# Patent

## Title
Organic light-emitting device

## Abstract

Provided is an organic light-emitting device including a first electrode; a second electrode facing the first electrode; and an organic layer between the first electrode and the second electrode, the organic layer including an emission layer. The emission layer includes a first compound represented by Formula 1-1 or Formula 1-2 below, a second compound represented by Formula 2 below, and a third compound represented by Formula 3 below:




where Ar1 to Ar8, R1 to R3, A, L1, L2, a1, a2, b1, b2, c1, c2, l1, and l2 are as defined in the specification.

## Background
CROSS-REFERENCE TO RELATED APPLICATION
Korean Patent Application No. 10-2014-0170823, filed on Dec. 2, 2014, in the Korean Intellectual Property Office, and entitled: “Organic Light-Emitting Device,” is incorporated by reference herein in its entirety.
BACKGROUND
1. Field
Embodiments relate to an organic light-emitting device.
2. Description of the Related Art
Organic light emitting devices are self-emission devices that have wide viewing angles, high contrast ratios, short response times, and excellent luminance, driving voltage, and response speed characteristics, and produce full-color images.
The organic light-emitting device may include an anode, and a hole transport region, an emission layer, an electron transport region, and a cathode, which are sequentially disposed. Holes provided from the anode may move toward the emission layer through the hole transport region, and electrons provided from the cathode may move toward the emission layer through the electron transport region. Carriers, such as holes and electrons, are recombined in the emission layer to produce excitons. The excitors change from an excited state to a ground state, generating light.
SUMMARY
Embodiments are directed to an organic light-emitting device that includes a first electrode, a second electrode facing the first electrode, and an organic layer between the first electrode and the second electrode, the organic layer including an emission layer. The emission layer includes a first compound represented by Formula 1-1 or Formula 1-2 below, a second compound represented by Formula 2, and a third compound represented by Formula 3.




In the formulae above,
L1 and L2 are each independently selected from a substituted or unsubstituted C6-C40 arylene group,
A is a substituted or unsubstituted C6-C40 arylene group, a substituted or unsubstituted divalent C6-C40 non-aromatic hetero condensed polycyclic group, or a combination of these groups and a styrylene group,
Ar1 to Ar8 may be each independently a substituted or unsubstituted C6-C40 aryl group,
R1 to R4 may be each independently selected from a deuterium atom, a halogen atom, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid or a salt thereof, a sulfonic acid or a salt thereof, a phosphoric acid or a salt thereof, a substituted or unsubstituted C1-C20 alkyl group, a substituted or unsubstituted C2-C20 alkenyl group, a substituted or unsubstituted C2-C20 alkynyl group, a substituted or unsubstituted C1-C20 alkoxy group, a substituted or unsubstituted C3-C10 cycloalkyl group, a substituted or unsubstituted C1-C10 heterocycloalkyl group, a substituted or unsubstituted C3-C10 cycloalkenyl group, a substituted or unsubstituted C1-C10 heterocycloalkenyl group, a substituted or unsubstituted C6-C40 aryl group, a substituted or unsubstituted C1-C40 heteroaryl group, a substituted or unsubstituted C5-C40 aryloxy group, a substituted or unsubstituted C5-C40 arylthio group, a substituted or unsubstituted monovalent C6-C40 non-aromatic condensed polycyclic group(non-aromatic condensed polycyclic group), a substituted or unsubstituted monovalent C6-C40 non-aromatic hetero condensed polycyclic group(non-aromatic hetero condensed polycyclic group), —N(Q1)(Q2), —P(═O)(Q3)(Q4), —Si(Q5)(Q6)(Q7), —Ge(Q5)(Q6)(Q7), and —B(Q8)(Q9)(Q1 to Q9 are each independently a hydrogen atom, a C1-C20 alkyl group, or a C6-C40 aryl group);
at least one of substituents of the substituted C1-C20 alkyl group, substituted C2-C20 alkenyl group, substituted C2-C20 alkynyl group, substituted C1-C20 alkoxy group, substituted C3-C10 cycloalkyl group, substituted C1-C10 heterocycloalkyl group, substituted C3-C10 cycloalkenyl group, substituted C1-C10 heterocycloalkenyl group, substituted C6-C40 aryl group, substituted C1-C40 heteroaryl group, substituted C5-C40 aryloxy group, substituted C5-C40 arylthio group, substituted monovalent C6-C40 non-aromatic condensed polycyclic group, substituted monovalent C6-C40 non-aromatic hetero condensed polycyclic group, and substituted C6-C40 arylene group may be selected from:
a deuterium atom, a halogen atom, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid or a salt thereof, a sulfonic acid or a salt thereof, a phosphoric acid or a salt thereof, a C1-C20 alkyl group, a C2-C20 alkenyl group, a C2-C20 alkynyl group, a C1-C20 alkoxy group, a C3-C10 cycloalkyl group, a C1-C10 heterocycloalkyl group, a C3-C10 cycloalkenyl group, a C1-C10 heterocycloalkenyl group, a C6-C40 aryl group, a C1-C40 heteroaryl group, a C5-C40 aryloxy group, a C5-C40 arylthio group, monovalent C6-C40 non-aromatic condensed polycyclic group, monovalent C6-C40 non-aromatic hetero condensed polycyclic group, —N(Q11)(Q12), —Si(Q13)(Q14)(Q15), —Ge(Q13)(Q14)(Q15), and B(Q16)(Q17) (Q11 to Q17 are each independently selected from a hydrogen atom, a C1-C20 alkyl group, and a C6-C40 aryl group),
a1 and a2 are each independently an integer from 0 to 4;
b1 and b2 are each independently 1 or 2;
c1 and c2 are each independently an integer from 0 to 7; and
l1 and l2 are each independently an integer from 0 to 3.



BRIEF DESCRIPTION OF THE DRAWING
Features will become apparent to those of skill in the art by describing in detail exemplary embodiments with reference to the attached drawing in which:
FIG. 1 illustrates a schematic cross-sectional view of an organic light-emitting device according to an embodiment.



DETAILED DESCRIPTION
Example embodiments will now be described more fully hereinafter with reference to the accompanying drawings; however, they may be embodied in different forms and should not be construed as limited to the embodiments set forth herein. Rather, these embodiments are provided so that this disclosure will be thorough and complete, and will fully convey exemplary implementations to those skilled in the art.
In the drawing FIGURES, the dimensions of layers and regions may be exaggerated for clarity of illustration. It will also be understood that when a layer or element is referred to as being “on” another layer or substrate, it can be directly on the other layer or substrate, or intervening layers may also be present. Further, it will be understood that when a layer is referred to as being “between” two layers, it can be the only layer between the two layers, or one or more intervening layers may also be present. Like reference numerals refer to like elements throughout.
FIG. 1 illustrates a schematic cross-sectional view of an organic light-emitting device 10 according to an embodiment.
Referring to FIG. 1, the organic light-emitting device 10 includes a first electrode 110, an organic layer 150, and a second electrode 190.
A substrate may be additionally disposed under the first electrode 110 or above the second electrode 190. The substrate may be a substrate with excellent mechanical strength, thermal stability, transparency, surface smoothness, ease of handling, and waterproofness. For example, the substrate may be a glass substrate or a transparent plastic substrate.
The first electrode 110 may be formed by depositing or sputtering a material for forming the first electrode on the substrate. When the first electrode 110 is an anode, the material for the first electrode 110 may be selected from materials with a high work function such that holes be easily injected. The first electrode 110 may be a reflective electrode or a transmissive electrode. The material for the first electrode 110 may be a transparent and highly conductive material. Examples of such a material include indium tin oxide (ITO), indium zinc oxide (IZO), tin oxide (SnO2), and zinc oxide (ZnO). When the first electrode 110 is a semi-transmissive electrode or a reflective electrode, at least one of magnesium (Mg), aluminum(Al), aluminum-lithium (Al—Li), calcium (Ca), magnesium-indium(Mg—In), magnesium-silver (Mg—Ag) may be used as a material for forming the first electrode 110, as examples. The first electrode 110 may have a single-layer structure, or a multi-layer structure including two or more layers. For example, the first electrode 110 may have a three-layered structure of ITO/Ag/ITO.
An organic layer 150 may be disposed on the first electrode 110. The organic layer 150 may include an emission layer. The organic layer 150 may include a hole transport region disposed between the first electrode 110 and the emission layer and an electron transport region disposed between the emission layer and the second electrode 190.
The hole transport region may include at least one selected from a hole injection layer (HIL), a hole transport layer (HTL), a buffer layer, and an electron blocking layer (EBL). The electron transport region may include at least one selected from a hole blocking layer (HBL), an electron transport layer (ETL), and an electron injection layer (EIL).
The hole transport region may have a single-layered structure formed of a single material, a single-layered structure formed of a plurality of different materials, or a multi-layered structure having a plurality of layers formed of a plurality of different materials.
For example, the hole transport region may have a single-layered structure formed of a plurality of different materials, or a structure of hole injection layer/hole transport layer, a structure of hole injection layer/hole transport layer/buffer layer, a structure of hole injection layer/buffer layer, a structure of hole transport layer/buffer layer, a structure of hole injection layer/hole transport layer/electron blocking layer, or a structure of a hole transport layer/electron blocking layer, wherein layers of each structure are sequentially stacked from the first electrode 110 in this stated order.
When the hole transport region includes a hole injection layer, the hole injection layer may be formed on the first electrode 110 by a suitable method, such as vacuum deposition, spin coating casting, a Langmuir-Blodgett (LB) method, ink-jet printing, laser-printing, or laser-induced thermal imaging.
When a hole injection layer is formed by vacuum deposition, for example, the vacuum deposition may be performed at a deposition temperature of about 100 to about 500° C., at a vacuum degree of about 10−8 to about 10−3 torr, and at a deposition rate of about 0.01 to about 100 Å/sec in consideration of a compound for a hole injection layer to be deposited, and the structure of a hole injection layer to be formed.
When a hole injection layer is formed by spin coating, the spin coating may be performed at a coating rate of about 2,000 rpm to about 5,000 rpm, and at a temperature of about 80° C. to 200° C. in consideration of a compound for a hole injection layer to be deposited, and the structure of a hole injection layer to be formed.
When the hole transport region includes a hole transport layer, the hole transport layer may be formed on either the first electrode 130 or the hole injection layer by using a suitable method, such as vacuum deposition, spin coating, casting, a LB method, ink-jet printing, laser-printing, or laser-induced thermal imaging. When the hole transport layer is formed by vacuum deposition or spin coating, deposition and coating conditions for the hole transport layer may be the same as the deposition and coating conditions for the hole injection layer.
The hole transport region may include at least one selected from 4,4′,4′′-tris(N-3-methylphenyl-N-phenylamino)triphenylamine (m-MTDATA), 4,4′,4′′-tris(N,N-diphenyl-amino)triphenylamine (TDATA), 4,4′,4′′-tris[2-naphthyl(phenyl)amino]triphenylamine(2-TNATA), N,N′-bis(naphthalen-1-yl)-N,N′-bis(phenyl)-benzidine (NPB), N,N′-bis(naphthalen-2-yl)-N,N′-bis(phenyl)-benzidine (β-NPB), N,N′-bis(naphthalen-1-yl)-N,N′-bis(phenyl)-2,2′-dimethylbenzidine (α-NPD), N,N′-bis(3-methylphenyl)-N,N′-bis(phenyl)-benzidine (TPD), Spiro-TPD, Spiro-NPB, di-[4-(N,N-ditolyl-amino)-phenyl]cyclohexane (TAPC), N,N,N′,N′-tetrakis(3-methylphenyl)-3,3′-dimethylbenzidine (HMTPD), 4,4′,4′′-tris(N-carbazolyl)triphenylamine (TCTA), polyaniline/dodecylbenzenesulfonic acid (Pani/DBSA), poly(3,4-ethylenedioxythiophene)/poly(4-styrenesulfonate) (PEDOT/PSS), polyaniline/camphor sulfonic acid (Pani/CSA), (polyaniline)/poly(4-styrenesulfonate) (PANI/PSS), a compound represented by Formula 201, and a compound represented by Formula 202:













In Formulae 201 and 202,
L201 to L205 may be each independently selected from a substituted or unsubstituted C3-C10 cycloalkylene group, a substituted or unsubstituted C1-C10 heterocycloalkylene group, a substituted or unsubstituted C3-C10 cycloalkenylene group, a substituted or unsubstituted C1-C10 heterocycloalkenylene group, a substituted or unsubstituted C6-C60 arylene group, a substituted or unsubstituted C1-C60 heteroarylene group, a substituted or unsubstituted divalent non-aromatic condensed polycyclic group, and a substituted or unsubstituted divalent non-aromatic condensed heteropolycyclic group,
at least one substituent of the substituted C3-C10 cycloalkylene group, the substituted C1-C10 heterocycloalkylene group, the substituted C3-C10 cycloalkenylene group, the substituted C1-C10 heterocycloalkenylene group, the substituted C6-C60 arylene group, the substituted C1-C60 heteroarylene group, the substituted divalent non-aromatic condensed polycyclic group, and the substituted divalent non-aromatic condensed heteropolycyclic group may be selected from:
a deuterium atom, —F, —Cl, —Br, —I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid group or a salt thereof, a sulfonic acid group or a salt thereof, a phosphoric acid group or a salt thereof, a C1-C60 alkyl group, a C2-C60 alkenyl group, a C2-C60 alkynyl group, and a C1-C60 alkoxy group;
a C1-C60 alkyl group, a C2-C60 alkenyl group, a C2-C60 alkynyl group, and a C1-C60 alkoxy group, each substituted with at least one selected from a deuterium atom, —F, —Cl, —Br, —I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid or a salt thereof, a sulfonic acid or a salt thereof, a phosphoric acid or a salt thereof, a C3-C10 cycloalkyl group, a C1-C10 heterocycloalkyl group, a C3-C10 cycloalkenyl group, a C1-C10 heterocycloalkenyl group, a C6-C60 aryl group, a C6-C60 aryloxy group, a C6-C60 arylthio group, a C1-C60 heteroaryl group, a monovalent non-aromatic condensed polycyclic group, a monovalent non-aromatic condensed heteropolycyclic group, —N(Q201)(Q202), —Si(Q203)(Q204)(Q205), and —B(Q206)(Q207);
a C3-C10 cycloalkyl group, a C1-C10 heterocycloalkyl group, a C3-C10 cycloalkenyl group, a C1-C10 heterocycloalkenyl group, a C6-C60 aryl group, a C6-C60 aryloxy group, a C6-C60 arylthio group, a C1-C60 heteroaryl group, a monovalent non-aromatic condensed polycyclic group, and a monovalent non-aromatic condensed heteropolycyclic group;
a C3-C10 cycloalkyl group, a C1-C10 heterocycloalkyl group, a C3-C10 cycloalkenyl group, a C1-C10 heterocycloalkenyl group, a C6-C60 aryl group, a C6-C60 aryloxy group, a C6-C60 arylthio group, a C1-C60 heteroaryl group, a monovalent non-aromatic condensed polycyclic group, or a monovalent non-aromatic condensed heteropolycyclic group, each substituted with at least one selected from a deuterium atom. —F, —Cl, —Br, —I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid or a salt thereof, a sulfonic acid or a salt thereof, a phosphoric acid or a salt thereof, a C1-C60 alkyl group, a C2-C60 alkenyl group, a C2-C60 alkynyl group, a C1-C60 alkoxy group, a C3-C10 cycloalkyl group, a C6-C60 heterocycloalkyl group, a C3-C10 cycloalkenyl group, a C1-C10 heterocycloalkenyl group, a C6-C60 aryl group, a C6-C60 aryloxy group, a C6-C60 arylthio group, a C1-C60 heteroaryl group, a monovalent non-aromatic condensed polycyclic group, a monovalent non-aromatic condensed heteropolycyclic group, —N(Q211)(Q212), —Si(Q213)(Q214)(Q215), and —B(Q216)(Q217); and
—N(Q221)(Q222), —Si(Q223)(Q224)(Q225), and —B(Q226)(Q227);
xa1 to xa4 may be each independently selected from 0, 1, 2, and 3;
xa5 may be selected from 1, 2, 3, 4, and 5; and
R201 to R205 may each independently be selected from a C1-C60 alkyl group, a C2-C60 alkenyl group, a C2-C60 alkynyl group, and a C1-C60 alkoxy group;
a C1-C60 alkyl group, a C2-C60 alkenyl group, a C2-C60 alkynyl group, and a C1-C6 alkoxy group, each substituted with at least one selected from a deuterium atom, —F, —Cl, —Br, —I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid or a salt thereof a sulfonic acid or a salt thereof, a phosphoric acid or a salt thereof, a C3-C10 cycloalkyl group, a C1-C10 heterocycloalkyl group, a C3-C10 cycloalkenyl group, a C1-C10 heterocycloalkenyl group, a C6-C60 aryl group, a C6-C60 aryloxy group, a C6-C60 arylthio group, a C1-C60 heteroaryl group, a monovalent non-aromatic condensed polycyclic group, a monovalent non-aromatic condensed heteropolycyclic group, —N(Q231)(Q232), —Si(Q233)(Q234)(Q235), and —B(Q236)(Q237);
a C3-C10 cycloalkyl group, a C1-C10 heterocycloalkyl group, a C3-C10 cycloalkenyl group, a C1-C10 heterocycloalkenyl group, a C6-C60 aryl group, a C6-C60 aryloxy group, a C6-C60 arylthio group, a C1-C60 heteroaryl group, a monovalent non-aromatic condensed polycyclic group, and a monovalent non-aromatic condensed heteropolycyclic group; and
a C3-C10 cycloalkyl group, a C1-C10 heterocycloalkyl group, a C3-C10 cycloalkenyl group, a C1-C10 heterocycloalkenyl group, a C6-C60 aryl group, a C6-C60 aryloxy group, a C6-C60 arylthio group, a C1-C60 heteroaryl group, a monovalent non-aromatic condensed polycyclic group, and a monovalent non-aromatic condensed heteropolycyclic group, each substituted with at least one selected from a deuterium atom, —F, —Cl, —Br, —I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid or a salt thereof, a sulfonic acid or a salt thereof, a phosphoric acid or a salt thereof, a C1-C60 alkyl group, a C2-C60 alkenyl group, a C2-C60 alkynyl group, a C1-C60 alkoxy group, a C3-C10 cycloalkyl group, a C1-C10 heterocycloalkyl group, a C3-C10 cycloalkenyl group, a C1-C10 heterocycloalkenyl group, a C6-C60 aryl group, a C6-C60 aryloxy group, a C6-C60 arylthio group, a C1-C60 heteroaryl group, a monovalent non-aromatic condensed polycyclic group, a monovalent non-aromatic condensed heteropolycyclic group, —N(Q241)(Q242), —Si(Q243)(Q244)(Q245), and —B(Q246)(Q247); and
Q201 to Q207, Q211 to Q217, Q221 to Q227, Q231 to Q237, and Q241 to Q247 may be each independently selected from a hydrogen atom, a deuterium atom. —F. —Cl, —Br, —I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid or a salt thereof, a sulfonic acid or a salt thereof, a phosphoric acid or a salt thereof, a C1-C60 alkyl group, a C2-C60 alkenyl group, a C2-C60 alkynyl group, and a C1-C60 alkoxy group;
a C1-C60 alkyl group, a C2-C60 alkenyl group, a C2-C60 alkynyl group, and a C1-C60 alkoxy group, each substituted with at least one selected from a deuterium atom, —F, —Cl, —Br, —I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid or a salt thereof, a sulfonic acid or a salt thereof, a phosphoric acid or a salt thereof, a C3-C10 cycloalkyl group, a C1-C10 heterocycloalkyl group, a C3-C10 cycloalkenyl group, a C1-C10 heterocycloalkenyl group, a C6-C60 aryl group, a C6-C60 aryloxy group, a C6-C60 arylthio group, a C1-C60 heteroaryl group, a monovalent non-aromatic condensed polycyclic group, and a monovalent non-aromatic condensed heteropolycyclic group;
a C3-C10 cycloalkyl group, a C1-C10 heterocycloalkyl group, a C3-C10 cycloalkenyl group, a C1-C10 heterocycloalkenyl group, a C6-C60 aryl group, a C6-C60 aryloxy group, a C6-C60 arylthio group, a C1-C60 heteroaryl group, a monovalent non-aromatic condensed polycyclic group, and a monovalent non-aromatic condensed heteropolycyclic group; and
a C3-C10 cycloalkyl group, a C1-C10 heterocycloalkyl group, a C3-C10 cycloalkenyl group, a C1-C10 heterocycloalkenyl group, a C6-C60 aryl group, a C6-C60 aryloxy group, a C6-C60 arylthio group, a C1-C60 heteroaryl group, a monovalent non-aromatic condensed polycyclic group, and a monovalent non-aromatic condensed heteropolycyclic group, each substituted with at least one selected from a deuterium atom. —F, —Cl, —Br, —I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid or a salt thereof, a sulfonic acid or a salt thereof, a phosphoric acid or a salt thereof, a C1-C60 alkyl group, a C2-C60 alkenyl group, a C2-C60 alkynyl group, a C1-C60 alkoxy group, a C3-C10 cycloalkyl group, a C1-C10 heterocycloalkyl group, a C3-C10 cycloalkenyl group, a C1-C10 heterocycloalkenyl group, a C6-C60 aryl group, a C6-C60 aryloxy group, a C6-C60 arylthio group, a C1-C60 heteroaryl group, a monovalent non-aromatic condensed polycyclic group, and a monovalent non-aromatic condensed heteropolycyclic group.
In some embodiments, in Formulae 201 and 202,
L201 to L205 may be each independently selected from a phenylene group, a naphthylene group, a fluorenylene group, a spiro-fluorenylene group, a benzofluorenylene group, a dibenzofluorenylene group, a phenanthrenylene group, anthrylene group, a pyrenylene group, a chrysenylene group, a pyridinylene group, a pyrazinylene group, a pyrimidinylene group, a pyridazinylene group, a quinolinylene group, an isoquinolinylene group, a quinoxalinylene group, a quinazolinylene group, a carbazolylene group, and a triazinylene group; and
a phenylene group, a naphthylene group, a fluorenylene group, a spiro-fluorenylene group, a benzofluorenylene group, a dibenzofluorenylene group, a phenanthrenylene group, an anthrylene group, a pyrenylene group, a chrysenylene group, a pyridinylene group, a pyrazinylene group, a pyrimidinylene group, a pyridazinylene group, a quinolinylene group, an isoquinolinylene group, a quinoxalinylene group, a quinazolinylene group, a carbazolylene group, and a triazinylene group, each substituted with at least one selected from a deuterium atom, —F, —Cl, —Br, —I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid or a salt thereof, a sulfonic acid or a salt thereof, a phosphoric acid or a salt thereof, a C1-C20 alkyl group, a C1-C20 alkoxy group, a phenyl group, a naphthyl group, a fluorenyl group, a spiro-fluorenyl group, a benzofluorenyl group, a dibenzofluorenyl group, a phenanthrenyl group, an anthryl group, a pyrenyl group, a chrysenyl group, a pyridyl group, a pyrazinyl group, a pyrimidinyl group, a pyridazinyl group, an isoindolyl group, a quinolyl group, an isoquinolyl group, a quinoxalinyl group, a quinazolinyl group, a carbazolyl group, and a triazinyl group;
xa1 to xa4 may be each independently 0, 1, or 2; and
xa5 may be 1, 2, or 3;
R201 to R205 may be each independently selected from a phenyl group, a naphthyl group, a fluorenyl group, a spiro-fluorenyl group, a benzofluorenyl group, a dibenzofluorenyl group, a phenanthrenyl group, an anthryl group, a pyrenyl group, a chrysenyl group, a pyridyl group, a pyrazinyl group, a pyrimidinyl group, a pyridazinyl group, a quinolyl group, an isoquinolyl group, a quinoxalinyl group, a quinazolinyl group, a carbazolyl group, and a triazinyl group; and
a phenyl group, a naphthyl group, a fluorenyl group, a spiro-fluorenyl group, a benzofluorenyl group, a dibenzofluorenyl group, a phenanthrenyl group, an anthryl group, a pyrenyl group, a chrysenyl group, a pyridyl group, a pyrazinyl group, a pyrimidinyl group, a pyridazinyl group, a quinolyl group, an isoquinolyl group, a quinoxalinyl group, a quinazolinyl group, a carbazolyl group, and a triazinyl group, each substituted with at least one selected from a deuterium atom, —F, —Cl, —Br, —I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid or a salt thereof, a sulfonic acid or a salt thereof, a phosphoric acid or a salt thereof, a C1-C20 alkyl group, a C1-C20 alkoxy group, a phenyl group, a naphthyl group, an azulenyl group, a fluorenyl group, a spiro-fluorenyl group, a benzofluorenyl group, a dibenzofluorenyl group, a phenanthrenyl group, an anthryl group, a pyrenyl group, a chrysenyl group, a pyridyl group, a pyrazinyl group, a pyrimidinyl group, a pyridazinyl group, a quinolyl group, an isoquinolyl group, a quinoxalinyl group, a quinazolinyl group, a carbazolyl group, and a triazinyl group.
The compound represented by Formula 201 may be represented by Formula 201A below:




For example, the compound represented by Formula 201 may be represented by Formula 201A-1 below:




For example, the compound represented by Formula 202 may be represented by Formula 202A below:




Descriptions of L201 to L203, xa1 to xa3, xa5, and R202 to R204 in Formulae 201A, 201A-1, and 202A are the same as described above, and descriptions of R211 and R212 are the same as the description of R203,
R213 to R217 may be each independently selected from a hydrogen atom, a deuterium atom, —F, —Cl, —Br, —I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid or a salt thereof, a sulfonic acid or a salt thereof, a phosphoric acid or a salt thereof, a C1-C60 alkyl group, a C2-C60 alkenyl group, a C2-C60 alkynyl group, a C1-C60 alkoxy group, a C3-C10 cycloalkyl group, a C1-C10 heterocycloalkyl group, a C3-C10 cycloalkenyl group, a C1-C10 heterocycloalkenyl group, a C6-C60 aryl group, a C6-C60 aryloxy group, a C6-C60 arylthio group, a C1-C60 heteroaryl group, a monovalent non-aromatic condensed polycyclic group, and a monovalent non-aromatic condensed heteropolycyclic group.
In some embodiments. L201 to L203 in Formulae 201A, 201A-1, and 202A may be each independently selected from a phenylene group, a naphthylene group, a fluorenylene group, a spiro-fluorenylene group, a benzofluorenylene group, a dibenzofluorenylene group, a phenanthrenylene group, anthrylene group, a pyrenylene group, a chrysenylene group, a pyridinylene group, a pyrazinylene group, a pyrimidinylene group, a pyridazinylene group, a quinolinylene group, an isoquinolinylene group, a quinoxalinylene group, a quinazolinylene group, a carbazolylene group, and a triazinylene group; and
a phenylene group, a naphthylene group, a fluorenylene group, a spiro-fluorenylene group, a benzofluorenylene group, a benzofluorenylene group, a phenanthrenylene group, an anthrylene group, a pyrenylene group, a chrysenylene group, a pyridinylene group, a pyrazinylene group, a pyrimidinylene group, a pyridazinylene group, a quinolinylene group, an isoquinolinylene group, a quinoxalinylene group, a quinazolinylene group, a carbazolylene group and a triazinylene group, each substituted with at least one selected from a deuterium atom, —F, —Cl, —Br, —I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid or a salt thereof, a sulfonic acid or a salt thereof, a phosphoric acid or a salt thereof, a C1-C20 alkyl group, a C1-C20 alkoxy group, a phenyl group, a naphthyl group, a fluorenyl group, a spiro-fluorenyl group, a benzofluorenyl group, a dibenzofluorenyl group, a phenanthrenyl group, an anthryl group, a pyrenyl group, a chrysenyl group, a pyridyl group, a pyrazinyl group, a pyrimidinyl group, a pyridazinyl group, a quinolyl group, an isoquinolyl group, a quinoxalinyl group, a quinazolinyl group, a carbazolyl group, and a triazinyl group;
xa1 to xa3 may be each independently 0 or 1;
R203, R211, and R212 may be each independently selected from a phenyl group, a naphthyl group, a fluorenyl group, a spino-fluorenyl group, a benzofluorenyl group, a dibenzofluorenyl group, a phenanthrenyl group, an anthryl group, a pyrenyl group, a chrysenyl group, a pyridyl group, a pyrazinyl group, a pyrimidinyl group, a pyridazinyl group, a quinolyl group, an isoquinolyl group, a quinoxalinyl group, a quinazolinyl group, a carbazolyl group, and a triazinyl group; and
a phenyl group, a naphthyl group, a fluorenyl group, a spiro-fluorenyl group, a benzofluorenyl group, a dibenzofluorenyl group, a phenanthrenyl group, an anthryl group, a pyrenyl group, a chrysenyl group, a pyridyl group, a pyrazinyl group, a pyrimidinyl group, a pyridazinyl group, a quinolyl group, an isoquinolyl group, a quinoxalinyl group, a quinazolinyl group, a carbazolyl group, and a triazinyl group, each substituted with at least one selected from a deuterium atom, —F, —Cl, —Br, —I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid or a salt thereof, a sulfonic acid or a salt thereof, a phosphoric acid or a salt thereof, a C1-C20 alkyl group, a C1-C20 alkoxy group, a phenyl group, a naphthyl group, a fluorenyl group, a spiro-fluorenyl group, a benzofluorenyl group, a dibenzofluorenyl group, a phenanthrenyl group, an anthryl group, a pyrenyl group, a chrysenyl group, a pyridyl group, a pyrazinyl group, a pyrimidinyl group, a pyridazinyl group, a quinolyl group, an isoquinolyl group, a quinoxalinyl group, a quinazolinyl group, a carbazolyl group, and a triazinyl group;
R213 and R214 may be each independently selected from a C1-C20 alkyl group and a C1-C20 alkoxy group;
a C1-C20 alkyl group and a C1-C20 alkoxy group, each substituted with at least one selected from a deuterium atom, —F, —Cl, —Br, —I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid or a salt thereof, a sulfonic acid or a salt thereof, a phosphoric acid or a salt thereof, a phenyl group, a naphthyl group, a fluorenyl group, a spiro-fluorenyl group, a benzofluorenyl group, a dibenzofluorenyl group, a phenanthrenyl group, an anthryl group, a pyrenyl group, a chrysenyl group, a pyridyl group, a pyrazinyl group, a pyrimidinyl group, a pyridazinyl group, a quinolyl group, an isoquinolyl group, a quinoxalinyl group, a quinazolinyl group, a carbazolyl group, and a triazinyl group;
a phenyl group, a naphthyl group, a fluorenyl group, a spiro-fluorenyl group, a benzofluorenyl group, a dibenzofluorenyl group, a phenanthrenyl group, an anthryl group, a pyrenyl group, a chrysenyl group, a pyridyl group, a pyrazinyl group, a pyrimidinyl group, a pyridazinyl group, a quinolyl group, an isoquinolyl group, a quinoxalinyl group, a quinazolinyl group, a carbazolyl group, and a triazinyl group; and
a phenyl group, a naphthyl group, a fluorenyl group, a spiro-fluorenyl group, a benzofluorenyl group, a dibenzofluorenyl group, a phenanthrenyl group, an anthryl group, a pyrenyl group, a chrysenyl group, a pyridyl group, a pyrazinyl group, a pyrimidinyl group, a pyridazinyl group, a quinolyl group, an isoquinolyl group, a quinoxalinyl group, a quinazolinyl group, a carbazolyl group, and a triazinyl group, each substituted with at least one selected from a deuterium atom, —F, —Cl, —Br, —I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid or a salt thereof, a sulfonic acid or a salt thereof, a phosphoric acid or a salt thereof a C1-C20 alkyl group, a C1-C20 alkoxy group, a phenyl group, a naphthyl group, a fluorenyl group, a spiro-fluorenyl group, a benzofluorenyl group, a dibenzofluorenyl group, a phenanthrenyl group, an anthryl group, a pyrenyl group, a chrysenyl group, a pyridyl group, a pyrazinyl group, a pyrimidinyl group, a pyridazinyl group, a quinolyl group, an isoquinolyl group, a quinoxalinyl group, a quinazolinyl group, a carbazolyl group, and a triazinyl group;
R215 and R217 may be each independently selected from a hydrogen atom, a deuterium atom, —F, —Br, —I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid or a salt thereof, a sulfonic acid or a salt thereof, and a phosphoric acid or a salt thereof,
a C1-C20 alkyl group and a C1-C20 alkoxy group;
a C1-C20 alkyl group and a C1-C20 alkoxy group, each substituted with at least one selected from a deuterium atom, —F, —Br, —I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid or a salt thereof, a sulfonic acid or a salt thereof, a phosphoric acid or a salt thereof, a phenyl group, a naphthyl group, a fluorenyl group, a Spiro-fluorenyl group, a benzofluorenyl group, a dibenzofluorenyl group, a phenanthrenyl group, an anthryl group, a pyrenyl group, a chrysenyl group, a pyridyl group, a pyrazinyl group, a pyrimidinyl group, a pyridazinyl group, a quinolyl group, an isoquinolyl group, a quinoxalinyl group, a quinazolinyl group, a carbazolyl group, and a triazinyl group;
a phenyl group, a naphthyl group, a fluorenyl group, a spiro-fluorenyl group, a benzofluorenyl group, a dibenzofluorenyl group, a phenanthrenyl group, an anthryl group, a pyrenyl group, a chrysenyl group, a pyridyl group, a pyrazinyl group, a pyrimidinyl group, a pyridazinyl group, a quinolyl group, an isoquinolyl group, a quinoxalinyl group, a quinazolinyl group, and a triazinyl group; and
a phenyl group, a naphthyl group, a fluorenyl group, a spiro-fluorenyl group, a benzofluorenyl group, a dibenzofluorenyl group, a phenanthrenyl group, an anthryl group, a pyrenyl group, a chrysenyl group, a pyridyl group, a pyrazinyl group, a pyrimidinyl group, a pyridazinyl group, a quinolyl group, an isoquinolyl group, a quinoxalinyl group, a quinazolinyl group, a carbazolyl group, and a triazinyl group, each substituted with at least one selected from a deuterium atom, —F, —Cl, —Br, —I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid or a salt thereof, a sulfonic acid or a salt thereof, a phosphoric acid or a salt thereof, a C1-C20 alkyl group, a C1-C20 alkoxy group, a phenyl group, a naphthyl group, a fluorenyl group, a spiro-fluorenyl group, a benzofluorenyl group, a dibenzofluorenyl group, a phenanthrenyl group, an anthryl group, a pyrenyl group, a chrysenyl group, a pyridyl group, a pyrazinyl group, a pyrimidinyl group, a pyridazinyl group, a quinolyl group, an isoquinolyl group, a quinoxalinyl group, a quinazolinyl group, and a triazinyl group; and
xa5 is 1 or 2.
R213 and R214 in Formulae 201A, and 201A-1 may bind to each other to form a saturated or unsaturated ring.
The compound represented by Formula 201, and the compound represented by Formula 202 may each include compounds HT1 to HT20 illustrated below.



















A thickness of the hole transport region may be in a range of about 100 Å to about 10,000 Å, for example, about 100 Å to about 1,000 Å. When the hole transport region includes both a hole injection layer and a hole transport layer, a thickness of the hole injection layer may be in a range of about 100 Å to about 10,000 Å, for example, about 100 Å to about 1,000 Å, and a thickness of the hole transport layer may be in a range of about 50 Å to about 2,000 Å, for example about 100 Å to about 1,500 Å. When the thicknesses of the hole transport region, the hole injection layer, and the hole transport layer are within these ranges, satisfactory hole transporting characteristics may be obtained without a substantial increase in driving voltage.
The hole transport region may further include, in addition to these materials, a charge-generation material for the improvement of conductive properties. The charge-generation material may be homogeneously or non-homogeneously dispersed in the hole transport region.
The charge-generation material may be, for example, a p-dopant. Examples of the p-dopant are a quinone derivative, such as tetracyanoquinodimethane (TCNQ) and tetrafluorotetracyanoquinodimethane (F4-TCNQ); a metal oxide, such as a tungsten oxide and a molybdenum oxide; and 1,4,5,8,9,11-hexaazatriphenylene-hexacarbonitrile (HATCN) illustrated below.




The hole transport region may further include, in addition to the hole injection layer, and the hole transport layer, at least one layer selected from a buffer layer and an electron blocking layer. The buffer layer may compensate for an optical resonance distance according to a wavelength of light emitted from the emission layer. Accordingly, light-emission efficiency of a formed organic light-emitting device may be improved. For use as a material included in the buffer layer, materials that are included in the hole transport region may be used. The electron blocking layer may help prevent injection of electrons from the electron transport region. For example, a material for the electron blocking layer may be mCP.




An emission layer may be formed on the first electrode 110 or the hole transport region by using a suitable, such as vacuum deposition, spin coating, casting, a LB method, ink-jet printing, laser-printing, or laser-induced thermal imaging. When an emission layer is formed by vacuum deposition or spin coating, deposition and coating conditions for the emission may be the same as those for the hole injection layer.
The emission layer may include a first compound represented by Formula 1-1 or Formula 1-2 below, a second compound represented by Formula 2, and a third compound represented by Formula 3. The first compound may be a host, the second compound may be a dopant, and the third compound may be a hole transport material.
The emission layer may emit blue light.




In Formulae 1-1, 1-2, 2, and 3,
L1 and L2 may each be independently selected from a substituted or unsubstituted C6-C40 arylene group,
A may be a substituted or unsubstituted C6-C40 arylene group, a substituted or unsubstituted divalent C6-C40 non-aromatic hetero condensed polycyclic group, or a combination of these groups and a styrylene group,
Ar1 to Ar8 may be each independently a substituted or unsubstituted C6-C40 aryl group,
R1 to R4 may be each independently selected from a deuterium atom, a halogen atom, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid or a salt thereof, a sulfonic acid or a salt thereof, a phosphoric acid or a salt thereof, a substituted or unsubstituted C1-C20 alkyl group, a substituted or unsubstituted C2-C20 alkenyl group, a substituted or unsubstituted C2-C20 alkynyl group, a substituted or unsubstituted C1-C20 alkoxy group, a substituted or unsubstituted C3-C10 cycloalkyl group, a substituted or unsubstituted C1-C10 heterocycloalkyl group, a substituted or unsubstituted C3-C10 cycloalkenyl group, a substituted or unsubstituted C1-C10 heterocycloalkenyl group, a substituted or unsubstituted C6-C40 aryl group, a substituted or unsubstituted C1-C40 heteroaryl group, a substituted or unsubstituted C5-C40 aryloxy group, a substituted or unsubstituted C5-C40 arylthio group, a substituted or unsubstituted monovalent C6-C40 non-aromatic condensed polycyclic group(non-aromatic condensed polycyclic group), a substituted or unsubstituted monovalent C6-C40 non-aromatic hetero condensed polycyclic group(non-aromatic hetero condensed polycyclic group), —N(Q1)(Q2), —P(═O)(Q3)(Q4), —Si(Q5)(Q6)(Q7), —Ge(Q5)(Q6)(Q7), and —B(Q8)(Q9)(Q1 to Q9 are each independently a hydrogen atom, a C1-C20 alkyl group, or a C6-C40 aryl group);
at least one of substituents of the substituted C1-C20 alkyl group, substituted C2-C20 alkenyl group, substituted C2-C20 alkynyl group, substituted C1-C20 alkoxy group, substituted C3-C10 cycloalkyl group, substituted C1-C10 heterocycloalkyl group, substituted C3-C10 cycloalkenyl group, substituted C1-C10 heterocycloalkenyl group, substituted C6-C40 aryl group, substituted C1-C40 heteroaryl group, substituted C5-C40 aryloxy group, substituted C5-C40 arylthio group, substituted monovalent C6-C40 non-aromatic condensed polycyclic group, substituted monovalent C6-C40 non-aromatic hetero condensed polycyclic group, and substituted C6-C40 arylene group may be selected from:
a deuterium atom, a halogen atom, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid or a salt thereof, a sulfonic acid or a salt thereof, a phosphoric acid or a salt thereof, a C1-C20 alkyl group, a C2-C20 alkenyl group, a C2-C20 alkynyl group, a C1-C20 alkoxy group, a C3-C10 cycloalkyl group, a C1-C10 heterocycloalkyl group, a C3-C10 cycloalkenyl group, a C1-C10 heterocycloalkenyl group, a C6-C40 aryl group, a C1-C40 heteroaryl group, a C5-C40 aryloxy group, a C5-C40 arylthio group, monovalent C6-C40 non-aromatic condensed polycyclic group, monovalent C6-C40 non-aromatic hetero condensed polycyclic group, —N(Q11)(Q12), —Si(Q13)(Q14)(Q15), —Ge(Q13)(Q14)(Q15), and B(Q16)(Q17) (Q11 to Q17 are each independently selected from a hydrogen atom, a C1-C20 alkyl group, and a C6-C40 aryl group),
a1 and a2 are each independently an integer from 0 to 4;
b1 and b2 are each independently 1 or 2;
a1 and a2 are each independently an integer from 0 to 7; and
l1 and l2 are each independently an integer from 0 to 3.
A may be selected from the following substituents:
(1) a chrysenylene group, a pyrenylene group, a perylenylene group, a fluorenylene group, a spiro-fluorenylene group;
(2) a chrysenylene group, a pyrenylene group, a perylenylene group, a fluorenylene group, each substituted with at least one selected from a deuterium atom, a halogen atom, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a styryl group, a carboxylic acid or a salt thereof, a sulfonic acid or a salt thereof, a phosphoric acid or a salt thereof, a C1-C20 alkyl group, a C2-C20 alkenyl group, a C2-C20 alkynyl group, a C1-C20 alkoxy group, a C6-C40 aryl group, a C1-C40 heteroaryl group, a C5-C40 aryloxy group, a C5-C40 arylthio group, a monovalent C6-C40 non-aromatic condensed polycyclic group, a monovalent C6-C40 non-aromatic hetero condensed polycyclic group, —N(Q11)(Q12), —Si(Q13)(Q14)(Q15), —Ge(Q13)(Q14)(Q15), —B(Q16)(Q17) (Q11 to Q17 may be each independently selected from a hydrogen atom, a C1-C20 alkyl group, and a C6-C40 aryl group); and
(3) a group made up of a at least one styryl group combined with at least one substituent of the substituents (1) and (2).
For example, A may be represented by any one of Formulae 4A to Formula 4F:




in Formulae 4A to 4F,
Z11 to Z14 may be each independently selected from a deuterium atom, a halogen atom, a C1-C20 alkyl group, a C6-C40 aryl group, a monovalent C6-C40 non-aromatic condensed polycyclic group, —Si(Q13)(Q14)(Q15), and —Ge(Q13)(Q14)(Q15) (Q13 to Q15 may be each independently selected from a hydrogen atom, a C1-C20 alkyl group, and a C6-C40 aryl group);
a C1-C20 alkyl group, substituted with at least one selected from a deuterium atom and a halogen atom; and
a C6-C40 aryl group and a monovalent C6-C40 non-aromatic condensed polycyclic group, each substituted with at least one selected from a deuterium atom, a halogen atom, a C1-C20 alkyl group, and a C6-C20 aryl group.
p1 is an integer from 0 to 5,
p2 is an integer from 0 to 4;
p3 is an integer from 0 to 6,
p4 is an integer from 0 to 3;
p5 is an integer from 0 to 8; and
* indicates a binding site.
For example, A may be represented by any one of Formulae 5A to Formula 5F:







L1 and L2 are each independently selected from
a phenylene group, a naphthylene group, a phenanthrenylene group, and an anthrylene group; and
a phenylene group, a naphthylene group, a phenanthrenylene group and an anthrylene group, each substituted with at least one selected from a deuterium atom, a halogen atom, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid or a salt thereof, a sulfonic acid or a salt thereof, a phosphoric acid or a salt thereof, a C1-C10 alkyl group, a C1-C10 alkoxy group, a phenyl group, a naphthyl group, a phenanthrenyl group, an anthryl group, and —Si(Q13)(Q14)(Q15) (Q13 to Q15 may be each independently selected from a hydrogen atom, a C1-C20 alkyl group, and a C6-C40 aryl group).
Ar1 to Ar8 may be each independently selected from
a phenyl group, a pentalenyl group, an indenyl group, a naphthyl group, an azulenyl group, a heptalenyl group, an indacenyl group, an acenaphthyl group, a fluorenyl group, a spiro-fluorenyl group, a benzofluorenyl group, a dibenzofluorenyl group, a phenalenyl group, a phenanthrenyl group, an anthracenyl group, a fluoranthenyl group, a triphenylenyl group, a pyrenyl group, a chrysenyl group, a naphthacenyl group, a picenyl group, a perylenyl group, a pentacenyl group, a hexacenyl group, a rubicenyl group, a coronenyl group, and an ovalenyl group; and
a phenyl group, a pentalenyl group, an indenyl group, a naphthyl group, an azulenyl group, a heptalenyl group, an indacenyl group, an acenaphthyl group, a fluorenyl group, a spiro-fluorenyl group, a benzofluorenyl group, a dibenzofluorenyl group, a phenalenyl group, a phenanthrenyl group, an anthracenyl group, a fluoranthenyl group, a triphenylenyl group, a pyrenyl group, a chrysenyl group, a naphthacenyl group, a picenyl group, a perylenyl group, a pentaphenyl group, a hexacenyl group, a pentacenyl group, a rubicenyl group, a coronenyl group, and an ovalenyl group, each substituted with at least one selected from:
a deuterium atom, —F, —Cl, —Br, —I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid or a salt thereof, a sulfonic acid or a salt thereof, a phosphoric acid or a salt thereof, a C1-C20 alkyl group, a C1-C20 alkoxy group, a phenyl group, a pentalenyl group, an indenyl group, a naphthyl group, an azulenyl group, a heptalenyl group, an indacenyl group, an acenaphthyl group, a fluorenyl group, a Spiro-fluorenyl group, a benzofluorenyl group, a dibenzofluorenyl group, a phenalenyl group, a phenanthrenyl group, an anthracenyl group, a fluoranthenyl group, a triphenylenyl group, a pyrenyl group, a chrysenyl group, a naphthacenyl group, a picenyl group, a perylenyl group, a pentaphenyl group, a hexacenyl group, a pentacenyl group, a rubicenyl group, a coronenyl group, an ovalenyl group, and —Si(Q13)(Q14)(Q15),
wherein Q13 to Q15 may be each independently selected from a hydrogen atom, a C1-C10 alkyl group, a C1-C10 alkoxy group, a phenyl group, a naphthyl group, a fluorenyl group, a spiro-fluorenyl group, a benzofluorenyl group, a dibenzofluorenyl group, a phenanthrenyl group, an anthracenyl group, a triphenylenyl group, a pyrenyl group, a chrysenyl group, a pyrrolyl group, a thiophenyl group, a furanyl group, an imidazolyl group, a pyrazolyl group, a thiazolyl group, an isothiazolyl group, an oxazolyl group, an isoxazolyl group, a pyridinyl group, a pyrazinyl group, a pyrimidinyl group, a pyridazinyl group, a quinolinyl group, an isoquinolinyl group, a benzoquinolinyl group, a quinoxalinyl group, a quinazolinyl group, a carbazolyl group, a phenanthrolinyl group, a benzoimidazolyl group, a benzofuranyl group, a benzothiophenyl group, an isobenzothiazolyl group, a benzoxazolyl group, an isobenzoxazolyl group, a triazolyl group, an oxadiazolyl group, a triazinyl group, a dibenzofuranyl group, a dibenzothiophenyl group, a benzocarbazolyl group, a dibenzocarbazolyl group, a dibenzosilolyl group, a thiadiazolyl group, an imidazopyridinyl group, and an imidazopyrimidinyl group.
R1 to R4 may be each independently selected from:
a deuterium atom, a halogen atom, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid or a salt thereof, a sulfonic acid or a salt thereof, a phosphoric acid or a salt thereof, a methyl group, an ethyl group, an n-propyl group, an iso-propyl group, an n-butyl group, an iso-butyl group, a sec-butyl group, a tert-butyl group, an n-pentyl group, an iso-pentyl group, a sec-pentyl group, a tert-pentyl group, a methoxy group, an ethoxy group, a propoxy group, a butoxy group, a pentoxy group, a phenyl group, a pentalenyl group, an indenyl group, a naphthyl group, an azulenyl group, a heptalenyl group, an indacenyl group, an acenaphthyl group, a fluorenyl group, a Spiro-fluorenyl group, a benzofluorenyl group, a dibenzofluorenyl group, a phenalenyl group, a phenanthrenyl group, an anthracenyl group, a fluoranthenyl group, a triphenylenyl group, a pyrenyl group, a chrysenyl group, a naphthacenyl group, a picenyl group, a perylenyl group, a pentacenyl group, a hexacenyl group, a rubicenyl group, a coronenyl group, an ovalenyl group; and
a pentalenyl group, an indenyl group, a naphthyl group, an azulenyl group, a heptalenyl group, an indacenyl group, an acenaphthyl group, a fluorenyl group, a spiro-fluorenyl group, a benzofluorenyl group, a dibenzofluorenyl group, a phenalenyl group, a phenanthrenyl group, an anthracenyl group, a fluoranthenyl group, a triphenylenyl group, a pyrenyl group, a chrysenyl group, a naphthacenyl group, a picenyl group, a perylenyl group, a pentaphenyl group, a hexacenyl group, a pentacenyl group, a rubicenyl group, a coronenyl group, and an ovalenyl group, each substituted with at least one selected from:
a deuterium atom, —F, —Cl, —Br, —I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid or a salt thereof, a sulfonic acid or a salt thereof, a phosphoric acid or a salt thereof, a C1-C20 alkyl group, a C1-C20 alkoxy group, a phenyl group, a pentalenyl group, an indenyl group, a naphthyl group, an azulenyl group, a heptalenyl group, an indacenyl group, an acenaphthyl group, a fluorenyl group, a spiro-fluorenyl group, a benzofluorenyl group, a dibenzofluorenyl group, a phenalenyl group, a phenanthrenyl group, an anthracenyl group, a fluoranthenyl group, a triphenylenyl group, a pyrenyl group, a chrysenyl group, a naphthacenyl group, a picenyl group, a perylenyl group, a pentaphenyl group, a hexacenyl group, a pentacenyl group, a rubicenyl group, a coronenyl group, an ovalenyl group, a pyrrolyl group, a thiophenyl group, a furanyl group, an imidazolyl group, a pyrazolyl group, a thiazolyl group, an isothiazolyl group, an oxazolyl group, an isoxazolyl group, a pyridyl group, a pyrazinyl group, a pyrimidinyl group, a pyridazinyl group, an isoindolyl group, an indolyl group, an indazolyl group, a purinyl group, a quinolyl group, an isoquinolyl group, benzoquinolyl group, a phthalazinyl group, a naphthyridinyl group, a quinoxalinyl group, a quinazolinyl group, a cinnolinyl group, a carbazolyl group, a phenanthridinyl group, an acridinyl group, a phenanthrolinyl group, a phenazinyl group, a benzofluorenyl group, a benzimidazolyl group, a benzofuranyl group, a benzothiophenyl group, a benzothiazolyl group, a benzoxazolyl group, an isobenzoxazolyl group, a triazolyl group, a tetrazolyl group, an oxadiazolyl group, a triazinyl group, a dibenzofluorenyl group, a dibenzofuranyl group, a dibenzothiophenyl group, a benzocarbazolyl group, a dibenzocarbazolyl group, a thiadiazolyl group, an imidazopyridyl group, an imidazopyrimidinyl group, N(Q11)(Q12), and —Si(Q13)(Q14)(Q15).
In this regard, Q11 to Q15 may be each independently selected from a hydrogen atom, a C1-C10 alkyl group, a C1-C10 alkoxy group, a phenyl group, a naphthyl group, a fluorenyl group, a spiro-fluorenyl group, a benzofluorenyl group, a dibenzofluorenyl group, a phenanthrenyl group, an anthracenyl group, a triphenylenyl group, a pyrenyl group, a chrysenyl group, a pyrrolyl group, a thiophenyl group, a furanyl group, an imidazolyl group, a pyrazolyl group, a thiazolyl group, an isothiazolyl group, an oxazolyl group, an isoxazolyl group, a pyridinyl group, a pyrazinyl group, a pyrimidinyl group, a pyridazinyl group, a quinolinyl group, an isoquinolinyl group, a benzoquinolinyl group, a quinoxalinyl group, a quinazolinyl group, a carbazolyl group, a phenanthrolinyl group, a benzoimidazolyl group, a benzofuranyl group, a benzothiophenyl group, an isobenzothiazolyl group, a benzoxazolyl group, an isobenzoxazolyl group, a triazolyl group, an oxadiazolyl group, a triazinyl group, a dibenzofuranyl group, a dibenzothiophenyl group, a benzocarbazolyl group, a dibenzocarbazolyl group, a dibenzosilolyl group, a thiadiazolyl group, an imidazopyridinyl group, and an imidazopyrimidinyl group.
In detail, R1 to R4 may be each independently selected from:
a C1-C20 alkyl group, and Formulae 6A to 6G:







wherein in Formulae 6A to 6G,
Z21 to Z26 may be each independently selected from a deuterium atom, a halogen atom, a C1-C20 alkyl group, a C6-C40 aryl group, a monovalent C6-C40 non-aromatic condensed polycyclic group, —N(Q11)(Q12), —Si(Q13)(Q14)(Q15), Ge(Q13)(Q14)(Q15) (Q11 to Q15 may be each independently a hydrogen atom, a C1-C20 alkyl group, or a C6-C40 aryl group);
a C1-C20 alkyl group, substituted with at least one selected from a deuterium atom and a halogen atom; and
a C6-C40 aryl group and a monovalent C6-C40 non-aromatic condensed polycyclic group, each substituted with at least one selected from a deuterium atom, a halogen atom, a C1-C20 alkyl group, and a C6-C20 aryl group.
q1 may be an integer from 0 to 5,
q2 may be an integer from 0 to 7,
q3 may be an integer from 0 to 9, and
q4 may be an integer from 0 to 3.
In some implementations, when q2 in Formula 6E is 2 or more, a plurality of Z22 may be connected to be condensed to the fluorenyl group, thereby forming a condensed ring.
For example, R1 to R4 may be each independently selected from:
a methyl group, an ethyl group, an n-propyl group, an iso-propyl group, an n-butyl group, an iso-butyl group, a sec-butyl group, a tert-butyl group, and Formulae 7A to 7L:







In some embodiments, in Formula 1-1 or Formula 1-2,
L1 and L2 may be each independently selected from a phenylene group and a naphthylene group,
Ar1 and Ar2 may be each independently selected from a naphthyl group, a phenanthrenyl group, and a pyrenyl group, and
R1 and R2 may be each independently selected from a phenyl group, a naphthyl group, a fluorenyl group, and a benzofluorenyl group; and a phenyl group, a naphthyl group, a fluorenyl group, and a benzofluorenyl group, each substituted with at least one selected from a deuterium atom, a halogen atom, a phenyl group, and a naphthyl group.
In this regard, a1 and a2 may be each independently 0 or 1.
l1 and l2 may be each independently an integer from 0 to 2.
In some embodiments, in Formula 2.
A may be selected from a chrysenylene group, a pyrenylene group, a perylenylene group, and a fluorenylene group; and
a chrysenylene group, a pyrenylene group, a perylenylene group, and a fluorenylene group, each substituted with at least one selected from a deuterium atom, a halogen atom, a methyl group, an ethyl group, an n-propyl group, an iso-propyl group, an n-butyl group, an iso-butyl group, a sec-butyl group, a tert-butyl group, and a styryl group,
Ar3 to Ar6 may be each independently selected from a phenyl group and a naphthyl group; and
a phenyl group and a naphthyl group, each substituted with at least one selected from a deuterium atom, a halogen atom, a methyl group, an n-propyl group, and an iso-propyl group.
In this regard, b1 and b2 may be each independently 0 or 1.
For example, b1 and b2 may all be 1.
For example, b1 and b2 may all be 0. For example, when A is a perylenylene group, b1 and b2 may all be 0.
In some embodiments, in Formula 3, R3 and R4 may be each independently selected from:
a phenyl group, a naphthyl group, a fluorenyl group, a carbazolyl group, and a fluoranthenyl group; and
a phenyl group, a naphthyl group, a fluorenyl group, a carbazolyl group, and a fluoranthenyl group, each substituted with at least one selected from a methyl group, a phenyl group, a pyridyl group, a pyrimidyl group, and —N(Q11)(Q12) (Q11 and Q12 may be each independently a phenyl group or a naphthyl group), and
Ar7 and Ar8 may be each independently selected from a phenyl group and a fluorenyl group;
a phenyl group and a fluorenyl group, each substituted with at least one selected from a methyl group and a phenyl group.
c1 and c2 may be each independently 0 to 1.
For example, the host compound represented by Formula 1-1 or Formula 1-2 may be one of Compounds H-1 to H-43 below:




























The dopant compound represented by Formula 2 may be one of Compounds D-1 to D-6 below:







For example, the dopant compound represented by Formula 3 may be one of Compounds HT-1 to HT-14 below:










The emission layer may include an anthracene-based host represented by Formula 1-1 or Formula 1-2 and a hole transport compound represented by Formula 3. Accordingly, surplus holes existing in the emission layer may be removed, leading to an increase in both the lifespan and efficiency of a device.
An amount of the dopant may be in a range of about 0.01 to about 15 vol % based on a total volume of the emission layer, for example.
An amount of the hole transport material may be in a range of about 0.01 to about 15 vol % based on a total volume of the emission layer, for example.
A thickness of the emission layer may be in a range of about 100 Å to about 1,000 Å, or, for example, about 200 Å to about 600 Å. When the thickness of the emission layer is within this range, excellent light-emission characteristics may be obtained without a substantial increase in driving voltage.
When the organic light-emitting device 10 is a full color organic light-emitting device, the emission layer may be patterned into a red emission layer, a green emission layer, or a blue emission layer, according to a sub pixel. In some embodiments, the emission layer may have a stacked structure of a red emission layer, a green emission layer, and a blue emission layer, or may include a red-light emission material, a green-light emission material, and a blue-light emission material, which are mixed with each other in a single layer, to emit white light. When white light is emitted from the emission layer, the organic light-emitting device may further include a color conversion layer or a color filter. An emission layer as described above may be used as a blue emission layer.
The electron transport region may include at least one selected from a hole blocking layer (HBL), an electron transport layer (ETL), and an electron blocking layer (EBL), as examples.
For example, the electron transport region may have a structure of electron transport layer/electron injection layer or a structure of hole blocking layer/electron transport layer/electron injection layer, wherein layers of each structure are sequentially stacked from the emission layer in the stated order.
The electron transport region may include a hole blocking layer. The hole blocking layer may be formed to prevent diffusion of electrons from the emission layer to the electrode transport layer.
When the electron transport region includes a hole blocking layer, the hole blocking layer may be formed on the emission layer by a suitable method, such as vacuum deposition, spin coating casting, a LB method, ink-jet printing, laser-printing, or laser-induced thermal imaging. When the hole blocking layer is formed by vacuum deposition or spin coating, deposition and coating conditions for the hole blocking layer may be determined by referring to the deposition and coating conditions for the hole injection layer.
In some embodiments, the hole blocking layer may include at least one selected from BCP (bathocuproine), Bphen (4,7-diphenyl-1,10-phenanthroline), TmPyPB (3,3′-[5′-[3-(3-pyridinyl)phenyl][1,1′:3′,1′′-terphenyl]-3,3′′-diyl]bispyridine)).




A thickness of the hole blocking layer may be in a range of about 20 Å to about 1,000 Å, or, for example, about 30 Å to about 300 Å. When the thickness of the hole blocking layer is within these ranges, the hole blocking layer may have excellent hole blocking characteristics without a substantial increase in driving voltage.
The electron transport region may include an electron transport layer. The electron transport layer may be formed on the emission layer or the hole blocking layer by a suitable method, such as vacuum deposition, spin coating casting, a LB method, ink-jet printing, laser-printing, or laser-induced thermal imaging. When an electron transport layer is formed by vacuum deposition or spin coating, deposition and coating conditions for the electron transport layer may be the same as the deposition and coating conditions for the hole injection layer.
In some embodiments, the electron transport layer may further include at least one selected from BCP, Bphen, Alq3, bis(2-methyl-8-quinolinolato)(4-phenylphenolato)aluminum (III) (Balq), 3-(4-biphenylyl)-4-phenyl-5-(4-tert-butylphenyl)-1,2,4-triazole (TAZ), and 4-(naphthalen-1-yl)-3,5-diphenyl-4H-1,2,4-triazole (NTAZ).




In some embodiments, the electron transport layer may further include at least one of compounds represented by Formula 601 below:

Ar601-[(L601)xe1-E601]xe2  <Formula 601>

wherein in Formula 601,
Ar601 may be selected from
a naphthalene, a heptalene, a fluorene, a spiro-fluorene, a benzofluorene, a dibenzofluorene, a phenalene, a phenanthrene, an anthracene, a fluoranthene, a triphenylene, a pyrene, a chrysene, a naphthacene, a picene, a perylene, a pentaphene, and an indenoanthracene; and
a naphthalene, a heptalene, a fluorene, a spiro-fluorene, a benzofluorene, a dibenzofluorene, a phenalene, a phenanthrene, an anthracene, a fluoranthene, a triphenylene, a pyrene, a chrysene, a naphthacene, a picene, a perylene, a pentaphene, and an indenoanthracene, each substituted with at least one selected from a deuterium atom, —F, —Cl, —Br, —I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid or a salt thereof, a sulfonic acid or a salt thereof, a phosphoric acid or a salt thereof, a C1-C60 alkyl group, a C2-C60 alkenyl group, a C2-C60 alkynyl group, a C1-C60 alkoxy group, a C3-C10 cycloalkyl group, a C3-C10 heterocycloalkyl group, a C3-C10 cycloalkenyl group, a C3-C10 heterocycloalkenyl group, a C6-C60 aryl group, a C6-C60 aryloxy group, a C6-C60 arylthio group, a C2-C60 heteroaryl group, a monovalent C2-C60 non-aromatic condensed polycyclic group, and —Si(Q301)(Q302)(Q303) (Q301 to Q303 are each independently selected from a hydrogen, a C1-C60 alkyl group, a C2-C60 alkenyl group, a C6-C60 aryl group, and a C2-C60 heteroaryl group);
a description of L601 may be understood by referring to the description provided in connection with L201;
E601 may be selected from:
a pyrrolyl group, a thiophenyl group, a furanyl group, an imidazolyl group, a pyrazolyl group, a thiazolyl group, an isothiazolyl group, an oxazolyl group, an isoxazolyl group, a pyridinyl group, a pyrazinyl group, a pyrimidinyl group, a pyridazinyl group, an isoindolyl group, an indolyl group, an indazolyl group, a purinyl group, a quinolinyl group, an isoquinolinyl group, a benzoquinolinyl group, a phthalazinyl group, a naphthyridinyl group, a quinoxalinyl group, a quinazolinyl group, a cinnolinyl group, carbazolyl, a phenanthridinyl group, an acridinyl group, a phenanthrolinyl group, a phenazinyl group, benzoimidazolyl, a benzofuranyl group, a benzothiophenyl group, isobenzothiazolyl, a benzoxazolyl group, an isobenzoxazolyl group, a triazolyl group, a tetrazolyl group, an oxadiazolyl group, a triazinyl group, a dibenzofuranyl group, a dibenzothiophenyl group, a benzocarbazolyl group, and a dibenzocarbazolyl group; and
a pyrrolyl group, a thiophenyl group, a furanyl group, an imidazolyl group, a pyrazolyl group, a thiazolyl group, an isothiazolyl group, an oxazolyl group, an isoxazolyl group, a pyridinyl group, a pyrazinyl group, a pyrimidinyl group, a pyridazinyl group, an isoindolyl group, an indolyl group, an indazolyl group, a purinyl group, a quinolinyl group, an isoquinolinyl group, a benzoquinolinyl group, a phthalazinyl group, a naphthyridinyl group, a quinoxalinyl group, a quinazolinyl group, a cinnolinyl group, a carbazolyl group, a phenanthridinyl group, an acridinyl group, a phenanthrolinyl group, a phenazinyl group, a benzoimidazolyl group, a benzofuranyl group, a benzothiophenyl group, an isobenzothiazolyl group, a benzoxazolyl group, an isobenzoxazolyl group, a triazolyl group, a tetrazolyl group, an oxadiazolyl group, a triazinyl group, a dibenzofuranyl group, a dibenzothiophenyl group, a benzocarbazolyl group, and a dibenzocarbazolyl group, each substituted with at least one selected from a deuterium atom, —F, —Cl, —Br, —I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid or a salt thereof, a sulfonic acid or a salt thereof, a phosphoric acid or a salt thereof, a C1-C20 alkyl group, a C1-C20 alkoxy group, a phenyl group, a pentalenyl group, an indenyl group, a naphthyl group, an azulenyl group, a heptalenyl group, an indacenyl group, an acenaphthyl group, a fluorenyl group, a spiro-fluorenyl group, a benzofluorenyl group, a dibenzofluorenyl group, a phenalenyl group, a phenanthrenyl group, an anthracenyl group, a fluoranthenyl group, a triphenylenyl group, a pyrenyl group, a chrysenyl group, a naphthacenyl group, a picenyl group, a perylenyl group, a pentaphenyl group, a hexacenyl group, a pentacenyl group, a rubicenyl group, a coronenyl group, an ovalenyl group, a pyrrolyl group, a thiophenyl group, a furanyl group, an imidazolyl group, a pyrazolyl group, a thiazolyl group, an isothiazolyl group, an oxazolyl group, an isoxazolyl group, a pyridinyl group, a pyrazinyl group, a pyrimidinyl group, a pyridazinyl group, an isoindolyl group, an indolyl group, an indazolyl group, a purinyl group, a quinolinyl group, an isoquinolinyl group, a benzoquinolinyl group, a phthalazinyl group, a naphthyridinyl group, a quinoxalinyl group, a quinazolinyl group, a cinnolinyl group, a carbazolyl group, a phenanthridinyl group, an acridinyl group, a phenanthrolinyl group, a phenazinyl group, a benzoimidazolyl group, a benzofuranyl group, a benzothiophenyl group, an isobenzothiazolyl group, a benzoxazolyl group, an isobenzoxazolyl group, a triazolyl group, a tetrazolyl group, an oxadiazolyl group, a triazinyl group, a dibenzofuranyl group, a dibenzothiophenyl group, a benzocarbazolyl group, and a dibenzocarbazolyl group;
xe1 may be selected from 0, 1, 2, and 3; and
xe2 may be selected from 1, 2, 3, and 4.
In some embodiments, the electron transport layer may further include at least one of compounds represented by Formula 602 below:




wherein in Formula 602,
X611 may be N or C-(L611)xe611-R611, X612 may be N or C-(L612)xe612-R612, X613 may be N or C-(L613)xe613-R613, and at least one selected from X611 to X613 may be N;
L611 to L616 may be understood by referring to the description provided herein in connection with L201;
R611 and R616 may be each independently selected from:
a phenyl group, a naphthyl group, a fluorenyl group, a Spiro-fluorenyl group, a benzofluorenyl group, a dibenzofluorenyl group, a phenanthrenyl group, an anthryl group, a pyrenyl group, a chrysenyl group, a pyridyl group, a pyrazinyl group, a pyrimidinyl group, a pyridazinyl group, a quinolyl group, an isoquinolyl group, a quinoxalinyl group, a quinazolinyl group, a carbazolyl group, and a triazinyl group; and
a phenyl group, a naphthyl group, a fluorenyl group, a spiro-fluorenyl group, a benzofluorenyl group, a dibenzofluorenyl group, a phenanthrenyl group, an anthryl group, a pyrenyl group, a chrysenyl group, a pyridyl group, a pyrazinyl group, a pyrimidinyl group, a pyridazinyl group, a quinolyl group, an isoquinolyl group, a quinoxalinyl group, a quinazolinyl group, a carbazolyl group, and a triazinyl group, each substituted with at least one selected from a deuterium atom, —F, —Cl, —Br, —I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid or a salt thereof, a sulfonic acid or a salt thereof, a phosphoric acid or a salt thereof, a C1-C20 alkyl group, a C1-C20 alkoxy group, a phenyl group, a naphthyl group, an azulenyl group, a fluorenyl group, a spiro-fluorenyl group, a benzofluorenyl group, a dibenzofluorenyl group, a phenanthrenyl group, an anthryl group, a pyrenyl group, a chrysenyl group, a pyridyl group, a pyrazinyl group, a pyrimidinyl group, a pyridazinyl group, a quinolyl group, an isoquinolyl group, a quinoxalinyl group, a quinazolinyl group, a carbazolyl group, and a triazinyl group,
xe611 to xe616 may be each independently selected from 0, 1, 2, and 3.
The compound represented by Formula 601 and the compound represented by Formula 602 may include at least one of Compounds ET1 to ET15 illustrated below.
















A thickness of the electron transport layer may be in a range of about 100 Å to about 1,000 Å, or, for example, about 150 Å to about 500 Å. When the thickness of the electron transport layer is within the range described above, the electron transport layer may have satisfactory electron transport characteristics without a substantial increase in driving voltage.
Also, the electron transport layer may include, in addition to an electron transport organic compound, a metal-containing material.
The metal-containing material may include a Li complex. The Li complex may include, for example, lithium quinolate (LiQ) or lithium[2-(2-hydroxyphenyl)benzothiazole] (LiBTz).




The electron transport region may include an electron injection layer (EIL) that allows electrons to be easily provided from a second electrode 190.
The electron injection layer may include, for example, at least one selected from, LiF. NaCl, CsF, Li2O. BaO. and LiQ.
A thickness of the electron injection layer may be in a range of about 1 Å to about 100 Å, for example, about 3 Å to about 90 Å. When the thickness of the electron injection layer is within the range described above, the electron injection layer may have satisfactory electron injection characteristics without a substantial increase in driving voltage.
Layers or regions constituting the organic layer 150 may be formed by suitable methods, such as vacuum deposition, spin coating, casting, LB, ink-jet printing, laser printing, or laser-thermal transferring.
The second electrode 190 may be formed on the organic layer 150. The second electrode 190 may be a cathode. A material for forming the second electrode 190 may be a material having a relatively low work function. For example, the material for forming the second electrode 190 may be metal, an alloy, an electrically conductive compound, and a combination thereof, which. For example, lithium (Li), magnesium (Mg), aluminum (Al), aluminum-lithium (Al—Li), calcium (Ca), magnesium-indium (Mg—In), or magnesium-silver (Mg—Ag) may be formed as the material for forming the second electrode 190. To manufacture a top emission type light-emitting device, a transmissive electrode formed using ITO or IZO may be used as the second electrode 190.
Hereinbefore, the organic light-emitting device has been described with reference to FIG. 1, other implementations are possible.
The term “C1-C20 alkyl group” used herein refers to a linear or branched aliphatic hydrocarbon monovalent group having 1 to 20 carbon atoms. Detailed examples thereof include a methyl group, an ethyl group, an n-propyl group, an iso-propyl group, an n-butyl group, an iso-butyl group, a sec-butyl group, a tert-butyl group, a pentyl group, an iso-amyl group, and a hexyl group. The term “C1-C20 alkylene group” used herein refers to a divalent group having the same structure as the C1-C20 alkyl group.
The term “C1-C20 alkoxy group” used herein refers to a monovalent group represented by —OA101 (wherein A101 is the C1-C20 alkyl group). Detailed examples thereof include a methoxy group, an ethoxy group, and an isopropyloxy group.
The term “C2-C20 alkenyl group” used herein refers to a hydrocarbon group having at least one carbon double bond in the middle or at the terminal of the C1-C20 alkyl group. Detailed examples thereof include an ethenyl group, a propenyl group, and a butenyl group. The term “C2-C20 alkenylene group” used herein refers to a divalent group having the same structure as the C2-C20 alkenyl group.
The term “C2-C20 alkynyl group” used herein refers to a hydrocarbon group having at least one carbon trip bond in the middle or at the terminal of the C1-C20 alkyl group. Detailed examples thereof include an ethynyl group, and a propynyl group. The term “C2-C20 alkynylene group” used herein refers to a divalent group having the same structure as the C2-C20 alkynyl group.
The term “C3-C10 cycloalkyl group” used herein refers to a monovalent hydrocarbon monocyclic group having 3 to 10 carbon atoms. Detailed examples thereof include a cyclopropyl group, a cyclobutyl group, a cyclopentyl group, a cyclohexyl group, and a cycloheptyl group. The term “C3-C10 cycloalkylene group” used herein refers to a divalent group having the same structure as the C3-C10 cycloalkyl group.
The term “C1-C10 heterocycloalkyl group” used herein refers to a monovalent monocyclic group having at least one hetero atom selected from N, O, P, and S as a ring-forming atom and 1 to 10 carbon atoms. Detailed examples thereof include a tetrahydrofuranyl group, and a tetrahydrothiophenyl group. The term “C1-C10 heterocycloalkylene group” used herein refers to a divalent group having the same structure as the C1-C10 heterocycloalkyl group.
The term “C3-C10 cycloalkenyl group” used herein refers to a monovalent monocyclic group that has 3 to 10 carbon atoms and at least one double bond in the ring thereof and does not have aromaticity. Detailed examples thereof include a cyclopentenyl group, a cyclohexenyl group, and a cycloheptenyl group. The term “C3-C10 cycloalkenylene group” used herein refers to a divalent group having the same structure as the C3-C10 cycloalkenyl group.
The term “C1-C10 heterocycloalkenyl group” used herein refers to a monovalent monocyclic group that has at least one hetero atom selected from N, O, P, and S as a ring-forming atom, 1 to 10 carbon atoms, and at least one double bond in its ring. Detailed examples of the C1-C10 heterocycloalkenyl group include a 2,3-hydrofuranyl group and a 2,3-hydrothiophenyl group. The term “C1-C10 heterocycloalkenylene group” used herein refers to a divalent group having the same structure as the C1-C10 heterocycloalkenyl group.
The term “C6-C40 aryl group” used herein refers to a monovalent group having a carbocyclic aromatic system having 6 to 40 carbon atoms. The term “C6-C40 arylene group” used herein refers to a divalent group having a carbocyclic aromatic system having 6 to 40 carbon atoms. Detailed examples of the C6-C40 aryl group include a phenyl group, a naphthyl group, an anthryl group, a phenanthrenyl group, a pyrenyl group, and a chrysenyl group. When the C6-C40 aryl group and the C6-C40 arylene group each include two or more rings, the rings may be fused to each other.
The term “C1-C40 heteroaryl group” used herein refers to a monovalent group having a carbocyclic aromatic system that has at least one hetero atom selected from N, O, P, and S as a ring-forming atom, and 1 to 40 carbon atoms. The term “C1-C40 heteroarylene group” used herein refers to a divalent group having a carbocyclic aromatic system that has at least one hetero atom selected from N, O, P, and S as a ring-forming atom, and 1 to 40 carbon atoms. Examples of the C1-C40 heteroaryl group include a pyridyl group, a pyrimidinyl group, a pyrazinyl group, a pyridazinyl group, a triazinyl group, a quinolyl group, and an isoquinolyl group. When the C1-C40 heteroaryl group and the C1-C40 heteroarylene group each include two or more rings, the rings may be fused to each other.
The term “C6-C40 aryloxy group” used herein indicates —OA102 (wherein A102 is the C6-C40 aryl group), and the term “C6-C40 arylthio group” indicates —SA103 (wherein A103 is the C6-C40 aryl group).
The term “monovalent non-aromatic condensed polycyclic group” used herein refers to a monovalent group that has two or more rings condensed to each other, only carbon atoms as a ring forming atom, and non-aromaticity in the entire molecular structure. Detailed examples of the monovalent non-aromatic condensed polycyclic group include a fluorenyl group. The term “divalent non-aromatic condensed polycyclic group” used herein refers to a divalent group having the same structure as the monovalent non-aromatic condensed polycyclic group.
The term “monovalent non-aromatic condensed heteropolycyclic group” used herein refers to a monovalent group that has two or more rings condensed to each other, has a heteroatom selected from N, O P, and S, other than carbon atoms, as a ring forming atom, and has non-aromaticity in the entire molecular structure. Detailed examples of the monovalent non-aromatic condensed heteropolycyclic group include a carbazolyl group. The term “divalent non-aromatic condensed heteropolycyclic group” used herein refers to a divalent group having the same structure as the monovalent non-aromatic condensed heteropolycyclic group.
The following Examples and Comparative Examples are provided in order to highlight characteristics of one or more embodiments, but it will be understood that the Examples and Comparative Examples are not to be construed as limiting the scope of the embodiments, nor are the Comparative Examples to be construed as being outside the scope of the embodiments. Further, it will be understood that the embodiments are not limited to the particular details described in the Examples and Comparative Examples.
The following compounds are mentioned in the formation of organic light-emitting device according to Examples and Comparative Examples.







Examples 1-1 to 1-14
On an ITO anode (1,200 Å) disposed on a glass substrate, with an Ag lower reflective film thereunder, NPB:F4-TCNQ (1 vol %) was vacuum co-deposited to form a first hole transport layer that was doped with a p-type dopant and had a thickness of 100 Å. NPB was vacuum deposited on the first hole transport layer to form a second hole transport layer having a thickness of 1,200 Å.
MADN, Compound D-1, and one of the hole transport material shown in Table 1 were co-deposited on the second hole transport layer at a volume ratio of 94:3:3 to form an emission layer having a thickness of 250 Å.
TPBi and LiQ were co-deposited on the emission layer at a volume ratio of 50:50 to form an electron transport layer having a thickness of 350 Å. LiQ was deposited on the electron transport layer to form an electron injection layer having a thickness of 15 Å, and Mg:Ag were co-deposited at a volume ratio of 90:10 to form a cathode having a thickness of 100 Å to complete the manufacturing of an organic light-emitting device. Alq3 was vacuum deposited on the cathode to form a capping layer having a thickness of 600 Å.
Comparative Examples 1-1 to 1-3
Organic light-emitting devices were manufactured in the same manner as in Example 1-1 to Example 1-14, except that in forming an emission layer, MADN. Compound D-1 and hole transport materials shown in Table 1 were co-deposited at a volume ratio of 94:3:3 (in the case of Comparative Example 1-1, MADN and Compound D-1 were co-deposited at a volume ratio of 94:3).
Examples 2-1 to 2-14
Organic light-emitting devices were manufactured in the same manner as in Example 1-1 to Example 1-14, except that in forming an emission layer, MADN, Compound D-2 and hole transport materials shown in Table 2 were co-deposited at a volume ratio of 94:3:3.
Comparative Examples 2-1 to 2-3
Organic light-emitting devices were manufactured in the same manner as in Example 2-1 to Example 2-14, except that in forming an emission layer, MADN, Compound D-2 and hole transport materials shown in Table 2 were co-deposited at a volume ratio of 94:3:3 (in the case of Comparative Example 2-1, MADN and Compound D-2 were co-deposited at a volume ratio of 94:3).
Examples 3-1 to 3-14
Organic light-emitting devices were manufactured in the same manner as in Example 1-1 to Example 1-14, except that in forming an emission layer, MADN, Compound D-3 and hole transport materials shown in Table 3 were co-deposited at a volume ratio of 94:3:3.
Comparative Examples 3-1 to 3-3
Organic light-emitting devices were manufactured in the same manner as in Example 3-1 to Example 3-14, except that in forming an emission layer, MADN, Compound D-3 and hole transport materials shown in Table 3 were co-deposited at a volume ratio of 94:3:3 (in the case of Comparative Example 3-1, MADN and Compound D-3 were co-deposited at a volume ratio of 94:3).
Examples 4-1 to 4-14
Organic light-emitting devices were manufactured in the same manner as in Example 1-1 to Example 1-14, except that in forming an emission layer, MADN, Compound D-4 and hole transport materials shown in Table 3 were co-deposited at a volume ratio of 94:3:3.
Comparative Examples 4-1 to 4-3
Organic light-emitting devices were manufactured in the same manner as in Example 4-1 to Example 4-14, except that in forming an emission layer, MADN, Compound D-4 and hole transport materials shown in Table 3 were co-deposited at a volume ratio of 94:3:3 (in the case of Comparative Example 4-1, MADN and Compound D-4 were co-deposited at a volume ratio of 94:3).
Examples 5-1 to 5-14
Organic light-emitting devices were manufactured in the same manner as in Example 1-1 to Example 1-14, except that in forming an emission layer, MADN, Compound D-5 and hole transport materials shown in Table 3 were co-deposited at a volume ratio of 94:3:3.
Comparative Examples 5-1 to 5-3
Organic light-emitting devices were manufactured in the same manner as in Example 5-1 to Example 5-14, except that in forming an emission layer, MADN, Compound D-5 and hole transport materials shown in Table 3 were co-deposited at a volume ratio of 94:3:3 (in the case of Comparative Example 5-1, MADN and Compound D-5 were co-deposited at a volume ratio of 94:3).
Examples 6-1 to 6-14
Organic light-emitting devices were manufactured in the same manner as in Example 1-1 to Example 1-14, except that in forming an emission layer, MADN, Compound D-6 and hole transport materials shown in Table 3 were co-deposited at a volume ratio of 94:3:3.
Comparative Examples 6-1 to 6-3
Organic light-emitting devices were manufactured in the same manner as in Example 6-1 to Example 6-14, except that in forming an emission layer, MADN, Compound D-6 and hole transport materials shown in Table 3 were co-deposited at a volume ratio of 94:3:3 (in the case of Comparative Example 6-1, MADN and Compound D-6 were co-deposited at a volume ratio of 94:3).
Measurement Data
The driving voltage, current efficiency, and lifespan (T97) of the organic light-emitting devices of Examples 1-1 to 1-14, 2-1 to 2-14, 3-1 to 3-14, 4-1 to 4-14, 5-1 to 5-14, and 6-1 to 6-14, and Comparative Examples 1-1 to 1-3, 2-1 to 2-3, 3-1 to 3-3, 4-1 to 4-3, 5-1 to 5-3, and 6-1 to 6-3 were measured by using an IVL measurement device (PhotoResearch PR650, Keithley 238), and results thereof are shown in Tables 1 to 6 below. T97 indicates the amount of time that elapsed until luminance was reduced to 97% of the initial luminance (100%) of a device when the device was driven at room temperature at 800 nit.














TABLE 1











Current






Hole
Driving
effi-
Life-



Dop-

transport
voltage
ciency
span



ant
Host
material
(V)
(cd/A)
[h]






















Example 1-1
D-1
MADN
HT-1
5.0
4.2
70


Example 1-2
D-1
MADN
HT-2
4.9
4.3
75


Example 1-3
D-1
MADN
HT-3
4.9
4.2
75


Example 1-4
D-1
MADN
HT-4
5.0
4.2
65


Example 1-5
D-1
MADN
HT-5
4.8
4.3
80


Example 1-6
D-1
MADN
HT-6
4.9
4.3
75


Example 1-7
D-1
MADN
HT-7
5.1
4.2
65


Example 1-8
D-1
MADN
HT-8
4.9
4.2
70


Example 1-9
D-1
MADN
HT-9
4.9
4.2
70


Example 1-10
D-1
MADN
HT-10
4.9
4.2
75


Example 1-11
D-1
MADN
HT-11
5.0
4.3
60


Example 1-12
D-1
MADN
HT-12
4.8
4.4
80


Example 1-13
D-1
MADN
HT-13
5.0
4.2
75


Example 1-14
D-1
MADN
HT-14
5.1
4.2
70


Comparative
D-1
MADN
—
5.0
4.2
50


Example 1-1


Comparative
D-1
MADN
m-MTDATA
5.3
3.8
55


Example 1-2


Comparative
D-1
MADN
NPB
5.1
3.9
50


Example 1-3























TABLE 2











Current






Hole
Driving
effi-
Life-



Dop-

transport
voltage
ciency
span



ant
Host
material
(V)
(cd/A)
[h]






















Example 2-1
D-2
MADN
HT-1
4.6
4.8
105


Example 2-2
D-2
MADN
HT-2
4.5
4.9
110


Example 2-3
D-2
MADN
HT-3
4.6
4.8
115


Example 2-4
D-2
MADN
HT-4
4.7
4.8
100


Example 2-5
D-2
MADN
HT-5
4.4
4.8
120


Example 2-6
D-2
MADN
HT-6
4.5
4.9
110


Example 2-7
D-2
MADN
HT-7
4.6
4.8
100


Example 2-8
D-2
MADN
HT-8
4.6
4.8
105


Example 2-9
D-2
MADN
HT-9
4.5
4.8
105


Example 2-10
D-2
MADN
HT-10
4.6
4.8
110


Example 2-11
D-2
MADN
HT-11
4.6
4.9
90


Example 2-12
D-2
MADN
HT-12
4.5
5.0
115


Example 2-13
D-2
MADN
HT-13
4.6
4.8
105


Example 2-14
D-2
MADN
HT-14
4.5
4.8
105


Comparative
D-2
MADN
—
4.6
4.8
75


Example 2-1


Comparative
D-2
MADN
m-MTDATA
4.8
4.3
70


Example 2-2


Comparative
D-2
MADN
NPB
4.7
4.4
75


Example 2-3























TABLE 3











Current






Hole
Driving
effi-
Life-



Dop-

transport
voltage
ciency
span



ant
Host
material
(V)
(cd/A)
[h]






















Example 3-1
D-3
MADN
HT-1
5.1
4.3
85


Example 3-2
D-3
MADN
HT-2
5.0
4.4
90


Example 3-3
D-3
MADN
HT-3
5.1
4.3
90


Example 3-4
D-3
MADN
HT-4
5.1
4.2
80


Example 3-5
D-3
MADN
HT-5
4.9
4.2
95


Example 3-6
D-3
MADN
HT-6
5.1
4.4
90


Example 3-7
D-3
MADN
HT-7
5.1
4.3
75


Example 3-8
D-3
MADN
HT-8
5.1
4.4
95


Example 3-9
D-3
MADN
HT-9
4.9
4.3
85


Example 3-10
D-3
MADN
HT-10
5.0
4.2
85


Example 3-11
D-3
MADN
HT-11
5.1
4.4
80


Example 3-12
D-3
MADN
HT-12
5.2
4.3
95


Example 3-13
D-3
MADN
HT-13
5.1
4.2
90


Example 3-14
D-3
MADN
HT-14
5.1
4.3
85


Comparative
D-3
MADN
—
5.1
4.3
60


Example 3-1


Comparative
D-3
MADN
m-MTDATA
5.4
4.0
60


Example 3-2


Comparative
D-3
MADN
NPB
5.3
4.1
65


Example 3-3























TABLE 4











Current






Hole
Driving
effi-
Life-



Dop-

transport
voltage
ciency
span



ant
Host
material
(V)
(cd/A)
[h]






















Example 4-1
D-4
MADN
HT-1
4.9
4.6
85


Example 4-2
D-4
MADN
HT-2
4.8
4.7
90


Example 4-3
D-4
MADN
HT-3
4.9
4.6
95


Example 4-4
D-4
MADN
HT-4
4.9
4.5
85


Example 4-5
D-4
MADN
HT-5
4.7
4.5
100


Example 4-6
D-4
MADN
HT-6
4.8
4.7
90


Example 4-7
D-4
MADN
HT-7
4.9
4.6
95


Example 4-8
D-4
MADN
HT-8
4.8
4.6
90


Example 4-9
D-4
MADN
HT-9
4.7
4.6
85


Example 4-10
D-4
MADN
HT-10
4.8
4.5
90


Example 4-11
D-4
MADN
HT-11
4.9
4.7
80


Example 4-12
D-4
MADN
HT-12
4.9
4.7
95


Example 4-13
D-4
MADN
HT-13
4.9
4.5
90


Example 4-14
D-4
MADN
HT-14
4.8
4.6
95


Comparative
D-4
MADN
—
4.9
4.6
70


Example 4-1


Comparative
D-4
MADN
m-MTDATA
5.1
4.3
70


Example 4-2


Comparative
D-4
MADN
NPB
5.0
4.3
65


Example 4-3























TABLE 5











Current






Hole
Driving
effi-
Life-



Dop-

transport
voltage
ciency
span



ant
Host
material
(V)
(cd/A)
[h]






















Example 5-1
D-5
MADN
HT-1
5.0
4.4
80


Example 5-2
D-5
MADN
HT-2
4.9
4.5
85


Example 5-3
D-5
MADN
HT-3
4.9
4.4
85


Example 5-4
D-5
MADN
HT-4
5.0
4.4
75


Example 5-5
D-5
MADN
HT-5
4.8
4.4
90


Example 5-6
D-5
MADN
HT-6
4.9
4.5
85


Example 5-7
D-5
MADN
HT-7
5.0
4.4
80


Example 5-8
D-5
MADN
HT-8
4.9
4.4
80


Example 5-9
D-5
MADN
HT-9
4.8
4.4
80


Example 5-10
D-5
MADN
HT-10
4.9
4.4
85


Example 5-11
D-5
MADN
HT-11
5.0
4.5
70


Example 5-12
D-5
MADN
HT-12
4.9
4.6
90


Example 5-13
D-5
MADN
HT-13
5.0
4.4
85


Example 5-14
D-5
MADN
HT-14
5.0
4.4
80


Comparative
D-5
MADN
—
5.0
4.4
60


Example 5-1


Comparative
D-5
MADN
m-MTDATA
5.2
4.1
65


Example 5-2


Comparative
D-5
MADN
NPB
5.1
4.1
60


Example 5-3























TABLE 6











Current






Hole
Driving
effi-
Life-



Dop-

transport
voltage
ciency
span



ant
Host
material
(V)
(cd/A)
[h]






















Example 6-1
D-6
MADN
HT-1
4.9
4.6
95


Example 6-2
D-6
MADN
HT-2
4.8
4.7
100


Example 6-3
D-6
MADN
HT-3
4.9
4.6
105


Example 6-4
D-6
MADN
HT-4
4.9
4.5
90


Example 6-5
D-6
MADN
HT-5
4.7
4.5
110


Example 6-6
D-6
MADN
HT-6
4.8
4.7
100


Example 6-7
D-6
MADN
HT-7
4.9
4.6
90


Example 6-8
D-6
MADN
HT-8
4.9
4.6
100


Example 6-9
D-6
MADN
HT-9
4.7
4.6
95


Example 6-10
D-6
MADN
HT-10
4.8
4.5
100


Example 6-11
D-6
MADN
HT-11
4.9
4.7
85


Example 6-12
D-6
MADN
HT-12
4.9
4.7
105


Example 6-13
D-6
MADN
HT-13
4.9
4.5
100


Example 6-14
D-6
MADN
HT-14
4.8
4.6
95


Comparative
D-6
MADN
—
4.9
4.6
70


Example 6-1


Comparative
D-6
MADN
m-MTDATA
5.1
4.2
65


Example 6-2


Comparative
D-6
MADN
NPB
5.0
4.3
70


Example 6-3









Referring to Tables 1 to 6, it can be seen that the organic light-emitting devices according to Examples had higher efficiency and a longer lifespan than the organic light-emitting devices according to Comparative Examples.
When an emission layer includes a host represented by Formula 1-1 or Formula 1-2, a dopant represented by Formula 2, and a carbazole compound represented by Formula 3, an organic light-emitting device including the emission layer may have high efficiency and a long lifespan.
By way of summation and review, embodiments provide an organic light-emitting device having improved efficiency and lifespan characteristics.
Example embodiments have been disclosed herein, and although specific terms are employed, they are used and are to be interpreted in a generic and descriptive sense only and not for purpose of limitation. Accordingly, it will be understood by those of skill in the art that various changes in form and details may be made without departing from the spirit and scope thereof as set forth in the following claims.

## Claims

1. An organic light-emitting device, comprising:
a first electrode;
a second electrode facing the first electrode; and
an organic layer between the first electrode and the second electrode, the organic layer including an emission layer,
wherein the emission layer includes a first compound represented by Formula 1-1 or Formula 1-2 below, a second compound represented by Formula 2 below, and a third compound represented by Formula 3 below:




wherein in Formulae 1-1 to 3,
L1 and L2 are each independently a substituted or unsubstituted C6-C40 arylene group,
A is a substituted or unsubstituted C6-C40 arylene group, a substituted or unsubstituted divalent C6-C40 non-aromatic hetero condensed polycyclic group, or group made up of a substituted or unsubstituted C6-C40 arylene group, or a substituted or unsubstituted divalent C6-C40 non-aromatic hetero condensed polycyclic group combined with a styrylene group,
Ar1 to Ar8 are each independently a substituted or unsubstituted C6-C40 aryl group,
R1 to R4 are each independently selected from a deuterium atom, a halogen atom, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid or a salt thereof, a sulfonic acid or a salt thereof, a phosphoric acid or a salt thereof, a substituted or unsubstituted C1-C20 alkyl group, a substituted or unsubstituted C2-C20 alkenyl group, a substituted or unsubstituted C2-C20 alkynyl group, a substituted or unsubstituted C1-C20 alkoxy group, a substituted or unsubstituted C3-C10 cycloalkyl group, a substituted or unsubstituted C1-C10 heterocycloalkyl group, a substituted or unsubstituted C3-C10 cycloalkenyl group, a substituted or unsubstituted C1-C10 heterocycloalkenyl group, a substituted or unsubstituted C6-C40 aryl group, a substituted or unsubstituted C1-C40 heteroaryl group, a substituted or unsubstituted C5-C40 aryloxy group, a substituted or unsubstituted C5-C40 arylthio group, a substituted or unsubstituted monovalent C6-C40 non-aromatic condensed polycyclic group(non-aromatic condensed polycyclic group), a substituted or unsubstituted monovalent C6-C40 non-aromatic hetero condensed polycyclic group(non-aromatic hetero condensed polycyclic group), —N(Q1)(Q2), —P(═O)(Q3)(Q4), —Si(Q5)(Q6)(Q7), —Ge(Q5)(Q6)(Q7), and —B(Q8)(Q9), wherein Q1 to Q9 are each independently a hydrogen atom, a C1-C20 alkyl group, or a C6-C40 aryl group;
at least one substituent of the substituted C1-C20 alkyl group, substituted C2-C20 alkenyl group, substituted C2-C20 alkynyl group, substituted C1-C20 alkoxy group, substituted C3-C10 cycloalkyl group, substituted C1-C10 heterocycloalkyl group, substituted C3-C10 cycloalkenyl group, substituted C1-C10 heterocycloalkenyl group, substituted C6-C40 aryl group, substituted C1-C40 heteroaryl group, substituted C5-C40 aryloxy group, substituted C5-C40 arylthio group, substituted monovalent C6-C40 non-aromatic condensed polycyclic group, substituted monovalent C6-C40 non-aromatic hetero condensed polycyclic group, and substituted C6-C40 arylene group is selected from:
a deuterium atom, a halogen atom, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid or a salt thereof, a sulfonic acid or a salt thereof, a phosphoric acid or a salt thereof, a C1-C20 alkyl group, a C2-C20 alkenyl group, a C2-C20 alkynyl group, a C1-C20 alkoxy group, a C3-C10 cycloalkyl group, a C1-C10 heterocycloalkyl group, a C3-C10 cycloalkenyl group, a C1-C10 heterocycloalkenyl group, a C6-C40 aryl group, a C1-C40 heteroaryl group, a C5-C40 aryloxy group, a C5-C40 arylthio group, monovalent C6-C40 non-aromatic condensed polycyclic group, monovalent C6-C40 non-aromatic hetero condensed polycyclic group, —N(Q11)(Q12), —Si(Q13)(Q14)(Q15), —Ge(Q13)(Q14)(Q15), and B(Q16)(Q17), wherein Q11 to Q17 are each independently selected from a hydrogen atom, a C1-C20 alkyl group, and a C6-C40 aryl group,
a1 and a2 are each independently an integer from 0 to 4;
b1 and b2 are each independently 1 or 2;
c1 and c2 are each independently an integer from 0 to 7; and
l1 and l2 are each independently an integer from 0 to 3.

2. The organic light-emitting device as claimed in claim 1, wherein A is selected from the following substituents:
(1) a chrysenylene group, a pyrenylene group, a perylenylene group, a fluorenylene group, and a spiro-fluorenylene group;
(2) a chrysenylene group, a pyrenylene group, a perylenylene group, and a fluorenylene group, each substituted with at least one selected from a deuterium atom, a halogen atom, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a styryl group, a carboxylic acid or a salt thereof, a sulfonic acid or a salt thereof, a phosphoric acid or a salt thereof, a C1-C20 alkyl group, a C2-C20 alkenyl group, a C2-C20 alkynyl group, a C1-C20 alkoxy group, a C6-C40 aryl group, a C1-C40 heteroaryl group, a C5-C40 aryloxy group, a C5-C40 arylthio group, a monovalent C6-C40 non-aromatic condensed polycyclic group, a monovalent C6-C40 non-aromatic hetero condensed polycyclic group, —N(Q11)(Q12), —Si(Q13)(Q14)(Q15), —Ge(Q13)(Q14)(Q15), and —B(Q16)(Q17), wherein Q11 to Q17 are each independently selected from a hydrogen atom, a C1-C20 alkyl group, and a C6-C40 aryl group; and
(3) a group made up of at least one styryl group combined with at least one substituent of the substituents (1) and (2).

3. The organic light-emitting device as claimed in claim 1, wherein A is represented by any one of Formulae 4A to 4F below:






wherein Formulae 4A to 4F,
Z11 to Z14 are each independently selected from a deuterium atom, a halogen atom, a C1-C20 alkyl group, a C6-C40 aryl group, a monovalent C6-C40 non-aromatic condensed polycyclic group, —Si(Q13)(Q14)(Q15), and —Ge(Q13)(Q14)(Q15), wherein Q13 to Q15 are each independently selected from a hydrogen atom, a C1-C20 alkyl group, and a C6-C40 aryl group;
a C1-C20 alkyl group, substituted with at least one selected from a deuterium atom and a halogen atom; and
a C6-C40 aryl group and a monovalent C6-C40 non-aromatic condensed polycyclic group, each substituted with at least one selected from a deuterium atom, a halogen atom, a C1-C20 alkyl group, and a C6-C20 aryl group;
p1 is an integer from 0 to 5;
p2 is an integer from 0 to 4;
p3 is an integer from 0 to 6;
p4 is an integer from 0 to 3;
p5 is an integer from 0 to 8; and
* indicates a binding site to a neighboring atom.

4. The organic light-emitting device as claimed in claim 1, wherein A is represented by any one of Formulae 5A to 5F below:



wherein in formulae 5A to 5F, * indicates a binding site to a neighboring atom.

5. The organic light-emitting device as claimed in claim 1, wherein:
L1 and L2 are each independently selected from:
a phenylene group, a naphthylene group, a phenanthrenylene group, and an anthrylene group; and
a phenylene group, a naphthylene group, a phenanthrenylene group and an anthrylene group, each substituted with at least one selected from a deuterium atom, a halogen atom, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid or a salt thereof, a sulfonic acid or a salt thereof, a phosphoric acid or a salt thereof, a C1-C10 alkyl group, a C1-C10 alkoxy group, a phenyl group, a naphthyl group, a phenanthrenyl group, an anthryl group, and —Si(Q13)(Q14)(Q15), wherein Q13 to Q15 are each independently selected from a hydrogen atom, a C1-C20 alkyl group, and a C6-C40 aryl group.

6. The organic light-emitting device as claimed in claim 1, wherein:
Ar1 to Ar8 are each independently selected from:
a phenyl group, a pentalenyl group, an indenyl group, a naphthyl group, an azulenyl group, a heptalenyl group, an indacenyl group, an acenaphthyl group, a fluorenyl group, a spiro-fluorenyl group, a benzofluorenyl group, a dibenzofluorenyl group, a phenalenyl group, a phenanthrenyl group, an anthracenyl group, a fluoranthenyl group, a triphenylenyl group, a pyrenyl group, a chrysenyl group, a naphthacenyl group, a picenyl group, a perylenyl group, a pentacenyl group, a hexacenyl group, a rubicenyl group, a coronenyl group, and an ovalenyl group; and
a phenyl group, a pentalenyl group, an indenyl group, a naphthyl group, an azulenyl group, a heptalenyl group, an indacenyl group, an acenaphthyl group, a fluorenyl group, a spiro-fluorenyl group, a benzofluorenyl group, a dibenzofluorenyl group, a phenalenyl group, a phenanthrenyl group, an anthracenyl group, a fluoranthenyl group, a triphenylenyl group, a pyrenyl group, a chrysenyl group, a naphthacenyl group, a picenyl group, a perylenyl group, a pentaphenyl group, a hexacenyl group, a pentacenyl group, a rubicenyl group, a coronenyl group, and an ovalenyl group, each substituted with at least one selected from:
a deuterium atom, —F, —Cl, —Br, —I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid or a salt thereof, a sulfonic acid or a salt thereof, a phosphoric acid or a salt thereof, a C1-C20 alkyl group, a C1-C20 alkoxy group, a phenyl group, a pentalenyl group, an indenyl group, a naphthyl group, an azulenyl group, a heptalenyl group, an indacenyl group, an acenaphthyl group, a fluorenyl group, a spiro-fluorenyl group, a benzofluorenyl group, a dibenzofluorenyl group, a phenalenyl group, a phenanthrenyl group, an anthracenyl group, a fluoranthenyl group, a triphenylenyl group, a pyrenyl group, a chrysenyl group, a naphthacenyl group, a picenyl group, a perylenyl group, a pentaphenyl group, a hexacenyl group, a pentacenyl group, a rubicenyl group, a coronenyl group, an ovalenyl group, and —Si(Q13)(Q14)(Q15),
wherein Q13 to Q15 are each independently selected from a hydrogen atom, a C1-C10 alkyl group, a C1-C10 alkoxy group, a phenyl group, a naphthyl group, a fluorenyl group, a spiro-fluorenyl group, a benzofluorenyl group, a dibenzofluorenyl group, a phenanthrenyl group, an anthracenyl group, a triphenylenyl group, a pyrenyl group, a chrysenyl group, a pyrrolyl group, a thiophenyl group, a furanyl group, an imidazolyl group, a pyrazolyl group, a thiazolyl group, an isothiazolyl group, an oxazolyl group, an isoxazolyl group, a pyridinyl group, a pyrazinyl group, a pyrimidinyl group, a pyridazinyl group, a quinolinyl group, an isoquinolinyl group, a benzoquinolinyl group, a quinoxalinyl group, a quinazolinyl group, a carbazolyl group, a phenanthrolinyl group, a benzoimidazolyl group, a benzofuranyl group, a benzothiophenyl group, an isobenzothiazolyl group, a benzoxazolyl group, an isobenzoxazolyl group, a triazolyl group, an oxadiazolyl group, a triazinyl group, a dibenzofuranyl group, a dibenzothiophenyl group, a benzocarbazolyl group, a dibenzocarbazolyl group, a dibenzosilolyl group, a thiadiazolyl group, an imidazopyridinyl group, and an imidazopyrimidinyl group.

7. The organic light-emitting device as claimed in claim 1, wherein:
R1 to R4 are each independently selected from:
a deuterium atom, a halogen atom, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid or a salt thereof, a sulfonic acid or a salt thereof, a phosphoric acid or a salt thereof, a methyl group, an ethyl group, an n-propyl group, an iso-propyl group, an n-butyl group, an iso-butyl group, a sec-butyl group, a tert-butyl group, an n-pentyl group, an iso-pentyl group, a sec-pentyl group, a tert-pentyl group, a methoxy group, an ethoxy group, a propoxy group, a butoxy group, a pentoxy group, a phenyl group, a pentalenyl group, an indenyl group, a naphthyl group, an azulenyl group, a heptalenyl group, an indacenyl group, an acenaphthyl group, a fluorenyl group, a spiro-fluorenyl group, a benzofluorenyl group, a dibenzofluorenyl group, a phenalenyl group, a phenanthrenyl group, an anthracenyl group, a fluoranthenyl group, a triphenylenyl group, a pyrenyl group, a chrysenyl group, a naphthacenyl group, a picenyl group, a perylenyl group, a pentacenyl group, a hexacenyl group, a rubicenyl group, a coronenyl group, an ovalenyl group; and
a phenyl group, a pentalenyl group, an indenyl group, a naphthyl group, an azulenyl group, a heptalenyl group, an indacenyl group, an acenaphthyl group, a fluorenyl group, a spiro-fluorenyl group, a benzofluorenyl group, a dibenzofluorenyl group, a phenalenyl group, a phenanthrenyl group, an anthracenyl group, a fluoranthenyl group, a triphenylenyl group, a pyrenyl group, a chrysenyl group, a naphthacenyl group, a picenyl group, a perylenyl group, a pentaphenyl group, a hexacenyl group, a pentacenyl group, a rubicenyl group, a coronenyl group, and an ovalenyl group, each substituted with at least one selected from
a deuterium atom, —F, —Cl, —Br, —I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid or a salt thereof, a sulfonic acid or a salt thereof, a phosphoric acid or a salt thereof, a C1-C20 alkyl group, a C1-C20 alkoxy group, a phenyl group, a pentalenyl group, an indenyl group, a naphthyl group, an azulenyl group, a heptalenyl group, an indacenyl group, an acenaphthyl group, a fluorenyl group, a spiro-fluorenyl group, a benzofluorenyl group, a dibenzofluorenyl group, a phenalenyl group, a phenanthrenyl group, an anthracenyl group, a fluoranthenyl group, a triphenylenyl group, a pyrenyl group, a chrysenyl group, a naphthacenyl group, a picenyl group, a perylenyl group, a pentaphenyl group, a hexacenyl group, a pentacenyl group, a rubicenyl group, a coronenyl group, an ovalenyl group, a pyrrolyl group, a thiophenyl group, a furanyl group, an imidazolyl group, a pyrazolyl group, a thiazolyl group, an isothiazolyl group, an oxazolyl group, an isoxazolyl group, a pyridyl group, a pyrazinyl group, a pyrimidinyl group, a pyridazinyl group, an isoindolyl group, an indolyl group, an indazolyl group, a purinyl group, a quinolyl group, an isoquinolyl group, benzoa quinolyl group, a phthalazinyl group, a naphthyridinyl group, a quinoxalinyl group, a quinazolinyl group, a cinnolinyl group, a carbazolyl group, a phenanthridinyl group, an acridinyl group, a phenanthrolinyl group, a phenazinyl group, a benzofluorenyl group, a benzimidazolyl group, a benzofuranyl group, a benzothiophenyl group, a benzothiazolyl group, a benzoxazolyl group, an isobenzoxazolyl group, a triazolyl group, a tetrazolyl group, an oxadiazolyl group, a triazinyl group, a dibenzofluorenyl group, a dibenzofuranyl group, a dibenzothiophenyl group, a benzocarbazolyl group, a dibenzocarbazolyl group, a thiadiazolyl group, an imidazopyridyl group, an imidazopyrimidinyl group, —N(Q11)(Q12), and —Si(Q13)(Q14)(Q15),
wherein Q11 to Q15 are each independently selected from a hydrogen atom, a C1-C10 alkyl group, a C1-C10 alkoxy group, a phenyl group, a naphthyl group, a fluorenyl group, a spiro-fluorenyl group, a benzofluorenyl group, a dibenzofluorenyl group, a phenanthrenyl group, an anthracenyl group, a triphenylenyl group, a pyrenyl group, a chrysenyl group, a pyrrolyl group, a thiophenyl group, a furanyl group, an imidazolyl group, a pyrazolyl group, a thiazolyl group, an isothiazolyl group, an oxazolyl group, an isoxazolyl group, a pyridinyl group, a pyrazinyl group, a pyrimidinyl group, a pyridazinyl group, a quinolinyl group, an isoquinolinyl group, a benzoquinolinyl group, a quinoxalinyl group, a quinazolinyl group, a carbazolyl group, a phenanthrolinyl group, a benzoimidazolyl group, a benzofuranyl group, a benzothiophenyl group, an isobenzothiazolyl group, a benzoxazolyl group, an isobenzoxazolyl group, a triazolyl group, an oxadiazolyl group, a triazinyl group, a dibenzofuranyl group, a dibenzothiophenyl group, a benzocarbazolyl group, a dibenzocarbazolyl group, a dibenzosilolyl group, a thiadiazolyl group, an imidazopyridinyl group, and an imidazopyrimidinyl group.

8. The organic light-emitting device as claimed in claim 1, wherein:
R1 to R4 are each independently selected from:
a C1-C20 alkyl group, and a group represented by one of Formulae 6A to Formula 6G:








wherein, Formulae 6A to 6G,
Z21 to Z26 are each independently selected from a deuterium atom, a halogen atom, a C1-C20 alkyl group, a C6-C40 aryl group, a monovalent C6-C40 non-aromatic condensed polycyclic group, —N(Q11)(Q12), —Si(Q13)(Q14)(Q15), Ge(Q13)(Q14)(Q15), wherein Q11 to Q15 are each independently a hydrogen atom, a C1-C20 alkyl group, or a C6-C40 aryl group;
a C1-C20 alkyl group, substituted with at least one selected from a deuterium atom and a halogen atom; and
a C6-C40 aryl group and a monovalent C6-C40 non-aromatic condensed polycyclic group, each substituted with at least one selected from a deuterium atom, a halogen atom, a C1-C20 alkyl group, and a C6-C20 aryl group;
q1 is an integer from 0 to 5;
q2 is an integer from 0 to 7;
q3 is an integer from 0 to 9;
q4 is an integer from 0 to 3;
when q2 in Formula 6E is 2 or more, a plurality of Z22 are optionally connected to be condensed to the fluorenyl group, thereby forming a condensed ring; and
* indicates a binding site to a neighboring atom.

9. The organic light-emitting device as claimed in claim 1, wherein R1 to R4 are each independently selected from a methyl group, an ethyl group, an n-propyl group, an iso-propyl group, an n-butyl group, an iso-butyl group, a sec-butyl group, a tert-butyl group, and a group represented by one of Formulae 7A to 7L:






wherein in Formulae 7A to 7L, * indicates a binding site to a neighboring atom.

10. The organic light-emitting device as claimed in claim 1, wherein:
L1 and L2 are each independently selected from a phenylene group and a naphthylene group,
Ar1 and Ar2 are each independently selected from a naphthyl group, a phenanthrenyl group, and a pyrenyl group,
R1 and R2 are each independently selected from a phenyl group, a naphthyl group, a fluorenyl group, and a benzofluorenyl group; and a phenyl group, a naphthyl group, a fluorenyl group, and a benzofluorenyl group, each substituted with at least one selected from a deuterium atom, a halogen atom, a phenyl group, and a naphthyl group,
a1 and a2 are each independently 0 or 1, and
l1 and l2 are each independently an integer from 0 to 2.

11. The organic light-emitting device as claimed in claim 1, wherein:
A is selected from a chrysenylene group, a pyrenylene group, a perylenylene group, and a fluorenylene group; and
a chrysenylene group, a pyrenylene group, a perylenylene group, and a fluorenylene group, each substituted with at least one selected from:
a deuterium atom, a halogen atom, a methyl group, an ethyl group, an n-propyl group, an iso-propyl group, an n-butyl group, an iso-butyl group, a sec-butyl group, a tert-butyl group, and a styryl group,
Ar3 to Ar6 are each independently selected from a phenyl group and a naphthyl group; and
a phenyl group and a naphthyl group, each substituted with at least one selected from a deuterium atom, a halogen atom, a methyl group, an n-propyl group, and an iso-propyl group, and
b1 and b2 are each independently 0 or 1.

12. The organic light-emitting device as claimed in claim 1, wherein, when A is a perylenylene group, b1 and b2 are 0.

13. The organic light-emitting device as claimed in claim 1, wherein:
R3 and R4 are each independently selected from:
a phenyl group, a naphthyl group, a fluorenyl group, a carbazolyl group, and a fluoranthenyl group; and
a phenyl group, a naphthyl group, a fluorenyl group, a carbazolyl group, and a fluoranthenyl group, each substituted with at least one selected from a methyl group, a phenyl group, a pyridyl group, a pyrimidyl group, and —N(Q11)(Q12), wherein Q11 and Q12 are each independently a phenyl group or a naphthyl group,
Ar7 and Ar8 are each independently selected from:
a phenyl group and a fluorenyl group; and
a phenyl group and a fluorenyl group, each substituted with at least one selected from a methyl group and a phenyl group, and
c1 and c2 are each independently 0 or 1.

14. The organic light-emitting device as claimed in claim 1, wherein the first compound is one of Compounds H-1 to H-43 below:

15. The organic light-emitting device as claimed in claim 1, wherein the second compound is one of Compounds D-1 to D-6 below:

16. The organic light-emitting device as claimed in claim 1, wherein the third compound is one of Compounds HT-1 to HT-14 below:

17. The organic light-emitting device as claimed in claim 1, wherein an amount of the second compound is in a range of about 0.01 to about 15 vol % based on a total volume of the emission layer.

18. The organic light-emitting device as claimed in claim 1, wherein an amount of the third compound is in a range of about 0.01 to about 15 vol % based on a total volume of the emission layer.

19. The organic light-emitting device as claimed in claim 1, wherein the emission layer emits blue light.

20. The organic light-emitting device as claimed in claim 1, further comprising an electron transport region between the second electrode and the emission layer.