### Labels Special Labels 

## I P.ep Finder 

## 1 University Info 

## I Media 

### enter 

## 1

Contact 

### us 

# I l~hoose 

### a 

### Country



# Label Display Product Name Gramoxone Max (Herbicide) 

### Active 

### lngredien t Paraquat a 

### Crows) AceroIa, Alfalfa, Almonds, Avocados, Bananas, Beans garbanzo (dry), Beans, adzukl (dry), Beans, asparagus (dry), Beans, black (dry), Beans, broad (dry), Beans, field (dry), Beans, grain lupin (dry). Beans, kidney (dry), Beans, lablab (dry), Beans, lirna, Beans, llma (dry), Beans, moth (dry), Beans, mung (dry), Beans, navy (dry), Beans, pinto (dry), Beans, rice (dry), 

### Beans,snap, Beans, snap (dry), Beans, sweet lupin (dry), Beans,tepaly (dry), Beans, urd (dty) Beans, wax (dry), Beans,white lupin (dry), Beans, white sweet lupin (dry), Beechnut, Beets, sugar, Boysenbrries, Brazil nut, Butternut, Cabbage, Chinese, Cacao, Calamondins, Carrots, Cashew, Cassavas, Caljang (dry), Cavalo brocmlo, Chayote fruit, Chemical fallow, Cherries, Chestnut, Chickpeas (dry), Chinquapin, Cimn melon, Citron, citrus, Clover, Coffee, Collards, Conservation Compliance Programs, Conservation Resenre, Corn (popeom), Con %d, Cowpeas (dry), Eggplant, Elderberry, FederalSet-AsMe, Figs Gherkins, Gourds, edible, Grapefruit, Grasses,Greens, mustard, Greens, rape, Groundcherries, Guar, Guar (dry), Guava, Hidory nuHops, Hucklebeny, Kale, Kiwifrult, Kohlrabi, Kumquat, Lemons, Lentils,Lettuce, Lilies, Easter, 

### time,Loquat, Macadamianuts, Mandarins, Mandarins, satsurna, Mayhaw, Melon, Mint, Miuna, Mornordica, Mustard spinach, Ollves, Onions, Oranges, sour, Oranges, sweet, Oriental Pear, Papaya, Passionfruit, Pasture reseeding. Peas, Peas, blackeye (dry), Peas,crowder (dry), Peas, pigeon, Peas, southern (dry), Pecans, Pepino, Peppers, Pineapple, Pistachlos, Plums, Pmelos, Prunes, Raspberries, Rhubarb, Rice, Safflower, Sorghum, grain, Sugarcane, Sunflowers, Tanlers, Tam, dryland, tom at ill^, Tree ptantatiw establishment, Trees andvines, orchard, Trees andvlnes, ornamental, Trees and vines, shade, Trees and vines, vineyard, Trees andvines, windbreak, Tyfon, Walnuts, Waxgourds, Chinese, Wheat, Yams 

### Description A 

### non-setectivecontact herbicidefor mtrol of grasses and broadleafweeds In field, vegetable, forage and treecrops. 

### Also usei as a deslccanWdefoliantat harvest and 

### as a harvest aid for dry beans, cotton. guar, lentils, soybeans, sugar cane and sunflowers. This label registeredfor use in AZ, FL, HI, MU, NC, NM, TX and VA Registrationdelayed hCA. Not registeredfor use in CO, CT, DC, DE, IA. 1L, IN, KS, KY, MA, MD, ME, MI, MN, MT, ND, NE, NH, NJ, NV, 

### NY,OH, PA, PR, RI, SD, UT, WI, WY. Check with 

### Zeneca Registraf~n at (800) 544-0273xl184 for use in all other states. 

### Vlew Md

## MsDs

### I~hoose 

### a Country

special 

### Label:: 

## I Rep Finder 

## I Clniversitv Info 

## I Media Center 

## I 

# Label Display Product Name Gramoxone Extra (Herblcde) 

### Active lngredlent Paraquat 

### Crop(s) Acerola, Avocados, Bananas, Beans, adzuki (dry), 

### Beans, asparagus (drj), Beans, black (dry), Beans, bmd(dry), Beans, fielc (dry), Beans, garbanzo(dry), Beans, grain lupin (dry), Beans, kine) (dry), Beans, lablab (dry), Beans, lirna (dry), Beans, moth (dry), Beans, mung (dry), Beans, navy

### (dry),Beans, pinto (dry), 

### Beans, ric (dry), Beans, snap, Beans, snap (dry), 

### Beans,sweet lupin (dry), Beans, tepary (dry),Beans, urd (dry), Beans, wax (dry), Beans,whlt lupin (dry), Beans, white sweet lupin (dry), Beechnut, Boysenberries Brazil nut, Butternut, Cabbage, Chinese, Cacao, Calamondims, 

### Cashew, Catjang (dry), Cavab brocoolo, Chayotefruit, Chemical fallow, Chestnut, Chickpeas (dry), Chinquapin, Citron melon, Citron, citrus, Clovers and other legumes,Collards, Cmenration Compliance Programs. ConservationResewe, Corn (popcorn), 

### Con seed. Cowpeas (dry), Dandelion, Eggplant, Elderberry, Federal SetAside, Figs, Foxtall,giant, Gherkins, Gourds, edible, Grspefruit, Grasses, Greens, mustard, Greens, rape, Groundcherries, Guar, Guava, Hickory nut, Hops, Huckleberry, Kale, Kiwi fruit, Kohlrabi, Kumquat, Lemons. Lettuce, Lilies, Easter, Lime, Lquat, Macadamii nuts, Mandarins, Mandarins, satsuma, Mayhaw, Melon, Mlnt, Mlzuna, Mornordica, Muskmelons, Mustardspinach, Ollves, Oranges, sour, Oranges, sweet, Papaya, Pasture reseeding, 

### Pears, oriental, Peas, Mackeye (dry), Peas, crowder (dry), Peas, southern (dry), Pecans, Pepino, Peppers, chili, Pineapple, Pistachios, Pornelos, Prunes, Raspberries, Red rice, Rhubarb, Safflower, Sorghum, grain, Sugarcane, Tam, dryland, Tmatillos, 

### Treesand vines, orchard, Trees and vines, ornamental, Trees and vlnes, shade, Trees and vlnes, vineyard, Tmsandvines, windbreak, Tyfon, Volunteer cereals, Waxgourds, Chinese 

### Description A non-selective contact herbicidefor control of grasses

### ad broadleaf weeds infleld, vegetable,forage and tree crops. Also uw as a desiccantat harvest and as a harvest aid indry beans, guar, lentils, soybeans, sugar cane and sunflowers. Checkwlth Zeneca Registration at (600) 544-0273 x1184for 

### use In C

A. 

### View .I&& 

### MSnS

### Paraoxon 

### Pesticide 

### Dictionary CROP PROTECTION Paraoxon Identification 

### ED. 

### CODENUMBERS:E-600. 

### DIGCONTINUEDNAMES:Mintacnl* (Bayer). Chemidry COMPOSITION: 0,O-Diethyl O-p-nitmphenyl phwphate.

Paraoxon Actiode ACTION:Insecticide. Panp~z* 

### -seeParaquat. Parapest MSO*InsecwW(methyl parathion) -%ntinued 1995by PlantersMutts. Paraquat 

### BP: AgmDragon Co.,Ltd. (Agmquat*) AgsinPte. Ltd. (Hebone*,Paquat*) Biesterfeld US.,Inc. Camfall Corp. Chem East SA. Crvstal Chemical Inter-America (Crkauat*. Herhxone*)



## . . Fuicm Chemical Industrial Co., ~td. GriffinL.L.C. (Boa*) Industrias Bicquim SA. (Bioquat*) Kuo Ching ChmicdCo., Ltd. Marman

### USA, Inc. (Herbiquat*, Milquat*) Nu-Gro Frofessional& ConsumerGroup Pilarquim Corp. (Pilarqmt*, Pilarxone*) Sanonda Co., Ltd. (Weedless*) ShenzhenJiannshan Commerce & IndustmCorn. 

# - <. SinonCorp. Sundat 

### (S) Pte. Ltd. (Sunaquat*) Syngenta (Cyclone*, Gramoxone*,Gramoxone* Extra,

Starlire*} Identification COMMON NAME: f araquat(ISO, ANSI, BSI,JMAF, WSSA). CODE NUMBERS: CAS 4685-14-1; SHA 061601. CAS 191042-5 (paraquat dichloride). FORMULATORS'

### TRADE NAMES: Weedaway* (AgrolexPte.Ltd.) Paraquate* (The ArabPesticides &VeterinaryDrugs

### MQ.Co.) 

### Herboxone* (Dupocsa) * Grdn* (Invesa S.A.) * Markzone* (Ladda 

### Co.,Ltd.) Luxaquat*, Tenpa+ (Lwcan B.V.) Dipaxone* (Pap-n- omou Agrochemicals S.k) Parapaz*(PazchemLtd.) Woprogram* (B.V. Industria- & Handelsonderneming Simonis) Dextmne* (Syngenta) Mhil*,Malezil* Super (TODOAgriooh S.k) * Herbikill* TVArn>. 

## .--- --,- DIECONTINUED NAMES: Parakill* (Agrochemical industries Co., Ltd.) Herbaxon*(+ diquat&bromide)(A&Group) + Caldeml* (Ckquiea) 

### OW ParaquatCL(ChevronChemid Co.) Esgram*> Galdquat* 276 (F.E.Zuellig 

### Pk) Act&, Weedol* (+ diquatdibromide),Granmxone* 

### S,Sweep* (ICIAgrdemicah) + Osaquat &I& PruhhOSA SAC-LFJA) Uniquat* (Unitsd Phosphorus Ltd.). Chemktry COMPOSITION: l,l'-dirnethyl4,4'&pyridinium ion; present as tha dichloride salt(SmmntdCrvstal)ordimethvl sulfaC salt(hntinued). 

### CLASS:~i~sd&urn, dibyridY1ium. 

### - PROPERTIES: Stableexcept under alkalineconditions.No measurable vaprpressure.Colorlesscrystallinesolid dewmpssatapproximately 300% Sparingly soluble inloweraloohols,insoluble in hydrocarbons.

Pnraquat Action/U= ACTION: Contact herbicide. de~iccant. USE: Desiccationof seed crops;nonmpand industrialweedmntrol in bearing and nonbearing fruit orchards, shade trees, and ornamentals. Defoliationand desiccation of

## &. Harvest aid in soyb,flugarcane, gum, and sunflowers, for pasture renovation, forwe in No-Till" orbeforeplanting orcropemergence, dormant alfalfa andclover,dire& ed spray, and for killingpotato vines. Eradicationof weda in rubber plantations, coffee plantations, and paddy bund. Talent* postemergemin bananas,coma, mffee, mconuta, citrus,and sugarcane. FORPIIULATIONSGranular,solid, solubleconcentrate. PREMMES: Anwon* (+ diuron), Antox* (+ MSMA)(hicorn Crop Care S.B.) Talent*(+mulam)(AventisCropSueace) Crisquat

### D*, Herhne D* (+diuron)(Crystal ChemicalIntwAmerica and Dupocsa) 

### S&* (+ diuron)(PlatteChemical Co.) Preglone*, Riglone* (+diquatdibromide), Dexuron*, Gramocil*, Gramuron*, Parawl*, 

### T+ tad* (+ &won), Pathclew* 

### (+ diquat dihmide

### + simazine), Gramonal* (+ monolinuron) (Syngenta) Terraklene*(+simazine). Registmtion Notes 

### U.S.: Someorall applicationsmay be classified as RUP. OUTSIDE U.S.:Herboxone*. Lmquat*. in SouthAmerica. Tenpar* in Spain. EnvironmentalGuidelines HAZARDS: Fish:Slightlytaxic.Bird: Moderately toxic. SOIL PARTICLEADSORPTION: Strongly absorbed and inactivated by soil particles. SOLUBILITY: Dichloride saltis freely soiubleinwater. safetyGuidelines 

### SIGNALWORD:

### DANGER-POISON. MXlCrrYCLASS:1. 

## !bhc~ (Rat): Oral 

### LD, 150mgkg. PROTECTnrE CLOTHING: Rubber gloves and eye protedion when handling concenfxate.Wash youreelf-and your work dothas after us- ing tbeproduct. HANDLINGAND 

### STORAGECAUTIONS: Eye contectmay cawinjury. Cantact withirritated ski- ora cut,or repeated contact with intact &in will cause severe irrihtionandmay result injmisoning. Inhalation exposure may cause irritation, nosebleeds and may lead to poisoning.Keep outof reachof children. EmergencyGuideXinea 

### FIRSTAID: Get medical aid. &es, immediahty fluah with water for at least 15 minutes. 

### Slun. wash with soap and water. moveand wash allmntaminated clohngwith ,soapand hot water before reuse. J ' ' immediatdy get away from spray mist. hg&ui, induce vomiting by inserting linger in that.Administer fluids and induce furthervomiting. Rompttreatment isessential and mustbe initiated before sigm and symptoms of injuryappear. Paraquate' 

### -eee Paraquat. Paraslte An org+sm thatlives in or on a living plant oranimal (calleda host) 'and obtains all or part of its nutrients from it. A parasite is usually smaller thanitshost, andusually does notkill the host;however, under epidemicwnditiom thehmtmay be killed. Tapeworms, lice, and fleasareparasitic animals. Rust, smut,mildew, dodder,and mistletoe are examplesofparasitic pianh Parasul*

### -seeMethyl Parathion. Paratap 

### -seeMethyl Parathion. Parathion BF: CAC (Shanghai) International Trading Co.,Ltd. ChemEast S.A. CheminmAIS diangnu Over~eas Group SmodaGo., Ltd. (Fighe) ShanghaiZhmgxi (Group) Corp. ShenzheaJiangshanCommerce & IndustryCorp. Identlfhtion 

### COMMON

### NAME:Parathion(ISO,BSI,JMAF, 

### EW; thiophos WSSR). TRIVIAL

### NAME:Ethyl Parathion. 

### EX!'. CODE NLMBERS:

### AC 3422, E-605. OTHER CODE NUMBERS: CAS 56-3&2; 

### SHA 057501; 

### OMS 19 

### (WHO); ENT 15108;EINlECS 200-271-7. FORMULATORS'TRADE NAFAES:FaratioaMetilicn*(Agroquimims Versa, SAde C.V.) ChimacPar 

### H*(ChimaeAgnphar 

### SA.) Pox Konz* (Diachem S.p.A.1 Woprophos* (B.V. Industrie- & Handelsondernerning S~OU~B) Alhn*,Aileron*, Aphamite*, Cmothion*, Etilon*, Orthophm*,Panthion*,Paramar*,Phoskil*, Rhodiatox*, Soprathion*, Stathim*. DISCONTINUEDNAMES:Tbioh*Man Cydd Co.) Tam- 

### -* EP (+mehmiduphos), Ecombi* (+oxydemeh-methyl),Eladan*, Folidol (Bayed 0 &ion* (+aein~hos-ethyl 

### +azinphas-methyl) (Che?lagm Carp.) PanncapE*(ElfAtochem)

# . Fcmhm M)* (ICI chmnds) Niran* (+ chlordane),Wallop

### G*(+ pmpchlor)(M-to mtural Co.) Drifene* (+ die&), Drifme* A P. (+ endcaulfad (PechingrPro$) Eada Hua* (+ &uhn) (Platte Co.1 Sytemp*(+methyl par~w + kphene)(RingAround Products) 

### ' Roethyl-P* (RotamGmup) Bpwam* I+hdalw)(SmPR41.

Information is presented hemin for preliminary planning only. Exclusive reliance must be placed on informatioddirectionssupplied by manufacturer. FARM CHEMICALS HANDBOOK200 1

## ZENECA Ag 

## Products
MATERIAL SAFETY DATA 

## SHEET
GRAMOXONE

### MAX
Version: 3 Date 

### issued: 04/29/99 MSDS 

### Ha. UB006204_01 Date 

### printed: 05/10/99

Section 1

# - CHEMICALPRODUCTAND 

### COMPANY IDENTIFICATION
Company

Phone 

### number Emergency 

### phone : 

### Zeneca Agricultural 

### Products 1800 Concord Pike WiLmington 

### DE 19850
: 

### (302) 886-1000
: 

### Medical: 

### 800-327-8633 (1-800 FASTMED)

Cherntrec: 

### 800-424-9300 Technical:302-886-3000

Name used 

### on label : GRAMOXONE MAX 

### Product use : 

### Herbicide

A Registered 

### Trade Mark 

### of a Zeneca Group Company.



### Section2 

### -COMPOSITION/LNFORMATIONON 

### INGREDIENTS Identity CAS-no. 

### mica1 % 

### Paraquat 

### dichloride 1910-42-5 

### 43.8 % 

## I inerts 

## I 56.2 

### 8 Other 

### information

Ingredients not 

### precisely identified 

### are proprietary or 

### non 

### hazardous Values 

### are not 

### product specifications.



### Section 3

# -HAZARDS FDENTIFICATION
Physical 

### hazards: None
Health 

### hazards: Irritant 

### (skin 

### with prolonged contact), 

### irritant (eye, respiratory passages) 

### , inhalation(TLV) 

### , toxic (oral) May 

### be fatal 

### if swallowed. Harmful 

### if absorbed 

### through skin. Causes substantial 

### but temporary eye 

### injury.

Page 1of 10

## ZENECA Ag 

# Products
MATERIAL SAFETY 

## DATA SHEET
GRAMOXONE

### MAX
Version: 3 Date 

### issued: 

### 04/29/99 MSDSNo. US006204-01 Date printed: 05/10/99

Section 

### 4

# -FIRST AIDMEASURES

GENERAL 

### ADVICE: Call 

### Zeneca's 24 hour Energency 

### Information Network 

### at 1-800-FASTMED (327-8633) If 

### a known exposure 

### occurs 

### or is suspected, immediately start 

### the recommended procedures 

### below. IMMEDIATE 

### TREATMENT IS ESSENTIAL.



### IF IN 

### EYES: Immediately 

### flush with plenty 

### of water 

### for at least 

### 15 minutes. 

### Obtain medical attention.



### IF ON SKIN: Take 

### off immediately 

### all contaminated 

### clothing. Wash 

### material off 

### the 

### skin with plenty of 

### soap and water. 

### Obtain medical 

### attention.



### IF SWALLOWED: Immediately 

### induce vomiting by touching 

### back of throat 

### with finger. 

### Give
one or 

### more glasses of water to drink 

### and induce 

### further vomiting. Repeat 

### until vomit 

### is clear. ~f person is 

### unconscious 

### do not 

### give anything 

### by 

### mouth and do not 

### induce vomiting. 

### GET IMMEDIATE MEDICAL ATTENTION. Take 

### container and labeling 

### with you. 

### See section 

### on MEDICAL ADVICE.



### IF 

### INHALED: Remove victim to fresh 

### air. If 

### not breathing, 

### give 

### artificial respiration, preferably 

### mouth-to-mouth. Get medical attention. Inhalation 

### is an 

### unlikely route 

### of exposure 

### due 

### to low 

### vapor 

### pressure and large 

### spray droplet size, but mucosal 

### irritation 

### or nose bleeds may 

### occur. The odor 

### of this product 

### is NOT 

### paraquat; it 

### is an added 

### odorant intended to 

### deter ingestion 

### of this product.

MEDICAL ADVICE: CALL ZmCA'S 

### MEDICAL EMERGENCY 

### INFORMATION NETWORK AT 

### 1-800-327-8633 [Dial 

### 1-800-F-A-S-T-M-E-D) 

### at any 

### hour to 

### obtain toxicology and medical management consultation 

### and paraquat analyses. Prompt treatment is essential 

### and must 

### be initiated immediately 

### before signs and 

### symptoms appear. Symptoms are 

### prolonged 

### and painful 

### and may 

### be delayed 

### for days 

### after swallowing. Treatment may 

### include binding 

### paraquat in 

### the gut with suspensions 

### of clay 

### or charcoal; 

### and removal 

### of paraquat 

### from the blood 

### by prolonged charcoal hernodialysis. 

### Do NOT administer oxygen; oxygen potentiates the toxicity 

### of paraquat. Probable mucosal damage 

### may contraindicate the 

### use of gastric 

### lavage.

Page 2of 10

## ZENECA Ag 

# Products

GRAMOXONE

### MAX
Version: 3 

## MATERIAL 

## SAFETY DATA SHEET

Date issued: 04/29/99 =DES No. US006204-01 

### Date printed: 05/10/99



### Section 5 

### - FIRE FIGHTINGMEASURES
Flash point : > 

### 90 Oc 

### no flash point due 

### to high water 

### content Autoignition 

### temperature : r 625 OC 

### no ignition 

### Explosive properties : 

### LEL: Non-explosive. EXTINGUISHING MEDIA: 

### For 

### small fires, use foam, carbon 

### dioxide 

### or dry powder extinguishant. 

### For 

### large fires, use 

### foam 

### or water-fog; 

### avoid use 

### of water jet. Contain 

### run-off water with, 

### for example, temporary 

### earth 

### barriers. FIRE 

### AND EXPLOSION HAZARDS: 

### Technical 

### aqueous 

### solutions present 

### no ignition 

### hazards. The 

### pure 

### material may support 

### combustion. Keep fire 

### exposed 

### containers 

### cool by 

### spraying with water. PROTECTIVE EQUIPMENT: A self 

### contained breathing apparatus and suitable protective clothing must be 

### worn 

### in fire conditions. 

### ADDITIONAL INFORMATION: 

### We 

### assigned NFPA 

### and HMIS'ratings to 

### this product based 

### on the 

### hazards of its 

### ingredient(s). Because 

### the customer is most aware 

### of 

### the application 

### of the product, 

### he must ensure that the proper 

### personal protective equipment 

### (PPE) 

### is provided consistent 

### with information contained in 

### the 

### product msds. 

### NFPA RATING Health 3 

### Fire

### 0 Reactivity 1 

### HMIS RATING 

### Health 

### 3 Fire0 Reactivity 1



### Page 3of 

### 10

# ZENECA Ag 

## Products
MATERIAL SAFETY 

## DATA SHEET
GRAMOXONE

## MAX
Version: 3 Date 

### issued: 04/29/99 MSDS NO. US006~0~-01 Date 

### printed: 

### 05/10/99

Section 6 

### -ACCIDENTAL 

### RELEASE MEASURES

PERSONAL PRECAUTIONS: Wear 

### skin, eye and 

### respiratory protection during 

### clean up. 

### Spread 

### a suitable 

### absorbent such 

### as clay 

### on the spill, and 

### shovel into an open 

### drum. Untreated 

### spilled material 

### can dry to 

### a 

### highly irritating dust. 

### For chemical emergency: 

### spill, leak, 

### fire, exposure 

### or accident 

### call CHEMTREC 

### 1-800-424-9300. 

### ENVIRONMENTAL PRECAUTIONS: 

### Do not contaminate 

### waterways by 

### cleaning 

### of equipment 

### or by 

### disposal of wastes. Although 

### paraquat 

### is not 

### a RCRA 

### hazardous 

### waste, it 

### is recommended 

### that the 

### waste 

### be disposed 

### of in 

### a facility permitted 

### for 

### hazardous waste.

Section 7

### -HANDLING

### AND STORAGE

SAFE HANDLING ADVICE: Avoid contact 

### with 

### skin and eyes. Avoid 

### inhalation of high concentrations 

### of dusts. Avoid 

### inhalation of 

### liquid aerosols. REQUIREMENTS 

### FOR STOMGE ROOMS: Empty 

### container retains product 

### residue. Triple 

### rinse, or 

### equivalent, empty 

### container, return 

### rinse water to dilution 

### mixture, and dispose 

### of dilution mixture 

### as a hazardous waste 

### if it 

### cannot be disposed 

### of by use according 

### to label instructions. Do not reuse 

### container. Offer it for recycling 

### or reconditioning, 

### or puncture and dispose of 

### in properly permitted 

### landfill.



### Section8 

### -EXPOSURE CONTROLS/

### PERSONAL

### PROTECTION Occupational 

### emosure limits ZENECA 

### Standard 

### on: PARAQUAT 

### EMETIC TECHNICAL 8 

### hr TWA 

### 0.02 mg/m3 ZENECA 

### Standard 

### on: Paraquat 

### dichloride (Respirable Dust) TWA 

### 0.1 mg/mg 

### (Total Dust) TWA 0.5 mg/m3 TLV/ACGIH 

### Paraquat 

### dichloride 8 Hour TWA 

### 0.1 rng/rnj OSHA PEL Paraquat dichloride (Total Dust) 

### 8 Hour TWA 0.5 mg/m3 Occupational 

### exposure 

### standards ENGINEERING CONTROLS:
Page 4 

### of 10

## ZENECA Ag 

# Products
MATERIAL SAFETY DATA SHEET
GRAMOXONE

## MAX
Version: 3 Date issued: 

### 04/29/99 MSDS NO. U8006204-01 Date printed: 05/10/99



### VENTILATION: Use ventilation adequate to 

### maintain safe levels. 

### This product 

### is intended for use 

### outdoors 

### where engineering controls are not necessary. 

### If use 

### conditions 

### are different (e.g. 

### product 

### reformulation 

### or repackaging), 

### use ventilation adequate to maintain 

### safe levels. 

### EYE 

### PROTECTION: Use protective 

### eyewear. BODY 

### PROTECTION: This 

### product 

### is FIFRA regulated. Refer 

### to 

### product 

### labeling 

### for end-user 

### Personal Protection 

### requirements. Applicators 

### must wear long-sleeved shirt and long 

### pants, waterproof 

### gloves, shoes 

### and socks. 

### Mixers and 

### loaders must 

### wear long-sleeved 

### shirt and 

### long pants, waterproof 

### gloves, 

### shoes and socks, 

### face shield and chemical resistant apron. Remove 

### any contaminated clothing promptly. Zeneca Inc. conducted 

### ASTM 

### permeation tests 

### using PVC 

### gloves (0.2mm 

### thickness) and 

### showed no breakthrough of 

### the product 

### after eight 

### hours of testing. HYGENIC 

### MEASURES: Users 

### should wash 

### hands before 

### eating, drinking, 

### chewing gum, using tobacco or 

### using 

### the toilet. 

### Remove clothing 

### immediately 

### if pesticide gets 

### inside. Then wash thoroughly and put 

### on 

### clean clothing. Remove PPE 

### immediately after handling this 

### product. Wash 

### the 

### outside 

### of gloves 

### before removing. 

### As 

### soon 

### as possible, wash thoroughly 

### and 

### change into clean 

### clothing. Other protective equipment: Eyewash station 

### and safety 

### shower 

### in work area.



### !kction 9

# -PHYSICALAND 

### CHEMICALPROPERTlES 

## 1 Physical state 

## I Color 

## I Odor

Boiling point Melting point 

### Vapor Pressure

Vapour density 

## I Specific gravity:



### Solubility pH-value (quant.) Oxidizing properties : 

### liquid dark 

### green strong 

### pungent approx 100 OC aqueous solution 

### Not available. 23.7 nun Hg 

### at 25 OC Due 

### to 

### water, paraquat has negligible vapor pressure.

No data 1.132 

### soluble in/with water 5solution 5 % 

### Not applicable.

Page 5of 

### 10

## ZENECA Ag 

## Products mTERIAL 

## SAFETY DATA SHEET
GRAMOXONEMAX
Version: 3 

### Date issued: 

### 04/29/99 MSDS 

### No. US006204-01 

### Date printed: 

### 05/10/99



### Section 10 

### - STABKWYAND REACTIVJTY

HAZARDOUS 

### REACTIONS (CONDITIONS TO AVOID) Stable in acidic and 

### neutral solution; decomposed by alkali 

### and 

### in the presence of U.V. light. Compound 

### inactivated by adsorption 

### onto inert 

### clay. HAZARDOUS 

### REACTIONS (MATERIALS 

### TO 

### AVOID) Hydrolyzes 

### in alkaline media. 

### This product reacts 

### with 

### aluminum to 

### produce hydrogen gas. 

### Do 

### not mix or 

### store 

### in containers 

### or systems 

### made of 

### aluminum or having 

### aluminum fittings. HAZARWUS 

### DECOMPOSITION PRODUCTS Combustion products 

### of dry material: 

### Carbon dioxide, carbon 

### monoxide, chlorine, hydrogen 

### chloride, possible 

### trace arnouxlts 

### of phosgene, nitrogen oxides, 

### ammonia, 

### and other 

### toxic and 

### noxious fumes.



### Section 

### 11

# -TOXICOLOGICALINFORMATION

ACUTE 

### TOXICITY (LETHAL DOSES)

LD50 

### Oral 

### female rats Dose : 283 mg formulation/kg
Additional 

### inform. : An 

### emetic 

### is included 

### in the 

### formulation to induce vomiting. Signs and symptoms 

### following ingestion include 

### burning sensations, ulcerations 

### of the mouth, 

### tongue, pharynx 

### and esophagus; 

### vomiting, retching, 

### and diarrhea may then 

### ensue. A 

### 1 to 3 

### week period of progressive kidney 

### failure, liver complications, 

### and pulmonary insufficiency may 

### follow. Death is 

### usually due to 

### respiratory 

### failure 

### secondary to 

### pulmonary 

### fibrosis.

LD50 Dermal rat 

### Dose
Additional inform. : Intact 

### skin 

### is a very effective barrier to paraquat. 

### If extreme damage occurs this barrier is 

### removed and, 

### in the 

### presence of 

### sufficient paraquat, 

### absorption of toxic mounts may 

### occur. Lung, kidney 

### and liver 

### injuries 

### can ensue, followed 

### by renal 

### and pulmonary insufficiency. 

### Death ensues after respiratory 

### failure.
Repeated and/or prolonged 

### skin contact 

### with the concentrated product can cause 

### skin damage, including Page 

### 6of 10

### ZENECA 

### Ag 

# Products
MATERIAL SAFETY 

## DATA SHEET
GRAMOXONEMAX
Version: 3 Date issued: 

### 04/29/99 MSDS No. US006204-01 

### Date printed: 

### 05/10/99

erythema, edema, 

### and ulceration. Repeated 

### and/or prolonged 

### skin contact 

### with the spray 

### dilution may 

### cause mild skin irritation. Paraquat penetrates intact 

### human skin 

### very slowly 

### at 

### a rate 

### of less than 0.5% in 

### 24 

### hours. Penetration is 

### faster through 

### injured 

### or damaged 

### skin. Contamination 

### of nail 

### base 

### with concentrate 

### may cause 

### the formation 

### of white spots 

### on the 

### nail or, 

### in severe cases, transverse cracking and 

### loss of nail. 

### Normal growth 

### follows without delay.

LC50 

### Inhalation Dose : 0.6 

# .. 1.4 pg cation/l Period : 

### 4 hours Additional inform. : Paraquat is not volatile; 

### therefore, exposure to paraquat vapor 

### is not applicable. 

### Prolonged inhalation
or 

### overexposure to aerosolized 

### paraquat can cause irritation 

### of the upper respiratory tract 

### mucosa, as evidenced by 

### a burning 

### sensation, 

### nose bleeds, and sore throat. 

### These symptoms remit 

### on cessation of exposure. Systemic 

### toxicity 

### is unlikely to 

### develop following 

### inhalation because typical 

### spray droplets 

### are not likely to 

### be 

### of respirable 

### size.

ACUTE 

### TOXICITY (IRRITATION, 

### SENSITIZATION ETC.)
Eye Irritation Results : Moderate irritant to 

### rabbit eyes. 

### Additional inform. : Will cause eye irritation 

### in man. 

### This material 

### has a 

### delayed eye irritation effect. 

### May 

### lead to ulceration of cornea 

### and conjuctival epithelium 

### giving rise to 

### secondary 

### infection. Although healing may 

### be slow, the 

### injury is 

### superficial and 

### with proper 

### medical care recovery 

### will be complete, even 

### in severe cases.
Skin Irritation 

### Results : Slight 

### irritant to 

### rabbit skin. Additional inform. : Can cause inflammation 

### and in 

### severe cases blistering 

### of the 

### skin 

### with prolonged contact to undiluted product.
Skin Sensitization - 

### M&K Results : It is 

### not a skin sensitizer in 

### animal tests.

DELAYED OR CHRONIC TOXICOLOGICAL EFFECTS



### Page 7of 10

### Z-CA 

### Ag 

# Products
MATERIAL SAFETY DATA 

## SHEET
GRAMOXONE

### MAX
Version: 3 Date issued: 

### 04/29/99 MSDS 

### No. WS006204-01 Date 

### printed: 05/10/99

Long Term Exposure Symptoms

(rat). 

### Symptoms

NOEL



### (rat)


## . symptoms



### NOEL : 

### Studies in 

### animals have 

### shown that repeated doses do 

### not produce carcinogenic or teratogenic 

### effects.

: A 

### study 

### in animals has 

### shown that 

### repeated 

### doses

produce no adverse 

### reproductive effects.
: 150 ppm paraquat diet

: 

### Signs of 

### a proliferative lesion 

### in the epithelium 

### of

lung 

### alveoli in 

### rats. There was no 

### clear-cut evidence of 

### oncogenic potential.

: 

### 25 ppm paraquat diet over 

### 2 years
GENERAL INFORMATION 

### ABOUT ACUTE OR 

### OTHER TOXICITIES 

### General information 

### The health hazard 

### assessment is 

### based 

### on the results 

### of animal toxicity 

### testing 

### and reports of 

### accidental human exposures.



### Section 

### 12

### -ECOLOGICAL INFORMATION

ELIMINATION


### Additional inform. : There 

### is evidence of photodegradation 

### in air.

ADDITIONAL INFORMATION 

### ABOUT ECOLOGY 

### Toxic to wildlife.



### Section 13

### -DISPOSAL 

### CONSIDERATIONS

Empty container 

### retains product residue. Triple 

### rinse, 

### or equivalent, empty container, return 

### rinse water to dilution 

### mixture, 

### and dispose 

### of dilution mixture as a 

### hazardous waste 

### if it cannot 

### be disposed of by 

### use according to 

### label 

### instructions. 

### Do not 

### reuse container. Offer it 

### for recycling 

### or reconditioning, 

### or puncture 

### and dispose 

### of in properly permitted landfill. 

### Do 

### not discharge effluent containing 

### this product into lakes, 

### streams, ponds, 

### estuaries, oceans, 

### or public waters 

### unless this product 

### is specifically identified 

### and addressed 

### in a National Pollutant 

### Discharge Elimination System (NPDES ) permit.



### Page 8 

### of 10

## ZENECA Ag 

# Products
MATERIAL 

# SAFETY DATA 

## SHEET
GRAMOXONE MAX
Version: 3 Date 

### issued: 04/29/99 MSDS 

### No. USOO6204-01 

### Date printed: 

### 05/10/99

Won 14

# - TRANSPORT

### INFORMATION

ROAD TRANSPORT 

### DOT Proper Shipping 

### Name : BIPYRIDILIUM 

### PESTICIDE, LIQUID, 

### TOXIC, (contains 

### paraquat as 

### dichloride salt) Class : 6.1 UN 

### No. : 

### UN3016 Packaging group : / I11

Section 15 

### - REGULATORYINFORMATION

HAZARDOUS INGREDIENTS 

## I Paraquat dichloride

Other 

### regulations, restrictions 

### and 

### prohibitions

TSCA (Toxic Substances 

### Control Act) Regulations, 40CFR 

### 710: 

### This is a FIFRA-regulated pesticide 

### and is exempt 

### from TSCA 

### regulations.

CERCLA and SARA Regulations 

### (40 CFR 

### 355, 370, and 372): Section 313 Supplier Notification. 

### This product 

### contains the 

### following 

### toxic chemicals subject to 

### the reporting requirements 

### of Section 

### 313 of 

### the Emergency Planning and Community Right-To-Know 

### Act 

### of 1986 and of 40 CFR 

### 372: Paraquat dichloride 

### (CAS 1910-42-5) 

### The 

### Threshold Planning Quantity (TPQ) 

### under EPCRA 

### SARA 

### (Section 302) for Paraquat 

### dichloride 

### is 10 

### lbs.

Other Determined 

### Regulations: None

EPA EPA Registration 

### no.: 10182-372



### Section 16

# - OTHER INFORMATION

ZENECA Ag Products believes 

### that the information and recommendations 

### contained 

### herein 

### (including data and statements) 

### are accurate as 

### of the date thereof. NO 

### WARRANTY OF FITNESS FOR 

### ANY PARTICULAR PURPOSE, WARRANTY OF MERCHANTABILITY, OR 

### ANY OTHER WARRANTY, EXPRESS OR IMPLIED, IS 

### MADE CONCERNING THE INFORMATION PROVIDED 

### HEREIN. The 

### information provided herein relates to the specific 

### product designated 

### and may not 

### be valid 

### where such product 

### is used 

### in combination with any other 

### materials or 

### in any 

### process. Further, 

### since
Page 

### 9 of 10

## ZENECA Ag 

# Products
MATERIAL SAFETY 

## DATA S-ET
GRAMOXONJ3

## MAX
Version: 

### 3 Date issued: 04/29/99 MSDS 

### NO* WS006204-01 Date 

### printed: 

### 05/10/99

the 

### conditions 

### and methods 

### of use 

### of the 

### product 

### and 

### of the 

### information 

### referred to herein 

### are beyond the 

### control 

### of ZENECA Ag 

### Products, ZENECA Ag 

### Products expressly 

### disclaims any 

### and all liability 

### as to any 

### results obtained 

### or arising 

### from any use of the product 

### or reliance on such 

### information.

A 

### vertical bar 

## (1) in the left margin 

### indicates an amendment 

### from 

### the previous 

### version.

Page 10of 10