A copy ofthe Chain of 

Custody can be found in 

LAB WARE LIMS 

A copy ofthe GPO and/or 

Protocol can be found in the 

Lotus Notes GPO Database 

Communications 

Misc. 
Weston Solutions, Inc. 

1400 Weston Way 

P.O. Box 2653 

Westchester, Pennsylvania 19380 

610-701-3000 • Fax 610-701-3186 

® www.westonsolutions.com 

The Trusted Integrator for Sustainable Solutions 

Febraary21,2011 

Dr. Cleston Lange 

3M Environmental Laboratory 

3M Center 

Building 260-5N-17 

St. Paul, MN 55144-1000 

Dear Dr. Lange: 

Per your request, I am returning herewith Interim Report 11 for study GLP 10-01-01 for 

Decatur, Alabama. The appropriate pages have been signed and are included with this 

transmittal. 

Should you have any questions, please do not hesitate to contact me at 610-701-3761. 

Very truly yours, 

WESXOf^ SOLUTIONS, INC. 

JaisirnhaXesari, P.E., DEE 

Principal Project Manager 

Enclosure 

an employee-owned company 

M:\FOLDERS.O-9\3M-DECA'nUnge-13.docx 

® 
Standard Prep 

Sample Prep 

Collection Bottle Prep 
Note To File 

Project or Study 

Description: 

LIMS Number: 

Affected Data: 

Decatur Phase 3 - FSIA groundwater 

GLPl 0-01-01-11/GLPl 0-01-02-11 

None 

One hundred eighty-nine 250 mL Nalgene bottles were marked with a 200 mL level line and labeled. 

The following trip blanks/spikes were filled with RO water (TN10-0311) and sealed after they were spiked. 

On 10/21/10, the field matrix spike bottles were spiked with the following: 

Well No. 

136R,137R,1378,137L, 138L 

130L, 131L, 1313, 133R, 1348, 

1358,1363 

130R, 1303, 132R, 132L, 1328, 

1333, 133L, 134L, 135L, 136L, 

1388, 138R, CW26R, CW26L, 140R, 

141R,142R, 143R, and 144R 

131R, 134R, 135R 

Trip Blank 1-4 

Sample 

Level 

Low 

Mid 

High 

Low 

Mid 

High 

Low 

Mid 

High 

Low 

High 

Low 

Mid 

Mid-High 

High 

Spiking 

Solution 

10 005-187 

10 005-187 

10 005-187 

10 005-187 

10 005-187 

10 006-12 

10 005-187 

10 006-12 

10 006-12 

10 006-12 

10 006-12 

10 005-187 

10 005-187 

10 006-12 

10 006-12 

Approx. 

Value 

(Mg/mL) 

2.0 

2.0 

2.0 

2.0 

2.0 

100 

2.0 

100 

100 

100 

100 

2.0 

2.0 

100 

100 

Spike 

Amount 

(ML) 

10 

100 

1000 

100 

1000 

200 

1000 

200 

2000 

200 

2000 

100 

1000 

200 

2000 

Spike 

Cone. 

(ng/mL) 

0.1 

1.0 

10 

1 

10 

100 

10 

100 

1000 

100 

1000 

1 

10. 

100 

1000 

Used Eppendorf Research pipettes 3402277 and 2077127 to add spiking solution to samples. 
Printing 12/30/2010; 2:53 PM 

GLP10-01-01-11 Sample Prep Wort( Slieet; ETS-8-044 

date; 12/30/10 

Sample ID 

LCS-101230-1 

LCS-101230-2 

LCS-101230-3 

LCS-101230-4 

LCS-101230-5 

LCS-101230-6 

LCS-101230-7 

LCS-101230-8 

LCS-101230-9 

LCS-101230-10 

LCS-101230-11 

LCS-101230-12 

LCS-101230-13 

LCS-101230-14 

LCS-101230-15 

LCS-101230-16 

LCS-101230-17 

LCS-101230-18 

Analyst: CJG 

Sample Description 

O.Sppb LCS 

0.5ppb LCS 

0.5ppb LCS 

5ppb LCS 

5ppb LCS 

5ppb LCS 

30ppb LCS 

30ppb LCS 

30ppb LCS 

O.Sppb LCS ECF 

O.Sppb LCS ECF 

O.Sppb LCS ECF 

Sppb LCS ECF 

Sppb LCS ECF 

Sppb LCS ECF 

30ppb LCS ECF 

30ppb LCS ECF 

30ppb LCS ECF 

Spiking std ID 

09 004-194 

09 004-194 

09 004-194 

09 004-193 

09 004-193 

09 004-193 

09 004-192 

09 004-192 

09 004-192 

10 010-18 

10 010-18 

10 010-18 

10 010-17 

10 010-17 

10 010-17 

10 006-27 

10 006-27 

10 006-27 

Spike Amt (uL) 

SO 

so 

50 

50 

50 

50 

30 

30 

30 

50 

SO 

SO 

25 

25 

25 

30 

30 

30 

Lab water (mL) 

10 

10 

10 

10 

10 

10 

10 

10 

10 

10 

10 

10 

10 

10 

10 

10 

10 

10 

12/30/10 CJG; LCS and Solvent Blanks prepared witti Milli Q Water (TN10-0475), vortex mixed, and aliquoted into 2-mL glass autovials. 

1 1 

12/30/10 CJG; 1 set of aliquots of 08 008-194 curve were transferred into 2-mL glass autovials 

1 1 

12/30/10 CJG; Samples GLP10-01-01-11 requiring 1:10 dilution were prepared by taking 1 mL of sample and adding 9 mL of Milli Q Element Water (TNI 0-0475), mixed , and then aliquoted into 2-mL glass autovials. 

12/30/10 CJG; Samples GLPl0-01-01-11 requiring 1:100 dilution were prepared by taking 0.1 mL of sample and adding 9.9 mL of Milli Q Element Water (TNI0-0475), mixed , and then aliquoted into 2-mL glass autovials. 

12/30/10 CJG; Samples GLP10-01-01-11 not requiring dilution were aliquoted into a 2-mL glass autovial 

1 

12/30/10 CJG; Pipette used: 4215537 

Sample ID 

GLP10-01-01-11-003 

GLPl 0-01-01-11-004 

GLP10-01-01-11-016 

GLP10-01-01-11-036 

GLP10-01-01-11-037 

GLP10-01-01-11-038 

GLPl 0-01-01-11-039 

GLP10-01-01-11-040 

GLP10-01-01-11-045 

GLP10-01-01-11-054 

GLP10-01-01-11-056 

GLP10-01-01-11-059 

GLP10-01-01-11-060 

GLP10-01-01-11-062 

GLP10-01-01-11-072 

GLP10-01-01-11-079 

GLPl 0-01-01-11-080 

GLPl 0-01-01-11-126 

GLP10-01-01-11-127 

GLP10-01-01-11-132 

GLP10-01-01-11-139 

Overfill/Underfill Amount (cm) 

7.4 

7.5 

8.0 

7.9 

7.9 

8.0 

8.0 

8.1 

7.6 

8.0 

7.5 

7.4 

7.5 

7.4 

7.5 

8.0 

8.0 

8.0 

8.0 

8.1 

8.0 

ETS-8-044 sample prep 101230.xls 

rJ6 /2-30-/0 

Page 1 of 1 
Curve Points and LCS; Method ETS-8-044 

Concentration - u 

Stock ID 

09 004-194 

09 004-193 

09 004-192 

09 004-180 

09 004-181 

10 010-17 

10 010-18 

10 006-27 

PFOA 

0.0999 

0.999 

9.99 

99.9 

2.00 

0.100 

10.0 

g/mL 

PF&& 

0.0999 

0.999 

9.99 

99.9 

-

PFHS 

0.100 

1.00 

10.0 

100 

-

PFOS 

0.0999 

0.999 

9.99 

99.9 

1.98 

0.0989 

9.89 

08008-194-1 0.025 ng/mL FC std in Milli Q water 

08008-194-2 0.03 ng/mL FC std in Milli Q water 

08008-194-3 0.04 ng/mL FC std in Milli Q water 

08008-194-4 0.05 ng/mL FC std in Milli Q water 

08008-194-5 0.1 ng/mL FC std in Milli Q water 

08008-194-6 0.25 ng/mL FC std in Milli Q water 

08008-194-7 0.5 ng/mL FC std in Milli Q water 

08008-194-8 1.0 ng/mL FC std in Milli Q water 

08008-194-9 2.5 ng/mL FC std in Milli Q water 

08008-194-10 5 ng/mL FC std in Milli Q water 

08008-194-11 10 ng/mL FC std in Milli Q water 

08008-194-12 25 ng/mL FC std in Milli Q water 

08008-194-13 50 ng/mL FC std in Milli Q water 

08008-194-14 75 ng/mL FC std in Milli Q water 

08008-194-15 100 ng/mL FC std in Milli Q water 

PFOA 

0.0250 

0.0300 

0.0400 

0.0500 

0.0999 

0.250 

0.500 

0.999 

2.50 

5.00 

9.99 

25.0 

50.0 

74.9 

99.9 

PFBS 

0.0250 

0.0300 

0.0400 

0.0500 

0.0999 

0.250 

0.500 

0.999 

2.50 

5.00 

9.99 

25.0 

50.0 

74.9 

99.9 

PFHS 

0.0250 

0.0300 

0.0400 

0.0500 

0.100 

0.250 

0.500 

1.00 

2.50 

5.00 

10.0 

25.0 

50.0 

75.0 

100 

LCS-101230-1 O.Sppb LCS 

LCS-101230-2 O.Sppb LCS 

LCS-101230-3 O.Sppb LCS 

LCS-101230-4 Sppb LCS 

LCS-101230-S Sppb LCS 

LCS-101230-6 Sppb LCS 

LCS-101230-7 30ppbLCS 

LCS-101230-8 30ppbLCS 

LCS-101230-9 30ppbLCS 

LCS-101230-1Q O.Sppb LCS ECF 

LCS-101230-11 O.Sppb LCS ECF 

LCS-101230-12 O.Sppb LCS ECF 

LCS-101230-13 Sppb LCS ECF 

LCS-101230-14 Sppb LCS ECF 

LCS-101230-1S Sppb LCS ECF 

LCS-101230-16 30ppbLCSECF 

LCS-101230-17 30ppbLCSECF 

LCS-101230-18 30ppb LCS ECF 

0.497 

0.497 

0.497 

4.97 

4.97 

4.97 

29.9 

29.9 

29.9 

0.498 

0.498 

0.498 

4.99 

4.99 

4.99 

29.9 

29.9 

29.9 

0.497 

0.497 

0.497 

4.97 

4.97 

4.97 

29.9 

29.9 

29.9 

-

0.498 

0.498 

0.498 

4.98 

4.98 

4.98 

29.9 

29.9 

29.9 

-

PFOS 

0.0250 

0.0300 

0.0400 

0.0500 

0.0999 

0.250 

0.500 

0.999 

2.50 

5.00 

9.99 

25.0 

50.0 

74.9 

99.9 

Stock ID 

09 004-194 

09 004-194 

09 004-194 

09 004-194 

09 004-194 

09 004-194 

09 004-193 

09 004-193 

09 004-192 

09 004-192 

09 004-192 

09 004-192 

09 004-192 

09 004-192 

09 004-192 

0.497 

0.497 

0.497 

4.97 

4.97 

4.97 

29.9 

29.9 

29.9 

0.492 

0.492 

0.492 

4.95 

4.95 

4.95 

29.7 

29.7 

29.7 

09 004-194 

09 004-194 

09 004-194 

09 004-193 

09 004-193 

09 004-193 

09 004-192 

09 004-192 

09 004-192 

10 010-18 

10 010-18 

10 010-18 

10 010-17 

10 010-17 

10 010-17 

10 006-27 

10 006-27 

10 006-27 

Spike 

Volume 

(uL) 

• 25 

30 

40 

50 

100 

250 

50 

100 

25 

50 

100 

250 

500 

750 

1000 

50 

50 

50 

50 

50 

50 

30 

30 

30 

50 

50 

50 

25 

25 

25 

30 

30 

30 

Surrogate 

Volume (uL) 

Final 

Volume 

(mL) 

25 100 

30 100 

40 100 

50 100 

100 100 

250 100 

100 

100 

100 

100 

100 

100 

100 

100 

100 

-

-

10.05 

10.05 

10.05 

10.05 

10.05 

10.05 

10.03 

10.03 

10.03 

10.05 

10.05 

10.05 

10.025 

10.025 

10.025 

10.03 

10.03 

10.03 

ETS-8-044 sample prep 101230.xls Calibration Curve Page 1 of 1 
Sampl

e Id 

LCS-101230-1 

LCS-101230-2 

LCS-101230-3 

LCS-101230-4 

LCS-101230-5 

LCS-101230-6 

LCS-101230-7 

LCS-101230-8 

LCS-101230-9 

LCS-101230-10 

LCS-101230-11 

LCS-101230-12 

LCS-101230-13 

LCS-101230-14 

LCS-101230-15 

LCS-101230-16 

LCS-101230-17 

LCS-101230-18 

Description 

O.Sppb LCS 

O.Sppb LCS 

O.Sppb LCS 

Sppb LCS 

Sppb LCS 

Sppb LCS 

30ppb LCS 

30ppb LCS 

30ppb LCS 

O.Sppb LCS ECF 

O.Sppb LCS ECF 

O.Sppb LCS ECF 

Sppb LCS ECF 

Sppb LCS ECF 

Sppb LCS ECF 

30ppb LCS ECF 

30ppb LCS ECF 

30ppb LCS ECF 

GLP10-01-01-11-001 DAL GW130R 0 101105 (dil 1:100) 

GLP10-01-01-11-002 DALGW130RDB 101105 (dil 1:100) 

GLP10-01-01-11-003 DALGW130RLS 101105 (dil 1:100) 

GLP10-01-01-11-004 DAL GW130R MS 101105 (dil1:100) 

GLP10-01-01-11-005 DAL GW 130R HS 101105 (dil 1:100) 

GLP10-01-01-11-006 DAL GW 130S 0 101105 (dil 1:100) 

GLP10-01-01-11-007 DAL GW 130S DB 101105 (dil 1:100) 

GLP10-01-01-11-008 DAL GW 130S LS 101105 (dil 1:100) 

GLP10-01-01-11-009 DALGW 130S MS 101105 (dil 1:100) 

GLP10-01-01-11-010 DAL GW 130S HS 101105 (dil 1:100) 

GLP10-01-01-11-011 DAL GW130L 0 101105 (dil 1:10) 

GLP10-01-01-11-012 DALGW130LDB 101105 (dil 1:10) 

GLP10-01-01-11-013 DAL GW 130L LS 101105 (dil 1:10) 

GLP10-01-01-11-014 DAL GW 130L MS 101106 (dil 1:10) 

GLP10-01-01-11-015 DALGW 130LHS 101105 (dil 1:10) 

GLP10-01.01-11-017 DAL GW 131R 0 101103 (dil 1:100) 

GLP10-01-01-11-018 DALGW 131R DB 101103 (dil 1:100) 

GLP10-01-01-11-019 DAL GW131RLS 101103 (dil 1:100) 

GLP10-01-01-11-020 DALGW 131RHS 101103 (dil 1:100) 

GLP10-01-01-11-021 DAL GW131S 0 101103 (dil 1:10) 

GLP10-01-01-11-022 DALGW 131S DB 101103 (dil 1:10) 

GLP10-01-01-11-023 DAL GW131SLS 101103 (dil 1:10) 

GLP10-01-01-11-024 DAL GW131SHS 101103 (dil 1:10) 

GLP10-01-01-11-025 DAL GW 131S MS 101103 (dil 1:10) 

GLP10-01-01-11-026 DAL GW131L 0 101103 (dil 1:10) 

GLP10-01-01-11-027 DAL GW131LDB 101103 (dil 1:10) 

GLP10-01-01-11-028 DALGW 131LLS 101103 (dil 1:10) 

GLP10-01-01-11-029 DAL GW131L MS 101103 (dil 1:10) 

GLP10-01-01-11-030 DAL GW 131L HS 101103 (dil 1:10) 

GLP10-01-01-11-031 DALGW 132R 0101102 (dil 1:100) 

GLP10-01-01-11-032 DAL GW 132R DB 101102 (dil 1:100) 

GLP10-01-01-11-033 DAL GW 132R LS 101102 (dil 1:100) 

GLP10-01-01-11-034 DAL GW132R MS 101102 (dil 1:100) 

GLP10-01-01-11-035 DAL GW132RHS 101102 (dil 1:100) 

GLP10-01-01-11-036 DAL GW 132S 0 101102 (dil 1:100) 

6LP10-01-01-11-037 DAL GW 132S DB 101102 (dil 1:100) 

GLP10-01-01-11-038 DAL GW 132S LS 101102 (dil 1:100) 

GLP10-01-01-11-039 DALGW132SMS 101102 (dil 1:100) 

GLP10-01-01-11-040 DAL GW 132S HS 101102 (dil 1:100) 

GLP10-01-01-11-041 DAL GW132L 0 101103 (dil 1:10) 

GLP10-01-01-11-042 DALGW 132LDB 101103 (dil 1:10) 

GLP10-01-01-11-043 DALGW 132LLS 101103 (dil 1:10) 

GLP10-01-01-11-044 DALGW 132LMS 101103 (dil 1:10) 

GLP10-01-01-11-045 DAL GW 132L HS 101103 (dil 1:10) 

GLP10-01-01-11-046 DAL GW 133R 0 101102 (dil 1:10) 

GLP10-01-01-11-047 DAL GW 133R DB 101102 (dil 1:10) 

GLP10-01-01-11-048 DAL GW 133R LS 101102 (dil 1:10) 

GLP10-01-01-11-049 DAL GW 133R MS 101102 (dil 1:10) 

GLP10-01-01-11-050 DALGW 133R HS 101102 (dil 1:10) 

GLP10-01-01-11-0S1 DAL GW133S 0 101103 (dil 1:10) 

GLP10-01-01-11-052 DALGW133SDB101103(dil 1:10) 

GLP10-01-01-11-053 DALGW 133S LS 101103 (dil 1:10) 

GLP10-01-01-11-054 DALGW133SMS 101103 (dil 1:10) 

GLP10-01-01-11-055 DALGW 133S HS 101103 (dil 1:10) 

GLP10-01-01-11-056 DAL GW133L 0101103 (dil 1:10) 

GLP10-01-01-11-057 DALGW 133LDB 101103 (dil 1:10) 

GLP10-01-01-11-058 DAL GW133LLS 101103 (dil 1:10) 

GLP10-01-01-11-059 DALGW133LMS101103(dil 1:10) 

GLP10-01-01-11-060 DAL GW133LHS 101103 (dil 1:10) 

GLP10-01-01-11-061 DALGW 134R 0 101105 (dil 1:100) 

GLP10-01-01-11-062 DAL GW134RDB 101105 (dil 1:100) 

GLP10-01-01-11-063 DAL GW 134R LS 101105 (dil 1:100) 

GLP10-01-01-11-064 DAL GW 134R HS 101106 (dil 1:100) 

GLP10-01-01-11-070 DAL GW134L 0 101105 (dil 1:10) 

GLP10-01-01-11-071 DAL GW 134L DB 101106 (dil 1:10) 

GLP10-01-01-11-072 DAL GW134LLS 101106 (dil 1:10) 

Prep Date 

Prepared: 

Prepared: 

Prepared: 

Prepared: 

Prepared: 

Prepared: 

Prepared: 

Prepared: 

Prepared: 

Prepared: 

Prepared: 

Prepared: 

Prepared: 

Prepared: 

Prepared: 

Prepared: 

Prepared: 

Prepared: 

Prepared: 

Prepared: 

Prepared: 

Prepared: 

Prepared: 

Prepared: 

Prepared: 

Prepared: 

Prepared: 

Prepared: 

Prepared: 

Prepared: 

Prepared: 

Prepared: 

Prepared: 

Prepared: 

Prepared: 

Prepared: 

Prepared: 

Prepared: 

Prepared: 

Prepared: 

Prepared: 

Prepared: 

Prepared: 

Prepared: 

Prepared: 

Prepared: 

Prepared: 

Prepared: 

Prepared: 

Prepared: 

Prepared: 

Prepared: 

Prepared: 

Prepared: 

Prepared: 

Prepared: 

Prepared: 

Prepared: 

Prepared: 

Prepared: 

Prepared: 

Prepared: 

Prepared: 

Prepared: 

Prepared: 

Prepared: 

Prepared: 

Prepared: 

Prepared: 

Prepared: 

Prepared: 

Prepared: 

Prepared: 

Prepared: 

Prepared: 

Prepared: 

Prepared: 

Prepared: 

Prepared: 

Prepared: 

Prepared: 

Prepared: 

Prepared: 

Prepared: 

12/30/10 CJG 

12/30/10 CJG 

12/30/10 CJG 

12/30/10 CJG 

12/30/10 CJG 

12/30/10 CJG 

12/30/10 CJG 

12/30/10 CJG 

12/30/10 CJG 

12/30/10 CJG 

12/30/10 CJG 

12/30/10 CJG 

12/30/10 CJG 

12/30/10 CJG 

12/30/10 CJG 

12/30/10 CJG 

12/30/10 CJG 

12/30/10 CJG 

12/30/10 CJG 

12/30/10 CJG 

12/30/10 CJG 

12/30/10 CJG 

12/30/10 CJG 

12/30/10 CJG 

12/30/10 CJG 

12/30/10 CJG 

12/30/10 CJG 

12/30/10 CJG 

12/30/10 CJG 

12/30/10 CJG 

12/30/10 CJG 

12/30/10 CJG 

12/30/10 CJG 

12/30/10 CJG 

12/30/10 CJG 

12/30/10 CJG 

12/30/10 CJG 

12/30/10 CJG 

12/30/10 CJG 

12/30/10 CJG 

12/30/10 CJG 

12/30/10 CJG 

12/30/10 CJG 

12/30/10 CJG 

12/30/10 CJG 

12/30/10 CJG 

12/30/10 CJG 

12/30/10 CJG 

12/30/10 CJG 

12/30/10 CJG 

12/30/10 CJG 

12/30/10 CJG 

12/30/10 CJG 

12/30/10 CJG 

12/30/10 CJG 

12/30/10 CJG 

12/30/10 CJG 

12/30/10 CJG 

12/30/10 CJG 

12/30/10 CJG 

12/30/10 CJG 

12/30/10 CJG 

12/30/10 CJG 

12/30/10 CJG 

12/30/10 CJG 

12/30/10 CJG 

12/30/10 CJG 

12/30/10 CJG 

12/30/10 CJG 

12/30/10 CJG 

12/30/10 CJG 

12/30/10 CJG 

12/30/10 CJG 

12/30/10 CJG 

12/30/10 CJG 

12/30/10 CJG 

12/30/10 CJG 

12/30/10 CJG 

12/30/10 CJG 

12/30/10 CJG 

12/30/10 CJG 

12/30/10 CJG 

12/30/10 CJG 

12/30/10 CJG 

toxic. Refrigerate 

toxic, Refrigerate 

toxic, Refrigerate 

toxic. Refrigerate 

toxic. Refrigerate 

toxic. Refrigerate 

toxic. Refrigerate 

toxic. Refrigerate 

toxic. Refrigerate 

toxic. Refrigerate 

toxic. Refrigerate 

toxic. Refrigerate 

toxic. Refrigerate 

toxic. Refrigerate 

toxic. Refrigerate 

toxic. Refrigerate 

toxic. Refrigerate 

toxic, Refrigerate 

toxic. Refrigerate 

toxic. Refrigerate 

toxic. Refrigerate 

toxic. Refrigerate 

toxic. Refrigerate 

toxic, Refrigerate 

toxic. Refrigerate 

toxic. Refrigerate 

toxic. Refrigerate 

toxic. Refrigerate 

toxic. Refrigerate 

toxic. Refrigerate 

toxic. Refrigerate 

toxic. Refrigerate 

toxic. Refrigerate 

toxic. Refrigerate 

toxic. Refrigerate 

toxic. Refrigerate 

toxic. Refrigerate 

toxic. Refrigerate 

toxic. Refrigerate 

toxic. Refrigerate 

toxic. Refrigerate 

toxic. Refrigerate 

toxic. Refrigerate 

toxic. Refrigerate 

toxic. Refrigerate 

toxic. Refrigerate 

toxic. Refrigerate 

toxic. Refrigerate 

toxic. Refrigerate 

toxic. Refrigerate 

toxic. Refrigerate 

toxic. Refrigerate 

toxic. Refrigerate 

toxic. Refrigerate 

toxic. Refrigerate 

toxic. Refrigerate 

toxic. Refrigerate 

toxic. Refrigerate 

toxic. Refrigerate 

toxic. Refrigerate 

toxic, Refrigerate 

toxic. Refrigerate 

toxic. Refrigerate 

toxic. Refrigerate 

toxic. Refrigerate 

toxic. Refrigerate 

toxic. Refrigerate 

toxic. Refrigerate 

toxic. Refrigerate 

toxic. Refrigerate 

toxic. Refrigerate 

toxic. Refrigerate 

toxic. Refrigerate 

toxic. Refrigerate 

toxic. Refrigerate 

toxic. Refrigerate 

toxic. Refrigerate 

toxic. Refrigerate 

toxic. Refrigerate 

toxic. Refrigerate 

toxic. Refrigerate 

toxic. Refrigerate 

toxic. Refrigerate 

toxic. Refrigerate 

ETS-8-044 saLiiple prep 101230.xls Page 1 of 5 

^G7|-l€-(l 
Sampl

e Id Description Prep Date 

GLP10-01-01-11-073 DAL GW134L MS 101105 (dil 1:10) Prepared: 12/30/10 CJG toxic, Refrigerate 

GLP10-01-01-11-074 DAL GW134LHS 101105 (dil 1:10) Prepared: 12/30/10 CJG toxic, Refrigerate 

GLP10-01-01-11-075 DAL GW135R0 101105 (dil 1:100) Prepared: 12/30/10 CJG toxic, Refrigerate 

GLP10-01-01-11-076 DAL GW135RDB 101105 (dil 1:100) Prepared: 12/30/10 CJG toxic, Refrigerate 

GLP10-01-01-11-077 DAL GW135RLS 101105 (dil 1:100) Prepared: 12/30/10 CJG toxic, Refrigerate 

GLP10-01-01-11-078 DAL GW136RHS 101105 (dil 1:100) Prepared: 12/30/10 CJG toxic, Refrigerate 

GLP10-01-01-11-084 DAL GW136L 0 101105 (dil 1:100) Prepared: 12/30/10 CJG toxic, Refrigerate 

GLP10-01-01-11-085 DAL GW135LDB 101105 (dil 1:100) Prepared: 12/30/10 CJG toxic, Refrigerate 

GLP10-01-01-11-086 DAL GW136LLS 101105 (dil 1:100) Prepared: 12/30/10 CJG toxic. Refrigerate 

GLP10-01-01-11-087 DAL GW136L MS 101106 (dil 1:100) Prepared: 12/30/10 CJG toxic, Refrigerate 

GLP10-01-01-11-088 DAL GW136LHS 101105 (dil 1:100) Prepared: 12/30/10 CJG toxic, Refrigerate 

GLP10-01-01-11-089 DAL GW136S 0 101103 (dil 1:10) Prepared: 12/30/10 CJG toxic, Refrigerate 

GLP10-01-01-11-090 DAL GW136SDB 101103 (dil 1:10) Prepared: 12/30/10 CJG toxic, Refrigerate 

GLPl0-01-01-11-091 DAL GW136SLS 101103 (dil 1:10) Prepared: 12/30/10 CJG toxic. Refrigerate 

GLP10-01-01-11-092 DAL GW136S MS 101103 (dil 1:10) Prepared: 12/30/10 CJG toxic. Refrigerate 

GLP10-01-01-11-093 DAL GW136SHS 101103 (dil 1:10) Prepared: 12/30/10 CJG toxic. Refrigerate 

GLP10-01-01-11-094 DALGW136L0101103(dil1:10) Prepared: 12/30/10CJG toxic. Refrigerate 

GLP10-01-01-11-096 DAL GW136LDB 101103 (dil 1:10) Prepared: 12/30/10 CJG toxic. Refrigerate 

GLP10-01-01-11-096 DAL GW136LLS 101103 (dil 1:10) Prepared: 12/30/10 CJG toxic. Refrigerate 

GLP10-01-01-11-097 DAL GW136L MS 101103 (dil 1:10) Prepared: 12/30/10 CJG toxic. Refrigerate 

GLP10-01-01-11-098 DAL GW136LHS 101103 (dil 1:10) Prepared: 12/30/10 CJG toxic. Refrigerate 

GLP10-01-01-11-109 DALGW 1388 0 101110 (dil 1:10) Prepared: 12/30/10CJG toxic. Refrigerate 

GLP10-01-01-11-110 DALGW 138SDB 101110(dil 1:10) Prepared: 12/30/10CJG toxic. Refrigerate 

GLP10-01-01-11-111 DALGW 138SLS 101110(dil 1:10) Prepared: 12/30/10CJG toxic. Refrigerate 

GLP10-01-01-11-112 DALGW138SMS101110(dil1:10) Prepared: 12/30/10CJG toxic. Refrigerate 

GLP10-01-01-11-113 DALGW 138SHS 101110(dil 1:10) Prepared: 12/30/10CJG toxic. Refrigerate 

GLP10-01-01-11-119 DALGWCW26R0 101110 (dil 1:10) Prepared: 12/30/10 CJG toxic. Refrigerate 

GLP10-01-01-11-120 DALGWCW26RDB101110(dil 1:10) Prepared: 12/30/10CJG toxic. Refrigerate 

GLP10-01-01-11-121 DAL GW CW26R LS 101110 (dil 1:10) Prepared: 12/30/10 CJG toxic. Refrigerate 

GLP10-01-01-11-122 DALGWCW26RMS101110(dil1:10) Prepared: 12/30/10CJG toxic. Refrigerate 

GLP10-01-01-11-123 DALGWCW26RHS101110(dil 1:10) Prepared: 12/30/10 CJG toxic. Refrigerate 

GLP10-01-01-11-124 DAL GW CW26L 0 101110 (dil 1:10) Prepared: 12/30/10 CJG toxic. Refrigerate 

GLP10-01-01-11-126 DAL GWCW26LDB 101110 (dil 1:10) Prepared: 12/30/10 CJG toxic. Refrigerate 

GLP10-01-01-11-126 DAL GW CW26L LS 101110 (dil 1:10) Prepared: 12/30/10 CJG toxic, Refrigerate 

GLP10-01-01-11-127 DALGWCW26LMS101110(dil1:10) Prepared: 12/30/10 CJG toxic. Refrigerate 

GLP10-01-01-11-128 DAL GWCW26LHS 101110 (dil 1:10) Prepared: 12/30/10 CJG toxic. Refrigerate 

GLP10-01-01-11-129 DALGW140R0101104(dil1:10) Prepared: 12/30/10CJG toxic. Refrigerate 

GLP10-01-01-11-130 DAL GW140RDB 101104 (dil 1:10) Prepared: 12/30/10 CJG toxic. Refrigerate 

GLP10-01-01-11-131 DAL GW140RLS 101104 (dil 1:10) Prepared: 12/30/10 CJG toxic. Refrigerate 

GLP10-01-01-11-132 DAL GW140R MS 101104 (dil 1:10) Prepared: 12/30/10 CJG toxic. Refrigerate 

GLP10-01-01-11-133 DAL GW140RHS 101104 (dil 1:10) Prepared: 12/30/10 CJG toxic. Refrigerate 

GLP10-01-01-11-134 DALGW 141R0 101110(dil 1:10) Prepared: 12/30/10 CJG toxic. Refrigerate 

GLP10-01-01-11-135 DALGW141RDB101110(dil1:10) Prepared: 12/30/10CJG toxic. Refrigerate 

GLP10-01-01-11-136 DAL GW141RLS 101110 (dil 1:10) Prepared: 12/30/10 CJG toxic. Refrigerate 

GLP10-01-01-11-137 DAL GW 141R MS 101110 (dil 1:10) Prepared: 12/30/10 CJG toxic. Refrigerate 

GLP10-01-01-11-138 DAL GW141RHS 101110 (dil 1:10) Prepared: 12/30/10 CJG toxic. Refrigerate 

GLP10-01-01-11-139 DAL GW142R0101110(dil 1:10) Prepared: 12/30/10 CJG toxic. Refrigerate 

GLP10-01-01-11-140 DALGW142RDB101110(dil1:10) Prepared: 12/30/10CJG toxic. Refrigerate 

GLP10-01-01-11-141 DAL GW142RLS 101110 (dil 1:10) Prepared: 12/30/10 CJG toxic. Refrigerate 

GLP10-01-01-11-142 DAL GW142R MS 101110 (dii1:10) Prepared: 12/30/10 CJG toxic. Refrigerate 

GLP10-01-01-11-143 DALGW142RHS101110(dil1:10) Prepared: 12/30/10CJG toxic. Refrigerate 

GLP10-01-01-11-144 DALGW144R0101110(dil1:10) Prepared: 12/30/10CJG toxic. Refrigerate 

GLP10-01-01-11-145 DALGW144RDB101110(dil1:10) Prepared: 12«0/10CJG toxic. Refrigerate 

GLP10-01-01-11-146 DAL GW144RLS 101110 (dil 1:10) Prepared: 12/30/10 CJG toxic. Refrigerate 

GLP10-01-01-11-147 DAL GW144R MS 101110 (dil 1:10) Prepared: 12/30/10 CJG toxic. Refrigerate 

GLP10-01-01-11-148 DAL GW144RHS 101110 (dil 1:10) Prepared: 12/30/10 CJG toxic. Refrigerate 

GLP10-01-01-11-154 Trip Blank Set 1 HS (dil 1:100) Prepared: 12/30/10 CJG toxic. Refrigerate 

GLP10-01-01-11-159 Trip Blank Set 2 HS (dil 1:100) Prepared: 12/30/10 CJG toxic. Refrigerate 

GLP10-01-01-11-164 Trip Blank Set 3 HS (dil 1:100) Prepared: 12/30/10 CJG toxic. Refrigerate 

GLP10-01-01-11-169 Trip Blank Set 4 HS (dil 1:100) Prepared: 12/30/10 CJG toxic. Refrigerate 

Solvent Blank Milli Q Water TNI0-0475 Aliquoted: 12/30/10 CJG toxic. Refrigerate 

Solvent Blank MilliQ Water TN10-0475 Aliquoted: 12/30/10 CJG toxic. Refrigerate 

Solvent Blank MilliQ Water TNI 0-0475 Aliquoted: 12/30/10 CJG toxic. Refrigerate 

Solvent Blank Milli Q Water TN10-0475 Aliquoted: 12/30/10 CJG toxic. Refrigerate 

Solvent Blank Milli Q Water TNI0-0475 Aliquoted: 12/30/10 CJG toxic. Refrigerate 

Solvent Blank Milli Q Water TN10-0475 Aliquoted: 12/30/10 CJG toxic. Refrigerate 

Solvent Blank Milli Q Water TN10-0475 Aliquoted: 12/30/10 CJG toxic. Refrigerate 

Solvent Blank MilliQ Water TN10-0475 Aliquoted: 12/30/10 CJG toxic. Refrigerate 

Solvent Blank . Milli Q Water TNI0-0475 Aliquoted; 12/30/10 CJG toxic. Refrigerate 

Solvent Blank Milli Q Water TN10-0475 Aliquoted: 12/30/10 CJG toxic. Refrigerate 

08008-194-1 0.025 ng/mL FC std in Milli Q Water Aliquoted: 12/30/10 CJG toxic, Refrigerate 

08008-194-2 0.03 ng/mL FC std in Milli Q Water Aliquoted: 12/30/10 CJG toxic. Refrigerate 

08008-194-3 0.04 ng/mL FC std in Milli Q Water Aliquoted: 12/30/10 CJG toxic, Refrigerate 

08008-194-4 0.05 ng/mLFC std in MilliQ Water Aliquoted: 12/30/10 CJG toxic, Refrigerate 

08008-194-6 0.1 ng/mL FC std in Milli Q Water Aliquoted: 12/30/10 CJG toxic, Refrigerate 

08008-194-6 0.25 ng/mL FC std in Milli Q Water Aliquoted: 12/30/10 CJG toxic. Refrigerate 

08008-194-7 0.5 ng/mL FC std in Milli Q Water Aliquoted: 12/30/10 CJG toxic, Refrigerate 

08008-194-8 1.0 ng/mLFC std in MilliQ Water Aliquoted: 12/30/10 CJG toxic, Refrigerate 

08008-194-9 2.5 ng/mL FC std in Milli Q Water Aliquoted: 12/30/10 CJG toxic. Refrigerate 

08008-194-10 5.0 ng/mL FC std in Milli Q Water Aliquoted: 12/30/10 CJG toxic. Refrigerate 

08008-194-11 10 ng/mLFC std in MilliQ Water Aliquoted: 12/30/10 CJG toxic, Refrigerate 

08008-194-12 25 ng/mL FC std in Milli Q Water Aliquoted: 12/30/10 CJG toxic, Refrigerate 

08008-194-13 50 ng/mL FC std in Milli Q Water Aliquoted: 12/30/10 CJG toxic, Refrigerate 

08008-194-14 75 ng/mL FC std in Milli Q Water Aliquoted: 12/30/10 CJG toxic, Refrigerate 

ETS-8-044 sample prep 101230.xls Pag

e 2 of 5 
Sampl

e Id 

08008-194-15 

LCS-101230-1 

LCS-101230-2 

LCS-101230-3 

LCS-101230-4 

LCS-101230-5 

LCS-101230-6 

LCS-101230-7 

LCS-101230-8 

LCS-101230-9 

LCS-101230-10 

LCS-101230-11 

LCS-101230-12 

LCS-101230-13 

LCS-101230-14 

LCS-101230-15 

LCS-101230-16 

LCS-101230-17 

LCS-101230-18 

Description 

100 ng/mL FC std in Milli Q Water 

O.Sppb LCS 

O.Sppb LCS 

O.Sppb LCS 

Sppb LCS 

Sppb LCS 

Sppb LCS 

30ppb LCS 

30ppb LCS 

30ppb LCS 

O.Sppb LCS ECF 

O.Sppb LCS ECF 

O.Sppb LCS ECF 

Sppb LCS ECF 

Sppb LCS ECF 

Sppb LCS ECF 

30ppb LCS ECF 

30ppb LCS ECF 

30ppb LCS ECF 

Prep Date 

Aliquoted: 12/30/10 CJG toxic. Refrigerate 

GLP10-01-01-11-001 DALGW 130R0 101105 (dil 1:100) 

GLP10-01-01-11-002 DALGW 130RDB10110S(diM:100) 

GLP10-01-01-11-003 DALGW 130R LS 10110S(di11:100) 

GLP10-01-01-11-004 DALGW130RMS 101105 (dil 1:100) 

GLP10-01-01-11-005 DALGW ISOR HS 101105 (dil 1:100) 

GLP10-01-01-11-006 DAL GW 130S 0 101105 (dil 1:100) 

GLP10-01-01-11-007 DAL GW 130S DB 101105 (dil 1:100) 

GLP10-01-01-11-008 DAL GW 130S LS 101105 (dil 1:100) 

GLP10-01-01-11-009 DAL GW 130S MS 10110S (dil 1:100) 

GLP10-01-01-11-010 DAL GW 130S HS 101105 (dil 1:100) 

GLP10-01-01-11-011 DAL GW130L 0101105 (dil 1:10) 

GLP10-01-01-11-012 DAL GW130LDB 101105 (dil1:10) 

GLP10-01-01-11-013 DALGW 130LLS 101105 (dil 1:10) 

GLP10-01-01-11-014 DALGW 130LMS 101105 (dil 1:10) 

GLP10-01-01-11-015 DAL GW 130L HS 101105 (dil 1:10) 

GLP10-01-01-11-016 DAL GW 130L RB 101105 

GLP10-01-01-11-017 DAL GW 131R 0 101103 (dil 1:100) 

GLP10-01-0M1-018 DAL GW 131R DB 101103 (dil 1:100) 

GLP10-01-01-11-019 DAL GW131RLS 101103 (dil1:100) 

GLP10-01-01-11-020 DALGW 131RHS 101103 (dil 1:100) 

GLP10-01-01-11-021 DAL GW 131S 0 101103 (dil 1:10) 

GLP10-01-01-11-022 DALGW131SDB 101103 (dil 1:10) 

GLP10-01-01-11-023 DAL GW 131S LS 101103 (dil 1:10) 

GLP1O-01-0M1-024 DAL GW 131S HS 101103 (dil 1:10) 

GLP10-01-01-11-025 DAL GW 131S MS 101103 (dil 1:10) 

GLP10-01-01-11-026 DAL GW131L 0 101103 (dil 1:10) 

GLP10-01-01-11-027 DAL GW 131L DB 101103 (dil 1:10) 

GLP10-01-01-11-028 DAL GW 131L LS 101103 (dil 1:10) 

GLP10-01-01-11-029 DAL GW131L MS 101103 (dil 1:10) 

GLP10-01-OM1-030 DAL GW131LHS 101103 (dil 1:10) 

GLP10-01-01-11-031 DAL GW 132R 0 101102 (dil 1:100) 

GLP10-01-01-11-032 DAL GW 132R DB 101102 (dil 1:100) 

GLP10-01-01-11-033 DAL GW 132R LS 101102 (dil 1:100) 

GLP10-01-01-11-034 DAL GW 132R MS 101102 (dil 1:100) 

GLP1CW)1-01-11-035 DAL GW 132R HS 101102 (dil 1:100) 

GLP10-01-01-11-036 DAL 6W132S 0 101102 (dil 1:100) 

GLP10-01-01-11-037 DAL GW132SDB 101102 (dil 1:100) 

GLP10-01-01-11-038 DAL GW 132S LS 101102 (dil 1:100) 

GLP10-01-01-11-039 DAL GW 132S MS 101102 (dil 1:100) 

GLP10-01-01-11-040 DAL GW 132S HS 101102 (dil 1:100) 

GLP10-01-01-11-041 DAL GW132L 0 101103 (dil 1:10) 

GLP10-01-01-11-042 DAL GW 132L DB 101103 (dil 1:10) 

GLP10-01-01-11-043 DAL GW132LLS 101103 (dil 1:10) 

GLP10-01-01-11-044 DALGW 132LMS 101103 (dil 1:10) 

GLP10-01-01-11-045 DAL GW 132L HS 101103 (dil 1:10) 

GLP10-01-01-11-046 DAL GW 133R 0 101102 (dil 1:10) 

GLP10-01-01-11-047 DAL GW 133R DB 101102 (dil 1:10) 

GLP10-01-01-11-048 DAL GW 133R LS 101102 (dil 1:10) 

GLP10-01-01-11-049 DALGW 133RMS 101102 (dil 1:10) 

GLP10-01-01-11-050 DALGW 133R HS 101102 (dil 1:10) 

GLP10-01-01-11-051 DAL GW 133S 0 101103 (dil 1:10) 

GLP10-01-01-11-052 DAL GW 133S DB 101103 (dil 1:10) 

GLP10-01-01-11-053 DAL GW 133S LS 101103 (dil 1:10) 

GLP10-01-01-11-054 DALGW133SMS 101103 (dil 1:10) 

GLP10-01-01-11-0SS DAL GW133SHS 101103 (dil 1:10) 

GLP10-01-01-11-056 DAL GW133L 0 101103 (dil 1:10) 

GLP10-01-01-11-057 DAL GW 133L DB 101103 (dil 1:10) 

GLP10-01-01-11-OS8 DAL GW 133L LS 101103 (dil 1:10) 

GLP10-01-01-11-059 DAL GW133LMS 101103 (dit 1:10) 

GLP10-01-01-11-060 DAL GW 133L HS 101103 (dil 1:10) 

GLP10-01-01-11-061 DALGW134R0 101105 (dil 1:100) 

GLP10-01-01-11-062 DAL GW 134R DB 10110S (dil 1:100) 

GLP10-01-01-11-063 DAL GW 134R LS 101105 (dil 1:100) 

GLP10-01-01-11-064 DAL GW 134R HS 101105 (dil 1:100) 

Aliquoted: 

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2/30/10 CJG 

2/30/10 CJG 

2/30/10 CJG 

2/30/10 CJG 

2/30/10 CJG 

2/30/10 CJG 

2/30/10 CJG 

2/30/10 CJG 

2/30/10 CJG 

2/30/10 CJG 

2/30/10 CJG 

2/30/10 CJG 

2/30/10 CJG 

2/30/10 CJG 

2/30/10 CJG 

2/30/10 CJG 

2/30/10 CJG 

2/30/10 CJG 

2/30/10 CJG 

2/30/10 CJG 

2/30/10 CJG 

2/30/10 CJG 

2/30/10 CJG 

2/30/10 CJG 

2/30/10 CJG 

2/30/10 CJG 

2/30/10 CJG 

2/30/10 CJG 

2/30/10 CJG 

2/30/10 CJG 

2/30/10 CJG 

2/30/10 CJG 

2/30/10 CJG 

2/30/10 CJG 

2/30/10 CJG 

2/30/10 CJG 

2/30/10 CJG 

2/30/10 CJG 

2/30/10 CJG 

2/30/10 CJG 

2/30/10 CJG 

2/30/10 CJG 

2/30/10 CJG 

2/30/10 CJG 

2/30/10 CJG 

2/30/10 CJG 

2/30/10 CJG 

2/30/10 CJG 

2/30/10 CJG 

2/30/10 CJG 

2/30/10 CJG 

2/30/10 CJG 

2/30/10 CJG 

2/30/10 CJG 

2/30/10 CJG 

2/30/10 CJG 

2/30/10 CJG 

2/30/10 CJG 

2/30/10 CJG 

2/30/10 CJG 

2/30/10 CJG 

2/30/10 CJG 

2/30/10 CJG 

2/30/10 CJG 

2/30/10 CJG 

2/30/10 CJG 

2/30/10 CJG 

2/30/10 CJG 

2/30/10 CJG 

2/30/10 CJG 

2/30/10 CJG 

2/30/10 CJG 

2/30/10 CJG 

2/30/10 CJG 

2/30/10 CJG 

2/30/10 CJG 

2/30/10 CJG 

2/30/10 CJG 

2/30/10 CJG 

2/30/10 CJG 

2/30/10 CJG 

2/30/10 CJG 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

toxic, 

Refrigerate 

Refrigerate 

Refrigerate 

Refrigerate 

Refrigerate 

Refrigerate 

Refrigerate 

Refrigerate 

Refrigerate 

Refrigerate 

Refrigerate 

Refrigerate 

Refrigerate 

Refrigerate 

Refrigerate 

Refrigerate 

Refrigerate 

Refrigerate 

Refrigerate 

Refrigerate 

Refrigerate 

Refrigerate 

Refrigerate 

Refrigerate 

Refrigerate 

Refrigerate 

Refrigerate 

Refrigerate 

Refrigerate 

Refrigerate 

Refrigerate 

Refrigerate 

Refrigerate 

Refrigerate 

Refrigerate 

Refrigerate 

Refrigerate 

Refrigerate 

Refrigerate 

Refrigerate 

Refrigerate 

Refrigerate 

Refrigerate 

Refrigerate 

Refrigerate 

Refrigerate 

Refrigerate 

Refrigerate 

Refrigerate 

Refrigerate 

Refrigerate 

Refrigerate 

Refrigerate 

Refrigerate 

Refrigerate 

Refrigerate 

Refrigerate 

Refrigerate 

Refrigerate 

Refrigerate 

Refrigerate 

Refrigerate 

Refrigerate 

Refrigerate 

Refrigerate 

Refrigerate 

Refrigerate 

Refrigerate 

Refrigerate 

Refrigerate 

Refrigerate 

Refrigerate 

Refrigerate 

Refrigerate 

Refrigerate 

Refrigerate 

Refrigerate 

Refrigerate 

Refrigerate 

Refrigerate 

Refrigerate 

Refrigerate 

ETS-8-044 sample prep 101230.xls Pag

e 3 of 5 
Sampl

e Id Description Prep Date 

GLP10-01-01-11-065 DAL GW 134S 0 101105 Aliquoted: 12/30/10 CJG toxic, Refrigerate 

GLP10-01-01-11-066 DAL GW134SDB 101105 Aliquoted: 12/30/10 CJG toxic, Refrigerate 

GLP10-01-01-11-067 DALGW134SLS101105 Aliquoted: 12/30/10 CJG toxic, Refrigerate 

GLP10-01-01-11-068 DAL GW134S MS 101105 Aliquoted: 12/30/10 CJG toxic, Refrigerate 

GLP10-01-01-11-069 DAL GW134SHS 101106 Aliquoted: 12/30/10 CJG toxic. Refrigerate 

GLP10-01-01-11-070 DALGW134L0101106(dil1:10) Aliquoted: 12/30/10CJG toxic, Refrigerate 

GLP10-01-01-11-071 DALGW134LDB101105(dil1:10) Aliquoted: 12/30/10CJG toxic, Refrigerate 

GLP10-01-01-11-072 DAL GW134LLS 101106 (dil 1:10) Aliquoted: 12/30/10 CJG toxic. Refrigerate 

GLP10-01-01-11-073 DALGW 134LMS 101106(dil 1:10) Aliquoted: 12/30/10 CJG toxic. Refrigerate 

GLP10-01-01-11-074 DALGW134LHS 101106(dil 1:10) Aliquoted: 12/30/10CJG toxic. Refrigerate 

GLP10-01-01-11-076 DAL GW135R 0 101106 (dil 1:100) Aliquoted: 12/30/10 CJG toxic. Refrigerate 

GLP10-01-01-11-076 DAL GW135RDB 101105(dil 1:100) Aliquoted: 12/30/10 CJG toxic, Refrigerate 

GLP10-01-01-11-077 DALGW135RLS 101106(dil 1:100) Aliquoted: 12/30/10CJG toxic. Refrigerate 

GLP10-01-01-11-078 DALGW136RHS 101105(dil 1:100) Aliquoted: 12/30/10CJG toxic. Refrigerate 

GLP10-01-01-11-079 DAL GW135S 0 101105 Aliquoted: 12/30/10 CJG toxic. Refrigerate 

GLP10-01-01-11-080 DAL GW135SDB 101105 Aliquoted: 12/30/10 CJG toxic. Refrigerate 

GLP10-01-01-11-081 DALGW135SLS101105 Aliquoted: 12/30/10 CJG toxic. Refrigerate 

GLP10-01-01-11-082 DAL GW135S MS 101105 Aliquoted: 12/30/10 CJG toxic. Refrigerate 

GLP10-01-01-11-083 DALGW135SHS101106 Aliquoted: 12/30/10 CJG toxic, Refrigerate 

GLP10-01-01-11-084 DAL GW136L 0 101105 (dil 1:100) Aliquoted: 12/30/10 CJG toxic. Refrigerate 

GLP10-01-01-11-085 DAL GW135LDB 101105 (dil 1:100) Aliquoted: 12/30/10 CJG toxic. Refrigerate 

GLP10-01-01-11-086 DAL GW135LLS 101105 (dil 1:100) Aliquoted: 12/30/10 CJG toxic. Refrigerate 

GLP10-01-01-11-087 DAL GW135L MS 101105 (dil 1:100) Aliquoted: 12/30/10 CJG toxic. Refrigerate 

GLP10-01-01-11-088 DAL GW136LHS 101105 (dil 1:100) Aliquoted: 12/30/10 CJG toxic. Refrigerate 

GLP10-01-01-11-089 DALGW 136S0 101103(dil 1:10) Aliquoted: 12/30/10CJG toxic. Refrigerate 

GLP10-01-01-11-090 DALGW136SDB 101103(dil1:10) Aliquoted: 12/30/10CJG toxic. Refrigerate 

GLP10-01-01-11-091 DALGW136SLS101103(dil1:10) Aliquoted: 12/30/10 CJG toxic. Refrigerate 

GLP10-01-01-11-092 DALGW136SMS101103(dil 1:10) Aliquoted: 12/30/10 CJG toxic. Refrigerate 

GLP10-01-01-11-093 DAL GW136SHS 101103 (dil 1:10) Aliquoted: 12/30/10 CJG toxic. Refrigerate 

GLP10-01-01-11-094 DALGW136L0101103(dil 1:10) Aliquoted: 12/30/10CJG toxic. Refrigerate 

GLP10-01-01-11-096 DALGW 136LDB 101103(dil 1:10) Aliquoted: 12/30/10CJG toxic. Refrigerate 

GLPl 0-01-01-11-096 DAL GW 136L LS 101103 (dil 1:10) Aliquoted: 12/30/10 CJG toxic. Refrigerate 

GLP10-01-01-11-097 DALGW 136LMS 101103(dil 1:10) Aliquoted: 12/30/10 CJG toxic. Refrigerate 

GLP10-01-01-11-098 DAL GW136LHS 101103 (dil 1:10) Aliquoted: 12/30/10 CJG toxic. Refrigerate 

GLP10-01-01-11-099 DAL GW137S 0 101109 Aliquoted: 12/30/10 CJG toxic. Refrigerate 

GLP10-01-01-11-100 DAL GW137SDB 101109 Aliquoted: 12/30/10 CJG toxic. Refrigerate 

GLP10-01-01-11-101 DAL GW137SLS 101109 Aliquoted: 12/30/10 CJG toxic. Refrigerate 

GLP10-01-01-11-102 DALGW137SMS101109 Aliquoted: 12/30/10 CJG toxic. Refrigerate 

GLP10-01-01-11-103 DALGW137SHS101109 Aliquoted: 12/30/10 CJG toxic. Refrigerate 

GLP10-01-01-11-104 DALGW 137L0 101109 Aliquoted: 12/30/10 CJG toxic. Refrigerate 

GLP10-01-01-11-106 DAL GW 137L DB 101109 Aliquoted: 12/30/10 CJG toxic. Refrigerate 

GLP10-01-01-11-106 DALGW 137LLS 101109 Aliquoted: 12/30/10 CJG toxic. Refrigerate 

GLP10-01-01-11-107 DALGW 137LMS 101109 Aliquoted: 12/30/10 CJG toxic. Refrigerate 

GLP10-01-01-11-108 DALGW 137LHS 101109 Aliquoted: 12/30/10 CJG toxic. Refrigerate 

GLP10-01-01-11-109 DAL GW138S 0 101110 (dil 1:10) Aliquoted: 12/30/10 CJG toxic. Refrigerate 

GLP10-01-01-11-110 DAL GW138SDB 101110 (dil 1:10) Aliquoted: 12/30/10 CJG toxic. Refrigerate 

GLP10-01-01-11-111 DAL GW138SLS 101110 (dil 1:10) Aliquoted: 12/30/10 CJG toxic. Refrigerate 

GLP10-01-01-11-112 DALGW138SMS101110(dil1:10) Aliquoted: 12/30/10 CJG toxic. Refrigerate 

GLP10-01-01-11-113 DAL GW138SHS 101110 (dil 1:10) Aliquoted: 12/30/10 CJG toxic. Refrigerate 

GLP10-01-01-11-114 DALGW 138L0 101110 Aliquoted: 12/30/10 CJG toxic. Refrigerate 

GLP10-01-01-11-115 DALGW 138LDB 101110 Aliquoted: 12/30/10 CJG toxic. Refrigerate 

GLP10-01-01-11-116 DALGW 138LLS 101110 Aliquoted: 12/30/10 CJG toxic. Refrigerate 

GLP10-01-01-11-117 DALGW 138LMS 101110 Aliquoted: 12/30/10 CJG toxic. Refrigerate 

GLP10-01-01-11-118 DALGW 138LHS 101110 Aliquoted: 12/30/10 CJG toxic. Refrigerate 

GLP10-01-01-11-119 DALGWCW26R0 101110 (dil 1:10) Aliquoted: 12/30/10 CJG toxic. Refrigerate 

GLP10-01-01-11-120 DAL GWCW26RDB 101110 (dil 1:10) Aliquoted: 12/30/10 CJG toxic. Refrigerate 

GLP10-01-01-11-121 DAL GWCW26RLS 101110 (dil 1:10) Aliquoted: 12/30/10 CJG toxic. Refrigerate 

GLP10-01-01-11-122 DALGWCW26RMS 101110(dil 1:10) Aliquoted: 12/30/10 CJG toxic. Refrigerate 

GLP10-01-01-11-123 DAL GWCW26RHS 101110 (dil 1:10) Aliquoted: 12/30/10 CJG toxic. Refrigerate 

GLP10-01-01-11-124 DALGWCW26L0 101110 (dil 1:10) Aliquoted: 12/30/10 CJG toxic. Refrigerate 

GLP10-01-01-11-126 DAL GWCW26LDB 101110 (dil 1:10) Aliquoted: 12/30/10 CJG toxic. Refrigerate 

GLP10-01-01-11-126 DAL GWCW26LLS 101110 (dil 1:10) Aliquoted: 12/30/10 CJG toxic. Refrigerate 

GLP10-01-01-11-127 DALGWCW26LMS101110(dil1:10) Aliquoted: 12/30/10 CJG toxic. Refrigerate 

GLP10-01-01-11-128 DALGWCW26LHS101110(dil1:10) Aliquoted: 12/30/10 CJG toxic. Refrigerate 

GLP l 0-01-01-11-129 DAL GW140R 0 101104 (dil 1:10) Aliquoted: 12/30/10 CJG toxic. Refrigerate 

GLPl 0-01-01-11-130 DAL GW140RDB 101104 (dil 1:10) Aliquoted: 12/30/10 CJG toxic. Refrigerate 

GLPl 0-01-01-11-131 DAL GW140RLS 101104 (dil 1:10) Aliquoted: 12/30/10 CJG toxic. Refrigerate 

GLP10-01-01-11-132 DAL GW140R MS 101104 (dil 1:10) Aliquoted: 12/30/10 CJG toxic. Refrigerate 

GLP10-01-01-11-133 DAL GW140RHS 101104 (dil 1:10) Aliquoted: 12/30/10 CJG toxic. Refrigerate 

GLP10-01-01-11-134 DAL GW141R 0 101110 (dil 1:10) Aliquoted: 12/30/10 CJG toxic. Refrigerate 

GLP10-01-01-11-135 DAL GW141RDB 101110 (dil 1:10) Aliquoted: 12/30/10 CJG toxic. Refrigerate 

GLP10-01-01-11-136 DAL GW141RLS 101110 (dil 1:10) Aliquoted: 12/30/10 CJG toxic. Refrigerate 

GLP10-01-01-11-137 DAL GW141R MS 101110 (dil 1:10) Aliquoted: 12/30/10 CJG toxic, Refrigerate 

GLP10-01-01-11-138 DALGW141RHS101110(dil1:10) Aliquoted: 12/30/10 CJG toxic, Refrigerate 

GLP10-01-01-11-139 DAL GW142R 0 101110 (dil 1:10) Aliquoted: 12/30/10 CJG toxic, Refrigerate 

GLP10-01-01-11-140 DALGW142RDB 101110(dil 1:10) Aliquoted: 12/30/10 CJG toxic. Refrigerate 

GLP10-01-01-11-141 DAL GW142RLS 101110 (dil 1:10) Aliquoted: 12/30/10 CJG toxic, Refrigerate 

GLP10-01-01-11-142 DAL GW142R MS 101110 (dil 1:10) Aliquoted: 12/30/10 CJG toxic. Refrigerate 

GLP10-01-01-11-143 DAL GW142RHS 101110 (dil 1:10) Aliquoted: 12/30/10 CJG toxic. Refrigerate 

GLP10-01-01-11-144 DAL GW144R 0 101110 (dil 1:10) Aliquoted: 12/30/10 CJG toxic. Refrigerate 

GLP10-01-01-11-146 DALGW144RDB101110(dil1:10) Aliquoted: 12/30/10 CJG toxic. Refrigerate 

GLP10-01-01-11-146 DALGW144RLS101110(dil1:10) Aliquoted: 12/30/10 CJG toxic. Refrigerate 

GLP10-01-01-11-147 DAL GW144R MS 101110 (dil 1:10) Aliquoted: 12/30/10 CJG toxic, Refrigerate 

GLP10-01-01-11-148 DALGW144RHS101110(dil1:10) Aliquoted: 12/30/10 CJG toxic. Refrigerate 

GLP10-01-01-11-149 DAL GW144RRB 101110 Aliquoted: 12/30/10 CJG toxic. Refrigerate 

ETS-8-044 sample prep 101230.xls label Pag

e 4 of 5 
Sample Id 

GLP10-01-01 

GLP10-01-01 

GLP10-01-01 

GLP10-01-01 

GLP10-01-01 

GLP10-01-01 

GLP10-01-01 

GLP10-01-01 

GLP10-01-01 

GLP10-01-01 

GLP10-01-01 

GLP10-01-01 

GLP10-01-01 

GLP10-01-01 

GLP10-01-01 

GLP10-01-01 

GLP10-01-01 

GLP10-01-01 

GLP10-01-01 

GLP10-01-01 

GLP10-01-01 

11-160 

11-161 

11-152 

11-163 

11-164 

11-166 

11-156 

11-157 

11-158 

-11-159 

11-160 

11-161 

11-162 

11-163 

11-164 

11-165 

-11-166 

11-167 

-11-168 

11-169 

12-009 

Description 

Trip Blank Set 

Trip Blank Set 

Trip Blank Set 

Trip Blank Set 

Trip Blank Set 

Trip Blank Set 

Trip Blank Set 

Trip Blank Set 

Trip Blank Set 

Trip Blank Set 

Trip Blank Set 

Trip Blank Set 

Trip Blank Set 

Trip Blank Set 

Trip Blank Set 

Trip Blank Set 

Trip Blank Set 

Trip Blank Set 

Trip Blank Set 

Trip Blank Set 

DAL SS 607R 

1 Sample 

1 LS 

1 MS 

1 MHS 

1 HS (dil 1:100) 

2 Sample 

2LS 

2 MS 

2 MHS 

2 HS (dil 1:100) 

3 Sample 

3LS 

3 MS 

3 MHS 

3 HS (dil 1:100) 

4 Sample 

4LS 

4 MS 

4 MHS 

4HS(dil 1:100) 

RB0040 

Prep Date 

Aliquoted: 

Aliquoted: 

Aliquoted: 

Aliquoted: 

Aliquoted: 

Aliquoted: 

Aliquoted: 

Aliquoted: 

Aliquoted: 

Aliquoted: 

Aliquoted: 

Aliquoted: 

Aliquoted: 

Aliquoted: 

Aliquoted: 

Aliquoted: 

Aliquoted: 

Aliquoted: 

Aliquoted: 

Aliquoted: 

Aliquoted: 

12/30/10 CJG 

12/30/10 CJG 

12/30/10 CJG 

12/30/10 CJG 

12/30/10 CJG 

12/30/10 CJG 

12/30/10 CJG 

12/30/10 CJG 

12/30/10 CJG 

12/30/10 CJG 

12/30/10 CJG 

12/30/10 CJG 

12/30/10 CJG 

12/30/10 CJG 

12/30/10 CJG 

12/30/10 CJG 

12/30/10 CJG 

12/30/10 CJG 

12/30/10 CJG 

12/30/10 CJG 

12/30/10 CJG 

toxic. Refrigerate 

toxic. Refrigerate 

toxic. Refrigerate 

toxic. Refrigerate 

toxic. Refrigerate 

toxic. Refrigerate 

toxic. Refrigerate 

toxic. Refrigerate 

toxic, Refrigerate 

toxic. Refrigerate 

toxic. Refrigerate 

toxic, Refrigerate 

toxic. Refrigerate 

toxic. Refrigerate 

toxic. Refrigerate 

toxic. Refrigerate 

toxic. Refrigerate 

toxic. Refrigerate 

toxic. Refrigerate 

toxic, Refrigerate 

toxic. Refrigerate 

ETS-8-044 sample prep 101230.xls label Page 5 of 6 
Analytical Case Narrative 

Data Reduction Calculations 

Control Chart - Analytical 

Uncertainty 
3M ENVIRONMENTAL LABORATORY 

Note to File 

Project or Study Number: 

LIMS Number: 

Affected Data: 

GLPlO-01-01-11 

GLPlO-01-01-11 

None 

All logbook pages for the individual stock standards and mixes used for the calibration curves 

and LCS used for the analysis of GLP10-01-01-11 were printed to pdf (exact copies of originals) 

and included in a folder labeled 'Logbook pages' located in the project folder located at: 

\\Winsnas01a\b2\Projects\Lab_ESA Analytical\Lab Requests 2010 - stw\GLP10-01 Decatur 

Phase 3\GLP10-01-01 PFOA\GLP10-01-01-11 On-site FSIA Wells - Oct\Logbook pages 

The chromatograms for results file b110103a were printed to pdf and saved in the project folder 

located at: 

\\Winsnas01a\b2\Projects\Lab_ESA AnalyticalVLab Requests 2010 - stw\GLP10-01 Decatur 

Phase 3\GLP10-01-01 PFOA\GLP10-01-01-11 On-site FSIA Wells - Oct\b110103a 

A pdf copy of the signed protocol amendment GLP10-01-01 Amendment 11 is located in the 

project folder located at: 

\\Winsnas01a\b2\Projects\Lab_ESA Analytical\Lab Requests 2010 - stw\GLP10-01 Decatur 

Phase 3\GLP10-01-01 PFOA\ GLPlO-01-01-11 On-site FSIA Wells - Oct 

Once the data package has been reviewed by QA and the report signed, the pdf will be moved to 

the shared drive (\\Winsnas01a\b2\Projects\Lab_Shared\Archive Requests\Electronic Reports) 

and a reference to the location of the pdf will be added to the archived request form under Elec 

Media Path. 

Recorded By: Date: 

Page 1 of 1 
3M Confidential 

RECORD OF DEVIATION/NONCONFORMANCE 

/. Identification 

Study / Project No. Date(s) of Occurrence: Document Number: 

GLPlO-01-01-11 1-3-11 ETS-8-044.0 

Deviation type IZl SOP D Equipment Procedure D Method 

(Check one) D Protocol D GPO D Other: 

//. Description (attach extra pages as needed) 

MethocJ Requirements: 

1. LCS average recoveries within ± 20% (section 10.5). 

2. FMS recoveries within ± 30% (section 10.6) 

Actual procedure/process: 

1. The average PFOA recovery for the 5 ppb ECF LCS was 123%. 

2. The high FMS recovery for sample DAL GW 134R was 69.1%. 

///, Actions Taken 

(such as amendment issued, SOP revision, etc.) 

Corrective Action (D Yes 0 No) Reference: 

Acceptability of the nonconforming work: 

1. Low, mid, and high sets of linear, and linear + branched (ECF) LCS samples were prepared and analyzed 

with the samples. All sets met rhethod acceptance criteria with the exception of the mid level ECF LCS. 

The linear + branched PFOA LCS, when quantitated against calibration curve point prepared from linear 

PFOA, have been quantitating around 5-15% higher. The recovery for the 5 ppb ECF LCS (123%) will be 

flagged in the final report. All LCS were used in the determination of method analytical uncertainty. 

2. The FMS recovery for the sample outside the acceptance criteria will be flagged in the final report. The 

method uncertainty for PFOA will be adjusted according. 

Actions: D Halting of Work D Client Notification D Work Recall D Withholding of Report 

0 Other: Deviations will be noted in final report. 

Project Lead/PAI Approval: f) ^ Date:, , 

study Director (if GLP): ^"^^kS^ Datey^// 

Sponsor Approval (for GLP protocol deviations): NA Date: NA 

Technical Reviewer (optional): NA Date: NA 

Laboratory Department Manager Approval: Date: 

IV. Authorization to Resume Work 

Where halting of work occurred, resumption of work must first be approved by Laboratory Management 

Laboratory Department Manager Approval: « Date: A 

Deviation No. 

(assigned by Study Director or Team Leader atthe end of study or project) 

Attachment A ETS-4-008.7 • Page 1 of 1 

Documentation of Deviations and Control of Nonconforming Testing 
P:\Projects\Lab_Shared\Control Charts\ETS-8-044 LCMS Direct 

Date 

9/27/2010 

9/27/2010 

9/27/2010 

9/27/2010 

9/27/2010 

9/27/2010 

9/27/2010 

9/27/2010 

9/27/2010 

9/27/2010 

9/27/2010 

9/27/2010 

9/27/2010 

9/27/2010 

10/25/2010 

10/25/2010 

10/25/2010 

10/25/2010 

10/25/2010 

10/25/2010 

10/25/2010 

10/25/2010 

10/25/2010 

10/25/2010 

10/25/2010 

10/25/2010 

11/4/2010 

11/4/2010 

11/4/2010 

11/4/2010 

11/4/2010 

11/4/2010 

1/3/2011 

1/3/2011 

1/3/2011 

1/3/2011 

1/3/2011 

1/3/2011 

1/3/2011 

1/4/2011 

1/4/2011 

1/4/2011 

1/4/2011 

1/4/2011 

1/4/2011 

1/4/2011 

1/4/2011 

1/4/2011 

1/4/2011 

1/4/2011 

Analyte 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

Project 

E10-0535 CG 

E10-053S CG 

E10-0S3S CG 

E10-053SCG 

E10-0535CG 

E10-053SCG 

E10-053SCG 

E10-0S3S CG 

E10-0S3SCG 

E10-0S3SCG 

E10-0S3S CG 

E10-0S3S CG 

E10-0S3S CG 

El 0-0535 CG 

GLP10-01-01-

GLP10-01-01-

GLP10-01-01-

GLP10-01-01-

GLP10-01-01-

GLPip-01-01-

GLP10-01-01-

GLP10-01-01-

GLP10-01-01-

GLP10-01-01-

GLP10-01-01-

GLP10-01-01-

GLP10-01-01-

GLP10-01-01-

GLP10-01-01-

GLP10-01-01-

GLP10-01-01-

GLP10-01-01-

GLP10-01-01-

GLP10-01-01-

GLP10-01-01-

GLP10-01-01-

GLP10-01-01-

GLP10-01-01-

GLP10-01-01-

GLP10-01-01-

GLP10-01-01-

GLP10-01-01-

GLP10-01-01-

GLP10-01-01-

GLP10-01-01-

GLP10-01-01-

GLP10-01-01-

GLP10-01-01-

GLP10-01-01-

GLP10-01-01-

Stormwater 

Stormwater 

Stormwater 

Stormwater 

Stormwater 

Stormwater 

stormwater 

stormwater 

stormwater 

stormwater 

stormwater 

stormwater 

stormwater 

Stormwater 

09 Dec 3rd Qtr GW 

09 Dec 3rd Qtr GW 

09 Dec 3rd Qtr GW 

09 Dec 3rd Qtr GW 

09 Dec 3rd Qtr GW 

09 Dec 3rd Qtr GW 

09 Dec 3rd Qtr GW 

09 Dec 3rd Qtr GW 

09 Dec 3rd Qtr GW 

09 Dec 3rd Qtr GW 

09 Dec 3rd Qtr GW 

09 Dec 3rd Qtr GW 

09 Dec 3rd Qtr GW 

09 Dec 3rd Qtr GW 

09 Dec 3rd Qtr GW 

09 Dec 3rd Qtr GW 

09 Dec 3rd Qtr GW 

09 Dec 3rd Qtr GW 

11 On-Site FSIA Wells 

11 On-Site FSIA Wells 

11 On-Site FSIA Wells 

11 On-Srte FSIA Wells 

11 On-Site FSIA Wells 

11 On-Site FSIA Wells 

11 On-SKe FSIA Wells 

11 On-Site FSIA Wells 

11 On-SHe FSIA Wells 

11 On-Site FSIA Wells 

11 On-Site FSIA Wells 

11 On-Site FSIA Wells 

11 On-Site FSIA Wells 

11 On-Site FSIA Wells 

11 On-Site FSIA Wells 

11 On-Site FSIA Wells 

11 On-Site FSIA Wells 

11 On-Site FSIA Wells 

Inject 

Prep Analyst 

kje 

kje 

kje 

kje 

kje 

kje 

kje 

kje 

kje 

kje 

kje 

kje 

kje 

kje 

stw 

stw 

stw 

stw 

stw 

stw 

stw 

stw 

stw 

stw 

stw 

stw 

cjg 

cjg 

cjg 

cjg 

cjg 

cjg 

cjg 

cjg 

cjg 

cjg 

cjg 

cjg 

cjg 

cjg 

cjg 

cjg 

cjg 

cjg 

cjg 

cjg 

cjg 

cjg 

cjg 

cjg 

LC/MS Analyst 

kje 

kje 

kje 

kje 

kje 

kje 

kje 

kje 

kje 

kje 

kje 

kje 

kje 

kje 

stw 

stw 

stw 

stw 

stw 

stw 

stw 

stw 

stw 

stw 

stw 

stw 

cjg 

cjg 

cjg 

cjg 

cjg 

cjg 

cjg 

cjg 

cjg 

cjg 

cjg 

cjg 

cjg 

cjg 

cjg 

cjg 

cjg 

cjg 

cjg 

cjg 

cjg 

cjg 

cjg 

cjg 

Instrument 

Buster 

Buster 

Buster 

Buster 

Buster 

Buster 

Buster 

Buster 

Buster 

Buster 

Buster 

Buster 

Buster 

Buster 

Ginger 

Ginger 

Ginger 

Ginger 

Ginger 

Ginger 

Ginger 

Ginger 

Ginger 

Ginger 

Ginger 

Ginger 

Buster 

Buster 

Buster 

Buster 

Buster 

Buster 

Buster 

Buster 

Buster 

Buster 

Buster 

Buster 

Buster 

Buster 

Buster 

Buster 

Buster 

Buster 

Buster 

Buster 

Buster 

Buster 

Buster 

Buster 

t Sample ID 

LCS-100927-5 

LCS-100927-6 

LCS-100927-13 

LCS-100927-14 

LCS-100927-15 

LCS-100927-7 ECF 

LCS-100927-8 ECF 

LCS-100927-9 ECF 

LCS-100927-10 ECF 

LCS-100927-11 ECF 

LCS-100927-12 ECF 

LCS-100927-16 ECF 

LCS-100927-17 ECF 

LCS-100927-18 ECF 

LCS-101020-1 

LCS-101020-2 

LCS-101020-3 

LCS-101020-4 

LCS-101020-5 

LCS-101020-6 

LCS-101020-7 ECF 

LCS-101020-8 ECF 

LCS-101020-9 ECF 

LCS-101020-10 ECF 

LCS-101020-11 ECF 

LCS-101020-12ECF 

LCS-101104-01 

LCS-101104-02 

LCS-101104-03 

LCS-101104-04ECF 

LCS-101104-05ECF 

LCS-101104-06 ECF 

LCS-101230-1 

LCS-101230-2 

LCS-101230-3 

LCS-101230-4 

LCS-101230-5 

LCS-101230-8 

LCS-101230-7 

LCS-101230-8 

LCS-101230-9 

LCS-101230-10 

LCS-101230-11 

LCS-101230-12 

LCS-101230-13 

LCS-101230-14 

LCS-101230-15 

LCS-101230-16 

LCS-101230-17 

LCS-101230-18 

True Value, ng/mL Recovered value ng/mL % 

1.9800 

1.9800 

19.9000 

19.9000 

19.9000 

0.1980 

0.1980 

0.1980 

1.9900 

1.9900 

1.9900 

19.8000 

19.8000 

19.8000 

2.0000 

2.0000 

2.0000 

20.0000 

20.0000 

20.0000 

2.0000 

2.0000 

2.0000 

20.0000 

20.0000 

20.0000 

2S.0000 

25.0000 

25.0000 

25.0000 

25.0000 

25.0000 

0.4970 

0.4970 

0.4970 

4.9700 

4.9700 

4.9700 

30.0000 

30.0000 

30.0000 

0.4980 

0.4980 

0.4980 

5.0000 

5.0000 

S.OOOO 

30.0000 

30.0000 

30.0000 

Average 

1.82 

1.71 

16.8 

17.8 

18.8 

0.193 

0.211 

0.192 

1.91 

1.96 

1.94 

19.0 

18.2 

19.9 

2.13 

2.03 

2.1S 

18.8 

19.5 

19.9 

2.33 

2.54 

2.35 

23.9 

23.9 

22.3 

25.7 

25.8 

26 

27.2 

27.2 

26.9 

0.S8 

0.SS7 

0.59 

5.83 

S.69 

5.6S 

25.6 

25.8 

25.7 

0.546 

0.553 

0.541 

6.29 

6.03 

6.12 

31.3 

30.8 

30.6 

Standard Deviation 

Std Dev *2 

Recovery Comments 

92.0 

86.6 

84.7 

89.3 

94.7 

97.6 

106 

97.2 

95.8 

98.7 

97.4 

96.1 

91.8 

101 

107 

102 

108 

93.9 

97.6 

99.5 

117 

127 

118 

119 

119 

112 

103 

103 

104 

109 

109 

108 

117 

112 

119 

117 

115 

114 

85.3 

86.0 

85.6 

110 

111 

109 

126 

121 

122 

104 

103 

102 

105 

11.3 

22.6 

Metiiod Uncertainty GLP10-01-01-11.xls PFOA Page 1 of 1 

CDS hlS'l l 
3M Confidential 3M Environmental Laboratory 

Project: GLPlO-01-01-11 

Sequence b110103a 

3M Environmental Laboratory 

3M Technical Lead: Susan Wolf 

Building 260-5N-17 

651-733-9851 

Report Author Cheisie Grochow 

Analytical Team: 

Susan Wolf 

Analytical Case Narrative for Method ETS-8-44.0 

Project GLP10-01-01-11 

Decatur Phase 3 - On site FSIA Groundwater - October 2010 

Direct injection analysis of samples 

Sequence b110103a 

Report Date: January 14, 2011 

Instrument summary and calibration curves will be printed and included in the raw data package. 

Chromatograms will be printed to pdf. 

ETS 8-044 Analytical Summary Checklist Page 1 of 3 
3M Confidential 

1 Project Scope and Data Quality Objective 

3M Environmental Laboratory 

Project: GLPlO-01-01-11 

Sequence b110103a 

General Project Outline available. 

GLP 

^Ye s 

El Yes 

D No 

D No 

If No, Please briefly describe 

project scope and DQO 

2 Sample Container Preparation 

Sample container preparation documented in a Note to File included in the raw data package. 

3 Sample Analysis 

3.1 System Suitability 

Initial System Suitability area counts with RSD <5% and retention time with 

RSD <2% 13 Yes D N O 

3.1.1 System Suitability Deviations 

NA. 

3.2 Instrument Calibration 

Curve type 

r^>0.990 Linearity criteria met (ETS-8-44 section 12.2) 

< ± 25% residuals, except LOQ of ±30% (ETS-8-44 section 12.2) 

Mid-level calibration points disabled 

Quadratic, 1/x 

jgjYes 

13 Yes 

DYe s 

D N O 

D N O 

KJNo 

The two highest calibration standards were deactivated to meet accuracy criteria. 

3.3 Continuing Calibration Verification 

+25% Difference criteria met for periodic CCVs (ETS-8-44 section 12.2) ^Ye s D N O 

3.3.1 Continuing Calibration Verification Deviations 

NA. 

3.4 Method Blanks 

Method blanks uniquely identified in the run sequence. 

Average area counts of target analytes in the method blank present at > Vi x 

the area counts ofthe LOQ standard (b 1S-8-44 Section 10.2) 

13 Yes 

SYe s 

D N o 

D N O 

3.4.1 Method Blank Deviations 

NA. 

ETS 8-044 Analytical Summary Checklist Page 2 of 3 
3M Confidential 

3.5 Lab Control Spikes 

3M Environmental Laboratory 

Project: GLPlO-01-01-11 

Sequence b110103a 

±20% recovery criteria met (ETS 8-44 Section 10.5) 

<20% RSD precision (ETS 8-44 Section 10.5) 

DYe s 

El Yes 

13 No 

D N O 

3.5.1 Lab Control Spike Deviations 

The ECF PFOA recovery ofthe 5 ppb LCS had an average recovery of 123%. 

3.6 Sample Replicates 

RPD for field duplicates <20% (ETS-8-44 Section 10.5) El Yes D N O 

3.6.1 Sample Replicates Deviations 

NA 

3.7 Field Matrix Spikes 

±30% recovery criteria met. (ETS 8-44 Section 10.5) DYe s El NO 

3.7.1 Field Matrix Spike Deviations 

134R; The high FMS recovery was 69.1%, 

No appropriate spike level for 131R, and 135R. 

3.8 Limit of Quantitation (LOQ) 

All LOQs equal the low-level calibration standard concentration 

with area counts at least twice that of the method blank(s) (ETS 8-

44 Section 10.2) 

El Yes D N o 

3.9 Manual Integrations 

Manual integration reviewed by another analyst/team lead: 

Reviewed by: ^ Date:_L |g \ II El Yes D N O 

4 Additional analytical notes 

Samples 132L MS and HS and all 134L samples were re-injected within the analytical batch run at a higher 

dilution factor since the first injections were above the ULOQ. Sample 141R and the corresponding duplicate and 

Low Spike were re-injected at a lower dilution factor since the first injections of the sample and sample duplicate 

were near the LLOQ. Only the re-injected sample results will be reported. 

All other data will be reported from this run. 

5 Signatures 

aiAlhUL '^/lAV-hATUj t'l^'l l 

Analyst Date 

ETS 8-044 Analytical Summary Checklist Page 3 of 3 
Buster: API4000: J2930203 page 1/1 

DATE 01/03/11 

ANALYST: CJG 

STUDY NUMBER: GLPlO-01-01-11 Matrix: water 

Injection volume: 10 uL Electrode: turbo ion spray 

LC/MS/MS method: PFOA only 

Mobile Phase: (A) 2mM ammonium acetate (B) Methanol 

TN-A- or standard number (A) 10 010-61 (B) TNlO-0448-2/8 

Guard (pre-autosampler) column Prism RP 

Size: 2.1 mm X 50 mm Type: C12 Sphere size: 5 

Part number: 32105-052130 Lot number: 9411 Serial number 0903541V Started 10-29-10 

Analytical column betasil €18 

Size: 2.1 mm X 100 mm Type: €18 Sphere size: 5 

Part number: 70105-102130 Lot number: 10683 Serial number 1000992T Started 10-29-10 

Data File: bl 10103a 

S^mpl^ bnOiO^bSXH H(X^ hM-elx/ injec-^ed bu-f five 

da+A •fi\^ fT>r -l-hjs '^aYTip)c could nc^i- be reiiovered 

diuciiD a computer ennDr. cj a i-ii-w 

A\SO, +tie [ac.'i--h^o CJLMS vvTtr^ \f\a.d^^^-fer\-^y^ injecfed 

(X^ 5juL inst-«<^cl t-^ /D|aL. The aiiutio n factor \NaSi 

Printed: Monday, January 03, 2011 10:21 AM 

c j e I'll-II 
*Buster J2330203 

PtDJect: P:\PrajectsiLab_lnstmment DataVBustertBuster Data\Projects\fluorD 

Sample 

1 

2 1 

3 

4 

5 

6 

7 

8 

9 

10 

11 

12 

13 

14 

15 

16 

17 

18 

19 

20 

21 

22 

23 

24 

25 

26 

27 

28 

29 

30 

31 

32 

33 

34 

35 

36 

37 

38 

39 

40 

41 

42 

43 

44 

45 

46 

47 

48 

49 

50 

51 

52 

53 

54 

55 

56 

Sample Name 

b110103a001 

bl101033002 

bl101038003 

bl101033004 

bl101033005 

bl101033006 

bl101033007 

bl101033008 

bl101033009 

bl101033010 

b1101033011 

bl101033012 

bl101033013 

bl101033014 

bl101033015 

bl101033016 

bl101033017 

bl101033018 

bl101033019 

bl101033020 

bl101033021 

bl101033022 

bl101033023 

bl 101033024 

bl101033025 

bl101033026 

bl101033027 

bl101033028 

bl101033029 

b1101033030 

bl101033031 

bl101033032 

bl101033033 

bl101033034 

bl101033035 

bl101033036 

bl101033037 

bl101033038 

bl101033039 

bl101033040 

bl101033041 

b110103a042 

bl101033043 

bl101033044 

bl101033045 

b110103a046 

bl101033047 

bl101033048 

bl101038049 

bl101033050 

bl101038051 

bl101033052 

bl101033053 

bl101033054 

bl101033055 

bl101033056 

Sample ID 

Solvent Blank (MIIIIQ Bement) 

Solvent BIsnk (MIIIIQ Bement) 

Solvent Blank (MlliQ Bement) 

Solvent Btenk (MlliQ Bement) 

Solvent BIsnk (MlliQ Bement) 

Solvent Bl3nk (MlliQ Bement) 

08008-194-11 system suit 

08008-194-11 system suit 

08008-194-11 system suit 

08008-194-11 system suit 

Solvent Bl3nk (MlliQ Bement) 

Solvent Bl3nk (MlliQ Benrent) 

08008-194-1 

08008-194-2 

08008-194-3 

08008-194-4 

08008-194-5 

08008-194-6 

08008-194-7 

08008-194-8 

08008-194-9 

08008-194-10 

08008-194-11 

08008-194-12 

08008-194-13 

08008-194-14 

08008-194-15 

Solvent Bl3nk (MlliQ Bement) 

Solvent Blank (MlliQ Bement) 

Solvent Bl3nk (MlliQ Bement) 

08008-194-10 

Solvent Blank (MlliQ Bement) 

LCS-101230-1 

LCS-101230-2 

LCS-101230-3 

LCS-101230-4 

LCS-101230-5 

LCS-101230-6 

LCS-101230-7 

LCS-101230-8 

LCS-101230-9 

Solvent Blank (MlliQ Bement) 

Solvent Bl3nk (MlliQ Bement) 

08008-194-9 

Solvent Bl3nk (MlliQ Bement) 

LCS-101230-10 

LCS-101230-11 

LCS-101230-12 

LCS-101230-13 

LCS-101230-14 

LCS-101230-15 

LCS-101230-16 

LCS-101230-17 

LCS-101230-18 

Solvent BIsnk (MlliQ Bement) 

Solvent BIsnk (MlliQ Bement) 

Vial Position 

91 

91 

91 

91 

91 

91 

11 

11 

11 

11 

91 

91 

1 

2 

3 

4 

5 

6 

7 

8 

9 

10 

11 

12 

13 

14 

15 

91 

92 

92 

10 

92 

16 

17 

18 

19 

20 

21 

22 

23 

24 

92 

93 

9 

93 

25 

26 

27 

28 

29 

30 

31 

32 

33 

93 

94 

nchemicals\water Batch:b110103a 

Data File 

bl 101033 

bl 101033 

bl 101033 

bl 101033 

bl 101033 

bl 101033 

bl 101033 

bl 101033 

bl 101033 

bl 101033 

bl 101033 

bl 101038 

bl 101033 

bl 101033 

bl 101033 

b1101033 

bl 101033 

b1101033 

bl 101033 

bl 101033 

bl 101033 

bl 10103a 

bl 101033 

bl 10103a 

bl 10103a 

bl 101038 

bl 101033 

bl 101033 

bl 101033 

bl 101033 

bl 101033 

bl 101033 

bl 101033 

bl 101033 

bl 101033 

b1101033 

bl101038 

b1101038 

b1101033 

b1101033 

b1101038 

bl101033 

bl101033 

bl101033 

bl101033 

bl101033 

bl101033 

bl101038 

bl101038 

bl101038 

bl101033 

bl101038 

bl101033 

bl101038 

bl101033 

bl101038 

Inj.Volume (pi) 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

Tab:Sample Set:SET1 AcqMethod:PFOA 

Comment s 

MlliQ\/\feter TNI 0-0475 

Mill Q\Afeter TNI 0-0475 

Mill QW^ter TNI 0-0475 

Mill QV\feiter TNI 0-0475 

MlliQVifeiter TNI 0-0475 

Mill QVVfeiter TNI 0-0475 

10 ng/mL FC std in Mill Q \Afater 

10 ng/mL FC std in Mill Q Water 

10 ng/mL FCsld in Mill Q Water 

10 ng/mL FC std in Mlli Q W^ter 

MlliQ Water TNI 0-0475 

MlliQ Water TNI 0-0475 

0.025 ng/mL FC std in Mlli Q V\feiter 

0.03 ng/mL FC std in Mill Q V\fater 

0.04 ng/mL FC std in Mill 0 V\fater 

0.05 ng/mL FC std in Mlli Q V\fater 

0.1 ng/mL FC std in Mlli 0 W^ter 

0.25 ng/mL FC std In Mlli Q V\fater 

0.5 nglrrt FC std In Mlli Q V\feter 

1.0 ng/mLFC std in Mlli Q\Afeter 

2.5 ng/mL FC std in Mlli Q \rtfeter 

5.0 ng/mL FC std in Mlli Q Water 

10 ng/mL FC std in Mlli Q W^ter 

25 ng/mL FC std in Mlli Q Waiter 

50 ng/mL FC std in Mlli Q Wfeiter 

75 ng/mL FC std in Min Q Water 

100 ng/mL FC std in Mlli Q Wfeiter 

Mlli QWfeiter TNI 0-0475 

Mlli QW&ter TNI 0-0475 

Mlli QW&ter TNI 0-0475 

5.0 ng/mL FC std in Mlli Q Water 

Mlli QW^ter TNI 0-0475 

O.Sppb LCS 

0.5ppb LCS 

0.5ppb LCS 

5ppb LCS 

Sppb LCS 

Sppb LCS 

30ppb LCS 

30ppb LCS 

30ppb LCS 

MlliQ Water TNI 0-0475 

Mlli QWfeiter TNI 0-0475 

2.5 ng/mL FC std in Min Q Wfeiter 

Min Q Water TNI 0-0475 

O.Sppb LCS ECF 

O.Sppb LCS ECF 

O.Sppb LCS ECF 

Sppb LCS ECF 

Sppb LCS ECF 

Sppb LCS ECF 

30ppb LCS ECF 

30ppb LCS ECF 

30ppb LCS ECF 

Min QW^ter TNI 0-0475 

Min Q Water TNI 0-0475 

only.dam 

Printing Time: 10:22:59 AM 

Printing Date: Monday, January 03, 2011 

Page 1 of 6 

(oroi-ii-ii 
*Buster J2930203 

PtDJect: P:\Projectsi\Lab_lnstrument Data\BustertBusterData\Projects\fluororchemicals\waterBatch;b110103a 

Sample 

57 

58 

59 

60 

61 

62 

63 

64 

65 

66 

67 

68 

69 

70 

71 

72 ; 

73 

74 

75 

76 

77 

78 

79 

80 

81 

82 

83 

84 

85 

86 

87 

88 • 

89 

90 

91 

92 

93 

94 

95 

96 

97 

98 

99 

100 

101 

102 

103 

104 

105 

106 

107 

108 

109 

110 

111 

112 

Sample Name 

bl101038057 

bl 101038058 

bl101038059 

bl101038060 

bl 101038061 

bl101033062 

bl101038063 

bl101033064 

bl101033065 

b1101033066 

bl101033067 

bl101033068 

bl101038069 

bl101038070 

bl101038071 

bl101038072 

b110103a073 

bl 101038074 

bl 101033075 

bl 101033076 

bl 101033077 

bl101033078 

bl101033079 

bl101033080 

bl 101033081 

bl101033082 

bl101033083 

bl101033084 

bl101033085 

bl101033086 

bl101033087 

bl101033088 

bl101033089 

bl101033090 

bl101033091 

bl101033092 

bl101033093 

bl101038094 

bl101038095 

b110103a096 

b110103a097 

bl101038098 

bl101033099 

bl101038100 

b1101038l01 

bl101038102 

b1101033l03 

b1101038lO4 

b1101038lOS 

b1101038l06 

b1101038l07 

bl101038108 

bl101033109 

b1101038l10 

b1101033l11 

b1101033l12 

Sample ID 

08008-194-11 

Solvent BIsnk (MlliQ Bement) 

GLPlO-01-01-11-150 

GLPlO-01-01-11-151 

GLPlO-01-01-11-152 

GLPlO-01-01-11-153 

GLPl 0-01-01-11-154 

GLPl 0-01-01-11-155 

GLPl 0-01-01-11-156 

GLPlO-01-01-11-157 

GLPl 0-01-01-11-158 

GLPl 0-01-01-11-159 

Solvent Blank (MHiO Bement) 

Solvent BIsnk (MUiO Bement) 

08008-194-10 

Solvent Blank (MNIQ Bement) 

GLPlO-01-01-11-160 

GLPlO-01-01-11-161 

GLPlO-01-01-11-162 

GLPlO-01-01-11-163 

GLPlO-01-01-11-164 

GLPlO-01-01-11-165 

GLPlO-01-01-11-166 

GLPl 0-01-01-11-167 

GLPlO-01-01-11-168 

GLPlO-01-01-11-169 

Solvent BIsnk (MlliQ Bement) 

Solvent BIsnk (MlliQ Bement) 

08008-194-9 

Solvent BIsnk (MlliQ Bement) 

GLPl 0-01-01-12-009 

GLPlO-01-01-11-016 

GLPlO-01-01-11-149 

GLPlO-01-01-11-06S 

GLPlO-01-01-11-066 

GLPlO-01-01-11-067 

GLPlO-01-01-11-068 

GLPlO-01-01-11-069 

Solvent Blank (MlliQ Bement) 

Solvent BIsnk (MlliQ Bement) 

08008-194-8 

Solvent BIsnk (MHIQ Bement) 

GLPlO-01-01-11-079 

GLPlO-01-01-11-080 

GLPlO-01-01-11-081 

GLPlO-01-01-11-082 

GLPlO-01-01-11-083 

GLPlO-01-01-11-099 

GLPlO-01-01-11-100 

GLPlO-01-01-11-101 

GLPlO-01-01-11-102 

GLPlO-01-01-11-103 

Solvent BIsnk (MUiQ Bement) 

Solvent Blank (MlliQ Bement) 

08008-194-11 

Solvent BIsnk (MniQ Bement) 

Vial Position 

11 

94 

34 

35 

36 

37 

38 

39 

40 

41 

42 

43 

94 

95 

10 

95 

44 

45 

46 

47 

48 

49 

SO 

51 

52 

S3 

95 

96 

9 

96 

54 

55 

56 

57 

58 

59 

60 

61 

96 

97 

8 

97 

62 

63 

64 

65 

66 

67 

68 

69 

70 

71 

97 

98 

11 

98 

Data File 

bl 101033 

bl 10103a 

bl101033 

bl101033 

bl10103a 

bl10103a 

bl 10103a 

bl101033 

bl 101033 

bl 101033 

bl 101038 

bl 101033 

bl101038 

bl10103a 

bl101038 

bl10103a 

bl10103a 

bl101038 

bl10103a 

b1101033 

b110103s 

bl101038 

b1101033 

b1101033 

b1101038 

b1101033 

b1101038 

bl10103a 

bl101033 

bl101033 

bl101038 

bl101033 

bl101033 

bl101033 

bl101033 

bl101033 

bl101033 

bl101033 

bl101033 

bl101033 

bl101033 

bl101033 

bl10103a 

bl101033 

bl101033 

bl101033 

bl101038 

bl101033 

bl101033 

bl101033 

bl101033 

bl101033 

bl101038 

bl10103a 

b1101038 

bl10103a 

Inj.Volume (pi) 

10.000 

10.000 

10.000 

10.000 

10.000 

2.000 

10.000 

10.000 

10.000 

10.000 

2.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

2.000 

10.000 

10.000 

10.000 

10.000 

2.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

2.000 

2.000 

2.000 

2.000 

2.000 

10.000 

10.000 

10.000 

10.000 

2.000 

2.000 

2.000 

2.000 

2.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

Tab:Sample SetiSETI AcqMethod:PFOA only.dam 

Comment s 

10 ng/mL FC std in Mlli Q Wfeiter 

MinQV\faterTN10-047S 

Trip BIsnk Set 1 Ssmple 

Trip BIsnk Set 1 LS 

Trip BIsnk Set 1 MS 

Trip Blank Set 1 MHS 

Trip BIsnk Set 1 HS (dil 1:100) 

Trip BIsnk Set 2 Ssmple 

Trip BIsnk Set 2 LS 

Trip BIsnk Set 2 MS 

Trip BIsnk Set 2 MHS 

Trip BIsnk Set 2 HS (dil 1:100) 

MlliQ Water TN10-0475 

Min QW3ter TNI 0-0475 

5.0 ng/nl FC std in Mlli Q Water 

Min Q Water TNI 0-0475 

Trip BIsnk Set 3 Ssmple 

Trip BIsnk Set 3 LS 

Trip BIsnk Set 3 MS 

Trip BIsnk Set 3 MHS 

Trip Blank Set 3 HS(dn 1:100) 

Trip Blank Set 4 Sample 

TripBl3nkSet4LS 

Trip BIsnk Set 4 MS 

Trip Blank Set 4 MHS 

Trip BlankSet4HS (dil 1:100) 

MUiQ water TNI 0-0475 

Min QV\feter TNI 0-0475 

2.5 ng/mL FC std in Mlli 0 Water 

Min QV\fater TNI 0-0475 

DAL SS 607R RB 0040 

DAL GW130LRB 101105 

DAL GW144RRB 101110 

DAL GW134S0 101105 

DALGW134SDB10110S 

DAL GW134SLS 101105 

DALGW134SMS101105 

DAL GW134SHS 101105 

Min QW^ter TNI 0-0475 

Min Q Water TNI 0-0475 

1.0 ng/mL FC std in Min 0 V\feter 

Min QV\fater TNI 0-0475 

DAL GW13SS 0 101105 

DAL GW135SDB 101105 

DAL GW13SSLS 101105 

DAL GW135S MS 101105 

DAL GW135SHS 101105 

DAL GW137S 0101109 

DAL GW137SDB 101109 

DAL GW137SLS 101109 

DAL GW137S MS 101109 

DAL GW137SI-IS 101109 

Min Q Water TNI 0-0475 

Min Q Water TNI 0-0475 

10 ng/mL FC std in Mlli Q Water 

Min QWSter TNI 0-0475 

Printing Time; 

Printing Date: 

10:22:59 AM 

Monday, January 03, 2011 

Page 2 of 6 
•Buster J2930203 

Project: P:\Projects\Lab_lnstmment Data\Buster\Buster Data\Projects\fluororchemicalSwate 

Sample 

113 

114 

115 

116 

117 

118 

119 

120 

121 

122 

123 

124 

125 

126 

127 

128 

129 

130 

131 

132 

133 

134 

135 

136 

137 

138 

139 

140 

141 

142 

143 

144 

145 

146 

147 

148 

149 

ISO 

151 

152 

153 

154 

1SS 

156 

157 

158 

159 

160 

161 

162 

163 

164 

165 

166 

167 

168 

Sample Name 

b110103a113 

bl101038114 

bl 1010381 IS 

bl 101038116 

b110103a117 

b1101038l18 

b1101038l19 

bllOl038120 

bllOl038121 

bl 101038122 

bl 101038123 

bl 101038124 

b1101033l25 

bl101038126 

bl 101033127 

bl 101033128 

bl 101033129 

bl 101038130 

bl 101038131 

b110103a132 

bl 101038133 

bl101033134 

bl101038135 

bl101033136 

bl101033137 

bl101033138 

bl101033139 

bl101033140 

bl101033141 

b110103a142 

bl101033143 

bl101033144 

b110103a145 

bl101033146 

bl101033147 

bl101033148 

bl101033149 

b1101033lS0 

b1101033l51 

bl101038152 

bl101033153 

bllOl033154 

bl1010381SS 

b1101033l56 

bl101033157 

bl101033158 

bl101033159 

bl101033160 

bl101033161 

bl101033162 

bl101038163 

bl101033164 

bl101033165 

bl101038166 

b110103a167 

b1101033l68 

Sample ID 

GLPl 0-01-01-11-104 

GLPlO-01-01-11-105 

GLPlO-01-01-11-106 

GLPlO-01-01-11-107 

GLPlO-01-01-11-108 

GLPlO-01-01-11-114 

GLPlO-01-01-11-115 

GLPlO-01-01-11-116 

GLPlO-01-01-11-117 

GLPlO-01-01-11-118 

Solvent Blank (MlliQ Bement) 

Solvent Blank (MlliQ Bement) 

08008-194-10 

Solvent Blank (MlliQ Element) 

GLPlO-01-01-11-011 

GLPlO-01-01-11-012 

GLPlO-01-01-11-013 

GLPlO-01-01-11-014 

GLPlO-01-01-11-015 

GLPlO-01-01-11-021 

GLPlO-01-01-11-022 

GLPlO-01-01-11-023 

GLPlO-01-01-11-024 

GLPlO-01-01-11-025 

Solvent Blank (MlliQ Bement) 

Solvent BIsnk (MlliQ Bement) 

08008-194-9 

Solvent BIsnk (MlliQ Bement) 

GLPlO-01-01-11-026 

GLPlO-01-01-11-027 

GLPlO-01-01-11-028 

GLPlO-01-01-11-029 

GLPlO-01-01-11-030 

GLPlO-01-01-11-041 

GLPlO-01-01-11-042 

GLPlO-01-01-11-043 

GLPlO-01-01-11-044 

GLPlO-01-01-11-045 

Solvent BIsnk (MlliQ Bement) 

Solvent Blank (MUiQ Bement) 

08008-194-12 

Solvent Blank (MlliQ Bement) 

GLPlO-01-01-11-046 

GLPlO-01-01-11-047 

GLPlO-01-01-11-048 

GLPlO-01-01-11-049 

GLPlO-01-01-11-050 

GLPlO-01-01-11-0S1 

GLPlO-01-01-11-052 

GLPlO-01-01-11-0S3 

GLPlO-01-01-11-054 

GLPlO-01-01-11-055 

Solvent BIsnk (MlliQ Bement) 

Solvent Blank (MlliQ Bement) 

08008-194-11 

Solvent Blank (MlliQ Bement) 

Vial Position 

72 

73 

74 

75 

76 

77 

78 

79 

80 

81 

98 

99 

10 

99 

82 

83 

84 

85 

86 

87 

88 

89 

90 

34 

99 

100 

9 

100 

35 

36 

37 

38 

39 

40 

41 

42 

43 

44 

100 

91 

12 

91 

45 

46 

47 

48 

49 

50 

51 

52 

53 

54 

91 

92 

11 

92 

Data File 

b1101033 

b1101038 

b1101038 

b1101038 

b110103s 

b1101033 

bl 101038 

bl101033 

bl101038 

bl101038 

bl101038 

bl 101038 

bl 10103a 

bl 101033 

bl 101033 

bl 10103s 

bl 101033 

bl 101033 

bl 101033 

bl 101033 

bl 101038 

bl 10103a 

bl 101038 

bl 10103a 

bl 101038 

bl 101038 

bl 10103a 

bl 101038 

bl 101038 

bl 10103a 

bl 101038 

bl 101033 

bl 101033 

bl 10103s 

bl 101033 

bl 101033 

bl 101033 

bl 101033 

b1101033 

bl 101033 

bl 101033 

bl 101038 

b110103a 

b1101038 

b1101038 

bl 10103a 

bl 101038 

bl 101033 

bl 101038 

bl 10103a 

bl101033 

bl 101038 

bl 101033 

bl 10103s 

bl 10103s 

bl 101033 

rBatch:b110103a 

Inj.Volume (pi) 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

2.000 

2.000 

2.000 

2.000 

2.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

2.000 

2.000 

2.000 

2.000 

2.000 

10.000 

10.000 

10.000 

10.000 

Tab:Sample Set:SET1 AcqMethod:PFOA only.dam 

Comment s 

DAL GW137L 0101109 

DAL GW137LDB 101109 

DAL GW137LLS 101109 

DALGW137LMS101109 

DAL GW137LI-IS 101109 

DAL GW138L 0 101110 

DAL GW138LDB 101110 

DAL GW138LLS 101110 

DALGW138LMS101110 

DALGW138LHS101110 

Min Q Water TNI 0-0475 

Min Q Water TNI 0-0475 

5.0 ng/mL FC std in MUi Q \Afater 

MUIQ Water TNI 0-0475 

DAL GW130L0 101105 (dU 1:10) 

DAL GW130LDB 101105 (dU 1:10) 

DAL GW130LLS 101105 (dU 1:10) 

DAL GW130L MS 101105 (dil 1:10) 

DAL GW130L HS 101105 (dH 1:10) 

DAL GW131S 0 101103 (dil 1:10) 

DAL GW131S DB 101103 (dil 1:10) 

DAL GW 131S LS 101103 (dH 1:10) 

DAL GW 131S HS 101103 (dU 1:10) 

DALGW131SMS101103(dni:10) 

MUiQ Water TNI 0-0475 

MUiQ Water TNI 0-0475 

2.5 ng/mL FC std in MUi Q W^ter 

MUi QV\feiter TNI 0-0475 

DAL GW 131L 0 101103 (dil 1:10) 

DAL GW131L DB 101103 (dil 1:10) 

DAL GW131LLS 101103 (dil 1:10) 

DAL GW131L MS 101103 (dU 1:10) 

DAL GW131L HS 101103 (dil 1:10) 

DAL GW132L0 101103 (dU 1:10) 

DAL GW132LDB 101103 (dU 1:10) 

DAL GW132LLS 101103 (dU 1:10) 

DAL GW132L MS 101103 (dU 1:10) 

DAL GW132LHS 101103 (dH 1:10) 

MUiQ Water TNI 0-0475 

MinQV\feterTN10-047S 

25 ng/mL FC std in MUi Q W^ter 

MUIQ water TNI 0-0475 

DAL GW133R0 101102 (dU 1:10) 

DAL GW133RDB 101102 (dU 1:10) 

DAL GW133RLS 101102 (dil 1:10) 

DALGW133RMS101102(dU1:10) 

DAL GW133RHS 101102 (dU 1:10) 

DAL GW 133S 0 101103 (dil 1:10) 

DAL GW 133S DB 101103 (dU 1:10) 

DAL GW133S LS 101103 (dil 1:10) 

DAL GW133S MS 101103 (dfl 1:10) 

DAL GW133S HS 101103 (dU 1:10) 

Min Q water TNI 0-0475 

MUiQ water TNI 0-0475 

10 ng/mL FC std in Mlli Q water 

MUIQ Water TNI 0-0475 

Printing Time: 10:22:59 AM 

Printing Date: Monday, January 03, 2011 

Page 3 of 6 
•Buster J2930203 

Project: P:\Projects\Lab_lnstnjment DataVBustertBuster Data\Projects\fluoro 

Sample 

169 

170 

171 

172 

173 

174 

175 

176 

177 

178 

179 

180 

181 

182 

183 

184 

185 

186 

187 

188 

189 

190 

191 

192 

193 

194 

195 

196 

197 

198 

199 

200 

201 

202 

203 

204 

205 

206 

207 

208 

209 

210 

211 

212 

213' 

214 

215 

216 

217 

218 

219 

220 

221 

222 

223 

224 

Sample Name 

bl101038169 

bl101033170 

bl101038171 

bl101033172 

bl101038173 

b1101038l74 

b1101038l75 

bl101033176 

bl 101033177 

b1101033l78 

bl 101033179 

bl 101033180 

b110103s181 

bl 101033182 

bl101033183 

bl101033184 

bl101033185 

bl101033186 

bl 101033187 

bl 101033188 

b110103a189 

bl101038190 

bl101038191 

b110103a192 

bl 101038193 

bl 101038194 

bl 101038195 

bl 101033196 

bl101033197 

bl101033198 

bl101033199 

bl101038200 

bl101038201 

bl101033202 

b110103a203 

bl101033204 

bl101033205 

bl101033206 

bl 101033207 

bl101033208 

bl101038209 

bl101038210 

b1101038211 

bl101038212 

bl101038213 

bl101038214 

b110103a215 

bl101033216 

bl101038217 

bl101038218 

bl101033219 

bl101033220 

bl101038221 

bl 101038222 

bl101038223 

b110103a224 

Sample ID 

GLPl 0-01-01-11-056 

GLPl 0-01-01-11-057 

GLPlO-01-01-11-058 

GLPlO-01-01-11-059 

GLPlO-01-01-11-060 

GLPlO-01-01-11-070 

GLPlO-01-01-11-071 

GLPlO-01-01-11-072 

GLPlO-01-01-11-073 

GLPlO-01-01-11-074 

Solvent Blank (MlliQ Bement) 

Solvent BIsnk (MlliQ Bement) 

08008-194-10 

Solvent BIsnk (MlliQ Bement) 

GLPlO-01-01-11-089 

GLPlO-01-01-11-090 

GLPlO-01-01-11-091 

GLPlO-01-01-11-092 

GLPlO-01-01-11-093 

GLPlO-01-01-11-094 

GLPlO-01-01-11-095 

GLPlO-01-01-11-096 

GLPlO-01-01-11-097 

GLPlO-01-01-11-098 

Solvent BIsnk (MlliQ Bement) 

Solvent BIsnk (MlliQ Bement) 

08008-194-9 

Solvent BIsnk (MlliQ Bement) 

GLPlO-01-01-11-109 

GLPlO-01-01-11-110 

GLPlO-01-01-11-111 

GLPl 0-01-01-11-112 

GLPl 0-01-01-11-113 

GLPlO-01-01-11-119 

GLPlO-01-01-11-120 

GLPlO-01-01-11-121 

GLPlO-01-01-11-122 

GLPlO-01-01-11-123 

Solvent BIsnk (MUiQ Bement) 

Solvent BIsnk (MlliQ Bement) 

08008-194-12 

Solvent BIsnk (MlliQ Bement) 

GLPlO-01-01-11-124 

GLPlO-01-01-11-125 

GLPlO-01-01-11-126 

GLPlO-01-01-11-127 

GLPlO-01-01-11-128 

GLPlO-01-01-11-129 

GLPl 0-01-01-11-130 

GLPl 0-01-01-11-131 

GLPlO-01-01-11-132 

GLPl 0-01-01-11-133 

Solvent BIsnk (MUiQ Bement) 

Solvent BIsnk (MUiQ Bement) 

08008-194-10 

Solvent BIsnk (MUIQ Bement) 

Vial Position 

SS 

56 

57 

58 

59 

60 

61 

62 

63 

64 

92 

93 

10 

93 

65 

66 

67 

68 

69 

70 

71 

72 

73 

74 

93 

94 

9 

94 

75 

76 

77 

78 

79 

80 

81 

82 

83 

84 

94 

95 

12 

95 

85 

86 

87 

88 

89 

90 

34 

35 

36 

37 

95 

96 

10 

96 

nchemicals\waterBatch:b110103a 

Data File 

bl 10103a 

bl 101033 

bl 101033 

bl 101033 

bl 101033 

bl 101038 

bl 101038 

bl 10103a 

bl 101038 

bl 101033 

bl 101033 

bl 101033 

bl 101033 

bl 10103s 

bl 101033 

bl 101033 

bl 101033 

bl 101033 

bl 101033 

bl 101038 

bl 101033 

bl 101038 

bl 101038 

bl 101038 

bl 101038 

bl 10103a 

bl 10103a 

bl 101033 

bl 10103s 

bl 101033 

bl 101033 

bl 101033 

bl 101033 

bl 101033 

bl 101033 

bl 101033 

bl 101038 

bl 10103a 

bl 101038 

bl 101038 

bl 101038 

bl 10103a 

bl 101038 

bl 101033 

bl 10103s 

bl 101033 

bl 101038 

b110103s 

b110103a 

b1101033 

bl 101033 

b1101033 

bl 101038 

bl 101038 

bl 101038 

bl 101038 

Inj.Volume (pi) 

2.000 

2.000 

2.000 

2.000 

2.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

2.000 

2.000 

2.000 

2.000 

2.000 

10.000 

10.000 

10.000 

10.000 

2.000 

2.000 

2.000 

2.000 

2.000 

2.000 

2.000 

2.000 

2.000 

2.000 

10.000 

10.000 

10.000 

10.000 

2.000 

2.000 

2.000 

2.000 

2.000 

2.000 

2.000 

2.000 

2.000 

2.000 

10.000 

10.000 

10.000 

10.000 

Tab:Sample Set:SET1 AcqMethod:PFOA only.dam 

Comments 

DAL GW133L 0 101103 (dU 1:10) 

DAL GW133L DB 101103 (dU 1:10) 

DAL GW133L LS 101103 (dU 1:10) 

DAL GW 133L MS 101103 (dil 1:10) 

DAL GW133L HS 101103 (dU 1:10) 

DAL GW 134L 0 101105 (dil 1:10) 

DAL GW 134L DB 101105 (dU 1:10) 

DAL GW 134L LS 101105 (dil 1:10) 

DAL GW 134L MS 101105 (dU 1:10) 

DAL GW134LHS 101105 (dil 1:10) 

Min 0 Water TNI 0-0475 

MUIQ Water TNI 0-047S 

5.0 ng/nt FC std in Mlli Q water 

MUIQ Water TNI 0-0475 

DAL GW136S 0 101103 (dU 1:10) 

DAL GW136S DB 101103 (dil 1:10) 

DAL GW136S LS 101103 (dU 1:10) 

DAL GW136S MS 101103 (dU 1:10) 

DAL GW136S HS 101103 (dU 1:10) 

DAL GW 136L 0 101103 (dil 1:10) 

DAL GW 136L DB 101103 (dil 1:10) 

DAL GW 136L LS 101103 (dH 1:10) 

DAL GW 136L MS 101103 (dU 1:10) 

DAL GW 136L HS 101103 (dil 1:10) 

Min 0 water TNI 0-0475 

Min Q Water TNI 0-0475 

2.S ng/mL FC std in MUi Q Water 

MUiQ Water TNI 0-047S 

DAL GW138S 0 101110 (dU 1:10) 

DAL GW138SDB 101110 (dil 1:10) 

DAL GW138SLS 101110 (dU 1:10) 

DAL GW138S MS 101110 (dU 1:10) 

DAL GW138SI-IS 101110 (dU 1:10) 

DAL GWCW26R0 101110 (dil 1:10) 

DAL GWCW26RDB 101110 (dU 1:10 

DALGWCW26RLS 101110 (dU 1:10) 

DAL GWCW26R MS 101110 (dU 1:10 

DAL GWCW26R HS 101110 (dU 1:10 

Min 0 water TNI 0-0475 

Min 0 water TNI 0-0475 

25 ng/mL FC std in Mlli Q Water 

Min 0 water TNI 0-047S 

DAL GWCW26L 0 101110 (dU 1:10) 

DAL GWCW26L DB 101110 (dil 1:10) 

DAL GWCW26L LS 101110 (dU 1:10) 

DAL GWCW26L MS 101110 (dU 1:10 

DAL GWCW26L HS 101110 (drt 1:10) 

DAL GW140R0 101104 (dil 1:10) 

DAL GW140RDB 101104 (dU 1:10) 

DALGW140RLS 101104 (dU 1:10) 

DALGW140RMS101104(dU1:10) 

DAL GW 140R HS 101104 (dU 1:10) 

Min 0 water TNI 0-0475 

Min Q Water TNI 0-0475 

5.0 ng/mL FC std in MUi Q Water 

Min Q water TNI 0-0475 

Printing Time; 10;22;59 AM 

Printing Date: Monday, January 03, 

Page 4 of 6 
•Buster J2930203 

Project: P:\Projects^Lab_l^ 

Sample 

225 

226 

227 

228 

229 

230 

231 

232 

233 

234 

235 

236 ;,: 

237 

238 

239 

240 

241 

242 

243 : 

244 

245 

246 

247 

248 

249 

250 

251 

252 

253 

254 

255 

256 

257 a 

258 -

259 

260 

261 

262 

263 

264 

265~~l 

266 

267 

268 

269 

270 

271 

272 

273 

274 

275 

276 

277 

278 

279 

280 

Sample Name 

bl101033225 

bl101033226 

bl101033227 

bl101033228 

bl101033229 

bl101033230 

bl101033231 

bl101033232 

bl101038233 

bl101038234 

b110103823S 

bl101033236 

bl101038237 

bl101033238 

bl101033239 

bl101033240 

bl101033241 

bl101033242 

b110103a243 

bl101038244 

bl101038245 

bl101033246 

bl101033247 

bl101033248 

bl101033249 

bl101038250 

bl101033251 

bl101033252 

bl101033253 

bl101038254 

bl101038255 

bl101038256 

bl101038257 

bl 101038258 

bl 101038259 

bl 101038260 

bl 101033261 

bl 101033262 

bl101033263 

bl101033264 

bl101038265 

bl101033266 

bl101033267 

bl101033268 

bl101033269 

bl101033270 

bl101033271 

bl101033272 

bl101033273 

bl101038274 

bl101038275 

bl 101038276 

bl 101033277 

bl 101033278 

bl 101033279 

bl 101033280 

strument DataVBustertBuster Data\Projects\fluoiorchemicals\wate 

Sample ID 

GLPlO-01-01-11-134 

GLPl 0-01-01-11-135 

GLPl 0-01-01-11-136 

GLPlO-01-01-11-137 

GLPlO-01-01-11-138 

GLPlO-01-01-11-139 

GLPlO-01-01-11-140 

GLPlO-01-01-11-141 

GLPlO-01-01-11-142 

GLPlO-01-01-11-143 

Solvent Blank (MlliQ Bement) 

Solvent Blank (MlliQ Bement) 

08008-194-11 

Solvent Blank (MUiQ Bement) 

GLPlO-01-01-11-144 

GLPt 0-01-01-11-145 

GLPlO-01-01-11-146 

GLPlO-01-01-11-147 

GLPlO-01-01-11-148 

GLPlO-01-01-11-001 

GLPlO-01-01-11-002 

GLPlO-01-01-11-003 

GLPlO-01-01-11-004 

GLPlO-01-01-11-005 

Solvent BIsnk (MUiQ Bement) 

Solvent BIsnk (MUiQ Bement) 

08008-194-12 

Solvent BIsnk (MUIQ Bement) 

GLPlO-01-01-11-006 

GLPlO-01-01-11-007 

GLPlO-01-01-11-008 

GLPlO-01-01-11-009 

GLPlO-01-01-11-010 

Solvent BIsnk (MlliQ Bement) 

Solvent BIsnk (MlliQ Bement) 

08008-194-10 

Solvent BIsnk (MUiQ Bement) 

GLPlO-01-01-11-017 

GLPlO-01-01-11-018 

GLPl 0-01-01-11-019 

GLPlO-01-01-11-020 

Solvent BIsnk (MUIQ Bement) 

GLPlO-01-01-11-031 

GLPlO-01-01-11-032 

GLPlO-01-01-11-033 

GLPlO-01-01-11-034 

GLPlO-01-01-11-035 

Solvent BIsnk (MlliQ Bement) 

Solvent BIsnk (MlliQ Bement) 

08008-194-11 

Solvent Blank (MUiQ Bement) 

GLPlO-01-01-11-036 

GLPlO-01-01-11-037 

GLPlO-01-01-11-038 

GLPlO-01-01-11-039 

GLPlO-01-01-11-040 

Vial Position 

38 

39 

40 

41 

42 

43 

44 

45 

46 

47 

96 

97 

11 

97 

48 

49 

50 

51 

52 

53 

54 

55 

56 

57 

97 

98 

12 

98 

58 

59 

60 

61 

62 

98 

99 

10 

99 

63 

64 

65 

66 

99 

67 

68 

69 

70 

71 

99 

100 

11 

100 

72 

73 

74 

75 

76 

Data File 

bl 10103a 

bl 101038 

bl 10103a 

bl 101033 

b110103s 

b1101038 

b1101038 

bl 101038 

bl 101033 

bl 101033 

bl 101033 

bl 101033 

bl 101033 

bl 101038 

bl 101038 

bl 10103a 

bl 10103a 

bl 101038 

bl10103a 

bl 10103a 

bl 101033 

bl 101033 

bl 101033 

bl 10103a 

bl 101033 

*bTl0103ir" 

bl 101033 

bl 101033 

bl 10103s 

bl 101033 

bl101033 

b1101038 

bl 101033 

bl 10103s 

bl 10103s 

bl 101033 

bl 101033 

bl 101038 

bl 10103a 

bl 10103a 

bl 101038 

bl 10103a 

b1101038 

b110103a 

bl10103a 

bl101033 

bl101033 

bl101033 

bl101033 

bl101033 

bl101038 

bl10103a 

bl 10103a 

bl10103a 

bl10103a 

bl10103a 

rBatch:b110103a 

Inj.Volume (pi) 

2.000 

2.000 

2.000 

2.000 

2.000 

2.000 

2.000 

2.000 

2.000 

2.000 

10.000 

10.000 

10.000 

10.000 

2.000 

2.000 

2.000 

2.000 

2.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 ' 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

Tab:Sample Set:SET1 AcqMethod:PFOA only.dam 

Comments 

DAL GW141R0 101110 (dU 1:10) 

DAL GW141RDB 101110 (dil 1:10) 

DALGW141RLS101110(dni:10) 

DAL GW141RMS 101110 (dil 1:10) 

DAL GW141RHS 101110 (dil 1:10) 

DALGW142R0 101110(dil1:10) 

DALGW142RDB101110(dU1:10) 

DALGW142RLS 101110 (dU 1:10) 

DAL GW142RMS 101110 (dU 1:10) 

DAL GW142RHS 101110 (dU 1:10) 

MUiQ Water TNI 0-0475 

MUiQ Water TNI 0-0475 

10 ng/mLFC std in Min Q Water 

MUiQ water TNI 0-0475 

DAL GW144R0 101110 (dU 1:10) 

DAL GW144RDB 101110 (dil 1:10) 

DAL GW 144RLS 101110 (dH 1:10) 

DAL GW144RMS 101110 (dn 1:10) 

DAL GW144RI-IS 101110 (dU 1:10) 

DAL GW130R0 101105 (dil 1:100) 

DAL GW130RDB 101105 (dU 1:100) 

DAL GW 130RLS 101105 (dU 1:100) 

DAL GW130RMS 101105 (dU 1:100) 

DAL GW130RHS 101105 (dU 1:100) 

MUIQ water TNI 0-0475 

MUiQ Water TNI 0-0475 

25 ng/mL FC std In Mlli Q Water 

Min Q Water TNI 0-0475 

DAL GW130S0 101105 (dU 1:100) 

DAL GW130SDB 101105 (dil 1:100) 

DAL GW130S LS 101105 (dU 1:100) 

DAL GW130S MS 101105 (dU 1:100) 

DAL GW 130S HS 101105 (dU 1:100) 

Min Q\Afeter TNI 0-0475 

MUi QV\fater TNI 0-0475 

5.0 ng/nnL FC std in MUi Q Water 

MUi Q\Afater TNI 0-0475 

DALGW131R0 101103(dU1:100) 

DAL GW131RDB 101103 (dil 1:100) 

DAL GW131RLS 101103 (dH 1:100) 

DALGW131RHS 101103 (dH 1:100) 

Min Q Water TNI 0-0475 

DAL GW132R0 101102 (dH 1:100) 

DAL GW132RDB 101102 (dU 1:100) 

DALGW132RLS 101102 (dil 1:100) 

DAL GW 132R MS 101102 (dU 1:100) 

DAL GW 132R HS 101102 (dU 1:100) 

MUi QV\&ter TNI 0-0475 

MUiQ water TNI 0-0475 

10 ng/mL FC std in Mlli Q V\feter 

MUi Q\/\feiter TNI 0-0475 

DAL GW132S 0 101102 (dU 1:100) 

DAL GW132S DB 101102 (dil 1:100) 

DALGW132S LS 101102 (dH 1:100) 

DAL GW132S MS 101102 (dH 1:100) 

DAL GW132S HS 101102 (dH 1:100) 

Printing Time; 10:22:59 AM 

Printing Date; Monday, January 03, 

Page 5 of 6 
•Buster J2930203 

Project: P:\Projects\Lab_lnstrument Data\BustertBuster Data\Projects\fluororchemicals\water Batch:b110103a Tab:Sample Set:SET1 AcqMethod:PFOA only.dam 

Sample 

281 

282 

283 

284 

285 

286 

287 5 

288 

289 

290 

291 

292 

293 

294 

295 

296 

297 

298 

299 

300 

301 

302 

303 

304 

305 

306 

Sample Name 

bl 101033281 

bl 101033282 

bl101033283 

bl101033284 

bl101033285 

bl 101038286 

bl101033287 

bl101038288 

b110103a289 

bl101033290 

bl101038291 

bl101038292 

bl101033293 

bl101033294 

bl101033295 

bl101033296 

bl101033297 

bl101038298 

bl101033299 

bl101038300 

bl101038301 

b110103a302 

bl101033303 

bl101038304 

bl101033305 

bl101033306 

Sample ID 

Solvent BIsnk (MlliQ Bement) 

Solvent Bl3nk (MlliQ Bement) 

08008-194-12 

Solvent BIsnk (MlliQ Bement) 

GLPlO-01-01-11-061 

GLPlO-01-01-11-062 

GLPlO-01-01-11-063 

GLPlO-01-01-11-064 

Solvent BIsnk (MlliQ Element) 

GLPlO-01-01-11-075 

GLPlO-01-01-11-076 

GLPlO-01-01-11-077 

GLPlO-01-01-11-078 

Solvent BIsnk (MlliQ Bement) 

Solvent Blank (MlliQ Bement) 

08008-194-10 

Solvent Blank (MlliQ Bement) 

GLPlO-01-01-11-084 

GLPlO-01-01-11-085 

GLPl 0-01-01-11-086 

GLPlO-01-01-11-087 

GLPlO-01-01-11-088 

Solvent BIsnk (MUiQ Bement) 

Solvent BIsnk (MUiQ Bement) 

08008-194-11 

Solvent BIsnk (MUiQ Bement) 

Vial Pos'ition 

100 

91 

12 

91 

77 

78 

79 

80 

91 

81 

82 

83 

84 

91 

92 

10 

92 

85 

86 

87 

88 

89 

92 

93 

11 

93 

Data File 

bl10103s 

bl 101033 

bl 101033 

bl 101033 

bl 101038 

bl 10103a 

bl101033 

b1101033 

b1101033 

b110103a 

b110103s 

bl10103s 

bl101033 

bl 101033 

bl 101033 

bl 101038 

bl 101033 

bl 101038 

b1101038 

b110103a 

b1101038 

b1101033 

b1101033 

bl 101033 

bl 10103s 

bl 10103s 

Inj.Volume (pi) 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

Comments 

Min QV\feter TNI 0-0475 

MUIQ water TNI 0-0475 

25 ng/nt FC std in Mlli Q Water 

MUiQ water TNI 0-0475 

DALGW134R0 101105 (dil 1:100) 

DAL GW 134R DB 101105 (dH 1:100) 

DAL GW134RLS 101105 (dU 1:100) 

DAL GW134RHS 101105 (dU 1:100) 

MUIQ Water TNI 0-0475 

DAL GW135R0 101105 (dH 1:100) 

DAL GW135RDB 101105 (dU 1:100) 

DAL GW135RLS 101105 (dH 1:100) 

DAL GW135RHS 101105 (dil 1:100) 

Min QV\feter TNI 0-0475 

Min Q\/\feter TNI 0-0475 

5.0 ng/mL FC std in Mlli Q Water 

MUIQ Water TNI 0-0475 

DAL GW 135L 0 101105 (dU 1:100) 

DAL GW135L DB 101105 (dH 1:100) 

DAL GW135L LS 101105 (dil 1:100) 

DALGW135L MS 101105 (dH 1:100) 

DAL GW135L HS 101105 (dU 1:100) 

MUIQ Water TNI 0-0475 

MUIQ water TNI 0-0475 

10 ng/mL FC std in MUi Q Water 

MIUQ water TNI 0-0475 

Printing Time; 10:22:59 AM 

Printing Date; Monday, January 03, 2011 

Page 6 of 6 
•Buster J2930203 

Project: F 

Sample 

1 

2 

3 

4 

5 

6 

7 

8 

9 

10 

11 

12 

13 

14 

15 

16 

17 

18 

19 

20 

21 

22 

23 

24 

25 

26 

27 

28 

29 

30 

3.1 

32 

33 

34 

35 

36 

37 

38 

39 

40 

41 

42 

43 

44 

45 

46 

47 

48 

49 

50 

51 

.52U--

53 

54 

55 

56 

':\Projects\Lab_lnstrument Data\BustertBuster Data\Prajects\fluoro 

Sample Name 

bl101033001 

bl101033002 

bl101033003 

bl101033004 

bl101033005 

bl101033006 

bl101033007 

bl101038008 

bl101038009 

b110103a010 

b110103a011 

bl101033012 

b1101038013 

bl101038014 

bl101033015 

bl101038016 

bl101038017 

bl101033018 

bl101038019 

bl101033020 

bl101033021 

bl101038022 

bl101033023 

b110103a024 

bl101038025 

bl101033026 

bl101038027 

b110103a028 

bl101038029 

bl101033030 

bl101038031 

bl101033032 

bl101038033 

bl101038034 

bl101038035 

bl101033036 

bl101033037 

bl101033038 

bl101033039 

bl101033040 

bl101033041 

bl101033042 

bl101033043 

bl101033044 

bl101033045 

bl101033046 

bl101033047 

bl101033048 

bl101038049 

bl101038050 

bl101038051 

bl101038052 

bl101033053 

bl101033054 

bl101038055 

bl101033056 

Sample ID 

Solvent Bl3nk (MlliQ Bement) 

Solvent BIsnk (MUiQ Bement) 

Solvent BIsnk (MUIQ Bement) 

Solvent BIsnk (MUiQ Bement) 

Solvent BIsnk (MlliQ Bement) 

Solvent BIsnk (MlliQ Bement) 

08008-194-11 system suit 

08008-194-11 system suit 

08008-194-11 system suit 

08008-194-11 systemsuit 

Solvent Blank (MlliQ Bement) 

Solvent Blank (MlliQ Bement) 

08008-194-1 

08008-194-2 

08008-194-3 

08008-194-4 

08008-194-5 

08008-194-6 

08008-194-7 

08008-194-8 

08008-194-9 

08008-194-10 

08008-194-11 

08008-194-12 

08008-194-13 

08008-194-14 

08008-194-15 

Solvent Blank (MlliQ Bement) 

Solvent Blank (MUIQ Bement) 

Solvent Blank (MlliQ Bement) 

08008-194-10 

Solvent Blank (MlliQ Bement) 

LCS-101230-1 

LCS-101230-2 

LCS-101230-3 

LCS-101230-4 

LCS-101230-5 

LCS-101230-6 

LCS-101230-7 

LCS-101230-8 

LCS-101230-9 

Solvent Blank (MlliQ Bement) 

Solvent BIsnk (MlliQ Bement) 

08008-194-9 

Solvent BIsnk (MlliQ Bement) 

LCS-101230-10 

LCS-101230-11 

LCS-101230-12 

LCS-101230-13 

LCS-101230-14 

LCS-101230-15 

LCS-101230-16 

LCS-101230-17 

LCS-101230-18 

Solvent BIsnk (MUiQ Bement) 

Solvent Blank (MlliQ Bement) 

Vial Position 

91 

91 

91 

91 

91 

91 

11 

11 

11 

11 

91 

91 

1 

2 

3 

4 

5 

6 

7 

8 

9 

10 

11 

12 

13 

14 

15 

91 

92 

92 

10 

92 

16 

17 

18 

19 

20 

21 

22 

23 

24 

92 

93 

9 

93 

25 

26 

27 

28 

29 

30 

31 

32 

33 

93 

94 

rchemicals\waterBatch:b110103a 

Data File 

bl10103a 

bl101038 

bl 10103a 

bl 10103a 

bl 10103a 

bl101033 

bl10103s 

bl10103s 

bl101033 

bl101033 

bl101033 

bl10103s 

bl 101033 

bl 101033 

bl101038 

b110103s 

b1101033 

bl 101038 

b1101038 

bl 101038 

bl 101033 

bl 101033 

bl 101038 

bl 101033 

bl 101033 

bl 101038 

bl 101033 

bl 101038 

bl 101038 

bl 101038 

bl 10103a 

bl 101038 

bl 101033 

bl 10103s 

bl 10103s 

bl 101033 

bl 101033 

bl 101038 

bl 101033 

bl 101033 

bl 101038 

bl 10103a 

bl 101033 

b1101033 

bl 101033 

bl 101033 

bl 101033 

bl 10103s 

b110103s 

b110103s 

bl 101033 

bl 101033 

bl 101033 

bl 101033 

bl 101038 

bl 101033 

Inj.Volume (pi) 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

Tab:Sample Set:SET1 AcqMethod:PFOA only.dam 

Comments 

Min Q\/\feter TNI 0-0475 

MUiQ water TNI 0-0475 

MUiQ water TNI 0-0475 

Min Q water TNI 0-0475 

Min Q Water TNI 0-0475 

Min QV\fater TNI 0-0475 

10 ng/mL FC std in Mlli Q Water 

10 ng/mL FC std in Mlli Q Water 

10 ng/mL FC std in MIU Q Water 

10 ng/mL FC std in Mlli Q Water 

MIUQ water TNI 0-0475 

MUIQ water TNI 0-0475 

0.025 ng/mL FC std in Mlli Q Water 

0.03 ng/mL FC std in MHi Q Water 

0.04 ng/mL FC std in Mill Q Water 

0.05 ng/mL FC std in Mill Q Water 

0.1 ng/mL FC std in MUI Q V\fafer 

0.25 ng/mL FC std in MHi Q Water 

0.5 ng/mL FC std in MUI Q V\fater 

1.0 ng/mL FC std in MUi Q V\fater 

2.5 ng/mL FC std in MUi 0 V\fater 

5.0 ng/mL FC std in MUI Q Water 

10 ng/mL FC std in MHi Q Water 

25 ng/mL FC std in MHi Q Water 

50 ng/mL FC std in MUi 0 Water 

75 ng/mL FC std in MUi Q Water 

100 ng/mL FC std in MUi Q Water 

MUi QV\feter TNI 0-0475 

MUIQ water TNI 0-0475 

MUi Q\/\feter TNI 0-0475 

5.0 ng/mL FC std In Mlli Q Water 

MUi QV\feter TNI 0-0475 

0.5ppb LCS 

0.5ppb LCS 

0.5ppb LCS 

5ppb LCS 

5ppb LCS 

5ppb LCS 

30ppb LCS 

30ppb LCS 

30ppb LCS 

MUIQ water TNI 0-0475 

MHi Q Water TNI 0-0475 

2.5 ng/mL FC std in MUi Q Water 

MHi Q water TNI 0-0475 

O.Sppb LCS ECF 

O.Sppb LCS ECF 

O.Sppb LCS ECF 

Sppb LCS ECF 

Sppb LCS ECF 

Sppb LCS ECF 

30ppb LCS ECF 

30ppb LCS ECF 

30ppb LCS ECF 

MUiQ Water TNI 0-047S 

MUi QV\feter TNI 0-0475 

Printing Time; 

Printing Date; 

10:07:20 AM 

Friday, January 07, 2011 

Page 1 of 6 

CXJCil il't i 
•Buster J2930203 

Project: P:\ProjectsALab_lnstrument Data\BustertBuster Data\Prajects\fluororchemicals\wate 

Sample 

57 

58 

59 iv 

60 -

61 

62 

63 

64 

65 

66~~~1 

67 

68 

69 

70 

71 

72 

73 

74 

75 

76 

77 

78 

79 

80 

81 

82 

83 

84 

85 

86 

87 

88 

89 

90 

91 

92 

93 

94 

95 

96 

97 

98 

99 

100 

101 

102 n 

103 

104 

105 

106 

107 

108 

110 

111 

112 

Sample Name 

bl 101033057 

bl101033058 

bl101033059 

bl101038060 

bl101038061 

bl101038062 

bl101038063 

bl101033064 

bl101033065 

bl101038066 

bl101038067 

bl101033068 

bl101033069 

bl101033070 

bl101038071 

bl101038072 

bl101038073 

bl101033074 

bl101033075 

bl101033076 

bl101033077 

bl101038078 

bl101038079 

bl101033080 

bl101038081 

bl101038082 

bl101033083 

bl101038084 

bl101033085 

bl101033086 

bl101038087 

bl101033088 

bl101033089 

bl101033090 

bl101033091 

bl101033092 

bl101033093 

bl101038094 

bl101038095 

bl101038096 

b110103a097 

bl101038098 

bl101038099 

b1101038l00 

b110103a101 

bl101033102 

bl101033103 

bl101033104 

bl101033105 

bl101033106 

blf01033l07 

bl101033108 

bl101038109 

bl101033110 

bl101033111 

bl101033112 

Sample ID 

08008-194-11 

Solvent BIsnk (MUIQ Bement) 

GLPlO-01-01-11-150 

GLPlO-01-01-11-151 

GLPlO-01-01-11-152 

GLPlO-01-01-11-1S3 

GLPlO-01-01-11-154 

GLPlO-01-01-11-155 

GLPlO-01-01-11-156 

GLPlO-01-01-11-157 

GLPlO-01-01-11-158 

GLPlO-01-01-11-159 

Solvent BIsnk (MUiQ Bement) 

Solvent BIsnk (MHiQ Bement) 

08008-194-10 

Solvent BIsnk (MHiQ Bennent) 

GLPlO-01-01-11-160 

GLPl 0-01-01-11-161 

GLPlO-01-01-11-162 

GLPlO-01-01-11-163 

GLPlO-01-01-11-164 

GLPlO-01-01-11-165 

GLPlO-01-01-11-166 

GLPlO-01-01-11-167 

GLPlO-01-01-11-168 

GLPlO-01-01-11-169 

Solvent BIsnk (MUiQ Bement) 

Solvent BIsnk (MHiQ Bement) 

08008-194-9 

Solvent BIsnk (MUiQ Bement) 

GLPl 0-01-01-12-009 

GLPlO-01-01-11-016 

GLPlO-01-01-11-149 

GLPlO-01-01-11-065 

GLPlO-01-01-11-066 

GLPlO-01-01-11-067 

GLPl 0-01-01-11-068 

GLPlO-01-01-11-069 

Solvent BIsnk (MUiQ Bement) 

Solvent BIsnk (MHiQ Bement) 

08008-194-8 

Solvent BIsnk (MHiQ Bement) 

GLPlO-01-01-11-079 

GLPl 0-01-01-11-080 

GLPlO-01-01-11-081 

GLPlO-01-01-11-082 

GLPlO-01-01-11-083 

GLPl 0-01-01-11-099 

GLPlO-01-01-11-100 

GLPlO-01-01-11-101 

GLPlO-01-01-11-102 

GLPlO-01-01-11-103 

Solvent Bl3nk (MUiQ Bement) 

Solvent BIsnk (MUiQ Bement) 

08008-194-11 

Solvent Blank (MlliQ Bement) 

Vial Position 

11 

94 

34 

35 

36 

37 

38 

39 

40 

41 

42 

43 

94 

95 

10 

95 

44 

45 

46 

47 

48 

49 

SO 

51 

52 

53 

95 

96 

9 

96 

54 

55 

56 

57 

58 

59 

60 

61 

96 

97 

8 

97 

62 

63 

64 

65 

66 

67 

68 

69 

70 

71 

97 

98 

11 

98 

Data File 

bl 101033 

bl 101033 

bl 101033 

bl 101033 

bl 101033 

bl 101033 

bl 101033 

bl 101033 

bl 101038 

bl 101033 

bl 101033 

bl 101033 

bl 101038 

bl101033 

bl101033 

bl10103s 

bl 101033 

bl 101033 

bl 101033 

bl 101033 

bl 101038 

bl 10103a 

bl 10103a 

bl 10103a 

bl 10103a 

bl 10103a 

bl101033 

bl101033 

bl101033 

bl101033 

bl101033 

bl101033 

bl 101033 

bl 101033 

bl 101038 

bl 101038 

bl 10103a 

bl 10103a 

bl101038 

bl10103a 

bl 101033 

bl101033 

bl101038 

bl101038 

bl 101038 

bl 10103a 

bl 101038 

bl 101038 

bl 101038 

bl 10103a 

bl 10103a 

bl 101033 

bl 101038 

bl 101033 

bl 10103a 

bl101038 

rBatch:b110103a 

Inj.Volume (pi) 

10.000 

10.000 

10.000 

10.000 

10.000 

2.000 

10.000 

10.000 

10.000 

10.000 

2.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

2.000 

10.000 

10.000 

10.000 

10.000 

2.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

2.000 

2.000 

2.000 

2.000 

2.000 

10.000 

10.000 

10.000 

10.000 

2.000 

2.000 

2.000 

2.000 

2.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

Tab:Sample Set:SET1 AcqMethod:PF 

Comment s 

10 ng/mL FC std in MUi 0 \/\fater 

Min QV\feter TNI 0-0475 

Trip Blank Set 1 Sartple 

Trip Bl3nk Set 1 LS 

Trip Blank Set 1 MS 

Trip Blank Set 1 MHS 

Trip Blank Set 1 HS(dH 1:100) 

Trip BIsnk Set 2 Ssmple 

Trip BIsnk Set 2 LS 

Trip BIsnk Set 2 MS 

Trip BIsnk Set 2 MHS 

Trip BIsnk Set 2 HS(dn 1:100) 

Min QV\feter TNI 0-0475 

MHi QWster TNI 0-0475 

5.0 ng/nnL FC std in Mlli Q Water 

Min QV\fater TNI 0-0475 

Trip BIsnk Set 3 Sample 

Trip BIsnk Set 3 LS 

Trip BIsnk Set 3 MS 

Trip BIsnk Set 3 MHS 

Trip BIsnk Set 3 HS(dH 1:100) 

Trip BIsnk Set 4 Sample 

Trip Blank Set 4 LS 

Trip BIsnk Set 4 MS 

Trip BIsnk Set 4 MHS 

Trip Bl3nkSet4HS(dH 1:100) 

MHi QV\fater TNI 0-0475 

MHi Q\/\feiter TNI 0-0475 

2.S ng/mL FC std in MHi Q Water 

MHi QV\feiter TNI 0-0475 

DAL SS607RRB 0040 

DAL GW130LRB 101105 

DAL GW144RRB 101110 

DAL GW134S 0 101105 

DAL GW134SDB 101105 

DAL GW134SLS 101105 

DAL GW134S MS 101105 

DAL GW134SHS 101105 

MHiQ Water TNI 0-047S 

MHiQ Water TNI 0-0475 

1.0 ng/mL FC std in MUi Q Water 

MHi QV\feter TNI 0-0475 

DAL GW13SS 0 101105 

DALGW13SSDB10110S 

DAL GW13SSLS 101105 

DAL GW13SS MS 101105 

DALGW13SSHS10110S 

DAL GW137S 0 101109 

DALGW137SDB101109 

DAL GW137SLS 101109 

DAL GW137S MS 101109 

DALGW137SI-IS101109 

MUiQ Water TNI 0-0475 

MUiQ water TNI 0-0475 

10 ng/mL FC std in Mlli Q Water 

MUiQ Water TNI 0-0475 

OA only.dam 

Printing Time; 

Printing Date; 

10:07:20 AM 

Friday, January 07, 2011 

Page 2 of 6 
•Buster J2930203 

Project: P:\Projects^Lab_lnstrument Data\BustertBuster Data\Projects\fluoro 

Sample 

113 

114 

115 

116 

117 

118 

119 

120 

121 

122 

123 

124 

125 

126 

127 

1283" 

129 

130 

131 

132 

133 

134 ' 

135 

136 

137 

138 

139 

140 

141 

142 

143 

144 

145 

146 

147 

148 

149 

ISO 

151 

152 

153 

154 

155 

156 

157 

158 

159 

160 

161 

162 

163 

164 

165 

166 

167 

168 

Sample Name 

b110103a113 

b1101038l14 

b1101038l15 

bl101033116 

b1101033l17 

b1101033l18 

b110103s119 

bl101038120 

b110103s121 

bl101033122 

bl101033123 

bl101038124 

bl101033125 

bl101033126 

bl101033127 

bl101033128 

bl101033129 

bl101033130 

bl101033131 

bl101033132 

b110103s133 

bllOl038134 

bl101038135 

bl101038136 

bl101033137 

bl101033138 

bl101033139 

bl101033140 

bl101033141 

bl101033142 

bl101033143 

bl101033144 

bl101033145 

bl101033146 

bl101033147 

bl101033148 

bl101033149 

bl101033150 

b1101033l51 

bl101033152 

bl101033153 

bl101033154 

bl101033155 

bl101033156 

bl101033157 

bl101033158 

bl101033159 

bl101038160 

b1101038l61 

bl101038162 

bl101038163 

b1101038l64 

b1101038l6S 

bl101033166 

b110103a167 

b1101033l68 

Sample ID 

GLPl 0-01-01-11-104 

GLPl 0-01-01-11-105 

GLPlO-01-01-11-106 

GLPlO-01-01-11-107 

GLPlO-01-01-11-108 

GLPlO-01-01-11-114 

GLPlO-01-01-11-115 

GLPlO-01-01-11-116 

GLPlO-01-01-11-117 

GLPlO-01-01-11-118 

Solvent BIsnk (MHiQ Bement) 

Solvent BIsnk (MlliQ Bement) 

08008-194-10 

Solvent Bl3nk (MlliQ Bement) 

GLPlO-01-01-11-011 

GLPlO-01-01-11-012 

GLPl 0-01-01-11-013 

GLPlO-01-01-11-014 

GLPl 0-01-01-11-015 

GLPlO-01-01-11-021 

GLPlO-01-01-11-022 

GLPlO-01-01-11-023 

GLPl 0-01-01-11-024 

GLPl 0-01-01-11-025 

Solvent BIsnk (MUiQ Bement) 

Solvent BIsnk (MUiQ Bement) 

08008-194-9 

Solvent Blank (MUiQ Bement) 

GLPl 0-01-01-11-026 

GLPlO-01-01-11-027 

GLPlO-01-01-11-028 

GLPlO-01-01-11-029 

GLPlO-01-01-11-030 

GLPlO-01-01-11-041 

GLPl 0-01-01-11-042 

GLPlO-01-01-11-043 

GLPlO-01-01-11-044 

GLPlO-01-01-11-045 

Solvent BIsnk (MHiQ Bement) 

Solvent BIsnk (MHiQ Bement) 

08008-194-12 

Solvent BIsnk (MHiQ Bement) 

GLPlO-01-01-11-046 

GLPlO-01-01-11-047 

GLPlO-01-01-11-048 

GLPlO-01-01-11-049 

GLPlO-01-01-11-050 

GLPlO-01-01-11-051 

GLPl 0-01-01-11-052 

GLPlO-01-01-11-053 

GLPlO-01-01-11-054 

GLPl 0-01-01-11-055 

Solvent Blank (MlliQ Bement) 

Solvent Blank (MlliQ Bement) 

08008-194-11 

Solvent Blank (MUiQ Bement) 

Vial Position 

72 

73 

74 

75 

76 

77 

78 

79 

80 

81 

98 

99 

10 

99 

82 

83 

84 

85 

86 

87 

88 

89 

90 

34 

99 

100 

9 

100 

35 

36 

37 

38 

39 

40 

41 

42 

43 

44 

100 

91 

12 

91 

45 

46 

47 

48 

49 

50 

51 

52 

53 

54 

91 

92 

11 

92 

rchemicalsVwate 

Data RIe 

bl 10103a 

bl 101038 

bl 101038 

bl 101033 

bl 101033 

b1101033 

b110103s 

bl 101038 

bl 10103a 

bl 101033 

bl 101033 

bl 101033 

bl 10103s 

bl 10103s 

bl 101033 

bl 101033 

bl 10103s 

bl 101033 

bl 101033 

bl 101033 

bl 101033 

bl 101033 

bl 101038 

bl 101038 

bl 10103s 

bl 101038 

bl 101033 

bl 101038 

bl 10103a 

bl 101038 

bl10103a 

b110103a 

b1101038 

bl 101038 

b1101033 

bl 10103s 

bl 10103s 

bl10103s 

bl 101033 

bl101033 

bl10103s 

bl10103s 

bl101033 

bl 10103s 

bl 101033 

bl 10103s 

bl10103s 

bl 101033 

bl 101033 

bl 101033 

bl 101033 

bl 101033 

bl 101033 

bl 101038 

bl101038 

bl101038 

rBatch:b110103a 

Inj.Volume (pi) 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

2.000 

2.000 

2.000 

2.000 

2.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

2.000 

2.000 

2.000 

2.000 

2.000 

10.000 

10.000 

10.000 

10.000 

Tab:Sample Set:SET1 AcqMethod:PFOA 

Comment s 

DAL GW137L 0 101109 

DAL GW137LDB 101109 

DAL GW137LLS 101109 

DAL GW137L MS 101109 

DAL GW137LHS 101109 

DAL GW138L 0 101110 

DAL GW138LDB 101110 

DAL GW138LLS 101110 

DAL GW138L MS 101110 

DALGW138LHS101110 

MHi QVVfafer TNI 0-0475 

MHi QWfater TNI 0-0475 

5.0 ng/mL FC std in MUi Q Water 

MHiQ Water TNI 0-0475 

DAL GW130L0 101105 (dH 1:10) 

DAL GW130L DB 101105 (dH 1:10) 

DAL GW130LLS 101105 (dH 1:10) 

DAL GW130L MS 101105 (dH 1:10) 

DAL GW130L HS 101105 (dH 1:10) 

DAL GW131S 0 101103 (dH 1:10) 

DAL GW131SDB 101103 (dH 1:10) 

DALGW131S LS 101103 (dH 1:10) 

DAL GW131SHS 101103 (dU 1:10) 

DAL GW131S MS 101103 (dU 1:10) 

MUiQ Water TNI 0-0475 

MUiQ water TNI 0-0475 

2.5 ng/mL FC std in MHi Q Water 

MUiQ water TNI 0-0475 

DAL GW131L0 101103 (dH 1:10) 

DAL GW131L DB 101103 (dH 1:10) 

DAL GW 131L LS 101103 (dU 1:10) 

DAL GW131L MS 101103 (dH 1:10) 

DAL GW 131L HS 101103 (dH 1:10) 

DAL GW 132L 0 101103 (dH 1:10) 

DAL GW 132L DB 101103 (dU 1:10) 

DAL GW 132L LS 101103 (dH 1:10) 

DAL GW 132L MS 101103 (dU 1:10) 

DAL GW132L HS 101103 (dU 1:10) 

MUiQ water TNI 0-0475 

MUIQ Water TNI 0-0475 

25 ng/mL FC std in MUi Q Water 

MUiQ Water TNI 0-0475 

DAL GW133R0 101102 (dH 1:10) 

DAL GW133RDB 101102 (dU 1:10) 

DAL GW133RLS 101102 (dH 1:10) 

DAL GW133R MS 101102 (dU 1:10) 

DAL GW133RHS 101102 (dU 1:10) 

DAL GW133S0 101103 (dH 1:10) 

DAL GW133S DB 101103 (dU 1:10) 

DAL GW133S LS 101103 (dH 1:10) 

DAL GW 133S MS 101103 (dU 1:10) 

DALGW133S HS 101103 (dU 1:10) 

MHiQ Water TNI 0-0475 

MUiQ Water TNI 0-0475 

10 ng/nt FC std in MUi Q V\feter 

MHi QV\feter TNI 0-0475 

only.dam 

Printing Time: 

Printing Date; 

10:07:20 AM 

Friday, January 07, 2011 

Page 3 of 6 
•Buster J2930203 

Project: P:\Projects\Lab_lr 

Sample 

169 

UO ' 

171 

172 

173 

174 

175 

176 

177 

178 

179 

180 

181 

182 

183 

184 

185 

186 

187 

188 

189 

190 

191 

192 

193 

194 

195 

196 

197 

198 

199 

200 

201 

202 

203 

204 

205 

206 

207 

208 

209 

210 

211 

212 

213 

214 

215 

216 

217 

218 

219 

220 

221 

222 

223 

224 

Sample Name 

b110103a169 

bl 101033170 

bl 101038171 

bl101038172 

tmm033l73~^ 

bl 101038174 

bl101038175 

bl101033176 

bl101033177 

bl 101033178 

bl101033179 

bl101033180 

biiordssTsT^ 

bl 101038182 

bl101033183 

bl101033184 

b110103s185 

b1101033l86 

bl101033187 

bl 101033188 

bl 101033189 

bl 101033190 

b1101033l91 

bl 101038192 

bl 101038193 

b1101033l94 

bl 101033195 

bl 101033196 

bl 101033197 

bl 101038198 

bl101038199 

bl101033200 

bl101033201 

bl101038202 

bl 101038203 

bl 101033204 

bl 101033205 

bl 101033206 

bl 101038207 

bl101033208 

bl101038209 

b1101033210 

bl101038211 

bl101033212 

bl101033213 

bl101033214 

bl101033215 

bl101033216 

bl101033217 

b110103a218 

b110103s219 

bl101033220 

bl101038221 

bl101038222 

bl101038223 

bl101038224 

strument Data\Buster\Buster Data\Projects\fluoro 

Sample ID 

GLPlO-01-01-11-056 

GLPlO-01-01-11-057 

GLPlO-01-01-11-058 

GLPlO-01-01-11-059 

GLPlO-01-01-11-060 

GLPl 0-01-01-11-070 

GLPlO-01-01-11-071 

GLPlO-01-01-11-072 

GLPlO-01-01-11-073 

GLPlO-01-01-11-074 

Solvent Blank (MUiQ Bement) 

Solvent Blank (MUiQ Bement) 

08008-194-10 

Solvent Blank (MUiQ Bement) 

GLPlO-01-01-11-089 

GLPlO-01-01-11-090 

GLPlO-01-01-11-091 

GLPlO-01-01-11-092 

GLPlO-01-01-11-093 

GLPlO-01-01-11-094 

GLPlO-01-01-11-095 

GLPlO-01-01-11-096 

GLPlO-01-01-11-097 

GLPlO-01-01-11-098 

Solvent Blank (MUiQ Bennent) 

Solvent Blank (MUiQ Bement) 

08008-194-9 

Solvent BIsnk (MUiQ Bement) 

GLPlO-01-01-11-109 

GLPlO-01-01-11-110 

GLPlO-01-01-11-111 

GLPlO-01-01-11-112 

GLPl 0-01-01-11-113 

GLPl 0-01-01-11-119 

GLPlO-01-01-11-120 

GLPlO-01-01-11-121 

GLPlO-01-01-11-122 

GLPlO-01-01-11-123 

Solvent BIsnk (MUIQ Bement) 

Solvent Blank (MUiQ Bement) 

08008-194-12 

Solvent Blank (MUiQ Bement) 

GLPl 0-01-01-11-124 

GLPlO-01-01-11-125 

GLPlO-01-01-11-126 

GLPlO-01-01-11-127 

GLPlO-01-01-11-128 

GLPlO-01-01-11-129 

GLPlO-01-01-11-130 

GLPlO-01-01-11-131 

GLPlO-01-01-11-132 

GLPlO-01-01-11-133 

Solvent BIsnk (MUiQ Bement) 

Solvent BIsnk (MHiQ Bement) 

08008-194-10 

Solvent BIsnk (MHiQ Bement) 

Vial Position 

55 

56 

57 

58 

59 

60 

61 

62 

63 

64 

92 

93 

10 

93 

65 

66 

67 

68 

69 

70 

71 

72 

73 

74 

93 

94 

9 

94 

75 

76 

77 

78 

79 

80 

81 

82 

83 

84 

94 

95 

12 

95 

85 

86 

87 

88 

89 

90 

34 

35 

36 

37 

95 

96 

10 

96 

rchemicals\waterBatch:b110103a 

Data File 

b1101033 

bl 101033 

b1101033 

bl 101033 

bl 101033 

bl 10103s 

bl 101033 

bl10103s 

bl 101033 

bl 101033 

bl 101033 

bl 101033 

bl 10103a 

bl 101033 

bl 101033 

bl 10103s 

b1101033 

bl 10103s 

b1101033 

bl 101033 

bl 101033 

bl 101033 

bl 101033 

bl 10103s 

bl 101038 

bl 101038 

bl 101038 

bl 101038 

bl 101038 

bl 101033 

bl 101033 

bl 101038 

bl 101038 

bl 101038 

bl 10103a 

bl 101033 

bl 101033 

bl 101033 

bl 101038 

bl 101038 

bl 101033 

bl 101038 

bl 10103a 

bl 101038 

bl 10103a 

bl 10103a 

bl 101038 

bl 101038 

bl 10103a 

bl 10103a 

bl 10103a 

bl 101033 

bl 101033 

bl 101033 

bl 10103s 

bl 101033 

Inj.Volume (pi) 

2.000 

2.000 

2.000 

2.000 

2.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

2.000 

2.000 

2.000 

2.000 

2.000 

10.000 

10.000 

10.000 

10.000 

2.000 

2.000 

2.000 

2.000 

2.000 

2.000 

2.000 

2.000 

2.000 

2.000 

10.000 

10.000 

10.000 

10.000 

2.000 

2.000 

2.000 

2.000 

2.000 

2.000 

2.000 

2.000 

2.000 

2.000 

10.000 

10.000 

10.000 

10.000 

Tab:Sample Set:SET1 AcqMethod:PFOA only.dam 

Comments 

DAL GW 133L 0 101103 (dH 1:10) 

DAL GW133L DB 101103 (dH 1:10) 

DAL GW133LLS 101103 (dH 1:10) 

DAL GW 133L MS 101103 (dU 1:10) 

DAL GW133L HS 101103 (dH 1:10) 

DAL GW 134L 0 101105 (dH 1:10) 

DAL GW134L DB 101105 (dH 1:10) 

DAL GW134L LS 101105 (dH 1:10) 

DAL GW 134L MS 101105 (dU 1:10) 

DAL GW134L HS 101105 (dH 1:10) 

MHiQ water TNI 0-0475 

MHiQ water TNI0-0475 

5.0 ng/mL FC std in Mlli Q V\feter 

MHiQ Water TNI0-0475 

DAL GW136S 0 101103 (dH 1:10) 

DAL GW 136S DB 101103 (dH 1:10) 

DAL GW136S LS 101103 (dH 1:10) 

DAL GW 136S MS 101103 (dU 1:10) 

DAL GW136S HS 101103 (dU 1:10) 

DALGW136L0 101103 (dU 1:10) 

DAL GW136L DB 101103 (dH 1:10) 

DAL GW136L LS 101103 (dU 1:10) 

DAL GW 136L MS 101103 (dH 1:10) 

DAL GW 136L HS 101103 (dH 1:10) 

MHIQ Water TNI0-0475 

MHi QVVfater TNI 0-0475 

2.5 ng/mL FC std in Mlli Q Water 

MHIQ water TNI0-0475 

DAL GW138S0 101110 (dU 1:10) 

DAL GW138SDB 101110 (dH 1:10) 

DAL GW138SLS 101110 (dH 1:10) 

DAL GW138S MS 101110 (dH 1:10) 

DAL GW138SHS 101110 (dH 1:10) 

DAL GWCW26R0 101110 (dU 1:10) 

DAL GWCW26RDB 101110 (dH 1:10 

DAL GWCW26RLS 101110 (dH 1:10) 

DAL GWCW26RMS 101110 (dH 1:10 

DAL GWCW26RHS 101110 (dH 1:10 

MHiQ Water TNI0-0475 

MHiQ water TNI0-0475 

25 ng/mL FC std in MUi Q water 

MHiQ water TNI0-0475 

DAL GWCW26L 0 101110 (dH 1:10) 

DALGWCW26L DB 101110 (dH 1:10) 

DAL GWCW26L LS 101110 (dU 1:10) 

DAL GWCW26L MS 101110 (dH 1:10 

DAL GWCW26L HS 101110 (dH 1:10) 

DAL GW 140R 0 101104 (dH 1:10) 

DAL GW140RDB 101104 (dH 1:10) 

DAL GW140RLS 101104 (dH 1:10) 

DALGW140RMS101104(dH1:10) 

DAL GW140RHS 101104 (dH 1:10) 

MUIQ water TNI 0-0475 

MUiQ water TNI 0-0475 

5.0 ng/mL FC std in MUi Q Water 

MUi Q water TN1.0-0475 

Printing Time; 

Printing Date; 

10:07:20 AM 

Friday, January 07, 2011 

Page 4 of 6 
•Buster J2930203 

Project: P:\Projects\Lab_lnstrument Data\Buster\Buster DataVProjectsVluororohemicals^wate 

Sample 

225 

225—^ 

227 

228 

229 

230 

231 

232 

233 

234 

235 

236 

237 

238 

239 

240 

241 

242 

243 

244 

245 

246 

247 

248 

249 

250 

251 

252 

253 

254 

255 

256 

257 

258 

259 

260 

261 

262 

263 

264 

265 

266 

267 

268 

269 

270 

271 

272 

273 

274 

275 

276 

277 

278 

279 

280 

Sample Name 

bl101033225 

bl101033226 

bl101033227 

bl101033228 

bl101038229 

bl101038230 

bl101038231 

bl101038232 

bl101038233 

bl101033234 

bl101033235 

bl101033236 

bl101033237 

bl101033238 

bl101038239 

bl101033240 

bl101033241 

bl101033242 

bl101033243 

b110103s244 

b1101033245 

bl101033246 

b1101033247 

bl101033248 

bl101038249 

b1101033250 

b1101033251 

bl101033252 

bl101038253 

bl101038254 

bl101033255 

bl 101033256 

bl101033257 

bl 101033258 

bl101038259 

bl101033260 

bl101033261 

bl101038262 

b1101033263 

b110103s264 

bl101033265 

bl101033266 

bl101033267 

bl101033268 

bl101033269 

b110103s270 

bl101033271 

bl101038272 

bl 101038273 

bl101038274 

bl 101038275 

b110103a276 

bl101038277 

bl101033278 

bl101033279 

bl101033280 

Sample ID 

GLPlO-01-01-11-134 

GLPlO-01-01-11-135 

GLPlO-01-01-11-136 

GLPlO-01-01-11-137 

GLPlO-01-01-11-138 

GLPlO-01-01-11-139 

GLPlO-01-01-11-140 

GLPl 0-01-01-11-141 

GLPlO-01-01-11-142 

GLPlO-01-01-11-143 

Solvent Bl3nk (MlliQ Bement) 

Solvent BIsnk (MUiQ Bement) 

08008-194-11 

Solvent Bl8nk (MUiQ Bement) 

GLPlO-01-01-11-144 

GLPlO-01-01-11-145 

GLPlO-01-01-11-146 

GLPlO-01-01-11-147 

GLPlO-01-01-11-148 

GLPlO-01-01-11-001 

GLPlO-01-01-11-002 

GLPlO-01-01-11-003 

GLPlO-01-01-11-004 

GLPlO-01-01-11-005 

Solvent BIsnk (MHiQ Bement) 

Solvent BIsnk (MlliQ Bement) 

08008-194-12 

Solvent BIsnk (MHiQ Bennent) 

GLPlO-01-01-11-006 

GLPlO-01-01-11-007 

GLPlO-01-01-11-008 

GLPlO-01-01-11-009 

GLPlO-01-01-11-010 

Solvent BIsnk (MHiQ Bement) 

Solvent BIsnk (MHiQ Bement) 

08008-194-10 

Solvent BIsnk (MlliQ Bement) 

GLPlO-01-01-11-017 

GLPlO-01-01-11-018 

GLPlO-01-01-11-019 

GLPlO-01-01-11-020 

Solvent BIsnk (MlliQ Bement) 

GLPlO-01-01-11-031 

GLPlO-01-01-11-032 

GLPlO-01-01-11-033 

GLPlO-01-01-11-034 

GLPlO-01-01-11-035 

Solvent BIsnk (MUiQ Bement) 

Solvent BIsnk (MUiQ Bement) 

08008-194-11 

Solvent BIsnk (MUiQ Bement) 

GLPlO-01-01-11-036 

GLPl 0-01-01-11-037 

GLPlO-01-01-11-038 

GLPl 0-01-01-11-039 

GLPlO-01-01-11-040 

Vial Position 

38 

39 

40 

41 

42 

43 

44 

45 

46 

47 

96 

97 

11 

97 

48 

49 

50 

51 

52 

53 

54 

55 

56 

57 

97 

98 

12 

98 

58 

59 

60 

61 

62 

98 

99 

10 

99 

63 

64 

65 

66 

99 

67 

68 

69 

70 

71 

99 

100 

11 

100 

72 

73 

74 

75 

76 

Data File 

bl 101033 

bl 10103s 

bl 101038 

bl 101033 

bl 101033 

bl 101033 

bl 101033 

bl 101033 

bl 101033 

bl 101033 

bl 101033 

bl 101033 

bl 101033 

bl 10103s 

bl 101038 

bl 101038 

bl 101038 

bl 101033 

bl 101038 

bl 101033 

bl 101038 

bl 101038 

bl 101038 

bl 101038 

bl 101033 

bl 101033 

bl 101033 

bl 101033 

bl 101033 

bl 101033 

bl 10103s 

bl 101033 

bl 101033 

bl 10103s 

bl 101033 

bl 101033 

bl 10103s 

bl 101033 

bl 10103s 

bl 101033 

bl 10103s 

bl 10103s 

bl 10103s 

bl 101038 

bl 10103a 

bl 10103a 

bl 101038 

bl 101033 

bl 101033 

bl 101033 

bl 10103s 

bl 101038 

bl 101038 

bl 10103a 

bl 10103a 

bl 101033 

rBatch:b110103a 

Inj.Volume (pi) 

2.000 

2.000 

2.000 

2.000 

2.000 

2.000 

2.000 

2.000 

2.000 

2.000 

10.000 

10.000 

10.000 

10.000 

2.000 

2.000 

2.000 

2.000 

2.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

Tab:Sample Set:SET1 AcqMethod:PF 

Comment s 

DAL GW141R0 101110 (dH 1:10) 

DAL GW141RDB 101110 (dU 1:10) 

DAL GW141RLS 101110 (dH 1:10) 

DAL GW141RMS 101110 (dU 1:10) 

DAL GW141RHS 101110 (dU 1:10) 

DAL GW142R0 101110 (dH 1:10) 

DAL GW142RDB 101110 (dU 1:10) 

DAL GW142RLS 101110 (dH 1:10) 

DAL GW142R MS 101110 (dU 1:10) 

DAL GW142RHS 101110 (dH 1:10) 

MUi QV\feter TNI 0-0475 

MUi QV\feiter TNI 0-0475 

10 ng/mL FC std in MUi Q water 

MUiQ water TNI 0-0475 

DALGW144R0 101110 (dU 1:10) 

DAL GW 144RDB 101110 (dH 1:10) 

DALGW144RLS 101110 (dH 1:10) 

DALGW144RMS101110(dH1:10) 

DAL GW144RHS 101110 (dH 1:10) 

DAL GW130R0 101105 (dH 1:100) 

DAL GW130RDB 101105 (dH 1:100) 

DALGW130RLS 101105 (dH 1:100) 

DAL GW130R MS 101105 (dH 1:100) 

DAL GW130RHS 101105 (dH 1:100) 

MHiQ water TNI 0-0475 

MHiQ Water TNI 0-0475 

25 ng/mL FC std in MHi Q Water 

MHi QWfeter TNI 0-0475 

DAL GW130S0 101105 (dH 1:100) 

DAL GW130S DB 101105 (dU 1:100) 

DAL GW 130S LS 101105 (dH 1:100) 

DAL GW 130S MS 101105 (dU 1:100) 

DAL GW130SHS 101105 (dH 1:100) 

MHi Q\Afeter TNI 0-0475 

MHi QV\fater TNI 0-0475 

5.0 ng/mL FC std in MHi Q Water 

MHiQ Water TNI 0-0475 

DAL GW131R0 101103 (dU 1:100) 

DAL GW131RDB 101103 (dH 1:100) 

DALGW131RLS 101103 (dH 1:100) 

DAL GW131RHS 101103 (dH 1:100) 

MUiQ water TNI 0-0475 

DAL GW132R0 101102 (dH 1:100) 

DAL GW132RDB 101102 (dU 1:100) 

DALGW132RLS 101102 (dU 1:100) 

DAL GW132RMS 101102 (dU 1:100) 

DAL GW132RHS 101102 (dH 1:100) 

MUiQ Water TNI 0-0475 

MUiQ Water TNI 0-0475 

10 ng/mLFC std in MHiQ Water 

MUiQ water TNI 0-0475 

DAL GW132S0 101102 (dU 1:100) 

DAL GW132SDB 101102 (dH 1:100) 

DAL GW132S LS 101102 (dU 1:100) 

DAL GW132S MS 101102 (dU 1:100) 

DAL GW132S HS 101102 (dU 1:100) 

OA only.dam 

Printing Time; 10:07:21 AM 

Printing Date: Friday, January 07, 

Page 5 of 6 
•Buster J2930203 

Project: P:\Projects\Lab_lnstrument Data\BustertBuster Data\Projects\fluoroTChemicals\wate 

Sample 

281 

282 

283 

284 

285 

286 

287 

288 

289 

290 

291 

292 

293 i 

294 , 

295 

296 

297 

298 

299 

300 

301 

302 

303 

304 

305 

306 

307 

308 

309 j4 

310 

311 

312 

313 

314 

315 

316 

317 

318 ^ 

319 

320 

321 

322 

323 

324 . 

Sample Name 

bl101033281 

bl 101033282 

bl101033283 

bl101033284 

bl101038285 

bl101033286 

bl101033287 

bl101033288 

bl101033289 

bl101033290 

bl101033291 

bl101038292 

bl101038293 

b110103a294 

b110103s295 

bl101033296 

bl101033297 

bl101033298 

bl101038299 

bl101033300 

bl101033301 

bl101033302 

bl101033303 

bl101033304 

bl101033305 

bl101033306 

b110103b307 

b110103b308 

b110103b309 

b110103b310 

b110103b311 

b110103b312 

b110103b313 

b110103b314 

b110103b315 

b110103b316 

b110103b317 

b110103b318 

b110103b319 

b110103b320 

b110103b321 

b110103b322 

b110103b323 

b110103b324 

Sami 

The 

lowe 

volur 

Sample ID 

Solvent Blank (MlliQ Bement) 

Solvent Blank (MlliQ Bement) 

08008-194-12 

Solvent BIsnk (MUiQ Bement) 

GLPl 0-01-01-11-061 

GLPl 0-01-01-11-062 

GLPl 0-01-01-11-063 

GLPl 0-01-01-11-064 

Solvent BIsnk (MUiQ Bement) 

GLPlO-01-01-11-075 

GLPlO-01-01-11-076 

GLPlO-01-01-11-077 

GLPlO-01-01-11-078 

Solvent BIsnk (MUiQ Bement) 

Solvent BIsnk (MUiQ Bement) 

08008-194-10 

Solvent BIsnk (MUiQ Bement) 

GLPlO-01-01-11-084 

GLPlO-01-01-11-085 

GLPlO-01-01-11-086 

GLPlO-01-01-11-087 

GLPlO-01-01-11-088 

Solvent BIsnk (MUiQ Bement) 

Solvent BIsnk (MUiQ Bement) 

08008-194-11 

Solvent BIsnk (MUiQ Bement) 

GLPlO-01-01-11-044 

GLPlO-01-01-11-045 

Solvent BIsnk (MUiQ Bement) 

GLPlO-01-01-11-070 

GLPlO-01-01-11-071 

GLPlO-01-01-11-072 

GLPl 0-01-01-11-073 

GLPlO-01-01-11-074 

Solvent BIsnk (MUiQ Bement) 

Solvent Blank (MUiQ Bement) 

08008-194-10 

Solvent Blank (MlliQ Bement) 

GLPl 0-01-01-11-134 

GLPl 0-01-01-11-135 

GLPlO-01-01-11-136 

Solvent BIsnk (MlliQ Bement) 

08008-194-9 

Solvent BIsnk (MlliQ Bement) 

Dies bll0103b307 thru b 

samples with high area c 

r volume and samples wi 

ne. OG 1-7-11 

Vial Position 

100 

91 

12 

91 

77 

78 

79 

80 

91 , 

81 

82 

83 

84 

91 

92 

10 

92 

85 

86 

87 

88 

89 

92 

93 

11 

93 

71 

72 

94 

73 

74 

75 

76 

77 

94 

95 

10 

95 

78 

79 

80 

95 

9 

96 

110103b32' 

ounts above 

th area cou 

Data File 

bl 10103a 

bl 101038 

bl 10103a 

bl 10103a 

bl 10103a 

bl 101033 

bl 101038 

bl 10103a 

bl 10103a 

bl 101033 

bl 101038 

bl 10103a 

bl 10103a 

bl 101038 

bl 10103a 

bl 101033 

bl 101033 

bl 101033 

bl 101038 

bl 10103s 

bl 10103s 

bl 10103a 

bl 101033 

bl 101038 

bl 10103a 

bl 101033 

bl 101033 

bl 10103s 

bl 101033 

bl 101033 

bl 101038 

bl 101038 

bl 101033 

bl 101033 

bl 10103s 

bl 101038 

bl 10103a 

bl 101033 

bl 101038 

bl 10103a 

bl 101038 

bl 101033 

bl 101038 

DataSETI 

i were adde 

: the calibra 

nts near the 

rBatch:b110103a 

Inj.Volume (pi) 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

10.000 

2.000 

2.000 

10.000 

2.000 

2.000 

2.000 

2.000 

2.000 

10.000 

5.000 

5.000 

5.000 

10.000 

10.000 

10.000 

5.000 

5.000 

5.000 

d to the sequ 

tion cun/e we 

LOQ were in 

Tab:Sample Set:SET1 AcqMethod:PFOA only.dam 

Comments 

MHiQ water TNI0-0475 

MHiQ water TNI 0-0475 

25 ng/mL FC std in MHi Q Water 

MHiQ water TNI 0-0475 

DAL GW134R0 101105 (dU 1:100) 

DAL GW 134R DB 101105 (dH 1:100) 

DAL GW134RLS 101105 (dH 1:100) 

DAL GW134RHS 101105 (dU 1:100) 

MHiQ Water TNI 0-0475 

^LGW135R 0 101105 (dU 1:100) 

DAL GW 135R DB 101105 (dH 1:100) 

DAL GW135RLS 101105 (dH 1:100) 

DAL GW135RHS 101105 (dH 1:100) 

MHiQ Water TNI 0-0475 

MHiQ water TNI 0-0475 

5.0 ng/mL FC std in MUi Q Water 

MHiQ Water TNI 0-0475 

DAL GW135L0 101105 (dH 1:100) 

DAL GW135LDB 101105 (dH 1:100) 

DAL GW135L LS 101105 (dH 1:100) 

DAL GW135L MS 101105 (dH 1:100) 

DAL GW135LHS 101105 (dH 1:100) 

MHiQ Water TNI0-0475 

MHiQ water TNI0-0475 

10 ng/mL FC std in Mlli Q Water 

MHiQ water TNI 0-0475 

DAL GW132L MS 101103 (dH 1:10) 

DAL GW132L HS 101103 (dH 1:10) 

MHiQ Water TNI 0-0475 

DAL GW134L0 101105 (dH 1:10) 

DAL GW134LDB 101105 (dU 1:10) 

DAL GW134LLS 101105 (dH 1:10) 

DAL GW134L MS 101105 (dU 1:10) 

DAL GW134L HS 101105 (dil 1:10) 

MHiQ Water TNI0-0475 

MHiQ water TNI 0-0475 

5.0 ng/mL FC std in MUi Q water 

MHiQ Water TNI 0-0475 

DALGW141R0 101110 (dH 1:10) 

DALGW141RDB101110(dH1:10) 

DALGW141RLS 101110 (dU 1:10) 

MHiQ Water TNI 0-0475 

2.5 ng/nnL FC std in MHi Q V\feter 

MHiQ Water TNI 0-0475 

ence on 1-7-11. 

re injected at a 

ected with a higher 

Printing Time: 10:07:21 AM 

Printing Date: Friday, January 07, 2011 

Page 6 of 6 
•Buster J2930203 

Acquisition Information 

Acquisiticn Nfethod: 

Created: 

Last Mxlified; 

CUlllKnt: 

Synchrcri zaticn Made: 

fluto-Eqiii 1 ihratioi: 

Acquisition Duration: 

Nuttier Of Scans: 

Periods m File: 

Acquisition Madule; 

Software versicr 

Agilent LC Puip Nfethod ErTTPrties 

PLItpMDdel: 

MinijTun Pressure (psi) 

Nbxinun EressucE (psi) 

Dead Volutie (pi); 

Ntednun Flow Kanp (nil/rain'): 

Nfexinun Pressure Ranp (psi/sec); 

Step Table; 

Stq: Tbtal Time (rain) 

0 0.00 

1 2.00 

2 14.50 

3 15.50 

4 16.50 

5 20.00 

left Oaipressibility: 

Ri^it Ctnpressibility; 

Left Dead Volute (pi); 

R i ^ Dead Vbluie (pi) 

left Stroke Vblune (pi) 

Flow Rate (pl/min) 

300 

300 

300 

300 

300 

300 

50.0 

115.0 

40.0 

40.0 

Ricfit Strcke Volune (pi) : 

Left Solvent: 

R i ^ Solveit: 

Al 

Bl 

Agilent Autorartpler Prqpertipfl 

Autoraitpler Majel: 

Syringe Size (pi): 

Injecticn Volune (pi) ; 

Draw Speed (pl/rain); 

Eject ^ee d (pl/min); 

Ifeedle Level (nin): 

TfenpeEHtiure Ctntirol 

V6£h is not used 

PPDA OTly.dam 

Thursday NavHiber 04 2010 13; 27; 53 JM 

Nfcnday Janiary 03 2011 08: 25: 49 AM 

PEQA only 

DC Sync 

Off 

20min0sec 

3809 

1 

Acquisition Nfethod 

Analyst 1.4.2 

i^ilen t 1100 IC Birary Puip 

0.0 

5801.0 

40.0 

100.0 

290.0 

A (%) B (%) 

97.0 3.0 

97.0 3.0 

5.0 95.0 

5.0 95.0 

97.0 3.0 

97.0 3.0 

-1.0 

-1.0 

fgilsJt 1100 TheniD Autoranpler 

100 

5.00 

200.0 

200.0 

0.00 

Not Used 

U ^ Custcra Irrjector Prograrr 

Agilent Cblum Oven Prcperties 

Left 'teiperature CC); 

R i ^ Tfenperature CC) 30.00 

Tfenperature Tblerance +/- CC); 

Start AajLtLsition Tblerance +/- (°C); 

Time Table 

Cblum Switching Valve 

(NDt Used) 

Installed 

Etsiticn for first sanple in the batch; 

No 

30.00 

1.00 

0.50 

R i ^ 

nse sma pasi tion for al l tuple s in the batch 

Tbtal TinE(min) 

0.00 Left 

4.00 Ri ^ 

Iteriod 1; 

Scans in Eteriod: 

Relative Start Time: 

Experiments in Eteriod: 

Period 1 B^erimEnt 

Scan Type; 

Etolarlty; 

Scan Nbde: 

Valve Ebsiticn 

3809 

0.00 msec 

1 

1: 

f m (MW) 

tfegative 

N/A 

Printing Time; 10:23:45 AM 

Printing Date; Monday, January 03, 2011 

Page 1 of 2 

cse i-'i-n 
*Buste r J293020 3 

I c n Scurce ; 

Resolutic n Ql; 

Resolutic n Q3; 

Tlrrhn Ppmy 

Unit 

Chit 

Intensit y Thres. ; 0.00 

Settlin g Time; 

NR E&use: 

M3^: ND 

ste p Size : 

Ql N6SS (anu) 

413.00 

0.0000 ttsec 

5.0070 msec 

0.00 anu 

Q3 Nbss (anu) 

369.00 

c p s 

Evelldnsec ) 

100.OC 

ftrair 

CS 

Off 

Star t 

-14.00 

-9.0 0 

Step 

-14.00 

-9.0 0 

CP- N6ss (anu) 

413.00 

03 N6ss (anu) 

219.00 

Dwell (msec) 

100. OC 

Eaiair 

CE 

CXE 

Star t Step 

-24.00 -24.00 

-15.00 -15.00 

Ql ybss (anu) 

413.00 

Q3 N6SS (anu) 

169.00 

Dwell(msec) 

100. OC 

Etaan 

CE 

Off 

Star t 

-28.00 

-9.0 0 

Step 

-28.00 

-9.0 0 

laraneter TSble (PerixxJ 1 B^eriment 1): 

O O 

CUR 

GSl 

GS2 

I S ; 

TEM 

i h e 

DP 

EE 

IQl 

6.00 

35.00 

45.00 

60.00 

-4500.00 

450.00 

CN 

-40.00 

-10.00 

10.00 

Printing Time: 10:23:45 AM Page 2 of 2 

Printing Date: Monday, January 03, 2011 
*** Buster J2930203 Batch Name: bll0103a.dab 

1 

2 

3 

4 

5 

6 

7 

8 

9 

10 

11 

12 

13 

'14 

15 

; i 6 

17 

18 

19 

20 

21 

22 

23 

24 

25 

26 

27 

28 

29 

•30 

31 

32 

33 

34 

35 

36 

37 

38 

,39 

,40 

'41 

42 

43 

44 

45 

46 

47 

48 

49 

50 

51 

52 

53 

Sampl e 

Nam e 

b110103a001 

b110103a002 

bllOIOSaOOa 

b110103a004 

b110103a005 

b110103a006 

b110103a007 

b110103a008 

bil0103a00 9 

b l 101033010 

b110103a011 

b110103a012 

bll'OIOSaOIS 

'bli6l03a01 4 

;b110103a015 

'b110103a016 

'b110103a017 

b110103a018 

b110103a019 

b110103a020 

b110103a021 

b110103a022 

b110103a023 

b110103a024 

b110103a025 

bii0103a02 6 

:b110103a027 

•b110103a028 

•b110103a029 

^b110103a030 

bl101033031 

b110103a032 

b1ldl03ab3 3 

bl101033034 

b110T03a035 

bl10103303 6 

bTlOi'033037 

b110f033038 

'b110103a039 

b110103a040 

Ibl101033041 

;b1101033042 

:b110103a043 

b110103a044 

b110103a045 

b110103a046 

b110103a047 

bl101033048 

b110103a049 

bl101033050 

b110103a051 

bl101033052 

b110103a053 

_. _ 

Sampl e ID 

Solvent Blank (MilliQ Element) 

Sol\«nt Bl3nl< (MilliQ Element) 

Solvent Blanl<lMiliiQ Element) 

Solvent Blanl< (MilliQ Element) 

Solvent Blenk (MilliQ Element) 

Solvent Blank (MilliQ Element) 

08008-194-1 Tsyste m suit 

08008-194-11 system suit 

08008-194-1 rsysfe m suit 

08008-194-11 system suit 

Solvent BianMrSilliQ Element) 

Solvent Blenk (MiiiiQ Element) 

08008-194-1 

08008-194-2 

08008-194-3 

'08008-194 ^ 

08008-194-5 

08008-1"94-6 

08008-194-7 

08008-194 ^ 

08008-194-9 

08008^194-10 

08008-194-11 

08008-194-12 

08008-194-13 

08008-194-14 

08008-194-15 

Solvent BIsnk (MilliQ Element) 

SoTvent Blenk (TviiTliQ^Eiement) 

Solvent Blank (MilliQ Element) 

08068-194-W 

Solvent Blank (MilliQ'Element) 

LCS-101230-1 

LCS-101230-2 

LCs;T0i23 M 

LCS-101230 ^ 

LCS-101230-5 

LCS-101230-6 

LCS-101230-7 

LCS-i01236-8 

LCS-101230-9 

Solvent Blank (MilliQ Element) 

Solvent Blank (MilliQEIement) 

08008-194"-9 

Solvent Blenk (MilliQ Element) 

LCS-101230-10 

LCS-101230-11 

LCS-10^1230^12" 

LCS-101230-13 

LCS-l6l230-1 4 

LCS-101230-15 

LCS-101230-16 

LCS-101230-17" 

-

Sampl e Commen t 

Milli QW3terTlM10-0475 

MilliQ Wate r TN10-0475 

Milli Q Wate r TN10-0475 

MilliQ Wate r 7^10-0475 

MilliQ Wate r ^10-047 5 

Milli Q Wate r TN10-0475 

10 ng/mL FC std in Milli Q Wate r 

10 ng/mL FC std in Milli Q Wate r 

10 ng/mL FC std in Milli Q Wate r 

10 ng/mL FC std in Milli Q Water 

Milli Q Water TN10-0475 

Milli Q Water TMi0-047 5 

0.025 ng/mL F C std in'Miili Q Weter 

0.03 ng/mL FC std in Milli Q Wafer 

0.04 ng/mL FC std in Milli Q Water 

0.05 ng/mL FC std in'Miili Q Water 

0.1 ng/mL F C std in Milli Q Water 

0.25 ng/mL FC std in Milli-Q Water 

0.5 ng/mL F C std in Milli Q Water 

1.0 ng/mL F C st d in Milli Q Water" 

2.5 ng/mL FC std in Milli Q Wate r 

5.0 ng/mL FC std in Milli Q Wate r 

10 ng/mL FC std in Milli Q Wate r 

25 ng/mL FC std in M'ilfi Q Water 

50 ng/mL F C st d in Milli Q Wate r 

75 ng/mL FC std7n Mli' Q Water 

100 ng/mL FC std in Milli Q Water 

Milli Q Wate r TNIO-O4T5 

Milli Q Wate r TNiO-0475 

Milli Q Wate r TNIO-0475 

5.0 ng/mL> C stdTTMili i Q Water 

Milli Q Wate r TNIO-0475 

O.'SppbLCS" 

0.5ppb LCS 

O.Sppb LCS 

Sppb LCS 

Sppb LCS 

Sppb LCS 

30ppb LCS 

36ppb LCS 

30ppb LCS 

Milli Q Wate r TNIO-0475 

Milli Q Wate r TNIO-0475 

2.5 ng/mL F C std in Milli Q Water 

Milli Q Wate r TIM10-047S 

O.Sppb LCS ECF 

O.Sppb LCS ECF 

O.Sppb LCS EC F 

Sppb LCS EC F 

Sppb LCS ECF 

Sppb LCS EC F 

30ppb LCS EC F 

30ppb LCS EC F 

" -

Sampl e Typ e 

Unknown 

Unknovi/n 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

. Unknown 

, Standard 

Stand3rd 

'St3nd3rd 

Standard 

Standsrd 

Stsndard 

Sland3rd 

Standard 

Stand3rd 

Standard 

Standsrd 

Standard 

Standsrd 

Standard 

' Stand3rd 

lUnknown 

Unknown 

Unknown 

Quality Control 

Unknown 

Qualify ControT 

Quality Control 

Quality Confror 

Quality Control 

•Quality Control 

Quality Control 

Quality Control 

•Quality Control 

Quality Control 

Unknown 

Unknown 

Quality Controf 

Unknown 

Quality Control 

Quality Control 

Quality Control 

Quality Control 

Quality Control 

Quality Control 

Quslity Control 

Quality Control 

Analyt e 

iPFO A 

iPFOA 

IPFOA 

•PFOA 

PFOA 

PFOA 

:PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFO A 

PFO A 

PFO A 

iPFOA 

jPFOA 

PFO A 

PFOA 

iPFOA 

"PFOA" " 

PFOA 

PFOA ' 

PFOA 

P?O A 

PFO A 

PFO A 

IPFOA 

PFO A 

|PF"O A 

iPFOA 

ffSpOA 

jPFO A 

"iPFOA 

'PFO A 

• PFOA 

'pFO A 

""PFOA 

' PFO A 

• PFO A 

PTOA"' 

|PFOA 

jPFOA 

iPFOA 

IPFOA 

ipFO A 

'PFO A 

PFOA 

'PTOA 

PFO A 

PFO A 

PFO A 

,PFOA 

•PFOA" 

122173 

52536 

28650 

12167 

12448 

10221 

1249S490 

12215120 

12324736 

11450824 

6606 

2332 

37830 

41393 

56098 

75572 

132768 

359735 

742330 

" 1459884 " 

3428859 

6123442 

11917422 

26587835 

40S33214 

51331914 

60209610 

•6282 

7216 

6020 

'6060156 

7890 

768848 

738280 

781204 

7346457 

7181734 

7129469 

27084675 

27247469 

27144534 

8416 

6881 

'323131 8 

6622 

'724663 

733363 

717394 

7896783 

7590038 

7693343 

31293719 

30923802 

Analyt e 

Retentio n 

Tim e (mi n 

•14.9 

14.8 

14.9 

14.9 

14.9 

14.8 

14.8 

14.8 

14.8 

14.8 

14.9 

14.8 

'14.8 

114.8 

'14.8 

'14.8 

^14.8 

14.8 

14.8 

14.8 

14.8 

14.8 

14.8 

14.8 

14.8 

:i4. 8 

;i4. 8 

|14.8 

|14:8 

^14.8 

h4.8"" 

14.8 

14.8 

'14.8 

14.8 

14.8 

14"8 

14:8 

!l4. 8 

114.8 

il4. 8 

114.8 

:i4 8 

!l4. 8 

14.8 

14.8 

14.8 

14; 8 

14.8 

14.8 

14.8 

•14.8 

14.8 

. _ - . 

Analyt e 

Concentratio n 

) (ng/mL ) 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

"N/A 

N/A 

"07025d 

"o.o'sod ' 

0.0400 

o.dsoo 

0.0999 

0.250 

0.500 

0.999 " 

2.50 

5.00 

9.99 

2"5.0" 

50.0 

75.0"' ' 

"99.9 

N/A 

WK 

N/A 

S.OO 

N/A 

""0T4"97 

0.497 

0.497 

4.97 

4.97 

4r9'7" 

29.9 

29.9" 

29'. 9^ 

N/A 

N/A 

'2.50 " 

N/A 

0.49"8" 

0.498 

0.498 

4.99 

4:99 ^ 

4.99 

29.9 

29.9 ' 

. 

Use 

Re CO re 

K 

E 

E 

E 

E 

E 

E 

E 

E 

E 

E 

E 

E 

D 

D 

'E 

E 

E 

E 

E 

E 

E 

E 

E 

E 

E 

E 

E 

E 

E 

E 

E 

E 

E 

Calculate d 

Concentratio n 

(ng/mL ) 

10.0871 

10.0343 

10.0161 

0.00363 

•0.00384 

0.00216 

10.3 

10.0 

10.1 

9.35 

< 0 

< 0 

0.0231 

0.0258 

!o.0370 

|o.OS17 

10.0952 

0.268 ' 

:0.560 

1.11 

2.65 

4.82 

9.77 

25.0 

50.2 

;No Intercept 

jNo Intercept 

I<0 

l < 0 

[4.77 " 

i0.000388 

lo.'ssd 

0.557 

07590 

5.83 

5.69 

is.es 

[25.6 

125.8 

125.7 

0.000787 

< 0 

|2.49 

< 0 

laS4 6 

055 3 

'0.S4'l ' 

6.29 

•6.03 

;6.12 

^31.3 

Accurac y (%) 

N/A 

N/A 

N7A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A ' 

N/A 

"N/'A 

N/A 

92.4 

86.0 

92.4 

103. 

95'.'3 

107. 

112. 

TTL 

106. 

"96.3"' 

97.8 

99.9 ' 

100. 

N/A 

N/A 

N/A 

N/A 

N/A 

95.3 

N/A 

T17: 

112. 

119; 

117. 

"115. 

114. 

85.6 

86.3" 

85.9 

N/A 

N/A' 

*99.7 

N/A 

'110. 

111. 

'idg . 

126. 

"121. 

123. 

105. 

30.8 T103: 

"' " 

Recor d 

Modifie d 

D 

D 

E 

E 

E 

D 

E 

E 

a 

E 

E 

D 

D 

n 

D 

D 

n 

D 

D 

D 

E 

E 

n 

D 

E 

D 

D 

D 

E 

D 

D 

E 

E 

E 

d E 

D 

E 

E 

D 

D 

E 

b 

E E 

E 

E 

E 

E 

E 

E 

E 

E 

Dilutio n . .. . „ 

Facto r Acquisitio n Date 

1 1/3/2011 10:27:06 A M 

1 1/3/2011 10:48:16A M 

1 ' 1/3/2011 11:09:18 A M 1 

1 1/3/2011 11:30:22 A M ; 

1 1/3/2'O-il 11:51:22 A M 

1 1/3/2011 12:12:25 PM 

1 1/3/2011" 12:33:31 PM ' 

1 1/3/2011 12:54:35 PM 

1 l/3/2"0"l"l"l:TS:37"PM 

1 1/3/2011 1:36:38 PM 

1 '1/3/2011 1:57:41 PM 

1 1/3/2011 2:18:44 PM 

'1 1/3/2011'2:39:46 PM "; 

1' "l7372'0'Tl 3:00:51 PM • 

1 1/3/2011 3:21:50 PM j 

1 T/3"/20il'3:42:52 PM ] 

1 1/3/2011 4:03:56 PM "' 

1 l73/20i l 4:24:59 P M ] 

1 "1/3/2011 4:46:01 P M , 

1 1/3/2dl"r5:0'7T04"PM" " j 

1 1/3/2011 5:28:09 P M 

1 l"/3/20Ti 5:49:12 P M ": 

1 1/3/2011 6:10:17 PM 

1 1/3/2011 6:31:20 PM • 

1 1/3/2011 6:52:20 P M j 

1 1/3/2011 7:13:28 PM i 

1 l73/2'011 7:34:34 PM | 

1 1/3/2011 7:55:36 PM 

1 1/3/2011 8:16:38 PM ; 

1 1/3/2011 8:37:40 PM 

1 1/3/2011 8:58:43 P M 

1 "1/3/2011 9:19:54 P M 

1 T/3"/20ir9741:02 PM ' ' ; 

1 1/3/2011 10:02:08 PM 

f "T/3/2dlTl"0:"23:15""PM i 

1 1/3/2011 10:44:15 P M ] 

1 1/3/2011 11:05:17 P M j 

1 "173/2611 11:26:26 P M ; 

1 1/3/2011 11:47:36 P M ; 

1 " 'l74"/2diri2:08:3 8 AM" " 

1 "l74/2"011 12:29:43 A M • 

1 ' '1/472'0"11 12:50:47 A M i 

1 1/4/2011 1:11:53 A M 

1 " 'T7472dlT"l:3"2:58 A M ; 

1 ' 1/472"0l"ri:"54:04 A M 

1 1/4/2011 "2:15:13 A M 

1 1/4/2011 2:36:19 A M 

i 'l7"472011 2r57:23"AM 

1 1/4/2011 3:18:29 A M 1 

1 "l74/'2011 3:39:37 A M j 

1 1/4/2011 4:00:44 A M 

1 1/4/2011 4;21:50 A M , 

1 1/4/2011 4:42:54 A M \ 

_ - , 

Data printed by STW 

Printing Time: 1:04:40 PM 

Printing Date: Tuesday, January 18, 2011 

Page 1 of 7 

^\^''^' ' ^( ^ 
*** Buster J2930203 Batch Name: bll0103a.dab 

54 

55 

56 

57 

S8 

59 

60 

61 

62 

63 

64 

65 

66 

67 

68 

69 

70 

71 

72 

73 

74 

75 

76 

77 

78 

79 

80 

81 

82 

83 

84 

85 

86 

87 

88 

89 

90 

91 

92 

93 

94 

95 

96 

97 

98 

99 

100 

101 

102 

103 

104 

105 

106 

Sampl e _ , , „ 

Nam e Sampl e ID 

b110103a054 LCS-101230-18 

b l 101033055 Solvent Blank (MilliQ Element) 

b l 101033056 Solvent Blank (MilliQ Element) 

b l 101033057 08008-194-11 

b l 101033058 Solvent Blank (MilliQ Element) 

b110103a059 GLP10-01-01-11-150 

b1101033060 GLP10-01-01-11-151 

b110103a061 GLP10-01-01-11-152 

b l 101033062 GLP10"-bl-01-1l"-15""3 

b l 101033063 GLPlO-01-01-11-154 

b110103a064" GLP10"^T-O1-Tl-T55 

b110103a065 GLPIO-OI-OI-'-IT^ISe 

b l 101033066 GLPlO-01-01-11-157 

b11010"33067 GLP'lMl'^"i^-l'5 8 

b1101033068 GLP10-01-01-11-159 

b1101033069 Solvent Bla7fk'(MilTiQ Element) 

b110103a070 Solvent Blank (MilliQ Element) 

b110103a071 08008-l"94-l"o" 

b1101033072 Solvent Blank (MilliQ Element) 

b110103a073 GLPlO-01-01-11-160 

b110103a074 GLPlO-01-01-11-161 

b l 101033075 GLPl6-bl"-Ol"-l"l~162"" 

b110103a076 GLPlO-01-01-11-163 

b l 101033077 GLPlO-01-01-11-164 

b110103a078 GLP10-0T5ri-l'vi6 l 

b1101033079 GLP10-01-01-11-166 

b l 101033080 GLPlO-01-01-11--i67 

b l 101033081 GLPIO-Ol-OI-l 1-168" 

b"lT0103"a0'8"2 GL"pi0^l'^-l'l^16" 9 " " 

b1101033083 Solvent Ble'nk" (Mii b Erem"ent) 

b l 101033084 Solvent Blank (MilliQ Element) 

b l 101033085 08008-194-9 

b l 101033086 Solvent Blenk (MilliQ Element) 

•b1101033087 GLP10-01-01-12-009 

b1101033088 GLP10-01-01-11-016 

b1101033089 GLP10-01-01-11-149 

b1101033090 GLP10-01-01-11-065 

b110103a091 GLPIO-Oijdl-l"^-*) ^ 

b110103a092 GLPlO-01-01-11-067 

b110103a093 GLPl"0-01^1^T-d68 " 

b110103a094 GLPlO-01-01-11-069' 

b110103a095 Solvent Blank (MilliQ Element) 

b l 101033096 Solvent Bl3nk (^filli'Q Element) 

b1101033097 08008-l"94"-8 " 

b l 101033098 Solvent Ble'nk (IVIilliQ E'lement) 

b l 101033099 G"LP10-dl^l"-"l 1-079 

b l 101033100 GLPlO-01-01-11-080 

b1-i01033l01 GLP'lO'-6l^1-lT68 1 

b1101033l02 GLPlO-01-01-11-082 

b l 101033103 GL'P10-d"l-d"l-i~1-'0"8"3 " 

b1101033l04 GLPIO-01-01-11-0'99 

b110103a105"GLP10-01-01-l'l-l'00 

b110103a106'GLP10-bl-dl-11-101 

Sampl e Commen t 

30ppb LCS ECF 

Milli Q Water TNIO-0475 

Milli Q Water TNIO-0475 

10 ng/mL FC std in Milli Q Water 

Milli Q Water TNIO-0475 

Trip Blank Set 1 Semple 

Trip Blank Set 1 LS 

Trip Blank Set 1 M S 

Trip Blank Set 1 MHS 

Trip Blank Set 1 HS (dil 1:100) 

Trip Blank Set 2 Sample 

Trip Blank Set 2 LS 

Trip Blank Set 2 M S 

Trip BIsnk Set 2 MH S 

Trip BIsnk Set 2 HS (dil 1:100) 

Milli Q Water TNIO-0475 

Milli Q Water TNIO-0475 

5.0 ng/mL F C st d in Milli Q Wate r 

Milli Q Water TNIO-0475 

Trip BIsnk Set 3 Ssmpfe 

Trip BIsnk Set 3 LS 

Trip BIsnk Set 3 M S 

Trip BIsnk Set 3 MHS 

Trip Blank Set 3 HS (dil 1:100)" 

Trip Blank Set 4 Sample 

Trip Blank Ser4L S 

Trip BIsnk Set 4 M S 

Trip Blank Set 4 MHS 

Trip BIsnk Set 4 HS (dil 1:100) 

Milli Q Water TNIO-0475 

Milli Q Wsle r TNIO-0475 

2.5 ng/mL FC std in Milli Q Wste r 

Milli Q Water TNIO-0475 

DAL SS 607R RB 0040 

DAL GW 130L RB 101105 

DALG W 144RR B 101110 

DALG W 134S 0 fOIIOS 

DALG W 134SD B 101105 

DALG W 134S LS 101105 

DALG W 134S M S 101105 

DALG W 134S HS 101105 

Milli Q Water TNIO-0475 

Milli Q Wster TNIO-0475 

1.0 ng/mL FC std in Milli Q Wste r 

Milli Q Water TNIO-0475 

DALG W 135S 0 101105 

DALG W 135S DB 101105 

DALG W 135S LS 101105 

DALG W 135S M S 101105 

DALG W 135S HS 101105 

DALG W 137S 0 101109 

DALG W 137S DB 101109 

DALG W 137S LS 101109 

Sampl e Typ e 

Quality Control 

Unknown 

Unknown 

Quality Control 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

'Unknown 

' Unknown 

' Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

.Quality Control 

Unknown 

Unknown 

Unknown 

Unknovm 

Unknown 

Unknown 

Unknown 

! Unknown 

Unknown 

lUnknown 

rOnknown 

lUnknown 

1 Unknown 

1 Quality Control 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

LJnknown 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Quslity Control 

lUnknown 

lUnknown 

I Unknown 

[Unknown 

i Unknown 

j Unknown 

; Unknown 

' Unknown 

i Unknown 

Pea k Nam e ,^„^„,^ j 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

;PFOA 

PFOA 

iPFQA 

PFOA 

.PFOA 

PFOA 

'PFO A 

PFOA 

PFOA 

PFO A 

PFOA 

PFOA 

'PFO A 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

•pFOA 

ipFO A 

tpFO A 

IPFOA 

fpFO A 

'PFO A 

"PF"6A" 

IPFOA 

IPFOA 

PFOA 

'P'FOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

• PFOA 

;PFOA 

jPFO A 

IPFOA 

IPFOA 

IPFOA 

IPFOA 

IPFOA 

IPFOA 

;PFOA 

30841439 

7447 

5266 

11720413 

5464 

8037 

1421703 

12846497 

22141613 

12654575 

8204 

1415310 

13193191 

21741202 

12417320 

11757 

11846 

6012794 

7724 

17118 

1401751 

12602629 

22478050 

12695449 

29675 

1389272 

12576565 

21456264 

12004570 

14359 

7659 

3161679 

10450 ^ " 

8141 

9"801 

7163 

1483145 

1404255 

1819806 

4262639 

22681178 

16634 

10130 

1431336 

10796 

3595339 

3465272 

3756038 

6161559 

24122281 

366990 

359413 

467843 

Analyt e 

Retentio n 

Tim e (mi n 

14.8 

14.8 

14.8 

14.8 

14.8 

14.8 

14.8 

'14.8 

14.8 

114.8 

14.8 

14.8 

14.8 

14.8 

14.8 

14.8 

14.8 

14.8 

14.8 

14.8 

14.8 

14.8 

14.7 

14.8 

14.8 

14.8" 

14.8 

114.7 

• 14.8 

•14.8 

Ii4. 8 

,14.8 

!l"4T7 

14.8 

14.8 

14.8 

'l4. 7 

14.7 

14.7 

14.7 

14.7 

14.7 

14.8 

'14.8 

'14.8 

:14.7 

'14.8 

114.7 

'14.8 

'14.7 

14.8 

14.8 

:i4. 8 

Analyt e 

Concentratio n 

) (ng/mL ) 

29.9 

N/A 

N/A 

9.99 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A " '" " 

N/A 

' N/'A 

" N7 A • 

N/A 

N/A 

N/A 

5.00 

N/A 

N/A ' ' 

N/A 

N/A" 

N/A 

N/A 

'N/A " 

N/A 

N/A 

'N/A' - • -

N/A 

'N/A 

2.50 

'NTA 

N/A 

"N7A 

N/A 

"NTA "" 

"N'/A 

N/A' 

N/A 

N/A 

N/A 

N/A 

0.999 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

Calculate d 

_ _, Concentratio n 

"""^• ^ (ng/mL ) 

E 30.6 

0000051 6 

< 0 

E 9-59 

< 0 

0.000499 

1.08 

;10.6 

199.1 

1040. 

0.000625 

'1.08 

10.9 

96.9 

1020. 

0.00332 

0.00339 

E "'^'3 

0.000261 

0.00739 

1.07 

10.4 

101. 

1050. 

100169 

11.06 

110.4 

195.4 

•985. 

10.00529 

0.000212 

E ;2-44 

i"0.00233 

i0.000578 

10.00184 

< 0 

5.64 

5.34 

6.95 

16.6 

102. 

0.00702 

10.00209 

" E '1-09 

iO.00259 

|13.9 

i13.4 

.114.5 

124.2 

110. 

10.273 

026 8 

•035 0 

Accurac y 

(%) 

102. 

N/A 

N/A 

96.0 

N/A 

N/A 

N/A 

N/A 

,N/A" 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

94.5 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

IN/A 

!N/A 

jN/A 

'N/A 

iN/A 

'97.5 

,N7A 

N/A 

N/A 

N/A 

N7>. 

N/A 

N/A 

N/A" 

N/A 

N/A 

N/A 

'109. 

N/A 

N/A 

N/A 

N/A 

IN/A 

;N/A " 

IN/A 

N/A 

• N/A 

Recor d 

Modifie d 

E 

D 

a 

E 

E 

E 

n 

E 

E 

• D 

D 

E 

E 

D 

E 

E 

D 

E 

D 

c: 

a 

n 

n 

b 

D 

n 

E 

E 

b 

E E 

E 

E 

E 

E 

E 

E 

E 

E 

E 

D 

E 

E 

E 

E 

E 

E 

E 

E 

E 

Dilutio n 

Facto r 

100 

•'•--- -

!5 ' 

100 

100 

"•r"" 

ii 

h lib'o 

1 

-" 1 - " 

i i 

H" " 

""5" 

5 

5 

l'5 

•'5 

'1 

; i 

"'"l 

l l 

•5 

i5 

fs" 

15 

5' ' ' 

11 

' l 

l l 

Acquisitio n Date 

1/4/2011 5:03:57 A M • 

1/4/2011 5:25:03 A M 

1/4/2011 5:46:16 A M 

1/4/2011 6:07:20 A M 

1/4/2011 6:28:25 A M 

1/4/2011 6:49:37 A M 

1/4/2011 7:10:43 A M 

1/4/2011 7:31:59 A M 1 

1/4/2011 7:53:01 AM" 

1/4/2011 8:14:04 A M 1 

1/4/2011 8:35:07 A M 

1/4/2011 8:56:11 A M 

1/4/2011 9:17:18 A M 

1/4/2011 9:38:28 A M 

1/4/2011 9:59:28 A M 

1/4/2011 10:20:34 A M 

1/4/2011 10:41:49 A M 

1/4/2011 11:02:53 A M 

1/4/2011 11:23:59 A M 

1/4/2011 11:45:05 A M 

1/4/2011 12:06:15 P M 

1/4/2011 12:27:23 P M 

1/4/2011 12:48:26 PM 

1/4/2011 1:09:32 P M 

1/4/2011 1:30:40 P M 

"1/4/2011 1:51:45 "PM "i 

1/4/2011 2:12:52 P M 

'1/4/2011 2:33:57 P M 1 

1/4/2011 2:55:03 P M ] 

1/4/2011 3:16:10 P M 

1/4/2011 3:37:18'PM 7 

1/4/2011 3:58:21 P M 1 

1/4/2011 4:19:28 PM ' ' , 

1/4/2011 4:40:33 P M • 

1/4/2011 5roi:46"PM' " 1 

1/4/2011 5:22:52 P M 

"1/4/2011 5:'44;03 PM 

1/4/2011 6:05:11 P M 

1/4/2011 6:26:10 P M 

1/4/2011 6:47:07 P M 

1/4/2011 7:08:08 P M • 

1/4/2011 7:29:11 P M i 

1/4/2011 7:50:14 P M 

1/4/2011 8:11:20 P M 

1/4/2011 8:32:29 P M 

1/4/2011 8:53:36 P M i 

1/4/2011 9:14:43 PM ' 

1/4/2011 9:35:50 P M 

1/4/2011 9:56:52 P M 

1/4/2011 10:17:58 PM 

1/4/2011 10:38:57 PM 

1/4/2011 11:00:05 PM 

1/4/2011 11:21:16 PM ; 

Data printed by STW 

Printing Time: 1:04:40 PM 

Printing Date: Tuesday, January 18, 2011 

Page 2 of 7 
*** Buster J2930203 Batch Name: bll0103a.dab 

107 

108 

109 

110 

111 

112 

113 

114 

115 

116 

117 

118 

119 

120 

121 

122 

123 

124 

125 

126 

127 

128 

129 

130 

131 

132 

133 

134 

,135 

136 

137 

138 

139 

140 

141 

142 

143 

144 

145 

146 

147 

148 

149 

150 

151 

152 

153 

154 

155 

156 

157 

158 

159 

Sample 

Name 

bl101033107 

b110103al08 

bl101033109 

b1101033l10 

bl101033111 

b110103a112 

b1101033l13 

b1101033l14 

b110103al15 

b110103a116 

b1101033l17 

b1101033l18 

b110103sl19 

b1101033l20 

bll01033l21 

b110103s122 

bll01033l23 

bl101033124 

b1l01033l25 

"bll0103al26 

b1101033l27 

bll0103a128 

b1101033l29 

bl101033130 

b110103s131 

b"ll0103al"32 

•b1101033l33 

bll0103a134 

bl101033135 

'bll0103a136 

blToi033137 

b110103"a138 

Sample ID 

GLPlO-01-01-11-102 

GLPlO-01-01-11-103 

Solvent BIsnk (MilliQ Element) 

Solvent BIsnk (MilliQ Element) 

08008-194-11 

Solvent BIsnk (MilliQ Element) 

GLPld-01-01-l"l-"f04 

GLP10-01-01-11-105 

GLP10-01-dl-1l'l"d6 

GLPlO-01-01-11-107 

GLPl"0-dT<11-'l1-"ld8 ' 

GLP1"0^1-0~1-11-11'4 

GLP10-01-01-1l"-ri5" 

GLP10-01-dT-11-116" 

GLPlO-01-01-11-117 

GLPlO-01-01-11-118 

Solvent Blank (MilliQ Element) 

Solvent Blank "(MJiliQ Element) 

08008-194-10 " 

Solvent Blank (MilliQ Element) 

GLP10-01-01-11-011 

GLPlO^l'-dl'ri^'lT ' 

GLP10-01-01-11-013 

GLP10-0"l'-dl'-11^4 

GLP10-01-01-11-015 

GCP10-0'T531-lT-d21 " 

GLP10-01-01-11-022 

GLP10^1-"di;i'l-'d23 ' 

GLP10-dl7dl-Tv024 " 

GLPlO-01-01-11-025 

Solvent "Blsnk'(M"i"llTQ"Ele"ment) 

Solvenf BIsnk fMJiJi'Q Element) 

bll0103a139 08008-194-9 

bl101033140 

bl'-io'ld3'al'4'l 

bl101033142 

blldl"033l43 

bl101033144 

bl101033145 

b110103al46 

bl101033147 

bl101033148 

bl101033149 

bl101033150 

bll0103sl51 

b110103s152 

bll01033l53 

bll0103s154 

b1101033l55 

bll0103s156 

b110103s157 

bl10103s158 

bll0103s159 

Solvent BIsnk (MilliQ Element) 

GLPlO-01-01-11-026 

GLPlO-01-01-11-027 

GLPlO-01-01-11-028 

GLPl d-0T-O'l -"l"l -029 

GLPld<l1-0"l-^ 1-030 

GLPl'0^"l-Ori 1-041 

GLPlO-01-01-11-042 

GLPlO-01-01-11-043 

GLPlO-01-01-1-1-044 

GLPlO-01-01-11-045 

Solvent BIsnk (MilliQ Element) 

SoTvent BIsnk (MJIIiQEIement) 

08008-194-12 

Solvenf BIsnk (MilliQ Element) 

GLPlO-01-01-11-046 

"GLPlO-OI-dT-l 1-047 

GLP10-bl-01-llk)4"8 

GLP10-01-01-11-049 

'GL'P10-01"-01-1 1-050 

Sample Comment 

DALGW 137S MS 101109 

DAL GW 137S HS 101109 

Milli Q Water TNIO-0475 

Milli Q Wster TNIO-0475 

10 ng/mL FC std in Milli Q Wster 

MilliQ Wster TNIO-0475 

DALGW 137L0 101109 

DALGW 137L OS 101109 

DALGW 137LLS 101109 

DALGW 137LMS 101109 

DAL GW 137L HS 101109 " 

DALGW 138L0 101110 

DALGW 138LDB 101 no " 

DALGW 138LLS 101110 

DALGW 138LMS 101110 

DALGW 138LHS 101110 

Milli Q Wster TNIO-0475 

Milli Q Water TNIO-0475 

5.0 ng/mL FC std in Milli Q Wster 

' Milli Q Water TNIO-0475 

DALGW 130L0 101105 (dil 1:10) 

DAL GW 130L DB 101105 (diM:'ld) 

DALGW 130LLS 101105 (dil 1:10) 

DALGW 130LMS 101-105 (dil i:ld) 

DALGW 130LHS 101105 (dil 1:10) 

DALGW 131S0 101103 (dlfLld)" ' 

DALGW 131S DB 101103 (dil 1:10) 

DALGW 131S LS 101103 (dil 1:10) 

DAL GW 131S HS 101103 (dil "l:Td) " 

DALGW 131S MS 101103 (dil 1:10) 

Milli Q Water TN10-d475 

MilliQ Water TNIO-0475 

2.5 ng/mLFC std in Milli Q Water " 

MilliQ Water TNIO-0475 

DAL GW'131L 0 101l"03 (dil 1:l"d) 

DALGW 131LDB 101103 (dil 1:10) 

DALGW 131LLS 101103 (dif 1:10) 

DALGW 131LMS 101103 (dil 1:10) 

DALGW 131LHS 101103 (dil 1:10) 

DALGW 132L0 101103 (dil 1:10) 

DALGW 132LDB 101103 (dil 1:10) 

DALGW 132LLS 101103 (dil 1:10) 

DAL GW 132L MS 101103 (dil 1:10) 

DAL GW 132L HS 10il03'(dil 1:10) 

Milli Q Water TN10-0475 

Milli Q Water TNIO-0475 

25 ng/mL FC std in Milli Q Wster 

Milli Q Wster TNIO-0475 

DAL GW 133R 0 101102 (dil 1:10) 

DALGW 133RDB 101102 (dil 1:10) 

DALGW 133RLS 101102 (dil 1:10) 

DALGW 133RMS 101102 (dil 1:10) 

DALGW 133RHS 101102 (dil 1:10) 

Sample Type 

Unknown 

Unknown 

Unknown 

Unknown 

'Quality Control 

Unknown 

Unknown 

Unknown 

Unknown 

lUnknown 

Unknown 

. Unknown 

LJnknown 

ijnknown 

Unknown 

Unknown 

Unknown 

Unknown 

Quslity Control 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Quslity Control 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

i Quslity Control 

Unknown 

• Unknown 

• Unknown 

• Unknown 

Unknown 

Unknown 

Peak Name ,^^^„,^ , 

PFOA 1725661 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA ' 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA " 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

13210569 

10126 

6229 

11631825 

12828 

480722 

482391 

608860 

1829729 

12920917 

1565046 

1465502 

1628218 

2831875 

13550199 

7041 

3059 

5878650 

5663 

8653188 

8822514 

8856615 

9124240 " 

18739190 

674635 

647153 

671531 

3301682 

915445 

6838 

6325 

3164428 

7152 

10"856l"4T 

11393589 

10787841 

11828686 

20316820 

36353492 

36958687 

38739064 

43620505 

' 75121396" 

15349 

14303 

24278311 

7292 

12907656 

11878519 

12373815 

13032826 

21672309 

Analyte 

Retention 

Time (min 

14.8 

14.8 

14.8 

14.8 

14.8 

14.8 

14.8 

14.8 

14.8 

,14.8 

,14.8 

14.8 

'14.8 

14.8 

14.8 

14.8' 

'14.8 

14.8 

14.8 

'14.8 

14.8 

14.8 

14.8 

14.8 

14.8 

14.7" 

14.7 

14.7 

14.7 

14.7 

ll"4.8 

14.8 

114.8 

14.8 

14;8"" " ' 

14.8 

,14.8" 

14.8 

14.8 

14.8 

!l4.8 

14.8 

14.7 

"14.8 

,14.8 

^14.8 

J14.8 

i14.8 

'14.8 

;14.8 

14.8 

14.8 

14.8 

Analyte 

Concentration 

(ng/mL) 

N/A 

N/A 

N/A 

N/A 

9.99 

N/A 

N/A' 

N/A 

N/A 

N/A 

N/A 

N/A 

N/'A' 

N/A 

N/A 

N/A 

N/A 

N/A 

5.00 

"N7A" 

N/A 

N/A"' 

N/A 

N/A ' 

N/A 

N7A " " 

N/A 

"N/A 

N/'A 

N/A 

~N7A 

N/A • 

zFo" 

N/A 

N/A 

N/A 

"N/A 

N/A" 

N/A 

N/A 

"N/A 

N/A 

N/A 

N/A"" 

N/A 

N/A" 

25.0 

N7A 

N/A 

N/"A 

N/A 

N/A 

N/A 

Calculated 

JlT,.rM Concentration Record , , , , (ng/mL) 

1.32 

10.9 

0.00208 

< 0 

E s^s-i 

000413 

0360 

0361 

• 0458 

1.40 

10.7 

1.19 

1.12 

1.24 

2.18 

11.2 

< 0 

< 0 

E "62 

< 0 

,69.3 

70.7 

71.0 

73.3 

162. 

,25.4 

,24.4 

125.3 

127. 

34.6 

< 0 

< 0 

E '2.44 

< 0 

88:3 

93.0 

87.7 

96.9 

179. 

398. 

410. 

451. 

No Intercept 

'No Intercept 

: 0.00604 

• 0.00525 

E |22.2 

< 0 

107. 

'97.3 

102. 

108. 

193. 

Accuracy 

(%) 

N/A 

N/A 

N/A 

N/A 

95.2 

N/A 

,N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

92.3 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

'97.6 

N/A 

N/A 

N/A 

",N/A" 

N/A 

N/A 

IN/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

188.9 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

Record 

Modified 

E 

E 

E 

E 

D 

D 

E 

E 

E 

E 

E 

E 

E 

E 

E 

E 

E 

E 

E 

E 

E 

E 

E 

E 

E 

E 

E 

E 

E 

E 

E 

E 

E 

E 

E 

E 

E 

E 

E 

E 

E 

~E 

E 

E 

b 

E 

E 

E 

E 

E 

E 

E 

E 

Dilution 

Factor 

'-] 

l l 

11 

l"l ' 

7 i ' 

10 

10 

10 

10 

10 

"'50 

50 

150 

"J5d 

l50 

"ll " 

'1 

Ti 

11 

•To 

10 

Tfd " 

'10 

10 

10 

.10 

10 

* 1 0 

'"id " "' 

1 

,1 

1 

1 

10 

110 

10 

10 

" 10 

Acquisition Date 

1/4/2011 11:42:26 PM 

1/5/2011 12:03:37 AM 

1/5/2011 12:24:52 AM 

1/5/2011 12:46:01 AM 

1/5/2011 1:07:06 AM 

1/5/2011 1:28:18 AM 

1/5/2011 1:49:25 AM 

1/5/2011 2:10:34 AM 

1/5/2011 2:31:40 AM ' 

1/5/2011 2:52:51 AM 

1/5/2011 3:14:04 AM 

1/5/2011 3:35:18 AM 

1/5/2011 3:56:32 AM 

1/5/2011 4:17:40 AM 

1/5/2011 4:38:46 AM , 

1/5/2011 4:59:55 AM 

1/5/2011 5:21:05 AM 1 

1/5/2011 5:42:16AM 

1/5/2011 6:03:23 AM 

1/5/2011 6:24:36 AM 

1/5/2011 6:45:46 AM 

1/5/2011 7:06:53 AM , 

1/5/2011 7:27:55 AM 

1/5/2011 7:48:59 AM 

1/5/2011 8:10:06 AM 

1/5/2011 8:31:11 AM ": 

1/5/2011 8:52:15 AM ; 

1/5/2011 9:13:18 AM , 

1/5/2011 9:34:26 AM ", 

1/5/2011 9:55:33 AM 1 

" 1/5/2011 1ft16:33"AM ' 

1/5/2011 10:37:38 AM 1 

1/5/2011 10:58:51 AM 

1/5/2011 11:20:00 AM 

"T/5720TT 11:4"T:10"AM " 

1/5/2011 12:02:19 PM 

1/5/'2011 "12:23:28"PM"""^ 

1/5/2011 12:44:40 P"M • 

11/5/2011 1:05:46 PM • 

l/5/2dl1 1:26:50 PM 

1/5/2011 1:47:59 PM 

1/5/2011 2:09:10 PM ' 

1/5/2011 2:30:16 PM 1 

'l/5/2dlf 2:51:23 PM 1 

1/5/2011 3:12:29 PM 

1/5/2011 3:33:38 PM 

1/5/2011 3:54:50 PM ; 

1/5/2011 4:15:57 PM 1 

1/5/2011 4:37:09 PM 

1/5/2011 4:58:20 PM 

1/5/2011 5:19:25 PM 1 

1/5/2011 5:40:32 PM 

175/201 i 6:01:45 PM 

Data printe d by STW 

Printin g Time: 1:04:40 PM 

Printin g Date: Tuesday, January 18, 2011 

Page 3 of 7 
Buster J2930203 Batch Name: bll0103a.dab 

160 

161 

162 

163 

164 

165 

166 

167 

168 

169 

170 

171 

172 

173 

174 

175 

176 

177 

178 

179 

180 

181 

182 

183 

184 

185 

186 

187 

188 

189 

190 

191 

192 

193 

194 

195 

196 

197 

198 

199 

200 

201 

202 

203 

204 

205 

206 

207 

208 

209 

210 

211 

212 

%z': «-p'«'=> 

b110103a160 GLPlO-01-01-11-051 

b110103a161 GLP10O1-01-11-052 

b l 101033162 GLPlO-01-01-11-053 

b l 101033163 GLPlO-01-01-11-054 

b l 101033164 GLPlO-01-01-11-055 

b1101033165 Solvent BIsnk (MilliQ Element) 

b l 101033166 Solvent BIsnk (MilliQ Element) 

b110103s167 08008-194-11 

b l 101033168 Solvent Blank (MilliQ Element) 

b110103al69 GLPlO-01-01-11-056 

b110103a170 GLP10-01-01-11-057 

b110103s171 GLPlO-01-01-11-058 

bl101033l7 2 GLP'lO-dl-Ol-11-059 

b110103s173 GLPlO-01-01-11-060 

b110103s174 GLPlO-01-01-11-070 

bl10103a175 GLPlO-01-01-11-071 

b110103a176 GLPlO-01-01-11-072 

b110103a177 GLPlO-01-01-11-073 

b110103s178 GLPlO-01-01-11-074 

b110"l033l79 Solvent Blank (MilliQ'Element) 

b1101033l80 Solvent BIsnk (MilliQ Element) 

b l 101033181 08008-194-10 

b l 101033182 Solvent BIsnk (MilliQ Element) 

'b1ldl03al8 3 GLPlO-01-01-11-089 

b1101033l84 GLPlO-01-01-11-090 

b1101033l85 GLPlO-01-01-11-091 

b110103s186 GLP10-01-01-11-092 

b1101033l87 GLPlO-01-01-11-093 

bl10103s188 GLPlO-01-01-11^9 4 

bll0103al8 9 GLPlO-01-01-11-095 

bl10103aT90 GLPIO-01-OT-l 1-096 

b110103s19T GLPlO-01-01-11-097 

"bl Tdld3a'l92 GLPlO-dT-01-1 l"-d98 

b110103a193 Solvent BIsnk (MilliQ Element) 

bTl'01033l94 SoTvefif Blank (MiiiiQ Element) 

b110103s195 08008-194-9 

"bildld3al"96" S"olve'nf Bfank (MilfiQ Efemenf j 

b110103a197'GLPld-01-01-11-109 

b1101033l98 GLP10-01-01-11-110 

b110103aT9"9 GLP'ld-dl-01-11-111 

b l 101033200'GLPIO-OI-OI-l 1-112 

b l 101033201 GLPlO-01-01-11-113 

b11010332'02 GLP10-01-01-11-119 

biidid'3'3203 G'L'pid.oT-oi-ii;i'2d ' 

Ib110103s204 GLPlO-01-01-11-121 

b110103s2d5 GLP10-01-01-11-122 

bl10103s206 GLPlO-01-01-11-123 

b110103s207 Solvent BIsnk (MilliQ Eleme'ntj 

b110103s208 Solvent BIsnk (MilliQ Element) 

b110103a209 08008-194-12 

b110103s210 Solvent BIsnk (MilliQ Element) 

b110103s211 GLPlO-01-01-11-124 

bli0103a21 2 GLPlO-01-01-11-125 

Sampl e Commen t 

DALG W 133S 0 101103 (dil 1:10) 

DALG W 133S DB 101103 (dil 1:10) 

DALG W 133S LS 101103 (dil 1:10) 

DAL G W 133S M S 101103 (dil 1:10) 

DALG W 133S HS 101103 (dil 1:10) 

Milli Q Wster TNIO-0475 

Milli Q Water TNIO-0475 

10 ng/mL FC std in Milli Q Water 

Milli Q Wster TNIO-0475 

DAL G W 133L 0 101103 (dil 1:10) 

DAL GW 133L DB 101103 (dil 1:10) 

DALG W 133LLS 101103 (dil 1:10) 

DAL GW 133L M S 101103 (d'ii 1:10)" 

DAL GW T33L HS 101l"03 (dil 1T1O')" " 

DALG W 134L 0 101105 (dil 1:10) 

DALG W 134LD B 101105 (dil 1:10) 

DALG W 134LLS 101105 (dil 1:10) 

D AL GW 134L M S 101105 (dil 1:10) 

DALG W 134LH S 101105 (dil 1:10) 

Milli Q Wste r TNIO-0475 

Milli Q Wste r TNIO-0475 

5.0 ng/mL FC st d in Milli Q Wster 

Milli Q Water TNIO-0475 

DALG W 136S 0 101103" (dil 1:10) 

DAL G W 136S DB 101103 (dil 1:10) 

DAL G W 136S LS 101103 (dil 1:10)" 

DAL GW 136S M S 101103 (dil 1:10) 

DAL GW 136S HS 101103 (dil 1:10) 

DAL G W 136L d' 101 T03"(diT 1 :"ld) " 

DALG W 136LD B 101103 (dil 1:10) 

DA' L GW 136L LS 10Tld 3 (dfl 1:10) 

DALG W 136LM S 101103 (dil 1:10) 

D AL G"w"l3"6L"HS"l01103"(clil l":10")"" 

Milli Q Water TNIO-0475 

Milli Q Wafer TNIO-0475 

2.5 ng/mL FC std in Milli Q Wster 

Milli Q Wste r TNldJ347"5" 

D AL G W 138S 0 101110 (diri:10 ) 

DAL G W 138S DB 101110 (dil 1:10) 

DALG W 138S LS 101110 (dil 1:10)' 

DALG W 138S M S 101110 (dil 1:10) 

DALG W 138S HS 101110 (diri:10 ) 

DALG W CW26R 0 101110 (dil 1:10) 

DAL G W CW26R'b B l"oil10'(di l iT'lo T 

DAL GW CW26 R LS 101110 (dil 1:10) 

DAL GW CW26 R MS"l011l"0 ('diri:10) 

DAL GW CW26 R HS 101110 (dil 1:10) 

Milli Q Wster TNIO-0475 

Milli Q Wster TNIO-0475 

' 2 5 ng/mL FC std in Milli QWate r " 

Milli Q Wste r TNIO-0475 

DALG W CW26L 0 101110 (dil 1:10) 

'DALGWCW26LD B 101110 (dif 1:10) 

Sampi e Typ e 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Quality Control 

Unknown 

'Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

1 Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Quslity ContnDl 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

'Unknown 

Unknown 

Unknown 

1Onknown 

'Unknown 

1 Unknown 

i Unknown 

Unknown 

1 Quslity Control 

i Unknown 

Unknown 

'unknow n 

Unknown 

Unknown 

1 Unknown 

•Unknown 

Unknown 

j Unknown 

1 Unknown 

]Unknown 

{unknow n 

j Unknown 

iQuality Control 

1 Unknown 

i Unknown 

lUnknown 

~;ff».r:5-

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA" 

PFOA 

PTOA" 

PFOA" 

PFOA 

PFOA 

P'FOA 

PFOA 

PFOA 

'PF"O A 

PFOA 

PFOA 

PFOA . 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

P"FO/\ 

PFOA 

"PFOA 

PFOA 

PTOA" " 

PFOA 

PFOA" 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PTOA" 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

9752747 

9365275 

10066915 

11841620 

26718379 

17266 

12765 

11214481 

11204 

6411795 

6341074 

6706914 

8846255 

25676211 

47049147 

46331948 

46447617 

51001970 

81201588 

' l"474l" 

9988 

5631998 

11314 

9193170 

9536137 

9630649 

10604264 

19117110 

1939709 

1998701 

22'51311 

4337401 

22883027 

9804 

58'3'l 

3097198 

loTsd" 

3853490 

3711370 

4184501 

5859397 

22662086 

9496331 

9644255 

9786135 

"11057441 

27200353 

13718 

7995 

24018723 

8600 

13615881 

13033020 

Analyt e 

Retentio n 

Tim e (mi n 

•14.7 

14.7 

14.7 

14.7 

14.7 

14.8 

14.8 

14.8 

14.8 

14.7 

14.7 

14.7 

14.7 

14.7 

14.8 

14.8 

14.8 

14.8 

14.8 

l'4l8 

14.8 

14.8 

14.8 

14.8 

14.8 

14.8 

14.8 

14.8 

14.7 

14.7 

14l7 

:14.7 

14.7 

14.8 

14.8 

14.8 

14.8 

14.7 

14.7 

'14. 7 

14.7 

14.7 

14.7 

IT4.7 

114.7 

114.7 

;i4. 7 

.14.8 

14.8 

114.7 

14.7 

14.7 

714. 7 

Analyt e 

Concentratio n 

(ng/mL ) 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

9.99 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

5.00 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

'N/A 

2.50 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A" 

N/A 

N/A 

N/A 

N/A 

N/A 

25.0 

N/A 

N/A 

N/A 

Calculate d 

ReSr d concentratio n 

(ng/mL ) 

393. 

377. 

407. 

485. 

1260 

0.00750 

0.00408 

E 9.15 

0.00290 

253. 

250. 

265. 

355. 

1190. 

No Intercept 

No Intercept 

No Intercept 

No Intercept 

No Intercept 

d. 00558 

0.00198 

E ''.42 

0.00298 

73.9 

76.8 

77.6 

,86.1 

166. 

74.1 

76.4 

!86.2 

1169. 

11030. 

1000184 

?° 

E 12.39 

'O.bo'209 

T49. 

1144. 

l"62. 

'23 0 

•1020. 

1382. 

|389. 

1395. 

450. 

1290. 

0.00481 

{0,000467 

' E i21 9 

1 10.000926 

1 1565. 

'539. 

Accurac y 

(%) 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

91.5 

N/A 

N/A 

N/A 

N/A 

N/A 

,N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

88.3 

N/A 

N/A 

N/A 

N/A 

'N/A 

'N/A 

N/A" 

N/A 

":N/ A 

N/A 

N/A 

N/A 

N/A 

,95.5 

jN/A 

[N/A 

IN/A 

!N/A 

JN/A 

JN/A 

IN/A 

IN/A 

N/A 

N/A 

N/A 

|N/A 

]N/A 

;87.7 

iN/A 

N/A 

N/A 

Recor d 

Modifie d 

E 

E 

E 

E 

E 

E 

b 

E 

E 

E 

E 

E 

E 

E 

E 

E 

E 

E 

E 

E 

E 

E 

E 

E 

E 

E 

E 

E 

E 

E 

E 

E 

E 

E 

E 

n 

E 

E 

E 

E 

E 

E 

E 

E 

E 

E 

E 

b 

E 

b 

E 

E 

E 

Dilutio n 

Facto r 

50 

50 

50 

50 

50 

1 

1 

1 

1 

50 

50 

50 

50 

50 

10 

10 

10 

10 

10 

1 

1 

1 

1 

10 

10 

i d " 

10 

10 

50 

50 

50 " 

50 

5 0 " 

1 

1 ^ " 

1 

1 

50 

50 

50 

50 

50 

50 

5 0 " 

50 

50 

50 

1 

1 

1 

1 

50 

50 

Acquisitio n Date 

1/5/2011 6:22:51 PM 

1/5/2011 6:43:59 PM • 

1/5/2011 7:05:01 PM 

1/5/2011 7:26:02 PM 

1/5/2011 7:47:02 PM 

1/5/2011 8:08:07 PM 

1/5/2011 8:29:15 PM 

1/5/20l f 8:50:22 P M , 

1/5/2011 9:'T1:29PM " 

1/5/2011 9:32:37 P M 

1/5/2011 9:53:48 P M "; 

1/5/2011 10:14:53 PM 

•i/5/2011 10:35:55"P'M ", 

1/5/2011 ld:56:57PM"' l 

1/5/2011 11:17:56 PM 

1/5/2011 11:39^00 PM' 

1/6/2011 12:00:11 A M 

1/6/2011 12:21:15'A M " 

1/6/2011 12:42:26 A M 

1/6/20111 :d3":34 AM " ~' 

1/6/2011 1:24:45AM 

l/6/201' l 1:45"55 AM " '1 

1/6/2011 2:07:09 A M 

1/6/2011 2:28:21 AM " 7 

1/6/2011 2:49:35 A M 

1/6/2011 "3"10":42"AM ' " 

1/6/2011 3:31:52 A M | 

1/6/2011 3:53:09 A M ' 

1/6/2011 4:14:T' 5 AM " "; 

1/6/2011 4:35:23 A M 7 

1/6/20"l"l"4:56730 AM""~ 1 

1/6/2011 5:17:34 A M 

1/"67"2dir5"38738AM'"' l 

1/6/2011 5:59:46 A M 

" 1/6/2011 6:2d: 55" A'M ^ 1 

1/6/2011 6:42:02 A M ' 

1/6/20"Tr7":d3:13"AM" " • 

1/6/2011 7:27:54 A M | 

1/6/2011 7:49:07 A M ' 

1/6/20l"T8:l"d:"l2 A M "1 

1/6/2011 8:31:20 A M ' 

1/6/2011 8:52:21 A M j 

1/6/2011 9:13:21 A M 1 

1/6/2011 9;34:23"A"M"" 1 

1/6/2011 9:55:31 A M '] 

1/6/2011 10:16:37 A M [ 

1/6/2011 10:37:37 A M i 

"1/6/2011 I'0:'5'8:43"AM " [ 

1/6/2011 11:19:50A M | 

1/6/2011 11:40:57 A"M '1 

1/6/2011 12:02:04 PM j 

1/6/2011 12:23:16 PM 1 

l/6/2dl 1 12:44:24 PM i 

Data printed by STW 

Printing Time: 1:04:40 PM 

Printing Date: Tuesday, January 16 

Page 4 of 7 

2011 
Buste r J2930203 Batch Name: bllOlOSa.dab 

213 

214 

215 

216 

217 

218 

219 

220 

221 

222 

223 

224 

225 

226 

227 

228 

229 

230 

231 

232 

233 

234 

235 

236 

237 

238 

239 

240 

241 

242 

243 

244 

245 

246 

247 

248 

249 

250 

251 

252 

253 

254 

255 

256 

257 

258 

259 

260 

261 

262 

263 

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265 

'uT^ e sampl e ,D 

b l 101033213 GLPlO-01-01-11-126 

b l 101033214 GLPlO-01-01-11-127 

bll0103a21 5 GLPlO-01-01-11-128 

b110103a216 GLPlO-01-01-11-129 

b l 101033217 GLPlO-01-01-11-130 

b1l0103321 8 GLP10-01-01-11-131 

b110103s219 GLP10-01-01-11-132 

b l 101033220 GLPlO-01-01-11-133 

b110"l~03s"221 Solvent BIsnk (MilliQ Elemen7) 

b110103s222 Solvent BIsnk (MilliQ Element) 

b110l"d3"s223 08008-194-10 

b110103a224 Solvent BIsnk (MilliQ Element) 

b110103a225 GLPlO-01-01-11-134 

b110ld3a22 6 GLP10-01-01-11-135 

b1101033227 GLPlO-01-01-11-136 

b1l0l0'3s22 8 GLPlO-01-01-11-137 

bll0103"3229 GLPlO-01-01-11-138 

blldld'3'a23 0 GLPlO-01-01-11-139 

b l 101033231 GLPlO-01-01-11-140 

b l 101033232 GLPlO-01-01-11-141 

b l 101033233 GLPlO-01-01-11-142 

blTdld3a234'GLPlO-01-01-11--J43 

b l 101033235 Solvent Blank (MilliQ Element) 

b110l'03s23"6 Solvent BIsnk (MilliQ Efemenf) 

b l 101033237 08008-194-11 

b110103a238 Solvent BIsnk (MilliQ E'lement) 

b l 101033239 GLPlO-01-01-11-144 

b110103a240 GLPlO-01-01-11-145 

b110W3a241 GLPlO-01-01-11-146 

b110l03s24 2 GLPlO-01-01-11-147 

b110l"03s243 GLP10-01-01-11-148 

b1l6l03324 4 GLPlO-01-01-11-001 ." 

bll0ld3324 5 GLP10-d"l-dl-11^d2 

bll0103324 6 GLP 10-01-01-11-003 

bll0103s24 7 GLPl0-01-dl-11-0"d4 

bll0103s24 8 GLP10-01-01-11-005 

b l 101033249 Solvent Blank (MilliQ Element) 

b110l"d3s250 Sol\ent Blank (MilliQ Elernent) 

bl10103a25 1 08008-194-12 

b110'l0"3a252 Solvent Blank (MiiiiQ Eiement) 

b110103a253 GLPlO-01-01-11-006 

b1l'0103a254 GLPlO-01-01-11-007 

:b110103a255 GLPlO-01-01-11-008 

'b"l1CilO"3a25"6 GLP 10-01-01-11-009 

b110T03a25"7 GLPlO-01-01-11-010 

b110103'3258 Solvent Blank (MilliQ Elefnent) 

b l 101033259 Solvent Blank (MilliQ Element) 

blldl03326 0 08008-194-10 

bll0103a26 1 Solvent BIsnk (MilliQ Element) 

b110103s262 GLP10-01-01-11.017 

bll0103a26 3 GLP10-01-01-11-018 

b l 101033264 GLPlO-01-01-11-019 

b1ldl03s26 5 GLPlO-01-01-11-020 

Sampl e Commen t 

DAL GW CW26 L LS 101110 (dil 1:10) 

DAL GW CW26 L MS 101110 (dil 1:10) 

DALG W CW26LH S 101110 (dil 1:10) 

DALG W 140R 0 101104 (dil 1:10) 

DAL G W 140R DB 101104 (dil 1:10) 

DALG W 140RLS 101104 (dil 1:10) 

DAL GW 140R MS 10110.4 (dil 1:10) 

DALG W 140R HS 101104 (dil 1:10) 

MiiiiQ Wate r TNIO-0475 

MilliQ Wate r TNIO-0475 

5 0 ng/mL FC std in Milli Q \(Vater 

Milli Q Wste r TN10-0475 

DALG W 141R 0 101110 (dil 1:10) 

DALG W 141RD B 101110 (dil i;10) 

DALG W 141RLS 101110 (dil 1:10) 

DALG W 141RM S 101110 (dil 1:10) 

DALG W 141R HS 101110 (dil 1:10) 

DALG W 142R 0 101110 (dil 1:10) 

DALG W 142RD B 101110 (dil 1:10) 

'DALG W 142RLS 1011ld(di l 1:10) 

DALG W 142RM S 101110 (dil 1:10) 

DALG W 142RH S 101110 (dil 1:10) 

Milli Q Wste r TNIO-0475 

MilliQ Wste r TNIO-0475 

10 ng/mL FC std in Milli Q Wste r 

Milli QWate r TNIO-0475" 

DALG W 144R 0 101110 (dil 1:10) 

DALG W 144RD B 101110 (dil 1:10) 

DAL G W 144R LS lOlll' O (dil 1:10) 

DALG W 144RM S 101110 (dil 1:10) 

DAL G W 144R HS 101110 ("dil 1:10) 

DAL GW 130R 0 101105 (dil 1:100) 

' DAL GW i 30R DB 10"l l"05'(diri: 100) 

DALG W 130RLS 101105 (dil 1:100) 

'i5ALGW'l30RM S 101105 (dil 1:10d) 

DAL GW 130R HS 101105 (dil 1:100) 

Milli Q'WaterTNld"-d4"75 " ' 

Milli Q Wate r TNIO-0475 

25 ng/mL FC std in Milli Q Water 

MilliQ Wate r TNIO-0475. 

ioALG W 130S 0 101105 (dil 1:100) 

DAL G W 130S DB 101105 (dil 1:100) 

DAL G W 130S LS 101105 (dil 1:100) 

DAL G W 130S M S lOll'dS (dil 1:100) 

DALG W 130S HS 101105 (dil 1:100) 

Milli Q Wate r •nMIO-0475 

MilliQ Wate r TNIO-0475 

5.0 ng/mL FC std in Miili Q Water 

Milli Q Wate r TNIO-0475 

DALG W 131R 0 101103 (dil 1:100) 

DALG W 131RD B 101103 (dil 1:100) 

DALG W 131RLS 101103 (dil 1:100) 

DALG W 131RH S 10il03(di l 1:100) 

Sampl e Typ e 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Quality Controf 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Quality Control 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Quality Control 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Quslity Control 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Analyt e 

,PFOA 

PFOA 

PFOA 

PFOA 

PFO A 

PFO A 

PFO A 

IPFOA 

PFO A 

PFO A 

IPFOA 

PFO A 

PFO A 

PFO A 

PFO A 

PFO A 

,PFOA 

PFO A 

PFO A 

iPFO A 

IPFOA 

jPFO A 

PFO A 

>FO A 

i P'FOA 

''PFO A 

PFO A 

PFO A 

'"P'FOA 

iPFOA 

I'PFOA 

IPFOA 

"tpF'OA " 

IPFOA 

iPFO A 

PFO A 

'PFO A 

PFO A 

PFO A 

PFO A 

PFO A 

,PFOA 

[PFOA 

IPFOA 

'PFO A 

PFOA 

PFO A 

"PFO A 

PFO A 

PFO A 

PFO A 

PFO A 

iPFO A 

13332174 

14848827 

30108416 

3137118 

3108042 

3316596 

5534720 

21812703 

18763 

14822 

5339252 

13183 

41825 

36907 

285119 

2488401 

20585221 

1225281 

1281065 

1452800 

3700068 

20923205 

14280 

11186 

10785200 

13250 ' 

1501303 

1505445 

1771974 

3659265 

21671909 

9772347 

985'312d'" 

9964100 

10988265 

19317943 

13033 

8481 

23685649 

9989 

2271794 

2256849 

2388059 

3499246 

13865697 

9285 

8096 

5480015 

11339 

26754828 

26472573 

27140690 

32029721 

Analyt e 

Retentio n 

Tim e (mi n 

14.7 

14.7 

14.7 

14.7 

14.7 

14.7 

14.7 

14.7 

14.7 

14.7 

'14.8 " 

14.7 

14.7 

14.7 

14.7 

14.7 

14.7 

14.7 

14.7 

14.7 

14.7 

'14.7"""" 

14.8 

l"4"."7 ' " 

14.8 

14.8 

14.7 

14.7 

14.7 

14.7 " 

"14.7 

14.8 

14.8 

14.8 

14:8 

14.8 

1478 

14.7 

14.8 

Il4."8" 

.14.8 

14.8 

114.8 

114.8" 

14.8 

14^8" " 

14.8 

14.8 

14.8 

14.8 "" 

14.8 

14.8 

;14.8 

A"aly* « Use 

Concentratio n „ 

, ,„ , V Recor d 

(ng/mL ) 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

5.00 ' E " 

N/A 

" N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A " ' 

N/A 

N/A ' ~ ' 

N/A 

N/A 

9.99 E 

N/A' 

N/A 

N/A 

N/A 

N/A 

" N/A ' • 

N/A 1 

"TT/A " ' ' 

N/A 

"N/A ' " 

N/A 

N/A 

N/A 

25.0 K 

N/A 

N/A 

N/A 

N/A ; 

N/A . ' 

N/A 

N/A 

N/A 

5.00 K 

N/A 

N/A 

N/A 

N/A . 

N/A 

Calculate d 

Concentratio n 

(ng/mL ) 

552. 

623. 

1480. 

121. 

1 2 a 

128. 

217. 

973. 

00086 3 

0.00564 

4,18 

0.00440 

1.31 

1.12 

10.5 

95.5 

908. 

46.5 

48.7 

55:3 " 

143. 

925. 

0.00523 

0700289 

8.77 

0.00445 

57.2 

57.3 

67.6 

142. 

966. 

789. 

796." 

805. 

89"5". " " 

1680. 

'd700429 

0.000836 

21.5 

0.00198 

174. 

173. 

183. 

270. 

1150. 

0.00144 

0.000543 

4.29 

0.00300 

2520. 

2480. 

2570. 

3240." 

Accurac y 

(%) 

|N/A 

N/A 

IN/ A 

N/A 

N/A 

N/A 

N/A 

• N/A 

N/A 

,N/A 

83.6" 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

>/A" 

N/A 

N/A 

N/A 

N/A 

87.8 

N/A 

N/A 

iN/A 

N/A 

N/A 

' NTA 

N/A 

iN/A 

N/A 

'IN/ A 

N/A 

N/A' 

N/A ' 

86.2 

'N/A 

IN/A 

iN/A 

JN/A 

IN/A 

IN/A 

N/A 

N/A 

85.9 " 

N/A 

I'N/A 

'N/A 

IN/A 

jN/A 

Recor d 

Modifie d 

E 

E 

E 

E 

E 

E 

E 

E 

E 

E 

b 

E 

E 

E 

E 

E 

E 

E 

E 

E 

E 

E 

E 

E 

n 

E 

E 

E 

E 

E 

E 

E 

E 

E 

E 

E 

E 

E 

D 

E 

E 

E 

E 

E 

E 

E 

E 

E 

E 

E 

E 

E 

E 

Dilutio n 

Facto r 

50 

50 

50 

50 

50 

50 

50 

I50 

1 

1 

| l 

11 

,50 

150 

50 

50 

50 

50 

50 

50 

50 

150 

'1 

1 

'1 

1 

50 

50 

50 

_^50 

^ 0 

|100 

;"i"d"o 

100 

'10 0 

1100 

'i 

' 1 

11 

'1 

,wo 

llOO 

'100 

1100 

100 

1 

1 

,1 

1 

100 

I100 

100 

ilOO 

Acquisitio n Date 

1/6/2011 1:05:26 P M 

1/6/2011 1:26:29 P M 

1/6/2011 1:47:27 P M 

1/6/2011 2:08:34 P M 

1/6/2011 2:29:38 P M 

1/6/2011 2:50:40 P M 

1/6720li"'3?l'l:47PM 

1/6/2011 3:32:48 P M 

l/6/20ir3T53:5 5 P M 

1/6/2011 4:15:01 P M 

1/6/20ir4:3"6:Tl'P M 

1/6/2011 4:57:21 P M 

1/6/20115:18:29 P M 

1/6/2011 5:39:32 P M 

1/6/2011 6:00:31 P M 

1/6/2011 6:21:37 P M 

1/6/2011 6:42:41 P M 

'l/6"/2dfW:03:4 3 P M 

1/6/2011 7:24:46 P M 

1/6/2011 7:45:50 P M 

1/6/2011 8:06:57 P M 

1/6/2011 8:27:59 P M 

1/6/2011 8:49:04 P M 

l/'6/2dll'97l'0Tl6'PM 

1/6/2011 9:31:24 P M 

' l/6/2'01l'9r5'2734 P M 

1/6/2011 ldl3:4 3 P M 

l/6/2dl l ld:34?52 F=M ' 

I/6/20I 1 l0T55:"52 P M 

1/6/2011 11:16:55 P M 

* T/672dlT7lT37:55"P M 

l76/20l'l'l"l':5"8:"55PM 

1/7/2011 12:20:04 A M | 

1/7/2011 12:41:11 A M 

1/7/2011 1:02:21 A M 

1/7/2011 1:23:27 A M 

T/772dlT"l744r33"AM 

1/7/20l"l 2705:42 A M 

1/7/2011 2:26:49 A M 1 

1/7/2011 274'7r5'7 A' M 

I/7/2OI I 3:09:08 A M j 

1/7/2011 3:301 8 A M i 

1/7/20ir3:5'l:24'A M I 

1/7/2011 4:12:33 A M ' 

1/7/2011 4:33:"46 A M 

1/7/2011 4:'54:51 A M 

1/7/2011 5:16:02 A M 

1/7/2011 5^37:15" A M 

1/7/2011 5:58:26 A M 

1/7/2011 "6:19:37 AM " • 

1/7/2011 6:4d:48 A M \ 

I/7/2OI I 7:01:57 A M j 

11/7/2011 7:23:04 A M ' 

Data printe d by STW 

Printin g Time: 1:04:40 PM 

Printin g Date: Tuesday, January 18, 2011 

Page 5 of 7 
•** Buster J2930203 Batch Name: bll0103a.dab 

266 

267 

268 

269 

270 

271 

272 

273 

274 

275 

276 

277 

278 

279 

280 

281 

282 

283 

284 

285 

286 

•287 

288 

289 

290 

291 

292 

293 

294 

295 

296 

297 

298 

299 

300 

301 

302 

303 

304 

305 

306 

307 

308 

309 

310 

311 

312 

313 

314 

315 

316 

317 

318 

%Z' : sampl e ID 

b l 101033266 Solvent Blank (MilliQ Element) 

b l 101033267 GLPlO-01-01-11-031 

b l 101033268 GLPlO-01-01-11-032 

b110103a269 GLPlO-01-01-11-033 

b l 101033270 GLPlO-01-01-11-034 

b l 101033271 GLPlO-01-01-11-035 

b110103a272 Solvent Blank (MilliQ Element) 

bl10103a273 Solvent BIsnk (MilliQ Element) 

b110103s27"4 08008-194-11 

b110103a275 Solvent Blank (MilliQ Element) 

bl10103a276 GLPlO-01-01-11-036 

b110103s277 GLP10-01-01-11-037 

b l 101033278 "G'LPIO-01-01- 1 1-038 

• bll0103s279 " GLPlO-01-01-11-039" 

b l 101033280 GLP10-01-01-11-040 

b110"l03a281 "Solvent Blank (MilliQ Element) 

b110103s282 Solvent BIsnk (MilliQ Element) 

b110ld33283 08008-194-12 

b l 101033284 Solvent BIsnk (MilliQ Element) 

b l 10l"03s285 "G'CPIO-OIJOI- I 1-061 

b110103s286 GLPlO-01-01-11-062 

b110103"s287 7GLP10-O1-Ol-11-063 

b l 101033288 'GLPIO-OI-OI- I 1-064 

b1ld"l'03s2a9""Solvent BIsnk (MiiiiQ Eleme"nt) 

b110103s29d GLP10-01-01-11-075 

bll"010332¥l'73lP10-01-01-11-d76" 

bl10103s292 GLPlO-01-01-11-077 

b110103s293""G'LP10-01-01-l 1-078 

bl10103s294 Solvent BIsnk (MiiiiQ Element) 

b110103a29'5 Solvent Blank (MilliQ Eiement) 

bll0103a29 6 08008-194-10 

b110103a29"7 Solvent Blank (MilliQ Element) 

b l 101033298 GLPlO-01-01-11-084 

b l 101033299 GLPlO-01-01-11-085 

b l ldl0333"dd""GLPld".Ol"-01-11-086 

b1l0l03s30 1 GLPlO-01-01-11-087 

b110l03s302 GLPlO-01-01-11-088 

b l 101033303,Solvent BIsnk (MiiliQ"Efefne"nt) 

b1101033304 'Solvent Blank (MilliQ Element) 

1 b l 10l0333"d5" 0"8'008-"l'94-11 

ibl10103s3d6 Solvent Blank (MilliQ Eiement) 

b110103b307 GLPlO-01-01-11-044 

b110103b3d8 GLP10-01-01-11-045 

b11010"3b3d9 S'olvent Blank (MilliQ Element) 

b110103b310 GLPlO-01-01-11-070 

"b110103b311 GLPlO-01-01-11-071 " • 

b110103b312 GLPlO-01-01-11-072 

b110103b3l73'GLPlO-01-01-11-073" 

b110103b314 GLPlO-Ol-Ol-l 1-074 

b110103b315' Solvent Blank (MilliQ Element) 

b110103b316 Solvent Blank (MilliQ Element) 

bl10103b317 08008-194-10 

bl10103b318 Solvent Blank (MilliQ Element) 

Sampl e Commen t 

Milli Q Wster TNIO-0475 

DALG W 132R 0 101102 (dil 1:100) 

DALG W 132Rb B 101102 (dil 1:100) 

DALG W 132RLS 101102 (di| 1:100) 

DALG W 132R M S 101102 (dil 1:100) 

DALG W 132RH S 101102 (dil 1:100) 

Milli Q Water fNlO-047 5 

Milli Q Water TNIO-0475 

10 ng/mL FC std in Milli Q Wste r 

Milli Q Water TNIO-0475 

DALG W 132S 0 101102 (dil 1:100) 

DALG W 132S DB 101102 (dil 1:100) 

DAL G W 132S L"S 101102 (dil 1:100) " 

DAL G W 132S M S 101102 (dil 1:ldO) 

DAL G W 132S HS 101102 (dil 1:100) 

Milli Q Water TNIO-0475 

Milli QWate r TNIO-0475 

25 ng/mL FC std in Milli Q Water 

Milli Q Water TNIO-0475 

DAL G W l"34Rd"l01105 (dil 1:100) 

DALG W 134RD B 101105 (dil 1:100) 

DALG W 134RLS 101105 (dil 1:100)' 

DALG W 134RH S 101105 (dil 1:100) 

Milli Q Water"TMl0-047 5 

DALG W 135R 0 101105 (dil 1:100) 

DAL G W 135'R'DB"I"0110 5 (dil 1:100) 

DALG W 135RLS 101105 (dil 1:100) 

DAL G W 135R HS 101105 (dil 1:100) 

Milli Q Water TNIO-0475 

Milli Q Wste r TNIO-0475 

'5.0 ng/mL FC sTd""in Milli QWate r 

Milli Q Water TNIO-0475 

DAL G W l35 L 0"l"Ol10"5 (dil 1:100) 

DALG W 135LD B 101105 (dil 1:100) 

DAL G W 135L L'S 101105 (dil 1:100) 

D AL G W 135L M S 101105 (dil 1:100) ' 

"DAL G W l35 L HS 101105 (dil 1:100)" 

Milli Q Water TN'10^47 5 

Milli QWate r TNIO-0475 

10 ng/mL FC std in Milli Q Wste r 

Milli Q Water TNl0-047 5 

'DALG W 132LM S 101103 (dil 1:10) 

DALG W 132LH S 101103 (dil 1:10) 

Milli Q Water TNIO-0475 

DALG W 134L 0 101105 (dil 1:10) 

DAL G W 134L DB 101105 (dil 1:10) 

DALG W 134LLS 101105 (dil 1:10) 

DAL G W 134LM S 101105 (dil 1:10) 

DALG W 134LH S 101105 (dil 1:10) 

Milli Q Water TNIO-0475 

Milli QWate r TNIO-0475 

5.0 ng/mL FC std in Milli Q Wste r 

Milli Q Wster TNIO-0475 

Sampi e Typ e 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

, Unknown 

Unknown 

Unknown 

Quslity Control 

Unknown 

Unknown 

Unknown 

1 Unknown 

' Unknown 

lUnknown 

• Unknown 

Unknown 

Quslity Control 

Unknown 

Unknown 

Unknown 

I Unknown 

1 Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

LJnknown 

Unknown 

'^Quality Control 

lUnknown 

1 Unknown 

Unknown 

tjnknown 

'Unknown 

Unknown 

Unknown 

lUnknown 

iQuslity Control 

1 Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

Unknown 

'Unknown 

Unknown 

Unknown 

'Quslity Control 

i Unknown 

/-iyt e ^nalyte ^ 

Pea k Nam e ,^„^„,3 , 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA 

PFOA" 

PFOA 

PFQA 

PFOA 

PFOA 

,PFQA " 

PFOA 

PFOA " 

PFOA 

PFOA 

PFOA 

PFOA" 

PFOA 

PFOA 

PFOA 

PFOA " " 

PFOA 

PFOA 

PFQA 

PFOA 

. PFQA 

•PFOA 

TPF'OA " " 

jPFOA 

>FO'A " 

PFOA 

PFOA 

PFOA 

'PFOA" 

PFOA 

PFOA 

PF'O'A^ 

PFO'A 

iPFQA 

PFOA 

PFOA" 

•PFOA 

IPFOA 

IPFOA 

jPFOA 

IPFOA 

*PFOA 

PFO A 

PFOA 

PFOA 

13356 

3319308 

3177175 

3450906 

4570635 

13927051 

12098 

6448 

10070287 

6415 

11710611 

11769462 

11344334 

12342816 

20552908 

5875 

7642 

22967082 

6974 

18853500 

17361970 

18697994 

24492523 

" 9548 

298///2 2 

29605829 

29924930 

35622424 

ll62 8 

8804 

"5316990 

8630 

l62"6310 

1586003 

" 1697090 

2930743 

12977811 

5855 

6572 

10556334 

7918 

11778131 

27276083 

20015 

12686239 

12526431 

12842609 

14340418 

28819223 

43946 

28968 

2887597 

10221 

Analyt e 

Retentio n 

Tim e (mi n 

14.8 

14.7 

14.7 

14.7 

14.7 

14.8 

14.8 

14.8 

14.7 

14.7 

14.7 

14.7 

14.7 

;14.7 

14.7 

14l8 

14.8 

14.7 

14.7 

l'4.7 

14.7 

14.7 

14.7 

14.7 ' 

14.7 

14.7 ' 

14.7 

14.7 

14.7" 

14.7 

11417 

M . 7 

14.7 

14.7 

1477 

14.7 

l4. 7 

'14.7 

14.8 

14.7 

14.8 

14.7 

14.7 

14.8" 

14.7 

14.7 

14.7 

,l4.f 

14.7 

14.7 

14.7 

14.7 

14.7 

Analyt e 

Concentratio n 

(ng/mL ) 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

9.99 

N/A 

N/A 

N/A 

N/A 

Ivl/A 

N/A 

N/A 

N/A 

25.0 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

'N/A 

N/A 

N/A 

N/A 

N/A 

's.od 

N/A 

"N'/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

9.'99 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

N/A 

5.00 

N/A 

„ Calculate d 

_ ^ Concentratio n 

""O^ d (ng/mL ) 

E 

E 

S 

s 

.. K 

0.00453 

256. 

245. 

267. 

356. 

1160. 

0.00358 

'< 0 

8.14 

< 0 

959. 

964. 

926. 

11020. " 

il810. 

•< 0 

'0.00020d 

,20.7 

< 0 

' 164d. 

1490. 

.11620. 

12250. 

0.00164 

2930. 

2890. 

2930. 

3840. 

10.00322 

,00010 8 

14.1"'6'"' 

|d.0'00949 

"il"247 

'121 . 

129. 

!226. 

lofd. "" 

' < 0 

1<0 

[8.57 " 

0.000409 

:482. 

1290. 

10.00958 

523. 

1516. 

'530, 

J599. 

11390. 

0.0277 

'0.0327 

4.44 

'0.00431 

Accurac y 

(%) 

N/A 

N/A 

N/A 

,N/A 

N/A 

N/A 

"•N/A 

N/A 

81.5 

N/A 

" 'N/A 

N/A 

N7A' 

"N/A 

;N/A 

N/A 

N/A 

,82.9 

N/A 

iN/A 

" ,N7A 

'N/A 

N/A 

'N/A 

"tig/A 

N/A 

N/A 

'NIA ' ' 

IN/A 

183.2 

[N/A" 

"tN/ A 

'N/ A 

,N/A 

N/A 

,N/A 

'NTA' " 

N/A 

"85'.'8' 

'iNIA 

' N/A 

N/A 

"N/A " 

N/A 

IN/A ' 

IN/A 

JN/A 

|N/A 

' iN/A 

' N/A 

88.9 

N/A' 

Recor d 

Modifie d 

E 

E 

E 

E 

E 

E 

E 

E 

D 

E 

E 

E 

K 

E 

E 

E 

E 

D 

E 

E 

E 

E 

E 

E 

E 

E 

E 

E 

E 

E 

E 

E 

E 

E 

E 

E 

E 

E 

E 

E 

E 

E 

E 

E 

E 

E 

E 

E 

E 

E 

E 

b 

E 

Dilutio n 

Facto r 

1 

100 

100 

•100 

•100 

IlOO 

•1 

1 

1 

' l 

lod" 

100 

;iod 

pw)" 

iioo 

• f 

'^ 

1 

1 

100 " 

100 

"ti"dd"" 

iioo 

^"-"" 

100 

100 

100 

IlOO 

"11 " • 

1 

" 1 

Ii " 

jlOO 

;100 

^'lidd ^ 

iioo 

' Tid'o" " 

- ^ 1 

' 1 

- n "-

"11 

•50 

^50 

' i 

''5d 

jsd" ' 

150 

"150- -

i1°""-

12 

" !2 " 

12" 

Acquisitio n Date 

1/7/2011 7:44:14 A M 

1/7/2011 8:05:19 A M 

1/7/2011 8:26:32 A M 

1/7/2011 8:47:44 A M 

1/7/2011 9:08:53 A M , 

1/7/2011 9:300 2 A M 

1/7/2011 9:51:l3"/\M 

1/7/2011 10:17? ? A M 

1/7/2011 1033731 A M 

1/7/2011 10:54:39 A M 

1/7/2011 11:15:"50"7^M 

1/7/2011 11:36:57 A M 

1/7/2011 11:58:d4"AM , 

1/7/2011 12:19:l5'P M 

1/7/2011 12:40:23 PM ] 

1/7/2011 1:01:36 PM ' 

1/7/2011 1:22:47 PM 

1/7/2011 1:43:56'P'M 

1/7/2011 2:05:02 P U 

1/7/2011 2:26:l7rpiui" " i 

1/7/2011 2:47:30 P M , 

1/7/2011 3:da'38'PM' "" 

1/7/2011 3:29:44 PM 

1/7/2011 3:50!56?'"i^" 

1/7/2011 4:12:04 P M 

1/7/2011 4:33711"TM 

1/7/2011 4:54:21 P M 

1/7/2011 5:15:29 PM ' 

1/7/2011 5:36:33 Pfvl ' 

1/7/2011 5:57:43 PM 

"l/"7/2'0"il 6:i8748"p'ivr " ; 

" 1/7/2011 6:4d:03"PM | 

1/7/2011 7:01:15 PM | 

1/7/2011 7:22:30 PM ; 

1/7/2011 7:43:38 P M 

1/7/2011 8:04:51 P M 

""l7'7720ll 8:25:55 P M 1 

1/7/2011 8^47:03"P" M 1 

1/7/2011 9:08:15 P M 

1/7/2dll"9:29;y3"p"ivi" " 1 

'1/7/2011 9:50:28 PM | 

1/7/2011 10:20:37 PM 1 

1/7/2011 10:41:44 P M 

1/7/20lill:02:4"3"p"M " • 

1/7/2dl1 11:23:45"PM 

1/772011 11:44:50 Pful 

1/8/2011 12:05:53 A M | 

1/8/2011 12:26:58 A M j 

1/8/2011 12:48:01 A M 

1/8/2011 1:"09:0"6"Aivl 

1/8/2011 1:30:12 A M ' 

1/8/2011 1:51:18 A M 

1/8/2011 2:12:26 A M " , 

Data printed by STW 

Printing Time: 1:04:40 PM 

Printing Date: Tuesday, January IE 

Page 6 of 7 
Buster J2930203 Batch Name: bllOlOSa.dab 

Sampie 

Name Sampie ID 

319 

320 

321 

322 

323 

b110103b319 GLPlO-01-01-11-134 

bl10103b320 GLP10-01-01-11-135 

,b110103b321 GLPlO-01-01-11-136 

.bl10103b322 Solvent BIsnk (MilliQ Element) 

b110103b323 08008-194-9 

Sample Comment 

DALGW 141R0 101110 (dil 1:10) 

DALGW 141RDB 101110 (dil 1:10) 

DAL GW 141R LS 101110 (dil 1:10) 

MilliQ Water TNIO-0475 

2.5 ng/mL FC std in Milli Q Water 

Sample 

Unknown 

Unknown 

Unknown 

Unknown 

Type 

Quality Control 

, _^ Analyte 

Analyte p^g^ i^ea 

Peak Name ,^^^^,3, 

PFOA 

PFOA 

PFOA 

'PFQA 

PFOA 

288285 

211534 

1492482 

15732 

1561815 

Analyte 

Retention 

Time (min 

14.7 

14.7 

14.7 

14.7 

14.7 

Analyte 

Concentration 

(ng/mL) 

N/A 

N/A 

N/A 

N/A 

2.50 

Use 

Record 

E 

Calculated 

Concentration 

(ng/mL) 

2.13 

1.55 

11.4 

00127 

2.38 

Accuracy 

(%) 

N/A 

N/A 

N/A 

'N/A 

:95.2 

Record 

Modified 

E 

E 

E 

E 

E 

Dilution 

Factor 

;10 1 

10 1 

10 1 

2 1 

2 1 

Acquisition Date 

1/8/2011 2:33:30 AM 

1/8/2011 2:54:36 AM 

1/8/2011 3:15:40 AM 

1/8/2011 3:36:46 AM 

1/8/2011 3:57:53 AM 

Data printed by STW 

Printing Time: 1:04:40 PM 

Printing Date: Tuesday, January 18, 2011 

Page 7 of 7 
** Buster J2930203 3atch Name: bll0103a.dab 

• bl 10103a.rdb (PFOA): "Quadratic" Regression ("1 / x" weighting): y = -1.02e+004 x'^2 + 1.32e+006 x + 7.38e+003 (r = 0.9996) 

6.2e7 ] 

6.0e7-

5.5e7-

5.0e7-

4.5e7-

4.0e7-

3.5e7-

"c 

Z! 

8 3.0e7-

co" 

CD 

< 

2.5e7-

2.0e7-

1.5e7-

1.0e7-

5.0e6-

0.0-

^•- ^ 

^ 

,/ 

/ 

/ / 

/ 

/ 

> 

/ 

0 5 10 15 20 25 30 35 40 45 50 55 60 65 70 

Concentration, ng/mL 

O 

—^. ^ 

75 

^ ^ 

80 85 

" ^ \ 

90 

• \ 

95 

O 

100 

Data printed by STW 

Printing Time: 1:04:52 PM 

Printing Date: Tuesday, January 18, 2011 

Page 1 of 1 

\V'fe\vv5 ^