Emission Factor Development EX 

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## 4 1 Rj 3 4 Emtission Factor Develop for Stack Testino of Scrubber Stack at Boral Bricks, Henderson Plant in June, 1995 by METCO Kiln 1 Schedule: 43 cars/day 2,916 brick/car Brick Weight: 3.98 Ib/fired brick (ve(fied by quaiity control reports)

= 43 saf 2,916 brisk 3.98 ib I day I ton

day saf bp;ska 1 24 hr 1 2000 Ib

= 10.40 ton/hr
Kiln 2 Schedule: 43 cars/day 2,916 brick/car Brick Weight: 3.98 Ib/fired brick (verified by quality control reports)
43 saF 2,916 bdsk 3.98 ib I day I ton day eaF brisk 1 24 hr 1 2000 Ib

= 10.40 ton/hr Total = 20.79 tonlhr

Emission Factor Develoament

fiiterabie PM = [ Average Emission Rate (Ib PM / hr) ] [ Kiln Throughput (ton / hr) j

= 9.01 Ib hf

if 20.79 ton

filterable PM = 0.43 Ib/ton
Emission Factor Summary:

Pollutant Avg. Emission Rate Avg. Emission Factor PM 9.01 Ib/hr 0.43 Ib/ton SOZ 20.9 Ib/hr 1.01 Ib/ton NOx 5.37 Ib/hr 0.26 Ib/ton HF 1 1.171b/hr 1 0.0561b/ton
Notes -



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### SOURCE EMISSIONS SURVEY

OF BORAL BRICKS, INC. ABSORBER STACK (EPN-K) HENDERSON, TEXAS TACB PERMIT 21012
JUNE 1995

FILE NUMBER 95-134

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TABLE OF CONTENTS


## PAGE 1 2 7 9 11 

### 16. 18 

### INTRODUCTION SUMMARY OF RESULTS DISCUSSION OF RESULTS DESCRIPTION OF SAMPLING LOCATION SAMPLING AND ANALYTICAL PROCEDURES DESCRIPTION OF TESTS APPENDICES A. Location of Sampling Points B. Source Emissions Calculations 

## C. Calibration Data D. Field Testing Data 

## E. Analytical Data F. Reference Method Monitor Data G. Visible Emissions Data 

## H. Plant Operational Data I. TACB Permit J. Chain of Custody K. Resumes of Test Personnel

95-134 

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SOURCE EMISSIONS SURVEY BORAL BRICKS, INC. ABSORBER STACK (EPN-K) 

## HENDERSON,TEXAS TACB PERMIT 21012 ; FILE NUMBER 95-134
INTRODUCTION 

## METCO Environmental, Dallas, Texas, conducted a source emissions survey of Boral Bricks, Inc., located in Henderson, Texas, on June 28, 29, and 30, 1995. The purpose of these tests was to determine the concentrations of particulate matter, :i 

### hydrogen fluoride, sulfur dioxide, and oxides of nitrogen being emitted to the


## ~ atmosphere via the Absorber Stack (EPN-K). The visible emissions were also determined. The sampling followed the procedures set forth in the Appendix to the Code of Federal 

## Regulations, Title 40, Chapter I, Part 60, Methods 1, 2, 3B, 4, 5, 6, 7E, 9, and 1313; and in the "Sampling Procedures Manual, Texas Air Control Board, Revised July 1985." 

## The testing was observed by Mr. Greg Orr of the Texas Natural Resource Conservation Commission.



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IBM SUMMARY OF RESULTS Absorber Stack (EPN-K)

* 29.92 "Hg, 68°F (760 mm Hg, 20°C)

95-134 -6- 

# ~ Run Number 1 2 3 Date 06/29/95 06/29/95 06/30/95 Time 0953-1110 1512-1632 0825-0941 Stack Flow Rate - ACFM 84,544 87,277 85,329 Stack Flow Rate - DSCFM* 44,301 45,234 45,239 % Water Vapor -% Vol. 7.94 8.12 8.02 %CO 2 -%Vol. 2.2 2.2 2.2 %0 2 -%Vol. 17.0 17.2 17.2 % Excess Air Q Sampling Point 385 414 414 Stack Temperature -°F 463 470 452 Stack Pressure -"Hg 29.66 29.62 29.68 Sulfur Dioxide Emissions - ppm 48.2 46.5 45.2 Sulfur Dioxide Emissions - Ibs/hr 21.3 20.9 20.4 Oxides of Nitrogen Emissions - ppm 16.0 17.0 17.0 Ox of Nitrogen Emissions - Ibs/hr ides 5.08 5.51 5.51

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DISCUSSION OF RESULTS 

## The three tests for particulate matter and hydrogen fluoride appeared to be valid representations of the actual emissions during the tests. AII leak checks performed on the sampling train and the pitot tubes showed no leaks before or after each test. The indicative parameters calculated from the field data were in close agreement. The moisture percentages for the three tests were within 1.8 percent of the mean value. 

## The measured flow rates (Q s ) for the tests were within 0.8 percent of the mean value. The rates of sampling for the three tests were within the specified limits (90 to 110 percent isokinetic). The greatest deviation from 100 percent isokinetic was 1.4 percent. 

## The calculated emissions (pounds per hour) of particulate matter for the three tests showed a range of -22.9 percent to +33.3 percent variation from the mean value. The calculated emissions (pounds per hour) of hydrogen fluoride for the three tests 

## showed a range of -4.0 percent to +2.9 percent variation from the mean value. The three tests for sulfur dioxide and oxides of nitrogen appeared to be valid representations of the actual emissions during the tests. AII leak checks performed on the sampling train, the pitot tubes, and the monitor sampling system showed no leaks before or after each test. The zero and calibration drift tests of the monitor were stable with no variations greater than 3.0 percent. The calibration error check, sampling system bias check, and NO 2 to NO conversion efficiency check performed prior to testing were valid.

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## The indicative parameters calculated from the field data were in close agreement. The moisture percentages for the three tests were within 1.2 percent of the mean 

## value. The measured flow rates (Q s ) for the tests were within 1.4 percent of the mean value. The collection efficiencies between the two sulfur dioxide impingers in these tests were very 

## good, indicating that little, if any, sulfur dioxide was bypassed.
The efficiencies were as follows:
Run Number 1 2 3 Impinger #2 99.3 99.0 98.9 

### Impinger #3 0.7 1.0 1.1 Collection of 90 percent or more of the sampled sulfur dioxide in the first sulfur dioxide 

## impinger is a verification of a representative sample. The calculated emissions (pounds per hour) of sulfur dioxide for the three tests 

## showed a range of -2.2 percent to +2.1 percent variation from the mean value. The calculated emissions (pounds per hour) of oxides of nitrogen for the three tests showed a range of -5.3 percent to +2.7 percent variation from the mean value.

95-134 -8-

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### DESCRIPTION OF SAMPLING LOCATIONS 

## The sampling location on the Absorber Stack (EPN-K) is 90 feet 6 inches above the ground. The sampling ports are located 40 feet (6.73 stack diameters) downstream from the inlet to the stack and 6 feet 5 1/2 inches (1.09 stack diameters) upstream from the outlet of the .stack.



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95-134 -9-


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SAMPLING AND ANALYTICAL PROCEDURES The sampling followed the procedures set forth in the Appendix to the Code of Federal 

## Regulations, Title 40, Chapter I, Part 60, Methods 1, 2, 313, 4, 5, 6, 7E, 9, and 136; and in the "Sampling Procedures Manual, Texas Air Control Board, Revised July 1985." 

## A preliminary velocity traverse was made at each of the two ports on the stack, in order to determine the uniformity and magnitude of the flow prior to testing. Several traverse points were checked for cyclonic flow and none was found to be present.

## Twelve traverse points were sampled from each of the two ports for a total of twentyfour traverse points.

N 

## The sampling trains were leak-checked at the nozzle at 15 inches of inercury vacuum

before each test, and again after each test at the highest vacuum reading recorded during the test. This was done to predetermine the possibility of a diluted sample. 

## The pitot tube lines were checked for leaks before and after each test under both a vacuum and a pressure. The lines were also checked for clearance and the manometer was zeroed before each test. 

## An integrated orsat samples was collected and analyzed according to EPA Method 3B during each test.

95-134 -11- 

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## Particulate Matter and Hydrogen Fluoride 

## Triplicate samples for particulate matter and hydrogen fluoride were collected. The samples were taken according to EPA Methods 1, 2, 3B, 4, 5, and 13B; and the "Sampling Procedures Manual, Texas Air Control Board, Revised July 1985." For each run, samples of five-minute duration were taken isokinetically at each of the twenty-four traverse points for a total sampling time of 120 minutes. Reagent blanks were submitted. 

## The " front-half " of the sampling train contained the following components: Stainless Steel Nozzle Heated Glass Probe @ 248°F ± 25°F Heated Quartz Fiber Filter and Teflon Support @ 248°F ± 25°F 

## The " back-half " of the sampling train contained the following components: Impinger Number Contents Amount Parameter Collected 

## 1 HPLC Water 100 mi Particulate Matter and Hydrogen Fluoride 

## 2 HPLC Water 100 ml Particulate Matter and Hydrogen Fluoride .3 Empty -------- Moisture 4 Silica Gel 200 g Moisture 

## Particulate matter emissions were calculated from gravimetric analysis using both the " front-half " and " back-half " collections of the sampling train. The hydrogen fluoride samples were analyzed by ion chromatography.

95-134 -12- 14

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Sulfur Dioxide 

## Triplicate samples for sulfur dioxide were collected. The samples were taken according to EPA Methods 1, 2, 3B, 4, and 6; and the "Sampling Procedures Manual, Texas Air Control Board, Revised July 1985.° Large impingers (500 mi), as specified in EPA Method 8, were used. For each run, samples of three-minute duration 

## were taken at each of the twenty-four traverse points for a total sampling time of 72 minutes. At the conclusion of each run, the sampling train was purged for fifteen minutes with ambient air at the same rate at which the sample was taken. Reagent blanks were submitted. 

## The " front-half " of the sampling train contained the following components: Stainless Steel Nozzle Heated Glass Probe @ 248°F ± 25°F 

## Heated Glass Fiber Filter and Glass Support @ 248°F ± 25°F 

## a The " back-half " of the sampling train contained the following components:

Impinger Number Contents Amount Parameter Collected 1 80% Isopropyl Alcohol 200 ml Sulfur Trioxide 2 6% Hydrogen Peroxide 200 ml Sulfur Dioxide 3 6% Hydrogen Peroxide 200 ml Sulfur Dioxide 4 Empty ------ Moisture 5 Silica Gel 200 g Moisture

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## The isopropyl alcohol solution was checked for hydrogen peroxide contamination and none was found. 

## The samples were analyzed by barium perchlorate titration using thorin indicator. Oxides of Nitrogen 

### The oxides of nitrogen sampling was performed according to EPA Method 7E. A Thermo Environmental Model 10S Oxides of Nitrogen Analyzer (Serial Number 10S-49429-282) was used to monitor the concentrations of oxides of nitrogen during 

## each run. The reference method analyzer was operated at a range of 0 to 100 parts per million. A multi-point calibration was performed on the reference method analyzer prior to testing. An analyzer calibration error check, a sampling system bias check, and a NO 2 to NO conversion efficiency check were also conducted prior to testing. eN, 

## After each run, the zero and calibration drift of the reference method monitor was

checked. The calibration gases were as follows: Zero Nitrogen 18.7 ppm NO in N 2 (ALM 40839) 48.1 ppm NO in N 2 (BLM 3576) 85.4 ppm NO in N. (ALM 38783) 

## The reference method sampling system consisted of a heated probe; a heated glass fiber filter, a chilled condenser, and a teflon sample line. The calibration gases for the bias and drift checks were introduced upstream of the chilled condenser. 

## Calibration gas certifications are included in Appendix C.
95-134 -14- ' 

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Visible Emissions 

### The visible emissions observations were performed according to EPA Method 9. The visible emissions were recorded at fifteen-second intervals over a sixty-minute 

## observation period for a total of 240 readings.

95-134 -15-



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DESCRIPTION OF TESTS Personnel from METCO Environmental arrived at the plant at 2:30 p.m. on Wednesday, June 28, 1995. After meeting with plant personnel, the equipment was moved onto the Absorber Stack (EPN-K) and secured for the night. AII work was completed at 6:00 p.m. On Thursday, June 29, work began at 6:45 a.m. The monitor was calibrated and the equipment was prepared for testing. The first test for sulfur dioxide and oxides of nitrogen began at 9:53 a.m. Testing continued until the completion of the second test at 4:32 p.m. The first test for particulate matter and hydrogen fluoride began at 12:40 p.m. Testing continued until the completion of the second test at 7:22 p.m. The first test for visible emissions began at 6:20 p.m. and was completed at 7:20 p.m. The monitor was calibrated and the samples were recovered. The equipment was secured for the night and all work was completed at 8:30 p.m. On Friday, June 30, work began at 7:00 a.m. The monitor was calibrated and the equipment was prepared for testing. The third test for sulfur dioxide and oxides of nitrogen began at 8:25 a.m. and was completed at 9:41 a.m. The third test for particulate matter and hydrogen fluoride began at 10:18 a.m. and was completed at 12:19 p.m. The second test for visible emissions began at 8:38 a.m. Testing continued until the completion of the third test at 12:20 p.m.

957134 -16-

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## The monitor was calibrated and secured for transport. The equipment was moved off 

## of the stack and loaded into the sampling van. The samples were recovered and transported to METCO Environmental's laboratory in Dallas, Texas, for analysis and evaluation. Operations at Boral Bricks, Inc., Absorber Stack (EPN-K), located in Henderson, Texas, were completed at 3:00 p.m. on Friday, June 30, 1995.

. , Billy J. Mullins, Jr., P.E. President
95-134 -17- 1-7

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APPENDICES
A. Location of Sampling Points B. Source Emissions Calculations 

## C. Calibration Data D. Field Testing Data E. Analytical Data F. Reference Method Monitor Data G. Visible Emissions Data 

## H. Plant Operational Data I. TACB Permit J. Chain of Custody K. Resumes of Test Personnel

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APPENDIX A 

### Location of Sampling Points Absorber Stack (EPN-K) 

## The sampling ports are located 40 feet (6.73 stack diameters) downstream from the inlet to the stack and 6 feet 5 1/2 inches (1.09 stack diameters) upstream from the outlet of the stack. The locations of the sampling points were calculated as follows:
Port and Wall Thickness = 6 1/4 inches Inside Stack Diameter = 71 3/8 inches
Point Percent of Diameter Distance 

### Number From Wall From Wall 1 2.1 1 1/2 " 2 6.7 4 13/16 " 3 11.8 8 7/16 " 4 17.7 12 5/8 " 5 25.0 17 7/8 " 6 35.6 25 7/16 " 7 64.4 45 15/16 " 8 75.0 53 1/2 " 9 82.3 58 3/4 " 10 88.2 62 15/16 " 11 93.3 66 9/16 " 12 97.9 69 7/8 "

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### APPENDIX A Location of Sampling Points Absorber Stack (EPN-K)



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### APPENDIX B 

## Nomenclature and Equations



## for Calculation of Source Emissions

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NOMENCLATURE FOR PARTICULATE CALCULATIONS English Metric Symbol Units Units Description 

### A s in. 2 m 2 Stack Area 

## C an gr/dscf* g/dscm* Particulate - probe, cyclone, and filter C ao gr/dscf* g/dscm* Particulate - total

gr/CF C at C~ 

## stack g/m 3 Particulate - probe, cyclone, and filter

conditions gr/CF 

## C a „ C

~ 

## stack g/m 3 Particulate - total conditions 

## C aW Ibs/hr kg/hr Particulate - probe, cyclone, and filter Cax Ibs/hr kg/hr Particulate - total C P Pitot Tube Calibration Factor D n in. m Sampling Nozzle Diameter %EA Percent Excess Air at sampling point g 32.2 ftlsec

2 Acceleration of Gravity %I Percent Isokinetic %M Percent Moisture in the stack gas by volume M d Mole fraction of dry gas
m f mg mg Particulate - probe, cyclone, and filter * 29.92 "Hg, 68°F (760 mm Hg, 20°C) B-2 

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### English Metric

Symbol Units Units 

### M Water 181b/Ib-mole m, mg mg MW Ib/Ib-mole g/g-mole M W air 28.95 Ib/

Ib-mole MW d Ib/Ib-mole g/g-mole P b "Hg mm Hg

Absolute P m "H 2 0 mm H 2 0 P s "Hg mm Hg

Absolute AP "H 2 0 mm H 2 0 P std 29.92 "Hg 760 mm Hg Q a ACFM m 3 /hr
Q 3 DSCFM* dscm/hr*
R 21.83 "Hgft 3 /Ib-mole°R 

## T m ° F ° C Description 

### Molecular Weight of water 

## Particulate - total Molecular Weight of stack gas Molecular Weight of air Molecular Weight of dry stack gas Barometric Pressure Orifice Pressure drop Stack Pressure 

## Velocity Head of stack gas Standard Barometric Pressure 

## Stack Gas Volume at actual stack conditions Stack Gas Volume at 29.92 "Hg, 528°R, dry 

## Universal Gas Constant Average Gas Meter Temperature

* 29.92 "Hg, 68°F (760 mm Hg, 20°C) B-3

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English Metric Symbol Units Units T t min min 

### T. ° 

### F ° 

### C T s , d 528°R 293°K 

### V m ft 3 m 3

Vmstd dscf* dscm*

V s fpm m/sec 

## V. ml ml
Vw 9as scf'` scm'`
pair 0.07481bs/ft 3
Pwater 1 g/m I 

### Pman 51.631bS/ft 3 Description Net time of test 

## Stack Temperature Standard Temperature Volume of dry gas sampled @ meter conditions 

## Volume of dry gas sampled @ standard conditions Stack velocity @ stack conditions Total water collected in impingers and silica gel Volume of water vapor collected @ standard conditions Density of Air Density of Water Density of Manometer Oil Standard Conditions: 29.92 "Hg, 68°F (760 mm Hg, 20°C)

'` 29.92 "Hg, 68°F (760 mm Hg, 20°C) B-4~ 

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4. Mole fraction of dry gas.

_ 

# 100 - %M Md 

### 100 

## 5. Average molecular weight of dry stack gas.
MW —%CO x 44 +%O x 32 +%N x 28 +%CO x 28 = IbJlb-mole d 2 100 2 100 2 100 100 

### = g/g-mole 

### 6. Molecular weight of stack gas.
MW = MW d x M

d + 

### 18 (1-M

d ) = 

### Ib

= glg-mole Ib-mole


### 7. Percent excess air at sampling point.
%EA = 

### 100 (%0 2 - 0.5% CO) 

### 0.265 (%N 2 ) - [(%0 2 ) 

### + 0.5 (%CO)]



### 8. Stack Pressure.



## Stack 

## Pressure "H O P S = P b + 2 = "Hg Absolute



### 13.6
P s ="Hg Abs. x 

### 25.4 + mm Hg .~ I



### '` 29.92 "Hg, 68°F (760 mm Hg, 20°C) B-6_7 

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9. Stack velocity at stack coriditions.

2 

### V— C 60

2g x P man x Pstd



### x MW a „ x(T s + 460) x OP

s
S 

### P 12 xP air 

### xPsxMWxTstd

2 

### ( T + 460) V s = 5,123.8 Cp Ps x MW FP a verage = fpm

V s = fpm x 0.00508 = m/sec



## 10. Dry stack gas volume at standard conditions.*

1 Tstd Ps 

### QS __ 144 VS x A S

x M d x T S + 460 x

Psrd Q _ 0.12 

### 3 V

S xA s xM

d xP s = DSCFM S 

### T

s + 460 Q s = DSCFM x 1.6990 = dscm/hr


## 11. Actual stack gas volume at stack conditions.

Qa V 

### 144 s= ACFM
Q a = ACFM x 1.6990 = m 3 /hr

* 29.92 "Hg, 68°F (760 mm Hg, 20°C) B-7 ~



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12. Percent isokinetic.
/o al Vm s t d x(T s + 

### 460) x 

### P srd x 

### 100 x 

### 144 = 

### M d

x T std x P s x T t x VS n 

### D" 4

0 

### 1039 V

srd x(T 

# /o S

+ 460)
~ 

# _ M d xP s XT t XV S XD~



### 13. Particulate - probe, cyclone, and filter.

0 

# _ m, 1 gr

Can x 

### Vmsrd 

### 64.8 mg


### C a „ = 0.0154 x

m ' 

### = gr/dscP' Vmsrd 

### C an = grldscf x 2.290 = g/dscm*


## 14. Particulate total.
C ao = 0.0154 X mt

= grldscf Vmsrd 

### C ao = gr/dscf x 2.290 = gldscm*



### * 29.92 "Hg, 68°F (760 mm Hg, 20°C) B-8_-I 

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## 15. Particulate - probe, cyclone, and filter at stack conditions.

PS ( Tsrd) 

### Ca t 

### __ Can X Pstd X (T

S + 

### 460) X M

d

C


### _ = 

### 17.65 XCanXPsXMd r/CF a 

### ` T

S + 460 g
C at = gr/CF x 

### 2.290 = glm 3 

## 16. Particulate - total, at stack conditions.
C 

### _ 17.65 X C ao X



### P s x M d 

### = gr/CF a 

### " — T

S + 460 

### C au = grlCF x 2.290 = g/m 3
17. Particulate - probe, cyclone, and filter. C C XQ X 60min x 1/b aw — — an 

### S 

### 1 hr 

### 7000 gr 

### C aw = 0.00857 x C an X Q s = Ibs/hr
C aw = Ibslhr x 

### 0.4536 = kglhr 

## 18. Particulate - total. C aX = 

### 0.00857 x C ao x Q S = Ibslhr
C aX = Ibslhr x 

### 0.4536 = kglhr 

### * 29.92 "Hg, 68°F (760 mm Hg, 20°C) B-9

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EXAMPLE CALCULATIONS

Ibs/hr = mg_ 

### x 2.205 x 10" 6 Ibs/mg x DSCFM* x 60 min/hr

Vmstd
Vm s , a = Volume of dry gas sampled (dscf") DSCFM* = Stack Flow Rate

ppm = mq 

### x 24.04 

### Vms,d (m 3 ) MW


### 24.04 = Ideal Gas Constant liters/g-mole Vmstd = Volume of dry gas sampled (m 3 ") MW = Molecular Weight Compound Molecular Weight 

### Hydrogen Fluoride 20.01
* 29.92 "Hg, 68°F (760 mm Hg, 20°C)



## B 

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### EXAMPLE CALCULATIONS

Ibs/hr = ppm x CF x 60 min/hr x DSCFM* CF = Conversion Factor for ppm to Ibs/scf" 

### Compound Conversion Factor NO X 1.194 x 10"'

* 29.92 "Hg, 68°F (760 mm Hg, 20°C)

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EXAMPLE CALCULATIONS 

## Equation 6C-1

C 

# ma _ ~ _

~ ' 

# ~ Cgas — 

### C. - (i o Where: C gas = Effluent gas concentration - dry basis (ppm)

- 

### 0= Average gas concentration indicated by gas ana/yzer - dry basis (ppm) C o = Average of initial and final system calibration bias check responses for the zero gas (ppm) C m = Average of initial and final system calibration bias check responses for the upsca/e calibration gas (ppm) C ma = Actual concentration of the upsca/e calibration gas (ppm) ~



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SOURCE EMISSION SURVEY

~ JOB NUMBER: 95-134

JOB NAME: BORAL BRICK INC. LOCATION: HENDERSON, TEXAS UNIT TESTED: ABSORBER STACK (EPN - K) PART/HF
SOURCE EMISSION CALCULATIONS
SYMBOL DESCRIPTION

-----------------------------------------------------------------I UNITS I ----------------a I RUN # 1 I

1 1 1 --------------------I

1 I I --------------------I

2 1 1 --------------------I

3 1 I I 1 DATE I I

1 I I 1 I I 6-29-95 1 I I 6-29-95 1 I I 6-30-95 1

I I BEGIN 1 1 1240 1 1718 1 1018 I TIME I I I I t I I END I

1 I 1 I

14491 I

1922 1 1219 1 1 TIME I I I I I I I I P(b) I

I BAROMETRIC PRESSURE "Hg Abs. 1 I 29.70 1 I

29.66 1 I

29.721 I 1 I

1 (mm Hg) 1 1 (754)1

I (753)1

1 (755)1 `

1 1 P(m) I ORIFICE PRESSURE DROP "H20 1 1.1061 1.079 1 1.075 1 I I I

I (mm H20) 1 1 (28.1)1

1 (27.4)1

1 (27.3)1

1 1 V(m) I VOLUME DRY GAS SAMPLED ft.^3 1 74.315 1 74.035 1 72.762 1 i 1 @ METER CONDITIONS (m^3) 1 1 (2.104)1

1 (2.096)1

1 (2.060)1

1 1 1 T(m) 1

I AVERAGE GAS METER DEG.F 1 851 86 1 81 1 I 1 TEMPERATURE (DEG.C) 1 (29)1 (30)1 1 (27)1

1 I 1 V(m[std])' 1

I VOLUME DRY GAS SAMPLED 1 DSCF 1 1

71.675 1 71.174 1 70.738 1 I I 1 @ STANDARD CONDITIONS'

1 (DSCM) 1 1 (2.030)1

1 (2.015)1

1 (2.003)1

1 1 V(w) I TOTAL WATER COLLECTED, ml 1 122.2 1 125.9 1 122.8 1 1 1 IMPINGERS & SILICA GEL I I I I I

I 1 I V(w(gas]) I

I VOLUME WATER VAPOR I SCF 1 I

5.768 1 5.942 1 5.796 1 I I COLLECTED @ STANDARD (SCM) 1 (0.163)1 (0.168)1 (0.164)1 1 1 CONDITIONS' I I I I I%M I MOISTURE IN STACK GAS % 1 7.45 1 7.71 1 7.57 1 1 1 BY VOLUME I I I I

' 68 Deg.F, 29.92 "Hg (20 Deg.C, 760 mm Hg) 

### B-13 ;

# ~

FA 

# MEK0

SOURCE EMISSION CALCULATIONS BORAL BRICK INC. HENDERSON,TEXAS ABSORBER STACK (EPN - K) PART/HF SYMBOL ----------------a DESCRIPTION UNITS Md -----------------------------------------------------------------I

I MOL FRACTION OF DRY GAS I 1 I --------------------I 0.9255 1 I --------------------I 0.9229 1 I --------------------I 0.9243 1 I CO2 I

I 1 I % 1

1 I

2.1 1 1 I

2.21' 1 I

2.01 1 02 1

1 1 1 % 1

1 1

17.31 1 1

17.01 1 1

17.21 1 CO 1

I I 1 % 1

I 1

0.01 I 1

0.01 I 1

0.01 I N2 I

I 1 I % 1

1 I

80.6 1 1 I

80.8 1 1 I

80.8 1 1 '/oEA 1

I EXCESS AIR @ SAMPLING 1 % 1 1 426.2 1 1

385.3 1 1

408.4 1 1 POINT I I I I VIWd I

I MOLECULAR WEIGHT OF I LB/LB-MOLE 1 I 29.03 1 I

29.03 1 I

29.01 1 1 DRY STACK GAS I (g/g-MOLE) 1 1 (29.03)1

1 (29.03)1

1 (29.01)1 VIW I MOLECULAR WEIGHT OF LB/LB-MOLE 1 28.21 1 28.181 1 28.171 1 STACK GAS 1 (g/g-MOLE) 1 i (28.21)1

1 (28.18)1 (28.17)1 DELTA P I VELOCITY HEAD OF STACK "H20 1 0.4871 1 0.478 1 1

0.470 1 1 GAS I (mm H20) 1 I (12.4)1

I (12.1)1

I (11.9)1 Fs I STACK TEMPERATURE DEG. F 1 472 1 472 1 I 459 1 1 1 (DEG. C) 1 1 (244)1

1 (244)1

1 (237)1 's I STACK PRESSURE "Hg Abs. 1 29.66 1 29.62 1 1 29.681 1 1 (mm Hg) 1 1 (753)1

1 (752)1

1 (754)1

1 ✓ s I STACK VELOCITY @ STACK FPM 1 3,041 1 3,018 1 2,968 1

1 CONDITIONS 1 (m/SEC.) 1 1 (15.45)1

1 (15.33)1

1 (15.08)1

1 \s I STACK AREA (SQ.INCHES) 1 4,001 1 4,001 1 4,001 1

I I (SQ.METERS) I 1 (2.58)1

1 (2.58)1

1 (2.58)1

1 )s I DRY STACK GAS VOLUME @ DSCFM 1 44,078 1 43,563 1 43,601 1

1 STANDARD CONDITIONS' 1 (DSCM/HR) 1 1 (74,889)1

1 (74,014)1

1 (74,078)1

1 )a I ACTUAL STACK GAS VOLUME ACFM 1 84,480 1 83,852 1 82,471 1

I @ STACK CONDITIONS (m^3/HR) 1 (143,532)1 (142,465)1 (140,118)1 ' 68 Deg.F, 29.92 "Hg (20 Deg.C, 760 mm Hg)

# MEMO

~ 

### J Ef1VIR0(1fTl>=(TfAI

SOURCE EMISSION CALCULATIONS BORAL BRICK INC. 

### HENDERSON,TEXAS ABSORBER STACK (EPN - K) PART/HF

(o UNITS ---------------I MINUTES


### IN. (m) % SYMBOL DESCRIPTION ----------------a ----------------------------------------------- Tt I NET TIME OF TEST

I I Dn I SAMPLING NOZZLE DIAM.
%I I PERCENT ISOKINETIC

I Mf I

I PARTICULATE - PROBE, I CYCLONE AND FILTER Mt 

### I

I PARTICULATE - TOTAL 

### I Can I

I PARTICULATE - PROBE, I CYCLONE AND FILTER I Cao I PARTICULATE - TOTAL

I Cat I

I PARTIC.-PROBE, CYCLONE I AND FILTER @ STACK COND. I Cau I PARTICULATE - TOTAL @

I STACK CONDITIONS I Caw I PARTICULATE - PROBE,

I CYCLONE AND FILTER I :,ax I PARTICULATE - TOTAL

I 1201 1 ------------I --------------------I

1201 1 --------------------1

1201 1 1 0.262 1 1

0.262 1 1

0.262 1 (0.007)1 1 (0.007)1

1 (0.007)1

1 100.91 1 101.41

1 100.71

1 1 60.4 1 1 1

100.51 f 1

81.01 1 I 99.4 1 1 1

148.71 1 1

85.31 1 1 0.0130 1 1

0.0217 1 1

0.0176 1 (0.0297)1 1 (0.0498)1

1 (0.0404)1

1 0.0214 1 0.0322 1 0.0186 1 (0.0489)1 1 (0.0737)1

1 (0.0425)1

1 0.0067 1 0.0113 1 0.0093 1 (0.0154)1 1 (0.0258)1

1 (0.0213)1

1 0.0111 1 0.0167 1 0.0098 1 (0.0254)1 1 (0.0382)1

1 (0.0224)1

1 4.90 1 8.12 1 6.59 1 (2.22)1 1 (3.68)1

1 (2.99)1

1 8.07 1 12.01 1 6.94 1 (3.66)1 (5.45)1 (3.15)1 

### mg
mg gr/DSCF* (g/DSCM) gr/DSCF* (g/DSCM) gr/CF (g/m3) gr/CF (g/m3) LBS/HR (Kg/HR) LBS/HR I (Kg/HR) I * 68 Deg.F, 29.92 "Hg (20 Deg.C, 760 mm Hg)



### B-1S 

# 9 rDATE I I I BEGIN I TIME I

I END I TIME I

I P(b) I BAROMETRIC PRESSURE

I I P(m) I ORIFICE PRESSURE DROP

I i V(m) I VOLUME DRY GAS SAMPLED

I @ METER CONDITIONS I T(m) I AVERAGE GAS METER

I TEMPERATURE I V(m[std])* I VOLUME DRY GAS SAMPLED

I @ STANDARD CONDITIONS* V(w) i

I TOTAL WATER COLLECTED, I IMPINGERS & SILICA GEL I V(w[gas]) I VOLUME WATER VAPOR

I COLLECTED @ STANDARD I CONDITIONS* %M I MOISTURE IN STACK GAS

I BY VOLUME Tt I

I NET TIME OF TEST * 68 Deg.F, 29.92 "Hg (20 Deg.C, 760 mm Hg) 

# MEMO



# [_J E(1VIR0(1(TlE(17A1

SOURCE EMISSION SURVEY
JOB NUMBER: 95-134 JOB NAME: BORAL BRICK INC. LOCATION: HENDERSON, TEXAS UNIT TESTED: ABSORBER STACK (EPN - K) S02
SOURCE EMISSION CALCULATIONS
SYMBOL DESCRIPTION ----------------I -------------------------- RUN # I UNITS
--- — --------------- I --------------------I

1 1 11

I --------------------I

21 1 --------------------I

31 1 1 1 I I 6-29-95 1 I 1 6-29-95 1

I 1 6-30-95 1

I I I I I

0953 1 I I

1512 1 I I

0825 1 I I 1 I I

11101 I I

1632 1 I i

0941 1 I "Hg Abs. 1 29.70 1 29.66 1 29.72 1 (mm Hg) 1

1 (754)1

1 (753)1

1 (755) i

1 "H 20 1 0.971 1 1.0001 1.0001 (mm H20) 1

1 (24.7)1

1 (25.4)1

1 (25.4)1

1 ft^3 1 42.285 1 43.234 1 42.151 1 (m^3) 1 (1.197)1 (1.224)1 1 (1.194)1

1 1 DEG.F 1 1 761 881 731 (DEG.C) 1

1 (24)1

1 (31)1

1 (23)1

1 DSCF 1 41.454.1 41.4031 41.5861 (DSCM) 1

1 (1.174),I

1 (1.172)1

1 (1.178)1

1 ml 1

1 75.8 1

1 77.5 1

1 76.8 1

1 1 SCF 1 1

3.578) 1

3.6581 1

3.6251 (SCM) 1

1 (0.101)1

1 (0.104)1

1 (0.103)1

1 % 1 1 7.941

1 8.12 1

1 8.021

1 1 MINUTES 1 1 72 1 1

72 1 1

72 1
B-16 

# 3

# METCO- e C~J 

### NIVIROf1fYlEf1TAL

FM. SOURCE EMISSION CALCULATIONS BORAL BRICK INC. HENDERSON,TEXAS ABSORBER STACK (EPN - K) S02 SYMBOL ----------------4 DESCRIPTION

-----------------------------------------------------------------I UNITS Md I MOL FRACTION OF DRY GAS

I 1 I --------------------I 0.9206 1 I --------------------I 0.9188 1 I --------------------I 0.9198 1 I CO2 I

I 1 I % 1

1 I

2.21 1 I

2.2 1 1 I

2.2 1 1 02 1

1 I 1 % 1

I 1

17.01 I 1

17.21 I 1

17.2 1 I CO I

I I I % 1

I I

0.01 I I

0.01 I I

0.0 1 I N2 I

I 1 I % 1

I I

80.8 1 I I

80.6 1 I I

80.6 1 I %EA I

I EXCESS AIR @ SAMPLING I % 1 I 385.3 1 I

413.61 I

413.6 1 1 POINT I I I I I MWd I

I MOLECULAR WEIGHT OF LB/LB-MOLE 1 I 29.03 1 I

29.04 1 I

29.04 1 1 DRY STACK GAS 1 (g/g-MOLE) 1 1 (29.03)1

1 (29.04)1

1 (29.04)1

1 MW I MOLECULAR WEIGHT OF LB/LB-MOLE 1 28.161 28.141 28.15 1

1 STACK GAS 1 (g/g-MOLE) 1 1 (28.16)1

1 (28.14)1

1 (28.15)1

1 DELTA P I VELOCITY HEAD OF STACK "H20 1 0.486 1 0.5131 0.506 1

1 GAS (mm H20) 1 (12.3)1 (13.0)1 1 (12.9)1

1 Ts 1

I STACK TEMPERATURE 1 DEG. F 1 1 463 1 470 1 452 1 1 1 (DEG. C) 1 1 (239)1

1 (243)1

1 (233)1

1 Ps I STACK PRESSURE "Hg Abs. 1 29.66 1 29.62 1 29.68 1

1 1 (mm Hg) 1 1 (753) I

1 (752)1

1 (754)1

1 Vs I STACK VELOCITY @ STACK FPM 1 3,043 1 3;141 1 3,071 1

1 CONDITIONS (m/SEC.) 1 (15.46)1 (.15.96)1 1 (15.60)1

1 As 1

I STACK AREA 1 (SQ.INCHES) 1 1 4,001 1 4,001 1 4,001 1 I I (SQ.METERS) I 1 (2.58)1

1 (2.58)1

1 (2.58)1

1 Qs I DRY STACK GAS VOLUME @ DSCFM 1 44,301 1 45,234 1 45,239 1

1 STANDARD CONDITIONS' (DSCM/HR) 1 (75,267)1 (76,853)1 1 (76,861)1

1 Qa 1

I ACTUAL STACK GAS VOLUME 1 ACFM 1 1 84,544 1 87,277 1 85,329 1 1 @ STACK CONDITIONS (m^3/HR) 1 (143,640)1 (148,284)1 (144,974)1 ` 68 Deg.F, 29.92 "Hg (20 Deg.C, 760 mm Hg) 

### B-17IN 

# F 

# ?l 

# ms o Ef1VIR0(1(71Ef1TAl

SULFUR DIOXIDE EMISSION DATA JOB NUMBER: 95-134 JOB NAME: BORAL BRICK INC. LOCATION: HENDERSON, TEXAS UNIT TESTED: ABSORBER STACK (EPN - K) I S02 I--------------------------------------------- I RUN NUMBER 1 --------------------------------------------- ------------------I ------------------I 1 1 I 2 ------------------I 3 I DATE 1 1 6-29-95 I 6-29-95 6-30-95

--------------------------------------------- I START TIME 1 1 0953 I 1512 0825

--------------------------------------------- I END TIME 1 1 1110 I 1632 0941

--------------------------------------------- I N- NORMALITY OF Ba(CI04)2 I ---------------------------- 1 0.0100 I 0.0100 0.0100

- ------------ -- I ML(I)- ml IN IMPINGER 2 1 1 380.00 I 395.00 400.00

-- ------------ - ---------------- ---------- I ML(I)- ml IN IMPINGER 3 1 335.00 I 444.00 330.00 1 ------------------------- - ------ - ----- ---- I ML(A)- ml IN ALIQUOT #2 1 1 3.00 I 3.00 3.00

--------------------------------------------- I ML(A)- ml IN ALIQUOT #3 1 10.00 I 10.00 10.00 I -- ----- -- -------------- -------------------- . I ML(B) - mi OF Ba(CI04)2 TO TITRATE #2 1 3.73 I 145 3.33 1 ---------------------------------- ---------- I ML(B) - ml OF Ba(CI04)2 TO TITRATE #3 1 ---------------------------- - ---------- -_- 1 0.15 I 0.15 0.20 I ML(BB) - ml OF Ba(CI04)2 TO TITRATE BLANK 1 -- -------------- - ------ - ---- - ---- -------- 1 0.05 I 0.05 0.05 I Tm - AVERAGE GAS METER TEMPERATURE, DEG.F 1 76 I 88 73 1 --------------------------------------------- I Vm - VOLUME OF DRY GAS SAMPLED @ METER 1 42.285 43.234 42.151 1 CONDITIONS, FT^3 I --------------------------------- I I ----------- I Pb - BAROMETRIC PRESSURE, "Hg Abs. 1 29.70 I 29.66 29.72 1 --------------------------------------------- I Qs - STACK GAS VOLUME DRY @ STANDARD 1 44,301 45,234 45,239 1 CONDITIONS, 'SCFM I ----------------------------- I I - ----- -------- I C(I) - S02 IN IMPINGER #2 IN mgs 1 149.16 143.25 139.95 1 -------------------------- - ------ - --- ---- I C(I) - S02 IN IMPINGER #3 IN mgs I 1 1.07 1.42 1.58 1 -------------------------------------------- I C(T) - TOTAL S02 IN IMPINGERS, IN mgs I 1 150.2 I 144.7 141.5 1 --------------------------------------------- I ppm S02 1 48.2 46.5 45.2 1 --------------------------------------------- 1 C(S02) - EMISSION RATE OF S02, Ibs/day I 1 510.5 I 502.6 489.6 1 --------------------------------------------- 1 C(S02) - EMISSION RATE OF S02, Ibs/hr 1 21.3 I 20.9 20.4 1 --------------------------------------------- I Cs - EMISSION RATE OF SULFUR, Ibs/day I --------------------------------------------- 1 255.2 I 251.3 244.8 ' 68 Deg.F, 29.92 "Hg (20 Deg.C, 760 mm Hg) C(I) = ML(I) '[ ML(B) - ML(BB) ]' N - 32 / ML(A) C(T) = C(I) #2 + C(I) #3 ppm S02 = 0.7513 ' C(T) '[ Tm + 460 ]/ Vm ' Pb C(S02) = ppm S02 ' Os ' 0.0002392 3_ 1 s 

# ~

~



# Jc /~



### ... ~ 

### i 

# MEFCO.

~ 

### 1 Ef1VIR0(1fYlG1TAl

SULFUR TRIOXIDE EMISSION DATA JOB NUMBER: 95-134 JOB NAME: BORAL BRICK INC. LOCATION: HENDERSON, TEXAS UNIT TESTED:

--------------------------------------------- ABSORBER STACK (EPN - K) I ------------------I ------------------I S02 RUN NUMBER
--------------------------------------------- 1 1 I 2 ------------------I 3 DATE
--------------------------------------------- 1 6-29-95 I 6-29-95 6-30-95 START TIME
--------------------------------------------- 1 0953 I 1512 0825 END TIME 1 1110 I 1632 0941
--------------------------------------------- N- NORMALITY OF Ba(CI04)2 1 0.0100 I 0.0100 0.0100

--------------------------------------------- ML(I) - ml IN IMPINGER
--------------------------------------------- 1 208.00 I 300.00 262.00 ML(A) - ml IN ALIQUOT
--------------------------------------------- 1 10.00 I 10.00 10.00 ML(B) - ml OF Ba(CI04)2 TO TITRATE 1 0.63 0.45 0.70

--------------------------------------------- ML(BB) - ml OF Ba(CI04)2 TO TITRATE BLANK I 1 0.05 0.05 0.05

--------------------------------------------- Tm - AVERAGE GAS METER TEMPERATURE, DEG.F I 1 76 I 88 73

--------------------------------------------- Vm - VOLUME OF DRY GAS SAMPLED @ METER 1 42.285 43.234 42.151 CONDITIONS, FT^3
--------------------------------------------- I I Pb - BAROMETRIC PRESSURE, "Hg Abs. 1 29.70 I 29.66 29.72

--------------------------------------------- Qs - STACK GAS VOLUME DRY @ STANDARD 1 44,301 45,234 45,239 CONDITIONS, 'SCFM
--------------------------------------------- I I C(I) - S03 IN IMPINGERS IN mgs
--------------------------------------------- 1 4.8 I 4.8 6.8 ppm S03
--------------------------------------------- 1 1.2 I 1.2 1.7 C(S03) - EMISSION RATE OF S03, Ibs/day
--------------------------------------------- 1 16.4 I 16.7 23.6 Cs - EMISSION RATE OF SULFUR, Ibs/day

--------------------------------------------- 1 6.6 I 6.7 9.4 ' 68 Deg.F, 29.92 "Hg (20 Deg.C, 760 mm Hg) C(I) = ML(I) '[ ML(B) - ML(BB) ]' N' 40 / ML(A) ppm S03 = 0.6021 ' C(I) '[ Tm + 460 ]! Vm ' Pb C(S03) = ppm S03 ' Qs ' 0.0002991 Cs = C(S03) / 2.5

B-19 

# le

## ~ 

# FI MEM0, Ef1VIR0(1(11Ff7fAl

Equipment Pitot Tube #17-10-1 (56) 

### Pitot Tube #HT-4 Pitot Tube #12-10-1 (29) Probe Tip #17-4 (II-4) APPENDIX C


## Calibration Data

Calibration Factor 0.814 0.809 0.808
0.262 

## Calibration Date 04/11/95 04/06/95 04/20/95
04/11/95 Dry Gas Meter #17-2 (17) 1.005 04/11/95 Stack Unit Orifice #17-2 (17) 04/11 /95 Digital Temperature Indicator #17-2 (17) 04/11/95 Barometer #17-2 (10) 04/10/95

95-134 C-1 

# RE K 1 , 1 0 i ~

## ~ PITO`l' TUBE CALIBRA"I'ION

Date: 'fime: 

### /.` /y Pitot No. /-(O- b' -„ Hg Pitot Dimensions: /p' T s : G ~

~ F

_ 

### CALIBRATOR Pfotor fps STANDARD STANDARD CAL. Settine mark START END AVERAGE , HIGH IIIGH FACTOR P s :

— 

### "H 2 0 C pstd: ( )

. q~
CAL, LOIV ~ CIV FAr

- rr 4 20 O(0 c:.lu 0

, 3 16 a.l.S s 9 - - 7 6.808 387 n. P,C4 20 30 D.ClGR D.

~ ; - 6G `” D. 0,' : .154; 31 40 0 SS 3 Ci ) 0.10 1& 6 0'7 , I G 39 50 O.S , b. V 95 - O.P 1 0.qc0 p. Ct3 ~ 0

~ ?' U.Roo 49 60 ~~ o.0 0. 9,9 q i. I cR .' 0'l l. v 1.colS 0 80 8 57 70 ton 0.r{2 ~ i.S"e, l, 2 2 5 - U,o 68 80 ;, ~ /. iqo i 9 /,396 0. SOP, 0 qlq 0.'79 76 90 l.rr 1.6o /.2LS 2-35 /.S 3 JI 0. ", L7 2_v ~ y .- ,, o.

39 SO O.Sy O.Sq 0.7 S 2 O. ioo C:.°ct'. o. , 0.9 00 O. 0 c

~ 39 50



### Average p ; 0. 0

Summary of Results: Normal higlt side calibration factor '? ~ ~ variation 0. 74"% 

### N'ormal low side calibration factor variation



### Signature of Calibrator

✓ 

# `.

~ 

# 4L~ P ITO'I' TUBC CALI BRATION

Date: 

### y - (0 - `J5 7 'C.imc: 

### `f- SO Pitot \

~ o. 

### '~ ~ ~ ~ ~ P b : Zy- z Hg 

## T : 7 °r Pitot Dimensions: 

# ~ X s



### CALIBRATOR Motor fps STANDARD STANDARD CAL. Setting mark START END AVERAGE . HIGH \ HIGH F'ACTOR p s: -- I IH2O 

# c pstd: 

## O. 17 `J

CAL. i.nN l i ntv FArTn

a 4 20 

### `~.~(~ ~~~ ~- ~ ~~s 

## D- 57 bG06 20 30 

## D- 2 Z D. 2 2- 0 23 2 

## 3 0 

## .6

9 OC 1 3 1 0.3 D S7`{ b. 31 40 (2- 3 Y 

## .3q 5

- 3,J d• 7/`{ ('

~ 

## 9 , 00 9,7 7/y O ~ 

### 39 50 0- 

## -SY _J

r 7 ~- ~J~ (~~~
-~ 7 

## C20 D. 0.8' 49 60 

## (2,60 0- c

~ 

## 'f'(Z i- Z0 /- 075 - U- 5'-76 j• l.S 1-07Z O. 82-Z 57 70 

## V •

0U 1.01f) OC) 1• 2Z5 O-OOB 1, SO 1• ZZS 0.9:

~ 

## ) LC 68 80
~ 

## 0 21010 Iql 0.C C 306 I

~



## J f !.

~ 

## G 0

, 916 76 9 0 

## l.

~ 

## D (. ~ ~ 

## /. ZC

~ 

## S Z. 3s ). 533 - 81 2. 35 - i. 5 13 8(

39 50 5V 

## 0- 73.5 U G0.3 ,09 0 0 1Qg a L 39 50 

## b o- 73 5 808 Z - 90b

~ 

## 30`

Average 

### ~ 

## . ~ 

## 'o? 0- 31 2

Summary of Results: Normal liigh side calibration factor 

## 0_ - sUy variation 

### Normal loW side calibration factor variation 

## f1.3$ -Off7t, /



## ~ ✓ ~/~ 4- / D Z ~ 

### ig ture of Calibrator



### C-3 04- 

# 3

### 0 1 I"IT01' TUB(: G1LIBRATION

Date: 2 6 f

~ ./', :/ j4 Q S "rime: Pitot No. 

### /Z-/0- / ( zq ~ Pb 

# ?g./

~ 

# 7 "lig P s : 

# _ ~~H 2 O 

### T s ~ y or 

### C pstd: Pitot Dimensions: ~~ ` K, ~/~ " e) c ~ ~ 

### CALIBRATOR Motor fps STANDARD STANDARD 

### CAL.

~- ~ - 

### CAL. Settin 

### e mark START END AVERAGE , HIGH V HI(;fi - rACTnR r.n a .FT OIIJ I:A!`-rnn 4 20 .! O

. 1 0 O. P 0

. SZ9 O/S ct387 20 30 , ~ _ Z

~ •3> 5 ► `~ O. ~t ~ ~ .3Z 0.5 ~~ o.82 " 31 40 0.'3y v. o• y 0 • gog o.5o .•70`7 $1W 39 SO p Sy 0.54 0:?35 ,; 2. 0 , . 9rD 03(-5 0 - 29 1 $t 8 49 60

~~

fa t~ ~O G.5 ~`~ oRS t)-8 og a0 l.095 S 7 70 1

, 66 (,4 1 5 I. zeq CS

~ z - 11

~ 1 , c 4 68 80 1.30 1.30 1.140 1

, q5 1.3 1 14F ~.~~c~ 1.170 1.3
- ~ ` 0 o gl 76 90 I.(00 o 1.2r,5 -2. 3s 1533

39 SO 0. 5q o-s`I o.735 G• SZ o.`I o 0. ( ?e3 7`? v. , 9 9 ` 7 0. el 

# e 39 50 S,4 o. s

- 4 0_ 735 O. ;S''Z 0. q i 

## a_ a -) 9 0. W1



### Average 0 .gcg



### Summary of Results: Normal hig11 side calibration factor 

### variation 

### N'ormal low side calibration factor variation 0. q8n ,



### Signature of Calibrator

C-4M2 

# ~


# ..,

~ NOZZLE CALIBRATION Nozzle Set No.
~~ l~'~ 

# MEFCO L_J 

### E(1VIR0(1(TlE(TML

Date: z//// Calibrator: 2( u, ~ 1 2 3 4 5 Reading 1 -)- S 0,2op n_ 2S4 0, 2.62. 0. 320 Reading 2 o i 2S o.2og D.2S6 b 2r;2, 0• ~ Z3 Reading 3 0. i2S y. zoq n.2SG 6. - 1G2 b 31 ~ Reading 4 ~~ i zS 0.20R ( 1 ).25Is' 63 )c'
- ) Reading 5 p 0.322 Reading 6 o. fl O. 2 s'G 0.321 Reading 7 c.i2s
~ ".2on o_~r~ o• , .~ z b. i2l Reading 8 a 72 S 0.2oG D x_
~ ( O. ~ GZ 0.32G Reading 9 o. i 2 2 rG b. - ;L t,%t O•922 Reading 10 i2S c2.25

- (f, 0.
~ G2 0.32U Average o.; zS ~ O. Zo ~ ~ O
6 7 8 9 10 Reading 1 0.301 D. 31,1 D. 017 D. q1.S O. (0?7 Reading 2 b.
~~ u3 D.' ~2 ~ 6.y77 0.lo3
- 7 Reading 3 0. 3L-U P. 0• yz ? I Q. 43 7 Reading 4

~~ oS 0.3G2 D.q - z $ o.q 27 0.&36 Reading S p ~ C(, G.3L ~ D , `~~ ~ ~g t~. 6 97 Reading 6 0~O~ 0.3b1 Q 66, - 31a Reading 7 U.;ot 0.1101 b.421 6,3
- 1 Reading 8 O. D 36,1 h37 Reading 9 O31C 0.3&1 0.63Q Reading 10 e,306 0.3 n D.l ~'~ D.yz? 

### Average 0,306 

### C-5 

## ~~~1~ 

### .S

~ i

to 

# ~ 

# MUCO Ef1VIROf1f'(1Ef7TAl



### Dry Gas Dteter Calibration
Dry Gas Aleter Number 

## / ~ 

### =z Dat e : // 

## ~

oH C DG ("H 2 0) 0.5 /, Do0 1.0 ODZ
1.5 /,DD~/ 2.0 /, ODIo
3.0 /, DD-7 - 4.0 /, D// 

### Average ~ p 4S 

### Variation:

Calibrator: 

# ~ Checked by:



### C DG @ 2 liters/min. = 

## / O0 8

C-G

### I! 1{



### ..~ ~ ~ • • • •• ll ~



### DRY GAS METER CALIBRATION
hleter Number• 

### /1 7- 

### .z Calibrator: Date:

Wet Test hfeter V



### Calibration Factor (C ) = mstd DG Dry Gas bieter V 

### m 

### std

Run No. : 

### ~~~ -Sa ~ 

### ~ p b : ~9~ 8 IlH g Control r[odule Vacuum "Hg


### IVET TEST METER (No. r2 ) DRY GAS METER


### I Meter p 

### Meter Temp. P



### Time Reading Tem . m Reading In Out m
!~ End 

### cf °F / 30 „H20 

### MZ& c f 

## 71 °F 

## 69 ° F "H 2 O Start 

### 083 ;- 

### p.0 00 cf 

### ° F
- 

### /,30 ~ +H Z O ~~ 

### .Z ~ cf ~ 

### D °F 

### 68°F 

### 4 ,~`z~ ~~H 2O

~ ~ ° 

## a. so

cf 

### ° F "H Z O cf F "H 2 0



### - / .30 

### iVet Test bteter V 

### = 17.65 x - , 5
- .A, / , y — v7/

g, -zg 

### + 13.6 m std + 460 (C f 

### )

Dry Gas Meter V 

### m std 

### = 17.6S x — D 

### • .So 

## a9z8 + 13.6 

### ~j~ + 460 

## z =y9~~ dscf

C 

### DG 

## y 9 ; Ps

C_7 

# ki" /

# v
~ 

# i I 1

~ 

# ziQU ff"ROM)EML

DRY GAS METER CALIBRATION Meter Number: ~7~ ~' 2 

### Calibrator: D a t e:



### Wet Test Meter V m 

### Calibration Factor (C ) = std 

### DG Dry Gas Meter V m std

Run No . . . / OO L ~ 

### O P b : ~ --~ 19 "Hg



### Control Module Vacuum "Hg
1VET TEST METER (No . ^ 2 ) 

### DRY GAS METER
Meter 

### p Meter Temp. 

### P Time Reading Tem . 

### m Reading In Out m

~ 

### ! End 6903 53 ~ 

### 9 cf °F -'H 2 O Gos

- &2cf 7 "~(~ ° 

### F ~ 

### O °F /DO 1-H20 Start 0855 ~ 

### O•000 cf °F "H 2 0 OCD-5711 ~ 

### f °F G9 °F /.40 "H 2 0

3 3~~ /cf aF 

### -~ 

### 9D -Z



### ~ ,Z oF

~ 

### DO 2 

### „H 0 f 

### "H 0 2



### 1Vet Test Meter V 

### m std = 17.6S 

### x S 3-?9 — 1-0 9 1 9 8 + 13.6 ~ + 460 (C f )

= 

### Dry Gas Meter V 

### m std 17. 6 S x 

### S . 30Z o?9• a 

### 8

~ 

# z /. 00

+ 460") ~ dscf

~ CDG



### C-8

# k z -~ 

# 11 I
~ 

# 7-1LU

DRY GAS 61ETER CALIBRATION 

### Meter Number: Date:

~ 

### Calibrator:



### Wet Test Meter V Calibration Factor (C ) = 

### mstd DG Dry Gas Meter V m 

### std

Run No . :


### . 

### /~ /SO ril 

### ~ D p b : 

### 079 .Zg "Hg 

### Control Module Vacuum "Hg



### IVET TEST METER (No. 

### ;2 ) DRY GAS METER
Meter P hieter Temp. P 

### Time Reading Tem . 

### m Reading In O 

### ut m End ~ 

### .ZoZ /O. Qo.Z cf ~~ 

### 'F =Z.30 H 2 O D .S/Dcf °F ° F "H 2 O Start cf 

### 7

~ 

### / ° F H 0 GL


### - f 

### -7S °F °F /.So 

### "H 0 —~ 

## /o.D62 cf F 

## ,

o -a 30 9- 9i ~ ~ ~y ✓ ~ ~—o H 2 0 cf 0 F "H 2 0

. –.7• 

### 3 U

_ ~ 

### Z = 9 dscf IVet Test
~ teter V = 17.65 

### x/4 06 ~ °?9 8 + 13.6

) Y O-
~ 3 ~ 

### g m std ~~ + 460 (C f )



### Dry Gas Ateter V m 

### std = 17.6S x 9• 9/ 49 —



### C 

### DG /, SD



### 079

~ 8 + 13.6

+ 460 

## 9 ~~g 9 ~2 ~ _ a?- ,;Zdscf

# ITIEK-0

DRY GAS b1ETER CALIBRATION
hteter Number: ~7~ `'? Calibrator: 

### D a t e:
,


### Wet Test Meter V Calibration Factor (C ) = mstd 

### DG Dry Gas Meter V m 

### std

Run No . : . / 6 ~ , eD

IVET TEST METER 

### (No. 0 2 

### ) 

## P : °79 ?8 "Hg b Control rfodule Vacuum "Hg



### DRY GAS METER

iR 

### Meter P Meter Temp. P

Time Reading Temp. m Reading In Out m End /D 4590 cf °F 11H Z O OZB.6.3.5 cf OF 9'.Z OF ,7 Do „H 2 0 Start 49ZS O.00O cf ~/ °F ~ ~o ~~H 0 

### O/8//.Z cf °F ~ V OF ,~.DD t'H 2 0 i /D•69~ ~/ -~. 30 /D S23 / , ~~ 

### cf ° 

### F "H 2 0 cf 0 

### F "H Z O

{Vet Test

~ 

### teter V 

### m 

### std = 17.6S x 

### /O.

= o 

## z92g In + 13.6 

### X D
~ 

### 3 = ~~ , 

### Z6/d s c f + 460 (C f )



### Dry Gas Ateter V 

### m 

### std 17.6S x 

### l, ~ 

### , .523

~ 

### lo ,z, o0 + 13.6 + 460 ✓ 

### dscf

C DG 

## /O. Z6/

C-10



# ~~

# vzel ~~~ 

# iQv RXYTEMAL



# a DRY GAS METER CALIBRATION Meter Number: 

## /

~ 

## --- ~ D a t e : ~,~~//,



## /99. ~ --~ -~ 

### Calibrator:

Wet Test Nfeter V 

### Calibration Factor (C ) = mstd 

### DG Dry Gas Meter V m std

Run No . : / ~ 3 DD ~~ I 4 ~ 1 

### Pb: 

## • ~ 9219 

### "Hg



### Control Module Vacuum S 4 

### "Hg
1VET TEST METER (No. -1 7 ) DRY GAS METER


### Meter p 

### Meter Temp. P Time Reading Temp. m Reading In Out m 

### End 09.S.Z 

### /'

~ 

### ' /y o cf °F 31 7:: ' -'H 2 O c f 83 °F :;3 °F ~ . OU 

### -'H2C Start 

## o9

~ I•2 p. DOU 

### cf 

### ° F

- 

## 3. 7011H20 c f

~ 

### y' °F F H 2 O /D, - -3• 70 / • / 

### ~~' ~~' ~ . OO

cf 

### ° F "H 2 0 cf 

### ° F "H 2 0

lVet Test Meter V = 17.65 

### x /D.A/D _ 

# a9.z8 x 9.?Adscf



### m std + 460 (C f )

Dry Gas Meter V 

### m std 

### a9 28 3 , o0 + 13.6 + 460 

### =9~y~ dscf



### C DG ~ ~. r 

# 9 6ys 

# _ ,;2 ✓

C-11E3 

# d~r~~~~

DRY GAS METER CALIBRATION hteter Number: 

## ? D a t e:

~ 

### Calibrator:



### Wet Test Meter V Calibration Factor (CDG) _ m std Dry Gas bieter V m 

### std

Run No . 

### /

~~ 

### '

- 10 

### p b ; v ?928 

### "Hg Control Module Vacuum S 0 "Hg
IVET TEST METER (No. R 7 ) DRY GAS METER
Meter p 

### Meter Temp. p 

### Time Reading Temp. m Reading In Out m End /D0.3 

### cf ~ 

### / °F

_ ~ 

### /oIOIIH 2 O D.i

-

e. 0 23 

### cf BS ° F 

### °F y 

### DO„H20 Start 

### 0- 5 "y D•D DD, cf 

### ° F



### - 

## 4 ,1401 H 2 0 03 

### 9906 cf 

## Sz ° F 

### ° F"H 2 0 

### y~ ~ 

### /a. Z/ ~ ~ y~ ° cf 

### ° F "H 2 0 cf F "H 2 0



### IVet Test tfeter V 

### m std = 17.6S 

### x /a4 ~ 1 

### ,:?9. 093 ;z / + 13.6 

### x p, y'
~ 

### '3 =

~ 

### D- aed s c f

+ 460 (C f )



### Dry Gas rieter V 

### m std = 17.65 

### x/O.Z/7' — 

## y, o 0

~ 

### 9Z 8

+ 13.6 + 460 ✓



### = 9 ~ y 

### dscf

✓ 

### C DG 

## 9 89y

C-12 

## ~/~

# a 

# 11 R7-,t 

# ~

DRY GAS METER CALIBRATION Meter Number: ~~ ''? Date: ,L

~ ///

~~ -S

~ 

### Calibrator: ,~~'~ .e2pdx/,S"

~ /~ 7/~i~



### Wet Test Meter V Calibration Factor (C ) = . mstd 

### DG Dry Gas Meter V 

## m std

Run No . : 

### . / ~~~j eJ ~ 

### • pb ; 

## va928 I,H g Control riodule Vacuum 

### SO "Hg



### tVET TEST METER 

### (No. 

### / ) 

### DRY GAS METER
. Meter p Meter Temp. p 

### Time Reading Tem . 

### m Reading In Out m End Ilpl cf ~ 

### XO ° F

— ,,, ~ 

### /J "H 2 0 OS

3 • 17 o 0 cf 7Z

- 3 ° F 7 2 3 ° F O

. QZ 

### "H 2 0 Start 

### /03, , 1

11 D. DDO 

### cf

: 

### 70 °F

—



### /.A ) "H 0 

### 6

-, !5 -1 ~~ 

### e2 cf

- 

### ~ 7 ~ 1 °F 

### 7 3 °F 

### O , OZ "H 0



### — T 2

9-4 -// ~ ~ 

### ,038 ✓ /

~ 

### . OS

~ 

### Zp • 0 2



### cf ° F "H 2 0 cf

~ 3 ~ 

### F "H 2 0

~ 

### {let Test Aieter V = 17.6S x ~ ~y~ 

### '7 

### ~ 28 + 13.6 ,~ /,DO3 

### _ /p,Zdscf

m std ~ 

### v + 460 (C f )

Dry Gas Ateter V 

### m 

### std = 17.6S x a O 3 8 — 

### D . 0 2 

## Z9z8 + 13.6

, ~ ,3 + 46 0 /

~ 

## "'d dscf



### C 

### DG 

# _ /, oog •

C-13



# ~~

## c-ia ® ®

~

~

~ ~



# _ ~i 

# ~~i~i~~_~ • 

# . ~o ~~ 

# ~ ~~~ Q • 

# _

~ 

# INN • 

# L E E ME



# OE ffiffiffiffiffiffifflE ~~~~~~ O • • • ° • • I E • O 

# OMEN ~~ 

# _~

~ 

# EMO® ~ 

# 110IMMEN ~~~~~ ONE ~ 

# EMENNE 

# EME ME ® `\ 

# \

~ --I

~ V C+7

~ d



# ~11

~ 

## F
.p l U 

## = J 

# N
u i
~ X] CY

~ r 

# ~ ~ ~

.~

\~ 

# ~
~

o! 

# \



# ~ ~ ~

# 111HQU

T,

,

, DIGITAL TEMPERATURE INDICATOR N0. 

### ~~ ' ? ( 1 7 ) CALIBRATIO,1 DATA

Date :



### Media Time Diercury Thermometer ( ° F) DTI ( ° F) Ice Bath ,~ 

### qfoo 3V Ambient Air Boiling Water Oven 

### OBZ ~ 

### ZS 2 

### Z.

~ 

### 3 Oven 

## 08 2 9 30•z ,343 Oven Oven 

## ""),f 3W 378

hleter Adjusted? Yes No 

# K

~ i - ~ . . 

## C-i5 C!oa'i 

# kX411 

# ~ ~!!~'

BAROAtETER CALIBRATION Barometer No. 

# / 7— a

Date: 

# y /07A l Time:



### Barometric Pressure @ Addison Field @ 719 ft. = 

# al l? Sv

- 

### 0.719 

### Absolute Pressure at Addison Field = 

# 2 F. ?a /

+ . 

### 0.083 

### Absolute Pressure @ A4ETC0 @ 636 ft. = 

# I p. 9O

Barometer Reading = 

# g g

Variation = 7L Q 1 7/



### Barometer Adjusted? Yes v No



# ~ gnature of Calibrator C-16



## ~~~

# .~: 

# Scott Specialty Gases, Inc. 1290 COMBERMERE STREET, TROY, MI 48083 (810) 589-2950 FAX:(810) 589-2134 

### CERTIFICATE OF ANALYSIS: EPA PROTOCOL GAS Customer METCO ENVIRONMENTAL Attn : Jim Monfries 16115 Dooley Road Dallas, TX 75244 Assay Laboratory Scott Spccially Gases, Inc 1290 Combcrniere Troy, MI 48083 Purcltase Order : 3067 Scott Project # : 572186

ANALYTICAL INFORMATION This certification -was perfomled according to EPA Traceability Protocol For Assay and Certification of Gaseous Calibration Standards; Procedure GI; September, 1993. -- I

Cylinder Nut»ber : ALA4040839

Cylinder Pressure + : 1900 psig
ANALYZED CYLINDE R Components Nitric Oxide Total Oxides of Nitrogen Certiticate Date : 10/26/94 Previous Certificate Date : Notie

Certified Concentration 18.72 ppm 19.10 ppm Expiration Date : 10/26/96

Analytical Uncertainty* t1°/a NIST Directly Traceable Reference Value Only Balance Gas: Nitrogen +Do r.ot use witen cylinder presssure is below 150 psig. •Anal%tical aceuracy ts inclusn•e of usual I:no%%n error sources which at least include precision of die measurernent processes. 

### REFERENCESTANDARD Type Expiration Date Cylinder Number Concentration NTR-%4 1684 4/1/96 ALM-024582 95.2 ppm Nitric Oxide in Nitrogen

~ INSTRUAIENTATION

InstrumentlA'IodeUSerial # Last Date Calibrated Analytical Principle NO : Horiba/OPE-235/483814 10/25/94 Chemiluminescence



### ANALYZER READINGS (Z=Zero Gas R=Reference Gas T=Test Gas r

— Correlation Coefficient) Components First Triad Analysis Second Triad Analysis Calibration Curve Dale: 10r26194 Response Units: mv Concentration=A•Bx•Cx?Di •Ex d Nitric Oxide Date: 10/19/94 Response Units: mv Z1=0.00 R1=95.20 T1=18.80 Z1=0.00 R1=95.20 T1=18.70 r-0.99999 NTRM 1684 R2=95.20 Z2=0.00 T2=18.70 R2=95.20 Z2=0.00 T2=18.70 Conslanls: A=0.000000000 Z3=0.00 T3=18.70 R3=95.20 Z3=0.00 T3=18.70 R3=95.20 B=1.000000000 C=0.000000000 Avg. Conc. of Cust. Cyl. 18.73 ppm Avg. Conc. of Cust. Cyl: 18.70 ppm 0=0.000000000 E=0.000000000

Special Notes

Customer C _ 17

# :~

.. 

# Scott SpeciaIty Gases, Inc. 1290 COMBERMERE STREET, TROY, MI 48083 (810) 589-2950 FAX:(810) 589-2134 

### CERTIFICATE OF ANALYSIS: EPA PROTOCOL GAS Customer METCO ENVIRONMENTAL 16115 DOOLGY ROAD DALLAS, TX 75244 Assay Laboratory Scott Specialty Gascs, fnc 1290 Cotnbermere l'roy, MI 48083 Purchase Order: 2835 Scott Project f# : 565362

ANALYTICAL INFORMATION This certification lvas performed according to L•PA Traceability Protocol For Assay and Ccrtification of Gascous Calibration Standards; Procedure G1; Septembcr, 1993. Cylinder Number : BLl`4003576 Cylinder Pressure + : 1900 psig
ANALYZED CYLINDER Components iVitric Oxide Total Oxides of Nitrogen Certificate Date : 5/16/94 Previous Certificate Date : None

Certified Concentration 48.05 ppm 48.20 ppm Expiration Date : 5/16/96

Analytical Uncertainty* f1% NIST Directly Traceable Reference Value Only Balance Gas: Nitrogen +Do not use when cylinder presssure is below 150 psig. •Anal.:ical accuracy is inclusive of usual knot%n error sources witich at least include precis ion of the tneasuretnent processes REFEREiVCE STANDARD Type Expiration Date Cylinder Number Concentration NTRM 1694 4/1/96 ALM-024622 95.3 ppm Nitric Oxide in Nitrogen

INSTRUMENTATION
~ Instrument/i\lodel/Serial # Last Date Calibrated Analytical Principle

NO : 1-ioriba/OPE-235/483814 5/4/94 Chemiluminesence

ANALYZER READINGS (Z=Zero Gas R=Reference Gas T=Test Gas r

— Correlation Coefficient) Components First Triad Analysis Second Triad Analysis Calibration Curve Nitric Oxide Date: 5/9/94 Response Unils: mv Date: 5/16194 Response UnHs: mv Concentration=A•Bz•Cz .Dz •Ex d Z1=0.00 R1=95.30 T1=48.00 Z1=0.00 R1=95.30 T1=48.10 r-0.99999 NTRM 1694 R2=95.30 Z2=0.00 T2=48.00 R2=95.30 Z2=0.00 T2=48.10 Constanls: A=0.000000000 Z3=0.00 T3=48.00 R3=95.30 Z3=0.00 T3=48.10 R3=95.30 8=1.000000000 C=0.000000000 Avg. Conc. of Cust. Cyl. 48.00 ppm Avg. Conc. ot Cusl. Cyl: 48.10 ppm D=0.000000000 E=0.000D00D00

Special Notes

C-18 Analyst Don Eichler, 1r CW

# .~

.. 

# Scott Specialty Gases, Inc.
1290 COMBERMERE STREET, TROY, MI 48083 (810) 589-2950 FAX:(810) 589-2134 

### CERTIFICATE OF ANALYSIS: EPA PROTOCOL GAS Custonter Assay Laboratory METCO ENVIRONMENTAL Scott Spccialty Gases, Inc Attn : Jiln Monfrics 1290 Combennere 16115 Dooley Road Troy, MI 48083 Dallas, TX 75244 Purchase Order : 3067 Scott Project # : 572186

ANALYTICAL INFORMATION

- rhis certification was perfomtcd according to EPA Traceability Protocol For Assay and Certification of Gaseous Calibration Standards; Procedure G1; September, 1993. Cylinder Number : ALM038783 Cylinder Pressure+: 1900 psig
ANALYZED CYLINDER Contponents Nitric Oxide Total Oxides of Nitrogen Certificate Date : 10/26/94 Previous Certificate Date : None

Certiried Concentration 85.40 ppm 86.10 ppm Expiration Date : 10/26/96

Analytical Uncertainty* f1% NIST Directly Traceable Reference Value Only

fm Balance Gas: Nitrogen +Do not use when cylinder presssure is bclow 150 psig. •Anal }

- tica l ac curacy is inclusive of usual known error sources which at least include precision of the measurement processes. 

### REFERENCESTANDARD Type Expiration Date Cylinder Number Concentration NTRM 1684 4/1/96 ALM-024582 95.2 ppm Nitric Oxide in Nitrogen

INSTRUI•tENTATION Instrument/Aiodel/Serial # Last Date Calibrated Analytical Principle NO : Horiba/OPE-235/483814 10/25/94 Chemiluminescence



### ANALYZER READINGS (Z--Zero Gas R=Refercnce Gas T=Tcst Gas r

— Correlation CocfGcient) Components First Triad Analysis Second Triad Analysis Calibration Curve Concentration=A•Bx•Cx?Dz •Ex 4 Nitric Oxide Date: 10/19194 Response Unils: mv Date: 10/26194 Response Unils: mv Z1=0.00 R1=95.20 T1=85.50 Z1=0.00 R1=95.20 T7=85.60 r=0.99999 NTRM 1684 R2=95.20 Z2=0.00 T2=85.10 R2=95.20 72=0.00 T2=85.60 Conslants: A=O.OD0000000 Z3=0.00 T3=85.00 R3=95.20 Z3=0.00 T3=85.60 R3=95.20 8=1.000000000 C=0.000000000 Avg. Conc. o( Cust. Cyl. 85.20 ppm Avg. Conc. of Cust. Cyl: 85.60 ppm D=0.000000000 E=0.000000000

Special Notes


## ~

MISp P-1 Customcr C_ 19 Analyst 

# ~~

## mecooECUROnfTEffAL --~

APPENDIX D



### 23 

## Field Testing Data

95-134 D-1o
~ ~ I
~ d V? Q ~

~ V V

~ S y I,-•

~ o m Ij~ 0 n~'1

t c 

# o r

c a ~~o W n~~~~N ~~~~rt ~ ~
~ ~~, 

### ~ 0 0 ~ c~

(~ 'l N

`9 Cj N~ n` (D'

~ . K K 

# inlm° ~

`9 ~ 

### _ f~ N f~ N ~ N~~ 4` ~~

0 a E o E ~~ ~ c J co O O V ~ . ~ ~g ~9 `~ ~ ZA ~n 111

~

~ CZ)
~ 

## ° ~

_ a o m 

### N O 1l ~ o

~ , Z 1l

- ) -z, CRO 

## ~ ~ c~ p - , p O qi 

### 60 ~C) ~o ~ 

## o p a O u. M ~ ~ 

### ~ C-)



### _ `~ ~ `n ~ 

### - p 

### ~ ~

~ ci M ~ c~ N t" - r O 

# o

~ l

m O v 1 p 'D N Mut) ~~ lr ~



# Ln

~ 

### .s

,

~ t ` d 1

~ J-

~ Ln a' E 

### U ` U U !y

~ O 

### 11 11

~ 

# _ _rn

N

- ~ Q i/7 L J C ~ Y

cu G~ co i O J E n 2 CJ3 "- ~ ¢ ¢a- USi ~ F-F I

J

~ 

# Z

y 

# ` Z LLJ 

### O cr: 

### Z W

.. 

### O
S~ ~ W
~ ~ \~I

s U co co ~ 

## " s o 

# =- ° az• Lt. y

d ~ t ~

~ ~ Y



### , co 

# o . ~ c

~e o
~ ~

~ y

2 1 ~ ~ a~. n~ 

## . 'a.

0 Z 

### O Cn 

## z z Z ✓ ~ 

## , ? a

~ n GfJ ~

\ d Z " cc:

W ~ x Y

~ ~ 

### O C 

### V C ` I 1 E


## ~ I (C ~ O U ~ d ~ \ a o .`

~ (

~ N 

### V U rn

~
~ 

### v 

# d J
CD Q 

## o 

# E cz

cn cts m 1 ° > ~

.~ 

### ~

\

~ o

•~ \

~
~ o ca ~ Y U ~ ~ Q N C" 7 O (! ~ o ~ 

### ~ s ~ 

### E U
, 

# O

, 

# `° 2 0 - 

# m tZ o o ¢

\--, \ 

# o 1- c 

# E E O


# _ `D N

~ 

## N n

~ ~ N ° C •j E m D

- 4 i a-

~ U U O w ~

~ V 0 ^~ 

### o ?

~ 

### c 1) 

### E_ U

~ (Z. ~ y ~ --- C/) D-2 /// /~ Impinger Box h'o. 'Ja!er yJeighl G?in

%M = Impinger 1 ~ 2 .5 Impinger 2 Impinger 3 

### 3 Impinger 4 

### /S 3 

### V. = g SO Z = Impinger 5 

### V. = Impinger 6

Impinger 7 

### /S' . 3 Total 

### /Z Z. V

w 

### P b = 

### ? 9. ~(~ 

### ~ ,/%co2 V. 74 315 %o Z V. = 

### /ZZ. Z 

# f %CO P. = c • /o

~ , 

## ~ N Z '°//

_ 

### gn

~



### „ r. Avg AP = , 0,

~ 6'I A s = 4{00 ( 7/ D. = O• ~~02 

# / Avg aP = ~~55 

## ~ 

# T,

_ tZO 

## C p = P, _ f) •8
~ 9 —a. 5D f

H Z O aq.(C& 'Hg T. = ~ {S / , °F ° R T. = 7 Z41° F 

### Q'3 °R 

# 7 M= D, 9Z S3

~

d 

# _

MW a 

### ;? 9r

~ 8 MW — Impin er 1 ~

i ` Impinger 2

Impinger 3



## ~ Impinger 4

Impinger 5 . .

~ Impinger 6 )

~ Impinger 7

Moisture Conteni: Fnal Weight

Initial Weight 

### Increase Fnal Weight 

### Initial Weight Increase Fnal Weight Initial Weight 

### Increase Final Weight Initial Weight 

### Increase Fnal Weight Initial Weight 

### Increase Fnal Weight Initial Weight 

### Increase Fnal Weight Initial Weight 

### Incnease ~ ./ r -7
(QGO • G 

### ( o /3, ~ ' 

### S~ lo

i/C? ~ ! L/



### ~ 

## !3

P Pb 

## + 13.6

~ 4 3/5 

## 2 9 (.7o

~ - 

## l 10 (o stt3 Vm srd - 

## 17.65 Vm •r 

## + 460 — 17.65 x~•~ 

### 13.6



## _ d.T
~ 

### T_ 

## sctm

m 8 S 

## + 460
Vw 9a3 = 0.0472 x Vw = 0.0472 x = 

### -5- 7:9 sft3 % Moisture = Vw „ x 100 = -~ 

### 768 x 100 = ~ ~ S 

### ✓ °



### Vm, d + Vw 9u V, = 5123.8 x 

### .SO7 ~~~ t,,.,, nrr ~ I ; .~ ... ~ 2 q ~~ a x ZS• z/ • 

### ~ ~ 

### SCFM: y ~ 

### 79 A 71.675 

# 9

~ 

### • / 

## 3 o S// x rz v x o. 9z x a 9.C ~'o ~ 

## i 0. 2iaZ 1~ ~° 

## % E A: //2
~ 

## , Z D-3 4 

# ~ ^

# ''1

~

~ Q 1-- ~ Q

~
w ~



### ~

~ \



### ~ 4 ~

~ v U

d

~

~ E ~ z

~ 

## 'c ~- E



### ~



### aE

.

ly 2 s
a ry
a~ ~ ~ Y fO

~ N Q 

## llllllllll 

# liilll

~ 

# il II il I~ ~i 

# l► iliilii ,,

RO ~ 00

N V- 1

\v Q)r I
C p.

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~ LL ~ 

# n n

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n . f-



### ~ E o

m 

### s ~ = 0 ~(1 ~ a'•m ~ 

# >_ c9v

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~ 

# l N o ~ ~ ~ I

~ 

# ,,,r

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¢ O - ~ 

# $=

~ 

# N`- a ~ M ~ ~°- M

_ I V O ` 

### t O 00 ~

~ 

# -Tl 1 

# 1 I 

# A I O

NU- 

# cuo (~ 

## p C3


## ~ ~ ~

~~ ~~ N N M r~ M ~ — 

### o E ~~ 

### cV r 

### 4

~ ~


### D -4 

# &5U ~ ~ C U ~ U d

~ o •

~ 

# cN==

C Z ~ 

### a ' N 

## o = o

Y ~4 

### C d J O J J a) E N 

## E E ca N ~'-~ `a

cQQaUSU

### I i



## ~

F-E I

J i-- ~ Z w Cl
CE:

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### o

~ 

# ~ L1J ~,I

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### N L hi U o .E R

d m ~ J LM 0 2 ) O



### aE I

V

~ ~ \ lL

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y 

## o d

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~ '

7
O z o E E m ZZZ ~ c, a. ! (D

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G 

# _ 1 ~ U 

# II ~9 

## o ~
Q. 

# ~ x 

# J ~ ( n x

~ 

### I

. ~ 

# I E

~ co ~ (

~ U ~ \ Q c. "=

(3 

### N U V
~ c

~ co ca J ~ d U

~ O ~ ~ O Z y a ~



## ~ >° ~ ~ m F 0 — > ~

~ Q bo C Q .0

y ~ o Z ~

~ O

In o a CdN ~ ¢ 

### ~ N °

~ a ,

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~ (r•8 2-5 Vw 9a3 = 0.0472 x Vw = 0.0472 x ~~'~ = 3~~7 

# f sfl' % Moisture = Vw~~ x 100 =' 6Z5 ~~ x 100 q. Cz %



### Vm, + Vw 9u V, = 5123.8 x ~~'~ `~ I Z x •~ - 3o ~ / ~ ~ ,,,, nrF

~~ : 

### 8573 z 7 

# ~ J o~~.~Og X 2(

~ , /S r S1,S , 239 f SCFM: oil _— i nQg
.. ~ _• i0 / I / "C 'E4: 3 :. ~

x x{ )

D-1S 

# ~~Q

¢ ~ C, I w LL

\f) V -, ~ 

### J ~

~ S

C' 

## ~ 

# M z ~ Su cc: Z:) Q H



# CL

1 7

H E 

## '

~ C 

## i,i

~ ~ ~ ~ ~ i 

## +Iil

i ~ 1 

## i

(9 E a> . ¢

N UloO 

## " a° = ~ o ~ 

# o,mp

y ~ f0 O 

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C ~ ~

~ 

# w~ O • 1 ~ 

# V 1 '

CL m E1.L 

## a9 0

ma 

## smo a ~ 

## y- ~ ~

~ 

## I

c Y i °' c% o F- mE -~ ~
~ ~ ~' ~ M

~ ~

. ~ Ln ~

m 

# n i = r

~ 0

- 

### m p

2 

# O "

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### m LL 

### U a`> (~

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a


### D-19 

# ®

### r. 

# dmo

APPENDIX E

~ 

## Analytical Data

95-134 E-1



# ~ 

# 9n 

### 1IETC0 Environraental Particulate Analysis Suaunary
Job Number ,Jr — ~ 

### 3
-, Job Name 

## ~~2~ kGd

Location 

## ~ ii1 

## ~ ,9 

## ~ j1] 

### Date Malysis Completed ;Z-1O-9S Unit Tested



### Run No. ~ 

### Particulate on Filter (mg) ' 

### Particulate in Front Wash (mg rO. D

~ RF (mg) 

### Particulate in Impinger 01 (mg) 

## wr (mg) Y
- 1 ✓ ~



# ~ w / 

### Analyst

• Less Acetone Residue

E - 2 Q'l 

## ~

# m DIETCO Environmental Particulate Analysis EPA Nlethod S

Stack Filters f HF 

### Job Number ~j~ ~~ 

### Location

- Job Name r-;
~ . ~, ~ ,.i' ~ :~ 

### Unit Tested
Desiccator Time In /0 G0 ~ 

### s ~ 

### 0 30 ;Z 6 

### Desiccator Time Out 

## 10 2-5- (, 13 ys ; 7 , 7
Run No. Filter No. 

### Filter & Particulate + Tare Weight (g) Tare Weight (g) ✓ Filter & Particulate (g) 

### Filter & Particulate Average (g) z9 , 5

- 3 ~ 

### Initial Filter Weight (g) , i Total Particulate (mg)

Run No. 

# o

~ Filter No. 

# YF4 91 6 5 1 

### Filter $ Particulate + Tare Weight (g) Tare Weight (g) ✓ Filter & Particulate (g) ,S ( 1 ~ ~ 

# a

Filter & Particulate Average (g) d 

### S3Z
~ 

### Initial Filter IVeight (g) D, SQ 74) 

### ! Total Particulate (mg)

-- ~


### Run No. 

## ~_ Filter No. 

# ffQw i l y 

### Filter $ Particulate + Tare Weight (g) Tare Weight (g) / Filter & Particulate (g) 6 

## 2, S g

Filter & Particulate Average (g) 

### Q, Initial Filter Weight (g) 

### Total Particulate (mg)

)AL 

### Analyst

E - 3 R'J

# to METCO Environmental Particulate Analysis EPA Diethod S

Stack Filters Job Number Location Job Name 

### ~ ,.- l/ 

### ~ Zj 

### Unit Tested 

# .l Desiccator Time In CoO s 32 6 Desiccator Time Out 

## 12 30
Run No. Filter No. Filter & Particulate + Tare Weight (g) Tare Weight (g) ~ Filter & Particulate (g) 

### , s/

~ 

### $ Filter & Particulate Average (g) 

### 4, Initial Filter Weight (g) 

### Total Particulate (mg) ~



### Run No. Filter No. Filter & Particulate + Tare Weight (g) Tare Weight (g) Filter f, Particulate (g) Filter & Particulate Average (g) Initial Filter lVeight (g) Total Particulate (mg)

Run No. Filter No. Filter & Particulate + Tare Weight (g) Tare Weight (g) Filter $ Particulate (g) Filter & Particulate Average (g) Initial Filter lVeight (g) Total Particulate (mg)

Analyst 

# C-4 yg—

# IN n METCO Environmental Particulate Analysis EPA D1ethod S DI - H 2 0 Front iVash Job Number

.~ Job Name ~ , .E ~ ti- ~ ~ ? .~ r~ ., Location _..`.: : • , ,

~ ;~ 

### Unit Tested Desiccator Time In .

~ 

### ' 63d 7-~ Des iccator Time Out 

### ! ✓ 1 4'= -Y l/
Run No. 

# / Volume (ml) a a Final iVeight (g) 

### 1;; j j

~ / 

### V, ~ 

### ( 77 30 ~ 

### Initial Weight (g) 165

- :76 1 415Ala/ Particulate 1Veight (g) ~ ~ 

### 3/ 5 , ~~~ 

### Particulate Average (mg) Less Ammonium Sulfate (mg) 

# _-- Total Particulate (mg) Run No. Volume (ml) Final 1Yeight (g) Initial {t'eight (g) 1, ~ 

### . Particulate R'eight (g) J~ 

### , 12 xdG; Particulate Average (mg) Less Ammonium Sulfate (mg) 

# — Total Particulate (mg) 

### Run No. - ~ 

# _3 Volume (ml) 

# a (

~ 

### Final j9eight (g) ~,.~ ~ ?~~

. ~ : ,
~ ..•. ; , ,

~a~ 5~~~ ✓ 

### Initial Weight (g) Particulate Weight (g) 

### OS e ~ 

### Particulate Average (mg) Less Ammonium Sulfate (mg) Total Particulate (mg)l , 7 — Blank ; Volume (ml) dSa Final Weight (g) 

### 1,2 Initial Weight (g) 

### 9,3 Difference (g) 

### Average (mg) Less Ammonium Sulfate (mg) Total Particulate (mg)

mg/1 /• ~ ~



### Analyst E-S 

# ~~ 

### METCO Environmental Particulate Analysis EPA Method S 

# A c,-4tFront Wash Job Number 

## q~ /~L~ Location ~'~ 

### (.'--

~~~ 

### ., ~

.► %-~ ~ 

### ; G% . Job Name 

### -~ ~Z.~.~~ Unit Tested /^ r :,~~ 

### l%r. ~: ~~, 

### Desiccator Time In 

### 7 6 Desiccator Time Out
Run No. 

### ~_ Volume (ml) Final Weight (g) 

### 3 f~7~ % /~ ~9~ ✓ Initial SVeight (g) 

### /`

~ 

### .3.

. ' 

### ~JQ~ /~ 

### , ~ Particulate Wei ht () 

## D. 0055 - Particulate Average (mg) Less Acetone Blank (mg) Total Particulate (mg) , Run No. 

# ~_ Volume (ml) -2 

### -0 , C? Final Wei ht ( ) Initial Weight (g) 

## la8 Particulate Weight (g) ~~ 1~~= ~: ~ j, 6 

### 7 ,1)~~ 

### Particulate Average (mg) Less Acetone Blank (mg) Total Particulate (mg)
Run No. J 

# ~ Volume (ml) 

### I$3 Final Weight (g) ~?~~ ~ r ~.~;~ /~ ;7 ✓ 

### Initial Weight (g) a, ~ ~~ 

### -72 

### Particulate Weight (g) Particulate Average (mg) Less Acetone Blank (mg) - Tota1 Part'iculate (mg) s '

Acetone Blank Volume (ml) 300 

### Final Weight (g) Initial Weight (g) ZZ ~ 

### Difference (g) 

## 0 Q,

~ 

## ? 3 Average (mg) a, ' * mg/ 1 * Note: If greater than 7.9 mg/1, use 7.9 mg/1. 

# A/4- E-6 Analyst 

# ~

### METCO Environmental Particulate Analysis EPA Method S Back Half Analysis 57y; 

# , /

~ 

### Job Number ~ 

### Location



# - ~3~ U Job Name 17, 

### Unit Tested ` 

### Desiccator Time In P16 Desiccator Time Out /y/ 0 ~ 2 30 ~ io


### Run No. 

# ~_ Volume (ml) 36-1 , ZS S 

### Final Weight (g) 

### ~ ~
, Q ,j 

### Initial Weight (g) ~~ 

### , Q D3 /(

~ 

### .Q,203 Particulate Weight (g) 

### Particulate Average (mg) 

# 3 9, D

~ 

### Less Ammonium Sulfate (mg) 

# _ Total Particulate (mg) 

### 3 D Run No .

- 

# 4_ Vo lume (ml ) Final Weight (g) 

### j3 2 ,5
- 6 

## .331t ✓ Initial Weight (g) Z~ra~



### Wei ht Particulate (g)

g , Q

/~

, ~, k ~~~.•~'~

- 

### Particulate Average Less Ammonium Sulfate (mg) (mg) 

### ;2

~ 

## — Total Particulate (mg)
Run No. 

## ~ Volume (m1) Final Weight (g) /S/ j ~ 

### Initial Weight (g) Particulate Weight (g) 

### Particulate Average (mg) Less Ammonium Sulfate (mg)

— 

### Total Particulate (mg) ,3
Run No. Volume (ml) Final Weight (g) In itial Weight (g) Particulate Weight (g) Particulate Average (mg) Less Ammonium Sulfate (mg) Total Particulate (mg)

''. 

# C-7 9 ~ 

# K Analyst

# METCO,-, L_J E(1VIR0f1(TIEfTTRI 

### ~



### FA

### uS 10

20



## n METCO ENVIRONMENTAL



# - ------------------------------- : Sample Name: Rl FILTER (25ML) Date 

# _ 07/17/1995 16:00:00 ; ; Data File : C:\DX\DATA\ANIONS\95-134\7-170011.D02 ; ; Method : C:\DX\METHOD\FLUO.MET

~ 

### ; ACI Address: 1 System: 1 Inject#: 2 Detector:CDM-2 ; ; Analyst . Column: AS4A-SC,4mm, STARTED 10-14-94 ; 

# ----------------------------------------------------------------------------- Calibration Volume Dilution F'oints Rate Start Stop Area Reject 

# -------------------------------------------------------------------- External 1 1 4200 5H.: 0.00 14.00 500 Component Report: C:omponents Found Ret Couponent Area Heiglzt Concentration Time Name ppm 

# ------------------------------------------------------------- 2.15 fluoride 45807458 10181323 1.526



# ------------------------------------ Totals 45807458 10181323 1.526 Fiie: 7-170011.D02 Sampie: R1 FILfiFR (25ML)

i 4 6 8 10 12 14 

### Minutes

C-9 K

### METCO ENVIRONMENTAL

----------- 

### ; Sample Name: R1 FILTER (25ML) DUP Date: 07/17/1995 16:46:19 ; ; Data File : C:\DX\DATA\ANIONS\95-134\7-170001.D05 ; ; Method : C:\DX\METHOD\FLUO.MET ; ; ACI Address: 1 System: 1 Inject#: 5 Detector:CDM-2 ; ; Analyst Column: AS4A-SC,4mm, STARTED 10-14-94 ;

----------------------------------------------------------------------------- ----------------------------------------------------------------------------- 

### Calibration Volume Dilut.ion Points Rate Start Stop Area Reject
-------------------------------------------------------------------- External 1 1 4200 5Hz 0.00 14.00 500 Component 

### Report: Components Found Ret Component Area Heiglit Concentration Time Name ppm ------------------------------------------------------------- 2.15 fluoride 45714635 10235629 1.523
------------------------------------ Totals 45714635 10235629 1.523 

## PA File: 7-170001.D05 Sample: Ri FILTER (25N1L) DUP 7 

## 1

20

us 10



## N

0 2 4 6 8 10 12 14 

## Minutes

E-10

### METCO ENVIRONMENTAL

----------------------------------------------------------------------------- ----------------------------------------------------------------------------- 

### ; Sample Name: R1 DIFW (222ML) Date: 07/17/1995 17:41:35 ; ; Data File : C:\DX\DATA\ANIONS\95-134\7 =170001.D09 ; ; Method : C:\DX\METHOD\FLUO.MET ; ; ACI Addre--s: 1 System: 1 Inject#: 9 Detector:CDM-2 ; ; Analyst Column: AS4A-SC,4mm, STARTED 10-14-94 ;

----------------------------------------------------------------------------- ----------------------------------------------------------------------------- 

### Calibration Volume - Dilution Points Rate Start Stop Area Reject

-------------------------------------------------------------------- 

### External 1 1 4200 5Hz 0.00 14.00 500 Component Report: Components Found Ret Component Area Height Concentration Time Name ppm

------------------------------------------------------------- 

### 2.15 fluoride 76692821 15756763 2.555
------------------------------------ Totals 76692821 15756763 2.555

~ 

## File: 7-170001.D09 Sample: Rl C}IFUII (222N1L)

16 14 12 10 

### 8 

## uS g 4 2

0

~ -~ 0 2 4 6 8 10 12 14 Minutes



### E-11 e 

# ~ n

### METCO ENVIRONMENTAL ; Sample Name: R1I1 DIBH (361ML) 5X Date: 07/18/1995 14:41:37 ; ; Data File : C:\DX\DATA\ANIONS\95-134\7-180001.D15 ; ; Method : C:\DX\METHOD\FLUO.MET ; ; ACI Address: 1 System: 1 Inject#: 15 Detector:CDM-2 ; ; Analyst
. Column: AS4A-SC,4mm, STARTED 10-14-94 ; ----------------------------------------------------------------------------- 

### Calibration Volume Dilution Foints Rate Start Stop Area Reject
-------------------------------------------------------------------- 

### EYternal 1 1 4200 5Hz 0.00 14.00 500 Component Report: Components Found Ret Component Area Height Concentration Time Name ppm ------------------------------------------------------------- 

### 2.17 fluoride 208839017 40452395 6.957
------------------------------------ Totals 208839017 40452395 6.957 

### 0 File: 7-180601.D15 Sample: R1li DIBH (361ML) 5X

90 80 70 

### 60 50 fluoride

I 

### uS 40 30 

## ~ f 20 + 10 

## ~ t 

### OE 

## i 0 2 4 6 8 10 12 14 Minutes

C-12 p

### 16

14 12 10 8 6 4 2 0 -2 uS nuonae



# I

0 2 4 6 8 10 12 14 

### METCO FNVIRONMENTAL

----------------------------------------------------------------------------- 

### ; Sample Name: R1I2,3 (255ML) Date: 07/18/1995 13:20:58 ; ; Data File : C:\DX\DATA\ANIONS\95-134\7-180001.D10 ; ; Method : C:\DX\METHOD\FLUO.MET ; ; ACI Address: 1 System: 1 Inject#: 10 Detector:CDM-2 ; ; Analyst
. Column: AS4A-SC,4mm, STARTED 10-14-94 ;

~ 

### ----------------------------------------------------------------------------- 

### Calibration Volume Dilution Foints Rate Start Stop Area Reject.
-------------------------------------------------------------------- 

### External 1 1 4200 5Hz 0.00 14.00 500 Component Report: Components Found Ret Component Area Height Concentration Time Name ppm

------------------------------------------------------------- 

### 2.17 fluoride 70335155 14926708 2.343

Totals 70335155 14926708 2.343


### m File: 7-180001.D18 Sample: R112,3 (255ML)

Minutes ~

G-13 ql

# ~

7

METCO ENVIRONMENTAL Data Reprocessed On 07/17/1995 16:25:30

-------------------------------- 

### Sample Name: R2 FILTER (25ML) Date: 07/17/1995 16:15:24 ' ; Data File : C:\DX\DATA\ANIONS\95-134\7-170001.D03 ; Method : C:\DX\METHOD\FLUO.MET ACI Address: 1 System: 1 Inject#: 3 Detect•or:CUM-2 ; Analyst
. Column: AS4A-SC.4mm, STARTED 10-14-94 ; Calibration Volume Dilution Points Rate Start Stop Area Reject : External 1 1 -------------------------------------------------------------------- 

### 4200 5Hz 0.00 14.00 500 Component Report: Components Found Ret Component Area Height Concentration
~.~ 

### Time.Name pp m
------------------------------------------------------------- 

### 2.15 fluoride 54135912 11658143 1.803 

# ~ ------------------------------------ Totals 5413591-

9 11658143 1.803
Ei~~. ~- i~~}~~ 1.~~ }3 .
~~ uifij> 

### ic: ~~ €~~T ~~ (~~~ 

# v L)

^a

~



## us 10

0

0 2 4 6 8 10 12 14 Minutes
E-14

# ~

.;



### METCO ENVIRONMENTAL ; Sample Name: R2 FILTER (25ML)DUP Date: 07/17/1995 17:01:38 ; ;.Data File : C:\DX\DATA\ANIONS\95-134\7-170001.D06 ; ; Method : C:\DX\METHOD\FLUO.MET ; ; ACI Address: 1 System: 1 Inject#: 6 I)etector:CDM-2 ; Analyst : Column: AS4A-SC,4mm, STARTED 10-14-94 ~ 

### t".alibration Volume Dilution Points Rate Start Stop Area Reject External 1 -------------------------------------------------------------------- 

### 1 4200 5Hz 0.00 14.00 500 Component Report: Components Found Ret Component Area Height Concentration Time Name i.. 

### ~ 

# ------------------------- ---------------------------=----- ~~~ 2.15 fluoride 53453218 11511294
------------------------------------ 

### 1.781 Totals 53453218 11511294 1.781 

### A File: 7-170001.1306 Sample: R2 FILTER (25ML)dUP

20

~


### uS 10

0



### 0 2 4 6 8 10 12 14 Minutes

G-15 0

### 40 1 i 

### 30 ; fluoride

20 uS 10

0 ~

,.,

- J

~.~ I 

### METCO ENVIRONMENTAL

----------------------------------------------------------------------------- 

### ; Sample Name: R2 DIFW (233ML) Date: 07/17/1995 17:56:59 ; ; Data File : C:\DX\DATA\ANIONS\95-134\7-170001.D10 ; : :'Sethod : C:\DX\METHOD\FLUO.MET 

### ; ACI Address: 1 System: 1 Inject#: 10 Detector:CDM-2 ; ; Analyst. . Column: AS4A-SC,4mm, STARTED 10-14-94 ; ----------------------------------------------------------------------------- - ----------------------------------------------------------------------------- 

### Calibration Volume Dilution Foints Rate Start Stop Area Reject.
-------------------------------------------------------------------- 

### External 1 1 4200 5Hz 0.00 14.00 500 Component Report: Components Found Ret Component Area I-Height Concentration Time Name ppm ------------------------------------------------------------- 

### 2.15 fluoride 138393191 26608543 4.610
------------------------------------ Totals 138393191 26608543 4.610 

### 9 File: 7-170001.d10 Samp{e: R2 DIFW (233ML)

0 2 4 6 8 10 12 14 

### Minutes

E-16 

# q

### METCO E'rlV I ROr]MENTAL 

### ; Samplz Name: R2 DIFW (2X)SPK 5 PPM Date: 07/18/1995 16:36:58 ; ; Data File : C:\DX\DATA\ANIUNS\95-134\7-180001.D23 ; ; Method : C : \DX\METHC?D\FLUC) . MET ; 

### ; ACI Address: 1 System: 1 Inject#: 23 Detector:CDM-2 ; ; Analyst . t"olumn: AS4A-SC',4mm, STARTED 10-14-94 ; --------------------------------------------------------------------------=-- ----------------------------------------------------------------------------- 

### c"alibration Volume Dilutioii Foints

-------------------------------------------------------------------- 

### kate Start Stop Area Re

~ 

### iect External 1 1 2991 5Hz 0.00 15.57 500 Component Report: Components Found Ret Component Area Height Concentration Time Name

------------------------------------------------------------- 

### ppm 2.17 fluoride 218192518 44018947

------------------------------------ 

### 7.268 Totals 218192518 44018947 7.268


### Fil

~ 

### : 7-

~ 

### 1;:i ~ciC~1.C~2:~ S~~ 

### mp1e: t;: ~ C~ 

### IFV"! (2X);

~ 

### PK:, PlDN:i P.

- 

### 14i a

.1 20 'I {?0 (l ~~ -" I i 

### i 40 ;

Gi 

### flLloflr1e

( 1 2 .} C'i _l

- 1 0 - 1 2 - 1 4 P•'li{luLr ==

c-i7 

# ~~ r 

# i

### METCO ENVIRONMENTAL ; Sample Name: R2 DIFW (2X)SPK 5 PPM DUP Date: 07/18/1995 16:53:10 ; ; Data File : C:\DX\DATA\ANI ONS\95-134\7-180001.D24 ; ; Method : C:\DX\METHOD\FLUO.MET ; ; ACI Address: 1 System: 1 Inject#: 24 Detector:CDM-2 ; ; Analyst
. Column: AS4A-SC,4nun, STARTED 10-14-94 ;

----------------------------------------------------------------------------- ----------------------------------------------------------------------------- 

### Calibration Volume ------------------------------------------------------=------------- Diltition Points Rate Start Stop Area Reject External 1 1 4200 5Hz 0.00 14.00 500 Component Report: Components Found Ret Component Area Height C:oncentration Time Name
------------------------------------------------------------- ppm 2.17 fluoride 219787830 43305568
------------------------------------ 7.321 "Totals 219787830 43305568 7.321 

## File: 7-1800U1.1314 Sample: R2 DIPtrV (M5PK 5 PPM DUN 70 60 50 40 uS 30 20 10 0 -10 0 2 4 6 8 10 12 14 nninutes 

### ii

E-18

### METCO ENVIRONMENTAL


# ----------------------------------------------------------------------------- ; Sample Name: CCV 10 PPM F. STD Date: 07/18/1995 11:18:10 ; ; Data File : C:\DX\DATA\ANIONS\95-134\7-180001.D02 ; ; Method : C:\DX\METHOD\FLUO.MET ; ; ACI Address: 1 System: 1 Injec:t#: 2 Detector:CDM-2 ; ; Analyst
. Column: AS4A-SC,4mm, STARTED 10-14-94 ; 

# ----------------------------------------------------------------------------- c:alibration Volume Dilution Points Rate Start Stop Area Reject.
-------------------------------------------------------------------- E'xternal 1 1 4200 5Hz 0.00 14.00 500 Component Report: Components Found Ret Component Area Height Concentration Time Name ppm ------------------------------------------------------------- 2.18 fluoride 305275841 58437700 10.169
------------------------------------ Totals 305275841 58437700 10.169 

## -0 File: 7-180001.D02 Sample: CCV 10 PPM F STD

80 70 60 50 40 uS 30 20 10 0 -10 

### 0 2 4 6 8 10 12 14 Minutes 

# n

E-19

### METCO ENVIRONMENTAL



# ----------------------------------- ; Sample Name: R2I1 DIBH (345ML) 5X Date 

# _ 07/18/1995 15:12:16 ; ; Data File : C:\DX\DATA\ANIONS\95-134\7-180001.D17 ; ; Method : C:\DX\METHOD\FLUO.MET ; ACI Address: 1 System: 1 Inject#: 17 Detector:CDM-2 ; ; Analyst
_ Column: AS4A-SC.4mm, STARTED 10-14-94 ; Calibration Volume Dilution points Rate Start Stop Area R,eject
-------------------------------------------------------------------- 

### E:cternal 1 1 4200 5Hz 0.00 14.00 500 Component Report: Components Found Ret Component Area Height Concentration Time Name ppm ------------------------------------------------------------- 

### 2.17 fluoride 197969472 38695533 6.594
------------------------------------ Totals 197969472 38695533 6.594 

### File: 7-180001.D17 Sample: R211 DIBH (345ML) 5X
40

30
20 uS 10



### 0

0 2 4 6 8 10 12 14 

## ~ 

# 1

Minutes


### E-20 

## I 

# l

### METCO ENVIRONMENTAL

---------- 

### ; Sample Name: R2I1 DIBH (345ML) 5X DUP Date: 07/18/1995 15:27:36 ; ; Data File : C:\DX\DATA\ANIONS\95-134\7-180001.D18 ; ; Method : C:\DX\METHOD\FLUO.MET ; ; ACI Address: 1 System: 1 Inject#: 18 Detector:CDM-2 ; a; Analyst
. Column: AS4A-SC,4mm, STARTED 10-14-94
--------------------------------------------------- 

### Calibration Volume Dilution Points Rate Start Stop Area Reject
-------------------------------------------------------------------- 

### External 1 1 4200 5Hz 0.00 14.00 500 Component Report: Components Found Ret Component Area Height Concentration Time Name - ppm - ------------------------------------------------------------- 

### 2.17 fluoride 195512773 38612399 6.513
------------------------------------ i Totals 195512773 38612399 6.513 

## mt. File: 7-1$0001.Di8 Sample: R21i DIBH (345fv1L) 5X DUP ~

40

30

20 

### uS 10

0

0 2 4 6 8 10 12 14 M inutes

E-21 

# ~ 'J

### METCO E'NVIRONMENTAL

----------------------------------------------------------------------------- ----------------------------------------------------------------------------- 

### ; Sample Name: R2I2,3 (271ML) Date: 07/18/1995 13:36:17 ; ; Data File : C:\DX\DATA\ANIONS\95-134\7-180001.D11 ; ; Method : C:\DX '\METHOD\FLUO.MET ; ; ACI Address: 1 System: 1 Iiijec:t#: 11 Det.ector:CDM-2 ; Analyst . Column: AS4A-SC,4mm, STARTED 10-14-94 ; ----------------------------------------------------------------------------- 

### i:alibration Volume - Dilution Foints
-------------------------------------------------------------------- 

### Rate Start Stop Area Reject. External 1 1 4200 5H.: 0.00 14.00 500 

### Component Report: Components Found Ret Component Area Height Concentration Time Name
------------------------------------------------------------- 

### ppm 2.17 fluoride 69641120 1488180_

~ 

### '
------------------------------------ 

### 2.320

~ 

### Totals 69641120 14881802 2.320 

### 19 rile: 7-180001.D11 Sample: R212,3 (271ML)

40

30

20 uS 10

0



### 0 2 4 6 8 10 12 14 Minutes

E-22 

# ~ 1

### METCO ENVIRONMENTAL 

### ; Sample Name: R3 FILTER (25ML) Date: 07/17/1995 16 30:43 ; ; Data File : C:\DX\DATA\ANIONS\95-134\7-170001.D04 ; ; Method : C:\DX\METHOD\FLUO.MET ; ; ACI Address: 1 System: 1 Inject#: 4 Detector:CDM-2 ; ; Analyst
. Column: AS4A-SC,4mm, STARTED 10-14-94 ; ----------------------------------------------------------------------------- 

### c:alibration Volume Dilution Points Rate Start Stop Area Re,ject
-------------------------------------------------------------------- 

### Esternal 1 i 4129 5Hz 0.00 13.76 500 Component Report: Components Found Ret Componer.t Area Height Concentration Time Name ppm ------------------------------------------------------------- 

### 2.15 fluoride 46435664 9808065 1.547
------------------------------------ Totals 46435664 9808065 1.547 

### File: 7-170001.d04 Sample: R3 FILTER (25ML)

20

uS 10

0



### 0 / 2 4 6 8 10 12 Minutes 1 

### ~

E-23

### METCO ENVIRONMENTAL

-------------------------------- 

### ; Sample Name: R3 DIFW (265ML) Date: 07/18/1995 11:48:50 ; ; Data File : C:\DX\DATA\ANIONS\95-134\7-180001.D04 ; Method : C:\DX\METHOD\FLLIO.MET ; ACI Address: 1 System: 1 Inject#: 4 Detector:CDM-2 ; Analyst
. Column: AS4A-SC,4mm, STARTED 10-14-94 ; Calibration Volume Dilution Points Rate Start Stop Area Reject.
-------------------------------------------------------------------- EYternal 1 1 4200 5Hz 0.00 14.00 500 Component 

### Report: Components Found Ret Component Area Height Concentration Time Name ppm ------------------------------------------------------------- 2.15 fluoride 137105384 25215950 4.567
------------------------------------ ! Totals 137105384 25215950 4.567

File: 7-180001.D04 Sample: R3 DIFW (265ML) 40
30
20 uS 10
0



### 0 2 4 6 8 10 12 14 Minufes 1
- 1



### E-24

### 40 

# I i 

### j fluoride 301 1
20 uS 10

0 METCO ENVIRONMENTAL

----------- 

### ; Sample Name: R3 DIFta (265ML)DUP Date: 07/18/1995 12:04:14 ; ; Data File : C:\DX\DATA\ANIONS\95-134\7-180001.D05 ; ; Method : C:\DX\METHOD\FLt10.MET ; ; ACI Address: 1 System: l Inject#: 5 Detector:CDM-2 ; ; Analyst
. Column: AS4A-SC,4mm, STARTED 10-14-94 ;

----------------------------------------------------------------------------- ----------------------------------------------------------------------------- 

### Calik,ration Volume Dilution Points
-------------------------------------------------------------------- Rate Start Stop Area Reject E:cternal 1 1 4200 5Hz 0.00 14.00 500 Component Report: Components Found Ret Component Area Height Concentration Time Name
------------------------------------------------------------- ppm 2.17 fluoride 137020354 28290570
------------------------------------ 4.564 Totals 137020354 28290570 4.564 

### Fi(e: 7-180001.DO5 Sample: R3 DIFW (265iNL)DUP

0 2 4 6 8 10 12 14 Minutes
E-25 

# fP 

# 3

### METCO ENVIRONMENTAL

-------------- 

### ; Sample Name: R3I1 DIBH (274ML) 5X Date: 07/18/1995 15:42:56 ; ; Data File : C:\DX\DATA\ANIONS\95-134\7-180001.D19 ; ; Method : C:\DX\METHOD\FLUO.MET ; ACI Address: 1 System: 1 Inject#: 19 Detector:CDM-2 ; ; Analyst
. Column: AS4A-SC,4nun, STARTED 10-14-94 ; !:alibration Volume Dilution Foints Rate Start Stop Area Reject
-------------------------------------------------------------------- 

### External 1 1 4200 5Hz 0.00 14.00 500 Component Report: Components Found Ret Component Area Height Concentration Time Name ppm ------------------------------------------------------------- 

### 2.18 fluoride 265669319 53124065 8.850
------------------------------------ Totals 265669319 53124065 8.850


### n F11e: 7-1 80001.D 1 9 Sample: R31 i DIBH (274ML) 5X

80 70 60 

### 50 40 

### fluoride



# I

M0 20 

### 1n i I ~ 

### I 0 -1A 1 0 2 4 6 $ 10 12 14 Minutes -,



## E-26 lb

### METCO EN`JIRONMENTAL

----------------------------------------------------------------------------- ----------------------------------------------------------------------------- 

### ; Sample Name: R3I1 DIBH (274ML) 5X DUP Date: 07!18!1995 15:58:07 ; ; Data File : C:\DX\DATA\ANIONS\95-134\7-180001.D20 ; ; Method : C:\DX\METHOD\FLUO.MET ; ; ACI Address: 1 System: 1 Inject#: 20 Detector:CDM-2 ; ; Analyst
. Column: AS4A-SC,4mm, STARTED 10-14-94 ; ----------------------------------------------------------------------------- 

### Calibration Volume Dilution F'oints Rate Start Stop Area Reject.
-------------------------------------------------------------------- 

### EYternal 1 1 4120 5Hz 0.00 13.73 500 Component Report: Components Found Ret Component Area Heig)Zt Concentration Time Name ppm ------------------------------------------------------------- 

### 2.13 fluoride 266136227 52666831 8.865
------------------------------------ Totals 266136227 52666831 8.865

. .-._...

~ 

### _,.... .:__... 

## Fiie: 7-18Q ~~1.~~~ 

## Sample: R311 DIBH (274(v1L) 5X DUP
80 70 60 50 40 

### uS 30 20 10 0 -10 

### 0 2 4 6 8 10 12 tviinutes



# _ G 27 / 

# p J ~ 77

### METCO ENVIRONMENTAL

----------------------------------------------------------------------------- ----------------------------------------------------------------------------- 

### ; Sample Name: R3I2,3 (215ML) Date: 07/18/1995 13:51:37 ; ; Data File : C:\.DX\DATA\ANIONS\95-134\7-180041.D12 ; ; Method : C:\DX\METHOD\FLUO.MET ; ; ACI Address: 1 System: 1 Inject#: 12 Detector:CDM-2 ; ; Analyst Column: AS4A-SC,4mm, STARTED 10-14-94 ; ----------------------------------------------------------------------------- 

### Calibration Volume
- -------------------------------------------------------------------- 

### Dilution Foints Rate Start Stop Area Reject External 1 1 4200 5Hz 0.00 14.00 500 Component Report: Components Found Ret Component Area Heigllt Concentration Time Name
------------------------------------------------------------- 

### ppm 2.17 fluoride 83536272 1796280' 2.783 i 

### ------------------------------------ Totals 83536272 17962802 2.783


### a File: 7-180801.D12 Sample: a312,3 (215ML) r-1)

~



### 30
uS 20
ffel


### U
0 2 4 6 8 10 12 14 Minutes

C-28 I t /„

### METCO ENVIRONMENTAL

- ---------------- 

### ; Sample Name: DI BLANK Date: 07/18/1995 14:26:19 ; ; Data File : C:\DX\DATA\ANIONS\95-134\7-180001.D14 ; ; Method : C:\DX\METHOD\FLUO.MET ; ; ACI Address: 1 System: 1 Inject#: 14 Detector:CDM-2 ; ; AnalYst
. Column: AS4A-SC,4mm, STARTED 10-14-94 ;

----------------------------------------------------------------------------- ----------------------------------------------------------------------------- 

### Calibration Volume Dilution Points Rate Start Stop Area Reject• E.:ternal 1 -------------------------------------------------------------------- 

### 1 4200 5Hz CJ . 00 

### 14.00 500 

### Component Report: Components Found Ret Component Area Height Concentration Time Name

------------------------------------------------------------- 

### ppm 2.15 fluoride 516949 75216

------------------------------------ 

### 0.017 Totals 516949 75216 0.017 

# a t=iie: 7-i

~ 

## uuc ~ 

## i.Di4 5ampie: Di BLANKr0.4

0.3
0,2 

### uS 0.1

0.0

-0.1 0 2 4 6 8 10 12 14 

### Minutes


### G-29 fbI

### METCO ENVIRONMENTAL

Sample Name: FILTER BLANK Date: 07/17/1995 17:26:15 ; Data File : C:\DX\DATA\ANIONS\95-134\7-170001.D08 ; ; Method : C:\DX\METHOD\\FLU0.MET ; ACI Address: 1 System: 1 Inject#: 8 Detector:CDM-2 ; ; Analyst
. Column: AS4A-SC,4mm, t;TARTED 10-14-94 ; Calibration Volume Dilutioil Foints Rate Start Stop Area Reject External 1 -------------------------------------------------------------------- 1 4200 5HZ 

### 0.00 14.00 500 Component Report: Components Found Ret Component Area Height Coiicentration Time Name
-------------------------------------------------------------- ppm 2.15 fluoride 10190970 2040563
------------------------------------ 0.339 Totals 10190970 2040563 0.339 

## 0 rile: 7-170001.D08 Sample: i=iL IEK BL,yNk

4.0
3.0
2.0 us 1.0
0.0

0 2 4 6 8 10 12 14 Minutes

E-30

### * 29.92 "Hg, 68 ° F (760 mm Hg, 20 ° C)

C 1 = bfL l

x(ML B - ML BB ) x N x 32



### ML A
C T = C I #2 + C 1 #3 S0 2 Eh1ISSI0N DATA rl Job Number Job Name Location ~~t~p~~, Unit Tested' 

# ~
-



### n Run Number N- normality of Ba(C104)2 ML I - ml in impinger #2 ML I - ml in impinger #3 3 ~ 3130 

### ML A - ml in aliquot #2

~ ML A - ml in al iquot #3

ML B - ml of Ba(C10 4 ) 2 to titrate #2 ?S 

### 3. 7-s 3..3s Average ML B - ml of Ba(C104) 2 

## 3.3.3

ML B - ml o f Ba (C10 4 ) 2 to titrate #3 15 l , /,5 , Average ML B - ml of Ba(C10 4 ) 2

~ /j

~ ` j l. , ML BB - ml of Ba(C10 4 ) 2 to titrate blank 

### T m - average gas meter temp., ° F

~ 

### - volume of dry gas sampled m @ meter conditions ft. 3 P b - barometric pressure, "Hg Abs. _ stack gas volume dry @ Qs standard conditions, *SCFM C I - S0 2 in impinger #2, mgs 

### l~ , / 3 , J? 

### 1,3CJ C~ C 1 - S0 2 in impinger #3, mgs C T - total S0 2 in impingers, mgs 

### 152~ ppm S0 2 

### C S0 2 - emission rate of S0 2 , lbs/day 

### C SO 2 - emission rate of S0 2 , lbs/hr C s - emission rate of S, lbs/day 0.7513 x C T x(T m + 460) ppm S0 2 = vm pb C 

### S0 2 = ppm S0 2 x Q s x 239.2 x 10 -6 C S02 E-31 C s 2


## ~~ /ML I x (M L B - ML BB ) x N x 40 M L A C I = 

# 9 

# d m Erco

SULFUR TRIOXIDE EMISSION DATA Job Number Location 

### -~z~~~ - nrJ. 

### ~ Job Name 

### Unit Tested
Run Number Date Time N - normality of Ba(C10 4 ) 2 

### •O/CO ~ 

### ML I - ml in impinger ; 2 _0 3 00 

### ML A - ml in aliquot i p



### ML B - ml of Ba(C10 4 ) 2 to titrate d ss - /a 

### ~ Average AiL B - ml of Ba(C104) 2 to titrate

~ 

### 0~ 

## 3

, 

## Q. ~ 

## O ML BB - ml of Ba(C10 4 ) 2 to titrate blank
~ 

### 0-5- > T m - average gas meter temp., ° F v- volume of dry gas samplsd m @ meter conditions, ft. ~
p b 

### - barometric pressure, "Hg Abs. _ stack gas volume dry @ Qs standard conditions *SCFM C I - S0 3 in impinger, mgs ppm S0 3 ; 

## c S0 3 - emission rate of S0 31 lbs/day C S - emission rate of S, lbs/day ~ 

### * 29.92 "Hg, 68 ° F (760 mm Hg, 20 ° C) 0.6021 x C I x(T m + 460) 

### ppm S0 3 = 

## u m P b 

## c 50 3 = ppm S0 3 x Q s x 299.1 x 10-6 C S03 E-32 CS 2.S

### -, 

# m,,

~ 

# 4

7



### APPENDIX F


# a Reference Method Monitor Data

95-134 F-1 

## /~~

# meco

~ (~ 

### Ef1VIR0(1(TIEf'iTAI

Absorber Stack (EPN - K) Oxides of Nitrogen Concentration

Run Measured Adjusted 

### Number jPP ~ 

### m* 1 16.5 16.0 2 17.4 17.0 3 17.7 17.0 

## "Calculated according to equation 6C-1.

m.

F-2

/// ~0 a~ a~ o 0 0 

# a0> Z 

# c 0
~ c~ 

## QU>~k ° ~ ~ v

00 x 

### O 

### z a ~ rn cz N 't c0

~ p 

## Q O O O

.—. Y Y

v T ~ n N Z c
~ n ~ c C~ C~ 

### (L E

~



### o "E ~ 

### N p U) 

### z U ~ 

## c o

~ _O 

### x ,C



## O U z ~~~+ ~ ~~~ =

C~ pJ ( ~

O C'7 O C'7 O
~ = x ~ v o iU O 

### p

~ a (1)
(~ T ,^
. y

~ +I V
a V V V Q

~ U N 

### o cU 

## ~ M o T ~~~~

•~ L ~ ~ ~

~ 

### p

~ Y U U ~ ~ • ~ ~ ~ co (Y) co 

## z E~~ 6 06 d6•

• i ~

~ I C ~ rr E

~ T N co 

### z

r--3 ~ 

### I



# 115

# q ~ BORAL 4 BRICK

HENDERSON TEXAS


### ~ ABSORBER STACK i Page : 1
NOX PPM 06/29/95 07:18 O.00
~ 06/29/95 07:19 O.00 06/29/95 07:20 0.0C 06/29/95 07:21 0.0C 06/29/95 07:22 O.00 Z~ Eoi(lr 5'G 9/a/7/ZALC 06/29/95 07:23 O.00 06/29/95 07:24 85.5C 06/29/95 07:25 86.8C 06/29/95 07:26 86.8C 06/29/95 07:27 48.00 t 06/29/95 07:28 0.2C 06/29/95 ! 07:29 2.9C 06/29/95 07:30 50.2C 06/29/95 07:31 49.6C 418. a.5;4,1+— 411 1 ar r ~C~~ 3S26 06/29/95 07:32 49.6C 06/29/95 07:33 25.1C 06/29/95 07:34 0.2C 06/29/95 07:35 O.iC
~ 06/29/95 07:36 0.0C 06/29/95 07:37 8.3C ;j 06/29/95 07:38 18.9C 06/29/95 ! ~ 07:39 18.7C 06/29/95 07:40 18.6C 06/29/95 ~ 07:41 9.9C 06/29/95 07:42 0.1C

; A1IERAGES : 2
- 2.4

F-4|/

~
6/

~ 9/9b ... _-.... ..... ..... ' ..... _ ... ..... '

... .... --__-_'- -_- -- '---_-- ---- - '-
/ ^ Time PP ~ _-_'-_-- -........ ---__-_-____-__-____'___

~ . ~ 7 47 --_-__-__-----__.--- 30,0000C ' 07:4O 30.0000C 07:49 30,0000C 07:50 29.9000C 07:5l 29'9000C 07:52 29'9000C

, 07153 29'9000C '{ 7: 24 29.9000C 07,55 29'9000C 07:56 29'9000 ~ W:57 30.0000C ' 07;50 30'0000C 08:00 29.9000C 0G:01 29.9000C 08:52 29'9000C 08:03 30.0000C 08:04 29'9000C .1 O8z05 29.9000C 08:06 29.9000C 0G:O7 29.9000C ! 0n08 29.6000C ' 08:09 29'9000C 06:10 29'6000C 8: i1 29.7000C 08:12 29.7000C

' o8;13 08:14 08:15 08116 29.7:00C

29'7000C 29'6000C 29.7000C

~ AX : 30'0000 !IN r 29.6000 AVG ; 29'8667 ' SCANS. 30

'

c``--77,' ' P-S

- - 

# //5"',1- 1 ?1v9s (-/"



# - _ ° " _ - ZE ~o~I/ Z 

# 8//

~ 

# 5 Cf/EGE

~ i% 

# O 

# ,:

~ 

# =: _._ 7

45.

U w:

F-6SERAL BUCK

HEMM

WN

F R
~ 0619R5 1455 ?42055 A56 Oloov, zloty 

## 6ellAllizote 0"535 1057 ooZW55 1053 

### H. 50 Oc!'23i35 14: 57 47.,

- C 

# (ID SAW5 002 002IR5 1513 RIC AM= 1004 23C 06=5 552W95 1005

•106 0 A r-

, 0. 5L

2 0. 9



### F-10' /

~ u`Iiiar` "vprage kepon!

_ Aux Interval Date '

~~ ------------'-- N DX ^ ~~~~ ~ p~

~ , - ' vFY

. ~ i5:14 17'1000 17'10`)0 i5:l5 17'C000 15:16 17'l000 15:17 17'2000 + ~ 15; i8 17,2000

~ 15:19 15,20 17,3000 1s:21 17,5000

17'5000 15,22 ' 17 7000 10:23 17'7000

~ ~ 1b;24 15:25 17'5000

17'50

~ 0 15:26 17,5000 15:27 17'4000 15:28 i7'3

~ 00 1 - o000 15:32 16.7000
~ M33 i6.G000 15:34 17.0000 ~° 15:3 5 15:36 17 3000 ' 17'4000 15:37 17'300-) 15:38 17'3000

.

. 15:39 15;40 17'5000

17'0000 15:41 15:42 16'6000

16.4000 i8.40O0

~ VG : 16'4000

17'2867 30

P-ll

. / ~ | \

~F

- I

LA ~ ~ux~ iiary

~ `/er

~~ ge
~ ep ~ rt 07 Site CORAL Aux | Daie

----------------------------

- --------------

- --- --- --------'----'-- --- -------------------

- ------- '---

, ~r~, PPM
15;57 15:58 ... .... ... ______________

17'8000 17'4000 15:59 17,3000 16:00 17'3000 16;01 17.300; 16;02 13.3000 16103 18.4000 10;04 17'4000 1o:05 17,2000 16:06 17.4000 10:97 17'600(` ib:08 !7.8Oo0 16:09 17'700 ~ 16:10 i7.5000 16:11 17,5000 16:12 17,6000 16r13 17'4000 16:14 17.1000 16:13 17'0000 16:16 17.1C00 16:17 17.400C 16:18 17'4000 16:19 17.4000 16;20 17'3000 16:21 16:22 17'5000

17.5000 16:23 17.7000 i6:24 17'7000 16:25 i7.5000 16:26 17.6000 16:27 17'800 ~ MAX : 18.4000 MIN : L7'0000 AVG : 17'5129 SZANS: 31.

Vl27 19 4 7

9, -u 4 1

0
014 /vz ul a j - .5 i

6f 9, ;-sisc

~ -4

0: 0

43- 5

6

7

7



## In

F-13._l 95 1.'

~ 4 bORAL BRICK HENDERSON TEXAS i ABSORRER STACK

~ Fage : 1


### NOX FRM 06/30/95 07:05 06/30/95 07:06 06/30/95 07:07 06/30/95 07:08 06/30/95 07:09 06/30/95 07:10 06/30/95 07:11 ! 06/30/95 07:12 06/30/95 07:13 06/30/95 07:14 06/30/95 07:15 06/30/95 07:16 06/30/95 07:17 =: 06/30/95 07:18 06/30/95 07:19 06/30/95 07:20 06/30/95 07:21 06/30/95 07:22 06/30/95 07:23 06/30/95 07:24
~ 06/30/95 07:25 J 06/30/95 07:26 06/130/95 07:27
~ 06/30/95 07:28 06/30/95 07:29 06/30/95 07::,0 06/30/95 07:31
AUERAGES : -O.iC -0. iC S6 `1le 171-- /V z ,C -o.1c 

### Z 0.1C 17.8C O.1C O.iC 37.5C 85.2C 86.4C 86, /~~ ,vOk AGmo3 ~7~j 86.4C 45.4C O.3c 14.00

~ ~ sj°P••, .t/oX BUn GY ~ 3-S ~6 49. 7C 27.2C 0.2C 0.1C 11.9c i8.8C 18.6c ~~ ~Z~oM~ /oX
~ 9L ~ oyo ~ S39 18.6C 12.7C 0.2C O.1C O.iC

21.5



### F-14 

# /~ 

# /'.

--

~

~ ._-_--_-__---__-_---_ --- --- ' - -- _._.-_'-_- ----'-- -- - ' - -' -- -- - 07i34 07 ;35

~ 07:36 3t'20{'0C ZL'L00KC 35'2000C 07:37

~ 5'200

~ C

~ 7;

~ 8 3}'2000C O7

~ J9 07:40 35'2000C

35.Z000C ' 07:42 ' 35'2000C 07:43 35'2000C 07:44 07r45 35'2000C

30'2000C 07

~ 4 , 16 07;47 ~ 5'2

~ 0oC

35'2000C

~ | 07:48 35'2000C 07:49 35.1000C 07;50 351100011, 07:53 35. 1000

~ - 07:52 S5'10o0C 07:53 35.0000C 07:54 35.0000C 07:55 i 07:56 34'0000 ~ 34'9000C 07:57 34'9000C 07:58 07 08:00 08:01 Q8n02 34'8000C

4.800 ~-i~ 34'8000C 34'D0S0C 54'7000C 08:03

~ AX ~

. .1IN : AVG : 34'W0OC

35'2000 34.700u 35'0600 SCANS ~ 30

F-lS

_ _ ~

## ri

I L V



### x/, 8,~s ~



### C , -6j 

### I i i 5,
6 

# :,: ,. _... 1 j

Ale'. 

### eloS" •K 7 j

1 13

F-16 

# 1a. ~'

------ --- — ..... .... .... .... ------ ----------------'-----------------'------------ --- --

~ U:Z6 ' --'-------------

~ 8'0

~ 00 0

~ :27 1

~ '90

~ 0

~ 8:28 i7'9000 Wn29 17'

~ 000 0O:30 17'4000 0a:31 18'3000 08:12 18'4000 00;33 17'7000 00034 17'2000 08:35 17'4000 0B:36 17'5000 08:37 17'7000 OB:38 17'8000 08:39 17'8000 08:40 17'7000 08:41 17'8000 08:42 i7.6000 08:43 17.3000 08:44 16'9000 08:45 17'0000 0B:46 17.2000 08c47 17,7000 | 08

~ 48 13.0000 08:49 18'0000 08:50 17'7000
~~ 08:51 18'0 ~00 ~D~~7 1~ '3000 08;55 l7'7000 08:54 17,3000 08:45 17,4000 MAX : 18.4000 MIN : AV6 16.9000

17.6633 SCANS: 30

F-17! '

---------------..... ---'-- ------------- ...... .... ..... - ..... -.... ------------------'-'-'---'---------'--------'-------'

, ~~u~ ~&'- ~'~~ Time

-------------------- 09:06 18-4000 ' ^ 09:07 17.6000 39:08 17'7000 ~ 09:09 17,7000 09:10 18-1000 09z11 18.1000 09;12 17.9000 09:13 18. 0000 09:14 17.8000 09:15 17.6000 09:16 17.4000 09:17 17.1000 09;18 17.1000 09:19 17.3000 09;20 17'6000 09z21 17.8000 09:22 17,6000 09:23 17.9000 | S9:24 17 ^ 9000 09:25 17.7000 09:26 l7.8000 / 09:27 | . 17 7000 09:28 17'6000 09:29 17.7000 o9:30 17'900V 09:31 17.8000 09:32 17'700 ~ 09:33 17.70O0 09:34 17'800 ~ 09:35 17.3000

~ AX : ~ 8.4000 MIN : l7.1000 4VG : 17.7100 SCANS: 30

F-l8D R H L I L 1.

PAroe

i 9 : 4 L 0 4C J` v % - ,0, - ' 07: 

### 45 z'C

o l

~ illl 

### zewco 6 5 t

~ ? : a6

69:47 6. OIC 0 i 4 S 4 7 C 0 1 41 48. 4C "' 1 6" 7 :0 15 5 C , 9: 4 7 C Oi 5 1
7 "0 i c, 5 6i: 94 6 5 0 i 3 5. 5 O.-IC
7- 6 ' -

~ T•0 1: i cl

19 

# 1aa

### 7 

# MEMO [—J 

### E(1VIR0fl(11i=f1TAl



### APPENDIX G



# a Visible Emissions Data

95-134 G-1



## r~~

# ~ VISIBLE EMISSIONS OBSERVATION FORM


### Source Name ~~K~ $"0( - 

### Observation Date 6

~ 9 9S 

### Start Time / 60 ' z 6 

### Stop Time Address 1319 Phone 903
- 6s 7-3sa.s Source ID Number Pnxess Equipment s'r, ~ Operating Mode /6o t

~ 'c City ws a~ tate T.y. Zip Code 7565 2 Control Equipment Operating Mode -'?c 5'ccDescribe Emission Point 57,

~ f

a~ac~oom000 .



# mv I- 0000asn

mc~r-~einmooc-w

m®c~aoo©c~ov mac-~oomovr-~o mor-~oeovor~a~

mar~enor~vvo ovac-~emvoao o®c~000©avo 

### avy , /), S G-2 Height Above Ground Level /DD ' Distance Direetion from Observer

ZGlO ' from Observer Descrbe Emissions Emission Color

GdNi TE Plume Type: ,_ Continuous _ Fugitive —Intermittent Water Droplets Present: No _ Yes If Water Droplet Plume: _ Attached _ Detached , Point in the Plume at which Opacity was determined 

### Z Descnbe the Background 

### dF' 0 " r '`f`' -s ~ Badcground Color 

### 6eV1 Sky Conditions OvE~c~ST Wind Speed S - i0 Wind Direction 

### 1 1 7 — Ambient Temperature 

### $.s Average Opacity for Highest Period Number of Readings Above % Were Range of Opaaty Readings: O Minimum 

## ~ Ma)dmum Observers Name (Print) Observers Signature Date Organization Cettified By Date r S Verified By Date Source Layout Sketch Draw North Agow



## ~ X`L Emission Point

1 'L

Sun + Wind ' Plume and Stack



### C= _4, Observers Position

Sun Location Line Comments: oAWC , rY 4 0 C4 4- 6 LIAl I T CHnA!« 6-M&

-- e Zo.s

~ c. ~ vleW zo. I have received a copy of these opacity observations Signature Tille _ Date 

# m

### ~

~ 

## i 

## VISIBLE EMISSIONS OBSERVATION FORM

Source Name 

### Observation Date 6 30 9S 

### Start Time 

### pS -3 ~ 

### Stop Time 0938 Address 1009
~ «d

~ 'E"

~ . Phone 2 Sa3 6.573,

~ zS -- Source ID Number 6 7 PX1 /C

- ~ - ' Process Equipment h' , 5tr&&' ,R5z 1 ST'

. ~ ! Operating Mode ~ 7 ~ 1'/t °, ! Ci ta t e TX• Zip Code Control Equipment Ae1 Sceaa Operating Mode /80



# of ~ 

# os®esms®as 

# a©sso®©moo ©o ova®msoo ©momo©ovom o©mmmomvom ©mramm©vmom
mmmmmnmmmm 

# o©soam©oo ~ 

# MMMMMMMMM ~ 

# oamoamvvov 

# mmmomo©or-

~ 

# v mosoomvvov ®osoomoovv 

# ®©omoo©vvo ammmmmmmmm 

# ®msosmoovo m©ovom©ooa movaomvvvo 

# mmmmmmmmmm m©moom©o ~c~ 

# MMMMMMMMMM ®ODMO®v000 

# o©aoo®©©vv

mr.~ 

# ooramoc

~or~

mM I MMMOMMOM 

# LEMMMMOM



# MMM

Desabe Emission Point -172 

### ' 1 ~ Height Above Ground Level 

### /04 " Distance Direction 

### ~ from Observer Z~ ~ from Observer Desaibe Emissions FA

~ / Emission Color

t*lS

~ iTL5 Plume Type: _ Continuous _ Fugdive !E' Intermittent Water Droplets Present: k No _ Yes If VJater Droplet Plume: _ Attached _ Detached , Point in the Plume at which Opaaty was detennined 

### 2 Descrbe the Background Background Color.BLUE Sky Conditions 

### ,-e.6W e Wind Speed 

### .S Wind Direction Ambient Temperature 8D Average Opacity for Highest Period Number of Readings Above % Were Range of Opacily Readings: D Minimum 

### Z (5

-- M

- a)dmum Observers Name (Print) Observers Signature 

### ~~ Date

- 3 d 9S Organization w Certbed By

/'7 //lecif Date 3 p~ Verified By Date Source Layout Sketch Draw North Arrow
X 'z" Emission Point 

# IZ

Sun + Wind ' Plume and Stack



### C= _,& 

### ~ Observers Position



# — — )!

~ 

# r Sun Location Line Comments: y ~ .*C/7'3' dGCae'S r ~1~ r'E't/ c/'yi 7—

-- C/

~ r/tiE
- S o ✓ f ~ (a

~ •x ~ 1

~ osEC. Dv-e

~ T ia~/~ I have received a oopy of these opaaty observations Signature Title Date

G-3 

### ~~~

### (-! VISIBLE EMISSIONS OBSERVATION FORM


### Souroe Name Observation Date 6 36 S 

### Start Time Stop Time

. 14?0 o 

### Address ~- 3 ~ 1" / ~C~a~ - ~~ 

### Phone 9a36S 735-aS 

### Souroe ID Number Process Equipment /?,3So.09ET



### - , 7, -9 Opera6ng Mode /6 0
~ 7 a

~ 

### City -f

~ 1 ~ 0 -~ 

### tate 7

- 4 

### ZZp Code 75

-

6 S2 

### Control Equipment ~s~ .Sc.E'v ~.~2 

### Operating Mode 180 SE C ,



### to 

# ms®smms®s® a©ocav®©moo 

# ©mmvv®maioo ©ovvv©oo vv o©vvvo®vvo ©OVOGi©00©0
mmmmmmmumn 

# oQOriMm©ocao 

# oovovovmvo 00000mvovv 

# m©v000ravmv mia000mvvvv 

# ®vovomvvov ®M000M©000

mmmmmommmm 

# ®ovvomvvov mmme'om©vvm ®omvomvvvv moEaovovvvs momvom©moo

MMMMMMMMMM 

# ®mmom®omor- ~ 

# o©mvv®©000 ®r•ivvo©cimaio mmmvvovvoo ®vomv®©mvo mmmvonaooa ®r-amommvvvv m©ocavomvon

~ 

# omovomcs000 

# mm mmmommom Describe Emission Point 'y C ' 4t' Height Above Ground Level 

### /O , Q " Distance Direction ~ from Observer Z~ ~ from Observer Desaibe Emissions Emission Color ~ ✓

f~i7 ~ Plume Type: _ Continuous _ Fugiiive 'r Intermittent Water Droplets Present: -_Y No _ Yes If Water Droplet Plume: _ Attached _ Detached Point in the Plume at which Opacity was deteanined 

# z ~ Describe the Background <S~y Background Color 

## S

LUC Sky Conditions

- _ Sa 97 - Wind Speed _ ~ Wind Direction 

### N Ambient Temperature 

### 85 - Average Opacity for Highest Period Number of Readings Above °k Were Range of Opacity Readings: O Minimum 

### A 7 — Ma)dmum Observers Name (Print) Observers Signature Date Organization Certified By Tit/

,- CC Date 3/ 9S ' Verified By Date Source Layout Sketch Draw North Arrow
X
- -Emission Point i 1

Sun * Wind ~ Plume and Stack 

### C= ,,&, Observers Position

Sun Location Line Comments: Od" r/U SeC. Dd ~ E'9T1o ~ / I have received a copy of these opacity observations Signature Title Date


### 4 v g , o ~f C, - 4 1~~7-1 

# meco.

APPENDIX H Plant Operational Data

95-134 H-1 l''yl

# BoRAL BRICKS

~ 

# VA ; t Henderson Division P.O. Box 2110 • Henderson, Texas 75653-2110 Telephone 903/657-3505 FAX 903/657-7139 ~ ~ -~ I 

### ~,~ ~,~; ~~ I ~~~~ ,~j ~ - , 

## in J U L 12 1995 B v_

July 3, 1995



### Mr. Rob Patterson METCO Environmental P. O. Box 598 Addison, TX 75001 Dear Mr. Patterson: On Thursday and Friday June 29th and 30th, 1995, your firm performed Source Emission Testing on the Adsorber Stack (EPN-K) at the Henderson Plant to demonstrate compliance with Texas Natural Resource Conservation Commission Permit No. 21012 requirements. The following operating parameters were recorded during this Source Emission Testing and are submitted to METCO for reporting operating data on your report. Kiln #1 and #2 Throughput: 499.1 Tons/Day Of Fired Ware Kiln #1 and #2 Fuel Input: 1,266 MCF/Day Natural Gas Kiln #1 Stack Temperature: 485° F Kiln #2 Stack Temperature: 550° F Boral Bricks and I thank you for your cooperation in this matter, and if you have any questions or need more information, please contact me at (903) 657-3505. Thank You! Sincerely,

J. senhour, Jr. Manufacturing Manager Boral Bricks, Inc. ~

11-2 

# J39---

# Moco- ErmRonn'EffAc n

APPENDIX I



### A TACB Permit

95-134 

# 1 ~~?

# TEXAS AIIZ C®I®ITR®L B ®A.RD A PERMIT IS HEREBY ISSUED TO 

### BORAL BRICKS, INC. - HENDERSON BRICK DIVISION AUTHORIZING THE CONSTRUCTION AND OPERATION OF



### Henderson Brick - Plant No. 1

TO BE LOCATED AT 

### Henderson, Rusk County, Texas Lat. 32 0 10'51" Long. 94 0 48 1 '12" and which is to be aonstructed and operated in aocordance with and subjed to the Texas Clean Air Act (Texas Health and Safety Code, Chapter382) and all Rules, Regulations and Orders of the Texas Air Control Board. Said permit is subject to any additional or amended Rules, Regulations and Orders of the Board adopted pursuant to the Act and to all of the following conditions: l.'Ihis pemvt may not be transferred, assigned or cronveyed by the holder, and applies only to the location spedfied herein. 2 This permit is automatically void upon the oavnence of any of the following: a. Failure to begin oonstruction within eighteen months of the date of issuance. b. Disoontinuanee ofc+on.struc6on prior to completion for a period of eighteen oonsecutive months or more. c f'ailure to oomplete construction within a reasonable time. 3. The fadlities oovered by this penmit shall be constructed and operated as specified in the appUcation for the permit. 4. All representations regarding oonstrudion plan.s and operation procedures c+ontained in the perrnit application, unless spedhmlly changed in the appUmtion for this pennit beoome oonditions upon which this permit is issued. It shaU be unlawfui for any person to vary from such representation if the change will cause a change in the method of control of emissions, the character of the emissions or will result in an increase in the disdharge of the various emissions, unless he first makes appUmtion to the Execvtive IUirector to amend this permit in that regerd and such amendment is approved. 5. The Board shall be notified prior to the start-up of the fadlities authorized by this permit in such a manner that a representative of the Texas Air Control Board may be present at the time of start-up. 6. The Board shall be notified prior to the start of any required sampling and/or monitoring of the fadli ties authorized by this permit in such a manner that a representative of the Texas Air Control Board maybe present during the required sampling and/or monitoring. Upon request by the Fxecutive Director, the holder of this permit shall make sufficlent stack sampling analyses, or other tests, to prove satisfactory equipment performanoe. All sampling and testing procedures shall be approved by the Fxecutive Director and coordinated with the regional representatives of the Texis Air Control Board. IT - 7. This pemvt does not absolve the holder from the responsibility for the consequenoes of nonoomplianoe Kith all Rules, Regulations and Orders of the Texas Air Contiol Board or with the requirements of the Texas Clean Air Act 8 The faalities covered by this permit shall not be operated unless aU assodated air poUution abatement equipment is maintained in good worldng order and operating property during normal faalli ty operations. 9. Emissions from this faoility must not cause or aontribute to a mndition of'air poUution' as defined in Section 382003(3) of the Texas Clean Air Ad or violate Section 382085 of the Texas Clean Air Act lf the Fxecutive Director determines that such a oondition or violation occvrs, the holder shaU implement additional abatement measures as necessary to control or prevent the oondition or violation. 

# 1 ~ 10.ProvLions: See attachments labeled "General Provisions 21012, 

# ~ 1-6, and "Special Provisions 21012," 1-9. Acrocptance of the pentiit oonstitutes an aclmowledgement and agreement that the holder will comply with aU Rules, Rcgulations and Ordcrs of 

# i 1 the Board issued in conformity with the Acd and the c+onditions preoedent to the granting of this pemut. Failure to comply with all oonditions and ( spedal provisions of this permit will subject the holder to the enforcement provLsions of the Texas Clean Air Act This pemvt expires 5 years from date of issuance unless renewed as dcfined in Section 382055 of the Texas Clean Air Act



# ~ I S/7/9 3 PER

~ fTT h0. 2 10 12 DATE



## ~ FJCECITiVEDIRECTOR A5AIRCOVTROI.BOARD 

## ~

I-2 

## ~~

# ~ i 

### GENERAL PROVISIONS Permit No. 21012
1. Equivalency of Methods - It shall be the responsibility of the holder of this permit to demonstrate or- otherwise 

### justify the equivalency of emission control methods, sampling or other emission testing methods and monitoring methods proposed as alternatives.to methods indicated in the provisions of this permit. Alternative methods shall be applied for in writing and shall be reviewed and approved by the Executive Director prior to their use in ^ fulfilling any requirements of this permit.

2. Sampling Requirements - If sampling of stacks or process vents is required, *the holder of this permit must contact 

### the : Source and Mobile Monitoring Division of the Texas Air Control Board (TACB) prior to sampling to obtain the proper data forms and procedures. The holder of this ` permit is also
. responsible for providing sampling facilities and conducting the sampling operations at his own expense. 3. Appeal - This permit may be appealed pursuant to Rule 103.81 of the Procedural Rules of

- the TACB and Section 382.032 of the Texas Clean Air Act. Failure to take such appeal constitutes acceptance by the applicant of all terms of the permit.

~ 

### 4. Construction Progress - Start of construction,

construction interruptions exceeding 45 days and 

### completion of construction shall be reported to the appropriate regional office of the TACB not later than 10 

### working days after occurrence of the event. 5. Recordkeepinq - Information and data concerning production, operating hours, sampling and monitoring data, if applicable, fuel type and fuel sulfur content, if applicable, shall be maintained in a file at the plant 

### site and made available at the request of personnel from the TACB or any local air pollution control program having jurisdiction. The file shall be retained for at least two years following the date that the information or data is obtained. 6. Maintenance of Emission Control - The facilities covered by this permit shall not be operated unless all air pollution emission capture equipment and abatement equipment are maintained in good working order and operating properly during normal facility operations.

/ I-3 

# 13'~ .;

Li 

### SPECIAL PROVISIONS Permit No. 21012

EMISSION STANDARDS AND FUEL SPECIFICATIONS 

### 1. This permit covers only those sources of emissions listed in the attached table entitled "Emission Sources - Maximum A1lowable Emission Rates", and those sources are limited to the emission limits and other conditions specified in that attached table. Annual emissions are calbulated for a consecutive 12-month period. 2. Fuels used in both kilns shall be limited to natural gas (NG). The NG shall contain no more than 0.25 grains of hydrogen sulfide and 5 grains of total sulfur per 100 dry standard cubic feet. Use of any other fuel shall require 

### an amendment to the permit. , 3. Opacity of emissions from Emission Point No. (EPN)-K shall not exceed 5 percent, averaged over a 6-minute period, except for those periods described in Rule 111.111(a)(1)(E) of Texas Air Control Board (TACB) 

### Regulation I. INITIAL DETERMINATION OF COMPLIANCE 

### 4. The holder of this permit shall perform stack sampling and other testing as required to establish the actual pattern and quantities of air contaminants being emitted into the atmosphere from EPN-K. The testing required by this special provision shall be used to determine initial compliance with the pound-per-hour limits of the maximum allowable emissiori rates table. Initial compliance with the permit opacity limit shall be demonstrated on the basis of 30 six-minute averages. Sampling must be conducted in accordance with appropriate procedures of the TACB Sampling Procedures Manual and in accordance with Environmental Protection Agency (EPA) Reference Method 9 for opacity, Reference Method 10 for carbon monoxide (CO), Reference Method 7E for nitrogen oxides (NO x ), and Reference Method 3 for oxygen (0 2 ) or equivalent methods. The holder of this permit is responsible for providing the sampling and testing facilities, conducting the sampling and testing operation and all associated expenses. A. The TACB regional office with jurisdiction shall be notified as soon as testing is scheduled, but not less than 45 days prior to sampling to arrange a pretest meeting. The notice shall include:

I-4 

# /3~

### ~

SPECIAL PROVISIONS

Permit No. 21012 Page 3



### 6. Operational logs shall be kept for each piece of equipment listed in the Permit Table 1(a). These logs shall report the daily and year-to-date hours of operation and finished product production rates. Any abatement equipment downtime shall be recorded on the operational logs and referenced to the equipment it serVes. Operational logs shall be kept on-site for a period of two years and made available upon request to any representative of the TACB or EPA with jurisdiction. 7. Upon request by the TACB, the holder of this permit, at its own expense, shall make sufficient stack sampling analyses, or other tests, to prove compliance with-this permit. A11 sampling and testing procedures shall be • • approved by the TACB and coordinated with.the regional

representatives of_the TACB. 8. Upon request by the TACB, the holder of this permit, at its own expense, shall perform air dispersion modeling analyses as directed by the TACB to prove compliance with 

### this permit. ADDITIONAL PROVISIONS

~ 

### 9. The holder of this permit shall physically identify and

mark in a conspicuous location all equipment that has the 

### potential of emitting air contaminants as follows: A. The facility`"identification number as submitted to .the Emissions Inventory Section of the TACB. B. The EPN as listed on the maximum allowable emission rates table.

I-6 

# 131
.'

### EMISSION SOURCES - MAXIMUM ALLOWABLE EMISSION RATES Permit No. 21012

~ 

### This table lists the maximum allowable emission rates and all sources of air 

### contaminants on the applicant's property covered by this permit. The emission rates shown are those derived from information submitted as part of the application for permit and are the maximum rates allowed for these facilities. Any proposed increase in emission rates may require an application for a modification of the facilities covered by this permit. AIR CONTAMINANTS DATA Emission Source Air Contaminant 

### Emission Rates* Point No. (1) Name (2) Name (3) lb/hr TPY K Adsorber for both VOC 0.2 0.9 Tunnel Kiln Stacks NOx 4.0 17.6 S02 21.2 93.3 PM 10. 2 44 .8' `

- CO 1.3 5.8 

### HF 0.9 3.9 

### (1) Emission point identification - either specific equipment designation or emission point number from plot plan. (2) Specific point source name. For fugitive sources use area name or fugitive source name. (3) VOC - volatile organic compounds as defined in General Rule 101.1 NOx - total oxides of nitrogen

~ 

### S02 - sulfur dioxide

CO - carbon monoxide HF - hydrogen fluoride PM - particulate matter (all forms) * Emission rates are based on and the facilities are limited by the following maximum operating schedule; are based upon simultaneous operation of both kilns: Hrs/day 24 

### Days/week 7 

### Weeks/year 52 

### or Hrs/year8,760

I-7 

# I3~r ; 

# mgco- EnviRonrnEnTAC

APPENDIX J

0 Chain of Custody



## 95-134 J-1

~ 7

### r"1 

# ~ . •• . •

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### No. o( Aba«b. 

### I n ~ 

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### 45 z 9 MethoC P ro}ect



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## / Recov. b}/ sarYp;ex Z --Recav. bY S.arnp{eeK --'> Recx7v. by S.arrp;es Recov. 

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## /3d L«atEo«, ~/~ SampiGo Reaav. by Oate Tlme Locstfori 

### Sampdes Rcvd. by o~ tran s port DetA 6
~ d Tl me Se.tr - p;e Rcvd. at Eab by ~~ c_, Date Tlme 

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J-3 

# /~

### 1 

# V? I 

# MEICO 9MROMEf1TAl



## am APPENDIX K
Resumes of Test Personnel

95-134 K-1


## ~ 

# v

### ~ 

# METC-0- L_J 

### Ef1VIR0(1fTlEf (TAl

BILLY J. MULLINS, JR., President


## Education 

## Post Graduate Study Environmental Engineering at

Southern Methodist University, Dallas, Texas 1970. M.S. 1969, New York University, New York, New York, in Civil Engineering (Air Resources). B.S. 1968, Texas Tech University, Lubbock, Texas, in Civil Engineering (Water Resources). Studies in Engineering at U.S. 

## Naval Academy, Annapolis, Maryland, 1963-1964.
Professional Attended Short Course on Air Pollution Engineering at 

## Traininq the University of Texas at Austin, February 1970. Courses Attended four-week management course presented by the



## American Management Association, 1976.
Certification Registered Professional Engineer

Certified Visible Emissions Evaluator Certified Fallout Shelter Analyst Licensed Private Pilot (Multi-Engine-Land, Instrument) 

## Diplomat in the American Academy of Environmental Engineers Inductee into the Stack Sampling Hall of Fame
Professional 

## Air & Waste Management Association - Past Chairman, Past Vice Memberships 

## Chairman and Past Board of Directors

Southwest Section: Past Chairman, Consultants Committee; Past Chairman, Source Measurement Committee 

## Source Evaluation Society - Past President, Past Board of Directors American Management Association

K- Z 

# iq3

### ij 

# me 1E(1TAl :t i 1



### MULLINS

Publications 

### Co-authored "Sulfur Compound Emissions of the

Petroleum Production Industry," December 1974. Co-authored "Field Procedure for Stabilizing Hydrogen Sulfide Samples to be Analyzed Using Modified Methylene Blue Technique," presented at the Conference on Ambient Air Quality Measurements, Austin, Texas, March 1975. Co-authored "Atmospheric Emissions Survey of the Sour Gas Industry," October 1975. Co-authored "Technique for Insuring the Validity of Samples for High Concentrations of Sulfur Dioxide Using the EPA Method 5 Sampling Train,° presented at the Third National Conference on Energy and the Environment, College Corner, Ohio, September 1975. Teaching 

### Served as a lecturer in the Environmental Protection Experience 

### Agency's training course number 450, "Source Sampling

for Particulate Pollutants," for two years from January 1974 to October 1975 and in March, 1992. Conducted a two-day training course entitled "Technical Assistance in Source Sampling" at lowa State University, Ames, lowa, for the Environmental Protection Agency, October 1974. Conducted EPA's training course number 450, "Source Sampling for Particulate Pollutants," for the EPA at Research Triangle Park, North Carolina, September 1975.



# ,-, A

### In 

# me~ L~ 

### Ef1VIROf1f71

~ 

### f1TAL

MULLINS 

## Teachinq 

## Conducted a two-day short course entitled "Performing Experience 

## and Observing Source Sampling" at Dallas, Texas,

July 1976, May 1977, October 1977, November 1987 and November 

## 1988; at Lake Charles, Louisiana, May 1977; at Casper, Wyoming, May 1977; and at Point Comfort, Texas, November 1992. Served as a lecturer in the Environmental Protection Agency's two-day seminar entitled "Asphalt Industry 

## Environmental Solutions," presented in Dallas, Texas, on March 21 and 22, 1979. Conducted a two-day short course entitled "Performing and Observing Source Sampling" in Phoenix, Arizona in August, 

## 1990 for the State of Arizona, Department of Environmental Quality; in Lincoln, Nebraska, in March 1980 for the State of Nebraska, Air Quality Control Division. 

## Technical Directed and performed stack sampling on over Experience 

### 2000 sources of which over 500 were sampled simultaneously



## using more than one sampling train at several points in the flue gas stream. 1972-present. Directed and performed over 200 short-term ambient air 

## studies using mobile sampling vans and various ambient air sampling equipment. 1972-present. Designed, directed and operated over 20 permanent 

## ambient air networks of various size and duration for a variety of parameters. 1972-present. 

## Designed surface and underground drainage systems for residential subdivisions, public works projects, and shopping centers. 1969-1972. Designed several residential subdivisions including lot 

## layout, street design, drainage design, and utility design. 1969-1972.

K-4 I 

## ~~ 

# 9

r,

# MEFCO_ L~J 

### Ef1VIROfIfI'E(1TAL



### MULLINS


## Research Supervised and conducted a study made by the Hawaiian Proiects Sugar Planters' Association to characterize the emissions

for several bagasse-fired boilers. April-May 1976. Supervised and conducted a study made by the Rio 

## Grande Valley Sugar Growers, Inc. to determine the area affected by the burning of sugarcane fields prior to harvesting. November 1974-April 1975. Supervised and conducted a study by a lightweight 

## aggregate manufacturer to develop a material balance around the process through sampling and analysis of several parameters. November 1973. Conducted a study in New York City to attempt to 

## develop a correlation in the ambient air between carbon dioxide and sulfur dioxide to provide a tool for 

## predicting air pollution episodes. January-May 1969. Related Served as Chairman of the Engineering Foundation Conference on Proiects Stack Sampling and Source Evaluation in Santa Barbara, California,

1985. 

## Served as Session Chairman at th e Engineering Foundation Conference on Stack Sampling and Source Evaluati.on in Hershey, Pennsylvania, 1984; in San Diego, 

## California, 1993; and in Palm Coast, Florida, 1994.

n 

# 14 ~

r"

### ri 

# PIm Erc 

# o

—~ 

### Ef1ViROflfTli=fTfAl



### GORDON G. SMITH, Project Supervisor I


## Education B.S. 1988, University of Massachusetts, Amherst, Massachusetts, in

Environmental Design. A.S. 1986, Stockbridge School of Agriculture, Amherst, 

## Massachusetts, in Landscape Operations.
Professional Attended 40-hour Occupational and Environmental Training Program Training

, 

## on Hazardous Materials (CFR 1910.120) Dallas, Texas, April 1992. Courses


## Technical Participated in the sampling of over 150 sources, including several of Experience which were sampled simultaneously using more than one sampling

train. Thoroughly trained in all EPA testing procedures. 1992-present. p

~ 

### _ x-6 M ' I

# ~ 

# mErco- a

TIM STARTZ, Project Supervisor


## Education B.B.A. 1991, University of Texas at Arlington, Arlington, Texas,

in Management with a minor in Accounting.


## Professional Attended 40-hour Occupational and Environmental Training Program Traininq on Hazardous Materials (CFR 1910.120) Dallas, Texas, April 1992. Courses Also attended an 8-hour refresher course, February 1995.


## Technical Participated in the sampling of over 300 sources, including 

## Experience several of which were sampled simultaneously using more than one

sampling train. Thoroughly trained in all EPA testing procedures. 1992-present. 

## Experienced in the analysis of commercial calibration gas cylinders for CO 2 , 0 2 , NO X , S0 2 , and CO. Experienced with the Modified Method 5 Sampling Train (Method 0010). Experienced with the Chrome 6 Sampling Train. Experienced with the PM, o Sampling Train. 

## Experienced with various multiple metals and acid gas sampling trains. Experienced with the VOST sampling procedure (Method 0030). 

## Experienced with calibration techniques for all field testing equipment. Has performed on-site S0 2 analysis. Has performed on-site H 2 S analysis.

K-7 

# /4f

### ~ 

# METCO ~ 1 

### t`nVlRonmFiTAl_

STARTZ 

## Thoroughly trained in the operation and routine maintenance of the

following: Thermo Environmental Model 10AR and 10S Oxides of Nitrogen Analyzers Teledyne Model 326 Oxygen Analyzer 

## Ratfisch Model RS-55 Total Hydrocarbon Analyzer Horiba Model PIR 2000 Carbon Dioxide Analyzer J.U.M. Model VE-7 Total Hydrocarbon Analyzer Western Research 721 M Sulfur Dioxide Analyzer Thermo Environmental Model 48 Carbon Monoxide Analyzer Anarad 880 Oxides of Nitrogen Analyzer 

## Anarad 23 Oxygen Analyzer Anarad 30 Sulfur Dioxide Analyzer 

## Anarad 50C Carbon Dioxide Analyzer 0



## I h-s I W1 I

# V 

# ?J mErcoEnuRonrnEnTAC

DALE GREENFEATHER, Environmental Technician I


## Education B.S. 1994, Wichita State University, Wichita, Kansas, in Geology.
Technical Participated in the sampling of over 25 sources, including Experience several of which were sampled simultaneously using more than

one sampling train. Thoroughly trained in all EPA testing procedures. 1994-present.

K-9 

## ~