## Material Safety Data Sheet



## Genetron® 32

Version 2 Revision Date 12/15/2009 Print Date 03/28/2014

Page 1 / 11 SECTION 1. PRODUCT AND COMPANY IDENTIFICATION

Product name : Genetron® 32

MSDS Number : 000000009907 Product Use Description : Refrigerant

Company : Honeywell International, Inc.

101 Columbia Road
Morristown, NJ 07962-1057

For more information call : 800-522-8001 (Monday-Friday, 9:00am-5:00pm)

In case of emergency call : Medical: 1-800-498-5701

: Transportation: 1-800-424-9300 or +1-703-527-3887 : (24 hours/day, 7 days/week)

SECTION 2. HAZARDS IDENTIFICATION

Emergency Overview

Form : Liquefied gas

Color : colourless

Odor : slight sweet ether-like

Hazard Summary : Warning! Container under pressure. Flammable. Gas reduces oxygen available for breathing. Causes asphyxiation in high

concentrations. The victim w ill not realize that he/she is suffocating. Inhalation may cause central nervous system effects. May cause cardiac arrhythmia. May cause drowsiness and dizziness. Do not breathe vapour. Irritating to eyes and

skin. Avoid contact with skin , eyes and clothing. At higher temperatures, (>250 C), decomposition products may include hydrofluoric acid (HF) and carbonyl halides. The ACGIHThreshold Limit Values (2007) for Hydrogen Fluoride are TLVTWA 0.5 ppm and Ceiling Exposure Limit 2 ppm.

Potential Health Effects

Skin : Avoid skin contact with leaking liquid (danger of frostbite). May cause frostbite. Irritating to skin.

Eyes : Causes serious eye irritation.

## Material Safety Data Sheet



## Genetron® 32

Version 2 Revision Date 12/15/2009 Print Date 03/28/2014

Page 2 / 11 May cause frostbite.

Ingestion : Unlikely route of exposure. Effects due to ingestion may include:

Gastrointestinal discomfort

Inhalation : Gas reduces oxygen available for breathing. Causes asphyxiation in high co ncentrations. The victim will not realize that he/she is suffocating. Inhalation may cause central nervous system effects. May cause cardiac arrhythmia. Vapours may cause drowsiness and dizziness.

Chronic Exposure : None known.

Carcinogenicity

No component of this product presen t at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP, IARC, or OSHA.

SECTION 3. COMPOSITION/IN FORMATION ON INGREDIENTS

Component CAS-No. Weight percent

Difluoromethane 75-10-5 100.00

SECTION 4. FIRST AID MEASURES

Inhalation : Move to fresh air. If breathing is irregular or stopped, administer artificial respirat ion. Use oxygen as required, provided a qualified operator is present. Call a physician. Do not give drugs from adrenaline-ephedrine group.

Skin contact : After contact with skin, wash immediately with plenty of water. If there is evidence of frostbite, bathe (do not rub) with lukewarm (not hot) water. If water is not available, cover with a clean, soft cloth or similar covering. If symptoms persist, call a physician.

Eye contact : Remove contact lenses . Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.

Ingestion : Unlikely route of exposure. As this product is a gas, refer to the inhalation section. Do not induce vomiting without medical advice. Call a physician immediately.

## Material Safety Data Sheet



## Genetron® 32

Version 2 Revision Date 12/15/2009 Print Date 03/28/2014

Page 3 / 11 Notes to physician

Treatment : Because of the possible disturbances of cardiac rhythm, catecholamine drugs, such as epinephrine, should be used with special caution and only in situations of emergency life support. Treatment of overexposure should be directed at thecontrol of symptoms and the clinical conditions. Treat frostbitten areas as needed.

Treatment : Do not give adrenaline or similar drugs.

SECTION 5. FIRE-FIGHTING MEASURES

Flash point : not applicable

Ignition temperature : >750 °C (1,382 °F)

Lower explosion limit : 14.4 %(V)

Upper explosion limit : 33.4 %(V)

Suitable extinguishing

media : Use water spray, alcohol-resistant foam, dry chemical or

carbon dioxide. Use extinguishing measures that are appropriate to local

circumstances and the surrounding environment.

Specific hazards during fire fighting : Contents under pressure.

Flammable. Flash back possible over considerable distance. Container may rupture on heating. Cool closed containers exposed to fire with water spray. Do not allow run-off from fire fighting to enter drains or water

courses. Vapours are heavier than air and can cause suffocation by reducing oxygen available for breathing. Rapid evaporation of the liquid may cause frostbite. In case of fire hazardous decomposition products may be produced such as: Hydrogen fluoride

Carbon monoxide Carbon dioxide (CO2) Carbonyl halides

Special protective equipment for fire-fighters : In the event of fire and/or explosion do not breathe fumes. Wear self-contained breathing apparatus and protective suit. No unprotected exposed skin areas.

## Material Safety Data Sheet



## Genetron® 32

Version 2 Revision Date 12/15/2009 Print Date 03/28/2014

Page 4 / 11 SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions : Immediately evacuate personnel to safe areas. Keep people away from and upwind of spill/leak. Wear personal protective equipment. Unprotected persons must be kept away. Remove all sources of ignition. Avoid skin contact with leaking liquid (danger of frostbite).

Ventilate the area. After release, disperses into the air. Vapours are heavier than air and can cause suffocation by reducing oxygen available for breathing. Avoid accumulation of vapours in low areas. Unprotected personnel should not return until air has been

tested and determined safe. Ensure that the oxygen content is >= 19.5%.

Environmental precautions : Prevent further leakage or spillage if safe to do so. The product evaporates readily.

Methods for cleaning up : Ventilate the area.

SECTION 7. HANDLING AND STORAGE

Handling

Handling : Handle with care. Avoid inhalation of vapour or mist. Do not get in eyes, on skin, or on clothing. Wear personal protective equipment. Use only in well-ventilated areas.

Pressurized container. Protect from sunlight and do not expose to temperatures exceeding 50 °C. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Follow all standard safety precautions for handling and use of compressed gas cylinders. Protect cylinders from physical damage. Do not puncture or drop cylinders, expose them to open flame

or excessive heat. Do not pierce or burn, even after use. Do not spray on a naked flame or any incandescent material. Do not remove screw cap until immediately ready for use. Always replace cap after use.

Handling : Open drum carefully as content may be under pressure. The product should only be used in areas from which all naked lights and other sources of ignition have been excluded.

## Material Safety Data Sheet



## Genetron® 32

Version 2 Revision Date 12/15/2009 Print Date 03/28/2014

Page 5 / 11 Pressurized container. Protect from sunlight and do not expose to temperatures exceeding 50 °C. Do not pierce or burn, even after use. Do not spray on a naked flame or any incandescent material. Do not use in areas without adequate ventilation. Contaminated equipment (brushes, rags) must be cleaned immediately with water.

Advice on protection against fire and explosion : Vapours may form explosive mixture with air. Container hazardous when empty. Keep product and empty cont ainer away from heat and sources of ignition. The heavy vapours can overcome a considerable distance up to the source of ignition. Take measures to prevent the build up of electrostatic charge. Electrical equipment should be protected to the appropriate

standard.

Storage

Requirements for storage

areas and containers : Keep containers tightly closed in a dry, cool and well-ventilated place.

Pressurized container: Protect from sunlight and do not expose to temperatures exceeding 50 °C. Do not pierce or burn, even

after use. Keep away from heat and sources of ignition. Protect cylinders from physical damage. Store away from incompatible substances. Storage rooms must be properly ventilated. Ensure adequate ventilation, especially in confined areas.

Further information on storage conditions : Store in original container. Keep containers tightly closed in a cool, well-ventilated place. Keep away from direct sunlight.

SECTION 8. EXPOSURE CONT ROLS/PERSONAL PROTECTION

Protective measures : Do not breathe vapour. Avoid contact with skin, eyes and clothing. Ensure that eyewash stations and safety showers are close to

the workstation location.

Engineering measures : General room vent ilation is adequate for storage and handling. Perform filling operations only at stations with exhaust

ventilation facilities.

## Material Safety Data Sheet



## Genetron® 32

Version 2 Revision Date 12/15/2009 Print Date 03/28/2014

Page 6 / 11 Eye protection : Do not wear contact lenses. Wear as appropriate: Safety glasses with side-shields If splashes are likely to occur, wear: Goggles or face shield, giving complete protection to eyes

Hand protection : Leather gloves In case of contact through splashing: Protective gloves Neoprene gloves Polyvinyl alcohol or nitrile- butyl-rubber gloves

Skin and body protection : Avoid skin contact with leaking liquid (danger of frostbite). Wear cold insulating gloves/face shield/eye protection.

Respiratory protection : In case of insu fficient ventilation wear suitable respiratory equipment. Wear a positive-pressure supplied-air respirator. Vapours are heavier than air and can cause suffocation by reducing oxygen available for breathing.For rescue and maintenance work in storage tanks use selfcontained breathing apparatus.

Hygiene measures : Handle in accordance with good industrial hygiene and safety practice. Ensure adequate ventilation, especially in confined areas. Avoid contact with skin, eyes and clothing. Remove and wash contaminated clothing before re-use. Keep working clothes separately.

Exposure Guidelines

Difluoromethane 75-10-5 WEEL TWA 1,000 ppm 2,200 mg/m3

TX ESL ST ESL 10600 ug/m3

HONEYWELL TWA 1,000 ppm

TX ESL AN ESL 1060 ug/m3

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Form : Liquefied gas

Color : colourless

Odor : slight sweet ether-like

## Material Safety Data Sheet



## Genetron® 32

Version 2 Revision Date 12/15/2009 Print Date 03/28/2014

Page 7 / 11 Molecular Weight : 52 g/mol

pH : neutral

Freezing point : -136 °C (-213 °F)

Boiling point/boiling range : -51.7 °C (-61.1 °F)

Vapor pressure : 15,189 hPa at 21.1 °C (70.0 °F)

Vapor pressure : 34,804 hPa at 54.4 °C (129.9 °F)

Relative vapour density : 1.8 (Air = 1.0)

Density : 1.002 g/cm3 at 26.7 °C (80.1 °F) Water solubility : insoluble

Partition coefficient: noctanol/water : log Pow : 0.21

SECTION 10. STABILITY AND REACTIVITY

Conditions to avoid : Protect from heat/overheating. Decomposes under high temperature. Contains gas under pressure; may explode if heated. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep away from direct sunlight. Some risk may be expected of corrosive and toxic decomposition products.

Materials to avoid : Finely divided aluminium

Potassium

Calcium

Powdered metals

Aluminium Magnesium

Zinc

Hazardous decomposition products : Halogenated compounds Hydrogen fluoride Carbonyl halides

Carbon oxides

## Material Safety Data Sheet



## Genetron® 32

Version 2 Revision Date 12/15/2009 Print Date 03/28/2014

Page 8 / 11 Thermal decomposition : >250 °C To avoid thermal decompo sition, do not overheat.

Hazardous reactions : Hazardous polymerisation does not occur.

Stable under normal conditions.

SECTION 11. TOXICOLOGICAL INFORMATION

Acute inhalation toxicity : LC50 rat

Dose : > 520000 ppm Exposure time: 4 h

Sensitisation : Cardiac sensitization dogs

No-observed-effect level >350,000 ppm

Repeated dose toxicity : Inhalation rat Subchronic toxicity NOEL: 50,000 ppm

Genotoxicity in vitro : Ames test negative

Genotoxicity in vitro : Human lymphocytes negative Mutagenicity (in vitro mammalian cytogenetic test)

Genotoxicity in vitro : Chromosome aberration test in vitro negative

Genotoxicity in vivo : Species: mouse Cell type: Bone marrow Mutagenicity (micronucleus test) negative

Teratogenicity : rat NOEL - 50,000 ppm

Teratogenicity : rabbit NOEL - 50,000 ppm

SECTION 12. ECOLOGICAL INFORMATION

Biodegradability : Minimal

## Material Safety Data Sheet



## Genetron® 32

Version 2 Revision Date 12/15/2009 Print Date 03/28/2014

Page 9 / 11 Additional ecological

information : This product is subject to U.S. Environmental Protection Agency Clean Air Act Regulations at 40 CFR Part 82. This product contains greenhouse gases which may contribute to global warming. Do NOT vent to the atmosphere. To comply with provisions of the U.S. Clean Air Act, any residual must be

recovered.

SECTION 13. DISPOSAL CONSIDERATIONS

Waste Information: Observe all Federal, State, and Local Environmental regulations. Additional advice : This product is subject to U.S. Environmental Protection Agency Clean Air Act Regulations Section 608 in 40 CFR Part 82 regarding refrigerant recycling.

SECTION 14. TRANSPORT INFORMATION

DOT UN-Number : 3252 Proper shipping name : DIFLUOROMETHANE

Class 2.1 Packing group

Hazard Labels 2.1

IATA UN Number : 3252 Description of the goods : DIFLUOROMETHANE

Class : 2.1

Hazard Labels : 2.1 Packing instruction (cargo aircraft) : 200

IMDG Substance No. : UN 3252 Description of the goods : DIFLUOROMETHANE

Class : 2.1

Hazard Labels : 2.1

EmS Number : F-D Marine pollutant : no

SECTION 15. REGULATORY INFORMATION

Inventories

1907/2006 (EU) : This mixture contains only ingredients which have been subject to a pre-registration according to Regulation (EC) No. 1907/2006 (REACH). US. Toxic Substances : On TSCA Inventory

## Material Safety Data Sheet



## Genetron® 32

Version 2 Revision Date 12/15/2009 Print Date 03/28/2014

Page 10 / 11 Control Act

Australia. Industrial Chemical (Notification and Assessment) Act : On the inventory, or in compliance with the inventory

Canada. Canadian

Environmental Protection Act (CEPA). Domestic Substances List (DSL). (Can. Gaz. Part II, Vol. 133) : All components of this product are on the Canadian DSL list.

Japan. Kashin-Hou Law

List : On the inventory, or in compliance with the inventory

Korea. Toxic Chemical Control Law (TCCL) List : On the inventory, or in compliance with the inventory

Philippines. The Toxic

Substances and Hazardous

and Nuclear Waste Control

Act : On the inventory, or in compliance with the inventory

China. Inventory of Existing

Chemical Substances : On the inventory, or in compliance with the inventory

New Zealand. Inventory of Chemicals (NZIoC), as published by ERMA New

Zealand : On the inventory, or in compliance with the inventory

National regulatory information

SARA 311/312 Hazards : Fire Hazard

Acute Health Hazard

Sudden Release of Pressure Hazard

California Prop. 65 : WARNING! This product contains a chemical known in the

State of California to cause cancer.

Dichloromethane 75-09-2

## Material Safety Data Sheet



## Genetron® 32

Version 2 Revision Date 12/15/2009 Print Date 03/28/2014

Page 11 / 11 : WARNING! This product contains a chemical known in the

State of California to cause birt h defects or other reproductive

harm.

Chloromethane 74-87-3

Massachusetts RTK : Dichloromethane 75-09-2

New Jersey RTK : Difluoromethane 75-10-5

Pennsylvania RTK : Difluoromethane 75-10-5

WHMIS Classification : A This product has been classified according to the hazard criteria

of the CPR and the MSDS contains all of the information required by the CPR.

Global warming potential : 550

SECTION 16. OTHER INFORMATION

HMIS III NFPA

Health hazard : 1 2 Flammability : 4 4 Physical Hazard : 0 Instability : 0

## Material Safety Data Sheet



## Genetron® 125

Version 2 Revision Date 12/15/2009 Print Date 03/28/2014

Page 1 / 10 SECTION 1. PRODUCT AND COMPANY IDENTIFICATION

Product name : Genetron® 125

MSDS Number : 000000009884 Product Use Description : Refrigerant

Company : Honeywell International, Inc.

101 Columbia Road
Morristown, NJ 07962-1057

For more information call : 800-522-8001 (Monday-Friday, 9:00am-5:00pm)

In case of emergency call : Medical: 1-800-498-5701

: Transportation: 1-800-424-9300 or +1-703-527-3887 : (24 hours/day, 7 days/week)

SECTION 2. HAZARDS IDENTIFICATION

Emergency Overview

Form : Liquefied gas

Color : colourless

Odor : slight

Hazard Summary : Warning! Container under pressure. This product is not flammable at ambient temperatures and atmospheric pressure. Gas reduces oxygen available for breathing. Causes asphyxiation in high co ncentrations. The victim will not realize that he/she is suffocating. Inhalation may cause central nervous system effects. May cause cardiac arrhythmia. May cause drowsiness and dizziness. Do not breathe vapour. Irritating to eyes and skin. Avoid contact with skin, eyes and clothing. At higher temperatures, (>250 C), decomposition products may include hydrofluoric acid (HF) and carbonyl halides. The ACGIH Threshold Limit Values (2007) for Hydrogen Fluoride are TLV-TWA 0.5 ppm and Ceiling Exposure Limit 2 ppm.

Potential Health Effects

Skin : Avoid skin contact with leaking liquid (danger of frostbite). May cause frostbite. Irritating to skin.

## Material Safety Data Sheet



## Genetron® 125

Version 2 Revision Date 12/15/2009 Print Date 03/28/2014

Page 2 / 10 Eyes : Causes serious eye irritation. May cause frostbite.

Ingestion : Unlikely route of exposure. Effects due to ingestion may include:

Gastrointestinal discomfort

Inhalation : Gas reduces oxygen available for breathing. Causes asphyxiation in high co ncentrations. The victim will not realize that he/she is suffocating. Inhalation may cause central nervous system effects. May cause cardiac arrhythmia. Vapours may cause drowsiness and dizziness.

Chronic Exposure : None known.

Carcinogenicity

No component of this product presen t at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP, IARC, or OSHA.

SECTION 3. COMPOSITION/IN FORMATION ON INGREDIENTS

Component CAS-No. Weight percent

Pentafluoroethane 354-33-6 100.00

SECTION 4. FIRST AID MEASURES

Inhalation : Move to fresh air. If breathing is irregular or stopped, administer artificial respirat ion. Use oxygen as required, provided a qualified operator is present. Call a physician. Do not give drugs from adrenaline-ephedrine group.

Skin contact : After contact with skin, wash immediately with plenty of water. If there is evidence of frostbite, bathe (do not rub) with lukewarm (not hot) water. If water is not available, cover with a clean, soft cloth or similar covering. If symptoms persist, call a physician.

Eye contact : Rinse immediately with plen ty of water, also under the eyelids,

for at least 15 minutes. In case of frostbite water should be lukewarm, not hot. If symptoms persist, call a physician.

Ingestion : Unlikely route of exposure. As this product is a gas, refer to the inhalation section. Do not induce vomiting without medical

## Material Safety Data Sheet



## Genetron® 125

Version 2 Revision Date 12/15/2009 Print Date 03/28/2014

Page 3 / 10 advice. Call a physician immediately.

Notes to physician

Treatment : Because of the possible disturbances of cardiac rhythm, catecholamine drugs, such as epinephrine, should be used with special caution and only in situations of emergency life support. Treatment of overexposure should be directed at thecontrol of symptoms and the clinical conditions. Treat frostbitten areas as needed.

SECTION 5. FIRE-FIGHTING MEASURES

Flash point : not applicable

Ignition temperature : >750 °C (1,382 °F)

Lower explosion limit : None

Upper explosion limit : None

Suitable extinguishing

media : The product is not flammable.

ASHRAE 34 Use water spray, alcohol-resistant foam, dry chemical or

carbon dioxide. Use extinguishing measures that are appropriate to local

circumstances and the surrounding environment.

Specific hazards during fire fighting : Contents under pressure. This product is not flammable at ambient temperatures and atmospheric pressure. However, this material can ignite when mixed with air under pressure and exposed to strong ignition sources. Container may rupture on heating. Cool closed containers exposed to fire with water spray. Do not allow run-off from fire fighting to enter drains or water

courses. Vapours are heavier than air and can cause suffocation by reducing oxygen available for breathing. In case of fire hazardous decomposition products may be produced such as: Hydrogen halides Hydrogen fluoride

Carbon monoxide Carbon dioxide (CO2) Carbonyl halides

## Material Safety Data Sheet



## Genetron® 125

Version 2 Revision Date 12/15/2009 Print Date 03/28/2014

Page 4 / 10 Special protective equipment for fire-fighters : In the event of fire and/or explosion do not breathe fumes. Wear self-contained breathing apparatus and protective suit. No unprotected exposed skin areas.

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions : Immediately evacuate personnel to safe areas. Keep people away from and upwind of spill/leak. Wear personal protective equipment. Unprotected persons must be kept away. Remove all sources of ignition. Avoid skin contact with leaking liquid (danger of frostbite).

Ventilate the area. After release, disperses into the air. Vapours are heavier than air and can cause suffocation by reducing oxygen available for breathing. Avoid accumulation of vapours in low areas. Unprotected personnel should not return until air has been

tested and determined safe. Ensure that the oxygen content is >= 19.5%.

Environmental precautions : Prevent further leakage or spillage if safe to do so. The product evaporates readily.

Methods for cleaning up : Ventilate the area.

SECTION 7. HANDLING AND STORAGE

Handling

Handling : Handle with care. Avoid inhalation of vapour or mist. Do not get in eyes, on skin, or on clothing. Wear personal protective equipment. Use only in well-ventilated areas.

Pressurized container. Protect from sunlight and do not expose to temperatures exceeding 50 °C. Follow all standard safety precautions for handling and use of compressed gas cylinders. Use authorized cylinders only. Protect cylinders from physical damage. Do not puncture or drop cylinders, expose them to open flame

or excessive heat. Do not pierce or burn, even after use. Do not spray on a naked flame or any incandescent material. Do not remove screw cap until immediately ready for use. Always replace cap after use.

## Material Safety Data Sheet



## Genetron® 125

Version 2 Revision Date 12/15/2009 Print Date 03/28/2014

Page 5 / 10 Advice on protection against fire and explosion : The product is not flammable. Can form a combustible mixture with air at pressures above atmospheric pressure.

Storage

Requirements for storage

areas and containers : Pressurized container: Protec t from sunlight and do not expose to temperatures exceeding 50 °C. Do not pierce or burn, even

after use. Keep containers tightly closed in a dry, cool and well-ventilated place. Storage rooms must be properly ventilated. Ensure adequate ventilation, especially in confined areas. Protect cylinders from physical damage.

SECTION 8. EXPOSURE CONT ROLS/PERSONAL PROTECTION

Protective measures : Do not breathe vapour. Avoid contact with skin, eyes and clothing. Ensure that eyewash stations and safety showers are close to

the workstation location.

Engineering measures : General room vent ilation is adequate for storage and handling. Perform filling operations only at stations with exhaust

ventilation facilities.

Eye protection : Wear as appropriate: Safety glasses with side-shields If splashes are likely to occur, wear: Goggles or face shield, giving complete protection to eyes

Hand protection : Leather gloves In case of contact through splashing: Protective gloves Neoprene gloves Polyvinyl alcohol or nitrile- butyl-rubber gloves

Skin and body protection : Avoid skin contact with leaking liquid (danger of frostbite). Wear cold insulating gloves/face shield/eye protection.

Respiratory protection : In case of insuffi cient ventilation, wear suitable respiratory equipment. Wear a positive-pressure supplied-air respirator. Vapours are heavier than air and can cause suffocation by reducing oxygen available for breathing.For rescue and maintenance work in storage tanks use selfcontained breathing apparatus.

## Material Safety Data Sheet



## Genetron® 125

Version 2 Revision Date 12/15/2009 Print Date 03/28/2014

Page 6 / 10 Hygiene measures : Handle in accordance with good industrial hygiene and safety practice. Ensure adequate ventilation, especially in confined areas. Avoid contact with skin, eyes and clothing. Remove and wash contaminated clothing before re-use. Keep working clothes separately.

Exposure Guidelines

Pentafluoroethane 354-33-6 WEEL TWA 1,000 ppm 4,900 mg/m3

HONEYWELL TWA 1,000 ppm

TX ESL AN ESL 2450 ug/m3

TX ESL ST ESL 24500 ug/m3

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Form : Liquefied gas

Color : colourless

Odor : slight

Molecular Weight : 120.03 g/mol

Melting point/range : -103 °C (-153 °F)

Boiling point/boiling range : -48.5 °C (-55.3 °F)

Vapor pressure : 12,438 hPa at 21.1 °C (70.0 °F)

Vapor pressure : 28,110 hPa at 54.4 °C (129.9 °F)

Relative vapour density : 4.2 (Air = 1.0)

Density : 1.21 g/cm3 at 21.1 °C (70.0 °F) Water solubility : 0.9 g/l

Partition coefficient: noctanol/water : log Pow : 1.48

## Material Safety Data Sheet



## Genetron® 125

Version 2 Revision Date 12/15/2009 Print Date 03/28/2014

Page 7 / 10 The product is more soluble in octanol.

SECTION 10. STABILITY AND REACTIVITY

Conditions to avoid : Pressurized cont ainer. Protect from sunlight and do not expose to temperatures exceeding 50 °C. Decomposes under high temperature. Some risk may be expected of corrosive and toxic decomposition products. Can form a combustible mixture with air at pressures above atmospheric pressure. Do not mix with oxygen or air above atmospheric pressure.

Materials to avoid : Finely divided aluminium

Potassium

Calcium

Powdered metals

Aluminium Magnesium

Zinc

Hazardous decomposition products : In case of fire hazardous decomposition products may be produced such as: Halogenated compounds Hydrogen fluoride Carbonyl halides

Carbon monoxide Carbon dioxide (CO2)

Thermal decomposition : >250 °C To avoid thermal decompo sition, do not overheat.

Hazardous reactions : Hazardous polymerisation does not occur.

Stable under normal conditions.

SECTION 11. TOXICOLOGICAL INFORMATION

Acute inhalation toxicity : rat

Dose : > 769000 ppm Exposure time: 4 h

Sensitisation : Cardiac sensitization dogs

No-observed-effect level 75,000 ppm

Lowest observable effect level 100,000 ppm

## Material Safety Data Sheet



## Genetron® 125

Version 2 Revision Date 12/15/2009 Print Date 03/28/2014

Page 8 / 10 Repeated dose toxicity : Inhalation rat Subchronic toxicity NOEL: >= 50000 ppm

Genotoxicity in vitro : In vitro tests did not show mutagenic effects

Additional advice : Vapours are heavier than air and can cause suffocation by reducing oxygen available for breathing. Irritating to eyes and skin. Rapid evaporation of the liquid may cause frostbite. Avoid skin contact with leaking liquid (danger of frostbite). May cause cardiac arrhythmia.

SECTION 12. ECOLOGICAL INFORMATION

Additional ecological

information : Accumulation in aquatic organisms is unlikely. This product contains greenhouse gases which may contribute to global warming. Do NOT vent to the atmosphere. To comply with provisions of the U.S. Clean Air Act, any residual must be

recovered.

SECTION 13. DISPOSAL CONSIDERATIONS

Waste Information: Observe all Federal, State, and Local Environmental regulations. Additional advice : This product is subject to U.S. Environmental Protection Agency Clean Air Act Regulations Section 608 in 40 CFR Part 82 regarding refrigerant recycling.

SECTION 14. TRANSPORT INFORMATION

DOT UN-Number : 3220 Proper shipping name : PENTAFLUOROETHANE

Class 2.2 Packing group

Hazard Labels 2.2

IATA UN Number : 3220 Description of the goods : PENTAFLUOROETHANE

Class : 2.2

Hazard Labels : 2.2 Packing instruction (cargo aircraft) : 200

## Material Safety Data Sheet



## Genetron® 125

Version 2 Revision Date 12/15/2009 Print Date 03/28/2014

Page 9 / 10 Packing instruction (passenger aircraft) : 200

IMDG Substance No. : UN 3220 Description of the goods : PENTAFLUOROETHANE

Class : 2.2

Hazard Labels : 2.2

EmS Number : F-C Marine pollutant : no

SECTION 15. REGULATORY INFORMATION

Inventories

1907/2006 (EU) : This mixture contains only ingredients which have been subject to a pre-registration according to Regulation (EC) No. 1907/2006 (REACH).

US. Toxic Substances

Control Act : On TSCA Inventory

Australia. Industrial Chemical (Notification and Assessment) Act : On the inventory, or in compliance with the inventory

Canada. Canadian

Environmental Protection Act (CEPA). Domestic Substances List (DSL). (Can. Gaz. Part II, Vol. 133) : All components of this product are on the Canadian DSL list.

Japan. Kashin-Hou Law

List : On the inventory, or in compliance with the inventory

Korea. Toxic Chemical Control Law (TCCL) List : On the inventory, or in compliance with the inventory

Philippines. The Toxic

Substances and Hazardous

and Nuclear Waste Control

Act : On the inventory, or in compliance with the inventory

China. Inventory of Existing

Chemical Substances : On the inventory, or in compliance with the inventory

New Zealand. Inventory of Chemicals (NZIoC), as published by ERMA New

Zealand : Not in compliance with the inventory

## Material Safety Data Sheet



## Genetron® 125

Version 2 Revision Date 12/15/2009 Print Date 03/28/2014

Page 10 / 10 : Pentafluoroethane 354-33-6

National regulatory information

SARA 311/312 Hazards : Acute Health Hazard

Sudden Release of Pressure Hazard

California Prop. 65 : This product does not contain any chemicals known to the State of California to cause cancer, bi rth, or any other reproductive

defects.

WHMIS Classification : A This product has been classified according to the hazard criteria

of the CPR and the MSDS contains all of the information required by the CPR.

Global warming potential : 3,400

Ozone depletion potential (ODP) : 0

SECTION 16. OTHER INFORMATION

HMIS III NFPA

Health hazard : 1 2 Flammability : 1 1 Physical Hazard : 0 Instability : 0

## SAFETY DATA SHEET

Genetron® 134a

000000009876

Page 1 / 13 Version 2.5 Revision Date 12/06/2012 Print Date 03/28/2014

SECTION 1. PRODUCT AND COMPANY IDENTIFICATION

Product name : Genetron® 134a

MSDS Number : 000000009876

Product Use Description : Refrigerant, Propellant

Company : Honeywell International, Inc.

101 Columbia Road
Morristown, NJ 07962-1057

For more information call : 800-522-8001

+1-973-455-6300 (Monday-Friday, 9:00am-5:00pm)

In case of emergency call : Medical: 1-800-498-5701 or +1-303-389-1414

: Transportation (CHEMTREC): 1-800-424-9300 or +1-703-

527-3887

: : (24 hours/day, 7 days/week)

SECTION 2. HAZARDS IDENTIFICATION

Emergency Overview

Form : Liquefied gas

Color : colourless

Odor : weak

Hazard Summary : Warning! Container under pressure. This product is not flammable at ambient temperatures and atmospheric pressure. Gas reduces oxygen available for breathing. Causes asphyxiation in high co ncentrations. The victim will not realize that he/she is suffocating. Excessive exposure may cause central nervous system effects including drowsiness and dizziness. Excessive exposure may also cause cardiac arrhythmia. Do not breathe v apour. Rapid evaporation of the liquid may cause frostbite. Avoid contact with skin, eyes and

## SAFETY DATA SHEET

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clothing. At higher temperatures, (>250 C), decomposition products may include hydrofluoric acid (HF) and carbonyl halides. The ACGIH Threshold Limit Values (2007) for Hydrogen Fluoride are TLV-TWA 0.5 ppm and Ceiling Exposure Limit 2 ppm.

Potential Health Effects

Skin : Avoid skin contact with leaking liquid (danger of frostbite). May cause frostbite. Irritating to skin.

Eyes : Causes serious eye irritation. May cause frostbite.

Ingestion : Unlikely route of exposure. Effects due to ingestion may include:

Gastrointestinal discomfort

Inhalation : Gas reduces oxygen available for breathing. Causes asphyxiation in high co ncentrations. The victim will not realize that he/she is suffocating. Excessive exposure may caus e central nervous system effects including drowsiness and dizziness. Excessive exposure may also cause cardiac arrhythmia.

Chronic Exposure : None known.

Carcinogenicity

No component of this product presen t at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP, IARC, or OSHA.

SECTION 3. COMPOSITION/IN FORMATION ON INGREDIENTS

Formula : CF3CH2F

Chemical nature : Substance

Chemical Name CAS-No. Concentration

## SAFETY DATA SHEET

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1,1,1,2-Tetrafluoroethane 811-97-2 99.80 %

SECTION 4. FIRST AID MEASURES

Inhalation : Move to fresh air. If breathing is irregular or stopped, administer artificial respirat ion. Use oxygen as required, provided a qualified operator is present. Call a physician. Do not give drugs from adrenaline-ephedrine group.

Skin contact : After contact with skin, wash immediately with plenty of water. If there is evidence of frostbite, bathe (do not rub) with lukewarm (not hot) water. If water is not available, cover with a clean, soft cloth or similar covering. If symptoms persist, call a physician.

Eye contact : Rinse immediately with plen ty of water, also under the eyelids,

for at least 15 minutes. In case of frostbite water should be lukewarm, not hot. If symptoms persist, call a physician.

Ingestion : Unlikely route of exposure. As this product is a gas, refer to the inhalation section. Do not induce vomiting without medical advice. Call a physician immediately.

Notes to physician

Treatment : Because of the possible disturbances of cardiac rhythm, catecholamine drugs, such as epinephrine, should be used with special caution and only in situations of emergency life support. Treatment of overexposure should be directed at thecontrol of symptoms and the clinical conditions. Treat frostbitten areas as needed.

SECTION 5. FIREFIGHTING MEASURES

Suitable extinguishing media : The product is not flammable. Use water spray, alcohol-resistant foam, dry chemical or

carbon dioxide. Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

Specific hazards during : Contents under pressure.

## SAFETY DATA SHEET

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firefighting This product is not flammable at ambient temperatures and atmospheric pressure. However, this material can ignite when mixed with air under pressure and exposed to strong ignition sources. Container may rupture on heating. Cool closed containers exposed to fire with water spray. Do not allow run-off from fire fighting to enter drains or water

courses. Vapours are heavier than air and can cause suffocation by reducing oxygen available for breathing. In case of fire hazardous decomposition products may be produced such as: Hydrogen halides Hydrogen fluoride

Carbon monoxide Carbon dioxide (CO2) Carbonyl halides

Special protective equipment for firefighters : In the event of fire and/or explosion do not breathe fumes. Wear self-contained breathing apparatus and protective suit. No unprotected exposed skin areas.

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions : Immediately evacuate personnel to safe areas. Keep people away from and upwind of spill/leak. Wear personal protective equipment. Unprotected persons must be kept away. Remove all sources of ignition. Avoid skin contact with leaking liquid (danger of frostbite).

Ventilate the area. After release, disperses into the air. Vapours are heavier than air and can cause suffocation by reducing oxygen available for breathing. Avoid accumulation of vapours in low areas. Unprotected personnel should not return until air has been

tested and determined safe. Ensure that the oxygen content is >= 19.5%.

Environmental precautions : Prevent further leakage or spillage if safe to do so. The product evaporates readily.

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Methods for cleaning up : Ventilate the area.

SECTION 7. HANDLING AND STORAGE

Handling

Handling : Handle with care. Avoid inhalation of vapour or mist. Do not get in eyes, on skin, or on clothing. Wear personal protective equipment. Use only in well-ventilated areas.

Pressurized container. Protect from sunlight and do not expose to temperatures exceeding 50 °C. Follow all standard safety precautions for handling and use of compressed gas cylinders. Use authorized cylinders only. Protect cylinders from physical damage. Do not puncture or drop cylinders, expose them to open flame

or excessive heat. Do not pierce or burn, even after use. Do not spray on a naked flame or any incandescent material. Do not remove screw cap until immediately ready for use. Always replace cap after use.

Advice on protection against fire and explosion : The product is not flammable. Can form a combustible mixture with air at pressures above atmospheric pressure.

Storage

Requirements for storage

areas and containers : Pressurized container: protec t from sunlight and do not expose to temperatures exceeding 50 °C. Do not pierce or burn, even

after use. Keep containers tightly closed in a dry, cool and well-ventilated place. Storage rooms must be properly ventilated. Ensure adequate ventilation, especially in confined areas. Protect cylinders from physical damage.

SECTION 8. EXPOSURE CONT ROLS/PERSONAL PROTECTION

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Protective measures : Do not breathe vapour. Avoid contact with skin, eyes and clothing. Ensure that eyewash stations and safety showers are close to

the workstation location.

Engineering measures : General room vent ilation is adequate for storage and handling. Perform filling operations only at stations with exhaust

ventilation facilities.

Eye protection : Wear as appropriate: Safety glasses with side-shields If splashes are likely to occur, wear: Goggles or face shield, giving complete protection to eyes

Hand protection : Leather gloves In case of contact through splashing: Protective gloves Neoprene gloves Polyvinyl alcohol or nitrile- butyl-rubber gloves

Skin and body protection : Avoid skin contact with leaking liquid (danger of frostbite). Wear cold insulating gloves/ face shield/ eye protection.

Respiratory protection : In case of insuffi cient ventilation, wear suitable respiratory equipment. Wear a positive-pressure supplied-air respirator. Vapours are heavier than air and can cause suffocation by reducing oxygen available for breathing.For rescue and maintenance work in storage tanks use selfcontained breathing apparatus.

Hygiene measures : Handle in accordance with good industrial hygiene and safety practice. Ensure adequate ventilation, especially in confined areas. Avoid contact with skin, eyes and clothing. Remove and wash contaminated clothing before re-use. Keep working clothes separately.

Exposure Guidelines

Components CAS-No. Value Control
parameters Upda

te Basis

## SAFETY DATA SHEET

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1,1,1,2-

Tetrafluoroethane 811-97-2 TWA :

time weighted

average (1,000 ppm) Honeywell : Limit established by Honeywell

International Inc.

1,1,1,2-

Tetrafluoroethane 811-97-2 TWA :

time weighted

average 4,240 mg/m3 (1,000 ppm) 2007 WEEL : US. AIHA Workplace

Environmental Exposure Level (WEEL) Guides

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Physical state : Liquefied gas

Color : colourless

Odor : weak

pH : Note: neutral

Melting point/freezing point : -101 °C

Boiling point/boiling range : -26.2 °C

Flash point : Note: not applicable

Evaporation rate : > 1 Method: Compared to CCl4.

Lower explosion limit : Note: None

Upper explosion limit : Note: None

Vapor pressure : 5,915 hPa

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at 21.1 °C(70.0 °F)
14,713 hPa at 54.4 °C(129.9 °F)

Vapor density : 3.5

Density : 1.2 g/cm3

Water solubility : 1.5 g/l

Partition coefficient: noctanol/water : log Pow: 1.06 Note: The product is more soluble in octanol.

Ignition temperature : > 750 °C

Autoignition temperature : > 750 °C

Decomposition temperature : > 250 °C Note: To avoid thermal decomposition, do not overheat.

Molecular Weight : 102.02 g/mol

Global warming potential (GWP) : 1,300

Ozone depletion potential (ODP) : 0

SECTION 10. STABILITY AND REACTIVITY

Chemical stability : Stable under normal conditions.

Possibility of hazardous

reactions : Hazardous polymerisation does not occur.

Conditions to avoid : Pressurized cont ainer. Protect from sunlight and do not expose to temperatures exceeding 50 °C. Decomposes under high temperature. Some risk may be expected of corrosive and toxic

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decomposition products. Can form a combustible mixture with air at pressures above atmospheric pressure. Do not mix with oxygen or air above atmospheric pressure.

Incompatible materials to

avoid : Finely divided aluminium

Potassium

Calcium

Powdered metals

Aluminium Magnesium

Zinc

Hazardous decomposition products : Halogenated compounds Hydrogen fluoride Carbonyl halides

Carbon oxides

SECTION 11. TOXICOLOGICAL INFORMATION

Acute inhalation toxicity : LC50: > 500000 ppm Exposure time: 4 h Species: rat

Sensitisation : Cardiac sensitization Species: dogs Note: No-observed-effect level 50 000 ppm Lowest observable effect level 75 000 ppm

Repeated dose toxicity : Species: rat NOEL: 40000 ppm

Genotoxicity in vitro : Note: In vitro tests did not show mutagenic effects

Further information : Note: Vapours are heavier than air and can cause suffocation by reducing oxygen available for breathing. Rapid evaporation of the liquid may cause frostbite. Avoid skin contact with

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leaking liquid (danger of frostbite).

SECTION 12. ECOLOGICAL INFORMATION

Further information on ecology

Additional ecological

information : Accumulation in aquatic organisms is unlikely. This product contains greenhouse gases which may contribute to global warming. Do NOT vent to the atmosphere. To comply with provisions of the U.S. Clean Air Act, any

residual must be recovered.

SECTION 13. DISPOSAL CONSIDERATIONS

Disposal methods : Observe all Federal, State, and Local Environmental regulations.

Note : This product is subject to U.S. Environmental Protection Agency Clean Air Act Regulations Section 608 in 40 CFR Part 82 regarding refrigerant recycling.

SECTION 14. TRANSPORT INFORMATION

DOT UN/ID No. : UN 3159 Proper shipping name : 1,1,1,2-Tetrafluoroethane

Class 2.2 Packing group

Hazard Labels 2.2

IATA UN/ID No. : UN 3159 Description of the goods : 1,1,1,2-Tetrafluoroethane

Class : 2.2

Hazard Labels : 2.2 Packing instruction (cargo aircraft) : 200

Packing instruction (passenger aircraft) : 200

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IMDG UN/ID No. : UN 3159 Description of the goods : 1,1,1,2-Tetrafluoroethane

Class : 2.2

Hazard Labels : 2.2

EmS Number : F-C, S-V Marine pollutant : no

SECTION 15. REGULATORY INFORMATION

Inventories

US. Toxic Substances

Control Act : On TSCA Inventory

Australia. Industrial Chemical (Notification and Assessment) Act : On the inventory, or in compliance with the inventory

Canada. Canadian

Environmental Protection Act (CEPA). Domestic Substances List (DSL) : All components of this product are on the Canadian DSL list.

Japan. Kashin-Hou Law

List : On the inventory, or in compliance with the inventory

Korea. Existing Chemicals Inventory (KECI) : On the inventory, or in compliance with the inventory

Philippines. The Toxic

Substances and Hazardous

and Nuclear Waste Control

Act : On the inventory, or in compliance with the inventory

China. Inventory of Existing

Chemical Substances : On the inventory, or in compliance with the inventory

NZIOC - New Zealand : On the inventory, or in compliance with the inventory

National regulatory information

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SARA 302 Components : SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.

SARA 313 Components : SARA 313: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313.

SARA 311/312 Hazards : Acute Health Hazard

Sudden Release of Pressure Hazard

California Prop. 65 : This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.

New Jersey RTK : 1,1,1,2-Tetrafluoroethane 811-97-2

Pennsylvania RTK : 1,1,1,2-Tetrafluoroethane 811-97-2

WHMIS Classification : A : Compressed Gas This product has been classified according to the hazard criteria

of the CPR and the MSDS contains all of the information required by the CPR.

Global warming potential : 1,300

Ozone depletion potential (ODP) : 0

SECTION 16. OTHER INFORMATION

HMIS III NFPA

Health hazard : 1 2 Flammability : 1 1

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Physical Hazard : 0 Instability : 0

Hazard rating and rating systems (e.g. HMIS® III, NFPA): This information is intended solely for the use of individuals trained in the particular system.

Further information

The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publicati on. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. Final determination of suitability of any material is the sole responsibility of the user. This information should not constitute a guarantee for any specific product properties.

Changes since the last version are highlighted in the margin. This version replaces all previous

versions.

Previous Issue Date : 12/15/2009 Prepared by: Honeywell Performance Materials and Technologies Product Stewardship Group

## SAFETY DATA SHEET

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SECTION 1. PRODUCT AND COMPANY IDENTIFICATION

Product name : Solstice® 1234ze

MSDS Number : 000000012546

Product Use Description : Aerosol propellant, Foam blowing agent

Manufacturer or supplier's

details : Honeywell International, Inc.

101 Columbia Road
Morristown, NJ 07962-1057

For more information call : 800-522-8001

+1-973-455-6300 (Monday-Friday, 9:00am-5:00pm)

In case of emergency call : Medical: 1-800-498-5701 or +1-303-389-1414

: Transportation (CHEMTREC): 1-800-424-9300 or +1-703-

527-3887

: : (24 hours/day, 7 days/week)

SECTION 2. HAZARDS IDENTIFICATION

Emergency Overview

Form : Liquefied gas

Color : colourless

Odor : slight ether-like

Classification of the substance or mixture

Classification of the

substance or mixture : Gases under pressure, Liquefied gas Simple Asphyxiant

GHS Label elements, including precautionary statements

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Symbol(s) :

Signal word : Warning

Hazard statements : Contains gas unde r pressure; may explode if heated. May displace oxygen and cause rapid suffocation.

Precautionary statements : Prevention: Use personal protective equipment as required.

Storage: Protect from sunlight. Store in a well-ventilated place.

Carcinogenicity

No component of this product presen t at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP, IARC, or OSHA.

SECTION 3. COMPOSITION/IN FORMATION ON INGREDIENTS

Chemical nature : Substance

Chemical Name CAS-No. Concentration

trans-1,3,3,3-Tetrafluoroprop-1-ene 29118-24-9 100.00 %

SECTION 4. FIRST AID MEASURES

Inhalation : Remove to fresh air. If breathing is irregular or stopped, administer artificial respirat ion. Use oxygen as required, provided a qualified operator is present. Call a physician.

Skin contact : Rapid evapouration of the liquid may cause frostbite. If there is evidence of frostbite, bathe (do not rub) with lukewarm (not hot) water. If water is not available, cover with a clean, soft cloth or similar covering. Call a physician if irritation develops

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or persists.

Eye contact : Rinse immediately with plen ty of water, also under the eyelids,

for at least 15 minutes. In case of frostbite water should be lukewarm, not hot. If symptoms persist, call a physician.

Ingestion : Unlikely route of exposure. As this product is a gas, refer to the inhalation section. Do not induce vomiting without medical advice. Call a physician immediately.

Notes to physician

Treatment : Treat frost-bitten areas as needed.

SECTION 5. FIREFIGHTING MEASURES

Suitable extinguishing media : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

Water mist Dry powder

Foam Carbon dioxide (CO2)

Unsuitable extinguishing

media : High volume water jet

Specific hazards during firefighting : Contents under pressure. Heating will cause pressure ri se with risk of bursting Cool closed containers exposed to fire with water spray.

Product is not combustible under normal conditions. However, this material can ignite when mixed with air under pressure and exposed to strong ignition sources. Do not allow run-off from fire fighting to enter drains or water

courses. Vapours are heavier than air and can cause suffocation by reducing oxygen available for breathing. Some risk may be expected of corrosive and toxic decomposition products. Fire may cause evolution of: Hydrogen fluoride

Special protective equipment for firefighters : In the event of fire and/or explosion do not breathe fumes. Wear self-contained breathing apparatus and protective suit. No unprotected exposed skin areas.

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Exposure to decomposition products may be a hazard to

health.

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions : Immediately evacuate personnel to safe areas. Keep people away from and upwind of spill/leak. Wear personal protective equipment. Unprotected persons must be kept away. Remove all sources of ignition. Avoid skin contact with leaking liquid (danger of frostbite).

Ventilate the area. After release, disperses into the air. Vapours are heavier than air and can cause suffocation by reducing oxygen available for breathing. Avoid accumulation of vapours in low areas. Unprotected personnel should not return until air has been

tested and determined safe.

Environmental precautions : Prevent further leakage or spillage if safe to do so. The product evapourates readily. Prevent spreading over a wide area (e.g. by containment or oil barriers).

Methods for cleaning up : Do not direct water spray at the point of leakage. Allow to evapourate.

SECTION 7. HANDLING AND STORAGE

Handling

Handling : Handle with care. Avoid inhalation of vapour or mist. Do not get in eyes, on skin, or on clothing. Wear personal protective equipment.

Pressurized container. Protect from sunlight and do not expose to temperatures exceeding 50 °C. Follow all standard safety precautions for handling and use of compressed gas cylinders. Use authorized cylinders only.

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Protect cylinders from physical damage. Do not puncture or drop cylinders, expose them to open flame

or excessive heat. Do not pierce or burn, even after use. Do not spray on a naked flame or any incandescent material. Do not remove screw cap until immediately ready for use. Always replace cap after use.

Advice on protection against fire and explosion : Do not spray on a naked flame or any incandescent material. Keep away from direct sunlight. Fire or intense heat may cause violent rupture of packages. Vapours may form explosive mixtures with air. The product is not easily combustible.

Storage

Requirements for storage

areas and containers : Keep containers tightly closed in a cool, well-ventilated place. Keep away from direct sunlight. Protect cylinders from physical damage. Store away from incompatible substances.

Further information on storage conditions : Keep only in the original container at temperature not exceeding 50°C

Advice on common storage : Do not store together with: Oxidizing agents

SECTION 8. EXPOSURE CONT ROLS/PERSONAL PROTECTION

Protective measures : Do not breathe vapour. Avoid contact with skin, eyes and clothing. Ensure that eyewash stations and safety showers are close to

the workstation location.

Engineering measures : Local exhaust

Eye protection : Goggles

Hand protection : Protective gloves

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Skin and body protection : impervious clothing Wear cold insulating gloves/ face shield/ eye protection.

Respiratory protection : In case of insu fficient ventilation wear suitable respiratory equipment. Wear a positive-pressure supplied-air respirator.

Hygiene measures : Avoid br eathing vapours, mist or gas. Keep working clothes separately.

Do not smoke.

Exposure Guidelines

Components CAS-No. Value Control
parameters Upda

te Basis

trans-1,3,3,3-Tetrafluoroprop1-ene 29118-24-9 TWA :

time weighted

average (800 ppm) 2012 WEEL : US. AIHA Workplace

Environmental Exposure Level (WEEL) Guides

trans-1,3,3,3-Tetrafluoroprop1-ene 29118-24-9 TWA :

time weighted

average (800 ppm) 31.03.

11 Honeywell : Limit established by Honeywell

International Inc.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Physical state : Liquefied gas

Color : colourless

Odor : slight ether-like

pH : Note: neutral

Boiling point/boiling range : -19 °C

Flash point : Note: does not flash

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Lower explosion limit : Note: Exhibits flam e limits at temperatures in excess of 28  ̊ C.

Upper explosion limit : Note: Exhibits flame limits at temperatures in excess of 28  ̊ C.

Vapor pressure : 4,192 hPa at 20 °C(68 °F)
10,998 hPa at 54.4 °C(129.9 °F)

Vapor density : 4 Note: (Air = 1.0)

Density : 1.17 g/cm3 at 21.1 °C

Water solubility : 0.373 g/l

Partition coefficient: noctanol/water : log Pow: 1.6

Ignition temperature : 368 °C Method: Auto-ignition temperature

SECTION 10. STABILITY AND REACTIVITY

Chemical stability : Stable under normal conditions.

Possibility of hazardous

reactions : Hazardous polymerisation does not occur.

Conditions to avoid : Pressurized cont ainer. Protect from sunlight and do not expose to temperatures exceeding 50 °C. Can form a combustible mixture with air at pressures above

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atmospheric pressure. Do not mix with oxygen or air above atmospheric pressure.

Incompatible materials to

avoid : Reactions with alkali metals.

Hazardous decomposition products : Pyrolysis products containing fluoride

Fluorocarbons Hydrogen fluoride

SECTION 11. TOXICOLOGICAL INFORMATION

Acute inhalation toxicity : Species: mouse Note: Acute (4-Hour) Inhalation Toxicity Screening Study (mouse): No lethality at >100,000 ppm.

: LC50: > 207000 ppm Exposure time: 4 h Species: rat

Skin irritation : Species: rabbit

Result: No skin irritation

Method: OECD Test Guideline 404

Sensitisation : Cardiac sensitization Species: dogs Result: Did not cause sensitisation on laboratory animals.

Repeated dose toxicity : Species: rat Application Route: Inhalation Exposure time: 13 Weeks Note: Causes mild effects on the heart. NOEL 5,000 ppm

Genotoxicity in vitro : Test Method: Chromosome aberration test in vitro Cell type: Human lymphocytes Result: negative

: Test Method: Ames test Result: negative

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Genotoxicity in vivo : Test Method: Mutagenicity (in vivo mammalian bone-marrow cytogenetic test, chromosomal analysis) Species: mouse Cell type: Micronucleus Application Route: Inhalation Result: negative

Teratogenicity : Species: rabbit Method: Prenatal Developmental Inhalation Toxicity Study Note: Did not show teratogenic effects in animal experiments.

: Species: rat Method: Prenatal Developmental Inhalation Toxicity Study Note: Did not show teratogenic effects in animal experiments.

Further information : Note: Excessive ex posure may cause central nervous system effects including drowsiness and dizziness. Excessive exposure may also cause cardiac arrhythmia. Rapid evapouration of the liquid may cause frostbite.

SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity effects

Toxicity to fish : NOEC: > 117 mg/l Exposure time: 96 h Species: Cyprinus carpio (Carp)

Toxicity to daphnia and other aquatic invertebrates : EC50: > 160 mg/l Exposure time: 48 h Species: Daphnia magna (Water flea)

Toxicity to algae : Growth inhibition NOEC: > 170 mg/l Exposure time: 72 h Species: Algae

## SAFETY DATA SHEET

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Elimination information (persistence and degradability)

Biodegradability : aerobic Result: Not readily biodegradable.

Further information on ecology

Additional ecological

information : no data available

SECTION 13. DISPOSAL CONSIDERATIONS

Disposal methods : Observe all Federal, State, and Local Environmental regulations.

SECTION 14. TRANSPORT INFORMATION

DOT UN/ID No. : UN 3163 Proper shipping name : LIQUEFIED GAS, N.O.S. (trans-1,3,3,3-Tetrafluoroprop-1-ene)

Class 2.2 Packing group

Hazard Labels 2.2

IATA UN/ID No. : UN 3163 Description of the goods : L IQUEFIED GAS, N.O.S. (trans-1,3,3,3-Tetrafluoroprop-1-ene)

Class : 2.2

Hazard Labels : 2.2 Packing instruction (cargo aircraft) : 200

Packing instruction (passenger aircraft) : 200

IMDG UN/ID No. : UN 3163 Description of the goods : L IQUEFIED GAS, N.O.S. (TRANS-1,3,3,3-TETRAFLUOROPROP-1-ENE)

Class : 2.2

Hazard Labels : 2.2

## SAFETY DATA SHEET

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EmS Number : F-C, S-V Marine pollutant : no

SECTION 15. REGULATORY INFORMATION

Inventories

US. Toxic Substances

Control Act : On TSCA Inventory

Australia. Industrial Chemical (Notification and Assessment) Act : Not in compliance with the inventory

: trans-1,3,3,3-Tetrafluoroprop-1-

ene 29118-24-9

Canada. Canadian

Environmental Protection Act (CEPA). Domestic Substances List (DSL) : All components of this product are on the Canadian DSL.

Japan. Kashin-Hou Law

List : On the inventory, or in compliance with the inventory

Korea. Toxic Chemical Control Law (TCCL) List : Not in compliance with the inventory

: trans-1,3,3,3-Tetrafluoroprop-1-

ene 29118-24-9

Philippines. The Toxic

Substances and Hazardous

and Nuclear Waste Control

Act : Not in compliance with the inventory

: trans-1,3,3,3-Tetrafluoroprop-1-

ene 29118-24-9

China. Inventory of Existing

Chemical Substances : On the inventory, or in compliance with the inventory

New Zealand. Inventory of Chemicals (NZIoC), as published by ERMA New

Zealand : Not in compliance with the inventory

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: trans-1,3,3,3-Tetrafluoroprop-1-

ene 29118-24-9

National regulatory information

SARA 302 Components : SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.

SARA 313 Components : SARA 313: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313.

SARA 311/312 Hazards : Acute Health Hazard

Sudden Release of Pressure Hazard

California Prop. 65 : This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.

WHMIS Classification : A : Compressed Gas This product has been classified according to the hazard criteria

of the CPR and the MSDS contains all of the information required by the CPR.

SECTION 16. OTHER INFORMATION

HMIS III NFPA

Health hazard : 1 2 Flammability : 0 0 Physical Hazard : 0 Instability : 0

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Hazard rating and rating systems (e.g. HMIS® III, NFPA): This information is intended solely for the use of individuals trained in the particular system.

Further information

The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publicati on. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. Final determination of suitability of any material is the sole responsibility of the user. This information should not constitute a guarantee for any specific product properties.

Changes since the last version are highlighted in the margin. This version replaces all previous

versions.

Previous Issue Date : 01/24/2014 Prepared by Honeywell Performance Materials and Technologies Product Stewardship Group

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SECTION 1. PRODUCT AND COMPANY IDENTIFICATION

Product name : Solstice® N-40

MSDS Number : 000000017419

Product Use Description : Refrigerant

Manufacturer or supplier's

details : Honeywell International, Inc.

101 Columbia Road
Morristown, NJ 07962-1057

For more information call : 800-522-8001

+1-973-455-6300 (Monday-Friday, 9:00am-5:00pm)

In case of emergency call : Medical: 1-800-498-5701 or +1-303-389-1414

: Transportation (CHEMTREC): 1-800-424-9300 or +1-703-

527-3887

: : (24 hours/day, 7 days/week)

SECTION 2. HAZARDS IDENTIFICATION

Emergency Overview

Form : Liquefied gas

Color : clear colourless

Odor : slight ether-like

Classification of the substance or mixture

Classification of the

substance or mixture : Gases under pressure, Liquefied gas Simple Asphyxiant

GHS Label elements, including precautionary statements

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Symbol(s) :

Signal word : Warning

Hazard statements : Contains gas unde r pressure; may explode if heated. May displace oxygen and cause rapid suffocation.

Precautionary statements : Prevention: Use personal protective equipment as required.

Storage: Protect from sunlight. Store in a well-ventilated place.

Hazards not otherwise

classified : May cause frostbite. May cause cardiac arrhythmia. May cause eye and skin irritation.

Carcinogenicity

No component of this product presen t at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP, IARC, or OSHA.

SECTION 3. COMPOSITION/IN FORMATION ON INGREDIENTS

Chemical nature : Mixture

Chemical Name CAS-No. Concentration

Difluoromethane 75-10-5 26.00 %

Pentafluoroethane 354-33-6 26.00 %

1,1,1,2-Tetrafluoroethane 811-97-2 21.00 %

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2,3,3,3-Tetrafluoroprop-1-ene 754-12-1 20.00 %

trans-1,3,3,3-Tetrafluoroprop-1-ene 29118-24-9 7.00 %

SECTION 4. FIRST AID MEASURES

Inhalation : Move to fresh air. If breathing is irregular or stopped, administer artificial respirat ion. Use oxygen as required, provided a qualified operator is present. Call a physician. Do not give drugs from adrenaline-ephedrine group.

Skin contact : After contact with skin, wash immediately with plenty of water. If there is evidence of frostbite, bathe (do not rub) with lukewarm (not hot) water. If water is not available, cover with a clean, soft cloth or similar covering. If symptoms persist, call a physician.

Eye contact : Rinse immediately with plen ty of water, also under the eyelids,

for at least 15 minutes. In case of frostbite water should be lukewarm, not hot. If symptoms persist, call a physician.

Ingestion : Unlikely route of exposure. As this product is a gas, refer to the inhalation section. Do not induce vomiting without medical advice. Call a physician immediately.

Notes to physician

Treatment : Because of the possible disturbances of cardiac rhythm, catecholamine drugs, such as epinephrine, should be used with special caution and only in situations of emergency life support. Treatment of overexposure should be directed at thecontrol of symptoms and the clinical conditions. Treat frostbitten areas as needed.

SECTION 5. FIREFIGHTING MEASURES

Suitable extinguishing media : The product is not flammable. Use water spray, alcohol-resistant foam, dry chemical or

carbon dioxide. Use extinguishing measures that are appropriate to local

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circumstances and the surrounding environment.

Specific hazards during firefighting : Contents under pressure. This product is not flammable at ambient temperatures and atmospheric pressure. However, this material can ignite when mixed with air under pressure and exposed to strong ignition sources. Container may rupture on heating. Cool closed containers exposed to fire with water spray. Do not allow run-off from fire fighting to enter drains or water

courses. Vapours are heavier than air and can cause suffocation by reducing oxygen available for breathing. In case of fire hazardous decomposition products may be produced such as: Hydrogen halides Hydrogen fluoride

Carbon monoxide Carbon dioxide (CO2) Carbonyl halides

Special protective equipment for firefighters : In the event of fire and/or explosion do not breathe fumes. Wear self-contained breathing apparatus and protective suit. No unprotected exposed skin areas.

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions : Immediately evacuate personnel to safe areas. Keep people away from and upwind of spill/leak. Wear personal protective equipment. Unprotected persons must be kept away. Remove all sources of ignition. Avoid skin contact with leaking liquid (danger of frostbite).

Ventilate the area. After release, disperses into the air. Vapours are heavier than air and can cause suffocation by reducing oxygen available for breathing. Avoid accumulation of vapours in low areas. Unprotected personnel should not return until air has been

tested and determined safe. Ensure that the oxygen content is >= 19.5%.

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Environmental precautions : Prevent further leakage or spillage if safe to do so. The product evapourates readily.

Methods for cleaning up : Ventilate the area.

SECTION 7. HANDLING AND STORAGE

Handling

Handling : Handle with care. Avoid inhalation of vapour or mist. Do not get in eyes, on skin, or on clothing. Wear personal protective equipment. Use only in well-ventilated areas.

Pressurized container. Protect from sunlight and do not expose to temperatures exceeding 50 °C. Follow all standard safety precautions for handling and use of compressed gas cylinders. Use authorized cylinders only. Protect cylinders from physical damage. Do not puncture or drop cylinders, expose them to open flame

or excessive heat. Do not pierce or burn, even after use. Do not spray on a naked flame or any incandescent material. Do not remove screw cap until immediately ready for use. Always replace cap after use.

Advice on protection against fire and explosion : The product is not flammable. Can form a combustible mixture with air at pressures above atmospheric pressure.

Storage

Requirements for storage

areas and containers : Pressurized container: protec t from sunlight and do not expose to temperatures exceeding 50 °C. Do not pierce or burn, even

after use. Keep containers tightly closed in a dry, cool and well-ventilated place. Storage rooms must be properly ventilated. Ensure adequate ventilation, especially in confined areas. Protect cylinders from physical damage.

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SECTION 8. EXPOSURE CONT ROLS/PERSONAL PROTECTION

Protective measures : Do not breathe vapour. Avoid contact with skin, eyes and clothing. Ensure that eyewash stations and safety showers are close to

the workstation location.

Engineering measures : General room vent ilation is adequate for storage and handling. Perform filling operations only at stations with exhaust

ventilation facilities.

Eye protection : Wear as appropriate: Safety glasses with side-shields If splashes are likely to occur, wear: Goggles or face shield, giving complete protection to eyes

Hand protection : Leather gloves In case of contact through splashing: Protective gloves Neoprene gloves Polyvinyl alcohol or nitrile- butyl-rubber gloves

Skin and body protection : Avoid skin contact with leaking liquid (danger of frostbite). Wear cold insulating gloves/ face shield/ eye protection.

Respiratory protection : In case of insuffi cient ventilation, wear suitable respiratory equipment. Wear a positive-pressure supplied-air respirator. Vapours are heavier than air and can cause suffocation by reducing oxygen available for breathing.For rescue and maintenance work in storage tanks use selfcontained breathing apparatus.

Hygiene measures : Handle in accordance with good industrial hygiene and safety practice. Ensure adequate ventilation, especially in confined areas. Avoid contact with skin, eyes and clothing. Remove and wash contaminated clothing before re-use. Keep working clothes separately.

Exposure Guidelines

Components CAS-No. Value Control
parameters Upda

te Basis

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Difluoromethane 75-10-5 TWA :

time weighted

average 2,200 mg/m3 (1,000 ppm) 2007 WEEL : US. AIHA Workplace

Environmental Exposure Level (WEEL) Guides

Difluoromethane 75-10-5 TWA :

time weighted

average (1,000 ppm) 1994 Honeywell : Limit established by Honeywell

International Inc.

Pentafluoroethan

e 354-33-6 TWA :

time weighted

average 4,900 mg/m3 (1,000 ppm) 2007 WEEL : US. AIHA Workplace

Environmental Exposure Level (WEEL) Guides

Pentafluoroethan

e 354-33-6 TWA :

time weighted

average (1,000 ppm) Honeywell : Limit established by Honeywell

International Inc.

1,1,1,2-

Tetrafluoroethane 811-97-2 TWA :

time weighted

average (1,000 ppm) Honeywell : Limit established by Honeywell

International Inc.

1,1,1,2-

Tetrafluoroethane 811-97-2 TWA :

time weighted

average 4,240 mg/m3 (1,000 ppm) 2007 WEEL : US. AIHA Workplace

Environmental Exposure Level (WEEL) Guides

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2,3,3,3-Tetrafluoroprop1-ene 754-12-1 TWA :

time weighted

average (500 ppm) 2009 WEEL : US. AIHA Workplace

Environmental Exposure Level (WEEL) Guides

2,3,3,3-Tetrafluoroprop1-ene 754-12-1 TWA :

time weighted

average (500 ppm) 03 15

2010 Honeywell : Limit established by Honeywell

International Inc.

2,3,3,3-Tetrafluoroprop1-ene 754-12-1 STEL :

Short

term

exposure
limit (1,500 ppm) 03 15

2010 Honeywell : Limit established by Honeywell

International Inc.

trans-1,3,3,3-Tetrafluoroprop1-ene 29118-24-9 TWA :

time weighted

average (800 ppm) 2012 WEEL : US. AIHA Workplace

Environmental Exposure Level (WEEL) Guides

trans-1,3,3,3-Tetrafluoroprop1-ene 29118-24-9 TWA :

time weighted

average (800 ppm) 31.03.

11 Honeywell : Limit established by Honeywell

International Inc.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Physical state : Liquefied gas

Color : clear colourless

Odor : slight ether-like

pH : Note: neutral

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Melting point/freezing point : Note: no data available

Boiling point/boiling range : Note: no data available

Flash point : Note: not applicable

Lower explosion limit : Note: None

Upper explosion limit : Note: None

Vapor pressure : 1,120 kPa at 21.1 °C(70.0 °F)
2,588 kPa at 54.4 °C(129.9 °F)

Vapor density : Note: no data available

Density : Note: no data available

Water solubility : Note: no data available

Partition coefficient: noctanol/water : Note: no data available

Ignition temperature : Note: no data available

Decomposition temperature : > 250 °C Note: To avoid thermal decomposition, do not overheat.

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SECTION 10. STABILITY AND REACTIVITY

Chemical stability : Stable under normal conditions.

Possibility of hazardous

reactions : Hazardous polymerisation does not occur.

Conditions to avoid : Pressurized cont ainer. Protect from sunlight and do not expose to temperatures exceeding 50 °C. Decomposes under high temperature. Some risk may be expected of corrosive and toxic decomposition products. Can form a combustible mixture with air at pressures above atmospheric pressure. Do not mix with oxygen or air above atmospheric pressure.

Incompatible materials to

avoid : Finely divided aluminium

Potassium

Calcium

Powdered metals

Aluminium Magnesium

Zinc

Hazardous decomposition products : Halogenated compounds Hydrogen fluoride Carbonyl halides

Carbon oxides

SECTION 11. TOXICOLOGICAL INFORMATION

Acute inhalation toxicity Difluoromethane : LC50: > 520000 ppm Exposure time: 4 h Species: rat

Pentafluoroethane : > 769000 ppm Exposure time: 4 h Species: rat

1,1,1,2-Tetrafluoroethane : LC50: > 500000 ppm

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Exposure time: 4 h Species: rat

2,3,3,3-Tetrafluoroprop-1-

ene : LC50: > 400000 ppm Exposure time: 4 h Species: rat

trans-1,3,3,3- Tetrafluoroprop-1-ene : 100000 ppm Species: mouse Note: Acute (4-Hour) Inhalation Toxicity Screening Study (mouse): No lethality at >100,000 ppm.

LC50: > 207000 ppm Exposure time: 4 h Species: rat

Skin irritation
trans-1,3,3,3- Tetrafluoroprop-1-ene : Species: rabbit

Result: No skin irritation

Method: OECD Test Guideline 404

Sensitisation

Difluoromethane : Cardiac sensitization Species: dogs

Note: No-observe d-effect level >350 000 ppm

Pentafluoroethane : Cardiac sensitization Species: dogs

Note: No-observe d-effect level 75 000 ppm

Lowest observable effect level 100 000 ppm

1,1,1,2-Tetrafluoroethane : Cardiac sensitization Species: dogs

Note: No-observe d-effect level 50 000 ppm

Lowest observable effect level 75 000 ppm

2,3,3,3-Tetrafluoroprop-1-

ene : Cardiac sensitization Species: dogs

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Result: No effects observed fo r exposures up to 12% (120,189 ppm).

trans-1,3,3,3- Tetrafluoroprop-1-ene : Cardiac sensitization Species: dogs Note: Did not cause sensitisation on laboratory animals.

Repeated dose toxicity Difluoromethane : Species: rat Application Route: Inhalation Exposure time: (90 d) NOEL: 50000 ppm Subchronic toxicity

Pentafluoroethane : Species: rat Application Route: Inhalation Exposure time: (4 Weeks) NOEL: 50000 ppm Subchronic toxicity

1,1,1,2-Tetrafluoroethane : Species: rat NOEL: 40000 ppm

2,3,3,3-Tetrafluoroprop-1-

ene : Species: rat Application Route: Inhalation Exposure time: (2 Weeks) NOEL: 50000 ppm

Species: rat Application Route: Inhalation Exposure time: (4 Weeks) NOAEL (No observed adverse effect level): 50000 ppm

Species: rat Application Route: Inhalation Exposure time: (13 Weeks) NOAEL (No observed adverse effect level): 50000 ppm

Species: rabbit, male Application Route: Inhalation Exposure time: (28 d) No-observed-effect level: 500 ppm

Species: rabbit, female

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Application Route: Inhalation Exposure time: (28 d) No-observed-effect level: 1000 ppm

Species: mini-pig Application Route: Inhalation Exposure time: (28 d) NOAEL (No observed adverse effect level): 10,000 ppm (highest exposure tested).

trans-1,3,3,3- Tetrafluoroprop-1-ene : Species: rat Application Route: Inhalation Exposure time: (13 Weeks) NOEL: 5000 ppm

Causes mild effects on the heart.

Genotoxicity in vitro

Difluoromethane : Test Method: Ames test Result: negative

Pentafluoroethane : Test Method: Ames test Result: negative

1,1,1,2-Tetrafluoroethane : Note: In vitro tests did not show mutagenic effects

2,3,3,3-Tetrafluoroprop-1-

ene : Test Method: Ames test Result: 20% and higher, positive in TA 100 and e. coli WP2 uvrA, negative in TA98, TA100, and TA1535.

trans-1,3,3,3- Tetrafluoroprop-1-ene : Test Method: Chromosome aberration test in vitro Cell type: Human lymphocytes Result: negative

: Cell type: Human lymphocytes Result: negative Method: Mutagenicity (in vitro mammalian cytogenetic test)

: Test Method: Chromosome aberration test in vitro Result: negative

: Cell type: Human lymphocytes Result: negative

: Cell type: Chinese Hamster Ovary Cells

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Result: negative

: Test Method: Chromosome aberration test in vitro Cell type: Human lymphocytes Result: negative Note: Dose 760,000 ppm

: Test Method: Chromosome aberration test in vitro Cell type: Chinese Hamster Lung Cells Result: negative

: Test Method: Ames test Result: negative

Genotoxicity in vivo Difluoromethane : Species: mouse Cell type: Bone marrow Method: Mutagenicity (micronucleus test) Result: negative

2,3,3,3-Tetrafluoroprop-1-

ene : Species: mouse Cell type: Micronucleus Dose: up to 200,000 ppm (4 hour) Result: negative

: Test Method: Unscheduled DNA synthesis Dose: up to 50,000 ppm (4 weeks) Result: negative

: Species: rat Cell type: Micronucleus Dose: up to 50,000 ppm (4 weeks) Result: negative

trans-1,3,3,3- Tetrafluoroprop-1-ene : Test Method: Mutagenicity (in vivo mammalian bone-marrow cytogenetic test, chromosomal analysis) Species: mouse Cell type: Micronucleus Application Route: Inhalation Result: negative

Reproductive toxicity 2,3,3,3-Tetrafluoroprop-1- : Species: rat

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ene Application Route: Inhalation exposure Exposure time: Two-generation reproductive toxicity NOAEL,parent: 50,000 ppm NOAEL,F1: 50,000 ppm NOAEL,F2: 50,000 ppm

Teratogenicity Difluoromethane : Species: rat Dose: NOEL - 50,000 ppm Note: Did not show teratogenic effects in animal experiments.

Species: rabbit Dose: NOEL - 50,000 ppm Note: Did not show teratogenic effects in animal experiments.

Pentafluoroethane : Species: rabbit Application Route: Inhalation exposure NOAEL,Teratog: 50,000 ppm NOAEL,Maternal: 50,000 ppm Note: Did not show teratogenic effects in animal experiments.

Species: rat Application Route: Inhalation exposure NOAEL,Teratog: 50,000 ppm NOAEL,Maternal: 50,000 ppm Note: Did not show teratogenic effects in animal experiments.

2,3,3,3-Tetrafluoroprop-1-

ene : Species: rat Dose: NOAEL (No observed adverse effect level) - 50,000

ppm

Species: rabbit Dose: NOAEL (No observed adverse effect level) - 4,000 ppm

trans-1,3,3,3- Tetrafluoroprop-1-ene : Species: rabbit Method: Prenatal Developmental Inhalation Toxicity Study Note: Did not show teratogenic effects in animal experiments.

Species: rat Method: Prenatal Developmental Inhalation Toxicity Study Note: Did not show teratogenic effects in animal experiments.

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Further information 1,1,1,2-Tetrafluoroethane : Note: Vapours are heavier than air and can cause suffocation by reducing oxygen available for breathing. Rapid evapouration of the liquid may cause frostbite. Avoid skin contact with leaking liquid (danger of frostbite).

SECTION 12. ECOLOGICAL INFORMATION

Toxicity to fish 2,3,3,3-Tetrafluoroprop-1-

ene : LC50: > 197 mg/l Exposure time: 96 h Species: Cyprinus carpio (Carp)

Method: OECD Test Guideline 203

Note: No demonstrable toxic effect in saturated solution.

trans-1,3,3,3- Tetrafluoroprop-1-ene : NOEC: > 117 mg/l Exposure time: 96 h Species: Cyprinus carpio (Carp)

Toxicity to daphnia and other aquatic invertebrates 2,3,3,3-Tetrafluoroprop-1-

ene : EC50: > 83 mg/l Exposure time: 48 h Species: Daphnia magna (Water flea)

Method: OECD Test Guideline 202

trans-1,3,3,3- Tetrafluoroprop-1-ene : EC50: > 160 mg/l Exposure time: 48 h Species: Daphnia magna (Water flea)

Toxicity to algae 2,3,3,3-Tetrafluoroprop-1-

ene : EC50: > 100 mg/l Species: Scenedesmus capricornutum (fresh water algae)

trans-1,3,3,3- Tetrafluoroprop-1-ene : Growth inhibition NOEC: > 170 mg/l Exposure time: 72 h Species: Algae

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Biodegradability

Difluoromethane : Note: Minimal

Pentafluoroethane : Result: Not readily biodegradable.

Value: 5 %

Method: OECD 301 D

2,3,3,3-Tetrafluoroprop-1-

ene : Result: Not readily biodegradable.

trans-1,3,3,3- Tetrafluoroprop-1-ene : aerobic Result: Not readily biodegradable.

Further information on ecology

Additional ecological

information : This product is subject to U.S. Environmental Protection Agency Clean Air Act Regulations at 40 CFR Part 82. This product contains greenhouse gases which may contribute to global warming. Do NOT vent to the atmosphere. To comply with provisions of the U.S. Clean Air Act, any

residual must be recovered.

SECTION 13. DISPOSAL CONSIDERATIONS

Disposal methods : Observe all Federal, State, and Local Environmental regulations.

SECTION 14. TRANSPORT INFORMATION

DOT UN/ID No. : UN 3163 Proper shipping name : LIQUEFIED GAS, N.O.S. (Pentafluoroethane, Difl uoromethane, 1,1,1,2- Tetrafluoroethane)

Class 2.2 Packing group

Hazard Labels 2.2

IATA UN/ID No. : UN 3163 Description of the goods : L IQUEFIED GAS, N.O.S. (Pentafluoroethane, Di fluoromethane, 1,1,1,2-

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Tetrafluoroethane)

Class : 2.2

Hazard Labels : 2.2 Packing instruction (cargo aircraft) : 200

Packing instruction (passenger aircraft) : 200

IMDG UN/ID No. : UN 3163 Description of the goods : L IQUEFIED GAS, N.O.S. (PENTAFLUOROETHANE, DIFLUOROMETHANE, 1,1,1,2- TETRAFLUOROETHANE)

Class : 2.2

Hazard Labels : 2.2

EmS Number : F-C, S-V Marine pollutant : no

SECTION 15. REGULATORY INFORMATION

Inventories

US. Toxic Substances

Control Act : On TSCA Inventory

Australia. Industrial Chemical (Notification and Assessment) Act : Not in compliance with the inventory

Canada. Canadian

Environmental Protection Act (CEPA). Domestic Substances List (DSL) : All components of this product are on the Canadian DSL.

Japan. Kashin-Hou Law

List : On the inventory, or in compliance with the inventory

Korea. Toxic Chemical Control Law (TCCL) List : On the inventory, or in compliance with the inventory

Philippines. The Toxic

Substances and Hazardous

and Nuclear Waste Control

Act : Not in compliance with the inventory

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China. Inventory of Existing

Chemical Substances : Not in compliance with the inventory

New Zealand. Inventory of Chemicals (NZIoC), as published by ERMA New

Zealand : Not in compliance with the inventory

TSCA 12B : US. Toxic Substances Control Act (TSCA) Section 12(b) Export Notification (40 CFR 707, Subpt D)

2,3,3,3-Tetrafluoroprop-1-ene 754-12-1

National regulatory information

SARA 302 Components : SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.

SARA 313 Components : SARA 313: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313.

SARA 311/312 Hazards : Sudden Release of Pressure Hazard

Acute Health Hazard

California Prop. 65 : WARNING! This product contains a chemical known to the

State of California to cause cancer.

Dichloromethane 75-09-2

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: WARNING: This product contains a chemical known to the

State of California to cause birt h defects or other reproductive

harm.

Chloromethane 74-87-3

Massachusetts RTK : Dichloromethane 75-09-2

Pennsylvania RTK : Difluoromethane 75-10-5

WHMIS Classification : A : Compressed Gas This product has been classified according to the hazard criteria

of the CPR and the MSDS contains all of the information required by the CPR.

SECTION 16. OTHER INFORMATION

HMIS III NFPA

Health hazard : 1 2 Flammability : 1 1 Physical Hazard : 0 Instability : 0

Hazard rating and rating systems (e.g. HMIS® III, NFPA): This information is intended solely for the use of individuals trained in the particular system.

Further information

The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publicati on. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. Final determination of suitability of any material is the sole responsibility of the user. This information should not constitute a guarantee for any specific product properties.

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Changes since the last version are highlighted in the margin. This version replaces all previous

versions.

Previous Issue Date : 09/04/2013 Prepared by Honeywell Performance Materials and Technologies Product Stewardship Group

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SECTION 1. PRODUCT AND COMPANY IDENTIFICATION

Product name : Solstice® yf Refrigerant (R-1234yf)

MSDS Number : 000000011078

Product Use Description : Refrigerant

Manufacturer or supplier's

details : Honeywell International, Inc.

101 Columbia Road
Morristown, NJ 07962-1057

For more information call : 800-522-8001

+1-973-455-6300 (Monday-Friday, 9:00am-5:00pm)

In case of emergency call : Medical: 1-800-498-5701 or +1-303-389-1414

: Transportation (CHEMTREC): 1-800-424-9300 or +1-703-

527-3887

: : (24 hours/day, 7 days/week)

SECTION 2. HAZARDS IDENTIFICATION

Emergency Overview

Form : Liquefied gas

Color : clear

Odor : slight

Classification of the substance or mixture

Classification of the

substance or mixture : Flammable gases, Category 1 Gases under pressure, Liquefied gas Simple Asphyxiant

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GHS Label elements, including precautionary statements

Symbol(s) :

Signal word : Danger

Hazard statements : Extremely flammable gas. Contains gas under pressure ; may explode if heated. May displace oxygen and cause rapid suffocation.

Precautionary statements : Prevention: Keep away from heat/sparks/open flames/hot surfaces. - No smoking.

Response: Leaking gas fire: Do not extinguish, unless leak can be stopped safely. Eliminate all ignition sources if safe to do so.

Storage: Protect from sunlight. Store in a well-ventilated place.

Hazards not otherwise

classified : May cause eye and skin irritation. May cause frostbite.

Carcinogenicity

No component of this product presen t at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP, IARC, or OSHA.

SECTION 3. COMPOSITION/IN FORMATION ON INGREDIENTS

Chemical nature : Substance

Chemical Name CAS-No. Concentration

2,3,3,3-Tetrafluoroprop-1-ene 754-12-1 100.00 %

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SECTION 4. FIRST AID MEASURES

General advice : First aider needs to pr otect himself. Take off all contaminated clothing immediately.

Inhalation : Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Use oxygen as required, provided a qualified operator is present. Call a physician.

Skin contact : After contact with skin, wash immediately with plenty of water. Rapid evapouration of the liquid may cause frostbite. If there is evidence of frostbite, bathe (do not rub) with lukewarm (not hot) water. If water is not available, cover with a clean, soft cloth or similar covering. Call a physician. Wash contaminated clothing before re-use.

Eye contact : Rinse immediately with plen ty of water, also under the eyelids,

for at least 15 minutes. In case of frostbite water should be lukewarm, not hot. Call a physician.

Ingestion : Unlikely route of exposure. As this product is a gas, refer to the inhalation section. Do not induce vomiting without medical advice. If conscious, drink plenty of water. Never give anything by mouth to an unconscious person. Call a physician immediately.

Notes to physician

Treatment : Treat frost-bitten areas as needed. Treat symptomatically.

SECTION 5. FIREFIGHTING MEASURES

Suitable extinguishing media : In case of fire, allow gas to burn if flow cannot be shut off immediately. Apply water from a safe distance to cool container and protect surrounding area. Use water spray, alcohol-resistant foam, dry chemical or

carbon dioxide.

Specific hazards during firefighting : Flammable gas. Contents under pressure.

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Vapours are heavier than air and can cause suffocation by reducing oxygen available for breathing. Vapors may travel to areas away from work site before igniting/flashing back to vapor source. Fire or intense heat may cause violent rupture of packages. Cool closed containers exposed to fire with water spray. Do not allow run-off from fire fighting to enter drains or water

courses. In case of fire hazardous decomposition products may be produced such as: Hydrogen fluoride Carbonyl halides

Carbon monoxide Carbon dioxide (CO2)

Special protective equipment for firefighters : In the event of fire and/or explosion do not breathe fumes. Wear self-contained breathing apparatus and protective suit. No unprotected exposed skin areas.

Further information : In case of fire: Evac uate area. Fight fire remotely due to the risk of explosion.

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions : Immediately evacuate personnel to safe areas. Keep people away from and upwind of spill/leak. Wear personal protective equipment. Unprotected persons must be kept away. Wear self-contained breathing apparatus and protective suit. Eliminate all ignition sources if safe to do so. Avoid skin contact with leaking liquid (danger of frostbite).

Ventilate the area. Vapors may travel to areas away from work site before igniting/flashing back to vapor source. Vapours are heavier than air and can cause suffocation by reducing oxygen available for breathing. Avoid accumulation of vapours in low areas. Unprotected personnel should not return until air has been

tested and determined safe. Ensure that the oxygen content is >= 19.5%.

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Environmental precautions : Prevent further leakage or spillage if safe to do so. The product evapourates readily. Discharge into the environment must be avoided.

Methods for cleaning up : Use explosion-proof equipment. No sparking tools should be used.

Ventilate the area. Allow to evapourate.

SECTION 7. HANDLING AND STORAGE

Handling

Handling : Handle with care. Wear personal protective equipment. Do not breathe vapour. Avoid contact with skin, eyes and clothing. Use only in well-ventilated areas.

Pressurized container. Protect from sunlight and do not expose to temperatures exceeding 50 °C. Follow all standard safety precautions for handling and use of compressed gas cylinders. Use authorized cylinders only. Protect cylinders from physical damage. Do not puncture or drop cylinders, expose them to open flame

or excessive heat. Do not remove screw cap until immediately ready for use. Always replace cap after use.

Advice on protection against fire and explosion : Container hazardous when empty.

Prevent the creation of flammabl e or explosive concentrations of vapour in air and avoid vapour concentration higher than the occupational exposure limits. Keep product and empty cont ainer away from heat and sources of ignition. Do not pressurize, cut, weld, br aze, solder, drill, grind or expose containers to heat or sources of ignition. Take measures to prevent the build up of electrostatic charge. Electrical equipment should be protected to the appropriate

standard. Use explosion-proof equipment. No sparking tools should be used. No smoking.

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Storage

Requirements for storage

areas and containers : Pressurized container: protec t from sunlight and do not expose to temperatures exceeding 50 °C. Do not pierce or burn, even

after use. Keep containers tightly closed in a dry, cool and well-ventilated place. Keep away from heat and sources of ignition. Storage rooms must be properly ventilated. Ensure adequate ventilation, especially in confined areas. Protect cylinders from physical damage. Store away from incompatible substances. Store in original container.

SECTION 8. EXPOSURE CONT ROLS/PERSONAL PROTECTION

Protective measures : Ensure that eyewash stations and safety showers are close to

the workstation location. Do not breathe vapour. Avoid contact with skin, eyes and clothing.

Engineering measures : Use with local exhaust ventilation.

Eye protection : Safety goggles

Hand protection : Protective gloves Gloves must be inspected prior to use. Replace when worn.

Skin and body protection : Avoid skin contact with leaking liquid (danger of frostbite). Wear suitable protective equipment.

Respiratory protection : No personal respiratory protective equipment normally required. When workers are facing conc entrations above the exposure limit they must use appropriate certified respirators. Use NIOSH approved respiratory protection.

Hygiene measures : Handle in accordance with good industrial hygiene and safety practice. Ensure adequate ventilation, especially in confined areas. When using do not eat, drink or smoke.

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Remove and wash contaminated clothing before re-use. Keep working clothes separately. Do not breathe vapour. Avoid contact with skin, eyes and clothing.

Exposure Guidelines

Components CAS-No. Value Control
parameters Upda

te Basis

2,3,3,3-Tetrafluoroprop1-ene 754-12-1 TWA :

time weighted

average (500 ppm) 2009 WEEL : US. AIHA Workplace

Environmental Exposure Level (WEEL) Guides

2,3,3,3-Tetrafluoroprop1-ene 754-12-1 TWA :

time weighted

average (500 ppm) 03 15

2010 Honeywell : Limit established by Honeywell

International Inc.

2,3,3,3-Tetrafluoroprop1-ene 754-12-1 STEL :

Short

term

exposure
limit (1,500 ppm) 03 15

2010 Honeywell : Limit established by Honeywell

International Inc.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Physical state : Liquefied gas

Color : clear

Odor : slight

pH : Note: no data available

Boiling point/boiling range : -29.4 °C

Flash point : Note: not applicable

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Evaporation rate : Note: not determined

lower flammability limit : 6 %(V)

upper flammability limit : 12.3 %(V)

Vapor pressure : 6,067 hPa at 21.1 °C(70.0 °F)
14,203 hPa at 54.4 °C(129.9 °F)

Vapor density : 4 Note: (Air = 1.0)

Density : 1.1 g/cm3 at 25 °C

Water solubility : 198.2 mg/l at 24 °C

Method: 92/69/EEC, A.6

Partition coefficient: noctanol/water : log Pow: 2.15 Method: 92/69/EEC, A.8

Ignition temperature : 405 °C Method: Auto-ignition temperature

Molecular weight : 114 g/mol

SECTION 10. STABILITY AND REACTIVITY

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Chemical stability : Stable under normal conditions.

Possibility of hazardous

reactions : Hazardous polymerisation does not occur.

Conditions to avoid : Keep away from heat and sources of ignition.

Pressurized container. Prot ect from sunlight and do not expose to temperatures exceeding 50 °C. Do not pressurize, cut, weld, br aze, solder, drill, grind or expose containers to heat or sources of ignition. Decomposes under high temperature. Some risk may be expected of corrosive and toxic decomposition products.

Incompatible materials to

avoid : Strong oxidizing agents Finely divided aluminium

Zinc Magnesium

Hazardous decomposition products : In case of fire hazardous decomposition products may be produced such as: Hydrogen fluoride Carbonyl halides

Carbon monoxide Carbon dioxide (CO2)

SECTION 11. TOXICOLOGICAL INFORMATION

Acute inhalation toxicity : LC50: > 400000 ppm Exposure time: 4 h Species: rat

Sensitisation : Cardiac sensitization Species: dogs

Result: No effects observed fo r exposures up to 12% (120,189 ppm).

Repeated dose toxicity : Species: rat Application Route: Inhalation Exposure time: 2 Weeks No-observed-effect level: 50000 ppm

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: Species: rat Application Route: Inhalation Exposure time: 4 Weeks NOAEL (No observed adverse effect level): 50000 ppm

: Species: rat Application Route: Inhalation Exposure time: 13 Weeks NOAEL (No observed adverse effect level): 50000 ppm

: Species: rabbit, male Application Route: Inhalation Exposure time: 28 d No-observed-effect level: 500 ppm

: Species: rabbit, female Application Route: Inhalation Exposure time: 28 d No-observed-effect level: 1000 ppm

: Species: mini-pig Application Route: Inhalation Exposure time: 28 d NOAEL (No observed adverse effect level): 10,000 ppm Note: (highest exposure tested).

Genotoxicity in vitro : Test Method: Ames test Result: 20% and higher, positive in TA 100 and e. coli WP2 uvrA, negative in TA98, TA100, and TA1535.

: Test Method: Chromosome aberration test in vitro Cell type: Human lymphocytes Result: negative Note: Dose 760,000 ppm

: Test Method: Chromosome aberration test in vitro Cell type: Chinese Hamster Lung Cells Result: negative

Genotoxicity in vivo : Species: mouse Cell type: Micronucleus Dose: up to 200,000 ppm (4 hour) Result: negative

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Genotoxicity in vivo : Test Me thod: Unscheduled DNA synthesis Dose: up to 50,000 ppm (4 weeks) Result: negative

Genotoxicity in vivo : Species: rat Cell type: Micronucleus Dose: up to 50,000 ppm (4 weeks) Result: negative

Reproductive toxicity : Species: rat Application Route: Inhalation exposure Exposure time: Two-generation reproductive toxicity NOAEL,parent: 50,000 ppm NOAEL,F1: 50,000 ppm NOAEL,F2: 50,000 ppm

Teratogenicity : Species: rat Dose: NOAEL (No observed adverse effect level) - 50,000

ppm

: Species: rabbit Dose: NOAEL (No observed adverse effect level) - 4,000 ppm

SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity effects

Toxicity to fish : LC50: > 197 mg/l Exposure time: 96 h Species: Cyprinus carpio (Carp)

Method: OECD Test Guideline 203

Note: No demonstrable toxic effect in saturated solution.

Toxicity to daphnia and other aquatic invertebrates : EC50: > 83 mg/l Exposure time: 48 h Species: Daphnia magna (Water flea)

Method: OECD Test Guideline 202

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Toxicity to algae : EC50: > 100 mg/l Species: Scenedesmus capricornutum (fresh water algae)

Elimination information (persistence and degradability)

Biodegradability : Result: Not readily biodegradable.

Further information on ecology

SECTION 13. DISPOSAL CONSIDERATIONS

Disposal methods : Observe all Federal, State, and Local Environmental regulations.

SECTION 14. TRANSPORT INFORMATION

DOT UN/ID No. : UN 3161 Proper shipping name : LIQUEFIED GAS, FLAMMABLE, N.O.S. ( R-1234yf)

Class 2.1 Packing group

Hazard Labels 2.1

IATA UN/ID No. : UN 3161 Description of the goods : LIQUEFI ED GAS, FLAMMABLE, N.O.S. ( R-1234yf)

Class : 2.1

Hazard Labels : 2.1 Packing instruction (cargo aircraft) : 200

IMDG UN/ID No. : UN 3161 Description of the goods : LIQUEFI ED GAS, FLAMMABLE, N.O.S. ( R-1234yf)

Class : 2.1

Hazard Labels : 2.1

EmS Number : F-D, S-U

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Marine pollutant : no

SECTION 15. REGULATORY INFORMATION

Inventories

US. Toxic Substances

Control Act : On TSCA Inventory

Australia. Industrial Chemical (Notification and Assessment) Act : Not in compliance with the inventory

: 2,3,3,3-Tetrafluoroprop-1-ene 754-12-1

Canada. Canadian

Environmental Protection Act (CEPA). Domestic Substances List (DSL) : All components of this product are on the Canadian DSL.

Japan. Kashin-Hou Law

List : On the inventory, or in compliance with the inventory

Korea. Toxic Chemical Control Law (TCCL) List : On the inventory, or in compliance with the inventory

Philippines. The Toxic

Substances and Hazardous

and Nuclear Waste Control

Act : Not in compliance with the inventory

: 2,3,3,3-Tetrafluoroprop-1-ene 754-12-1 China. Inventory of Existing

Chemical Substances : Not in compliance with the inventory

: 2,3,3,3-Tetrafluoroprop-1-ene 754-12-1 New Zealand. Inventory of Chemicals (NZIoC), as published by ERMA New

Zealand : Not in compliance with the inventory

: 2,3,3,3-Tetrafluoroprop-1-ene 754-12-1

TSCA 12B : US. Toxic Substances Control Act (TSCA) Section 12(b) Export Notification (40 CFR 707, Subpt D)

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2,3,3,3-Tetrafluoroprop-1-ene 754-12-1

National regulatory information

US. Toxic Substances Control Act (TSCA) Section 5(a)(2) Final Significant New Use Rules (SNURs) (40 CFR 721, Subpt E) :

: Issued.

: 2,3,3,3-Tetrafluoroprop-1-ene 754-12-1

SARA 302 Components : SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.

SARA 313 Components : SARA 313: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313.

SARA 311/312 Hazards : Fire Hazard

Acute Health Hazard

Sudden Release of Pressure Hazard

California Prop. 65 : This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.

New Jersey RTK : 2,3,3,3-Tetrafluoroprop-1-ene 754-12-1

Pennsylvania RTK : 2,3,3,3-Tetrafluoroprop-1-ene 754-12-1

WHMIS Classification : B1 : Flammable gas

A : Compressed Gas This product has been classified according to the hazard criteria

of the CPR and the MSDS contains all of the information required by the CPR.

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SECTION 16. OTHER INFORMATION

HMIS III NFPA

Health hazard : 0 2 Flammability : 2 2 Physical Hazard : 2 Instability : 0

Hazard rating and rating systems (e.g. HMIS® III, NFPA): This information is intended solely for the use of individuals trained in the particular system.

Further information

The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publicati on. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. Final determination of suitability of any material is the sole responsibility of the user. This information should not constitute a guarantee for any specific product properties.

Changes since the last version are highlighted in the margin. This version replaces all previous

versions.

Previous Issue Date : 06/13/2013 Prepared by Honeywell Performance Materials and Technologies Product Stewardship Group