S-Metolachlor Dietary Exposure and Risk Assessment DP # D396451 

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resulting from the Section 3 use of S-metolachlor on cilantro and garden beet leaves to control 

weeds.

Executive Summary

Acute and chronic dietary risk assessments were conducted for S-metolachlor using the Dietary 

Exposure Evaluation Model (DEEM-FCID, Version 2.03), which uses food consumption data 

from the USDA’s Continuing Surveys of Food Intakes by Individuals (CSFII) from 1994-1996 

and 1998. The analyses were performed to support a Section 3 request for proposed uses of Smetolachlor on cilantro and garden beet. 

 

Acute Dietary Exposure Results and Characterization

A conservative acute dietary exposure analysis was performed for the general U.S. population 

and various population subgroups. Tolerance level residues and 100 percent crop treated 

assumptions were used. DEEM default processing factors were used to modify the tolerance 

values. The acute analysis incorporated the 1 in 10 year peak surface drinking water estimate 

from application of S-metolachlor on turf. This assessment concludes that, for all supported 

commodities, the acute dietary exposure estimates are below HED’s level of concern. The 95th

percentile acute dietary exposure estimate for the highest exposed population subgroup, all 

infants < 1 year old, is 1.5% of the acute population adjusted dose (aPAD). 

Chronic Dietary Exposure Results and Characterization

A conservative chronic dietary exposure analysis was performed for the general U.S. population 

and various population subgroups. Tolerance level residues and 100 percent crop treated 

assumptions were used. DEEM default processing factors were used to modify the tolerance 

values. The chronic analysis incorporated the 10 year average surface drinking water estimate 

from application of S-metolachlor to turf. The chronic dietary exposure estimate for the highest 

exposed population subgroup, all infants < 1 year old, is 11.6% of the chronic population 

adjusted dose (cPAD).

I. Introduction

Dietary risk assessment incorporates both exposure and toxicity of a given pesticide. For acute 

and chronic assessments, the risk is expressed as a percentage of a maximum acceptable dose 

(i.e., the dose which HED has concluded will result in no unreasonable adverse health effects). 

This dose is referred to as the population adjusted dose (PAD). The PAD is equivalent to the 

Reference Dose (RfD) divided by the FQPA Safety Factor.

For acute and non-cancer chronic exposures, HED is concerned when estimated dietary risk 

exceeds 100% of the PAD. References that discuss the acute and chronic risk assessments in 

more detail are available on the EPA/pesticides web site: “Available Information on Assessing 

Exposure from Pesticides, A User’s Guide,” 6/21/2000, web link: 
S-Metolachlor Dietary Exposure and Risk Assessment DP # D396451 

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http://www.epa.gov/fedrgstr/EPA_PEST/2000/July/Day_12/6061.pdf ; or see SOP 99.6 

(8/20/99). 

The most recent dietary risk assessment for S-metolachlor was conducted by W. Cutchin 

(D391172, 7/20/11) for the Section 18 use on leaf lettuce.

II. Residue Information

Metolachlor (PC Code 108801) is a racemic herbicide that consists of 50% each of the Renantiomer and the S-enantiomer. S-metolachlor products are an isomer enriched formula 

comprised of 88% S-isomer and 12% R-isomer. The residues of concern for S-metolachlor are 

the same as those for metolachlor (D226780, L. Kutney, 11/12/96). The Metabolism Assessment 

Review Committee (MARC, 8/14/001) determined that the residues of concern for plant and 

livestock commodities are metolachlor and its metabolites, determined as the derivatives 2- [(2-

ethyl-6- methylphenyl)amino]-1-propanol (CGA-37913) and 4-(2-ethyl-6-methylphenyl)-2-

hydroxy-5-methyl-3-morpholinone (CGA-49751). Metabolites of metolachlor are assumed to be 

toxicologically equivalent to parent metolachlor. Permanent tolerances are established at 40 

CFR §180.368(a)(2) for S-metolachlor in/on a variety of crop commodities, at levels ranging 

from 0.02 in/on meat and dairy products to 20 ppm in/on peanut hay. Tolerances are established 

for residues of S-metolachlor, including its metabolites and degradates, in or on the commodities. 

In cases where separate tolerance listings occur for both metolachlor and S-metolachlor on the 

same commodity, the higher value of the two is used in the analyses. Residues used in the acute 

and chronic dietary analyses are provided in Tables 1, 2, 3 and 4.

Table 1. Metolachlor Tolerances

Commodity Tolerance (ppm)

Almond, hulls 0.3

Animal feed, nongrass, group 18 1

Cattle, fat; Cattle, meat 0.02

Cattle, kidney 0.2

Cattle, liver 0.05

Cattle, meat byproducts, except kidney and liver 0.04

Corn, field, forage; Corn, field, stover; Corn, sweet, forage; Corn, sweet, stover 6

Corn, field, grain 0.1

Corn, sweet, kernel plus cob with husks removed 0.1

Cotton, gin byproducts 4

Cotton, undelinted seed 0.1

Dillweed 0.5

Egg 0.02

Goat, fat; Goat, meat 0.02

Goat, kidney 0.2

Goat, liver 0.05

Goat, meat byproducts, except kidney and liver 0.04

Grass, forage 10

Grass, hay 0.2

Horse, fat; Horse, meat 0.02
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Table 1. Metolachlor Tolerances

Commodity Tolerance (ppm)

Horse, kidney 0.2

Horse, liver 0.05

Horse, meat byproducts, except kidney and liver 0.04

Milk 0.02

Nut, tree, group 14 0.1

Okra 0.5

Peanut 0.2

Peanut, hay 20

Peanut, meal 0.4

Potato 0.2

Poultry, fat; Poultry, meat 0.02

Poultry, meat byproducts 0.05

Safflower, seed 0.1

Sheep, fat; Sheep, meat 0.02

Sheep, kidney 0.2

Sheep, liver 0.05

Sheep, meat byproducts, except kidney and liver 0.04

Sorghum, grain, forage 1

Sorghum, grain, grain 0.3

Sorghum, grain, stover 4

Soybean, forage 5

Soybean, hay 8

Soybean, seed 0.2

Tomato 0.1

Vegetable, foliage of legume, subgroup 7A, except soybean 15

Vegetable, legume, group 6 0.3

Table 2. S-metolachlor Tolerances 

Commodity Tolerance (ppm)

Asparagus 0.1

Beet, sugar, molasses 2

Beet, sugar, roots 0.5

Beet, sugar, tops 15

Brassica, head and stem, subgroup 5A 0.6

Bushberry subgroup 13-07B 0.15

Caneberry, Subgroup 13-07A 0.1

Carrot 0.40

Cattle, fat; Cattle, meat 0.02

Cattle, kidney 0.2

Cattle, liver 0.05

Cattle, meat byproducts, except kidney and liver 0.04

Corn, field, grain 0.1

Corn, field, forage; Corn, field, stover; Corn, pop, stover; Corn, sweet, forage; Corn, sweet, 

stover

6

Corn, pop, grain 0.1

Corn, sweet, kernel plus cob with husks removed 0.1

Cotton, gin byproducts 4

Cotton, undelinted seed 0.1
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Table 2. S-metolachlor Tolerances 

Commodity Tolerance (ppm)

Cucumber 0.13

Egg 0.02

Garlic, bulb 0.1

Grain, aspirated fractions 0.7

Goat, fat; Goat, meat 0.02

Goat, kidney 0.2

Goat, liver 0.05

Goat, meat byproducts, except kidney and liver 0.04

Grass, forage 10

Grass, hay 0.2

Horse, fat; Horse, meat 0.02

Horse, kidney 0.2

Horse, liver 0.05

Horse, meat byproducts, except kidney and liver 0.04

Leafy Brassica Greens, Subgroup 5-B 1.8

Leaf petioles, subgroup 4B 0.1

Lettuce, leaf 0.5

Milk 0.02

Melon subgroup 9A 0.1

Okra 0.10

Onion, Bulb, Subgroup 3-07A 0.1

Onion, Green, Subgroup 3-07B 2

Peanut 0.2

Peanut, hay 20

Peanut, meal 0.4

Pepper, non-bell 0.50

Pepper, tobasco 0.50

Poultry, fat; Poultry, meat 0.02

Poultry, meat byproducts 0.05

Pumpkin 0.1

Safflower, seed 0.1

Sesame, seed 0.13

Shallot, bulb 0.1

Sheep, fat; Sheep, meat 0.02

Sheep, kidney 0.2

Sheep, liver 0.05

Sheep, meat byproducts, except kidney and liver 0.04

Sorghum, grain, forage 1

Sorghum, grain, grain 0.3

Sorghum, grain, stover 4

Sorghum, sweet stalk 4

Soybean, forage 5

Soybean, hay 8

Soybean, seed 0.2

Spinach 0.5

Squash, winter 0.1

Sunflower, seed 0.5

Sunflower, meal 1

Tomato, paste 0.3
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Table 2. S-metolachlor Tolerances 

Commodity Tolerance (ppm)

Turnip Greens 1.8

Vegetable, foliage of legume, except soybean, subgroup 7A 15

Vegetable, fruiting, group 8, except tabasco pepper 0.1

Vegetable, legume, group 6 0.3

Vegetable, root, except sugar beet, subgroup 1B 0.3

Vegetable, tuberous and corm, subgroup 1C 0.2

Table 3. Metolachlor Inadvertent Tolerances

Commodities Tolerance (ppm)

Animal feed, nongrass, group 18 1.0

Barley, grain 0.10

Barley, hay 0.80

Barley, straw 0.80

Buckwheat, grain 0.10

Millet, forage 0.50

Millet, grain 0.10

Millet, hay 0.80

Millet, straw 0.80

Oat, forage 0.50

Oat, grain 0.10

Oat, hay 0.80

Oat, straw 0.80

Rice, grain 0.10

Rye, forage 0.50

Rye, grain 0.10

Rye, straw 0.80

Wheat, forage 0.50

Wheat, grain 0.10

Wheat, hay 0.80

Wheat, straw 0.80

Table 4. S-metolachlor Inadvertent Tolerances

Commodity Tolerance (ppm)

Animal feed, nongrass, group 18 1.0

Barley, grain 0.10

Barley, hay 0.50

Barley, straw 0.50

Buckwheat, grain 0.10

Millet, forage 0.50

Millet, grain 0.10

Millet, hay 0.50

Millet, straw 0.50

Oat, forage 0.50

Oat, grain 0.10

Oat, hay 0.50

Oat, straw 0.50

Rice, grain 0.10

Rye, forage 0.50
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Table 4. S-metolachlor Inadvertent Tolerances

Commodity Tolerance (ppm)

Rye, grain 0.10

Rye, straw 0.50

Wheat, forage 0.50

Wheat, grain 0.10

Wheat, hay 0.50

Wheat, straw 0.50

In addition, ARIA is also recommending tolerances of 8.0 ppm on fresh or dried cilantro leaves, 

0.13 ppm on coriander seed, and 1.8 ppm on leaves of garden beet as a result of the present 

Section 3 request.

III. Water Data

The Environmental Fate and Effects Division (EFED) calculated conservative, Tier I Estimated 

Drinking Water Concentrations (EDWCs) of metolachlor and S-metolachlor in ground water and 

surface water for use in the human health risk assessment (D368735, C. Koper, 4/22/10). 

EDWCs for metolachlor and S-metolachlor were calculated for both the parent compound and 

the ethanesulfonic acid (ESA) and oxanilic acid (OA) degradates. Although it was determined 

by the MARC that the ESA and OA metabolites appear to be less toxic than parent metolachlor, 

they are included in the risk assessment since they were found in greater abundance than the 

parent in water monitoring studies. 

This drinking water assessment was conducted on the parent S-metolachlor and its major 

degradates ethanesulfonic acid (ESA) and oxanilic acid (OA) as a result of the use on turf. The 

environmental fate data has been bridged from the racemic mixture (50:50) of metolachlor to the 

newer isomer (88:12) S-metolachlor, based on similarities in environmental fate behavior. Tier I 

and Tier II screening models were employed for this assessment. For surface water, 

PRZM/EXAMS (PE5) and FIRST (FQPA Index Reservoir Screening Tool) Version1.1.1 models 

were used to estimate drinking water concentrations for the parent S-metolachlor and the ESA 

and OA degradates, respectively. The SCI-GROW model (Screening Concentration in Ground 

Water Program Version 2.3) was used to predict the maximum acute and chronic concentrations 

present in shallow groundwater. In addition, since the previous EDWCs for surface water for the 

parent S-metolachlor were based on NAWQA monitoring data, a search of the available 

monitoring data was performed on March 30, 2010 to ensure that the most current monitoring 

data were considered in this assessment. The data set captured the timeframe of October 1991 to 

October 2009 and included the parent S-metolachlor and its degradates ESA and OA. Based on 

a review of the current monitoring data, concentrations of parent S-metolachlor and its 

degradates were less than values reported from the previous monitoring data (US EPA, 2002). 

Therefore, EDWCs based on previous monitoring are still valid. The recommended total EEC’s 

for peak and average surface water respectively are 219 ppb (78 ppb parent + 48 ppb ESA+ 94 

ppb OA) and 119 ppb (18 ppb parent + 34 ppb ESA+ 34 ppb OA). Recommended groundwater 

EECs (peak and average) are 126 ppb (33 ppb parent + 64 ppb ESA+ 30 OA). A summary of 

recommended surface and groundwater EDWCs for the human dietary risk assessment for the 
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parent S-metolachlor and its degradates ESA and OA are presented in Table 5.

Table 5. Recommended Drinking Water Concentrations (EDWCs) and Source for Surface Water and Groundwater for 

Human Dietary Health Risk Assessment

Chemical Identity Acute (μg/L) Average (μg/L) Cancer Chronic (μg/L)

Surface Water

S-metolachlor (parent) 77.60 (monitoring data) 18.15CA (cole crop) 9.15 (KS sorghum)

Ethanesulfonic Acid (ESA) 47.61(caneberry) 34.04 (caneberry) 34.04 (caneberry)

Oxanilic Acid (OA) 93.57 (caneberry) 66.62 (caneberry) 66.62 (caneberry)

Total 218.78 118.81 109.81

Groundwater

S-metolachlor (parent) 32.8 (monitoring data) 32.8 (monitoring data) 32.8 (monitoring data)

Ethanesulfonic Acid (ESA) 63.7 (monitoring data) 63.7 (monitoring data) 63.7 (monitoring data)

Oxanilic Acid (OA) 29.7 (caneberry) 29.7 (caneberry) 29.7 (caneberry)

Total 126.2 126.2 126.2

IV. DEEM-FCIDTM Program and Consumption Information

S-metolachlor acute and chronic dietary exposure assessments were conducted using the Dietary 

Exposure Evaluation Model software with the Food Commodity Intake Database (DEEMFCIDTM, Version 2.10), which incorporates consumption data from USDA’s Continuing Surveys 

of Food Intakes by Individuals (CSFII), 1994-1996 and 1998. The 1994-96, 98 data are based on 

the reported consumption of more than 20,000 individuals over two non-consecutive survey 

days. Foods “as consumed” (e.g., apple pie) are linked to EPA-defined food commodities (e.g. 

apples, peeled fruit - cooked; fresh or N/S; baked; or wheat flour - cooked; fresh or N/S, baked) 

using publicly available recipe translation files developed jointly by USDA/ARS and EPA. For 

chronic exposure assessment, consumption data are averaged for the entire U.S. population and 

within population subgroups, but for acute exposure assessment are retained as individual 

consumption events. Based on analysis of the 1994-96, 98 CSFII consumption data, which took 

into account dietary patterns and survey respondents, HED concluded that it is most appropriate 

to report risk for the following population subgroups: the general U.S. population, all infants (<1 

year old), children 1-2, children 3-5, children 6-12, youth 13-19, adults 20-49, females 13-49, 

and adults 50+ years old.

For chronic dietary exposure assessment, an estimate of the residue level in each food or foodform (e.g., orange or orange juice) on the food commodity residue list is multiplied by the 

average daily consumption estimate for that food/food form. The resulting residue consumption 

estimate for each food/food form is summed with the residue consumption estimates for all other 

food/food forms on the commodity residue list to arrive at the total average estimated exposure. 

Exposure is expressed in mg/kg body weight/day and as a percent of the cPAD. This procedure 

is performed for each population subgroup.
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For acute exposure assessments, individual one-day food consumption data are used on an 

individual-by-individual basis. The reported consumption amounts of each food item can be 

multiplied by a residue point estimate and summed to obtain a total daily pesticide exposure for a 

deterministic exposure assessment, or “matched” in multiple random pairings with residue values 

and then summed in a probabilistic assessment. The resulting distribution of exposures is 

expressed as a percentage of the aPAD on both a user (i.e., those who reported eating relevant 

commodities/food forms) and a per-capita (i.e., those who reported eating the relevant 

commodities as well as those who did not) basis. In accordance with HED policy, per capita 

exposure and risk are reported for all tiers of analysis. However significant differences in user 

vs. per capita exposure and risk are identified and noted in the risk assessment.

V. Toxicological Information

HED evaluated the toxicology data base for S-metolachlor and selected the following doses and 

endpoints for acute and chronic dietary and drinking water risk assessments. 

Table 6. Summary of Toxicological Endpoints for S-metolachlor for Use in Dietary Human Health Risk 

Assessments

Exposure

Scenario

Point of 

Departure

Uncertainty/FQP

A Safety Factors

RfD, PAD, 

LOC for Risk 

Assessment

Study and Toxicological Effects

Acute Dietary

(general 

population)

NOAEL = 

300 

mg/kg/day

UFA= 10x

UFH=10x

FQPA SF= 1x

Acute RfD = 3.0 

mg/kg/day

aPAD = 3.0 

mg/kg/day

Developmental Toxicity Study - Rat 

LOAEL = 1000 mg/kg/day based on increased 

incidence of death, clinical signs (clonic and/or 

tonic convulsions, excessive salivation, urinestained abdominal fur and/or excessive 

lacrimation) and decreased body weight gain. 

Chronic 

Dietary 

(all 

populations)

NOAEL = 

9.7

mg/kg/day

UFA= 10x

UFH=10x

FQPA SF= 1x

Chronic RfD = 

0.097

mg/kg/day

cPAD = 

0.097mg/kg/day

Chronic Toxicity - Dog;

LOAEL = 33 mg/kg/day based decreased body 

weight gain in females 

Cancer 

(all routes)

Metolachlor has been classified as a Group C carcinogen with risk quantitated using a non-linear (Margin 

of Exposure) approach. 

Point of Departure (POD) = A data point or an estimated point that is derived from observed dose-response data and used to mark the beginning 

of extrapolation to determine risk associated with lower environmentally relevant human exposures. NOAEL = no observed adverse effect level. 

NOAEL = no observed adverse effect level. 

LOAEL = lowest observed adverse effect level. 

UF = uncertainty factor. UFA = extrapolation from animal to human (interspecies). UFH = potential variation in sensitivity among members of 

the human population (intraspecies). 

FQPA SF = FQPA Safety Factor. 

PAD = population adjusted dose (a = acute, c = chronic). 

RfD = reference dose. 

VI. Results/Discussion

As stated above, for acute and chronic assessments, HED is concerned when dietary risk exceeds 

100% of the PAD. The DEEM-FCIDTM analyses estimate the dietary exposure of the U.S. 

population and various population subgroups. The results reported in Tables 7 and 8 are for the 

general U.S. Population, all infants (<1 year old), children 1-2, children 3-5, children 6-12, youth 
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13-19, females 13-49, adults 20-49, and adults 50+ years.

Results of Acute Dietary Exposure Analysis

Table 7: Summary of Acute Dietary Exposure and Risk for S-metolachlor and Metolachlor

Population Subgroup aPAD (mg/kg/day) Acute (95th Percentile)

Exposure (mg/kg/day) %aPAD

General U.S. Population

3.0

0.014688 <1.0

All Infants (< 1 year old) 0.046244 1.5

Children 1-2 years old 0.025061 <1.0

Children 3-5 years old 0.022362 <1.0

Children 6-12 years old 0.015532 <1.0

Youth 13-19 years old 0.011553 <1.0

Adults 20-49 years old 0.012690 <1.0

Adults 50+ years old 0.011471 <1.0

Females 13-49 years old 0.012602 <1.0

Results of Chronic Dietary Exposure Analysis

Table 8: Summary of Chronic Dietary Exposure and Risk for S-metolachlor and Metolachlor

Population Subgroup cPAD (mg/kg/day) Chronic

Exposure (mg/kg/day) %cPAD

General U.S. Population

0.1

0.004550 4.5

All Infants (< 1 year old) 0.011574 11.6

Children 1-2 years old 0.008666 8.7

Children 3-5 years old 0.007852 7.9

Children 6-12 years old 0.005372 5.4

Youth 13-19 years old 0.003698 3.7

Adults 20-49 years old 0.003994 4.0

Adults 50+ years old 0.004017 4.0

Females 13-49 years old 0.003929 3.9

VI. Characterization of Inputs/Outputs

The acute and chronic dietary analyses are very conservative. Tolerance level residues used in 

the analysis are expected to exceed the residues actually consumed. In addition, the 100% crop 

treated estimate used for all crops in the assessment will considerably overestimate the actual 

percent crop treated. 

VII. Conclusions

Based on analyses of estimated dietary risks for the general U.S. population and various 

population subgroups, the acute and chronic dietary exposure estimates for S-metolachlor are 

significantly below HED’s level of concern for all supported commodities (Tables 7 and 8). The 

95th percentile acute dietary exposure estimate for the highest exposed population subgroup, all 

infants < 1 year old is 1.5% of the aPAD. The chronic dietary exposure estimate for the highest 

exposed population subgroup, all infants < 1 year old is 11.6% of the cPAD.
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VIII. List of Attachments

1. Acute DEEM-FCID Residue Input File.

2. Results of Acute DEEM-FCID Dietary Exposure Analysis.

3. Chronic DEEM-FCID Residue Input File.

4. Results of Chronic DEEM-FCID Dietary Exposure Analysis.
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Attachment 1 Acute DEEM-FCID Residue Input File

Filename: F:\telework\s-metolachlor2011\108800a_rad.R98

Chemical: Metolachlor and S-metolachlor

RfD(Chronic): .1 mg/kg bw/day NOEL(Chronic): 9.7 mg/kg bw/day

RfD(Acute): 3 mg/kg bw/day NOEL(Acute): 300 mg/kg bw/day

Date created/last modified: 12-12-2011/09:22:54/14 Program ver. 2.10

--------------------------------------------------------------------------------

 EPA Crop Def Res Adj.Factors Comment

 Code Grp Commodity Name (ppm) #1 #2 

-------- ---- ------------------------------- ---------- ------ ------ -------

95000190 O Asparagus 0.100000 1.000 1.000 

95001280 O Cottonseed, oil 0.100000 1.000 1.000 

95001281 O Cottonseed, oil-babyfood 0.100000 1.000 1.000 

95002630 O Peanut 0.200000 1.000 1.000 

95002640 O Peanut, butter 0.200000 1.890 1.000 

95002650 O Peanut, oil 0.200000 1.000 1.000 

95003360 O Sesame, seed 0.130000 1.000 1.000 PP#6E7

 Full comment: PP#6E7607

95003361 O Sesame, seed-babyfood 0.130000 1.000 1.000 PP#6E7

 Full comment: PP#6E7607

95003370 O Sesame, oil 0.130000 1.000 1.000 PP#6E7

 Full comment: PP#6E7607

95003371 O Sesame, oil-babyfood 0.130000 1.000 1.000 PP#6E7

 Full comment: PP#6E7607

86010000 O Water, direct, all sources 0.219000 1.000 1.000 

86020000 O Water, indirect, all sources 0.219000 1.000 1.000 

21000440 M Beef, meat 0.020000 1.000 1.000 

21000441 M Beef, meat-babyfood 0.020000 1.000 1.000 

21000450 M Beef, meat, dried 0.020000 1.920 1.000 

21000460 M Beef, meat byproducts 0.040000 1.000 1.000 

21000461 M Beef, meat byproducts-babyfood 0.040000 1.000 1.000 

21000470 M Beef, fat 0.020000 1.000 1.000 

21000471 M Beef,fat-babyfood 0.020000 1.000 1.000 

21000480 M Beef, kidney 0.200000 1.000 1.000 

21000490 M Beef, liver 0.050000 1.000 1.000 

21000491 M Beef, liver-babyfood 0.050000 1.000 1.000 

23001690 M Goat, meat 0.020000 1.000 1.000 

23001700 M Goat, meat byproducts 0.040000 1.000 1.000 

23001710 M Goat, fat 0.020000 1.000 1.000 

23001720 M Goat, kidney 0.200000 1.000 1.000 

23001730 M Goat, liver 0.050000 1.000 1.000 

24001890 M Horse, meat 0.020000 1.000 1.000 

26003390 M Sheep, meat 0.020000 1.000 1.000 

26003391 M Sheep, meat-babyfood 0.020000 1.000 1.000 

26003400 M Sheep, meat byproducts 0.040000 1.000 1.000 

26003410 M Sheep, fat 0.020000 1.000 1.000 

26003411 M Sheep, fat-babyfood 0.020000 1.000 1.000 

26003420 M Sheep, kidney 0.200000 1.000 1.000 

26003430 M Sheep, liver 0.050000 1.000 1.000 

40000930 P Chicken, meat 0.020000 1.000 1.000 

40000931 P Chicken, meat-babyfood 0.020000 1.000 1.000 

40000940 P Chicken, liver 0.050000 1.000 1.000 

40000950 P Chicken, meat byproducts 0.050000 1.000 1.000 

40000951 P Chicken, meat byproducts-babyfoo 0.050000 1.000 1.000 

40000960 P Chicken, fat 0.020000 1.000 1.000 

40000961 P Chicken, fat-babyfood 0.020000 1.000 1.000 

40000970 P Chicken, skin 0.050000 1.000 1.000 

40000971 P Chicken, skin-babyfood 0.050000 1.000 1.000 

70001450 P Egg, whole 0.020000 1.000 1.000 

70001451 P Egg, whole-babyfood 0.020000 1.000 1.000 

70001460 P Egg, white 0.020000 1.000 1.000 
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70001461 P Egg, white (solids)-babyfood 0.020000 1.000 1.000 

70001470 P Egg, yolk 0.020000 1.000 1.000 

70001471 P Egg, yolk-babyfood 0.020000 1.000 1.000 

60003010 P Poultry, other, meat 0.020000 1.000 1.000 

60003020 P Poultry, other, liver 0.050000 1.000 1.000 

60003030 P Poultry, other, meat byproducts 0.050000 1.000 1.000 

60003040 P Poultry, other, fat 0.020000 1.000 1.000 

60003050 P Poultry, other, skin 0.050000 1.000 1.000 

50003820 P Turkey, meat 0.020000 1.000 1.000 

50003821 P Turkey, meat-babyfood 0.020000 1.000 1.000 

50003830 P Turkey, liver 0.050000 1.000 1.000 

50003831 P Turkey, liver-babyfood 0.050000 1.000 1.000 

50003840 P Turkey, meat byproducts 0.050000 1.000 1.000 

50003841 P Turkey, meat byproducts-babyfood 0.050000 1.000 1.000 

50003850 P Turkey, fat 0.020000 1.000 1.000 

50003851 P Turkey, fat-babyfood 0.020000 1.000 1.000 

50003860 P Turkey, skin 0.050000 1.000 1.000 

50003861 P Turkey, skin-babyfood 0.050000 1.000 1.000 

27002220 D Milk, fat 0.020000 1.000 1.000 

27002221 D Milk, fat - baby food/infant for 0.020000 1.000 1.000 

27012230 D Milk, nonfat solids 0.020000 1.000 1.000 

27012231 D Milk, nonfat solids-baby food/in 0.020000 1.000 1.000 

27022240 D Milk, water 0.020000 1.000 1.000 

27022241 D Milk, water-babyfood/infant form 0.020000 1.000 1.000 

27032251 D Milk, sugar (lactose)-baby food/ 0.020000 1.000 1.000 

01030150 1CD Arrowroot, flour 0.200000 1.000 1.000 

01030151 1CD Arrowroot, flour-babyfood 0.200000 1.000 1.000 

01030170 1CD Artichoke, Jerusalem 0.200000 1.000 1.000 

01010500 1AB Beet, garden, roots 0.300000 1.000 1.000 

01010501 1AB Beet, garden, roots-babyfood 0.300000 1.000 1.000 

01010520 1A Beet, sugar 0.500000 1.000 1.000 

01010521 1A Beet, sugar-babyfood 0.500000 1.000 1.000 

01010530 1A Beet, sugar, molasses 2.000000 1.000 1.000 

01010531 1A Beet, sugar, molasses-babyfood 2.000000 1.000 1.000 

01010670 1AB Burdock 0.300000 1.000 1.000 

01010780 1AB Carrot 0.400000 1.000 1.000 PP#9E7

 Full comment: PP#9E7607

01010781 1AB Carrot-babyfood 0.400000 1.000 1.000 PP#9E7

 Full comment: PP#9E7607

01010790 1AB Carrot, juice 0.400000 1.000 1.000 PP#9E7

 Full comment: PP#9E7607

01030820 1CD Cassava 0.200000 1.000 1.000 

01030821 1CD Cassava-babyfood 0.200000 1.000 1.000 

01010840 1AB Celeriac 0.300000 1.000 1.000 

01011000 1AB Chicory, roots 0.300000 1.000 1.000 

01031390 1CD Dasheen, corm 0.200000 1.000 1.000 

01031660 1CD Ginger 0.200000 1.000 1.000 

01031661 1CD Ginger-babyfood 0.200000 1.000 1.000 

01031670 1CD Ginger, dried 0.200000 1.000 1.000 

01011680 1AB Ginseng, dried 0.300000 1.000 1.000 

01011900 1AB Horseradish 0.300000 1.000 1.000 

01012500 1AB Parsley, turnip rooted 0.300000 1.000 1.000 

01012510 1AB Parsnip 0.300000 1.000 1.000 

01012511 1AB Parsnip-babyfood 0.300000 1.000 1.000 

01032960 1C Potato, chips 0.200000 1.000 1.000 

01032970 1C Potato, dry (granules/ flakes) 0.200000 6.500 1.000 

01032971 1C Potato, dry (granules/ flakes)-b 0.200000 6.500 1.000 

01032980 1C Potato, flour 0.200000 6.500 1.000 

01032981 1C Potato, flour-babyfood 0.200000 1.000 1.000 

01032990 1C Potato, tuber, w/peel 0.200000 1.000 1.000 

01032991 1C Potato, tuber, w/peel-babyfood 0.200000 1.000 1.000 

01033000 1C Potato, tuber, w/o peel 0.200000 1.000 1.000 

01033001 1C Potato, tuber, w/o peel-babyfood 0.200000 1.000 1.000 
S-Metolachlor Dietary Exposure and Risk Assessment DP # D396451 

Page 14 of 27

01013140 1AB Radish, roots 0.300000 1.000 1.000 

01013160 1AB Radish, Oriental, roots 0.300000 1.000 1.000 

01013270 1AB Rutabaga 0.300000 1.000 1.000 

01013310 1AB Salsify, roots 0.300000 1.000 1.000 

01033660 1CD Sweet potato 0.200000 1.000 1.000 

01033661 1CD Sweet potato-babyfood 0.200000 1.000 1.000 

01033710 1CD Tanier, corm 0.200000 1.000 1.000 

01033870 1CD Turmeric 0.200000 1.000 1.000 

01013880 1AB Turnip, roots 0.300000 1.000 1.000 

01034060 1CD Yam, true 0.200000 1.000 1.000 

01034070 1CD Yam bean 0.200000 1.000 1.000 

02000510 2 Beet, garden, tops 1.800000 1.000 1.000 1E7898

03001640 3 Garlic 0.100000 1.000 1.000 

03001650 3 Garlic, dried 0.100000 9.000 1.000 

03001651 3 Garlic, dried-babyfood 0.100000 9.000 1.000 

03001980 3 Leek 2.000000 1.000 1.000 

03002370 3 Onion, dry bulb 0.100000 1.000 1.000 PP#9E7

 Full comment: PP#9E7607

03002371 3 Onion, dry bulb-babyfood 0.100000 1.000 1.000 PP#9E7

 Full comment: PP#9E7607

03002380 3 Onion, dry bulb, dried 0.100000 9.000 1.000 PP#9E7

 Full comment: PP#9E7607

03002381 3 Onion, dry bulb, dried-babyfood 0.100000 9.000 1.000 PP#9E7

 Full comment: PP#9E7607

03002390 3 Onion, green 2.000000 1.000 1.000 PP#9E7

 Full comment: PP#9E7607

03003380 3 Shallot 2.000000 1.000 1.000 

04020760 4B Cardoon 0.100000 1.000 1.000 

04020850 4B Celery 0.100000 1.000 1.000 

04020851 4B Celery-babyfood 0.100000 1.000 1.000 

04020860 4B Celery, juice 0.100000 1.000 1.000 

04020870 4B Celtuce 0.100000 1.000 1.000 

04021520 4B Fennel, Florence 0.100000 1.000 1.000 

04012050 4A Lettuce, leaf 0.500000 1.000 1.000 

04023220 4B Rhubarb 0.100000 1.000 1.000 

04013550 4A Spinach 0.500000 1.000 1.000 

04013551 4A Spinach-babyfood 0.500000 1.000 1.000 

04023670 4B Swiss chard 0.100000 1.000 1.000 

05010610 5A Broccoli 0.600000 1.000 1.000 

05010611 5A Broccoli-babyfood 0.600000 1.000 1.000 

05010620 5A Broccoli, Chinese 0.600000 1.000 1.000 

05020630 5B Broccoli raab 1.800000 1.000 1.000 PP#6E7

 Full comment: PP#6E7607

05010640 5A Brussels sprouts 0.600000 1.000 1.000 

05010690 5A Cabbage 0.600000 1.000 1.000 

05020700 5B Cabbage, Chinese, bok choy 1.800000 1.000 1.000 PP#6E7

 Full comment: PP#6E7607

05010710 5A Cabbage, Chinese, napa 0.600000 1.000 1.000 

05010720 5A Cabbage, Chinese, mustard 0.600000 1.000 1.000 

05010830 5A Cauliflower 0.600000 1.000 1.000 

05021170 5B Collards 1.800000 1.000 1.000 PP#6E7

 Full comment: PP#6E7607

05021940 5B Kale 1.800000 1.000 1.000 PP#6E7

 Full comment: PP#6E7607

05011960 5A Kohlrabi 0.600000 1.000 1.000 

05022290 5B Mustard greens 1.800000 1.000 1.000 PP#9E7

 Full comment: PP#9E7607

05023180 5B Rape greens 1.800000 1.000 1.000 PP#9E7

 Full comment: PP#9E7607

05023890 5B Turnip, greens 1.800000 1.000 1.000 PP#9E7

 Full comment: PP#9E7607

06030300 6C Bean, black, seed 0.300000 1.000 1.000 

06020310 6B Bean, broad, succulent 0.300000 1.000 1.000 Additi
S-Metolachlor Dietary Exposure and Risk Assessment DP # D396451 

Page 15 of 27

 Full comment: Additional data required.

06030320 6C Bean, broad, seed 0.300000 1.000 1.000 

06020330 6B Bean, cowpea, succulent 0.300000 1.000 1.000 Additi

 Full comment: Additional data required.

06030340 6C Bean, cowpea, seed 0.300000 1.000 1.000 

06030350 6C Bean, great northern, seed 0.300000 1.000 1.000 

06030360 6C Bean, kidney, seed 0.300000 1.000 1.000 

06020370 6B Bean, lima, succulent 0.300000 1.000 1.000 Additi

 Full comment: Additional data required.

06030380 6C Bean, lima, seed 0.300000 1.000 1.000 

06030390 6C Bean, mung, seed 0.300000 1.000 1.000 

06030400 6C Bean, navy, seed 0.300000 1.000 1.000 

06030410 6C Bean, pink, seed 0.300000 1.000 1.000 

06030420 6C Bean, pinto, seed 0.300000 1.000 1.000 

06010430 6A Bean, snap, succulent 0.300000 1.000 1.000 Additi

 Full comment: Additional data required.

06010431 6A Bean, snap, succulent-babyfood 0.300000 1.000 1.000 Additi

 Full comment: Additional data required.

06030980 6C Chickpea, seed 0.300000 1.000 1.000 

06030981 6C Chickpea, seed-babyfood 0.300000 1.000 1.000 

06030990 6C Chickpea, flour 0.300000 1.000 1.000 

06031820 6C Guar, seed 0.300000 1.000 1.000 

06031821 6C Guar, seed-babyfood 0.300000 1.000 1.000 

06032030 6C Lentil, seed 0.300000 1.000 1.000 

06022550 6B Pea, succulent 0.300000 1.000 1.000 Additi

 Full comment: Additional data required.

06022551 6B Pea, succulent-babyfood 0.300000 1.000 1.000 Additi

 Full comment: Additional data required.

06032560 6C Pea, dry 0.300000 1.000 1.000 

06032561 6C Pea, dry-babyfood 0.300000 1.000 1.000 

06012570 6A Pea, edible podded, succulent 0.300000 1.000 1.000 Additi

 Full comment: Additional data required.

06032580 6C Pea, pigeon, seed 0.300000 1.000 1.000 

06022590 6B Pea, pigeon, succulent 0.300000 1.000 1.000 Additi

 Full comment: Additional data required.

06003470 6 Soybean, seed 0.300000 1.000 1.000 

06003480 6 Soybean, flour 0.300000 1.000 1.000 

06003481 6 Soybean, flour-babyfood 0.300000 1.000 1.000 

06003490 6 Soybean, soy milk 0.300000 1.000 1.000 

06003491 6 Soybean, soy milk-babyfood or in 0.300000 1.000 1.000 

06003500 6 Soybean, oil 0.300000 1.000 1.000 

06003501 6 Soybean, oil-babyfood 0.300000 1.000 1.000 

08001480 8 Eggplant 0.100000 1.000 1.000 

08002340 8 Okra 0.500000 1.000 1.000 PP#6E7

 Full comment: PP#6E7607

08002700 8 Pepper, bell 0.100000 1.000 1.000 

08002701 8 Pepper, bell-babyfood 0.100000 1.000 1.000 

08002710 8 Pepper, bell, dried 0.100000 1.000 1.000 

08002711 8 Pepper, bell, dried-babyfood 0.100000 1.000 1.000 

08002720 8 Pepper, nonbell 0.500000 1.000 1.000 Tabasc

 Full comment: Tabasco peppers @ 0.5 ppm

08002721 8 Pepper, nonbell-babyfood 0.500000 1.000 1.000 Tabasc

 Full comment: Tabasco peppers @ 0.5 ppm

08002730 8 Pepper, nonbell, dried 0.500000 1.000 1.000 Tabasc

 Full comment: Tabasco peppers @ 0.5 ppm

08003740 8 Tomatillo 0.100000 1.000 1.000 

08003750 8 Tomato 0.100000 1.000 1.000 

08003751 8 Tomato-babyfood 0.100000 1.000 1.000 

08003760 8 Tomato, paste 0.300000 5.400 1.000 

08003761 8 Tomato, paste-babyfood 0.300000 5.400 1.000 

08003770 8 Tomato, puree 0.100000 3.300 1.000 

08003771 8 Tomato, puree-babyfood 0.100000 3.300 1.000 

08003780 8 Tomato, dried 0.100000 14.300 1.000 
S-Metolachlor Dietary Exposure and Risk Assessment DP # D396451 

Page 16 of 27

08003781 8 Tomato, dried-babyfood 0.100000 14.300 1.000 

08003790 8 Tomato, juice 0.100000 1.500 1.000 

09010750 9A Cantaloupe 0.100000 1.000 1.000 PP#6E7

 Full comment: PP#6E7607

09010800 9A Casaba 0.100000 1.000 1.000 PP#6E7

 Full comment: PP#6E7607

09021350 9B Cucumber 0.130000 1.000 1.000 PP#6E7

 Full comment: PP#6E7607

09011870 9A Honeydew melon 0.100000 1.000 1.000 PP#6E7

 Full comment: PP#6E7607

09023080 9B Pumpkin 0.100000 1.000 1.000 

09023090 9B Pumpkin, seed 0.100000 1.000 1.000 

09023570 9B Squash, winter 0.100000 1.000 1.000 

09023571 9B Squash, winter-babyfood 0.100000 1.000 1.000 

09013990 9A Watermelon 0.100000 1.000 1.000 PP#6E7

 Full comment: PP#6E7607

09014000 9A Watermelon, juice 0.100000 1.000 1.000 PP#6E7

 Full comment: PP#6E7607

13010550 13A Blackberry 0.100000 1.000 1.000 PP#6E7

 Full comment: PP#6E7607

13010560 13A Blackberry, juice 0.100000 1.000 1.000 PP#6E7

 Full comment: PP#6E7607

13010561 13A Blackberry, juice-babyfood

 240-Cooked; Canned; Cook Meth N/S

 0.100000 1.000 1.000 PP#6E7

 Full comment: PP#6E7607

13020570 13B Blueberry 0.150000 1.000 1.000 PP#6E7

 Full comment: PP#6E7607

13020571 13B Blueberry-babyfood 0.150000 1.000 1.000 PP#6E7

 Full comment: PP#6E7607

13010580 13A Boysenberry 0.100000 1.000 1.000 PP#6E7

 Full comment: PP#6E7607

13021360 13B Currant 0.150000 1.000 1.000 PP#6E7

 Full comment: PP#6E7607

13021370 13B Currant, dried 0.150000 1.000 1.000 PP#6E7

 Full comment: PP#6E7607

13011420 13A Dewberry 0.100000 1.000 1.000 PP#6E7

 Full comment: PP#6E7607

13021490 13B Elderberry 0.150000 1.000 1.000 PP#6E7

 Full comment: PP#6E7607

13021740 13B Gooseberry 0.150000 1.000 1.000 PP#6E7

 Full comment: PP#6E7607

13021910 13B Huckleberry 0.150000 1.000 1.000 PP#6E7

 Full comment: PP#6E7607

13012080 13A Loganberry 0.100000 1.000 1.000 PP#6E7

 Full comment: PP#6E7607

13013200 13A Raspberry 0.100000 1.000 1.000 PP#6E7

 Full comment: PP#6E7607

13013201 13A Raspberry-babyfood 0.100000 1.000 1.000 PP#6E7

 Full comment: PP#6E7607

13013210 13A Raspberry, juice 0.100000 1.000 1.000 PP#6E7

 Full comment: PP#6E7607

13013211 13A Raspberry, juice-babyfood 0.100000 1.000 1.000 PP#6E7

 Full comment: PP#6E7607

14000030 14 Almond 0.100000 1.000 1.000 

14000031 14 Almond-babyfood 0.100000 1.000 1.000 

14000040 14 Almond, oil 0.100000 1.000 1.000 

14000041 14 Almond, oil-babyfood 0.100000 1.000 1.000 

14000590 14 Brazil nut 0.100000 1.000 1.000 

14000680 14 Butternut 0.100000 1.000 1.000 

14000810 14 Cashew 0.100000 1.000 1.000 

14000920 14 Chestnut 0.100000 1.000 1.000 

14001550 14 Filbert 0.100000 1.000 1.000 
S-Metolachlor Dietary Exposure and Risk Assessment DP # D396451 

Page 17 of 27

14001560 14 Filbert, oil 0.100000 1.000 1.000 

14001850 14 Hickory nut 0.100000 1.000 1.000 

14002130 14 Macadamia nut 0.100000 1.000 1.000 

14002690 14 Pecan 0.100000 1.000 1.000 

14002820 14 Pistachio 0.100000 1.000 1.000 

14003910 14 Walnut 0.100000 1.000 1.000 

15000250 15 Barley, pearled barley 0.100000 1.000 1.000 

15000251 15 Barley, pearled barley-babyfood 0.100000 1.000 1.000 

15000260 15 Barley, flour 0.100000 1.000 1.000 

15000261 15 Barley, flour-babyfood 0.100000 1.000 1.000 

15000270 15 Barley, bran 0.100000 1.000 1.000 

15000650 15 Buckwheat 0.100000 1.000 1.000 Additi

 Full comment: Additional data required.

15000660 15 Buckwheat, flour 0.100000 1.000 1.000 Additi

 Full comment: Additional data required.

15001200 15 Corn, field, flour 0.100000 1.000 1.000 

15001201 15 Corn, field, flour-babyfood 0.100000 1.000 1.000 

15001210 15 Corn, field, meal 0.100000 1.000 1.000 

15001211 15 Corn, field, meal-babyfood 0.100000 1.000 1.000 

15001220 15 Corn, field, bran 0.100000 1.000 1.000 

15001230 15 Corn, field, starch 0.100000 1.000 1.000 

15001231 15 Corn, field, starch-babyfood 0.100000 1.000 1.000 

15001240 15 Corn, field, syrup 0.100000 1.500 1.000 

15001241 15 Corn, field, syrup-babyfood 0.100000 1.500 1.000 

15001250 15 Corn, field, oil 0.100000 1.000 1.000 

15001251 15 Corn, field, oil-babyfood 0.100000 1.000 1.000 

15001260 15 Corn, pop 0.100000 1.000 1.000 

15001270 15 Corn, sweet 0.100000 1.000 1.000 

15001271 15 Corn, sweet-babyfood 0.100000 1.000 1.000 

15002260 15 Millet, grain 0.100000 1.000 1.000 

15002310 15 Oat, bran 0.100000 1.000 1.000 

15002320 15 Oat, flour 0.100000 1.000 1.000 

15002321 15 Oat, flour-babyfood 0.100000 1.000 1.000 

15002330 15 Oat, groats/rolled oats 0.100000 1.000 1.000 

15002331 15 Oat, groats/rolled oats-babyfood 0.100000 1.000 1.000 

15003230 15 Rice, white 0.100000 1.000 1.000 

15003231 15 Rice, white-babyfood 0.100000 1.000 1.000 

15003240 15 Rice, brown 0.100000 1.000 1.000 

15003241 15 Rice, brown-babyfood 0.100000 1.000 1.000 

15003250 15 Rice, flour 0.100000 1.000 1.000 

15003251 15 Rice, flour-babyfood 0.100000 1.000 1.000 

15003260 15 Rice, bran 0.100000 1.000 1.000 

15003261 15 Rice, bran-babyfood 0.100000 1.000 1.000 

15003280 15 Rye, grain 0.100000 1.000 1.000 

15003290 15 Rye, flour 0.100000 1.000 1.000 

15003440 15 Sorghum, grain 0.300000 1.000 1.000 PP#9E7

 Full comment: PP#9E7607

15003450 15 Sorghum, syrup 4.000000 1.000 1.000 PP#9E7

 Full comment: PP#9E7607

15003810 15 Triticale, flour 0.100000 1.000 1.000 

15003811 15 Triticale, flour-babyfood 0.100000 1.000 1.000 

15004010 15 Wheat, grain 0.100000 1.000 1.000 

15004011 15 Wheat, grain-babyfood 0.100000 1.000 1.000 

15004020 15 Wheat, flour 0.100000 1.000 1.000 

15004021 15 Wheat, flour-babyfood 0.100000 1.000 1.000 

15004030 15 Wheat, germ 0.100000 1.000 1.000 

15004040 15 Wheat, bran 0.100000 1.000 1.000 

15004050 15 Wild rice 0.100000 1.000 1.000 

19011030 19A Chive 2.000000 1.000 1.000 

19011180 19A Coriander, leaves 8.000000 1.000 1.000 1E7898

19011181 19A Coriander, leaves-babyfood 8.000000 1.000 1.000 1E7898

19021190 19B Coriander, seed 0.130000 1.000 1.000 1E7898

19021191 19B Coriander, seed-babyfood 0.130000 1.000 1.000 1E7898
S-Metolachlor Dietary Exposure and Risk Assessment DP # D396451 

Page 18 of 27

19011440 19A Dillweed 0.500000 1.000 1.000 
S-Metolachlor Dietary Exposure and Risk Assessment DP # D396451 

Page 19 of 27

Attachment 2. Results of Acute DEEM-FCID Dietary Exposure Analysis

California Department of Pesticide Regulation Ver. 2.10

DEEM-FCID ACUTE Analysis for METOLACHLOR AND S-METOLACHLOR (1994-98 data)

Residue file: 108800a_rad.R98 Adjustment factor #2 NOT used.

Analysis Date: 12-12-2011/10:27:42 Residue file dated: 12-12-2011/09:22:54/14

NOEL (Acute) = 300.000000 mg/kg body-wt/day

Run Comment: ""

===============================================================================

Summary calculations--per capita:

--- 95th Percentile---- --- 99th Percentile---- ---99.9th Percentile----

Exposure % aRfD MOE Exposure % aRfD MOE Exposure % aRfD MOE 

---------- ------- -------- ---------- ------- -------- ---------- ------- --------

U.S. Population:

 0.014688 0.49 20424 0.025201 0.84 11904 0.045781 1.53 6552 

All infants:

 0.046244 1.54 6487 0.065073 2.17 4610 0.113186 3.77 2650 

Children 1-2 yrs:

 0.025061 0.84 11970 0.037494 1.25 8001 0.053742 1.79 5582 

Children 3-5 yrs:

 0.022362 0.75 13415 0.031735 1.06 9453 0.055918 1.86 5364 

Children 6-12 yrs:

 0.015532 0.52 19314 0.023518 0.78 12756 0.031437 1.05 9542 

Youth 13-19 yrs:

 0.011553 0.39 25967 0.019123 0.64 15688 0.034214 1.14 8768 

Adults 20-49 yrs:

 0.012690 0.42 23641 0.019849 0.66 15114 0.034828 1.16 8613 

Adults 50+ yrs:

 0.011471 0.38 26152 0.016069 0.54 18669 0.025954 0.87 11558 

Females 13-49 yrs:

 0.012602 0.42 23804 0.019466 0.65 15411 0.034625 1.15 8664 
S-Metolachlor Dietary Exposure and Risk Assessment DP # D396451 

Page 20 of 27

Attachment 3. Chronic DEEM-FCID Residue Input File

Filename: F:\telework\s-metolachlor2011\108800c_rad.R98

Chemical: Metolachlor and S-metolachlor

RfD(Chronic): .1 mg/kg bw/day NOEL(Chronic): 9.7 mg/kg bw/day

RfD(Acute): 3 mg/kg bw/day NOEL(Acute): 300 mg/kg bw/day

Date created/last modified: 12-12-2011/09:24:01/14 Program ver. 2.10

--------------------------------------------------------------------------------

 EPA Crop Def Res Adj.Factors Comment

 Code Grp Commodity Name (ppm) #1 #2 

-------- ---- ------------------------------- ---------- ------ ------ -------

95000190 O Asparagus 0.100000 1.000 1.000 

95001280 O Cottonseed, oil 0.100000 1.000 1.000 

95001281 O Cottonseed, oil-babyfood 0.100000 1.000 1.000 

95002630 O Peanut 0.200000 1.000 1.000 

95002640 O Peanut, butter 0.200000 1.890 1.000 

95002650 O Peanut, oil 0.200000 1.000 1.000 

95003360 O Sesame, seed 0.130000 1.000 1.000 PP#6E7

 Full comment: PP#6E7607

95003361 O Sesame, seed-babyfood 0.130000 1.000 1.000 PP#6E7

 Full comment: PP#6E7607

95003370 O Sesame, oil 0.130000 1.000 1.000 PP#6E7

 Full comment: PP#6E7607

95003371 O Sesame, oil-babyfood 0.130000 1.000 1.000 PP#6E7

 Full comment: PP#6E7607

86010000 O Water, direct, all sources 0.126000 1.000 1.000 

86020000 O Water, indirect, all sources 0.126000 1.000 1.000 

21000440 M Beef, meat 0.020000 1.000 1.000 

21000441 M Beef, meat-babyfood 0.020000 1.000 1.000 

21000450 M Beef, meat, dried 0.020000 1.920 1.000 

21000460 M Beef, meat byproducts 0.040000 1.000 1.000 

21000461 M Beef, meat byproducts-babyfood 0.040000 1.000 1.000 

21000470 M Beef, fat 0.020000 1.000 1.000 

21000471 M Beef,fat-babyfood 0.020000 1.000 1.000 

21000480 M Beef, kidney 0.200000 1.000 1.000 

21000490 M Beef, liver 0.050000 1.000 1.000 

21000491 M Beef, liver-babyfood 0.050000 1.000 1.000 

23001690 M Goat, meat 0.020000 1.000 1.000 

23001700 M Goat, meat byproducts 0.040000 1.000 1.000 

23001710 M Goat, fat 0.020000 1.000 1.000 

23001720 M Goat, kidney 0.200000 1.000 1.000 

23001730 M Goat, liver 0.050000 1.000 1.000 

24001890 M Horse, meat 0.020000 1.000 1.000 

26003390 M Sheep, meat 0.020000 1.000 1.000 

26003391 M Sheep, meat-babyfood 0.020000 1.000 1.000 

26003400 M Sheep, meat byproducts 0.040000 1.000 1.000 

26003410 M Sheep, fat 0.020000 1.000 1.000 

26003411 M Sheep, fat-babyfood 0.020000 1.000 1.000 

26003420 M Sheep, kidney 0.200000 1.000 1.000 

26003430 M Sheep, liver 0.050000 1.000 1.000 

40000930 P Chicken, meat 0.020000 1.000 1.000 

40000931 P Chicken, meat-babyfood 0.020000 1.000 1.000 

40000940 P Chicken, liver 0.050000 1.000 1.000 

40000950 P Chicken, meat byproducts 0.050000 1.000 1.000 

40000951 P Chicken, meat byproducts-babyfoo 0.050000 1.000 1.000 

40000960 P Chicken, fat 0.020000 1.000 1.000 

40000961 P Chicken, fat-babyfood 0.020000 1.000 1.000 

40000970 P Chicken, skin 0.050000 1.000 1.000 

40000971 P Chicken, skin-babyfood 0.050000 1.000 1.000 

70001450 P Egg, whole 0.020000 1.000 1.000 

70001451 P Egg, whole-babyfood 0.020000 1.000 1.000 

70001460 P Egg, white 0.020000 1.000 1.000 
S-Metolachlor Dietary Exposure and Risk Assessment DP # D396451 

Page 21 of 27

70001461 P Egg, white (solids)-babyfood 0.020000 1.000 1.000 

70001470 P Egg, yolk 0.020000 1.000 1.000 

70001471 P Egg, yolk-babyfood 0.020000 1.000 1.000 

60003010 P Poultry, other, meat 0.020000 1.000 1.000 

60003020 P Poultry, other, liver 0.050000 1.000 1.000 

60003030 P Poultry, other, meat byproducts 0.050000 1.000 1.000 

60003040 P Poultry, other, fat 0.020000 1.000 1.000 

60003050 P Poultry, other, skin 0.050000 1.000 1.000 

50003820 P Turkey, meat 0.020000 1.000 1.000 

50003821 P Turkey, meat-babyfood 0.020000 1.000 1.000 

50003830 P Turkey, liver 0.050000 1.000 1.000 

50003831 P Turkey, liver-babyfood 0.050000 1.000 1.000 

50003840 P Turkey, meat byproducts 0.050000 1.000 1.000 

50003841 P Turkey, meat byproducts-babyfood 0.050000 1.000 1.000 

50003850 P Turkey, fat 0.020000 1.000 1.000 

50003851 P Turkey, fat-babyfood 0.020000 1.000 1.000 

50003860 P Turkey, skin 0.050000 1.000 1.000 

50003861 P Turkey, skin-babyfood 0.050000 1.000 1.000 

27002220 D Milk, fat 0.020000 1.000 1.000 

27002221 D Milk, fat - baby food/infant for 0.020000 1.000 1.000 

27012230 D Milk, nonfat solids 0.020000 1.000 1.000 

27012231 D Milk, nonfat solids-baby food/in 0.020000 1.000 1.000 

27022240 D Milk, water 0.020000 1.000 1.000 

27022241 D Milk, water-babyfood/infant form 0.020000 1.000 1.000 

27032251 D Milk, sugar (lactose)-baby food/ 0.020000 1.000 1.000 

01030150 1CD Arrowroot, flour 0.200000 1.000 1.000 

01030151 1CD Arrowroot, flour-babyfood 0.200000 1.000 1.000 

01030170 1CD Artichoke, Jerusalem 0.200000 1.000 1.000 

01010500 1AB Beet, garden, roots 0.300000 1.000 1.000 

01010501 1AB Beet, garden, roots-babyfood 0.300000 1.000 1.000 

01010520 1A Beet, sugar 0.500000 1.000 1.000 

01010521 1A Beet, sugar-babyfood 0.500000 1.000 1.000 

01010530 1A Beet, sugar, molasses 2.000000 1.000 1.000 

01010531 1A Beet, sugar, molasses-babyfood 2.000000 1.000 1.000 

01010670 1AB Burdock 0.300000 1.000 1.000 

01010780 1AB Carrot 0.400000 1.000 1.000 PP#9E7

 Full comment: PP#9E7607

01010781 1AB Carrot-babyfood 0.400000 1.000 1.000 PP#9E7

 Full comment: PP#9E7607

01010790 1AB Carrot, juice 0.400000 1.000 1.000 PP#9E7

 Full comment: PP#9E7607

01030820 1CD Cassava 0.200000 1.000 1.000 

01030821 1CD Cassava-babyfood 0.200000 1.000 1.000 

01010840 1AB Celeriac 0.300000 1.000 1.000 

01011000 1AB Chicory, roots 0.300000 1.000 1.000 

01031390 1CD Dasheen, corm 0.200000 1.000 1.000 

01031660 1CD Ginger 0.200000 1.000 1.000 

01031661 1CD Ginger-babyfood 0.200000 1.000 1.000 

01031670 1CD Ginger, dried 0.200000 1.000 1.000 

01011680 1AB Ginseng, dried 0.300000 1.000 1.000 

01011900 1AB Horseradish 0.300000 1.000 1.000 

01012500 1AB Parsley, turnip rooted 0.300000 1.000 1.000 

01012510 1AB Parsnip 0.300000 1.000 1.000 

01012511 1AB Parsnip-babyfood 0.300000 1.000 1.000 

01032960 1C Potato, chips 0.200000 1.000 1.000 

01032970 1C Potato, dry (granules/ flakes) 0.200000 6.500 1.000 

01032971 1C Potato, dry (granules/ flakes)-b 0.200000 6.500 1.000 

01032980 1C Potato, flour 0.200000 6.500 1.000 

01032981 1C Potato, flour-babyfood 0.200000 1.000 1.000 

01032990 1C Potato, tuber, w/peel 0.200000 1.000 1.000 

01032991 1C Potato, tuber, w/peel-babyfood 0.200000 1.000 1.000 

01033000 1C Potato, tuber, w/o peel 0.200000 1.000 1.000 

01033001 1C Potato, tuber, w/o peel-babyfood 0.200000 1.000 1.000 
S-Metolachlor Dietary Exposure and Risk Assessment DP # D396451 

Page 22 of 27

01013140 1AB Radish, roots 0.300000 1.000 1.000 

01013160 1AB Radish, Oriental, roots 0.300000 1.000 1.000 

01013270 1AB Rutabaga 0.300000 1.000 1.000 

01013310 1AB Salsify, roots 0.300000 1.000 1.000 

01033660 1CD Sweet potato 0.200000 1.000 1.000 

01033661 1CD Sweet potato-babyfood 0.200000 1.000 1.000 

01033710 1CD Tanier, corm 0.200000 1.000 1.000 

01033870 1CD Turmeric 0.200000 1.000 1.000 

01013880 1AB Turnip, roots 0.300000 1.000 1.000 

01034060 1CD Yam, true 0.200000 1.000 1.000 

01034070 1CD Yam bean 0.200000 1.000 1.000 

02000510 2 Beet, garden, tops 1.800000 1.000 1.000 1E7898

03001640 3 Garlic 0.100000 1.000 1.000 

03001650 3 Garlic, dried 0.100000 9.000 1.000 

03001651 3 Garlic, dried-babyfood 0.100000 9.000 1.000 

03001980 3 Leek 2.000000 1.000 1.000 

03002370 3 Onion, dry bulb 0.100000 1.000 1.000 PP#9E7

 Full comment: PP#9E7607

03002371 3 Onion, dry bulb-babyfood 0.100000 1.000 1.000 PP#9E7

 Full comment: PP#9E7607

03002380 3 Onion, dry bulb, dried 0.100000 9.000 1.000 PP#9E7

 Full comment: PP#9E7607

03002381 3 Onion, dry bulb, dried-babyfood 0.100000 9.000 1.000 PP#9E7

 Full comment: PP#9E7607

03002390 3 Onion, green 2.000000 1.000 1.000 PP#9E7

 Full comment: PP#9E7607

03003380 3 Shallot 2.000000 1.000 1.000 

04020760 4B Cardoon 0.100000 1.000 1.000 

04020850 4B Celery 0.100000 1.000 1.000 

04020851 4B Celery-babyfood 0.100000 1.000 1.000 

04020860 4B Celery, juice 0.100000 1.000 1.000 

04020870 4B Celtuce 0.100000 1.000 1.000 

04021520 4B Fennel, Florence 0.100000 1.000 1.000 

04012050 4A Lettuce, leaf 0.500000 1.000 1.000 

04023220 4B Rhubarb 0.100000 1.000 1.000 

04013550 4A Spinach 0.500000 1.000 1.000 

04013551 4A Spinach-babyfood 0.500000 1.000 1.000 

04023670 4B Swiss chard 0.100000 1.000 1.000 

05010610 5A Broccoli 0.600000 1.000 1.000 

05010611 5A Broccoli-babyfood 0.600000 1.000 1.000 

05010620 5A Broccoli, Chinese 0.600000 1.000 1.000 

05020630 5B Broccoli raab 1.800000 1.000 1.000 PP#6E7

 Full comment: PP#6E7607

05010640 5A Brussels sprouts 0.600000 1.000 1.000 

05010690 5A Cabbage 0.600000 1.000 1.000 

05020700 5B Cabbage, Chinese, bok choy 1.800000 1.000 1.000 PP#6E7

 Full comment: PP#6E7607

05010710 5A Cabbage, Chinese, napa 0.600000 1.000 1.000 

05010720 5A Cabbage, Chinese, mustard 0.600000 1.000 1.000 

05010830 5A Cauliflower 0.600000 1.000 1.000 

05021170 5B Collards 1.800000 1.000 1.000 PP#6E7

 Full comment: PP#6E7607

05021940 5B Kale 1.800000 1.000 1.000 PP#6E7

 Full comment: PP#6E7607

05011960 5A Kohlrabi 0.600000 1.000 1.000 

05022290 5B Mustard greens 1.800000 1.000 1.000 PP#9E7

 Full comment: PP#9E7607

05023180 5B Rape greens 1.800000 1.000 1.000 PP#9E7

 Full comment: PP#9E7607

05023890 5B Turnip, greens 1.800000 1.000 1.000 PP#9E7

 Full comment: PP#9E7607

06030300 6C Bean, black, seed 0.300000 1.000 1.000 

06020310 6B Bean, broad, succulent 0.300000 1.000 1.000 Additi
S-Metolachlor Dietary Exposure and Risk Assessment DP # D396451 

Page 23 of 27

 Full comment: Additional data required.

06030320 6C Bean, broad, seed 0.300000 1.000 1.000 

06020330 6B Bean, cowpea, succulent 0.300000 1.000 1.000 Additi

 Full comment: Additional data required.

06030340 6C Bean, cowpea, seed 0.300000 1.000 1.000 

06030350 6C Bean, great northern, seed 0.300000 1.000 1.000 

06030360 6C Bean, kidney, seed 0.300000 1.000 1.000 

06020370 6B Bean, lima, succulent 0.300000 1.000 1.000 Additi

 Full comment: Additional data required.

06030380 6C Bean, lima, seed 0.300000 1.000 1.000 

06030390 6C Bean, mung, seed 0.300000 1.000 1.000 

06030400 6C Bean, navy, seed 0.300000 1.000 1.000 

06030410 6C Bean, pink, seed 0.300000 1.000 1.000 

06030420 6C Bean, pinto, seed 0.300000 1.000 1.000 

06010430 6A Bean, snap, succulent 0.300000 1.000 1.000 Additi

 Full comment: Additional data required.

06010431 6A Bean, snap, succulent-babyfood 0.300000 1.000 1.000 Additi

 Full comment: Additional data required.

06030980 6C Chickpea, seed 0.300000 1.000 1.000 

06030981 6C Chickpea, seed-babyfood 0.300000 1.000 1.000 

06030990 6C Chickpea, flour 0.300000 1.000 1.000 

06031820 6C Guar, seed 0.300000 1.000 1.000 

06031821 6C Guar, seed-babyfood 0.300000 1.000 1.000 

06032030 6C Lentil, seed 0.300000 1.000 1.000 

06022550 6B Pea, succulent 0.300000 1.000 1.000 Additi

 Full comment: Additional data required.

06022551 6B Pea, succulent-babyfood 0.300000 1.000 1.000 Additi

 Full comment: Additional data required.

06032560 6C Pea, dry 0.300000 1.000 1.000 

06032561 6C Pea, dry-babyfood 0.300000 1.000 1.000 

06012570 6A Pea, edible podded, succulent 0.300000 1.000 1.000 Additi

 Full comment: Additional data required.

06032580 6C Pea, pigeon, seed 0.300000 1.000 1.000 

06022590 6B Pea, pigeon, succulent 0.300000 1.000 1.000 Additi

 Full comment: Additional data required.

06003470 6 Soybean, seed 0.300000 1.000 1.000 

06003480 6 Soybean, flour 0.300000 1.000 1.000 

06003481 6 Soybean, flour-babyfood 0.300000 1.000 1.000 

06003490 6 Soybean, soy milk 0.300000 1.000 1.000 

06003491 6 Soybean, soy milk-babyfood or in 0.300000 1.000 1.000 

06003500 6 Soybean, oil 0.300000 1.000 1.000 

06003501 6 Soybean, oil-babyfood 0.300000 1.000 1.000 

08001480 8 Eggplant 0.100000 1.000 1.000 

08002340 8 Okra 0.500000 1.000 1.000 PP#6E7

 Full comment: PP#6E7607

08002700 8 Pepper, bell 0.100000 1.000 1.000 

08002701 8 Pepper, bell-babyfood 0.100000 1.000 1.000 

08002710 8 Pepper, bell, dried 0.100000 1.000 1.000 

08002711 8 Pepper, bell, dried-babyfood 0.100000 1.000 1.000 

08002720 8 Pepper, nonbell 0.500000 1.000 1.000 Tabasc

 Full comment: Tabasco peppers @ 0.5 ppm

08002721 8 Pepper, nonbell-babyfood 0.500000 1.000 1.000 Tabasc

 Full comment: Tabasco peppers @ 0.5 ppm

08002730 8 Pepper, nonbell, dried 0.500000 1.000 1.000 Tabasc

 Full comment: Tabasco peppers @ 0.5 ppm

08003740 8 Tomatillo 0.100000 1.000 1.000 

08003750 8 Tomato 0.100000 1.000 1.000 

08003751 8 Tomato-babyfood 0.100000 1.000 1.000 

08003760 8 Tomato, paste 0.300000 5.400 1.000 

08003761 8 Tomato, paste-babyfood 0.300000 5.400 1.000 

08003770 8 Tomato, puree 0.100000 3.300 1.000 

08003771 8 Tomato, puree-babyfood 0.100000 3.300 1.000 

08003780 8 Tomato, dried 0.100000 14.300 1.000 
S-Metolachlor Dietary Exposure and Risk Assessment DP # D396451 

Page 24 of 27

08003781 8 Tomato, dried-babyfood 0.100000 14.300 1.000 

08003790 8 Tomato, juice 0.100000 1.500 1.000 

09010750 9A Cantaloupe 0.100000 1.000 1.000 PP#6E7

 Full comment: PP#6E7607

09010800 9A Casaba 0.100000 1.000 1.000 PP#6E7

 Full comment: PP#6E7607

09021350 9B Cucumber 0.130000 1.000 1.000 PP#6E7

 Full comment: PP#6E7607

09011870 9A Honeydew melon 0.100000 1.000 1.000 PP#6E7

 Full comment: PP#6E7607

09023080 9B Pumpkin 0.100000 1.000 1.000 

09023090 9B Pumpkin, seed 0.100000 1.000 1.000 

09023570 9B Squash, winter 0.100000 1.000 1.000 

09023571 9B Squash, winter-babyfood 0.100000 1.000 1.000 

09013990 9A Watermelon 0.100000 1.000 1.000 PP#6E7

 Full comment: PP#6E7607

09014000 9A Watermelon, juice 0.100000 1.000 1.000 PP#6E7

 Full comment: PP#6E7607

13010550 13A Blackberry 0.100000 1.000 1.000 PP#6E7

 Full comment: PP#6E7607

13010560 13A Blackberry, juice 0.100000 1.000 1.000 PP#6E7

 Full comment: PP#6E7607

13010561 13A Blackberry, juice-babyfood

 240-Cooked; Canned; Cook Meth N/S

 0.100000 1.000 1.000 PP#6E7

 Full comment: PP#6E7607

13020570 13B Blueberry 0.150000 1.000 1.000 PP#6E7

 Full comment: PP#6E7607

13020571 13B Blueberry-babyfood 0.150000 1.000 1.000 PP#6E7

 Full comment: PP#6E7607

13010580 13A Boysenberry 0.100000 1.000 1.000 PP#6E7

 Full comment: PP#6E7607

13021360 13B Currant 0.150000 1.000 1.000 PP#6E7

 Full comment: PP#6E7607

13021370 13B Currant, dried 0.150000 1.000 1.000 PP#6E7

 Full comment: PP#6E7607

13011420 13A Dewberry 0.100000 1.000 1.000 PP#6E7

 Full comment: PP#6E7607

13021490 13B Elderberry 0.150000 1.000 1.000 PP#6E7

 Full comment: PP#6E7607

13021740 13B Gooseberry 0.150000 1.000 1.000 PP#6E7

 Full comment: PP#6E7607

13021910 13B Huckleberry 0.150000 1.000 1.000 PP#6E7

 Full comment: PP#6E7607

13012080 13A Loganberry 0.100000 1.000 1.000 PP#6E7

 Full comment: PP#6E7607

13013200 13A Raspberry 0.100000 1.000 1.000 PP#6E7

 Full comment: PP#6E7607

13013201 13A Raspberry-babyfood 0.100000 1.000 1.000 PP#6E7

 Full comment: PP#6E7607

13013210 13A Raspberry, juice 0.100000 1.000 1.000 PP#6E7

 Full comment: PP#6E7607

13013211 13A Raspberry, juice-babyfood 0.100000 1.000 1.000 PP#6E7

 Full comment: PP#6E7607

14000030 14 Almond 0.100000 1.000 1.000 

14000031 14 Almond-babyfood 0.100000 1.000 1.000 

14000040 14 Almond, oil 0.100000 1.000 1.000 

14000041 14 Almond, oil-babyfood 0.100000 1.000 1.000 

14000590 14 Brazil nut 0.100000 1.000 1.000 

14000680 14 Butternut 0.100000 1.000 1.000 

14000810 14 Cashew 0.100000 1.000 1.000 

14000920 14 Chestnut 0.100000 1.000 1.000 

14001550 14 Filbert 0.100000 1.000 1.000 
S-Metolachlor Dietary Exposure and Risk Assessment DP # D396451 

Page 25 of 27

14001560 14 Filbert, oil 0.100000 1.000 1.000 

14001850 14 Hickory nut 0.100000 1.000 1.000 

14002130 14 Macadamia nut 0.100000 1.000 1.000 

14002690 14 Pecan 0.100000 1.000 1.000 

14002820 14 Pistachio 0.100000 1.000 1.000 

14003910 14 Walnut 0.100000 1.000 1.000 

15000250 15 Barley, pearled barley 0.100000 1.000 1.000 

15000251 15 Barley, pearled barley-babyfood 0.100000 1.000 1.000 

15000260 15 Barley, flour 0.100000 1.000 1.000 

15000261 15 Barley, flour-babyfood 0.100000 1.000 1.000 

15000270 15 Barley, bran 0.100000 1.000 1.000 

15000650 15 Buckwheat 0.100000 1.000 1.000 Additi

 Full comment: Additional data required.

15000660 15 Buckwheat, flour 0.100000 1.000 1.000 Additi

 Full comment: Additional data required.

15001200 15 Corn, field, flour 0.100000 1.000 1.000 

15001201 15 Corn, field, flour-babyfood 0.100000 1.000 1.000 

15001210 15 Corn, field, meal 0.100000 1.000 1.000 

15001211 15 Corn, field, meal-babyfood 0.100000 1.000 1.000 

15001220 15 Corn, field, bran 0.100000 1.000 1.000 

15001230 15 Corn, field, starch 0.100000 1.000 1.000 

15001231 15 Corn, field, starch-babyfood 0.100000 1.000 1.000 

15001240 15 Corn, field, syrup 0.100000 1.500 1.000 

15001241 15 Corn, field, syrup-babyfood 0.100000 1.500 1.000 

15001250 15 Corn, field, oil 0.100000 1.000 1.000 

15001251 15 Corn, field, oil-babyfood 0.100000 1.000 1.000 

15001260 15 Corn, pop 0.100000 1.000 1.000 

15001270 15 Corn, sweet 0.100000 1.000 1.000 

15001271 15 Corn, sweet-babyfood 0.100000 1.000 1.000 

15002260 15 Millet, grain 0.100000 1.000 1.000 

15002310 15 Oat, bran 0.100000 1.000 1.000 

15002320 15 Oat, flour 0.100000 1.000 1.000 

15002321 15 Oat, flour-babyfood 0.100000 1.000 1.000 

15002330 15 Oat, groats/rolled oats 0.100000 1.000 1.000 

15002331 15 Oat, groats/rolled oats-babyfood 0.100000 1.000 1.000 

15003230 15 Rice, white 0.100000 1.000 1.000 

15003231 15 Rice, white-babyfood 0.100000 1.000 1.000 

15003240 15 Rice, brown 0.100000 1.000 1.000 

15003241 15 Rice, brown-babyfood 0.100000 1.000 1.000 

15003250 15 Rice, flour 0.100000 1.000 1.000 

15003251 15 Rice, flour-babyfood 0.100000 1.000 1.000 

15003260 15 Rice, bran 0.100000 1.000 1.000 

15003261 15 Rice, bran-babyfood 0.100000 1.000 1.000 

15003280 15 Rye, grain 0.100000 1.000 1.000 

15003290 15 Rye, flour 0.100000 1.000 1.000 

15003440 15 Sorghum, grain 0.300000 1.000 1.000 PP#9E7

 Full comment: PP#9E7607

15003450 15 Sorghum, syrup 4.000000 1.000 1.000 PP#9E7

 Full comment: PP#9E7607

15003810 15 Triticale, flour 0.100000 1.000 1.000 

15003811 15 Triticale, flour-babyfood 0.100000 1.000 1.000 

15004010 15 Wheat, grain 0.100000 1.000 1.000 

15004011 15 Wheat, grain-babyfood 0.100000 1.000 1.000 

15004020 15 Wheat, flour 0.100000 1.000 1.000 

15004021 15 Wheat, flour-babyfood 0.100000 1.000 1.000 

15004030 15 Wheat, germ 0.100000 1.000 1.000 

15004040 15 Wheat, bran 0.100000 1.000 1.000 

15004050 15 Wild rice 0.100000 1.000 1.000 

19011030 19A Chive 2.000000 1.000 1.000 

19011180 19A Coriander, leaves 8.000000 1.000 1.000 1E7898

19011181 19A Coriander, leaves-babyfood 8.000000 1.000 1.000 1E7898

19021190 19B Coriander, seed 0.130000 1.000 1.000 1E7898

19021191 19B Coriander, seed-babyfood 0.130000 1.000 1.000 1E7898
S-Metolachlor Dietary Exposure and Risk Assessment DP # D396451 

Page 26 of 27

19011440 19A Dillweed 0.500000 1.000 1.000 
S-Metolachlor Dietary Exposure and Risk Assessment DP # D396451 

Page 27 of 27

Attachment 4 Results of Chronic DEEM-FCID Dietary Exposure Analysis

California Department of Pesticide Regulation Ver. 2.00

DEEM-FCID Chronic analysis for METOLACHLOR AND S-METOLACHLOR (1994-98 data)

Residue file name: F:\telework\s-metolachlor2011\108800c_rad.R98

 Adjustment factor #2 NOT used.

Analysis Date 12-12-2011/10:33:12 Residue file dated: 12-12-2011/09:24:01/14

Reference dose (RfD, Chronic) = .1 mg/kg bw/day

===============================================================================

 Total exposure by population subgroup

-------------------------------------------------------------------------------

 Total Exposure

 -----------------------------------

 Population mg/kg Percent of 

 Subgroup body wt/day Rfd 

-------------------------------------- ------------- ---------------

U.S. Population (total) 0.004550 4.5%

U.S. Population (spring season) 0.004522 4.5%

U.S. Population (summer season) 0.004755 4.8%

U.S. Population (autumn season) 0.004468 4.5%

U.S. Population (winter season) 0.004450 4.4%

Northeast region 0.004282 4.3%

Midwest region 0.004614 4.6%

Southern region 0.004385 4.4%

Western region 0.004983 5.0%

Hispanics 0.004981 5.0%

Non-hispanic whites 0.004405 4.4%

Non-hispanic blacks 0.004634 4.6%

Non-hisp/non-white/non-black 0.005662 5.7%

All infants (< 1 year) 0.011574 11.6%

Nursing infants 0.004534 4.5%

Non-nursing infants 0.014246 14.2%

Children 1-6 yrs 0.007966 8.0%

Children 7-12 yrs 0.005096 5.1%

Females 13-19 (not preg or nursing) 0.003461 3.5%

Females 20+ (not preg or nursing) 0.004053 4.1%

Females 13-50 yrs 0.004122 4.1%

Females 13+ (preg/not nursing) 0.004142 4.1%

Females 13+ (nursing) 0.005449 5.4%

Males 13-19 yrs 0.003911 3.9%

Males 20+ yrs 0.003928 3.9%

Seniors 55+ 0.004009 4.0%

Children 1-2 yrs 0.008666 8.7%

Children 3-5 yrs 0.007852 7.9%

Children 6-12 yrs 0.005372 5.4%

Youth 13-19 yrs 0.003698 3.7%

Adults 20-49 yrs 0.003994 4.0%

Adults 50+ yrs 0.004017 4.0%

Females 13-49 yrs 0.003929 3.9%

-------------------------------------------------------------------------------