Ve rsion 2011.0.3 Prices subject to change. Visit www.energylab.com for up

- to

- date pricing. www.energylab.com 

### Waters - 1 

# WATER List of Acronyms

E200.7 Inductively Coupled Plasma (ICP

- Analytical Method) MDL Method Detection Limit

E200.8 Inductively Coupled Plasma

- Mass Spectrometry (ICP

- MS

- Analytical Method) NaOH Sodium Hydroxide

E200.9 Stabilized Temperature Graphite Atomic Absorption Spectroscopy (STGFAA

- Analytical Method) NPDES National Pollutant Discharge Elimination System

A Standard Methods NR Not Regulated

ASTM American Society for Testing & Materials NTU Nephelometric Turbidity Units

BOD Biochemical Oxygen Demand OH Hydroxide

CaCO 3 

### Calcium Carbonate PCBs Polychlorinated Biphenyls

CO 3 

### Carbonate pCi/L Picocuries per Liter

COD Chemical Oxygen Demand ppb parts per billion

DBCP 1, 2

- Dibromo

- 3

- chloropropane ppm parts per million

DOC Dissolved Organic Carbon PQLs Practical Quantitation Limits If the sample is contaminated, i t may require dilution prior to analysis. The PQL of diluted samples will be correspondingly higher.

EDB Dibromoethane PVC Polyvinyl Chloride

E or EPA US Environmental Protection Agency TDS Total Dissolved Solids

GC/FID Gas Chromatograph /Flame Ionization Detector TKN Total Kjeldahl Nitrogen

H 2 

### SO 4 

### Sulfuric Acid TOC Total Organic Carbon

HCI Hydrochloric Acid TOX Total Organic Halogens

HCO 3 

### Bicarbonate TPH Total Petroleum Hydrocarbons

HNO 3 

### Nitric Acid TSS Total Suspen ded Solids

ICP Inductively Coupled Plasma VOA Volatile Organic Analysis

ICP

- MS Inductively Coupled Plasma

- Mass Spectrophotometer VOCs Volatile Organic Chemicals

MCL Maximum Contaminant Level VSS Volatile Suspended Solids

MCLG Maxi mum Contamination Level Goals WAD Weak Acid Dissociable

The analytical methods listed above are typically referenced for drinking water and clean water regulations.Ve rsion 2011.0.3 Prices subject to change. Visit www.energylab.com for up

- to

- date pricing. www.energylab.com 

### Waters - 2 

# WATER

METALS METHOD REPORTING LIMIT UNIT PRICE

Total Metals Digestion E200.2

- - $15.00

Filtering or preserving samples on receipt at the laboratory, as appropriate

- per fraction 20.00

Aluminum E200.7/E200.8 0.1 mg/L 10.00

Aluminum, low level E200.7/E200.8 0.05 mg/L 25.00

Antimony E200.7/E200.8 0.005 mg/L 10.00

Antimony, low level E200. 8 0.001 mg/L 25.00

Arsenic E200.8/A3114B 0.005 mg/L 10.00

Arsenic, low level E200.8/A3114B 0.001 mg/L 25.00

Arsenic, III & V speciation E1632A Mod. 0.005 mg/L 50.00

Barium E200.7/E200.8 0.1 mg/L 10.00

Barium, low level E200.7/E200.8 0.005 mg/L 25.00

Beryllium E200.7/E200.8 0.001 mg/L 10.00

Bismuth E200.7/E200.8 0.01 mg/L 10.00

Boron E200.7/E200.8 0.1 mg/L 10.00

Cadmium E200.7/E200.8 0.001 mg/L 10.00

Cadmium, low level E200.7/E200.8 0.0001 mg/L 25.00

Calcium E200.7/E200.8 1 mg/L 10.00

Chromium E2 00.7/E200.8 0.01 mg/L 10.00

Chromium, low level E200.7/E200.8 0.001 mg/L 25.00
Chromium, Hexavalent (Cr +6 

### ) A 3500 Cr B/D 0.01 mg/L 50.00

Cobalt E200.7/E200.8 0.01 mg/L 10.00

Copper E200.7/E200.8 0.01 mg/L 10.00

Copper, low level E200.7/E200.8 0.001 mg /L 25.00

Gallium E200.8 0.01 mg/L 25.00

Gold E200.7/E200.8 0.01 mg/L 25.00

Iron E200.7/E200.8 0.03 mg/L 10.00

Iron, low level E200.7/E200.8 0.005 mg/L 25.00

Iron, Ferrous (Fe II) E200.7 0.1 mg/L 10.00Ve rsion 2011.0.3 Prices subject to change. Visit www.energylab.com for up

- to

- date pricing. www.energylab.com 

### Waters - 3 

# WATER

METALS METHOD REPORTING LIMIT UNIT PRIC E

Total Metals Digestion E200.2

- - $15.00

Filtering or preserving samples on receipt at the laboratory, as appropriate

- per fraction 20.00

Iron, Ferric (Fe III) Calculated from Iron and Iron, Ferrous

Lead E200.7/E200.8 0.01 mg/L 10.00

Lead, low leve l E200.8 0.002 mg/L 25.00

Lithium E200.8 0.1 mg/L 10.00

Magnesium E200.7/E200.8 1 mg/L 10.00

Manganese E200.7/E200.8 0.01 mg/L 10.00

Manganese, low level E200.7/E200.8 0.005 mg/L 25.00

Mercury E245.2/E245.1/E200.8/ A3112 B Mod. 0.001 mg/L 10.00

Mercur y, low level E245.2/E245.1/E200.8/A 3112B Mod. 0.0001 mg/L 25.00

Mercury, ultra low level E245.7 0.000005 mg/L 50.00

For Ultra low

- level mercury by method 245.7, both a trip blank and field blank are required for each set of samples. Both the trip blank and field blank will be analyzed and charged at $50 each. 

### Molybdenum E200.7/E200.8 0.005 mg/L 10.00

Nickel E200.7/E200.8 0.01 mg/L 10.00

Nickel, low level E200.8 0.005 mg/L 25.00

Potassium E200.7/E200.8 1 mg/L 10.00

Rubidium E200.8 0.01 mg/L 25.00

Se lenium E200.7/E200.8/A 3114B 0.005 mg/L 10.00

Selenium, low level E200.8/A 3114 B 0.001 mg/L 25.00

Selenium, IV & VI speciation A 3114 B Mod. 0.005 mg/L 50.00

Silicon E200.7/E200.8 0.1 mg/L 10.00

Silver E200.7/E200.8 0.005 mg/L 10.00

Silver, low level E200.7/E200.8 0.0005 mg/L 25.00

Sodium E200.7/E200.8 1 mg/L 10.00

Strontium E200.7/E200.8 0.1 mg/L 10.00

Strontium, low level E200.7/E200.8 0.005 mg/L 25.00

Tellurium E200.7/E200.8 0.1 mg/L 25.00Ve rsion 2011.0.3 Prices subject to change. Visit www.energylab.com for up

- to

- date pricing. www.energylab.com 

### Waters - 4 

# WATER

METALS METHOD REPORTING LIMIT UNIT PRICE

To tal Metals Digestion E200.2

- - $15.00
Filtering or preserving samples on receipt at the laboratory, as appropriate

- per fraction 20.00

Thallium E200.7/E200.8 0.005 mg/L 10.00

Thallium, low level E200.7/E200.8 0.001 mg/L 25.00

Tin E200.7/E200.8 0.1 mg /L 10.00

Titanium E200.7/E200.8 0.01 mg/L 10.00
Tungsten E200.7/E200.8 0.1 mg/L 10.00

Uranium

- fluorescence E908.0 0.2 pCi/L 25.00

Uranium

- ICP MS E200.8 0.0003 mg/L 25.00

Vanadium E200.7/E200.8 0.1 mg/L 10.00

Vanadium, low level E200.7/E200.8 0.01 mg/ L 25.00

Zinc E200.7/E200.8 0.01 mg/L 10.00

Zinc, low level E200.7/E200.8 0.001 mg/L 25.00

Zirconium E200.7/E200.8 0.005 mg/L 25.00

NON

- METALS METHOD REPORTING LIMIT UNIT PRICE

Acidity, Total as CaCO 3 

### A2310B 1 mg/L $15.00 Alkalinity, total as CaCO 3 

### , includes bicarbonate as HCO 3 

### , Carbonate as CO 3 

### , and hydroxide as OH A 2320 B 1 mg/L 10.00

Ammonia (see Nitrogen, Ammonia) - - - -

Asbestos E600/4/80

- 005 (TEM) 1 mf/L(million fibers/liter) by Quote

Biochemical Oxygen Demand (BOD) A5210B 2 mg/L 50.00

Bi ochemical Oxygen Demand, Carbonaceous A5210 B mg/L 50.00

Bromate E300.0 0.005 mg/L by Quote

Bromide E300.0 0.5 mg/L 10.00
Chemical Oxygen Demand (COD) E410.4 1 mg/L 25.00

Chloride E300.0/A 4500 CL B 1 mg/L 10.00

Chlorine, Residual A4500CL2

- G /E330.5 Mod. 0.1 mg/L 25.00

Chlorophyll a A 10200 H 0.1 mg/m 3 

### 65.00

Color A 2120 B 0 Color Units 30.00
Conductance, Specific @ 25 ° C E120.1/A 2510 B 1 μ mhos/cm 10.00Ve rsion 2011.0.3 Prices subject to change. Visit www.energylab.com for up

- to

- date pricing. www.energylab.com 

### Waters - 5 

# WATER

NON

- METALS, continued METHOD REPORTING LIMIT UNIT PRICE

Corrosivity (Ca, Alkalinity, pH, TDS) Calculation

- - $40.00

Cyanates A 4500 CN L 0.1 mg/L 50.00 Cyanide, Amenable to Chlorination A4500

- CN

- G 0.005 mg/L 50.00

Cyanide, Free (Electrode) A 4500 CN F/ Electrode Manufacturer 0.2 mg/L 50.00

Cyanide, Total Kelada mod / E335.4 0.005 mg/L 50.00
Cyanide, Weak Acid Dissociable ASTM D2036 0.005 mg/L 50.00
Cyanide, Thiocyanate as N A 4500 CN M. 0.2 mg/L 50.00
Ethylene Glycol ASTM D2982 Mod. 10 mg/L 50.00

Fluoride, Electrode A 4500 F

- C/ Technicon 380

- 7WE 0.1 mg/L 15.00

Foaming Agents A5540 C 1 mg/L 15.00
Foaming Agents, low level A5540C 0.1 Mg/L 70.00
Formaldehyde NIOSH 3500 Mod. 0.25 mg/L 60.00
Hardness, Total as CaCO 3 

### A 2340 B 1 mg/L 20.00

Iodide E300.0 0.1 mg/L 60.00

Methane, ethane, ethene GC

- FID/ Kampbell (SW 8015 Mod.) 0.0002 mg/L 50.00

Nitrogen: Ammonia as N A 4500 NH 3 

### H 0.05 mg/L 15.00
Nitrogen: Nitrate plus Nitrite as N E353.2 0.01 mg/L 20.00
Nitrogen: Nitrate as N E353.2/E300.0 0.05 mg/L 30.00
Nitrogen: Nitrate as N, low level E353.2 0.01 mg/L 50.00
Nitrogen: Nitrite as N E353.2/E300.0/A 4500 NO 2 

### B 0.05 mg/L 20.00
Nitrogen: Nitrite as N, low level E353.2/A 4500 NO 2 

### B 0.01 mg/L 25.00
Nitrogen: Total Kjeldahl as N A 4500 N org 0.5 mg/L 25.00
Nitrogen, Total Total Nitrogen = Nitrate plus Nitrite as N + Total Kjeldahl Nitrog en Nitrogen, Total (persulfate

- includes TKN, NO 3 

### , and NO 2 

### ) A 4500 N org. D 0.03 mg/L 40.00

Nitrogen, Organic Organic Nitrogen = Total Kjeldahl Nitrogen

- Ammonia Nitrogen

Odor A 2150B Present/Absent 30.00 Oil & Grease, Gravimetric

- Freon extractable E4 13.1 1 mg/L 75.00

Oil and Grease, IR E413.2 0.1 mg/L 75.00 Oil & Grease, Gravimetric

- Hexane extractable E1664A / A 5520 B 1 mg/L 75.00

Oil & Grease Sulfur corrected w/Copper E1664

- Cu 5 mg/L 100.00Ve rsion 2011.0.3 Prices subject to change. Visit www.energylab.com for up

- to

- date pricing. www.energylab.com 

### Waters - 6 

# WATER

NON

- METALS, continued METHOD REPORTING LIMIT UNIT PRICE

Organic Carbon, Total (TOC) E415.x 1 mg/L $25.00 Organic Carbon, Total (TOC), low level, public water E415.2/A 5310 C 0.5 mg/L 40.00
Organic Carbon, Dissolved (DOC) E415.2/A 5310 C 2 mg/L 35.00

pH E150.2/A 4500 H B 0.1 s.u. 10.00

Oxidation

- Reduction Potential A 2580 1 mV 25.00

Phenolics, Total E420.4 0.01 mg/L 50.00
Phenolics, Total (distillation) E420.1 0.01 mg/L 120.00

Phosphorus, Hydrolyzable E365.1 0.01 mg/L 100 .00
Phosphorus, Ortho E365.1 0.01 mg/L 15.00
Phosphorus, Ortho, low leve l E365.1 0.003 mg/L 25.00
Phosphorus, Total Organic E365.1 0.01 mg/L 25.00
Phosphorus, Total E365.1 0.01 mg/L 15.00
Phosphorus, Total, low level E365.1 0.005 mg/L 25.00 Residue, Non

- Filterable Total Suspended Solids (TSS) A2540D 10 mg/L 15.00

Residue , Total A2540B 10 mg/L 10.00
Residue, Total Filtered Total Dissolved Solids (TDS) A 2540 C 10 mg/L 15.00

Residue, Volatile Volatile Suspended Solids (VSS) @ 550° E160.4 10 mg/L 20.00

Residue, Settleable Matter E160.5 0.5 mL/L 10.00

Resistivity E120.1 0.046 ohm

meters 10.00

Silica E200.7 0.1 mg/L 10.00
Specific Gravity A 2710 F unitless 10.00

Sulfate E300.0 1 mg/L 10.00
Sulfide, Iodine Titrimetric 4500

- S2

- F 1 mg/L 35.00 Sulfide, Methylene Blue Colorimetric 4500

- S2

- D 0.04 mg/L 50.00

Sulfite 4500

- S2

- B 2 mg/L 30.00

Surfactants (MBAS, Foaming Agents) A5540C or LaMotte DS

- 1 1 mg/L 10.00

Surfactants, low level (MBAS, Foaming Agents) A5540C 0.1 mg/L 50.00

Tannins and Lignins A 5550 0.1 mg/L 40.00
Total Petroleum Hydrocarbons E418.1 0.1 mg/L $60.00 Total Petroleum Hydrocarbons by TCEQ (Texas only) 1005 1 mg/L 60.00Ve rsion 2011.0.3 Prices subject to change. Visit www.energylab.com for up

- to

- date pricing. www.energylab.com 

### Waters - 7 

# WATER

NON

- METALS, continued METHOD REPORTING LIMIT UNIT PRICE

Total Organic Halogens (TOX) SW 9020B 0.01 mg/L 90.00

TPH, Gravimetric

- Hexane extractable E1664A / A 5520 B 1 mg/L 75.0 0

TPH, Sulfur corrected w/Copper E1664

- Cu 5 mg/L 100.00

Turbidity E180.1 / A2130B 0.01 NTU 10.00

RADIOCHEMISTRY METHOD REPORTING LIMIT (1) 

### UNIT PRICE

Gamma Emitting Radionuclides E901.1

- pCi/L $75.00

Gross Alpha Radioactivity E900.0 1.0 pCi/L 50.00

Gross Beta Radioactivity E900.0 2.0 pCi/L 50.00

Gross Alpha and Beta E900.0 1.0/2.0 pCi/L 75.00 Gross Radium Alpha (minus Radon & Uranium) 

### 00

- 02 1.0 pCi/L 50.00

210 

### Lead E905.0 Mod. 1.0 pCi/L 75.00

210 

### Polonium RMO

- 3008 1.0 pCi/L 75.00

226 

### Radium (Al pha Emitting Isotopes) E903.0 0.2 pCi/L 75.00

228 

### Radium RA

- 05 1.0 pCi/L 75.00

222 

### Radon ASTM D5072

- 92 100 pCi/L 50.00

Radioactive Strontium E905.0 10 pCi/L 100.00
Isotopic Thorium ( 228 

### Th, 230 

### Th, 232 

### Th) E907.0 0.2 pCi/L 100.00

230 

### Thorium E907.0 0.2 p Ci/L 75.00

Tritium E906.9 1200 pCi/L 75.00
Isotopic Uranium ( 234 

### U, 235 

### U, 238 

### U) E907.0 0.2 pCi/L 100.00

Uranium by fluorescence E908.0 0.2 pCi/L 25.00

Uranium by ICP

- MS E200.8 0.0003 mg/L 10.00

NOTES: (1) Some reporting limits are dependant on sample size.Ve rsion 2011.0.3 Prices subject to change. Visit www.energylab.com for up

- to

- date pricing. www.energylab.com 

### Waters - 8 

# WATER

BACTERIA METHOD REPORTING LIMIT UNIT PRICE

E. Coli 9223B 1 MPN/100ml $20.00

E. Coli, membrane filtration E1603 1 CFU/100mL 50.00

Fecal Coliforms, membrane filtration A 9222 D 1 CFU/100mL 50.00
Fecal Coliforms, sludge, membrane filtration A 9222 D 1 CFU/g 50.00

Fecal Coliforms, sludge A 9221 E 1 MPN/g 150.00

Fecal Coliforms, water A 9221 E 1 MPN/g 100.00

Enterococci Enterolert 1 MPN/100ml 50.00

Enterococci, membrane filtration E1600 1 CFU/100mL 50.00

Total Coliforms, present/absent A 9223 B 1 P/A 20.00 Total Coliforms, present/absent (Pools & Spas) A 9221 D 1 P/A 20.00

Total Coliform/E.Coli A9223B Colilert Quantitray 1 MPN/100ml 50.00
Total Coliforms (count), membrane filtration A 9222 B 1 CFU/100mL 50.00

Heterotrophic Plate Count A 9215 B 1 MPN/mL 50.00

Sulfate Reducing Bacteria 28 day indicating ampule 1 CFU/mL 50.00

Iron Bacteria A 9240 B/ Biological Activity Reaction Test (BART) 1 CFU/mL 50.00

NOTE: Weekend and holiday rate by quoteVe rsion 2011.0.3 Prices subject to change. Visit www.energylab.com for up

- to

- date pricing. www.energylab.com 

### Waters - 9 

# WATER
PARAMETER GROUPINGS

1. DOMESTIC WATER ANALYSIS

Parameter Suitability Tolerances, mg/L Parameter Suitability Tolerances, mg/L

Potassium

- Total Dissolved Solids 1500

Sodium 250 Alkalinity

-
Calcium

- Conductivity

- Magnesium

- pH 6.50

- 8.50 s.u.

Sulfate 250 Nitrate + Nitrite as N 10. 0

Chloride 250

- -
Hardness See Notes

- - Sampling: 1

- 1

- liter plastic bottle, unpreserved. Store at 6°C.
Holding Time: Various

- refer to Sampling and Preservation table located in the back of this section

Note: Irrigation Classification and Livestock Suitability available with this analysis at no additional charge.

Suitabilty recommendations are taken from various state and federal guidelines. There are no regulations in place that provide limitations for private water wells.

EPA recommends that pe ople on low salt diets or who have high blood pressure limit their sodium to 20 mg/L.

Calcium and magnesium expressed as calcium carbonate. These elements do not adversely affect water quality but may have a detrimental effect on plumbing fixtures and ap pliances, such as water heaters. Soft water: 0

- 49 mg/L or 1

- 3 grains/gallon Medium

- Hard water: 50

- 149 mg/L or 3

- 9 grains/gallon Hard water: 150

- 249 mg/L or 9

- 15 grains/gallon Very Hard water: 250

- 299 mg/L or 15

- 18 grains/gallon Extremely Hard water: >30 0 mg/L or >18 grains/gallon Domestic Water Analysis Cost Per Sample $120.00

2. LIVESTOCK SUITABILITY

Parameter Suitability Tolerances, mg/L Parameter Suitability Tolerances, mg/L

Nitrate + Nitrite as N 100 Sulfate 3000

- 5000
pH 6.50

- 8.50 s.u. Total Di ssolved Solids (see notes) 

### 5000

- 7000
Sampling: 1

- 500 mL plastic bottle, unpreserved. Store at 6°C.
Holding Time: Various

- refer to Sampling and Preservation table located in the back of this section

Note: Poultry will experience decreased performance using water with TDS above 1,000 mg/L. Livestock, compared to humans, can tolerate higher concentrations of minerals in their drinking water. Sudden changes in livestock water quality (low to high concentrations) have proven fatal to some animals.

Liv estock Suitability Cost Per Sample $55.00

3. IRRIGATION CLASSIFICATION

Conductivity Magnesium Sodium Adsorption Ratio

Calcium Sodium

- Sampling: 1

- 250 mL plastic bottle, unpreserved.
Holding Time: Various

- refer to Sampling and Preservation table l ocated in the back of this section
Irrigation Classification Cost Per Sample $55.00Ve rsion 2011.0.3 Prices subject to change. Visit www.energylab.com for up

- to

- date pricing. www.energylab.com 

### Waters - 10 

# WATER
PARAMETER GROUPINGS

4. TOTAL COLIFORM BACTERIA ANALYSIS

Sampling: 1

- sterile sample container received from laboratory. Maintain at normal water temperature o r store at 6°C.
Holding Time: 30 hours

Note: The analysis takes 24 hours to complete. Weekend and holiday rate by quote.
Total Coliform Bacteria Analysis Cost Per Sample $20.00

5. DRINKING WATER COMPLETE RADIOCHEMICAL ANALYSIS

Gross Alpha particle a ctivity $50.00

226 

### Radium particle activity 75.00

228 

### Radium particle activity 75.00 Sampling: 2

- 1000 mL plastic, preserved with HNO 3 

### (red capped ampule). Sample location

– within the distribution system. Holding Time: 6 months

Note: Drinking water reg ulations require the analysis of gross alpha particle activity. When the Gross Alpha particle activity exceeds 5 pCi/L, the same or an equivalent sample shall be analyzed for 226 

### Radium. If the concentration of 226 

### Radium exceeds 3 pCi/L, the same or equiv alent sample shall be analyzed for
228 

### Radium. Refer to the Radiochemical Section for additional information.

6. LEAD AND COPPER RULE
Sampling: Collect the first 1

- liter after the water has stood motionless in the pipes for at least six hours. The labor atory will preserve with HNO 3 

### (red capped ampule) within 14 days of sampling. Sample location

– within the distribution system. Holding Time: 6 months

Note: The EPA has established Maximum Cont amination Limit Goals (MCLG) of 0 for lead and 1.3 mg/L for copper. Action levels are 0.015 mg/L for lead and 1.3 mg/L for copper measured in the 90 th 

### percentile at consumers’ taps.
Lead And Copper Rule Cost Per Sample $20.00

7. SAFE DRINKING WATER ACT PHASE II AND V

INORGANICS

– METALS
METALS, total EPA MCL, mg/L (ppm) METALS, total EPA MCL, mg/L (ppm)
Antimony 0.006 Chromium 0.1

Arsenic 0.01 Mercury 0.002

Barium 2 Nickel 0.1
Beryllium 0.004 Selenium 0.05

Cadmium 0.005 Thallium 0.002

Sodium (1)



### - - - Sampling: 1

- 1 L plastic, preserved with HNO 3 

### (red capped ampule). Sample location

- entry point to distribution after treatment. Holding Time: All metals except Mercury

– 6 months; Mercury

– 28 days.

Note: (1) 

### Sodium is only tested in selected s tates. Speak to an ELI Project Manager for more information.
Safe Drinking Water Act Phase II And V Metals Cost Per Sample $100.00Ve rsion 2011.0.3 Prices subject to change. Visit www.energylab.com for up

- to

- date pricing. www.energylab.com 

### Waters - 11 

# WATER
PARAMETER GROUPINGS

INORGANICS

– NITRATE PLUS NITRITE AS N

EPA MCL 10 mg/L (ppm)
Sampling: 1

- 500 mL plastic, preserve with H 2 

### SO 4 

### (yellow capped ampule) to pH < 2. Store at 6°C. Sample location

- e ntry point to distribution after treatment. Holding Time: 28 days

Note: Cyanide is not required for Montana public water supplies.

Safe Drinking Water Act Phase II And V Nitrate Plus Nitrite as N Cost Per Sample $20.00

INORGANICS

– NON

- METALS

NON

- ME TALS EPA MCL, mg/L (ppm)

Fluoride 4.0

Sulfate 250
Sampling: 1

- 500 mL plastic, unpreserved. Store at 6°C. Sample location

- entry point to distribution after treatment. Holding Time: 28 days

Safe Drinking Water Act Phase II And V Non

- Metals Cost Per Sample $20.00 7. SAFE DRINKING WATER ACT PHASE II AND V (continued)

INORGANICS

– CYANIDE

EPA MCL 0.2 mg/L (ppm)
Sampling: 1

- 500 mL plastic, preserved with NaOH (green capped ampule) to pH <12. Store at 6°C. Sample location

- entry point to distribution after treatment. Holding Time: 14 days

Note: Cyanide is not required for Montana public water supplies

. Safe Drinking Water Act Phase II And V Cyanide Cost Per Sample $50.00Ve rsion 2011.0.3 Prices subject to change. Visit www.energylab.com for up

- to

- date pricing. www.energylab.com 

### Waters - 12 

# WATER
PARAMETER GROUPINGS

7. SAFE DRINKING WATER ACT PHASE II AND V (continued)
VOLATILE ORGANIC CONTAMINANTS (VOC)

– METHOD E524.2

REGULATED VOC’S EPA MCL, μ g/L REGULATED VOC’S EPA MCL, μ g/L
Benzene 5 Styrene 100
Carbon tetrachlorid e 5 Tetrachloroethene 5
Chlorobenzene 100 Toluene 1000 1,2

- Dichlorobenzene 600 1,2,4

- Trichlorobenzene 70 1,4

- Dichlorobenzene 75 1,1,1

- Trichloroethane 200 1,2

- Dichloroethane 5 1,1,2

- Trichloroethane 5 1,1

- Dichloroethene 7 Trichloroethene 5
cis

- 1,2

- Dich loroethene 70 Vinyl chloride 2
trans

- 1,2

- Dichloroethene 100 m+p

- Xylenes

- 1,2

- Dichloropropane 5 o

- Xylene

- Ethylbenzene 700 Total Xylenes 10000 Methylene chloride 5

- - TRIHALOMETHANES EPA MCL, μ g/L TRIHALOMETHANES EPA MCL, μ g/L
Bromodichloromethane

- Chlorodibromomethane

- Bromoform

- Chloroform

- Total Trihalomethanes 80

- - OTHER EPA LISTED VOC’S EPA MCL, μ g/L OTHER EPA LISTED VOC’S EPA MCL, μ g/L
Bromobenzene NR 1,3

- Dichloropropane NR
Bromochloromethane NR cis

- 1,3

- Dichloropropene NR
Bromometh ane NR trans

- 1,3

- Dichloropropene NR

n

- Butylbenzene NR 2,2

- Dichloropropane NR

sec

- Butylbenzene NR Hexachlorobutadiene NR
tert

- Butylbenzene NR Isopropylbenzene NR
Chloroethane NR p

- Isopropyltoluene NR
Chloromethane NR Trichlorofluoromethane NR
2

- Chloro toluene NR Naphthalene NR
4

- Chlorotoluene NR n

- Propylbenzene NR 1,2

- Dibromo

- 3

- chloropropane (DBCP) 0.02 (See Note) 

### 1,1,1,2

- Tetrachloroethane NR 1,2

- Dibromoethane (EDB) 0.01 (See Note) 

### 1,1,2,2

- Tetrachloroethane NR
Dibromomethane NR Methyl

- t

- butyl ether NR 1,3

- Dichlorobenzene NR 1,2,3

- Trichlorobenzene NR
Dichlorodifluoromethane NR 1,2,3

- Trichloropropane NR 1,1

- Dichloroethane NR 1,2,4

- Trimethylbenzene NR 1,1

- Dichloropropene NR 1,3,5

- Trimethylbenzene

- Sampling: 3

- 40 mL VOA vials preserved with 5

- 10 d rops of HCl (smaller blue capped ampule) to pH <2 , add ascorbic acid to chlorinated samples. The vial must be completely full with no air bubbles. Store at 6°C. Sample location

- entry point to distribution after treatment. Holding Time: 14 days
Note : For regulatory compliance, DBCP and EDB should be analyzed by EPA method 504.1, which has lower PQLs. Safe Drinking Water Act Phase II And V VOCs

– Method E524.2 Cost Per Sample $130.00Ve rsion 2011.0.3 Prices subject to change. Visit www.energylab.com for up

- to

- date pricing. www.energylab.com 

### Waters - 13 

# WATER
PARAMETER GROUPINGS

7. SAFE DRINKING WATER ACT PHASE II AN D V (continued)

LOW LEVEL EDB AND DBCP

– METHOD E504.1 (See Note)



### LOW LEVEL EDB AND DBCP EPA MCL, μ g/L LOW LEVEL EDB AND DBCP EPA MCL, μ g/L

1,2

- Dibromo

- 3

- chloropropane (DBCP) 0.02 1,2

- Dibromoethane (EDB) 0.01

Sampling: 3

- 40 mL VOA vials, add 3 mg sodium thiosulfate to chlorinated and non

- chlorinated samples. The vials must be completely full with no air bubbles. Store at 6°C. Sample location

- entry point to distribution after treatment. Holding Time: 14 days

Note: Currently not required in t he State of Montana

Safe Drinking Water Act Phase II And V Low Level EDB And DBCP

- Method E504.1 Cost Per Sample $130.00



### HERBICIDES

– METHOD E515.1

HERBICIDES EPA MCL, μ g/L HERBICIDES EPA MCL, μ g/L
Dalapon 200 Picloram 500

Dicamba NR 2,4

- D 70

Dinos eb 7.0 2,4,5

- TP 50
Pentachlorophenol 1.0

- - Sampling: 2

- 1000 mL glass; add ascorbic acid to chlorinated samples. Store at 6°C.
Holding Time: 14 days to extraction; 28 days to analysis
Safe Drinking Water Act Phase II And V Herbicides

– Method E515.1 Cost Per Sample $180.00Ve rsion 2011.0.3 Prices subject to change. Visit www.energylab.com for up

- to

- date pricing. www.energylab.com 

### Waters - 14 

# WATER
PARAMETER GROUPINGS

7. SAFE DRINKING WATER ACT PHASE II AND V (continued)

PESTICIDES

– METHOD E525.2

– Drinking Water List

PESTICIDES EPA MCL, μ g/L PESTICIDES EPA MCL, μ g/L

Alachlor 2 Methoxychlor 40

Aldrin NR Metolach lor NR

Atrazine 3 Metribuzin NR
Benzo(a)pyrene 0.2 Propachlor NR

Butachlor NR Simazine 4

Chlordane 2 Simazine 4
bis(2

- ethylhexyl)adipate 400 Toxaphene 3
bis(2

- ethylhexyl)phthalate 6 For all Aroclor PCBs detected 0.5

Dieldrin NR Aroclor

- 1016

--
Endr in 2 Aroclor

- 1221

-- Heptachlor 0.4 Aroclor

- 1232

-- Heptachlor Epoxide 0.2 Aroclor

- 1242

--
Hexachlorobenzene 1 Aroclor

- 1248

-- Hexachlorocyclopentadiene 50 Aroclor

- 1254

--

Gamma

- BHC (Lindane) 0.2 Aroclor

- 1260

-- Sampling: 2

- 1000 mL glass bottles, pre served with HCl (blue capped ampule) to pH <2 , add sodium sulfite to chlorinated samples. Dechlorinate before adding the HCl. Store at 6°C. Sample location

- entry point to distribution after treatment. Holding Time: 14 days to extraction; 30 days from sampling to analysis

Note: The State of Montana Pesticides List is identified on page Organics

- 14

Safe Drinking Water Act Phase II And V Pesticides

– Method E525.5 Cost Per Sample $350.00
Safe Drinking Water Act Phase II And V Pesticides

– Method E525.5 State of Montana Pesticides List Cost Per Sample $300.00

CARBAMATE PESTICIDES

– METHOD E531.1

CARBAMATE PESTICIDES EPA MCL, μ g/L CARBAMATE PESTICIDES EPA MCL, μ g/L

Aldicarb 3 Carbofuran 40

Aldicarb Sulfone 2 3

- Hydroxycarbofuran NR

Aldicarb Sulfoxide 4 Methomyl NR
Carbaryl NR Oxamyl 200 Sampling: 2

- 40 mL VOA vials containing 1.2 mL monochloroacetic acid, add sodium thiosulfate to chlorinated samples. Do not rinse the sample bottles as it contains the buffer. Store at 6°C. Sample location

- entry point to distribution after treatment. Holding Time: 28 days

Safe Drinking Water Act Phase II And V Carbamate Pesticides

- Method E531.1 Cost Per Sample $175.00Ve rsion 2011.0.3 Prices subject to change. Visit www.energylab.com for up

- to

- date pricing. www.energylab.com 

### Waters - 15 

# WATER
PARAMETER GROUPINGS

7. SAFE DRINKING WATER ACT PHASE II AND V (continued)

GLYPHOSA TE

– METHOD E547 (See Note)



### EPA MCL 700 μ g/L Sampling: 1

- 40 mL VOA vial, add sodium thiosulfate to chlorinated samples. Store at 6°C. Sample location

- entry point to distribution after treatment. Holding Time: 14 days

Note: Currently not required i n the States of Montana or Wyoming
Safe Drinking Water Act Phase II And V Glyphosate

- Method E547 Cost Per Sample $140.00

ENDOTHALL

- METHOD E548.1 (See Note)



### EPA MCL 100 μ g/L Sampling: 1

- 1000 mL glass, add sodium thiosulfate to chlorinated samples. Store at 6°C. Sample location

- entry point to distribution after treatment. Holding Time: 7 days to extraction; EPA recommends 14 day extract holding time

Note: Currently not required in the States of Montana or Wyoming.
Safe Drinking Water Act Phase II And V Endothall

- Method E548.1 Cost Per Sample $200.00

DIQUAT

– METHOD E549.1 (See Note)



### EPA MCL 20 μ g/L Sampling: 1

- liter plastic or PVC bottles, add sodium thiosulfate to chlorinated samples. Store at 6°C. Sample location

- entry point to dist ribution after treatment. Holding Time: 7 days to extraction; 24 days to analysis

Note: Currently not required in the States of Montana or Wyoming
Safe Drinking Water Act Phase II And V Diquat

- Method E549.1 Cost Per Sample $180.00Ve rsion 2011.0.3 Prices subject to change. Visit www.energylab.com for up

- to

- date pricing. www.energylab.com 

### Waters - 16 

# WATER
PARAMETER GROUPINGS

8. LANDFILL GROUNDWATER ANALYSIS (40 CFR Part 258) (1)



### Appendix I

- Constituents for Detection Monitoring

– Inorganics (Metals, Minerals, Demand, and Nutrients)
Antimony Chloride Copper Nickel Sulfate
Arseni c Chromium Cyanide Nitrate + Nitrit e Thallium
Barium Cobalt Iron pH Vanadium Beryllium COD Lead Selenium Zinc Cadmium Conductivity Mercury Silver Sampling: 1

- 500 mL plastic bottle, unfiltered, preserved with H 2 

### SO 4 

### (yellow capped ampule). Store at 6°C

– Nutrients & Demand. 1

- 500 mL p lastic bottle, unfiltered, unpreserved. Store at 6°C

– Minerals & Demand. 1

- 500 mL plastic bottle, filtered, preserved with HNO 3 

### (red capped ampule)

– Metals. 1

- 500 mL plastic bottle, unfiltered, preserved with NaOH (green capped ampule). Store at 6° C

– Cyanide. Holding Time: Various

- refer to Sampling and Preservation table located in the back of this section

Appendix I

- Constituents for Detection Monitoring

– Purgeable Organics (VOCs), Method SW 8260B
Sampling: 3

- 40 mL VOA vials, completely full with no air bubbles. Preserved with 5

- 10 drops with HCl (blue capped ampule) to pH <2 . Add ascorbic acid to chlorinated samples. Store at 6°C. Holding Time: 14 days
Landfill Groundwater Analysis Appendix I Detection Monitoring Cost Per Sample $400.00

Appendix II

- Assessment Monitoring

- Inorganics (Metals, Sulfide, and Cyanide)
Sampling: 1

- 500 mL plastic bottle, unfiltered, preserved with Zinc Acetate (purple capped ampule) and NaOH (green capped ampule) to pH > 9. Bottle must be filled completel y full with no headspace. Store at 6°C.

– Sulfide 1

- 500 mL plastic bottle, filtered, preserved with HNO 3 

### (red capped ampule).

- Metals 1

- 500 mL plastic bottle, unfiltered, preserved with NaOH (green capped ampule). Store at 6°C.

- Cyanide Holding Ti me: Various

- refer to Sampling and Preservation table located in the back of this section
Appendix II

- Assessment Monitoring

- Organochlorine Pesticides and PCBs, Method SW 8081A and SW 8082

Sampling: 2

- 1 liter glass, unpreserved. Store at 6°C.

Hold ing Time: 7 days to extraction, 40 days to analysis
Appendix II

- Assessment Monitoring

- Chlorinated Herbicides, Method SW 8151A

Sampling: 2

- 1 liter glass, unpreserved. Store at 6°C. Holding Time: 7 days to extraction, 40 days to analysis
Appendix I I

- Assessment Monitoring

– Purgeable Organics (VOCs), Method SW 8260B
Sampling: 3

- 40 mL VOA vials, completely full with no air bubbles. Preserved with 2 drops of HCl (blue capped ampule) to pH <2 . Store at 6°C. Holding Time: 14 days
Appendix II

- Asse ssment Monitoring

- Acrolein, EPA Method SW 8260B
Sampling: 3

- 40 mL VOA vials. Unpreserved (raw), chilled to 6 ° C and analyzed within 3 days of collection. Or, pH adjusted to 4

- 5 with HCL, chilled to 6°C, and analyzed within 14 days. Add ascorbic acid to chlorinated samples. The vials must be completely full with no air bubbles. Store at 6°C. Holding Time: 14 days
Appendix II

- Assessment Monitoring

- Semi

- Volatile Organics (SVOC), Method SW 8270C

Sampling: 2

- 1 liter glass, unpreserved. Store at 6 °C. Holding Time: 7 days to extraction, 40 days to analysis
Landfill Groundwater Analysis Appendix II Cost Per Sample $1,500.00

(1) Each state may have different requirements. Please contact an Energy Laboratory representative for more information.Ve rsion 2011.0.3 Prices subject to change. Visit www.energylab.com for up

- to

- date pricing. www.energylab.com 

### Waters - 17 

# WATER
PARAMETER GROUPINGS

9. PRIORITY POLLUTANTS

Category Method Cost Per Sample

Volatiles Short List Volatiles Acrolein/Acrylonitrile E624 E624 $150.00 80.00 Sampling: 3

- 40 mL glass/teflon VOA vials

. Add 3

- 5 drops of HCl

. For Acrolein take an additional 3

- 40 mL VOA vials. Unpreserved (raw) and analyzed within 3 days of collection. Or, pH adjusted to 4

- 5 with HCL, and analyzed within 14 days. Contact the laboratory prior to sampling to arrange for this analysis. Add sodium thiosulfate or ascorbic acid to chlorinated samples. The vials must be completely full with no air bubbles. Store at 6 ° C. Holding Time: 14 days (3 days for unpreserved Acrolein)

Pesticides/PCBs E608 250.00 Sampling: 1

- 1000 mL glass bottle. Add ascorbic acid to ch lorinated samples. The vials must be completely full with no air bubbles. Store at 6°C. Holding Time: 7 days to extraction, then 40 days to analysis Semi

- Volatiles Acid Compounds Base Neutrals 2,3,7,8

- TCDD E625 E625 E625 screening 170.00 200.00 100. 00 Sampling: 4

- 1000 mL glass bottles. Add 40 mg sodium thiosulfate to chlorinated samples. Store at 6°C. Holding Time: 7 days to extraction, then 40 days to analysis Inorganics

Metals, Totals Antimony Cadmium Lead Selenium
Arsenic Chromium Mercury Silver Beryllium Copper Nickel Thallium

- - - Zinc Sampling: 1

- 250 mL plastic bottle. Preserve with HNO 3 

### (red capped ampule).
Holding Time: All metals except Mercury

– 6 months; Mercury

– 28 days.
Cyanide, Total
Sampling: 1

- 250 mL plastic bottle. P reserve with NaOH (green capped ampule).
Holding Time: 14 days

Phenolics

Sampling: 1

- 250 mL glass bottle. Preserve with H 2 

### SO 4 

### (yellow capped ampule), 2 drops/vial.
Holding Time: 28 days
Priority Pollutants Cost Per Sample $180.00

10. METALS SCAN

A luminum Cadmium Iron Nickel Sodium
Antimony Calcium Lead Phosphorus Strontium

Barium Chromium Magnesium Potassium Thallium
Beryllium Cobalt Manganese Silicon Titanium

Boron Copper Molybdenum Silver Vanadium

- - - - Zinc
Sampling: 1

- 250 mL plastic bot tle preserved with HNO 3 

### (red capped ampule).
Holding Time: 6 months

ICP Scan: Analyzed in water by ICP to a 0.1 mg/L reporting limit. (Calcium, Magnesium, Sodium, Potassium 5 mg/L reporting limit.) ICP Scan Cost Per Sample $125.00

ICP

- MS Scan: A semi

- quantitative analysis of water by ICP

- MS. This includes 65 elements from lithium at 7 atomic mass units (amu) through uranium (238 amu). Semi

- quantitative measurements are made at the sub parts per billion concentration range. Not included are scandium, yttrium, indium, bismuth, and gold.

ICP

- MS Scan Cost Per Sample $250.00Ve rsion 2011.0.3 Prices subject to change. Visit www.energylab.com for up

- to

- date pricing. www.energylab.com 

### Waters - 18 

# WATER
PARAMETER GROUPINGS

1 1. UCMR

- LIST 1 CONTAMINANTS

METHOD 527

- INSECTICIDES AND FLAME RETARDANTS

COMPOUND EPA MRL (ug/L)

Dimethoate 0.7

Terbufos Sulfone 0.4

2,2',4,4'

- tet rabromodiphenyl ether(BDE

- 47) 0.3

2,2',4,4',5

- pentabromodiphenyl ether(BDE

- 99) 0.9

2,2',4,4',5,5'

- hexabromodiphenyl ether(BDE

- 153) 0.8

2,2',4,4',6

- pentabromodiphenyl ether(BDE

- 100) 0.5

2,2',4,4',5,5'

- hexabromodiphenyl ether(HBB) 0.7
Sampling: 4

- 1000m l amber glasss bottles, preserved with Na3EDTA

- KH2citrate
Holding Time: 14 days to extraction
Cost Per Sample $250.00

METHOD 529

- EXPLOSIVES

COMPOUND EPA MRL (ug/L)

2,4,6

- trinitrontoluene(TNT) 0.8

1,3

- dinitrobenzene 0.8
Hexahydro

- 1,3,5

- trinitro

- 1,3 ,5

- triazine (RDX) 1.0
Sampling: 4

- 1000ml amber glasss bottles, preserved with CuSO4

- TRIZ
Holding Time: 14 days to extraction
Cost Per Sample $250.00Ve rsion 2011.0.3 Prices subject to change. Visit www.energylab.com for up

- to

- date pricing. www.energylab.com 

### Waters - 19 

# RECOMMENDATIONS FOR
SAMPLING AND PRESERVATION OF WATERS

MEASUREMENT Volume Required (mL) Container P=Plastic G=Glass PRESERVATIVE HOLDING TIME

Preservative ampules: HNO 3 

### – nitric acid (red cap), H 2 

### SO 4 

### - sulfuric acid (yellow cap), HCl

- hydrochloric acid (blue cap), H 3 

### PO 4 

### - phosphoric acid (white cap), NaOH

- sodium hydroxide (green cap), or zinc acet ate (purple cap). Major minerals, including the following: Potassium, Sodium, Calcium, Magnesium, Sulfate, Chloride, Bicarbonate, Carbonate, pH, Specific Conductance, Total Dissolved Solids 500 P or G Cool, 

# ≤ 6 ° C see holding times for each individual
para meter, below

METALS

Dissolved Metals 250 P or G Filter (0.45 micron), then add HNO 3 

### to pH <2 6 months

Total Metals 250 P or G HNO 3 

### to pH <2 6 months

Chromium +6 

### 200 P or G Cool, 

# ≤ 6 ° C 24 hours

Ferrous Iron (Fe II

- requires field filtering) 100 P or G Filter (0.45 micron), then add HNO 3 

### to pH <2 6 months

Mercury 100 P or G same as tot. or diss. Metals 28 days

NON

- METALLICS

Acidity 100 P or G Cool, 

# ≤ 6 ° C 14 days

Alkalinity 100 P or G Cool, 

# ≤ 6 ° C 14 days

Biochemical Oxygen Demand (BOD) 1000 P or G Co ol, 

# ≤ 6 ° C 48 hours

Bromide 100 P or G None Required 28 days

Carbonaceous BOD 1000 P or G Cool, 

# ≤ 6 ° C 48 hours

Chemical Oxygen Demand (COD) 50 P or G H 2 

### SO 4 

### to pH <2, Cool, 

# ≤ 6 ° C 28 days

Chloride 50 P or G None Required 28 days

Chlorine 50 P or G None R equired 15 minutes

Chlorophyll a 1000 P or G Cool, 

# ≤ 6 ° C , keep in
the dark NA

Color 50 P or G Cool, 

# ≤ 6 ° C 48 hours

Conductance 100 P or G Cool, 

# ≤ 6 ° C 28 days

Cyanates 250 P NaOH to pH >12, Cool, 

# ≤ 6 ° C 14 days

Cyanides 500 P or G NaOH to pH >12, Cool, 

# ≤ 6 ° C 14 days

Ethylene Glycol 500 P or G Cool, 

# ≤ 6 ° C NA

Formaldehyde 100 P or G Cool, 

# ≤ 6 ° C NAVe rsion 2011.0.3 Prices subject to change. Visit www.energylab.com for up

- to

- date pricing. www.energylab.com 

### Waters - 20 

# RECOMMENDATIONS FOR SAMPLING AND PRESERVATION OF WATERS, continued

MEASUREMENT Volume Required (mL) Container P=Plastic G=Glass PRESERVATIVE HOLDING TIME

NON

- METALLICS continued

Fluoride 50 P or G None Required 28 days

Iodide 100 P or G None Required 28 days

Hardness 100 P or G Cool, 

# ≤ 6 ° C 6 months

Methane 40 mL VOA vial

- no headspace

- 4 drops H 2 

### SO 4 

### NA

Nitrogen, Ammonia 50 P or G H 2 

### SO 4 

### to pH <2, Cool, 

# ≤ 6 ° C 28 days

Nitrogen, Total Kjeldahl 500 P or G H 2 

### SO 4 

### to pH <2, Cool, 

# ≤ 6 ° C 28 days

Nitrogen, Nitrate plus Nitrite 50 P or G H 2 

### SO 4 

### to pH <2, Cool, 

# ≤ 6 ° C 28 days

Nitrogen, Nitrate 50 P or G Cool, 

# ≤ 6 ° C 48 hours

Nitrogen, Nitrite 50 P or G Cool, 

# ≤ 6 ° C 4 8 hours
Nitrogen, Total (Persulfate Method) 50 P or G Cool, 

# ≤ 6 ° C NA

Oil and Grease 2

- 1000 G H 2 

### SO 4 

### to pH <2, Cool, 

# ≤ 6 ° C 28 days

Organic Carbon 125 G H 3 

### PO 4 

### to pH <2, Cool, 

# ≤ 6 ° C 28 days

Organic Carbon, Public Water Supply 500 G H 3 

### PO 4 

### to pH <2, Cool, 

# ≤ 6 ° C 28 days

pH 25 P or G None Required 15 miuntes

Phenolics by E420.4 250 G H 2 

### SO 4 

### to pH <2, Cool, 

# ≤ 6 ° C 28 days

Phenols by E420.1 distillation 2

- 1000 G H 2 

### SO 4 

### to pH <2, Cool, 

# ≤ 6 ° C 28 days

Phosphorus, Hydrolyzable 250 P or G H 2 

### SO 4 

### to pH <2, Cool, 

# ≤ 6 ° C 28 days

Phosphorus, Ortho 250 P or G Filter within 15 minutes

, Cool, 

# ≤ 6 ° C 48 hours

Phosphorus, Total 250 P or G H 2 

### SO 4 

### to pH <2, Cool, 

# ≤ 6 ° C 28 days

Residue, Filterable Total Dissolved Solids (TDS) 500 P or G Cool, 

# ≤ 6 ° C 7 days

Residue, Non

- filtera ble Total Suspended Solids (TSS) 500 P or G Cool, 

# ≤ 6 ° C 7 days

Residue, Total 100 P or G Cool, 

# ≤ 6 ° C 7 days

Residue, Volatile Volatile Suspended Solids (VSS) 100 P or G Cool, 

# ≤ 6 ° C 7 days

Settleable Matter 1000 P or G Cool, 

# ≤ 6 ° C 48 hoursVe rsion 2011.0.3 Prices subject to change. Visit www.energylab.com for up

- to

- date pricing. www.energylab.com 

### Waters - 21 

# RECOMMENDA TIONS FOR SAMPLING AND PRESERVATION OF WATERS, continued

MEASUREMENT Volume Required (mL) Container P=Plastic G=Glass PRESERVATIVE HOLDING TIME

NON

- METALLICS continued

Sulfate 100 P or G Cool, 

# ≤ 6 ° C 28 days

Sulfide 250 P or G Add 2 mL zinc acetate, ze ro headspace, NaOH to pH > 9, Cool, 

# ≤ 6 ° C 7 days

Sulfite 100 P or G 1 mL of EDTA 15 minutes

Surfactants (Foaming Agents) 500 P or G Cool, 

# ≤ 6 ° C 48 hours

Tannins & Lignins 25 P or G Cool, 

# ≤ 6 ° C 14 days

Thiocyanates 100 P or G HNO 3 

### to pH <2 NA

Total Pet roleum Hydrocarbons (TPH) 2

- 1000 G H 2 

### SO 4 

### to pH < 2, Cool, 

# ≤ 6 ° C 28 days

Total Petroleum Hydrocarbons (TPH) by TCEQ 1005 3

- VOA vials with zero headspace G HCI to pH < 2, Cool, 

# ≤ 6 ° C 14 days

Turbidity 100 P or G Cool, 

# ≤ 6 ° C 48 hours

BACTERIA

Total Col iform Bacteria 120 Sterile Cool, 

# ≤ 6 ° C 30 hours

Fecal Coliform Bacteria 120 Sterile Cool, 

# ≤ 6 ° C 8 hours

Heterotrophic Plate Count 120 Sterile Cool, 

# ≤ 6 ° C 24 hours

Sulfate Reducing Bacteria 120 Sterile Cool, 

# ≤ 6 ° C 48 hours

Iron Bacteria 100 Sterile Cool

, 

# ≤ 6 ° C NA

RADIOCHEMISTRY

Gross Alpha 2

– 1000 P or G HNO 3 

### to pH < 2 6 months

Gross Beta 2

– 1000 P or G HNO 3 

### to pH < 2 6 months

210 

### Lead 2

– 1000 P or G HNO 3 

### to pH < 2 6 months

210 

### Polonium 2

– 1000 P or G HNO 3 

### to pH < 2 6 months

222 

### Radon 3

- VOA vials with zero headspace G Cool, 

# ≤ 6 ° C 8 days

226 

### Radium 2

– 1000 P or G HNO 3 

### to pH < 2 6 months

228 

### Radium 2

– 1000 P or G HNO 3 

### to pH < 2 6 months

230 

### Thorium 2

– 1000 P or G HNO 3 

### to pH < 2 6 months

Uranium 2

– 1000 P or G HNO 3 

### to pH < 2 6 months

# BLANKVersion 2011.0.0 Prices subject to change. Visit www.energylab.com for up- to -date pricing. www.energylab.com 

### Organics - 1 

# OR GANIC CHEMISTRY List of Acronyms

A Standard Methods NR Not Regulated

BTEX Benzene, Toluene, Ethylbenzene, Xylenes PAH Polynuclear Aromatic Hydrocarbons

CFR Code of Federal Regulations PCBs Polychlorinated Biphenyls

DBCP 1,2

- Dibromo

- 3

- chl oropropane POX Purgeable Halocarbons

DRO Diesel Range Organics ppb parts per billion

EDB Dibromoethane ppm parts per million

EOX Extractable Organic Halogens PQLs Practical Quantitation Limits The PQL of diluted samples will be correspond ingly higher.

E or EPA US Environmental Protection Agency PVC Polyvinyl Chloride

EPH Extractable Petroleum Hydrocarbons SVOC Semi

- Volatile Organic Compounds

GC Gas Chromatograph TCL Target Compound List

GC/FID Gas Chromatograph/Flam e Ionization Detector TOC Total Organic Carbon

GC/MS Gas Chromatograph/Mass Spectrometer TOX Total Organic Halogens

GRO Gasoline Range Organics TEPH Total Extractable Petroleum Hydrocarbons

H 2 

### SO 4 

### Sulfuric Acid TPH Total Petroleum Hydroca rbons

HCI Hydrochloric Acid TPH

- D Total Petroleum Hydrocarbons as Diesel

HPLC High Performance Liquid Chromatography TPH

- G Total Petroleum Hydrocarbons as Gasoline

IR Infrared Spectroscopy TPH

- IR Total Petroleum Hydrocarbons by Infrared Spectroscopy

MCL Maximum Contaminant Level TRPH Total Recoverable Petroleum Hydrocarbons

NaOH Sodium Hydroxide VOCs Volatile Organic Chemicals

NH 4 

### CI Ammonium Chloride VPH Volatile Petroleum HydrocarbonsVersion 2011.0.0 Prices subject to change. Visit www.energylab.com for up- to -date pricing. www.energylab.com 

### Organics - 2 

# ORGANIC CHEMISTRY

1. DRI NKING WATER ANALYSIS

ANALYSIS METHOD METHOD DETAILS, Organics Page PRICE, WATER

Trihalomethanes E502.2/E524.2 7 $100.00

Maximum Trihalomethane Potential 40 CFR Part 141.30 7 120.00

Volatile Halogenated Compounds E502.2/E524.2 7 90.00

Volatile Aromati c Compounds E502.2/E524.2 8 90.00

EDB and DBCP, low level E504.1 8 130.00

Nitrogen

- Phosphorus and Sulfur Pesticides by GC/MS E507 Mod. 10 150.00

Chlorinated Pesticides and PCBs E508 9 180.00

PCBs as decachlorobiphenyl E508A 10 200.00

Chlorinated Acid Herbicides E515.1 11 180.00

Chlorinated Acid Herbicides, long list E515.1 11 225.00

Regulated and Unregulated VOCs E524.2/E502.2 13 130.00

Regulated and Unregulated VOCs, long list E524.2 long list 14 220.00
Pesticides (Semi

- Volatile Organic Compounds ), drinking water list E525.2 11 350.00

Pesticides (Semi

- Volatile Organic Compounds), Montana drinking water list E525.2 12 300.00

Pesticides (Semi

- Volatile Organic Compounds), long list E525.2 12 400.00

Carbamates E531.1 15 175.00

Glyphosate E547 15 1 40.00

Endothall E548.1 15 200.00

Diquat E549.1 15 180.00

Haloacetic Acids E552.2 16 200.00



### 2. VOLATILES

ANALYSIS METHOD METHOD DETAILS, Organics Page PRICE, WATER or

SOLIDS
Purgeable Halocarbons (POX) E601/SW 8021B/E624/ SW 8260B 16 $110.00

Purgeab le Aromatics E602/SW 8021B/E624/ SW 8260B 17 90.00

POX and Purgeable Aromatics together E601+E602/E624/SW 8260B 16, 17 150.00

Benzene, Toluene, Ethylbenzene, Xylenes (BTEX) E602/SW 8021B 17 $75.00

Benzene, Toluene, Ethylbenzene, Xylenes (BTEX) E524.2/E6 24/SW 8260B 17 90.00Version 2011.0.0 Prices subject to change. Visit www.energylab.com for up- to -date pricing. www.energylab.com 

### Organics - 3 

# ORGANIC CHEMISTRY

2. VOLATILES (continued)

ANALYSIS METHOD METHOD DETAILS, Organics Page PRICE, WATER or

SOLIDS
Gasoline Range Organics (GRO) 1990 Draft Method 24 75.00

BTEX and GRO together 1990 Draft Method 17, 24 120.00

Purge able Organics (VOCs), short list E624/SW 8260B 20 150.00

Acrolein and Acrylonitrile E624/SW 8260B 19 80.00

Purgeable Organics (VOCs), long list SW 8260B 21 220.00

Total Petroleum Hydrocarbons as Gasoline (TPH

- G) SW 8015 Mod. 24 75.00

Total Petroleum Hy drocarbons TCEQ 1005 60.00



### 3. PETROLEUM, UST, LUST RELATED ANALYSIS

ANALYSIS METHOD METHOD DETAILS, Organics Page PRICE, WATER, SOLIDS,

or AIR
Benzene, Toluene, Ethylbenzene, Xylenes (BTEX) E602/SW 8021B 17 $75.00

Benzene, Toluene, Ethylbenzene, Xyl enes (BTEX) E524.2/E624/SW 8260B 17 90.00

Benzene, Toluene, Ethylbenzene, Xylenes (BTEX) E524.2 13 90.00

Gasoline Range Organics (GRO) 1993 Draft Method 24 75.00

BTEX and GRO together E602/SW 8021B + GRO 17, 24 120.00

Diesel Range Organics (DRO) 1993 D raft Method 25 75.00

Extractable Petroleum Hydrocarbons Screen (EPH) MT DEQ MA EPH 26 75.00
Extractable Petroleum Hydrocarbons (EPH) (after screening option without PAHs

- if required) MT DEQ MA EPH 26 150.00

Extractable Petroleum Hydrocarbons (EPH) (afte r screening option with PAHs

- if required) MT DEQ MA EPH 26 200.00

Extractable Petroleum Hydrocarbons (EPH) (complete without screening) MT DEQ MA EPH 26 250.00

Volatile Petroleum Hydrocarbons (VPH) MT DEQ MA VPH 25 120.00

Carbon Scan with DRO (product i dentification

- fingerprinting) GC/FID 25 120.00

Total Petroleum Hydrocarbons as Gasoline (TPH

- G) SW 8015 Mod. 24 75.00

Total Petroleum Hydrocarbons as Diesel (TPH

- D) SW 8015 Mod. 25 75.00

Total Petroleum Hydrocarbons TCEQ 1005 60.00

Total Petroleum H ydrocarbons by Infrared Spectroscopy (TPH

- IR) E418.1 27 75.00

Purgeable Organics (VOCs) E624/SW 8260B 20, 21 150.00

Oil & Grease, Hexanes Extraction/Gravimetric E1664A 28 75.00
Oil & Grease, Hexanes Extraction/Gravimetric Sulfur Corrected w/Copper E1664

- Cu 27 100.00

TPH, Hexanes Extraction/Gravimetric E1664A 28 75.00
TPH, Hexanes Extraction/Gravimet Sulfur Corrected w/Copper E1664

- Cu 27 100.00Version 2011.0.0 Prices subject to change. Visit www.energylab.com for up- to -date pricing. www.energylab.com 

### Organics - 4 

# ORGANIC CHEMISTRY

3. PETROLEUM, UST, LUST RELATED ANALYSIS (continued)

ANALYSIS METHOD METHOD DETAILS, Org anics

Page PRICE, WATER, SOLIDS,

or AIR

Oil and Grease, Freon Extractable/Gravimetric E413.1 27 75.00

Acrylamide by HPLC SW 8316 28 100.00

Oil and Grease, Freon Extractable/Infrared Spectroscopy E413.2 27 $75.00

Oil and Grease or TPH by Soxhlet Extrac tion SW 9071 27 125.00

Hydrocarbons in Headspace Gas GC/FID/ Kampbell (SW 8015 Mod.) 

### 28 50.00



### 4. SEMI

- VOLATILES

ANALYSIS METHOD METHOD DETAILS, Organics

Page PRICE, WATER or

SOLIDS

Semi

- volatile Organics (SVOC) by GC/MS E625/SW 8270C 22 $370.00

SVOC acid extractables E625/SW 8270C 22 170.00

SVOC base/neutral extractables E625/SW 8270C 22 200.00

2,3,7,8

- TCDD Dioxin

– Screening test E625 screening 23 100.00

Phenols, individual compounds by GC/MS E625/SW 8270C 23 170.00

Phenols, total in water, color imetric E420.4 Waters

– 6 20.00

Phenols, total in soil, colorimetric E420.2 Mod. Waters

– 6 150.00

Phthalate Esters E625/SW 8270C 23 200.00

Polynuclear Aromatic Hydrocarbons (PAH), by GC/MS E625/SW 8270C 24 200.00

Polynuclear Aromatic Hydrocarbons (PAH ), by HPLC SW 8310 24 200.00

Diesel Range Organics (DRO) 1993 Draft Method 25 75.00

Carbon Scan with DRO (product identification

– fingerprinting) GC/FID 25 120.00

Total Petroleum Hydrocarbons as Diesel (TPH

- D) SW 8015 Mod. 25 75.00

Total Petroleum Hyd rocarbons by Infrared Spectroscopy (TPH

- IR) E418.1 27 60.00

Acrylamide by HPLC SW 8316 28 100.00

Explosives

– Nitroaromatics and Nitramines by HPLC SW 8330 28 300.00

Explosives

– Nitroglycerine and PETN by HPLC SW 8332 28 200.00



### 5. HERBICIDES, PESTICI DES AND PCBs

ANALYSIS METHOD METHOD DETAILS, Organics

Page PRICE, WATER or

SOLIDS

Polychlorinated biphenyls (PCBs) E608/SW 8082 18 $120.00
PCBs in transformer oil (5 mg/Kg) SW 8082 19 120.00

Organochlorine Pesticides and PCBs E608 or SW 8081A+ SW 8082 18 250.00Version 2011.0.0 Prices subject to change. Visit www.energylab.com for up- to -date pricing. www.energylab.com 

### Organics - 5 

# ORGANIC CHEMISTRY

5. HERBICIDES, PESTICIDES AND PCBs (continued)

ANALYSIS METHOD METHOD DETAILS, Organics

Page PRICE, WATER or

SOLIDS

Organochlorine Pesticides E608/SW 8081A 18 200.00

Chlorinated Herbicides E615/SW 8151A 19 225.00



### 6. OTHER ORGANICS

ANALYSIS METHOD METHOD DETAILS, Organics

Page PRICE, WATER or

SOLIDS

Total Organic Carbon (TOC) E415.2 Waters

– 6 $25.00

Total Organic Halogens (TOX) SW 9020 Waters

– 7 90.00

Ethylene Glycol ASTM D2982 Mod. Waters

– 5, Waters

– 17 50.00

Glyc ol by GC GC

- FID / SW 8015M Organics

– 27 100.00

Formaldehyde NIOSH 3500 Mod. Waters

– 5 60.00

Methanol SW 8015 24 90.00

Methane GC

- FID/ Kampbell (SW 8015 Mod.) Waters

– 5, Organics

– 28 50.00



### 7. PREPARATORY METHODS

Extractions, Preparations and Clean ups From SW

- 846, Test Methods For Evaluating Solid Waste These methods are used to prepare or cleanup samples for analysis. Unless specified by the sample submitter, the laboratory will select the appropriate method based on the sample matrix, the analytic al method, and the data objectives.



### Method DESCRIPTION

SW 3510C Separatory Funnel Liquid

- Liquid Extraction

SW 3520C Continuous Liquid

- Liquid Extraction

SW 3540C Soxhlet Extraction

SW 3545 Accelerated Solvent Extraction

SW 3550B Ultrasonic Extraction

SW 3580A Waste Dilution

SW 5030B Purge

- and

- Trap

SW 3620B Florisil Column Cleanup

SW 3630C Silica Gel Cleanup

SW 3640A Gel

- Permeation Cleanup

SW 3650A Acid

- Base Partition Cleanup

SW 3660B Sulfur Cleanup

SW 3665A Sulfuric Acid/Permanganate CleanupVersion 2011.0.0 Prices subject to change. Visit www.energylab.com for up- to -date pricing. www.energylab.com 

### Organics - 6 

# ORGANIC CHEMISTRY
SAMPLING AND PRESERVATION

METHOD SAMPLE BOTTLE(s),

Water (1) 

### SAMPLE BOTTLE, Solids (1) 

### Preservation of water samples (solids are

not preserved) (2) 

### Additional treatment for chlorinated samples Holding time to extraction, days Holding time to analysis,

days
E502.2 3

- 40 mL VOA (3) 

### NA HCl to pH <2 sodium thiosulfate NA 14

E504.1 3

- 40 mL VOA (3) 

### NA 3 mg sodium thiosulfate ascorbic acid or sodium thiosulfate 14 24 hours

E507mod 2

- 1000 mL G 125 mL w/m G none sodium thiosulfate 14 28

E508 1

- 1000 mL G NA none sodium thiosulfate 7 14

E508 A 2

- 1000 mL G NA none None 14 30

E515.1 1

- 1000 mL G NA none ascorbic acid 14 28

E524.2 3

- 40 mL VOA (3) 

### NA HCl to pH <2 ascorbic acid NA 14

E525.2 2

- 1000 mL G NA HCl to pH <2 sodium sulfite

– d echlorinat e before adding acid. 14 30

E531.1 3

- 40 mL VOA (3) 

### NA 1.2 mL monochloro

acetic acid sodium thiosulfate NA 28

E547 1

- 40 mL VOA (3) 

### NA none sodium thiosulfate NA 14

E548.1 1

- 1000 mL G NA none sodium thiosulfate 7 14

E549 2

- liter P (or PVC) NA none sodium thiosulfate 7 21

E552.2 3

- 40 mL VOA (3) 

### NA NH 4 

### Cl, 100 mg/L none 14 14
E601/ SW 8021B 3

- 40 mL VOA (3) 

### 125 mL w/m G HCl to pH <2 ascorbic acid NA 14

E602/ SW 8021B 3

- 40 mL VOA (3) 

### 125 mL w/m G HCl to pH <2 ascorbic acid NA 14

E608/ SW 8081A 1

- 1000 mL G 125 mL w/m G none sodium thiosulfate 7 (w); 14 (s) 40

E612/ SW 8121 1

- 1000 mL G 125 mL w/m G none none 7 (w); 14 (s) 40

E615/ SW 8151A 1

- 1000 mL G 125 mL w/m G none sodium thiosulfate 7 (w); 14 (s) 40

E624/ SW 8260B 4

- 40 mL VOA (3) 

### 125 mL w/m G HCl to p H <2 ascorbic acid NA 14

Acrolein and Acrylonitrile should be sampled in separate vials from other VO Cs 3

- 40 mL VOA vials. Unpreserved (raw), chilled to 6 ° C and analyzed within 3 days of collection. Or, pH adjusted to 4

- 5 with HCL, chilled to 6 ° C, and a nalyzed within 14 days. Add ascorbic acid to chlorinated samples. Store at 6 ° C. Contact the laboratory prior to sampling to arrange for this analysis

E625/ SW 8270C 2

- 1000 mL G 125 mL w/m G none sodium thiosulfate 7 (w); 14 (s) 40

SW 8310 2

- 1000 mL G 1 25 mL w/m G none none 7 (w); 14 (s) 40

SW 8316 3

- 40 mL VOA 125 mL w/m G none none NA 14

SW 8330 2

- 1000 mL G 125 mL w/m G none none 7 (w); 14 (s) 40

SW 8332 2

- 1000 mL G 125 mL w/m G none none 7 (w); 14 (s) 40

BTEX 3

- 40 mL VOA (3) 

### 125 mL w/m G HCl to pH <2 ascorbic acid NA 14

GRO/TPH

- g 3

- 40 mL VOA (3) 

### 125 mL w/m G HCl to pH <2 none NA 14

DRO/TPH

- d 2

- 1000 mL G 125 mL w/m G H 2 

### SO4 to pH <2 none 7 (w); 14 (s) 40Version 2011.0.0 Prices subject to change. Visit www.energylab.com for up- to -date pricing. www.energylab.com 

### Organics - 7 

# ORGANIC CHEMISTRY SAMPLING AND PRESERVATION (continued)

METHOD SAMPLE BOTTLE(s),

Water (1) 

### S AMPLE BOTTLE, Solids (1) 

### Preservation of water samples (solids are

not preserved) (2) 

### Additional treatment for chlorinated samples Holding time to extraction, days Holding time to analysis,

days
E418.1/TPH 1

- 1000 mL G 125 mL w/m G H 2 

### SO4 to pH <2 none 7 4 0 TPH byTCEQ 1005 3

- 40mL VOA 4 oz G HCl to pH <2 none 14 14

E1664 O & G 2

- 1000 mL c G NA H 2 

### SO4 to pH <2 none NA 28

E1664 TPH 2

- 1000 mL c G NA H 2 

### SO4 to pH <2 None NA 28

EPH 2

- 1000 mL G 125 mL w/m G H 2 

### SO 4 

### to pH <2 none 14(w); 7(s) 40

VPH 3

- 40 mL VOA (3 ) 

### 125 mL w/m G HCl to pH <2 ascorbic acid 7(s) 14 (w); 28(s)
Notes: 1

– Sample bottles; P = plastic; G = glass; w/m = wide mouth; c = clear 2

– Most parameters should be shipped and stored at6°C. 3

– Water samples collected for volatiles must be taken w ith zero headspace. The VOA vial must be completely full, no headspace. 4

– 7 days if heptachlor epoxide is required.Version 2011.0.0 Prices subject to change. Visit www.energylab.com for up- to -date pricing. www.energylab.com 

### Organics - 8 

# ORGANIC CHEMISTRY
DESCRIPTION OF METHODS

Trihalomethanes (Method E502.2/E524.2)
Sampling: 3

- 40 mL glass/teflon VOA vials completel y full with no air bubbles. Store at6°C. Add ascorbic acid to chlorinated samples. Preserve with 5

- 10 drops hydrochloric acid to pH <2 (smaller blue capped ampule).

Holding Time: 14 days

Drinking Water MCL: 80 μ g/L total of all four trihalomethan es

CAS NO. PQL, μ g/L CAS NO. PQL, μ g/L
Bromodichloromethane 75

- 27

- 4 0.5 Chloroform 67

- 66

- 3 0.5 Bromoform 75

- 25

- 2 0.5 Dibromochloromethane 124

- 48

- 1 0.5



### Maximum Trihalomethane Potential (40 CFR Part 141.30)
Sampling: Sample in 40 mL glass/teflon VOA vials completely full with no air bubbles. If no residual chlorine is present, obtain 10 vials; if residual chlorine is present, take 4 vials. Store at6°C. Do not
preserve.

Holding Time: None specified in method. Incubation should be started upon rec eipt of samples.



### Volatile Halogenated Compounds (Method E502.2/E524.2)
Sampling: 3

- 40 mL glass/Teflon VOA vials completely full with no air bubbles. Store at6°C. Add ascorbic acid to chlorinated samples. Preserve with 5

- 10 drops hydrochloric acid to pH <2 (smaller blue capped ampule).

Holding Time: 14 days

Notes: MCL = Drinking Water MCL EPA MCL for the Total for all four Trihalomethanes = 80 μ g/L For regulatory compliance, DBCP and EDB should be analyzed by Method E504.1, which has lower PQLs. E 500 series methods are appropriate only for drinking water analyses. For other waters, wastewaters or solids use the E600 or SW 8000 series methods.

CAS NO. MCL,

μ g/L PQL,

μ g/L CAS NO. MCL,

μ g/L PQL, μ g/L
Bromobenzene 108

- 86

- 1 NR 0.5 1,2

- Dichloroetha ne 107

- 06

- 2 5 0.5
Bromochloromethane 74

- 97

- 5 NR 0.5 1,1

- Dichloroethene 75

- 35

- 4 7 0.5
Bromodichloromethane 75

- 27

- 4 (See THM Note) 0.5 cis

- 1,2

- Dichloroethene 156

- 59

- 2 70 0.5
Bromoform 75

- 25

- 2 (See THM Note) 0.5 trans

- 1,2

- Dichloroethene 156

- 60

- 5 100 0.5
B romomethane 74

- 83

- 9 NR 0.5 1,2

- Dichloropropane 78

- 87

- 5 5 0.5
Carbon Tetrachloride 56

- 23

- 5 5 0.5 1,3

- Dichloropropane 142

- 28

- 9 NR 0.5
Chlorobenzene 108

- 90

- 7 100 0.5 1,1

- Dichloropropene 563

- 58

- 6 NR 0.5
Chloroethane 75

- 00

- 3 NR 0.5 Methylene Chloride (Dic hloromethane) 75

- 09

- 2 5 0.5

Chloroform 67

- 66

- 3 (See THM Note) 0.5 1,1,1,2

- Tetrachloroethane 630

- 20

- 6 NR 0.5
Chloromethane 74

- 87

- 3 NR 0.5 1,1,2,2

- Tetrachloroethane 79

- 34

- 5 NR 0.5
2

- Chlorotoluene 95

- 49

- 8 NR 0.5 Tetrachloroethene (Tetrachloroethylene) 127

- 18

- 4 5 0.5

Chlorodibromomethane 124

- 48

- 1 (See THM Note) 0.5 1,1,1

- Trichloroethane 71

- 55

- 6 200 0.5 1,2

- Dibromo

- 3

- chloropropane (DBCP) 96

- 12

- 8 0.02 (See Notes) 0.5 1,1,2

- Trichloroethane 79

- 00

- 5 5 0.5

Dibromoethane (EDB) 106

- 93

- 4 0.01 (See Notes) 0.5 T richloroethene (Trichloroethylene) 79

- 01

- 6 5 0.5

Dibromomethane 74

- 95

- 3 NR 0.5 Trichlorofluoromethane 75

- 69

- 4 NR 0.5 1,2

- Dichlorobenzene 95

- 50

- 1 NR 0.5 1,2,3

- Trichloropropane 96

- 18

- 4 NR 0.5 1,3

- Dichlorobenzene 541

- 73

- 1 600 0.5 Vinyl Chloride (Chl oroethene) 75

- 01

- 4 2 0.5

1,4

- Dichlorobenzene 106

- 46

- 7 75 0.5
Dichlorodifluoromethane 75

- 71

- 8 NR 0.5 1,1

- Dichloroethane 75

- 34

- 3 NR 0.5Version 2011.0.0 Prices subject to change. Visit www.energylab.com for up- to -date pricing. www.energylab.com 

### Organics - 9 

# ORGANIC CHEMISTRY
DESCRIPTION OF METHODS

Volatile Aromatic Compounds (Method E502.2/E524.2)
Sampling: 3

- 40 mL glass/teflon VOA vials completely full with no air bubbles. Store at6°C. Add ascorbic acid to chlorinated samples. Preserve with 5

- 10 drops hydrochloric acid to pH <2 (smaller blue capped ampule).

Holding Time: 14 days

Notes: MCL = Drinking Water MCL E500 series methods are appropriate only for drinking water analyses. For other waters, wastewaters or solids use the E600 or SW 8000 series methods.

CAS NO. MCL, μ g/L PQL, μ g/L CAS NO. MCL, μ g/L PQL μ g/L
Benzene 71

- 43

- 2 5 0.5 Naphthalene 9 1

- 20

- 3 NR 0.5
Bromobenzene 108

- 86

- 1 NR 0.5 n

- Propylbenzene 103

- 65

- 1 NR 0.5

n

- Butylbenzene 104

- 51

- 8 NR 0.5 Styrene 100

- 42

- 5 100 0.5

sec

- Butylbenzene 135

- 98

- 8 NR 0.5 Tetrachloroethene (Tetrachloroethylene) 127

- 18

- 4 5 0.5

tert

- Butylbenzene 98

- 06

- 6 NR 0 .5 Toluene 108

- 88

- 3 1000 0.5
Chlorobenzene 108

- 90

- 7 100 0.5 1,2,3

- Trichlorobenzene 87

- 61

- 6 NR 0.5
2

- Chlorotoluene 95

- 49

- 8 NR 0.5 1,2,4

- Trichlorobenzene 120

- 82

- 1 70 0.5
4

- Chlorotoluene 106

- 43

- 4 NR 0.5 Trichloroethene (Trichloroethylene) 79

- 01

- 6 5 0.5

1,2

- Dichlorobenzene 95

- 50

- 1 600 0.5 1,2,4

- Trimethylbenzene 95

- 63

- 6 NR 0.5 1,3

- Dichlorobenzene 541

- 73

- 1 NR 0.5 1,3,5

- Trimethylbenzene 108

- 67

- 8 NR 0.5 1,4

- Dichlorobenzene 106

- 46

- 7 75 0.5 Xylenes: 10000 0.5 Ethylbenzene 100

- 41

- 4 700 0.5 M 108

- 38

- 3
Hex achlorobutadiene 87

- 68

- 3 NR 0.5 P 106

- 42

- 3 Isopropylbenzene 98

- 82

- 8 NR 0.5 O 95

- 47

- 6

p

- Isopropyltoluene 99

- 87

- 6 NR 0.5



### Low Level EDB and DBCP (Method E504.1)
Sampling: 3

- 40mL glass/teflon VOA vials completely full with no air bubbles. Store a t6°C. Add 3 mg sodium thiosulfate to chlorinated and non

- chlorinated samples.

Holding Time: 14 days.

Notes: MCL = Drinking Water MCL E500 series methods are appropriate only for drinking water analyses. For other waters, wastewaters or solids use the E600 or SW 8000 series methods.

CAS NO. MCL,

μ g/L PQL,

μ g/L CAS NO. MCL,

μ g/L PQL,

μ g/L 1,2

- Dibromo

- 3

- Chloropropane (DBCP) 96

- 12

- 8 0.002 0.02 1,2

- Dibromoethane (Ethylene Dibromide) (EDB) 106

- 93

- 4 0.001 0.01

1,2,3,

- Trichloropropane 96

- 18

- 4 NR 0.05Version 2011.0.0 Prices subject to change. Visit www.energylab.com for up- to -date pricing. www.energylab.com 

### Organics - 10 

# ORGANIC CHEMISTRY
DESCRIPTION OF METHODS

Nitrogen, Phosphorus, and Sulfur Containing Pesticides (Method E507 Mod.)
Sampling: Water: 2

- 1000 mL glass/teflon bottles. Store at6°C. Add sodium thiosulfate to chlorinated samples.

Soil: 1 25 mL wide mouth glass jar. Store at6°C.

Holding Time: 14 days to extraction; 28 days to analysis

Notes: All analytes are analyzed and positively identified using a mass spectrometer detector in place of the nitrogen

- phosphorus detector specified.



 PQL



   PQL



 CAS NO. mg/Kg μ g/L CAS NO. mg/Kg μ g/L
Alachlor 15972

- 60

- 8 0.003 0.1 Metolachlor 51218

- 45

- 2 0.063 Ametryn 834

- 12

- 8 0.003 0.1 Metribuzin 21087

- 64

- 9 0.003 0.1
Atraton 1610

- 17

- 9 0.003 0.1 Mevinphos 7786

- 34

- 7 0.003 0.1
Atrazine 191 2

- 24

- 9 0.003 0.1 MGK

- 264 113

- 48

- 4 0.003 0.1
Benefin 1861

- 40

- 1 0.003 0.1 Molinate 2212

- 67

- 1 0.003 0.1
Bromacil 314

- 40

- 9 0.003 0.1 Napropamide 15299

- 99

- 7 0.003 0.1
Butachlor 23184

- 66

- 9 0.003 0.1 Norflurazon 27314

- 13

- 2 0.003 0.1 Butylate 2008

- 41

- 5 0.003 0 .1 Oxadiazon 19666

- 30

- 9 0.003 0.1
Carboxin 5234

- 68

- 5 0.003 0.1 Oxyfluorfen 42874

- 03

- 3 0.003 0.5 Chlorpropham 101

- 21

- 3 0.003 0.1 Pebulate 1114

- 71

- 2 0.003 0.1 Chlorpyrifos 2921

- 88

- 2 0.003 0.1 Pendimethalin 40487

- 42

- 1 0.003 0.1 Cyanazine 21725

- 46

- 2 0.003 0.1 Phorate 298

- 02

- 2 0.003 0.1 Cycloate 1134

- 23

- 2 0.003 0.1 Profluralin 26399

- 36

- 0 0.003 0.1
Diazinon 333

- 41

- 5 0.003 0.1 Prometon 1610

- 18

- 0 0.003 0.1
Dichlorvos 62

- 73

- 7 0.003 0.1 Prometryne 7287

- 19

- 6 0.003 0.1 Diphenamid 957

- 51

- 7 0.003 0.1 Pronamide 23 950

- 58

- 5 0.003 0.1
Disulfoton 298

- 04

- 4 0.003 0.1 Propachlor 1918

- 16

- 7 0.003 0.1
EPTC 759

- 94

- 4 0.003 0.1 Propazine 139

- 40

- 2 0.003 0.1
Ethalfluralin 55283

- 68

- 6 0.003 0.1 Simazine 122

- 34

- 9 0.003 0.1 Ethoprop 13194

- 48

- 4 0.003 0.1 Simetryn 1014

- 70

- 6 0.003 0 .1 Fenamiphos 22224

- 92

- 6 0.003 0.1 Stirofos 22248

- 79

- 9 0.003 0.1
Fenarimol 60168

- 88

- 9 0.017 0.5 Terbacil 5902

- 51

- 2 0.003 0.1
Fluridone 59756

- 60

- 4 0.003 0.1 Terbufos 13071

- 79

- 9 0.003 0.1
Fonofos 944

- 22

- 9 0.003 0.1 Terbutryn 886

- 50

- 0 0.003 0.1
Hexazinon e 51235

- 04

- 2 0.003 0.1 Triadimefon 43121

- 43

- 3 0.003 0.1 Isopropalin 33820

- 53

- 0 0.003 0.1 Triallate 2303

- 17

- 5 0.003 0.1
Malathion 121

- 7

- 5 0.3 0.1 Tricyclazole 41814

- 78

- 2 0.003 0.1 Merphos 150

- 50

- 5 0.003 0.1 Trifluralin 1582

- 09

- 8 0.003 0.1 Methyl paraoxo n 950

- 35

- 6 0.017 0.1 Vernolate 1929

- 77

- 7 0.003 0.1Version 2011.0.0 Prices subject to change. Visit www.energylab.com for up- to -date pricing. www.energylab.com 

### Organics - 11 

# ORGANIC CHEMISTRY
DESCRIPTION OF METHODS

Chlorinated Acid Herbicides (Method E515.1)
Sampling: 1

- 1000 mL glass/teflon bottle. Store at6°C. Add ascorbic acid or sodium thiosulfate to chlorinated.

Holding Time: 14 days to extraction; 28 days to analysis.

Notes: MCL = Drinking Water MCL E500 series methods are appropriate only for drinking water analyses. For other waters, wastewaters or solids use the E600 or SW 8000 series methods.

CAS N O. MCL, μ g/L PQL,

μ g/L CAS NO. MCL, μ g/L PQL,

μ g/L 2,4

- D 94

- 75

- 7 70 1.0 Dinoseb 88

- 85

- 7 7 1.0 2,4

- DB 94

- 82

- 6 NR 2.5 Pentachlorophenol (PCP) 87

- 86

- 5 1 0.10 Dalapon 75

- 99

- 0 200 10 Picloram 1918

- 02

- 1 500 0.50
Dicamba 1918

- 00

- 9 NR 0.25 2,4,5

- TP (Silvex) 9 3

- 72

- 1 50 0.20 Dichlorprop 120

- 36

- 5 NR 1.0



### Chlorinated Acid Herbicides (Method E515.1

- Long List)
Sampling: 1

- 1000 mL glass/teflon bottle. Store at6°C. Add ascorbic acid or sodium thiosulfate to chlorinated samples.

Holding Time: 14 days to extraction; 28 days to analysis.

Notes: MCL = Drinking Water MCL These compounds are only qualitatively identified.

CAS NO. MCL, μ g/L PQL, μ g/L CAS NO. MCL, μ g/L PQL,

μ g/L Acifluorfen 50594

- 66

- 6 NR 0.5 3,5

- Dichlorobenzoic acid 88

- 85

- 7 NR 0.5
Bent azon 25057

- 89

- 0 NR 2.5 Dichlorprop 87

- 86

- 5 NR 1.0
Chloramben 133

- 90

- 4 NR See Note Dinoseb 1918

- 02

- 1 7 1.0 2,4

- D 94

- 75

- 7 70 1.0 4

- Nitrophenol 93

- 72

- 1 NR 0.5 2,4

- DB 94

- 82

- 6 NR 2.5 Pentachlorophenol (PCP) 87

- 86

- 5 1 0.10 Dalapon 75

- 99

- 0 200 10 Picloram 191 8

- 02

- 1 500 0.50
DCPA acid metabolites 2136

- 79

- 0 NR See Note 2,4,5

- T 93

- 76

- 5 NR 0.1
Dicamba 1918

- 00

- 9 NR 0.25 2,4,5

- TP (Silvex) 93

- 72

- 1 50 0.20Version 2011.0.0 Prices subject to change. Visit www.energylab.com for up- to -date pricing. www.energylab.com 

### Organics - 12 

# ORGANIC CHEMISTRY
DESCRIPTION OF METHODS

Pesticides (Method E525.2

- Drinking Water List)
Sampling: 2

- 1000 mL glass bottles preserved with hydrochloric acid (large blue capped ampule) to a pH <2. Residual chlorine is reduced in the sample by the addition of 40

- 50 mg of sodium sulfite. Mix well to insure it is dissolved in the sample. It is very important that the sample be dechlorinated prior to adding acid to lower the pH. Store at6°C.

Holding Time: 14 days to extraction; 30 days to analysis.

Notes: MCL = Drinking Water MCL E500 series methods are appropriate only for drinking water analyses. For oth er waters, wastewaters or solids use the E600 or SW 8000 series methods.

CAS NO. MCL, μ g/L PQL, μ g/L CAS NO. MCL, μ g/L PQL, μ g/L

Alachlor 5972

- 60

- 8 2 0.1 Chlordane 57

- 74

- 9 2 1
Aldrin 309

- 00

- 2 NR 0.1 Dieldrin 60

- 57

- 1 NR 0.1
PCBs 0.5 Endrin 72

- 20

- 8 2 0.1
Aroclor 1016 12674

- 11

- 2 NR 0.08 gamma

- BHC (Lindane) 58

- 89

- 9 0.2 0.1
Aroclor 1221 11104

- 28

- 2 NR 2 Heptachlor 76

- 44

- 8 0.4 0.1
Aroclor 1232 11141

- 16

- 5 NR 0.5 Heptachlor epoxide 1024

- 57

- 3 0.2 0.1
Aroclor 1242 53469

- 21

- 9 NR 0.3 Hexachlorobenzene 118

- 74

- 1 1 0.1

Aroclor 1248 12672

- 29

- 6 NR 0.1 Hexa

chlorocyclopentadiene 77

- 74

- 4 50 0.1
Aroclor 1254 11097

- 69

- 1 NR 0.1 Methoxychlor 72

- 43

- 5 40 0.1
Aroclor 1260 11096

- 82

- 5 NR 0.2 Metolachlor 51218

- 45

- 2 NR 0.1
Atrazine 1912

- 24

- 9 3 0.1 Metribuzin 21087

- 64

- 9 NR 0.1 Benzo(a)pyrene 50

- 32

- 8 0.2 0.1 Propachlor 1918

- 16

- 7 NR 0.1 bis(2

- ethylhexyl)Adipate 103

- 23

- 1 400 0.5 Simazine 122

- 34

- 9 4 0.1 bis(2

- ethylhexyl) Phthalate 117

- 81

- 7 6 2 Toxaphene 8001

- 35

- 2 3 2
Butachlor 23184

- 66

- 9 NR 0.1Version 2011.0.0 Prices subject to change. Visit www.energylab.com for up- to -date pricing. www.energylab.com 

### Organics - 13 

# ORGANIC CHEMISTRY
DE SCRIPTION OF METHODS

Pesticides (Method E525.2

- Long List)
Sampling: 2

- 1000 mL glass bottles preserved with hydrochloric acid (large blue capped ampule) to a pH <2. Residual chlorine is reduced in the sample by the addition of 40

- 50 mg of sodium sulfit e. Mix well to insure it is dissolved in the sample. It is very important that the sample be dechlorinated prior to adding acid to lower the pH. Store at6°C.

Holding Time: 14 days to extraction; 30 days to analysis.

Notes: ** Compounds included on the State of Montana Drinking Water Pesticide List. MCL = Drinking Water MCL E500 series methods are appropriate only for drinking water analyses. For other waters, wastewaters or solids use the E600 or SW 8000 series methods.

CAS NO. MCL,

μ g/L PQL,

μ g /L CAS NO MCL,

μ g/L PQL,

μ g/L Acenaphthylene 208

- 96

- 8 NR 0.10 ** Di (2

- ethylhexyl) Adipate 103

- 23

- 1 400 0.50
** Alachlor 15972

- 60

- 8 2 0.10 Fluorene 86

- 73

- 7 NR 0.10
** Aldrin 309

- 00

- 2 NR 0.10 ** Heptachlor 76

- 44

- 8 0.4 0.10
Anthracene 120

- 12

- 7 NR 0.10 * * Heptachlor Epoxide 1024

- 57

- 3 0.2 0.10
** Atrazine 1912

- 24

- 9 3 0.10 Heptachlorobiphenyl 52663

- 71

- 5 NR 0.10 Benzo(a)anthracene 56

- 55

- 3 NR 0.10 ** Hexachlorobenzene 118

- 74

- 1 1 0.10 Benzo(b)fluoranthene 205

- 99

- 2 NR 0.10 Hexachlorobiphenyl 60145

- 22

- 4 NR 0. 10 Benzo(k)fluoranthene 207

- 08

- 9 NR 0.10 ** Hexachlorocyclopentadiene 77

- 47

- 4 50 0.50 Benzo(g h i)perylene 191

- 24

- 2 NR 0.10 Indeno(1 2 3

- cd)pyrene 193

- 39

- 5 NR 0.10 ** Benzo(a)pyrene 50

- 32

- 8 0.2 0.10 ** Lindane 58

- 89

- 9 0.2 0.10
** Butachlor 23184

- 66

- 9 N R 0.10 ** Methoxychlor 72

- 43

- 5 40 0.10 Butylbenzylphthalate 85

- 68

- 7 NR 0.10 ** Metolachlor 51218

- 45

- 2 NR 0.10 ** Alpha

- chlordane 5103

- 71

- 9 (Chlordane 0.10 ** Metribuzin 21087

- 64

- 9 NR 0.10
** Gamma

- chlordane 5103

- 74

- 2 MCL: 2) 0.10 Trans

- Nonachlor 21641

- 7 0

- 3 NR 0.10
2

- Chlorobiphenyl 2051

- 60

- 7 NR 0.10 Pentachlorobiphenyl 55215

- 17

- 3 NR 0.10 Chrysene 218

- 01

- 9 NR 0.10 Octachlorobiphenyl 40186

- 71

- 8 NR 0.10 Dibenzo(a h)anthracene 53

- 70

- 3 NR 0.10 Pentachlorophenol 87

- 86

- 5 1 1.0 2,3

- Dichlorobiphenyl 16605

- 91

- 7 NR 0.10 Phenanthrene 85

- 01

- 8 NR 0.10
** Dieldrin 60

- 57

- 1 NR 0.10 ** Propachlor 1918

- 16

- 7 NR 0.10 Diethylphthalate 84

- 66

- 2 NR 0.10 ** Pyrene 129

- 00

- 0 NR 0.10 ** Di(2

- ethylhexyl)Phthalate 117

- 81

- 7 6 2.0 Simazine 122

- 34

- 9 4 0.10 Dimethyl Phthalate 131

- 11

- 3 NR 0.10 Tetrachlorobiphenyl 2437

- 79

- 8 NR 0.10
Di

- n

- Butylphthalate 84

- 74

- 2 NR 0.10 ** Toxaphene 8001

- 35

- 2 3 0.10
** Endrin 72

- 20

- 8 2 0.10 2,4,5

- Trichlorobiphenyl 15862

- 07

- 4 NR 0.10Version 2011.0.0 Prices subject to change. Visit www.energylab.com for up- to -date pricing. www.energylab.com 

### Organics - 14 

# ORGANIC CHEMISTRY
DESCRIPTION OF METHODS

Regulated and Unregulated Volatile Organic Compounds (VOCs) (Method E524.2)
Sampling: 3

- 40 mL glass/teflon VOA vials completely full with no air bubbles. Store at6°C. Add ascorbic acid to chlorinated samples. Preserve with 5

- 10 drops hydrochloric acid to pH <2 (smaller blue
cap ped ampule).

Holding Time: 14 days

Notes: MCL = Drinking Water MCL EPA MCL for the Total for all four Trihalomethanes = 80 μ g/L For regulatory compliance, DBCP and EDB should be analyzed by EPA Method 504.1, which has lower PQLs. E500 series method s are appropriate only for drinking water analyses. For other waters, wastewaters or solids use the E600 or SW 8000 series methods.

Regulated VOCs CAS NO. MCL, μ g/L PQL* μ g/L Regulated VOCs CAS NO. MCL,

μ g/L PQL* μ g/L
Benzene 71

- 43

- 2 5 0.5 Styrene 100

- 42

- 5 100 0.5
Carbon Tetrachloride 56

- 23

- 5 5 0.5 Tetrachloroethene 127

- 18

- 4 5 0.5
Chlorobenzene 108

- 90

- 7 100 0.5 Toluene 108

- 88

- 3 1000 0.5 1,2

- Dichlorobenzene 95

- 50

- 1 600 0.5 1,2,4

- Trichlorobenzene 120

- 82

- 1 70 0.5 1,4

- Dichlorobenzene 106

- 46

- 7 75 0.5 1,1,1

- Trichloroethane 71

- 55

- 6 200 0.5 1,2

- Dichloroethane 107

- 06

- 2 5 0.5 1,1,2

- Trichloroethane 79

- 00

- 5 5 0.5 1,1

- Dichloroethene 75

- 35

- 4 7 0.5 Trichloroethene 79

- 01

- 6 5 0.5
cis

- 1,2

- Dichloroethene 156

- 59

- 2 70 0.5 Vinyl Chloride 75

- 01

- 4 2 0.5
trans

- 1,2

- Dichloro ethene 156

- 60

- 5 100 0.5 Xylenes: 10000 0.5 1,2

- Dichloropropane 78

- 87

- 5 5 0.5 M 108

- 38

- 3 Ethylbenzene 100

- 41

- 4 700 0.5 P 106

- 42

- 3 Methylene Chloride 75

- 09

- 2 5 0.5 0 95

- 47

- 6

Total Trihalomethanes CAS NO. MCL, μ g/L PQL μ g/L Total Trihalome thanes CAS NO. MCL,
μ g/L PQL μ g/L Bromodichloromethane 75

- 27

- 4 See Note 0.5 Chlorodibromomethane 124

- 48

- 1 See Note 0.5
Bromoform 75

- 25

- 2 See Note 0.5 Chloroform 67

- 66

- 3 See Note 0.5

Other EPA Listed VOCs CAS NO. MCL, μ g/L PQL μ g/L Other EPA Lis ted VOCs CAS NO. MCL,
μ g/L PQL μ g/L Bromobenzene 108

- 86

- 1 NR 0.5 1,3

- Dichloropropane 142

- 28

- 9 NR 0.5
Bromochloromethane 74

- 97

- 5 NR 0.5 cis

- 1,3

- Dichloropropene 10061

- 01

- 5 NR 0.5
Bromomethane 74

- 83

- 9 NR 0.5 trans

- 1,3

- Dichloropropene 10061

- 02

- 6 NR 0.5

n

- Butylbenzene 104

- 51

- 8 NR 0.5 2,2

- Dichloropropane 590

- 20

- 7 NR 0.5

sec

- Butylbenzene 135

- 98

- 8 NR 0.5 Hexachlorobutadiene 87

- 68

- 3 NR 0.5
tert

- Butylbenzene 98

- 06

- 6 NR 0.5 Isopropylbenzene 98

- 82

- 8 NR 0.5
Chloroethane 75

- 00

- 3 NR 0.5 p

- Isopropyltoluene 99

- 87

- 6 NR 0.5
Chloromethane 74

- 87

- 3 NR 0.5 Trichlorofluoromethane 75

- 69

- 4 NR 0.5
2

- Chlorotoluene 95

- 49

- 8 NR 0.5 Naphthalene 91

- 20

- 3 NR 0.5
4

- Chlorotoluene 106

- 43

- 4 NR 0.5 n

- Propylbenzene 103

- 65

- 1 NR 0.5 1,2

- Dibromo

- 3

- chloropropane (DBCP) 96

- 12

- 8 0.2 (S ee Note) 1 1,1,1,2

- Tetrachloroethane 630

- 20

- 6 NR 0.5

1,2

- Dibromoethane (EDB) 106

- 93

- 4 0.1 (See Note) 0.5 1,1,2,2

- Tetrachloroethane 79

- 34

- 5 NR 0.5

Dibromomethane 74

- 95

- 3 NR 0.5 Methyl

- t

- butyl ether 1634

- 04

- 4 NR 0.5 1,3

- Dichlorobenzene 541

- 73

- 1 NR 0.5 1,2 ,3

- Trichlorobenzene 87

- 61

- 6 NR 0.5
Dichlorodifluoromethane 75

- 71

- 8 NR 0.5 1,2,3

- Trichloropropane 96

- 18

- 4 NR 0.5 1,1

- Dichloroethane 75

- 34

- 3 NR 0.5 1,2,4

- Trimethylbenzene 95

- 63

- 6 NR 0.5 1,1

- Dichloropropene 563

- 58

- 6 NR 0.5 1,3,5

- Trimethylbenzene 108

- 67

- 8 N R 0.5Version 2011.0.0 Prices subject to change. Visit www.energylab.com for up- to -date pricing. www.energylab.com 

### Organics - 15 

# ORGANIC CHEMISTRY
DESCRIPTION OF METHODS

Volatile Organic Compounds (VOCs) (Method E524.2

- Long List)
Sampling: 3

- 40 mL glass/teflon VOA vials completely full with no air bubbles. Store at6°C. Add ascorbic acid to chlorinated samples. Preser ve with 5

- 10 drops hydrochloric acid to pH <2 (smaller blue capped ampule). Holding Time: 14 days

Notes: MCL = Drinking Water MCL EPA MCL Total for all four Trihalomethanes = 80 μ g/L For regulatory compliance, DBCP and EDB should be analyzed by Method E504.1, which has lower PQLs. E500 series methods are appropriate only for drinking water analyses. For other waters, wastewaters or solids use the E600 or SW 8000 series methods.

Regulated VOCs CAS NO. MCL,

μ g/L PQL,

μ g/L Regulated VOCs CAS NO. MCL,

μ g/L PQL,

μ g/L
Benzene 71

- 43

- 2 5 0.5 Styrene 100

- 42

- 5 100 0.5 Carbon Tetrachloride 56

- 23

- 5 5 0.5 Tetrachloroethene 127

- 18

- 4 5 0.5 Chlorobenzene 108

- 90

- 7 100 0.5 Toluene 108

- 88

- 3 1000 0.5 1,2

- Dichlorobenzene 95

- 50

- 1 600 0.5 1,2,4

- Trichlorobenzene 120

- 82

- 1 70 0.5 1,4

- Dichlorobenzene 106

- 46

- 7 75 0.5 1,1,1

- Trichloroethane 71

- 55

- 6 200 0.5 1,2

- Dichloroethane 107

- 06

- 2 5 0.5 1,1,2

- Trichloroethane 79

- 00

- 5 5 0.5 1,1

- Dichloroethene 75

- 35

- 4 7 0.5 Trichloroethene 79

- 01

- 6 5 0.5 cis

- 1,2

- Dichloroethene 156

- 59

- 2 70 0 .5 Vinyl Chloride 75

- 01

- 4 2 0.5 trans

- 1,2

- Dichloroethene 156

- 60

- 5 100 0.5 Xylenes: 10000 0.5 1,2

- Dichloropropane 78

- 87

- 5 5 0.5 M 108

- 38

- 3 Ethylbenzene 100

- 41

- 4 700 0.5 P 106

- 42

- 3 Methylene Chloride 75

- 09

- 2 5 0.5 0 95

- 47

- 6

Total Trihalo methanes CAS NO. MCL,
μ g/L PQL,

μ g/L Total Trihalomethanes CAS NO. MCL,
μ g/L PQL,

μ g/L
Bromodichloromethane 75

- 27

- 4 See Note 0.5 Chlorodibromomethane 124

- 48

- 1 See Note 0.5 Bromoform 75

- 25

- 2 See Note 0.5 Chloroform 67

- 66

- 3 See Note 0.5

Other EPA Listed VOCs CAS NO. MCL,
μ g/L PQL,

μ g/L Other EPA Listed VOCs CAS NO. MCL,
μ g/L PQL,

μ g/L
Acetone 67

- 64

- 1 NR 20 trans

- 1,3

- Dichloropropene 10061

- 02

- 6 NR 0.5 Acrylonitrile 107

- 13

- 1 NR 20 2,2

- Dichloropropane 590

- 20

- 7 NR 0.5 Allyl chloride 107

- 05

- 1 NR 10 Diethyl ether 60

- 29

- 7 NR 1.0 Bromobenzene 108

- 86

- 1 NR 0.5 Ethyl methacrylate 97

- 63

- 2 NR 10 Bromochloromethane 74

- 97

- 5 NR 0.5 Fluorotrichloromethane 75

- 69

- 4 NR 0.5 Bromomethane 74

- 83

- 9 NR 0.5 Hexachlorobutadiene 87

- 68

- 3 NR 0.5 2

- Butanone 78

- 93

- 3 NR 20 H exachloroethane 67

- 72

- 1 NR 10

n

- Butylbenzene 104

- 51

- 8 NR 0.5 2

- Hexanone 591

- 78

- 6 NR 10

sec

- Butylbenzene 135

- 98

- 8 NR 0.5 Isopropylbenzene 98

- 82

- 8 NR 0.5 tert

- Butylbenzene 98

- 06

- 6 NR 0.5 p

- Isopropyltoluene 99

- 87

- 6 NR 0.5 Carbon disulfide 75

- 15

- 0 NR 10 Me thacrylonitrile 126

- 98

- 7 NR 10 Chloroacetonitrile 107

- 14

- 2 NR 10 Methylacrylate 96

- 33

- 3 NR 10 1

- Chlorobutane 109

- 69

- 3 NR 10 Methyliodide (Iodomethane) 74

- 88

- 4 NR 1.0

Chloroethane 75

- 00

- 3 NR 0.5 Methylmethacrylate 80

- 62

- 6 NR 10 Chloromethane 74

- 87

- 3 NR 0.5 4

- Methyl

- 2

- pentanone 108

- 10

- 1 NR 10 2

- Chlorotoluene 95

- 49

- 8 NR 0.5 Methyl

- t

- butyl ether 1634

- 04

- 4 NR 1.0 4

- Chlorotoluene 106

- 43

- 4 NR 0.5 Naphthalene 91

- 20

- 3 NR 0.5 1,2

- Dibromo

- 3

- chloropropane (DBCP) 96

- 12

- 8 0.2 (See Note) 1 Nitrobenzene 98

- 95

- 3 NR 50

1,2

- Dibromoethane (EDB) 106

- 93

- 4 0.1 (See Note) 0.5 2

- Nitropropane 79

- 46

- 9 NR 20

Dibromomethane 74

- 95

- 3 NR 0.5 Pentachloroethane 76

- 01

- 7 NR 10 1,3

- Dichlorobenzene 541

- 73

- 1 NR 0.5 Propionitrile 107

- 12

- 0 NR 20 trans

- 1,4

- Dichloro

- 2

- butene 110

- 57

- 6 NR 1 .0 n

- Propylbenzene 103

- 65

- 1 NR 0.5 Dichlorodifluoromethane 75

- 71

- 8 NR 0.5 1,1,1,2

- Tetrachloroethane 630

- 20

- 6 NR 0.5 1,1

- Dichloroethane 75

- 34

- 3 NR 0.5 1,1,2,2

- Tetrachloroethane 79

- 34

- 5 NR 0.5 1,1

- Dichloropropanone 513

- 88

- 2 NR 20 Tetrahydrofuran 109

- 99

- 9 NR 50 1,1

- Dichloropropene 563

- 58

- 6 NR 0.5 1,2,3

- Trichlorobenzene 87

- 61

- 6 NR 0.5 1,3

- Dichloropropane 142

- 28

- 9 NR 0.5 1,2,3

- Trichloropropane 96

- 18

- 4 NR 0.5 cis

- 1,3

- Dichloropropene 10061

- 01

- 5 NR 0.5 1,2,4

- Trimethylbenzene 95

- 63

- 6 NR 0.5 1,3,5

- Trimethy lbenzene 108

- 67

- 8 NR 0.5Version 2011.0.0 Prices subject to change. Visit www.energylab.com for up- to -date pricing. www.energylab.com 

### Organics - 16 

# ORGANIC CHEMISTRY
DESCRIPTION OF METHODS

Carbamates (Method E531.1)
Sampling: 3

- 40 mL glass/teflon VOA vials or 1

- 60 mL vial. The bottle must not be prerinsed with sample. Samples must be preserved at pH 3 with monochloro

- ac etic acid buffer (1.2 mL/40 mL VOA vial). Store at6°C. Add sodium thiosulfate to chlorinated samples.

Holding Time: 28 days

Note: MCL = Drinking Water MCL E500 series methods are appropriate only for drinking water analyses

CAS NO. MCL,
μ g/L P QL,
μ g/L CAS NO. MCL,
μ g/L PQL
μ g/L Aldicarb Sulfone 1646

- 88

- 4 2 1.0 3

- Hydroxycarbofuran 16655

- 82

- 6 NR 1.0 Aldicarb Sulfoxide NA 4 1.0 Methiocarb (Mesurol®) 2032

- 65

- 7 NR 1.0 Aldicarb (Temik®) 116

- 06

- 3 3 1.0 Methomyl (Lannate®) 16752

- 77

- 5 NR 1.0 Carbar yl (Sevin®) 63

- 25

- 2 NR 1.0 Oxamyl (Vydate®) 23135

- 22

- 0 200 1.0 Carbofuran (Furadan®) 1563

- 66

- 2 40 1.0 Propoxur (Baygon®) 114

- 26

- 1 NR 1.0



### Glyphosate (Method E547)
Sampling: 1

- 40 mL glass VOA vial. Store at6°C. Add sodium thiosulfate to chlorinated samp les.

Note: E500 series methods are appropriate only for drinking water analyses

Holding Time CAS NO. Drinking Water MCL, μ g/L PQL, μ g/L
14 days 1071

- 83

- 6 700 10



### Endothall (Method E548.1)
Sampling: 1

- 1000 mL glass bottle. Store at6°C. Add sodiu m thiosulfate to chlorinated samples.

Note: E500 series methods are appropriate only for drinking water analyses

Holding Time CAS NO. Drinking Water MCL, μ g/L PQL, μ g/L
7 days to extraction 145

- 73

- 3 100 20
14 days to analysis



### Diquat (Metho d E549.1)
Sampling: 2

- 1000 mL plastic or PVC bottles. Store at6°C. Add sodium thiosulfate to chlorinated samples.

Note: E500 series methods are appropriate only for drinking water analyses

Holding Time CAS NO. Drinking Water MCL, μ g/L PQL, μ g/L
7 days to extraction 85

- 00

- 7 20 2.0
21 days to analysisVersion 2011.0.0 Prices subject to change. Visit www.energylab.com for up- to -date pricing. www.energylab.com 

### Organics - 17 

# ORGANIC CHEMISTRY
DESCRIPTION OF METHODS

Haloacetic Acids (Method E552.2)
Sampling: 3

- 40 mL amber glass VOA vials. Store at6°C in dark. Vials are pre

- preserved with NH 4 

### Cl.

Holding Time: 14 days to extraction (if preserved with NH 4 

### Cl); 14 days to analysis.

Note: Drinking Water MCL: 60 μ g/L total of all five regulated Haloacetic Acids. Determination of Haloacetic Acids in drinking water by Liquid

- Liquid Extraction, Derivitization,

an d Gas Chromatography with Electron Capture Detection. E500 series methods are appropriate only for drinking water analyses

CAS NO. PQL μ g/L CAS NO. PQL μ g/L Bromochloroacetic Acid 5589

- 96

- 3 0.5 (NR) Monobromoacetic Acid 79

- 08

- 3 0.5 Dibromoacetic Acid 631

- 64

- 1 0.25 Monochloroacetic Acid 79

- 11

- 8 0.75 Dichloroacetic Acid 79

- 43

- 6 0.75 Trichloroacetic Acid 76

- 03

- 9 0.25



### Purgeable Halocarbons (POX) (Method E601/E624/SW 8021B/SW 8260B)
Sampling: Water: 4

- 40 mL (2 preserved samples in glass and 2 unpreserv ed samples in Teflon) VOA vials completely full with no air bubbles. Store at 

# ≤ 6 ° C. Add ascorbic acid to chlorinated samples. Preserve with 5

- 10 drops hydrochloric acid to pH <2 except the Acrolein and Acroylontirile compound which require a pH of 4

- 5.

Soil: 125 mL wide mouth glass jar. Store at6°C.

Holding Time: 14 days

  PQL



   PQL



 CAS NO. μ g/L mg/Kg CAS NO. μ g/L mg/Kg Bromodichloromethane 75

- 27

- 4 1.0 0.2 1,1

- Dichloroethene 75

- 35

- 4 1.0 0.2
Bromoform 75

- 25

- 2 1.0 0.2 Cis

- 1,2

- Dic hloroethene 156

- 59

- 4 1.0 0.2
Bromomethane 74

- 83

- 9 1.0 0.2 trans

- 1,2

- Dichloroethene 156

- 60

- 5 1.0 0.2
Carbon Tetrachloride 56

- 23

- 5 1.0 0.2 1,2

- Dichloropropane 78

- 87

- 5 1.0 0.2
Chlorobenzene 108

- 90

- 7 1.0 0.2 Cis

- 1,3

- Dichloropropene 10061

- 01

- 5 1.0 0.2
Chlor oethane 75

- 00

- 3 1.0 0.2 trans

- 1,3

- Dichloropropene 10061

- 02

- 6 1.0 0.2
2

- Chloroethyl Vinyl Ether 110

- 75

- 8 1.0 0.2 Methylene Chloride 75

- 09

- 2 1.0 0.2
Chloroform 67

- 66

- 3 1.0 0.2 (Dichloromethane)
Chloromethane 74

- 87

- 3 1.0 0.2 1,1,2,2

- Tetrachloroethane 79

- 34

- 5 1.0 0.2
2

- Chlorotoluene 95

- 49

- 8 1.0 0.2 Tetrachloroethene 127

- 18

- 4 1.0 0.2
Chlorodibromomethane 124

- 48

- 1 1.0 0.2 (Tetrachloroethylene) 1,2

- Dichlorobenzene 95

- 50

- 1 1.0 0.2 1,1,1

- Trichloroethane 71

- 55

- 6 1.0 0.2 1,3

- Dichlorobenzene 541

- 73

- 1 1.0 0.2 1,1,2

- Trichloroethane 79

- 00

- 5 1.0 0.2 1,4

- Dichlorobenzene 106

- 46

- 7 1.0 0.2 Trichloroethene 79

- 01

- 6 1.0 0.2
Dichlorodifluoromethane 75

- 71

- 8 1.0 0.2 (Trichloroethylene) 1,1

- Dichloroethane 75

- 34

- 3 1.0 0.2 Trichlorofluoromethane 75

- 69

- 4 1.0 0 .2 1,2

- Dichloroethane 107

- 06

- 2 1.0 0.2 Vinyl Chloride (Chloroethene) 75

- 01

- 4 1.0 0.2Version 2011.0.0 Prices subject to change. Visit www.energylab.com for up- to -date pricing. www.energylab.com 

### Organics - 18 

# ORGANIC CHEMISTRY
DESCRIPTION OF METHODS

Purgeable Aromatics (Method E602/E624/SW 8021B/SW 8260B)
Sampling: Water: 3

- 40 mL (2 preserved samples in glass and 2 unpres erved samples in Teflon) VOA vials completely full with no air bubbles. Store at 

# ≤ 6 ° C. Add ascorbic acid to chlorinated samples. Preserve with 5

- 10 drops hydrochloric acid to pH <2 except the Acrolein and Acroylontirile compound which require a pH of 4

- 5.

Soil: 125 mL wide mouth glass jar. Store at6°C.

Holding Time: 14 days

  PQL



   PQL



 CAS NO. μ g/L mg/Kg CAS NO. μ g/L mg/Kg
Benzene 71

- 43

- 2 1.0 0.2 Ethylbenzene 100

- 41

- 4 1.0 0.2 Chlorobenzene 108

- 90

- 7 1.0 0.2 Toluene 108

- 88

- 3 1.0 0 .2 1,2

- Dichlorobenzene 95

- 50

- 1 1.0 0.2 Xylenes:

- 1.0 0.2 1,3

- Dichlorobenzene 541

- 73

- 1 1.0 0.2 M 108

- 38

- 3 1,4

- Dichlorobenzene 106

- 46

- 7 1.0 0.2 P 106

- 42

- 3 O 95

- 47

- 6



### Benzene, Toluene, Ethylbenzene and Xylenes (BTEX) (Method E602/SW 8021B or E 624/SW 8260B)
Sampling: Water: 3

- 40 mL glass VOA vials with no air bubbles. Store at6°C. Add ascorbic acid to chlorinated samples. Preserve with 5

- 10 drops hydrochloric acid to pH <2.

Soil: 125 mL wide mouth glass jar. Store at6°C.

Holding Ti me: 14 days

Note: The PQL for BTEX in air is 2.5 mg/m 3 

### ; for MTBE it is 10 mg/m 3



### .



 PQL



   PQL



 CAS NO. μ g/L mg/Kg CAS NO. μ g/L mg/Kg
Benzene 71

- 43

- 2 0.5 0.2 Xylenes

- 1.0 0.2 Toluene 108

- 88

- 3 0.5 0.2 M 108

- 38

- 3 Ethylbenzene 100

- 41

- 4 0.5 0.2 P 106

- 42

- 3 MTBE 1634

- 04

- 4 2 0.8 O 95

- 47

- 6Version 2011.0.0 Prices subject to change. Visit www.energylab.com for up- to -date pricing. www.energylab.com 

### Organics - 19 

# ORGANIC CHEMISTRY
DESCRIPTION OF METHODS

Organochlorine Pesticides and PCBs (Method E608 or SW 8081A+SW 8082)
Sampling: Water: 1

- 1000 mL glass/teflon bottle. Store at6°C. Add sodium thiosulfate to chlorinated samples.

Soil: 125 mL wide mouth glass jar. Store at6°C.

Holding Time: 7(water) or 14(soil) days to extraction; 40 days to analysis



 PQL



   PQL



 CAS NO. μ g/L mg/Kg CAS NO. μ g/L mg/Kg
Aldrin 309

- 00

- 2 0.050 0.0017 Endrin 72

- 20

- 8 0.050 0.0017 alpha

- BHC 319

- 84

- 6 0.050 0.0017 Endrin Aldehyde 7421

- 93

- 4 0.050 0.0017
beta

- BHC 319

- 85

- 7 0.050 0.0017 Heptachlor 76

- 44

- 8 0.050 0.0017
delta

- BHC 319

- 86

- 8 0.050 0.0017 Heptachlor Epoxide 1024

- 57

- 3 0.050 0.0017

gamma

- BHC (Lindane) 58

- 89

- 9 0.050 0.0017 Isodrin 465

- 73

- 6 0.050 0.0017 alpha

- Chlordane 5103

- 71

- 9 0.050 0.0017 Kepone 143

- 50

- 0 0.10 0.0033

gamma

- Chlordane 5103

- 74

- 2 0.050 0.0017 Methoxychlor 72

- 43

- 5 0.050 0.0017 4,4'

- DDD 72

- 54

- 8 0.050 0.0017 Chlordane (technical) 57

- 74

- 9 0.50 0. 017 4,4'

- DDE 72

- 55

- 9 0.050 0.0017 Toxaphene 8001

- 35

- 2 5.0 0.167 4,4'

- DDT 50

- 29

- 3 0.050 0.0017 PCBs
Dieldrin 60

- 57

- 1 0.050 0.0017 Aroclor

- 1016 12674

- 11

- 2 1.0 0.033
Endosulfan I 959

- 98

- 8 0.050 0.0017 Aroclor

- 1221 11104

- 28

- 2 2.0 0.067
Endosulfan II 33 213

- 65

- 9 0.050 0.0017 Aroclor

- 1232 11141

- 16

- 5 1.0 0.033
Endosulfan Sulfate 1031

- 07

- 8 0.050 0.0017 Aroclor

- 1242 53469

- 21

- 9 1.0 0.033
Aroclor

- 1248 12672

- 29

- 6 1.0 0.033
Aroclor

- 1254 11097

- 69

- 1 1.0 0.033
Aroclor

- 1260 11096

- 82

- 5 1.0 0.033



### Orga nochlorine Pesticides (Method E608/SW 8081A)
Sampling: Water: 1

- 1000 mL glass/teflon bottle. Store at6°C. Add sodium thiosulfate to chlorinated samples.

Soil: 125 Ml wide mouth glass jar. Store at6°C.

Holding Time: 7(water) or 14(soil) days to extraction; 40 days to analysis



 PQL



   PQL



 CAS NO. μ g/L mg/Kg CAS NO. μ g/L mg/Kg
Aldrin 309

- 00

- 2 0.050 0.0017 Endrin 72

- 20

- 8 0.050 0.0017 alpha

- BHC 319

- 84

- 6 0.050 0.0017 Endrin Aldehyde 7421

- 93

- 4 0.050 0.0017
beta

- BHC 319

- 85

- 7 0.050 0.001 7 Endrin Ketone 53494

- 70

- 5 0.050 0.0017
delta

- BHC 319

- 86

- 8 0.050 0.0017 Heptachlor 76

- 44

- 8 0.050 0.0017

gamma

- BHC (Lindane) 58

- 89

- 9 0.050 0.0017 Heptachlor Epoxide 1024

- 57

- 3 0.050 0.0017 alpha

- Chlordane 5103

- 71

- 9 0.050 0.0017 Isodrin 465

- 73

- 6 0.050 0.00 17

gamma

- Chlordane 5103

- 74

- 2 0.050 0.0017 Kepone 143

- 50

- 0 0.10 0.0033 4,4'

- DDD 72

- 54

- 8 0.050 0.0017 Methoxychlor 72

- 43

- 5 0.050 0.0017 4,4'

- DDE 72

- 55

- 9 0.050 0.0017 Chlordane (technical) 57

- 74

- 9 0.50 0.017 4,4'

- DDT 50

- 29

- 3 0.050 0.0017 Toxaphene 8001

- 35

- 2 5.0 0.167
Dieldrin 60

- 57

- 1 0.050 0.0017
Endosulfan I 959

- 98

- 8 0.050 0.0017
Endosulfan II 33213

- 65

- 9 0.050 0.0017
Mirex 2385

- 85

- 5 0.050 0.0017
Endosulfan Sulfate 1031

- 07

- 8 0.050 0.0017Version 2011.0.0 Prices subject to change. Visit www.energylab.com for up- to -date pricing. www.energylab.com 

### Organics - 20 

# ORGANIC CHEMISTRY
DESCRIPTION OF METHODS

Polychlorinated Biphenyls (PCBs) (Method SW 8082)
Sampling: Water: 1

- 1000 mL glass/teflon bottle. Store at6°C. Add sodium thiosulfate to chlorinated samples.

Soil: 125 mL wide mouth glass jar. Store at6°C.

Transformer Oil: 4 dram vial

H olding Time: 7(water) or 14(soil) days to extraction; 40 days to analysis



 PQL



 Transformer Oil
PCBs CAS NO. μ g/L mg/Kg mg/Kg
Aroclor

- 1016 12674

- 11

- 2 0.50 0.017 2.0
Aroclor

- 1221 11104

- 28

- 2 1.0 0.033 2.0
Aroclor

- 1232 11141

- 16

- 5 0.50 0.017 2.0
Aro clor

- 1242 53469

- 21

- 9 0.50 0.017 2.0
Aroclor

- 1248 12672

- 29

- 6 0.50 0.017 2.0
Aroclor

- 1254 11097

- 69

- 1 0.50 0.017 2.0
Aroclor

- 1260 11096

- 82

- 5 0.50 0.017 2.0
Aroclor

- 1262 37324

- 23

- 5 0.50 0.017 2.0
Aroclor

- 1268 11100

- 14

- 4 0.50 0.017 2.0



### Chlorinated Herbic ides (Method E615/SW 8151A)
Sampling: Water: 1

- 1000 mL glass/teflon bottle. Store at6°C. Add ascorbic acid to chlorinated samples.

Soil: 125 mL wide mouth glass/teflon jar. Store at6°C.

Waste: 125 mL wide mouth glass/teflon jar. Store at6°C.

Holding Time: 7(water) or 14(soil) days to extraction; 40 days to analysis



 PQL



   PQL



 CAS NO. μ g/L mg/Kg CAS NO. μ g/L mg/Kg 2,4

- D 94

- 75

- 7 1.0 0.020 Dinoseb 88

- 85

- 7 1.0 0.02 2,4

- DB 94

- 82

- 6 1.0 0.020 2,4,5

- TP (Silvex) 93

- 72

- 1 0.20 0.004 Dalapon 75

- 99

- 0 10 0.2 2,4,5

- T 93

- 76

- 1 0.20 0.004
Dicamba 1918

- 00

- 9 0.25 0.005 MCPA 94

- 74

- 6 250 5 Dichlorprop 120

- 36

- 5 1.0 0.02 MCPP 93

- 65

- 2 250 5 Pentachlorophenol 87

- 86

- 5 0.10 0.002



### Acrolein (E624/SW 8260B)
Sampling: Water: 3

- 40 mL VOA vials. Unpreserved (raw), chilled to 6 ° C and analyzed within 3 days of
collection. Or, pH adjusted to 4

- 5 with HCL, chilled to 6 ° C, and analyzed within 14 days. Add ascorbic acid to chlorinated samples. The vials must be completely full with no air bubbles. Store at 6 ° C. Contact the laboratory prior to sampling to arrange for this analysis.

Soil: 125 mL wide mouth glass jar. Store at6°C.

Holding Time: 14 days (3 days for unpreserved Acrolein)



 PQL



   PQL



 CAS NO. μ g/L mg/Kg CAS NO. μ g/L mg/Kg Acrolein 107

- 02

- 8 20 4.0 Acrylonitrile 107

- 13

- 1 20 4.0Version 2011.0.0 Prices subject to change. Visit www.energylab.com for up- to -date pricing. www.energylab.com 

### Organics - 21 

# ORGANIC CHEMISTRY
DESCRIPTION OF METHODS

Purgeable Organics (VOCs) by GC/MS (Method E624/SW 8260B

- Short List)
Sampling: Water: 3

- 40 mL (2 preserved samples in glass and 2 unpreserved samp les in Teflon) VOA vials completely full with no air bubbles. Store at 

# ≤ 6 ° C. Add ascorbic acid to chlorinated samples. Preserve with 5

- 10 drops hydrochloric acid to pH <2 except the Acrolein and Acroylontirile compound which require a pH of 4

- 5.

S oil: 125 mL wide mouth glass jar. Store at6°C.

Holding Time: 14 days

Note: Method SW 8260B is the capillary column equivalent to Method SW 8240



 PQL



   PQL



 CAS NO. μ g/L mg/Kg CAS NO. μ g/L mg/Kg
Benzene 71

- 43

- 2 1.0 0.20 2,2

- Dichloro propane 594

- 20

- 7 1.0 0.20
Bromobenzene 108

- 86

- 1 1.0 0.20 1,1

- Dichloropropene 563

- 58

- 6 1.0 0.20
Bromochloromethane 74

- 97

- 5 1.0 0.20 cis

- 1,3

- Dichloropropene 10061

- 01

- 5 1.0 0.20
Bromodichloromethane 75

- 27

- 4 1.0 0.20 trans

- 1,3

- Dichloropropene 10061

- 02

- 6 1.0 0.20
Bromoform 75

- 25

- 2 1.0 0.20 Ethylbenzene 100

- 41

- 4 1.0 0.20
Bromomethane 74

- 83

- 9 1.0 0.20 Methyl

- t

- butyl ether 1634

- 04

- 4 1.0 0.20
Carbon Tetrachloride 56

- 23

- 5 1.0 0.20 Methylene Chloride 75

- 09

- 2 1.0 0.20
Chlorobenzene 108

- 90

- 7 1.0 0.20 (Dichlor omethane)
Chloroethane 75

- 00

- 3 1.0 0.20 Methyl Ethyl Ketone 78

- 93

- 3 20 4.0
2

- Chloroethyl Vinyl Ether 110

- 75

- 8 1.0 0.20 (2

- Butanone)
Chloroform 67

- 66

- 3 1.0 0.20 Styrene 100

- 42

- 5 1.0 0.20
Chloromethane 74

- 87

- 3 1.0 0.20 1,1,1

- 2

- Tetrachloroethane 630

- 20

- 6 1.0 0.20
2

- Chlorotoluene 95

- 49

- 8 1.0 0.20 1,1,2,2

- Tetrachloroethane 79

- 34

- 5 1.0 0.20
4

- Chlorotoluene 106

- 43

- 4 1.0 0.20 Tetrachloroethene 127

- 18

- 4 1.0 0.20
Chlorodibromomethane 124

- 48

- 1 1.0 0.20 (Tetrachloroethylene) 1,2

- Dibromoethane 10 6

- 93

- 4 1.0 0.20 Toluene 108

- 88

- 3 1.0 0.20
Dibromomethane 74

- 95

- 3 1.0 0.20 1,1,1

- Trichloroethane 71

- 55

- 6 1.0 0.20 1,2

- Dichlorobenzene 95

- 50

- 1 1.0 0.20 1,1,2

- Trichloroethane 79

- 00

- 5 1.0 0.20 1,3

- Dichlorobenzene 541

- 73

- 1 1.0 0.20 Trichloroethene 79

- 01

- 6 1. 0 0.20 1,4

- Dichlorobenzene 106

- 46

- 7 1.0 0.20 (Trichloroethylene)
Dichlorodifluoromethane 75

- 71

- 8 1.0 0.20 Trichlorofluoromethane 75

- 69

- 4 1.0 0.20 1,1

- Dichloroethane 75

- 34

- 3 1.0 0.20 1,2,3

- Trichloropropane 96

- 18

- 4 1.0 0.20 1,2

- Dichloroethane 107

- 0 6

- 2 1.0 0.20 Vinyl Chloride 75

- 01

- 4 1.0 0.20 1,1

- Dichloroethene 75

- 35

- 4 1.0 0.20 (Chloroethene)
cis

- 1,2

- Dichloroethene 156

- 59

- 2 1.0 0.20 Benzene 71

- 43

- 2 1.0 0.20
trans

- 1,2

- Dichloroethene 156

- 60

- 5 1.0 0.20 Ethylbenzene 100

- 41

- 4 1.0 0.20 1,2

- Dichlo ropropane 78

- 87

- 5 1.0 0.20 Toluene 108

- 88

- 3 1.0 0.20 1,3

- Dichloropropane 142

- 28

- 9 1.0 0.20 Xylenes:

- 1.0 0.20
meta

- 108

- 38

- 3
Para

- 106

- 42

- 3
ortho

- 95

- 47

- 6Version 2011.0.0 Prices subject to change. Visit www.energylab.com for up- to -date pricing. www.energylab.com 

### Organics - 22 

# ORGANIC CHEMISTRY
DESCRIPTION OF METHODS

Purgeable Organics (VOCs) by GC/M S (Method SW 8260B

- Long List)
Sampling: Water: 3

- 40 mL glass/teflon VOA vials

. Add 3

- 5 drops of HCl

.

For Acrolein take an additional 3

- 40 mL VOA vials. Unpreserved (raw) and analyzed within 3 days of collection. Or, pH adjusted to 4

- 5 with HCL, a nd analyzed within 14 days. Contact the laboratory prior to sampling to arrange for this analysis. Add sodium thiosulfate or ascorbic acid to chlorinated samples. The vials must be completely full with no air bubbles. Store at 6 ° C.

Soil: 125 mL wide mouth glass jar. Store at6°C

Holding Time: 14 days (3 days for unpreserved Acrolein)

Note: Method SW 8260B is the capillary column equivalent to Method SW 8240



 PQL



   PQL



 CAS NO. μ g/L mg/Kg CAS NO. μ g/L mg/Kg
Acetone 67

- 64

- 1 5 0 10 2,2

- Dichloropropane 594

- 20

- 7 1.0 0.20
Acetonitrile 75

- 08

- 8 20 4.0 1,1

- Dichloropropene 563

- 58

- 6 1.0 0.20
Acolein 107

- 02

- 8 20 4.0 cis

- 1,3

- Dichloropropene 10061

- 01

- 5 1.0 0.20 Acrylonitrile 107

- 13

- 1 20 4.0 trans

- 1,3

- Dichloropropene 10061

- 02

- 6 1.0 0.20
Benzene 71

- 43

- 2 1.0 0.20 Ethylbenzene 100

- 41

- 4 1.0 0.20
Bromobenzene 108

- 86

- 1 1.0 0.20 Hexachlorobutadiene 87

- 68

- 3 1.0 0.20
Bromochloromethane 74

- 97

- 5 1.0 0.20 2

- Hexanone 591

- 78

- 6 20 4.0
Bromodichloromethane 75

- 27

- 4 1.0 0.20 Iodomethane 74

- 88

- 4 1.0 0.2 0
Bromoform 75

- 25

- 2 1.0 0.20 Isopropylbenzene 98

- 82

- 8 1.0 0.20
Bromomethane 74

- 83

- 9 1.0 0.20 p

- Isopropyltoluene 99

- 87

- 6 1.0 0.20

n

- Butylbenzene 104

- 51

- 8 1.0 0.20 Methyl

- t

- butyl ether 1634

- 04

- 4 1.0 0.20

sec

- Butylbenzene 135

- 98

- 8 1.0 0.20 Methyl Ethyl Ke tone 78

- 93

- 3 20 4.0
tert

- Butylbenzene 98

- 06

- 6 1.0 0.20 (2

- Butanone)
Carbon Disulfide 75

- 15

- 0 1.0 0.20 Methyl Isobutyl Ketone 108

- 10

- 1 20 4.0
Carbon Tetrachloride 56

- 23

- 5 1.0 0.20 (4

- Methyl

- 2

- pentanone)
Chlorobenzene 108

- 90

- 7 1.0 0.20 Methy lene Chloride 75

- 09

- 2 1.0 0.20
Chloromethane 124

- 48

- 1 1.0 0.20 (Dichloromethane)
Chloroethane 75

- 00

- 3 1.0 0.20 Naphthalene 91

- 20

- 3 1.0 0.20
2

- Chloroethyl Vinyl Ether 110

- 75

- 8 1.0 0.20 n

- Propylbenzene 103

- 65

- 1 1.0 0.20
Chloroform 67

- 66

- 3 1.0 0.20 Styrene 100

- 42

- 5 1.0 0.20
Chloromethane 74

- 87

- 3 1.0 0.20 Tetrachloroethene 127

- 18

- 4 1.0 0.20 (Tetrachloroethylene)
2

- Chlorotoluene 95

- 49

- 8 1.0 0.20 1,1,1,2

- Tetrachloroethane 630

- 20

- 6 1.0 0.20
4

- Chlorotoluene 106

- 43

- 4 1.0 0.20 1,1,2,2

- Tetrachl oroethane 79

- 34

- 5 1.0 0.20 1,2

- Dibromo

- 3

- chloropropane (DBCP) 96

- 12

- 8 1.0 0.20 1,2,3

- Trichlorobenzene 87

- 61

- 6 1.0 0.20 1,2

- Dibromoethane (EDB) 106

- 93

- 4 1.0 0.20 1,2,4

- Trichlorobenzene 120

- 82

- 1 1.0 0.20
Dibromomethane 74

- 95

- 3 1.0 0.20 1,1,1

- Trichloroetha ne 71

- 55

- 6 1.0 0.20 1,2

- Dichlorobenzene 95

- 50

- 1 1.0 0.20 1,1,2

- Trichloroethane 79

- 00

- 5 1.0 0.20 1,3

- Dichlorobenzene 541

- 73

- 1 1.0 0.20 Trichloroethene 1,4

- Dichlorobenzene 106

- 46

- 7 1.0 0.20 (Trichloroethylene) 79

- 01

- 6 1.0 0.20
Dichlorodifluoromethane 75

- 71

- 8 1.0 0.20 Trichlorofluoromethane 75

- 69

- 4 1.0 0.20 1,1

- Dichloroethane 75

- 34

- 3 1.0 0.20 1,2,3

- Trichloropropane 96

- 18

- 4 1.0 0.20 1,2

- Dichloroethane 107

- 06

- 2 1.0 0.20 1,2,4

- Trimethylbenzene 95

- 63

- 6 1.0 0.20 1,1

- Dichloroethene 75

- 35

- 4 1.0 0.20 1,3,5

- T rimethylbenzene 108

- 67

- 8 1.0 0.20
cis

- 1,2

- Dichloroethene 156

- 59

- 2 1.0 0.20 Toluene 108

- 88

- 3 1.0 0.20
trans

- 1,2

- Dichloroethene 156

- 60

- 5 1.0 0.20 Vinyl Acetate 108

- 05

- 4 1.0 0.20 1,2

- Dichloropropane 78

- 87

- 5 1.0 0.20 Vinyl Chloride 1,3

- Dichloropropane 1 42

- 28

- 9 1.0 0.20 (Chloroethene) 75

- 01

- 4 1.0 0.20 Xylenes: 1.0 0.20
meta

- 108

- 38

- 3

para

- 106

- 42

- 3
ortho

- 95

- 47

- 6Version 2011.0.0 Prices subject to change. Visit www.energylab.com for up- to -date pricing. www.energylab.com 

### Organics - 23 

# ORGANIC CHEMISTRY
DESCRIPTION OF METHODS

Semi

- Volatile Organics (SVOCs) by GC/MS (Method E625/SW 8270C)
Sampling : Water: 2

- 1000 mL glass/teflon bottles. Store at6°C. Add 80 mg sodium thiosulfate to chlorinated samples.

Soil: 125 mL wide mouth glass jar. Store at6°C.

Holding Time: 7(water) or 14(soil) days to extraction; 40 days to analysis

ACID EXTRACT ABLES

  PQL



   PQL



 CAS NO. μ g/L mg/Kg CAS NO. μ g/L mg/Kg
4

- Chloro

- 3

- methylphenol 4,6

- Dinitro

- 2

- methylphenol (p

- Chloro

- m

- cresol) 59

- 50

- 7 10 0.33 (4,6

- Dinitro

- o

- cresol) 534

- 52

- 1 50 1.65
2

- Chlorophenol 95

- 57

- 8 10 0.33 2,4

- Dinitrophenol 51

- 28

- 5 50 1.65
4

- Chlorophenol 106

- 48

- 9 10 0.33 2

- Nitrophenol 88

- 75

- 5 10 0.33
Cresols: 4

- Nitrophenol 100

- 02

- 7 50 1.65
2

- Methylphenol 95

- 48

- 7 10 0.33 Pentachlorophenol 87

- 86

- 5 50 1.65
3

- Methylphenol 108

- 39

- 4 10 0.33 Phenol 108

- 95

- 2 10 0.33
4

- Methylphenol 106

- 44

- 5 10 0.33 2,4,5

- Trichlorophenol 95

- 95

- 4 10 0.33 2,4

- Dichlorophenol 120

- 83

- 2 10 0.33 2,4,6

- Trichlorophenol 88

- 06

- 2 10 0.33 2,4

- Dimethylphenol 105

- 67

- 9 10 0.33

BASE NEUTRAL EXTRACTABLES

  PQL



   PQL



 CAS NO. μ g/L mg/Kg CAS NO. μ g/L mg/ Kg Acenaphthene 83

- 32

- 9 10 0.33 Diethyl phthalate 84

- 66

- 2 10 0.33 Acenaphthylene 208

- 96

- 8 10 0.33 Dimethyl phthalate 131

- 11

- 3 10 0.33
Anthracene 120

- 12

- 7 10 0.33 2,4

- Dinitrotoluene 121

- 14

- 2 10 0.33 Benzo(a)anthracene 56

- 55

- 3 10 0.33 2,6

- Dinitrotoluene 606

- 20

- 2 10 0.33
Benzidine 92

- 87

- 5 20 0.66 1,2

- Diphenylhydrazine as 103

- 33

- 3 10 0.33 Benzo(b)fluoranthene 205

- 99

- 2 10 0.33 Azobenzene Benzo(k)fluoranthene 207

- 08

- 9 10 0.33 Fluorene 86

- 73

- 7 10 0.33 Benzo(g,h,i)perylene 191

- 24

- 2 10 0.33 Fluoranthen e 206

- 44

- 0 10 0.33 Benzo(a)pyrene 50

- 32

- 8 10 0.33 Hexachlorobenzene 118

- 74

- 1 10 0.33 Bis(2

- chloroethoxy)methane 111

- 91

- 1 10 0.33 Hexachlorobutadiene 87

- 68

- 3 10 0.33 Bis(2

- chloroethyl)ether 111

- 44

- 4 10 0.33 Hexachlorocyclopentadiene 77

- 47

- 4 10 0.33 Bis( 2

- chloroisopropyl)ether 108

- 60

- 1 10 0.33 Hexachloroethane 67

- 72

- 1 10 0.33 Bis(2

- ethylhexyl)phthalate 117

- 81

- 7 10 0.33 Indeno(1,2,3

- cd)pyrene 193

- 39

- 5 10 0.33
4

- Bromophenylphenylether 101

- 55

- 3 10 0.33 Isophorone 78

- 59

- 1 10 0.33 Butyl benzyl phthalate 85

- 68

- 7 10 0.33 1

- Methylnaphthalene 90

- 12

- 0 10 0.33
2

- Chloronaphthalene 91

- 58

- 7 10 0.33 2

- Methylnaphthalene 91

- 57

- 6 10 0.33
4

- Chlorophenyl

- phenylether 7005

- 72

- 3 10 0.33 Naphthalene 91

- 20

- 3 10 0.33 Chrysene 218

- 01

- 9 10 0.33 Nitrobenzene 98

- 95

- 3 10 0.33
Di

- n

- butyl phthalate 84

- 74

- 2 10 0.33 N

- Nitrosodi

- n

- propylamine 621

- 64

- 7 10 0.33
Di

- n

- octyl phthalate 117

- 84

- 0 10 0.33 N

- Nitrosodimethylamine 62

- 75

- 9 10 0.33 Dibenzo(a,h)anthracene 53

- 70

- 3 10 0.33 N

- Nitrosodiphenylamine 86

- 30

- 6 10 0.33 1,2

- Dichlorobenzene 9 5

- 50

- 1 10 0.33 Phenanthrene 85

- 01

- 8 10 0.33 1,3

- Dichlorobenzene 541

- 73

- 1 10 0.33 Pyrene 129

- 00

- 0 10 0.33 1,4

- Dichlorobenzene 106

- 46

- 7 10 0.33 Pyridine 110

- 86

- 1 20 0.66 3,3'

- Dichlorobenzidine 91

- 94

- 1 20 0.66 1,2,4

- Trichlorobenzene 120

- 82

- 1 10 0.33Version 2011.0.0 Prices subject to change. Visit www.energylab.com for up- to -date pricing. www.energylab.com 

### Organics - 24 

# ORGANIC CHEMISTRY
DESCRIPTION OF METHODS

Phenols, Individual Compounds by GC/MS (Method E625/SW 8270C)
Sampling: Water: 2

- 1000 mL glass/teflon bottles. Store at6°C. Add 80 mg sodium thiosulfate to chlorinated samples.

Soil: 125 mL wide mouth glass ja r. Store at6°C.

Holding Time: 7(water) or 14(soil) days to extraction; 40 days to analysis



 PQL



   PQL



 CAS NO. μ g/L mg/Kg CAS NO. μ g/L mg/Kg
4

- Chloro

- 3

- methylphenol 59

- 50

- 7 10 0.33 4,6

- Dinitro

- 2

- methylphenol 534

- 52

- 1 50 1.65 (p

- chlor o

- m

- cresol) (4

- 6

- Dinitro

- o

- cresol)
2

- Chlorophenol 95

- 57

- 8 10 0.33 2,4

- Dinitrophenol 51

- 28

- 5 50 1.65
Cresols: 2

- Nitrophenol 88

- 75

- 5 10 0.33
2

- Methylphenol 95

- 48

- 7 10 0.33 4

- Nitrophenol 100

- 02

- 7 50 1.65
3

- Methylphenol 106

- 44

- 5 10 0.33 Pentach lorophenol 87

- 86

- 5 50 1.65
4

- Methylphenol 108

- 39

- 4 10 0.33 Phenol 108

- 95

- 2 10 0.33 2,4

- Dichlorophenol 120

- 83

- 2 10 0.33 2,4,5

- Trichlorophenol 95

- 95

- 4 10 0.33 2,4

- Dimethylphenol 105

- 67

- 9 10 0.33 2,4,6

- Trichlorophenol 88

- 06

- 2 10 0.33



### Phthalate Esters (Me thod E625/SW 8270C)
Sampling: Water: 2

- 1000 mL glass/teflon bottles. Store at6°C.

Soil: 125 mL wide mouth glass jar. Store at6°C.

Holding Time: 7(water) or 14(soil) days to extraction; 40 days to analysis



 PQL



   PQL



 CAS NO. μ g/L mg /Kg CAS NO. μ g/L mg/Kg Bis(2

- ethylhexyl)
Phthalate 117

- 81

- 7 10 0.33 Di

- n

- octyl phthalate 117

- 84

- 0 10 0.33 Butyl benzyl phthalate 85

- 68

- 7 10 0.33 Diethyl phthalate 84

- 66

- 2 10 0.33
Di

- n

- butyl phthalate 84

- 74

- 2 10 0.33 Dimethyl phthalate 131

- 11

- 3 10 0.33



### 2,3,7,8

- TCDD

- Dioxin Screening (Method E625 Screening Test)
Sampling: Water: 2

- 1000 mL glass/teflon bottles. Store at6°C. Soils: 125 mL wide mouth glass ajr. Store at6°C.

Holding Time: 7(water) or 14(soil) days to extraction; 40 days to analysis.

PQL: Water: 2 μ g/L Soils: 0.066 mg/kgVersion 2011.0.0 Prices subject to change. Visit www.energylab.com for up- to -date pricing. www.energylab.com 

### Organics - 25 

# ORGANIC CHEMISTRY
DESCRIPTION OF METHODS

Polynuclear Aromatic Hydrocarbons (PAH) (Method E625/SW 8270C

- GC/MS or SW 8310

- HPLC)
Sampling: Water: 2

- 1000 mL glass/Teflon bottles. Store at6 °C. Add 80 mg sodium thiosulfate to chlorinated samples.

Soil: 125 mL wide mouth glass jar. Store at6°C.

Holding Time: 7(water) or 14(soil) days to extraction; 40 days to analysis



 PQL



   PQL



 CAS NO. μ g/L mg/Kg CAS NO. μ g/L mg/Kg
A cenaphthene 83

- 32

- 9 10 0.33 Chrysene 218

- 01

- 9 10 0.33 Acenaphthylene 208

- 96

- 8 10 0.33 Dibenzo(a,h)anthracene 53

- 70

- 3 10 0.33
Anthracene 120

- 12

- 7 10 0.33 Fluoranthene 206

- 44

- 0 10 0.33 Benzo(a)anthracene 56

- 55

- 3 10 0.33 Fluorene 86

- 73

- 7 10 0.33 Benzo(b)f luoranthene 205

- 99

- 2 10 0.33 Indeno(1,2,3

- cd)pyrene 193

- 39

- 5 10 0.33 Benzo(k)fluoranthene 207

- 08

- 9 10 0.33 Naphthalene 91

- 20

- 3 10 0.33 Benzo(g,h,I)perylene 191

- 24

- 2 10 0.33 Phenanthrene 85

- 01

- 8 10 0.33 Benzo(a)pyrene 50

- 32

- 8 10 0.33 Pyrene 129

- 00

- 0 10 0 .33



### Gasoline Range Organics (GRO) and Total Petroleum Hydrocarbons as Gasoline or Methanol

EPA Method: 1990 Draft GRO Method or SW 5030/SW 8015 Mod.

- Purge & Trap/GC

- FID

Sampling: Water: 3

- 40 mL glass/teflon VOA vials completely full with no air b ubbles. Preserved with 5

- 10 drops hydrochloric acid to pH <2. Store at6°C.

Soil: 125 mL glass jar. Store at6°C.

Holding Time: 14 days

PQL: GRO: 20 μ g/L (water); 2 mg/Kg (soil); 30 mg/m 3 

### (air) Methanol: 2.5 mg/L (water)

Notes: The anal ysis for Gasoline Range Organics includes three components:
Gasoline Range Organics are defined as all the hydrocarbons eluting between 2

- Methylpentane and 1,2,4

- Trimethylbenzene.
Gasoline Range Organics as Gasoline is defined by the analyst as t he portion of the chromatogram in the gasoline range that resembles gasoline.
Total Purgeable Hydrocarbons as Gasoline include all the hydrocarbon responses regardless of elution time. This is equivalent to Method SW 8015 Mod. TPH as gasoline.Version 2011.0.0 Prices subject to change. Visit www.energylab.com for up- to -date pricing. www.energylab.com 

### Organics - 26 

# ORGANIC CHEMISTRY
DESCRIPTION OF METHODS

Diesel Range Organics (DRO), Total Petroleum Hydrocarbons as Diesel, or Carbon Scan

EPA Method: 1990 EPA/API Draft DRO Method or SW 3550/E 8015 Mod.

- Methylene chloride extraction/GC

- FID.

Sampling: Water: 2

- 100 0 mL glass bottles preserved with sulfuric acid. Store at6°C.

Soil: 125 mL glass jar. Store at6°C.

Holding Time: 7(water) or 14(soil) days to extraction; 40 days to analysis

PQL: 0.5 mg/L (water); 10 mg/Kg (soil)

Notes: The analysis for Diesel Range Organics includes three components:
Diesel Range Organics are defined as all hydrocarbons eluting between C10 and C28.
Diesel Range Organics as Diesel is the portion of the hydrocarbons between C10 and C28, which resemble diesel.

Total Extractable Hydrocarbons as Diesel is the total hydrocarbon response regardless of elution time. This value is equivalent to Method SW 8015 Mod. TPH as diesel.



### Volatile Petroleum Hydrocarbons (VPH)

EPA Method: January 1998 Massachusetts metho d as modified by Montana DEQ

Sampling: Water: 3

- 40 mL glass/teflon VOA vials completely full with no air bubbles. Preserved with 5

- 10 drops hydrochloric acid to pH <2. Store at6°C.

Soil: 125 mL glass jar. Store at6°C.

Holding Time: 7 (soi l) days to extraction; 14 (water) & 28 (soil) days to analysis



 PQL



   PQL



 CAS NO. μ g/L mg/Kg CAS NO. μ g/L mg/Kg Methyl t

- butylether 1634

- 04

- 4 1.0 0.10 Total Xylenes NA 0.50 0.050
Benzene 71

- 43

- 2 0.50 0.050 Naphthalene 91

- 20

- 3 1.0 0.10
Tolu ene 108

- 88

- 3 0.50 0.050 C 9 to C 10 Aromatics NA 20 2.0 Ethylbenzene 100

- 41

- 4 0.50 0.050 C 5 to C 8 Aliphatics NA 20 2.0 m+p Xylenes 108

- 38

- 3/ 0.50 0.050 C 9 to C 12 Aliphatics NA 20 2.0
106

- 42

- 3 Total Purgeable Hydrocarbons NA 20 2.0

o

- Xylene 95

- 47

- 6 0 .50 0.050Version 2011.0.0 Prices subject to change. Visit www.energylab.com for up- to -date pricing. www.energylab.com 

### Organics - 27 

# ORGANIC CHEMISTRY
DESCRIPTION OF METHODS

Extractable Petroleum Hydrocarbons (EPH)

Method: January 1998 Massachusetts method as modified by Montana DEQ

Sampling: Water: 2

- 1000 mL glass bottles preserved with sulfuric acid. Store at6 °C.

Soils: 125 mL glass jar. Store at6°C.

Holding Time: 14(water) or 7(soil) days to extraction; 40 days to analysis

PQL EPH Screen: Water: 0.30 mg/L as total extractable hydrocarbons

Soil: 20 mg/Kg as total extractable hydrocarbons

N otes: EPH screening: Samples that contain 50 mg/Kg for soil or 1000 μ g/L for water will require EPH aromatic/aliphatic fractionation and MBTEX analysis. The need for PAH analysis on these samples will be determined by the MDEQ case manager on a case by cas e basis.
MBTEX will be performed by Method SW 8021B or SW 8260B. PAH analysis on soil extracts may be analyzed by GC

- FID. On waters, PAHs are analyzed using Method SW 8270C. PAH hits must be confirmed by second column analysis or GC

- MS.

EPH Complete :

  PQL



   PQL



 CAS NO. mg/L mg/Kg CAS NO. mg/L mg/Kg C9

- C18 Aliphatics NA 0.60 20 Anthracene 120

- 12

- 7 0.010 0.33 C19

- C36 Aliphatics NA 0.60 20 Fluoranthene 206

- 44

- 0 0.010 0.33 C11

- C22 Aromatics NA 0.60 20 Pyrene 129

- 00

- 0 0.010 0.33 Tota l Extractable Hydrocarbons NA 0.30 20 Benzo(a)Anthracene 56

- 55

- 3 0.010 0.33 (Screen) Chrysene 218

- 01

- 9 0.010 0.33 Total Extractable Hydrocarbons NA 0.60 10 Benzo(b)Fluoranthene & 205

- 99

- 2 0.020 0.67 (Fractionation) Benzo(k)Fluoranthene 207

- 08

- 9 Naphthalene 91

- 20

- 3 0.010 0.33 Benzo(a)pyrene 50

- 32

- 8 0.010 0.33 2

- Methylnaphthalene 91

- 57

- 6 0.010 0.33 Indeno(1,2,3

- cd)Pyrene & 193

- 39

- 5 0.020 0.67 Acenaphthylene 208

- 96

- 8 0.010 0.33 Dibenzo(a,h)Anthracene 53

- 70

- 3 Acenaphthene 83

- 32

- 9 0.010 0.33 Ben zo(g,h,i)Perylene 191

- 24

- 2 0.010 0.33 Fluorene 86

- 73

- 7 0.010 0.33 Phenanthrene 85

- 01

- 8 0.010 0.33



### Glycols by GC

- FID

EPA Method: SW 8015 M

Sampling: Water: 500 mL glass or plastic bottle, unpreserved. Store at6°C. Soil: 125 mL glass jar. Store at6°C.

Holding Time: N/A

  PQL



   PQL



 CAS NO. μ g/L mg/Kg CAS NO. μ g/L mg/Kg Ethylene Glycol 107

- 21

- 1 5 5 Propylene Glycol 57

- 55

- 6 5 5Version 2011.0.0 Prices subject to change. Visit www.energylab.com for up- to -date pricing. www.energylab.com 

### Organics - 28 

# ORGANIC CHEMISTRY
DESCRIPTION OF METHODS

Total Petroleum Hydrocarbons by IR

Method: Meth od E418.1 or E418.1 Mod. using Freon extraction and infrared spectroscopy.

Sampling: Water: 1000 mL glass bottle preserved with sulfuric acid.

Soil: 125 mL glass jar.

Holding Time: 7 days to extraction; 40 days to analysis

PQL: 0.1 mg/L (w ater); 10 mg/Kg (soil)

Note: TPH by IR is primarily recommended for use as a screening tool, as it cannot speciate between hydrocarbon types.



### Oil and Grease

- Freon Extraction/Gravimetric

Method: E413.1 Freon Extraction/Gravimetric

Sampling: Wat er: 1000 mL glass bottle preserved with sulfuric acid.

Soil: NA

Holding Time: 28 days

PQL: 1 mg/L (water)

Notes: This method is used to determine relatively non

- volatile hydrocarbons, vegetable or animal oils, and related matter. It is no t applicable to the measurement of light hydrocarbons that volatilize below 85 ° C. Petroleum fuels, from gasoline through No. 2 fuel oils, are completely or partially lost.



### Oil and Grease

- Freon Extraction/IR

EPA Method: E413.2 or E413.2 Mod. using Fre on extraction and infrared spectroscopy

.
Sampling: Water: 1000 mL glass bottle preserved with sulfuric acid.

Soil: 125 mL glass jar.

Holding Time: 28 days

PQL: 0.1 mg/L (water); 10 mg/Kg (soil)



### Oil and Grease or TPH

- Soxhlet Extraction

EPA Method: SW 9071 Soxhlet Extraction/Gravimetric

Sampling: Water: NA

Soil: 125 mL glass jar

Note: This method is used to measure relatively polar, non

- volatile petroleum hydrocarbons. It is not suitable for fractions that volatilize below 70 ° C.



### Oil and Grease

- Hexanes Extraction/Gravimetric and Sulfur Corrected w/Copper

EPA and Standard Method: E1664/A 5520 B, Hexanes Extractable/Gravimetric

E1664

- Cu Hexanes Extractable/Gravimetric Sulfur Corrected w/Copper

Sampling: Water: 100 0 mL glass bottle preserved with sulfuric acid.

Soil: NA

Holding Time: 28 days

Note: This method is not applicable to the measurement of light hydrocarbons that volatilize below 85 ° C. Petroleum fuels, from gasoline through No. 2 fuel oils, ar e completely or partially lost.Version 2011.0.0 Prices subject to change. Visit www.energylab.com for up- to -date pricing. www.energylab.com 

### Organics - 29 

# ORGANIC CHEMISTRY
DESCRIPTION OF METHODS

Total Organic Halogens (TOX)

Method: SW 9020

Sampling: Water: 4

- 40 mL glass septum bottles, completely full, no air bubbles. Preserve chlorinated samples with 10 mg sodium thi osulfate. Store at6°C.

Soil: 125 mL wide mouth glass jar. Store at6°C.

Holding Time: 14 days



### Hydrocarbons in Headspace Gas

Method: GC/FID Kampbell (SW 8015 Mod.)

Sampling: 3

- 40 mL VOA vials, completely full with no air bubbles, preserved with 5

- 10 drops H 2 

### SO 4



### Holding Time: NA

Note: This analysis determines the ppm concentration of methane and heavier volatile hydrocarbons in air.



### Acrylamide (Method SW 8316 HPLC)

Method: SW 8316 HPLC

Sampling: 3

- 40 mL VOA vials, completely fu ll with no air bubbles. Store at6°C.

Holding Time: 14 days



### Nitroaromatics and Nitramines (Method SW 8330

- HPLC)
Sampling: Water: 2

- 1000 mL glass/Teflon bottles. Store at6°C.

Soil: 125 mL wide mouth glass jar. Store at6°C.

Holding Time: 7(water) or 14(soil) days to extraction; 40 days to analysis



 PQL



   PQL



 CAS NO. μ g/L mg/Kg CAS NO. μ g/L mg/Kg
HMX 2691

- 41

- 0 0.20 0.10 4

- Amino

- 2,6

- dinitrotoluene 19406

- 51

- 0 0.20 0.10
RDX 121

- 82

- 4 0.20 0.10 2

- Amino

- 4,6

- dinitrotoluene 355

- 72

- 7 8

- 2 0.20 0.10 1,3,5

- Trinitrobenzene 99

- 35

- 4 0.20 0.10 2,6

- Dinitrotoluene 606

- 20

- 2 0.20 0.10 1,3

- Dinitrobenzene 99

- 65

- 0 0.20 0.10 2,4

- Dinitrotoluene 121

- 14

- 2 0.20 0.10
TETRYL 479

- 45

- 8 0.20 0.10 2

- Nitrotoluene 88

- 72

- 2 0.20 0.10
Nitrobenzene 98

- 95

- 3 0.20 0.10 4

- Nitrotoluene 99

- 99

- 0 0.20 0.10 2,4,6

- Trinitrotoluene 118

- 96

- 7 0.20 0.10 3

- Nitrotoluene 99

- 08

- 1 0.20 0.10



### Nitroglycerin and PETN (Method SW 8332

- HPLC)
Sampling: Water: 2

- 1000 mL glass/Teflon bottles. Store at6°C.

Soil: 125 mL wide mouth g lass jar. Store at6°C.

Holding Time: 7(water) or 14(soil) days to extraction; 40 days to analysis



 PQL



   PQL



 CAS NO. μ g/L mg/Kg CAS NO. μ g/L mg/Kg Nitroglycerin 55

- 63

- 0 0.20 0.10 PETN 75

- 11

- 5 0.20 0.10