### 13339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone: 980-875-5245 Fax: 980-875-4349 

# Order Summary Report

Analytical Laboratory

Order Number: J10120259

Lab Contact: Jason C Perkins 

### Date: 1/6/2011 Customer Address: 253 Plant Allen Road Customer Name(s): Don Scruggs, Robbin Jolly, Ray Lidke, Bill Kennedy

Belmont, NC 28012
Phone: 980-875-5348 Report Authorized By: (Signature) 

### Program Comments: FGD Test burn #2 - 12/9 Data Flags & Calculations: Any analytical tests or individual analytes within a test flagged with an "X" or "1" indicate a deviation from the method quality system or quality control requirement. All results are reported on a dry weight basis unless otherwise noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions.The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Labor atory Certificate of Analysis, Analytical Laboratory QC Reports, Sub-contracted Laborator y Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods.

## Sample ID's & Descriptions: Sample ID Plant/Station Collection Date and Time Collected By Sample Description 2010013548 ALLEN 09-Dec-10 11:05 AM Chris Greene FGD Purge Eff 2010013549 ALLEN 09-Dec-10 11:06 AM Chris Greene EQ Tank Eff 2010013550 ALLEN 09-Dec-10 11:00 AM Chris Greene BioReactor 1 Inf 2010013551 ALLEN 09-Dec-10 11:04 AM Chris Greene BioReactor 2 Inf 2010013552 ALLEN 09-Dec-10 11:10 AM Chris Greene BioReactor 2 Eff 2010013553 ALLEN 09-Dec-10 Chris Greene Filter Blk 6 Total Samples

### COC and .pdf report are in agreement with sample totals and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. All laboratory QA/QC requirements are acceptable. The Vendor Laboratories have been qualified by the Analytical Laboratory Yes No 

# Technical Validation Review Checklist:

Yes No
Yes No



## Report Sections Included: Job Summary Report Sub-contracted Laboratory Results Sample Identification Customer Specific Data Sheets, Reports, & Documentation Technical Validation of Data Package Customer Database Entries Analytical Laboratory Certificate of Analysis Test Case Narratives Analytical Laboratory QC Report Chain of Custody

Reviewed By: 

### Jenny A Herman Date: 

### 1/6/2011 Yes

Electronic Data Deliverable (EDD) Sent Separately

# Certificate of Laboratory Analysis This re port shall not be re produced, exce pt in full. 

## Order # J10120259

2010013548 Collection Date: 09-Dec-10 11:05 AM 

### Site: FGD Purge Eff Matrix: OTHER
Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

### Sample #:

Analyst MERCURY (COLD VAPOR) IN WATER Mercury (Hg) 19.9 ug/L EPA 245.1 16-Dec-10 14:59 2.5 MHH7131 TOTAL RECOVERABLE METALS BY ICP Boron (B) 186 mg/L EPA 200.7 14-Dec-10 15:20 0.5 DJSULL1 DISSOLVED METALS BY ICP-MS Selenium (Se) 217 ug/L EPA 200.8 27-Dec-10 15:31 10 KRICHAR TOTAL RECOVERABLE METALS BY ICP-MS Arsenic (As) 281 ug/L EPA 200.8 30-Dec-10 14:37 10 KRICHAR Chromium (Cr) 200 ug/L EPA 200.8 30-Dec-10 14:37 10 KRICHAR Copper (Cu) 214 ug/L EPA 200.8 30-Dec-10 14:37 10 KRICHAR Nickel (Ni) 348 ug/L EPA 200.8 30-Dec-10 14:37 10 KRICHAR Selenium (Se) 2070 ug/L EPA 200.8 30-Dec-10 14:37 10 KRICHAR Silver (Ag) < 10 ug/L EPA 200.8 30-Dec-10 14:37 10 KRICHAR Zinc (Zn) 437 ug/L EPA 200.8 30-Dec-10 14:37 20 KRICHAR TOTAL DISSOLVED SOLIDS Vendor Parameter Complete V_PRISM 

### 2010013549 Collection Date: 09-Dec-10 11:06 AM 

### Site: EQ Tank Eff Matrix: OTHER
Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

### Sample #:

Analyst MERCURY (COLD VAPOR) IN WATER Mercury (Hg) 18.4 ug/L EPA 245.1 16-Dec-10 15:02 2.5 MHH7131 TOTAL RECOVERABLE METALS BY ICP Boron (B) 148 mg/L EPA 200.7 14-Dec-10 15:25 0.5 DJSULL1 DISSOLVED METALS BY ICP-MS Selenium (Se) 124 ug/L EPA 200.8 27-Dec-10 15:46 10 KRICHAR TOTAL RECOVERABLE METALS BY ICP-MS Arsenic (As) 155 ug/L EPA 200.8 30-Dec-10 14:43 10 KRICHAR Chromium (Cr) 121 ug/L EPA 200.8 30-Dec-10 14:43 10 KRICHAR Copper (Cu) 137 ug/L EPA 200.8 30-Dec-10 14:43 10 KRICHAR Nickel (Ni) 236 ug/L EPA 200.8 30-Dec-10 14:43 10 KRICHAR Selenium (Se) 1140 ug/L EPA 200.8 30-Dec-10 14:43 10 KRICHAR Silver (Ag) < 10 ug/L EPA 200.8 30-Dec-10 14:43 10 KRICHAR Zinc (Zn) 267 ug/L EPA 200.8 30-Dec-10 14:43 20 KRICHAR

# Certificate of Laboratory Analysis This re port shall not be re produced, exce pt in full. 

## Order # J10120259

2010013550 Collection Date: 09-Dec-10 11:00 AM 

### Site: BioReactor 1 Inf Matrix: OTHER
Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

### Sample #:

Analyst TOTAL RECOVERABLE METALS BY ICP Boron (B) 131 mg/L EPA 200.7 14-Dec-10 15:48 0.5 DJSULL1 DISSOLVED METALS BY ICP-MS Selenium (Se) 92.8 ug/L EPA 200.8 27-Dec-10 15:49 10 KRICHAR TOTAL RECOVERABLE METALS BY ICP-MS Arsenic (As) < 10 ug/L EPA 200.8 30-Dec-10 14:48 10 KRICHAR Chromium (Cr) < 10 ug/L EPA 200.8 30-Dec-10 14:48 10 KRICHAR Copper (Cu) < 10 ug/L EPA 200.8 30-Dec-10 14:48 10 KRICHAR Nickel (Ni) 33.0 ug/L EPA 200.8 30-Dec-10 14:48 10 KRICHAR Selenium (Se) 83.7 ug/L EPA 200.8 30-Dec-10 14:48 10 KRICHAR Silver (Ag) < 10 ug/L EPA 200.8 30-Dec-10 14:48 10 KRICHAR Zinc (Zn) < 20 ug/L EPA 200.8 30-Dec-10 14:48 20 KRICHAR 

### 2010013551 Collection Date: 09-Dec-10 11:04 AM 

### Site: BioReactor 2 Inf Matrix: OTHER
Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

### Sample #:

Analyst TOTAL RECOVERABLE METALS BY ICP Boron (B) 119 mg/L EPA 200.7 14-Dec-10 15:52 0.5 DJSULL1 TOTAL RECOVERABLE METALS BY ICP-MS Arsenic (As) < 10 ug/L EPA 200.8 30-Dec-10 15:04 10 KRICHAR Chromium (Cr) < 10 ug/L EPA 200.8 30-Dec-10 15:04 10 KRICHAR Copper (Cu) < 10 ug/L EPA 200.8 30-Dec-10 15:04 10 KRICHAR Nickel (Ni) 40.9 ug/L EPA 200.8 30-Dec-10 15:04 10 KRICHAR Selenium (Se) < 10 ug/L EPA 200.8 30-Dec-10 15:04 10 KRICHAR Silver (Ag) < 10 ug/L EPA 200.8 30-Dec-10 15:04 10 KRICHAR Zinc (Zn) < 20 ug/L EPA 200.8 30-Dec-10 15:04 20 KRICHAR 

### 2010013552 Collection Date: 09-Dec-10 11:10 AM 

### Site: BioReactor 2 Eff Matrix: OTHER
Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

### Sample #:

Analyst MERCURY (COLD VAPOR) IN WATER Mercury (Hg) < 1 ug/L EPA 245.1 16-Dec-10 15:04 1 MHH7131 TOTAL RECOVERABLE METALS BY ICP Boron (B) 81.5 mg/L EPA 200.7 14-Dec-10 15:56 0.5 DJSULL1 TOTAL RECOVERABLE METALS BY ICP-MS Arsenic (As) < 5 ug/L EPA 200.8 30-Dec-10 15:09 5 KRICHAR

# Certificate of Laboratory Analysis This re port shall not be re produced, exce pt in full. 

## Order # J10120259

2010013552 Collection Date: 09-Dec-10 11:10 AM 

### Site: BioReactor 2 Eff Matrix: OTHER
Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

### Sample #:

Analyst TOTAL RECOVERABLE METALS BY ICP-MS Chromium (Cr) < 5 ug/L EPA 200.8 30-Dec-10 15:09 5 KRICHAR Copper (Cu) < 5 ug/L EPA 200.8 30-Dec-10 15:09 5 KRICHAR Nickel (Ni) < 5 ug/L EPA 200.8 30-Dec-10 15:09 5 KRICHAR Selenium (Se) < 5 ug/L EPA 200.8 30-Dec-10 15:09 5 KRICHAR Silver (Ag) < 5 ug/L EPA 200.8 30-Dec-10 15:09 5 KRICHAR Zinc (Zn) < 10 ug/L EPA 200.8 30-Dec-10 15:09 10 KRICHAR 

### 2010013553 Collection Date: 09-Dec-10 

### Site: Filter Blk Matrix: OTHER
Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

### Sample #:

Analyst DISSOLVED METALS BY ICP-MS Selenium (Se) < 2 ug/L EPA 200.8 27-Dec-10 15:54 2 KRICHAR

### This data package contains the analytical results for the project identified above and includes a Case Narrative, Sample Results and Chain of Custody. Unless otherwise noted, all samples were received in acceptable condition and processed according to the referenced methods. Data qualifiers are flagged individually on each sample. A key reference for the data qualifiers appears at the end of this case narrative. NC Certification No. 402 SC Certification No. 99012 NC Drinking Water Cert No. 37735 

# Case Narrative 12/27/2010

Duke Energy Corporation Jay Perkins 13339 Hagers Ferry Road Huntersville, NC 28078 Project: Allen - FGD Alternative Fuels Test Burn #2 Daily Project No.: J10120259 Lab Submittal Date: 12/13/2010 Prism Work Order: 0120406

Please call if you have any questions relating to this analytical report. Respectfully, PRISM LABORATORIES, INC.



### VP Laboratory Services Reviewed By

Data Qualifiers Key Reference:



### Method Detection Limit MDL Below Reporting Limit BRL Relative Percent Difference RPD 

## * Results reported to the reporting limit. All other results are reported to the MDL with values between MDL and reporting limit indicated with a J.

This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.

449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 

## Page 1 of 5

# Sample Receipt Summary 12/27/2010 

## Prism Work Order: 0120406 Client Sample ID Matrix Lab Sample ID Date Sampled Date Received 

### 0120406-01 12/09/10 2010013548/FGD Purge Eff 12/13/10 Water Samples received in good condition at 1.5 degrees C unless otherwise noted.

This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.

449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 

## Page 2 of 5

# Laboratory Report 12/27/2010

Result Parameter Batch ID Report Limit Analysis Date/Time Method Dilution Factor Units MDL Analyst 

### 13339 Hagers Ferry Road Project No.: J10120259 Project: Allen - FGD Alternative Fuels Test Burn #2 Daily Duke Energy Corporation
Huntersville, NC 28078 Attn: Jay Perkins Sample Matrix: Water Client Sample ID: 2010013548/FGD Purge E Prism Sample ID: 0120406-01 Prism Work Order: 0120406 Time Collected: 12/09/10 11:05 Time Submitted: 12/13/10 15:00

General Chemistry Parameters 10000 *SM2540 C P0L0357 1 50 12/16/10 14:00 JAB mg/L 8.7 Total Dissolved Solids

This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 

## Page 3 of 5

### 12/27/10 

## Level II QC Report

13339 Hagers Ferry Road Project No: J10120259 Project: Allen - FGD Alternative Fuels Test Burn #2 Daily Duke Energy Corporation Huntersville, NC 28078 Attn: Jay Perkins Prism Work Order: 0120406 Time Submitted: 12/13/10 3:00:00PM

Result Limit

Reporting Units Level Spike Result

Source %REC %REC Limits RPD RPD Limit Notes Analyte General Chemistry Parameters - Quality Control



### Batch P0L0357 - NO PREP Blank (P0L0357-BLK1) 

### Prepared & Analyzed: 12/16/10 Total Dissolved Solids mg/L BRL 50 LCS (P0L0357-BS1) 

### Prepared & Analyzed: 12/16/10 Total Dissolved Solids mg/L 998 50 1000 90-110 100 Duplicate (P0L0357-DUP1) 

### Prepared & Analyzed: 12/16/10 Source: 0120406-01 Total Dissolved Solids mg/L 9820 50 9990 20 2 

### Sample Extraction Data NO PREP Lab Number Batch Date Initial Final P0L0357 0120406-01 12/16/10 50 50 mL mL

This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.

449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 

## Page 4 of 5Page 5 of 5