# Mo**nitor:** Broad Street

**AI RS:**  421010047

**Year Quarter**  **FRM Mass Blank Mass**  **Non-B Mass Sulfate**  Average 1 12.6 0.5 12.1 2.8 Average 2 13.0 0.5 12.5 5.0 Average 3 13.2 0.5 12.7 6.0 Average 4 12.2 0.5 11.7 3.2



# H2O A**dvanced (Low acidity** **)**

**Quarter S Term**  **N Term A** **Term Part 1**  1 0.4142 0.3427 0.2431 -20872.7206 2 0.6815 0.0614 0.2571 -22320.5337 3 0.7492 0.0015 0.2493 -21411.6157 4 0.4808 0.2685 0.2506 -21686.5381 

# Relative Composition (%**)**

**Year Quarter**  **Sulfate** Average 1 0.2300 Average 2 0.4004 Average 3 0.4736 Average 4 0.2687



# FRM**Speciation**

**Year Quarter**  **FRM Mass Blank Mass**  **Non-B Mass Sulfate**  Average 1 16.59 0.5 16.1 3.70 Average 2 16.45 0.5 16.0 6.39 Average 3 15.80 0.5 15.3 7.25 Average 4 15.37 0.5 14.9 3.99



# RRFs

**Year Quarter**  **Blank Mass Sulfate**  Average 1 1.0 0.942937887 Average 2 1.0 0.727183908 Average 3 1.0 0.661878738 Average 4 1.0 0.904348218 

# Future PM 2.5 - Version 4 (Original and Modeled NH4 by **DON; High A cidity** 

**Water)**

**Year Quarter**  **FRM Mass Blank Mass**  **Non-B Mass Sulfate**  Average 1 15.45 0.5 14.9 3.5 Average 2 13.08 0.5 12.6 4.6 Average 3 11.44 0.5 10.9 4.8 Average 4 14.17 0.5 13.7 3.6 **Total** 13.5



# H2O A**dvanced (Low acidity** **) Quarter**  **S Term N Term**  **A Term**  **Part 1** 1 0.4234 0.3335 0.2431 -20870.1404 2 0.6803 0.0628 0.2569 -22305.3054 3 0.7490 0.0019 0.2491 -21389.2875 4 0.4815 0.2678 0.2507 -21690.3036**Nitrate OC**  **EC Wa** **ter Am** **monium Crustal**  **DON** 2.3 3.0 0.7 1.3 1.6 0.3 0.35 0.4 1.7 0.7 2.1 1.9 0.6 0.35 0.0 0.8 0.7 2.5 2.0 0.6 0.33 1.8 2.3 1.1 1.4 1.6 0.4 0.36

**Part 2 Part 3**  **Sum Total**  19516.3549 1356.5594 0.1936 1.2985 20744.8648 1575.9620 0.2931 2.1442 19984.0517 1427.8804 0.3164 2.5316 20206.4610 1480.2833 0.2062 1.3516

**Nitrate OC**  **EC Wa** **ter Am** **monium Crustal**  **DON** SUM 0.1903 0.2483 0.0602 0.1075 0.1350 0.0287 1.0 0.0361 0.1352 0.0584 0.1722 0.1510 0.0467 1.0 0.0010 0.0661 0.0556 0.2000 0.1576 0.0461 1.0 0.1500 0.1985 0.0903 0.1152 0.1400 0.0372 1.0

**Nitrate OC**  **EC Wa** **ter Am** **monium Crustal**  **DON** 3.06 3.99 0.97 1.73 2.17 0.46 0.35 0.58 2.16 0.93 2.75 2.41 0.74 0.35 0.01 1.01 0.85 3.06 2.41 0.71 0.33 2.23 2.95 1.34 1.71 2.08 0.55 0.36

**Nitrate OC**  **EC Wa** **ter Am** **monium Crustal**  **DON** 0.8976 0.9514 0.8171 0.9228 1.0988 1.0 0.7450 0.9867 0.8083 0.7561 1.1700 1.0 0.8218 0.9875 0.7927 0.7457 1.1869 1.0 0.9008 0.9848 0.8058 0.9264 1.1433 1.0 

# Future PM 2.5 - Version 4 (Original and Modeled NH4 by **DON; High A cidity** 

**Water)**

**Nitrate OC**  **EC Wa** **ter Am** **monium Crustal**  **DON** 2.7 3.8 0.8 1.6 2.0 0.5 0.35 0.4 2.1 0.8 2.0 1.8 0.9 0.35 0.0 1.0 0.7 2.0 1.6 0.8 0.33 2.0 2.9 1.1 1.5 1.9 0.6 0.36**Part 2 Part 3**  **Sum Total** 

19514.4224 1355.9130 0.1950 1.6067 20732.1011 1573.4968 0.2925 1.9973 19965.1818 1424.4217 0.3159 2.0232 20209.6494 1480.8606 0.2064 1.5486

# Mo**nitor:**Broad Street

**AI RS:**  421010047

**Year Quarter**  **FRM Mass Year**  **Quarter FRM Mass** 

2000 1 16.3 2000-02 1 17.14

2000 2 19.0 2000-02 2 17.15

2000 3 15.4 2000-02 3 15.83

2000 4 17.9 2000-02 4 16.15

2001 1 19.7 2001-03 1 17.22

2001 2 17.3 2001-03 2 16.43

2001 3 16.3 2001-03 3 15.95

2001 4 14.7 2001-03 4 15.31

2002 1 15.5 2002-04 1 15.40

2002 2 15.1 2002-04 2 15.78

2002 3 15.8 2002-04 3 15.62

2002 4 15.9 2002-04 4 14.65

2003 1 16.5

2003 2 16.8 Average 1 16.59

2003 3 15.8 Average 2 16.45

2003 4 15.4 Average 3 15.80

2004 1 14.2 Average 4 15.37

2004 2 15.4

2004 3 15.3

2004 4 12.7

Average 1 16.43 Average 2 16.73 Average 3 15.71 Average 4 15.30

## Speciation: Elmwood

**AI RS:**  421010136

**Year Quarter**  **FRM Mass Blank Mass**  **Non-B Mass Sulfate**  **Nitrate** 2002 1 2002 2 13.6 0.5 13.1 5.3 0.0 2002 3 15.6 0.5 15.1 6.6 0.0 2002 4 13.5 0.5 13.0 3.6 2.4 2003 1 13.8 0.5 13.3 3.4 3.1 2003 2 13.2 0.5 12.7 4.5 0.8 2003 3 13.9 0.5 13.4 6.5 0.0 2003 4 12.3 0.5 11.8 2.9 1.5 2004 1 11.3 0.5 10.8 2.2 1.5 2004 2 12.0 0.5 11.5 5.1 0.6 2004 3 10.0 0.5 9.5 4.9 0.0 2004 4 10.9 0.5 10.4 2.9 1.4

Average 1 12.6 0.5 12.1 2.8 2.3 Average 2 13.0 0.5 12.5 5.0 0.4 Average 3 13.2 0.5 12.7 6.0 0.0 Average 4 12.2 0.5 11.7 3.2 1.8

0.356364406 0.061671478 0.439706862 0.048767488**OC EC**  **Wa ter**  **Am monium**  **Crustal DON**  Ammonium 2New OC 2

2.3 0.8 1.8 2.2 0.6 0.3 1.8 2.7 2.7 0.8 2.1 2.3 0.5 0.33 2.2 2.9 2.2 1.0 1.2 2.2 0.3 0.36 2.0 2.4 2.2 0.8 1.2 2.3 0.4 0.35 2.1 2.5 2.5 0.8 1.5 2.0 0.6 0.34 1.8 2.7 0.7 0.7 2.2 2.5 0.8 0.33 2.2 1.1 2.8 1.2 1.0 1.7 0.6 0.36 1.5 3.1 4.1 0.6 0.7 1.3 0.3 0.34 1.2 4.2 0.8 0.6 1.6 2.4 0.6 0.37 2.0 1.2 0.1 0.7 1.6 1.8 0.5 0.33 1.6 0.3 2.2 1.0 0.9 1.8 0.4 0.36 1.4 2.5

3.2 0.7 1.0 1.8 0.3 0.35 1.6 3.3 1.9 0.7 1.6 2.2 0.6 0.35 1.9 2.2 1.2 0.7 2.0 2.2 0.6 0.33 2.0 1.4 2.4 1.1 1.0 1.9 0.4 0.36 1.6 2.7

0.195852291 0.061611016 0.121287241 0.157866892 0.045346675 0.07041972 0.047901399 0.137841439 0.206862092 0.048500999**Date FRM**  **SO4 NO3**  **EC H2O**  **NH4 Crustal**  **OC**

1/2/2002 1/8/2002 1/14/2002 1/20/2002 1/26/2002 2/1/2002 2/7/2002 2/13/2002 2/19/2002 2/25/2002 3/3/2002 3/9/2002 3/15/2002 3/21/2002 3/27/2002 4/2/2002 4/8/2002 12 4.7 0 0.77 1.68 2.18 0.81 3.36 4/14/2002 8.7 3.06 0 0.5 1.1 1.36 0.84 2.6 4/20/2002 12.7 4.06 0 1.2 1.45 2.16 1.1 3.78 4/26/2002 3.47 0 0.97 1.24 2.04 0.47 3.82 5/2/2002 19.7 6.2 0 1.09 2.22 2.4 1.26 4.84 5/8/2002 3.99 0 0.96 1.43 1.52 0.34 3.62 5/14/2002 6.3 2.87 0 0.3 1.06 1.04 0.23 1.91 5/20/2002 6.8 3.14 0 0.6 1.07 1.23 0.2 2.11 5/26/2002 16 6.81 0 0.99 2.31 2.69 0.59 5.17 6/1/2002 14.7 5.57 0 0.54 1.85 2.2 0.47 6.4 6/7/2002 5.1 0.35 0 0.07 0.33 0.01 0.08 1.77 6/13/2002 10.7 4.77 0 1.38 1.57 1.98 0.32 3.22 6/19/2002 16.9 7.25 0 1.56 2.41 3.46 0.58 5.2 6/25/2002 33.4 18.6 0 0.88 5.47 6.81 1.21 7.8 7/1/2002 21.7 5.51 0 1.07 2.05 1.95 0.47 7.12 7/7/2002 7/13/2002 10.1 2.62 0 0.79 0.97 0.93 0.34 4.79 7/19/2002 57.3 31.8 0 1.03 9.7 11.4 2.22 10.5 7/25/2002 7/31/2002 12 3.14 0 0.91 0.82 0.88 0.55 6.68 8/6/2002 7.1 2.5 0 0.4 0.58 0.77 0.37 6.23 8/12/2002 28 12.3 0 1.15 4.1 4.05 0.66 7.87 8/18/2002 19.2 8.69 0 0.56 3.04 3.35 0.3 5.35 8/24/2002 12.8 5.35 0 1.3 1.92 2.02 0.23 3.37 8/30/2002 3.4 1.57 0 0.7 0.36 0.47 0.17 2.34 9/5/2002 7.4 2.39 0 0.57 0.72 0.71 0.22 4.19 9/11/2002 9.5 4.33 0 0.49 1.53 1.5 0.21 3.34 9/17/2002 12 4.09 0 0.92 1.47 1.65 0.27 4.27 9/23/2002 6.5 3.06 0 0.53 0.99 0.99 0.24 2.37 9/29/2002 10.8 4.92 0 0.66 1.49 2.19 0.23 5.06 10/5/2002 16.5 8.28 0 0.3 2.99 2.86 0.28 3.75 10/11/2002 4.4 1.15 0 1.02 0.28 0.33 0.39 3.34 10/17/2002 10/23/2002 14.4 3.39 2.13 1.15 1.01 2.38 0.58 4.34 10/29/2002 9.4 2.18 0.72 1.2 0.69 1.03 0.31 3.4 11/4/2002 3.86 2.44 1.05 1.16 2.64 0.32 4.48 11/10/2002 11.9 3.91 0 0.71 1.4 1.7 0.24 3.81 11/16/2002 15 2.96 2.06 1.36 0.89 1.83 0.3 5.86 11/22/2002 13.4 3.76 2.82 1.72 1.08 2.26 0.17 4.05 11/28/2002 10.8 2.31 3.85 0.6 0.9 1.93 0.16 3.26 12/4/2002 11.7 2.09 3.62 0.47 0.87 1.84 0.32 2.91 12/10/2002 28.2 4.98 10.13 2.51 1.83 5.1 0.44 10.112/16/2002 7.2 2.15 0.16 0.62 0.75 1.01 0.19 2.74

12/22/2002 12/28/2002 19.1 6.09 3.58 0.78 1.83 3.4 0.34 3.91 1/3/2003 7.3 2.22 1.2 0.66 0.58 0.93 0.28 2.69 1/9/2003 14.3 1.43 0 1.52 0.51 0.74 0.76 6.32 1/15/2003 2.65 7.29 0.42 1.56 3.17 0.31 3.2 1/21/2003 9.3 2.15 2.64 0.48 0.77 1.48 0.18 2.69 1/27/2003 6.1 1.43 1.01 0.58 0.41 0.7 0.2 2.46 2/2/2003 10.8 4.43 0.82 0.58 1.49 2.15 0.29 2.15 2/8/2003 16.5 3.23 5.48 0.74 1.33 2.8 0.29 4.25 2/14/2003 19.9 2.66 8.27 1.09 1.6 3.48 0.42 5.48 2/20/2003 34.1 8.48 7.65 1.64 2.63 5.95 0.35 7.91 2/26/2003 12.7 3.23 2.77 0.82 1.01 2 0.37 3.25 3/4/2003 3/10/2003 2.68 2.03 0.5 0.81 1.6 0.21 2.55 3/16/2003 3/22/2003 11.3 5.77 0.36 0.78 1.81 3.31 0.27 2.51 3/28/2003 9.8 3.22 0.19 0.95 1.13 1.41 0.73 3.02 4/3/2003 4/9/2003 11.2 3.05 2.75 0.7 0.99 1.83 0.13 2.44 4/15/2003 14.14 5.83 0 0.77 2.09 2.24 1.13 4.8 4/21/2003 7.41 2.13 0 0.79 0.77 0.71 0.49 2.81 4/27/2003 2.65 0 0.75 0.95 1.14 0.62 3.66 5/3/2003 1.61 0 0.47 0.44 0.46 0.56 2.81 5/9/2003 24.28 7.54 5.19 1.23 2.26 4.4 0.51 4.62 5/15/2003 12.1 2.53 0 1.38 0.85 0.8 0.74 4.71 5/21/2003 11.5 2.31 0 1.01 0.83 1.07 0.68 4.31 5/27/2003 2.66 0 0.77 0.95 1.44 0.69 4.2 6/2/2003 1.33 0 0.34 0.39 0.39 0.36 3.64 6/8/2003 14.43 8.73 1.21 0.55 2.99 3.94 0.56 2.81 6/14/2003 11 0 0.55 3.94 4.85 0.42 4.27 6/20/2003 10.72 7.57 1.05 0.88 2.61 2.84 0.61 3.83 6/26/2003 7/2/2003 19.89 8.21 0 0.84 2.94 3.58 0.76 4.94 7/8/2003 16.47 6.99 0 0.52 2.58 2.55 1.42 3.99 7/14/2003 13.1 4.33 0 0.81 1.55 1.7 0.9 5.03 7/20/2003 7.38 0 0.42 2.74 2.63 0.51 7.27 7/26/2003 10.2 0 0.61 3.65 4.16 0.82 6.48 8/1/2003 18.64 10.7 0 0.71 3.83 4.39 1.18 3.79 8/7/2003 17.1 7.83 0.59 1.22 2.48 3.6 1 4.11 8/13/2003 35.6 22.6 0 0.95 6.46 8.38 1.02 5.44 8/19/2003 13.09 3.82 0 0.57 1.37 1.57 0.5 4.89 8/25/2003 16.97 7.26 0 0.79 2.53 2.35 0.82 5.14 8/31/2003 6.75 2.1 0 0.32 0.77 0.72 0.24 4.31 9/6/2003 4.55 0.87 0 0.48 0.37 0.14 0.28 3.63 9/12/2003 6.09 1.36 0 0.44 0.31 0.28 0.82 2.76 9/18/2003 7.67 2.02 0 0.55 0.58 0.59 0.73 3.01 9/24/2003 11.09 5.08 0 0.75 1.82 1.96 0.71 3.46 9/30/2003 7.34 2.98 0 0.62 1.07 1.31 0.8 2.74 10/6/2003 11.13 3.59 0 1.06 1.29 1.44 0.55 4.04 10/12/2003 10.42 4.17 0 0.42 1.54 1.52 0.38 3.9 10/18/2003 7.92 2.59 1.4 0.67 0.78 1.82 0.29 3.57 10/24/2003 8.93 2.63 0 1.12 0.94 1.31 0.67 4.64 10/30/2003 9.8 3.3 0 1.19 1.18 1.51 0.85 3.85 11/5/2003 9.67 3.37 2 1.69 1.04 1.82 0.76 3.66 11/11/2003 16.43 2.83 1.02 2.08 0.89 1.94 1.15 6.33 11/17/2003 22.6 4.35 4.45 1.91 1.39 3.14 0.81 7.19 11/23/2003 19.72 2.89 4.87 1.02 1.18 2.75 0.86 5.88 11/29/2003 4.9 1.87 0 0.35 0.67 0.87 0.15 1.4412/5/2003 15 2.55 2.89 1.11 0.88 1.61 0.61 4.18

12/11/2003 4.4 1.73 0 0.43 0.53 0.52 0.17 1.29 12/17/2003 11.1 2.82 1.59 0.98 0.85 1.61 0.34 2.57 12/23/2003 12.9 2.27 0 1.62 0.81 1.25 1.02 5.2 12/29/2003 19.6 3.08 4.36 1.83 1.13 2.63 0.93 6.25 1/4/2004 20.4 2.87 1.73 1.36 0.86 1.83 0.73 5.12 1/10/2004 5.2 1.01 0.89 0.32 0.32 0.51 0.14 2.98 1/16/2004 0.77 0.47 0.12 0.26 0.28 0.14 1.39 1/22/2004 16.3 2.45 3.57 0.94 0.92 2.11 0.57 3.56 1/28/2004 12 2.93 2.79 0.6 0.96 1.86 0.23 2.36 2/3/2004 13.1 2.19 2.99 1.01 0.83 1.59 0.38 3.48 2/9/2004 12.8 2.71 1.77 0.83 0.81 1.58 0.65 3.54 2/15/2004 12.5 2.08 2.37 0.52 0.69 1.48 0.27 2.81 2/21/2004 16 4.18 3.49 0.68 1.28 2.86 0.25 2.79 2/27/2004 4.6 0.9 0 0.52 0.32 0.51 0.49 2.33 3/4/2004 3/10/2004 9.5 2.89 0.86 0.56 0.93 1.4 0.23 2.58 3/16/2004 8.9 2.43 0.66 0.58 0.81 1.02 0.23 1.84 3/22/2004 4.6 1.6 0 0.43 0.57 0.65 0.23 2.03 3/28/2004 1.82 0 0.29 0.65 0.72 0.16 2.31 4/3/2004 12.7 4.19 1.45 0.59 1.33 2.16 0.33 2.58 4/9/2004 15.8 3.99 2.49 0.66 1.19 2.87 0.49 3.11 4/15/2004 4.1 1.24 0 0.28 0.46 0.45 0.31 1.53 4/21/2004 6.8 2.08 0 0.44 0.75 0.84 1.04 2.6 4/27/2004 11.1 4.01 0 0.47 1.44 2.31 0.56 1.96 5/3/2004 5 1.86 0 0.53 0.67 0.76 0.17 2 5/9/2004 14.9 6.22 0 0.48 2.23 2.49 0.9 4.12 5/15/2004 18.5 6.75 0 0.46 2.42 2.55 1.15 4.4 5/21/2004 20.3 13 3.38 1.15 2.79 7.3 0.43 4.62 5/27/2004 11.7 6.47 0 0.81 1.78 3.47 0.55 4.35 6/2/2004 6/8/2004 6/14/2004 11.8 5.55 0 0.62 1.84 2.02 0.85 3.57 6/20/2004 4.8 1.45 0 0.12 0.54 0.52 0.19 3.16 6/26/2004 19.1 9.19 0 0.58 3.25 3.31 0.31 5 7/2/2004 24.8 13.7 0 0.91 4.21 4.93 0.55 6 7/8/2004 15.8 9.6 0 0.51 2.73 3.84 0.33 4.18 7/14/2004 10.5 5.42 0 0.88 1.58 2.02 0.7 3.53 7/20/2004 8.65 0 0.62 3.1 3.35 1.04 5.38 7/26/2004 7.9 1.69 0 0.75 0.62 0.58 0.97 4.41 8/1/2004 3.7 1.42 0 0.32 0.43 0.46 0.19 2.66 8/7/2004 4.1 1.09 0 0.46 0.35 0.34 0.18 2.6 8/13/2004 10 5.13 0 0.66 1.63 1.66 0.3 2.76 8/19/2004 20 10.2 0 0.86 3.25 3.78 0.52 5.34 8/25/2004 7 2.37 0 0.61 0.87 0.87 0.51 3.24 8/31/2004 7.5 4.26 0 0.31 1.24 1.43 0.41 2.6 9/6/2004 3.4 1.14 0 0.25 0.25 0.24 0.29 2.32 9/12/2004 8.6 4 0 0.49 1.27 1.45 0.55 3.57 9/18/2004 2.4 0.89 0 0.39 0.34 0.13 0.11 2.14 9/24/2004 13.4 4.47 0 1.26 1.6 2.01 0.67 4.7 9/30/2004 11.4 4.55 0 1.21 1.56 2.03 0.77 3.66 10/6/2004 5.9 1.94 0 0.63 0.64 0.94 0.36 3.73 10/12/2004 3.5 1.34 0 0.47 0.42 0.48 0.17 2.4 10/18/2004 8.2 3.43 0 0.71 1.21 1.51 0.27 2.85 10/24/2004 7.2 2.95 0 0.55 1.02 1.23 0.27 2.97 10/30/2004 20.8 8.24 4.47 0.76 2.07 5.17 0.24 5.78 11/5/2004 2.9 1.11 0 0.74 0.31 0.51 0.11 2.12 11/11/2004 14.5 3.07 1.66 1.68 0.81 2.32 0.67 7.57 11/17/2004 16.3 3.47 2.1 2.25 0.97 2.64 0.74 6.911/23/2004 18 4.69 3.84 1.44 1.43 3.68 0.68 4.1

11/29/2004 5.9 1.46 0 1.02 0.53 0.54 0.36 3.25 12/5/2004 15.3 2.77 2.39 1.01 0.85 2.34 0.3 4.75 12/11/2004 9.4 2.07 2.62 0.82 0.74 1.51 0.22 2.65 12/17/2004 18.5 2.27 1.84 1.15 0.69 1.57 0.44 4.18 12/23/2004 6.1 1.73 0 0.43 0.36 0.44 0.26 2.11 12/29/2004**Flag DON** 

0 0.37 0 0.37 0 0.37 0 0.37 0 0.37 0 0.37 0 0.36 0 0.37 0 0.37 0 0.37 0 0.02 0 0.37 0 0.37 0 0.36 0 0.35 4 0 0.35 0 0.35 2 0 0.28 0 0.3 0 0.32 0 0.37 0 0.37 0 0.29 0 0.29 0 0.34 0 0.37 0 0.32 0 0.37 0 0.34 0 0.28 2 0 0.37 0 0.37 0 0.37 0 0.37 0 0.37 0 0.37 0 0.35 0 0.37 0 0.370 0.37

0 0.37 0 0.26 0 0.37 0 0.37 0 0.33 0 0.28 0 0.37 0 0.37 0 0.37 0 0.37 0 0.37

0 0.37

0 0.37 0 0.37

0 0.33 0 0.37 0 0.33 0 0.37 0 0.28 0 0.37 0 0.31 0 0.37 0 0.37 0 0.29 0 0.37 0 0.37 0 0.33

0 0.37 0 0.36 0 0.37 0 0.35 0 0.37 0 0.37 0 0.37 0 0.37 0 0.37 0 0.32 0 0.34 0 0.15 0 0.2 0 0.29 0 0.37 0 0.37 0 0.37 0 0.36 0 0.37 0 0.37 0 0.37 0 0.36 0 0.37 0 0.37 0 0.37 0 0.370 0.3

0 0.3 0 0.37 0 0.37 0 0.37 0 0.37 0 0.24 0 0.18 0 0.37 0 0.35 0 0.32 0 0.37 0 0.37 0 0.37 0 0.37 2 0 0.37 0 0.34 0 0.37 0 0.37 0 0.37 0 0.37 0 0.36 0 0.37 0 0.37 0 0.37 0 0.37 0 0.37 0 0.37 0 0.37

0 0.36 0 0.35 0 0.36 0 0.36 0 0.37 0 0.37 0 0.37 0 0.34 0 0.32 0 0.3 0 0.32 0 0.37 0 0.36 0 0.33 0 0.2 0 0.36 0 0.14 0 0.37 0 0.37 0 0.37 0 0.35 0 0.37 0 0.37 0 0.37 0 0.37 0 0.37 0 0.370 0.37

0 0.37 0 0.37 0 0.36 0 0.37 0 0.25Date _id lat long _TYPE DATE NH4-adj **SO4 NO3R** **NH4** 4/8/02 421010136 39.92 -75.22STN 20020408 1.739 **4.7 0** **2.18** 4/14/02 421010136 39.92 -75.22STN 20020414 1.1322 **3.06 0**  **1.36** 4/20/02 421010136 39.92 -75.22STN 20020420 1.5022 **4.06 0** **2.16** 4/26/02 421010136 39.92 -75.22STN 20020426 1.2839 **3.47 0** **2.04** 5/2/02 421010136 39.92 -75.22STN 20020502 2.294 **6.2 0**  **2.4** 5/8/02 421010136 39.92 -75.22STN 20020508 1.4763 **3.99 0**  **1.52** 5/14/02 421010136 39.92 -75.22STN 20020514 1.0332 **2.87 0**  **1.04** 5/20/02 421010136 39.92 -75.22STN 20020520 1.1618 **3.14 0**  **1.23** 5/26/02 421010136 39.92 -75.22STN 20020526 2.5197 **6.81 0** **2.69** 6/1/02 421010136 39.92 -75.22STN 20020601 2.0609 **5.57 0**  **2.2** 6/7/02 421010136 39.92 -75.22STN 20020607 0.007 **0.35 0**  **0.01** 6/13/02 421010136 39.92 -75.22STN 20020613 1.7649 **4.77 0**  **1.98** 6/19/02 421010136 39.92 -75.22STN 20020619 2.6825 **7.25 0** **3.46** 6/25/02 421010136 39.92 -75.22STN 20020625 6.696 **18.6 0**  **6.81** 7/1/02 421010136 39.92 -75.22STN 20020701 1.9285 **5.51 0**  **1.95** 7/7/02 421010136 39.92 -75.22STN 20020707 1.221 **3.3 0** **2.08** 7/13/02 421010136 39.92 -75.22STN 20020713 0.917 **2.62 0**  **0.93** 7/19/02 421010136 39.92 -75.22STN 20020719 11.13 **31.8 0**  **11.4** 7/25/02 421010136 39.92 -75.22STN 20020725 0.0085 **0.05 0**  **0.01** 7/31/02 421010136 39.92 -75.22STN 20020731 0.8792 **3.14 0**  **0.88** 8/6/02 421010136 39.92 -75.22STN 20020806 0.75 **2.5 0**  **0.77** 8/12/02 421010136 39.92 -75.22STN 20020812 3.936 **12.3 0** **4.05** 8/18/02 421010136 39.92 -75.22STN 20020818 3.2153 **8.69 0** **3.35** 8/24/02 421010136 39.92 -75.22STN 20020824 1.9795 **5.35 0** **2.02** 8/30/02 421010136 39.92 -75.22STN 20020830 0.4553 **1.57 0**  **0.47** 9/5/02 421010136 39.92 -75.22STN 20020905 0.6931 **2.39 0**  **0.71** 9/11/02 421010136 39.92 -75.22STN 20020911 1.4722 **4.33 0**  **1.5** 9/17/02 421010136 39.92 -75.22STN 20020917 1.5133 **4.09 0**  **1.65** 9/23/02 421010136 39.92 -75.22STN 20020923 0.9792 **3.06 0**  **0.99** 9/29/02 421010136 39.92 -75.22STN 20020929 1.8204 **4.92 0** **2.19** 10/5/02 421010136 39.92 -75.22STN 20021005 2.8152 **8.28 0** **2.86** 10/11/02 421010136 39.92 -75.22STN 20021011 0.322 **1.15 0**  **0.33** 10/17/02 421010136 39.92 -75.22STN 20021017 1.2583 **3.15 0.32**  **1.64** 10/23/02 421010136 39.92 -75.22STN 20021023 1.872 **3.39 2.13** **2.38** 10/29/02 421010136 39.92 -75.22STN 20021029 1.0154 **2.18 0.72**  **1.03** 11/4/02 421010136 39.92 -75.22STN 20021104 2.1358 **3.86 2.44** **2.64** 11/10/02 421010136 39.92 -75.22STN 20021110 1.4467 **3.91 0**  **1.7** 11/16/02 421010136 39.92 -75.22STN 20021116 1.6926 **2.96 2.06**  **1.83** 11/22/02 421010136 39.92 -75.22STN 20021122 2.209 **3.76 2.82** **2.26** 11/28/02 421010136 39.92 -75.22STN 20021128 1.925 **2.31 3.85**  **1.93** 12/4/02 421010136 39.92 -75.22STN 20021204 1.8231 **2.09 3.62**  **1.84** 12/10/02 421010136 39.92 -75.22STN 20021210 4.7803 **4.98 10.13**  **5.1** 12/16/02 421010136 39.92 -75.22STN 20021216 0.8419 **2.15 0.16**  **1.01** 12/28/02 421010136 39.92 -75.22STN 20021228 3.2915 **6.09 3.58**  **3.4** 1/3/03 421010136 39.92 -75.22STN 20030103 0.9252 **2.22 1.2**  **0.93** 1/9/03 421010136 39.92 -75.22STN 20030109 0.5291 **1.43 0**  **0.74** 1/15/03 421010136 39.92 -75.22STN 20030115 3.0946 **2.65 7.29** **3.17** 1/21/03 421010136 39.92 -75.22STN 20030121 1.4751 **2.15 2.64**  **1.48** 1/27/03 421010136 39.92 -75.22STN 20030127 0.6933 **1.43 1.01**  **0.7** 2/2/03 421010136 39.92 -75.22STN 20030202 1.8769 **4.43 0.82** **2.15** 2/8/03 421010136 39.92 -75.22STN 20030208 2.7843 **3.23 5.48**  **2.8** 2/14/03 421010136 39.92 -75.22STN 20030214 3.3825 **2.66 8.27** **3.48** 2/20/03 421010136 39.92 -75.22STN 20030220 5.3561 **8.48 7.65** **5.95** 2/26/03 421010136 39.92 -75.22STN 20030226 1.9984 **3.23 2.77**  **2** 3/10/03 421010136 39.92 -75.22STN 20030310 1.5803 **2.68 2.03**  **1.6** 3/17/03 421010136 39.92 -75.22STN 20030317 0.6475 **1.75 0**  **0.9** 3/22/03 421010136 39.92 -75.22STN 20030322 2.2393 **5.77 0.36** **3.31** 3/28/03 421010136 39.92 -75.22STN 20030328 1.2465 **3.22 0.19**  **1.41**4/4/03 421010136 39.92 -75.22STN 20030404 2.0853 **4.86 0.99** **2.15** 4/9/03 421010136 39.92 -75.22STN 20030409 1.804 **3.05 2.75**  **1.83** 4/15/03 421010136 39.92 -75.22STN 20030415 2.1571 **5.83 0** **2.24** 4/21/03 421010136 39.92 -75.22STN 20030421 0.7029 **2.13 0**  **0.71** 4/27/03 421010136 39.92 -75.22STN 20030427 0.9805 **2.65 0**  **1.14** 5/3/03 421010136 39.92 -75.22STN 20030503 0.4508 **1.61 0**  **0.46** 5/9/03 421010136 39.92 -75.22STN 20030509 4.2949 **7.54 5.19**  **4.4** 5/15/03 421010136 39.92 -75.22STN 20030515 0.7843 **2.53 0**  **0.8** 5/21/03 421010136 39.92 -75.22STN 20030521 0.8547 **2.31 0**  **1.07** 5/27/03 421010136 39.92 -75.22STN 20030527 0.9842 **2.66 0**  **1.44** 6/2/03 421010136 39.92 -75.22STN 20030602 0.3857 **1.33 0**  **0.39** 6/8/03 421010136 39.92 -75.22STN 20030608 3.581 **8.73 1.21**  **3.94** 6/14/03 421010136 39.92 -75.22STN 20030614 4.07 **11 0** **4.85** 6/20/03 421010136 39.92 -75.22STN 20030620 2.8026 **7.57 1.05** **2.84** 7/2/03 421010136 39.92 -75.22STN 20030702 3.0377 **8.21 0** **3.58** 7/8/03 421010136 39.92 -75.22STN 20030708 2.5164 **6.99 0** **2.55** 7/14/03 421010136 39.92 -75.22STN 20030714 1.6021 **4.33 0**  **1.7** 7/20/03 421010136 39.92 -75.22STN 20030720 2.583 **7.38 0** **2.63** 7/26/03 421010136 39.92 -75.22STN 20030726 3.774 **10.2 0** **4.16** 8/1/03 421010136 39.92 -75.22STN 20030801 3.959 **10.7 0** **4.39** 8/7/03 421010136 39.92 -75.22STN 20030807 3.0682 **7.83 0.59**  **3.6** 8/13/03 421010136 39.92 -75.22STN 20030813 8.362 **22.6 0**  **8.38** 8/19/03 421010136 39.92 -75.22STN 20030819 1.4134 **3.82 0**  **1.57** 8/25/03 421010136 39.92 -75.22STN 20030825 2.3232 **7.26 0** **2.35** 8/31/03 421010136 39.92 -75.22STN 20030831 0.714 **2.1 0**  **0.72** 9/6/03 421010136 39.92 -75.22STN 20030906 0.1305 **0.87 0**  **0.14** 9/12/03 421010136 39.92 -75.22STN 20030912 0.272 **1.36 0**  **0.28** 9/18/03 421010136 39.92 -75.22STN 20030918 0.5858 **2.02 0**  **0.59** 9/24/03 421010136 39.92 -75.22STN 20030924 1.8796 **5.08 0**  **1.96** 9/30/03 421010136 39.92 -75.22STN 20030930 1.1026 **2.98 0**  **1.31** 10/6/03 421010136 39.92 -75.22STN 20031006 1.3283 **3.59 0**  **1.44** 10/12/03 421010136 39.92 -75.22STN 20031012 1.5012 **4.17 0**  **1.52** 10/18/03 421010136 39.92 -75.22STN 20031018 1.3643 **2.59 1.4**  **1.82** 10/24/03 421010136 39.92 -75.22STN 20031024 0.9731 **2.63 0**  **1.31** 10/30/03 421010136 39.92 -75.22STN 20031030 1.221 **3.3 0**  **1.51** 11/5/03 421010136 39.92 -75.22STN 20031105 1.7932 **3.37 2**  **1.82** 11/11/03 421010136 39.92 -75.22STN 20031111 1.3429 **2.83 1.02**  **1.94** 11/17/03 421010136 39.92 -75.22STN 20031117 2.9 **4.35 4.45** **3.14** 11/23/03 421010136 39.92 -75.22STN 20031123 2.4816 **2.89 4.87** **2.75** 11/29/03 421010136 39.92 -75.22STN 20031129 0.6919 **1.87 0**  **0.87** 12/5/03 421010136 39.92 -75.22STN 20031205 1.6031 **2.55 2.89**  **1.61** 12/11/03 421010136 39.92 -75.22STN 20031211 0.519 **1.73 0**  **0.52** 12/17/03 421010136 39.92 -75.22STN 20031217 1.5045 **2.82 1.59**  **1.61** 12/23/03 421010136 39.92 -75.22STN 20031223 0.8399 **2.27 0**  **1.25** 12/29/03 421010136 39.92 -75.22STN 20031229 2.404 **3.08 4.36** **2.63** 1/4/04 421010136 39.92 -75.22STN 20040104 1.5636 **2.87 1.73**  **1.83** 1/10/04 421010136 39.92 -75.22STN 20040110 0.5005 **1.01 0.89** **0.51** 1/16/04 421010136 39.92 -75.22STN 20040116 0.2749 **0.77 0.47** **0.28** 1/22/04 421010136 39.92 -75.22STN 20040122 1.9418 **2.45 3.57** **2.11** 1/28/04 421010136 39.92 -75.22STN 20040128 1.8346 **2.93 2.79**  **1.86** 2/3/04 421010136 39.92 -75.22STN 20040203 1.5679 **2.19 2.99**  **1.59** 2/9/04 421010136 39.92 -75.22STN 20040209 1.516 **2.71 1.77**  **1.58** 2/15/04 421010136 39.92 -75.22STN 20040215 1.4569 **2.08 2.37**  **1.48** 2/21/04 421010136 39.92 -75.22STN 20040221 2.5587 **4.18 3.49** **2.86** 2/27/04 421010136 39.92 -75.22STN 20040227 0.333 **0.9 0**  **0.51** 3/4/04 421010136 39.92 -75.22STN 20040304 0 3/10/04 421010136 39.92 -75.22STN 20040310 1.3187 **2.89 0.86**  **1.4** 3/16/04 421010136 39.92 -75.22STN 20040316 1.0176 **2.43 0.66**  **1.02** 3/22/04 421010136 39.92 -75.22STN 20040322 0.592 **1.6 0**  **0.65**3/28/04 421010136 39.92 -75.22STN 20040328 0.6734 **1.82 0**  **0.72** 4/3/04 421010136 39.92 -75.22STN 20040403 1.9708 **4.19 1.45** **2.16** 4/9/04 421010136 39.92 -75.22STN 20040409 2.1984 **3.99 2.49** **2.87** 4/15/04 421010136 39.92 -75.22STN 20040415 0.4464 **1.24 0**  **0.45** 4/21/04 421010136 39.92 -75.22STN 20040421 0.7696 **2.08 0**  **0.84** 4/27/04 421010136 39.92 -75.22STN 20040427 1.4837 **4.01 0** **2.31** 5/3/04 421010136 39.92 -75.22STN 20040503 0.6882 **1.86 0**  **0.76** 5/9/04 421010136 39.92 -75.22STN 20040509 2.3014 **6.22 0** **2.49** 5/15/04 421010136 39.92 -75.22STN 20040515 2.4975 **6.75 0** **2.55** 5/21/04 421010136 39.92 -75.22STN 20040521 5.7902 **13 3.38**  **7.3** 5/27/04 421010136 39.92 -75.22STN 20040527 2.3939 **6.47 0** **3.47** 6/14/04 421010136 39.92 -75.22STN 20040614 1.998 **5.55 0** **2.02** 6/20/04 421010136 39.92 -75.22STN 20040620 0.5075 **1.45 0**  **0.52** 6/26/04 421010136 39.92 -75.22STN 20040626 3.3084 **9.19 0** **3.31** 7/2/04 421010136 39.92 -75.22STN 20040702 4.932 **13.7 0** **4.93** 7/8/04 421010136 39.92 -75.22STN 20040708 3.552 **9.6 0** **3.84** 7/14/04 421010136 39.92 -75.22STN 20040714 2.0054 **5.42 0** **2.02** 7/20/04 421010136 39.92 -75.22STN 20040720 3.2005 **8.65 0** **3.35** 7/26/04 421010136 39.92 -75.22STN 20040726 0.5746 **1.69 0**  **0.58** 8/1/04 421010136 39.92 -75.22STN 20040801 0.4544 **1.42 0**  **0.46** 8/7/04 421010136 39.92 -75.22STN 20040807 0.327 **1.09 0**  **0.34** 8/13/04 421010136 39.92 -75.22STN 20040813 1.6416 **5.13 0**  **1.66** 8/19/04 421010136 39.92 -75.22STN 20040819 3.774 **10.2 0** **3.78** 8/25/04 421010136 39.92 -75.22STN 20040825 0.8532 **2.37 0**  **0.87** 8/31/04 421010136 39.92 -75.22STN 20040831 1.4058 **4.26 0**  **1.43** 9/6/04 421010136 39.92 -75.22STN 20040906 0.228 **1.14 0**  **0.24** 9/12/04 421010136 39.92 -75.22STN 20040912 1.44 **4 0**  **1.45** 9/18/04 421010136 39.92 -75.22STN 20040918 0.1246 **0.89 0**  **0.13** 9/24/04 421010136 39.92 -75.22STN 20040924 1.6539 **4.47 0** **2.01** 9/30/04 421010136 39.92 -75.22STN 20040930 1.6835 **4.55 0** **2.03** 10/6/04 421010136 39.92 -75.22STN 20041006 0.7178 **1.94 0**  **0.94** 10/12/04 421010136 39.92 -75.22STN 20041012 0.469 **1.34 0**  **0.48** 10/18/04 421010136 39.92 -75.22STN 20041018 1.2691 **3.43 0**  **1.51** 10/24/04 421010136 39.92 -75.22STN 20041024 1.0915 **2.95 0**  **1.23** 10/30/04 421010136 39.92 -75.22STN 20041030 4.3451 **8.24 4.47** **5.17** 11/5/04 421010136 39.92 -75.22STN 20041105 0.4107 **1.11 0**  **0.51** 11/11/04 421010136 39.92 -75.22STN 20041111 1.6173 **3.07 1.66** **2.32** 11/17/04 421010136 39.92 -75.22STN 20041117 1.8929 **3.47 2.1**  **2.64** 11/23/04 421010136 39.92 -75.22STN 20041123 2.8489 **4.69 3.84** **3.68** 11/29/04 421010136 39.92 -75.22STN 20041129 0.5402 **1.46 0**  **0.54** 12/5/04 421010136 39.92 -75.22STN 20041205 1.718 **2.77 2.39** **2.34** 12/11/04 421010136 39.92 -75.22STN 20041211 1.505 **2.07 2.62**  **1.51** 12/17/04 421010136 39.92 -75.22STN 20041217 1.3735 **2.27 1.84**  **1.57** 12/23/04 421010136 39.92 -75.22STN 20041223 0.4325 **1.73 0**  **0.44**OCB **EC** CRUSTAL**SA LT** **DON H2O_A** **IM** OC NO3SO4_3S**CRUSTA L_A** **LT FRM_MA**  **SS**MEASURED_FMRCFM 1.83**0.77** 0.73 **0.01 0.37**  **1.68**3.362.11 **0.81** 12 15.5 13.25 1.07 **0.5** 1.03 **0 0.37**  **1.1** 2.6 1.6 **0.84** 8.7 11.6 9.3 2.25 **1.2** 1.12 **0 0.37**  **1.45**3.782.89 **1.1** 12.7 14.8 14.79 2.29**0.97** 0.39 **0 0.37**  **1.24**3.822.97 **0.47** 10.8 13.17 3.31 **1.09** 0.99 **0 0.37**  **2.22**4.84 1.97 **1.26** 19.7 21.6 17.78 2.09**0.96** 0.34 **0 0.37**  **1.43**3.62 1.35 **0.34** 9.6 11.45 0.38 **0.3** 0.19 **0 0.36**  **1.06** 1.91 0.27 **0.23** 6.3 9.2 5.32 0.58 **0.6** 0.18 **0 0.37**  **1.07**2.11 0.34 **0.2** 6.8 7.7 6.35 3.64**0.99** 0.49 **0 0.37**  **2.31** 5.17 1.83 **0.59** 16 17.8 18.3 4.87**0.54** 0.44 **0 0.37**  **1.85** 6.4 0.8 **0.47** 14.7 18.6 16.49 0.24**0.07** 0.07 **0 0.02**  **0.33** 1.77 0.1 **0.08** 5.1 1.6 1.09 1.69 **1.38** 0.3 **0 0.37**  **1.57**3.22 1.66 **0.32** 10.7 13 12.74 3.67 **1.56** 0.55 **0 0.37**  **2.41** 5.2 4.4 **0.58** 16.9 19.4 22.89 6.27**0.88** 1.13 **0 0.36**  **5.47** 7.8 1.9 **1.21** 33.4 41.5 38.81 5.59 **1.07** 0.4 **0 0.35**  **2.05**7.12 0.62 **0.47** 21.7 20.7 17.67 51.47 **1.6** 0.56 **0.06 0.37**  **1.18** 53 1.86 **0.65** 94.1 98.9 81.15 3.26**0.79** 0.33 **0 0.35**  **0.97**4.790.54 **0.34** 10.1 10.5 9.98 8.97 **1.03** 2.06 **0 0.35**  **9.7** 10.52.88 **2.22** 57.3 60 63.08 -0.41 **0.07** 0.05 **0 0.17**  **0.02** 1.12 0.05 **0.05** 5.3 3.2 -0.32 5.15**0.91** 0.57 **0 0.28**  **0.82**6.680.31 **0.55** 12 13.6 13.41 4.7 **0.4** 0.42 **0 0.3**  **0.58**6.230.22 **0.37** 7.1 7.3 11.12 6.34 **1.15** 0.68 **0 0.32**  **4.1** 7.870.74 **0.66** 28 30.8 28.57 3.82 **0.56** 0.31 **0 0.37**  **3.04**5.350.44 **0.3** 19.2 18.7 18.73 1.84 **1.3** 0.28 **0 0.37**  **1.92** 3.37 1.77 **0.23** 12.8 11.3 13.8 0.81 **0.7** 0.21 **0 0.29**  **0.36**2.340.32 **0.17** 3.4 5.4 4.62 2.66**0.57** 0.19 **0 0.29**  **0.72**4.190.22 **0.22** 7.4 5.9 8.05 1.81 **0.49** 0.19 **0 0.34**  **1.53**3.34 0.4 **0.21** 9.5 8.8 9.69 2.74**0.92** 0.24 **0 0.37**  **1.47**4.270.85 **0.27** 12 9.3 11.72 0.84**0.53** 0.22 **0 0.32**  **0.99**2.370.44 **0.24** 6.5 7.7 6.7 3.53**0.66** 0.21 **0 0.37**  **1.49**5.06 1 **0.23** 10.8 12.3 13.87 2.22 **0.3** 0.24 **0 0.34**  **2.99**3.75 1.03 **0.28** 16.5 14.8 16.36 1.81 **1.02** 0.43 **0 0.28**  **0.28**3.340.95 **0.39** 4.4 6 6.79 **0.37 1.09**  3.11 9.5 2.81 **1.15** 0.54 **0.01 0.37**  **1.01** 4.344.62 **0.58** 14.4 12.5 16.24 1.87 **1.2** 0.27 **0 0.37**  **0.69** 3.4 1.94 **0.31** 9.4 9.5 9.59 2.95 **1.05** 0.31 **0.04 0.37**  **1.16**4.484.26 **0.32** 17.7 16.29 2.28**0.71** 0.21 **0.01 0.37**  **1.4**3.81 1.11 **0.24** 11.9 10.1 10.92 4.33 **1.36** 0.27 **0.25 0.37**  **0.89**5.86 3 **0.3** 15 16.3 15.64 2.52 **1.72** 0.21 **0.03 0.37**  **1.08**4.053.58 **0.17** 13.4 14.2 15.24 1.73 **0.6** 0.15 **0 0.35**  **0.9**3.264.41 **0.16** 10.8 10.1 12.04 1.38**0.47** 0.27 **0 0.37**  **0.87**2.91 3.99 **0.32** 11.7 11.2 10.69 8.57**2.51** 0.49 **0.84 0.37**  **1.83** 10.1 10.6 **0.44** 28.2 31.2 35.52 1.21 **0.62** 0.17 **0.04 0.37**  **0.75**2.74 1.12 **0.19** 7.2 8.1 6.88 2.38**0.78** 0.28 **0 0.37**  **1.83**3.91 4.37 **0.34** 19.1 17.7 18.4 1.16**0.66** 0.24 **0 0.26**  **0.58**2.69 1.51 **0.28** 7.3 6.9 7.53 4.79 **1.52** 0.66 **0 0.37**  **0.51** 6.32 1.5 **0.76** 14.3 11.9 12.79 1.67**0.42** 0.25 **0.04 0.37**  **1.56** 3.2 7.68 **0.31** 15.1 16.56 1.16**0.48** 0.16 **0.02 0.33**  **0.77**2.692.92 **0.18** 9.3 8.4 8.99 0.93**0.58** 0.16 **0.02 0.28**  **0.41** 2.46 1.21 **0.2** 6.1 5.3 5.57 0.62 **0.58** 0.32 **0 0.37**  **1.49**2.15 1.99 **0.29** 10.8 10.1 10.42 2.72 **0.74** 0.25 **0.05 0.37**  **1.33**4.255.81 **0.29** 16.5 16.3 16.73 3.95 **1.09** 0.4 **0.31 0.37**  **1.6**5.488.68 **0.42** 19.9 21.6 21.88 6.38 **1.64** 0.35 **0.23 0.37**  **2.63**7.91 8.62 **0.35** 34.1 32.9 33.7 1.72 **0.82** 0.32 **0 0.37**  **1.01** 3.253.07 **0.37** 12.7 12.7 11.95 1.02 **0.5** 0.19 **0.03 0.37**  **0.81** 2.552.44 **0.21** 9.2 8.95 2.29 **1.49** 0.37 **0 0.37**  **0.63**3.82 1.95 **0.44** 8.8 9.99 0.98**0.78** 0.27 **0 0.37**  **1.81** 2.51 4.13 **0.27** 11.3 14.1 15.68 1.49**0.95** 0.62 **0.05 0.37**  **1.13**3.02 2.6 **0.73** 9.8 13.1 11.440.66**0.58** 0.21 **0.01 0.37**  **1.62**2.19 1.3 **0.22** 11.88 9.2 10.07

0.91 **0.7** 0.16 **0.01 0.33**  **0.99**2.443.07 **0.13** 11.2 9.8 10.29 3.27**0.77** 0.95 **0 0.37**  **2.09** 4.8 1.6 **1.13** 14.14 17.3 16.38 1.28**0.79** 0.43 **0 0.33**  **0.77**2.81 1.31 **0.49** 7.41 6.5 7.63 2.13**0.75** 0.56 **0 0.37**  **0.95**3.660.92 **0.62** 10.7 9.12 1.28**0.47** 0.46 **0 0.28**  **0.44**2.81 0.84 **0.56** 6.5 6.02 3.09 **1.23** 0.46 **0.01 0.37**  **2.26**4.62 6.88 **0.51** 24.28 24.1 25.26 3.18 **1.38** 0.67 **0 0.31**  **0.85**4.71 1.04 **0.74** 12.1 11.4 11.32 2.78 **1.01** 0.57 **0.03 0.37**  **0.83**4.31 2.19 **0.68** 11.5 13.7 11.48 2.67**0.77** 0.6 **0.01 0.37**  **0.95** 4.2 3.04 **0.69** 12.3 12.69 2.11 **0.34** 0.34 **0.02 0.29**  **0.39**3.640.23 **0.36** 7.3 5.76 1.28**0.55** 0.45 **0 0.37**  **2.99**2.81 2.54 **0.56** 14.43 20.9 18.08 2.74**0.55** 0.36 **0 0.37**  **3.94**4.273.72 **0.42** 23.7 24.67 2.3**0.88** 0.51 **0 0.33**  **2.61** 3.832.38 **0.61** 10.72 18.5 18.09 3.41 **0.84** 0.68 **0.01 0.37**  **2.94**4.942.98 **0.76** 19.89 23.6 21.42 2.46**0.52** 1.32 **0 0.36**  **2.58**3.990.68 **1.42** 16.47 17.7 15.77 3.5**0.81** 0.9 **0.03 0.37**  **1.55**5.030.69 **0.9** 13.1 15.2 13.46 5.74**0.42** 0.47 **0.01 0.35**  **2.74**7.270.57 **0.51** 20 19.81 4.95**0.61** 0.7 **0.05 0.37**  **3.65**6.482.22 **0.82** 26.4 25.13 2.26**0.71** 1.07 **0.01 0.37**  **3.83**3.79 1.83 **1.18** 18.64 23.8 22.02 2.58 **1.22** 1.02 **0.01 0.37**  **2.48**4.11 2.77 **1** 17.1 22.3 20.19 3.91 **0.95** 1.04 **0.11 0.37**  **6.46**5.442.19 **1.02** 35.6 43.341.36 3.36**0.57** 0.48 **0.01 0.37**  **1.37**4.89 1.11 **0.5** 13.09 16.6 12.44 3.61 **0.79** 0.79 **0.01 0.32**  **2.53**5.140.79 **0.82** 16.97 20.5 17.64 2.78**0.32** 0.25 **0.02 0.34**  **0.77**4.31 0.51 **0.24** 6.75 7.7 8.01 2.1 **0.48** 0.26 **0.01 0.15**  **0.37**3.630.26 **0.28** 4.55 5.3 5.21 1.23**0.44** 0.71 **0.01 0.2**  **0.31** 2.76 0.6 **0.82** 6.09 8.5 5.51 1.48**0.55** 0.62 **0.28 0.29**  **0.58**3.01 0.59 **0.73** 7.67 9.1 6.79 1.93**0.75** 0.63 **0.01 0.37**  **1.82** 3.460.89 **0.71** 11.09 15.6 12.21 1.21 **0.62** 0.73 **0.01 0.37**  **1.07**2.74 1.28 **0.8** 7.34 8 8.79 2.51 **1.06** 0.51 **0.02 0.37**  **1.29**4.04 1.07 **0.55** 11.13 13.3 11.4 2.37**0.42** 0.37 **0.03 0.36**  **1.54** 3.90.44 **0.38** 10.42 12 10.41 2.04**0.67** 0.29 **0.01 0.37**  **0.78**3.573.42 **0.29** 7.92 11.9 11.79 3.11 **1.12** 0.6 **0.01 0.37**  **0.94**4.64 1.75 **0.67** 8.93 13.3 11.95 2.32 **1.19** 0.76 **0.03 0.37**  **1.18**3.852.13 **0.85** 9.8 12.3 12.48 2.13 **1.69** 0.74 **0.05 0.36**  **1.04**3.662.53 **0.76** 9.67 14.8 13.31 4.8**2.08** 1.02 **0.13 0.37**  **0.89**6.333.36 **1.15** 16.43 20.1 18.04 5.66 **1.91** 0.71 **0.09 0.37**  **1.39** 7.196.14 **0.81** 22.6 24.4 24.45 4.35 **1.02** 0.76 **0.09 0.37**  **1.18**5.88 6 **0.86** 19.72 18.4 19.58 -0.09**0.35** 0.17 **0.01 0.37**  **0.67** 1.440.86 **0.15** 4.9 7.3 4.08 2.65 **1.11** 0.61 **0.38 0.3**  **0.88**4.183.26 **0.61** 15 14.6 13.14 -0.24**0.43** 0.17 **0.04 0.3**  **0.53** 1.290.38 **0.17** 4.4 6.2 3.14 1.04**0.98** 0.33 **0.01 0.37**  **0.85**2.572.36 **0.34** 11.1 10.2 9.69 3.67 **1.62** 0.91 **0.06 0.37**  **0.81** 5.2 1.82 **1.02** 12.9 14.2 13.13 4.72 **1.83** 0.81 **0.16 0.37**  **1.13**6.255.47 **0.93** 19.6 22.2 20.54 3.59 **1.36** 0.61 **0.35 0.37**  **0.86**5.122.68 **0.73** 20.4 17.7 14.4 1.45**0.32** 0.15 **0.01 0.24**  **0.32**2.980.98 **0.14** 5.2 6 5.16 -0.14**0.12** 0.18 **0.01 0.18**  **0.26** 1.390.67 **0.14** 3.8 2.03 2.03**0.94** 0.51 **0.01 0.37**  **0.92** 3.564.18 **0.57** 16.3 14.4 13.06 0.83 **0.6** 0.22 **0.01 0.35**  **0.96**2.363.14 **0.23** 12 12.4 10.06 1.95 **1.01** 0.35 **0.01 0.32**  **0.83**3.483.27 **0.38** 13.1 12.3 11.32 2.01 **0.83** 0.67 **0.01 0.37**  **0.81** 3.542.68 **0.65** 12.8 13 11.49 1.28**0.52** 0.29 **0.02 0.37**  **0.69**2.81 2.84 **0.27** 12.5 11.3 9.12 1.26**0.68** 0.32 **0.01 0.37**  **1.28**2.794.74 **0.25** 16 16.4 14.63 0.8**0.52** 0.42 **0.01 0.37**  **0.32**2.330.92 **0.49** 4.6 5.1 4.49 2.82 **1.23** 0.68 4.35 25.4 27.7 1.05**0.56** 0.25 **0.01 0.37**  **0.93**2.58 1.82 **0.23** 9.5 9.5 8.6 0.31 **0.58** 0.25 **0.01 0.34**  **0.81** 1.84 1.31 **0.23** 8.9 7.7 6.29 0.5**0.43** 0.22 **0.01 0.37**  **0.57**2.030.51 **0.23** 4.6 5.1 4.20.78**0.29** 0.17 **0.01 0.37**  **0.65**2.31 0.48 **0.16** 5.9 4.67

1.05**0.59** 0.3 **0.07 0.37**  **1.33**2.582.87 **0.33** 12.7 13.5 11.82 1.58**0.66** 0.44 **0.01 0.37**  **1.19**3.11 5.64 **0.49** 15.8 16.1 16.07 0**0.28** 0.3 **0.01 0.36**  **0.46** 1.530.35 **0.31** 4.1 4.4 2.73 1.07**0.44** 0.93 **0.06 0.37**  **0.75** 2.6 1.35 **1.04** 6.8 9.5 7.47 0.43**0.47** 0.49 **0.01 0.37**  **1.44** 1.963.05 **0.56** 11.1 9.9 11.01 0.47**0.53** 0.22 **0.01 0.37**  **0.67** 2 0.7 **0.17** 5 22.5 4.86 2.59**0.48** 0.94 **0.01 0.37**  **2.23**4.122.17 **0.9** 14.9 19.2 16.4 2.87**0.46** 1.03 **0.04 0.37**  **2.42** 4.4 1.2 **1.15** 18.5 18.7 16.33 3.09 **1.15** 0.69 **0.01 0.37**  **2.79**4.62 7.24 **0.43** 20.3 36.3 33.38 2.82 **0.81** 0.62 **0.01 0.37**  **1.78**4.353.67 **0.55** 11.7 16.8 19.01 2.04**0.62** 0.76 **0.06 0.36**  **1.84**3.570.75 **0.85** 11.8 24.1 12.83 1.63**0.12** 0.19 **0.01 0.35**  **0.54**3.160.21 **0.19** 4.8 6.1 4.85 3.47**0.58** 0.3 **0.05 0.36**  **3.25** 5 1.2 **0.31** 19.1 20.7 19.92 4.47**0.91** 0.59 **0.06 0.36**  **4.21** 6 1.12 **0.55** 24.8 29.7 28.04 2.65**0.51** 0.46 **0.01 0.37**  **2.73**4.18 1.98 **0.33** 15.8 21.8 20.43 2 **0.88** 0.72 **0.03 0.37**  **1.58**3.53 1.48 **0.7** 10.5 14.1 13.76 3.85**0.62** 0.81 **0.01 0.37**  **3.1** 5.38 1.94 **1.04** 24.5 21.21 2.88**0.75** 0.89 **0.01 0.34**  **0.62**4.41 0.42 **0.97** 7.9 11.1 8.54 1.13**0.32** 0.23 **0.04 0.32**  **0.43**2.660.36 **0.19** 3.7 6.5 4.55 1.07**0.46** 0.17 **0.01 0.3**  **0.35** 2.60.13 **0.18** 4.1 4.5 3.8 1.23**0.66** 0.3 **0.02 0.32**  **1.63**2.76 0.4 **0.3** 10 11.5 10.25 3.81 **0.86** 0.51 **0.01 0.37**  **3.25**5.340.98 **0.52** 20 25.7 22 1.71 **0.61** 0.47 **0.01 0.36**  **0.87**3.240.53 **0.51** 7 8.8 7.42 1.07**0.31** 0.41 **0.01 0.33**  **1.24** 2.6 0.3 **0.41** 7.5 9.6 8.46 0.79**0.25** 0.27 **0.44 0.2**  **0.25**2.32 0.43 **0.29** 3.4 5.6 3.76 2.04**0.49** 0.52 **0.01 0.36**  **1.27**3.570.71 **0.55** 8.6 10.9 10.28 0.61 **0.39** 0.15 **0.05 0.14**  **0.34**2.140.12 **0.11** 2.4 4.1 2.76 3.17 **1.26** 0.66 **0.03 0.37**  **1.6** 4.7 2.5 **0.67** 13.4 14.8 15.73 2.13 **1.21** 0.75 **0.03 0.37**  **1.56**3.66 1.55 **0.77** 11.4 14.3 13.19 2.2 **0.63** 0.41 **0.02 0.37**  **0.64**3.73 1.3 **0.36** 5.9 6 8.46 0.87**0.47** 0.22 **0.01 0.35**  **0.42** 2.4 0.3 **0.17** 3.5 5.2 4.13 1.32 **0.71** 0.29 **0.02 0.37**  **1.21** 2.85 1.48 **0.27** 8.2 9.8 9.47 1.44**0.55** 0.48 **0.01 0.37**  **1.02**2.97 1.22 **0.27** 7.2 8.5 8.67 4.25**0.76** 0.28 **0.1 0.37**  **2.07**5.786.15 **0.24** 20.8 29.3 26.26 0.59**0.74** 0.16 **0.01 0.37**  **0.31** 2.12 0.75 **0.11** 2.9 4.5 4.22 6.04 **1.68** 0.66 **0.06 0.37**  **0.81** 7.573.91 **0.67** 14.5 19.6 20.06 5.37**2.25** 0.73 **0.06 0.37**  **0.97** 6.94.58 **0.74** 16.3 19.4 21.18 2.57 **1.44** 0.64 **0.01 0.37**  **1.43** 4.1 5.81 **0.68** 18 19.9 19.62 1.72 **1.02** 0.34 **0.01 0.37**  **0.53**3.250.49 **0.36** 5.9 10.2 6.41 3.22 **1.01** 0.32 **0.05 0.37**  **0.85**4.754.26 **0.3** 15.3 15.4 15.14 1.12 **0.82** 0.21 **0.11 0.36**  **0.74**2.653.87 **0.22** 9.4 10.5 10.44 2.65 **1.15** 0.52 **0.01 0.37**  **0.69**4.183.04 **0.44** 18.5 12.9 12.43 0.58**0.43** 0.27 **0.02 0.25**  **0.36**2.11 0.52 **0.26** 6.1 7.2 4.56Al Ca Fe Ti Si EPA_FLAG OC-Calc YearMonthDayQuarterYear_Quarter Valid Data Yr_Qr_Valid

0.040.040.11 0.01 0.13 0 2002 4 8 2 2002_2 1 2002_2_1 0.170.050.090.01 0.14 0 2002 4 14 2 2002_2 1 2002_2_1 0.130.040.11 00.21 0 2002 4 20 2 2002_2 1 2002_2_1 0.01 0.02 0.060.01 0.07 0 2002 4 26 2 2002_2 1 2002_2_1 0.01 0.050.130.01 0.23 0 2002 5 2 2 2002_2 1 2002_2_1 0.030.02 0.05 00.05 0 2002 5 8 2 2002_2 1 2002_2_1 0.01 0.01 0.02 00.05 0 2002 5 14 2 2002_2 1 2002_2_1 0.01 0.01 0.02 0.01 0.04 0 2002 5 20 2 2002_2 1 2002_2_1 0.01 0.030.050.01 0.12 0 2002 5 26 2 2002_2 1 2002_2_1 0.02 0.02 0.06 00.09 0 2002 6 1 2 2002_2 1 2002_2_1 0.01 0 0 00.02 0 2002 6 7 2 2002_2 1 2002_2_1 0.01 0.02 0.050.01 0.05 0 2002 6 13 2 2002_2 1 2002_2_1 0.01 0.040.12 0.01 0.07 0 2002 6 19 2 2002_2 1 2002_2_1 0.01 0.050.090.01 0.32 0 2002 6 25 2 2002_2 1 2002_2_1 0.01 0.030.060.01 0.07 0 2002 7 1 3 2002_3 1 2002_3_1 0.01 0.130.040.01 0.09 4 2002 7 7 3 2002_3 2002_3_ 0.02 0.02 0.040.01 0.06 0 2002 7 13 3 2002_3 1 2002_3_1 0.01 0.170.180.01 0.53 0 2002 7 19 3 2002_3 1 2002_3_1 0.01 0.01 00.01 0 2 2002 7 25 3 2002_3 2002_3_ 0.050.03 0.1 0.01 0.07 0 2002 7 31 3 2002_3 1 2002_3_1 0.01 0.030.06 00.09 0 2002 8 6 3 2002_3 1 2002_3_1 0.040.050.11 0.01 0.09 0 2002 8 12 3 2002_3 1 2002_3_1 0.030.02 0.04 00.04 0 2002 8 18 3 2002_3 1 2002_3_1 0.040.02 0.050.01 0.02 0 2002 8 24 3 2002_3 1 2002_3_1 0.01 0.02 0.050.01 0.02 0 2002 8 30 3 2002_3 1 2002_3_1 0.01 0.01 0.03 00.04 0 2002 9 5 3 2002_3 1 2002_3_1 0.01 0.01 0.03 00.03 0 2002 9 11 3 2002_3 1 2002_3_1 0.01 0.01 0.06 00.03 0 2002 9 17 3 2002_3 1 2002_3_1 0.01 0.01 0.03 00.04 0 2002 9 23 3 2002_3 1 2002_3_1 0.01 00.03 00.05 0 2002 9 29 3 2002_3 1 2002_3_1 0.01 0.01 0.04 00.05 0 2002 10 5 4 2002_4 1 2002_4_1 0.01 0.030.13 00.02 0 2002 10 11 4 2002_4 1 2002_4_1 2 2002 10 17 4 2002_4 2002_4_ 0.01 0.02 0.160.01 0.04 0 2002 10 23 4 2002_4 1 2002_4_1 0.01 0.02 0.050.01 0.04 0 2002 10 29 4 2002_4 1 2002_4_1 0.02 0.01 0.07 00.04 0 2002 11 4 4 2002_4 1 2002_4_1 0.01 0.01 0.04 00.04 0 2002 11 10 4 2002_4 1 2002_4_1 0.01 0.02 0.07 00.03 0 2002 11 16 4 2002_4 1 2002_4_1 0.02 0.01 0.05 00.01 0 2002 11 22 4 2002_4 1 2002_4_1 0.01 00.03 00.03 0 2002 11 28 4 2002_4 1 2002_4_1 0.01 0.01 0.05 00.05 0 2002 12 4 4 2002_4 1 2002_4_1 0.01 0.02 0.11 00.07 0 2002 12 10 4 2002_4 1 2002_4_1 0.01 0.01 0.03 00.03 0 2002 12 16 4 2002_4 1 2002_4_1 0.01 0.01 0.04 00.06 0 2002 12 28 4 2002_4 1 2002_4_1 0.01 0.02 0.04 00.04 0 2003 1 3 1 2003_1 1 2003_1_1 0.01 0.040.15 00.09 0 2003 1 9 1 2003_1 1 2003_1_1 0.01 0.01 0.04 00.05 0 2003 1 15 1 2003_1 1 2003_1_1 0.01 0.01 0.03 00.03 0 2003 1 21 1 2003_1 1 2003_1_1 0.01 0.01 0.01 00.04 0 2003 1 27 1 2003_1 1 2003_1_1 0.05 00.02 00.06 0 2003 2 2 1 2003_1 1 2003_1_1 0.01 0.02 0.040.01 0.04 0 2003 2 8 1 2003_1 1 2003_1_1 0.01 0.03 0.1 00.05 0 2003 2 14 1 2003_1 1 2003_1_1 0.01 0.02 0.1 00.02 0 2003 2 20 1 2003_1 1 2003_1_1 0.01 0.02 0.06 00.05 0 2003 2 26 1 2003_1 1 2003_1_1 0.01 0.02 0.04 00.03 0 2003 3 10 1 2003_1 1 2003_1_1 0.01 0.030.06 00.06 0 2003 3 17 1 2003_1 1 2003_1_1 0.01 0.02 0.05 00.04 0 2003 3 22 1 2003_1 1 2003_1_1 0.01 0.050.11 0.01 0.1 0 2003 3 28 1 2003_1 1 2003_1_10.01 0.02 0.050.01 0.02 0 2003 4 4 2 2003_2 1 2003_2_1

0.02 0.01 0.03 00.01 0 2003 4 9 2 2003_2 1 2003_2_1 0.02 0.060.150.01 0.18 0 2003 4 15 2 2003_2 1 2003_2_1 0.01 0.040.08 00.07 0 2003 4 21 2 2003_2 1 2003_2_1 0.040.030.06 00.12 0 2003 4 27 2 2003_2 1 2003_2_1 0.01 0.050.06 00.09 0 2003 5 3 2 2003_2 1 2003_2_1 0.02 0.02 0.1 00.07 0 2003 5 9 2 2003_2 1 2003_2_1 0.01 0.050.140.01 0.08 0 2003 5 15 2 2003_2 1 2003_2_1 0.01 0.030.11 0 0.1 0 2003 5 21 2 2003_2 1 2003_2_1 0.01 0.040.13 00.08 0 2003 5 27 2 2003_2 1 2003_2_1 0.02 0.02 0.060.01 0.05 0 2003 6 2 2 2003_2 1 2003_2_1 0.01 0.01 0.08 0 0.1 0 2003 6 8 2 2003_2 1 2003_2_1 0.01 0.02 0.08 00.05 0 2003 6 14 2 2003_2 1 2003_2_1 0.01 0.040.09 00.09 0 2003 6 20 2 2003_2 1 2003_2_1 0.01 0.040.140.01 0.09 0 2003 7 2 3 2003_3 1 2003_3_1 0.1 0.050.150.01 0.26 0 2003 7 8 3 2003_3 1 2003_3_1 0.070.060.14 00.12 0 2003 7 14 3 2003_3 1 2003_3_1 0.01 0.030.12 0.01 0.05 0 2003 7 20 3 2003_3 1 2003_3_1 0.01 0.040.130.01 0.12 0 2003 7 26 3 2003_3 1 2003_3_1 0.050.050.180.01 0.17 0 2003 8 1 3 2003_3 1 2003_3_1 0.050.050.180.01 0.15 0 2003 8 7 3 2003_3 1 2003_3_1 0.01 0.050.150.01 0.22 0 2003 8 13 3 2003_3 1 2003_3_1 0.02 0.02 0.12 0.01 0.05 0 2003 8 19 3 2003_3 1 2003_3_1 0.030.050.180.01 0.08 0 2003 8 25 3 2003_3 1 2003_3_1 0.01 0.02 0.07 00.01 0 2003 8 31 3 2003_3 1 2003_3_1 0.01 0.01 0.06 00.03 0 2003 9 6 3 2003_3 1 2003_3_1 0.01 0.060.12 00.12 0 2003 9 12 3 2003_3 1 2003_3_1 0.01 0.070.090.01 0.1 0 2003 9 18 3 2003_3 1 2003_3_1 0.01 0.030.150.01 0.08 0 2003 9 24 3 2003_3 1 2003_3_1 0.01 0.040.190.01 0.07 0 2003 9 30 3 2003_3 1 2003_3_1 0.01 00.14 00.05 0 2003 10 6 4 2003_4 1 2003_4_1 0.03 00.05 00.07 0 2003 10 12 4 2003_4 1 2003_4_1 0.02 0.02 0.06 00.03 0 2003 10 18 4 2003_4 1 2003_4_1 0.01 0.030.14 00.07 0 2003 10 24 4 2003_4 1 2003_4_1 0.01 0.030.190.01 0.09 0 2003 10 30 4 2003_4 1 2003_4_1 0.030.030.18 00.07 0 2003 11 5 4 2003_4 1 2003_4_1 0.01 0.060.230.01 0.13 0 2003 11 11 4 2003_4 1 2003_4_1 0.01 0.040.15 0 0.1 0 2003 11 17 4 2003_4 1 2003_4_1 0.01 0.040.17 0 0.1 0 2003 11 23 4 2003_4 1 2003_4_1 0.02 0.01 0.02 00.02 0 2003 11 29 4 2003_4 1 2003_4_1 0.050.040.09 00.09 0 2003 12 5 4 2003_4 1 2003_4_1 0.01 0.02 0.04 00.01 0 2003 12 11 4 2003_4 1 2003_4_1 0.01 0.050.07 00.02 0 2003 12 17 4 2003_4 1 2003_4_1 0.01 0.050.21 0.01 0.11 0 2003 12 23 4 2003_4 1 2003_4_1 0.01 0.030.190.01 0.11 0 2003 12 29 4 2003_4 1 2003_4_1 0.01 0.02 0.1 00.12 0 2004 1 4 1 2004_1 1 2004_1_1 0.01 0.02 0.03 00.01 0 2004 1 10 1 2004_1 1 2004_1_1 0.030.01 0.02 00.02 0 2004 1 16 1 2004_1 1 2004_1_1 0.030.030.07 00.09 0 2004 1 22 1 2004_1 1 2004_1_1 0.01 0.02 0.04 00.03 0 2004 1 28 1 2004_1 1 2004_1_1 0.01 0.02 0.08 00.04 0 2004 2 3 1 2004_1 1 2004_1_1 0.060.030.11 00.09 0 2004 2 9 1 2004_1 1 2004_1_1 0.02 0.030.05 00.03 0 2004 2 15 1 2004_1 1 2004_1_1 0.050.02 0.05 00.03 0 2004 2 21 1 2004_1 1 2004_1_1 0.01 0.030.08 00.07 0 2004 2 27 1 2004_1 1 2004_1_1 0.030.030.15 00.08 2 2004 3 4 1 2004_1 2004_1_ 0.01 0.02 0.060.01 0.01 0 2004 3 10 1 2004_1 1 2004_1_1 0.02 0.01 0.04 00.03 0 2004 3 16 1 2004_1 1 2004_1_1 0.01 0.02 0.04 00.03 0 2004 3 22 1 2004_1 1 2004_1_10.01 0.01 0.04 00.01 0 2004 3 28 1 2004_1 1 2004_1_1

0.01 0.02 0.040.01 0.05 0 2004 4 3 2 2004_2 1 2004_2_1 0.02 0.02 0.07 00.07 0 2004 4 9 2 2004_2 1 2004_2_1 0.02 0.02 0.04 00.05 0 2004 4 15 2 2004_2 1 2004_2_1 0.04 0.1 0.11 0.01 0.16 0 2004 4 21 2 2004_2 1 2004_2_1 0.01 0.02 0.090.01 0.08 0 2004 4 27 2 2004_2 1 2004_2_1 0.030.02 0.03 00.02 0 2004 5 3 2 2004_2 1 2004_2_1 0.1 0.060.11 0.01 0.14 0 2004 5 9 2 2004_2 1 2004_2_1 0.050.070.13 00.19 0 2004 5 15 2 2004_2 1 2004_2_1 0.050.030.16 00.06 0 2004 5 21 2 2004_2 1 2004_2_1 0.01 0.040.11 0 0.1 0 2004 5 27 2 2004_2 1 2004_2_1 0.01 0.05 0.1 00.17 0 2004 6 14 2 2004_2 1 2004_2_1 0.01 0.01 0.04 00.02 0 2004 6 20 2 2004_2 1 2004_2_1 0.01 0.02 0.06 00.04 0 2004 6 26 2 2004_2 1 2004_2_1 0.01 0.050.11 00.09 0 2004 7 2 3 2004_3 1 2004_3_1 0.050.02 0.08 00.05 0 2004 7 8 3 2004_3 1 2004_3_1 0.01 0.040.11 00.14 0 2004 7 14 3 2004_3 1 2004_3_1 0.01 0.030.08 00.21 0 2004 7 20 3 2004_3 1 2004_3_1 0.01 0.1 0.2 00.08 0 2004 7 26 3 2004_3 1 2004_3_1 0.01 0.02 0.06 00.01 0 2004 8 1 3 2004_3 1 2004_3_1 0.01 0.01 0.03 00.02 0 2004 8 7 3 2004_3 1 2004_3_1 0.01 0.01 0.06 00.04 0 2004 8 13 3 2004_3 1 2004_3_1 0.01 0.03 0.1 00.08 0 2004 8 19 3 2004_3 1 2004_3_1 0.01 0.04 0.1 00.05 0 2004 8 25 3 2004_3 1 2004_3_1 0.01 0.01 0.05 0 0.1 0 2004 8 31 3 2004_3 1 2004_3_1 0.01 0.030.040.01 0.03 0 2004 9 6 3 2004_3 1 2004_3_1 0.01 0.02 0.07 00.12 0 2004 9 12 3 2004_3 1 2004_3_1 0.01 0.01 0.03 00.01 0 2004 9 18 3 2004_3 1 2004_3_1 0.01 0.04 0.2 0.01 0.03 0 2004 9 24 3 2004_3 1 2004_3_1 0.01 0.03 0.2 0.01 0.06 0 2004 9 30 3 2004_3 1 2004_3_1 0.01 0.02 0.13 00.01 0 2004 10 6 4 2004_4 1 2004_4_1 0.01 0.01 0.06 00.01 0 2004 10 12 4 2004_4 1 2004_4_1 0.01 0.02 0.08 00.01 0 2004 10 18 4 2004_4 1 2004_4_1 0.1 0.01 0.07 00.02 0 2004 10 24 4 2004_4 1 2004_4_1 0.01 00.08 00.03 0 2004 10 30 4 2004_4 1 2004_4_1 0.01 0.01 0.04 00.01 0 2004 11 5 4 2004_4 1 2004_4_1 0.01 0.030.14 0 0.1 0 2004 11 11 4 2004_4 1 2004_4_1 0.01 0.04 0.2 00.06 0 2004 11 17 4 2004_4 1 2004_4_1 0.02 0.030.14 00.08 0 2004 11 23 4 2004_4 1 2004_4_1 0.01 0.02 0.09 00.03 0 2004 11 29 4 2004_4 1 2004_4_1 0.01 0.02 0.090.01 0.01 0 2004 12 5 4 2004_4 1 2004_4_1 0.01 0.01 0.04 00.03 0 2004 12 11 4 2004_4 1 2004_4_1 0.070.02 0.09 00.05 0 2004 12 17 4 2004_4 1 2004_4_1 0.01 0.030.07 00.01 0 2004 12 23 4 2004_4 1 2004_4_1**2002 Quarter 02**  **2003 Quarter 03**  **2004 Quarter 04**  **Year Start Date** 

1/2/2002 1 1/3/2003 1 1/4/2004 1 2002 1/1/2002 1/8/2002 1 1/9/2003 1 1/10/2004 1 2002 4/1/2002 1/14/2002 1 1/15/2003 1 1/16/2004 1 2002 7/1/2002 1/20/2002 1 1/21/2003 1 1/22/2004 1 2002 10/1/2002 1/26/2002 1 1/27/2003 1 1/28/2004 1 2/1/2002 1 2/2/2003 1 2/3/2004 1 2/7/2002 1 2/8/2003 1 2/9/2004 1 2003 1/1/2003 2/13/2002 1 2/14/2003 1 2/15/2004 1 2003 4/1/2003 2/19/2002 1 2/20/2003 1 2/21/2004 1 2003 7/1/2003 2/25/2002 1 2/26/2003 1 2/27/2004 1 2003 10/1/2003 3/3/2002 1 3/4/2003 1 3/4/2004 1 3/9/2002 1 3/10/2003 1 3/10/2004 1 3/15/2002 1 3/16/2003 1 3/16/2004 1 2004 1/1/2004 3/21/2002 1 3/22/2003 1 3/22/2004 1 2004 4/1/2004 3/27/2002 1 3/28/2003 1 3/28/2004 1 2004 7/1/2004 4/2/2002 2 4/3/2003 2 4/3/2004 2 2004 10/1/2004 4/8/2002 2 4/9/2003 2 4/9/2004 2 4/14/2002 2 4/15/2003 2 4/15/2004 2 4/20/2002 2 4/21/2003 2 4/21/2004 2 4/26/2002 2 4/27/2003 2 4/27/2004 2 5/2/2002 2 5/3/2003 2 5/3/2004 2 5/8/2002 2 5/9/2003 2 5/9/2004 2 5/14/2002 2 5/15/2003 2 5/15/2004 2 5/20/2002 2 5/21/2003 2 5/21/2004 2 5/26/2002 2 5/27/2003 2 5/27/2004 2 6/1/2002 2 6/2/2003 2 6/2/2004 2 6/7/2002 2 6/8/2003 2 6/8/2004 2 6/13/2002 2 6/14/2003 2 6/14/2004 2 6/19/2002 2 6/20/2003 2 6/20/2004 2 6/25/2002 2 6/26/2003 2 6/26/2004 2 7/1/2002 3 7/2/2003 3 7/2/2004 3 7/7/2002 3 7/8/2003 3 7/8/2004 3 7/13/2002 3 7/14/2003 3 7/14/2004 3 7/19/2002 3 7/20/2003 3 7/20/2004 3 7/25/2002 3 7/26/2003 3 7/26/2004 3 7/31/2002 3 8/1/2003 3 8/1/2004 3 8/6/2002 3 8/7/2003 3 8/7/2004 3 8/12/2002 3 8/13/2003 3 8/13/2004 3 8/18/2002 3 8/19/2003 3 8/19/2004 3 8/24/2002 3 8/25/2003 3 8/25/2004 3 8/30/2002 3 8/31/2003 3 8/31/2004 3 9/5/2002 3 9/6/2003 3 9/6/2004 3 9/11/2002 3 9/12/2003 3 9/12/2004 3 9/17/2002 3 9/18/2003 3 9/18/2004 3 9/23/2002 3 9/24/2003 3 9/24/2004 3 9/29/2002 3 9/30/2003 3 9/30/2004 3 10/5/2002 4 10/6/2003 4 10/6/2004 4 10/11/2002 4 10/12/2003 4 10/12/2004 4 10/17/2002 4 10/18/2003 4 10/18/2004 4 10/23/2002 4 10/24/2003 4 10/24/2004 4 10/29/2002 4 10/30/2003 4 10/30/2004 4 11/4/2002 4 11/5/2003 4 11/5/2004 4 11/10/2002 4 11/11/2003 4 11/11/2004 4 11/16/2002 4 11/17/2003 4 11/17/2004 4 11/22/2002 4 11/23/2003 4 11/23/2004 4 11/28/2002 4 11/29/2003 4 11/29/2004 4 12/4/2002 4 12/5/2003 4 12/5/2004 4 12/10/2002 4 12/11/2003 4 12/11/2004 412/16/2002 4 12/17/2003 4 12/17/2004 4

12/22/2002 4 12/23/2003 4 12/23/2004 4 12/28/2002 4 12/29/2003 4 12/29/2004 4**Quarter Total**  **Obs Count Valid Day**  **s %**  1 15 0 0 0.0 2 15 14 14 93.3 3 16 16 14 87.5 4 15 14 13 86.7 Total 61 44 41 67.2

1 15 14 14 93.3 2 15 14 14 93.3 3 16 16 16 100.0 4 15 15 15 100.0 Total 61 59 59 96.7

1 15 15 14 93.3 2 15 13 13 86.7 3 16 16 16 100.0 4 15 14 14 93.3 Total 61 58 57 93.4