# November 8, 2012 CA **A Section 114 - Poly** 

**viny l Chloride and Copoly** **mers (PVC) Production Process Wastew ater**  **PVC General Company and Facility** 

**Information**
**Instructions** Please complete this worksheet for your parent company and PVC production facility

.
**Parent Company General Information** Parent Company

Name: Address: City : Country : USA Size of Com pany

(approximate number of employees including all subsidiaries, branches, and related establishments owned): **PVC Production Facility General Information** Facility Name: Facility Address: Facility City : Facility Technical Contact Name: Technical Contact Telephone Number: Technical Contact Email: Number of employees attached to the PVC production facility : 45 P.O. Box 860 CertainTeed Corporation

337-708-2722 bruce.j.brocka@saint-gobain.com Lake Charles Polyme r Plant 3300 Pete Manena Road We stlake Bruce Brocka Valley Forge

# November 8, 2012 CA **A Section 114 - Poly** 

**viny l Chloride and Copoly** **mers (PVC) Production Process Wastew ater** 

State: PA Zip Code: 19482

Size of Com pany

(approximate number of employees including all subsidiaries, branches, and related establishments owned): >1500

State: LA Zip Code: 70669

# November 8, 2012 CA **A Section 114 - Poly** 

**viny l Chloride and Copoly** **mers (PVC) Production Process Wastew ater**  **PVC Production Process Wastew ater Treatment Sy** **stem Information Update**
**Instructions**
2. Also complete the additional supplemental questions to Form C-1-c.

**FORM C-1-c PROCESS EQUIPMENT - WA** **STEWA TER STEA** **M STRIPPER** Process Unit ID: P-1 Process Equipment ID: U-12 Wa stewater Feed Rate (lb/hr): 3.5 Feed Temperature (°F): 68 Feed Inlet Pressure (psia): Liquid Loading Rate (liters/m2): Steam Feed Rate (lb/hr): Steam to Feed Ratio (kg steam/liter of wastewater): Operating Temperature (°F): 250 Operating Pressure (psig): 17 Total Number of Stages: Overall Calculated Tray Efficiency : Stripping Factor: Flow configuration (countercurrent, cocurrent): Number of Actual Trays: 1 Colum n Height (meters): 1.87 Year Equipm ent Installed: 1998 Equipm ent Currently

Regulated Under (cite regulations): 40 CFR 61 Subpart F 1. A copy

of your facility's responses on Form C-1-c of the August 21, 2009 CAA section 114 request were included with the CAA Section 114 request letter dated November XX, 2012. Please review those previous responses and update if necessary below.

# November 8, 2012 CA **A Section 114 - Poly** 

**viny l Chloride and Copoly** **mers (PVC) Production Process Wastew ater** 

**Form C-1-c Supplemental Questions** Please also provide the stripper feed rate in liters per hour, or liters for batch strippers: If the above stripper feed rate or capacity does not equal the maximum design rate or capacity , please provide those values: 1. A copy

of your facility's responses on Form C-1-c of the August 21, 2009 CAA section 114 request were included with the CAA Section 114 request letter dated November XX, 2012. Please review those previous responses and update if necessary

# Please also provide the stripper feed rate in liters per hour, or liters for batch strippers: liters/hour 465 liters If the above stripper feed rate or capacity does not equal the maximum design rate or capacity , please provide those values: liters/hour (max design) liters (max design) 1. A copy

of your facility's responses on Form C-1-c of the August 21, 2009 CAA section 114 request were included with the CAA Section 114 request letter dated November XX, 2012. Please review those previous responses and update if necessary

# November 8, 2012 CA **A Section 114 - Poly** 

**viny l Chloride and Copoly** **mers (PVC) Production Process Wastew ater**  **PVC Production Process Wastew ater Stream Information** 
**Instructions** 1. Complete a row in Table 1 below for each PVC process wastewater stream generated within the PVC production facility that exits a piece of PVC production process equipment and is not treated by a PVC production process wastewater treatment system. 2. Complete a row in Table 2 below for each PVC process wastewater stream that exits a PVC production process wastewater treatment system. 3. In Table 4, please provide the source, flow rates, and the ID of the PVC process wastewater treatment system for each stream that enters a PVC process wastewater treatment system but that does not originate from the PVC production facility

.
**Table 1. Process Wastewater Streams Not Treated by a PVC Process Wastewater Treatment System 1**  **3**

P-1 W-4 **PVC Process Unit ID**  **Name of PVC Process Wastewater Stream 2** 

**PVC Process Wastewater**  **Stream ID**

Scrubber effluent water

# Table 2. Process Wastewater Streams Exiting a PVC Process Wastewater Treatment System **1 2**  **3 4**  **5 6** 

**Min** P-1 U-12 Steam Stripping Batch W- 3

**Table 3. PVC Process Wastewater Destination Codes Table** Wa stewater treatment system Discharge without treatment by pipeline, sewer, or other conveyance to surface water Discharge to POTW , no treatment Discharge to PrOTW , no treatment Zero discharge or alternative disposal method Recycle to process Other
**Table 4. Non-PVC Production Process Wastewater Streams Entering a PVC Process Wastewater Treatment System 2**  **3**

**Min Ma** **x Ty**  **pe of Process Wastewater**  **Treatment System Is this**  **process wastewater**  **treatment system batch**  **or continuous operation?** 

**1**

Not Applicable **Source of Process Wastewater Stream Destination Description** 

**PVC Process Wastewater**  **Treatment System ID**  **PVC Process Unit ID**  **PVC Process Wastewater Stream Flow Rate**

**Process Wastewater Stream Flow Rate**

**(gallons per day) PVC Process**  **Wastewater Stream ID** 

# November 8, 2012 CA **A Section 114 - Poly** 

**viny l Chloride and Copoly** **mers (PVC) Production Process Wastew ater** 

1. Complete a row in Table 1 below for each PVC process wastewater stream generated within the PVC production facility that exits a piece of PVC production process equipment and is not treated by a PVC production process wastewater treatment system. 2. Complete a row in Table 2 below for each PVC process wastewater stream that exits a PVC production process wastewater treatment system. 3. In Table 4, please provide the source, flow rates, and the ID of the PVC process wastewater treatment system for each stream that enters a PVC process wastewater treatment system but that does not originate from the PVC production facility

.
**Table 1. Process Wastewater Streams Not Treated by a PVC Process Wastewater Treatment System 4**  **5 6**  **7 8** 

**Min Ma** **x Av** **erage** 165,600 Estimated 350

**Flow Rate Determination**  **Me thod**  **Operating Days Per Year**  **PVC Process Wastewater Stream Flow Rate**

**(gallons per day)**

# 7 **8 9**  **10 11** 

**Ma x**  **Av erage**  10 Estimated 23 SW

**Code** WWT Provide nam e of the wastewater treatment system SW Provide nam e of outfall POTW RAW Provide nam e of POTW PrOTW RAW Provide nam e of PrOTW ZEROALT Describe method RECYC Describe where in the process the stream is recycled OTHER Describe
**Table 4. Non-PVC Production Process Wastewater Streams Entering a PVC Process Wastewater Treatment System 4**  **5 6**  **7**

**Av erage**  **PVC Process Wastewater Stream**  **Destination Code** (Refer to Table 3 below)

**Process Wastewater Destination Details to Provide in Column 12 of Table 1 and Column 11 of Table 2**

**Flow Rate Determination**  **Me thod**  **PVC Process Wastewater**  **Treatment System ID**  **PVC Process Wastewater Stream Flow Rate**

**(gallons per day) Flow Rate**  **Determination Me** **thod**

**Operating Days Per Year**  **Process Wastewater Stream Flow Rate**

**(gallons per day) Operating Days**  **Per Year**

# 1. Complete a row in Table 1 below for each PVC process wastewater stream generated within the PVC production facility that exits a piece of PVC production process equipment and is not treated by a PVC production process wastewater treatment system. 3. In Table 4, please provide the source, flow rates, and the ID of the PVC process wastewater treatment system for each stream that enters a PVC process wastewater treatment system but that does not originate from the PVC production facility

.

**9 10** 

C-2 Thermal Oxidizer Scrubber **Originating PVC Process Equipment ID**  **Originating PVC Process Equipment Description** 

# 12 **13**

Outfall 001 Yes

Provide nam e of the wastewater treatment system

Describe where in the process the stream is recycled **Is this PVC process wastewater stream exposed to the atmosphere**  **at any point between the outlet of the PVC process wastewater**  **treatment system and its destination?**  **As sociated Destination**  **Information** (Refer to Table 3 below)

**Process Wastewater Destination Details to Provide in Column 12 of Table 1 and Column 11 of Table 2**

# 11 **12**

SW Outfall 001 **PVC Process Wastewater Stream Destination Code**  (Refer to Table 3 below) **As sociated Destination Information** 

# 14

**If your response in Column 3 is "Other" then please provide a description of the process wastewaetr treatment system** 

**Process Wastewater Destination Details to Provide in Column 12 of Table 1 and Column 11 of Table 2**

# 13

Yes **Is this PVC process wastewater stream exposed to the atmosphere**  **at any point between the originating PVC process equipment**  **and its destination?**

# If your response in Column 3 is "Other" then please provide a description of the process wastewaetr

### November 8, 2012 CAA Section 114 - Polyvinyl Chloride and Copolymers (PVC) Production Process Wastewater **PVC Production Process Wastewater Sampling and Analysis Data**
**Instructions** 1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system that was sampled and analyzed. Complete one worksheet for each single stream (make copies of this worksheet if necessary). 2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of the "Stream Info" worksheet. 3. Complete columns 1 through 30. Enter the sample date, resin type, stream flow rate, basis for flow rate determination, stream temperature, sample type, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed. 4. Enter any other HAP expected to be present (that are not listed in Table 10 to Subpart HHHHHHH of Part 63) in the table below. 4. For compounds that were not detected, indicate as such in the "Non-Detect?" column and prov ide the method detection limit, in ppmw, in the "Concentration (ppmw)" column. 5. Enter any notes or additional information relevant to the sampling or analysis.

**Company** CertainTeed Corporation **Facility** Lake Charles Polymer Plant **PVC Process Wastewater Treatment System ID**

**CAS No. HAP**  **Analysis Method Concentration**  **(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  107211 Ethylene glycol SW -846-8015C 64000 50400 67561 Methanol SW -846-8015C 0.25 Non-detect MDL in concentration column 0.25 Non-detect MDL in concentration column 75070 Acetaldehyde SW -846-8315A 0.094 0.0058 Non-detect MDL in concentration column 50000 Formaldehyde SW -846-8315A 0.093 0.04 51285 2,4-dinitrophenol SW -846-8270D 0.015 Estimate btw MDL and PQL 0.012 Estimate btw MDL and PQL 98862 Acetophenone SW -846-8270D 0.0034 Estimate btw MDL and PQL 0.0017 Estimate btw MDL and PQL 117817 Bis(2-ethylhexyl) phthalate (DEHP) SW -846-8270D 0.00084 Estimate btw MDL and PQL 0.000075 Non-detect MDL in concentration column 123319 Hydroquinone SW -846-8270D 0.002 Non-detect MDL in concentration column 0.002 Non-detect MDL in concentration column 108952 Phenol SW -846-8270D 0.000061 Non-detect MDL in concentration column 0.000061 Non-detect MDL in concentration column 79345 1,1,2,2-tetrachloroethane SW -846-8260B 0.00038 Non-detect MDL in concentration column 0.00038 Non-detect MDL in concentration column 106990 1,3-butadiene SW -846-8260B 0.00012 Non-detect MDL in concentration column 0.00012 Non-detect MDL in concentration column 540841 2,2,4-trimethylpentane SW -846-8260B 0.00017 Non-detect MDL in concentration column 0.00017 Non-detect MDL in concentration column 71432 Benzene SW -846-8260B 0.00021 Non-detect MDL in concentration column 0.00021 Non-detect MDL in concentration column 108907 Chlorobenzene SW -846-8260B 0.00036 Non-detect MDL in concentration column 0.00036 Non-detect MDL in concentration column 67663 Chloroform SW -846-8260B 0.0019 0.00039 Estimate btw MDL and PQL 126998 Chloroprene SW -846-8260B 0.00068 Non-detect MDL in concentration column 0.00068 Non-detect MDL in concentration column 98828 Cumene SW -846-8260B 0.00023 Non-detect MDL in concentration column 0.00023 Non-detect MDL in concentration column 75003 Ethyl chloride (Chloroethane) SW -846-8260B 0.00043 Non-detect MDL in concentration column 0.00043 Non-detect MDL in concentration column 100414 Ethylbenzene SW -846-8260B 0.0002 Non-detect MDL in concentration column 0.0002 Non-detect MDL in concentration column 107062 Ethylene dichloride (1,2-Dichloroethane) SW -846-8260B 0.00034 Non-detect MDL in concentration column 0.00034 Non-detect MDL in concentration column 75343 Ethylidene dichloride (1,1-Dichloroethane) SW -846-8260B 0.00029 Non-detect MDL in concentration column 0.00029 Non-detect MDL in concentration column 74873 Methyl chloride (Chloromethane) SW -846-8260B 0.0041 0.002 75092 Methylene chloride SW -846-8260B 0.00081 Non-detect MDL in concentration column 0.00081 Non-detect MDL in concentration column 110543 n-Hexane SW -846-8260B 0.00081 Non-detect MDL in concentration column 0.00081 Non-detect MDL in concentration column 108883 Toluene SW -846-8260B 0.00027 Non-detect MDL in concentration column 0.00027 Non-detect MDL in concentration column 71556 Methyl chloroform (1,1,1-Trichloroethane) SW -846-8260B 0.00025 Non-detect MDL in concentration column 0.00025 Non-detect MDL in concentration column 79005 1,1,2-Trichloroethane SW -846-8260B 0.00035 Non-detect MDL in concentration column 0.00035 Non-detect MDL in concentration column 108054 Vinyl acetate SW -846-8260B 0.00033 Non-detect MDL in concentration column 0.00033 Non-detect MDL in concentration column 593602 Vinyl bromide SW -846-8260B 0.00029 Non-detect MDL in concentration column 0.00029 Non-detect MDL in concentration column 75014 Vinyl chloride EPA Method 107 0.7 Analysis Method SW -846-8260B 0.3 Analysis Method SW -846-8260B 75354 Vinylidene chloride (1,1-Dichloroethylene) SW -846-8260B 0.00041 Non-detect MDL in concentration column 0.00041 Non-detect MDL in concentration column 1330207 Xylenes (isomers and mixtures) SW -846-8260B 0.0002 Non-detect MDL in concentration column 0.0002 Non-detect MDL in concentration column **Resin Type (suspension, dispersion, bulk, etc.) -->** 04/07/13 **Sample Date -->** Bulk Bulk **Stream Flow Rate (gallons per minute) -->**

L0028025-01&TC28532-1 4/11/2013&4/10/2013 **Flow Rate Determination Method -->** 10

L0027451-01&TC27843-1 L0027451&TC27843 **Lab Sample ID --> Lab Report ID -->**  **Analysis Date --> Stream Temperature (degrees F) -->**  03/27/13&03/26/13&04/03/13&03/28/13 L0028025&TC28532 **1**

not measured 10 03/25/13
Estimated **2**

70.1 degrees C conv erted to 158 degrees F Estimated**Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **3 4**  **5 6** **Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **10 7**  **8 9** **Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **12 14**  **13 11** **Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **15 16**  **17 18** **Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **19 20**  **21 22** **Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **26 23**  **24 25** **Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s) 29**  **30 27**  **28**