# Acopyofth eChai no f Custodycanb efoun din LA B WAR ELIM S

Acopyofth eGP O and/o r Protoco lcanb efoun dinth e Lotu s Note s GP O Databas e

Communication s Misc

.

### Westo n Solutions , Inc

. 140 0 Westo n Way P.O

. Bo x265 3 Westchester, Pennsylvani a1938 0 610-701-300 0 •Fa

x610-701-318 6 ® www.westonsolutions.co m 

# Th e Truste d Integrato rfo rSustainabl e Solution s



# Febraary21,201 1

Dr

. Clesto nLang e 3 MEnvironmentalLaboratory 3 MCenter Buildin g260-5N-1 7 St

. Paul , MN55144-100 0

Dea r Dr

. Lange :

Per your request , Iamreturnin gherewithInteri mReport 1 1 for studyGLP10-01-0 1 for Decatur , Alabama

. Th eappropriatepage s hav ebeensigne dandareinclude dwiththi s transmittal

. Shouldyouhav eanyquestions , pleas edono t hesitatet ocontac t

mea t 610-701-3761

. Ver ytrul yyours , WESXOf ^SOLUTIONS , INC

.

JaisirnhaXesari , P.E. , DEE PrincipalProjec t

Manager

Enclosure

a n employee-owne d compan y

M:\FOLDERS.O-9\3M-DECA'nUnge-13.docx 

# ®

# Standar dPre p

Sampl ePre p Collectio nBottl ePre p

# Not eT oFil e

Projec t o r Stud y Description : LIM S Number : Affecte dData : Decatu r Phas e3 - FSI Agroundwate r

GLP l0-01-01-11/GLP l0-01-02-1 1 Non e

On e hundre d eighty-nin e 25 0 m LNalgen e bottle s were marke d wit h a20 0 m Lleve l lin e an d labeled

. Th e followin g tri p blanks/spike s were fille d wit h RO wate r(TN10-0311 ) an d seale d afte rtheywere spiked

. O n 10/21/10 , th e fiel d matri xspike bottle s were spike d wit h th e following :

Wel l No

.

136R,137R,1378,137L , 138 L

130L , 131L , 1313 , 133R , 1348 , 1358,136 3

130R , 1303 , 132R , 132L , 1328 , 1333 , 133L , 134L , 135L , 136L , 1388 , 138R , CW26R , CW26L , 140R , 141R,142R , 143R , an d 144 R 131R , 134R , 135 R

Tri p Blan k

1-4 Sampl e Leve l

Low Mi d Hig h Low Mi d Hig h Low Mi d Hig h Low Hig h Low Mi d Mid-Hig h Hig h Spikin g

Solutio n

1 0 005-18 7 1 0 005-18 7 1 0 005-18 7 1 0 005-18 7 1 0 005-18 7 1 0 006-1 2 1 0 005-18 7 1 0 006-1 2 1 0 006-1 2 1 0 006-1 2 1 0 006-1 2 1 0 005-18 7 1 0 005-18 7 1 0 006-1 2 1 0 006-1 2 Approx

.

Valu e (Mg/mL ) 2. 0 2. 0 2. 0 2. 0 2. 0 10 0 2. 0 10 0 10 0 10 0 10 0 2. 0 2. 0 10 0 10 0 Spik e

Amoun t (ML ) 1 0 10 0 100 0 10 0 100 0 20 0 100 0 20 0 200 0 20 0 200 0 10 0 100 0 20 0 200 0 Spik e

Cone

. (ng/mL ) 0. 1 1. 0 1 0 1 1 0 10 0 1 0 10 0 100 0 10 0 100 0 1 10

. 10 0 100 0



## UsedEppendor

f Researchpipette s 340227 7 and2077127 toaddspikingsolutiontosamples

.Printin g 12/30/2010 ; 2:5 3 P M

GLP10-01-01-1 1 Sampl e Pre p Wort ( Slieet ; ETS-8-04 4 date ; 12/30/1 0

Sampl e I D LCS-101230- 1 LCS-101230- 2 LCS-101230- 3 LCS-101230- 4 LCS-101230- 5 LCS-101230- 6 LCS-101230- 7 LCS-101230- 8 LCS-101230- 9 LCS-101230-1 0 LCS-101230-1 1 LCS-101230-1 2 LCS-101230-1 3 LCS-101230-1 4 LCS-101230-1 5 LCS-101230-1 6 LCS-101230-1 7 LCS-101230-1 8 Analyst : CJ G Sampl e Descriptio n O.Sppb LC S 0.5pp b LC S 0.5pp b LC S 5pp b LC S 5pp b LC S 5pp b LC S 30pp b LC S 30pp b LC S 30pp b LC S O.Sppb LC S EC F O.Sppb LC S EC F O.Sppb LC S EC F Spp b LC S EC F Spp b LC S EC F Spp b LC S EC F 30pp b LC S EC F 30pp b LC S EC F 30pp b LC S EC F Spikin g st d I D 0 9 004-19 4 0 9 004-19 4 0 9 004-19 4 0 9 004-19 3 0 9 004-19 3 0 9 004-19 3 0 9 004-19 2 0 9 004-19 2 0 9 004-19 2 1 0 010-1 8 1 0 010-1 8 1 0 010-1 8 1 0 010-1 7 1 0 010-1 7 1 0 010-1 7 1 0 006-2 7 1 0 006-2 7 1 0 006-2 7 Spik e Am t(uL ) S O 

## s o 5 0 5 0 5 0 5 0 3 0 3 0 3 0 5 0 S O S O 2 5 2 5 2 5 3 0 3 0 3 0 La b wate r(mL )

1 0 1 0 1 0 1 0 1 0 1 0 1 0 1 0 1 0 1 0 1 0 1 0 1 0 1 0 1 0 1 0 1 0 1 0

12/30/1 0 CJG ; LC S an d Solven tBlanks prepare d witt i Mill i Q Wate r(TN10-0475) , vorte xmixed , an d aliquote d int o 2-m Lglas s autovials

.



## 1 1 12/30/1 0 CJG ; 1 se tofaliquot s of0 8 008-19 4curv e were transferre d int o 2-m Lglas s autovial s



## 1 1 12/30/1 0 CJG ; Sample s GLP10-01-01-1 1 requirin g 1:1 0 dilutio n wer e prepare d bytakin g 1 m Lo fsampl e an d addin g 9 m LofMill i Q Elemen tWate r(TN I 0-0475) , mixe d , an d the n aliquote d int o 2-m Lglas s autovials

. 12/30/1 0 CJG ; Sample s GLPl0-01-01-1 1 requirin g 1:10 0 dilutio n wer e prepare d bytakin g 0. 1 m Lo fsampl e an d addin g 9. 9 m Lo fMill i Q Elemen tWate r(TNI0-0475) , mixe d , an d the n aliquote d int o 2-m Lglas s autovials

. 12/30/1 0 CJG ; Sample s GLP10-01-01-1 1 no trequirin g dilutio n wer e aliquote d int o a2-m Lglas s autovia l



## 1 12/30/1 0 CJG ; Pipett e used : 421553 7

Sampl e I D GLP10-01-01-11-00 3 GLP l 0-01-01-11-00 4 GLP10-01-01-11-01 6 GLP10-01-01-11-03 6 GLP10-01-01-11-03 7 GLP10-01-01-11-03 8 GLP l 0-01-01-11-03 9 GLP10-01-01-11-04 0 GLP10-01-01-11-04 5 GLP10-01-01-11-05 4 GLP10-01-01-11-05 6 GLP10-01-01-11-05 9 GLP10-01-01-11-06 0 GLP10-01-01-11-06 2 GLP10-01-01-11-07 2 GLP10-01-01-11-07 9 GLP l 0-01-01-11-08 0 GLP l 0-01-01-11-12 6 GLP10-01-01-11-12 7 GLP10-01-01-11-13 2 GLP10-01-01-11-13 9 Overfill/Underfil l Amoun t(cm ) 7. 4 7. 5 8. 0 7. 9 7. 9 8. 0 8. 0 8. 1 7. 6 8. 0 7. 5 7. 4 7. 5 7. 4 7. 5 8. 0 8. 0 8. 0 8. 0 8. 1 8. 0

ETS-8-04 4sampl e pre p 101230.xl s 

# rJ 6/2-30-/ 0

Pag e 1 of1Curv e Point s an d LCS ; Metho d ETS-8-04 4

Concentratio n - u Stoc k I D 0 9 004-19 4

0 9 004-19 3 0 9 004-19 2 0 9 004-18 0 0 9 004-18 1 1 0 010-1 7 1 0 010-1 8 1 0 006-2 7 PFO A 0.099 9 0.99 9 9.9 9 99. 9

2.0 0 0.10 0 10. 0 g/m L



### PF& & 0.099 9 0.99 9 9.9 9

99. 9



## - PFH S

0.10 0 1.00 10. 0

10 0



## - PFO S

0.099 9 0.99 9 9.9 9

99. 9 1.98 0.098 9 9.8 9

08008-194- 1 0.02 5 ng/m LFC st d i n Mill i Q wate r 08008-194- 2 0.0 3 ng/mLF C st d i n Mill i Q wate r 08008-194- 3 0.0 4ng/mLF C st d i n Mill i Q wate r 08008-194- 40.0 5 ng/mLF C st d i n Mill i Q wate r 08008-194- 5 0. 1 ng/m LFC st d i n Mill i Q wate r 08008-194- 6 0.2 5 ng/m LF C st d i n Mill i Q wate r 08008-194- 70. 5 ng/m LFC st d i n Mill i Q wate r 08008-194- 8 1. 0 ng/m LFC st d i n Mill i Q wate r 08008-194- 9 2. 5 ng/m LFC st d i n Mill i Q wate r 08008-194-1 0 5 ng/m LF C st d i n Mill i Q wate r 08008-194-1 1 1 0 ng/m LF C st d i n Mill i Q wate r 08008-194-1 2 2 5 ng/m LF C st d i n Mill i Q wate r 08008-194-1 3 5 0 ng/m LF C st d i n Mill i Q wate r 08008-194-1 47 5 ng/m LF C st d i n Mill i Q wate r 08008-194-1 5 10 0 ng/mLFC st d i n Mill i Q wate r PFO A 0.025 0 0.030 0 0.040 0 0.050 0 0.099 9 0.25 0 0.50 0 0.99 9 2.5 0 5.0 0 9.9 9 25. 0 50. 0 74. 9 99. 9 PFB S

0.025 0 0.030 0 0.040 0 0.050 0 0.099 9 0.25 0 0.50 0 0.99 9 2.5 0 5.0 0 9.9 9 25. 0 50. 0 74. 9 99. 9 PFH S

0.025 0 0.030 0 0.040 0 0.050 0 0.10 0 0.25 0 0.50 0 1.00 2.5 0 5.0 0 10. 0 25. 0 50. 0 75. 0 10 0 LCS-101230- 1 O.Spp b LCS LCS-101230-2 O.Spp b LCS LCS-101230-3 O.Spp b LCS LCS-101230-4Spp b LCS LCS-101230-S Spp b LCS LCS-101230-6 Spp b LCS LCS-101230-730ppbLC S LCS-101230-8 30ppbLC S LCS-101230-9 30ppbLC S LCS-101230-1 Q O.Spp b LCS EC F LCS-101230-1 1 O.Spp b LCS EC F LCS-101230-1 2 O.Spp b LCS EC F LCS-101230-1 3 Sppb LCS EC F LCS-101230-1 4Sppb LCS EC F LCS-101230-1 S Sppb LCS EC F LCS-101230-1 6 30ppbLCSEC F LCS-101230-1 730ppbLCSEC F LCS-101230-1 8 30ppb LCS EC F 0.49 7 0.49 7 0.49 7 4.9 7 4.9 7 4.9 7 29. 9 29. 9 29. 9 0.49 8 0.49 8 0.49 8 4.9 9 4.9 9 4.9 9 29. 9 29. 9 29. 9 0.49 7

0.49 7 0.49 7 4.9 7 4.9 7 4.9 7 29. 9 29. 9 29. 9



## - 0.49 8

0.49 8 0.49 8 4.9 8 4.9 8 4.9 8 29. 9 29. 9 29. 9



## - PFO S

0.025 0 0.030 0 0.040 0 0.050 0 0.099 9 0.25 0 0.50 0 0.99 9 2.5 0 5.0 0 9.9 9 25. 0 50. 0 74. 9 99. 9 Stoc k

I D 0 9 004-19 4 0 9 004-19 4 0 9 004-19 4 0 9 004-19 4 0 9 004-19 4 0 9 004-19 4 0 9 004-19 3 0 9 004-19 3 0 9 004-19 2 0 9 004-19 2 0 9 004-19 2 0 9 004-19 2 0 9 004-19 2 0 9 004-19 2 0 9 004-19 2

0.49 7 0.49 7 0.49 7 4.9 7 4.9 7 4.9 7 29. 9 29. 9 29. 9 0.49 2 0.49 2 0.49 2 4.95 4.95 4.95 29. 7 29. 7 29. 7 0 9 004-19 4

0 9 004-19 4 0 9 004-19 4 0 9 004-19 3 0 9 004-19 3 0 9 004-19 3 0 9 004-19 2 0 9 004-19 2 0 9 004-19 2 1 0 010-1 8 1 0 010-1 8 1 0 010-1 8 1 0 010-1 7 1 0 010-1 7 1 0 010-1 7 1 0 006-2 7 1 0 006-2 7 1 0 006-2 7 Spik e

Volum e (uL )

•2 5 3 0 4 0 5 0 10 0 25 0 5 0 10 0 2 5 5 0 10 0 25 0 50 0 75 0 100 0

5 0 5 0 5 0 5 0 5 0 5 0 3 0 3 0 3 0 5 0 5 0 5 0 2 5 2 5 2 5 3 0 3 0 3 0 Surrogat e Volum e (uL ) Fina l

Volum e (mL ) 2 5 10 0 3 0 10 0 4 0 10 0 5 0 10 0 10 0 10 0 25 0 10 0

10 0 10 0 10 0 10 0 10 0 10 0 10 0 10 0 10 0



## -

- 10.0 5

10.0 5 10.0 5 10.0 5 10.0 5 10.0 5 10.0 3 10.0 3 10.0 3 10.0 5 10.0 5 10.0 5 10.02 5 10.02 5 10.02 5 10.0 3 10.0 3 10.0 3

ETS-8-04 4sampl e pre p 101230.xl s Calibratio n Curv e Pag e 1 of1Sampl e I d

LCS-101230- 1 LCS-101230- 2 LCS-101230- 3 LCS-101230- 4 LCS-101230- 5 LCS-101230- 6 LCS-101230- 7 LCS-101230- 8 LCS-101230- 9 LCS-101230-1 0 LCS-101230-1 1 LCS-101230-1 2 LCS-101230-1 3 LCS-101230-1 4 LCS-101230-1 5 LCS-101230-1 6 LCS-101230-1 7 LCS-101230-1 8 Descriptio n O.Sppb LC S O.Sppb LC S O.Sppb LC S Spp b LC S Spp b LC S Spp b LC S 30pp b LC S 30pp b LC S 30pp b LC S O.Sppb LC S EC F O.Sppb LC S EC F O.Sppb LC S EC F Spp b LC S EC F Spp b LC S EC F Spp b LC S EC F 30pp b LC S EC F 30pp b LC S EC F 30pp b LC S EC F

GLP10-01-01-11-00 1 DA LGW130 R 0 10110 5 (di l 1:100 ) GLP10-01-01-11-00 2 DALGW130RD B 10110 5 (di l 1:100 ) GLP10-01-01-11-00 3 DALGW130RL S 10110 5 (di l 1:100 ) GLP10-01-01-11-004DA LGW130 R M S 10110 5 (dil1:100 ) GLP10-01-01-11-00 5 DA LG W130 R H S 10110 5 (di l 1:100 ) GLP10-01-01-11-00 6 DA LG W130 S 0 10110 5 (di l 1:100 ) GLP10-01-01-11-00 7DA LG W130 S D B 10110 5 (di l 1:100 ) GLP10-01-01-11-00 8 DA LG W130 S L S 10110 5 (di l 1:100 ) GLP10-01-01-11-00 9 DALG W130 S M S 10110 5 (di l 1:100 ) GLP10-01-01-11-010 DA LG W130 S H S 10110 5 (di l 1:100 ) GLP10-01-01-11-01 1 DA LGW130 L0 10110 5 (di l 1:10 ) GLP10-01-01-11-01 2 DALGW130LD B 10110 5 (di l 1:10) GLP10-01-01-11-01 3 DA LG W130 LL S 10110 5 (di l 1:10) GLP10-01-01-11-01 4DA LG W130 LM S 10110 6 (di l 1:10) GLP10-01-01-11-01 5 DALG W130LH S 10110 5 (di l 1:10) GLP10-01.01-11-01 7DA LG W131 R 0 10110 3 (di l 1:100 ) GLP10-01-01-11-01 8 DALG W131 R D B 10110 3 (di l 1:100 ) GLP10-01-01-11-01 9 DA LGW131RL S 10110 3 (di l 1:100 ) GLP10-01-01-11-020 DALG W131RH S 10110 3 (di l 1:100 ) GLP10-01-01-11-02 1 DA LGW131 S 0 10110 3 (di l 1:10) GLP10-01-01-11-02 2 DALG W131 S D B 10110 3 (di l 1:10) GLP10-01-01-11-02 3 DA LGW131SL S 10110 3 (di l 1:10) GLP10-01-01-11-024DA LGW131SH S 10110 3 (di l 1:10) GLP10-01-01-11-02 5 DA LG W131 S M S 10110 3 (di l 1:10) GLP10-01-01-11-02 6 DA LGW131 L0 10110 3 (di l 1:10) GLP10-01-01-11-02 7DA LGW131LD B 10110 3 (di l 1:10) GLP10-01-01-11-02 8 DALG W131LL S 10110 3 (di l 1:10 ) GLP10-01-01-11-02 9 DA LGW131 LM S 10110 3 (di l 1:10) GLP10-01-01-11-030 DA LG W131 LH S 10110 3 (di l 1:10) GLP10-01-01-11-03 1 DALG W132 R 010110 2 (di l 1:100 ) GLP10-01-01-11-03 2 DA LG W132 R D B 10110 2 (di l 1:100 ) GLP10-01-01-11-03 3 DA LG W132 R L S 10110 2 (di l 1:100 ) GLP10-01-01-11-034DA LGW132 R M S 10110 2 (di l 1:100 ) GLP10-01-01-11-03 5 DA LGW132RH S 10110 2 (di l 1:100 ) GLP10-01-01-11-03 6 DA LG W132 S 0 10110 2 (di l 1:100 ) 6LP10-01-01-11-03 7DA LG W132 S D B 10110 2 (di l 1:100 ) GLP10-01-01-11-03 8 DA LG W132 S L S 10110 2 (di l 1:100 ) GLP10-01-01-11-03 9 DALGW132SM S 10110 2 (di l 1:100 ) GLP10-01-01-11-040 DA LG W132 S H S 10110 2 (di l 1:100 ) GLP10-01-01-11-04 1 DA LGW132 L0 10110 3 (di l 1:10) GLP10-01-01-11-04 2 DALG W132LD B 10110 3 (di l 1:10 ) GLP10-01-01-11-04 3 DALG W132LL S 10110 3 (di l 1:10) GLP10-01-01-11-044DALG W132LM S 10110 3 (di l 1:10 ) GLP10-01-01-11-04 5 DA LG W132 LH S 10110 3 (di l 1:10) GLP10-01-01-11-04 6 DA LG W133 R 0 10110 2 (di l 1:10) GLP10-01-01-11-04 7DA LG W133 R D B 10110 2 (di l 1:10) GLP10-01-01-11-04 8 DA LG W133 R L S 10110 2 (di l 1:10) GLP10-01-01-11-04 9 DA LG W133 R M S 10110 2 (di l 1:10) GLP10-01-01-11-050 DALG W133 R H S 10110 2 (di l 1:10) GLP10-01-01-11-0S 1 DA LGW133 S 0 10110 3 (di l 1:10) GLP10-01-01-11-05 2 DALGW133SDB101103(di l 1:10) GLP10-01-01-11-05 3 DALG W133 S L S 10110 3 (di l 1:10) GLP10-01-01-11-05 4DALGW133SM S 10110 3 (di l 1:10) GLP10-01-01-11-05 5 DALG W133 S H S 10110 3 (di l 1:10) GLP10-01-01-11-05 6 DA LGW133 L010110 3 (di l 1:10) GLP10-01-01-11-05 7DALG W133LD B 10110 3 (di l 1:10 ) GLP10-01-01-11-05 8 DA LGW133LL S 10110 3 (di l 1:10) GLP10-01-01-11-05 9 DALGW133LMS101103(di l 1:10) GLP10-01-01-11-060 DA LGW133LH S 10110 3 (di l 1:10 ) GLP10-01-01-11-06 1 DALG W134 R 0 10110 5 (di l 1:100 ) GLP10-01-01-11-06 2 DA LGW134RD B 10110 5 (di l 1:100 ) GLP10-01-01-11-06 3 DA LG W134 R L S 10110 5 (di l 1:100 ) GLP10-01-01-11-06 4DA LG W134 R H S 10110 6 (di l 1:100 ) GLP10-01-01-11-07 0 DA LGW134 L0 10110 5 (di l 1:10) GLP10-01-01-11-07 1 DA LG W134 LD B 10110 6 (di l 1:10) GLP10-01-01-11-07 2 DA LGW134LL S 10110 6 (di l 1:10) Pre p Dat e Prepared : Prepared : Prepared : Prepared : Prepared : Prepared : Prepared : Prepared : Prepared : Prepared : Prepared : Prepared : Prepared : Prepared : Prepared : Prepared : Prepared : Prepared : Prepared : Prepared : Prepared : Prepared : Prepared : Prepared : Prepared : Prepared : Prepared : Prepared : Prepared : Prepared : Prepared : Prepared : Prepared : Prepared : Prepared : Prepared : Prepared : Prepared : Prepared : Prepared : Prepared : Prepared : Prepared : Prepared : Prepared : Prepared : Prepared : Prepared : Prepared : Prepared : Prepared : Prepared : Prepared : Prepared : Prepared : Prepared : Prepared : Prepared : Prepared : Prepared : Prepared : Prepared : Prepared : Prepared : Prepared : Prepared : Prepared : Prepared : Prepared : Prepared : Prepared : Prepared : Prepared : Prepared : Prepared : Prepared : Prepared : Prepared : Prepared : Prepared : Prepared : Prepared : Prepared : Prepared : 12/30/1 0 CJ G

12/30/1 0 CJ G 12/30/1 0 CJ G 12/30/1 0 CJ G 12/30/1 0 CJ G 12/30/1 0 CJ G 12/30/1 0 CJ G 12/30/1 0 CJ G 12/30/1 0 CJ G 12/30/1 0 CJ G 12/30/1 0 CJ G 12/30/1 0 CJ G 12/30/1 0 CJ G 12/30/1 0 CJ G 12/30/1 0 CJ G 12/30/1 0 CJ G 12/30/1 0 CJ G 12/30/1 0 CJ G

12/30/1 0 CJ G 12/30/1 0 CJ G 12/30/1 0 CJ G 12/30/1 0 CJ G 12/30/1 0 CJ G 12/30/1 0 CJ G 12/30/1 0 CJ G 12/30/1 0 CJ G 12/30/1 0 CJ G 12/30/1 0 CJ G 12/30/1 0 CJ G 12/30/1 0 CJ G 12/30/1 0 CJ G 12/30/1 0 CJ G 12/30/1 0 CJ G 12/30/1 0 CJ G 12/30/1 0 CJ G 12/30/1 0 CJ G 12/30/1 0 CJ G 12/30/1 0 CJ G 12/30/1 0 CJ G 12/30/1 0 CJ G 12/30/1 0 CJ G 12/30/1 0 CJ G 12/30/1 0 CJ G 12/30/1 0 CJ G 12/30/1 0 CJ G 12/30/1 0 CJ G 12/30/1 0 CJ G 12/30/1 0 CJ G 12/30/1 0 CJ G 12/30/1 0 CJ G 12/30/1 0 CJ G 12/30/1 0 CJ G 12/30/1 0 CJ G 12/30/1 0 CJ G 12/30/1 0 CJ G 12/30/1 0 CJ G 12/30/1 0 CJ G 12/30/1 0 CJ G 12/30/1 0 CJ G 12/30/1 0 CJ G 12/30/1 0 CJ G 12/30/1 0 CJ G 12/30/1 0 CJ G 12/30/1 0 CJ G 12/30/1 0 CJ G 12/30/1 0 CJ G 12/30/1 0 CJ G 12/30/1 0 CJ G 12/30/1 0 CJ G 12/30/1 0 CJ G 12/30/1 0 CJ G 12/30/1 0 CJ G 12/30/1 0 CJ G 12/30/1 0 CJ G 12/30/1 0 CJ G 12/30/1 0 CJ G 12/30/1 0 CJ G 12/30/1 0 CJ G 12/30/1 0 CJ G 12/30/1 0 CJ G 12/30/1 0 CJ G 12/30/1 0 CJ G 12/30/1 0 CJ G 12/30/1 0 CJ G toxic

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ETS-8-04 4saLiipl e pre p 101230.xl s Pag e 1 o f5 

# ^G7|-l€-( lSampl e I d Descriptio n Pre p Dat e

GLP10-01-01-11-07 3 DA LGW134 LM S 10110 5 (di l 1:10) Prepared : 12/30/1 0 CJ G toxic , Refrigerat e GLP10-01-01-11-074DA LGW134LH S 10110 5 (di l 1:10) Prepared : 12/30/1 0 CJ G toxic , Refrigerat e GLP10-01-01-11-07 5 DA LGW135R 0 10110 5 (di l 1:100 ) Prepared : 12/30/1 0 CJ G toxic , Refrigerat e GLP10-01-01-11-07 6 DA LGW135RD B 10110 5 (di l 1:100 ) Prepared : 12/30/1 0 CJ G toxic , Refrigerat e GLP10-01-01-11-07 7DA LGW135RL S 10110 5 (di l 1:100 ) Prepared : 12/30/1 0 CJ G toxic , Refrigerat e GLP10-01-01-11-07 8 DA LGW136RH S 10110 5 (di l 1:100 ) Prepared : 12/30/1 0 CJ G toxic , Refrigerat e GLP10-01-01-11-08 4DA LGW136 L0 10110 5 (di l 1:100 ) Prepared : 12/30/1 0 CJ G toxic , Refrigerat e GLP10-01-01-11-08 5 DA LGW135LD B 10110 5 (di l 1:100 ) Prepared : 12/30/1 0 CJ G toxic , Refrigerat e GLP10-01-01-11-08 6 DA LGW136LL S 10110 5 (di l 1:100 ) Prepared : 12/30/1 0 CJ G toxic

. Refrigerat e GLP10-01-01-11-08 7DA LGW136 LM S 10110 6 (di l 1:100 ) Prepared : 12/30/1 0 CJ G toxic , Refrigerat e GLP10-01-01-11-08 8 DA LGW136LH S 10110 5 (di l 1:100 ) Prepared : 12/30/1 0 CJ G toxic , Refrigerat e GLP10-01-01-11-08 9 DA LGW136 S 0 10110 3 (di l 1:10) Prepared : 12/30/1 0 CJ G toxic , Refrigerat e GLP10-01-01-11-09 0 DA LGW136SD B 10110 3 (di l 1:10) Prepared : 12/30/1 0 CJ G toxic , Refrigerat e GLPl0-01-01-11-09 1 DA LGW136SL S 10110 3 (di l 1:10) Prepared : 12/30/1 0 CJ G toxic

. Refrigerat e GLP10-01-01-11-09 2 DA LGW136 S M S 10110 3 (di l 1:10) Prepared : 12/30/1 0 CJ G toxic

. Refrigerat e GLP10-01-01-11-09 3 DA LGW136SH S 10110 3 (di l 1:10) Prepared : 12/30/1 0 CJ G toxic

. Refrigerat e GLP10-01-01-11-09 4DALGW136L0101103(dil1:10 ) Prepared : 12/30/10CJ G toxic

. Refrigerat e GLP10-01-01-11-09 6 DA LGW136LD B 10110 3 (di l 1:10) Prepared : 12/30/1 0 CJ G toxic

. Refrigerat e GLP10-01-01-11-09 6 DA LGW136LL S 10110 3 (di l 1:10) Prepared : 12/30/1 0 CJ G toxic

. Refrigerat e GLP10-01-01-11-09 7DA LGW136 LM S 10110 3 (di l 1:10) Prepared : 12/30/1 0 CJ G toxic

. Refrigerat e GLP10-01-01-11-09 8 DA LGW136LH S 10110 3 (di l 1:10) Prepared : 12/30/1 0 CJ G toxic

. Refrigerat e GLP10-01-01-11-10 9 DALG W138 8 0 10111 0 (di l 1:10) Prepared : 12/30/10CJ G toxic

. Refrigerat e GLP10-01-01-11-110 DALG W138SD B 101110(di l 1:10) Prepared : 12/30/10CJ G toxic

. Refrigerat e GLP10-01-01-11-11 1 DALG W138SL S 101110(di l 1:10) Prepared : 12/30/10CJ G toxic

. Refrigerat e GLP10-01-01-11-11 2 DALGW138SMS101110(dil1:10 ) Prepared : 12/30/10CJ G toxic

. Refrigerat e GLP10-01-01-11-11 3 DALG W138SH S 101110(di l 1:10) Prepared : 12/30/10CJ G toxic

. Refrigerat e GLP10-01-01-11-11 9 DALGWCW26R 0 10111 0 (di l 1:10) Prepared : 12/30/1 0 CJ G toxic

. Refrigerat e GLP10-01-01-11-12 0 DALGWCW26RDB101110(di l 1:10) Prepared : 12/30/10CJ G toxic

. Refrigerat e GLP10-01-01-11-12 1 DA LG WCW26 R L S 10111 0 (di l 1:10) Prepared : 12/30/1 0 CJ G toxic

. Refrigerat e GLP10-01-01-11-12 2 DALGWCW26RMS101110(dil1:10 ) Prepared : 12/30/10CJ G toxic

. Refrigerat e GLP10-01-01-11-12 3 DALGWCW26RHS101110(di l 1:10) Prepared : 12/30/1 0 CJ G toxic

. Refrigerat e GLP10-01-01-11-12 4DA LG WCW26 L0 10111 0 (di l 1:10) Prepared : 12/30/1 0 CJ G toxic

. Refrigerat e GLP10-01-01-11-12 6 DA LGWCW26LD B 10111 0 (di l 1:10) Prepared : 12/30/1 0 CJ G toxic

. Refrigerat e GLP10-01-01-11-12 6 DA LG WCW26 LL S 10111 0 (di l 1:10) Prepared : 12/30/1 0 CJ G toxic , Refrigerat e GLP10-01-01-11-12 7DALGWCW26LMS101110(dil1:10 ) Prepared : 12/30/1 0 CJ G toxic

. Refrigerat e GLP10-01-01-11-12 8 DA LGWCW26LH S 10111 0 (di l 1:10) Prepared : 12/30/1 0 CJ G toxic

. Refrigerat e GLP10-01-01-11-12 9 DALGW140R0101104(dil1:10 ) Prepared : 12/30/10CJ G toxic

. Refrigerat e GLP10-01-01-11-130 DA LGW140RD B 10110 4(di l 1:10 ) Prepared : 12/30/1 0 CJ G toxic

. Refrigerat e GLP10-01-01-11-13 1 DA LGW140RL S 10110 4(di l 1:10) Prepared : 12/30/1 0 CJ G toxic

. Refrigerat e GLP10-01-01-11-13 2 DA LGW140 R M S 10110 4(di l 1:10) Prepared : 12/30/1 0 CJ G toxic

. Refrigerat e GLP10-01-01-11-13 3 DA LGW140RH S 10110 4(di l 1:10) Prepared : 12/30/1 0 CJ G toxic

. Refrigerat e GLP10-01-01-11-134DALG W141R 0 101110(di l 1:10) Prepared : 12/30/1 0 CJ G toxic

. Refrigerat e GLP10-01-01-11-13 5 DALGW141RDB101110(dil1:10 ) Prepared : 12/30/10CJ G toxic

. Refrigerat e GLP10-01-01-11-13 6 DA LGW141RL S 10111 0 (di l 1:10) Prepared : 12/30/1 0 CJ G toxic

. Refrigerat e GLP10-01-01-11-13 7DA LG W141 R M S 10111 0 (di l 1:10) Prepared : 12/30/1 0 CJ G toxic

. Refrigerat e GLP10-01-01-11-13 8 DA LGW141RH S 10111 0 (di l 1:10) Prepared : 12/30/1 0 CJ G toxic

. Refrigerat e GLP10-01-01-11-13 9 DA LGW142R0101110(di l 1:10) Prepared : 12/30/1 0 CJ G toxic

. Refrigerat e GLP10-01-01-11-14 0 DALGW142RDB101110(dil1:10 ) Prepared : 12/30/10CJ G toxic

. Refrigerat e GLP10-01-01-11-14 1 DA LGW142RL S 10111 0 (di l 1:10) Prepared : 12/30/1 0 CJ G toxic

. Refrigerat e GLP10-01-01-11-14 2 DA LGW142 R M S 10111 0 (dii1:10 ) Prepared : 12/30/1 0 CJ G toxic

. Refrigerat e GLP10-01-01-11-14 3 DALGW142RHS101110(dil1:10 ) Prepared : 12/30/10CJ G toxic

. Refrigerat e GLP10-01-01-11-14 4DALGW144R0101110(dil1:10 ) Prepared : 12/30/10CJ G toxic

. Refrigerat e GLP10-01-01-11-14 5 DALGW144RDB101110(dil1:10 ) Prepared : 12«0/10CJ G toxic

. Refrigerat e GLP10-01-01-11-14 6 DA LGW144RL S 10111 0 (di l 1:10) Prepared : 12/30/1 0 CJ G toxic

. Refrigerat e GLP10-01-01-11-14 7DA LGW144 R M S 10111 0 (di l 1:10) Prepared : 12/30/1 0 CJ G toxic

. Refrigerat e GLP10-01-01-11-14 8 DA LGW144RH S 10111 0 (di l 1:10) Prepared : 12/30/1 0 CJ G toxic

. Refrigerat e GLP10-01-01-11-15 4Tri p Blan k Se t1 H S (di l 1:100 ) Prepared : 12/30/1 0 CJ G toxic

. Refrigerat e GLP10-01-01-11-15 9 Tri p Blan k Se t2 H S (di l 1:100 ) Prepared : 12/30/1 0 CJ G toxic

. Refrigerat e GLP10-01-01-11-16 4Tri p Blan k Se t3 H S (di l 1:100 ) Prepared : 12/30/1 0 CJ G toxic

. Refrigerat e GLP10-01-01-11-16 9 Tri p Blan k Se t4H S (di l 1:100 ) Prepared : 12/30/1 0 CJ G toxic

. Refrigerat e

Solven tBlan k

Mill i Q Wate rTNI0-047 5 Aliquoted : 12/30/1 0 CJ G toxic

. Refrigerat e Solven tBlan k

Milli Q Wate rTN10-047 5 Aliquoted : 12/30/1 0 CJ G toxic

. Refrigerat e Solven tBlan k

Milli Q Wate rTN I 0-047 5 Aliquoted : 12/30/1 0 CJ G toxic

. Refrigerat e Solven tBlan k

Mill i Q Wate rTN10-047 5 Aliquoted : 12/30/1 0 CJ G toxic

. Refrigerat e Solven tBlan k

Mill i Q Wate rTNI0-047 5 Aliquoted : 12/30/1 0 CJ G toxic

. Refrigerat e Solven tBlan k

Mill i Q Wate rTN10-047 5 Aliquoted : 12/30/1 0 CJ G toxic

. Refrigerat e Solven tBlan k

Mill i Q Wate rTN10-047 5 Aliquoted : 12/30/1 0 CJ G toxic

. Refrigerat e Solven tBlan k

Milli Q Wate rTN10-047 5 Aliquoted : 12/30/1 0 CJ G toxic

. Refrigerat e Solven tBlan k

. Mill i Q Wate rTNI0-047 5 Aliquoted ; 12/30/1 0 CJ G toxic

. Refrigerat e Solven tBlan k

Mill i Q Wate rTN10-047 5 Aliquoted : 12/30/1 0 CJ G toxic

. Refrigerat e 08008-194- 1 0.02 5 ng/m LF C st d i n Mill i Q Wate rAliquoted : 12/30/1 0 CJ G toxic , Refrigerat e 08008-194- 2 0.0 3 ng/m LF C st d i n Mill i Q Wate rAliquoted : 12/30/1 0 CJ G toxic

. Refrigerat e 08008-194- 3 0.0 4ng/m LF C st d i n Mill i Q Wate rAliquoted : 12/30/1 0 CJ G toxic , Refrigerat e 08008-194- 40.0 5 ng/mLF C st d i n Milli Q Wate rAliquoted : 12/30/1 0 CJ G toxic , Refrigerat e 08008-194- 6 0. 1 ng/m LF C st d i n Mill i Q Wate rAliquoted : 12/30/1 0 CJ G toxic , Refrigerat e 08008-194- 6 0.2 5 ng/m LF C st d i n Mill i Q Wate rAliquoted : 12/30/1 0 CJ G toxic

. Refrigerat e 08008-194- 70. 5 ng/m LF C st d i n Mill i Q Wate rAliquoted : 12/30/1 0 CJ G toxic , Refrigerat e 08008-194- 8 1. 0 ng/mLF C st d i n Milli Q Wate rAliquoted : 12/30/1 0 CJ G toxic , Refrigerat e 08008-194- 9 2. 5 ng/m LF C st d i n Mill i Q Wate rAliquoted : 12/30/1 0 CJ G toxic

. Refrigerat e 08008-194-1 0 5. 0 ng/m LF C st d i n Mill i Q Wate rAliquoted : 12/30/1 0 CJ G toxic

. Refrigerat e 08008-194-1 1 1 0 ng/mLF C st d i n Milli Q Wate rAliquoted : 12/30/1 0 CJ G toxic , Refrigerat e 08008-194-1 2 2 5 ng/m LF C st d i n Mill i Q Wate rAliquoted : 12/30/1 0 CJ G toxic , Refrigerat e 08008-194-1 3 5 0 ng/m LF C st d i n Mill i Q Wate rAliquoted : 12/30/1 0 CJ G toxic , Refrigerat e 08008-194-1 47 5 ng/m LF C st d i n Mill i Q Wate rAliquoted : 12/30/1 0 CJ G toxic , Refrigerat e

ETS-8-04 4sampl e pre p 101230.xl s Pag e 2 o f5Sampl e I d

08008-194-1 5

LCS-101230- 1 LCS-101230- 2 LCS-101230- 3 LCS-101230- 4 LCS-101230- 5 LCS-101230- 6 LCS-101230- 7 LCS-101230- 8 LCS-101230- 9 LCS-101230-1 0 LCS-101230-1 1 LCS-101230-1 2 LCS-101230-1 3 LCS-101230-1 4 LCS-101230-1 5 LCS-101230-1 6 LCS-101230-1 7 LCS-101230-1 8 Descriptio n 10 0 ng/m LF C st d i n Mill i Q Wate r O.Sppb LC S O.Spp b LC S O.Sppb LC S Spp b LC S Spp b LC S Spp b LC S 30pp b LC S 30pp b LC S 30pp b LC S O.Spp b LC S EC F O.Spp b LC S EC F O.Spp b LC S EC F Spp b LC S EC F Spp b LC S EC F Spp b LC S EC F 30pp b LC S EC F 30pp b LC S EC F 30pp b LC S EC F Pre p Dat e Aliquoted : 12/30/1 0 CJ G toxic

. Refrigerat e

GLP10-01-01-11-00 1 DALG W130R 0 10110 5 (di l 1:100 ) GLP10-01-01-11-00 2 DALG W130RDB10110S(diM:100 ) GLP10-01-01-11-00 3 DALG W130 R L S 10110S(di11:100 ) GLP10-01-01-11-004DALGW130RM S 10110 5 (di l 1:100 ) GLP10-01-01-11-00 5 DALG WISO R H S 10110 5 (di l 1:100 ) GLP10-01-01-11-00 6 DA LG W130 S 0 10110 5 (di l 1:100 ) GLP10-01-01-11-00 7DA LG W130 S D B 10110 5 (di l 1:100 ) GLP10-01-01-11-00 8 DA LG W130 S L S 10110 5 (di l 1:100 ) GLP10-01-01-11-00 9 DA LG W130 S M S 10110 S (di l 1:100 ) GLP10-01-01-11-010 DA LG W130 S H S 10110 5 (di l 1:100 ) GLP10-01-01-11-01 1 DA LGW130 L010110 5 (di l 1:10) GLP10-01-01-11-01 2 DA LGW130LD B 10110 5 (dil1:10 ) GLP10-01-01-11-01 3 DALG W130LL S 10110 5 (di l 1:10) GLP10-01-01-11-014DALG W130LM S 10110 5 (di l 1:10) GLP10-01-01-11-01 5 DA LG W130 LH S 10110 5 (di l 1:10) GLP10-01-01-11-01 6 DA LG W130 LR B 10110 5 GLP10-01-01-11-01 7DA LG W131 R 0 10110 3 (di l 1:100 ) GLP10-01-0M1-01 8 DA LG W131 R D B 10110 3 (di l 1:100 ) GLP10-01-01-11-01 9 DA LGW131RL S 10110 3 (dil1:100 ) GLP10-01-01-11-020 DALG W131RH S 10110 3 (di l 1:100 ) GLP10-01-01-11-02 1 DA LG W131 S 0 10110 3 (di l 1:10) GLP10-01-01-11-02 2 DALGW131SD B 10110 3 (di l 1:10) GLP10-01-01-11-02 3 DA LG W131 S L S 10110 3 (di l 1:10) GLP1O-01-0M1-02 4DA LG W131 S H S 10110 3 (di l 1:10) GLP10-01-01-11-02 5 DA LG W131 S M S 10110 3 (di l 1:10) GLP10-01-01-11-02 6 DA LGW131 L0 10110 3 (di l 1:10) GLP10-01-01-11-02 7DA LG W131 LD B 10110 3 (di l 1:10) GLP10-01-01-11-02 8 DA LG W131 LL S 10110 3 (di l 1:10) GLP10-01-01-11-02 9 DA LGW131 LM S 10110 3 (di l 1:10) GLP10-01-OM1-03 0 DA LGW131LH S 10110 3 (di l 1:10) GLP10-01-01-11-03 1 DA LG W132 R 0 10110 2 (di l 1:100 ) GLP10-01-01-11-03 2 DA LG W132 R D B 10110 2 (di l 1:100 ) GLP10-01-01-11-03 3 DA LG W132 R L S 10110 2 (di l 1:100 ) GLP10-01-01-11-034DA LG W132 R M S 10110 2 (di l 1:100 ) GLP1CW)1-01-11-03 5 DA LG W132 R H S 10110 2 (di l 1:100 ) GLP10-01-01-11-03 6 DA L6W132 S 0 10110 2 (di l 1:100 ) GLP10-01-01-11-03 7DA LGW132SD B 10110 2 (di l 1:100 ) GLP10-01-01-11-03 8 DA LG W132 S L S 10110 2 (di l 1:100 ) GLP10-01-01-11-03 9 DA LG W132 S M S 10110 2 (di l 1:100 ) GLP10-01-01-11-040 DA LG W132 S H S 10110 2 (di l 1:100 ) GLP10-01-01-11-04 1 DA LGW132 L0 10110 3 (di l 1:10) GLP10-01-01-11-04 2 DA LG W132 LD B 10110 3 (di l 1:10) GLP10-01-01-11-04 3 DA LGW132LL S 10110 3 (di l 1:10) GLP10-01-01-11-044DALG W132LM S 10110 3 (di l 1:10) GLP10-01-01-11-04 5 DA LG W132 LH S 10110 3 (di l 1:10) GLP10-01-01-11-04 6 DA LG W133 R 0 10110 2 (di l 1:10) GLP10-01-01-11-04 7DA LG W133 R D B 10110 2 (di l 1:10) GLP10-01-01-11-04 8 DA LG W133 R L S 10110 2 (di l 1:10) GLP10-01-01-11-04 9 DALG W133RM S 10110 2 (di l 1:10) GLP10-01-01-11-050 DALG W133 R H S 10110 2 (di l 1:10) GLP10-01-01-11-05 1 DA LG W133 S 0 10110 3 (di l 1:10) GLP10-01-01-11-05 2 DA LG W133 S D B 10110 3 (di l 1:10) GLP10-01-01-11-05 3 DA LG W133 S L S 10110 3 (di l 1:10) GLP10-01-01-11-05 4DALGW133SM S 10110 3 (di l 1:10) GLP10-01-01-11-0S S DA LGW133SH S 10110 3 (di l 1:10) GLP10-01-01-11-05 6 DA LGW133 L0 10110 3 (di l 1:10) GLP10-01-01-11-05 7DA LG W133 LD B 10110 3 (di l 1:10) GLP10-01-01-11-OS 8 DA LG W133 LL S 10110 3 (di l 1:10) GLP10-01-01-11-05 9 DA LGW133LM S 10110 3 (di t1:10) GLP10-01-01-11-060 DA LG W133 LH S 10110 3 (di l 1:10) GLP10-01-01-11-06 1 DALGW134R 0 10110 5 (di l 1:100 ) GLP10-01-01-11-06 2 DA LG W134 R D B 10110 S (di l 1:100 ) GLP10-01-01-11-06 3 DA LG W134 R L S 10110 5 (di l 1:100 ) GLP10-01-01-11-064DA LG W134 R H S 10110 5 (di l 1:100 ) Aliquoted : Aliquoted : Aliquoted : Aliquoted : Aliquoted : Aliquoted : Aliquoted : Aliquoted : Aliquoted : Aliquoted ; Aliquoted : Aliquoted : Aliquoted : Aliquoted : Aliquoted : Aliquoted : Aliquoted : Aliquoted : Aliquoted : Aliquote d Aliquote d Aliquote d Aliquote d Aliquote d Aliquote d Aliquote d Aliquote d Aliquote d Aliquote d Aliquote d Aliquote d Aliquote d Aliquote d Aliquote d Aliquote d Aliquote d Aliquote d Aliquote d Aliquote d Aliquote d Aliquote d Aliquote d Aliquote d Aliquote d Aliquote d Aliquote d Aliquote d Aliquote d Aliquote d Aliquote d Aliquote d Aliquote d Aliquote d Aliquote d Aliquote d Aliquote d Aliquote d Aliquote d Aliquote d Aliquote d Aliquoted : Aliquoted : Aliquoted : Aliquoted : Aliquote d Aliquote d Aliquoted : Aliquote d Aliquote d Aliquoted : Aliquoted : Aliquoted : Aliquote d Aliquoted : Aliquote d Aliquoted : Aliquote d Aliquote d Aliquote d Aliquoted : Aliquoted : Aliquote d 2/30/1 0 CJ G

2/30/1 0 CJ G 2/30/1 0 CJ G 2/30/1 0 CJ G 2/30/1 0 CJ G 2/30/1 0 CJ G 2/30/1 0 CJ G 2/30/1 0 CJ G 2/30/1 0 CJ G 2/30/1 0 CJ G 2/30/1 0 CJ G 2/30/1 0 CJ G 2/30/1 0 CJ G 2/30/1 0 CJ G 2/30/1 0 CJ G 2/30/1 0 CJ G 2/30/1 0 CJ G 2/30/1 0 CJ G

2/30/1 0 CJ G 2/30/1 0 CJ G 2/30/1 0 CJ G 2/30/1 0 CJ G 2/30/1 0 CJ G 2/30/1 0 CJ G 2/30/1 0 CJ G 2/30/1 0 CJ G 2/30/1 0 CJ G 2/30/1 0 CJ G 2/30/1 0 CJ G 2/30/1 0 CJ G 2/30/1 0 CJ G 2/30/1 0 CJ G 2/30/1 0 CJ G 2/30/1 0 CJ G 2/30/1 0 CJ G 2/30/1 0 CJ G 2/30/1 0 CJ G 2/30/1 0 CJ G 2/30/1 0 CJ G 2/30/1 0 CJ G 2/30/1 0 CJ G 2/30/1 0 CJ G 2/30/1 0 CJ G 2/30/1 0 CJ G 2/30/1 0 CJ G 2/30/1 0 CJ G 2/30/1 0 CJ G 2/30/1 0 CJ G 2/30/1 0 CJ G 2/30/1 0 CJ G 2/30/1 0 CJ G 2/30/1 0 CJ G 2/30/1 0 CJ G 2/30/1 0 CJ G 2/30/1 0 CJ G 2/30/1 0 CJ G 2/30/1 0 CJ G 2/30/1 0 CJ G 2/30/1 0 CJ G 2/30/1 0 CJ G 2/30/1 0 CJ G 2/30/1 0 CJ G 2/30/1 0 CJ G 2/30/1 0 CJ G 2/30/1 0 CJ G 2/30/1 0 CJ G 2/30/1 0 CJ G 2/30/1 0 CJ G 2/30/1 0 CJ G 2/30/1 0 CJ G 2/30/1 0 CJ G 2/30/1 0 CJ G 2/30/1 0 CJ G 2/30/1 0 CJ G 2/30/1 0 CJ G 2/30/1 0 CJ G 2/30/1 0 CJ G 2/30/1 0 CJ G 2/30/1 0 CJ G 2/30/1 0 CJ G 2/30/1 0 CJ G 2/30/1 0 CJ G toxic ,

toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , toxic , Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e Refrigerat e

ETS-8-04 4sampl e pre p 101230.xl s Pag e 3 o f5Sampl e I d Descriptio n Pre p Dat e

GLP10-01-01-11-06 5 DA LG W134 S 0 10110 5 Aliquoted : 12/30/1 0 CJ G toxic , Refrigerat e GLP10-01-01-11-06 6 DA LGW134SD B 10110 5 Aliquoted : 12/30/1 0 CJ G toxic , Refrigerat e GLP10-01-01-11-06 7DALGW134SLS10110 5 Aliquoted : 12/30/1 0 CJ G toxic , Refrigerat e GLP10-01-01-11-06 8 DA LGW134 S M S 10110 5 Aliquoted : 12/30/1 0 CJ G toxic , Refrigerat e GLP10-01-01-11-06 9 DA LGW134SH S 10110 6 Aliquoted : 12/30/1 0 CJ G toxic

. Refrigerat e GLP10-01-01-11-070 DALGW134L0101106(dil1:10 ) Aliquoted : 12/30/10CJ G toxic , Refrigerat e GLP10-01-01-11-07 1 DALGW134LDB101105(dil1:10 ) Aliquoted : 12/30/10CJ G toxic , Refrigerat e GLP10-01-01-11-07 2 DA LGW134LL S 10110 6 (di l 1:10) Aliquoted : 12/30/1 0 CJ G toxic

. Refrigerat e GLP10-01-01-11-07 3 DALG W134LM S 101106(di l 1:10) Aliquoted : 12/30/1 0 CJ G toxic

. Refrigerat e GLP10-01-01-11-074DALGW134LH S 101106(di l 1:10) Aliquoted : 12/30/10CJ G toxic

. Refrigerat e GLP10-01-01-11-07 6 DA LGW135 R 0 10110 6 (di l 1:100 ) Aliquoted : 12/30/1 0 CJ G toxic

. Refrigerat e GLP10-01-01-11-07 6 DA LGW135RD B 101105(di l 1:100 ) Aliquoted : 12/30/1 0 CJ G toxic , Refrigerat e GLP10-01-01-11-07 7DALGW135RL S 101106(di l 1:100 ) Aliquoted : 12/30/10CJ G toxic

. Refrigerat e GLP10-01-01-11-07 8 DALGW136RH S 101105(di l 1:100 ) Aliquoted : 12/30/10CJ G toxic

. Refrigerat e GLP10-01-01-11-07 9 DA LGW135 S 0 10110 5 Aliquoted : 12/30/1 0 CJ G toxic

. Refrigerat e GLP10-01-01-11-080 DA LGW135SD B 10110 5 Aliquoted : 12/30/1 0 CJ G toxic

. Refrigerat e GLP10-01-01-11-08 1 DALGW135SLS10110 5 Aliquoted : 12/30/1 0 CJ G toxic

. Refrigerat e GLP10-01-01-11-08 2 DA LGW135 S M S 10110 5 Aliquoted : 12/30/1 0 CJ G toxic

. Refrigerat e GLP10-01-01-11-08 3 DALGW135SHS10110 6 Aliquoted : 12/30/1 0 CJ G toxic , Refrigerat e GLP10-01-01-11-084DA LGW136 L0 10110 5 (di l 1:100 ) Aliquoted : 12/30/1 0 CJ G toxic

. Refrigerat e GLP10-01-01-11-08 5 DA LGW135LD B 10110 5 (di l 1:100 ) Aliquoted : 12/30/1 0 CJ G toxic

. Refrigerat e GLP10-01-01-11-08 6 DA LGW135LL S 10110 5 (di l 1:100 ) Aliquoted : 12/30/1 0 CJ G toxic

. Refrigerat e GLP10-01-01-11-08 7DA LGW135 LM S 10110 5 (di l 1:100 ) Aliquoted : 12/30/1 0 CJ G toxic

. Refrigerat e GLP10-01-01-11-08 8 DA LGW136LH S 10110 5 (di l 1:100 ) Aliquoted : 12/30/1 0 CJ G toxic

. Refrigerat e GLP10-01-01-11-08 9 DALG W136S 0 101103(di l 1:10) Aliquoted : 12/30/10CJ G toxic

. Refrigerat e GLP10-01-01-11-09 0 DALGW136SD B 101103(dil1:10 ) Aliquoted : 12/30/10CJ G toxic

. Refrigerat e GLP10-01-01-11-09 1 DALGW136SLS101103(dil1:10 ) Aliquoted : 12/30/1 0 CJ G toxic

. Refrigerat e GLP10-01-01-11-09 2 DALGW136SMS101103(di l 1:10) Aliquoted : 12/30/1 0 CJ G toxic

. Refrigerat e GLP10-01-01-11-09 3 DA LGW136SH S 10110 3 (di l 1:10 ) Aliquoted : 12/30/1 0 CJ G toxic

. Refrigerat e GLP10-01-01-11-094DALGW136L0101103(di l 1:10) Aliquoted : 12/30/10CJ G toxic

. Refrigerat e GLP10-01-01-11-09 6 DALG W136LD B 101103(di l 1:10) Aliquoted : 12/30/10CJ G toxic

. Refrigerat e GLP l 0-01-01-11-09 6 DA LG W136 LL S 10110 3 (di l 1:10) Aliquoted : 12/30/1 0 CJ G toxic

. Refrigerat e GLP10-01-01-11-09 7DALG W136LM S 101103(di l 1:10) Aliquoted : 12/30/1 0 CJ G toxic

. Refrigerat e GLP10-01-01-11-09 8 DA LGW136LH S 10110 3 (di l 1:10) Aliquoted : 12/30/1 0 CJ G toxic

. Refrigerat e GLP10-01-01-11-09 9 DA LGW137 S 0 10110 9 Aliquoted : 12/30/1 0 CJ G toxic

. Refrigerat e GLP10-01-01-11-100 DA LGW137SD B 10110 9 Aliquoted : 12/30/1 0 CJ G toxic

. Refrigerat e GLP10-01-01-11-10 1 DA LGW137SL S 10110 9 Aliquoted : 12/30/1 0 CJ G toxic

. Refrigerat e GLP10-01-01-11-10 2 DALGW137SMS10110 9 Aliquoted : 12/30/1 0 CJ G toxic

. Refrigerat e GLP10-01-01-11-10 3 DALGW137SHS10110 9 Aliquoted : 12/30/1 0 CJ G toxic

. Refrigerat e GLP10-01-01-11-104DALG W137L 0 10110 9 Aliquoted : 12/30/1 0 CJ G toxic

. Refrigerat e GLP10-01-01-11-10 6 DA LG W137 LD B 10110 9 Aliquoted : 12/30/1 0 CJ G toxic

. Refrigerat e GLP10-01-01-11-10 6 DALG W137LL S 10110 9 Aliquoted : 12/30/1 0 CJ G toxic

. Refrigerat e GLP10-01-01-11-10 7DALG W137LM S 10110 9 Aliquoted : 12/30/1 0 CJ G toxic

. Refrigerat e GLP10-01-01-11-10 8 DALG W137LH S 10110 9 Aliquoted : 12/30/1 0 CJ G toxic

. Refrigerat e GLP10-01-01-11-10 9 DA LGW138 S 0 10111 0 (di l 1:10) Aliquoted : 12/30/1 0 CJ G toxic

. Refrigerat e GLP10-01-01-11-11 0 DA LGW138SD B 10111 0 (di l 1:10) Aliquoted : 12/30/1 0 CJ G toxic

. Refrigerat e GLP10-01-01-11-11 1 DA LGW138SL S 10111 0 (di l 1:10) Aliquoted : 12/30/1 0 CJ G toxic

. Refrigerat e GLP10-01-01-11-11 2 DALGW138SMS101110(dil1:10 ) Aliquoted : 12/30/1 0 CJ G toxic

. Refrigerat e GLP10-01-01-11-11 3 DA LGW138SH S 10111 0 (di l 1:10) Aliquoted : 12/30/1 0 CJ G toxic

. Refrigerat e GLP10-01-01-11-114DALG W138L 0 10111 0 Aliquoted : 12/30/1 0 CJ G toxic

. Refrigerat e GLP10-01-01-11-11 5 DALG W138LD B 10111 0 Aliquoted : 12/30/1 0 CJ G toxic

. Refrigerat e GLP10-01-01-11-11 6 DALG W138LL S 10111 0 Aliquoted : 12/30/1 0 CJ G toxic

. Refrigerat e GLP10-01-01-11-11 7DALG W138LM S 10111 0 Aliquoted : 12/30/1 0 CJ G toxic

. Refrigerat e GLP10-01-01-11-11 8 DALG W138LH S 10111 0 Aliquoted : 12/30/1 0 CJ G toxic

. Refrigerat e GLP10-01-01-11-11 9 DALGWCW26R 0 10111 0 (di l 1:10) Aliquoted : 12/30/1 0 CJ G toxic

. Refrigerat e GLP10-01-01-11-12 0 DA LGWCW26RD B 10111 0 (di l 1:10) Aliquoted : 12/30/1 0 CJ G toxic

. Refrigerat e GLP10-01-01-11-12 1 DA LGWCW26RL S 10111 0 (di l 1:10) Aliquoted : 12/30/1 0 CJ G toxic

. Refrigerat e GLP10-01-01-11-12 2 DALGWCW26RM S 101110(di l 1:10) Aliquoted : 12/30/1 0 CJ G toxic

. Refrigerat e GLP10-01-01-11-12 3 DA LGWCW26RH S 10111 0 (di l 1:10) Aliquoted : 12/30/1 0 CJ G toxic

. Refrigerat e GLP10-01-01-11-124DALGWCW26L 0 10111 0 (di l 1:10) Aliquoted : 12/30/1 0 CJ G toxic

. Refrigerat e GLP10-01-01-11-12 6 DA LGWCW26LD B 10111 0 (di l 1:10) Aliquoted : 12/30/1 0 CJ G toxic

. Refrigerat e GLP10-01-01-11-12 6 DA LGWCW26LL S 10111 0 (di l 1:10) Aliquoted : 12/30/1 0 CJ G toxic

. Refrigerat e GLP10-01-01-11-12 7DALGWCW26LMS101110(dil1:10 ) Aliquoted : 12/30/1 0 CJ G toxic

. Refrigerat e GLP10-01-01-11-12 8 DALGWCW26LHS101110(dil1:10 ) Aliquoted : 12/30/1 0 CJ G toxic

. Refrigerat e GLP l 0-01-01-11-12 9 DA LGW140 R 0 10110 4(di l 1:10 ) Aliquoted : 12/30/1 0 CJ G toxic

. Refrigerat e GLP l 0-01-01-11-13 0 DA LGW140RD B 10110 4(di l 1:10) Aliquoted : 12/30/1 0 CJ G toxic

. Refrigerat e GLP l 0-01-01-11-13 1 DA LGW140RL S 10110 4(di l 1:10) Aliquoted : 12/30/1 0 CJ G toxic

. Refrigerat e GLP10-01-01-11-13 2 DA LGW140 R M S 10110 4(di l 1:10) Aliquoted : 12/30/1 0 CJ G toxic

. Refrigerat e GLP10-01-01-11-13 3 DA LGW140RH S 10110 4(di l 1:10) Aliquoted : 12/30/1 0 CJ G toxic

. Refrigerat e GLP10-01-01-11-134DA LGW141 R 0 10111 0 (di l 1:10) Aliquoted : 12/30/1 0 CJ G toxic

. Refrigerat e GLP10-01-01-11-13 5 DA LGW141RD B 10111 0 (di l 1:10) Aliquoted : 12/30/1 0 CJ G toxic

. Refrigerat e GLP10-01-01-11-13 6 DA LGW141RL S 10111 0 (di l 1:10) Aliquoted : 12/30/1 0 CJ G toxic

. Refrigerat e GLP10-01-01-11-13 7DA LGW141 R M S 10111 0 (di l 1:10) Aliquoted : 12/30/1 0 CJ G toxic , Refrigerat e GLP10-01-01-11-13 8 DALGW141RHS101110(dil1:10 ) Aliquoted : 12/30/1 0 CJ G toxic , Refrigerat e GLP10-01-01-11-13 9 DA LGW142 R 0 10111 0 (di l 1:10) Aliquoted : 12/30/1 0 CJ G toxic , Refrigerat e GLP10-01-01-11-140 DALGW142RD B 101110(di l 1:10) Aliquoted : 12/30/1 0 CJ G toxic

. Refrigerat e GLP10-01-01-11-14 1 DA LGW142RL S 10111 0 (di l 1:10) Aliquoted : 12/30/1 0 CJ G toxic , Refrigerat e GLP10-01-01-11-14 2 DA LGW142 R M S 10111 0 (di l 1:10 ) Aliquoted : 12/30/1 0 CJ G toxic

. Refrigerat e GLP10-01-01-11-14 3 DA LGW142RH S 10111 0 (di l 1:10) Aliquoted : 12/30/1 0 CJ G toxic

. Refrigerat e GLP10-01-01-11-144DA LGW144 R 0 10111 0 (di l 1:10) Aliquoted : 12/30/1 0 CJ G toxic

. Refrigerat e GLP10-01-01-11-14 6 DALGW144RDB101110(dil1:10 ) Aliquoted : 12/30/1 0 CJ G toxic

. Refrigerat e GLP10-01-01-11-14 6 DALGW144RLS101110(dil1:10 ) Aliquoted : 12/30/1 0 CJ G toxic

. Refrigerat e GLP10-01-01-11-14 7DA LGW144 R M S 10111 0 (di l 1:10) Aliquoted : 12/30/1 0 CJ G toxic , Refrigerat e GLP10-01-01-11-14 8 DALGW144RHS101110(dil1:10 ) Aliquoted : 12/30/1 0 CJ G toxic

. Refrigerat e GLP10-01-01-11-14 9 DA LGW144RR B 10111 0 Aliquoted : 12/30/1 0 CJ G toxic

. Refrigerat e

ETS-8-04 4sampl e pre p 101230.xl s labe l Pag e 4o f5Sampl e I d GLP10-01-0 1 GLP10-01-0 1 GLP10-01-0 1 GLP10-01-0 1 GLP10-01-0 1 GLP10-01-0 1 GLP10-01-0 1 GLP10-01-0 1 GLP10-01-0 1 GLP10-01-0 1 GLP10-01-0 1 GLP10-01-0 1 GLP10-01-0 1 GLP10-01-0 1 GLP10-01-0 1 GLP10-01-0 1 GLP10-01-0 1 GLP10-01-0 1 GLP10-01-0 1 GLP10-01-0 1 GLP10-01-0 1 11-16 0

11-16 1 11-15 2 11-16 3 11-16 4 11-16 6 11-15 6 11-15 7 11-15 8 -11-15 9 11-16 0 11-16 1 11-16 2 11-16 3 11-16 4 11-16 5 -11-16 6 11-16 7 -11-16 8 11-16 9 12-00 9 Descriptio n Tri p Blan k

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Se t DA LS S 607 R 1 Sampl e

1 L S 1 M S 1 MH S 1 H S (di l 1:100 ) 2 Sampl e 2L S 2 M S 2 MH S 2 H S (di l 1:100 ) 3 Sampl e 3L S 3 M S 3 MH S 3 H S (di l 1:100 ) 4Sampl e 4L S 4M S 4MH S 4HS(di l 1:100 ) RB004 0 Pre p Dat e Aliquoted : Aliquoted : Aliquoted : Aliquoted : Aliquoted : Aliquoted : Aliquoted : Aliquoted : Aliquoted : Aliquoted : Aliquoted : Aliquoted : Aliquoted : Aliquoted : Aliquoted : Aliquoted : Aliquoted : Aliquoted : Aliquoted : Aliquoted : Aliquoted : 12/30/1 0 CJ G

12/30/1 0 CJ G 12/30/1 0 CJ G 12/30/1 0 CJ G 12/30/1 0 CJ G 12/30/1 0 CJ G 12/30/1 0 CJ G 12/30/1 0 CJ G 12/30/1 0 CJ G 12/30/1 0 CJ G 12/30/1 0 CJ G 12/30/1 0 CJ G 12/30/1 0 CJ G 12/30/1 0 CJ G 12/30/1 0 CJ G 12/30/1 0 CJ G 12/30/1 0 CJ G 12/30/1 0 CJ G 12/30/1 0 CJ G 12/30/1 0 CJ G 12/30/1 0 CJ G toxic

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ETS-8-04 4sampl e pre p 101230.xl s labe l Pag e 5 o f6

# AnalyticalCas eNarrativ e Dat aReductio nCalculation s Contro lChart

- Analytical Uncertainty

# 3 MENVIRONMENTA LLABORATOR Y



# Not et oFil e Projec t o r Stud yNumber : LIM S Number : Affecte dData : GLPlO-01-01-1 1

GLPlO-01-01-1 1

Non e

Al l logboo k

page s fo rth e individua l stoc k standard s an d mixe s use d fo rth e calibratio n curve s an d LC S use d fo rth e analysi s o fGLP10-01-01-1 1 wer e printe d t o pd f(exactcopie s o foriginals ) an d include d i n afolde rlabele d 'Logboo k pages ' locate d i n th e projectfolde rlocate d at : \\Winsnas01a\b2\Projects\Lab_ES AAnalytical\La b Request s 201 0 - stw\GLP10-0 1 Decatu r Phas e 3\GLP10-01-0 1 PFOA\GLP10-01-01-1 1 On-sit e FSI AWell s - Oct\Logboo k page s

Th e chromatogram s fo rresult s fil e b110103 awer e printe d t o pd fan d save d i n th e projectfolde r locate d at : \\Winsnas01a\b2\Projects\Lab_ES AAnalyticalVLa b Request s 201 0 - stw\GLP10-0 1 Decatu r Phas e 3\GLP10-01-0 1 PFOA\GLP10-01-01-1 1 On-sit e FSI AWell s - Oct\b110103 a

Apd fcop yo fth e signe d protoco l amendmen tGLP10-01-0 1 Amendmen t1 1 i s locate d i n th e projectfolde rlocate d at : \\Winsnas01a\b2\Projects\Lab_ES AAnalytical\La b Request s 201 0 - stw\GLP10-0 1 Decatu r Phas e 3\GLP10-01-0 1 PFOA \ GLPlO-01-01-1 1 On-sit e FSI AWell s - Oct

Onc e th e dat apackag e ha s bee n reviewe d byQ Aan d th e reportsigned , th e pd fwil l b e move d t o th e share d driv e (\\Winsnas01a\b2\Projects\Lab_Shared\Archiv e Requests\Electroni cReports ) an d areferenc e t o th e locatio n o fth e pd fwil l b e adde d t o th e archive d reques tfor m unde rEle c Medi aPath

.



# Recorde dBy : Date :

Pag e1 o f 1

## 3 M Confidentia l 

# RECOR D O FDEVIATION/NONCONFORMANC E

/

. Identificatio n Stud y/ Projec tNo

. Date(s ) o fOccurrence : Documen tNumber : GLPlO-01-01-1 1 1-3-1 1 ETS-8-044. 0 Deviatio n typ e IZl SO P D Equipmen tProcedur e D Metho d (Chec k one ) D Protoco l D GP O D Other :



# //

. Descriptio n (attac h extr apages as needed ) Methoc J Requirements :

1

. LC S averag e recoverie s withi n ±20 % (sectio n 10.5)

. 2

. FM S recoverie s withi n ±30 % (sectio n 10.6 )



# Actua l procedure/process :

1

. Th e averag e PFOArecoveryfo rth e 5 pp b EC FLC S wa s 123%

. 2

. Th e hig h FM S recoveryfo rsampl e DA LG W134 R wa s 69.1%

.



# /// , Action s Take n (suc h a s amendmen tissued , SO P revision , etc. ) 

# Correctiv e Actio n ( D Yes 0 No) Reference : Acceptabilit yo fth e nonconformin g work :

1

. Low , mid , an d hig h set s oflinear , an d linea r+ branche d (ECF ) LC S sample s wer e prepare d an d analyze d wit h th e samples

. Al l set s me trhetho d acceptanc e criteri awit h th e exceptio n ofth e mi d leve l EC FLCS

. Th e linea r+ branche d PFOALCS , whe n quantitate d agains tcalibratio n curv e poin tprepare d fro m linea r PFOA , hav e bee n quantitatin g aroun d 5-15 % higher

. Th e recoveryfo rth e 5 pp b EC FLC S (123% ) wil l b e flagge d i n th e fina l report

. Al l LC S wer e use d i n th e determinatio n ofmetho d analytica l uncertainty

. 2

. Th e FM S recoveryfo rth e sampl e outsid e th e acceptanc e criteri awil l b e flagge d i n th e fina l report

. Th e metho d uncertaintyfo rPFO Awil l b e adjuste d according

.



# Actions : D Haltin g o

fWork D Clien tNotificatio n D Work Recal l D Withholdin g o fRepor t 0 Other : Deviation s wil l b e note d i n fina l report

. 

# ProjectLead/PA I Approval : f ) ^ Date: , , stud yDirecto r(i fGLP) : 

# ^"^^kS ^ Datey^/

/

Sponso rApprova l (fo rGL P protoco l deviations) : N ADate : N A Technica l Reviewe r(optional): N ADate : N A

LaboratoryDepartmen tManage rApproval : Date :

IV

. Authorizatio n t o Resum e Wor k Where haltin g o fwor k

occurred , resumptio n o fwor k mus tfirs tb e approve d b yLaboratoryManagemen t 

# Laborator yDepartmen tManage rApproval : « Date : A

Deviatio n No

. (assigned b

yStudyDirecto ro rTeam Leade ratth e en d ofstudyo rproject)



# AttachmentAETS-4-008. 7•Page 1 o f1 Documentatio n o

fDeviation s an d Contro l o fNonconformin g Testin gP:\Projects\Lab_Shared\Contro l Charts\ETS-8-04 4LCM S Direc t

Date 9/27/201 0 9/27/201 0 9/27/201 0 9/27/201 0 9/27/201 0 9/27/201 0 9/27/201 0 9/27/201 0 9/27/201 0 9/27/201 0 9/27/201 0 9/27/201 0 9/27/201 0 9/27/201 0 10/25/201 0 10/25/201 0 10/25/201 0 10/25/201 0 10/25/201 0 10/25/201 0 10/25/201 0 10/25/201 0 10/25/201 0 10/25/201 0 10/25/201 0 10/25/201 0 11/4/201 0 11/4/201 0 11/4/201 0 11/4/201 0 11/4/201 0 11/4/201 0 1/3/201 1 1/3/201 1 1/3/201 1 1/3/201 1 1/3/201 1 1/3/201 1 1/3/201 1 1/4/201 1 1/4/201 1 1/4/201 1 1/4/201 1 1/4/201 1 1/4/201 1 1/4/201 1 1/4/201 1 1/4/201 1 1/4/201 1 1/4/201 1 Analyt e

PFOA PFOA PFOA PFOA PFOA PFOA PFOA PFOA PFOA PFOA PFOA PFOA PFOA PFOA PFOA PFOA PFOA PFOA PFOA PFOA PFOA PFOA PFOA PFOA PFOA PFOA PFOA PFOA PFOA PFOA PFOA PFOA PFOA PFOA PFO A PFOA PFOA PFOA PFOA PFOA PFOA PFOA PFOA PFOA PFOA PFOA PFOA PFOA PFOA PFOA Projec

t E10-053 5 C G E10-053 S C G E10-0S3S C G E10-053SC G E10-0535C G E10-053SC G E10-053SC G E10-0S3S C G E10-0S3SC G E10-0S3SC G E10-0S3S C G E10-0S3S C G E10-0S3S C G E l 0-053 5 C G GLP10-01-01

- GLP10-01-01

- GLP10-01-01

- GLP10-01-01

- GLP10-01-01

- GLPip-01-01

- GLP10-01-01

- GLP10-01-01

- GLP10-01-01

- GLP10-01-01

- GLP10-01-01

- GLP10-01-01

- GLP10-01-01

- GLP10-01-01

- GLP10-01-01

- GLP10-01-01

- GLP10-01-01

- GLP10-01-01

- GLP10-01-01

- GLP10-01-01

- GLP10-01-01

- GLP10-01-01

- GLP10-01-01

- GLP10-01-01

- GLP10-01-01

- GLP10-01-01

- GLP10-01-01

- GLP10-01-01

- GLP10-01-01

- GLP10-01-01

- GLP10-01-01

- GLP10-01-01

- GLP10-01-01

- GLP10-01-01

- GLP10-01-01

- GLP10-01-01

- Stormwate r

Stormwate r Stormwate r Stormwate r Stormwate r Stormwate r stormwate r stormwate r stormwate r stormwate r stormwate r stormwate r stormwate r Stormwate r 0 9 Dec3rd Qt rG W 0 9 Dec3rd Qt rG W 0 9 Dec3rd Qt rG W 0 9 Dec3rd Qt rG W 0 9 Dec3rd Qt rG W 0 9 Dec3rd Qt rG W 0 9 Dec3rd Qt rG W 0 9 Dec3rd Qt rG W 0 9 Dec3rd Qt rG W 0 9 Dec3rd Qt rG W 0 9 Dec3rd Qt rG W 0 9 Dec3rd Qt rG W 0 9 Dec3rd Qt rG W 0 9 Dec3rd Qt rG W 0 9 Dec3rd Qt rG W 0 9 Dec3rd Qt rG W 0 9 Dec3rd Qt rG W 0 9 Dec3rd Qt rG W 1 1 On-Site FSI AWell s 1 1 On-Site FSI AWell s 1 1 On-Site FSI AWell s 1 1 On-Srte FSI AWell s 1 1 On-Site FSI AWell s 1 1 On-Site FSI AWell s 1 1 On-SK e FSI AWell s 1 1 On-Site FSI AWell s 1 1 On-SH e FSI AWell s 1 1 On-Site FSI AWell s 1 1 On-Site FSI AWell s 1 1 On-Site FSI AWell s 1 1 On-Site FSI AWell s 1 1 On-Site FSI AWell s 1 1 On-Site FSI AWell s 1 1 On-Site FSI AWell s 1 1 On-Site FSI AWell s 1 1 On-Site FSI AWell s Injec t Pre p Analyst kj e kj e kj e kj e kj e kj e kj e kj e kj e kj e kj e kj e kj e kj e st w st w st w st w st w st w st w st w st w st w st w stw cj g cj g cj g cj g cj g cj g cj g cj g cj g cj g cj g cj g cj g cj g cj g cj g cj g cj g cj g cj g cj g cj g cj g cj g LC/M S Analyst

kj e kj e kj e kj e kj e kj e kj e kj e kj e kj e kj e kj e kj e kj e st w stw st w st w st w stw stw stw stw st w stw stw cj g cj g cj g cj g cj g cj g cj g cj g cj g cj g cj g cj g cj g cj g cj g cj g cj g cj g cj g cj g cj g cj g cj g cj g Instrument

Buste r Buste r Buste r Buste r Buste r Buste r Buste r Buste r Buste r Buste r Buste r Buste r Buste r Buste r Ginge r Ginge r Ginge r Ginge r Ginge r Ginge r Ginge r Ginge r Ginge r Ginge r Ginge r Ginge r Buste r Buste r Buste r Buste r Buste r Buste r Buste r Buste r Buste r Buste r Buste r Buste r Buste r Buste r Buste r Buste r Buste r Buste r Buste r Buste r Buste r Buste r Buste r Buste r tSampl e I D

LCS-100927- 5 LCS-100927- 6 LCS-100927-1 3 LCS-100927-1 4 LCS-100927-1 5 LCS-100927- 7EC F LCS-100927- 8 EC F LCS-100927- 9 EC F LCS-100927-1 0 EC F LCS-100927-1 1 EC F LCS-100927-1 2 EC F LCS-100927-1 6 EC F LCS-100927-1 7EC F LCS-100927-1 8 EC F LCS-101020- 1 LCS-101020- 2 LCS-101020- 3 LCS-101020- 4 LCS-101020- 5 LCS-101020- 6 LCS-101020- 7EC F LCS-101020- 8 EC F LCS-101020- 9 EC F LCS-101020-1 0 EC F LCS-101020-1 1 EC F LCS-101020-12EC F LCS-101104-0 1 LCS-101104-0 2 LCS-101104-0 3 LCS-101104-04EC F LCS-101104-05EC F LCS-101104-0 6 EC F LCS-101230- 1 LCS-101230- 2 LCS-101230- 3 LCS-101230- 4 LCS-101230- 5 LCS-101230- 8 LCS-101230- 7 LCS-101230- 8 LCS-101230- 9 LCS-101230-1 0 LCS-101230-1 1 LCS-101230-1 2 LCS-101230-1 3 LCS-101230-1 4 LCS-101230-1 5 LCS-101230-1 6 LCS-101230-1 7 LCS-101230-1 8 Tru e Value , ng/m LRecovere d valu e ng/m L% 1.9800 1.9800 19.900 0 19.900 0 19.900 0 0.198 0 0.198 0 0.198 0 1.9900 1.9900 1.9900 19.800 0 19.800 0 19.800 0 2.000 0 2.000 0 2.000 0 20.000 0 20.000 0 20.000 0 2.000 0 2.000 0 2.000 0 20.000 0 20.000 0 20.000 0 2S.0000 25.000 0 25.000 0 25.000 0 25.000 0 25.000 0 0.4970 0.497 0 0.497 0 4.970 0 4.970 0 4.970 0 30.000 0 30.000 0 30.000 0 0.498 0 0.498 0 0.498 0 5.000 0 5.000 0 S.OOO O 30.000 0 30.000 0 30.000 0

Averag e 1.8 2 1.7 1 16. 8 17. 8 18. 8 0.19 3 0.21 1 0.19 2 1.9 1 1.9 6 1.9 4 19. 0 18. 2 19. 9 2.1 3 2.0 3 2.1 S 18. 8 19. 5 19. 9 2.3 3 2.5 4 2.3 5 23. 9 23. 9 22. 3 25. 7 25. 8 2 6 27. 2 27. 2 26. 9 0.S 8 0.SS 7 0.5 9 5.8 3 S.6 9 5.6 S 25. 6 25. 8 25. 7 0.54 6 0.55 3 0.54 1 6.2 9 6.0 3 6.1 2 31. 3 30. 8 30. 6

Standar d Deviatio n St d De v* 2 Recover yComment s 92. 0 86. 6 84. 7 89. 3 94. 7 97. 6 106 97. 2 95. 8 98. 7 97. 4 96. 1 91. 8 10 1 107 102 108 93. 9 97. 6 99. 5 11 7 12 7 11 8 11 9 11 9 11 2 10 3 103 104 109 10 9 10 8 11 7 11 2 11 9 11 7 11 5 11 4 85. 3 86. 0 85. 6 11 0 11 1 10 9 12 6 12 1 12 2 104 103 10 2

10 5 11. 3 22. 6

Metiio d Uncertaint yGLP10-01-01-11.xl s PFO A Pag e 1 o f1 

# CD S hlS'l l

## 3 M Confidentia l 3 M Environmenta l Laboratory Project : GLPlO-01-01-1 1 Sequenc e b110103 a 3 M Environmenta l Laboratory 3 M Technica l Lead : Susa n Wol f Buildin g 260-5N-1 7 651-733-985 1 Repor tAutho rCheisi e Grochow Analytica l Team : Susa n Wol f



# Analytica l Cas e Narrativ e fo rMetho d ETS-8-44. 0

Projec tGLP10-01-01-1 1

Decatu rPhas e 3 - O n sit e FSI AGroundwate r- Octobe r201 0

Direc tinjectio n analysi s o

fsamples Sequenc e b110103a ReportDate : January14 , 2011

Instrumentsummar

yan d calibratio n curves wil l be printed an d included i n th e ra wdatapackage

. Chromatogram s wil l be printed to pdf

.

ETS 8-04 4 Analytica l SummaryChecklis tPag e 1 o f3

## 3 M Confidentia l



# 1 Projec tScop e an d Dat aQualit yObjectiv e 3 M Environmenta l Laborator y Project : GLPlO-01-01-1 1 Sequenc e b110103 a

Genera l ProjectOutlin e available

.

GL P ^Ye s

E l Ye s D N o

D N o I fNo , Pleas e briefl ydescrib e

projectscop e an d DQ O



# 2 Sampl e Containe rPreparatio n

Sampl e containe rpreparatio n documente d i n aNot e t o Fil e include d i n th e rawdat apackage

. 

# 3 Sampl e Analysi s

3. 1 Syste m Suitabilit y

Initia l Syste m Suitabilityare acount s wit h RS D <5 % an d retentio n tim e wit h RS D <2 % 

# 1 3 Ye s D N O



# 3.1. 1 Syste m Suitabilit yDeviation s

NA

. 

# 3. 2 Instrumen tCalibratio n Curv e typ e r^>0.99 0 Linearitycriteri ame t(ETS-8-4 4sectio n 12.2 )

< ±25 % residuals , excep tLO Q o f±30 % (ETS-8-4 4sectio n 12.2 ) Mid-leve l calibratio n point s disable d Quadratic , 1/ x jgjYe s 1 3 Ye s DYe s D N O

D N O 

## KJN o

Th e tw o highes tcalibratio n standard s wer e deactivate d t o mee taccuracycriteria

. 

# 3. 3 Continuin g Calibratio n Verificatio n

+25 % Differenc e criteri ame tfo rperiodi cCCV s (ETS-8-4 4sectio n 12.2 ) ^Ye s D N O 

# 3.3. 1 Continuin g Calibratio n Verificatio n Deviation s NA

. 

# 3. 4Metho d Blank s

Metho d blanks uniquel yidentifie d i n th e ru n sequence

. Averag e are acount s o ftarge tanalyte s i n th e metho d blan k presen tat> V i x th e are acount s ofth e LO Q standar d ( b 1S-8-44Sectio n 10.2 ) 1 3 Ye s

SYe s D N o

D N O



# 3.4. 1 Metho d Blan k

Deviation s NA

.

ET S 8-04 4Analytica l Summar yChecklis t Pag e 2 o f3

## 3 M Confidentia l



# 3. 5 La b Contro l Spike s 3 M Environmenta l Laborator y Project : GLPlO-01-01-1 1 Sequenc e b110103 a

±20 % recoverycriteri ame t(ET S 8-4 4Sectio n 10.5 ) <20 % RS D precisio n (ET S 8-4 4Sectio n 10.5 ) DYe s E l Ye s 1 3 N o

D N O 

# 3.5. 1 La b Contro l Spik e Deviation s Th e EC FPFOArecoveryofth e 5 pp b LC S ha d a n averag e recoveryo f123%

. 

# 3. 6 Sampl e Replicate s

RP D fo rfiel d duplicate s <20 % (ETS-8-4 4Sectio n 10.5 ) E l Ye s D N O 

# 3.6. 1 Sampl e Replicate s Deviation s N A



# 3. 7Fiel d Matri xSpike s

±30 % recoverycriteri amet

. (ET S 8-4 4Sectio n 10.5 ) DYe s E l N O 

# 3.7. 1 Fiel d Matri xSpik e Deviation s 134R ; Th e hig h FM S recoverywa s 69.1% , N o appropriat e spik e leve l fo r131R , an d 135R

. 

# 3. 8 Limi to fQuantitatio n (LOQ )

Al l LOQ s equa l th e low-leve l calibratio n standar d concentratio n wit h are acount s atleas ttwic e tha to fth e metho d blank(s ) (ET S 8

- 4 4Sectio n 10.2 ) E l Ye s D N o



# 3. 9 Manua l Integration s

Manua l integratio n reviewe d byanothe ranalyst/tea m lead : Reviewe d by: ^

Date:_ L|g \ I I E l Ye s D N O



# 4Additiona l analytica l note s

Sample s 132 LM S an d H S an d al l 134 Lsample s wer e re-injecte d withi n th e analytica l batc h ru n atahighe r dilutio n facto rsinc e th e firs tinjection s wer e abov e th e ULOQ

. Sampl e 141 R an d th e correspondin g duplicat e an d LowSpik e wer e re-injecte d atalowe rdilutio n facto rsinc e th e firs tinjection s o fth e sampl e an d sampl e duplicat e wer e nea rth e LLOQ

. Onl yth e re-injecte d sampl e result s wil l b e reported

. Al l othe rdat awil l b e reporte d fro m thi s run

. 

# 5 Signature s



# aiAlhUL'^/lAV-hATU

j t'l^'l l Analys t Dat e

ET S 8-04 4Analytica l Summar yChecklis t Pag e 3 o f3

# Buster : API4000 : J293020 3 pag e1/ 1

DAT E01/03/1 1

ANALYST : CJG

STUDYNUMBER : GLPlO-01-01-1 1 Matrix : water Injectionvolume : 1 0u

LElectrode : turb oionspra y

LC/MS/M S method : PFOAonly

Mobil ePhase : (A) 2m Mammoniumacetate(B ) Methanol

TN-A

- or standardnumbe

r (A) 1 0010-6 1 (B ) TNlO-0448-2/8

Guar d(pre-autosampler ) columnPrismRP

Size : 2. 1 m

mX5 0m mType : C1 2Spher esize : 5

Par t number : 32105-05213 0Lot number : 941 1 Seria

lnumbe r 0903541 VStarted10-29-1 0

Analyticalcolumnbetasil€1 8

Size : 2. 1 m

mX10 0m mType : €1 8 Spher esize : 5

Par t number : 70105-10213 0Lot number : 1068 3 Seria

lnumbe r 1000992TStarted10-29-1 0

DataFile : b l10103 a 

# S^mpl ^bnOiO^bSX HH(X ^hM-elx / injec-^e dbu- f

fiv e da+ A•fi\ ^fT>

r -l-hj s '^aYTip) ccoul dnc^i

- b ereiiovere d diucii D acompute r

ennDr

. cj ai-ii- w A\SO , +ti e[ac.'i--h^ o CJLM S 

# vvTtr ^\f\a.d^^^-fer\-^y ^injecfe d (X ^5ju Linst-«<^clt- ^/D|aL

. Th eaiiutio nfacto r \NaSi

Printed : Monday , Januar

y03 , 201 1 10:2 1 AM 

# c j eI'll-I I*Buste r J233020 3

PtDJect : P:\PrajectsiLab_lnstmmen tDataVBustertBuste rData\Projects\fluor D Sampl e

1 

## 2 1 3 4 5 6 7 8 9 1 0 1 1 1 2 1 3 1 4 1 5 1 6 1 7 1 8 1 9 2 0 2 1 2 2 2 3 2 4 2 5 2 6 2 7 2 8 2 9 3 0 3 1 3 2 3 3 3 4 3 5 3 6 3 7 3 8 3 9 4 0 4 1 4 2 4 3 4 4 4 5 4 6 4 7 4 8 4 9 5 0 5 1 5 2 5 3 5 4 5 5 5 6 Sampl e Nam e

b110103a00 1 bl10103300 2 bl10103800 3 bl10103300 4 bl10103300 5 bl10103300 6 bl10103300 7 bl10103300 8 bl10103300 9 bl10103301 0 b110103301 1 bl10103301 2 bl10103301 3 bl10103301 4 bl10103301 5 bl10103301 6 bl10103301 7 bl10103301 8 bl10103301 9 bl10103302 0 bl10103302 1 bl10103302 2 bl10103302 3 b l 10103302 4 bl10103302 5 bl10103302 6 bl10103302 7 bl10103302 8 bl10103302 9 b110103303 0 bl10103303 1 bl10103303 2 bl10103303 3 bl10103303 4 bl10103303 5 bl10103303 6 bl10103303 7 bl10103303 8 bl10103303 9 bl10103304 0 bl10103304 1 b110103a04 2 bl10103304 3 bl10103304 4 bl10103304 5 b110103a04 6 bl10103304 7 bl10103304 8 bl10103804 9 bl10103305 0 bl10103805 1 bl10103305 2 bl10103305 3 bl10103305 4 bl10103305 5 bl10103305 6 Sampl e I D

Solven tBlan k

(MIIII Q Bement ) Solven tBIsn k

(MIIII Q Bement ) Solven tBlan k

(Mlli Q Bement ) Solven tBten k

(Mlli Q Bement ) Solven tBIsn k

(Mlli Q Bement ) Solven tBl3n k

(Mlli Q Bement ) 08008-194-1 1 syste m sui t 08008-194-1 1 syste m sui t 08008-194-1 1 syste m sui t 08008-194-1 1 syste m sui t Solven tBl3n k

(Mlli Q Bement ) Solven tBl3n k

(Mlli Q Benrent ) 08008-194- 1 08008-194- 2 08008-194- 3 08008-194- 4 08008-194- 5 08008-194- 6 08008-194- 7 08008-194- 8 08008-194- 9 08008-194-1 0 08008-194-1 1 08008-194-1 2 08008-194-1 3 08008-194-1 4 08008-194-1 5 Solven tBl3n k

(Mlli Q Bement ) Solven tBlan k

(Mlli Q Bement ) Solven tBl3n k

(Mlli Q Bement ) 08008-194-1 0 Solven tBlan k

(Mlli Q Bement ) LCS-101230- 1 LCS-101230- 2 LCS-101230- 3 LCS-101230- 4 LCS-101230- 5 LCS-101230- 6 LCS-101230- 7 LCS-101230- 8 LCS-101230- 9 Solven tBlan k

(Mlli Q Bement ) Solven tBl3n k

(Mlli Q Bement ) 08008-194- 9 Solven tBl3n k

(Mlli Q Bement ) LCS-101230-1 0 LCS-101230-1 1 LCS-101230-1 2 LCS-101230-1 3 LCS-101230-1 4 LCS-101230-1 5 LCS-101230-1 6 LCS-101230-1 7 LCS-101230-1 8 Solven tBIsn k

(Mlli Q Bement ) Solven tBIsn k

(Mlli Q Bement ) Via l Positio n

9 1 9 1 9 1 9 1 9 1 9 1 1 1 1 1 1 1 1 1 9 1 9 1 1 2 3 4 5 6 7 8 9 1 0 1 1 1 2 1 3 1 4 1 5 9 1 9 2 9 2 1 0 9 2 1 6 1 7 1 8 1 9 2 0 2 1 2 2 2 3 2 4 9 2 9 3 9 9 3 2 5 2 6 2 7 2 8 2 9 3 0 3 1 3 2 3 3 9 3 9 4 nchemicals\wate rBatch:b110103 a

Dat aFil e b l 10103 3 b l 10103 3 b l 10103 3 b l 10103 3 b l 10103 3 b l 10103 3 b l 10103 3 b l 10103 3 b l 10103 3 b l 10103 3 b l 10103 3 b l 10103 8 b l 10103 3 b l 10103 3 b l 10103 3 b110103 3 b l 10103 3 b110103 3 b l 10103 3 b l 10103 3 b l 10103 3 b l 10103 a b l 10103 3 b l 10103 a b l 10103 a b l 10103 8 b l 10103 3 b l 10103 3 b l 10103 3 b l 10103 3 b l 10103 3 b l 10103 3 b l 10103 3 b l 10103 3 b l 10103 3 b110103 3 bl10103 8 b110103 8 b110103 3 b110103 3 b110103 8 bl10103 3 bl10103 3 bl10103 3 bl10103 3 bl10103 3 bl10103 3 bl10103 8 bl10103 8 bl10103 8 bl10103 3 bl10103 8 bl10103 3 bl10103 8 bl10103 3 bl10103 8 Inj.Volum e (pi )

10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 Tab:Sampl e Set:SET 1 AcqMethod:PFO A

Comment s MlliQ\/\fete rTN I 0-047 5 Mil l Q\Afete rTN I 0-047 5 Mil l QW^te rTN I 0-047 5 Mil l QV\feite rTN I 0-047 5 MlliQVifeite rTN I 0-047 5 Mil l QVVfeite rTN I 0-047 5 1 0 ng/mLFC st d i n Mil l Q \Afate r 1 0 ng/mLFC st d i n Mil l Q Wate r 1 0 ng/mLFCsl d i n Mil l Q Wate r 1 0 ng/mLF C st d i n Mll i Q W^te r Mlli Q Wate rTN I 0-047 5 Mlli Q Wate rTN I 0-047 5 0.02 5 ng/m LF C st d i n Mll i Q V\feite r 0.0 3 ng/m LF C st d i n Mil l Q V\fate r 0.0 4ng/m LF C st d i n Mil l 0 V\fate r 0.0 5 ng/m LF C st d i n Mll i Q V\fate r 0. 1 ng/mLFC st d i n Mll i 0 W^te r 0.2 5 ng/m LF C st d I n Mll i Q V\fate r 0. 5 nglrr tFC st d I n Mll i Q V\fete r 1. 0 ng/mLF C st d i n Mll i Q\Afete r 2. 5 ng/mLFC st d i n Mll i Q \rtfete r 5. 0 ng/mLFC st d i n Mll i Q Wate r 1 0 ng/m LF C st d i n Mll i Q W^te r 2 5 ng/mLF C st d i n Mll i Q Waite r 5 0 ng/mLF C st d i n Mll i Q Wfeite r 7 5 ng/mLF C st d i n Mi n Q Wate r 10 0 ng/m LF C st d i n Mll i Q Wfeite r Mll i QWfeite rTN I 0-047 5 Mll i QW&te rTN I 0-047 5 Mll i QW&te rTN I 0-047 5 5. 0 ng/m LF C st d i n Mll i Q Wate r Mll i QW^te rTN I 0-047 5 O.Spp b LC S 0.5pp b LC S 0.5pp b LC S 5pp b LC S Spp b LC S Spp b LC S 30pp b LC S 30pp b LC S 30pp b LC S Mlli Q Wate rTN I 0-047 5 Mll i QWfeite rTN I 0-047 5 2. 5 ng/mLF C st d i n Mi n Q Wfeite r Mi n Q Wate rTN I 0-047 5 O.Spp b LC S EC F O.Spp b LC S EC F O.Spp b LC S EC F Spp b LC S EC F Spp b LC S EC F Spp b LC S EC F 30pp b LC S EC F 30pp b LC S EC F 30pp b LC S EC F Mi n QW^te rTN I 0-047 5 Mi n Q Wate rTN I 0-047 5 only.da m

Printin g Time : 10:22:5 9 A M Printin g Date : Monday , Januar y03 , 201 1 Pag e 1 o f 6 

# (oroi-ii-i i*Buste r J293020 3

PtDJect : P:\Projectsi\Lab_lnstrumen tData\BustertBusterData\Projects\fluororchemicals\waterBatch;b110103 a Sampl e

5 7 5 8 5 9 6 0 6 1 6 2 6 3 6 4 6 5 6 6 6 7 6 8 6 9 7 0 7 1 7 2 ; 7 3 7 4 7 5 7 6 7 7 7 8 7 9 8 0 8 1 8 2 8 3 8 4 8 5 8 6 8 7 8 8 • 8 9 9 0 9 1 9 2 9 3 9 4 9 5 9 6 9 7 9 8 9 9 10 0 10 1 10 2 10 3 10 4 10 5 10 6 10 7 10 8 10 9 11 0 11 1 11 2 Sampl e Nam e bl10103805 7 b l 10103805 8 bl10103805 9 bl10103806 0 b l 10103806 1 bl10103306 2 bl10103806 3 bl10103306 4 bl10103306 5 b110103306 6 bl10103306 7 bl10103306 8 bl10103806 9 bl10103807 0 bl10103807 1 bl10103807 2 b110103a07 3 b l 10103807 4 b l 10103307 5 b l 10103307 6 b l 10103307 7 bl10103307 8 bl10103307 9 bl10103308 0 b l 10103308 1 bl10103308 2 bl10103308 3 bl10103308 4 bl10103308 5 bl10103308 6 bl10103308 7 bl10103308 8 bl10103308 9 bl10103309 0 bl10103309 1 bl10103309 2 bl10103309 3 bl10103809 4 bl10103809 5 b110103a09 6 b110103a09 7 bl10103809 8 bl10103309 9 bl10103810 0 b1101038l0 1 bl10103810 2 b1101033l0 3 b1101038lO 4 b1101038lO S b1101038l0 6 b1101038l0 7 bl10103810 8 bl10103310 9 b1101038l1 0 b1101033l1 1 b1101033l1 2 Sampl e I D

08008-194-1 1 Solven tBIsn k

(Mlli Q Bement ) GLPlO-01-01-11-15 0 GLPlO-01-01-11-15 1 GLPlO-01-01-11-15 2 GLPlO-01-01-11-15 3 GLP l 0-01-01-11-15 4 GLP l 0-01-01-11-15 5 GLP l 0-01-01-11-15 6 GLPlO-01-01-11-15 7 GLP l 0-01-01-11-15 8 GLP l 0-01-01-11-15 9 Solven tBlan k

(MHi O Bement ) Solven tBIsn k

(MUi O Bement ) 08008-194-1 0 Solven tBlan k

(MNI Q Bement ) GLPlO-01-01-11-16 0 GLPlO-01-01-11-16 1 GLPlO-01-01-11-16 2 GLPlO-01-01-11-16 3 GLPlO-01-01-11-16 4 GLPlO-01-01-11-16 5 GLPlO-01-01-11-16 6 GLP l 0-01-01-11-16 7 GLPlO-01-01-11-16 8 GLPlO-01-01-11-16 9 Solven tBIsn k

(Mlli Q Bement ) Solven tBIsn k

(Mlli Q Bement ) 08008-194- 9 Solven tBIsn k

(Mlli Q Bement ) GLP l 0-01-01-12-00 9 GLPlO-01-01-11-01 6 GLPlO-01-01-11-14 9 GLPlO-01-01-11-06 S GLPlO-01-01-11-06 6 GLPlO-01-01-11-06 7 GLPlO-01-01-11-06 8 GLPlO-01-01-11-06 9 Solven tBlan k

(Mlli Q Bement ) Solven tBIsn k

(Mlli Q Bement ) 08008-194- 8 Solven tBIsn k

(MHI Q Bement ) GLPlO-01-01-11-07 9 GLPlO-01-01-11-08 0 GLPlO-01-01-11-08 1 GLPlO-01-01-11-08 2 GLPlO-01-01-11-08 3 GLPlO-01-01-11-09 9 GLPlO-01-01-11-10 0 GLPlO-01-01-11-10 1 GLPlO-01-01-11-10 2 GLPlO-01-01-11-10 3 Solven tBIsn k

(MUi Q Bement ) Solven tBlan k

(Mlli Q Bement ) 08008-194-1 1 Solven tBIsn k

(Mni Q Bement ) Via l Positio n

1 1 9 4 3 4 3 5 3 6 3 7 3 8 3 9 4 0 4 1 4 2 4 3 9 4 9 5 1 0 9 5 4 4 4 5 4 6 4 7 4 8 4 9 S O 5 1 5 2 S3 9 5 9 6 9 9 6 5 4 5 5 5 6 5 7 5 8 5 9 6 0 6 1 9 6 9 7 8 9 7 6 2 6 3 6 4 6 5 6 6 6 7 6 8 6 9 7 0 7 1 9 7 9 8 1 1 9 8 Dat aFil e

b l 10103 3 b l 10103 a bl10103 3 bl10103 3 bl10103 a bl10103 a b l 10103 a bl10103 3 b l 10103 3 b l 10103 3 b l 10103 8 b l 10103 3 bl10103 8 bl10103 a bl10103 8 bl10103 a bl10103 a bl10103 8 bl10103 a b110103 3 b110103 s bl10103 8 b110103 3 b110103 3 b110103 8 b110103 3 b110103 8 bl10103 a bl10103 3 bl10103 3 bl10103 8 bl10103 3 bl10103 3 bl10103 3 bl10103 3 bl10103 3 bl10103 3 bl10103 3 bl10103 3 bl10103 3 bl10103 3 bl10103 3 bl10103 a bl10103 3 bl10103 3 bl10103 3 bl10103 8 bl10103 3 bl10103 3 bl10103 3 bl10103 3 bl10103 3 bl10103 8 bl10103 a b110103 8 bl10103 a Inj.Volum e (pi )

10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 2.00 0 10.00 0 10.00 0 10.00 0 10.00 0 2.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 2.00 0 10.00 0 10.00 0 10.00 0 10.00 0 2.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 2.00 0 2.00 0 2.00 0 2.00 0 2.00 0 10.00 0 10.00 0 10.00 0 10.00 0 2.00 0 2.00 0 2.00 0 2.00 0 2.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 Tab:Sampl e SetiSET I AcqMethod:PFO Aonly.da m

Comment s 1 0 ng/m LF C st d i n Mll i Q Wfeite r MinQV\faterTN10-047 S Tri p BIsn k

Se t1 Ssmpl e Tri p BIsn k

Se t1 L S Tri p BIsn k

Se t1 M S Tri p Blan k

Se t1 MH S Tri p BIsn k

Se t1 H S (di l 1:100 ) Tri p BIsn k

Se t2 Ssmpl e Tri p BIsn k

Se t2 L S Tri p BIsn k

Se t2 M S Tri p BIsn k

Se t2 MH S Tri p BIsn k

Se t2 H S (di l 1:100 ) Mlli Q Wate rTN10-047 5 Mi n QW3te rTN I 0-047 5 5. 0 ng/n l F C st d i n Mll i Q Wate r Mi n Q Wate rTN I 0-047 5 Tri p BIsn k

Se t3 Ssmpl e Tri p BIsn k

Se t3 L S Tri p BIsn k

Se t3 M S Tri p BIsn k

Se t3 MH S Tri p Blan k

Se t3 HS(d n 1:100 ) Tri p Blan k

Se t4Sampl e TripBl3nkSet4L S Tri p BIsn k

Se t4M S Tri p Blan k

Se t4MH S Tri p BlankSet4H S (di l 1:100 ) MUi Q wate rTN I 0-047 5 Mi n QV\fete rTN I 0-047 5 2. 5 ng/mLFC st d i n Mll i 0 Wate r Mi n QV\fate rTN I 0-047 5 DA LS S 607 R R B 004 0 DA LGW130LR B 10110 5 DA LGW144RR B 10111 0 DA LGW134S 0 10110 5 DALGW134SDB10110 S DA LGW134SL S 10110 5 DALGW134SMS10110 5 DA LGW134SH S 10110 5 Mi n QW^te rTN I 0-047 5 Mi n Q Wate rTN I 0-047 5 1. 0 ng/mLFC st d i n Mi n 0 V\fete r Mi n QV\fate rTN I 0-047 5 DA LGW13S S 0 10110 5 DA LGW135SD B 10110 5 DA LGW13SSL S 10110 5 DA LGW135 S M S 10110 5 DA LGW135SH S 10110 5 DA LGW137 S 010110 9 DA LGW137SD B 10110 9 DA LGW137SL S 10110 9 DA LGW137 S M S 10110 9 DA LGW137SI-I S 10110 9 Mi n Q Wate rTN I 0-047 5 Mi n Q Wate rTN I 0-047 5 1 0 ng/mLF C st d i n Mll i Q Wate r Mi n QWSte rTN I 0-047 5

Printin g Time ; Printin g Date : 10:22:5 9 AM

Monday , Januar y03 , 201 1 Pag e 2 o f 6•Buste r J293020 3

Project : P:\Projects\Lab_lnstmmen tData\Buster\Buste rData\Projects\fluororchemicalSwat e Sampl e

11 3 11 4 11 5 11 6 11 7 11 8 11 9 12 0 12 1 12 2 12 3 12 4 12 5 12 6 12 7 12 8 12 9 13 0 13 1 13 2 13 3 13 4 13 5 13 6 13 7 13 8 13 9 14 0 14 1 14 2 14 3 14 4 14 5 14 6 14 7 14 8 14 9 IS O 15 1 15 2 15 3 15 4 1SS 15 6 15 7 15 8 15 9 16 0 16 1 16 2 16 3 16 4 16 5 16 6 16 7 16 8 Sampl e Nam e b110103a11 3 bl10103811 4 b l 101038 1 I S b l 10103811 6 b110103a11 7 b1101038l1 8 b1101038l1 9 bllOl03812 0 bllOl03812 1 b l 10103812 2 b l 10103812 3 b l 10103812 4 b1101033l2 5 bl10103812 6 b l 10103312 7 b l 10103312 8 b l 10103312 9 b l 10103813 0 b l 10103813 1 b110103a13 2 b l 10103813 3 bl10103313 4 bl10103813 5 bl10103313 6 bl10103313 7 bl10103313 8 bl10103313 9 bl10103314 0 bl10103314 1 b110103a14 2 bl10103314 3 bl10103314 4 b110103a14 5 bl10103314 6 bl10103314 7 bl10103314 8 bl10103314 9 b1101033lS 0 b1101033l5 1 bl10103815 2 bl10103315 3 bllOl03315 4 bl1010381S S b1101033l5 6 bl10103315 7 bl10103315 8 bl10103315 9 bl10103316 0 bl10103316 1 bl10103316 2 bl10103816 3 bl10103316 4 bl10103316 5 bl10103816 6 b110103a16 7 b1101033l6 8 Sampl e I D

GLP l 0-01-01-11-10 4 GLPlO-01-01-11-10 5 GLPlO-01-01-11-10 6 GLPlO-01-01-11-10 7 GLPlO-01-01-11-10 8 GLPlO-01-01-11-11 4 GLPlO-01-01-11-11 5 GLPlO-01-01-11-11 6 GLPlO-01-01-11-11 7 GLPlO-01-01-11-11 8 Solven tBlan k

(Mlli Q Bement ) Solven tBlan k

(Mlli Q Bement ) 08008-194-1 0 Solven tBlan k

(Mlli Q Element ) GLPlO-01-01-11-01 1 GLPlO-01-01-11-01 2 GLPlO-01-01-11-01 3 GLPlO-01-01-11-01 4 GLPlO-01-01-11-01 5 GLPlO-01-01-11-02 1 GLPlO-01-01-11-02 2 GLPlO-01-01-11-02 3 GLPlO-01-01-11-02 4 GLPlO-01-01-11-02 5 Solven tBlan k

(Mlli Q Bement ) Solven tBIsn k

(Mlli Q Bement ) 08008-194- 9 Solven tBIsn k

(Mlli Q Bement ) GLPlO-01-01-11-02 6 GLPlO-01-01-11-02 7 GLPlO-01-01-11-02 8 GLPlO-01-01-11-02 9 GLPlO-01-01-11-03 0 GLPlO-01-01-11-04 1 GLPlO-01-01-11-04 2 GLPlO-01-01-11-04 3 GLPlO-01-01-11-04 4 GLPlO-01-01-11-04 5 Solven tBIsn k

(Mlli Q Bement ) Solven tBlan k

(MUi Q Bement ) 08008-194-1 2 Solven tBlan k

(Mlli Q Bement ) GLPlO-01-01-11-04 6 GLPlO-01-01-11-04 7 GLPlO-01-01-11-04 8 GLPlO-01-01-11-04 9 GLPlO-01-01-11-05 0 GLPlO-01-01-11-0S 1 GLPlO-01-01-11-05 2 GLPlO-01-01-11-0S 3 GLPlO-01-01-11-05 4 GLPlO-01-01-11-05 5 Solven tBIsn k

(Mlli Q Bement ) Solven tBlan k

(Mlli Q Bement ) 08008-194-1 1 Solven tBlan k

(Mlli Q Bement ) Via l Positio n

7 2 7 3 7 4 7 5 7 6 7 7 7 8 7 9 8 0 8 1 9 8 9 9 1 0 9 9 8 2 8 3 8 4 8 5 8 6 8 7 8 8 8 9 9 0 3 4 9 9 10 0 9 10 0 3 5 3 6 3 7 3 8 3 9 4 0 4 1 4 2 4 3 4 4 10 0 9 1 1 2 9 1 4 5 4 6 4 7 4 8 4 9 5 0 5 1 5 2 5 3 5 4 9 1 9 2 1 1 9 2 Dat aFil e

b110103 3 b110103 8 b110103 8 b110103 8 b110103 s b110103 3 b l 10103 8 bl10103 3 bl10103 8 bl10103 8 bl10103 8 b l 10103 8 b l 10103 a b l 10103 3 b l 10103 3 b l 10103 s b l 10103 3 b l 10103 3 b l 10103 3 b l 10103 3 b l 10103 8 b l 10103 a b l 10103 8 b l 10103 a b l 10103 8 b l 10103 8 b l 10103 a b l 10103 8 b l 10103 8 b l 10103 a b l 10103 8 b l 10103 3 b l 10103 3 b l 10103 s b l 10103 3 b l 10103 3 b l 10103 3 b l 10103 3 b110103 3 b l 10103 3 b l 10103 3 b l 10103 8 b110103 a b110103 8 b110103 8 b l 10103 a b l 10103 8 b l 10103 3 b l 10103 8 b l 10103 a bl10103 3 b l 10103 8 b l 10103 3 b l 10103 s b l 10103 s b l 10103 3 rBatch:b110103 a

Inj.Volum e (pi ) 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 2.00 0 2.00 0 2.00 0 2.00 0 2.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 2.00 0 2.00 0 2.00 0 2.00 0 2.00 0 10.00 0 10.00 0 10.00 0 10.00 0 Tab:Sampl e Set:SET 1 AcqMethod:PFO Aonly.da m

Comment s DA LGW137 L010110 9 DA LGW137LD B 10110 9 DA LGW137LL S 10110 9 DALGW137LMS10110 9 DA LGW137LI-I S 10110 9 DA LGW138 L0 10111 0 DA LGW138LD B 10111 0 DA LGW138LL S 10111 0 DALGW138LMS10111 0 DALGW138LHS10111 0 Mi n Q Wate rTN I 0-047 5 Mi n Q Wate rTN I 0-047 5 5. 0 ng/mLF C st d i n MU i Q \Afate r MUI Q Wate rTN I 0-047 5 DA LGW130L 0 10110 5 (d U 1:10 ) DA LGW130LD B 10110 5 (d U 1:10 ) DA LGW130LL S 10110 5 (d U 1:10 ) DA LGW130 LM S 10110 5 (di l 1:10 ) DA LGW130 LH S 10110 5 (d H 1:10 ) DA LGW131 S 0 10110 3 (di l 1:10 ) DA LGW131 S D B 10110 3 (di l 1:10 ) DA LG W131 S L S 10110 3 (d H 1:10 ) DA LG W131 S H S 10110 3 (d U 1:10 ) DALGW131SMS101103(dni:10 ) MUi Q Wate rTN I 0-047 5 MUi Q Wate rTN I 0-047 5 2. 5 ng/mLF C st d i n MU i Q W^te r MU i QV\feite rTN I 0-047 5 DA LG W131 L0 10110 3 (di l 1:10 ) DA LGW131 LD B 10110 3 (di l 1:10 ) DA LGW131LL S 10110 3 (di l 1:10 ) DA LGW131 LM S 10110 3 (d U 1:10 ) DA LGW131 LH S 10110 3 (di l 1:10 ) DA LGW132L 0 10110 3 (d U 1:10 ) DA LGW132LD B 10110 3 (d U 1:10 ) DA LGW132LL S 10110 3 (d U 1:10 ) DA LGW132 LM S 10110 3 (d U 1:10 ) DA LGW132LH S 10110 3 (d H 1:10 ) MUi Q Wate rTN I 0-047 5 MinQV\feterTN10-047 S 2 5 ng/mLF C st d i n MU i Q W^te r MUI Q wate rTN I 0-047 5 DA LGW133R 0 10110 2 (d U 1:10 ) DA LGW133RD B 10110 2 (d U 1:10 ) DA LGW133RL S 10110 2 (di l 1:10 ) DALGW133RMS101102(dU1:10 ) DA LGW133RH S 10110 2 (d U 1:10 ) DA LG W133 S 0 10110 3 (di l 1:10 ) DA LG W133 S D B 10110 3 (d U 1:10 ) DA LGW133 S L S 10110 3 (di l 1:10 ) DA LGW133 S M S 10110 3 (df l 1:10 ) DA LGW133 S H S 10110 3 (d U 1:10 ) Mi n Q wate rTN I 0-047 5 MUi Q wate rTN I 0-047 5 1 0 ng/mLF C st d i n Mll i Q wate r MUI Q Wate rTN I 0-047 5

Printin g Time : 10:22:5 9 AM Printin g Date : Monday , Januar y03 , 201 1 Pag e 3 o f 6•Buste r J293020 3

Project : P:\Projects\Lab_lnstnjmen tDataVBustertBuste rData\Projects\fluor o Sampl e

16 9 17 0 17 1 17 2 17 3 17 4 17 5 17 6 17 7 17 8 17 9 18 0 18 1 18 2 18 3 18 4 18 5 18 6 18 7 18 8 18 9 19 0 19 1 19 2 19 3 19 4 19 5 19 6 19 7 19 8 19 9 20 0 20 1 20 2 20 3 20 4 20 5 20 6 20 7 20 8 20 9 21 0 21 1 21 2 213 ' 21 4 21 5 21 6 21 7 21 8 21 9 22 0 22 1 22 2 22 3 22 4 Sampl e Nam e

bl10103816 9 bl10103317 0 bl10103817 1 bl10103317 2 bl10103817 3 b1101038l7 4 b1101038l7 5 bl10103317 6 b l 10103317 7 b1101033l7 8 b l 10103317 9 b l 10103318 0 b110103s18 1 b l 10103318 2 bl10103318 3 bl10103318 4 bl10103318 5 bl10103318 6 b l 10103318 7 b l 10103318 8 b110103a18 9 bl10103819 0 bl10103819 1 b110103a19 2 b l 10103819 3 b l 10103819 4 b l 10103819 5 b l 10103319 6 bl10103319 7 bl10103319 8 bl10103319 9 bl10103820 0 bl10103820 1 bl10103320 2 b110103a20 3 bl10103320 4 bl10103320 5 bl10103320 6 b l 10103320 7 bl10103320 8 bl10103820 9 bl10103821 0 b110103821 1 bl10103821 2 bl10103821 3 bl10103821 4 b110103a21 5 bl10103321 6 bl10103821 7 bl10103821 8 bl10103321 9 bl10103322 0 bl10103822 1 b l 10103822 2 bl10103822 3 b110103a22 4 Sampl e I D

GLP l 0-01-01-11-05 6 GLP l 0-01-01-11-05 7 GLPlO-01-01-11-05 8 GLPlO-01-01-11-05 9 GLPlO-01-01-11-06 0 GLPlO-01-01-11-07 0 GLPlO-01-01-11-07 1 GLPlO-01-01-11-07 2 GLPlO-01-01-11-07 3 GLPlO-01-01-11-07 4 Solven tBlan k

(Mlli Q Bement ) Solven tBIsn k

(Mlli Q Bement ) 08008-194-1 0 Solven tBIsn k

(Mlli Q Bement ) GLPlO-01-01-11-08 9 GLPlO-01-01-11-09 0 GLPlO-01-01-11-09 1 GLPlO-01-01-11-09 2 GLPlO-01-01-11-09 3 GLPlO-01-01-11-09 4 GLPlO-01-01-11-09 5 GLPlO-01-01-11-09 6 GLPlO-01-01-11-09 7 GLPlO-01-01-11-09 8 Solven tBIsn k

(Mlli Q Bement ) Solven tBIsn k

(Mlli Q Bement ) 08008-194- 9 Solven tBIsn k

(Mlli Q Bement ) GLPlO-01-01-11-10 9 GLPlO-01-01-11-11 0 GLPlO-01-01-11-11 1 GLP l 0-01-01-11-11 2 GLP l 0-01-01-11-11 3 GLPlO-01-01-11-11 9 GLPlO-01-01-11-12 0 GLPlO-01-01-11-12 1 GLPlO-01-01-11-12 2 GLPlO-01-01-11-12 3 Solven tBIsn k

(MUi Q Bement ) Solven tBIsn k

(Mlli Q Bement ) 08008-194-1 2 Solven tBIsn k

(Mlli Q Bement ) GLPlO-01-01-11-12 4 GLPlO-01-01-11-12 5 GLPlO-01-01-11-12 6 GLPlO-01-01-11-12 7 GLPlO-01-01-11-12 8 GLPlO-01-01-11-12 9 GLP l 0-01-01-11-13 0 GLP l 0-01-01-11-13 1 GLPlO-01-01-11-13 2 GLP l 0-01-01-11-13 3 Solven tBIsn k

(MUi Q Bement ) Solven tBIsn k

(MUi Q Bement ) 08008-194-1 0 Solven tBIsn k

(MUI Q Bement ) Via l Positio n

S S 5 6 5 7 5 8 5 9 6 0 6 1 6 2 6 3 6 4 9 2 9 3 1 0 9 3 6 5 6 6 6 7 6 8 6 9 7 0 7 1 7 2 7 3 7 4 9 3 9 4 9 9 4 7 5 7 6 7 7 7 8 7 9 8 0 8 1 8 2 8 3 8 4 9 4 9 5 1 2 9 5 8 5 8 6 8 7 8 8 8 9 9 0 3 4 3 5 3 6 3 7 9 5 9 6 1 0 9 6 nchemicals\waterBatch:b110103 a

Dat aFil e b l 10103 a b l 10103 3 b l 10103 3 b l 10103 3 b l 10103 3 b l 10103 8 b l 10103 8 b l 10103 a b l 10103 8 b l 10103 3 b l 10103 3 b l 10103 3 b l 10103 3 b l 10103 s b l 10103 3 b l 10103 3 b l 10103 3 b l 10103 3 b l 10103 3 b l 10103 8 b l 10103 3 b l 10103 8 b l 10103 8 b l 10103 8 b l 10103 8 b l 10103 a b l 10103 a b l 10103 3 b l 10103 s b l 10103 3 b l 10103 3 b l 10103 3 b l 10103 3 b l 10103 3 b l 10103 3 b l 10103 3 b l 10103 8 b l 10103 a b l 10103 8 b l 10103 8 b l 10103 8 b l 10103 a b l 10103 8 b l 10103 3 b l 10103 s b l 10103 3 b l 10103 8 b110103 s b110103 a b110103 3 b l 10103 3 b110103 3 b l 10103 8 b l 10103 8 b l 10103 8 b l 10103 8 Inj.Volum e (pi )

2.00 0 2.00 0 2.00 0 2.00 0 2.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 2.00 0 2.00 0 2.00 0 2.00 0 2.00 0 10.00 0 10.00 0 10.00 0 10.00 0 2.00 0 2.00 0 2.00 0 2.00 0 2.00 0 2.00 0 2.00 0 2.00 0 2.00 0 2.00 0 10.00 0 10.00 0 10.00 0 10.00 0 2.00 0 2.00 0 2.00 0 2.00 0 2.00 0 2.00 0 2.00 0 2.00 0 2.00 0 2.00 0 10.00 0 10.00 0 10.00 0 10.00 0 Tab:Sampl e Set:SET 1 AcqMethod:PFO Aonly.da m

Comment s DA LGW133 L0 10110 3 (d U 1:10 ) DA LGW133 LD B 10110 3 (d U 1:10 ) DA LGW133 LL S 10110 3 (d U 1:10 ) DA LG W133 LM S 10110 3 (di l 1:10 ) DA LGW133 LH S 10110 3 (d U 1:10 ) DA LG W134 L0 10110 5 (di l 1:10 ) DA LG W134 LD B 10110 5 (d U 1:10 ) DA LG W134 LL S 10110 5 (di l 1:10 ) DA LG W134 LM S 10110 5 (d U 1:10 ) DA LGW134LH S 10110 5 (di l 1:10 ) Mi n 0 Wate rTN I 0-047 5 MUI Q Wate rTN I 0-047 S 5. 0 ng/n tF C st d i n Mll i Q wate r MUI Q Wate rTN I 0-047 5 DA LGW136 S 0 10110 3 (d U 1:10 ) DA LGW136 S D B 10110 3 (di l 1:10 ) DA LGW136 S L S 10110 3 (d U 1:10 ) DA LGW136 S M S 10110 3 (d U 1:10 ) DA LGW136 S H S 10110 3 (d U 1:10 ) DA LG W136 L0 10110 3 (di l 1:10 ) DA LG W136 LD B 10110 3 (di l 1:10 ) DA LG W136 LL S 10110 3 (d H 1:10 ) DA LG W136 LM S 10110 3 (d U 1:10 ) DA LG W136 LH S 10110 3 (di l 1:10 ) Mi n 0 wate rTN I 0-047 5 Mi n Q Wate rTN I 0-047 5 2. S ng/m LF C st d i n MU i Q Wate r MUi Q Wate rTN I 0-047 S DA LGW138 S 0 10111 0 (d U 1:10 ) DA LGW138SD B 10111 0 (di l 1:10 ) DA LGW138SL S 10111 0 (d U 1:10 ) DA LGW138 S M S 10111 0 (d U 1:10 ) DA LGW138SI-I S 10111 0 (d U 1:10 ) DA LGWCW26R 0 10111 0 (di l 1:10 ) DA LGWCW26RD B 10111 0 (d U 1:1 0 DALGWCW26RL S 10111 0 (d U 1:10 ) DA LGWCW26 R M S 10111 0 (d U 1:1 0 DA LGWCW26 R H S 10111 0 (d U 1:1 0 Mi n 0 wate rTN I 0-047 5 Mi n 0 wate rTN I 0-047 5 2 5 ng/mLFC st d i n Mll i Q Wate r Mi n 0 wate rTN I 0-047 S DA LGWCW26 L0 10111 0 (d U 1:10 ) DA LGWCW26 LD B 10111 0 (di l 1:10 ) DA LGWCW26 LL S 10111 0 (d U 1:10 ) DA LGWCW26 LM S 10111 0 (d U 1:1 0 DA LGWCW26 LH S 10111 0 (dr t1:10 ) DA LGW140R 0 10110 4(di l 1:10 ) DA LGW140RD B 10110 4(d U 1:10 ) DALGW140RL S 10110 4(d U 1:10 ) DALGW140RMS101104(dU1:10 ) DA LG W140 R H S 10110 4(d U 1:10 ) Mi n 0 wate rTN I 0-047 5 Mi n Q Wate rTN I 0-047 5 5. 0 ng/mLFC st d i n MU i Q Wate r Mi n Q wate rTN I 0-047 5

Printin g Time ; 10;22;5 9 AM Printin g Date : Monday , Januar y03 , Pag e 4 o f 6•Buste r J293020 3

Project : P:\Projects^Lab_l ^ Sampl e

22 5 22 6 22 7 22 8 22 9 23 0 23 1 23 2 23 3 23 4 23 5 23 6 ;, : 23 7 23 8 23 9 24 0 24 1 24 2 24 3 : 24 4 24 5 24 6 24 7 24 8 24 9 25 0 25 1 25 2 25 3 25 4 25 5 25 6 25 7a 25 8 - 25 9 26 0 26 1 26 2 26 3 26 4 265~~ l 26 6 26 7 26 8 26 9 27 0 27 1 27 2 27 3 27 4 27 5 27 6 27 7 27 8 27 9 28 0 Sampl e Nam e bl10103322 5 bl10103322 6 bl10103322 7 bl10103322 8 bl10103322 9 bl10103323 0 bl10103323 1 bl10103323 2 bl10103823 3 bl10103823 4 b110103823 S bl10103323 6 bl10103823 7 bl10103323 8 bl10103323 9 bl10103324 0 bl10103324 1 bl10103324 2 b110103a24 3 bl10103824 4 bl10103824 5 bl10103324 6 bl10103324 7 bl10103324 8 bl10103324 9 bl10103825 0 bl10103325 1 bl10103325 2 bl10103325 3 bl10103825 4 bl10103825 5 bl10103825 6 bl10103825 7 b l 10103825 8 b l 10103825 9 b l 10103826 0 b l 10103326 1 b l 10103326 2 bl10103326 3 bl10103326 4 bl10103826 5 bl10103326 6 bl10103326 7 bl10103326 8 bl10103326 9 bl10103327 0 bl10103327 1 bl10103327 2 bl10103327 3 bl10103827 4 bl10103827 5 b l 10103827 6 b l 10103327 7 b l 10103327 8 b l 10103327 9 b l 10103328 0 strumen tDataVBustertBuste rData\Projects\fluoiorchemicals\wat e

Sampl e I D GLPlO-01-01-11-13 4 GLP l 0-01-01-11-13 5 GLP l 0-01-01-11-13 6 GLPlO-01-01-11-13 7 GLPlO-01-01-11-13 8 GLPlO-01-01-11-13 9 GLPlO-01-01-11-14 0 GLPlO-01-01-11-14 1 GLPlO-01-01-11-14 2 GLPlO-01-01-11-14 3 Solven tBlan k

(Mlli Q Bement ) Solven tBlan k

(Mlli Q Bement ) 08008-194-1 1 Solven tBlan k

(MUi Q Bement ) GLPlO-01-01-11-14 4 GLP t0-01-01-11-14 5 GLPlO-01-01-11-14 6 GLPlO-01-01-11-14 7 GLPlO-01-01-11-14 8 GLPlO-01-01-11-00 1 GLPlO-01-01-11-00 2 GLPlO-01-01-11-00 3 GLPlO-01-01-11-00 4 GLPlO-01-01-11-00 5 Solven tBIsn k

(MUi Q Bement ) Solven tBIsn k

(MUi Q Bement ) 08008-194-1 2 Solven tBIsn k

(MUI Q Bement ) GLPlO-01-01-11-00 6 GLPlO-01-01-11-00 7 GLPlO-01-01-11-00 8 GLPlO-01-01-11-00 9 GLPlO-01-01-11-01 0 Solven tBIsn k

(Mlli Q Bement ) Solven tBIsn k

(Mlli Q Bement ) 08008-194-1 0 Solven tBIsn k

(MUi Q Bement ) GLPlO-01-01-11-01 7 GLPlO-01-01-11-01 8 GLP l 0-01-01-11-01 9 GLPlO-01-01-11-02 0 Solven tBIsn k

(MUI Q Bement ) GLPlO-01-01-11-03 1 GLPlO-01-01-11-03 2 GLPlO-01-01-11-03 3 GLPlO-01-01-11-03 4 GLPlO-01-01-11-03 5 Solven tBIsn k

(Mlli Q Bement ) Solven tBIsn k

(Mlli Q Bement ) 08008-194-1 1 Solven tBlan k

(MUi Q Bement ) GLPlO-01-01-11-03 6 GLPlO-01-01-11-03 7 GLPlO-01-01-11-03 8 GLPlO-01-01-11-03 9 GLPlO-01-01-11-04 0 Via l Positio n 3 8 3 9 4 0 4 1 4 2 4 3 4 4 4 5 4 6 4 7 9 6 9 7 1 1 9 7 4 8 4 9 5 0 5 1 5 2 5 3 5 4 5 5 5 6 5 7 9 7 9 8 1 2 9 8 5 8 5 9 6 0 6 1 6 2 9 8 9 9 1 0 9 9 6 3 6 4 6 5 6 6 9 9 6 7 6 8 6 9 7 0 7 1 9 9 10 0 1 1 10 0 7 2 7 3 7 4 7 5 7 6 Dat aFil e

b l 10103 a b l 10103 8 b l 10103 a b l 10103 3 b110103 s b110103 8 b110103 8 b l 10103 8 b l 10103 3 b l 10103 3 b l 10103 3 b l 10103 3 b l 10103 3 b l 10103 8 b l 10103 8 b l 10103 a b l 10103 a b l 10103 8 bl10103 a b l 10103 a b l 10103 3 b l 10103 3 b l 10103 3 b l 10103 a b l 10103 3 *bTl0103ir " b l 10103 3 b l 10103 3 b l 10103 s b l 10103 3 bl10103 3 b110103 8 b l 10103 3 b l 10103 s b l 10103 s b l 10103 3 b l 10103 3 b l 10103 8 b l 10103 a b l 10103 a b l 10103 8 b l 10103 a b110103 8 b110103 a bl10103 a bl10103 3 bl10103 3 bl10103 3 bl10103 3 bl10103 3 bl10103 8 bl10103 a b l 10103 a bl10103 a bl10103 a bl10103 a rBatch:b110103 a

Inj.Volum e (pi ) 2.00 0 2.00 0 2.00 0 2.00 0 2.00 0 2.00 0 2.00 0 2.00 0 2.00 0 2.00 0 10.00 0 10.00 0 10.00 0 10.00 0 2.00 0 2.00 0 2.00 0 2.00 0 2.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 ' 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 Tab:Sampl e Set:SET 1 AcqMethod:PFO Aonly.da m

Comment s DA LGW141R 0 10111 0 (d U 1:10 ) DA LGW141RD B 10111 0 (di l 1:10 ) DALGW141RLS101110(dni:10 ) DA LGW141RM S 10111 0 (di l 1:10 ) DA LGW141RH S 10111 0 (di l 1:10 ) DALGW142R 0 101110(dil1:10 ) DALGW142RDB101110(dU1:10 ) DALGW142RL S 10111 0 (d U 1:10 ) DA LGW142RM S 10111 0 (d U 1:10 ) DA LGW142RH S 10111 0 (d U 1:10 ) MUi Q Wate rTN I 0-047 5 MUi Q Wate rTN I 0-047 5 1 0 ng/mLF C st d i n Mi n Q Wate r MUi Q wate rTN I 0-047 5 DA LGW144R 0 10111 0 (d U 1:10 ) DA LGW144RD B 10111 0 (di l 1:10 ) DA LG W144RL S 10111 0 (d H 1:10 ) DA LGW144RM S 10111 0 (d n 1:10 ) DA LGW144RI-I S 10111 0 (d U 1:10 ) DA LGW130R 0 10110 5 (di l 1:100 ) DA LGW130RD B 10110 5 (d U 1:100 ) DA LG W130RL S 10110 5 (d U 1:100 ) DA LGW130RM S 10110 5 (d U 1:100 ) DA LGW130RH S 10110 5 (d U 1:100 ) MUI Q wate rTN I 0-047 5 MUi Q Wate rTN I 0-047 5 2 5 ng/mLF C st d I n Mll i Q Wate r Mi n Q Wate rTN I 0-047 5 DA LGW130S 0 10110 5 (d U 1:100 ) DA LGW130SD B 10110 5 (di l 1:100 ) DA LGW130 S L S 10110 5 (d U 1:100 ) DA LGW130 S M S 10110 5 (d U 1:100 ) DA LG W130 S H S 10110 5 (d U 1:100 ) Mi n Q\Afete rTN I 0-047 5 MU i QV\fate rTN I 0-047 5 5. 0 ng/nn LF C st d i n MU i Q Wate r MU i Q\Afate rTN I 0-047 5 DALGW131R 0 101103(dU1:100 ) DA LGW131RD B 10110 3 (di l 1:100 ) DA LGW131RL S 10110 3 (d H 1:100 ) DALGW131RH S 10110 3 (d H 1:100 ) Mi n Q Wate rTN I 0-047 5 DA LGW132R 0 10110 2 (d H 1:100 ) DA LGW132RD B 10110 2 (d U 1:100 ) DALGW132RL S 10110 2 (di l 1:100 ) DA LG W132 R M S 10110 2 (d U 1:100 ) DA LG W132 R H S 10110 2 (d U 1:100 ) MU i QV\&te rTN I 0-047 5 MUi Q wate rTN I 0-047 5 1 0 ng/mLF C st d i n Mll i Q V\fete r MU i Q\/\feite rTN I 0-047 5 DA LGW132 S 0 10110 2 (d U 1:100 ) DA LGW132 S D B 10110 2 (di l 1:100 ) DALGW132 S L S 10110 2 (d H 1:100 ) DA LGW132 S M S 10110 2 (d H 1:100 ) DA LGW132 S H S 10110 2 (d H 1:100 )

Printin g Time ; 10:22:5 9 AM Printin g Date ; Monday , Januar y03 , Pag e 5 o f 6•Buste r J293020 3

Project : P:\Projects\Lab_lnstrumen tData\BustertBuste rData\Projects\fluororchemicals\wate rBatch:b110103 aTab:Sampl e Set:SET 1 AcqMethod:PFO Aonly.da m Sampl e

28 1 28 2 28 3 28 4 28 5 28 6 28 75 28 8 28 9 29 0 29 1 29 2 29 3 29 4 29 5 29 6 29 7 29 8 29 9 30 0 30 1 30 2 30 3 30 4 30 5 30 6 Sampl e Nam e

b l 10103328 1 b l 10103328 2 bl10103328 3 bl10103328 4 bl10103328 5 b l 10103828 6 bl10103328 7 bl10103828 8 b110103a28 9 bl10103329 0 bl10103829 1 bl10103829 2 bl10103329 3 bl10103329 4 bl10103329 5 bl10103329 6 bl10103329 7 bl10103829 8 bl10103329 9 bl10103830 0 bl10103830 1 b110103a30 2 bl10103330 3 bl10103830 4 bl10103330 5 bl10103330 6 Sampl e I D

Solven tBIsn k

(Mlli Q Bement ) Solven tBl3n k

(Mlli Q Bement ) 08008-194-1 2 Solven tBIsn k

(Mlli Q Bement ) GLPlO-01-01-11-06 1 GLPlO-01-01-11-06 2 GLPlO-01-01-11-06 3 GLPlO-01-01-11-06 4 Solven tBIsn k

(Mlli Q Element) GLPlO-01-01-11-07 5 GLPlO-01-01-11-07 6 GLPlO-01-01-11-07 7 GLPlO-01-01-11-07 8 Solven tBIsn k

(Mlli Q Bement ) Solven tBlan k

(Mlli Q Bement ) 08008-194-1 0 Solven tBlan k

(Mlli Q Bement ) GLPlO-01-01-11-08 4 GLPlO-01-01-11-08 5 GLP l 0-01-01-11-08 6 GLPlO-01-01-11-08 7 GLPlO-01-01-11-08 8 Solven tBIsn k

(MUi Q Bement ) Solven tBIsn k

(MUi Q Bement ) 08008-194-1 1 Solven tBIsn k

(MUi Q Bement ) Via l Pos'itio n

10 0 9 1 1 2 9 1 7 7 7 8 7 9 8 0 9 1 8 1 8 2 8 3 8 4 9 1 9 2 1 0 9 2 8 5 8 6 8 7 8 8 8 9 9 2 9 3 1 1 9 3 Dat aFil e

bl10103 s b l 10103 3 b l 10103 3 b l 10103 3 b l 10103 8 b l 10103 a bl10103 3 b110103 3 b110103 3 b110103 a b110103 s bl10103 s bl10103 3 b l 10103 3 b l 10103 3 b l 10103 8 b l 10103 3 b l 10103 8 b110103 8 b110103 a b110103 8 b110103 3 b110103 3 b l 10103 3 b l 10103 s b l 10103 s Inj.Volum e (pi )

10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 Comment s

Mi n QV\fete rTN I 0-047 5 MUI Q wate rTN I 0-047 5 2 5 ng/n tF C st d i n Mll i Q Wate r MUi Q wate rTN I 0-047 5 DALGW134R 0 10110 5 (di l 1:100 ) DA LG W134 R D B 10110 5 (d H 1:100 ) DA LGW134RL S 10110 5 (d U 1:100 ) DA LGW134RH S 10110 5 (d U 1:100 ) MUI Q Wate rTN I 0-047 5 DA LGW135R 0 10110 5 (d H 1:100 ) DA LGW135RD B 10110 5 (d U 1:100 ) DA LGW135RL S 10110 5 (d H 1:100 ) DA LGW135RH S 10110 5 (di l 1:100 ) Mi n QV\fete rTN I 0-047 5 Mi n Q\/\fete rTN I 0-047 5 5. 0 ng/mLFC st d i n Mll i Q Wate r MUI Q Wate rTN I 0-047 5 DA LG W135 L0 10110 5 (d U 1:100 ) DA LGW135 LD B 10110 5 (d H 1:100 ) DA LGW135 LL S 10110 5 (di l 1:100 ) DALGW135 LM S 10110 5 (d H 1:100 ) DA LGW135 LH S 10110 5 (d U 1:100 ) MUI Q Wate rTN I 0-047 5 MUI Q wate rTN I 0-047 5 1 0 ng/mLF C st d i n MU i Q Wate r MIU Q wate rTN I 0-047 5

Printin g Time ; 10:22:5 9 AM Printin g Date ; Monday , Januar y03 , 201 1 Pag e 6 o f 6•Buste r J293020 3

Project : F Sampl e

1 2 3 4 5 6 7 8 9 1 0 1 1 1 2 1 3 1 4 1 5 1 6 1 7 1 8 1 9 2 0 2 1 2 2 2 3 2 4 2 5 2 6 2 7 2 8 2 9 3 0 3. 1 3 2 3 3 3 4 3 5 3 6 3 7 3 8 3 9 4 0 4 1 4 2 4 3 4 4 4 5 4 6 4 7 4 8 4 9 5 0 5 1 .52U-

- 5 3 5 4 5 5 5 6 ':\Projects\Lab_lnstrumen tData\BustertBuste rData\Prajects\fluor o

Sampl e Nam e bl10103300 1 bl10103300 2 bl10103300 3 bl10103300 4 bl10103300 5 bl10103300 6 bl10103300 7 bl10103800 8 bl10103800 9 b110103a01 0 b110103a01 1 bl10103301 2 b110103801 3 bl10103801 4 bl10103301 5 bl10103801 6 bl10103801 7 bl10103301 8 bl10103801 9 bl10103302 0 bl10103302 1 bl10103802 2 bl10103302 3 b110103a02 4 bl10103802 5 bl10103302 6 bl10103802 7 b110103a02 8 bl10103802 9 bl10103303 0 bl10103803 1 bl10103303 2 bl10103803 3 bl10103803 4 bl10103803 5 bl10103303 6 bl10103303 7 bl10103303 8 bl10103303 9 bl10103304 0 bl10103304 1 bl10103304 2 bl10103304 3 bl10103304 4 bl10103304 5 bl10103304 6 bl10103304 7 bl10103304 8 bl10103804 9 bl10103805 0 bl10103805 1 bl10103805 2 bl10103305 3 bl10103305 4 bl10103805 5 bl10103305 6 Sampl e I D

Solven tBl3n k

(Mlli Q Bement ) Solven tBIsn k

(MUi Q Bement ) Solven tBIsn k

(MUI Q Bement ) Solven tBIsn k

(MUi Q Bement ) Solven tBIsn k

(Mlli Q Bement ) Solven tBIsn k

(Mlli Q Bement ) 08008-194-1 1 syste m sui t 08008-194-1 1 syste m sui t 08008-194-1 1 syste m sui t 08008-194-1 1 systemsui t Solven tBlan k

(Mlli Q Bement ) Solven tBlan k

(Mlli Q Bement ) 08008-194- 1 08008-194- 2 08008-194- 3 08008-194- 4 08008-194- 5 08008-194- 6 08008-194- 7 08008-194- 8 08008-194- 9 08008-194-1 0 08008-194-1 1 08008-194-1 2 08008-194-1 3 08008-194-1 4 08008-194-1 5 Solven tBlan k

(Mlli Q Bement ) Solven tBlan k

(MUI Q Bement ) Solven tBlan k

(Mlli Q Bement ) 08008-194-1 0 Solven tBlan k

(Mlli Q Bement ) LCS-101230- 1 LCS-101230- 2 LCS-101230- 3 LCS-101230- 4 LCS-101230- 5 LCS-101230- 6 LCS-101230- 7 LCS-101230- 8 LCS-101230- 9 Solven tBlan k

(Mlli Q Bement ) Solven tBIsn k

(Mlli Q Bement ) 08008-194- 9 Solven tBIsn k

(Mlli Q Bement ) LCS-101230-1 0 LCS-101230-1 1 LCS-101230-1 2 LCS-101230-1 3 LCS-101230-1 4 LCS-101230-1 5 LCS-101230-1 6 LCS-101230-1 7 LCS-101230-1 8 Solven tBIsn k

(MUi Q Bement ) Solven tBlan k

(Mlli Q Bement ) Via l Positio n

9 1 9 1 9 1 9 1 9 1 9 1 1 1 1 1 1 1 1 1 9 1 9 1 1 2 3 4 5 6 7 8 9 1 0 1 1 1 2 1 3 1 4 1 5 9 1 9 2 9 2 1 0 9 2 1 6 1 7 1 8 1 9 2 0 2 1 2 2 2 3 2 4 9 2 9 3 9 9 3 2 5 2 6 2 7 2 8 2 9 3 0 3 1 3 2 3 3 9 3 9 4 rchemicals\waterBatch:b110103 a

Dat aFil e bl10103 a bl10103 8 b l 10103 a b l 10103 a b l 10103 a bl10103 3 bl10103 s bl10103 s bl10103 3 bl10103 3 bl10103 3 bl10103 s b l 10103 3 b l 10103 3 bl10103 8 b110103 s b110103 3 b l 10103 8 b110103 8 b l 10103 8 b l 10103 3 b l 10103 3 b l 10103 8 b l 10103 3 b l 10103 3 b l 10103 8 b l 10103 3 b l 10103 8 b l 10103 8 b l 10103 8 b l 10103 a b l 10103 8 b l 10103 3 b l 10103 s b l 10103 s b l 10103 3 b l 10103 3 b l 10103 8 b l 10103 3 b l 10103 3 b l 10103 8 b l 10103 a b l 10103 3 b110103 3 b l 10103 3 b l 10103 3 b l 10103 3 b l 10103 s b110103 s b110103 s b l 10103 3 b l 10103 3 b l 10103 3 b l 10103 3 b l 10103 8 b l 10103 3 Inj.Volum e (pi )

10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 Tab:Sampl e Set:SET 1 AcqMethod:PFO Aonly.da m

Comment s Mi n Q\/\fete rTN I 0-047 5 MUi Q wate rTN I 0-047 5 MUi Q wate rTN I 0-047 5 Mi n Q wate rTN I 0-047 5 Mi n Q Wate rTN I 0-047 5 Mi n QV\fate rTN I 0-047 5 1 0 ng/mLF C st d i n Mll i Q Wate r 1 0 ng/mLF C st d i n Mll i Q Wate r 1 0 ng/m LF C st d i n MI U Q Wate r 1 0 ng/mLF C st d i n Mll i Q Wate r MIU Q wate rTN I 0-047 5 MUI Q wate rTN I 0-047 5 0.02 5 ng/m LF C st d i n Mll i Q Wate r 0.0 3 ng/mLF C st d i n MH i Q Wate r 0.0 4ng/mLF C st d i n Mil l Q Wate r 0.0 5 ng/mLF C st d i n Mil l Q Wate r 0. 1 ng/m LFC st d i n MU I Q V\fafe r 0.2 5 ng/m LF C st d i n MH i Q Wate r 0. 5 ng/m LFC st d i n MU I Q V\fate r 1. 0 ng/m LFC st d i n MU i Q V\fate r 2. 5 ng/m LF C st d i n MU i 0 V\fate r 5. 0 ng/m LF C st d i n MU I Q Wate r 1 0 ng/mLF C st d i n MH i Q Wate r 2 5 ng/mLF C st d i n MH i Q Wate r 5 0 ng/mLF C st d i n MU i 0 Wate r 7 5 ng/mLF C st d i n MU i Q Wate r 10 0 ng/m LF C st d i n MU i Q Wate r MU i QV\fete rTN I 0-047 5 MUI Q wate rTN I 0-047 5 MU i Q\/\fete rTN I 0-047 5 5. 0 ng/mLFC st d I n Mll i Q Wate r MU i QV\fete rTN I 0-047 5 0.5pp b LC S 0.5pp b LC S 0.5pp b LC S 5pp b LC S 5pp b LC S 5pp b LC S 30pp b LC S 30pp b LC S 30pp b LC S MUI Q wate rTN I 0-047 5 MH i Q Wate rTN I 0-047 5 2. 5 ng/mLFC st d i n MU i Q Wate r MH i Q wate rTN I 0-047 5 O.Spp b LC S EC F O.Spp b LC S EC F O.Spp b LC S EC F Spp b LC S EC F Spp b LC S EC F Spp b LC S EC F 30pp b LC S EC F 30pp b LC S EC F 30pp b LC S EC F MUi Q Wate rTN I 0-047 S MU i QV\fete rTN I 0-047 5

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# CXJCi l il't i•Buste r J293020 3

Project : P:\ProjectsALab_lnstrumen tData\BustertBuste rData\Prajects\fluororchemicals\wat e Sampl e

5 7 5 8 5 9 i v 6 0 - 6 1 6 2 6 3 6 4 6 5 66~~~ 1 6 7 6 8 6 9 7 0 7 1 7 2 7 3 7 4 7 5 7 6 7 7 7 8 7 9 8 0 8 1 8 2 8 3 8 4 8 5 8 6 8 7 8 8 8 9 9 0 9 1 9 2 9 3 9 4 9 5 9 6 9 7 9 8 9 9 10 0 10 1 10 2 n 10 3 10 4 10 5 10 6 10 7 10 8

11 0 11 1 11 2 Sampl e Nam e b l 10103305 7 bl10103305 8 bl10103305 9 bl10103806 0 bl10103806 1 bl10103806 2 bl10103806 3 bl10103306 4 bl10103306 5 bl10103806 6 bl10103806 7 bl10103306 8 bl10103306 9 bl10103307 0 bl10103807 1 bl10103807 2 bl10103807 3 bl10103307 4 bl10103307 5 bl10103307 6 bl10103307 7 bl10103807 8 bl10103807 9 bl10103308 0 bl10103808 1 bl10103808 2 bl10103308 3 bl10103808 4 bl10103308 5 bl10103308 6 bl10103808 7 bl10103308 8 bl10103308 9 bl10103309 0 bl10103309 1 bl10103309 2 bl10103309 3 bl10103809 4 bl10103809 5 bl10103809 6 b110103a09 7 bl10103809 8 bl10103809 9 b1101038l0 0 b110103a10 1 bl10103310 2 bl10103310 3 bl10103310 4 bl10103310 5 bl10103310 6 blf01033l0 7 bl10103310 8 bl10103810 9 bl10103311 0 bl10103311 1 bl10103311 2 Sampl e I D

08008-194-1 1 Solven tBIsn k

(MUI Q Bement ) GLPlO-01-01-11-15 0 GLPlO-01-01-11-15 1 GLPlO-01-01-11-15 2 GLPlO-01-01-11-1S 3 GLPlO-01-01-11-15 4 GLPlO-01-01-11-15 5 GLPlO-01-01-11-15 6 GLPlO-01-01-11-15 7 GLPlO-01-01-11-15 8 GLPlO-01-01-11-15 9 Solven tBIsn k

(MUi Q Bement ) Solven tBIsn k

(MHi Q Bement ) 08008-194-1 0 Solven tBIsn k

(MHi Q Bennent) GLPlO-01-01-11-16 0 GLP l 0-01-01-11-16 1 GLPlO-01-01-11-16 2 GLPlO-01-01-11-16 3 GLPlO-01-01-11-16 4 GLPlO-01-01-11-16 5 GLPlO-01-01-11-16 6 GLPlO-01-01-11-16 7 GLPlO-01-01-11-16 8 GLPlO-01-01-11-16 9 Solven tBIsn k

(MUi Q Bement ) Solven tBIsn k

(MHi Q Bement ) 08008-194- 9 Solven tBIsn k

(MUi Q Bement ) GLP l 0-01-01-12-00 9 GLPlO-01-01-11-01 6 GLPlO-01-01-11-14 9 GLPlO-01-01-11-06 5 GLPlO-01-01-11-06 6 GLPlO-01-01-11-06 7 GLP l 0-01-01-11-06 8 GLPlO-01-01-11-06 9 Solven tBIsn k

(MUi Q Bement ) Solven tBIsn k

(MHi Q Bement ) 08008-194- 8 Solven tBIsn k

(MHi Q Bement ) GLPlO-01-01-11-07 9 GLP l 0-01-01-11-08 0 GLPlO-01-01-11-08 1 GLPlO-01-01-11-08 2 GLPlO-01-01-11-08 3 GLP l 0-01-01-11-09 9 GLPlO-01-01-11-10 0 GLPlO-01-01-11-10 1 GLPlO-01-01-11-10 2 GLPlO-01-01-11-10 3 Solven tBl3n k

(MUi Q Bement ) Solven tBIsn k

(MUi Q Bement ) 08008-194-1 1 Solven tBlan k

(Mlli Q Bement ) Via l Positio n

1 1 9 4 3 4 3 5 3 6 3 7 3 8 3 9 4 0 4 1 4 2 4 3 9 4 9 5 1 0 9 5 4 4 4 5 4 6 4 7 4 8 4 9 S O 5 1 5 2 5 3 9 5 9 6 9 9 6 5 4 5 5 5 6 5 7 5 8 5 9 6 0 6 1 9 6 9 7 8 9 7 6 2 6 3 6 4 6 5 6 6 6 7 6 8 6 9 7 0 7 1 9 7 9 8 1 1 9 8 Dat aFil e

b l 10103 3 b l 10103 3 b l 10103 3 b l 10103 3 b l 10103 3 b l 10103 3 b l 10103 3 b l 10103 3 b l 10103 8 b l 10103 3 b l 10103 3 b l 10103 3 b l 10103 8 bl10103 3 bl10103 3 bl10103 s b l 10103 3 b l 10103 3 b l 10103 3 b l 10103 3 b l 10103 8 b l 10103 a b l 10103 a b l 10103 a b l 10103 a b l 10103 a bl10103 3 bl10103 3 bl10103 3 bl10103 3 bl10103 3 bl10103 3 b l 10103 3 b l 10103 3 b l 10103 8 b l 10103 8 b l 10103 a b l 10103 a bl10103 8 bl10103 a b l 10103 3 bl10103 3 bl10103 8 bl10103 8 b l 10103 8 b l 10103 a b l 10103 8 b l 10103 8 b l 10103 8 b l 10103 a b l 10103 a b l 10103 3 b l 10103 8 b l 10103 3 b l 10103 a bl10103 8 rBatch:b110103 a

Inj.Volum e (pi ) 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 2.00 0 10.00 0 10.00 0 10.00 0 10.00 0 2.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 2.00 0 10.00 0 10.00 0 10.00 0 10.00 0 2.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 2.00 0 2.00 0 2.00 0 2.00 0 2.00 0 10.00 0 10.00 0 10.00 0 10.00 0 2.00 0 2.00 0 2.00 0 2.00 0 2.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 Tab:Sampl e Set:SET 1 AcqMethod:P F

Comment s 1 0 ng/m LF C st d i n MU i 0 \/\fate r Mi n QV\fete rTN I 0-047 5 Tri p Blan k

Se t1 Sartpl e Tri p Bl3n k

Se t1 L S Tri p Blan k

Se t1 M S Tri p Blan k

Se t1 MH S Tri p Blan k

Se t1 HS(d H 1:100 ) Tri p BIsn k

Se t2 Ssmpl e Tri p BIsn k

Se t2 L S Tri p BIsn k

Se t2 M S Tri p BIsn k

Se t2 MH S Tri p BIsn k

Se t2 HS(d n 1:100 ) Mi n QV\fete rTN I 0-047 5 MH i QWste rTN I 0-047 5 5. 0 ng/nn LFC st d i n Mll i Q Wate r Mi n QV\fate rTN I 0-047 5 Tri p BIsn k

Se t3 Sampl e Tri p BIsn k

Se t3 L S Tri p BIsn k

Se t3 M S Tri p BIsn k

Se t3 MH S Tri p BIsn k

Se t3 HS(d H 1:100 ) Tri p BIsn k

Se t4Sampl e Tri p Blan k

Se t4L S Tri p BIsn k

Se t4M S Tri p BIsn k

Se t4MH S Tri p Bl3nkSet4HS(d H 1:100 ) MH i QV\fate rTN I 0-047 5 MH i Q\/\feite rTN I 0-047 5 2. S ng/mLFC st d i n MH i Q Wate r MH i QV\feite rTN I 0-047 5 DA LSS607RR B 004 0 DA LGW130LR B 10110 5 DA LGW144RR B 10111 0 DA LGW134 S 0 10110 5 DA LGW134SD B 10110 5 DA LGW134SL S 10110 5 DA LGW134 S M S 10110 5 DA LGW134SH S 10110 5 MHi Q Wate rTN I 0-047 S MHi Q Wate rTN I 0-047 5 1. 0 ng/mLFC st d i n MU i Q Wate r MH i QV\fete rTN I 0-047 5 DA LGW13S S 0 10110 5 DALGW13SSDB10110 S DA LGW13SSL S 10110 5 DA LGW13S S M S 10110 5 DALGW13SSHS10110 S DA LGW137 S 0 10110 9 DALGW137SDB10110 9 DA LGW137SL S 10110 9 DA LGW137 S M S 10110 9 DALGW137SI-IS10110 9 MUi Q Wate rTN I 0-047 5 MUi Q wate rTN I 0-047 5 1 0 ng/m LFC st d i n Mll i Q Wate r MUi Q Wate rTN I 0-047 5 OAonly.da m

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Project : P:\Projects^Lab_lnstrumen tData\BustertBuste rData\Projects\fluor o Sampl e

11 3 11 4 11 5 11 6 11 7 11 8 11 9 12 0 12 1 12 2 12 3 12 4 12 5 12 6 12 7 

## 1283 " 12 9 13 0 13 1 13 2 13 3 13 4' 13 5 13 6 13 7 13 8 13 9 14 0 14 1 14 2 14 3 14 4 14 5 14 6 14 7 14 8 14 9 IS O 15 1 15 2 15 3 15 4 15 5 15 6 15 7 15 8 15 9 16 0 16 1 16 2 16 3 16 4 16 5 16 6 16 7 16 8 Sampl e Nam e b110103a11 3 b1101038l1 4 b1101038l1 5 bl10103311 6 b1101033l1 7 b1101033l1 8 b110103s11 9 bl10103812 0 b110103s12 1 bl10103312 2 bl10103312 3 bl10103812 4 bl10103312 5 bl10103312 6 bl10103312 7 bl10103312 8 bl10103312 9 bl10103313 0 bl10103313 1 bl10103313 2 b110103s13 3 bllOl03813 4 bl10103813 5 bl10103813 6 bl10103313 7 bl10103313 8 bl10103313 9 bl10103314 0 bl10103314 1 bl10103314 2 bl10103314 3 bl10103314 4 bl10103314 5 bl10103314 6 bl10103314 7 bl10103314 8 bl10103314 9 bl10103315 0 b1101033l5 1 bl10103315 2 bl10103315 3 bl10103315 4 bl10103315 5 bl10103315 6 bl10103315 7 bl10103315 8 bl10103315 9 bl10103816 0 b1101038l6 1 bl10103816 2 bl10103816 3 b1101038l6 4 b1101038l6 S bl10103316 6 b110103a16 7 b1101033l6 8 Sampl e I D

GLP l 0-01-01-11-10 4 GLP l 0-01-01-11-10 5 GLPlO-01-01-11-10 6 GLPlO-01-01-11-10 7 GLPlO-01-01-11-10 8 GLPlO-01-01-11-11 4 GLPlO-01-01-11-11 5 GLPlO-01-01-11-11 6 GLPlO-01-01-11-11 7 GLPlO-01-01-11-11 8 Solven tBIsn k

(MHi Q Bement ) Solven tBIsn k

(Mlli Q Bement ) 08008-194-1 0 Solven tBl3n k

(Mlli Q Bement ) GLPlO-01-01-11-01 1 GLPlO-01-01-11-01 2 GLP l 0-01-01-11-01 3 GLPlO-01-01-11-01 4 GLP l 0-01-01-11-01 5 GLPlO-01-01-11-02 1 GLPlO-01-01-11-02 2 GLPlO-01-01-11-02 3 GLP l 0-01-01-11-02 4 GLP l 0-01-01-11-02 5 Solven tBIsn k

(MUi Q Bement ) Solven tBIsn k

(MUi Q Bement ) 08008-194- 9 Solven tBlan k

(MUi Q Bement ) GLP l 0-01-01-11-02 6 GLPlO-01-01-11-02 7 GLPlO-01-01-11-02 8 GLPlO-01-01-11-02 9 GLPlO-01-01-11-03 0 GLPlO-01-01-11-04 1 GLP l 0-01-01-11-04 2 GLPlO-01-01-11-04 3 GLPlO-01-01-11-04 4 GLPlO-01-01-11-04 5 Solven tBIsn k

(MHi Q Bement ) Solven tBIsn k

(MHi Q Bement ) 08008-194-1 2 Solven tBIsn k

(MHi Q Bement ) GLPlO-01-01-11-04 6 GLPlO-01-01-11-04 7 GLPlO-01-01-11-04 8 GLPlO-01-01-11-04 9 GLPlO-01-01-11-05 0 GLPlO-01-01-11-05 1 GLP l 0-01-01-11-05 2 GLPlO-01-01-11-05 3 GLPlO-01-01-11-05 4 GLP l 0-01-01-11-05 5 Solven tBlan k

(Mlli Q Bement ) Solven tBlan k

(Mlli Q Bement ) 08008-194-1 1 Solven tBlan k

(MUi Q Bement ) Via l Positio n

7 2 7 3 7 4 7 5 7 6 7 7 7 8 7 9 8 0 8 1 9 8 9 9 1 0 9 9 8 2 8 3 8 4 8 5 8 6 8 7 8 8 8 9 9 0 3 4 9 9 10 0 9 10 0 3 5 3 6 3 7 3 8 3 9 4 0 4 1 4 2 4 3 4 4 10 0 9 1 1 2 9 1 4 5 4 6 4 7 4 8 4 9 5 0 5 1 5 2 5 3 5 4 9 1 9 2 1 1 9 2 rchemicalsVwate

Dat aRI e b l 10103 a b l 10103 8 b l 10103 8 b l 10103 3 b l 10103 3 b110103 3 b110103 s b l 10103 8 b l 10103 a b l 10103 3 b l 10103 3 b l 10103 3 b l 10103 s b l 10103 s b l 10103 3 b l 10103 3 b l 10103 s b l 10103 3 b l 10103 3 b l 10103 3 b l 10103 3 b l 10103 3 b l 10103 8 b l 10103 8 b l 10103 s b l 10103 8 b l 10103 3 b l 10103 8 b l 10103 a b l 10103 8 bl10103 a b110103 a b110103 8 b l 10103 8 b110103 3 b l 10103 s b l 10103 s bl10103 s b l 10103 3 bl10103 3 bl10103 s bl10103 s bl10103 3 b l 10103 s b l 10103 3 b l 10103 s bl10103 s b l 10103 3 b l 10103 3 b l 10103 3 b l 10103 3 b l 10103 3 b l 10103 3 b l 10103 8 bl10103 8 bl10103 8 rBatch:b110103 a

Inj.Volum e (pi ) 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 2.00 0 2.00 0 2.00 0 2.00 0 2.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 2.00 0 2.00 0 2.00 0 2.00 0 2.00 0 10.00 0 10.00 0 10.00 0 10.00 0 Tab:Sampl e Set:SET 1 AcqMethod:PFO A

Comment s DA LGW137 L0 10110 9 DA LGW137LD B 10110 9 DA LGW137LL S 10110 9 DA LGW137 LM S 10110 9 DA LGW137LH S 10110 9 DA LGW138 L0 10111 0 DA LGW138LD B 10111 0 DA LGW138LL S 10111 0 DA LGW138 LM S 10111 0 DALGW138LHS10111 0 MH i QVVfafe rTN I 0-047 5 MH i QWfate rTN I 0-047 5 5. 0 ng/mLF C st d i n MU i Q Wate r MHi Q Wate rTN I 0-047 5 DA LGW130L 0 10110 5 (d H 1:10 ) DA LGW130 LD B 10110 5 (d H 1:10 ) DA LGW130LL S 10110 5 (d H 1:10 ) DA LGW130 LM S 10110 5 (d H 1:10 ) DA LGW130 LH S 10110 5 (d H 1:10 ) DA LGW131 S 0 10110 3 (d H 1:10 ) DA LGW131SD B 10110 3 (d H 1:10 ) DALGW131 S L S 10110 3 (d H 1:10 ) DA LGW131SH S 10110 3 (d U 1:10 ) DA LGW131 S M S 10110 3 (d U 1:10 ) MUi Q Wate rTN I 0-047 5 MUi Q wate rTN I 0-047 5 2. 5 ng/mLFC st d i n MH i Q Wate r MUi Q wate rTN I 0-047 5 DA LGW131L 0 10110 3 (d H 1:10 ) DA LGW131 LD B 10110 3 (d H 1:10 ) DA LG W131 LL S 10110 3 (d U 1:10 ) DA LGW131 LM S 10110 3 (d H 1:10 ) DA LG W131 LH S 10110 3 (d H 1:10 ) DA LG W132 L0 10110 3 (d H 1:10 ) DA LG W132 LD B 10110 3 (d U 1:10 ) DA LG W132 LL S 10110 3 (d H 1:10 ) DA LG W132 LM S 10110 3 (d U 1:10 ) DA LGW132 LH S 10110 3 (d U 1:10 ) MUi Q wate rTN I 0-047 5 MUI Q Wate rTN I 0-047 5 2 5 ng/mLF C st d i n MU i Q Wate r MUi Q Wate rTN I 0-047 5 DA LGW133R 0 10110 2 (d H 1:10 ) DA LGW133RD B 10110 2 (d U 1:10 ) DA LGW133RL S 10110 2 (d H 1:10 ) DA LGW133 R M S 10110 2 (d U 1:10 ) DA LGW133RH S 10110 2 (d U 1:10 ) DA LGW133S 0 10110 3 (d H 1:10 ) DA LGW133 S D B 10110 3 (d U 1:10 ) DA LGW133 S L S 10110 3 (d H 1:10 ) DA LG W133 S M S 10110 3 (d U 1:10 ) DALGW133 S H S 10110 3 (d U 1:10 ) MHi Q Wate rTN I 0-047 5 MUi Q Wate rTN I 0-047 5 1 0 ng/n tF C st d i n MU i Q V\fete r MH i QV\fete rTN I 0-047 5 only.da m

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Project : P:\Projects\Lab_l r Sampl e

16 9 U O ' 17 1 17 2 17 3 17 4 17 5 17 6 17 7 17 8 17 9 18 0 18 1 18 2 18 3 18 4 18 5 18 6 18 7 18 8 18 9 19 0 19 1 19 2 19 3 19 4 19 5 19 6 19 7 19 8 19 9 20 0 20 1 20 2 20 3 20 4 20 5 20 6 20 7 20 8 20 9 21 0 21 1 21 2 21 3 21 4 21 5 21 6 21 7 21 8 21 9 22 0 22 1 22 2 22 3 22 4 Sampl e Nam e b110103a16 9 b l 10103317 0 b l 10103817 1 bl10103817 2 tmm033l73~ ^ b l 10103817 4 bl10103817 5 bl10103317 6 bl10103317 7 b l 10103317 8 bl10103317 9 bl10103318 0 

## biiordssTsT^ b l 10103818 2 bl10103318 3 bl10103318 4 b110103s18 5 b1101033l8 6 bl10103318 7 b l 10103318 8 b l 10103318 9 b l 10103319 0 b1101033l9 1 b l 10103819 2 b l 10103819 3 b1101033l9 4 b l 10103319 5 b l 10103319 6 b l 10103319 7 b l 10103819 8 bl10103819 9 bl10103320 0 bl10103320 1 bl10103820 2 b l 10103820 3 b l 10103320 4 b l 10103320 5 b l 10103320 6 b l 10103820 7 bl10103320 8 bl10103820 9 b110103321 0 bl10103821 1 bl10103321 2 bl10103321 3 bl10103321 4 bl10103321 5 bl10103321 6 bl10103321 7 b110103a21 8 b110103s21 9 bl10103322 0 bl10103822 1 bl10103822 2 bl10103822 3 bl10103822 4 strumen tData\Buster\Buste rData\Projects\fluor o

Sampl e I D GLPlO-01-01-11-05 6 GLPlO-01-01-11-05 7 GLPlO-01-01-11-05 8 GLPlO-01-01-11-05 9 GLPlO-01-01-11-06 0 GLP l 0-01-01-11-07 0 GLPlO-01-01-11-07 1 GLPlO-01-01-11-07 2 GLPlO-01-01-11-07 3 GLPlO-01-01-11-07 4 Solven tBlan k

(MUi Q Bement ) Solven tBlan k

(MUi Q Bement ) 08008-194-1 0 Solven tBlan k

(MUi Q Bement ) GLPlO-01-01-11-08 9 GLPlO-01-01-11-09 0 GLPlO-01-01-11-09 1 GLPlO-01-01-11-09 2 GLPlO-01-01-11-09 3 GLPlO-01-01-11-09 4 GLPlO-01-01-11-09 5 GLPlO-01-01-11-09 6 GLPlO-01-01-11-09 7 GLPlO-01-01-11-09 8 Solven tBlan k

(MUi Q Bennent) Solven tBlan k

(MUi Q Bement ) 08008-194- 9 Solven tBIsn k

(MUi Q Bement ) GLPlO-01-01-11-10 9 GLPlO-01-01-11-11 0 GLPlO-01-01-11-11 1 GLPlO-01-01-11-11 2 GLP l 0-01-01-11-11 3 GLP l 0-01-01-11-11 9 GLPlO-01-01-11-12 0 GLPlO-01-01-11-12 1 GLPlO-01-01-11-12 2 GLPlO-01-01-11-12 3 Solven tBIsn k

(MUI Q Bement ) Solven tBlan k

(MUi Q Bement ) 08008-194-1 2 Solven tBlan k

(MUi Q Bement ) GLP l 0-01-01-11-12 4 GLPlO-01-01-11-12 5 GLPlO-01-01-11-12 6 GLPlO-01-01-11-12 7 GLPlO-01-01-11-12 8 GLPlO-01-01-11-12 9 GLPlO-01-01-11-13 0 GLPlO-01-01-11-13 1 GLPlO-01-01-11-13 2 GLPlO-01-01-11-13 3 Solven tBIsn k

(MUi Q Bement ) Solven tBIsn k

(MHi Q Bement ) 08008-194-1 0 Solven tBIsn k

(MHi Q Bement ) Via l Positio n

5 5 5 6 5 7 5 8 5 9 6 0 6 1 6 2 6 3 6 4 9 2 9 3 1 0 9 3 6 5 6 6 6 7 6 8 6 9 7 0 7 1 7 2 7 3 7 4 9 3 9 4 9 9 4 7 5 7 6 7 7 7 8 7 9 8 0 8 1 8 2 8 3 8 4 9 4 9 5 1 2 9 5 8 5 8 6 8 7 8 8 8 9 9 0 3 4 3 5 3 6 3 7 9 5 9 6 1 0 9 6 rchemicals\waterBatch:b110103 a

Dat aFil e b110103 3 b l 10103 3 b110103 3 b l 10103 3 b l 10103 3 b l 10103 s b l 10103 3 bl10103 s b l 10103 3 b l 10103 3 b l 10103 3 b l 10103 3 b l 10103 a b l 10103 3 b l 10103 3 b l 10103 s b110103 3 b l 10103 s b110103 3 b l 10103 3 b l 10103 3 b l 10103 3 b l 10103 3 b l 10103 s b l 10103 8 b l 10103 8 b l 10103 8 b l 10103 8 b l 10103 8 b l 10103 3 b l 10103 3 b l 10103 8 b l 10103 8 b l 10103 8 b l 10103 a b l 10103 3 b l 10103 3 b l 10103 3 b l 10103 8 b l 10103 8 b l 10103 3 b l 10103 8 b l 10103 a b l 10103 8 b l 10103 a b l 10103 a b l 10103 8 b l 10103 8 b l 10103 a b l 10103 a b l 10103 a b l 10103 3 b l 10103 3 b l 10103 3 b l 10103 s b l 10103 3 Inj.Volum e (pi )

2.00 0 2.00 0 2.00 0 2.00 0 2.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 2.00 0 2.00 0 2.00 0 2.00 0 2.00 0 10.00 0 10.00 0 10.00 0 10.00 0 2.00 0 2.00 0 2.00 0 2.00 0 2.00 0 2.00 0 2.00 0 2.00 0 2.00 0 2.00 0 10.00 0 10.00 0 10.00 0 10.00 0 2.00 0 2.00 0 2.00 0 2.00 0 2.00 0 2.00 0 2.00 0 2.00 0 2.00 0 2.00 0 10.00 0 10.00 0 10.00 0 10.00 0 Tab:Sampl e Set:SET 1 AcqMethod:PFO Aonly.da m

Comment s DA LG W133 L0 10110 3 (d H 1:10 ) DA LGW133 LD B 10110 3 (d H 1:10 ) DA LGW133LL S 10110 3 (d H 1:10 ) DA LG W133 LM S 10110 3 (d U 1:10 ) DA LGW133 LH S 10110 3 (d H 1:10 ) DA LG W134 L0 10110 5 (d H 1:10 ) DA LGW134 LD B 10110 5 (d H 1:10 ) DA LGW134 LL S 10110 5 (d H 1:10 ) DA LG W134 LM S 10110 5 (d U 1:10 ) DA LGW134 LH S 10110 5 (d H 1:10 ) MHi Q wate rTN I 0-047 5 MHi Q wate rTNI0-047 5 5. 0 ng/mLF C st d i n Mll i Q V\fete r MHi Q Wate rTNI0-047 5 DA LGW136 S 0 10110 3 (d H 1:10 ) DA LG W136 S D B 10110 3 (d H 1:10 ) DA LGW136 S L S 10110 3 (d H 1:10 ) DA LG W136 S M S 10110 3 (d U 1:10 ) DA LGW136 S H S 10110 3 (d U 1:10 ) DALGW136L 0 10110 3 (d U 1:10 ) DA LGW136 LD B 10110 3 (d H 1:10 ) DA LGW136 LL S 10110 3 (d U 1:10 ) DA LG W136 LM S 10110 3 (d H 1:10 ) DA LG W136 LH S 10110 3 (d H 1:10 ) MHI Q Wate rTNI0-047 5 MH i QVVfate rTN I 0-047 5 2. 5 ng/mLF C st d i n Mll i Q Wate r MHI Q wate rTNI0-047 5 DA LGW138S 0 10111 0 (d U 1:10 ) DA LGW138SD B 10111 0 (d H 1:10 ) DA LGW138SL S 10111 0 (d H 1:10 ) DA LGW138 S M S 10111 0 (d H 1:10 ) DA LGW138SH S 10111 0 (d H 1:10 ) DA LGWCW26R 0 10111 0 (d U 1:10 ) DA LGWCW26RD B 10111 0 (d H 1:1 0 DA LGWCW26RL S 10111 0 (d H 1:10 ) DA LGWCW26RM S 10111 0 (d H 1:1 0 DA LGWCW26RH S 10111 0 (d H 1:1 0 MHi Q Wate rTNI0-047 5 MHi Q wate rTNI0-047 5 2 5 ng/mLF C st d i n MU i Q wate r MHi Q wate rTNI0-047 5 DA LGWCW26 L0 10111 0 (d H 1:10 ) DALGWCW26 LD B 10111 0 (d H 1:10 ) DA LGWCW26 LL S 10111 0 (d U 1:10 ) DA LGWCW26 LM S 10111 0 (d H 1:1 0 DA LGWCW26 LH S 10111 0 (d H 1:10 ) DA LG W140 R 0 10110 4(d H 1:10 ) DA LGW140RD B 10110 4(d H 1:10 ) DA LGW140RL S 10110 4(d H 1:10 ) DALGW140RMS101104(dH1:10 ) DA LGW140RH S 10110 4(d H 1:10 ) MUI Q wate rTN I 0-047 5 MUi Q wate rTN I 0-047 5 5. 0 ng/mLFC st d i n MU i Q Wate r MU i Q wate rTN1.0-047 5

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Project : P:\Projects\Lab_lnstrumen tData\Buster\Buste rDataVProjectsVluororohemicals^wat e Sampl e

22 5 225— ^ 22 7 22 8 22 9 23 0 23 1 23 2 23 3 23 4 23 5 23 6 23 7 23 8 23 9 24 0 24 1 24 2 24 3 24 4 24 5 24 6 24 7 24 8 24 9 25 0 25 1 25 2 25 3 25 4 25 5 25 6 25 7 25 8 25 9 26 0 26 1 26 2 26 3 26 4 26 5 26 6 26 7 26 8 26 9 27 0 27 1 27 2 27 3 27 4 27 5 27 6 27 7 27 8 27 9 28 0 Sampl e Nam e

bl10103322 5 bl10103322 6 bl10103322 7 bl10103322 8 bl10103822 9 bl10103823 0 bl10103823 1 bl10103823 2 bl10103823 3 bl10103323 4 bl10103323 5 bl10103323 6 bl10103323 7 bl10103323 8 bl10103823 9 bl10103324 0 bl10103324 1 bl10103324 2 bl10103324 3 b110103s24 4 b110103324 5 bl10103324 6 b110103324 7 bl10103324 8 bl10103824 9 b110103325 0 b110103325 1 bl10103325 2 bl10103825 3 bl10103825 4 bl10103325 5 b l 10103325 6 bl10103325 7 b l 10103325 8 bl10103825 9 bl10103326 0 bl10103326 1 bl10103826 2 b110103326 3 b110103s26 4 bl10103326 5 bl10103326 6 bl10103326 7 bl10103326 8 bl10103326 9 b110103s27 0 bl10103327 1 bl10103827 2 b l 10103827 3 bl10103827 4 b l 10103827 5 b110103a27 6 bl10103827 7 bl10103327 8 bl10103327 9 bl10103328 0 Sampl e I D

GLPlO-01-01-11-13 4 GLPlO-01-01-11-13 5 GLPlO-01-01-11-13 6 GLPlO-01-01-11-13 7 GLPlO-01-01-11-13 8 GLPlO-01-01-11-13 9 GLPlO-01-01-11-14 0 GLP l 0-01-01-11-14 1 GLPlO-01-01-11-14 2 GLPlO-01-01-11-14 3 Solven tBl3n k

(Mlli Q Bement ) Solven tBIsn k

(MUi Q Bement ) 08008-194-1 1 Solven tBl8n k

(MUi Q Bement ) GLPlO-01-01-11-14 4 GLPlO-01-01-11-14 5 GLPlO-01-01-11-14 6 GLPlO-01-01-11-14 7 GLPlO-01-01-11-14 8 GLPlO-01-01-11-00 1 GLPlO-01-01-11-00 2 GLPlO-01-01-11-00 3 GLPlO-01-01-11-00 4 GLPlO-01-01-11-00 5 Solven tBIsn k

(MHi Q Bement ) Solven tBIsn k

(Mlli Q Bement ) 08008-194-1 2 Solven tBIsn k

(MHi Q Bennent) GLPlO-01-01-11-00 6 GLPlO-01-01-11-00 7 GLPlO-01-01-11-00 8 GLPlO-01-01-11-00 9 GLPlO-01-01-11-01 0 Solven tBIsn k

(MHi Q Bement ) Solven tBIsn k

(MHi Q Bement ) 08008-194-1 0 Solven tBIsn k

(Mlli Q Bement ) GLPlO-01-01-11-01 7 GLPlO-01-01-11-01 8 GLPlO-01-01-11-01 9 GLPlO-01-01-11-02 0 Solven tBIsn k

(Mlli Q Bement ) GLPlO-01-01-11-03 1 GLPlO-01-01-11-03 2 GLPlO-01-01-11-03 3 GLPlO-01-01-11-03 4 GLPlO-01-01-11-03 5 Solven tBIsn k

(MUi Q Bement ) Solven tBIsn k

(MUi Q Bement ) 08008-194-1 1 Solven tBIsn k

(MUi Q Bement ) GLPlO-01-01-11-03 6 GLP l 0-01-01-11-03 7 GLPlO-01-01-11-03 8 GLP l 0-01-01-11-03 9 GLPlO-01-01-11-04 0 Via l Positio n 3 8 3 9 4 0 4 1 4 2 4 3 4 4 4 5 4 6 4 7 9 6 9 7 1 1 9 7 4 8 4 9 5 0 5 1 5 2 5 3 5 4 5 5 5 6 5 7 9 7 9 8 1 2 9 8 5 8 5 9 6 0 6 1 6 2 9 8 9 9 1 0 9 9 6 3 6 4 6 5 6 6 9 9 6 7 6 8 6 9 7 0 7 1 9 9 10 0 1 1 10 0 7 2 7 3 7 4 7 5 7 6 Dat aFil e

b l 10103 3 b l 10103 s b l 10103 8 b l 10103 3 b l 10103 3 b l 10103 3 b l 10103 3 b l 10103 3 b l 10103 3 b l 10103 3 b l 10103 3 b l 10103 3 b l 10103 3 b l 10103 s b l 10103 8 b l 10103 8 b l 10103 8 b l 10103 3 b l 10103 8 b l 10103 3 b l 10103 8 b l 10103 8 b l 10103 8 b l 10103 8 b l 10103 3 b l 10103 3 b l 10103 3 b l 10103 3 b l 10103 3 b l 10103 3 b l 10103 s b l 10103 3 b l 10103 3 b l 10103 s b l 10103 3 b l 10103 3 b l 10103 s b l 10103 3 b l 10103 s b l 10103 3 b l 10103 s b l 10103 s b l 10103 s b l 10103 8 b l 10103 a b l 10103 a b l 10103 8 b l 10103 3 b l 10103 3 b l 10103 3 b l 10103 s b l 10103 8 b l 10103 8 b l 10103 a b l 10103 a b l 10103 3 rBatch:b110103 a

Inj.Volum e (pi ) 2.00 0 2.00 0 2.00 0 2.00 0 2.00 0 2.00 0 2.00 0 2.00 0 2.00 0 2.00 0 10.00 0 10.00 0 10.00 0 10.00 0 2.00 0 2.00 0 2.00 0 2.00 0 2.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 Tab:Sampl e Set:SET 1 AcqMethod:P F

Comment s DA LGW141R 0 10111 0 (d H 1:10 ) DA LGW141RD B 10111 0 (d U 1:10 ) DA LGW141RL S 10111 0 (d H 1:10 ) DA LGW141RM S 10111 0 (d U 1:10 ) DA LGW141RH S 10111 0 (d U 1:10 ) DA LGW142R 0 10111 0 (d H 1:10 ) DA LGW142RD B 10111 0 (d U 1:10 ) DA LGW142RL S 10111 0 (d H 1:10 ) DA LGW142 R M S 10111 0 (d U 1:10 ) DA LGW142RH S 10111 0 (d H 1:10 ) MU i QV\fete rTN I 0-047 5 MU i QV\feite rTN I 0-047 5 1 0 ng/mLF C st d i n MU i Q wate r MUi Q wate rTN I 0-047 5 DALGW144R 0 10111 0 (d U 1:10 ) DA LG W144RD B 10111 0 (d H 1:10 ) DALGW144RL S 10111 0 (d H 1:10 ) DALGW144RMS101110(dH1:10 ) DA LGW144RH S 10111 0 (d H 1:10 ) DA LGW130R 0 10110 5 (d H 1:100 ) DA LGW130RD B 10110 5 (d H 1:100 ) DALGW130RL S 10110 5 (d H 1:100 ) DA LGW130 R M S 10110 5 (d H 1:100 ) DA LGW130RH S 10110 5 (d H 1:100 ) MHi Q wate rTN I 0-047 5 MHi Q Wate rTN I 0-047 5 2 5 ng/mLF C st d i n MH i Q Wate r MH i QWfete rTN I 0-047 5 DA LGW130S 0 10110 5 (d H 1:100 ) DA LGW130 S D B 10110 5 (d U 1:100 ) DA LG W130 S L S 10110 5 (d H 1:100 ) DA LG W130 S M S 10110 5 (d U 1:100 ) DA LGW130SH S 10110 5 (d H 1:100 ) MH i Q\Afete rTN I 0-047 5 MH i QV\fate rTN I 0-047 5 5. 0 ng/mLF C st d i n MH i Q Wate r MHi Q Wate rTN I 0-047 5 DA LGW131R 0 10110 3 (d U 1:100 ) DA LGW131RD B 10110 3 (d H 1:100 ) DALGW131RL S 10110 3 (d H 1:100 ) DA LGW131RH S 10110 3 (d H 1:100 ) MUi Q wate rTN I 0-047 5 DA LGW132R 0 10110 2 (d H 1:100 ) DA LGW132RD B 10110 2 (d U 1:100 ) DALGW132RL S 10110 2 (d U 1:100 ) DA LGW132RM S 10110 2 (d U 1:100 ) DA LGW132RH S 10110 2 (d H 1:100 ) MUi Q Wate rTN I 0-047 5 MUi Q Wate rTN I 0-047 5 1 0 ng/mLF C st d i n MHi Q Wate r MUi Q wate rTN I 0-047 5 DA LGW132S 0 10110 2 (d U 1:100 ) DA LGW132SD B 10110 2 (d H 1:100 ) DA LGW132 S L S 10110 2 (d U 1:100 ) DA LGW132 S M S 10110 2 (d U 1:100 ) DA LGW132 S H S 10110 2 (d U 1:100 ) OAonly.da m

Printin g Time ; 10:07:2 1 AM Printin g Date : Friday , Januar y07 , Pag e 5 o f 6•Buste r J293020 3

Project : P:\Projects\Lab_lnstrumen tData\BustertBuste rData\Projects\fluoroTChemicals\wat e Sampl e

28 1 28 2 28 3 28 4 28 5 28 6 28 7 28 8 28 9 29 0 29 1 29 2 29 3 i 29 4, 29 5 29 6 29 7 29 8 29 9 30 0 30 1 30 2 30 3 30 4 30 5 30 6 30 7 30 8 30 9 j 4 31 0 31 1 31 2 31 3 31 4 31 5 31 6 31 7 31 8 ^ 31 9 32 0 32 1 32 2 32 3 32 4

. Sampl e Nam e

bl10103328 1 b l 10103328 2 bl10103328 3 bl10103328 4 bl10103828 5 bl10103328 6 bl10103328 7 bl10103328 8 bl10103328 9 bl10103329 0 bl10103329 1 bl10103829 2 bl10103829 3 b110103a29 4 b110103s29 5 bl10103329 6 bl10103329 7 bl10103329 8 bl10103829 9 bl10103330 0 bl10103330 1 bl10103330 2 bl10103330 3 bl10103330 4 bl10103330 5 bl10103330 6 b110103b30 7 b110103b30 8 b110103b30 9 b110103b31 0 b110103b31 1 b110103b31 2 b110103b31 3 b110103b31 4 b110103b31 5 b110103b31 6 b110103b31 7 b110103b31 8 b110103b31 9 b110103b32 0 b110103b32 1 b110103b32 2 b110103b32 3 b110103b32 4



## Sam i Th e lowe volu r Sampl e I D Solven tBlan k

(Mlli Q Bement ) Solven tBlan k

(Mlli Q Bement ) 08008-194-1 2 Solven tBIsn k

(MUi Q Bement ) GLP l 0-01-01-11-06 1 GLP l 0-01-01-11-06 2 GLP l 0-01-01-11-06 3 GLP l 0-01-01-11-06 4 Solven tBIsn k

(MUi Q Bement ) GLPlO-01-01-11-07 5 GLPlO-01-01-11-07 6 GLPlO-01-01-11-07 7 GLPlO-01-01-11-07 8 Solven tBIsn k

(MUi Q Bement ) Solven tBIsn k

(MUi Q Bement ) 08008-194-1 0 Solven tBIsn k

(MUi Q Bement ) GLPlO-01-01-11-08 4 GLPlO-01-01-11-08 5 GLPlO-01-01-11-08 6 GLPlO-01-01-11-08 7 GLPlO-01-01-11-08 8 Solven tBIsn k

(MUi Q Bement ) Solven tBIsn k

(MUi Q Bement ) 08008-194-1 1 Solven tBIsn k

(MUi Q Bement ) GLPlO-01-01-11-04 4 GLPlO-01-01-11-04 5 Solven tBIsn k

(MUi Q Bement ) GLPlO-01-01-11-07 0 GLPlO-01-01-11-07 1 GLPlO-01-01-11-07 2 GLP l 0-01-01-11-07 3 GLPlO-01-01-11-07 4 Solven tBIsn k

(MUi Q Bement ) Solven tBlan k

(MUi Q Bement ) 08008-194-1 0 Solven tBlan k

(Mlli Q Bement ) GLP l 0-01-01-11-13 4 GLP l 0-01-01-11-13 5 GLPlO-01-01-11-13 6 Solven tBIsn k

(Mlli Q Bement ) 08008-194- 9 Solven tBIsn k

(Mlli Q Bement )



## Die s bll0103b30 7thr u b samples wit h hig h are ac rvolum e an d samples w i ne

. O G 1-7-1 1 Via l Positio n 10 0 9 1 1 2 9 1 7 7 7 8 7 9 8 0 9 1 , 8 1 8 2 8 3 8 4 9 1 9 2 1 0 9 2 8 5 8 6 8 7 8 8 8 9 9 2 9 3 1 1 9 3 7 1 7 2 9 4 7 3 7 4 7 5 7 6 7 7 9 4 9 5 1 0 9 5 7 8 7 9 8 0 9 5 9 9 6



## 110103b32 ' ounts abov

e t h are aco u Dat aFil e

b l 10103 a b l 10103 8 b l 10103 a b l 10103 a b l 10103 a b l 10103 3 b l 10103 8 b l 10103 a b l 10103 a b l 10103 3 b l 10103 8 b l 10103 a b l 10103 a b l 10103 8 b l 10103 a b l 10103 3 b l 10103 3 b l 10103 3 b l 10103 8 b l 10103 s b l 10103 s b l 10103 a b l 10103 3 b l 10103 8 b l 10103 a b l 10103 3 b l 10103 3 b l 10103 s b l 10103 3 b l 10103 3 b l 10103 8 b l 10103 8 b l 10103 3 b l 10103 3 b l 10103 s b l 10103 8 b l 10103 a b l 10103 3 b l 10103 8 b l 10103 a b l 10103 8 b l 10103 3 b l 10103 8 DataSET I



## i were add e : th e calibra nt s nea rth e rBatch:b110103 a

Inj.Volum e (pi ) 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 10.00 0 2.00 0 2.00 0 10.00 0 2.00 0 2.00 0 2.00 0 2.00 0 2.00 0 10.00 0 5.00 0 5.00 0 5.00 0 10.00 0 10.00 0 10.00 0 5.00 0 5.00 0 5.00 0



## d t o th e seq u tio n cun/ e we LO Q were i n Tab:Sampl e Set:SET 1 AcqMethod:PFO Aonly.da m

Comment s MHi Q wate rTNI0-047 5 MHi Q wate rTN I 0-047 5 2 5 ng/mLF C st d i n MH i Q Wate r MHi Q wate rTN I 0-047 5 DA LGW134R 0 10110 5 (d U 1:100 ) DA LG W134 R D B 10110 5 (d H 1:100 ) DA LGW134RL S 10110 5 (d H 1:100 ) DA LGW134RH S 10110 5 (d U 1:100 ) MHi Q Wate rTN I 0-047 5 ^LGW135R 0 10110 5 (d U 1:100 ) DA LG W135 R D B 10110 5 (d H 1:100 ) DA LGW135RL S 10110 5 (d H 1:100 ) DA LGW135RH S 10110 5 (d H 1:100 ) MHi Q Wate rTN I 0-047 5 MHi Q wate rTN I 0-047 5 5. 0 ng/mLF C st d i n MU i Q Wate r MHi Q Wate rTN I 0-047 5 DA LGW135L 0 10110 5 (d H 1:100 ) DA LGW135LD B 10110 5 (d H 1:100 ) DA LGW135 LL S 10110 5 (d H 1:100 ) DA LGW135 LM S 10110 5 (d H 1:100 ) DA LGW135LH S 10110 5 (d H 1:100 ) MHi Q Wate rTNI0-047 5 MHi Q wate rTNI0-047 5 1 0 ng/mLF C st d i n Mll i Q Wate r MHi Q wate rTN I 0-047 5 DA LGW132 LM S 10110 3 (d H 1:10 ) DA LGW132 LH S 10110 3 (d H 1:10 ) MHi Q Wate rTN I 0-047 5 DA LGW134L 0 10110 5 (d H 1:10 ) DA LGW134LD B 10110 5 (d U 1:10 ) DA LGW134LL S 10110 5 (d H 1:10 ) DA LGW134 LM S 10110 5 (d U 1:10 ) DA LGW134 LH S 10110 5 (di l 1:10 ) MHi Q Wate rTNI0-047 5 MHi Q wate rTN I 0-047 5 5. 0 ng/m LF C st d i n MU i Q wate r MHi Q Wate rTN I 0-047 5 DALGW141R 0 10111 0 (d H 1:10 ) DALGW141RDB101110(dH1:10 ) DALGW141RL S 10111 0 (d U 1:10 ) MHi Q Wate rTN I 0-047 5 2. 5 ng/nn LF C st d i n MH i Q V\fete r MHi Q Wate rTN I 0-047 5



## ence o n 1-7-11

. re injecte d a ta ecte d wit h ahighe r

Printin g Time : 10:07:2 1 AM Printin g Date : Friday , Januar y07 , 201 1 Pag e 6 o f 6•Buste r J293020 3

Acquisitio nInformatio n Acquisitic nNfethod : Created : Las t Mxlified ; CUlllKnt : Synchrcr izatic nMade : fluto-Eqiii1 ihratioi : Acquisitio nDuration : Nuttie r O f Scans : Period s mFile : Acquisitio nMadule ; Softwar eversic r Agilen t L C Pui pNfethodErTTPrtie s PLItpMDdel : MinijTu nPressur e(psi ) Nbxinu nEressuc E(psi ) DeadVoluti e(pi) ; Ntednu nFlo wKan

p(nil/rain') : Nfexinu nPressur eRan

p(psi/sec) ;

Ste pTable ; Stq : Tbta lTim

e(rain) 00.0 0 1 2.0 0 214.5 0 3 15.5 0 416.5 0 5 20.0 0

lef t Oaipressibility : Ri^i t Ctnpressibility ; Left DeadVolut e(pi) ; R i ^DeadVblui e(pi ) lef t Strok eVblun e(pi ) Flo wRat e(pl/min ) 30 0 30 0 30 0 30 0 30 0 30 0

50. 0 115. 0 40. 0 40. 0

Ricfi t Strck eVolun e(pi ) : Left Solvent : R i ^Solveit : A l B l

Agilen t Autorartple r

Prqpertipfl Autoraitple r

Majel : Syring eSiz e(pi) : Injectic nVolun e(pi ) ; Dra wSpee d(pl/rain) ; Ejec t ^ee d(pl/min) ; Ifeedl eLeve l(nin) : TfenpeEHtiur

eCtntiro l V6£ hi s no t use d PPD AOTly.dam Thursda yNavHiber

0 4201 013 ; 27 ; 5 3 J M Nfcnda yJaniar y0 3 201 1 08 : 25 : 4 9 A M PEQ Aonl y D C Syn c Off 20min0se c 380 9 1 Acquisitio nNfethod Analys t 1.4. 2

i^ilen t 1100I C Birar yPui p 0. 0 5801. 0 40. 0 100. 0 290. 0

A(% ) B (% ) 97. 03. 0 97. 03. 0 5. 095. 0 5. 095. 0 97. 03. 0 97. 03. 0

-1. 0 -1. 0

fgilsJ t 110 0Theni D Autoranple r 10 0 5.0 0 200. 0 200. 0 0.0 0 No t Use d

U ^CustcraIrrjecto r

Prograrr Agilen t Cblu mOvenPrcpertie s Left 'teiperatur eCC) ; R i ^Tfenperatur eCC) 30.0 0 Tfenperatur eTbleranc e+/

- CC) ; Star t AajLtLsitio nTbleranc e+/

- (°C) ; TimeTabl e Cblu mSwitchin gValv e (ND t Used) Installe d Etsitic nfo r

firs t sanpl ei nth ebatch ; N o

30.0 0

1.0 0 0.5 0

R i ^

ns esm apas itio nfo r al ltuple s i nth ebatc h Tbta lTinE(min ) 0.0 0Left 4.0 0Ri ^

Iterio d1 ;

Scan s i nEteriod : Relativ eStar t

Time : Experiment s i nEteriod :

Perio d1 B^erimEn t

ScanType ; Etolarlty ; ScanNbde : Valv eEbsitic n

380 9 0.0 0mse c 1

1 :

f m(MW ) tfegativ e N/ A

Printin g Time ; 10:23:4 5 AM Printin g Date ; Monday , Januar y03 , 201 1 Pag e 1 o f 2 

# cs e i-'i- n*Buste r J293020 3

I c nScurce ; Resolutic nQl ; Resolutic nQ3 ; Tlrrh nPpm y

Uni t Chi t Intensit yThres. ; 0.0 0 Settlin gTime ; N RE&use : M3^ : N

D ste pSize :

Q lN6S S (anu ) 413.0 0 0.000 0ttse c

5.007 0mse c

0.0 0an u

Q 3 Nbs s (anu ) 369.0 0 c p s

Evelldnsec ) 100.O C ftrair

CS Of f Star t -14.0 0 -9.0 0 Ste p

-14.0 0 -9.0 0

CP

- N6s s (anu ) 413.0 0 0 3 N6s s (anu )

219.0 0 Dwel l(msec )

100

. O C Eaiai r

C E CXE Star t

Ste p -24.0 0-24.0 0 -15.0 0-15.0 0

Q lybs s (anu ) 413.0 0 Q 3 N6S S (anu )

169.0 0 Dwell(msec )

100

. O C Etaa n

C E Of f Star t -28.0 0 -9.0 0 Ste p

-28.0 0 -9.0 0



### laranete r TSble(Perixx

J1 B^eriment

1) : O O CU R GS l GS 2 I S ; TE M i h e D P E E IQ l 6.0 0

35.0 0 45.0 0 60.0 0 -4500.0 0 450.0 0 C N -40.0 0 -10.0 0 10.0 0

Printin g Time : 10:23:4 5 AMPag e 2 o f 2 Printin g Date : Monday , Januar y03 , 201 1

### ** * Buste r J293020 3 BatchName : bll0103a.dab

1 2 3 4 5 6 7 8 9 1 0 1 1 1 2 1 3 '1 4 1 5 ; i 6 1 7 1 8 1 9 2 0 2 1 2 2 2 3 2 4 2 5 2 6 2 7 2 8 2 9 •3 0 3 1 3 2 3 3 3 4 3 5 3 6 3 7 3 8 ,3 9 ,4 0 '4 1 4 2 4 3 4 4 4 5 4 6 4 7 4 8 4 9 5 0 5 1 5 2 5 3 Sampl e

Nam e

b110103a00 1 b110103a00 2 bllOIOSaOO a b110103a00 4 b110103a00 5 b110103a00 6 b110103a00 7 b110103a00 8 bil0103a00 9 b l 10103301 0 b110103a01 1 b110103a01 2 bll'OIOSaOI S 'bli6l03a01 4 ;b110103a01 5 'b110103a01 6 'b110103a01 7 b110103a01 8 b110103a01 9 b110103a02 0 b110103a02 1 b110103a02 2 b110103a02 3 b110103a02 4 b110103a02 5 bii0103a02 6 :b110103a02 7 •b110103a02 8 •b110103a02 9 ^b110103a03 0 bl10103303 1 b110103a03 2 b1ldl03ab3 3 bl10103303 4 b110T03a03 5 bl10103303 6 bTlOi'03303 7 b110f03303 8 'b110103a03 9 b110103a04 0 Ibl10103304 1 ;b110103304 2 :b110103a04 3 b110103a04 4 b110103a04 5 b110103a04 6 b110103a04 7 bl10103304 8 b110103a04 9 bl10103305 0 b110103a05 1 bl10103305 2 b110103a05 3



# _ . _ Sampl e I D

Solven tBlan k

(Milli Q Element ) Sol\«n tBl3nl < (Milli Q Element ) Solven tBlanl<lMilii Q Element ) Solven tBlanl < (Milli Q Element ) Solven tBlen k

(Milli Q Element ) Solven tBlan k

(Milli Q Element ) 08008-194- 1 Tsyste m sui t 08008-194-1 1 syste m sui t 08008-194- 1 rsysfe m sui t 08008-194-1 1 syste m sui t Solven tBianMrSilli Q Element ) Solven tBlen k

(Miiii Q Element ) 08008-194- 1 08008-194- 2 08008-194- 3 '08008-194 ^ 08008-194- 5 08008-1"94- 6 08008-194- 7 08008-194 ^ 08008-194- 9 08008^194-1 0 08008-194-1 1 08008-194-1 2 08008-194-1 3 08008-194-1 4 08008-194-1 5 Solven tBIsn k

(Milli Q Element ) SoTven tBlen k

(TviiTliQ^Eiement ) Solven tBlan k

(Milli Q Element ) 08068-194- W Solven tBlan k

(MilliQ'Element ) LCS-101230- 1 LCS-101230- 2 LCs;T0i23 M LCS-101230 ^ LCS-101230- 5 LCS-101230- 6 LCS-101230- 7 LCS-i01236- 8 LCS-101230- 9 Solven tBlan k

(Milli Q Element ) Solven tBlan k

(MilliQEIement ) 08008-194"- 9 Solven tBlen k

(Milli Q Element ) LCS-101230-1 0 LCS-101230-1 1 LCS-10^1230^12 " LCS-101230-1 3 LCS-l6l230-1 4 LCS-101230-1 5 LCS-101230-1 6 LCS-101230-17 "



# - Sampl e Commen t

Mill i QW3terTlM10-047 5 Milli Q Wate rTN10-047 5 Mill i Q Wate rTN10-047 5 Milli Q Wate r7^10-047 5 Milli Q Wate r^10-047 5 Mill i Q Wate rTN10-047 5 1 0 ng/m LF C st d i n Mill i Q Wate r 1 0 ng/m LF C st d i n Mill i Q Wate r 1 0 ng/m LF C st d i n Mill i Q Wate r 1 0 ng/m LF C st d i n Mill i Q Wate r Milli Q Wate rTN10-047 5 Milli Q Wate rTMi0-047 5 0.02 5 ng/m LF C st d in'Miil i Q Wete r 0.0 3 ng/m LF C st d i n Mill i Q Wafe r 0.0 4ng/m LF C st d i n Mill i Q Wate r 0.0 5 ng/m LF C st d in'Miil i Q Wate r 0. 1 ng/m LF C st d i n Mill i Q Wate r 0.2 5 ng/m LF C st d i n Milli- Q Wate r 0. 5 ng/m LF C st d i n Mill i Q Wate r 1. 0 ng/m LF C st d i n Mill i Q Water " 2. 5 ng/m LF C st d i n Mill i Q Wate r 5. 0 ng/m LF C st d i n Mill i Q Wate r 1 0 ng/m LF C st d i n Mill i Q Wate r 2 5 ng/m LF C st d i n M'ilf i Q Wate r 5 0 ng/m LF C st d i n Mill i Q Wate r 7 5 ng/m LF C std7 n Mli' Q Wate r 10 0 ng/m LF C st d i n Mill i Q Wate r Milli Q Wate rTNIO-O4T 5 Mill i Q Wate rTNiO-047 5 Mill i Q Wate rTNIO-047 5 5. 0 ng/mL> C stdTTMili i Q Wate r Mill i Q Wate rTNIO-047 5 O.'SppbLCS " 0.5pp b LC S O.Spp b LC S Spp b LC S Spp b LC S Spp b LC S 30pp b LC S 36pp b LC S 30pp b LC S Milli Q Wate rTNIO-047 5 Milli Q Wate rTNIO-047 5 2. 5 ng/m LF C st d i n Mill i Q Wate r Mill i Q Wate rTIM10-047 S O.Spp b LC S EC F O.Spp b LC S EC F O.Spp b LC S EC F Spp b LC S EC F Spp b LC S EC F Spp b LC S EC F 30pp b LC S EC F 30pp b LC S EC F 

# " - Sampl e Typ e

Unknow n Unknovi/ n Unknow n Unknow n Unknow n Unknow n Unknow n Unknow n Unknow n Unknow n Unknow n

. Unknow n

, Standar d Stand3r d 'St3nd3r d Standar d Standsr d Stsndar d Sland3r d Standar d Stand3r d Standar d Standsr d Standar d Standsr d Standar d

' Stand3r d lUnknow n Unknow n Unknow n Qualit yContro l Unknow n Qualif yContro T Qualit yContro l Qualit yConfro r Qualit yContro l •Qualit yContro l Qualit yContro l Qualit yContro l •Qualit yContro l Qualit yContro l Unknow n Unknow n Qualit yContro f Unknow n Qualit yContro l Qualit yContro l Qualit yContro l Qualit yContro l Qualit yContro l Qualit yContro l Quslit yContro l Qualit yContro l Analyt e

iPFO A iPFO A IPFO A •PFO A PFO A PFO A :PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A iPFO A jPFO A PFO A PFO A iPFO A

"PFOA" " PFO A PFO A' PFO A

P?O A PFO A PFO A IPFO A PFO A |PF"O A iPFO A ffSpO A jPFO A "iPFO A 'PFO A

•PFO A 'pFO A ""PFO A

' PFO A

•PFO A PTOA" ' |PFO A jPFO A iPFO A IPFO A ipFO A 'PFO A PFO A 'PTO A PFO A PFO A PFO A ,PFO A •PFOA " 12217 3

5253 6 2865 0 1216 7 1244 8 1022 1 1249S49 0 1221512 0 1232473 6 1145082 4 660 6 233 2 3783 0 4139 3 5609 8 7557 2 13276 8 35973 5 74233 0

" 145988 4" 342885 9 612344 2 1191742 2 2658783 5 40S3321 4 5133191 4 6020961 0 •628 2 721 6 602 0 '606015 6 789 0 76884 8 73828 0 78120 4 734645 7 718173 4 712946 9 2708467 5 2724746 9 2714453 4 841 6 688 1 '323131 8 662 2 '72466 3 73336 3 71739 4 789678 3 759003 8 769334 3 3129371 9 3092380 2 Analyt e

Retentio n Tim e (mi n •14. 9 14. 8 14. 9 14. 9 14. 9 14. 8 14. 8 14. 8 14. 8 14. 8 14. 9 14. 8 '14. 8 114. 8 '14. 8 '14. 8 ^14. 8 14. 8 14. 8 14. 8 14. 8 14. 8 14. 8 14. 8 14. 8 :i4. 8 ;i4. 8 |14. 8 |14: 8 ^14. 8 h4.8" " 14. 8 14. 8 '14. 8 14. 8 14. 8 14" 8 14: 8 !l4. 8 114. 8 il4. 8 114. 8 :i4 8 !l4. 8 14. 8 14. 8 14. 8 14 ; 8 14. 8 14. 8 14. 8 •14. 8 14. 8



# . _- . Analyt e

Concentratio n ) (ng/mL ) N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A "N/ A N/ A "07025 d "o.o'so d ' 0.040 0 o.dsoo 0.099 9 0.25 0 0.50 0 0.999 " 2.5 0 5.0 0 9.9 9 2"5.0 " 50. 0 75.0" ' ' "99. 9 N/ A W K N/ A S.OO N/ A ""0T4"9 7 0.49 7 0.49 7 4.9 7 4.9 7 4r9'7 " 29. 9 29.9 " 29'

. 9 ^ N/ A N/ A '2.50 " N/ A 0.49"8 " 0.49 8 0.49 8 4.9 9 4:99 ^ 4.9 9 29. 9 29.9 '



# . Us e

R e CO re



### K E E E E E E E E E E E E D D



## ' E

E 

## E E E E E E E E

E

E E E E E E E E Calculate d Concentratio n (ng/mL ) 10.087 1 10.034 3 10.016 1 0.0036 3 •0.0038 4 0.0021 6 10. 3 10. 0 10. 1 9.3 5

< 0

< 0 0.023 1 0.025 8 !o.037 0 |o.OS1 7 10.095 2 0.26 8 ' :0.56 0 1.1 1 2.6 5 4.8 2 9.7 7 25. 0 50. 2 ;N o Intercep t jN o Intercep t

I< 0 l < 0 [4.7 7" i0.00038 8 lo.'ssd 0.55 7 0759 0 5.8 3 5.6 9 is.e s [25. 6 125. 8 125. 7 0.00078 7

< 0 |2.4 9

< 0 laS4 6 055 3 '0.S4'l ' 6.2 9 •6.0 3 ;6.1 2 ^31. 3 Accurac y



## (%)

N/ A N/ A N7 A N/ A N/ A N/ A N/ A N/ A N/ A' N/ A

"N/' A N/ A 92. 4 86. 0 92. 4 103

. 95'.' 3 107

. 112

. TT L 106

. "96.3" ' 97. 8 99.9 ' 100

. N/ A N/ A N/ A N/ A N/ A 95. 3 N/ A T17 : 112

. 119 ; 117

. "115

. 114

. 85. 6 86.3 " 85. 9 N/ A N/A ' *99. 7 N/ A '110

. 111

. 'idg

. 126

. "121

. 123

. 105

. 30. 8 T103 : 

# " ' " Recor d Modifie d 

### D D E E E D E E 

# a E E D D 

# n D D 

# n D D D E E 

# n D E D D 

## D E D D 

## E E E 

# d E D E E D D E 

# b E E E E E E E E E E Dilutio n

. .. . „

Facto rAcquisitio n Dat e

1 1/3/201 1 10:27:0 6 A M 1 1/3/201 1 10:48:16A M 1 ' 1/3/201 1 11:09:1 8 A M 1 1 1/3/201 1 11:30:2 2 A M ; 1 1/3/2'O-i l 11:51:2 2 A M 1 1/3/201 1 12:12:2 5 P M 1 1/3/2011 " 12:33:3 1 P M ' 1 1/3/201 1 12:54:3 5 P M 1 l/3/2"0"l"l"l:TS:37"P M 1 1/3/201 1 1:36:3 8 P M 1 '1/3/201 1 1:57:4 1 P M 1 1/3/201 1 2:18:4 4P M

' 1 1/3/2011'2:39:4 6 P M " ; 1 ' "l7372'0'T l 3:00:5 1 P M • 1 1/3/201 1 3:21:5 0 P M j 1 T/3"/20il'3:42:5 2 P M ] 1 1/3/201 1 4:03:5 6 P M " ' 1 l73/20i l 4:24:5 9 P M ] 1 "1/3/201 1 4:46:0 1 P M , 1 1/3/2dl"r5:0'7T04"PM " " j 1 1/3/201 1 5:28:0 9 P M 1 l"/3/20T i 5:49:1 2 P M " : 1 1/3/201 1 6:10:1 7P M 1 1/3/201 1 6:31:2 0 P M • 1 1/3/201 1 6:52:2 0 P M j 1 1/3/201 1 7:13:2 8 P M i 1 l73/2'01 1 7:34:3 4 P M | 1 1/3/201 1 7:55:3 6 P M 1 1/3/201 1 8:16:3 8 P M ; 1 1/3/201 1 8:37:4 0 P M 1 1/3/201 1 8:58:4 3 P M 1 "1/3/201 1 9:19:5 4 P M 1 T/3"/20ir9741:0 2 PM ' ' ; 1 1/3/201 1 10:02:0 8 P M f"T/3/2dlTl"0:"23:15""P M i 1 1/3/201 1 10:44:1 5 P M ] 1 1/3/201 1 11:05:1 7P M j 1 "173/261 1 11:26:2 6 P M ; 1 1/3/201 1 11:47:3 6 P M ; 1 " 'l74"/2diri2:08:3 8 AM" " 1 "l74/2"01 1 12:29:4 3 A M • 1 ' '1/472'0"1 1 12:50:4 7A M i 1 1/4/201 1 1:11:5 3 A M 1 " 'T7472dlT"l:3"2:5 8 A M ; 1 ' 1/472"0l"ri:"54:0 4 A M 1 1/4/201 1 "2:15:1 3 A M 1 1/4/201 1 2:36:1 9 A M i 'l7"47201 1 2r57:23"A M 1 1/4/201 1 3:18:2 9 A M 1 1 "l74/'201 1 3:39:3 7 A M j 1 1/4/201 1 4:00:4 4A M 1 1/4/201 1 4;21:5 0 A M , 1 1/4/201 1 4:42:5 4A M \



# _- , Dat a printe db

yST W Printing Time : 1:04:4 0 P M Printing Date : Tuesday , Januar y18 , 201 1 Page 1 o f 7



# ^\^''^' ' ^( ^** * Buste r J293020 3 Batc hName : bll0103a.da b

5 4 5 5 5 6 5 7 S 8 5 9 6 0 6 1 6 2 6 3 6 4 6 5 6 6 6 7 6 8 6 9 7 0 7 1 7 2 7 3 7 4 7 5 7 6 7 7 7 8 7 9 8 0 8 1 8 2 8 3 8 4 8 5 8 6 8 7 8 8 8 9 9 0 9 1 9 2 9 3 9 4 9 5 9 6 9 7 9 8 9 9 10 0 10 1 10 2 10 3 10 4 10 5 10 6 Sampl e

_, , „

Nam e Sampl e I D

b110103a05 4LCS-101230-1 8 b l 10103305 5 Solven tBlan k (Milli Q Element ) b l 10103305 6 Solven tBlan k (Milli Q Element ) b l 10103305 708008-194-1 1 b l 10103305 8 Solven tBlan k (Milli Q Element ) b110103a05 9 GLP10-01-01-11-15 0 b110103306 0 GLP10-01-01-11-15 1 b110103a06 1 GLP10-01-01-11-15 2 b l 10103306 2 GLP10"-bl-01-1l"-15"" 3 b l 10103306 3 GLPlO-01-01-11-15 4 b110103a064 " GLP10"^T-O1-Tl-T5 5 b110103a06 5 GLPIO-OI-OI-'-IT^IS e b l 10103306 6 GLPlO-01-01-11-15 7 b11010"3306 7GLP'lMl'^"i^-l'5 8 b110103306 8 GLP10-01-01-11-15 9 b110103306 9 Solven tBla7fk'(MilTi Q Element ) b110103a07 0 Solven tBlan k (Milli Q Element ) b110103a07 1 08008-l"94-l"o " b110103307 2 Solven tBlan k (Milli Q Element ) b110103a07 3 GLPlO-01-01-11-16 0 b110103a07 4GLPlO-01-01-11-16 1 b l 10103307 5 GLPl6-bl"-Ol"-l"l~162" " b110103a07 6 GLPlO-01-01-11-16 3 b l 10103307 7GLPlO-01-01-11-16 4 b110103a07 8 GLP10-0T5ri-l'vi6 l b110103307 9 GLP10-01-01-11-16 6 b l 10103308 0 GLPlO-01-01-11--i6 7 b l 10103308 1 GLPIO-Ol-OI- l 1-168 " b"lT0103"a0'8" 2 GL"pi0^l'^-l'l^16" 9 " " b110103308 3 Solven tBle'nk " (Mii b Erem"ent ) b l 10103308 4Solven tBlan k (Milli Q Element ) b l 10103308 5 08008-194- 9 b l 10103308 6 Solven tBlen k (Milli Q Element ) •b110103308 7GLP10-01-01-12-00 9 b110103308 8 GLP10-01-01-11-01 6 b110103308 9 GLP10-01-01-11-14 9 b110103309 0 GLP10-01-01-11-06 5 b110103a09 1 GLPIO-Oijdl-l"^-*) ^ b110103a09 2 GLPlO-01-01-11-06 7 b110103a09 3 GLPl"0-01^1^T-d68 " b110103a09 4GLPlO-01-01-11-069 ' b110103a09 5 Solven tBlan k (Milli Q Element ) b l 10103309 6 Solven tBl3n k (^filli' Q Element ) b110103309 708008-l"94"- 8 " b l 10103309 8 Solven tBle'n k (IVIilli Q E'lement ) b l 10103309 9 G"LP10-dl^l"-" l 1-07 9 b l 10103310 0 GLPlO-01-01-11-08 0 b1-i01033l0 1 GLP'lO'-6l^1-lT68 1 b1101033l0 2 GLPlO-01-01-11-08 2 b l 10103310 3 GL'P10-d"l-d"l-i~1-'0"8" 3 " b1101033l0 4GLPIO-01-01-11-0'9 9 b110103a105"GLP10-01-01-l'l-l'0 0 b110103a106'GLP10-bl-dl-11-10 1 Sampl e Commen t

30pp b LC S EC F Mill i Q Wate rTNIO-047 5 Mill i Q Wate rTNIO-047 5 1 0 ng/m LF C st d i n Mill i Q Wate r Milli Q Wate rTNIO-047 5 Tri p Blan k

Se t1 Sempl e Tri p Blan k

Se t1 L S Tri p Blan k

Se t1 M S Tri p Blan k

Se t1 MH S Tri p Blan k

Se t1 H S (di l 1:100 ) Tri p Blan k

Se t2 Sampl e Tri p Blan k

Se t2 L S Tri p Blan k

Se t2 M S Tri p BIsn k

Se t2 MH S Tri p BIsn k

Se t2 H S (di l 1:100 ) Mill i Q Wate rTNIO-047 5 Milli Q Wate rTNIO-047 5 5. 0 ng/m LF C st d i n Mill i Q Wate r Milli Q Wate rTNIO-047 5 Tri p BIsn k

Se t3 Ssmpf e Tri p BIsn k

Se t3 L S Tri p BIsn k

Se t3 M S Tri p BIsn k

Se t3 MH S Tri p Blan k

Se t3 H S (di l 1:100) " Tri p Blan k

Se t4Sampl e Tri p Blan k

Ser4L S Tri p BIsn k

Se t4M S Tri p Blan k

Se t4MH S Tri p BIsn k

Se t4H S (di l 1:100 ) Mill i Q Wate rTNIO-047 5 Milli Q Wsle rTNIO-047 5 2. 5 ng/m LF C st d i n Mill i Q Wste r Mill i Q Wate rTNIO-047 5 DA LS S 607 R R B 004 0 DA LG W130 LR B 10110 5 DALG W144RR B 10111 0 DALG W134 S 0 fOIIO S DALG W134SD B 10110 5 DALG W134 S L S 10110 5 DALG W134 S M S 10110 5 DALG W134 S H S 10110 5 Milli Q Wate rTNIO-047 5 Milli Q Wste rTNIO-047 5 1. 0 ng/m LF C st d i n Mill i Q Wste r Milli Q Wate rTNIO-047 5 DALG W135S 0 10110 5 DALG W135 S D B 10110 5 DALG W135 S L S 10110 5 DALG W135 S M S 10110 5 DALG W135 S H S 10110 5 DALG W137 S 0 10110 9 DALG W137 S D B 10110 9 DALG W137 S L S 10110 9 Sampl e Typ e

Qualit yContro l Unknow n Unknow n Qualit yContro l Unknow n Unknow n Unknow n Unknow n Unknow n Unknow n 'Unknow n

' Unknow n

' Unknow n Unknow n Unknow n Unknow n Unknow n .Qualit yContro l Unknow n Unknow n Unknow n Unknov m Unknow n Unknow n Unknow n ! Unknow n Unknow n lUnknow n rOnknow n lUnknow n 1 Unknow n 1 Qualit yContro l Unknow n Unknow n Unknow n Unknow n Unknow n LJnknow n Unknow n Unknow n Unknow n Unknow n Unknow n Quslit yContro l lUnknow n lUnknow n I Unknow n [Unknow n i Unknow n j Unknow n ; Unknow n

' Unknow n i Unknow n Pea k Nam e ,^„^„,^ j

PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A ;PFO A PFO A iPFQ A PFO A .PFO A PFO A 'PFO A PFO A PFO A PFO A PFO A PFO A 'PFO A PFO A PFO A PFO A PFO A PFO A •pFO A ipFO A tpFO A IPFO A fpFO A 'PFO A "PF"6A " IPFO A IPFO A PFO A 'P'FO A PFO A PFO A PFO A PFO A PFO A PFO A

•PFO A ;PFO A jPFO A IPFO A IPFO A IPFO A IPFO A IPFO A IPFO A ;PFO A 3084143 9

744 7 526 6 1172041 3 546 4 803 7 142170 3 1284649 7 2214161 3 1265457 5 820 4 141531 0 1319319 1 2174120 2 1241732 0 1175 7 1184 6 601279 4 772 4 1711 8 140175 1 1260262 9 2247805 0 1269544 9 2967 5 138927 2 1257656 5 2145626 4 1200457 0 1435 9 765 9 316167 9 1045 0 ^ " 814 1 9"80 1 716 3 148314 5 140425 5 181980 6 426263 9 2268117 8 1663 4 1013 0 143133 6 1079 6 359533 9 346527 2 375603 8 616155 9 2412228 1 36699 0 35941 3 46784 3 Analyt e

Retentio n Tim e (mi n 14. 8 14. 8 14. 8 14. 8 14. 8 14. 8 14. 8 '14. 8 14. 8 114. 8 14. 8 14. 8 14. 8 14. 8 14. 8 14. 8 14. 8 14. 8 14. 8 14. 8 14. 8 14. 8 14. 7 14. 8 14. 8 14.8 " 14. 8 114. 7

•14. 8 •14. 8 Ii4. 8 ,14. 8 !l"4T 7 14. 8 14. 8 14. 8 'l4. 7 14. 7 14. 7 14. 7 14. 7 14. 7 14. 8 '14. 8 '14. 8 :14. 7 '14. 8 114. 7 '14. 8 '14. 7 14. 8 14. 8 :i4. 8 Analyt e

Concentratio n ) (ng/mL ) 29. 9 N/ A N/ A 9.9 9 N/ A N/ A N/ A N/ A N/ A N/ A N/ A" ' " " N/ A

' N/'A

" N7 A• N/ A N/ A N/ A 5.0 0 N/ A N/ A' ' N/ A N/A " N/ A N/ A

'N/A " N/ A N/ A 'N/A ' - •- N/ A 'N/ A 2.5 0 'NT A N/ A "N7 A N/ A "NTA" " "N'/ A N/A ' N/ A N/ A N/ A N/ A 0.99 9 N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A Calculate d

__

, Concentratio n """^• ^ (ng/mL ) E 30. 6 0000051 6

< 0 E 9-5 9

< 0 0.00049 9 1.0 8 ;10. 6 199. 1 1040

. 0.00062 5 '1.0 8 10. 9 96. 9 1020

. 0.0033 2 0.0033 9 

### E "'^' 3 0.00026 1 0.0073 9 1.0 7 10. 4 101

. 1050

. 10016 9 11.0 6 110. 4 195. 4 •985

. 10.0052 9 0.00021 2 E ;2-4 4 i"0.0023 3 i0.00057 8 10.0018 4

< 0 5.6 4 5.3 4 6.9 5 16. 6 102

. 0.0070 2 10.0020 9

" E '1-0 9

iO.0025 9 |13. 9 i13. 4 .114. 5 124. 2 110

. 10.27 3 026 8 •035 0 Accurac y



## (%)

102

. N/ A N/ A 96. 0 N/ A N/ A N/ A N/ A ,N/A " N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A 94. 5 N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A IN/ A !N/ A jN/ A 'N/ A iN/ A '97. 5 ,N7A N/ A N/ A N/ A N7>

. N/ A N/ A N/A " N/ A N/ A N/ A '109

. N/ A N/ A N/ A N/ A IN/ A ;N/ A" IN/ A N/ A

•N/ A Recor d

Modifie d 

### E D 

# a E E E 

# n E E 

# • D

D E E D E E D E D 

# c: a n n b D 

# n E E 

# b E E E E E E E E E E E D E E E E E E E E E Dilutio n

Facto r

10 0

•'•---

- ! 5 ' 10 0

10 0

"•r" " 

### i i 

# h lib' o 1

- " 1 - " i i H " "

""5 " 5 5 l' 5

•' 5

' 1 ; i

"'" l l l

• 5 i 5 

### fs " 1 5 5 ' ' ' 1 1

' l l l Acquisitio n Dat e

1/4/201 1 5:03:5 7A M • 1/4/201 1 5:25:0 3 A M 1/4/201 1 5:46:1 6 A M 1/4/201 1 6:07:2 0 A M 1/4/201 1 6:28:2 5 A M 1/4/201 1 6:49:3 7A M 1/4/201 1 7:10:4 3 A M 1/4/201 1 7:31:5 9 A M 1 1/4/201 1 7:53:0 1 AM " 1/4/201 1 8:14:0 4A M 1 1/4/201 1 8:35:0 7A M 1/4/201 1 8:56:1 1 A M 1/4/201 1 9:17:1 8 A M 1/4/201 1 9:38:2 8 A M 1/4/201 1 9:59:2 8 A M 1/4/201 1 10:20:3 4A M 1/4/201 1 10:41:4 9 A M 1/4/201 1 11:02:5 3 A M 1/4/201 1 11:23:5 9 A M 1/4/201 1 11:45:0 5 A M 1/4/201 1 12:06:1 5 P M 1/4/201 1 12:27:2 3 P M 1/4/201 1 12:48:2 6 P M 1/4/201 1 1:09:3 2 P M 1/4/201 1 1:30:4 0 P M "1/4/201 1 1:51:4 5 "P M " i 1/4/201 1 2:12:5 2 P M '1/4/201 1 2:33:5 7P M 1 1/4/201 1 2:55:0 3 P M ] 1/4/201 1 3:16:1 0 P M 1/4/201 1 3:37:18'P M 7 1/4/201 1 3:58:2 1 P M 1 1/4/201 1 4:19:2 8 PM ' ' , 1/4/201 1 4:40:3 3 P M • 1/4/201 1 5roi:46"PM' " 1 1/4/201 1 5:22:5 2 P M "1/4/201 1 5:'44;0 3 P M 1/4/201 1 6:05:1 1 P M 1/4/201 1 6:26:1 0 P M 1/4/201 1 6:47:0 7P M 1/4/201 1 7:08:0 8 P M • 1/4/201 1 7:29:1 1 P M i 1/4/201 1 7:50:1 4P M 1/4/201 1 8:11:2 0 P M 1/4/201 1 8:32:2 9 P M 1/4/201 1 8:53:3 6 P M i 1/4/201 1 9:14:4 3 P M ' 1/4/201 1 9:35:5 0 P M 1/4/201 1 9:56:5 2 P M 1/4/201 1 10:17:5 8 P M 1/4/201 1 10:38:5 7P M 1/4/201 1 11:00:0 5 P M 1/4/201 1 11:21:1 6 P M ;

Dat a printe db yST W Printin g Time : 1:04:4 0 P M Printin g Date : Tuesday , Januar y18 , 201 1 Pag e 2 o f 7

### ** * Buste r

J293020 3 Batc hName : bll0103a.da b

10 7 10 8 10 9 11 0 11 1 11 2 11 3 11 4 11 5 11 6 11 7 11 8 11 9 12 0 12 1 12 2 12 3 12 4 125 12 6 12 7 12 8 12 9 13 0 13 1 13 2 13 3 13 4 ,13 5 13 6 13 7 13 8 13 9 140 14 1 142 143 14 4

14 5 14 6 14 7 14 8 14 9 15 0 15 1 15 2 15 3 15 4 15 5 15 6 15 7 15 8 15 9 Sampl e

Nam e bl10103310 7 b110103al0 8 bl10103310 9 b1101033l1 0 bl10103311 1 b110103a11 2 b1101033l1 3 b1101033l1 4 b110103al1 5 b110103a11 6 b1101033l1 7 b1101033l1 8 b110103sl1 9 b1101033l2 0 bll01033l2 1 b110103s12 2 bll01033l2 3 bl10103312 4 b1l01033l2 5 "bll0103al2 6 b1101033l2 7 bll0103a12 8 b1101033l2 9 bl10103313 0 b110103s13 1 b"ll0103al"3 2 •b1101033l3 3 bll0103a13 4 bl10103313 5 'bll0103a13 6 blToi03313 7 b110103"a13 8 Sampl e I D

GLPlO-01-01-11-10 2 GLPlO-01-01-11-10 3 Solven tBIsn k

(Milli Q Element ) Solven tBIsn k

(Milli Q Element ) 08008-194-1 1 Solven tBIsn k

(Milli Q Element ) GLPld-01-01-l"l-"f0 4 GLP10-01-01-11-10 5 GLP10-01-dl-1l'l"d 6 GLPlO-01-01-11-10 7 GLPl"0-dT<11-'l1-"ld 8 ' GLP1"0^1-0~1-11-11' 4 GLP10-01-01-1l"-ri5 " GLP10-01-dT-11-116 " GLPlO-01-01-11-11 7 GLPlO-01-01-11-11 8 Solven tBlan k

(Milli Q Element ) Solven tBlan k

"(MJili Q Element ) 08008-194-1 0 " Solven tBlan k

(Milli Q Element ) GLP10-01-01-11-01 1 GLPlO^l'-dl'ri^'l T' GLP10-01-01-11-01 3 GLP10-0"l'-dl'-11^ 4 GLP10-01-01-11-01 5 GCP10-0'T531-lT-d2 1 " GLP10-01-01-11-02 2 GLP10^1-"di;i'l-'d2 3' GLP10-dl7dl-Tv02 4" GLPlO-01-01-11-02 5 Solven t"Blsnk'(M"i"llTQ"Ele"ment) Solven fBIsn k

fMJiJi'Q Element ) bll0103a13 9 08008-194- 9 bl10103314 0 bl'-io'ld3'al'4' l bl10103314 2 blldl"033l4 3 bl10103314 4 bl10103314 5 b110103al4 6 bl10103314 7 bl10103314 8 bl10103314 9 bl10103315 0 bll0103sl5 1 b110103s15 2 bll01033l5 3 bll0103s15 4 b1101033l5 5 bll0103s15 6 b110103s15 7 bl10103s15 8 bll0103s15 9 Solven tBIsn k (Milli Q Element ) GLPlO-01-01-11-02 6 GLPlO-01-01-11-02 7 GLPlO-01-01-11-02 8 GLP l d-0T-O' l -"l" l -02 9 GLPld<l1-0"l- ^

1-030 GLPl'0^"l-Or i 1-04 1 GLPlO-01-01-11-04 2 GLPlO-01-01-11-04 3 GLPlO-01-01-1-1-04 4 GLPlO-01-01-11-04 5 Solven tBIsn k

(Milli Q Element ) SoTventBIsn k

(MJIIiQEIement ) 08008-194-1 2 Solven fBIsn k

(Milli Q Element ) GLPlO-01-01-11-04 6 "GLPlO-OI-dT- l 1-047 GLP10-bl-01-llk)4" 8 GLP10-01-01-11-04 9 'GL'P10-01"-01- 1 1-050 Sampl e Commen t

DALG W137 S M S 10110 9 DA LG W137 S H S 10110 9 Mill i Q Wate rTNIO-047 5 Mill i Q Wste rTNIO-047 5 1 0 ng/m LF C st d i n Mill i Q Wste r Milli Q Wste rTNIO-047 5 DALG W137L 0 10110 9 DALG W137 LOS 10110 9 DALG W137LL S 10110 9 DALG W137LM S 10110 9 DA LG W137 LH S 10110 9 " DALG W138L 0 10111 0 DALG W138LD B 10 1 no " DALG W138LL S 10111 0 DALG W138LM S 10111 0 DALG W138LH S 10111 0 Mill i Q Wste rTNIO-047 5 Mill i Q Wate rTNIO-047 5 5. 0 ng/m LF C st d i n Mill i Q Wste r

' Mill i Q Wate rTNIO-047 5 DALG W130L 0 10110 5 (di l 1:10 ) DA LG W130 LD B 10110 5 (diM:'ld ) DALG W130LL S 10110 5 (di l 1:10 ) DALG W130LM S 101-105 (di l i:ld ) DALG W130LH S 10110 5 (di l 1:10 ) DALG W131S 0 10110 3(dlfLld) " ' DALG W131 S D B 10110 3(di l 1:10 ) DALG W131 S L S 10110 3(di l 1:10 ) DA LG W131 S H S 10110 3(di l "l:Td ) " DALG W131 S M S 10110 3(di l 1:10 ) Mill i Q Wate rTN10-d47 5 Milli Q Wate rTNIO-047 5 2. 5 ng/mLF C st d i n Mill i Q Wate r" Milli Q Wate rTNIO-047 5 DA LGW'131 L0 101l"0 3(di l 1:l"d ) DALG W131LD B 10110 3(di l 1:10 ) DALG W131LL S 10110 3(di f1:10 ) DALG W131LM S 10110 3(di l 1:10 ) DALG W131LH S 10110 3(di l 1:10 ) DALG W132L 0 10110 3(di l 1:10 ) DALG W132LD B 10110 3(di l 1:10 ) DALG W132LL S 10110 3(di l 1:10 ) DA LG W132 LM S 10110 3(di l 1:10 ) DA LG W132 LH S 10il03'(di l 1:10 ) Mill i Q Wate rTN10-047 5 Mill i Q Wate rTNIO-047 5 2 5 ng/m LF C st d i n Mill i Q Wste r Mill i Q Wste rTNIO-047 5 DA LG W133 R 0 10110 2 (di l 1:10 ) DALG W133RD B 10110 2 (di l 1:10 ) DALG W133RL S 10110 2 (di l 1:10 ) DALG W133RM S 10110 2 (di l 1:10 ) DALG W133RH S 10110 2 (di l 1:10 ) Sampl e Typ e

Unknow n Unknow n Unknow n Unknow n 'Qualit yContro l Unknow n Unknow n Unknow n Unknow n lUnknow n Unknow n

. Unknow n LJnknown ijnknow n Unknow n Unknow n Unknow n Unknow n Quslit yContro l Unknow n Unknow n Unknow n Unknow n Unknow n Unknow n Unknow n Unknow n Unknow n Unknow n Unknow n Unknow n Unknow n Quslit yContro l Unknow n Unknow n Unknow n Unknow n Unknow n Unknow n Unknow n Unknow n Unknow n Unknow n Unknow n Unknow n Unknow n i Quslit yContro l Unknow n

•Unknow n

•Unknow n

•Unknow n Unknow n Unknow n Pea k

Nam e ,^^^„,^ , PFO A172566 1 PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A' PFO A PFO A PFO A PFO A PFO A PFO A" PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A 1321056 9

1012 6 622 9 1163182 5 1282 8 48072 2 48239 1 60886 0 182972 9 1292091 7 156504 6 146550 2 162821 8 283187 5 1355019 9 704 1 305 9 587865 0 566 3 865318 8 882251 4 885661 5 912424 0 " 1873919 0 67463 5 64715 3 67153 1 330168 2 91544 5 683 8 632 5 316442 8 715 2 10"856l"4 T 1139358 9 1078784 1 1182868 6 20316820 3635349 2 3695868 7 38739064 4362050 5

' 75121396 " 1534 9 1430 3 2427831 1 729 2 1290765 6 1187851 9 1237381 5 1303282 6 2167230 9 Analyt e

Retentio n Tim e (mi n 14. 8 14. 8 14. 8 14. 8 14. 8 14. 8 14. 8 14. 8 14. 8 ,14. 8 ,14. 8 14. 8 '14. 8 14. 8 14. 8 14.8 ' '14. 8 14. 8 14. 8 '14. 8 14. 8 14. 8 14. 8 14. 8 14. 8 14.7 " 14. 7 14. 7 14. 7 14. 7 ll"4. 8 14. 8 114. 8 14. 8 14;8" " " ' 14. 8 ,14.8 " 14. 8 14. 8 14. 8 !l4. 8 14. 8 14. 7 "14. 8 ,14. 8 ^14. 8 J14. 8 i14. 8 '14. 8 ;14. 8 14. 8 14. 8 14. 8 Analyt e

Concentratio n (ng/mL ) N/ A N/ A N/ A N/ A 9.9 9 N/ A N/A ' N/ A N/ A N/ A N/ A N/ A N/'A ' N/ A N/ A N/ A N/ A N/ A 5.0 0 "N7A " N/ A N/A" ' N/ A N/ A' N/ A N7 A" " N/ A "N/A N/' A N/ A ~N7 A N/ A• zFo " N/ A N/ A N/ A "N/ A N/A " N/ A N/ A "N/ A N/ A N/ A N/A" " N/ A N/A " 25. 0 N7 A N/ A N/" A N/ A N/ A N/ A Calculate d

JlT,.r M Concentratio n Recor d , , , ,

(ng/mL ) 1.32 10. 9 0.0020 8

< 0 E s^s- i 00041 3 036 0 036 1

•045 8 1.40 10. 7 1.1 9 1.1 2 1.24 2.1 8 11. 2

< 0

< 0 E "6 2

< 0 ,69. 3 70. 7 71. 0 73. 3 162

. ,25. 4 ,24. 4 125. 3 127

. 34. 6

< 0

< 0 E '2.4 4

< 0 88: 3 93. 0 87. 7 96. 9 179

. 398

. 410

. 451

. N o Intercep t 'N o Intercep t

: 0.0060 4

•0.0052 5 E |22. 2

< 0 107

. '97. 3 102

. 108

. 193

. Accurac y



## (%) N/ A N/ A N/ A N/ A 95. 2 N/ A ,N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A 92. 3 N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A '97. 6 N/ A N/ A N/ A ",N/A " N/ A N/ A IN/ A N/ A N/ A N/ A N/ A N/ A N/ A 188. 9 N/ A N/ A N/ A N/ A N/ A N/ A Recor d

Modifie d 

## E E E E D D E E E E E E E E E E E E 

## E E E E E E E E E E E E E E E 

## E E E E E E E E

~ E E E 

# b E E E E E E E E Dilutio n

Facto r

'- ]

l l 1 1 l" l '

7 i '

1 0 1 0 1 0 1 0 1 0 "'5 0

5 0 15 0 "J5 d l5 0 "ll "

' 1 

### T i

1 1 •T o 1 0 Tfd " '1 0 1 0 1 0 .1 0 1 0 * 1 0 '"id " " ' 1

, 1 1 1 1 0 11 0 1 0 1 0

" 1 0 Acquisitio n Dat e

1/4/201 1 11:42:2 6 P M 1/5/201 1 12:03:3 7A M 1/5/201 1 12:24:5 2 A M 1/5/201 1 12:46:0 1 A M 1/5/201 1 1:07:0 6 A M 1/5/201 1 1:28:1 8 A M 1/5/201 1 1:49:2 5 A M 1/5/201 1 2:10:3 4A M 1/5/201 1 2:31:4 0 A M ' 1/5/201 1 2:52:5 1 A M 1/5/201 1 3:14:0 4A M 1/5/201 1 3:35:1 8 A M 1/5/201 1 3:56:3 2 A M 1/5/201 1 4:17:4 0 A M 1/5/201 1 4:38:4 6 A M , 1/5/201 1 4:59:5 5 A M 1/5/201 1 5:21:0 5 A M 1 1/5/201 1 5:42:16A M 1/5/201 1 6:03:2 3 A M 1/5/201 1 6:24:3 6 A M 1/5/201 1 6:45:4 6 A M 1/5/201 1 7:06:5 3 A M , 1/5/201 1 7:27:5 5 A M 1/5/201 1 7:48:5 9 A M 1/5/201 1 8:10:0 6 A M 1/5/201 1 8:31:1 1 A M " : 1/5/201 1 8:52:1 5 A M ; 1/5/201 1 9:13:1 8 A M , 1/5/201 1 9:34:2 6 A M " , 1/5/201 1 9:55:3 3 A M 1

" 1/5/201 1 1ft16:33"A M ' 1/5/201 1 10:37:3 8 A M 1 1/5/201 1 10:58:5 1 A M 1/5/201 1 11:20:0 0 A M "T/5720TT11:4"T:10"A M " 1/5/201 1 12:02:1 9 P M 1/5/'201 1 "12:23:28"PM""" ^ 1/5/201 1 12:44:4 0 P" M • 11/5/201 1 1:05:4 6 P M • l/5/2dl 1 1:26:5 0 P M 1/5/201 1 1:47:5 9 P M 1/5/201 1 2:09:1 0 P M ' 1/5/201 1 2:30:1 6 P M 1 'l/5/2dl f2:51:2 3 P M 1 1/5/201 1 3:12:2 9 P M 1/5/201 1 3:33:3 8 P M 1/5/201 1 3:54:5 0 P M ; 1/5/201 1 4:15:5 7P M 1 1/5/201 1 4:37:0 9 P M 1/5/201 1 4:58:2 0 P M 1/5/201 1 5:19:2 5 P M 1 1/5/201 1 5:40:3 2 P M 175/20 1 i 6:01:4 5 P M



### Dat aprinte db yST

W Printin gTime : 1:04:4 0P M Printin gDate : Tuesday , Januar y18 , 201 1 Pag e3 o f 7Buste r J293020 3 Batc hName : bll0103a.da b

16 0 16 1 16 2 16 3 16 4 16 5 16 6 16 7 16 8 16 9 17 0 17 1 17 2 17 3 17 4 17 5 17 6 17 7 17 8 17 9 18 0 18 1 18 2 18 3 18 4 18 5 18 6 18 7 18 8 18 9 19 0 19 1 19 2 19 3 19 4 19 5 19 6 19 7 19 8 19 9 20 0 20 1 20 2 20 3 20 4 20 5 20 6 20 7 20 8 20 9 21 0 21 1 21 2 

## %z' : «-p'«'=>

b110103a16 0 GLPlO-01-01-11-05 1 b110103a16 1 GLP10O1-01-11-05 2 b l 10103316 2 GLPlO-01-01-11-05 3 b l 10103316 3 GLPlO-01-01-11-05 4 b l 10103316 4GLPlO-01-01-11-05 5 b110103316 5 Solven tBIsn k (Milli Q Element ) b l 10103316 6 Solven tBIsn k (Milli Q Element ) b110103s16 708008-194-1 1 b l 10103316 8 Solven tBlan k (Milli Q Element ) b110103al6 9 GLPlO-01-01-11-05 6 b110103a17 0 GLP10-01-01-11-05 7 b110103s17 1 GLPlO-01-01-11-05 8 bl101033l7 2 GLP'lO-dl-Ol-11-05 9 b110103s17 3 GLPlO-01-01-11-06 0 b110103s17 4GLPlO-01-01-11-07 0 bl10103a17 5 GLPlO-01-01-11-07 1 b110103a17 6 GLPlO-01-01-11-07 2 b110103a17 7GLPlO-01-01-11-07 3 b110103s17 8 GLPlO-01-01-11-07 4 b110"l033l7 9 Solven tBlan k (MilliQ'Element ) b1101033l8 0 Solven tBIsn k (Milli Q Element ) b l 10103318 1 08008-194-1 0 b l 10103318 2 Solven tBIsn k (Milli Q Element ) 'b1ldl03al8 3 GLPlO-01-01-11-08 9 b1101033l8 4GLPlO-01-01-11-09 0 b1101033l8 5 GLPlO-01-01-11-09 1 b110103s18 6 GLP10-01-01-11-09 2 b1101033l8 7GLPlO-01-01-11-09 3 bl10103s18 8 GLPlO-01-01-11^9 4 bll0103al8 9 GLPlO-01-01-11-09 5 bl10103aT9 0 GLPIO-01-OT- l 1-09 6 b110103s19 TGLPlO-01-01-11-09 7 "b l Tdld3a'l9 2 GLPlO-dT-01- 1 l"-d9 8 b110103a19 3 Solven tBIsn k (Milli Q Element ) bTl'01033l9 4SoTvefi fBlan k (Miiii Q Element ) b110103s19 5 08008-194- 9 "bildld3al"96 " S"olve'n fBfan k (Milfi Q Efemen fj b110103a197'GLPld-01-01-11-10 9 b1101033l9 8 GLP10-01-01-11-11 0 b110103aT9" 9 GLP'ld-dl-01-11-11 1 b l 101033200'GLPIO-OI-OI- l 1-11 2 b l 10103320 1 GLPlO-01-01-11-11 3 b11010332'0 2 GLP10-01-01-11-11 9 biidid'3'320 3 G'L'pid.oT-oi-ii;i'2d ' Ib110103s20 4GLPlO-01-01-11-12 1 b110103s2d 5 GLP10-01-01-11-12 2 bl10103s20 6 GLPlO-01-01-11-12 3 b110103s20 7Solven tBIsn k (Milli Q Eleme'nt j b110103s20 8 Solven tBIsn k (Milli Q Element ) b110103a20 9 08008-194-1 2 b110103s21 0 Solven tBIsn k (Milli Q Element ) b110103s21 1 GLPlO-01-01-11-12 4 bli0103a21 2 GLPlO-01-01-11-12 5 Sampl e Commen t

DALG W133 S 0 10110 3 (di l 1:10 ) DALG W133 S D B 10110 3 (di l 1:10 ) DALG W133 S L S 10110 3 (di l 1:10 ) DA LG W133 S M S 10110 3 (di l 1:10 ) DALG W133 S H S 10110 3 (di l 1:10 ) Mill i Q Wste rTNIO-047 5 Milli Q Wate rTNIO-047 5 1 0 ng/m LF C st d i n Mill i Q Wate r Mill i Q Wste rTNIO-047 5 DA LG W133 L0 10110 3 (di l 1:10 ) DA LG W133 LD B 10110 3 (di l 1:10 ) DALG W133LL S 10110 3 (di l 1:10 ) DA LG W133 LM S 10110 3 (d'i i 1:10) " DA LG WT33 LH S 101l"0 3 (di l 1T1O') " " DALG W134L 0 10110 5 (di l 1:10 ) DALG W134LD B 10110 5 (di l 1:10 ) DALG W134LL S 10110 5 (di l 1:10 ) D A LG W134 LM S 10110 5 (di l 1:10 ) DALG W134LH S 10110 5 (di l 1:10 ) Milli Q Wste rTNIO-047 5 Mill i Q Wste rTNIO-047 5 5. 0 ng/m LF C st d i n Mill i Q Wste r Milli Q Wate rTNIO-047 5 DALG W136S 0 101103 " (di l 1:10 ) DA LG W136 S D B 10110 3 (di l 1:10 ) DA LG W136 S L S 10110 3 (di l 1:10) " DA LG W136 S M S 10110 3 (di l 1:10 ) DA LG W136 S H S 10110 3 (di l 1:10 ) DA LG W136 Ld ' 10 1 T03"(di T1 :"ld ) " DALG W136LD B 10110 3 (di l 1:10 ) DA' LG W136 LL S 10Tld 3 (df l 1:10 ) DALG W136LM S 10110 3 (di l 1:10 ) D A LG"w"l3"6L"HS"l01103"(cli l l":10")" " Mill i Q Wate rTNIO-047 5 Mill i Q Wafe rTNIO-047 5 2. 5 ng/m LF C st d i n Mill i Q Wste r Milli Q Wste rTNldJ347"5 " D A LG W138 S 0 10111 0 (diri:10 ) DA LG W138 S D B 10111 0 (di l 1:10 ) DALG W138 S L S 10111 0 (di l 1:10) ' DALG W138 S M S 10111 0 (di l 1:10 ) DALG W138 S H S 10111 0 (diri:10 ) DALG WCW26R 0 10111 0 (di l 1:10 ) DA LG WCW26R'b B l"oil10'(di l iT'lo T DA LG WCW26 R L S 10111 0 (di l 1:10 ) DA LG WCW26 R MS"l011l" 0 ('diri:10 ) DA LG WCW26 R H S 10111 0 (di l 1:10 ) Milli Q Wste rTNIO-047 5 Mill i Q Wste rTNIO-047 5 ' 2 5 ng/m LF C st d i n Mill i QWate r" Mill i Q Wste rTNIO-047 5 DALG WCW26L 0 10111 0 (di l 1:10 ) 'DALGWCW26LD B 10111 0 (di f1:10 ) Sampi e Typ e

Unknow n Unknow n Unknow n Unknow n Unknow n Unknow n Unknow n Qualit yContro l Unknow n 'Unknow n Unknow n Unknow n Unknow n Unknow n 1 Unknow n Unknow n Unknow n Unknow n Unknow n Unknow n Unknow n Quslit yContnD l Unknow n Unknow n Unknow n Unknow n Unknow n 'Unknow n Unknow n Unknow n 1Onknow n 'Unknow n 1 Unknow n i Unknow n Unknow n 1 Quslit yContro l i Unknow n Unknow n 'unknow n Unknow n Unknow n 1 Unknow n •Unknow n Unknow n j Unknow n 1 Unknow n ]Unknow n {unknow n j Unknow n iQualit yContro l 1 Unknow n i Unknow n lUnknow n 

# ~;ff».r:5

-

PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFOA " PFO A PTOA " PFOA " PFO A PFO A P'FO A PFO A PFO A

'PF"O A PFO A PFO A PFO A

. PFO A PFO A PFO A PFO A PFO A PFO A PFO A P"FO/ \ PFO A "PFO A PFO A PTOA " " PFO A PFOA " PFO A PFO A PFO A PFO A PFO A PFO A PTOA " PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A 975274 7

936527 5 1006691 5 1184162 0 2671837 9 1726 6 1276 5 1121448 1 1120 4 641179 5 634107 4 670691 4 884625 5 2567621 1 4704914 7 4633194 8 4644761 7 5100197 0 8120158 8

' l"474l " 998 8 563199 8 1131 4 919317 0 953613 7 963064 9 1060426 4 1911711 0 193970 9 199870 1 22'5131 1 433740 1 2288302 7 980 4 58'3' l 309719 8 loTsd " 385349 0 371137 0 418450 1 585939 7 2266208 6 949633 1 964425 5 978613 5 "1105744 1 2720035 3 1371 8 799 5 2401872 3 860 0 1361588 1 1303302 0 Analyt e

Retentio n Tim e (mi n •14. 7 14. 7 14. 7 14. 7 14. 7 14. 8 14. 8 14. 8 14. 8 14. 7 14. 7 14. 7 14. 7 14. 7 14. 8 14. 8 14. 8 14. 8 14. 8 l'4l 8 14. 8 14. 8 14. 8 14. 8 14. 8 14. 8 14. 8 14. 8 14. 7 14. 7 14l 7 :14. 7 14. 7 14. 8 14. 8 14. 8 14. 8 14. 7 14. 7 '14. 7 14. 7 14. 7 14. 7 IT4. 7 114. 7 114. 7 ;i4. 7 .14. 8 14. 8 114. 7 14. 7 14. 7 714. 7 Analyt e

Concentratio n (ng/mL ) N/ A N/ A N/ A N/ A N/ A N/ A N/ A 9.9 9 N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A 5.0 0 N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A 'N/ A 2.5 0 N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/A " N/ A N/ A N/ A N/ A N/ A 25. 0 N/ A N/ A N/ A Calculate d

ReSr d concentratio n

(ng/mL ) 393

. 377

. 407

. 485

. 126 0 0.0075 0 0.0040 8 E 9.1 5 0.0029 0 253

. 250

. 265

. 355

. 1190

. N o Intercep t N o Intercep t N o Intercep t N o Intercep t N o Intercep t d

. 0055 8 0.0019 8 

### E ''.42 0.0029 8 73. 9 76. 8 77. 6 ,86. 1 166

. 74. 1 76. 4 !86. 2 1169

. 11030

. 100018 4 

# ? ° E 12.3 9 'O.bo'20 9 T49

. 1144

. l"62

. '23 0 •1020

. 1382

. |389

. 1395

. 450

. 1290

. 0.0048 1 {0,00046 7

' E i21 9 1 10.00092 6 1 1565

.

'539

. Accurac y



## (%)

N/ A N/ A N/ A N/ A N/ A N/ A N/ A 91. 5 N/ A N/ A N/ A N/ A N/ A ,N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A 88. 3 N/ A N/ A N/ A N/ A 'N/ A 'N/ A N/A " N/ A

":N/ A N/ A N/ A N/ A N/ A ,95. 5 jN/ A [N/ A IN/ A !N/ A JN/ A JN/ A IN/ A IN/ A N/ A N/ A N/ A |N/ A ]N/A ;87. 7 iN/ A N/ A N/ A Recor d

Modifie d 

### E E E E E E 

# b E E E E E E E E E E E E E E E E E E E E E E E E E E E E 

# n E E E E E E E E E E E 

# b E 

# b E E E Dilutio n

Facto r

5 0 5 0 5 0 5 0 5 0 1 1 1 1 5 0 5 0 5 0 5 0 5 0 1 0 1 0 1 0 1 0 1 0 1 1 1 1 1 0 1 0 i d " 1 0 1 0 5 0 5 0 5 0 " 5 0 5 0 " 1 1 ^ " 1 1 5 0 5 0 5 0 5 0 5 0 5 0 5 0 " 5 0 5 0 5 0 1 1 1 1 5 0 5 0 Acquisitio n Dat e

1/5/201 1 6:22:5 1 P M 1/5/201 1 6:43:5 9 P M • 1/5/201 1 7:05:0 1 P M 1/5/201 1 7:26:0 2 P M 1/5/201 1 7:47:0 2 P M 1/5/201 1 8:08:0 7P M 1/5/201 1 8:29:1 5 P M 1/5/20l f8:50:2 2 P M , 1/5/201 1 9:'T1:29PM " 1/5/201 1 9:32:3 7P M 1/5/201 1 9:53:4 8 P M " ; 1/5/201 1 10:14:5 3 P M •i/5/201 1 10:35:55"P' M " , 1/5/201 1 ld:56:57PM"' l 1/5/201 1 11:17:5 6 P M 1/5/201 1 11:39^0 0 PM ' 1/6/201 1 12:00:1 1 A M 1/6/201 1 12:21:15'A M " 1/6/201 1 12:42:2 6 A M 1/6/2011 1 :d3":3 4AM " ~ ' 1/6/201 1 1:24:45A M l/6/201' l 1:45"5 5 AM " ' 1 1/6/201 1 2:07:0 9 A M 1/6/201 1 2:28:2 1 AM " 7 1/6/201 1 2:49:3 5 A M 1/6/201 1 "3"10":42"AM ' " 1/6/201 1 3:31:5 2 A M | 1/6/201 1 3:53:0 9 A M ' 1/6/201 1 4:14:T' 5 AM " " ; 1/6/201 1 4:35:2 3 A M 7 1/6/20"l"l"4:5673 0 AM""~ 1 1/6/201 1 5:17:3 4A M 1/"67"2dir5"38738AM'"' l 1/6/201 1 5:59:4 6 A M

" 1/6/201 1 6:2d : 55 " A'M ^ 1 1/6/201 1 6:42:0 2 A M ' 1/6/20"Tr7":d3:13"AM " " • 1/6/201 1 7:27:5 4A M | 1/6/201 1 7:49:0 7A M ' 1/6/20l"T8:l"d:"l 2 A M " 1 1/6/201 1 8:31:2 0 A M ' 1/6/201 1 8:52:2 1 A M j 1/6/201 1 9:13:2 1 A M 1 1/6/201 1 9;34:23"A"M"" 1 1/6/201 1 9:55:3 1 A M ' ] 1/6/201 1 10:16:3 7A M [ 1/6/201 1 10:37:3 7A M i "1/6/201 1 I'0:'5'8:43"AM " [ 1/6/201 1 11:19:50A M | 1/6/201 1 11:40:5 7A" M ' 1 1/6/201 1 12:02:0 4P M j 1/6/201 1 12:23:1 6 P M 1 l/6/2dl 1 12:44:2 4P M i

Dat a printe db yST W Printin g Time : 1:04:4 0 P M Printin g Date : Tuesday , Januar y1 6 Pag e 4 o f 7

201 1

### Buste r

J293020 3 Batc hName : bllOlOSa.da b

21 3 21 4 21 5 21 6 21 7 21 8 21 9 22 0 22 1 22 2 22 3 22 4 22 5 22 6 22 7 22 8 22 9 23 0 23 1 23 2 23 3 23 4 23 5 23 6 23 7 23 8 23 9 24 0 24 1 24 2 24 3 24 4 24 5 24 6 24 7 24 8 24 9 25 0 25 1 25 2 25 3 25 4 25 5 25 6 25 7 25 8 25 9 26 0 26 1 26 2 26 3 26 4 26 5 'uT^ e sampl e , D

b l 10103321 3 GLPlO-01-01-11-12 6 b l 10103321 4GLPlO-01-01-11-12 7 bll0103a21 5 GLPlO-01-01-11-12 8 b110103a21 6 GLPlO-01-01-11-12 9 b l 10103321 7GLPlO-01-01-11-13 0 b1l0103321 8 GLP10-01-01-11-13 1 b110103s21 9 GLP10-01-01-11-13 2 b l 10103322 0 GLPlO-01-01-11-13 3 b110"l~03s"22 1 Solven tBIsn k (Milli Q Elemen7 ) b110103s22 2 Solven tBIsn k (Milli Q Element ) b110l"d3"s22 3 08008-194-1 0 b110103a22 4Solven tBIsn k (Milli Q Element ) b110103a22 5 GLPlO-01-01-11-13 4 b110ld3a22 6 GLP10-01-01-11-13 5 b110103322 7GLPlO-01-01-11-13 6 b1l0l0'3s22 8 GLPlO-01-01-11-13 7 bll0103"322 9 GLPlO-01-01-11-13 8 blldld'3'a23 0 GLPlO-01-01-11-13 9 b l 10103323 1 GLPlO-01-01-11-14 0 b l 10103323 2 GLPlO-01-01-11-14 1 b l 10103323 3 GLPlO-01-01-11-14 2 blTdld3a234'GLPlO-01-01-11--J4 3 b l 10103323 5 Solven tBlan k (Milli Q Element ) b110l'03s23" 6 Solven tBIsn k (Milli Q Efemenf ) b l 10103323 708008-194-1 1 b110103a23 8 Solven tBIsn k (Milli Q E'lement ) b l 10103323 9 GLPlO-01-01-11-14 4 b110103a24 0 GLPlO-01-01-11-14 5 b110W3a24 1 GLPlO-01-01-11-14 6 b110l03s24 2 GLPlO-01-01-11-14 7 b110l"03s24 3 GLP10-01-01-11-14 8 b1l6l03324 4GLPlO-01-01-11-00 1

. " bll0ld3324 5 GLP10-d"l-dl-11^d 2 bll0103324 6 GL P 10-01-01-11-00 3 bll0103s24 7GLPl0-01-dl-11-0"d 4 bll0103s24 8 GLP10-01-01-11-00 5 b l 10103324 9 Solven tBlan k (Milli Q Element ) b110l"d3s25 0 Sol\en tBlan k (Milli Q Elernent ) bl10103a25 1 08008-194-1 2 b110'l0"3a25 2 Solven tBlan k (Miiii Q Eiement ) b110103a25 3 GLPlO-01-01-11-00 6 b1l'0103a25 4GLPlO-01-01-11-00 7 :b110103a25 5 GLPlO-01-01-11-00 8 'b"l1CilO"3a25" 6 GL P 10-01-01-11-00 9 b110T03a25" 7GLPlO-01-01-11-01 0 b110103'325 8 Solven tBlan k (Milli Q Elefnent ) b l 10103325 9 Solven tBlan k (Milli Q Element ) blldl03326 0 08008-194-1 0 bll0103a26 1 Solven tBIsn k (Milli Q Element ) b110103s26 2 GLP10-01-01-11.01 7 bll0103a26 3 GLP10-01-01-11-01 8 b l 10103326 4GLPlO-01-01-11-01 9 b1ldl03s26 5 GLPlO-01-01-11-02 0 Sampl e Commen t

DA LG WCW26 LL S 10111 0 (di l 1:10 ) DA LG WCW26 LM S 10111 0 (di l 1:10 ) DALG WCW26LH S 10111 0 (di l 1:10 ) DALG W140R 0 10110 4(di l 1:10 ) DA LG W140 R D B 10110 4(di l 1:10 ) DALG W140RL S 10110 4(di l 1:10 ) DA LG W140 R M S 10110. 4(di l 1:10 ) DALG W140 R H S 10110 4(di l 1:10 ) Miiii Q Wate rTNIO-047 5 Milli Q Wate rTNIO-047 5 5 0 ng/m LF C st d i n Mill i Q \(Vate r Mill i Q Wste rTN10-047 5 DALG W141R 0 10111 0 (di l 1:10 ) DALG W141RD B 10111 0 (di l i;10 ) DALG W141RL S 10111 0 (di l 1:10 ) DALG W141RM S 10111 0 (di l 1:10 ) DALG W141 R H S 10111 0 (di l 1:10 ) DALG W142R 0 10111 0 (di l 1:10 ) DALG W142RD B 10111 0 (di l 1:10 ) 'DALG W142RL S 1011ld(di l 1:10 ) DALG W142RM S 10111 0 (di l 1:10 ) DALG W142RH S 10111 0 (di l 1:10 ) Mill i Q Wste rTNIO-047 5 Milli Q Wste rTNIO-047 5 1 0 ng/m LF C st d i n Mill i Q Wste r Mill i QWate rTNIO-0475 " DALG W144R 0 10111 0 (di l 1:10 ) DALG W144RD B 10111 0 (di l 1:10 ) DA LG W144 R L S lOlll' O (di l 1:10 ) DALG W144RM S 10111 0 (di l 1:10 ) DA LG W144 R H S 10111 0 ("di l 1:10 ) DA LG W130 R 0 10110 5 (di l 1:100 )

' DA LG Wi 30 R D B 10" l l"05'(diri : 100 ) DALG W130RL S 10110 5 (di l 1:100 ) 'i5ALGW'l30RM S 10110 5 (di l 1:10d ) DA LG W130 R H S 10110 5 (di l 1:100 ) Mill i Q'WaterTNld"-d4"7 5 " ' Mill i Q Wate rTNIO-047 5 2 5 ng/m LF C st d i n Mill i Q Wate r Milli Q Wate rTNIO-0475

. ioALG W130S 0 10110 5 (di l 1:100 ) DA LG W130 S D B 10110 5 (di l 1:100 ) DA LG W130 S L S 10110 5 (di l 1:100 ) DA LG W130 S M S lOll'd S (di l 1:100 ) DALG W130 S H S 10110 5 (di l 1:100 ) Mill i Q Wate r•nMIO-047 5 Milli Q Wate rTNIO-047 5 5. 0 ng/m LF C st d i n Miil i Q Wate r Mill i Q Wate rTNIO-047 5 DALG W131R 0 10110 3 (di l 1:100 ) DALG W131RD B 10110 3 (di l 1:100 ) DALG W131RL S 10110 3 (di l 1:100 ) DALG W131RH S 10il03(di l 1:100 ) Sampl e Typ e

Unknow n Unknow n Unknow n Unknow n Unknow n Unknow n Unknow n Unknow n Unknow n Unknow n Qualit yContro f Unknow n Unknow n Unknow n Unknow n Unknow n Unknow n Unknow n Unknow n Unknow n Unknow n Unknow n Unknow n Unknow n Qualit yContro l Unknow n Unknow n Unknow n Unknow n Unknow n Unknow n Unknow n Unknow n Unknow n Unknow n Unknow n Unknow n Unknow n Qualit yContro l Unknow n Unknow n Unknow n Unknow n Unknow n Unknow n Unknow n Unknow n Quslit yContro l Unknow n Unknow n Unknow n Unknow n Unknow n Analyt e

,PFO A PFO A PFO A PFO A PFO A PFO A PFO A IPFO A PFO A PFO A IPFO A PFO A PFO A PFO A PFO A PFO A ,PFO A PFO A PFO A iPFO A IPFO A jPFO A PFO A >FO A i P'FO A ''PFO A PFO A PFO A '"P'FO A iPFO A I'PFO A IPFO A "tpF'OA" IPFO A iPFO A PFO A 'PFO A PFO A PFO A PFO A PFO A ,PFO A [PFO A IPFO A 'PFO A PFO A PFO A "PFO A PFO A PFO A PFO A PFO A iPFO A 1333217 4

1484882 7 3010841 6 313711 8 310804 2 331659 6 553472 0 2181270 3 1876 3 1482 2 533925 2 1318 3 4182 5 3690 7 28511 9 248840 1 2058522 1 122528 1 128106 5 145280 0 370006 8 2092320 5 1428 0 1118 6 1078520 0 13250 ' 150130 3 150544 5 177197 4 365926 5 2167190 9 977234 7 985'312d' " 996410 0 1098826 5 1931794 3 1303 3 848 1 2368564 9 998 9 227179 4 225684 9 238805 9 349924 6 1386569 7 928 5 809 6 548001 5 1133 9 2675482 8 2647257 3 2714069 0 3202972 1 Analyt e

Retentio n Tim e (mi n 14. 7 14. 7 14. 7 14. 7 14. 7 14. 7 14. 7 14. 7 14. 7 14. 7 '14. 8 " 14. 7 14. 7 14. 7 14. 7 14. 7 14. 7 14. 7 14. 7 14. 7 14. 7 '14.7""" " 14. 8 l"4"."7 ' " 14. 8 14. 8 14. 7 14. 7 14. 7 14.7 " "14. 7 14. 8 14. 8 14. 8 14: 8 14. 8 147 8 14. 7 14. 8 Il4."8 " .14. 8 14. 8 114. 8 114.8 " 14. 8 14^8 " " 14. 8 14. 8 14. 8 14. 8 " " 14. 8 14. 8 ;14. 8 A"aly* « Us e

Concentratio n „

, ,„ , VRecor d (ng/mL ) N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A 5.0 0 ' E " N/ A

" N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A" ' N/ A N/A ' ~ ' N/ A N/ A 9.9 9 E N/A ' N/ A N/ A N/ A N/ A

" N/ A' • N/ A1 "TT/A " ' ' N/ A "N/ A' " N/ A N/ A N/ A 25. 0 K N/ A N/ A N/ A N/ A; N/ A

. ' N/ A N/ A N/ A 5.0 0 K N/ A N/ A N/ A N/ A

. N/ A Calculate d Concentratio n (ng/mL ) 552

. 623

. 1480

. 121

. 1 2 a 128

. 217

. 973

. 00086 3 0.0056 4 4,1 8 0.0044 0 1.3 1 1.1 2 10. 5 95. 5 908

. 46. 5 48. 7 55:3 " 143

. 925

. 0.0052 3 070028 9 8.7 7 0.0044 5 57. 2 57. 3 67. 6 142

. 966

. 789

. 796. " 805

. 89"5"

. " " 1680

. 'd70042 9 0.00083 6 21. 5 0.0019 8 174

. 173

. 183

. 270

. 1150

. 0.0014 4 0.00054 3 4.2 9 0.0030 0 2520

. 2480

. 2570

. 3240. " Accurac y



## (%)

|N/ A N/ A

IN/ A N/ A N/ A N/ A N/ A

•N/ A N/ A ,N/ A 83.6 " N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A >/A " N/ A N/ A N/ A N/ A 87. 8 N/ A N/ A iN/ A N/ A N/ A

' NT A N/ A iN/ A N/ A 'IN/ A N/ A N/A ' N/ A' 86. 2 'N/ A IN/ A iN/ A JN/ A IN/ A IN/ A N/ A N/ A 85. 9 " N/ A

I'N/ A 'N/ A IN/ A jN/ A Recor d

Modifie d E E E E E E E E E E 

# b E E E E E E E 

### E E E E E E 

# n E E E E E E 

### E E E E 

### E E E D E E E E E E E E E E E E E E Dilutio n

Facto r

5 0 5 0 5 0 5 0 5 0 5 0 5 0 I5 0 1 1 | l 1 1 ,5 0 15 0 5 0 5 0 5 0 5 0 5 0 5 0 5 0 15 0

' 1 1

' 1 1 5 0 5 0 5 0 _^5 0

^ 0 |10 0 ;"i"d" o 10 0 '10 0 110 0



### ' i

' 1 1 1

' 1 ,w o llO O '10 0 110 0 10 0 1 1

, 1 1 10 0 I10 0 10 0 ilO O Acquisitio n Dat e

1/6/201 1 1:05:2 6 P M 1/6/201 1 1:26:2 9 P M 1/6/201 1 1:47:2 7 P M 1/6/201 1 2:08:3 4P M 1/6/201 1 2:29:3 8 P M 1/6/201 1 2:50:4 0 P M 1/6720li"'3?l'l:47P M 1/6/201 1 3:32:4 8 P M l/6/20ir3T53:5 5 P M 1/6/201 1 4:15:0 1 P M 1/6/20ir4:3"6:Tl'P M 1/6/201 1 4:57:2 1 P M 1/6/20115:18:2 9 P M 1/6/201 1 5:39:3 2 P M 1/6/201 1 6:00:3 1 P M 1/6/201 1 6:21:3 7P M 1/6/201 1 6:42:4 1 P M 'l/6"/2dfW:03:4 3 P M 1/6/201 1 7:24:4 6 P M 1/6/201 1 7:45:5 0 P M 1/6/201 1 8:06:5 7P M 1/6/201 1 8:27:5 9 P M 1/6/201 1 8:49:0 4P M l/'6/2dll'97l'0Tl6'P M 1/6/201 1 9:31:2 4P M

' l/6/2'01l'9r5'273 4P M 1/6/201 1 ldl3:4 3 P M l/6/2dl l ld:34?5 2 F= M ' I/6/20I 1 l0T55:"5 2 P M 1/6/201 1 11:16:5 5 P M

* T/672dlT7lT37:55" P M l76/20l'l'l"l':5"8:"55P M 1/7/201 1 12:20:0 4A M | 1/7/201 1 12:41:1 1 A M 1/7/201 1 1:02:2 1 A M 1/7/201 1 1:23:2 7 A M T/772dlT"l744r33"A M 1/7/20l" l 2705:4 2 A M 1/7/201 1 2:26:4 9 A M 1 1/7/201 1 274'7r5' 7A' M I/7/2OI I 3:09:0 8 A M j 1/7/201 1 3:301 8 A M i 1/7/20ir3:5'l:24'A M I 1/7/201 1 4:12:3 3 A M ' 1/7/201 1 4:33:"4 6 A M 1/7/201 1 4:'54:5 1 A M 1/7/201 1 5:16:0 2 A M 1/7/201 1 5^37:15 " A M 1/7/201 1 5:58:2 6 A M 1/7/201 1 "6:19:3 7AM " • 1/7/201 1 6:4d:4 8 A M \ I/7/2OI I 7:01:5 7A M j 11/7/201 1 7:23:0 4A M '



### Dat aprinte db yST

W Printin gTime : 1:04:4 0P M Printin gDate : Tuesday , Januar y18 , 201 1 Pag e5 o f 7•* * Buste r J293020 3 Batc hName : bll0103a.da b

26 6 26 7 26 8 26 9 27 0 27 1 27 2 27 3 27 4 27 5 27 6 27 7 27 8 27 9 28 0 28 1 28 2 28 3 28 4 28 5 28 6 •28 7 28 8 28 9 29 0 29 1 29 2 29 3 29 4 29 5 29 6 29 7 29 8 29 9 30 0 30 1 30 2 30 3 30 4 30 5 30 6 30 7 30 8 30 9 31 0 31 1 31 2 31 3 31 4 31 5 31 6 31 7 31 8 %Z' : sampl e I D

b l 10103326 6 Solven tBlan k (Milli Q Element ) b l 10103326 7GLPlO-01-01-11-03 1 b l 10103326 8 GLPlO-01-01-11-03 2 b110103a26 9 GLPlO-01-01-11-03 3 b l 10103327 0 GLPlO-01-01-11-03 4 b l 10103327 1 GLPlO-01-01-11-03 5 b110103a27 2 Solven tBlan k (Milli Q Element ) bl10103a27 3 Solven tBIsn k (Milli Q Element ) b110103s27" 408008-194-1 1 b110103a27 5 Solven tBlan k (Milli Q Element ) bl10103a27 6 GLPlO-01-01-11-03 6 b110103s27 7GLP10-01-01-11-03 7 b l 10103327 8 "G'LPIO-01-01- 1 1-03 8

•bll0103s279 " GLPlO-01-01-11-039 " b l 10103328 0 GLP10-01-01-11-04 0 b110"l03a28 1 "Solven tBlan k (Milli Q Element ) b110103s28 2 Solven tBIsn k (Milli Q Element ) b110ld3328 3 08008-194-1 2 b l 10103328 4Solven tBIsn k (Milli Q Element ) b l 10l"03s28 5 "G'CPIO-OIJOI- I 1-06 1 b110103s28 6 GLPlO-01-01-11-06 2 b110103"s28 77GLP10-O1-Ol-11-06 3 b l 10103328 8 'GLPIO-OI-OI- I 1-06 4 b1ld"l'03s2a9""Solven tBIsn k (Miiii Q Eleme"nt ) b110103s29 d GLP10-01-01-11-07 5 bll"010332¥l'73lP10-01-01-11-d76 " bl10103s29 2 GLPlO-01-01-11-07 7 b110103s293""G'LP10-01-01- l 1-07 8 bl10103s29 4Solven tBIsn k (Miiii Q Element ) b110103a29' 5 Solven tBlan k (Milli Q Eiement ) bll0103a29 6 08008-194-1 0 b110103a29" 7Solven tBlan k (Milli Q Element ) b l 10103329 8 GLPlO-01-01-11-08 4 b l 10103329 9 GLPlO-01-01-11-08 5 b l ldl0333"dd""GLPld".Ol"-01-11-08 6 b1l0l03s30 1 GLPlO-01-01-11-08 7 b110l03s30 2 GLPlO-01-01-11-08 8 b l 101033303,Solven tBIsn k (MiiliQ"Efefne"nt ) b110103330 4'Solven tBlan k (Milli Q Element ) 1 b l 10l0333"d5 " 0"8'008-"l'94-1 1 ibl10103s3d 6 Solven tBlan k (Milli Q Eiement ) b110103b30 7GLPlO-01-01-11-04 4 b110103b3d 8 GLP10-01-01-11-04 5 b11010"3b3d 9 S'olven tBlan k (Milli Q Element ) b110103b31 0 GLPlO-01-01-11-07 0 "b110103b31 1 GLPlO-01-01-11-07 1 " • b110103b31 2 GLPlO-01-01-11-07 2 b110103b3l73'GLPlO-01-01-11-073 " b110103b31 4GLPlO-Ol-Ol- l 1-07 4 b110103b315 ' Solven tBlan k (Milli Q Element ) b110103b31 6 Solven tBlan k (Milli Q Element ) bl10103b31 708008-194-1 0 bl10103b31 8 Solven tBlan k (Milli Q Element ) Sampl e Commen t

Mill i Q Wste rTNIO-047 5 DALG W132R 0 10110 2 (di l 1:100 ) DALG W132Rb B 10110 2 (di l 1:100 ) DALG W132RL S 10110 2 (di | 1:100 ) DALG W132 R M S 10110 2 (di l 1:100 ) DALG W132RH S 10110 2 (di l 1:100 ) Mill i Q Wate rfNlO-047 5 Milli Q Wate rTNIO-047 5 1 0 ng/m LF C st d i n Mill i Q Wste r Mill i Q Wate rTNIO-047 5 DALG W132S 0 10110 2 (di l 1:100 ) DALG W132 S D B 10110 2 (di l 1:100 ) DA LG W132 S L" S 10110 2 (di l 1:100 ) " DA LG W132 S M S 10110 2 (di l 1:ldO ) DA LG W132 S H S 10110 2 (di l 1:100 ) Mill i Q Wate rTNIO-047 5 Mill i QWate rTNIO-047 5 2 5 ng/m LF C st d i n Mill i Q Wate r Mill i Q Wate rTNIO-047 5 DA LG Wl"34Rd"l0110 5 (di l 1:100 ) DALG W134RD B 10110 5 (di l 1:100 ) DALG W134RL S 10110 5 (di l 1:100) ' DALG W134RH S 10110 5 (di l 1:100 ) Mill i Q Water"TMl0-047 5 DALG W135 R 0 10110 5 (di l 1:100 ) DA LG W135'R'DB"I"0110 5 (di l 1:100 ) DALG W135RL S 10110 5 (di l 1:100 ) DA LG W135 R H S 10110 5 (di l 1:100 ) Mill i Q Wate rTNIO-047 5 Milli Q Wste rTNIO-047 5 '5. 0 ng/m LF C sTd""i n Mill i QWate r Milli Q Wate rTNIO-047 5 DA LG Wl35 L0"l"Ol10" 5 (di l 1:100 ) DALG W135LD B 10110 5 (di l 1:100 ) DA LG W135 LL' S 10110 5 (di l 1:100 ) D A LG W135 LM S 10110 5 (di l 1:100 ) ' "DA LG Wl35 LH S 10110 5 (di l 1:100) " Mill i Q Wate rTN'10^47 5 Mill i QWate rTNIO-047 5 1 0 ng/m LF C st d i n Mill i Q Wste r Mill i Q Wate rTNl0-047 5 'DALG W132LM S 10110 3 (di l 1:10 ) DALG W132LH S 10110 3 (di l 1:10 ) Mill i Q Wate rTNIO-047 5 DALG W134L 0 10110 5 (di l 1:10 ) DA LG W134 LD B 10110 5 (di l 1:10 ) DALG W134LL S 10110 5 (di l 1:10 ) DA LG W134LM S 10110 5 (di l 1:10 ) DALG W134LH S 10110 5 (di l 1:10 ) Mill i Q Wate rTNIO-047 5 Mill i QWate rTNIO-047 5 5. 0 ng/m LF C st d i n Mill i Q Wste r Mill i Q Wste rTNIO-047 5 Sampi e Typ e

Unknow n Unknow n Unknow n Unknow n Unknow n

, Unknow n Unknow n Unknow n Quslit yContro l Unknow n Unknow n Unknow n 1 Unknow n

' Unknow n lUnknow n

•Unknow n Unknow n Quslit yContro l Unknow n Unknow n Unknow n I Unknow n 1 Unknow n Unknow n Unknow n Unknow n Unknow n Unknow n LJnknow n Unknow n '^Qualit yContro l lUnknow n 1 Unknow n Unknow n tjnknow n 'Unknow n Unknow n Unknow n lUnknow n iQuslit yContro l 1 Unknow n Unknow n Unknow n Unknow n Unknow n Unknow n Unknow n Unknow n 'Unknow n Unknow n Unknow n 'Quslit yContro l i Unknow n /-iyt e ^nalyte ^

Pea k Nam e ,^„^„,3 , PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFO A PFOA " PFO A PFQ A PFO A PFO A ,PFQ A" PFO A PFO A" PFO A PFO A PFO A PFOA " PFO A PFO A PFO A PFOA " " PFO A PFO A PFQ A PFO A

. PFQ A •PFO A TPF'O A" " jPFO A

>FO'A " PFO A PFO A PFO A 'PFOA " PFO A PFO A PF'O'A^ PFO' A iPFQ A PFO A PFOA " •PFO A IPFO A IPFO A jPFO A IPFO A *PFO A PFO A PFO A PFO A 1335 6

331930 8 317717 5 345090 6 457063 5 1392705 1 1209 8 644 8 1007028 7 641 5 1171061 1 1176946 2 1134433 4 1234281 6 2055290 8 587 5 764 2 2296708 2 697 4 1885350 0 1736197 0 1869799 4 2449252 3

" 954 8 298///2 2 2960582 9 2992493 0 3562242 4 ll62 8 880 4 "531699 0 863 0 l62"631 0 158600 3

" 169709 0 293074 3 1297781 1 585 5 657 2 1055633 4 791 8 1177813 1 2727608 3 2001 5 1268623 9 1252643 1 1284260 9 1434041 8 2881922 3 4394 6 2896 8 288759 7 1022 1 Analyt e

Retentio n Tim e (mi n 14. 8 14. 7 14. 7 14. 7 14. 7 14. 8 14. 8 14. 8 14. 7 14. 7 14. 7 14. 7 14. 7 ;14. 7 14. 7 14l 8 14. 8 14. 7 14. 7 l'4. 7 14. 7 14. 7 14. 7 14. 7' 14. 7 14. 7' 14. 7 14. 7 14.7 " 14. 7 1141 7 M . 7 14. 7 14. 7 147 7 14. 7 l4. 7 '14. 7 14. 8 14. 7 14. 8 14. 7 14. 7 14.8 " 14. 7 14. 7 14. 7 ,l4. f 14. 7 14. 7 14. 7 14. 7 14. 7 Analyt e

Concentratio n (ng/mL ) N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A 9.9 9 N/ A N/ A N/ A N/ A Ivl/ A N/ A N/ A N/ A 25. 0 N/ A N/ A N/ A N/ A N/ A N/ A N/ A 'N/ A N/ A N/ A N/ A N/ A 's.o d N/ A "N'/A N/ A N/ A N/ A N/ A N/ A N/ A 9.'9 9 N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A N/ A 5.0 0 N/ A „ Calculate d

_^

Concentratio n ""O^ d (ng/mL )



### E

E



# S



# s

. . K 0.0045 3

256

. 245

. 267

. 356

. 1160

. 0.0035 8

' < 0 8.1 4

< 0 959

. 964

. 926

. 11020

. " il810

.

• < 0 '0.00020 d ,20. 7

< 0

' 164d

. 1490

. .11620

. 12250

. 0.0016 4 2930

. 2890

. 2930

. 3840

. 10.0032 2 ,00010 8 14.1"'6'" ' |d.0'0094 9 "il"24 7 '121

. 129

. !226

. lofd

. " " ' < 0 

### 1< 0 [8.5 7" 0.00040 9 :482

. 1290

. 10.0095 8 523

. 1516

. '530 , J599

. 11390

. 0.027 7 '0.032 7 4.4 4 '0.0043 1 Accurac y



## (% )

N/ A N/ A N/ A ,N/ A N/ A N/ A "•N/ A N/ A 81. 5 N/ A

" 'N/ A N/ A N7A ' "N/A ;N/A N/ A N/ A ,82. 9

N/ A iN/ A

" ,N7A 'N/ A N/ A 'N/ A "tig/ A N/ A N/ A 'NIA ' ' IN/ A 183. 2 [N/A " "tN/ A 'N/ A ,N/ A N/ A ,N/ A 'NTA ' " N/ A "85'.'8 ' 'iNI A

' N/ A N/ A "N/ A" N/ A IN/ A' IN/ A JN/ A |N/ A

' iN/ A

' N/ A 88. 9 N/A ' Recor d

Modifie d 

### E E E E E E E E D E E E K E E E E D 

## E E E E E E E E E E E 

## E E E E E E E E E E E E E E E E E E E E E E 

# b E Dilutio n

Facto r

1 10 0 10 0 •10 0 •10 0 IlO O

• 1 1 

### 1

' l lod " 10 0 ;io d 

## pw) " iio o

•f



# ' ^ 1 1 10 0 " 10 0 "ti"dd" " 

### iio o 

# ^"-" " 10 0 10 0 10 0 IlO O "11 " • 1 

## " 1 I i " jlO O ;10 0 ^'lidd ^ iio o

' Tid'o " "

- ^ 1

' 1



# - n "

- "1 1 •5 0 ^5 0

' i ''5 d jsd " ' 15 0 "150

- - 

# i1°""

- 1 2

" ! 2 " 

### 12 " Acquisitio n Dat e

1/7/201 1 7:44:1 4A M 1/7/201 1 8:05:1 9 A M 1/7/201 1 8:26:3 2 A M 1/7/201 1 8:47:4 4A M 1/7/201 1 9:08:5 3 A M , 1/7/201 1 9:300 2 A M 1/7/201 1 9:51:l3"/\ M 1/7/201 1 10:17? ? A M 1/7/201 1 103373 1 A M 1/7/201 1 10:54:3 9 A M 1/7/201 1 11:15:"50"7^ M 1/7/201 1 11:36:5 7A M 1/7/201 1 11:58:d4"A M , 1/7/201 1 12:19:l5'P M 1/7/201 1 12:40:2 3 P M ] 1/7/201 1 1:01:3 6 P M ' 1/7/201 1 1:22:4 7 P M 1/7/201 1 1:43:56'P' M 1/7/201 1 2:05:0 2 P U 1/7/201 1 2:26:l7rpiui " " i 1/7/201 1 2:47:3 0 P M , 1/7/201 1 3:da'38'PM ' " " 1/7/201 1 3:29:4 4P M 1/7/201 1 3:50!56?'"i^ " 1/7/201 1 4:12:0 4P M 1/7/201 1 4:33711" TM 1/7/201 1 4:54:2 1 P M 1/7/201 1 5:15:2 9 P M ' 1/7/201 1 5:36:3 3 Pfv l ' 1/7/201 1 5:57:4 3 P M "l/"7/2'0"i l 6:i8748"p'iv r" ;

" 1/7/201 1 6:4d:03"P M | 1/7/201 1 7:01:1 5 P M | 1/7/201 1 7:22:3 0 P M ; 1/7/201 1 7:43:3 8 P M 1/7/201 1 8:04:5 1 P M ""l7'7720l l 8:25:5 5 P M 1 1/7/201 1 8^47:03"P" M 1 1/7/201 1 9:08:1 5 P M 1/7/2dll"9:29;y3"p"ivi " " 1 '1/7/201 1 9:50:2 8 P M | 1/7/201 1 10:20:3 7P M 1 1/7/201 1 10:41:4 4P M 1/7/20lill:02:4"3"p"M " • 1/7/2dl 1 11:23:45"P M 1/77201 1 11:44:5 0 Pfu l 1/8/201 1 12:05:5 3 A M | 1/8/201 1 12:26:5 8 A M j 1/8/201 1 12:48:0 1 A M 1/8/201 1 1:"09:0"6"Aiv l 1/8/201 1 1:30:1 2 A M ' 1/8/201 1 1:51:1 8 A M 1/8/201 1 2:12:2 6 A M " ,

Dat a printe db yST W Printin g Time : 1:04:4 0 P M Printin g Date : Tuesday , Januar yI E Pag e 6 o f 7Buste r J293020 3 Batc hName : bllOlOSa.da b

Sampi e Nam e Sampi e I D

31 9 32 0 32 1 32 2 32 3 b110103b31 9 GLPlO-01-01-11-13 4 bl10103b32 0 GLP10-01-01-11-13 5 ,b110103b32 1 GLPlO-01-01-11-13 6 .bl10103b32 2 Solven tBIsn k (Milli Q Element ) b110103b32 3 08008-194- 9 Sampl e Commen t

DALG W141R 0 10111 0 (di l 1:10) DALG W141RD B 10111 0 (di l 1:10) DA LG W141 R L S 10111 0 (di l 1:10) Milli Q Wate rTNIO-047 5 2. 5 ng/m LFC st d i n Mill i Q Wate r Sampl e

Unknow n Unknow n Unknow n Unknow n Typ e

Qualit yContro l , _ ^ Analyt e Analyt e p^g ^

i^e a Pea k Nam e ,^^^^,3 , PFO A PFO A PFO A 'PFQ A PFO A 28828 5

21153 4 149248 2 1573 2 156181 5 Analyt e

Retentio n Tim e (mi n 14. 7 14. 7 14. 7 14. 7 14. 7 Analyt e

Concentratio n (ng/mL ) N/ A N/ A N/ A N/ A 2.5 0 Us e

Recor d



## E Calculate d Concentratio n (ng/mL ) 2.1 3 1.55 11. 4 0012 7 2.3 8 Accurac y



## (%)

N/ A N/ A N/ A 'N/A :95. 2 Recor d

Modifie d 

### E E E E E Dilutio n

Facto r ;1 0 1 1 0 1 1 0 1 2 1 2 1 Acquisitio n Dat e

1/8/201 1 2:33:3 0 A M 1/8/201 1 2:54:3 6 A M 1/8/201 1 3:15:4 0 A M 1/8/201 1 3:36:4 6 A M 1/8/201 1 3:57:5 3 A M

Dat a printe db yST W Printin g Time : 1:04:4 0 P M Printin g Date : Tuesday , Januar y18 , 201 1 Pag e 7 o f 7* * Buste r J293020 3 3atc hName : bll0103a.da b



### •b l 10103a.rd b (PFOA) : "Quadratic " Regressio n (" 1 / x " weighting) : y= -1.02e+00 4x'^ 2 + 1.32e+00 6 x+ 7.38e+00 3 ( r= 0.9996 )

6.2e 7] 6.0e7

-

5.5e7

-

5.0e7

-

4.5e7

-

4.0e7

-

3.5e7

-

" c Z ! 

### 8 3.0e7

- co "

C D 

### < 2.5e7

-

2.0e7

-

1.5e7

-

1.0e7

-

5.0e6

-

0.0

- 

# ^•- ^



# ^

, /



# / / /

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Dat a printe dbyST W Printin g Time : 1:04:5 2 P M Printin g Date : Tuesday , Januar y18 , 201 1 

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