No. 481039-01].

5. The registrant stated that the product contains no known impurities of toxicological concern. The

potential impurities in the product are identified, and their origin and mechanism of formation were

provided. The product chemistry data submitted corresponding to guideline reference 830.1670

(discussion on the formation of impurities) satisfy the data requirements for 40CFR§158.167 [MRIO No.

481039·01 [.

6. The preliminary analysis was performed at ReC Ltd., ZelgJiweg 1, 4452ltingen, Switzerland, under

compliance with the Swiss Ordinance on Good Laboratory Practice. Analytical results were provided for

five batches of the product. The content of active ingredient was determined using HPLC-UV. Moisture

content was determined using Karl Fischer titration. The inorganic impurities were determined using

CIPAC Method MT 29. The data submitted correspond'lng to the guideline reference 830.1700

(preliminary analysis) satisfy the data reqUirements of 40CFR§158.170 [MRIO No. 481039-02].

7. Recovery of active ingredient ranged from an acceptable range of 98.98%

- 99.65%.

Mean Average= 99.39% of Propiconazole ± 0.27%.

8. The enforcement analytical method to determine the content of active ingredient is HPLC-UV. The

method was validated for linearity, accuracy, and precision. The data submitted corresponding to the

guideline reference 830.1800 (enforcement analytical method) satisfy the data requirements of

40CFR§158.180[MRID No. 481039·011.

9. The data subm'itted corresponding to guidelines 830 Series Subgroup B (physical-chemical properties)

do not satisfy the data requirements of 40CFR§158.190. Data gaps were identified for storage stability

and corrosion characteristics [MRID No. 481039-03 through 481039-05[.



### 2

### BARCODE: 0379844; Reg. No. IFILE SYMBOL No.:**87284~R;** 

### PRODUCT: Willowood Propiconazole

Technical

CONCLUSIONS:

1). All product chemistry data submitted for guideline 830 Series group A & 

### group B are acceptable

except

Guideline storage stability and corrosion characteristics

2). The proposed CSF is acceptable and attached.

3). Guideline storage stability and corrosion characteristics testing will need to be conducted.



### 3

### BARCODE: 0379844; Reg. No. IFILE SYMBOL No.: 87284-R; PRODUCI : Willowood Propiconazole

Technical

830.1550. Product identity 

### & composition: (MRID No. 481039-01)

Common Name: Propiconazole

Chemical name (CAS): 1-[[2-{2,4-dichlorophenyl)-4-propyl-1, 3-dioxolan-2-yl]methylj-1-H-1 ,2,4-triazole

(I UPAC): (±)-1-[2-{2 ,4-dichlorophenyl)-4- propyl-1 ,2 -dioxol an-2-yIJmethyIJ-1 H-1 ,2,4-triazole

CAS No.: 60207-90-1

PC Code No.: 122101

Molecular Weight: 342.2

Structural formula:



### c,



# c,



# II

Product Identity and composition 481039..01

830.1600 of materials used to provided.

830.1620 Description of production process, and II

iii

830.1670 of formation of of formation of Ihe 'i" 'pOliti"; 

# w'"

I i

i,

830.1750 Certified limits 481039-01 on results

830.1800 En10rcement analytical melhod 481039-01 I,

I'



### 4

### BARCODE: 

### 0379844; Reg. 

### No. IFILE SYMBOL 

### No.: 87284·R; PRODUCI : Willowood Propiconazole

Technical



### 830 S enes 

### S b u::>group 

### B (Ph I Ch nyslca· emlca 

### IP rope 

### rti 

### es

Table 2: Ph sical and Chemical Pro erties of Willowood Pro iconazole Technical TGAI/MUP

GlN Requirement MRID Status Result or Deficiency

830.6302 Color 481039-05 A Yellow

830.6303 Physical state 481039-05 A Viscous liquid (paste)

830.6304 Odor 481039-05 A Practically odorless

830.6313 Stabifity to normal and 481039-03 A Stable at normal and elevated (54") temperatures.

elevated temperatures,

metals, and metal ions 481039-05 

### W The product is not packaged in metal containers

and is not expected to contact metals or metal ions

during its storage or use.

830.6314 Oxidalion/reduction: 481039-04 A Compatible with water, powdered iron, 10%

chemical incompatibility potassium permanganate, 10% monoammonium

phosphale, and kerosene.

830.6315 Flammability 481039-05 

### W The product is a solid and not expected to be

flammable.

830.6316 Explodabilily 481039-05 

### W The product does not have the chemical bonds or

functional9roups associated with explosive

chemicals.

830.6317 Storage stability G No data submitted

830.63f9 Miscibility 481039-05 NfA The product is not an emusifiable liquid to be diluted

with petroleum solvents.

830.6320' Corrosion characteristics G No data submitted

830.7000 pH 481039-03 A 5.75 (1% aqueous solution)

830.7050 UVNisible absorption 481039-05 A Wavelength; molar absorption:

At pH<:2: 1.150 nm: £= 31326.6

At pH 7: 1.095 nm: E = 29828.4

At pH>10; 0.919 nm; E = 12517.0

830.7100 Viscosity 481039-05 

### W The product is a very viscous liquid at room

1emperature and is not conducive to testing.

830.7200 Melting point 481039-05 NfA The product is a liquid

830.7220 Boiling point 481039-05 A 179"C

830.7300 Density 481039-03 A 1.2961 9/cm3 at 20'C

830.7370 Dissociation constants in 481039-05 

### W The product has no functional groups that would

water (DC) dissociate.

830.7550 Partition coefficient 481039-05 A log P '" 3.37 at 20'C (The Pesticide Manual, 13 th

ed, p. 924)

830.7840 Water solubility 481039-05 A 36 mgll al pH 5-9 and 20·C. Readily soluble in

most organic solvents such as dichloromethane

(>200 gIL), isopropanol and toluene (50- toO gIL)

(The Pesticide Manual,13 th ed, p.924).



### 5

### BARCODE: D379844; 

### Reg. No. 

### IFILE SYMBOL No.: 87284-R; 

### PRODUCT: Willowood Propiconazole

Technical

Table 2: Ph sical and Chemical Pro erties of : Willowood Propiconazole Technical TGAIIMUP

GLN Requirement MRID Status Result or Deficiency

830.7950 Vapor**pr~ssure** 481039-05 A 1.7 X 10- 3 mP 

### at 20"C (The Pesticide Manual,

13'" ed, p. 924)

A 

### = Acceplable; N = unacceptable (see Deficiency); N/A 

### = Not Applicable; G 

### = Data gap; I 

### = In progress or need upgrade; U = Upgrade (additional informalion required); W 

### = waivers



### 830.1800. Enforcement analytical method: The enforcement analytical method to determine the content

of active ingredient is HPLC-UV. Sample chromatograms were provided. The content of the

impurity is determined by Karl-Fischer titration. The content of inorganic impurities as Is

determined by CIPAC Method 

### MT 29. The registrant provided the following details in 

### MRID 481039-02:



### 6

### BARCODE: 0379844; Reg. No. IFILE SYMBOL No.: 87284-R; PRODUCT: Willowood Propiconazole

Technical

HPLC/UV Method

HPLC Conditions

Auto Sampler:

Pump:

Detector:

Column:

Pre-Column:

Eluent A:

Eluent 

### B:

Gradient:

Run time:

Flow Rate:

Injection, Volume:

Detection Wave Length:

Retention Time:

Preparation of Calibration Solutions Merck-Hitachi L-7200

Merck-Hitachi L-71 00

Merck-Hitachi L-7400

Luna Ci8; 250x 4.6mm; 5 J.lm

Phenomenex C1 B (ODS, Octadecyl); 4 x 3 mm

ACNIH 2 

### 01/9

ACf\!

Minutes



### 0

3

B



### 12

12.1



### 30

30 min

0.8 mLfmln

10 

### ilL

230 nm % EluentA % Eluent 

### B



### 50 50

50 50

10 90

10 90

50 50

50 50

Propiconazole: approximately 12.2 min

50.03 mg of Propiconazole (analytical**~t~ndard,** purity 96.7% 

### w/w) were accurately weighed

into a 50 mL volumetric flask and filled up to the mark with acetonitrile to prepare a stock

solution of 967.58 mg/L. Allquots 

### of this stock solution were further diluted with acetonitrile 

### to

prepare standard solutions of 50.31 to 150.9 mglL.

These solutions were used to calibrate the HPLC/UV system.**Prepara~jon** of Sample Solutions

Quantities of about 250 mg of Proplconazole were accurately weighed into 50 mL volumetric

flasks and fllied up to the mark with acetonitrile to prepare solutidns of approximately

5000 mg/L. These solutions were diluted by a factor of 50 (2 TTlL to 100 mL) with acetonitrile

to prepare solutions of approximately 100 mg/L and measured 

### by HPLC-UV to determine the

content, of Propiconazole 'In Propitonazole (technical).

For each batch at least two samples were prepared and measured by HPLC-UV.

The weightings of the test item for the determination of the actjve ingredient In the five

batches are given In Table 3-1, page 20.



### 7

### BARCODE: D379844; Reg. No. IFILE SYMBOL No.: 87284-R; PRODUCT: WiJlowood Propiconazole

Technical

Evaluation 

### of Results (HPLC Method)

Injected samples were quantified by peak areas with reference to the**r~spe~tive** 

### cali?ration

curve. The latter was obtained by correlation of the peak area of the .callbratlon**.,soIUtIO~S** 

### to

their corresponding concentration in' mg/L The correlation 

## was perfonned uSing. 

## a linear

function given below (equation 

### 1). From the calibration curve the concentration 

## x of

propiconazole in an injected sample was 

### calculated by the following equation (1):



## .y-a

x**=~---**



### where

y



### x



### a

b b



# =

=

=



### = (1 )



### Peak area of the Propiconazole In injected sample [counts]

Concentration of Propiconazole in injected sample [mg/LJ

y-axis intercept

Slope

The content of Propiconazo!e in the test item was 

### calculated by the equation (2):

x·100%



### c=

Cl\om 

### (2)



### where



### c = Content of the Propiconazole in the test item [%]

Cnom 

### =

X 

### = 

### Test item concentration in sample solution [mg/L]

. Concentration of Propiconazole in injected sample [mg/L] 

### from equation (1)

Specificity:

The specificity of the analytical method for Propiconazole was verified by the analysis of a blank solution

using GC/FID and HPLC/UV. The chromatograms were compared to those of a test item solution. The

blank chromatogram showed no interferences at the retention time of Propiconazole. Acceptance

criterion: Interferences at the retention time of !he active ingredient should not contribute more than 3% to

the peak area measured for the active ingredient in the sample solution. Thus, the acceptance criterion is

fulfilled.

Linearity:

The linearity of the method was tested by measuring standard solutions of Propiconazole with different

concentrations. 50.03 mg of Propiconazole (analytical standard, purity 96.7% w/w) 

### were accurately

weighed into 50 mL volumetric flasks, and filled up to the mark with acetonitrile to prepare a stock solution

of 967.6 mg/L Aliquots of this stock solution were further diluted with acetonitrile to prepare standard

solutions of 50.3 to 150.9 

## mg/L Results are shown in Figure 1. Acceptance Criteria: The calibration

coefficient should be at leas! 0.99. Thus, the acceptance criterion is fulfilled.

8

### BARCODE: 

### 0379844; Reg. No./FILE SYMBOL No.:**87284~R;** 

### PRODUCT: Willowood Propiconazole

Technical

l'olOOCOOO

12OiJCOCO

lOOOOOGO

&lCC(]c.a •

00_ 

# ,,-

"""" Concentration 

### measured

y '" 

### 79075>: + 

### 257538**R~** '" 0.9988**'--~-.~-.-------------.--.-----'** 

### Figure 1, linearity for method for Propicona20le analysis

Accuracy:

Since the specificity and the precision of the analytical method are within the acceptance criteria, the accuracy

can be expected to be acceptable, as well.

Precision:



### 250.79 mg of Propiconazole (Batch 

### 20061101) were accurately weighed into a 

### 25 mL volumetric flask and filled

up to the mark with acetonitrile to prepare a stock solution of 

### 51 05.8 mg/L. This solution was diluted by a factor

of 

### 50 (2 mL to 

### 100 mL) with acetonitrile to prepare a measurement solution of 

### 110.32 mg/L. Further sample

solutions of 

### 100.20 mg/L, 

### 100.8 mg/L, 

### 100.7 mgfL, and 

### 100.01 mg/L of batch 

### 20061101 were prepared

accordingly. These samples were used to determine the precision. The results are presented in Table 3.

Acceptance Criteria: According to the modified Horwitz equation, the relative standard deviation should not be

more than 

### 1.34% for substances With a concentration of 

### 98.59'% (results for batch 

### 20061101). Thus, the

acceptance criterion is fulfilled,



# •**r~~_'{=<i ~.;,,~**  courr::s**dPl:<;:io::;~~** ..

:'1 <::€44-

::Dre£a7**:O-:J~n:4 ~(I.:.E;;:!,l:;>** **~~;::.;,** 

# •**tb;:;l-~** o::n;:e:-'uD;::l



### ct Fl'I:j::W>;:=o!= ,',:,.g-'l'

1':':l;!.3;2

10J:.on

1',Y,.r.,.;

1':.J.':;'''

1,::U,<)'**:.~o~** iSEl:>4

:.os'!.?

;:.(2.:",**;;C!L~ ~:.m.'"**  S'E.'l:'ani**:::;)'~;'IJ.:n** 

### :%J

Table 3. Precision of method for Propiconazole analysis



### 9

### BARCODE: 0379844; Reg. No. IFILE SYMBOL No.: 87284-R; PRODUCT: Willowood Propiconazole

Technical**DmFi!~:** Method:**Atq~:** l'rhitod;

Sample 

### ID.

lrjj.Vo!.:



# -

"" 

# -



# -

1-



# -**.,~**



# ,



# ""

M \l.wwst0nEZPath2lhojcdi\Aa7()o!.!\In..ta\A114JO_UlUI7Jc2S)1 14_J l.dat**\~Ulh2\Projecu\AS704-1\Metbod\All+J(U\rop~Je_W9.mel** 19.12..2007**~16:S7** 19.12.2.001 !6

..**29:~3** . J I HPLC: LC25

JO Vi;L!; 14

w

### ""~



# ,. " " 'M 

# '"**,~** 11.1 

# "., n.



# - """'



# ....

"""'I

""'"

"'''''



# ,

n, 

# ",



# .,

Figure 2. Chromatogram of Propiconazole Technical (Batch 20061101) used for

quantification and determination of precision

10FormApprovedOMBNo,2070-0060IUNITEDSTATESENVIRONMENTALPROTECTIONAGENCY401MStreet,S.W.WASHINGTON,D.C.20460PaperworkReductionActNotice:Thepublicreportingburdenforthiscollectionofinformationisestimatedtoaverage0.25hoursperresponseforregistrationactivitiesand0.25hoursperresponseforreregistrationandspecialreviewactivities,includingtimeforreadingtheinstructionsandcompletingthenecessaryforms.Sendcommentsregardingtheburdenestimateoranyotheraspectofthiscollectionofinformation,includingsuggestionsforreducingtheburdento:Director,OPPEInformationManagementDivision(2137),U.S.EnvironmentalProtectionAgency,401MStreet,S.W.,Washington,DC20460.Donotsendtheformtothisaddress.'DATAMATRIXDateNov.16,2010EPAReQ.No.lFileSymbolIPagelof8Applicant'sJRegistrant'sName&AddressProductWillowoodPropiconazole,LlCWiUowoodPropiconazoleTechnical1600NWGardenValleyBlvd.Roseburg,OR97471IngredientPropiconazole(CASNo.60207-90-1)GuidelineReferenceNumberGuldelineStudyNameMRIDNumberSubmitterStatusNo"ProductSpecificDataRequirements830.1550ProductIdentityandComposition48103901WillowoodPropiconazole,LlCOWN830.1600DescriptionofMaterialsUsedtoProducethe48103901WiI!owoodPropiconazole,LLCOWNProduct830.1620DescriptionofProductionProcess48103901WillowoodPropiconazole,LLCOWN830.1650DescriptionofFormulationProcessNotReooired1830.1670DiscussionofFormationofImpurities48103901WillowoodPropiconazole,LLCOWN830.1700Preliminary__Analysis48103902830.1750CertifiedLimits48103901WillowoodPropiconazole,LLCOWN830.1800EnforcementAnalvticalMethod48103901WillowoodPropiconazole,LLCOWN830.6302Color48103903WillowoodPropiconazole,LLCOWN830.6303PhvsicalState48103903WillowoodProoiconazole,LLCOWN830.6304Odor48103903WillowoodPropiconazole,LlCOWN830.6313StabilitytoNormalandElevatedTemperatures,48103903WillowoodPropiconazole,LLCOWNDataMetals,andMetalIons48103905WillowoodProoiconazole,llCOWNWaiverSignalureNameandTilleOateAnnM.Tillman,ConsultantNov.16,2010EPAFOIID6570-35(9-97)ElectronicandPaperversionsavailable.SubmitonlyPaperversion.Agenc)'InlernalUseCopyFOffilApprovedOMSNo.2070-0060UNITEDSTATESENVIRONMENTALPROTECTIONAGENCY401MStreet,S.W.WASHINGTON,D.C.20460PapelWorkReductionActNotice:Thepublicreportingburdenforthiscollectionofinformationisestimatedtoaverage0.25hoursperresponseforregistrationactivitiesand0.25hoursperresponseforreregistrationandspecialreviewactivities,includingtimeforreadingtheinstructionsandcompletingthenecessaryforms.Sendcommentsregardingtheburdenestimateoranyotheraspectofthiscollectionofinformation,includingsuggestionsforreducingtheburdento:Director,OPPEInformationManagementDivision(2137),U.S.EnvironmentalProtectionAgency,401MStreet,SW.,Washington,DC20460.Donotsendtheformtothisaddress.DATAMATRIXDateNov.16,2010EPAReg.No.lFileSymbol87284-RIPage;/of8Applicant's/Registrant'sName&AddressProductWi!lowoodPropiconazole,llCWillowoodPropiconazoleTechnical1600NWGardenVaneyBlvd.Roseburg,OR97471I!!gredientNo.60207-90.1)GuidelineReferenceNumberGuidelineStudyNameMRIONumoorSubmitterStalusNol.830.6314Oxidation/Reduction:ChemicalIncompatibility48103904WillowoodPrgpiconazole,llCOWN830.6315Flammability48103905WillowoodPropiconazole,llCOWNWaiver830.631648103905Wi!lowoodProoiconazole,llCOWNWaiver4830.6317StorageStabilityPRN92_55830.6319MiscibilityNotReauired6830.6320CorrosionCharacteristicsPRN92-.55830.6321DielectricBreakdownVoltaaeNot830.7000IpH48103903WiUowoodPropiconazole,llCOWN830.7050UVMsibleAbsQrption48103903Wi!lowoodPrQpiconazole,llCOWN830.7100Viscosity48103905WiUowoodPropiconazole,llCOWNWaiver7830.7200MeltinaPointJMeltinqRanqeNotReg!Jireds830.7220BoilingPointJBoilingRange48103903WillowoodPropiconazole,llCOWN830.7300Density/RelativeDensity/BulkDensity48103903WillowoodProDiconazole,llCOWN830.7370DissociationConstantsinWater48103905WillowoodPropiconazole,llCOWNWaive?SignalureNameandnleo.t.AnnM.Tillman,ConsultantNov.16,2010EPAFOIm8570-35(9-97)EledronicandPaperversionsavailable.SubmilonlyPaperwrsion.AgencyInternalUlieCopyFormApprovedOMSNo,2070·0060UNITEDSTATESENVIRONMENTALPROTECTIONAGENCY401MStreet,S.W.WASHINGTON,D.C.20460PaperworkReductionActNotice:Thepublicreportingburdenforthiscollectionofinformationisestimatedtoaverage0.25hoursperresponseforregistrationactivitiesand0.25hoursperresponseforreregistrationandspecialreviewactivities,includingtimeforreadingtheinstructionsandcompletingthenecessaryforms.Sendcommentsregardingtheburdenestimateoranyotheraspectofthiscollectionofinformation,includingsuggestionsforreducingtheburdento:Director,OPPEInformationManagementDivision(2137),U.S.EnvironmentalProtectionAgency,401MStreet,S.W.,Washington,DC20460.Donotsendtheformtothisaddress.•DATAMATRIXDateNov.16,2010EPAReg.No.lFileSymbol87284-RIPaae30f8Applicant's/Registrant'sName&AddressProductWillowoodPropiconazole,LLCWillowoodPropiconazoleTechnical,1600NWGardenValleyBlvd.Rosebura,OR97471InaredientProoiconazole(CASNo.60207-90·1)GuidelineReferenceNumberGuidelineSludyNameMRIDNumberSubmitterStatusNote830.7520ParticleSize,FiberLength,andDiameterNotRequired6Distribution830.7550PartitionCoefficient(n·octanoVwater),Shake48103905WilloWQodPropiconazole,LLCPLFlaskMethod830.7560PartitionCoefficient(n-octanol/water),See830.7550GeneratorColumnMethod830.7570PartitionCoefficient(n-octanoVwater),See830.7550EstimationbyLiquidChromatography830.7840WaterSolubility:ColumnElutionMethod;48103905WillowoodPropiconazole,LLCPLShakeFlaskMethod830.7860WaterSolubUf!y,GeneratorColumnMethodSee830.7840830.7950VaporPressure48103905WillowoodPropiconazole,LLCPL870.1100AcuteOralToxicity:RatCite-AllPAY870.1200AcuteDermalToxicitv:RatPAY870.1300AcuteInhalationPAYSignalureNameandTIlle0",AnnM.Tillman,ConsultantNov.16,2010EPAForm8570-35(9-97)ElectroniCandPaperversionsavailable.onlyPaperversion.AgencyInternaluseCOpyFormApprovedOMBNo,2070-0060UNITEDSTATESENVIRONMENTALPROTECTIONAGENCY401MStreet,S.W.WASHINGTON,D.C.20460PaperworkReductionActNotice:Thepublicreportingburdenforthiscollectionofinformationisestimatedtoaverage0.25hoursperresponseforregistrationactivitiesand0.25hoursperresponseforreregistrationandspecialreviewactivities,includingtimeforreadingtheinstructionsandcompletingthenecessaryforms.Sendcommentsregardingtheburdenestimateoranyotheraspectofthiscollectionofinformation,includingsuggestionsforreducingtheburdento:Director,OPpEInfonnationManagementDivision(2137),U.S.EnvironmentalProtectionAgency,401MStreet,S.W.,Washington,DC20460.Donotsendthe!formtothisaddress.DATAMATRIXIDateNov.16,2010EPAReg.No.lFileSymbol87284-RI8Applicant'siRegistrant'sName&AddressProductWillowoodPropiconazole,LLCWillowoodPropiconazoleTechnicali1600NWGardenValleyBlvd.Roseburg,OR97471IngredientPropiconazole(CASNo.60207·90·1)GuidelineReferenceNumberGuidelineStudvNameMRIDNumberSubmitterStatusNo'"870.2400prim§ll)'Irritation:RabbitCite-AllPAY870.2500primaryDermalIrritationCite-AllPAY870.2600DermalSensitizationCite-AllPAyPropiconazoleProductSpecificandGenericDataRequirementsWillowoodPropiconazole,LLCwillmakeoffers-to-paytothefollowingcompaniesonthe!propiconazoledatasubmitterstistofSept.30,2010.Cite-AllSvnaentaCropProtectionInc.PAYCite-AllBaverCropScienceLPPAYCite-AllEI.DuPontdeNemoursandPAYCo.Cite-AllIBCManufacturingCo.PAYCite-AllBaverCorp.PAYCite-AllTrovChemicalCorp.PAYCite-AllBASFCorp.PAYSignalureNameandTitleDaleAnnM.Tillman,ConsultantNov.16,2010EPAFOmJ8570·35(9-97)ElectronicandPaperversionsavailable.Submitonly"Paperversion.AgencyInternalUs.CopyFormApprovedOMBNo.20"70-0060UNITEDSTATESENVIRONMENTALPROTECTIONAGENCY401MStreet.S.W.WASHINGTON,D.C.20460PaperworkReductionActNotice:Thepublicreportingburdenforthiscollectionofinformationisestimatedtoaverage0.25hoursperresponseforregistrationactivitiesand0.25hoursperresponseforreregistrationandspecialreviewactivities,includingtimeforreadingtheinstructionsandcompletingthenecessaryforms.Sendcommentsregardingtheburdenestimateoranyotheraspectofthiscollectionofinformation,includingsuggestionsforreducingtheburdento:Director,OPPEInformationManagementDivision(2137),U.S.EnvironmentalProtectionAgency,401MStreet,S.W.,Washington,DC20460.Donotsendtheformtothisaddress.DATAMATRIXDateNov.16,2010EPANo.lFileSvmbol87284-RIPaoesOt8Applicant's/Registrant'sName&AddressProductWillowoodPropiconazole,LLCWillowoodPropiconazoleTechnical1600NWGardenValleyBlvd.Roseburg,OR97471IngredientPr()piconazole(CASNo.60207-90-1).GuidelineReferenceNumberGuidelineSludvNameMRIONumberSubmitterStatusNoteCite-AllTheAndersonsLawnFertilizerPAYDivisionCite-AllMakhteshimChemicalWorksPAYLtd.Cite-AllLovelandProdUcts,Inc.PAYCite-AllNufarmLimitedPAYCite-AllAlbaughInc.PAY.Cite-AllJanssenPMPPAYCite-AllBASFSpark.sLLCPAYCite-AllControlSolutionsInc.PAYCite-AllContechemInc.PAYCite-AllKoo-CoatInc.PAYCite-AllSipmcanAgroUSAInc.PAYCite-AllTessenderloKerleyInc.PAYCite-AllArchWoodProtectionInc.PAYSignatureNamearxfTilleAnnM.Tillman,ConsultantNov.16,2010EPAForm8570-35(9-97)EleclronicandPaperversionsavailable.SubmitonlyPaperversiofl.AgencyInternalUseCopyFormApprovedOMSNo.2070-0060!UNITEDSTATESENVIRONMENTALPROTECTIONAGENCY401MStreet.S.W.WASHINGTON,D.C.20460PaperworkReductionActNotice:Thepublicreportingburdenforthiscollectionofinformationisestimatedtoaverage0.25hoursperresponseforregistrationactiviliesand0.25hoursperresponseforreregistrationandspecialreviewactivities,includingtimeforreadingtheinstruclionsandcompletingthenecessaryforms.Sendcommentsregardingtheburdenestimateoranyotheraspectofthiscollectionofinformation,includingsuggestionsforreducingtheburdento:Director,OPPEInformationManagementDivision(2137),U.S,EnvironmentalProtectionAgency,401MStreet,S.w.,Wash'lngton,DC20460.DonotsendIheformtothisaddress.DATAMATRIXDateNov.16,2010EPANo.lFileSvmbolB7284-RIPoo.Goof8Applicant'sJRegistrant'sName&AddressProductWillowoodPropiconazole,LLCWillowoodPropiconazole Technical1600NWGardenValleyBlvd.Rosebuig,OR97471I_ngredientPropiconazole(CASNo.80207-90-1)_GuiderlneReferenceNumberGuidenneStudyNameMRIDNumberSubmitterSlatusCite-AllDowAQroSciencesLLCPAYCite-AllMakhteshimAganofNorthPAYAmerica,Inc.--Cite-AIIArystaUfescienceNorthPAYAmericaInc.Cite-AllSprayDriftTaskForcePAYCite-AllDiaconTechnolggiesLtd.PAYCite-AllDr.WolmanGmbhPAYCite-AllISKBiocides,Inc.PAYNichinoAmerica,Inc.PAYCite-AllOutdoorResidentialExposurePAYTaskForceCile-AIIAgriculturalReentryTaskpAYForceCite-AllBayerAdvancedpAYSignatureNameandTitleOaleAnnM.Tillman,ConsultantNov.16,2010EPAFOIITI8570-35(9·97)ElectronicandPaperversionsavailable.SUbmitonlyPaperversion.AgencyInlernalUseCopyFormApprovedOMBNo.2070-0060UNITEDSTATESENVIRONMENTALPROTECTIONAGENCY401MStreet,S.W.WASHINGTON,D.C.20460PaperworkRedUctionActNotice:Thepublicreportingburdenforthiscollectionofinformationisestimatedtoaverage0,25hoursperresponseforregistrationactivitiesand0.25hoursperresponseforreregistrationandspecialreviewactivities,includingtimeforreadingtheinstructionsandcompletingthenecessaryforms.Sendcommentsregardingtheburdenestimateoranyotheraspectofthiscollectionofinformation,includingsuggestionsforreducingtheburdento:Director,OPPEInformationManagementDivision(2137),U.S.EnvironmentalProtectionAgency,401MStreet,S.w.,Washington,DC20460.Donotsendtheformtoth'lSaddress.DATAMATRIXDateNov.16,2010EPAReg.No.lFileSymbol87284-RIPage7of8Applicant'slRegistrant'sName&AddressProductWillowoodPropiconazole,LLCWillowoodPropiconazoleTechnical1600NWGardenValleyBlvd.Roseburg,OR97471IngredientPropkonazole(CASNo.60207·90-1)GuidelineReferenceNumberGuidelineStudNameMRIDNumberSubmitterStatusN,toCite-AllZelamLtd.PAY•.Cite-AllSapstainIndustryGroupPAYCite-AllFIFRAEndangeredSpeciesPAYTaskForceLLCCite-AllIrvitaPlantProtectionN.v.PAYCite-AllOsmoseNewZealandPAYCite-AI!ResidentialExposureJointPAYVentureCite-AllSupremeChemicalsofPAYGeorgiaInc.Cite-AllArchWoodProtection(NZ)PAYLtd.Cite-AllAgriculturalHandlersPAYExoosureTaskForceCite-AllArchTreatmentTechnologies,PAYInc.....SignatureNameandTitle0.10d-1,(;,]LAnnM,TIllman,ConsultantNov.16,2010EPAForm8570-35(9·97)ElectronicandPaperversionsavailable.SubmllonlyPapervelSion.AgencyInternalUseCopyFormApprovedOMBNo.2070-0060UNITEDSTATESENVIRONMENTALPROTECTIONAGENCY401MStreet,S.W.WASHINGTON,D.C.20460PaperworkReductionActNotice:Thepublicreportingburdenforthiscollectionofinformationisestimatedtoaverage0.25hoursperresponseforregistrationactivitiesand0.25hoursperresponseforreregistrationandspecialreviewactivities,includingtimeforreadingtheinstructionsandcompletingthenecessaryforms.Sendcommentsregardingtheburdenestimateoranyotheraspectofthiscollectionofinformation,includingsuggestionsforreducingtheburdento:Director,OPPEInformationManagementDivision(2t37),U.S.EnvironmentalProtectionAgency,401MStreet,SW.,Washington,DC20460.Donotsendtheformtothisaddress.DATAMATRIXDateNov.16,2010EPAReg.No.lFileSymbol87284-RIPaaefof8Applicant's/Registrant'sName&AddressProductWillowoodPropiconazole,LLCWillowoodPropiconazoleTechnical1600NWGardenValleyBlvd.Rosebura,OR97471IngredientProoiconazole(CASNo.60207-90-1)GuidelineReferenceNumberGuidelineStudYNameMRIDNumberSubmitterStatusNoteCite-AllU.S.TriazoleTaskForcePAY",Cite-AllGro-ProLLCPAYCite-AllPhoenixEnvironmentalCarePAYLLCCite-AllEti9raLLCPAYCite-AllShardaWorldwideExportsPAYPvt.Ltd.Cite-AllJ.OliverProducts,LLCPAYCite-AllShardaUSALLCPAYCite-AllAmTideLLCPAYCite-AllGenericEndangeredSpeCiesPAYTaskForceCite-AllBerkemDevelopmentPAYCite-AllWillowoodLLCOWNSeeendnote10SignatureNameandTille0."AnnM.Tillman,ConsultantNov.16,2010EPAForm8570-35(9-97)ElectronicandPaperversionsavailable.SubmitonlyPaperversion.Agency[nternalUseCopy

## Endnotes for Data Matrix for Willowood Propiconazole Technical

1 

### 830.1650**~** 

### These data are not required for the registration of a technical grade active ingredient

product. See 830.1620 for production process information.

2 

### 830.6313

_ Willowood Propiconazole, LLC does not package Willowood Propiconazole Technical in

metal containers, nor is Willowood Propiconazole Technical expected to come into contact with metals

or metal ions during its storage or use. Therefore, a waiver from the requirement of these data is

requested. Willowood Propiconazole Technical was found to be stable at normal and elevated

temperatures.

3 

### 830.6315

_ Willowood Propiconazole, LLC requests a waiver from the requirement of this data

requirement since Willowood Propiconazole Technical is a solid and is not expected to be flammable.

Please refer to the Confidential Statement of Formula for Willowood Propiconazole Technical.

4 

### 830.6316**~** 

### Willowood Propiconazole, LLC requests a waiver from this data requirement because

propiconazole does not have the chemical bonds or functional groups associated with explosive

chemicals. Please refer to the Confidential Statement of Formula for Willowood Propiconazole

Technical.

5 

### 830 .6317, 830.6320**~** 

### Per PR Notice**92~5,** 

### storage stability and corrosion characteristics data are not

required to be submitted unless specifically requested by the Agency. Willowood Propiconazole, LLC

agrees to conduct this stUdy if required and requests that the study be made a condition of registration.

s 830.6319, 830.6321, 830.7520

- Willowood Propiconazole Technical is a solid and not an emulsifrable

concentrate and is not to be diluted with petroleum solvents. Therefore, miscibility data are not

required for this technical. Willowood Propiconazole Technical is not to be used around electrical

equipment and data for dielectric breakdown constant are not required. Willowood Propiconazole, LLC

is seeking a waiver for particle size, fiber length and diameter distribution because Willowood

Propiconazole Technical is not water insoluble nor is it a fibrous material.

7 

### 830.7100 • Willowood Propiconazole, LLC requests a waiver from this data requirement because

Willowood Propiconazole Technical is a very viscous liquid at room temperature and is not conducive

to viscosity testing.

8 

### 83 0.7200

_ Willowood Propiconazole Technical is a liquid solid and melting pOint data are not required

for liquids. Data for boiling point are required for liquids. See Guideline 830.7220.

9 

### 830.7370**~** 

### Willowood Propiconazole, LLC is seeking a waiver for this data requirement for Willowood

Propiconazole Technical because the product does not have any functional groups that would

dissociate.

10 

### Willowood, LLC is the parent company for the subsidiary, Willowood Propiconazole LLC and therefore

no offer to pay is required.

Page 

### 1 0'1

### UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

WASHINGTON, D.C. 20460



## June 2, 2010



## PYXIS REGULATORY CONSULTING, INC.

WILLOWOOD PROPICONAZOLE, LLC

4110 1136TH STREET, NW

GIG 

## HARBOR, W A 98332-

Report of Analysis for Compliance with PR Notice 86-5 OFFICEQF

PREVENTION, PESTICIDES AND

TOXIC SUBSTANCES



## Thank you for your submittal of 24-MA Y -10. Our staff has completed a preliminary

analysis of the material. The results are provided as follows:

Your submittal was found to be in full compliance with the standards for submission of

data contained in PR Notice 86-5. A copy of your bibliography is enclosed, annotated with

Master Record ID's (MRIDs) assigned to each document submitted. Please use these numbers in

all future references to these documents. Thank you for your cooperation. If you have any

questions concerning this data submission, please raise them 

## with the cognizant Product

Manager, to whom the data have been released.

## i



# 21-Day Screen Completed by

Contractor

21-Day 

# Expires on

__**G~-/_L(_--,-/_o~_**



# Jacket # 

# R 7 

# z '2'-(

- 

# 12

MRID# '-I 

# '& los <;-



# Content Screen: Recommended to

# ~Fail

86-5 Review: asse fFailedfNA



# Transfer This Jacket to:

# PRIA 2 - 21 Day Content Screen Review Worksheet

(EPAJOPP Use Only)

3/23/09

21 Day Screen Start Date: S-

- 2. 

## 'i' - / ()**~** 

## Experts In-Processing Signature: 

# etC /-/d.te4.I"""'/t:.78N 

## Date 

## .s--Z 7-/" Fee Paid: 

## Yes_V

Division management contacted on issues No Yes Date



## EPA Reg. Number: 

# 9 72. 

# E- '(

- /2. EPA Receipt Date: 

# ::;--2'7"-10

1

2



## 3 Items for Review

Application Form (EPA Form 8570-1)(link to form) signed & 

## complete

including package type

Confidential Statement of Formula all boxes completed, form signed, and

a) All inerts (link to http://www.epa.gov/opprdOOliinerts/),

including fragrances, approved for the proposed uses (see



## Footnote yes no

Certification with Respect to Citation of Data (EPA Form 8570-34) (Link to

form) completed and signed (N/A if 100% repack)

Certificate and data matrix consistent

If applicant is relying on data that 

## are compensable, is the offer

to pay statement included. (see Footnote 

## B)

is a letter of for exclusive use

Formulator's Exemption Statement (EPA Fonn yes no Yes No N/A*



## 4 completed and signed (N/A if source is unregistered or applicant owns the



## 5

6 Data Matrix (EPA Form 8570-35) (Link to form) both internal and external

copies (PR 98-5) (Link to PR 98-5) completed and signed (N/A if 100% 

# X

Selective Method

b) Cite-All (Fee category experts use)

c) Applicant owns all data (Fee category experts use)



## 5 Copies of Label (link to http://www.epa.gov/oppfeadl/labeling/lrmD

(Electronic labels on 

## CD are encouraged and guidance is 

## available)( link to 

# Vhttp://www.epa.gov/pesticides/regulating/registering/submissions/index.htm#Jabels / \

I

## 7 

# X

, 

## Is 

## the data package consistent with PR Notice 86-5 (link 

## to PRN 86-5)

Notice of Filing (link to



## 8 http://www.epa.gov/pesticides/regulating/toleranee petitions.htm) included

# ~ , 

## with petitions (link to

http://www

. epa

. .e;ov /pesficid es/re.e;ula ting/tol eran ces.htm)



## 9 If 

## applicable for conventional applications, reduced risk rationale (link to 

# X

http://www.epa.gov/opprdOOliworkpianireducedrisk.html)

Required Data (link to

h 

## ttn:/ /www.ella.gov/pesticides/regulatin2idafa reguirements.htm) and/or

data waivers. See Footnote C.

a) List study (or studies) not included with application



## 10

2

## Comments:



# iIX)JeS 

# fAsscd fto· S KCDtruJ

{(finiCal 

# and. lfY1yurihl' 00\<j

'N/A

- Not Applicable

Footnotes 

# f'1r<fD LfJI03

A. 

## During the 21 day initial content review, all eSFs will be reviewed to determine

whether all inerts listed, including fragrances, are approved for the proposed uses. 

## If an

unapproved inert is identified, the applicant must either 1) resolve the inert issue by, for

example, removing the inert, substituting it with an approved inert, submitting

documentation that EPA approved the inert for the proposed pesticidal uses, correcting

mistakes on the eSF, etc. or 2) provide the data to support OPP approval of the inert or 3)

withdraw the application. Removing or substituting an inert ingredient will require a new

eSF and may require submission of data. All information, forms, data and

documentation resolving the inert issue must have been received by the Agency or the

application withdrawn within the 21 day period, otherwise, the Agency will reject the

application as described below.

To successfully complete this aspect of the 21 day initial content screen, applicants are

strongly encouraged to verify that all inert ingredients have been approved for the

application's uses even if a product is currently registered by consulting the inert Web



## 3

## site [link to http://www.epa.gov/opprdOOllinertsllists.htmIJ and if the inert is not

approved, to obtain the necessary inert approval prior to submitting an application

to register a pesticide product containing that inert ingredient. Some inert

ingredients are no longer approved for food uses or certain types of uses. The name

and/or CAS number on a CSF must match the name and CAS number on this web site.

Simple typographical errors in the name or CAS number have resulted in processing

delays.

If an inert is not listed on the inert ingredient web site and the applicant believes that the

inert has been approved, the applicant should contact the Inert Ingredient Assessment

Branch (IIAB) at inertsbranch@epa.gov and resolve the issue. Copies of the

correspondence with IIAB resolving the issue should accompany the application. All

new inerts except PIP inerts are reviewed by liAB. The IIAB should also be contacted

for any questions on what supporting data needs to be submitted for and the Agency's

inert review process. Questions on PIP inerts should be directed to the Chief of

Microbial Pesticides Branch [Link to

http://www.epa.gov/oppbppdllbiopesticides/contacts bppd.htmJ.

\\!hen a brand, trade, or proprietary name of an inert ingredient is listed on a CSF,

additional information such as an alternate name of the inert, CAS number or other

infonnation [link to http://www.epa.gov/opprd001/inerts/tips.pdfl must also be included

to enable the Agency to determine if it has been approved. Each component of an inert

mixture (including a fragrance) must be identified. In 

## some cases, the supplier of the

mixture or fragrance may need to provide this information to the Agency. Prior to the

Agency's receipt ofan application, applicants must arrange with a proprietary mixture or

fragrance supplier to provide the component information to the Agency or promptly upon

EPA's request. If the inert ingredients in a proprietary blend (including fragrances)

cannot or are not identified or provided within the 21-day content review period, the

Agency 

## will reject the application.

During the 21 day content review, applicants should submit information to the individual

identified by the Agency when the applicant is informed of an unapproved inert.

Unapproved Inerts Identified on CSFs

All applications except conventional new products and PIPs

Once an unapproved inert is identified on a CSF, the Agency will contact the

applicant with the following options:

1. Correct the application by, for instance, correcting the inert's identity or CAS

number, providing documentation that the inert has been approved, or

removing the unapproved inert from the CSF or replacing it with one that is

approved for the application's uses; or

2. Submit the information and data needed for the Agency to approve the

1Ulapproved inert If this option is selected and implemented, the Agency may

request an extension in the PRIA decision review timeframe to accommodate

the inert review/approval process;

4

## 3. Withdraw the application (the Agency retains 25% of the full fee for the fee

category estimated); or

Ifnone of these options is selected and implemented by the applicant within the

21 day content review period, the Agency will reject the application and retain

25% ofthe full fee of the category identified.

Conventional New Product Applications

When the Registration Division identifies an unapproved inert on a CSF with an

application for a new product that the applicant has not identified as requiring an

inert approval (R311, R312 or R313), it will contact the applicant with the

following options:

1. Correct the application by, for instance, correcting the inert's identity or CAS

number, providing documentation that the inert has been approved, or

removing the unapproved inert from the CSF or replacing it with one that is

approved for the application's uses; or

2. Submit the information and data needed for the Agency to approve the

unapproved inert, including any required petition to establish or amend a

tolerance or exemption from a tolerance. (This option may change the PRIA

category for the application, which could require a longer decision review

time and a larger fee. If additional fees are due, they must be received by the

Agency within the 21 day content review period.)

3. Withdraw the application (the Agency retains 25% of the full fee for the fee

category estimated); or

Ifnone of the above options is selected and implemented during the 2l-day

content-review period, the Agency will reject the application and retain 25% of

the appropriate fee for the new product-inert approval category.

PIP Applications

When the Biopesticide and Pollution Prevention Division identifies an

unapproved inert on a PIP CSF and a request to approve the inert does not

accompany the application, it will contact the applicant with the following

options:

1. Correct the application by, for instance, correcting the spelling or name of the

inert to that in 

## 40 CFR 174, or providing documentation that the inert has been

approved; or

2. Submit the information and data needed for the Agency to approve the

unapproved inert. If an inert ingredient tolerance exemption petition is

required, the petition must be received by the Agency and the B903 fee paid

within the 21 day period. Ifthis option is selected and implemented, the

Agency will discuss harmonizing the timeframe for both actions.

5

## 3. Withdraw the application (the Agency retains 25% of the full fee for the fee

category estimated); or

Ifnone of the above options is selected and implemented during the 21 day

content review period, the Agency will reject the application and retain 25% of

the fee.

B. 

## A policy on documentation of offers to pay is still being developed, however, for a

me-too or fast track (similarlidentical) new product, R300 or A530, an application

without the necessary authorizations of offers to pay will be placed into either R301 or

A531. The Agency recommends that authorizations of offers to pay be submitted with

other PRlA applications to avoid delays in the Agency's decision.



# c. Biopesticide applicants are advised to contact the Agency and discuss study waivers

prior to submitting their application to the Agency. Documentation of such discussions

should be submitted with the study waiver.

6

## j 

# /

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

WASHINGTON, D.C. 20460



## May 26, 2010

OPP Decision Number: D-434097

EPA File Symbol or Registration Number: 87284-R

Product Name: WILLOWOOD PROPICONAZOLE TECHNICAL

EPA Receipt Date: 24-May-201O

EPA Company Number: 87284

Company Name: WILLOWOOD PROPICONAZOLE,



# Ann Tillman

PYXIS REGULATORY CONSULTING, INC.

WlLLOWOOD PROPICONAZOLE, LLC

4110 1136TH STREET, NW

GIG HARBOR, W A 98332- OFFICE OF

PREVENTION, PESTICIDES AND

TOXIC SUBSTA..'1CES



## SUBJECT: Receipt of Application and 50% Small Business Waiver Request

Dear Registrant:

The Office of Pesticide 

## Programs has received your application, 50% small business

waiver request, and cerification of payment. 

## If you submitted data with this application, the

results of the 

## PRN-86-5 screen 

## will be communicated separately. During the administrative

screen, the Office of Pesticide 

## Programs has detennined that this Action is subject to a Pesticide

Registration Service Fee as defined in the Pesticide Registration Improvement Act.

The Action has been identified as Action Code: R310

NEW PRODUCT;NON-FAST TRACK (INCLUDES REVIEWS OF PRODUCT

CHEMISTRY;ACUTE TOXICITY;PUBLIC HEALTH PEST EFFICACY);



## Your request for waiver has been forwarded for review. You will be notified in writing when a

determination is made regarding your request. If your 

## waiver request is approved, the decision

review time period will start on the date of approval. If your 

## waiver request is denied, you will

receive an 

## invoice for the outstanding balance.

If you 

## have any questions, please contact the Pesticide Registration Service Fee

Ombudsman at (703) 305-6249.



## Sincerely,

Front End 

## Pr

lnfonn

.**'!"",y)~** 

## Resources Management Division

## I 

# %

IFee for Servicel 

# (8752469-

This package includes the following

(!) 

# New Registration

°Amendment for Division



# °AD

°BPPD

(!) 

# RD

Receipt No. 

# s-I 875246

EPA File Symbol/Reg. No. 

# I 87284-R

Pin-Punch Date: 

# I 5/24/2010



# D This item is NOT subject to FFS action.

Action eode: 

# II Parent/Child Decisions:

Requested: 

# I iZ- '2, 

# ! 0 

# I

,



# , I

# Il~(O 

# I Granted:

Amount Due: 

# $ L(S}'Y ' 

# ro ! 

# , i

,

,



## Il!i 

# Inert Clea e( for Intended Us @jj 

# Uncleared Inert in Product

Reviewer: 

# !**~\l(~** )**L,{~** Date: 

# Ske-!d

! 

# , Remarks: !



# I

# /

/ Mike Kellogg

From:

Sent:



## To: paygovadmin@maiLdoc.twai.gov

Thursday, May 20,201010:47 AM

Mike Kellogg

Subject: 

### Pay.Goy Payment Confirmation



## THIS IS AN AUTOMATED MESSAGE. PLEASE DO NOT REPLY,



## Your transaction has been successfully completed.

Transaction summary

Application Name: PRIA Service Fees

Pay.gov Tracking 10: 2S8RRQ1A

Agency Tracking 10: 74117488811



## Account Holder Name: Brian Heinze

Transaction Type: Sale

Transaction Amount: $2)289.ee

Billing Address: 8698 Lookingglass Road

City: 

## Roseburg

State/province: OR

Zip/Postal Code: 97471

Country: USA



## Card Type: Master Card

Card Number: ************6885

Transaction Date: May 2a

J 

## 2818 1:46:44 PM

Decision Number:



## Registration Number: 87284-xx

Company Name: Willowood Propiconazole

Company Number: 87284

Action Code: R318

1 , , » "



## , ,

" " , !



### , ,

;'! '



### , 

### , '>'



## , , "



## ,

"

"

, , , >



### ",

;



### , 

## , , ,

# -

.. • 

# , rovo OMRNo 

# , 

# .... "

Ul'Iitod $tollr 

# §

Registration OPP'dol'ltifio' Numb,r 

# oEPA Environmental Protection Agency Amendment**W.~hjn"ton,** OC 204&0 

## Other

Application for Pesticide· Section I

1.**comp.nV~GdIl~t** Numb,r 2. EPA**Produ~1** MOl'lo".r 3, Propo.od Clanificotion



### 87284

- S. Joyner

## ~NOM 

# o

Rutric;tod

4. ComponylProdur;1 !Nlmo) 

# 'M'

Willowood Propiconazo!e. LLCNVillowood Propiconawle Techl'lical 

### 20

s.' Nom, end AddleS, of Apprlcanl (fncludll ZIP Cod" 

### 6. Expedited Reveiw. In accordance with FIFRA Section 3(cH31

Willowaod Propioon;lzole, LLC (bW), my product is similar or identical in composition and labelingc/o Pyxis Rcgula10ry COl'Isullh'lg, InC. to: 

## 83851-6 411013611'1 SI. NW EPA Reg. No. Gig Harbor, WA 98332 

# o

Ch.r;1{ if lhi,,;s II now add,us P d N Amtide Technical Propiconazole

ro uct 

### ame



## Section· II



# 0 Amtlndmonl' Explllln below. 

# U Finol prinled lob,ls in rllpllOnso 10

Agency lotlor dolod 

# 0 RtlSubmiulol'lln rOlponlo 10 AGal'lcy lottor deled 

# 0 -Mil Too" Applicalion.



# .0 NOIi/iealion· Expllin billow. 

# 0 Olher· fxploin bolow.

Explanation: u!O oddllionlll p

.. polftl if nee,nary. IFor soclion I lind Soctlon 11.1

This application falls under Category R310 

### (46: New manufactUfing use product) because it is an application fOI legistration for

a new technical product identical in composition to a currently legisteled product. The fee which is due is 

### $4,578.00 but

Willowood Plopiconazole, LLC is requesting a small business fee reduction of 

### 50% to 

### $2,289. The decision timeline is 

### 6

months.



## Section**~** 

## III

1.**,M.wr'~** ThIto P1oduC1 WIN 

### a. Packaged In:

Child·Rn;;I

.. nl Poekoll,ng Unil "Ickopinp W.I" SOlublo Pock aping 2. Typo 01 Conloine' 

# @Y" @voo**~** V" 

# E]M".r

., N.

., N • 

### N. Plastle

Gloos

I 

### CfNtificlltion 

### must If -Yu" No. por If ·Yos· No. per Peper lined slainless

Unil ".ckaginll wgl. conl,inllr Peckago Wpl conl.iner ./ Olher {Specifyl steel drum Inr 

### submitttHI

I

3. Locolion of Nil Conlllnls Inlormotion 4. Sizolll RIIIOil Contoin

.. 

# !

S. LocOlion 01 Lobel Oirecuonl 

# 1£ 

# U

Conlainor**~Onl.Jlal**



# ..... r

200 liIer

- On Lob.llng • .,.omp_nvIR!l p",duOI

a. Manner in Which Label i, Affixld to Producl 

# lJ

Uthoproph 

# U 0

.... '

J**Pepll~'uod** Slone ed



## Section ·IV

I. Contoct Point (Compl.fo 

### {ferm dincf/y b./ow for id.nfificl1tion of indMdulll to b. conlacflld, ifnocfllIlI.ry. to procellll/hiJI fJPPficllion./

N,amo Till, 

## I Telephone No. lIncludo Arllo Code)

Pyxis Regulatory Consulting. Inc. Agent 

### (253)-853-7369

CertificlJ\lon G. 00111 Appli<lltion

I cortily Ihat Ih, I"tomllnlsi hevo mod. On thlll (orm ond Itll Itt.ehmenlS Ihereto .ro lruo, occuroto ond completo. R.c&ivld



## ,

, 

## "

laeltnowlodgo Ihlt any knowijngl'y foln Or mialoading stolllment moy bll pun/,hoble by fino or imprillorvnont or (StI!l'!'j)eij)

tlOIh under IpplioGblo low. , , , " l



# - . , 2. SiGnature 

# '0

# ~kft 3. Titl, 

### , 

## , •



## , , 

## " ,

Consultant 

## " 

## , , ,

1/'lf1' 

## It,'{_ -<"_- ,"

, 

## , 

## "

, ,



## , , , 

## ,

4. Typod Nllma 5.0al

.. 

### , 

# .5 /d0/.Lci/D 

# .. '



## , , ,

Ann 

### M. Tillman



### , 

## , ,-" " 

# , ,



# .. . •



## - EPA For"" 957G.' IRev. 3 941 PreVIous editions oro OO1010to. Whltl

- EPA Fu. COpy loriglnal)

" " ",



### ,

### \ 

## P**'.<L.~** 

## REGULATORY CONSULT1.

, :'NC.

4110 136 th 

### S1. NW

Gig Harbor, WA 98332



### OVERNIGHT DELIVERY

Shaja B. Joyner (PM 20)

Document Processing Desk (REGFEE)

Office of Pesticide Programs (7504P)

U.S. Environmental Protection Agency

Room 8-4900, One Potomac Yard

2777 S. Crystal Drive

Arlington, VA 22202

RE: Willowood Propiconazole, LLC May 20, 2010

Willowood Propiconazole Technical (EPA File Symbol 87284- )

Application for New Pesticide Registration

Dear Dr. Joyner, 

## 481039'()O

Phone: 253-853-7369

Fax: 253-853-5516

www.PyxisRC.com



### On behalf of Willowood Propiconazole, LLC, we are submitting an application for registration of

Willowood Propiconazole Technical. In support of this application, we submit the following documents:

1. Application for a New Pesticide Registration (EPA Fonn 8570-1)

2. Confidential Statement of Formula (EPA Fonn 8570-4)

3. Three (3) Copies of the Proposed Labeling

4. A CD containing an electronic version of the proposed labeling

5. Certification with Respect to Label Integrity

6. Certification with Respect to Citation of Data (EPA Fonn 8570-34)

7. Agency Internal Use Copy of the Data Matrix

8. Public File Copy of the Data Matrix

9. Documentation of Small Business for PRIA fee reduction

10. Copy ofPRIA payment

II. Letter of Authorization

12. Product Specific Data (3 copies of each report):



## - -'-'



## 48103901 Volume 1 830.1550,830.1600, Tillman, A. M. Product Identity and Composition,**De:su~ption** 

### of

830.1620,830.1670, the 

### Materials Used, Description of the 

### Production Process,

830.1750,830.1800 Discussion of the Formation of Impurities, Certified Limits, and

Enforcement Analytical Method for Willowood Propiconazole

Technical. Con.tains Confidential Business Information.



## 48103802 Volume 2 830.1700,830.1800 Schoop, 

## T. Propiconazole Technical Quantification and



### Identification of the Active Ingredient and 

### Impurities in 

### Five

Batches by Validated Methods.

## 48103903 Volume 3 830.6302,830.6303,



### 830.6304, 830.6313,

830.7000,830.7050,



### 830.7200,830.7300



## 48103904 Volume 4 

### 830.6314



## 48103906 Volume 5 830.6313, 830.6315,

830.6316, 830.6317,

830.6319,830.6320,

830.6321,830.7100,

830.7200,830.7370,

830.7520,830.7550-

7570,830.7840-

7860,830.7950 Wo. 

# c. Willowood Propiconazoie 

### Technical S. 

### Joyner

May 20, 2010

Page 2 of2



## - Physical 

## 'nd

Chemical Characteristics: 

### Color, Physical State, Odor, Stability to

Nannal and Elevated Temperature, pH, UVNisible 

### Absorption,

Boiling point and DensitylRelative Density.

Wo. C. Willowood 

### Propiconazole Technical**~** 

### Physical 

## !md

Chemical Characteristics: OxidationIReduction.



### Tillman, A. 

### M. 

### Willowood Propiconazole Technical Physical

and Chemical Properties and Waiver Requests. Contains



### Confidential Business Information.



### We would like to note that Willowood Propiconazole, LLC is using the cite-all method of support. As

per EPA's interpretations of 40 CFR Parts 152.86(b)(2)(i) and I 52.93(b)(2)(i), Willowood Propiconazole,

LLC submitted notices of intent to apply and offers to pay to all companies on the March 31, 2010 Data

Submitter's List. This action falls under PRIA category R310 (46: New manufacturing use product)

because it is an application for registration for a technical product identical to a currently registered

product. The fee for this action is $4,578, but Willowood Propiconazole, LLC is requesting a 50% PRIA

fee reduction to $2,289. Documentation to support eligibility as a small business is enclosed. The PRIA

fee has been paid. The decision timeline is 6 months.

We trust you will find this application complete. However,**p~ease** 

### feel free to contact me «253) 853-

7369, Ann@PyxisRC.collJ) if you have any**que~ions** 

### or need any additional information.

Sincerely,

Ann M. Tillman

EnclosuresForm Approved ONlB No. 2070-0060 

# @ UN(TED STATES ENV(RONMENTAL PROTECTiON AGENCY

401 M Street, S,W,

WASH(NGTON, D,C. 

### 20460

P.porwork Reduction Act Nottco! The putllc reporting**bLl'd~n** for this colledion**otlnform~tion** ls**~stmilted** to allBrage 1.25 hems per response for mglstnl!ion

a1'ld-D.25 hours per Il!sponse for reregistration and speciall review activrties, indoom9 time for Il!ading the Instructions and complebng the necessary Iorms. Send**comm~nt'lll'!garding** bumenestima!e or any other aaped. ofthls coltt>:c\ion Of Information, Including SU9gestions tor reducing the bLl'den t): Diredor, OPPE**Informa~on Man~ement**  Division (2137), U.S. Environmental Protedion AgenO/, 401 M**SlrlI~l,** S.w.. washington. DC 20400.

Do oot send the completed form to this address.

Certification with Respect to Citation of Data

Applicanl'slRegistranl's Name. Mdress, and Teit!phone Number EPA Registration Number/file Symbol

Wilowood Propiconru:ole, llC clo Pyxis Regulatory 4110 136th SI. NW Gig Harbor. WA 98332, 2H 87284

Active frn!redient(s) ami/or representative res! compound(s) Dale

## "~l~ 

# . ,I,

Propiconazofa

### ~."2-D 

### /d

o

General Use Palem(s) (llsl al those daimed for this produd u:;inp 40 CFR Part 15/l) ProdudName

TGAI Willowood**Proplcona~oleTechnical**

NOTE: It your product Is a 100% repackaging ofanotller purchased EPA.registered prod\JCt labeled for ai the same U1;es on your Iilbel. you do not need to**~ubmit** this form. You musl submit lhe**Formutato~s** Exemption Stiilement (EPA Form 6570-27),



# 0 I am responding to a Dnta.QIlI·tn NoUce, and haw Induded with th's form a list of**companie~** senl offers of compensation (lhe Data MaVix i:lrm Should

be uood i:lr thit! purpose).

SECTION I: METHOD OF DATA SUPPORT (Ched<. one method only)



# 0 tam u:ing the ote-a. methOd of support, and**ha~** Induded with this form 

# 0 I am uslnillhe selecttve method 01 support (Of dIe-ail Option

a fist of canpanies wnt olTers 0( compenli3Uon (the Data Ma1rtx!Orm under the seit!d.illC method), and have incItJded with this fann a

should be used !Or this purpose). completed list ot data**requirem~nts** (the Data Matrix form must be

used),

SECTtON It: GENERAL OFFER TO PAY

[Roquired if using the dte-all method or when using the**dte-~~** option under the selective method to**sa~sly** one or more data reqi.Aremeflls) 

# 0 t hen!by olWr and agree 10 pay compensation, to other peruons, WIth regan:! to thB**~pproVllt** of this application. to the extent roquired by FIFRA.

SECTION til: CERTIFtCATlON

I certify lIlat this apPlication for registration, this form for reregistration, or Ihis Data·Call-ln response is supported by alt data submitted or**c~oo** illhe

applicatton for registration. the form for reregistration, or the Data·Cell-ln**re~onS9,** In**IIdd~ion. ~**  lIle**cite-~n** option orcile·aU oplion under the sek!ctrvc method is

indic:ated 11 Sedion I, this appication is supported by aU data in the Agency's files that (I (concem the properties oreifeds oftlls prodlld or**~n** identical or**subslilntiil~** similar product, or one or more of the ingredients in this product: and (2) is a !)pe of dab that would be required to be iiUbmilted urderthe data

requirements in effed on the dale ofapp1lval ofthjs appliC<ltion if the application sought the inilial regislration 01 a prnduCl of identical or simtla:r composition and**u~e$** .

t oertJfy thaI for each exdu&ive uw study dec:! h sUpport of this reglstrallon or rereglsllatinn,that I am ttl!! originat data SUbmitter or that t**ha~** ohlained

the wrltlen permission of the original data submiHerfo dIe that ztudy_

I certify that for each study cited in so..pport oflhls registration or reregistration that Is not an**exdu~iYe** use study, either:**{~(** t am \he ofiginal dala

submiltef: (b) t have oblained Ihe permission of the originllt data submitter 10 use the study In support ollhis**~pplcation:** (c) an periods of eligibility for**compem;iI~on** have expi'ed for the sludy: {d( tile study (s in the pubic**I~erature;** or (e) t haw notified in writing tho compooy that submitted lhG study and have**o~red** (I) to pay compensation 10 the extent required by sections 3(c)(IHF) ardlor 3(cX2)(B( ofFIFRA: and (ii) to commence negotialions to detl!rmine tie

amount and terms ot compen$aUon, If**a~,** to be paid for the use of the study.

I rertiry tl\(ll m all inslances where an offer of compensation is required, copies ofal olfers to pay compensation and evidence of their delivery In

accordance Wlth sedions 3{c)(1)(F) andlor3(cH2XB) ofFIFRA are available and will be**suhmi~ed** 10 the Agercy upon request. Should I 181t to**~odtJCJ S~'I::n**  '

e1ence to 1I1e Agency upon request, t urdersfand lhat the AI/I!nr:)' may Initiale action to deny, canrel or suspend the regit!lration qfJllJ 

### pry1uct In o:J'ilrp1Jllltv**'~~h** FI RA.



## ,

, , 

# . ,

I C(lr1lfy thaI tllo stllWrJI(Ints t havo made on this form and alt ahchmonts 10 it ilfa truo, aCCUril", and compt(lti. t aCknOwtedgolllllt iltoy

knowlngty fa\$o or mbteadlng statornentma), bo punishabtll by fino Of Imprisonmant or both Und(lf appltcable law. ' ) ; , ) : ;' , , •

, 

### ,

, , " 

# dU/0-**/t(/:1£~** ,. 

# , Signa111nl 

# D"" Typed 0( Printed Namll.n",ljt.,



## , 

# , , ) 

# ';;:(>D/I' Ann M, Trllman. Agent 

## ,

, , 

# ,

c· 

### E A



### e Form 6570·34 9-9 

## n Electmnic ano P erversions awilable Submilonl 

### e, 

# , , erver!Olon, , 

# .

,"



## ,

, 

## , , ,

# WILLOWOOD PROPICONAZOLE, LLC

411O 136" St. NW Phone: 253-853-7369

Gig Harbor, WA 98332

November 9, 2009

Document Processing Desk (COADR)

Office of Pesticide Programs (7504P)

U.S. Environmental Protection Agency

Room 

## SA900, One Potomac Yard

2777 S. Crystal Drive

Arlington, VA 22202



## To Whom It 

## May Concern:

RE: Letter of Authorization Fax: 253-853-5516



## Please let this letter serve to notify you that Pyxis Regulatory Consulting, Inc, (contact

information below) is authorized to represent Willowood Propiconazoie, LLC (Co. No. pending)

as authorized agent before the U.s. Environmental Protection Agency in all matters regarding

our pesticide registrations and applications for registrations pursuant to the Federal Insecticide,

Fungicide and Rodenticide Act (FIFRA), 7 USC Section 136 et seq. Direct all official

correspondence from EPA to:

Agent:



## Pyxis Regulatory Consulting, Inc,

4110136" St. NW

Gig Harbor, W A 98332

T: (253) 853-7369

F: (253) 853-5516

info@PyxisRC.com

Tfyou have any questions, please do not hesitate to 

## contact me.

Sincerely,

# bnz~

President

Willowood Propiconazole, LLC

cc: Pyxis Regulatory Consulting, Inc. , "



## , , 

## , '"

, 

## , 

# "

,

"

, 

## ,

'"



## , , ,,)

.)

,),



### , 

## ",

'FonnApprovedOMSNo.2070-0060UNITEDSTATESENVIRONMENTALPROTECTIONAGENCY401MStreet,S.W.WASHINGTON,D.C.20460PaperworkReductionActNotice:Thepublicreportingburdenforthiscollectionofinformationisestimatedtoaverage0.25hoursperresponseforregistrationactivitiesand0.25hoursperresponseforreregistrationandspecialreviewactivities,includingtimeforreadingtheinstructionsandcompletingthenecessaryforms.Sendcommentsregardingtheburdenestimateoranyotheraspectofthiscollectionofinformation,includingsuggestionsforreducingtheburdento:Director,OPPEInformationManagementDivision(2137),U.S.EnvironmentalProtectionAgency,401MStreet,S.W.,Washington,DC20460.Donotsendtheformtothisaddress.DATAMATRIXDateMav17,2010Applicant's/Registrant'sName&AddressWillowoodPropiconazole,LLC1600NWGardenValleyBlvd.RoseburQ,OR97471InaredientProoiconazole(CASNo.60207-90-tlGuidelineReferenceNumber!GuidelineSludl(NameProductSpecificDataReQuirements830.1550IProductIdentitvandComposition830.1600DescriptionofMaterialsUsedtoProducetheProduct830.1620\DescriptionofProductionProcess830.1650IDescriptionofFormulationProcessMRIONumberVolume1Volume1Volume1830.1670IDiscussionofFormationofImpurities\Volume1830.1700IPreliminaryAnalysisIVolume2830.1750ICertifiedLimitsIVolume1830.1800lEnforcementAnalYticalMethodIVolume1--..VGlwme3EPAReg.No.lFileSymbol87284-Iof8ProductWillowoodPropiconazoleTechnicalSubmitterStatusINoteWillowoodProiconazole,LLCOWNWillowoodPropiconazole,LLCOWNWilJowoodPropiconazole,LLCIOWNNotRequired1WillowoodLLC\OWNWilJowoodPropiconazole,LLCOWNWillowoodProoiconazole,LLCOWNWilJowoodPropiconazole,LLCOWNWillowoodPropiconazole,LLCOWNWiJlowoodPropiconazole,LLCOWN830.6313StabilitytoNormalandElevatedTemperatures,IVolume3 IWillowoodPropicorazole,LLCOWNazole,LLCOWNNameandTilleIMetals,andMetalIons:W"if:JVO!lhl)e5IWilJowoodPropicor..SignatureOate.tLh,(WL.'"AnnM.Tillman,ConsultantMay17,2010EPAForm8570·35(9-97)EleclmnicandPaperversionsavailable.SubmitonlyPaperversion.AgencyInternillUseCopyFormApprovedOMSNo.2070-0060UNITEDSTATESENVIRONMENTALPROTECTIONAGENCY401MStreet,S.W.WASHINGTON,D.C.20460PaperworkReductionActNotice:Thepublicreportingburdenforthiscollectionofinformationisestimatedtoaverage0.25hoursperresponseforregistrationactivitiesand0.25hoursperresponseforreregistrationandspecialreviewactivities,includingtimeforreadingtheinstructionsandcompletingthenecessaryforms.Sendcommentsregardingtheburdenestimateoranyotheraspectofthiscollectionofinformation,includingsuggestionsforreducingtheburdento:Director,OPPEInformationManagementDivision(2137),U.S.EnvironmentalProtectionAgency,401MStreet,S.W.,Washington,DC20460.Donotsendtheformtothisaddress.DATAMATRIXDateMay17,2010EPAReo.No'/FileSymbol87284-IPaoeZof8Applicant's/Registrant'sName&AddressProduct,.WillowoodPropiconazole,LLCWlliowoodProplconazoleTechnical1600NWGardenValleyBlvd.Roseburg,OR97471IngredientPropiconazole(CASNo.60207·90·1)GuidelineReferenceNumberGuidelineStuEY_NameMRIDNumberSubmitterStatusNote830.6314Oxidation/Reduction:ChemicalIncompatibilitvVolume4WillowoodPropiconazole,LLCOWN830.6315FlammabilityVolume5WiliowoodPropiconazole,LLCOWN830.6316ExplodabilityVolume5WillowoodPropiconazole,LLCOWNWaiver4830.6317StorageStabilityPRN92_55830.6319MiscibilityNotReauired6830.6320CorrosionCharacteristicsPRN92_55830.6321Dielectric BreakdownVoltaqeNotRequired6830.7000IpHVolume3WiliowoodPropiconazole,LLCOWN830.7050WNisibleAbsorptionVolume3WiliowoodPropiconazole,LLCOWN830.7100ViscosityVolume5WillowoodPropiconazole,LLCOWNWaiver7830.7200MeltinaPoinUMeltinqRanaeNotRequired6830.7220BoilinqPoinUBoilinqRanaeVolume3WillowoodPropiconazole,LLCOWN830.7300Density/RelativeDensity/BulkDensityVolume3WillowoodPropiconazole,LLCOWN830.7370DissociationConstantsinWaterVolume5WiliowoodPropiconazole,LLCOWNWaiverSignatureNameandTitleOaleAnnM.Tillman,ConsultantMay17,2010EPAForm8570·35(9-97)ElectronicandPaperversionsavailable.SubmUonlyPaperversion.AgencyInternalUseCopyFormApprovedOMSNo,2070-0060UNITEDSTATESENVIRONMENTALPROTECTIONAGENCY401MStreet,S.W.WASHINGTON,D.C.20460PaperworkReductionActNotice:Thepublicreportingburdenforthiscollectionofinformationisestimatedtoaverage0.25hoursperresponseforregistrationactivitiesand0.25hoursperresponseforreregistrationandspecialreviewactivities,includingtimeforreadingtheinstructionsandcompletingthenecessaryforms.Sendcommentsregardingtheburdenestimateoranyotheraspectofthiscollectionofinformation,includingsuggestionsforreducingtheburdento:Director,OPPEInformationManagementDivision(2137),U.S.EnvironmentalProtectionAgency,401MStreet.S.W.,Washington,DC20460.Donotsendtheformtothisaddress.DATAMATRIXDateMay17,2010EPAReo.No.lFile87284·JPaoe3of8AppJicant's/Registrant'sName&AddressProductWillowoodPropiconazole,LLCWillowoodPropiconazoleTechnical1600NWGardenValleyBlvd.Roseburq,OR97471IngredientPropiconazde(CASNo.60207-90-1)GuidelineReferenceNumberGuidelineStudNameMRIDNumberSubmitterStatusNote830.7520ParticleSize,FiberLength,andDiameterNotRequired6Distribution830.7550PartitionCoefficient(n-octanol/water),ShakeVolume5WillowoodPropiconazole,LLCPLFlaskMethod830.7560PartitionCoefficient(n-octanollwater),See830.7550GeneratorColumnMethod830.7570PartitionCoefficient(n-octanol/water),See830.7550EstimationbyJlqLJidChromatQf1@phv830.7840WaterSolubility:ColumnElutionMethod;Volume5WillowoodPropiconazole,LLCPLShakeFlaskMethod830.7860WaterSolubility,GeneratorColumnMethodSee830.7840830.7950VaporPressureVolume5Wrl1owoooPropiconazole,LLCPL870.1100AcuteOralToxictty:RatCite-AllPAY870.1200AcuteDermalToxicitV:RatCite-AllPAY870.1300AcuteInhalationToxicity:RatCite-AllPAYSignatureNameandTilleOateAnnM.Tillman,ConsultantMay17,2010EPAForm8570·35(9-97)ElectroniCandPaperversionsavailable.SubmitonlyPaperversion.AgencyInternalUseCopyFormApprovedOMBNo.2070-0060UNITEDSTATESENVIRONMENTALPROTECTIONAGENCY401MStreet,S,W.WASHINGTON,D.C.20460PaperworkReductionActNotice:Thepublicreportingburdenforthiscollectionofinformationisestimatedtoaverage0.25hoursperresponseforregistrationactivitiesand0.25hoursperresponseforreregistrationandspecialreviewactivities,includingtimeforreadingtheinstructionsandcompletingthenecessaryforms.Sendcommentsregardingtheburdenestimateoranyotheraspectofthiscollectionofinformation,includingsuggestionsforreducingtheburdento:Director,OPPEInformationManagementDivision(2137),U.S.EnvironmentalProtectionAgency,401MStreet,S.W.,Washington,DC20460.Donotsendtheformtothisaddress.DATAMATRIXDateMav17.2010EPAReg.No.lFileSymbol87284-IPag,,4of8Applicant'slRegistrant'sName&AddressProductWillowoodPropiconazole,LLCWillowoodPropiconazoleTechnical1600NWGardenValleyBlvd.Roseburq,OR97471IngredientPropiconazole(CASNo.60207-90-1)GuidelineReferenceNumberGuidelineStudyNameMRIDNumberSubmitterStatusNote870.2400PrimaryEyeIrritation:RabbitCite-AI!PAY870.2500PrimaryDerma!IrritationCite-AllPAY870.2600DermalSensitizationCite-AllPAYProDiconazoleProductSDecificandGenericDataRequirementsWillowoodPropiconazole,LLCwi!Jmakeoffers-to-paytothefollowingcompaniesontheIpropiconazo!edatasubmitterslistofMarch31,2010.Cite-AllSyngentaCropProtectionInc.PAYCite-AllBayerCropScienceLPPAYCite-AllE.l.DuPontdeNemoursandPAYCo.Cite-AllIBCManufacturinaCo.PAYCite-AllBayerCorp.PAYCite-AllTroyChemicalCorp.PAYCite-AI!BASFCorp.PAYSignalureNameandTilleOateAnnM.Tillman,ConsultantMay17,2010EPAForm8570·35(9·97)EleclronicandPaperversionsavailable.onlyPaperversion.AgencyInternalUseCopyFormApprovedOMSNo.2070-0060UNITEDSTATESENVIRONMENTALPROTECTIONAGENCY401MStreet,S.W.WASHINGTON,D,C,20460PaperworkReductionActNotice:Thepublicreportingburdenforthiscollectionofinformationisestimatedtoaverage0.25hoursperresponseforregistrationactivitiesand0.25hoursperresponseforreregistrationandspecialreviewactivities,includingtimeforreadingtheinstructionsandcompletingthenecessaryforms.Sendcommentsregardingtheburdenestimateoranyotheraspectofthiscollectionofinformation,includingsuggestionsforreducingtheburdento:Director,OPPEInformationManagementDivision(2137),U.S.EnvironmentalProtectionAgency,401MStreet,S.W.,Washington,DC20460.Donotsendtheformtothisaddress.DATAMATRIXDateMav17,2010EPARea.No.fFileSvmbol87284-IPaoe'?o!8Applicant'sJRegistrant'sName&AddressProductWillowoodPropiconazole,LLCWillowoodPropiconazoleTechnicalt600NWGardenValleyBlvd.Roseburq,OR9747tInaredientProoiconazo!e(CASNo.60207-90-1\GuidelineReferenceNumberGuidelineStudvNameMRIDNumberSubmitterStatusNoteCite-AllTheAndersonsLawnFertilizerPAYDivisionCite-AllMakhteshimChemicalWorksPAYLid,Cite-AllLovelandProducts,Inc.PAYCite-AllJanssenPMPPAYCite-AllBASFSparksLLCPAYCite-AllControlSolutionsInc.PAYCite-AllContechemInc.PAYCite-AllKOD-COatInc.PAYCite-AllSiomcanAqroUSAInc.PAYCite-AllArchWoodProtectionInc.PAYCite-AllDowAqroSciencesLLCPAYCite-AllMakhteshimAganofNorthPAYAmerica,Inc.SignatureNameandTilleoated..1<JJLAnnM.Tillman,ConsultantMayt7,2010EPAFonn8570-35(9-97)EleclronicandPaperversionsavailable.SubmitonlyPaperversion.AgencyInternalUseCopyFormApprovedOMBNo.2070-0060UNITEDSTATESENVIRONMENTALPROTECTIONAGENCY401MStreet,S.W.WASHINGTON,D.C.20460PaperworkReductionActNotice:Thepublicreportingburdenforthiscollectionofinformationisestimatedtoaverage0.25hoursperresponseforregistrationactivitiesand0.25hoursperresponseforreregistrationandspecialreviewactivities,includingtimeforreadingtheinstructionsandcompletingthenecessaryforms.Sendcommentsregardingtheburdenestimateoranyotheraspectofthiscollectionofinformation,includingsuggestionsforreducingtheburdento:Director,OPPEInformationManagementDivision(2137),U.S.EnvironmentalProtectionAgency,401MStreet,S.W.,Washington,DC20460.Donotsendtheformtothisaddress.DATAMATRIXDaleMav17.2010EPAReo.No.lFileSvmbol87284-IPaoe&of8Applicant's/Registrant'sName&AddressProductWillowoodPropiconazole,LLCWillowoodPropiconazoleTechnical1600NWGardenValleyBlvd.Rosebura,OR97471lnaredien!Proniconazole(CASNo.60207-90-1\GuidelineReferenceNumberGuidelineStudNameMRIDNumberSubmitterStatusNoteCite-AllArystaLifescienceNorthPAYAmericaInc.Cite-AllSeravDriftTaskForcePAYCite-AllDiaconTechnoloQiesLtd.PAYCite-AllDr.WolmanGmbhPAYCite-AllISKBiocides,Inc.PAYNichinoAmerica,Inc.PAYCite-AllOutdoorResidentialExposurePAYTaskForceCite-AllAgriculturalReentryTaskPAYForceCite-AllBaverAdvancedPAYCite-AllZelamLtd.PAYCite-AllSanstainIndustrvGrouePAYSignatureNameandTilleDateAnnM.Tillman,ConsultantMay17,2010__.__L.....L -___..__......___-------------------EPAForm8570-35(9_97)EleclronicandPaperversionsavailable.SUbmitonlyPaperversion.AgencyInternalUseCopyFormApprovedOMSNo.2070-0060UNITEDSTATESENVIRONMENTALPROTECTIONAGENCY401MStreet,S.W.WASHINGTON,D.C.20460PaperworkReductionActNotice;ThepublicreportingbUrdenforthiscollectionofinformationisestimatedtoaverage0.25hoursperresponseforregistrationactivitiesand0.25hoursperresponseforreregistrationandspecialreviewactivities,includingtimeforreadingtheinstructionsandcompletingthenecessaryforms.Sendcommentsregardingtheburdenestimateoranyotheraspectofthiscollectionofinformation,includingsuggestionsforreducingtheburdento:Director.OPPEInformationManagementDivision(2137),U.S.EnvironmentalProtectionAgency,401MStreet,S.W.,Washington,DC20460.Donotsendtheformtothisaddress.DATAMATRIXDateMay17.2010EPANo.lFile§ymbol87284-LPage70f8Applicant's/Registrant'sName&AddressProductWillowoodPropiconazole,LLCWillowoodPropiconazoleTechnical1600NWGardenValleyBlvd.RoseburQ,OR97471IngredientPropiconazole(CASNo.60207-90-1)GuidelineReferenceNumberGuidelineStudyNameMRIONumberSubmiUerStatusNoteCite-AllFIFRAEndangeredSpeciesPAYTaskForceLLCCite-AUOsmoseNewZealandPAYCite-AllResidentialExposureJointPAYVentureCite-AllSupremeChemicalsofPAYGeol1liaInc.Cite-AllArchWoodProtection(NZ)PAYLtd.Cite-AllAgriculturalHandlersPAYExposureTaskForceCite-AllArchTreatmentTechnologies,PAYInc.Cite-AllU.S.TriazoleTaskForcePAYCite-AllGro-ProLLCPAYSignatureNameandTilleDaleAnnM.Tillman,ConsultantMay17,2010-_.-EPAForm8570-35(9-97)ElectronicandPaperversionsavailable.SubmitonlyPaperversion.AgencyInternalUseCopyFormApprovedOMSNo.2070-0060UNITEDSTATESENVIRONMENTALPROTECTIONAGENCY401MStreet,S.W.WASHINGTON,D.C.20460PaperworkReductionActNotice:Thepublicreportingburdenforthiscollectionofinformationisestimatedtoaverage0.25hoursperresponseforregistrationactivitiesand0.25hoursperresponseforreregistrationandspecialreviewactivities,includingtimeforreadingtheinstructionsandcompletingthenecessaryforms.Sendcommentsregardingtheburdenestimateoranyotheraspectofthiscollectionofinformation,includingsuggestionsforreducingtheburdento:Director,OPPEInformationManagementD·lvision(2137),U.S.EnvironmentalProtecfronAgency,401MStreet,S.W.,Washington,DC20460.Donotsendtheformtothisaddress.DATAMATRIXDateMay17,2010EPARea.No.lFileSvmbol87284-IPaqe<bof8Applicant's/Registrant'sName&AddressProductWillowoodpropiconazole,llCWillowoodPropiconazoleTechnical1600NWGardenValleyBlvd.RosebufQ,OR97471IngredientPropJconazole(CASNo.60207-90-1)GuidelineReferenceNumberGuidelineStudyNameMRiDNumberSubmitterStalusNoteCite-AllPhoenixEnvironmentalCarePAYLLCCite-AllEliqraLLCPAYCite-AllShardaWorldwideExportsPAYPvt.Ltd.Cite-AllJ.OliverProducts,llCPAYCite-AllAmTidellCPAYCite-AllGenericEndangeredSpeciesPAYTaskForceSignatureNameandTitleDateAnnM.Tillman,ConsultantMay17,2010-_.._...._.._._.-_.--_....--_...EPAForm8570-35(9-97)ElectronicandPaperversionsavailable.SubmitonlyPaperversion.AgencyInternalUseCopy

## Endnotes for Data Matrix for Willowood Propiconazole Technical

1 

### 830.1650

_ These data are not required for the registration of a technical grade active ingredient

product. See 830.1620 for production process information.

2 

### 830.6313

_ Wiflowood Propiconazole, LLC does not package Wiflowood Propiconazole Technical in



### metal conta'iners, nor is 

### Willowood Propiconazole Technical 

### expected to come into 

### contact with 

### metals



### or metal ions during its storage or use. Therefore, a waiver from the requirement of these data is

requested. Wilfowood Propiconazole Technical was found to be stable at normal and elevated

temperatures.

3 

### 830.6315

_ Willowood Propiconazole, LLC requests a waiver from the requirement of this data

requirement since Willowood Propiconazole Technical is a solid and is not expected to be ftammable.

Please refer to the Confidential Statement of Formula for Willowood Propiconazole Technical.

4 

### 830.6316

_ Wllowood Propiconazole, LLC requests a waiver from this data requirement because

propiconazole does not have the chemical bonds or functional groups associated with explosive

chemicals. Please refer to the Confidential Statement of Formula for Willowood Propiconazole

Technical.

5830.6317, 830.6320

- Per PR Notice 92-5, storage stability and corrosion characteristics data are not

required to be submitted unless specifically requested by the Agency. Wllowood Propiconazole, LLC

agrees to conduct this study if required and requests that the study be made a condition of registration.

s 830.6319, 830.6321, 830.7520

_ WiUowood Propiconazole Technical is a solid and not an emulsifiable

concentrate and is not to be diluted with petroleum solvents. Therefore, miscibility data are not

required for this technical. Willowood Propiconazole Technical is not to be used around electrical

equipment and data for dielectric breakdown constant are not required. Willowood Propiconazole, LLC

is seeking a waiver for particle size, fiber length and diameter distribution because Willowood

Propiconazole Technical is not water insoluble nor is it a fibrous material.

7 

### 830.7100

_ Willowood Propiconazole, LLC requests a waiver from this data requirement because

Willowood Propiconazole Technical is a very viscous liqUid at room temperature and is not conducive

to viscosity testing.

8830.7200

_ Wllowood Propiconazole Technical is a liquid solid and melting point data are not required

for liquids. Data for boiling point are required for liquids. See Guideline 830.7220.

9830.7370

_ Willowood Propiconazole, LLC is seeking a waiver for this data requirement for Willowood

Propiconazole Technical because the product does not have any functional groups that would

dissociate.



### Page 

### 1 of 

### 1

# Certification with Respect to Label Integrity

version: **9/11/02**



## I certify that the information (including, but not limited to, text, tables, and graphics)

contained in the electronic file identified below by file name and submitted with this

certification is the same infonnation as that on the paper copies of these documents

included with this submission.

IPROPOSED LABEL



## Date Submitted

EPA Registration 

## # to EPA Electronic file name

087284-xxxxx May 20,2010 087284-xxxxx.201 00517 Willowood

Propiconazole Technical label v1.pdf

I certify that the statements that I have made on this form are true, accurate, and

complete. I acknowledge that any knowingly false or misleading statements may be

punishable by fine or imprisonment or both under applicable law.

Signature

Ann M. Tillman

Consultant, Willowood Propiconazole, LLC May 20, 2010

Date

, '>'

, 

## , , , , " ) , , > ,



# . ,

,

,

" , J , ,



### , 

## ,



# .

. " "

, , , >



## ., ,

, 

## "

, ; 

## , ,



# . '"

,

" J ,

)" '

# PROCFSSING ELECTRONIC'LABELS

(rev. 115109, ten)



## If e-Iabel submitted via XML e-submission (not on CD-ROM), you may wish to find e-Iabel in

Documentum, save e-Iabel to "My Documents", add e-Iabel to ELL, start below at step 5.



# Initial E-Label per application (on CD-ROM with paper via ITRMD)

1 

### ITRMO 

### receives

paper submission

wI a-label on CD

U 

### Save copy of e·

label from 

### Ell to



### My Documents

!lI Send annolated

a·label to registrant



### via email**~** 

### Tracking

record added to

OPPIN

I 

### Review label

11 File print of

annotated a-label



### and email in jackel J 

### ITRMD adds

e·label to ELL



### in-process

II Add commenls



### to a-label

(.avo: odd 'With

ccmmonf4" fu r.'c""mo



### review



# " Add annolaled e·

label 10 ELL



### out-process**~** 

### ITRMD sends

paper submission

10 AD/BPPD/RD**~** 

### Connect ELL

record with

OPPIN 5#

U 

### Print annotated e.

label

(u," • PI'ot wilh fll.Horno")



### n Close

submission in



### OPPIN



## Resubmission (via email '0 

### staffer or PM)

14 

### Receive email

submIssion wI 

### e·

label allached**1~** Add Iracking

record 10

OPPIN 'to Add e-Iabel

10 ELL



### in-process**l~** 

### Save copy 

# 0'

e"

labels 

### {od & new) from



### ELL to 

### My Documenls HI Compare old and

new labels wHh

Acrobal**~ll** Prinl e-Iabel,**~1** Mail slamped

slamp, wrile cover label & cover

leller leller 10 regislranl

("", "1'",,1**",1IcF~n"omu")**



### grocess

- big picture

1- create OPPIN tracking

2- put Jabe) in ELL; link 

### 10 S#

3- save ELL Jabel to MyDocuments

4- compare / commenl

5- outprocess review

U File slamped

label & cover letter

in Jackel



### out-process 11 Connecl ELL

record wllh



### OPPIN S#



### (if revisions needed repeat steps 8-19)

O'J Add cover

leiter to ELL

(,,,,,,,d,,lcry,1**~"''''Pl"d** w'"h com',"U,"I.)**~4** Close

submission in



### OPPIN



### techniques to know

- filename for e-JabeJs

- "print with filename"

- compare 

### I comment

- printing with comments

# There is an 

# ELECTRONIC LABEL for this action

You can use Acrobat to compare the e-Iabel to the previous version (and find the

changes). You can also use Acrobat to mark-up the e-Iabel with your comments.

If e-Iabel was submitted via



# CD-ROM with paper application

then you will find e-Iabel in



# Electronic Label Library

If /110 e·/abol is not found In 1/10 eLL tllQn i/IVOS probably /10/ nDlllod

correctly and cOlild no/ bo entered Inlo tile eLL. However, /lIB fila



### can be rEtrioved**rrom-,!~'!..gp \~!!Ic/l!~** **reloll1()~** 

### I/le 

### F'!:!!lLl=J!ci.:,

__ 

### J 

# or If e-Iabel was submitted via



# XML E-Submission (no paper)

then you will find e-Iabel in



# Documentum

See overview of processing e-Iabels on other side of this sheet.

If you have any questions on e-Iabels, please contact one of your division e-Iabel experts:



# AD



# BPPD

RD Willie Abney

Renae Whitaker

Tracy Lantz

Tom Harris 

## 308-1689

308-7003

308-6415

308-9423

## WILLOWOOD PROPICONAZOLE TECHNICAL

FOR USE IN FORMULATING FUNGICIDES ONLY

ACTIVE INGREDIENT:

Propiconazole: 1-[(2-(2,4-dichlorophenyl)-4-propyl-1 ,3-dioxolan-2-yIJmethyl]-1 

### H-1 ,2,4-

traizole

.............................................................................................................................. 99.00/0

OTHER INGREDIENTS

..................................................................................................... 1.0%



### TOTAL

.............. '

.................................. "

............... ,"

........................... "

.... 100.0%



## KEEP OUT OF REACH OF CHILDREN



# Warning/Aviso

Si usted no entiende la etiqueta, busque a alguien para que se la explique a usted en detaUe.

(If you do not understand the label, find someone to explain 

### it to you in detail)



## FIRST AID

IF IN EYES: • Hold eye open and rinse slowly and gently with water for 15 -20

minutes.

• Remove contact lenses, if present, after the first 5 minutes, then

continue rinsing.

• Call a Poison Control Center or doctor for treatment advice.

IF ON SKIN OR • Take off contaminated clothing.

CLOTHING: • Rinse skin immediately with plenty of water for 15 -20 minutes.

• Call a Poison Control Center or doctor for treatment advice.

IF SWALLOWED • Call a poison control center or doctor immediately for treatment advice.

• Have person sip a glass of water if able to swallow.

• Do not induce vomiting unless told to do so by the poison control center

or doctor.

• Do not give anything by mouth to an unconscious person.

IF INHALED 

# • Move person to fresh air.



# • If person is not breathing, call 911 or an ambulance, then give

artificial respiration, preferably by mouth-to-mouth, if possible.

• Call a poison control center or doctor for further treatment advice.

,N 

# ..

For Medical Emergencies call 24 Hours a Day 1-800-858-7378. Have the product container or

label with you when callina a Poison Control Center or doctor or going for treatment.

EPA Reg. No. 87284-

Manufactured for:

Wllowood Propiconazole, LLC

1600 NW Garden Valley Blvd.

Roseburg, OR 97471

Willowood Propiconazole Technical Label 

### Net Contents:

# toffl'~~**JI-1°~** 

# .1IL

- ()J'.u..1.£, 

# (J'JJiJ



# N/1'1

- alfcll-uvUlSu EPA Est. No.

1

### PRECAUTIONARY STATEMENTS

HAZARD TO HUMANS AND DOMESTIC ANIMALS 0' 

### WARNING. Causes substantial but temporary eye irritation. Harmful 

### if swaUowed",inf:laled or

-absDlbed tillougl, skin. Do not get in eyes or on clothing. Wear protective eyewear (goggles,

face shield or safety glasses). Wash thoroughly after handling and before eating, drinking,

chewing gum, using tobacco, or using the toilet. Remove and wash contaminated clothing

before reuse. "Prolonged <3r fFC6\UeAtly repeated**sl~lf\** 

### eentaGt may cause 0\!cFgie**Fe8etiG~**

# ~ ENVIRONMENTAL HAZARDS 

## aVThis product is toxic to fish. Do not discharge effluent containing this product directly into lakes, /'

streams, ponds, estuaries, oceans or public waters unless in accordance with the requirements

of a National Pollutant Discharge Elimination System (NPDES) permit and the permitting

authority has been notified in writing prior to discharge. Do not discharge effluent containing

this product to sewer systems without previously notifying the local sewage treatment plant

authority. For guidance, contact your State Water Board or Regional Office of the

Environmental Protection Agency.

DIRECTIONS FOR USE



### It is a violation of Federal law to use this prpduct in a manner inconsistent with its labeling. 

# SGld-= Sew 0\!}fJ

## ~q 

# cJNWfnwvThis product may only be used to formulate

## end~u&e pro-ducts with

## th~t~lIowing uses:

(1) Almonds, Banana and Plantain, Berry Crop Group,

### Carro~Celery and Leaf Petiole**Subgrou~Cereals** 

### (Barley, Oats, Rye, Triticale, Wheat), Citrus**(Non~bearing),** 

### Corn

(Field, 

# Beet1, Pop, Sweet), Cranberries (OR, WA, WI only), Filberts, Grasses grown for

Seed (ftr,--MN, NE, OR and WA only), Onions (dry bulb and green), Peanuts, Pecans,

Peppermint and Spearmint, Pineapple (HI only), Pistachio, Rice, Sorghum, Soybeans,

Stone Fruit, Strawberry, Sugar Beet, Sugargane, Tree Nuts

t 

### Turf and Ornamental, Wild

Rice (MN only) 

## !**~** 

# flti2C-<'- 

# chp <:.uiQ, 

# "1

(2) uses for which US EPA has accepted the required data and/or citati6ns of data that the

formulator has submitted in support of registration; and

(3) uses for experimental purposes that are in compliance with U.S. EPA requirements.



## STORAGE AND DISPOSAL

Do not contaminate water, food or feed by storage or disposal.

PESTICIDE STORAGE: Store in original container tightly closed and in a safe place.

PESTICIDE DISPOSAL: Dispose of wastes resulting from the use of this product on site or at

an approved waste disposal fadlity.

CONTAINER DISPOSAL: Nonrefillable container. Do not reuse or refill this container. Offer

the drum for recycling, if available. Clean container promptly after emptying. Triple rinse as

follows: Empty the remaining contents into application equipment or a mix tank. Fill the

container 1/4 full with water. Replace and tighten closures. Tip container on its side and roll it

back and forth, ensuring at least one complete revolution, for 30 seconds. Stand the container

on its end and tip it back and forth several times. Turn the container over onto its other end and

tip it back and forth several times. Empty the rinsate into application equipment or a mix tank or

store rinsate for later use or disposal. Repeat this procedure two more times. Pressure rinse

as follows: Empty the remaining contents into application equipment or a mix tank. Hold the

container upside down over application equipment or mix tank or collect rinsate for later use or

disposal. Insert pressure rinsing nozzle in .the side of the container and rinse at about 40 psi for

at least 30 seconds. Drain for 10 seconds after the flow begins to drip.

Willowood Propiconazole Technical Label 2

### WARRANTY STATEMENT



### IMPORTANT NOTICE -SelJer warrants that this product conforms to the chemical description



### and is reasonably fit 

### for purposes stated on the label when used in accordance with the

directions and instructions under normal conditions of use; but neither this warranty nor any

other warranty of merchantability or fitness for a particular purpose, express or implied, extends



### to the use contrary to label instructions, or under conditions not reasonably foreseeable to

seifer, and to the extent consistent with applicable law, buyer assumes the risk of any such use.

Willowood Propiconazole Technical Label 

### 3___:WMiMiM_"""w,_,...PRFORM,a-i.l.......-.....CONEIDENTIALSTATEMENTOFFORMULAENCLOSED..DoNotWriteComments,Formul8,orPartsofFonnulaonThisEnvelope!\IOTEIt,sballbeunlawful-foranyto:useforhisownadVantageortoreveal.,othe,"tllanto'the',"Secretar:loroffldalsoremployees,of,theUnitedStates,DtJP.rtmentofA"tcultureorotherFederalagencies,or,tothecouftsIn""'Ponse'toasubpoena.ortophJSldafts.and,litemergencies,topharin8cfstSand,other:quallfledperSons.foruseInthepreparation:of;antldOteSr"In'accordance'Wftti'suchdlreCtfoas:aatheSecretaryInformationrel8tivetoform,ui;',of>'productsacquiredbYaUthorityofSecUon4oftheFung1clde.andUSO..Aai

### BARCODE: 0379844; Reg. No./FILE SYMBOL No.: 87284-R; PRODUCT: Willowood Propiconazole

Technical

830.1750. Certified limits: (MRID 481039-01)

The certified limits for the active ingredient specified on the CSF are within the OPPTS 830.1750

recommended range. Upper certified limits were provided on the CSF for the impurities in the product.

21