S

- Metola chlor Dietary Exposure and Risk Assessment DP # D396451



### Page 2 of 27 re sulting from the Section 3 use of S

- metolachlor on cilantro and garden beet leaves to control

weeds

.

Executive Summary

Acute and chronic dietary risk assessments were conducted for S

- metolachlor using the Dietary

Exposure Evaluation Model (DEEM

- FCID, Version 2.03), which uses food consumption data

from the USDA’s Continuing Surveys of Food Intakes by Individuals (CSFII) from 1994

- 1996

and 1998. The analyses were performed to suppor t a Section 3 request for proposed uses of S

metolachlor on cilantro and garden beet

.

Acute Dietary Exposure Results and Characterization

A conservative acute dietary exposure analysis was performed for the general U.S. population

and various populat ion subgroups. Tolerance level residues and 100 percent crop treated

assumptions were used. DEEM default processing factors were used to modify the tolerance

values. The acute analysis incorporated the 1 in 10 year peak surface drinking water estimate

f r om application of S

- metolachlor on turf

. This assessment concludes that, for all supported

commodities, the acute dietary exposure estimates are below HED’s level of concern. The 95 th



### percentile acute dietary exposure estimate for t he highest exposed population subgroup, all

infants < 1 year old, is 1.5 % of the acute population adjusted dose ( aPAD )

.

Chronic Dietary Exposure Results and Characterization

A conservative chronic dietary exposure analysis was performed for the general U.S. population

and various population subgroups. Tolerance level residues and 100 percent crop treated

assumptions were used. DEEM default processing factors were used to modify the tolerance

values. The chronic analysis incorporated the 10 year avera ge surface drinking water estimate

from application of S

- metolachlor to turf

. The chronic dietary exposure estimate for the highest

exposed population subgroup, all infants < 1 year old, is 1 1 .6 % of the chronic population

adjusted dose ( cPAD )

.

I. Introdu ction

Dietary risk assessment incorporates both exposure and toxicity of a given pesticide. For acute

and chronic assessments, the risk is expressed as a percentage of a maximum acceptable dose

(i.e., the dose which HED has concluded will result in no un reasonable adverse health effects).

This dose is referred to as the population adjusted dose (PAD). The PAD is equivalent to the

Reference Dose (RfD) divided by the FQPA Safety Factor.

For acute and non

- cancer chronic exposures, HED is concerned when es timated dietary risk

exceeds 100 % of the PAD. References that discuss the acute and chronic risk assessments in

more detail are available on the EPA/pesticides web site: “Available Information on Assessing

Exposure from Pesticides, A User’s Guide,” 6/21/ 2000, web link:S

- Metola chlor Dietary Exposure and Risk Assessment DP # D396451



### Page 3 of 27 http://www.epa.gov/fedrgstr/EPA_PEST/2000/July/Day_12/6061.pdf ; or see SOP 99.6

(8/20/99).

The most recent dietary risk assessment for S

- metolachlor was condu cted by W. Cutchin

( D 3 91172

, 7/20/11 ) for the Section 18 use on leaf lettuce

.

II. Residue Information

Metolachlor (PC Code 108801) is a racemic herbicide that consists of 50% each of the R

enantiomer and the S

- enantiomer. S

- metola chlor products are an isomer enriched formula

comprised of 88% S

- isomer and 12% R

- isomer. The residues of concern for S

- metolachlor are

the same as those for metolachlor (D226780, L. Kutney, 11/12/96). The Metabolism Assessment

Review Committee (MARC

, 8/14/001 ) determined that the residues of concern for plant and

livestock commodities are metolachlor and its metabolites, determined as the derivatives 2

- [(2

- ethyl

- 6

- methylphenyl)amino]

- 1

- propanol ( CGA

- 37913 ) and 4

- (2

- ethyl

- 6

- methylphenyl)

- 2

- hydroxy

- 5

- methyl

- 3

- morpholinone ( CGA

- 49751 ) . Metabolites of metolachlor are assumed to be

toxicologically equivalent to parent metolachlor. Permanent tolerances are established at 40

CFR §180.368(a)(2) for S

- metolachlor in/on a variety of crop commodities, at leve ls ranging

from 0.02 in/on meat and dairy products to 20 ppm in/on peanut hay. Tolerances are established

for residues of S

- metolachlor, including its metabolites and degra dates, in or on the commodities

. In cases where separate tolerance listings occur for both metolachlor and S

- metolachlor on the

same commodity, the higher value of the two is used in the analyses. Residues used in the acute

and chronic dietary analyses are provided in Table s 1 , 2, 3 and 4

.

Table 1. Metolachlor Tolerances

Commodity To lerance ( ppm )

Almond, hulls 0.3

Animal feed, nongrass, group 18 1

Cattle, fat; Cattle, meat 0.02

Cattle, kidney 0.2

Cattle, liver 0.05

Cattle, meat byproducts, except kidney and liver 0.04

Corn, field, forage; Corn, field, stover; Corn, sweet, forag e; Corn, sweet, stover 6

Corn, field, grain 0.1

Corn, sweet, kernel plus cob with husks removed 0.1

Cotton, gin byproducts 4

Cotton, undelinted seed 0.1

Dillweed 0.5

Egg 0.02

Goat, fat; Goat, meat 0.02

Goat, kidney 0.2

Goat, liver 0.05

Goat, meat byproducts, except kidney and liver 0.04

Grass, forage 10

Grass, hay 0.2

Horse, fat; Horse, meat 0.02S

- Metola chlor Dietary Exposure and Risk Assessment DP # D396451



### Page 4 of 27 Table 1. Metolachlor Tolerances

Commodity To lerance ( ppm )

Horse, kidney 0.2

Horse, liver 0.05

Horse, meat byproducts, except kidney and liver 0.04

Milk 0.02

Nut, tree, group 14 0.1

Okra 0.5

Peanut 0.2

Peanut, hay 20

Peanut, meal 0.4

Potato 0.2

Poultry, fat; Poultry, meat 0.02

Poultry, meat byproducts 0.05

Safflower, seed 0.1

Sheep, fat; Sheep, meat 0.02

Sheep, kidney 0.2

Sheep, liver 0.05

Sheep, meat byproducts, except kidney and liver 0.04

S orghum, grain, forage 1

Sorghum, grain, grain 0.3

Sorghum, grain, stover 4

Soybean, forage 5

Soybean, hay 8

Soybean, seed 0.2

Tomato 0.1

Vegetable, foliage of legume, subgroup 7A, except soybean 15

Vegetable, legume, group 6 0.3

Table 2. S

- metola chlor Tolerances

Commodity Tolerance ( ppm )

Asparagus 0.1

Beet, sugar, molasses 2

Beet, sugar, roots 0.5

Beet, sugar, tops 15

Brassica, head and stem, subgroup 5A 0.6

Bushberry subgroup 13

- 07B 0.15

Caneberry, Subgroup 13

- 07A 0.1

Carrot 0.40

Cattl e, fat; Cattle, meat 0.02

Cattle, kidney 0.2

Cattle, liver 0.05

Cattle, meat byproducts, except kidney and liver 0.04

Corn, field, grain 0.1

Corn, field, forage; Corn, field, stover; Corn, pop, stover; Corn, sweet, forage; Corn, sweet,

stover 6

Corn, pop, grain 0.1

Corn, sweet, kernel plus cob with husks removed 0.1

Cotton, gin byproducts 4

Cotton, undelinted seed 0.1S

- Metola chlor Dietary Exposure and Risk Assessment DP # D396451



### Page 5 of 27 Table 2. S

- metola chlor Tolerances

Commodity Tolerance ( ppm )

Cucumber 0.1 3

Egg 0.02

Garlic, bulb 0.1

Grain, aspirated fractions 0.7

Goat, fat; Goat, meat 0.02

Goat, kidney 0.2

Goat, live r 0.05

Goat, meat byproducts, except kidney and liver 0.04

Grass, forage 10

Grass, hay 0.2

Horse, fat; Horse, meat 0.02

Horse, kidney 0.2

Horse, liver 0.05

Horse, meat byproducts, except kidney and liver 0.04

Leafy Brassica Greens, Subgroup 5

- B 1.8

Leaf petioles, subgroup 4B 0.1

Lettuce, leaf 0.5

Milk 0.02

Melon subgroup 9A 0.1

Okra 0.10

Onion, Bulb, Subgroup 3

- 07A 0.1

Onion, Green, Subgroup 3

- 07B 2

Peanut 0.2

Peanut, hay 20

Peanut, meal 0.4

Pepper, non

- bell 0.50

Pepper, tobasco 0.50

Po ultry, fat; Poultry, meat 0.02

Poultry, meat byproducts 0.05

Pumpkin 0.1

Safflower, seed 0.1

Sesame, seed 0.1 3

Shallot, bulb 0.1

Sheep, fat; Sheep, meat 0.02

Sheep, kidney 0.2

Sheep, liver 0.05

Sheep, meat byproducts, except kidney and liver 0.04

Sorghum, grain, forage 1

Sorghum, grain, grain 0.3

Sorghum, grain, stover 4

Sorghum, sweet stalk 4

Soybean, forage 5

Soybean, hay 8

Soybean, seed 0.2

Spinach 0.5

Squash, winter 0.1

Sunflower, seed 0.5

Sunflower, meal 1

Tomato, paste 0.3S

- Metola chlor Dietary Exposure and Risk Assessment DP # D396451



### Page 6 of 27 Table 2. S

- metola chlor Tolerances

Commodity Tolerance ( ppm )

Turnip Greens 1.8

Vegetable, foliage of legume, except soybean, subgroup 7A 15

Vegetable, fruiting, group 8, except tabasco pepper 0.1

Vegetable, legume, group 6 0.3

Vegetable, root, except sugar beet, subgroup 1B 0.3

Vegetable, tuberous and corm, subgroup 1C 0.2

Table 3. Metolachlor Inadvertent Tolerances

Commodities Tolerance (ppm)

Animal feed, nongrass, group 18 1.0

Barley, grain 0.10

Barley, hay 0.80

Barley, straw 0.80

Buckwheat, grain 0.10

Millet, forage 0.50

Millet, grain 0.10

Millet, hay 0. 80

Millet, straw 0.80

Oat, forage 0.50

Oat, grain 0.10

Oat, hay 0.80

Oat, straw 0.80

Rice, grain 0.10

Rye, forage 0.50

Rye, grain 0.10

Rye, straw 0.80

Wheat, forage 0.50

Wheat, grain 0.10

Wheat, hay 0.80

Wheat, straw 0.80

Table 4. S

- metolach lor Inadvertent Tolerances

Commodity Tolerance (ppm)

Animal feed, nongrass, group 18 1.0

Barley, grain 0.10

Barley, hay 0.50

Barley, straw 0.50

Buckwheat, grain 0.10

Millet, forage 0.50

Millet, grain 0.10

Millet, hay 0.50

Millet, straw 0.50

Oat, forage 0.50

Oat, grain 0.10

Oat, hay 0.50

Oat, straw 0.50

Rice, grain 0.10

Rye, forage 0.50S

- Metola chlor Dietary Exposure and Risk Assessment DP # D396451



### Page 7 of 27 Table 4. S

- metolach lor Inadvertent Tolerances

Commodity Tolerance (ppm)

Rye, grain 0.10

Rye, straw 0.50

Wheat, forage 0.50

Wheat, grain 0.10

Wheat, hay 0.50

Wheat, straw 0.50



### In addition, ARIA is also recommending toleranc es of 8.0 ppm on fresh or dried cilantro leaves,

0.13 ppm on coriander seed, and 1.8 ppm on leaves of garden beet as a result of the present

Section 3 request.

III. Water Data

The Environmental Fate and Effects Division (EFED) calculated conservative, Ti er I Estimated

Drinking Water Concentrations (EDWCs) of metolachlor and S

- metolachlor in ground water and

surface water for use in the human health risk assessment (D 368735, C. Koper, 4/22/10 )

. EDWCs for metolachlor and S

- metolachlor were calculated for b oth the parent compound and

the ethanesulfonic acid (ESA) and oxanilic acid (OA) degradates. Although it was determined

by the MARC that the ESA and OA metabolites appear to be less toxic than parent metolachlor,

they are included in the risk assessment s ince they were found in greater abundance than the

parent in water monitoring studies.

This drinking water assessment was conducted on the parent S

- metolachlor and its major

degradates ethanesulfonic acid (ESA) and oxanilic acid (OA) as a result of the use on turf

. T he

environmental fate data has been bridged from the racemic mixture (50:50) of metolachlor to the

newer isomer (88:12) S

- metolachlor , based on similarities in environmental fate behavior. Tier I

and Tier II screening models were employed f or this assessment. For surface water,

PRZM/EXAMS (PE5) and FIRST ( F QPA I ndex R eservoir S creening T ool) Version1.1.1 models

were used to estimate drinking water concentrations for the parent S

- metolachlor and the ESA

and OA degradates, respectively. The SCI

- GROW model ( Screening Concentration in Ground

Water Program Version 2.3) was used to predict the maximum acute and chronic concentrations

present in shallow groundwater. In addition, s ince the previous EDWCs for surface water for the

parent S

- metolach lor were based on NAWQA monitoring data, a search of the available

monitoring data was performed on March 30, 2010 to ensure that the most current monitoring

data were considered in this assessment. The data set captured the timeframe of October 1991 to

O ctober 2009 and included the parent S

- metolachlor and its degradates ESA and OA. Based on

a review of the current monitoring data, concentrations of parent S

- metolachlor and its

degradates were less than values reported from the previous monitoring data ( US EPA, 2002).

Therefore, EDWCs based on previous monitoring are still valid. The recommended total EEC’s

for peak and average surface water respectively are 219 pp b ( 78 pp b parent + 48 pp b ESA+ 94

pp b OA) and 119 pp b ( 18 pp b parent + 34 pp b ESA+ 34 pp b OA) . Recommended groundwater

EECs (peak and average) are 126 ppb ( 33 pp b parent + 64 pp b ESA+ 30 OA)

. A summary of

recommended surface and groundwater EDWCs for the human dietary risk assessment for theS

- Metola chlor Dietary Exposure and Risk Assessment DP # D396451



### Page 8 of 27 parent S

- metolachlor and its degradates ESA and OA are presented in Table 5

.

Table 5. Recommended Drinking Water Concentrations (EDWCs) and Source for Surface Water and Groundwater for

Human Dietary Health Risk Assessment

Chemical Identity Acute (μg/L) Average (μg/L) Cancer Chronic (μg/L)

Surface Wat er

S

- metolachlor (parent) 77.60 (monitoring data) 18.15CA (cole crop) 9.15 (KS sorghum)

Ethanesulfonic Acid (ESA) 47.61(caneberry) 34.04 (caneberry) 34.04 (caneberry)

Oxanilic Acid (OA) 93.57 (caneberry) 66.62 (caneberry) 66.62 (caneberry)

Total 218.78 118.81 109.81

Groundwater

S

- metolachlor (parent) 32.8 (monitoring data) 32.8 (monitoring data) 32.8 (monitoring data)

Ethanesulfonic Acid (ESA) 63.7 (monitoring data) 63.7 (monitoring data) 63.7 (monitoring data)

Oxanilic Acid (OA) 29.7 ( caneberry) 29.7 (caneberry) 29.7 (caneberry)

Total 126.2 126.2 126.2



### IV. DEEM

- FCIDTM Program and Consumption Information

S

- metolachlor acute and chronic dietary exposure assessments were conducted using the Dietary

Exposure Evaluation Model software wi th the Food Commodity Intake Database (DEEM

FCIDTM, Version 2. 10 ), which incorporates consumption data from USDA’s Continuing Surveys

of Food Intakes by Individuals (CSFII), 1994

- 1996 and 1998. The 1994

- 96, 98 data are based on

the reported consumption of more than 20,000 individuals over two non

- consecutive survey

days. Foods “as consumed” (e.g., apple pie) are linked to EPA

- defined food commodities (e.g.

apples, peeled fruit

- cooked; fresh or N/S; baked; or wheat flour

- cooked; fresh or N/S, baked)

usi ng publicly available recipe translation files developed jointly by USDA/ARS and EPA. For

chronic exposure assessment, consumption data are averaged for the entire U.S. population and

within population subgroups, but for acute exposure assessment are reta ined as individual

consumption events. Based on analysis of the 1994

- 96, 98 CSFII consumption data, which took

into account dietary patterns and survey respondents, HED concluded that it is most appropriate

to report risk for the following population subg roups: the general U.S. population, all infants (<1

year old), children 1

- 2, children 3

- 5, children 6

- 12, youth 13

- 19, adults 20

- 49, females 13

- 49,

and adults 50+ years old.

For chronic dietary exposure assessment, an estimate of the residue level in each food or food

form (e.g., orange or orange juice) on the food commodity residue list is multiplied by the

average daily consumption estimate for that food/food form. The resulting residue consumption

estimate for each food/food form is summed with the res idue consumption estimates for all other

food/food forms on the commodity residue list to arrive at the total average estimated exposure.

Exposure is expressed in mg/kg body weight/day and as a percent of the cPAD. This procedure

is performed for each po pulation subgroup.S

- Metola chlor Dietary Exposure and Risk Assessment DP # D396451



### Page 9 of 27 For acute exposure assessments, individual one

- day food consumption data are used on an

individual

- by

- individual basis. The reported consumption amounts of each food item can be

multiplied by a residue point estimate and summed to obta in a total daily pesticide exposure for a

deterministic exposure assessment, or “matched” in multiple random pairings with residue values

and then summed in a probabilistic assessment. The resulting distribution of exposures is

expressed as a percentage o f the aPAD on both a user (i.e., those who reported eating relevant

commodities/food forms) and a per

- capita (i.e., those who reported eating the relevant

commodities as well as those who did not) basis. In accordance with HED policy, per capita

exposure and risk are reported for all tiers of analysis. However significant differences in user

vs. per capita exposure and risk are identified and noted in the risk assessment.

V. Toxicological Information

HED evaluated the toxicology data base for S

- metolach lor and selected the following doses and

endpoints for acute and chronic dietary and drinking water risk assessments.

Table 6 . Summary of Toxicological Endpoints for S

- metolachlor for Use in Dietary Human Health Risk

Assessments

Exposure

Scenario Poin t of

Departure Uncertainty/FQP

A Safety Factors RfD, PAD,

LOC for Risk

Assessment Study and Toxicological Effects

Acute Dietary

( g eneral

p opulation) NOAEL =

300

mg/kg/day UFA= 10x

UFH=10x

FQPA SF= 1x Acute RfD = 3.0

mg/kg/day

aPAD = 3.0

mg/kg/day Develop mental Toxicity Study

- Rat

LOAEL = 1000 mg/kg/day based on increased

incidence of death, clinical signs (clonic and/or

tonic convulsions, excessive salivation, urine

stained abdominal fur and/or excessive

lacrimation) and decreased body weight gain.

Chronic

Dietary

( a ll

p opulations) NOAEL =

9.7

mg/kg/day UFA= 10x

UFH=10x

FQPA SF= 1x Chronic RfD =

0. 0 97

mg/kg/day

cPAD =

0. 0 97mg/kg/day Chronic Toxicity

- Dog;

LOAEL = 33 mg/kg/day based decreased body

weight gain in females

Cancer

(all routes) Metol achlor has been classified as a Group C carcinogen with risk quantitated using a non

- linear (Margin

of Exposure) approach.

Point of Departure (POD) = A data point or an estimated point that is derived from observed dose

- response data and used to mark t he beginning

of extrapolation to determine risk associated with lower environmentally relevant human exposures. NOAEL = no observed adver se effect level.

NOAEL = no observed adverse effect level.

LOAEL = lowest observed adverse effect level.

UF = un certainty factor. UF A = extrapolation from animal to human (interspecies). UF H = potential variation in sensitivity among members of

the human population (intraspecies).

FQPA SF = FQPA Safety Factor.

PAD = population adjusted dose (a = acute, c = chr onic).

RfD = reference dose.



### VI. Results/Discussion

As stated above, for acute and chronic assessments, HED is concerned when dietary risk exceeds

100% of the PAD. The DEEM

- FCIDTM analyses estimate the dietary exposure of the U.S.

population and various population subgroups. The results reported in Tables 7 and 8 are for the

general U.S. Population, all infants (<1 year old), children 1

- 2, children 3

- 5, children 6

- 12, youthS

- Metola chlor Dietary Exposure and Risk Assessment DP # D396451



### Page 10 of 27 13

- 19, females 13

- 49, adults 20

- 49, and adults 50+ years.

Results of Acute Dietary Exposure Analysis

Table 7 : Summary of Acute Diet ary Exposure and Risk for S

- metolachlor and Metolachlor

Population Subgroup aPAD (mg/kg/day) Acute (95th Percentile)

Exposure (mg/kg/day) %aPAD

General U.S. Population

3.0 0.014 688 <1 .0

All Infants (< 1 year old) 0.04 6244 1.5

Children 1

- 2 years old 0.02 5061 <1 .0

Children 3

- 5 years old 0.022 362 <1 .0

Children 6

- 12 years old 0. 015 532 <1.0

Youth 13

- 19 years old 0.011 553 <1.0

Adults 20

- 49 years old 0.012 6 90 <1.0

Adults 50+ years old 0.0114 71 <1.0

Females 13

- 49 years old 0.012 602 <1.0



### Resul ts of Chronic Dietary Exposure Analysis

Table 8 : Summary of Chronic Dietary Exposure and Risk for S

- metolachlor and Metolachlor

Population Subgroup cPAD (mg/kg/day) Chronic

Exposure (mg/kg/day) %cPAD

General U.S. Population

0. 1 0.004 550 4.5

All In fants (< 1 year old) 0.011 574 11. 6

Children 1

- 2 years old 0.008 666 8. 7

Children 3

- 5 years old 0.007 852 7. 9

Children 6

- 12 years old 0.005 372 5. 4

Youth 13

- 19 years old 0.0036 98 3.7

Adults 20

- 49 years old 0.0039 94 4 .0

Adults 50+ years old 0.00 401 7 4 .0

Females 13

- 49 years old 0.003 929 3.9



### VI. Characterization of Inputs/Outputs

The acute and chronic dietary analys e s are very conservative. T olerance level residues used in

the analysis are expected to exceed the residues actually consumed. In a ddition, the 100% crop

treated estimate used for all crops in the assessment will considerably overestimate the actual

percent crop treated.

VII. Conclusions

Based on analyses of estimated dietary risks for the general U.S. population and various

popul ation subgroups, the acute and chronic dietary exposure estimates for S

- metolachlor are significantly below HED’s level of concern for all supported commodities (Tables 7 and 8 ). The

95th percentile acute dietary exposure estimate for the highest exposed population subgroup, all

infants < 1 year old is 1.5 % of the aPAD. The chronic dietary exposure estimate for the highest

exposed population subgroup, all infants < 1 year old is 1 1

. 6 % of the cPAD.S

- Metola chlor Dietary Exposure and Risk Assessment DP # D396451



### Page 11 of 27 VIII. List of Attachments

1. Acute DEEM

- FCID Residue In put File.

2. Results of Acute DEEM

- FCID Dietary Exposure Analysis.

3. Chronic DEEM

- FCID Residue Input File.

4. Results of Chronic DEEM

- FCID Dietary Exposure Analysis.S

- Metola chlor Dietary Exposure and Risk Assessment DP # D396451



### Page 12 of 27 Attachment 1 Acute DEEM

- FCID Residue Input File

Filename: F: \ telework \ s

- metolachlor2011 \ 108800a_rad.R98

Chemical: Metolachlor and S

- metolachlor

RfD(Chronic): .1 mg/kg bw/day NOEL(Chronic): 9.7 mg/kg bw/day

RfD(Acute): 3 mg/kg bw/day NOEL(Acute): 300 mg/kg bw/day

Date created/last modified: 12

- 12

- 2011/09:22:54/14 Program ver. 2.10

--------------------------------------------------------------------------------

EPA Crop Def Res Adj.Factors Comment

Code Grp Commodity Name (ppm) #1 #2

-------- ---- ------------------------------- ---------- ------ ------ -------

95000190 O Asparagus 0.100000 1.000 1.000

95001280 O Cottonseed, oil 0.100000 1.000 1.000

95001281 O Cottonseed, oil

- babyfood 0.100000 1.000 1.000

95002630 O Peanut 0.200000 1.000 1.000

95002640 O Peanut, butter 0.200000 1.890 1.000

95002650 O Peanut, oil 0.200000 1.000 1.000

95003360 O Sesame, seed 0.130000 1.000 1.000 PP#6E7

Full comment: PP#6E7607

95003361 O Sesame, seed

- babyfood 0.130000 1.000 1.000 PP#6E7

Ful l comment: PP#6E7607

95003370 O Sesame, oil 0.130000 1.000 1.000 PP#6E7

Full comment: PP#6E7607

95003371 O Sesame, oil

- babyfood 0.130000 1.000 1.000 PP#6E7

Full comment: PP#6E7607

86010 000 O Water, direct, all sources 0.219000 1.000 1.000

86020000 O Water, indirect, all sources 0.219000 1.000 1.000

21000440 M Beef, meat 0.020000 1.000 1.000

21000441 M Beef, meat

- babyfood 0.020000 1.000 1.000

21000450 M Beef, meat, dried 0.020000 1.920 1.000

21000460 M Beef, meat byproducts 0.040000 1.000 1.000

21000461 M Beef, meat byproducts

- babyfood 0.040000 1.000 1.000

21000470 M Beef, fat 0.020000 1.000 1.000

21000471 M Beef,fat

- babyfood 0.020000 1.000 1.000

21000480 M Beef, kidney 0.200000 1.000 1.000

21000490 M Beef, liv er 0.050000 1.000 1.000

21000491 M Beef, liver

- babyfood 0.050000 1.000 1.000

23001690 M Goat, meat 0.020000 1.000 1.000

23001700 M Goat, meat byproducts 0.040 000 1.000 1.000

23001710 M Goat, fat 0.020000 1.000 1.000

23001720 M Goat, kidney 0.200000 1.000 1.000

23001730 M Goat, liver 0.050000 1.000 1.000

24001890 M Horse, meat 0.020000 1.000 1.000

26003390 M Sheep, meat 0.020000 1.000 1.000

26003391 M Sheep, meat

- babyfood 0.020000 1.000 1.000

26003400 M Sheep, meat byproducts 0.040000 1.000 1.000

26003410 M Sheep, fat 0.020000 1.000 1.000

26003411 M Sheep, fat

- babyfood 0.020000 1.000 1.000

26003420 M Sheep, kidney 0.200000 1.000 1.000

26003430 M Sheep, liver 0.050000 1.000 1.000

40000930 P Chicken, meat 0.020000 1.000 1.000

40000931 P Chicken, meat

- babyfood 0.020000 1.000 1.000

40000940 P Chicken, liver 0.050000 1.000 1.000

40000950 P Chicken, meat byproducts 0.050000 1.000 1.000

40000951 P Chicken, meat byproducts

- babyfoo 0.050000 1.000 1.000

40000960 P Chicken, fat 0.020000 1.000 1.000

40000961 P Chicken, fat

- babyfood 0.020000 1.000 1.000

40000970 P Chicken, skin 0.050000 1.000 1.000

40000971 P Chicken, skin

- babyfood 0.050000 1.000 1.000

70001450 P E gg, whole 0.020000 1.000 1.000

70001451 P Egg, whole

- babyfood 0.020000 1.000 1.000

70001460 P Egg, white 0.020000 1.000 1.000S

- Metola chlor Dietary Exposure and Risk Assessment DP # D396451



### Page 13 of 27 70001461 P Egg, white (solids)

- babyfood 0.020000 1.000 1.000

70001470 P Egg, yolk 0.020000 1.000 1.000

70001471 P Egg, yolk

- babyfood 0.020000 1.000 1.000

60003010 P Poultry, other, meat 0.020000 1.000 1.000

60 003020 P Poultry, other, liver 0.050000 1.000 1.000

60003030 P Poultry, other, meat byproducts 0.050000 1.000 1.000

60003040 P Poultry, other, fat 0.020000 1.000 1.000

60003050 P Poultry, other, ski n 0.050000 1.000 1.000

50003820 P Turkey, meat 0.020000 1.000 1.000

50003821 P Turkey, meat

- babyfood 0.020000 1.000 1.000

50003830 P Turkey, liver 0.050000 1.00 0 1.000

50003831 P Turkey, liver

- babyfood 0.050000 1.000 1.000

50003840 P Turkey, meat byproducts 0.050000 1.000 1.000

50003841 P Turkey, meat byproducts

- babyfood 0.050000 1.000 1.000

50003850 P Turkey , fat 0.020000 1.000 1.000

50003851 P Turkey, fat

- babyfood 0.020000 1.000 1.000

50003860 P Turkey, skin 0.050000 1.000 1.000

50003861 P Turkey, skin

- babyfood 0. 050000 1.000 1.000

27002220 D Milk, fat 0.020000 1.000 1.000

27002221 D Milk, fat

- baby food/infant for 0.020000 1.000 1.000

27012230 D Milk, nonfat solids 0.020000 1.000 1.000

2701223 1 D Milk, nonfat solids

- baby food/in 0.020000 1.000 1.000

27022240 D Milk, water 0.020000 1.000 1.000

27022241 D Milk, water

- babyfood/infant form 0.020000 1.000 1.000

27032251 D Milk, sugar (lactose)

- ba by food/ 0.020000 1.000 1.000

01030150 1CD Arrowroot, flour 0.200000 1.000 1.000

01030151 1CD Arrowroot, flour

- babyfood 0.200000 1.000 1.000

01030170 1CD Artichoke, Jerusalem 0.200000 1.000 1. 000

01010500 1AB Beet, garden, roots 0.300000 1.000 1.000

01010501 1AB Beet, garden, roots

- babyfood 0.300000 1.000 1.000

01010520 1A Beet, sugar 0.500000 1.000 1.000

01010521 1A Beet, sugar

- babyfood 0.500000 1.000 1.000

01010530 1A Beet, sugar, molasses 2.000000 1.000 1.000

01010531 1A Beet, sugar, molasses

- babyfood 2.000000 1.000 1.000

01010670 1AB Burdock 0.30000 0 1.000 1.000

01010780 1AB Carrot 0.400000 1.000 1.000 PP#9E7

Full comment: PP#9E7607

01010781 1AB Carrot

- babyfood 0.400000 1.000 1.000 PP#9E7

Full comment: PP#9E7607

0101079 0 1AB Carrot, juice 0.400000 1.000 1.000 PP#9E7

Full comment: PP#9E7607

01030820 1CD Cassava 0.200000 1.000 1.000

01030821 1CD Cassava

- babyfood 0.200000 1.000 1.000

01010840 1AB Celeriac 0.300000 1.000 1.000

01011000 1AB Chicory, roots 0.300000 1.000 1.000

01031390 1CD Dasheen, corm 0.200000 1.000 1.000

01031660 1CD Ginger 0.200000 1.000 1.000

01031661 1CD Ginger

- babyfood 0.200000 1.000 1.000

01031670 1CD Ginger, dried 0.200000 1.000 1.000

01011680 1AB Ginseng, dried 0.300000 1.000 1.000

01011900 1AB Horseradish 0.300000 1.000 1.000

01012500 1AB Parsley, turnip rooted 0.300000 1.000 1.000

01012510 1AB Parsnip 0.300000 1.000 1.000

01012511 1AB Pa rsnip

- babyfood 0.300000 1.000 1.000

01032960 1C Potato, chips 0.200000 1.000 1.000

01032970 1C Potato, dry (granules/ flakes) 0.200000 6.500 1.000

01032971 1C Potato, dry (granules/ flakes)

- b 0.200000 6.500 1.000

01032980 1C Potato, flour 0.200000 6.500 1.000

01032981 1C Potato, flour

- babyfood 0.200000 1.000 1.000

01032990 1C Potato, tuber, w/peel 0.200000 1.000 1.000

010 32991 1C Potato, tuber, w/peel

- babyfood 0.200000 1.000 1.000

01033000 1C Potato, tuber, w/o peel 0.200000 1.000 1.000

01033001 1C Potato, tuber, w/o peel

- babyfood 0.200000 1.000 1.000S

- Metola chlor Dietary Exposure and Risk Assessment DP # D396451



### Page 14 of 27 01013140 1AB Radish, roots 0.300000 1.000 1.000

01013160 1AB Radish, Oriental, roots 0.300000 1.000 1.000

01013270 1AB Rutabaga 0.300000 1.000 1.000

01013310 1AB Salsify, roots 0.300000 1.000 1.000

01033660 1CD Sweet potato 0.200000 1.000 1.000

01033661 1CD Sweet potato

- babyfood 0.200000 1.000 1.000

01033710 1CD Tanier, corm 0.200000 1.000 1.000

01033870 1CD Turmeri c 0.200000 1.000 1.000

01013880 1AB Turnip, roots 0.300000 1.000 1.000

01034060 1CD Yam, true 0.200000 1.000 1.000

01034070 1CD Yam bean 0.2 00000 1.000 1.000

02000510 2 Beet, garden, tops 1.800000 1.000 1.000 1E7898

03001640 3 Garlic 0.100000 1.000 1.000

03001650 3 Garlic, dried 0.100000 9.000 1.000

03 001651 3 Garlic, dried

- babyfood 0.100000 9.000 1.000

03001980 3 Leek 2.000000 1.000 1.000

03002370 3 Onion, dry bulb 0.100000 1.000 1.000 PP#9E7

Full comment: PP# 9E7607

03002371 3 Onion, dry bulb

- babyfood 0.100000 1.000 1.000 PP#9E7

Full comment: PP#9E7607

03002380 3 Onion, dry bulb, dried 0.100000 9.000 1.000 PP#9E7

Full comment: PP#9E7607

03002381 3 Onion , dry bulb, dried

- babyfood 0.100000 9.000 1.000 PP#9E7

Full comment: PP#9E7607

03002390 3 Onion, green 2.000000 1.000 1.000 PP#9E7

Full comment: PP#9E7607

03003380 3 Shallot 2.000000 1.000 1.000

04020760 4B Cardoon 0.100000 1.000 1.000

04020850 4B Celery 0.100000 1.000 1.000

04020851 4B Celery

- babyfood 0.100000 1.000 1.000

0 4020860 4B Celery, juice 0.100000 1.000 1.000

04020870 4B Celtuce 0.100000 1.000 1.000

04021520 4B Fennel, Florence 0.100000 1.000 1.000

04012050 4A Lettuce, leaf 0.500000 1.000 1.000

04023220 4B Rhubarb 0.100000 1.000 1.000

04013550 4A Spinach 0.500000 1.000 1.000

04013551 4A Spinach

- babyfood 0.500000 1.0 00 1.000

04023670 4B Swiss chard 0.100000 1.000 1.000

05010610 5A Broccoli 0.600000 1.000 1.000

05010611 5A Broccoli

- babyfood 0.600000 1.000 1.000

05010620 5A Brocc oli, Chinese 0.600000 1.000 1.000

05020630 5B Broccoli raab 1.800000 1.000 1.000 PP#6E7

Full comment: PP#6E7607

05010640 5A Brussels sprouts 0.600000 1.000 1.000

05010690 5 A Cabbage 0.600000 1.000 1.000

05020700 5B Cabbage, Chinese, bok choy 1.800000 1.000 1.000 PP#6E7

Full comment: PP#6E7607

05010710 5A Cabbage, Chinese, napa 0.600000 1.000 1.000

0 5010720 5A Cabbage, Chinese, mustard 0.600000 1.000 1.000

05010830 5A Cauliflower 0.600000 1.000 1.000

05021170 5B Collards 1.800000 1.000 1.000 PP#6E7

Full comment: PP #6E7607

05021940 5B Kale 1.800000 1.000 1.000 PP#6E7

Full comment: PP#6E7607

05011960 5A Kohlrabi 0.600000 1.000 1.000

05022290 5B Mustard greens 1.800000 1.000 1.000 PP#9E7

Full comment: PP#9E7607

05023180 5B Rape greens 1.800000 1.000 1.000 PP#9E7

Full comment: PP#9E7607

05023890 5B Turnip, greens 1.800000 1.000 1.000 PP#9E7

Full comment: PP#9E7607

06030300 6C Bean, black, seed 0.300000 1.000 1.000

06020310 6B Bean, broad, succulent 0.300000 1.000 1.000 AdditiS

- Metola chlor Dietary Exposure and Risk Assessment DP # D396451



### Page 15 of 27 Full comment: Additional data required.

06030320 6C Bean, broad, seed 0.300000 1.000 1.000

06020330 6B Bean, cowpea, succulent 0.300000 1.000 1.000 Additi

Full comment: Additional data required.

06030340 6C Bean, cowpea, seed 0.300000 1.000 1. 000

06030350 6C Bean, great northern, seed 0.300000 1.000 1.000

06030360 6C Bean, kidney, seed 0.300000 1.000 1.000

06020370 6B Bean, lima, succulent 0.300000 1.000 1.000 Additi

Full comm ent: Additional data required.

06030380 6C Bean, lima, seed 0.300000 1.000 1.000

06030390 6C Bean, mung, seed 0.300000 1.000 1.000

06030400 6C Bean, navy, seed 0.300000 1.000 1.000

06030410 6C Bean, pink, seed 0.300000 1.000 1.000

06030420 6C Bean, pinto, seed 0.300000 1.000 1.000

06010430 6A Bean, snap, succulent 0.300000 1.000 1.000 Additi

Full comment: A dditional data required.

06010431 6A Bean, snap, succulent

- babyfood 0.300000 1.000 1.000 Additi

Full comment: Additional data required.

06030980 6C Chickpea, seed 0.300000 1.000 1.000

06030981 6C Chickpea, s eed

- babyfood 0.300000 1.000 1.000

06030990 6C Chickpea, flour 0.300000 1.000 1.000

06031820 6C Guar, seed 0.300000 1.000 1.000

06031821 6C Guar, seed

- babyfood 0.30000 0 1.000 1.000

06032030 6C Lentil, seed 0.300000 1.000 1.000

06022550 6B Pea, succulent 0.300000 1.000 1.000 Additi

Full comment: Additional data required.

06022551 6B Pea, succulent

- ba byfood 0.300000 1.000 1.000 Additi

Full comment: Additional data required.

06032560 6C Pea, dry 0.300000 1.000 1.000

06032561 6C Pea, dry

- babyfood 0.300000 1.000 1.000

060125 70 6A Pea, edible podded, succulent 0.300000 1.000 1.000 Additi

Full comment: Additional data required.

06032580 6C Pea, pigeon, seed 0.300000 1.000 1.000

06022590 6B Pea, pigeon, succulent 0.30000 0 1.000 1.000 Additi

Full comment: Additional data required.

06003470 6 Soybean, seed 0.300000 1.000 1.000

06003480 6 Soybean, flour 0.300000 1.000 1.000

06003481 6 Soybean, flour

- ba byfood 0.300000 1.000 1.000

06003490 6 Soybean, soy milk 0.300000 1.000 1.000

06003491 6 Soybean, soy milk

- babyfood or in 0.300000 1.000 1.000

06003500 6 Soybean, oil 0.300000 1. 000 1.000

06003501 6 Soybean, oil

- babyfood 0.300000 1.000 1.000

08001480 8 Eggplant 0.100000 1.000 1.000

08002340 8 Okra 0.500000 1.000 1.000 PP#6E7

Fu ll comment: PP#6E7607

08002700 8 Pepper, bell 0.100000 1.000 1.000

08002701 8 Pepper, bell

- babyfood 0.100000 1.000 1.000

08002710 8 Pepper, bell, dried 0.100000 1.000 1.000

08002711 8 Pepper, bell, dried

- babyfood 0.100000 1.000 1.000

08002720 8 Pepper, nonbell 0.500000 1.000 1.000 Tabasc

Full comment: Tabasco peppers @ 0.5 ppm

08002721 8 Pepper, nonbell

- babyfood 0.500000 1.000 1.000 Tabasc

Full comment: Tabasco peppers @ 0.5 ppm

08002730 8 Pepper, nonbell, dried 0.500000 1.000 1.000 Tabasc

Full comment: Tabasco peppers @ 0.5 ppm

08003740 8 Tomatillo 0.10 0000 1.000 1.000

08003750 8 Tomato 0.100000 1.000 1.000

08003751 8 Tomato

- babyfood 0.100000 1.000 1.000

08003760 8 Tomato, paste 0.300000 5.400 1.000

08003761 8 Tomato, paste

- babyfood 0.300000 5.400 1.000

08003770 8 Tomato, puree 0.100000 3.300 1.000

08003771 8 Tomato, puree

- babyfood 0.100000 3.300 1.000

08003780 8 Tomato, dried 0.100000 14.300 1.000S

- Metola chlor Dietary Exposure and Risk Assessment DP # D396451



### Page 16 of 27 08003781 8 Tomato, dried

- babyfood 0.100000 14.300 1.000

08003790 8 Tomato, juice 0.100000 1.500 1.000

09010750 9A Cantaloupe 0.100000 1.000 1.00 0 PP#6E7

Full comment: PP#6E7607

09010800 9A Casaba 0.100000 1.000 1.000 PP#6E7

Full comment: PP#6E7607

09021350 9B Cucumber 0.130000 1.000 1.000 PP#6E7

Full c omment: PP#6E7607

09011870 9A Honeydew melon 0.100000 1.000 1.000 PP#6E7

Full comment: PP#6E7607

09023080 9B Pumpkin 0.100000 1.000 1.000

09023090 9B Pumpkin, seed 0.100000 1.000 1.000

09023570 9B Squash, winter 0.100000 1.000 1.000

09023571 9B Squash, winter

- babyfood 0.100000 1.000 1.000

09013990 9A Watermelon 0.100000 1.000 1.000 PP#6E 7

Full comment: PP#6E7607

09014000 9A Watermelon, juice 0.100000 1.000 1.000 PP#6E7

Full comment: PP#6E7607

13010550 13A Blackberry 0.100000 1.000 1.000 PP#6E7

Full comment: PP#6E7607

13010560 13A Blackberry, juice 0.100000 1.000 1.000 PP#6E7

Full comment: PP#6E7607

13010561 13A Blackberry, juice

- babyfood

240

- Cooked; Canned; Cook Meth N/S

0.100000 1.000 1.000 PP#6E7

Full comment: PP#6E7607

13020570 13B Blueberry 0.150000 1.000 1.000 PP#6E7

Full comment: PP#6E7607

13020571 13B Blueberry

- babyfood 0.150000 1.000 1.000 PP#6E7

Full comment: PP#6E7607

13010580 13A Boysenberry 0.100000 1.000 1.000 PP#6E7

Full comment: PP#6E7607

13021360 13B Currant 0.150000 1.000 1.000 PP#6E7

Full comment: PP#6E7607

13021370 13B Currant, dried 0.150000 1.000 1.000 PP#6E7

Full comment: PP#6E7607

13011420 13A Dewberry 0.100000 1.000 1.000 PP#6E7

Full comment: PP#6E7607

13 021490 13B Elderberry 0.150000 1.000 1.000 PP#6E7

Full comment: PP#6E7607

13021740 13B Gooseberry 0.150000 1.000 1.000 PP#6E7

Full comment: PP#6E7607

13021910 13B Huckleberry 0.150000 1.000 1.000 PP#6E7

Full comment: PP#6E7607

13012080 13A Loganberry 0.100000 1.000 1.000 PP#6E7

Full comment: PP#6E7607

13013200 13A Raspberry 0.100 000 1.000 1.000 PP#6E7

Full comment: PP#6E7607

13013201 13A Raspberry

- babyfood 0.100000 1.000 1.000 PP#6E7

Full comment: PP#6E7607

13013210 13A Raspberry, juice 0.100000 1.000 1.000 PP#6E7

Full comment: PP#6E7607

13013211 13A Raspberry, juice

- babyfood 0.100000 1.000 1.000 PP#6E7

Full comment: PP#6E7607

14000030 14 Almond 0.100000 1.000 1.000

14000031 14 Almond

- babyfood 0.100000 1.000 1.000

14000040 14 Almond, oil 0.100000 1.000 1.000

14000041 14 Almond, oil

- babyfood 0.100000 1.000 1.000

14000590 14 Brazil nut 0.100000 1. 000 1.000

14000680 14 Butternut 0.100000 1.000 1.000

14000810 14 Cashew 0.100000 1.000 1.000

14000920 14 Chestnut 0.100000 1.000 1.000

14001550 14 Filb ert 0.100000 1.000 1.000S

- Metola chlor Dietary Exposure and Risk Assessment DP # D396451



### Page 17 of 27 14001560 14 Filbert, oil 0.100000 1.000 1.000

14001850 14 Hickory nut 0.100000 1.000 1.000

14002130 14 Macadamia nut 0.100000 1.000 1.000

14002690 14 Pecan 0.100000 1.000 1.000

14002820 14 Pistachio 0.100000 1.000 1.000

14003910 14 Walnut 0.100000 1.000 1.000

15000 250 15 Barley, pearled barley 0.100000 1.000 1.000

15000251 15 Barley, pearled barley

- babyfood 0.100000 1.000 1.000

15000260 15 Barley, flour 0.100000 1.000 1.000

15000261 15 Barley, flour

- babyfood 0.100000 1.000 1.000

15000270 15 Barley, bran 0.100000 1.000 1.000

15000650 15 Buckwheat 0.100000 1.000 1.000 Additi

Full comment: Additional data required.

15000660 15 Buckwheat, flour 0.100000 1.000 1.000 Additi

Full comment: Additional data required.

15001200 15 Corn, field, flour 0.100000 1.000 1.000

15001201 15 Corn, field, flour

- babyfood 0.100000 1 .000 1.000

15001210 15 Corn, field, meal 0.100000 1.000 1.000

15001211 15 Corn, field, meal

- babyfood 0.100000 1.000 1.000

15001220 15 Corn, field, bran 0.100000 1.000 1.000

15001230 15 Cor n, field, starch 0.100000 1.000 1.000

15001231 15 Corn, field, starch

- babyfood 0.100000 1.000 1.000

15001240 15 Corn, field, syrup 0.100000 1.500 1.000

15001241 15 Corn, field, syrup

- babyfood 0.100000 1.500 1.000

15001250 15 Corn, field, oil 0.100000 1.000 1.000

15001251 15 Corn, field, oil

- babyfood 0.100000 1.000 1.000

15001260 15 Corn, pop 0.100000 1.000 1.000

1500 1270 15 Corn, sweet 0.100000 1.000 1.000

15001271 15 Corn, sweet

- babyfood 0.100000 1.000 1.000

15002260 15 Millet, grain 0.100000 1.000 1.000

15002310 15 Oat, bran 0.100000 1.000 1.000

15002320 15 Oat, flour 0.100000 1.000 1.000

15002321 15 Oat, flour

- babyfood 0.100000 1.000 1.000

15002330 15 Oat, groats/rolled oats 0.100000 1.000 1.000

15002331 15 Oat, groats/rolled oats

- babyfood 0.100000 1.000 1.000

15003230 15 Rice, white 0.100000 1.000 1.000

15003231 15 Rice, white

- babyfood 0.100000 1.000 1.000

15003240 15 Rice, br own 0.100000 1.000 1.000

15003241 15 Rice, brown

- babyfood 0.100000 1.000 1.000

15003250 15 Rice, flour 0.100000 1.000 1.000

15003251 15 Rice, flour

- babyfood 0.10 0000 1.000 1.000

15003260 15 Rice, bran 0.100000 1.000 1.000

15003261 15 Rice, bran

- babyfood 0.100000 1.000 1.000

15003280 15 Rye, grain 0.100000 1.000 1.000

15003290 15 Rye, flour 0.100000 1.000 1.000

15003440 15 Sorghum, grain 0.300000 1.000 1.000 PP#9E7

Full comment: PP#9E7607

15003450 15 Sorghum, syrup 4.000000 1.000 1.000 P P#9E7

Full comment: PP#9E7607

15003810 15 Triticale, flour 0.100000 1.000 1.000

15003811 15 Triticale, flour

- babyfood 0.100000 1.000 1.000

15004010 15 Wheat, grain 0.100000 1.000 1.000

15004011 15 Wheat, grain

- babyfood 0.100000 1.000 1.000

15004020 15 Wheat, flour 0.100000 1.000 1.000

15004021 15 Wheat, flour

- babyfood 0.100000 1.000 1.000

15004030 15 Wheat, g erm 0.100000 1.000 1.000

15004040 15 Wheat, bran 0.100000 1.000 1.000

15004050 15 Wild rice 0.100000 1.000 1.000

19011030 19A Chive 2.00 0000 1.000 1.000

19011180 19A Coriander, leaves 8.000000 1.000 1.000 1E7898

19011181 19A Coriander, leaves

- babyfood 8.000000 1.000 1.000 1E7898

19021190 19B Coriander, seed 0.130000 1.000 1.000 1E7898

19021191 19B Coriander, seed

- babyfood 0.130000 1.000 1.000 1E7898S

- Metola chlor Dietary Exposure and Risk Assessment DP # D396451



### Page 18 of 27 19011440 19A Dillweed 0.500000 1.000 1.000S

- Metola chlor Dietary Exposure and Risk Assessment DP # D396451



### Page 19 of 27 Attachment 2. Results of Acute DEEM

- FCID Dietary Exposure Analysis

California Department of Pesticide Regulation Ver. 2.10

DEEM

- FCID ACUTE Analysis for METOLACHLOR AND S

- METOLACHLOR (1994

- 98 data)

Residue file: 108800a_rad.R98 Adjustment factor #2 N OT used.

Analysis Date: 12

- 12

- 2011/10:27:42 Residue file dated: 12

- 12

- 2011/09:22:54/14

NOEL (Acute) = 300.000000 mg/kg body

- wt/day

Run Comment: ""

===============================================================================

Summary calculations

-- per capita:

--- 95th Percentile

---- --- 99th Percentile

---- --- 99.9th Percentile

----

Exposure % aRfD MOE Exposure % aRfD MOE Exposure % aRfD MOE

---------- ------- -------- ---------- ------- -------- ---------- ------- ---- ----

U.S. Population:

0.014688 0.49 20424 0.025201 0.84 11904 0.045781 1.53 6552

All infants:

0.046244 1.54 6487 0.065073 2.17 4610 0.113186 3.77 2650

Children 1

- 2 yrs:

0.025061 0.84 11970 0.0 37494 1.25 8001 0.053742 1.79 5582

Children 3

- 5 yrs:

0.022362 0.75 13415 0.031735 1.06 9453 0.055918 1.86 5364

Children 6

- 12 yrs:

0.015532 0.52 19314 0.023518 0.78 12756 0.031437 1.05 9542

Youth 13

- 19 yrs:

0.011553 0.39 25967 0.019123 0.64 15688 0.034214 1.14 8768

Adults 20

- 49 yrs:

0.012690 0.42 23641 0.019849 0.66 15114 0.034828 1.16 8613

Adults 50+ yrs:

0.011471 0.38 26152 0. 016069 0.54 18669 0.025954 0.87 11558

Females 13

- 49 yrs:

0.012602 0.42 23804 0.019466 0.65 15411 0.034625 1.15 8664S

- Metola chlor Dietary Exposure and Risk Assessment DP # D396451



### Page 20 of 27 Attachment 3. Chronic DEEM

- FCID Residue Input File

Filename: F: \ t elework \ s

- metolachlor2011 \ 108800c_rad.R98

Chemical: Metolachlor and S

- metolachlor

RfD(Chronic): .1 mg/kg bw/day NOEL(Chronic): 9.7 mg/kg bw/day

RfD(Acute): 3 mg/kg bw/day NOEL(Acute): 300 mg/kg bw/day

Date created/last modified: 12

- 12

- 2011/09:24:01/14 Program ver. 2.10

--------------------------------------------------------------------------------

EPA Crop Def Res Adj.Factors Comment

Code Grp Commodity Name (ppm) #1 # 2

-------- ---- ------------------------------- ---------- ------ ------ -------

95000190 O Asparagus 0.100000 1.000 1.000

95001280 O Cottonseed, oil 0.100000 1.000 1.000

95001281 O Cotto nseed, oil

- babyfood 0.100000 1.000 1.000

95002630 O Peanut 0.200000 1.000 1.000

95002640 O Peanut, butter 0.200000 1.890 1.000

95002650 O Peanut, oil 0 .200000 1.000 1.000

95003360 O Sesame, seed 0.130000 1.000 1.000 PP#6E7

Full comment: PP#6E7607

95003361 O Sesame, seed

- babyfood 0.130000 1.000 1.000 PP#6E7

Full comment: PP#6E7607

9 5003370 O Sesame, oil 0.130000 1.000 1.000 PP#6E7

Full comment: PP#6E7607

95003371 O Sesame, oil

- babyfood 0.130000 1.000 1.000 PP#6E7

Full comment: PP#6E7607

86010000 O Water, direct , all sources 0.126000 1.000 1.000

86020000 O Water, indirect, all sources 0.126000 1.000 1.000

21000440 M Beef, meat 0.020000 1.000 1.000

21000441 M Beef, meat

- babyfood 0.020000 1.000 1.000

21000450 M Beef, meat, dried 0.020000 1.920 1.000

21000460 M Beef, meat byproducts 0.040000 1.000 1.000

21000461 M Beef, meat byproducts

- babyfood 0.040000 1.000 1.000

21000470 M Beef, fat 0.020000 1.000 1.000

21000471 M Beef,fat

- babyfood 0.020000 1.000 1.000

21000480 M Beef, kidney 0.200000 1.000 1.000

21000490 M Beef, liver 0.050000 1.000 1.000

21000491 M Beef, liver

- babyfood 0.050000 1.000 1.000

23001690 M Goat, meat 0.020000 1.000 1.000

23001700 M Goat, meat byproducts 0.040000 1.000 1.000

2 3001710 M Goat, fat 0.020000 1.000 1.000

23001720 M Goat, kidney 0.200000 1.000 1.000

23001730 M Goat, liver 0.050000 1.000 1.000

24001890 M Horse, meat 0.020000 1.000 1.000

26003390 M Sheep, meat 0.020000 1.000 1.000

26003391 M Sheep, meat

- babyfood 0.020000 1.000 1.000

26003400 M Sheep, meat byproducts 0.040000 1.0 00 1.000

26003410 M Sheep, fat 0.020000 1.000 1.000

26003411 M Sheep, fat

- babyfood 0.020000 1.000 1.000

26003420 M Sheep, kidney 0.200000 1.000 1.000

26003430 M Sheep , liver 0.050000 1.000 1.000

40000930 P Chicken, meat 0.020000 1.000 1.000

40000931 P Chicken, meat

- babyfood 0.020000 1.000 1.000

40000940 P Chicken, liver 0 .050000 1.000 1.000

40000950 P Chicken, meat byproducts 0.050000 1.000 1.000

40000951 P Chicken, meat byproducts

- babyfoo 0.050000 1.000 1.000

40000960 P Chicken, fat 0.020000 1.000 1.000

400009 61 P Chicken, fat

- babyfood 0.020000 1.000 1.000

40000970 P Chicken, skin 0.050000 1.000 1.000

40000971 P Chicken, skin

- babyfood 0.050000 1.000 1.000

70001450 P Egg, whole 0.020000 1.000 1.000

70001451 P Egg, whole

- babyfood 0.020000 1.000 1.000

70001460 P Egg, white 0.020000 1.000 1.000S

- Metola chlor Dietary Exposure and Risk Assessment DP # D396451



### Page 21 of 27 70001461 P Egg, white (solids)

- babyfood 0.020000 1.000 1 .000

70001470 P Egg, yolk 0.020000 1.000 1.000

70001471 P Egg, yolk

- babyfood 0.020000 1.000 1.000

60003010 P Poultry, other, meat 0.020000 1.000 1.000

60003020 P Poultry, o ther, liver 0.050000 1.000 1.000

60003030 P Poultry, other, meat byproducts 0.050000 1.000 1.000

60003040 P Poultry, other, fat 0.020000 1.000 1.000

60003050 P Poultry, other, skin 0.0500 00 1.000 1.000

50003820 P Turkey, meat 0.020000 1.000 1.000

50003821 P Turkey, meat

- babyfood 0.020000 1.000 1.000

50003830 P Turkey, liver 0.050000 1.000 1.000

50003831 P Turkey, liver

- babyfood 0.050000 1.000 1.000

50003840 P Turkey, meat byproducts 0.050000 1.000 1.000

50003841 P Turkey, meat byproducts

- babyfood 0.050000 1.000 1.000

50003850 P Turkey, fat 0.020000 1.000 1.000

50003851 P Turkey, fat

- babyfood 0.020000 1.000 1.000

50003860 P Turkey, skin 0.050000 1.000 1.000

50003861 P Turkey, skin

- babyfood 0.050000 1.000 1.000

27002220 D Milk, fat 0.020000 1.000 1.000

27002221 D Milk, fat

- baby food/infant for 0.020000 1.000 1.000

27012230 D Milk, nonfat solids 0.020000 1.000 1.000

27012231 D Milk, nonfat so lids

- baby food/in 0.020000 1.000 1.000

27022240 D Milk, water 0.020000 1.000 1.000

27022241 D Milk, water

- babyfood/infant form 0.020000 1.000 1.000

27032251 D Milk, sugar (lactose)

- baby food/ 0.020000 1.000 1.000

01030150 1CD Arrowroot, flour 0.200000 1.000 1.000

01030151 1CD Arrowroot, flour

- babyfood 0.200000 1.000 1.000

01030170 1CD Artichoke, Jerusalem 0.200000 1.000 1.000

01010500 1AB Be et, garden, roots 0.300000 1.000 1.000

01010501 1AB Beet, garden, roots

- babyfood 0.300000 1.000 1.000

01010520 1A Beet, sugar 0.500000 1.000 1.000

01010521 1A Beet, sugar

- babyfood 0.500000 1.000 1.000

01010530 1A Beet, sugar, molasses 2.000000 1.000 1.000

01010531 1A Beet, sugar, molasses

- babyfood 2.000000 1.000 1.000

01010670 1AB Burdock 0.300000 1.000 1.000

010 10780 1AB Carrot 0.400000 1.000 1.000 PP#9E7

Full comment: PP#9E7607

01010781 1AB Carrot

- babyfood 0.400000 1.000 1.000 PP#9E7

Full comment: PP#9E7607

01010790 1AB Carrot, juice 0.400000 1.000 1.000 PP#9E7

Full comment: PP#9E7607

01030820 1CD Cassava 0.200000 1.000 1.000

01030821 1CD Cassava

- babyfood 0.200000 1.000 1.000

01010840 1AB Celeri ac 0.300000 1.000 1.000

01011000 1AB Chicory, roots 0.300000 1.000 1.000

01031390 1CD Dasheen, corm 0.200000 1.000 1.000

01031660 1CD Ginger 0. 200000 1.000 1.000

01031661 1CD Ginger

- babyfood 0.200000 1.000 1.000

01031670 1CD Ginger, dried 0.200000 1.000 1.000

01011680 1AB Ginseng, dried 0.300000 1.000 1.000

0101190 0 1AB Horseradish 0.300000 1.000 1.000

01012500 1AB Parsley, turnip rooted 0.300000 1.000 1.000

01012510 1AB Parsnip 0.300000 1.000 1.000

01012511 1AB Parsnip

- babyfood 0.300000 1.000 1.000

01032960 1C Potato, chips 0.200000 1.000 1.000

01032970 1C Potato, dry (granules/ flakes) 0.200000 6.500 1.000

01032971 1C Potato, dry (granules/ flakes)

- b 0.200000 6.500 1. 000

01032980 1C Potato, flour 0.200000 6.500 1.000

01032981 1C Potato, flour

- babyfood 0.200000 1.000 1.000

01032990 1C Potato, tuber, w/peel 0.200000 1.000 1.000

01032991 1C Potato, tub er, w/peel

- babyfood 0.200000 1.000 1.000

01033000 1C Potato, tuber, w/o peel 0.200000 1.000 1.000

01033001 1C Potato, tuber, w/o peel

- babyfood 0.200000 1.000 1.000S

- Metola chlor Dietary Exposure and Risk Assessment DP # D396451



### Page 22 of 27 01013140 1AB Radish, roots 0.30000 0 1.000 1.000

01013160 1AB Radish, Oriental, roots 0.300000 1.000 1.000

01013270 1AB Rutabaga 0.300000 1.000 1.000

01013310 1AB Salsify, roots 0.300000 1.000 1.000

01033660 1CD Sweet potato 0.200000 1.000 1.000

01033661 1CD Sweet potato

- babyfood 0.200000 1.000 1.000

01033710 1CD Tanier, corm 0.200000 1.000 1.000

01033870 1CD Turmeric 0.200000 1.000 1.000

01013880 1AB Turnip, roots 0.300000 1.000 1.000

01034060 1CD Yam, true 0.200000 1.000 1.000

01034070 1CD Yam bean 0.200000 1.000 1.000

02000510 2 Beet, garden, tops 1.800000 1.000 1.000 1E7898

03001640 3 Garlic 0.100000 1.000 1.000

03001650 3 Garlic, dried 0.100000 9.000 1.000

03001651 3 Garlic, dr ied

- babyfood 0.100000 9.000 1.000

03001980 3 Leek 2.000000 1.000 1.000

03002370 3 Onion, dry bulb 0.100000 1.000 1.000 PP#9E7

Full comment: PP#9E7607

03002371 3 O nion, dry bulb

- babyfood 0.100000 1.000 1.000 PP#9E7

Full comment: PP#9E7607

03002380 3 Onion, dry bulb, dried 0.100000 9.000 1.000 PP#9E7

Full comment: PP#9E7607

03002381 3 Onion, dry bulb, dried

- baby food 0.100000 9.000 1.000 PP#9E7

Full comment: PP#9E7607

03002390 3 Onion, green 2.000000 1.000 1.000 PP#9E7

Full comment: PP#9E7607

03003380 3 Shallot 2.000000 1.000 1.000

04020760 4B Cardoon 0.100000 1.000 1.000

04020850 4B Celery 0.100000 1.000 1.000

04020851 4B Celery

- babyfood 0.100000 1.000 1.000

04020860 4B Celery, j uice 0.100000 1.000 1.000

04020870 4B Celtuce 0.100000 1.000 1.000

04021520 4B Fennel, Florence 0.100000 1.000 1.000

04012050 4A Lettuce, leaf 0.500 000 1.000 1.000

04023220 4B Rhubarb 0.100000 1.000 1.000

04013550 4A Spinach 0.500000 1.000 1.000

04013551 4A Spinach

- babyfood 0.500000 1.000 1.000

04023670 4 B Swiss chard 0.100000 1.000 1.000

05010610 5A Broccoli 0.600000 1.000 1.000

05010611 5A Broccoli

- babyfood 0.600000 1.000 1.000

05010620 5A Broccoli, Chinese 0.600000 1.000 1.000

05020630 5B Broccoli raab 1.800000 1.000 1.000 PP#6E7

Full comment: PP#6E7607

05010640 5A Brussels sprouts 0.600000 1.000 1.000

05010690 5A Cabbage 0.600000 1.000 1.000

05020700 5B Cabbage, Chinese, bok choy 1.800000 1.000 1.000 PP#6E7

Full comment: PP#6E7607

05010710 5A Cabbage, Chinese, napa 0.600000 1.000 1.000

05010720 5A Cabbage, Chinese, mustard 0.600000 1.000 1.000

05010830 5A Cauliflower 0.600000 1.000 1.000

05021170 5B Collards 1.800000 1.000 1.000 PP#6E7

Full comment: PP#6E7607

05021940 5B Kale 1.800000 1.000 1.000 PP#6E7

Full comment: PP#6E7607

05011960 5A Kohlrabi 0.600000 1.000 1.000

05022290 5B Mustard greens 1.800000 1.000 1.000 PP#9E7

Full comment: PP#9E7607

05023180 5B Rape greens 1.800000 1.000 1.000 PP#9E7

Full comment: PP#9E7607

05023890 5B Turnip, greens 1.800000 1.000 1.000 PP#9E7

Full comment: P P#9E7607

06030300 6C Bean, black, seed 0.300000 1.000 1.000

06020310 6B Bean, broad, succulent 0.300000 1.000 1.000 AdditiS

- Metola chlor Dietary Exposure and Risk Assessment DP # D396451



### Page 23 of 27 Full comment: Additional data required.

06030320 6C Bean, broad, seed 0.300000 1.000 1.000

06020330 6B Bean, cowpea, succulent 0.300000 1.000 1.000 Additi

Full comment: Additional data required.

06030340 6C Bean, cowpea, seed 0.300000 1.000 1.000

06030350 6C Be an, great northern, seed 0.300000 1.000 1.000

06030360 6C Bean, kidney, seed 0.300000 1.000 1.000

06020370 6B Bean, lima, succulent 0.300000 1.000 1.000 Additi

Full comment: Additional data r equired.

06030380 6C Bean, lima, seed 0.300000 1.000 1.000

06030390 6C Bean, mung, seed 0.300000 1.000 1.000

06030400 6C Bean, navy, seed 0.300000 1.000 1.000

06030410 6C Bean, pi nk, seed 0.300000 1.000 1.000

06030420 6C Bean, pinto, seed 0.300000 1.000 1.000

06010430 6A Bean, snap, succulent 0.300000 1.000 1.000 Additi

Full comment: Additional data require d.

06010431 6A Bean, snap, succulent

- babyfood 0.300000 1.000 1.000 Additi

Full comment: Additional data required.

06030980 6C Chickpea, seed 0.300000 1.000 1.000

06030981 6C Chickpea, seed

- babyfood 0.300000 1.000 1.000

06030990 6C Chickpea, flour 0.300000 1.000 1.000

06031820 6C Guar, seed 0.300000 1.000 1.000

06031821 6C Guar, seed

- babyfood 0.300000 1.000 1.000

060 32030 6C Lentil, seed 0.300000 1.000 1.000

06022550 6B Pea, succulent 0.300000 1.000 1.000 Additi

Full comment: Additional data required.

06022551 6B Pea, succulent

- babyfood 0.30 0000 1.000 1.000 Additi

Full comment: Additional data required.

06032560 6C Pea, dry 0.300000 1.000 1.000

06032561 6C Pea, dry

- babyfood 0.300000 1.000 1.000

06012570 6A Pea, edible po dded, succulent 0.300000 1.000 1.000 Additi

Full comment: Additional data required.

06032580 6C Pea, pigeon, seed 0.300000 1.000 1.000

06022590 6B Pea, pigeon, succulent 0.300000 1.000 1.000 Addi ti

Full comment: Additional data required.

06003470 6 Soybean, seed 0.300000 1.000 1.000

06003480 6 Soybean, flour 0.300000 1.000 1.000

06003481 6 Soybean, flour

- babyfood 0.30 0000 1.000 1.000

06003490 6 Soybean, soy milk 0.300000 1.000 1.000

06003491 6 Soybean, soy milk

- babyfood or in 0.300000 1.000 1.000

06003500 6 Soybean, oil 0.300000 1.000 1.000

06003501 6 Soybean, oil

- babyfood 0.300000 1.000 1.000

08001480 8 Eggplant 0.100000 1.000 1.000

08002340 8 Okra 0.500000 1.000 1.000 PP#6E7

Full comment: PP#6E7607

08002700 8 Pepper, bell 0.100000 1.000 1.000

08002701 8 Pepper, bell

- babyfood 0.100000 1.000 1.000

08002710 8 Pepper, bell, dried 0.100000 1.000 1.000

08002711 8 Pepper, bell, dri ed

- babyfood 0.100000 1.000 1.000

08002720 8 Pepper, nonbell 0.500000 1.000 1.000 Tabasc

Full comment: Tabasco peppers @ 0.5 ppm

08002721 8 Pepper, nonbell

- babyfood 0.500000 1.000 1.000 Tabasc

Full comment: Tabasco peppers @ 0.5 ppm

08002730 8 Pepper, nonbell, dried 0.500000 1.000 1.000 Tabasc

Full comment: Tabasco peppers @ 0.5 ppm

08003740 8 Tomatillo 0.100000 1.000 1.000

08003750 8 Tomato 0.100000 1.000 1.000

08003751 8 Tomato

- babyfood 0.100000 1.000 1.000

08003760 8 Tomato, paste 0.300000 5.400 1.000

08003761 8 Tomato, paste

- bab yfood 0.300000 5.400 1.000

08003770 8 Tomato, puree 0.100000 3.300 1.000

08003771 8 Tomato, puree

- babyfood 0.100000 3.300 1.000

08003780 8 Tomato, dried 0.100000 14. 300 1.000S

- Metola chlor Dietary Exposure and Risk Assessment DP # D396451



### Page 24 of 27 08003781 8 Tomato, dried

- babyfood 0.100000 14.300 1.000

08003790 8 Tomato, juice 0.100000 1.500 1.000

09010750 9A Cantaloupe 0.100000 1.000 1.000 PP#6E7

Fu ll comment: PP#6E7607

09010800 9A Casaba 0.100000 1.000 1.000 PP#6E7

Full comment: PP#6E7607

09021350 9B Cucumber 0.130000 1.000 1.000 PP#6E7

Full comment: PP#6E7607

0901 1870 9A Honeydew melon 0.100000 1.000 1.000 PP#6E7

Full comment: PP#6E7607

09023080 9B Pumpkin 0.100000 1.000 1.000

09023090 9B Pumpkin, seed 0.100000 1.000 1.0 00

09023570 9B Squash, winter 0.100000 1.000 1.000

09023571 9B Squash, winter

- babyfood 0.100000 1.000 1.000

09013990 9A Watermelon 0.100000 1.000 1.000 PP#6E7

Full comme nt: PP#6E7607

09014000 9A Watermelon, juice 0.100000 1.000 1.000 PP#6E7

Full comment: PP#6E7607

13010550 13A Blackberry 0.100000 1.000 1.000 PP#6E7

Full comment: PP#6E7607

13010560 13A Blackberry, juice 0.100000 1.000 1.000 PP#6E7

Full comment: PP#6E7607

13010561 13A Blackberry, juice

- babyfood

240

- Cooked; Canned; Cook Meth N/S

0.100000 1 .000 1.000 PP#6E7

Full comment: PP#6E7607

13020570 13B Blueberry 0.150000 1.000 1.000 PP#6E7

Full comment: PP#6E7607

13020571 13B Blueberry

- babyfood 0.150000 1.000 1.000 PP#6E7

Full comment: PP#6E7607

13010580 13A Boysenberry 0.100000 1.000 1.000 PP#6E7

Full comment: PP#6E7607

13021360 13B Currant 0.150000 1.000 1.000 PP#6E7

Full comment: PP#6E760 7

13021370 13B Currant, dried 0.150000 1.000 1.000 PP#6E7

Full comment: PP#6E7607

13011420 13A Dewberry 0.100000 1.000 1.000 PP#6E7

Full comment: PP#6E7607

13021490 13B Elderberry 0.150000 1.000 1.000 PP#6E7

Full comment: PP#6E7607

13021740 13B Gooseberry 0.150000 1.000 1.000 PP#6E7

Full comment: PP#6E7607

13021910 13B Huckleberry 0 .150000 1.000 1.000 PP#6E7

Full comment: PP#6E7607

13012080 13A Loganberry 0.100000 1.000 1.000 PP#6E7

Full comment: PP#6E7607

13013200 13A Raspberry 0.100000 1.000 1.000 PP #6E7

Full comment: PP#6E7607

13013201 13A Raspberry

- babyfood 0.100000 1.000 1.000 PP#6E7

Full comment: PP#6E7607

13013210 13A Raspberry, juice 0.100000 1.000 1.000 PP#6E7

Full commen t: PP#6E7607

13013211 13A Raspberry, juice

- babyfood 0.100000 1.000 1.000 PP#6E7

Full comment: PP#6E7607

14000030 14 Almond 0.100000 1.000 1.000

14000031 14 Almond

- babyfood 0.10 0000 1.000 1.000

14000040 14 Almond, oil 0.100000 1.000 1.000

14000041 14 Almond, oil

- babyfood 0.100000 1.000 1.000

14000590 14 Brazil nut 0.100000 1.000 1.000

14000680 14 Butternut 0.100000 1.000 1.000

14000810 14 Cashew 0.100000 1.000 1.000

14000920 14 Chestnut 0.100000 1.000 1.000

14001550 14 Filbert 0.100000 1.000 1.000S

- Metola chlor Dietary Exposure and Risk Assessment DP # D396451



### Page 25 of 27 14001560 14 Filbert, oil 0.100000 1.000 1.000

14001850 14 Hickory nut 0.100000 1.000 1.000

14002130 14 Macadamia nut 0.100000 1.000 1.00 0

14002690 14 Pecan 0.100000 1.000 1.000

14002820 14 Pistachio 0.100000 1.000 1.000

14003910 14 Walnut 0.100000 1.000 1.000

15000250 15 Barley, pearl ed barley 0.100000 1.000 1.000

15000251 15 Barley, pearled barley

- babyfood 0.100000 1.000 1.000

15000260 15 Barley, flour 0.100000 1.000 1.000

15000261 15 Barley, flour

- babyfood 0.100000 1.000 1.000

15000270 15 Barley, bran 0.100000 1.000 1.000

15000650 15 Buckwheat 0.100000 1.000 1.000 Additi

Full comment: Additional data required.

15000660 15 Buckwheat, flour 0.100000 1.000 1.000 Additi

Full comment: Additional data required.

15001200 15 Corn, field, flour 0.100000 1.000 1.000

15001201 15 Corn, field, flour

- babyfood 0.100000 1.000 1.000

15001210 15 Corn, field, meal 0.100000 1.000 1.000

15001211 15 Corn, field, meal

- babyfood 0.100000 1.000 1.000

15001220 15 Corn, field, bran 0.100000 1.000 1.000

15001230 15 Corn, field, starch 0.100000 1.000 1.000

15001231 15 Corn, field, starch

- babyfood 0.100000 1.000 1.000

15001240 15 Corn, field, syrup 0.100000 1.500 1.000

15001241 15 Corn, field, syrup

- babyfood 0.100000 1.500 1.0 00

15001250 15 Corn, field, oil 0.100000 1.000 1.000

15001251 15 Corn, field, oil

- babyfood 0.100000 1.000 1.000

15001260 15 Corn, pop 0.100000 1.000 1.000

15001270 15 Corn, sweet 0.100000 1.000 1.000

15001271 15 Corn, sweet

- babyfood 0.100000 1.000 1.000

15002260 15 Millet, grain 0.100000 1.000 1.000

15002310 15 Oat, bran 0.100000 1.000 1.000

15002320 15 Oat, flour 0.100000 1.000 1.000

15002321 15 Oat, flour

- babyfood 0.100000 1.000 1.000

15002330 15 Oat, groats/rolled oats 0.100000 1.000 1.000

15002331 15 Oat, groats/rolled oats

- babyfood 0.100000 1.000 1.000

15003230 15 Rice, white 0.100000 1.000 1.000

15003231 15 Rice, white

- babyfood 0.100000 1.000 1.000

15003240 15 Rice, brown 0.100000 1.000 1.000

15003241 15 Rice, brown

- babyfood 0.100000 1.000 1.000

15003250 15 Rice, flour 0.100000 1.000 1.000

15003251 15 Rice, flour

- babyfood 0.100000 1.000 1.000

15003260 15 Rice, bran 0.100000 1.000 1.000

15003261 15 Rice, bran

- babyfood 0.100000 1.000 1.000

15003280 15 Rye, grain 0.100000 1.000 1.000

15003290 15 Rye, flour 0.100000 1.000 1.000

15003440 15 Sorghum, grain 0.300000 1.000 1.000 PP#9E7

Full comment: PP#9E7607

15003450 15 Sorghum, syrup 4.000000 1.000 1.000 PP#9E7

Full c omment: PP#9E7607

15003810 15 Triticale, flour 0.100000 1.000 1.000

15003811 15 Triticale, flour

- babyfood 0.100000 1.000 1.000

15004010 15 Wheat, grain 0.100000 1.000 1.000

15004011 15 Wheat, grain

- babyfood 0.100000 1.000 1.000

15004020 15 Wheat, flour 0.100000 1.000 1.000

15004021 15 Wheat, flour

- babyfood 0.100000 1.000 1.000

15004030 15 Wheat, germ 0.100000 1.000 1.000

15004040 15 Wheat, bran 0.100000 1.000 1.000

15004050 15 Wild rice 0.100000 1.000 1.000

19011030 19A Chive 2.000000 1.000 1.000

19011180 19A Coriander, leaves 8.000000 1.000 1.000 1E7898

19011181 19A Coriander, leaves

- babyfood 8.000000 1.000 1.000 1E7898

19021190 19B Coriander, seed 0.130000 1.000 1.000 1E7898

19021191 19B Coriander, seed

- babyfood 0.130000 1.000 1.000 1E7898S

- Metola chlor Dietary Exposure and Risk Assessment DP # D396451



### Page 26 of 27 19011440 19A Dillweed 0.500000 1.000 1.000S

- Metola chlor Dietary Exposure and Risk Assessment DP # D396451



### Page 27 of 27 Attachment 4 Results of Chronic DEEM

- FCID Dietary Exposure Analysis

California Department of Pesticide Regulation Ver. 2.00

DEEM

- FCID Chronic analysis for METOLACHLOR AND S

- METOLACHLOR (1994

- 98 data)

Residue file name: F: \ telework \ s

- metolachlor2011 \ 108800c_rad.R98

Adjustment factor #2 NOT used.

Analysis Date 12

- 12

- 2011/10:33:12 Residue file dated: 12

- 12

- 2011/09:24:01/14

Reference dose (RfD, Chronic) = .1 mg/kg bw/day

============================================================================== =

Total exposure by population subgroup

-------------------------------------------------------------------------------

Total Exposure

------- ---------------------------- Population mg/kg Percent of

Subgroup body wt/day Rfd

-------------------------------------- ------------- ------------ ---

U.S. Population (total) 0.004550 4.5%

U.S. Population (spring season) 0.004522 4.5%

U.S. Population (summer season) 0.004755 4.8%

U.S. Population (autumn seaso n) 0.004468 4.5%

U.S. Population (winter season) 0.004450 4.4%

Northeast region 0.004282 4.3%

Midwest region 0.004614 4.6%

Southern region 0.004385 4.4%

Western region 0.004983 5.0%

Hispanics 0.004981 5.0%

Non

- hispanic whites 0.004405 4.4%

Non

- hispanic blacks 0.004634 4.6%

Non

- hisp/non

- white/non

- black 0.005662 5.7%

All infants (< 1 year) 0.011574 11.6%

Nursing infants 0.004534 4.5%

Non

- nursing infants 0.014246 14.2%

Children 1

- 6 yrs 0.007966 8.0%

Children 7

- 12 yrs 0.005096 5.1%

Females 13

- 19 (not preg or nursing) 0.003461 3.5%

Females 20+ (not preg or nursing) 0.004053 4.1%

Females 13

- 50 yrs 0.0 04122 4.1%

Females 13+ (preg/not nursing) 0.004142 4.1%

Females 13+ (nursing) 0.005449 5.4%

Males 13

- 19 yrs 0.003911 3.9%

Males 20+ yrs 0.003928 3.9%

Seniors 55+ 0.004009 4.0%

Children 1

- 2 yrs 0.008666 8.7%

Children 3

- 5 yrs 0.007852 7.9%

Children 6

- 12 yrs 0.005372 5.4%

Youth 13

- 19 yrs 0.003698 3.7%

Adults 20

- 49 yrs 0.003994 4.0%

Adults 50+ yrs 0.004017 4.0%

Females 13

- 49 yrs 0.003929 3.9%

-------------------------------------------------------------------------------