Plant name: Dal Italia LLC DIOXIN-FURAN PARTICLE CATCH DIOXIN-FURAN EMISSION CALCULATION

Location: Muskogee, OK

FACID: DALT-1

Test date: 5/10-16/2010

Equipment: Roller Kilns #3,4

Control device: Wet Scrubber #2

Measured wt, pg Measured wt, ng Volum. Volum. Gas Gas Emission Emission Process

Compound Mass (pg) Flag Mass (pg) Flag Mass (pg) Flag Congener Run 1 Run 2 Run 3 Run Test Flow rate, Flow rate, volume, volume, % Stack gas O2 conc., Velocity, Mass, Run Concentration, rate, rate, rate, Emission factor,

Total TCDD 6570 ADL 6510 ADL 11200 ADL Total TCDD 6.57 6.51 11.2 Pollutant No. Method ACFM DSCFM DSCF DSCM Moisture temp., F % ft/sec ng Flag gr/dscf ng/dscm ng/dscm @7%O2 g/hr lb/hr ton/hr g/ton lb/ton

Total PeCDD 6560 ADL 6620 ADL 9710 ADL Total PeCDD 6.56 6.62 9.71 CDD/CDF 1 M23 66,874 50,239 146.72 4.15 18.6 132 18.6 39.4 71.7881 DLL 7.55E-09 17.2771 104.414 1.47E-03 3.25E-06 27.30 5.40E-05 1.19E-07

Total HxCDD 9080 ADL 7760 ADL 10700 ADL Total HxCDD 9.08 7.76 10.7 2 68,621 51,264 161.73 4.58 19 133 19.0 40.4 61.6392 DLL 5.88E-09 13.4572 98.450 1.17E-03 2.58E-06 27.44 4.27E-05 9.42E-08

Total HpCDD 10200 ADL 8220 ADL 13400 ADL Total HpCDD 10.2 8.22 13.4 3 68,485 51,356 162.91 4.61 18.8 133 18.8 40.4 88.5521 DLL 8.39E-09 19.1936 127.0435 1.67E-03 3.69E-06 26.83 6.24E-05 1.38E-07

Total OCDD 39300 ADL 32400 ADL 43400 ADL Total OCDD 39.3 32.4 43.4 Average 67,993 50,953 157.12 4.45 18.80 132.6 18.8 40.1 7.27E-09 16.6426 109.969 1.44E-03 3.18E-06 27.19 5.30E-05 1.17E-07

Total dioxins 71.71 61.51 88.41 TEQ 1 M23 66,874 50,239 146.72 4.15 18.6 132 18.6 39.4 1.697189 DLL 1.79E-10 0.408458 2.468508 3.49E-05 7.69E-08 27.30 1.28E-06 2.82E-09

Total TCDF 50.4 ADL 73.8 ADL 96.6 ADL Total TCDF 0.0504 0.0738 0.0966 2 68,621 51,264 161.73 4.58 19 133 19.0 40.4 1.720058 DLL 1.64E-10 0.375525 2.747265 3.27E-05 7.21E-08 27.44 1.19E-06 2.63E-09

Total PeCDF 5.57 ADL 45.6 ADL 35.1 ADL Total PeCDF 0.00557 0.0456 0.0351 3 68,485 51,356 162.91 4.61 18.8 133 18.8 40.4 2.294856 DLL 2.17E-10 0.497409 3.292373 4.34E-05 9.57E-08 26.83 1.62E-06 3.57E-09

Total HxCDF 13.6 ADL 5.2 ADL 3.66 ADL Total HxCDF 0.0136 0.0052 0.00366 Average 67,993 50,953 157.12 4.45 18.80 132.6 18.8 40.1 1.87E-10 0.427131 2.836049 3.70E-05 8.16E-08 27.19 1.36E-06 3.00E-09

Total HpCDF 0.77 BDL 0.76 BDL 0.66 BDL Total HpCDF 0.00077 0.00076 0.00066

Total OCDF 7.8 BDL 3.8 BDL 6.1 BDL Total OCDF 0.0078 0.0038 0.0061

Total furans 0.07814 0.12916 0.14212

TOTAL CDD/CDF 71.7881 61.6392 88.5521

Measured wt, ng TEQ, ng

Congener Mass (pg) Flag Mass (pg) Flag Mass (pg) Flag Congener Run 1 Run 2 Run 3 Congener Run 1 Run 2 Run 3 TEF

2,3,7,8-TCDD 768 ADL 744 ADL 1090 ADL 2,3,7,8 TCDD 0.768 0.744 1.09 2,3,7,8 TCDD 0.768 0.744 1.09 1

1,2,3,7,8-PeCDD 705 ADL 780 ADL 941 ADL 1,2,3,7,8 PeCDD 0.705 0.78 0.941 1,2,3,7,8 PeCDD 0.705 0.78 0.941 1

1,2,3,4,7,8-HxCDD 345 ADL 271 ADL 350 ADL 1,2,3,4,7,8 HxCDD 0.345 0.271 0.35 1,2,3,4,7,8 HxCDD 0.0345 0.0271 0.035 0.1

1,2,3,6,7,8-HxCDD 414 ADL 377 ADL 473 ADL 1,2,3,6,7,8 HxCDD 0.414 0.377 0.473 1,2,3,6,7,8 HxCDD 0.0414 0.0377 0.0473 0.1

1,2,3,7,8,9-HxCDD 908 ADL 834 ADL 1050 ADL 1,2,3,7,8,9 HxCDD 0.908 0.834 1.05 1,2,3,7,8,9 HxCDD 0.0908 0.0834 0.105 0.1

1,2,3,4,6,7,8-HpCDD 4150 ADL 3360 ADL 5870 ADL 1,2,3,4,6,7,8 HpCDD 4.15 3.36 5.87 1,2,3,4,6,7,8 HpCDD 0.0415 0.0336 0.0587 0.01

OCDD 39300 ADL 32400 ADL 43400 ADL Total OCDD 39.3 32.4 43.4 Total OCDD 0.0118 0.0097 0.013 0.0003

Total CDD congeners 46.59 38.766 53.174 Total CDD congeners 1.693 1.7155 2.29

Measured wt, ng TEQ, ng

2,3,7,8-TCDF 13.8 ADL 7.6 BDL 12.3 ADL 2,3,7,8 TCDF 0.0138 0.0076 0.0123 2,3,7,8 TCDF 0.0014 0.0008 0.0012 0.1

1,2,3,7,8-PeCDF 4.7 BDL 7.52 ADL 4.6 BDL 1,2,3,7,8 PeCDF 0.0047 0.00752 0.0046 1,2,3,7,8 PeCDF 0.0001 0.0002 0.0001 0.03

2,3,4,7,8-PeCDF 5.1 BDL 7.26 ADL 8.42 ADL 2,3,4,7,8 PeCDF 0.0051 0.00726 0.00842 2,3,4,7,8 PeCDF 0.0015 0.0022 0.0025 0.3

1,2,3,4,7,8-HxCDF 2.7 BDL 2.5 BDL 1.7 BDL 1,2,3,4,7,8 HxCDF 0.0027 0.0025 0.0017 1,2,3,4,7,8 HxCDF 0.0003 0.0003 0.0002 0.1

1,2,3,6,7,8-HxCDF 4.6 BDL 5.5 BDL 4.1 BDL 1,2,3,6,7,8 HxCDF 0.0046 0.0055 0.0041 1,2,3,6,7,8 HxCDF 0.0005 0.0006 0.0004 0.1

2,3,4,6,7,8-HxCDF 2 BDL 2.67 ADL 2.1 BDL 2,3,4,6,7,8 HxCDF 0.002 0.00267 0.0021 2,3,4,6,7,8 HxCDF 0.0002 0.0003 0.0002 0.1

1,2,3,7,8,9-HxCDF 1.4 BDL 2.27 ADL 0.99 BDL 1,2,3,7,8,9 HxCDF 0.0014 0.00227 0.00099 1,2,3,7,8,9 HxCDF 0.0001 0.0002 1E-04 0.1

1,2,3,4,6,7,8-HpCDF 5.7 BDL 5.9 BDL 4.5 BDL 1,2,3,4,6,7,8 HpCDF 0.0057 0.0059 0.0045 1,2,3,4,6,7,8 HpCDF 6E-05 6E-05 5E-05 0.01

1,2,3,4,7,8,9-HpCDF 1.9 BDL 2 BDL 0.66 BDL 1,2,3,4,7,8,9 HpCDF 0.0019 0.002 0.00066 1,2,3,4,7,8,9 HpCDF 2E-05 2E-05 7E-06 0.01

OCDF 7.8 BDL 3.8 BDL 6.1 BDL Total OCDF 0.0078 0.0038 0.0061 Total OCDF 2E-06 1E-06 2E-06 0.0003

Total CDF congeners 0.0497 0.04702 0.04547 Total CDF congeners 0.0042 0.0045 0.0048

TOTAL CDD/CDF 46.6397 38.813 53.2195 TOTAL CDD/CDF (TEQ) ###### ###### ######

Run 1 Run 2 Run 3

Run 1 Run 2 Run 3

09000064819365ee Sample 12/1/2014