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MATERIAL SAFETY D A TA S H EET (Developmental Product)

SEC T IO N I

- PR O DUC T I DEN T I FI C A TI O N

P R O DUCT N A M E (S) : DP

- 11 1

P R O DUCT N A M E /C L A S S : N on

– h a l o g e n at e d f l a m e retarda n t

CHE M I C A L F A M IL Y : Phosphinates

F O R M U L A : R e g i s t e r ed T r a d e S e cr et

P R O DUCT U S E : F l a m e retard a nt f or p l a s t i c s s u c h a s poly amides , polyesters

S U P P L I E R/ M A NU F A C T URER: J J I T e c hnolo g ies , LLC

A DD R E SS : 1350 Bacon Road Painesville, OH. 44077

24 HOUR E M E R G E NCY P H O N E : 800

- 424

- 9300 CHEMTREC

D A T E O F P R E P A R A

T I O N: April 4 , 20 1 2



### SEC T IO N I I

- CO M P O S I T IO N a n d I N FOR M A T IO N O N I N G RED I EN T S

CHE M IC A L N A M E C A S # E C # % W /V

Proprietary Phosphinate Registered Trade Secret Registered Trade Secret 100%

SECTION III

– HAZARDS IDENTIFICATION

EMERGENCY OVERVIEW

Appearance: Fine , free

- flowing White Powder

Warning: May be harmful if inhaled. May cause eye and skin irritation. May cause respiratory and digestive tract

irritation

.

Target Organs: None known

Potential Health Effects

Eye : May cause eye irritation.

Skin : May cause skin irritation.

Ingestion : Harmful if swallowed.

Inhalation : May cause effects similar to tho se described for ingestion. May cause respiratory tract irritation.

Chronic : Repeated exposure may cause sensitization dermatitis.

SECTION IV

- FIRST AID ME ASURES

Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids.

Seek medical attention.

Skin: Immediately flush skin with plenty of water for at least 15 minutes while removing conta minated clothing and

shoes. Wash clothing before reuse.

Ingestion: Call a poison control center. If swallowed, do not induce vomiting unless directed to do so by medical

personnel. Never give anything by mouth to an unconscious person. Seek medical attention.

Inhalation: Seek medical attention immediately. Remove from exposure and move to fresh air immediately. If not

breathing, give a rtificial respiration. If breathing becomes difficult, give oxygen. Do not use mouth

- to

- mouth

resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a

bag and mask.1350 Bacon Road P a i n e s v i l l e , O H . 4 4 0 7 7 Tel: 4 4 0

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Notes to Physician: Trea t symptomatically and supportively.

SECTION V

- FIRE FIGHTING MEASURES

General Information: During a f ire, irritating and noxious gases may be generated by thermal decomposition or

combustion. Wear appropriate protective clothing to prevent contact with s kin and eyes. Wear a self

- contained

breathing apparatus (SCBA) to prevent contact with thermal decomposition products. Dust can be an explosion hazard

when exposed to heat or flame.

Extinguishing Media: For small fires, use dry chemical, carbon dioxide, water spray or foam. Water or foam may cause

frothing. Use water spray to cool fire

- exposed containers.

Flash Point: Not applicable

Autoignition Temperature: 340C

Explosion Limits: Pmax = 5.8 (+/

- 10%), Kst= 198 (+/

- 12%), MIE = 1.2

NFPA Rating: (estimated) Health: 0; Flammability: 2; Instability: 0

Section VI

- ACCIDENTAL RELEASE MEASURES

Genera l Information: Use proper personal protective equipment as indicated in section VIII.

Spills/Leaks: Ventilate area of spill. Keep unnecessary and unprotected people away from area of spill. Wear appropriate

personal protective equipment as specified in Section 8. Spills: Pick up and place in a suitable container for reclamation

or disposal, using a meth od that does not generate dust. Clean up spills immediately, observing precautions in the

Protective Equipment section.

S ECTION VII

- HANDLING AND STORAGE

Handling: Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Avoid contact with

eyes, skin and clothing. Keep away from heat, sparks and flame. Avoid ingestion and inhalation. Use with adequate

ventilation.

Storage: Keep away from heat, sparks, and flame. Keep from contact with oxidizing materials. Store in a cool, dry, well

ventilated area away from incompatible substances.

SECTION VIII

- EXPOSURE CONTROLS, PERSONAL PROTECTION

Engineering Controls: Facilities storing or utilizing this material should be equipped with an eye wash facility and a safety

shower. Use proce ss enclosure, local exhaust ventilation, or other engineering controls to control airborne levels.

Personal Protective Equipment

Eyes : Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA’s eye and face protection

regula tions in 29 CFR 1910.133 or European Standard EN166.

Skin : Wear appropriate gloves to prevent skin exposure.

Clothing : Wear appropriate protective clothing to prevent skin exposure.

Respirators: A respiratory protection program that meets OSHA’s 29 CFR 1910.134 and ANSI Z88.2 requirements or

European Standard EN 149 must be followed whenever workplace conditions warrant a respirator’s use.

SEC T IO N IX

- PHYS IC A L A N D CHE MIC A L P R O PER T I E S

P H Y S I C A L F O R M : p o w d e r C O L O R: wh i t e

APPEARANCE: Fine white powder ODOR : None reported

BOILING P O IN T : Not applicable S O LUBI L I T Y : min. w a t er solubility1350 Bacon Road P a i n e s v i l l e , O H . 4 4 0 7 7 Tel: 4 4 0

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V A P O R D E N S I T Y : Not a p p li c a b l e V I S C O S I T Y : Not a p p li c a b l e

E V A PO R A T I O N R A T E : N ot a p p l i c a b l e S P E CIFIC G R A V I TY : 1.87

pH: 3

- 5 V A P O R P R E S S U R E : N ot a p p li c a b l e

M E LTING P O IN T : Decomposes >315 C R E L A T I V E V A P O R D E N S I T Y : Not a p p li c a b l e

O D O R T HRE S H O L D : Not a p p l i c a b l e E X P A N S I O N R A T I O : N ot a p p l i c a b l e

Not e : T h e s e p h y s i c al d a t a are t y p i c a l v a l u e s b a s ed o n m at e r i al t e s t e d b ut m a y v a r y f r o m s a m p l e to s a m p l e. T y p i c a l

v a l u e s s h o u l d n o t b e c o n s t r u e d as a g u aran t ee a n al y s i s of a n y s p e c i f i c l ot or as s p e c i f i c at i o ns f or the pr o d u ct

.

Section X . STABILITY AND REACTIVITY

Chemical stability

Stable under recommended storage conditions.

Conditions to avoid

Ignition sources, excess heat, temperatures exceeding temp. stability of product, strong oxidants, bases, sparks and open

flames. Avoid using in combination with catalytic radicali c initiators such as Copper halogenides including, but not limited

to Copper iodide, copper bromide and copper chloride additives. Avoid dispersing in dust cloud as material may be

combustible in dust cloud form. Avoid static accumulation/discharge.

Incom patibilities with Other Materials: Strong oxidizers, bases , catalytic initiators especially those typically used as heat

stabilizers (Copper Halogenides

- i.e

. Copper iodide, copper bromide and copper chloride)

Haz a rdous Decomposition Products: Pyrolysis tests performed in the presence of oxygen at temperatures exceeding the

product decomposition temperature have shown no formation or releases of hazardous products. Under vacuum, In the

absence of oxygen, phosphine gas may be formed.

Section XI

. TOXICOLOGICAL INFORMATION

Epidemiology

Teratogenicity: No data available

Reproductive Effects: No data available

. Mutagenicity: No data available.

Neurotoxicity: No data available.

Chronic Exposure

IARC: This product does not contain greater than or equal to 0.1% of a component identified as probable, possible or

confirmed human carcinogen by IARC.

ACGIH: This product does not contain greater than or equal to 0.1% of a component identified as a carcinogen or

potential carcinogen by ACGIN.

NTP: This product does not contain greater than or equal to 0.1% of a component identified as a known or anticipated

carcinogen by NTP.

OSHA: This product does not contain greater than or equal to 0.1% of a component identified as a carcinogen or

potential carcinog en by OSHA.1350 Bacon Road P a i n e s v i l l e , O H . 4 4 0 7 7 Tel: 4 4 0

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Section XII. ECOLOGICAL INFORMATION

No data available.

Section XIII . DISPOSAL CONSIDERATIONS

Product

Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA

guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must

consult state and local hazardous waste regulations to ensure complete and accurate classification.

Contaminated packaging

Dispose of as unused product.

Section XIV . TRANSPORT INFORMATION

DOT (US)

Hazard Class 4.1, UN 3178, Packing group II

Section XV . REGULATORY INFORMATION

T S C A S T A T U S : The product is under review for TSCA status

. Chemical Test Rule: None of the chemicals in this product are under a Chemical Test Rule

Section 12b: None of the chemicals are listed under TSCA Section 12b.

TSCA Significant New Use Rule: None of the chemicals in this material have a SNUR under TSCA.

NOTE: This product is for research and development purpose s only. The toxicological properties of this material have

not been fully investigated and it should be treated as though it were toxic. It must be used only under the supervision

of a technically qualified individual. Product is being exported in quantit ies that are not subject to REACH requirements.

C E RC L A R E P O R T A B L E Q U A N T I T Y : None

S A R A T I T LE II I :

SE C T I O N 3 0 2 : None

SE C T I O N 3 1 1/ 3 1 2: None

SE C T I O N 3 1 3: None

Clean Water Act: None of the chemicals in this product are considered highly hazardous by OSHA.

OSHA: None of the chemicals in this product are considered highly hazardous by OSHA.

State: Substance cannot be found on the following right to know lists: California, New Jersey, Pennsylvania, Minnesota,

or Massechusetts

.

California Prop 651350 Bacon Road P a i n e s v i l l e , O H . 4 4 0 7 7 Tel: 4 4 0

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This product does not contain any chemical known to the state of California to cause cancer, birth, or any other

reproductive effects.

European/International Regulations

European Labeling in Accordance with EC Directives

Hazard Symbols:

F

Risk Phrases:

R10 Flammable

Safety Phrases:

S22 Do not breath dust.

S7 Keep contained tightly closed

S16 Keep away from sources of ignition

- No Smoking

Revision number: DP

- 11 1

- MSDS

- R 7

WARNING: By following the directions and warnings provide d with this product, the risk associated with the use of this

product can be greatly reduced but never entirely elimi nated. JJI Technologies, LLC makes no warranties, expressed or

implied, with respect to this product and EXPRESSLY DISCLAIMS THE WARRANTY OF MERCHANTABILITY AND ANY

WARRANTY OF FITNESS FOR A PARTICULAR PURPOSE. Users assume all risks in handling, using or storing th is product.

JJI Technologies, LLC urges each customer or recipient of this (M)SDS to study it carefully and consult appropriate expertise , as

necessary or appropriate, to become aware of and understand the data contained in this (M)SDS and any hazards a ssociated with the

product. The information herein is provided in good faith and believed to be accurate as of the effective date shown above. H owever,

no warranty, express or implied, is given. Regulatory requirements are subject to change and may differ between various locations. It is

the buyer's/user's responsibility to ensure that its activities comply with all federal, state, provincial or local laws. The information

presented here pertains only to the product as shipped. Since conditions for use of t he product are not under the control of JJI

Technologies, LLC, it is the buyer's/user's duty to determine the conditions necessary for the safe use of this product. Due to the

proliferation of sources for information such as manufacturer

- specific (M)SDSs, we are not and cannot be responsible for (M)SDSs

obtained from any source other than ourselves. If you have obtained an (M)SDS from another source or if you are not sure that the

(M)SDS you have is current, please contact us for the most current version.