# Patent

## Title
Color depositing shampoo

## Abstract

A composition for coloring and shampooing hair substantially free, preferably totally and completely free, of anionic surfactants, comprising at least one cationic dye, n-methyl alkyl glucamide with a carbon chain length from 8 and 20, inclusive, preferably 8 and 10, an aqueous carrier, and at least one stabilizer of anti-oxidant and free radical scavanger. By weight, (based on the total weight of the composition), the composition comprises 0.0005% to 3.0% cationic dye, 2.5 to 30% n-methyl alkyl glucamide, 30 to 70% water, and 0.01 to 0.5% stabilizers of anti-oxidant and free radical scavenger. Other ingredients, including a rheology modifying polymer, conditioning ingredients, and additional surfactants, may also be included in the composition and are also included in the scope of the invention.

## Background
FIELD OF THE INVENTION
The present invention relates to compositions for coloring and cleansing hair using a one-part formulation. More specifically, the invention relates to shampoo compositions containing at least one cationic dye and a nonionic surfactant with improved foaming ability compared to existing color depositing shampoo products.
BACKGROUND
Basic cationic hair dyes have been available for use in cosmetic products for more than twenty years. They have been adapted for use in color refreshing shampoo and conditioners, temporary hair color gels, and cremes. The products are intended to enhance and refresh previously colored hair, neutralize an unwanted shade, bring new highlights, and create visible color change.
One of the main drawbacks for cationic dyes in many types of hair care products is they are not useful in combination with or within products containing anionic ingredients, particularly anionic surfactants. The combination of cationic dyes and anionic ingredient(s) in a single product, e.g., a color depositing shampoo, causes a reduction of foaming properties (in a shampoo, foaming is recognized as being a desirable attribute. A shampoo that does not foam or does not foam adequately or with a suitable foam quality generally has perceived consumer negatives) and reduced color deposition. The combination of the two could also cause precipitation of an unwanted anionic/cationic complex. Common industry practice therefore utilizes high levels/quantities of cationic dyes in order to compensate for these drawbacks while still achieving a desired level of color deposition. Consequently, existing color depositing shampoos must use greater amounts of dye in the products to account for the “waste” causing higher costs of goods and thus higher retail prices effectively rendering combined cationic dye with anionic surfactant products highly difficult to market.
The current industry alternative for color depositing shampoos is a combination of a cationic dye with amphoteric and/or nonionic surfactants. Those products do not suffer from the above stated disadvantages arising primarily from the opposing ionic charges of the dye and surfactant. Here again, however, there are well known disadvantages. One problem with coloring shampoos which are generally free of anionic surfactants (that is, they are based on nonionic, amphoteric and/or cationic surfactants) is that they have a tendency not to foam adequately or may have poor sensory properties associated with the foaming, such as a tendency for any foam that does generate to generate slowly, spread slowly, or to dissipate quickly. The viscosity of the product(s) is also difficult to control. Addition of a small amount of an anionic surfactant (which adds to the production steps and increases cost of goods) is sometimes done to improve the foaming properties of a dye product made with a nonionic, amphoteric and/or cationic surfactants, knowing the resulting product will suffer from decreased dye deposition and/or suffer long term stability issues such as tonal shifts, precipitation or separation.
Thus there is a need for a color depositing shampoo made with cationic dyes that is substantially free from anionic surfactants with good foaming properties to efficiently and effectively deliver the dyes to the hair. It would be highly beneficial to have a color depositing shampoo that can achieve equal, if not more, dye deposition (and thus color change) compared to existing products, using less dye within the compositions of those existing products. There is a need for a color depositing shampoo that has less waste of dye when used. There is a need for a lower cost to manufacture color depositing shampoo that can effectively deposit color with good foaming properties.
It is thus an object of the present invention to provide a shampoo based formulation that will efficiently color the hair and effectively clean the hair. It is also an object of the invention to provide a shampoo based formulation that will replace ordinary shampoo but also be useful as a hair dye, a composition with improved and more desirable foaming properties.
SUMMARY OF THE INVENTION
Applicant has invented a composition that overcomes these and other shortcomings. While the invention will be described in connection with certain embodiments, it will be understood that the invention is not limited to those embodiments. To the contrary, the invention includes all alternatives, modifications and equivalents as may be included within the spirit and scope of the present invention.
Applicant has surprisingly discovered that the combination of a specific non-ionic surfactant, namely n-methyl alkyl glucamide, with a cationic dye(s) can be used to create an effective and efficient color depositing shampoo with unexpected and desirable foaming properties. Thus, Applicant has discovered that a color depositing shampoo with preferred foaming properties can be made without the need for extra dye and without any anionic surfactant. Applicant has discovered an efficient, effective, lower dye composition, color depositing shampoo with desirable foaming properties comprising a cationic dye and n-methyl alkyl glucamide. Applicant has discovered that use of n-methyl alkyl glucamide with a chain length anywhere from 8 to 20 is possible and included within the scope of the invention, with a C8/C10 carbon chain length most preferred for its lathering properties. The invention allows for efficient dye deposition with commercially acceptable foaming characteristics. The composition of the present invention thus provides unexpected superior results for a shampoo capable of depositing color with desirable foaming
The present invention relates to the application of cationic dyes to human hair using a one-part shampoo based formulation. The invention is a cleansing and coloring composition that is substantially free, preferably totally and completely free, of anionic surfactants. In one embodiment, said composition according to the invention comprises:

    
    
        (a) at least one cationic dye;
        (b) n-methyl alkyl glucamide with a carbon chain length between 8 and 20 (C8-C20), inclusive, preferably 8 (C8) and 10 (C10);
        (c) an aqueous carrier; and
        (d) at least one stabilizer of anti-oxidant and free radical scavanger.

Optionally, other ingredients that may be added to the composition but which are not necessary for the composition, include a rheology modifying polymer, conditioning ingredients, and additional surfactants.

    
    


The color depositing shampoo composition according to the invention comprises, by weight (all the weight percents are based on the total weight of the composition):

    
    
        (a) 0.0005% to 3.0% cationic dye;
        (b) 2.5 to 30% n-methyl alkyl glucamide;
        (c) 30 to 70% water; and
        (d) 0.01 to 0.5% stabilizers of anti-oxidant and free radical scavenger.
    
    


The properties of the invention are surprising and unique over existing technologies because the composition effectively delivers acceptable and efficient color to hair along with a consumer acceptable foam. The color and long term stability of the composition continues to deliver the same amount of color to the hair. Formulas with materials that are anionic deliver less color to the hair and overtime are seen to deliver less or undesirable results. The foaming characteristics of the invention is closer to the amount of foam delivered from a traditional anionic, sulfate shampoo.



BRIEF DESCRIPTION OF THE DRAWINGS
The patent or application file contains at least one drawing executed in color. Copies of this patent or patent application publication with color drawing(s) will be provided by the Office upon request and payment of the necessary fee.
The accompanying drawings, which are incorporated in and constitute a part of this specification, illustrate embodiments of the invention and, together with the general description of the invention given above and the detailed description of an embodiment given below, serve to explain the principles of the present invention. Similar components of the devices are similarly numbered for simplicity.
FIG. 1 illustrates the composition for one example embodiment of the invention with the percentages representing the amount by weight compared to total weight of the composition.
FIG. 2 is a graph showing the foaming properties of n-methyl alkyl glucamide surfactants having different carbon chain lengths.
FIGS. 3 and 5 include pictures of swatches dyed with a composition according to the invention and four other comparative compositions at day 1 and day 21, respectively.
FIGS. 4 and 6 are line graphs showing the change in color for the swatches compared to the control bleached swatch (overall color change ΔE=SQRT(ΔL2+Δa2+Δb2) at day 1 and day 21, respectively.
FIG. 7 contains a table showing the results of the foaming tests for the compositions tested.
FIGS. 8-11 contain tables with the compositions of the comparative examples tested and compared to test results for Applicant's example composition.
FIG. 12 illustrates the composition for a second example embodiment of the invention with the percentages representing the amount by weight compared to total weight of the composition.



DETAILED DESCRIPTION OF THE INVENTION
Reference is being made in detail to presently preferred embodiments of the invention. Selective embodiments are provided by way of explanation of the invention, which is not intended to be limited thereto. In fact, those of ordinary skill in the art may appreciate upon reading the present specification and viewing the present drawings that various modifications and variations can be made.
The present invention is a one-part shampoo based composition for cleansing and coloring hair that is substantially free, preferably totally and completely free, of anionic surfactants. In one embodiment, the composition according to the invention comprises:

    
    
        (a) at least one cationic dye;
        (b) n-methyl alkyl glucamide with a carbon chain length between 8 and 20, inclusive, preferably 8 and 10;
        (c) an aqueous carrier; and
        (d) at least one stabilizer of anti-oxidant and free radical scavanger.

Optionally, other ingredients that may be added to the composition but which are not necessary for the composition, include a rheology modifying polymer, conditioning ingredients, and additional surfactants.

    
    


The color depositing shampoo composition according to the invention comprises, by weight (all the weight percents are based on the total weight of the composition):

    
    
        (a) 0.0005% to 3.0% cationic dye;
        (b) 2.5 to 30% n-methyl alkyl glucamide;
        (c) 30 to 70% water; and
        (d) 0.01 to 0.5% stabilizers of anti-oxidant and free radical scavenger.
    
    


It being understood that the above described compositions are open to the inclusion of other ingredients that may alter the characteristics of the formula without rendering the system inoperative as a color depositing shampoo.
Use of a stabilizer prevents a shift in the color deposition as the product ages and is exposed to heat. The stabilizer consist of an anti-oxidant and free radical scavenger, such as, for example, tocopherol and sodium citrate.
Other active ingredients may include rheology modifiers, fragrances, chelating agents, opacifiers, conditioning ingredients and other adjuvants. Optionally, suitable amphoteric, nonionic and/or cationic surfactants may be added to the compositions of the invention as desired. Compositions of this invention may contain any other non-anionic ingredients normally used in hair shampoos. These other ingredients may include proteins, fragrances, preservatives, thickeners, conditioners, humectants, opacifiers, and/or pH adjustors.
FIG. 1 illustrates the composition for one example embodiment of the invention with the percentages representing the amount by weight compared to total weight of the composition. In FIG. 1, the n-methyl alkyl glucamide has a carbon chain length of eight and ten (C8/C10). Applicant has surprisingly discovered that using a n-methyl alkyl glucamide surfactant with a C8/C10 carbon chain length produces a non-ionic based surfactant shampoo with superior foaming properties when cationic dyes are incorporated to create a color depositing shampoo. As shown in FIG. 2, the foaming properties of a shampoo made from n-methyl alkyl glucamide is greatest when the carbon chain length is C8/C10, and decreases as the carbon chain length increases, such as seen in the results for the C12/C14 and the C12/C18 chain length ranges. The n-methyl alkyl glucamide surfactant used in the composition of an embodiment of the invention is not, however, limited to just the C8/C10 carbon chain length. The invention also includes embodiments comprising other carbon chain lengths of the n-methyl alkyl glucamide surfactant in the composition. For example, an embodiment may include a combination of n-methyl alkyl glucamide surfactant having carbon chain lengths C8 to C12, or C8 to C14, or C12 to C14, and others. Combinations of different carbon chain lengths ranging from C8 to C20 are possible and included in the scope of the invention. The n-methyl alkyl glucamide surfactant may be one from the group consisting of capryloyl/caproyl methyl glucamide, lauroyl/myristoyl methyl glucamide, and cocoyl methyl glucamide. The dye may be at least one from the group consisting of Basic Blue 124, Basic Yellow 87, Basic Red 51, Basic Orange 31, Basic Brown 17, Basic Blue 99, HC Blue 16, HC Blue 15, Basic Violet 2, Basic Brown 16, and Basic Yellow 57.
The compositions of the invention may be made by dispersing the ingredients in water followed by the application of sufficient heat to dissolve the ingredients without causing decomposition. For example, the procedure to create the example composition identified in FIG. 1 is as follows:

    
    
        1. To vessel, add water and disperse guar hydroxypropyltrimonium chloride with a prop mixer.
        2. Add polyacrylate-1 cross polymer with continued mixing.
        3. Add surfactants, chelator, preservatives, panthenol and protein.
        4. Premix the fragrance and the phytantriol and add to main batch.
        5. Adjust pH to between 4.5 and 5.0 with citric acid. Continue mixing for 45 minutes.
        6. In a separate vessel, charge water and add dyes. Heat to 60 degrees Celsius and mix until dyes are dissolved. Add to main vessel and mix until uniform.
    
    


The superior color depositing and foaming properties of the shampoo according to the invention is depicted by way of a comparison with existing compositions. Applicant's color depositing shampoo according to the example embodiment in FIG. 1 (an illustration of the invention and not intended to limit same) was compared to four other shampoos that impart color to the hair and those products are described in published patent references. For purposes of the comparison, Applicant's composition is identified as “Example 1” and the other compositions are identified as “A”, “B”, “C” and “D”. The compositions were all produced exactly as disclosed in the patent references, and the dye colors were replaced with the same basic cationic dye colors used in Example 1 and in equal amounts, that is 0.13% basic brown 17, 0.13% basic blue 99, and 0.2% basic red 76, for a total dye composition of 0.46% by weight.
Example 1 and all four comparative compositions (A, B, C, and D) were evaluated by the same two tests, one to measure the amount of hair color change resulting from use (the amount of dye deposition), and one to measure foaming.
For the dye deposition measurement test, bleached hair swatches supplied by International Hair Importers were used. Each swatch was dyed out with one of the compositions, the dye out procedure involved one lather of the shampoo with rinsing, followed by blow drying of the swatch. The procedure was repeated after a 21 day period on new swatches. The color was visually assessed at day 1 and at day 21 with side by side comparisons of the swatches. The amount of color change was also measured at day 1 and day 21 on the CIELAB scale using a Hunter Lab Ultra Scan XE Colormeter. FIGS. 3 and 5 include pictures of the swatches at day 1 and day 21, respectively. FIGS. 4 and 6 are line graphs showing the overall color change (ΔE) for the swatches at day 1 and day 21, respectively.
The foaming of each shampoo was assessed by a blender test modified version of ASTM D3519-88 Foam in aqueous media (blender test). 1.0 grams of shampoo was mixed with 99.0 grams deionized water until homogeneous. The shampoo solution was put into a Bodum blender and run on “high” for 60 seconds. The height of the foam was measured. FIG. 7 contains a table showing the results of the foaming test.
Comparative example A is from Tamareselvy et. al. (U.S. Pat. No. 7,378,479), which discloses the combination of the cationic dyes with anionic surfactants (sodium and ammonium laureth sulfates), in combination with amphoteric surfactants (such as cocamidopropyl betaine) and cationic compatible amino-substituted vinyl polymer as a shampoo for color treatment and color maintenance. The composition for A produced and tested is set forth in FIG. 8. As shown in the results, significantly less color deposition occurred on the swatch for A compared to Applicant's Example 1.
Comparative example B is from Kapsner, et. al. (U.S. Pat. No. 6,500,413 B1) which discloses the combination of one or more cationic components in an anionic system provided the predominant anionic surfactant is an alkyl glucoester. The composition for B produced and tested is set forth in FIG. 9. As shown in the results, less color deposition occurred compared to Example 1 and B produced significantly less foaming compared to Example 1.
Comparative example C is from Massoni (U.S. Pat. No. 7,578,857 B1) which discloses use of cationic dyes, amphoteric surfactants, nonionic surfactants and an anionic sarcosinate surfactant for a shampoo coloring formulation. The composition for C produced and tested is set forth in FIG. 10. As shown in the results, less color deposition occurred compared to Example 1 and C produced significantly less foaming compared to Example 1.
Comparative example D is from Schmucker-Castner et. al., (U.S. Pat. No. 7,217,752) which discloses a stable, aqueous composition containing a substantially cross linked alkali-swellable acrylate copolymer rheology modifier, a surfactant, an alkaline material and various compounds requiring suspension or stabilization. Additionally, the reference discloses a phase stable cationic dye composition. The composition for D produced and tested is set forth in FIG. 11. Although the amount of color deposition compared to Example 1 may be close, D provides significantly less foaming than Example 1.
Accordingly, none of the other compositions tested provide the same or an equivalent ability to color hair and foam.
It should be understood, of course, that the foregoing relates to exemplary embodiments of the invention and that modifications may be made without departing from the spirit and scope of the present invention.

## Claims

1. A one-part coloring depositing shampoo composition for human hair comprising:
at least one cationic dye;
a non-ionic surfactant that is n-methyl alkyl glucamide with a carbon chain length of 8 and 10; and
an aqueous carrier;
wherein said composition does not contain any anionic surfactant.

2. The composition of claim 1, wherein the composition comprises, by weight:
0.0005% to 3.0% cationic dye;
2.5 to 30% n-methyl alkyl glucamide; and
30 to 70% aqueous carrier.

3. The composition of claim 2, wherein said n-methyl alkyl glucamide is selected from the group consisting of capryloyl/caproyl methyl glucamide and cocoyl methyl glucamide.

4. The composition of claim 2, further comprising an amphoteric surfactant or a nonionic surfactant.

5. The composition of claim 2, further comprising a thickener.

6. The composition of claim 2, further comprising a stabilizer.

7. The composition of claim 2, further comprising an opacifier.

8. The composition of claim 2, further comprising a chelating agent.

9. The composition of claim 2, wherein said cationic dye is at least one from the group consisting of Basic Blue 124, Basic Yellow 87, Basic Red 51, Basic Orange 31, Basic Brown 17, Basic Blue 99, HC Blue 16, HC Blue 15, Basic Violet 2, Basic Brown 16, and Basic Yellow 57.

10. The composition of claim 2, wherein said aqueous carrier is water.

11. The composition of claim 1, wherein the composition comprises, by weight:
less than 0.50% cationic dye;
2.5 to 30% n-methyl alkyl glucamide; and
30 to 70% water.

12. The composition of claim 11, wherein said cationic dye composition is about 0.46% by weight.

13. The composition of claim 12, wherein said n-methyl alkyl glucamide is about 2.5% by weight.

14. A method of dyeing human hair, which comprises shampooing the hair with the composition as claimed in claim 1.

15. A method of dyeing human hair, which comprises shampooing the hair with the composition as claimed in claim 2.

16. A method of dyeing human hair, which comprises shampooing the hair with the composition as claimed in claim 3.

17. A method of dyeing human hair, which comprises shampooing the hair with the composition as claimed in claim 4.

18. A method of dyeing human hair, which comprises shampooing the hair with the composition as claimed in claim 5.

19. A method of dyeing human hair, which comprises shampooing the hair with the composition as claimed in claim 6.

20. A method of dyeing human hair, which comprises shampooing the hair with the composition as claimed in claim 7.

21. A method of dyeing human hair, which comprises shampooing the hair with the composition as claimed in claim 8.

22. A method of dyeing human hair, which comprises shampooing the hair with the composition as claimed in claim 9.

23. A method of dyeing human hair, which comprises shampooing the hair with the composition as claimed in claim 10.

24. A method of dyeing human hair, which comprises shampooing the hair with the composition as claimed in claim 11.

25. A method of dyeing human hair, which comprises shampooing the hair with the composition as claimed in claim 12.

26. A method of dyeing human hair, which comprises shampooing the hair with the composition as claimed in claim 13.

27. A one-part coloring depositing shampoo composition for human hair comprising:
at least one cationic dye, wherein said total amount, by weight, of cationic dye is 0.0005% to 3.0%;
a non-ionic surfactant that is n-methyl alkyl glucamide with a carbon chain length greater than or equal to 8 and less than or equal to 20; and
an aqueous carrier;
wherein said composition does not contain any anionic surfactant.

28. The composition of claim 27, wherein said composition comprises, by weight 2.5 to 30 percent n-methyl alkyl glucamide.