1 

### U.S. ENVIRONMENTAL PROTECTION AGENCY

INSTRUCTIONS FOR THE SIGNIFICANT NEW ALTERNATIVES POLICY (SNAP)

PROGRAM TSCA/SNAP ADDENDUM

August, 2014

EPA

‐ 1265

‐ 14 Office of Atmospheric Programs

Washington, DC 20460

The U.S. Environmental Protection Agency (EPA) has prepared this instruction manual to help you in

submitting information on alternatives to the Significant New Alternatives Policy (SNAP) program in

conjunction with a Premanufacture Notice (PMN) under the Toxic Substance Control Act (TSCA) (EPA

Form 7710

‐ 25). This manual provides instructions on submitting the TSCA/SNAP Addendum forms,

asserting confidentiality claims, and submitting test data and optional information. However, please

note that in the event of any discrepancies between this document and the Code of Federal Regulations

(CFR), the CFR requirements are legally binding and take precedence.



## Part I

– Introduction and CBI

Section A

‐ Instructions

All submitters must complete all of Part I

‐ Introduction and CBI, Part II

‐ Contact Information, Part III

‐

General Information, Part VI

‐ Attachments, and Part VII

‐ Certification. For each sector for which the

alternative is being submitted, submitters must also complete the corresponding sector

‐ specific data

requirements found in Part IV.

 Refrigeration and Air Conditioning

 Foam Blowing

 Cleaning Solvents

 Fire Suppression

 Aerosols

 Sterilants

 Adhesives, Coatings and Inks

 Tobacco Expansion



### Section B

‐ Identification of Alternatives

Please identify the alternative, sector(s), end

‐ use(s), and application(s) (if applicable) for which the form

is being submitter in Part I, Section B.



### Section C

‐ Confidentiality Claims

If you submit information for which you would like to request Confidential Business Information (CBI)

status, you must make a claim of confidentiality at the time of submission and substantiate that claim.

EPA will treat all claims of confidentiality consistent with 40 CFR Part 2, Subpart B. To claim information

as CBI, bracket the specific information you claim as confidential and mark the confidential box in the2 column on the right

‐ side of the page in the corresponding row. If information is claimed as CBI, then a

public version must be submitted with the bracketed information redacted/removed.



### To ensure that no confidential information is disclosed to the public, you must submit an additional

copy of the notice form, including attachments, which does not contain confidential information.

This version ("sanitized", "redacted") will be placed in the public file. It must contain all non

‐

confidential information. To assert confidentiality claims for information in attachments to the

form, provide a complete copy of the attachment that clearly indicates (e.g., by circling or

bracketing) the information you wish to claim as confidential. Bracket only the specific information

you claim as confidential.

Provide a Statement of Data Confidentiality Claims in Part I, Section C based on the instructions provided

in the form. EPA requires substantiation of all CBI claims under SNAP or a submission will be considered

incomplete.



## Part II

– Contact Information

Section A

‐ Submitter Contact Information

All contacts listed in Part II will be granted access to CBI, unless otherwise noted and substantiated in

Part I, Section C.

1. Person Submitting Notice

‐ Enter information for the primary submitter of the notice. The

person submitting the notice form must sign the certification in Part VII

‐ Certification.

2. Agent

‐ Complete only if you authorize an agent to assist you in preparing this notice. The agent

must also sign the certification in Part VII

‐ Certification.

3. Technical Contact

‐ Identify a person who can provide EPA with additional technical information

on the substitute during the review period, if that contact is different than the “Person

Submitting Notice”. The technical contact identified should be located within the U.S. and be

available to be reached by telephone during normal business hours. If the authorized agent is

also the technical contact, include that person’s information in both locations.

4. Joint Submitter

‐ Identify the joint submitter, if any, who is authorized by the primary submitter

to provide some of the information required in the notice. A submission will not be considered

complete until EPA receives all information. If information from multiple parties will not be sent

together, mark each set clearly with the same alternative identification information.

If you authorize another person (e.g., a foreign manufacturer or supplier) to provide information

directly to EPA, indicate which information will be supplied by the other person in Part V

Additional Information. Such a letter in support of your notice should be provided by the Joint

Submitter on their company letterhead. An example of where this option could apply would be

in situations where alternative formulation information is held confidentially by a foreign

manufacturer. A notice will be considered incomplete until this information is provided.

Whenever possible, use the same name for the alternative (e.g., generic name) to link this

information to your submission.3 

## Part III

– General Information

Section A

– Alternative

‐ Specific Information

EPA must receive a complete and unambiguous identification of the new substitute. If the alternative is

not adequately identified, we will consider the submission incomplete. If you are an importer of an

alternative and do not know the chemical identity of a substitute because it is confidential, you must

contact the manufacturer or supplier and have the specific chemical identity provided directly to EPA. In

this way, manufacturers can protect confidential business information. This information may be

provided in a letter on company letterhead from the supplier.

1. Identify Proposed Substitute

‐ (a

‐ d) Enter the specific name of the chemical substance, the

percent of the composition, the Chemical Abstracts Service (CAS) registry number, and the

molecular formula of the alternative. In describing chemical substances, EPA prefers that

International Union of Pure and Applied Chemistry (IUPAC) nomenclature be used for

identification purposes. If the substitute is a blend of chemicals, you must provide the exact

composition and/or the range of percent composition of all components of the blend. In

addition to active ingredients, you must also list other chemical substances in blends, such as

solvents, inhibitors, etc., that may also be present in the alternative.

2. Commercial/Trade name(s) of alternative

– Indicate the name(s) under which the alternative is

marketed.

3. Generic name ‐ If the identity of a substitute and the commercial/trade name are claimed as

confidential, you must provide a generic name that is only as generic as necessary to protect the

confidential identity. The name should reveal the chemical identity or alternative process

description to the maximum extent possible. The generic name may be published in the Federal

Register notice announcing EPA’s acceptability determination of your alternative. If the name

seems more generic than necessary, EPA will contact you and assist you in developing an

adequate name.

The generic name should provide sufficient information for the public by indicating the classes

of chemicals which the alternative contains without revealing specific information about the

product's composition. For example, it may be necessary to reveal that a refrigerant blend

contains an HCFC in order to allow users or importers to comply with regulations issued under

sections 604, 605 or 608 of the CAA.

4. Ozone depletion potential (ODP)

‐ (a) Provide information on the predicted 100

‐ year ODP of

the alternative relative to CFC

‐ 11. If the substitute is a blend, provide the ODPs of the individual

constituents. You should also provide supporting documentation indicating how and by whom

this value was calculated.

For purposes of calculating ODP, EPA recommends the methodology used in the Scientific

Assessment of Ozone Depletion prepared for the United Nations Environment Programme

(UNEP) by the World Meteorological Organization (WMO). The ODP refers to the amount of

ozone destroyed by a gas over its entire atmospheric lifetime (e.g. at a steady state) relative to

that due to emissions of the same mass of CFC

‐ 11. It is defined in modeling calculations as

follows:

‐4 

### 11

- CFC by caused O Global x by caused O Global

= ODP

3 3

x 

###  

Calculations should reflect ground level emissions. For aircraft applications, be sure to also

consider emissions at the appropriate altitude.

(b) You should also include any other related data available to you, such as information on the

substitute's chlorine or bromine loading potential. See the 2010 WMO Scientific Assessment of

Ozone Depletion for additional information on calculating ODP and related information.

5. Global Warming Characteristics

‐ (a

‐ c) Provide information on the 100

‐ year global warming

potentials (GWPs) of the proposed substitute relative to CO 2 , as well as atmospheric lifetime

(ATL) of the proposed substitute. If the substitute is a blend, provide the GWPs of the individual

constituents and an estimate of the blend at its nominal composition.

Provide GWPs as listed in the 2007 Intergovernmental Panel for Climate Change Fourth

Assessment Report (IPCC AR4). Alternate sources may include the 2010 WMO Scientific

Assessment of Ozone Depletion or the peer

‐ reviewed literature. IPCC defines GWP of the

emissions of a greenhouse gas as the time integrated commitment to climate forcing from the

instantaneous release of 1kg of a trace gas expresses relative to that from 1 kg of CO 2

.



### dt c a dt c a

= GWP

CO CO n

0 i i n

0

2 2 

#  

where

‐

a i = the instantaneous radiative forcing due to a unit increase in the concentration of trace gas, i

c i = the concentration of trace gas, i, remaining at time, t, after its release, and

n = the number of years over which the calculation is performed.

Corresponding values for CO 2 are in the denominator.

For GWP values that do not come from IPCC AR4 or WMO 2010, you should also include the

data used to calculate these potentials such as atmospheric lifetime, infrared adsorption

spectrum, and infrared absorption capacity. Provide all supporting documentation.

(d) If the alternative is captured as a byproduct of another manufacturing or industrial process,

indicate the source of the alternative. This information is important in assessing the effects of

the new use of the substitute versus those effects occurring strictly because of the release of a

byproduct.



### Section B: End

‐ Use and Application Information

1. Specific End

‐ use ‐ (a

‐ c) Identify the specific end

‐ uses within the sector in which the alternative is

to be used. For refrigeration and air conditioning, select the appropriate applications and5 indicate if the substitute is intended for new equipment, retrofit equipment or both. Specify the

ozone

‐ depleting substance (ODS) and other substances being replaced, and include an estimate

of the quantity of alternative (lb) needed to replace the ODS or other substance for each end

‐

use. This is known as the replacement ratio. For example, if 100 lb of a new refrigerant will

replace 150 lb of CFC

‐ 12, the replacement ratio is 1:1.5.

2. End

‐ Use Specific Standards

‐ List any standard

‐ setting organizations that will evaluate the

proposed substitute or will set requirements or guidelines for the substitute rom a health and

safety perspective in the proposed end

‐ use(s), such as the Underwriters Laboratories (UL), the

American Society of Heating, Refrigerating and Air Conditioning Engineers (ASHRAE), the Society

of Automotive Engineers (SAE), the National Fire Protection Association (NFPA), or the

International Organization for Standardization (ISO).

3. Technology Changes and Cost

‐ Describe any new equipment technology changes and associated

costs that will be necessary in order to use the proposed substitute.

4. Production and Market Share

‐ Provide estimated information on production of the proposed

substitute or equipment using the proposed substitute. Indicate when you anticipate the

substitute or new equipment using the substitute will enter the marketplace. Include the value

for total production anticipated during the first year of production in kg.

Also, provide information on the levels of market penetration that you expect for the substitute

or new use of an existing substitute. Include estimates for the number of years you anticipate

until the substitute reaches its maximum market penetration for those uses included in

submission, and the total production level that you anticipate for the substitute when it reaches

the point of market saturation. Finally, if possible, estimate the percentage of the market held

by the substance(s) being replaced that will be captured by this substitute.

5. Energy Efficiency

‐ (a

‐ b) For refrigeration, air conditioning and foam blowing, provide the

alternative’s impact on energy efficiency relative to the substance it is replacing for each end

‐

use. Attach and describe the results of any energy efficiency testing or modeling performed.

Laboratory testing of equipment should evaluate the proposed substitute vs. the substance(s)

being replaced. Values should be given in kWh/day or a similar measure.



### Section C: Flammability (Required for Refrigeration and Air Conditioning, Foam Blowing, Cleaning

Solvent, Aerosols, Sterilant, and Adhesives, Coatings, and Inks)

1. Flammability

‐ Related Physical and Chemical Properties

‐ Provide information on the physical

and chemical properties relevant to evaluating the flammability of the proposed substitute.

2. Flammability Assessments and Test Data

– For flammable substitutes, please include as an

attachment the results of ASTM E681 Flammability Limits in Air. The numerical values for the

upper and lower flammability limits are requested in Part III. For flammable refrigerants, please

provide information on the maximum pressure of combustion, the maximum rate of pressure

increase during combustion, and the minimum ignition energy. If you have conducted any

analyses on flammability, please provide them.6 For refrigeration and air conditioning, if an alternative is flammable (this applies to both blends

and pure materials), you must analyze the risk of fire resulting from the use of the substitute in

each proposed end

‐ use/application through a risk assessment. For refrigeration and air

conditioning, a Fault Tree Analysis (FTA) or Failure Mode and Effects Analysis (FMEA) is also

required. An FTA should include, but not be limited to, a description of typical scenarios in which

the substitute is used, potential leak scenarios, sources of ignition, and probabilities of ignition.

It should also assess the likelihood of injury within each scenario. An FMEA should describe

identified failures that could result in a spark, flame, explosion, or other fire risk and mitigation

measure for each failure mode. Significant differences exist both in the design and in the

ambient conditions for various end

‐ uses. Thus, risk assessments are extremely sensitive to end

‐

use. Low risk in one end

‐ use does not, in general, imply low risk in another end

‐ use.

3. Flammability Concerns and Mitigation

‐ If a substitute is flammable under the conditions

expected in the proposed end

‐ use/application, describe any abatement techniques being used

to minimize the risks associated with use of a flammable substance (e.g., equipment design

modifications or alternate labeling).

For flammable foam blowing agents used in spray foam, provide a training program that address

flammability concerns specific to the substitute.



## Part IV: Sector

‐ Specific Information

Due to the unique uses and exposures of alternatives for each of the SNAP industrial sectors, Part IV

includes individual Sections for each sector. You are only required to complete those sections for which

you are submitting to SNAP. Below are instructions for questions found in Part IV. If you are submitting

the substitute for several end

‐ uses or applications, you must provide the requested information for

each.

 Application of Proposed Substitute

– Provide information requested in each sector

‐ specific

section on the specific application of the substitute. These questions are related to both

manufacturing and use.

 Additional End

‐ Use Description

‐ Provide a written description of the specific uses for which you

are submitting.

 Compressor Oil

– For refrigeration and air conditioning only, provide information on the

chemical class of refrigerant oil you anticipate will be used (e.g., polyalkylene glycol, polyolester,

mineral oil) and information on the refrigerant/oil solubility.

 Compatibility

‐ For cleaning solvents only, provide information on the compatibility of the

solvent with metals and plastics with regards to its use as a cleaning solvent (e.g., is the solvent

corrosive to some materials).

 Consumer Use

– Where requested, indicate whether the proposed substitute will be used for

consumer use. If consumer use is expected, please describe the anticipated consumer

applications.7 

## Part V

– Additional Information

Provide any additional information that may assist EPA’s review. Submitters are not required to include

information in this section.



## Part VI

‐ Attachments

Clearly identify all attachments being provided in support of the submission.

Mark (X) in the CBI box next to any attachment that you claim as confidential. The public version of the

submission form must include the attachment name/citation at a minimum. All claims of confidentiality

must be substantiated in Part I.



## Part VII

‐ Certification

The individual identified in Part I of the form as the person submitting the Information Notice must sign

the certification in Part XIV of the form. This official is responsible for the truth and accuracy of each

statement in the certification. If an agent assists you in preparing the submission, the agent must also

sign the certification.

A printed copy of the certification page, with original signature, must be submitted with electronic or

paper submissions. If the submission is not signed, EPA will consider the submission incomplete and will

not review the substitute.