Table s A

- F Page 1 

# Attachment A

Table A. SVOC Emission Factors for CL 5036 RO 2

Table B. SVOC Emission Factors for CL 5036 WP 15

Table C. SVOC Emission Factors for CL 5036 RO+R 29

Table D. SVOC Emission Factors for E2300 RO 42

Table E. SVOC Emission Factors for ACT

- HW 55

Table F. SVOC Emission Factors for AFB RO 68Table s A

- F Page 2

Table A . SVOC Em ission Factors for CL 5036 RO

CL 5036 RO

Compound μg/g PM μg/kg (dry) μg/MJ in μg/MJ out

avg sd % sd avg sd % sd avg sd % sd avg sd % sd

PAH

Nap h thalene 11.7 4.0 33.81% 229.7 16.3 7.1% 11.7 0.7 6.23% 57.7 7.9 13.76%

1

- Methylnaphthalene

2

- Methylnaphthalene

2,6

- D i methylnaphthalene

Acenap h thylene 40.2 34.9 86.80% 1284.3 1053.7 82.0% 65.5 53.9 82.32% 354.2 295.0 83.31%

Acenap h thene

Dibenzofuran 4.8 1.9 40.98% 132.7 57.2 43.1% 6.7 2.9 43.03% 37.2 11.8 31.76%

Fluorene 152.3 62.2 40.84% 4334.5 1286.8 29.7% 219.8 63.9 29.07% 1264.5 489.0 38.67%

Methylfluorene 95.5 35.7 37.43% 2760.1 908.0 32.9% 139.9 45.1 32.20% 815.9 374.3 45.88%

Phenanthrene 1962.5 1937.9 98.75% 53394.6 39458.9 73.9% 2711.4 2000.5 73.78% 15653.6 12409.6 79.28%

Anthracene 500.1 489.4 97.84% 13577.6 10006.1 73.7% 689.7 507.8 73.63% 3947.1 3038.3 76.98%Table s A

- F Page 3 CL 5036 RO

Compound μg/g PM μg/kg (dry) μg/MJ in μg/MJ out

avg sd % sd avg sd % sd avg sd % sd avg sd % sd

9

- Methylanthracene 26.0 9.4 36.19% 727.9 234.1 32.2% 36.9 11.7 31.79% 219.3 95.7 43.65%

Fluoranthene 1321.7 1129.9 85.49% 42 294.0 18422.0 43.6% 2153.3 935.1 43.43% 12059.6 6040.0 50.08%

Retene 815.8 877.1 107.51% 24258.8 11109.6 45.8% 1237.9 572.8 46.27% 6683.7 3073.0 45.98%

Pyrene 1203.2 1120.3 93.11% 37251.5 17585.5 47.2% 1897.1 894.2 47.14% 10574.6 5488.4 51.90%

Benzo(ghi )fl u oranthene

Cyclopenta(cd)pyrene

Benz(a)anthracene 323.5 310.9 96.11% 10029.6 4652.1 46.4% 510.8 237.0 46.39% 2857.5 1485.1 51.97%

Chrysene 331.6 349.2 105.31% 10044.4 4342.9 43.2% 512.1 223.3 43.61% 2832.8 1350.0 47.66%

1

- Met hylchrysene 22.8 14.1 61.95% 801.3 301.0 37.6% 40.8 15.3 37.47% 227.7 106.0 46.57%

Benzo(b)fluoranthene 168.7 139.4 82.60% 5659.1 3311.3 58.5% 287.5 166.3 57.85% 1687.9 1268.3 75.14%

Benzo(k)fluoranthene 42.8 42.0 98.24% 1306.2 714.6 54.7% 66.4 36.1 54.3 5% 385.2 262.3 68.10%

Benzo(e)pyrene 64.2 52.4 81.54% 2149.9 1241.5 57.7% 109.2 62.2 56.96% 644.3 497.1 77.15%

Benzo(a)pyrene 113.0 94.5 83.65% 3797.3 2581.4 68.0% 192.8 129.5 67.16% 1150.6 982.8 85.42%Table s A

- F Page 4 CL 5036 RO

Compound μg/g PM μg/kg (dry) μg/MJ in μg/MJ out

avg sd % sd avg sd % sd avg sd % sd avg sd % sd

Perylene 18.2 14.3 78.43% 627.9 400.7 63.8% 31.9 2 0.1 63.04% 188.9 152.9 80.92%

Indeno(1,2,3

- cd)pyrene 107.2 111.1 103.72% 4323.7 4430.5 102.5% 218.9 222.5 101.64% 1356.8 1605.3 118.32%

Dibenzo(a,h)anthracene 28.0 0.00% 419.6 0.0% 21.6 0.00% 121.8 0.00%

Benzo(ghi)perylene 81.0 63.8 78.66% 2955.3 23 53.7 79.6% 149.8 118.2 78.92% 909.2 831.2 91.42%

Coronene 28.0 37.8 134.94% 1130.8 1480.4 130.9% 57.4 74.9 130.63% 330.4 429.3 129.93%

Dibenz(a,e)pyrene

sum

n

- alkanes

n

- Decane

n

- Undecane

n

- Dodecane

n

- Tridecane

n

- Tetradecane 32.0 0.00% 2209.6 0.0% 113.3 0.00% 559.9 0.00%Table s A

- F Page 5 CL 5036 RO

Compound μg/g PM μg/kg (dry) μg/MJ in μg/MJ out

avg sd % sd avg sd % sd avg sd % sd avg sd % sd

n

- Pentadecane

n

- Hexadecane

n

- Heptadecane 19.4 0.00% 522.5 0.0% 26.5 0.00% 112.9 0.00%

n

- Octadecane 13.4 0.00% 3 61.8 0.0% 18.4 0.00% 78.2 0.00%

n

- Nonadecane 25.7 9.9 38.51% 1045.5 618.3 59.1% 53.4 31.9 59.70% 279.8 147.0 52.55%

n

- Eicosane 47.4 16.7 35.25% 2038.9 1486.6 72.9% 104.2 76.5 73.46% 545.1 358.5 65.76%

n

- Heneicosane 75.4 18.5 24.54% 3180.3 1941.9 61.1 % 162.4 100.1 61.61% 858.1 464.5 54.13%

n

- Docosane 101.4 37.3 36.76% 4590.6 3673.9 80.0% 234.7 189.0 80.54% 1226.6 896.3 73.07%

n

- Tricosane 101.8 36.0 35.33% 4635.3 3715.3 80.2% 236.9 191.1 80.67% 1239.8 904.7 72.97%

n

- Tetracosane 60.3 24.2 40.19% 2747. 6 2314.2 84.2% 140.5 119.0 84.73% 732.2 564.8 77.14%

n

- Pentacosane 71.7 30.8 42.98% 3270.0 2800.8 85.7% 167.2 144.0 86.15% 873.9 683.6 78.23%

n

- Hexacosane 25.1 19.2 76.32% 1313.2 1566.7 119.3% 67.2 80.4 119.67% 341.5 390.9 114.49%

n

- Heptacosane 45.7 42. 5 93.05% 2880.9 3172.0 110.1% 147.5 162.9 110.42% 750.2 785.7 104.73%Table s A

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Compound μg/g PM μg/kg (dry) μg/MJ in μg/MJ out

avg sd % sd avg sd % sd avg sd % sd avg sd % sd

n

- Octacosane 75.5 1.9 2.57% 5208.2 133.9 2.6% 267.1 6.9 2.57% 1319.7 33.9 2.57%

n

- Nonacosane 84.6 3.2 3.82% 5839.5 223.2 3.8% 299.5 11.4 3.82% 1479.7 56.6 3.82%

n

- Triacontane 44.8 7.8 17.32% 3093.4 535.7 17.3% 158.7 27.5 17.32% 783.9 135.7 17.32%

n

- Hentricontane 33.4 7.1 21.31% 2304.3 491.0 21.3% 118.2 25.2 21.31% 583.9 124.4 21.31%

n

- Dotriacontane 32.9 0.00% 2272.7 0.0% 116.6 0.00% 575.9 0.00%

n

- Tritriacontane

n

- Te tratriacontane

n

- Pentatriacontane

n

- Hexatriacontane

n

- Heptatriacontane

n

- Octatriacontane

branched and cyclic

alkanesTable s A

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Compound μg/g PM μg/kg (dry) μg/MJ in μg/MJ out

avg sd % sd avg sd % sd avg sd % sd avg sd % sd

Phytane

Dodecylcyclohexane

2

- Methylnonadecane

3

- Methylnonadecane

Pentadecylcyclohexane

Nonadecylcyclohexane

Squalene

Pristane

methoxyphenols

Guaiacol 74.1 27.4 36.95% 3216. 7 2332.4 72.5% 164.4 120.0 73.03% 864.3 571.3 66.10%

2

- Methoxymethylphenol 37.7 9.7 25.60% 921.8 294.5 31.9% 47.1 15.1 31.99% 245.4 99.0 40.36%

Ethylguaiacol 64.3 34.6 53.75% 1930.7 1265.6 65.6% 98.2 64.8 66.01% 559.7 370.2 66.15%Table s A

- F Page 8 CL 5036 RO

Compound μg/g PM μg/kg (dry) μg/MJ in μg/MJ out

avg sd % sd avg sd % sd avg sd % sd avg sd % sd

Eugenol 50.0 18.1 36.2 4% 1399.7 571.3 40.8% 71.1 29.1 40.88% 394.4 127.2 32.26%

Propylguaiacol 45.8 15.8 34.52% 1492.2 327.1 21.9% 75.7 17.3 22.84% 426.1 78.7 18.47%

Vanillin 837.8 378.4 45.16% 30451.4 11605.7 38.1% 1551.4 593.0 38.22% 8471.0 3387.9 39.99%

Iso

- Eugenol 2893.8 1968.1 68.01% 92431.7 54383.0 58.8% 4698.4 2759.8 58.74% 26088.4 15593.6 59.77%

3,5

- Dimethoxyphenol 302.8 0.00% 11807.8 0.0% 598.3 0.00% 3342.8 0.00%

Syringaldehyde 9156.6 3961.4 43.26% 426766.7 325227.8 76.2% 21804.1 16728.6 76.72% 115131.6 80510.1 69.93%

3,5

- Dimethoxy

- 4

-

hydroxyacetophenone 2616.3 974.8 37.26% 115436.8 82894.7 71.8% 5898.0 4265.9 72.33% 31209.1 20445.9 65.51%

4

- Hydroxy

- 3

-

methoxycinnamaldehyde

n

- alkanoic acids

Hexanoic Acid 28.1 21.5 76.61% 1 124.3 920.3 81.9% 57.5 47.3 82.31% 298.4 226.1 75.77%

Caprylic or Octanoic acid 31.4 15.9 50.86% 822.1 288.2 35.1% 41.7 14.5 34.74% 240.5 102.4 42.60%Table s A

- F Page 9 CL 5036 RO

Compound μg/g PM μg/kg (dry) μg/MJ in μg/MJ out

avg sd % sd avg sd % sd avg sd % sd avg sd % sd

est..Nonanoic Acid 83.5 33.5 40.12% 3115.2 913.3 29.3% 158.7 47.3 29.79% 866.1 254.0 29.32%

Capric or Decanoic Acid 46.3 27.3 58.94% 1616.1 609.2 37.7% 82.3 30.9 37.51% 455.7 196.1 43.04%

Dodecanoic Acid 221.3 63.4 28.66% 9654.2 6644.7 68.8% 493.1 342.0 69.36% 2618.8 1607.5 61.38%

Tetradecanoic Acid ME 248.7 67.4 27.11% 10875.4 7555.2 69.5% 555.5 388.9 7 0.00% 2903.2 1819.8 62.68%

est...Pentadecanoic Acid 131.6 45.5 34.58% 5937.9 4705.5 79.2% 303.5 242.1 79.76% 1578.6 1144.9 72.53%

Hexandecanoic Acid 1413.3 382.5 27.07% 61380.0 42074.5 68.5% 3135.6 2166.1 69.08% 16396.4 10113.8 61.68%

est...Heptadecanoi c Acid 87.0 25.1 28.87% 3812.3 2691.5 70.6% 194.8 138.5 71.12% 1018.8 650.6 63.86%

Octadecanoic Acid 281.7 87.6 31.10% 12397.3 9128.5 73.6% 633.5 469.8 74.16% 3313.7 2206.8 66.60%

est...Nonadecanoic Acid 34.6 11.8 33.98% 1486.6 1057.8 71.2% 76.0 54.4 71. 66% 396.1 255.5 64.50%

Eicosanoic Acid 145.2 38.5 26.53% 6210.8 3916.8 63.1% 317.2 201.6 63.56% 1664.2 944.9 56.78%

est..Heneicosananoic

Acid 139.4 43.8 31.43% 5876.2 3626.7 61.7% 300.2 186.6 62.16% 1577.9 883.5 55.99%

Docosanoic Acid 544.9 198.3 36.39% 24991.2 19455.6 77.8% 1277.2 1000.6 78.34% 6687.3 4762.0 71.21%

est...Tricosanoic Acid 229.8 89.4 38.88% 10283.7 7712.3 75.0% 525.7 396.6 75.45% 2736.3 1902.8 69.54%Table s A

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Compound μg/g PM μg/kg (dry) μg/MJ in μg/MJ out

avg sd % sd avg sd % sd avg sd % sd avg sd % sd

Tetracosanoic Acid 1706.9 620.0 36.33% 72132.6 44150.4 61.2% 3683.7 2269.4 61.61% 19580 .4 10895.6 55.65%

est...Pentacosanoic Acid 128.0 63.6 49.68% 5405.1 3565.2 66.0% 276.6 183.0 66.18% 1427.2 939.5 65.83%

est...Hexacosanoic Acid 906.5 688.8 75.98% 37143.5 27800.1 74.8% 1897.3 1426.0 75.16% 10299.1 7429.8 72.14%

est...Heptacosanoic Acid 30.4 0.00% 1062.7 0.0% 54.3 0.00% 301.4 0.00%

Octacosanoic Acid 66.0 24.6 37.21% 2915.0 1370.7 47.0% 149.1 70.3 47.16% 781.3 352.3 45.09%

est...Nonacosanoic Acid

Triacontanoic Acid

di

- alkanoic aci ds #DIV/0! #DIV/0! #DIV/0!

Succinic or Butanedioic

acid 753.4 291.3 38.67% 34214.9 26508.5 77.5% 1746.2 1362.0 78.00% 9452.0 6703.5 70.92%

Glutaric or Pentanedioic

Acid 507.5 148.9 29.34% 21973.0 13636.5 62.1% 1119.8 698.5 62.38% 6220.6 3874.9 6 2.29%Table s A

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Compound μg/g PM μg/kg (dry) μg/MJ in μg/MJ out

avg sd % sd avg sd % sd avg sd % sd avg sd % sd

Adipic or Hexanedioic

Acid 336.3 213.1 63.38% 18714.8 17167.1 91.7% 955.6 882.5 92.35% 5110.3 4277.5 83.70%

Pimelic or Heptanedioic

acid 43.1 13.4 31.11% 1638.0 606.9 37.1% 83.7 31.3 37.36% 429.8 153.3 35.66%

Suberic or Octanedioic

Acid 52.3 18.4 35.10% 2955.8 2016.7 68.2% 151.2 103.8 68.65% 752.2 512.9 68.18%

Azelaic or Nonanedioic

Acid 280.4 260.0 92.72% 15571.5 20262.8 130.1% 797.1 1040.3 130.50% 4034.8 5079.3 125.89%

Sebacic or Decanedioic

Acid 177.7 91.2 51.31% 9866.6 8693.9 88.1% 505.7 446. 3 88.25% 2538.7 2158.5 85.02%

aromatic acids

1,2

- Benzenedicarboxylic

Acid 270.7 105.7 39.07% 11913.4 9244.8 77.6% 608.3 475.5 78.17% 3211.9 2286.2 71.18%

1,4

- Benzenedicarboxylic

Acid 42.6 17.3 40.71% 1805.5 1304.2 72.2% 92.2 67 .1 72.78% 484.7 318.2 65.64%

1,2

- Benzenedicarboxylic 73.0 36.5 49.95% 3453.7 3226.6 93.4% 176.5 165.8 93.99% 921.2 799.6 86.80%Table s A

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Compound μg/g PM μg/kg (dry) μg/MJ in μg/MJ out

avg sd % sd avg sd % sd avg sd % sd avg sd % sd

Acid, 4

- methyl

1,2,3

-

Benzenetricarboxylic

Acid

1,2,4

-

Benzenetricarboxylic

Acid 4.3 0.3 6.16% 171.7 7.5 4.4% 8.7 0.4 5.18% 57.2 10.0 17.55%

1,3,5

-

Benzenetricarboxylic

Acid 2.3 0.00% 92.5 0.0% 4.6 0.00% 35.7 0.00%

1,2,3,4

-

Benzenetetracaroboxylic

Acid

alkenoic acids

Palmitoleic or 9

-

Hexadecenoic Acid 57.0 37.9 66.54% 2482. 0 1451.9 58.5% 126.3 73.8 58.43% 704.7 375.1 53.22%

Linoleic Acid 495.1 209.4 42.30% 18676.9 8010.4 42.9% 952.2 408.8 42.93% 5122.5 2160.5 42.18%Table s A

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Compound μg/g PM μg/kg (dry) μg/MJ in μg/MJ out

avg sd % sd avg sd % sd avg sd % sd avg sd % sd

Oleic Acid 582.6 217.5 37.33% 21836.8 7976.8 36.5% 1113.7 409.1 36.73% 5954.4 1985.9 33.35%

Linolenic Acid 112.6 47.6 42.27% 4158.1 1573.8 37.8% 212.0 80.3 37.90% 1139.7 409.3 35.91%

resin acids

Isopimaric Acid 246.2 309.1 125.53% 6078.1 4435.9 73.0% 309.9 227.2 73.32% 1669.9 1171.5 70.16%

Dehydroabietic Acid 550.8 745.6 135.36% 135 22.4 10277.1 76.0% 690.0 527.0 76.37% 3690.8 2761.2 74.81%

Abietic Acid 347.1 338.1 97.40% 8879.3 4402.3 49.6% 452.4 225.6 49.87% 2432.6 1040.3 42.76%

Pinonic Acid 39.3 1.3 3.29% 2714.6 89.3 3.3% 139.2 4.6 3.29% 687.9 22.6 3.29%

Glycerin 680.4 319.4 46.95% 26129.5 14763.1 56.5% 1334.3 759.5 56.93% 7085.2 3729.2 52.63%

Galactosan 494.3 367.8 74.41% 16735.0 9978.8 59.6% 855.0 511.4 59.81% 4487.9 2790.8 62.19%

Mannosan 323.7 315.1 97.34% 10169.5 8433.5 82.9% 519.8 431.6 83.03% 2735.0 2381.7 87.08%Table s A

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Compound μg/g PM μg/kg (dry) μg/MJ in μg/MJ out

avg sd % sd avg sd % sd avg sd % sd avg sd % sd

Monolein 107.6 36.0 33.50% 2678.9 792.3 29.6% 136.3 39.7 29.09% 714.3 275.9 38.63%

Monosterin

Levoglucosan 31331.1 14823.2 47.31% 1408621.1 1119238.8 79.5% 71948.4 57503.2 79.92% 391209.8 282614.4 72.24%

Cholesterol 189 .9 91.7 48.28% 9477.2 8450.2 89.2% 484.8 433.8 89.47% 2452.2 2135.2 87.07%

Cholestanol

Stigmasterol 40.3 0.00% 1411.8 0.0% 72.2 0.00% 400.5 0.00%Table s A

- F Page 15

Table B . SVOC Emission Factors for CL 5036 WP

CL 5036 WP

Compound μg/g PM μg/kg (dry) μg/ MJ in μg/MJ out

avg sd % sd avg sd % sd avg sd % sd avg sd % sd

PAH

Nap h thalene 25.4 27.9 109.81

% 1423.5 165.7 11.64% 66.0 7.8 11.87% 397.7 58.3 14.65%

1

- Methylnaphthalene 5.5 0.00% 846.2 0.00% 39.3 0.00% 287.6 0.00%

2

- Methylnaphthale ne 19.3 15.4 80.15% 1069.8 317.4 29.67% 49.7 14.7 29.60% 309.1 185.0 59.86%

2,6

-

D i methylnaphthalene

Acenap h thylene 623.3 720.8 115.65

% 86316.5 111799.6 129.52

% 4001.2 5186.2 129.62

% 27466.9 37486.4 136.48

%

Acenap h thene 168.5 77.6 46.04% 2459 9.5 12035.5 48.93% 1140.2 559.1 49.03% 7808.6 4477.6 57.34%

Dibenzofuran 29.6 26.2 88.49% 3904.4 4155.7 106.44

% 180.9 192.6 106.46

% 1213.8 1352.8 111.46

%

Fluorene 651.8 477.4 73.24% 80077.8 82540.7 103.08

% 3711.2 3827.8 103.14

% 24851.0 27468.1 110.53

%

M ethylfluorene 268.4 148.6 55.38% 23743.7 16754.1 70.56% 1100.2 777.1 70.64% 7045.6 5731.5 81.35%Table s A

- F Page 16 CL 5036 WP

Compound μg/g PM μg/kg (dry) μg/ MJ in μg/MJ out

avg sd % sd avg sd % sd avg sd % sd avg sd % sd

Phenanthrene 6740.3 6133.5 91.00% 504060.3 308705.2 61.24% 23360.3 14329.1 61.34% 146043.2 105089.3 71.96%

Anthracene 1606.1 1237.4 77.05% 138737.2 108310.0 78.07% 6430.0 5023.7 78.13% 41334.5 37228.7 90.07%

9

- Methylanthracene 82.3 68.4 83.11% 5956.3 3584.0 60.17% 276.0 166.4 60.28% 1718.7 1243.9 72.38%

Fluoranthene 2440.1 2349.6 96.29% 175592.7 103703.9 59.06% 8137.9 4816.2 59.18% 50628.2 35294.2 69.71%

Re tene 22235.

9 27320.

1 122.86

% 1057584.

8 573854.1 54.26% 48975.2 26747.2 54.61% 275328.7 118348.4 42.98%

Pyrene 1946.1 1672.5 85.94% 155371.4 108285.2 69.69% 7201.5 5026.6 69.80% 45718.9 37531.7 82.09%

Benzo(ghi)fl u oranthene

Cyclopenta(cd)pyre ne

Benz(a)anthracene 713.6 626.7 87.83% 56529.1 37776.8 66.83% 2620.3 1753.9 66.94% 16561.2 12991.0 78.44%

Chrysene 646.4 656.8 101.61

% 46778.0 28601.7 61.14% 2168.2 1328.1 61.26% 13493.8 9602.8 71.16%

1

- Methylchrysene 161.4 182.8 113.26

% 95 47.8 4436.1 46.46% 442.4 206.4 46.66% 2629.3 1222.8 46.51%

Benzo(b)fluoranthene 406.3 267.5 65.84% 31064.8 15666.6 50.43% 1439.0 727.0 50.52% 8926.5 5090.5 57.03%Table s A

- F Page 17 CL 5036 WP

Compound μg/g PM μg/kg (dry) μg/ MJ in μg/MJ out

avg sd % sd avg sd % sd avg sd % sd avg sd % sd

Benzo(k)fluoranthene 91.2 66.2 72.62% 7107.5 3769.9 53.04% 329.3 174.9 53.12% 2069.5 1302.3 62.93%

Benzo(e)pyrene 146.3 94.4 64.50% 11223.2 5603.3 49.93% 519.8 259.9 49.99% 3232.5 1865.6 57.71%

Benzo(a)pyrene 305.2 183.5 60.12% 24495.9 12946.5 52.85% 1134.6 600.2 52.90% 7116.5 4320.8 60.72%

Perylene 51.8 39.9 77.04% 3964.9 2074.4 52.32% 183.7 96.2 52.35% 1144.7 688.9 60.18%

Indeno(1,2,3

- cd)pyrene 257.3 122.9 47.77% 23082.0 18793.7 81.42% 1069.0 872.2 81.59% 6670.4 5483.3 82.20%

Dibenzo(a,h)anthracene 48.0 22.9 47.70% 4009.5 1681.9 41.95% 185.8 77.7 41.79% 1208.2 669.1 55.38%

Benzo(ghi)peryl ene 148.3 52.1 35.14% 13298.4 8859.0 66.62% 616.0 411.2 66.75% 3884.0 2745.5 70.69%

Coronene 78.2 47.2 60.29% 6569.5 4113.7 62.62% 304.4 191.0 62.74% 1925.8 1396.7 72.53%

Dibenz(a,e)pyrene

sum

n

- alkanes

n

- Decane

n

- UndecaneTable s A

- F Page 18 CL 5036 WP

Compound μg/g PM μg/kg (dry) μg/ MJ in μg/MJ out

avg sd % sd avg sd % sd avg sd % sd avg sd % sd

n

- Dodecane

n

- Tridecane

n

- Tetradecane

n

- Pentadecane

n

- Hexadecane 7.1 0.00% 1064.6 0.00% 49.4 0.00% 300.8 0.00%

n

- Heptadecane 18.2 3.9 21.34% 2249.2 846.4 37.63% 104.2 39.2 37.63% 684.7 265.6 38.79%

n

- Octadecane 10.0 1.1 10.73% 1002.2 512.6 51.15% 46.4 23.8 51.39% 299.4 171.2 57.19%

n

- Nonadecane 18.3 4.0 21.88% 1744.0 833.4 47.78% 80.7 38.7 47.98% 516.6 278.8 53.98%

n

- Eicosane 14.9 3.7 24.63% 1396.0 650.8 46.62% 64.6 30.3 46.87% 411.9 215.5 52.32%

n

- Heneicosane 67.7 59.8 88.43% 4133.0 1555.3 37.63% 191.4 72.5 37.86% 1145.2 519.0 45.32%

n

- Docosane 33.5 43.0 128.34

% 1796.0 983.3 54.75% 83.2 45.8 55.06% 484.2 241.6 49.91%

n

- Tricosane 30.6 30.8 100.83

% 1922.4 916.0 47. 65% 89.1 42.7 47.89% 540.4 306.3 56.68%Table s A

- F Page 19 CL 5036 WP

Compound μg/g PM μg/kg (dry) μg/ MJ in μg/MJ out

avg sd % sd avg sd % sd avg sd % sd avg sd % sd

n

- Tetracosane 28.9 39.9 138.04

% 1478.9 954.7 64.56% 68.5 44.4 64.82% 392.6 220.9 56.26%

n

- Pentacosane 35.5 62.0 174.65

% 1578.2 1560.3 98.86% 73.2 72.6 99.16% 409.4 337.8 82.51%

n

- Hexacosane 68.6 0.00% 1921.4 0.0 0% 89.3 0.00% 405.1 0.00%

n

- Heptacosane 68.6 0.00% 1921.4 0.00% 89.3 0.00% 405.1 0.00%

n

- Octacosane

n

- Nonacosane

n

- Triacontane

n

- Hentricontane

n

- Dotriacontane

n

- Tritriacontane

n

- Tetratriacontane

n

- PentatriacontaneTable s A

- F Page 20 CL 5036 WP

Compound μg/g PM μg/kg (dry) μg/ MJ in μg/MJ out

avg sd % sd avg sd % sd avg sd % sd avg sd % sd

n

- Hexatriacontane

n

- Heptatriacontane

n

- Octatriacontane

branched and cyclic

alkanes

Phytane

Dodecylcyclohexa ne 15.2 0.00% 2000.0 0.00% 92.4 0.00% 603.3 0.00%

2

- Methylnonadecane #DIV/0!

3

- Methylnonadecane #DIV/0!

Pentadecylcyclohexane 6.5 0.00% 975.9 0.00% 45.3 0.00% 275.7 0.00%

Nonadecylcyclohexane

Squalene

PristaneTable s A

- F Page 21 CL 5036 WP

Compound μg/g PM μg/kg (dry) μg/ MJ in μg/MJ out

avg sd % sd avg sd % sd avg sd % sd avg sd % sd

methoxy phenols

Guaiacol 126.9 172.3 135.82

% 6692.3 4086.7 61.07% 310.2 190.3 61.36% 1814.4 1024.1 56.45%

2

- Methoxymethylphenol 75.3 101.8 135.26

% 3661.3 2452.2 66.98% 169.8 114.1 67.18% 986.1 612.8 62 .14%

Ethylguaiacol 113.5 65.3 57.50% 16584.1 10113.2 60.98% 768.7 469.7 61.10% 5302.5 3641.2 68.67%

Eugenol 131.2 84.5 64.36% 18541.2 13187.5 71.13% 859.2 611.5 71.17% 5817.8 4446.3 76.43%

Propylguaiacol 126.2 82.2 65.13% 17878.1 12354.9 69.11% 828.4 57 2.5 69.11% 5581.4 4080.2 73.10%

Vanillin 1317.0 755.3 57.35% 99408.7 49827.5 50.12% 4604.9 2315.8 50.29% 28518.5 16837.9 59.04%

Iso

- Eugenol 7052.0 4579.8 64.94% 853851.1 804633.8 94.24% 39563.7 37291.6 94.26% 261542.5 259545.1 99.24%

3,5

- Dimethoxyphenol

Syringaldehyde 1338.1 689.4 51.52% 123728.6 115973.1 93.73% 5729.0 5386.5 94.02% 34749.7 33328.9 95.91%

3,5

- Dimethoxy

- 4

-

hydroxyacetophenone 154.4 0.00% 3550.6 0.00% 162.7 0.00% 664.6 0.00%Table s A

- F Page 22 CL 5036 WP

Compound μg/g PM μg/kg (dry) μg/ MJ in μg/MJ out

avg sd % sd avg sd % sd avg sd % sd avg sd % sd

4

- Hydroxy

- 3

-

methoxycinnamaldehyd

e 2112.4 0.00% 318973.5 0.00% 14802.0 0.00% 90115.6 0.00%

n

- alkanoic acids

Hexanoic Acid 14.4 4.9 34.39% 943.8 508.9 53.92% 43.6 23.7 54.28% 256.9 164.9 64.17%

Caprylic or Octanoic

acid 192.5 166.1 86.26% 17215.3 13828.6 80.33% 798.2 641. 7 80.40% 5010.2 4225.2 84.33%

est..Nonanoic Acid 271.7 294.2 108.29

% 17967.7 9880.5 54.99% 832.8 459.4 55.16% 5006.8 2831.1 56.55%

Capric or Decanoic Acid 143.1 156.0 109.03

% 8981.8 4492.4 50.02% 416.2 208.9 50.19% 2497.3 1333.6 53.40%

Dodecanoic Acid 1 44.8 186.4 128.80

% 8682.8 5196.0 59.84% 402.4 241.4 60.00% 2406.3 1465.5 60.90%

Tetradecanoic Acid ME 264.9 280.4 105.86

% 16935.0 8342.9 49.26% 784.8 388.1 49.46% 4733.8 2566.7 54.22%

est...Pentadecanoic 155.1 123.2 79.43% 10890.0 5215.6 47.89% 504. 5 242.5 48.06% 3095.5 1767.6 57.10%Table s A

- F Page 23 CL 5036 WP

Compound μg/g PM μg/kg (dry) μg/ MJ in μg/MJ out

avg sd % sd avg sd % sd avg sd % sd avg sd % sd

Acid

Hexandecanoic Acid 4063.4 2679.6 65.95% 299800.0 147929.9 49.34% 13888.4 6874.2 49.50% 86127.7 51863.4 60.22%

est...Heptadecanoic

Acid 142.3 97.1 68.28% 10616.8 5571.6 52.48% 491.9 258.8 52.62% 3054.6 1930.7 63.21%

Oc tadecanoic Acid 1301.7 874.5 67.18% 97174.1 50317.1 51.78% 4501.8 2337.3 51.92% 28010.5 17647.7 63.00%

est...Nonadecanoic Acid 51.2 5.8 11.33% 5383.6 3183.9 59.14% 249.3 147.9 59.35% 1625.4 1085.4 66.77%

Eicosanoic Acid 478.3 270.3 56.51% 36289.2 18550.2 51.12% 1680.8 861.0 51.22% 10488.3 6555.0 62.50%

est..Heneicosananoic

Acid 52.0 23.5 45.13% 4267.6 3053.6 71.55% 197.7 141.7 71.70% 1217.8 922.2 75.72%

Docosanoic Acid 412.0 171.7 41.69% 35868.5 26924.6 75.06% 1662.0 1250.3 75.23% 10384.3 8334.4 80.26%

est...Tricosanoic Acid 75.2 64.5 85.83% 5648.9 3840.8 67.99% 261.8 178.4 68.13% 1600.5 1168.4 73.00%

Tetracosanoic Acid 470.4 139.3 29.62% 44835.8 36759.7 81.99% 2077.6 1707.4 82.18% 13153.1 11272.6 85.70%

est...Pentacosanoic

Acid 20.9 0.00% 3149.4 0. 00% 146.1 0.00% 889.8 0.00%

est...Hexacosanoic Acid 78.1 51.0 65.30% 9340.8 9465.0 101.33 433.0 439.7 101.53 2792.2 2784.3 99.72%Table s A

- F Page 24 CL 5036 WP

Compound μg/g PM μg/kg (dry) μg/ MJ in μg/MJ out

avg sd % sd avg sd % sd avg sd % sd avg sd % sd

% %

est...Heptacosanoic

Acid

Octacosanoic Acid

est...Nonacosanoic Acid

Triacontanoic Acid

di

- alkanoic acids

Succinic or Butanedioic

acid 581.2 613.7 105.60

% 37049.6 21373.3 57.69% 1717.2 994.6 57.92% 10228.0 6110.1 59.74%

Glutaric or Pentanedioic

Acid 501.1 436.0 87.01% 34576.7 19232.1 55.62% 1602.2 894.4 55.82% 9684.5 5797.2 59.86%

Adipic or Hexanedioic

Acid 291.0 183.1 62.92% 21376.4 11718.4 54.82% 988.8 543.2 54.93% 6323.6 4157.9 65.75%Table s A

- F Page 25 CL 5036 WP

Compound μg/g PM μg/kg (dry) μg/ MJ in μg/MJ out

avg sd % sd avg sd % sd avg sd % sd avg sd % sd

Pimelic or Heptanedioic

acid 52.4 23.5 44.91% 6194.6 4548.1 73.42% 286.8 210.6 73.43% 1866.2 139 2.5 74.62%

Suberic or Octanedioic

Acid 213.4 332.8 155.91

% 12222.4 10222.1 83.63% 566.8 474.9 83.78% 3405.1 2899.6 85.15%

Azelaic or Nonanedioic

Acid 659.9 630.7 95.57% 52187.9 38016.5 72.85% 2418.8 1762.5 72.87% 15280.6 12732.0 83.32%

Sebacic or Decane dioic

Acid 186.7 289.4 155.00

% 9498.9 7123.4 74.99% 440.4 331.4 75.25% 2542.6 1654.3 65.06%

aromatic acids

1,2

-

Benzenedicarboxylic

Acid 329.9 464.0 140.64

% 15055.9 10417.5 69.19% 697.6 485.4 69.58% 3867.9 2068.7 53.48%

1,4

-

Benz enedicarboxylic

Acid 60.8 91.4 150.29

% 2082.4 2337.9 112.27

% 96.6 108.8 112.62

% 477.2 479.0 100.38

%

1,2

-

Benzenedicarboxylic 86.0 149.3 173.67

% 3495.6 3680.0 105.27

% 162.1 171.2 105.65

% 867.7 731.9 84.35%Table s A

- F Page 26 CL 5036 WP

Compound μg/g PM μg/kg (dry) μg/ MJ in μg/MJ out

avg sd % sd avg sd % sd avg sd % sd avg sd % sd

Acid, 4

- methyl

1,2,3

-

Benzenetricarboxylic

Acid

1,2,4

-

Benzenetricarboxylic

Acid 25.4 0.00% 26.8 0.00% 109.5 0.00%

1,3,5

-

Benzenetricarboxylic

Acid

1,2,3,4

-

Benzenetetracaroboxyli

c Acid

alkenoic acids

Palmitoleic or 9

-

Hexadecenoic Acid 37.9 5.0 13.29% 163.2 179.7 110.09

% 957.3 1145.0 119.60

%

Linoleic Acid 4929.7 1797.4 36.46% 457414.5 321930.6 70.38% 21192.2 14936.3 70.48% 136257.7 109243.2 80.17%Table s A

- F Page 27 CL 5036 WP

Compound μg/g PM μg/kg (dry) μg/ MJ in μg/MJ out

avg sd % sd avg sd % sd avg sd % sd avg sd % sd

Oleic Acid 5377.4 2829.4 52.62% 434854.5 251283.4 57.79% 20145.7 11665.8 57.91% 12677 3.2 86822.0 68.49%

Linolenic Acid 1232.7 590.2 47.88% 109486.9 81792.3 74.71% 5073.7 3797.9 74.85% 31798.9 25129.9 79.03%

resin acids

Isopimaric Acid 22295.

0 13159.

4 59.02% 1831768.

2 1119775.

0 61.13% 84860.2 51920.7 61.18% 5332 24.0 373010.2 69.95%

Dehydroabietic Acid 41878.

7 53972.

5 128.88

% 2297095.

2 1305480.

2 56.83% 106430.

7 60709.3 57.04% 622549.1 325413.2 52.27%

Abietic Acid 59073.

7 24541.

2 41.54% 6214451.

2 5157989.

0 83.00% 287923.

7 239075.

8 83.03% 1865679.

2 1661463.

9 89.05 %

Pinonic Acid

Glycerin 1005.0 1549.8 154.21

% 53129.3 39532.4 74.41% 2463.9 1839.6 74.66% 14128.0 8971.5 63.50%Table s A

- F Page 28 CL 5036 WP

Compound μg/g PM μg/kg (dry) μg/ MJ in μg/MJ out

avg sd % sd avg sd % sd avg sd % sd avg sd % sd

Galactosan 1960.1 3987.8 203.45

% 70761.9 104482.3 147.65

% 3284.0 4858.5 147.95

% 16995.8 21385.7 125.8 3

%

Mannosan 847.1 818.0 96.56% 54775.4 29528.8 53.91% 2538.1 1373.6 54.12% 15153.3 8711.1 57.49%

Monolein 149.2 66.4 44.52% 11396.8 7219.5 63.35% 527.4 334.0 63.33% 3330.6 2470.8 74.19%

Monosterin

Levoglucosan 13831.

7 3730.5 26.97% 1194004.

7 764403.3 64.02% 55279.9 35509.5 64.24% 347756.4 243253.0 69.95%

Cholesterol 210.2 254.4 121.00

% 10622.3 4320.2 40.67% 492.5 200.4 40.69% 2852.2 838.7 29.40%

Cholestanol

StigmasterolTable s A

- F Page 29

Table C . SVOC Emission Factors for CL 5036 RO+R

CL 5036 RO+R

Compound μg/g PM μg/kg (dry) μg/MJ in μg/MJ out

avg sd % sd avg sd % sd avg sd % sd avg sd % sd

PAH

Nap h thalene 7.1 3.1 43.71% 241.7 272.8 112.87% 12.3 14.0 113.99% 105.7 136.4 129.00%

1

- Methylnaphthalene

2

- Methylnaphthalene

2,6

- D i methylnaphthalene

Acenap h thylene 48.5 83.9 173.14% 2881.6 5471.6 189.88% 147.1 278.9 189.66% 1430.0 2836.3 198.35%

Acenap h thene 17.5 0.00% 1119.9 0.00% 57.1 0.00% 575.6 0.00%

Dibenzofuran 4.6 5.9 128. 47% 270.5 391.9 144.86% 13.8 20.0 144.56% 130.0 205.9 158.40%

Fluorene 225.0 212.3 94.35% 12969.5 14085.1 108.60% 662.8 717.7 108.28% 6176.9 7437.3 120.41%

Methylfluorene 78.4 55.2 70.43% 4236.7 3586.7 84.66% 216.8 183.0 84.43% 1925.1 1852.8 96.24%

Phen anthrene 1953.4 1458.4 74.66% 98974.4 92770.5 93.73% 5062.4 4736.0 93.55% 44748.4 47806.6 106.83%

Anthracene 614.2 533.0 86.79% 31861.1 32500.8 102.01% 1629.2 1658.4 101.80% 14682.5 16713.2 113.83%Table s A

- F Page 30 CL 5036 RO+R

Compound μg/g PM μg/kg (dry) μg/MJ in μg/MJ out

avg sd % sd avg sd % sd avg sd % sd avg sd % sd

9

- Methylanthracene 27.9 12.5 44.82% 1451.9 847.3 58.35% 74.3 43.1 58.00% 661.4 466.9 70.60%

Fluoranthene 1258.6 796.7 63.30% 60671.9 52984.7 87.33% 3103.5 2704.6 87.15% 27051.0 27771.9 102.66%

Retene 803.9 189.0 23.51% 29303.3 15500.2 52.90% 1497.1 794.4 53.06% 11882.0 9628.9 81.04%

Pyrene 1287.2 927.0 72.02 % 63734.0 58839.6 92.32% 3259.9 3003.1 92.12% 28784.5 30523.9 106.04%

Benzo(ghi)fl u oranthene

Cyclopenta(cd)pyrene

Benz(a)anthracene 331.3 221.5 66.86% 16304.8 14588.1 89.47% 834.1 744.6 89.27% 7296.0 7599.6 104.16%

Chrysene 273. 3 167.3 61.23% 13121.0 11475.4 87.46% 671.2 585.7 87.27% 5836.2 6045.8 103.59%

1

- Methylchrysene 30.1 17.3 57.56% 1476.7 1352.4 91.58% 75.6 69.1 91.47% 642.1 688.4 107.21%

Benzo(b)fluoranthene 189.3 137.5 72.65% 9179.3 9762.5 106.35% 469.6 497.9 106.01% 4 100.1 5171.2 126.13%

Benzo(k)fluoranthene 51.6 48.2 93.44% 2652.9 3284.9 123.82% 135.6 167.5 123.47% 1224.1 1726.2 141.01%

Benzo(e)pyrene 76.7 59.1 77.04% 3725.4 4177.7 112.14% 190.6 213.0 111.78% 1680.7 2216.2 131.86%

Benzo(a)pyrene 158.7 140.5 88.52% 8000.5 9655.6 120.69% 409.1 492.3 120.32% 3661.2 5087.1 138.95%Table s A

- F Page 31 CL 5036 RO+R

Compound μg/g PM μg/kg (dry) μg/MJ in μg/MJ out

avg sd % sd avg sd % sd avg sd % sd avg sd % sd

Perylene 28.8 26.5 92.05% 1460.4 1806.1 123.67% 74.7 92.1 123.31% 675.9 952.0 140.85%

Indeno(1,2,3

- cd)pyrene 132.3 89.3 67.47% 6302.7 6325.1 100.36% 323.0 323.3 100.10% 2677.1 3203.4 119.66%

Dibenzo(a,h)anthracene 24.0 14.6 60.90% 1358.2 1086.9 80.02% 69.3 55.4 79.84% 674.3 579.2 85.89%

Benzo(ghi)perylene 101.4 80.7 79.56% 4954.0 5569.1 112.41% 253.5 283.8 111.97% 2229.6 2960.1 132.76%

Coronene 81.4 46.1 56.68% 4139.5 3039.0 73.41% 211.9 1 55.1 73.18% 1849.1 1593.9 86.20%

Dibenz(a,e)pyrene

sum

n

- alkanes

n

- Decane

n

- Undecane

n

- Dodecane

n

- Tridecane 56.4 32.7 58.06% 1213.6 870.3 71.72% 62.0 43.6 70.33% 247.1 171.1 69. 24%

n

- Tetradecane 25.5 13.3 52.21% 839.2 702.6 83.72% 42.9 35.9 83.67% 308.5 373.7 121.15%Table s A

- F Page 32 CL 5036 RO+R

Compound μg/g PM μg/kg (dry) μg/MJ in μg/MJ out

avg sd % sd avg sd % sd avg sd % sd avg sd % sd

n

- Pentadecane

n

- Hexadecane 29.0 0.00% 667.7 0.00% 33.9 0.00% 134.4 0.00%

n

- Heptadecane 35.9 30.3 84.41% 2048.9 2529.5 123.46% 105.7 130.3 123.29% 695.7 906.3 130.27%

n

- Octadecane 52.0 51.8 99.51% 2148.2 2294.5 106.81% 110.6 118.4 107.08% 772.0 818.1 105.97%

n

- Nonadecane 99.5 119.8 120.39% 3501.5 3443.7 98.35% 180.3 178.3 98.88% 1203.2 1162.4 96.61%

n

- Eicosane 115.5 128.5 111.26% 4030.3 3405.9 84 .51% 207.4 176.5 85.10% 1418.2 1200.1 84.62%

n

- Heneicosane 135.2 120.2 88.94% 4975.6 3895.6 78.29% 255.8 201.7 78.84% 1797.6 1439.6 80.08%

n

- Docosane 142.4 130.7 91.76% 5146.1 3800.2 73.85% 264.5 196.8 74.41% 1857.3 1425.3 76.74%

n

- Tricosane 160.6 136.9 85.29% 5938.9 4468.8 75.24% 305.2 231.2 75.76% 2154.2 1707.0 79.24%

n

- Tetracosane 132.6 132.8 100.14% 4947.3 4496.1 90.88% 254.5 232.6 91.38% 1764.7 1591.7 90.19%

n

- Pentacosane 128.4 132.7 103.34% 4839.0 4749.5 98.15% 249.0 245.6 98.63% 1713.3 1640.7 95 .76%

n

- Hexacosane 105.4 122.1 115.80% 4021.1 4785.2 119.00% 207.3 247.3 119.26% 1352.9 1617.9 119.59%

n

- Heptacosane 155.7 157.7 101.32% 5656.2 5644.1 99.78% 292.0 291.6 99.86% 1811.7 1947.8 107.51%Table s A

- F Page 33 CL 5036 RO+R

Compound μg/g PM μg/kg (dry) μg/MJ in μg/MJ out

avg sd % sd avg sd % sd avg sd % sd avg sd % sd

n

- Octacosane 120.9 114.8 94.94% 4892.7 5542.3 113.28% 2 52.5 286.0 113.27% 1619.4 1944.3 120.06%

n

- Nonacosane 145.6 145.0 99.54% 6308.0 8389.7 133.00% 325.6 432.7 132.90% 2080.7 2953.4 141.94%

n

- Triacontane 191.9 196.2 102.26% 7593.3 9217.8 121.39% 392.1 475.6 121.29% 2448.9 3226.4 131.75%

n

- Hentricontane 30 8.1 236.8 76.86% 11596.4 7742.3 66.76% 598.7 399.9 66.79% 3854.0 2718.2 70.53%

n

- Dotriacontane 403.4 426.0 105.60% 12742.2 9063.1 71.13% 659.2 469.5 71.22% 3860.5 2855.0 73.95%

n

- Tritriacontane 554.5 644.4 116.21% 16175.1 11127.2 68.79% 837.4 578.6 69.09 % 4761.5 2997.4 62.95%

n

- Tetratriacontane 807.1 606.8 75.18% 23788.7 2176.4 9.15% 1232.3 104.1 8.45% 6756.3 2920.7 43.23%

n

- Pentatriacontane 705.9 524.5 74.30% 20915.9 2168.8 10.37% 1083.5 104.8 9.67% 5952.8 2639.4 44.34%

n

- Hexatriacontane 700.3 549.6 7 8.48% 20242.0 905.8 4.47% 1048.8 39.6 3.77% 5703.0 2220.8 38.94%

n

- Heptatriacontane 1114.3 0.00% 20058.2 0.00% 1044.6 0.00% 4229.0 0.00%

n

- Octatriacontane

branched and cyclic

alkanesTable s A

- F Page 34 CL 5036 RO+R

Compound μg/g PM μg/kg (dry) μg/MJ in μg/MJ out

avg sd % sd avg sd % sd avg sd % sd avg sd % sd

Phytane

Dodecy lcyclohexane 23.9 0.00% 1599.0 0.00% 82.4 0.00% 556.9 0.00%

2

- Methylnonadecane

3

- Methylnonadecane

Pentadecylcyclohexane 74.8 0.00% 3515.9 0.00% 179.8 0.00% 1635.4 0.00%

Nonadecylcyclohexane

Squalene

Pristane

methoxyphenols

Guaiacol 86.4 27.3 31.66% 3544.4 2072.1 58.46% 181.3 106.2 58.59% 1439.3 1125.8 78.22%

2

- Methoxymethylphenol 20.2 12.2 60.76% 1025.7 1157.9 112.89% 52.4 58.9 112.34% 495.8 639.5 128.98%

Ethylguaiacol 65.0 49.6 76.24% 3877.7 3406.2 87.84% 198.3 173.4 87.46% 1821.6 1838.1 100.90%Table s A

- F Page 35 CL 5036 RO+R

Compound μg/g PM μg/kg (dry) μg/MJ in μg/MJ out

avg sd % sd avg sd % sd avg sd % sd avg sd % sd

Eugenol 72.6 55.5 76.37% 4698.5 3478.9 74.04% 240.2 176.5 73.47% 2229.4 2050.2 91.96%

Propylguaiacol 56.3 37.8 67.10% 3648.3 2355.5 64.56% 186.6 119.3 63.94% 17 10.8 1442.9 84.34%

Vanillin 996.8 397.9 39.92% 43350.8 30854.3 71.17% 2218.5 1585.2 71.45% 17335.7 14736.0 85.00%

Iso

- Eugenol 3456.2 3144.6 90.99% 192590.0 203531.9 105.68% 9857.1 10403.1 105.54% 86944.4 100263.7 115.32%

3,5

- Dimethoxyphenol

Syringaldehyde 6070.0 2971.5 48.95% 233381.6 133269.6 57.10% 11943.9 6834.9 57.22% 88541.6 65692.7 74.19%

3,5

- Dimethoxy

- 4

-

hydroxyacetophenone 1313.4 472.5 35.98% 50496.8 25539.3 50.58% 2583.2 1308.2 50.64% 19721.4 14299.9 72.51%

4

- Hydroxy

- 3

-

methoxycinna maldehyde 491.1 249.1 50.73% 27366.2 21257.6 77.68% 1399.5 1084.0 77.46% 11913.4 12360.1 103.75%

n

- alkanoic acids

Hexanoic Acid 22.3 11.6 51.83% 966.8 581.6 60.16% 49.5 29.7 60.05% 408.4 317.8 77.81%

Caprylic or Octanoic acid 4 1.3 37.2 90.18% 2234.4 2604.4 116.56% 114.3 133.0 116.41% 1006.4 1319.1 131.07%Table s A

- F Page 36 CL 5036 RO+R

Compound μg/g PM μg/kg (dry) μg/MJ in μg/MJ out

avg sd % sd avg sd % sd avg sd % sd avg sd % sd

est..Nonanoic Acid 114.4 68.3 59.72% 6231.7 5258.1 84.38% 319.3 269.8 84.48% 2643.0 2451.4 92.75%

Capric or Decanoic Acid 66.3 29.7 44.77% 3141.1 2489.7 79.26% 160.8 127.5 7 9.31% 1344.2 1254.4 93.32%

Dodecanoic Acid 202.7 126.4 62.34% 8776.6 7182.3 81.83% 449.2 367.9 81.89% 3650.9 3535.9 96.85%

Tetradecanoic Acid ME 219.2 80.7 36.85% 9849.6 7810.3 79.30% 504.6 402.6 79.79% 3925.7 3299.0 84.04%

est...Pentadecanoic Acid 101. 6 27.4 26.91% 4307.2 2734.1 63.48% 220.5 140.6 63.76% 1724.7 1339.0 77.64%

Hexandecanoic Acid 2452.5 1613.6 65.79% 116579.7 128729.1 110.42% 5979.9 6643.9 111.10% 44844.6 47119.1 105.07%

est...Heptadecanoic Acid 105.6 34.7 32.89% 4665.8 3210.8 68.82% 238 .9 165.0 69.05% 1890.5 1540.9 81.51%

Octadecanoic Acid 595.9 482.2 80.91% 29178.4 36281.2 124.34% 1497.7 1872.1 125.00% 11073.8 13027.3 117.64%

est...Nonadecanoic Acid 53.1 8.4 15.78% 2352.2 1054.8 44.84% 120.5 53.9 44.78% 966.9 622.7 64.41%

Eicosanoic Acid 224.6 88.7 39.49% 10194.5 7074.6 69.40% 522.0 362.9 69.52% 4211.9 3484.4 82.73%

est..Heneicosananoic

Acid 132.2 54.4 41.12% 5895.7 4268.5 72.40% 301.7 218.5 72.40% 2430.5 2222.5 91.44%

Docosanoic Acid 623.4 281.1 45.10% 27708.6 19442.2 70.17% 1418.1 997.7 70.36% 11213.2 9432.4 84.12%

est...Tricosanoic Acid 193.1 79.9 41.40% 8493.6 5877.7 69.20% 434.5 300.8 69.22% 3494.9 3086.1 88.30%Table s A

- F Page 37 CL 5036 RO+R

Compound μg/g PM μg/kg (dry) μg/MJ in μg/MJ out

avg sd % sd avg sd % sd avg sd % sd avg sd % sd

Tetracosanoic Acid 2400.5 1037.5 43.22% 109050.9 77867.2 71.40% 5582.8 3994.8 71.56% 44632.3 37914.5 84.95%

est...P entacosanoic Acid 109.5 9.1 8.28% 4955.9 2547.4 51.40% 253.9 130.5 51.40% 2031.4 1393.7 68.61%

est...Hexacosanoic Acid 808.7 318.0 39.33% 36568.6 25273.8 69.11% 1872.8 1297.1 69.26% 15095.6 12286.2 81.39%

est...Heptacosanoic Acid 26.4 0.00% 474.9 0.00% 24.7 0.00% 100.1 0.00%

Octacosanoic Acid 46.4 19.3 41.63% 2040.9 1688.2 82.72% 104.8 87.2 83.18% 744.1 632.8 85.05%

est...Nonacosanoic Acid

Triacontanoic Acid

di

- alkanoic acids

Succini c or Butanedioic

acid 791.9 201.5 25.44% 33896.2 22154.9 65.36% 1735.5 1139.4 65.65% 13653.0 10762.0 78.83%

Glutaric or Pentanedioic

Acid 539.1 166.6 30.90% 22809.0 14275.9 62.59% 1167.5 734.0 62.87% 9146.7 6974.2 76.25%Table s A

- F Page 38 CL 5036 RO+R

Compound μg/g PM μg/kg (dry) μg/MJ in μg/MJ out

avg sd % sd avg sd % sd avg sd % sd avg sd % sd

Adipic or Hexanedioic

Acid 439.1 62.7 14.28% 15808.6 11648.1 73.68% 813.1 601.1 73.92% 4623.4 4756.5 102.88%

Pimelic or Heptanedioic

acid 55.4 18.8 33.88% 2398.9 1503.1 62.66% 123.0 77.1 62.66% 947.0 750.0 79.20%

Suberic or Octanedioic

Acid 90.7 43.0 47.43% 3767.0 3183.1 84.50% 193.0 16 3.6 84.77% 1474.6 1465.0 99.35%

Azelaic or Nonanedioic

Acid 575.1 289.7 50.38% 25653.5 19467.4 75.89% 1313.8 1001.9 76.26% 10194.1 8470.2 83.09%

Sebacic or Decanedioic

Acid 179.5 97.4 54.30% 7781.9 4081.2 52.44% 398.2 209.0 52.49% 3137.4 2105.8 67.12%

aromatic acids

1,2

- Benzenedicarboxylic

Acid 153.0 71.4 46.66% 5294.2 3533.4 66.74% 271.0 182.2 67.26% 1809.7 1392.5 76.95%

1,4

- Benzenedicarboxylic

Acid 1710.7 3513.7 205.40% 41632.8 59721.8 143.45% 2153.3 3114.8 144.65% 12287.3 1 2228.8 99.52%

1,2

- Benzenedicarboxylic 39.8 28.0 70.28% 1390.8 756.0 54.36% 71.1 38.6 54.37% 505.2 307.3 60.82%Table s A

- F Page 39 CL 5036 RO+R

Compound μg/g PM μg/kg (dry) μg/MJ in μg/MJ out

avg sd % sd avg sd % sd avg sd % sd avg sd % sd

Acid, 4

- methyl

1,2,3

-

Benzenetricarboxylic

Acid

1,2,4

-

Benzenetricarboxylic

Acid 8.5 0.00% 85.4 0.00% 4.2 0.00% 16.2 0.00%

1, 3,5

-

Benzenetricarboxylic

Acid

1,2,3,4

-

Benzenetetracaroboxylic

Acid

alkenoic acids

Palmitoleic or 9

-

Hexadecenoic Acid 27.1 0.00% 1734.7 0.00% 88.5 0.00% 891.6 0.00%

Linoleic Acid 1098.5 412.3 37.53% 48433.6 33220.8 68.59% 2478.8 1702.4 68.68% 19813.9 16995.2 85.77%Table s A

- F Page 40 CL 5036 RO+R

Compound μg/g PM μg/kg (dry) μg/MJ in μg/MJ out

avg sd % sd avg sd % sd avg sd % sd avg sd % sd

Oleic Acid 913.9 389.3 42.60% 42830.1 33715.8 78.72% 2193.7 1730.4 78.88% 17677.1 16003.2 90.53%

Linolenic Acid 203.5 85.7 42.10% 9509.0 7275.5 76.51% 486.8 373.2 76.65% 3955.6 3545.1 89. 62%

resin acids

Isopimaric Acid 459.9 472.6 102.77% 24101.2 30112.6 124.94% 1231.2 1535.7 124.73% 11414.4 15631.1 136.94%

Dehydroabietic Acid 1024.3 597.0 58.28% 50781.8 42699.5 84.08% 2598.5 2187.3 84.18% 22104.2 20921.1 94.65 %

Abietic Acid 1222.2 1143.4 93.55% 67811.2 73654.6 108.62% 3469.4 3761.5 108.42% 30913.4 37067.4 119.91%

Pinonic Acid

Glycerin 644.1 236.8 36.77% 27841.9 19387.2 69.63% 1423.8 998.2 70.11% 11382.2 9199.3 80.82%

Galactosan 806.9 424.7 52.63% 30081.7 18549.3 61.66% 1534.3 952.7 62.10% 12415.6 10407.1 83.82%

Mannosan 911.7 636.2 69.79% 41608.3 35705.0 85.81% 2127.6 1830.8 86.05% 18022.0 17174.1 95.30%Table s A

- F Page 41 CL 5036 RO+R

Compound μg/g PM μg/kg (dry) μg/MJ in μg/MJ out

avg sd % sd avg sd % sd avg sd % sd avg sd % sd

Monolein 261.8 190.9 72.93% 12508.3 10894.4 87.10% 639.8 557.6 87.15% 5411.3 5395.6 99.71%

Monosterin 237.7 0.00% 15925.7 0.00% 821.2 0.00% 5546.9 0.00%

Levoglucosan 29768.6 9828.7 33.02% 1142391.0 800902.7 70.11% 58465.9 41424.5 70.85% 427206.7 326500.6 76.43%

Cholesterol 121.1 91.2 75.26% 4916.5 2718.9 55.30% 251.7 140.8 55.94% 1589.1 921.5 57.99%

Cholestanol

Stigmasterol 28.1 0.00% 1800.6 0.00% 91.8 0.00% 925.4 0.00%Table s A

- F Page 42

Table D . SVOC Emission Factors for E2300 RO

E2300 RO

Compound μg/g PM μg/kg (dry) μg/MJ in μg/MJ out

avg sd % sd avg sd % sd avg sd % sd avg sd % sd

PAH

Nap h thalene 11.5 2.9 25.08% 116.7 83.1 71.25% 6.1 4.2 70.03% 28.9 23.1 79.73%

1

- Methylnaphthalene

2

- Methylnaphthalene

2,6

- D i methylnaphthalene

Acenap h thylene 12.6 5.0 40.0 7% 239.7 153.8 64.15% 12.2 7.7 62.66% 68.8 53.4 77.67%

Acenap h thene

Dibenzofuran 1.9 0.9 44.79% 43.5 21.9 50.49% 2.2 1.1 48.77% 12.8 8.6 67.04%

Fluorene 135.1 0.00% 3106.4 0.00% 156.7 0.00% 994.7 0.00%

Methylfluorene 38.6 33.4 86.58% 79 9.8 831.6 103.96% 40.7 41.8 102.66% 234.8 272.9 116.25%

Phenanthrene 1166.8 857.9 73.53% 20146.9 20360.2 101.06% 1027.8 1035.3 100.73% 5625.0 6276.2 111.58%

Anthracene 267.7 214.6 80.17% 4762.5 5185.7 108.88% 243.1 264.0 108.59% 1329.8 1573.2 118.31%Table s A

- F Page 43 E2300 RO

Compound μg/g PM μg/kg (dry) μg/MJ in μg/MJ out

avg sd % sd avg sd % sd avg sd % sd avg sd % sd

9

- Methylanthracene 18.5 3.8 20.58% 326.0 166.1 50.95% 16.6 8.5 51.39% 90.0 53.0 58.87%

Fluoranthene 1133.6 365.5 32.25% 15586.4 11233.0 72.07% 796.5 573.3 71.98% 4193.3 3422.3 81.61%

Retene 41.2 6.4 15.56% 397.1 231.8 58.39% 20.5 12.0 58.57% 99.1 74.6 75.2 3%

Pyrene 913.3 290.1 31.76% 12625.9 9713.4 76.93% 645.3 495.7 76.82% 3397.0 2957.1 87.05%

Benzo(ghi)fl u oranthene

Cyclopenta(cd)pyrene

Benz(a)anthracene 268.0 60.1 22.42% 3536.2 2658.8 75.19% 181.0 135.7 74.96% 946.0 801.8 84.75 %

Chrysene 298.0 69.5 23.33% 3664.1 2435.9 66.48% 187.9 124.9 66.48% 964.0 712.8 73.94%

1

- Methylchrysene 37.9 16.1 42.40% 445.3 289.0 64.90% 22.8 14.9 65.09% 115.7 84.6 73.14%

Benzo(b)fluoranthene 149.7 50.5 33.72% 1895.3 1612.1 85.06% 96.7 81.4 84.12% 513.7 512.8 99.83%

Benzo(k)fluoranthene 36.1 8.4 23.29% 460.8 372.2 80.77% 23.6 19.1 80.74% 121.8 104.8 86.03%

Benzo(e)pyrene 54.2 18.2 33.57% 695.0 591.3 85.09% 35.5 30.1 84.58% 186.5 181.7 97.42%

Benzo(a)pyrene 89.8 37.2 41.37% 1225.7 1179.0 96.19% 62 .6 59.8 95.59% 333.8 365.6 109.55%Table s A

- F Page 44 E2300 RO

Compound μg/g PM μg/kg (dry) μg/MJ in μg/MJ out

avg sd % sd avg sd % sd avg sd % sd avg sd % sd

Perylene 13.6 6.0 44.39% 185.2 182.7 98.64% 9.5 9.3 98.17% 50.2 55.8 111.15%

Indeno(1,2,3

- cd)pyrene 97.3 79.9 82.08% 1543.6 2151.0 139.35% 78.3 108.4 138.41% 448.3 700.5 156.27%

Dibenzo(a,h)anthracene 12.6 0.00% 265.5 0.00% 13.8 0.00% 64.0 0.00%

Benzo(ghi)perylene 58.1 38.7 66.61% 925.6 1111.9 120.12% 47.1 56.2 119.38% 262.2 357.1 136.19%

Coronene 51.3 25.7 50.01% 853.9 874.0 102.36% 43.4 44.3 102.02% 242.2 287.5 118.74%

Dibenz(a,e)pyrene

sum

n

- alkanes

n

- Decane

n

- Undecane

n

- Dodecane

n

- Tridecane

n

- Tetradecane 36.9 12.9 34.97% 383.6 306.1 79.79% 19.8 15.7 79.22% 101.2 83.0 82.00%Table s A

- F Page 45 E2300 RO

Compound μg/g PM μg/kg (dry) μg/MJ in μg/MJ out

avg sd % sd avg sd % sd avg sd % sd avg sd % sd

n

- Pentadecane 12.6 0.00% 25.2 0.00% 1.5 0.0 0% 6.7 0.00%

n

- Hexadecane 38.5 0.00% 884.7 0.00% 44.6 0.00% 283.3 0.00%

n

- Heptadecane 19.8 0.00% 39.6 0.00% 2.4 0.00% 10.5 0.00%

n

- Octadecane 11.8 0.7 5.87% 176.1 131.4 74.62% 9.1 6.6 72.14% 49.6 39.7 79.99%

n

- Nonadecane 33.1 7.1 21.62% 423.6 388.5 91.72% 21.7 19.7 90.83% 115.0 119.5 103.86%

n

- Eicosane 51.0 15.2 29.80% 650.5 534.7 82.20% 33.4 27.3 81.71% 173.8 161.1 92.73%

n

- Heneicosane 74.9 18.3 24.43% 972.4 745.7 76.69% 49.9 38.1 76.36% 259.7 223.4 86.03%

n

- Docosane 86.7 16.7 19.27% 1112.5 811.6 72.96% 57.1 41.6 72.72% 296.1 235.7 79.60%

n

- Tricosane 106.3 21.5 20.23% 1345.3 965.0 71.73% 69.1 49.3 71.40% 358.3 285.4 79.65%

n

- Tetracosane 61.5 17.3 28.15% 770.1 554.8 72.04% 39.6 28.5 71.88% 203.7 158.7 77.90%

n

- Pentacosane 58.9 18.6 31.59% 728.5 518.6 71.19% 37.5 26.7 71.13% 191.9 146.3 76.22%

n

- Hexacosane 21.1 7.8 37.21% 251.5 169.2 67.26% 12.9 8.7 67.30% 65.9 48.9 74.11%

n

- Heptacosane 26.8 0.00% 375.7 0.00% 19.4 0.00% 100.7 0.00%Table s A

- F Page 46 E2300 RO

Compound μg/g PM μg/kg (dry) μg/MJ in μg/MJ out

avg sd % sd avg sd % sd avg sd % sd avg sd % sd

n

- Octacosane

n

- Nonacosane

n

- Triacontane

n

- Hentricontane

n

- Dotriacontane

n

- Tritriacontane

n

- Tetratriacontane

n

- Pentatriacontane

n

- Hexatriacontane

n

- Heptatriacontane

n

- Octatriaconta ne

branched and cyclic

alkanesTable s A

- F Page 47 E2300 RO

Compound μg/g PM μg/kg (dry) μg/MJ in μg/MJ out

avg sd % sd avg sd % sd avg sd % sd avg sd % sd

Phytane

Dodecylcyclohexane

2

- Methylnonadecane

3

- Methylnonadecane

Pentadecylcyclohexane

Nonadecylcyclohexane

Squalene

Pristane

methoxy phenols

Guaiacol 118.1 23.6 19.94% 1340.7 780.5 58.22% 68.8 39.6 57.57% 353.3 236.2 66.85%

2

- Methoxymethylphenol 33.0 16.7 50.48% 514.8 222.9 43.30% 26.3 11.8 44.86% 138.9 62. 1 44.71%

Ethylguaiacol 49.2 0.00% 1130.5 0.00% 57.0 0.00% 362.0 0.00%Table s A

- F Page 48 E2300 RO

Compound μg/g PM μg/kg (dry) μg/MJ in μg/MJ out

avg sd % sd avg sd % sd avg sd % sd avg sd % sd

Eugenol 24.8 0.00% 570.2 0.00% 28.8 0.00% 182.6 0.00%

Propylguaiacol 20.9 0.00% 481.7 0.00% 24.3 0.00% 154.2 0.00%

Vanillin 903.7 481.3 53.27% 13917.9 11323.9 81.36% 710. 6 579.4 81.54% 3776.4 3307.1 87.57%

Iso

- Eugenol 1350.3 1451.2 107.47% 24242.5 36775.6 151.70% 1234.6 1856.9 150.40% 7040.1 11765.5 167.12%

3,5

- Dimethoxyphenol

Syringaldehyde 4958.7 2940.9 59.31% 73749.8 58972.5 79.96% 3755.7 2984.6 79.47% 20 243.4 18159.9 89.71%

3,5

- Dimethoxy

- 4

-

hydroxyacetophenone 2004.9 421.5 21.02% 23760.0 13986.3 58.86% 1218.0 706.9 58.04% 6324.5 4174.4 66.00%

4

- Hydroxy

- 3

-

methoxycinnamaldehyde 507.1 168.4 33.22% 4998.1 4773.0 95.50% 259.4 244.4 94.22% 1295.4 1329.4 102.62 %

n

- alkanoic acids

Hexanoic Acid 57.8 25.4 43.93% 770.3 557.5 72.37% 39.8 28.8 72.29% 198.5 145.3 73.18%

Caprylic or Octanoic acid 89.7 66.1 73.68% 801.8 389.6 48.59% 41.4 19.3 46.72% 205.4 136.5 66.44%Table s A

- F Page 49 E2300 RO

Compound μg/g PM μg/kg (dry) μg/MJ in μg/MJ out

avg sd % sd avg sd % sd avg sd % sd avg sd % sd

est..Nonanoic Acid 196. 8 105.9 53.82% 1944.3 1292.9 66.50% 100.2 64.7 64.59% 515.4 439.8 85.32%

Capric or Decanoic Acid 113.4 50.7 44.73% 1159.6 764.5 65.92% 59.8 38.5 64.36% 306.3 248.6 81.16%

Dodecanoic Acid 325.8 223.9 68.74% 4368.7 5735.6 131.29% 225.4 297.3 131.88% 1109.4 1397.3 125.94%

Tetradecanoic Acid ME 259.3 64.4 24.85% 2914.0 1896.0 65.06% 149.9 96.7 64.53% 763.9 560.3 73.35%

est...Pentadecanoic Acid 119.4 36.9 30.92% 1307.7 834.5 63.82% 67.3 42.5 63.19% 341.9 251.2 73.48%

Hexandecanoic Acid 2124.9 486.8 22.91% 2 4435.8 16216.1 66.36% 1254.7 823.8 65.65% 6459.9 5018.5 77.69%

est...Heptadecanoic Acid 106.3 25.0 23.53% 1316.9 957.0 72.67% 67.6 48.9 72.40% 348.7 285.0 81.74%

Octadecanoic Acid 397.4 47.8 12.02% 4799.7 3319.6 69.16% 246.3 168.8 68.53% 1278.2 1015.0 79 .41%

est...Nonadecanoic Acid 41.0 11.3 27.67% 543.7 439.8 80.89% 27.9 22.4 80.50% 145.8 132.5 90.87%

Eicosanoic Acid 172.6 45.0 26.10% 2330.0 1919.2 82.37% 119.3 97.8 81.98% 627.5 581.9 92.73%

est..Heneicosananoic

Acid 118.7 46.2 38.95% 1760.8 1575.9 89 .50% 90.2 80.5 89.26% 478.2 465.8 97.41%

Docosanoic Acid 594.7 159.1 26.75% 8245.5 6830.3 82.84% 422.0 347.5 82.35% 2237.4 2104.2 94.05%

est...Tricosanoic Acid 185.3 55.7 30.04% 2634.0 2231.5 84.72% 134.7 113.5 84.23% 717.7 686.6 95.66%Table s A

- F Page 50 E2300 RO

Compound μg/g PM μg/kg (dry) μg/MJ in μg/MJ out

avg sd % sd avg sd % sd avg sd % sd avg sd % sd

Tetracosanoic Ac id 1986.6 765.0 38.51% 29093.0 25968.7 89.26% 1490.2 1331.1 89.32% 7830.4 7474.9 95.46%

est...Pentacosanoic Acid 102.0 43.8 42.94% 1640.2 1384.3 84.40% 84.0 71.0 84.51% 446.9 389.4 87.14%

est...Hexacosanoic Acid 696.5 354.1 50.84% 10816.3 10643.4 98.40% 553.0 542.5 98.10% 2968.9 3171.6 106.83%

est...Heptacosanoic Acid

Octacosanoic Acid 71.4 19.2 26.93% 1238.4 1015.2 81.97% 62.1 51.7 83.25% 376.8 353.0 93.70%

est...Nonacosanoic Acid

Triacontanoic Acid

di

- alkanoic acids

Succinic or Butanedioic

acid 501.6 202.1 40.29% 7090.1 6736.7 95.02% 361.8 340.6 94.13% 1955.8 2131.5 108.99%

Glutaric or Pentanedioic

Acid 526.2 172.8 32.84% 6506.9 5417.8 83.26% 332.6 271.7 81.68% 1785.8 1757 .2 98.40%Table s A

- F Page 51 E2300 RO

Compound μg/g PM μg/kg (dry) μg/MJ in μg/MJ out

avg sd % sd avg sd % sd avg sd % sd avg sd % sd

Adipic or Hexanedioic

Acid 236.5 147.7 62.48% 2842.0 2831.7 99.64% 145.3 145.7 100.26% 720.6 706.5 98.04%

Pimelic or Heptanedioic

acid 62.8 42.0 66.95% 1111.6 1154.7 103.88% 57.0 59.2 103.87% 306.1 324.0 105.85%

Suberic or Octanedioic

Acid 132 .8 127.4 95.98% 2509.5 2905.7 115.78% 130.0 150.8 116.02% 620.0 688.1 110.98%

Azelaic or Nonanedioic

Acid 510.9 423.3 82.85% 7173.6 9751.2 135.93% 369.6 505.7 136.84% 1817.2 2395.8 131.84%

Sebacic or Decanedioic

Acid 502.7 621.0 123.53% 2929.2 468.0 15.9 8% 157.9 10.9 6.91% 814.1 232.8 28.59%

aromatic acids

1,2

- Benzenedicarboxylic

Acid 523.1 488.5 93.38% 3659.9 1832.9 50.08% 189.6 92.7 48.88% 889.8 542.1 60.92%

1,4

- Benzenedicarboxylic

Acid 178.0 208.7 117.29% 1257.1 344.6 27.41 % 66.1 17.1 25.90% 343.9 132.9 38.64%

1,2

- Benzenedicarboxylic 95.7 56.1 58.66% 996.2 582.6 58.49% 51.4 29.5 57.35% 267.4 157.7 58.98%Table s A

- F Page 52 E2300 RO

Compound μg/g PM μg/kg (dry) μg/MJ in μg/MJ out

avg sd % sd avg sd % sd avg sd % sd avg sd % sd

Acid, 4

- methyl

1,2,3

-

Benzenetricarboxylic

Acid

1,2,4

-

Benzenetricarboxylic

Acid

1,3,5

-

Benzene tricarboxylic

Acid

1,2,3,4

-

Benzenetetracaroboxylic

Acid

alkenoic acids

Palmitoleic or 9

-

Hexadecenoic Acid 54.3 12.7 23.34% 1184.8 201.8 17.04% 60.7 11.5 18.97% 326.9 9.6 2.94%

Linoleic Acid 1253.4 517.3 41.27% 17943.2 16335.7 91.04% 916.3 829.0 90.47% 4908.0 4987.9 101.63%Table s A

- F Page 53 E2300 RO

Compound μg/g PM μg/kg (dry) μg/MJ in μg/MJ out

avg sd % sd avg sd % sd avg sd % sd avg sd % sd

Oleic Acid 674.5 178.3 26.44% 9407.7 8044.8 85.51% 481.6 409.3 84.99% 2556.3 2452.2 95.93%

Linolenic Acid 164.0 54.3 33.11% 2327.3 2066.1 88.78% 118.9 104.9 88.23% 635.2 637.2 100.32 %

resin acids

Isopimaric Acid

Dehydroabietic Acid 24.5 10.1 41.30% 300.4 277.6 92.40% 15.5 14.4 92.86% 76.7 69.4 90.55%

Abietic Acid 59.1 4.1 6.92% 917.9 710.2 77.36% 47.3 35.4 74.96% 260.8 220.1 84.38%

Pinonic Acid

Glycerin 711.5 426.3 59.91% 7150.4 4572.9 63.95% 365.9 225.0 61.49% 1845.9 1192.7 64.61%

Galactosan 1023.5 599.1 58.53% 9720.5 5700.8 58.65% 497.5 287.3 57.74% 2429.5 1588.8 65.39%

Mannosan 767.0 365.0 47.59% 1 0553.3 6967.0 66.02% 542.7 360.8 66.48% 2775.0 1763.9 63.56%Table s A

- F Page 54 E2300 RO

Compound μg/g PM μg/kg (dry) μg/MJ in μg/MJ out

avg sd % sd avg sd % sd avg sd % sd avg sd % sd

Monolein 282.6 116.7 41.31% 3929.2 2415.8 61.48% 202.4 125.6 62.07% 1017.8 635.5 62.44%

Monosterin

Levoglucosan 36791.1 10814.3 29.39% 400762.8 235815.3 58.84% 20528.5 11708.1 57.0 3% 106904.6 76096.5 71.18%

Cholesterol 255.4 133.3 52.19% 1980.6 1468.3 74.13% 103.8 74.3 71.55% 497.8 427.5 85.88%

Cholestanol

Stigmasterol 51.2 0.00% 1076.0 0.00% 55.8 0.00% 259.4 0.00%Table s A

- F Page 55

Table E . SVOC Emission Factors for ACT

- HW

ACT

- H W

Compound μg/g PM μg/kg (dry) μg/MJ in μg/MJ out

avg sd % sd avg sd % sd avg sd % sd avg sd % sd

PAH

Nap h thalene 9.0 6.6 73.30% 2.3 0.6 26.83% 0.114 0.030 26.44% 0.27 0.07 25.54%

1

- Methylnaphthalene

2

- Methylnaphthalene

2,6

- D i methylnaphthalene 19.1 0.00% 3.1 0.00% 0.152 0.00% 0.34 0.00%

Acenap h thylene 31.5 46.2 146.93% 6.1 6.4 104.65% 0.306 0.317 103.43% 0.71 0.69 97.73%

Acenap h thene

Dibenzofuran 3.7 3.0 82.92% 1.0 0.1 9.70% 0.052 0.004 8.24% 0. 12 0.00 1.78%

Fluorene 20.7 20.0 96.72% 6.2 3.7 59.36% 0.310 0.184 59.34% 0.75 0.45 59.66%

Methylfluorene 7.8 1.8 23.08% 4.0 0.9 23.08% 0.202 0.047 23.08% 0.50 0.12 23.08%

Phenanthrene 103.0 37.3 36.25% 40.5 29.0 71.68% 2.049 1.481 72.26% 5.04 3.77 74.7 5%

Anthracene 19.8 6.1 30.99% 7.3 4.9 67.36% 0.371 0.253 68.06% 0.91 0.65 71.06%Table s A

- F Page 56 ACT

- H W

Compound μg/g PM μg/kg (dry) μg/MJ in μg/MJ out

avg sd % sd avg sd % sd avg sd % sd avg sd % sd

9

- Methylanthracene

Fluoranthene 116.7 56.2 48.20% 42.7 34.4 80.58% 2.155 1.751 81.26% 5.28 4.45 84.25%

Retene 72.3 25.8 35.77% 27.8 20.4 73.25% 1.408 1.040 73. 87% 3.46 2.65 76.56%

Pyrene 122.3 57.3 46.90% 41.3 29.0 70.12% 2.085 1.478 70.88% 5.08 3.77 74.27%

Benzo(ghi)fl u oranthene

Cyclopenta(cd)pyrene

Benz(a)anthracene 34.7 6.8 19.43% 12.8 7.7 60.08% 0.647 0.394 60.81% 1.59 1.01 63.97%

Chrysene 41.4 7.1 17.20% 15.0 8.6 57.12% 0.760 0.440 57.88% 1.86 1.14 61.17%

1

- Methylchrysene 1.3 0.00% 0.6 0.00% 0.033 0.00% 0.08 0.00%

Benzo(b)fluoranthene 28.7 6.1 21.30% 10.5 6.4 60.63% 0.531 0.326 61.37% 1.30 0.84 64.55%

Benzo(k)fluoranthene 9.8 2.1 20.93% 3.6 2.2 60.49% 0.183 0.112 61.21% 0.45 0.29 64.34%

Benzo(e)pyrene 16.1 4.3 26.79% 5.5 2.7 49.21% 0.277 0.138 50.05% 0.67 0.36 53.73%

Benzo(a)pyrene 16.5 4.3 26.32% 5.7 2.9 51.42% 0.286 0.150 52.25% 0.70 0.39 55.84%Table s A

- F Page 57 ACT

- H W

Compound μg/g PM μg/kg (dry) μg/MJ in μg/MJ out

avg sd % sd avg sd % sd avg sd % sd avg sd % sd

Perylene 6.0 0.5 7.44% 3.1 0.2 7.44% 0.156 0.012 7.44% 0.39 0.03 7.44%

Indeno(1,2,3

- cd)pyrene 17.6 0.00% 2.8 0.00% 0.139 0.00% 0.31 0.00%

Dibenzo(a,h)anthracene

Benzo(ghi)perylene 8.3 0.00% 4.2 0.00% 0.214 0.00% 0.53 0.00%

Coronene 23.4 8.3 35.36% 3.7 1.3 35.36% 0.186 0.066 35.36% 0.42 0.15 35.36%

Dibenz(a,e)pyrene

sum

n

- alkanes

n

- Decane

n

- Undecane

n

- Dodecane

n

- Tridecane

n

- Tetradecane 17.8 0.00% 9.1 0.00% 0.461 0 .00% 1.15 0.00%Table s A

- F Page 58 ACT

- H W

Compound μg/g PM μg/kg (dry) μg/MJ in μg/MJ out

avg sd % sd avg sd % sd avg sd % sd avg sd % sd

n

- Pentadecane 11.1 2.2 19.97% 5.7 1.1 19.97% 0.288 0.057 19.97% 0.72 0.14 19.97%

n

- Hexadecane 9.0 1.6 18.00% 4.6 0.8 18.00% 0.234 0.042 18.00% 0.58 0.10 18.00%

n

- Heptadecane 13.4 0.00% 6.8 0.00% 0.346 0.00% 0.86 0.00%

n

- Octadecane 9.7 2.3 23.39% 4.9 1.2 23.39% 0.250 0.059 23.39% 0.62 0.15 23.39%

n

- Nonadecane 9.0 2.1 23.57% 4.6 1.1 23.57% 0.234 0.055 23.57% 0.58 0.14 23.57%

n

- Eicosane

n

- Heneicosane 12.7 0.00% 6.5 0.00% 0.329 0.00% 0.82 0.00%

n

- Docosane 27.7 11.6 4 1.96% 9.3 2.5 26.64% 0.471 0.130 27.73% 1.15 0.37 32.50%

n

- Tricosane 34.0 6.5 19.22% 12.6 5.4 42.70% 0.635 0.277 43.58% 1.56 0.74 47.38%

n

- Tetracosane 26.1 9.5 36.40% 10.6 4.0 37.39% 0.535 0.203 37.89% 1.32 0.53 40.08%

n

- Pentacosane 29.3 21.4 72.99% 8.7 3.7 42.65% 0.435 0.187 42.90% 1.05 0.47 44.46%

n

- Hexacosane 14.3 8.7 60.86% 4.9 0.4 7.71% 0.247 0.022 8.75% 0.60 0.08 13.41%

n

- HeptacosaneTable s A

- F Page 59 ACT

- H W

Compound μg/g PM μg/kg (dry) μg/MJ in μg/MJ out

avg sd % sd avg sd % sd avg sd % sd avg sd % sd

n

- Octacosane

n

- Nonacosane 45.8 0.00% 23.4 0.00% 1.186 0.00% 2.96 0.00%

n

- Triacontan e

n

- Hentricontane

n

- Dotriacontane

n

- Tritriacontane

n

- Tetratriacontane

n

- Pentatriacontane

n

- Hexatriacontane

n

- Heptatriacontane

n

- Octatriacontane

branched and cyclic

alkanesTable s A

- F Page 60 ACT

- H W

Compound μg/g PM μg/kg (dry) μg/MJ in μg/MJ out

avg sd % sd avg sd % sd avg sd % sd avg sd % sd

Phytane

Dodecylcyclohexane

2

- Methylnonadecane

3

- Methylnonadecane

Pentadecylcyclohexane

Nonadecylcyclohexane

Squalene

Pristane

methoxy henols

Guaiacol 45.2 8.7 19.31% 14.1 8.3 58.76% 0.709 0.426 60.16% 1.72 1.14 66.33%

2

- Methoxymethylphenol

EthylguaiacolTable s A

- F Page 61 ACT

- H W

Compound μg/g PM μg/kg (dry) μg/MJ in μg/MJ out

avg sd % sd avg sd % sd avg sd % sd avg sd % sd

Eugenol

Propylguaiacol

Vanillin 76.0 34.3 45.05% 27.7 5.8 20.82% 1.399 0.303 21.67% 3.42 0.87 25.43%

Iso

- Eugenol 88.0 19.2 21.78% 27.1 15.4 56.66% 1.366 0.793 58.09% 3.30 2.13 64.35%

3,5

- Dimethoxyphenol

Syringaldehyde 730.6 347.0 47.50% 293.2 216.3 73.78% 14.833 11.018 74.28% 36.54 27.93 76.44%

3,5

- Dimethoxy

- 4

-

hydroxyacetophenone 139.1 42.3 30.44% 59.5 35.9 60.35% 3.010 1.830 60.78% 7.44 4.66 62.61%

4

- Hydroxy

- 3

-

methoxycinnamaldehyde

n

- alkanoic acids

Hexanoic Acid 1 75.1 69.5 39.67% 56.8 23.7 41.73% 2.863 1.218 42.54% 6.95 3.21 46.20%

Caprylic or Octanoic acid 92.3 51.8 56.15% 30.2 14.2 47.01% 1.521 0.724 47.59% 3.69 1.86 50.36%Table s A

- F Page 62 ACT

- H W

Compound μg/g PM μg/kg (dry) μg/MJ in μg/MJ out

avg sd % sd avg sd % sd avg sd % sd avg sd % sd

est..Nonanoic Acid 143.0 90.3 63.15% 41.3 13.5 32.62% 2.076 0.686 33.02% 5.00 1.76 35.29 %

Capric or Decanoic Acid 33.9 24.4 71.79% 9.3 3.0 32.08% 0.466 0.150 32.12% 1.12 0.37 32.96%

Dodecanoic Acid 53.1 40.9 77.11% 14.4 4.9 34.11% 0.725 0.246 33.97% 1.74 0.59 34.02%

Tetradecanoic Acid ME 86.1 56.5 65.66% 24.2 7.0 28.86% 1.218 0.355 29.12% 2.92 0.90 30.89%

est...Pentadecanoic Acid 36.2 17.6 48.66% 12.3 6.2 50.45% 0.620 0.317 51.10% 1.51 0.82 54.07%

Hexandecanoic Acid 373.9 127.8 34.18% 145.6 95.2 65.38% 7.363 4.857 65.97% 18.10 12.40 68.50%

est...Heptadecanoic Acid 11.5 1.7 14.77% 5.8 0.9 14.77% 0.297 0.044 14.77% 0.74 0.11 14.77%

Octadecanoic Acid 106.6 30.5 28.64% 43.1 22.8 52.85% 2.183 1.165 53.37% 5.38 2.99 55.63%

est...Nonadecanoic Acid 4.3 0.7 15.77% 2.2 0.3 15.77% 0.112 0.018 15.77% 0.28 0.04 15.77%

Eicosanoic Acid 13.3 4.1 30.51 % 6.8 2.1 30.51% 0.345 0.105 30.51% 0.86 0.26 30.51%

est..Heneicosananoic

Acid 8.7 0.00% 4.5 0.00% 0.226 0.00% 0.56 0.00%

Docosanoic Acid 23.5 8.2 34.83% 12.0 4.2 34.83% 0.608 0.212 34.83% 1.52 0.53 34.83%

est...Tricosanoic Acid 11.4 0.00% 5.8 0.0 0% 0.296 0.00% 0.74 0.00%Table s A

- F Page 63 ACT

- H W

Compound μg/g PM μg/kg (dry) μg/MJ in μg/MJ out

avg sd % sd avg sd % sd avg sd % sd avg sd % sd

Tetracosanoic Acid 65.3 31.3 47.95% 33.3 16.0 47.95% 1.688 0.810 47.95% 4.21 2.02 47.95%

est...Pentacosanoic Acid

est...Hexacosanoic Acid 50.5 0.00% 25.7 0.00% 1.306 0.00% 3.26 0.00%

est...Heptacosanoic Acid

Octacosanoic Acid

est...Nonacosanoic Acid

Triacontanoic Acid

di

- alkanoic acids

Succinic or Butanedioic

acid 116.2 148.0 127.36% 21.8 21.4 98.20% 1.084 1.055 97.34% 2.48 2.32 93.36%

Glutaric or Pentanedioic

Acid 27.8 9.3 33.50% 11.4 4.5 39.71% 0.579 0.233 40.19% 1.43 0.60 42.30%Table s A

- F Page 64 ACT

- H W

Compound μg/g PM μg/kg (dry) μg/MJ in μg/MJ out

avg sd % sd avg sd % sd avg sd % sd avg sd % sd

Adipic or Hexanedioic

Acid 29.1 27.8 95.64% 6.3 2.1 33.66% 0.315 0.101 32.04% 0.74 0.18 24.64%

Pimelic or Heptanedioic

acid

Suberic or Octanedioic

Acid 74.2 0.00% 11.9 0.00% 0.588 0.00% 1.31 0.00%

Azelaic or Nonanedioic

Acid 68.4 66.5 97.22% 14.8 8.3 55.96% 0.740 0.408 55.10% 1.73 0.89 51.41%

Sebacic or Decanedioic

Acid

aromatic acids

1,2

- Benzenedicarboxylic

Acid 1803.2 1095.5 60.75% 583.3 372.4 63.85% 29.406 18.965 64.49% 71.39 48.17 67.47%

1,4

- Benzenedicarboxylic

Acid 829.0 494.9 59.69% 422.8 252.4 59.69% 21.451 12.804 59.69% 53.51 31.94 59.69%

1,2

- Benzenedicarboxylic 89.8 0.00% 45.8 0.00% 2.323 0.00% 5.80 0.00%Table s A

- F Page 65 ACT

- H W

Compound μg/g PM μg/kg (dry) μg/MJ in μg/MJ out

avg sd % sd avg sd % sd avg sd % sd avg sd % sd

Acid, 4 met hyl

1,2,3

-

Benzenetricarboxylic

Acid

1,2,4

-

Benzenetricarboxylic

Acid

1,3,5

-

Benzenetricarboxylic

Acid

1,2,3,4

-

Benzenetetracaroboxylic

Acid

alk enoic acids

Palmitoleic or 9

-

Hexadecenoic Acid

Linoleic Acid 21.5 0.00% 10.9 0.00% 0.556 0.00% 1.39 0.00%Table s A

- F Page 66 ACT

- H W

Compound μg/g PM μg/kg (dry) μg/MJ in μg/MJ out

avg sd % sd avg sd % sd avg sd % sd avg sd % sd

Oleic Acid 49.5 10.5 21.27% 22.8 10.2 44.73% 1.155 0.520 45.03% 2.87 1.33 46.30%

Linolenic Acid 9.2 2.2 23.80% 4.7 1.1 23.80% 0.239 0.057 23.80% 0.60 0.14 23.80%

resin acids

Isopimaric Acid

Dehydroabietic Acid 31.2 14.5 46.49% 9.3 4.4 47.13% 0.467 0.224 47.97% 1.13 0.58 51.80%

Abietic Acid

Pinonic Acid

Glycerin 1002.3 1806.8 180.26% 216.4 279.8 129.30% 10.816 13.862 128.16% 25.26 31.10 123.12%

Galactosan 1213.8 1569.7 129.32% 302.0 285.4 94.48% 15.148 14.280 94.26% 35.94 33.68 93.70%

MannosanTable s A

- F Page 67 ACT

- H W

Compound μg/g PM μg/kg (dry) μg/MJ in μg/MJ out

avg sd % sd avg sd % sd avg sd % sd avg sd % sd

Monolein

Monosterin

Levoglucosan 8216.7 3762.9 45.80% 2890.8 1716.9 59.39% 145.944 87.643 60.05% 356.48 224.56 62.99%

Cholesterol 303.8 43.0 14.16% 154.9 21.9 14.16% 7.860 1.113 14.16% 19.61 2.78 14.16%

Cholestanol

StigmasterolTable s A

- F Page 68

Table F . SVOC Emission Factors for AFB RO

AFB RO

Compound μg/g PM μg/kg (dry) μg/MJ in μg/MJ out

avg sd % sd avg sd % sd avg sd % sd avg sd % sd

PAH

Nap h thalene 16.5 14.4 87.41% 25.3 12.8 50.46% 1.3 0.7 50.85% 1.5 0.9 61.51%

1

- Methy lnaphthalene

2

- Methylnaphthalene

2,6

- D i methylnaphthalene

Acenap h thylene 13.3 0.00% 38.6 0.00% 2.0 0.00% 2.4 0.00%

Acenap h thene

Dibenzofuran

Fluorene

Methylfluorene

Phenanthrene 209.5 400.1 190.93% 637.1 1170.1 183.67% 32.7 60.0 183.75% 39.6 72.9 184.19%

Anthracene 115.2 117.5 102.04% 354.9 311.4 87.73% 18.2 16.0 87.81% 22.1 19.4 87.72%Table s A

- F Page 69 AFB RO

Compound μg/g PM μg/kg (dry) μg/MJ in μg/MJ out

avg sd % sd avg sd % sd avg sd % sd avg sd % sd

9

- Methylanthracene 20.0 0.00% 57.9 #DIV/0! #DIV/0! 3.0 0.00% 3.6 0.00%

F luoranthene 908.0 1401.0 154.28% 2734.9 4212.5 154.03% 140.1 216.2 154.27% 168.2 263.6 156.69%

Retene 318.9 208.5 65.38% 777.0 589.8 75.91% 39.7 30.3 76.29% 45.5 37.5 82.51%

Pyrene 807.2 1321.2 163.68% 2386.9 3912.0 163.90% 122.3 200.8 164.12% 146.7 244. 8 166.88%

Benzo(ghi)fl u oranthene

Cyclopenta(cd)pyrene

Benz(a)anthracene 253.3 292.6 115.50% 737.9 895.0 121.28% 37.8 46.0 121.56% 44.9 56.5 125.87%

Chrysene 226.3 286.9 126.80% 640.5 872.6 136.23% 32.8 44.8 136.56% 38.9 54.9 141 .04%

1

- Methylchrysene 19.4 10.2 52.70% 51.7 34.9 67.50% 2.6 1.8 67.94% 3.1 2.3 75.66%

Benzo(b)fluoranthene 127.1 128.4 101.00% 369.9 407.9 110.29% 18.9 20.9 110.57% 22.4 25.9 115.55%

Benzo(k)fluoranthene 34.0 33.5 98.45% 94.8 103.5 109.18% 4.9 5.3 109.4 4% 5.7 6.6 116.09%

Benzo(e)pyrene 40.8 35.1 85.86% 113.0 110.7 97.94% 5.8 5.7 98.24% 6.8 7.1 105.12%

Benzo(a)pyrene 60.0 62.3 103.86% 174.3 195.7 112.27% 8.9 10.0 112.47% 10.6 12.4 117.67%Table s A

- F Page 70 AFB RO

Compound μg/g PM μg/kg (dry) μg/MJ in μg/MJ out

avg sd % sd avg sd % sd avg sd % sd avg sd % sd

Perylene 13.4 9.6 71.38% 41.1 31.5 76.75% 2.1 1.6 76.82% 2.5 2.0 81.59%

Indeno(1,2,3

- cd)pyrene 79.0 8.7 10.98% 276.6 41.9 15.13% 14.2 2.1 15.02% 17.2 2.6 15.16%

Dibenzo(a,h)anthracene

Benzo(ghi)perylene 56.3 27.7 49.12% 187.2 46.4 24.81% 9.6 2.4 24.92% 11.7 2.9 24.78%

Coronene 55.6 58.8 105.80% 170.3 15 7.6 92.59% 8.7 8.1 92.66% 10.6 9.8 92.58%

Dibenz(a,e)pyrene

sum

n

- alkanes

n

- Decane

n

- Undecane

n

- Dodecane

n

- Tridecane

n

- TetradecaneTable s A

- F Page 71 AFB RO

Compound μg/g PM μg/kg (dry) μg/MJ in μg/MJ out

avg sd % sd avg sd % sd avg sd % sd avg sd % sd

n

- Pentadecane

n

- Hexadecane

n

- Heptadecane

n

- Octadecane

n

- Nonadecane

n

- Eicosane 15.3 4.5 29.53% 44.0 11.1 25.20% 2.2 0.6 25.55% 2.7 0.7 28.14%

n

- Heneicosane 19.6 6.3 31.91% 54.9 2.7 4.84% 2.8 0.2 6.71% 3.3 0.3 9. 36%

n

- Docosane 32.9 15.9 48.34% 76.1 12.9 16.95% 3.9 0.7 17.13% 4.3 1.0 22.98%

n

- Tricosane 25.5 6.2 24.32% 72.2 7.5 10.41% 3.7 0.4 11.66% 4.4 0.6 13.86%

n

- Tetracosane 27.2 12.4 45.46% 65.8 23.6 35.87% 3.4 1.2 36.49% 3.8 1.7 44.67%

n

- Pentacosane 43.7 21 .8 49.85% 89.8 45.5 50.60% 4.6 2.3 50.95% 5.4 3.0 54.89%

n

- Hexacosane 28.6 19.5 68.29% 57.5 28.1 48.88% 3.0 1.4 48.87% 3.8 1.7 44.35%

n

- HeptacosaneTable s A

- F Page 72 AFB RO

Compound μg/g PM μg/kg (dry) μg/MJ in μg/MJ out

avg sd % sd avg sd % sd avg sd % sd avg sd % sd

n

- Octacosane

n

- Nonacosane

n

- Triacontane

n

- Hentricontan e

n

- Dotriacontane

n

- Tritriacontane

n

- Tetratriacontane

n

- Pentatriacontane

n

- Hexatriacontane

n

- Heptatriacontane

n

- Octatriacontane

branched a nd cyclic

alkanesTable s A

- F Page 73 AFB RO

Compound μg/g PM μg/kg (dry) μg/MJ in μg/MJ out

avg sd % sd avg sd % sd avg sd % sd avg sd % sd

Phytane

Dodecylcyclohexane

2

- Methylnonadecane

3

- Methylnonadecane

Pentadecylcyclohexane

Nonadecylcyclohexane

Squalene

Pristane

methoxyphenols

Guaiacol 119.7 32.2 26.88% 260.2 77.5 29.78% 13.3 4.0 30.08% 15.5 5.3 33.94%

2

- Methoxymethylphenol 24.0 4.5 18.83% 69.7 14.3 20.52% 3.6 0.8 21.53% 4.2 1.0 24.54%

EthylguaiacolTable s A

- F Page 74 AFB RO

Compound μg/g PM μg/kg (dry) μg/MJ in μg/MJ out

avg sd % sd avg sd % sd avg sd % sd avg sd % sd

Eugenol

Propylguaiacol

Vanillin 365.0 221.4 60.65% 1057.9 891.2 84.24% 54.1 45.8 84.58% 63.6 57.7 90.70%

Iso

- Eugenol 199.0 74.7 37.56% 438.4 206.9 47.19% 22.4 10.7 47.54% 26.4 13.7 51.76%

3,5

- Dimethoxyphenol

Syringealdehyde 6755.2 44 45.9 65.81% 17751.7 15745.6 88.70% 905.1 805.6 89.01% 1040.9 999.2 95.99%

3,5

- Dimethoxy

- 4

-

hydroxyacetophenone 2451.0 769.2 31.38% 6115.5 2096.1 34.27% 311.9 107.1 34.33% 353.5 153.8 43.51%

4

- Hydroxy

- 3

-

methoxycinnamaldehyde 1517.9 593.9 39.13% 3671.1 1016 .9 27.70% 187.0 50.7 27.12% 211.0 76.0 36.05%

n

- alkanoic acids

Hexanoic Acid 426.9 834.1 195.38% 516.0 844.2 163.62% 26.5 43.5 163.95% 36.2 66.3 183.09%

Caprylic or Octanoic acid 137.6 181.9 132.22% 220.5 201.9 91.57% 11.3 10.4 92.09% 14.4 15.2 106.02%Table s A

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Compound μg/g PM μg/kg (dry) μg/MJ in μg/MJ out

avg sd % sd avg sd % sd avg sd % sd avg sd % sd

est..Nonanoic Acid 291.4 274.5 94.22% 494.6 271.7 54.93% 25.4 14.1 55.62% 30.7 21.2 69.06%

Capric or Decanoic Acid 119.6 102.0 85.30% 207.8 129.5 62.32% 10.6 6.7 63.04% 12.7 9.2 71.84%

Dodecanoic Acid 166.2 97.3 58.53% 317.5 59 .2 18.65% 16.2 3.1 18.93% 19.3 6.0 31.30%

Tetradecanoic Acid ME 240.7 109.7 45.58% 481.3 52.9 10.98% 24.6 2.9 11.76% 28.9 6.1 21.20%

est...Pentadecanoic Acid 104.9 31.0 29.52% 229.6 86.9 37.85% 11.7 4.5 38.10% 13.8 5.9 42.66%

Hexandecanoic Acid 1447.8 4 51.5 31.18% 3144.0 900.4 28.64% 160.6 46.0 28.64% 185.0 56.1 30.30%

est...Heptadecanoic Acid 57.4 17.9 31.17% 130.1 48.7 37.47% 6.6 2.5 37.55% 7.6 3.1 40.59%

Octadecanoic Acid 294.7 63.3 21.46% 654.5 214.6 32.79% 33.5 11.1 33.12% 39.1 14.4 36.89%

est... Nonadecanoic Acid 17.8 3.6 20.27% 45.1 11.7 25.87% 2.3 0.6 26.51% 2.6 1.0 37.11%

Eicosanoic Acid 70.7 14.8 20.93% 180.4 59.4 32.95% 9.2 3.1 33.15% 10.5 4.5 42.63%

est..Heneicosananoic

Acid 43.1 10.2 23.76% 108.5 31.0 28.58% 5.5 1.6 28.73% 6.3 2.4 38.59%

Docosanoic Acid 178.3 58.5 32.79% 473.6 235.1 49.64% 24.1 12.0 49.62% 27.9 15.8 56.59%

est...Tricosanoic Acid 75.8 14.2 18.77% 200.6 75.0 37.40% 10.3 3.9 38.10% 11.9 5.4 45.66%Table s A

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Compound μg/g PM μg/kg (dry) μg/MJ in μg/MJ out

avg sd % sd avg sd % sd avg sd % sd avg sd % sd

Tetracosanoic Acid 670.0 132.3 19.75% 1749.7 682.6 39.01% 89.3 35.0 39.19% 1 02.6 48.9 47.63%

est...Pentacosanoic Acid 75.4 25.9 34.34% 233.2 110.8 47.52% 11.9 5.8 48.62% 14.2 7.1 50.13%

est...Hexacosanoic Acid 640.1 239.6 37.43% 1668.8 829.9 49.73% 85.5 43.2 50.49% 97.4 56.5 57.97%

est...Heptacosanoic Acid

Octacosa noic Acid 75.1 0.00% 217.7 0.00% 11.2 0.00% 13.3 0.00%

est...Nonacosanoic Acid

Triacontanoic Acid

di

- alkanoic acids

Succinic or Butanedioic

acid 912.3 781.9 85.70% 2234.0 2449.6 109.65 % 114.5 125.8 109.89% 135.4 154.3 113.90%

Glutaric or Pentanedioic

Acid 740.3 213.2 28.80% 1629.9 610.3 37.44% 83.3 31.4 37.72% 97.6 40.9 41.88%Table s A

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Compound μg/g PM μg/kg (dry) μg/MJ in μg/MJ out

avg sd % sd avg sd % sd avg sd % sd avg sd % sd

Adipic or Hexanedioic

Acid 128.9 91.5 71.01% 289.8 106.2 36.66% 14.8 5.5 36.97% 16.1 5.7 35.66%

Pimelic or H eptanedioic

acid 43.4 40.0 92.26% 93.2 39.3 42.16% 4.8 2.0 41.93% 5.0 1.6 31.58%

Suberic or Octanedioic

Acid 65.7 72.5 110.48% 130.9 78.4 59.89% 6.7 4.0 59.67% 6.9 2.9 41.76%

Azelaic or Nonanedioic

Acid 215.4 154.0 71.47% 456.0 335.7 73.63% 23.4 17.3 73. 88% 26.6 20.3 76.25%

Sebacic or Decanedioic

Acid 1321.6 1205.2 91.19% 2680.5 1665.1 62.12% 136.7 85.2 62.33% 144.1 84.3 58.49%

aromatic acids

1,2

- Benzenedicarboxylic

Acid 1662.4 1544.9 92.93% 2784.5 1217.7 43.73% 142.5 62.9 44. 15% 168.2 92.4 54.94%

1,4

- Benzenedicarboxylic

Acid 310.7 212.8 68.49% 693.2 334.0 48.18% 35.2 16.5 46.96% 38.9 19.8 50.96%

1,2

- Benzenedicarboxylic 219.1 122.9 56.09% 490.1 91.7 18.71% 25.0 4.3 17.37% 27.5 5.4 19.73%Table s A

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Compound μg/g PM μg/kg (dry) μg/MJ in μg/MJ out

avg sd % sd avg sd % sd avg sd % sd avg sd % sd

Acid, 4

– methyl

1,2,3

-

Benzenetricarb oxylic

Acid

1,2,4

-

Benzenetricarboxylic

Acid

1,3,5

-

Benzenetricarboxylic

Acid

1,2,3,4

-

Benzenetetracaroboxylic

Acid

alkenoic acids

Palmitoleic or 9

-

Hexadecenoic Acid

L inoleic Acid 1345.4 303.0 22.52% 3364.1 793.4 23.58% 171.8 41.3 24.03% 195.5 68.5 35.03%Table s A

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Compound μg/g PM μg/kg (dry) μg/MJ in μg/MJ out

avg sd % sd avg sd % sd avg sd % sd avg sd % sd

Oleic Acid 389.6 97.9 25.12% 971.6 241.6 24.86% 49.6 12.6 25.30% 56.2 20.0 35.68%

Linolenic Acid 100.8 23.4 23.17% 252.1 61.9 24.56% 12.9 3.2 24.97% 14.7 5.2 35.79%

resin acids

Isopimaric Acid 164.2 119.7 72.89% 298.4 118.2 39.61% 15.3 6.1 40.00% 17.9 8.2 45.70%

Dehydroabietic Acid 368.9 219.6 59.53% 715.7 276.4 38.62% 36.6 14.3 38.98% 43.1 19.2 44.68%

Abietic Acid 156.6 84.7 54.07% 427.8 314.1 73.42% 21.9 16.2 73.87% 25.4 20.6 81.16%

Pinonic Acid 9.8 0.00% 28.3 0.00% 1.5 0.00% 1.7 0.00%

Glycerin 1250.6 1128.6 90.25% 2184.0 1551.2 71.03% 111.9 79.8 71.33% 132.4 103.0 77.75%

Galactosan 1994.9 2224.8 111.52 % 4647.2 6660.2 143.32% 238.1 341.9 143.60% 287.4 417.3 145.17%

Mannosan 479.1 648.4 135.32% 1434.0 1865.5 130.09% 73.5 95.8 130.24% 88.9 116.5 131.02%Table s A

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Compound μg/g PM μg/kg (dry) μg/MJ in μg/MJ out

avg sd % sd avg sd % sd avg sd % sd avg sd % sd

Monolein

Monosterin

Levoglucosan 48273.0 15199.8 31.49% 121803.7 69306.9 56. 90% 6233.7 3573.6 57.33% 7225.8 4501.4 62.30%

Cholesterol 231.7 69.5 29.99% 790.5 33.7 4.26% 40.5 1.8 4.38% 49.2 2.1 4.23%

Cholestanol

Stigmasterol