November 8, 2012 CAA Section 114 - Polyvinyl Chloride and Copolymers (PVC) Production Process Wastewater

PVC General Company and Facility Information

Instructions

Please complete this worksheet for your parent company and PVC production facility.

Parent Company General Information

Parent Company Name:

Address:

City: State: Texas Zip Code: 75244-6119

Country: USA

Size of Company (approximate number of employees including all subsidiaries, branches, and related establishments owned): 3000

PVC Production Facility General Information

Facility Name:

Facility Address:

Facility City: State: New Jersey Zip Code: 8067

Facility Technical Contact Name:

Technical Contact Telephone Number:

Technical Contact Email:

Number of employees attached to the PVC production facility: 38

5005 LBJ Freeway

Occidental Chemical Corporation

856-299-8465

elizabeth_vanek@oxy.com

OxyVinyls - Pedricktown NJ Plant

PO Box 411, Rt. 130 & Porcupine Rd.

Pedricktown

Elizabeth A. Vanek

Dallas
November 8, 2012 CAA Section 114 - Polyvinyl Chloride and Copolymers (PVC) Production Process Wastewater

PVC Production Process Wastewater Treatment System Information Update

Instructions

2. Also complete the additional supplemental questions to Form C-1-c.

Form C-1-c Supplemental Questions

FORM C-1-c

PROCESS EQUIPMENT - WASTEWATER STEAM STRIPPER Please also provide the stripper feed rate in liters per hour, or liters for batch strippers: liters/hour

 liters

Process Unit ID: See PolyOne Corporation WW Stripping Column

If the above stripper feed rate or capacity does not equal the maximum design rate or capacity, please provide those values:

Process Equipment ID:

Wastewater Feed Rate (lb/hr): liters/hour (max design)

Feed Temperature (°F): liters (max design)

Feed Inlet Pressure (psia):

Liquid Loading Rate (liters/m2):

Steam Feed Rate (lb/hr):

Steam to Feed Ratio (kg steam/liter of wastewater):

Operating Temperature (°F):

Operating Pressure (psig):

Total Number of Stages:

Overall Calculated Tray Efficiency:

Stripping Factor:

Flow configuration (countercurrent, cocurrent):

Number of Actual Trays:

Column Height (meters):

Year Equipment Installed:

Equipment Currently Regulated Under (cite regulations):

1. A copy of your facility's responses on Form C-1-c of the August 21, 2009 CAA section 114 request were included with the CAA Section 114 request letter dated November XX, 2012. Please review those previous responses and update if 

necessary below.
November 8, 2012 CAA Section 114 - Polyvinyl Chloride and Copolymers (PVC) Production Process Wastewater

PVC Production Process Wastewater Stream Information

Instructions

1. Complete a row in Table 1 below for each PVC process wastewater stream generated within the PVC production facility that exits a piece of PVC production process equipment and is not treated by a PVC production process wastewater treatment system.

2. Complete a row in Table 2 below for each PVC process wastewater stream that exits a PVC production process wastewater treatment system.

3. In Table 4, please provide the source, flow rates, and the ID of the PVC process wastewater treatment system for each stream that enters a PVC process wastewater treatment system but that does not originate from the PVC production facility.

Table 1. Process Wastewater Streams Not Treated by a PVC Process Wastewater Treatment System

1 3 4 5 6 7 8 9 10 11 12 13

Min Max Average

P-1, P-6 W-604 0 312000 227000 Estimated 365 U-105 Dryer Centrifuge WWT Polyone Corporation Yes

P-2, P-6 W-604 0 281000 183000 Estimated 365 U-204 Dryer Centrifuge WWT Polyone Corporation Yes

P-1 W-100 275000 446000 320000 Measured 306 C-108 Rotary Dryer Scrubber WWT Polyone Corporation Yes

P-2 Venturi 1st Stage Dryer Scrubber Water W-223 273600 576000 367000 Measured 327 C-209 1st Stage Venturi Scrubber WWT Polyone Corporation Yes

P-2 Venturi 2nd Stage Dryer Scrubber Water W-200 86000 288000 158000 Measured 327 C-212 2nd Stage Dryer Scrubber WWT Polyone Corporation Yes

P-3 Catalyst Bottle Wash Water W-605 90 240 170 Estimated 180 U-312 Catalyst Make-Up Bottle Flush WWT Polyone Corporation Yes

Table 2. Process Wastewater Streams Exiting a PVC Process Wastewater Treatment System

1 2 3 4 5 6 7 8 9 10 11 12 13

Min Max Average

Wastewater Stripper(s) owned and operated by PolyOne

Table 3. PVC Process Wastewater Destination Codes Table

Code

Wastewater treatment system WWT Provide name of the wastewater treatment system

Discharge without treatment by pipeline, sewer, or other conveyance to surface water SW Provide name of outfall

Discharge to POTW, no treatment POTWRAW Provide name of POTW

Discharge to PrOTW, no treatment PrOTWRAW Provide name of PrOTW

Zero discharge or alternative disposal method ZEROALT Describe method

Recycle to process RECYC Describe where in the process the stream is recycled

Other OTHER Describe

Table 4. Non-PVC Production Process Wastewater Streams Entering a PVC Process Wastewater Treatment System

2 3 4 5 6 7

Min Max Average

1

Destination Description Process Wastewater Destination Details to Provide in Column 12 of Table 1 and Column 11 of Table 2

Source of Process Wastewater Stream

PVC Process 

Wastewater 

Treatment 

System ID

Operating Days 

Per Year

Flow Rate 

Determination 

Method

Process Wastewater Stream Flow Rate 

(gallons per day)

14

Type of Process 

Wastewater 

Treatment System

If your response in Column 3 is "Other" then please provide a description of the process wastewaetr 

treatment system

PVC Process 

Unit ID

PVC Process 

Wastewater 

Stream ID

Is this PVC process wastewater 

stream exposed to the atmosphere 

at any point between the outlet of 

the PVC process wastewater 

treatment system and its 

destination?

Associated Destination Information

(Refer to Table 3 below)

PVC Process 

Wastewater Stream 

Destination Code

(Refer to Table 3 below)

Operating Days 

Per Year

Flow Rate 

Determination 

Method

PVC Process Wastewater Stream Flow Rate 

(gallons per day)

PVC Process 

Wastewater 

Treatment 

System ID

Is this 

process 

wastewater 

treatment 

system batch 

or continuous 

operation?

2

Rotary Dryer Scrubber Water

PVC Process 

Unit ID Name of PVC Process Wastewater Stream

 (OxyVinyls believes W-605 is maintenance wastewater)

Centrifuge Effluent- U204, S-211 

Centrifuge Effluent- U105, S-111

Is this PVC process wastewater 

stream exposed to the atmosphere 

at any point between the originating 

PVC process equipment and its 

destination?

Originating PVC Process 

Equipment Description

Originating PVC Process 

Equipment ID Associated Destination Information

Flow Rate 

Determination 

Method

PVC Process Wastewater Stream 

Destination Code

(Refer to Table 3 below)

PVC Process Wastewater Stream Flow Rate 

(gallons per day) Operating Days Per 

Year

PVC Process 

Wastewater 

Stream ID
November 8, 2012 CAA Section 114 - Polyvinyl Chloride and Copolymers (PVC) Production Pro

PVC Production Process Wastewater Sampling and Analysis Data

Instructions

1. Complete the table below for each PVC process wastewater steam exiting a process wastewater treatment system 

2. Enter the PVC process wastewater treatment system ID for the stream that was sampled and analyzed. The ID mu

3. Complete columns 1 through 30. Enter the sample date, resin type, stream flow rate, basis for flow rate determinat

4. Enter any other HAP expected to be present (that are not listed in Table 10 to Subpart HHHHHHH of Part 63) in the 

4. For compounds that were not detected, indicate as such in the "Non-Detect?" column and provide the method dete

5. Enter any notes or additional information relevant to the sampling or analysis.

Company

Facility

PVC Process Wastewater Treatment System ID

CAS No. HAP

107211 Ethylene glycol

67561 Methanol

75070 Acetaldehyde

50000 Formaldehyde

51285 2,4-dinitrophenol

98862 Acetophenone

117817 Bis(2-ethylhexyl) phthalate (DEHP)

123319 Hydroquinone

108952 Phenol

79345 1,1,2,2-tetrachloroethane

106990 1,3-butadiene

540841 2,2,4-trimethylpentane

71432 Benzene

108907 Chlorobenzene

67663 Chloroform

126998 Chloroprene

98828 Cumene

75003 Ethyl chloride (Chloroethane)

100414 Ethylbenzene

107062 Ethylene dichloride (1,2-Dichloroethane)

75343 Ethylidene dichloride (1,1-Dichloroethane)

74873 Methyl chloride (Chloromethane)

75092 Methylene chloride

110543 n-Hexane

Resin Type (suspension, dispersion, bulk, etc.) -->
108883 Toluene

71556 Methyl chloroform (1,1,1-Trichloroethane)

79005 1,1,2-Trichloroethane

108054 Vinyl acetate

593602 Vinyl bromide

75014 Vinyl chloride

75354 Vinylidene chloride (1,1-Dichloroethylene)

1330207 Xylenes (isomers and mixtures)
 Chloride and Copolymers (PVC) Production Process Wastewater

g and Analysis Data

stewater steam exiting a process wastewater treatment system that was sampled and analyzed. Complete one worksheet for each single st

m ID for the stream that was sampled and analyzed. The ID must match the IDs listed in Table 2 of the "Stream Info" worksheet.

date, resin type, stream flow rate, basis for flow rate determination, stream temperature, sample type, analysis date, lab report ID, and lab sa

re not listed in Table 10 to Subpart HHHHHHH of Part 63) in the table below.

such in the "Non-Detect?" column and provide the method detection limit, in ppmw, in the "Concentration (ppmw)" column.

 the sampling or analysis.

Occidental Chemical Corporation

OxyVinyls - Pedricktown NJ Plant

See PolyOne Corp. Data Submission

Analysis Method Concentration 

(ppmw) Non-Detect?

SW-846-8015C

SW-846-8015C

SW-846-8315A

SW-846-8315A

SW-846-8270D

SW-846-8270D

SW-846-8270D

SW-846-8270D

SW-846-8270D

SW-846-8260B

SW-846-8260B

SW-846-8260B

SW-846-8260B

SW-846-8260B

SW-846-8260B

SW-846-8260B

SW-846-8260B

SW-846-8260B

SW-846-8260B

SW-846-8260B

SW-846-8260B

SW-846-8260B

SW-846-8260B

SW-846-8260B

Analysis Date -->

Lab Sample ID -->

Lab Report ID -->

Flow Rate Determination Method -->

Stream Temperature (degrees F) -->

Sample Date -->

Stream Flow Rate (gallons per minute) -->

Resin Type (suspension, dispersion, bulk, etc.) -->
SW-846-8260B

SW-846-8260B

SW-846-8260B

SW-846-8260B

SW-846-8260B

EPA Method 107

SW-846-8260B

SW-846-8260B
and analyzed. Complete one worksheet for each single stream (make copies of this worksheet if necessary).

sted in Table 2 of the "Stream Info" worksheet.

ature, sample type, analysis date, lab report ID, and lab sample ID. Enter the concentration results for each HAP listed.

, in the "Concentration (ppmw)" column.

Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

1 2

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

3

Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

4 5

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

6

Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

7 8

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

9

Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

10 11

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

12

Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

13 14

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

15

Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

16 17

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

18

Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

19 20

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

21

Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

22 23

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

24

Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

25 26

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

27

Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

28 29

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

30

Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

31 32

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

33

Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

34 35

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

36

Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

37 38

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

39

Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

40 41

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

42

Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

43 44

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

45

Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

46 47

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

48

Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

49 50

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

51

Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

52 53

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

54

Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

55 56

Concentration 

(ppmw) Non-Detect? Note(s) Concentration (ppmw) Non-Detect?

57

Note(s) Concentration 

(ppmw) Non-Detect? Note(s)

58 59

Concentration 

(ppmw) Non-Detect? Note(s)

60