tlebe ;.f$lunitipal autboritp 

Members of the Board 

FRANK BAZZONE 

DALE R. MCCALL 

REGIS T. MCI.JIUGHLIN 

LUETHEL NESBIT 

NICKOLAS J. SHERMENTI 

November 23, 2010 

Mr. Chad Harsh 

NPDES Enforcement Branch 

Water Protection Division 

of tb.e C!Citp of ;ffmc1keesport 

100 Atlantic Avenue 

McKeesport, PA 15132 

Office: (412) 673-8276 

Fax: (412) 673-4283 

www. mck-macm.org 

Joseph E. Rost 

Executive Director 

Phone (412) 673-9701 

RECEIIE 

EP/\ nEC?iON Ill 

NOV 2 9 2010 ~PDES E !FO CH;c'H BRAi·1CH 

(3VVP42) 

U.S. Environmental Protection Division 

1650 Arch Street 

Philadelphia, PA 19103 

Dear Mr. Harsh: 

As requested in your letter dated February 19, 2009, enclosed is a copy of the Authority's latest 

submittal to the Pennsylvania Department of Environmental Protection in response to its order 

issued October 23, 2008. This Order was issued relative to the gas well water that the Authority 

has received for treatment. 

If you have any questions, please contact me at ( 412) 673-9701 x 12. 

Sincerely, 

ktf{:/f: 

Enclosures 
'aebe iMuntctpal autbotttp 

Members of the Board 

FRANK BAZZONE 

DALE R. McCALL 

REGIS T. MCLAUGHLIN 

LUETHEL NESBIT 

NICKOLAS SHERMENTI 

November 23,2010 

of tbt Q!:itp of :flld&.tt5port 

100 Atlantic Avenue 

McKeesport,PA 15132 

Office: (412) 673-8276 

Fax: (412) 673-4283 

www.mckeesport-macm.org 

Mr. Kevin Halloran, Water Quality Specialist Supervisor 

Water Management 

Pennsylvania Department of Environmental Protection 

400 Waterfront Drive 

Pittsburgh, PA 15222-4745 

Dear Mr. Halloran: 

Municipal Authority of the City of McKeesport 

Analysis of Gas Well Wastewaters 

As Required Under the 

P A DEP Administrative Order Dated October 23, 2008 

Joseph E. Rost 

Executive Director 

Phone (412) 673-9701 

Please find enclosed copies of the laboratory analyses of fourteen (14) wells owned by 

Chesapeake Energy for the parameters specified in the Administrative Order. The wells are 

identified as #831 596- drill water, #831572, #627044- drill water, #831927, #831200- drill 

water, #831202- brine water, #627045 -drill water, #627025, #and 627043 -drill water. 

The Authority is currently accepting gas well water from three companies, Huntley & Huntley, 

Chesapeake Energy, and CNX Gas. Wastewaters from new wells accepted by the plant are in the 

process of being analyzed by Environmental Service Laboratories (ESL) located in Indiana, P A. 

As the results are received by the Authority copies will be forwarded to your office. 

If you have any questions, please contact me at (412) 673-9701 ext. 12. 

Sincerely, 

....,.,Lr.~ ttZrcc: Michael C, Sherrieb, KLH Engineers, Inc. 

Chad Harsh, EPA 
ENVIRONMENTAL SERVICE 

LABORATORIES, INC. SAMPLE REQUEST & CHAIN OF CUSTODY 

HEADQUARTERS: ~ SOUll-IERN DMSION: 

1 803 Philadelphia Sl 

~ 

1276 BenUeyville Road D Indiana, PA 15701 Van Voomls, PA 15366 (724) 463-TEST (724) 258-TEST 

(724) 465-4209 (724) 258-8376 

FOR INTERNAL LAB ORA TORY USE ONLY 

-

-

Sample Identification ESL# 

TRIP 

,. 

BLANK 

~~~ 

Date/ Time 

OF CUSTODY SEAL BROKEN: Yes No 

I· ' : 

c-~:: ., >.--<· 

-

.. 

• I \. 

··•"" 

·--- l \. 

Matrix # of Containers 

WN 

-

WN il3 

-

lfVIN 

-

lfVIN 

-

lfVIN 2 

-

lfVIN 

-

WN 

-

lfVIN 2 

-

lfVIN 2 

Water 2 

Date/ Time 

.. QJ ~ r·' 

0 j\j 

( \ j\i ~ ~\.\ Container Type 

Preservative 

Plastic Uter 

none 

Plastic Uter 

none 

Plastic Uter 

HN03 

Plastic Uter 

H,SO, 

Plastic Uter 

HN03 

Amber Glass L 

HCI 

Amber Glass L 

~so, 

Amber VOA Vials 

none 

Aniber VOA Vials 

HCI 

Amber VOA Vials 

HCI 

Fax: 

f\j//~

M

Ch

900 
F. ~'"! \J ! t):.f""!"""1 f\! !\ii F t,J "t A ! lilill I W Y I •'- ~I~ J· W '1- I W •.• '\:JIIiii 

SEr<VICt LABoRATORIES. INC. 

1 e03 FNodelphia St., lrK1iana., P.l\ 15701 

(72<1) 463·TI:ST (724) L!C~'>420Q 

Name: 

Sample Start Date: 

Chesapeake Appalachia, LLC 

900 Pennsylvania A venue 

Attn: Mr. Eric Gillespie 

Charleston, WV 25302 

8/112010 10:30 AM 

Receipt Date: 8/3/2010 4:37PM 

Report Date: 8/23/2010 

Analyte Analyst Analysis 

Date 

Acidity to pH=8.3 BF 08/10 

Alkalinity to pH=4.5 BF 08/12 

Biological Oxygen Demand 05 szc 08/04 

Chemical Oxygen Demand ZTR 08/19 

Ammonia as N I Distilled MAD 08/13 

Chloride JFW 08/17 

Kjeldahl Nitrogen as N ZTR 08/18 

pH (SM) LL 08/04 

Sulfate ASTM ZTR 08/11 

Total Nitrate +Nitrite as N AID 08/11 

Aluminum- ICP GJT 08/17 

Arsenic-ICP GJT 08/18 

Barium- ICP GJT 08/17 

Beryllium - ICP GJT 08/18 

Boron MAD 08/10 

Cadmium - ICP GJT 08/18 

Calcium - ICP GJT 08/17 

Chromium- ICP GJT 08/17 

Cobalt- ICP GJT 08/17 

Copper- ICP GJT 08/17 

Hardness GJT 08/17 

Report of Analysis 

Analysis Sample 

Time Result 

n/a 117 

n/a 130 

7:00AM 121.8 

n/a 2997.5 

n/a 82.63 

n/a 142760.4 

n/a 76.4 

n/a 5.95 

n/a ND 

n/a 0.20 

n/a 1.150 

n/a ND 

n/a 1866.550 

n/a ND 

n/a 6.50 

n/a ND 

n/a 10071.550 

n/a ND 

n/a ND 

n/a ND 

nla 29664 

Sample ID#: 

Sample Type: 

Sample Source: 

Sampler: 

10 24746 

Waste Water 

Grab 

Client Sample ID: 

CLIENT (Client) 

831202 Brine Water 

Units Data Method 

I Qualifier 

mg/1 as CaC03 n/a SM2310B 

mg/1 as CaC03 n/a SM2320B 

mg/1 R SM5210B 

mg/1 D SM5220D 

mg/1 n/a SM4500NH3B & D 

mg/1 n/a SM4500ClC 

mg/1 n/a SM4500Norg-C,D 

su n/a SM4500H-B 

mg/1 n/a D516-02 

mg/1 n/a SM4500N03E 

mg/1 n/a 200.7/6010 

mg/1 n/a 200.7/6010 

mg/1 n/a 200.7/6010 

mg/1 n/a 200.7/6010 

mg/1 D SM4500B-B 

mg/1 n/a 200.7/6010 

mg/1 n/a 200.7/6010 

mg/1 n/a 200.7/6010 

mg/1 n/a 200.7/6010 

mg/1 n/a 200.7/6010 

mg/1 n/a SM2340B 

RPL 

2 

20 

2.0 

500.0 

0.91 

5.0 

4.4 

0.01 

5 

0.05 

0.500 

0.500 

0.250 

0.250 

2.50 

0.250 

25.000 

0.250 

0.250 

0.250 

I 

jNDo:Not Detected 

____ n_EP __ cert ifi ion#_s 2-oo -------------------------------------~~ 

Data Qualifiers: D =The reported value is from dilution. E = Estimated value. S = Surrogate out of control limits. 

R = Sample received out of holding time. H = Sample analyzed out of holding time. C = Sample received in incorrect container. 

B = Analyte was detected in both sample and methods blank. X = User defined data qualifier. 

Page 1 of 3 
t:' ~\. i I i~r-z. ~if. At: i\. j ·f ~ .. i •... j ...... , • .... .. J • ~·~. .... I; •;· .. ,. ........ :1!. 

....: .I "W W' a .... ~ a .... I W lliiil.· J: • I 6 'l:.aiSERVICE LABORATORIES, INC. 

1-00.1 PhEade!pt1iO St .. lr'di'.JilO. PA 1 5701 

(724) 46-"'HfST (724) .<16!':>-4209 

Name: 

Sample Start Date: 

Chesapeake Appalachia, LLC 

900 Pennsylvania Avenue 

Attn: Mr. Eric Gillespie 

Charleston, WV 25302 

8/112010 10:30 AM 

Receipt Date: 8/3/2010 4:37PM 

Report Date: 8/23/2010 

Analyte Analyst Analysis 

Date 

Iron- ICP GJT 08/17 

Iron,Dissolved-ICP GJT 08/17 

Lead-ICP GJT 08/17 

Lithium - ICP GJT 08/18 

Magnesium-ICP GJT 08/17 

Manganese- ICP GJT 08/18 

Mercury DRM 08111 

Nickel- ICP GJT 08/17 

Selenium-ICP GJT 08/17 

Silver-ICP GJT 08/17 

Sodium- ICP GJT 08/18 

Strontium- ICP GJT 08/18 

Zinc- ICP GJT 08/17 

Osmotic Pressure MAD 08/10 

Detergents, l\1BAS TL 08/04 

Oil and Grease - HEM CLM 08116 

Phenolics, as Phenol AID 08/05 

Specific Conductance LL 08/04 

Total Dissolved Solids (TDS) szc 08/09 

Total Suspended Solids szc 08/09 

1) Benzene RO 08/04 

Report of Analysis 

Analysis Sample 

Time Result 

n/a 60.600 

n/a 50.100 

n/a ND 

n/a 72.250 

n/a 1096.450 

n/a 4.050 

n/a ND 

n/a ND 

n/a ND 

n/a ND 

n/a 30698.000 

n/a 1682.000 

n/a ND 

n/a 3520 

3:55PM 0.617 

n/a ND 

n/a 1.060 

n/a 134400 

n/a 143700 

n/a 225 

n/a ND 

Sample ID#: 

Sample Type: 

Sample Source: 

Sampler: 

10 24746 

Waste Water 

Grab 

Client Sample ID: 

CLIENT (Client) 

831202 Brine Water 

Units Data Method 

Qualifier 

mg/1 n/a 200.7/6010 

mg/1 n/a 200.7/6010 

mg/1 n/a 200.7/6010 

mg/1 n/a 200.7/6010 

mg/1 n/a 200.7/6010 

mg/1 n/a 200.7/6010 

mg/1 D 245.1 

mg/1 n/a 200.7/6010 

mg/1 n/a 200.7/6010 

mg/1 n/a 200.7/6010 

mg/1 n/a 200.7/6010 

mg/1 n/a 200.7/6010 

mg/1 n/a 200.7/6010 

mOs/kg D OSP 

mg/1 n/a SM5540C 

mg/1 n/a 1664A 

mg/1 D 420.1 

uS/em n/a SM25IOB 

rng/1 n/a SM2540C 

rng/1 n/a SM2540D 

ug/L n/a 624/8260B 

RPL 

0.500 

0.500 

0.250 

25.000 

25.000 

0.250 

0.0008 

0.250 

0.500 

0.250 

500.000 

10.000 

0.250 

1000 

0.200 

5.0 

0.500 

I 

25 

5 

10.00 

f D=Not Detected 

DEP Certification #s 32-00382 

Data Qualifiers: D =The reported value is from dilution. E = Estimated value. S =Surrogate out of control limits. 

R = Sample received out of holding time. H = Sample analyzed out of holding time. C = Sample received in incorrect container. 

B = Analyte was detected in both sample and methods blank. X = User defined data qualifier. 

Page 2 of 3 
Name: 

F 

....

.

F. 

\.! \1 i !:_)f1 ~ i ftfi ~ f\: T fl. ~ -. ... ••"""'~"Wj'I'J.wr . ..... -6 .._..._ 

SERVICE LABORATORIES. INC. I 001 FhiladelptllO Sl.. lf~( 'J rJ U.. PA 15701 

(724) 46.1·TEST (724) 46.>~209 

Sample Start Date: 

Chesapeake Appalachia, LLC 

900 Pennsylvania A venue 

Attn: Mr. Eric Gillespie 

Charleston, WV 25302 

8/1/2010 10:30 AM 

Receipt Date: 8/3/2010 4:37PM 

Report Date: 8/23/2010 

Analyte Analyst Analysis 

Date 

47) Toluene RO 08/04 

Report of Analysis 

Analysis Sample 

Time Result 

n/a ND 

Sample ID#: 

Sample Type: 

Sample Source: 

Sampler: 

10 24746 

Waste Water 

Grab 

Client Sample ID: 

CLIENT (Client) 

831202 Brine Water 

Units Data Method 

LQualifier 

ug/L nla 624/8260B 

RPL 

10.00 

Comments: 

IND=Not Detected 

DEP Certification lis 32-00382 

Data Qualifiers: D =The reported value is from dilution. E = Estimated value. S = Surrogate out of control limits. 

R =Sample received out of holding time. H =Sample analyzed out of holding time. C =Sample received in incorrect container. 

B = Analyte was detected in both sample and methods blank. X= User defined data qualifier. 

Page 3 of 3 
a: i\ i \ 1 1 t}r_._""'\ t ... e i\ ~ c i\ i ;-t A i :.l ~ -: : ~; ': 1'.:; ;w.; ~ ;...-;..;. 

SERVICE LABORATORIES. INC. 

1 003 FNooelpliiO St .. lr"·dk:JriO, PA 15701 

(724) 46-l TfST (724) 116-5-42()<;1 

Name: 

Sample Start Date: 

Receipt Date: 

Report Date: 

Analyte 

Prep-16 Send Out 

Ethylene Glycol 

Radiologicals 

Chesapeake Appalachia, LLC 

900 Pennsylvania A venue 

Attn: Mr. Eric Gillespie 

Charleston, WV 25302 

8/1/2010 10:30 AM 

8/3/2010 4:37PM 

8/26/2010 

Analyst Analysis 

Date 

DAS 08/05 

MetPeal< 08/09 

enchmm 08/13 

Report of Analysis 

Analysis Sample 

Time Result 

n/a D 

n/a <25.500 

nla * 

Sample ID#: 

Sample Type: 

Sample Source: 

Sampler: 

10 24747 

Waste Water 

Grab 

Client Sample ID: 

CLIENT (Client) 

831202 Brine Water 

Units Data Method 

. Qualifier 

none nla Gen. Prep. 

mglkg nla 300.0 M 

mg/1 nla RAD-CTDHS 

RPL 

0 

25.500 

0.000 

Comments: Ethylene Glycol subcontracted to Metrohm-Peak, ISO# 10001397QM08 Radiologicals done by 

Benchmark Analytical, PADEP Lab ID: 39-00401 IND=Not Detected 

DEP Certification #s 32-003 82 

Data Qualifiers: D =The reported value is from dilution. E =Estimated value. S =Surrogate out of control limits. 

R =Sample received out of holding time. H =Sample analyzed out of holding time. C =Sample received in incorrect container. 

B = Analyte was detected in both sample and methods blank. X = User defined data qualifier. 

Page 1 of 1 
LAB iD: 39-00401 

SEND DATA TO: 

NAME: Mike Moyer 

BENCHMARK ANAL YTICS, INC. 

4777 Saucon Creek Road 

Center Valley, PA 18034-9004 

PHONE (610) 974-8100 

FAX (610) 974-8104 

COMPANY: Environmental Service Laboratories, Inc 

ADDRESS: 1803 Philadelphia St 

PHONE: 

FAX: 

Indiana, PA 15701 

(724) 463-8378 

(724) 465-4209 

TEST REPORT 

WO#: 

PAGE: 

PO#: 

PWSID# 

Work Order: 10081066 

10081066 

5 of6 

DAS0407201 0 

RECEIVED FOR LAB BY: MAK DATE: 08/06/2010 9:35 Page 5 of6 

SAMPLE: 10 24747 Lab 10: 10081066-005A Grab 

SAMPLED BY: David Stiles Sample Time 08/01/2010 10:30 

illl ~ Uncert. .MQA .!.!.nil! ~ 

EPA 900.0 

EPA 900.0 

MCL Anatvsls Start Analysis End ~ 

06/10/10 9:00 08/13/10 BPS-CV 

08/10/10 9:00 08/13/10 BPS-CV 

Gross Alpha 4436 ± 613.7 1266.00 pCi/L 

Gross Beta 2365 ± 537.0 1535.00 pCVL 

REMARKS: 

Where the analytical method has been perfonned under NELAP certification, the analysis has met all of the requirements of 

the NELAC standard unless otherwise noted on the Analytical Report. 

• CV = Benchmark Analytics, Inc. Center Valley, PA; SA = Benchmark Analytics, Inc. Sayre, PA 

MANAGER ------------~ --~·~~~---------------------- DATE: ___ 8_n_5_a_o_JO ____ _ 
Name: 

f:; 

a·· ·

A.H 

• .._. •• 

i! II! fie-"'1 

~ 1 ... a 

~ i i1. !H.:~ i-t 1\ i Mli' "-·• I •• a •.. . • .... 11· .-,. • il W W' •• -.~I ._IW'I_.I. .. 1• ..__.. 

SERVICE lABORATORIES, INC. 1 rD3 Fhi:OdelphiO St" lr.dl~ria.. PA 15701 

(72~) 463·TI:ST (724) 46.54209 

Sample Start Date: 

Chesapeake Appalachia, LLC 

900 Pennsylvania Avenue 

Attn: Mr. Eric Gillespie 

Charleston, WV 25302 

8/112010 

Receipt Date: 8/3/2010 4:37PM 

Report Date: 8/5/2010 

Analyte Analyst Analysis 

Date 

I) Benzene RO 08/04 

47) Toluene RO 08/04 

Comments: 

DEP Certification #s 32-00382 

Report of Analysis 

Analysis Sample 

Time Result 

n/a ND 

n/a ND 

Sample ID#: 

Sample Type: 

Sample Source: 

Sampler: 

10 24748 

Waste Water 

Grab 

CLIENT (Client) 

Client Sample ID: 831202 Brine Water Trip Blank 

Units Data Method RPL 

Qualifier 

ug/L n/a 624/8260B 1.00 

ug/L nla 624/8260B 1.00 

jND=Not Detected 

Data Qualifiers: 

R 

D 

= 

=The 

Sample 

reported value is from dilution. E = Estimated value. S =Surrogate out of control limits. 

B = Analyte was 

received 

detected 

out of 

in 

holding 

both sample 

time. 

and 

H 

methods 

= Sample analyzed out of holding time. C = Sample received in incorrect container. 

blank. X= User defined data qualifier. 

Page 1 of 1 
Metrohm 

USA ln(. 

Sample Results Su.m1nary 

Environmental Service Labs, Inc - Indiana, PA 

Lab Report 201 0-1636 

Results Prepared for: Michael Moyer I Kathy Brown 

August 9, 2010 

MUSAJob # Sample ID Ethylene Glycol 

mg/Kg 

1636-1 10 24747 < 25.500 

1636-2 10 24750 270.738 

1636-2 Dup 10 24750 Dup 276.245 

Mean 273.492 

QC 74.466 

QC Value 77.583 

%Recovery 95.982 

Instrument Detection Limit 5.000 

Sample Detection Limit varies by dilution 

Report by: 4 ~ "fho. ·l k 

6555 Pelican Creek Circle, Riverview, FL 33578 813-316-4777 
ENVIRONMENTAL SERVICE 

LABORATORIES INC. SAMPLE REQUEST & CHAIN OF CUSTODY 

HEADQUARTERS: SOUlllERN DIVISION: 

1 803 Philadelphia St 1276 Bentleyville Road D Indiana, PA 15701 Van Voorhis, PA 15366 (724) 463-TEST (724) 258-TEST 'T .•. I . , .. 

(724) 465-4209 (724) 258-8376 

FOR INTERNAL LABORATORY USE ONLY f-.. 

j •• -

Sample Identification I ESL# I Composite I Grab I 

TRIP BLANK 

1)-

Date/ Time 

N OF CUSTODY SEAL BROKEN: Yes No 

-' . I.., 

·-

.,_);\j (b 

\0 

Matrix I # of Containers I 

ww I 1 I 

ww I Jl3 I ww I 1 I 

INVV I 1 I 

ww I 2 I ww I 1 I ww I 1 I 

INVV I 2 I INVV 

I 

2 

Water 2 I 

1\l ' .. 

N 

f\J 

Container Type 

Preservative 

Plastic Liter 

none 

Plastic Liter 

none 

Plastic Liter 

HNO, 

---

Plastic Liter 

H2so. 

Plastic Liter 

HNO, 

---

Amber Glass L 

HCI 

-

Amber Glass L 

H,so. 

Amber VOA Vials 

none 

Amber VOA Vials 

HCI 

1\...,...J.. ....... \Ir 

Company/Name: 

Person: 

Ch

90
ENV!RONr'v1ENTAL 

SERVICE LABORATORIES, INC. 

1 003 Phladephlo St., lrdiano, PA 15701 

(724) 463-TEST (724}A65-420Q 

Name: 

Sample Start Date: 

Receipt Date: 

Report Date: 

Chesapeake Appalachia, LLC 

900 Pennsylvania Avenue 

Attn: Mr. Eric Gillespie 

Charleston, WV 25302 

7/16/2010 12:44 PM 

7/20/2010 4:24PM 

10/6/2010 

Analyte Analyst Analysis 

Date 

Acidity to pH=8.3 BF 07/27 

Alkalinity to pH=4.5 BF 07/30 

Biological Oxygen Demand 05 LMB 07/21 

Chemical Oxygen Demand ZTR 08/03 

Ammonia as N I Distilled ZTR 07/29 

Chloride BF 08/04 

Kjeldabl Nitrogen as N MAD 08/02 

pH(SM) AO 07/22 

Sulfate ASTM ZTR 08/02 

Total Nitrate+ Nitrite as N AJD 07/28 

Aluminum - ICP GJT 0&104 

Arsenic-ICP GJT 08/03 

Barium- ICP GJT 0&/03 

Beryllium - ICP GJT 08/04 

Boron AJD 07/27 

Cadmium - ICP GJT 08/04 

Calcium - ICP GJT 08/03 

Chromium - ICP GJT 08/03 

Cobalt- ICP GJT 08/03 

Copper- ICP GJT 08/03 

Hardness GJT 08/03 

Report of Analysis 

Analysis Sample 

Time Result 

n/a ND 

n/a 235 

8:00AM 79.8 

n/a 153.0 

n/a 0.98 

n/a 157.5 

n/a 5.7 

n/a 6.98 

n/a 70 

n/a &.90 

n!a 1.702 

nla ND 

n/a 470.850 

n/a ND 

n/a ND 

n/a ND 

n/a 15&5.850 

n/a 0.750 

n/a ND 

n/a 2.500 

n/a 6156 

SampleiD#: 

Sample Type: 

Sample Source: 

Sampler: 

10 22788 

Waste Water 

Grab 

Client Sample ID: 

CLIENT (Client) 

831596 Drill Water 

Units Data Method 

Qualifier 

mg/1 as CaC03 n/a SM2310B 

mg/1 as CaC03 n/a SM2320B 

mg/1 E SM5210B 

mg/1 D SM5220D 

mg/1 n/a SM4500NH3B & D 

mg/1 n/a SM4500ClC 

mg/1 n/a SM4500Norg-C,D 

su n/a SM4500H-B 

mg/1 D D516-02 

mg/1 D SM4500N03E 

mg/1 n/a 200.7/6010 

mg/1 n/a 200.7/6010 

mg/1 n/a 200.7/6010 

mg/1 n/a 200.7/6010 

mg/1 n/a SM4500B-B 

mg/1 n/a 200.7/6010 

mg/1 n/a 200.7/6010 

mg/1 n/a 200.7/6010 

mg/1 n/a 200.7/6010 

mg/1 n/a 200.7/6010 

mg/1 n/a SM2340B 

RPL 

2 

20 

2.0 

100.0 

0.89 

1.0 

3.5 

0.01 

50 

0.50 

0.010 

0.500 

0.250 

0.005 

0.25 

0.005 

25.000 

0.250 

0.250 

0.250 

I 

f D=Not Detected 

DEP Certification #s 32-00382 

Data Qualifiers: D =The reported value is from dilution. E = Estimated value. S =Surrogate out of control limits. 

R =Sample received out of holding time. H = Sample analyzed out of holding time. C =Sample received in incorrect container. 

B = Analyte was detected in both sample and methods blank. X = User defined data qualifier. 

Page 1 of3 
Name: 

Sample Start Date: 

Receipt Date: 

Report Date: 

Analyte 

Iron- ICP 

Iron,Dissolved-I CP 

Lead-ICP 

Lithium - ICP 

Magnesium-ICP 

Manganese- ICP 

Mercury 

Nickel- ICP 

Selenium-ICP 

Silver-ICP 

Sodium- ICP 

Strontium - ICP 

Zinc- ICP 

Osmotic Pressure 

Chesapeake Appalachia, LLC 

900 Pennsylvania A venue 

Attn: Mr. Eric Gillespie 

Charleston, WV 25302 

7/16/2010 12:44 PM 

7/20/2010 4:24PM 

10/6/2010 

Analyst Analysis 

Date 

GJT 08/03 

GJT 08/03 

GJT 08/03 

GJT 08/04 

GJT 08/03 

GJT 08/03 

DRM 07/21 

GJT 08/03 

GJT 08/04 

GJT 08/03 

GJT 08/04 

GJT 08/05 

GJT 08/03 

AID 07/28 

Prep-2, Metals Digestion DMM 07/21 

Detergents, MBAS TL 07/22 

Oil and Grease - HEM CLM 08/05 

Phenolics, as Phenol AID 08/05 

Specific Conductance AO 07/22 

Total Dissolved Solids (TDS) LMB 07/23 

Total Suspended Solids LMB 07/23 

Report of Analysis 

Analysis Sample 

Time Result 

nla 135.750 

n/a 10.800 

n/a 0.650 

n/a ND 

n/a 533.200 

n/a 4.300 

n/a NO 

n/a 0.550 

n/a 0.046 

n/a ND 

n/a 167.040 

n/a 1.812 

n/a 2.100 

n/a ND 

11:35AM D 

1:34PM 0.302 

n/a ND 

n/a ND 

n/a 1069 

n/a 557 

n/a 120 

SampleiD#: 

Sample Type: 

Sample Source: 

Sampler: 

10 22788 

Waste Water 

Grab 

Client Sample ID: 

CLIENT (Client) 

831596 Drill Water 

Units Data Method 

Qualifier 

mg/1 n/a 200.7/6010 

mg/1 n/a 200.7/6010 

mg/1 n/a 200.7/6010 

mg/1 n/a 200.7/6010 

mg/1 n/a 200.7/6010 

mg/1 n/a 200.7/6010 

mg/1 n/a 245.1 

mg/1 n/a 200.7/6010 

mgll n/a 200.7/6010 

mgll n/a 200.7/6010 

mg/1 n/a 200.7/6010 

mg/1 n/a 200.7/6010 

mg/1 n/a 200.7/6010 

mOs/kg n/a OSP 

none n/a 3010A/3020A/3015 

mg/1 n/a SM5540C 

mgll n/a 1664A 

mgll D 420.1 

uS/em n/a SM2510B 

mg/1 n/a SM2540C 

mg/1 n/a SM2540D 

RPL 

0.500 

0.500 

0.250 

0.500 

25.000 

0.250 

0.0002 

0.250 

0.010 

0.250 

5.000 

0.010 

0.250 

100 

1 

0.200 

5.0 

0.500 

1 

25 

5 

jND=Not Detected 

DEP Certification #s 32-00382 

Data Qualifiers: D =The reported value is from dilution. E = Estimated value. S = Surrogate out of control limits. 

R = Sample received out of holding time. H = Sample analyzed out of holding time. C =Sample received in incorrect container. 

B = Analyte was detected in both sample and methods blank. X = User defined data qualifier. 

Page 2 of 3 
Name: 

Sample Start Date: 

Receipt Date: 

Report Date: 

Analyte 

1) Benzene 

47) Toluene 

Chesapeake Appalachia, LLC 

900 Pennsylvania Avenue 

Attn: Mr. Eric Gillespie 

Charleston, WV 25302 

7/16/2010 12:44 PM 

7/20/2010 4:24PM 

10/6/2010 

Analyst Analysis 

Date 

RO 07/21 

RO 07/21 

Report of Analysis 

Analysis Sample 

Time Result 

n!a ND 

n!a ND 

Sample ID#: 

Sample Type: 

Sample Source: 

Sampler: 

10 22788 

Waste Water 

Grab 

Client Sample ID: 

CLIENT (Client) 

831596 Drill Water 

Units Data Method 

Qualifier 

ug!L n!a 624/8260B 

ug!L n!a 624/8260B 

RPL 

20.00 

20.00 

Comments: 

jND=Not Detected 

DEP Certification #s 32-00382 

Data Qualifiers: D = The reported value is from dilution. E = Estimated value. S = Surrogate out of control limits. 

B 

R 

= 

= 

Analyte 

Sample 

was 

received out of holding time. H = Sample analyzed out of holding time. C = Sample received in incorrect container. 

detected in both sample and methods blank. X = User defined data qualifier. 

Page 3 of3 
ENVIRON~J!ENTAl 

SERVICE LABORATORIES, INC. 

1003 Fhlode~hlo st., lrdiano, PA 15701 

(72.:1) 463-"TEST (724) 465-4209 

Name: 

Sample Start Date: 

Receipt Date: 

Report Date: 

Analyte 

Ethylene Glycol 

Radiologicals 

Chesapeake Appalachia, LLC 

900 Pennsylvania Avenue 

Attn: Mr. Eric Gillespie 

Charleston, WV 25302 

7/16/2010 12:44 PM 

7/20/2010 4:24PM 

10/6/2010 

Analyst Analysis 

Date 

!MetPeak 07/27 

enchmru 07/30 

Report of Analysis 

Analysis Sample 

Time Result 

n/a 80.453 

n/a * 

SampleiD#: 

Sample Type: 

Sample Source: 

Sampler: 

10 22789 

Waste Water 

Grab 

Client Sample ID: 

CLIENT (Client) 

831596 Drill Water 

Units Data Method 

I Qualifier 

mglkg n/a 300.0M 

mg/1 n/a RAD-CTDHS 

RPL 

25.000 

0.000 

Comments: Radiologicals done by Benchmark Analytical, PADEP Lab ID: 39-00401 Ethylene Glycol subcontracted 

to Metrohm-Peak, ISO# 10001397QM08 jND=Not Detected 

Note: DEP Certification #s 32-00382 

Data Qualifiers: D =The reported value is from dilution. E = Estimated value. S = Surrogate out of control limits. 

R = Sample received out of holding time. H = Sample analyzed out of holding time. C = Sample received in incorrect container. 

B = Analyte was detected in both sample and methods blank. X= User defined data qualifier. 

Page 1 of 1 

------
LAB ID: 39-00401 

SEND DATA TO: 

NAME: Kathy Brown 

BENCHMARK ANAL YTICS, INC. 

4777 Saucon Creek Road 

Center Valley, PA 18034-9004 

PHONE (610) 974-8100 

FAX (610) 974-8104 

Work Order: 10073819 

WO#: 

COMPANY: 

ADDRESS: 

Environmental Service Laboratories, Inc 

1803 Philadelphia St PAGE: 

10073819 

1 of 1 

Indiana, PA 15701 

PHONE: 

FAX: 

(724) 463-8378 

(724) 465-4209 

10 22789 

RECEIVEO FOR LAB BY: MAK 

SAMPLE: 10 22789 

SAMPLED BY: Client 

illl 

Gross Alpha 

Gross Beta 

Combined Activity 

(Alpha + Beta) 

REMARKS: 

Result 

16.61 

32.49 

49.10 

Uncert. 

:t 4.26 

:t 3.66 

PO#: 

TEST REPORT PWS ID# 

DATE: 07/23/2010 9:45 Page 1 of 1 

Lab 10: 10073B19.{)01A Grab 

Sample Time 07/16/2010 12:44· 

MQA Unjts Method MCL Analysis Start Analysis End Anatvst " 

6.30 pCi/L EPA 900.0 07/26/10 9:05 07/29/10 BPS-CV 

7.21 pCUL EPA 900.0 07/26/10 9:05 07/29/10 BPS-CV 

pCi/L Calculation 07/30/10 15:02 BPS-CV 

the 

Where 

NELAC 

the analytical 

standard 

method has been performed under NELAP certification, the analysis has met all,of the requirements of 

unless otherwise noted on the Analytical Report. 

• CV = Benchmar1c Analytics, Inc. Center Valley, PA; SA = Benchmark Analytics, Inc. Sayre, PA 

MANAGER ----------~~--·~~ ~~~~~·--__________________ DATE: ____ JO IO ____ _ 
Name: 

Sample Start Date: 

Receipt Date: 

Report Date: 

Analyte 

1) Benzene 

47) Toluene 

Chesapeake Appalachia, LLC 

900 Pennsylvania A venue 

Attn: Mr. Eric Gillespie 

Charleston, WV 25302 

7/16/2010 

7/20/2010 4:24PM 

7/22/2010 

Analyst 

RO 

RO 

Analysis 

Date 

07/21 

07/21 

Report of Analysis 

Analysis Sample 

Time Result 

nla ND 

nla ND 

SampleiD#: 

Sample Type: 

Sample Source: 

Sampler: 

10 22790 

Waste Water 

Grab 

Client Sample ID: 

CLIENT (Client) 

Trip Blank 

Units Data Method 

Qualifier 

ug!L nla 624/8260B 

ug!L n/a 624/8260B 

RPL 

1.00 

1.00 

Comments: jND=Not Detected 

DEP Certification #s 32-00382 

Data Qualifiers: D =The reported value is from dilution. E =Estimated value. S =Surrogate out of control limits. 

R =Sample received out of holding time. H = Sample analyzed out of holding time. C = Sample received in incorrect container. 

B = Analyte was detected in both sample and methods blank. X= User defined data qualifier. 

Page 1 of 1 
ENVIRONMENTAL SERVICE 

LABORATORIES, INC. SAMPLE REQUEST & CHAIN OF CUSTOD

HEADQUARTERS: SOI.IlMERN DMSION: 

1803 Philadelphia Sl 1276 Bentleyville Road ~-. :-·.:~ c--: ~·.:· F:-:,\//":...-! I() f"\J 

Indiana, PA 15701 M D Van Voorhis, PA 15366 (724) 463-TEST (724) 258-TEST "<'' '·-·· ·,I 1 .} .- /~ C) c~ (724) 465-4209 (724) 258-8376 

FOR INTERNAL LASORA TORY USE ONLY 

Sample Identification ESL# 

.. 

TRIP BLANK 

L09~~~ 

THESE SERVICE CHARGES v.ILL ACCRUE AT THE RATE OF 1 112% PER MONTH (16% PER ANNUM OR 1l1E MI\XJMUM Al.LO\M:D BY LAW.) 

THE UNDERSIGNED PURCHASER AGREES TO PAY, IN 1l1E EVENT HIS ACCOUNT BECOMES DEUNQUENT AND IS TURNED OVER TO ANY 

REASONABLE ATTORNEY'S FEES PLUS Al.L COURT AND ATTENDANT COLLECTION COSTS. 

::ftAn.e. ~O,a£>10 l \\5 Tim~:~ Date/ . ····-

Date/ Time 

OF CUSTODY SEAL BROKEN: Yes No 

./ /, !"\. l ~:~ ::<. 

Matrix # of Containers 

WN 

-

WN ~3 -

WN 

-

WN 

-

WN 2 

-

WN 

-

WN 

-

WN 2 

-

WN 2 

Water 2 

(2) N 

(y) 

G) 

N N/A 

N 

Container Type 

Preservative 

Plastic Uter 

none 

Plastic Uter 

none 

Plastic Liter 

HN03 

Plastic Liter 

H2S04 

Plastic Liter 

HN03 

Amber Glass L 

HCI 

Amber Glass L 

H2SO, 

Amber VOA Vials 

none 

Amber VOA Vials 

HCI 

Amber VOA Vials 

HCI 

Company/Name: 

C

90
Name: 

Sample Start Date: 

Receipt Date: 

Report Date: 

Analyte 

Acidity to pH=8.3 

Chesapeake Appalachia, LLC 

900 Pennsylvania A venue 

Attn: Mr. Eric Gillespie 

Charleston, WV 25302 

6/30/2010 11:15 AM 

7/2/2010 2:41PM 

10/11/2010 

Analyst Analysis 

Date 

BF 07/12 

Alkalinity to pH=4.5 ZTR 07/18 

Biological Oxygen Demand 05 szc 07/02 

Chemical Oxygen Demand ZTR 07/06 

Ammonia as N I Distilled MAD 07/09 

Chloride BF 07/08 

Kjeldabl Nitrogen as N AID 07/16 

pH(SM) LL 07/06 

Sulfate ASTM ZTR 07/12 

Total Nitrate+ Nitrite as N MAD 07/16 

Aluminum - ICP GJT 07/27 

Arsenic-ICP GJT 07/27 

Barium- ICP GJT 07/23 

Beryllium - ICP GJT 07/27 

Boron MAD 07/07 

Cadmium - ICP GJT 07/27 

Calcium - ICP GJT 07/23 

Chromium- ICP GJT 07/27 

Cobalt- ICP GJT 07/23 

Copper- ICP GJT 07/23 

Hardness GJT 07/27 

Report of Analysis 

Analysis Sample 

Time Result 

n/a ND 

n/a 564 

3:00PM 1119.0 

n/a 2470.0 

n/a 4.10 

n/a 14903.4 

n/a 7.2 

n/a 11.66 

n/a 370 

n/a 0.06 

n/a 44.100 

n/a ND 

n/a 4.900 

n/a ND 

n/a ND 

n/a ND 

n/a 693.400 

n/a ND 

n/a ND 

n/a 0.650 

n/a 1858 

Sample ID#: 

Sample Type: 

Sample Source: 

Sampler: 

10 20502 

Waste Water 

Grab 

Client Sample ID: 

CLIENT (Client) 

627044 Drill Water 

Units Data Method 

Qualifier 

mg/1 as CaC03 n/a SM2310B 

mg/1 as CaC03 n/a SM2320B 

mg/1 n/a SM5210B 

mg/1 D SM5220D 

mg/1 n/a SM4500NH3B&D 

mg/1 n/a SM4500ClC 

mg/1 D SM4500Norg-C,D 

su n/a SM4500H-B 

mg/1 D D516-02 

mg/1 n/a SM4500N03E 

mg/1 n/a 200.7/6010 

mg/1 n/a 200.7/6010 

mg/1 n/a 200.7/6010 

mg/1 n/a 200.7/6010 

mg/1 n/a SM4500B-B 

mg/1 n/a 200.7/6010 

mg/1 n/a 200.7/6010 

mg/1 n/a 200.7/6010 

mg/1 n/a 200.7/6010 

mg/1 n/a 200.7/6010 

mg/1 n/a SM2340B 

RPL 

2 

20 

2.0 

500.0 

0.09 

1.0 

4.5 

0.01 

50 

0.05 

0.500 

0.500 

0.250 

0.250 

0.25 

0.250 

25.000 

0.250 

0.250 

0.250 

I 

Comments: Ethylene Glycol subcontracted to Metrohm-Peak, ISO# 10001397QM08 Radiologicals done by 

Benchmark Analytical, PADEP Lab ID: 39-00401 

IND=Not Detected 

DEP Certification #s 32-003 82 

Data Qualifiers: D =The reported value is from dilution. E = Estimated value. S =Surrogate out of control limits. 

R = Sample received out of holding time. H =Sample analyzed out of holding time. C =Sample received in incorrect container. 

B = Analyte was detected in both sample and methods blank. X = User defined data qualifier. 

Page 1 of 3 
ENVIRON~.r1ENTAL SERVICE LABORATORIES, INC. 

1 003 Phl::lde~hla St:, lrdk:ina. PA 15701 

(724) 463-TEST (724) 465420Q 

Name: 

Sample Start Date: 

Receipt Date: 

Report Date: 

Analyte 

Iron- ICP 

Iron,Dissolved-ICP 

Lead-ICP 

Lithium- ICP 

Magnesium-ICP 

Manganese - ICP 

Mercury 

Nickel- ICP 

Selenium-ICP 

Silver-ICP 

Sodium- ICP 

Strontium - ICP 

Zinc- ICP 

Osmotic Pressure 

Chesapeake Appalachia, LLC 

900 Pennsylvania Avenue 

Attn: Mr. Eric Gillespie 

Charleston, WV 25302 

6/30/2010 11:15 AM 

7/2/2010 2:41PM 

10/11/2010 

Analyst Analysis 

Date 

GJT 07/23 

GJT 07/23 

GJT 07/23 

GJT 08/02 

GJT 07/27 

GJT 07/23 

DRM 07/07 

GJT 07/23 

GJT 07/23 

GJT 07/23 

GJT 07/28 

GJT 08/02 

GJT 07/23 

MAD 07/07 

Prep-2, Metals Digestion. DMM 07/08 

Detergents, MBAS TL 07/02 

Oil and Grease - HEM CLM 07/20 

Phenolics, as Phenol AID 07/14 

Specific Conductance LL 07/06 

Total Dissolved Solids (TDS) LMB 07/05 

Total Suspended Solids LMB 07/05 

Report of Analysis 

Analysis Sample 

Time Result 

n/a 86.300 

n/a 0.850 

n/a 0.350 

n/a ND 

n/a 30.850 

nla 2.150 

n/a ND 

n/a ND 

n/a ND 

n/a ND 

n/a 10847.000 

n/a 8.450 

n/a 0.900 

nla 786 

4:17PM D 

2:16PM 10.500 

nla 14.0 

n!a ND 

nla 41800 

nla 27500 

nla 412 

Sample ID#: 

Sample Type: 

Sample Source: 

Sampler: 

10 20502 

Waste Water 

Grab 

Client Sample ID: 

CLIENT (Client) 

627044 Drill Water 

Units Data Method 

Qualifier 

mg/1 n/a 200.7/6010 

mg/1 n/a 200.7/6010 

mg/1 n/a 200.7/6010 

mg/1 n/a 200.7/6010 

mg/1 n/a 200.7/6010 

mg/1 n/a 200.7/6010 

mg/1 D 245.1 

mg/1 n/a 200.7/6010 

mg/1 n/a 200.7/6010 

mg/1 n/a 200.7/6010 

mg/1 n/a 200.7/6010 

mg/1 n/a 200.7/6010 

mg/1 n/a 200.7/6010 

mOs/kg n/a OSP 

none n!a 3010A/3020AJ3015 

mg/1 nla SM5540C 

mg/1 n!a 1664A 

mg/1 D 420.1 

uS/em n!a SM2510B 

mg/1 n/a SM2540C 

mg/1 n!a SM2540D 

RPL 

0.500 

0.500 

0.250 

25.000 

25.000 

0.250 

0.0020 

0.250 

0.500 

0.250 

500.000 

0.500 

0.250 

100 

1 

2.000 

5.0 

0.500 

1 

25 

5 

Comments: Ethylene Glycol subcontracted to Metrohm-Peak, ISO# 10001397QM08 Radiologicals done by 

Benchmark Analytical, PADEP Lab ID: 39-00401 IND=Not Detected 

DEP Certification #s 32-00382 

Data Qualifiers: D =The reported value is from dilution. E = Estimated value. S =Surrogate out of control limits. 

R = Sample received out of holding time. H =Sample analyzed out of holding time. C = Sample received in incorrect container. 

8 = Analyte was detected in both sample and methods blank. X = User defined data qualifier. 

Page 2 of3 
ENVIRONl\1ENTAl 

SERVICE LABORATORIES. INC. 

1003 PhJade'phio St., lrdbno. PA 15701 

(72£1) 463-lEST (724) .<f6.5.420'1I 

Name: 

Sample Start Date: 

Receipt Date: 

Report Date: 

Analyte 

1) Benzene 

47) Toluene 

Chesapeake Appalachia, LLC 

900 Pennsylvania Avenue 

Attn: Mr. Eric Gillespie 

Charleston, WV 25302 

6/30/2010 11:15 AM 

7/2/2010 2:41 PM 

1011112010 

Analyst Analysis 

Date 

RO 07/02 

RO 07/02 

Report of Analysis 

Analysis Sample 

Time Result 

nla ND 

n!a ND 

SampleiD#: 

Sample Type: 

Sample Source: 

Sampler: 

10 20502 

Waste Water 

Grab 

Client Sample ID: 

CLIENT (Client) 

627044 Drill Water 

Units Data Method 

I Qualifier 

ug!L nla 624/8260B 

ug!L nla 624/8260B 

RPL 

10.00 

10.00 

Comments: Ethylene Glycol subcontracted to Metrohm-Peak, ISO# 10001397QM08 Radiologicals done by 

Benchmark Analytical, PADEP Lab ID: 39-00401 

IND=Not Detected 

DEP Certification #s 32-00382 

Data Qualifiers: D =The reported value is from dilution. E = Estimated value. S = Surrogate out of control limits. 

R =Sample received out of holding time. H = Sample analyzed out of holding time. C =Sample received in incorrect container. 

B = Analyte was detected in both sample and methods blank. X = User defined data qualifier. 

Page 3 of 3 
ENVIRON~1ENTAL SEfMCE LABORATORIES. INC. 

1 e03 Phlcx:Je~hio St., lrdlanQ. PA 15701 

(724) 463-TEST (724) 465-420Q 

Name: 

Sample Start Date: 

Receipt Date: 

Report Date: 

Analyte 

Ethylene Glycol 

Radiologicals 

Chesapeake Appalachia, LLC 

900 Pennsylvania A venue 

Attn: Mr. Eric Gillespie 

Charleston, WV 25302 

6/30/2010 11:15 AM 

7/2/2010 3:01PM 

10/11/2010 

Analyst Analysis 

Date 

IMetPeal< 07/13 

enchmru 07/22 

Report of Analysis 

Analysis Sample 

Time Result 

n/a 177.664 

n/a * 

Sample ID#: 

Sample Type: 

Sample Source: 

Sampler: 

10 20521 

Waste Water 

Grab 

Client Sample ID: 

CLIENT (Client) 

627044 Drill Water 

Units Data Metbod 

I Qualifier 

mg/kg n/a 300.0M 

mg/1 n/a RAD-CTDHS 

RPL 

5.000 

0.000 

Comments: Ethylene Glycol subcontracted to Metrohm-Peak, lSO # 10001397QM08 Radiologicals done by 

Benchmark Analytical, PADEP Lab ID: 39-00401 [ND=Not Detected 

DEP Certification #s 32-00382 

Data Qualifiers: D =The reported value is from dilution. E = Estimated value. S = Surrogate out of control limits. 

R =Sample received out of holding time. H = Sample analyzed out of holding time. C =Sample received in incorrect container. 

B = Analyte was detected in both sample and methods blank. X = User defined data qualifier. 

Page 1 of 1 
LAB ID: 39-00401 

>END DATA TO: 

~AME: Kathy Brown 

BENCHMARK ANAL YTICS, INC. 

4 777 Saucon Creek Road 

Center Valley, PA 18034-9004 

PHONE (610) 974-8100 

FAX (610) 974-8104 

~OMPANY: Environmental Service Laboratories, Inc 

1DDRESS: 1803 Philadelphia St 

HONE: 

AX: 

Indiana, PA 15701 

(724) 463-8378 

(724) 465-4209 

0 20557 & 20251 

TEST REPORT 

WO#: 

PAGE: 

PO#: 

PWS ID# 

Work Order: 10071120 

10071120 

2 of2 

ECEIVED FOR LAB BY: JEC DATE: 07/08/2010 9:40 Page2 of2 

\MPLE: 10 20521 

SAMPLED BY: Client 

~ 

Gross Alpha 

Gross Beta 

ARKS: 

Lab ID: 10071120-002A Grab 

Sample Time 06/30/2010 11:15 

~ Uncert. MDA Unjts 

255.9 ± 136.5 395.20 pCiiL 

1221 ± 171.3 384.20 pCi/L 

Method 

EPA 900.0 

EPA 900.0 

MCL Analysis Start Analysis End Analyst * 

07/19/10 9:00 07/22110 BPS-CV 

07/19110 9:00 07/22/10 BPS-CV 

NELAC 

·ere the analytical method has been performed under NELAP certification, the analysis has met all of the requirements of 

standard unless otherwise noted on the Analytical Report. 

v == Benchmark Analytics, Inc. Center Valley, PA; SA== Benchmari< Analytics, Inc. Sayre, PA 

\GER ------------~--~·~~~~~--__________________ DATE: ____ 28 10 ____ _ 
~arne: 

t.:;r. nJ•n,.,.~..Jr;.•:u:·~~.. ~TJ; 1 •· · l'\J ' : .-.;< 1.. J ;\, • '' • m I\.; • ...:., • lliil a: .. W I ....... ...._, 1 I w 1.._ • .. •• ,._..._ 

SERVICE LABORATORIES, INC. 

1 eD3 Fhib'Jelpt1ia St.,. lrdiano, PA 15701 

(72'~) 4.')..1-TEST (124) 465·4...?tN 

lample Start Date: 

~eceipt Date: 

teport Date: 

Chesapeake Appalachia, LLC 

900 Pennsylvania A venue 

Attn: Mr. Eric Gillespie 

Charleston, WV 25302 

6/30/2010 

7/2/2010 2:41PM 

7/6/2010 

Analyte Analyst Analysis 

Date 

1) Benzene RO 07/02 

47) Toluene RO 07/02 

:omments: 

DEP Certification #s 32-00382 

Report of Analysis 

Analysis Sample 

Time Result 

n/a ND 

n/a ND 

Sample ID#: 

Sample Type: 

Sample Source: 

Sampler: 

10 20503 

Waste Water 

Grab 

CLIENT (Client) 

Client Sample ID: 627044 Drill Water Trip Blank 

Units Data Method RPL 

Qualifier 

ug/L n/a 624/8260B 1.00 

ug/L n/a 624/8260B 1.00 

IND=Not Detected 

ata Qualifiers: D = The reported value is from dilution. E = Estimated value. S = Surrogate out of control limits. 

R = Sample received out of holding time. H = Sample analyzed out of holding time. C = Sample received in incorrect container. 

B = Analyte was detected in both sample and methods blank. X = User defined data qualifier. 

Page 1 of 1 
ENVIRONMENTAL SERVICE 

LABORATORIES, INC. SAMPLE REQUEST & CHAIN OF CUSTOD

HEADQUARlCRS: 

1803 Philadelphia Sl 

Indiana, PA 15701 

(724) 463-TEST 

(724) 465-4209 

00 SOUTliERN DIVISION: 1276 Bendeyville Road Van Voorhis, PA 15366 (724) 256-TEST 

(724) 258-8376 

FOR INTERNAL LAB ORA TORYUSEONL Y 

D 

Sample Identification ESL# 

y 

TRIP BLANK ,l,(?:/Ji ~~~ 

Matrix #of Containers 

WN 

--

WN .L3 

--

WN 

--

WN 

--

WN 2 

--

WN 

--

WN 

--

WoN 2 

--

WN 2 

Water 2 

Container Type 

Preservative 

Plastic Liter 

none 

Plastic Liter 

none 

Plastic Liter 

HN03 

Plastic Liter 

H2SO, 

Plastic Liter 

HN03 

Amber Glass L 

HCI 

Amber Glass L 

H2SO, 

Amber VOA Vials 

none 

Amber VOA Vials 

HCI 

Amber VOA Vials 

HCI 

r \ 

THESE SERVICE CHARGES 'I'IIU. ACCRUE AT THE RATE OF 1 112% PER MONTH (18% PER ANNUM OR THE MAXIMUM ALLOWED BY lAW,) 

THE UNDERSIGNED PURCHASER AGREES TO PAY,IN THE EVENT HIS ACCOUNT BECOMES DEUNQUENT AND hS TURNED OVER TO ANY 

REASONABLE AITORNEY"S FEES PLUS ALL COURT AND AITENOANT COLLECTION COSTS. ,\Q. 

Company/Name: C

/l :_ ~ - -( - f. iV. 1£; !Address: 

. l 

90

u f/ vc. <~/ 

-~&0'::&..1 v-· us -ru 

1

contact Person: 

~Af"'_gl\Md Bv: ~~~~--;-;;y- ..,/I......,..-- 1:7 ~-·-• ~-- Phone: 

Date/ Time 

'F-iM:;;;;;:;;-J:-h:· :; .. ;; ..;;:::;:::\----------------l Contact Person: 

Date/ Time Phone: 

N OF CUSTODY SEAL BROKEN: Yes No Fax: 
RECEIVED 

t! 

•-- .. 

~ ,. 

i \ 

a.r i I 

•~• 

ht~~ ~ i if i: :\.iT;:-'& 3 JUL 2 2 2010 .- ,.•"••'9e•il"•·· •·"'• •. .-.a :L .. W: r ., ~II !WI W .... I:.._ I• 'l.a.i 

SERVICE LABORATORIES, INC. 

1 E03 fN ooelphiO St., lrtJiona. PA 15701 

(724) 46..'3-TEST (724) A0.'>-420? REGULATORY 

Name: 

Sample Start Date: 

Receipt Date: 

Report Date: 

Analyte 

Acidity to pH=8.3 

Chesapeake Appalachia, LLC 

900 Pennsylvania Avenue 

Attn: Mr. Eric Gillespie 

Charleston, WV 25302 

6/16/2010 2:45PM 

6/18/2010 2:24PM 

7/14/2010 

Analyst Analysis 

Date 

BF 06/21 

Alkalinity to pH=4.5 BF 06/28 

Biological Oxygen Demand 05 szc 06/19 

Chemical Oxygen Demand ZTR 06/23 

Ammorua as N I Distilled AID 06/28 

Chloride BF 06/29 

Kjeldah1 Nitrogen as N MAD 07/06 

pH(SM) LL 06/18 

Sulfate ASTM ZTR 06/22 

Total Nitrate +Nitrite as N AID 06/30 

Aluminum- ICP GJT 06/29 

Arsenic-ICP GJT 06/29 

Barium- ICP GJT 06/29 

Beryllium - ICP GJT 07/03 

Boron MAD 06/23 

Cadmium - ICP GJT 06/29 

Calcium - ICP GJT 06/29 

Chromium - ICP GJT 06/29 

Cobalt- ICP GJT 06129 

Copper- ICP GJT 06/29 

Hardness GJT 06/29 

Report of Analysis 

Analysis Sample 

Time Res11lt 

n/a ND 

n/a 24908 

12:15 PM 186.0 

n/a 2670.0 

n/a 28.24 

n/a 502.2 

n/a 216.0 

n/a 8.36 

n/a ND 

n/a * 

n/a 6915.900 

n/a 4.200 

n/a 222.700 

n/a ND 

n/a 1.96 

n/a ND 

n/a 12460.000 

n/a 11.300 

n/a 1.800 

n/a 16.600 

n/a 46042 

Sample ID#: 

Sample Type: 

Sample Source: 

Sampler: 

10 18730 

Waste Water 

Grab 

Client Sample ID: 

CLIENT (Client) 

627043 Drill 

Units Data Method 

Qualifier 

mg/1 as CaC03 n/a SM2310B 

mg/1 as CaC03 n/a SM2320B 

mg/1 H SM52IOB 

mg/1 D SM5220 D 

mg/1 n/a SM4500NH3B & D 

mg/1 n/a SM4500ClC 

mg/1 n/a SM4500Norg-C,D 

su n/a SM4500H-B 

mg/1 0 D516-02 

mg/1 X SM4500N03E 

mg/1 n/a 200.7/6010 

mg/1 n/a 200.7/6010 

mg/1 n/a 200.7/6010 

mg/1 n/a 200.7/6010 

mg/1 D SM4500B-B 

mg/1 n/a 200.7/6010 

mg/1 n/a 200.7/6010 

mg/1 n/a 200.7/6010 

mg/1 n/a 200.7/6010 

mg/1 n/a 200.7/6010 

mg/1 n/a SM2340B 

RPL 

2 

20 

2.0 

1000.0 

9.11 

1.0 

56.9 

0.01 

25000 

0.05 

1.000 

1.000 

0.500 

0.500 

1.00 

0.500 

50.000 

0.500 

0.500 

0.500 

I 

Comments: Due to nature of sample, a dilution of I :5000 was needed to pass the background check for sulfates. The 

sample was then analyzed and the result was ND. ZTR 06/22/10 Possible Bias High BOD results DUE TO 

QAIQC FAILURE RO *Uable to analyze due to sample matrix. GJT 06/30/10 *Unable to analyze for 

Total Nitrate+ Nitrite due to sample matrix. (AID 06/30/2010) Ethylene Dibromide subcontracted to 

Metrohm-Peak, ISO# IOOOI397QM08 Radiologicals done by Benchmark Analytical, PADEP Lab ID: 39-

00401 Oil and Grease analyzed by method 9071 for solids due to sample matrix. CLM 07/14/10 

jND=Not Detected 

Note: DEP Certification #s 32-00382 

Data Qualifiers: D ==The reoorted value is from dilution . E == Estimated value. 
1 003 Pl'li1adephio St., IMionO. PA 15701 

(724) 463"TEST (724) i16!>-420? 

Name: 

Sample Start Date: 

Receipt Date: 

Report Date: 

Analyte 

Iron- ICP 

Iron,Dissolved-ICP 

Lead-ICP 

Lithium- ICP 

Magnesium-ICP 

Manganese - ICP 

Mercury 

Nickel- ICP 

Selenium-ICP 

Silver-ICP 

Sodium- ICP 

Strontium- ICP 

Zinc- ICP 

Osmotic Pressure 

Detergents, MBAS 

Ethylene Glycol 

Chesapeake Appalachia, LLC 

900 Pennsylvania Avenue 

Attn: Mr. Eric Gillespie 

Charleston, WV 25302 

6/16/2010 2:45PM 

6/18/2010 2:24PM 

7/14/2010 

Aoa_lyst Analysis 

Date 

GJT 07/03 

GJT 07/06 

GJT 06/29 

GJT 07/03 

GJT 06/29 

GJT 06/29 

DRM 06/23 

GJT 06/29 

GJT 06129 

GJT 06/29 

GJT 06/29 

GJT 07/06 

GJT 06/29 

GJT 07/06 

TL 06118 

IMetPeak 06/29 

Oil and Grease - HEM CLM 07/13 

Phenolics, as Phenol MAD 07/02 

Percent Total Solids DRM 06/28 

Specific Conductance LL 06/18 

Total Dissolved Solids (TDS) LMB 06/23 

Report of Analysis 

Analysis Sample 

Time Result 

n/a 17727.900 

n/a * 

n/a 8.000 

nla ND 

nla 3625.400 

n/a 345.200 

nla 0.0290 

nla 16.200 

nla ND 

nla ND 

nla 1114.100 

nla 54.300, 

n/a 38.300 

nla * 

10:19 AM ND 

nla <25.000 

nla 149.3 

n/a ND 

n/a 51 

n/a 1329 

nla 38000 

Sample ID#: 

Sample Type: 

Sample Source: 

Sampler: 

10 18730 

Waste Water 

Grab 

Client Sample ID: 

CLIENT (Client) 

627043 Drill 

Units Data Method 

Qualifier 

mg/1 n/a 200.7/6010 

mg/1 n/a 200.7/6010 

mg/1 n/a 200.7/6010 

mg/1 nla 200.7/6010 

mg/1 nla 200.7/6010 

mg/1 n/a 200.7/6010 

mg/1 n/a 245.1 

mg/1 n/a 200.7/6010 

mg/1 n/a 200.7/6010 

mg/1 n/a 200.7/6010 

mg/1 n/a 200.7/6010 

mg/1 n/a 200.7/6010 

mg/1 n/a 200.7/6010 

mOs/kg n/a OSP 

mg/1 n/a SM5540C 

mg/kg n/a 300.0 M 

mg/kg n/a 1664A 

mg/1 0 420.1 

% n/a SM2540B 

uS/em n/a SM2510B 

mg/1 n/a SM2540C 

RPL 

1.000 

0.010 

0.500 

50.000 

50.000 

0.500 

0.0200 

0.500 

1.000 

0.500 

50.000 

1.000 

0.500 

100 

0.200 

25.000 

5.0 

5.000 

5 

1 

25 

Comments: Due to nature of sample, a dilution of 1:5000 was needed to pass the background check for sulfates. The 

sample was then analyzed and the result was ND. ZTR 06/22/10 Possible Bias High BOD results DUE TO 

QNQC FAILURE RO *Uable to analyze due to sample matrix. GJT 06/30/10 *Unable to analyze for 

Total Nitrate+ Nitrite due to sample matrix. (AID 06/30/2010) Ethylene Dibromide subcontracted to 

Metrohm-Peak, ISO# 10001397QM08 Radiologicals done by Benchmark Analytical, PADEP Lab ID: 39-

00401 Oil and Grease analyzed by method 9071 for solids due to sample matrix. CLM 07/14110 

IND=Not Detected 

DEP Certification lis 32-00382 

------------------~01~ 

Data Qualifiers: D = The reported value is from dilution. E =Estimated value. S = SurroQate out of control limits. 
!;: t~! \!! Df"-:-1 i\J !\A~ i\J T A ! liiil.l -. W I .. "~ I 'WI"' & ... l ':II I tl 'li .. 

SERVICE lABORATORIES, INC. 

11'YJ3 Phl<XJept1ia Sl.. lrr.:1klna. PA 15701 

(72~) 46-'FTEST (724) 465-420? 

Name: 

Sample Start Date: 

Receipt Daie: 

Report Date: 

Analyte 

Chesapeake Appalachia, LLC 

900 Pennsylvania Avenue 

Attn: Mr. Eric Gillespie 

Charleston, WV 25302 

6/16/2010 2:45PM 

6/18/2010 2:24PM 

7/14/2010 

Analyst Analysis 

Date 

Total Suspended Solids LMB 06/23 

Radiologicals enchmar 07/03 

1) Benzene RO 06/18 

47) Toluene RO 06/18 

Report of Analysis 

Analysis Sample 

Time Result 

n/a 599000 

n/a * 

n/a ND 

n/a ND 

Sample ID#: 

Sample Type: 

Sample Source: 

Sampler: 

10 18730 

Waste Water 

Grab 

Client Sample ID: 

CLIENT (Client) 

627043 Drill 

Units Data Method 

Qualifier 

mg/1 n/a SM2540D 

mg/1 n/a RAD-CTDHS 

ug!L n/a 624/8260B 

ug!L n/a 624/8260B 

RPL 

5 

0.000 

50.00 

50.00 

Comments: Due to nature of sample, a dilution of 1 :5000 was needed to pass the background check for sulfates. The 

sample was then analyzed and the result was ND. ZTR 06/22110 Possible Bias High BOD results DUE TO 

QA/QC FAll.,URE RO *Uable to analyze due to sample matrix. GJT 06/30/10 *Unable to analyze for 

Total Nitrate+ Nitrite due to sample matrix. (AID 06/30/2010) Ethylene Dibromide subcontracted to 

Metrohm-Peak, ISO# 10001397QM08 Radiologicals done by Benchmark Analytical, PADEP Lab ID: 39-

00401 Oil and Grease analyzed by method 9071 for solids due to sample matrix. CLM 07/14/10 

IND=Not Detected 

DEP Certification #s 32-00382 

Data Qualifiers: D = The reported value is from dilution. E = Estimated value. S = Surrooate out of control limits. 
iCf\~\iJri~-~r-'L•~ ACf\it'i'. ~ 

~ . ~ ~ : ~ ~ = ~J r':: ~ t. ~ ~;. 

SERVICE tABORATORIES, INC. 

l e03 Pt•,OCX:Iept)ia Sl .. lrv..ilt:mo. PA 15701 

(724) 46.3-TEST (724) 465-420Q 

Name: 

Sample Start Date: 

Receipt Date: 

Report Date: 

Analyte 

Chesapeake Appalachia, LLC 

900 Pennsylvania Avenue 

Attn: Mr. Eric Gillespie 

Charleston, WV 25302 

6/16/2010 2:45 PM 

6/18/2010 2:24PM 

7/14/2010 

Analyst Analysis 

Date 

Total Suspended Solids LMB 06/23 

Radiologicals enclumu 07/03 

l) Benzene RO 06/18 

47) Toluene RO 06/18 

Report of Analysis 

Analysis Sample 

Time Result 

nla 599000 

n!a * 

n!a ND 

nla ND 

Sample ID#: 

Sample Type: 

Sample Source: 

Sampler: 

10 18730 

Waste Water 

Grab 

Client Sample ID: 

CLIENT (Client) 

627043 Drill 

Units Data Method 

Qualifier 

mgll n!a SM2540D 

mg/1 n!a RAD-CTDHS 

ug!L n!a 624/8260B 

ug!L n!a 624/8260B 

RPL 

5 

0.000 

50.00 

50.00 

Comments: Due to nature of sample, a dilution of 1:5000 was needed to pass the background check for sulfates. The 

sample was then analyzed and the result was ND. ZTR 06/22/10 Possible Bias High BOD results DUE TO 

QA/QC F AlLURE RO *Uable to analyze due to sample matrix. GJT 06/30/10 *Unable to analyze for 

Total Nitrate+ Nitrite due to sample matrix. (AID 06/30/2010) Ethylene Dibromide subcontracted to 

Metrohm-Peak, ISO# 10001397QM08 Radiologicals done by Benchmark Analytical, PADEP Lab ID: 39-

00401 Oil and Grease analyzed by method 9071 for solids due to sample matrix. CLM 07/14/10 

fD=Not Detected 

Note: DEP Certification #s 32-00382 

Data Qualifiers: D =The reported value is from dilution. E = Estimated value. S = Surroqate out of control limits. 
LAB 10: 39-00401 BENCHMARK ANALYTICS, INC. 

4 777 Saucon Creek Road 

Center Valley, PA 18034-9004 

PHONE (610) 974-8100 

FAX (610) 974-8104 

SEND DATA TO: . 

NAME: 

COMPANY: 

ADDRESS: 

PHONE: 

FAX: 

10 18730 

Kathy Brown 

Environmental Service laboratories, Inc 

1803 Philadelphia St 

Indiana, PA 15701 

(724) 463-8378 

(724) 465-4209 

TEST REPORT 

WO#: 

PAGE: 

PO#: 

PWS ID# 

Work Order: 10063929 

10063929 

1 of 1 

RECEIVED FOR LAB BY: MAK DATE: 06/24/201010:40 Page 1 ofl 

SAMPLE: 10 18730 

SAMPLED BY: Client 

Lab 10: 10063929-001A Grab 

Test 

Gross Alpha 

Gross Beta 

Sample Time: 06/16/2010 14:45 

Result Uncert. MDA Units 

3969 ± 871 .90 1687.00 pCilkg-dry 

2416 ± 528.20 1447.00 pCUkg-dry 

Combined Activity (Alpha 6386 

+Beta) 

pCilkg-dry 

REMARKS: 

Method 

EPA 900.0 

EPA900.0 

Calculation 

MCL Analysis Start Analysis End Analyst • 

06/30/10 9:00 07/03/10 BPS-CV 

06130/10 9:00 07/03/10 BPS-CV 

07106/10 13:33 BPS-CV 

Where the analytical method has been performed under NELAP certification, the analysis has met all of the requirements of 

the NELAC standard unless otherwise noted on the Analytical Report. 

• CV =Benchmark Analytics, Inc. Center Valley, PA; SA= Benchmark Analytics , Inc. Sayre, PA 

MANAGER ~ t?1.,_L --------------=---~---~=-~--~------------------------

DATE: --------------- 711312010 
LAB ID: 39-00401 

LAB ID: 08-00380 

SEND DATA TO: 

NAME: Kathy Brown 

Benchmark Analytics, Inc. 

4777 Saucon Creek Road 

Center Valley, PA 18034 

Phone: (610) 974-8100 

Fax: (610) 974-8104 

Work Order: 10063929 

WO#: 

COMPANY: 

ADDRESS: 

Environmental Service Laboratories, Inc 

1803 Philadelphia St PAGE: 

10063929 

1 of 1 

PHONE: 

FAX: 

10 18730 

Indiana, PA 15701 

(724) 463-8378 

(724) 465-4209 

RECEIVED FOR LAB BY: MAK 

SAMPLE: 10 18730 

SAMPLED BY: Client 

Test 

Percent Moisture 

REMARKS: 

Result 

49.9% 

PO#: 

TEST REPORT PWS ID# 

DATE: 06/24/201 0 1 0:40 Page 1 of 1 

Lab 10: 10063929-001A Grab 

Sample Time: 06/16/2010 14:45 

Method 

SM2540G 

EM. 

Limit Analysis Start Analysis End Analyst • 

07107110 14:15 07/09/10 BJW-CV 

Where the analytical method has been performed under NELAP certification, the analysis has met all of the requirements of 

the NELAC standard unless otherwise noted on the Analytical Report. 

• CV =Benchmark Analytics, Inc. Center Valley, PA; SA= Benchmark Analytics, Inc. Sayre, PA 

MANAGER ------------~~--~·~~~--____________________ DATE: ____ V_JJ_fl_Ol_O ____ _ 
I 

! 

SERVICE LABORATORIES, INC. 

I ~03 Fhi.<.x.1elpt1iO St., lrdbnu.. PA 1 ~, 0 I 

(72'4) L16.1-TEST (724) tU\", 42m 

Name: 

Sample Start Date: 

Receipt Date: 

Report Date: 

Analyte 

Chesapeake Appalachia, LLC 

900 Pennsylvania Avenue 

Attn: Mr. Eric Gillespie 

Charleston, WV 25302 

6/16/201 0 2:45 PM 

6118/201 0 2:24 PM 

6/21/2010 

Analyst 

RO 

Analysis 

Date 

~ 

06118 I) Benzene 

47) Toluene RO 06/18 --

Report of Analysis 

Analysis Sample 

Time Result 

n/a ND 

n/a ND 

Sample ID#: 

Sample Type: 

Sample Source: 

Sampler: 

Client Sample ID: 

1018731 

Waste Water 

Grab 

CLIENT (Client) 

Trip Blank 

Units Data Method 

_Qualifier 

ug!L n/a 624/8260B 

ug!L n/a 624/8260B 

RPL 

1.00 

I 1.00 

Comments: 

jND=Not Detected 

DEP Certification #s 32-00382 

Data Qualifiers: D = The reported value is from dilution. E = Estimated value. S = Surrogate out of control limits. 

R = Sample received out of holding time. H = Sample analyzed out of holding time. C = Sample received in incorrect container. 

B = Analyte was detected in both sample and methods blank. X = User defined data qualifier. 

Page 1 of 1 

I