Emission Factor Development EX ~f' C 1 T- ~ =!\ 

11-- ;-- 0 0 9 sc~

}:eh 41 Rj 34 

Emtission Factor Develop for Stack Testino of Scrubber Stack at Boral Bricks, Henderson Plant in June, 1995 

by METCO 

Kiln 1 

Schedule: 43 cars/day 

2,916 brick/car 

Brick Weight: 3.98 Ib/fired brick (ve(fied by quaiity control reports) 

= 43 saf 2,916 brisk 3.98 ib I day I ton 

day saf bp;ska 1 24 hr 1 2000 Ib 

= 10.40 ton/hr 

Kiln 2 

Schedule: 43 cars/day 

2,916 brick/car 

Brick Weight: 3.98 Ib/fired brick (verified by quality control reports) 

43 saF 2,916 bdsk 3.98 ib I day I ton 

day eaF brisk 1 24 hr 1 2000 Ib 

= 10.40 ton/hr 

Total = 20.79 tonlhr 

Emission Factor Develoament 

fiiterabie PM = [ Average Emission Rate (Ib PM / hr) ] 

[ Kiln Throughput (ton / hr) j 

= 9.01 Ib hf 

if 20.79 ton 

filterable PM = 0.43 Ib/ton 

Emission Factor Summary: 

Pollutant Avg. Emission Rate Avg. Emission Factor 

PM 9.01 Ib/hr 0.43 Ib/ton 

SOZ 20.9 Ib/hr 1.01 Ib/ton 

NOx 5.37 Ib/hr 0.26 Ib/ton 

HF 1 1.171b/hr 

1 0.0561b/ton 

Notes - 

I 
PIMErco. 

 Ef1VIR0(1f71E('(TAl 

P.O. Dox 598 

Addison, TX 75001 

(214) 931-7127 

SOURCE EMISSIONS SURVEY 

OF 

BORAL BRICKS, INC. 

ABSORBER STACK (EPN-K) 

HENDERSON, TEXAS 

TACB PERMIT 21012 

JUNE 1995 

FILE NUMBER 95-134 
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TABLE OF CONTENTS 

PAGE 

1 

2 

7 

9 

11 

16. 

18 

INTRODUCTION 

SUMMARY OF RESULTS 

DISCUSSION OF RESULTS 

DESCRIPTION OF SAMPLING LOCATION 

SAMPLING AND ANALYTICAL PROCEDURES 

DESCRIPTION OF TESTS 

APPENDICES 

A. Location of Sampling Points 

B. Source Emissions Calculations 

C. Calibration Data 

D. Field Testing Data 

E. Analytical Data 

F. Reference Method Monitor Data 

G. Visible Emissions Data 

H. Plant Operational Data 

I. TACB Permit 

J. Chain of Custody 

K. Resumes of Test Personnel 

95-134 

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SOURCE EMISSIONS SURVEY 

BORAL BRICKS, INC. 

ABSORBER STACK (EPN-K) 

HENDERSON,TEXAS 

TACB PERMIT 21012 

; FILE NUMBER 95-134 

INTRODUCTION 

METCO Environmental, Dallas, Texas, conducted a source emissions survey of 

Boral Bricks, Inc., located in Henderson, Texas, on June 28, 29, and 30, 1995. The 

purpose of these tests was to determine the concentrations of particulate matter, :i 

hydrogen fluoride, sulfur dioxide, and oxides of nitrogen being emitted to the 

~ atmosphere via the Absorber Stack (EPN-K). The visible emissions were also 

determined. 

The sampling followed the procedures set forth in the Appendix to the Code of Federal 

Regulations, Title 40, Chapter I, Part 60, Methods 1, 2, 3B, 4, 5, 6, 7E, 9, and 1313; 

and in the "Sampling Procedures Manual, Texas Air Control Board, Revised July 

1985." 

The testing was observed by Mr. Greg Orr of the Texas Natural Resource 

Conservation Commission. 

~ 95-134 -1- 
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SUMMARY OF RESULTS 

Absorber Stack (EPN-K) 

* 29.92 "Hg, 68°F (760 mm Hg, 20°C) 

95-134 -6- 

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Run Number 1 2 3 

Date 06/29/95 06/29/95 06/30/95 

Time 0953-1110 1512-1632 0825-0941 

Stack Flow Rate - ACFM 84,544 87,277 85,329 

Stack Flow Rate - DSCFM* 44,301 45,234 45,239 

% Water Vapor -% Vol. 7.94 8.12 8.02 

%CO2 -%Vol. 2.2 2.2 2.2 

%02 -%Vol. 17.0 17.2 17.2 

% Excess Air Q Sampling Point 385 414 414 

Stack Temperature -°F 463 470 452 

Stack Pressure -"Hg 29.66 29.62 29.68 

Sulfur Dioxide Emissions - ppm 48.2 46.5 45.2 

Sulfur Dioxide Emissions - Ibs/hr 21.3 20.9 20.4 

Oxides of Nitrogen Emissions - ppm 16.0 17.0 17.0 

Ox ides of Nitrogen Emissions - Ibs/hr 5.08 5.51 5.51 
P_ 

IME1 

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DISCUSSION OF RESULTS 

The three tests for particulate matter and hydrogen fluoride appeared to be valid 

representations of the actual emissions during the tests. AII leak checks performed on 

the sampling train and the pitot tubes showed no leaks before or after each test. The 

indicative parameters calculated from the field data were in close agreement. The 

moisture percentages for the three tests were within 1.8 percent of the mean value. 

The measured flow rates (Qs) for the tests were within 0.8 percent of the mean value. 

The rates of sampling for the three tests were within the specified limits (90 to 

110 percent isokinetic). The greatest deviation from 100 percent isokinetic was 

1.4 percent. 

The calculated emissions (pounds per hour) of particulate matter for the three tests 

showed a range of -22.9 percent to +33.3 percent variation from the mean value. 

The calculated emissions (pounds per hour) of hydrogen fluoride for the three tests 

showed a range of -4.0 percent to +2.9 percent variation from the mean value. 

The three tests for sulfur dioxide and oxides of nitrogen appeared to be valid 

representations of the actual emissions during the tests. AII leak checks performed on 

the sampling train, the pitot tubes, and the monitor sampling system showed no leaks 

before or after each test. The zero and calibration drift tests of the monitor were 

stable with no variations greater than 3.0 percent. The calibration error check, 

sampling system bias check, and NO2to NO conversion efficiency check performed 

prior to testing were valid. 

9,5-134 -7- 

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The indicative parameters calculated from the field data were in close agreement. 

The moisture percentages for the three tests were within 1.2 percent of the mean 

value. The measured flow rates (Qs) for the tests were within 1.4 percent of the mean 

value. 

The collection efficiencies between the two sulfur dioxide impingers in these tests were 

very good, indicating that little, if any, sulfur dioxide was bypassed. 

The efficiencies were as follows: 

Run Number 1 2 3 

Impinger #2 99.3 99.0 98.9 

Impinger #3 0.7 1.0 1.1 

Collection of 90 percent or more of the sampled sulfur dioxide in the first sulfur dioxide 

impinger is a verification of a representative sample. 

The calculated emissions (pounds per hour) of sulfur dioxide for the three tests 

showed a range of -2.2 percent to +2.1 percent variation from the mean value. 

The calculated emissions (pounds per hour) of oxides of nitrogen for the three tests 

showed a range of -5.3 percent to +2.7 percent variation from the mean value. 

95-134 -8- 
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DESCRIPTION OF SAMPLING LOCATIONS 

The sampling location on the Absorber Stack (EPN-K) is 90 feet 6 inches above the 

ground. The sampling ports are located 40 feet (6.73 stack diameters) downstream 

from the inlet to the stack and 6 feet 5 1/2 inches (1.09 stack diameters) upstream 

from the outlet of the .stack. 

0- 

95-134 -9- 

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SAMPLING AND ANALYTICAL PROCEDURES 

The sampling followed the procedures set forth in the Appendix to the Code of Federal 

Regulations, Title 40, Chapter I, Part 60, Methods 1, 2, 313, 4, 5, 6, 7E, 9, and 136; 

and in the "Sampling Procedures Manual, Texas Air Control Board, Revised July 

1985." 

A preliminary velocity traverse was made at each of the two ports on the stack, in 

order to determine the uniformity and magnitude of the flow prior to testing. Several 

traverse points were checked for cyclonic flow and none was found to be present. 

Twelve traverse points were sampled from each of the two ports for a total of twentyfour traverse points. 

N The sampling trains were leak-checked at the nozzle at 15 inches of inercury vacuum 

before each test, and again after each test at the highest vacuum reading recorded 

during the test. This was done to predetermine the possibility of a diluted sample. 

The pitot tube lines were checked for leaks before and after each test under both a 

vacuum and a pressure. The lines were also checked for clearance and the 

manometer was zeroed before each test. 

An integrated orsat samples was collected and analyzed according to EPA Method 3B 

during each test. 

95-134 -11- 

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Particulate Matter and Hydrogen Fluoride 

Triplicate samples for particulate matter and hydrogen fluoride were collected. The 

samples were taken according to EPA Methods 1, 2, 3B, 4, 5, and 13B; and the 

"Sampling Procedures Manual, Texas Air Control Board, Revised July 1985." For 

each run, samples of five-minute duration were taken isokinetically at each of the 

twenty-four traverse points for a total sampling time of 120 minutes. Reagent blanks 

were submitted. 

The " front-half " of the sampling train contained the following components: 

Stainless Steel Nozzle 

Heated Glass Probe @ 248°F ± 25°F 

Heated Quartz Fiber Filter and Teflon Support @ 248°F ± 25°F 

The " back-half " of the sampling train contained the following components: 

Impinger 

Number Contents Amount Parameter Collected 

1 HPLC Water 100 mi Particulate Matter and 

Hydrogen Fluoride 

2 HPLC Water 100 ml Particulate Matter and 

Hydrogen Fluoride 

.3 Empty -------- Moisture 

4 Silica Gel 200 g Moisture 

Particulate matter emissions were calculated from gravimetric analysis using both the 

" front-half " and " back-half " collections of the sampling train. 

The hydrogen fluoride samples were analyzed by ion chromatography. 

95-134 -12- 

14 
mErcoo- EnuROnME-MAL 

Sulfur Dioxide 

Triplicate samples for sulfur dioxide were collected. The samples were taken 

according to EPA Methods 1, 2, 3B, 4, and 6; and the "Sampling Procedures Manual, 

Texas Air Control Board, Revised July 1985.° Large impingers (500 mi), as specified 

in EPA Method 8, were used. For each run, samples of three-minute duration 

were taken at each of the twenty-four traverse points for a total sampling time of 

72 minutes. At the conclusion of each run, the sampling train was purged for fifteen 

minutes with ambient air at the same rate at which the sample was taken. Reagent 

blanks were submitted. 

The " front-half " of the sampling train contained the following components: 

Stainless Steel Nozzle 

Heated Glass Probe @ 248°F ± 25°F 

Heated Glass Fiber Filter and Glass Support @ 248°F ± 25°F 

a 

The " back-half " of the sampling train contained the following components: 

Impinger 

Number Contents Amount Parameter Collected 

1 80% Isopropyl Alcohol 200 ml Sulfur Trioxide 

2 6% Hydrogen Peroxide 200 ml Sulfur Dioxide 

3 6% Hydrogen Peroxide 200 ml Sulfur Dioxide 

4 Empty ------ Moisture 

5 Silica Gel 200 g Moisture 

95-134 -13- 

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mErco 

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The isopropyl alcohol solution was checked for hydrogen peroxide contamination and 

none was found. 

The samples were analyzed by barium perchlorate titration using thorin indicator. 

Oxides of Nitrogen 

The oxides of nitrogen sampling was performed according to EPA Method 7E. A 

Thermo Environmental Model 10S Oxides of Nitrogen Analyzer (Serial Number 

10S-49429-282) was used to monitor the concentrations of oxides of nitrogen during 

each run. The reference method analyzer was operated at a range of 0 to 100 parts 

per million. A multi-point calibration was performed on the reference method analyzer 

prior to testing. An analyzer calibration error check, a sampling system bias check, 

and a NO2to NO conversion efficiency check were also conducted prior to testing. 

eN, After each run, the zero and calibration drift of the reference method monitor was 

checked. The calibration gases were as follows: 

Zero Nitrogen 

18.7 ppm NO in N2(ALM 40839) 

48.1 ppm NO in N2(BLM 3576) 

85.4 ppm NO in N. (ALM 38783) 

The reference method sampling system consisted of a heated probe; a heated glass 

fiber filter, a chilled condenser, and a teflon sample line. The calibration gases for the 

bias and drift checks were introduced upstream of the chilled condenser. 

Calibration gas certifications are included in Appendix C. 

95-134 -14- '~ 
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MEFCOOEnu ROn ff 1,9TA L 

Visible Emissions 

The visible emissions observations were performed according to EPA Method 9. The 

visible emissions were recorded at fifteen-second intervals over a sixty-minute 

observation period for a total of 240 readings. 

95-134 -15- 

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mErcoEnUROMEMAC 

DESCRIPTION OF TESTS 

Personnel from METCO Environmental arrived at the plant at 2:30 p.m. on 

Wednesday, June 28, 1995. After meeting with plant personnel, the equipment was 

moved onto the Absorber Stack (EPN-K) and secured for the night. AII work was 

completed at 6:00 p.m. 

On Thursday, June 29, work began at 6:45 a.m. The monitor was calibrated and the 

equipment was prepared for testing. The first test for sulfur dioxide and oxides of 

nitrogen began at 9:53 a.m. Testing continued until the completion of the second test 

at 4:32 p.m. The first test for particulate matter and hydrogen fluoride began at 

12:40 p.m. Testing continued until the completion of the second test at 7:22 p.m. The 

first test for visible emissions began at 6:20 p.m. and was completed at 7:20 p.m. The 

monitor was calibrated and the samples were recovered. The equipment was secured 

for the night and all work was completed at 8:30 p.m. 

On Friday, June 30, work began at 7:00 a.m. The monitor was calibrated and the 

equipment was prepared for testing. The third test for sulfur dioxide and oxides of 

nitrogen began at 8:25 a.m. and was completed at 9:41 a.m. The third test for 

particulate matter and hydrogen fluoride began at 10:18 a.m. and was completed at 

12:19 p.m. The second test for visible emissions began at 8:38 a.m. Testing 

continued until the completion of the third test at 12:20 p.m. 

957134 -16- 
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 ~JIf~O(1(TlE(nAl 

The monitor was calibrated and secured for transport. The equipment was moved off 

of the stack and loaded into the sampling van. The samples were recovered and 

transported to METCO Environmental's laboratory in Dallas, Texas, for analysis and 

evaluation. 

Operations at Boral Bricks, Inc., Absorber Stack (EPN-K), located in Henderson, 

Texas, were completed at 3:00 p.m. on Friday, June 30, 1995. 

. 

, 

Billy J. Mullins, Jr., P.E. 

President 

95-134 -17- 

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APPENDICES 

A. Location of Sampling Points 

B. Source Emissions Calculations 

C. Calibration Data 

D. Field Testing Data 

E. Analytical Data 

F. Reference Method Monitor Data 

G. Visible Emissions Data 

H. Plant Operational Data 

I. TACB Permit 

J. Chain of Custody 

K. Resumes of Test Personnel 

95-134 : 
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~METO 

8f1lJIR0f1(118f (rAL 

APPENDIX A 

Location of Sampling Points 

Absorber Stack (EPN-K) 

The sampling ports are located 40 feet (6.73 stack diameters) downstream from the 

inlet to the stack and 6 feet 5 1/2 inches (1.09 stack diameters) upstream from the 

outlet of the stack. The locations of the sampling points were calculated as follows: 

Port and Wall Thickness = 6 1/4 inches 

Inside Stack Diameter = 71 3/8 inches 

Point Percent of Diameter Distance 

Number From Wall From Wall 

1 2.1 1 1/2 " 

2 6.7 4 13/16 " 

3 11.8 8 7/16 " 

4 17.7 12 5/8 " 

5 25.0 17 7/8 " 

6 35.6 25 7/16 " 

7 64.4 45 15/16 " 

8 75.0 53 1/2 " 

9 82.3 58 3/4 " 

10 88.2 62 15/16 " 

11 93.3 66 9/16 " 

12 97.9 69 7/8 " 

95-134 A-1 

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APPENDIX A 

Location of Sampling Points 

Absorber Stack (EPN-K) 

0 

.. . . . . . . . . .. 

95-134 A-2 
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APPENDIX B 

Nomenclature and Equations 

for 

Calculation of Source Emissions 

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EnvlROnfTEnTAL 

NOMENCLATURE FOR PARTICULATE CALCULATIONS 

English Metric 

Symbol Units Units Description 

As in.2 m2 Stack Area 

Can gr/dscf* g/dscm* Particulate - probe, cyclone, and filter 

Cao gr/dscf* g/dscm* Particulate - total 

gr/CF 

Cat C~ stack g/m3 Particulate - probe, cyclone, and filter 

conditions 

gr/CF 

Ca„ C~ stack g/m3 Particulate - total 

conditions 

CaW Ibs/hr kg/hr Particulate - probe, cyclone, and filter 

Cax Ibs/hr kg/hr Particulate - total 

CP Pitot Tube Calibration Factor 

Dn in. m Sampling Nozzle Diameter 

%EA Percent Excess Air at sampling point 

g 32.2 ftlsec2 Acceleration of Gravity 

%I Percent Isokinetic 

%M Percent Moisture in the stack gas by 

volume 

Md Mole fraction of dry gas 

m f mg mg Particulate - probe, cyclone, and filter 

* 29.92 "Hg, 68°F (760 mm Hg, 20°C) B-2 fti 
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English Metric 

Symbol Units Units 

MWater 181b/Ib-mole 

m, mg mg 

MW Ib/Ib-mole g/g-mole 

M Wair 28.95 Ib/ 

Ib-mole 

MWd Ib/Ib-mole g/g-mole 

Pb "Hg mm Hg 

Absolute 

Pm "H20 mm H20 

Ps "Hg mm Hg 

Absolute 

AP "H20 mm H20 

Pstd 29.92 "Hg 760 mm Hg 

Qa ACFM m3/hr 

Q3 DSCFM* dscm/hr* 

R 21.83 "Hgft3/Ib-mole°R 

Tm ° F °C 

Description 

Molecular Weight of water 

Particulate - total 

Molecular Weight of stack gas 

Molecular Weight of air 

Molecular Weight of dry stack gas 

Barometric Pressure 

Orifice Pressure drop 

Stack Pressure 

Velocity Head of stack gas 

Standard Barometric Pressure 

Stack Gas Volume at actual stack 

conditions 

Stack Gas Volume at 29.92 "Hg, 

528°R, dry 

Universal Gas Constant 

Average Gas Meter Temperature 

* 29.92 "Hg, 68°F (760 mm Hg, 20°C) B-3 
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i`nvlROnfYIFWAL 

English Metric 

Symbol Units Units 

Tt min min 

T. °F °C 

Ts,d 528°R 293°K 

Vm ft3 m3 

Vmstd dscf* dscm* 

Vs fpm m/sec 

V. ml ml 

Vw9as scf'` scm'` 

pair 0.07481bs/ft3 

Pwater 1 g/m I 

Pman 51.631bS/ft3 

Description 

Net time of test 

Stack Temperature 

Standard Temperature 

Volume of dry gas sampled @ meter 

conditions 

Volume of dry gas sampled @ standard 

conditions 

Stack velocity @ stack conditions 

Total water collected in impingers and 

silica gel 

Volume of water vapor collected @ 

standard conditions 

Density of Air 

Density of Water 

Density of Manometer Oil 

Standard Conditions: 29.92 "Hg, 68°F (760 mm Hg, 20°C) 

'` 29.92 "Hg, 68°F (760 mm Hg, 20°C) B-4 
~ HIME] o 

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4. Mole fraction of dry gas. 

_ 100 - %M 

Md 100 

5. Average molecular weight of dry stack gas. 

MW —%CO x 44 +%O x 32 +%N x 28 +%CO x 28 = IbJlb-mole d 2 100 2 100 2 100 100 

= g/g-mole 

6. Molecular weight of stack gas. 

MW = MWdx Md+ 18 (1-Md) = Ib = glg-mole 

Ib-mole 

7. Percent excess air at sampling point. 

%EA = 

100 (%0

2 

 - 0.5% CO) 

0.265 (%N2) - [(%02) + 0.5 (%CO)] 

8. Stack Pressure. 

Stack Pressure "H O 

PS= Pb+ 2= "Hg Absolute 

13.6 

Ps="Hg Abs. x 25.4 + mm Hg 

.~ 

I 

'` 29.92 "Hg, 68°F (760 mm Hg, 20°C) B-6 
_7 Mm ~o 

 Ef1vIROf1fT16f1TAL 

9. Stack velocity at stack coriditions. 

2 

V— C 60 2g x P man x Pstd x MWa„ x(Ts + 460) x OPs 

S P 12 xPair xPsxMWxTstd 

2 

( T + 460) 

Vs= 5,123.8 Cp Ps x MW FP a verage = fpm 

Vs= fpm x 0.00508 = m/sec 

10. Dry stack gas volume at standard conditions.* 

1 Tstd Ps 

QS __ 144 VS x ASx Mdx TS+ 460 x Psrd 

Q_ 0.123 VS xAs xMd xPs 

 = DSCFM 

S Ts+ 460 

Qs= DSCFM x 1.6990 = dscm/hr 

11. Actual stack gas volume at stack conditions. 

Qa V 144 

s= ACFM 

Qa= ACFM x 1.6990 = m 3/hr 

* 29.92 "Hg, 68°F (760 mm Hg, 20°C) B-7 

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12. Percent isokinetic. 

al /o

Vmstdx(Ts+ 460) x Psrd x 100 x 144 

= 

Md x Tstd x Ps x Tt x VS nD" 

4 

0 1039 Vsrd x(T /o S + 460) 

~ _ Md xPs XTt XVS XD~ 

13. Particulate - probe, cyclone, and filter. 

0 

_m, 1 gr 

Can Vmsrd x 64.8 mg 

Ca„ = 0.0154 xm' = gr/dscP' 

Vmsrd 

Can = grldscf x 2.290 = g/dscm* 

14. Particulate total. 

Cao = 0.0154 X mt = grldscf 

Vmsrd 

Cao = gr/dscf x 2.290 = gldscm* 

* 29.92 "Hg, 68°F (760 mm Hg, 20°C) B-8 
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Ef1VIR0(1(1'lEf (TAl 

15. Particulate - probe, cyclone, and filter at stack conditions. 

PS ( Tsrd) 

Cat __ Can X Pstd 

X (TS+ 460) 

X Md 

C_ 17.65 XCanXPsXMd = r/CF 

a ` TS+ 460 g 

Cat = gr/CF x 2.290 = glm 3 

16. Particulate - total, at stack conditions. 

C _ 17.65 X Cao X Psx Md = gr/CF 

a" — TS + 460 

Cau = grlCF x 2.290 = g/m 3 

17. Particulate - probe, cyclone, and filter. 

C C XQ X 60min x 1/b 

aw — — an S 1 hr 7000 gr 

Caw= 0.00857 x CanX Qs= Ibs/hr 

Caw= Ibslhr x 0.4536 = kglhr 

18. Particulate - total. 

CaX= 0.00857 x Caox QS= Ibslhr 

CaX= Ibslhr x 0.4536 = kglhr 

* 29.92 "Hg, 68°F (760 mm Hg, 20°C) B-9 
~ ~m El 8 

E1VIR0(1fY1Ef1TAl 

EXAMPLE CALCULATIONS 

Ibs/hr = mg_ x 2.205 x 10"6Ibs/mg x DSCFM* x 60 min/hr 

Vmstd 

Vms,a = Volume of dry gas sampled (dscf") 

DSCFM* = Stack Flow Rate 

ppm = mq x 24.04 

Vms,d (m3) MW 

24.04 = Ideal Gas Constant liters/g-mole 

Vmstd = Volume of dry gas sampled (m 3") 

MW = Molecular Weight 

Compound Molecular Weight 

Hydrogen Fluoride 20.01 

* 29.92 "Hg, 68°F (760 mm Hg, 20°C) 

B -10 ~'l 
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EXAMPLE CALCULATIONS 

Ibs/hr = ppm x CF x 60 min/hr x DSCFM* 

CF = Conversion Factor for ppm to Ibs/scf" 

Compound Conversion Factor 

NOX 1.194 x 10"' 

* 29.92 "Hg, 68°F (760 mm Hg, 20°C) 

B-ll ~~ 
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EXAMPLE CALCULATIONS 

Equation 6C-1 

_ ~ _ Cma 

~' 

~ 

Cgas — C. - (io 

Where: Cgas= Effluent gas concentration - dry basis (ppm) 

-0= Average gas concentration indicated by gas ana/yzer - 

dry basis (ppm) 

Co= Average of initial and final system calibration bias check 

responses for the zero gas (ppm) 

Cm= Average of initial and final system calibration bias check 

responses for the upsca/e calibration gas (ppm) 

Cma= Actual concentration of the upsca/e calibration gas (ppm) 

~ 

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[~J E(1VIROf1fTlEf iTAI 

SOURCE EMISSION SURVEY 

~ JOB NUMBER: 95-134 

JOB NAME: BORAL BRICK INC. 

LOCATION: HENDERSON, TEXAS 

UNIT TESTED: ABSORBER STACK (EPN - K) PART/HF 

SOURCE EMISSION CALCULATIONS 

SYMBOL DESCRIPTION 

-----------------------------------------------------------------I 

UNITS 

I ----------------a 

I RUN # 

1 

I 

1 

1 

1 

--------------------I 

1 I 

I 

--------------------I 

2 1 

1 

--------------------I 

3 1 

I 

I 

1 DATE 

I 

I 

1 

I 

I 

1 

I 

I 

6-29-95 1 

I 

I 

6-29-95 1 

I 

I 

6-30-95 1 

I 

I BEGIN 1 1 1240 1 1718 1 1018 

I TIME I I I I t 

I 

I END 

I 

1 

I 

1 

I 

14491 

I 

1922 1 1219 1 

1 TIME I I 

I 

I I I 

I 

I P(b) 

I 

I BAROMETRIC PRESSURE "Hg Abs. 1 

I 

29.70 1 

I 

29.66 1 

I 

29.721 

I 

1 

I 

1 

(mm Hg) 1 

1 

(754)1 

I 

(753)1 

1 

(755)1 ` 

1 

1 P(m) I ORIFICE PRESSURE DROP "H20 1 1.1061 1.079 1 1.075 1 

I 

I 

I 

I 

(mm H20) 1 

1 

(28.1)1 

1 

(27.4)1 

1 

(27.3)1 

1 

1 V(m) I VOLUME DRY GAS SAMPLED ft.^3 1 74.315 1 74.035 1 72.762 1 

i 1 @ METER CONDITIONS (m^3) 1 

1 

(2.104)1 

1 

(2.096)1 

1 

(2.060)1 

1 1 

1 T(m) 

1 

I AVERAGE GAS METER DEG.F 1 851 86 1 81 1 

I 1 TEMPERATURE (DEG.C) 1 (29)1 (30)1 

1 

(27)1 

I 1 

1 V(m[std])' 

1 

I VOLUME DRY GAS SAMPLED 

1 

DSCF 1 

1 

71.675 1 71.174 1 70.738 1 

I 

I 

1 @ STANDARD CONDITIONS' 

1 

(DSCM) 1 

1 

(2.030)1 

1 

(2.015)1 

1 

(2.003)1 

1 

1 V(w) I TOTAL WATER COLLECTED, ml 1 122.2 1 125.9 1 122.8 1 

1 1 IMPINGERS & SILICA GEL I I I 

I 

I 

1 I 

I V(w(gas]) 

I 

I VOLUME WATER VAPOR 

I 

SCF 1 

I 

5.768 1 5.942 1 5.796 1 

I I COLLECTED @ STANDARD (SCM) 1 (0.163)1 (0.168)1 (0.164)1 

1 1 CONDITIONS' I I I I 

I%M I MOISTURE IN STACK GAS % 1 7.45 1 7.71 1 7.57 1 

1 1 BY VOLUME I I I I 

' 68 Deg.F, 29.92 "Hg (20 Deg.C, 760 mm Hg) B-13 

; 
~ 

FA 

MEK0 

SOURCE EMISSION CALCULATIONS 

BORAL BRICK INC. 

HENDERSON,TEXAS 

ABSORBER STACK (EPN - K) PART/HF 

SYMBOL 

----------------a 

DESCRIPTION UNITS 

Md 

-----------------------------------------------------------------I 

I MOL FRACTION OF DRY GAS 

I 

1 

I 

--------------------I 

0.9255 1 

I 

--------------------I 

0.9229 1 

I 

--------------------I 

0.9243 1 

I 

CO2 

I 

I 

1 

I 

% 1 

1 

I 

2.1 1 

1 

I 

2.21' 

1 

I 

2.01 

1 

02 

1 

1 

1 

1 

% 1 

1 

1 

17.31 

1 

1 

17.01 

1 

1 

17.21 

1 

CO 

1 

I 

I 

1 

% 1 

I 

1 

0.01 

I 

1 

0.01 

I 

1 

0.01 

I 

N2 

I 

I 

1 

I 

% 1 

1 

I 

80.6 1 

1 

I 

80.8 1 

1 

I 

80.8 1 

1 

'/oEA 

1 

I EXCESS AIR @ SAMPLING 

1 

% 1 

1 

426.2 1 

1 

385.3 1 

1 

408.4 1 

1 POINT I I I I 

VIWd 

I 

I MOLECULAR WEIGHT OF 

I 

LB/LB-MOLE 1 

I 

29.03 1 

I 

29.03 1 

I 

29.01 1 

1 DRY STACK GAS 

I 

(g/g-MOLE) 1 

1 

(29.03)1 

1 

(29.03)1 

1 

(29.01)1 

VIW I MOLECULAR WEIGHT OF LB/LB-MOLE 1 28.21 1 28.181 

1 

28.171 

1 STACK GAS 

1 

(g/g-MOLE) 1 

i 

(28.21)1 

1 

(28.18)1 (28.17)1 

DELTA P I VELOCITY HEAD OF STACK "H20 1 0.4871 

1 

0.478 1 

1 

0.470 1 

1 GAS 

I 

(mm H20) 1 

I 

(12.4)1 

I 

(12.1)1 

I 

(11.9)1 

Fs I STACK TEMPERATURE DEG. F 1 472 1 472 1 

I 

459 1 

1 

1 

(DEG. C) 1 

1 

(244)1 

1 

(244)1 

1 

(237)1 

's I STACK PRESSURE "Hg Abs. 1 29.66 1 29.62 1 

1 

29.681 

1 

1 

(mm Hg) 1 

1 

(753)1 

1 

(752)1 

1 

(754)1 

1 

✓s I STACK VELOCITY @ STACK FPM 1 3,041 1 3,018 1 2,968 1 

1 CONDITIONS 

1 

(m/SEC.) 1 

1 

(15.45)1 

1 

(15.33)1 

1 

(15.08)1 

1 

\s I STACK AREA (SQ.INCHES) 1 4,001 1 4,001 1 4,001 1 

I 

I 

(SQ.METERS) I 

1 

(2.58)1 

1 

(2.58)1 

1 

(2.58)1 

1 

)s I DRY STACK GAS VOLUME @ DSCFM 1 44,078 1 43,563 1 43,601 1 

1 STANDARD CONDITIONS' 

1 

(DSCM/HR) 1 

1 

(74,889)1 

1 

(74,014)1 

1 

(74,078)1 

1 

)a I ACTUAL STACK GAS VOLUME ACFM 1 84,480 1 83,852 1 82,471 1 

I @ STACK CONDITIONS (m^3/HR) 1 (143,532)1 (142,465)1 (140,118)1 

' 68 Deg.F, 29.92 "Hg (20 Deg.C, 760 mm Hg) 
~

MEMO 

J Ef1VIR0(1fTl>=(TfAI 

SOURCE EMISSION CALCULATIONS 

BORAL BRICK INC. 

HENDERSON,TEXAS 

ABSORBER STACK (EPN - K) PART/HF 

(o 

UNITS 

---------------I 

MINUTES 

IN. 

(m) 

% 

SYMBOL DESCRIPTION 

----------------a ----------------------------------------------- 

Tt I NET TIME OF TEST 

I 

I 

Dn I SAMPLING NOZZLE DIAM. 

%I I PERCENT ISOKINETIC 

I 

Mf 

I 

I PARTICULATE - PROBE, 

I CYCLONE AND FILTER 

Mt 

I 

I PARTICULATE - TOTAL 

I 

Can 

I 

I PARTICULATE - PROBE, 

I CYCLONE AND FILTER 

I 

Cao I PARTICULATE - TOTAL 

I 

Cat 

I 

I PARTIC.-PROBE, CYCLONE 

I AND FILTER @ STACK COND. 

I 

Cau I PARTICULATE - TOTAL @ 

I STACK CONDITIONS 

I 

Caw I PARTICULATE - PROBE, 

I CYCLONE AND FILTER 

I 

:,ax I PARTICULATE - TOTAL 

I 

1201 

1 

------------I --------------------I 

1201 

1 

--------------------1 

1201 

1 

1 

0.262 1 

1 

0.262 1 

1 

0.262 1 

(0.007)1 

1 

(0.007)1 

1 

(0.007)1 

1 

100.91 

1 

101.41 

1 

100.71 

1 

1 

60.4 1 

1 

1 

100.51 

f 

1 

81.01 

1 

I 

99.4 1 

1 

1 

148.71 

1 

1 

85.31 

1 

1 

0.0130 1 

1 

0.0217 1 

1 

0.0176 1 

(0.0297)1 

1 

(0.0498)1 

1 

(0.0404)1 

1 

0.0214 1 0.0322 1 0.0186 1 

(0.0489)1 

1 

(0.0737)1 

1 

(0.0425)1 

1 

0.0067 1 0.0113 1 0.0093 1 

(0.0154)1 

1 

(0.0258)1 

1 

(0.0213)1 

1 

0.0111 1 0.0167 1 0.0098 1 

(0.0254)1 

1 

(0.0382)1 

1 

(0.0224)1 

1 

4.90 1 8.12 1 6.59 1 

(2.22)1 

1 

(3.68)1 

1 

(2.99)1 

1 

8.07 1 12.01 1 6.94 1 

(3.66)1 (5.45)1 (3.15)1 

mg 

mg 

gr/DSCF* 

(g/DSCM) 

gr/DSCF* 

(g/DSCM) 

gr/CF 

(g/m3) 

gr/CF 

(g/m3) 

LBS/HR 

(Kg/HR) 

LBS/HR I 

(Kg/HR) I 

* 68 Deg.F, 29.92 "Hg (20 Deg.C, 760 mm Hg) 

B-1S 9r 
DATE I 

I 

I 

BEGIN I 

TIME I 

I 

END I 

TIME I 

I 

P(b) I BAROMETRIC PRESSURE 

I 

I 

P(m) I ORIFICE PRESSURE DROP 

I 

i 

V(m) I VOLUME DRY GAS SAMPLED 

I @ METER CONDITIONS 

I 

T(m) I AVERAGE GAS METER 

I TEMPERATURE 

I 

V(m[std])* I VOLUME DRY GAS SAMPLED 

I @ STANDARD CONDITIONS* 

V(w) 

i 

I TOTAL WATER COLLECTED, 

I IMPINGERS & SILICA GEL 

I 

V(w[gas]) I VOLUME WATER VAPOR 

I COLLECTED @ STANDARD 

I CONDITIONS* 

%M I MOISTURE IN STACK GAS 

I BY VOLUME 

Tt 

I 

I NET TIME OF TEST 

* 68 Deg.F, 29.92 "Hg (20 Deg.C, 760 mm Hg) 

MEMO [_J E(1VIR0(1(TlE(17A1 

SOURCE EMISSION SURVEY 

JOB NUMBER: 95-134 

JOB NAME: BORAL BRICK INC. 

LOCATION: HENDERSON, TEXAS 

UNIT TESTED: ABSORBER STACK (EPN - K) S02 

SOURCE EMISSION CALCULATIONS 

SYMBOL DESCRIPTION 

----------------I -------------------------- 

RUN # I 

UNITS 

--- — --------------- I --------------------I 

1 

1 

11 

I 

--------------------I 

21 

1 

--------------------I 

31 

1 

1 

1 

I 

I 

6-29-95 1 

I 

1 

6-29-95 1 

I 

1 

6-30-95 1 

I 

I 

I 

I 

I 

0953 1 

I 

I 

1512 1 

I 

I 

0825 1 

I 

I 

1 

I 

I 

11101 

I 

I 

1632 1 

I 

i 

0941 1 

I 

"Hg Abs. 1 29.70 1 29.66 1 29.72 1 

(mm Hg) 1 

1 

(754)1 

1 

(753)1 

1 

(755) i 

1 

"H 20 1 0.971 1 1.0001 1.0001 

(mm H20) 1 

1 

(24.7)1 

1 

(25.4)1 

1 

(25.4)1 

1 

ft^3 1 42.285 1 43.234 1 42.151 1 

(m^3) 1 (1.197)1 (1.224)1 

1 

(1.194)1 

1 1 

DEG.F 1 

1 

761 881 731 

(DEG.C) 1 

1 

(24)1 

1 

(31)1 

1 

(23)1 

1 

DSCF 1 41.454.1 41.4031 41.5861 

(DSCM) 1 

1 

(1.174),I 

1 

(1.172)1 

1 

(1.178)1 

1 

ml 1 

1 

75.8 1 

1 

77.5 1 

1 

76.8 1 

1 

1 

SCF 1 

1 

3.578) 

1 

3.6581 

1 

3.6251 

(SCM) 1 

1 

(0.101)1 

1 

(0.104)1 

1 

(0.103)1 

1 

% 1 

1 

7.941 

1 

8.12 1 

1 

8.021 

1 

1 

MINUTES 1 

1 

72 1 

1 

72 1 

1 

72 1 

B-16 3 
METCO-e C~J NIVIROf1fYlEf1TAL 

FM. 

SOURCE EMISSION CALCULATIONS 

BORAL BRICK INC. 

HENDERSON,TEXAS 

ABSORBER STACK (EPN - K) S02 

SYMBOL 

----------------4 

DESCRIPTION 

-----------------------------------------------------------------I 

UNITS 

Md I MOL FRACTION OF DRY GAS 

I 

1 

I 

--------------------I 

0.9206 1 

I 

--------------------I 

0.9188 1 

I 

--------------------I 

0.9198 1 

I 

CO2 

I 

I 

1 

I 

% 1 

1 

I 

2.21 

1 

I 

2.2 1 

1 

I 

2.2 1 

1 

02 

1 

1 

I 

1 

% 1 

I 

1 

17.01 

I 

1 

17.21 

I 

1 

17.2 1 

I 

CO 

I 

I 

I 

I 

% 1 

I 

I 

0.01 

I 

I 

0.01 

I 

I 

0.0 1 

I 

N2 

I 

I 

1 

I 

% 1 

I 

I 

80.8 1 

I 

I 

80.6 1 

I 

I 

80.6 1 

I 

%EA 

I 

I EXCESS AIR @ SAMPLING 

I 

% 1 

I 

385.3 1 

I 

413.61 

I 

413.6 1 

1 POINT I 

I 

I I I 

MWd 

I 

I MOLECULAR WEIGHT OF LB/LB-MOLE 1 

I 

29.03 1 

I 

29.04 1 

I 

29.04 1 

1 DRY STACK GAS 

1 

(g/g-MOLE) 1 

1 

(29.03)1 

1 

(29.04)1 

1 

(29.04)1 

1 

MW I MOLECULAR WEIGHT OF LB/LB-MOLE 1 28.161 28.141 28.15 1 

1 STACK GAS 

1 

(g/g-MOLE) 1 

1 

(28.16)1 

1 

(28.14)1 

1 

(28.15)1 

1 

DELTA P I VELOCITY HEAD OF STACK "H20 1 0.486 1 0.5131 0.506 1 

1 GAS (mm H20) 1 (12.3)1 (13.0)1 

1 

(12.9)1 

1 

Ts 

1 

I STACK TEMPERATURE 

1 

DEG. F 1 

1 

463 1 470 1 452 1 

1 

1 

(DEG. C) 1 

1 

(239)1 

1 

(243)1 

1 

(233)1 

1 

Ps I STACK PRESSURE "Hg Abs. 1 29.66 1 29.62 1 29.68 1 

1 

1 

(mm Hg) 1 

1 

(753) I 

1 

(752)1 

1 

(754)1 

1 

Vs I STACK VELOCITY @ STACK FPM 1 3,043 1 3;141 1 3,071 1 

1 CONDITIONS (m/SEC.) 1 (15.46)1 (.15.96)1 

1 

(15.60)1 

1 

As 

1 

I STACK AREA 

1 

(SQ.INCHES) 1 

1 

4,001 1 4,001 1 4,001 1 

I 

I 

(SQ.METERS) I 

1 

(2.58)1 

1 

(2.58)1 

1 

(2.58)1 

1 

Qs I DRY STACK GAS VOLUME @ DSCFM 1 44,301 1 45,234 1 45,239 1 

1 STANDARD CONDITIONS' (DSCM/HR) 1 (75,267)1 (76,853)1 

1 

(76,861)1 

1 

Qa 

1 

I ACTUAL STACK GAS VOLUME 

1 

ACFM 1 

1 

84,544 1 87,277 1 85,329 1 

1 @ STACK CONDITIONS (m^3/HR) 1 (143,640)1 (148,284)1 (144,974)1 

` 68 Deg.F, 29.92 "Hg (20 Deg.C, 760 mm Hg) 

B-17 
IN 

F?lms o 

 Ef1VIR0(1(71Ef1TAl 

SULFUR DIOXIDE EMISSION DATA 

JOB NUMBER: 95-134 

JOB NAME: BORAL BRICK INC. 

LOCATION: HENDERSON, TEXAS 

UNIT TESTED: ABSORBER STACK (EPN - K) 

I 

S02 

I--------------------------------------------- 

I RUN NUMBER 

1 --------------------------------------------- 

------------------I ------------------I 

1 1 

I 

2 

------------------I 

3 

I DATE 

1 

1 6-29-95 

I 

6-29-95 6-30-95 

--------------------------------------------- 

I START TIME 

1 

1 0953 

I 

1512 0825 

--------------------------------------------- 

I END TIME 

1 

1 1110 

I 

1632 0941 

--------------------------------------------- 

I N- NORMALITY OF Ba(CI04)2 

I ---------------------------- 

1 0.0100 

I 

0.0100 0.0100 

- ------------ -- 

I ML(I)- ml IN IMPINGER 2 

1 

1 380.00 

I 

395.00 400.00 

-- ------------ - ---------------- ---------- 

I ML(I)- ml IN IMPINGER 3 1 335.00 

I 

444.00 330.00 

1 ------------------------- - ------ - ----- ---- 

I ML(A)- ml IN ALIQUOT #2 

1 

1 3.00 

I 

3.00 3.00 

--------------------------------------------- 

I ML(A)- ml IN ALIQUOT #3 1 10.00 

I 

10.00 10.00 

I -- ----- -- -------------- -------------------- . 

I ML(B) - mi OF Ba(CI04)2 TO TITRATE #2 1 3.73 

I 

145 3.33 

1 ---------------------------------- ---------- 

I ML(B) - ml OF Ba(CI04)2 TO TITRATE #3 

1---------------------------- - ---------- -_- 

1 0.15 

I 

0.15 0.20 

I ML(BB) - ml OF Ba(CI04)2 TO TITRATE BLANK 

1-- -------------- - ------ - ---- - ---- -------- 

1 0.05 

I 

0.05 0.05 

I Tm - AVERAGE GAS METER TEMPERATURE, DEG.F 1 76 

I 

88 73 

1 --------------------------------------------- 

I Vm - VOLUME OF DRY GAS SAMPLED @ METER 1 42.285 43.234 42.151 

1 CONDITIONS, FT^3 

I --------------------------------- 

I 

----------- I 

I Pb - BAROMETRIC PRESSURE, "Hg Abs. 1 29.70 

I 

29.66 29.72 

1 --------------------------------------------- 

I Qs - STACK GAS VOLUME DRY @ STANDARD 1 44,301 45,234 45,239 

1 CONDITIONS, 'SCFM 

I ----------------------------- 

I 

- ----- -------- I 

I C(I) - S02 IN IMPINGER #2 IN mgs 1 149.16 143.25 139.95 

1-------------------------- - ------ - --- ---- 

I C(I) - S02 IN IMPINGER #3 IN mgs 

I 

1 1.07 1.42 1.58 

1-------------------------------------------- 

I C(T) - TOTAL S02 IN IMPINGERS, IN mgs 

I 

1 150.2 

I 

144.7 141.5 

1 --------------------------------------------- 

I ppm S02 1 48.2 46.5 45.2 

1 --------------------------------------------- 

1 C(S02) - EMISSION RATE OF S02, Ibs/day 

I 

1 510.5 

I 

502.6 489.6 

1 --------------------------------------------- 

1 C(S02) - EMISSION RATE OF S02, Ibs/hr 1 21.3 

I 

20.9 20.4 

1 --------------------------------------------- 

I Cs - EMISSION RATE OF SULFUR, Ibs/day 

I --------------------------------------------- 

1 255.2 

I 

251.3 244.8 

' 68 Deg.F, 29.92 "Hg (20 Deg.C, 760 mm Hg) 

C(I) = ML(I) '[ ML(B) - ML(BB) ]' N - 32 / ML(A) 

C(T) = C(I) #2 + C(I) #3 

ppm S02 = 0.7513 ' C(T) '[ Tm + 460 ]/ Vm ' Pb 

C(S02) = ppm S02 ' Os ' 0.0002392 3_ 1 s 

~ 

~ 

Jc/ 
~ 

...~ 

i 

~

MEFCO. 

1 Ef1VIR0(1fYlG1TAl 

SULFUR TRIOXIDE EMISSION DATA 

JOB NUMBER: 95-134 

JOB NAME: BORAL BRICK INC. 

LOCATION: HENDERSON, TEXAS 

UNIT TESTED: 

--------------------------------------------- 

ABSORBER STACK (EPN - K) 

I ------------------I ------------------I 

S02 

RUN NUMBER 

--------------------------------------------- 

1 1 

I 

2 

------------------I 

3 

DATE 

--------------------------------------------- 

1 6-29-95 

I 

6-29-95 6-30-95 

START TIME 

--------------------------------------------- 

1 0953 

I 

1512 0825 

END TIME 1 1110 

I 

1632 0941 

--------------------------------------------- 

N- NORMALITY OF Ba(CI04)2 1 0.0100 

I 

0.0100 0.0100 

--------------------------------------------- 

ML(I) - ml IN IMPINGER 

--------------------------------------------- 

1 208.00 

I 

300.00 262.00 

ML(A) - ml IN ALIQUOT 

--------------------------------------------- 

1 10.00 

I 

10.00 10.00 

ML(B) - ml OF Ba(CI04)2 TO TITRATE 1 0.63 0.45 0.70 

--------------------------------------------- 

ML(BB) - ml OF Ba(CI04)2 TO TITRATE BLANK 

I 

1 0.05 0.05 0.05 

--------------------------------------------- 

Tm - AVERAGE GAS METER TEMPERATURE, DEG.F 

I 

1 76 

I 

88 73 

--------------------------------------------- 

Vm - VOLUME OF DRY GAS SAMPLED @ METER 1 42.285 43.234 42.151 

CONDITIONS, FT^3 

--------------------------------------------- 

I 

I 

Pb - BAROMETRIC PRESSURE, "Hg Abs. 1 29.70 

I 

29.66 29.72 

--------------------------------------------- 

Qs - STACK GAS VOLUME DRY @ STANDARD 1 44,301 45,234 45,239 

CONDITIONS, 'SCFM 

--------------------------------------------- 

I 

I 

C(I) - S03 IN IMPINGERS IN mgs 

--------------------------------------------- 

1 4.8 

I 

4.8 6.8 

ppm S03 

--------------------------------------------- 

1 1.2 

I 

1.2 1.7 

C(S03) - EMISSION RATE OF S03, Ibs/day 

--------------------------------------------- 

1 16.4 

I 

16.7 23.6 

Cs - EMISSION RATE OF SULFUR, Ibs/day 

--------------------------------------------- 

1 6.6 

I 

6.7 9.4 

' 68 Deg.F, 29.92 "Hg (20 Deg.C, 760 mm Hg) 

C(I) = ML(I) '[ ML(B) - ML(BB) ]' N' 40 / ML(A) 

ppm S03 = 0.6021 ' C(I) '[ Tm + 460 ]! Vm ' Pb 

C(S03) = ppm S03 ' Qs ' 0.0002991 

Cs = C(S03) / 2.5 

B-19 

le 
~ FIMEM0, Ef1VIR0(1(11Ff7fAl 

Equipment 

Pitot Tube #17-10-1 (56) 

Pitot Tube #HT-4 

Pitot Tube #12-10-1 (29) 

Probe Tip #17-4 (II-4) 

APPENDIX C 

Calibration Data 

Calibration Factor 

0.814 

0.809 

0.808 

0.262 

Calibration Date 

04/11/95 

04/06/95 

04/20/95 

04/11/95 

Dry Gas Meter #17-2 (17) 1.005 04/11/95 

Stack Unit Orifice #17-2 (17) 04/11 /95 

Digital Temperature 

Indicator #17-2 (17) 04/11/95 

Barometer #17-2 (10) 04/10/95 

95-134 C-1 

REK1,1 0 i ~ 
~ 

PITO`l' TUBE CALIBRA"I'ION 

Date: 'fime: /.` /y 

Pitot No. /-(O- b' 

-„ 

Hg 

Pitot Dimensions: /p' 

T~ s : G _ ~ F 

CALIBRATOR 

Pfotor fps STANDARD STANDARD CAL. 

Settine mark START END AVERAGE , HIGH IIIGH FACTOR 

P s :— "H 2 0 

Cpstd:(). q~ 

CAL, 

LOIV ~CIV FAr-rr 

4 20 O(0 c:.lu 0 , 3 16 a.l.S s 9 --7 6.808 387 n. P,C4 

20 30 D.ClGR D. ~;-6G `” D. 0,' : .154; 

31 40 0 SS 3 Ci ) 0.10 1& 6 0'7 , I G 

39 50 O.S, b. V 95- O.P 1 0.qc0 p. Ct3 ~ 0 ~?' U.Roo 

49 60 ~~ o.0 0. 9,9 q i. I cR .' 0'l l. v 1.colS 0 80 8 

57 70 ton 0.r{2 ~ i.S"e, l, 2 2 5- U,o 

68 80 ;, ~ /. iqo i 9 /,396 0. SOP, 0 qlq 0.'79 

76 90 l.rr 1.6o /.2LS 2-35 /.S 3 

JI 

0. ", L7 2_v~ y .-,, o. 

39 SO O.Sy O.Sq 0.7 S 2 O. ioo C:.°ct'. o. , 0.9 00 O. 0 c 

 ~ 

39 50 

Average p ; 0. 0 

Summary of Results: 

Normal higlt side calibration factor '? ~ ~ 

variation 0. 74"% 

N'ormal low side calibration factor 

variation 

Signature of Calibrator 

✓ `. 

~4L 
~ 

P ITO'I' TUBC CALI BRATION 

Date: y - (0 - `J57 'C.imc: `f- SO 

Pitot \~ o. '~ ~ ~ 

~ ~ P b : Zy- z Hg 

T : 7 °r 

Pitot Dimensions: ~ X s 

CALIBRATOR 

Motor fps STANDARD STANDARD CAL. 

Setting mark START END AVERAGE . HIGH \ HIGH F'ACTOR 

p s: -- I IH2O 

c

pstd: O. 17 `J 

CAL. 

i.nN l i ntv FArTn 

a 

4 20 `~.~(~ ~~~ ~- ~ ~~s 

D- 57 

bG06 

20 30 D- 2Z D. 2 2- 0 2323 0.69OC13 1 0.3 D S7`{ b. 

31 40 (2- 3 Y .3q 5-3,J d• 7/`{ ('~ 9,00 9,7 7/y O~ 

39 50 0- -SY _Jr 7 ~- ~J~ (~~~ -~7C20 D. 0.8' 

49 60 (2,60 0- c~'f'(Z i- Z0 /- 075- U- 5'-76 j• l.S 1-07Z O. 82-Z 

57 70 V• 0U 1.01f) OC) 1• 2Z5 O-OOB 1, SO 1• ZZS 0.9: ~) LC 

68 80 ~0 21010 Iql 0.CC306 IJ~f !. ~G 0, 916 

76 9 0 l. ~D (. ~ ~ /. ZC~S Z. 3s ). 533 - 81 2. 35- i. 5 13 8( 

39 50 5V 0- 73.5 U G0.3 ,090 0 1Qg a L 

39 50 b o- 73 5 808 Z - 90b ~30` 

Average ~. ~'o? 0- 31 2 

Summary of Results: 

Normal liigh side calibration factor 0_- sUy 

variation 

Normal loW side calibration factor 

variation f1.3$ -Off7t, / 

~ 

✓ ~/~ 

4- / D Z ~ 

ig ture of Calibrator 

C-3 

04-3 
0 

1 I"IT01' TUB(: G1LIBRATION 

Date: 26 f~ ./', :/ j4 Q S "rime: 

Pitot No. /Z-/0- / ( zq ~ 

Pb ?g./ ~7 "lig P s : _ ~~H 2 O 

Ts ~ y or Cpstd: Pitot Dimensions: ~~ ` K,~/~ " e) c~ ~ 

CALIBRATOR 

Motor fps STANDARD STANDARD ~-~ - CAL. CAL. 

Settin e mark START END AVERAGE , HIGH V HI(;fi

- 

rACTnR r.n a .FT OIIJ I:A!`-rnn 

4 20 .!O . 1 0 O. P 0 . SZ9 O/S ct387 

20 30 , ~ _ Z ~ •3> 5 ► `~ O. ~t ~ ~.3Z 0.5~~ 

o.82 " 

31 40 0.'3y v. o• y 0•gog o.5o .•70`7 $1W 

39 SO p Sy 0.54 0:?35 ,; 2. 0,. 9rD 03(-5 0 -29 1 $t 8 

49 60 ~~fa t~ ~O G.5 ~`~ oRS t)-8og a0 l.095 

S 7 70 1 , 66 (,415 I. zeq CS~z - 11 ~1 , c4 

68 80 1.30 1.30 1.140 1 , q5 1.3 114F ~.~~c~ 1.170 1.3 -~ `0 o gl 

76 90 I.(00 o 1.2r,5 -2. 3s 1533 

39 SO 0. 5q o-s`I o.735 G• SZ o.`I o 0. (?e3 7`? v. ,99 `7 0. ele 

39 50 S,4 o. s

-4 0_ 735 O. ;S''Z 0. q i a_ a -) 9 0. W1 

Average 0 .gcg 

Summary of Results: 

Normal hig11 side calibration factor 

variation 

N'ormal low side calibration factor 

variation 0.q8n, 

Signature of Calibrator 

C-4 
M2 

~ 

.., 

~ 

NOZZLE CALIBRATION 

Nozzle Set No.~~l~'~ 

MEFCO 

L_J E(1VIR0(1(TlE(TML 

Date: z//// Calibrator: 2( u,~ 

1 2 3 4 5 

Reading 1 -)- S 0,2op n_ 2S4 0, 2.62. 0. 320 

Reading 2 oi 2S o.2og D.2S6 b 2r;2, 0• ~ Z3 

Reading 3 0. i2S y. zoq n.2SG 6. -1G2 b 31 ~ 

Reading 4 ~~ izS 0.20R (1).25Is' 63)c'-) 

Reading 5 p 0.322 

Reading 6 o. fl O. 2 s'G 0.321 

Reading 7 c.i2s ~".2on o_~r~ o• , .~ z b. i2l 

Reading 8 a 72S 0.2oG D x_~( O. ~ GZ 0.32G 

Reading 9 o. i 2 2 rG b. -;L t,%t O•922 

Reading 10 i2S c2.25-(f, 0. ~ G2 0.32U 

Average o.; zS ~ O. Zo ~ ~ O 

6 7 8 9 10 

Reading 1 0.301 D. 31,1 D. 017 D. q1.S O. (0?7 

Reading 2 b. ~~u3 D.'~2 ~ 6.y77 0.lo3 -7 

Reading 3 0. 3L-U P. 0• yz?I Q. 43 7 

Reading 4 ~~oS 0.3G2 D.q -z $ o.q 27 0.&36 

Reading S p ~ C(, G.3L ~ D , `~~ ~ ~g t~. 6 97 

Reading 6 0~O~ 0.3b1 Q 66, -31a 

Reading 7 U.;ot 0.1101 b.421 6,3-1 

Reading 8 O. D 36,1 h37 

Reading 9 O31C 0.3&1 0.63Q 

Reading 10 e,306 0.3 n D.l ~'~ D.yz? 

Average 0,306 

C-5 

~~~1 
~ 

.S 

~ 

i 

to 

~

MUCO 

Ef1VIROf1f'(1Ef7TAl 

Dry Gas Dteter Calibration 

Dry Gas Aleter Number/~ =z 

Dat e : //~ 

oH 

("H2 0) CDG 

0.5 /, Do0 

1.0 ODZ 

1.5 /,DD~/ 

2.0 /, ODIo 

3.0 /, DD-7- 

4.0 /,D// 

Average ~ p4S Variation: 

Calibrator: ~ 

Checked by: 

C DG @ 2 liters/min. = / O08 

C-G 
I! 

1{ 

..~ 

~ ~ • 

• • •• ll~ 

DRY GAS METER CALIBRATION 

hleter Number•/17-.z Calibrator: 

Date: 

Wet Test hfeter V 

Calibration Factor (C ) = mstd 

 DG Dry Gas bieter V 

mstd 

Run No. : ~~~ -Sa ~ ~ pb : ~9~8 IlH

g 

Control r[odule Vacuum "Hg 

IVET TEST METER (No. r2 ) DRY GAS METER 

I Meter p Meter Temp. P 

Time Reading Tem . m Reading In Out m 

!~ End cf °F /30 „H20 MZ& cf 71 °F 69 ° F "H 2O 

Start 083;- p.000 cf ° F -/,30 ~ +H ZO ~~.Z~ cf ~D°F 68°F 4,~`z~ ~~H 2O 

~ ~ ° a. so 

cf ° F "HZO cf F "H 20 

-/ .30 

iVet Test bteter V = 17.65 x -,5-.A,/, y — v7/g, -zg + 13.6 

mstd + 460 (C f) 

Dry Gas Meter V 

mstd 

= 17.6S x — 

D• .So 

a9z8 + 13.6 

~j~ + 460 

z 

=y9~~ dscf 

C DG y 9;Ps 

C_7 

ki" / 
v~i I 1 ~ziQU 

ff"ROM)EML 

DRY GAS METER CALIBRATION 

Meter Number: ~7~ ~'2 Calibrator: 

D a t e: 

 m 

Wet Test Meter V 

Calibration Factor (C ) = std 

DG Dry Gas Meter V 

m std 

Run No . . . / OO L~ O Pb : ~ --~ 19 "Hg 

Control Module Vacuum "Hg 

1VET TEST METER (No . ^2) DRY GAS METER 

Meter p Meter Temp. P 

Time Reading Tem . m Reading In Out m 

~! End 6903 53~9 cf °F -'H 2O Gos-&2cf "~(~ 7 °F ~O °F /DO 1-H20 

Start 0855~ O•000 cf °F "H20 OCD-5711~ f °F G9 °F /.40 "H 20 

3 3~~ 

/cf 

aF -~ 9D -Z 

~,Z oF ~DO 

2 

„H 0 f "H 0 2 

1Vet Test Meter V 

mstd 

= 17.6S x S 3-?9 — 1-09 198 + 13.6 ~ 

+ 460 (C f) 

Dry Gas Meter V = 

m std 

17. 6 S x S. 30Z o?9• a8 

~ z 

/. 00 

+ 460") 

~ 

dscf 

~ 

CDG 

C-8 
kz-~ 11 I~7-1LU 

DRY GAS 61ETER CALIBRATION 

Meter Number: 

Date: 

~ 

Calibrator: 

Wet Test Meter V 

Calibration Factor (C ) = mstd 

DG Dry Gas Meter V 

mstd 

Run No . :. /~/SO ril~ D pb: 079 .Zg "Hg 

Control Module Vacuum "Hg 

IVET TEST METER (No. ;2) DRY GAS METER 

Meter P hieter Temp. P 

Time Reading Tem . m Reading In Out m 

End ~.ZoZ /O. Qo.Z cf ~~ 'F =Z.30 H 2O D .S/Dcf °F ° F "H 2O 

Start —~ 

cf ~7 /° F H 0 GL-f -7S °F °F /.So "H 0 

/o.D62 

cf F 

o -a 30 , 9- 9i~ ~ ~y ✓ ~ ~—o 

H 20 cf 

0

F "H 20 

. –.7• 3U _ ~ 

IVet Test ~teter V = 17.65 x/4 06~ Z = 9 dscf °?9 8 + 13.6

)

YO-~3 ~g 

m std ~~ + 460 (C f) 

Dry Gas Ateter V 

mstd 

= 17.6S x 9• 9/49— 

CDG 

/, SD 

079 ~8 + 13.6 

+ 460 

9 ~~g 

9 ~2 ~ 

_ a?-,;Zdscf 
ITIEK-0 

DRY GAS b1ETER CALIBRATION 

hteter Number: ~7~ `'? Calibrator: 

D a t e: 

, 

Wet Test Meter V 

Calibration Factor (C ) = mstd 

DG Dry Gas Meter V 

mstd 

Run No . : . / 6~, eD 

IVET TEST METER (No. 02) 

P : °79 ?8 "Hg b 

Control rfodule Vacuum "Hg 

DRY GAS METER 

iR 

Meter P Meter Temp. P 

Time Reading Temp. m Reading In Out m 

End /D 4590 cf °F 11H ZO OZB.6.3.5 cf OF 9'.Z OF ,7 Do „H20 

Start 49ZS O.00O cf ~/ °F ~ ~o ~~H 0 O/8//.Z cf °F ~V OF ,~.DD t'H 2 0 

i 

/D•69~ ~/ -~. 30 /D S23 / 

, 

~~ 

cf ° F "H 20 cf 

0

F "H ZO 

{Vet Test ~teter V 

mstd 

= 17.6S x /O. 

= 

oz92g 

In 

+ 13.6 X D~3 =~~,Z6/d s c f 

+ 460 (C f) 

Dry Gas Ateter V 

mstd 

17.6S x l,~, .523 

~lo 

,z, o0 

+ 13.6 

+ 460 

✓ 

dscf 

CDG 

/O. Z6/ 

C-10 

~~ 
vzel ~~~ iQv 

RXYTEMAL 

a 

DRY GAS METER CALIBRATION 

Meter Number:/~---~ 

D a t e : ~,~~//, /99.~ 

--~ -~ 

Calibrator: 

Wet Test Nfeter V 

Calibration Factor (C ) = mstd 

DG Dry Gas Meter V 

mstd 

Run No . : / ~3 DD ~~I 4~1 Pb:•~

9219 "Hg 

Control Module Vacuum S 4 "Hg 

1VET TEST METER (No. -17) DRY GAS METER 

Meter p Meter Temp. P 

Time Reading Temp. m Reading In Out m 

End 09.S.Z /'~' /yocf °F 31 7::' -'H2O cf 83 °F :;3 °F ~. OU -'H2C 

Start o9~I•2 p. DOU cf ° F -3. 7011H20 cf ~y' °F F H 2O 

/D, - -3• 70 / • / ~~' ~~' ~. OO 

cf ° F "H 20 cf ° F "H 20 

lVet Test Meter V = 17.65 x /D.A/D _ a9.z8 

x 9.?Adscf 

m std + 460 (C f) 

Dry Gas Meter V 

m std 

a9 28 

3, o0 

+ 13.6 

+ 460 =9~y~ dscf 

CDG 

~ ~. 

r 

9 6ys _ ,;2 ✓ 

C-11 
E3 

d~r~~~~ 

DRY GAS METER CALIBRATION 

hteter Number: ? 

D a t e: 

~ 

Calibrator: 

Wet Test Meter V 

Calibration Factor (CDG) _ mstd 

 Dry Gas bieter V 

mstd 

Run No . / ~~'-10 pb; v?928 "Hg 

Control Module Vacuum S 0 "Hg 

IVET TEST METER (No. R7 ) DRY GAS METER 

Meter p Meter Temp. p 

Time Reading Temp. m Reading In Out m 

End /D0.3 cf ~ / °F _ ~/oIOIIH2O D.i -e.023 cf BS ° F °F y DO„H20 

Start 0-5"y D•DDD, cf ° F - 4,1401 H20 039906cf Sz° F °F"H2 0 

y~ ~ /a. Z/~ ~ y~ ° 

cf ° F "H20 cf F "H20 

IVet Test tfeter V 

mstd 

= 17.6S x /a4~1 

,:?9. 093 

;z / 

+ 13.6 x p, y'~'3 =~D- aed s c f 

+ 460 (C f) 

Dry Gas rieter V 

m std 

= 17.65 x/O.Z/7' — 

y, o0 

~9Z8 + 13.6 

+ 460 

✓ 

= 9~ydscf 

✓ 

C DG 9 89y 

C-12 

~/~ 
a 

11 R7-,t~ 

DRY GAS METER CALIBRATION 

Meter Number: ~~ ''? 

Date: ,L~ ///~~-S 

~ 

Calibrator: ,~~'~.e2pdx/,S"/~~ 7/~i~ 

Wet Test Meter V 

Calibration Factor (C ) = . mstd 

DG Dry Gas Meter V 

mstd 

Run No . :. /~~~jeJ~• pb ; va928 I,Hg 

Control riodule VacuumSO "Hg 

tVET TEST METER (No./) DRY GAS METER 

. Meter p Meter Temp. p 

Time Reading Tem . m Reading In Out m 

End Ilpl cf ~XO ° F — ,,,~/J "H20 OS3• 17o0cf 7Z-3 °F 723 ° F O. QZ "H20 

Start /03,,111 D. DDO —T cf :70 °F —/.A) "H06-,!5-1 ~~e2 cf -~7~1°F73°FO, OZ "H 0 2 

9-4 -//~ ~,038 ✓ / 

~. OS~

Zp • 0 2 

cf ° F "H 20 cf ~3 ~F "H 20 

~ 

{let Test Aieter V = 17.6S x ~ ~y~ 

'7~28 + 13.6 ,~ /,DO3 _ /p,Zdscf 

mstd ~v + 460 (C f) 

Dry Gas Ateter V 

mstd 

= 17.6S x a O38 — 

D. 0 2 

Z9z8 + 13.6 

,~,3 + 46 0 

/ 

~"'d 

dscf 

CDG _ /, oog • 

C-13 

~~ 
c-ia 

® ® 

~ 

~ 

~ ~ 

_~i~~i~i~~_~ • . 

~o~~ ~~~~ Q • _ ~INN • 

LEE ME 

OE 

ffiffiffiffiffiffifflE~~~~~~ 

O • • • ° • 

• I 

E 

• O 

OMEN~~ 

_~ 

~EMO®~ 

110IMMEN~~~~~ 

ONE ~ 

ME ® EMENNEEME 

`\ \ 

~ 

--I 

~ 

V 

C+7 

~ 

d 

~11 

~ F 

.p 

l U 

= J N 

u i ~ 

X] 

CY 

~ 

r 

~ 

~ 

~ 

.~ 

\~ 

~ 

~ 

o! 

\ 

~ 

~ ~ 
111HQU 

T, 

, 

, 

DIGITAL TEMPERATURE INDICATOR N0. ~~ '?(1 7) 

CALIBRATIO,1 DATA 

Date : 

Media Time Diercury Thermometer ( ° F) DTI ( ° F) 

Ice Bath ,~qfoo 3V 

Ambient Air 

Boiling Water 

Oven OBZ~ ZS2 Z.~3 

Oven 0829 30•z ,343 

Oven 

Oven ""),f 3W 378 

hleter Adjusted? Yes NoK 

~i - ~ . . 

C-i5 

C!o 
a'i kX411 ~ ~!!~' 

BAROAtETER CALIBRATION 

Barometer No. / 7— a 

Date: y /07Al 

Time: 

Barometric Pressure @ Addison Field @ 719 ft. = all? Sv 

- 0.719 

Absolute Pressure at Addison Field = 2 F. ?a / 

+ . 0.083 

Absolute Pressure @ A4ETC0 @ 636 ft. = I p. 9O 

Barometer Reading = g g 

Variation = 7L Q 17/ 

Barometer Adjusted? Yes v No 

~ 

gnature of Calibrator 

C-16 

~~~ 
.~: Scott Specialty Gases, Inc. 

1290 COMBERMERE STREET, TROY, MI 48083 (810) 589-2950 FAX:(810) 589-2134 

CERTIFICATE OF ANALYSIS: EPA PROTOCOL GAS 

Customer 

METCO ENVIRONMENTAL 

Attn : Jim Monfries 

16115 Dooley Road 

Dallas, TX 75244 

Assay Laboratory 

Scott Spccially Gases, Inc 

1290 Combcrniere 

Troy, MI 48083 

Purcltase Order : 3067 

Scott Project # : 572186 

ANALYTICAL INFORMATION 

This certification -was perfomled according to EPA Traceability Protocol For Assay and Certification of Gaseous 

Calibration Standards; Procedure GI; September, 1993. 

--I 

Cylinder Nut»ber : ALA4040839 

Cylinder Pressure + : 1900 psig 

ANALYZED CYLINDER 

Components 

Nitric Oxide 

Total Oxides of Nitrogen 

Certiticate Date : 10/26/94 

Previous Certificate Date : Notie 

Certified Concentration 

18.72 ppm 

19.10 ppm 

Expiration Date : 10/26/96 

Analytical Uncertainty* 

t1°/a NIST Directly Traceable 

Reference Value Only 

Balance Gas: Nitrogen 

+Do r.ot use witen cylinder presssure is below 150 psig. 

•Anal%tical aceuracy ts inclusn•e of usual I:no%%n error sources which at least include precision of die measurernent processes. 

REFERENCESTANDARD 

Type Expiration Date Cylinder Number Concentration 

NTR-%4 1684 4/1/96 ALM-024582 95.2 ppm Nitric Oxide in Nitrogen 

~ INSTRUAIENTATION 

InstrumentlA'IodeUSerial # Last Date Calibrated Analytical Principle 

NO : Horiba/OPE-235/483814 10/25/94 Chemiluminescence 

ANALYZER READINGS (Z=Zero Gas R=Reference Gas T=Test Gas r— Correlation Coefficient) 

Components First Triad Analysis Second Triad Analysis Calibration Curve 

Nitric Oxide Date: 10/19/94 Response Units: mv Dale: 10r26194 Response Units: mv Concentration=A•Bx•Cx?Di •Exd 

Z1=0.00 R1=95.20 T1=18.80 Z1=0.00 R1=95.20 T1=18.70 r-0.99999 NTRM 1684 

R2=95.20 Z2=0.00 T2=18.70 R2=95.20 Z2=0.00 T2=18.70 Conslanls: A=0.000000000 

Z3=0.00 T3=18.70 R3=95.20 Z3=0.00 T3=18.70 R3=95.20 B=1.000000000 C=0.000000000 

Avg. Conc. of Cust. Cyl. 18.73 ppm Avg. Conc. of Cust. Cyl: 18.70 ppm 0=0.000000000 E=0.000000000 

Special Notes 

Customer C _ 17 
:~.. Scott SpeciaIty Gases, Inc. 

1290 COMBERMERE STREET, TROY, MI 48083 (810) 589-2950 FAX:(810) 589-2134 

CERTIFICATE OF ANALYSIS: EPA PROTOCOL GAS 

Customer 

METCO ENVIRONMENTAL 

16115 DOOLGY ROAD 

DALLAS, TX 75244 

Assay Laboratory 

Scott Specialty Gascs, fnc 

1290 Cotnbermere 

l'roy, MI 48083 

Purchase Order: 2835 

Scott Project f# : 565362 

ANALYTICAL INFORMATION 

This certification lvas performed according to L•PA Traceability Protocol For Assay and Ccrtification of Gascous 

Calibration Standards; Procedure G1; Septembcr, 1993. 

Cylinder Number : BLl`4003576 

Cylinder Pressure + : 1900 psig 

ANALYZED CYLINDER 

Components 

iVitric Oxide 

Total Oxides of Nitrogen 

Certificate Date : 5/16/94 

Previous Certificate Date : None 

Certified Concentration 

48.05 ppm 

48.20 ppm 

Expiration Date : 5/16/96 

Analytical Uncertainty* 

f1% NIST Directly Traceable 

Reference Value Only 

Balance Gas: Nitrogen 

+Do not use when cylinder presssure is below 150 psig. 

•Anal.:ical accuracy is inclusive of usual knot%n error sources witich at least include precis ion of the tneasuretnent processes 

REFEREiVCE STANDARD 

Type Expiration Date Cylinder Number Concentration 

NTRM 1694 4/1/96 ALM-024622 95.3 ppm Nitric Oxide in Nitrogen 

INSTRUMENTATION 

~ Instrument/i\lodel/Serial # Last Date Calibrated Analytical Principle 

NO : 1-ioriba/OPE-235/483814 5/4/94 Chemiluminesence 

ANALYZER READINGS (Z=Zero Gas R=Reference Gas T=Test Gas r— Correlation Coefficient) 

Components First Triad Analysis Second Triad Analysis Calibration Curve 

Nitric Oxide Date: 5/9/94 Response Unils: mv Date: 5/16194 Response UnHs: mv Concentration=A•Bz•Cz .Dz •Exd 

Z1=0.00 R1=95.30 T1=48.00 Z1=0.00 R1=95.30 T1=48.10 r-0.99999 NTRM 1694 

R2=95.30 Z2=0.00 T2=48.00 R2=95.30 Z2=0.00 T2=48.10 Constanls: A=0.000000000 

Z3=0.00 T3=48.00 R3=95.30 Z3=0.00 T3=48.10 R3=95.30 8=1.000000000 C=0.000000000 

Avg. Conc. of Cust. Cyl. 48.00 ppm Avg. Conc. ot Cusl. Cyl: 48.10 ppm D=0.000000000 E=0.000D00D00 

Special Notes 

C-18 

Analyst Don Eichler, 1r 

CW 
.~..Scott Specialty Gases, Inc. 

1290 COMBERMERE STREET, TROY, MI 48083 (810) 589-2950 FAX:(810) 589-2134 

CERTIFICATE OF ANALYSIS: EPA PROTOCOL GAS 

Custonter Assay Laboratory 

METCO ENVIRONMENTAL Scott Spccialty Gases, Inc 

Attn : Jiln Monfrics 1290 Combennere 

16115 Dooley Road Troy, MI 48083 

Dallas, TX 75244 

Purchase Order : 3067 

Scott Project # : 572186 

ANALYTICAL INFORMATION 

-rhis certification was perfomtcd according to EPA Traceability Protocol For Assay and Certification of Gaseous 

Calibration Standards; Procedure G1; September, 1993. 

Cylinder Number : ALM038783 

Cylinder Pressure+: 1900 psig 

ANALYZED CYLINDER 

Contponents 

Nitric Oxide 

Total Oxides of Nitrogen 

Certificate Date : 10/26/94 

Previous Certificate Date : None 

Certiried Concentration 

85.40 ppm 

86.10 ppm 

Expiration Date : 10/26/96 

Analytical Uncertainty* 

f1% NIST Directly Traceable 

Reference Value Only 

fm 

Balance Gas: Nitrogen 

+Do not use when cylinder presssure is bclow 150 psig. 

•Anal } -tica l accuracy is inclusive of usual known error sources which at least include precision of the measurement processes. 

REFERENCESTANDARD 

Type Expiration Date Cylinder Number Concentration 

NTRM 1684 4/1/96 ALM-024582 95.2 ppm Nitric Oxide in Nitrogen 

INSTRUI•tENTATION 

Instrument/Aiodel/Serial # Last Date Calibrated Analytical Principle 

NO : Horiba/OPE-235/483814 10/25/94 Chemiluminescence 

ANALYZER READINGS (Z--Zero Gas R=Refercnce Gas T=Tcst Gas r— Correlation CocfGcient) 

Components First Triad Analysis Second Triad Analysis Calibration Curve 

Nitric Oxide Date: 10/19194 Response Unils: mv Date: 10/26194 Response Unils: mv Concentration=A•Bx•Cx?Dz •Ex4 

Z1=0.00 R1=95.20 T1=85.50 Z1=0.00 R1=95.20 T7=85.60 r=0.99999 NTRM 1684 

R2=95.20 Z2=0.00 T2=85.10 R2=95.20 72=0.00 T2=85.60 Conslants: A=O.OD0000000 

Z3=0.00 T3=85.00 R3=95.20 Z3=0.00 T3=85.60 R3=95.20 8=1.000000000 C=0.000000000 

Avg. Conc. o( Cust. Cyl. 85.20 ppm Avg. Conc. of Cust. Cyl: 85.60 ppm D=0.000000000 E=0.000000000 

Special Notes 

~ 

MISp P-1 

Customcr C_ 19 Analyst ~~ 
mecooECUROnfTEffAL 

--~ 

APPENDIX D 

23 

Field Testing Data 

95-134 D-1 
o ~ 

~ I ~ 

d V? 

Q ~ 

~ V V 

y I,-• ~S 

~ o 

m 

Ij~ 0 n~'1 

t c or 

c a 

~~o 

W 

n~~~~N ~~~~rt ~ ~ 

~ ~~, 

~ 0 0 ~ c~ 

(~'l N 

`9 

Cj 

n` N~ (D' 

~ . K K 

inlm° ~ 

`9 ~ 

_ 

f~ 

N 

f~ N ~ N~~ 4` ~~ 

0 

aE o 

E ~~ ~ cJ co O O 

V ~ . ~ ~g ~9 `~ ~ 

ZA ~n 111 

~ 

~ CZ) ~ ° ~ 

_ 

ao m N O 1l~ o ~, Z 1l-) -z, 

CRO ~ ~ c~ p-, p 

O qi 

60 ~C) ~o ~ o p a O 

u. M ~ ~ 

~ 

C-) 

_ `~ ~ `n ~ 

- 

p 

~ 

~ 

~ ci M ~ c~ N t" - r O o ~l 

m O v 1 p 'D N 

Mut)

~~ lr ~ 

Ln ~ 

.s 

, 

~ 

t ` d 

1 

~J- 

~ 

Ln 

a' U E ` U U 

!y 

~ 

O 

11 11 

~ 

_ _rn 

N 

- 

~ 

Q i/7 L 

C ~ J 

Y 

cu 

G~

co O J i 

E n 2 

CJ3 

"- ~ ¢ ¢a- USi~ 

F-F I 

J 

~ Z 

y ` Z 

LLJ 

O 

cr: 

ZW .. 

O 

S~ ~ W 

~ 

~ 

\~I 

 

s 

U 

co 

co ~ 

"s o 

az• =-° 

Lt. y 

d ~ 

t ~ 

~ ~ Y 

, co o .~ c

~eo 

~ 

~ 

~ y 

21 

~ ~ a~. n~. 'a. 

0 

Z 

O 

Cn 

z z Z ✓ ~ , ? a 

~ 

n GfJ 

~ 

\ 

d 

Z " cc: 

~ ~ W x Y ~ 

O ` I CVC 1 E 

~ (C I ~ O 

U 

~ 

d ~ 

\ a o .` 

~ ( 

N V U ~ rn ~ 

~ 

v J d CD Q 

o 

E cz cn 

cts 

m 1 ° > ~ 

.~ 

~ 

\ 

~ o 

•~ \ 

~ 

~ 

o ca ~ 

Y 

~ U ~ N Q 7 C" O (!~ 

o ~ ~s ~ E U 

, O , `° 2 

0- m tZ o o ¢ 

\--, \ 

o 1- c E E O _ 

`D N 

~ N n 

~ ~ N ° 

C 

•j 

E 

m D 

-4 i 

a- 

~ U 

U 

Ow 

~ 

~ 

V 

0 ^~ 

o ?~c 

1) 

E_ U ~ 

(Z. ~ y ~ --- C/) 

D-2 

/// / 
~ Impinger Box h'o. 

'Ja!er yJeighl G?in 

%M = 

Impinger 1 ~2 .5 

Impinger 2 

Impinger 3 3 

Impinger 4 /S 3 

V. = 

g SOZ= Impinger 5 

V. = 

Impinger 6 

Impinger 7 

/S'. 3 Total /ZZ. V 

w 

Pb = ?9. ~(~ ~ ,/%co2 

V. 74 315 %oZ 

V. = /ZZ. Zf %CO 

P. = c • /o ~, ~ '°// NZ _ gn ~„ 

r. 

Avg AP = , 0, ~6'I As = 4{00 ( 

7/ 

D. = O• ~~02 / Avg aP = ~~55 ~ T, _ tZO 

Cp= 

P, _ 

f) •8 ~ 9 

—a. 5D fHZO aq.(C& 'Hg 

T. = ~{S / ,°F °R 

T. = 7 Z41°F Q'3 °R 

7 M= D, 9Z S3~ d _ MWa ;? 9r~ 8 MW — 

Impin er 1 ~ 

i ` Impinger 2 

Impinger 3 

~ Impinger 4 

Impinger 5 . . 

~ Impinger 6 

) 

~ 

Impinger 7 

Moisture Conteni: 

Fnal Weight 

Initial Weight 

Increase 

Fnal Weight 

Initial Weight 

Increase 

Fnal Weight 

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Initial Weight 

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Initial Weight 

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Initial Weight 

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Impinger 1 Final Weight 70q impinger 1 

Initial Weight 

Increase Impinger 2 ~ 

Impinger 2 Fnal Weight Impinger 3 3. n 

Initial Weight f%Z 

Increase / 7, g Impinger 4 :2 

V. - 

Impinger 3 Fnal 1h'eight ~~' 1 3 g SOZ= Impinger 5 

Initial Vlreight V = 

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Increase 3. o Impinger 6 

Impinger 4 Fnal Weight $$ 2 Impinger 7 

Initial Weight IZ6-6-1-3 / 

Increase /(~ , 7 Total / Z S V w 

Impinger5.. Fnal Weight _•_ Pb = aF. ~~ Z %oCO2 

Initial VJeight V. = /0 02 = /7. ~o 

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Impinger 6 Fnal Weight Avg dP = 6• `~ ~ g 

Initial Weight 

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CP = nPc,!~f ~ 

Impinger 7 Fnal Weight P. = --0. 60 /HZO a 9.<~ z—~'Hg 

Initial Weight Tm = ~F °R 

Increase T. = ~{~Z °F °R 

, ✓ J~ ~~ Moisture Content: %M = 7. -7 1 Ma = o. 9 zz '7 MWa = ,z 1 . c3 Z MW 

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Vw,. = 0.0472 x Vw = 0.0472 x / 25 •`~ _ _ S ~y Z- ~sft3 

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Impinger t Final VJeigl ~ t Impinger 1 ~ 

Initial Weight S 2 

Increase $?,5 Impinger 2 /E. C. 

Impinger 2 Fnal Weight Impinger 3 12 

Initial Weight L?0. (o ; 

Increase /g lv ' Impinger 4 

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Initial Weight 41qL. 7_ V. = 

Increase r, ) Impinger 6 

Impinger 4 Final Weight g79,3 Impinger 7 

Initial Weight 05f. 3 

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Impinger 5.. Fnal Weight 

Initial 

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Initial Weight / D„ = D. 2( Z ~ 

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Impinger 7 Fnal Weight Ps 5 e-) 20 ~(~ 'Hg 

IniGal Weight T. = ~_°F s`~ / ~ °R 

Increase T: _ ~ 

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Increase 

Fnal Weight 

Initial Weight 

Increase 

tmpinger 4 

Impinger 5 . . 

Impinger 6 

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Impinger Box No. 0 - I 

Impinger 1 Fnal Weight ~o' ~ 

Waler Weiqht Gain 

Impinger 

Initial Weight Ce 7 q, (1 

Increase ~~' 6 ~ Impinger 2 

Impinger 2 Final Weight Impinger 3 ~•~ 

Initial Weight 7 3 7. a 

Increase Impinger 4 

Vw 

tmpinger 3 Fnal Weight 70!5, ~ g SOZ=- 0• 2 / Impinger 5 ~~ a 

Initial Weight (v 2S 5 Vw= 75.0 

Increase 30 , -3 Impinger 6 

Moisture Content: 

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Total w 

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'v'Ja!er Weio!d Gain 

Impinger 1 Fnal Weiglit 6~o'3 Impinger 1 

Initial Weight 67"~• y 

Increase --? J' Impinger 2 

Impinger2 Final Weight 7gF' Impinger3 

Initial Weight 737.5 

Increase .5X0 Impinger 4 ~' P 

Impinger 3 Final Weight -70-$' S g SOZ = Impinger 5 

Initial Weight V. = 

Increase /D• Impinger 6 

Impinger 4 Fnal Weight y9y 3 Impinger 7 

Initial Weight 

Increase d• 9 Total -77, V w 

Impinger 5 . . Fnal Weight _ ~63' 6 Pb = ~ ~1v ~ ~ %COZ = 

Initial Weight g50-5- V. = <{ 3. 2 3 ,/ j %02 = 

Increase // / V„ = `/'/. S~/ %CO 

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= o c7 / 

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= 

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CP = st/U 

Impinger7 Fnal Weight P, = — 'HZO .Z9.(o ~~ 'Hg 

Initial Weight T. = 8? O F °R 

Increase T, = 47i-) °F ~ q.°R 

Moisture Content : %M = 

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0.0472 x Vw = 0.0472 x • s ~~ = y~ / sft3 

% Moisture = _ Vw~„ x 100 = s• ~s8~

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Vm, , + Vwfl„ / 3 + 3-6~~ 

V. = 5123.8 xjD• ~ 9 -3 0 Y l) 7/~ ~ ,~/~~ ~,rt, 

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ll-1? 
Impinger Box No. 1 7 - / 

Waler Weiqhl Gain 

Impinger 1 Fnal Weight ~_ Impinger 

Initial Weight 

Incnease Impinger 2 

Impinger 2 Final VJeight ~Q~_ Z Irnpinger 3 

Initial Weight 

Increase Impinger 4 

V„ 

Impinger 3 Fnal Weight g SOz =- 0, I / Impinger 5 

Initial Weight V. 

Increase ~ ( ~ Impinger 6 

Impinger4 Fnal Weight 60 1 'S_ Impinger7 

Initial Weight 

Increase 

5~b• 7 

Total 

Impinger 5.. Fnal Weight Pb=?~7 Z- ~ %CO2 = Z Z ✓ 

Initial Weight 9630 V. = 2•/ %OZ = J 7. "2- 

Increase ~L c~ rJ V, = i~ ~ %CO 

/ 

f = ~ r 

P. = ~ %N2 = ~70, U' 

Impinger 6 Fnal Weight Avg DP = n. 90 1~6 A, = 4/)q/ ✓ 

Initial Weight D. 

/ 

_ --- 

Increase Avg AP = /D T ~ = ?Z 

C

P — O / 

Impinger 7 Fnal Weight P, = —o • 5'c: ~'HZO a°) ('~gf 'Hg 

IniGal Weight T. = 73 ~°F 

,°F 

.5,3 3 °R 

Increase T= = ~Sz 'Z ~ °R 

g.oz ~ b.qi9E ~ ~~ ✓ 

Moisture Content: %M = S-.0:9) M, _ MWa = 0^?9.OW0 MW = ~2 

Pm 

Vm Srd = 17.65 Vm Pb + 13.6 = 17.65 x y2 ~ 2q 7Z + 13.6 ~ !S7 ~ scfm Tm + 460 -;>3 + 460 = ~ 

~ (r•8 2-5 

Vw9a3 = 0.0472 x Vw = 0.0472 x ~~'~ = 3~~7 f sfl' 

% Moisture = Vw~~ x 100 =' 6Z5~~ x 100 

q. Cz 

% 

Vm, + Vw9u 

V, = 5123.8 x ~~'~ `~ I Z x •~ - 3o ~ / ~~,,,, nrF ~~ : 8573 z 7 ~ 

J o~~.~Og X 2(~, /S r S1,S, 239 f 

SCFM: 

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APPENDIX E 

~ 

Analytical Data 

95-134 E-1 

~9 
n 1IETC0 Environraental 

Particulate Analysis Suaunary 

Job Number ,Jr— ~ 3 

-, Job Name ~~2~ kGd 

Location ~ii1~,9~j1] 

Date Malysis Completed ;Z-1O-9S 

Unit Tested 

Run No. ~ 

Particulate on Filter (mg) 

' Particulate in Front Wash (mg 

rO. D ~ 

RF (mg) 

Particulate in Impinger 01 (mg) 

wr (mg) 

Y - 1 ✓ ~ 

~w 

/ 

Analyst 

• Less Acetone Residue 

E - 2 Q'l~ 
m 

DIETCO Environmental 

Particulate Analysis EPA Nlethod S 

Stack Filters f HF 

Job Number ~j~ ~~ Location 

- Job Name r-; ~. ~, ~,.i'~ :~ Unit Tested 

Desiccator Time In /0 G0 ~ s ~030 ;Z 6 

Desiccator Time Out 102-5- (, 13 ys ;7 ,7 

Run No. Filter No. 

Filter & Particulate 

+ Tare Weight (g) 

Tare Weight (g) ✓ 

Filter & Particulate (g) 

Filter & Particulate Average (g) z9 ,5- 3 ~ 

Initial Filter Weight (g) , i 

Total Particulate (mg) 

Run No. o~ Filter No. YF491651 

Filter $ Particulate 

+ Tare Weight (g) 

Tare Weight (g) ✓ 

Filter & Particulate (g) ,S (1~ ~ a 

Filter & Particulate Average (g) d S3Z ~ 

Initial Filter IVeight (g) D, SQ 74)! 

Total Particulate (mg) --~ 

Run No. ~_ Filter No.ffQwily 

Filter $ Particulate 

+ Tare Weight (g) 

Tare Weight (g) / 

Filter & Particulate (g) 62, S g 

Filter & Particulate Average (g) Q, 

Initial Filter Weight (g) 

Total Particulate (mg) 

)AL 

Analyst 

E - 3 R'J 
to 

METCO Environmental 

Particulate Analysis EPA Diethod S 

Stack Filters 

Job Number Location 

Job Name ~,.- l/~ Zj Unit Tested 

.l 

Desiccator Time In CoO s 32 6 

Desiccator Time Out 12 30 

Run No. Filter No. 

Filter & Particulate 

+ Tare Weight (g) 

Tare Weight (g) ~ 

Filter & Particulate (g) , s/ ~$ 

Filter & Particulate Average (g) 4, 

Initial Filter Weight (g) 

Total Particulate (mg) ~ 

Run No. Filter No. 

Filter & Particulate 

+ Tare Weight (g) 

Tare Weight (g) 

Filter f, Particulate (g) 

Filter & Particulate Average (g) 

Initial Filter lVeight (g) 

Total Particulate (mg) 

Run No. Filter No. 

Filter & Particulate 

+ Tare Weight (g) 

Tare Weight (g) 

Filter $ Particulate (g) 

Filter & Particulate Average (g) 

Initial Filter lVeight (g) 

Total Particulate (mg) 

Analyst 

C-4 

yg— 
IN 

n METCO Environmental 

Particulate Analysis EPA D1ethod S 

DI - H 2 0 Front iVash 

Job Number 

.~ 

Job Name ~, .E ~ti-~ ~ ? .~ r~ ., 

Location _..`.: : • , , 

~ ;~ 

Unit Tested 

Desiccator Time In . ~63d ' 7-~ 

Des iccator Time Out ! ✓ 14'= -Y l/ 

Run No. / Volume (ml) a a 

Final iVeight (g) 1;; j j~/V, ~( 77 30 ~ 

Initial Weight (g) 165- :76 1 415Ala/ 

Particulate 1Veight (g) ~ ~3/ 5 , ~~~ 

Particulate Average (mg) 

Less Ammonium Sulfate (mg) _-- 

Total Particulate (mg) 

Run No. Volume (ml) 

Final 1Yeight (g) 

Initial {t'eight (g) 1,~ . 

Particulate R'eight (g) J~, 12 xdG; 

Particulate Average (mg) 

Less Ammonium Sulfate (mg) — 

Total Particulate (mg) 

Run No. -

~_3 Volume (ml) a (~ 

Final j9eight (g) ~,.~ ~ ?~~ 

. ~ : , ~..•. ; , , 

~a~ 5~~~ ✓ 

Initial Weight (g) 

Particulate Weight (g) OS e~ 

Particulate Average (mg) 

Less Ammonium Sulfate (mg) 

Total Particulate (mg)l , 7 — 

Blank ; Volume (ml) dSa 

Final Weight (g) 1,2 

Initial Weight (g) 9,3 

Difference (g) 

Average (mg) 

Less Ammonium Sulfate (mg) 

Total Particulate (mg) 

mg/1 /• ~ ~ 

Analyst 

E-S ~ 
~ METCO Environmental 

Particulate Analysis EPA Method S 

Ac,-4tFront Wash 

Job Number q~ /~L~ Location ~'~(.'--~~~., ~.►%-~ ~; G% . 

Job Name -~ ~Z.~.~~ Unit Tested /^ r:,~~l%r.~: ~~, 

Desiccator Time In 7 6 

Desiccator Time Out 

Run No. ~_ Volume (ml) 

Final Weight (g) 3 f~7~ % /~ ~9~ ✓ 

Initial SVeight (g) /`~.3. . /~ ' ~JQ~ , ~ 

Particulate Wei ht () D. 0055- 

Particulate Average (mg) 

Less Acetone Blank (mg) 

Total Particulate (mg) , 

Run No. ~_ Volume (ml) -2-0 ,C? 

Final Wei ht ( ) 

Initial Weight (g) la8 

Particulate Weight (g) ~~ 1~~= ~: ~ j, 67 ,1)~~ 

Particulate Average (mg) 

Less Acetone Blank (mg) 

Total Particulate (mg) 

Run No.J~ Volume (ml) I$3 

Final Weight (g) ~?~~ ~ r~.~;~ /~ ;7 ✓ 

Initial Weight (g) a, ~ ~~ -72 

Particulate Weight (g) 

Particulate Average (mg) 

Less Acetone Blank (mg) - 

Tota1 Part'iculate (mg) s ' 

Acetone Blank Volume (ml) 300 

Final Weight (g) 

Initial Weight (g) ZZ ~ 

Difference (g) 0 Q,~? 3 

Average (mg) a, ' 

* mg/ 1 

* Note: If greater than 7.9 mg/1, use 7.9 mg/1. 

A/4- 

E-6 Analyst ~ 
METCO Environmental 

Particulate Analysis EPA Method S 

Back Half Analysis 

57y; , /

Job Number - ~3~ U ~ ~ Location 

Job Name 17, Unit Tested ` 

Desiccator Time In P16 

Desiccator Time Out /y/0 ~ 2 30 ~ io 

Run No. ~_ Volume (ml) 36-1 , ZSS 

Final Weight (g) ~ ~ , Q ,j 

Initial Weight (g) ~~, Q D3 /(~.Q,203 

Particulate Weight (g) 

Particulate Average (mg) 3 9, D ~ 

Less Ammonium Sulfate (mg) _ 

Total Particulate (mg) 3 D 

Run No .

-4_ Vo lume (ml ) 

Final Weight (g) j32 ,5-6 .331t ✓ 

Initial Weight (g) Z~ra~ 

Particulate Wei ht g (g) 

, Q 

/~ , ~,k~~~.•~'~ -Particulate Average 

Less Ammonium Sulfate 

(mg) 

(mg) 

;2 ~ 

— 

Total Particulate (mg) 

Run No. ~ Volume (m1) 

Final Weight (g) /S/ j ~ 

Initial Weight (g) 

Particulate Weight (g) 

Particulate Average (mg) 

Less Ammonium Sulfate (mg) — 

Total Particulate (mg) ,3 

Run No. Volume (ml) 

Final Weight (g) 

In itial Weight (g) 

Particulate Weight (g) 

Particulate Average (mg) 

Less Ammonium Sulfate (mg) 

Total Particulate (mg) 

''. C-7 

Analyst 9~K 
METCO,-, 

L_J E(1VIR0f1(TIEfTTRI 

~ 

FA 
uS 

10 

20 

n 

METCO ENVIRONMENTAL 

- ------------------------------- 

: Sample Name: Rl FILTER (25ML) Date

_ 07/17/1995 16:00:00 ; 

; Data File : C:\DX\DATA\ANIONS\95-134\7-170011.D02 ; 

; Method : C:\DX\METHOD\FLUO.MET ~ 

; ACI Address: 1 System: 1 Inject#: 2 Detector:CDM-2 ; 

; Analyst . Column: AS4A-SC,4mm, STARTED 10-14-94 ; 

----------------------------------------------------------------------------- 

Calibration Volume Dilution F'oints Rate Start Stop Area Reject 

-------------------------------------------------------------------- 

External 1 1 4200 5H.: 0.00 14.00 500 

Component Report: C:omponents Found 

Ret Couponent Area Heiglzt Concentration 

Time Name ppm 

------------------------------------------------------------- 

2.15 fluoride 45807458 10181323 1.526 

------------------------------------ Totals 45807458 10181323 1.526 

Fiie: 7-170011.D02 Sampie: R1 FILfiFR (25ML) 

i 

4 6 8 10 12 14 

Minutes 

C-9 

K 
METCO ENVIRONMENTAL 

----------- 

; Sample Name: R1 FILTER (25ML) DUP Date: 07/17/1995 16:46:19 ; 

; Data File : C:\DX\DATA\ANIONS\95-134\7-170001.D05 ; 

; Method : C:\DX\METHOD\FLUO.MET ; 

; ACI Address: 1 System: 1 Inject#: 5 Detector:CDM-2 ; 

; Analyst Column: AS4A-SC,4mm, STARTED 10-14-94 ; 

----------------------------------------------------------------------------- 

----------------------------------------------------------------------------- 

Calibration Volume Dilut.ion Points Rate Start Stop Area Reject 

-------------------------------------------------------------------- 

External 1 1 4200 5Hz 0.00 14.00 500 

Component Report: Components Found 

Ret Component Area Heiglit Concentration 

Time Name ppm 

------------------------------------------------------------- 

2.15 fluoride 45714635 10235629 1.523 

------------------------------------ 

Totals 45714635 10235629 1.523 

PA File: 7-170001.D05 Sample: Ri FILTER (25N1L) DUP 

71 

20 

us 10 

N 

0 2 4 6 8 10 12 14 

Minutes 

E-10 
METCO ENVIRONMENTAL 

----------------------------------------------------------------------------- 

----------------------------------------------------------------------------- 

; Sample Name: R1 DIFW (222ML) Date: 07/17/1995 17:41:35 ; 

; Data File : C:\DX\DATA\ANIONS\95-134\7 =170001.D09 ; 

; Method : C:\DX\METHOD\FLUO.MET ; 

; ACI Addre--s: 1 System: 1 Inject#: 9 Detector:CDM-2 ; 

; Analyst Column: AS4A-SC,4mm, STARTED 10-14-94 ; 

----------------------------------------------------------------------------- 

----------------------------------------------------------------------------- 

Calibration Volume - Dilution Points Rate Start Stop Area Reject 

-------------------------------------------------------------------- 

External 1 1 4200 5Hz 0.00 14.00 500 

Component Report: Components Found 

Ret Component Area Height Concentration 

Time Name ppm 

------------------------------------------------------------- 

2.15 fluoride 76692821 15756763 2.555 

------------------------------------ 

Totals 76692821 15756763 2.555 

~ File: 7-170001.D09 Sample: Rl C}IFUII (222N1L) 

16 

14 

12 

10 

8 

uS g 

4 

2 

0 

~ 

-~ 

0 2 4 6 8 10 12 14 

Minutes 

E-11 

e~ 

n 
METCO ENVIRONMENTAL 

; Sample Name: R1I1 DIBH (361ML) 5X Date: 07/18/1995 14:41:37 ; 

; Data File : C:\DX\DATA\ANIONS\95-134\7-180001.D15 ; 

; Method : C:\DX\METHOD\FLUO.MET ; 

; ACI Address: 1 System: 1 Inject#: 15 Detector:CDM-2 ; 

; Analyst . Column: AS4A-SC,4mm, STARTED 10-14-94 ; 

----------------------------------------------------------------------------- 

Calibration Volume Dilution Foints Rate Start Stop Area Reject 

-------------------------------------------------------------------- 

EYternal 1 1 4200 5Hz 0.00 14.00 500 

Component Report: Components Found 

Ret Component Area Height Concentration 

Time Name ppm 

------------------------------------------------------------- 

2.17 fluoride 208839017 40452395 6.957 

------------------------------------ 

Totals 208839017 40452395 6.957 

0 File: 7-180601.D15 Sample: R1li DIBH (361ML) 5X 

90 

80 

70 

60 

50 fluoride 

I 

uS 40 

30 ~ 

f 

20 + 

10 ~ 

t 

OE 

i 

0 2 4 6 8 10 12 14 

Minutes 

C-12 

p 
16 

14 

12 

10 

8 

6 

4 

2 

0 

-2 

uS 

nuonae 

I 

0 2 4 6 8 10 12 14 

METCO FNVIRONMENTAL 

----------------------------------------------------------------------------- 

; Sample Name: R1I2,3 (255ML) Date: 07/18/1995 13:20:58 ; 

; Data File : C:\DX\DATA\ANIONS\95-134\7-180001.D10 ; 

; Method : C:\DX\METHOD\FLUO.MET ; 

; ACI Address: 1 System: 1 Inject#: 10 Detector:CDM-2 ; 

; Analyst . Column: AS4A-SC,4mm, STARTED 10-14-94 ; 

~ ----------------------------------------------------------------------------- 

Calibration Volume Dilution Foints Rate Start Stop Area Reject. 

-------------------------------------------------------------------- 

External 1 1 4200 5Hz 0.00 14.00 500 

Component Report: Components Found 

Ret Component Area Height Concentration 

Time Name ppm 

------------------------------------------------------------- 

2.17 fluoride 70335155 14926708 2.343 

Totals 70335155 14926708 2.343 

m File: 7-180001.D18 Sample: R112,3 (255ML) 

Minutes 

~ 

G-13 

ql 
~ 

7 

METCO ENVIRONMENTAL 

Data Reprocessed On 07/17/1995 16:25:30 

-------------------------------- 

Sample Name: R2 FILTER (25ML) Date: 07/17/1995 16:15:24 ' 

; Data File : C:\DX\DATA\ANIONS\95-134\7-170001.D03 ; 

Method : C:\DX\METHOD\FLUO.MET 

ACI Address: 1 System: 1 Inject#: 3 Detect•or:CUM-2 ; 

Analyst . Column: AS4A-SC.4mm, STARTED 10-14-94 ; 

Calibration Volume Dilution Points Rate Start Stop Area Reject 

: External 1 1 

-------------------------------------------------------------------- 

4200 5Hz 0.00 14.00 500 

Component Report: Components Found 

Ret Component Area Height Concentration 

~.~ Time.Name ppm 

------------------------------------------------------------- 

2.15 fluoride 54135912 11658143 1.803 

~ ------------------------------------ 

Totals 5413591-9 11658143 1.803 

Ei~~. ~- i~~}~~ 1.~~}3 .~~ uifij> ic: ~~ €~~T ~~ (~~~v L) 

^a ~ 

us 10 

0 

0 2 4 6 8 10 12 14 

Minutes 

E-14 
~ 

.; 

METCO ENVIRONMENTAL 

; Sample Name: R2 FILTER (25ML)DUP Date: 07/17/1995 17:01:38 ; 

;.Data File : C:\DX\DATA\ANIONS\95-134\7-170001.D06 ; 

; Method : C:\DX\METHOD\FLUO.MET ; 

; ACI Address: 1 System: 1 Inject#: 6 I)etector:CDM-2 ; 

Analyst : Column: AS4A-SC,4mm, STARTED 10-14-94 ~ 

t".alibration Volume Dilution Points Rate Start Stop Area Reject 

External 1 

-------------------------------------------------------------------- 

1 4200 5Hz 0.00 14.00 500 

Component Report: Components Found 

Ret Component Area Height Concentration 

Time Name 

i..~ ------------------------- ---------------------------=----- ~~~ 

2.15 fluoride 53453218 11511294 

------------------------------------ 

1.781 

Totals 53453218 11511294 1.781 

A File: 7-170001.1306 Sample: R2 FILTER (25ML)dUP 

20 

~ 

uS 10 

0 

0 2 4 6 8 10 12 14 

Minutes 

G-15 

0 
40 1 

i 

30 ; fluoride 

20 

uS 

10 

0 

~ 

,., 

- J 

~.~ 

I 

METCO ENVIRONMENTAL 

----------------------------------------------------------------------------- 

; Sample Name: R2 DIFW (233ML) Date: 07/17/1995 17:56:59 ; 

; Data File : C:\DX\DATA\ANIONS\95-134\7-170001.D10 ; 

: :'Sethod : C:\DX\METHOD\FLUO.MET 

; ACI Address: 1 System: 1 Inject#: 10 Detector:CDM-2 ; 

; Analyst. . Column: AS4A-SC,4mm, STARTED 10-14-94 ; 

- ----------------------------------------------------------------------------- ----------------------------------------------------------------------------- 

Calibration Volume Dilution Foints Rate Start Stop Area Reject. 

-------------------------------------------------------------------- 

External 1 1 4200 5Hz 0.00 14.00 500 

Component Report: Components Found 

Ret Component Area I-Height Concentration 

Time Name ppm 

------------------------------------------------------------- 

2.15 fluoride 138393191 26608543 4.610 

------------------------------------ 

Totals 138393191 26608543 4.610 

9 File: 7-170001.d10 Samp{e: R2 DIFW (233ML) 

0 2 4 6 8 10 12 14 

Minutes 

E-16 q 
METCO E'rlV I ROr]MENTAL 

; Samplz Name: R2 DIFW (2X)SPK 5 PPM Date: 07/18/1995 16:36:58 ; 

; Data File : C:\DX\DATA\ANIUNS\95-134\7-180001.D23 ; 

; Method : C : \DX\METHC?D\FLUC) . MET ; 

; ACI Address: 1 System: 1 Inject#: 23 Detector:CDM-2 ; 

; Analyst . t"olumn: AS4A-SC',4mm, STARTED 10-14-94 ; 

--------------------------------------------------------------------------=-- ----------------------------------------------------------------------------- 

c"alibration Volume Dilutioii Foints 

-------------------------------------------------------------------- 

kate Start Stop Area Re ~iect 

External 1 1 2991 5Hz 0.00 15.57 500 

Component Report: Components Found 

Ret Component Area Height Concentration 

Time Name 

------------------------------------------------------------- 

ppm 

2.17 fluoride 218192518 44018947 

------------------------------------ 

7.268 

Totals 218192518 44018947 7.268 

Fil~ : 7- ~1;:i~ciC~1.C~2:~ S~~ mp1e: t;:~ C~ IFV"! (2X);~PK:, PlDN:i 

P. 

-14i a 

.1 20 

'I {?0 

~~ (l -" I 

i 

i 

40 ; 

Gi 

flLloflr1e 

( 1 2 .} C'i _l -1 0 - 1 2 - 1 4 

P•'li{luLr == 

c-i7 

~~ 

ri 
METCO ENVIRONMENTAL 

; Sample Name: R2 DIFW (2X)SPK 5 PPM DUP Date: 07/18/1995 16:53:10 ; 

; Data File : C:\DX\DATA\ANI ONS\95-134\7-180001.D24 ; 

; Method : C:\DX\METHOD\FLUO.MET ; 

; ACI Address: 1 System: 1 Inject#: 24 Detector:CDM-2 ; 

; Analyst . Column: AS4A-SC,4nun, STARTED 10-14-94 ; 

----------------------------------------------------------------------------- 

----------------------------------------------------------------------------- 

Calibration Volume 

------------------------------------------------------=------------- 

Diltition Points Rate Start Stop Area Reject 

External 1 1 4200 5Hz 0.00 14.00 500 

Component Report: Components Found 

Ret Component Area Height C:oncentration 

Time Name 

------------------------------------------------------------- 

ppm 

2.17 fluoride 219787830 43305568 

------------------------------------ 

7.321 

"Totals 219787830 43305568 7.321 

File: 7-1800U1.1314 Sample: R2 DIPtrV (M5PK 5 PPM DUN 

70 

60 

50 

40 

uS 30 

20 

10 

0 

-10 

0 2 4 6 8 10 12 14 

nninutes 

ii 

E-18 
METCO ENVIRONMENTAL 

----------------------------------------------------------------------------- 

; Sample Name: CCV 10 PPM F. STD Date: 07/18/1995 11:18:10 ; 

; Data File : C:\DX\DATA\ANIONS\95-134\7-180001.D02 ; 

; Method : C:\DX\METHOD\FLUO.MET ; 

; ACI Address: 1 System: 1 Injec:t#: 2 Detector:CDM-2 ; 

; Analyst . Column: AS4A-SC,4mm, STARTED 10-14-94 ; 

----------------------------------------------------------------------------- 

c:alibration Volume Dilution Points Rate Start Stop Area Reject. 

-------------------------------------------------------------------- 

E'xternal 1 1 4200 5Hz 0.00 14.00 500 

Component Report: Components Found 

Ret Component Area Height Concentration 

Time Name ppm 

------------------------------------------------------------- 

2.18 fluoride 305275841 58437700 10.169 

------------------------------------ 

Totals 305275841 58437700 10.169 

-0 File: 7-180001.D02 Sample: CCV 10 PPM F STD 

80 

70 

60 

50 

40 

uS 30 

20 

10 

0 

-10 

0 2 4 6 8 10 12 14 

Minutes 

n 

E-19 
METCO ENVIRONMENTAL 

; Sample Name: R2I1 DIBH (345ML) 5X 

----------------------------------- 

Date_ 07/18/1995 15:12:16 ; 

; Data File : C:\DX\DATA\ANIONS\95-134\7-180001.D17 ; 

; Method : C:\DX\METHOD\FLUO.MET 

; ACI Address: 1 System: 1 Inject#: 17 Detector:CDM-2 ; 

; Analyst _ Column: AS4A-SC.4mm, STARTED 10-14-94 ; 

Calibration Volume Dilution points Rate Start Stop Area R,eject 

-------------------------------------------------------------------- 

E:cternal 1 1 4200 5Hz 0.00 14.00 500 

Component Report: Components Found 

Ret Component Area Height Concentration 

Time Name ppm 

------------------------------------------------------------- 

2.17 fluoride 197969472 38695533 6.594 

------------------------------------ 

Totals 197969472 38695533 6.594 

File: 7-180001.D17 Sample: R211 DIBH (345ML) 5X 

40 

30 

20 

uS 

10 

0 

0 2 4 6 8 10 12 14 

~ 1 

Minutes 

E-20 

I l 
METCO ENVIRONMENTAL 

---------- 

; Sample Name: R2I1 DIBH (345ML) 5X DUP Date: 07/18/1995 15:27:36 ; 

; Data File : C:\DX\DATA\ANIONS\95-134\7-180001.D18 ; 

; Method : C:\DX\METHOD\FLUO.MET ; 

; ACI Address: 1 System: 1 Inject#: 18 Detector:CDM-2 ; 

a; Analyst . Column: AS4A-SC,4mm, STARTED 10-14-94 

--------------------------------------------------- 

Calibration Volume Dilution Points Rate Start Stop Area Reject 

-------------------------------------------------------------------- 

External 1 1 4200 5Hz 0.00 14.00 500 

Component Report: Components Found 

Ret Component Area Height Concentration 

Time Name - ppm 

- ------------------------------------------------------------- 

2.17 fluoride 195512773 38612399 6.513 

------------------------------------ 

i Totals 195512773 38612399 6.513 

mt. File: 7-1$0001.Di8 Sample: R21i DIBH (345fv1L) 5X DUP 

~ 

40 

30 

20 

uS 

10 

0 

0 2 4 6 8 10 12 14 

M inutes 

E-21 ~'J 
METCO E'NVIRONMENTAL 

----------------------------------------------------------------------------- 

----------------------------------------------------------------------------- 

; Sample Name: R2I2,3 (271ML) Date: 07/18/1995 13:36:17 ; 

; Data File : C:\DX\DATA\ANIONS\95-134\7-180001.D11 ; 

; Method : C:\DX'\METHOD\FLUO.MET ; 

; ACI Address: 1 System: 1 Iiijec:t#: 11 Det.ector:CDM-2 ; 

Analyst . Column: AS4A-SC,4mm, STARTED 10-14-94 ; 

----------------------------------------------------------------------------- 

i:alibration Volume - Dilution Foints 

-------------------------------------------------------------------- 

Rate Start Stop Area Reject. 

External 1 1 4200 5H.: 0.00 14.00 500 

Component Report: Components Found 

Ret Component Area Height Concentration 

Time Name 

------------------------------------------------------------- 

ppm 

2.17 fluoride 69641120 1488180_~' 

------------------------------------ 

2.320 

~ Totals 69641120 14881802 2.320 

19 rile: 7-180001.D11 Sample: R212,3 (271ML) 

40 

30 

20 

uS 

10 

0 

0 2 4 6 8 10 12 14 

Minutes 

E-22 ~ 1 
METCO ENVIRONMENTAL 

; Sample Name: R3 FILTER (25ML) Date: 07/17/1995 16 30:43 ; 

; Data File : C:\DX\DATA\ANIONS\95-134\7-170001.D04 ; 

; Method : C:\DX\METHOD\FLUO.MET ; 

; ACI Address: 1 System: 1 Inject#: 4 Detector:CDM-2 ; 

; Analyst . Column: AS4A-SC,4mm, STARTED 10-14-94 ; 

----------------------------------------------------------------------------- 

c:alibration Volume Dilution Points Rate Start Stop Area Re,ject 

-------------------------------------------------------------------- 

Esternal 1 i 4129 5Hz 0.00 13.76 500 

Component Report: Components Found 

Ret Componer.t Area Height Concentration 

Time Name ppm 

------------------------------------------------------------- 

2.15 fluoride 46435664 9808065 1.547 

------------------------------------ 

Totals 46435664 9808065 1.547 

File: 7-170001.d04 Sample: R3 FILTER (25ML) 

20 

uS 

10 

0 

0 / 2 4 6 8 10 12 

Minutes 

1~ 

E-23 
METCO ENVIRONMENTAL 

-------------------------------- 

; Sample Name: R3 DIFW (265ML) Date: 07/18/1995 11:48:50 ; 

; Data File : C:\DX\DATA\ANIONS\95-134\7-180001.D04 

; Method 

; ACI Address: 1 System: 1 Inject#: 4 

: C:\DX\METHOD\FLLIO.MET 

Detector:CDM-2 

; Analyst . Column: AS4A-SC,4mm, STARTED 10-14-94 ; 

Calibration Volume Dilution Points Rate Start Stop Area Reject. 

-------------------------------------------------------------------- 

EYternal 1 1 4200 5Hz 0.00 14.00 500 

Component Report: Components Found 

Ret Component Area Height Concentration 

Time Name ppm 

------------------------------------------------------------- 

2.15 fluoride 137105384 25215950 4.567 

------------------------------------ 

! Totals 137105384 25215950 4.567 

File: 7-180001.D04 Sample: R3 DIFW (265ML) 

40 

30 

20 

uS 

10 

0 

0 2 4 6 8 10 12 14 

Minufes 

1-1 

E-24 
40 I 

i 

j fluoride 

301 1 

20 

uS 

10 

0 

METCO ENVIRONMENTAL 

----------- 

; Sample Name: R3 DIFta (265ML)DUP Date: 07/18/1995 12:04:14 ; 

; Data File : C:\DX\DATA\ANIONS\95-134\7-180001.D05 ; 

; Method : C:\DX\METHOD\FLt10.MET ; 

; ACI Address: 1 System: l Inject#: 5 Detector:CDM-2 ; 

; Analyst . Column: AS4A-SC,4mm, STARTED 10-14-94 ; 

----------------------------------------------------------------------------- 

----------------------------------------------------------------------------- 

Calik,ration Volume Dilution Points 

-------------------------------------------------------------------- 

Rate Start Stop Area Reject 

E:cternal 1 1 4200 5Hz 0.00 14.00 500 

Component Report: Components Found 

Ret Component Area Height Concentration 

Time Name 

------------------------------------------------------------- 

ppm 

2.17 fluoride 137020354 28290570 

------------------------------------ 

4.564 

Totals 137020354 28290570 4.564 

Fi(e: 7-180001.DO5 Sample: R3 DIFW (265iNL)DUP 

0 2 4 6 8 10 12 14 

Minutes 

E-25 fP 3 
METCO ENVIRONMENTAL 

-------------- 

; Sample Name: R3I1 DIBH (274ML) 5X Date: 07/18/1995 15:42:56 ; 

; Data File : C:\DX\DATA\ANIONS\95-134\7-180001.D19 ; 

; ACI Address: 1 System: 1 Inject#: 19 

; Method : C:\DX\METHOD\FLUO.MET 

Detector:CDM-2 ; 

; Analyst . Column: AS4A-SC,4nun, STARTED 10-14-94 ; 

!:alibration Volume Dilution Foints Rate Start Stop Area Reject 

-------------------------------------------------------------------- 

External 1 1 4200 5Hz 0.00 14.00 500 

Component Report: Components Found 

Ret Component Area Height Concentration 

Time Name ppm 

------------------------------------------------------------- 

2.18 fluoride 265669319 53124065 8.850 

------------------------------------ 

Totals 265669319 53124065 8.850 

n F11e: 7-1 80001.D 1 9 Sample: R31 i DIBH (274ML) 5X 

80 

70 

60 

50 

40 

fluoride 

I 

M0 

20 

1n i 

I ~ I 

0 

-1A 1 

0 2 4 6 $ 10 12 14 

Minutes 

-, 

E-26 

lb 
METCO EN`JIRONMENTAL 

----------------------------------------------------------------------------- 

----------------------------------------------------------------------------- 

; Sample Name: R3I1 DIBH (274ML) 5X DUP Date: 07!18!1995 15:58:07 ; 

; Data File : C:\DX\DATA\ANIONS\95-134\7-180001.D20 ; 

; Method : C:\DX\METHOD\FLUO.MET ; 

; ACI Address: 1 System: 1 Inject#: 20 Detector:CDM-2 ; 

; Analyst . Column: AS4A-SC,4mm, STARTED 10-14-94 ; 

----------------------------------------------------------------------------- 

Calibration Volume Dilution F'oints Rate Start Stop Area Reject. 

-------------------------------------------------------------------- 

EYternal 1 1 4120 5Hz 0.00 13.73 500 

Component Report: Components Found 

Ret Component Area Heig)Zt Concentration 

Time Name ppm 

------------------------------------------------------------- 

2.13 fluoride 266136227 52666831 8.865 

------------------------------------ 

Totals 266136227 52666831 8.865 

. .-._... ~_,.... .:__... 

Fiie: 7-18Q~~1.~~~ Sample: R311 DIBH (274(v1L) 5X DUP 

80 

70 

60 

50 

40 

uS 30 

20 

10 

0 

-10 

0 2 4 6 8 10 12 

tviinutes 

G 27 _ / p J~ 

77 
METCO ENVIRONMENTAL 

----------------------------------------------------------------------------- 

----------------------------------------------------------------------------- 

; Sample Name: R3I2,3 (215ML) Date: 07/18/1995 13:51:37 ; 

; Data File : C:\.DX\DATA\ANIONS\95-134\7-180041.D12 ; 

; Method : C:\DX\METHOD\FLUO.MET ; 

; ACI Address: 1 System: 1 Inject#: 12 Detector:CDM-2 ; 

; Analyst Column: AS4A-SC,4mm, STARTED 10-14-94 ; 

----------------------------------------------------------------------------- 

Calibration Volume 

- -------------------------------------------------------------------- 

Dilution Foints Rate Start Stop Area Reject 

External 1 1 4200 5Hz 0.00 14.00 500 

Component Report: Components Found 

Ret Component Area Heigllt Concentration 

Time Name 

------------------------------------------------------------- 

ppm 

2.17 fluoride 83536272 1796280' 2.783 

i ------------------------------------ 

Totals 83536272 17962802 2.783 

a File: 7-180801.D12 Sample: a312,3 (215ML) 

r-1) 

~ 

30 

uS 20 

ffel 

U 

0 2 4 6 8 10 12 14 

Minutes 

C-28 I t /„ 
METCO ENVIRONMENTAL 

- ---------------- 

; Sample Name: DI BLANK Date: 07/18/1995 14:26:19 ; 

; Data File : C:\DX\DATA\ANIONS\95-134\7-180001.D14 ; 

; Method : C:\DX\METHOD\FLUO.MET ; 

; ACI Address: 1 System: 1 Inject#: 14 Detector:CDM-2 ; 

; AnalYst . Column: AS4A-SC,4mm, STARTED 10-14-94 ; 

----------------------------------------------------------------------------- 

----------------------------------------------------------------------------- 

Calibration Volume Dilution Points Rate Start Stop Area Reject• 

E.:ternal 1 

-------------------------------------------------------------------- 

1 4200 5Hz CJ . 00 14.00 500 

Component Report: Components Found 

Ret Component Area Height Concentration 

Time Name 

------------------------------------------------------------- 

ppm 

2.15 fluoride 516949 75216 

------------------------------------ 

0.017 

Totals 516949 75216 0.017 

a 

t=iie: 7-i ~uuc~ i.Di4 5ampie: Di BLANK 

r0.4 

0.3 

0,2 

uS 

0.1 

0.0 

-0.1 

0 2 4 6 8 10 12 14 

Minutes 

G-29 fbI 
METCO ENVIRONMENTAL 

Sample Name: FILTER BLANK Date: 07/17/1995 17:26:15 

; Data File : C:\DX\DATA\ANIONS\95-134\7-170001.D08 ; 

; Method 

; ACI Address: 1 System: 1 Inject#: 8 

: C:\DX\METHOD\\FLU0.MET 

Detector:CDM-2 ; 

; Analyst . Column: AS4A-SC,4mm, t;TARTED 10-14-94 ; 

Calibration Volume Dilutioil Foints Rate Start Stop Area Reject 

External 1 

-------------------------------------------------------------------- 

1 4200 5HZ 0.00 14.00 500 

Component Report: Components Found 

Ret Component Area Height Coiicentration 

Time Name 

-------------------------------------------------------------- 

ppm 

2.15 fluoride 10190970 2040563 

------------------------------------ 

0.339 

Totals 10190970 2040563 0.339 

0 

rile: 7-170001.D08 Sample: i=iL IEK BL,yNk 

4.0 

3.0 

2.0 

us 

1.0 

0.0 

0 2 4 6 8 10 12 14 

Minutes 

E-30 
* 29.92 "Hg, 68 ° F (760 mm Hg, 20 ° C) 

C 1= 

bfL lx(MLB- MLBB ) x N x 32 

MLA 

CT= C I#2 + C 1#3 

S02Eh1ISSI0N DATA 

rl 

Job Number 

Job Name 

Location ~~t~p~~, 

Unit Tested' ~- 

n 

Run Number 

N- normality of Ba(C104)2 

ML I- ml in impinger #2 

ML I- ml in impinger #3 3~ 3130 

MLA - ml in aliquot #2 

~ 

MLA- ml in al iquot #3 

ML B- ml of Ba(C104) 2to titrate #2 ?S 

3. 7-s 3..3sAverage ML B- ml of Ba(C104) 2 3.3.3 

MLB- ml o f Ba (C104 ) 2to titrate #3 15 

l , /,5 , 

Average MLB- ml of Ba(C104 ) 2 ~/j ~` j l. , 

MLBB- ml of Ba(C104 ) 2to titrate blank 

Tm- average gas meter temp., ° F 

~ - volume of dry gas sampled 

m @ meter conditions ft. 3 

Pb- barometric pressure, "Hg Abs. 

_ stack gas volume dry @ 

Qs standard conditions, *SCFM 

C I- S0 2in impinger #2, mgs l~ , / 3, J? 1,3CJ C~ 

C 1- S0 2in impinger #3, mgs 

CT- total S0 2in impingers, mgs 152~ 

ppm S0 2 

CS0 2- emission rate of S0 2 , lbs/day 

CSO 2 - emission rate of S0 2 , lbs/hr 

C s- emission rate of S, lbs/day 

0.7513 x C Tx(Tm+ 460) 

ppm S0 2 = 

vm pb 

CS02= ppm S02x Qs x 239.2 x 10 -6 

C S02 

E-31 C s 2 ~~ / 
ML Ix (M L B - ML BB ) x N x 40 

M LA 

C I = 

9 

dmErco 

SULFUR TRIOXIDE EMISSION DATA 

Job Number Location -~z~~~-nrJ. ~ 

Job Name Unit Tested 

Run Number 

Date 

Time 

N - normality of Ba(C104 ) 2 •O/CO ~ 

ML I- ml in impinger ;2_0 3 00 

MLA- ml in aliquot i p 

MLB- ml of Ba(C104 ) 2to titrate d ss- /a ~ 

Average AiLB- ml of Ba(C104) 2to titrate ~ 

0~3 , Q. ~ O 

MLBB- ml of Ba(C104 ) 2 to titrate blank ~

0-5- > 

T 

m 

 - average gas meter temp., ° F 

v-volume of dry gas samplsd 

m @ meter conditions, ft. 

~ 

pb- barometric pressure, "Hg Abs. 

_ stack gas volume dry @ 

Qs standard conditions *SCFM 

C I- S0 3in impinger, mgs 

ppm S03 ; 

cS0 3- emission rate of S0 31 lbs/day 

CS- emission rate of S, lbs/day ~ 

* 29.92 "Hg, 68 ° F (760 mm Hg, 20 ° C) 0.6021 x C I x(Tm + 460) 

ppm S03= 

um Pb 

c50 3 = ppm S0 3 x Qs x 299.1 x 10-6 

C S03 

E-32 CS 2.S 
-, m,,4 ~

7 

APPENDIX F 

a Reference Method Monitor Data 

95-134 F-1 

/~~ 
meco 

~ (~Ef1VIR0(1(TIEf'iTAI 

Absorber Stack (EPN - K) 

Oxides of Nitrogen 

Concentration 

Run Measured Adjusted 

Number jPP~ m* 

1 16.5 16.0 

2 17.4 17.0 

3 17.7 17.0 

"Calculated according to equation 6C-1. 

m. 

F-2 

///~ 
0 

a~ a~ 

o 0 0 a0> 

Z 

c 0 ~ 

c~ 

QU>~k° ~ ~ 

v00 

x 

O 

z 

a~ 

rn 

cz N 't c0 

Q ~p O O O 

.—. 

Y 

Y 

v 

T ~n N Z c~n ~ c C~ C~ 

(L E ~ 

o 

"E~ N p 

U U) z 

~ c o 

~ 

_O 

x ,C O U 

z 

 ~~~+ 

~ 

~~~ 

= C~ pJ 

( ~ 

O 

C'7 

O 

C'7 

O 

~ = x ~ vo

iU O p 

~ 

a 

(1) 

(~ T 

 ,^ .y ~+I V 

Q a V V V 

~ 

U 

N 

o cU ~ M o T 

~~~~ 

L •~ 

~ ~ ~ 

~ p 

~ Y 

U U 

~ 

~ •~ ~ ~ co (Y) co 

z E~~ 6 

06 

d6• 

• i 

~ 

~I 

C ~ 

rr E 

~ 

T N co 

z 

r--3 ~ I 

115 
q

~ 

BORAL 4BRICK 

HENDERSON TEXAS 

~ ABSORBER STACK 

i Page : 1 

NOX 

PPM 

06/29/95 07:18 O.00 

~ 06/29/95 07:19 O.00 

06/29/95 07:20 0.0C 

06/29/95 07:21 0.0C 

06/29/95 07:22 O.00 Z~Eoi(lr 5'G 9/a/7/ZALC 

06/29/95 07:23 O.00 

06/29/95 07:24 85.5C 

06/29/95 07:25 86.8C 

06/29/95 07:26 86.8C 

06/29/95 07:27 48.00 

t 

06/29/95 07:28 0.2C 

! 06/29/95 07:29 2.9C 

06/29/95 07:30 50.2C 

06/29/95 07:31 49.6C 418. a.5;4,1+— 4111ar r~C~~3S26 

06/29/95 07:32 49.6C 

06/29/95 07:33 25.1C 

06/29/95 07:34 0.2C 

06/29/95 07:35 O.iC 

~ 06/29/95 07:36 0.0C 

06/29/95 07:37 8.3C 

;j 06/29/95 07:38 18.9C 

! ~ 06/29/95 07:39 18.7C 

06/29/95 07:40 18.6C 

~ 06/29/95 07:41 9.9C 

06/29/95 07:42 0.1C 

; A1IERAGES : 2 -2.4 

F-4 
|/ 

~ 

6/ ~ 9/9b 

... _-.... ..... ..... ' ..... _ ... ..... ' ... .... --__-_'- -_- -- '---_-- ---- - '- 

/ ^ Time PP ~ 

_-_'-_-- -........ ---__-_-____-__-____'___ 

~

. 

~ 7 47 

--_-__-__-----__.--- 

30,0000C 

' 07:4O 30.0000C 

07:49 30,0000C 

07:50 29.9000C 

07:5l 29'9000C 

07:52 29'9000C 

, 

07153 29'9000C 

'{ 7: 24 29.9000C 

 07,55 29'9000C 

07:56 29'9000 ~ 

W:57 30.0000C 

 ' 07;50 30'0000C 

08:00 29.9000C 

0G:01 29.9000C 

08:52 29'9000C 

08:03 30.0000C 

08:04 29'9000C 

.1 O8z05 29.9000C 

08:06 29.9000C 

0G:O7 29.9000C 

! 0n08 29.6000C 

' 08:09 29'9000C 

06:10 29'6000C 

8: i1 29.7000C 

08:12 29.7000C 

' 

o8;13 

08:14 

08:15 

08116 

29.7:00C 

29'7000C 

29'6000C 

29.7000C 

~ AX : 30'0000 

!IN r 29.6000 

AVG ; 29'8667 ' 

SCANS. 30 

' 

c``--77,' ' 

P-S 

- - 

//5"', 
1-1?1v9s (-/" 

- _ ° " _ - ZE~o~I/Z 8//~5 Cf/EGE~ 

i% O 

,: ~ =: _._ 

7 

45. 

U w: 

F-6 
SERAL BUCK 

HEMM 

WN 

F R~ 

0619R5 1455 

?42055 A56 Oloov, zloty 6ellAllizote 

0"535 1057 

ooZW55 1053 H. 50 

Oc!'23i35 14: 57 47.,- C 

002IR5 

SAW5 

1513 

002 (ID RIC 

AM= 1004 23C 

06=5 

552W95 

1005 

•106 

0 A r-, 0. 5L 

2 0. 9 

F-10 
' 

/ 

~ u`Iiiar` "vprage kepon! 

_ 

Aux Interval Date ' 

~~ 

------------'-- 

N DX ^~~~~ 

~

p~~, 

- 

 ' 

vFY 

. ~ 

i5:14 

17'1000 

17'10`)0 

i5:l5 17'C000 

15:16 17'l000 

15:17 17'2000 

+~ 15; i8 17,2000 

~ 15:19 

15,20 

17,3000 

1s:21 

17,5000 

17'5000 

15,22 ' 17 7000 

10:23 17'7000 

~

~ 

1b;24 

15:25 

17'5000 

17'50 ~ 0 

15:26 17,5000 

15:27 17'4000 

15:28 i7'3 ~ 00 

1 

- 

o000 

15:32 16.7000 

~ M33 i6.G000 

15:34 17.0000 

~° 

15:3 5 

15:36 

17 3000 ' 

17'4000 

15:37 17'300-) 

15:38 17'3000 

. 

. 

15:39 

15;40 

17'5000 

17'0000 

15:41 

15:42 

16'6000 

16.4000 

i8.40O0 

~ VG : 

16'4000 

17'2867 

30 

P-ll 

. 

/ 

~

| 

\

~ 
F-I 

LA 

~ ~ux~ iiary ~ `/er ~~ ge ~ ep ~ rt 

07 Site CORAL Aux | Daie 

---------------------------- - -------------- - --- 

--- --------'----'-- 

--- ------------------- -------- '--- 

,~r~, 

PPM 

15;57 

15:58 

... .... ... ______________ 

17'8000 

17'4000 

15:59 17,3000 

16:00 17'3000 

16;01 17.300; 

16;02 13.3000 

16103 18.4000 

10;04 17'4000 

1o:05 17,2000 

16:06 17.4000 

10:97 17'600(` 

ib:08 !7.8Oo0 

16:09 17'700 ~ 

16:10 i7.5000 

16:11 17,5000 

16:12 17,6000 

16r13 17'4000 

16:14 17.1000 

16:13 17'0000 

16:16 17.1C00 

16:17 17.400C 

16:18 17'4000 

16:19 17.4000 

16;20 17'3000 

16:21 

16:22 

17'5000 

17.5000 

16:23 17.7000 

i6:24 17'7000 

16:25 i7.5000 

16:26 17.6000 

16:27 17'800 ~ 

MAX : 18.4000 

MIN : L7'0000 

AVG : 17'5129 

SZANS: 31. 

Vl2 
7 19 4 7 

9, -u 4 10 

014 

/vz 

ul a 

j -.5 i 

6f 9, 

;-sisc 0: ~-4 043-5 

6 

77 

In 

F-13 
._l 95 1.'~ 4 

bORAL BRICK 

HENDERSON TEXAS 

i ABSORRER STACK 

~ Fage : 1 

NOX 

FRM 

06/30/95 07:05 

06/30/95 07:06 

06/30/95 07:07 

06/30/95 07:08 

06/30/95 07:09 

06/30/95 07:10 

06/30/95 07:11 

! 06/30/95 07:12 

06/30/95 07:13 

06/30/95 07:14 

06/30/95 07:15 

06/30/95 07:16 

06/30/95 07:17 

=: 06/30/95 07:18 

06/30/95 07:19 

06/30/95 07:20 

06/30/95 07:21 

06/30/95 07:22 

06/30/95 07:23 

06/30/95 07:24 

~ 06/30/95 07:25 

J 06/30/95 07:26 

06/130/95 07:27 

~ 06/30/95 07:28 

06/30/95 07:29 

06/30/95 07::,0 

06/30/95 07:31 

AUERAGES : 

-O.iC 

-0. iC S6 `1le 171-- /Vz,C 

-o.1c Z 

0.1C 

17.8C 

O.1C 

O.iC 

37.5C 

85.2C 

86.4C 86, /~~ ,vOk AGmo3~7~j 

86.4C 

45.4C 

O.3c 

14.00 

~ ~

sj°P••, .t/oX BUn GY~ 3-S~6 

49. 7C 

27.2C 

0.2C 

0.1C 

11.9c 

i8.8C 

18.6c ~~ ~Z~oM~/oX ~9L~oyo~S39 

18.6C 

12.7C 

0.2C 

O.1C 

O.iC 

21.5 

F-14 /~/ 
'. 

-- 

~ 

~ 

._-_--_-__---__-_---_ --- --- ' - -- _._.-_'-_- ----'-- -- - ' - -' -- -- - 

07i34 

07 ;35 

~ 07:36 

3t'20{'0C 

ZL'L00KC 

35'2000C 

07:37 ~ 5'200 ~ C 

~ 7; ~ 8 3}'2000C 

O7 ~ J9 

07:40 

35'2000C 

35.Z000C 

' 07:42 ' 35'2000C 

07:43 35'2000C 

07:44 

07r45 

35'2000C 

30'2000C 

07 ~ 4 ,16 

07;47 

~ 5'2 ~ 0oC 

35'2000C 

~ | 07:48 35'2000C 

07:49 35.1000C 

07;50 351100011, 

07:53 35. 1000 ~ - 

07:52 S5'10o0C 

07:53 35.0000C 

07:54 35.0000C 

07:55 

i 07:56 

34'0000 ~ 

34'9000C 

07:57 34'9000C 

07:58 

07 

08:00 

08:01 

Q8n02 

34'8000C 

4.800 ~-i~ 

34'8000C 

34'D0S0C 

54'7000C 

08:03 

~ AX ~ 

. .1IN : 

AVG : 

34'W0OC 

35'2000 

34.700u 

35'0600 

 SCANS ~ 30 

F-lS 

_ _ ~ 
ri 

I L V 

C, -6j I i i 5, x/, 8,~s ~ 

6 :,: 

,. _... 

1 

j 

Ale'. eloS" •K 

7 j 

1 13 

F-16 1a.~ 
' 

------ --- — ..... .... .... .... ------ ----------------'-----------------'------------ 

--- -- 

~ U:Z6 

' --'------------- 

~ 8'0 ~ 00 

0 ~ :27 1 ~ '90 ~ 0 

~ 8:28 i7'9000 

Wn29 17' ~ 000 

0O:30 17'4000 

0a:31 18'3000 

08:12 18'4000 

00;33 17'7000 

00034 17'2000 

08:35 17'4000 

0B:36 17'5000 

08:37 17'7000 

OB:38 17'8000 

08:39 17'8000 

08:40 17'7000 

08:41 17'8000 

08:42 i7.6000 

08:43 17.3000 

08:44 16'9000 

08:45 17'0000 

0B:46 17.2000 

08c47 17,7000 

| 08 ~ 48 13.0000 

08:49 18'0000 

08:50 17'7000 

~~ 08:51 18'0 ~00 

~D~~7 1~ '3000 

08;55 l7'7000 

08:54 17,3000 

08:45 17,4000 

MAX : 18.4000 

MIN : 

AV6 

16.9000 

17.6633 

SCANS: 30 

F-17 
! ' 

---------------..... 

---'-- ------------- 

...... .... ..... - ..... -.... ------------------'-'-'---'---------'--------'-------' 

,~~u~~&'-~'~~ 

Time 

-------------------- 

09:06 18-4000 ^ ' 09:07 17.6000 

39:08 17'7000 ~ 

09:09 17,7000 

09:10 18-1000 

09z11 18.1000 

09;12 17.9000 

09:13 18. 0000 

09:14 17.8000 

09:15 17.6000 

09:16 17.4000 

 09:17 17.1000 

09;18 17.1000 

09:19 17.3000 

09;20 17'6000 

09z21 17.8000 

09:22 17,6000 

09:23 17.9000 

| S9:24 17 ^ 9000 

09:25 17.7000 

09:26 l7.8000 

/ 09:27 | 17 7000 . 

09:28 17'6000 

09:29 17.7000 

o9:30 17'900V 

09:31 17.8000 

09:32 17'700 ~ 

09:33 17.70O0 

09:34 17'800 ~ 

09:35 17.3000 

~ AX : ~ 8.4000 

MIN : l7.1000 

4VG : 17.7100 

SCANS: 30 

F-l8 
D R H L I L 1. 

PAroe 

i 9 : 4 L 0 4C 

J`v % -,0,-' 07: 45 z'C 

ol~illl 

zewco 

6 5 t~ ? : a6 

69:47 6. OIC 

0 i 4 S 4 7 C 

0 141 48. 4C 

"'1

6" 7:0 15 5 C,9: 4 7 C 

Oi 5 1 

7 

"0 i c, 5 6i: 94 

6 5 0 i 3 5. 5 O.-IC 

7- 

6 ' -~T•0 1: i cl 

19 1aa 
7 MEMO 

[—JE(1VIR0fl(11i=f1TAl 

APPENDIX G 

a Visible Emissions Data 

95-134 G-1 

r~~ 
~ 

VISIBLE EMISSIONS OBSERVATION FORM 

Source Name ~~K~ $"0(- Observation Date 6 ~9 9S Start Time /60' z6 Stop Time 

Address 1319 Phone 903 -6s7-3sa.s Source ID Number 

Pnxess Equipment s'r,~Operating Mode /6o t~ 'c 

City wsa~tate T.y. Zip Code 75652 Control Equipment Operating Mode -'?c 5'ccDescribe Emission Point 57,~f 

a~ac~oom000 . 

mv I- 0000asn 

mc~r-~einmooc-w 

m®c~aoo©c~ov 

mac-~oomovr-~o 

mor-~oeovor~a~ 

mar~enor~vvo 

ovac-~emvoao 

o®c~000©avo 

avy , /), S G-2 

Height Above Ground Level/DD ' 

Distance Direetion 

from ObserverZGlO ' from Observer 

Descrbe Emissions 

Emission ColorGdNiTE 

Plume Type: ,_ Continuous _ Fugitive —Intermittent 

Water Droplets Present: No _ Yes 

If Water Droplet Plume: _ Attached _ Detached , 

Point in the Plume at which Opacity was determined Z 

Descnbe the Background dF'0"r'`f`' -s~ 

Badcground Color6eV1 Sky Conditions OvE~c~ST 

Wind SpeedS-i0 Wind Direction 117 — 

Ambient Temperature $.s 

Average Opacity for Highest Period 

Number of Readings Above % Were 

Range of Opaaty Readings: O Minimum ~ Ma)dmum 

Observers Name (Print) 

Observers Signature Date 

Organization 

Cettified By Date 

r

S 

Verified By Date 

Source Layout Sketch Draw North Agow 

~ X`L Emission Point 

1 'L 

Sun + Wind ' 

Plume and Stack C= _4, Observers Position 

Sun Location Line 

Comments: oAWC , rY 40C44-6 LIAl I T 

CHnA!« 6-M&--e Zo.s~c. ~vleWzo. 

I have received a copy of these opacity observations 

Signature 

Tille _ Date 

m 
~ 

~ i VISIBLE EMISSIONS OBSERVATION FORM 

Source Name Observation Date 6 30 9S Start TimepS-3 ~ Stop Time 0938 

Address 1009 ~«d~'E" ~. Phone2 Sa3 6.573,~zS-- Source ID Number 67PX1 /C-~ 

- ' Process Equipment h',5tr&&',R5z1 ST'.~! Operating Mode ~7~1'/t°, 

! Ci ta t e TX• Zip Code Control Equipment Ae1 Sceaa Operating Mode /80 

of 

~ os®esms®as a©sso®©moo ©o ova®msoo ©momo©ovom o©mmmomvom ©mramm©vmom 

mmmmmnmmmm o©soam©oo~ MMMMMMMMM~ 

oamoamvvov mmmomo©or-~v 

mosoomvvov ®osoomoovv ®©omoo©vvo 

ammmmmmmmm ®msosmoovo m©ovom©ooa 

movaomvvvo 

mmmmmmmmmm m©moom©o~c~ 

MMMMMMMMMM 

®ODMO®v000 o©aoo®©©vv 

mr.~ooramoc~or~ 

mMI MMMOMMOM 

LEMMMMOMMMM 

Desabe Emission Point -172'1~ 

Height Above Ground Level /04 " 

Distance Direction ~ 

from ObserverZ~ ~ from Observer 

Desaibe Emissions FA~/ 

Emission Color t*lS~iTL5 

Plume Type: _ Continuous _ Fugdive !E' Intermittent 

Water Droplets Present:kNo _ Yes 

If VJater Droplet Plume: _ Attached _ Detached , 

Point in the Plume at which Opaaty was detennined 2 

Descrbe the Background 

Background Color.BLUE Sky Conditions ,-e.6We 

Wind Speed .S Wind Direction 

Ambient Temperature 8D 

Average Opacity for Highest Period 

Number of Readings Above % Were 

Range of Opacily Readings: D Minimum Z(5--M-a)dmum 

Observers Name (Print) 

Observers Signature ~~ Date -3d 9S 

Organizationw 

Certbed By /'7//lecif Date 3 p~ 

Verified By Date 

Source Layout Sketch Draw North Arrow 

X 'z" Emission Point IZ 

Sun + Wind ' 

Plume and Stack C= _,&~ Observers Position 

— —)!~r 

Sun Location Line 

Comments: y~.*C/7'3' dGCae'S r~1~r'E't/ c/'yi 7— 

-- C/~r/tiES o - ✓f~ (a~•x~1 ~osEC. Dv-e~Tia~/~ 

I have received a oopy of these opaaty observations 

Signature 

Title Date 

G-3 ~~~ 
(-! 

VISIBLE EMISSIONS OBSERVATION FORM 

Souroe Name Observation Date 6 36 S Start Time Stop Time . 14?0o 

Address~-3~1" /~C~a~-~~ Phone 9a36S735-aS Souroe ID Number 

Process Equipment/?,3So.09ET-,7,-9Opera6ng Mode /60 ~7a 

~ City-f~ 1~0-~tate 7-4 ZZp Code 75-6 S2 Control Equipment ~s~.Sc.E'v~.~2Operating Mode 180 SEC, 

to 

ms®smms®s® a©ocav®©moo ©mmvv®maioo ©ovvv©oo vv o©vvvo®vvo 

©OVOGi©00©0 

mmmmmmmumn oQOriMm©ocao 

oovovovmvo 00000mvovv m©v000ravmv mia000mvvvv ®vovomvvov 

®M000M©000 

mmmmmommmm ®ovvomvvov mmme'om©vvm ®omvomvvvv moEaovovvvs momvom©moo 

MMMMMMMMMM ®mmom®omor-~ o©mvv®©000 ®r•ivvo©cimaio 

mmmvvovvoo ®vomv®©mvo 

mmmvonaooa ®r-amommvvvv m©ocavomvon ~ omovomcs000 mmmmmommom 

Describe Emission Point 'yC'4t' 

Height Above Ground Level /O,Q " 

Distance Direction ~ 

from Observer Z~ ~ from Observer 

Desaibe Emissions 

Emission Color ~✓f~i7~ 

Plume Type: _ Continuous _ Fugiiive 'r Intermittent 

Water Droplets Present: -_Y No _ Yes 

If Water Droplet Plume: _ Attached _ Detached 

Point in the Plume at which Opacity was deteanined z ~ 

Describe the Background <S~y 

Background Color SLUC Sky Conditions -

_ 

 Sa97- 

Wind Speed _~ Wind Direction N 

Ambient Temperature 85- 

Average Opacity for Highest Period 

Number of Readings Above °k Were 

Range of Opacity Readings: O Minimum A7 —Ma)dmum 

Observers Name (Print) 

Observers Signature Date 

Organization 

Certified By Tit/,-CC Date 3/ 9S' 

Verified By Date 

Source Layout Sketch Draw North Arrow 

X - -Emission Point 

i 1 

Sun * Wind ~ 

Plume and Stack C= ,,&, Observers Position 

Sun Location Line 

Comments: 

Od" r/U SeC. Dd~E'9T1o~ / 

I have received a copy of these opacity observations 

Signature 

Title Date 

4 v g , o ~f C, - 4 1~~ 
7-1 meco. 

APPENDIX H 

Plant Operational Data 

95-134 H-1 

l''yl 
BoRAL BRICKS 

~ VA; t 

Henderson Division 

P.O. Box 2110 • Henderson, Texas 75653-2110 

Telephone 903/657-3505 FAX 903/657-7139 

~ ~ -~ 

I ~,~ ~,~; ~~ I ~~~~ ,~j ~ - , 

in J U L 12 1995 

B v_ 

July 3, 1995 

Mr. Rob Patterson 

METCO Environmental 

P. O. Box 598 

Addison, TX 75001 

Dear Mr. Patterson: 

On Thursday and Friday June 29th and 30th, 1995, your firm performed Source 

Emission Testing on the Adsorber Stack (EPN-K) at the Henderson Plant to 

demonstrate compliance with Texas Natural Resource Conservation Commission 

Permit No. 21012 requirements. 

The following operating parameters were recorded during this Source Emission Testing 

and are submitted to METCO for reporting operating data on your report. 

Kiln #1 and #2 Throughput: 499.1 Tons/Day Of Fired Ware 

Kiln #1 and #2 Fuel Input: 1,266 MCF/Day Natural Gas 

Kiln #1 Stack Temperature: 485° F 

Kiln #2 Stack Temperature: 550° F 

Boral Bricks and I thank you for your cooperation in this matter, and if you have any 

questions or need more information, please contact me at (903) 657-3505. 

Thank You! 

Sincerely, 

J. senhour, Jr. 

Manufacturing Manager 

Boral Bricks, Inc. 

~ 

11-2 J39--- 
Moco- ErmRonn'EffAc 

n 

APPENDIX I 

A 

TACB Permit 

95-134 

1 ~~? 
TEXAS AIIZ C®I®ITR®L B ®A.RD 

A PERMIT IS HEREBY ISSUED TO 

BORAL BRICKS, INC. - HENDERSON BRICK DIVISION 

AUTHORIZING THE CONSTRUCTION AND OPERATION OF 

Henderson Brick - Plant No. 1 

TO BE LOCATED AT 

Henderson, Rusk County, Texas 

Lat. 32 0 10'51" Long. 94 0 48 1'12" 

and which is to be aonstructed and operated in aocordance with and subjed to the Texas Clean Air Act (Texas Health and Safety Code, Chapter 

382) and all Rules, Regulations and Orders of the Texas Air Control Board. Said permit is subject to any additional or amended Rules, Regulations and Orders of the Board adopted pursuant to the Act and to all of the following conditions: 

l.'Ihis pemvt may not be transferred, assigned or cronveyed by the holder, and applies only to the location spedfied herein. 

2 This permit is automatically void upon the oavnence of any of the following: 

a. Failure to begin oonstruction within eighteen months of the date of issuance. 

b. Disoontinuanee ofc+on.struc6on prior to completion for a period of eighteen oonsecutive months or more. 

c f'ailure to oomplete construction within a reasonable time. 

3.The fadlities oovered by this penmit shall be constructed and operated as specified in the appUcation for the permit. 

4.All representations regarding oonstrudion plan.s and operation procedures c+ontained in the perrnit application, unless spedhmlly changed in 

the appUmtion for this pennit beoome oonditions upon which this permit is issued. It shaU be unlawfui for any person to vary from such 

representation if the change will cause a change in the method of control of emissions, the character of the emissions or will result in an 

increase in the disdharge of the various emissions, unless he first makes appUmtion to the Execvtive IUirector to amend this permit in that 

regerd and such amendment is approved. 

5.The Board shall be notified prior to the start-up of the fadlities authorized by this permit in such a manner that a representative of the Texas 

Air Control Board may be present at the time of start-up. 

6.The Board shall be notified prior to the start of any required sampling and/or monitoring of the fadli ties authorized by this permit in such a 

manner that a representative of the Texas Air Control Board maybe present during the required sampling and/or monitoring. Upon request 

by the Fxecutive Director, the holder of this permit shall make sufficlent stack sampling analyses, or other tests, to prove satisfactory 

equipment performanoe. All sampling and testing procedures shall be approved by the Fxecutive Director and coordinated with the regional 

representatives of the Texis Air Control Board. 

IT - 

7.This pemvt does not absolve the holder from the responsibility for the consequenoes of nonoomplianoe Kith all Rules, Regulations and 

Orders of the Texas Air Contiol Board or with the requirements of the Texas Clean Air Act 

8 The faalities covered by this permit shall not be operated unless aU assodated air poUution abatement equipment is maintained in good 

worldng order and operating property during normal faalli ty operations. 

9. Emissions from this faoility must not cause or aontribute to a mndition of'air poUution' as defined in Section 382003(3) of the Texas Clean Air 

Ad or violate Section 382085 of the Texas Clean Air Act lf the Fxecutive Director determines that such a oondition or violation occvrs, the 

holder shaU implement additional abatement measures as necessary to control or prevent the oondition or violation. 1 ~ 10.ProvLions: See attachments labeled "General Provisions 21012, 

~ 1-6, and "Special Provisions 21012," 1-9. 

Acrocptance of the pentiit oonstitutes an aclmowledgement and agreement that the holder will comply with aU Rules, Rcgulations and Ordcrs of 

i

1 the Board issued in conformity with the Acd and the c+onditions preoedent to the granting of this pemut. Failure to comply with all oonditions and 

( spedal provisions of this permit will subject the holder to the enforcement provLsions of the Texas Clean Air Act 

This pemvt expires 5 years from date of issuance unless renewed as dcfined in Section 382055 of the Texas Clean Air Act 

~ I S/7/9 3 

PER~fTT h0. 2 10 12 DATE 

~ 

FJCECITiVEDIRECTOR A5AIRCOVTROI.BOARD 

~ 

I-2 ~~ 
~i 

GENERAL PROVISIONS 

Permit No. 21012 

1. Equivalency of Methods - It shall be the responsibility 

of the holder of this permit to demonstrate or- otherwise 

justify the equivalency of emission control methods, 

sampling or other emission testing methods and monitoring 

methods proposed as alternatives.tomethods indicated in 

the provisions of this permit. Alternative methods shall 

be applied for in writing and shall be reviewed and 

approved by the Executive Director prior to their use in 

^ fulfilling any requirements of this permit. 

2. Sampling Requirements - If sampling of stacks or process 

vents is required, *the holder of this permit must contact 

the : Source and Mobile Monitoring Division of the Texas 

Air Control Board (TACB) prior to sampling to obtain the 

proper data forms and procedures. The holder of this ` 

permit is also .responsible for providing sampling 

facilities and conducting the sampling operations at his 

own expense. 

3. Appeal - This permit may be appealed pursuant to Rule 

103.81 of the Procedural Rules of - the TACB and Section 

382.032 of the Texas Clean Air Act. Failure to take such 

appeal constitutes acceptance by the applicant of all 

terms of the permit. 

~ 4. Construction Progress - Start of construction, 

construction interruptions exceeding 45 days and 

completion of construction shall be reported to the 

appropriate regional office of the TACB not later than 10 

working days after occurrence of the event. 

5. Recordkeepinq - Information and data concerning 

production, operating hours, sampling and monitoring 

data, if applicable, fuel type and fuel sulfur content, 

if applicable, shall be maintained in a file at the plant 

site and made available at the request of personnel from 

the TACB or any local air pollution control program 

having jurisdiction. The file shall be retained for at 

least two years following the date that the information 

or data is obtained. 

6. Maintenance of Emission Control - The facilities covered 

by this permit shall not be operated unless all air 

pollution emission capture equipment and abatement 

equipment are maintained in good working order and 

operating properly during normal facility operations. 

/ 

I-3 13' 
~ .; 

Li 

SPECIAL PROVISIONS 

Permit No. 21012 

EMISSION STANDARDS AND FUEL SPECIFICATIONS 

1. This permit covers only those sources of emissions listed 

in the attached table entitled "Emission Sources - 

Maximum A1lowable Emission Rates", and those sources are 

limited to the emission limits and other conditions 

specified in that attached table. Annual emissions are 

calbulated for a consecutive 12-month period. 

2. Fuels used in both kilns shall be limited to natural gas 

(NG). The NG shall contain no more than 0.25 grains of 

hydrogen sulfide and 5 grains of total sulfur per 100 dry 

standard cubic feet. Use of any other fuel shall require 

an amendment to the permit. , 

3. Opacity of emissions from Emission Point No. (EPN)-K 

shall not exceed 5 percent, averaged over a 6-minute 

period, except for those periods described in Rule 

111.111(a)(1)(E) of Texas Air Control Board (TACB) 

Regulation I. 

INITIAL DETERMINATION OF COMPLIANCE 

4. The holder of this permit shall perform stack sampling 

and other testing as required to establish the actual 

pattern and quantities of air contaminants being emitted 

into the atmosphere from EPN-K. The testing required by 

this special provision shall be used to determine initial 

compliance with the pound-per-hour limits of the maximum 

allowable emissiori rates table. Initial compliance with 

the permit opacity limit shall be demonstrated on the 

basis of 30 six-minute averages. Sampling must be 

conducted in accordance with appropriate procedures of 

the TACB Sampling Procedures Manual and in accordance 

with Environmental Protection Agency (EPA) Reference 

Method 9 for opacity, Reference Method 10 for carbon 

monoxide (CO), Reference Method 7E for nitrogen oxides 

(NOx ), and Reference Method 3 for oxygen (02 ) or 

equivalent methods. The holder of this permit is 

responsible for providing the sampling and testing 

facilities, conducting the sampling and testing operation 

and all associated expenses. 

A. The TACB regional office with jurisdiction shall be 

notified as soon as testing is scheduled, but not 

less than 45 days prior to sampling to arrange a 

pretest meeting. The notice shall include: 

I-4 

/3~ 
~ 

SPECIAL PROVISIONS 

Permit No. 21012 

Page 3 

6. Operational logs shall be kept for each piece of 

equipment listed in the Permit Table 1(a). These logs 

shall report the daily and year-to-date hours of 

operation and finished product production rates. Any 

abatement equipment downtime shall be recorded on the 

operational logs and referenced to the equipment it 

serVes. Operational logs shall be kept on-site for a 

period of two years and made available upon request to 

any representative of the TACB or EPA with jurisdiction. 

7. Upon request by the TACB, the holder of this permit, at 

its own expense, shall make sufficient stack sampling 

analyses, or other tests, to prove compliance with-this 

permit. A11 sampling and testing procedures shall be 

• • approved by the TACB and coordinated with.the regional 

representatives of_the TACB. 

8. Upon request by the TACB, the holder of this permit, at 

its own expense, shall perform air dispersion modeling 

analyses as directed by the TACB to prove compliance with 

this permit. 

ADDITIONAL PROVISIONS 

~ 9. The holder of this permit shall physically identify and 

mark in a conspicuous location all equipment that has the 

potential of emitting air contaminants as follows: 

A. The facility`"identification number as submitted to 

.the Emissions Inventory Section of the TACB. 

B. The EPN as listed on the maximum allowable emission 

rates table. 

I-6 131 .' 
EMISSION SOURCES - MAXIMUM ALLOWABLE EMISSION RATES 

Permit No. 21012 

~ 

This table lists the maximum allowable emission rates and all sources of air 

contaminants on the applicant's property covered by this permit. The 

emission rates shown are those derived from information submitted as part of 

the application for permit and are the maximum rates allowed for these 

facilities. Any proposed increase in emission rates may require an 

application for a modification of the facilities covered by this permit. 

AIR CONTAMINANTS DATA 

Emission Source Air Contaminant Emission Rates* 

Point No. (1) Name (2) Name (3) lb/hr TPY 

K Adsorber for both VOC 0.2 0.9 

Tunnel Kiln Stacks NOx 4.0 17.6 

S02 21.2 93.3 

PM 10. 2 44 .8' ` 

- CO 1.3 5.8 

HF 0.9 3.9 

(1) Emission point identification - either specific equipment designation or 

emission point number from plot plan. 

(2) Specific point source name. For fugitive sources use area name or 

fugitive source name. 

(3) VOC - volatile organic compounds as defined in General Rule 101.1 

NOx - total oxides of nitrogen 

~ S02 - sulfur dioxide 

CO - carbon monoxide 

HF - hydrogen fluoride 

PM - particulate matter (all forms) 

* Emission rates are based on and the facilities are limited by the 

following maximum operating schedule; are based upon simultaneous 

operation of both kilns: 

Hrs/day24 Days/week 7 Weeks/year52 or Hrs/year8,760 

I-7 I3~ 
r; mgco- EnviRonrnEnTAC 

APPENDIX J 

0 Chain of Custody 

95-134 J-1 

~7 
r"1 

~ . •• . • 

}06* 

untt 

No. o( Aba«b. I n~. 

Conta f ners So{ut {on Vd. 

Finet Co(ft A/ 

FraM W as h 

Ch2m af (.ist Od Y 

Dete 45 z 9 

MethoC 

P ro}ect 

Pert. S02 S03 Othei Mahlaes 

✓ 

11---- ~7F 

~ 

K! 

m 

B~c k W a.s h 

I ~~

~ 

` ~ ✓ 

InV+nQeg' 2 

I mQ( rtger 3 ~ P "OYI 

riCE7crf~✓. 

tnvtrve" 

tMQtr) 9 e C - -11-'

- 

Bl.ank t 

Blank 2 

Other 

S pec4a I f ns 

e 6109 nm%5°~ Locatbn 

8 ~ ZY nrne 20 LocatSai 

e ~~° Ttme ~f

l3

d Locstlon-'/',~ 

Tlme Locatfon 

a tran s poft. Datel M-rTlme ~S~o 

Sarrp4a#/Recov. b}/ 

sarYp;ex Z --Recav. bY 

S.arnp{eeK --'> Recx7v. by 

S.arrp;es Recov. 

Sarrp{es Rcvd. by 

v 71me ~ 

Safre Rcvd. at Eab byr ~ 

D ~o a 

- 

I y 

lf ~ t~ I ~E3tA/~/ Satmple ^nafyzed by ~ , 

. OHte /~~ ~ , 1 1q" Tifi19 Derta Checked by ~' 

J-2 
7 

R 

C 

C12im of Cj:st(>dy 

C14ent ~D•• Method 410' 

i~

SQiC~, ~ P ro}ect 1~, l ocat Fon 

llntt 

No o( Abaorb. Init. Part. S02 S03 Othei MaNaeG 

Contairrets Sautfor, va. 

Fllter COCtit 

Frostt W ea h 

Back Wa.sh 

r~ 

,ro70 z 

Impi*rV(x 2 ~ T 

lmpdnger 3 

(ttpftes 4 

Imp4ro¢ec 5 

BlFitlk 1 

Biank 2 ~ 

hecSpeclat tnatnxd Ion 

~ 

e ~O ~9 Tlme ~~°i~ LocatSor~ 4/l9i(/ 

. : .. . 

8~d ocat)on U~l~ 

/~/3d L«atEo«, ~/~ 

SampiGo Reaav. by Oate Tlme Locstfori 

Sampdes Rcvd. by o~ tran s port DetA 6 ~dTl me 

Se.tr-p;e Rcvd. at Eab by ~~c_, Date Tlme Q ~G'o 

S.e, mp{e A-r;atyZed by ~ rf . ~ l ~ ; OeiA 9S Tkne 1;;2e d 

Data Checked t7y ~+r Dete ~~ I'~1 ~ Tlme D OO 

J-3 /~ 
1 V?IMEICO 

 9MROMEf1TAl 

am 

APPENDIX K 

Resumes of Test Personnel 

95-134 K-1 

~ v 
~ METC-0- 

L_J Ef1VIR0(1fTlEf (TAl 

BILLY J. MULLINS, JR., President 

Education Post Graduate Study Environmental Engineering at 

Southern Methodist University, Dallas, Texas 1970. 

M.S. 1969, New York University, New York, New York, 

in Civil Engineering (Air Resources). 

B.S. 1968, Texas Tech University, Lubbock, Texas, in Civil 

Engineering (Water Resources). Studies in Engineering at U.S. 

Naval Academy, Annapolis, Maryland, 1963-1964. 

Professional Attended Short Course on Air Pollution Engineering at 

Traininq the University of Texas at Austin, February 1970. 

Courses 

Attended four-week management course presented by the 

American Management Association, 1976. 

Certification Registered Professional Engineer 

Certified Visible Emissions Evaluator 

Certified Fallout Shelter Analyst 

Licensed Private Pilot (Multi-Engine-Land, Instrument) 

Diplomat in the American Academy of Environmental Engineers 

Inductee into the Stack Sampling Hall of Fame 

Professional Air & Waste Management Association - Past Chairman, Past Vice 

Memberships Chairman and Past Board of Directors 

Southwest Section: Past Chairman, Consultants Committee; Past 

Chairman, Source Measurement Committee 

Source Evaluation Society - Past President, Past Board of Directors 

American Management Association 

K- Z iq3 
ij me1E(1TAl 

:t 

i 1 

MULLINS 

Publications Co-authored "Sulfur Compound Emissions of the 

Petroleum Production Industry," December 1974. 

Co-authored "Field Procedure for Stabilizing Hydrogen 

Sulfide Samples to be Analyzed Using Modified 

Methylene Blue Technique," presented at the Conference 

on Ambient Air Quality Measurements, Austin, Texas, 

March 1975. 

Co-authored "Atmospheric Emissions Survey of the Sour 

Gas Industry," October 1975. 

Co-authored "Technique for Insuring the Validity of 

Samples for High Concentrations of Sulfur Dioxide Using 

the EPA Method 5 Sampling Train,° presented at the 

Third National Conference on Energy and the 

Environment, College Corner, Ohio, September 1975. 

Teaching Served as a lecturer in the Environmental Protection 

Experience Agency's training course number 450, "Source Sampling 

for Particulate Pollutants," for two years from 

January 1974 to October 1975 and in March, 1992. 

Conducted a two-day training course entitled "Technical 

Assistance in Source Sampling" at lowa State University, 

Ames, lowa, for the Environmental Protection Agency, 

October 1974. 

Conducted EPA's training course number 450, "Source 

Sampling for Particulate Pollutants," for the EPA at 

Research Triangle Park, North Carolina, September 1975. 

,-, A 
In 

me~ 

L~ Ef1VIROf1f71~f1TAL 

MULLINS 

Teachinq Conducted a two-day short course entitled "Performing 

Experience and Observing Source Sampling" at Dallas, Texas, 

July 1976, May 1977, October 1977, November 1987 and November 

1988; at Lake Charles, Louisiana, May 1977; at Casper, Wyoming, 

May 1977; and at Point Comfort, Texas, November 1992. 

Served as a lecturer in the Environmental Protection 

Agency's two-day seminar entitled "Asphalt Industry 

Environmental Solutions," presented in Dallas, Texas, on 

March 21 and 22, 1979. 

Conducted a two-day short course entitled "Performing 

and Observing Source Sampling" in Phoenix, Arizona in August, 

1990 for the State of Arizona, Department of Environmental Quality; 

in Lincoln, Nebraska, in March 1980 for the State of Nebraska, Air 

Quality Control Division. 

Technical Directed and performed stack sampling on over 

Experience 2000 sources of which over 500 were sampled simultaneously 

using more than one sampling train at several points in 

the flue gas stream. 1972-present. 

Directed and performed over 200 short-term ambient air 

studies using mobile sampling vans and various ambient 

air sampling equipment. 1972-present. 

Designed, directed and operated over 20 permanent 

ambient air networks of various size and duration for a 

variety of parameters. 1972-present. 

Designed surface and underground drainage systems for 

residential subdivisions, public works projects, and 

shopping centers. 1969-1972. 

Designed several residential subdivisions including lot 

layout, street design, drainage design, and utility design. 

1969-1972. 

K-4 I ~~ 

9 

r, 
MEFCO_ 

L~J Ef1VIROfIfI'E(1TAL 

MULLINS 

Research Supervised and conducted a study made by the Hawaiian 

Proiects Sugar Planters' Association to characterize the emissions 

for several bagasse-fired boilers. April-May 1976. 

Supervised and conducted a study made by the Rio 

Grande Valley Sugar Growers, Inc. to determine the area 

affected by the burning of sugarcane fields prior to 

harvesting. November 1974-April 1975. 

Supervised and conducted a study by a lightweight 

aggregate manufacturer to develop a material balance 

around the process through sampling and analysis of 

several parameters. November 1973. 

Conducted a study in New York City to attempt to 

develop a correlation in the ambient air between carbon 

dioxide and sulfur dioxide to provide a tool for 

predicting air pollution episodes. January-May 1969. 

Related Served as Chairman of the Engineering Foundation Conference on 

Proiects Stack Sampling and Source Evaluation in Santa Barbara, California, 

1985. 

Served as Session Chairman at th e Engineering Foundation 

Conference on Stack Sampling and Source Evaluati.on in Hershey, 

Pennsylvania, 1984; in San Diego, California, 1993; and in Palm 

Coast, Florida, 1994. 

n 14 

~ 

r" 
ri PImErco —~ Ef1ViROflfTli=fTfAl 

GORDON G. SMITH, Project Supervisor I 

Education B.S. 1988, University of Massachusetts, Amherst, Massachusetts, in 

Environmental Design. 

A.S. 1986, Stockbridge School of Agriculture, Amherst, 

Massachusetts, in Landscape Operations. 

Professional Attended 40-hour Occupational and Environmental Training Program 

Training , on Hazardous Materials (CFR 1910.120) Dallas, Texas, April 1992. 

Courses 

Technical Participated in the sampling of over 150 sources, including several of 

Experience which were sampled simultaneously using more than one sampling 

train. Thoroughly trained in all EPA testing procedures. 

1992-present. 

p 

~_ x-6 M ' I 
~ mErco- a 

TIM STARTZ, Project Supervisor 

Education B.B.A. 1991, University of Texas at Arlington, Arlington, Texas, 

in Management with a minor in Accounting. 

Professional Attended 40-hour Occupational and Environmental Training Program 

Traininq on Hazardous Materials (CFR 1910.120) Dallas, Texas, April 1992. 

Courses Also attended an 8-hour refresher course, February 1995. 

Technical Participated in the sampling of over 300 sources, including 

Experience several of which were sampled simultaneously using more than one 

sampling train. Thoroughly trained in all EPA testing procedures. 

1992-present. 

Experienced in the analysis of commercial calibration gas cylinders 

for CO2, 02 , NOX , S02 , and CO. 

Experienced with the Modified Method 5 Sampling Train (Method 0010). 

Experienced with the Chrome 6 Sampling Train. 

Experienced with the PM, oSampling Train. 

Experienced with various multiple metals and acid gas sampling trains. 

Experienced with the VOST sampling procedure (Method 0030). 

Experienced with calibration techniques for all field testing equipment. 

Has performed on-site S02analysis. 

Has performed on-site H 2S analysis. 

K-7 /4f 
~ METCO 

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STARTZ 

Thoroughly trained in the operation and routine maintenance of the 

following: 

Thermo Environmental Model 10AR and 10S Oxides of Nitrogen 

Analyzers 

Teledyne Model 326 Oxygen Analyzer 

Ratfisch Model RS-55 Total Hydrocarbon Analyzer 

Horiba Model PIR 2000 Carbon Dioxide Analyzer 

J.U.M. Model VE-7 Total Hydrocarbon Analyzer 

Western Research 721 M Sulfur Dioxide Analyzer 

Thermo Environmental Model 48 Carbon Monoxide Analyzer 

Anarad 880 Oxides of Nitrogen Analyzer 

Anarad 23 Oxygen Analyzer 

Anarad 30 Sulfur Dioxide Analyzer 

Anarad 50C Carbon Dioxide Analyzer 

0 

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V?J mErcoEnuRonrnEnTAC 

DALE GREENFEATHER, Environmental Technician I 

Education B.S. 1994, Wichita State University, Wichita, Kansas, in Geology. 

Technical Participated in the sampling of over 25 sources, including 

Experience several of which were sampled simultaneously using more than 

one sampling train. Thoroughly trained in all EPA testing procedures. 

1994-present. 

K-9 ~