13339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone: 980-875-5245 Fax: 980-875-4349 

# Order Summary Report 

# Analytical Laboratory

Order Number: J 13050207 Project Name:

L ab Contact: Jason C Perkins Date: 6/18/2014 Customer Address: 3195 Pine Hall Rd Customer Name(s): Bill Kennedy

Mailcode: Belews Steam Station Belews Creek, NC 28012 Phone: 980-875-5348 Report Authorized By: (Signature) Program Comments: in house report...was not set out....a summary report will be sent...see J13050208 Data Flags & Calculations: Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. Jason C Perkins

### Sample ID's & Descriptions:

Sample ID Plant/Station Collection Date and Time Collected By Sample Description 2013010541 BELEWS 08-May-13 1:30 PM EFF. TANK - MF 2013010546 BELEWS 08-May-13 8:00 AM BLANK MF 2 Total SamplesCOC and .pdf report are in agreement with sample totals

and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. All laboratory QA/QC requirements are acceptable. Yes No



## Technical Validation Review Checklist:

Yes No Yes No 

### Report Sections Included:

Job Summary Report Sub-contracted Laboratory Results Sample Identification Customer Specific Data Sheets, Reports, & Documentation Technical Validation of Data Package Customer Database Entries Analytical Laboratory Certificate of Analysis Analytical Laboratory QC Report Chain of Custody

Reviewed By: DBA Account Date: 6/5/2013 Electronic Data Deliverable (EDD) Sent Separatel

## Certificate of Laboratory Analysis This report shall not be reproduced, except in full.



### Order # J13050207
2013010541 Collection Date: 08-May-13 1:30 PM Site: EFF. TANK - MF Matrix: OTHER Analyte Analysis Date/Time Method Units Qualifiers RDL Result Sample #:
Analyst DF NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric) 36 mg-N/L EPA 353.2 05/20/2013 12:21 BGN9034 0.5 50 MERCURY 1631 - (Analysis Performed by Brooks Rand Labs LLC) Vendor Parameter Complete Vendor Method V_BRAND TOTAL RECOVERABLE METALS BY ICP-MS Arsenic (As) < 5 ug/L EPA 200.8 05/23/2013 11:23 DJSULL1 5 5 Selenium (Se) 1010 ug/L EPA 200.8 05/23/2013 11:23 DJSULL1 5 5

## Certificate of Laboratory Analysis This report shall not be reproduced, except in full.



### Order # J13050207
2013010546 Collection Date: 08-May-13 8:00 AM Site: BLANK MF Matrix: OTHER Analyte Analysis Date/Time Method Units Qualifiers RDL Result Sample #:
Analyst DF MERCURY 1631 - (Analysis Performed by Brooks Rand Labs LLC) Vendor Parameter Complete Vendor Method V_BRAND

## Certificate of Laboratory Analysis This report shall not be reproduced, except in full.



### Order # J13050207

Q13050233 C_NO2NO3 NITRITE + NITRATE (COLORIMETRIC) 

### Level II QC Summary

Final Qualifier Dil Measured Units: Parameter Blank # 1 RDL Relative Concentration

Nitrite + Nitrate (Colorimetric) 0.0023 mg-N/L - 1 0.0023 0.01 < 1/2 RDL

Final Qualifier Dil Measured Units: Parameter LCS # 1 % Recovery LCL UCL Spike Nitrite + Nitrate (Colorimetric) 1.18 5.75 102 mg-N/L - 115 85 5 5.89

Final Qualifier Dil Measured Units: Parameter MS # 1 % Recovery LCL UCL Spike Parent Sample: J13050061 -- 2013009824 Nitrite + Nitrate (Colorimetric) 0.773 0.5 98.7 mg-N/L - 130 70 1 0.773

Final Qualifier Dil Measured Units: Parameter MSD # 1 RPD % Recovery LCL UCL Spike Parent Sample: J13050061 -- 2013009824 Nitrite + Nitrate (Colorimetric) 0.77 0.5 98.2 0.488 mg-N/L - 130 70 1 0.77

## Certificate of Laboratory Analysis This report shall not be reproduced, except in full.



### Order # J13050207

Q13050194 IMS_TRM TOTAL RECOVERABLE METALS B Y ICP-MS 

### Level II QC Summary

Final Qualifier Dil Measured Units: Parameter Blank # 1 RDL Relative Concentration

Arsenic (As) -0.185 ug/L - 1 -0.185 1 < 1/2 RDL Selenium (Se) -0.0058 ug/L - 1 -0.0058 1 < 1/2 RDL
Final Qualifier Dil Measured Units: Parameter LCS # 1 % Recovery LCL UCL Spike Arsenic (As) 110 100 110 ug/L - 115 85 1 110 Selenium (Se) 101 100 101 ug/L - 115 85 1 101
Final Qualifier Dil Measured Units: Parameter MS # 1 % Recovery LCL UCL Spike Parent Sample: J13050207 -- 2013010540 Arsenic (As) 21.4 100 105 ug/L - 130 70 5 107 Selenium (Se) 17.3 100 83.6 ug/L - 130 70 5 86.4
Final Qualifier Dil Measured Units: Parameter MSD # 1 RPD % Recovery LCL UCL Spike Parent Sample: J13050207 -- 2013010540 Arsenic (As) 22.2 100 109 3.97 ug/L - 130 70 5 111 Selenium (Se) 18.4 100 89.2 6.54 ug/L - 130 70 5 92
Final Qualifier Dil Measured Units: Parameter MS # 2 % Recovery LCL UCL Spike Parent Sample: J13050207 -- 2013010537 Arsenic (As) 21.3 100 105 ug/L - 130 70 5 107 Selenium (Se) 97.5 100 90.2 ug/L - 130 70 5 487
Final Qualifier Dil Measured Units: Parameter MS # 3 % Recovery LCL UCL Spike Parent Sample: J13050207 -- 2013010538 Arsenic (As) 22 100 108 ug/L - 130 70 5 110 Selenium (Se) 19.4 100 92.2 ug/L - 130 70 5 96.9
Final Qualifier Dil Measured Units: Parameter MS # 4 % Recovery LCL UCL Spike Parent Sample: J13050207 -- 2013010539 Arsenic (As) 22.1 100 109 ug/L - 130 70 5 110 Selenium (Se) 27.6 100 99.5 ug/L - 130 70 5 138
Final Qualifier Dil Measured Units: Parameter MS # 5 % Recovery LCL UCL Spike Parent Sample: J13050207 -- 2013010541 Arsenic (As) 16.9 100 82.5 ug/L - 130 70 5 84.3 Selenium (Se) 219 100 79.5 ug/L - 130 70 5 1090

### June 18, 2014 Duke Energy ATTN: Jay Perkins 13339 Hagers Ferry Road Huntersville NC 28078 j perkins@duke-energy.com RE: Project DUK-HV1201 Dear Jay Perkins, This report contains results for the 2 samples received by Brooks Rand Labs (BRL) on May 14, 2013. The samples were logged-in for the contracted analyses according to the chain-of-custody form(s). The samples were received, prepared, analyzed, and stored according to BRL SOPs and EPA methodology. The results were method blank corrected as described in the calculations section of the relevant BRL SOP(s) and may have been evaluated using reporting limits that have been adjusted to account for sample aliquot size. Please refer to the Sample Results page for sample-specific MDLs, MRLs, and other details. All data is reported without qualification (with the exception o f concentration qualifiers), and all associated quality control sample results meet the acceptance criteria. BRL, an accredited laboratory, certifies that the reported results of all analyses for which BRL is NELAP accredited meet all NELAP requirements. For more details, please see the Repor t Information page in your report. Please feel free to contact me if you have any questions regarding this report. Client Pro j ect: J13050207

Sincerely,
Lydia Greaves ProjectManager lydia @brooksrand.com

3958 6th Avenue NW Seattle WA 98107 · P(206) 632-6206 · F(206) 632-6017 · brl@brooksrand.com · www.broo ksrand.com 

### Revision 2: This revision includes results only for BRL Sample IDs 1320012-05 and 1320012-10.Proj ect ID: DUK-HV1201 PM: Tiffan yStilwater Client PM: Ja yPerkins Client PO: 141391



### Definition of Data Qualifiers (Effective 9/23/09) 

### Laboratory Accreditation BRL is accredited by the National Environmental Laboratory Accreditation Program (NELAP) through the State of Florida Department of Health, Bureau of Laboratories (E87982) and is ce rtified to perform many environmental analyses. BRL is also certified by many other states to perform environmental analyses. For a current list of ou r accreditations/certifications, please visi t our website at <http://www.brooksrand.c om/about/accreditations-certifications/>. Results reported relate only to the samples listed in the report. 

# Report Information

BLK BRL BS CAL CC V CRM D DUP IC V MSD ND NR PS REC RPD RSD SC V SOP method blank Brooks Rand Labs laboratoryfortified blank calibration standard continuin g calibration verification certified reference material dissolved fraction duplicate initial calibration verification matrix spike duplicate non-detect non-reportable post preparation spike percent recovery relative percent difference relative standard deviation secondarycalibration verification standard operatin g procedure MDL MRL MS

method detection limit method reportin g limit matrix spike

SRM T COC

standard reference material total recoverable fraction chain of custod yrecord 

### Common Abbreviations

These qualifiers are based on those previously ut ilized by Brooks Rand Labs, those found in the EPA SOW ILM 03.0, Exhibit B, Section III, pg. B-18, and the USEPA Contract Laboratory Program National Functional Guidelines for Inorganic Superfund Data Review ; USEPA ;January2010. These supersede all previous qua lifiers ever employed by BRL. Detected b ythe instrument, the result is > the MDL but ≤ the MRL. Result is reported and considered an estimate. B E A n estimated value due to the presence of interferences. A full explanation is presented in the narrative. H Holdin g time and/or preservation requirem ents not met. Result is estimated. J Estimated value. A full explanation is presented in the narrative. J-M Duplicate precision ( RPD ) for associated QC sample was not within acceptance criteria. Result is estimated. J-N Spike recoveryfor associated QC sample was not within acceptance criteria. Result is estimated. M Duplicate precision ( RPD ) was not within acceptance criteria. Result is estimated. N Spike recoverywas not within acceptance criteria. Result is estimated. R Re j ected, unusable value. A full explanation is presented in the narrative. U Result is ≤ the MDL or client requested reportin g limit ( CRRL ) . Result reported as the MDL or CRRL. X Result is not BLK-corrected and is within 10x the absol ute value of the highest detectable BLK in the batch. Result is estimated. 

### Field Quality Control Samples Please be notified that certain EPA methods require the collection of field quality control samples of an appropriate type and frequency; failure to do so is considered a deviation from some methods and for compliance purposes should only be done with the approval of regulatory authorit ies. Please see the specific EPA met hods for details regarding required field quality control samples.

IBL instrument blank

3958 6th Avenue NW Seattle WA 98107 · P(206) 632-6206 · F(206) 632-6017 · brl@brooksrand.com · www.broo ksrand.comProj ect ID: DUK-HV1201 PM: Tiffan yStilwater Client PM: Ja yPerkins Client PO: 141391 

# Sample Information
Type Sample Sample Effluent Tank-MF Lab ID Report Matrix 1320012-05 FGD Wastewater Field Blank DIW 1320012-10 Blank-MF Sampled Received 05/08/2013 05/14/2013 05/08/2013 05/14/2013



# Batch Summary
Analyte Prepared Analyzed Sequence Batch Lab Matrix Method B130795 05/17/2013 05/20/2013 1300344 Water EPA 1631 Hg 

# Sample Results
Sample Sequenc e Result MDL MRL Unit Batch Qualifier Analyte Basis Report Matrix Blank-M F 0.15 T U 1300344 B130795 DIW 0.40 0.15 1320012-10 Hg ng/L Effluent Tank-M F 113 T 1300344 B130795 FGD Wastewater 2.11 0.79 1320012-05 Hg ng/L

3958 6th Avenue NW Seattle WA 98107 · P(206) 632-6206 · F(206) 632-6017 · brl@brooksrand.com · www.broo ksrand.comProj ect ID: DUK-HV1201 PM: Tiffan yStilwater Client PM: Ja yPerkins Client PO: 141391 

# Accuracy & Precision Summary

Batch: B130795

Anal yte Result Units Native Spike REC & Limits RPD & Limits Method: EPA 1631 Lab Matrix: Water Sample Certified Reference Material ( 1317016, NIST 1641d 1000x dilution ) B130795-SRM1 15.68 104% ng/L 85-115 Hg 16.37 Matrix Spike ( 1320012-01 ) B130795-MS2 421.1 107% ng/L 71-125 Hg 610.3 161.0 Matrix Spike Duplicate ( 1320012-01 ) B130795-MSD2 421.1 110% ng/L 71-125 242% Hg 624.4 161.0 

# Method Blanks & Reporting Limits

Batch: B130795 Method: EPA 1631 Matrix: Water Anal yte: H g Result Units Sample B130795-BLK1 ng/L 0.22 B130795-BLK2 ng/L 0.24 B130795-BLK3 ng/L 0.24 B130795-BLK4 ng/L 0.19 MDL: 0.15 Avera g e: 0.22 Standard Deviation: 0.02 Limit: 0.10 Limit: 0.50 MRL: 0.39

3958 6th Avenue NW Seattle WA 98107 · P(206) 632-6206 · F(206) 632-6017 · brl@brooksrand.com · www.broo ksrand.comProj ect ID: DUK-HV1201 PM: Tiffan yStilwater Client PM: Ja yPerkins Client PO: 141391 

# Sample Containers
Lab ID: 1320012-05 Re p ort Matrix: FGD Wastewater Sam p le T yp e: Sam p le Received: 05 / 14 /2013 Sample: Effluent Tank-MF Collected: 05 / 08 /2013 Shi p . Cont. pH P-Lot Preservation Lot Size Containe r Des A 13-0001 Cooler none n/a 250mL Bottle FLPE H g -T

3958 6th Avenue NW Seattle WA 98107 · P(206) 632-6206 · F(206) 632-6017 · brl@brooksrand.com · www.broo ksrand.com Re p ort Matrix: DIW Sam p le T yp e: Field Blank Collected: 05 / 08 /2013 Received: 05 / 14 /2013 Lab ID: 1320012-10 Sample: Blank-MF pH Shi p . Cont. P-Lot Lot Size 13-0001 Cooler Preservation none n/a 250mL Des Containe r A Bottle FLPE H g -T 

# Shipping Containers
Cooler Received: Ma y14, 2013 10:30 Trackin g No: 557566434797 via FedEx Coolant T yp e: None Tem p erature: ambient Descri p tion: Cooler Dama g ed in transit? No Returned to client? No Custod y seals p resent? Ye s Custod y seals intact? Ye s COC p resent? Ye s