# Patent

## Title
Composition comprising HF, 3,3,3-trifluoro-2-chloropropene, and E-3,3,3-trifluoro-1-chloropropene

## Abstract

An azeotropic or quasi-azeotropic composition including hydrogen fluoride, 3,3,3-trifluoro-2-chloropropene and one or more (hydro)halogen-carbon compounds including between 1 and 3 carbon atoms. Also an azeotropic or quasi-azeotropic composition including hydrogen fluoride, 3,3,3-trifluoro-2-chloropropene, and one or more compounds selected from among 1,3,3,3-tetrafluoropropene, 1,1,1,2,2-pentafluoropropane, 2,3,3,3-tetrafluoropropene, 3,3,3-trifluoropropene, E-3,3,3-trifluoro-1-chloropropene, trifluoropropyne, 1,1,3,3-pentafluoropropane, 1,1,1,3,3-pentafluoropropane, 1,1,1,3,3-pentafluoropropene, 1,1,1,2,3-pentafluoropropene and 2-chloro,1,1,1,2-1 tetrafluoropropane.

## Background
The present invention relates to azeotropic or quasi-azeotropic compositions comprising 3,3,3-trifluoro-2-chloropropene and hydrogen fluoride. These compositions may originate from intermediate compositions in the production of 3,3,3-trifluoro-2-chloropropene and are generally useful in processes for recycling hydrogen fluoride.
The manufacture of 3,3,3-trifluoro-2-chloropropene accompanied by a multitude of by-products, having a boiling point close to HCFO-1233xf, leads to relatively complex and expensive purification steps. The difficulty encountered during the purification of HCFO-1233xf generally implies an appreciable loss of desired product. Furthermore, these by-products may form azeotropic compositions with 3,3,3-trifluoro-2-chloropropene, making separation by distillation simple, very difficult, or even impossible.
Fluids comprising 3,3,3-trifluoro-2-chloropropene are promising for numerous applications in varied industrial fields, especially as reaction intermediate, heat-transfer fluid, propellants, foaming agents, swelling agents, gaseous dielectrics, polymerization medium or monomer, support fluids, abrasive agents, drying agents and fluids for power production units.
Particular importance is given to fluids that have a low impact on the environment.
The subject of the present invention is an azeotropic or quasi-azeotropic composition comprising hydrogen fluoride, 3,3,3-trifluoro-2-chloropropene and one or more (hydro)halocarbon compounds comprising between 1 and 3 carbon atoms.
According to one embodiment of the invention, the composition is heteroazeotropic or quasi-heteroazeotropic.
A heteroazeotropic or quasi-heteroazeotropic mixture is an azeotropic or quasi-azeotropic mixture in which the condensed liquid forms two immiscible solutions that can be readily separated, for example by decantation. This property is a considerable advantage for the recovery of HF.
The term “quasi-azeotropic” or “quasi-heteroazeotropic” has a broad meaning and is intended to include compositions that are strictly azeotropic or strictly heteroazeotropic and those that behave like an azeotropic or heteroazeotropic mixture.
A mixture is azeotropic when the pressure at the dew point is equal to that at the bubble formation point, which means that the vapor composition is equal to that of the condensed liquid.
A mixture is considered as quasi-azeotropic when the pressure at the dew point is substantially equal to that at the bubble formation point, which means that the vapor composition is substantially equal to that of the condensed liquid.
Another way of characterizing a mixture as quasi-azeotropic when the pressure difference between the pressure at the dew point and the pressure at the bubble formation point is low, preferentially less than or equal to 5%, on the basis of the pressure at the bubble formation point.
Compositions according to the invention especially concern the following compounds, the acronyms of which represent:

    
    
        HF: hydrogen fluoride
        HCC-40: chloromethane, or CH3Cl
        HCFC-115: chloropentafluoroethane, or C2F5Cl
        HCFC-124: chlorotetrafluoroethane, or C2HF4Cl
        HFC-125: pentafluoroethane, or C2HF5 
        HCFC-133a: 1-chloro-2,2,2-trifluoroethane, or C2H2F3Cl
        HFC-134a: 1,1,1,2-tetrafluoroethane, or C2H2F4 
        HCFC-142b: 1-chloro-1,1-difluoroethane, or C2H3F2Cl
        HFC-143a: 1,1,1-trifluoroethane, or C2H3F3 
        HFC-152a: 1,1-difluoroethane, or C2H4F2 
        HFO-1132: 1,2-difluoroethylene, or C2H2F2 
        HFO-1141: fluoroethylene, or C2H3F
        HFO-1234yf: 2,3,3,3-tetrafluoropropene or CH2═CF—CF3 
        HFC-245cb: 1,1,1,2,2-pentafluoropropane or CF3—CF2—CH3 
        HFO-1234zeE: E-1,3,3,3-tetrafluoropropene or E-CF3—CH═CHF
        HFO-1234zeZ: Z-1,3,3,3-tetrafluoropropene or Z—CF3—CH═CHF
        HFO-1243zf: 3,3,3-trifluoropropene or CF3—CH═CH2 
        HCFO-1233xf: 3,3,3-trifluoro-2-chloropropene or CF3—CCl═CH2 
        HCFO-1233zdE: E-3,3,3-trifluoro-1-chloropropene or E-CF3—CH═CHCl
        HCFO-1233zdZ: Z-3,3,3-trifluoro-1-chloropropene or Z—CF3—CH═CHCl
        HFO-1225yeZ: Z-1,1,1,2,3-pentafluoropropene or Z—CHF═CF—CF3 
        HFO-1225yeE: E-1,1,1,2,3-pentafluoropropene or E-CHF═CF—CF3 
        HFO-1225zc: 1,1,3,3,3-pentafluoropropene or CF2═CH—CF3 
        HFO-1225yc: 1,1,2,3,3-pentafluoropropene or CF2═CF—CF2 
        HCFC-1214: dichlorotetrafluoropropene, or C3F4Cl2 
        HCFO-1215: chloropentafluoropropene, or C3F5Cl
        HFO-1216: hexafluoropropene, or C3F6 
        HCFO-1223: dichlorotrifluoropropene, or C3HF3Cl2 
        HCFO-1224: chlorotetrafluoropropene, or C3HF4Cl
        HCFO-1232: dichlorodifluoropropene, or C3H2F2Cl2 
        HCFO-1233xc: 1,1,3-trifluoro-2-chloropropene or CH2F—CCl═CF2 
        HCFO-1233xe: 1,3,3-trifluoro-2-chloropropene or CHF2—CCl═CHF
        HCFO-1233yb: 1,2,3-trifluoro-1-chloropropene or CH2F—CF═CFCl
        HCFO-1233yc: 1,1,2-trifluoro-3-chloropropene or CH2Cl—CF═CF2 
        HCFO-1233yd: 2,3,3-trifluoro-1-chloropropene or CHF2—CF═CHCl
        HCFO-1233ye: 1,2,3-trifluoro-3-chloropropene or CHClF—CF═CHF
        HCFO-1233yf: 2,3,3-trifluoro-3-chloropropene or CClF2—CF═CH2 
        HCFO-1233zb: 1,3,3-trifluoro-1-chloropropene or CHF2—CH═CFCl
        HCFO-1233zc: 1,1,3-trifluoro-3-chloropropene or CHClF—CH═CF2 
        HCFO-1233ze: 1,3,3-trifluoro-3-chloropropene or CClF2—CH═CHF
        HFO-1234yc: 1,1,2,3-tetrafluoropropene or CF2═CF—CH2F
        HFO-1234ye: 1,2,3,3-tetrafluoropropene or CHF═CF—CHF2 
        HFO-1234zc: 1,1,3,3-tetrafluoropropene or CF2═CH—CHF2 
        HCFO-1242: chlorodifluoropropene, or C3H3F2Cl
        HFO-1243yc: 1,1,2-trifluoropropene or CH3—CF═CF2 
        HFO-1243ye: 1,2,3-trifluoropropene or CH2F—CF═CHF
        HFO-1243yf: 2,3,3-trifluoropropene or CHF2—CF═CH2 
        HFO-1243zc: 1,1,3-trifluoropropene or CH2F—CH═CF2 
        HFO-1243ze: 1,3,3-trifluoropropene or CHF2—CH═CHF
        HCFO-1251: chlorofluoropropene, or C3H4FCl
        HFO-1252: difluoropropene, or C3H4F2 
        HFO-216: hexafluoropropene, or C3F6Cl2 
        HCFO-217: chloroheptafluoropropane, or C3F7Cl
        HFC-218: octafluoropropane, or C3F8 
        HCFC-225: dichloropentafluoropropane, or C3HF5Cl2 
        HCFC-226: chlorohexafluoropropane, or C3HF6Cl
        HFC-227: heptafluoropropane, or C3HF7 
        HCFC-234: dichlorotetrafluoropropane, or C3H2F4Cl2 
        HCFC-235: chloropentafluoropropane, or C3H2F5Cl
        HFC-236: hexafluoropropane, or C3H2F6 
        HCFC-243: dichlorotrifluoropropane, or C3H3F3Cl2 
        HCFC-244: chlorotetrafluoropropane, or C3H3F4Cl
        HCFC-244bb: 2-chloro,1,1,1,2-tetrafluoropropane or CF3—CFCl—CH3 
        HFC-245fa: 1,1,1,3,3-pentafluoropropane or CF3—CH2—CHF2 
        HFC-245ea: 1,1,2,3,3-pentafluoropropane or CHF2—CHF—CHF2 
        HFC-245eb: 1,1,1,2,3-pentafluoropropane or CF3—CHF—CH2F
        HFC-245ca: 1,1,2,2,3-pentafluoropropane or CHF2—CF2—CH2F
        HCFC-253: chlorotrifluoropropane, or C3H4F3Cl
        HFC-254: tetrafluoropropane, or C3H4F4 
        HCFC-262: Chlorodifluoropropane, or C3H5F2Cl
        HFC-263: trifluoropropane, or C3H5F3 
        Trifluoropropyne: CF3—C≡CH
    
    


The composition according to the invention may optionally be a mixture of one or more azeotropes and/or heteroazeotropes of ternary, quaternary, penternary systems, systems with six compounds, systems with seven compounds, systems with eight or more compounds.
The compound(s) containing 1 and/or 2 carbon atoms may be chosen especially from chloromethane, chloropentafluoroethane, 1-chloro-1,2,2,2-tetrafluoroethane, 1-chloro-1,1,2,2-tetrafluoroethane, pentafluoroethane, 1-chloro-1,2,2-trifluoroethane, 1-chloro-2,2,2-trifluoroethane, 1,1,2,2-tetrafluoroethane, 1,1,1,2-tetrafluoroethane, 1-chloro-1,2-difluoroethane, 1-chloro-1,1-difluoroethane, 1,1,2-trifluoroethane, 1,1,1-trifluoroethane, 1,1,2-trifluoroethane, 1,1-difluoroethane, 1,2-difluoroethylene and fluoroethylene.
The compound(s) containing 3 carbon atoms may be chosen especially from 1,2-dichloro-1,1,2,3,3,3-hexafluoropropane, 1,3-dichloro-1,1,2,2,3,3-hexafluoropropane, 1,1-dichloro-1,2,2,3,3,3-hexafluoropropane, 2,2-dichloro-1,1,1,3,3,3-hexafluoropropane, 1-chloro-1,1,2,2,3,3,3-heptafluoropropane, 2-chloro-1,1,1,2,3,3,3-heptafluoropropane, octafluoropropane, dichloropentafluoropropane, 2,2-dichloro-1,1,1,3,3-pentafluoropropane, 2,3-dichloro-1,1,1,2,3-pentafluoropropane, 1,2-dichloro-1,1,2,3,3-pentafluoropropane, 3,3-dichloro-1,1,1,2,2-pentafluoropropane, 1,3-dichloro-1,1,2,2,3-pentafluoropropane, 1,1-dichloro-1,2,2,3,3-pentafluoropropane, 1,2-dichloro-1,1,3,3,3-pentafluoropropane, 1,3-dichloro-1,1,2,3,3-pentafluoropropane, 1,1-dichloro-1,2,3,3,3-pentafluoropropane, chlorohexafluoropropane, 2-chloro-1,1,1,2,3,3-hexafluoropropane, 3-chloro-1,1,1,2,2,3-hexafluoropropane, 1-chloro-1,1,2,2,3,3-hexafluoropropane, 2-chloro-1,1,1,3,3,3-hexafluoropropane, 1-chloro-1,1,2,3,3,3-hexafluoropropane, 1,1,2,2,3,3,3-heptafluoropropane, 1,1,1,2,3,3,3-Heptafluoropropane, dichlorotetrafluoropropane, 2,2-dichloro-1,1,3,3-tetrafluoropropane, 2,2-dichloro-1,1,1,3-tetrafluoropropane, 1,2-dichloro-1,2,3,3-tetrafluoropropane, 2,3-dichloro-1,1,1,2-tetrafluoropropane, 1,2-dichloro-1,1,2,3-tetrafluoropropane, 1,3-dichloro-1,2,2,3-tetrafluoropropane, 1,1-dichloro-2,2,3,3-tetrafluoropropane, 1,3-dichloro-1,1,2,2-tetrafluoropropane, 1,1-dichloro-1,2,2,3-tetrafluoropropane, 2,3-dichloro-1,1,1,3-tetrafluoropropane, 1,3-dichloro-1,1,3,3-tetrafluoropropane, 1,3-dichloro-1,1,3,3-tetrafluoropropane, 1,1-dichloro-1,3,3,3-tetrafluoropropane, 1,1-dichloro-2,3,3,3-tetrafluoropropane, 1,3-dichloro-1,1,2,3-tetrafluoropropane, 1,1-dichloro-1,2,3,3-tetrafluoropropane, chloropentafluoropropane, 1-chloro-1,2,2,3,3-pentafluoropropane, 3-chloro-1,1,1,2,3-pentafluoropropane, 1-chloro-1,1,2,2,3-pentafluoropropane, 2-chloro-1,1,1,3,3-pentafluoropropane, 1-chloro-1,1,3,3,3-pentafluoropropane, 1-chloro-1,1,2,3,3-pentafluoropropane, 3-chloro-1,1,1,2,2-pentafluoropropane, 2-chloro-1,1,2,3,3-pentafluoropropane, 2-chloro-1,1,1,2,3-pentafluoropropane, 1,1,1,2,2,3-hexafluoropropane, 1,1,1,2,3,3-hexafluoropropane, 1,1,1,3,3,3-hexafluoropropane, 1,1,2,2,3,3-hexafluoropropane, dichlorotrifluoropropane, 1,1-dichloro-3,3,3-trifluoropropane, 1,3-dichloro-1,1,3-trifluoropropane, 1,1-dichloro-1,3,3-trifluoropropane, 1,3-dichloro-1,2,3-trifluoropropane, 1,1-dichloro-2,3,3-trifluoropropane, 1,3-dichloro-1,1,2-trifluoropropane, 1,1-dichloro-1,2,3-trifluoropropane, 1,2-dichloro-1,3,3-trifluoropropane, 2,3-dichloro-1,1,1-trifluoropropane, 1,2-dichloro-1,1,3-trifluoropropane, 1,3-dichloro-1,2,2-trifluoropropane, 1,1-dichloro-2,2,3-trifluoropropane, 1,1-dichloro-1,2,2-trifluoropropane, 2,3-dichloro-1,1,2-trifluoropropane, 1,2-dichloro-1,2,3-trifluoropropane, 1,2-dichloro-1,2-trifluoropropane, 2,2-dichloro-1,1,3-trifluoropropane, 2,2-dichloro-3,3,3-trifluoropropane, chlorotetrafluoropropane, 2-chloro-1,2,3,3-tetrafluoropropane, 2-chloro-1,1,1,2-tetrafluoropropane, 3-chloro-1,1,2,2-tetrafluoropropane, 1-chloro-1,2,2,3-tetrafluoropropane, 1-chloro-1,1,2,2-tetrafluoropropane, 2-chloro-1,1,3,3-tetrafluoropropane, 2-chloro-1,1,1,3-tetrafluoropropane, 3-chloro-1,1,2,3-tetrafluoropropane, 3-chloro-1,1,1,2-tetrafluoropropane, 1-chloro-1,1,2,3-tetrafluoropropane, 3-chloro-1,1,1,3-tetrafluoropropane, 1-chloro-1,1,3,3-tetrafluoropropane, pentafluoropropane, 1,1,1,2,2-pentafluoropropane, 1,1,2,2,3-pentafluoropropane, 1,1,2,3,3-pentafluoropropane, 1,1,1,2,3-pentafluoropropane, 1,1,1,3,3-pentafluoropentane, chlorotrifluoropropane, 2-chloro-1,2,3-trifluoropropane, 2-chloro-1,1,2-trifluoropropane, 1-chloro-2,2,3-trifluoropropane, 1-chloro-1,2,2-trifluoropropane, 3-chloro-1,1,2-trifluoropropane, 1-chloro-1,2,3-trifluoropropane, 1-chloro-1,1,2-trifluoropropane, 3-chloro-1,3,3-trifluoropropane, 3-chloro-1,1,1-trifluoropropane, 1-chloro-1,1,3-trifluoropropane, 2-chloro-1,1,3-trifluoropropane, 2-chloro-1,1,1-trifluoropropane, 1,1,2,2-tetrafluoropropane, 1,1,1,3-tetrafluoropropane, 1,1,2,3-tetrafluoropropane, 1,1,1,2-tetrafluoropropane, 1,2,2,3-tetrafluoropropane, 1,1,3,3-tetrafluoropropane, chlorodifluoropropane, 1-chloro-2,2-difluoropropane, 3-chloro-1,1-difluoropropane, 1-chloro-1,3-difluoropropane, 1-chloro-1,1-difluoropropane, 1-chloro-2,3-difluoropropane, 1-chloro-1,2-difluoropropane, 2-chloro-1,3-difluoropropane, 2-chloro-1,1-difluoropropane, 2-chloro-1,2-difluoropropane, trifluoropropane, 1,1,1-trifluoropropane, 1,1,3-trifluoropropane, 1,2,3-trifluoropropane, 1,1,2-trifluoropropane, 1,2,2-trifluoropropane, dichlorotetrafluoropropene, 1,2-dichloro-1,3,3,3-tetrafluoropropene, 1,1-dichloro-2,3,3,3-tetrafluoropropene, 1,3-dichloro-1,2,3,3-tetrafluoropropene, 2,3-dichloro-1,1,3,3-tetrafluoropropene, 3,3-dichloro-1,1,2,3-tetrafluoropropene, chloropentafluoropropene, 1-chloropentafluoropropene, 2-chloropentafluoropropene, 3-chloropentafluoropropene, hexafluoropropene, dichlorotrifluoropropene, 1,1-dichloro-3,3,3-trifluoropropene, 1,2-dichloro-3,3,3-trifluoropropene, 2,3-dichloro-1,3,3-trifluoropropene, 1,3-dichloro-2,3,3-trifluoropropene, 1,2-dichloro-1,3,3-trifluoropropene, 2,3-dichloro-1,1,3-trifluoropropene, 1,1-dichloro-2,3,3-trifluoropropene, 1,3-dichloro-1,2,3-trifluoropropene, 3,3-dichloro-1,1,2-trifluoropropene, 3,3-dichloro-1,2,3-trifluoropropene, 1,3-dichloro-1,3,3-trifluoropropene, 3,3-dichloro-1,1,3-trifluoropropene, 1-chloro-2,3,3,3-tetrafluoropropene, 1-chloro-1,3,3,3-tetrafluoropropene, 2-chloro-1,3,3,3-tetrafluoropropene, 3-chloro-1,2,3,3-tetrafluoropropene, 3-chloro-1,1,3,3-tetrafluoropropene, 2-chloro-1,1,3,3-tetrafluoropropene, 1-chloro-1,2,3,3-tetrafluoropropene, 3-chloro-1,1,2,3-tetrafluoropropene, 1,2,3,3,3-pentafluoropropene, 1,1,3,3,3-pentafluoropropene, 1,1,2,3,3-pentafluoropropene, dichlorodifluoropropene, 2,3-dichloro-3,3-difluoropropene, 1,2-dichloro-1,3-difluoropropene, 2,3-dichloro-1,1-difluoropropene, 1,2-dichloro-3,3-difluoropropene, 2,3-dichloro-1,3-difluoropropene, 1,1-dichloro-2,3-difluoropropene, 1,3-dichloro-1,2-difluoropropene, 1,3-dichloro-2,3-difluoropropene, 3,3-dichloro-1,2-difluoropropene, 3,3-dichloro-2,3-difluoropropene, 1,1-dichloro-3,3-difluoropropene, 1,3-dichloro-1,3-difluoropropene, 3,3-dichloro-1,1-difluoropropene, 1,3-dichloro-3,3-difluoropropene, 3,3-dichloro-1,3-difluoropropene, chlorotrifluoropropene, 2-chloro-1,1,3-trifluoropropene, 2-chloro-1,3,3-trifluoropropene, 1-chloro-1,2,3-trifluoropropene, 3-chloro-1,1,2-trifluoropropene, 1-chloro-2,3,3-trifluoropropene, 3-chloro-1,2,3-trifluoropropene, 3-chloro-2,3,3-trifluoropropene, 1-chloro-1,3,3-trifluoropropene, 3-chloro-1,1,3-trifluoropropene, 3-chloro-1,3,3-trifluoropropene, 2,3,3,3-tetrafluoropropene, 1,1,2,3-tetrafluoropropene, 1,2,3,3-tetrafluoropropene, 1,1,3,3-tetrafluoropropene, chlorodifluoropropene, 3-chloro-3,3-difluoropropene, 3-chloro-1,3-difluoropropene, 2-chloro-1,1-difluoropropene, 2-chloro-1,3-difluoropropene, 2-chloro-3,3-difluoropropene, 1-chloro-1,2-difluoropropene, 1-chloro-2,3-difluoropropene, 3-chloro-1,2-difluoropropene, 3-chloro-2,3-difluoropropene, 1-chloro-1,3-difluoropropene, 3-chloro-1,1-difluoropropene, 1-chloro-3,3-difluoropropene, trifluoropropene, 1,1,2-trifluoropropene, 1,2,3-trifluoropropene, 2,3,3-trifluoropropene, 1,1,3-trifluoropropene, 1,3,3-trifluoropropene, chlorofluoropropene, 1-chloro-3-fluoropropene, 1-chloro-1-fluoropropene, 1-chloro-2-fluoropropene, 2-chloro-1-fluoropropene, 2-chloro-3-fluoropropene, 3-chloro-2-fluoropropene, 3-chloro-1-fluoropropene, 3-chloro-3-fluoropropene, difluoropropene, 1,2-difluoropropene, 2,3-difluoropropene, 1,1-difluoropropene, 1,3-difluoropropene, 3,3-difluoropropene, E-1,3,3,3-tetrafluoropropene, Z-1,3,3,3-tetrafluoropropene, 3,3,3-trifluoropropene, 3,3,3-trifluoro-2-chloropropene, E-3,3,3-trifluoro-1-chloropropene, Z-3,3,3-trifluoro-1-chloropropene and trifluoropropyne.
Preferably, the ternary compositions consisting essentially of HF-HFCO-1233xf-HFC-245fcb, HF-HFCO-1233xf-HCFC-244bb and HF-HCFO-1233xf-HFO-1230xa (1,1,2,3-tetrachloropropene) are excluded from the present invention.
A subject of the present invention is also an azeotropic or quasi-azeotropic composition comprising hydrogen fluoride, 3,3,3-trifluoro-2-chloropropene, and one or more compounds chosen from E-1,3,3,3-tetrafluoropropene, Z-1,3,3,3-tetrafluoropropene, 3,3,3-trifluoropropene, 2,3,3,3-tetrafluoropropene, E-3,3,3-trifluoro-1-chloropropene, trifluoropropyne, 1,1,1,3,3-pentafluoropropane, 1,1,1,3,3-pentafluoropropene, 1,1,1,2,2-pentafluoropropane, 2-chloro-1,1,1,2-tetrafluoropropane and 1,1,1,2,3-pentafluoropropene.
A subject of the present invention is also a composition comprising hydrogen fluoride, 3,3,3-trifluoro-2-chloropropene and at least one or more organic compounds chosen from E-3,3,3-trifluoro-1-chloropropene, E-1,3,3,3-tetrafluoropropene, Z-1,3,3,3-tetrafluoropropene, 3,3,3-trifluoropropene, 1,1,1,2,2-pentafluoropropane and 2,3,3,3-tetrafluoropropene.
According to one embodiment, the composition according to the invention comprises hydrogen fluoride, 3,3,3-trifluoro-2-chloropropene, E-1,3,3,3-tetrafluoropropene and optionally one or more compounds chosen from Z-1,3,3,3-tetrafluoropropene, 3,3,3-trifluoropropene, 2,3,3,3-tetrafluoropropene, E-3,3,3-trifluoro-1-chloropropene, trifluoropropyne, 1,1,1,3,3-pentafluoropropane, 1,1,1,3,3-pentafluoropropene, 1,1,1,2,2-pentafluoropropane, 2-chloro-1,1,1,2-tetrafluoropropane and 1,1,1,2,3-pentafluoropropene.
According to another embodiment, the composition according to the invention comprises hydrogen fluoride, 3,3,3-trifluoro-2-chloropropene, Z-1,3,3,3-tetrafluoropropene and optionally one or more compounds chosen from 3,3,3-trifluoropropene, 2,3,3,3-tetrafluoropropene, E-3,3,3-trifluoro-1-chloropropene, trifluoropropyne, 1,1,1,3,3-pentafluoropropane, 1,1,1,3,3-pentafluoropropene, 1,1,1,2,2-pentafluoropropane, 2-chloro-1,1,1,2-tetrafluoropropane and 1,1,1,2,3-pentafluoropropene.
According to one embodiment, the composition according to the invention comprises hydrogen fluoride, 3,3,3-trifluoro-2-chloropropene, 3,3,3-trifluoropropene and optionally one or more compounds chosen from 2,3,3,3-tetrafluoropropene, E-3,3,3-trifluoro-1-chloropropene, trifluoropropyne, 1,1,1,3,3-pentafluoropropane, 1,1,1,3,3-pentafluoropropene, 1,1,1,2,2-pentafluoropropane, 2-chloro-1,1,1,2-tetrafluoropropane and 1,1,1,2,3-pentafluoropropene.
According to another embodiment, the composition according to the invention comprises hydrogen fluoride, 3,3,3-trifluoro-2-chloropropene, 2,3,3,3-tetrafluoropropene and optionally one or more compounds chosen from E-3,3,3-trifluoro-1-chloropropene, trifluoropropyne, 1,1,1,3,3-pentafluoropropane, 1,1,1,3,3-pentafluoropropene, 1,1,1,2,2-pentafluoropropane, 2-chloro, 1,1,1,2-tetrafluoropropane and 1,1,1,2,3-pentafluoropropene.
According to another embodiment, the composition according to the invention comprises hydrogen fluoride, 3,3,3-trifluoro-2-chloropropene, E-3,3,3-trifluoro-1-chloropropene and optionally one or more compounds chosen from trifluoropropyne, 1,1,1,3,3-pentafluoropropane, 1,1,1,3,3-pentafluoropropene, 1,1,1,2,2-pentafluoropropane, 2-chloro-1,1,1,2-tetrafluoropropane and 1,1,1,2,3-pentafluoropropene.
According to one embodiment, the composition according to the invention comprises hydrogen fluoride, 3,3,3-trifluoro-2-chloropropene, trifluoropropyne and optionally one or more compounds chosen from 1,1,1,3,3-pentafluoropropane, 1,1,1,3,3-pentafluoropropene, 1,1,1,2,2-pentafluoropropane, 2-chloro,1,1,1,2-tetrafluoropropane and 1,1,1,2,3-pentafluoropropene.
According to another embodiment, the composition according to the invention comprises hydrogen fluoride, 3,3,3-trifluoro-2-chloropropene, 1,1,1,3,3-pentafluoropropane and optionally one or more compounds chosen from 1,1,1,3,3-pentafluoropropene, 1,1,1,2,2-pentafluoropropane, 2-chloro,1,1,1,2-tetrafluoropropane and 1,1,1,2,3-pentafluoropropene.
According to one embodiment, the composition according to the invention comprises hydrogen fluoride, 3,3,3-trifluoro-2-chloropropene, 1,1,1,3,3-pentafluoropropene and optionally one or more compounds chosen from 1,1,1,2,2-pentafluoropropane, 2-chloro,1,1,1,2-tetrafluoropropane and 1,1,1,2,3-pentafluoropropene.
According to one embodiment, the composition according to the invention comprises hydrogen fluoride, 3,3,3-trifluoro-2-chloropropene, 1,1,1,2,2-pentafluoropropane and optionally one or more compounds chosen from 2-chloro-1,1,1,2-tetrafluoropropane and 1,1,1,2,3-pentafluoropropene.
According to another embodiment according to the invention, the composition comprises hydrogen fluoride, 3,3,3-trifluoro-2-chloropropene, 2-chloro-1,1,1,2-tetrafluoropropane and optionally 1,1,1,2,3-pentafluoropropene.
According to one embodiment, the composition according to the invention comprises hydrogen fluoride, 3,3,3-trifluoro-2-chloropropene and 1,1,1,2,3-pentafluoropropene.
According to one embodiment, the composition according to the invention comprises hydrogen fluoride, 3,3,3-trifluoro-2-chloropropene, E-3,3,3-trifluoro-1-chloropropene and optionally one or more organic compounds chosen from E-1,3,3,3-tetrafluoropropene, Z-1,3,3,3-tetrafluoropropene, 3,3,3-trifluoropropene, 1,1,1,2,2-pentafluoropropane, 2,3,3,3-tetrafluoropropene, trifluoropropyne, 1,1,1,3,3-pentafluoropropene, 2-chloro-1,1,1,2-tetrafluoropropane, 1,1,1,3,3-pentafluoropropane and 1,1,1,2,3-pentafluoropropene.
According to one embodiment, the composition according to the invention comprises hydrogen fluoride, 3,3,3-trifluoro-2-chloropropene, E-1,3,3,3-tetrafluoropropene and optionally one or more compounds chosen from Z-1,3,3,3-tetrafluoropropene, 3,3,3-trifluoropropene, 1,1,1,2,2-pentafluoropropane, 2,3,3,3-tetrafluoropropene, trifluoropropyne, 1,1,1,3,3-pentafluoropropene, 2-chloro-1,1,1,2-tetrafluoropropane, 1,1,1,3,3-pentafluoropropane and 1,1,1,2,3-pentafluoropropene.
According to another embodiment, the composition according to the invention comprises hydrogen fluoride, 3,3,3-trifluoro-2-chloropropene, Z-1,3,3,3-tetrafluoropropene and optionally one or more organic compounds chosen from 3,3,3-trifluoropropene, 1,1,1,2,2-pentafluoropropane, 2,3,3,3-tetrafluoropropene, trifluoropropyne, 1,1,1,3,3-pentafluoropropene, 2-chloro-1,1,1,2-tetrafluoropropane, 1,1,1,3,3-pentafluoropropane and 1,1,1,2,3-pentafluoropropene.
According to one embodiment according to the invention, the composition comprises hydrogen fluoride, 3,3,3-trifluoro-2-chloropropene, 3,3,3-trifluoropropene and optionally one or more organic compounds chosen from 1,1,1,2,2-pentafluoropropane, 2,3,3,3-tetrafluoropropene, trifluoropropyne, 1,1,1,3,3-pentafluoropropene, 2-chloro-1,1,1,2-tetrafluoropropane, 1,1,1,3,3-pentafluoropropane and 1,1,1,2,3-pentafluoropropene.
According to another embodiment, the composition according to the invention comprises hydrogen fluoride, 3,3,3-trifluoro-2-chloropropene, 1,1,1,2,2-pentafluoropropane and one or more organic compounds chosen from 2,3,3,3-tetrafluoropropene, trifluoropropyne, 1,1,1,3,3-pentafluoropropene, 2-chloro-1,1,1,2-tetrafluoropropane, 1,1,1,3,3-pentafluoropropane and 1,1,1,2,3-pentafluoropropene.
According to one embodiment, the composition according to the invention comprises hydrogen fluoride, 3,3,3-trifluoro-2-chloropropene, 2,3,3,3-tetrafluoropropene and one or more organic compounds chosen from trifluoropropyne, 1,1,1,3,3-pentafluoropropene, 2-chloro-1,1,1,2-tetrafluoropropane, 1,1,1,3,3-pentafluoropropane and 1,1,1,2,3-pentafluoropropene.
Irrespective of the embodiment, the composition preferably comprises from 1% to 85% and advantageously from 5% to 80% by weight of hydrogen fluoride and from 99% to 15% and advantageously from 20% to 95% by weight of the sum of the organic compounds; more particularly, the composition comprises from 1% to 85% by weight of hydrogen fluoride and from 99% to 15% by weight of the sum of the organic compounds (HCFO-1233xf and the (hydro)halocarbon compounds).
Irrespective of the embodiment, the boiling point of the composition according to the invention is between −20° C. and 80° C. and at a pressure between 0.1 and 44 bar absolute, preferentially between 0° C. and 40° C. and preferentially at a pressure of between 0.7 and 18 bar absolute, advantageously between 0.9 and 12.5 bar absolute.
The Applicant has discovered that the compositions according to the invention have advantageous properties in particular for the recycling of HF in the reaction step. Thus, the condensed phase of these compositions, optionally when they are subjected to a distillation step and/or a liquid/liquid separation step, such as by decantation, form two immiscible liquid phases.
By way of example, for the ternary compounds containing hydrogen fluoride, 3,3,3-trifluoro-2-chloropropene and a compound chosen from 2,3,3,3-tetrafluoropropene, 3,3,3-trifluoropropene, 1,3,3,3-tetrafluoropropene, 1,1,1,2,2-pentafluoropropane and E-3,3,3-trifluoro-1-chloropropene, the appearance of a heteroazeotrope characterized by two liquid phases, one rich in HF and the other depleted in HF, depends on the amount of HF in the composition. These decantation ranges as a function of the HF content in the compositions were characterized for at least isotherms at 0° C., 25° C. and 40° C.
Similarly, the decantation ranges for the ternary compounds containing hydrogen fluoride, 3,3,3-trifluoro-2-chloropropene and a compound chosen from trifluoropropyne, 1,1,1,3,3-pentafluoropropene, 2-chloro-1,1,1,2-tetrafluoropropane, 1,1,1,3,3-pentafluoropentane and Z-1,1,1,2,3-pentafluoropropene are characterized by a phase depleted in HF and a phase enriched in HF for at least isotherms at 0° C., 25° C. and 40° C.
The Applicant has observed the same phenomenon for compositions of hydrogen fluoride, 3,3,3-trifluoro-2-chloropropene comprising several compounds chosen from 2,3,3,3-tetrafluoropropene, 3,3,3-trifluoropropene, E-3,3,3-trifluoro-1-chloropropene, trifluoropropyne, 1,1,1,3,3-pentafluoropropene, 2-chloro-1,1,1,2-tetrafluoropropane and 1,1,1,2,3-pentafluoropropene.
An azeotropic or quasi-azeotropic composition that is preferred according to the invention comprises from 1% to 80% by weight of hydrogen fluoride and from 99% to 20% by weight of the sum of HCFO-1233xf and of HCFO-1233zdE, the boiling point of this preferred composition is between 0 and 40° C. at a pressure of between 0.9 and 11.6 bar absolute.
An azeotropic or quasi-azeotropic composition that is preferred according to the invention preferably comprises from 5% to 75% by weight of hydrogen fluoride and from 95% to 25% by weight of the sum of HCFO-1233xf and of HCFO-1233zdE, the boiling point of this preferred composition is between 0 and 40° C. at a pressure of between 0.9 and 11.6 bar absolute.
An azeotropic or quasi-azeotropic composition that is preferred according to the invention preferably comprises from 1% to 80% by weight of hydrogen fluoride and from 99% to 20% by weight of the sum of HCFO-1233xf and of HFO-1243zf, the boiling point of this preferred composition is between 0 and 40° C. at a pressure of between 0.9 and 11.6 bar absolute.
An azeotropic or quasi-azeotropic composition that is preferred according to the invention preferably comprises from 5% to 75% by weight of hydrogen fluoride and from 95% to 25% by weight of the sum of HCFO-1233xf and of HFO-1243zf, the boiling point of this preferred composition is between 0 and 40° C. at a pressure of between 0.9 and 11.6 bar absolute.
An azeotropic or quasi-azeotropic composition that is preferred according to the invention comprises from 1% to 85% by weight of hydrogen fluoride and from 99% to 15% by weight of the sum of HCFO-1233xf, of HCFO-1233zdE and of HFC-245cb, the boiling point of this preferred composition is between 0 and 40° C. at a pressure of between 0.9 and 11.6 bar absolute.
An azeotropic or quasi-azeotropic composition that is preferred according to the invention preferably comprises from 5% to 80% by weight of hydrogen fluoride and from 95% to 20% by weight of the sum of HCFO-1233xf, of HCFO-1233zdE and of HFC-245cb, the boiling point of this preferred composition is between 0 and 40° C. at a pressure of between 0.9 and 11.6 bar absolute.
An azeotropic or quasi-azeotropic composition that is preferred according to the invention comprises from 1% to 85% by weight of hydrogen fluoride and from 99% to 15% by weight of the sum of HCFO-1233xf, of HFO-1243zf and of HFC-245cb, the boiling point of this preferred composition is between 0 and 40° C. at a pressure of between 0.9 and 11.6 bar absolute.
An azeotropic or quasi-azeotropic composition that is preferred according to the invention preferably comprises from 5% to 80% by weight of hydrogen fluoride and from 95% to 20% by weight of the sum of HCFO-1233xf, of HFO-1243zf and of HFC-245cb, the boiling point of this preferred composition is between 0 and 40° C. at a pressure of between 0.9 and 11.6 bar absolute.
An azeotropic or quasi-azeotropic composition that is preferred according to the invention comprises from 1% to 80% by weight of hydrogen fluoride and from 99% to 20% by weight of the sum of HCFO-1233xf, of HCFO-1233zdE and of HFO-1243zf, the boiling point of this preferred composition is between 0 and 40° C. at a pressure of between 0.9 and 11.6 bar absolute.
An azeotropic or quasi-azeotropic composition that is preferred according to the invention preferably comprises from 5% to 75% by weight of hydrogen fluoride and from 95% to 25% by weight of the sum of HCFO-1233xf, of HCFO-1233zdE and of HFO-1243zf, the boiling point of this preferred composition is between 0 and 40° C. at a pressure of between 0.9 and 11.6 bar absolute.
An azeotropic or quasi-azeotropic composition that is preferred according to the invention comprises from 1% to 85% by weight of hydrogen fluoride and from 99% to 15% by weight of the sum of HCFO-1233xf, of HFC-245cb and of HCFC-244bb, the boiling point of this preferred composition is between 0 and 40° C. at a pressure of between 0.9 and 11.6 bar absolute.
An azeotropic or quasi-azeotropic composition that is preferred according to the invention preferably comprises from 5% to 80% by weight of hydrogen fluoride and from 95% to 20% by weight of the sum of HCFO-1233xf, of HFC-245cb and of HCFC-244bb, the boiling point of this preferred composition is between 0 and 40° C. at a pressure of between 0.7 and 8.6 bar absolute.
An azeotropic or quasi-azeotropic composition that is preferred according to the invention comprises from 1% to 85% by weight of hydrogen fluoride and from 99% to 15% by weight of the sum of HCFO-1233xf, of HFC-245cb, of HFO-1243zf and of HFO-1233zdE, the boiling point of this preferred composition is between 0 and 40° C. at a pressure of between 0.9 and 11.6 bar absolute.
An azeotropic or quasi-azeotropic composition that is preferred according to the invention preferably comprises from 5% to 80% by weight of hydrogen fluoride and from 95% to 20% by weight of the sum of HCFO-1233xf, of HFC-245cb, of HCFO-1233zdE and of HFO-1243zf, the boiling point of this preferred composition is between 0 and 40° C. at a pressure of between 0.9 and 11.6 bar absolute.
An azeotropic or quasi-azeotropic composition that is preferred according to the invention comprises from 1% to 85% by weight of hydrogen fluoride and from 99% to 15% by weight of the sum of HCFO-1233xf, of HCFC-244bb, of HFC-245a, of trifluoropropyne, of HFO-1225yeZ and of HFO-1225zc, the boiling point of this preferred composition is between 0 and 40° C. at a pressure of between 0.7 and 18 bar absolute.
An azeotropic or quasi-azeotropic composition that is preferred according to the invention preferably comprises from 5% to 80% by weight of hydrogen fluoride and from 95% to 20% by weight of the sum of HCFO-1233xf, of HCFC-244bb, of HFC-245a, of trifluoropropyne, of HFO-1225yeZ and of HFO-1225zc, the boiling point of this preferred composition is between 0 and 40° C. at a pressure of between 0.7 and 18 bar absolute.
Examples 2, 5, 8, 11, 14, 17 and 20 represent the boiling points and pressure ranges of the mixtures and Examples 3, 6, 9, 12, 15, 18 and 21 represent the decantation ranges of the mixtures of Examples 1, 4, 7, 10, 13, 16 and 19 as a function of the mass percentage of HF characterized for isotherms at 0° C., 25° C. and 40° C. The decantation ranges of Examples 3, 6, 9, 12, 15, 18 and 21 are calculated for mixtures of organic compounds having equal-mass contents. By way of example, for a ternary mixture, a mixture containing 50% by weight of each of the two organic compounds is considered; for a penternary mixture, a mixture containing 25% by weight of each of the four organic compounds is considered, the mass fraction of HF ranging from 0 to 1. These calculations are performed at the liquid-vapor equilibrium, under azeotropic conditions.


Example 1: Ternary Mixtures, Isotherm at 25° C.












HF - HCFO-1233xf - HFO-1234zeE









Organics
Organics
Organics


0.95 F1234zeE +
0.5 F1234zeE +
0.05 F1234zeE +


0.05 F1233xf
0.5 F1233xf
0.95 F1233xf













TOTAL

TOTAL

TOTAL



PRES-

PRES-

PRES-


MASSFRAC
SURE
MASSFRAC
SURE
MASSFRAC
SURE


HF
bar
HF
bar
HF
bar





0
4.7
0
3.3
0
1.7


0.05
5.7
0.05
4.3
0.05
2.8


0.1
5.7
0.1
4.3
0.1
2.8


0.15
5.7
0.15
4.3
0.15
2.8


0.2
5.7
0.2
4.3
0.2
2.8


0.25
5.7
0.25
4.3
0.25
2.8


0.3
5.7
0.3
4.3
0.3
2.8


0.35
5.7
0.35
4.3
0.35
2.8


0.4
5.7
0.4
4.3
0.4
2.8


0.45
5.7
0.45
4.3
0.45
2.8


0.5
5.6
0.5
4.3
0.5
2.8


0.55
5.6
0.55
4.2
0.55
2.8


0.6
5.5
0.6
4.2
0.6
2.8


0.65
5.4
0.65
4.2
0.65
2.8


0.7
5.2
0.7
4.1
0.7
2.8


0.75
5.0
0.75
3.9
0.75
2.8


0.8
4.7
0.8
3.7
0.8
2.6


0.85
4.2
0.85
3.3
0.85
2.4


0.9
3.5
0.9
2.8
0.9
2.2


0.95
2.5
0.95
2.1
0.95
1.7


1
1.2
1
1.2
1
1.2










HF - HCFO-1233xf - HFO-1234zeZ









Organics
Organics
Organics


0.95 F1234zeZ +
0.5 F1234zeZ +
0.05 F1234zeZ +


0.05 F1233xf
0.5 F1233xf
0.95 F1233xf













TOTAL

TOTAL

TOTAL



PRES-

PRES-

PRES-


MASSFRAC
SURE
MASSFRAC
SURE
MASSFRAC
SURE


HF
bar
HF
bar
HF
bar





0
1.8
0
1.7
0
1.6


0.05
2.9
0.05
2.8
0.05
2.7


0.1
2.9
0.1
2.8
0.1
2.7


0.15
2.9
0.15
2.8
0.15
2.7


0.2
2.9
0.2
2.8
0.2
2.7


0.25
2.9
0.25
2.8
0.25
2.7


0.3
2.9
0.3
2.8
0.3
2.7


0.35
2.9
0.35
2.8
0.35
2.7


0.4
2.9
0.4
2.8
0.4
2.7


0.45
2.9
0.45
2.8
0.45
2.7


0.5
2.9
0.5
2.8
0.5
2.7


0.55
2.9
0.55
2.8
0.55
2.7


0.6
2.9
0.6
2.8
0.6
2.7


0.65
2.9
0.65
2.8
0.65
2.7


0.7
2.9
0.7
2.8
0.7
2.7


0.75
2.9
0.75
2.8
0.75
2.7


0.8
2.8
0.8
2.7
0.8
2.5


0.85
2.6
0.85
2.5
0.85
2.4


0.9
2.3
0.9
2.2
0.9
2.1


0.95
1.8
0.95
1.8
0.95
1.7


1
1.2
1
1.2
1
1.2










HF - HCFO-1233xf - HCFO-1233zdE









Organics
Organics
Organics


0.95 F1233zdE +
0.5 F1233zdE +
0.05 F1233zdE +


0.05 F1233xf
0.5 F1233xf
0.95 F1233xf













TOTAL

TOTAL

TOTAL



PRES-

PRES-

PRES-


MASSFRAC
SURE
MASSFRAC
SURE
MASSFRAC
SURE


HF
bar
HF
bar
HF
bar





0
1.3
0
1.4
0
1.5


0.05
2.4
0.05
2.5
0.05
2.6


0.1
2.4
0.1
2.5
0.1
2.6


0.15
2.4
0.15
2.5
0.15
2.6


0.2
2.4
0.2
2.5
0.2
2.6


0.25
2.4
0.25
2.5
0.25
2.6


0.3
2.4
0.3
2.5
0.3
2.6


0.35
2.4
0.35
2.5
0.35
2.6


0.4
2.4
0.4
2.5
0.4
2.6


0.45
2.4
0.45
2.5
0.45
2.6


0.5
2.4
0.5
2.5
0.5
2.6


0.55
2.4
0.55
2.5
0.55
2.6


0.6
2.4
0.6
2.5
0.6
2.6


0.65
2.4
0.65
2.5
0.65
2.6


0.7
2.4
0.7
2.5
0.7
2.6


0.75
2.4
0.75
2.5
0.75
2.6


0.8
2.3
0.8
2.4
0.8
2.5


0.85
2.2
0.85
2.3
0.85
2.3


0.9
1.9
0.9
2.0
0.9
2.1


0.95
1.6
0.95
1.7
0.95
1.7


1
1.2
1
1.2
1
1.2










HF - HCFO-1233xf - HFO-1243zf









Organics
Organics
Organics


0.95 F1243zf +
0.5 F1243zf +
0.05 F1243zf +


0.05F1233xf
0.5 F1233xf
0.95 F1233xf













TOTAL

TOTAL

TOTAL


MASSFRAC
PRES
MASSFRAC
PRES
MASSFRAC
PRES


HF
bar
HF
bar
HF
bar





0
5.7
0
4.0
0
1.8


0.05
6.6
0.05
5.0
0.05
2.9


0.1
6.7
0.1
5.0
0.1
2.9


0.15
6.6
0.15
5.0
0.15
2.9


0.2
6.6
0.2
5.0
0.2
2.9


0.25
6.6
0.25
5.0
0.25
2.9


0.3
6.6
0.3
5.0
0.3
2.9


0.35
6.6
0.35
5.0
0.35
2.9


0.4
6.6
0.4
5.0
0.4
2.9


0.45
6.6
0.45
5.0
0.45
2.9


0.5
6.6
0.5
5.0
0.5
2.9


0.55
6.6
0.55
5.0
0.55
2.9


0.6
6.6
0.6
5.0
0.6
2.9


0.65
6.5
0.65
4.9
0.65
2.9


0.7
6.4
0.7
4.9
0.7
2.9


0.75
6.3
0.75
4.7
0.75
2.9


0.8
6.0
0.8
4.5
0.8
2.7


0.85
5.5
0.85
4.1
0.85
2.5


0.9
4.7
0.9
3.5
0.9
2.2


0.95
3.3
0.95
2.6
0.95
1.8


1
1.2
1
1.2
1
1.2










HF - HFO-1234yf - HCFO-1233xf









Organics
Organics
Organics


0.95 F1233xf +
0.5 F1233xf +
0.05 F1233xf +


0.05 F1234yf
0.5 F1234yf
0.95 F1234yf













TOTAL

TOTAL

TOTAL



PRES-

PRES-

PRES-


MASSFRAC
SURE
MASSFRAC
SURE
MASSFRAC
SURE


HF
bar
HF
bar
HF
bar





0
1.9
0
4.3
0
6.6


0.05
3.0
0.05
5.4
0.05
7.5


0.1
3.0
0.1
5.4
0.1
7.5


0.15
3.0
0.15
5.4
0.15
7.5


0.2
3.0
0.2
5.4
0.2
7.5


0.25
3.0
0.25
5.4
0.25
7.5


0.3
3.0
0.3
5.4
0.3
7.5


0.35
3.0
0.35
5.4
0.35
7.5


0.4
3.0
0.4
5.4
0.4
7.5


0.45
3.0
0.45
5.4
0.45
7.5


0.5
3.0
0.5
5.4
0.5
7.5


0.55
3.0
0.55
5.4
0.55
7.5


0.6
3.0
0.6
5.4
0.6
7.5


0.65
2.9
0.65
5.4
0.65
7.5


0.7
2.9
0.7
5.4
0.7
7.5


0.75
2.9
0.75
5.3
0.75
7.4


0.8
2.8
0.8
5.0
0.8
7.0


0.85
2.6
0.85
4.6
0.85
6.5


0.9
2.3
0.9
3.9
0.9
5.4


0.95
1.8
0.95
2.8
0.95
3.8


1
1.2
1
1.2
1
1.2









Example 2: Temperature and Pressure Range of Ternary Mixtures













Boiling point range










Temperature
Pressure


Ternary
° C.
bar abs





HF-HFO-1234yf-HCFO-1233xf
0 to 40
 ~1.1 to ~11.4


HF-HCFO-1233xf-HFO-1234zeE
0 to 40
~1.1 to ~8.8


HF-HCFO-1233xf-HFO-1234zeZ
0 to 40
~1.0 to ~4.8


HF-HCFO-1233xf-HCFO-1233zdE
0 to 40
~0.9 to ~4.0


HF-HCFO-1233xf-HFO-1243zf
0 to 40
 ~1.1 to ~10.2









Example 3: Decantation Range of Ternary Mixtures













Decantation ranges



Mass percentage of HF











Isotherm
Isotherm
Isotherm


Ternary
0° C.
25° C.
40° C.





HF-HFO-1234yf-HCFO-1233xf
5-75
5-75
15-50


HF-HCFO-1233xf-HFO-
5-70
5-60
10-45


1234zeE


HF-HCFO-1233xf-HFO-
5-80
5-70
 5-65


1234zeZ


HF-HCFO-1233xf-HCFO-
5-80
5-75
 5-65


1233zdE


HF-HCFO-1233xf-HFO-1243zf
5-75
10-65 
20-40









Example 4: Quaternary Mixtures, Isotherm at 25° C.












HF - HCFO-1233xf - HCFO-1233zdE - HFC-245cb










Organics
Organics
Organics
Organics


0.9 F1233xf +
0.4 F1233xf +
0.05 F1233xf +
0.05 F1233xf +


0.05 F1233zdE +
0.3 F1233zdE +
0.9 F1233zdE +
0.05 F1233zdE +


0.05 F245cb
0.3 F245cb
0.05 F245cb
0.9 F245cb















TOTAL

TOTAL

TOTAL

TOTAL


MASSFRAC
PRESSURE
MASSFRAC
PRESSURE
MASSFRAC
PRESSURE
MASSFRAC
PRESSURE


HF
bar
HF
bar
HF
bar
HF
bar





0
1.7
0
2.4
0
1.5
0
4.3


0.05
2.8
0.05
3.6
0.05
2.6
0.05
5.5


0.1
2.8
0.1
3.6
0.1
2.6
0.1
5.5


0.15
2.8
0.15
3.6
0.15
2.6
0.15
5.5


0.2
2.8
0.2
3.6
0.2
2.6
0.2
5.5


0.25
2.8
0.25
3.6
0.25
2.6
0.25
5.5


0.3
2.8
0.3
3.6
0.3
2.6
0.3
5.5


0.35
2.8
0.35
3.6
0.35
2.6
0.35
5.5


0.4
2.8
0.4
3.6
0.4
2.6
0.4
5.5


0.45
2.8
0.45
3.6
0.45
2.6
0.45
5.5


0.5
2.8
0.5
3.6
0.5
2.6
0.5
5.5


0.55
2.8
0.55
3.6
0.55
2.6
0.55
5.5


0.6
2.8
0.6
3.7
0.6
2.6
0.6
5.5


0.65
2.8
0.65
3.7
0.65
2.6
0.65
5.5


0.7
2.8
0.7
3.7
0.7
2.6
0.7
5.6


0.75
2.8
0.75
3.7
0.75
2.6
0.75
5.6


0.8
2.7
0.8
3.7
0.8
2.5
0.8
5.6


0.85
2.5
0.85
3.4
0.85
2.4
0.85
5.5


0.9
2.2
0.9
2.9
0.9
2.1
0.9
4.8


0.95
1.8
0.95
2.2
0.95
1.7
0.95
3.4


1
1.2
1
1.2
1
1.2
1
1.2










HF - HCFO-1233xf - HFO-1234zeE - HFC-245cb










Organics
Organics
Organics
Organics


0.9 F1233xf +
0.4 F1233xf +
0.05 F1233xf +
0.05 F1233xf +


0.05 F1234zeE +
0.3 F1234zeE +
0.9 F1234zeE +
0.05 F1234zeE +


0.05 F245cb
0.3 F245cb
0.05 F245cb
0.9 F245cb















TOTAL

TOTAL

TOTAL

TOTAL


MASSFRAC
PRES
MASSFRAC
PRES
MASSFRAC
PRES
MASSFRAC
PRES


HF
bar
HF
bar
HF
bar
HF
bar





0
3.2
0
3.5
0
4.7
0
4.5


0.05
4.3
0.05
4.6
0.05
5.7
0.05
5.7


0.1
4.3
0.1
4.6
0.1
5.7
0.1
5.7


0.15
4.3
0.15
4.6
0.15
5.7
0.15
5.7


0.2
4.3
0.2
4.6
0.2
5.7
0.2
5.7


0.25
4.3
0.25
4.6
0.25
5.7
0.25
5.7


0.3
4.3
0.3
4.6
0.3
5.7
0.3
5.7


0.35
4.3
0.35
4.6
0.35
5.7
0.35
5.7


0.4
4.4
0.4
4.6
0.4
5.7
0.4
5.7


0.45
4.4
0.45
4.6
0.45
5.7
0.45
5.7


0.5
4.4
0.5
4.6
0.5
5.7
0.5
5.7


0.55
4.4
0.55
4.6
0.55
5.6
0.55
5.7


0.6
4.4
0.6
4.6
0.6
5.6
0.6
5.7


0.65
4.4
0.65
4.7
0.65
5.5
0.65
5.7


0.7
4.5
0.7
4.7
0.7
5.3
0.7
5.7


0.75
4.5
0.75
4.6
0.75
5.1
0.75
5.7


0.8
4.5
0.8
4.4
0.8
4.8
0.8
5.7


0.85
4.2
0.85
4.0
0.85
4.3
0.85
5.6


0.9
3.6
0.9
3.4
0.9
3.6
0.9
4.8


0.95
2.6
0.95
2.5
0.95
2.6
0.95
3.4


1
1.2
1
1.2
1
1.2
1
1.2










HF - HCFO-1233xf - HFO-1234zeZ - HFC-245cb










Organics
Organics
Organics
Organics


0.9 F1233xf +
0.4 F1233xf +
0.05 F1233xf +
0.05 F1233xf +


0.05 F1234zeZ +
0.3 F1234zeZ +
0.9 F1234zeZ +
0.05 F1234zeZ +


0.05 F245cb
0.3 F245cb
0.05 F245cb
0.9 F245cb















TOTAL

TOTAL

TOTAL

TOTAL


MASSFRAC
PRESSURE
MASSFRAC
PRESSURE
MASSFRAC
PRESSURE
MASSFRAC
PRESSURE


HF
bar
HF
bar
HF
bar
HF
bar





0
1.7
0
2.6
0
1.9
0
4.3


0.05
2.8
0.05
3.7
0.05
3.0
0.05
5.5


0.1
2.8
0.1
3.7
0.1
3.0
0.1
5.5


0.15
2.8
0.15
3.7
0.15
3.0
0.15
5.5


0.2
2.8
0.2
3.7
0.2
3.0
0.2
5.5


0.25
2.8
0.25
3.7
0.25
3.0
0.25
5.5


0.3
2.8
0.3
3.7
0.3
3.0
0.3
5.5


0.35
2.8
0.35
3.7
0.35
3.0
0.35
5.5


0.4
2.8
0.4
3.7
0.4
3.0
0.4
5.5


0.45
2.8
0.45
3.7
0.45
3.1
0.45
5.5


0.5
2.8
0.5
3.7
0.5
3.1
0.5
5.5


0.55
2.9
0.55
3.7
0.55
3.1
0.55
5.5


0.6
2.9
0.6
3.8
0.6
3.1
0.6
5.5


0.65
2.9
0.65
3.8
0.65
3.1
0.65
5.6


0.7
2.9
0.7
3.8
0.7
3.1
0.7
5.6


0.75
2.9
0.75
3.8
0.75
3.1
0.75
5.6


0.8
2.7
0.8
3.8
0.8
2.9
0.8
5.6


0.85
2.5
0.85
3.5
0.85
2.7
0.85
5.5


0.9
2.2
0.9
3.0
0.9
2.4
0.9
4.8


0.95
1.8
0.95
2.3
0.95
1.9
0.95
3.4


1
1.2
1
1.2
1
1.2
1
1.2










HF - HCFO-1233xf - HFO-1243zf - HFC-245cb










Organics
Organics
Organics
Organics


0.9 F1233xf +
0.4 F1233xf +
0.05 F1233xf +
0.05 F1233xf +


0.05 F1243zf +
0.3 F1243zf +
0.9 F1243zf +
0.05 F1243zf +


0.05 F245cb
0.3 F245cb
0.05 F245cb
0.9 F245cb















TOTAL

TOTAL

TOTAL

TOTAL


MASSFRAC
PRESSURE
MASSFRAC
PRESSURE
MASSFRAC
PRESSURE
MASSFRAC
PRESSURE


HF
bar
HF
bar
HF
bar
HF
bar





0
2.0
0
4.0
0
5.6
0
4.6


0.05
3.1
0.05
5.1
0.05
6.6
0.05
5.7


0.1
3.1
0.1
5.1
0.1
6.6
0.1
5.7


0.15
3.1
0.15
5.1
0.15
6.6
0.15
5.7


0.2
3.1
0.2
5.1
0.2
6.6
0.2
5.7


0.25
3.1
0.25
5.1
0.25
6.6
0.25
5.7


0.3
3.1
0.3
5.1
0.3
6.6
0.3
5.7


0.35
3.1
0.35
5.1
0.35
6.6
0.35
5.7


0.4
3.1
0.4
5.1
0.4
6.6
0.4
5.8


0.45
3.1
0.45
5.1
0.45
6.6
0.45
5.8


0.5
3.1
0.5
5.1
0.5
6.6
0.5
5.8


0.55
3.1
0.55
5.1
0.55
6.6
0.55
5.8


0.6
3.1
0.6
5.1
0.6
6.5
0.6
5.8


0.65
3.1
0.65
5.1
0.65
6.5
0.65
5.8


0.7
3.1
0.7
5.1
0.7
6.4
0.7
5.8


0.75
3.1
0.75
5.1
0.75
6.3
0.75
5.8


0.8
2.9
0.8
4.8
0.8
6.0
0.8
5.8


0.85
2.7
0.85
4.5
0.85
5.5
0.85
5.7


0.9
2.4
0.9
3.8
0.9
4.7
0.9
4.9


0.95
1.9
0.95
2.8
0.95
3.3
0.95
3.5


1
1.2
1
1.2
1
1.2
1
1.2










HF - HCFO-1233xf - HCFO-1233zdE - HFO-1234zeE










Organics
Organics
Organics
Organics


0.9 F1233xf +
0.05 F1233xf +
0.05 F1233xf +
0.4 F1233xf +


0.05 F1233zdE +
0.9 F1233zdE +
0.05 F1233zdE +
0.3 F1233zdE +


0.05 F1234zeE
0.05 F1234zeE
0.9 F1234zeE
0.3 F1234zeE















TOTAL

TOTAL

TOTAL

TOTAL


MASSFRAC
PRESSURE
MASSFRAC
PRESSURE
MASSFRAC
PRESSURE
MASSFRAC
PRESSURE


HF
bar
HF
bar
HF
bar
HF
bar





0
1.7
0
1.5
0
4.6
0
2.5


0.05
2.8
0.05
2.6
0.05
5.5
0.05
3.6


0.1
2.8
0.1
2.6
0.1
5.5
0.1
3.6


0.15
2.8
0.15
2.6
0.15
5.5
0.15
3.6


0.2
2.8
0.2
2.6
0.2
5.5
0.2
3.6


0.25
2.8
0.25
2.6
0.25
5.5
0.25
3.6


0.3
2.8
0.3
2.6
0.3
5.5
0.3
3.6


0.35
2.8
0.35
2.6
0.35
5.5
0.35
3.6


0.4
2.8
0.4
2.6
0.4
5.5
0.4
3.6


0.45
2.8
0.45
2.6
0.45
5.5
0.45
3.6


0.5
2.8
0.5
2.6
0.5
5.5
0.5
3.6


0.55
2.8
0.55
2.6
0.55
5.4
0.55
3.5


0.6
2.8
0.6
2.6
0.6
5.4
0.6
3.5


0.65
2.8
0.65
2.6
0.65
5.3
0.65
3.5


0.7
2.8
0.7
2.6
0.7
5.1
0.7
3.5


0.75
2.8
0.75
2.6
0.75
4.9
0.75
3.3


0.8
2.6
0.8
2.5
0.8
4.6
0.8
3.2


0.85
2.4
0.85
2.3
0.85
4.1
0.85
2.9


0.9
2.2
0.9
2.0
0.9
3.4
0.9
2.5


0.95
1.7
0.95
1.7
0.95
2.5
0.95
1.9


1
1.2
1
1.2
1
1.2
1
1.2










HF - HCFO-1233xf - HCFO-1233zdE - HFO-1234zeZ










Organics
Organics
Organics
Organics


0.9 F1233xf +
0.05 F1233xf +
0.05 F1233xf +
0.4 F1233xf +


0.05 F1233zdE +
0.9 F1233zdE +
0.05 F1233zdE +
0.3 F1233zdE +


0.05 F1234zeZ
0.05 F1234zeZ
0.9 F1234zeZ
0.3 F1234zeZ















TOTAL

TOTAL

TOTAL

TOTAL


MASSFRAC
PRESSURE
MASSFRAC
PRESSURE
MASSFRAC
PRESSURE
MASSFRAC
PRESSURE


HF
bar
HF
bar
HF
bar
HF
bar





0
1.5
0
1.4
0
1.8
0
1.6


0.05
2.7
0.05
2.5
0.05
2.9
0.05
2.7


0.1
2.7
0.1
2.5
0.1
2.9
0.1
2.7


0.15
2.7
0.15
2.5
0.15
2.9
0.15
2.7


0.2
2.7
0.2
2.5
0.2
2.9
0.2
2.7


0.25
2.7
0.25
2.5
0.25
2.9
0.25
2.7


0.3
2.7
0.3
2.5
0.3
2.9
0.3
2.7


0.35
2.7
0.35
2.5
0.35
2.9
0.35
2.7


0.4
2.7
0.4
2.5
0.4
2.9
0.4
2.7


0.45
2.7
0.45
2.5
0.45
2.9
0.45
2.7


0.5
2.7
0.5
2.5
0.5
2.9
0.5
2.7


0.55
2.7
0.55
2.5
0.55
2.9
0.55
2.7


0.6
2.7
0.6
2.5
0.6
2.9
0.6
2.7


0.65
2.7
0.65
2.5
0.65
2.9
0.65
2.7


0.7
2.7
0.7
2.5
0.7
2.9
0.7
2.7


0.75
2.7
0.75
2.5
0.75
2.9
0.75
2.7


0.8
2.5
0.8
2.4
0.8
2.8
0.8
2.6


0.85
2.4
0.85
2.2
0.85
2.6
0.85
2.4


0.9
2.1
0.9
2.0
0.9
2.3
0.9
2.1


0.95
1.7
0.95
1.6
0.95
1.8
0.95
1.7


1
1.2
1
1.2
1
1.2
1
1.2










HF - HCFO-1233xf - HCFO-1233zdE - HFO-1243zf










Organics
Organics
Organics
Organics


0.9 F1233xf +
0.05 F1233xf +
0.05 F1233xf +
0.4 F1233xf +


0.05 F1233zdE +
0.9 F1233zdE +
0.05 F1233zdE +
0.3 F1233zdE +


0.05 F1243zf
0.05 F1243zf
0.9 F1243zf
0.3 F1243zf















TOTAL

TOTAL

TOTAL

TOTAL


MASSFRAC
PRESSURE
MASSFRAC
PRESSURE
MASSFRAC
PRESSURE
MASSFRAC
PRESSURE


HF
bar
HF
bar
HF
bar
HF
bar





0
1.8
0
1.6
0
5.5
0
3.0


0.05
2.9
0.05
2.7
0.05
6.4
0.05
4.1


0.1
2.9
0.1
2.7
0.1
6.5
0.1
4.1


0.15
2.9
0.15
2.7
0.15
6.5
0.15
4.1


0.2
2.9
0.2
2.7
0.2
6.5
0.2
4.1


0.25
2.9
0.25
2.7
0.25
6.5
0.25
4.1


0.3
2.9
0.3
2.7
0.3
6.5
0.3
4.1


0.35
2.9
0.35
2.7
0.35
6.5
0.35
4.1


0.4
2.9
0.4
2.7
0.4
6.5
0.4
4.1


0.45
2.9
0.45
2.7
0.45
6.5
0.45
4.1


0.5
2.9
0.5
2.7
0.5
6.4
0.5
4.1


0.55
2.9
0.55
2.7
0.55
6.4
0.55
4.1


0.6
2.9
0.6
2.7
0.6
6.4
0.6
4.0


0.65
2.9
0.65
2.7
0.65
6.4
0.65
4.0


0.7
2.9
0.7
2.7
0.7
6.3
0.7
4.0


0.75
2.9
0.75
2.7
0.75
6.1
0.75
3.9


0.8
2.7
0.8
2.6
0.8
5.8
0.8
3.7


0.85
2.5
0.85
2.4
0.85
5.3
0.85
3.4


0.9
2.2
0.9
2.1
0.9
4.5
0.9
2.9


0.95
1.8
0.95
1.7
0.95
3.2
0.95
2.2


1
1.2
1
1.2
1
1.2
1
1.2










HF - HCFO-1233xf - HFO-1234zeE - HFO-1234zeZ










Organics
Organics
Organics
Organics


0.9 F1233xf +
0.05 F1233xf +
0.05 F1233xf +
0.4 F1233xf +


0.05 F1234zeE +
0.9 F1234zeE +
0.05 F1234zeE +
0.3 F1234zeE +


0.05 F1234zeZ
0.05 F1234zeZ
0.9 F1234zeZ
0.3 F1234zeZ















TOTAL

TOTAL

TOTAL

TOTAL


MASSFRAC
PRESSURE
MASSFRAC
PRESSURE
MASSFRAC
PRESSURE
MASSFRAC
PRESSURE


HF
bar
HF
bar
HF
bar
HF
bar





0
1.7
0
4.6
0
1.9
0
2.7


0.05
2.8
0.05
5.5
0.05
3.1
0.05
3.7


0.1
2.8
0.1
5.5
0.1
3.0
0.1
3.7


0.15
2.8
0.15
5.5
0.15
3.0
0.15
3.7


0.2
2.8
0.2
5.5
0.2
3.0
0.2
3.7


0.25
2.8
0.25
5.5
0.25
3.0
0.25
3.7


0.3
2.8
0.3
5.5
0.3
3.0
0.3
3.7


0.35
2.8
0.35
5.5
0.35
3.0
0.35
3.7


0.4
2.8
0.4
5.5
0.4
3.0
0.4
3.7


0.45
2.8
0.45
5.5
0.45
3.0
0.45
3.7


0.5
2.8
0.5
5.5
0.5
3.0
0.5
3.7


0.55
2.8
0.55
5.4
0.55
3.0
0.55
3.7


0.6
2.8
0.6
5.4
0.6
3.0
0.6
3.6


0.65
2.8
0.65
5.3
0.65
3.0
0.65
3.6


0.7
2.8
0.7
5.1
0.7
3.0
0.7
3.6


0.75
2.8
0.75
4.9
0.75
3.0
0.75
3.5


0.8
2.7
0.8
4.6
0.8
2.9
0.8
3.3


0.85
2.5
0.85
4.1
0.85
2.7
0.85
3.0


0.9
2.2
0.9
3.4
0.9
2.3
0.9
2.6


0.95
1.8
0.95
2.5
0.95
1.9
0.95
2.0


1
1.2
1
1.2
1
1.2
1
1.2










HF - HCFO-1233xf - HFO-1234zeE - HFO-1243zf










Organics
Organics
Organics
Organics


0.9 F1233xf +
0.05 F1233xf +
0.05 F1233xf +
0.4 F1233xf +


0.05 F1234zeE +
0.9 F1234zeE +
0.05 F1234zeE +
0.3 F1234zeE +


0.05 F1243zf
0.05 F1243zf
0.9 F1243zf
0.3 F1243zf















TOTAL

TOTAL

TOTAL

TOTAL


MASSFRAC
PRESSURE
MASSFRAC
PRESSURE
MASSFRAC
PRESSURE
MASSFRAC
PRESSURE


HF
bar
HF
bar
HF
bar
HF
bar





0
2.0
0
4.8
0
5.6
0
4.0


0.05
3.1
0.05
5.7
0.05
6.6
0.05
5.1


0.1
3.1
0.1
5.8
0.1
6.6
0.1
5.1


0.15
3.1
0.15
5.8
0.15
6.6
0.15
5.1


0.2
3.1
0.2
5.8
0.2
6.6
0.2
5.1


0.25
3.1
0.25
5.8
0.25
6.6
0.25
5.1


0.3
3.1
0.3
5.8
0.3
6.6
0.3
5.0


0.35
3.1
0.35
5.7
0.35
6.6
0.35
5.0


0.4
3.1
0.4
5.7
0.4
6.6
0.4
5.0


0.45
3.1
0.45
5.7
0.45
6.6
0.45
5.0


0.5
3.1
0.5
5.7
0.5
6.6
0.5
5.0


0.55
3.1
0.55
5.7
0.55
6.6
0.55
5.0


0.6
3.1
0.6
5.6
0.6
6.5
0.6
5.0


0.65
3.1
0.65
5.5
0.65
6.5
0.65
4.9


0.7
3.0
0.7
5.3
0.7
6.4
0.7
4.8


0.75
3.0
0.75
5.1
0.75
6.2
0.75
4.7


0.8
2.9
0.8
4.8
0.8
5.9
0.8
4.4


0.85
2.6
0.85
4.3
0.85
5.4
0.85
4.0


0.9
2.3
0.9
3.6
0.9
4.6
0.9
3.4


0.95
1.8
0.95
2.6
0.95
3.3
0.95
2.5


1
1.2
1
1.2
1
1.2
1
1.2










HF - HCFO-1233xf - HFO-1234zeZ - HFO-1243zf










Organics
Organics
Organics
Organics


0.9 F1233xf +
0.05 F1233xf +
0.05 F1233xf +
0.4 F1233xf +


0.05 F1234zeZ +
0.9 F1234zeZ +
0.05 F1234zeZ +
0.3 F1234zeZ +


0.05 F1243zf
0.05 F1243zf
0.9 F1243zf
0.3 F1243zf















TOTAL

TOTAL

TOTAL

TOTAL


MASSFRAC
PRESSURE
MASSFRAC
PRESSURE
MASSFRAC
PRESSURE
MASSFRAC
PRESSURE


HF
bar
HF
bar
HF
bar
HF
bar





0
1.8
0
2.0
0
5.5
0
3.1


0.05
2.9
0.05
3.1
0.05
6.4
0.05
4.2


0.1
2.9
0.1
3.1
0.1
6.5
0.1
4.2


0.15
2.9
0.15
3.1
0.15
6.5
0.15
4.2


0.2
2.9
0.2
3.1
0.2
6.5
0.2
4.2


0.25
2.9
0.25
3.1
0.25
6.5
0.25
4.2


0.3
2.9
0.3
3.1
0.3
6.5
0.3
4.2


0.35
2.9
0.35
3.1
0.35
6.5
0.35
4.2


0.4
2.9
0.4
3.1
0.4
6.5
0.4
4.2


0.45
2.9
0.45
3.1
0.45
6.5
0.45
4.2


0.5
2.9
0.5
3.1
0.5
6.4
0.5
4.2


0.55
2.9
0.55
3.1
0.55
6.4
0.55
4.2


0.6
2.9
0.6
3.1
0.6
6.4
0.6
4.1


0.65
2.9
0.65
3.1
0.65
6.4
0.65
4.1


0.7
2.9
0.7
3.1
0.7
6.3
0.7
4.1


0.75
2.9
0.75
3.1
0.75
6.1
0.75
4.0


0.8
2.8
0.8
3.0
0.8
5.8
0.8
3.8


0.85
2.5
0.85
2.7
0.85
5.3
0.85
3.5


0.9
2.2
0.9
2.4
0.9
4.5
0.9
3.0


0.95
1.8
0.95
1.9
0.95
3.2
0.95
2.3


1
1.2
1
1.2
1
1.2
1
1.2










HF - HCFO-1233xf - HFO-1234yf - HFC-245cb










Organics
Organics
Organics
Organics


0.9 F1233xf +
0.4 F1233xf +
0.05 F1233xf +
0.05 F1233xf +


0.05 F1234yf +
0.3 F1234yf +
0.9 F1234yf +
0.05 F1234yf +


0.05 F245cb
0.3 F245cb
0.05 F245cb
0.9 F245cb















TOTAL

TOTAL

TOTAL

TOTAL


MASSFRAC
PRESSURE
MASSFRAC
PRESSURE
MASSFRAC
PRESSURE
MASSFRAC
PRESSURE


HF
bar
HF
bar
HF
bar
HF
bar





0
2.0
0
4.2
0
6.5
0
4.6


0.05
3.1
0.05
5.3
0.05
7.4
0.05
5.8


0.1
3.1
0.1
5.3
0.1
7.4
0.1
5.8


0.15
3.1
0.15
5.3
0.15
7.4
0.15
5.8


0.2
3.1
0.2
5.3
0.2
7.4
0.2
5.8


0.25
3.1
0.25
5.3
0.25
7.4
0.25
5.8


0.3
3.1
0.3
5.3
0.3
7.4
0.3
5.8


0.35
3.1
0.35
5.3
0.35
7.4
0.35
5.8


0.4
3.1
0.4
5.3
0.4
7.4
0.4
5.8


0.45
3.1
0.45
5.3
0.45
7.4
0.45
5.8


0.5
3.1
0.5
5.3
0.5
7.4
0.5
5.8


0.55
3.1
0.55
5.3
0.55
7.4
0.55
5.8


0.6
3.1
0.6
5.3
0.6
7.4
0.6
5.8


0.65
3.1
0.65
5.3
0.65
7.4
0.65
5.8


0.7
3.1
0.7
5.3
0.7
7.4
0.7
5.8


0.75
3.1
0.75
5.4
0.75
7.3
0.75
5.8


0.8
3.0
0.8
5.2
0.8
7.0
0.8
5.8


0.85
2.8
0.85
4.8
0.85
6.4
0.85
5.7


0.9
2.4
0.9
4.1
0.9
5.4
0.9
4.9


0.95
1.9
0.95
2.9
0.95
3.7
0.95
3.5


1
1.2
1
1.2
1
1.2
1
1.2










HF - HCFO-1233xf - HFO-1234yf - HCFO-1233zdE










Organics
Organics
Organics
Organics


0.9 F1233xf +
0.05 F1233xf +
0.05 F1233xf +
0.4 F1233xf +


0.05 F1234yf +
0.9 F1234yf +
0.05 F1234yf +
0.3 F1234yf +


0.05 F1233zdE
0.05 F1233zdE
0.9 F1233zdE
0.3 F1233zdE















TOTAL

TOTAL

TOTAL

TOTAL


MASSFRAC
PRESSURE
MASSFRAC
PRESSURE
MASSFRAC
PRESSURE
MASSFRAC
PRESSURE


HF
bar
HF
bar
HF
bar
HF
bar





0
1.8
0
6.3
0
1.7
0
3.2


0.05
3.0
0.05
7.3
0.05
2.8
0.05
4.3


0.1
3.0
0.1
7.3
0.1
2.8
0.1
4.3


0.15
3.0
0.15
7.3
0.15
2.8
0.15
4.3


0.2
2.9
0.2
7.3
0.2
2.8
0.2
4.3


0.25
2.9
0.25
7.3
0.25
2.8
0.25
4.3


0.3
2.9
0.3
7.3
0.3
2.8
0.3
4.3


0.35
2.9
0.35
7.3
0.35
2.8
0.35
4.3


0.4
2.9
0.4
7.3
0.4
2.8
0.4
4.3


0.45
2.9
0.45
7.3
0.45
2.7
0.45
4.3


0.5
2.9
0.5
7.3
0.5
2.7
0.5
4.3


0.55
2.9
0.55
7.3
0.55
2.7
0.55
4.3


0.6
2.9
0.6
7.3
0.6
2.7
0.6
4.3


0.65
2.9
0.65
7.3
0.65
2.7
0.65
4.3


0.7
2.9
0.7
7.3
0.7
2.7
0.7
4.3


0.75
2.9
0.75
7.1
0.75
2.7
0.75
4.2


0.8
2.8
0.8
6.8
0.8
2.6
0.8
4.0


0.85
2.6
0.85
6.2
0.85
2.4
0.85
3.7


0.9
2.3
0.9
5.3
0.9
2.1
0.9
3.1


0.95
1.8
0.95
3.7
0.95
1.7
0.95
2.3


1
1.2
1
1.2
1
1.2
1
1.2










HF - HCFO-1233xf - HFO-1234yf - HFO-1234zeE










Organics
Organics
Organics
Organics


0.9 F1233xf +
0.05 F1233xf +
0.05 F1233xf +
0.4 F1233xf +


0.05 F1234yf +
0.9 F1234yf +
0.05 F1234yf +
0.3 F1234yf +


0.05 F1234zeE
0.05 F1234zeE
0.9 F1234zeE
0.3 F1234zeE















TOTAL

TOTAL

TOTAL

TOTAL


MASSFRAC
PRESSURE
MASSFRAC
PRESSURE
MASSFRAC
PRESSURE
MASSFRAC
PRESSURE


HF
bar
HF
bar
HF
bar
HF
bar





0
2.0
0
6.5
0
4.8
0
4.2


0.05
3.1
0.05
7.4
0.05
5.8
0.05
5.3


0.1
3.1
0.1
7.4
0.1
5.8
0.1
5.3


0.15
3.1
0.15
7.4
0.15
5.8
0.15
5.3


0.2
3.1
0.2
7.4
0.2
5.8
0.2
5.3


0.25
3.1
0.25
7.4
0.25
5.8
0.25
5.3


0.3
3.1
0.3
7.4
0.3
5.8
0.3
5.3


0.35
3.1
0.35
7.4
0.35
5.8
0.35
5.3


0.4
3.1
0.4
7.4
0.4
5.8
0.4
5.3


0.45
3.1
0.45
7.4
0.45
5.8
0.45
5.3


0.5
3.1
0.5
7.4
0.5
5.8
0.5
5.3


0.55
3.1
0.55
7.4
0.55
5.7
0.55
5.3


0.6
3.1
0.6
7.4
0.6
5.6
0.6
5.3


0.65
3.1
0.65
7.5
0.65
5.5
0.65
5.3


0.7
3.1
0.7
7.4
0.7
5.4
0.7
5.2


0.75
3.1
0.75
7.2
0.75
5.2
0.75
5.0


0.8
2.9
0.8
6.9
0.8
4.8
0.8
4.7


0.85
2.7
0.85
6.3
0.85
4.3
0.85
4.3


0.9
2.3
0.9
5.3
0.9
3.6
0.9
3.6


0.95
1.9
0.95
3.7
0.95
2.6
0.95
2.6


1
1.2
1
1.2
1
1.2
1
1.2










HF - HCFO-1233xf - HFO-1234yf - HFO-1234zeZ










Organics
Organics
Organics
Organics


0.9 F1233xf +
0.05 F1233xf +
0.05 F1233xf +
0.4 F1233xf +


0.05 F1234yf +
0.9 F1234yf +
0.05 F1234yf +
0.3 F1234yf +


0.05 F1234zeZ
0.05 F1234zeZ
0.9 F1234zeZ
0.3 F1234zeZ















TOTAL

TOTAL

TOTAL

TOTAL


MASSFRAC
PRESSURE
MASSFRAC
PRESSURE
MASSFRAC
PRESSURE
MASSFRAC
PRESSURE


HF
bar
HF
bar
HF
bar
HF
bar





0
1.9
0
6.3
0
2.1
0
3.3


0.05
3.0
0.05
7.3
0.05
3.2
0.05
4.4


0.1
3.0
0.1
7.3
0.1
3.2
0.1
4.4


0.15
3.0
0.15
7.3
0.15
3.2
0.15
4.4


0.2
3.0
0.2
7.3
0.2
3.2
0.2
4.4


0.25
3.0
0.25
7.3
0.25
3.2
0.25
4.4


0.3
3.0
0.3
7.3
0.3
3.2
0.3
4.4


0.35
3.0
0.35
7.3
0.35
3.2
0.35
4.4


0.4
3.0
0.4
7.3
0.4
3.2
0.4
4.4


0.45
3.0
0.45
7.3
0.45
3.2
0.45
4.4


0.5
3.0
0.5
7.3
0.5
3.2
0.5
4.4


0.55
3.0
0.55
7.3
0.55
3.2
0.55
4.4


0.6
3.0
0.6
7.3
0.6
3.2
0.6
4.4


0.65
3.0
0.65
7.3
0.65
3.2
0.65
4.4


0.7
3.0
0.7
7.3
0.7
3.2
0.7
4.4


0.75
2.9
0.75
7.1
0.75
3.1
0.75
4.3


0.8
2.8
0.8
6.8
0.8
3.0
0.8
4.1


0.85
2.6
0.85
6.3
0.85
2.8
0.85
3.7


0.9
2.3
0.9
5.3
0.9
2.4
0.9
3.2


0.95
1.8
0.95
3.7
0.95
1.9
0.95
2.4


1
1.2
1
1.2
1
1.2
1
1.2










HF - HCFO-1233xf - HFO-1234yf - HFO-1243zf










Organics
Organics
Organics
Organics


0.9 F1233xf +
0.05 F1233xf +
0.05 F1233xf +
0.4 F1233xf +


0.05 F1234yf +
0.9 F1234yf +
0.05 F1234yf +
0.3 F1234yf +


0.05 F1243zf
0.05 F1243zf
0.9 F1243zf
0.3 F1243zf















TOTAL

TOTAL

TOTAL

TOTAL


MASSFRAC
PRESSURE
MASSFRAC
PRESSURE
MASSFRAC
PRESSURE
MASSFRAC
PRESSURE


HF
bar
HF
bar
HF
bar
HF
bar





0
2.1
0
6.5
0
5.8
0
4.6


0.05
3.2
0.05
7.5
0.05
6.8
0.05
5.6


0.1
3.2
0.1
7.5
0.1
6.8
0.1
5.7


0.15
3.2
0.15
7.5
0.15
6.8
0.15
5.6


0.2
3.2
0.2
7.5
0.2
6.8
0.2
5.6


0.25
3.2
0.25
7.5
0.25
6.8
0.25
5.6


0.3
3.2
0.3
7.5
0.3
6.8
0.3
5.6


0.35
3.2
0.35
7.5
0.35
6.8
0.35
5.6


0.4
3.2
0.4
7.5
0.4
6.8
0.4
5.6


0.45
3.2
0.45
7.5
0.45
6.8
0.45
5.6


0.5
3.2
0.5
7.5
0.5
6.8
0.5
5.6


0.55
3.2
0.55
7.5
0.55
6.7
0.55
5.6


0.6
3.2
0.6
7.5
0.6
6.7
0.6
5.6


0.65
3.2
0.65
7.5
0.65
6.7
0.65
5.6


0.7
3.2
0.7
7.4
0.7
6.6
0.7
5.6


0.75
3.2
0.75
7.3
0.75
6.4
0.75
5.4


0.8
3.0
0.8
7.0
0.8
6.1
0.8
5.1


0.85
2.8
0.85
6.4
0.85
5.6
0.85
4.7


0.9
2.4
0.9
5.4
0.9
4.8
0.9
4.0


0.95
1.9
0.95
3.7
0.95
3.4
0.95
2.9


1
1.2
1
1.2
1
1.2
1
1.2










HF - HFO-1234yf - HCFO-1233xf - HCFC-244bb










Organics
Organics
Organics
Organics


0.9 F1233xf +
0.05 F1233xf +
0.05 F1233xf +
0.4 F1233xf +


0.05 F1234yf +
0.9 F1234yf +
0.05 F1234yf +
0.3 F1234yf +


0.05 F244bb
0.05 F244bb
0.9 F244bb
0.3 F244bb















TOTAL

TOTAL

TOTAL

TOTAL


MASSFRAC
PRESSURE
MASSFRAC
PRESSURE
MASSFRAC
PRESSURE
MASSFRAC
PRESSURE


HF
bar
HF
bar
HF
bar
HF
bar





0
1.8
0
6.3
0
1.1
0
3.1


0.05
2.9
0.05
7.3
0.05
2.2
0.05
4.2


0.1
2.9
0.1
7.3
0.1
2.2
0.1
4.2


0.15
2.9
0.15
7.3
0.15
2.2
0.15
4.2


0.2
2.9
0.2
7.3
0.2
2.2
0.2
4.2


0.25
2.9
0.25
7.3
0.25
2.2
0.25
4.2


0.3
2.9
0.3
7.3
0.3
2.2
0.3
4.2


0.35
2.9
0.35
7.3
0.35
2.2
0.35
4.2


0.4
2.9
0.4
7.3
0.4
2.2
0.4
4.2


0.45
2.9
0.45
7.3
0.45
2.2
0.45
4.2


0.5
2.9
0.5
7.3
0.5
2.2
0.5
4.1


0.55
2.9
0.55
7.3
0.55
2.2
0.55
4.1


0.6
2.9
0.6
7.3
0.6
2.2
0.6
4.1


0.65
2.9
0.65
7.3
0.65
2.2
0.65
4.1


0.7
2.9
0.7
7.3
0.7
2.1
0.7
4.0


0.75
2.9
0.75
7.1
0.75
2.1
0.75
4.0


0.8
2.8
0.8
6.8
0.8
2.1
0.8
3.9


0.85
2.6
0.85
6.2
0.85
2.1
0.85
3.5


0.9
2.2
0.9
5.2
0.9
1.9
0.9
3.1


0.95
1.8
0.95
3.6
0.95
1.6
0.95
2.3


1
1.2
1
1.2
1
1.2
1
1.2










HF - HCFO-1233xf - HFC-245cb - HCFC-244bb










Organics
Organics
Organics
Organics


0.9 F1233xf +
0.05 F1233xf +
0.05 F1233xf +
0.4 F1233xf +


0.05 F245cb +
0.9 F245cb +
0.05 F245cb +
0.3 F245cb +


0.05 F244bb
0.05 F244bb
0.9 F244bb
0.3 F244bb















TOTAL

TOTAL

TOTAL

TOTAL


MASSFRAC
PRESSURE
MASSFRAC
PRESSURE
MASSFRAC
PRESSURE
MASSFRAC
PRESSURE


HF
bar
HF
bar
HF
bar
HF
bar





0
1.7
0
4.3
0
0.9
0
2.3


0.05
2.8
0.05
5.5
0.05
2.1
0.05
3.4


0.1
2.8
0.1
5.5
0.1
2.1
0.1
3.4


0.15
2.8
0.15
5.5
0.15
2.1
0.15
3.4


0.2
2.8
0.2
5.5
0.2
2.1
0.2
3.4


0.25
2.8
0.25
5.5
0.25
2.1
0.25
3.4


0.3
2.8
0.3
5.5
0.3
2.1
0.3
3.4


0.35
2.8
0.35
5.5
0.35
2.1
0.35
3.4


0.4
2.8
0.4
5.5
0.4
2.1
0.4
3.4


0.45
2.8
0.45
5.5
0.45
2.1
0.45
3.4


0.5
2.8
0.5
5.5
0.5
2.1
0.5
3.4


0.55
2.8
0.55
5.5
0.55
2.1
0.55
3.4


0.6
2.8
0.6
5.5
0.6
2.0
0.6
3.4


0.65
2.8
0.65
5.5
0.65
2.0
0.65
3.4


0.7
2.8
0.7
5.5
0.7
2.0
0.7
3.4


0.75
2.8
0.75
5.5
0.75
2.0
0.75
3.4


0.8
2.7
0.8
5.5
0.8
2.0
0.8
3.4


0.85
2.5
0.85
5.5
0.85
2.0
0.85
3.3


0.9
2.2
0.9
4.7
0.9
1.9
0.9
2.9


0.95
1.8
0.95
3.4
0.95
1.6
0.95
2.2


1
1.2
1
1.2
1
1.2
1
1.2









Example 5: Temperature and Pressure Range of Quaternary Mixtures













Boiling point range










Temperature
Pressure bar


Quaternary
° C.
abs





HF - HCFO-1233xf - HFC-245cb - HCFO-1233zdE
0 to 40
~1.0 to ~8.7


HF - HCFO-1233xf - HFC-245cb - HFO-1234zeE
0 to 40
~1.1 to ~8.8


HF - HCFO-1233xf - HFC-245cb - HFO-1234zeZ
0 to 40
~1.1 to ~8.8


HF - HCFO-1233xf - HFC-245cb - HFO - 1243zf
0 to 40
 ~1.2 to ~10.1


HF - HCFO-1233xf - HCFO-1233zdE - HFO- 1234zeE
0 to 40
~1.0 to ~8.6


HF - HCFO-1233xf - HCFO-1233zdE - HFO- 1234zeZ
0 to 40
~0.9 to ~4.8


HF - HCFO-1233xf - HCFO-1233zdE - HFO-
0 to 40
~1.0 to ~9.9


1243zf


HF - HCFO-1233xf - HFO-1234zeE - HFO- 1234zeZ
0 to 40
~1.1 to ~8.6


HF - HCFO-1233xf - HFO-1234zeE - HFO-1243zf
0 to 40
 ~1.2 to ~10.1


HF - HCFO-1233xf - HFO-1234zeZ - HFO-1243zf
0 to 40
~1.1 to ~9.9


HF - HCFO-1233xf - HFC-245cb - HFO-1234yf
0 to 40
 ~1.2 to ~10.0


HF - HCFO-1233xf - HFO-1234yf - HCFO- 1233zdE
0 to 40
 ~1.0 to ~11.1


HF - HCFO-1233xf - HFO-1234yf - HFO-1234zeE
0 to 40
 ~1.2 to ~11.3


HF - HCFO-1233xf - HFO-1234yf - HFO-1234zeZ
0 to 40
 ~1.0 to ~11.0


HF - HCFO-1233xf - HFO-1234yf - HFO-1243zf
0 to 40
 ~1.3 to ~11.3


HF - HFO-1234yf - HCFO-1233xf - HCFC-244bb
0 to 40
 ~0.8 to ~11.0


HF - HCFO-1233xf - HFC-245cb - HCFC-244bb
0 to 40
~0.7 to ~8.6









Example 6: Decantation Range of Quaternary Mixtures













Decantation ranges



Mass percentage of HF












Iso-



Quaternary
Isotherm
therm
Isotherm


HF-Orga1 Orga2 Orga3
0° C.
25° C.
40° C.





HF - HCFO-1233xf - HFC-245cb -
5-75
5-75
15-70


HFO-1234yf


HF - HCFO-1233xf - HFC-245cb -
5-80
5-75
 5-70


HCFO-1233zdE


HF - HCFO-1233xf - HFC-245cb -
5-75
5-70
15-60


HFO-1234zeE


HF - HCFO-1233xf - HFC-245cb -
5-80
5-75
 5-70


HFO-1234zeZ


HF - HCFO-1233xf - HFC-245cb -
5-75
5-70
15-60


HFO-1243zf


HF - HCFO-1233xf - HFO-1234yf -
5-75
5-70
10-60


HCFO-1233zdE


HF - HCFO-1233xf - HFO-1234yf -
5-70
10-60 
*


HFO-1234zeE


HF - HCFO-1233xf - HFO-1234yf -
5-75
5-70
10-60


HFO-1234zeZ


HF - HCFO-1233xf - HFO-1234yf -
5-75
10-65 
*


HFO-1243zf


HF - HCFO-1233xf - HCFO-1233zdE -
5-75
5-65
 5-55


HFO-1234zeE


HF - HCFO-1233xf - HCFO-1233zdE -
5-80
5-75
 5-65


HFO-1234zeZ


HF - HCFO-1233xf - HCFO-1233zdE -
5-75
5-70
10-60


HFO-1243zf


HF - HCFO-1233xf - HFO-1234zeE -
5-75
5-65
10-55


HFO-1234zeZ


HF - HCFO-1233xf - HFO-1234zeE -
5-70
10-60 
*


HFO-1243zf


HF - HCFO-1233xf - HFO-1234zeZ -
5-75
5-70
10-55


HFO-1243zf


HF - HFO-1234yf-HCFO-1233xf -
1-80
20-99 
 5-75


HCFC-244bb


HF - HCFO-1233xf - HFC-245cb -
1-85
15-99 
 5-80


HCFC-244bb









Example 7: Penternary Mixtures, Isotherm at 25° C.












HF - HCFO-1233xf - HFC-245cb - HCFO-1233zdE - HFO-1234zeE











Organics
Organics
Organics
Organics
Organics


0.9 F1233xf +
0.033 F1233xf +
0.033 F1233xf +
0.034 F1233xf +
0.25 F1233xf +


0.033 F1233zdE +
0.9 F1233zdE +
0.033 F1233zdE +
0.033 F1233zdE +
0.25 F1233zdE +


0.033 F245cb +
0.033 F245cb +
0.9 245cb +
0.033 F245cb +
0.25 F245cb +


0.034 F1234zeE
0.034 F1234zeE
0.034 F1234zeE
0.9 F1234zeE
0.25 F1234zeE

















TOTAL

TOTAL

TOTAL

TOTAL

TOTAL


MASSFRA
PRESSUR
MASSFRA
PRESSUR
MASSFRA
PRESSUR
MASSFRA
PRESSUR
MASSFRA
PRESSUR


HF
bar
HF
bar
HF
bar
HF
bar
HF
bar





0
1.8
0
1.6
0
4.4
0
4.7
0
3.2


0.05
2.9
0.05
2.7
0.05
5.6
0.05
5.6
0.05
4.3


0.1
2.9
0.1
2.7
0.1
5.6
0.1
5.6
0.1
4.3


0.15
2.9
0.15
2.7
0.15
5.6
0.15
5.6
0.15
4.3


0.2
2.9
0.2
2.7
0.2
5.6
0.2
5.6
0.2
4.3


0.25
2.9
0.25
2.7
0.25
5.6
0.25
5.6
0.25
4.3


0.3
2.9
0.3
2.7
0.3
5.6
0.3
5.6
0.3
4.3


0.35
2.9
0.35
2.7
0.35
5.6
0.35
5.6
0.35
4.3


0.4
2.9
0.4
2.7
0.4
5.6
0.4
5.6
0.4
4.3


0.45
2.9
0.45
2.7
0.45
5.6
0.45
5.6
0.45
4.3


0.5
2.9
0.5
2.7
0.5
5.6
0.5
5.6
0.5
4.3


0.55
2.9
0.55
2.7
0.55
5.6
0.55
5.6
0.55
4.3


0.6
2.9
0.6
2.7
0.6
5.6
0.6
5.5
0.6
4.3


0.65
2.9
0.65
2.7
0.65
5.6
0.65
5.4
0.65
4.3


0.7
2.9
0.7
2.7
0.7
5.7
0.7
5.2
0.7
4.3


0.75
2.9
0.75
2.7
0.75
5.7
0.75
5.0
0.75
4.2


0.8
2.7
0.8
2.6
0.8
5.7
0.8
4.7
0.8
4.0


0.85
2.5
0.85
2.4
0.85
5.6
0.85
4.2
0.85
3.7


0.9
2.2
0.9
2.1
0.9
4.8
0.9
3.5
0.9
3.2


0.95
1.8
0.95
1.7
0.95
3.4
0.95
2.5
0.95
2.4


1
1.2
1
1.2
1
1.2
1
1.2
1
1.2










HF - HCFO-1233xf - HFC-245cb - HCFO-1233zdE - HFO-1234zeZ











Organics
Organics
Organics
Organics
Organics


0.9 F1233xf +
0.033 F1233xf +
0.033 F1233xf +
0.034 F1233xf +
0.25 F1233xf +


0.033 F1233zdE +
0.9 F1233zdE +
0.033 F1233zdE +
0.033 F1233zdE +
0.25 F1233zdE +


0.033 F245cb +
0.033 F245cb +
0.9 F245cb +
0.033 F245cb +
0.25 F245cb +


0.034 F1234zeZ
0.034 F1234zeZ
0.034 F1234zeZ
0.9 F1234zeZ
0.25 F1234zeZ

















TOTAL

TOTAL

TOTAL

TOTAL

TOTAL


MASSFRA
PRESSUR
MASSFRA
PRESSUR
MASSFRA
PRESSUR
MASSFRA
PRESSUR
MASSFRA
PRESSUR


HF
bar
HF
bar
HF
bar
HF
bar
HF
bar





0
1.7
0
1.5
0
4.3
0
1.9
0
2.3


0.05
2.8
0.05
2.6
0.05
5.5
0.05
3.0
0.05
3.5


0.1
2.8
0.1
2.6
0.1
5.5
0.1
3.0
0.1
3.5


0.15
2.8
0.15
2.6
0.15
5.5
0.15
3.0
0.15
3.5


0.2
2.8
0.2
2.6
0.2
5.5
0.2
3.0
0.2
3.5


0.25
2.8
0.25
2.6
0.25
5.5
0.25
3.0
0.25
3.5


0.3
2.8
0.3
2.6
0.3
5.5
0.3
3.0
0.3
3.5


0.35
2.8
0.35
2.6
0.35
5.5
0.35
3.0
0.35
3.5


0.4
2.8
0.4
2.6
0.4
5.5
0.4
3.0
0.4
3.5


0.45
2.8
0.45
2.6
0.45
5.5
0.45
3.0
0.45
3.5


0.5
2.8
0.5
2.6
0.5
5.5
0.5
3.0
0.5
3.5


0.55
2.8
0.55
2.6
0.55
5.5
0.55
3.0
0.55
3.5


0.6
2.8
0.6
2.6
0.6
5.5
0.6
3.0
0.6
3.5


0.65
2.8
0.65
2.6
0.65
5.5
0.65
3.0
0.65
3.6


0.7
2.8
0.7
2.6
0.7
5.6
0.7
3.0
0.7
3.6


0.75
2.8
0.75
2.6
0.75
5.6
0.75
3.0
0.75
3.6


0.8
2.7
0.8
2.5
0.8
5.6
0.8
2.9
0.8
3.5


0.85
2.5
0.85
2.3
0.85
5.5
0.85
2.7
0.85
3.3


0.9
2.2
0.9
2.1
0.9
4.8
0.9
2.4
0.9
2.8


0.95
1.8
0.95
1.7
0.95
3.4
0.95
1.9
0.95
2.2


1
1.2
1
1.2
1
1.2
1
1.2
1
1.2










HF - HCFO-1233xf - HFC-245cb - HCFO-1233zdE - HFO-1243zf











Organics
Organics
Organics
Organics
Organics


0.9 F1233xf +
0.033 F1233xf +
0.033 F1233xf +
0.034 F1233xf +
0.25 F1233xf +


0.033 F1233zdE +
0.9 F1233zdE +
0.033 F1233zdE +
0.033 F1233zdE +
0.25 F1233zdE +


0.033 F245cb +
0.033 F245cb +
0.9 F245cb +
0.033 F245cb +
0.25 F245cb +


0.034 F1243zf
0.034 F1243zf
0.034 F1243zf
0.9 F1243zf
0.25 F1243zf

















TOTAL

TOTAL

TOTAL

TOTAL

TOTAL


MASSFRA
PRESSURE
MASSFRA
PRESSURE
MASSFRA
PRESSURE
MASSFRA
PRESSURE
MASSFRA
PRESSURE


HF
bar
HF
bar
HF
bar
HF
bar
HF
bar





0
1.8
0
1.6
0
4.5
0
5.6
0
3.5


0.05
3.0
0.05
2.8
0.05
5.7
0.05
6.5
0.05
4.6


0.1
3.0
0.1
2.8
0.1
5.7
0.1
6.6
0.1
4.6


0.15
3.0
0.15
2.8
0.15
5.7
0.15
6.6
0.15
4.6


0.2
3.0
0.2
2.8
0.2
5.7
0.2
6.5
0.2
4.6


0.25
3.0
0.25
2.8
0.25
5.7
0.25
6.5
0.25
4.6


0.3
3.0
0.3
2.8
0.3
5.7
0.3
6.5
0.3
4.6


0.35
2.9
0.35
2.8
0.35
5.7
0.35
6.5
0.35
4.6


0.4
2.9
0.4
2.8
0.4
5.7
0.4
6.5
0.4
4.6


0.45
2.9
0.45
2.7
0.45
5.7
0.45
6.5
0.45
4.6


0.5
2.9
0.5
2.7
0.5
5.7
0.5
6.5
0.5
4.6


0.55
2.9
0.55
2.7
0.55
5.7
0.55
6.5
0.55
4.6


0.6
2.9
0.6
2.7
0.6
5.7
0.6
6.5
0.6
4.6


0.65
2.9
0.65
2.7
0.65
5.7
0.65
6.4
0.65
4.6


0.7
2.9
0.7
2.7
0.7
5.7
0.7
6.4
0.7
4.7


0.75
2.9
0.75
2.7
0.75
5.7
0.75
6.2
0.75
4.6


0.8
2.8
0.8
2.6
0.8
5.7
0.8
5.9
0.8
4.4


0.85
2.6
0.85
2.4
0.85
5.6
0.85
5.4
0.85
4.1


0.9
2.3
0.9
2.2
0.9
4.8
0.9
4.6
0.9
3.5


0.95
1.8
0.95
1.8
0.95
3.4
0.95
3.3
0.95
2.6


1
1.2
1
1.2
1
1.2
1
1.2
1
1.2










HF - HCFO-1233xf - HFC-245cb - HFO-1234zeE - HFO-1234zeZ











Organics
Organics
Organics
Organics
Organics


0.9 F1233xf +
0.033 F1233xf +
0.033 F1233xf +
0.034 F1233xf +
0.25 F1233xf +


0.033 F1234zeE +
0.9 1234zeE +
0.033 F1234zeE +
0.033 F1234zeE +
0.25 F1234zeE +


0.033 F245cb +
0.033 F245cb +
0.9 F245cb +
0.033 F245cb +
0.25 F245cb +


0.034 F1234zeZ
0.034 F1234zeZ
0.034 F1234zeZ
0.9 F1234zeZ
0.25 F1234zeZ

















TOTAL

TOTAL

TOTAL

TOTAL

TOTAL


MASSFRAC
PRESSURE
MASSFRAC
PRESSURE
MASSFRAC
PRESSURE
MASSFRAC
PRESSURE
MASSFRAC
PRESSURE


HF
bar
HF
bar
HF
bar
HF
bar
HF
bar





0
1.8
0
4.7
0
4.5
0
2.0
0
3.2


0.05
2.9
0.05
5.6
0.05
5.6
0.05
3.1
0.05
4.3


0.1
2.9
0.1
5.7
0.1
5.6
0.1
3.1
0.1
4.3


0.15
2.9
0.15
5.6
0.15
5.6
0.15
3.1
0.15
4.3


0.2
2.9
0.2
5.6
0.2
5.6
0.2
3.1
0.2
4.3


0.25
2.9
0.25
5.6
0.25
5.6
0.25
3.1
0.25
4.3


0.3
2.9
0.3
5.6
0.3
5.6
0.3
3.1
0.3
4.3


0.35
2.9
0.35
5.6
0.35
5.6
0.35
3.1
0.35
4.3


0.4
2.9
0.4
5.6
0.4
5.6
0.4
3.1
0.4
4.3


0.45
2.9
0.45
5.6
0.45
5.6
0.45
3.1
0.45
4.3


0.5
2.9
0.5
5.6
0.5
5.6
0.5
3.1
0.5
4.3


0.55
2.9
0.55
5.6
0.55
5.6
0.55
3.1
0.55
4.3


0.6
2.9
0.6
5.5
0.6
5.6
0.6
3.1
0.6
4.3


0.65
2.9
0.65
5.4
0.65
5.7
0.65
3.1
0.65
4.4


0.7
2.9
0.7
5.2
0.7
5.7
0.7
3.1
0.7
4.4


0.75
2.9
0.75
5.0
0.75
5.7
0.75
3.1
0.75
4.3


0.8
2.7
0.8
4.7
0.8
5.7
0.8
3.0
0.8
4.1


0.85
2.5
0.85
4.2
0.85
5.6
0.85
2.7
0.85
3.8


0.9
2.2
0.9
3.5
0.9
4.8
0.9
2.4
0.9
3.3


0.95
1.8
0.95
2.6
0.95
3.4
0.95
1.9
0.95
2.4


1
1.2
1
1.2
1
1.2
1
1.2
1
1.2










HF - HCFO-1233xf - HFC-245cb - HFO-1234zeE - HFO-1243zf











Organics
Organics
Organics
Organics
Organics


0.9 F1233xf +
0.033 F1233xf +
0.033 F1233xf +
0.034 F1233xf +
0.25 F1233xf +


0.033 F1234zeE +
0.9 F1234zeE +
0.033 F1234zeE +
0.033 F1234zeE +
0.25 F1234zeE +


0.033 F245cb +
0.033 F245cb +
0.9 F245cb +
0.033 F245cb +
0.25 F245cb +


0.034 F1243zf
0.034 F1243zf
0.034 F1243zf
0.9 F1243zf
0.25 F1243zf

















TOTAL

TOTAL

TOTAL

TOTAL

TOTAL


MASSFRA
PRESSUR
MASSFRA
PRESSUR
MASSFRA
PRESSUR
MASSFRA
PRESSUR
MASSFRA
PRESSUR


HF
bar
HF
bar
HF
bar
HF
bar
HF
bar





0
2.0
0
4.8
0
4.6
0
5.7
0
4.4


0.05
3.1
0.05
5.8
0.05
5.8
0.05
6.6
0.05
5.4


0.1
3.1
0.1
5.8
0.1
5.8
0.1
6.7
0.1
5.4


0.15
3.1
0.15
5.8
0.15
5.8
0.15
6.6
0.15
5.4


0.2
3.1
0.2
5.8
0.2
5.8
0.2
6.6
0.2
5.4


0.25
3.1
0.25
5.8
0.25
5.8
0.25
6.6
0.25
5.4


0.3
3.1
0.3
5.8
0.3
5.8
0.3
6.6
0.3
5.4


0.35
3.1
0.35
5.8
0.35
5.8
0.35
6.6
0.35
5.4


0.4
3.1
0.4
5.8
0.4
5.8
0.4
6.6
0.4
5.4


0.45
3.1
0.45
5.8
0.45
5.8
0.45
6.6
0.45
5.4


0.5
3.1
0.5
5.7
0.5
5.8
0.5
6.6
0.5
5.4


0.55
3.1
0.55
5.7
0.55
5.8
0.55
6.6
0.55
5.4


0.6
3.1
0.6
5.6
0.6
5.8
0.6
6.6
0.6
5.4


0.65
3.1
0.65
5.5
0.65
5.8
0.65
6.5
0.65
5.4


0.7
3.1
0.7
5.4
0.7
5.8
0.7
6.4
0.7
5.4


0.75
3.0
0.75
5.2
0.75
5.8
0.75
6.3
0.75
5.3


0.8
2.9
0.8
4.8
0.8
5.8
0.8
6.0
0.8
5.0


0.85
2.7
0.85
4.3
0.85
5.7
0.85
5.5
0.85
4.6


0.9
2.3
0.9
3.6
0.9
4.9
0.9
4.7
0.9
3.9


0.95
1.9
0.95
2.6
0.95
3.5
0.95
3.3
0.95
2.8


1
1.2
1
1.2
1
1.2
1
1.2
1
1.2










HF - HCFO-1233xf - HFC-245cb - HFO-1234zeZ - HFO-1243zf











Organics
Organics
Organics
Organics
Organics


0.9 F1233xf +
0.033 F1233xf +
0.033 F1233xf +
0.034 F1233xf +
0.25 F1233xf +


0.033 F1234zeZ +
0.9 F1234zeZ +
0.033 F1234zeZ +
0.033 F1234zeZ +
0.25 F1234zeZ +


0.033 F245cb +
0.033 F245cb +
0.9 F245cb +
0.033 F245cb +
0.25 F245cb +


0.034 F1243zf
0.034 F1243zf
0.034 F1243zf
0.9 F1243zf
0.25 F1243zf

















TOTAL

TOTAL

TOTAL

TOTAL

TOTAL


MASSFRA
PRESSUR
MASSFRA
PRESSUR
MASSFRA
PRESSUR
MASSFRA
PRESSUR
MASSFRA
PRESSUR


HF
bar
HF
bar
HF
bar
HF
bar
HF
bar





0
1.9
0
2.1
0
4.5
0
5.6
0
3.6


0.05
3.0
0.05
3.2
0.05
5.7
0.05
6.5
0.05
4.7


0.1
3.0
0.1
3.2
0.1
5.7
0.1
6.6
0.1
4.7


0.15
3.0
0.15
3.2
0.15
5.7
0.15
6.6
0.15
4.7


0.2
3.0
0.2
3.2
0.2
5.7
0.2
6.6
0.2
4.7


0.25
3.0
0.25
3.2
0.25
5.7
0.25
6.5
0.25
4.7


0.3
3.0
0.3
3.2
0.3
5.7
0.3
6.5
0.3
4.7


0.35
3.0
0.35
3.2
0.35
5.7
0.35
6.5
0.35
4.7


0.4
3.0
0.4
3.2
0.4
5.7
0.4
6.5
0.4
4.7


0.45
3.0
0.45
3.2
0.45
5.7
0.45
6.5
0.45
4.7


0.5
3.0
0.5
3.2
0.5
5.7
0.5
6.5
0.5
4.7


0.55
3.0
0.55
3.2
0.55
5.7
0.55
6.5
0.55
4.7


0.6
3.0
0.6
3.2
0.6
5.7
0.6
6.5
0.6
4.7


0.65
3.0
0.65
3.2
0.65
5.7
0.65
6.5
0.65
4.7


0.7
3.0
0.7
3.2
0.7
5.7
0.7
6.4
0.7
4.7


0.75
3.0
0.75
3.2
0.75
5.7
0.75
6.2
0.75
4.7


0.8
2.8
0.8
3.0
0.8
5.7
0.8
5.9
0.8
4.5


0.85
2.6
0.85
2.8
0.85
5.6
0.85
5.4
0.85
4.2


0.9
2.3
0.9
2.5
0.9
4.8
0.9
4.6
0.9
3.6


0.95
1.8
0.95
1.9
0.95
3.4
0.95
3.3
0.95
2.6


1
1.2
1
1.2
1
1.2
1
1.2
1
1.2










HF - HCFO-1233xf - HCFO-1233zdE - HFO-1234zeE 5 - HFO-1234zeZ











Organics
Organics
Organics
Organics
Organics


0.9 F1233xf +
0.033 F1233xf +
0.033 F1233xf +
0.034 F1233xf +
0.25 F1233xf +


0.033 F1234zeE +
0.9 F1234zeE +
0.033 F1234zeE +
0.033 F1234zeE +
0.25 F1234zeE +


0.033 F1233zdE +
0.033 F1233zdE +
0.9 F1233zdE +
0.033 F1233zdE +
0.25 F1233zdE +


0.034 F1234zeZ
0.034 F1234zeZ
0.034 F1234zeZ
0.9 F1234zeZ
0.25 F1234zeZ

















TOTAL

TOTAL

TOTAL

TOTAL

TOTAL


MASSFRA
PRESSUR
MASSFRA
PRESSUR
MASSFRA
PRESSUR
MASSFRA
PRESSUR
MASSFRA
PRESSUR


HF
bar
HF
bar
HF
bar
HF
bar
HF
bar





0
1.7
0
4.6
0
1.5
0
1.9
0
2.4


0.05
2.8
0.05
5.5
0.05
2.6
0.05
3.0
0.05
3.5


0.1
2.8
0.1
5.5
0.1
2.6
0.1
3.0
0.1
3.5


0.15
2.8
0.15
5.5
0.15
2.6
0.15
3.0
0.15
3.5


0.2
2.8
0.2
5.5
0.2
2.6
0.2
3.0
0.2
3.5


0.25
2.8
0.25
5.5
0.25
2.6
0.25
3.0
0.25
3.5


0.3
2.8
0.3
5.5
0.3
2.6
0.3
3.0
0.3
3.5


0.35
2.8
0.35
5.5
0.35
2.6
0.35
3.0
0.35
3.5


0.4
2.8
0.4
5.5
0.4
2.6
0.4
3.0
0.4
3.5


0.45
2.8
0.45
5.5
0.45
2.6
0.45
3.0
0.45
3.5


0.5
2.8
0.5
5.5
0.5
2.6
0.5
3.0
0.5
3.5


0.55
2.8
0.55
5.4
0.55
2.6
0.55
3.0
0.55
3.4


0.6
2.8
0.6
5.4
0.6
2.6
0.6
3.0
0.6
3.4


0.65
2.8
0.65
5.3
0.65
2.6
0.65
3.0
0.65
3.4


0.7
2.8
0.7
5.1
0.7
2.5
0.7
3.0
0.7
3.4


0.75
2.7
0.75
4.9
0.75
2.5
0.75
3.0
0.75
3.3


0.8
2.6
0.8
4.6
0.8
2.4
0.8
2.8
0.8
3.1


0.85
2.4
0.85
4.1
0.85
2.3
0.85
2.6
0.85
2.9


0.9
2.1
0.9
3.4
0.9
2.0
0.9
2.3
0.9
2.5


0.95
1.7
0.95
2.5
0.95
1.7
0.95
1.9
0.95
1.9


1
1.2
1
1.2
1
1.2
1
1.2
1
1.2










HF - HCFO-1233xf- HCFO-1233zdE - HFO-1234zeE - HFO-1243zf











Organics
Organics
Organics
Organics
Organics


0.9 F1233xf +
0.033 F1233xf +
0.033 F1233xf +
0.034 F1233xf +
0.25 F1233xf +


0.033 F1234zeE +
0.9 F1234zeE +
0.033 F1234zeE +
0.033 F1234zeE +
0.25 1234zeE +


0.033 F1233zdE +
0.033 F1233zdE +
0.9 F1233zdE +
0.033 F1233zdE +
0.25 F1233zdE +


0.034 F1243zf
0.034 F1243zf
0.034 F1243zf
0.9 F1243zf
0.25 F1243zf

















TOTAL

TOTAL

TOTAL

TOTAL

TOTAL


MASSFRA
PRESSUR
MASSFRA
PRESSUR
MASSFRA
PRESSUR
MASSFRA
PRESSUR
MASSFRA
PRESSUR


HF
bar
HF
bar
HF
bar
HF
bar
HF
bar





0
1.9
0
4.7
0
1.7
0
5.6
0
3.6


0.05
3.0
0.05
5.7
0.05
2.8
0.05
6.5
0.05
4.7


0.1
3.0
0.1
5.7
0.1
2.8
0.1
6.6
0.1
4.7


0.15
3.0
0.15
5.7
0.15
2.8
0.15
6.6
0.15
4.7


0.2
3.0
0.2
5.7
0.2
2.8
0.2
6.5
0.2
4.7


0.25
3.0
0.25
5.7
0.25
2.8
0.25
6.5
0.25
4.6


0.3
2.9
0.3
5.7
0.3
2.7
0.3
6.5
0.3
4.6


0.35
2.9
0.35
5.7
0.35
2.7
0.35
6.5
0.35
4.6


0.4
2.9
0.4
5.7
0.4
2.7
0.4
6.5
0.4
4.6


0.45
2.9
0.45
5.7
0.45
2.7
0.45
6.5
0.45
4.6


0.5
2.9
0.5
5.6
0.5
2.7
0.5
6.5
0.5
4.6


0.55
2.9
0.55
5.6
0.55
2.7
0.55
6.5
0.55
4.6


0.6
2.9
0.6
5.5
0.6
2.7
0.6
6.5
0.6
4.6


0.65
2.9
0.65
5.4
0.65
2.7
0.65
6.4
0.65
4.5


0.7
2.9
0.7
5.3
0.7
2.7
0.7
6.3
0.7
4.5


0.75
2.9
0.75
5.0
0.75
2.7
0.75
6.2
0.75
4.3


0.8
2.7
0.8
4.7
0.8
2.6
0.8
5.9
0.8
4.1


0.85
2.5
0.85
4.2
0.85
2.4
0.85
5.4
0.85
3.7


0.9
2.2
0.9
3.5
0.9
2.1
0.9
4.6
0.9
3.1


0.95
1.8
0.95
2.5
0.95
1.7
0.95
3.3
0.95
2.3


1
1.2
1
1.2
1
1.2
1
1.2
1
1.2










HF - HCFO-1233xf - HCFO-1233zdE - HFO-1234zeZ - HFO-1243zf











Organics
Organics
Organics
Organics
Organics


0.9 F1233xf +
0.033 F1233xf +
0.033 F1233xf +
0.034 F1233xf +
0.25 F1233xf +


0.033 F1234zeZ +
0.9 F1234zeZ +
0.033 F1234zeZ +
0.033 F1234zeZ +
0.25 F1234zeZ +


0.033 F1233zdE +
0.033 F1233zdE +
0.9 F1233zdE +
0.033 F1233zdE +
0.25 F1233zdE +


0.034 F1243zf
0.034 F1243zf
0.034 F1243zf
0.9 F1243zf
0.25 F1243zf

















TOTAL

TOTAL

TOTAL

TOTAL

TOTAL


MASSFRA
PRESSUR
MASSFRA
PRESSUR
MASSFRA
PRESSUR
MASSFRA
PRESSUR
MASSFRA
PRESSUR


HF
bar
HF
bar
HF
bar
HF
bar
HF
bar





0
1.7
0
1.9
0
1.5
0
5.5
0
2.8


0.05
2.8
0.05
3.0
0.05
2.6
0.05
6.4
0.05
3.9


0.1
2.8
0.1
3.0
0.1
2.6
0.1
6.5
0.1
3.9


0.15
2.8
0.15
3.0
0.15
2.6
0.15
6.5
0.15
3.9


0.2
2.8
0.2
3.0
0.2
2.6
0.2
6.5
0.2
3.9


0.25
2.8
0.25
3.0
0.25
2.6
0.25
6.5
0.25
3.9


0.3
2.8
0.3
3.0
0.3
2.6
0.3
6.5
0.3
3.9


0.35
2.8
0.35
3.0
0.35
2.6
0.35
6.5
0.35
3.9


0.4
2.8
0.4
3.0
0.4
2.6
0.4
6.5
0.4
3.9


0.45
2.8
0.45
3.0
0.45
2.6
0.45
6.4
0.45
3.9


0.5
2.8
0.5
3.0
0.5
2.6
0.5
6.4
0.5
3.9


0.55
2.8
0.55
3.0
0.55
2.6
0.55
6.4
0.55
3.9


0.6
2.8
0.6
3.0
0.6
2.6
0.6
6.4
0.6
3.9


0.65
2.8
0.65
3.0
0.65
2.6
0.65
6.4
0.65
3.8


0.7
2.8
0.7
3.0
0.7
2.6
0.7
6.3
0.7
3.8


0.75
2.8
0.75
3.0
0.75
2.6
0.75
6.1
0.75
3.7


0.8
2.7
0.8
2.9
0.8
2.5
0.8
5.8
0.8
3.6


0.85
2.5
0.85
2.7
0.85
2.3
0.85
5.3
0.85
3.3


0.9
2.2
0.9
2.4
0.9
2.1
0.9
4.5
0.9
2.8


0.95
1.8
0.95
1.9
0.95
1.7
0.95
3.2
0.95
2.2


1
1.2
1
1.2
1
1.2
1
1.2
1
1.2










HF - HCFO-1233xf - HFO-1234zeE - HFO-1234zeZ - HFO-1243zf











Organics
Organics
Organics
Organics
Organics


0.9 F1233xf +
0.033 F1233xf +
0.033 F1233xf +
0.034 F1233xf +
0.25 F1233xf +


0.033 F1234zeE +
0.9 F1234zeE +
0.033 F1234zeE +
0.033 F1234zeE +
0.25 F1234zeE +


0.033 F1234zeZ +
0.033 F1234zeZ +
0.9 F1234zeZ +
0.033 F1234zeZ +
0.25 F1234zeZ +


0.034 F1243zf
0.034 F1243zf
0.034 F1243zf
0.9 F1243zf
0.25 F1243zf

















TOTAL

TOTAL

TOTAL

TOTAL

TOTAL


MASSFRA
PRESSUR
MASSFRA
PRESSUR
MASSFRA
PRESSUR
MASSFRA
PRESSUR
MASSFRA
PRESSUR


HF
bar
HF
bar
HF
bar
HF
bar
HF
bar





0
1.9
0
4.7
0
2.1
0
5.6
0
3.7


0.05
3.0
0.05
5.7
0.05
3.2
0.05
6.5
0.05
4.7


0.1
3.0
0.1
5.7
0.1
3.2
0.1
6.6
0.1
4.7


0.15
3.0
0.15
5.7
0.15
3.2
0.15
6.6
0.15
4.7


0.2
3.0
0.2
5.7
0.2
3.2
0.2
6.5
0.2
4.7


0.25
3.0
0.25
5.7
0.25
3.2
0.25
6.5
0.25
4.7


0.3
3.0
0.3
5.7
0.3
3.2
0.3
6.5
0.3
4.7


0.35
3.0
0.35
5.7
0.35
3.2
0.35
6.5
0.35
4.7


0.4
3.0
0.4
5.7
0.4
3.2
0.4
6.5
0.4
4.7


0.45
3.0
0.45
5.7
0.45
3.2
0.45
6.5
0.45
4.7


0.5
3.0
0.5
5.6
0.5
3.2
0.5
6.5
0.5
4.7


0.55
2.9
0.55
5.6
0.55
3.1
0.55
6.5
0.55
4.6


0.6
2.9
0.6
5.5
0.6
3.1
0.6
6.5
0.6
4.6


0.65
2.9
0.65
5.4
0.65
3.1
0.65
6.4
0.65
4.6


0.7
2.9
0.7
5.3
0.7
3.1
0.7
6.3
0.7
4.5


0.75
2.9
0.75
5.0
0.75
3.1
0.75
6.2
0.75
4.4


0.8
2.8
0.8
4.7
0.8
3.0
0.8
5.9
0.8
4.1


0.85
2.6
0.85
4.2
0.85
2.7
0.85
5.4
0.85
3.8


0.9
2.2
0.9
3.5
0.9
2.4
0.9
4.6
0.9
3.2


0.95
1.8
0.95
2.5
0.95
1.9
0.95
3.3
0.95
2.4


1
1.2
1
1.2
1
1.2
1
1.2
1
1.2










HF - HCFO-1233xf - HFC-245cb - HFO-1234yf - HFO-1243zf











Organics
Organics
Organics
Organics
Organics


0.9 F1233xf +
0.033 F1233xf +
0.033 F1233xf +
0.034 F1233xf +
0.25 F1233xf +


0.033 F1234yf +
0.9 F1234yf +
0.033 F1234yf +
0.033 F1234yf +
0.25 F1234yf +


0.033 F245cb +
0.033 F245cb +
0.9 F245cb +
0.033 F245cb +
0.25 F245cb +


0.034 F1243zf
0.034 F1243zf
0.034 F1243zf
0.9 F1243zf
0.25 F1243zf

















TOTAL

TOTAL

TOTAL

TOTAL

TOTAL


MASSFRA
PRESSUR
MASSFRA
PRESSUR
MASSFRA
PRESSUR
MASSFRA
PRESSUR
MASSFRA
PRESSUR


HF
bar
HF
bar
HF
bar
HF
bar
HF
bar





0
2.0
0
6.5
0
4.7
0
5.7
0
4.8


0.05
3.2
0.05
7.5
0.05
5.8
0.05
6.7
0.05
5.9


0.1
3.2
0.1
7.5
0.1
5.9
0.1
6.7
0.1
5.9


0.15
3.2
0.15
7.5
0.15
5.9
0.15
6.7
0.15
5.9


0.2
3.2
0.2
7.5
0.2
5.9
0.2
6.7
0.2
5.9


0.25
3.2
0.25
7.5
0.25
5.9
0.25
6.7
0.25
5.9


0.3
3.2
0.3
7.5
0.3
5.9
0.3
6.7
0.3
5.9


0.35
3.2
0.35
7.5
0.35
5.9
0.35
6.7
0.35
5.9


0.4
3.2
0.4
7.5
0.4
5.9
0.4
6.7
0.4
5.9


0.45
3.2
0.45
7.5
0.45
5.9
0.45
6.7
0.45
5.9


0.5
3.1
0.5
7.5
0.5
5.9
0.5
6.7
0.5
5.9


0.55
3.1
0.55
7.5
0.55
5.9
0.55
6.7
0.55
5.9


0.6
3.1
0.6
7.5
0.6
5.9
0.6
6.6
0.6
5.9


0.65
3.1
0.65
7.5
0.65
5.9
0.65
6.6
0.65
5.9


0.7
3.1
0.7
7.5
0.7
5.9
0.7
6.5
0.7
5.9


0.75
3.1
0.75
7.4
0.75
5.9
0.75
6.3
0.75
5.9


0.8
3.0
0.8
7.0
0.8
5.9
0.8
6.1
0.8
5.6


0.85
2.7
0.85
6.5
0.85
5.8
0.85
5.6
0.85
5.2


0.9
2.4
0.9
5.4
0.9
5.0
0.9
4.7
0.9
4.4


0.95
1.9
0.95
3.8
0.95
3.5
0.95
3.4
0.95
3.1


1
1.2
1
1.2
1
1.2
1
1.2
1
1.2










HF - HCFO-1233xf - HFO-1234yf - HFO-1234zeE - HFO-1234zeZ











Organics
Organics
Organics
Organics
Organics


0.9 F1233xf +
0.033 F1233xf +
0.033 F1233xf +
0.034 F1233xf +
0.25 F1233xf +


0.033 F1234zeE +
0.9 F1234zeE +
0.033 F1234zeE +
0.033 F1234zeE +
0.25 F1234zeE +


0.033 F1234zeZ +
0.033 F1234zeZ +
0.9 F1234zeZ +
0.033 F1234zeZ +
0.25 F1234zeZ +


0.034 F1234yf
0.034 F1234yf
0.034 F1234yf
0.9 F1234yf
0.25 F1234yf

















TOTAL

TOTAL

TOTAL

TOTAL

TOTAL


MASSFRA
PRESSUR
MASSFRA
PRESSUR
MASSFRA
PRESSUR
MASSFRA
PRESSUR
MASSFRA
PRESSURE


HF
bar
HF
bar
HF
bar
HF
bar
HF
bar





0
1.9
0
4.7
0
2.1
0
6.4
0
3.8


0.05
3.0
0.05
5.7
0.05
3.2
0.05
7.4
0.05
4.9


0.1
3.0
0.1
5.7
0.1
3.2
0.1
7.4
0.1
4.9


0.15
3.0
0.15
5.7
0.15
3.2
0.15
7.4
0.15
4.9


0.2
3.0
0.2
5.7
0.2
3.2
0.2
7.4
0.2
4.9


0.25
3.0
0.25
5.7
0.25
3.2
0.25
7.4
0.25
4.9


0.3
3.0
0.3
5.7
0.3
3.2
0.3
7.4
0.3
4.9


0.35
3.0
0.35
5.7
0.35
3.2
0.35
7.4
0.35
4.9


0.4
3.0
0.4
5.7
0.4
3.2
0.4
7.4
0.4
4.9


0.45
3.0
0.45
5.7
0.45
3.2
0.45
7.4
0.45
4.9


0.5
3.0
0.5
5.7
0.5
3.2
0.5
7.4
0.5
4.9


0.55
3.0
0.55
5.6
0.55
3.2
0.55
7.4
0.55
4.9


0.6
3.0
0.6
5.6
0.6
3.2
0.6
7.4
0.6
4.8


0.65
3.0
0.65
5.5
0.65
3.2
0.65
7.4
0.65
4.8


0.7
3.0
0.7
5.3
0.7
3.2
0.7
7.4
0.7
4.8


0.75
2.9
0.75
5.1
0.75
3.1
0.75
7.2
0.75
4.6


0.8
2.8
0.8
4.7
0.8
3.0
0.8
6.9
0.8
4.4


0.85
2.6
0.85
4.3
0.85
2.8
0.85
6.3
0.85
4.0


0.9
2.3
0.9
3.6
0.9
2.4
0.9
5.3
0.9
3.4


0.95
1.8
0.95
2.6
0.95
1.9
0.95
3.7
0.95
2.5


1
1.2
1
1.2
1
1.2
1
1.2
1
1.2










HF - HCFO-1233xf - HFO-1234yf - HFO-1234zeE - HFO-1243zf











Organics
Organics
Organics
Organics
Organics


0.9 F1233xf +
0.033 F1233xf +
0.033 F1233xf +
0.034 F1233xf +
0.25 F1233xf +


0.033 F1234zeE +
0.9 F1234zeE +
0.033 F1234zeE +
0.033 F1234zeE +
0.25 F1234zeE +


0.033 F1243zf +
0.033 F1243zf +
0.9 F1243zf +
0.033 F1243zf +
0.25 F1243zf +


0.034 F1234yf
0.034 F1234yf
0.034 F1234yf
0.9 F1234yf
0.25 F1234yf

















TOTAL

TOTAL

TOTAL

TOTAL

TOTAL


MASSFRA
PRESSUR
MASSFRA
PRESSUR
MASSFRA
PRESSUR
MASSFRA
PRESSUR
MASSFRA
PRESSUR


HF
bar
HF
bar
HF
bar
HF
bar
HF
bar





0
2.1
0
4.9
0
5.7
0
6.5
0
4.9


0.05
3.2
0.05
5.8
0.05
6.7
0.05
7.5
0.05
5.9


0.1
3.2
0.1
5.9
0.1
6.7
0.1
7.5
0.1
5.9


0.15
3.2
0.15
5.9
0.15
6.7
0.15
7.5
0.15
5.9


0.2
3.2
0.2
5.9
0.2
6.7
0.2
7.5
0.2
5.9


0.25
3.2
0.25
5.9
0.25
6.7
0.25
7.5
0.25
5.9


0.3
3.2
0.3
5.9
0.3
6.7
0.3
7.5
0.3
5.9


0.35
3.2
0.35
5.9
0.35
6.7
0.35
7.5
0.35
5.9


0.4
3.1
0.4
5.8
0.4
6.7
0.4
7.5
0.4
5.9


0.45
3.1
0.45
5.8
0.45
6.7
0.45
7.5
0.45
5.9


0.5
3.1
0.5
5.8
0.5
6.7
0.5
7.5
0.5
5.9


0.55
3.1
0.55
5.8
0.55
6.7
0.55
7.5
0.55
5.9


0.6
3.1
0.6
5.7
0.6
6.6
0.6
7.5
0.6
5.9


0.65
3.1
0.65
5.6
0.65
6.6
0.65
7.5
0.65
5.8


0.7
3.1
0.7
5.4
0.7
6.5
0.7
7.5
0.7
5.7


0.75
3.1
0.75
5.2
0.75
6.3
0.75
7.3
0.75
5.6


0.8
2.9
0.8
4.9
0.8
6.0
0.8
7.0
0.8
5.3


0.85
2.7
0.85
4.4
0.85
5.5
0.85
6.4
0.85
4.8


0.9
2.4
0.9
3.6
0.9
4.7
0.9
5.4
0.9
4.0


0.95
1.9
0.95
2.6
0.95
3.3
0.95
3.7
0.95
2.9


1
1.2
1
1.2
1
1.2
1
1.2
1
1.2










HF - HCFO-1233xf - HFO-1234yf - HFO-1234zeE - HCFO-1233zdE











Organics
Organics
Organics
Organics
Organics


0.9 F1233xf +
0.033 F1233xf +
0.033 F1233xf +
0.034 F1233xf +
0.25 F1233xf +


0.033 F1234zeE +
0.9 F1234zeE +
0.033 F1234zeE +
0.033 F1234zeE +
0.25 F1234zeE +


0.033 F1233zdE +
0.033 F1233zdE +
0.9 F1233zdE +
0.033 F1233zdE +
0.25 F1233zdE +


0.034 F1234yf
0.034 F1234yf
0.034 F1234yf
0.9 F1234yf
0.25 F1234yf

















TOTAL

TOTAL

TOTAL

TOTAL

TOTAL


MASSFRAC
PRESSURE
MASSFRAC
PRESSURE
MASSFRAC
PRESSURE
MASSFRAC
PRESSURE
MASSFRAC
PRESSURE


HF
bar
HF
bar
HF
bar
HF
bar
HF
bar





0
1.9
0
4.7
0
1.7
0
6.4
0
3.8


0.05
3.0
0.05
5.7
0.05
2.8
0.05
7.4
0.05
4.8


0.1
3.0
0.1
5.7
0.1
2.8
0.1
7.4
0.1
4.8


0.15
3.0
0.15
5.7
0.15
2.8
0.15
7.4
0.15
4.8


0.2
3.0
0.2
5.7
0.2
2.8
0.2
7.4
0.2
4.8


0.25
3.0
0.25
5.7
0.25
2.8
0.25
7.4
0.25
4.8


0.3
3.0
0.3
5.7
0.3
2.8
0.3
7.4
0.3
4.8


0.35
3.0
0.35
5.7
0.35
2.8
0.35
7.4
0.35
4.8


0.4
3.0
0.4
5.7
0.4
2.8
0.4
7.4
0.4
4.8


0.45
3.0
0.45
5.7
0.45
2.8
0.45
7.4
0.45
4.8


0.5
3.0
0.5
5.7
0.5
2.8
0.5
7.4
0.5
4.8


0.55
3.0
0.55
5.6
0.55
2.8
0.55
7.4
0.55
4.8


0.6
3.0
0.6
5.5
0.6
2.8
0.6
7.4
0.6
4.8


0.65
2.9
0.65
5.4
0.65
2.7
0.65
7.4
0.65
4.8


0.7
2.9
0.7
5.3
0.7
2.7
0.7
7.4
0.7
4.7


0.75
2.9
0.75
5.1
0.75
2.7
0.75
7.2
0.75
4.6


0.8
2.8
0.8
4.7
0.8
2.6
0.8
6.9
0.8
4.3


0.85
2.6
0.85
4.2
0.85
2.4
0.85
6.3
0.85
3.9


0.9
2.3
0.9
3.6
0.9
2.1
0.9
5.3
0.9
3.3


0.95
1.8
0.95
2.6
0.95
1.7
0.95
3.7
0.95
2.4


1
1.2
1
1.2
1
1.2
1
1.2
1
1.2










HF - HCFO-1233xf- HFO-1234yf - HFO-1234zeZ - HFO-1243zf











Organics
Organics
Organics
Organics
Organics


0.9 F1233xf +
0.033 F1233xf +
0.033 F1233xf +
0.034 F1233xf +
0.25 F1233xf +


0.033 F1234zeZ +
0.9 F1234zeZ +
0.033 F1234zeZ +
0.033 F1234zeZ +
0.25 F1234zeZ +


0.033 F1243zf +
0.033 F1243zf +
0.9 F1243zf +
0.033 F1243zf +
0.25 F1243zf +


0.034 F1234yf
0.034 F1234yf
0.034 F1234yf
0.9 F1234yf
0.25 F1234yf

















TOTAL

TOTAL

TOTAL

TOTAL

TOTAL


MASSFRAC
PRESSURE
MASSFRAC
PRESSURE
MASSFRAC
PRESSURE
MASSFRAC
PRESSURE
MASSFRAC
PRESSURE


HF
bar
HF
bar
HF
bar
HF
bar
HF
bar





0
1.9
0
2.1
0
5.6
0
6.4
0
4.1


0.05
3.1
0.05
3.2
0.05
6.6
0.05
7.4
0.05
5.2


0.1
3.1
0.1
3.2
0.1
6.6
0.1
7.4
0.1
5.2


0.15
3.1
0.15
3.2
0.15
6.6
0.15
7.4
0.15
5.2


0.2
3.1
0.2
3.2
0.2
6.6
0.2
7.4
0.2
5.2


0.25
3.1
0.25
3.2
0.25
6.6
0.25
7.4
0.25
5.2


0.3
3.1
0.3
3.2
0.3
6.6
0.3
7.4
0.3
5.2


0.35
3.0
0.35
3.2
0.35
6.6
0.35
7.4
0.35
5.2


0.4
3.0
0.4
3.2
0.4
6.6
0.4
7.4
0.4
5.2


0.45
3.0
0.45
3.2
0.45
6.6
0.45
7.4
0.45
5.2


0.5
3.0
0.5
3.2
0.5
6.6
0.5
7.4
0.5
5.2


0.55
3.0
0.55
3.2
0.55
6.6
0.55
7.4
0.55
5.2


0.6
3.0
0.6
3.2
0.6
6.5
0.6
7.4
0.6
5.2


0.65
3.0
0.65
3.2
0.65
6.5
0.65
7.4
0.65
5.2


0.7
3.0
0.7
3.2
0.7
6.4
0.7
7.4
0.7
5.1


0.75
3.0
0.75
3.2
0.75
6.2
0.75
7.2
0.75
5.0


0.8
2.9
0.8
3.1
0.8
6.0
0.8
6.9
0.8
4.8


0.85
2.6
0.85
2.8
0.85
5.5
0.85
6.3
0.85
4.4


0.9
2.3
0.9
2.5
0.9
4.6
0.9
5.3
0.9
3.7


0.95
1.8
0.95
2.0
0.95
3.3
0.95
3.7
0.95
2.7


1
1.2
1
1.2
1
1.2
1
1.2
1
1.2










HF - HCFO-1233xf - HFO-1234yf - HFO-1234zeZ - HCFO-1233zdE











Organics
Organics
Organics
Organics
Organics


0.9 F1233xf +
0.033 F1233xf +
0.033 F1233xf +
0.034 F1233xf +
0.25 F1233xf +


0.033 F1234zeZ +
0.9 F1234zeZ +
0.033 F1234zeZ +
0.033 F1234zeZ +
0.25 F1234zeZ +


0.033 F1233zdE +
0.033 F1233zdE +
0.9 F1233zdE +
0.033 F1233zdE +
0.25 F1233zdE +


0.034 F1234yf
0.034 F1234yf
0.034 F1234yf
0.9 F1234yf
0.25 F1234yf

















TOTAL

TOTAL

TOTAL

TOTAL

TOTAL


MASSFRA
PRESSURE
MASSFRA
PRESSURE
MASSFRA
PRESSURE
MASSFRA
PRESSURE
MASSFRA
PRESSURE


HF
bar
HF
bar
HF
bar
HF
bar
HF
bar





0
1.8
0
2.0
0
1.6
0
6.3
0
3.0


0.05
2.9
0.05
3.1
0.05
2.7
0.05
7.3
0.05
4.1


0.1
2.9
0.1
3.1
0.1
2.7
0.1
7.3
0.1
4.1


0.15
2.9
0.15
3.1
0.15
2.7
0.15
7.3
0.15
4.1


0.2
2.9
0.2
3.1
0.2
2.7
0.2
7.3
0.2
4.1


0.25
2.9
0.25
3.1
0.25
2.7
0.25
7.3
0.25
4.1


0.3
2.9
0.3
3.1
0.3
2.7
0.3
7.3
0.3
4.1


0.35
2.9
0.35
3.1
0.35
2.7
0.35
7.3
0.35
4.1


0.4
2.9
0.4
3.1
0.4
2.7
0.4
7.3
0.4
4.1


0.45
2.9
0.45
3.1
0.45
2.7
0.45
7.3
0.45
4.1


0.5
2.9
0.5
3.1
0.5
2.7
0.5
7.3
0.5
4.1


0.55
2.9
0.55
3.1
0.55
2.7
0.55
7.3
0.55
4.1


0.6
2.9
0.6
3.1
0.6
2.7
0.6
7.3
0.6
4.1


0.65
2.9
0.65
3.1
0.65
2.7
0.65
7.3
0.65
4.1


0.7
2.9
0.7
3.1
0.7
2.7
0.7
7.3
0.7
4.0


0.75
2.8
0.75
3.1
0.75
2.6
0.75
7.1
0.75
4.0


0.8
2.7
0.8
2.9
0.8
2.5
0.8
6.8
0.8
3.8


0.85
2.5
0.85
2.7
0.85
2.4
0.85
6.2
0.85
3.5


0.9
2.2
0.9
2.4
0.9
2.1
0.9
5.3
0.9
3.0


0.95
1.8
0.95
1.9
0.95
1.7
0.95
3.7
0.95
2.3


1
1.2
1
1.2
1
1.2
1
1.2
1
1.2










HF - HCFO-1233xf - HFO-1234yf - HCFO-1233zdE - HFO-1243zf











Organics
Organics
Organics
Organics
Organics


0.9 F1233xf +
0.033 F1233xf +
0.033 F1233xf +
0.034 F1233xf +
0.25 F1233xf +


0.033 F1243zf +
0.9 F1243zf +
0.033 F1243zf +
0.033 F1243zf +
0.25 F1243zf +


0.033 F1233zdE +
0.033 F1233zdE +
0.9 F1233zdE +
0.033 F1233zdE +
0.25 F1233zdE +


0.034 F1234yf
0.034 F1234yf
0.034 F1234yf
0.9 F1234yf
0.25 F1234yf

















TOTAL

TOTAL

TOTAL

TOTAL

TOTAL


MASSFRAC
PRESSURE
MASSFRAC
PRESSURE
MASSFRAC
PRESSURE
MASSFRAC
PRESSURE
MASSFRAC
PRESSURE


HF
bar
HF
bar
HF
bar
HF
bar
HF
bar





0
1.9
0
5.6
0
1.7
0
6.4
0
4.1


0.05
3.0
0.05
6.6
0.05
2.8
0.05
7.4
0.05
5.2


0.1
3.0
0.1
6.6
0.1
2.8
0.1
7.4
0.1
5.2


0.15
3.0
0.15
6.6
0.15
2.8
0.15
7.4
0.15
5.2


0.2
3.0
0.2
6.6
0.2
2.8
0.2
7.4
0.2
5.2


0.25
3.0
0.25
6.6
0.25
2.8
0.25
7.4
0.25
5.2


0.3
3.0
0.3
6.6
0.3
2.8
0.3
7.4
0.3
5.2


0.35
3.0
0.35
6.6
0.35
2.8
0.35
7.4
0.35
5.2


0.4
3.0
0.4
6.6
0.4
2.8
0.4
7.4
0.4
5.2


0.45
3.0
0.45
6.6
0.45
2.8
0.45
7.4
0.45
5.2


0.5
3.0
0.5
6.6
0.5
2.8
0.5
7.4
0.5
5.1


0.55
3.0
0.55
6.6
0.55
2.8
0.55
7.4
0.55
5.1


0.6
3.0
0.6
6.5
0.6
2.8
0.6
7.4
0.6
5.1


0.65
3.0
0.65
6.5
0.65
2.8
0.65
7.4
0.65
5.1


0.7
3.0
0.7
6.4
0.7
2.8
0.7
7.4
0.7
5.1


0.75
3.0
0.75
6.2
0.75
2.8
0.75
7.2
0.75
4.9


0.8
2.8
0.8
6.0
0.8
2.7
0.8
6.9
0.8
4.7


0.85
2.6
0.85
5.5
0.85
2.5
0.85
6.3
0.85
4.3


0.9
2.3
0.9
4.6
0.9
2.2
0.9
5.3
0.9
3.7


0.95
1.8
0.95
3.3
0.95
1.8
0.95
3.7
0.95
2.7


1
1.2
1
1.2
1
1.2
1
1.2
1
1.2










HF - HCFO-1233xf - HFC-245cb - HFO-1234zeE - HFO-1234yf











Organics
Organics
Organics
Organics
Organics


0.9 F1233xf +
0.033 F1233xf +
0.033 F1233xf +
0.034 F1233xf +
0.25 F1233xf +


0.033 F1234zeE +
0.9 F1234zeE +
0.033 F1234zeE +
0.033 F1234zeE +
0.25 F1234zeE +


0.033 F245cb +
0.033 F245cb +
0.9 F245cb +
0.033 F245cb +
0.25 F245cb +


0.034 F1234yf
0.034 F1234yf
0.034 F1234yf
0.9 F1234yf
0.25 F1234yf

















TOTAL

TOTAL

TOTAL

TOTAL

TOTAL


MASSFRAC
PRESSURE
MASSFRAC
PRESSURE
MASSFRAC
PRESSURE
MASSFRAC
PRESSURE
MASSFRAC
PRESSURE


HF
bar
HF
bar
HF
bar
HF
bar
HF
bar





0
2.0
0
4.8
0
4.6
0
6.5
0
4.6


0.05
3.1
0.05
5.8
0.05
5.8
0.05
7.5
0.05
5.6


0.1
3.1
0.1
5.8
0.1
5.8
0.1
7.5
0.1
5.6


0.15
3.1
0.15
5.8
0.15
5.8
0.15
7.5
0.15
5.6


0.2
3.1
0.2
5.8
0.2
5.8
0.2
7.5
0.2
5.6


0.25
3.1
0.25
5.8
0.25
5.8
0.25
7.5
0.25
5.6


0.3
3.1
0.3
5.8
0.3
5.8
0.3
7.5
0.3
5.6


0.35
3.1
0.35
5.8
0.35
5.8
0.35
7.5
0.35
5.6


0.4
3.1
0.4
5.8
0.4
5.8
0.4
7.5
0.4
5.6


0.45
3.1
0.45
5.8
0.45
5.8
0.45
7.5
0.45
5.6


0.5
3.1
0.5
5.8
0.5
5.8
0.5
7.5
0.5
5.6


0.55
3.1
0.55
5.7
0.55
5.8
0.55
7.5
0.55
5.6


0.6
3.1
0.6
5.7
0.6
5.8
0.6
7.5
0.6
5.6


0.65
3.1
0.65
5.6
0.65
5.8
0.65
7.5
0.65
5.7


0.7
3.1
0.7
5.4
0.7
5.8
0.7
7.5
0.7
5.7


0.75
3.1
0.75
5.2
0.75
5.8
0.75
7.3
0.75
5.5


0.8
2.9
0.8
4.9
0.8
5.8
0.8
7.0
0.8
5.3


0.85
2.7
0.85
4.4
0.85
5.7
0.85
6.4
0.85
4.8


0.9
2.4
0.9
3.7
0.9
4.9
0.9
5.4
0.9
4.1


0.95
1.9
0.95
2.6
0.95
3.5
0.95
3.7
0.95
2.9


1
1.2
1
1.2
1
1.2
1
1.2
1
1.2










HF - HCFO-1233xf - HFC-245cb - HCFO-1233zdE - HFO-1234yf











Organics
Organics
Organics
Organics
Organics


0.9 F1233xf +
0.033 F1233xf +
0.033 F1233xf +
0.034 F1233xf +
0.25 F1233xf +


0.033 F1233zdE +
0.9 F1233zdE +
0.033 F1233zdE +
0.033 F1233zdE +
0.25 F1233zdE +


0.033 F245cb +
0.033 F245cb +
0.9 F245cb +
0.033 F245cb +
0.25 F245cb +


0.034 F1234yf
0.034 F1234yf
0.034 F1234yf
0.9 F1234yf
0.25 F1234yf

















TOTAL

TOTAL

TOTAL

TOTAL

TOTAL


MASSFRA
PRESSUR
MASSFRA
PRESSUR
MASSFRA
PRESSUR
MASSFRA
PRESSUR
MASSFRA
PRESSUR


HF
bar
HF
bar
HF
bar
HF
bar
HF
bar





0
1.9
0
1.7
0
4.5
0
6.4
0
3.7


0.05
3.0
0.05
2.8
0.05
5.7
0.05
7.4
0.05
4.8


0.1
3.0
0.1
2.8
0.1
5.7
0.1
7.4
0.1
4.8


0.15
3.0
0.15
2.8
0.15
5.7
0.15
7.4
0.15
4.8


0.2
3.0
0.2
2.8
0.2
5.7
0.2
7.4
0.2
4.8


0.25
3.0
0.25
2.8
0.25
5.7
0.25
7.4
0.25
4.8


0.3
3.0
0.3
2.8
0.3
5.7
0.3
7.4
0.3
4.8


0.35
3.0
0.35
2.8
0.35
5.7
0.35
7.4
0.35
4.8


0.4
3.0
0.4
2.8
0.4
5.7
0.4
7.4
0.4
4.8


0.45
3.0
0.45
2.8
0.45
5.7
0.45
7.4
0.45
4.8


0.5
3.0
0.5
2.8
0.5
5.7
0.5
7.4
0.5
4.8


0.55
3.0
0.55
2.8
0.55
5.7
0.55
7.4
0.55
4.8


0.6
3.0
0.6
2.8
0.6
5.7
0.6
7.4
0.6
4.8


0.65
3.0
0.65
2.8
0.65
5.7
0.65
7.4
0.65
4.9


0.7
3.0
0.7
2.8
0.7
5.7
0.7
7.4
0.7
4.9


0.75
3.0
0.75
2.8
0.75
5.7
0.75
7.2
0.75
4.9


0.8
2.8
0.8
2.7
0.8
5.7
0.8
6.9
0.8
4.7


0.85
2.6
0.85
2.5
0.85
5.7
0.85
6.4
0.85
4.3


0.9
2.3
0.9
2.2
0.9
4.9
0.9
5.4
0.9
3.7


0.95
1.8
0.95
1.8
0.95
3.5
0.95
3.7
0.95
2.7


1
1.2
1
1.2
1
1.2
1
1.2
1
1.2










HF - HCFO-1233xf - HFC-245cb - HFO-1234zeZ - HFO-1234yf











Organics
Organics
Organics
Organics
Organics


0.9 F1233xf +
0.033 F1233xf +
0.033 F1233xf +
0.034 F1233xf +
0.25 F1233xf +


0.033 F1234zeZ +
0.9 F1234zeZ +
0.033 F1234zeZ +
0.033 F1234zeZ +
0.25 F1234zeZ +


0.033 F245cb +
0.033 F245cb +
0.9 F245cb +
0.033 F245cb +
0.25 F245cb +


0.034 F1234yf
0.034 F1234yf
0.034 F1234yf
0.9 F1234yf
0.25 F1234yf

















TOTAL

TOTAL

TOTAL

TOTAL

TOTAL


MASSFRAC
PRESSURE
MASSFRAC
PRESSURE
MASSFRAC
PRESSURE
MASSFRAC
PRESSURE
MASSFRAC
PRESSURE


HF
bar
HF
bar
HF
bar
HF
bar
HF
bar





0
1.9
0
2.1
0
4.5
0
6.4
0
3.7


0.05
3.0
0.05
3.2
0.05
5.7
0.05
7.4
0.05
4.9


0.1
3.0
0.1
3.2
0.1
5.7
0.1
7.4
0.1
4.9


0.15
3.0
0.15
3.2
0.15
5.7
0.15
7.4
0.15
4.9


0.2
3.0
0.2
3.2
0.2
5.7
0.2
7.4
0.2
4.9


0.25
3.0
0.25
3.2
0.25
5.7
0.25
7.4
0.25
4.9


0.3
3.0
0.3
3.2
0.3
5.7
0.3
7.4
0.3
4.9


0.35
3.0
0.35
3.2
0.35
5.7
0.35
7.4
0.35
4.9


0.4
3.0
0.4
3.2
0.4
5.7
0.4
7.4
0.4
4.9


0.45
3.0
0.45
3.2
0.45
5.7
0.45
7.4
0.45
4.9


0.5
3.0
0.5
3.2
0.5
5.7
0.5
7.4
0.5
4.9


0.55
3.0
0.55
3.2
0.55
5.7
0.55
7.4
0.55
4.9


0.6
3.0
0.6
3.2
0.6
5.7
0.6
7.4
0.6
4.9


0.65
3.0
0.65
3.2
0.65
5.7
0.65
7.4
0.65
4.9


0.7
3.0
0.7
3.2
0.7
5.7
0.7
7.4
0.7
4.9


0.75
3.0
0.75
3.2
0.75
5.7
0.75
7.2
0.75
5.0


0.8
2.8
0.8
3.0
0.8
5.7
0.8
6.9
0.8
4.8


0.85
2.6
0.85
2.8
0.85
5.7
0.85
6.4
0.85
4.4


0.9
2.3
0.9
2.5
0.9
4.9
0.9
5.4
0.9
3.8


0.95
1.8
0.95
2.0
0.95
3.5
0.95
3.7
0.95
2.7


1
1.2
1
1.2
1
1.2
1
1.2
1
1.2









Example 8: Temperature and Pressure Range of Penternary Mixtures













Boiling point range










Tem-




perature
Pressure


System with 5 compounds
° C.
bar abs





HF - HCFO-1233xf - HFC-245cb - HCFO-
0 to 40
~1.0 ~8.9


1233zdE - HFO-1234zeE


HF - HCFO-1233xf - HFC-245cb - HCFO-
0 to 40
~1.0 to ~8.8


1233zdE - HFO-1234zeZ


HF - HCFO-1233xf - HFC-245cb - HCFO-
0 to 40
~1.0 to ~10.0


1233zdE - HFO-1243zf


HF - HCFO-1233xf - HFC-245cb - HCFO-
0 to 40
~1.0 to ~11.2


1233zdE - HFO-1234yf


HF - HCFO-1233xf - HFC-245cb - HFO-
0 to 40
~1.1 to ~8.8


1234zeE - HFO-1234zeZ


HF - HCFO-1233xf - HFC-245cb - HFO-
0 to 40
~1.0 to ~10.2


1234zeE - HFO-1243zf


HF - HCFO-1233xf - HFC-245cb - HFO-
0 to 40
~1.0 to ~11.4


1234zeE - HFO-1234yf


HF - HCFO-1233xf - HFC-245cb - HFO-
0 to 40
~1.1 to ~10.1


1234zeZ - HFO-1243zf


HF - HCFO-1233xf - HFC-245cb - HFO-
0 to 40
~1.1 to ~11.2


1234zeZ - HFO-1234yf


HF - HCFO-1233xf - HFC-245cb - HFO-
0 to 40
~1.2 to ~11.4


1234yf - HFO-1243zf


HF - HCFO-1233xf - HFO-1234yf - HFO-
0 to 40
~1.1 to ~11.2


1234zeE - HFO-1234zeZ


HF - HCFO-1233xf - HFO-1234yf - HFO-
0 to 40
~1.2 to ~11.4


1234zeE - HFO-1243zf


HF - HCFO-1233xf - HFO-1234yf - HFO-
0 to 40
~1.0 to ~11.2


1234zeE-HCFO-1233zdE


HF - HCFO-1233xf - HFO-1234yf - HFO-
0 to 40
~1.2 to ~11.2


1234zeZ - HFO-1243zf


HF - HCFO-1233xf - HFO-1234yf - HFO-
0 to 40
~1.0 ~11.1


1234zeZ-HCFO-1233zdE


HF - HCFO-1233xf - HFO-1234yf - HCFO-
0 to 40
~1.0 ~11.2


1233zdE - HFO-1243zf


HF - HCFO-1233xf - HCFO-1233zdE - HFO-
0 to 40
~0.9 to ~8.6


1234zeE - HFO-1234zeZ


HF - HCFO-1233xf - HCFO-1233zdE - HFO-
0 to 40
~1.0 to ~10.1


1234zeE - HFO-1243zf


HF - HCFO-1233xf - HCFO-1233zdE - HFO-
0 to 40
~1.0 to ~9.9


1234zeZ - HFO-1243zf


HF - HCFO-1233xf - HFO-1234zeE - HFO-
0 to 40
~1.0 to ~10.1


1234zeZ - HFO-1243zf









Example 9: Decantation Range of Penternary Mixtures













Decantation ranges



Mass percentage of HF











Iso-
Iso-
Iso-



therm
therm
therm


System with 5 compounds
0° C.
25° C.
40° C.





HF - HCFO-1233xf - HFC-245cb - HCFO-
5-75
5-70
10-60


1233zdE-HFO-1234zeE


HF - HCFO-1233xf - HFC-245cb - HCFO-
5-80
5-75
 5-70


1233zdE - HFO-1234zeZ


HF - HCFO-1233xf - HFC-245cb - HCFO-
5-75
5-70
 5-65


1233zdE-HFO-1243zf


HF - HCFO-1233xf - HFC-245cb - HCFO-
5-75
5-75
10-65


1233zdE - HFO-1234yf


HF - HCFO-1233xf - HFC-245cb - HFO-
5-75
5-70
10-60


1234zeE - HFO-1234zeZ


HF - HCFO-1233xf - HFC-245cb - HFO-
10-75 
10-65 
*


1234zeE - HFO-1243zf


HF - HCFO-1233xf - HFC-245cb - HFO-
5-75
10-70 
*


1234zeE - HFO-1234yf


HF - HCFO-1233xf - HFC-245cb - HFO-
5-75
5-70
10-60


1234zeZ - HFO-1243zf


HF - HCFO-1233xf - HFC-245cb - HFO-
5-75
5-75
10-65


1234zeZ - HFO-1234yf


HF - HCFO-1233xf - HFC-245cb - HFO-
5-75
10-70 
*


1234yf - HFO-1243zf


HF - HCFO-1233xf - HFO-1234yf - HFO-
5-75
5-65
15-45


1234zeE - HFO-1234zeZ


HF - HCFO-1233xf - HFO-1234yf - HFO-
5-70
10-60 
*


1234zeE - HFO-1243zf


HF - HCFO-1233xf - HFO-1234yf - HFO-
5-75
5-65
10-50


1234zeE - HCFO-1233zdE


HF - HCFO-1233xf - HFO-1234yf - HFO-
5-75
10-65 
20-40


1234zeZ - HFO-1243zf


HF - HCFO-1233xf - HFO-1234yf - HFO-
5-75
5-70
10-60


1234zeZ - HCFO-1233zdE


HF - HCFO-1233xf - HFO-1234yf - HCFO-
5-75
5-65
15-45


1233zdE - HFO-1243zf


HF - HCFO-1233xf - HCFO-1233zdE -
5-75
5-70
 5-60


HFO-1234zeE - HFO-1234zeZ


HF - HCFO-1233xf - HCFO-1233zdE -
5-75
5-65
15-45


HFO-1234zeE - HFO-1243zf


HF - HCFO-1233xf - HCFO-1233zdE -
5-75
5-70
10-60


HFO- 1234zeZ - HFO-1243zf


HF - HCFO-1233xf - HFO-1234zeE - HFO-
5-75
10-65 
15-40


1234zeZ - HFO-1243zf









Example 10: Systems with Six Compounds, Isotherm at 25° C.












HF - HCFO-1233xf - HFO-1234yf - HFC-245cb - HFO-1234zeE- HFO-1234zeZ












Organics 0.2 F1233xf + 0.2
Organics 0.96 F1233xf + 0.01
Organics 0.01 F1233xf + 0.96
Organics 0.01 F1233xf + 0.01
Organics 0.01 F1233xf + 0.01
Organics 0.01 F1233xf + 0.01


F1234yf + 0.2 F245cb 0.2
F1234yf + 0.01 F245cb + 0.01
F1234yf + 0.01 F245cb + 0.01
F1234yf + 0.96 F245cb + 0.01
F1234yf + 0.01 F245cb + 0.96
F1234yf + 0.01 F245cb + 0.01


F1234zeE + 0.2
F1234zeE + 0.01
F1234zeE + 0.01
F1234zeE + 0.01
F1234zeE + 0.01
F1234zeE + 0.96


F1234zeZ
F1234zeZ
F1234zeZ
F1234zeZ
F1234zeZ
F1234zeZ



















TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL


MASSFR
PRESSU
MASSFR
PRESSU
MASSFR
PRESSU
MASSFR
PRESSU
MASSFR
PRESSU
MASSFR
PRESSU


HF
bar
HF
bar
HF
bar
HF
bar
HF
bar
HF
bar





0
4.0
0
1.7
0
6.7
0
4.6
0
4.8
0
1.9


0.05
5.1
0.05
2.8
0.05
7.6
0.05
5.8
0.05
5.8
0.05
3.0


0.1
5.1
0.1
2.8
0.1
7.6
0.1
5.8
0.1
5.8
0.1
3.0


0.15
5.1
0.15
2.8
0.15
7.6
0.15
5.8
0.15
5.8
0.15
3.0


0.2
5.1
0.2
2.8
0.2
7.6
0.2
5.8
0.2
5.8
0.2
3.0


0.25
5.1
0.25
2.8
0.25
7.6
0.25
5.8
0.25
5.8
0.25
3.0


0.3
5.1
0.3
2.8
0.3
7.6
0.3
5.8
0.3
5.8
0.3
3.0


0.35
5.1
0.35
2.8
0.35
7.6
0.35
5.8
0.35
5.8
0.35
3.0


0.4
5.1
0.4
2.8
0.4
7.6
0.4
5.8
0.4
5.8
0.4
3.0


0.45
5.1
0.45
2.8
0.45
7.6
0.45
5.8
0.45
5.8
0.45
3.0


0.5
5.1
0.5
2.8
0.5
7.6
0.5
5.8
0.5
5.7
0.5
3.0


0.55
5.1
0.55
2.8
0.55
7.6
0.55
5.8
0.55
5.7
0.55
3.0


0.6
5.1
0.6
2.8
0.6
7.6
0.6
5.8
0.6
5.6
0.6
3.0


0.65
5.1
0.65
2.8
0.65
7.6
0.65
5.8
0.65
5.5
0.65
3.0


0.7
5.1
0.7
2.8
0.7
7.6
0.7
5.8
0.7
5.4
0.7
3.0


0.75
5.0
0.75
2.8
0.75
7.5
0.75
5.8
0.75
5.1
0.75
3.0


0.8
4.8
0.8
2.6
0.8
7.1
0.8
5.8
0.8
4.8
0.8
2.9


0.85
4.4
0.85
2.5
0.85
6.5
0.85
5.8
0.85
4.3
0.85
2.7


0.9
3.7
0.9
2.2
0.9
5.5
0.9
5.0
0.9
3.6
0.9
2.4


0.95
2.7
0.95
1.8
0.95
3.8
0.95
3.5
0.95
2.6
0.95
1.9


1
1.2
1
1.2
1
1.2
1
1.2
1
1.2
1
1.2










HF - HCFO-1233xf - HFO-1234yf - HFC-245cb - HFO-1234zeE- HCFO-1233zdE












Organics 0.2 F1233xf + 0.2
Organics 0.96 F1233xf + 0.01
Organics 0.01 F1233xf + 0.96
Organics 0.01 F1233xf + 0.01
Organics 0.01 F1233xf + 0.01
Organics 0.01 F1233xf + 0.01


F1234yf + 0.2 F245cb 0.2
F1234yf + 0.01 F245cb + 0.01
F1234yf + 0.01 F245cb + 0.01
F1234yf + 0.96 F245cb + 0.01
F1234yf + 0.01 F245cb + 0.96
F1234yf + 0.01 F245cb + 0.01


F1234zeE + 0.2
F1234zeE + 0.01
F1234zeE + 0.01
F1234zeE + 0.01
F1234zeE + 0.01
F1234zeE + 0.96


F1233zdE
F1233zdE
F1233zdE
F1233zdE
F1233zdE
F1233zdE



















TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL


MASSFR
PRESSU
MASSFR
PRESSU
MASSFR
PRESSU
MASSFR
PRESSU
MASSFR
PRESSU
MASSFR
PRESSU


HF
bar
HF
bar
HF
bar
HF
bar
HF
bar
HF
bar





0
3.9
0
1.7
0
6.7
0
4.6
0
4.8
0
1.5


0.05
5.0
0.05
2.8
0.05
7.6
0.05
5.8
0.05
5.8
0.05
2.6


0.1
5.0
0.1
2.8
0.1
7.6
0.1
5.8
0.1
5.8
0.1
2.6


0.15
5.0
0.15
2.8
0.15
7.6
0.15
5.8
0.15
5.8
0.15
2.6


0.2
5.0
0.2
2.8
0.2
7.6
0.2
5.8
0.2
5.8
0.2
2.6


0.25
5.0
0.25
2.8
0.25
7.6
0.25
5.8
0.25
5.8
0.25
2.6


0.3
5.0
0.3
2.8
0.3
7.6
0.3
5.8
0.3
5.8
0.3
2.6


0.35
5.0
0.35
2.8
0.35
7.6
0.35
5.8
0.35
5.8
0.35
2.6


0.4
5.0
0.4
2.8
0.4
7.6
0.4
5.8
0.4
5.8
0.4
2.6


0.45
5.0
0.45
2.8
0.45
7.6
0.45
5.8
0.45
5.8
0.45
2.6


0.5
5.0
0.5
2.8
0.5
7.6
0.5
5.8
0.5
5.7
0.5
2.6


0.55
5.0
0.55
2.8
0.55
7.6
0.55
5.8
0.55
5.7
0.55
2.6


0.6
5.0
0.6
2.8
0.6
7.6
0.6
5.8
0.6
5.6
0.6
2.6


0.65
5.0
0.65
2.8
0.65
7.6
0.65
5.8
0.65
5.5
0.65
2.6


0.7
5.1
0.7
2.8
0.7
7.6
0.7
5.8
0.7
5.4
0.7
2.6


0.75
5.0
0.75
2.8
0.75
7.5
0.75
5.8
0.75
5.1
0.75
2.6


0.8
4.7
0.8
2.6
0.8
7.1
0.8
5.8
0.8
4.8
0.8
2.4


0.85
4.3
0.85
2.5
0.85
6.5
0.85
5.8
0.85
4.3
0.85
2.3


0.9
3.7
0.9
2.2
0.9
5.5
0.9
5.0
0.9
3.6
0.9
2.0


0.95
2.7
0.95
1.8
0.95
3.8
0.95
3.5
0.95
2.6
0.95
1.7


1
1.2
1
1.2
1
1.2
1
1.2
1
1.2
1
1.2










HF - HCFO-1233xf - HFO-1234yf - HFC-245cb - HFO-1234zeE- HFO-1243zf












Organics
Organics
Organics
Organics
Organics
Organics


0.2 F1233xf + 0.2
0.96 F1233xf + 0.01
0.01 F1233xf + 0.96
0.01 F1233xf + 0.01
0.01 F1233xf + 0.01
0.01 F1233xf + 0.01


F1234yf + 0.2 F245cb 0.2
F1234yf + 0.01 F245cb + 0.01
F1234yf + 0.01 F245cb + 0.01
F1234yf + 0.96 F245cb + 0.01
F1234yf + 0.01 F245cb + 0.96
F1234yf + 0.01 F245cb + 0.01


F1234zeE + 0.2
F1234zeE + 0.01
F1234zeE + 0.01
F1234zeE + 0.01
F1234zeE + 0.01
F1234zeE + 0.96


F1243zf
F1243zf
F1243zf
F1243zf
F1243zf
F1243zf



















TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL


MASSFRA
PRESSUR
MASSFRA
PRESSUR
MASSFRA
PRESSUR
MASSFRA
PRESSUR
MASSFRA
PRESSUR
MASSFRA
PRESSUR


HF
bar
HF
bar
HF
bar
HF
bar
HF
bar
HF
bar





0
4.9
0
1.7
0
6.7
0
4.7
0
4.9
0
5.8


0.05
5.9
0.05
2.8
0.05
7.7
0.05
5.8
0.05
5.8
0.05
6.7


0.1
5.9
0.1
2.8
0.1
7.7
0.1
5.8
0.1
5.9
0.1
6.8


0.15
5.9
0.15
2.8
0.15
7.7
0.15
5.8
0.15
5.8
0.15
6.8


0.2
5.9
0.2
2.8
0.2
7.7
0.2
5.8
0.2
5.8
0.2
6.8


0.25
5.9
0.25
2.8
0.25
7.7
0.25
5.8
0.25
5.8
0.25
6.8


0.3
5.9
0.3
2.8
0.3
7.7
0.3
5.8
0.3
5.8
0.3
6.8


0.35
5.9
0.35
2.8
0.35
7.7
0.35
5.8
0.35
5.8
0.35
6.8


0.4
5.9
0.4
2.8
0.4
7.7
0.4
5.8
0.4
5.8
0.4
6.8


0.45
5.9
0.45
2.8
0.45
7.7
0.45
5.8
0.45
5.8
0.45
6.7


0.5
5.9
0.5
2.8
0.5
7.7
0.5
5.8
0.5
5.8
0.5
6.7


0.55
5.9
0.55
2.8
0.55
7.7
0.55
5.8
0.55
5.7
0.55
6.7


0.6
5.9
0.6
2.8
0.6
7.7
0.6
5.8
0.6
5.7
0.6
6.7


0.65
5.9
0.65
2.8
0.65
7.7
0.65
5.8
0.65
5.6
0.65
6.6


0.7
5.9
0.7
2.8
0.7
7.6
0.7
5.8
0.7
5.4
0.7
6.5


0.75
5.7
0.75
2.8
0.75
7.5
0.75
5.8
0.75
5.2
0.75
6.4


0.8
5.5
0.8
2.7
0.8
7.2
0.8
5.8
0.8
4.8
0.8
6.1


0.85
5.0
0.85
2.5
0.85
6.6
0.85
5.8
0.85
4.3
0.85
5.6


0.9
4.2
0.9
2.2
0.9
5.5
0.9
5.0
0.9
3.6
0.9
4.8


0.95
3.0
0.95
1.8
0.95
3.8
0.95
3.5
0.95
2.6
0.95
3.4


1
1.2
1
1.2
1
1.2
1
1.2
1
1.2
1
1.2










HF - HCFO-1233xf - HFO-1234yf - HFC-245cb - HFO-1234zeZ- HCFO-1233zdE












Organics
Organics
Organics
Organics
Organics
Organics


0.2 F1233xf + 0.2
0.96 F1233xf + 0.01
0.01 F1233xf + 0.96
0.01 F1233xf + 0.01
0.01 F1233xf + 0.01
0.01 F1233xf + 0.01


F1234yf + 0.2 F245cb 0.2
F1234yf + 0.01 F245cb + 0.01
F1234yf + 0.01 F245cb + 0.01
F1234yf + 0.96 F245cb + 0.01
F1234yf + 0.01 F245cb + 0.96
F1234yf + 0.01 F245cb + 0.01


F1234zeZ + 0.2
F1234zeZ + 0.01
F1234zeZ + 0.01
F1234zeZ + 0.01
F1234zeZ + 0.01
F1234zeZ + 0.96


F1233zdE
F1233zdE
F1233zdE
F1233zdE
F1233zdE
F1233zdE



















TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL


MASSFR
PRESSU
MASSFR
PRESSU
MASSFR
PRESSU
MASSFR
PRESSU
MASSFR
PRESSU
MASSFR
PRESSU


HF
bar
HF
bar
HF
bar
HF
bar
HF
bar
HF
bar





0
3.3
0
1.6
0
6.6
0
4.6
0
1.9
0
1.4


0.05
4.4
0.05
2.8
0.05
7.6
0.05
5.8
0.05
3.0
0.05
2.5


0.1
4.4
0.1
2.8
0.1
7.6
0.1
5.8
0.1
3.0
0.1
2.5


0.15
4.4
0.15
2.8
0.15
7.6
0.15
5.8
0.15
3.0
0.15
2.5


0.2
4.4
0.2
2.8
0.2
7.6
0.2
5.8
0.2
3.0
0.2
2.5


0.25
4.4
0.25
2.8
0.25
7.6
0.25
5.8
0.25
3.0
0.25
2.5


0.3
4.4
0.3
2.8
0.3
7.6
0.3
5.8
0.3
3.0
0.3
2.5


0.35
4.4
0.35
2.8
0.35
7.6
0.35
5.8
0.35
3.0
0.35
2.5


0.4
4.4
0.4
2.8
0.4
7.6
0.4
5.8
0.4
3.0
0.4
2.5


0.45
4.4
0.45
2.8
0.45
7.6
0.45
5.8
0.45
3.0
0.45
2.5


0.5
4.4
0.5
2.8
0.5
7.6
0.5
5.8
0.5
3.0
0.5
2.5


0.55
4.4
0.55
2.8
0.55
7.6
0.55
5.8
0.55
3.0
0.55
2.5


0.6
4.4
0.6
2.8
0.6
7.6
0.6
5.8
0.6
3.0
0.6
2.5


0.65
4.5
0.65
2.8
0.65
7.6
0.65
5.8
0.65
3.0
0.65
2.5


0.7
4.5
0.7
2.8
0.7
7.6
0.7
5.8
0.7
3.0
0.7
2.5


0.75
4.5
0.75
2.8
0.75
7.4
0.75
5.8
0.75
3.0
0.75
2.5


0.8
4.3
0.8
2.6
0.8
7.1
0.8
5.8
0.8
2.9
0.8
2.4


0.85
4.0
0.85
2.4
0.85
6.5
0.85
5.8
0.85
2.7
0.85
2.3


0.9
3.4
0.9
2.2
0.9
5.5
0.9
5.0
0.9
2.3
0.9
2.0


0.95
2.5
0.95
1.7
0.95
3.8
0.95
3.5
0.95
1.9
0.95
1.7


1
1.2
1
1.2
1
1.2
1
1.2
1
1.2
1
1.2










HF - HCFO-1233xf - HFO-1234yf - HFC-245cb - HFO-1234zeZ- HFO-1243zf












Organics
Organics
Organics
Organics
Organics
Organics


0.2 F1233xf + 0.2
0.96 F1233xf + 0.01
0.01 F1233xf + 0.96
0.01 F1233xf + 0.01
0.01 F1233xf + 0.01
0.01 F1233xf + 0.01


F1234yf + 0.2 F245cb 0.2
F1234yf + 0.01 F245cb + 0.01
F1234yf + 0.01 F245cb + 0.01
F1234yf + 0.96 F245cb + 0.01
F1234yf + 0.01 F245cb + 0.96
F1234yf + 0.01 F245cb + 0.01


F1234zeZ + 0.2
F1234zeZ + 0.01
F1234zeZ + 0.01
F1234zeZ + 0.01
F1234zeZ + 0.01
F1234zeZ +


F1243zf
F1243zf
F1243zf
F1243zf
F1243zf
0.96 F1243zf



















TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL


MASSFRA
PRESSUR
MASSFRA
PRESSUR
MASSFRA
PRESSUR
MASSFRA
PRESSUR
MASSFRA
PRESSUR
MASSFRA
PRESSUR


HF
bar
HF
bar
HF
bar
HF
bar
HF
bar
HF
bar





0
4.2
0
1.7
0
6.7
0
4.6
0
1.9
0
5.8


0.05
5.3
0.05
2.8
0.05
7.6
0.05
5.8
0.05
3.0
0.05
6.7


0.1
5.3
0.1
2.8
0.1
7.7
0.1
5.8
0.1
3.0
0.1
6.8


0.15
5.3
0.15
2.8
0.15
7.6
0.15
5.8
0.15
3.0
0.15
6.7


0.2
5.3
0.2
2.8
0.2
7.6
0.2
5.8
0.2
3.0
0.2
6.7


0.25
5.3
0.25
2.8
0.25
7.6
0.25
5.8
0.25
3.0
0.25
6.7


0.3
5.3
0.3
2.8
0.3
7.6
0.3
5.8
0.3
3.0
0.3
6.7


0.35
5.3
0.35
2.8
0.35
7.6
0.35
5.8
0.35
3.0
0.35
6.7


0.4
5.3
0.4
2.8
0.4
7.6
0.4
5.8
0.4
3.0
0.4
6.7


0.45
5.3
0.45
2.8
0.45
7.6
0.45
5.8
0.45
3.0
0.45
6.7


0.5
5.3
0.5
2.8
0.5
7.6
0.5
5.8
0.5
3.0
0.5
6.7


0.55
5.3
0.55
2.8
0.55
7.6
0.55
5.8
0.55
3.0
0.55
6.7


0.6
5.3
0.6
2.8
0.6
7.6
0.6
5.8
0.6
3.0
0.6
6.7


0.65
5.3
0.65
2.8
0.65
7.6
0.65
5.8
0.65
3.0
0.65
6.6


0.7
5.3
0.7
2.8
0.7
7.6
0.7
5.8
0.7
3.0
0.7
6.5


0.75
5.3
0.75
2.8
0.75
7.5
0.75
5.8
0.75
3.0
0.75
6.4


0.8
5.1
0.8
2.7
0.8
7.2
0.8
5.8
0.8
2.9
0.8
6.1


0.85
4.7
0.85
2.5
0.85
6.6
0.85
5.8
0.85
2.7
0.85
5.6


0.9
4.0
0.9
2.2
0.9
5.5
0.9
5.0
0.9
2.4
0.9
4.7


0.95
2.9
0.95
1.8
0.95
3.8
0.95
3.5
0.95
1.9
0.95
3.4


1
1.2
1
1.2
1
1.2
1
1.2
1
1.2
1
1.2










HF - HCFO-1233xf - HFO-1234yf - HFC-245cb - HCFO-1233zdE- HFO-1243zf












Organics
Organics
Organics
Organics
Organics
Organics


0.2 F1233xf + 0.2
0.96 F1233xf + 0.01
0.01 F1233xf + 0.96
0.01 F1233xf + 0.01
0.01 F1233xf + 0.01
0.01 F1233xf + 0.01


F1234yf + 0.2 F245cb 0.2
F1234yf + 0.01 F245cb + 0.01
F1234yf + 0.01 F245cb + 0.01
F1234yf + 0.96 F245cb + 0.01
F1234yf + 0.01 F245cb + 0.96
F1234yf + 0.01 F245cb + 0.01


F1233zdE + 0.2
F1233zdE + 0.01
F1233zdE + 0.01
F1233zdE + 0.01
F1233zdE + 0.01
F1233zdE + 0.96


F1243zf
F1243zf
F1243zf
F1243zf
F1243zf
F1243zf



















TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL


MASSFR
PRESSU
MASSFR
PRESSU
MASSFR
PRESSU
MASSFR
PRESSU
MASSFR
PRESSU
MASSFR
PRESSU


HF
bar
HF
bar
HF
bar
HF
bar
HF
bar
HF
bar





0
4.2
0
1.7
0
6.7
0
4.6
0
1.5
0
5.8


0.05
5.3
0.05
2.8
0.05
7.6
0.05
5.8
0.05
2.6
0.05
6.7


0.1
5.3
0.1
2.8
0.1
7.7
0.1
5.8
0.1
2.6
0.1
6.8


0.15
5.3
0.15
2.8
0.15
7.6
0.15
5.8
0.15
2.6
0.15
6.7


0.2
5.3
0.2
2.8
0.2
7.6
0.2
5.8
0.2
2.6
0.2
6.7


0.25
5.3
0.25
2.8
0.25
7.6
0.25
5.8
0.25
2.6
0.25
6.7


0.3
5.3
0.3
2.8
0.3
7.6
0.3
5.8
0.3
2.6
0.3
6.7


0.35
5.3
0.35
2.8
0.35
7.6
0.35
5.8
0.35
2.6
0.35
6.7


0.4
5.3
0.4
2.8
0.4
7.6
0.4
5.8
0.4
2.6
0.4
6.7


0.45
5.3
0.45
2.8
0.45
7.6
0.45
5.8
0.45
2.6
0.45
6.7


0.5
5.3
0.5
2.8
0.5
7.6
0.5
5.8
0.5
2.6
0.5
6.7


0.55
5.3
0.55
2.8
0.55
7.6
0.55
5.8
0.55
2.6
0.55
6.7


0.6
5.3
0.6
2.8
0.6
7.6
0.6
5.8
0.6
2.6
0.6
6.7


0.65
5.3
0.65
2.8
0.65
7.6
0.65
5.8
0.65
2.6
0.65
6.6


0.7
5.3
0.7
2.8
0.7
7.6
0.7
5.8
0.7
2.6
0.7
6.5


0.75
5.2
0.75
2.8
0.75
7.5
0.75
5.8
0.75
2.6
0.75
6.4


0.8
5.0
0.8
2.7
0.8
7.2
0.8
5.8
0.8
2.5
0.8
6.1


0.85
4.6
0.85
2.5
0.85
6.6
0.85
5.8
0.85
2.3
0.85
5.6


0.9
3.9
0.9
2.2
0.9
5.5
0.9
5.0
0.9
2.0
0.9
4.7


0.95
2.8
0.95
1.8
0.95
3.8
0.95
3.5
0.95
1.7
0.95
3.4


1
1.2
1
1.2
1
1.2
1
1.2
1
1.2
1
1.2










HF - HCFO-1233xf - HFO-1234yf - HFO-1234zeE - HFO-1234zeZ - HCFO-1233zdE












Organics 0.2 F1233xf + 0.2
Organics 0.96 F1233xf + 0.01
Organics 0.01 F1233xf + 0.96
Organics 0.01 F1233xf + 0.01
Organics 0.01 F1233xf + 0.01
Organics 0.01 F1233xf + 0.01


F1234yf + 0.2 F1233zdE 0.2
F1234yf + 0.01 F1233zdE +
F1234yf + 0.01 F1233zdE +
F1234yf + 0.96 F1233zdE +
F1234yf + 0.01 F1233zdE +
F1234yf + 0.01 F1233zdE +


F1234zeE + 0.2
0.01 F1234zeE +
0.01 F1234zeE +
0.01 F1234zeE +
0.96 F1234zeE +
0.01 F1234zeE +


F1234zeZ
0.01 F1234zeZ
0.01 F1234zeZ
0.01 F1234zeZ
0.01 F1234zeZ
0.96 F1234zeZ



















TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL


MASSFRA
PRESSUR
MASSFRA
PRESSUR
MASSFRA
PRESSUR
MASSFRA
PRESSUR
MASSFRA
PRESSUR
MASSFRA
PRESSUR


HF
bar
HF
bar
HF
bar
HF
bar
HF
bar
HF
bar





0
3.4
0
1.6
0
6.6
0
1.4
0
4.8
0
1.9


0.05
4.4
0.05
2.8
0.05
7.6
0.05
2.5
0.05
5.8
0.05
3.0


0.1
4.4
0.1
2.8
0.1
7.6
0.1
2.5
0.1
5.8
0.1
3.0


0.15
4.4
0.15
2.8
0.15
7.6
0.15
2.5
0.15
5.8
0.15
3.0


0.2
4.4
0.2
2.8
0.2
7.6
0.2
2.5
0.2
5.8
0.2
3.0


0.25
4.4
0.25
2.8
0.25
7.6
0.25
2.5
0.25
5.8
0.25
3.0


0.3
4.4
0.3
2.8
0.3
7.6
0.3
2.5
0.3
5.8
0.3
3.0


0.35
4.4
0.35
2.8
0.35
7.6
0.35
2.5
0.35
5.8
0.35
3.0


0.4
4.4
0.4
2.8
0.4
7.6
0.4
2.5
0.4
5.8
0.4
3.0


0.45
4.4
0.45
2.7
0.45
7.6
0.45
2.5
0.45
5.7
0.45
3.0


0.5
4.4
0.5
2.7
0.5
7.6
0.5
2.5
0.5
5.7
0.5
3.0


0.55
4.4
0.55
2.7
0.55
7.6
0.55
2.5
0.55
5.7
0.55
3.0


0.6
4.4
0.6
2.7
0.6
7.6
0.6
2.5
0.6
5.6
0.6
3.0


0.65
4.4
0.65
2.7
0.65
7.6
0.65
2.5
0.65
5.5
0.65
3.0


0.7
4.4
0.7
2.7
0.7
7.6
0.7
2.5
0.7
5.3
0.7
3.0


0.75
4.2
0.75
2.7
0.75
7.4
0.75
2.5
0.75
5.1
0.75
3.0


0.8
4.0
0.8
2.6
0.8
7.1
0.8
2.4
0.8
4.8
0.8
2.8


0.85
3.6
0.85
2.4
0.85
6.5
0.85
2.2
0.85
4.3
0.85
2.6


0.9
3.1
0.9
2.1
0.9
5.5
0.9
2.0
0.9
3.6
0.9
2.3


0.95
2.3
0.95
1.7
0.95
3.8
0.95
1.7
0.95
2.6
0.95
1.9


1
1.2
1
1.2
1
1.2
1
1.2
1
1.2
1
1.2










HF - HCFO-1233xf - HFO-1234yf - HFO-1234zeE - HFO-1234zeZ - HFO-1243zf












Organics
Organics
Organics
Organics
Organics
Organics


0.2 F1233xf + 0.2
0.96 F1233xf + 0.01
0.01 F1233xf + 0.96
0.01 F1233xf + 0.01
0.01 F1233xf + 0.01
0.01 F1233xf + 0.01


F1234yf + 0.2 F1243zf 0.2
F1234yf + 0.01 F1243zf + 0.01
F1234yf + 0.01 F1243zf + 0.01
F1234yf + 0.96 F1243zf + 0.01
F1234yf + 0.01 F1243zf + 0.96
F1234yf + 0.01 F1243zf + 0.01


F1234zeE + 0.2
F1234zeE + 0.01
F1234zeE + 0.01
F1234zeE + 0.01
F1234zeE + 0.01
F1234zeE + 0.96


F1234zeZ
F1234zeZ
F1234zeZ
F1234zeZ
F1234zeZ
F1234zeZ



















TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL


MASSFRA
PRESSUR
MASSFRA
PRESSUR
MASSFRA
PRESSUR
MASSFRA
PRESSUR
MASSFRA
PRESSUR
MASSFRA
PRESSUR


HF
bar
HF
bar
HF
bar
HF
bar
HF
bar
HF
bar





0
4.3
0
1.7
0
6.7
0
5.8
0
4.8
0
1.9


0.05
5.3
0.05
2.8
0.05
7.6
0.05
6.7
0.05
5.8
0.05
3.0


0.1
5.3
0.1
2.8
0.1
7.6
0.1
6.7
0.1
5.8
0.1
3.0


0.15
5.3
0.15
2.8
0.15
7.6
0.15
6.7
0.15
5.8
0.15
3.0


0.2
5.3
0.2
2.8
0.2
7.6
0.2
6.7
0.2
5.8
0.2
3.0


0.25
5.3
0.25
2.8
0.25
7.6
0.25
6.7
0.25
5.8
0.25
3.0


0.3
5.3
0.3
2.8
0.3
7.6
0.3
6.7
0.3
5.8
0.3
3.0


0.35
5.3
0.35
2.8
0.35
7.6
0.35
6.7
0.35
5.8
0.35
3.0


0.4
5.3
0.4
2.8
0.4
7.6
0.4
6.7
0.4
5.8
0.4
3.0


0.45
5.3
0.45
2.8
0.45
7.6
0.45
6.7
0.45
5.8
0.45
3.0


0.5
5.3
0.5
2.8
0.5
7.6
0.5
6.7
0.5
5.8
0.5
3.0


0.55
5.3
0.55
2.8
0.55
7.6
0.55
6.7
0.55
5.7
0.55
3.0


0.6
5.3
0.6
2.8
0.6
7.6
0.6
6.7
0.6
5.6
0.6
3.0


0.65
5.3
0.65
2.8
0.65
7.6
0.65
6.6
0.65
5.5
0.65
3.0


0.7
5.2
0.7
2.8
0.7
7.6
0.7
6.5
0.7
5.4
0.7
3.0


0.75
5.0
0.75
2.8
0.75
7.5
0.75
6.3
0.75
5.1
0.75
3.0


0.8
4.8
0.8
2.7
0.8
7.1
0.8
6.1
0.8
4.8
0.8
2.9


0.85
4.3
0.85
2.5
0.85
6.5
0.85
5.6
0.85
4.3
0.85
2.7


0.9
3.7
0.9
2.2
0.9
5.5
0.9
4.7
0.9
3.6
0.9
2.4


0.95
2.7
0.95
1.8
0.95
3.8
0.95
3.4
0.95
2.6
0.95
1.9


1
1.2
1
1.2
1
1.2
1
1.2
1
1.2
1
1.2










HF - HCFO-1233xf - HFO-1234yf - HFO-1234zeE - HCFO-1233zdE - HFO-1243zf












Organics
Organics
Organics
Organics
Organics
Organics


0.2 F1233xf + 0.2
0.96 F1233xf + 0.01
0.01 F1233xf + 0.96
0.01 F1233xf + 0.01
0.01 F1233xf + 0.01
0.01 F1233xf + 0.01


F1234yf + 0.2 F1243zf + 0.2
F1234yf + 0.01 F1243zf + 0.01
F1234yf + 0.01 F1243zf + 0.01
F1234yf + 0.96 F1243zf + 0.01
F1234yf + 0.01 F1243zf + 0.96
F1234yf + 0.01 F1243zf + 0.01


F1234zeE + 0.2
F1234zeE + 0.01
F1234zeE + 0.01
F1234zeE + 0.01
F1234zeE + 0.01
F1234zeE + 0.96


F1233zdE
F1233zdE
F1233zdE
F1233zdE
F1233zdE
F1233zdE



















TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL


MASSFR
PRESSU
MASSFR
PRESSU
MASSFR
PRESSU
MASSFR
PRESSU
MASSFR
PRESSU
MASSFR
PRESSU


HF
bar
HF
bar
HF
bar
HF
bar
HF
bar
HF
bar





0
4.3
0
1.7
0
6.7
0
5.8
0
4.8
0
1.5


0.05
5.3
0.05
2.8
0.05
7.6
0.05
6.7
0.05
5.8
0.05
2.6


0.1
5.3
0.1
2.8
0.1
7.6
0.1
6.7
0.1
5.8
0.1
2.6


0.15
5.3
0.15
2.8
0.15
7.6
0.15
6.7
0.15
5.8
0.15
2.6


0.2
5.3
0.2
2.8
0.2
7.6
0.2
6.7
0.2
5.8
0.2
2.6


0.25
5.3
0.25
2.8
0.25
7.6
0.25
6.7
0.25
5.8
0.25
2.6


0.3
5.3
0.3
2.8
0.3
7.6
0.3
6.7
0.3
5.8
0.3
2.6


0.35
5.3
0.35
2.8
0.35
7.6
0.35
6.7
0.35
5.8
0.35
2.6


0.4
5.3
0.4
2.8
0.4
7.6
0.4
6.7
0.4
5.8
0.4
2.6


0.45
5.3
0.45
2.8
0.45
7.6
0.45
6.7
0.45
5.8
0.45
2.6


0.5
5.3
0.5
2.8
0.5
7.6
0.5
6.7
0.5
5.8
0.5
2.6


0.55
5.3
0.55
2.8
0.55
7.6
0.55
6.7
0.55
5.7
0.55
2.6


0.6
5.3
0.6
2.8
0.6
7.6
0.6
6.7
0.6
5.6
0.6
2.6


0.65
5.2
0.65
2.8
0.65
7.6
0.65
6.6
0.65
5.5
0.65
2.6


0.7
5.1
0.7
2.8
0.7
7.6
0.7
6.5
0.7
5.4
0.7
2.6


0.75
5.0
0.75
2.8
0.75
7.5
0.75
6.3
0.75
5.1
0.75
2.6


0.8
4.7
0.8
2.6
0.8
7.1
0.8
6.1
0.8
4.8
0.8
2.4


0.85
4.3
0.85
2.5
0.85
6.5
0.85
5.6
0.85
4.3
0.85
2.3


0.9
3.6
0.9
2.2
0.9
5.5
0.9
4.7
0.9
3.6
0.9
2.0


0.95
2.6
0.95
1.8
0.95
3.8
0.95
3.4
0.95
2.6
0.95
1.7


1
1.2
1
1.2
1
1.2
1
1.2
1
1.2
1
1.2










HF - HCFO-1233xf - HFO-1234yf - HFO-1234zeZ - HCFO-1233zdE - HFO-1243zf












Organics
Organics
Organics
Organics
Organics
Organics


0.2 F1233xf + 0.2
0.96 F1233xf + 0.01
0.01 F1233xf + 0.96
0.01 F1233xf + 0.01
0.01 F1233xf + 0.01
0.01 F1233xf + 0.01


F1234yf + 0.2 F1243zf + 0.2
F1234yf + 0.01 F1243zf + 0.01
F1234yf + 0.01 F1243zf + 0.01
F1234yf + 0.96 F1243zf + 0.01
F1234yf + 0.01 F1243zf + 0.96
F1234yf + 0.01 F1243zf + 0.01


F1234zeZ + 0.2
F1234zeZ + 0.01
F1234zeZ + 0.01
F1234zeZ + 0.01
F1234zeZ + 0.01
F1234zeZ + 0.96


F1233zdE
F1233zdE
F1233zdE
F1233zdE
F1233zdE
F1233zdE



















TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL


MASSFR
PRESSU
MASSFR
PRESSU
MASSFR
PRESSU
MASSFR
PRESSU
MASSFR
PRESSU
MASSFR
PRESSU


HF
bar
HF
bar
HF
bar
HF
bar
HF
bar
HF
bar





0
3.6
0
1.7
0
6.6
0
5.7
0
1.9
0
1.4


0.05
4.7
0.05
2.8
0.05
7.6
0.05
6.7
0.05
3.0
0.05
2.6


0.1
4.7
0.1
2.8
0.1
7.6
0.1
6.7
0.1
3.0
0.1
2.6


0.15
4.7
0.15
2.8
0.15
7.6
0.15
6.7
0.15
3.0
0.15
2.6


0.2
4.7
0.2
2.8
0.2
7.6
0.2
6.7
0.2
3.0
0.2
2.6


0.25
4.7
0.25
2.8
0.25
7.6
0.25
6.7
0.25
3.0
0.25
2.6


0.3
4.7
0.3
2.8
0.3
7.6
0.3
6.7
0.3
3.0
0.3
2.6


0.35
4.7
0.35
2.8
0.35
7.6
0.35
6.7
0.35
3.0
0.35
2.5


0.4
4.7
0.4
2.8
0.4
7.6
0.4
6.7
0.4
3.0
0.4
2.5


0.45
4.7
0.45
2.8
0.45
7.6
0.45
6.7
0.45
3.0
0.45
2.5


0.5
4.7
0.5
2.8
0.5
7.6
0.5
6.7
0.5
3.0
0.5
2.5


0.55
4.7
0.55
2.8
0.55
7.6
0.55
6.7
0.55
3.0
0.55
2.5


0.6
4.7
0.6
2.8
0.6
7.6
0.6
6.6
0.6
3.0
0.6
2.5


0.65
4.7
0.65
2.8
0.65
7.6
0.65
6.6
0.65
3.0
0.65
2.5


0.7
4.7
0.7
2.8
0.7
7.6
0.7
6.5
0.7
3.0
0.7
2.5


0.75
4.5
0.75
2.8
0.75
7.4
0.75
6.3
0.75
3.0
0.75
2.5


0.8
4.3
0.8
2.6
0.8
7.1
0.8
6.0
0.8
2.9
0.8
2.4


0.85
3.9
0.85
2.4
0.85
6.5
0.85
5.5
0.85
2.7
0.85
2.3


0.9
3.4
0.9
2.2
0.9
5.5
0.9
4.7
0.9
2.3
0.9
2.0


0.95
2.5
0.95
1.7
0.95
3.8
0.95
3.3
0.95
1.9
0.95
1.7


1
1.2
1
1.2
1
1.2
1
1.2
1
1.2
1
1.2










HF - HCFO-1233xf - HFC-245cb - HFO-1234zeE - HFO-1234zeZ - HCFO-1233zdE












Organics
Organics
Organics
Organics
Organics
Organics


0.2 F1233xf + 0.2
0.96 F1233xf + 0.01
0.01 F1233xf + 0.96
0.01 F1233xf + 0.01
0.01 F1233xf + 0.01
0.01 F1233xf + 0.01


F245cb + 0.2 F1233zdE 0.2
F245cb + 0.01 F1233zdE + 0.01
F245cb + 0.01 F1233zdE + 0.01
F245cb + 0.96 F1233zdE + 0.01
F245cb + 0.01 F1233zdE + 0.96
F245cb + 0.01 F1233zdE + 0.01


F1234zeE + 0.2
F1234zeE +
F1234zeE +
F1234zeE +
F1234zeE +
F1234zeE +


F1234zeZ
0.01 F1234zeZ
0.01 F1234zeZ
0.01 F1234zeZ
0.01 F1234zeZ
0.96 F1234zeZ



















TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL


MASSFRA
PRESSUR
MASSFRA
PRESSUR
MASSFRA
PRESSUR
MASSFRA
PRESSUR
MASSFRA
PRESSUR
MASSFRA
PRESSUR


HF
bar
HF
bar
HF
bar
HF
bar
HF
bar
HF
bar





0
2.9
0
1.6
0
4.6
0
1.4
0
4.8
0
1.9


0.05
4.0
0.05
2.7
0.05
5.7
0.05
2.5
0.05
5.7
0.05
3.0


0.1
4.0
0.1
2.7
0.1
5.7
0.1
2.5
0.1
5.8
0.1
3.0


0.15
4.0
0.15
2.7
0.15
5.7
0.15
2.5
0.15
5.8
0.15
3.0


0.2
4.0
0.2
2.7
0.2
5.7
0.2
2.5
0.2
5.8
0.2
3.0


0.25
4.0
0.25
2.7
0.25
5.7
0.25
2.5
0.25
5.8
0.25
3.0


0.3
4.0
0.3
2.7
0.3
5.7
0.3
2.5
0.3
5.8
0.3
3.0


0.35
4.0
0.35
2.7
0.35
5.7
0.35
2.5
0.35
5.7
0.35
3.0


0.4
4.0
0.4
2.7
0.4
5.7
0.4
2.5
0.4
5.7
0.4
3.0


0.45
4.0
0.45
2.7
0.45
5.7
0.45
2.5
0.45
5.7
0.45
3.0


0.5
4.0
0.5
2.7
0.5
5.7
0.5
2.5
0.5
5.7
0.5
3.0


0.55
4.0
0.55
2.7
0.55
5.7
0.55
2.5
0.55
5.6
0.55
3.0


0.6
4.0
0.6
2.7
0.6
5.7
0.6
2.5
0.6
5.6
0.6
3.0


0.65
4.0
0.65
2.7
0.65
5.7
0.65
2.5
0.65
5.5
0.65
3.0


0.7
4.0
0.7
2.7
0.7
5.8
0.7
2.5
0.7
5.3
0.7
3.0


0.75
4.0
0.75
2.7
0.75
5.8
0.75
2.5
0.75
5.1
0.75
3.0


0.8
3.8
0.8
2.6
0.8
5.8
0.8
2.4
0.8
4.7
0.8
2.8


0.85
3.5
0.85
2.4
0.85
5.8
0.85
2.2
0.85
4.3
0.85
2.6


0.9
3.0
0.9
2.1
0.9
5.0
0.9
2.0
0.9
3.6
0.9
2.3


0.95
2.3
0.95
1.7
0.95
3.5
0.95
1.7
0.95
2.6
0.95
1.9


1
1.2
1
1.2
1
1.2
1
1.2
1
1.2
1
1.2










HF - HCFO-1233xf - HFC-245cb - HFO-1234zeE - HFO-1234zeZ - HFO-1243zf












Organics
Organics
Organics
Organics
Organics
Organics


0.2 F1233xf + 0.2
0.96 F1233xf + 0.01
0.01 F1233xf + 0.96
0.01 F1233xf + 0.01
0.01 F1233xf + 0.01
0.01 F1233xf + 0.01


F245cb + 0.2 F1243zf 0.2
F245cb + 0.01 F1243zf + 0.01
F245cb + 0.01 F1243zf + 0.01
F245cb + 0.96 F1243zf + 0.01
F245cb + 0.01 F1243zf + 0.96
F245cb + 0.01 F1243zf + 0.01


F1234zeE + 0.2
F1234zeE + 0.01
F1234zeE + 0.01
F1234zeE + 0.01
F1234zeE + 0.01
F1234zeE + 0.96


F1234zeZ
F1234zeZ
F1234zeZ
F1234zeZ
F1234zeZ
F1234zeZ



















TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL


MASSFRA
PRESSUR
MASSFRA
PRESSUR
MASSFRA
PRESSUR
MASSFRA
PRESSUR
MASSFRA
PRESSUR
MASSFRA
PRESSUR


HF
bar
HF
bar
HF
bar
HF
bar
HF
bar
HF
bar





0
3.8
0
1.7
0
4.6
0
5.8
0
4.8
0
1.9


0.05
4.9
0.05
2.8
0.05
5.8
0.05
6.7
0.05
5.8
0.05
3.0


0.1
4.9
0.1
2.8
0.1
5.8
0.1
6.7
0.1
5.8
0.1
3.0


0.15
4.9
0.15
2.8
0.15
5.8
0.15
6.7
0.15
5.8
0.15
3.0


0.2
4.9
0.2
2.8
0.2
5.8
0.2
6.7
0.2
5.8
0.2
3.0


0.25
4.9
0.25
2.8
0.25
5.8
0.25
6.7
0.25
5.8
0.25
3.0


0.3
4.9
0.3
2.8
0.3
5.8
0.3
6.7
0.3
5.8
0.3
3.0


0.35
4.9
0.35
2.8
0.35
5.8
0.35
6.7
0.35
5.8
0.35
3.0


0.4
4.9
0.4
2.8
0.4
5.8
0.4
6.7
0.4
5.8
0.4
3.0


0.45
4.9
0.45
2.8
0.45
5.8
0.45
6.7
0.45
5.8
0.45
3.0


0.5
4.9
0.5
2.8
0.5
5.8
0.5
6.7
0.5
5.7
0.5
3.0


0.55
4.9
0.55
2.8
0.55
5.8
0.55
6.7
0.55
5.7
0.55
3.0


0.6
4.9
0.6
2.8
0.6
5.8
0.6
6.6
0.6
5.6
0.6
3.0


0.65
4.9
0.65
2.8
0.65
5.8
0.65
6.6
0.65
5.5
0.65
3.0


0.7
4.9
0.7
2.8
0.7
5.8
0.7
6.5
0.7
5.4
0.7
3.0


0.75
4.8
0.75
2.8
0.75
5.8
0.75
6.3
0.75
5.1
0.75
3.0


0.8
4.6
0.8
2.6
0.8
5.8
0.8
6.0
0.8
4.8
0.8
2.9


0.85
4.2
0.85
2.4
0.85
5.8
0.85
5.6
0.85
4.3
0.85
2.7


0.9
3.6
0.9
2.2
0.9
5.0
0.9
4.7
0.9
3.6
0.9
2.4


0.95
2.6
0.95
1.8
0.95
3.5
0.95
3.4
0.95
2.6
0.95
1.9


1
1.2
1
1.2
1
1.2
1
1.2
1
1.2
1
1.2










HF - HCFO-1233xf - HFC-245cb - HFO-1234zeE - HCFO-1233zdE - HFO-1243zf












Organics
Organics
Organics
Organics
Organics
Organics


0.2 F1233xf + 0.2
0.96 F1233xf + 0.01
0.01 F1233xf + 0.96
0.01 F1233xf + 0.01
0.01 F1233xf + 0.01
0.01 F1233xf + 0.01


F245cb + 0.2 F1243zf + 0.2
F245cb + 0.01 F1243zf + 0.01
F245cb + 0.01 F1243zf + 0.01
F245cb + 0.96 F1243zf + 0.01
F245cb + 0.01 F1243zf + 0.96
F245cb + 0.01 F1243zf + 0.01


F1234zeE + 0.2
F1234zeE + 0.01
F1234zeE + 0.01
F1234zeE + 0.01
F1234zeE + 0.01
F1234zeE + 0.96


F1233zdE
F1233zdE
F1233zdE
F1233zdE
F1233zdE
F1233zdE



















TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL


MASSFR
PRESSU
MASSFR
PRESSU
MASSFR
PRESSU
MASSFR
PRESSU
MASSFR
PRESSU
MASSFR
PRESSU


HF
bar
HF
bar
HF
bar
HF
bar
HF
bar
HF
bar





0
3.8
0
1.7
0
4.6
0
5.8
0
4.8
0
1.5


0.05
4.9
0.05
2.8
0.05
5.8
0.05
6.7
0.05
5.8
0.05
2.6


0.1
4.9
0.1
2.8
0.1
5.8
0.1
6.7
0.1
5.8
0.1
2.6


0.15
4.9
0.15
2.8
0.15
5.8
0.15
6.7
0.15
5.8
0.15
2.6


0.2
4.9
0.2
2.8
0.2
5.8
0.2
6.7
0.2
5.8
0.2
2.6


0.25
4.9
0.25
2.8
0.25
5.8
0.25
6.7
0.25
5.8
0.25
2.6


0.3
4.9
0.3
2.8
0.3
5.8
0.3
6.7
0.3
5.8
0.3
2.6


0.35
4.9
0.35
2.8
0.35
5.8
0.35
6.7
0.35
5.8
0.35
2.6


0.4
4.9
0.4
2.8
0.4
5.8
0.4
6.7
0.4
5.8
0.4
2.6


0.45
4.9
0.45
2.8
0.45
5.8
0.45
6.7
0.45
5.8
0.45
2.6


0.5
4.9
0.5
2.8
0.5
5.8
0.5
6.7
0.5
5.7
0.5
2.6


0.55
4.9
0.55
2.8
0.55
5.8
0.55
6.7
0.55
5.7
0.55
2.6


0.6
4.9
0.6
2.8
0.6
5.8
0.6
6.6
0.6
5.6
0.6
2.6


0.65
4.9
0.65
2.8
0.65
5.8
0.65
6.6
0.65
5.5
0.65
2.5


0.7
4.9
0.7
2.8
0.7
5.8
0.7
6.5
0.7
5.4
0.7
2.5


0.75
4.7
0.75
2.8
0.75
5.8
0.75
6.3
0.75
5.1
0.75
2.5


0.8
4.5
0.8
2.6
0.8
5.8
0.8
6.0
0.8
4.8
0.8
2.4


0.85
4.1
0.85
2.4
0.85
5.8
0.85
5.6
0.85
4.3
0.85
2.3


0.9
3.5
0.9
2.2
0.9
5.0
0.9
4.7
0.9
3.6
0.9
2.0


0.95
2.6
0.95
1.7
0.95
3.5
0.95
3.3
0.95
2.6
0.95
1.7


1
1.2
1
1.2
1
1.2
1
1.2
1
1.2
1
1.2










HF - HCFO-1233xf - HFC-245cb - HFO-1234zeZ - HCFO-1233zdE - HFO-1243zf












Organics
Organics
Organics
Organics
Organics
Organics


0.2 F1233xf + 0.2
0.96 F1233xf + 0.01
0.01 F1233xf + 0.96
0.01 F1233xf + 0.01
0.01 F1233xf + 0.01
0.01 F1233xf + 0.01


F245cb + 0.2 F1243zf + 0.2
F245cb + 0.01 F1243zf + 0.01
F245cb + 0.01 F1243zf + 0.01
F245cb + 0.96 F1243zf + 0.01
F245cb + 0.01 F1243zf + 0.96
F245cb + 0.01 F1243zf + 0.01


F1234zeZ + 0.2
F1234zeZ + 0.01
F1234zeZ + 0.01
F1234zeZ + 0.01
F1234zeZ + 0.01
F1234zeZ + 0.96


F1233zdE
F1233zdE
F1233zdE
F1233zdE
F1233zdE
F1233zdE



















TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL


MASSFR
PRESSU
MASSFR
PRESSU
MASSFR
PRESSU
MASSFR
PRESSU
MASSFR
PRESSU
MASSFR
PRESSU


HF
bar
HF
bar
HF
bar
HF
bar
HF
bar
HF
bar





0
3.2
0
1.6
0
4.6
0
5.7
0
1.9
0
1.4


0.05
4.3
0.05
2.7
0.05
5.7
0.05
6.7
0.05
3.0
0.05
2.5


0.1
4.3
0.1
2.7
0.1
5.7
0.1
6.7
0.1
3.0
0.1
2.5


0.15
4.3
0.15
2.7
0.15
5.7
0.15
6.7
0.15
3.0
0.15
2.5


0.2
4.3
0.2
2.7
0.2
5.7
0.2
6.7
0.2
3.0
0.2
2.5


0.25
4.3
0.25
2.7
0.25
5.7
0.25
6.7
0.25
3.0
0.25
2.5


0.3
4.3
0.3
2.7
0.3
5.7
0.3
6.7
0.3
3.0
0.3
2.5


0.35
4.3
0.35
2.7
0.35
5.7
0.35
6.7
0.35
3.0
0.35
2.5


0.4
4.3
0.4
2.7
0.4
5.8
0.4
6.7
0.4
3.0
0.4
2.5


0.45
4.3
0.45
2.7
0.45
5.8
0.45
6.7
0.45
3.0
0.45
2.5


0.5
4.3
0.5
2.7
0.5
5.8
0.5
6.7
0.5
3.0
0.5
2.5


0.55
4.3
0.55
2.7
0.55
5.8
0.55
6.7
0.55
3.0
0.55
2.5


0.6
4.3
0.6
2.7
0.6
5.8
0.6
6.6
0.6
3.0
0.6
2.5


0.65
4.3
0.65
2.7
0.65
5.8
0.65
6.6
0.65
3.0
0.65
2.5


0.7
4.3
0.7
2.7
0.7
5.8
0.7
6.5
0.7
3.0
0.7
2.5


0.75
4.3
0.75
2.7
0.75
5.8
0.75
6.3
0.75
3.0
0.75
2.5


0.8
4.1
0.8
2.6
0.8
5.8
0.8
6.0
0.8
2.9
0.8
2.4


0.85
3.8
0.85
2.4
0.85
5.8
0.85
5.5
0.85
2.7
0.85
2.3


0.9
3.3
0.9
2.1
0.9
5.0
0.9
4.7
0.9
2.3
0.9
2.0


0.95
2.4
0.95
1.7
0.95
3.5
0.95
3.3
0.95
1.9
0.95
1.7


1
1.2
1
1.2
1
1.2
1
1.2
1
1.2
1
1.2










HF - HCFO-1233xf - HFO-1234zeE-HFO-1234zeZ - HCFO-1233zdE- HFO-1243zf












Organics 0.2 F1233xf + 0.2
Organics 0.96 F1233xf + 0.01
Organics 0.01 F1233xf + 0.96
Organics 0.01 F1233xf + 0.01
Organics 0.01 F1233xf + 0.01
Organics 0.01 F1233xf + 0.01


F1243zf + 0.2 F1233zdE 0.2
F1243zf + 0.01 F1233zdE +
F1243zf + 0.01 F1233zdE +
F1243zf + 0.96 F1233zdE +
F1243zf + 0.01 F1233zdE +
F1243zf + 0.01 F1233zdE +


F1234zeE + 0.2
0.01 F1234zeE +
0.01 F1234zeE +
0.01 F1234zeE +
0.96 F1234zeE +
0.01 F1234zeE +


F1234zeZ
0.01 F1234zeZ
0.01 F1234zeZ
0.01 F1234zeZ
0.01 F1234zeZ
0.96 F1234zeZ



















TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL


MASSFR
PRESSU
MASSFR
PRESSU
MASSFR
PRESSU
MASSFR
PRESSU
MASSFR
PRESSU
MASSFR
PRESSU


HF
bar
HF
bar
HF
bar
HF
bar
HF
bar
HF
bar





0
3.2
0
1.6
0
5.7
0
1.4
0
4.8
0
1.9


0.05
4.3
0.05
2.7
0.05
6.7
0.05
2.5
0.05
5.7
0.05
3.0


0.1
4.3
0.1
2.7
0.1
6.7
0.1
2.5
0.1
5.8
0.1
3.0


0.15
4.3
0.15
2.7
0.15
6.7
0.15
2.5
0.15
5.8
0.15
3.0


0.2
4.3
0.2
2.7
0.2
6.7
0.2
2.5
0.2
5.8
0.2
3.0


0.25
4.3
0.25
2.7
0.25
6.7
0.25
2.5
0.25
5.8
0.25
3.0


0.3
4.3
0.3
2.7
0.3
6.7
0.3
2.5
0.3
5.8
0.3
3.0


0.35
4.3
0.35
2.7
0.35
6.7
0.35
2.5
0.35
5.8
0.35
3.0


0.4
4.3
0.4
2.7
0.4
6.7
0.4
2.5
0.4
5.8
0.4
3.0


0.45
4.3
0.45
2.7
0.45
6.7
0.45
2.5
0.45
5.7
0.45
3.0


0.5
4.3
0.5
2.7
0.5
6.7
0.5
2.5
0.5
5.7
0.5
3.0


0.55
4.2
0.55
2.7
0.55
6.6
0.55
2.5
0.55
5.7
0.55
3.0


0.6
4.2
0.6
2.7
0.6
6.6
0.6
2.5
0.6
5.6
0.6
3.0


0.65
4.2
0.65
2.7
0.65
6.6
0.65
2.5
0.65
5.5
0.65
3.0


0.7
4.2
0.7
2.7
0.7
6.5
0.7
2.5
0.7
5.3
0.7
3.0


0.75
4.0
0.75
2.7
0.75
6.3
0.75
2.5
0.75
5.1
0.75
3.0


0.8
3.8
0.8
2.6
0.8
6.0
0.8
2.4
0.8
4.7
0.8
2.8


0.85
3.5
0.85
2.4
0.85
5.5
0.85
2.2
0.85
4.3
0.85
2.6


0.9
3.0
0.9
2.1
0.9
4.7
0.9
2.0
0.9
3.6
0.9
2.3


0.95
2.2
0.95
1.7
0.95
3.3
0.95
1.7
0.95
2.6
0.95
1.9


1
1.2
1
1.2
1
1.2
1
1.2
1
1.2
1
1.2









Example 11: Temperature and Pressure Range of Systems with 6 Compounds













Boiling point range










Tem-




perature
Pressure bar


System with 6 compounds
° C.
abs





HF-HCFO-1233xf-HFO-1234yf-HFC-245cb-
0 to 40
~1.0 ~11.6


HFO- 1234zeE-HFO-1234zeZ


HF-HCFO-1233xf-HFO-1234yf-HFC-245cb-
0 to 40
~0.9 to ~11.6


HFO- 1234zeE-HCFO-1233zdE


HF-HCFO-1233xf-HFO-1234yf-HFC-245cb-
0 to 40
~1.0 to ~11.6


HFO- 1234zeE-HFO-1243zf


HF-HCFO-1233xf-HFO-1234yf-HFC-245cb-
0 to 40
~0.9 to ~11.5


HFO- 1234zeZ-HCFO-1233zdE


HF-HCFO-1233xf-HFO-1234yf-HFC-245cb-
0 to 40
~1.0 to ~11.6


HFO- 1234zeZ-HFO-1243zf


HF-HCFO-1233xf-HFO-1234yf-HFC-245cb-
0 to 40
~0.9 to ~11.6


HCFO- 1233zdE-HFO-1243zf


HF-HCFO-1233xf-HFO-1234yf-HFO-
0 to 40
~0.9 to ~11.5


1234zeE-HFO- 1234zeZ-HCFO-1233zdE


HF-HCFO-1233xf-HFO-1234yf-HFO-
0 to 40
~1.0 to ~11.6


1234zeE-HFO- 1234zeZ-HFO-1243zf


HF-HCFO-1233xf-HFO-1234yf-HFO-
0 to 40
~0.9 to ~11.6


1234zeE-HCFO- 1233zdE-HFO-1243zf


HF-HCFO-1233xf-HFO-1234yf-HFO-
0 to 40
~0.9 to ~11.6


1234zeZ-HCFO- 1233zdE-HFO-1243zf


HF-HCFO-1233xf-HFC-245cb-HFO-1234zeE-
0 to 40
~0.9 to ~9.0


HFO- 1234zeZ-HCFO-1233zdE


HF-HCFO-1233xf-HFC-245cb-HFO-1234zeE-
0 to 40
~1.0 to ~10.3


HFO- 1234zeZ-HFO-1243zf


HF-HCFO-1233xf-HFC-245cb-HFO-1234zeE-
0 to 40
~0.9 to ~10.3


HCFO- 1233zdE-HFO-1243zf


HF-HCFO-1233xf-HFC-245cb-HFO-1234zeZ-
0 to 40
~1.0 to ~10.3


HCFO- 1233zdE-HFO-1243zf


HF-HCFO-1233xf-HFO-1234zeE-HFO-
0 to 40
~0.9 ~10.3


1234zeZ-HCFO- 1233zdE-HFO-1243zf









Example 12: Decantation Range of Systems with 6 Compounds













Decantation ranges



Mass percentage of HF











Iso-
Iso-
Iso-



therm
therm
therm


System with 6 compounds
0° C.
25° C.
40° C.





HF-HCFO-1233xf-HFO-1234yf-HFC-245cb-
5-75
5-70
15-55


HFO- 1234zeE-HFO-1234zeZ


HF-HCFO-1233xf-HFO-1234yf-HFC-245cb-
5-75
5-70
15-55


HFO- 1234zeE-HCFO-1233zdE


HF-HCFO-1233xf-HFO-1234yf-HFC-245cb-
5-75
10-65 
*


HFO- 1234zeE-HFO-1243zf


HF-HCFO-1233xf-HFO-1234yf-HFC-245cb-
5-75
5-75
10-65


HFO- 1234zeZ-HCFO-1233zdE


HF-HCFO-1233xf-HFO-1234yf-HFC-245cb-
5-75
10-70 
15-50


HFO- 1234zeZ-HFO-1243zf


HF-HCFO-1233xf-HFO-1234yf-HFC-245cb-
5-75
5-70
15-55


HCFO- 1233zdE-HFO-1243zf


HF-HCFO-1233xf-HFO-1234yf-HFO-
5-75
5-65
10-55


1234zeE-HFO- 1234zeZ-HCFO-1233zdE


HF-HCFO-1233xf-HFO-1234yf-HFO-
5-70
10-65 
*


1234zeE-HFO- 1234zeZ-HFO-1243zf


HF-HCFO-1233xf-HFO-1234yf-HFO-
5-70
10-75 
*


1234zeE-HCFO- 1233zdE-HFO-1243zf


HF-HCFO-1233xf-HFO-1234yf-HFO-
5-75
5-70
10-55


1234zeZ-HCFO- 1233zdE-HFO-1243zf


HF-HCFO-1233xf-HFC-245cb-HFO-1234zeE-
5-75
5-70
10-65


HFO- 1234zeZ-HCFO-1233zdE


HF-HCFO-1233xf-HFC-245cb-HFO-1234zeE-
5-75
10-70 
15-45


HFO- 1234zeZ-HFO-1243zf


HF-HCFO-1233xf-HFC-245cb-HFO-1234zeE-
5-75
5-70
15-50


HCFO- 1233zdE-HFO-1243zf


HF-HCFO-1233xf-HFC-245cb-HFO-1234zeZ-
5-75
5-70
10-65


HCFO- 1233zdE-HFO-1243zf


HF-HCFO-1233xf-HFO-1234zeE-HFO-
5-75
5-65
10-55


1234zeZ-HCFO- 1233zdE-HFO-1243zf









Example 13: Systems with Seven Compounds, Isotherm at 25° C.












HF - HCFO-1233xf - HFC-245cb - HCFO-1233zdE-HFO-1234zeE - HFO-1234zeZ -HFO-1243zf













Organics
Organics
Organics
Organics
Organics
Organics
Organics


0.15 F1233xf + 0.17
0.95 F1233xf +
0.01 F1233xf +
0.01 F1233xf +
0.01 F1233xf +
0.01 F1233xf +
0.01 F1233xf +


F245cb + 0.17
0.01 F245cb + 0.01
0.95 F245cb + 0.01
0.01 F245cb + 0.95
0.01 F245cb + 0.01
0.01 F245cb + 0.01
0.01 F245cb + 0.01


F1233zdE + 0.17
F1233zdE + 0.01
F1233zdE + 0.01
F1233zdE + 0.01
F1233zdE + 0.95
F1233zdE + 0.01
F1233zdE + 0.01


F1234zeE + 0.17
F1234zeE + 0.01
F1234zeE + 0.01
F1234zeE + 0.01
F1234zeE + 0.01
F1234zeE + 0.01
F1234zeE + 0.95


F1234zeZ + 0.17 F1243zf
F1234zeZ + 0.01 F1243zf
F1234zeZ + 0.01 F1243zf
F1234zeZ + 0.01 F1243zf
F1234zeZ + 0.01 F1243zf
F1234zeZ + 0.95 F1243zf
F1234zeZ + 0.01 F1243zf





















TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL


MASSFRAC
PRESS.
MASSFR
PRESS.
MASSF
PRESS.
MASSFR
PRESS.
MASSFR
PRESS.
MASSFR
PRESS.
MASSFR
PRESS.


HF
bar
HF
bar
HF
bar
HF
bar
HF
bar
HF
bar
HF
bar





0
3.5
0
1.7
0
4.6
0
1.5
0
4.8
0
5.7
0
1.9


0.05
4.6
0.05
2.8
0.05
5.7
0.05
2.6
0.05
5.7
0.05
6.7
0.05
3.0


0.1
4.6
0.1
2.8
0.1
5.7
0.1
2.6
0.1
5.8
0.1
6.7
0.1
3.0


0.15
4.6
0.15
2.8
0.15
5.7
0.15
2.6
0.15
5.8
0.15
6.7
0.15
3.0


0.2
4.6
0.2
2.8
0.2
5.7
0.2
2.6
0.2
5.8
0.2
6.7
0.2
3.0


0.25
4.6
0.25
2.8
0.25
5.8
0.25
2.6
0.25
5.8
0.25
6.7
0.25
3.0


0.3
4.6
0.3
2.8
0.3
5.8
0.3
2.6
0.3
5.8
0.3
6.7
0.3
3.0


0.35
4.6
0.35
2.8
0.35
5.8
0.35
2.6
0.35
5.8
0.35
6.7
0.35
3.0


0.4
4.6
0.4
2.8
0.4
5.8
0.4
2.6
0.4
5.8
0.4
6.7
0.4
3.0


0.45
4.6
0.45
2.8
0.45
5.8
0.45
2.6
0.45
5.7
0.45
6.7
0.45
3.0


0.5
4.6
0.5
2.8
0.5
5.8
0.5
2.6
0.5
5.7
0.5
6.7
0.5
3.0


0.55
4.6
0.55
2.8
0.55
5.8
0.55
2.6
0.55
5.7
0.55
6.6
0.55
3.0


0.6
4.6
0.6
2.8
0.6
5.8
0.6
2.6
0.6
5.6
0.6
6.6
0.6
3.0


0.65
4.6
0.65
2.8
0.65
5.8
0.65
2.6
0.65
5.5
0.65
6.6
0.65
3.0


0.7
4.6
0.7
2.8
0.7
5.8
0.7
2.6
0.7
5.3
0.7
6.5
0.7
3.0


0.75
4.5
0.75
2.8
0.75
5.8
0.75
2.6
0.75
5.1
0.75
6.3
0.75
3.0


0.8
4.2
0.8
2.6
0.8
5.8
0.8
2.4
0.8
4.8
0.8
6.0
0.8
2.9


0.85
3.9
0.85
2.4
0.85
5.8
0.85
2.3
0.85
4.3
0.85
5.5
0.85
2.7


0.9
3.3
0.9
2.2
0.9
4.9
0.9
2.0
0.9
3.6
0.9
4.7
0.9
2.4


0.95
2.5
0.95
1.8
0.95
3.5
0.95
1.7
0.95
2.6
0.95
3.3
0.95
1.9


1
1.2
1
1.2
1
1.2
1
1.2
1
1.2
1
1.2
1
1.2










HF - HCFO-1233xf - HFO-1234yf - HFC-245cb - HCFO-1233zdE - HFO-1234zeE -HFO-1234zeZ













Organics
Organics
Organics
Organics
Organics
Organics
Organics


0.15 F1233xf +
0.01 F1233xf +
0.01 F1233xf +
0.01 F1233xf +
0.01 F1233xf +
0.01 F1233xf +
0.95 F1233xf +


0.17 F1234yf +
0.95 F1234yf +
0.01 F1234yf +
0.01 F1234yf +
0.01 F1234yf +
0.01 F1234yf +
0.01 F1234yf +


0.17 F245cb + 0.17
0.01 F245cb + 0.01
0.95 F245cb + 0.01
0.01 F245cb + 0.95
0.01 F245cb + 0.01
0.01 F245cb + 0.01
0.01 F245cb + 0.01


F1233zdE + 0.17
F1233zdE + 0.01
F1233zdE + 0.01
F1233zdE + 0.01
F1233zdE + 0.95
F1233zdE + 0.01
F1233zdE + 0.01


F1234zeE + 0.17 F1234zeZ
F1234zeE + 0.01 F1234zeZ
F1234zeE + 0.01 F1234zeZ
F1234zeE + 0.01 F1234zeZ
F1234zeE + 0.01 F1234zeZ
F1234zeE + 0.95 F1234zeZ
F1234zeE + 0.01 F1234zeZ





















TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL


MASSFR
PRESSU
MASSFR
PRESSU
MASSFR
PRESSU
MASSFR
PRESSU
MASSFR
PRESSU
MASSFR
PRESSU
MASSFR
PRESSU


HF
bar
HF
bar
HF
bar
HF
bar
HF
bar
HF
bar
HF
bar





0
3.6
0
6.6
0
4.6
0
1.5
0
4.8
0
1.9
0
1.7


0.05
4.7
0.05
7.6
0.05
5.8
0.05
2.6
0.05
5.8
0.05
3.0
0.05
2.8


0.1
4.7
0.1
7.6
0.1
5.8
0.1
2.6
0.1
5.8
0.1
3.0
0.1
2.8


0.15
4.7
0.15
7.6
0.15
5.8
0.15
2.6
0.15
5.8
0.15
3.0
0.15
2.8


0.2
4.7
0.2
7.6
0.2
5.8
0.2
2.6
0.2
5.8
0.2
3.0
0.2
2.8


0.25
4.7
0.25
7.6
0.25
5.8
0.25
2.6
0.25
5.8
0.25
3.0
0.25
2.8


0.3
4.7
0.3
7.6
0.3
5.8
0.3
2.6
0.3
5.8
0.3
3.0
0.3
2.8


0.35
4.7
0.35
7.6
0.35
5.8
0.35
2.6
0.35
5.8
0.35
3.0
0.35
2.8


0.4
4.7
0.4
7.6
0.4
5.8
0.4
2.6
0.4
5.8
0.4
3.0
0.4
2.8


0.45
4.7
0.45
7.6
0.45
5.8
0.45
2.6
0.45
5.7
0.45
3.0
0.45
2.8


0.5
4.7
0.5
7.6
0.5
5.8
0.5
2.6
0.5
5.7
0.5
3.0
0.5
2.8


0.55
4.7
0.55
7.6
0.55
5.8
0.55
2.6
0.55
5.7
0.55
3.0
0.55
2.8


0.6
4.7
0.6
7.6
0.6
5.8
0.6
2.6
0.6
5.6
0.6
3.0
0.6
2.8


0.65
4.7
0.65
7.6
0.65
5.8
0.65
2.6
0.65
5.5
0.65
3.0
0.65
2.8


0.7
4.7
0.7
7.6
0.7
5.8
0.7
2.6
0.7
5.3
0.7
3.0
0.7
2.8


0.75
4.6
0.75
7.4
0.75
5.8
0.75
2.6
0.75
5.1
0.75
3.0
0.75
2.8


0.8
4.4
0.8
7.1
0.8
5.8
0.8
2.5
0.8
4.8
0.8
2.9
0.8
2.6


0.85
4.1
0.85
6.5
0.85
5.8
0.85
2.3
0.85
4.3
0.85
2.7
0.85
2.5


0.9
3.5
0.9
5.5
0.9
5.0
0.9
2.0
0.9
3.6
0.9
2.4
0.9
2.2


0.95
2.5
0.95
3.8
0.95
3.5
0.95
1.7
0.95
2.6
0.95
1.9
0.95
1.8


1
1.2
1
1.2
1
1.2
1
1.2
1
1.2
1
1.2
1
1.2










HF - HCFO-1233xf - HFO-1234yf - HFC-245cb - HCFO-1233zdE - HFO-1234zeE -HFO-1243zf













Organics
Organics
Organics
Organics
Organics
Organics
Organics


0.15 F1233xf + 0.17
0.01 F1233xf + 0.95
0.01 F1233xf + 0.01
0.01 F1233xf + 0.01
0.01 F1233xf + 0.01
0.01 F1233xf + 0.01
0.95 F1233xf + 0.01


F1234yf + 0.17
F1234yf + 0.01
F1234yf + 0.95
F1234yf + 0.01
F1234yf + 0.01
F1234yf + 0.01
F1234yf + 0.01


F245cb + 0.17
F245cb + 0.01
F245cb + 0.01
F245cb + 0.95
F245cb + 0.01
F245cb + 0.01
F245cb + 0.01


F1233zdE + 0.17
F1233zdE + 0.01
F1233zdE + 0.01
F1233zdE + 0.01
F1233zdE + 0.95
F1233zdE + 0.01
F1233zdE + 0.01


F1234zeE + 0.17 F1243zf
F1234zeE + 0.01 F1243zf
F1234zeE + 0.01 F1243zf
F1234zeE + 0.01 F1243zf
F1234zeE + 0.01 F1243zf
F1234zeE + 0.95 F1243zf
F1234zeE + 0.01 F1243zf





















TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL


MASSFR
PRESSU
MASSFR
PRESSU
MASSFR
PRESSU
MASSFR
PRESSU
MASSFR
PRESSU
MASSFR
PRESSU
MASSFR
PRESSU


HF
bar
HF
bar
HF
bar
HF
bar
HF
bar
HF
bar
HF
bar





0
4.4
0
6.6
0
4.6
0
1.5
0
4.8
0
5.8
0
1.7


0.05
5.4
0.05
7.6
0.05
5.8
0.05
2.6
0.05
5.8
0.05
6.7
0.05
2.8


0.1
5.4
0.1
7.6
0.1
5.8
0.1
2.6
0.1
5.8
0.1
6.7
0.1
2.8


0.15
5.4
0.15
7.6
0.15
5.8
0.15
2.6
0.15
5.8
0.15
6.7
0.15
2.8


0.2
5.4
0.2
7.6
0.2
5.8
0.2
2.6
0.2
5.8
0.2
6.7
0.2
2.8


0.25
5.4
0.25
7.6
0.25
5.8
0.25
2.6
0.25
5.8
0.25
6.7
0.25
2.8


0.3
5.4
0.3
7.6
0.3
5.8
0.3
2.6
0.3
5.8
0.3
6.7
0.3
2.8


0.35
5.4
0.35
7.6
0.35
5.8
0.35
2.6
0.35
5.8
0.35
6.7
0.35
2.8


0.4
5.4
0.4
7.6
0.4
5.8
0.4
2.6
0.4
5.8
0.4
6.7
0.4
2.8


0.45
5.4
0.45
7.6
0.45
5.8
0.45
2.6
0.45
5.8
0.45
6.7
0.45
2.8


0.5
5.4
0.5
7.6
0.5
5.8
0.5
2.6
0.5
5.8
0.5
6.7
0.5
2.8


0.55
5.4
0.55
7.6
0.55
5.8
0.55
2.6
0.55
5.7
0.55
6.7
0.55
2.8


0.6
5.4
0.6
7.6
0.6
5.8
0.6
2.6
0.6
5.6
0.6
6.7
0.6
2.8


0.65
5.4
0.65
7.6
0.65
5.8
0.65
2.6
0.65
5.5
0.65
6.6
0.65
2.8


0.7
5.4
0.7
7.6
0.7
5.8
0.7
2.6
0.7
5.4
0.7
6.5
0.7
2.8


0.75
5.3
0.75
7.4
0.75
5.8
0.75
2.6
0.75
5.1
0.75
6.3
0.75
2.8


0.8
5.0
0.8
7.1
0.8
5.8
0.8
2.5
0.8
4.8
0.8
6.1
0.8
2.7


0.85
4.6
0.85
6.5
0.85
5.8
0.85
2.3
0.85
4.3
0.85
5.6
0.85
2.5


0.9
3.9
0.9
5.5
0.9
5.0
0.9
2.1
0.9
3.6
0.9
4.7
0.9
2.2


0.95
2.8
0.95
3.8
0.95
3.5
0.95
1.7
0.95
2.6
0.95
3.4
0.95
1.8


1
1.2
1
1.2
1
1.2
1
1.2
1
1.2
1
1.2
1
1.2










HF - HCFO-1233xf - HFO-1234yf - HFC-245cb - HCFO-1233zdE 5 - HFO-1243zf - HFO-1234zeZ













Organics
Organics
Organics
Organics
Organics
Organics
Organics


0.15 F1233xf + 0.17
0.01 F1233xf + 0.95
0.01 F1233xf + 0.01
0.01 F1233xf + 0.01
0.01 F1233xf + 0.01
0.01 F1233xf + 0.01
0.95 F1233xf + 0.01


F1234yf + 0.17
F1234yf + 0.01
F1234yf + 0.95
F1234yf + 0.01
F1234yf + 0.01
F1234yf + 0.01
F1234yf + 0.01


F245cb +
F245cb +
F245cb +
F245cb +
F245cb +
F245cb +
F245cb +


0.17 F1243zf + 0.17
0.01 F1243zf + 0.01
0.01 F1243zf + 0.01
0.95 F1243zf + 0.01
0.01 F1243zf + 0.95
0.01 F1243zf + 0.01
0.01 F1243zf + 0.01


F1233zdE + 0.17 F1234zeZ
F1233zdE + 0.01 F1234zeZ
F1233zdE + 0.01 F1234zeZ
F1233zdE + 0.01 F1234zeZ
F1233zdE + 0.01 F1234zeZ
F1233zdE + 0.95 F1234zeZ
F1233zdE + 0.01 F1234zeZ





















TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL


MASSFR
PRESSU
MASSFR
PRESSU
MASSFR
PRESSU
MASSF
PRESSU
MASSF
PRESSU
MASSF
PRESSU
MASSF
PRESSU


HF
bar
HF
bar
HF
bar
HF
bar
HF
bar
HF
bar
HF
bar





0
3.8
0
6.6
0
4.6
0
5.7
0
1.5
0
1.9
0
1.7


0.05
4.9
0.05
7.6
0.05
5.8
0.05
6.7
0.05
2.6
0.05
3.0
0.05
2.8


0.1
4.9
0.1
7.6
0.1
5.8
0.1
6.7
0.1
2.6
0.1
3.0
0.1
2.8


0.15
4.9
0.15
7.6
0.15
5.8
0.15
6.7
0.15
2.6
0.15
3.0
0.15
2.8


0.2
4.9
0.2
7.6
0.2
5.8
0.2
6.7
0.2
2.6
0.2
3.0
0.2
2.8


0.25
4.9
0.25
7.6
0.25
5.8
0.25
6.7
0.25
2.6
0.25
3.0
0.25
2.8


0.3
4.9
0.3
7.6
0.3
5.8
0.3
6.7
0.3
2.6
0.3
3.0
0.3
2.8


0.35
4.9
0.35
7.6
0.35
5.8
0.35
6.7
0.35
2.6
0.35
3.0
0.35
2.8


0.4
4.9
0.4
7.6
0.4
5.8
0.4
6.7
0.4
2.6
0.4
3.0
0.4
2.8


0.45
4.9
0.45
7.6
0.45
5.8
0.45
6.7
0.45
2.6
0.45
3.0
0.45
2.8


0.5
4.9
0.5
7.6
0.5
5.8
0.5
6.7
0.5
2.6
0.5
3.0
0.5
2.8


0.55
4.9
0.55
7.6
0.55
5.8
0.55
6.7
0.55
2.6
0.55
3.0
0.55
2.8


0.6
4.9
0.6
7.6
0.6
5.8
0.6
6.6
0.6
2.6
0.6
3.0
0.6
2.8


0.65
4.9
0.65
7.6
0.65
5.8
0.65
6.6
0.65
2.6
0.65
3.0
0.65
2.8


0.7
4.9
0.7
7.6
0.7
5.8
0.7
6.5
0.7
2.6
0.7
3.0
0.7
2.8


0.75
4.9
0.75
7.4
0.75
5.8
0.75
6.3
0.75
2.6
0.75
3.0
0.75
2.8


0.8
4.7
0.8
7.1
0.8
5.8
0.8
6.0
0.8
2.5
0.8
2.9
0.8
2.7


0.85
4.3
0.85
6.5
0.85
5.8
0.85
5.5
0.85
2.3
0.85
2.7
0.85
2.5


0.9
3.7
0.9
5.5
0.9
5.0
0.9
4.7
0.9
2.0
0.9
2.4
0.9
2.2


0.95
2.7
0.95
3.8
0.95
3.5
0.95
3.3
0.95
1.7
0.95
1.9
0.95
1.8


1
1.2
1
1.2
1
1.2
1
1.2
1
1.2
1
1.2
1
1.2










HF - HCFO-1233xf - HFO-1234yf - HFC-245cb -HFO-1234zeE - HFO-1234zeZ - HFO-1243zf













Organics
Organics
Organics
Organics
Organics
Organics
Organics


0.15 F1233xf + 0.17
0.01 F1233xf + 0.95
0.01 F1233xf + 0.01
0.01 F1233xf + 0.01
0.01 F1233xf + 0.01
0.01 F1233xf + 0.01
0.95 F1233xf + 0.01


F1234yf + 0.17
F1234yf + 0.01
F1234yf + 0.95
F1234yf + 0.01
F1234yf + 0.01
F1234yf + 0.01
F1234yf + 0.01


F245cb +
F245cb +
F245cb +
F245cb +
F245cb +
F245cb +
F245cb +


0.17 F1243zf + 0.17
0.01 F1243zf + 0.01
0.01 F1243zf + 0.01
0.95 F1243zf + 0.01
0.01 F1243zf + 0.95
0.01 F1243zf + 0.01
0.01 F1243zf + 0.01


F1234zeE + 0.17 F1234zeZ
F1234zeE + 0.01 F1234zeZ
F1234zeE + 0.01 F1234zeZ
F1234zeE + 0.01 F1234zeZ
F1234zeE + 0.01 F1234zeZ
F1234zeE + 0.95 F1234zeZ
F1234zeE + 0.01 F1234zeZ





















TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL


MASSFR
PRESSU
MASSFR
PRESSU
MASSFR
PRESSU
MASSF
PRESSU
MASSF
PRESSU
MASSF
PRESSU
MASSF
PRESSU


HF
bar
HF
bar
HF
bar
HF
bar
HF
bar
HF
bar
HF
bar





0
4.4
0
6.6
0
4.6
0
5.8
0
4.8
0
2.0
0
1.7


0.05
5.5
0.05
7.6
0.05
5.8
0.05
6.7
0.05
5.8
0.05
3.1
0.05
2.8


0.1
5.5
0.1
7.6
0.1
5.8
0.1
6.7
0.1
5.8
0.1
3.1
0.1
2.8


0.15
5.5
0.15
7.6
0.15
5.8
0.15
6.7
0.15
5.8
0.15
3.1
0.15
2.8


0.2
5.5
0.2
7.6
0.2
5.8
0.2
6.7
0.2
5.8
0.2
3.1
0.2
2.8


0.25
5.5
0.25
7.6
0.25
5.8
0.25
6.7
0.25
5.8
0.25
3.1
0.25
2.8


0.3
5.5
0.3
7.6
0.3
5.8
0.3
6.7
0.3
5.8
0.3
3.1
0.3
2.8


0.35
5.5
0.35
7.6
0.35
5.8
0.35
6.7
0.35
5.8
0.35
3.1
0.35
2.8


0.4
5.5
0.4
7.6
0.4
5.8
0.4
6.7
0.4
5.8
0.4
3.1
0.4
2.8


0.45
5.5
0.45
7.6
0.45
5.8
0.45
6.7
0.45
5.8
0.45
3.1
0.45
2.8


0.5
5.5
0.5
7.6
0.5
5.8
0.5
6.7
0.5
5.8
0.5
3.1
0.5
2.8


0.55
5.5
0.55
7.6
0.55
5.8
0.55
6.7
0.55
5.7
0.55
3.1
0.55
2.8


0.6
5.5
0.6
7.6
0.6
5.8
0.6
6.7
0.6
5.6
0.6
3.1
0.6
2.8


0.65
5.5
0.65
7.6
0.65
5.8
0.65
6.6
0.65
5.5
0.65
3.1
0.65
2.8


0.7
5.5
0.7
7.6
0.7
5.8
0.7
6.5
0.7
5.4
0.7
3.1
0.7
2.8


0.75
5.3
0.75
7.4
0.75
5.8
0.75
6.3
0.75
5.1
0.75
3.1
0.75
2.8


0.8
5.1
0.8
7.1
0.8
5.8
0.8
6.1
0.8
4.8
0.8
2.9
0.8
2.7


0.85
4.6
0.85
6.5
0.85
5.8
0.85
5.6
0.85
4.3
0.85
2.7
0.85
2.5


0.9
3.9
0.9
5.5
0.9
5.0
0.9
4.7
0.9
3.6
0.9
2.4
0.9
2.2


0.95
2.8
0.95
3.8
0.95
3.5
0.95
3.4
0.95
2.6
0.95
1.9
0.95
1.8


1
1.2
1
1.2
1
1.2
1
1.2
1
1.2
1
1.2
1
1.2










HF - HCFO-1233xf - HFO-1234yf - HCFO-1233zdE -HFO-1234zeE 5 - HFO-1234zeZ - HFO-1243zf













Organics
Organics
Organics
Organics
Organics
Organics
Organics


0.15 F1233xf + 0.17
0.01 F1233xf + 0.95
0.01 F1233xf + 0.01
0.01 F1233xf + 0.01
0.01 F1233xf + 0.01
0.01 F1233xf + 0.01
0.95 F1233xf + 0.01


F1234yf + 0.17
F1234yf + 0.01
F1234yf + 0.95
F1234yf + 0.01
F1234yf + 0.01
F1234yf + 0.01
F1234yf + 0.01


F1233zdE +
F1233zdE +
F1233zdE +
F1233zdE +
F1233zdE +
F1233zdE +
F1233zdE +


0.17 F1243zf + 0.17
0.01 F1243zf + 0.01
0.01 F1243zf + 0.01
0.95 F1243zf + 0.01
0.01 F1243zf + 0.95
0.01 F1243zf + 0.01
0.01 F1243zf + 0.01


F1234zeE + 0.17 F1234zeZ
F1234zeE + 0.01 F1234zeZ
F1234zeE + 0.01 F1234zeZ
F1234zeE + 0.01 F1234zeZ
F1234zeE + 0.01 F1234zeZ
F1234zeE + 0.95 F1234zeZ
F1234zeE + 0.01 F1234zeZ





















TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL


MASSFR
PRESSU
MASSFR
PRESSU
MASSFR
PRESSU
MASSF
PRESSU
MASSF
PRESSU
MASSF
PRESSU
MASSF
PRESSU


HF
bar
HF
bar
HF
bar
HF
bar
HF
bar
HF
bar
HF
bar





0
3.9
0
6.6
0
1.5
0
5.7
0
4.8
0
1.9
0
1.7


0.05
5.0
0.05
7.6
0.05
2.6
0.05
6.7
0.05
5.8
0.05
3.0
0.05
2.8


0.1
4.9
0.1
7.6
0.1
2.6
0.1
6.7
0.1
5.8
0.1
3.0
0.1
2.8


0.15
4.9
0.15
7.6
0.15
2.6
0.15
6.7
0.15
5.8
0.15
3.0
0.15
2.8


0.2
4.9
0.2
7.6
0.2
2.6
0.2
6.7
0.2
5.8
0.2
3.0
0.2
2.8


0.25
4.9
0.25
7.6
0.25
2.6
0.25
6.7
0.25
5.8
0.25
3.0
0.25
2.8


0.3
4.9
0.3
7.6
0.3
2.6
0.3
6.7
0.3
5.8
0.3
3.0
0.3
2.8


0.35
4.9
0.35
7.6
0.35
2.6
0.35
6.7
0.35
5.8
0.35
3.0
0.35
2.8


0.4
4.9
0.4
7.6
0.4
2.6
0.4
6.7
0.4
5.8
0.4
3.0
0.4
2.8


0.45
4.9
0.45
7.6
0.45
2.6
0.45
6.7
0.45
5.8
0.45
3.0
0.45
2.8


0.5
4.9
0.5
7.6
0.5
2.6
0.5
6.7
0.5
5.7
0.5
3.0
0.5
2.8


0.55
4.9
0.55
7.6
0.55
2.6
0.55
6.7
0.55
5.7
0.55
3.0
0.55
2.8


0.6
4.9
0.6
7.6
0.6
2.6
0.6
6.6
0.6
5.6
0.6
3.0
0.6
2.8


0.65
4.9
0.65
7.6
0.65
2.6
0.65
6.6
0.65
5.5
0.65
3.0
0.65
2.8


0.7
4.8
0.7
7.6
0.7
2.6
0.7
6.5
0.7
5.3
0.7
3.0
0.7
2.8


0.75
4.7
0.75
7.4
0.75
2.6
0.75
6.3
0.75
5.1
0.75
3.0
0.75
2.8


0.8
4.4
0.8
7.1
0.8
2.5
0.8
6.0
0.8
4.8
0.8
2.9
0.8
2.6


0.85
4.0
0.85
6.5
0.85
2.3
0.85
5.5
0.85
4.3
0.85
2.7
0.85
2.5


0.9
3.4
0.9
5.5
0.9
2.0
0.9
4.7
0.9
3.6
0.9
2.4
0.9
2.2


0.95
2.5
0.95
3.8
0.95
1.7
0.95
3.3
0.95
2.6
0.95
1.9
0.95
1.8


1
1.2
1
1.2
1
1.2
1
1.2
1
1.2
1
1.2
1
1.2










HF - HCFO-1233xf - HCFC-244bb- HFC-245fa - Trifluoropropyne- HFO-1225yeZ-HFO-1225zc















Organics 0.15 F1233xf +
Organics 0.95 F1233xf +
Organics 0.01 F1233xf +
Organics 0.01 F1233xf +
Organics 0.01 F1233xf +
Organics 0.01 F1233xf +
Organics 0.01F1233xf +



0.17 F244bb +
0.01 F244bb +
0.95 F244bb +
0.01 F244bb +
0.01 F244bb +
0.01 F244bb +
0.01 F244bb +



0.17 F245fa +
0.01 F245fa +
0.01 F245fa +
0.95 F245fa +
0.01 F245fa +
0.01 F245fa +
0.01 F245fa +



0.17TFP +
0.01 TFP +
0.01 TFP +
0.01 TFP +
0.95 TFP +
0.01 TFP +
0.01 TFP +



0.17 F1225yeZ +
0.01 F1225yeZ +
0.01 F1225yeZ +
0.01 F1225yeZ +
0.01 F1225yeZ +
0.95 F1225yeZ +
0.01 F1225yeZ +



0.17 F1225zc
0.01 F1225zc
0.01 F1225zc
0.01 F1225zc
0.01 F1225zc
0.01 F1225zc
0.95 F1225zc



TOTAL
TOTAL
TOTAL
TOTAL
TOTAL
TOTAL
TOTAL


MASSFRAC
PRESSURE
PRESSURE
PRESSURE
PRESSURE
PRESSURE
PRESSURE
PRESSURE


HF
bar
bar
bar
bar
bar
bar
bar





0
4.8
1.8
0.9
1.7
11.3
5.1
5.3


0.05
5.9
2.9
2.1
2.8
12.1
6.2
6.3


0.1
5.9
2.9
2.1
2.8
12.0
6.2
6.3


0.15
5.9
2.9
2.1
2.8
11.9
6.2
6.3


0.2
5.9
2.9
2.1
2.8
11.8
6.2
6.3


0.25
5.9
2.9
2.1
2.8
11.7
6.2
6.3


0.3
5.8
2.9
2.1
2.8
11.6
6.2
6.2


0.35
5.8
2.9
2.1
2.8
11.5
6.2
6.2


0.4
5.8
2.9
2.1
2.8
11.5
6.2
6.2


0.45
5.8
2.9
2.0
2.8
11.4
6.2
6.2


0.5
5.8
2.9
2.0
2.8
11.5
6.2
6.2


0.55
5.7
2.8
2.0
2.8
11.5
6.2
6.2


0.6
5.7
2.8
2.0
2.8
11.5
6.2
6.1


0.65
5.6
2.8
2.0
2.8
11.5
6.2
6.0


0.7
5.6
2.8
2.0
2.8
11.5
6.1
5.8


0.75
5.5
2.8
2.0
2.8
11.5
5.9
5.6


0.8
5.2
2.7
2.0
2.7
11.3
5.6
5.2


0.85
4.7
2.5
2.0
2.5
10.5
5.0
4.6


0.9
4.0
2.2
1.8
2.2
8.9
4.2
3.8


0.95
2.8
1.8
1.6
1.8
6.0
3.0
2.7


1
1.2
1.2
1.2
1.2
1.2
1.2
1.2









Example 14: Temperature and Pressure Range of System with 7 Compounds













Boiling point range










Temperature
Pressure


System with 7 compounds
° C.
bar abs





HF-HCFO-1233xf-HFO-1234yf-HFC-245cb-HCFO-
0 to 40
~0.9 ~11.5


1233zdE-HFO- 1234zeE-HFO-1234zeZ


HF-HCFO-1233xf-HFO-1234yf-HFC-245cb-HCFO-
0 to 40
~1.0 to ~11.6


1233zdE-HFO- 1234zeE-HFO-1243zf


HF-HCFO-1233xf-HFO-1234yf-HFC-245cb-HCFO-
0 to 40
~0.9 to ~11.5


1233zdE-HFO- 1234zeZ-HFO-1243zf


HF-HCFO-1233xf-HFO-1234yf-HFC-245cb-HFO-
0 to 40
~1.1 to ~11.6


1234zeE-HFO- 1234zeZ-HFO-1243zf


HF-HCFO-1233xf-HFO-1234yf-HCFO-1233zdE-HFO-
0 to 40
~0.9 to ~11.5


1234zeE-HFO- 1234zeZ-HFO-1243zf


HF-HCFO-1233xf-HFC-245cb-HCFO-1233zdE-HFO-
0 to 40
~0.9 to ~10.3


1234zeE-HFO- 1234zeZ-HFO-1243zf


HF - HCFO-1233xf-HCFC-244bb-HFC-245fa -
0 to 40
~0.7 to ~17.5


Trifluoropropyne- HFO-1225yeZ-HFO-1225zc









Example 15: Decantation Range of System with 7 Compounds













Decantation ranges



Mass percentage of HF











Temp
Temp



System with 7 compounds
0° C.
25° C.
Temp 40° C.





HF-HCFO-1233xf-HFO-1234yf-HFC-245cb-HCFO-
5-75
 5-70
10-60


1233zdE- HFO-1234zeE-HFO-1234zeZ


HF-HCFO-1233xf-HFO-1234yf-HFC-245cb-HCFO-
5-75
10-65
20


1233zdE- HFO-1234zeE-HFO-1243zf


HF-HCFO-1233xf-HFO-1234yf-HFC-245cb-HCFO-
5-70
 5-70
10-60


1233zdE- HFO-1234zeZ-HFO-1243zf


HF-HCFO-1233xf-HFO-1234yf-HFC-245cb-HFO-
5-75
10-65
*


1234zeE-HFO- 1234zeZ-HFO-1243zf


HF-HCFO-1233xf-HFO-1234yf-HCFO-1233zdE-HFO-
5-75
10-65
15-45


1234zeE- HFO-1234zeZ-HFO-1243zf


HF-HCFO-1233xf-HFC-245cb-HCFO-1233zdE-HFO-
5-75
 5-70
10-55


1234zeE- HFO-1234zeZ-HFO-1243zf


HF - HCFO-1233xf - HCFC-244bb- HFC-245fa -
1-80
20-99
 5-75


Trifluoropropyne- HFO-1225yeZ-HFO-1225zc









Example 16: Systems with 8 Compounds












HF - HCFO-1233xf - HFO-1234yf - HFC-245cb - HCFO-1233zdE 5-HFO-1234zeE - HFO-1234zeZ - HFO-1243zf


























Organics

Organics







Organics

Organics

Organics

0.01 F1233xf +

0.01 F1233xf +

Organics

Organics


0.01 F1233xf +

0.01 F1233xf +

0.01 F1233xf +

0.01 F1234yf +

0.01 F1234yf +

0.01 F1233xf +

0.16 F1233xf +


0.94 F1234yf +

0.01 F1234yf +

0.01 F1234yf +

0.01 F245cb +

0.01 F245cb +

0.01 F1234yf +

0.14 F1234yf +


0.01 F245cb +

0.94 F245cb +

0.01 F245cb +

0.01 F1233zdE +

0.01 F1233zdE +

0.01 F245cb +

0.14 F245cb +


0.01 F1233zdE +

0.01 F1233zdE +

0.94 F1233zdE +

0.94

0.01

0.01 F1233zdE +

0.14 F1233zdE +


0.01 F1234zeE +

0.01 F1234zeE +

0.01 F1234zeE +

F1234zeE + 0.01

F1234zeE + 0.94

0.01 F1234zeE +

0.14 F1234zeE +


0.01 F1234zeZ +

0.01 F1234zeZ +

0.01 F1234zeZ +

F1234zeZ + 0.01

F1234zeZ + 0.01

0.01 F1234zeZ +

0.14 F1234zeZ +


0.01 F1243zf

0.01 F1243zf

0.01 F1243zf

F1243zf

F1243zf

0.94 F1243zf

0.14 F1243zf





















TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL


MASSFR
PRESSU
MASSFR
PRESSU
MASSFR
PRESSU
MASSFR
PRESSU
MASSFR
PRESSU
MASSFR
PRESSU
MASSFR
PRESSU


HF
bar
HF
bar
HF
bar
HF
bar
HF
bar
HF
bar
HF
bar





0
6.6
0
4.6
0
1.5
0
4.8
0
2.0
0
5.7
0
3.9


0.05
7.6
0.05
5.8
0.05
2.6
0.05
5.8
0.05
3.1
0.05
6.7
0.05
5.0


0.1
7.6
0.1
5.8
0.1
2.6
0.1
5.8
0.1
3.1
0.1
6.7
0.1
5.0


0.15
7.6
0.15
5.8
0.15
2.6
0.15
5.8
0.15
3.1
0.15
6.7
0.15
5.0


0.2
7.6
0.2
5.8
0.2
2.6
0.2
5.8
0.2
3.1
0.2
6.7
0.2
5.0


0.25
7.6
0.25
5.8
0.25
2.6
0.25
5.8
0.25
3.1
0.25
6.7
0.25
5.0


0.3
7.6
0.3
5.8
0.3
2.6
0.3
5.8
0.3
3.1
0.3
6.7
0.3
5.0


0.35
7.6
0.35
5.8
0.35
2.6
0.35
5.8
0.35
3.1
0.35
6.7
0.35
5.0


0.4
7.6
0.4
5.8
0.4
2.6
0.4
5.8
0.4
3.1
0.4
6.7
0.4
5.0


0.45
7.6
0.45
5.8
0.45
2.6
0.45
5.8
0.45
3.1
0.45
6.7
0.45
5.0


0.5
7.6
0.5
5.8
0.5
2.6
0.5
5.7
0.5
3.1
0.5
6.7
0.5
5.0


0.55
7.6
0.55
5.8
0.55
2.6
0.55
5.7
0.55
3.1
0.55
6.7
0.55
5.0


0.6
7.6
0.6
5.8
0.6
2.6
0.6
5.6
0.6
3.1
0.6
6.6
0.6
5.0


0.65
7.6
0.65
5.8
0.65
2.6
0.65
5.5
0.65
3.1
0.65
6.6
0.65
5.0


0.7
7.5
0.7
5.8
0.7
2.6
0.7
5.4
0.7
3.1
0.7
6.5
0.7
5.0


0.75
7.4
0.75
5.8
0.75
2.6
0.75
5.1
0.75
3.1
0.75
6.3
0.75
4.9


0.8
7.1
0.8
5.8
0.8
2.5
0.8
4.8
0.8
2.9
0.8
6.0
0.8
4.6


0.85
6.5
0.85
5.8
0.85
2.3
0.85
4.3
0.85
2.7
0.85
5.5
0.85
4.2


0.9
5.5
0.9
5.0
0.9
2.1
0.9
3.6
0.9
2.4
0.9
4.7
0.9
3.6


0.95
3.8
0.95
3.5
0.95
1.7
0.95
2.6
0.95
1.9
0.95
3.3
0.95
2.6


1
1.2
1
1.2
1
1.2
1
1.2
1
1.2
1
1.2
1
1.2










HF-HFO-1234yf-HFC-245cb-HCFO-1233xf-HFO-1234zeE-HFO-1234zeZ-HCFO-1233zdE-HCFC-244bb
















Organics 0.94
Organics 0.01
Organics 0.01
Organics 0.01
Organics 0.01
Organics 0.01
Organics 0.01
Organics 0.16



F1233xf +
F1233xf +
F1233xf +
F1233xf +
F1233xf +
F1233xf +
F1233xf +
F1233xf +



0.01 F1234yf +
0.94 F1234yf +
0.01 F1234yf +
0.01 F1234yf +
0.01 F1234yf +
0.01 F1234yf +
0.01 F1234yf +
0.14 F1234yf +



0.01 F245cb + 0.01
0.01 F245cb + 0.01
0.94 F245cb + 0.01
0.01 F245cb + 0.94
0.01 F245cb + 0.01
0.01 F245cb + 0.01
0.01 F245cb + 0.01
0.14 F245cb + 0.14



F1233zdE +
F1233zdE +
F1233zdE +
F1233zdE +
F1233zdE +
F1233zdE +
F1233zdE +
F1233zdE +



0.01 F1234zeE +
0.01 F1234zeE +
0.01 F1234zeE +
0.01 F1234zeE +
0.94 F1234zeE +
0.01 F1234zeE +
0.01 F1234zeE +
0.14 F1234zeE +



0.01 F1234zeZ +
0.01 F1234zeZ +
0.01 F1234zeZ +
0.01 F1234zeZ +
0.01 F1234zeZ +
0.94 F1234zeZ +
0.01 F1234zeZ +
0.14 F1234zeZ +



0.01 F244bb
0.01 F244bb
0.01 F244bb
0.01 F244bb
0.01 F244bb
0.01 F244bb
0.94 F244bb
0.14 F244bb



TOTAL
TOTAL
TOTAL
TOTAL
TOTAL
TOTAL
TOTAL
TOTAL


MASSFRA
PRESSURE
PRESSURE
PRESSURE
PRESSURE
PRESSURE
PRESSURE
PRESSURE
PRESSURE


HF
bar
bar
bar
bar
bar
bar
bar
bar





0
1.7
6.6
4.5
1.5
4.8
1.9
0.8
3.2


0.05
2.8
7.5
5.7
2.6
5.7
3.0
2.0
4.3


0.1
2.8
7.5
5.7
2.6
5.7
3.0
2.0
4.3


0.15
2.8
7.5
5.7
2.6
5.7
3.0
2.0
4.3


0.2
2.8
7.5
5.7
2.6
5.7
3.0
2.0
4.3


0.25
2.8
7.5
5.7
2.6
5.7
3.0
2.0
4.3


0.3
2.8
7.5
5.7
2.6
5.7
3.0
2.0
4.3


0.35
2.8
7.5
5.7
2.6
5.7
3.0
2.0
4.3


0.4
2.8
7.5
5.7
2.6
5.7
3.0
2.0
4.3


0.45
2.8
7.5
5.7
2.6
5.7
3.0
2.0
4.3


0.5
2.8
7.5
5.7
2.6
5.7
3.0
2.0
4.3


0.55
2.8
7.5
5.7
2.6
5.6
3.0
2.0
4.2


0.6
2.8
7.5
5.7
2.6
5.6
3.0
2.0
4.2


0.65
2.8
7.5
5.7
2.6
5.5
3.0
2.0
4.2


0.7
2.8
7.5
5.7
2.6
5.3
3.0
2.0
4.2


0.75
2.8
7.4
5.7
2.6
5.1
3.0
1.9
4.2


0.8
2.6
7.0
5.7
2.4
4.7
2.9
1.9
4.0


0.85
2.4
6.5
5.7
2.3
4.3
2.7
1.9
3.7


0.9
2.2
5.4
4.9
2.0
3.6
2.4
1.8
3.2


0.95
1.8
3.8
3.5
1.7
2.6
1.9
1.6
2.4


1
1.2
1.2
1.2
1.2
1.2
1.2
1.2
1.2










HF-HFO-1234yf-HFC-245cb-HCFO-1233xf-HFO-1234zeE-5 HFO-1234zeZ-HCFO-1233zdE-Trifluoropropyne
















Organics

Organics



Organics




0.16 F1234yf +
Organics 0.94 F1234yf +
0.01 F1234yf +
Organics 0.01 F1234yf +
Organics 0.01 F1234yf +
Organics 0.01 F1234yf +
0.01 F1234yf +
Organics 0.01 F1234yf +



0.14 F245cb +
0.01 F245cb +
0.94 F245cb +
0.01 F245cb +
0.01 F245cb +
0.01 F245cb +
0.01 F245cb +
0.01 F245cb +



0.14 F1233xf +
0.01 F1233xf +
0.01 F1233xf +
0.94 F1233xf +
0.01 F1233xf +
0.01 F1233xf +
0.01 F1233xf +
0.01 F1233xf +



0.14 F1234zeE +
0.01 F1234zeE +
0.01 F1234zeE +
0.01 F1234zeE +
0.94 F1234zeE +
0.01 F1234zeE +
0.01 F1234zeE +
0.01 F1234zeE +



0.14 F1234zeZ +
0.01 F1234zeZ +
0.01 F1234zeZ +
0.01 F1234zeZ +
0.01 F1234zeZ +
0.94 F1234zeZ +
0.01 F1234zeZ +
0.01 F1234zeZ +



0.14 F1233zdE
0.01 F1233zdE
0.01 F1233zdE
0.01 F1233zdE
0.01 F1233zdE
0.01 F1233zdE
0.94 F1233zdE
0.01 F1233zdE



TOTAL
TOTAL
TOTAL
TOTAL
TOTAL
TOTAL
TOTAL
TOTAL


MASSFRA
PRESSURE
PRESSURE
PRESSURE
PRESSURE
PRESSURE
PRESSURE
PRESSURE
PRESSURE


HF
bar
bar
bar
bar
bar
bar
bar
bar





0
5.0
6.7
4.7
1.8
4.9
2.0
1.6
11.2


0.05
6.0
7.6
5.8
2.9
5.8
3.1
2.7
12.0


0.1
6.0
7.6
5.8
2.9
5.9
3.1
2.7
11.9


0.15
6.0
7.6
5.8
2.9
5.9
3.1
2.7
11.8


0.2
6.0
7.6
5.8
2.9
5.9
3.1
2.7
11.7


0.25
6.0
7.6
5.8
2.9
5.8
3.1
2.7
11.6


0.3
6.0
7.6
5.8
2.9
5.8
3.1
2.7
11.5


0.35
6.0
7.6
5.8
2.9
5.8
3.1
2.7
11.5


0.4
6.0
7.6
5.8
2.9
5.8
3.1
2.7
11.4


0.45
6.0
7.6
5.8
2.9
5.8
3.1
2.7
11.4


0.5
6.0
7.6
5.8
2.9
5.8
3.1
2.7
11.4


0.55
6.0
7.6
5.8
2.9
5.8
3.1
2.7
11.5


0.6
6.0
7.6
5.8
2.9
5.7
3.1
2.7
11.5


0.65
6.0
7.6
5.8
2.9
5.6
3.1
2.7
11.5


0.7
6.0
7.6
5.8
2.9
5.4
3.1
2.7
11.5


0.75
5.9
7.5
5.8
2.9
5.2
3.1
2.7
11.5


0.8
5.6
7.1
5.8
2.8
4.9
3.0
2.6
11.2


0.85
5.1
6.6
5.8
2.6
4.4
2.8
2.4
10.4


0.9
4.3
5.5
5.0
2.2
3.6
2.4
2.1
8.8


0.95
3.1
3.8
3.5
1.8
2.6
1.9
1.7
5.9


1
1.2
1.2
1.2
1.2
1.2
1.2
1.2
1.2










HF-HFO-1234yf-HFC-245cb-HCFO-1233xf-HFO-1234zeE-HFO-1234zeZ-HCFO- 1233zdE-HFC-245fa
















Organics

Organics



Organics




0.16 F1234yf +
Organics 0.94 F1234yf +
0.01 F1234yf +
Organics 0.01 F1234yf +
Organics 0.01 F1234yf +
Organics 0.01 F1234yf +
0.01 F1234yf +
Organics 0.01 F1234yf +



0.14 F245cb +
0.01 F245cb +
0.94 F245cb +
0.01 F245cb +
0.01 F245cb +
0.01 F245cb +
0.01 F245cb +
0.01 F245cb +



0.14 F1233xf +
0.01 F1233xf +
0.01 F1233xf +
0.94 F1233xf +
0.01 F1233xf +
0.01 F1233xf +
0.01 F1233xf +
0.01 F1233xf +



0.14 F1234zeE +
0.01 F1234zeE +
0.01 F1234zeE +
0.01 F1234zeE +
0.94 F1234zeE +
0.01 F1234zeE +
0.01 F1234zeE +
0.01 F1234zeE +



0.14 F1234zeZ +
0.01 F1234zeZ +
0.01 F1234zeZ +
0.01 F1234zeZ +
0.01 F1234zeZ +
0.94 F1234zeZ +
0.01 F1234zeZ +
0.01 F1234zeZ +



0.14 F1233zdE
0.01 F1233zdE
0.01 F1233zdE
0.01 F1233zdE
0.01 F1233zdE
0.01 F1233zdE
0.94 F1233zdE
0.01 F1233zdE



TOTAL
TOTAL
TOTAL
TOTAL
TOTAL
TOTAL
TOTAL
TOTAL


MASSFRA
PRESSURE
PRESSURE
PRESSURE
PRESSURE
PRESSURE
PRESSURE
PRESSURE
PRESSURE


HF
bar
bar
bar
bar
bar
bar
bar
bar





0
3.4
6.6
4.5
1.7
4.8
1.9
1.5
1.6


0.05
4.5
7.5
5.7
2.8
5.7
3.0
2.6
2.8


0.1
4.5
7.5
5.7
2.8
5.7
3.0
2.6
2.8


0.15
4.5
7.5
5.7
2.8
5.7
3.0
2.6
2.8


0.2
4.5
7.5
5.7
2.8
5.7
3.0
2.6
2.8


0.25
4.5
7.5
5.7
2.8
5.7
3.0
2.6
2.8


0.3
4.5
7.5
5.7
2.8
5.7
3.0
2.6
2.8


0.35
4.5
7.5
5.7
2.8
5.7
3.0
2.6
2.8


0.4
4.5
7.5
5.7
2.8
5.7
3.0
2.6
2.8


0.45
4.5
7.5
5.7
2.8
5.7
3.0
2.6
2.8


0.5
4.5
7.5
5.7
2.8
5.7
3.0
2.6
2.8


0.55
4.5
7.5
5.7
2.8
5.6
3.0
2.6
2.8


0.6
4.5
7.5
5.7
2.8
5.6
3.0
2.6
2.8


0.65
4.5
7.5
5.7
2.8
5.5
3.0
2.6
2.8


0.7
4.5
7.5
5.7
2.8
5.3
3.0
2.6
2.8


0.75
4.4
7.4
5.7
2.8
5.1
3.0
2.6
2.8


0.8
4.2
7.1
5.8
2.6
4.7
2.9
2.5
2.7


0.85
3.9
6.5
5.7
2.5
4.3
2.7
2.3
2.5


0.9
3.3
5.4
4.9
2.2
3.6
2.4
2.0
2.2


0.95
2.4
3.8
3.5
1.8
2.6
1.9
1.7
1.8


1
1.2
1.2
1.2
1.2
1.2
1.2
1.2
1.2










HF-HFO-1234yf-HFC-245cb-HCFO-1233xf-HFO-1234zeE-5 HFO-1234zeZ-HCFO-1233zdE-HFO-1225yeZ
















Organics

Organics



Organics




0.16 F1234yf +
Organics 0.94 F1234yf +
0.01 F1234yf +
Organics 0.01 F1234yf +
Organics 0.01 F1234yf +
Organics 0.01 F1234yf +
0.01 F1234yf +
Organics 0.01 F1234yf +



0.14 F245cb +
0.01 F245cb +
0.94 F245cb +
0.01 F245cb +
0.01 F245cb +
0.01 F245cb +
0.01 F245cb +
0.01 F245cb +



0.14 F1233xf +
0.01 F1233xf +
0.01 F1233xf +
0.94 F1233xf +
0.01 F1233xf +
0.01 F1233xf +
0.01 F1233xf +
0.01 F1233xf +



0.14 F1234zeE +
0.01 F1234zeE +
0.01 F1234zeE +
0.01 F1234zeE +
0.94 F1234zeE +
0.01 F1234zeE +
0.01 F1234zeE +
0.01 F1234zeE +



0.14 F1234zeZ +
0.01 F1234zeZ +
0.01 F1234zeZ +
0.01 F1234zeZ +
0.01 F1234zeZ +
0.94 F1234zeZ +
0.01 F1234zeZ +
0.01 F1234zeZ +



0.14 F1233zdE
0.01 F1233zdE
0.01 F1233zdE
0.01 F1233zdE
0.01 F1233zdE
0.01 F1233zdE
0.94 F1233zdE
0.01 F1233zdE



TOTAL
TOTAL
TOTAL
TOTAL
TOTAL
TOTAL
TOTAL
TOTAL


MASSFRA
PRESSURE
PRESSURE
PRESSURE
PRESSURE
PRESSURE
PRESSURE
PRESSURE
PRESSURE


HF
bar
bar
bar
bar
bar
bar
bar
bar





0
3.8
6.6
4.6
1.7
4.8
1.9
1.5
5.1


0.05
4.9
7.6
5.8
2.8
5.8
3.0
2.6
6.1


0.1
4.9
7.6
5.8
2.8
5.8
3.0
2.6
6.1


0.15
4.9
7.6
5.8
2.8
5.8
3.0
2.6
6.1


0.2
4.9
7.5
5.8
2.8
5.8
3.0
2.6
6.1


0.25
4.9
7.6
5.8
2.8
5.8
3.0
2.6
6.1


0.3
4.9
7.6
5.8
2.8
5.8
3.0
2.6
6.1


0.35
4.9
7.6
5.8
2.8
5.8
3.0
2.6
6.1


0.4
4.9
7.6
5.8
2.8
5.8
3.0
2.6
6.1


0.45
4.9
7.6
5.8
2.8
5.8
3.0
2.6
6.1


0.5
4.9
7.6
5.8
2.8
5.7
3.0
2.6
6.1


0.55
4.9
7.6
5.8
2.8
5.7
3.0
2.6
6.1


0.6
4.9
7.6
5.8
2.8
5.6
3.0
2.6
6.1


0.65
4.9
7.6
5.8
2.8
5.5
3.0
2.6
6.1


0.7
5.0
7.5
5.8
2.8
5.3
3.0
2.6
6.0


0.75
4.8
7.4
5.8
2.8
5.1
3.0
2.6
5.8


0.8
4.6
7.1
5.8
2.7
4.8
2.9
2.5
5.5


0.85
4.2
6.5
5.8
2.5
4.3
2.7
2.3
5.0


0.9
3.6
5.5
4.9
2.2
3.6
2.4
2.1
4.2


0.95
2.6
3.8
3.5
1.8
2.6
1.9
1.7
2.9


1
1.2
1.2
1.2
1.2
1.2
1.2
1.2
1.2










HF-HFO-1234yf-HFC-245cb-HCFO-1233xf-HFO-1234zeE-HFO-1234zeZ-HCFC-1233zdE-HFO-1225zc
















Organics

Organics



Organics




0.16 F1234yf +
Organics 0.94 F1234yf +
0.01 F1234yf +
Organics 0.01 F1234yf +
Organics 0.01 F1234yf +
Organics 0.01 F1234yf +
0.01 F1234yf +
Organics 0.01 F1234yf +



0.14 F245cb +
0.01 F245cb +
0.94 F245cb +
0.01 F245cb +
0.01 F245cb +
0.01 F245cb +
0.01 F245cb +
0.01 F245cb +



0.14 F1233xf +
0.01 F1233xf +
0.01 F1233xf +
0.94 F1233xf +
0.01 F1233xf +
0.01 F1233xf +
0.01 F1233xf +
0.01 F1233xf +



0.14 F1234zeE +
0.01 F1234zeE +
0.01 F1234zeE +
0.01 F1234zeE +
0.94 F1234zeE +
0.01 F1234zeE +
0.01 F1234zeE +
0.01 F1234zeE +



0.14 F1234zeZ +
0.01 F1234zeZ +
0.01 F1234zeZ +
0.01 F1234zeZ +
0.01 F1234zeZ +
0.94 F1234zeZ +
0.01 F1234zeZ +
0.01 F1234zeZ +



0.14 F1233zdE +
0.01 F1233zdE +
0.01 F1233zdE +
0.01 F1233zdE +
0.01 F1233zdE +
0.01 F1233zdE +
0.94 F1233zdE +
0.01 F1233zdE +



0.14 F1225zc
0.01 F1225zc
0.01 F1225zc
0.01 F1225zc
0.01 F1225zc
0.01 F1225zc
0.01 F1225zc
0.94 F1225zc



TOTAL
TOTAL
TOTAL
TOTAL
TOTAL
TOTAL
TOTAL
TOTAL


MASSFRA
PRESSURE
PRESSURE
PRESSURE
PRESSURE
PRESSURE
PRESSURE
PRESSURE
PRESSURE


HF
bar
bar
bar
bar
bar
bar
bar
bar





0
3.9
6.6
4.6
1.7
4.8
1.9
1.5
5.2


0.05
4.9
7.6
5.8
2.8
5.8
3.0
2.6
6.2


0.1
4.9
7.6
5.8
2.8
5.8
3.0
2.6
6.2


0.15
4.9
7.6
5.8
2.8
5.8
3.0
2.6
6.2


0.2
4.9
7.6
5.8
2.8
5.8
3.0
2.6
6.2


0.25
4.9
7.6
5.8
2.8
5.8
3.0
2.6
6.2


0.3
4.9
7.6
5.8
2.8
5.8
3.0
2.6
6.2


0.35
4.9
7.6
5.8
2.8
5.8
3.0
2.6
6.2


0.4
4.9
7.6
5.8
2.8
5.8
3.0
2.6
6.2


0.45
4.9
7.6
5.8
2.8
5.8
3.0
2.6
6.2


0.5
4.9
7.6
5.8
2.8
5.7
3.0
2.6
6.1


0.55
4.9
7.6
5.8
2.8
5.7
3.0
2.6
6.1


0.6
4.9
7.6
5.8
2.8
5.6
3.0
2.6
6.0


0.65
4.9
7.6
5.8
2.8
5.5
3.0
2.6
5.9


0.7
4.9
7.5
5.8
2.8
5.3
3.0
2.6
5.8


0.75
4.8
7.4
5.8
2.8
5.1
3.0
2.6
5.5


0.8
4.6
7.1
5.8
2.7
4.8
2.9
2.5
5.1


0.85
4.2
6.5
5.8
2.5
4.3
2.7
2.3
4.6


0.9
3.5
5.5
4.9
2.2
3.6
2.4
2.1
3.8


0.95
2.6
3.8
3.5
1.8
2.6
1.9
1.7
2.7


1
1.2
1.2
1.2
1.2
1.2
1.2
1.2
1.2









Example 17: Temperature and Pressure Range of System with 5 to 8 Compounds













Boiling point range










Temperature
Pressure


System with 8 compounds
° C.
bar abs





HF-HCFO-1233xf-HFO-1234yf-HFC-245cb-HCFO-1233zdE-HFO-
0 to 40
~1.0 ~11.5


1234zeE-HFO-1234zeZ-HFO-1243zf


HF-HFO-1234yf-HFC-245cb-HCFO-1233xf-HFO-1234zeE-HFO-
0 to 40
~0.7 to ~11.5


1234zeZ-HCFO-1233zdE-HCFC-244bb


HF-HFO-1234yf-HFC-245cb-HCFO-1233xf-HFO-1234zeE-HFO-
0 to 40
~1.0 to ~17.4


1234zeZ-HCFO-1233zdE-Trifluoropropyne


HF-HFO-1234yf-HFC-245cb-HCFO-1233xf-HFO-1234zeE-HFO-
0 to 40
~0.9 to ~11.5


1234zeZ-HCFO-1233zdE-HFC-245fa


HF-HFO-1234yf-HFC-245cb-HCFO-1233xf-HFO-1234zeE-HFO-
0 to 40
~1.0 to ~11.5


1234zeZ-HCFO-1233zdE-HFO-1225yeZ


HF-HFO-1234yf-HFC-245cb-HCFO-1233xf-HFO-1234zeE-HFO-
0 to 40
~1.0 to ~11.5


1234zeZ-HCFC-1233zdE-HFO-1225zc









Example 18: Decantation Ranges of System with 8 Compounds













Decantation ranges



Mass percentage of HF



Temperature










System with 8 compounds
0° C.
25° C.
40° C.





HF-HCFO-1233xf-HFO-1234yf-HFC-245cb-HCFO-1233zdE-HFO-
  5-75%
  5-70%
  15-50%


1234zeE-HFO-1234zeZ-HFO-1243zf


HF-HFO-1234yf-HFC-245cb-HCFO-1233xf-HFO-1234zeE-HFO-
5-80
5-75
 5-70


1234zeZ-HCFO-1233zdE-HCFC-244bb


HF-HFO-1234yf-HFC-245cb-HCFO-1233xf-HFO-1234zeE-HFO-
5-75
10-65 
*


1234zeZ-HCFO-1233zdE-Trifluoropropyne


HF-HFO-1234yf-HFC-245cb-HCFO-1233xf-HFO-1234zeE-HFO-
5-75
5-70
10-60


1234zeZ-HCFO-1233zdE-HFC-245fa


HF-HFO-1234yf-HFC-245cb-HCFO-1233xf-HFO-1234zeE-HFO-
5-75
5-70
15-55


1234zeZ-HCFO-1233zdE-HFO-1225yeZ


HF-HFO-1234yf-HFC-245cb-HCFO-1233xf-HFO-1234zeE-HFO-
5-75
5-65
15-50


1234zeZ-HCFC-1233zdE-HFO-1225zc









Example 19: Systems with 13 Compounds










HF - HFO-1234yf - HFC-245cb - HCFO-1233xf - HCFO-1233zdE - HFO-1234zeE - HFO-1234zeZ -


HFC-1243zf - HCFC-244bb - TFP - HFC-245fa - HFO-1225yeZ - 5 HFO-1225zc













Organics 0.087







F1234yf + 0.083



Organics



F245cb + 0.083
Organics 0.89 F1234yf +
Organics 0.01 F1234yf +
Organics 0.01 F1234yf +
0.01 F1234yf +



F1233xf + 0.083
0.01 F245cb +
0.01 F245cb +
0.01 F245cb +
0.01 F245cb +



F1233zdE + 0.083
0.01 F1233xf +
0.89 F1233xf +
0.01 F1233xf +
0.01 F1233xf +



F1234zeE + 0.083
0.01 F1233zdE +
0.01 F1233zdE +
0.01 F1233zdE +
0.89 F1233zdE +



F1234zeZ + 0.083
0.01 F1234zeE +
0.01 F1234zeE +
0.89 F1234zeE +
0.01 F1234zeE +



F1243zf + 0.083
0.01 F1234zeZ +
0.01 F1234zeZ +
0.01 F1234zeZ +
0.01 F1234zeZ +



F244bb + 0.083
0.01 F1243zf +
0.01 F1243zf +
0.01 F1243zf +
0.01 F1243zf +



F245fa + 0.083
0.01 F244bb +
0.01 F244bb +
0.01 F244bb +
0.01 F244bb +



TFP + 0.083
0.01 F245fa +
0.01 F245fa +
0.01 F245fa +
0.01 F245fa +



F1225yeZ + 0.83
0.01 TFP + 0.01
0.01 TFP + 0.01
0.01 TFP + 0.01
0.01 TFP + 0.01



F1225zc
F1225yeZ + 0.1 F1225zc
F1225yeZ + 0.1 F1225zc
F1225yeZ + 0.1 F1225zc
F1225yeZ + 0.1



TOTAL
TOTAL
TOTAL
TOTAL
F1225zc TOTAL


MASSFRAC
PRESSURE
PRESSURE
PRESSURE
PRESSURE
PRESSURE


HF
bar
bar
bar
bar
bar















0
4.5
6.5
1.9
4.8
1.7


0.05
5.6
7.5
3.0
5.8
2.9


0.1
5.6
7.5
3.0
5.8
2.9


0.15
5.6
7.5
3.0
5.8
2.8


0.2
5.6
7.5
3.0
5.8
2.8


0.25
5.6
7.5
3.0
5.8
2.8


0.3
5.6
7.5
3.0
5.8
2.8


0.35
5.6
7.5
3.0
5.8
2.8


0.4
5.6
7.5
3.0
5.8
2.8


0.45
5.5
7.5
3.0
5.8
2.8


0.5
5.5
7.5
3.0
5.8
2.8


0.55
5.5
7.5
3.0
5.7
2.8


0.6
5.5
7.5
3.0
5.6
2.8


0.65
5.5
7.5
3.0
5.5
2.8


0.7
5.4
7.5
3.0
5.4
2.8


0.75
5.3
7.3
3.0
5.2
2.8


0.8
5.1
7.0
2.8
4.8
2.7


0.85
4.6
6.4
2.6
4.3
2.5


0.9
3.9
5.4
2.3
3.6
2.2


0.95
2.8
3.7
1.8
2.6
1.8


1
1.2
1.2
1.2
1.2
1.2









Example 20: Temperature and Pressure Range of System with 13 Compounds













Boiling point range










Temperature
Pressure


System with 13 compounds
° C.
bar abs





HF - HFO-1234yf - HFC-245cb - HCFO-
0 to 40
~0.7 ~18.0


1233xf - HCFO-1233zdE - HFO-1234zeE -


HFO-1234zeZ - HFC-1243zf -


HCFC-244bb - TFP - HFC-245fa -


HFO-1225yeZ - HFO-1225zc









Example 21: Decantation Ranges of System with 13 Compounds













Decantation ranges



Mass percentage of HF



Temperature










System with 13 compounds
0° C.
25° C.
40° C.





HF - HFO-1234yf - HFC-245cb -
5-75%
10-70%
15-60%


HCFO-1233xf - HCFO-1233zdE -


HFO-1234zeE - HFO-1234zeZ -


HFC-1243zf - HCFC-244bb- TFP -


HFC-245fa - HFO-1225yeZ - HFO-1225zc

## Claims

1. An azeotropic or quasi-azeotropic composition comprising:
a) hydrogen fluoride;
b) 3,3,3-trifluoro-2-chloropropene;
c) E-3,3,3-trifluoro-1-chloropropene; and
d) optionally, one or more organic compounds selected from the group consisting of E-1,333-tetrafluoropropene, Z-1,3,3,3-tetrafluoropropene, 3,3,3-trifluoropropene, 1,1,1,2,2-pentafluoropropane and 2,3,3,3-tetrafluoropropene,

wherein the composition is heteroazeotropic or quasi-heteroazeotropic.

2. The composition as claimed in claim 1, in which it further comprises one or more organic compounds selected from the group consisting of E-1,3,3,3-tetrafluoropropene, Z-1,3,3,3-tetrafluoropropene, 3,3,3-trifluoropropene, 1,1,1,2,2-pentafluoropropane and 2,3,3,3-tetrafluoropropene.

3. The composition as claimed in claim 1, in which the composition comprises from 1% to 85% by weight of hydrogen fluoride and from 99% to 15% by weight of the sum of the organic compounds.

4. The composition as claimed in claim 1, in which the composition comprises from 5% to 80% by weight of hydrogen fluoride and from 95% to 20% by weight of the sum of the organic compounds.

5. The composition as claimed in claim 1, in which the boiling point of said composition is between −20° C. and 80° C., and at a pressure of between 0.1 and 44 bar absolute.

6. The composition as claimed in claim 1, in which the boiling point of said composition is between 0° C. and 40° C. and at a pressure of between 0.7 and 18 bar absolute.

7. The composition as claimed in claim 1, in which the boiling point of said composition is between 0° C. and 40° C. and at a pressure of between 0.9 and 12.5 bar absolute.