13339 Hagers Ferry Road

Huntersville, NC 28078-7929

McGuire Nuclear Complex - MG03A2

Phone: 980-875-5245 Fax: 980-875-4349

Order Summary Report

Analytical Laboratory

Order Number: J13060456

Project Name:

Lab Contact: Jason C Perkins

Date: 7/11/2013

Customer Address: 3195 Pine Hall Rd

Customer Name(s): Josh Quinn

Mailcode: Belews Steam Station

Belews Creek, NC 28012

Phone: 980-875-5348

Report Authorized By:

(Signature)

Program Comments:

Please contact the Program Manager (Jason C Perkins) with any questions regarding this report.

Data Flags & Calculations:

Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality 

system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) 

under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data 

included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the 

subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have 

been qualified by Duke Energy to perform these analyses except where noted.

Data Package:

This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of 

the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except 

in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The 

order of individual sections within this report is as follows:

Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, 

Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports & 

Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)

Certification:

The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina 

(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of 

specific methods. 

Jason C Perkins

Page 1 of 25
Sample ID's & Descriptions:

Sample ID Plant/Station

Collection 

Date and Time Collected By Sample Description

2013014995 BELEWS 27-Jun-13 8:00 AM David Horne Bottom Ash Sluice 0.3m

2013014996 BELEWS 27-Jun-13 9:52 AM David Horne Service/ Intake Water 0.3m

2013014997 BELEWS 27-Jun-13 9:15 AM David Horne Ash Basin

2013014998 BELEWS 27-Jun-13 7:50 AM David Horne Blank

4 Total Samples

Page 2 of 25
COC and .pdf report are in agreement with sample totals 

and analyses (compliance programs and procedures).

All Results are less than the laboratory reporting limits.

All laboratory QA/QC requirements are acceptable.

Yes No

Technical Validation Review

Checklist:

Yes No

Yes No

Report Sections Included:

Job Summary Report Sub-contracted Laboratory Results

Sample Identification Customer Specific Data Sheets, Reports, & Documentation

Technical Validation of Data Package Customer Database Entries

Analytical Laboratory Certificate of Analysis

Analytical Laboratory QC Report

Chain of Custody

Reviewed By: DBA Account Date: 7/11/2013

Electronic Data Deliverable (EDD) Sent Separately

Page 3 of 25
Certificate of Laboratory Analysis

This report shall not be reproduced, except in full.

Order # J13060456

2013014995

Collection Date: 27-Jun-13 8:00 AM

Site: Bottom Ash Sluice 0.3m

Matrix: OTHER

Analyte Result Units Qualifiers RDL Method Analysis Date/Time

Sample #:

DF Analyst

OIL AND GREASE IN WATER - SOLID PHASE EXTRACTION

Oil and Grease < 5 mg/L 5 1 EPA 1664B 06/28/2013 10:15 TJA7067

BIOCHEMICAL OXYGEN DEMAND (BOD) - (Analysis Performed by Pace Laboratories)

BOD Complete Vendor Method V_PACE

AMMONIA (COLORIMETRIC)

Ammonia (Colorimetric) 0.037 mg-N/L 0.02 1 EPA 350.1 07/08/2013 11:54 BGN9034

NITRITE + NITRATE (COLORIMETRIC)

Nitrite + Nitrate (Colorimetric) < 0.01 mg-N/L 0.01 1 EPA 353.2 07/08/2013 11:08 BGN9034

TOTAL KJELDAHL NITROGEN (COLORIMETRIC)

Total Kjeldahl Nitrogen 

(Colorimetric)

0.20 mg-N/L 0.15 1 EPA 351.2 07/10/2013 14:02 TLINN

TOTAL PHOSPHORUS (COLORIMETRIC)

Total Phosphorus (Colorimetric) 0.035 mg-P/L 0.005 1 EPA 365.1 07/09/2013 08:34 BGN9034

INORGANIC IONS BY IC

Chloride 7.6 mg/L 0.5 5 EPA 300.0 07/01/2013 15:16 JAHERMA

Sulfate 10 mg/L 1 10 EPA 300.0 07/01/2013 15:16 JAHERMA

TOTAL RECOVERABLE METALS BY ICP

Aluminum (Al) 0.790 mg/L 0.05 10 EPA 200.7 07/08/2013 10:19 MHH7131

Manganese (Mn) < 0.05 mg/L 0.05 10 EPA 200.7 07/08/2013 10:19 MHH7131

Silicon (Si) 7.21 mg/L 0.1 10 EPA 200.7 07/08/2013 10:19 MHH7131

Titanium (Ti) 0.072 mg/L 0.05 10 EPA 200.7 07/08/2013 10:19 MHH7131

Vanadium (V) < 0.05 mg/L 0.05 10 EPA 200.7 07/08/2013 10:19 MHH7131

Miscellaneous Tests by a Vendor Laboratory - (Analysis Performed by Element One)

Vendor Parameter Complete Vendor Method V_ELE1

SULFIDE - (Analysis Performed by Element One)

Vendor Parameter Complete Vendor Method V_ELE1

TOTAL DISSOLVED SOLIDS

TDS 94 mg/L 25 1 SM2540C 07/02/2013 14:14 SWILLI3

2013014996

Collection Date: 27-Jun-13 9:52 AM

Site: Service/ Intake Water 0.3m

Matrix: OTHER

Analyte Result Units Qualifiers RDL Method Analysis Date/Time

Sample #:

DF Analyst

OIL AND GREASE IN WATER - SOLID PHASE EXTRACTION

Oil and Grease < 5 mg/L 5 1 EPA 1664B 06/28/2013 10:15 TJA7067

Page 4 of 25
Certificate of Laboratory Analysis

This report shall not be reproduced, except in full.

Order # J13060456

2013014996

Collection Date: 27-Jun-13 9:52 AM

Site: Service/ Intake Water 0.3m

Matrix: OTHER

Analyte Result Units Qualifiers RDL Method Analysis Date/Time

Sample #:

DF Analyst

BIOCHEMICAL OXYGEN DEMAND (BOD) - (Analysis Performed by Pace Laboratories)

BOD Complete Vendor Method V_PACE

AMMONIA (COLORIMETRIC)

Ammonia (Colorimetric) 0.038 mg-N/L 0.02 1 EPA 350.1 07/08/2013 11:55 BGN9034

NITRITE + NITRATE (COLORIMETRIC)

Nitrite + Nitrate (Colorimetric) < 0.01 mg-N/L 0.01 1 EPA 353.2 07/08/2013 11:09 BGN9034

TOTAL KJELDAHL NITROGEN (COLORIMETRIC)

Total Kjeldahl Nitrogen 

(Colorimetric)

0.19 mg-N/L 0.15 1 EPA 351.2 07/10/2013 14:03 TLINN

TOTAL PHOSPHORUS (COLORIMETRIC)

Total Phosphorus (Colorimetric) 0.006 mg-P/L 0.005 1 EPA 365.1 07/09/2013 08:35 BGN9034

INORGANIC IONS BY IC

Chloride 7.5 mg/L 0.5 5 EPA 300.0 07/01/2013 14:39 JAHERMA

Sulfate 9.7 mg/L 0.5 5 EPA 300.0 07/01/2013 14:39 JAHERMA

TOTAL RECOVERABLE METALS BY ICP

Aluminum (Al) 0.031 mg/L 0.005 1 EPA 200.7 07/08/2013 10:14 MHH7131

Manganese (Mn) 0.011 mg/L 0.005 1 EPA 200.7 07/08/2013 10:14 MHH7131

Silicon (Si) 5.82 mg/L 0.01 1 EPA 200.7 07/08/2013 10:14 MHH7131

Titanium (Ti) < 0.005 mg/L 0.005 1 EPA 200.7 07/08/2013 10:14 MHH7131

Vanadium (V) < 0.005 mg/L 0.005 1 EPA 200.7 07/08/2013 10:14 MHH7131

Miscellaneous Tests by a Vendor Laboratory - (Analysis Performed by Element One)

Vendor Parameter Complete Vendor Method V_ELE1

SULFIDE - (Analysis Performed by Element One)

Vendor Parameter Complete Vendor Method V_ELE1

TOTAL DISSOLVED SOLIDS

TDS 78 mg/L 25 1 SM2540C 07/02/2013 14:14 SWILLI3

2013014997

Collection Date: 27-Jun-13 9:15 AM

Site: Ash Basin

Matrix: OTHER

Analyte Result Units Qualifiers RDL Method Analysis Date/Time

Sample #:

DF Analyst

SULFIDE - (Analysis Performed by Element One)

Vendor Parameter Complete Vendor Method V_ELE1

Page 5 of 25
Certificate of Laboratory Analysis

This report shall not be reproduced, except in full.

Order # J13060456

2013014998

Collection Date: 27-Jun-13 7:50 AM

Site: Blank

Matrix: OTHER

Analyte Result Units Qualifiers RDL Method Analysis Date/Time

Sample #:

DF Analyst

TOTAL RECOVERABLE METALS BY ICP

Aluminum (Al) < 0.005 mg/L 0.005 1 EPA 200.7 07/08/2013 10:10 MHH7131

Manganese (Mn) < 0.005 mg/L 0.005 1 EPA 200.7 07/08/2013 10:10 MHH7131

Silicon (Si) 0.057 mg/L 0.01 1 EPA 200.7 07/08/2013 10:10 MHH7131

Titanium (Ti) < 0.005 mg/L 0.005 1 EPA 200.7 07/08/2013 10:10 MHH7131

Vanadium (V) < 0.005 mg/L 0.005 1 EPA 200.7 07/08/2013 10:10 MHH7131

Page 6 of 25
#=CL#

July 05, 2013

LIMS USE: FR - PROGRAM MANAGER

LIMS OBJECT ID: 92163334

92163334

Project:

Pace Project No.:

RE:

Program Manager

Duke Energy

,

313060456

Dear Program Manager:

Enclosed are the analytical results for sample(s) received by the laboratory on June 28, 2013. The

results relate only to the samples included in this report. Results reported herein conform to the

most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless

otherwise noted in the body of the report.

Analyses were performed at the Pace Analytical Services location indicated on the sample analyte

page for analysis unless otherwise footnoted.

If you have any questions concerning this report, please feel free to contact me.

Sincerely,

Tabitha M Dacal for

Kevin Herring

kevin.herring@pacelabs.com

Project Manager

Enclosures

cc: Rodney Wike, Duke Energy

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full,

without the written consent of Pace Analytical Services, Inc..

Pace Analytical Services, Inc.

9800 Kincey Ave. Suite 100

Huntersville, NC 28078

(704)875-9092

Pace Analytical Services, Inc.

2225 Riverside Dr.

Asheville, NC 28804

(828)254-7176

Pace Analytical Services, Inc.

205 East Meadow Road - Suite A

Eden, NC 27288

(336)623-8921

Page 1 of 11

Page 7 of 25
#=CP#

CERTIFICATIONS

Pace Project No.:

Project:

92163334

313060456

Asheville Certification IDs

2225 Riverside Dr., Asheville, NC 28804

Florida/NELAP Certification #: E87648

Massachusetts Certification #: M-NC030

North Carolina Drinking Water Certification #: 37712

North Carolina Wastewater Certification #: 40

South Carolina Certification #: 99030001

West Virginia Certification #: 356

Virginia/VELAP Certification #: 460222

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full,

without the written consent of Pace Analytical Services, Inc..

Pace Analytical Services, Inc.

9800 Kincey Ave. Suite 100

Huntersville, NC 28078

(704)875-9092

Pace Analytical Services, Inc.

2225 Riverside Dr.

Asheville, NC 28804

(828)254-7176

Pace Analytical Services, Inc.

205 East Meadow Road - Suite A

Eden, NC 27288

(336)623-8921

Page 2 of 11

Page 8 of 25
#=SA#

SAMPLE ANALYTE COUNT

Pace Project No.:

Project:

92163334

313060456

Lab ID Sample ID Method

Analytes

Analysts Reported Laboratory

92163334001 2013014995 SM 5210B MDW 1 PASI-A

92163334002 2013014996 SM 5210B MDW 1 PASI-A

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full,

without the written consent of Pace Analytical Services, Inc..

Pace Analytical Services, Inc.

9800 Kincey Ave. Suite 100

Huntersville, NC 28078

(704)875-9092

Pace Analytical Services, Inc.

2225 Riverside Dr.

Asheville, NC 28804

(828)254-7176

Pace Analytical Services, Inc.

205 East Meadow Road - Suite A

Eden, NC 27288

(336)623-8921

Page 3 of 11

Page 9 of 25
#=NA#

PROJECT NARRATIVE

Pace Project No.:

Project:

92163334

313060456

Method:

Client: Duke Energy

SM 5210B

Date: July 05, 2013

Description: 5210B BOD, 5 day

General Information:

2 samples were analyzed for SM 5210B. All samples were received in acceptable condition with any exceptions noted below.

Hold Time:

The samples were analyzed within the method required hold times with any exceptions noted below.

Sample Preparation:

The samples were prepared in accordance with with any exceptions noted below.

Method Blank:

All analytes were below the report limit in the method blank with any exceptions noted below.

Laboratory Control Spike:

All laboratory control spike compounds were within QC limits with any exceptions noted below.

Matrix Spikes:

All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.

Duplicate Sample:

All duplicate sample results were within method acceptance criteria with any exceptions noted below.

Additional Comments:

This data package has been reviewed for quality and completeness and is approved for release.

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full,

without the written consent of Pace Analytical Services, Inc..

Pace Analytical Services, Inc.

9800 Kincey Ave. Suite 100

Huntersville, NC 28078

(704)875-9092

Pace Analytical Services, Inc.

2225 Riverside Dr.

Asheville, NC 28804

(828)254-7176

Pace Analytical Services, Inc.

205 East Meadow Road - Suite A

Eden, NC 27288

(336)623-8921

Page 4 of 11

Page 10 of 25
#=AR#

ANALYTICAL RESULTS

Pace Project No.:

Project:

92163334

313060456

Sample: 2013014995 Lab ID: 92163334001 Collected: 06/27/13 08:00 Received: 06/28/13 13:30 Matrix: Water

Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual

5210B BOD, 5 day Analytical Method: SM 5210B

BOD, 5 day ND mg/L 2.0 1 06/28/13 23:20 07/03/13 17:30

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full,

Date: 07/05/2013 01:35 PM without the written consent of Pace Analytical Services, Inc..

Pace Analytical Services, Inc.

9800 Kincey Ave. Suite 100

Huntersville, NC 28078

(704)875-9092

Pace Analytical Services, Inc.

2225 Riverside Dr.

Asheville, NC 28804

(828)254-7176

Pace Analytical Services, Inc.

205 East Meadow Road - Suite A

Eden, NC 27288

(336)623-8921

Page 5 of 11

Page 11 of 25
#=AR#

ANALYTICAL RESULTS

Pace Project No.:

Project:

92163334

313060456

Sample: 2013014996 Lab ID: 92163334002 Collected: 06/27/13 09:52 Received: 06/28/13 13:30 Matrix: Water

Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual

5210B BOD, 5 day Analytical Method: SM 5210B

BOD, 5 day ND mg/L 2.0 1 06/28/13 23:20 07/03/13 17:30

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full,

Date: 07/05/2013 01:35 PM without the written consent of Pace Analytical Services, Inc..

Pace Analytical Services, Inc.

9800 Kincey Ave. Suite 100

Huntersville, NC 28078

(704)875-9092

Pace Analytical Services, Inc.

2225 Riverside Dr.

Asheville, NC 28804

(828)254-7176

Pace Analytical Services, Inc.

205 East Meadow Road - Suite A

Eden, NC 27288

(336)623-8921

Page 6 of 11

Page 12 of 25
#=QC#

QUALITY CONTROL DATA

Pace Project No.:

Project:

92163334

313060456

QC Batch:

QC Batch Method:

Analysis Method:

Analysis Description:

WET/26028

SM 5210B

SM 5210B

5210B BOD, 5 day

Associated Lab Samples: 92163334001, 92163334002

Parameter Units

Blank

Result

Reporting

Limit Qualifiers

METHOD BLANK: 1002335

Associated Lab Samples: 92163334001, 92163334002

Matrix: Water

Analyzed

BOD, 5 day mg/L ND 2.0 07/03/13 17:30

Parameter Units

LCS

Result

% Rec

Conc. % Rec Limits Qualifiers

LABORATORY CONTROL SAMPLE: 1002336

Spike LCS

BOD, 5 day mg/L 198 204 103 84.5-115.4

Parameter Units

Dup

Result Result RPD Qualifiers

92163289001

SAMPLE DUPLICATE: 1002337

BOD, 5 day mg/L 2980 3040 2

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full,

Date: 07/05/2013 01:35 PM without the written consent of Pace Analytical Services, Inc..

Pace Analytical Services, Inc.

9800 Kincey Ave. Suite 100

Huntersville, NC 28078

(704)875-9092

Pace Analytical Services, Inc.

2225 Riverside Dr.

Asheville, NC 28804

(828)254-7176

Pace Analytical Services, Inc.

205 East Meadow Road - Suite A

Eden, NC 27288

(336)623-8921

Page 7 of 11

Page 13 of 25
#=QL#

QUALIFIERS

Pace Project No.:

Project:

92163334

313060456

DEFINITIONS

DF - Dilution Factor, if reported, represents the factor applied to the reported data due to changes in sample preparation, dilution of

the sample aliquot, or moisture content.

ND - Not Detected at or above adjusted reporting limit.

J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.

MDL - Adjusted Method Detection Limit.

PRL - Pace Reporting Limit.

RL - Reporting Limit.

S - Surrogate

1,2-Diphenylhydrazine (8270 listed analyte) decomposes to Azobenzene.

Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.

LCS(D) - Laboratory Control Sample (Duplicate)

MS(D) - Matrix Spike (Duplicate)

DUP - Sample Duplicate

RPD - Relative Percent Difference

NC - Not Calculable.

SG - Silica Gel - Clean-Up

U - Indicates the compound was analyzed for, but not detected.

N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for

each analyte is a combined concentration.

Acid preservation may not be appropriate for 2-Chloroethylvinyl ether, Styrene, and Vinyl chloride.

Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.

TNI - The NELAC Institute.

LABORATORIES

PASI-A Pace Analytical Services - Asheville

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full,

Date: 07/05/2013 01:35 PM without the written consent of Pace Analytical Services, Inc..

Pace Analytical Services, Inc.

9800 Kincey Ave. Suite 100

Huntersville, NC 28078

(704)875-9092

Pace Analytical Services, Inc.

2225 Riverside Dr.

Asheville, NC 28804

(828)254-7176

Pace Analytical Services, Inc.

205 East Meadow Road - Suite A

Eden, NC 27288

(336)623-8921

Page 8 of 11

Page 14 of 25
#=CR#

QUALITY CONTROL DATA CROSS REFERENCE TABLE

Pace Project No.:

Project:

92163334

313060456

Lab ID Sample ID QC Batch Method QC Batch Analytical Method

Analytical

Batch

92163334001 2013014995 SM 5210B WET/26028 SM 5210B WET/26029

92163334002 2013014996 SM 5210B WET/26028 SM 5210B WET/26029

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full,

Date: 07/05/2013 01:35 PM without the written consent of Pace Analytical Services, Inc..

Pace Analytical Services, Inc.

9800 Kincey Ave. Suite 100

Huntersville, NC 28078

(704)875-9092

Pace Analytical Services, Inc.

2225 Riverside Dr.

Asheville, NC 28804

(828)254-7176

Pace Analytical Services, Inc.

205 East Meadow Road - Suite A

Eden, NC 27288

(336)623-8921

Page 9 of 11

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