# tlebe ;.f$lunitipal autboritp

Members of the Board FRANK BAZZONE DALE R. MCCALL REGIS T. MCI.JIUGHLIN LUETHEL NESBIT NICKOLAS J. SHERMENTI



### November 23, 2010



## Mr. Chad Harsh NPDES Enforcement Branch Water Protection Division 

# of 

# tb.e 

# C!Citp of ;ffmc1keesport 100 Atlantic Avenue McKeesport, PA 15132 Office: (412) 673-8276

Fax: (412) 673-4283 

### www. mck-macm.org Joseph E. Rost Executive Director Phone (412) 673-9701



## RECEIIE E P/\ nE C?i ON Ill



# NOV 2 9 2010**~PDES** 

### E!FO CH;c'H BRAi·1CH (3VVP4 2 )


### U.S. Environmental Protection Division 1650 Arch Street Philadelphia, PA 19103 Dear Mr. Harsh: As requested in your letter dated February 19, 2009, enclosed is a copy ofthe Authority's latest submittal to the Pennsylvania Department ofEnvironmental Protection in response to its order issued October 23, 2008. This Order was issued relative to the gas well water that the Authority has received for treatment. If

### you have any questions, please contact me at (412) 673-9701 x 12. Sincerely, 

# ktf {

: /f:

Enclosures

# 'aebe 

# iMuntctpal autbotttp

Members of the Board FRANK BAZZONE DALE R. McCALL REGIS T. MCLAUGHLIN LUETHEL NESBIT NICKOLAS SHERMENTI



### November 23,2010 

# of tbt Q!:itp 

# of :flld&.tt5port 100 Atlantic Avenue McKeesport,PA 15132 Office: (412) 673-8276



### Fax: (412) 673-4283 www
. mckeesport-macm.org



### Mr. Kevin Halloran, Water Quality Specialist Supervisor Water Management Pennsylvania Department ofEnvironmental Protection 400 Waterfront Drive Pittsburgh, PA 15222-4745 Dear Mr. Halloran: 

## Municipal Authority ofthe City ofMcKeesport Analysis of Gas Well Wastewaters As Required Under the P A DEP Administrative Order Dated October 23, 2008 Joseph 

### E. Rost Executive Director Phone (412) 673-9701



### Please find enclosed copies ofthe laboratory analyses offourteen (14) wells owned by Chesapeake Energy for the parameters specified in the Administrative Order. The wells are identified as #831 596- drill water, #831572, #627044- drill water, #831927, #831200- drill water, #831202- brine water, #627045 -drill water, #627025, #and 627043 -drill water. The Authority is currently accepting gas well water from three companies, Huntley & 

### Huntley, Chesapeake Energy, and CNX Gas. Wastewaters from new wells accepted by the plant are 

## in the process ofbeing analyzed by Environmental Service Laboratories (ESL) located in Indiana, PA. As the results are received by the Authority copies will be forwarded to your office. Ifyou have any questions, please contact me at (412) 673-9701 ext. 12. Sincerely,



# ....,.,Lr.
**~** 

# ttZrcc: Michael C , Sherrieb, KLH Engineers, Inc. Chad Harsh, EPAENVIRONMENTAL SERVICE LABORATORIES, INC. SAMPLE REQUEST & CHAIN OF CUSTODY PAGE OF

HEADQUARTERS: **~** SOUll-IERN DMSION:

1

803 Philadelphia Sl **~** 1276 BenUeyville Road D

Indiana, PA 15701 Van Voomls, PA 15366

(724)

463- TEST (724) 258- TEST

(7 2 4 ) 465-4209 (7 2 4 ) 258-8376

FOR

INTERNAL LAB ORA TORY USE ONLY - -

Sample Identification ESL#

,. **~~~**

TRIP BLANK Date/ Time

OF CUSTODY SEAL BROKEN: Yes No I· ' : **c-~::** ., >.--<· - ..

•

I \. ·· • "" ·---

l \. Matrix # of Containers

WN
- WN il3

- lfVIN
- lfVIN - lfVIN 2

- lfVIN - WN - lfVIN 2

- lfVIN 2 Water 2 Date/ Time **~**

.. QJ r·' 0 j\j

( \ j\i **~ ~\.\**  Container Type Preservati ve Plastic Uter none Plastic Uter none Plastic Uter HN0 3 Plastic

Uter H,SO, Plastic Uter HN0 3 Amber

Glass L

H C I Amber Glass L **~so,** Amber VOA Vials none Aniber VOA Vials HCI Amber VOA Vials HCI Fax : **f\j//~, s**  Analysis Requested

pH, SC, Choride, Sulfate, Osmotic

Pressure, Alkalinity, Acid i ty

TSS, TDS, Dissolved Iron, Boron,

BOD, MBAS Surfac!ants

AI , As. Ba, Be, Cd

. Cr. Co

, Cu. Fe , Pb , M!l.

Mn,

Hg, Ni, Se, Ag, Sr, Zn , Li, Na, Ca, Hardness Nitrate+N i trite, TKN, Ammonia, COD
Gross Alpha, Gross Beta

OU & Grease Total Phenolics

E t h yle n e Glycol Benzene, Toluene Benzen e , Tolu e ne Chesapeake Appalachia, LLC.

900 Pennsylvania Avenue

## F.

**~'"!** 

## \J ! t):
. f""!"""1 

## f\! !\ii F 

## t,J " t

# A ! lilill I W Y I •'-

**~I~** J · W '1- I W • . • '\:JIIiii 

### SEr<VICt 

### LABoRATORIES. INC. 1 e03 FNodelphia 

### St ., lrK1iana., P.l\ 

### 15701 (72<1) 463 ·TI:ST (724)

**L!C~'>420Q**



### Name:

Sample Start Date: Chesapeake Appalachia, LLC 900 Pennsylvania Avenue Attn: 

### Mr. Eric Gillespie Charleston, WV 25302 8/112010 10:30 AM Receipt Date: 8/3/2010 4:37PM Report Date: 8/23/2010 Analyte Analyst Analysis Date Acidity to pH=8.3 BF 08/10 Alkalinity to pH=4.5 BF 08/12 Biological Oxygen Demand 05 

# szc 08/04 Chemical Oxygen Demand ZTR 08/19 Ammonia as N 

### I Distilled 

### MAD 08/13 Chloride JFW 08/17 Kjeldahl Nitrogen as N ZTR 08/18 pH (SM) LL 08/04 Sulfate ASTM ZTR 08/11 Total Nitrate +Nitrite as N AID 08/11 Aluminum- ICP GJT 08/17 Arsenic-ICP GJT 08/18 Barium- ICP GJT 08/17 Beryllium

- ICP GJT 08/18 Boron MAD 08/10 Cadmium

- ICP GJT 08/18 Calcium

- ICP GJT 08/17 Chromium- ICP GJT 08/17 Cobalt- ICP GJT 08/17 Copper- ICP GJT 08/17 Hardness GJT 08/17 

## Report 

## of Analysis

Analysis Sample

Time Result

n/a 117 n/a 

### 130 7:00AM 121.8 n/a 2997.5 n/a 82.63 n/a 142760.4 n/a 76.4 n/a 5.95 n/a 

### ND n/a 0.20 n/a 1.150 n/a 

### ND n/a 1866.550 n/a 

### ND n/a 6

.50 n/a ND n/a 10071.550 n/a ND n/a 

### ND n/a 

### ND nla 29664 Sample ID#: Sample Type: Sample Source: Sampler: 10 24746 Waste Water Grab Client Sample ID: CLIENT (Client) 831202 Brine Water

Units Data Method
I 

### Qualifier mg/1 as CaC03 n/a SM2310B mg/1 as CaC03 n/a SM2320B mg/1 R 

### SM5210B mg/1 D SM5220D mg/1 n/a SM4500NH3B & 

### D mg/1 n/a SM4500ClC mg/1 n/a SM4500Norg-C,D 

# su n/a SM4500H-B mg/1 n/a D516-02 mg/1 n/a SM4500N03E mg/1 n/a 200.7/6010 mg/1 n/a 200.7/6010 mg/1 n/a 200.7/6010 mg/1 n/a 200.7/6010 mg/1 D SM4500B-B mg/1 n/a 200.7/6010 mg/1 n/a 200.7/6010 mg/1 n/a 200.7/6010 mg/1 n/a 200.7/6010 mg/1 n/a 200.7/6010 mg/1 n/a SM2340B RPL 2 20 2.0 500.0 0.91 5.0 4.4 0.01

5 0.05 0.500 0

.500 0.250 0.250 2.50 0.250 25.000 0.250 0.250 0.250 I
jNDo:Not De tec

ted



### ____ n

_ EP

__



# ce
**rt ifi** 

**io n#_s** 

**2- oo**  **------------**
**---- --------------** 

**-- -----**  **~~**
Data Qualifiers: D =The reported value is from dilution

. E = Estimated value. S = Surrogate out of control limits

. R = Sample received out of holding time. H 

## =Sample analyzed out of holding time. C = Sample received in incorrect container

. B 

## =Analyte was detected in both sample and methods blank

. X 

### =User defined data qualifier. Page 1 of 3

### t:'

**~\.** i I

**i~r-z. ~if.**  

### At: 

### i\. j ·f

**~** .. i • . . . j
......, • .... .. J•

**~·~.** .... I; •;· .. ,. ........ :1!. ....: .I "W W' a ....

**~** a .... I W lliiil.· J: • I 6 'l:.ai

### SERVICE LABORATORIES, INC. 1-00.1 PhEade!pt1iO St

.. lr'di'.JilO. PA 1 5701 (724) 46-"'HfST (724) .<16!':>-4209



### Name:

Sample Start Date: Chesapeake Appalachia, LLC 900 Pennsylvania Avenue Attn: 

### Mr. Eric Gillespie Charleston, WV 25302 8/112010 10:30 AM Receipt Date: 8/3/2010 4:37PM Report Date: 8/23/2010 Analyte Analyst Analysis Date Iron- ICP GJT 08/17 Iron,Dissolved-ICP GJT 

### 08/17 Lead-ICP GJT 08/17 Lithium

- ICP GJT 08/18 Magnesium-ICP GJT 08/17 Manganese- ICP GJT 08/18 Mercury DRM 08111 Nickel- ICP GJT 08/17 Selenium-ICP GJT 08/17 Silver-ICP GJT 

### 08/17 Sodium- ICP GJT 08/18 Strontium- ICP GJT 08/18 Zinc- ICP GJT 08/17 Osmotic Pressure MAD 

### 08/10 Detergents, l\1BAS TL 08/04 Oil and Grease

- HEM CLM 08116 Phenolics, as Phenol AID 08/05 Specific Conductance LL 08/04 Total Dissolved Solids (TDS) 

# szc 08/09 Total Suspended Solids 

# szc 08/09 1) Benzene RO 08/04 

## Report ofAnalysis

Analysis Sample

Time Result

n/a 60.600 n/a 50.100 n/a 

### ND n/a 72.250 n/a 1096.450 n/a 4.050 n/a 

### ND n/a 

### ND n/a 

### ND n/a 

### ND n/a 30698.000 n/a 1682.000 n/a 

### ND n/a 3520 3:55PM 0.617

n/a 

### ND n/a 1.060 n/a 134400 n/a 143700 n/a 225 n/a 

### ND Sample ID#: Sample Type: Sample Source: Sampler: 10 24746 Waste Water Grab 

### Client Sample ID: CLIENT (Client) 831202 Brine Water

Units Data Method Qualifier mg/1 n/a 200.7/6010 mg/1 n/a 200.7/6010 mg/1 n/a 200.7/6010 mg/1 n/a 200.7/6010 mg/1 n/a 200.7/6010 mg/1 n/a 200.7/6010 mg/1 D 245.1 mg/1 n/a 200.7/6010 mg/1 n/a 200.7/6010 mg/1 n/a 200.7/6010 mg/1 n/a 200.7/6010 mg/1 n/a 200.7/6010 mg/1 n/a 200.7/6010 mOs/kg D OSP

mg/1 n/a SM5540C mg/1 n/a 1664A mg/1 D 420.1 uS/em n/a SM25IOB rng/1 n/a SM2540C rng/1 n/a SM2540D ug/L n/a 624/8260B RPL 0.500 0.500 0.250 25.000 25.000 0.250 0.0008 0.250 0.500 0.250 500.000 10.000 0.250 1000 0.200

5.0 0.500

I 25 5 10.00

f D=Not Detected

DEP Certification #s 32-00382

Data Qualifiers: D =The reported value is from dilution. E = Estimated value. S =Surrogate out of control limits

. R 

## = Sample received out of holding time. H 

## = Sample analyzed out of holding time. C 

## = Sample received in incorrect container

. B = Analyte was detected in both sample and methods blank

. X = User defined data qualifier. Page 2 of 3

### Name: 

## F

. F \.! \1 

## i 

## !:_)f1

**~** 

### iftfi

**~** 

## f\: 

## T fl.

**~** ... .

. -. ... **••"""'~"Wj'I'J.wr** . .... . -6 .._..._ 

### SERVICE LABORATORIES. INC

. I 001 F hiladelptll O Sl.

.

**lf ~(** 

**'J rJ**  **U..** PA 15701 (724) 46.1 ·TEST (724)

**46.>~209**



### Sample Start Date: Chesapeake 

### Appalachia, LLC 900 Pennsylvania A venue Attn: Mr. Eric Gillespie Charleston, WV 25302 8/1/2010 10:30 AM 

### Receipt Date: 8/3/2010 4:37PM 

### Report Date: 8/23/2010 

### Analyte Analyst Analysis Date 47) 

### Toluene 

### RO 08/04 

## Report of Analysis

Analysis Sample

Time Result

n/a ND 

### Sample ID#: Sample Type: Sample Source: Sampler: 10 24746 Waste Water Grab 

### Client Sample ID: CLIENT 

### (Client) 831202 Brine Water



### Units Data Method L Qualifier ug/L nla 624/8260B 

### RPL 10

.00

Comments: I ND=Not Detected

DEP Certification lis 32-00382

Data Qualifiers: D =The reported value is from dilution. E = Estimated va lue
. S = Surrogate out of contro l limits

. R =Sample received out of holding time. H =Sample analyzed out of holding time. C =Sample received in incorrect container. B = Analyte was detected in both sample and methods blank

. X= User defined data qualifier

. Page 3 of 3

## a: i\ 

### i \ 1 1t}r_._""'\ 

### t... 

## e i\

**~** 

## c i\ i 

### ;-t A i :.l

**~** -: :

**~;** ': 1'.:; ;w.;

**~** ;...-;..;. 

### SERVICE LABORATORIES. INC. 1 003 FNooelpliiO St

.. lr"·dk:JriO, PA 15701 (724) 

### 46-l TfST (724) 116-5-42()<;1



### Name:

Sample Start Date: Receipt Date: Report Date: Analyte Prep-16 Send Out Ethylene Glycol Radiologicals Chesapeake Appalachia, LLC 900 Pennsylvania A 

### venue Attn: 

### Mr. Eric Gillespie Charleston, WV 

### 25302 8/1/2010 10:30 AM 8/3/2010 4:37PM 8/26/2010 Analyst Analysis Date DAS 08/05 MetPeal< 08/09 enchmm 08/13 

## Report ofAnalysis

Analysis Sample

Time Result

n/a D 

### n/a <25.500 nla 

## * Sample ID#: Sample Type: Sample Source: Sampler: 10 24747 Waste Water Grab Client Sample ID: CLIENT (Client) 831202 Brine Water

Units Data Method

. Qualifier none nla Gen. Prep

. mglkg nla 300.0 M mg/1 

### nla RAD-CTDHS RPL 0 25.500 0.000

Comments: Ethylene Glycol subcontracted to Metrohm-Peak, ISO# 10001397QM08 Radiologicals done by Benchmark Analytical, PADEP Lab ID: 39-00401 I ND=Not D etected

DEP Certification #s 32-003 82

Data Qualifiers: D =The reported value is from dilution. E =Estimated value

. S =Surrogate out of control limits. R =Sample received out of holding time. H =Sample analyzed out of holding time. C =Sample received in incorrect container. B = Analyte was detected in both sample and methods blank. X 

## =User defined data qualifier. Page 1 of 1

### LAB 

### iD: 39-00401



## SEND DATA TO: NAME: Mike Moyer 

### BENCHMARK ANAL YTICS, INC. 4777 Saucon Creek Road Center Valley, PA 18034-9004 

## PHONE (610) 974-8100

FAX (610) 974-8104

COMPANY: 

### Environmental Service Laboratories, Inc ADDRESS: 1803 

### Philadelphia St


## PHONE: FAX: 

### Indiana, PA 15701 

### (724) 463-8378 (724) 465-4209 

## TEST REPORT WO#: 

## PAGE: PO#: 

## PWSID# Work Order : 10081066

10081066 

### 5 of6 DAS0407201 

### 0

RECEIVED 

### FOR LAB BY: MAK 

## DATE: 08/06/2010 9:35 

## Page 5 

## of6 SAMPLE: 10 24747 Lab 10: 10081066-005A Grab SAMPLED BY: David Stiles Sample Time 08/01/2010 10:30



### illl

**~** Uncert. .MQA 

### .!.!.nil!

**~** EPA 900.0 EPA 900.0 MCL Anatvsls Start Analysis End

**~** 06/10/10 9:00 08/13/10 BPS-CV 08/10/10 9:00 08/13/10 BPS-CV Gross Alpha 4436 ± 613

.7 1266

.00 pCi/L Gross Beta 2365 ± 537

.0 1535.00 pCVL

REMARKS:

Where the analytical method has been perfonned under NELAP certification, the analysis has met all of the requirements of the NELAC standard unless otherwise noted on the Analytical Report. • CV 

### = Benchmark Analytics, Inc. Center Valley, PA; SA 

### = Benchmark Analytics, Inc

. Sayre , PA



# MANAGER **------------~**

**--~ ·~**  **~~ ----------------------**  DATE:
___ 8

_ n

_

5

_ a

_

o

_ JO

____ _

### Name: f:; A.H i! fie-"'1

**~** i 

### i1.

**!H.:~** 

### i-t 1\ i a· · ·• .._. •• II!

**~** 1
.. . a "-·• I •• a • . . . • .... 11· .-,. • Mli' il W W' •• **-.~I** ._IW'I_.I.
.. 1• ..__.. 

### SERVICE lABORATORIES, 

### INC. 1 

### rD3 Fhi:Odelph iO St"

**lr.dl~ria..** PA 15701

**(72~)** 463 ·TI:ST (724) 46.54209



### Sample Start Date: Chesapeake Appalachia, LLC 900 Pennsylvania Avenue 

### Attn: Mr. 

### Eric Gillespie Charleston, 

### WV 25302 8/112010 Receipt Date: 8/3/2010 4:37PM Report Date: 8/5/2010 Analyte Analyst Analysis Date I) Benzene 

## RO 08/04 47) Toluene 

## RO 08/04

Comments:

DEP Certification #s 32-00382 

## Report ofAnalysis

Analysis Sample

Time Result

n/a ND n/a 

### ND 

### Sample ID#: Sample Type: Sample Source: Sampler: 10 24748 Waste Water Grab CLIENT 

### (Client) Client Sample ID: 831202 Brine Water Trip 

### Blank

Units Data Method RPL 

### Qualifier ug/L n/a 

### 624/8260B 1.00 ug/L nla 

### 624/8260B 1.00

jND=Not Detected

Data Qualifiers: D =The reported value is from dilution. E = Estimated value

. S =Surrogate out of control limits. R = Sample received out of holding time. H = Sample analyzed out of holding time. C = Sample received in incorrect container

. B = Analyte was detected in both sample and methods blank

. X= User defined data qualifier. Page 1 of 1

# Metrohm USA ln(. 

# Sample Results Su.m1nary

Environmental Service Labs, Inc
- Indiana , PA Lab Rep ort 201 0-1636 Results Prepared for: Michael Moye r 

### I Ka thy Brown August 9, 2010 MUSAJob 

### # Sample ID Ethylene Glycol mg/Kg 

### 1636-1 10 24747 < 

### 25

.500 163 6-2 10 24750 270.738 1636-2 Dup 

### 10 24750 Dup 

### 276.245 Mean 

### 273.492 QC 

### 74 .466 QC 

### Value 

### 77.583 %Recovery 

### 95

. 982 Instrument Detection Limit 

### 5.000 Sa mp le Detection Limit varies by dilution



## Report by: 

# 4

**~ "fho.** 

**·l k**  6555 Pelican Creek Circle, Riverview, FL 33578 813-316-4777ENVIRONMENTALSERVICELABORATORIESINC.SAMPLEREQUEST&CHAINOFCUSTODYPAGEOFHEADQUARTERS:SOUlllERNDIVISION:1803PhiladelphiaSt1276BentleyvilleRoadDIndiana,PA15701VanVoorhis,PA15366(724)463-TEST(724)258-TEST'T.•.I.,..(724)465-4209(724)258-8376FORINTERNALLABORATORYUSEONLYf-..j••-SampleIdentificationIESL#ICompositeIGrabITRIPBLANK1)-Date/TimeNOFCUSTODYSEALBROKEN:YesNo-'.I..,·-.,_);\j(b\0MatrixI#ofContainersIwwI1IwwIJl3IwwI1IINVVI1IwwI2IwwI1IwwI1IINVVI2IINVVI2IWater21\l'..Nf\JContainerTypePreservativePlasticLiternonePlasticLiternonePlasticLiterHNO,---PlasticLiterH2so.PlasticLiterHNO,---AmberGlassLHCI-AmberGlassLH,so.AmberVOAVialsnoneAmberVOAVialsHCI1\...,...J.........\IrCompany/Name:Person:AnalysisRequestedpH,SC,Choride,Sulfate,OsmoticPressure,Alkalinity,AcidityTSS,TDS,DissolvedIron,Boron,BOD,MBASSurfactantsAI,As,Ba,Be,Cd,Cr,Co,Cu.Fe,Pb,Mg,Mn,Hg,Ni,Se,Ag,Sr,Zn,Li,Na,Ca,HardnessNitrate+Nitrite,TKN,Ammonia,CODGrossAlpha,GrossBetaGlycolTolueneTolueneChesapeakeAppalachia,LLC.900PennsylvaniaAvenue

# ENV!RONr'v1ENTAL SERVICE LABORATORIES, INC. 1 003 Phladephlo St ., lrdiano, PA 15701 (724) 463-TEST (724}A65-420Q



### Name:

Sample Start Date: Receipt Date: Report Date: Chesapeake Appalachia, LLC 900 Pennsylvania Avenue Attn: 

### Mr. Eric Gillespie Charleston, WV 25302 7/16/2010 12:44 PM 7/20/2010 4:24PM 10/6/2010 Analyte Analyst Analysis Date Acidity to pH=8

. 3 BF 07/27 Alkalinity to pH=4.5 BF 07/30 Biological Oxygen Demand 05 LMB 07/21 Chemical Oxygen Demand ZTR 08/03 Ammonia as N 

### I Distilled ZTR 07/29 Chloride BF 08/04 Kjeldabl Nitrogen as N MAD 08/02 pH(SM) AO 07/22 Sulfate ASTM ZTR 08/02 Total Nitrate+ Nitrite as N AJD 07/28 Aluminum

- ICP GJT 

### 0&104 Arsenic-ICP GJT 08/03 Barium- ICP GJT 0&/03 Beryllium

- ICP GJT 08/04 Boron AJD 07/27 Cadmium

- ICP GJT 08/04 Calcium

- ICP GJT 08/03 Chromium

- ICP GJT 08/03 Cobalt- ICP GJT 08/03 Copper- ICP GJT 08/03 Hardness GJT 08/03 

## Report ofAnalysis

Analysis Sample

Time Result

n/a ND n/a 235 8 :00AM 79.8

n/a 153.0 n/a 0.98 n/a 157.5 n/a 5.7 n/a 6.98 n/a 70 n/a &.90 n!a 1.702 nla 

### ND n/a 470.850 n/a 

### ND n/a 

### ND n/a ND n/a 15&5

.850 n/a 0.750 n/a ND n/a 2

.500 n/a 6156 SampleiD#: Sample Type: Sample Source: Sampler: 10 22788 Waste Water Grab Client Sample ID: CLIENT (Client) 831596 Drill Water

Units Data Method Qualifier mg/1 as CaC03 n/a SM2310B mg/1 as CaC03 n/a SM2320B mg/1 E SM5210B mg/1 D SM5220D mg/1 n/a SM4500NH3B 

### & D mg/1 n/a SM4500ClC mg/1 n/a SM4500Norg-C,D 

## su n/a SM4500H-B mg/1 D D516-02 mg/1 D SM4500N03E mg/1 n/a 200.7/6010 mg/1 n/a 200.7/6010 mg/1 n/a 200.7/6010 mg/1 n/a 200.7/6010 mg/1 n/a SM4500B-B mg/1 n/a 200.7/6010 mg/1 n/a 200.7/6010 mg/1 n/a 200.7/6010 mg/1 n/a 200.7/6010 mg/1 n/a 200.7/6010 mg/1 n/a SM2340B 

### RPL 2 20 2.0 100.0 0

. 89 1.0 3.5 0.01 50 0

.50 0

.010 0

.500 0.250 0

.005 0.25 0.005 25.000 0.250 0.250 0

.250

I

f D=Not Detected

DEP Certifica tion #s 32-00382

Data Qualifiers: D =The reported value is from dilution. E = Estimated value. S =Surrogate out of control limits. R =Sample received out of hold i ng time. H = Sample analyzed out of holding time

. C =Sample received in incorrect container

. B = Analyte was detected in both sample and methods blank. X = User defined data qualifier. Page 1 of3

### Name:

Sample Start Date: Receipt Date: Report Date: Analyte Iron- ICP Iron,Dissolved- ICP Lead-ICP Lithium

- ICP Magnesium-ICP Manganese- ICP Mercury Nickel- ICP Selenium

-ICP Silver-ICP Sodium- ICP Strontium

- ICP Zinc- ICP Osmotic Pressure Chesapeake Appalachia, LLC 900 Pennsylvania Avenue Attn: Mr. Eric Gillespie Charleston, WV 25302 7/16/2010 12:44 PM 7/20/2010 4:24PM 10/6/2010 Analyst Analysis Date GJT 08/03 GJT 08/03 GJT 08/03 GJT 08/04 GJT 08/03 GJT 08/03 

## DRM 07/21 GJT 08/03 GJT 08/04 GJT 08/03 GJT 08/04 GJT 08/05 GJT 08/03 AID 07/28 Prep-2, Metals Digestion DMM 07/21 Detergents , MBAS TL 07/22 Oil and Grease

- HEM CLM 08/05 Phenolics, as Phenol AID 08/05 Specific Conductance AO 07/22 Total Dissolved Solids (TDS) LMB 07/23 Total Suspended Solids LMB 07/23 

## Report 

## of Analysis

Analysis Sample

Time Result

nla 135

.750 n/a 10.800 n/a 0

.650 n/a ND n/a 533.200 n/a 4.300 n/a NO n/a 0

.550 n/a 0

.046 n/a ND n/a 167.040 n/a 1.812 n/a 2.100 n/a ND 11:35AM D

1:34PM 0.302

n/a 

### ND n/a ND n/a 1069 n/a 557 n/a 120 SampleiD#: Sample Type: Sample Source: Sampler: 10 22788 Waste Water Grab Client Sample ID: CLIENT (Client) 831596 Drill Water

Units Data Method Qualifier mg/1 n/a 200.7/6010 mg/1 n/a 200.7/6010 mg/1 n/a 200.7/6010 mg/1 n/a 200.7/6010 mg/1 n/a 200.7/6010 mg/1 n/a 200.7/6010 mg/1 n/a 245.1 mg/1 n/a 200.7/6010 mgll n/a 200

.7/6010 mgll n/a 200.7/6010 mg/1 n/a 200.7/6010 mg/1 n/a 200.7/6010 mg/1 n/a 200.7/6010 mOs/kg n/a OSP

none n/a 3010A/3020A/3015 mg/1 n/a SM5540C mgll n/a 1664A mgll D 420.1 uS/em n/a SM2510B mg/1 n/a SM2540C mg/1 n/a SM2540D 

### RPL 0

.500 0.500 0

.250 0.500 25.000 0.250 0.0002 0.250 0

.010 0.250 5.000 0.010 0.250

100

1 0

.200

5

.0 0

.500

1 25 5
jND= Not D etected

DEP Certification #s 32-00382

Data Qualifiers: D =The reported value is from dilution. E = Estimated value

. S = Surrogate out of control limits. R = Sample received out of holding time. H = Sample analyzed out of holding time. C =Sample received in incorrect container

. B = Analyte was detected in both sample and methods blank. X = User defined data qualifier. Page 2 of 3

### Name:

Sample Start Date: Receipt Date: Report Date: Analyte 1) Benzene 47) Toluene Chesapeake Appalachia, LLC 900 Pennsylvania Avenue Attn: 

### Mr. Eric Gillespie Charleston, WV 

### 25302 7/16/2010 12:44 PM 7/20/2010 4:24PM 10/6/2010 Analyst Analysis Date RO 07/21 RO 07/21 

## Report ofAnalysis

Analysis Sample

Time Result

n!a 

### ND n!a 

### ND Sample ID#: 

### Sample Type: Sample Source: Sampler: 10 22788 Waste Water Grab Client Sample ID: 

### CLIENT (Client) 831596 Drill Water

Units Data Method Qualifier ug!L n!a 624/8260B ug!L n!a 624/8260B 

### RPL 20.00 20.00

Comments: jND=Not Detected

DEP Certification #s 32

-00382

Data Qualifiers: D 

## =The reported value is from dilution

. E 

### = Estimated value. S = Surrogate out of control limits

. R = Sample received out of holding time. H 

## = Sample analyzed out of holding time. C 

## = Sample received in incorrect container

. B = Analyte was detected in both sample and methods blank. X = User defined data qualifier

. Page 3 of3

## ENVIRON~J!ENTAl SERVICE LABORATORIES, INC. 1003

**Fhlode~hlo** 

### st., lrdiano, PA 15701 (72.:1) 463-"TEST (724) 465-4209



### Name:

Sample Start Date: Receipt Date: Report Date: Analyte Ethylene Glycol Radiologicals Chesapeake Appalachia, LLC 900 Pennsylvania Avenue Attn: Mr. Eric Gillespie Charleston, WV 25302 7/16/2010 12:44 PM 7/20/2010 4:24PM 10/6/2010 

### Analyst Analysis Date 

### !MetPeak 07/27 enchmru 07/30 

## Report ofAnalysis

Analysis Sample

Time Result

n/a 80.453 n/a 

## * SampleiD#: Sample Type: Sample Source: Sampler: 10 22789 Waste Water Grab 

### Client Sample ID: CLIENT (Client) 831596 Drill Water



### Units Data Method I 

### Qualifier mglkg 

### n/a 300.0M mg/1 

### n/a RAD-CTDHS 

### RPL 25.000 0.000

Comments: 

### Radiologicals done by Benchmark Analytical, PADEP Lab ID: 39-00401 Ethylene Glycol subcontracted to Metrohm-Peak, ISO# 10001397QM08 jND=Not Detected

Note: DEP Certification #s 32-00382

Data Qualifiers: D =The reported value is from dilution. E 

## = Estimated value. S 

## = Surrogate out of control limits. R = Sample received out of holding time

. H = Sample analyzed out of holding time. C = Sample received in incorrect container

. B = Analyte was detected in both sample and methods blank. X= User defined data qualifier

. Page 1 of 1



# ------

### LAB ID: 39-00401

SEND DATA TO: NAME: Kathy Brown 

## BENCHMARK ANALYTICS, INC. 4777 Saucon Creek Road Center Valley, PA 18034-9004 PHONE (610) 974-8100

FAX (610) 974-8104 Work Order: 10073819

WO#: 

### COMPANY: ADDRESS: Environmental Service Laboratories, Inc 

### 1803 Philadelphia St 

### PAGE: 

### 10073819 1 of 

### 1 Indiana, 

### PA 15701 PHONE: FAX: 

### (724) 463-8378 (724) 465-4209 10 22789 RECEIVEO FOR LAB BY: 

### MAK SAMPLE: 10 22789 SAMPLED BY: Client



### illl Gross Alpha Gross Beta Combined Activity (Alpha + Beta)



### REMARKS: Result 16.61 32.49 49

. 10 Uncert. :t 4.26 :t 3

. 66 

### PO#: 

## TEST REPORT PWS 

### ID#

DATE: 

### 07/23/2010 9:45 Page 1 of 1 Lab 10: 10073B19.{)01A Grab Sample Time 07/16/2010 12:44· MQA Unjts Method MCL Analysis Start Analysis End Anatvst " 6.30 pCi/L EPA 900.0 07/26/10 9 :05 07/29/10 BPS-CV 7.21 pCUL EPA 900

. 0 07/26/10 9 :05 07/29/10 BPS-CV pCi/L Calculation 07/30/10 15 :02 BPS-CV

Where the analytical method has been performed under NELAP certification, the analysis has met all ,of the requirements of the NELAC standard unless otherwise noted on the Analytical Report. • CV 

### = Benchmar1c Analytics, Inc. Center Valley, PA; SA 

### = Benchmark Analytics, Inc. Sayre, PA



### MANAGER



# ----------~
**~-- ·~~**  **~~ ~~~**  **·--** __________________ DATE:
____



# JO **IO** ____ _

### Name:

Sample Start Date: Receipt Date: Report Date: Analyte 1) Benzene 47) Toluene Chesapeake Appalachia, LLC 900 Pennsylvania Avenue Attn: Mr. 

### Eric Gillespie Charleston, WV 25302 7/16/2010 7/20/2010 4:24PM 7/22/2010 Analyst RO RO 

### Analysis Date 07/21 07/21 

## Report of Analysis

Analysis Sample

Time Result

nla ND 

### nla ND 

### SampleiD#: Sample Type: Sample Source: Sampler: 10 22790 Waste Water Grab Client Sample ID: CLIENT (Client) Trip Blank

Units Data Method Qualifier ug!L nla 

### 624/8260B ug!L n/a 624/8260B RPL 1.00 1.00

Comments: jND=Not D e tected

DEP Certification #s 32-00382

Data Qualifiers: D =The reported value is from dilution. E =Estimated value. S =Surrogate out of control limits. R =Sample received out of holding time. H = Sample analyzed out of holding time. C = Sample received in incorrect container

. B = Analyte was detected in both sample and methods blank

. X= User defined data qualifier

. Page 1 of 1ENVIRONMENTAL SERVICE LABORATORIES, INC. SAMPLE REQUEST & CHAIN OF CUSTODY PAGE OF

HEADQUARTERS: SOI.IlMERN DMSION:

1803

Philadelphia Sl 1276 Bentleyville Road **~-. :-·.:~**  c--:

**~·.:·** F:-:,\//":...-! I() f"\J

Indiana, PA 15701 M D

Van Voorhis, PA 15366

(724)

463- TEST (724) 258-TEST "<'' '·-·· ·,I 1 .} .- **/~** C) **c~**

(724)

465-4209 (724) 258-8376

FOR

INTERNAL LASORA TORY USE ONLY

Sample Identification ESL#

.. **L09~~~**

TRIP BLANK THESE SERVICE CHARGES v.ILL ACCRUE AT THE RATE OF 1 112% PER MONTH (16% PER ANNUM OR 1l1E MI\XJMUM Al.LO\M:D BY LAW.)

THE

UNDERSIGNED PURCHASER AGREES TO PAY, IN 1l1E EVENT HIS ACCOUNT BECOMES DEUNQUENT AND IS TURNED OVER TO ANY

REASONABLE

ATTORNEY'S FEES PLUS Al.L COURT AND ATTENDANT COLLECTION COSTS.
::ftAn.e. **~O,a£>10** l \\5

**Tim~:~** Date/

. ····- Date/ Time

OF CUSTODY SEAL BROKEN: Yes No ./ /, !"\

. l **~:~** ::<. Matrix # of Containers

WN
- WN **~3**

- WN - WN - WN 2

- WN - WN - WN 2

- WN 2 Water 2 (2) N (y) G) N N/A
N Container Type Preservative Plastic Uter none Plastic Uter none Plastic Liter HN0 3 Plastic

Liter

H 2 S0 4 Plastic

Liter HN0 3 Amber

Glass L HCI Amber Glass L

H 2 SO, Amber VOA Vials none Amber VOA Vials HCI Amber VOA Vials HCI Company/Name: **,,~** -.,. **~-** Analysis Requested

pH, SC, Choride, Sulfate, Osmotic

Pressure, Alkalinity, Acidity

TSS, TDS, Dissolved iron, Boron,

BOD, MBAS Surfactants

AI, As, Ba, Be, Cd, Cr, Co, Cu, Fe, Pb, Mg,

Mn,

Hg, Ni, Se, Ag, Sr, Zn, Li, Na, Ca, Hardness Nitrate+Nitrite, TKN, Ammonia, COD
Gross Alpha, Gross Beta

Oil & Grease Total Phenolics Ethylene Glycol Benzene, Toluene Benzene, Toluene Chesapeake Appalachia, LLC.

900 Pennsylvania AvenueName:

Sample Start Date: Receipt Date: Report Date: Analyte Acidity to pH=8.3 Chesapeake Appalachia, LLC 900 Pennsylvania Avenue Attn: Mr. Eric Gillespie Charleston, WV 25302 6/30/2010 11:15 AM 7/2/2010 2:41PM 10/11/2010 Analyst Analysis Date BF 07/12 Alkalinity to pH=4.5 ZTR 07/18 Biological Oxygen Demand 05 

## szc 07/02 Chemical Oxygen Demand ZTR 07/06 Ammonia as N 

### I Distilled MAD 07/09 Chloride BF 07/08 Kjeldabl Nitrogen as N AID 07/16 pH(SM) LL 07/06 Sulfate ASTM ZTR 07/12 Total Nitrate+ Nitrite as N MAD 07/16 Aluminum

- ICP GJT 07/27 Arsenic-ICP GJT 07/27 Barium- ICP GJT 07/23 Beryllium

- ICP GJT 07/27 Boron MAD 07/07 Cadmium

- ICP GJT 07/27 Calcium

- ICP GJT 07/23 Chromium- ICP GJT 07/27 Cobalt- ICP GJT 07/23 Copper- ICP GJT 07/23 Hardness GJT 07/27 

## Report of Analysis

Analysis Sample

Time Result

n/a ND n/a 564 3:00PM 1119.0

n/a 2470.0 n/a 4.10 n/a 14903.4 n/a 7.2 n/a 11.66 n/a 370 n/a 0.06 n/a 44.100 n/a ND n/a 4.900 n/a ND n/a ND n/a ND n/a 693.400 n/a ND n/a ND n/a 0.650 n/a 1858 Sample ID#: Sample Type: Sample Source: Sampler: 10 20502 Waste Water Grab Client Sample ID: CLIENT (Client) 627044 Drill Water

Units Data Method Qualifier mg/1 as CaC03 n/a SM2310B mg/1 as CaC03 n/a SM2320B mg/1 n/a SM5210B mg/1 D SM5220D mg/1 n/a SM4500NH3B&D mg/1 n/a SM4500ClC mg/1 D SM4500Norg-C,D 

## su n/a SM4500H-B mg/1 D D516-02 mg/1 n/a SM4500N03E mg/1 n/a 200.7/6010 mg/1 n/a 200.7/6010 mg/1 n/a 200.7/6010 mg/1 n/a 200.7/6010 mg/1 n/a SM4500B-B mg/1 n/a 200.7/6010 mg/1 n/a 200.7/6010 mg/1 n/a 200.7/6010 mg/1 n/a 200.7/6010 mg/1 n/a 200.7/6010 mg/1 n/a SM2340B 

### RPL 2 20 2.0 500.0 0.09 1.0 4.5 0.01 50 0.05 0.500 0.500 0.250 0.250 0.25 0.250 25.000 0.250 0.250 0.250



### I

Comments: Ethylene Glycol subcontracted to Metrohm-Peak, ISO# 10001397QM08 Radiologicals done by Benchmark Analytical, PADEP Lab ID: 39-00401 IND=Not Detected

DEP Certification #s 32-003 82

Data Qualifiers: D =The reported value is from dilution. E = Estimated value. S =Surrogate out of control limits. R = Sample received out of holding time. H =Sample analyzed out of holding time. C =Sample received in incorrect container

. B = Analyte was detected in both sample and methods blank. X = User defined data qualifier. Page 1 of 3

# ENVIRON~.r1ENTAL SERVICE LABORATORIES, INC. 1 003

**Phl::lde~hla** St:, lrdk:ina. PA 

### 15701 (724) 463-TEST (724) 465420Q



### Name:

Sample Start Date: Receipt Date: Report Date: Analyte Iron- ICP Iron,Dissolved-ICP Lead-ICP Lithium- ICP Magnesium-ICP Manganese

- ICP Mercury Nickel- ICP Selenium-ICP Silver-ICP Sodium- ICP Strontium

- ICP Zinc- ICP Osmotic Pressure Chesapeake Appalachia, LLC 900 Pennsylvania Avenue Attn: Mr. Eric Gillespie Charleston, WV 25302 6/30/2010 11:15 AM 7/2/2010 2:41PM 10/11/2010 Analyst Analysis Date GJT 07/23 GJT 07/23 GJT 07/23 GJT 08/02 GJT 07/27 GJT 07/23 

## DRM 07/07 GJT 07/23 GJT 07/23 GJT 07/23 GJT 07/28 GJT 08/02 GJT 07/23 

### MAD 07/07 Prep-2, Metals Digestion

. DMM 07/08 Detergents, MBAS TL 07/02 Oil and Grease

- HEM CLM 07/20 Phenolics, as Phenol AID 07/14 Specific Conductance LL 07/06 Total Dissolved Solids (TDS) LMB 07/05 Total Suspended Solids LMB 07/05 

## Report of Analysis

Analysis Sample

Time Result

n/a 86.300 n/a 0.850 n/a 0.350 n/a 

### ND n/a 30.850 nla 2.150 n/a 

### ND n/a 

### ND n/a 

### ND n/a 

### ND n/a 10847.000 n/a 8.450 n/a 0.900 nla 786 4:17PM D 2:16PM 10

.500

nla 14.0 n!a 

### ND nla 41800 nla 27500 nla 412 Sample ID#: Sample Type: Sample Source: Sampler: 10 20502 Waste Water Grab Client Sample ID: CLIENT (Client) 627044 Drill Water

Units Data Method Qualifier mg/1 n/a 200.7/6010 mg/1 n/a 200.7/6010 mg/1 n/a 200.7/6010 mg/1 n/a 200.7/6010 mg/1 n/a 200.7/6010 mg/1 n/a 200.7/6010 mg/1 D 245.1 mg/1 n/a 200.7/6010 mg/1 n/a 200.7/6010 mg/1 n/a 200.7/6010 mg/1 n/a 200.7/6010 mg/1 n/a 200.7/6010 mg/1 n/a 200.7/6010 mOs/kg n/a OSP

none n!a 3010A/3020AJ3015 mg/1 nla SM5540C mg/1 n!a 1664A mg/1 D 420.1 uS/em n!a SM2510B mg/1 n/a SM2540C mg/1 n!a SM2540D 

### RPL 0.500 0.500 0.250 25

.000 25.000 0.250 0.0020 0.250 0.500 0

.250 500.000

0.500 0.250

100



### 1 2.000

5.0 0.500

1 25 5
Comments: Ethylene Glycol subcontracted to Metrohm-Peak, ISO# 10001397QM08 Radiologicals done by Benchmark Analytical, PADEP Lab ID: 39-00401 I ND=Not Detected

DEP Certification #s 32-00382

Data Qualifiers: D =The reported value is from dilution. E = Estimated value. S =Surrogate out of control limits. R = Sample received out of holding time. H =Sample analyzed out of holding time. C = Sample received in incorrect container. 8 = Analyte was detected in both sample and methods blank

. X = User defined data qualifier. Page 2 of3

# ENVIRONl\1ENTAl SERVICE LABORATORIES. INC. 1003 PhJade'phio St., lrdbno. PA 15701 (72£1) 463-lEST (724) .<f6.5.420'1I



### Name:

Sample Start Date: Receipt Date: Report Date: Analyte 1) Benzene 47) Toluene Chesapeake Appalachia, LLC 900 Pennsylvania Avenue Attn: 

### Mr. Eric Gillespie Charleston, WV 25302 6/30/2010 11:15 AM 7/2/2010 2:41 PM 1011112010 Analyst Analysis Date 

### RO 07/02 

### RO 07/02 

## Report ofAnalysis

Analysis Sample

Time Result

nla ND 

### n!a ND SampleiD#: Sample Type: Sample Source: Sampler: 10 20502 Waste Water Grab Client Sample ID: CLIENT (Client) 627044 Drill Water

Units Data Method IQualifier ug!L nla 624/8260B ug!L nla 624/8260B RPL 10.00 10.00

Comments: Ethylene Glycol subcontracted to Metrohm-Peak, ISO# 10001397QM08 Radiologicals done by Benchmark Analytical, PADEP Lab ID: 39-00401 I ND=Not Detected

DEP Certification #s 32-00382

Data Qualifiers: D =The reported value is from dilution. E = Estimated value. S = Surrogate out of control limits. R =Sample received out of holding time. H = Sample analyzed out of holding time. C =Sample received in incorrect container. B = Analyte was detected in both sample and methods blank. X = User defined data qualifier. Page 3 of 3

# ENVIRON~1ENTAL SEfMCE LABORATORIES. INC. 1 e03

**Phlcx:Je~hio** St., lrdlanQ. PA 15 7

01 (724) 463-TEST (724) 465-420Q



### Name:

Sample Start Date: Receipt Date: Report Date: Analyte Ethylene Glycol Radiologicals Chesapeake Appalachia, LLC 900 Pennsylvania Avenue Attn: 

### Mr. Eric Gillespie Charleston, WV 25302 6/30/2010 11:15 AM 7/2/2010 3:01PM 10/11/2010 Analyst Analysis Date IMetPeal< 07/13 enchmru 07/22 

## Report of Analysis

Analysis Sample

Time Result

n/a 177.664 n/a 

## * Sample ID#: Sample Type: Sample Source: Sampler: 10 20521 Waste Water Grab Client Sample ID: CLIENT (Client) 627044 Drill Water

Units Data Metbod I

### Qualifier mg/kg n/a 300.0M 

### mg/1 n/a RAD-CTDHS RPL 5

.000 0

.000

Comments: Ethylene Glycol subcontracted to Metrohm-Peak, lSO # 10001397QM08 Radiologicals done by Benchmark Analytical, PADEP Lab ID: 39-00401 [ ND=Not Detected

DEP Certification #s 32-00382

Data Qualifiers: D =The reported value is from dilution. E = Estimated value. S = Surrogate out of control limits. R =Sample received out of holding time. H = Sample analyzed out of holding time. C =Sample received in incorrect container

. B = Analyte was detected in both sample and methods blank. X = User defined data qualifier

. Page 1 of 1

## LAB ID: 39-00401

>END DATA TO:

**~AME:** Kathy Brown 

## BENCHMARK ANALYTICS, INC

. 4777 Saucon Creek Road Center Valley, PA 18034-9004 PHONE (610) 974-8100

FAX (610) 974-8104

**~OMPANY**

**:** Environmental Service Laboratories, Inc 1DDRESS: 

### 1803 Philadelphia St

HONE: 

### AX: Indiana, PA 

### 15701 (724) 463-8378 (724) 465-4209 

### 0 20557 &20251 

### TEST REPORT WO#: PAGE : PO#: PWS ID# 

### Work Order: 10071120

10071120 2 of2

ECEIVED FOR LAB BY: JEC DATE: 

### 07/08/2010 9:40 Page2 of2 \MPLE: 10 20521 SAMPLED BY: Client

**~** Gross Alpha Gross Beta

ARKS: Lab ID : 10071120-002A Grab Sample T i me 06/30/2010 11:15

**~** Uncert. MDA Unjts 255.9 ± 136

. 5 395

. 20 pCiiL 1221 ± 171

.3 384.20 pCi/L Method EPA 900

.0 EPA 900.0 MCL Analysis Start Analysis End Analyst * 07/19/10 9:00 07/22110 BPS-CV 07/19110 9:00 07/22/10 BPS-CV

·ere the analytical method has been performed under NELAP certification, the analysis has met all of the requirements of NELAC standard unless otherwise noted on the Analytical Report. 

## v == Benchmark Analytics, Inc. Center Valley, PA; SA== Benchmari< Analytics, Inc. Sayre, PA

\GER



# ------------ **~--~ ·~**  **~~ ~~**  **--** __________________ DATE:
____



# 28 **10** ____ _**~arne:** 

### t.:;r.**nJ•n,.,.~..Jr;.•:u:·~~.. ~TJ;**  1 •· · l'\J ' : .-.;< 1.. J ;\, • ''• m I\.; • ...:., • lliil a: .. W I ....... ...._, 1 I w 1.._ • .. •• ,._..._ 

### SERVICE LABORATORIES, INC. 1 eD3 Fhib'Jelpt1ia St.,. lrdiano, PA 15701**(72'~)** 4.')..1-TEST (124) 465·4...?tN



### lample Start Date:**~eceipt** 

### Date: teport Date: Chesapeake Appalachia, LLC 900 Pennsylvania Avenue Attn: Mr. Eric Gillespie Charleston, WV 25302 6/30/2010 7/2/2010 2:41PM 7/6/2010 Analyte Analyst Analysis Date 1) Benzene RO 07/02 47) Toluene RO 07/02

:omments:

DEP Certification #s 32-00382 

## Report of Analysis

Analysis Sample

Time Result

n/a ND n/a 

## ND Sample ID#: Sample Type: Sample Source: Sampler: 10 20503 Waste Water Grab CLIENT (Client) Client Sample ID: 627044 Drill Water Trip Blank

Units Data Method RPL Qualifier ug/L n/a 624/8260B 1.00 ug/L n/a 624/8260B 1.00

I ND=Not Detected

ata Qualifiers: D 

## = The reported value is from dilution. E 

## =Estimated value. S 

## =Surrogate out of control limits. R 

## =Sample received out of holding time. H 

## =Sample analyzed out of holding time. C 

## =Sample received in incorrect container

. B = Analyte was detected in both sample and methods blank. X = User defined data qualifier. Page 1 of 1ENVIRONMENTAL SERVICE LABORATORIES, INC. SAMPLE REQUEST & CHAIN OF CUSTODY OF

HEADQUARlCRS: 1803 Philadelphia Sl Indiana,

PA 15701 (724) 463- TEST (724) 465-4209 00 SOUTliERN DIVISION:
1276 Bendeyville Road

Van

Voorhis, PA 15366 (724) 256- TEST (724) 258-8376

FOR

INTERNAL LAB ORA TORYUSEONL Y D

Sample Identification ESL#

y ,l,(?:/Ji **~~~**

TRIP BLANK Matrix #of Containers

WN -- WN .L3
-- WN -- WN -- WN 2 -- WN -- WN -- WoN 2 -- WN 2 Water 2 Container Type Preservative Plastic Liter none Plastic Liter none Plastic Liter HN0 3 Plastic

Liter

H 2 SO, Plastic Liter HN0 3 Amber

Glass L HCI Amber Glass L

H 2 SO, Amber VOA Vials none Amber VOA Vials HCI Amber VOA Vials HCI r \ **\~~**

: ... **~,** . \ ) ... ''

'\ **\\J.f,~,.**

_I··. !\I

· ' Analysis Requested

pH, SC, Choride. Sulfate, Osmotic

Pressure

, Alkalinity, Acidity

TSS, TDS, Dissolved Iron, Boron,

BOD, MBAS Surfactants

AI, As, Ba, Be, Cd, Cr, Co, Cu, Fe, Pb, Mg,

Mn,

Hg, Ni, Se, Ag, Sr, Zn, Li, Na, Ca, Hardness Nitrate+Nitrite, TKN, Ammonia, COD
Gros5 Alpha , Gros£ Beta

OU & Grease Total Phenolics Ethylene Glycol Benzene, Toluene Benzene, Toluene

THESE SERVICE CHARGES 'I'IIU. ACCRUE AT THE RATE OF 1 112% PER MONTH (18% PER ANNUM OR THE MAXIMUM ALLOWED BY lAW , )

THE

UNDERSIGNED PURCHASER AGREES TO PAY,IN THE EVENT HIS ACCOUNT BECOMES DEUNQUENT AND hS TURNED OVER TO ANY

REASONABLE

AITORNEY"S FEES PLUS ALL COURT AND AITENOANT COLLECTION COSTS. ,\Q. AncJ\/eJ

as So\ . I J Company/Name: Chesapeake Appalachia, LLC.

/l :_

**~** - -(

- f. iV. 1£; !Address:

.

l 900 Pennsylvania Avenue

u f/ vc.

**<~/ -~&0'::&..1**  v- · us -ru 1 contact Person:

**~Af"'_gl\Md**

Bv: **~~ ~~--;-;;y-**  .., /I......,..-- 1:7 **~-·-• ~--**  Phone:

Date/ Time 'F - iM:;;;;;:;;-J:-h: · :; . . ;; .. ;;:::;:::\-

---- -----------l

Contact Person: Phone:

Date/ Time

N OF CUSTODY SEAL BROKEN: Yes No Fax :

# RECEIVED
t!

**~** 

### i \ i I

**ht~~**
**~** i

**if** 

### i: :\.iT;:-'& 3 

## JUL 

# 2 2 

## 2010

• -- .. ,. a.r

**•~•** ,.•"••'9e•il"•· · •·"'• •. .-.a .- :

L .. W: r

**., ~II**  !WI W
... . I:.._ 

### I• 'l.a.i 

### SERVICE LABORATORIES, INC. 1 E03 fN ooelphiO St

., lrtJiona. P A 15701 (724) 4 6.

.'3-TEST (724) A0. '>-420? 

# REGULATORY

Name:

Sample Start Date: Receipt Date: Report Date: Analyte Acidity to pH=8.3 Chesapeake Appalachia, LLC 900 Pennsylvania Avenue Attn: 

### Mr. Eric Gillespie Charleston, WV 25302 6/16/2010 2:45PM 6/18/2010 2:24PM 7/14/2010 Analyst Analysis Date BF 06/21 Alkalinity to pH=4.5 BF 06/28 Biological Oxygen Demand 05 

## szc 06/19 Chemical Oxygen Demand ZTR 06/23 Ammorua as N 

### I Distilled AID 06/28 Chloride BF 06/29 Kjeldah1 Nitrogen as N MAD 

### 07/06 pH(SM) LL 06/18 Sulfate ASTM ZTR 06/22 Total Nitrate +Nitrite as N AID 06/30 Aluminum- ICP GJT 06/29 Arsenic-ICP GJT 06/29 Barium- ICP GJT 06/29 Beryllium

- ICP GJT 07/03 Boron 

### MAD 06/23 Cadmium

- ICP GJT 06/29 Calcium

- ICP GJT 06/29 Chromium

- ICP GJT 06/29 Cobalt- ICP GJT 06129 Copper- ICP GJT 06/29 Hardness GJT 06/29 

## Report of Analysis

Analysis Sample

Time Res11lt

n/a ND 

### n/a 24908 12:15 PM 186

.0 n/a 2670.0 n/a 28.24 n/a 502.2 n/a 216

.0 n/a 8.36 n/a ND 

### n/a 

## * n/a 6915.900 n/a 4.200 n/a 222.700 n/a ND 

### n/a 1.96 n/a ND 

### n/a 12460.000 n/a 11.300 n/a 1.800 n/a 16.600 n/a 46042 Sample ID#: Sample Type: Sample Source: Sampler: 10 18730 Waste Water Grab Client Sample ID: CLIENT (Client) 627043 Drill

Units Data Method Qualifier mg/1 as CaC03 n/a SM2310B mg/1 as CaC03 n/a SM2320B mg/1 H SM52IOB mg/1 D SM5220 D mg/1 n/a SM4500NH3B 

### & D mg/1 n/a SM4500ClC mg/1 n/a SM4500Norg-C,D 

## su n/a SM4500H-B mg/1 0 D516-02 mg/1 X 

### SM4500N03E mg/1 n/a 200.7/6010 mg/1 n/a 200.7/6010 mg/1 n/a 200.7/6010 mg/1 n/a 200

.7/6010 mg/1 D SM4500B-B mg/1 n/a 200.7/6010 mg/1 n/a 200

.7/6010 mg/1 n/a 200

.7/6010 mg/1 n/a 200

.7/6010 mg/1 n/a 200.7/6010 mg/1 n/a SM2340B RPL 2 20 2

.0 1000.0 9.11 1.0 56.9 0.01 25000 0.05 1.000 1.000 0.500 0

.500 1.00 0

.500 50.000 0

.500 0.500 0.500

I
Comments: 

### Due to nature ofsample, a dilution of I :5000 was needed to pass the background check for sulfates. The sample was then analyzed and the result was ND. ZTR 06/22/10 Possible Bias High BOD results DUE TO 

### QAIQC FAILURE RO *Uable to analyze due to sample matrix. GJT 06/30/10 *Unable to analyze for Total Nitrate+ Nitrite due to sample matrix. (AID 06/30/2010) Ethylene Dibromide subcontracted to Metrohm-Peak, ISO# IOOOI397QM08 Radiologicals done by Benchmark Analytical, PADEP Lab 

### ID: 39- 00401 Oil and Grease analyzed by 

### method 9071 for solids due to sample matrix. CLM 07/14/10 jND=Not Detected

Note: DEP Certification #s 32-00382

Data Qualifiers: D ==The reoorted value is from dilution

. E == Estimated value.1 003 Pl'li1adephio St., IMionO. PA 15701 (724) 463"TEST (724) i16!>-420?

Name:

Sample Start Date: Receipt Date: Report Date: Analyte Iron- ICP Iron,Dissolved-ICP Lead-ICP Lithium- ICP Magnesium-ICP Manganese

- ICP Mercury Nickel- ICP Selenium-ICP Silver-ICP Sodium- ICP Strontium- ICP Zinc- ICP Osmotic Pressure Detergents, MBAS Ethylene Glycol Chesapeake Appalachia, LLC 900 Pennsylvania Avenue Attn: Mr. Eric Gillespie Charleston, WV 25302 6/16/2010 2:45PM 6/18/2010 2:24PM 7/14/2010 Aoa_lyst Analysis Date GJT 07/03 GJT 07/06 GJT 06/29 GJT 07/03 GJT 06/29 GJT 06/29 DRM 06/23 GJT 06/29 GJT 

### 06129 GJT 06/29 GJT 06/29 GJT 07/06 GJT 06/29 GJT 07/06 TL 06118 IMetPeak 06/29 Oil and Grease

- HEM CLM 07/13 Phenolics, as Phenol MAD 07/02 Percent Total Solids DRM 06/28 Specific Conductance LL 06/18 Total Dissolved Solids (TDS) LMB 06/23 

## Report of Analysis

Analysis Sample

Time Result

n/a 17727.900 n/a 

## * n/a 8.000 nla 

### ND nla 3625.400 n/a 345.200 nla 0.0290 nla 16.200 nla 

### ND nla 

### ND nla 1114.100 nla 54.300, n/a 38.300 nla 

## * 10:19 AM 

### ND nla <25.000 nla 149.3 n/a 

### ND n/a 51 n/a 1329 nla 38000 Sample ID#: Sample Type: Sample Source: Sampler: 10 18730 Waste Water Grab Client Sample ID: CLIENT (Client) 627043 Drill

Units Data Method Qualifier mg/1 n/a 200.7/6010 mg/1 n/a 200

.7/6010 mg/1 n/a 200.7/6010 mg/1 nla 200.7/6010 mg/1 nla 200.7/6010 mg/1 n/a 200.7/6010 mg/1 n/a 245.1 mg/1 n/a 200.7/6010 mg/1 n/a 200.7/6010 mg/1 n/a 200.7/6010 mg/1 n/a 200.7/6010 mg/1 n/a 200.7/6010 mg/1 n/a 200.7/6010 mOs/kg n/a OSP

mg/1 n/a SM5540C mg/kg n/a 300.0 M mg/kg n/a 1664A mg/1 0 420.1

% n/a SM2540B uS/em n/a SM2510B mg/1 n/a SM2540C RPL 1.000 0.010 0.500 50.000 50.000 0.500 0.0200 0.500 1.000 0.500 50.000 1.000 0.500

100 0.200 25.000

5.0 5.000

5 1 25
Comments: Due to nature of sample, a dilution of 1:5000 was needed to pass the background check for sulfates. The sample was then analyzed and the result was ND

. ZTR 06/22/10 Possible Bias High BOD results DUE TO 

### QNQC FAILURE RO *Uable to analyze due to sample matrix. GJT 06/30/10 *Unable to analyze for Total Nitrate+ Nitrite due to sample matrix. (AID 06/30/2010) Ethylene Dibromide subcontracted to Metrohm-Peak, ISO# 10001397QM08 Radiologicals done by Benchmark Analytical, PADEP Lab ID: 39- 00401 Oil and Grease analyzed by method 9071 for solids due to sample matrix. CLM 07/14110 IND=Not Detected

DEP Certification lis 32-00382



# ------------------ **~01~** Data Qualifiers: D = The reported value is from dilution

. E =Estimated value

. S 

## =SurroQate out of control limits

.

### !;:

**t~!** 

## \!! Df"-:-1 

## i\J

**!\A~** 

## i\J 

# T A 

## ! liiil.l -. W I ..
**"~** I 'WI"' &

... l ':II I tl 'li .. 

### SERVICE lABORATORIES, INC. 11'YJ3 Phl<XJept1ia 

### Sl.

. lrr.:1klna. PA 15701

**(72~)** 46-'FTEST (724) 465-420?

Name:

Sample Start Date: Receipt Daie: Report Date: Analyte Chesapeake Appalachia, LLC 900 Pennsylvania Avenue Attn: 

### Mr. Eric Gillespie Charleston, WV 25302 6/16/2010 2:45PM 6/18/2010 2:24PM 7/14/2010 Analyst Analysis Date Total Suspended Solids LMB 06/23 Radiologicals enchmar 07/03 1) Benzene RO 06/18 47) Toluene RO 06/18 

## Report of Analysis

Analysis Sample

Time Result

n/a 599000 n/a * n/a 

### ND n/a 

### ND Sample ID#: Sample Type: Sample Source: Sampler: 10 18730 Waste Water Grab Client Sample ID: CLIENT (Client) 627043 Drill

Units Data 

### Method Qualifier mg/1 n/a SM2540D mg/1 n/a RAD-CTDHS ug!L n/a 624/8260B ug!L n/a 624/8260B RPL 5 0.000 50.00 50.00

Comments: Due to nature of sample, a dilution of 1:5000 was needed to pass the background check for sulfates. The sample was then analyzed and the result was ND. ZTR 06/22110 Possible Bias High BOD results DUE TO QA/QC FAll.,URE RO *Uable to analyze due to sample matrix. GJT 06/30/10 *Unable to analyze for Total Nitrate+ Nitrite due to sample matrix. (AID 06/30/2010) Ethylene Dibromide subcontracted to Metrohm-Peak, ISO# 10001397QM08 Radiologicals done by Benchmark Analytical, PADEP Lab ID: 39- 00401 Oil and Grease analyzed by method 9071 for solids due to sample matrix. CLM 07/14/10 I ND=Not Detected

DEP Certification #s 32-00382

Data Qualifiers: D = The reported value is from dilution. E = Estimated value

. S = Surrooate out of control limits.**iCf\~\iJri~-~r-'L•~** ACf\it'i'.

**~**

**~** .

**~ ~**  :

**~ ~**  =

**~J** 

## r'::

**~** t.

**~ ~;.**  

### SERVICE tABORATORIES, INC. l e03 Pt•,OCX:Iept)ia Sl

.. lrv..ilt:mo. PA 15701 (724) 46.3-TEST (724) 465

- 420Q



### Name:

Sample Start Date: Receipt Date: Report Date: Analyte Chesapeake Appalachia, LLC 900 Pennsylvania Avenue Attn: 

### Mr. Eric Gillespie Charleston, WV 25302 6/16/2010 2:45 PM 6/18/2010 2:24PM 7/14/2010 Analyst Analysis Date Total Suspended Solids LMB 06/23 Radiologicals enclumu 07/03 l) Benzene RO 06/18 47) Toluene RO 06/18 

## Report 

## ofAnalysis

Analysis Sample

Time Result

nla 599000 n!a 

## * n!a 

### ND nla 

### ND Sample ID#: Sample Type: Sample Source: Sampler: 10 18730 Waste Water Grab Client Sample ID: CLIENT (Client) 627043 Drill

Units Data Method Qualifier mgll n!a SM2540D mg/1 n!a RAD-CTDHS ug!L n!a 624/8260B ug!L n!a 624/8260B RPL 5 0.000 50.00 50

.00

Comments: 

### Due to nature ofsample, a dilution of 1:5000 was needed to pass the background check for sulfates. The sample was then analyzed and the result was ND. ZTR 06/22/10 Possible Bias High BOD results DUE TO QA/QC FAlLURE RO *Uable to analyze due to sample matrix. GJT 06/30/10 *Unable to analyze for Total Nitrate+ Nitrite due to sample matrix. (AID 06/30/2010) Ethylene Dibromide subcontracted to Metrohm-Peak, ISO# 10001397QM08 Radiologicals done by 

### Benchmark Analytical, PADEP Lab ID: 39- 00401 Oil and Grease analyzed by method 9071 for solids due to sample matrix. CLM 07/14/10 fD =Not Detected

Note: DEP Certification #s 32-00382

Data Qualifiers : D =The reported value is from dilution
. E = Estimated value. S 

## =Surroqate out of control limits

.

### LAB 10: 

### 39-00401 

## BENCHMARK ANALYTICS, INC

. 4777 Saucon Creek Road Center Valley, PA 18034-9004 PHONE (610) 974-8100

FAX (610) 974-8104 SEND DATA TO:

. NAME: COMPANY: ADDRESS:

PHONE: FAX: 

### 10 18730 Kathy Brown Environmental Service laboratories, Inc 

### 1803 Philadelphia St Indiana, PA 

### 15701 

### (724) 

### 463-8378 (724) 

### 465-4209 TEST REPORT WO#: PAGE: PO#: PWS ID# 

### Work Order: 10063929

10063929 1 

### of 1

RECEIVED FOR LAB BY: MAK DATE: 

### 06/24/201010:40 Page 

### 1 ofl SAMPLE: 10 18730 SAMPLED BY: Client Lab 10 : 10063929

-001A Grab

Test Gross Alpha Gross Beta Sample Time : 06/16/2010 14 :45 Resu lt Uncert. MDA Units 3969 ± 871

.90 1687.00 pCilkg-dry 2416 ± 528

.20 1447

.00 pCUkg-dry Combined Activity (Alpha 6386 +Beta) pCilkg-dry

REMARKS: Method EPA 900

.0 EPA900.0 Calculation MCL Analysis Start Analysis End Analyst • 06/30/10 9: 00 07/03/10 BPS-CV 06130/10 9: 00 07/03/10 BPS-CV 07106/10 13:33 BPS-CV

Where the analytical method has been performed under NELAP certification, the analysis has met all of the requirements of the NELAC standard unless otherwise noted on the Analytical Report

. • CV =Benchmark Analytics, Inc. Center Valley, PA; SA= Benchmark Analytics , Inc

. Sayre, PA

MANAGER



# ~ t?1.,_L DATE: **--------------=---~---~**

**=-~ --**  **~------------------------** 

# --------------- 711312010LAB ID: 39-00401 LAB ID: 08-00380

SEND DATA TO: NAME: Kathy Brown 

## Benchmark Analytics, Inc. 4777 Saucon Creek Road Center Valley, 

### PA 18034

Phone: (610) 974-8100 Fax: (610) 974-8104 Work Order: 10063929

WO#: COMPANY: ADDRESS: Environmental Service Laboratories, Inc 1803 Philadelphia St PAGE: 10063929 1 of 1

PHONE: FAX : 10 18730 Indiana, PA 15701 

### (724) 463-8378 (724) 465-4209

RECEIVED FOR LAB BY: MAK SAMPLE: 10 18730 SAMPLED BY: Client

Test Percent Moisture

REMARKS: Result 49.9% PO#: 

### TEST REPORT PWS ID#

DATE: 06/24/201 0 10:40 Page 1 of 1 Lab 10: 10063929-001A Grab Sample Time: 06/16/2010 14:45 Method SM2540G EM. Limit Analysis Start Analysis End Analyst • 07107110 14:15 07/09/10 BJW-CV

Where the analytical method has been performed under NELAP certification, the analysis has met all of the requirements of the NELAC standard unless otherwise noted on the Analytical Report. • CV =Benchmark Analytics, Inc. Center Valley, PA; SA= Benchmark Analytics, Inc. Sayre, PA MANAGER



# ------------~ **~--~ ·~**  **~~**
**--** ____________________ DATE : ____ 

### V

_ JJ

_ fl

_ Ol

_

O

____ _

# I

! 

### SERVICE LABORATORIES, INC. I

**~03** Fhi.<.x.1elpt1iO St., lrdbnu.. PA 1

**~, 0**  I (72'4) L16.1-TEST (724) tU\", 42m



### Name:

Sample Start Date: Receipt Date: Report Date: Analyte Chesapeake Appalachia, LLC 900 Pennsylvania Avenue Attn: 

### Mr. Eric Gillespie Charleston, 

### WV 25302 6/16/201 0 2:45 PM 6118/201 0 2:24 PM 6/21/2010 Analyst RO 

### Analysis Date 06118

**~** 

### I) Benzene 47) Toluene RO 

### 06/18

-- 

## Report of Analysis

Analysis Sample

Time Result

n/a 

### ND n/a 

### ND Sample ID#: Sample Type: Sample Source: Sampler: Client Sample ID: 1018731 Waste Water Grab 

### CLIENT (Client) Trip Blank

Units Data Method

_ Qualifier ug!L n/a 624/8260B ug!L n/a 624/8260B 

### RPL 1.00 

# I 1.00

Comments: jND=Not Detected

DEP Certification #s 32-00382

Data Qualifiers: D 

## = The reported value is from dilution. E 

## =Estimated value

. S 

## =Surrogate out of control limits

. R 

### = Sample received out of holding time. H 

### =Sample analyzed out of holding time. C 

## =Sample received in incorrect container

. B = Analyte was detected in both sample and methods blank

. X = User defined data qualifier. Page 1 of 1 

# I