## Effluent Quality Assessment 

# Florida Power & Light Lauderdale Plant
Broward County

NPDES #FL0001503 Sampled February 4, 2008

April 2008

Biology Section Bureau of Laboratories Division of Resource Asses sment and Management

Quality Manual No. 870346G NELAC Certification No. E31780

### 1 Florida Power & Light-Lauderdale Plant, 4300 SW 42 Avenue, Ft. Lauderdale, Broward County, Florida, NPDES #FL0001503. Effluent samples for this facility were collected on February 4, 2008.



### Introduction Florida Power & Light-Lauderdale Plant is a power pl ant with a design flow of 800 million gallons per day (MGD). Effluent discharge is continuous. The annual average daily flow (AADF) from February 2007 through February 2008 was 720 MGD. Wastewater consists of:

• Once-through cooling water;

• Auxiliary equipment discharges,

• Boiler blowdown discharges;

• Construction and Maintenance related discharges;

• Stormwater runoff;

• Reverse Osmosis (R.O.) reject wastewater;

• Demineralizer regeneration wastewater;

• Low-Volume waste treatment effluent;

• Metal cleaning waste effluent.

Boiler blowdown, metal cleaning wastes, and pre-treat ed oily waste-streams ar e treated in the plant’s wastewater treatment syst em prior to discharge to an on-site ca nal. Additional wastewater treatment includes chlorination with chlorine gas for once-through cooling water and auxiliary-equipment cooling water; pH-adjustment (if necessary) of R.O. reject -water, and neutralization of demineralizer-regeneration water. These wastewaters ar e discharged into an on-site canal, which in turn discharges into an on-site, Once-Through cooling pond. The Once-Through cooling pond discharges from Outfall D-001 through a culvert to the South Fork of New River, a Clas s III Marine surface water body. Additional permitted surface water discharges include stormwater thro ugh Outfall D-00B1 and intake-screen wastewater and strainer backwash water from Outfall D-009. Outfalls D-00B1 and D-009 discharge into the Dania Cutoff Canal.

The facility has no Administrative Orde rs or Consent Orders. The facility has no mixing zones. A review of Discharge Monitoring Report (DMR) data for the pa st year revealed no permit violations. (Facility information provided by Terry Davi s of FDEP Southeast District.)



### Methods “The samples for the FYI were not taken at D-001 (EFF -3), the cooling pond discharge to the South Fork of New River due to the potential inclusion of pollutant s from boats (yachts) dock ed just upstream of the sampling point. Since temperature is not an issue with the toxicity sampling, the samples were taken upstream where the discharge canal leaves the pl ant site and enters the cooling pond, located at approximately longitude 78o 02’ 37” W and latitude 23 o 54’ 00” N, as determined on FDEP Consolidated Web Mapping Application (C/A MapDirect). The samp les taken there would be more stringent than if taken at EFF-3 because there would not be the subst antial dilution or attenuation afforded by the cooling pond” (email correspondence from Terry Davis). The samples were collected by Terry Davis of FDEP Southeast District following DEP-SOP-001/01 FS 2400 Wastewater Sampling. All DEP SOPs are available on the web at: http://www.floridadep.org/labs/qa/sops.htm

. See Appendix A for the completed chain of custody form.

The 48-hour acute screening toxicity tests and alga l growth potential test were performed following internal DEP SOPs TA07_03, TA07_04, and TA08_01 through TA08_09. All internal DEP SOPs are available on the web at: http://www.floridadep.org/labs/cgi-bin/sop/biosop.asp . Although the 48-hour acute screening toxicity test does not reflect the re quired permit conditions, passing test results provide confidence that the required permit conditions would likely be met.



### Toxicity Test Results Tests were performed February 4 - 6, 2008.

### 2 Americamysis bahia 48-hour acute screening bioassay – LC 50 > 100%, 0% mortality* in 100% sample at 48 hours

Menidia beryllina 48 -hour acute screening bioassay – LC 50 > 100%, 0% mortality* in 100% sample at 48 hours

The bioassay samples were not acutely toxic to the test organisms.

See Appendix B for bioassay bench sheets. See Appendix C for results of the last 20 standard reference toxicant (SRT) tests and the bench sheets and statisti cal analyses of the SRT tests that correspond to these facility tests. See Appendix D for test organism receipts.

*NOTE: In a 48-hour acute screening test of 100% e ffluent, mortality of <20% provides confidence that the effluent meets the acute toxicity criterion of Florida’s Surface Water Quality Standards (Rule 62- 302.500 (1)(a)4, F.A.C.). Mortalit y between 20-50% indicates low to moderate levels of toxicity, and further action may be required. Mortality of >50% indi cates that the effluent fails to meet the minimum requirement to discharge to waters of the state (Rule 62-4.24 4(3)(a), F.A.C.).



### Algal Growth Potential The effluent Algal Growth Potential (AGP) was 3.3 mg dry wt/L of the saltwater species Dunaliella tertiolecta. Raschke and Shultz found that AGP values abov e 10.0 mg dry weight/L represent a “problem” threshold for marine receiving waters, implying nutrient enrichment (personal communication with Ron Raschke USEPA Region 4, 1987). The analytical chemistr y suggests that the e ffluent is phosphoruslimited.

See Table 1 for AGP results.



### Chemistry Results
Total residual chlorine and total ammonia were not dete cted in the bioassay sample in the laboratory. The total ammonia concentration in the sample collected and preserved for chemical analysis was 0.11 mg/L. Based on the pH, salinity, and temperature of the e ffluent as collected, the calculated unionized ammonia concentration was ≤ 0.02 mg/L.

Copper (8.4 μg/L) was detected in the effluent at levels that exc eed the Class III Marine water quality criteria for copper ( ≤ 3.7 μg/L; 62-302.530(23), F.A.C.). Ar senic and iron were detected between the laboratory method detection limits (MDL) and practical quantitation limits (PQL).

See Table 2 for results of analytes detected in t he effluent, and corresponding limits. See Appendix E for a complete list of chemical analyses performed.



### Conclusion The effluent sample collected from Outfall D00-1 for th is facility on February 4, 2008, was not acutely toxic to either test species during the 48-hour acut e screening bioassays. The effluent AGP result was less than the "problem” threshold for marine receiv ing waters. Effluent copper exceeded the Class III Marine water quality criterion for copper.



### Literature Cited Maloney, T. E., W. E. Miller, and D. T. Specht. 19 74. The Marine Algal Assay Procedure: Bottle Test. National Environmental Research Center Office of Research and Development. U. S. EPA, Corvallis, Oregon. 43 p.

### 3 Florida Power & Light Company Lauderdale Plant

Inor g anic Total Location N:P ratio N:P ratio Discharge Canal 3.3 A 21.8 46.9 A - Value reported is the mean of two or more determinations Table 1. Measured and predicted algal growth potential (AGP; mg dry weight/L) of the saltwater species Dunaliella tertiolecta and ratios of nitrogen to phosphorus for samples collected from the Florida Power and Light-Lauderdale Plant on February 4, 2008.

AGP (measured)

### 4 Florida Power & Light -Lauderdale Plant NPDES # FL0001503 Class III Criteria Effluent Limits

Aluminum ≤ 1,500 - 180 U Arsenic ≤ 50 - 1.6 I Cadmium ≤ 8.8 - 0.06 U Calcium (mg/L) - - 258 Chromium-III - - 3 U Copper ≤ 3.7 - 8.4 Iron ≤ 300 - 120 I Lead ≤ 8.5 - 0.6 U Magnesium (mg/L) - - 656 Nickel ≤ 8.3 - 0.75 U Selenium ≤ 71 - 1.5 U Silver ≤ 2.3 - 0.075 U Zinc ≤ 86 - 15 U

Ortho-phosphate - - 0.017 I Total Phosphorus - - 0.026 I Total Ammonia - - 0.11 Un-ionized Ammonia - - ≤ 0.02 c Nitrate and Nitrite - - 0.26 Total Kjeldahl Nitrogen - - 0.96 Organic Nitrogen - - 0.85 c Total Nitrogen - - 1.22 c

Dissolved Oxygen (mg/L) ≥ 4.0 - 7.2 pH (SU) 6.5 - 8.5 6.5 - 8.5 7.4 Conductivity (μmhos/cm) - - 28,570 Temperature °C - 36 m 34.2 Salinity - - 14.6 c Sample Depth (m) - - 0.1 Total Residual Chlorine (mg/L) ≤ 0.01 - ≤ 0.03 £ Chlorophyll a (μg/L) - Corrected - - 5 Phaeophytin (μg/L) - - 1.7 Total Dissolved Solids (mg/L) - - 18,000 Flow (MGD) - 800 a 720 a Hardness (mg CaCO 3 )

- - 3345.63 c

Value exceeds the Class III Water Quality Criteria or permit limits a - Annual average m - Monthly Maximum Oct.- May c - Value is calculated A

- Value reported is the mean of two or more determinations I - The reported value is between the laboratory method detection limit and the laboratory practical quantitation limit U - Material analyzed for but not detected; value reported is the method detection limit £- Measured in Central Lab Table 2. Effluent limits, Class III Criteria for predominantly marine waters and chemical data for samples collected from the Florida Power and Light-Lauderdale Plant on February 4, 2008.

Nutrients (mg/L)

General Physical and Chemical Parameters Effluent

Metals (μg/L unless otherwise noted)

### 5 Appendix A. Chain of Custody Form

### 6 Appendix B. Bench Sheets

### 7 Appendix B. (continued)

### 8 Appendix B. (continued)

### 9 Appendix B. (continued)

### 10 Appendix B. (continued)

### 11 Appendix C. SRT Bench Sheet s and Statistical Analysis Florida Department of Environmental Protection Bureau of Laboratories

Standard Reference Toxicant (SRT) Test Data - 48-hour Acute Toxicity Americamysis bahia (mysid shrimp) - Cadmium Chloride (CdCl 2 )

Date LC50 Mean LC50 Std Dev Lower Control Limit Upper Control Limit 08/01/06 78.84 54.85 12.54 29.78 79.92 09/06/06 63.78 55.44 12.30 30.85 80.04 10/03/06 57.10 55.55 11.89 31.77 79.32 10/31/06 47.52 55.07 11.67 31.73 78.42 11/28/06 54.87 55.06 11.33 32.41 77.71 01/16/07 38.23 54.18 13.92 26.33 82.03 02/13/07 56.06 54.27 12.71 28.85 79.69 03/14/07 70.07 55.86 11.23 33.40 78.32 04/10/07 42.91 56.00 11.04 33.91 78.08 05/08/07 39.00 55.42 11.63 32.16 78.68 05/30/07 49.64 54.95 11.67 31.62 78.29 07/03/07 49.64 55.04 11.62 31.80 78.27 07/31/07 43.54 54.34 11.88 30.58 78.10 09/05/07 45.79 54.15 11.99 30.17 78.13 10/02/07 41.44 53.25 12.24 28.76 77.73 11/06/07 35.65 52.06 12.76 26.55 77.57 12/11/07 50.27 52.86 12.06 28.75 76.98 01/08/08 64.65 53.42 12.03 29.36 77.48 2/5/2008 * 23.52 50.68 13.02 24.64 76.72 02/12/08 36.63 49.45 13.14 23.17 75.74

Lower Confidence Limit = mean - 2 * Std Dev CV = 26.57 Upper Confidence Limit = mean + 2 * Std Dev EPA reference 75th quartile CV = 26%

* Test result exceeded control limits on 2/5/2008. Test repeated on 2/12/2008. Standard Reference Toxicant Data Americamysis bahia LC 50

20 30 40 50 60 70 80 9008/01/0609/06/0610/03/0610/31/0611/28/0601/16/0702/13/0703/14/0704/10/0705/08/0705/30/0707/03/0707/31/0709/05/0710/02/0711/06/0712/11/0701/08/082/5/2008 *02/12/08

Test Dateμg/L CdCl2

LC50 Mean LC50 Lower Control Limit Upper Control Limit

### 12 Appendix C. (continued) Florida Department of Environmental Protection Bureau of Laboratories

Standard Reference Toxicant ( SRT ) Test Data - Acute Toxicit y M

en idi a b ery lli

na (I n l an d s il vers id e ) - C opper Chl or id e (C u Cl 2 

### )

Date LC50 Mean LC50 Lower control limit Lower warning limit Upper warning limit Upper control limit 07/15/06 264.59 325.48 247.2 284.4 387.2 401.5 08/01/06 210.80 316.05 221.3 263.4 369.7 395.6 09/12/06 258.82 312.50 221.3 259.6 369.7 395.6 10/03/06 217.64 307.20 217.0 256.6 369.7 395.6 10/31/06 203.06 304.28 210.0 249.7 369.7 395.6 11/28/06 140.31 292.22 201.0 221.3 341.2 391.4 01/16/07 301.29 291.93 201.0 221.3 341.2 391.4 02/14/07 278.00 291.27 201.0 221.3 341.2 391.4 03/14/07 316.16 287.74 201.0 221.3 333.3 391.4 04/10/07 338.35 291.67 201.0 221.3 334.8 391.4 05/22/07 257.44 293.42 201.0 247.5 334.8 391.4 05/30/07 247.36 289.10 201.0 239.9 334.4 391.4 07/03/07 357.65 288.79 201.0 239.9 334.4 391.4 07/31/07 350.68 290.88 201.0 239.9 341.4 391.4 09/05/07 338.18 288.38 201.0 239.9 338.2 363.8 10/02/07 338.90 289.15 201.0 239.9 338.4 363.8 11/06/07 419.55 289.15 201.0 239.9 338.4 363.8 12/04/07 356.07 285.50 201.0 239.9 338.4 356.2 01/08/08 329.03 285.29 200.9 239.9 338.5 356.2 02/05/08 357.47 294.07 210.0 254.9 341.9 357.5

Means are of the last 20 SRT tests. Upper warning and control limits are the 75th and 90th percentiles, respectively, of the past 20 LC50s. Lower warning and control limits are the 25th and 10th percentiles, respectively, of the past 20 LC50s. EPA reference 75th quartile CV = 21% CV = 23.05



### Standard Reference Toxicant Data

Menidia beryllina 48 hour LC50

0 50 100 150 200 250 300 350 400 45007/15/0608/01/0609/12/0610/03/0610/31/0611/28/0601/16/0702/14/0703/14/0704/10/0705/22/0705/30/0707/03/0707/31/0709/05/0710/02/0711/06/0712/04/0701/08/0802/05/08



### Test Dateμg/L CuCl2

Lower warning limit LC50 Mean LC50 Upper warning limit Lower control limit Upper control limit

### 13 Appendix C. (continued)

### 14 Appendix C. (continued)

### 15 Appendix C. (continued) 

### DATE: 2-12-08 TEST NUMBER: 1 DURATION: 48 h TOXICANT : CdCl2 SPECIES: Americamysis bahia

RAW DATA: Concentration Number Mortalities (ug/L) Exposed .00 20 0 20.00 20 1 30.00 20 2 45.00 20 18 67.00 20 20 100.00 20 20

SPEARMAN-KARBER TRIM: 5.00%

SPEARMAN-KARBER ESTIMATES: LC50: 36.53 95% LO WER CONFIDENCE: 33.62 95% UP PER CONFIDENCE: 39.69

-------------------------------------------- ---------------------------------- DATE: 2-5-08 TEST NUM BER: 1 DURATION: 48 h TOXICANT : CuCl2 SPECIES: Menidia beryllina

RAW DATA: Concentration Number Mortalities (ug/L) Exposed .00 20 0 100.00 20 2 200.00 20 1 300.00 20 6 400.00 20 12 500.00 20 17

SPEARMAN-KARBER TRIM: 15.00%

SPEARMAN-KARBER ESTIMATES: LC50: 357.47 95% LOWER CONFIDENCE: 314.66 95% UPPER CONFIDENCE: 406.10

NOTE: MORTALITY PROPORTIONS WERE NOT MONOTONICALLY INCREASING. ADJUSTMENTS WERE MADE PRIOR TO SPEARMAN-KARBER ESTIMATION.

### 16 Appendix D. Test Organism Receipts

### 17 Appendix D. (continued)18Appendix E. Chemical Analyses performed on the effluent from the Florida Power and Light- Lauderdale PlantOutfall D-001, sampled on February 4, 2008.Date Sampled Field ID Analysis Group Components Result Remarks Units MDL PQL2/4/2008 10:35 EFFLUENT AGP/LN Algal Growth Potential 3.33 A mg DryWt/L 3 32/4/2008 10:35 EFFLUENT Chlorophyll/Grain Size/BOD Phaeophytin-a 1.7 ug/L 0.24 0.712/4/2008 10:35 EFFLUENT Chlorophyll/Grain Size/BOD Chlorophyll-a, Corrected 5 ug/L 0.55 1.72/4/2008 10:35 EFFLUENT Toxicology Bioassay-Acute-Screen-SW-Mysid, LC50 100 L LC502/4/2008 10:35 EFFLUENT Toxicology Bioassay-Acute-Screen-SW-Fish, LC50 100 L LC502/4/2008 10:35 EFFLUENT Metals Calcium 258 mg/L 0.22 0.92/4/2008 10:35 EFFLUENT Metals Chromium 3 U ug/L 3 122/4/2008 10:35 EFFLUENT Metals Copper 8.4 ug/L 1.5 62/4/2008 10:35 EFFLUENT Metals Cadmium 0.06 U ug/L 0.06 0.242/4/2008 10:35 EFFLUENT Metals Selenium 1.5 U ug/L 1.5 62/4/2008 10:35 EFFLUENT Metals Lead 0.6 U ug/L 0.6 2.42/4/2008 10:35 EFFLUENT Metals Nickel 0.75 U ug/L 0.75 32/4/2008 10:35 EFFLUENT Metals Silver 0.075 U ug/L 0.075 0.32/4/2008 10:35 EFFLUENT Metals Aluminum 180 U ug/L 180 7202/4/2008 10:35 EFFLUENT Metals Arsenic 1.6 I ug/L 1.5 62/4/2008 10:35 EFFLUENT Metals Iron 120 I ug/L 90 3602/4/2008 10:35 EFFLUENT Metals Zinc 15 U ug/L 15 602/4/2008 10:35 EFFLUENT Metals Magnesium 656 mg/L 0.8 3.22/4/2008 10:35 EFFLUENT Nutrients O-Phosphate-P 0.017 I mg P/L 0.008 0.022/4/2008 10:35 EFFLUENT Nutrients Total-P 0.026 I mg P/L 0.02 0.062/4/2008 10:35 EFFLUENT Nutrients NO2NO3-N 0.26 mg N/L 0.004 0.012/4/2008 10:35 EFFLUENT Nutrients Kjeldahl Nitrogen 0.96 mg N/L 0.08 0.22/4/2008 10:35 EFFLUENT Nutrients Ammonia-N 0.11 mg N/L 0.01 0.022/4/2008 10:35 EFFLUENT Nutrients TDS 18000 mg/L 600 24002/4/2008 10:35 EFFLUENT Priority Organic Pollutants N-Nitrosodiphenylamine/ Diphenylamine 2.9 U ug/L 2.9 122/4/2008 10:35 EFFLUENT Priority Organic Pollutants Phenol 0.97 U ug/L 0.97 3.92/4/2008 10:35 EFFLUENT Priority Organic Pollutants Pyrene 0.97 U ug/L 0.97 3.92/4/2008 10:35 EFFLUENT Priority Organic Pollutants beta-BHC 1.5 U ug/L 1.5 5.82/4/2008 10:35 EFFLUENT Priority Organic Pollutants delta-BHC 1.5 U ug/L 1.5 5.82/4/2008 10:35 EFFLUENT Priority Organic Pollutants 4-Chlorophenyl phenyl ether 1.9 U ug/L 1.9 7.82/4/2008 10:35 EFFLUENT Priority Organic Pollutants 4-Nitrophenol 15 U ug/L 15 582/4/2008 10:35 EFFLUENT Priority Organic Pollutants Benzo(a)pyrene 0.97 U ug/L 0.97 3.92/4/2008 10:35 EFFLUENT Priority Organic Pollutants Di-n-butyl phthalate 4.9 U ug/L 4.9 1919Appendix E. (continued)Date Sampled Field ID Analysis Group Components Result Remarks Units MDL PQL2/4/2008 10:35 EFFLUENT Priority Organic Pollutants Di-n-octyl phthalate 0.97 U ug/L 0.97 3.92/4/2008 10:35 EFFLUENT Priority Organic Pollutants Endrin 1.5 U ug/L 1.5 5.82/4/2008 10:35 EFFLUENT Priority Organic Pollutants Fluoranthene 0.97 U ug/L 0.97 3.92/4/2008 10:35 EFFLUENT Priority Organic Pollutants Hexachlorobutadiene 2.9 U ug/L 2.9 122/4/2008 10:35 EFFLUENT Priority Organic Pollutants Hexachlorocyclopentadiene 2.9 U ug/L 2.9 122/4/2008 10:35 EFFLUENT Priority Organic PollutantsN-Nitrosodi-n-propylamine 1.9 U ug/L 1.9 7.82/4/2008 10:35 EFFLUENT Priority Organic Pollutants 2,4-Dichlorophenol 0.97 U ug/L 0.97 3.92/4/2008 10:35 EFFLUENT Priority Organic Pollutants 4,4'-DDE 1.5 U ug/L 1.5 5.82/4/2008 10:35 EFFLUENT Priority Organic Pollutants Anthracene 0.97 U ug/L 0.97 3.92/4/2008 10:35 EFFLUENT Priority Organic Pollutants Benzo(a)anthracene 0.97 U ug/L 0.97 3.92/4/2008 10:35 EFFLUENT Priority Organic Pollutants Butyl benzyl phthalate 4.9 U ug/L 4.9 192/4/2008 10:35 EFFLUENT Priority Organic Pollutants Dieldrin 1.5 U ug/L 1.5 5.82/4/2008 10:35 EFFLUENT Priority Organic Pollutants Endosulfan sulfate 1.5 U ug/L 1.5 5.82/4/2008 10:35 EFFLUENT Priority Organic Pollutants Heptachlor epoxide 1.5 U ug/L 1.5 5.82/4/2008 10:35 EFFLUENT Priority Organic Pollutants Hexachloroethane 2.9 U ug/L 2.9 122/4/2008 10:35 EFFLUENT Priority Organic Pollutants 2-Nitrophenol 0.97 U ug/L 0.97 3.92/4/2008 10:35 EFFLUENT Priority Organic Pollutants Bis(2-chloroethyl)ether 0.97 U ug/L 0.97 3.92/4/2008 10:35 EFFLUENT Priority Organic Pollutants Dimethyl phthalate 9.7 U ug/L 9.7 392/4/2008 10:35 EFFLUENT Priority Organic Pollutants Hexachlorobenzene 0.97 U ug/L 0.97 3.92/4/2008 10:35 EFFLUENT Priority Organic Pollutants Naphthalene 0.97 U ug/L 0.97 3.92/4/2008 10:35 EFFLUENT Priority Organic Pollutants 2-Chlorophenol 0.97 U ug/L 0.97 3.92/4/2008 10:35 EFFLUENT Priority Organic Pollutants 4-Bromophenyl phenyl ether 0.97 U ug/L 0.97 3.92/4/2008 10:35 EFFLUENT Priority Organic Pollutants 4-Chloro-3-methylphenol 0.97 U ug/L 0.97 3.92/4/2008 10:35 EFFLUENT Priority Organic Pollutants Dibenzo(a,h)anthracene 0.97 U ug/L 0.97 3.92/4/2008 10:35 EFFLUENT Priority Organic Pollutants Heptachlor 1.5 U ug/L 1.5 5.82/4/2008 10:35 EFFLUENT Priority Organic Pollutants Nitrobenzene 1.9 U ug/L 1.9 7.82/4/2008 10:35 EFFLUENT Priority Organic Pollutants Phenanthrene 0.97 U ug/L 0.97 3.92/4/2008 10:35 EFFLUENT Priority Organic Pollutants 2,4,6-Trichlorophenol 0.97 U ug/L 0.97 3.92/4/2008 10:35 EFFLUENT Priority Organic Pollutants 3,3'-Dichlorobenzidine 39 UJ ug/L 39 1602/4/2008 10:35 EFFLUENT Priority Organic Pollutants 4,4'-DDT 1.5 U ug/L 1.5 5.82/4/2008 10:35 EFFLUENT Priority Organic Pollutants Aldrin 1.5 U ug/L 1.5 5.82/4/2008 10:35 EFFLUENT Priority Organic Pollutants Benzo(g,h,i)perylene 0.97 U ug/L 0.97 3.92/4/2008 10:35 EFFLUENT Priority Organic Pollutants Endosulfan I 3.9 U ug/L 3.9 162/4/2008 10:35 EFFLUENT Priority Organic Pollutants N-Nitrosodimethylamine 1.9 U ug/L 1.9 7.82/4/2008 10:35 EFFLUENT Priority Organic Pollutants 1,2,4-Trichlorobenzene 0.97 U ug/L 0.97 3.920Appendix E. (continued)Date Sampled Field ID Analysis Group Components Result Remarks Units MDL PQL2/4/2008 10:35 EFFLUENT Priority Organic Pollutants 2,4-Dinitrophenol 15 U ug/L 15 582/4/2008 10:35 EFFLUENT Priority Organic Pollutants 2-Methyl-4,6-dinitrophenol 2.9 U ug/L 2.9 122/4/2008 10:35 EFFLUENT Priority Organic Pollutants 4,4'-DDD 1.5 U ug/L 1.5 5.82/4/2008 10:35 EFFLUENT Priority Organic Pollutants Acenaphthene 0.97 U ug/L 0.97 3.92/4/2008 10:35 EFFLUENT Priority Organic Pollutants Benzidine 97 U ug/L 97 3902/4/2008 10:35 EFFLUENT Priority Organic Pollutants Bis(2-chloroethoxy)methane 0.97 U ug/L 0.97 3.92/4/2008 10:35 EFFLUENT Priority Organic Pollutants Endrin aldehyde 3.9 UJ ug/L 3.9 162/4/2008 10:35 EFFLUENT Priority Organic Pollutants Chrysene 0.97 U ug/L 0.97 3.92/4/2008 10:35 EFFLUENT Priority Organic Pollutants Diethyl phthalate 0.97 U ug/L 0.97 3.92/4/2008 10:35 EFFLUENT Priority Organic Pollutants Endosulfan II 3.9 U ug/L 3.9 162/4/2008 10:35 EFFLUENT Priority Organic Pollutants Fluorene 0.97 U ug/L 0.97 3.92/4/2008 10:35 EFFLUENT Priority Organic Pollutants Indeno(1,2,3-cd)pyrene 0.97 U ug/L 0.97 3.92/4/2008 10:35 EFFLUENT Priority Organic Pollutants Pentachlorophenol 2.9 U ug/L 2.9 122/4/2008 10:35 EFFLUENT Priority Organic Pollutants alpha-BHC 1.5 U ug/L 1.5 5.82/4/2008 10:35 EFFLUENT Priority Organic Pollutants gamma-BHC 1.5 U ug/L 1.5 5.82/4/2008 10:35 EFFLUENT Priority Organic Pollutants 2,4-Dimethylphenol 9.7 U ug/L 9.7 392/4/2008 10:35 EFFLUENT Priority Organic Pollutants 2,4-Dinitrotoluene 0.97 U ug/L 0.97 3.92/4/2008 10:35 EFFLUENT Priority Organic Pollutants 2,6-Dinitrotoluene 0.97 U ug/L 0.97 3.92/4/2008 10:35 EFFLUENT Priority Organic Pollutants 2-Chloronaphthalene 0.97 U ug/L 0.97 3.92/4/2008 10:35 EFFLUENT Priority Organic Pollutants Acenaphthylene 0.97 U ug/L 0.97 3.92/4/2008 10:35 EFFLUENT Priority Organic Pollutants Benzo(b)fluoranthene 0.97 U ug/L 0.97 3.92/4/2008 10:35 EFFLUENT Priority Organic Pollutants Benzo(k)fluoranthene 0.97 U ug/L 0.97 3.92/4/2008 10:35 EFFLUENT Priority Organic PollutantsBis(2-chloroisopropyl)ether 2.9 U ug/L 2.9 122/4/2008 10:35 EFFLUENT Priority Organic Pollutants Bis(2-ethylhexyl)phthalate 15 U ug/L 15 582/4/2008 10:35 EFFLUENT Priority Organic Pollutants Isophorone 0.97 U ug/L 0.97 3.92/4/2008 10:35 EFFLUENT Field Parameter Temperature 34.16 C2/4/2008 10:35 EFFLUENT Field Parameter Specific Conductance 28570 umhos/cm2/4/2008 10:35 EFFLUENT Field Parameter Sample Depth 0.1 m2/4/2008 10:35 EFFLUENT Field Parameter Dissolved Oxygen 7.21 mg/L2/4/2008 10:35 EFFLUENT Field Parameter pH 7.352/4/2008 11:30 BLANK Metals Iron 30 U ug/L 30 1202/4/2008 11:30 BLANK Metals Copper 0.5 U ug/L 0.5 22/4/2008 11:30 BLANK Metals Selenium 0.5 U ug/L 0.5 22/4/2008 11:30 BLANK Metals Nickel 0.25 U ug/L 0.25 12/4/2008 11:30 BLANK Metals Arsenic 0.5 U ug/L 0.5 221Appendix E. (continued)Date Sampled Field ID Analysis Group Components Result Remarks Units MDL PQL2/4/2008 11:30 BLANK Metals Aluminum 60 U ug/L 60 2402/4/2008 11:30 BLANK Metals Calcium 0.075 U mg/L 0.075 0.32/4/2008 11:30 BLANK Metals Zinc 5 U ug/L 5 202/4/2008 11:30 BLANK Metals Cadmium 0.02 U ug/L 0.02 0.082/4/2008 11:30 BLANK Metals Magnesium 0.04 U mg/L 0.04 0.162/4/2008 11:30 BLANK Metals Chromium 1 U ug/L 1 42/4/2008 11:30 BLANK Metals Silver 0.025 U ug/L 0.025 0.12/4/2008 11:30 BLANK Metals Lead 0.2 U ug/L 0.2 0.82/4/2008 11:30 BLANK Nutrients Ammonia-N 0.01 U mg N/L 0.01 0.022/4/2008 11:30 BLANK Nutrients NO2NO3-N 0.004 U mg N/L 0.004 0.012/4/2008 11:30 BLANK Nutrients Kjeldahl Nitrogen 0.08 U mg N/L 0.08 0.22/4/2008 11:30 BLANK Nutrients O-Phosphate-P 0.004 U mg P/L 0.004 0.012/4/2008 11:30 BLANK Nutrients Total-P 0.02 U mg P/L 0.02 0.062/4/2008 11:30 BLANK Priority Organic Pollutants Benzo(b)fluoranthene 0.96 U ug/L 0.96 3.82/4/2008 11:30 BLANK Priority Organic PollutantsBis(2-chloroethoxy)methane 0.96 U ug/L 0.96 3.82/4/2008 11:30 BLANK Priority Organic PollutantsBis(2-chloroethyl)ether 0.96 U ug/L 0.96 3.82/4/2008 11:30 BLANK Priority Organic Pollutants Di-n-butyl phthalate 4.8 U ug/L 4.8 192/4/2008 11:30 BLANK Priority Organic Pollutants Dieldrin 1.4 U ug/L 1.4 5.82/4/2008 11:30 BLANK Priority Organic Pollutants Endrin aldehyde 3.8 UJ ug/L 3.8 152/4/2008 11:30 BLANK Priority Organic Pollutants Nitrobenzene 1.9 U ug/L 1.9 7.72/4/2008 11:30 BLANK Priority Organic Pollutants 1,2,4-Trichlorobenzene 0.96 U ug/L 0.96 3.82/4/2008 11:30 BLANK Priority Organic Pollutants 2,4-Dinitrotoluene 0.96 U ug/L 0.96 3.82/4/2008 11:30 BLANK Priority Organic Pollutants4-Chlorophenyl phenyl ether 1.9 U ug/L 1.9 7.72/4/2008 11:30 BLANK Priority Organic Pollutants Dimethyl phthalate 9.6 U ug/L 9.6 382/4/2008 11:30 BLANK Priority Organic Pollutants Endosulfan I 3.8 U ug/L 3.8 152/4/2008 11:30 BLANK Priority Organic Pollutants Endrin 1.4 U ug/L 1.4 5.82/4/2008 11:30 BLANK Priority Organic Pollutants Pentachlorophenol 2.9 U ug/L 2.9 122/4/2008 11:30 BLANK Priority Organic Pollutants Phenanthrene 0.96 U ug/L 0.96 3.82/4/2008 11:30 BLANK Priority Organic Pollutants alpha-BHC 1.4 U ug/L 1.4 5.82/4/2008 11:30 BLANK Priority Organic Pollutants 2-Chloronaphthalene 0.96 U ug/L 0.96 3.82/4/2008 11:30 BLANK Priority Organic Pollutants 4-Nitrophenol 14 U ug/L 14 582/4/2008 11:30 BLANK Priority Organic Pollutants Benzidine 96 U ug/L 96 3802/4/2008 11:30 BLANK Priority Organic Pollutants Benzo(g,h,i)perylene 0.96 U ug/L 0.96 3.82/4/2008 11:30 BLANK Priority Organic Pollutants Bis(2-chloroisopropyl)ether 2.9 U ug/L 2.9 122/4/2008 11:30 BLANK Priority Organic Pollutants Di-n-octyl phthalate 0.96 U ug/L 0.96 3.822Appendix E. (continued)Date Sampled Field ID Analysis Group Components Result Remarks Units MDL PQL2/4/2008 11:30 BLANK Priority Organic Pollutants Fluorene 0.96 U ug/L 0.96 3.82/4/2008 11:30 BLANK Priority Organic Pollutants Heptachlor 1.4 U ug/L 1.4 5.82/4/2008 11:30 BLANK Priority Organic Pollutants Hexachlorocyclopentadiene 2.9 U ug/L 2.9 122/4/2008 11:30 BLANK Priority Organic Pollutants Hexachloroethane 2.9 U ug/L 2.9 122/4/2008 11:30 BLANK Priority Organic Pollutants Isophorone 0.96 U ug/L 0.96 3.82/4/2008 11:30 BLANK Priority Organic Pollutants 2,4,6-Trichlorophenol 0.96 U ug/L 0.96 3.82/4/2008 11:30 BLANK Priority Organic Pollutants 2,4-Dimethylphenol 9.6 U ug/L 9.6 382/4/2008 11:30 BLANK Priority Organic Pollutants 2-Chlorophenol 0.96 U ug/L 0.96 3.82/4/2008 11:30 BLANK Priority Organic Pollutants 4-Bromophenyl phenyl ether 0.96 U ug/L 0.96 3.82/4/2008 11:30 BLANK Priority Organic Pollutants Acenaphthene 0.96 U ug/L 0.96 3.82/4/2008 11:30 BLANK Priority Organic Pollutants Benzo(a)pyrene 0.96 U ug/L 0.96 3.82/4/2008 11:30 BLANK Priority Organic Pollutants Indeno(1,2,3-cd)pyrene 0.96 U ug/L 0.96 3.82/4/2008 11:30 BLANK Priority Organic Pollutants Naphthalene 0.96 U ug/L 0.96 3.82/4/2008 11:30 BLANK Priority Organic Pollutants gamma-BHC 1.4 U ug/L 1.4 5.82/4/2008 11:30 BLANK Priority Organic Pollutants 3,3'-Dichlorobenzidine 38 UJ ug/L 38 1502/4/2008 11:30 BLANK Priority Organic Pollutants Benzo(k)fluoranthene 0.96 U ug/L 0.96 3.82/4/2008 11:30 BLANK Priority Organic Pollutants Bis(2-ethylhexyl)phthalate 14 U ug/L 14 582/4/2008 11:30 BLANK Priority Organic Pollutants Chrysene 0.96 U ug/L 0.96 3.82/4/2008 11:30 BLANK Priority Organic Pollutants Hexachlorobutadiene 2.9 U ug/L 2.9 122/4/2008 11:30 BLANK Priority Organic Pollutants beta-BHC 1.4 U ug/L 1.4 5.82/4/2008 11:30 BLANK Priority Organic Pollutants 4,4'-DDD 1.4 U ug/L 1.4 5.82/4/2008 11:30 BLANK Priority Organic Pollutants Aldrin 1.4 U ug/L 1.4 5.82/4/2008 11:30 BLANK Priority Organic Pollutants Benzo(a)anthracene 0.96 U ug/L 0.96 3.82/4/2008 11:30 BLANK Priority Organic Pollutants Dibenzo(a,h)anthracene 0.96 U ug/L 0.96 3.82/4/2008 11:30 BLANK Priority Organic Pollutants Diethyl phthalate 0.96 U ug/L 0.96 3.82/4/2008 11:30 BLANK Priority Organic Pollutants Endosulfan II 3.8 U ug/L 3.8 152/4/2008 11:30 BLANK Priority Organic Pollutants Endosulfan sulfate 1.4 U ug/L 1.4 5.82/4/2008 11:30 BLANK Priority Organic Pollutants Hexachlorobenzene 0.96 U ug/L 0.96 3.82/4/2008 11:30 BLANK Priority Organic Pollutants N-Nitrosodimethylamine 1.9 U ug/L 1.9 7.72/4/2008 11:30 BLANK Priority Organic Pollutants 2,4-Dichlorophenol 0.96 U ug/L 0.96 3.82/4/2008 11:30 BLANK Priority Organic Pollutants 2,4-Dinitrophenol 14 U ug/L 14 582/4/2008 11:30 BLANK Priority Organic Pollutants 2-Methyl-4,6-dinitrophenol 2.9 U ug/L 2.9 122/4/2008 11:30 BLANK Priority Organic Pollutants 2-Nitrophenol 0.96 U ug/L 0.96 3.82/4/2008 11:30 BLANK Priority Organic Pollutants 4,4'-DDE 1.4 U ug/L 1.4 5.82/4/2008 11:30 BLANK Priority Organic Pollutants 4,4'-DDT 1.4 U ug/L 1.4 5.823Appendix E. (continued)Date Sampled Field ID Analysis Group Components Result Remarks Units MDL PQL2/4/2008 11:30 BLANK Priority Organic Pollutants 4-Chloro-3-methylphenol 0.96 U ug/L 0.96 3.82/4/2008 11:30 BLANK Priority Organic Pollutants Butyl benzyl phthalate 4.8 U ug/L 4.8 192/4/2008 11:30 BLANK Priority Organic Pollutants Fluoranthene 0.96 U ug/L 0.96 3.82/4/2008 11:30 BLANK Priority Organic Pollutants Heptachlor epoxide 1.4 U ug/L 1.4 5.82/4/2008 11:30 BLANK Priority Organic Pollutants N-Nitrosodi-n-propylamine 1.9 U ug/L 1.9 7.72/4/2008 11:30 BLANK Priority Organic Pollutants N-Nitrosodiphenylamine/ Diphenylamine 2.9 U ug/L 2.9 122/4/2008 11:30 BLANK Priority Organic Pollutants delta-BHC 1.4 U ug/L 1.4 5.82/4/2008 11:30 BLANK Priority Organic Pollutants 2,6-Dinitrotoluene 0.96 U ug/L 0.96 3.82/4/2008 11:30 BLANK Priority Organic Pollutants Acenaphthylene 0.96 U ug/L 0.96 3.82/4/2008 11:30 BLANK Priority Organic Pollutants Anthracene 0.96 U ug/L 0.96 3.82/4/2008 11:30 BLANK Priority Organic Pollutants Phenol 0.96 U ug/L 0.96 3.82/4/2008 11:30 BLANK Priority Organic Pollutants Pyrene 0.96 U ug/L 0.96 3.82/4/2008 11:30 BLANK Nutrients Sample Depth 0.01 m

### 24 Transaction Code NPDES NUMBER YR/MO/DA Insp Type Inspector Fac Type

1 N 2 5 3 F L 0 0 0 1 5 0 3 11 12 0 8 0 2 0 5 18 B 19 S 20 2

66

Transaction Code NPDES NUMBER YR/MO/DA Insp Type Inspector Fac Type

1 N 2 5 3 F L 0 0 0 1 5 0 3 11 12 0 8 0 2 0 5 18 X 19 S 20 2

66

Transaction Code NPDES NUMBER YR/MO/DA Insp Type Inspector Fac Type

1 N 2 5 3 F L 0 0 0 1 5 0 3 11 12 0 8 0 2 0 5 18 S 19 S 20 2

66 

## The Bioassay of FPL-Lauderdale Plant effluent sampled on February 5, 2008. NPDES #FL0001503.

Fill Out This Section For All Surface Water Discharger Inspections(CEI, CSI, CBI, PAI, XSI-RI Optional)

Remarks



## The Priority Pollutants Analysis of FPL-Lauderdale Plant effluent sampled on February 5, 2008. NPDES #FL0001503.

Biological Analyses of FPL FPL-Lauderdale Plant effluent sampled on February 5, 2008. NPDES #FL0001503.

Fill Out This Section For All Surface Water Discharger Inspections(CEI, CSI, CBI, PAI, XSI-RI Optional)

Remarks Fill Out This Section For All Surface Water Discharger Inspections(CEI, CSI, CBI, PAI, XSI-RI Optional)

Remarks