### P. 1



# OAR Box 1851 Prepped by Keeia Richards

Document

Number: 

# 29 ) ll-A- 3
Docket Number: 

# A-90-1 9

Printed 11/19/200811:19:51 AM Sheet 29 of 41

### P. 2

i 

# A-90-1 9 ll-A- 3



# SURVE Y REPORT S O N ATMOSPHERIC EMISSION S FRO M TH E PETROCHEMICA

L INDUSTR

Y VOLUM E III

b y J
. W
. Pervier , R
. C

. Barley , D
. E
. Field , B.M
. Friedman , R
. B
. Morris , W
. A

. Schwart z

Houdr y Divisio n Ai r Product s an dChemicals , Inc
. P
. O

. Bo x 42 7 Marcu s Hook , Pennsylvani a1906 1
Contrac t No
. 68-02-025 5
EPAProjec t

Officer : Lesli e B
. Evan s Prepare dfo r 

# ENVIRONMENTAL PROTECTIO NAGENC Y Offic e of Ai r an dWate r

Program s Offic e of Ai r Qualit y Plannin g an dStandard s Researc hTriangl e Park , N
. C

. 2771 1

Apri l 197 4

### P. 3 

# •r Thi s repor t i s issue db y th e Environmenta l Protectio nAgenc y t o repor t technica l dat ao f interes t t o alimite dnumbe r

of readers

. Copie s ar e availabl e fre e of charg e t o Federa l employees , curren t contractor s an dgrantees , an dnonprofi t organization s a s supplie s permi t

- fro mth e Ai r

Pollutio nTechnica l Informatio nCenter , Environ

menta l Protectio nAgency , Researc hTriangl e Park , Nort hCarolin a27711 , o r fro m th e Nationa l Technica l Informatio nServic e 528 5 Por t Roya l Road , Springfield , Virgini a22151

.

Thi s repor t

wa s furnishe dt o th e Environmenta l Protectio nAgenc y b y Ai r Product s an dChemicals , Inc
. , Marcu s Hook , Pennsylvania , i nfulfillmen t of Contrac t No
. 68-02-0255

. Th e content s o f thi s repor t

ar e reproduce dherei na s receive d fro mAi r Product s an dChemicals , Inc
. Th e opinions , findings , an dconclusion s expresse dar e thos e o f th e autho r

an dno t necessaril y thos e o

f th e Environmenta l Protectio nAgency

. Mentio no f compan y o r

produc t name s i s no t

t o b e considere d a s a nendorsemen t

b y th e Environmenta l Protectio nAgency

.

Publicatio nNo
. EPA-450/3-73-005- C

n

## • — l

i

## I I i

TABLE MA-ll l NATIONA

L EMISSION S INVENTOR Y MAI.EIC ANHYDRID

E PRODUCTIO

N Cod e Numbe r o n strea m •cit y - Ton s Malei cAnhydrid e (MAN)/Yr . rag e Productio n - Ton s MAN/Yr . g e I n Productio n - 7 . o f Max . salon s t o Atmospher e Strea m
Flo v- SCF

M Flo vCharacteristi c- Continuou s o rIntermitten t I f Intermitten t- Hrs./Yr . o f Flo v Compositio n - Tons/To no f MA N Particulat e

N 2 co 2 C O Hj O MA N (a ) Malei cAci d Bencen e Foravtldehyd e Formi cAci d Xy len e Sampl e Ta p Locatio n Dat e o rFrequenc y o f Samplin g Typ e o f

Analysi s Odo rP ro b lea s ren tStack s Flo v- SCF

M pe rstac k Numbe r Heigh t- Fee t Diamete r- Inche s Esl tCa aTemperatur e - ° F Emissio n Contro l Devic e Typ e Catalo g I . D . Number Tota l Hydrocarbo

nEmission s - Ton/To nof MA

N Tota l partIculate/Aeroso l Emission s - Ion/To no f MA N Tota l N0 „ Emission s Tota l SO , Emission s Tota l CO Emission s 18- 1 20,00 0 0 Scrubbe r Ven t 42,00 0 Continuou s

6 2 6 1 0 2 0 0 0 0 128 0 328 0 841 6 867 4 235 4 004 0 062 4 015 4 001 2

To p o f Stac k Benzen e - 3/wea kOthat s I/wee k MS , CLC , F T Me tChemica l Ye s - I n plan t- N o - Of f Plan t 21.00 0 2 7 9 an d 9 9 2 4 10 9
Vate r Scrubbe r 0.083 0 0
0.867 4 Benzen e an d Produc t Recover y Ven t 43,10 0 Continuou s

5.67 2 7 2 6 781 8 1.280 0 0 610 9 0 872 7 0.002 7 0.003 3

Stac k Desig nCalc . N o 43,10 0 1 9 0 4 2 10 0 No tSpecifie d Pag e 1 o f 3 18- 1 197 2 22.00 0

Vacuu m Syste m Ven t 1 6 Con t inuous

0 003 0 0 010 0 0 000 9 Scrubber Ven t 289 0 Con t inuous

0 559 8 1 834 8 Incinerato r Ven t 740 0 Continuous

0 000 1 (Na ? C0 3 > 0 109 1 I.800 0 0 372 7
0 000 1

No tSpecifie d 0 044 9 0 000 2

Uate rScrubbe r 0.006 2 0 000 1
0.610 9 2 476 4

To p o f Stac k Desig nCalc . N o 1 6 I 8 5 2 8 0 Top o f Desig n N o 2 89 0 1 2 0 1 4 8 6 Stac k

Cal c Top o f

Desig n N o 7.40 0 1 3 6 1 4 20 0 Stack

Cal c

Vate rScrubbe r

NOTES : (Se e als o sheet s 2 an d 1 o l I ) ( a ) Ofte n emitte d a s malei caud , hu troniino u p i -ac ti i< • i s t o repor ti ta s th e anhydride .EP

A Cod e Numbe r Dat e o n strea m Capacit y - Ton s Malei cAnhydrid e (MAN)/Yr

. Averag e Productio n- Ton s MAN/Yr . Rang e I nProductio n- 7 . o f Max . Emission s t o Atmospher e Strea m TABL EMA-ll l NATIONALEMISSION S INVENTOR Y MALEI C ANHYDRIDEPRODUCTION 18- 3 196 1 10.00 0

Scrubbe r Ven t Pag e 2 o t 3 18- 4 17.00 0 0 Scrubbe r Ven t 18- 5 25.00 0 0 Scrubbe r Ven t Flo v - SCF M Flo v Characteristi c - Continuou s o r Intermitten t I f Intermitten t - Hrs./Yr
. o f Flo v Compositio n - Tons/To n o f MA N Particulat e

C O H- 0 MA N (a ) Malei c Aci d Benzen e Formaldehyd

e Formi c Aci d Xylen e Seattl e Ta p Locatio n Dat e o rFrequenc y o f Samplin g Typ e o f

Analysi s Odo rProblem s Ven tStack s Flo v- SCF

M pe ratac k Nuabe r Heigh t- Fea t Diamete r- Inche s Exi tCa s Temperatur e - ° F Emissio nContro l Devic e Typ o Catalo gI . D . Nuabe r Tota l Hydrocarbo nEmission s - Ton/To no f MA N Tota l partlculate/Aeroao l Emission s - Ton/To nMA N Tota l NO , Emission s Tota l S0 XErnieslon e Tota l CO Emission s 17,00 0 Continuou s

6.929 6 22.823 2 0.848 0 0.684 4 0.392 8 0.002 0 0.100 8

0.011 6 Scrubbe r Fou r sinc e 196 8 Gravimetri c - We t Chemica l N o 17,00 0 1 7 2 2 4 6 5
Vate r Scrubbe r 0.114 4 0

0.684 4 30.00 0 Continuou s 

## ) )32.181 0 

## ) 0.670 6 1.513 9 0.005 9 0.061 6

No t No t Ma t N o 3 0 , 1 7 4 2 4 10 0 Sam p Sam p Ba l
[10 0 le d le d anc e

Vate r Scrubbe r 0.067 5 0
0.670 6 42.00 0 Continuou s

4.955 0 24.265 6 1.312 6 0.443 4 1.364 2 0.011 5 0.062 7 )Inc l vlt h IMalel c Aci d

No t Specifie d Infreauen t No t Specifie d Ye s 42.00 0 1 6 5 3 6 10 0
Wate r Scrubbe r 0.074 2 0
0.443 4

QUOIA N " u

### I I I i t1 

## L

_ l L_ J 

## L J L . J L

_ J

__ i - J L_ .

od e Nuabe r o n stree a :lt y - Ton s Malei cAnhydrid e (MAN)/Yr . •g aProductio n - Ton s MAN/Yr . I n Productio n - 7. o f Max
. •Ion s t o Atmospher e i trea m
Flo v- SCF

M Flo vCharacteristi c- Continuou s o rIntermitten t i f Intermitten t- Hrs./Yr . o f Flo v Compoeltlo n - Tona/To n o f MA N Particulat e 

## ° 2 CO j C O Hj O MA N (a ) Malei cAci d Benzen e Formaldehyd e Parad e Aci d Xylen e Sampl e Ta p Locatio n Dat e o rFrequenc y o f Samplin g Typ e o f

Analysi s Odo rProblem s Stack s Flo v- SCF

M pe rstac k Numbe r Heigh t- Fee t Diamete r- Inche s Exi tGa s Temperatur e - ° F ato n Contro l Devic e Typ e Catalo g I . D . Numbe r 1 Hydrocarbo n Emission s - Ton/To no f MA N 1 Partlculata/Aeroao l Emission s - Ton/To nMA N 1 NO , Emission s 1 SO , Emission s i l CO Eausalon s 8crubbe r Ven t 78,00 0 Cont1nuou s TABLEMA-H I

NATIONALEMISSION S INVENTOR Y MALEI C ANHYDRID EPRODUCTIO N 18- 6 52.50 0

Fum e Scrubbe r

Ven t
Continuou s

3 . 19 . 1 . 0 . 1 . 

## ) o . ) 0 . )In c )MA N

No t No t Ma t N o No t No t No t No t 14 0 989 6 725 0 036 3 470 3 221 9 004 7 087 9 l . vlt h

Sample d Sample d

. Balanc e Specifie d Specifie d Specifie d Specifie d

Wate rScrubbe r

0.092 6 0
0.470 3 0.001 5

No tSample d No tSample d Mat
. Balanc e N o 4 5 1 9 . 5 3 10 0 

### Ventur l Scrubbe r Produc t Recover y Ven t 20,00 0 Continuou s Pag e 3 o f 1 18- 7 15.00 0 0 Scrubbe r Ven t 7.00 0 Con t i nuo u



### 2.458 7 19.042 1 1.077 6 0.685 9 0.654 1
0.197 6

No t Specifie d Bz
. - 2-3/week . C O - 1/ 2 mont h CL C an d Ma

tBalanc e N o 20,00 0 1 5 6 8 2 4 10 4 No t Specifie d 0.197 6 0

0 685 9 1.891 2 6 623 2

0.231 5

No t Sample d No t Sample d Desig nCal c . N o 7 00 0 1 3 0 2 4 7 7 Wate rScrubbe r



### b >

## 1 t L . J l.._/ . I . 

### _j i 

### ..J I

TABLENYL-ll l NATIONA

LEMISSION S TNVENTOR v

an tEP A Cod e Numbe r paclt y - Tons/Yr . o f Nylo n 6 oductlo n- Tons/Yr . o f Nylo n 6 ilssion s t o Atmospher e Strea m I . D . No . (Figur e NYL-l ) Strea m

Flo v- Lbs./Hr . Flo v Characteristi c - Continuou s o r Intermitten t I f Intermitten t - Hrs./Yr . Compositio n- Ton/To no f Nylo n6 Caprolacta m Benzen e Nitroge n Ai r Wate r Carbo nDioxid e Oligome r Phosphori c Aci d Hydroge n ven t Steck a Numbe r Heigh t - Fee t Diamete r - Inche s Exi t Ga s Temp . - F ° Flo v - SCF M Emlsaio nContro l Device s Typ e Analysi s Sampl e Te pLocatio n Det e o r Frequenc y o f Samplin g Typ e o f Analyal s Odo r Proble m _ary o f Ai r Pollutant s Hydrocarbon s - Ton/To no f Nylo n6 'Particulate s & Aerosol s - Ton/To no f Nylo n6 N0 X- Ton/To no f Nylo n6 S O - Ton/To no f Nylo n6 C O - Ton/To no f Nylo n6 Ho t Mel t Filte r Ven t 620 0 SCF M Continuou s NYLO N6

Vas hVate r Recover y Vacuu mJe t Exhaus t
Neve r Measure d Continuou s 19- 1 40.00 0 40.00 0
D Pelle t Dryin g 136 3 Con t i nuo u

.00000 1
( 1 ) ( 1 ) + (2)



### Ye s 

### 1 3 6 19. 5 by 

### 10 0 620 0 

### N o

Ye s Non e March , 14. 5

197 2 Chromatograp h 

### N o Ye s 

### 1 4 6 

### 2 9 0 N o

Non e

Non e 

### N o Pa R e I o f ' .

Vaporize d Henzen e fro mV'ast e Wate r

Con t imuni ?

.00185 2 .14316 9 .00561 8

.00015 3 Knuipmen t Cleanin g Kurnac e Afterburne r Exhaus t -~»31 8 SCK M lnterm i t ten t 41 6



### (3 )

00385 2 .00000 1 0 0 0

•Caprolacta m

vapor s ar e considere da s aerosols . (1 ) Mostl y

vate r andair . (2 ) Mostl y

air . (3 ) Complet e combustio nt o C0 « endH2 O reported .

# U J

# v.i i i 

## l J 

## L. J l

_J -_ J 

## L._ J


## — / L_j l 

# , 1 n r r

TABLENYL-II I NATIONALEMISSION S INVENTOR Y NYLO N 6 ag e 2 o i '

. 

### 'len t EP A Cod e Numbe r apaclty - Tons/Yr . of Nylo n6 Productio

n- Tons/Yr . of Nylo n6 mission s t o Atmospher e Strea m I . D . No . (Figur e NYL-I ) Strea m
Flo v - Lbs./Hr . Flo v Characteristi c - Continuou s o r Intermittent i f Intermittent - Hrs./Yr
. Compositio

n- Ton/To

no f Nylo

n6 Caprolacta

m Benzen e Nitrogen Ai r Wate r CarbonDioxid

e Oligome r Phosphori cAci d Hydroge n Ven tStack a Numbe r 

### Heigh t- Fee t Diamete r - Inche s Exi t Ga s Temp . - F ° Flo v - SCF M Emlaslo nContro l Device s 

## trv Analyal s Sampl e TapLocatio

n Dat a o r Frequenc

y of Samplin

g Type o f Analysi s Odor Proble

m Summar y o f Ai r Pollutant s Hydrocarbon s - Ton/To nof Nylo

n6 ^Particulate s & Aerosol s - Ton/Tono f Nylo n6 NO , - Ton/To

nof Nylo

n6 SO , - Ton/To

no f Nylo

n6 C O - Ton/To

no f Nylo

n6 B Mel t Polymerlzer 26 0 Continuou s

Neerly 1007
.

Ye s 1 7 0 1 4 4 26 0 Ye s Ven t Condense r Non e
Materia l Balanc e N o 19- 2 Coi n ident ia 1 (' ) Con f iden

t i a 1 B Chi p Polyme r i ze r 2 2 Continuou s

Nearl y1007
.

Ye s 1 7 0 1 4 4 25 0 Ye s Vent Condense r Non e
Materia l B

e lanc e No 0 + 0 0 0 Depolymerize r Ven t 47 7 Cont i nuou e

Nearl y100"/
.

Ye s 1 7 0 3 3 21 2 Ye s Ven t Condense r

Materia l Balanc e N o

1 ) Publishe d capacit y I s 4 5 M h lbs. /year .

0 0mm** * n M i f 

# L 

# ^—^ tr j

v. . .J > • ^ J.

TABL ENYL-ll l



### lan tEP A Code Numbe

r apaclt y - Tons/Yr . o f Nylo n 6 roductlo n - Tons/Yr . o f Nylo n 6 missio n t o Atmospher e Strea m I
. D
. No . (Figur e NYL-I ) Strea m
Flo v - Lbs./Hr
. Flo v Characteristi c - I f Intermittent - Continuou s o r

Hr s /Yr
. Compositio

n- Ton/To n o f Nylo n6 Caprolacta a Benzen e Nitroge n Ai r Wate r Carbo nDioxide Oligomer Phosphori c Aci d Hydroge n Ven t Stack a Number Heigh t - Feet Diameter . - Inchea Bai t Caa Temp . Flo w - SCFM 

## F ° Emissio nContro l Device s Typ a Intermittent Reacto r Ven t
Contlnuo u
.00096 0 .06499 1 .04178 0

Ye s 1 9 0 Unknown 8 0 68 5 Ye s Condense r Analyal s Sampl e Tap Locatio n Dat e o rFrequenc y o f Samplin g Typ ao f Analysi s OdorProble m Summar y o f Ai rPollutant s Hydrocarbon s - Ton/To no f Nylo n6 'Particulate s & Aerosol a- Ton/To no f Nylo n6 NO , - Ton/To n o f

Nylo n 6 SO , - Ton/To n o f

Nylo n 6 C O - Ton/To n o f

Nylo n 6 N o
Estimated N o NATIONA L EMISSION S NYLO N6

C Pelletize r Ven t
Continuou s INVENTOR Y
19- 3 119.00 0 119.00 0 Nylo n Chi p SlurryTan

k Ven t
Continuou s Pag e 3 o l 4

.00337 4
.47292 5

N o


### Estimate

d No .00006 2

.00179 7

Yee 1 9 5 1 2 8 0 240 0 Ye a Wete r Spre

y Ye s

1 Unknow n Unknow n 7 8 2 0 N o

No
Estimate

d N o 0 .00439 6 0 0 0 Caprolacta mRecovery Distillatio n Colum

n Ven t
Continuou s

.00860 5

Ye s 1 9 0 Unknown ^200 ° F 23 5 lb s /h r Ye s Condenser

. Stea m Ejecto r N o
Estimate d N o Depolymerlza t ion Reacto r Ven t
Intermitten t 180 0 Unknow n (Small )

Unknow n

Ye s 1 6 5 1 2 b y1 2 Ambien t t o 120 o F 180 0 Ye s Wate r Spra y N o

Non e N o

C O

### j L .. j

an t EP A

Cod e Numbe r paclt y - Tons/Yr . o f Nylo n6 oductlo n- Tons/Yr . o f Nylo n6 laalon a t o Atmospher e Stree m 1 . D . No . (Figur e NYL-I ) Strea m A Mi xTan k Vent s TABLENYL-ll l

NATIONA LEMISSION S INVENTOR Y NYLO N6

Spi nTan k Ven t a 19- 4 39,27 5 39,27 5
B Polymerlza t i o n Reacto r Ven t I>a g e U o I

Par t Cleanin g Furnac e Olf-ca s DepolymerIzat i o n Reacto r

Ven t Flo v - Lbs./Hr . Flo v Characteristi c - Continuou s o r Intermitten t Continuou s I f Intermitten t - Hrs./Yr . Compositio n- Ton/To no f Nylo n6 Caprolacta m

. 00000 5 Bensen e Nitroge n.00019 5 Ai r Wate r Carbo nDioxid e .00000 1 Oligome r Phosphori cAci d Hydroge n Ven tStack s No tSpecifie d Numbe r Heigh t- Fee t Diamete r- Inche s Bxl tca e Tamp . - F ° Flo w- SCF

M Ealaalo n Contro l Device s N o Typ e Analysi s Non e Sampl e Ta pLocatio n Dat e o r Frequenc y o f Samplin g Typ e o f Analyal s Estimat e Odo r Proble m Summer y

o f Ai r Pollutant s Hydrocarbon s - Ton/To no f Nylo n6 • •Particulate s 6 . Aerosol s - Ton/To no f Nylo n6 MO , - Ton/To no f Nylo n6 8 0 , • Ton/To no f Nylo n6 C O - Ton/To no f Nylo n6 Continuou s

.00011 8 .00143 3

No tSpecifie d



### N o

Non e

Estimat e Continuou s

.00010 0 00323 3 .00001 6

No t Specifie d

N o

Non e
Estimat e

0 .026 2 0 0 0 Interm i tten t No t Specifie d



## ( D (1 )
+ No t Specifie d



### N o

No

Non e Continuou s 

### (2 )

25422 0


### (2 ) (2 ) No t Specifie d

No

No

Non e

1 ) Compositio nunknown . (2 ) A tota l o f 3 vol
. 7. , epproxlmetel y .02 6 lbs . /lb
. nylo n t (no t considere d typical)
.



### o

### L~ . 

### L

TABL E Nb,6-II I NATIONA

L EMISSION S TNVEITOF " NYLO N 6, 6 FRO

M ^rYLO KTAL T Pag e 1 o f

n tCod e No . paclt y - Ton s Nylo n 6,o/Yea r i»g e i n Productio n - 7 . o f Mex . isslon s t o Atmospher e Strea m

Flo v - Lbs./Hr . Flo v Characteristi c Composition , Ton/To nNylo n6, 6 Nylo nSal t Wate r Hexemethylen e Diamin e Adipi c Aci d Nylo n6, 6 Polyme r Cyclopentenon e Halide s Tot . Organi cCarbo n Sulfonamid e i tStack a Numbe r Heigh t- Fee t Diamete r- Inche s Exi tGa s Temp. , ° F SCFM/Stec k isalo n Contro l Device s Typ e ilyse s Dat e o rFrequenc y o f Samplin g Sampl e Locatio n Typ e o f

Analysi s Odo rProble m
naar y o f

Ai rPollutant s Hydrocarbons , Ton/To n Nylo n 6, 6 Particulate s 6. Aerosol s - Ton/To nNylo n6, 6 NO , - Ton/To n Nylo n 6, 6 SO , - Ton/To n Nylo n 6, 6 C O - Ton/To n Nylo n 6, 6 20- 1 20- 2 Non e ( A ) - Evapo r Off-ca s 470 0 Continuou s 

### + 0.27470 0 0.00017 5 + • ato r 75,00 0 Non e ( B ) Autoclav e Off-C.a s 54 0 Continuou s 

### + 0.03148 0 0.00009 0 

### + Non e ( C ) Convevo r A i rExhaus t 750 0 Cont1nuou s



### + +

1 1 0 8 155 ° 166 5 Non e Neve r Calc'd . N o 1 2 6 4 400 ° 17 8 Non e Neve r Calc' d N o
0 0.00026 5 0 0 0 1 Cyclon e 129 ° 540 0 Non e Neve r Calc'd . N o 93.50 0 Non e ( IA ) - Evapo r o fi'-ra s 470 8 Continuou s 

### + 1.1050 0 0.0009 0 ato r (IH ) - Autoclav e Off- ca s t>1 0 Continuou s 

### + O.olOO O 0 0020 0

5 8 6 8 3h0 ° H.5 0 Non e Occasiona l TIT , CC . CRAV , TO C N o 2 1 8 8 4 300 ° 21 6 Non e Occasiona l TIT , CC , CRAV . TO C No
0 0.00290 0 0 0 0TABLEN6.6-1I I NATIONALEMISSION S IVVKNIOK Y

Plan t Cod e No . Capacit y

- Ton s Nylo n o,b/Yea r Rang e InProductio n- '/. o f Max . Emlseion s t o Atmospher e Strea m

Flo v - Lbs./Hr . Flo v Characteristi c Composition , Ton/To n Nylo n 6, 6 Nylo nSal t Wate r Hexamethylen e Diamin e Adlpi c Aci d Nylo n6, 6 Polyme r Cyclopen t enon e Hallde s 

### Tot . Organi cCarbo n Sulfonamid e 

## < • None (IIA ) - Ev

a Off-Ga s 142 2 Con tinuou s
+ 

### 0.3410 0 0.0000 9 porato r NYLO N 6 . 6 FRO

M NYLO NSAL T


### 20- 2 36,50 0 None (IIB ) - Reacto r Off-Ca s 455 4 Cont i nuou s
+ 

### 1.0930 0 0.0035 0 Pag e 2 o f

(TIC * - Separato r Off-Ca s 98 0 Con t i nuou s + 0.2350 0 0.0035 0 ( I TD ) Fin i slie r

Exhaus t 73 0 Con t inuou s + 0.1750 0 0 0001 3

Ven tSteck s Numbe r Heigh t- Fee t Diamete r- Inche s Exi tCa s Temp. , ° F SCFM/Stec k Emissio n Contro l Device s Typ e Analyee s Det e o rFrequenc y o f Samplin g Sampl e Locatio n Typ e o f Analysi s Odo rProble m 2 8 8 4 265 ° 45 0 Non e Occasiona l TIT , N o CRAV , TO C 

### 2 9 5 1 2 330 ° 149 0 None Occasiona l TIT . CRAV , TOC N o 2 8 3 2) > 600 " 

### 32 5 Non e Occasiona l TIT , CRAV

. TO C No 2 8 8 4 300 ° 24 0 Non e Occasiona l



### amar y o f Ai rPollutant s Hydrocarbon s - Ton/To n Nylo n6, 6 Particulate s & Aerosol s - Ton/To n Nylo n 6, 6 NO , - Ton/To n Nylo n 6. 6 SO , - Ton/To n Nylo n 6, 6 C O - Ton/To n Nylo n 6, 6 0 0.00720 0 0 0 0

### y 

### t

TABLEN6.6-11 I

•n tCod e No . paclt y - Ton s Nylo n6,6/Yea r ng e I n Productio n - 7 o f Max . tsslon s t o Atmospher e Strea m

Flo v- Lbs . /Hr . Flo vCharacteristi c Compositio n - Ton/To n Nylo n6, 6 Nylo n Sal t Wate r Hexamethylen e Diamin e Aldpl cAci d 

### Nylo n6, 6 Polyme r Cyclopentenone Ha l Idee Tot . Organi c Carbon Sulfonamide NATIONA L NYLO N6 

## *
Non e (IIIA ) Evaporato r Off-Ga s 608 0 Continuou s 

### + 0.7020 0 0.0001 6 EMISSION S tilVENTO W hFRO M NYLO NSALT

• 20- 2 38,00 0 Non e (IIIB ) Reacto r Off-Ca s 608 0 Continuou s
+ 0.7020 0 0.0018 0 Pag e 3 o t

Non e ( II1C ) Separato r 

### Off-Ca s 113 0 Con t i nuou s
0

. 1305 0 O.OOOdi

. (HID ) Finishe r Exhaus t 5 i. O Con t i nuou s


### 0.06470 0 0.00000 3

en t Steck s Number Heigh t - Feet Diameter - Inche s Exi t Ga s Temp. , ° F SCFM/Stac k amissio nContro l Device s Type Analyse s Det e o r Frequenc

y of Samplin

g Sampl e Location Type o f Analysi s Odor Proble

m Summar y o f Ai r Pollutant s Hydrocarbon s - Ton/To nNylo n6, 6 particulate s 6. Aerosol s - Ton/To nNylo n6. 6 NO , - Ton/TonNylo

n6, 6 SO , - Ton/TonNylo n6. 6 C O - Ton/TonNy1o

n6, 6 1 10 1 6 300 ° 200 0 Non e Occasiona l TIT , CRAV , TOC N o 1 11 2 1 2 570 ° 200 0 Non e Occasiona l TIT , CRAV , TO

C N o
0 0.0026 2 0 0 0 1 10 1 2 590 ° 37 0 Non e Occasiona l TIT , CRAV , TOC N o 1 10 1 2 300 ° 18 5 Non e Never

N o

## _- 1



### lan tEP A Code No . apeclt y - Ton s Alcohols/Yea r ang e o f Productio n - 7

. o f Max . mission s t o Atmospher e Strea m

Exi t Ga s Temp . F SCFM/Stac k Emissio n Contro l Devlce a Analysi s 

### Dat e o rFrequenc y o f Samplin g Tap LoeetIo n Typ e Analysi s OdorProble m Suaaar y o f

Ai rPollutant s Hydrocarbon s - Ton/To n Ale . Aeroaol a - Ton/To n Ale . .NO , •Ton/To n Ale . SO , - Ton/To n Ale . 

### C O - Ton/To n Ale . 21- 1 90,00 0 0 Aid. , Ale , Heav y Liquid s t o Incinerato r Flo v - Lbs./Hr . (SCFM ) Flo v Characteristi c If Intermitten

t Compositio

n- Ton/To

nAle . Hydroge n Nitroge n(Air ) C O C0 2 

### Stea m NO , C . - Q , 6 . Higher Hydrocarbona Aldehyde s &

> Alcohol s Particulate s Ven t Stock s Numbe r Heigh t - Fee t Dieaeter , Inche s 987 9 Continuou s (a ) 0.0111 3 0.2848 3 0.1335 6

Trac e
1 1 8 6 0
Incinerato r
Neve r
A ttime s TABL E OA-II I NATIONA

L EMISSION S INVENTOR Y ALCOHOL

S B Y TH E 0X 0 PROCES S



### Compresso

r
900 0 Continuou s (c )
0.0760 9 0.1195 6 0.1*56 5

14 ' & 10.5 ' 24 " & 16 " 850 ° F 75 0 None
Neve r Estimat e N o Trec e

0.0760 9 Ox o Reacto r Ven t Ga s 311 2 Continuou s
0.0000 6 0.0004 4 0.1526 8 0.0109 2 0.0000 6

1 2 0 4 100 ° 47 0 None

Neve r Mat'l . Balanc e N o 21- 2

75,00 0 0 Ale . Dlstn . Sectio nVen t 280 8 Continuou s
0.0000 3 0.0011 8
0.1405 4 0.0200 2 0.0007 6
6 2 0 - 20 0 2 - 4 90 ° - 200 ° 4 - 20 0 Non e
Onc e Ven t M.S . N o Pag e 1 o f 4

Aid. . Al e . Heavy Liquid s t o Incinerato r (50,000 ) Continuou s ( • ) 0.3295 9


### 0.0878 9 0.0219 9

Trac e Trec e

Incinerator

Never Estimat e Ye s Up-set Ca s t o Emergenc

y Flare (22 8 Avg. ) Variabl e (b ) 0.0001 2 0.0000 9 0.0000 6 0.0013 2 0.0003 5 0.0000 6

1 10 0 1 4 1000 ° 22 8 Flar e

Estimat e N o 0.0209 0

0.0005 0

## , — 1 

## i 4 . •1 

# I M 

# -. 1 

# K l

TABLEOA-I1 1 NATIONA L EMISSION

S INVENTOR

Y
'len tE M Cod e No . Opacit y - Ton s Alcohols/Yea r ang e o f Productio n - I o f

Max . Imlaalon at o Atmospher e Strea m
Flo v- Lbs./Hr . (SCFM ) Flo vCharacteristi c I f Intermittent , Hrs./Yr . Compositio n - Ton/To n Ale . Hydroge n 

### Nitroge n (Air ) C O CO , Stea m NO , C i - C 4 & Highe rHydrocarbon s Aldehyde s & Alcohol s Particulate s Ven tStack s Nuabe r Heigh t- Fee t Diamete r- Inche s 

### Exi tGa s Temp . ° F SCFM/Stac k Emissio n Contro l Device s 21- 4 48,00 0 0 Ox o Reacto

r Ven t Ga s 119,02 6 Continuou s (b )

6.928 7 3 891 5 0.0002 7
0.0000 2 

### 1 12 0

Flar e ALCOHOL S B Y TH E 0X 0

Ox o Reacto r Ven tCa s 207 2 Continuou s ( b ) 0.0000 2 0.0002 6 0.0003 0 0 0282 7 0.0128 7 PROCESS 21- 5 217,50 0 0 Cat . Regenerato r

Ven tGa s (1800 ) Continuou s

0 0810 2 

### Pag e 2 o f 4

1 10 0 2 0


### Flar e 0 0001 2 0 0001 2 Trac e 1 6 0 1 4 212 ° 180 0 Non e 21- 6 35.00 0 0 Oxo Reacto r Ven tCa s 18,24 0 Cont i nuou s 

### (>> > 0.0258 9 1.729 5 0 9571 0

1 12 5 1 6 

### 213 ° J60,00 0 Flar e Analysi s Dat ao rFrequenc y o f Samplin g Tap Locatio n Typ e o f Analyal s Odo rProble m Summar y o f Ai rPollutant s Hydrocarbon s - Ton/To n Ale . Aeroaol s - Ton/To

nAle . NO , - Ton/To n Ale . SO , - Ton/To n Ale . C O - Ton/To n Ale . Neve r Est . fro m Fee d N o
0.0000 2 0.0002 7 12/Da y in-line C . C . N o 1/Mont h in-lin e Mat . Bel. , TOC,TI T Ye s 0.0002 4 Trac e
0 0003 0 Onc e in-line G . C . N o

# r i t . i i \



# i i i 4r4r4ri

m tEP A CodaNo . >acit y - Ton s Alcohols/Yea r ig e e i Productio n - Z o f Max . sslon s t o Atmospher e Strea m
Flo v- Lbs./Hr . (SCFM ) Flo vCharacteristi c I f Intermittent , Hrs./Yr . Compositio n - Ton/To n Ale . Hydroge n Nitroge n (Air ) C O CO , Staa a NO , C t- C A &

. Highe rHydrocarbon s Aldehyde s & Alcohol s Particulate s Ven tStack a Numbe r Heigh t- Fee t Dlaaete r• Inche s Exi tGa e Temp . ° F SCFM/Stac k Emissio n Contro l Device s NATIONA L TABL E OA- m ENTOR

Y ALCOHOL

S B Y TH E 0X 0 PROCES S Pag e 3 o f 4 21- 7 80,00 0 0 

### Hyd . Reforme r Ven t ( 7 Avg. ) Intermitten t 8 0.00003 2 

### 0.00000 2 0.00017 8 0.00057 7 0.00000 6 CO , Remov e 1 Ven t 30 2 Continuou s
0.00006 3
0.00940 4 Cat . Recover y Syste m Ven t 73 0 Continuou s

0.02226 0 

### Cat . Regenerato r Syste m Vent 1 9 Cont i nuou s

0.0005 8

Trac e Trec e

Non e 4 2 None 15 1 None 4 Non e Analysi s Dat ao rFrequenc y o f Samplin g Tap Locatio n Typ ao f Analysi s OdorProble m immar y o f Ai rPollutant s Hydrocarbon s - To n /To n Ale . Aaroaol s - Ton/To n Ale . NO , • Ton/To n Ale . SO , - Ton/To n Ale . C O - Ton/To n Ale . Neve r Estimat e N o Once In-lin e G.C . N o Never Calculate

d Ye s Never Calculate

d Ye s

## i t« ? - TT4 7 -

f 

# ( ? 

# i

Plan tI M Cod e No . Capacit y - Ton s Alcohols/Yea r Rang e o f

Productio n - I o f

Max . Bmlsalem e t o Atmospher e Strea m Flo v- Lbs./Hr . (SCFM ) Flo vCharacteristi c I f Intermittent , Hrs./Yr . Compoaltlo n - Ton/To n Ale . Hydroge n Nitroge n C O CO , 

### Stea m HO , C i - C i i Highe rHydrocarbon s Aldehyde s 6

. Alcohol s Particulate s Ven tStack s (Air ) Compressor Flua hLine s (0.0 1 Avg . ) Intermittent 1 Trac e Trac e Trec e Trec e

Trac e Trac e TABLE OA-II I NATIONA L EMISSION S INVENTOR Y ALCOHOL

S BY TH

E 0X 0 PROCESS 21- 7 

### 80,00 0 0 Distn . Colum

n Ven t 11 0 Continuou s Pag e 4 o f4

Storag e Tan k Vent s 9 6 

### Continuou s

0.0030 1



### 0.0033 8 0.0000 6 Trec e
Heigh t- Fea t Diamete r- Inche s Exi tGa s Tamp . ° F SCFM/Stac k Emissio n Contro l Device s Non e 3 5 Non e Ox o Reecto r Ven tGas , Etc . 354 4 Continuou s (b ) 0.00011 3 0.01785 7 0.00094 0 0.5357 1 0.03849 6

1 20 0 2 4 

### 60 6 Flar e alysl a Dat e o rFrequenc y o f Samplin g Ta p Locatio n Typ e o f Analysi s OdorProble m axmry o f

Ai rPollutant s Hydrocarbon s - Ton/To n Ale . Aerosol s - Too/To n Ale . MO , - Ton/To n Ale . 8 0 , - Ton/To n Ale . C O - Ton/To o Ale . Neve r
N o 

### Neve r Calculate d N o 

### Never Calculate

d N o 3 times/year lin e t o flar

e M.S . N o 0.00006 6

0.00094 2

# , J.

TABLEPH-II I NATIONALEMISSION S INVENTOR Y PHENOLPRODUCTIO NFRO M CUMEN

E Pag e 1 o f 1 3 

### Plan t- EP

A Cod e Numbe r Capacit y - Ton s o f

Phenol/Yr . Aversg e Productio n - Ton s o f Phenol/Yr

. Qusrterl y Productio n Variatio n - % ot Max. Emission s t o Atmospher e Stree m

Flo v - Lb./Hr . Flo v Cherecteristlc s - Continuou s o r Intermittent if Intermitten t - Hrs/Yr . Flo w Compositio

n- Tons/Tonof Pheno l (5 ) Cuaen e Cuaen a Hydroperoxid e Pheno l Acetone -Methy l Styren e Acetophanone Aceteldehyd e Formeldehyde Meaity l Oxid e Dimethy l Bensy l Alcoho l Bensene Toluene Ethy l Bensene Miec . Hydrocarbon s Cumyl Pheno l & Phenoli c Ter s Wate r Carbo nDioxide Nitrogen Oxygen Sempl e TepLocation Dat e o r Preouenc

y o f Samplin

g Typ e o f Analysi s Odor Problem

s Ven t Stock s Flo v - SCFM/stac k Number Heigh t - Feet Diameter • Inche e Exi t Cea Temp . ° F Emissio nContro l Device s Typ e - Incinerator Flare Scrubbe r Othe r Catalog I . D . Number Tota l HydrocarbonEmission s - Ton/To no f Pheno l Tota l Particulat e 6. Aeroao l Emission s - Ton/To no f Pheno l Tota l NO , Emission s - Ton/To no f Pheno l Emiealona - Ton/To no f Pheno l Fee d Purlflcetlo

n Sectio n Ven t Unknow n( D Contlnuou

e
(+ )

(+ )

12 ' u p< 7 

### > Never N o
1 11 2 2 Ambien t Ye a
Liqui dTrap PH- I (+ ) 0 Oxidatio n Sectio n Ven t 21,80 0 < 2 ^ Continuou s 22- 1 26.50 0 26,50 0 0 Concentra t i o n

Sectio n Vapo r Condense r Ven t 51. 3 (2 > Continuou s 

### (+ )

(+ )

.002 5 (2 )


### + + + + Elevated< 7 

### > Tvlc e G.C . +57 . Ye a (T nplant ) 435 0 ( 2 

### > 1 12 5 1 0 Ambient Ye s

Scrubber-Coole r PH- I I .002 5 (2> 0 .0000 1 (3 )

(+ )

+ + .0002 5 < 2 

### > + + + Elevete d (7 ) 

### Tvlc e (197 0 6 . 1972 ) G.C . +10 % N o 10. 2 <2 ) 1 4 0 2 Ambien t Ye s

Vapo r Condenser PH-II I .000 3 <2 ) 0 Cleavag e Sec t io nVapo r Condenser Ven t Unknow n Continuou

a

(+ )
(+ ) (+ )

+ (57. )
+ + + + (7 ) Elevate d Once (1972 ) C C . +107 . N o
1 2 0 2 Ambien t Ye s

Vapo r Condense r Pll- X + 0
Tote l SO , Tota l C O Emleeione - Ton/To no f Pheno l

0 0

### r\ i I III * 

# i ; 1 . V i

TABL E PH-II I NATIONA L BWSSION B INVENTOR Y PHENO L PRODUCTIO N FRO M CUMEN

E 

### Pag e 2 o f 1 3 lan t- E M Cod e Numbe r ipaclt y - Ton e o f

Phenol/Yr . parag e Productio n - Too e o f Phenol/Yr . •arbsrl y Productio n Variatio n - I o f Max . deelon e t o Atmospher e Straa a

Flo v- Lb./Hr . Flo wCharacterlatlc a- Continuou s o rIntermitten t I f Intermitten t- Hre./Yr . Flo v Compoaltlo a• Tone/To n o f Pheno l (5 ) Pheno l 6 . Acetone Sap'av/Fvrlfteat Io n SentIon Vapor Cond
. Vent s Onknovn Continuou s 22 T 

### 1 26,50 0 26,50 0 0 Pheno l Recovery& Sep'n . Sectio n Vepo r Cond
. Ven t Unknow n Continuou s Residua l Oi l Sum p Ven t Unknow n Continuou s

Cuaen e Hydroperoxid e Aceton e .«Methy l Styren a Acetophenon e Aceteldehyd e Form aldahyd e Healty l Oxid e Dimethy l Benxy l Alcoho l Bensen e Toluen e Ethy l Bensen e Mlee . Rydrocarbon a Cuay l Pheno l & Phenoli cTar s Wate r Carbo n Dioxid e Nitroge n Oxyge n Sampl e Te p Locatio n Dat ao rFrequenc y o f Samplin g Type i o f Analysi s Odo rProblem s n tStack a Flo w- SCFM/atac k Numbe r Heigh t- Fee t Diamete r- Inche e Exi tCa aTamp . ° F isalo n Contro l Device s Typ a- Inclnarato r Flar a Scrubbe r Othe r Catalo g I . D . Nuabe r t a l Hydrocarbo n Emissio n • Ton/To n o f Pheno l t a l Particulat e & Aeroeo l Emlsalon s - Ton/To n o f Pheno l t a l NO , Emission s - Ton/To n o f Pheno l t a l SO , Emission s - Ton/To n o f Pheno l t a l C O Emission s - Ton/To n o f Pheno l 

### (+ )

(7 ) (+ )

Elevete d Neve r N o
1 12 0 3 Ambient Te a

Vapor Condenae r PH-XI , XI I (+ ) <* > 0 

### (+ )

(7 ) 

### (+ )

Elevete d Neve r N o


### 1 12 5 3 Ambien t Ye s
Vepo rCondense r PH-XII I (+ ) 0 Phenoli c Wate r Sum p Ven t Unknow n 

### Continuou s

( + )



### (+ )

No por t Neve r N o <<> >
1 3 0 2 Ambien t Ye s

Ye s 

## (< 0 PH-XIV ( + ) 0 (7 ) (+ )

No por t * 7 

### * Neve r Ye s (« )
1 2 4 6 Ambien t Non e

(+ ) 0

C O

## —t l_ - i

Len t- E M Cod e Nemma

r ipaclt y - Ton e o f

Phenol/Yr . rereg e Productio n • Ton e o f Phenol/Yr . terterl y Productio n Verletlo n - I o f Max . ilaalon e t o Atmoaphar e Strea m

Flo v- Lb./Hr . Flo vCharactarlatlc a- Contlnuou ao rIntermitten t I f Intermitten t- Hra./Y rFlo v Compositio n - Tons/To n o f Pheno l O Cuaan aHydroperoxid e Pheno l Aceton e ^.Matby l Styren e Ac e toph e non e Aceteldehyd e Formaldehyd e Meelty l Oxid e Dlaathy l Banxy l Alaoho l Bensen e Toluen e Ethy l Bensen e Mac . Hydrocarbon s Cumyl Pheno l & Phenoli cTar s Wate r Carbo n Dioxid e Hltroge n Oxyge n Sampl e Ta p Locatio n Dat ao rFrequenc y o f Samplin g Typ ao f Analyal a Odo rProblem e an tStack a Flo v- SCFM/etac k Nuabe r Heigh t- Fee t Diamete r- Incha a Exi tCa aTemp . ° F missio n Contro l Device s Typ a• Incinerato r Flar a Scrubbe r Othe r Catalo g I . D . Number ota l Hydrocarbo n Emission s - Ton/To n o f Pheno l ota l Particulat e &

> Aeroao l Emission s - Ton/To n o f Pheno l ota l NO , Bedaalon s • Ton/To n o f Pheno l ota l SO , Badaaion s - Ton/To n o f Pheno l ota l C O Emission s - Ton/To n o f Pamme l TABL E PH-II I NATIONA L EMISSION

S INVENTOR

Y PHENO L PRODUCTIO

N FRO M CUMEN

E Pag e 3 o f 1 3



### Oddatlo n Concentratio n Cleavag e Sectio nPum p Drai nSamplin g Ven t 1.45 5 Continuou s

.000000 9 (9 )

(7 ) + + + + A t grad e Onc e (1972 ) G.C . +5 X N o .2 9 1 7 0 2 Ambient None

.000000 9 0 (9 ) 22- 1 26,50 0 26,50 0 0 Mis c Vent Wate r Scrubbe r Stac k "< » Unknov n Continuou s 

### (+ ) (+ > (+ ) Proces s Bottom s Transfe r Pum p Unknow n Occasiona l

(+ ) (+ ) (+ ) (+ ) Need plot form Neve r N o
1 8 7 1 4 Ambien t

Ye s PH-XI V (+ ) 0 (7 ) (+ ) Ho t Ftac k <7 ) No t Sample d Occasiona l (8 )



## (I D (+ ) 0an t - E M

Cod a Number paclt y - Tone o f Phenol/Yr . eroge Productio

n- Tone o f Phenol/Yr . artarly

Productio

nVariation- X

ol Max . Strea m

Flo v- Lb./Hr . Flo vCharacteristic s - Continuou s o rIntermitten t i f Intermitten t- Hra./Yr . Flo v Compositio n - Tons/To n o f Pheno l (5 ) Cuman e Cuaen e Hydroperoxid e Pheno l Aceton e
• < Methy l Styren e Acetophenon e Acateldehyd e Foraeldehyd e Mealty l Oxid e Dimethy l Bensy l Alcoho l Bensen e Toluen e Ethy l Bensen e Misc . Hydrocarbon s Cuay l Pheno l 6 Phenoli cTer a Wate r Carbo n Dioxid e Nitroge n Oxyge n Seapl e Ta p Locatio n Dat ao rFrequenc y o f Samplin g Typ e o f

Analysi s Odo rProble m i n tStack a Flo v- SCFM/etec k Numbe r Heigh t- Fee t Diamete r• Inche e Exi tCe e Temp . ° F ala s io n Contro l Device s Typ e - Incinerato r

Flar e Scrubbe r Othe r Catalo g I . D . Numbe r ote l Hydrocarbo n Emission s - Ton/To no f Pheno l ote l Pertlculet e (• Aeroao l Emission s - Ton/To no f Pheno l ota l N O Emission s - Ton/To n o f Pheno l ote l S O Emission s - Ton/To n o f Pheno l ote l C O Emission s - Ton/To n o f Pheno l TABL E PH-II I NATIONA

L EMISSION S INVENTOR Y PHENO L PRODUCTIO

N FRO M CUMEN

E Pag e 4 o f 1 3

Oxidatio n Sectio n Ven t 114,30 0 Continuou s

0 t o .00 5

(13 )

(+ )

Active . Carbo

n 0 t o .00 5 < 12 ' (12 ) 22- 3 200,00 0 200,00 0 0 Oxida t io

n Sectio n Incinerato r Stac k 128,60 0 (13) ' Continuou s (15 ) Gase s (Calc. ) e x Incinera t io

n o f Ligh t Oi 1 Vast e 47,10 0 ' l6 > Cont inuou s Case s ( Calc.) e x In c i nera t i o

n o f Heav yOi 1 Wast e 142,00 0 fl; ) Cont i nuou s

"trace " (orgs. ) 0 t o .002 4 2.262 5 .119 0 Stelrwe y scces s e torigina l stsrt-u p Org

. G.C

. +20 1 Ye s (I n plsnt ) < 1A > 25.70 0

50 ° (+ ) Trec e
+ + 

### Difficul t Neve r N o d5 ) 20,25 0 1 5 5 7 2 450 ° Ye s (15 ) .052 2 .152 1 .667 9 .109 3 Non e '»8 ) .083 3 .358 3 2.181 3 .335 4 None 0* 0

Boile r (Fuel ) Boile r 0 1 Boile r (Fuel ) Boile r # 2 PH-I V (+ ) "trece " 0



## Ih o

# I I I I I I I

TABL E PH-II I NATIONA L EMISSlONS~INVENTQR Y PHENO L PRODUCTIO

N FRO M CUMEN

E Pag e 5 o f 1 3 in t- E M Cod e Nuabe r |>eclt y - Ton e o f

Phenol/Yr . •rag e Productio n - Ton s o f Phenol/Yr . irterl y Productio n Variatio n - X o f Max . Straa a

Flo v- Lb./H r Flo vCharacterletlc s - Continuou s o rIntermitten t I f Intermitten t- Hrs./Yr . Flo v Coapoeltlo n - Tons/To n o f Pheno l (5 ) Cumen e Hydroperoxid e Pheno l Aceton e

- < Methy l Styren e Acatophenon e Acetaldehyd e Formaldehyd e Meslty l Oxld a Dtamthy l Bansy l Alcoho l Bensen e Toluen e Ethy l Bensen e Misc . Hydrocarbon s Cuay l Pheno l & Phenoli cTer a Wate r Carbo n Dioxid e Nitroge n Oxyge n Sampl e Ta p Locatio n Dat ao rFrequenc y o f Samplin g Typ ao f Anelyal e Odo rProble m in tStack a Flo v• SCFM/etec k Nuabe r Heigh t- Fee t Diamete r- Inche s Exi tGa s Teap . ° F slsslo n Contro l Device s Typ e - Incinerato r

Flar a Scrubbe r Othe r Catalo g I . D . Nuabe r >ta l Hydrocarbo n Ealaaton a- Ton/To n o f Pheno l >ta l particulat e 6

, Aeroso l Emission s - Ton/To n o f Pheno l ita l NO , Emission s - Ton/To n o f Pheno l >ta l S O Emission s - Ton/To n o f Pheno l jta l C O Bmlaaion a- Ton/To n o f Pheno l Oxidize r Sectio n Ven t 53,50 0 0» > Continuou s
.002 0

arr i ( 1 » .003 2
.001 5

.001 7 1.655 0 .100 0 Easil y arrange d Neve r N o 

### 12,00 0 1 70 1 4 45 °

Refrlg . 7 3 psl g Cond . ( 2 0 

### > PH- V .006 7 Post Oxidize r Washer , Surg e Combinatio

n Ven t 79 0 (« ) Continuou s 2 2

125 , 125 , 0 Tan k 00 0 00 0 Cumen

e Stripper Je t Condense

r Ven t Unknow n Continuou s Aceton e Toppin

g Colum nOverhea

d Accumulator 6 4 d9 ) Continuou s .000 3



### + + Never(19 ) Yes (i n plant ) 18 0 1 3 0 4 85 °

1 8 psl g Chille r< 2 

### ° ) PH-I X .000 3 Couldarrang e Never N o Unknow n 1 4 0 6 130 °

C . W Condenser .001 2
.000 9 (+ )

(+ ) (+ ) Couldsrrang

e Never ( l9 

### ) Ye s (I nplant ) 7. 8 1 8 0 1 0 110 °

C . W . Condenser .002 1

## i i t 

## i i t j ti 

# i i i i i i i i 

# r

TABLE PH-II I NATIONAL EMISSION S INVENTOR Y PHENO L PRODUCTIO

N FRO M CUMEN

E Page 6 o f 1 3 len t • B M Cod a Nuabe r •paclt y - Tone o f Phenol/Yr . verag e Productio

n- Ton s o f Phenol/Yr . uarterly

Productio

nVariation- I O f Max . Strea a

Flo v - Lb./Hr . Flo v Charecterlatlc a - Continuou s o r Intermittent I f Intermittent - Hre./Yr . Flo y Compositio

n- Tone/Tono f Pheno l ( s > Cumen e Hydroperoxide Pheno l Aceton e • 4 Methyl Styrene Acetophenone Acetaldehyde Formaldehyd

e Meslty l Oxide Dimethy l Banxy l Alcoho l Pos t Cleavag e Reactor Vapo

r Condenae r Ven t Unknown Continuou s



### (+ ) Pos t Clesvag e Washe r Ven t Unknow n Continuou s

Toluen e Ethyl Bensene Misc . Hydrocarbon

a Caay l Pheno l & Phenoli c Tor e Wate r Carbo nDioxide Nitroge n Oxyge n Sampl e TapLocation Dat a or Frequenc

y o f Seapling Typ e o f Analysi s Odo r Proble

m Ven t Stack s Flo v - SCFM/stack Numbe r Heigh t - Feet Diameter - Inchee Exi t Ga s Temp - ° F Emissio nContro l Device s Typ e - Inclneretor Flere Scrubbe r Other Catalo g I . D . Number Tote l Hydrocarbo

nEmission s - Ton/To n o f Pheno l Tote l Perticulet e & Aeroeo l Emission s - Ton/To n o f Pheno l Tots l NO , Emission s - Ton/To n o f Pheno l Tote l SO , Emission s - Ton/To n o f Pheno l Tote l C O Emission s - Ton/Tono f Pheno l (+ ) (• )



### (+ )

(+ ) (+ ) ( + > (+ )

C . W . Condenser (+ ) (+ ) 22- 4 OD 125,00 0 125,00 0 0 Phenol-Aceton e Stil l Vapo r Condense r Ven t Unknov n Con t inuou s



### (+ ) Aceton e ( H lum n Vapo r Condense r Vent Unknov n Con t inuou s



### (+ ) Pheno l Hecouer y Overhead Accumul PI

< Sectio n wen t Unknov n Con t i nuou s


### (+ )

(+ ) (+ ) 

## (+ )

C . W . Condense r (+ ) Condense r 

### (+ )

C O

### TABL E PH-II I NATIONA L EMISSION

S INVENTOR

Y PHENO L PRODUCTIO

N FRO M CUMEN

E Pag e 7 o f 1 3
n t- E M Code Nuabe r paclt y - Ton s o f

Phenol/Yr . ereg e Productio n - Ton s o f Phenol/Yr . artarl y Productio n Variatio n - X ot Max . laelon s t o Atmospher e Strea m

Flo w- Lb./H r Flo wCharacteristic s - Continuou s o rIntermitten t i f Intermitten t- Hrs./Yr . Flo v Coapositlo n - Tone/To n o f Pheno l ( 5 

### ) Cumen e Cuaam m Hydroperoxid e Pheno l Acetone

. < Methy l Styren e Acatophenoo e Acetaldehyde Formaldehyd

e Maelty l Oxld

a Dimethy l Benxyl Alcoho l Toluene Ethy l Bensen

e Mlac . Hydrocarbon

a Cumy l Pheno l & Phenoli c Ter a Wate r Carbo nDioxid

e Nitrogen Oxyge n Sampl e Tap Locatio n Dat ao rFrequenc y o f Samplin g Typ ao f Analysi s Odo rProblem s in tStack s Flo v• SCFM/stac k Heigh t- Fee t Dlaaxate r- Inche s Exi tCa aTamp . ° F •leelo o Contro l Devlce e Typ a- Incinerato r Flar e Scrubbe r Othe r Catalo g I . D . Numbe r >ta l Hydrocarbo n Emission s - Ton/To n o f Pheno l ita l Particulat e & Aeroso l Emission s - Ton/To n o f Pheno l >ta l NO , Emission s - Ton/To n o f Pheno l >te l SO L Emission s - Ton/To n o f Pheno l >ta l C O Amission s - Ton/To n o f Pheno l 22- 5 107,50 0 107,50 0 0 Spen t Oxidatio n Ai r 48.08 0 (" > Continuou s
.001 5 (« )



## (+ ) (+ ) (+ ) .001 5 1.664 2 .130 9 Coul d instal l Neve r Non e N o 10,19 0 1 8 6 

### 1 0 40 °

Refrlg
. 7 0 psl g Condense r PH-V I .001 5 (" > Oxidize r Off-ge s Ven t (« ) 36,99 5 (Se e note )
.038 3

.001 5
(+ )
(+ ) .029 5 1.302 2 .103 2 Eesy eccee s zv Monthl y fro a 9/7 1 Acetone Scrub
. GL C Ye s (i n plsnt ) 757 6

100 ° @ 2 8 psl g

.039 8 ( 23 

### > 22- 6 100,00 0 100,00 0 0 

### Pos tOxidize r Cumen e Recover y Spen tAi r Ven t 33,97 3 Continuou s Pos tOxidize r Concentrat 1 o n Condense r Ven t 6 . 0 

### Continuou s Cleavag e Condense r Ven t 6 . 5 

### Continuou s
.002 0

.001 4

(+ ) .040 8 1 220 3 .095 1 Ees y ecces s 3 x/mont h fro

m 9/7 1 Aceton e Scrub
. GL C No 757 6 1 8 6 1 2 140 °

Carbo n Absorbe r PH-VI I .003 4 (24 ) 0000 2

.00000 7
.00000 2 .00000 1 .000000 2 (+ ) .0000 1 .0001 3 .0000 7 Easy , 10 ' up 9/1 8 6
. 9/20/7 2 C C . + 207
. No 1 1 1 7 6 2 105 °

.0000 3 .000 2
(+ ) (+ )

.0000 3 .0000 3 .0000 2 Easy . 5 ' u

p Neve r Desig n Calc . . + 20"/
. N o 0.8 3 7 6 2 95 °

.000 2

r o

## I s ili i

TABLE PH-II I NATIONA L EMISSION S INVENTOR Y PHENO L PRODUCTION FRO

M CUMEN

E Pag e 8 o f1 3 

### o t- E M Cod aNuabe r eclt y - Ton s o f

Phenol/Yr . rag aProductio n - Ton e o f Phenol/Yr . rterl y Productio n Variatio n - X o f Max. aalon e t o Ataoepher e Strea m



### Flo v- Lb./Hr . Flo vCharacteristic s - Continuou s o rIntermitten t I f Intermitten t- Hra./Y rFlo v Compositio n • Tona/To n o f Pheno l (5 ) 22- 6 100.00 0 100,00 0 0 Acetone Toppin g Colum n Vent 11 5 (25 )

Cumen e Hydroperoxid e Pheno l Aceton e «*J»thy l Styran e Acatophanon e Acetaldehyd e Formaldehyd e Mealcy l Oxid e Dimethy l Bansy l Alcoho l Continuou s

.004 3 

### Aceton e Tove r Ven t Unknov n Intermitten t ~160 0 (26 )

.000 3 

## (+ )

Toluen e Ethy l Bensen e Mac . Hydrocarbon a Cuap l Pheno l 6

. Phenoli cTar a Wate r Carbo n Dioxid e Hltroga n Oxyge n Sampl e Ta p Locatio n Dat ao rFrequenc y o f Samplin g Typ ao f Analyal s Odo rProblem s Ven tStack s Flo v- SCFM/atac k Heigh t- Fea t Dlaaate r- Inche s Exi tGa s Taap . ° F Emissio n Contro l Device s Typ e - Incinerato r Plar a Scrubbe r Othe r Catalo g I . D . Numbe r Tota l Hydrocarbo n Emlaaion a- Ton/To n o f Pheno l Tote l Particulat e & Aeroso l Emission s - Ton/To n o f Pheno l Tota l NO , Emission s - Ton/To n o f Pheno l Tote l SO , Emission s - Ton/To n o f Pheno l Tota l C O Emission s - Ton/To n o f Pheno l 

### (+ ) (+ ) Eesy ecces s Delly (liquid ) Celc . « CC . o

neqult . liqui d Yes , Infrequentl y

of f plen t 12. 8 

### 1 8 6 

### 6 130 ° 

### + + Remove drai nbel l Neve r Celc . 

### N o


### 1 8 6 1 8 95 °

.004 6 ( 2 5 

### > (26 ) 

### et Methy l Styren e Towe r Ven t 1 1 Continuou s
.000 1 Natura l Gas Fire d Rebolle r Stac k

.0000 5
.0000 4 .000 2 

## (+ )

Difficul t Dall y fo r> 1 yea r Calc . e xG.C . o n equll . liqui d Yes , Infrequentl y of f plan t 0.7 0 1 7 0 4 

### 289 °

000 4 (27 )
.0000000 4

lo i

## i I \ 

## I 

## 1 i i . i

TABL E PH-II I

Plen t- E M Code Nuabe r Capacit y - Ton s o f

Phenol/Yr . Averag e Productio n - Ton ao f Phenol/Yr . Chiarterl y Productio n Variatio n - X o f Max . Emission s t o Atmospher e Strea m

Flo v- Lb./Hr . Flo vCharacteristic s - Continuou s o rIntermitten t I f Intermitten t- Hra./Yr . Flo v Compositio n - Tons/To n o f Pheno l (5 ) Cumen e Cuaen aHydroperoxid e Pheno l Aceton e <• * Methy l Styren e Acetophenon e Aceteldehyd e Formaldehyd e Msslty l Oxid e Dimethy l Bensy l Alcoho l Bensen e Toluen e Ethy l Bensen e Misc . Hydrocarbon s Cumy l Pheno l & Phenoli cTor e Wata r Carbo n Dioxid e Nitroge n Oxyge n Sampl e Ta p Locatio n Dat ao rFrequenc y o f Samplin g Typ e o f Analysi s Odo rProblem s Ven tStack s Flo v- SCFM/stac k Nuabe r Heigh t• Pea t Diamete r- Inche e Exi tGa s Tamp . ° F Emissio n Contro l Device a Typ e - Incinerato r Flar a Scrubbe r Othe r Catalo g I . D . Nuabe r Tote l Hydrocerbo n Emission s - Ton/To n o f Pheno l Tota l Pertlculat e (, Aeroeo l Emission s - Ton/To n o f Pheno l Tote l NO , Emission s - Ton/To n o f Pheno l Tote l SO , Emission s - Ton/To n o f Pheno l Tota l C O Emission s - Ton/To n o f Pheno l NATIONA L EMISSION S INVENTOR Y PHENO L PRODUCTIO

N FRO M CUMEN

E 22- 7 40,00 0 40,00 0 0 Pos tOxidize rPos tOxidize r Carbo n Sorbe rStee m Je t Ven tVen t 23,80 0 ( 2 8 > N o det e Continuou s Continuou s Pheno l Recover y Purificatio n Ven t N o dat a Pag e 9 o f 1 3

Produc t Recover y Sectio n Stea m Je t Ven t No dat a Aceton e Recover y Sectio n Ven t No dat a 

## '
.002 9 

### (+ ) (+ ) (+ )

(+ )

Difficul t 4 time s pe ryee r GL C o ncond . llq . Undetermined 533 0 No t give n


### 41 °

Carbo n Adsorbe r PH-VII I .002 9 

### (+ )

(+ ) (+ ) (+ ) (+ ) 

### (+ ) (+ )

I 5 0 4 70 ° 1 7 0 4 70 ° 1 7 5 4 70 ° 1 7 5 4 70 °



### (+ ) (+ ) (+ ) (+ )

T l h o

### TABL E PH-II I NATIONA L EMISSION

S INVENTOR

Y

>n t- E M Cod e Nuabe r peclt y - Ton s o f

Phenol/Yr . crag e Productio n - Ton s o f Phenol/Yr . srterl y Productio n Variatio n - X o f Max . lealon at o Ataxtapher e Strea m

Flo v- Lb./Hr . Flo vCharacteristic s - Continuou s o rIntermitten t I f Intermitten t- Hra./Yr . Flo v Compoaltlo n - Tone/To n o f Pheno l (5 ) PHENO L PRODUCTIO

N FRO M CUMEN

E 22- 7 40,00 0 40,00 0 0 Produc toCMathy l Styren e Recover y Sectio n Recover y Sectio n Ven tStea m Je tVen t N o dat e No det e Pag e 1 0 o f 1 3

OCMethy l Styren e Recover y Sectio n Ven t No dat a Residua l Fue l Recover y Sectio n Ven t N o dat a



### Cumen e Hydroperoxid e Pheno l Aceton e er f Methy l Styren e Acetophanon e Acetaldehyd e Formaldehyd e Healty l Oxid e • Dimethy l Battay l Alcoho l Toluen e Ethy l Benzen e Mac . Hydrocarbon e Cuay l Pheno l & Phenoli cTar s Wate r CarbonDioxide Nitrogen Oxyge n Sampl e Ta p Locatio n Dat ao rFrequenc y o f Samplin g Typ e o f Analyal e Odo rProblem s in tSteck a Flo w- SCFM/etac k (+ )

Height - Fee t Diamete r - Inche a Exi t Ca e Tamp . ° F alsslo nContro l Device s Typa - Incinerato r Flar a Scrubbe r Othe r Catalog I . D . Number ota l Hydrocarbo

nEmission s - Ton/To no f Pheno l ota l Particulat e & Aeroso l Emission s - Ton/Tono f Pheno l s i NO , Ealeelone - Ton/To no f Pheno l ota l SO , Bad.salon

s - Ton/To

no f Pheno l ote l C O Emission s - Ton/To no f Pheno l 1 7 5 4 70 °

<+ ) (+ ) (+ )

(+ )
(+ ) (+ ) (+ ) 

### (+ )
(+ ) (+ ) (+ )

1 5 0 4 70 ° 1 5 0 4 70 ° 1 7 5 4 70 °

(+ ) (+ ) (+ )

r o ^ iTABL E PH-II I

t - E M Cod e Nuabe r cit y - Ton s o f Phenol/Yr . eg e Productio n- Ton e o f Phenol/Yr . terl y Productio nVariatio n- X o f Max . slon s t o Atmospher e tree a

lov - Lb./Hr . lo v Characteristic s - Continuou s o r Intermitten t I f Intermitten t - Hre./Yr . Flo v l ( 5 > 

### oppositio n - Tons/To n o f Pheno l Oxidize r Sectio n Ven t 14,22 0 Continuou s NATIONA LEMISSION S INVENTOR Y PHENO LPRODUCTIONFRO

M CUMEN

E



### Concentratio n Sectio n Combined Vent s 1 8 

### Continuou s 22- 8 30,00 0 30,00 0 7
. 57

. Cleavag e Sectio n Combine d Vent s 4 8 

### Continuo u
.004 0 

### (29 ) Cumen e Hydroperoxid e Pheno l Aceton e o< Methy l Styren e Acetophenon e Aceteldehyd e Formaldehyd e Meelty l Oxid e Dimethy l Bensy l Alcoho l Bensen e Toluen e Ethy l Bensen e Msc . Hydrocerbon e Cumy l Pheno l A Phenoli cTer a Wate r Carbo n Dioxid e Nitroge n Oxyge n tmpl aTap Locatio n Dat ao rFrequenc y o f Samplin g Typ e o f Analysi s OdorProblem a Stack a Flo v• SCFM/atec k Nuabe r Heigh t• Fee t Dieaete r- Inche s Exi tGa s Temp . ° F aa*lo n Contro l Devlce e Typ e - Incinerato r Flar e Scrubbe r Othe r Catalo g I . D . Nuabe r 1 Hydrocarbo n Emission s - Ton/To n o f Pheno l e l particulat e A Aeroeo l Eadaelon s - Ton/To n o f Pheno l 1 NO , Emission s - Ton/To n o f Pheno l a l SO , Emission s - Ton/To n o f Pheno l a l C O Emission s - Ton/To n o f Pheno l 

## (+ ) (+ )

.004 0 

### 1.771 1 .095 9 Non e (difficult ) Neve r Desig n Celc . (+20X ) Yea , I n plan t 320 0 1 5 0 6 65 ° .0000 5
.0000 3 

## (+ ) (+)

.001 9
.000 5 

### None (difficult ) Neve r Dealg n Calc . (+30X ) N o 

### .8 9 1 6 7 2 0 

### 4.8 5 1 1 5 2 .0 6 

### 1 5 0 3 -v/125 o 

### < 30 

### )215 ° 100 °

.004 0 ( 2 9 

### > .000 1 Pag e 1 1 o f 1 3

.002 4



### .001 3

.002 6



### Non e (difficult ) Neve r Dealg n Calc . (+507. ) Yes . i nplan t

. 2 1 6 0 1 3. 8 

### 1 9 3 1 6 6. 6 I 1 5 3 150°~12 5 (3° ) 215 °

.003 7 

### Produc t Recover y Sectio n Combine d Vent s 47. 5 Con t inuou s

.000000 7



### (+ ) .006 2

' .0000 3 

### Non e (difficult ) Neve r Desig n(+407 ) N o 0. 5 16.6 3 1 1 2 1 5 1 4 1^.0 ° O" ) 215 °

.000000 7 

### Phenoli c Heavy F.nd s Flar e 72,80 0 (31 ) Intermitten t 16 8

(+ ) (+ ) 021 7 024 1

, .137 1 .021 0 Ver ydifficul t Neve r Desig n Calc.r+207. ) Yes , I n plan t 

### 16,50 0 1 4 1 5 1000 ° Ye s Ye s

PII-X V (+ )

V Si o o

### TABL E PH-II I NATIONA L EMISSION

S INVENTOR

Y PHENO L PRODUCTIO

N FRO M CUMEN

E Pag e 1 2 o f 1 3 len t- E M Cod e Numbe r ipaclt y - Ton ao f

Phenol/Yr . rerag e Productio n • Ton s o f Phenol/Yr . larterl y Productio n Verletlo n - X o f Mex . ilsslon s t o Atmospher e Strea a

Flo v - Lb./Hr . Flo v Cherectarlatlc a - Contlnuoue or Intermitten t I f Intermittent - Hre./Tr . Flo v Compositio

n- Tons/Too o f Pheno l ( 5 

### > Poet Oxidlse r Recover y Section Ven t 11.27 0 <" > Continuou s CH P Conc'n . & Decomp . Sectio n Stee a Educto r Ven t Unknov n Continuou s 

### 2 2 2 8 2 8 - 9 50 0 50 0 297 . Re v

Aceton e Colum n Ven t Unknow n Continuou s



### Ouann a Hydroperoxid

e Pheno l Aceton e

- 4 Methy l Styren e Acetophanon e Aceteldehyd e Formaldehyd e Mealty l Oxid e Dimethy l Benxy l Alcoho l Baoxen e Toluene Ethy l Bonsan

e Mac . Hydrocarbon s Cumyl Pbono l A

Phenoli c Tor e Wate r CarbonDioxid

e Nitrogen Oxyge n Sampl e Ta p Locatio n Dat ao rFrequenc y o f Samplin g Typ ao f analysi s Odo rProblem s n tStack a Flo w- SCFM/stac k Cumen e Colum n Stea m Educto r Ven t Unknow n Continuou s 

## (+ )

(+ ) (+ ) (+ )

r Heigh t- Fee t Diamete r• Inche e Exi tCa aTaap . ° F leolo aContro l Devlce a Typ a- Incinerato r FUr e Scrubbe r Othe r Catalo g I . D . Numbe r t a l Hydrocarbo n Emission s - Ton/To n o f Pheno l t a l Particulat e A Aeroeo l Eedealon a- Ton/To n o f Pheno l t a l NO , Eadaelon e - Ton/To n o f Pheno l t a l SO Ba

d salon s - Ton/To n o f Pheno l t a l C O auteeloo B - Ton/To n o f Pheno l tXMethy l Styren e Column Stea n Educto r Ven t Unknovn Continuou s 

## (+ )

(+ ) (+ ) (+ ) 

## +

?1.674 4 None , difficul t Neve r Non e Yea , of f plan t Infreq . 250 0 1 4 5 1 4 70 ° 

### + 

## + + + Ver y difficul t Never Non e N o
2 5 7 1. 5 200 ° (+ ) (+ ) Ver y difficul t Neve r Non e "Not eppliceble "

1 8 0 3 70 ° +
+
+ + Ver y difficul t Never Non e N o
1 10 5 1. 5 200 ° +
+
+ + Ver y difficul t Never Non e N o
1 9 5 1. 5 200 °

### ' I 

# L ,

TABL E PH-II I

en t- E M Cod e Nuabe r peclt y - Ton s o f

Phenol/Yr . ereg e Productio n - Ton s o f Phenol/Yr . erterl y Productio n Variatio n - X o f Max. laalon at o Ataoapher c Strea m
Flo v- Lb./Hr . Flo v Cherecterlstie s - Contlnuoue o r Intermittent I f Intermittent - Hra./Yr . Flo y Compositio

n- Tons/Tono f Pheno l * 5 

### ' Cumen e Cumen e Hydroperoxide Pheno l Acetone « 4 Methy l Styren e Acetophenon

o Acetaldehyde Formaldehyde Maelty l Oxide Dimethy l Benzy l Alcoho l Bensene Toluene Ethyl Bensene Misc . Hydrocerbon s Cumyl Pheno l & Phenoli c Tera Wate r Carbo nDioxide Nitroge n Oxygen Sampl e TepLocation Dat a o r Frequency

o f Samplin

g Typ e o f Analysi s Odo r Problem

a i t Stack s Flo v - SCFM/stac k Nuaber Heigh t - Feet Dleaeter - Inche s Exi t Ga s Taap . ° F [sslo nContro l Device s Type - Incinerator Flare Scrubbe r Other Catalog I . D . Nuabe r :e l Hydrocerbo

nEmission s - Ton/To no f Pheno l :e l Particulat e A

Aeroao l Emission s - Ton/To no f Pheno l :a l NO , Emlaelone - Ton/Tono f Pheno l e l SO , Emission s - Ton/Tono f Pheno l :e l C O Emission s - Ton/Tono f pheno l NATIONA L EMISSION S INVENTOR Y PHENO L

Phonos * ' Colea nStea m Eductor Ven

t Unknovn . Continuou s PRODUCTIO N FRO M CUMEN E

Residue - Strippe r Steo

m Eductor Ven

t Unknov n Continuou s 22- 9 28,50 0 28,50 0 297 . Acetone Dilutio

n Colum n Ven t Unknow n Continuou s Acetone Concentratio

n Colum nVen t Unknow n Continuou s Pag

e 1 3 o f 1 3

Acetophenone Purificatio

nBatc h Stil l Stea

m Eductor Unknow n Intermittent



### (+ ) (+ )

(+ ) (+ )



## + +
+ + Ver y difficul t Neve r Non e N o
1 6 5 1. 5 200 ° +
+
+ + Ver y dlfflcu Neve r Non e N o
1 6 5 1 5 

### o 20 0 I

t 

### (+ )

(+ ) Ver y difficul t Never Non e "No t applicable "

1 8 0 3 70 ° (+ ) (+ ) None . Ver

y difficul t Neve r Non e "No t applicable "
1 9 3 3 70 ° +
+
+ + None , Ver

y difficul t Never Non e N o
1 9 5 2 200 °

+ (33 )

o

### - J I I

TABL EHP-II I NATIONALEMISSION S INVENTOR Y HIGH DENSIT Y POLYETHYLEN EPRODUCTION ipan y i tio n Cod e No . •cit y - Ton s o f

H.D . Polyethy lene/Yr . rag e Productio n- Ton s o f H.D
. P
. E./Yr

. ig e i nProductio n- X o f Max . salon s t o Atmospher e Strea m
Flo w- Lb./Hr . Flo wCharacteristi c- Continuou s o rIntermitten t I f Intermitten t- Hrs./Yr . Flo w Compositio n - Ton/To no f H.D . P.E . Hydroge n Ethylen e Buten e Iaobutan e Isopentsn e Hexen e Polyethylen e Cyclohexan e Ai r Alumin a Co-Monomer s Sampl e Ta p Locatio n Dat e o rFrequenc y o f Samplin g Typ e o f Analysi s Odo rP ro b le a n tStack s Flo vSCF

M pe rstac k Nuabe r Heigh t- Fee t Diamete r- Inche a Exi tGa s Temperatur e - F ° ilsalo n Contro l Device s Typ e - Fler e

Be g Hous e Cyclon e wate rScrubbe r Othe r Catalo g1 . D . Nuabe r ita l Hydrocarbo n amission s - ton/to nH.D . P . E . >ta l Particulat e - ton/to n t e l N0 „ - ton/to n at aI SO , - ton/to n 3ta l C O - ton/to n 24- 1 90.00 0 90,50 0 0 P.E . Strippin g & . Blendin g Ven t 200.40 0 Continuou s

.0176 8 8.83978

Up-strea m

o f HP- 1 Continuou s "Flammablllty " anal . N o No t Specifie d

"Dus t Precipitator " HP- 1 Reac t or Ven t 3.54 0 Intermitten t 1,25 0 I

| Non e j No t Sample d
N o No t Specifie d

X HP- 2 Emergenc y Ven t ex . Distillatio n No t Specifie d Intermitten t ( 3 min/lncident ) Equ i pt . Purg e & Emergenc yVen t ex . Compres s Sect . No t Specifie d Interm i tten t No t Spec i f ie d

Non e No t Sample d
N o Non e No t Sample d Pag e 1

Equ i pt . Purg e r Emergenc yVen t ex . Reacto r Sec t No t Specifie d Interm i t t en t No t Sep c i t i c d Ker ni p i

. I'.i r

yi * & Emergenc y Ven t ex . Holvme r

Recover y Si-it i No l Spe c i i ied In t erm i t ten t No t Spe c i1 i e d I

1 I

Non e No t Sample d Non e ; No t Sample d
I N o Ye s 1 23 5 3 0 No t Specifie d Ye s X

HP- 3 Canno t b e determine dbu t >.0176 8

Canno t be determine d

C OTABLEHP-Il l NATIONALEMISSION S INVENTOR Y HIGH DENSIT Y POLYETHYLEN EPRODUCTION Pag e 2 o f 5 ompan y ocet I o n P A Cod e Numbe r apaclt y - Ton s o f H.D
. Polyethylene/Yr

. verag e Productio n- Ton s o f H.D
. P.E./Yr

. ang e I n Productio n- 7 . o f Max
. mission s t o Atmospher e Strea m Flo w - lb./hr
. Flo v Characteristi c - Continuou s o r Intermitten t I f Intermitten t - hrs./yr . flo w Compositio n- ton/to n o f H.D . P.E . Hydroge n Ethylen e Buten e Isobutan e Iaopentan e Hexen e Polyethylen e Cyclohexen e Ai r Alumin a Co-Monome r Nitroge n Fue l Ga s Silic aGe l Sampl e Te p Locatio n Dat e o rFrequenc y o f Samplin g Typ e o f

Analyal s Odo rProble m ren tSteck e Flo vSCFM pe rstac k Numbe r Heigh t- Fee t Dlemete r- Inche s Exi tGa s Temperatur e - F ° Missio n Contro l Device s Typ e - Fler e

Be g Hous e Cyclon e Vote rScrubbe r Othe r Catalo g I . D . Numbe r Tota l Hydrocarbo nEmission s - ton/to nHDP E Tota l Particulete - ton/to nHDP E Tota l NO , Emission s ton/to nHDP E Tota l SO , Eaiaalon aton/to nHDP E Tota l C

O Emission s ton/to nHDP E Fee dPre p Sectio nPurg e No t Specifie d Intermitten t No t Specifie d



### + + No t Sample d Mat' l Bal . N o 24- 9 110,00 0 103,50 0 0 Solven t Recov
. Sectio nPurg e No t Specifie d Intermitten t No t Specifie d



### + No t Sample d
Mat' l Bal
. N o No t Ye s

Specifie d 1 15 0

Ye s + Emergenc y Ven t

e x . Peacto r 80,00 0 Interm i tten t ( 1 5 m i n/ i n c ident ) 

### + + + +

No t Sample d Mat' l Bal . N o Einergenc y Vrn t e x Solven t

I'r

. I'OO

- I 50 0 I n t e rm i f t en l No t Spe c i f

i e d

No t Sample d Mat' 1 Ba l N o

IIP- 4 Se e Continuatio no f Thi s Tabl eTABLE HP-Il l NATIONA

L EMISSION S INVENTOR Y HIG H DENSITY POLYETHYLEN E PRODUCTIO

N Pag e '. ) o l

>any I tio n Cod e Numbe r iclt y - Ton s o f

H.D . Polyethylene/Yr . rag e Productio n - Ton s o f H.D . P.E./Yr . g e i n Productio n- 7. o f Max
. salon s t o Atmospher e Strea m Flow - lb./hr . Flo w Characteristi c - Continuou s o r Intermitten t i f Intermitten t - hrs./yr . flow Compositio n- ton/to no f H.D . P.E. Hydroge n Ethylen e Buten e laobutan e Isopentsn e Hexen e Polyethylen e Cyclohexan e Ai r Alumin a Co-Monome r Nitroge n Fue l Ga a Silic a Ge l Sampl e Ta pLocatio n Dat e o r Frequenc y o f Samplin g Typ e o f Analysi s Odo r Proble m en t Stock s Flo w SCF M pe r stac k Nuabe r Heigh t - Fee t Dleaete r - Inche a Exi t Ca a Teaperetur e - F ° slaalo nContro l Device s Typ e - Fler e

Be g Hous e Cyclon e Wete r Scrubbe r I Othe r Catalo g 1 . D . Numbe r Tota l Hydrocarbo nEmission s - ton/to nHDP E Tota l Particulat e - ton/to nHDP E Tota l NO , Emission * ton/to nHDP E Tota l SO , Emission s ton/to nHDP E Tots l C O Emission s ton/to nHDP E 24- 9 110.00 0 103,50 0 0 Catalys t Activatio n Sectio nVen t 20 0 Continuou s Downstrea m

o f HP- 5

.0085 0

No t Sample d
Mat' l Bal . N o No t Specifie d

Ye s +

HP- 5 HDP E Conveyin g ex . Blendin g Ven t 42,17 2 (A ) Continuou s Downstrea m

o f HP- b

(Total ) 1.7928 0

No t Sample d
Mat' l Bal . N o No t Specifie d

Ye s lntermed

. Stg

. Conveyin g Ven t 680 0 < n Cont1nuou s Dovnstrea m o f

HP

—7

(Total ) .2720 0

HP- 6 (B ) 

# T

0355ti 4 No t Sample d Mat ' 1 Ba l

. N o No tSpec i fie d



### IIP- 7 (I D I' ac k ay i 1 1 g Cunvevo? " 96,40 0 fE ) Con t i nuou s Dovnstrea mo l llp- 8

(Totsl ) 3.8560 0

No t Sample d Mat' 1 Bal

. No No t Spec i f

ie d



### HP- H m

ailBlnliieAIO d M«U8 Q «A0 1 c o c oTABLEHP-Il l

mpan y c a tIo n A Cod e No . pacit y - Ton e o f

H.D . Polyethylene/Yr . erag e Productio n - Ton s o f H.D . P.E./Yr . ng e i n Productio n - 7 . o f Max
. ilsslon s t o Atmospher e Strea m Flow - Lb./Hr . Flo w Characteristi c - Continuou s or Intermitten t i f Intermitten t - Hrs./Yr . Flow Compositio n- Ton/To no f H.D . P.E . Hydroge n Ethylen e Buten e lsobutan e laopentan e Hexen e Polyethylen e Cyclohexan e Ai r Alumin a CO-monomer s Methan e Carbo nMonoxid e Carbo nDioxid e Unspecifie dHydrocarbon s Sampl e Ta pLocatio n Dat e or Frequenc y o f Samplin g Typ e o f Analysi s Odo r Problem ren t Stock s Flo v SCF M pe r Stac k Numbe r Height-Fea t Diameter-Inche s Exi t Ga s Teaperetur e - F ° •is*ionContro l Device s Typ e - Flar e

Ba g Hous e Cyclon e Wate r Scrubbe r Othe r Catalo g I . D . No . Tota l Hydrocarbo nEmission s - Ton/To nH.D . P.E . Tota l Particulat e - ton/to n Tota l NO , - Ton/To n Tota l SO , - Ton/To n Tota l C O - Ton/To n NATIONA L EMISSION S INVENTOR Y Hig hDensit y

Polyethylen e

24-1 0 151,00 0 151,00 0 0 Pit . I I Strippe r Syste m Vent 104 0 Continuou s

.0018 5 .0004 4

.0218 8

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## TABL E HP-II I EXPLANATIONO F NOTE S NATIONAL EMISSION S INVENTOR Y HIGH DENSITY POLYETHYLENE PRODUCTIO NPag e 5 o f 5 Not e Commen t ATota l maximu mflowfo r four separat e streams . B Devic e HP- 6 consist s o f 1 4 separat e ba g filter s wit h

an averag e o f four compartment s pe r filte r an d 1 5 bag s pe r compartment . C Reporte d dat a interprete d a s meanin g state d flowi s

tota l for eigh t separat e streams . D Devic e HP- 7 consist s o f 3 4 cyclone s an d 1 1 ba g filters
. Tabl e IV

list s the cyclone s unde r HP-7 a an d the ba g filter s unde r HP-7b
. E Reporte d dat a interprete d a s meanin g state d flowi s

tota l fo r four separat e streams . F Devic e HP- 8 consist s o f fou r cyclones
. G Responden t ha s verball yreporte d tha t hi s conveyo r

emissio n factor s ar e camparabl e t o thos e reporte d b y responden t 24-10
.

## 1 I 

## I I 

## I r I /

TABL E LP-II I NATIONA

L EMISSION S INVENTOR Y LO W DENSITY POLYETHYLEN E PRODUCTIO

N Pa^ e I ,.; " )

apan y catio n ' A Cod e No . ipaclt y - Ton s o f

L D Polyethylene/Tr . •rag e Productio n - Ton s o f LDPE/Yr . asona l Rang e i n Productio n - X ot Max . ilaalon s t o Atmospher e Strea m - Lette ro n Flo wDiagra m 24- 2 150,00 0 112,75 0 0 24- 3 110,00 0 110,00 0 0 24- 5 180,00 0 180.00 0 0
B 1 10.110 0 I 10,00 0 0
p . Descriptio n Flo w- Lb./Hr . o f

Pollutant s Flo wCharacteristi c• Continuou s o rIntermitten t i f Intermitten t- Hrs./Y rFlo w Compositio n - Ton/To n o f LDP E Ethylen e Polyethylen e Ai r Hydrocarbon s Sampl e Locatio n Dot e or Frequenc y

o f Samplin g Typ a o f Analysi s Odo r Proble

m »n t Stock s

Flov SCFM pe r stoc k Nuabe r Heigh t - Fee t Diamete r - Inche s Exi t Ga s Teaperetur e - F ° •isslo o Contro l Devic e Typ e - Fler e

Ba g Hous e Cyclon e Wate r Scrubbe r Othe r Catalo g I . D . Numbe r ota l Hydrocarbo nEmission s - ton/to nLDP E ota l Particulat e - ton/to nLDP E ota l N0 S - ton/to nLDP E ota l SO , - ton/to nLDP E ota l C O - ton/to nLDP E Othe r Emission s 514 * Continuou s

0.014 3 Non e

Non e Indicate d excep t fo remergenc y reacto roverpressur e

N o

0.014 3 Non e Liste d Non e Non e Non e Othe r Emission s 3* * Continuou s

0.000 1 Non e

0.000 1 Non e Non e Non e Non e Iso-Col . Emissio n 2 8 Cont inuou s

0.000 6 Ope nVen t Not Routinel y Mas s Spectrograph ' N o Non e Indicate d No tSpecifie d

0.000 6 Non e Non e Non e Non e Storag e Ven t 9 2 Con t i nuou s

0.00 2

No t Sample d
No t Analyse d No t Applicabl e Non e Indicate d li t he r Em i s s i on s 360 * Con t i nuou s

0.00 8 Non e

Non e Indicate d

No t Indicate d

0.00 2 

## *** * Non e Non e Non e Storag e Vei l Othe rEmission) . < 1 l, Con ti mum s Con tinuou s
0.0000 3 0.0 3 Non e No t Sample d Ind•rec t No t Applicahl e Ye s
lt. 0 Tota l No tIndicate d 7 5 1 0 Amb i en t N o 0.00 5 Non e

Non e Ind i ca te d

0.00 8 Non e Liste d Non e Non e Non e 0 0000 3 Non e Liste d Non e Non e Non e 0 000 5 Non e Liste d Non e Non e ' Non e

•Fro m materia l balance . '•Assumptio n ***"Teet s hav e bee n conducte d a tsevera l (other ) location s vit h goo d agreement" . • ••"Polyethylen e flne amay ala o b e entreine d I n th e ai rstream. " Mote : Fo rnon-pollutin g streams , pleas e se e Simplifie d Flo vDiagra m F'gur e LD- 1 . (Dravin g K-209 ) an d Tabl e IV .

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### I I

TABL E LP-II I NATIONA L EMISSION S INVENTORY LOV ' DENSIT YPOLYETHYLEN E PRODUCTIO N Pag e ? o f 3

Compan y Locatio n EP A Cod e Numbe r Capacit y

- Ton s o f L D Polyethylene/Yr . Avereg e Productio n- Ton s o f LDPE/Yr . Seeaona l Rang e I nProductio n- 7 . o f Max . Emission s t o Atmospher e Strea m Lette r o nFlo w

Diagra m 24- 7 182.50 0 182,50 0 0
B
Deecrlptlo n Flo w - ib./hr . o f Pollutant s Flo w Characte r tat l c i f Intermitten t Continuou s o r Intermitten t hrs./yr . flo v Compositio n- Ton/To no f LDP E Ethylen e Polyethylen e Ai r Hydrocarbon s Sampl e Locatio n Dat e o r Frequenc y o f Samplin g Typ e o f Analysi s Odo r Proble m Ven t Steck s Flo v SCP M pe r stac k Numbe r Heigh t - Fee t Diemete r - Inche s Exi t Co s Temperatur e - F ° Emlsalo nContro l Device s Typ e - Flar e

Ba g Houa e Cyclon e Wate r Scrubbe r Othe r Catalo g I . D . Numbe r Tota l Hydrocarbo nEmission s - Ton/To nLDP E Tota l Particulat e . ton/to nLDP E Tota l N0 XEmission s Ton/To nLDP E Tota l SO , Emission s Ton/To nLDP E Tote l C O Emission s Ton/To nLDP E Compresso r Purg e 2 3 Continuou s

0.000 5

No t Sample d
None * Non e Ye s 0.24 3 Ave . 2 1 5 0 4 10 0 Non e

0.000 5 Non e Non e Non e Non e Storag e Ven t 18 0 Continuou s

0.003 9 0.5 4
To po f pelle t bin s 

## * * * * N o Ye s 18 6 2 9 2 5 8 9 0 Non e

0.003 9 Non e Non e Non e Non e •"Equipmen t volum e plu s purg e procedure " use dt o determin e compositio nandflov . ••Sample e toke ndurin g th e laa t revision s t o th e purg e ai r system , abou t 1968 . ***Plo v

determine dfro

m purg e ai r syste m capacity .  I naddition , ther e ar e "compounding " en d"fine s removel " vent a vhic htota l les s tha n2 lbs./hr . LDP E fine s Note : Fo r non-pollutin g streams , plees e se e Simplifie dFlow Diagra m

Figur e LD-1 , (Drawin g R-209 ) an dTabl e I

V Intermediat e Storag e Vent- '

4 8 Con t inuou s

0.00 1 1.0 8
No t Sample d Compositio nEstimate d N o Ye s 345**  * 3 1 5 0 2 0 9 0 Non e

0.00 1 Non e Non e Non e Non e

c o ^ l

## ^

TABL ELP-II I NATIONA

LEMISSION S INVENTOR Y LO V DENSIT Y POLYETHYLEN E Pag e » o f 3
Compan y Locatio n EP A Cod e No . Capacit y - Ton s o f L D Polyethylene/Yr . Aversg e Productio n - Ton s o f LDPE/Yr . Sessone l Reng e I n Productio n - 7. o f Max
. Emission s t o Atmospher e Strea m Lette ro n Flo vDiagra m 24-11 * 150.00 0 150,00 0 0 7U- 1 2 150,00 0 150,001 ) 0 I ) Descriptio n Flo v- Lb./Hr . o f Pollutant s Flo vCharacteristi c- Continuou s o rIntermitten t i f Intermitten t- Hra./Yr . Flo v Compositio n - Ton/To n LDPE Ethylen e Polyethylen e NO , Vote rVepo r Carbo n Dioxid e Hydrocarbon s Sampl e Ta p Locatio n Dat e o rFrequenc y o f Samplin g Typ e o f

Analyal s Odo rProble m Ven tStack s Flo vSCF

M pe rStoc k Nuabe r Heigh t- Fee t Diamete r- Inche s Exi tCe aTemperatur e - F ° Emissio n Contro l Devlce e Typ e - Pler e

Be g Hous e Cyclon e Vote rScrubbe r Othe r Catalo g I . D . No . Tota l Hydrocarbo n Emission s - Ton/To n LDP E Tote l Particulat e - ton/to n LDP E Tota l N

O - Ton/To n LDPE Tote l SOj , - Ton/To n LDPE Tote l C

O - Ton/To n LDPE Purificatio n 6 Recover y Flar e 2 Continuou s

0.0000 6 0.04 2 0.09 5 Non e

Non e Indicate d Ye s 1,50 0 1 10 0 2 0 350 0 Ye s +

24- U 10 1 Non e Non e 0.0000 6 Non e Non e Othe r Emission s 21 1 Continuou s

0.00 6 Non e 

## * * Non e Indicate d No tIndicate d

Non e Indicate d

0.00 6 Non e Non e Non e Non e Material ? Handlin g Vent*** * 4 4 Con t inuou s
0.000 8 0.000 3

Non e

N o Ye s 72 5 Av e 6 9 o O 2 4 10 0 N o

0.000 8 0.000 3 Non e Non e Non e Deprefsur i n y Ven t F**".-'•-'. • f I n t erni i t ten t 5 4 0.000 ?

Odor , bu t n

o problem
v e p ?5 0 5 0 3 5 1 t o 3 5 0 - 20 0 Non e Indicate d

0.000 ? Hon e Non e Non e Kon e

•Compoaitio ncalculated . "Estimat e baae do nplant-vid e materia l balance . •••Combustio nproduct s from a liquid s Incinerato r als o exist . I nadditio nt o "othe r emissions" . Thes e combustio nproduct s presen t n o emission s inventor y contributio n(th e NO xan dC O ar e s o lov tha t the y

hav e n o s i gi. i f Icanc e a s pollutants) . ••••Compoaitio n& flo v estimate dfro

m materia l balanc e an destimate dpneumati c conveyo r hi ove r capacity . •••••"Compoaltio nbase do nproces s compositio n- flo v estimated" . Note : Fo r non-pollutin g streams , pleas e se e Simplifie dFlo w Diagra m

Figur e LD- 1 (Drawin g R-209 ) an dTabl e IV .

c o o o