### 13339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone: 980-875-5245 Fax: 980-875-4349 

# Order Summary Report 

# Analytical Laboratory

Order Number: J13060456 Project Name:

Lab Contact: Jason C Perkins 

## Date: 7/11/2013 Customer Address: 3195 Pine Hall Rd Customer Name(s): Josh Quinn

Mailcode: Belews Steam Station Belews Creek, NC 28012
Phone: 980-875-5348 Report Authorized By: (Signature) 

### Program Comments: Please contact the Program Manager (Jason C Perkins) with any questions regarding this report. Data Flags & Calculations: Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. Jason C Perkins

# Sample ID's & Descriptions:

Sample ID Plant/Station Collection Date and Time Collected By Sample Description 2013014995 BELEWS 27-Jun-13 8:00 AM David Horne Bottom Ash Sluice 0.3m 2013014996 BELEWS 27-Jun-13 9:52 AM David Horne Service/ Intake Water 0.3m 2013014997 BELEWS 27-Jun-13 9:15 AM David Horne Ash Basin 2013014998 BELEWS 27-Jun-13 7:50 AM David Horne Blank 4 Total Samples

### COC and .pdf report are in agreement with sample totals

and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. All laboratory QA/QC requirements are acceptable. Yes No



# Technical Validation Review Checklist:

Yes No
Yes No


# Report Sections Included:

Job Summary Report Sub-contracted Laboratory Results Sample Identification Customer Specific Data Sheets, Reports, & Documentation Technical Validation of Data Package Customer Database Entries Analytical Laboratory Certificate of Analysis Analytical Laboratory QC Report Chain of Custody

Reviewed By: 

### DBA Account Date: 

### 7/11/2013 Electronic Data Deliverable (EDD) Sent Separately

# Certificate of Laboratory Analysis This report shall not be reproduced, except in full.



## Order # J13060456

2013014995 Collection Date: 27-Jun-13 8:00 AM 

## Site:Bottom Ash Sluice 0.3m Matrix: OTHER
Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

## Sample #:

Analyst DF OIL AND GREASE IN WATER - SOLID PHASE EXTRACTION Oil and Grease < 5 mg/L EPA 1664B 06/28/2013 10:15 TJA7067 5 1 BIOCHEMICAL OXYGEN DEMAND (BOD) - (Analysis Performed by Pace Laboratories) BOD Complete Vendor Method V_PACE AMMONIA (COLORIMETRIC) Ammonia (Colorimetric) 0.037 mg-N/L EPA 350.1 07/08/2013 11:54 BGN9034 0.02 1 NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) < 0.01 mg-N/L EPA 353.2 07/08/2013 11:08 BGN9034 0.01 1 TOTAL KJELDAHL NITROGEN (COLORIMETRIC) Total Kjeldahl Nitrogen (Colorimetric) 0.20 mg-N/L EPA 351.2 07/10/2013 14:02 TLINN 0.15 1 TOTAL PHOSPHORUS (COLORIMETRIC) Total Phosphorus (Colorimetric) 0.035 mg-P/L EPA 365.1 07/09/2013 08:34 BGN9034 0.005 1 INORGANIC IONS BY IC Chloride 7.6 mg/L EPA 300.0 07/01/2013 15:16JAHERMA 0.5 5 Sulfate 10 mg/L EPA 300.0 07/01/2013 15:16JAHERMA 1 10 TOTAL RECOVERABLE METALS BY ICP Aluminum (Al) 0.790 mg/L EPA 200.7 07/08/2013 10:19 MHH7131 0.05 10 Manganese (Mn) < 0.05 mg/L EPA 200.7 07/08/2013 10:19 MHH7131 0.05 10 Silicon (Si) 7.21 mg/L EPA 200.7 07/08/2013 10:19 MHH7131 0.1 10 Titanium (Ti) 0.072 mg/L EPA 200.7 07/08/2013 10:19 MHH7131 0.05 10 Vanadium (V) < 0.05 mg/L EPA 200.7 07/08/2013 10:19 MHH7131 0.05 10 Miscellaneous Tests by a Vendor Laboratory - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS 94 mg/L SM2540C 07/02/2013 14:14 SWILLI3 25 1 

## 2013014996 Collection Date: 27-Jun-13 9:52 AM 

## Site:Service/ Intake Water 0.3m Matrix: OTHER
Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

## Sample #:

Analyst DF OIL AND GREASE IN WATER - SOLID PHASE EXTRACTION Oil and Grease < 5 mg/L EPA 1664B 06/28/2013 10:15 TJA7067 5 1

# Certificate of Laboratory Analysis This report shall not be reproduced, except in full.



## Order # J13060456

2013014996 Collection Date: 27-Jun-13 9:52 AM 

## Site:Service/ Intake Water 0.3m Matrix: OTHER
Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

## Sample #:

Analyst DF BIOCHEMICAL OXYGEN DEMAND (BOD) - (Analysis Performed by Pace Laboratories) BOD Complete Vendor Method V_PACE AMMONIA (COLORIMETRIC) Ammonia (Colorimetric) 0.038 mg-N/L EPA 350.1 07/08/2013 11:55 BGN9034 0.02 1 NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) < 0.01 mg-N/L EPA 353.2 07/08/2013 11:09 BGN9034 0.01 1 TOTAL KJELDAHL NITROGEN (COLORIMETRIC) Total Kjeldahl Nitrogen (Colorimetric) 0.19 mg-N/L EPA 351.2 07/10/2013 14:03 TLINN 0.15 1 TOTAL PHOSPHORUS (COLORIMETRIC) Total Phosphorus (Colorimetric) 0.006 mg-P/L EPA 365.1 07/09/2013 08:35 BGN9034 0.005 1 INORGANIC IONS BY IC Chloride 7.5 mg/L EPA 300.0 07/01/2013 14:39JAHERMA 0.5 5 Sulfate 9.7 mg/L EPA 300.0 07/01/2013 14:39JAHERMA 0.5 5 TOTAL RECOVERABLE METALS BY ICP Aluminum (Al) 0.031 mg/L EPA 200.7 07/08/2013 10:14MHH7131 0.005 1 Manganese (Mn) 0.011 mg/L EPA 200.7 07/08/2013 10:14MHH7131 0.005 1 Silicon (Si) 5.82 mg/L EPA 200.7 07/08/2013 10:14MHH7131 0.01 1 Titanium (Ti) < 0.005 mg/L EPA 200.7 07/08/2013 10:14MHH7131 0.005 1 Vanadium (V) < 0.005 mg/L EPA 200.7 07/08/2013 10:14MHH7131 0.005 1 Miscellaneous Tests by a Vendor Laboratory - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS 78 mg/L SM2540C 07/02/2013 14:14 SWILLI3 25 1 

## 2013014997 Collection Date: 27-Jun-13 9:15 AM 

## Site:Ash Basin Matrix: OTHER
Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

## Sample #:

Analyst DF SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1

# Certificate of Laboratory Analysis This report shall not be reproduced, except in full.



## Order # J13060456

2013014998 Collection Date: 27-Jun-13 7:50 AM 

## Site:Blank Matrix: OTHER
Analyte Analysis Date/Time Method Units Qualifiers RDL Result 

## Sample #:

Analyst DF TOTAL RECOVERABLE METALS BY ICP Aluminum (Al) < 0.005 mg/L EPA 200.7 07/08/2013 10:10 MHH7131 0.005 1 Manganese (Mn) < 0.005 mg/L EPA 200.7 07/08/2013 10:10 MHH7131 0.005 1 Silicon (Si) 0.057 mg/L EPA 200.7 07/08/2013 10:10 MHH7131 0.01 1 Titanium (Ti) < 0.005 mg/L EPA 200.7 07/08/2013 10:10 MHH7131 0.005 1 Vanadium (V) < 0.005 mg/L EPA 200.7 07/08/2013 10:10 MHH7131 0.005 1#=CL#



## July 05, 2013

LIMS USE: FR - PROGRAM MANAGER LIMS OBJECT ID: 92163334



## 92163334 Project: Pace Project No.: RE: Program Manager Duke Energy

,

313060456
Dear Program Manager: Enclosed are the analytical results for sample(s) received by the laboratory on June 28, 2013. The results relate only to the samples included in this report. Results reported herein conform to the most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. If you have any questions concerning this report, please feel free to contact me. Sincerely,
Tabitha M Dacal for Kevin Herring kevin.herring@pacelabs.com Project Manager

Enclosures

cc:Rodney Wike, Duke Energy



## REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc.

2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A

Eden, NC 27288 (336)623-8921

Page 1 of 11#=CP#



## CERTIFICATIONS
Pace Project No.: Project: 92163334

313060456

Asheville Certification IDs 2225 Riverside Dr., Asheville, NC 28804 Florida/NELAP Certification #: E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 West Virginia Certification #: 356 Virginia/VELAP Certification #: 460222



## REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc.

2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A

Eden, NC 27288 (336)623-8921

Page 2 of 11#=SA#



## SAMPLE ANALYTE COUNT
Pace Project No.: Project: 92163334

313060456

Lab ID Sample ID Method Analytes ReportedLaboratory Analysts 92163334001 2013014995 SM 5210B 1 PASI-A MDW 921633340022013014996 SM 5210B 1 PASI-A MDW



## REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc.

2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A

Eden, NC 27288 (336)623-8921

Page 3 of 11#=NA#



## PROJECT NARRATIVE
Pace Project No.: Project: 92163334

313060456

Method: Client: Duke Energy

SM 5210B
Date: July 05, 2013 Description:5210B BOD, 5 day

General Information: 2 samples were analyzed for SM 5210B. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with with any exceptions noted below.
Method Blank: All analytes were below the report limit in the method blank with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Duplicate Sample: All duplicate sample results were within method acceptance criteria with any exceptions noted below. Additional Comments: This data package has been reviewed for quality and completeness and is approved for release.



## REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc.

2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A

Eden, NC 27288 (336)623-8921

Page 4 of 11#=AR#



## ANALYTICAL RESULTS
Pace Project No.: Project: 92163334

313060456 Sample:2013014995 Lab ID:92163334001Collected:06/27/13 08:00Received:06/28/13 13:30Matrix:Water

Parameters Results Units DF Prepared Analyzed CAS No. Qual Report Limit 5210B BOD, 5 day Analytical Method: SM 5210B BOD, 5 day NDmg/L 07/03/13 17:30 06/28/13 23:20 2.0 1



## REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Date: 07/05/2013 01:35 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc.

2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A

Eden, NC 27288 (336)623-8921

Page 5 of 11#=AR#



## ANALYTICAL RESULTS
Pace Project No.: Project: 92163334

313060456 Sample:2013014996 Lab ID:92163334002Collected:06/27/13 09:52Received:06/28/13 13:30Matrix:Water

Parameters Results Units DF Prepared Analyzed CAS No. Qual Report Limit 5210B BOD, 5 day Analytical Method: SM 5210B BOD, 5 day NDmg/L 07/03/13 17:30 06/28/13 23:20 2.0 1



## REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Date: 07/05/2013 01:35 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc.

2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A

Eden, NC 27288 (336)623-8921

Page 6 of 11#=QC#



## QUALITY CONTROL DATA
Pace Project No.: Project: 92163334

313060456
QC Batch: QC Batch Method: Analysis Method: Analysis Description: WET/26028 SM 5210B SM 5210B 5210B BOD, 5 day Associated Lab Samples:92163334001, 92163334002

Parameter Units Blank Result Reporting

Limit Qualifiers METHOD BLANK:1002335 Associated Lab Samples:92163334001, 92163334002 Matrix:Water
Analyzed BOD, 5 day mg/L ND 2.007/03/13 17:30

Parameter Units LCS Result % Rec Limits Qualifiers % Rec Conc. 1002336 LABORATORY CONTROL SAMPLE: LCS Spike BOD, 5 day mg/L 204 198 103 84.5-115.4

Parameter Units Dup Result Qualifiers

RPD Result 92163289001 1002337 SAMPLE DUPLICATE:
BOD, 5 day mg/L 3040 2 2980



## REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Date: 07/05/2013 01:35 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc.

2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A

Eden, NC 27288 (336)623-8921

Page 7 of 11#=QL#



## QUALIFIERS
Pace Project No.: Project: 92163334

313060456
DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to changes in sample preparation, dilution of the sample aliquot, or moisture content. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL - Adjusted Method Detection Limit. PRL - Pace Reporting Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine (8270 listed analyte) decomposes to Azobenzene. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean-Up U - Indicates the compound was analyzed for, but not detected. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Acid preservation may not be appropriate for 2-Chloroethylvinyl ether, Styrene, and Vinyl chloride. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIESPace Analytical Services - Asheville PASI-A



## REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Date: 07/05/2013 01:35 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc.

2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A

Eden, NC 27288 (336)623-8921

Page 8 of 11#=CR#



## QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.: Project: 92163334

313060456

Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch 92163334001 WET/26028 WET/26029 2013014995 SM 5210B SM 5210B 92163334002 WET/26028 WET/26029 2013014996 SM 5210B SM 5210B



## REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Date: 07/05/2013 01:35 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services, Inc.

2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A

Eden, NC 27288 (336)623-8921

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