### CITY OF PHILADELPHIA DEPARTMENT OF PUBLIC HEALTH AIR MANAGEMENT SERVICES RACT PLAN APPROVAL

Effective Date: August 1, 2000 Amended Date: October 7, 2002, February 19, 2014 Expiration Date: None Replaces Permit No. None

In accordance with provisions ofthe Air Pollution Control Act, the Act ofJanuary 8, 1960, P.L. 2119, as amended, and after due consideration ofa ReasonablyAvailable Control Technology (RACT) proposal received underthe Pennsylvania Code, Title 25, Chapter 129.91 thru 129.95, ofthe rules and regulations ofthe Pennsylvania Department of Environmental Protection (PADEP), Air Management Services (AMS) approved the RACT proposal ofthe Facility belowfor the source(s) listed in section 1.A. Emission Sources ofthe attached RACT Plan Approval. Facility:
Owner: Location: Mailing Address: SIC Code(s): Plant ID: Facility Contact: Phone: 

# I Permit Contact: Phone: Responsible Official: 

# I Title:
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# ~~·~· Philadelphia Energy Solutions Refining and Marketing LLC (PES) Philadelphia Energy Solutions Refining and Marketing LLC Girard Point Processing Area located at 3001 Penrose Ave Point Breeze Processing Area located at3144 PassyunkAve 3144 Passyunk Ave., Philadelphia, PA 19145 2911 1501 and 1517 Charles Barksdale (215) 339-2074 Charles Barksdale (215) 339-2074 Nithia Thaver and James Keeler Vice Presidents and General Managers
1 /,**~** , ; i 

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### Wiener, ChiefofSource Registration Date 

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2/19114RACT PLAN APPROVAL PES Page 2

The RACTplan approval is subjecttothe following conditions: I. The purpose ofthis Plan Approval is to establish Nitrogen Oxides (NOx)lVolatile Organic Compound (VOC) Reasonably AvailableControl Technology (RACT) for PES Girard Point ProcessingArea and Point Breeze ProcessingArea. This includesthe following emission sources and control equipment: A. Emission Sources (I) Process Heaters: Unit 137: FI heater (415 MMBTU!hr) F2 heater (155 MMBTU/hr) F3 heater (60 MMBTU/hr) Process heaters FI and F2 bum refinery fuel gas orrefinery fuel oil. Heater F3 bums refinery fuel oil. (2) Process Heater: Unit231: B-10 1heater Heaterfires refineryfuel gas. (3) Process Heater: Unit433: H-I heater(243 MMBTU/hr) Heater fires refinery fuel gas. (4) Process Heaters: Unit 1332: H·400 heater(186 MMBTUlhr) H-401 heater(233 MMBTUlhr) H 600neater(21.3 MMBTU/hr) H 601 heater

### (48 MMBTUlnr) H 602 heater

### (49 MMBTUlnr) H 1heater (45 MMBTU/nr) H-2 heater (60 MMBTUlhr) H 3 heater (43 MMBTUlhr) These heaters bumrefinery fuel gas. (5) Process Heater: Unit 1232: B-104 heater(70 MMBTU/hr) Heaterfires refinery fuel gas.

(6) BoilerHouse #3: Boiler#37 (495 MMBTUlhr) Boiler#38 (495 MMBTU/hr) Boiler#39 (495 MMBTUlhr) Boiler#40 (660 MMBTUlhr) Theseboilers fire refinery fuel gas orrefineryfuel oil. (7) Sludge iRciReratar 8832: URil was 

### 44 MMBTU/hraRd bUrRed refiRery fuel gas orrefiRery fuel oil. (8) SulfurRecovery URit 532: 

### S02 incineratorwas 16 MMBTWhr. URit bUrRed refiRer)' fuel gas. (9) 1232 FCCU CO Boiler: CO '

....aste gas combustion unit (580 MMBTU/hr) bl:lRls I"roeess waste gas, refinery fuel gas and refiRery fuel oil. (I0) Asphalt Heater: HI (12.8 MMBTU/hr) 

### H2 02.8 MMBTu/hr) H3 (\2.8 MMBTWhr) H5 

### (12.8 MMBTU/hr) These heaters burned fire refinery fuel gas. (II) Crude Unit 210: Section A HTR HI01 Section B HTRH20I Section C HTR 13HI (235.4 MMBTU/hr) These heaters above fire refinery fuel gas. (12) Hydrocracker Unit 859: HTR IHI (76 MMBTu/hr) Unit fires refinery fuel gas and retinery fuel oil. 2/19114

### RACT PLAN APPROVAL PES Page 3 HTR 1

### H2 (70 MMBTU/hr) Unit fires refinery fuel gas and refinery fuel oil. HTR IH3 (211 MMBTU/hr) Unit tires refinery fuel gas and refinery fuel oil. HTR I

### H4 (19 

### MMBTU'hr) Unit tires refinery ftlel gas. (13) Reformer Unit 864: HTR PH3 (80 MMBTU/hr) HTR PHS (90 MMBTU!hr) HTR PHI (80 MMBTU.'hr) HTR PH2 

### (45 MMBTWhr) HTR PH4 (57 MMBTUihr) HTR PH7 

### (45.5 MMBTu/hr) HTR PHIl (74 MMBTU/hr) HTR PHI2 (85.1 MMBTUihr) These heaters fire refinery fuel gas and refinery fuel oil. (14) Hydrogen Plant 861: HTR 3HI S (123 MMBTUihr) HTR 3HIN (125 MMBTU/hr) These heaters burned refinery fuel gas. (IS) Distillate HDS Unit 865: HTR IIHI HTR 11

### H2 HTR I

### IH2 These heaters fire refinery fuel gas. (16) Gas 

### Oil HOS Unit 866: HTR 12HIHeaterfires refiflery fuel gas. Gas-Oil HDS Unit 866: HTR 12H

### 1Heater fires refinery fuel gas (17) 22 Boiler House: Boiler#1 (169 MMBTU/hr) Boiler#2 (169 MMBTUIhr) Boiler#3 (203 MMBTU/hr) These three boilers burn only refinery fuel gas or natural gas and are equipped with Ultra Low NOx Burners.
(18) Reformer Unit 860: HTR 2H3 (174.67 MMBTU/hr) Unit fires refinery fuel gas and refinery fuel oil. HTR 2H5 (155 MMBTUihr) Unit fires refinery fuel gas and refineryfuel oil. HTR 2HI (49 MMBTu/hr)Unit fires refinery fuel gas ansrefiner)'f1:lel oil. HTR 2H2 (69.78 MMBTU/hr) Unit fires refinery fuel gas and refinery fuel oil. HTR 2H4 (99.44 MMBTU/hr) Unit fires refinery fuel gas and refinery fuel oil. HTR 2H6 (36.7 MMBTUihr) Unit fires refinery f1:lel gas ana refinery f1:lel oil. HTR 2H7 (59 MMBTU/hr) Unit fires refinery fuel gas and refinery fuel oil. HTR 2H8 (49.6 

### MMBTUihr) Unit fires refinery fuel gas ans retinery fuel oil. Boiler2H9 (165 MMBTU/hr) Unit fires refinery fuel gas ornatural gas. (19) 868 FCCU HTR 8HlOI (49.5 MMBTUihr) Unit fires refiflery fuel gas. 868 FCCU HTR 8H1 0 1Unit fires refinery fuel gas (20) 868 FCCU CatalystRegenerator (21) 867 81:11fur Reco't'ery Unit Incinerator (22) Emergency Flares (23) Coolingtowers (24) Fugitive leaks: valves, tlanges, compressors, pumps, pipes. B. Control Eguipment (1) 

### Ultra-lowNOx burner(ULNB) systems are installed on the following sources to control NOx emissions: Unit433 H- J 

### heater Unit 1232 B-104 heater
2119/14RACT PLAN APPROVAL PES Page 4 #3 Boiler House boilers #37, #38, #39. and #40. Unit 210 H20I heater 2. This approval requires and authorizes: A. The installation ofthe Ultra Low NOx Burners on 433 H-I heater, 1232 B-104 heater, #3 Boiler House boilers #37. #38, #39, and #40, and 210 H20I heaterto comply with RACTrequirements. The installation ofthe burners has been completed. 

### i. The installation of Ultra Low NOx Burners on 231 BIOI heater and 865 IIHI heater to comply with RACT requirements afterthe issuance ofPlan Approval No. 12195. B. PES

### will use combustion tuningto comply with RACTrequirements forthe following heaters: Unit 137: FI heater, F2 heater, F3 heater Unit 231: B 101 heater Unit 1332: H-400 heater, H-40I heater, H-2 heater Crude Unit: 21OA HTR H10I,210C HTR 13HI Hydrocracker Unit 859: HTR IHI, HTR IH2, HTR IH3 Reformer Unit 864: HTRPH3, HTR PH5. HTR PHI, HTR PH2, HTR PH4, HTR PHil, HTR PHI2 Hydrogen Plant 861: HTR 3HIS, HTR 3HIN Distillate HDS Unit 865:HTR IIHI, HTR IIH2 ReformerUnit 860: HTR2H3, HTR2H5, HTR2H4, HTR2H2. HTR2H7 GasOil HDS Unit 866: HTR 12Hl Gas Oil HDS Unit 866: HTR 12HI, Unit 868: HTR 8HIOI C. All fuel burning sources will becapped at the heat inputspecified in the table below. [fPES desires to raise the cap, a RACT evaluation will have to be performed at that new heat input. The economicevaluation will be made using cost of living increases. Changes will require a resubmission as revision to the PA State Implementation Plan. The applicant shall bear the cost ofpublic hearing and notification required for EPA approval as stipulated in 25 PA Code § 129.9(h). Modifications or changes may require additional controls or more strict emission limits depending on the applicable regu atlOn trtggere I' . d as a resuI tot f he mod'fi I lcafIOn orchange,

Process Unit Unit 137:

Unit433: Unit 1332: Unit 1232: BoilerHouse #3:
HydrocrackerUnit 859:
Reformer Unit 864: Source FI heater F2 heater
H-I heater H-400 heater B-I04 heater Boilers#37, #38, #39 Boiler#40
HTRIH! HTRIH2 HTR PH3 I HTRPH5

HTRPH2 Heat Input Cap (MMBTUlhr) 415 155 741 186 70 495 660
76 70 80 90 45 HTR PH4 57 Hydrogen Plant 861: HTR3HIS 123 HTR 3HIN 125
D. PESsha11 monitor all fuel inputtoall heaters and boilerswith BTU limitations on a daily basisto insure capacity limits are not exceeded or PES shall install fuel limiting devices on the heaters orboilers to keep capacities belowallowable. The compliance method must be in place byJune 30th 2000. E. All fuel combustkm sources with heat input equal to Of greaterthan 20 MMBTUlhr and less than**~1i.tU** oomplj' with applicable presumptive RACT requirements of25 Pi\' Code I29.93(b)(2) (5). All fuel combustion sources wtth-heat input less than 20 MMBTUlhr shall complywith presumptive RACTreqttirements 0[15 PA Code 129.93(c). 

### 2/19/14RAeT PLAN APPROVAL PES Page 5

F. RACT for 22 Boiler House: Boiler#I, Boiler#2, and Boiler#3 is combustion tuning. G. RACT for Reformer Unit 860 HTR 2H9 is combustion tuning. H. The 868 FCCU NOx emissions shall be limited to 569 tons per year calculated on a 365 day rolling average basis. PES shall follow good combustion practices controlling the level of excess oxygen and CO promoter in the regenerator to minimize NOx emissions from the regenerator. J. PES shall utilize an inspection and maintenance/monitoring program for VOC fugitive emissions from cooling towers. K. PES shall utilize a fugitive emissions leak detection and repair program (LDAR) for all valves, pumps, flanges, and compressors in VOC service. All applicable equipment shall be tagged by May 31, 1995. Monitoring ofcomponents shall begin by July 

### 3 L 1995 and shall be conducted on a quarterly basis (gaseous service) and an annual basis (liquid service) for all sources not covered underan existing LDAR program. The 1232 FCCU CO Boiler: CO waste gas comet:lstioA t:lAit (580 MMBTUihr) shall comply with the presumptive RACT reqHirements of25 PA Code 129.93(c)('I), 'Ilhich is iflstallation, maintenance aAd operation ofthe source in accordance with mant:lfactt:lrers specifications. 3. RACT Implementation Schedule A. Upon issuance ofthis approval, PES shall begin immediate implementation ofthe measures necessary to comply with the approved RACT proposal. B. Sources proposing combustion tuning to comply with RACT requirements of25 PA Code 129.91({) shall perform the annual combustion tuning by December 31 H ofeach year not to exceed 12 months betweentunings. C. Sources applicable to presumptive RACT requirements of 25 PA Code 129.93(b)(2) shall complete the annual adjustment ortune-up by December 31 51 ofeach year notto exceed 12 months between tunings. D. Sources proposing installing Ultra Low NOx Burners to comply with RACT requirements of25 PA Code 129.91({) shall perform combustion tuningannually by December 31 st ofeach yearnot to exceed 12 months betweentunings. E. The installation of Ultra Low NOx Burners on 231 BIOI heater and 865 I1Hl heater to comply with RACT requirements within 18 months afterthe issuance ofPlan Approval No. 12195. The 231 B101 heater shall be limited to 91 MMBTU/hr and 0.122 Ibs NOxlMMBTU until the burners are installed. The 865 IIHI heater shall be limited to 72.2 MMBTU/hr and 0.113 lbs NOxlMMBTU until the burners are installed. The 0.030 Ibs/MMBTU NOx emission limit listed below for each unit will not become applicable until the burners are installed.

4. Testing Requirements and Stack Emission Limitations A. For units installing ULNB, PES shall conduct performance tests for NOx. The results of these tests have been submitted to AMS. B. The final NOx RACT emission limits for the #3 Boiler House boilers, 137 Unit FI heater, #22 Boiler House boilers: #I, 2, & 3, Unit 210 H20I heater, and the 860 unit Boiler 2H9 have been established through the use ofDepartment approved Continuous Emission Monitoring System (CEMS). Compliance with the limitations listed below will be on 

### a 30-day rolling average based on hourly averages ofCEM data, except for the Unit 210 H201 heater, which will be on a365

-d 

### ll' mg average based h I a a. ay ro on ounyaverages 0f CEM d t Source Limitation Boiler House #3 boilers #37, #38, #39, and #40 0.330 Ibs. NOx/MMBTU ! 137 Unit F Iheater 0.230 Ibs. NOxiMMBTU

Rdormer Unit 860 Boiler 2H9 0.20 Ibs. NOXlMMBTU 1122 Boiler House

- boilers #1, #2. and #3 0.20 Ibs. NOxlMMBTU Unit 210 H201 heater •0.030 Ibs. NOx/MMBTU C. Compliance With emISSion lImIts for combustion sources listed below shall be determIned by quarterly stack sampling with a portable NOx analyzer. After one year sampling, PES may petition AMS for semi-annual monitoring. AMS
2/19/14RACT PLAN APPROVAL PES Page 6
may, at any time, require three one-hour stack tests per fuel type for each unit where fuels can be tired separately. AMS may, at any time, require three one-hour stacktests for dual-fuel type combustion sources where both fuels must be fired at the same time and compliance with emission limits will be through the use ofone set ofthree one-hour stacktests Limitation (Ibs. NOx/MMBTU) Source Gas Oil Process Heater Unit 433 H-l heater 0.060 NiA Process Heater Unit 1332 H-400 heater 0.156 N/A Process Heater Unit 1332 H-40I heater 0.156 N/A Crude Unit 210A HTR H101 0.089 Crude Unit 210C HTR 13HI 0.104 0.4 Hydrocracker Unit 859 HTR IH3 0.134 0.4 Hydrogen Plant 861 HTR3HIS 0.133 

### N/A Hydrogen Plant 861 HTR3HIN 0.133 N/A F-2@ 137 Unit 0.257 0.4 F-3 @ 137 Unit 

### N/A 0.4 B-IOI@ 231 Unit (until ULNB installed) 0.122 

### N/A B-IOI(a) 231 Unit (after ULNB installed) 0.03 

### N/A H-2 (a) 1332 Unit 0.300 

### N/A B-I04 @ 1232 Unit 0.177 

### N/A IH-I (jj) 859 Unit 0.123 0.4 1 H-2 (a) 859 Unit 0.123 0.4 PH-3 @ 864 Unit 0.284 0.4 PH-5 (a) 864 Unit 0.283 0.4 PH-I (a) 864 Unit 0.167 0.4 PH-4 (jj) 864 Unit 0.102 0.4 PH-II @ 864 Unit 0.145 0.4 PH-12 @ 864 Unit 0.119 0.4 IIH-I @ 865 Unit (until ULNB installed) 0.113 IIH-l (a) 865 Unit (after ULNB installed) 0.113 

### N/A 2H-3 @ 860 Unit 0.163 0.4 2H-5 @ 860 Unit 0.163 0.4 2H-2 @ 860 Unit 0.350 0.4 2H-4 @ 860 Unit 0.270 0.4 2H-7 (jj) 860 Unit 0.157 0.4 Unit 865 IIH2 heater 0.113 

### N/A Unit 866 12HI heater 0.113 

### N/A Unit 868 8HI 0 I heater 0.113 

### N/A

.. D. All annual combustIOn tunIng shall at a mInImum meet the requIrements set forth In 129.93 (b)(2) through (5).
E. At least thirty(30) days priorto a performance NOx test, PES shall inform AMS ofthe date and time ofthe scheduled test. 

### F. PES shall conduct performancetests to determine compliance with the Ibs NOx/MMBTU emission limits ofthis plan approval for the following heaters:

1. Within 180 days ofthe installation ofULNBs for the Unit 23 I B I01 Heaterand the Unit 865 IIH I Heater. 11. Within 180 days ofthe issuance ofPlan Approval No. 12195 forthe Unit 210 HI0 I Heater, Unit 865 IIH2 Heater, Unit 866 12HI Heater, and Unit 868 8HI 0 I Heater. 111. Testing shall be conducted in accordance with 25 Pa. Code Chapter 139
G. The Unit 210 H20I Heater shall be equipped with continuous monitors and recorders for NOx andO2. The continuous monitors and recorders shall meet the requirements of25 Pa. Code Chapter 139.

2/\9/14

### RACT PLAN APPROVAL PES Page 7 H. Each heater listed belo\\< shall be limited to the following rolling 365-day heat input limits:

I. 

### Lnit 231 B101 Heater shall not exceed 915,420 MMBTU on arolling 365-day basis. Ii. Unit 865 IIH I Heater shall not exceed 764,748 MMBTU on arolling 365-day basis. iii. Unit 865 IIH2 Heatershall not exceed 562,392 MMBTU on arolling 365-day basis. iv. Unit 210 HI0 I Heater shall not exceed 1,681,920 MMBTU on arolling 365-daybasis. v. Unit 210 H20IAiB Heater shall not exceed 2,225,040 MMBTU on arolling 365-daybasis. vi. Unit 866 12HI Heater shall not exceed 536,112 MMBTU on arolling 365-daybasis. 1. Unit 868 8H 101 Heater shall not exceed 525,600 MMBTU on arolling 365-day basis 5. Recordkeeping and Reporting Requirements A. The permittee shall maintain a file containing all the records and other data that are required to be collected to demonstrate compliance with NOx/VOC RACT requirements of25 PA Code 129.91

- 129.94. B. The records shall provide sufficient data and calculations to clearly demonstrate that the requirements of §129.91­ 129.94 are met. C. Data or information required to determine compliance shall be recorded and maintained in a time frame consistent with the averaging period ofthe requirement. D. Records shall beretained for at leasttwo years and shall be made available to the Department on request. 6. The operatioR ofthe aforemeRtioRea seurees shall Rot at aR)' time result in the emissioA ofvisible air contaminants in excess ofthe limitations specified in 8eetion 123AI, 

### particulate matter ift excess oftAe limitations speeified in Section 123.11 orsulfuroxides ift e){eess oftAe limitatiofts specified in Section 123.22, all Sections ofChapter 123 ofArtieIe 1Il of tAe Rules and Regulations ofthe Department ofEW/ironmental Resources, or in the emission ofany ofthese or any other type ofair contamiftaftt 1ft exeess ofthe limitations speeified in, or established pursuant to, any other applicable rule or regulatioft eofttaifted ift Artiele Ill. 7. The company shall not impose conditions upon or otherwise restrict the Department's access to the aforementioned source(s) and/or any associated air cleaning device(s) and shall allow the Department to have access at any time to said source(s) and associated air cleaning device(s) with such measuring and recording equipment, including equipment recording visual observations, as the Department deems necessary and proper for performing its duties and for the effective enforcementofthe Air Pollution Control Act. 8. Revisions to any emission limitations incorporated in this RACT Approval will require resubmission as revision to the PA State Implementation Plan. The applicant shall bearthe cost ofpublic hearing and notification required for EPA approval as stipulated in 25 PA Code §129.9(h). ,VOTE: Wording witll sIFikell"ough/Ollt isNOTbeillgsubmitted/orSIPapproval.

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