Kleinfelder, Inc. 

6200 Harris Technology Blvd. 

Charlotte, NC 28269

Tampa Electric Company 

Mulberry, FL 

Project # 109381 

Analytical Report 

(0310-129)

EPA CTM 033 

Hydrogen Cyanide 

EPA SW-846 Method 0011

Formaldehyde 

EPA Method 26A 

Hydrogen Chloride, Hydrogen Fluoride, Chloride, and Fluoride 

EPA OTM 27 

PM >2.5 and PM2.5

EPA OTM 28 

Condensible Particulate Matter 

Enthalpy Analytical, Inc. 

Phone: (919) 850 - 4392 / Fax: (919) 850 - 9012 / www.enthalpy.com 

2202 Ellis Road Durham, NC 27703 - 5518 
I certify that to the best of my knowledge all analytical data presented in this report: 

 Have been checked for completeness 

 Are accurate, error-free, and legible 

 Have been conducted in accordance with approved protocol, and that all deviations and analytical 

problems are summarized in the appropriate narrative(s) 

This analytical report was prepared in Portable Document Format (.PDF) and contains 221 pages. 

EA# 0310-129 Page 2 of 221
Summary of Results

EA# 0310-129 Page 3 of 221
Compound Sample ID / Catch Weight (ug)

Unit 1 Run 1 Unit 1 Run 2 Unit 1 Run 3

Hydrogen Cyanide 41.8 ND 47.5 ND 46.3 ND

Impinger Spike Field Tr Blank Reagent Blank

Hydrogen Cyanide 996 26.0 ND 17.4 ND

Company

Analyst

Parameters

# Samples

Kleinfelder, Inc.

KHB

EPA CTM 033

3 Runs, 2 Blanks, 1 Spike

Client #

Job #

PO #

Report Date

109381

0310-129

Verbal

4/30/2010

0310-129 res ctm033 4/30/2010

EA# 0310-129 Page 4 of 221
Compound Sample ID / Catch Weight (ug)

Unit 1 Run 1 Unit 1 Run 2 Unit 1 Run 3

Formaldehyde 86.8 58.7 61.2 

Matrix Spike Imp Spike Field Blank

Formaldehyde 421 815 2.83 ND

Reagent Blank Sample Blank

Formaldehyde 5.76 J 54.6 

Company

Analyst

Parameters

# Samples

Kleinfelder, Inc.

KHB

EPA SW-846 Method 0011

3 Runs, 3 Blanks, 2 Spikes

Client #

Job #

PO #

Report Date

109381

0310-129

Verbal

4/30/2010

0310-129 res m0011 4/30/2010

EA# 0310-129 Page 5 of 221
Compound Sample ID / Catch Weight (ug)

Unit 1 Run 1 Unit 1 Run 2 Unit 1 Run 3

Hydrogen Fluoride 215 ND 223 ND 232 ND

Hydrogen Chloride 210 ND 217 ND 227 ND

Acid Blank DI H2O Blank

Hydrogen Fluoride 87.5 ND 10.4 ND 0 ND

Hydrogen Chloride 85.4 ND 10.2 ND 0 ND

Company

Analyst

Parameters

# Samples

Kleinfelder, Inc.

EO / KHB

EPA Method 26A (H2SO4)

3 Runs, 2 Blanks

Client #

Job #

PO #

Report Date

109381

0310-129

Verbal

4/29/2010

0310-129 res m26a acid 4/29/2010

EA# 0310-129 Page 6 of 221
Compound Sample ID / Catch Weight (ug)

Unit 1 Run 1 Unit 1 Run 2 Unit 1 Run 3

Chloride 198 ND 203 ND 187 ND

Base Blank DI H2O Blank

Chloride 84.2 ND 9.90 ND 0 ND

Company

Analyst

Parameters

# Samples

Kleinfelder, Inc.

EO / KHB

EPA Method 26A (NaOH)

3 Runs, 2 Blanks

Client #

Job #

PO #

Report Date

109381

0310-129

Verbal

4/29/2010

0310-129 res m26a base 5/11/2010

EA# 0310-129 Page 7 of 221
Compound Sample ID / Catch Weight (mg)

Unit 1 Run 1 Unit 1 Run 2 Unit 1 Run 3

PM >2.5 0.50 1.06 0.16

PM < 2.5 Fractions

47 mm Filter 10.7 9.64 10.1

Rinse 0.00 0.11 0.02

Net PM2.5 10.7 9.76 10.2

Total PM 11.2 10.8 10.3

Unit 1 Run 4 #REF! #REF!

PM >2.5 0.00 # 1.06 0.16

PM < 2.5 Fractions

47 mm Filter 10.5 9.64 10.15

Rinse 0.40 0.11 0.02

Net PM2.5 10.9 9.76 10.17

Total PM 10.9 10.82 10.33

# Negative catch set to 0.

Company

Analyst

Parameters

# Samples

Kleinfelder, Inc.

KTH

EPA OTM 27

4 Runs, Blanks

Client #

Job #

PO #

Report Date

109381

0310-129

Verbal

4/28/2010

EA# 0310-129 Page 8 of 221
Compound Sample ID / Condensible Particulate Matter (CPM) Weight (mg)

Unit 1 Run 1 Unit 1 Run 2 Unit 1 Run 3

Net Organic Catch 5.2 2.8 32.0

Corrected Inorganic 25.0 31.0 70.1

TB Corrected CPM 28.2 31.8 100.1

Unit 1 Run 4 0 0

Net Organic Catch 10.6 0.0 0.0

Corrected Inorganic 37.5 0.0 0.0

TB Corrected CPM 46.1 0.0 0.0

Train Blank

Organic Catch 2.0 If Train Blank Corrected CPM is >2.0 mg,

Inorganic Catch 2.4 then sample correction is 2.0 mg.

CPM 4.4

Company

Analyst

Parameters

# Samples

Kleinfelder, Inc.

KTH

EPA OTM 28

5 Runs, Blanks

Client #

Job #

PO #

Report Date

109381

0310-129

Verbal

4/28/2010

0310-129 res OTM-028 4/30/2010

EA# 0310-129 Page 9 of 221
Results

EA# 0310-129 Page 10 of 221
MDL 0.0143 (ug/mL) Lower Curve Limit 0.104 (ug/mL)

LOQ 0.104 (ug/mL) Upper Curve Limit 2.08 (ug/mL)

Compound

Sample

ID

Lab ID

 # 1

Lab ID

 # 2

Analysis

Method

Ret 

Time 

(min)

Ret 

Time 

(min)

% Diff

Ret

Conc

# 1

(ug/mL)

Conc

# 2

(ug/mL)

% Diff

Conc

Avg

Conc

(ug/mL)

Unit 1 Run 1 008-1301.D 008-1302.D HPLC50PG76.M NA NA NA 0.0143 0.0143 0.0 0.0143 

LD / Unit 1 Run 1 055-7801.D 055-7802.D HPLC50PG76.M NA NA NA 0.0143 0.0143 0.0 0.0143 

Unit 1 Run 2 009-1401.D 009-1402.D HPLC50PG76.M NA NA NA 0.0143 0.0143 0.0 0.0143 Unit 1 Run 3 010-1501.D 010-1502.D HPLC50PG76.M NA NA NA 0.0143 0.0143 0.0 0.0143 

Impinger Spike 013-2001.D 013-2002.D HPLC50PG76.M 8.54 8.60 0.7 1.06 0.977 4.0 1.02 

Spike 

Spike 

Field Tr Blank 011-1601.D 011-1602.D HPLC50PG76.M NA NA NA 0.0143 0.0143 0.0 0.0143 

Reagent Blank 012-1701.D 012-1702.D HPLC50PG76.M NA NA NA 0.0143 0.0143 0.0 0.0143 

Hydrogen Cyanide

Company

Analyst

Parameters

# Samples

Kleinfelder, Inc.KHBEPA CTM 0333 Runs, 2 Blanks, 1 Spike

Client #

Job #

PO #

Report Date

1093810310-129Verbal4/30/2010

0310-129 res ctm033 

EA# 0310-129 Page 11 of 221
MDL 0.0143 (ug/mL) Lower Curve Limit 0.104 (ug/mL)

LOQ 0.104 (ug/mL) Upper Curve Limit 2.08 (ug/mL)

Compound

Sample

ID

Lab ID

 # 1

Lab ID

 # 2

Analysis

Method

Ret 

Time 

(min)

Ret 

Time 

(min)

% Diff

Ret

Conc

# 1

(ug/mL)

Conc

# 2

(ug/mL)

% Diff

Conc

Avg

Conc

(ug/mL)

Hydrogen Cyanide

Company

Analyst

Parameters

# Samples

Kleinfelder, Inc.KHBEPA CTM 0333 Runs, 2 Blanks, 1 Spike

Client #

Job #

PO #

Report Date

1093810310-129Verbal4/30/2010

0.1N NaOH - RB 007-0801.D 007-0802.D HPLC50PG76.M NA NA NA 0.0143 0.0143 0.0 0.0143 

MS / Run 1 056-7901.D 056-7902.D HPLC50PG76.M 8.42 8.44 0.2 1.14 1.10 1.7 1.12 

Spike 

Native 

Spike 

MSD / Run 1 057-8001.D 057-8002.D HPLC50PG76.M 8.45 8.42 0.3 1.13 1.08 2.1 1.11 

Spike 

Native 

Spike 

LCS 1 043-6001.D 043-6002.D HPLC50PG76.M 8.05 8.03 0.2 1.25 1.28 1.4 1.26 

Spike 

Spike 

LCS 2 044-6101.D 044-6102.D HPLC50PG76.M 8.00 8.08 0.9 1.27 1.29 0.8 1.28 

Spike 

Spike 

0310-129 res ctm033 

EA# 0310-129 Page 12 of 221
MDL 0.0110 (ug/mL) Lower Curve Limit 0.0747 (ug/mL)

LOQ 0.0747 (ug/mL) Upper Curve Limit 15.0 (ug/mL)

Compound

Sample

ID Lab ID Analysis

Method

Ret 

Time 

(min)

Conc

(ug/mL)

Aliquot 

Factor

Vol

(mL)

Catch

Weight

(ug)

Qual

Unit 1 Run 1 011-0401.D HPLC48PG86D.M 6.57 0.226 2 192 86.8 

Unit 1 Run 1 Rep 011-0501.D HPLC48PG86D.M 6.58 0.227 2 192 87.1 

% Difference 0.4%

Unit 1 Run 1 Dup 012-0601.D HPLC48PG86D.M 7.62 0.275 2 186 102 

% Difference 17.6%

Unit 1 Run 2 013-0701.D HPLC48PG86D.M 6.52 0.169 2 174 58.7 

Unit 1 Run 3 014-0801.D HPLC48PG86D.M 6.43 0.215 1 285 61.2 

Matrix Spike 015-0901.D HPLC48PG86D.M 6.48 1.70 1 248 421 

Spike Amount (ug) 809

Spike Recovery (%) 52.0%

Imp Spike 016-1001.D HPLC48PG86D.M 6.58 5.47 1 149 815 

Spike Amount (ug) 809

Spike Recovery (%) 101%

Field Blank 017-1101.D HPLC48PG86D.M NA 0.0110 1 257 2.83 ND

Reagent Blank 018-1201.D HPLC48PG86D.M 6.54 0.0379 1 152 5.76 J

Sample Blank 019-1401.D HPLC48PG86D.M 6.77 0.172 1 318 54.6 

MB 4/20/10 021-1601.D HPLC48PG86D.M NA 0.0110 1 148 1.63 ND

MB 4/28/10 025-2701.D HPLC48PG86D.M NA 0.0110 1 145 1.60 ND

RB/100% ACN 008-0901.D HPLC48PG86B.M NA 0.0110 1 1.00 0.0110 ND

008-0902.D HPLC48PG86B.M NA 0.0110 1 1.00 0.0110 ND

RB/100% ACN 002-0301.D HPLC48PG86D.M NA 0.0110 1 1.00 0.0110 ND

Formaldehyde

Company

Analyst

Parameters

# Samples

Kleinfelder, Inc.

KHB

EPA SW-846 Method 0011

3 Runs, 3 Blanks, 2 Spikes

Client #

Job #

PO #

Report Date

109381

0310-129

Verbal

4/30/2010

0310-129 res m0011 4/30/2010

EA# 0310-129 Page 13 of 221
MDL 0.0110 (ug/mL) Lower Curve Limit 0.0747 (ug/mL)

LOQ 0.0747 (ug/mL) Upper Curve Limit 15.0 (ug/mL)

Compound

Sample

ID Lab ID Analysis

Method

Ret 

Time 

(min)

Conc

(ug/mL)

Aliquot 

Factor

Vol

(mL)

Catch

Weight

(ug)

Qual

Formaldehyde

Company

Analyst

Parameters

# Samples

Kleinfelder, Inc.

KHB

EPA SW-846 Method 0011

3 Runs, 3 Blanks, 2 Spikes

Client #

Job #

PO #

Report Date

109381

0310-129

Verbal

4/30/2010

MS / Run 2 022-2401.D HPLC48PG86D.M 7.40 2.77 1 128 355 

Spike Amount (ug) 253

Native Amount (ug) 9.78

Spike Recovery (%) 136%

MSD / Run 2 023-2501.D HPLC48PG86D.M 7.36 2.59 1 122 316 

Spike Amount (ug) 253

Native Amount (ug) 9.78

Spike Recovery (%) 121%

LCS 4/20/10 020-1501.D HPLC48PG86D.M 6.59 3.79 1 148 562 

Spike Amount (ug) 809

Spike Recovery (%) 69.4%

LCS 4/28/10 024-2601.D HPLC48PG86D.M 7.35 2.32 1 145 337 

Spike Amount (ug) 253

Spike Recovery (%) 133%

0310-129 res m0011 4/30/2010

EA# 0310-129 Page 14 of 221
MDL 0.0200 (ug/mL) Lower Curve Limit 0.100 (ug/mL)

LOQ 0.100 (ug/mL) Upper Curve Limit 14.8 (ug/mL)

Compound

Sample

ID

Lab ID

 # 1

Lab ID

 # 2

Analysis

Method

Ret 

Time 

(min)

Ret 

Time 

(min)

% Diff

Ret

Conc

# 1

(ug/mL)

Conc

# 2

(ug/mL)

% Diff

Conc

Avg

Conc

(ug/mL)

Acid 

Conversi

Factor

R1 A 008-0901.D 008-0902.D HPLC51PG84.M NA NA NA 0.0200 0.0200 0.0 0.0200 1.053 R2 A 011-1201.D 011-1202.D HPLC51PG84.M NA NA NA 0.0200 0.0200 0.0 0.0200 1.053 R3 A 012-1301.D 012-1302.D HPLC51PG84.M NA NA NA 0.0200 0.0200 0.0 0.0200 1.053 

Acid Blank 013-1401.D 013-1402.D HPLC51PG84.M NA NA NA 0.0200 0.0200 0.0 0.0200 1.053 

DI H2O Blank 014-1501.D 014-1502.D HPLC51PG84.M NA NA NA 0.0200 0.0200 0.0 0.0200 1.053 

0.1N H2SO4/NaOH MB 007-0801.D 007-0802.D HPLC51PG84.M NA NA NA 0.0200 0.0200 0.0 0.0200 1.053 

MS R1 A 009-1001.D 009-1002.D HPLC51PG84.M 2.78 2.78 0.0 3.55 3.54 0.1 3.54 1.053 

Sp

Na

Spi

MSD R1 A 010-1101.D 010-1102.D HPLC51PG84.M 2.78 2.78 0.0 3.53 3.54 0.1 3.54 1.053 

Sp

Na

Spi

Hydrogen Fluoride as Fluoride

Company

Analyst

Parameters

# Samples

Kleinfelder, Inc.EO / KHBEPA Method 26A (H2SO4)3 Runs, 2 Blanks

Client #

Job #

PO #

Report Date

1093810310-129Verbal4/29/2010

0310-129 res m26a acid 

EA# 0310-129 Page 15 of 221
MDL 0.0200 (ug/mL) Lower Curve Limit 0.100 (ug/mL)

LOQ 0.100 (ug/mL) Upper Curve Limit 14.8 (ug/mL)

Compound

Sample

ID

Lab ID

 # 1

Lab ID

 # 2

Analysis

Method

Ret 

Time 

(min)

Ret 

Time 

(min)

% Diff

Ret

Conc

# 1

(ug/mL)

Conc

# 2

(ug/mL)

% Diff

Conc

Avg

Conc

(ug/mL)

Acid 

Conversi

Factor

R1 A 008-0901.D 008-0902.D HPLC51PG84.M NA NA NA 0.0200 0.0200 0.0 0.0200 1.028 R2 A 011-1201.D 011-1202.D HPLC51PG84.M NA NA NA 0.0200 0.0200 0.0 0.0200 1.028 R3 A 012-1301.D 012-1302.D HPLC51PG84.M NA NA NA 0.0200 0.0200 0.0 0.0200 1.028 

Acid Blank 013-1401.D 013-1402.D HPLC51PG84.M NA NA NA 0.0200 0.0200 0.0 0.0200 1.028 

DI H2O Blank 014-1501.D 014-1502.D HPLC51PG84.M NA NA NA 0.0200 0.0200 0.0 0.0200 1.028 

0.1N H2SO4/NaOH MB 007-0801.D 007-0802.D HPLC51PG84.M NA NA NA 0.0200 0.0200 0.0 0.0200 1.028 

MS R1 A 009-1001.D 009-1002.D HPLC51PG84.M 3.74 3.74 0.0 2.85 2.85 0.0 2.85 1.028 

Sp

Na

Spi

MSD R1 A 010-1101.D 010-1102.D HPLC51PG84.M 3.74 3.74 0.0 2.85 2.86 0.1 2.85 1.028 

Sp

Na

Spi

Hydrogen Chloride as Chloride

Company

Analyst

Parameters

# Samples

Kleinfelder, Inc.EO / KHBEPA Method 26A (H2SO4)3 Runs, 2 Blanks

Client #

Job #

PO #

Report Date

1093810310-129Verbal4/29/2010

0310-129 res m26a acid 

EA# 0310-129 Page 16 of 221
MDL 0.0200 (ug/mL) Lower Curve Limit 0.100 (ug/mL)

LOQ 0.100 (ug/mL) Upper Curve Limit 14.8 (ug/mL)

Compound

Sample

ID

Lab ID

 # 1

Lab ID

 # 2

Analysis

Method

Ret 

Time 

(min)

Ret 

Time 

(min)

% Diff

Ret

Conc

# 1

(ug/mL)

Conc

# 2

(ug/mL)

% Diff

Conc

Avg

Conc

(ug/mL)

R1 B 015-1601.D 015-1602.D HPLC51PG84.M NA NA NA 0.0200 0.0200 0.0 0.0200 R2 B 018-2101.D 018-2102.D HPLC51PG84.M NA NA NA 0.0200 0.0200 0.0 0.0200 R3 B 019-2201.D 019-2202.D HPLC51PG84.M NA NA NA 0.0200 0.0200 0.0 0.0200 

Base Blank 020-2301.D 020-2302.D HPLC51PG84.M NA NA NA 0.0200 0.0200 0.0 0.0200 

DI H2O Blank 014-1501.D 014-1502.D HPLC51PG84.M NA NA NA 0.0200 0.0200 0.0 0.0200 

0.1N H2SO4/NaOH MB 007-0801.D 007-0802.D HPLC51PG84.M NA NA NA 0.0200 0.0200 0.0 0.0200 

MS R1 B 016-1901.D 016-1902.D HPLC51PG84.M 3.74 3.74 0.1 2.81 2.80 0.1 2.81 

Spik

Nativ

Spike 

MSD R1 B 017-2001.D 017-2002.D HPLC51PG84.M 3.73 3.72 0.2 2.88 2.89 0.1 2.88 

Spik

Nativ

Spike 

Chloride

Company

Analyst

Parameters

# Samples

Kleinfelder, Inc.EO / KHBEPA Method 26A (NaOH)3 Runs, 2 Blanks

Client #

Job #

PO #

Report Date

1093810310-129Verbal4/29/2010

0310-129 res m26a base 

EA# 0310-129 Page 17 of 221
Conditional Test Method 039 (CTM-039) - Particulate Determination - Data Analysis

Analysis of Particulate Recovery

Sample ID Unit 1 Run 1 Unit 1 Run 2 Unit 1 Run 3 Unit 1 Run 4

47 mm Filter ID 2386 Dates 2388 Dates 2389 Dates 2390 Dates

Final wt. (g) 1st 0.12250 4/24/10 0.12180 4/24/10 0.12373 4/24/10 0.12211 4/24/10

Final wt. (g) 2nd 0.12282 4/27/10 0.12156 4/27/10 0.12321 4/27/10 0.12239 4/27/10

Final Tare Weight (g) 0.11213 3/31/10 0.11192 3/31/10 0.11307 3/31/10 0.11194 3/31/10

Net filter catch (mg) 10.7 9.64 10.1 10.5

>2.5 PM Acetone Rinses

Beaker number 3123 Dates 3122 Dates 3121 Dates 3126 Dates

Final wt (g) 1st 1.91212 4/24/10 1.91083 4/24/10 1.90989 4/24/10 1.90860 4/24/10

Final wt (g) 2nd 1.91205 4/28/10 1.91073 4/28/10 1.90985 4/28/10 1.90858 4/28/10

 Beaker tare (g) 1.91155 4/20/10 1.90967 4/20/10 1.90969 4/20/10 1.90862 4/20/10

Acetone vol (mL) 38 35 28 26

>2.5 PM Catch (mg) 0.50 1.06 0.16 -0.05

<2.5 PM Acetone Rinses

Beaker number 3124 Dates 3125 Dates 3127 Dates 3128 Dates

Final wt (g) 1st 1.91140 4/24/10 1.90552 4/24/10 1.91038 4/24/10 1.91245 4/24/10

Final wt (g) 2nd 1.91136 4/28/10 1.90544 4/28/10 1.91035 4/28/10 1.91237 4/28/10

 Beaker tare (g) 1.91136 4/20/10 1.90532 4/20/10 1.91033 4/20/10 1.91197 4/20/10

Acetone vol (mL) 22 30 28 24

<2.5 PM Catch (mg) 0.00 0.11 0.02 0.40

Total particulate (mg) 11.2 10.8 10.3 10.9

 Reagent Blank Acetone Analysis

Blank beaker number 3129 Dates

Blank volume (mL) 202 Dates Final wt (g) 1st 1.91114 4/24/10

Beaker tare (g) 1.91134 4/20/10 Final wt (g) 2nd 1.91109 4/28/10

Max acetone residue (g) 0.0016 Acetone residue (g) -0.0002

 In-House Blank Acetone Analysis

Blank beaker number 3137 Dates

Blank volume (mL) 200 Dates Final wt (g) 1st 1.88286 4/28/10 A

Beaker tare (g) 1.88223 4/20/10 Final wt (g) 2nd 1.88288 4/28/10 P

Max acetone residue (g) 0.0016 Acetone residue (g) 0.0007

Company

Analyst

Parameters

# Samples

Kleinfelder, Inc.

KTH

EPA OTM 27

4 Runs, Blanks

Client #

Job #

PO #

Report Date

109381

0310-129

Verbal

4/28/2010

EA# 0310-129 Page 18 of 221
Analysis of Condensible Particulate Recovery

Sample ID Number Train Blank Unit 1 Run 1 Unit 1 Run 2 Unit 1 Run 3

Organic

Beaker Number 3134 3130 3131 3132

Initial MeCl2/Acetone Volume, mL 130 290 300 270

Lab MeCl2 Volume, mL 165 Dates 165 Dates 165 Dates 165 Dates

Final Weight, g 1.8809 4/28/10 A 1.8962 4/28/10 A 1.8913 4/28/10 A 1.9169 4/28/10 A

Reweigh, Final, g 1.8809 4/28/10 P 1.8961 4/28/10 P 1.8912 4/28/10 P 1.9167 4/28/10 P

Beaker Tare, g 1.8789 4/20/10 1.8909 4/20/10 1.8885 4/20/10 1.8847 4/20/10

Net Organic Catch, mg 2.0 5.2 2.8 32.0

Inorganic

Beaker Number 3261 Dates 3257 Dates 3258 Dates 3259 Dates

Final Weight, g 1.9297 4/28/10 A 1.9707 4/28/10 A 1.9621 4/28/10 A 1.9937 4/28/10 A

Reweigh, Final, g 1.9297 4/28/10 P 1.9707 4/28/10 P 1.9621 4/28/10 P 1.9936 4/28/10 P

Beaker Tare, g 1.9274 4/27/10 1.9213 4/27/10 1.9139 4/27/10 1.9144 4/27/10

H2O FV, mL 240 410 360 1,070

Resuspended Volume, mL 100.0 100.0 100.0 100.0

Removed Pre-aliquot, mL 0.5 0.5 0.5 0.5

Pre-aliquot CF 1.002 1.001 1.001 1.000

Removed Post-aliquot, mL 0.5 0.5 0.5 0.5

Post-aliquot CF 1.01 1.01 1.01 1.01

Net Inorganic, mg 2.4 49.7 48.5 79.6

Ammonium Correction, mg 0.0 24.7 17.5 9.5

Corrected Inorganic, mg 2.4 25.0 31.0 70.1

Condensible Particulate Matter, mg 4.4 30.2 33.8 102.1

TB Corrected CPM, mg 28.2 31.8 100.1

-----------------------------------------------------------------Client Blank Analyses------------------------------------------------------------------

Type Blank MeCl Blank Type Blank H2O Blank Type Blank 

Beaker Number 3135 Dates Beaker Number 3262 Dates Beaker Number 

Tare weight, g 1.8754 4/28/10 A Tare weight, g 1.9353 4/28/10 A Tare weight, g 

Dry Residue Weight, g 1.8757 4/28/10 P Dry Residue Weight, g 1.9365 4/28/10 P Dry Residue Weight, g 

Reweigh, Final, g 1.8756 4/20/10 Reweigh, Final, g 1.9365 4/27/10 Reweigh, Final, g 

MeCl2 Residue, g 0.0002 Water Residue, g 0.0012 Acetone Residue, g 

MeCl2 Volume, mL 134 Water Volume, mL 204 Acetone Volume, mL 

Max. MeCl2 Residue, g 0.0027 Max. Water Residue, g 0.0020 Max. Acetone Residue, g 

---------------------------------------------------------------In-House Blank Analyses------------------------------------------------------------------

Type Blank MeCl Blank Type Blank H2O Blank Type Blank 

Beaker Number 3136 Dates Beaker Number 3263 Dates Beaker Number 

Tare weight, g 1.8822 4/20/10 Tare weight, g 1.9272 4/27/10 Tare weight, g 

Dry Residue Weight, g 1.8848 4/28/10 A Dry Residue Weight, g 1.9285 4/28/10 A Dry Residue Weight, g 

Reweigh, Final, g 1.8848 4/28/10 P Reweigh, Final, g 1.9285 4/28/10 P Reweigh, Final, g 

MeCl2 Residue, g 0.0027 Water Residue, g 0.0012 Acetone Residue, g 

MeCl2 Volume, mL 225 Water Volume, mL 250 Acetone Volume, mL 

Max. MeCl2 Residue, g 0.0045 Max. Water Residue, g 0.0025 Max. Acetone Residue, g 

Company

Analyst

Parameters

# Samples

Kleinfelder, Inc.KTHEPA OTM 285 Runs, Blanks

Client #

Job #

PO #

Report Date

1093810310-129Verbal4/28/2010

EA# 0310-129 Page 19 of 221
Analysis of Condensible Particulate Recovery

Sample ID Number Train Blank Unit 1 Run 4

Organic

Beaker Number 3134 3133

Initial MeCl2/Acetone Volume, mL 130 230

Lab MeCl2 Volume, mL 165 Dates 165 Dates

Final Weight, g 1.8809 4/28/10 A 1.8946 4/28/10 A

Reweigh, Final, g 1.8809 4/28/10 P 1.8946 4/28/10 P

Beaker Tare, g 1.8789 4/20/10 1.8840 4/20/10

Net Organic Catch, mg 2.0 10.6

Inorganic

Beaker Number 3261 Dates 3260 Dates

Final Weight, g 1.9297 4/28/10 A 1.9762 4/28/10 A

Reweigh, Final, g 1.9297 4/28/10 P 1.9762 4/28/10 P

Beaker Tare, g 1.9274 4/27/10 1.9270 4/27/10

H2O FV, mL 240 350

Resuspended Volume, mL 100.0 100.0

Removed Pre-aliquot, mL 0.5 0.5

Pre-aliquot CF 1.002 1.001

Removed Post-aliquot, mL 0.5 0.5

Post-aliquot CF 1.01 1.01

Net Inorganic, mg 2.4 49.5

Ammonium Correction, mg 0.0 12.0

Corrected Inorganic, mg 2.4 37.5

Condensible Particulate Matter, mg 4.4 48.1

TB Corrected CPM, mg 46.1

-----------------------------------------------------------------Client Blank Analyses------------------------------------------------------------------

Type Blank MeCl Blank Type Blank H2O Blank Type Blank 

Beaker Number 3135 Dates Beaker Number 3262 Dates Beaker Number 

Tare weight, g 1.8754 4/28/10 A Tare weight, g 1.9353 4/28/10 A Tare weight, g 

Dry Residue Weight, g 1.8757 4/28/10 P Dry Residue Weight, g 1.9365 4/28/10 P Dry Residue Weight, g 

Reweigh, Final, g 1.8756 4/20/10 Reweigh, Final, g 1.9365 4/27/10 Reweigh, Final, g 

MeCl2 Residue, g 0.0002 Water Residue, g 0.0012 Acetone Residue, g 

MeCl2 Volume, mL 134 Water Volume, mL 204 Acetone Volume, mL 

Max. MeCl2 Residue, g 0.0027 Max. Water Residue, g 0.0020 Max. Acetone Residue, g 

---------------------------------------------------------------In-House Blank Analyses------------------------------------------------------------------

Type Blank MeCl Blank Type Blank H2O Blank Type Blank 

Beaker Number 3136 Dates Beaker Number 3263 Dates Beaker Number 

Tare weight, g 1.8822 4/20/10 Tare weight, g 1.9272 4/27/10 Tare weight, g 

Dry Residue Weight, g 1.8848 4/28/10 A Dry Residue Weight, g 1.9285 4/28/10 A Dry Residue Weight, g 

Reweigh, Final, g 1.8848 4/28/10 P Reweigh, Final, g 1.9285 4/28/10 P Reweigh, Final, g 

MeCl2 Residue, g 0.0027 Water Residue, g 0.0012 Acetone Residue, g 

MeCl2 Volume, mL 225 Water Volume, mL 250 Acetone Volume, mL 

Max. MeCl2 Residue, g 0.0045 Max. Water Residue, g 0.0025 Max. Acetone Residue, g 

Company

Analyst

Parameters

# Samples

Kleinfelder, Inc.KTHEPA OTM 285 Runs, Blanks

Client #

Job #

PO #

Report Date

1093810310-129Verbal4/28/2010

EA# 0310-129 Page 20 of 221
MDL 0.09 (mg Ammonium)

MDL 0.26 (mg Sulfate)

Blank titrant amount (Vtb) 0.04 [Set this equal to the In-House Blank Titration Volume and then white out this note]

NH4OH normality 0.1 Lot # Sigma Aldrich 318620

Sample ID.

Volume

Resuspended

(mL)

Titration

Aliquot

Vol (mL)

Aliquot Factor 

(mL rec'd/aliq mL)

Train Blank 100 99.5 0.06 ND 1.01 0.26 ND 0.09 ND

Unit 1 Run 1 100 99.5 14.50 1.01 69.81 24.75

Unit 1 Run 2 100 99.5 10.25 1.01 49.29 17.48

Unit 1 Run 3 100 99.5 5.58 1.01 26.75 9.48

Unit 1 Run 4 100 99.5 7.03 1.01 33.75 11.96

Reagent Blank 100 99.5 0.02 ND 1.01 0.26 ND 0.09 ND

In House 100 99.5 0.04 ND 1.01 0.26 ND 0.09 ND

SO4 Catch

(mg)

NH4OH

Titration

Vol (mL)

Ammonium

equivalent

(mg)

Company

Analyst

Parameters

# Samples

Kleinfelder, Inc.

KTH

EPA OTM 28

5 Runs, Blanks

Client #

Job #

PO #

Report Date

109381

0310-129

Verbal

4/28/2010

EA# 0310-129 Page 21 of 221
Narrative Summary

EA# 0310-129 Page 22 of 221
Enthalpy Analytical Narrative Summary 

Company Kleinfelder, Inc. Client # 109381

Analyst KHB Job # 0310-129 

Parameters EPA CTM-033 PO # Verbal 

# Samples 3 Runs, 2 Blanks, 1 Spike Report Date April 30, 2010 

Custody Jordan Laster received the samples on 4/16/10 after being relinquished 

by Kleinfelder, Inc. The samples were received at 2.3C in good 

condition. The pH for each NaOH fraction was measured prior to 

analysis. The value was 14 for each sample. Prior to, during, and after 

analysis, the samples were kept under lock with access only to 

authorized personnel by Enthalpy Analytical, Inc. 

Analysis The samples were analyzed for hydrogen cyanide using the analytical 

procedures in EPA Conditional Test Method 033, Sampling and 

Analysis for Hydrogen Cyanide Emissions from Stationary Sources. 

The DIONEX Model 500, High Performance Liquid Chromatograph 

("Grandmama") was equipped with a Dionex ED40 Electrochemical 

Detector and a Dionex Ion Pac AS7, 4 x 250 mm column (S/N 012759), 

for these analyses. 

Calibration The calibration curve is included in the Calibration Curve 

Chromatograms section of this report and referenced in the Analysis 

Method column on the Detailed Results page. 

The first page of the curve contains all method specific parameters (i.e., 

curve type, origin, weight, etc.) used to quantify the samples. The 

calibration curve section also includes a table with the Retention Time 

(RetTime), Level (Lvl), Amount (corresponding units), Area, Response 

Factor (Amt/Area) and the analyte Name. The calibration table is used 

to identify (by retention time) and quantify each target compound. 

Chromatographic 

Conditions 

The acquisition method 1000.M is included in the Calibration Curve 

Chromatograms section of this report. 

QC Notes The analyses of the field and reagent blanks received with these samples 

contained no hydrogen cyanide at concentrations greater than the MDL. 

The recovery value for hydrogen cyanide in the Impinger Spike was 

within 10% of the expected value. 

The analysis of the laboratory reagent blank contained no hydrogen 

cyanide at a concentration greater than the MDL. 

EA# 0310-129 Page 23 of 221
Enthalpy Analytical Narrative Summary 

(continued) 

QC Notes 

(continued) 

A Laboratory Duplicate (LD) analysis was performed on the sample 

Unit 1 Run 1.

Duplicate matrix spikes were prepared using sample Unit 1 Run 1 and 

exhibited recovery values of 113% and 112%. 

Prior to sample collection, the laboratory prepared aqueous spikes, each 

of which contained 1,023 μg of hydrogen cyanide. Two aqueous spikes 

were sent to the client and two were retaned at the laboratory and 

analyzed with the samples as LCS. The LCS exhibited recovery values 

of 124% and 125%. 

All samples were analyzed within the 30-day holding time specifed by 

the method. 

Reporting Notes The sample volumes measured and recored by the laboratory were used 

to determine the mass of hydrogen cyanide for each sample. 

The results presented in this report are representative of the samples as 

provided to the laboratory. 

Enthalpy Analytical, Inc. is accredited to perform this Method CTM033 for compliance purposes by the National Environmental Laboratory 

Accreditation Conference (NELAC) through the Louisiana 

Environmental Laboratory Accreditation Program (LELAP), certificate 

number 04010. 

EA# 0310-129 Page 24 of 221
Enthalpy Analytical Narrative Summary 

Company Kleinfelder, Inc. Client # 109381

Analyst KHB Job # 0310-129 

Parameters EPA SW-846 Method 0011 PO # Verbal 

# Samples 3 Runs, 2 Blanks, 2 Spikes Report Date April 30, 2010 

Custody Jordan Laster received the sam ples on 4/16/10 after being relinquished 

by Kleinfelder, Inc. The sam ples were received at -1.3 C in good 

condition. Prior to, during, and after analysis, the sam ples were kept 

under lock with access only to authorized personnel by Enthalpy 

Analytical, Inc. 

Analysis The sam ples were analyzed for form aldehyde using the analytical 

procedures in EPA SW -846 Method 0011, Sam pling for Selected 

Aldehyde and Ketone Emissions from Stationary Sources. 

The Agilent Model 1100, High Perf ormance Liquid Chrom atograph 

("Groucho") was equipped with an U ltraviolet (UV) Detector operating 

at 360 nm and Restek Ultra C18, 150 x 4 mm column (S/N 09070055T), 

for these analyses. 

Calibration The calibration curve is included in the Calibration Curve 

Chromatograms of this report and referenced in the Analysis Method 

column on the Detailed Results page. 

The first page of the curve contains all method specific parameters (i.e., 

curve type, origin, weight, etc.) used to quantify the sam ples. The 

calibration curve section also includes a table with the Retention Tim e 

(RetTime), Level (Lvl), Am ount (corresponding units), Area, Response 

Factor (Amt/Area) and the analyte Na me. The calibration table is used 

to identify (by retention time) and quantify each target compound. 

Chromatographic 

Conditions 

The acquisition m ethod hplc48pg84@.m is included in the Calibration 

Curve Chromatograms section of this report. 

QC Notes Formaldehyde was identified in the Reagent Blank at a concentration 

less than the LOQ. Form aldehyde wa s not identified in the laboratory 

reagent or method blanks. 

The analysis of the Impinger Spike sample exhibited a recovery value 

of 101%. The analyses of the Matrix Spike sample exhibited a recovery 

value of 52%. 

EA# 0310-129 Page 25 of 221
Enthalpy Analytical Narrative Summary 

(continued) 

QC Notes 

(continued) 

Prior to sam ple collection, four spike solutions were prepared containing 

809 μg of form aldehyde. Two spike solu tions were shipped to the client 

and two were retained by the lab to us e as LCSs. The analyses of the LCSs 

exhibited recovery values of 69.4% and 133%. 

Sample Unit 1 Run 1 was split during preparation to generate duplicate 

sample Unit 1 Run 1 Dup. The percent difference value between original 

and duplicate results was 17.6%. 

During sample preparation, Unit 1 Run 2 was split in half . The f irst half 

was analyzed as the sam ple and has an aliquot factor of two, as shown on 

the detailed results page. The other ha lf was split in thirds. Two of the 

thirds were used to prepare the Matr ix Spike and Matrix Spike Duplicate. 

One third was archived These spikes do not have an aliquot factor, and the 

native amount of the sample used in determining their recoveries is 1/6 the 

calculated f inal result f or the sam ple itself . The two m atrix spike 

recoveries were 136% and 121%. 

Reporting Notes The results presented in this report are representative of the sam ples as 

provided to the laboratory. 

EA# 0310-129 Page 26 of 221
Enthalpy Analytical Narrative Summary 

Company Kleinfelder, Inc. Client # 109381 

Analyst EO / KHB Job # 0310-129 

Parameters EPA Method 26A PO # Verbal 

# Samples 3 Runs, 3 Blanks Report Date April 29, 2010 

Custody Jordan Laster received the sam ples on 4/16/10 after being relinquished 

by Kleinfelder, Inc. The sam ples were received at 15.7 C in good 

condition. Prior to, during, and after analysis, the sam ples were kept 

under lock with access only to authorized personnel by Enthalpy 

Analytical, Inc. 

Analysis The sam ples were analyzed for hydrogen chloride (HCl), hydrogen 

fluoride (HF), chloride, and fluoride us ing the analytical procedures in 

EPA Method 26A, Determ ination of Hydrogen Halide and Halogen 

Emissions from Stationary Sources Isokinetic Method (40 CFR Part 60, 

Appendix A). 

The sam ples were analyzed followi ng the procedures in Section 11.0, 

Analytical Procedures. All sam ples and standards are prepared, stored, 

and analyzed using high-density polyethylene containers. 

The volume of the im pinger samples were m easured and recorded and 

used in calculating the catch weights. 

The Metrohm 861 Com pact IC ("Smithers" S/N 1861002007189) was 

equipped with a Metrohm 861 Conductivity Detector and a Metrosep A 

Supp 5 - 110/4.0mm column (S/N # 905298). 

Calibration The calibration curve is located in the back of this report and referenced 

in the Analysis Method column on the Detailed Results page. 

The first page of the curve contains all method specific parameters (i.e., 

curve type, origin, weight, etc.) us ed to quantif y the sam ples. The 

calibration curve section also includes a table with the Retention Tim e 

(RetTime), Level (Lvl), Am ount (corresponding units), Area, Response 

Factor (Amt/Area) and the analyte Na me. The calibration table is used 

to identify (by retention time) and quantify each target compound. 

Chromatographic 

Conditions 

The acquisition m ethod Metrohm .M is included in the Calibration 

Curve Chromatograms section of this report. 

QC Notes As required in Section 7.2.2, Absorbing Solution Blanks, clientprovided field and reagent blanks were analyzed. Additionally, quality 

control check samples were analyzed at the same time as the blanks and 

samples. All method required acceptance criteria were met. 

EA# 0310-129 Page 27 of 221
Enthalpy Analytical Narrative Summary 

(continued) 

QC Notes 

(continued) 

The m atrix spikes perform ed on sam ples R1 A and R1 B in duplicate 

(MS and MSD) exhibited recovery values of 118% and 118% for HF, 

94.9% and 95.1% for HCl, 106% and 108% for fluoride, and 93.6% and 

96.2% for chloride. 

All sam ple preparation and analytical holding tim es specif ied in the 

method were m et. In Section 13.2, Sam ple Stability, the specified 

analytical holding time is four weeks. 

Reporting Notes The results presented in this report are representative of the sam ples as 

provided to the laboratory. 

The H2SO4 matrix samples were analyzed for Cl- and F- but are reported 

as HCl and HF. The results were converted using an acid conversion 

factor of 1.028 for HCl and 1.053 for HF. 

Enthalpy Analytical, Inc. is accredited to perform this m ethod for 

compliance purposes by the National Environm ental Laboratory 

Accreditation Conference (NELAC) through the Louisiana 

Environmental Laboratory Accreditation Program (LELAP), certificate 

number 04010. 

EA# 0310-129 Page 28 of 221
Enthalpy Analytical Narrative Summary 

Company Kleinfelder, Inc. Client # 109381

Analyst ARM Job # 0310-129 

Parameters EPA OTM 27 PO # Verbal 

# Samples 3 Runs, Blank Report Date April 28, 2010 

Custody Jordan Laster received the samples on 4/16/10 after being relinquished 

by Kleinfelder, Inc. The samples were received at 16.6C in good 

condition. Prior to, during, and after analysis, the samples were kept 

under lock with access only to authorized personnel by Enthalpy 

Analytical, Inc. 

Analysis The samples were analyzed for PM2.5 and PM greater than 2.5 microns 

using EPA Other Test Method (OTM) 27, Determination of PM10 and 

PM2.5 Emissions from Stationary Sources (Constant Sampling Rate 

Procedures). 

The filters were placed in a desiccator for 24 hours. The filters were 

weighed at minimum 6-hour intervals until constant weights were 

achieved. 

The volumes of the acetone rinse fractions were measured and recorded. 

The acetone rinse fractions were transferred to tare weighed aluminum 

beakers and allowed to evaporate to dryness under nitrogen in a vented 

chamber. The remaining residues were placed in a desiccator for 24 

hours and then weighed at minimum 6-hour intervals until constant 

weights were achieved. 

All samples were weighed on a Sartorius Model ME 5-F balance (SN 

23104965) certified by Precision Weighing, Inc. through the end of 

October 2010. 

QC Notes No corrections for the acetone blank were made to the results. 

Reporting Notes The accuracy of gravimetric analyses is considered to be ±0.5 mg. 

Therefore, negative catch weights between 0 and -0.5 mg are set to zero 

and no investigation is undertaken. The negative weight for the >2.5 PM 

fraction of Unit 1 Run 4 was not used in the total particulate calculation. 

The results presented in this report are representative of the samples as 

provided to the laboratory. 

EA# 0310-129 Page 29 of 221
Enthalpy Analytical Narrative Summary 

Company Kleinfelder, Inc. Client # 109381

Analyst KTH Job # 0310-129 

Parameters EPA OTM 28 PO # Verbal 

# Samples 5 Runs, Blanks Report Date April 28, 2010 

Custody Jordan Laster received the samples on 4/16/10 after being relinquished 

by Kleinfelder, Inc. The samples were received at 16.6C in good 

condition. Prior to, during, and after analysis, the samples were kept 

under lock with access only to authorized personnel by Enthalpy 

Analytical, Inc. 

Analysis The samples were analyzed for Particulate Matter using the analytical 

procedures in EPA Other Test Method (OTM) 28, Dry Inpinger Method 

for Determining Condensable Particulate Emissions from Stationary 

Sources. 

The Teflon filters were folded into quarters and placed into a 40 mL 

VOA. 25 mLs of DIUF water was added to the VOA and sonicated for 

two minutes. The water extract was combined with the sample water 

fractions. This was repeated two times. A 25 mL aliquot of methylene 

chloride (MeCl2) was then added to the filter and sonicated for two 

minutes. This was repeated two times. This MeCl2 was combined with 

the client’s methylene chloride fractions. 

The water fractions were extracted three times, each time using 30 mL 

of methylene chloride. A 0.5 mL aliquot was archived. The remainder 

was evaporated in a Teflon beaker at 104.7 °C until less than 5 mL 

remained; this was dried at room conditions. The residue was 

resuspended in 100 mL of DIUF water; another 0.5 mL aliquot labeled 

“post” was taken and archived. The remainder was titrated with 0.1N 

NH4OH and returned to the oven until less than 5 mL remained; drying 

was completed at room conditions. The residue was transferred with 

acetone and a Teflon policeman to a tare weighed aluminum beaker and 

placed inside a vented chamber under nitrogen. The beakers were then 

placed in a desiccator for 24 hours. The beakers were weighed at 

minimum 6-hour intervals until constant weights were achieved. 

The organic fractions final volumes were taken. The client provided 

acetone and MeCl2 were combined with the 90 mL of MeCl2 (used to 

extract the water fraction) in tared aluminum beakers. The beaker 

samples were evaporated to dryness under nitrogen in a vented chamber 

and then placed in a desiccator for 24 hours. The samples were weighed 

at minimum 6-hour intervals until constant weights were achieved. 

EA# 0310-129 Page 30 of 221
Enthalpy Analytical Narrative Summary 

(continued) 

Analysis 

(continued) 

The Train Blank was treated as a sample. 

All samples were weighed on a Sartorius Model ME 5-F balance (SN 

23104965) certified by Precision Weighing, Inc. through the end of 

October 2010. 

QC Notes The method specifies blank corrections are accomplished by subtracting 

the particulate mass determined in the ‘Field Train Blank’ or 2 mg 

(whichever is less) from the sample weight. The train blank result was 

greater than 2.0 mg, so 2.0 has been used as the Train Blank (TB) 

Correction. 

The inorganic results for the samples were corrected for the ammonium 

ions used to precipitate the sulfate, per the formula in the Method 

(Section 12.2.1). 

Reporting Notes The accuracy of this gravimetric analyses is considered to be ±0.5 mg. 

Therefore, negative catch weights between 0 and -0.5 mg are set to zero 

and no investigation is undertaken. None of the catch results for this 

data set were negative. 

The results presented in this report are representative of the samples as 

provided to the laboratory. 

EA# 0310-129 Page 31 of 221
General Reporting Notes 

The following are general reporting notes that are a pplicable to all Enthalpy Analytical, Inc. data 

reports, unless specifically noted otherwise.

 The acronym MDL represents the Minim um Detection Lim it. Below this value the laboratory cannot 

determine the presence of the analyte of interest reliably. 

 The acrony m LOQ represents the Lim it of Quantification. Below this value the laboratory cannot 

quantitate the analyte of interest within the criteria of the method. 

 The acronym ND following a value indicates a non-detect or analytical result below the MDL. 

 The letter J following a value indicates an analy tical result between the MDL and the LOQ. A J flag 

indicates that the laboratory can positively identify th e analyte of interest as present, but the value 

should be considered an estimate. 

 The letter E following a value indicates an analy tical result exceeding 100% of the highest calibration 

point. The associated value should be considered as an estimate. 

 The acronym DF represents Dilution Factor. This number represents dilution of the sam ple during the 

preparation and/or analy sis process. The analy tical result taken from a laboratory instrum ent is 

multiplied by the DF to determine the final undiluted sample results. 

 The addition of MS to the Sam ple ID represents a Matrix Spike. An aliquot of an actual sam ple is 

spiked with a known amount of analyte so that a percent recovery value can be determined. This shows 

what effect the sample matrix may have on the target analyte, i.e. whether or not anything in the sample 

matrix interferes with the analysis of the analyte(s). 

 The addition of MSD to the Sam ple ID represents a Matrix Spike Duplicate. Prepared in the sam e 

manner as an MS, the use of duplicate m atrix spikes allows further confirmation of laboratory quality 

by showing the consistency of results gained by performing the same steps multiple times. 

 The addition of LD to the Sam ple ID represents a Laborat ory Duplicate. The analy st prepares an 

additional aliquot of sam ple for testing and the resu lts of the duplicate analy sis are compared to the 

initial result. The result should have a difference value of within 10% of the initial result (if the results 

of the original analysis are greater than the LOQ). 

 The addition of AD to the Sam ple ID represents an Alte rnate Dilution. The analy st prepares an 

additional aliquot at a different dilution factor (usu ally double the initial factor). This analy sis helps 

confirm that no additional compound is present and coeluting or sharing absorbance with the analyte of 

interest, as they would have a different response/absorbance than the analyte of interest. 

 The Sample ID LCS represents a Laboratory Control Sample. Clean matrix, similar to the client sample 

matrix, prepared and analy zed by the laboratory using the sam e reagents, spiking standards and 

procedures used for the client sam ples. The LCS is used to assess the control of the laboratory ’s 

analytical system. Whenever spikes are prepared for our client projects, two extra spikes are prepared. 

The extras (randomly chosen) are labeled with the asso ciated project number and kept in-house at the 

appropriate temperature conditions. When the project sam ples are received for analy sis, the LCSs are 

analyzed to confirm that the analy te could be recovered from the m edia, separate from the samples 

which were used on the project and which m ay have been affected by source matrix, sample collection 

and/or sample transport. 

EA# 0310-129 Page 32 of 221
General Reporting Notes 

(continued) 

 Significant Figures: Where the reported value is m uch greater than unity (1.00) in the units expressed, 

the number is rounded to a whole num ber of units, rather than to 3 significant figures. For example, a 

value of 10,456.45 ug catch is rounded to 10,456 ug. There are five significant digits display ed, but no 

confidence should be placed on more than two significant digits. 

 Manual Integration: The data sy stems used for processing w ill flag m anually integrated peaks with 

an “M”. There are several reasons a peak may be manually integrated. These reasons will be identified 

by the following two letter designations. The peak was not integrated by the software “NI”, the peak 

was integrated incorrectly by the software “II” or the wrong peak was integrated by the software 

“WP”. These codes will accom pany the analy st’s m anual integration stam p placed next to the 

compound name. 

EA# 0310-129 Page 33 of 221
Sample Custody

EA# 0310-129 Page 34 of 221




Sample 

Chromatograms

EA# 0310-129 Page 39 of 221
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\008-1301.D) 1.470 1.745 2.115 2.702

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.536 - - - Hydrogen Cyanide 

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

=====================================================================

 Area Percent Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\008-1301.D

Sample Name: Run 1*5 0310-129

 =====================================================================

 Acq. Operator : KHB Seq. Line : 13

 Acq. Instrument : Grandmama Location : -

 Injection Date : 4/29/2010 1:13:41 AM Inj : 1

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 4/8/2010 9:49:36 AM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M

 Last changed : 4/29/2010 3:34:02 PM by ARM

 =====================================================================

Instrument 3 4/30/2010 2:26:10 PM ARM Page 1 of 2

EA# 0310-129 Page 40 of 221
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\008-1302.D) 1.482 1.758 2.021 2.124 2.712

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.536 - - - Hydrogen Cyanide 

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

=====================================================================

 Area Percent Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\008-1302.D

Sample Name: Run 1*5 0310-129

 =====================================================================

 Acq. Operator : KHB Seq. Line : 13

 Acq. Instrument : Grandmama Location : -

 Injection Date : 4/29/2010 1:28:57 AM Inj : 2

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 4/8/2010 9:49:36 AM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M

 Last changed : 4/29/2010 3:34:02 PM by ARM

 =====================================================================

Instrument 3 4/30/2010 2:26:16 PM ARM Page 1 of 2

EA# 0310-129 Page 41 of 221
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\055-7801.D) 1.477 1.580 1.770 1.855 2.117 2.704

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.536 - - - Hydrogen Cyanide 

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

=====================================================================

 Area Percent Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\055-7801.D

Sample Name: LD/Run 1*5 0310-129

 =====================================================================

 Acq. Operator : KHB Seq. Line : 78

 Acq. Instrument : Grandmama Location : -

 Injection Date : 4/30/2010 1:05:50 PM Inj : 1

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 4/30/2010 12:54:42 PM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M

 Last changed : 4/29/2010 3:34:02 PM by ARM

 Sample Info : Lab Duplicate

 

 =====================================================================

Instrument 3 4/30/2010 2:57:38 PM ARM Page 1 of 2

EA# 0310-129 Page 42 of 221
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\055-7802.D) 1.473 1.581 1.767 1.848 2.120 2.695

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.536 - - - Hydrogen Cyanide 

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

=====================================================================

 Area Percent Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\055-7802.D

Sample Name: LD/Run 1*5 0310-129

 =====================================================================

 Acq. Operator : KHB Seq. Line : 78

 Acq. Instrument : Grandmama Location : -

 Injection Date : 4/30/2010 1:21:12 PM Inj : 2

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 4/30/2010 12:54:42 PM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M

 Last changed : 4/29/2010 3:34:02 PM by ARM

 Sample Info : Lab Duplicate

 

 =====================================================================

Instrument 3 4/30/2010 2:57:44 PM ARM Page 1 of 2

EA# 0310-129 Page 43 of 221
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\009-1401.D) 1.471 1.743 2.107 2.709

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.536 - - - Hydrogen Cyanide 

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

=====================================================================

 Area Percent Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\009-1401.D

Sample Name: Run 2*5 0310-129

 =====================================================================

 Acq. Operator : KHB Seq. Line : 14

 Acq. Instrument : Grandmama Location : -

 Injection Date : 4/29/2010 1:44:14 AM Inj : 1

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 4/8/2010 9:49:36 AM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M

 Last changed : 4/29/2010 3:34:02 PM by ARM

 =====================================================================

Instrument 3 4/30/2010 2:26:22 PM ARM Page 1 of 2

EA# 0310-129 Page 44 of 221
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\009-1402.D) 1.470 1.738 2.105 2.703

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.536 - - - Hydrogen Cyanide 

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

=====================================================================

 Area Percent Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\009-1402.D

Sample Name: Run 2*5 0310-129

 =====================================================================

 Acq. Operator : KHB Seq. Line : 14

 Acq. Instrument : Grandmama Location : -

 Injection Date : 4/29/2010 1:59:31 AM Inj : 2

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 4/8/2010 9:49:36 AM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M

 Last changed : 4/29/2010 3:34:02 PM by ARM

 =====================================================================

Instrument 3 4/30/2010 2:26:28 PM ARM Page 1 of 2

EA# 0310-129 Page 45 of 221
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\010-1501.D) 1.478 1.739 2.097 2.716

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.536 - - - Hydrogen Cyanide 

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

=====================================================================

 Area Percent Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\010-1501.D

Sample Name: Run 3*5 0310-129

 =====================================================================

 Acq. Operator : KHB Seq. Line : 15

 Acq. Instrument : Grandmama Location : -

 Injection Date : 4/29/2010 2:14:53 AM Inj : 1

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 4/8/2010 9:49:36 AM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M

 Last changed : 4/29/2010 3:34:02 PM by ARM

 =====================================================================

Instrument 3 4/30/2010 2:26:37 PM ARM Page 1 of 2

EA# 0310-129 Page 46 of 221
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\010-1502.D) 1.483 1.742 2.105 2.710

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.536 - - - Hydrogen Cyanide 

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

=====================================================================

 Area Percent Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\010-1502.D

Sample Name: Run 3*5 0310-129

 =====================================================================

 Acq. Operator : KHB Seq. Line : 15

 Acq. Instrument : Grandmama Location : -

 Injection Date : 4/29/2010 2:30:09 AM Inj : 2

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 4/8/2010 9:49:36 AM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M

 Last changed : 4/29/2010 3:34:02 PM by ARM

 =====================================================================

Instrument 3 4/30/2010 2:29:37 PM ARM Page 1 of 2

EA# 0310-129 Page 47 of 221
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\013-2001.D)

 Area: 2154.87

 1.487

 1.746

 2.110 2.287

 8.539 - Hydrogen Cyanide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.539 MM 2154.86670 4.90558e-4 1.05709 Hydrogen Cyanide 

Totals : 1.05709

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\013-2001.D

Sample Name: Imp Spk*5 0310-129

 =====================================================================

 Acq. Operator : KHB Seq. Line : 20

 Acq. Instrument : Grandmama Location : -

 Injection Date : 4/29/2010 4:47:38 AM Inj : 1

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 4/8/2010 9:49:36 AM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M

 Last changed : 4/29/2010 3:34:02 PM by ARM

 =====================================================================

Instrument 3 4/30/2010 2:31:01 PM ARM Page 1 of 1

EA# 0310-129 Page 48 of 221
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\013-2002.D) 1.494 1.738 8.598 - Hydrogen Cyanide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.598 BB 1996.46399 4.89178e-4 9.76626e-1 Hydrogen Cyanide 

Totals : 9.76626e-1

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\013-2002.D

Sample Name: Imp Spk*5 0310-129

 =====================================================================

 Acq. Operator : KHB Seq. Line : 20

 Acq. Instrument : Grandmama Location : -

 Injection Date : 4/29/2010 5:02:54 AM Inj : 2

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 4/8/2010 9:49:36 AM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M

 Last changed : 4/29/2010 3:34:02 PM by ARM

 =====================================================================

Instrument 3 4/30/2010 2:30:37 PM ARM Page 1 of 1

EA# 0310-129 Page 49 of 221
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\011-1601.D) 1.480 1.738 2.090 2.273

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.536 - - - Hydrogen Cyanide 

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

=====================================================================

 Area Percent Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\011-1601.D

Sample Name: Field Tr Blk*5 0310-129

 =====================================================================

 Acq. Operator : KHB Seq. Line : 16

 Acq. Instrument : Grandmama Location : -

 Injection Date : 4/29/2010 2:45:25 AM Inj : 1

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 4/8/2010 9:49:36 AM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M

 Last changed : 4/29/2010 3:34:02 PM by ARM

 Sample Info : Sample Blank

 

 =====================================================================

Instrument 3 4/30/2010 2:29:47 PM ARM Page 1 of 2

EA# 0310-129 Page 50 of 221
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\011-1602.D) 1.484 1.741

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.536 - - - Hydrogen Cyanide 

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

=====================================================================

 Area Percent Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\011-1602.D

Sample Name: Field Tr Blk*5 0310-129

 =====================================================================

 Acq. Operator : KHB Seq. Line : 16

 Acq. Instrument : Grandmama Location : -

 Injection Date : 4/29/2010 3:00:41 AM Inj : 2

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 4/8/2010 9:49:36 AM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M

 Last changed : 4/29/2010 3:34:02 PM by ARM

 Sample Info : Sample Blank

 

 =====================================================================

Instrument 3 4/30/2010 2:29:57 PM ARM Page 1 of 2

EA# 0310-129 Page 51 of 221
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\012-1701.D) 1.480 1.737

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.536 - - - Hydrogen Cyanide 

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

=====================================================================

 Area Percent Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\012-1701.D

Sample Name: Reagent Blk*5 0310-129

 =====================================================================

 Acq. Operator : KHB Seq. Line : 17

 Acq. Instrument : Grandmama Location : -

 Injection Date : 4/29/2010 3:15:58 AM Inj : 1

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 4/8/2010 9:49:36 AM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M

 Last changed : 4/29/2010 3:34:02 PM by ARM

 Sample Info : Sample Blank

 

 =====================================================================

Instrument 3 4/30/2010 2:30:03 PM ARM Page 1 of 2

EA# 0310-129 Page 52 of 221
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\012-1702.D) 1.485 1.742 2.134 2.277

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.536 - - - Hydrogen Cyanide 

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

=====================================================================

 Area Percent Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\012-1702.D

Sample Name: Reagent Blk*5 0310-129

 =====================================================================

 Acq. Operator : KHB Seq. Line : 17

 Acq. Instrument : Grandmama Location : -

 Injection Date : 4/29/2010 3:31:14 AM Inj : 2

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 4/8/2010 9:49:36 AM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M

 Last changed : 4/29/2010 3:34:02 PM by ARM

 Sample Info : Sample Blank

 

 =====================================================================

Instrument 3 4/30/2010 2:30:10 PM ARM Page 1 of 2

EA# 0310-129 Page 53 of 221
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\007-0801.D) 1.738 2.271

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.536 - - - Hydrogen Cyanide 

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

=====================================================================

 Area Percent Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\007-0801.D

Sample Name: 0.1N NaOH - RB

 =====================================================================

 Acq. Operator : KHB Seq. Line : 8

 Acq. Instrument : Grandmama Location : -

 Injection Date : 4/28/2010 10:40:56 PM Inj : 1

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 4/8/2010 9:49:36 AM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M

 Last changed : 4/29/2010 3:34:02 PM by ARM

 =====================================================================

Instrument 3 4/29/2010 3:40:50 PM ARM Page 1 of 2

EA# 0310-129 Page 54 of 221
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\007-0802.D) 1.673 1.740 2.272

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.536 - - - Hydrogen Cyanide 

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

=====================================================================

 Area Percent Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\007-0802.D

Sample Name: 0.1N NaOH - RB

 =====================================================================

 Acq. Operator : KHB Seq. Line : 8

 Acq. Instrument : Grandmama Location : -

 Injection Date : 4/28/2010 10:56:12 PM Inj : 2

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 4/8/2010 9:49:36 AM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M

 Last changed : 4/29/2010 3:34:02 PM by ARM

 =====================================================================

Instrument 3 4/29/2010 3:40:55 PM ARM Page 1 of 2

EA# 0310-129 Page 55 of 221
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\056-7901.D)

 Area: 2317.55

 1.473 1.580 1.761 1.845

 2.118

 2.691

 8.419 - Hydrogen Cyanide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.419 MM 2317.55493 4.91779e-4 1.13972 Hydrogen Cyanide 

Totals : 1.13972

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\056-7901.D

Sample Name: MS/Run 1 0310-129

 =====================================================================

 Acq. Operator : KHB Seq. Line : 79

 Acq. Instrument : Grandmama Location : -

 Injection Date : 4/30/2010 1:36:28 PM Inj : 1

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 4/30/2010 12:54:42 PM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M

 Last changed : 4/29/2010 3:34:02 PM by ARM

 Sample Info : Matrix Spike

 

 =====================================================================

Instrument 3 4/30/2010 3:41:23 PM ARM Page 1 of 1

EA# 0310-129 Page 56 of 221
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\056-7902.D) 1.475 1.585 1.763 1.850 2.121 2.693 8.438 - Hydrogen Cyanide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.438 BB 2243.35498 4.91244e-4 1.10203 Hydrogen Cyanide 

Totals : 1.10203

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\056-7902.D

Sample Name: MS/Run 1 0310-129

 =====================================================================

 Acq. Operator : KHB Seq. Line : 79

 Acq. Instrument : Grandmama Location : -

 Injection Date : 4/30/2010 1:51:44 PM Inj : 2

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 4/30/2010 12:54:42 PM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M

 Last changed : 4/29/2010 3:34:02 PM by ARM

 Sample Info : Matrix Spike

 

 =====================================================================

Instrument 3 4/30/2010 2:59:03 PM ARM Page 1 of 1

EA# 0310-129 Page 57 of 221
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\057-8001.D) 1.476 1.590 1.764 1.857 2.120 2.698 8.450 - Hydrogen Cyanide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.450 BB 2295.54639 4.91624e-4 1.12855 Hydrogen Cyanide 

Totals : 1.12855

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\057-8001.D

Sample Name: MSD/Run 1 0310-129

 =====================================================================

 Acq. Operator : KHB Seq. Line : 80

 Acq. Instrument : Grandmama Location : -

 Injection Date : 4/30/2010 2:07:01 PM Inj : 1

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 4/30/2010 12:54:42 PM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M

 Last changed : 4/29/2010 3:34:02 PM by ARM

 Sample Info : Matrix Spike Duplicate

 

 =====================================================================

Instrument 3 4/30/2010 2:59:13 PM ARM Page 1 of 1

EA# 0310-129 Page 58 of 221
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\057-8002.D) 1.473 1.589 1.762 1.856 2.119 2.694 8.423 - Hydrogen Cyanide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.423 BB 2204.25684 4.90948e-4 1.08217 Hydrogen Cyanide 

Totals : 1.08217

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\057-8002.D

Sample Name: MSD/Run 1 0310-129

 =====================================================================

 Acq. Operator : KHB Seq. Line : 80

 Acq. Instrument : Grandmama Location : -

 Injection Date : 4/30/2010 2:37:46 PM Inj : 2

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 4/30/2010 12:54:42 PM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M

 Last changed : 4/29/2010 3:34:02 PM by ARM

 Sample Info : Matrix Spike Duplicate

 

 =====================================================================

Instrument 3 4/30/2010 2:59:33 PM ARM Page 1 of 1

EA# 0310-129 Page 59 of 221
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\043-6001.D) 1.667 1.739 2.270 8.046 - Hydrogen Cyanide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.046 BB 2528.24194 4.93127e-4 1.24674 Hydrogen Cyanide 

Totals : 1.24674

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\043-6001.D

Sample Name: LCS 1*100 0410-22

 =====================================================================

 Acq. Operator : KHB Seq. Line : 60

 Acq. Instrument : Grandmama Location : -

 Injection Date : 4/30/2010 3:36:36 AM Inj : 1

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 4/8/2010 9:49:36 AM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M

 Last changed : 4/29/2010 3:34:02 PM by ARM

 Sample Info : Lab Control Spike

 

 =====================================================================

Instrument 3 4/30/2010 3:19:35 PM ARM Page 1 of 1

EA# 0310-129 Page 60 of 221
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\043-6002.D)

 Area: 2599.31

 1.667 1.734 1.855

 2.259

 8.026 - Hydrogen Cyanide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.026 MM 2599.30957 4.93532e-4 1.28284 Hydrogen Cyanide 

Totals : 1.28284

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\043-6002.D

Sample Name: LCS 1*100 0410-22

 =====================================================================

 Acq. Operator : KHB Seq. Line : 60

 Acq. Instrument : Grandmama Location : -

 Injection Date : 4/30/2010 3:51:52 AM Inj : 2

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 4/8/2010 9:49:36 AM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M

 Last changed : 4/29/2010 3:34:02 PM by ARM

 Sample Info : Lab Control Spike

 

 =====================================================================

Instrument 3 4/30/2010 3:19:48 PM ARM Page 1 of 1

EA# 0310-129 Page 61 of 221
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\044-6101.D) 1.664 1.729 2.255 8.001 - Hydrogen Cyanide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.001 BB 2579.91626 4.93424e-4 1.27299 Hydrogen Cyanide 

Totals : 1.27299

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\044-6101.D

Sample Name: LCS 2*100 0410-22

 =====================================================================

 Acq. Operator : KHB Seq. Line : 61

 Acq. Instrument : Grandmama Location : -

 Injection Date : 4/30/2010 4:07:15 AM Inj : 1

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 4/8/2010 9:49:36 AM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M

 Last changed : 4/29/2010 3:34:02 PM by ARM

 Sample Info : Lab Control Spike

 

 =====================================================================

Instrument 3 4/30/2010 3:38:00 PM ARM Page 1 of 1

EA# 0310-129 Page 62 of 221
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\044-6102.D)

 Area: 2618.32

 1.664 1.735

 2.261

 8.075 - Hydrogen Cyanide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.075 MM 2618.32080 4.93637e-4 1.29250 Hydrogen Cyanide 

Totals : 1.29250

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\044-6102.D

Sample Name: LCS 2*100 0410-22

 =====================================================================

 Acq. Operator : KHB Seq. Line : 61

 Acq. Instrument : Grandmama Location : -

 Injection Date : 4/30/2010 4:22:30 AM Inj : 2

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 4/8/2010 9:49:36 AM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M

 Last changed : 4/29/2010 3:34:02 PM by ARM

 Sample Info : Lab Control Spike

 

 =====================================================================

Instrument 3 4/30/2010 3:38:15 PM ARM Page 1 of 1

EA# 0310-129 Page 63 of 221
Calibration 

Curve Chromatograms

EA# 0310-129 Page 64 of 221
=====================================================================

 Calibration Table 

=====================================================================

Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM

Calculate : External Standard

Based on : Peak Area

Rel. Reference Window : 10.000 %

Abs. Reference Window : 0.300 min

Rel. Non-ref. Window : 10.000 %

Abs. Non-ref. Window : 0.300 min

Use Multiplier & Dilution Factor with ISTDs

Uncalibrated Peaks : not reported

Partial Calibration : Yes, identified peaks are recalibrated

Correct All Ret. Times: No, only for identified peaks

Curve Type : Linear

Origin : Connected

Weight : Linear (Amnt)

Recalibration Settings: 

Average Response : Average all calibrations

Average Retention Time: Floating Average New 75%

Calibration Report Options :

 Printout of recalibrations within a sequence:

 Calibration Table after Recalibration

 Normal Report after Recalibration

 If the sequence is done with bracketing:

 Results of first cycle (ending previous bracket)

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Lvl Amount Area Amt/Area Ref Grp Name 

 [min] Sig [ug/mL] 

-------|--|--|----------|----------|----------|---|--|---------------

 8.536 1 1 1.03500e-1 261.37402 3.95984e-4 Hydrogen Cyanide 

 2 5.07300e-1 1134.77325 4.47050e-4 

 3 9.90500e-1 2127.66284 4.65534e-4 

 4 1.54100 3112.55420 4.95092e-4 

 5 2.08000 4013.67810 5.18228e-4 

=====================================================================

 Peak Sum Table 

=====================================================================

***No Entries in table***

=====================================================================

Method H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M

Instrument 3 4/29/2010 3:35:19 PM ARM Page 1 of 2

EA# 0310-129 Page 65 of 221
=====================================================================

 Calibration Curves

=====================================================================

Amount[ug/mL]

0 1 2

Area

0

500

1000

1500

2000

2500

3000

3500

4000

1

2

3

4

5

Hydrogen Cyanide at exp. RT: 8.536

ADC1 A, ADC1 CHANNEL A

Correlation: 0.99877

Residual Std. Dev.: 113.97999

Formula: y = mx + b

 m: 1968.68232

 b: 73.79855

 x: Amount

 y: Area

Calibration Level Weights:

 Level 1 : 1

 Level 2 : 0.204021

 Level 3 : 0.104493

 Level 4 : 0.067164

 Level 5 : 0.04976

=====================================================================

Method H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M

Instrument 3 4/29/2010 3:35:19 PM ARM Page 2 of 2

EA# 0310-129 Page 66 of 221
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\001-0201.D) 1.673 1.736 2.039 2.276 8.577 - Hydrogen Cyanide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.577 BB 269.92654 3.72896e-4 1.00655e-1 Hydrogen Cyanide 

Totals : 1.00655e-1

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\001-0201.D

Sample Name: hplc50pg50 #1

 =====================================================================

 Acq. Operator : KHB Seq. Line : 2

 Acq. Instrument : Grandmama Location : -

 Injection Date : 4/28/2010 7:37:40 PM Inj : 1

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 4/8/2010 9:49:36 AM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M

 Last changed : 4/29/2010 3:34:02 PM by ARM

 =====================================================================

Instrument 3 4/29/2010 3:35:08 PM ARM Page 1 of 1

EA# 0310-129 Page 67 of 221
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\001-0202.D)

 Area: 252.821

 1.733

 8.522 - Hydrogen Cyanide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.522 MM 252.82149 3.72896e-4 9.42762e-2 Hydrogen Cyanide 

Totals : 9.42762e-2

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\001-0202.D

Sample Name: hplc50pg50 #1

 =====================================================================

 Acq. Operator : KHB Seq. Line : 2

 Acq. Instrument : Grandmama Location : -

 Injection Date : 4/28/2010 7:52:55 PM Inj : 2

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 4/8/2010 9:49:36 AM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M

 Last changed : 4/29/2010 3:34:02 PM by ARM

 =====================================================================

Instrument 3 4/29/2010 3:35:03 PM ARM Page 1 of 1

EA# 0310-129 Page 68 of 221
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\002-0301.D) 1.452 1.736 2.272 8.481 - Hydrogen Cyanide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.481 BB 1100.36694 4.73887e-4 5.21449e-1 Hydrogen Cyanide 

Totals : 5.21449e-1

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\002-0301.D

Sample Name: hplc50pg50 #2

 =====================================================================

 Acq. Operator : KHB Seq. Line : 3

 Acq. Instrument : Grandmama Location : -

 Injection Date : 4/28/2010 8:08:11 PM Inj : 1

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 4/8/2010 9:49:36 AM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M

 Last changed : 4/29/2010 3:34:02 PM by ARM

 =====================================================================

Instrument 3 4/29/2010 3:35:38 PM ARM Page 1 of 1

EA# 0310-129 Page 69 of 221
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\002-0302.D) 1.732 2.103 2.272 8.459 - Hydrogen Cyanide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.459 BB 1169.17957 4.75892e-4 5.56403e-1 Hydrogen Cyanide 

Totals : 5.56403e-1

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\002-0302.D

Sample Name: hplc50pg50 #2

 =====================================================================

 Acq. Operator : KHB Seq. Line : 3

 Acq. Instrument : Grandmama Location : -

 Injection Date : 4/28/2010 8:23:27 PM Inj : 2

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 4/8/2010 9:49:36 AM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M

 Last changed : 4/29/2010 3:34:02 PM by ARM

 =====================================================================

Instrument 3 4/29/2010 3:35:44 PM ARM Page 1 of 1

EA# 0310-129 Page 70 of 221
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\003-0401.D) 1.454 1.740 8.431 - Hydrogen Cyanide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.431 BB 2165.91235 4.90647e-4 1.06270 Hydrogen Cyanide 

Totals : 1.06270

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\003-0401.D

Sample Name: hplc50pg50 #3

 =====================================================================

 Acq. Operator : KHB Seq. Line : 4

 Acq. Instrument : Grandmama Location : -

 Injection Date : 4/28/2010 8:38:44 PM Inj : 1

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 4/8/2010 9:49:36 AM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M

 Last changed : 4/29/2010 3:34:02 PM by ARM

 =====================================================================

Instrument 3 4/29/2010 3:35:51 PM ARM Page 1 of 1

EA# 0310-129 Page 71 of 221
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\003-0402.D) 1.741 8.393 - Hydrogen Cyanide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.393 BB 2089.41333 4.90013e-4 1.02384 Hydrogen Cyanide 

Totals : 1.02384

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\003-0402.D

Sample Name: hplc50pg50 #3

 =====================================================================

 Acq. Operator : KHB Seq. Line : 4

 Acq. Instrument : Grandmama Location : -

 Injection Date : 4/28/2010 8:54:00 PM Inj : 2

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 4/8/2010 9:49:36 AM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M

 Last changed : 4/29/2010 3:34:02 PM by ARM

 =====================================================================

Instrument 3 4/29/2010 3:35:57 PM ARM Page 1 of 1

EA# 0310-129 Page 72 of 221
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\004-0501.D) 1.455 1.671 1.744 8.371 - Hydrogen Cyanide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.371 BB 3034.00415 4.95599e-4 1.50365 Hydrogen Cyanide 

Totals : 1.50365

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\004-0501.D

Sample Name: hplc50pg50 #4

 =====================================================================

 Acq. Operator : KHB Seq. Line : 5

 Acq. Instrument : Grandmama Location : -

 Injection Date : 4/28/2010 9:09:17 PM Inj : 1

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 4/8/2010 9:49:36 AM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M

 Last changed : 4/29/2010 3:34:02 PM by ARM

 =====================================================================

Instrument 3 4/29/2010 3:36:08 PM ARM Page 1 of 1

EA# 0310-129 Page 73 of 221
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\004-0502.D) 1.442 1.734 8.355 - Hydrogen Cyanide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.355 BB 3191.10425 4.96207e-4 1.58345 Hydrogen Cyanide 

Totals : 1.58345

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\004-0502.D

Sample Name: hplc50pg50 #4

 =====================================================================

 Acq. Operator : KHB Seq. Line : 5

 Acq. Instrument : Grandmama Location : -

 Injection Date : 4/28/2010 9:24:33 PM Inj : 2

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 4/8/2010 9:49:36 AM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M

 Last changed : 4/29/2010 3:34:02 PM by ARM

 =====================================================================

Instrument 3 4/29/2010 3:36:14 PM ARM Page 1 of 1

EA# 0310-129 Page 74 of 221
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\005-0601.D) 1.443 1.658 1.731 2.257 8.306 - Hydrogen Cyanide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.306 BB 3990.75879 4.98561e-4 1.98964 Hydrogen Cyanide 

Totals : 1.98964

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\005-0601.D

Sample Name: hplc50pg50 #5

 =====================================================================

 Acq. Operator : KHB Seq. Line : 6

 Acq. Instrument : Grandmama Location : -

 Injection Date : 4/28/2010 9:39:50 PM Inj : 1

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 4/8/2010 9:49:36 AM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M

 Last changed : 4/29/2010 3:34:02 PM by ARM

 =====================================================================

Instrument 3 4/29/2010 3:36:21 PM ARM Page 1 of 1

EA# 0310-129 Page 75 of 221
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\005-0602.D) 1.674 1.740 1.956 2.275 8.315 - Hydrogen Cyanide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.315 BB 4036.59741 4.98667e-4 2.01292 Hydrogen Cyanide 

Totals : 2.01292

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\005-0602.D

Sample Name: hplc50pg50 #5

 =====================================================================

 Acq. Operator : KHB Seq. Line : 6

 Acq. Instrument : Grandmama Location : -

 Injection Date : 4/28/2010 9:55:06 PM Inj : 2

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 4/8/2010 9:49:36 AM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M

 Last changed : 4/29/2010 3:34:02 PM by ARM

 =====================================================================

Instrument 3 4/29/2010 3:36:27 PM ARM Page 1 of 1

EA# 0310-129 Page 76 of 221
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\006-0701.D) 1.673 1.747 1.887 2.287 8.387 - Hydrogen Cyanide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.387 BB 1864.51013 4.87849e-4 9.09599e-1 Hydrogen Cyanide 

Totals : 9.09599e-1

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\006-0701.D

Sample Name: hplc50pg50 #LCS

 =====================================================================

 Acq. Operator : KHB Seq. Line : 7

 Acq. Instrument : Grandmama Location : -

 Injection Date : 4/28/2010 10:10:24 PM Inj : 1

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 4/8/2010 9:49:36 AM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M

 Last changed : 4/29/2010 3:34:02 PM by ARM

 =====================================================================

Instrument 3 4/29/2010 3:36:34 PM ARM Page 1 of 1

EA# 0310-129 Page 77 of 221
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\006-0702.D)

 Area: 1831.14

 1.388

 1.588 1.674 1.741

 2.275

 8.357 - Hydrogen Cyanide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.357 MM 1831.14062 4.87482e-4 8.92649e-1 Hydrogen Cyanide 

Totals : 8.92649e-1

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\006-0702.D

Sample Name: hplc50pg50 #LCS

 =====================================================================

 Acq. Operator : KHB Seq. Line : 7

 Acq. Instrument : Grandmama Location : -

 Injection Date : 4/28/2010 10:25:39 PM Inj : 2

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 4/8/2010 9:49:36 AM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M

 Last changed : 4/29/2010 3:34:02 PM by ARM

 =====================================================================

Instrument 3 4/29/2010 3:39:33 PM ARM Page 1 of 1

EA# 0310-129 Page 78 of 221
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\003-1101.D) 1.739 8.315 - Hydrogen Cyanide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.315 BB 2011.98828 4.89323e-4 9.84511e-1 Hydrogen Cyanide 

Totals : 9.84511e-1

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\003-1101.D

Sample Name: hplc50pg50 #3

 =====================================================================

 Acq. Operator : KHB Seq. Line : 11

 Acq. Instrument : Grandmama Location : -

 Injection Date : 4/29/2010 12:12:36 AM Inj : 1

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 4/8/2010 9:49:36 AM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M

 Last changed : 4/29/2010 3:34:02 PM by ARM

 =====================================================================

Instrument 3 4/29/2010 3:36:48 PM ARM Page 1 of 1

EA# 0310-129 Page 79 of 221
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\003-1102.D)

 Area: 2104.16

 1.673 1.741

 8.341 - Hydrogen Cyanide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.341 MM 2104.15771 4.90139e-4 1.03133 Hydrogen Cyanide 

Totals : 1.03133

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\003-1102.D

Sample Name: hplc50pg50 #3

 =====================================================================

 Acq. Operator : KHB Seq. Line : 11

 Acq. Instrument : Grandmama Location : -

 Injection Date : 4/29/2010 12:27:51 AM Inj : 2

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 4/8/2010 9:49:36 AM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M

 Last changed : 4/29/2010 3:34:02 PM by ARM

 =====================================================================

Instrument 3 4/29/2010 3:37:04 PM ARM Page 1 of 1

EA# 0310-129 Page 80 of 221
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\003-1801.D) 1.741 8.321 - Hydrogen Cyanide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.321 BB 2030.78601 4.89495e-4 9.94060e-1 Hydrogen Cyanide 

Totals : 9.94060e-1

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\003-1801.D

Sample Name: hplc50pg50 #3

 =====================================================================

 Acq. Operator : KHB Seq. Line : 18

 Acq. Instrument : Grandmama Location : -

 Injection Date : 4/29/2010 3:46:32 AM Inj : 1

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 4/8/2010 9:49:36 AM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M

 Last changed : 4/29/2010 3:34:02 PM by ARM

 =====================================================================

Instrument 3 4/29/2010 3:37:14 PM ARM Page 1 of 1

EA# 0310-129 Page 81 of 221
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\003-1802.D) 1.677 1.751 8.375 - Hydrogen Cyanide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.375 BB 2210.80005 4.90998e-4 1.08550 Hydrogen Cyanide 

Totals : 1.08550

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\003-1802.D

Sample Name: hplc50pg50 #3

 =====================================================================

 Acq. Operator : KHB Seq. Line : 18

 Acq. Instrument : Grandmama Location : -

 Injection Date : 4/29/2010 4:01:47 AM Inj : 2

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 4/8/2010 9:49:36 AM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M

 Last changed : 4/29/2010 3:34:02 PM by ARM

 =====================================================================

Instrument 3 4/29/2010 3:37:21 PM ARM Page 1 of 1

EA# 0310-129 Page 82 of 221
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\003-2501.D)

 Area: 1989.32

 1.460

 1.677 1.747

 1.950

 2.275

 8.753 - Hydrogen Cyanide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.753 MM 1989.31726 4.89110e-4 9.72995e-1 Hydrogen Cyanide 

Totals : 9.72995e-1

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\003-2501.D

Sample Name: hplc50pg50 #3

 =====================================================================

 Acq. Operator : KHB Seq. Line : 25

 Acq. Instrument : Grandmama Location : -

 Injection Date : 4/29/2010 7:20:23 AM Inj : 1

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 4/8/2010 9:49:36 AM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M

 Last changed : 4/29/2010 3:34:02 PM by ARM

 =====================================================================

Instrument 3 4/29/2010 3:37:45 PM ARM Page 1 of 1

EA# 0310-129 Page 83 of 221
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\003-2502.D) 1.750 8.776 - Hydrogen Cyanide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.776 BB 1963.49866 4.88862e-4 9.59881e-1 Hydrogen Cyanide 

Totals : 9.59881e-1

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\003-2502.D

Sample Name: hplc50pg50 #3

 =====================================================================

 Acq. Operator : KHB Seq. Line : 25

 Acq. Instrument : Grandmama Location : -

 Injection Date : 4/29/2010 7:35:39 AM Inj : 2

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 4/8/2010 9:49:36 AM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M

 Last changed : 4/29/2010 3:34:02 PM by ARM

 =====================================================================

Instrument 3 4/29/2010 3:37:51 PM ARM Page 1 of 1

EA# 0310-129 Page 84 of 221
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\003-3201.D)

 Area: 1973.17

 1.337 1.460 1.673 1.744 1.953 2.872

 8.766 - Hydrogen Cyanide

 12.620 12.791 12.923

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.766 MM 1973.17029 4.88956e-4 9.64793e-1 Hydrogen Cyanide 

Totals : 9.64793e-1

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\003-3201.D

Sample Name: hplc50pg50 #3

 =====================================================================

 Acq. Operator : KHB Seq. Line : 32

 Acq. Instrument : Grandmama Location : -

 Injection Date : 4/29/2010 10:54:16 AM Inj : 1

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 4/8/2010 9:49:36 AM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M

 Last changed : 4/29/2010 3:34:02 PM by ARM

 =====================================================================

Instrument 3 4/29/2010 3:38:09 PM ARM Page 1 of 1

EA# 0310-129 Page 85 of 221
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\003-3202.D) 1.571 1.676 1.748 5.950 8.791 - Hydrogen Cyanide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.791 BB 1956.64355 4.88796e-4 9.56399e-1 Hydrogen Cyanide 

Totals : 9.56399e-1

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\003-3202.D

Sample Name: hplc50pg50 #3

 =====================================================================

 Acq. Operator : KHB Seq. Line : 32

 Acq. Instrument : Grandmama Location : -

 Injection Date : 4/29/2010 11:09:32 AM Inj : 2

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 4/8/2010 9:49:36 AM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M

 Last changed : 4/29/2010 3:34:02 PM by ARM

 =====================================================================

Instrument 3 4/29/2010 3:38:18 PM ARM Page 1 of 1

EA# 0310-129 Page 86 of 221
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\003-3501.D)

 Area: 1983.16

 1.383 1.460

 1.673 1.741

 2.026

 2.283

 8.737 - Hydrogen Cyanide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.737 MM 1983.16333 4.89052e-4 9.69869e-1 Hydrogen Cyanide 

Totals : 9.69869e-1

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\003-3501.D

Sample Name: hplc50pg50 #3

 =====================================================================

 Acq. Operator : KHB Seq. Line : 35

 Acq. Instrument : Grandmama Location : -

 Injection Date : 4/29/2010 12:25:55 PM Inj : 1

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 4/8/2010 9:49:36 AM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M

 Last changed : 4/29/2010 3:34:02 PM by ARM

 =====================================================================

Instrument 3 4/29/2010 3:38:46 PM ARM Page 1 of 1

EA# 0310-129 Page 87 of 221
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\003-3502.D) 1.292 1.741 2.042 8.723 - Hydrogen Cyanide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.723 BB 1926.78931 4.88499e-4 9.41234e-1 Hydrogen Cyanide 

Totals : 9.41234e-1

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\003-3502.D

Sample Name: hplc50pg50 #3

 =====================================================================

 Acq. Operator : KHB Seq. Line : 35

 Acq. Instrument : Grandmama Location : -

 Injection Date : 4/29/2010 12:41:11 PM Inj : 2

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 4/8/2010 9:49:36 AM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M

 Last changed : 4/29/2010 3:34:02 PM by ARM

 =====================================================================

Instrument 3 4/29/2010 3:38:33 PM ARM Page 1 of 1

EA# 0310-129 Page 88 of 221
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\004-4301.D) 1.656 1.734 8.449 - Hydrogen Cyanide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.449 BB 3046.42651 4.95649e-4 1.50996 Hydrogen Cyanide 

Totals : 1.50996

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\004-4301.D

Sample Name: hplc50pg50 #4

 =====================================================================

 Acq. Operator : KHB Seq. Line : 43

 Acq. Instrument : Grandmama Location : -

 Injection Date : 4/29/2010 6:56:52 PM Inj : 1

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 4/8/2010 9:49:36 AM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M

 Last changed : 4/29/2010 3:34:02 PM by ARM

 =====================================================================

Instrument 3 4/30/2010 2:21:53 PM ARM Page 1 of 1

EA# 0310-129 Page 89 of 221
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\004-4302.D) 1.651 1.725 8.334 - Hydrogen Cyanide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.334 BB 3101.69263 4.95868e-4 1.53803 Hydrogen Cyanide 

Totals : 1.53803

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\004-4302.D

Sample Name: hplc50pg50 #4

 =====================================================================

 Acq. Operator : KHB Seq. Line : 43

 Acq. Instrument : Grandmama Location : -

 Injection Date : 4/29/2010 7:12:07 PM Inj : 2

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 4/8/2010 9:49:36 AM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M

 Last changed : 4/29/2010 3:34:02 PM by ARM

 =====================================================================

Instrument 3 4/30/2010 2:21:59 PM ARM Page 1 of 1

EA# 0310-129 Page 90 of 221
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\004-5001.D)

 Area: 3294.81

 1.656 1.736

 8.054 - Hydrogen Cyanide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.054 MM 3294.80566 4.96577e-4 1.63612 Hydrogen Cyanide 

Totals : 1.63612

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\004-5001.D

Sample Name: hplc50pg50 #4

 =====================================================================

 Acq. Operator : KHB Seq. Line : 50

 Acq. Instrument : Grandmama Location : -

 Injection Date : 4/29/2010 10:30:49 PM Inj : 1

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 4/8/2010 9:49:36 AM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M

 Last changed : 4/29/2010 3:34:02 PM by ARM

 =====================================================================

Instrument 3 4/30/2010 2:22:21 PM ARM Page 1 of 1

EA# 0310-129 Page 91 of 221
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\004-5002.D)

 Area: 3310.67

 1.651 1.734 1.843

 2.259

 8.015 - Hydrogen Cyanide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.015 MM 3310.66772 4.96631e-4 1.64418 Hydrogen Cyanide 

Totals : 1.64418

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\004-5002.D

Sample Name: hplc50pg50 #4

 =====================================================================

 Acq. Operator : KHB Seq. Line : 50

 Acq. Instrument : Grandmama Location : -

 Injection Date : 4/29/2010 10:46:05 PM Inj : 2

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 4/8/2010 9:49:36 AM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M

 Last changed : 4/29/2010 3:34:02 PM by ARM

 =====================================================================

Instrument 3 4/30/2010 2:22:42 PM ARM Page 1 of 1

EA# 0310-129 Page 92 of 221
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\004-5701.D) 1.657 1.735 1.855 2.271 7.996 - Hydrogen Cyanide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 7.996 BB 3246.41724 4.96407e-4 1.61154 Hydrogen Cyanide 

Totals : 1.61154

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\004-5701.D

Sample Name: hplc50pg50 #4

 =====================================================================

 Acq. Operator : KHB Seq. Line : 57

 Acq. Instrument : Grandmama Location : -

 Injection Date : 4/30/2010 2:04:51 AM Inj : 1

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 4/8/2010 9:49:36 AM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M

 Last changed : 4/29/2010 3:34:02 PM by ARM

 =====================================================================

Instrument 3 4/30/2010 2:22:50 PM ARM Page 1 of 1

EA# 0310-129 Page 93 of 221
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\004-5702.D) 1.664 1.742 8.024 - Hydrogen Cyanide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.024 BB 3291.89136 4.96567e-4 1.63464 Hydrogen Cyanide 

Totals : 1.63464

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\004-5702.D

Sample Name: hplc50pg50 #4

 =====================================================================

 Acq. Operator : KHB Seq. Line : 57

 Acq. Instrument : Grandmama Location : -

 Injection Date : 4/30/2010 2:20:13 AM Inj : 2

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 4/8/2010 9:49:36 AM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M

 Last changed : 4/29/2010 3:34:02 PM by ARM

 =====================================================================

Instrument 3 4/30/2010 2:23:04 PM ARM Page 1 of 1

EA# 0310-129 Page 94 of 221
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\004-6401.D) 1.665 1.746 8.335 - Hydrogen Cyanide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.335 BB 3212.47803 4.96285e-4 1.59430 Hydrogen Cyanide 

Totals : 1.59430

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\004-6401.D

Sample Name: hplc50pg50 #4

 =====================================================================

 Acq. Operator : KHB Seq. Line : 64

 Acq. Instrument : Grandmama Location : -

 Injection Date : 4/30/2010 5:38:54 AM Inj : 1

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 4/8/2010 9:49:36 AM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M

 Last changed : 4/29/2010 3:34:02 PM by ARM

 =====================================================================

Instrument 3 4/30/2010 2:23:12 PM ARM Page 1 of 1

EA# 0310-129 Page 95 of 221
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\004-6402.D)

 Area: 3253.24

 1.656 1.736

 8.324 - Hydrogen Cyanide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.324 MM 3253.24146 4.96431e-4 1.61501 Hydrogen Cyanide 

Totals : 1.61501

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\004-6402.D

Sample Name: hplc50pg50 #4

 =====================================================================

 Acq. Operator : KHB Seq. Line : 64

 Acq. Instrument : Grandmama Location : -

 Injection Date : 4/30/2010 5:54:10 AM Inj : 2

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 4/8/2010 9:49:36 AM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M

 Last changed : 4/29/2010 3:34:02 PM by ARM

 =====================================================================

Instrument 3 4/30/2010 2:23:29 PM ARM Page 1 of 1

EA# 0310-129 Page 96 of 221
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\004-7101.D) 1.654 1.734 8.396 - Hydrogen Cyanide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.396 BB 3107.08252 4.95889e-4 1.54077 Hydrogen Cyanide 

Totals : 1.54077

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\004-7101.D

Sample Name: hplc50pg50 #4

 =====================================================================

 Acq. Operator : KHB Seq. Line : 71

 Acq. Instrument : Grandmama Location : -

 Injection Date : 4/30/2010 9:12:45 AM Inj : 1

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 4/8/2010 9:49:36 AM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M

 Last changed : 4/29/2010 3:34:02 PM by ARM

 =====================================================================

Instrument 3 4/30/2010 2:23:36 PM ARM Page 1 of 1

EA# 0310-129 Page 97 of 221
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\004-7102.D)

 Area: 3196.89

 1.655 1.733

 2.258

 8.391 - Hydrogen Cyanide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.391 MM 3196.88696 4.96228e-4 1.58639 Hydrogen Cyanide 

Totals : 1.58639

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\004-7102.D

Sample Name: hplc50pg50 #4

 =====================================================================

 Acq. Operator : KHB Seq. Line : 71

 Acq. Instrument : Grandmama Location : -

 Injection Date : 4/30/2010 9:28:02 AM Inj : 2

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 4/8/2010 9:49:36 AM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M

 Last changed : 4/29/2010 3:34:02 PM by ARM

 =====================================================================

Instrument 3 4/30/2010 2:23:50 PM ARM Page 1 of 1

EA# 0310-129 Page 98 of 221
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\004-7701.D) 1.664 1.739 8.435 - Hydrogen Cyanide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.435 BB 3081.66040 4.95790e-4 1.52786 Hydrogen Cyanide 

Totals : 1.52786

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\004-7701.D

Sample Name: hplc50pg50 #4

 =====================================================================

 Acq. Operator : KHB Seq. Line : 77

 Acq. Instrument : Grandmama Location : -

 Injection Date : 4/30/2010 12:16:03 PM Inj : 1

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 4/8/2010 9:49:36 AM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M

 Last changed : 4/29/2010 3:34:02 PM by ARM

 =====================================================================

Instrument 3 4/30/2010 2:24:00 PM ARM Page 1 of 1

EA# 0310-129 Page 99 of 221
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\004-7702.D) 1.658 1.735 8.415 - Hydrogen Cyanide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.415 BB 3274.68652 4.96507e-4 1.62590 Hydrogen Cyanide 

Totals : 1.62590

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\004-7702.D

Sample Name: hplc50pg50 #4

 =====================================================================

 Acq. Operator : KHB Seq. Line : 77

 Acq. Instrument : Grandmama Location : -

 Injection Date : 4/30/2010 12:31:19 PM Inj : 2

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 4/8/2010 9:49:36 AM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M

 Last changed : 4/29/2010 3:34:02 PM by ARM

 =====================================================================

Instrument 3 4/30/2010 2:24:17 PM ARM Page 1 of 1

EA# 0310-129 Page 100 of 221
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\004-8401.D) 1.661 1.735 2.269 8.437 - Hydrogen Cyanide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.437 BB 3363.30884 4.96808e-4 1.67092 Hydrogen Cyanide 

Totals : 1.67092

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\004-8401.D

Sample Name: hplc50pg50 #4

 =====================================================================

 Acq. Operator : KHB Seq. Line : 84

 Acq. Instrument : Grandmama Location : -

 Injection Date : 4/30/2010 4:24:49 PM Inj : 1

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 4/30/2010 12:54:42 PM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M

 Last changed : 4/29/2010 3:34:02 PM by ARM

 =====================================================================

Instrument 3 4/30/2010 4:42:50 PM ARM Page 1 of 1

EA# 0310-129 Page 101 of 221
0 2 4 6 8 10 12 min

nC

50

100

150

200

250

300

350

400

 ADC1 A, ADC1 CHANNEL A (H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\004-8402.D) 1.660 1.736 8.432 - Hydrogen Cyanide

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Thursday, April 29, 2010 3:33:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [nC*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 8.432 BB 3268.78979 4.96486e-4 1.62291 Hydrogen Cyanide 

Totals : 1.62291

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GRANDMAM\DATA\APR\HPLC50PG76\004-8402.D

Sample Name: hplc50pg50 #4

 =====================================================================

 Acq. Operator : KHB Seq. Line : 84

 Acq. Instrument : Grandmama Location : -

 Injection Date : 4/30/2010 4:40:05 PM Inj : 2

 Acq. Method : H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Last changed : 4/30/2010 12:54:42 PM by KHB

 Analysis Method : H:\HPLC2010Q2\GRANDMAM\METHODS\HPLC50PG76.M

 Last changed : 4/29/2010 3:34:02 PM by ARM

 =====================================================================

Instrument 3 4/30/2010 4:55:11 PM ARM Page 1 of 1

EA# 0310-129 Page 102 of 221
 Method Information

 Method: H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

 Modified: 3/17/2010 at 9:48:43 AM

 Column: Dionex Ionpac AS7 4 X 250mm

 Eluent: 0.5M Sodium Acetate/0.1M NaOH/0.5% v/v Ethylenediamine

 Flow rate: 1.0 mL/min

=========================================================================

 ANALOG DIGITAL CONVERTER

=========================================================================

 Signal 1

 ---------------------

Description: ADC1 CHANNEL A

Source: Signal

Unit: nC

Units/Volt: 1000.000

Peakwidth (Data Rate): 0.133 Min (2.00 Hz)

Stop Time: 14.01 Min

Data Storage: All

Start Signal Source: External Device Will Start 35900

Timed Event Table:

 <no events>

 method: H:\HPLC2010Q1\GRANDMAM\METHODS\1000.M

Modified on: 3/17/2010 at 9:48:43 AM

Grandmama 3/17/2010 9:49:42 AM KHB Page 1 of 1

EA# 0310-129 Page 103 of 221
Sequence Table:

 Method and Injection Info Part:

 Line Location SampleName Method Inj SampleType InjVolume

 DataFile AutoBalance LimsID

 ==== ======== ==================== ==================== ======== ========== =========

 1 Vial 7 0.1N NaOH - RB 1000 4 Sample 

 

 2 Vial 1 hplc50pg50 #1 1000 2 Sample 

 3 Vial 2 hplc50pg50 #2 1000 2 Sample 

 4 Vial 3 hplc50pg50 #3 1000 2 Sample 

 5 Vial 4 hplc50pg50 #4 1000 2 Sample 

 6 Vial 5 hplc50pg50 #5 1000 2 Sample 

 7 Vial 6 hplc50pg50 #LCS 1000 2 Sample 

 8 Vial 7 0.1N NaOH - RB 1000 2 Sample 

 9 Vial 81 CTM033-1*5 0410-125 1000 2 Sample 

 10 Vial 82 CTM033-2*5 0410-125 1000 2 Sample 

 11 Vial 3 hplc50pg50 #3 1000 2 Sample 

 12 Vial 4 hplc50pg50 #4 1000 2 Sample 

 13 Vial 8 Run 1*5 0310-129 1000 2 Sample 

 14 Vial 9 Run 2*5 0310-129 1000 2 Sample 

 15 Vial 10 Run 3*5 0310-129 1000 2 Sample 

 16 Vial 11 Field Tr Blk*5 0310-129 1000 2 Sample 

 17 Vial 12 Reagent Blk*5 0310-129 1000 2 Sample 

 18 Vial 3 hplc50pg50 #3 1000 2 Sample 

 19 Vial 4 hplc50pg50 #4 1000 2 Sample 

 20 Vial 13 Imp Spk*5 0310-129 1000 2 Sample 

 21 Vial 14 LCS 1*100 0310-129 1000 2 Sample 

 22 Vial 15 LCS 2*100 0310-129 1000 2 Sample 

 23 Vial 16 U1-1*5 0410-101 1000 2 Sample 

 24 Vial 17 U1-2*5 0410-101 1000 2 Sample 

 25 Vial 3 hplc50pg50 #3 1000 2 Sample 

 26 Vial 4 hplc50pg50 #4 1000 2 Sample 

 27 Vial 18 U1-3*5 0410-101 1000 2 Sample 

Sequence: H:\HPLC2010Q1\GRANDMAM\SEQUENCE\HPLC50PG76.S

Instrument 3 4/30/2010 3:50:31 PM ARM Page 1 of 5

EA# 0310-129 Page 104 of 221
 Line Location SampleName Method Inj SampleType InjVolume

 DataFile AutoBalance LimsID

 ==== ======== ==================== ==================== ======== ========== =========

 28 Vial 19 U2-1*5 0410-101 1000 2 Sample 

 

 29 Vial 20 U2-2*5 0410-101 1000 2 Sample 

 30 Vial 21 U2-3*5 0410-101 1000 2 Sample 

 31 Vial 22 10N Rgt Blk*5 0410-101 1000 2 Sample 

 32 Vial 3 hplc50pg50 #3 1000 2 Sample 

 33 Vial 4 hplc50pg50 #4 1000 2 Sample 

 34 Vial 23 Field Blank*5 0410-101 1000 2 Sample 

 35 Vial 3 hplc50pg50 #3 1000 2 Sample 

 36 Vial 4 hplc50pg50 #4 1000 2 Sample 

 37 Vial 26 U1-HCN-NaOH-1*5 0410-22 1000 2 Sample 

 38 Vial 27 U1-HCN-PbAc-1*5 0410-22 1000 2 Sample 

 39 Vial 28 U1-HCN-NaOH-2*5 0410-22 1000 2 Sample 

 40 Vial 29 U1-HCN-PbAc-2*5 0410-22 1000 2 Sample 

 41 Vial 30 U1-HCN-NaOH-3*5 0410-22 1000 2 Sample 

 42 Vial 3 hplc50pg50 #3 1000 2 Sample 

 43 Vial 4 hplc50pg50 #4 1000 2 Sample 

 44 Vial 31 U1-HCN-PbAc-3*5 0410-22 1000 2 Sample 

 45 Vial 32 U2-HCN-NaOH-1*5 0410-22 1000 2 Sample 

 46 Vial 33 U2-HCN-PbAc-1*5 0410-22 1000 2 Sample 

 47 Vial 34 U2-HCN-NaOH-2*5 0410-22 1000 2 Sample 

 48 Vial 35 U2-HCN-PbAc-2*5 0410-22 1000 2 Sample 

 49 Vial 3 hplc50pg50 #3 1000 2 Sample 

 50 Vial 4 hplc50pg50 #4 1000 2 Sample 

 51 Vial 36 U2-HCN-NaOH-3*5 0410-22 1000 2 Sample 

 52 Vial 37 U2-HCN-PbAc-3*5 0410-22 1000 2 Sample 

 53 Vial 38 FB-NaOH*5 0410-22 1000 2 Sample 

 54 Vial 39 RB-NaOH*5 0410-22 1000 2 Sample 

 55 Vial 40 FS-NaOH*5 0410-22 1000 2 Sample 

 56 Vial 3 hplc50pg50 #3 1000 2 Sample 

 57 Vial 4 hplc50pg50 #4 1000 2 Sample 

Sequence: H:\HPLC2010Q1\GRANDMAM\SEQUENCE\HPLC50PG76.S

Instrument 3 4/30/2010 3:50:31 PM ARM Page 2 of 5

EA# 0310-129 Page 105 of 221
 Line Location SampleName Method Inj SampleType InjVolume

 DataFile AutoBalance LimsID

 ==== ======== ==================== ==================== ======== ========== =========

 58 Vial 41 FB-PbAc*5 0410-22 1000 2 Sample 

 

 59 Vial 42 RB-PbAc*5 0410-22 1000 2 Sample 

 60 Vial 43 LCS 1*100 0410-22 1000 2 Sample 

 61 Vial 44 LCS 2*100 0410-22 1000 2 Sample 

 62 Vial 45 M26-1*5 0310-104 1000 2 Sample 

 63 Vial 3 hplc50pg50 #3 1000 2 Sample 

 64 Vial 4 hplc50pg50 #4 1000 2 Sample 

 65 Vial 46 M26-2*5 0310-104 1000 2 Sample 

 66 Vial 47 M26-3*5 0310-104 1000 2 Sample 

 67 Vial 48 M26-FB*5 0310-104 1000 2 Sample 

 68 Vial 49 M26-FS*5 0310-104 1000 2 Sample 

 69 Vial 50 M26-RB*5 0310-104 1000 2 Sample 

 70 Vial 3 hplc50pg50 #3 1000 2 Sample 

 71 Vial 4 hplc50pg50 #4 1000 2 Sample 

 72 Vial 51 LCS 1*100 0310-104 1000 2 Sample 

 73 Vial 52 LCS 2*100 0310-104 1000 2 Sample 

 74 Vial 53 LCS 1*100 0410-95 1000 2 Sample 

 75 Vial 54 LCS 2*100 0410-95 1000 2 Sample 

 76 Vial 3 hplc50pg50 #3 1000 2 Sample 

 77 Vial 4 hplc50pg50 #4 1000 2 Sample 

 78 Vial 55 LD/Run 1*5 0310-129 1000 2 Sample 

 79 Vial 56 MS/Run 1 0310-129 1000 2 Sample 

 80 Vial 57 MSD/Run 1 0310-129 1000 2 Sample 

 81 Vial 58 LCS 1*100 0310-129 1000 2 Sample 

 82 Vial 59 LCS 2*100 0310-129 1000 2 Sample 

 83 Vial 3 hplc50pg50 #3 1000 2 Sample 

 84 Vial 4 hplc50pg50 #4 1000 2 Sample 

 85 Vial 60 LD/R1 6N NaOH*5 0410-95 1000 2 Sample 

 86 Vial 61 MS/R1 6N NaOH 0410-95 1000 2 Sample 

 87 Vial 62 MSD/R1 6N NaOH 0410-95 1000 2 Sample 

Sequence: H:\HPLC2010Q1\GRANDMAM\SEQUENCE\HPLC50PG76.S

Instrument 3 4/30/2010 3:50:31 PM ARM Page 3 of 5

EA# 0310-129 Page 106 of 221
 Line Location SampleName Method Inj SampleType InjVolume

 DataFile AutoBalance LimsID

 ==== ======== ==================== ==================== ======== ========== =========

 88 Vial 63 LD/R1 C4*5 0410-50 1000 2 Sample 

 

 89 Vial 64 MS/R1 C4 0410-50 1000 2 Sample 

 90 Vial 3 hplc50pg50 #3 1000 2 Sample 

 91 Vial 4 hplc50pg50 #4 1000 2 Sample 

 92 Vial 65 MSD/R1 C4 0410-50 1000 2 Sample 

 93 Vial 66 LD/U1 R1*5 0410-101 1000 2 Sample 

 94 Vial 67 MS/U1 R1 0410-101 1000 2 Sample 

 95 Vial 68 MSD/U1 R1 0410-101 1000 2 Sample 

 96 Vial 69 LD/U1-1*5 0410-22 1000 2 Sample 

 97 Vial 3 hplc50pg50 #3 1000 2 Sample 

 98 Vial 4 hplc50pg50 #4 1000 2 Sample 

 99 Vial 70 MS/U1-1 0410-22 1000 2 Sample 

 100 Vial 71 MSD/U1-1 0410-22 1000 2 Sample 

 101 Vial 72 LD/U2-1*5 0410-22 1000 2 Sample 

 102 Vial 73 MS/U2-1 0410-22 1000 2 Sample 

 103 Vial 74 MSD/U2-1 0410-22 1000 2 Sample 

 104 Vial 3 hplc50pg50 #3 1000 2 Sample 

 105 Vial 4 hplc50pg50 #4 1000 2 Sample 

 106 Vial 75 LD/M26-1*5 0310-104 1000 2 Sample 

 107 Vial 76 MS/M26-1 0310-104 1000 2 Sample 

 108 Vial 77 MSD/M26-1 0310-104 1000 2 Sample 

 109 Vial 78 U1,2 R1*5 0410-106 1000 2 Sample 

 110 Vial 79 U1,2 R2*5 0410-106 1000 2 Sample 

 111 Vial 3 hplc50pg50 #3 1000 2 Sample 

 112 Vial 4 hplc50pg50 #4 1000 2 Sample 

 113 Vial 80 U1,2 R3*5 0410-106 1000 2 Sample 

 114 Vial 81 U3 R1*5 0410-106 1000 2 Sample 

 115 Vial 82 U3 R2*5 0410-106 1000 2 Sample 

 116 Vial 83 U3 R3*5 0410-106 1000 2 Sample 

 117 Vial 84 RB*5 0410-106 1000 2 Sample 

Sequence: H:\HPLC2010Q1\GRANDMAM\SEQUENCE\HPLC50PG76.S

Instrument 3 4/30/2010 3:50:31 PM ARM Page 4 of 5

EA# 0310-129 Page 107 of 221
 Line Location SampleName Method Inj SampleType InjVolume

 DataFile AutoBalance LimsID

 ==== ======== ==================== ==================== ======== ========== =========

 118 Vial 3 hplc50pg50 #3 1000 2 Sample 

 

 119 Vial 4 hplc50pg50 #4 1000 2 Sample 

Sequence: H:\HPLC2010Q1\GRANDMAM\SEQUENCE\HPLC50PG76.S

Instrument 3 4/30/2010 3:50:31 PM ARM Page 5 of 5

EA# 0310-129 Page 108 of 221
Sample 

Chromatograms

EA# 0310-129 Page 109 of 221
=====================================================================

Acq. Operator : KHB Seq. Line : 4

Acq. Instrument : Groucho Location : Vial 11

Injection Date : 4/27/2010 5:22:46 PM Inj : 1

 Inj Volume : 15 μl

Acq. Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG84@.M

Last changed : 4/7/2010 2:42:28 PM by KHB

Analysis Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG86D.M

Last changed : 4/29/2010 6:04:31 PM by ARM

 (modified after loading)

5 10 15 20 25 30 min

mAU 

0

100

200

300

400

500

600

700

800

 VWD1 A, Wavelength=360 nm (H:\HPLC2010Q2\GROUCHO\DATA\APR\HPLC48PG102\011-0401.D)

 Area: 109.113

0.811 1.035

 1.486

 2.110

 3.601

 4.290

 4.974

 6.571 - Formaldehyde

 8.598

 10.837

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 4/29/2010 6:04:32 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: VWD1 A, Wavelength=360 nm

RetTime Type Area Amt/Area Amount Grp Name

 [min] mAU *s [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 6.571 MM 109.11267 2.07188e-3 2.26069e-1 Formaldehyde 

Totals : 2.26069e-1

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GROUCHO\DATA\APR\HPLC48PG102\011-0401.D

Sample Name: Run 1 0310-129

Instrument 3 4/29/2010 6:08:54 PM ARM Page 1 of 1

EA# 0310-129 Page 110 of 221
=====================================================================

Acq. Operator : KHB Seq. Line : 5

Acq. Instrument : Groucho Location : Vial 11

Injection Date : 4/27/2010 5:59:25 PM Inj : 1

 Inj Volume : 15 μl

Acq. Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG84@.M

Last changed : 4/7/2010 2:42:28 PM by KHB

Analysis Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG86D.M

Last changed : 4/29/2010 6:04:31 PM by ARM

 (modified after loading)

Sample Info : Duplicate Injection

 

5 10 15 20 25 30 min

mAU 

0

100

200

300

400

500

600

700

800

 VWD1 A, Wavelength=360 nm (H:\HPLC2010Q2\GROUCHO\DATA\APR\HPLC48PG102\011-0501.D)

 Area: 109.499

0.813

1.057 1.260 1.517

 2.146

 3.633

 4.307

 4.991

 6.581 - Formaldehyde

 8.590

 10.801

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 4/29/2010 6:04:32 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: VWD1 A, Wavelength=360 nm

RetTime Type Area Amt/Area Amount Grp Name

 [min] mAU *s [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 6.581 MM 109.49865 2.07188e-3 2.26869e-1 Formaldehyde 

Totals : 2.26869e-1

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GROUCHO\DATA\APR\HPLC48PG102\011-0501.D

Sample Name: Run 1 0310-129

Instrument 3 4/29/2010 6:09:11 PM ARM Page 1 of 1

EA# 0310-129 Page 111 of 221
=====================================================================

Acq. Operator : KHB Seq. Line : 6

Acq. Instrument : Groucho Location : Vial 12

Injection Date : 4/27/2010 6:36:00 PM Inj : 1

 Inj Volume : 15 μl

Acq. Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG84@.M

Last changed : 4/7/2010 2:42:28 PM by KHB

Analysis Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG86D.M

Last changed : 4/29/2010 6:09:28 PM by ARM

 (modified after loading)

Sample Info : Duplicate Sample

 

5 10 15 20 25 30 min

mAU 

0

100

200

300

400

500

600

700

800

 VWD1 A, Wavelength=360 nm (H:\HPLC2010Q2\GROUCHO\DATA\APR\HPLC48PG102\012-0601.D)

 Area: 132.509

0.905 1.077

 1.546

 2.198

 3.717

 4.551

 5.682

 7.623 - Formaldehyde

 9.194

 11.244

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 4/29/2010 6:09:28 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: VWD1 A, Wavelength=360 nm

RetTime Type Area Amt/Area Amount Grp Name

 [min] mAU *s [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 7.623 MM 132.50926 2.07188e-3 2.74544e-1 Formaldehyde 

Totals : 2.74544e-1

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GROUCHO\DATA\APR\HPLC48PG102\012-0601.D

Sample Name: Run 1 Dup 0310-129

Instrument 3 4/29/2010 6:09:31 PM ARM Page 1 of 1

EA# 0310-129 Page 112 of 221
=====================================================================

Acq. Operator : KHB Seq. Line : 7

Acq. Instrument : Groucho Location : Vial 13

Injection Date : 4/27/2010 7:12:38 PM Inj : 1

 Inj Volume : 15 μl

Acq. Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG84@.M

Last changed : 4/7/2010 2:42:28 PM by KHB

Analysis Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG86D.M

Last changed : 4/29/2010 6:09:36 PM by ARM

 (modified after loading)

5 10 15 20 25 30 min

mAU 

0

100

200

300

400

500

600

700

800

 VWD1 A, Wavelength=360 nm (H:\HPLC2010Q2\GROUCHO\DATA\APR\HPLC48PG102\013-0701.D)

 Area: 81.3893

0.880 1.052

 1.510

 2.127

 3.609

 4.272

 6.523 - Formaldehyde

 8.489

 10.729

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 4/29/2010 6:09:37 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: VWD1 A, Wavelength=360 nm

RetTime Type Area Amt/Area Amount Grp Name

 [min] mAU *s [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 6.523 MM 81.38933 2.07188e-3 1.68629e-1 Formaldehyde 

Totals : 1.68629e-1

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GROUCHO\DATA\APR\HPLC48PG102\013-0701.D

Sample Name: Run 2 0310-129

Instrument 3 4/29/2010 6:09:55 PM ARM Page 1 of 1

EA# 0310-129 Page 113 of 221
=====================================================================

Acq. Operator : KHB Seq. Line : 8

Acq. Instrument : Groucho Location : Vial 14

Injection Date : 4/27/2010 7:49:19 PM Inj : 1

 Inj Volume : 15 μl

Acq. Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG84@.M

Last changed : 4/7/2010 2:42:28 PM by KHB

Analysis Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG86D.M

Last changed : 4/29/2010 6:09:36 PM by ARM

 (modified after loading)

5 10 15 20 25 30 min

mAU 

0

100

200

300

400

500

600

700

800

 VWD1 A, Wavelength=360 nm (H:\HPLC2010Q2\GROUCHO\DATA\APR\HPLC48PG102\014-0801.D)

 Area: 103.688

0.896 1.068

 1.540

 2.149

 3.593

 4.209

 4.949

 6.431 - Formaldehyde

 10.599

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 4/29/2010 6:09:37 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: VWD1 A, Wavelength=360 nm

RetTime Type Area Amt/Area Amount Grp Name

 [min] mAU *s [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 6.431 MM 103.68850 2.07188e-3 2.14831e-1 Formaldehyde 

Totals : 2.14831e-1

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GROUCHO\DATA\APR\HPLC48PG102\014-0801.D

Sample Name: Run 3 0310-129

Instrument 3 4/29/2010 6:10:07 PM ARM Page 1 of 1

EA# 0310-129 Page 114 of 221
=====================================================================

Acq. Operator : KHB Seq. Line : 9

Acq. Instrument : Groucho Location : Vial 15

Injection Date : 4/27/2010 8:25:55 PM Inj : 1

 Inj Volume : 15 μl

Acq. Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG84@.M

Last changed : 4/7/2010 2:42:28 PM by KHB

Analysis Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG86D.M

Last changed : 4/29/2010 6:09:36 PM by ARM

 (modified after loading)

5 10 15 20 25 30 min

mAU 

0

100

200

300

400

500

600

700

800

 VWD1 A, Wavelength=360 nm (H:\HPLC2010Q2\GROUCHO\DATA\APR\HPLC48PG102\015-0901.D)

 Area: 818.967

0.889 1.069

 1.528

 2.122

 3.535

 4.251

 4.875

 6.484 - Formaldehyde

 8.382

 10.484

 11.457

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 4/29/2010 6:09:37 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: VWD1 A, Wavelength=360 nm

RetTime Type Area Amt/Area Amount Grp Name

 [min] mAU *s [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 6.484 MM 818.96747 2.07188e-3 1.69681 Formaldehyde 

Totals : 1.69681

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GROUCHO\DATA\APR\HPLC48PG102\015-0901.D

Sample Name: Matrix Spike 0310-129

Instrument 3 4/29/2010 6:10:19 PM ARM Page 1 of 1

EA# 0310-129 Page 115 of 221
=====================================================================

Acq. Operator : KHB Seq. Line : 10

Acq. Instrument : Groucho Location : Vial 16

Injection Date : 4/27/2010 9:02:29 PM Inj : 1

 Inj Volume : 15 μl

Acq. Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG84@.M

Last changed : 4/7/2010 2:42:28 PM by KHB

Analysis Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG86D.M

Last changed : 4/29/2010 6:09:36 PM by ARM

 (modified after loading)

5 10 15 20 25 30 min

mAU 

0

100

200

300

400

500

600

700

800

 VWD1 A, Wavelength=360 nm (H:\HPLC2010Q2\GROUCHO\DATA\APR\HPLC48PG102\016-1001.D)

 Area: 2639.07

0.835 0.916 1.073

 1.565

 2.156

 3.568

 6.578 - Formaldehyde

 10.766

 11.390

 13.971

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 4/29/2010 6:09:37 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: VWD1 A, Wavelength=360 nm

RetTime Type Area Amt/Area Amount Grp Name

 [min] mAU *s [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 6.578 MM 2639.06616 2.07188e-3 5.46784 Formaldehyde 

Totals : 5.46784

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GROUCHO\DATA\APR\HPLC48PG102\016-1001.D

Sample Name: Imp Spike 0310-129

Instrument 3 4/29/2010 6:10:33 PM ARM Page 1 of 1

EA# 0310-129 Page 116 of 221
=====================================================================

Acq. Operator : KHB Seq. Line : 11

Acq. Instrument : Groucho Location : Vial 17

Injection Date : 4/27/2010 9:39:05 PM Inj : 1

 Inj Volume : 15 μl

Acq. Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG84@.M

Last changed : 4/7/2010 2:42:28 PM by KHB

Analysis Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG86D.M

Last changed : 4/29/2010 5:46:03 PM by ARM

 (modified after loading)

Sample Info : Sample Blank

 

5 10 15 20 25 30 min

mAU 

0

100

200

300

400

500

600

700

800

 VWD1 A, Wavelength=360 nm (H:\HPLC2010Q2\GROUCHO\DATA\APR\HPLC48PG102\017-1101.D)

0.880 1.067

 1.568

 2.144

 4.556

 7.663

 11.077

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 4/29/2010 5:46:07 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: VWD1 A, Wavelength=360 nm

RetTime Type Area Amt/Area Amount Grp Name

 [min] mAU *s [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 6.578 - - - Formaldehyde 

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

Data File H:\HPLC2010Q2\GROUCHO\DATA\APR\HPLC48PG102\017-1101.D

Sample Name: Field Blank 0310-129

Instrument 3 4/29/2010 5:46:41 PM ARM Page 1 of 2

EA# 0310-129 Page 117 of 221
=====================================================================

Acq. Operator : KHB Seq. Line : 12

Acq. Instrument : Groucho Location : Vial 18

Injection Date : 4/27/2010 10:15:50 PM Inj : 1

 Inj Volume : 15 μl

Acq. Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG84@.M

Last changed : 4/7/2010 2:42:28 PM by KHB

Analysis Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG86D.M

Last changed : 4/29/2010 6:09:36 PM by ARM

 (modified after loading)

Sample Info : Sample Blank

 

5 10 15 20 25 30 min

mAU 

0

100

200

300

400

500

600

700

800

 VWD1 A, Wavelength=360 nm (H:\HPLC2010Q2\GROUCHO\DATA\APR\HPLC48PG102\018-1201.D) 0.815

1.078

 1.567 2.161

 3.570

 6.543 - Formaldehyde

 10.472

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 4/29/2010 6:09:37 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: VWD1 A, Wavelength=360 nm

RetTime Type Area Amt/Area Amount Grp Name

 [min] mAU *s [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 6.543 BB 18.28996 2.07188e-3 3.78947e-2 Formaldehyde 

Totals : 3.78947e-2

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GROUCHO\DATA\APR\HPLC48PG102\018-1201.D

Sample Name: Reagent Blank 0310-129

Instrument 3 4/29/2010 6:10:56 PM ARM Page 1 of 1

EA# 0310-129 Page 118 of 221
=====================================================================

Acq. Operator : KHB Seq. Line : 14

Acq. Instrument : Groucho Location : Vial 19

Injection Date : 4/27/2010 11:29:13 PM Inj : 1

 Inj Volume : 15 μl

Acq. Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG84@.M

Last changed : 4/7/2010 2:42:28 PM by KHB

Analysis Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG86D.M

Last changed : 4/29/2010 6:11:11 PM by ARM

 (modified after loading)

Sample Info : Sample Blank

 

5 10 15 20 25 30 min

mAU 

0

100

200

300

400

500

600

700

800

 VWD1 A, Wavelength=360 nm (H:\HPLC2010Q2\GROUCHO\DATA\APR\HPLC48PG102\019-1401.D) 0.848 1.091 1.601 2.191 3.616 6.772 - Formaldehyde 10.728

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 4/29/2010 6:11:12 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: VWD1 A, Wavelength=360 nm

RetTime Type Area Amt/Area Amount Grp Name

 [min] mAU *s [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 6.772 BB 82.81754 2.07188e-3 1.71588e-1 Formaldehyde 

Totals : 1.71588e-1

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GROUCHO\DATA\APR\HPLC48PG102\019-1401.D

Sample Name: Sample Blank 0310-129

Instrument 3 4/29/2010 6:11:23 PM ARM Page 1 of 1

EA# 0310-129 Page 119 of 221
=====================================================================

Acq. Operator : KHB Seq. Line : 16

Acq. Instrument : Groucho Location : Vial 21

Injection Date : 4/28/2010 12:42:33 AM Inj : 1

 Inj Volume : 15 μl

Acq. Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG84@.M

Last changed : 4/7/2010 2:42:28 PM by KHB

Analysis Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG86D.M

Last changed : 4/29/2010 5:46:03 PM by ARM

 (modified after loading)

Sample Info : Method Blank

 

5 10 15 20 25 30 min

mAU 

0

100

200

300

400

500

600

700

800

 VWD1 A, Wavelength=360 nm (H:\HPLC2010Q2\GROUCHO\DATA\APR\HPLC48PG102\021-1601.D) 0.844 1.087 1.593 3.545

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 4/29/2010 5:46:07 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: VWD1 A, Wavelength=360 nm

RetTime Type Area Amt/Area Amount Grp Name

 [min] mAU *s [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 6.578 - - - Formaldehyde 

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

Data File H:\HPLC2010Q2\GROUCHO\DATA\APR\HPLC48PG102\021-1601.D

Sample Name: MB 4/20/10 0310-129

Instrument 3 4/29/2010 5:47:16 PM ARM Page 1 of 2

EA# 0310-129 Page 120 of 221
=====================================================================

Acq. Operator : KHB Seq. Line : 27

Acq. Instrument : Groucho Location : Vial 25

Injection Date : 4/28/2010 10:21:47 PM Inj : 1

 Inj Volume : 15 μl

Acq. Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG84@.M

Last changed : 4/7/2010 2:42:28 PM by KHB

Analysis Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG86D.M

Last changed : 4/29/2010 5:48:14 PM by ARM

 (modified after loading)

Sample Info : Method Blank

 

5 10 15 20 25 30 min

mAU 

0

100

200

300

400

500

600

700

800

 VWD1 A, Wavelength=360 nm (H:\HPLC2010Q2\GROUCHO\DATA\APR\HPLC48PG102\025-2701.D)

0.911 0.970 1.194

 1.757 2.457

 4.104

 11.140

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 4/29/2010 5:48:15 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: VWD1 A, Wavelength=360 nm

RetTime Type Area Amt/Area Amount Grp Name

 [min] mAU *s [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 7.291 - - - Formaldehyde 

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

Data File H:\HPLC2010Q2\GROUCHO\DATA\APR\HPLC48PG102\025-2701.D

Sample Name: MB 4/28/10 0310-129

Instrument 3 4/29/2010 5:48:59 PM ARM Page 1 of 2

EA# 0310-129 Page 121 of 221
=====================================================================

Acq. Operator : KHB Seq. Line : 9

Acq. Instrument : Groucho Location : Vial 8

Injection Date : 4/9/2010 2:42:40 AM Inj : 1

 Inj Volume : 15 μl

Acq. Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG84@.M

Last changed : 4/7/2010 2:42:28 PM by KHB

Analysis Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG86B.M

Last changed : 4/9/2010 11:19:06 AM by KHB

 (modified after loading)

Sample Info : Reagent Blank Acetonitrile

 

5 10 15 20 25 30 min

mAU 

0

100

200

300

400

500

600

700

800

 VWD1 A, Wavelength=360 nm (H:\HPLC2010Q2\GROUCHO\DATA\APR\0310-39B\008-0901.D)

0.961

 1.413

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 4/9/2010 11:19:07 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: VWD1 A, Wavelength=360 nm

RetTime Type Area Amt/Area Amount Grp Name

 [min] mAU *s [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 5.862 - - - Formaldehyde 

 7.737 - - - Acetaldehyde 

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

Data File H:\HPLC2010Q2\GROUCHO\DATA\APR\0310-39B\008-0901.D

Sample Name: RB/100% ACN

Instrument 3 4/9/2010 11:33:59 AM KHB Page 1 of 2

EA# 0310-129 Page 122 of 221
=====================================================================

Acq. Operator : KHB Seq. Line : 9

Acq. Instrument : Groucho Location : Vial 8

Injection Date : 4/9/2010 3:19:16 AM Inj : 2

 Inj Volume : 15 μl

Acq. Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG84@.M

Last changed : 4/7/2010 2:42:28 PM by KHB

Analysis Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG86B.M

Last changed : 4/9/2010 11:19:06 AM by KHB

 (modified after loading)

Sample Info : Reagent Blank Acetonitrile

 

5 10 15 20 25 30 min

mAU 

0

100

200

300

400

500

600

700

800

 VWD1 A, Wavelength=360 nm (H:\HPLC2010Q2\GROUCHO\DATA\APR\0310-39B\008-0902.D)

0.965

 1.419

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 4/9/2010 11:19:07 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: VWD1 A, Wavelength=360 nm

RetTime Type Area Amt/Area Amount Grp Name

 [min] mAU *s [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 5.862 - - - Formaldehyde 

 7.737 - - - Acetaldehyde 

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

Data File H:\HPLC2010Q2\GROUCHO\DATA\APR\0310-39B\008-0902.D

Sample Name: RB/100% ACN

Instrument 3 4/9/2010 11:34:09 AM KHB Page 1 of 2

EA# 0310-129 Page 123 of 221
=====================================================================

Acq. Operator : KHB Seq. Line : 3

Acq. Instrument : Groucho Location : Vial 2

Injection Date : 4/27/2010 4:46:06 PM Inj : 1

 Inj Volume : 15 μl

Acq. Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG84@.M

Last changed : 4/7/2010 2:42:28 PM by KHB

Analysis Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG86D.M

Last changed : 4/29/2010 5:43:30 PM by ARM

 (modified after loading)

Sample Info : Lab Blank Acetonitrile

 

5 10 15 20 25 30 min

mAU 

0

100

200

300

400

500

600

700

800

 VWD1 A, Wavelength=360 nm (H:\HPLC2010Q2\GROUCHO\DATA\APR\HPLC48PG102\002-0301.D)

0.934 1.079

 1.560

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 4/29/2010 5:43:30 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: VWD1 A, Wavelength=360 nm

RetTime Type Area Amt/Area Amount Grp Name

 [min] mAU *s [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 6.808 - - - Formaldehyde 

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

Data File H:\HPLC2010Q2\GROUCHO\DATA\APR\HPLC48PG102\002-0301.D

Sample Name: RB/100% ACN

Instrument 3 4/29/2010 5:44:30 PM ARM Page 1 of 2

EA# 0310-129 Page 124 of 221
=====================================================================

Acq. Operator : KHB Seq. Line : 24

Acq. Instrument : Groucho Location : Vial 22

Injection Date : 4/28/2010 8:31:56 PM Inj : 1

 Inj Volume : 15 μl

Acq. Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG84@.M

Last changed : 4/7/2010 2:42:28 PM by KHB

Analysis Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG86D.M

Last changed : 4/29/2010 6:12:09 PM by ARM

 (modified after loading)

Sample Info : Matrix Spike

 

5 10 15 20 25 30 min

mAU 

0

100

200

300

400

500

600

700

800

 VWD1 A, Wavelength=360 nm (H:\HPLC2010Q2\GROUCHO\DATA\APR\HPLC48PG102\022-2401.D)

 Area: 1337.21

0.947 1.192 1.452 1.756

 2.482

 4.153

 4.926

 7.396 - Formaldehyde

 11.221

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 4/29/2010 6:12:10 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: VWD1 A, Wavelength=360 nm

RetTime Type Area Amt/Area Amount Grp Name

 [min] mAU *s [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 7.396 MM 1337.20776 2.07188e-3 2.77054 Formaldehyde 

Totals : 2.77054

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GROUCHO\DATA\APR\HPLC48PG102\022-2401.D

Sample Name: MS/Run 2 0310-129

Instrument 3 4/29/2010 6:12:20 PM ARM Page 1 of 1

EA# 0310-129 Page 125 of 221
=====================================================================

Acq. Operator : KHB Seq. Line : 25

Acq. Instrument : Groucho Location : Vial 23

Injection Date : 4/28/2010 9:08:33 PM Inj : 1

 Inj Volume : 15 μl

Acq. Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG84@.M

Last changed : 4/7/2010 2:42:28 PM by KHB

Analysis Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG86D.M

Last changed : 4/29/2010 6:12:09 PM by ARM

 (modified after loading)

Sample Info : Matrix Spike Duplicate

 

5 10 15 20 25 30 min

mAU 

0

100

200

300

400

500

600

700

800

 VWD1 A, Wavelength=360 nm (H:\HPLC2010Q2\GROUCHO\DATA\APR\HPLC48PG102\023-2501.D)

 Area: 1248.4

0.956 1.202 1.433 1.760

 2.488

 4.158

 4.840

 5.608

 7.362 - Formaldehyde

 11.065

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 4/29/2010 6:12:10 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: VWD1 A, Wavelength=360 nm

RetTime Type Area Amt/Area Amount Grp Name

 [min] mAU *s [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 7.362 MM 1248.39954 2.07188e-3 2.58654 Formaldehyde 

Totals : 2.58654

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GROUCHO\DATA\APR\HPLC48PG102\023-2501.D

Sample Name: MSD/Run 2 0310-129

Instrument 3 4/29/2010 6:12:33 PM ARM Page 1 of 1

EA# 0310-129 Page 126 of 221
=====================================================================

Acq. Operator : KHB Seq. Line : 15

Acq. Instrument : Groucho Location : Vial 20

Injection Date : 4/28/2010 12:05:53 AM Inj : 1

 Inj Volume : 15 μl

Acq. Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG84@.M

Last changed : 4/7/2010 2:42:28 PM by KHB

Analysis Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG86D.M

Last changed : 4/29/2010 5:46:03 PM by ARM

 (modified after loading)

Sample Info : Lab Control Sample

 

5 10 15 20 25 30 min

mAU 

0

100

200

300

400

500

600

700

800

 VWD1 A, Wavelength=360 nm (H:\HPLC2010Q2\GROUCHO\DATA\APR\HPLC48PG102\020-1501.D) 0.832

1.078

 1.576

 3.564

 6.594 - Formaldehyde

 10.576

 11.258

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 4/29/2010 5:46:07 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: VWD1 A, Wavelength=360 nm

RetTime Type Area Amt/Area Amount Grp Name

 [min] mAU *s [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 6.594 BB 1831.14307 2.07188e-3 3.79392 Formaldehyde 

Totals : 3.79392

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GROUCHO\DATA\APR\HPLC48PG102\020-1501.D

Sample Name: LCS 4/20/10 0310-129

Instrument 3 4/29/2010 5:47:06 PM ARM Page 1 of 1

EA# 0310-129 Page 127 of 221
=====================================================================

Acq. Operator : KHB Seq. Line : 26

Acq. Instrument : Groucho Location : Vial 24

Injection Date : 4/28/2010 9:45:08 PM Inj : 1

 Inj Volume : 15 μl

Acq. Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG84@.M

Last changed : 4/7/2010 2:42:28 PM by KHB

Analysis Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG86D.M

Last changed : 4/29/2010 5:48:14 PM by ARM

 (modified after loading)

Sample Info : Lab Control Sample

 

5 10 15 20 25 30 min

mAU 

0

100

200

300

400

500

600

700

800

 VWD1 A, Wavelength=360 nm (H:\HPLC2010Q2\GROUCHO\DATA\APR\HPLC48PG102\024-2601.D)

0.942 1.191

 1.762 2.471

 4.135

 7.351 - Formaldehyde

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 4/29/2010 5:48:15 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: VWD1 A, Wavelength=360 nm

RetTime Type Area Amt/Area Amount Grp Name

 [min] mAU *s [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 7.351 BB 1121.91760 2.07188e-3 2.32448 Formaldehyde 

Totals : 2.32448

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GROUCHO\DATA\APR\HPLC48PG102\024-2601.D

Sample Name: LCS 4/28/10 0310-129

Instrument 3 4/29/2010 5:48:52 PM ARM Page 1 of 1

EA# 0310-129 Page 128 of 221
Calibration 

Curve Chromatograms

EA# 0310-129 Page 129 of 221
=====================================================================

 Calibration Table 

=====================================================================

Calib. Data Modified : Friday, April 09, 2010 11:17:27 AM

Calculate : External Standard

Based on : Peak Area

Rel. Reference Window : 5.000 %

Abs. Reference Window : 0.000 min

Rel. Non-ref. Window : 5.000 %

Abs. Non-ref. Window : 0.000 min

Use Multiplier & Dilution Factor with ISTDs

Uncalibrated Peaks : not reported

Partial Calibration : Yes, identified peaks are recalibrated

Correct All Ret. Times: No, only for identified peaks

Curve Type : Average Response/Amount

Origin : Ignored

Weight : Equal

Recalibration Settings: 

Average Response : Average all calibrations

Average Retention Time: Floating Average New 75%

Calibration Report Options :

 Printout of recalibrations within a sequence:

 Calibration Table after Recalibration

 Normal Report after Recalibration

 If the sequence is done with bracketing:

 Results of first cycle (ending previous bracket)

Signal 1: VWD1 A, Wavelength=360 nm

RetTime Lvl Amount Area Amt/Area Ref Grp Name 

 [min] Sig [ug/mL] 

-------|--|--|----------|----------|----------|---|--|---------------

 6.039 1 1 7.47000e-2 29.58253 2.52514e-3 Formaldehyde 

 2 7.15000e-1 321.21284 2.22594e-3 

 3 2.50000 1089.59088 2.29444e-3 

 4 5.00000 2856.31934 1.75050e-3 

 5 9.01000 4565.10059 1.97367e-3 

 6 15.00000 8053.14917 1.86263e-3 

 7.982 1 1 7.47000e-2 23.19861 3.22002e-3 Acetaldehyde 

 2 7.15000e-1 249.11855 2.87012e-3 

 3 2.50000 823.64679 3.03528e-3 

 4 5.00000 2169.08740 2.30512e-3 

 5 9.01000 3454.04468 2.60854e-3 

 6 15.00000 6113.48096 2.45359e-3 

=====================================================================

 Peak Sum Table 

=====================================================================

***No Entries in table***

=====================================================================

Method H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG86B.M

Instrument 3 4/9/2010 11:18:13 AM KHB Page 1 of 2

EA# 0310-129 Page 130 of 221
=====================================================================

 Calibration Curves

=====================================================================

Amount[ug/mL]

0 10

Area

0

1000

2000

3000

4000

5000

6000

7000

12

3

4

5

6 Formaldehyde at exp. RT: 6.039

VWD1 A, Wavelength=360 nm

Correlation: 0.99851

Residual Std. Dev.: 479.32330

Formula: y = mx

 m: 482.65230

 x: Amount

 y: Area

Amount[ug/mL]

0 10

Area

0

1000

2000

3000

4000

5000

1

2

3

4

5

6 Acetaldehyde at exp. RT: 7.982

VWD1 A, Wavelength=360 nm

Correlation: 0.99842

Residual Std. Dev.: 342.60343

Formula: y = mx

 m: 368.86216

 x: Amount

 y: Area

=====================================================================

Method H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG86B.M

Instrument 3 4/9/2010 11:18:13 AM KHB Page 2 of 2

EA# 0310-129 Page 131 of 221
=====================================================================

Acq. Operator : KHB Seq. Line : 2

Acq. Instrument : Groucho Location : Vial 1

Injection Date : 4/8/2010 6:09:35 PM Inj : 1

 Inj Volume : 15 μl

Acq. Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG84@.M

Last changed : 4/7/2010 2:42:28 PM by KHB

Analysis Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG86B.M

Last changed : 4/9/2010 11:17:42 AM by KHB

5 10 15 20 25 30 min

mAU 

0

100

200

300

400

500

600

700

800

 VWD1 A, Wavelength=360 nm (H:\HPLC2010Q2\GROUCHO\DATA\APR\0310-39B\001-0201.D)

0.963

 1.418

 6.038 - Formaldehyde

 7.975 - Acetaldehyde

 10.249 10.695 11.531 13.545

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Friday, April 09, 2010 11:17:27 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: VWD1 A, Wavelength=360 nm

RetTime Type Area Amt/Area Amount Grp Name

 [min] mAU *s [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 6.038 BB 29.62583 2.07188e-3 6.13813e-2 Formaldehyde 

 7.975 BB 23.49199 2.71104e-3 6.36877e-2 Acetaldehyde 

Totals : 1.25069e-1

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GROUCHO\DATA\APR\0310-39B\001-0201.D

Sample Name: hplc48pg84 #1

Instrument 3 4/9/2010 11:18:30 AM KHB Page 1 of 1

EA# 0310-129 Page 132 of 221
=====================================================================

Acq. Operator : KHB Seq. Line : 2

Acq. Instrument : Groucho Location : Vial 1

Injection Date : 4/8/2010 6:46:14 PM Inj : 2

 Inj Volume : 15 μl

Acq. Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG84@.M

Last changed : 4/7/2010 2:42:28 PM by KHB

Analysis Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG86B.M

Last changed : 4/9/2010 11:17:42 AM by KHB

5 10 15 20 25 30 min

mAU 

0

100

200

300

400

500

600

700

800

 VWD1 A, Wavelength=360 nm (H:\HPLC2010Q2\GROUCHO\DATA\APR\0310-39B\001-0202.D)

0.975

 1.431

 6.039 - Formaldehyde

 7.984 - Acetaldehyde 10.228 10.668

 11.511

 13.519

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Friday, April 09, 2010 11:17:27 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: VWD1 A, Wavelength=360 nm

RetTime Type Area Amt/Area Amount Grp Name

 [min] mAU *s [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 6.039 BB 29.53923 2.07188e-3 6.12019e-2 Formaldehyde 

 7.984 BB 22.90523 2.71104e-3 6.20970e-2 Acetaldehyde 

Totals : 1.23299e-1

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GROUCHO\DATA\APR\0310-39B\001-0202.D

Sample Name: hplc48pg84 #1

Instrument 3 4/9/2010 11:18:35 AM KHB Page 1 of 1

EA# 0310-129 Page 133 of 221
=====================================================================

Acq. Operator : KHB Seq. Line : 3

Acq. Instrument : Groucho Location : Vial 2

Injection Date : 4/8/2010 7:22:57 PM Inj : 1

 Inj Volume : 15 μl

Acq. Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG84@.M

Last changed : 4/7/2010 2:42:28 PM by KHB

Analysis Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG86B.M

Last changed : 4/9/2010 11:17:42 AM by KHB

5 10 15 20 25 30 min

mAU 

0

100

200

300

400

500

600

700

800

 VWD1 A, Wavelength=360 nm (H:\HPLC2010Q2\GROUCHO\DATA\APR\0310-39B\002-0301.D)

0.963

 1.413

 5.960 - Formaldehyde

 7.881 - Acetaldehyde 10.122

 10.555

 11.386

 13.976

 15.347

 16.762

 18.830

 19.622

 20.750

 21.289

 26.759

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Friday, April 09, 2010 11:17:27 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: VWD1 A, Wavelength=360 nm

RetTime Type Area Amt/Area Amount Grp Name

 [min] mAU *s [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 5.960 BB 321.01724 2.07188e-3 6.65111e-1 Formaldehyde 

 7.881 BB 249.59560 2.71104e-3 6.76664e-1 Acetaldehyde 

Totals : 1.34177

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GROUCHO\DATA\APR\0310-39B\002-0301.D

Sample Name: hplc48pg84 #2

Instrument 3 4/9/2010 11:18:40 AM KHB Page 1 of 1

EA# 0310-129 Page 134 of 221
=====================================================================

Acq. Operator : KHB Seq. Line : 3

Acq. Instrument : Groucho Location : Vial 2

Injection Date : 4/8/2010 7:59:41 PM Inj : 2

 Inj Volume : 15 μl

Acq. Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG84@.M

Last changed : 4/7/2010 2:42:28 PM by KHB

Analysis Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG86B.M

Last changed : 4/9/2010 11:17:42 AM by KHB

5 10 15 20 25 30 min

mAU 

0

100

200

300

400

500

600

700

800

 VWD1 A, Wavelength=360 nm (H:\HPLC2010Q2\GROUCHO\DATA\APR\0310-39B\002-0302.D)

0.965

 1.414

 5.941 - Formaldehyde

 7.853 - Acetaldehyde 10.069

 10.497

 11.323 13.278

 15.122

 16.579

 18.614

 19.398

 20.474

 21.017

 25.809

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Friday, April 09, 2010 11:17:27 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: VWD1 A, Wavelength=360 nm

RetTime Type Area Amt/Area Amount Grp Name

 [min] mAU *s [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 5.941 BB 321.40845 2.07188e-3 6.65921e-1 Formaldehyde 

 7.853 BB 248.64151 2.71104e-3 6.74077e-1 Acetaldehyde 

Totals : 1.34000

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GROUCHO\DATA\APR\0310-39B\002-0302.D

Sample Name: hplc48pg84 #2

Instrument 3 4/9/2010 11:18:45 AM KHB Page 1 of 1

EA# 0310-129 Page 135 of 221
=====================================================================

Acq. Operator : KHB Seq. Line : 4

Acq. Instrument : Groucho Location : Vial 3

Injection Date : 4/8/2010 8:36:20 PM Inj : 1

 Inj Volume : 15 μl

Acq. Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG84@.M

Last changed : 4/7/2010 2:42:28 PM by KHB

Analysis Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG86B.M

Last changed : 4/9/2010 11:17:42 AM by KHB

5 10 15 20 25 30 min

mAU 

0

100

200

300

400

500

600

700

800

 VWD1 A, Wavelength=360 nm (H:\HPLC2010Q2\GROUCHO\DATA\APR\0310-39B\003-0401.D)

0.964

 1.416

 3.096

 5.901 - Formaldehyde

 7.793 - Acetaldehyde

 10.000

 10.419

 11.240

 12.362

 13.177

 15.025

 16.432

 18.430

 19.191

 20.228

 20.754

 26.110

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Friday, April 09, 2010 11:17:27 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: VWD1 A, Wavelength=360 nm

RetTime Type Area Amt/Area Amount Grp Name

 [min] mAU *s [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 5.901 BB 1088.98560 2.07188e-3 2.25625 Formaldehyde 

 7.793 BB 821.97125 2.71104e-3 2.22840 Acetaldehyde 

Totals : 4.48465

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GROUCHO\DATA\APR\0310-39B\003-0401.D

Sample Name: hplc48pg84 #3

Instrument 3 4/9/2010 11:18:50 AM KHB Page 1 of 1

EA# 0310-129 Page 136 of 221
=====================================================================

Acq. Operator : KHB Seq. Line : 4

Acq. Instrument : Groucho Location : Vial 3

Injection Date : 4/8/2010 9:13:00 PM Inj : 2

 Inj Volume : 15 μl

Acq. Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG84@.M

Last changed : 4/7/2010 2:42:28 PM by KHB

Analysis Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG86B.M

Last changed : 4/9/2010 11:19:06 AM by KHB

 (modified after loading)

5 10 15 20 25 30 min

mAU 

0

100

200

300

400

500

600

700

800

 VWD1 A, Wavelength=360 nm (H:\HPLC2010Q2\GROUCHO\DATA\APR\0310-39B\003-0402.D)

0.961

 1.412

 3.065

 5.852 - Formaldehyde

 7.737 - Acetaldehyde

 9.932 10.347

 11.165

 12.262

 13.083

 14.451

 15.774

 18.289

 19.052

 20.059

 20.574

 25.489

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 4/9/2010 11:19:07 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: VWD1 A, Wavelength=360 nm

RetTime Type Area Amt/Area Amount Grp Name

 [min] mAU *s [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 5.852 BB 1090.19617 2.07188e-3 2.25876 Formaldehyde 

 7.737 BB 825.32233 2.71104e-3 2.23748 Acetaldehyde 

Totals : 4.49624

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GROUCHO\DATA\APR\0310-39B\003-0402.D

Sample Name: hplc48pg84 #3

Instrument 3 4/9/2010 11:19:11 AM KHB Page 1 of 1

EA# 0310-129 Page 137 of 221
=====================================================================

Acq. Operator : KHB Seq. Line : 5

Acq. Instrument : Groucho Location : Vial 4

Injection Date : 4/8/2010 9:49:38 PM Inj : 1

 Inj Volume : 15 μl

Acq. Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG84@.M

Last changed : 4/7/2010 2:42:28 PM by KHB

Analysis Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG86B.M

Last changed : 4/9/2010 11:19:06 AM by KHB

 (modified after loading)

5 10 15 20 25 30 min

mAU 

0

100

200

300

400

500

600

700

800

 VWD1 A, Wavelength=360 nm (H:\HPLC2010Q2\GROUCHO\DATA\APR\0310-39B\004-0501.D)

0.966

 1.420

 1.860

 3.069

 5.857 - Formaldehyde

 7.735 - Acetaldehyde

 9.902 10.316

 11.126

 12.217

 13.025

 14.877

 16.211

 18.148

 18.880

 19.865

 20.381

 25.373

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 4/9/2010 11:19:07 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: VWD1 A, Wavelength=360 nm

RetTime Type Area Amt/Area Amount Grp Name

 [min] mAU *s [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 5.857 BB 2848.55664 2.07188e-3 5.90188 Formaldehyde 

 7.735 BB 2164.07910 2.71104e-3 5.86690 Acetaldehyde 

Totals : 11.76879

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GROUCHO\DATA\APR\0310-39B\004-0501.D

Sample Name: hplc48pg84 #4

Instrument 3 4/9/2010 11:19:18 AM KHB Page 1 of 1

EA# 0310-129 Page 138 of 221
=====================================================================

Acq. Operator : KHB Seq. Line : 5

Acq. Instrument : Groucho Location : Vial 4

Injection Date : 4/8/2010 10:26:16 PM Inj : 2

 Inj Volume : 15 μl

Acq. Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG84@.M

Last changed : 4/7/2010 2:42:28 PM by KHB

Analysis Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG86B.M

Last changed : 4/14/2010 4:48:16 PM by KHB

 (modified after loading)

5 10 15 20 25 30 min

mAU 

0

100

200

300

400

500

600

700

800

 VWD1 A, Wavelength=360 nm (H:\HPLC2010Q2\GROUCHO\DATA\APR\0310-39B\004-0502.D)

0.966

 1.421

 1.871

 3.069

 5.856 - Formaldehyde

 6.707

 7.726 - Acetaldehyde

 9.888 10.299

 11.106

 12.195

 13.000

 14.352

 15.985

 18.136

 18.868

 19.846

 20.351

 24.830

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 4/14/2010 4:48:17 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: VWD1 A, Wavelength=360 nm

RetTime Type Area Amt/Area Amount Grp Name

 [min] mAU *s [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 5.856 BB 2864.08203 2.07188e-3 5.93405 Formaldehyde 

 7.726 VB 2174.09570 2.71104e-3 5.89406 Acetaldehyde 

Totals : 11.82811

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GROUCHO\DATA\APR\0310-39B\004-0502.D

Sample Name: hplc48pg84 #4

Instrument 3 4/14/2010 4:48:23 PM KHB Page 1 of 1

EA# 0310-129 Page 139 of 221
=====================================================================

Acq. Operator : KHB Seq. Line : 6

Acq. Instrument : Groucho Location : Vial 5

Injection Date : 4/8/2010 11:02:51 PM Inj : 1

 Inj Volume : 15 μl

Acq. Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG84@.M

Last changed : 4/7/2010 2:42:28 PM by KHB

Analysis Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG86B.M

Last changed : 4/9/2010 11:19:06 AM by KHB

 (modified after loading)

5 10 15 20 25 30 min

mAU 

0

100

200

300

400

500

600

700

800

 VWD1 A, Wavelength=360 nm (H:\HPLC2010Q2\GROUCHO\DATA\APR\0310-39B\005-0601.D)

0.965

 1.414

 3.075

 5.862 - Formaldehyde

 7.730 - Acetaldehyde

 9.881 10.292

 11.096

 12.182

 12.983

 14.331

 15.622

 17.536

 18.265

 19.250

 19.756

 24.239

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 4/9/2010 11:19:07 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: VWD1 A, Wavelength=360 nm

RetTime Type Area Amt/Area Amount Grp Name

 [min] mAU *s [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 5.862 BB 4603.03223 2.07188e-3 9.53695 Formaldehyde 

 7.730 BB 3478.30127 2.71104e-3 9.42981 Acetaldehyde 

Totals : 18.96677

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GROUCHO\DATA\APR\0310-39B\005-0601.D

Sample Name: hplc48pg84 #5

Instrument 3 4/9/2010 11:19:51 AM KHB Page 1 of 1

EA# 0310-129 Page 140 of 221
=====================================================================

Acq. Operator : KHB Seq. Line : 6

Acq. Instrument : Groucho Location : Vial 5

Injection Date : 4/8/2010 11:39:27 PM Inj : 2

 Inj Volume : 15 μl

Acq. Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG84@.M

Last changed : 4/7/2010 2:42:28 PM by KHB

Analysis Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG86B.M

Last changed : 4/9/2010 11:19:06 AM by KHB

 (modified after loading)

5 10 15 20 25 30 min

mAU 

0

100

200

300

400

500

600

700

800

 VWD1 A, Wavelength=360 nm (H:\HPLC2010Q2\GROUCHO\DATA\APR\0310-39B\005-0602.D)

0.960

 1.410

 1.861

 3.067 4.009

 5.834 - Formaldehyde

 7.694 - Acetaldehyde

 9.853 10.260

 11.065

 12.150

 13.223

 14.821

 16.103

 18.009

 18.731

 19.700

 20.199

 24.128

 25.462

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 4/9/2010 11:19:07 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: VWD1 A, Wavelength=360 nm

RetTime Type Area Amt/Area Amount Grp Name

 [min] mAU *s [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 5.834 BB 4527.16895 2.07188e-3 9.37977 Formaldehyde 

 7.694 BB 3429.78809 2.71104e-3 9.29829 Acetaldehyde 

Totals : 18.67806

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GROUCHO\DATA\APR\0310-39B\005-0602.D

Sample Name: hplc48pg84 #5

Instrument 3 4/9/2010 11:19:59 AM KHB Page 1 of 1

EA# 0310-129 Page 141 of 221
=====================================================================

Acq. Operator : KHB Seq. Line : 7

Acq. Instrument : Groucho Location : Vial 6

Injection Date : 4/9/2010 12:16:01 AM Inj : 1

 Inj Volume : 15 μl

Acq. Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG84@.M

Last changed : 4/7/2010 2:42:28 PM by KHB

Analysis Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG86B.M

Last changed : 4/9/2010 11:19:06 AM by KHB

 (modified after loading)

5 10 15 20 25 30 min

mAU 

0

100

200

300

400

500

600

700

800

 VWD1 A, Wavelength=360 nm (H:\HPLC2010Q2\GROUCHO\DATA\APR\0310-39B\006-0701.D) 0 99 0.963 1.416 1.858 3.066 4.008 5.843 - Formaldehyde 7.706 - Acetaldehyde 9.857 10.266 11.067 12.151 12.947 14.576 16.101 18.023 18.745 19.717 20.219 22.033 24.642

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 4/9/2010 11:19:07 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: VWD1 A, Wavelength=360 nm

RetTime Type Area Amt/Area Amount Grp Name

 [min] mAU *s [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 5.843 VB 8018.26611 2.07188e-3 16.61292 Formaldehyde 

 7.706 BB 6072.08301 2.71104e-3 16.46166 Acetaldehyde 

Totals : 33.07458

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GROUCHO\DATA\APR\0310-39B\006-0701.D

Sample Name: hplc48pg84 #6

Instrument 3 4/9/2010 11:20:13 AM KHB Page 1 of 1

EA# 0310-129 Page 142 of 221
=====================================================================

Acq. Operator : KHB Seq. Line : 7

Acq. Instrument : Groucho Location : Vial 6

Injection Date : 4/9/2010 12:52:37 AM Inj : 2

 Inj Volume : 15 μl

Acq. Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG84@.M

Last changed : 4/7/2010 2:42:28 PM by KHB

Analysis Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG86B.M

Last changed : 4/9/2010 11:19:06 AM by KHB

 (modified after loading)

5 10 15 20 25 30 min

mAU 

0

100

200

300

400

500

600

700

800

 VWD1 A, Wavelength=360 nm (H:\HPLC2010Q2\GROUCHO\DATA\APR\0310-39B\006-0702.D) 0.802 0.965 1.415 1.859 3.068 4.002 5.835 - Formaldehyde 7.696 - Acetaldehyde 9.849 10.259 11.062 12.146 12.942 14.278 15.551 17.437 18.155 19.119 19.620 24.603

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 4/9/2010 11:19:07 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: VWD1 A, Wavelength=360 nm

RetTime Type Area Amt/Area Amount Grp Name

 [min] mAU *s [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 5.835 BB 8088.03223 2.07188e-3 16.75747 Formaldehyde 

 7.696 BB 6154.87891 2.71104e-3 16.68612 Acetaldehyde 

Totals : 33.44359

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GROUCHO\DATA\APR\0310-39B\006-0702.D

Sample Name: hplc48pg84 #6

Instrument 3 4/9/2010 11:20:07 AM KHB Page 1 of 1

EA# 0310-129 Page 143 of 221
=====================================================================

Acq. Operator : KHB Seq. Line : 8

Acq. Instrument : Groucho Location : Vial 7

Injection Date : 4/9/2010 1:29:16 AM Inj : 1

 Inj Volume : 15 μl

Acq. Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG84@.M

Last changed : 4/7/2010 2:42:28 PM by KHB

Analysis Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG86B.M

Last changed : 4/9/2010 11:19:06 AM by KHB

 (modified after loading)

5 10 15 20 25 30 min

mAU 

0

100

200

300

400

500

600

700

800

 VWD1 A, Wavelength=360 nm (H:\HPLC2010Q2\GROUCHO\DATA\APR\0310-39B\007-0801.D)

0.958

 1.410

 3.063

 5.831 - Formaldehyde

 7.689 - Acetaldehyde

 9.832 10.236

 11.035

 12.903

 14.240

 15.887

 17.902

 18.620

 19.569

 20.061

 24.821

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 4/9/2010 11:19:07 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: VWD1 A, Wavelength=360 nm

RetTime Type Area Amt/Area Amount Grp Name

 [min] mAU *s [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 5.831 BB 1204.60681 2.07188e-3 2.49581 Formaldehyde 

 7.689 BB 913.80304 2.71104e-3 2.47736 Acetaldehyde 

Totals : 4.97316

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GROUCHO\DATA\APR\0310-39B\007-0801.D

Sample Name: hplc48pg84 #SS

Instrument 3 4/9/2010 11:22:56 AM KHB Page 1 of 1

EA# 0310-129 Page 144 of 221
=====================================================================

Acq. Operator : KHB Seq. Line : 8

Acq. Instrument : Groucho Location : Vial 7

Injection Date : 4/9/2010 2:06:03 AM Inj : 2

 Inj Volume : 15 μl

Acq. Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG84@.M

Last changed : 4/7/2010 2:42:28 PM by KHB

Analysis Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG86B.M

Last changed : 4/9/2010 11:19:06 AM by KHB

 (modified after loading)

5 10 15 20 25 30 min

mAU 

0

100

200

300

400

500

600

700

800

 VWD1 A, Wavelength=360 nm (H:\HPLC2010Q2\GROUCHO\DATA\APR\0310-39B\007-0802.D)

0.963

 1.413

 3.068

 5.838 - Formaldehyde

 7.695 - Acetaldehyde

 9.843 10.249

 11.044

 12.904

 14.229

 15.486

 17.823

 18.551

 19.497

 19.985

 24.352

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 4/9/2010 11:19:07 AM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: VWD1 A, Wavelength=360 nm

RetTime Type Area Amt/Area Amount Grp Name

 [min] mAU *s [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 5.838 BV 1192.68018 2.07188e-3 2.47110 Formaldehyde 

 7.695 BB 906.35413 2.71104e-3 2.45716 Acetaldehyde 

Totals : 4.92826

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GROUCHO\DATA\APR\0310-39B\007-0802.D

Sample Name: hplc48pg84 #SS

Instrument 3 4/9/2010 11:23:05 AM KHB Page 1 of 1

EA# 0310-129 Page 145 of 221
=====================================================================

Acq. Operator : KHB Seq. Line : 2

Acq. Instrument : Groucho Location : Vial 1

Injection Date : 4/27/2010 4:09:25 PM Inj : 1

 Inj Volume : 15 μl

Acq. Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG84@.M

Last changed : 4/7/2010 2:42:28 PM by KHB

Analysis Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG86D.M

Last changed : 4/29/2010 5:43:30 PM by ARM

 (modified after loading)

5 10 15 20 25 30 min

mAU 

0

100

200

300

400

500

600

700

800

 VWD1 A, Wavelength=360 nm (H:\HPLC2010Q2\GROUCHO\DATA\APR\HPLC48PG102\001-0201.D)

1.023

 1.481

 6.808 - Formaldehyde

 8.758

 11.117

 12.019

 13.862

 15.151

 16.657

 19.284

 20.188

 21.294

 27.017

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 4/29/2010 5:43:30 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: VWD1 A, Wavelength=360 nm

RetTime Type Area Amt/Area Amount Grp Name

 [min] mAU *s [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 6.808 BB 1247.07935 2.07188e-3 2.58380 Formaldehyde 

Totals : 2.58380

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GROUCHO\DATA\APR\HPLC48PG102\001-0201.D

Sample Name: hplc48pg84 #3

Instrument 3 4/29/2010 5:44:07 PM ARM Page 1 of 1

EA# 0310-129 Page 146 of 221
=====================================================================

Acq. Operator : KHB Seq. Line : 13

Acq. Instrument : Groucho Location : Vial 1

Injection Date : 4/27/2010 10:52:29 PM Inj : 1

 Inj Volume : 15 μl

Acq. Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG84@.M

Last changed : 4/7/2010 2:42:28 PM by KHB

Analysis Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG86D.M

Last changed : 4/29/2010 5:46:03 PM by ARM

 (modified after loading)

5 10 15 20 25 30 min

mAU 

0

100

200

300

400

500

600

700

800

 VWD1 A, Wavelength=360 nm (H:\HPLC2010Q2\GROUCHO\DATA\APR\HPLC48PG102\001-1301.D)

1.067

 1.571 3.542

 6.557 - Formaldehyde

 8.519

 10.765

 11.631

 13.488

 14.551

 15.793 16.039

 18.155

 19.049

 19.961

 24.718

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 4/29/2010 5:46:07 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: VWD1 A, Wavelength=360 nm

RetTime Type Area Amt/Area Amount Grp Name

 [min] mAU *s [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 6.557 BB 1366.24646 2.07188e-3 2.83071 Formaldehyde 

Totals : 2.83071

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GROUCHO\DATA\APR\HPLC48PG102\001-1301.D

Sample Name: hplc48pg84 #3

Instrument 3 4/29/2010 5:47:23 PM ARM Page 1 of 1

EA# 0310-129 Page 147 of 221
=====================================================================

Acq. Operator : KHB Seq. Line : 17

Acq. Instrument : Groucho Location : Vial 1

Injection Date : 4/28/2010 1:19:12 AM Inj : 1

 Inj Volume : 15 μl

Acq. Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG84@.M

Last changed : 4/7/2010 2:42:28 PM by KHB

Analysis Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG86D.M

Last changed : 4/29/2010 5:47:31 PM by ARM

 (modified after loading)

5 10 15 20 25 30 min

mAU 

0

100

200

300

400

500

600

700

800

 VWD1 A, Wavelength=360 nm (H:\HPLC2010Q2\GROUCHO\DATA\APR\HPLC48PG102\001-1701.D)

1.144

 1.700

 3.741

 6.845 - Formaldehyde

 8.607

 10.831

 11.755

 13.396

 14.608

 16.126

 18.377

 19.168

 20.024

 25.181

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 4/29/2010 5:47:31 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: VWD1 A, Wavelength=360 nm

RetTime Type Area Amt/Area Amount Grp Name

 [min] mAU *s [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 6.845 BV 1467.89465 2.07188e-3 3.04131 Formaldehyde 

Totals : 3.04131

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GROUCHO\DATA\APR\HPLC48PG102\001-1701.D

Sample Name: hplc48pg84 #3

Instrument 3 4/29/2010 5:47:34 PM ARM Page 1 of 1

EA# 0310-129 Page 148 of 221
=====================================================================

Acq. Operator : KHB Seq. Line : 18

Acq. Instrument : Groucho Location : Vial 1

Injection Date : 4/28/2010 4:41:34 PM Inj : 1

 Inj Volume : 15 μl

Acq. Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG84@.M

Last changed : 4/7/2010 2:42:28 PM by KHB

Analysis Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG86D.M

Last changed : 4/29/2010 5:47:42 PM by ARM

 (modified after loading)

5 10 15 20 25 30 min

mAU 

0

100

200

300

400

500

600

700

800

 VWD1 A, Wavelength=360 nm (H:\HPLC2010Q2\GROUCHO\DATA\APR\HPLC48PG102\001-1801.D)

1.136

 1.676

 3.508

 6.395 - Formaldehyde

 8.202

 10.447

 11.314

 13.035

 14.302

 15.698

 18.242

 19.121

 20.046

 25.982

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 4/29/2010 5:47:43 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: VWD1 A, Wavelength=360 nm

RetTime Type Area Amt/Area Amount Grp Name

 [min] mAU *s [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 6.395 BB 1477.96533 2.07188e-3 3.06217 Formaldehyde 

Totals : 3.06217

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GROUCHO\DATA\APR\HPLC48PG102\001-1801.D

Sample Name: hplc48pg84 #3

Instrument 3 4/29/2010 5:47:47 PM ARM Page 1 of 1

EA# 0310-129 Page 149 of 221
=====================================================================

Acq. Operator : KHB Seq. Line : 20

Acq. Instrument : Groucho Location : Vial 1

Injection Date : 4/28/2010 6:05:15 PM Inj : 1

 Inj Volume : 15 μl

Acq. Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG84@.M

Last changed : 4/7/2010 2:42:28 PM by KHB

Analysis Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG86D.M

Last changed : 4/29/2010 5:47:59 PM by ARM

 (modified after loading)

5 10 15 20 25 30 min

mAU 

0

100

200

300

400

500

600

700

800

 VWD1 A, Wavelength=360 nm (H:\HPLC2010Q2\GROUCHO\DATA\APR\HPLC48PG102\001-2001.D)

1.195

 1.756

 7.657 - Formaldehyde

 9.471

 11.598

 12.349

 13.913

 15.159

 16.475

 19.020

 19.904

 20.863

 26.113

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 4/29/2010 5:47:59 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: VWD1 A, Wavelength=360 nm

RetTime Type Area Amt/Area Amount Grp Name

 [min] mAU *s [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 7.657 BV 1391.95471 2.07188e-3 2.88397 Formaldehyde 

Totals : 2.88397

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GROUCHO\DATA\APR\HPLC48PG102\001-2001.D

Sample Name: hplc48pg84 #3

Instrument 3 4/29/2010 5:48:02 PM ARM Page 1 of 1

EA# 0310-129 Page 150 of 221
=====================================================================

Acq. Operator : KHB Seq. Line : 28

Acq. Instrument : Groucho Location : Vial 1

Injection Date : 4/28/2010 10:58:27 PM Inj : 1

 Inj Volume : 15 μl

Acq. Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG84@.M

Last changed : 4/7/2010 2:42:28 PM by KHB

Analysis Method : H:\HPLC2010Q2\GROUCHO\METHODS\HPLC48PG86D.M

Last changed : 4/29/2010 5:48:14 PM by ARM

 (modified after loading)

5 10 15 20 25 30 min

mAU 

0

100

200

300

400

500

600

700

800

 VWD1 A, Wavelength=360 nm (H:\HPLC2010Q2\GROUCHO\DATA\APR\HPLC48PG102\001-2801.D)

1.035 1.198

 1.759

 4.133

 7.291 - Formaldehyde

 9.052

 11.132

 11.880

 13.366

 14.544

 15.723

 18.087

 18.921

 19.673

 24.430

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : 4/29/2010 5:48:15 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: VWD1 A, Wavelength=360 nm

RetTime Type Area Amt/Area Amount Grp Name

 [min] mAU *s [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 7.291 BV 1379.03076 2.07188e-3 2.85719 Formaldehyde 

Totals : 2.85719

=====================================================================

 *** End of Report ***

Data File H:\HPLC2010Q2\GROUCHO\DATA\APR\HPLC48PG102\001-2801.D

Sample Name: hplc48pg84 #3

Instrument 3 4/29/2010 5:48:21 PM ARM Page 1 of 1

EA# 0310-129 Page 151 of 221
EA# 0310-129 Page 152 of 221
EA# 0310-129 Page 153 of 221
EA# 0310-129 Page 154 of 221
EA# 0310-129 Page 155 of 221
Sequence Table:

 Method and Injection Info Part:

 Line Location SampleName Method Inj SampleType InjVolume

 DataFile AutoBalance LimsID

 ==== ======== ==================== ==================== ======== ========== =========

 1 Vial 8 RB/100% ACN HPLC48PG84@ 1 Sample 

 

 2 Vial 1 hplc48pg84 #1 HPLC48PG84@ 2 Sample 

 3 Vial 2 hplc48pg84 #2 HPLC48PG84@ 2 Sample 

 4 Vial 3 hplc48pg84 #3 HPLC48PG84@ 2 Sample 

 5 Vial 4 hplc48pg84 #4 HPLC48PG84@ 2 Sample 

 6 Vial 5 hplc48pg84 #5 HPLC48PG84@ 2 Sample 

 7 Vial 6 hplc48pg84 #6 HPLC48PG84@ 2 Sample 

 8 Vial 7 hplc48pg84 #SS HPLC48PG84@ 2 Sample 

 9 Vial 8 RB/100% ACN HPLC48PG84@ 2 Sample 

 10 Vial 31 MS/G235-110-2A 0310-125 HPLC48PG84@ 1 Sample 

 11 Vial 32 MSD/G235-110-2A 0310-125 HPLC48PG84@ 1 Sample 

 12 Vial 39 LCS 4/6/10 0310-39, 125 HPLC48PG84@ 1 Sample 

 13 Vial 40 MB 4/6/10 0310-39, 125 HPLC48PG84@ 1 Sample 

 14 Vial 3 hplc48pg84 #3 HPLC48PG84@ 1 Sample 

 15 Vial 33 MW-6 0310-39 HPLC48PG84@ 1 Sample 

 16 Vial 33 MW-6 0310-39 HPLC48PG84@ 1 Sample 

 17 Vial 34 MW-6 Dup 0310-39 HPLC48PG84@ 1 Sample 

 18 Vial 4 hplc48pg84 #4 HPLC48PG84@ 2 Sample 

 19 Vial 35 MW-7 0310-39 HPLC48PG84@ 1 Sample 

 20 Vial 36 MW-8 0310-39 HPLC48PG84@ 1 Sample 

 21 Vial 37 MW-14 0310-39 HPLC48PG84@ 1 Sample 

 22 Vial 38 MW-15 0310-39 HPLC48PG84@ 1 Sample 

 23 Vial 3 hplc48pg84 #3 HPLC48PG84@ 1 Sample 

Sequence: H:\HPLC2010Q1\GROUCHO\SEQUENCE\0310-39B.S

Instrument 3 4/9/2010 12:20:06 PM KHB Page 1 of 1

EA# 0310-129 Page 156 of 221
Sequence Table:

 Method and Injection Info Part:

 Line Location SampleName Method Inj SampleType InjVolume

 DataFile AutoBalance LimsID

 ==== ======== ==================== ==================== ======== ========== =========

 1 Vial 2 100% ACN HPLC48PG84@ 1 Sample 

 

 2 Vial 1 hplc48pg84 #3 HPLC48PG84@ 1 Sample 

 3 Vial 2 RB/100% ACN HPLC48PG84@ 1 Sample 

 4 Vial 11 Run 1 0310-129 HPLC48PG84@ 1 Sample 

 5 Vial 11 Run 1 0310-129 HPLC48PG84@ 1 Sample 

 6 Vial 12 Run 1 Dup 0310-129 HPLC48PG84@ 1 Sample 

 7 Vial 13 Run 2 0310-129 HPLC48PG84@ 1 Sample 

 8 Vial 14 Run 3 0310-129 HPLC48PG84@ 1 Sample 

 9 Vial 15 Matrix Spike 0310-129 HPLC48PG84@ 1 Sample 

 10 Vial 16 Imp Spike 0310-129 HPLC48PG84@ 1 Sample 

 11 Vial 17 Field Blank 0310-129 HPLC48PG84@ 1 Sample 

 12 Vial 18 Reagent Blank 0310-129 HPLC48PG84@ 1 Sample 

 13 Vial 1 hplc48pg84 #3 HPLC48PG84@ 1 Sample 

 14 Vial 19 Sample Blank 0310-129 HPLC48PG84@ 1 Sample 

 15 Vial 20 LCS 4/20/10 0310-129 HPLC48PG84@ 1 Sample 

 16 Vial 21 MB 4/20/10 0310-129 HPLC48PG84@ 1 Sample 

 17 Vial 1 hplc48pg84 #3 HPLC48PG84@ 1 Sample 

 18 Vial 1 hplc48pg84 #3 HPLC48PG84@ 1 Sample 

 19 Vial 19 Sample Blank 0310-129 HPLC48PG84@ 1 Sample 

 20 Vial 1 hplc48pg84 #3 HPLC48PG84@ 1 Sample 

 21 Vial 19 Sample Blank 0310-129 HPLC48PG84@ 1 Sample 

 22 Vial 20 LCS 4/20/10 0310-129 HPLC48PG84@ 1 Sample 

 23 Vial 21 MB 4/20/10 0310-129 HPLC48PG84@ 1 Sample 

 24 Vial 22 MS/Run 2 0310-129 HPLC48PG84@ 1 Sample 

 25 Vial 23 MSD/Run 2 0310-129 HPLC48PG84@ 1 Sample 

 26 Vial 24 LCS 4/28/10 0310-129 HPLC48PG84@ 1 Sample 

 27 Vial 25 MB 4/28/10 0310-129 HPLC48PG84@ 1 Sample 

Sequence: H:\HPLC2010Q2\GROUCHO\SEQUENCE\HPLC48PG102.S

Instrument 3 4/29/2010 5:40:45 PM ARM Page 1 of 2

EA# 0310-129 Page 157 of 221
 Line Location SampleName Method Inj SampleType InjVolume

 DataFile AutoBalance LimsID

 ==== ======== ==================== ==================== ======== ========== =========

 28 Vial 1 hplc48pg84 #3 HPLC48PG84@ 1 Sample 

 

Sequence: H:\HPLC2010Q2\GROUCHO\SEQUENCE\HPLC48PG102.S

Instrument 3 4/29/2010 5:40:45 PM ARM Page 2 of 2

EA# 0310-129 Page 158 of 221
Sample 

Chromatograms

EA# 0310-129 Page 159 of 221
=====================================================================

Acq. Operator : EO/KHB Seq. Line : 9

Acq. Instrument : Smithers Location : -

Injection Date : 4/26/2010 3:08:20 PM Inj : 1

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG84.M

Last changed : 4/27/2010 3:26:01 PM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\008-0901.D) 5.877

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 2.797 - - - Fluoride 

 3.735 - - - Chloride 

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

=====================================================================

 Area Percent Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Data File U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\008-0901.D

Sample Name: R1 A *20 0310-129

Instrument 1 4/27/2010 3:29:51 PM ARM Page 1 of 2

EA# 0310-129 Page 160 of 221
=====================================================================

Acq. Operator : EO/KHB Seq. Line : 9

Acq. Instrument : Smithers Location : -

Injection Date : 4/26/2010 3:19:08 PM Inj : 2

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG84.M

Last changed : 4/27/2010 3:26:01 PM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\008-0902.D) 5.873

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 2.797 - - - Fluoride 

 3.735 - - - Chloride 

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

=====================================================================

 Area Percent Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Data File U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\008-0902.D

Sample Name: R1 A *20 0310-129

Instrument 1 4/27/2010 3:29:59 PM ARM Page 1 of 2

EA# 0310-129 Page 161 of 221
=====================================================================

Acq. Operator : EO/KHB Seq. Line : 12

Acq. Instrument : Smithers Location : -

Injection Date : 4/26/2010 4:13:08 PM Inj : 1

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG84.M

Last changed : 4/27/2010 3:26:01 PM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\011-1201.D) 5.864

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 2.797 - - - Fluoride 

 3.735 - - - Chloride 

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

=====================================================================

 Area Percent Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Data File U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\011-1201.D

Sample Name: R2 A *20 0310-129

Instrument 1 4/27/2010 3:30:46 PM ARM Page 1 of 2

EA# 0310-129 Page 162 of 221
=====================================================================

Acq. Operator : EO/KHB Seq. Line : 12

Acq. Instrument : Smithers Location : -

Injection Date : 4/26/2010 4:23:56 PM Inj : 2

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG84.M

Last changed : 4/27/2010 3:26:01 PM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\011-1202.D) 5.866

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 2.797 - - - Fluoride 

 3.735 - - - Chloride 

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

=====================================================================

 Area Percent Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Data File U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\011-1202.D

Sample Name: R2 A *20 0310-129

Instrument 1 4/27/2010 3:30:54 PM ARM Page 1 of 2

EA# 0310-129 Page 163 of 221
=====================================================================

Acq. Operator : EO/KHB Seq. Line : 13

Acq. Instrument : Smithers Location : -

Injection Date : 4/26/2010 4:34:44 PM Inj : 1

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG84.M

Last changed : 4/27/2010 3:26:01 PM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\012-1301.D) 5.868

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 2.797 - - - Fluoride 

 3.735 - - - Chloride 

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

=====================================================================

 Area Percent Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Data File U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\012-1301.D

Sample Name: R3 A *20 0310-129

Instrument 1 4/27/2010 3:31:02 PM ARM Page 1 of 2

EA# 0310-129 Page 164 of 221
=====================================================================

Acq. Operator : EO/KHB Seq. Line : 13

Acq. Instrument : Smithers Location : -

Injection Date : 4/26/2010 4:45:32 PM Inj : 2

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG84.M

Last changed : 4/27/2010 3:26:01 PM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\012-1302.D) 5.881

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 2.797 - - - Fluoride 

 3.735 - - - Chloride 

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

=====================================================================

 Area Percent Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Data File U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\012-1302.D

Sample Name: R3 A *20 0310-129

Instrument 1 4/27/2010 3:31:09 PM ARM Page 1 of 2

EA# 0310-129 Page 165 of 221
=====================================================================

Acq. Operator : EO/KHB Seq. Line : 14

Acq. Instrument : Smithers Location : -

Injection Date : 4/26/2010 4:56:20 PM Inj : 1

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG84.M

Last changed : 4/27/2010 3:26:01 PM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\013-1401.D)

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 2.797 - - - Fluoride 

 3.735 - - - Chloride 

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

=====================================================================

 Area Percent Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Data File U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\013-1401.D

Sample Name: Acid Blank *20 0310-129

Instrument 1 4/27/2010 3:31:16 PM ARM Page 1 of 2

EA# 0310-129 Page 166 of 221
=====================================================================

Acq. Operator : EO/KHB Seq. Line : 14

Acq. Instrument : Smithers Location : -

Injection Date : 4/26/2010 5:07:07 PM Inj : 2

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG84.M

Last changed : 4/27/2010 3:26:01 PM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\013-1402.D)

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 2.797 - - - Fluoride 

 3.735 - - - Chloride 

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

=====================================================================

 Area Percent Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Data File U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\013-1402.D

Sample Name: Acid Blank *20 0310-129

Instrument 1 4/27/2010 3:31:24 PM ARM Page 1 of 2

EA# 0310-129 Page 167 of 221
=====================================================================

Acq. Operator : EO/KHB Seq. Line : 16

Acq. Instrument : Smithers Location : -

Injection Date : 4/26/2010 5:39:31 PM Inj : 1

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG84.M

Last changed : 4/27/2010 3:26:01 PM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\015-1601.D) 2.125 4.309 4.928 5.864

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 2.797 - - - Fluoride 

 3.735 - - - Chloride 

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

=====================================================================

 Area Percent Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Data File U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\015-1601.D

Sample Name: R1 B *20 0310-129

Instrument 1 4/27/2010 3:31:47 PM ARM Page 1 of 2

EA# 0310-129 Page 168 of 221
=====================================================================

Acq. Operator : EO/KHB Seq. Line : 16

Acq. Instrument : Smithers Location : -

Injection Date : 4/26/2010 5:56:18 PM Inj : 2

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG84.M

Last changed : 4/27/2010 3:26:01 PM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\015-1602.D) 2.128 4.313 4.930 5.873

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 2.797 - - - Fluoride 

 3.735 - - - Chloride 

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

=====================================================================

 Area Percent Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Data File U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\015-1602.D

Sample Name: R1 B *20 0310-129

Instrument 1 4/27/2010 3:31:54 PM ARM Page 1 of 2

EA# 0310-129 Page 169 of 221
=====================================================================

Acq. Operator : EO/KHB Seq. Line : 21

Acq. Instrument : Smithers Location : -

Injection Date : 4/26/2010 8:03:28 PM Inj : 1

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG84.M

Last changed : 4/27/2010 3:26:01 PM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\018-2101.D) 2.125 4.271 4.869 5.752

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 2.797 - - - Fluoride 

 3.735 - - - Chloride 

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

=====================================================================

 Area Percent Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Data File U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\018-2101.D

Sample Name: R2 B *20 0310-129

Instrument 1 4/27/2010 3:32:34 PM ARM Page 1 of 2

EA# 0310-129 Page 170 of 221
=====================================================================

Acq. Operator : EO/KHB Seq. Line : 21

Acq. Instrument : Smithers Location : -

Injection Date : 4/26/2010 8:20:15 PM Inj : 2

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG84.M

Last changed : 4/27/2010 3:26:01 PM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\018-2102.D) 2.126 4.264 4.864 5.735

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 2.797 - - - Fluoride 

 3.735 - - - Chloride 

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

=====================================================================

 Area Percent Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Data File U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\018-2102.D

Sample Name: R2 B *20 0310-129

Instrument 1 4/27/2010 3:32:41 PM ARM Page 1 of 2

EA# 0310-129 Page 171 of 221
=====================================================================

Acq. Operator : EO/KHB Seq. Line : 22

Acq. Instrument : Smithers Location : -

Injection Date : 4/26/2010 8:37:04 PM Inj : 1

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG84.M

Last changed : 4/27/2010 3:26:01 PM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\019-2201.D) 2.126 4.260 4.852 5.720

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 2.797 - - - Fluoride 

 3.735 - - - Chloride 

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

=====================================================================

 Area Percent Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Data File U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\019-2201.D

Sample Name: R3 B *20 0310-129

Instrument 1 4/27/2010 3:32:48 PM ARM Page 1 of 2

EA# 0310-129 Page 172 of 221
=====================================================================

Acq. Operator : EO/KHB Seq. Line : 22

Acq. Instrument : Smithers Location : -

Injection Date : 4/26/2010 8:53:51 PM Inj : 2

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG84.M

Last changed : 4/27/2010 3:26:01 PM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\019-2202.D) 2.128 4.256 4.842 5.705

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 2.797 - - - Fluoride 

 3.735 - - - Chloride 

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

=====================================================================

 Area Percent Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Data File U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\019-2202.D

Sample Name: R3 B *20 0310-129

Instrument 1 4/27/2010 3:32:56 PM ARM Page 1 of 2

EA# 0310-129 Page 173 of 221
=====================================================================

Acq. Operator : EO/KHB Seq. Line : 23

Acq. Instrument : Smithers Location : -

Injection Date : 4/26/2010 9:10:40 PM Inj : 1

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG84.M

Last changed : 4/27/2010 3:26:01 PM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\020-2301.D) 2.136 4.898

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 2.797 - - - Fluoride 

 3.735 - - - Chloride 

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

=====================================================================

 Area Percent Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Data File U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\020-2301.D

Sample Name: Base Blank *20 0310-129

Instrument 1 4/27/2010 3:33:03 PM ARM Page 1 of 2

EA# 0310-129 Page 174 of 221
=====================================================================

Acq. Operator : EO/KHB Seq. Line : 23

Acq. Instrument : Smithers Location : -

Injection Date : 4/26/2010 9:27:26 PM Inj : 2

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG84.M

Last changed : 4/27/2010 3:26:01 PM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\020-2302.D) 2.138 4.890

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 2.797 - - - Fluoride 

 3.735 - - - Chloride 

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

=====================================================================

 Area Percent Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Data File U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\020-2302.D

Sample Name: Base Blank *20 0310-129

Instrument 1 4/27/2010 3:33:10 PM ARM Page 1 of 2

EA# 0310-129 Page 175 of 221
=====================================================================

Acq. Operator : EO/KHB Seq. Line : 15

Acq. Instrument : Smithers Location : -

Injection Date : 4/26/2010 5:17:55 PM Inj : 1

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG84.M

Last changed : 4/27/2010 3:26:01 PM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\014-1501.D)

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 2.797 - - - Fluoride 

 3.735 - - - Chloride 

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

=====================================================================

 Area Percent Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Data File U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\014-1501.D

Sample Name: DI H2O Blank 0310-129

Instrument 1 4/27/2010 3:31:31 PM ARM Page 1 of 2

EA# 0310-129 Page 176 of 221
=====================================================================

Acq. Operator : EO/KHB Seq. Line : 15

Acq. Instrument : Smithers Location : -

Injection Date : 4/26/2010 5:28:42 PM Inj : 2

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG84.M

Last changed : 4/27/2010 3:26:01 PM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\014-1502.D)

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 2.797 - - - Fluoride 

 3.735 - - - Chloride 

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

=====================================================================

 Area Percent Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Data File U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\014-1502.D

Sample Name: DI H2O Blank 0310-129

Instrument 1 4/27/2010 3:31:40 PM ARM Page 1 of 2

EA# 0310-129 Page 177 of 221
=====================================================================

Acq. Operator : EO/KHB Seq. Line : 8

Acq. Instrument : Smithers Location : -

Injection Date : 4/26/2010 2:46:45 PM Inj : 1

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG84.M

Last changed : 4/27/2010 3:26:01 PM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\007-0801.D) 4.877

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 2.797 - - - Fluoride 

 3.735 - - - Chloride 

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

=====================================================================

 Area Percent Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Data File U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\007-0801.D

Sample Name: 0.1N H2SO4/NaOH MB

Instrument 1 4/27/2010 3:29:28 PM ARM Page 1 of 2

EA# 0310-129 Page 178 of 221
=====================================================================

Acq. Operator : EO/KHB Seq. Line : 8

Acq. Instrument : Smithers Location : -

Injection Date : 4/26/2010 2:57:32 PM Inj : 2

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG84.M

Last changed : 4/27/2010 3:26:01 PM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\007-0802.D)

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 2.797 - - - Fluoride 

 3.735 - - - Chloride 

Totals : 0.00000

1 Warnings or Errors :

Warning : Calibrated compound(s) not found

=====================================================================

=====================================================================

 Area Percent Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Data File U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\007-0802.D

Sample Name: 0.1N H2SO4/NaOH MB

Instrument 1 4/27/2010 3:29:43 PM ARM Page 1 of 2

EA# 0310-129 Page 179 of 221
=====================================================================

Acq. Operator : EO/KHB Seq. Line : 10

Acq. Instrument : Smithers Location : -

Injection Date : 4/26/2010 3:29:56 PM Inj : 1

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG84.M

Last changed : 4/27/2010 3:26:01 PM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\009-1001.D) 2.782 - Fluoride 3.737 - Chloride 5.094 5.209 5.844

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 2.782 BB 211.64490 1.67562e-2 3.54637 Fluoride 

 3.737 BB 112.34624 2.53577e-2 2.84884 Chloride 

Totals : 6.39521

=====================================================================

 *** End of Report ***

Data File U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\009-1001.D

Sample Name: MS R1 A *20 0310-129

Instrument 1 4/27/2010 3:30:07 PM ARM Page 1 of 1

EA# 0310-129 Page 180 of 221
=====================================================================

Acq. Operator : EO/KHB Seq. Line : 10

Acq. Instrument : Smithers Location : -

Injection Date : 4/26/2010 3:40:44 PM Inj : 2

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG84.M

Last changed : 4/27/2010 3:26:01 PM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\009-1002.D) 2.783 - Fluoride 3.738 - Chloride 5.095 5.211 5.844

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 2.783 BB 211.34271 1.67563e-2 3.54132 Fluoride 

 3.738 BB 112.25883 2.53579e-2 2.84665 Chloride 

Totals : 6.38797

=====================================================================

 *** End of Report ***

Data File U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\009-1002.D

Sample Name: MS R1 A *20 0310-129

Instrument 1 4/27/2010 3:30:14 PM ARM Page 1 of 1

EA# 0310-129 Page 181 of 221
=====================================================================

Acq. Operator : EO/KHB Seq. Line : 11

Acq. Instrument : Smithers Location : -

Injection Date : 4/26/2010 3:51:32 PM Inj : 1

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG84.M

Last changed : 4/27/2010 3:26:01 PM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\010-1101.D) 2.783 - Fluoride 3.737 - Chloride 5.094 5.208 5.842

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 2.783 BB 210.90742 1.67564e-2 3.53405 Fluoride 

 3.737 BB 112.30272 2.53578e-2 2.84775 Chloride 

Totals : 6.38180

=====================================================================

 *** End of Report ***

Data File U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\010-1101.D

Sample Name: MSD R1 A *20 0310-129

Instrument 1 4/27/2010 3:30:22 PM ARM Page 1 of 1

EA# 0310-129 Page 182 of 221
=====================================================================

Acq. Operator : EO/KHB Seq. Line : 11

Acq. Instrument : Smithers Location : -

Injection Date : 4/26/2010 4:02:20 PM Inj : 2

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG84.M

Last changed : 4/27/2010 3:26:01 PM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\010-1102.D) 2.783 - Fluoride 3.737 - Chloride 5.091 5.209 5.839 6.010

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 2.783 BB 211.21500 1.67563e-2 3.53919 Fluoride 

 3.737 BB 112.60306 2.53571e-2 2.85528 Chloride 

Totals : 6.39447

=====================================================================

 *** End of Report ***

Data File U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\010-1102.D

Sample Name: MSD R1 A *20 0310-129

Instrument 1 4/27/2010 3:30:38 PM ARM Page 1 of 1

EA# 0310-129 Page 183 of 221
=====================================================================

Acq. Operator : EO/KHB Seq. Line : 19

Acq. Instrument : Smithers Location : -

Injection Date : 4/26/2010 6:56:17 PM Inj : 1

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG84.M

Last changed : 4/27/2010 3:26:01 PM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\016-1901.D) 2.125 2.773 - Fluoride 3.740 - Chloride 4.312 4.994 5.245 5.867

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 2.773 BB 189.25595 1.67620e-2 3.17230 Fluoride 

 3.740 BB 110.83923 2.53615e-2 2.81105 Chloride 

Totals : 5.98335

=====================================================================

 *** End of Report ***

Data File U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\016-1901.D

Sample Name: MS R1 B *20 0310-129

Instrument 1 4/27/2010 3:32:02 PM ARM Page 1 of 1

EA# 0310-129 Page 184 of 221
=====================================================================

Acq. Operator : EO/KHB Seq. Line : 19

Acq. Instrument : Smithers Location : -

Injection Date : 4/26/2010 7:13:05 PM Inj : 2

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG84.M

Last changed : 4/27/2010 3:26:01 PM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\016-1902.D) 2.124 2.774 - Fluoride 3.735 - Chloride 4.303 4.976 5.226 5.820 6.015

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 2.774 BB 189.06126 1.67620e-2 3.16905 Fluoride 

 3.735 BB 110.58054 2.53622e-2 2.80456 Chloride 

Totals : 5.97361

=====================================================================

 *** End of Report ***

Data File U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\016-1902.D

Sample Name: MS R1 B *20 0310-129

Instrument 1 4/27/2010 3:32:10 PM ARM Page 1 of 1

EA# 0310-129 Page 185 of 221
=====================================================================

Acq. Operator : EO/KHB Seq. Line : 20

Acq. Instrument : Smithers Location : -

Injection Date : 4/26/2010 7:29:53 PM Inj : 1

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG84.M

Last changed : 4/27/2010 3:26:01 PM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\017-2001.D) 2.127 2.774 - Fluoride 3.728 - Chloride 4.290 4.952 5.199 5.778 6.038

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 2.774 BB 193.77460 1.67607e-2 3.24780 Fluoride 

 3.728 BB 113.71087 2.53544e-2 2.88307 Chloride 

Totals : 6.13087

=====================================================================

 *** End of Report ***

Data File U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\017-2001.D

Sample Name: MSD R1 B *20 0310-129

Instrument 1 4/27/2010 3:32:17 PM ARM Page 1 of 1

EA# 0310-129 Page 186 of 221
=====================================================================

Acq. Operator : EO/KHB Seq. Line : 20

Acq. Instrument : Smithers Location : -

Injection Date : 4/26/2010 7:46:40 PM Inj : 2

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG84.M

Last changed : 4/27/2010 3:26:01 PM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\017-2002.D) 2.125 2.773 - Fluoride 3.721 - Chloride 4.278 4.932 5.177 5.748 6.049

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 2.773 BB 194.02550 1.67606e-2 3.25199 Fluoride 

 3.721 BB 113.83198 2.53541e-2 2.88610 Chloride 

Totals : 6.13809

=====================================================================

 *** End of Report ***

Data File U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\017-2002.D

Sample Name: MSD R1 B *20 0310-129

Instrument 1 4/27/2010 3:32:26 PM ARM Page 1 of 1

EA# 0310-129 Page 187 of 221
Calibration 

Curve Chromatograms

EA# 0310-129 Page 188 of 221
=====================================================================

 Calibration Table 

=====================================================================

Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM

Calculate : External Standard

Based on : Peak Area

Rel. Reference Window : 10.000 %

Abs. Reference Window : 0.000 min

Rel. Non-ref. Window : 10.000 %

Abs. Non-ref. Window : 0.000 min

Use Multiplier & Dilution Factor with ISTDs

Uncalibrated Peaks : not reported

Partial Calibration : Yes, identified peaks are recalibrated

Correct All Ret. Times: No, only for identified peaks

Curve Type : Linear

Origin : Connected

Weight : Linear (Amnt)

Recalibration Settings: 

Average Response : Average all calibrations

Average Retention Time: Floating Average New 75%

Calibration Report Options :

 Printout of recalibrations within a sequence:

 Calibration Table after Recalibration

 Normal Report after Recalibration

 If the sequence is done with bracketing:

 Results of first cycle (ending previous bracket)

Signal 1: ADC1 B, ADC1 B, Metrohm

Signal 2: ADC1 A, ADC1 CHANNEL A

RetTime Lvl Amount Area Amt/Area Ref Grp Name 

 [min] Sig [ug/mL] 

-------|--|--|----------|----------|----------|---|--|---------------

 2.797 2 1 1.00000e-1 4.93494 2.02637e-2 Fluoride 

 2 9.99000e-1 61.49712 1.62447e-2 

 3 4.97500 309.78529 1.60595e-2 

 4 8.92000 544.06776 1.63950e-2 

 5 14.80000 859.88914 1.72115e-2 

 3.735 2 1 1.00000e-1 3.11882 3.20634e-2 Chloride 

 2 9.99000e-1 35.07049 2.84855e-2 

 3 4.97500 192.95622 2.57831e-2 

 4 8.92000 355.89272 2.50637e-2 

 5 14.80000 594.72375 2.48855e-2 

=====================================================================

 Peak Sum Table 

=====================================================================

***No Entries in table***

=====================================================================

Method U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG84.M

Instrument 1 4/27/2010 3:26:29 PM ARM Page 1 of 2

EA# 0310-129 Page 189 of 221
=====================================================================

 Calibration Curves

=====================================================================

Amount[ug/mL]

0 10

Area

0

100

200

300

400

500

600

700

800

1

2

3

4

5

Fluoride at exp. RT: 2.797

ADC1 A, ADC1 CHANNEL A

Correlation: 0.99952

Residual Std. Dev.: 17.53606

Formula: y = mx + b

 m: 59.85251

 b: -6.14262e-1 

 x: Amount

 y: Area

Calibration Level Weights:

 Level 1 : 1

 Level 2 : 0.1001

 Level 3 : 0.020101

 Level 4 : 0.011211

 Level 5 : 0.006757

Amount[ug/mL]

0 10

Area

0

100

200

300

400

500

1

2

3

4

5

Chloride at exp. RT: 3.735

ADC1 A, ADC1 CHANNEL A

Correlation: 0.99977

Residual Std. Dev.: 4.69415

Formula: y = mx + b

 m: 39.87393

 b: -1.24835

 x: Amount

 y: Area

Calibration Level Weights:

 Level 1 : 1

 Level 2 : 0.1001

 Level 3 : 0.020101

 Level 4 : 0.011211

 Level 5 : 0.006757

=====================================================================

Method U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG84.M

Instrument 1 4/27/2010 3:26:29 PM ARM Page 2 of 2

EA# 0310-129 Page 190 of 221
=====================================================================

Acq. Operator : EO/KHB Seq. Line : 2

Acq. Instrument : Smithers Location : -

Injection Date : 4/26/2010 12:37:11 PM Inj : 1

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG84.M

Last changed : 4/27/2010 3:26:01 PM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\001-0201.D) 2.776 - Fluoride 3.740 - Chloride

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 2.776 BB 4.55818 1.86185e-2 8.48667e-2 Fluoride 

 3.740 BB 3.04486 3.53611e-2 1.07670e-1 Chloride 

Totals : 1.92536e-1

=====================================================================

 *** End of Report ***

Data File U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\001-0201.D

Sample Name: HPLC51pg84 #1

Instrument 1 4/27/2010 3:26:14 PM ARM Page 1 of 1

EA# 0310-129 Page 191 of 221
=====================================================================

Acq. Operator : EO/KHB Seq. Line : 2

Acq. Instrument : Smithers Location : -

Injection Date : 4/26/2010 12:47:59 PM Inj : 2

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG84.M

Last changed : 4/27/2010 3:26:01 PM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\001-0202.D) 2.775 - Fluoride 3.738 - Chloride

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 2.775 BB 4.85643 1.86185e-2 9.04196e-2 Fluoride 

 3.738 BB 3.10949 3.51474e-2 1.09290e-1 Chloride 

Totals : 1.99710e-1

=====================================================================

 *** End of Report ***

Data File U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\001-0202.D

Sample Name: HPLC51pg84 #1

Instrument 1 4/27/2010 3:26:43 PM ARM Page 1 of 1

EA# 0310-129 Page 192 of 221
=====================================================================

Acq. Operator : EO/KHB Seq. Line : 62

Acq. Instrument : Smithers Location : -

Injection Date : 4/27/2010 11:24:48 AM Inj : 1

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG84.M

Last changed : 4/27/2010 3:26:01 PM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\001-6201.D) 2.774 - Fluoride 3.740 - Chloride

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 2.774 BB 5.16734 1.86185e-2 9.62084e-2 Fluoride 

 3.740 BB 3.17709 3.49332e-2 1.10986e-1 Chloride 

Totals : 2.07194e-1

=====================================================================

 *** End of Report ***

Data File U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\001-6201.D

Sample Name: HPLC51pg84 #1

Instrument 1 4/27/2010 3:26:51 PM ARM Page 1 of 1

EA# 0310-129 Page 193 of 221
=====================================================================

Acq. Operator : EO/KHB Seq. Line : 62

Acq. Instrument : Smithers Location : -

Injection Date : 4/27/2010 11:35:35 AM Inj : 2

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG84.M

Last changed : 4/27/2010 3:26:01 PM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\001-6202.D) 2.772 - Fluoride 3.738 - Chloride

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 2.772 BB 5.15779 1.86185e-2 9.60305e-2 Fluoride 

 3.738 BB 3.14384 3.50374e-2 1.10152e-1 Chloride 

Totals : 2.06182e-1

=====================================================================

 *** End of Report ***

Data File U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\001-6202.D

Sample Name: HPLC51pg84 #1

Instrument 1 4/27/2010 3:26:59 PM ARM Page 1 of 1

EA# 0310-129 Page 194 of 221
=====================================================================

Acq. Operator : EO/KHB Seq. Line : 3

Acq. Instrument : Smithers Location : -

Injection Date : 4/26/2010 12:58:47 PM Inj : 1

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG84.M

Last changed : 4/27/2010 3:26:01 PM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\002-0301.D) 2.777 - Fluoride 3.738 - Chloride 5.050 5.833

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 2.777 BB 59.29694 1.68808e-2 1.00098 Fluoride 

 3.738 BB 34.74036 2.59802e-2 9.02562e-1 Chloride 

Totals : 1.90354

=====================================================================

 *** End of Report ***

Data File U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\002-0301.D

Sample Name: HPLC51pg84 #2

Instrument 1 4/27/2010 3:27:07 PM ARM Page 1 of 1

EA# 0310-129 Page 195 of 221
=====================================================================

Acq. Operator : EO/KHB Seq. Line : 3

Acq. Instrument : Smithers Location : -

Injection Date : 4/26/2010 1:09:34 PM Inj : 2

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG84.M

Last changed : 4/27/2010 3:26:01 PM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\002-0302.D) 2.778 - Fluoride 3.740 - Chloride 5.051 5.835

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 2.778 BB 60.25044 1.68781e-2 1.01691 Fluoride 

 3.740 BB 34.82093 2.59781e-2 9.04583e-1 Chloride 

Totals : 1.92149

=====================================================================

 *** End of Report ***

Data File U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\002-0302.D

Sample Name: HPLC51pg84 #2

Instrument 1 4/27/2010 3:27:14 PM ARM Page 1 of 1

EA# 0310-129 Page 196 of 221
=====================================================================

Acq. Operator : EO/KHB Seq. Line : 63

Acq. Instrument : Smithers Location : -

Injection Date : 4/27/2010 11:46:23 AM Inj : 1

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG84.M

Last changed : 4/27/2010 3:26:01 PM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\002-6301.D) 2.775 - Fluoride 3.738 - Chloride 5.063 5.830 6.044

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 2.775 BB 63.30387 1.68699e-2 1.06793 Fluoride 

 3.738 BB 35.35503 2.59646e-2 9.17978e-1 Chloride 

Totals : 1.98591

=====================================================================

 *** End of Report ***

Data File U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\002-6301.D

Sample Name: HPLC51pg84 #2

Instrument 1 4/27/2010 3:27:22 PM ARM Page 1 of 1

EA# 0310-129 Page 197 of 221
=====================================================================

Acq. Operator : EO/KHB Seq. Line : 63

Acq. Instrument : Smithers Location : -

Injection Date : 4/27/2010 11:57:11 AM Inj : 2

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG84.M

Last changed : 4/27/2010 3:26:01 PM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\002-6302.D) 2.775 - Fluoride 3.739 - Chloride 5.065 5.835 6.040

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 2.775 BB 63.13723 1.68703e-2 1.06514 Fluoride 

 3.739 BB 35.36566 2.59643e-2 9.18244e-1 Chloride 

Totals : 1.98339

=====================================================================

 *** End of Report ***

Data File U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\002-6302.D

Sample Name: HPLC51pg84 #2

Instrument 1 4/27/2010 3:27:31 PM ARM Page 1 of 1

EA# 0310-129 Page 198 of 221
=====================================================================

Acq. Operator : EO/KHB Seq. Line : 4

Acq. Instrument : Smithers Location : -

Injection Date : 4/26/2010 1:20:22 PM Inj : 1

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG84.M

Last changed : 4/27/2010 3:26:01 PM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\003-0401.D) 2.782 - Fluoride 3.734 - Chloride 5.023 5.799 6.001

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 2.782 BB 297.33667 1.67423e-2 4.97809 Fluoride 

 3.734 BB 191.81564 2.52423e-2 4.84186 Chloride 

Totals : 9.81995

=====================================================================

 *** End of Report ***

Data File U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\003-0401.D

Sample Name: HPLC51pg84 #3

Instrument 1 4/27/2010 3:27:38 PM ARM Page 1 of 1

EA# 0310-129 Page 199 of 221
=====================================================================

Acq. Operator : EO/KHB Seq. Line : 4

Acq. Instrument : Smithers Location : -

Injection Date : 4/26/2010 1:31:10 PM Inj : 2

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG84.M

Last changed : 4/27/2010 3:26:01 PM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\003-0402.D) 2.784 - Fluoride 3.737 - Chloride 5.026 5.802 6.006

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 2.784 BB 302.67523 1.67416e-2 5.06728 Fluoride 

 3.737 BB 192.07166 2.52420e-2 4.84828 Chloride 

Totals : 9.91556

=====================================================================

 *** End of Report ***

Data File U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\003-0402.D

Sample Name: HPLC51pg84 #3

Instrument 1 4/27/2010 3:27:45 PM ARM Page 1 of 1

EA# 0310-129 Page 200 of 221
=====================================================================

Acq. Operator : EO/KHB Seq. Line : 64

Acq. Instrument : Smithers Location : -

Injection Date : 4/27/2010 12:07:58 PM Inj : 1

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG84.M

Last changed : 4/27/2010 3:26:01 PM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\003-6401.D) 2.781 - Fluoride 3.735 - Chloride 5.039 5.803 6.047

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 2.781 BB 319.44144 1.67399e-2 5.34741 Fluoride 

 3.735 BB 193.91412 2.52405e-2 4.89449 Chloride 

Totals : 10.24190

=====================================================================

 *** End of Report ***

Data File U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\003-6401.D

Sample Name: HPLC51pg84 #3

Instrument 1 4/27/2010 3:27:53 PM ARM Page 1 of 1

EA# 0310-129 Page 201 of 221
=====================================================================

Acq. Operator : EO/KHB Seq. Line : 64

Acq. Instrument : Smithers Location : -

Injection Date : 4/27/2010 12:18:46 PM Inj : 2

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG84.M

Last changed : 4/27/2010 3:26:01 PM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\003-6402.D) 2.781 - Fluoride 3.736 - Chloride 5.040 5.803 6.049

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 2.781 BB 319.68784 1.67398e-2 5.35152 Fluoride 

 3.736 BB 194.02347 2.52404e-2 4.89723 Chloride 

Totals : 10.24875

=====================================================================

 *** End of Report ***

Data File U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\003-6402.D

Sample Name: HPLC51pg84 #3

Instrument 1 4/27/2010 3:28:02 PM ARM Page 1 of 1

EA# 0310-129 Page 202 of 221
=====================================================================

Acq. Operator : EO/KHB Seq. Line : 5

Acq. Instrument : Smithers Location : -

Injection Date : 4/26/2010 1:41:58 PM Inj : 1

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG84.M

Last changed : 4/27/2010 3:26:01 PM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\004-0501.D) 2.791 - Fluoride 3.738 - Chloride 5.019 5.791 6.014

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 2.791 BB 526.93762 1.67272e-2 8.81420 Fluoride 

 3.738 BB 354.15213 2.51674e-2 8.91310 Chloride 

Totals : 17.72730

=====================================================================

 *** End of Report ***

Data File U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\004-0501.D

Sample Name: HPLC51pg84 #4

Instrument 1 4/27/2010 3:28:10 PM ARM Page 1 of 1

EA# 0310-129 Page 203 of 221
=====================================================================

Acq. Operator : EO/KHB Seq. Line : 5

Acq. Instrument : Smithers Location : -

Injection Date : 4/26/2010 1:52:46 PM Inj : 2

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG84.M

Last changed : 4/27/2010 3:26:01 PM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\004-0502.D) 2.790 - Fluoride 3.735 - Chloride 5.016 5.787 6.010

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 2.790 BB 532.82129 1.67270e-2 8.91250 Fluoride 

 3.735 BB 354.25323 2.51674e-2 8.91564 Chloride 

Totals : 17.82814

=====================================================================

 *** End of Report ***

Data File U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\004-0502.D

Sample Name: HPLC51pg84 #4

Instrument 1 4/27/2010 3:28:17 PM ARM Page 1 of 1

EA# 0310-129 Page 204 of 221
=====================================================================

Acq. Operator : EO/KHB Seq. Line : 65

Acq. Instrument : Smithers Location : -

Injection Date : 4/27/2010 12:29:34 PM Inj : 1

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG84.M

Last changed : 4/27/2010 3:26:01 PM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\004-6501.D) 2.788 - Fluoride 3.735 - Chloride 5.025 5.791 6.051

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 2.788 BB 558.03223 1.67261e-2 9.33372 Fluoride 

 3.735 BB 357.56897 2.51666e-2 8.99880 Chloride 

Totals : 18.33251

=====================================================================

 *** End of Report ***

Data File U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\004-6501.D

Sample Name: HPLC51pg84 #4

Instrument 1 4/27/2010 3:28:26 PM ARM Page 1 of 1

EA# 0310-129 Page 205 of 221
=====================================================================

Acq. Operator : EO/KHB Seq. Line : 65

Acq. Instrument : Smithers Location : -

Injection Date : 4/27/2010 12:40:22 PM Inj : 2

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG84.M

Last changed : 4/27/2010 3:26:01 PM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\004-6502.D) 2.787 - Fluoride 3.734 - Chloride 5.023 5.788 6.051

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 2.787 BB 558.47992 1.67261e-2 9.34120 Fluoride 

 3.734 BB 357.59656 2.51666e-2 8.99949 Chloride 

Totals : 18.34069

=====================================================================

 *** End of Report ***

Data File U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\004-6502.D

Sample Name: HPLC51pg84 #4

Instrument 1 4/27/2010 3:28:34 PM ARM Page 1 of 1

EA# 0310-129 Page 206 of 221
=====================================================================

Acq. Operator : EO/KHB Seq. Line : 6

Acq. Instrument : Smithers Location : -

Injection Date : 4/26/2010 2:03:34 PM Inj : 1

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG84.M

Last changed : 4/27/2010 3:26:01 PM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\005-0601.D) 2.798 - Fluoride 3.735 - Chloride 5.012 5.779 6.020

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 2.798 BB 838.87366 1.67200e-2 14.02594 Fluoride 

 3.735 BB 591.53021 2.51320e-2 14.86632 Chloride 

Totals : 28.89226

=====================================================================

 *** End of Report ***

Data File U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\005-0601.D

Sample Name: HPLC51pg84 #5

Instrument 1 4/27/2010 3:28:42 PM ARM Page 1 of 1

EA# 0310-129 Page 207 of 221
=====================================================================

Acq. Operator : EO/KHB Seq. Line : 6

Acq. Instrument : Smithers Location : -

Injection Date : 4/26/2010 2:14:22 PM Inj : 2

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG84.M

Last changed : 4/27/2010 3:26:01 PM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\005-0602.D) 2.799 - Fluoride 3.736 - Chloride 5.014 5.781 6.022

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 2.799 BB 845.34424 1.67199e-2 14.13405 Fluoride 

 3.736 BB 592.30658 2.51319e-2 14.88579 Chloride 

Totals : 29.01984

=====================================================================

 *** End of Report ***

Data File U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\005-0602.D

Sample Name: HPLC51pg84 #5

Instrument 1 4/27/2010 3:28:50 PM ARM Page 1 of 1

EA# 0310-129 Page 208 of 221
=====================================================================

Acq. Operator : EO/KHB Seq. Line : 66

Acq. Instrument : Smithers Location : -

Injection Date : 4/27/2010 12:51:10 PM Inj : 1

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG84.M

Last changed : 4/27/2010 3:26:01 PM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\005-6601.D) 2.796 - Fluoride 3.735 - Chloride 5.012 5.781 6.054

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 2.796 BB 877.50427 1.67194e-2 14.67137 Fluoride 

 3.735 BB 597.36316 2.51315e-2 15.01260 Chloride 

Totals : 29.68398

=====================================================================

 *** End of Report ***

Data File U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\005-6601.D

Sample Name: HPLC51pg84 #5

Instrument 1 4/27/2010 3:28:58 PM ARM Page 1 of 1

EA# 0310-129 Page 209 of 221
=====================================================================

Acq. Operator : EO/KHB Seq. Line : 66

Acq. Instrument : Smithers Location : -

Injection Date : 4/27/2010 1:01:57 PM Inj : 2

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG84.M

Last changed : 4/27/2010 3:26:01 PM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\005-6602.D) 2.797 - Fluoride 3.735 - Chloride 5.011 5.780 6.055

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 2.797 BB 877.83441 1.67194e-2 14.67689 Fluoride 

 3.735 BB 597.69507 2.51314e-2 15.02093 Chloride 

Totals : 29.69782

=====================================================================

 *** End of Report ***

Data File U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\005-6602.D

Sample Name: HPLC51pg84 #5

Instrument 1 4/27/2010 3:29:06 PM ARM Page 1 of 1

EA# 0310-129 Page 210 of 221
=====================================================================

Acq. Operator : EO/KHB Seq. Line : 7

Acq. Instrument : Smithers Location : -

Injection Date : 4/26/2010 2:25:09 PM Inj : 1

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG84.M

Last changed : 4/27/2010 3:26:01 PM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\006-0701.D) 2.782 - Fluoride 3.737 - Chloride

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 2.782 BB 247.18105 1.67493e-2 4.14010 Fluoride 

 3.737 BB 148.78517 2.52895e-2 3.76270 Chloride 

Totals : 7.90280

=====================================================================

 *** End of Report ***

Data File U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\006-0701.D

Sample Name: HPLC51pg84 #LCS

Instrument 1 4/27/2010 3:29:13 PM ARM Page 1 of 1

EA# 0310-129 Page 211 of 221
=====================================================================

Acq. Operator : EO/KHB Seq. Line : 7

Acq. Instrument : Smithers Location : -

Injection Date : 4/26/2010 2:35:58 PM Inj : 2

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG84.M

Last changed : 4/27/2010 3:26:01 PM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\006-0702.D) 2.783 - Fluoride 3.738 - Chloride

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 2.783 BB 247.53497 1.67492e-2 4.14601 Fluoride 

 3.738 BB 148.67773 2.52896e-2 3.76000 Chloride 

Totals : 7.90602

=====================================================================

 *** End of Report ***

Data File U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\006-0702.D

Sample Name: HPLC51pg84 #LCS

Instrument 1 4/27/2010 3:29:21 PM ARM Page 1 of 1

EA# 0310-129 Page 212 of 221
=====================================================================

Acq. Operator : EO/KHB Seq. Line : 17

Acq. Instrument : Smithers Location : -

Injection Date : 4/26/2010 6:13:06 PM Inj : 1

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG84.M

Last changed : 4/27/2010 3:26:01 PM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\100-1701.D) 2.788 - Fluoride 3.750 - Chloride 5.054 5.844 6.040

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 2.788 BB 316.86337 1.67401e-2 5.30433 Fluoride 

 3.750 BB 193.20160 2.52411e-2 4.87662 Chloride 

Totals : 10.18095

=====================================================================

 *** End of Report ***

Data File U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\100-1701.D

Sample Name: HPLC51pg84 #3

Instrument 1 4/27/2010 3:41:08 PM ARM Page 1 of 1

EA# 0310-129 Page 213 of 221
=====================================================================

Acq. Operator : EO/KHB Seq. Line : 17

Acq. Instrument : Smithers Location : -

Injection Date : 4/26/2010 6:23:53 PM Inj : 2

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG84.M

Last changed : 4/27/2010 3:26:01 PM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\100-1702.D) 2.787 - Fluoride 3.750 - Chloride 5.056 5.849 6.035

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 2.787 BB 317.41611 1.67401e-2 5.31357 Fluoride 

 3.750 BB 193.56297 2.52408e-2 4.88568 Chloride 

Totals : 10.19925

=====================================================================

 *** End of Report ***

Data File U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\100-1702.D

Sample Name: HPLC51pg84 #3

Instrument 1 4/27/2010 3:41:16 PM ARM Page 1 of 1

EA# 0310-129 Page 214 of 221
=====================================================================

Acq. Operator : EO/KHB Seq. Line : 29

Acq. Instrument : Smithers Location : -

Injection Date : 4/26/2010 11:32:12 PM Inj : 1

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG84.M

Last changed : 4/27/2010 3:26:01 PM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\100-2901.D) 2.788 - Fluoride 3.708 - Chloride 4.920 5.638 6.112

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 2.788 BB 317.66592 1.67400e-2 5.31774 Fluoride 

 3.708 BB 194.23117 2.52402e-2 4.90244 Chloride 

Totals : 10.22018

=====================================================================

 *** End of Report ***

Data File U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\100-2901.D

Sample Name: HPLC51pg84 #3

Instrument 1 4/27/2010 3:41:25 PM ARM Page 1 of 1

EA# 0310-129 Page 215 of 221
=====================================================================

Acq. Operator : EO/KHB Seq. Line : 29

Acq. Instrument : Smithers Location : -

Injection Date : 4/26/2010 11:43:00 PM Inj : 2

Acq. Method : H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Last changed : 2/23/2010 8:12:27 AM by mgb

Analysis Method : U:\HPLC2010Q2\SMITHERS\METHODS\HPLC51PG84.M

Last changed : 4/27/2010 3:26:01 PM by ARM

2 3 4 5 6 7 8 min

μS/cm

0

20

40

60

80

100

 ADC1 A, ADC1 CHANNEL A (U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\100-2902.D) 2.787 - Fluoride 3.707 - Chloride 4.919 5.637 6.110

=====================================================================

 External Standard Report 

=====================================================================

Sorted By : Signal

Calib. Data Modified : Tuesday, April 27, 2010 3:25:57 PM

Multiplier : 1.0000

Dilution : 1.0000

Use Multiplier & Dilution Factor with ISTDs

Signal 1: ADC1 A, ADC1 CHANNEL A

RetTime Type Area Amt/Area Amount Grp Name

 [min] [μS/cm*s] [ug/mL] 

-------|------|----------|----------|----------|--|------------------

 2.787 BB 318.14532 1.67400e-2 5.32575 Fluoride 

 3.707 BB 194.24059 2.52402e-2 4.90268 Chloride 

Totals : 10.22843

=====================================================================

 *** End of Report ***

Data File U:\HPLC2010Q2\SMITHERS\DATA\APR\HPLC51PG84\100-2902.D

Sample Name: HPLC51pg84 #3

Instrument 1 4/27/2010 3:41:32 PM ARM Page 1 of 1

EA# 0310-129 Page 216 of 221
 Method Information

 Method: H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

 Modified: 2/23/2010 at 8:12:27 AM

=========================================================================

 ANALOG DIGITAL CONVERTER

=========================================================================

 Signal 1

 ---------------------

Description: ADC1 CHANNEL A

Source: Signal

Unit: μS/cm

Units/Volt: 100.000

Peakwidth (Data Rate): 0.027 Min (10.00 Hz)

Stop Time: No Limit

Data Storage: All

Start Signal Source: External Device Will Start 35900

Timed Event Table:

 <no events>

 method: H:\HPLC2010Q1\SMITHERS\METHODS\METROHM.M

Modified on: 2/23/2010 at 8:12:27 AM

Smithers 3/16/2010 1:54:21 PM KHB/EO Page 1 of 1

EA# 0310-129 Page 217 of 221
Sequence Table:

 Method and Injection Info Part:

 Line Location SampleName Method Inj SampleType InjVolume

 DataFile AutoBalance LimsID

 ==== ======== ==================== ==================== ======== ========== =========

 1 Vial 127 DI Rinse METROHM 4 Sample 

 

 2 Vial 1 HPLC51pg84 #1 METROHM 2 Sample 

 3 Vial 2 HPLC51pg84 #2 METROHM 2 Sample 

 4 Vial 3 HPLC51pg84 #3 METROHM 2 Sample 

 5 Vial 4 HPLC51pg84 #4 METROHM 2 Sample 

 6 Vial 5 HPLC51pg84 #5 METROHM 2 Sample 

 7 Vial 6 HPLC51pg84 #LCS METROHM 2 Sample 

 8 Vial 7 0.1N H2SO4/NaOH MB METROHM 2 Sample 

 9 Vial 8 R1 A *20 0310-129 METROHM 2 Sample 

 10 Vial 9 MS R1 A *20 0310-129 METROHM 2 Sample 

 11 Vial 10 MSD R1 A *20 0310-129 METROHM 2 Sample 

 12 Vial 11 R2 A *20 0310-129 METROHM 2 Sample 

 13 Vial 12 R3 A *20 0310-129 METROHM 2 Sample 

 14 Vial 13 Acid Blank *20 0310-129 METROHM 2 Sample 

 15 Vial 14 DI H2O Blank 0310-129 METROHM 2 Sample 

 16 Vial 15 R1 B *20 0310-129 METROHM 2 Sample 

 17 Vial 100 HPLC51pg84 #3 METROHM 2 Sample 

 18 Vial 101 HPLC51pg84 #4 METROHM 2 Sample 

 19 Vial 16 MS R1 B *20 0310-129 METROHM 2 Sample 

 20 Vial 17 MSD R1 B *20 0310-129 METROHM 2 Sample 

 21 Vial 18 R2 B *20 0310-129 METROHM 2 Sample 

 22 Vial 19 R3 B *20 0310-129 METROHM 2 Sample 

 23 Vial 20 Base Blank *20 0310-129 METROHM 2 Sample 

 24 Vial 21 R1 *20 0410-50 METROHM 2 Sample 

 25 Vial 22 MS R1 *20 0410-50 METROHM 2 Sample 

 26 Vial 23 MSD R1 *20 0410-50 METROHM 2 Sample 

 27 Vial 24 R2 *20 0410-50 METROHM 2 Sample 

Sequence: U:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC51PG84.S

Instrument 1 4/27/2010 2:45:12 PM ARM Page 1 of 3

EA# 0310-129 Page 218 of 221
 Line Location SampleName Method Inj SampleType InjVolume

 DataFile AutoBalance LimsID

 ==== ======== ==================== ==================== ======== ========== =========

 28 Vial 25 R3 *20 0410-50 METROHM 2 Sample 

 

 29 Vial 100 HPLC51pg84 #3 METROHM 2 Sample 

 30 Vial 101 HPLC51pg84 #4 METROHM 2 Sample 

 31 Vial 102 HPLC51pg84 #LCS METROHM 2 Sample 

 32 Vial 103 0.1N H2SO4/NaOH MB METROHM 2 Sample 

 33 Vial 26 Acid Blank *20 0410-50 METROHM 2 Sample 

 34 Vial 27 DI H2O Blank 0410-50 METROHM 2 Sample 

 35 Vial 28 R1 *20 0410-120 METROHM 2 Sample 

 36 Vial 29 MS R1 *20 0410-120 METROHM 2 Sample 

 37 Vial 30 MSD R1 *20 0410-120 METROHM 2 Sample 

 38 Vial 31 R2 *20 0410-120 METROHM 2 Sample 

 39 Vial 32 R3 *20 0410-120 METROHM 2 Sample 

 40 Vial 33 R4 *20 0410-120 METROHM 2 Sample 

 41 Vial 110 HPLC51pg84 #3 METROHM 2 Sample 

 42 Vial 111 HPLC51pg84 #4 METROHM 2 Sample 

 43 Vial 34 R5 *20 0410-120 METROHM 2 Sample 

 44 Vial 35 R6 *20 0410-120 METROHM 2 Sample 

 45 Vial 36 Acid Blank *20 0410-120 METROHM 2 Sample 

 46 Vial 37 DI H2O Blank 0410-120 METROHM 2 Sample 

 47 Vial 38 U1R1 *20 0410-22 METROHM 2 Sample 

 48 Vial 39 MS U1R1 *20 0410-22 METROHM 2 Sample 

 49 Vial 40 MSD U1R1 *20 0410-22 METROHM 2 Sample 

 50 Vial 41 U1R2 *20 0410-22 METROHM 2 Sample 

 51 Vial 42 U1R3 *20 0410-22 METROHM 2 Sample 

 52 Vial 43 U2R1 *20 0410-22 METROHM 2 Sample 

 53 Vial 110 HPLC51pg84 #3 METROHM 2 Sample 

 54 Vial 111 HPLC51pg84 #4 METROHM 2 Sample 

 55 Vial 102 HPLC51pg84 #LCS METROHM 2 Sample 

 56 Vial 103 0.1N H2SO4/NaOH MB METROHM 2 Sample 

 57 Vial 44 U2R2 *20 0410-22 METROHM 2 Sample 

Sequence: U:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC51PG84.S

Instrument 1 4/27/2010 2:45:12 PM ARM Page 2 of 3

EA# 0310-129 Page 219 of 221
 Line Location SampleName Method Inj SampleType InjVolume

 DataFile AutoBalance LimsID

 ==== ======== ==================== ==================== ======== ========== =========

 58 Vial 45 U2R3 *20 0410-22 METROHM 2 Sample 

 

 59 Vial 46 Acid Blank *20 0410-22 METROHM 2 Sample 

 60 Vial 47 DI H2O Blank 0410-22 METROHM 2 Sample 

 61 Vial 48 FB *20 0410-22 METROHM 2 Sample 

 62 Vial 1 HPLC51pg84 #1 METROHM 2 Sample 

 63 Vial 2 HPLC51pg84 #2 METROHM 2 Sample 

 64 Vial 3 HPLC51pg84 #3 METROHM 2 Sample 

 65 Vial 4 HPLC51pg84 #4 METROHM 2 Sample 

 66 Vial 5 HPLC51pg84 #5 METROHM 2 Sample 

Sequence: U:\HPLC2010Q2\SMITHERS\SEQUENCE\HPLC51PG84.S

Instrument 1 4/27/2010 2:45:12 PM ARM Page 3 of 3

EA# 0310-129 Page 220 of 221
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EA# 0310-129 Page 221 of 221