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Material Safety Data Sheet

1. PRODUCT AND COMPANY IDENTIFICATION

ADCOTETM L76-186

Revision date: 08/25/2011

Supplier ROHM AND HAAS CANADA LP

A Subsidiary of The Dow Chemical Company

2 MANSE ROAD

WEST HILL, ON M1E 3T9 Canada

For non-emergency information contact: 416-284-4711

Fax: 416-287-4495

For non-emergency information contact: 215-592-3000

Emergency telephone number

989-636-4400

Local emergency telephone number

989-636-4400

2. COMPOSITION/INFORMATION ON INGREDIENTS

Component CAS-No. Concentration

Polyurethane resin Not Hazardous 72.0 - 74.0%

Methylenebis(4-phenyl isocyanate) 101-68-8 2.0 - 3.0%

Ethyl acetate 141-78-6 23.0 - 25.0%

3. HAZARDS IDENTIFICATION

Emergency Overview

Appearance

Form clear 

Form liquid 

Colour Light amber 
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Odour solvent-like 

Hazard Summary WARNING!

FLAMMABLE LIQUID AND VAPOR.

INHALATION OF VAPOR OR MIST CAN CAUSE THE FOLLOWING:

SHORTNESS OF BREATH

TIGHTNESS IN THE CHEST

IRRITATING TO EYES AND SKIN.

MAY CAUSE SENSITIZATION BY INHALATION AND SKIN 

CONTACT.

CLOSED CONTAINERS MAY EXPLODE WHEN HEATED OR 

CONTENTS CONTAMINATED WITH WATER.

PROLONGED OR REPEATED OVEREXPOSURE TO THE 

SOLVENT(S) IN THIS MATERIAL CAN CAUSE THE FOLLOWING:

KIDNEY DAMAGE

LIVER DAMAGE

HEART DAMAGE

CENTRAL NERVOUS SYSTEM (CNS) EFFECTS

BLOOD CHANGES

LUNG DAMAGE

Potential Health Effects

Primary Routes of Entry: Eye contact

 Inhalation

 Skin contact

Eyes: Material can cause the following:

Moderate irritation.

burning sensation

tearing

reddening

Skin: May cause sensitization by skin contact.

Material can cause the following:

Moderate irritation.

burning sensation

reddening

Itching

Ingestion: Material can cause the following:

severe irritation of the mouth, throat, and digestive tract

diarrhea

nausea

Vomiting

Abdominal pain

Inhalation: Inhalation of vapor or mist can cause the following:

coughing

irritation of nose, throat, and lungs

tightness in the chest

Shortness of breath

May cause severe allergic respiratory reaction.

Sensitisation
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Chronic Exposure: Long term exposure to diisocyanates may cause lung damage, including reduced 

lung function, which may be permanent.

Prolonged or repeated overexposure to the solvent(s) in this material can cause the following:

heart damage

Blood changes

central nervous system (CNS) effects

kidney damage

liver damage

lung damage

Methylenebis(4-phenyl isocyanate) IRIS Not classifiable.

Methylenebis(4-phenyl isocyanate) IARC Inadequate data.

Methylenebis(4-phenyl isocyanate) IARC No data.

Methylenebis(4-phenyl isocyanate) IARC No data.

Methylenebis(4-phenyl isocyanate) IARC Not classifiable as to 

carcinogenicity to humans.

Methylenebis(4-phenyl isocyanate) IRIS D: Not classifiable as to 

human carcinogenicity 

[1986 Guidelines]; 

Carcinogenic potential 

cannot be determined 

[1996 Guidelines]

4. FIRST AID MEASURES

Inhalation: Move to fresh air. If breathing is irregular or stopped, administer artificial respiration. Call a 

physician immediately.

Skin contact: Take off all contaminated clothing immediately. Wash off immediately with soap and 

plenty of water. If skin irritation persists, call a physician. Wash contaminated clothing before re-use.

Eye contact: Flush eyes with water as a precaution. If eye irritation persists, consult a specialist.

Ingestion: Never give anything by mouth to an unconscious person. If a person vomits when lying on 

his back, place him in the recovery position. Do NOT induce vomiting. Rinse mouth. Immediately give 

large quantities of water to drink. Call a physician immediately.

Notes to physician: Bronchial constriction may develop after extensive exposure to isocyanates, even 

in individuals who have not been shown to be previously sensitized.

5. FIRE-FIGHTING MEASURES

Flash point -3 °C ( 26.60 °F ) SETAFLASH CLOSED CUP

Ignition temperature 218.6 °C ( 425.48 °F) Ethyl acetate

Lower explosion limit 2.20 %(V)Ethyl acetate

Upper explosion limit 11.50 %(V)Ethyl acetate

Suitable extinguishing media:Foam

Carbon dioxide (CO2)

Dry powder

Thermal decomposition Heating or fire conditions liberates toxic gas.

Combustion Products: Hydrogen Cyanide

Carbon monoxide

Carbon dioxide

Nitrogen oxide (NO2)
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Specific hazards during fire fighting: Vapors can travel to a source of ignition and flash back. Heated 

material can form flammable or explosive vapors with air. Closed containers may rupture via pressure 

build-up when exposed to fire or extreme heat.

Special protective equipment for fire-fighters: Wear self-contained breathing apparatus and 

protective suit.

Further information: For safety reasons in case of fire, containers should be stored separately in 

closed containments.

Cool closed containers exposed to fire with water spray.

EXPLOSION HAZARD. Fight advanced fires from a protected location.

Collect contaminated fire extinguishing water separately. This must not be discharged into drains.

Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local 

regulations.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions

Use personal protective equipment.

Refer to protective measures listed in sections 7 and 8.

MATERIAL IS A POTENTIAL SENSITIZER.

If exposed to material during clean-up operations, IMMEDIATELY remove all contaminated clothing and 

wash exposed skin areas with soap and water. See SECTION 4, First Aid Measures, for further 

information.

Environmental precautions

Do not flush into surface water or sanitary sewer system.

Methods for cleaning up

Evacuate personnel to safe areas.

Remove all sources of ignition.

Ensure adequate ventilation.

Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand, earth, 

diatomaceous earth, vermiculite) and place in container for disposal according to local / national 

regulations (see section 13).

7. HANDLING AND STORAGE

Handling

Provide sufficient air exchange and/or exhaust in work rooms. Avoid exceeding of the given 

occupational exposure limits (see section 8). In case of insufficient ventilation, wear suitable respiratory 

equipment. Do not breathe vapours or spray mist. Wear personal protective equipment. For personal 

protection see section 8. Keep away from heat and sources of ignition. Take necessary action to avoid 

static electricity discharge (which might cause ignition of organic vapours). Ensure all equipment is 

electrically grounded before beginning transfer operations. May cause sensitization of susceptible 

persons by skin contact. CONTAINERS MAY BE HAZARDOUS WHEN EMPTY. Since emptied 

containers retain product residue follow all MSDS and label warnings even after container is emptied.

Storage

Storage conditions: Material can burn; limit indoor storage to approved areas equipped with automatic 

sprinklers. Keep container tightly closed in a dry and well-ventilated place. Keep away from heat and 

sources of ignition. Electrical installations / working materials must comply with the technological safety 

standards.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Exposure limit(s)

Exposure limits are listed below, if they exist.

Component Regulation Type of listing Value
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Methylenebis(4-phenyl 

isocyanate)

Rohm and Haas TWA 0.005 ppm

Rohm and Haas STEL 0.02 ppm

ACGIH TWA 0.005 ppm

NIOSH/GUIDE REL 0.05 mg/m3 0.005 ppm

NIOSH/GUIDE Ceil_Time 0.2 mg/m3 0.020 ppm

OSHA_TRANS Ceiling 0.2 mg/m3 0.02 ppm

Z1A Ceiling 0.2 mg/m3 0.02 ppm

Component Regulation Type of listing Value

Ethyl acetate Rohm and Haas TWA 150 ppm

Rohm and Haas STEL 300 ppm

ACGIH TWA 400 ppm

NIOSH/GUIDE REL 1,400 mg/m3 400 ppm

OSHA_TRANS PEL 1,400 mg/m3 400 ppm

Z1A TWA 1,400 mg/m3 400 ppm

Exposure controls

Engineering measures: Use explosion-proof local exhaust ventilation with a minimum capture 

velocity of 100 ft/min (0.5 m/sec) at the point of vapor evolution. Refer to the current edition of Industrial 

Ventilation: A Manual of Recommended Practice published by the American Conference of 

Governmental Industrial Hygienists for information on the design, installation, use, and maintenance of 

exhaust systems.

Hygiene measures: Wash hands before breaks and immediately after handling the product.

Protective measures: Facilities storing or utilizing this material should be equipped with an eyewash 

facility and a safety shower.

Individual protection measures

Eye/face protection: Use chemical splash goggles and face shield (ANSI Z87.1 or approved 

equivalent). Eye protection worn must be compatible with respiratory protection system 

employed.

Skin protection

Hand protection: Chemical-resistant gloves should be worn whenever this material is 

handled. The glove(s) listed below may provide protection against permeation. (Gloves 

of other chemically resistant materials may not provide adequate protection): 4H Glove 

(Trademark of Safety 4 A/S of Denmark) butyl-rubber Gloves should be removed and 

replaced immediately if there is any indication of degradation or chemical breakthrough. 

Before removing gloves clean them with soap and water. NOTE: Material is a possible 

skin sensitizer.

Other protection: Avoid all skin contact. Selection of specific personal protective 

equipment such as long sleeves, safety glasses with side shields, face shield, safety 

shoes, boots, apron, or full body suit will depend on the task.

Respiratory protection: A respiratory protection program meeting OSHA 1910.134 and ANSI 

Z88.2 requirements or equivalent must be followed whenever workplace conditions warrant a 

respirator‟s use. None required if airborne concentrations are maintained below the exposure 

limit listed in Exposure Limit Information. Above the exposure limit: Wear a properly fitted 

NIOSH approved (or equivalent) self-contained breathing apparatus in the pressure demand 

mode, OR full-facepiece, airline respirator in the pressure demand mode with emergency 

escape provision.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance

Form clear 

liquid 
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Colour Light amber 

Odour solvent-like 

pH not applicable

Melting point/range -84.00 °C ( -119.20 °F) Ethyl acetate

Boiling point/boiling range 77 °C ( 170.96 °F) Ethyl acetate

Flash point -3 °C ( 26.60 °F) SETAFLASH CLOSED CUP

Evaporation rate 6.20 Ethyl acetate

Lower explosion limit 2.20 %(V)Ethyl acetate

Upper explosion limit 11.50 %(V)Ethyl acetate

Relative vapour density 3.0Ethyl acetate

Water solubility insoluble

Autoignition temperature 218 °C (425.48 °F) Ethyl acetate

Density 1.15 g/cm3

Percent volatility 24 - 26 % 

NOTE: The physical data presented above are typical values and should not be construed as a 

specification.

10. STABILITY AND REACTIVITY

Hazardous reactions Stable under recommended storage conditions.

Avoid moisture.

Conditions to avoid Heat, flames and sparks. Exposure to water vapour. 

Materials to avoid Strong oxidizing agents Water 

Hazardous 

decomposition products Hydrogen Cyanide

Acetaldehyde

Isocyanate(s)

Polymerisation Hazardous polymerization will also occur if contaminated with the 

following:

- water (moisture)

11. TOXICOLOGICAL INFORMATION

Component: Methylenebis(4-phenyl isocyanate)

Acute oral toxicity LD50 rat 31,600 mg/kg

Component: Ethyl acetate

Acute oral toxicity LD50 human 6,100 mg/kg

Component: Ethyl acetate

Acute oral toxicity LD50 rat > 4,500 mg/kg

Component: Methylenebis(4-phenyl isocyanate)
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Acute inhalation toxicity LC50 rat male 4.0 h 369 mg/m3

Component: Methylenebis(4-phenyl isocyanate)

Acute inhalation toxicity LC50 rat 1 h 2.24 mg/l

Component: Methylenebis(4-phenyl isocyanate)

Acute inhalation toxicity LC50 rat female 4 h 380 mg/m3

Component: Ethyl acetate

Acute inhalation toxicity LC50 rabbit 4 h > 28.6 mg/l

Component: Methylenebis(4-phenyl isocyanate)

Acute dermal toxicity LD50 rabbit > 9,400 mg/kg

Component: Ethyl acetate

Acute dermal toxicity LD50 rabbit > 17,900 mg/kg

Component: Methylenebis(4-phenyl isocyanate)

Sensitisation Skin and respiratory sensitizer

Component: Ethyl acetate

Mutagenicity

Overall, no consistent mutagenic activity has been reported.

12. ECOLOGICAL INFORMATION

Ethyl acetate

Elimination information (persistence and degradability)

Biodegradability OECD Test Guideline 301A or Equivalent

100 %

Readily biodegradable

10-day Window: Pass

Ecotoxicity effects

Toxicity to fish LC50 Rainbow trout (Oncorhynchus mykiss) 96 h Method Not Specified

484 mg/l

Toxicity to fish LC50 Fathead minnow (Pimephales promelas) 96 h Method Not 

Specified

230 mg/l

Toxicity to algae EC50 Algae 96 h OECD Test Guideline 201

2,000 mg/l

Toxicity to aquatic 

invertebrates

EC50 Daphnia magna 48 h Method Not Specified

717 mg/l

13. DISPOSAL CONSIDERATIONS

Environmental precautions: Do not flush into surface water or sanitary sewer system.

Disposal

Waste Classification: D001
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For disposal, incinerate this material at a facility that complies with local, state, and federal regulations. 

(See 40 CFR 268)

14. TRANSPORT INFORMATION

DOT

Proper shipping name Adhesives

UN number UN 1133

Class 3

Packing group II

Reportable Quantity Ethyl acetate

IMO/IMDG

Proper shipping name ADHESIVES

UN number UN 1133

Class 3

Packing group II

Reportable Quantity Ethyl acetate

Transportation classifications may vary by container volume and may be influenced by regional or 

country variations in regulations

15. REGULATORY INFORMATION

Workplace Classification

OSHA: This product is considered hazardous under the OSHA Hazard Communication Standard 

(29 CFR 1910.1200).

WHMIS: This product is a „controlled product‟ under the Canadian Workplace Hazardous 

Materials Information System (WHMIS).

SARA TITLE III: Section 311/312 Categorizations (40CFR370): Fire Hazard

Acute Health Hazard

Chronic Health Hazard

SARA TITLE III: Section 313 Information (40CFR372)

This product contains a chemical which is listed in Section 313 at or above de minimis concentrations. 

The following listed chemicals are present: (Quantity present is found elsewhere on this MSDS.)

SARA Title III Components: Methylenebis(4-phenyl isocyanate) 101-68-8

CERCLA Information (40CFR302.4)

This material is regulated under the Comprehensive Environmental Response, Compensation and 

Liability Act (CERCLA)and the Superfund Amendments and Reauthorization Act (SARA) Title III Section 

304. This material is or contains chemical(s) listed in 40 CFR Table 302.4 or nondesignated RCRA ICR 

substance(s). (Nondesignated ICR substances apply to materials that will not be reused.) The 

Reportable Quantity(s) (RQ) are listed below. Releases in excess of its reportable quantity must be 

reported to the National Response Center (1-800-424-8802) and to the appropriate state and local 

emergency response organizations.

See Section 13, Disposal Considerations, Subsection Disposal, for CERCLA classification.

Ethyl acetate 141-78-6 5,000 lbs RQ
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US. Toxic Substances Control Act (TSCA): All components of this product are in compliance with 

the inventory listing requirements of the U.S. Toxic Substances Control Act (TSCA) Chemical 

Substance Inventory.

Pennsylvania

Any material listed as “Not Hazardous” in the CAS REG NO. column of SECTION 2, 

Composition/Information On Ingredients, of this MSDS is a trade secret under the provisions of the 

Pennsylvania Worker and Community Right-to-Know Act.

16. OTHER INFORMATION

HMIS: * = Chronic Effects (See Hazards Identification)

HMIS Hazard Rating

Health Fire Reactivity Physical 

Hazard PPE

*2 3 1

Legend

ACGIH American Conference of Governmental Industrial Hygienists

BAc Butyl acetate

OSHA Occupational Safety and Health Administration

PEL Permissible Exposure Limit

STEL Short Term Exposure Limit (STEL):

TLV Threshold Limit Value

TWA Time Weighted Average (TWA):

| Bar denotes a revision from prior MSDS.

The information provided in this Safety Data Sheet is correct to the best of our knowledge, information 

and belief at the date of its publication. The information given is designed only as a guidance for safe 

handling, use, processing, storage, transportation, disposal and release and is not to be considered a 

warranty or quality specification. The information relates only to the specific material designated and 

may not be valid for such material used in combination with any other materials or in any process, unless 

specified in the text.

Version: 1.1

Print Date: 11/09/2012

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