**Nov ember 8, 2012 CAA Section 114 - Polyvinyl Chloride and Copolymers (PVC) Production Process Wastewater** 

**PVC General Company and Facility Information**

**Instructions** Please complete this worksheet for your parent company and PVC production facility.

**Parent Company**

**General Information** Parent Company Name: Address: City : State: Texas Zip Code: 75244-6119 Country: USA Size of Company (approximate number of employees including all subsidiaries, branches, and related establishments owned): 3000
**PVC Production Facility General Information**  Facility Name: Facility Address: Facility City: State: New Jersey Zip Code: 8067 Facility Technical Contact Name: Technical Contact Telephone Number: Technical Contact Email: Number of employees attached to the PVC production facility: 38 5005 LBJ Freeway Occidental Chemical Corporation

856-299-8465 elizabeth_vanek@oxy.com OxyVinyls - Pedricktown NJ Plant PO Box 411, Rt. 130 & Porcupine Rd. Pedricktown Elizabeth A. Vanek Dallas**November 8, 2012 CA A**  **Section 114 - Polyvinyl Chloride and Copolymers (PVC) Production Process Wastewater PVC Production Process Wastewater Treatment System Information Update** 

**Instructions**

2. Also complete the additional supplemental questions to Form C-1-c.

**Form C-1-c Supplemental Questions FORM C-1-c**  **PROCESS EQUIPMENT - WA STEWA**  **TER STEA M STRIPPER**  Please also provide the stripper feed rate in liters per hour, or liters for batch strippers: liters/hour liters Process Unit ID: See PolyOne Corporation W W Stripping Column If the above stripper feed rate or capacity does not equal the maximum design rate or capacity, please provide those values: Process Equipment ID: Wa stewater Feed Rate (lb/hr): liters/hour (max design) Feed Temperature (°F): liters (max design) Feed Inlet Pressure (psia): Liquid Loading Rate (liters/m2): Steam Feed Rate (lb/hr): Steam to Feed Ratio (kg steam/liter of wastewater): Operating Temperature (°F): Operating Pressure (psig): Total Number of Stages: Overall Calculated Tray Efficiency: Stripping Factor: Flow configuration (countercurrent, cocurrent): Number of Actual Trays: Column Height (meters): Year Equipment Installed: Equipment Currently Regulated Under (cite regulations): 1. A copy of your facility's responses on Form C-1-c of the August 21, 2009 CAA section 114 request were included with the CAA Section 114 request letter dated November XX, 2012. Please review those previous responses and update if necessary below.**November 8, 2012 CAA Section 114 - Polyvinyl Chloride and Copolymers (PVC) Production Process Wastewater PVC Production Process Wastewater Stream Information** 

**Instructions** 1. Complete a row in Table 1 below for each PVC process wastewater stream generated within the PVC production facility that exits a piece of PVC production process equipment and is not treated by a PVC production process wastewater treatment system. 2. Complete a row in Table 2 below for each PVC process wastewater stream that exits a PVC production process wastewater treatment system. 3. In Table 4, please provide the source, flow rates, and the ID of the PVC process wastewater treatment system for each stream that enters a PVC process wastewater treatment system but that does not originate from the PVC production facility.

**Table 1. Process Wastewater Streams Not Treated by a PVC Process Wastewater Treatment System 1**  **3 4**  **5 6**  **7 8**  **9 10**  **11 12**  **13**

**Min Max**  **Average** P-1, P-6 W- 604 0 312000 227000 Estimated 365 U-105 Dryer Centrifuge WWT Polyone Corporation Yes P-2, P-6 W- 604 0 281000 183000 Estimated 365 U-204 Dryer Centrifuge WWT Polyone Corporation Yes P-1 W- 100 275000 446000 320000 Measured 306 C-108 Rotary Dryer Scrubber WWT Polyone Corporation Yes P-2 Venturi 1st Stage Dryer Scrubber W ater W- 223 273600 576000 367000 Measured 327 C-209 1st Stage Venturi Scrubber WWT Polyone Corporation Yes P-2 Venturi 2nd Stage Dryer Scrubber W ater W- 200 86000 288000 158000 Measured 327 C-212 2nd Stage Dryer Scrubber WWT Polyone Corporation Yes P-3 Catalyst Bottle W ash W ater W- 605 90 240 170 Estimated 180 U-312 Catalyst Make-Up Bottle Flush WWT Polyone Corporation Yes

**Table 2. Process Wastewater Streams Exiting a PVC Process Wastewater Treatment System 1**  **2 3**  **4 5**  **6 7**  **8 9**  **10 11**  **12 13** 

**Min Max**  **Average** Wa stewater Stripper(s) owned and operated by PolyOne

**Table 3. PVC Process Wastewater Destination Codes Table Code**  Wa stewater treatment system WWT Provide name of the wastewater treatment system Discharge without treatment by pipeline, sewer, or other conveyance to surface water SW Provide name of outfall Discharge to POTW , no treatment POTW RAW Provide name of POTW Discharge to PrOTW , no treatment PrOTW RAW Provide name of PrOTW Zero discharge or alternative disposal method ZEROALT Describe method Recycle to process RECYC Describe where in the process the stream is recycled Other OTHER Describe

**Table 4. Non-PVC Production Process Wastewater Streams Entering a PVC Process Wastewater Treatment System 2**  **3 4**  **5 6**  **7**

**Min Max**  **Average 1**  **Process Wastewater Destination Details to Provide in Column 12 of Table 1 and Column 11 of Table 2 Destination Description** 

**Source of Process Wastewater Stream PVC Process**  **Wastewater Treatment**  **System ID Operating Days**  **Per Year Flow Rate**  **Determination Method**  **Process Wastewater Stream Flow Rate**

**(gallons per day) 14** 

**Type of Process Wastewater**  **Treatment System If your response in Column 3 is "Other" then please provide a description of the process wastewaetr**  **treatment system PVC Process**  **Unit ID PVC Process**  **Wastewater Stream ID**  **Is this PVC process wastewater stream exposed to the atmosphere**  **at any point between the outlet of the PVC process wastewater**  **treatment system and its destination?**  **Associated Destination Information** (Refer to Table 3 below) **PVC Process Wastewater Stream**  **Destination Code** (Refer to Table 3 below) **Operating Days Per Year**  **Flow Rate Determination**  **Method PVC Process Wastewater Stream Flow Rate** 

**(gallons per day) PVC Process**  **Wastewater Treatment**  **System ID Is this**  **process wastewater**  **treatment system batch**  **or continuous operation?**  **2**

Rotary Dryer Scrubber W ater **PVC Process Unit ID**  **Name of PVC Process Wastewater Stream**

(OxyVinyls believes W -605 is maintenance wastewater) Centrifuge Effluent- U204, S-211 Centrifuge Effluent- U105, S-111 **Is this PVC process wastewater stream exposed to the atmosphere**  **at any point between the originating PVC process equipment and its** 

**destination? Originating PVC Process**  **Equipment Description Originating PVC Process**  **Equipment ID Associated Destination Information**  **Flow Rate Determination**  **Method PVC Process Wastewater Stream**  **Destination Code** (Refer to Table 3 below) **PVC Process Wastewater Stream Flow Rate**

**(gallons per day) Operating Days Per**  **Year PVC Process**  **Wastewater Stream ID** 

### November 8, 2012 CA **A Section 114 - Poly** 

**viny l Chloride and Copoly**  **mers (PVC) Production Process Wastew ater**  **PVC Production Process Wastew ater Sampling and A** **naly sis Data** 

**Instructions** 1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system that was sampled and analyzed. Com plete one worksheet for each single stream (make copies of this worksheet if necessary ). 2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of the "Stream Info" worksheet. 3. Complete columns 1 through 30. Enter the sample date, resin ty pe, stream flow rate, basis for flow rate determination, stream temperature, sample ty pe, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed. 4. Enter any

other HAP expected to be present (that are not listed in Table 10 to Subpart HHHHHHH of Part 63) in the table below. 4. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column. 5. Enter any

notes or additional information relevant to the sampling or analysis.

**Company Facility**  **PVC Process Wastewater Treatment Sy stem ID** 

**CA S No.**  **HA P**  107211 Ethylene glycol 67561 Methanol 75070 Acetaldehyde 50000 Formaldehyde 51285 2,4-dinitrophenol 98862 Acetophenone 117817 Bis(2-ethylhexyl) phthalate (DEHP) 123319 Hydroquinone 108952 Phenol 79345 1,1,2,2-tetrachloroethane 106990 1,3-butadiene 540841 2,2,4-trimethylpentane 71432 Benzene 108907 Chlorobenzene 67663 Chloroform 126998 Chloroprene 98828 Cumene 75003 Ethyl chloride (Chloroethane) 100414 Ethylbenzene 107062 Ethylene dichloride (1,2-Dichloroethane) 75343 Ethylidene dichloride (1,1-Dichloroethane) 74873 Methyl chloride (Chloromethane) 75092 Methylene chloride 110543 n-Hexane **Resin Type (suspension, dispersion, bulk, etc.) -->**108883 Toluene 71556 Methyl chloroform (1,1,1-Trichloroethane) 79005 1,1,2-Trichloroethane 108054 Vinyl acetate 593602 Vinyl bromide 75014 Vinyl chloride 75354 Vinylidene chloride (1,1-Dichloroethy lene) 1330207 Xylenes (isomers and mixtures)

### November 8, 2012 CA **A Section 114 - Poly** 

**viny l Chloride and Copoly**  **mers (PVC) Production Process Wastew ater**  **PVC Production Process Wastew ater Sampling and A**  **naly sis Data** 

1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system that was sampled and analyzed. Com plete one worksheet for each single stream (make copies of this worksheet if necessary ). 2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of the "Stream Info" worksheet. 3. Complete columns 1 through 30. Enter the sample date, resin ty pe, stream flow rate, basis for flow rate determination, stream temperature, sample ty pe, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed. 4. Enter any

other HAP expected to be present (that are not listed in Table 10 to Subpart HHHHHHH of Part 63) in the table below. 4. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column. 5. Enter any

notes or additional information relevant to the sampling or analysis.

Occidental Chemical Corporation Oxy Vinyls - Pedricktown NJ Plant See PolyOne Corp. Data Submission

**An alysis M**  **ethod Concentration**  **(ppmw) Non-Detect?**  SW -846-8015C SW -846-8015C SW -846-8315A SW -846-8315A SW -846-8270D SW -846-8270D SW -846-8270D SW -846-8270D SW -846-8270D SW -846-8260B SW -846-8260B SW -846-8260B SW -846-8260B SW -846-8260B SW -846-8260B SW -846-8260B SW -846-8260B SW -846-8260B SW -846-8260B SW -846-8260B SW -846-8260B SW -846-8260B SW -846-8260B SW -846-8260B **An alysis Date -->**  **Lab Sample ID --> Lab Report ID -->**  **Flow Rate Determination Method --> Stream Temperature (degrees F) -->** 

**Sample Date --> Stream Flow Rate (gallons per minute) -->**  **Resin Type (suspension, dispersion, bulk, etc.) -->**SW -846-8260B

SW -846-8260B SW -846-8260B SW -846-8260B SW -846-8260B EPA Method 107 SW -846-8260B SW -846-8260B1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system that was sampled and analyzed. Com plete one worksheet for each single stream (make copies of this worksheet if necessary ). 2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of the "Stream Info" worksheet. 3. Complete columns 1 through 30. Enter the sample date, resin ty pe, stream flow rate, basis for flow rate determination, stream temperature, sample ty pe, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed. 4. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column.

**Note(s) Concentration**  **(ppmw) Non-Detect?**  **Note(s) 2**  **1 Concentration** 

**(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **3 Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)**  **4 5** **Concentration**

**(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **6 Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)**  **7 8** **Concentration**

**(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **9 Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)**  **10 11** **Concentration**

**(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **12 Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)**  **13 14** **Concentration**

**(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **15 Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)**  **17 16** **Concentration**

**(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **18 Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)**  **19 20** **Concentration**

**(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **21 Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)**  **23 22** **Concentration**

**(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **24 Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)**  **25 26** **Concentration**

**(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **27 Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)**  **28 29** **Concentration**

**(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **30 Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)**  **31 32** **Concentration**

**(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **33 Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)**  **34 35** **Concentration**

**(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **36 Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)**  **38 37** **Concentration**

**(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **39 Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)**  **41 40** **Concentration**

**(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **42 Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)**  **43 44** **Concentration**

**(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **45 Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)**  **46 47** **Concentration**

**(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **48 Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)**  **49 50** **Concentration**

**(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **51 Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)**  **53 52** **Concentration**

**(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **54 Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)**  **56 55** **Concentration**

**(ppmw) Non-Detect?**  **Note(s) Concentration**  **(ppmw) Non-Detect?**  **57 Note(s)**  **Concentration (ppmw)**  **Non-Detect? Note(s)**  **59 58** **Concentration**

**(ppmw) Non-Detect?**  **Note(s) 60**