# RMB

# Gonsulting & Research, Inc.

5104 Bur Oak Circle Raleigh, North Caroli 

### na 27 612



### September 

## 2I,2009

Mr. Ron 

### Myers, D243-05 Measurement 

### Policy Group 

## U. S. 

### Environmental Protection Agency Research 

### Triangle Park, 

### NC 27109 Phone (919) 510-5102 

# FAX (919) 510-5104



# Re: Condensable Particulate 

### Matter (CPM) Test Report 

### for Coal-Fired Power Plant Submitted 

### for Rulemaking Docket 

### EPA-HQ-OAR-2008-0348
Dear Ron, Enclosed, please 

## find a 

### copy 

### of the above-referenced test 

## report. The 

### unit tested 

### is an

### electric 

## utility generating 

## unit (EGU) that burns eastern 

### bituminous coal and has a 

### nameplate 

### rating 

## in excess

## of 500

## MV/. The 

### unit has a

### selective catalytic 

### reduction (SCR) system 

### for NOx control; a 

### cold-side electrostatic 

### precipitator (ESP)

### for PM control, and a

### flue gas 

### desulfurization (FGD) system 

## for SOz 

### control.
The enclosed 

### report describes 

### the results 

### of a

### test 

### program 

### in which three independent sampling runs were conducted simultaneously using: (1) 

### EPA Method 5/202; (2) 

### EPA Method 

## 5/OTM 28; and 

### (3) Conditional Test 

### Method 

## (CTM) 

## 138. I believe thesetest 

### results 

### provide additional technical support 

## for some 

### of the comments we have 

### previously submitted 

### in regards 

### to Other Test 

### Method 

## (OTM) 28 andthe subsequently 

### proposed amendments 

### to 

### EPA 

## Method2}2.r'2 V/hile the 

### report contains lots 

### of data, the 

### results are

## well summarized 

### in Table 1 

### (p. 

## 3). Table 1 

### shows 

### that 

## OTM 28was 

### effective 

## in reducing some 

### of the (sulfate) biases 

### (0.041 versus 

### 0.023 lb/106 

### Btu) that have 

### historically plagued 

### EPA Method2O2.3 Unfortunately, Table 1 

### also shows 

### that the

## OTM 28 results are 

### over 2

### times (0.023 versus 0.0101b/106 

### Btu) the results obtained 

### from the

### controlled condensation method, 

### indicating to me 

### that a

### sulfate bias is

## still present. As you may remember, 

### while we agreedthat 

### the

## OTM 28 approach 

### (a.k.a. dry 

### impinger method) 

### could lessen 

### the sulfate bias as 

### compared

### to original Method 202 procedures, 

### we questioned

# if OTM 28

### would be a

### satisfactory 

### solution

## for all sources, 

### especially those 

### employing wet 

## pollution control technology. 

## I believe the 

### EPRI research, also 

### only performed 

### only on simulated 

### flue gas,

### showed that the effectiveness 

### ofthe 

## "dry impinger method" could be 

### compromised under more 

### challengingflue gas 

## conditions. 

## I only skimmed the

## field data sheets 

### in the enclosed report, 

### but I believe 80

### to 90 

## ml of condensate was 

### collected 

## for each

## OTM 28 

## run. In other words, the dry 

### impingers do 

### not stay 

### dry very 

### long, especially 

## for wet stacks.

' I4 Fed. P(eg. 1297 0 

### (Malch 25, 2009). 2 See,

### for example, Comments of the 

### Utility Air Regulatory Group, 

### May 26,2009, Docket EPA-HQ-OAR-2008- 0348-0049. 3

### In this letter, when refelence is made to Method 202,we are referring to the method EPA published at 56 Fed. Reg. 65435 (December 17, 1991).

## LETTER

# - Ron Myers

September 

## 21,2009 Page2 

## Notto get ahead

### of myself, but there 

### is another test 

### report, 

### which reflects a 

### quite 

### different plant configuration that 

## I am

### trying to get 

### finished and 

### delivered to

## you. That 

### unit burns 

### subbituminous coal and has a 

### spray 

### dryer absorber 

### (SDA) followed by a

### fabric

## filter. Because 

## of the

## fuel characteristics 

## (low sulfur and 

### high 

## alkalinity ash) and 

### the 

## pollution control technology, 

### combustion experts

### would doubt the presence 

### of measurable 

### concentration 

## of CPM. 

### Unfortunately, 

## OTM 28 

## "finds" the 

### CPM concentration to be 

### more than 

### twice the 

### filterable 

## pM concentration. 

## If you have any questions 

### regarding this enclosed test 

### report, please 

### do 

### not hesitate 

### to contact me at 

### loberson@rmb-consulting.com or (919) 510-O3l 6.


### Respectfully submitted,



### Ralph 

## L. Roberson, P.E. 

### Principal
Enclosure

# >JACG I

# lnformationat Test

Report

# for Gondensable 

# Particulate Matter and 

# Gontrolled Gondensation 

# forthe (Anonymous) åfí."äi,#^ï"åX, 

# lstack at (Anonymous) Fï,",ij8,?luouo#"

# lPower 

# Station
Pennsylvania Office 44e

### veir

# Road I 

# Prepared

# for lilii:lirrryãrrev' PA 

## 1e006 

## |

# {nnonv-ous) Fax: 

### (215) 

### 3644596



# Test 

# Date¡: June 10

# -,,1r 2OOg 

# Report 

# Date: August 1Tt 2OOg

ACG Contract Number 

## [private]

## 3.0



## 4.0 

# 2.0 Summary 

# of Results 

# Discussion of

# Results ..................7 

# Sampling and

# Analytical 

# Procedures .........7 

# 4.1 Sampling

# Procedures..............

.............. g 

## 4.1.1 Sampling Point Determination 

## - EpA Method 1............................... g 

## 4.1.2 Volumetric Measurements 

## - EpA

# Method2...........

............... g 

# 4.1.3 MolecularWeight Determination 

## - EpA Method

# 3.......

......... g 

# 4.1.4 Flue Gas Moisture Content 

## - EpA Method

# 4.....,..

............ 11 

# 4.1.5 Particulate Sampting 

## - 

## EpA Method

# St2O2

................... 11 

# 4.1.5.1 Sampling 

## Train

# Description .......1j 

# 4.1.5.2 Sampling 

## Train

# Operation. ............1j 

# 4.1.5.3 Sample 

# RecoveryandClean-Up.......... ..............12 

# 4.1.5.4 

# Blank ...............12 

# 4.1.6 Particulate Sampting 

## - EpA Method

# S/OTM-28 .......14 

# 4.1.6.1 Sampling 

## Train

# Description ...........14 

# 4.1.6.2 Sampling 

## Train

# Operation......... ..............14 

# 4.1.6.3 Sample Recovery and

# Clean-Up.......... ......16 

# 4.1.6.4 

# Blank ...........17 

## 4.1.7 condensable 

## sos/Hzsoa sampring 

## - EpA Method 

## crM-01 3P

..... 

### 17 

# 4.1.7.1 Sampling 

## Train

# Description .....17 

# 4.1.7.2 Sampling 

## Train

# Operation........

......... 1T 

# 4.1.7.3 Sample Recovery and

# Clean-Up..........

.............. 1g 

# 4.1.7.4 

# Blank

.................. 1g 

# 4.2 Analytical 

# Procedures.........

.......... 1g 

# 4.2.1 Molecular 

## Weight Determination 

## - EpA Method 

## 3A....................... 1g 

# 4.2.2 Moisture Content 

## - EPA Method

# 4..............

....... 1g 

# 4.2.3 condensable Particulate 

## Analyses

## - EpA Method 202 

## .................20 

## 4.2.4 condensabte Particulate 

## Analyses 

## - EpA Method 

## oTM-29 ..........20 

## 4.2.5 condensable 

## soa/Hzsoa Analyses 

## - EpA Method 

## crM-1 gB 

## .......21 

# 4.3 Data

# Analysis........ ...........21 

# 4.4 Equipment 

# Calibration............... ............22

# LIST OF 

# TABLES

Table 1

### - 

## Overall Summary 

# of (Anonymous) 

## Average

# Emissions

........ 3 

## Table 2 

## - Summary of 

## Total Suspended particutate (TSp)

Emissions 

## by EPA Method Sl2O2 

### Anatysis 

## - (Anonymous)


# ....... ........4 Table 3 

## - Summary of

## Total Suspended particutate (TSp)

Emissions by EPA Method 

## 5/orM-28 Analysis -

# (Anonymous)...

........ 

## s Table 

## 4 - 

## Summary of H2SO¿, 

### SOs, 

### and SOz



### Emissions by Conditionat 

## Test Method 138

# ...... ...........6



# LIST 

# OF FIGURES Figure 1

## - EPA Method 

## 5sampling and 

## rraverse points: (Anonymous) 

## stack............... g 

### Figure 

## 2 -EPA Method 3 

### Sampting

# Train........

..... 10 

### Figure 3

## - EPA Method 5 

### Sampling

# Train.

.. .......... 13 

### Figure 

## 4

## - EPA Method S/OTM 028 Sampting

# Train

.... 15 

### Figure 5 

## - EPA Method 

## CTM-0138 Sampting

# Train....

..... 19

# APPENDICES

AppendixA-TestLog Appendix B - Data 

## and Results Appendix 8.1 

## - EPA 

## Method 5t202 Data 

## and Results 

## Appendix 8.2 

## - EPA Method 

## 5/OTM-28 Data 

## and Results 

## Appendix 8.2 

## - EPA Method 

## CTM 138 Data 

## and Results 

## Appendix C

# - Equations 

## Appendix D

## - Raw 

## Field Data 

## Appendix D.1 

## - EPA 

## Method 5t202 Raw Fietd Data 

## Appendix 

## D.2-EPA Method S/OTM-28 Raw Fietd Data 

## Appendix D.3 

## - EPA Method 

## CTM 138 Raw Fietd Data 

## Appendix E -

## Analytical Data 

## Appendix E.1 

### -

## Analytical Gravimetric Data 

## for EPA 

## Method Sl2}2Analyses Appendix E.2 

### -

## Analytical Data 

## for EpA Method 

# crM 138 

## Analysis Appendix E.3 -

## Analyticat Data

## for EpA Method OTM-28 Analysis 

## Appendix E.4 -

## Analytical Data

## for 02 

## and

## coz Analyses of lniegrated Bags 

## Appendix F

## - Field Equipment Galibration Data 

## Appendix G 

## - 

## Facility Data

ilt

# Executive Summary

Air emissions 

## stack tests 

## were conducted at

## the (Anonymous) power Station on the 

## stack serving (Anonymous) to

## satisff the 

## diagnostic requirements set 

## by (Anonymous). The

## Air Compliance Group, LLC (ACG) 

## of Roanoke, 

## Virginia, conducted the

## test program on

## June 10 

## and 11 

### , 2009. Three 

## valid EPA Method 2O2, 

### CTM 

## 138, and OTM

## 28tests, 

## for the 

## determination of 

## Condensable Particulate Matter 

## (CpM) emissions 

## were completed on

## the (Anonymous) 

## stack. All pollutant sampling 

## was accompanied by 

## measurements of

## thetemperature, static 

## pressure, moisture 

## content, molecular weight, 

## velocity, and 

## volumetric flow rate of theflue 

## gas. The testing 

## was conducted in 

### accordance 

## withthe procedures of

## the Code 

## of Federat Regulations. Below are the 

## test results

# 1.0 lntroduction



# 1.1 Background An air

## emissionstest program 

## was be conducted on 

### (Anonymous) at

## the (Anonymous) power 

## station, located in (Anonymous 

## city), (Anonymous 

## State). The purpose of

## thetesting 

## was to evaluate 

## totalfilterable and 

## condensable particulate emissions 

## when measured by 

## ditferent EpA emission testing 

## procedures. The 

## filterable PM 

## emissions limitfor 

## thisfacility is 0.030 lb/mmbtu. The 

## test program 

## was conducted on

## June 10 

## and 11,2009 by The

## Air Compliance Group, LLC 

### (ACG) 

## of Roanoke, 

## Virginia. ACG personnel 

## participating in

## thetest program were Frank 

## craighead, Kenley Houtz, 

## Jared cypher, Aaron 

## cypher, Jason Hill, Michael 

## Wilson, and David Hill. [Un-named individual], 

## of (Anonymous) provided on-site project coordination.


# 1.2 Obiective The purpose of 

### the test 

### was to satisfu the 

### diagnostic requirements 

## set by (Anonymous) Power


# 1.3 Test

# Program Three 12O-minute 

### test runs for 

### condensable particulate matter, SO2, 

### and SO3/H2SOa 

## wêre conducted on

## the (Anonymous) 

## stack. Each 

## test run included 

## determination of 

## the given pollutant emissions, plus measurements 

## for gas temperature, moisture 

## content, molecular 

## weight, gas velocity and

## volumetric flow rate.

## Test runs

## were sampled in 

### conjunction with three of

## the EPA Method 5

### tests that were being run 

### to prove compliance.

# 2.0 Summary of Test Results

Table 1 

### is a 

## summary of the 

## averagetest results 

## from allthree 

## sampling methods 

## performed on (Anonymous). 

## Table 2 is a 

## summary of

## the EPA metho

## d 202 

### sampling, 

## Table 3 is a 

## summary of

## the EPA 

## method OTM-28 

## sampling, and Table 

## 4 is a summary of 

## the EPA method 

## CTM 138 sampling.



## Table 1

# - overall summary of (Anonymous) (Anonymous) Average Emissions EPA 

### Method Pollutant Reporting Units Emissions



### Limit Average

Emissions EPA Method 

### 5t202 Condensable Particulate Emissions lb/MMBtu (Oz based) N/A 0.041 EPA Method 

### s/OTM-28 NiA 0.023

EPA Method 

### 138 SO3 

### + 

### ¡1560 Emissions (as H2SO4) N/A 0.010

SO3 + 

## ¡r59a Emissions (as SO3) N/A 0.010

SOz Emissions N/A 0.064



### 3TAÊLE2 SU]ITIARY OF EPA TIEIHOD Ð2 GONDEflSGLE PARrþTT'IÍE TATTER EII1SSIOI¡S

EUN I.D. DATE ÏIMÊ STARTED fIMËENDED s0en6¿0âR5 06110r0s 

### &t{ f{r.t8 8û0-f,ãlito¿Rr



### Ë/lotlg l5rE5 1&{e 

### sll0{r6P@*8

06/1t/09 7:53 1ù,1t AVERAGE

GAT|IPUNG PARAilETERS UeûaodVotuna(d@ Ooneøed Wume(dscf) Totd lèslTlno (mr:n) l¡*ìneti<x (961 .GAS PÂRÃIIIETERS Gas To'llpor.tlÚl(.F) Oq¡gen (9É) Catôqrr Diorddc 

### (*) ûiloîst¡€ (9ó) EASFLOIIÍ RA?E våþdty(üqoê) Adrrd volumo (æ1Yn) Stsnda¡d Volurne (dsc{m) CONDÊI,|!¡IELE PAR¡lCtrLATE trISStONS Conc, (grfdsd) Itlass Rate (h/ht) tlaes Ralatlh/MMBùr) O2-bered

### . 93-¿t4ü 0r.475 1m 9t_0 

## s¡30

ôl-0rs 120 95.6 s0.628



### 833If 12i sü.6 94.8:Ì5

82.20 t2a 95.4

t07 1L0 3.5 7-2 

### lrF 14.O 3-2 7.1 107 14.0 ¿.0 t.7 107 14.0 

### s2 7.1

43.{E 

### 35lt¡æ z72owß

o.ot0 2d4ô8 o.04¡f4 49.44 3s131€1 269Ín1t

0.010 231.86 0.o+2ö 4Ð_il

35ãt664 2tl2&¿s
ol¡o8 1ù1Æ 0.û3.t8 ¡¡9.5f

35fe¡40 2708S8

0.0r0 z¿2.41 o.0406
'lbrf,tMBtu ìr¿luê based on F-lbctorof g7g0 dsüúftlMElu for t¡ifuminor¡¡ ooal lnTaôlc 

### i$2 of 40 OFR 60, Appendü A, Melhod 19.



## 4

### TABIEs SUI¡IIIIIRY OFTPA 

### Oilr ZC CONDENSIBLE PARITC-IJI¡TE MATÍER EIIISSIONg

RUNI.D. DAÎE ]rMESTARTED TIô,IEENDÉD 

### s00+toTti28d5A SOft-itoTit2ùR?A 

### s0GuoTilzt{8A 0at1ÆÁ TrSt 1e.17 AVËRAGE 06/f0/tt9 8tì4 10;¿18 0€/f0/09 l5:¡15 18;06
SAIIPLING PARAIìIETERS tyl€brcdVolu¡r¡e (dcf) Cor¡ecbd Volur¡e (dssf) Totd TeS?ïme{minl 

### ta*iuücs(?6) GAS PARA¡æTERS Gao 

### lerperaúre ("F) ,Otq,len (%) carbon Oioxitê (%) l\lt¡l*urc(%l
.GAS FLOT'I' RATE Veloclty (û$oc, AcütalVolune (acÉn) Sümded Vofune(dscfm) COIII}ENSIBLE PÄRTICUI.ATE E}IIEs K}NS Gonc- (grldscf) Mass Rate(lMrr) Mass RaE {tù/ùlll/8U}: O2-based. 90.410 78.670 

# In 912 s3.712

80.788 f20 c2.3

50,53 3590909 215132ø 95.325 81.818 12Q 94.2 93.t49

80.4!5 120 92.ö

107 14.2 3.5 7-4 105 14.2 3.1 7.O 109 14.0 

### 39 6.9 108 14.4 

### a5 8.4

¿[9.92 

### 3Éltt¿9 2710584

0.007 1f1.lo 0.0037 0.0û4 93.98 0.0175 

### oæ4 10û¡f ô-0r70 49.9t

3$9223 2'AÈÍITE 50.09 35õ9i¡21 273@96

0.005 12e69 o.oz3o 

## tlob. ' lMÍMB.tu røfues based on F{actD¡s lbr bii¡rrirous cæl h Tablc ,10,2 of 4o CFR 60. .Apperdlx A, [ilex,rod 19_

### TABLE4 SUIIMARY OF H2SO4 SO3, 

### ¡nd 

## so:l ElllssloilS BY COHDIT|oHAL TEST 

### ilETHOO 

### l3B

RUN I.D.



### , DATE TIME STARTED T¡f\,IE ENDED 

## s00.cf¡Í38.¡ul sotÞcTuf3Bfi3 s00-cTHt3Bfi4 0Añ1.99 7:50 

### 1ù17 AVERAGE 

### 0d10/0e 8:f)4 

### l0:48 06/10/0e

15:45 18:06


### SAIIPLING PARAMËTERS Mete¡ed Volume (dcf) Oonected 

### Vdurne(ds@ Total TestTìme (m[n) 

### .lsokinelics{%) G/IS PARATIETERS Gas Tempenature 

### ('F) Onruen(96) Carbon Dioxide (%) Molsture (%) GAS FLOIIY RATE Veloclty 

### (trsec) ActualVolume (acún) Stancfa¡d Volurne (dsclTn) 

### So3 + H2SO4 

### EillSgoNS (æ H2SO{) CorËênlfeüon (ppmdv) Mass RaÞ (lblhr) Mass 

### Raþ(lb/ltrlMBtuf 8O3 + H2SO¡I EIiIISSIONS(asSO3) Concenfration 

### þpmdv) Mass 

### Rab(b/tr) Mass 

### Rete(b/MMBt¡f


### soz EiltsstoNs Concenfatisr (pprnclv) Mass 

### Rata(fMrr) Mass Rata (lb¡lMMBürf 

### læ.404 91.738 120 9S.3

53-43 37S7181 2S03859

1_12 49.67 0.009

1.37 49-67 0.000

14.28 820-21 0.076 102-217

g2.622 12Ð 100.3

112 14.0 4.O ô.4

53-36 3791701 29036s-/

1,35 59.66 0.01o

1.65 5S.66 0.010

10.4€ 

## 4*.13 0.051 99-507

90.150 120 s8,8 t00.730

81.5(,3 

### 1m 99.õ

53.22 378f967 28e2272

1.33 58.ô0 0_010



# n.a &16.53 0.064 112 14.5 

### 2ß 6_6 

### 112 14.0 3_0 6.7 112 14-2 3.3 6.6

52,87 3757019 286S30f

1.52 66.46 0-011

1.86 

### 6t.46 0.011

13.17 565.25 0.0ô5 

### r.83 58-60 0.010



### 'IUMMBüJ values based 

### qr F-fâctors for bih.rminous c.oal inTable 1g-2 of ¡lO CFR 60, Appendix

## A r/þhod 

### lg.



## 6

# 3.0 Discussion 

# of Results

Testingwas conducted 

## as per

## thetest protocol, 

## dated May 5, 2OOg, 

### except for 

## the CTM 

## 138 trains, 

## which hadto omit 

## the coiled condenser due to 

## space restraints. No 

## further problems 

## were encountered 

## during the 

## execution of the 

## test program.


# 4.0 sampling and

# Analytical 

# Procedures sampting and anatyticat 

## procedures complied 

## with methods recommended 

## by USEPA in

## Appendix A to Tifle 40, 

### Part 

## 60 of

## the Code of Federal Regulations (a0 CFR 

## 60), or 

## other methods 

## accepted by 

## the USEPA. The following 

## specific methods 

## will be used:



# o EPA 

## Method 1

### for 

## determining sampling and

## traverse points; 

# o EPA Method 

## 2for 

## determining flue gas velocity and

## volumetricflow rate. 

# o EPA Methods 

## 3 (sampling procedure) 

## and 3A (analytical procedure) 

## for determining flue 

## gas composition and molecular weight; 

# o EPA Method 4for 

## determining flue gas moisture content; 

# o EPA 

## Method 5

### for 

## determining particulate emissions;



# . EPA Methods 202 and 

### OTM-28 for 

### determining condensable particulate emissions; and,



# . EPA Method 

## crM-O138 for 

## determining condensabre 

## sos/Hzso+.

7

### 4.1 

## Sampling Procedures



## 4-1-1 Sampling Point Determination - EPA 

## Method 

# 1 The procedures 

## of EpA Method 1

## were used to determine 

## the number 

## and location ofsampling and traverse 

## points at

## the stack. Twenty-four 

## sampling and 

## traverse points (six for 

## each of

## four ports in a 

## circular stack) 

## were used for sampling and 

## flow rate 

## measurements. Figure 1 

## shows the locations of the

## traverse points 

## for (Anonymous) used 

## for EpA Method 

## 202 and OTM-28 

## sampling. Sampling 

## for condensable SO3/HzSO+ 

### wâS 

## performed at a 

## single point in

## the stack.


## 4.1-2Volumetric Measurements - 

## EPA Method

# 2 EPA Reference Method 2

### was used to

### determine the 

### velocity and 

### volumetric flow rates ofthe stack 

## gases. Stainless steeltype

# S pitot tubes

## were used

# to measure

# the gas velocity heads. 

# pitot tubes were calibrated/checked according to EPA Method 

## 2. These measurements were performed in 

## conjunction withthe particulate sampling 

## described in

## section 4.1.5.


## 4.1.3 Molecular Weight Determination

# - EPA Method

# 3 Gas compositional 

## measurements (O2

## and CO2) 

## for determining the average molecular 

## weight of 

## the stack 

## gases 

## were made in accordance

## with EPA Reference Method

# 3. Multipoint, integrated 

## sampling 

## was used

## to obtain

# a constant-rate 

## sample 

## of flue 

## gas concurrent 

## with the 

## pollutant testing. Sampling 

## was

## of the same duration (except purges following port 

## changes) as 

## the pollutant runs.



## A stainless steel probe 

## was affixed 

## tothe pollutant-sampling probe for 

## this purpose, 

## and a peristaltic pump (delivering 500-750 ml/min of flue gas) 

## was used to 

## fill a

## Tedlar bag. Moisture 

## was removed from 

## thesample gas by an air-cooled 

## condenser located prior to 

## the pump. Figure 

## 2 shows a

## schematic of

## the Method 3 sampling train.


# I

### 12 3 4 5 6 

### 6 5 4 3 21

Port 

### Depth is 97 inches

Point o/o

### of lD Distance from lnside 

### of Port 

### linchesl
1 

### 21 9.79 2 

### 67 31.22 3 11.8 54.99 4 

### 177 82.48 5 25.0 116.50 6 

### 356 165.90 

### lnside Diameter 466 in. 38.8 ft. 

### Distance Upstream 

### from Disturbance 5880 in. 

### 12.62 dia. 

### Distance Downstream 

### from Disturbance 1710 

### in. 3.67 dia.



## Figure 

# I - Sampling and 

## Traverse Points 

## for Stack

### Method 

## 3 probe 

## (1|4-inch stainless 

## steel tubing) Peristaltic pump



## Tedlar sampling bag



## Figure 2

## - EPA 

## Method 3 

## Sampling Train

10

### 4-1-4 

## Flue Gas 

## Moisture Gontent - EPA 

## Method

# 4 The flue gas moisture 

### was measured



## in conjunctionwith each of

## the particulate 

## tests according to 

## thesampling and analytical 

## procedures outlined in EPA Method 4.



### Theflue gas moisture for 

### each test 

### was determined by 

### gravimetric or

### volumetric analysis 

## of thewater collected in

## the impingers 

## ofthe particulate sampling train. 

## All impingers were 

## contained 

## in an ice bath throughoutthe testing to ensure complete condensation of the moisture in

### the flue gas 

### stream.Any moisture not 

### condensed in

### the impingers 

### was captured in

## thesilica gel 

## contained in

### the fìnal impinger.


## 4-1.5 Particulate Sampling 

## - EPA 

## Method

# 51202 Condensableparticulateemissions 

## were measured in accordance 

## with EpA Methods 5 and 202.



## 4-1.5.1 

## Sampling Train 

# Description Figure 3 shows 

## the major components of the 

## Method 51202 

### sampling 

## train. A heated 

## stainless steel probe 

## with a

## Teflon (TFE) liner 

## was used to

## withdrawthe gas 

## sample. The probe 

## was heated 

## to 24goF 

### + 25oF, 

### to prevent 

## water condensation. The probe 

## was equipped 

## with an appropriately sized 

## stainless steel nozzle 

## for isokinetic gas 

## withdrawal. From 

## the nozzle 

## and probe, sample gas 

## was pulled 

## through a heated glass fiber 

## filter, maintained al24goF + 25oF, 

### and 

## subsequently passed 

## through an impinger 

## train consisting of five glass impingers 

## immersed in an 

## ice 

## bath. The first 

## three impingers 

## each contained 100 

## milliliters

## of deionized distilled 

## water. The 

## fourth impinger 

## was initially 

## empty, and the 

## fifth initially 

## contained approximately 200 grams of silica gel.



## 4.1.5.2 

## Sampling Train

# Operation Sampling

## was done 

## in accordance 

## with EpA Method 5 

### procedures and specifications, including leak checking, isokinetic sampling rate 

## and stack 

## traversing. Sampling 

## was conductedfor 5 minutes at 

## each of 

## the24 traverse 

## points (see Figure 

# 1). Each 

## test run had a duration 

## of 12O 

### minutes, 

## excluding the time required to

## change 

## ports. As required by 

### [Regulatory Reference], a

### sample volume of 

## greaterthan 60 

## dry standard cubic feet 

## was acquired 

## during each 

## sampling run. 11

## 4.1.5.3 

## Sample Recovery and

# Glean-Up Recovery of

### the Method 5

### sampling probe

was accomplished using a

### Teflon bristle 

### probe 

## brush. The nozzle, probe and 

### front-half 

## filter housing 

## was rinsed 

## with acetone three to six times 

## each and brushed between rinses.


## The back-half of

## the sampling 

## train (impingers plus connecting glassware) 

## was recovered in accordance 

## with EPA 

## Method 202 

## procedures.The pH ofthe 

## first impinger 

## was measured immediately after the

## test. The 

## entire impinger train was purged 

## for one hour using 

## ultra high 

## purity Nitrogen in accordance 

## with Method 202 

## procedures. This 

## was performed regardless of

## the pH of

## the impinger contents


## After purging, 

## the contents of the first 

## four impingers 

## was measured and 

## transferred to 

### glass

## jars. The first 

## four impingers and all back-half glassware 

## were rinsed twice with 

## water.Allwater rinses 

## were collected with 

## the impinger 

## contents. The back-half glassware 

## was then rinsed twice 

## with methylene 

## chloride. These rinses 

## were collected into a 

## separate glass

## jar. The 

## silica gel from the 

## fifth impinger 

## wastransferred back to its 

## original Nalgene container.


## 4.1.5.4 

# Blank The blank 

## was a sample 

## of reagent-stock 

## acetone collected 

## during the 

## test program, and 

## was analyzed in

## thesame manner as 

## the actual stack-test samples.

12Glass or stainless 

### steel nozzle
Heated 

### glass-lined probe 

### Thermometer Thermocouple Pitot 

### tubes (type S) lnclined



### manometer
100

# ml Empty deionized 

### water Silica gel



### ïhermometers

Exhaust I 

# t Coarse valve Vacuum

gauge lnclined 

### manometer Dry 

### gas meter Vane pump



# ì

Figure 3- EPA 

## Method 51202

## Sampling Train

13

## 4.1-6 Particulate Sampling - 

## EPA 

## Method

# 5/OTM-28 Solid and condensable

particulate 

## emissionswere also measured in

## a parallel sampling train accordance with EPA Method 5, coupled 

## with a back-half analysis in accordance 

## with EpA Other Test Method 028. 

## 4-1-6.1Sampling Train 

# Description Figure 

## 4 shows 

## the major components of the 

## Method 5/OTM-28 

## sampling

## train. A heated 

## stainless steel probe 

## with a

## Teflon (TFE) liner 

## was used to

## withdrawthe gas

## sample. The probe 

## was heated 

## to 24AoF

# j 2SoF, 

### to prevent 

## water 

## condensation. The probe was equipped 

## with an appropriately sized 

## stainless steel nozzlefor isokinetic gas 

## withdrawal. From 

## the nozzle 

## and probe, sample 

## gaswas pulled 

## through a heated glass fiber 

## filter, maintained at248oF 

# !25oF. After the 

## filter,the sample 

## gas passed 

## through a

## water-cooled glass condenser (capable 

## of cooling the stack 

## gas to between 80 

## and 85o 

### F) and a 

## series of

## glass 

## impingers. The 

## firsttwo impingers 

## were initially 

## clean and

## empty. lmpinger 1

## was a 

### condensate 

## dropout impinger without 

## a bubbler 

## tube and lmpinger 2

## was a modified Greenburg Smith 

## impinger. The 

## sample gas 

## then passed through 

## the CPM Teflon 

## filter and 

## subsequenily passedthroughthe moisture 

## traps. The moisture 

## traps consisted of 

## a modified 

## Greenburg Smith impinger (lmpinger 3) 

## containing 1OO 

### ml of water 

## followed by an 

## impinger (lmpinger 

## 4) that 

## contained approximately 

## 200 grams of silica 

## gel. The moisture 

## trap impingers 

## were maintained in 

### an ice bath 

## to keep the gas temperature below 680 F 

### at

## the exit of

## the impinger train.



## 4.1.6.2 

## Sampling Train

# Operation Sampling 

## was done 

## in accordance 

## with EpA Method 5 

### procedures and 

### specifications, including leak checking, isokinetic sampling rate 

## and stack

## traversing. Sampling 

## was conducted 

## for 5 minutes at 

## each of 

## the24traverse 

## points (see Figure 

# 1). Each 

## test run had aduration 

# ol 120 

## minutes, excluding the time required to change 

## ports. As required by 

### [Regulatory Reference], a

### sample volume of greater than 60 

## dry standard cubic feet 

## was acquired during each 

## sampling run.

14Glass nozzle 

### Condenser Thermocouple Heated glass-lined with coolant 

## water CPM Filter stainless steel 

### Stack 

# I L 

### rn"rrocoupte

Pitot 

### tubes (type S) lnclined



### manometer
Recircu at on Pump 

### Empty Water Silica gel
Vacuum line


### Thermometers 

# ,/\

lnclined 

### manometer Dry

### gas meter Vane pump Heated quarz or 

### fiberglass filter 

# ì

Figure 4

## - EPA 

## Method 5

## / OTM 028 

## Sampling Train

15

## 4.1.6.3 

## Sample Recovery and

# clean-up The probe and hot filter were



## disconnected from 

## the condenser 

## and impinger 

## train and 

## a post-test purge was performed 

## with ultra-pure 

## Nitrogen. The short 

## stem impinger insert 

## of lmpinger 1

### was replaced 

## with a modified Greenburg 

## Smith impinger 

## insert. The impinger tip extended 

## at least 1 

### cm below 

## the surface of the

## water. lf insufficient water 

## was collected, a 

## measured amount 

## was added 

## to the 

## dropout 

## impinger. The amount of

## water added was recorded 

## to correct 

## the moisture content of the effluent 

## gas. The purge 

## was performed 

## with the impinger 

## train connected to 

## the meter 

## box. The purge 

## was performed for 60 

## minutes at.the

## ^H@ of

## the meter box 

## with a positive 

## overflow rate of less than 2 

### liters/minute.


## Sample recovery 

## proceeded asfollows:


## Front half acetone 

# rinse: Recovery

## of the Method 

# s sampling probe was 

## accomplished using a

## Teflon-fiber probe 

## brush. The nozzle, probe andfront-half 

## filter housing 

## were rinsed 

## with acetone 

## at least three times each and brushed between rinses. 

## Filterable 

## particulate

# filter: The hot filter 

## was recovered into 

## a Petri dish. 

## Aqueous 

## Liquid 

## lmpinger: The liquid from the 

## dropout and impinger prior to the 

## CPM filter

## was measured and transferred

## to clean glass or plastic sample botfle. 

### The 

## condenser, lmpingers 1

## and2, connecting 

## glassware, and the

## front half ofthe CPM filter housing were rinsed twicewith

## water. The rinses were collected into 

### the 

## same bottle, Container 1. 

### GPM 

## organic Rinses: After the water rinse, 

## the condenser, rmpingers 

## 1 and 2, 

### connecting 

## glassware, and the front half of

## the CPM

## filter housing 

## were rinsed with 

## acetone, followed by 

## two rinses 

## of methylene 

## chloride. The organic rinses were collected 

## together into Container 2. 

### CPM 

# Filter: The filter 

## was removed from the CPM filter housing and placed into a 

### Petri Dish. 

## Gold lmpinger 

# Water: Thevolume of

## the contents of 

## the cold 

## water impinger 16 1



### 2. 3.



### 4.

5.
þ.

## was measured onsite and discarded.



# 7. SilicaGel: The silica gel was transferred back

# to its original container and 

### weighed.


## 4.1.6.4 

# Blank The blank 

## was a 

## sample of reagent-stock 

## acetone collected 

## during the 

## test program, and 

## analyzed in

## thesame manner as 

## the actual stack-test samples.


## 4.1.7 Gondensable SO3/HzSO¿ 

## Sampling - EPA 

## Method

# CTM-0138 Condensable 

## materials consisting 

## of SOs 

## and HzSO+ 

## wêrê measured 

## using EPA Conditional Test 

## Method 0138.

4.1.7.1 

## Sampling Train 

# Description Figure 5

### shows the major components of

### the 

### CTM

## 0138 sampling 

## train. The system consists 

## of 

## a high temperature quartz probe, 

## a high 

### temperature quartz filter, 

### two impingers containing 100o/o 

### isopropanolsolution, an unheated 

### filter, two impingers containing 3% hydrogen peroxide, and a

### silica 

### gel 

## impinger. The probe 

### was heatedto

### approximately 

## 400'F and the filter to

### approximately 500"F in

### orderto 

### prevent 

## the condensation 

## of any SO3 

## and/or HzSO¿

## on the filter, while still trapping non-sulfate 

## particulate 

## matter. Any SO3

# / HzSO+ 

## was collected 

## in thefirst impinger 

## and on the unheated 

## filter. Any SOz 

### that may be present in

### the 

### gas stream passed through tothe 

### final 

## two impingers containing HzOz.



## 4.1.7.2 

## SampleTrain 

# Operation The CTM-0138 sample 

## trainwas operated

## at an 

## isokinetic sampling rate, 

## at afixed location inthe

## stack. Testing 

## was performed over a 

## period

# of 120 minutes, simultaneously 

## with 

## the particulate sampling discussed 

## in the previous sections.



## 4.1.7.3 

## Sample 

## Recoveryand 

# Clean-Up Theprobeandfronthalf ofthefilterholder
were rinsed

## with 100% 

### lPA, and the 

### quartz fìlter

### was added to 

### the 

### samplejar containing the 17

## rinse 

## material. The contents of

## the IPA impingers 

## were placed in a sample 

## jar, and the



### impingers, as

## wellas the back half of

### the heated filter holder and the 

### connecting Teflon line 

## were rinsed 

## with 100o/o 

### lPA, with 

## the rinses added to the same sample

## jar. The unheated 

## filter 

## was placed 

## in a separate sample 

## jar containing lOOo/o 

## lPA, and 

## the connecting glassware from the back ofthe 

## second IPA 

### impinger to

### the front half ofthe unheated filter holder 

## was added tothe sample

## jar. The contents of 

### peroxide impingers were placed in a 

## sample

## jar, and the impingers, aswell asthe back half of 

## the unheatedfilter holder and 

### connecting tubing,were rinsed with 

## Dlwater, with 

### the rinses 

### added tothe same sample jar. 

## Thesilica gel 

## was recovered 

## into its

## original Nalgene botfle.


## 4.1.7.4 

# Blank The blank 

## was a

## sample of reagent-stock IPA 

## collected during 

## the test 

## program, and analyzed in

## the same manner as 

## the actual 

## stack-test samples 

# 4.2 AnalyticalProcedures 

## 4.2.1 Molecular 

## Weight Determination 

## - EPA Method

# 3A Flue gas compositional 

## analysisfor molecular weight 

## determinationwas conducted using instrumental analyzers 

## set up and operated in 

## general accordance 

## with EPA Method 

## 34. The instruments were 

## calibrated before each analysis 

## with EPA Protocol 1 

### calibration 

## gas standards. Each bag 

### was analyzed in

### triplicate and 

### the average flue 

### gas composition used 

### for calculation of 

### gas 

## volumetric flow rate.



## .4.2.2 

## Moisture Gontent 

# - EPA Method

# 4 Moisture contents 

## were determined 

## gravimetrically in

### accordance with Method 4 by 

### measuring either the

### volume or mass 

### gains of 

## each impinger in

## the pollutant 

## sampling trains.

18Glass nozzle 

### I 

# / Heated 

### glass-lined 

# / stainless 

### steel probe Heated Teflon 

### Thermometer line 

## Stack Thermocouple igh

### Temperature

Pitot 

### tip Filter

lnclined 

### manometer
100% isopropanol 3o/o

### HrO, Silica Gel

Vacuum line


### Thermometers 

# ,/\

lnclined 

### manometer Dry 

### gas meter Vane pump 

# =l

Figure 5 

## - EPA 

## Method CTM-0138 

## Sampling Train

19

# 4.2.3 Gondensable Particulate 

## Analysis - 

## EpA Method

# 202 The total



## condensable particulate matter in

## the back half of

## the sampling train 

## was determined in 

### accordance 

## with Method 2O2 

## procedures. The impinger contents and aqueous rinses 

## were combined 

## withthe methylene chloride rinses and extracted twice 

## with methylene 

## chloride using a separatory 

## funnel. The sample 

## was divided into 

## organic (methylene 

## chloride) and 

## inorganic (aqueous) 

## fractions. The organic fraction was 

## evaporated at 

### room 

## temperature and pressure, and 

## the resulting residue was analyzed gravimetrically 

## to a constant weight.



## The total condensable particulate matter in

## the back half of

## the EPA 

## Method S

### sampling 

## trainwas determined in accordance 

## with Method 202 procedures. The impinger contents and 

## aqueous rinses

## were combined with 

## the methylene 

## chloride rinses and 

## extracted twice 

## with methylene 

## chloride using a separatory 

## funnel. The sample was 

## divided into 

## organic (methylene 

## chloride) and 

## inorganic (aqueous) 

## fractions. The 

## organic fraction 

## was evaporated 

## at room 

## temperature and pressure, and 

## the resulting residue 

## was analyzed gravimetrically 

## to a constant weight.



## The inorganic 

## fraction was 

## evaporated to 

## dryness at 105oC, 

### and 

## the residue was 

## analyzed gravimetrically to a constant 

## weight. Since 

## the pH of

## the original solution was 

## greater than 

## 4.5 and 

## the optional 

## ammonia addition step 

## was omitted.



## The back-half condensable particulate catch was equal 

## theorganic residue plus the 

## inorganic residue.


# 4.2.4 Condensable Particulate 

## Analysis - EPA 

## Method

# OTM-28 Condensable 

## particulate matter was 

## determined in accordance 

## with EPA Other 

## Test Method 28 

## procedures. The 

## water soluble CPM 

## was extracted 

## from the CPM 

## filter and the 

## aqueous extract combined with 

## the contents of 

## Container 

## 1. The organic 

## soluble CpM was extracted fromthe CPM 

## filter and 

## the organic extract 

## was combined 

## with the 

## contents of Container 

# 2. The 

## aqueous impinger 

## contents in 

## Container 1

## was placed in a 

### 20

## separatory funnel and extracted twice 

## with 30 ml of methylene 

## chloride. This organic



## extract was combined 

## withthe organic 

## train rinse in Container 2.



## The organic phase 

## extracts and 

## rinses in Container 2

## were placed in

## a beaker and the 

## volume reduced 

## to less 

## than 10 

## mL at room 

## temperature. The beaker 

## contents were 

## thentransferred to 

## a pre-weighed 

## tin and evaporated 

## to dryness at room temperature. Following evaporation, 

## the organic fraction 

## was desiccated 

## for24 hours, and then 

## weighed at

## 6 hour intervals to a constant weight.



## The contents of 

## Container 1 

### (inorganic fraction) were transferred to 

## a clean beaker and 

### the 

## volume reduced 

## to less 

## than 10 mL 

## at 105oC, 

### and

## then allowed to 

## dry at room 

## temperature. The residue 

## was re-dissolved in 100 mL of deionized 

## distilled ultra-filtered 

## water. Titration 

## with 0.1 N NH4OH 

## was used 

## to neutralize acid in

## the inorganic sample 

## and remove 

## water of 

## hydration. Thevolume of

## titrant used 

## was 

## recorded. The volume of

## the aqueous phase 

## was reduced 

## to about 10 

### mL 

## at 105oC.The beaker contents was 

## thentransferred to 

## a pre-weighed 

## tin and evaporated to dryness at room temperature. Following evaporation, 

## the organic fraction 

## was desiccated tor 

## 24 hours, and then 

## weighed at 

## 6 hour intervals 

## to a constant 

## weight. The 

## weight of

## the inorganic residue 

## was corrected for 

## the NH4* 

## retained in

## the sample.


## 4.2.5 condensable Sog/HzSo¿ 

## - EPA 

## Method 

# CTM-138 sample analysis was 

## performed using lon Chromatography 

## with conductivity detection. 

# 4.3 Data

# Analysis Equations related 

## tothe pollutant sampling, including gas flow rates, 

## temperatures, percent 

## isokinetics, and moisture content are 

## shown in

## Appendix C.



### The 

## test results 

## are reported 

## as mass rate in

## terms of both lb/MMBtu and lb/hr. 

## Emissions in 

## lb/MMBtu is

## calculated using the 

## dry oxygen-based fuel factor 

## for bituminous coal (9780 dscf/MMBtu), 

## which is published in

## Table 19-2 

## oÍ EPA 

## Method 19 

### in 

## 40 CFR 60. 21

# 4-4 Equipment 

# Calibration Field equipment 

## was calibrated in accordance with the



## requirements of

## the applicable EPA Methods, and with 

## those recommended 

## within the Quality 

## Assurance Handbook for

## Air Pollution 

## Measurement Systems: 

## Volume 

## lll (EpA60014-77-027b, 

## August 1977). Appendix F

## contains records for allthe calibrations.

22

# Appendix A Test Log

# TEST LOG (Anonym 

## ous) Power 

## Station (Anonymous) Stack

Run l.D. 

### Test Parameter 

### Test Date 

### Start Time End



### Time
s00-M202-R5B Condensable Particulate Emissions 

### EPA Method 5/202 06/'10/09 0804 1048 

### s00-M202-R7B 1545 1806 

### s00-M202-R8B 06t11t09 0753 1017 

### s00-oTM28-R5A Condensable Particulate Emissions EPA 

### Method 5/OTM-28 06/1 0/09 0804 1048 

### s00-orM28-R7A 1545 '1806 

### s0o-orM28-R8A 06t11t09 0753 1017 

### s00-M138-R2 SO. + 

## ¡r59a Emissions 

### (as HzSO¿) SO3 

### + H2SOa Emissions (as SO3)
SOz Emissions 06/1 0/09 0804 1048



### s00-M138-R3 1545 1806



### s00-M13B-R4 06t11t09 0753 1017

# Appendix B 

# Data 

# and Results

# Appendix 8.1 EPA 

# Method 5//202 

# Data

# and Results

### Run Number s00-M5/202-R5

Date StartTime 

### E¡dïme SÞck Diameter 

### Nozle l.D. MeterBox Garnma 

## ' Meûer Box dH@ Barcmefic Cp

.Test Duration 06/10/0e 8:tÌ4 10:48 466 inches 0.240 ¡nches 0.s960 1.7414 26.80 in.Hg 0.84 120 minutes VoluEq Fìnal 1S1.0 120.O 100.0 5-0 

## lmplnger0 0.0 

## lmpirrgerT 0,0



## 300.0 4,16.0 11 

# t4
Metered

## Volume 9g.¡146 dgf 

## V0lume@.$td.Cond. 8t.3ZS dscf Ío

## Water 7.Zg Vo %

## fsokinetks 94.O ølo 

## Vdocity 49.46 ff/sec 

## ActualFlow 35l509tì acfm SH-

## Flour E&742 

## úm Std- Flor,t, 

# v"o2 14.00 Md 25.07 

# TñV¿ 3.20 Ms 28.27



# 0.t Ps 2t 

# 82.8 Fo 2.

SùafÌc Meter Meter 

# 0.63 'r.80 

## g4û_s28 

# 81 78 0.74 ?_to 

# Temp. Prcssure Detb

# p Deltn

# H Voturne



# . .Jemp. (Ðag.

# Fì

_ 

# po¡n! (Þr) t¡!.!=r=c)

# (¡!.Eg) 

# {in.wc) (¿cÐ 

# --ñ¡ãr- ourä 

# 1 108 0.37 0.57 

# 2 107 

# 3 106 

# 4 108 

# 5 105 

# 6 108 

# 7 107 

# I 108 

# e 108 

# 10 107 

# 11 110 

# 12 10Ð 

# 13 105 

# 14 108 

# 0.64 1.90 

# o.77 2.20 

# 0.87 1.90 

# 0.49 1.40 

# o.ff 1.50 

# 0.54 1.BO 

# 0.6t l.to 

# 0.73 2_10 

# 9.72 2-10 

# 0.53 1.50 

# 0.54 t.6t 

# 0.57 1_70 

# a.a1 1.90 

# 0.67 1.90 

# 0.58 1.70 

# 0.58 1.70 85



# 940.936 88 

# 988.57¿ 89 79 80 81

15 1û7 

# 16 tû6 

# 17 106 

# 18 107 

# 19 107 

# 20 f07 

# 21 108 

# 22 f rl5 

# 21 105 

# o.74 2.10 

## 88 81 

## 83 81 

## 86 81 

## 87 80 

# s8 81 

# 8S 82 

# 89 82 

# 82 8l 

# 8/.8r 85 81 

# 87 8f 

# 8S g2 

# Ð0 83 

# 86 83 

# 8tì 83 

# 88 83 

# 89 83 

# 86 82 0.59 0.68 0.71 1.70

1.Sû 2.10

## EPA ñfiethod 5//202:

## Gravi¡netric Data 

## and Results

SAfiIPUNG DATA Run number 

### Conected sarnple vof ume Corr€sted flou¡ rate 

### 02 Content CO2 Content 

### sa+Msl20a,R5 81.375 

### dscf 2720956 dscfrn 14.0 % 3.ZVa

# ' Run Number sGGMs/202-R7

Date SËartTime End Time 

### SÞck Díamster 

### Nozzb l.Ð. Meter Box Ganma Metei Box dH@ BaromeÍis Cp Test Duration 0tr1o/gs f 5-.45 18:06 4ö6 lnches 0.240 tncheË o.Ðs60 1.7414 26.50 Ín.Hg û.84 120 minutes 4 DÀTA
Volume Final 

# 1 100.0 210.0 110.0 

# lrnpínger2 

# f00.O 110.0 I 

# lmpînger3 

# 100O 89.û -1 

# 4 0.0 5.{t 5.t 

# $ o.o 

# 6 o.o lmpiinger 7 

# 300.0 414.0 114.0



# 20t.o 218.8 18-8

3 DATA 

## YoOZ 14.00 Md 29-2Ð



# 4.00 Ms 28.41 

# %co 0.o Ps 26.63 

# %N2 82.0 Fo 1.:t2s 

## OziûOZ 18.0 %EA f8g 1-f RESI|LTS Metered

## VoÌltæ SgjÊO dcf Volume @

## Std-Oond. St.S13 dscf 

## %Water T.OS % %

## lsokindics 95.6 % 

## Velocrþ 49.44 frlsec Aclual 

## F[ow BE13l61 acf.n SH- 

## Ffow 2Bg87Bô scfrn Skl.

## Ffow 2OS32l1 

## Temp. Pressure DelH

## p llelh 

## H Volume Temp. (Deg. F)



# . point (pgsJ) fi?.Yc) (in,rwc) 

# (in.w0l ldqÌ.J;iA-- oud€r 

# 1 109 0.41 0.56 1-00 s1-844 73 72 

# 2 707 0.37 

# 3 107 0.40 

# 4 108 0.38 

# 5 106 

# 6 108 

# 7 f08 

# I 108

107 109 

# 0-82 1.80



# 0.5s 1-70 

# 0.84 1-90 

# 0,89 2.û0 

# o.7s 2.20 

# 0.52 1.50 Meter



# 127.716 76 73 

# 77 73 

# 127.875 78 73 

# 175,837 7S 73 

# 80 73 

# 76 74 

# 79 74 

# 7S 74 

# 80 74 

# 81 77 

# g2 75 

# T5 74 

# 73 74 

# T7 74 

# 77 73 

# 77 7? 

# 7Ð. 73 

# 76 73 

# 80 74 81 74 

## I l0 

# 11 108 

# 12 105 

# t3 108 

# 14 108 

# 15 105 

# tE 1û6 

# 1T 106 

# 18 los 

# 19 1Ð7 

# 20 10s 

# 21 1û6 

# 22 1û8 

# 23 lû9 0.57 1.70 

# 0.4s 1.40 

# 0.66 1,90 

# 0.6ã 1.90 

# 0.ô3 1.80 

# 0.55 1.60 

# 9.57 1.70 

# 0.64 f .s0 

# 0_s9 1.€0 

# 0.63 l_so 

# 0.64 l.g0 

# 0-69 2.10 

# o.75 2'¡A 0.67 1-S0 

# 0.63 1.80



### . o.5g 1.80


## 81 74 

## M74 

# AVG. 107 0.39 0.63 1.86

## EPA MethodSl2O2: 

## Gravimetric Data 

## and 

## Results

SAMPL]NG DATA Run 

### number Conected sample volume Corrected flow rate 

### 02 Gonteflt CO2 Content 

### s0fr.M5f202.R7 81.913 dscf 2693211 dscftrt 

## f{.o % 

### 4.0 vo

Gorrected 

### to7% 

### 02 {gr/dscf) 

### Conected to12V, COZ (gr/dsc'f) 0.0100 

### o.4202 0.0301

## Run Number s00-M5r202-R8

Date 

### StartTíme End TÍme Stack Dlameter 

### Nozle l.D. Meter Eox Gamma


# , MeterBox dH@ Baromeüic 

### cp Test Duration 06/11¡tg 7:53 1O:17 466 inches 024O 

### ínúes 0.ss60 1.7114 2û.50 in-Hg 0-84 12O minutes 4 DATA Volqme 

## lnltlsl Fhd 

## I 100.0 204.0 1 lmpinger

# 2 100.0 110.0 10.0 lmpinger

# 3 100-0 9õ.0 4 

# 4 0_0 2,A 2.0 

# 5 0.0 

# ô 0.t 7 

## 300,0 412-A SiHca METHOD 1-4RESULTS lvletered

## Volumg 96.628 dcf Volume@ 

## Std.Cond. 83321 dçtf %

## Water 7.12 % %

## lsokineiics S6-6 % 

## Velocity 49.64 ft/sec Act¡af 

## Flot¡v 3527ffi4 acfm Std-

## Flow 2920885 scfm SûC-

## Flout 2712829 3 DATA 

# 14.00 frrd 

# %coz 320 t/ts 

# %CO 0.0 Ps 

## %NZ 82.8 Fo 

## O2+@2 17 2S.07 

### 2828 26.53 2.156 178

Stack Stattc Meter


# 1.90 238.2æ 76 72 

# 230 79 73 

### 2-1t 

# 234.463 83 75 

# 285-931 

# 85 7B 

# 87 77 

# 83 78 

# 86æ 89 B0 

# 90 81 

# 90 t2 

# 91 83 

# 85 82 

# 87 82 

# 89 82 

# 90 82 

# 90 82 

# s0 83 

# 83 81 

# 8ô 8t 

# 8¡ 81 

# 87 8{ 

# 87 81 

## Temp. Preszure Della

## p Delta 

## H Volume Temp. (Deg.

## F)

._ 

# polnt. (o.eg.F) t¡!.Lïc) 

# , (itÏtc) .l¡n_wct {ocÐ 

# Tter--lõrü-E- 1 104 0.36 0.ô2

- 

# 2 103 

# 3 107 

# 4 1t4 

# 5 103 

# € 110 

# 7 107 

# B 106 

# I 1r)6 

# 10 105 

# 11 10Ë 

# 12 104 

# 13 f04 

# 14 108 

# 15 107 

# o.41 0.63



# 432 0-78 

# 0.3s o.72



# 17' 106 

# 18 103 

# 19 105 

# 20 '105 

# 21 104 

# 22 1AB 

# 23 107 

# 24 103 

# 0.63 2.5Ð 

# 0.81 2.40 

# 0.58 1.70 

# 0_e+ 1.90

1.70 f-s0 1.90 2.10 1.50 

# o.54 1_70 

# 0.61 1.90 

# 0.60 1.S0 

# 0.54 1.70 

# 0.66 2.00 

# 0,53 1.60 

# 0.59 1.80

r.60 1-Sû 

# 0.67 2.10 0-58 0.an o.63 0.6s 0.49

16 106



### o.ffi 0.63 

## gl5 z.ffi 90

### EPA 

## Method SI202: 

## Gravimetric Data

## and Results

SAMPLING DATA Rr¡n 

### numbel 

### conected sa rnple vol ume 

### Conectedflowrate O2 Content COz Content 

### s0trM5f202-R8 83.371 

### dscf



# . 271Æ?:9 dscfm

14.O alo 3.2Vo

# AppendixB.2 EPA 

# Method SfOTltI-z8 Data 

# and Resulte

### Run NumbEr S0O-MOTiilz8-RSA
Date Start Time End

### ïme StäÊk Diameter Nozde l.Ð. l¡leter Box Gamma M6têr Box dH@ Barometrh Cp TeÊl Duration 00/10/0s 

## 8f4 10148 4ß6 inches 0.240 incf¡es 0.s950 1-7431 26-80|n-Hg 0.s4 120 minutês 4ÐATA

1 0.0

0.0 100.0 Final

67.0 30.0 123.0 67 lmplnger 2 fmpinger 3 lmpinger4

5 o 7 

## 100,0 220.0 1 Silica 

### od

## lol 200.0 233.0 33-0 LTS MeÞrcd

## Volume 90.410 dcf Vohme @

## Std.Cond. 78.670 

### dstt %

## waær 8.3S % %

## lsokinetfrx 912 çÃ 

## Velocily 49.92 fl/sec Actr¡al 

## Flor 3317829 aÉftr Std.

## Flow 2958810 scfrTr 27105&f dscfrr¡ 3 

# 14.4 Md 2s.



# VêCO? 3.50 Ms 

# V"Cö 0.0 Ps



## A2-1 Fo 1.857 

## 17.9 %EA 1

Statiê Prêssurc 

# MètÊr Meter 

# Volune Temp. (Deg- F) StâËk Temp. lDesE 108 Point 1 

### Delb P

2 3 4 5 6 7 

# I I 1{t 11 12 

### t3 14 15 16 17 18 19 20 21 22 23 24 109

108 107 108 f09 104 107 107 107 106 106 f08 108 110 109 10s 108 108 107 100 107 147 108 0.70 0.85 o-82 0.80 1.ûO 0-56 0-60 0.õ5 0.87 0.70 û.65 0.56 0.s3 0.54 o.56 o.50 0.61 0.õ0 0.61 0.54 0.G5 0.67 0,67 2.Ð0

f -90 2.,{O 2.30 2.9O 

### t.60 1.70 1.90 1.90 

### 2.æ 1.S0 J.60 1-50 1.50 1.60 

### 1.fl) 1.80 1.70 1_80 1.50 1.90 

### l.s0 1.90 75 7B 77 78 78 7S 7S 7g 80 80 80 80 80 81 

### t1 B1 81 82 82 83 82 83 83 

## w 79 83 86 88 88 88 82 84 87 88 89 8ft 

# u 86 87 88 89 

## st gr 88 89 8g 8S so 0.40 0,37 751.215 751.455 795_950

108 0.65 

### t.86 so.410 

# u

0.37

### Run Number s0fÌ-MoTtt¡!?8-R7A

Dde StartTime EndTinre Stack Diameter NolzlÊ l.D. Meter Box Gamma Meiler Box dH@ 'Ba¡omebic 

### @ Test Dt¡ration 06/10/09 15:45 18:08 466 inches 0.240 inche6 0.9950 1.7431 26.50 

### ií.Hs 0.&t 120 minutes 

### A Volume 

### I lnilial

0.0 0.0 1ül_o 

## 72.0 72. lmpinger2 lmpinger 3 3.0



## 11S-0 rS.0 4 0 lmpinger5 lmpinger6 7 Total 

# 100.0 1s4.0 94.0



# 200-0 233-7 ?3.7 Metered

## Volume S3,T1Z

### dd Volume@

## SU.Cord. g0.TBg d€sf 

## %Waær 6.sg % %

## fsokhetics gZ.B Vo 

# vefoctty so,s3 fl/sec Arü¡al

## Flow 35909f!D acfrn Sld.

## Flørrr 2956f2t scfr,n 3 DÀTA 

## 14.00 Md 2S.1t 

## 3.90 ME 28.41 

# O.0 Ps 2t 

# 92.1 Fo 1.

7A 78 78 7g 81 BO 80 8û 80 8û B1 80 

# It 8l 80 80 80 79 

## t0 80 80 80 

### 8t 82 8$ 85 86 87 84 s6 87 87 8T B8 83 85 85 85 86 85 83 85 s6 88 89 90 

## .2 3 

## ,4 5 G 7 

## I s 

## l0 JI 12 

## l3 14 

# '15
18

17 

# .f8 l9

20 

# .21 '4.> 4 

# '29 24 108 108 1ûS 107 108 107 107 107 108 11Ð 109 

### r08 r09 ,1û t0E 110 1f)9 

### t1û 109 110 110 110 109 0.41



### t.35 0.39 0.70

0.80 0.73 0_80 0.80 0.60 4.73 0.65 o.65 0.80 û-s5 0.55 0_5€ 0.56 0.54 0,05 0.63 0,56 0.60 0.60 0.65 0.70 0.70 2.00



### 2Ã0 2.1A 2.40 2_40 1.70 2.O0 r.90 1.9û 2.40 1.90 1.60 1.60 1.øt f .80 1.90 1.S0 

### 1.7t 1.8{¡ r-80 2.O0 2.10 2,1D 957.049

æ7.247 1ffÌ2.860



# AVG. 10S o.tt 0.66 r-94 9.3-712 83

### Run Number s00-MoTM28-R8A
Date 

### Startïme 

### Endïme Stack triarneter Nozzle LDMeter Box Gamrna MeterBox dH@ Barpmeûb Cp Test Brration 

### 06/fi/09 7:53 10:,17 466 lnches 0.240 incheÊ 0.9e50 1.7431 26.50 in.Hg 0-84 12O mlnutes METHOD4 DATA
YolurTtê F¡nâl lmplr¡gsr 

# 1 0.0 83.0 

# 2 0.0 2.o 

# 3 100.0 11s.0 1 lmpingêÌ4 lmpinger 5 lmplnger

# 6 0.0 

# 7 0.o 

# 'otaf '100.0 zOt.O Silíca ael

## fq) 200.0 230.5
MstÐr€d

## Votuma 95-325 dcf Volwne @

## Sffi.Cond. 81.818 dscf 

## %Watff 6.99 % %

## lsokinetics 54.2 % 

## Velocity 49.80 füseo Acluâl 

## Flow 35û9223 ärfrfi Std-

## Flo¡¡ 2363343 scfrn 2728978 dçsfm 

# 1420 Md 2S.0{ 

# 3.1O Ms 28.æ 

# û-û Ps 26.53 

# B2:t Fo 2.181 

## 17-3 dl"EA 1

Stâck $taüc MeÞr 

# Temp. Preesure Delta P D€¡ta

## H VoJume Temp- lDeg. F) 

# PoÌnt (DegF)

## .,., (i!.w_c)



## _

# {¡n.WÇ} 

# (in-WC) (dcf) lnl4 Otid€t 

# I lto 0.39 0.65 2.00 14.805 77 7s 

## 106 0.4f 0_60 

## 1.80 80_975 82 74 

## 3 101 0-37 0_M 

### l.so 

# 4 102 

# 5 103 

# 6 104 

# 710/. I 103 

# I 106 

# 10 142 

# 11 r03 

# 12 lM 

# 13 105 

# 14 107 

# 15 105 

# t6 10€ 

# 17 107 

# 18 J04 

# 19 105 

# 20 ,l05 

# 21 105 

# 22 106 

# 23 107 

# 24 105 

## 0.45 1.4D 

## 0.60 1.80 

## 86 75



## 61.'185 88 78 

## 110.3¡t0 8S TT



## 90 Tl 

## 85 T7 

## 89 80 

## gl 81 

## 92 82 

## 92 83 

## s2 83 

## 8784 90 84 

# s2æ 92 84 

# s2 85 

# w85 87 84 

# 8Sæ 90 84 

# 91 84 

# 9f 84 

# 9ru 0.4fr 0.65 2-ùo 

# 0.70 2.10 0_80 0.50 0.52 z_40



### r.50 1.60

0.50 0,60 0.5s 0.60 o_70 0.65 0.70 1.70

1.90 1.80 1.90 2.20 2.00 2.20 

# 0_70 2.20 

# 0.å5 2.00 

# 0.60 1.so 

# o.70 2.20 

# o.70 2.20 

# 0.75 2.30 

# 0.80 2"ffi AVG. 105 0.û+ 

### t.s8 

## 95:''8 85 0.40

# Appendix 8,3 EPA 

# Method 

# l3B Data 

# and Results

### Run Number 

## s004Tlti[138-R2

Date St¿rt Time End Time Stack Diarflster Nozzle l.D, Meter Box Gamma túøterBoxdH@ Barometic Cp Test Durât¡on 0d1O/tS 

### 8S4 1O:¿ftÌ ¿166 Ínches 0.240 inches 1.02Ê4 1.7246 26.50 in,Hg 

### 0.M 120 minutes

i/IETHOD 3 DATA

## 14.ffi Md



## oÃCOZ 2.80 Ms 28, 

# %CO 0.0 Ps 

# %t\¡2 82.7 Fo



### 4DATÀ lmpingerVolume 

## lnitial F¡nâl lmpinger 

## I 657.9 686.5 

# 2 783.5 785.3 1,8 

# 3 602.9 628.6 2'5.7 

## 4 835,0 876.5 41 lmpinger

# 5 0,0 lmpingêr

# 6 0,0 

# 7 D.0 2879.3 

## 2978_9 S7 1.4 RESULTS 

# MeÞredVoluma 100.4f]4 d0f Volume @

# Std.Cond. S1.738 dscf 

# %wars 6.58 % %

# lsokinetics 99.3 % 

# Velocity 53.4iÌ rus€c 

# ÄctualFlow 3797181

## únt Std.

# Flor¿ 310833{l 

## sún 

## Flo,¿ìl 2SO385S dscfrn

Stãck 

### Shlic Ms,ter 

# Temp. FrBssurs Deltâ

# P Delta

# H Volume Teflp. (Dsg. Fì 

# Point (DeeF) (in.WC) 

# (in.WC) (in.Vrt0) (&D lnlqt otilet 

# 1 111 0.32 0.80 2.30 830.793 67 67 

# 2 112 

# 3 1f3 

# 4 1',|2 

# 5 112 

# ö llÛ 

# 7 112 

# I 113 0.75



# 0.70 2.00 

# o.7Ð 2.00 

# 0.70 2.OO 

# 2.20 931.197 ö7 67

0.70 o.71 0.71 0-71 2.00

2.10 2.10 2.19

2.00 2.10 2.10 

# I 10 

# tf 12 13 110

112 112 1f1 112 66 oÐ 67 67 67 68 68 G8 68 68 68 67 67 SB 67 68 ôE 88 6g 69 70 70 70 89 68 68 08 09 

# 14 113 15 

### l8 17 18 113



### 1f0 112 111 

# ra 112 

# n 113 

# 21 172 

# 22 112 

# 23 111 

# 24 112 

# 0.70 z.EA 

# 0.75 220 

# 0,75 2.24 

# 0.75 2.29 

# 0.70 2.00 0.70 0.73 0.73 

# 0.75 220 

# 0.75 22Ð 

# o-72 2-10 

# 0.72 z,to 

# o.Tz 234 

# 0.75 220 

# 0.75 2.n 

# 70 ô8 

# 79 69 

# E8 63 

# Bg 68 

# 7t 68 

# 7n 68 

# 72 Tg 

# 72 7t 

# AVG. 112 A32 0.73 2.11 100rO4 68

### Run Number 

## s004TMf3B-R3

Dab Start Time EndTime Stack Dfame,ter Ftozzle l.D. 

# ' Meter Box Gâmma Meter Box rlH@ Baror¡ætrlc 

# 'Cp TestRrraüon 06/10/09 15:45 18:G6 4G6 ínclres 

### 0.240lndres 1.0264 1.7246 26.5û ln.Hg 0.84 120 minutes METHOD 

### 4DATA Volurne 

# lnitial Flnal fmpirper

# I 660.7 692-g 

# lmpingerZ 

# 767.7 7m-T lrnpÈ1ger

# 3 689.0 703.3 

# 4 824.6 860.3 5 lmpinger0 32.2 12.fr 14.3 

### 3sJ 0.0 

# 7 0.0 

# 2942.D 3036.2 54.2 

# 200.0 240.3 40.3 IIETHOD 

### I4RESULTS 

# MeteredVolwne 1A2.217

### dú Volume@ 

# Std.Gond. û2-622 

### dscf 

# %Waler €.41% %

# lsokinelics 10ü.3 96' 

# Velocity 53,36 fr/sec ,Achlal 

# FloË' 3791701 åcfrn SH-

# FTow 3102466 scfrn 2903657 dscfm IIETI{OD 3 DATA ,i/6o.2 

### %w¿ 96co 

# 14-00 tLtd



# 4-00 Ms 

# O.0 Pg 

# 82.0 Fo 2S20 28_48 2t-53 1.725



### $acf( Tefltp. StatÌc 

## Prsseure Dsltg P 

# o.70 2.00 

# 0.70 2.00 

# o.71 2.1A o.71 2-10 Meter Volume 

## 1055.694 

# 72 71



# 72 71 

# 73 71 Defta H 

# Point

,

# ,(ÞegF) (in.Wt) (ín.WCì (in.WË) (dcfì lnlet Outlat 

# 1 112 0.37 0-7s 2.20 953.477 73 72 

# .2113 3 f13 

# 4 112 

# 5 110 

# 6 112 

# 7 113 

# I 113 

# s 111 

# 10 11?. 

# 11 112

17 18 

# 'fs 113

112 

## 1fi 0-73

o.72 D_72 0.75 2.14

2.10 2.10 2-20 74 7E 74 74 74 75 75 76 74 73 73 73 74 75 71

70 71 71 71 71 71 71 

## t? 71 71 77 70 70 

# o,71 2.1Ð 

# o.70 2.00 

# 0_70 2_þ0 

# 0.73 2.10 

# t.73 2.10
12 13 113

110 

# 14 112 

# r5 112 

## 16 111 

# o.73 2.10 

# o.75 ?.20 

# 0.76 2.20 

# 0.75 2.2ô



# . 0-7s 2.20 

# 75 71 

# 7Ê 71 

# 2t 113 

# 21 112 

# ?2 715 

# 23 113 

# 24 111 

# 0.75 2-2t 

# 0.75 2.20 

# 0.75 2.20 71 71 71 12 7€ 78 79 79 0.73 

### 2.lD 

# 0.7s 2.1s Meter



### A\fB. 112 

# 0.37 0-73 2.12 

### 1t2217 73

### Run Number 

## $oo.cTñ/il38-R4

Dale Süart Time End 

### rime Stack Dlsmeter Nozzle l.DMeter Box Gsmma Meter BoxdH@ Bamnæûic 

## tp Test Duration 06/11rcS 7:53 10:17 4€6 inches 0.2¡t0 inches 1.0264 1.724ts 2S.50 in.Hg 0.84 12O minutes 4 DATA Volunæ lnitial 

### I 2 

# 660.7 698.7 mplruerS 

# 7M,9 754.S -10.3



# 700.4 7333 33.4 

# 813.6 861.7 48,1 0.0 0.0 lmpinger4 lmpirÐer 5 Implnger6 ImpingerT 

### otal 

# 2S39.6 3&ff8.8 22ß.4 

### iIETHOD 

### I.4 RËSULT$
Metered

# Vdume s9.5Ð7 dof Volume @

# Sld.Cond. 90.150 dscf %

# $rfaler 6,71 Vø %

# lsokinelhs S8.8 % 

# VeH:Íty 52.87 ft/sec 

# ActualFlow 3757019 acfrn Std-

# Flor¡r/ 3075795 

### sútn dscfin METHOD S DATA



# VoAZ î4.00 Md A VuCO? 3-Oû Ms 

## Vnæ 0-0 Ps 

## %N2 83.0 Fo

Temp.
110 11?: 112 113 111 112 111 112 

### t13 111 112 112 111 112 112 113 111 112 110 113 172 112 111 113 o.74 0_73 0.70 0.70 o-70 o.75 0.6s 0.70 0.75 0.70 0.70 0.70 0.70 0,70 o.72 o.T2 

## l.7i 0.7t 0.70 

### r-71 0.71 0.71 o-70 2.10

2.ßA 2.00 2.00 

## 2.fr 2.00 

### 2.m 

## 2.n 2.ffi 2-OO 2.00 

### 2.ffi 2.00 2.10 2.10 2.AO 2-0€ 2-00 ?.10 

### 2.'lo 2.70 

### 2.ffi Pressr¡re Delta P 0.30 67 ö7 67 6T 68 68 69 70 70 7"1 71 72 72 73 73 73 73 73 73 74 73 73 74 g9 70 70 

### tz 73 72 75 7ö 

## 7t 7A 78 75 

### TI T? 78 78 

### 7s 

## TI TT 73 79 80 80 2 3 4 5 6 T 

# I I 10 11 12 

### .13 14 15 

## l6 17 18 19 

# n .2122 23 24

# Appendix C 

# Equations

## EPA 

## METHODS 2-4 CALGULATIONS
Metered Gas 

### Sample Vofume 

### at 

### Standard Conditions



# 2, Gas 

### Volume 

### of WaterVapor 

### Gollected in lmplnger Liquid

V*q",0)

# : ( v

## ¡ - v¡

### ) x 0.

### 04707

Gas 

### Volume 

### of Water Vapor 

### Collected in 

### Silica Gel V,¿ñtd)

# : (

# w¡' w¡) x 0.047 I

## 5
Moisture Volume FractÍon in Flue Gas



# B*: Yd'ro)*V,weþtd) T wcþtd)

## * T úne6¡q 

## I Vnßu) 

# 5. Moísture 

### Volume Percentage in Flue Gas 

## g6HzO: Bn" 

### x 100


### Absolute Pressure 

### of Flue Gas

# P": Ps* P"uu" 13.6 

# 7- Nitrogen Content 

### of Flue Gas g6 

## Nz:tOï -(z6COz+9óOz+%CO)
Drf''Môlecutar Vüeight 

### of Flue Gas 

## Md:0.44 x%CO2+0.32 xoz6Oz+0.28

## x(% Nr+%CO)
Wet Molecular Weight 

### of Flue Gas



# M,: M¿

## x(I -

# 6þ+ 18x

# 3n 1.

e

4.

6.

8.

o

## EPA METHODS 2-4 CALCULATTONS -

## continued



# 10. Fuel 

### Factor Based 

### on FIue Gas 

### Composjtion 

# ^

_ 20.9 _96O¿ 

### n

# "-- %cor11. Excess 

### Air 

### of Flue Gas



# o/oEA: -

# r,.?ot-o.t*co *roo 0.264% 

## Nr-(%Or-0.5%CO)--- -

### - 

# 12. Average Gas Velocity, 

### ft/sec



# y,: 85.49

### x C e

### x (

# Lp* ),"r

# rffi
13. Area 

### of Round Duc,t

### or Stack 

## lrxD2 

## A": 

# i- ftound ducts) 

# 4x144

# \ ' 

# 14. Area 

### of Rectangular Duct



# ,

# -Lxw A,:

# -l7T (rectangular ducß)


# 15. Actual Volumetríc Flow Rate 

### of Flue Gas 

## Qo:vrxA"x60 

# 16. Flow Rate

### of Flue Gas 

### at

### standard remperature and pressure



# o

# :o

# *l

. 

# P"*sza I 

# !s +a l¡y"+460)x29.92 

# l 17. Dry 

### Flow Rate

### of Flue Gas at 

### Std. Temperature and 

### pressure


## e,¿=

## e, rc

## (I -

# B*)

## NOMENCLATURE FOR 

## EPA METHODS 

## 2.4



# As = Stack area,ft2 

# B,ns = Moisture volume fraction 

# Cp = Pitot 

## tube coefficient (S-type=0.84, Std.=0.99) 

# Ds = Stack diameter, inches 

# ^H = Average meter orifice pressure, in.W.C. 

# ^P = Pitot 

## tube differential pressure, in.W.C. 

# Fo = Combustion 

## factor 

# T = Meter calibration factor, garnma 

# L = Length 

## of rectangular stack 

## or duct, inches 

# Mo = Ðry 

## molecularweight, lb/lb-mole 

# M" = Wet molecularweight, lb/lb-mole 

# Pa = Barometríc pressure, in.Hg 

# P" = Absolute s,leck 

## pressure, in.Hg 

# Qa = Actual gas

## flow rate, 

## acfm 

# Q" = Standard gas flow rate, scfm 

# Qr¿ = Dry 

## standard gasflow rate, dscfm 

# T, = Average meter temperature, oF 

# Ë = Average stacktemperature, oF 

# V¡ = Final impinger volume, ml 

# v¡ = lnitial impinger volume, mf 

# Vm = Unconected metered gas volume, 

## dcf 

# Vm(srd) 

# = Conected gas volurne, 

## dscf 

# vs = Average gas velocity, fr/sec 

# Vy,¡qsta¡ 

# = Gas 

## volume ofwater caught in impíngers, 

## scf 

# Vwss(srd)

# = Gas 

## volume ofwater caught in silica 

## gel,

## scf 

# W = W¡dth 

## of rectangular stack or 

## duct, inches 

# W = Final silica 

## gel mass, gnams 

# W = fnitialsilica 

## gelmass, grams 

# o/oO2 = Dry.volumetric concentration 

## of C'2, 

### olodv 

# o/oO,Oz 

# = Dry 

## volumetric concentration 

## of COz, %odv 

# o/oCA = Dry 

## volurnetric concenüration 

## of CO, %dv 

# o/oN2 = Dryvolumetric concentration 

## of Nz, Todv 

# %EA = Percent excess 

## air

## EPA MËTHOD 

## 5 GR.AVIÍVIETRIC 

## CA.LCULATIONS



# 1. PM 

## Gollected 

## in Probe 

## Wash - Mp* 

## Mp* = (Wp*lm"t 

# - (Wr*)t"n 

# 2. Applicable Acetone Blank Correctiof,



## . B.o* 

# B.p, = l(w"u)r,n,t 

# -(w"àr"*l

# "

# E
3. Maximum 

## Allowable Acetone Blank - B",no



# B"*u = 0.TB4E

# x 0.00001

# * vo* 

# 4. Actual Probe Wash 

## Blank Correction - Bp,n 

## Bo* 

## =^ilNIMUM 

# lB+*, 

# B"rul


# 5. PM 

## Gollected on Filter - 

## M, 

# Mr=(W¡)nrr*(Wr)r"n 

# 6. Total PM 

## Gollected 

## for Method 5 

## Galculations - 

## M, 

# Ms=Mr**Mr-Bpn
NOMENCLATURE 

# 8,'n"* = Maximum allowable acetone blank 

## correction, based on

## weight of 

# B"o* = ä::',:i: il,iíii?#ååf¿nnff3o on residue or brank, srams 

# Bo,u = Acetone blank correction actually used, 

## grams 

# M5 = Total mass 

## of particulate in

## train corrected 

## for acetone blank, grams 

# Mr = Mass gain of

## filter, grams 

# Mo", = Probe 

## wash residue, grams 

# va¡ = Liquid

## volume of acetone blank, ml 

# vo* = Liquid volume 

## of probe wash, ml 

# (W"¡)nn"r

# - Finalweight 

## of beaker containing 

## acetone blank residue, grams 

# (W.¡)a," = Tare weight 

## of beaker containing 

## acetone blank residue, grams 

# (Wr)nn"r

# = Final 

## weight of filter, grams 

# (W),",, = Tare weight 

## offilter, grams 

# (Wp*)nnar 

# = Final 

## weight 

## of beaker containing probe 

## wash residue, grams 

# (Wo*)** = Tare

## weight

## of beaker containing probe 

## wash residue, grams

## PARTICULATE EMISSIONS CALGULATIONS



# 1. Particulate Concentration - C*o

la 

# r¿-=z(M)

# x Tooo 

# è-(¡

# V-(t'o) 453'593 

# 2. Particulate Concentration Gorrected to7olo Oz 

### - C=a@74/oO2
csd@7ro

## =

# c"ax#ffi

3. Particulate Goncentration Corrected

## to 12o/o 

### CO2

## - 

## C*.@I2VICO2 C*@t,rro 

## = Cr¿x

# #, 4. Particulate Goncentration Corrected 

## to 50% 

## Excess 

## Air - C"d@S0%EA
csd@.ov"EA

## = c*dx

# g#

5. Particulate Mass Rate - Mo



# *r=Hx Q"¿"

# *#*

6. lsokinetic Variation - o/olSO 

### ot_,^^


# _ 0.09450*(I"

# * 460)xVr,",,

prX vsxAax timex 

## (1

# - 8,"")

## PARTICULATE EMISS|ONS CALGULATTONS 

# (continued)

NOMENCLATURE 

# An = Nozle area,ft2 

# B'* = Moisture volume fraction 

# Csa = Particulate concentration, 

## grains/dscf 

# Dn = Nozzle 

## diameter, inches 

# )M¡ = Summation 

## of PM 

## collected in 

## sample train, grams 

# Mp = Mass rate 

## of particulate emissions, lb/hr 

# Ps = Absolute 

## stack pressure, in.Hg 

# Qsd = Dry standard gas 

## flow rate, dscfm 

# time = Net sampling 

## time, minutes 

# Ts = Average stack temperature, oF 

# Vm(std) 

# = Corected gas volume, 

## dscf 

# v5 = Average gas velocity, 

## ftlsec 

# YoOz = Dryvolumetric 

## concentration 

## of C,2, 

### o/odv 

# VICO2 = Dryvolumetric concentration 

## of COz, Yodv 

# o/oEA = Percent excess 

## air 

# %olso = Percent isokinetics

# Appendix D 

# Raw 

# Field Data

# A 

# ú?.r4

FACIUTY: 

# srARrrMeE0f

# =*"rÈE- polLr.trArrrr; 

# Pn lsoKttËTl ÎEST LOCATÍON:'



### . 

### cilAtNoFcusr@Y: (ruNrÂrNt R SAfi¡PTC ID. DESCRIFTlON 

### I 

# z J 

# 3u< fVo*If-iro 

# u ?ryÃffi 

# fJltl-h-"" v LEAKCI{EG¡* VACUUM 

## Tç" 

# 15" f

# f-t f

## ôi, RÂTE 

# ,ùaj -6Ð3 

# .æt 

# ,ûFTEST I-0CATION; ISOKINETÍ C SA¡TPTÀIG DAIASHÉHT 

# **r,*' i545 e¡pnr¡rrl6'

# l- eou.wmr: --- 

## F,/,? Rt)Nt.È.t!oqN,þ-rR18 

# *u*a*, f

LEATCC}IECK CONÍA¡æ R SÁl,Ff.E l.D, ÐËscRrFïosû 

## I 

# z
4 

## i) 

# 3io frr./i

# E"- ü .'4r I 

# tl.

# óur,æ VACUUM 

# il" Ior loD
8¡1TE 

# ,ñ4

.

## ôa5 

# ,6Ðtl

NOZLEM 

# k3 .]¿t
PITOT# 

## Q,lq BOXI.Þ, 

# 7
GAMIIIA 

### I 

# LqaËt ellÉb 

### t

# -? t4tq Fm 

# &,(

FILTER 

# h1

# -'00

TECH. 

## J

# I.L

# k=

# 3,!

FACIUfi: ST LOC.ATIff.I: 

## srmrn¡æ:

# o79?

# - olonn¡e 

## lo i

# ? pöturrnr.rr:

öHEC|C VACUUM 

# l5'r 

# tÞ" fo

## ìt

RATE 

## .oÐ11 

# ,tô3.



# . a03

NOZLEM 

# kl .l¿t
PITOT# 

# 4"1 BOXt.D. 

# '7 GAMIj'Å( 

# ù+l(Õ

elltfìl 

# l.'t4t4

P".o 

# il-,r

FILTER 

# 01*'àE
TECH. 

## -J

# R{

# Append¡x D.2 

# EPA 

# Method 

# 5fOïM'28 Raw 

# Field DataMEI,HOÞ ætsqlcNEnc sÂIr{pLtNG pÁTA SHEET -TESTLGAIION: 

## P"*

# 7t-'{ FOI"I-tJTÂ¡Íf: 

## 1'P ,4 

## P,{C{ OF 

### DATE: 

## /lr*¡rt-æ ptuvt.D.:fut 

## -uQÆ"aSA-



# *{

## lL

# t. PAGE_ 

### OF_
POLI-UTA¡rIT: 

## 1fA RUNI.ù.t#va 

## -tù\ffiR'lL 

# j,(,Ç 

# rrctlNtcl¡N{LI,IETHOÐ 23 lSOl(lNETtC SAMPL|NG DATA SHEET 

### PAGË-OF
: 

### .TE$rLocA-îo*- 

# I7 D^rE:

# Á*//-éf
-. ,. 

## re*r¡rcnr¡ 

# .ff-JrL p*^

# Zi

# Ç POLLUTAIIT: C-P

## -H.

..

## .--

## _ RUN 

### t.Dj

## -æ -ÃkdttJt|S&e

# d ÒA 

## 7
21 

# z
tc

# Appendix D.3 

# EPA 

# Methqd 138 Raw 

# Field DataTECHHIcIAN 

## bW Ps E 

## pou-urn¡n: C. 

## ¡nLrol 

## C¿ad¿+#r 

# \

.. PAGE 

## I OÉ--

RUN l,

## Þ.:Sq-jfi¿l3$-:¡- 

# â

NOZZLE M 

# =Èq BS PlïoT# 

### t3J BOXID 

# tl
GAIfif'rAl 

# t.sJ6fl eH@ 

### I

# rr*û
,,PROBË ID 

# Ft tb: I SYSTEM ID 

### ?

## 'ttuq 

## lt4*
FILTER ID 

### Urútáa¿rrPAGE 

### '.QF¿ D|ATE:

# ôqr ft__¿g_

nuur.o.r 

## lú¿

# ofvrß4.¡?



# . ïEctrurcr¡l¡

# et?¡J pu^*

# ?*.i- pouufÂrr; 

# f'o¡t 

# ¡l C¡-al"zæ¿,Ér'



# tJ

NOULEÀI 

# î.q '85

PITOT# 

## r3f
BOXID 

# Íl
GA¡¡liIA

### f 

# t Åq 

### l"L+ eH@ 

## J.-7 

## N}L
PROBE IÐ 

### Pu 

### th- | SYSTEM ID 

## ?rl lÌirì"

# 4 lun 4
FILTER IÞ I 

# uilT*trn

't



## ,'I

# Jor(

RUNt.D.tfro 

### rÊ-M 

## lîg -R

# t .PAGE 

### Porrur¡Nr; Carvbwl 

### úolul*.rqrú¿

OF CUSTOT}T .-...., '1.lrtìtj '':ij"l'tï; -'-r:i::l 

### :,;:

NOA.E M 

# ,&4ßs
PITOT# 

## I?I ErôYtfi - 

# tf
GAMIIAf 

# l, t

# ]t4
eH@ 

# L

# tt 4l.
PROEE ID 

# PL IbSYSTEM ID 

# frtilt-f /ue a F]LTER ID 

### t)l¿,TêEëD

# AppendÍx Ë 

# Analytical DataGRAVTIH 

### ETRIG 

### LÂBORATORY DATA 

### FÍNAL BEAKËR IIY€IGHTS

JOB T,IAME: @NTRACTI.{O:

### GRAVIMËTRIG T.IEORATORY OATJT FIHTTL 

### BEA¡TER WETGHTS

JOB t'tAME: CONTRACTT\¡O;



# I



# r

# Appendix E.2



# Analytical Data

# for EPII 

# ll¡lehod 

# l3B Anal¡rses

# First 

# Analytical Laboratories ANALYSF REPORT

Mettmd 

## CTM 13b: Sulfate 

# *ïr,fìfr

Reviewed 

## and,{pproved by;

l,aboratory Manager 

## JuIy 

## 13, zcÆ9

Ðo nol

### tryrcdnce this 

### rqon acep in wlnle witlwut the permission of thc 

### Iafuñory.

# First Analytical Laboratories
CASH NARRÁ.TTVE 

# Froject#:Il Report 

## Dafe: l3-tu1-09 

## Clîsnh

# Air Comptlqqce 

## Grot¡p L.,,ç,,L 

## rlu-tËut

# r-.r
Samnles: + 

## Twelve samples

## were 

## flIbmiüed for deærmination 

## of sulfaæ 

## by Method 

## CTM 

## 13b. Ttrree

## of these

## were

# blanls. Three day 

## rush service was 

## required

## for these 

## samples- 

## AII of the sarnples rvere 

## receivsd 

## with custody seals 

## intact and

## the 

## liquid Ievels 

## marked and 

## no apparent

## teakage, 

## Afrer analysis, any 

## remaining amounts 

# of the samples

# will be retained 

## by the 

## laboratory 

## for six months and

## then discarded,


## henaration: These 

## sanples did not 

## require any

## preparation. The sample 

## volumes applied were obtained 

## by measurement here at 

## fhe 

## laboratory. 

## Apdysis: Sulfate was

## determined 

## by lon Chromatogfaphy 

## with conductivity detection 

# (rc).

Results: 

## The results are preseuted as

## total milligrams 

# of sulfate found 

## in the whole sample. To convert 

## milligrafits 

## of zulfate ro 

## miiligrams 

## of SOr, 

## muttiply the 

## result by

## 0,833. 'To 

## convert

## to SO2, 

## multiply by 

## Û.66?. Sulfaæ rvas measurable 

## in 

## all

# of the 

## sanples. The highest 

## levels foundwere 

# in the hydrogen peroxide impinger solutiür-$

## which ranged 

## ftom 165 

## rng

# w 223 

## mg. Oualitv Control: The spike 

## recoyery 

# (n@was within the acceptable 

## range

## of 75T' 

## ttL25'ÃAll of the 

### samples 

## were anatyzed 

## in

## duplicate. The ending calibrations lryere 

## in good agreement 

## with the 

## initial calibrations.

# First AnalytiCal 

# LaboratOries

# J* (e1e)e4i2-s60? 

# lrzó Burning 

## rree 

# Dr. Chapel 

## Hill, 

## NC 

# 27517

# *#rJiRtr*:Ítr

Proiecr 

## #:

:

# - Clienl: Air Complionce Gruup



# - ANALYSIS RËPORT
Report 

## DuÌe: l3-Jul-09 Dale Received: t

## 0Jul-09

Totol 

## itilligroms ín,Somple

5o¿ mg

1Ó.2 

## o.8l ró5 Somple

3004 3005 

# ' 300ó

QUAL 

### lTY CO N

### TTO

# I SUItrtfitARY



### $pike. %

# Recovery '9OTo

# First

# fuialytical Laboratories 112ó 

### Burning Tree 

# Dr Chapel 

## Hill, NC 2'1517



# ANALYSIS REPORT

Prolect 

### *tr

# lll Clienl; Air Complionce Group Client Proiect lD; Report 

## Dule: l4-Jul-09 Dote Received: 

## l0Jul-09

Somple

3001 

### 3002 3003 3007 '3008 

## 3009 4000 4001 1AO2 

## Totolfitliltigroms 

## in Somple
5oo mg

r

### 3.9 0-3 

## 223 

## r8.5 Q,4 

### 203 1.59 

### 0.03 0.38

# SUIFATE

ICANALYSIS RU 

### N

### sufi IIIANY

### ANÞ C,ALCUTAilOH ÌYORKSHETÍ


### Clîenft Air Complionce 

### Group 

# r'ni.*'||] Dots: l0-Jul-09 MÐL

# = 0.1 mg,/L Spiks 

### concenl/n 

# = 20.0 mg/L

907I O.

# Rfr-04 17

# .C5 r

# 80 149

# .6 5 I 6, I

### ó 

# 907ïO.Rit-05t.6e 96 t4.l 5 0.8I 

## 90710.R3-Oó 

# 3r.0ó 266 2s8.8 20 165-23

907r

## o.R3-04S 35,90 

# 299.16 9lRec.= 89.896 

## QUÃLITY COHTROI DATA
Peok

## Ht, True conc. Somple

# lÞ Tesf 

# Sorrrple Peok Dil'n Totol 

# Clienl FAt Sol'nVolume 

# Height Faclor mg 

# mg/L ml os SOa
3004



# . 30{}5 300ó SpikÊ



### t'olibrotion Blonk Stqndond 1 

## - Stondqnd2 Stqndqrd 3 Stondord 

### 4


## ' Regresefon 

### $ûcll¡tirs RSquore Stundoñd Error Observnlions 

# 0.99978 lnlercept O



# 1.940 X

# Yorioble 8.33 5 0.0 84.9 

### ró5.2 247.5 335.4 

### o-0 IO-O 

### 20.0 30.0 40.o Regr 

### o.o 83.3 166.6 

### 250.0 333-3

# SUTFAÏË

ICANATYSIS RU 

### H gUiil¡IIIAHY 

### AND GALC U I,AII 

### ON WORKSH¡ ET 

### Clienh Åir Complionce 

### Grcup 

# rro¡*'Jf Duts; l4-Jul-09 MDL

# = 0.1 mg/L

Somple lD Clïenf



## 3t0r 3002 

### 3003 3007 3008 

### 3009 4000 400r 4002 FAt



### 907t0,R2-0r 907',to.w¿-oz 90710,R2-03 

### 907lo.M-07 907ro.M-08 907ï0.R4-09 

### 907r0.8-00 907ro.B-01 

### ç07r0.8-02 

## Te¡l Somple



## Sql'n Volume 

## mg/L ml
ì

### 7.1ï 

### t-28 39.1 ó
r

### ó.84 1.O4 

### 28-79 

### o.f9 0.33 

### 0.77 

### tó3

4T 

### 285 224 85 

### 352 

### t00 too 100 Penk

Hbighr

15T,0 

### t 

### r.3 345.5 148.ó 9.2 

### 254.4 7.0 

### 2.9 ó.8 Díl'n

Fqctor

Ë 

### 5 20 5 5 

### 20 20 I 5 Tolql 

## 'mg

os SOa
13,94 o.26 223.21 't8,52 Ð.44 202.67 

### t.59 0.03 0.38 

# QUATITY CONTROT ÞATA Cnlibrution Blonk Stondqrd 1 Stondord 

### 2 Stsndond 3 Stur¡dqrd 4 Stondord 5



### il,egrcssion Stotíelice RSquorè Stundqrd Error Observations Peqk Ht. 0-0 

### 48.8 ì

### 03.8 176.4 

### 264.4 348-S True conc. 0.0 5.0 IO.O 20.0 

### 30.o 40,0 Regr 

### 0.o 44-1 88.2 176.5 

### 264.7 353.0



### r.99ó80 7,501 ó lntercept

XVorioble 0

8.82

# 007I0



# TIIEATR COMPLI^A,NCE GROUP, 

# LLC Jufy 

### 8,2009
Firsú 

### Analytical Laboratories 

## 11âãBumirg Tree Drive 

### ChapelHill, 

# NC 77514 (e19) 

### s42-8S07

ATTN Sarnple Custodian : 

### Accompanying this 

### letter arc 

### sarnples frcmfour (4) CTM 13b samples (3 runs 

### and 1

## blank), We

### warrt 

## you

## to anal¡r*e 

## run 3,

## sample numberc 3004 300ã, and 

## 3006. The samples are 

### to be analyzed in 

### accordance 

### with CTM 13b 

### procedures. Flease trold 

### the rest 

### ofthe samples 

### urttilwË see 

### the results 

### from run J. 

### These samples are

## to have a

## 3-dayTAT placed on them. Please note 

### the following: 

# + Chain+f-Custody 

## sheeb accompany 

### the samples 

### and should be

checked 

### to ensurethat any holding tirne 

### requirements are met. 

# + Please submit 

### complete documentation for

### the analysis of 

### one

single sampling run. 

# t Please incft¡de 

### a narraltve stating any probletns, 

### or lack

## thercol

with the sampfe 

### processing or 

### analyses. 

# Subject: CTll 13b 

## analysis 

## fo

# î33Fi"hîiiFrank Crai'ghead, QSTI Pro¡ect 

### Manager endosure Sincerely, The 

### Air Gompliance 

### Group, LLG 

# Fnt

Ite.Àir Comptiance 

### Group, 

## LLC 5075Ho[insRoad Roanoke, Vr+, 24S19 

### Phone; (5d0)2ó5-r9t7 

## Fnx: (541)265-{,1082

# ÐtlT10

CHAII¡ OF CUSTODY
CONTRACTID
COt'fiRACTNUMBER



## - M 

# [ 

# 'l 3 B 'ISWANTE

ID TOI{TANER

NUMBËR TEST

LOCÂTION RUN ID SAMPI.É

TYPF \TT3LUME INITIALS DATÊ ]OMMENTS 3001 1 s00 s00.cTM13b-R2 PA FPC FPC FPC
FPC FPC FFC
FPC FFC FPC
FPC FPC FPC tt't0/200f X 300i I s00 soo-cTf\¡13b-R2 FIller H202 ô/10/200! X x 300! l' so0 soo.cTMlsb-Rz 8t1 012009
3004 1 s00 s00.cTM13h-R3 PA Ê11û/20ff X x x 300! 2 s00 soù.gTM13b-R3 FIlter .1Ðlrz 8/10/20û! 3006
3007 3008 3009

4Ð00 4001 4002 3 Êo0 soGCTM13h-R3 6/10t¿0ût

'l so0 soecTM13b-R4 PA 611 1t2000 x X 

## Ì

X X X 2 s00 stxÞcTlul3b-R4 F¡ltÊr ¡t202 Ê/rí]1200É 3 SÛO SOO-CTM13LR4 B/1 l¡200S

,| Bl'ånk

Blsnk Blank Bì.4}.¡K ¡PA E¡'|1/20.ûJ B/1 1l20f¡s 2 BLANK H20 + ËLANK H20Ê û111Þ0{rE

I FIY¿T TE ,ISHED EY: 

### rÉ IBY: ATE AirGom$sncaGruup, LLC 5O?5 HOLLÍNS ROAD ROANOKE. VA24+12 ,f -/:4.'-¿ 

### Å- H-x I'l¿l* F- -F ã 

# )-)ã, ìELINçII.,I$FIEO T'Y: )ATE 

### ;ttvtsu ttY: 

# ]ATE HRËLI¡Tç¡ÚSìHEdBiJ'ilDATË 

## 'Jil¡J*tr¡t+r FÈL 

## ìnûlfl ÚT,IJ ËY: }ATE IISHEOBY: (EGEIVFU ËY:

# Air Gompliance Group, LLC 5075 Hollins Road 

# Roanoke, 

# VA 24019



# Project No:



# Condensables

EPA Method OTM28



# Analytical Repoil 12659

Element 

## One, lnc. 5022-C 

### Wrightsville Av.,Wilmington, 

## NC 28403 91 0-7 

### g3-0 1

## 28 FAX: 

## I I

### 0-792-6853 e 1lab@-e 1

### lab.

### com

### The following data for 

### Analytical Report 12659 has been reviewed 

### for completeness, accuracy, adherence to method protocol, and compliance with quality assurance guidelines.

Review by: 

# f,,,,r*ol,rk

Renee 

### Chek, Chemist June 

### 29, 2009

Report Reviewed 

### and Finalieed By:



### June 

### 29, 2009



## elernentOne 12659ACG OTM 2Ê Report 

### Packet



### 2 o'Í 13

# SUTVIMARY 

# OF RESULTS

elementOne 1265S 

### ACG OTT\,! 28 Report Packet



### 3of13

## Summary of

# Analysis
Summary 

## of Method OTM2Û 

## Analysis

Fractlon lnorganic GPIS 

### lnorgan ic Nl-l+ 

### Conection Total lnorganic CPM 

### Organic CPM 

## TotalCPM* S00-Run 5 e12659.1 

### Catch, mg 

### 37.3 1.14 36.1 

## 2.60 38.2 $00-Run 7 e12659-2 

### Catch, mg 22.5 0.409 22.1 

### 0.600 22.2



### Field Blank ef265È4 

### Catch, mg 

### 0.400 0,00 0,400 <0.10 0.400 SOO-Run 

# I 6f2û59-3 

### Catch, mg 

### 22.9 1.31 

### 21.8 

## 0.200 21.3



### Fraction lnorganic CPM lnorganic NHa 

### Correction 

## Totallnorganíc GPM 

### Organic CPM 

## TotalCPM "With Field Blank

### Corredion



## elementOne 12659 

### ACc OTM 

### 28 Report Packet



# . Fage 

### 4o113

# ANALYTICAL NARRATIVE

elementOne 12659ACG OTM 28 Report Packet

Page 5

### of 13

## Elernent One

# Analytical Narrative

$umrnary of

## Analysis The EPA Method

## orM28 samples were prepared, extracted and measured according to rnethod 

## protocol. Each 

## filterwas exûacted twicewith 20mL 

## of deionized water, sonicated for at least 

### two minutes and 

### the extract removed, 

### The two extractswere then combined.wifh the agueous lir¡uid 

### impinger sent by 

### the client.The same filterc were again extrac.ted 

### twice 

### with 20mL of methylene chloride (Meclz) and 

### sonícated beforc the eHract was 

## rernoved. The two melhylene chloride exhacts were cornbined 

### wÍththe organic rinse 

### sent by 

### the 

## clienl. The combirred 

### aqueous impÍngers 

### and cornbined 

### organic impingers were extracted

## together. This step 

### was repeated 

### twicewith 

## s0 

## rnl of Meclz. Followíng extraction, the 

### aqueous impingerwas evaporated to dryness in a

### tin andthe organic rinse was evaponated 

### to dryness in a

### Teflon 

## bag. The organic fractionwas desiccated and 

### weighed to 

## a constant 

## weight. After the agueous impÍnger 

### was dry,

## the samplewas redissolved in 100mL 

## of ultrapure deionized 

## water- A pH was 

## taken and 

## the 100mL redissolved sample wastítrated with 0.090N arnmonium hydroxide to

## a pH 

### of

## 7.0. The sample was placed into a tin, 

### evaporated to dryness and 

## weþhed to a 

### constant weight. 

## Analysis QA/QC 

## All laboratory A,A/QC 

### guidelines werefollowed in

### the analysis of

### the samples. 

## AddÍtional Gomments The OTM28 Method ammonium conection factor has 

### been 

## implemented. EPA 

### Method OTIVI-28 

### Section 9.10states that 

### from the 

### fietd sample 

## weight, the condensable particulate mass of

### thefield

## train blank 

### determined 

## will be subtracted, or 

### 2.0m9, whichever is less.



## elenrentOne 12659ACG OTM 28 Report Packet

Page 6 

### of 13

# SAMPLE CUSTODY

elenrentOne 12659 

### ACG OTM 28 Repoft Packet

7 

### of13

# (r

!1 \Þ 

## fr¡ 

# I Ës€ 

# I *ÊË 

# Ër= $ËË Ë 

# ff

E r¡ 

## a u 

# gg ËË* =ËË ËËt



# frÞ ËËË ËEÈ ãFË

elernentOne 12Ê59 ACG 

### OTll 28 Repoil Pad(et

PagË

# I of

## t3

# ANALYTICAL DATA

elementOne fZSSg ACG OTM 28 Report Packet



### 9of13

# Analytical Galculations

lnorganic CPM

## Total 

## lnorganic CPM, m¡r 

## (rngl = 

## rti -

## t¡c Where. 

## m¡- inorganic fractÍon CPM after evaporation and 

### titration-oTwz1 crtndensibta wo¡t<sheet 

## mr- amount of 

### ammonium added (mg) 

## -- ammonium worksheet



## Ammonium Correction factorTotel ammonium added, 

## m, (mg) = 12,03*Vr*N

## Where17.03- 

### corectionfactorfor ammonium

# - ËpA Method OTM 2g
Vt 

### =volume of 

### titrant added

# - ammonium ur¡orlçs/¡eet 

### N

### = Norrnality of

### titrant

# ^ ammôniumworksf¡eef


## Tohl CPM

## Total 

## Condensible Particulate Matter, mt 

## (mg) = 

## rl¡r

# r mo

## Wheremn= 

### total inorganic CPM

# - OTM2B Conde¿siöle r¿¡o¡frsf¡e€t

mo =

### total oryanic catch

# - OTMZBAondensible 

### worksheet



# etement0ne 12659 ACG OTM 28 Report Packet

Page 10 of 13

# ëlêmentone AIR TESTTNG 

## sAltñpLE

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# FORM Lab

# lD i265g Anaþis Due 

## Date 06.24.09 CIA/QC/Report Due 

## Date 06.26.09 

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## elementOne 12659 AÇG OTM 28 Report Packet

Page 11

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## elernentOne 12659 ACG OTIVI 28 Report Packet

Page 12 

### of 13

DâIe: 

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## elementOne 12659 

### AgG OTM 2B Report Packet

Page-13 of 13

### INTËGRATED 

### BAG Añ¡ALYSIS 

### DATA



### Job Hame 

# Gontract 'd 

### Èlethod of ^Analusis 

### 3A Date D6/,tOffìo 

## - o6fi,ttûg

# Appendix F 

# Field Equipment Galibration Data

## TYPE S PITOT 

## TUBE INSPECTION 

## DATA FORM

BE 229

PITOT TUBE ASSEMBLY LEVEL?
TUBE OPENINGS DAMAGED?

Pa 1.25 Pb 48 1.25 

### =Pa
Dt 0.95 - 0.95 cm 

### Pa=Pb=[1.05-1.50]xDt

A

cornments

CALIBRATION REOUIRED?
lF NO CALIBRATION REQUIRED, BY DEFAULT PITOT COEFFICIENT 

### (Cp)= 6.34
INSPECTED BY

## TYPE S PITOT 

## TUBE INSPECTION 

## DATA FORM

PITOTTUBE

# ID I 144 

# DATE 

# I tnAtZOOA

PITOT TUBE ASSEMBLY LEVEL? yes

ves 

# I-l PITOT TUBE OPENINGS ifyes, see Note A

< 100 100



### z 0.05 < 0.32 cm 

### <50

< 0.08 cm 

### =Pa 1.2s 0,48 - 0.95 cm 

### Pa=Pb=[1.0S-1.S0]xDt

A

comments

CALIBRATION REQUIRED?
lF NO CALIBRATION REQUIRED, BY DEFAULT PITOT COEFFTCIENT (Cp) = 9.94 INSPECTED BY JBS

1 4

3 2 0.04
Pa 1.25 Dt 0.95

## TYPE S PITOT 

## TUBE INSPEGTION 

## DATA FORM

PITOTTUBË 

# ID I 13I 

# DATE 

# I 7t17 008

PITOT TUBE ASSEMBLY LEVEL? ves

ves 

# r_:l TUBE OPENINGS DAMAGED?



### betal 2 < 100



### <50 < 100 <50

< 0.08 cm 

# ffi=ra pa=pb=[1.0S-i,50JxDt

A

Other comments

CALIBRATION REQUIRED? yes

lF NO CALIBRATION REQUIRED, BY DEFAULT PITOT COEFFICIENT (Cp) = 0.84
INSPECTED BY JBS

1 

## I 4
2Page 1 of 2 TheA¡f Compliance Gfoup. LLC

EPA Method 5 Meter Bor Calibration Pre-Test Or¡ficê Mêthôd

Met€rBox # 

### oate: 04114109 BaromelricPressure: 

### _lÊJ!.Q_(ín.Hg) ïh€or€l¡calCritícal

### Vâcuum; 

### 13.54 (¡n. Hg) Calib¡ation

### Techniclan: MSH

-.- DRY GAS METER READINGS_--------.----

AH {¡n H2Ol 0.26 0.26 0.6 0.6 1,1 1.1 1.9 1.9 3.4 3.4 Time

fmlnì 5 5 6 6 5 5 7 7 5 5 Volume Total 

### ú:) 1.545 1.567 2.722 2.738 3.Olf 3.026 5.433 5.460 5.232 5.1 95

62.O 62.0 62.0 82.0 62.0 62.0 62.0 E2.O 62.0 62.0 9.0

64.0 64.0 64.0 65.0 65.0 66.0 66.0 67.0 69.0 

### Volumê Volum€ 

### lnitiâl Flnâl 

## ffr') (ñ:) 

### 716.û68 717.613 

### 717.613 719.180 

### 719.180 721.902 

### 721.902 724.640 

### T24.UA 727_651 

### 727.651 730.677 

### 730.677 736.110 

### 73ô-110 741_570 

### 741.570 746.802 

### 746.802 751.997 ldeo F) {deo F) (deg F} ldeo Fì tñit¡al Temûerâfur€ 

### lnlet Outlet F¡n4ljlamoerâturê



### hlet Outlet 

### 64.0 64.0 64.0 

### 64.0 64.0 64,0 

### 64.0 64.0 64.0 

### 64.0 64.0 64.0 €4.0 64-0 64.0 

### 65.0 64.0 

### 64.0 66.0 

### 64.0 66.0 

## 64.0 67.0 6s.0 

## 65.0 69.0 66.0 

## 66.0 70.0 66.0

CRITICAL ORIFICE READINGS

Ambient Temoerature Averâoe T€moerature 

### DGM DGM AmbieIlt 

### Outlet Overall Temp ldeq

### R) (deq

### R) (deq R) 

### 524.0 524.0 522.0 

### 524.0 s24.0 522.0 

### 524.0 524.0 522.0 

### 524.0 524.t 522.0 

### 524,0 524,5 522.0 

### 524.0 524.A 622.0 

### 524.0 525.0 522.0 

### 524.5 525.5 522.0 

### 525.5 526.8 522.0 

### 526.0 527.A 522.0 

### OrÌfice Actuat 

### Se¡ial# K'Orifrce Vacuum 

### lnumbe¡) Coefficient lin Ho) 

### KS-40 0.2406 23.0 

### KS-40 0.2406 23.0 

### KS-48 0.3497 22.O 

### KS-48 0.3497 22.O 

### KS-55 0.459f 20.0 

### KS-55 0.4591 20.0 

### KS-63 0.5898 18.0 

### KS-63 0.s898 18.0 

### KS-73 0.8057 í5.0 

### KS-73 0

### 8057 15.0 lnitial ({eg Fl 82.0 62.0 62.0 62.O 62.0 62.0 62.0 õ2.0 62.0 62.0 62.0 62.0 62.0 62.0 ô2.0 62.0 62.0 62.0 62.0 62.0 

### Final Average ldeo

### FJ {deg Fì

IMPORTANT: For valid test results, lhe Actuaf Vacuum should b€at least 1to 2 in. Hg greâter than the Theorel¡cel Criücal Vâcuum shown âbove.P^ge 2 ot 2 ThèAir Compl¡ânce Group, LLC

EPA Method 5 Meter Box Cafibration Pre-Test Orif¡ce Method

Meter Box

### # 4 

### Dâtê: 04114109 Earometrlç 

### Pressurei ____?9.20__ (in. HS) Theoretical Critical

### Vacuum: 

### 13.54 (¡n. Hg) Calibratíon

### Teohnícian: MSH

oRtFtGE 

## ----- VOLUME 

### VOLUME VOLUME 

## CORR. CORR. NOMINAL 

## Vc(std) Vc(std) Vcr 

## {e (ilters) f81 RESULTS



### .-- DRY GAS METER

### --- VOLUME VOLUME 

### CORR. CORR, 

### Vm(std) Vm(std) 

### fft"t ll¡rers) 1.494 1.515 2.634 2 649 2.515 2.928 5.265 5.246 5.072 5.027

1.O117 0.9975 1.OOO7 0.994Ð 0.9894 0.9849 0.9851 0.s812 0.9977 1.0067 0,9950 42.3

42.9 74.6 75.0 82.5 82.9 149.1 149.7 '143.6 142.4 42.8 42.8 74,6 74.6 81.7 81.7 146.9 146.9 143.3 143.3

lmm H2o) 39.31 39.31 42.94 42.94 45.67 45.67 47.80 47.75 45.71 45.66
44.28 1558

1.558 2-718 2.718 2.573 2.573 5.347 5.347 5.218 5.2't8

lln H2Ol2 -0.2 -0.2 -0.1 4.1 0.1 0.'l 0.1 0-l 0.1 0.1 0.0 ----. DRY GAS METER.--
CALIBRATION FACTOR 

### "Y'Value Variation 

### {numberì fnumber) 1

0.02 0.00 0.01 0.00 -0.01 -0.0r -0.01 -0.01 0.00 0.01 0,00 1.511 1.511 z,ÕJ0 2.636 2.844 2.884 5.186 5.1 86 5.060 5.060

(in H2Ol 1.5475 1,5475 1.6905 1.6905 1.7981 1.798',1 L881 9 1.8801 1.7994 1.7977 

### Average 1.7431 oRtF¡cE 

### --.-.-

CÂLIBRATION FACTOR "AH@'Value 

### Vâlue Variat¡on

Avemge 

## | = 0.9950 

## AH@= 1.7431

Pass

Notes: r For Cal¡blation Factof Y, the râtio of the reãding of the calibrâtion meter to lhe dry gas mete¡ acceptable tolerance of individual velues fiom lhe average is

### t 0-02. Var¡at¡ons shown hêvê bêên mundêd lo nearest 0.01

. 2 For Orifice Cal¡bration Faclor^H@, thê ófificê d¡fferential pressure in ínches of H20 tfiat equâtes to 0.75 cfm of aír at 68 deg F and 29.92 lnches of Hg, acceptable toleËnce ol indiv¡dual values from the average ls* 0,2, VanìatÍons shown have been roundêd to nearest û.1

-

QÄ/QC Performêd By: 

### Date; 04n7ß9Page f of2 TheAir Compliance Group, LLC

EPA Method 5 Meter Box Calibralion Post-TestOrlfice Melhod

Meter Box # 

### Date: 61221200S Barometric 

### PressureÌ 28.950 (in. Hg) Theorêtlcãl Critical

### Vacuum: 

### 13.ô6 (in. Hg) Calib¡ation

### Technician: FPC

DRYGAS METER READINGS

AH lin H2Ol l-10 Ll0 1.10 ïme

(min) 10_0 10.0 10.0 Volume

lnitial 

### (fll 785-639 791,614 797.671 Volume

Final 

## d) 791.614 797.671 803.726 Volume

Total 

# nl 5.975 6.057 6.055 lnitial Temp€rãture



### lnlet Outlet Final Temoerature



### lnlet Outlet



### Orifice Actual 

### Serial# K

### Orífice Vacuum 

### lnumbef) Coefücient {in Hq) 

## KS-55 0.4591 

## KS-55 0.4591 

## KS-55 0.¿1591 Ambient Temoeratu¡e 

## lnitial Final Average ldes

## Fl ldeg

## F) (deo F) 

## 80.0 80.0 80.0 

## 80.0 80.0 80.0 

## 80,0 80.0 8û.0 22.O 22.0 22.O CRITIGAL ORIFICE READINGS (deo 

### F) ldeo.

### Fì ldeo

### Ð ldeo Fì 

### 84.0 82.0 8S.0 84.0 

### 89.0 84.0 92,0 86.0 

## 92.t 86.0 

### 94.0 87.0

Averâoè T€mo€tetule 

### ÐGM DGM Ambient 

### Oullet Overall Temp (deq 

### R) ldet

### Rì ldeo R) 

### 543.0 544.8 s40.0 

### 545.0 547.8 s40.0 

### 546.5 549.8 5¿10.0

IMPORTANT: For val¡d test results, the Actual Vacuum should be I to 2 in, Hg greater than the Theor€t¡cel Critical Vacuum shown äbove.Page2 aÍ 2 The Air Compliance Group, LLC

EPA Method 5 Meter Box Celibrâti0n Post-Tesl Orifìce Method

Meter Box # 

## Date: 061ru09 Berometdc 

### Pressure: 28.95 (¡n. Hg)
Theoreticäl Critical Vacrrum:.. 

### 13.66 (in. Hg) Calibral¡on

### Technician: FPC

ORIFICE RESULTS



## - DRY GAS METER



## - VOLUME VOLUME 

## CORR. CORR. 

## Vm(std) Vm(std) 

## (fll {titers) 

## 5.617 159.1 

## 5.663 160.4 

## 5.640 159.7



## - ORY GAS METER



## - CALIBRATION FACTOR 

### 'Y'Value Vâriâtion 

### {numberl (number) 

## 1.0183 0,004 

## r.0100 -0.004 

## 1.0140 0.000 ORIFICE CALIBRATION FACTOR "ôH@"

### Value Value Vâriâtion lin

### H2O) lm.rTJ2O) (in H2Oì VOLUME CORR. Vc(std) tn.l 5.720 5.720 5,720

1.7796 1.7730 1.7682 

### VOLUME VOI-UME



### CORR. NOMINAL 

### Vc(std) Vcr 

### (lítersl (f1 

### 162.0 6.048 

### 1Ê2.0 6.04€ 

### 162.0 6.048



### 45.20 0.006 

### 45.03 -0.001 

### M.91 -0.005

AverageY6"a¡ 1.0141 Averâge dH@ 

### (p.9 1,7736

Test Avg. Gamma 

## (Y{po"q): 1.0141 

## iation: 0.0191 of

## Y: 0.0498 <ão/o

## otYT Yes
Note: The Variation labsolute value of the Calibrafion Fâclor Gârnmâ {Y) minus the PostTestAverage Gamma (Y¡p*r))l musl be less than or equal to 5% of Calibration Factor Gamma (Y).

QAJQG Pêdormed By: 

## Date; 6l23l200s

### THERMOCOUPLE 

### CALIBRATION DATA

Meier Box

## lD: 4 Meter BoxThermocouple: Stack Temp. Reference Calibrator

## lD: BTSZZB Reference Calibrator Model: HHZI CAL-K Reference Calibrator

## Type: K

a Difference, % (Based on degrees Rankin): 

## ' Absolute Difference =

bAverage Absolute Difference must be < 1.5%.

Calibration Performed By:

QA/QC Check Performed By: 

### Averageb

# I o.l Pass/Fail

## ? I Pass 01/16/09

x 100 1 2 a 4 5 o 7 

## I I 10 11 0

32 100 212 300 400 500 600 700 800 900 1

33 101 213 300 399 501 600 702 801 900 0.2

o.2 0.2 0,1 0.0 0.1 0.1 0.0 0.2 0.1 0.0

### THERMOCOUPLE CALIBRATION DATA

Meter Box

## lD: 4 Meter Box Thermocouple: Probe Heat Reference Calibrator

## lD: 875228 Reference Calibrator Model: HH71 CAL-K Reference Calibrator 

## Type: K

a Difference, % (Based on degrees Rankin): Absolute Dífference =

bAverage Absolute Difference must be

### s 1.5o/o,

Calibration Performed By:

QA/QC Check Performed By: 01/16/09



### Averageb 

# I o.t Pass/Fail 

## ? I Pass

I (Ref. Temp.+ 460) - (TC Temp.+ ¿00) |

Ref' TemP. +

## 460 x 100 Reference Point Reference

Temperature lotrì Thermocouple

Temperature loFl Absolute

Dlfferenceå lo/^\

1 2 3 4 5 b 7 0

32 100 212 300 400 500 0

32 ôo 211 300 402 501 0-0

0.0 0.2 0.1 0.0 o.2 0.1TH 

### ERMOCOUPLE 

### CALIBRATION DATA

Meter Box

## lD: 4 Meter Box Thermocouple: Filter Heat Reference Calibrator

## lD: BTEZZ9 Refere4ce Calibrator Model: HH71CAL-K Reference Calíbrator

## Type: K

a Difference, % (Based on degrees Rankin): Absolute Difference =

bAverage Absolute Difference musi be S 1.5%.

Cafibration Performed By:

QA/QC Check Performed By; 01/16/09



### Averageb 

## I o.l Pass/Fail

## ? I Pass

I (Ref. Temp.+ 460) - (TCTemp.+ 460) I

Ref. Temp. + 460 x 100 Reference Point Reference

Temperature 

### f"trl Thermocouple

Temperature fotrt Absolute

Differencea (o/"\

1 2 t 4 5 6 7 0

32 100 212 300 400 500 1

31 100 212 300 399 499 o.2

0.2 0.0 0.0 0.0 0.1 0.1

### THERMOCOUPLE 

### CALIBRATION DATA

Meter Box

## lD: 4
Meter BoxThermocouple: fmpinger Exit iXAD Condenser Reference Calibrator 

## lD: 875228 Reference Calibrator Model: HH71 CAL-K Reference Calibrator 

## Type: K 0f/16i09



## Average 

# I f
Pass/Fail 

## ? I Pass

(a) Absolute Difference must be s 2"F.

Calibration Performed By:

QA/OC Check Performed By: Reference Point Reference

Temperature ¿OFì Thermocouple

Temperature 

### I'Fì Absolute

Dlfferencea I'F'l

1 2 3 4 5 6 7 

## I I 0

10 20 32 40 50 60 68 80 0

10 21 32 41 50 61 67 78 0

0
1 0
1 0
1 1 2TH 

### ERMOCOUPLE 

### CALIBRATION DATA

Meter Box

## lD: 4 Meter Box Thermocouple: Meter lnlet
Reference Calibrator

## lD: 875228 Reference Calibrator Model: HH71 CAL-K Reference Calibrator

## Type: K

(a) Absolute Difference must be s5.4'F.

Calibration Performed By:

QA/QC Check Performed By: 

## Average 

## I I Pass/Fail

## ? I Pass



## Date: 01/16/09

Reference Poínt Reference

Temperature lotrì Thèrmocouple

Temperature 1"Fì Absolute

Difference' fotrì

1 2 3 4 5 6 7 

## I I 1g 11 0

32 50 68 80 90 100 110 120 

### r30 140 2

32 51 68 7g 89 100 110 120 132 140 2

0
1 0
1 1 0 0 0 2 0

### THERMOCOUPLE CALIBRATIONÐATA

Meter Box

## lD: 4 Meter Box Thermocouple: Meter Outlet Reference Calibrator

## fD: 875228 Reference Galibrator Model: HH71CAL-K Reference Calibrator 

## Type: K

(a) Absolute Difference must be <5.4'F.

Calibration Performed By:

AA/QC Check PeÍormed By: 

## Average 

## I f Pass/Fail

## ? I Pass 01hat09

Reference Point Reference

Temperature 

### t"Fl Thermocouple

Temperature 

### f'Fl Absolute

Differencea ¿OFì

1 z 3 4 5 6 7 

## I o 10 11 0

32 50 68 80 90 100 '110 120 130 140 1

33 50 69 80 90 100 110 121 130 143 1 1 0 'l 0 0 0 0
1 0 3Page 

### I of 2 TheAir Compllancê Group, LLC

EPA Method 5 Meter Box Calibrlíon Pre-Test Or¡f¡ce Mêlhod



### MeterBox# 7 

### Ðate: 06/03/09 Bârometric 

### Pressur€: 28.980 (ln. Hg) Theoretical Critícal

### Vacuum: 

### 13.97 (in. Hg) Calibration Technicien: MSH

-- ORY GAS METER READ¡NGS

AH (in H2Ol 0.29 o.29 0.62 0.62 1.1 1.1 1.8 1.8 3.3 Time

lmlnì 5 5 5 5 5 b 5 5 5 5 Volume Totel fr1 1.606 'l.611 2.321 2.317 3.O47 3.D47 3.887 3_888 5.212 5.212

74.O 74.0 74.0 74.0 74.0 74.0 74.0 74.0 74.0 74.0 78.0

80.0 8r.0 t1.0 83.0 

### Volume Volume 

### lnltiâl F¡nâl 

### lfl') É:) 

### 477,721 479.327 

### 479.327 480.938 

### 480.938 483.259 

### 483.259 4t5.576 

### 485.576 488.623 

### 488.623 491.670 

### 491,670 495.557 

### 495.557 499.445 

### 439.445 504.657 

### 504.657 509.869 ldeg Fl (deq F) ldeo F) fdeo F) 75.0 74.0 76.0 75.0 lnitlal Temoerature 

### lnlet Oul¡et


### 76.0 75.O 

### 77.0 75.0 

### 78.0 76.0 

### 78.0 76.0 F¡nalTemo€rature



### lnlet Outlet

76.0 78.0 

### 78.O 81.0 79.0 

### 79.0 83,0 79.0 79.0 

### 77.4 75.0



### 78.0 76.0 

### 78.0 76.0 

### 78.0 76.0 

### 80.0 78.0 

### 81.0 78.0 

### 84.0 79.0

CRITICAL ORIFICE READINGS

AmÞ¡gnt Temo€ralure Averaoe Temperature 

### DGM DGM Ambient 

### Outlet Ovêiåll Temp (deo 

### R) ldeo

### R) fdeg R) 

### 534.5 535.0 534.0 

### 535.0 535.0 534.0 

### 535.5 536.5 534.0 

### 536.0 æ7.0 534.0 

### 536.0 537.0 534.0 

### 537.0 539.0 534.0 

### 538.0 539.3 534.0 

### 538-5 539.8 534.0 

### 539.0 540.5 534.0 

### 539.0 541.3 534.0 

### Orifìc€ Actual 

### Serial# K'Orifice Vacuum 

### lnumber) Coeflìcíent (in Ho) 

### Ks-40 0.240ô 24.0 

### KS-40 0,2406 24-O 

### KS-48 0.3497 22.0 

### KS-48 0.3437 22.0 

### KS-55 0.4591 20.0 

### KS-55 0.4591 20.0 

### KSS3 0.5898 18.0 

### KS-63 0.5898 18.0 

### KS-73 0.8057 r5.0 

### KS-73 0.S057 15-0 lnítial {deo Fl 74.0 74.0 74.0 74.O 74.0 74.O 74.O 74.0 74.0 74.0 74.0 74.0 74.0 74.0 74.0 74.0 74.0 74.O 74.0 74.O 

### Final Average ldeo

### Fì ldèt Fì

IMPORTANT;

, For valid test results, lhe Actual Vacuum should be at least 1to 2 in. Hg greater than the Theoreticâl Criticãl Vecuum shown above.Pagø?õÍ2 The Air Compllance Group, LLC

EPA Mêthod 5 Motêr Box Calibrat¡on Pre-Test OrÍfice Method



### MeterBox# 7 

### Dâte: 06i/03/09



### --- ÐRY GAS METER

### -.-. VOLUME VOLUME 

### CORR. CORR, 

### Vm(std) Vm(std) 

### É (liters) ^n.r.fi*¡Èñr*á REsuLTs Bâromehic 

### Pressure: 28.98

. (¡n. Hg) Theor€tical Cril¡cal

### Vecuum: 

### 13.67 {in. H9) celibrâfion

### Technic¡an: MSH

oRlFlCE

### ------ VOLUME VOLUME 

### CORR. NOMINAL 

### Vc(std) Vcr 

### lliters) É1 r-536 1.538 2.2'15 2.209 2.909 2.903 3.702 3.699 4.971 4.964

o.9424 0.9807 0.9899 0.9926 0.9897 0.s915 0.999'1 0.sgs8 '1.0r64 1.0178
0.9960 43.5

43.6 62.7 62.6 82.4 82.2 104.8 104.8 '140.8 140.6

{.01 -0.02 -0.01 0.00 -0.01 0.00 0.00 0-t)0 0.02 o.o2 0.00 VOLUME CORR. Vc(std) fs:t 1.509 1.509 2.193 2.193 2.879 2.879 3.698 3.698 5.052 5.052

1.7143 't.7127 1.7317 1.7301 1.7809 1.7776 1,7592 1.7576 1.7251 1.7251
1.7414 42.7

42.7 62.1 62.1 81.5 81.5 104.7 104.7 143.1 143,1

43.54 43.50 43.99 43.94 45.24 45.15 44.68 44.64 43.82 43.82
44.23 1.576

1.576 2.291 2.291 3.007 3.007 3-863 3.863 5.277 5.277



### --- DRY GAS IIIETER

### --. CALIBRATION FACTOR 'Y"

### Value Variation 

### (numbe¡ì lnumber'l I oRtFtcE 

### ----- CALIBRATION FACTOR %H@"

### Value Value Var¡at¡on l¡n

### H2O) (rrU

### H2O) lin H2O)'z

Average Average 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0-0 0.0

verage Y = AverageÂH@

## = 1.7114 

## PasslFail? Pass

Notes: I For Cal¡bralion Factor Y, lhê rålio of the reading of the cetlbrât¡on mêter to lho dry gâs mêtèr, acceptrabìe tolerance of individuâl values from the average ís ù 0,02. Var¡et¡ons shown t¡ave been rounded to nêârest 0.0'1.

2 Fo¡ Q¡ifice CalibratÍon Factor AH@, the or¡fice d¡fferential prcssure in inches of H20 that equates to 0.75 cfm of elr at 68 deg Fand 29.92 ¡nchqs of Hg, âcceptåbl€ tolerance of individual vâlues from thê av€ragê is

### t 0.2. Variations shown hâve been rûund€d lo nèárêst 0-1.

QA/QC Performed By 

### Däte: 06/09/09Pagø I of 2 The Alr Compllance Group, LLC

EPA Method 5 Metêf Box Cal¡bÌâi¡on Post-Test Orifi ce Method



### MeterBox# 7 

### Date: 612212ô09 Barometric 

### Pressure: 28.950 (in. Hg) Theoretícel Critícal

### Vacuum: 

### 13.66 (in. Hg) Calibrät¡on

### Technic¡ân: FPc

DRY GAS MEÍER READINGS

AH lln H2O) 

### t.l0 1.10 1.10 Volume lnitial iÊ1 227.884 233.831 239.985 Volume

Final 

# ftl
233.831 239.985 246.161 Voluñe

Tolal 

### Gl 5.947 6.1 54 6,176 Time lminì 10.0 10.0 10.0 lnitíal Temoerature 

### lnlet Ouüel Fínal.Jêmpqalure



### lnlet Outlet



### 83.0 90.0 85.0 (deo

### Fì fdeg

### F) ldeq

### Fl (deo F) 

### 82.O 81.0 85.0 82.O 

### 85.0 82.0 88.0 83.0 88.0

Orifice 

### Serial# K Orifice 

### lnumberì Cæffrcient 

### KV-55 0.4616 

### KV-55 0.¿t616 

### KV-55 0.¿f616 Actual Vacuum (in Ho) 20.0 20.o 20.o lnitial

fdeg Fl 80.0 80.0 80,0 CRITICAL ORIFICE READINGS

Ambient Te¡noqrAture Averâoê T€moerâturë 

### DGM DGM Ambienl 

### Outlet Overall Temp ldes 

### ßì ldeg 

### R) {deo Rl 

### 541.5 542.5 540.0 

### 542.5 544.5 5¿m.0 

### 544.0 546.5 540.0 

### Fínal Average ldeo 

### Fì ldeo Fì 

### 80.0 80.0 

### 80.0 80.0 

### 80.0 80.0

IMPORTANT; For valÍd lest results, the Actual Vacuum should be 1to 2 in. H9 greater thãn the Theorel¡câl Crit¡cål Vacuum shown âbove.Page2oÍ2 Thê A¡r Compl¡ânce Group, LLC

EPA Method 5 Meter Box Calíbrat¡on FostJest Or¡t¡ce Method

Meler Box

## # 7 

### Dât€: 06122109 Barom€trìc

## Prêssure: 28.95 (in. Hg)
Theoretioal Critical Vacr.rum: 

### 13.66 (in. l-lg) Câlibration

## Technioian: FPC

oRlFlcË 

### VOLUME VOLUME VOLUME 

## CORR. CORR. NOMINAL 

## Vc{std) Vc(std) Vcr 

## ffl ll¡ters) É1) 

## 5.751 162.3 6,0Ûl 

## 5.751 162.3 6.081 

## 5.751 162.9 6.081

ORIFICE CALIBRATION FACTOR "ÂH@"

### Value Value Variation lin

### H2Ol ¿mm

### H2Oì (in H2O) 

### 1.7652 44.U 0.004 

### 1.7620 44.7s 0.001 

### 1.7571 M.63 {.004 RESULTS



## - DRY GAS METER



## - VOLUME VOLUME 

## CORR. CORR, 

### Vm(std) Vm(std) 

## fft3) llirersl 

## 5.614 159.0 

## 5788 163.9 

## 5.787 163.S



### - DRYGAS METER

### _- CÀLIBRATION FACTOR 

### 'Y'Value Vâriât¡on 

### {number) (numberl 

### 1.02M 0.021 

### 0.9936 {.010 

### 0-ss37 {.010

Average Y1o"s¡ 1.0039 Average dH@ 

### 1p*¡ 1.7614 Factor Gamma

## (Y): 0,9960 Test Avg. Gamma 

## (Ytpo.t)): 1.0039 

## : 0.0079 of

## Y: 0.0498 

## <SYooiY? Yes
Note: The Variation [absolfe value of lhe Calibration Factor Gamma (Y) minus the Post Test Average Gamma (Y1ro"1¡)] must be less than or equal to 50/o of Callbratlon Fäctor Gamma (Y).

QA/QC Performsd Ey: Datel 6t23t200s

### THERMOCOUPLE 

### CALIBRATION DATA

Meter Box

## lD: 7 Meter BoxThermocouple: Stack Temp. Reference Calibrator

## lD: 875228 Reference Galibrator Model: HH7'l CAL-K Reference Calibrator 

## Type: K

a Difference, % (Based on degrees Rankin): Absolute Difference =

b Average Absolute Difference must be

### s 1.5%.

Calibration Performed By:

QA/AC Check Performed By: 

### Averageþ 

# I o.t Pass/Fail

## ? I Pass 01/07/os

Reference Point Reference

Temperature 1øtr1 Thermocouple

Temperãture loF) Absolute

Differenceã (o/^\

1 2 3 4 5 6 7 

## I I 10 11 0

32 100 212 300 400 500 600 700 800 s00 0

33 101 211 301 400 500 602 702 801 900 0.0

0.2 0.2 0.1 0.1 0.0 0.0 0.2 0.2 0.1 0.0

### THERMOCOU 

### PLE CALIBRATION DATA

Meter Box

## lD: 7
Meter Box Thermocouple: Probe Heat Reference Calibrator

## lD: 875228
Reference Calibrator Model: HHTlCAL-K
Reference Calibrator 

## Type: K

a Difference, o/o(Based on degrees Rankin): Absolute Difference =

bAverage Absolute Difference must be

### s 1.5o/o.

Calibration Performed By:
Q¡/OG Check Performed By: 01to7tog



### Averageb 

# I o.o Pass/Fail 

## ? f Pass

| (Ref. Temp.+ 460) - (TC Temp.+ 4691 ¡

Ref. Temp. + 460 x 100 Reference Point Reference

Temperature lotrl Thermocouple

Temperature lotrì Absolute

Differenceâ to/^\

1 2 ó 4 5 b 7 0

32 100 212 300 400 500 0

32 100 212 301 399 500 0.0

0.0 0.0 0.0 0,1 0.'t 0,0TH ERM 

### OCOUPLE 

### CALIBRATION DATA

Meter Box

## lD: 7 Meter Box Thermocouple: Filter Heat Reference Calibrator

## lD: 875228 Reference Calibrator Model: HH71CAL-K Reference Calibrator 

## Type: K

a Difference, o/o(Based on degrees Rankin): Absolute Difference =

bAverage Absolute Difference must be s 1.5o/o.

Calibration Performed By:

QA/OC Check Performed By: 01lo7l09



### Averageb 

# I o.z Pass/Fait

## ? I Pass

I (Ref. Temp.+ 460): (TCTemp.+ +00) |

Ref. TemP.

## +460 x 100 Reference Polnt Reference

Temperature fotr\ Thermocouple

Temperature /otr\ Absolute

Differencea (o/^\

1 2 3 4 5 6 7 0

32 100 212 300 400 500 1

101 213 300 399 4S8 0.2

0.4 0.2 0.1 0.0 0.1 o.2

### THERMOCOUPLE 

### CALIBRATION DATA

Meter Box

## lD: 7
Meter BoxThermocouple: lmpinger Exit/XAD Condenser Reference Cafibrator 

## lD: 875228 Reference Galibrator Model: HH71 CAL-K Reference Calibrator 

## Type: K 01107109



## Average 

## | 1 Pass/Fail

## ? I Pass

(a) Absolute Ðifference must be <2'F.

Calibration Pedormed By:

OA/QC Check Performed By: Reference Point Reference

Temperature 

### f"trì Thermocouple

Temperature 

### t"trl Absolute

Þifference¿ 

### I'Fì

1 2 3 4 5 6 7 

## I I 0

10 20 32 40 50 60 68 80 0



## I 20 33 40 51 60 67 79 0
1 0 1 0 1 0 

### I
1TH 

### ERMOCOU 

### PLE 

### CALIBRATION DATA

Meter Box

## lD: 7 Meter Box

### Thermocouple: Auxillary Reference Calibrator

## lD: 875228 Reference Calibrator Model: HH7'l CAL-K Reference Calibrator 

## Type: K

(a)Absolute Difference must be <

### 2'F.

Calibration Performed By:

OA/OC Check Performed By: 

## Average 

## | 0 Pass/Fail

## ? | Pass 01t07tog

Reference Point Reference

Temperature loFl Thermocouple

Temperature f"F) Absolute

Differencea 

### t'F)
'l 2 3 4 5 6 7 

## I o 10 11 0

32 100 212 300 400 500 600 700 800 900 1

32 100 211 300 400 500 601 700 800 900 1

0 0
1 0 0 0
1 0 0 0

### THERMOCOUPLE CALIB RATION 

### DATA

Meter Box

## lD: 7
Meter BoxThermocouple: Meter lnlet Reference Calibrator

## lD: 875228 Reference Calibrator Model: HH71 CAL-K Reference Calibrator

## Type: K

(a)Absolute Difference must be s5.4'F.

Calibralion Performed By:

QA/OC Check Performed By: 

## Average 

## | 1 Pass/Fail

## ? I Pass 01lo7l0g

Reference Point Reference

Temperature t"F't ïhermocouple

Temperature 

### l"F\ Absolute

Differencea /otr\

1 ¿ 3 4 5 6 7 

## I I 10 11 0

32 50 68 80 90 100 110 120 130 140 0

31 53 67 8't 90 101 110 119 130 14',1 0 1 3
1
1 0
1 0
1 0
1

### THERMOCOUPLE 

### CALIBRATION DATA

Meter Box

## lD: 7 Meter Box Thermocouple: Meter Outlet Reference Caliþrator

## lD: 875228 Reference Calibrator Model: HH71 CAL-K Reference Cal¡brator

## Type: K

(a)Absolute Difference must be <5.4"F.

Calibration Performed By:

QA/OC Check Performed By: 

## Average 

## I f
Pass/Fail 

## ? I Pass a1rc7tog

Reference Point Reference

Temperature I"Fì Thermocouple

Temperature lotrì Absolute

Differencea 

### I'Ft

1 2 3 4 5 6 7 

## I I 10 11 0

32 50 6B 80 90 100 110 120 130 140 0

31 5'1 67 81 90 101 109 120 131 140 0 1 1 1 1 0
1 1 0
1 0Page I of2 The Alr Compliânce Group, LLL

EPA Method 5 Meter Box Calibration Pre-Test Oriticê Mêthod

Meler 

### Box# 11 

### Dâtei 12.30.08 Bãromêtr¡c

## Prêssure: 29.190 (ln. Hg) Theoretical Criticâl Vacuum:___! 3.ZZ_ (in. Hg) Calibration

## Technician: MRW

DRY GAS METER REAOINGS

ÀH fín H2O) o.29 0.29 0.6 0.6 1.1 1.1 f.9 1.9 3.4 3.4 Tlme

lmÍn) 5 5 5 5 5 5 6 5 5 5 Volume

lnitlal 

### id) 22.646 24.O47 35.842 38.05'1 40.27õ 43.173 46.078 50.636 25.624 30.721 Volume

Final 6:) 24.087 25.624 38.051 40.276 43.1 73 46.078 50.636 54.418 30.721 35.842 Volume

Totâl fr:) 1.541 1.537 2.209 2.225 2.097 2.905 4.558 3.782 5.097 5.121 64.0

64.0 65.0 65.0 66_0 66.0 66.0 67.0 64.0 65.0 63.0

63.0 64.0 64.0 64.0 64.0 64.O 65.0 63.0 63.0 64.0 ô4.0 64.0 65.0 65.0 63.0 64.0 lnitial Temoerature 

### lnlet outlet (deo 

### FJ ldeo F) Final TernûeÉtu¡e



### lnlet Outlet lded

### R (deo Fì 64.0 64.0 65.0 66.0 68.0 66.0 67.0 67.0 64.0 6s.o 63.0

63.0 64.0

CRITICAL ORIFICE READINGS

Ambient TemoeÊâture Avêråoê Te mþe ratu r,e_. 

### DGM DGM Ambienl 

### Oullet Overall Temp ldes 

### Rì (deo

### R) ldeg R) 

### 523.0 523.5 524.0 

### 523.0 s23.s 524.0 

### 524.0 524.5 524.0 

### 524.0 524.8 524.0 

### 524.0 525.0 624.0 

### 524.0 525.0 524,0 

### 524.5 525.5 524.0 

### 525.0 526.0 524.0 

### 523.0 523.5 524.0 

### 523.5 524.3 524.0 Orificê 

### Serlal# K'Orifioe 

### lnumber) Coefficient 

### KV-40 0-2404 

### KV40 A.2404 

### KV-48 0.3504 

### KV-48 0.3504 

### KV-55 0.4616 

### KV-55 0,4616 

### KV-63 0.6012 

### KV-63 0.6012 

### KV-73 0.8227 

### KV-73 0.8227 Actual Vacuum (in Ho) 21.0 21.0 19.0 19.0 18.0 18.0 f6-0 16.0 15-0 15.0 lnitial

ldeo FÌ 

### 64.0 64.0 

### 64.0 64.0 

### 64.0 64.0 

### 64.0 64.0 

### 64.0 64.0 

### 64.0 64.0 

### 64.0 64.0 

### 64.0 64.0 

### 64.0 64.0 

### 64.0 64.0



### F¡nal Average ldeg 

### F) (dea F)

64.0 64.0 64.0 64.0 64.0 64.0 64.0 64.0 64.0 64.0

IMPORTANT: For velid test results, the Actual Vacuum should be at least I to 2 ¡n. Hg greater than th€ Theoretical Critical Vacuum shown above.Fagè 2 of 2 The Air Compl¡a'lcê Group, LLC

EPA Method 5 Meter Box Cålibration Pre-Test Odnce Mêthod

Melêr Bôx # 

### Date: 12.30.08 Ba¡ometric 

### Pressure: 29.19 (in. Hg) TheoretícãlCrítical 

### Vacuum: 

### 13.77 (in. Hg) Calibration

### fechnícian: ¡¿RW.

RE



### --- DRY GAS I/IETER


### ---- VOLUMÊ VOLUMÊ 

### CORR. GORR, 

### vfn(std) vm(std) 

### fO flirerc) 

### 1.517 43.0 

### '1.513 42.9 

### 2.172 61.5 

### 2,187 61.9 

### 2.849 80.7 

### 2.857 80.9 

### 4.488 127.1 

### 3.720 105.4 

### 5.056 143.2 

### 5.073 143.7



### .-- DRY GAS METER 

### --- cALtBRAT|ON TACTOR 

### "Y'Value Ver¡ation
f

### numberl (numberì r
1.01 05 1.0131 1.0286 1.0217 1.0330 1.030r 1.0250 1.0304 1.0374 f.0340 1,0264 oRtFtcE 

### ----- VOLUME VOLUME VOLUME 

### CORR. CORR. NOMINAL 

### Vc(std) Vc(std) Vcr 

### (fl:t ltirerst ffl

oRrFrcE

### -----. CALIBRATION FACTOR %H@"

### Value Value Variation (ín

### H2O) (rflm 

### l-l2o) ßnH2O't2 1.533 r.533 2.234 2.z34 2.943 2.943 4.600 3.833 5.245 5.245

1.7097 1.7ø97 1.66t 8 1.6618 1.7556 1.7556 1.7859 1.7842 1,7115 r.7099
1.7246 43.4

43.4 63.3 63.3 83.3 83.3 r30.3 108.6 148.8 148.6 1.560

1.580 2.274 2.274 2.995 2.995 4.681 3.901 5.338 5.338

Averege -0.02 -0.01 0.00 0.00 0.01 0.00 0.00 0.00 0.01 0.01 0.00 Average 43.43 43.43 42.21 42.21 44.59 44.59 45.36 46.32 43.47 43.43
43.80 0.0

0.0 -0.1 -0.1 0.0 0.0 0.1 0.1 0.0 0.0 0.0 

## f= 1.0264 

## AH@= 1.7246

Pass

Notes: I For CalÍbratjon Factor Y, lhe ratio of the reading of the catibrat¡on meter to lhe dry gas meter, acceptable tolgrânce of indlvldual values from the averagë ls

### t 0-02- Varialions shown have beèn rounded to n€arest 0-01

. 2 For Or¡fice Câlibrâtion Factor ^H@, the orifice differentlal pressure in inches of H20 that èquates to 0.75 cfm õf aìr at 68 deg F ând 29.92 inches of Hg, âcceptâbtê tolerâncê of individual vãtues fiom the average is È02. Variâtions shown have been rounded to nearest 0.1_

QA/QC Performed By: 

### Dat€: 'l2l31l08Page 1of2

Meter Bóx

### # 11 

### Date: 06/25109 The Air Compllance GrouF, LLC EPA Method 5 Met€rBox Callbration Post.Test Orlfice Method (Full Calibration)

DRYGAS METER READINGS Baromelríc 

### PressürÊ: 

### _?{989_ (h. HS) Theorelhal CriticalVacuum: 

### 13.61 (¡n. Hg) Câl¡brafioil 

### Techniciân: MSH

ÂH (ln H2Ol 027 0,27 0.58 0.58 1.1 1.',1 1.8 1.8 J,¿ 3.2 Time

fminì 5 5 5 5 5 5 5 5 F 5 Volume Total fr1 1.509 1.517 2.225 2.197 2.925 2.896 3.759 3 759 5.092 5.093 72.0 72.O 71.0

72.0 74.0 74.0 7s.0 75.0 T7-O 77.0 æ,0 79.0 68.0

69,0 70.0 70.0 71,0 71.0 72.0 72.0 72-O 72.0 77.0 79.0

70.0 70.0 70.0 70.0 70.0 70.0 

### Volums Vo¡ume 

### lnitial Final 

# rfl rfr1 

### 486.663 488j72 

### 488.172 489.689 

### 449.689 491.914 

### 451.914 494.1 11 

### 494.111 497.036 

### 497.036 499,932 

### 4S9.932 503.691 

### 503,691 s07.¿150 

### 507,450 512.542 

### 512.542 517.635 InÍtíal Temoerature 

### lnlet Outlet 

### fd€qf) Jdeg Fl 

### 70.0 ô8.0 

### 71.0 08.0 

### 72.A 6S.0 74

### t 70.0 

### 74.O 70.0 

### 75.0 71-O 

### 75.0 71.0 

### 77.0 72.0 F¡nel TempeElure



### lnlet Outlet {deo

### t} ldeo Fl

CRITICAL ORIFICE READINGS

Ambiênt Temoerature Alrerâûe Temoerature 

### ÐGM oGM ,qmbient 

### Outlet Overall TemP (dea

### Rì (deg

### Rl tdeo R) 528

### 0 s29.3 530.0 

### 528.5 530.0 530.0 

### 529.5 531.3 530.0 

### 530.0 532.0 530.0 

### 530.5 532.5 530.0 

### 531.0 s33-0 530.0 531

### 5 533.8 530 0 

### 532.0 534.5 530,0 

### 532.0 535.0 530.0 

### 532.0 535.5 530.0 

### Orifice Actual 

### Serial# K

### Orifice Vacuum {number) Coefficlent (ln Hq) 

### KS-40 0.2406 23.0 

### KS-it0 0.2406 23.0 

### KS-48 0.3497 22.0 

### KS-48 0.3457 22.0 

### KS-55 0.4591 20.0 

### KS-55 0.4591 20.0 

### KS-83 0.5898 19.0 

### KS-63 0.589S 19-0 

### KS-73 0.8057 16-0 

### KS-73 0.8057 16.0 lnfrial (deg Fl 70,0 70.0 70.0 70.0 70.0 70.o 70.0 70-o 70.0 70.0 

### Fìnal Averäge

lde¡

### Él ldeo Fì 

### 70_o 70.0 

### 70.0 70,0 

### 70.0 70 0 70

### 0 70.0 700 70.0 70.0 70.0 700 70,0

IMPORTAI'IT: For val¡d test Þsufts, the Actual Vacuum should be at least 1 to2 in. Hg greaterihan thé Tlleoret¡cal CritìcalVacuum sho'¡,/n above.Page 2 ot 2

Meter Box

### # 11 

### Date: 06/25109 The Air Complíance Group, LLC ÊPA Method 5 Meter Box Calíþrat¡on Post-Test Orifìce Method (Full Calîbralion)

RESULTS Barometríc 

### Pressure; 28.86 (ín, Hg)

Theoret¡cal CriticalVacuum: 

### 13.61 {fn- Hg) Calibration 

### Technician: MSH



### --.- oRtFfcE VOLUME VOLUME VOLUME 

### CORR. CORR. NOMINAL 

### Vc(std) Vc(std) Vcr 

### Gl flitenì (t'l 

### - DRY GAS METER



### - VOLUME VOLUME 

### CORR, CORR. 

### vm(std) Vm(std) 

### lfrt) lliters) 

### 1.453 41.1 1

### .458 41.3 

### 2.135 60.5 

### 2.105 59.6 

### 2.804 7S-4 

### 2.n4 78,6 

### 3.602 102.0 

### 3.597 101.9 

### 4.8S5 138.3 

### 4.881 138.2



### - DRY GÀS METER



### - GALIBRATTON EACTOR 'Y"

### Value Variation 

### lnumber) (number)1 ORIFICE CÂLIBRATION FACTOR 'ÂH@"

### Value Value Variaü'on lin

### H2O) lmm 

### H2Oì (in H2O)2 1.508 1.508 2.192 ) 40t 2 878 2,878 3,697 3.697 5.050 5.050

1.6r03 1.6088 1.ô328 L63f3 1.7933 1.7916 1.7747 1,7730 1 6891 1.6891 1.6994 42-7

42.7 62-1 6?.1 81.5 81.5 104.7 104.7 143.0 143.0

40.90 40.86 41.47 41 49 45.55 45.51 45.08 45.O4 4290 42,90
43.17 1.570

1.570 2.282 2.2ð2. 2.996 2.996 3.849 3.849 5.258 5.258

Averâge 1.0383

1-0342 1-0265 1 .0410 1.0262 1.0374 '1.0264 1.0278 1.0338 r.0346 f.0326 0.01

000 {_01 0.01 -0.01 0.00 {,01 0.00 0.00 0.00 0.00 Average 4,1 {.1 {.1 {.1 0,1 0.1 0.'1 0.f 0.0 0.0 0,0 ration Factor Gamma 

## (Y): 1.0264 Test Avg. Gamma

## (!ooo¡): f .0326 0.00ô2 of

## Y: 0.0513 s 5o/o of

## Y? yes
Note: The Variation [absolute value of the Cal¡brat¡on Fac,tor Gamma (Y) minus the Post Test Averâge Gamma (Y(e*tt)l must bê lessthan or equâl to 5% of Câl¡brâtion Factor Gâmma (Y),

QÂ,/QC Performed By:

### THERMOGOUPLE 

### CALIBRATION DATA

Meter Box

## lD: 11 Meter Box Thermocouple: Stack Temp. Reference Calibrator

## lD: 875228 Reference Calibrator Model: HH71 CAL-K Reference Calibrator

## Type: K

a Difference, % (Based on degrees Rankin): Absolute Difference =

bAverage Absolute Difference must be 31.5o/o.

Calibration Performed By:


### O¡/QC Check Performed By: 

### Averageb 

## I o.t Pass/Fail

## ? | Pass 01/09/09

Reference Point Reference

Temperature loFl Thermocouple

Temperature fotrì Absolute

Dìfferencea (o/^\

1 2 3 4 5 6 7 

## I I 10 11 0

32 100 212 300 400 500 600 700 800 900 2

32 100 213 300 401 500 601 700 802 s02 0.4

0,0 0.0 0.1 0-0 0.1 0.0 0.1 0.0 0.2 0.1

### THERMOCOUPLE CALÍ 

### BRATION DATA

Meter Box lD: 11 Meter BoxThermocouple: Probe Heat Reference Calibrator

## lD: 875228 Reference Calibrator Model: HH7'l CAL-K Reference Calibrator

## Type; K

a Difference, % (Based on degrees Rankin): Absolute Difference =

bAverage Absolute Difference must be < 1.5%-

Galtbration Peúormed By:

OA/QC Check Performed By: 

## Averaget 

# I o,t PasslFail

## ? I Pass 01/09/09

x 100 Reference Point Reference

Temperature 1"tr\ Thermocouple

Temperature f"F) Absolute

Ðifferencea lo/^\

1 2 3 4 5 6 7 0

32 100 212 300 400 500 0

32 102 212 300 402 900 0.0

0.0 0.4 0.0 0.0 0.2 0.0TH 

### ERMOCOUPLE 

### CALIBRATION DATA

Meter Box

## lD: 11 Meter Box Thermocouple: Filter Heat
Reference Calibrator

## lD: 875228
Reference Caliþrator Model: HH71 CAL-K
Reference Calibrator 

## Type: K

a Difference, % (Based on degrees Rankin): Absolute Difference =

bAverage Absolute Difference must be 11.5o/o.

Calibration Performed By:

QA/QC Check Performed By: 

### Averageb 

# I o.r Pass/Fail 

## ? I Pass 01/09/09

Referencê Polnt Reference

Temperature 

### l.trl Thermocouple

Temperature f"F) Absolute

Ðifferencea (o/"\

1 2 3 4 5 6 7 0

32 100 212 300 400 500 0

32 101 212 300 401 502 0.0

0.0 o.2 0.0 0.0 0.1 o.2

### THERMOCOUPLE 

### CALIBRATION DATA

Meter Box lD: 11 Meter BoxThermocouple: lmpinger Exìt /)(AD Condenser Reference Cafibrator 

## lD: 875228 Reference Calibrator Model: HH71 CAL-K
Reference Calibrator

## Type: K 

## Date: 01/09/09



## Average 

## I I Pass/Fail

## ? I Pass

(a) Absolute Difference must be <2"F.

Cafibration Performed By:

OA/OC Check Performed By: Reference Point Reference

ïemperature f"Fì Thermocouple

Temperature loFì Absolute

DÌfferencea loF\

1 2 â 4 5 6 7 

## I I 0

10 20 32 40 50 60 68 80 0

10 22 32 41 50 60 69 82 0

0 2 0
1 0 0
1 2TH 

### ERMOCOUPLE 

### GALIBRATION DATA

'11 01/09/09 Meter Box lD:
Meter Box

### Thermocouple: Auxillary Reference Calibrator

## lD: 875228 Reference Calibrator Model: HH71CAL-K
Reference Calibrator

## Type: K

(a) Absolute Difference must be s 2"F.

Calibration Performed By:

OA/OC Check Performed By: 

## Average 

## ¡ 1 Pass/Fall

## ? I Pass Reference Point Reference

Temperature f"Fì Thermocouple

Temperature 

### l"Ël Absolute

Differenceg 

### I'Fì

1 2 3 4 5 o 7 

## I o '10 11 0

32 100 212 300 400 500 600 700 800 900 0

32 100 214 302 401 500 600 702 800 902 0

0 0 2 2
1 0 0 2 0 2

### THERMOCOU PLE 

### CALIBRATION DATA



## , Meter Box lD: Meter Box Thermocouple: Reference Calibrator lD : Reference Calibrator Model: Reference Calibrator Type: 11 Meter lnlet 875228 HHTlCAL-K

K 01/09/09



## Average 

## I f
Pass/Fail 

## ? | Pass

(a) Absolute Difference must be < 5.4"F.

Calibration Performed By:

QA/QC Check Performed By: Reference Point Reference

Temperature /ôtr\ Thermocouple

Temperature 

### I'Fì Absolute

Differenceâ loF\

1 2 3 4
6 7 8 

## I 10 1'l 0

32 50 68 80 90 100 

### 1lo 't20 130 140 0

32 

### 5l 69 82 90 101 112 120 130 141 0

0 1 1 2 0
1 2 0 0
1TH 

### ERMOCOUPLË 

### CALIBRATION DATA

Meter Box

## lD; 11 Meter Box Thermocouple: Meter Outlet
Reference Calibrator

## lD: 875228 Reference Calibrator Model: HH71 CAL-K
Reference Calibrator 

## Type; K

(a)Absolute Difference must be s 5-4"F.

Calibration Performed By:

QA/QC Check Pe¡formed By: 

## Av€rage 

## | 1 Pass/Fail 

## ? | Pass



## Date: 01/09/09

Reference Point Reference

Temperature 

### I'Fì Thermocouple

Temperature 

### f'Fl Absolute

Differenceâ I"Fì

1 2 3 4 5 6 7 

## I I 10 11 0

32 50 68 80 s0 100 110 120 r30 140 0

.)¿ 50 69 81 92 101 110 120 131 142 0

0 0 1 ,| 2 1 0 0
1 2AGG 

### Field Nozzle Galibration Form NOZIe Set

## ID: SÍLIOA COATED SET K 

### Date: 

## 7/09/08 Tectrnician: JBS

where:
u Dr, z, g,=three different 

### ¡odes diameters, mm (in.); measure to the nearest 0.025 mm (0.00f in.) b^D = maximum difference between any two dÍameters, mm (in.),^D #(0.10 mm) 0.004 in.

c Dara = âv€râgêof Dl, Dz, and Ds, Nozzle ldenlification Number 

### No2e Diametef
^D,b mm (in.) Du*" Dr, Mm (in.) Dz



### mm(n) De,

mm (in.)
K1 o.117 0.117 o.117 0.000 o.117

t<2. 0.175 0.175 0.176 0.001 0.175 K3 o.240 0.240 o.240 0.000 0 240
K4 0.350 0.350 0.351 0.001 0.350 K5 0.370 0-370 0.370 .0 000 0 370 K6 0.427 0.427 0.427 0.000 Q.427 K7 0-489 0.489 0 490 0.001 0 48SAGG 

### Field Nozzle 

### Calibration Form

Noz|eSet 

### ID: SILICACOATED SETJ 

### Date: 

## 709/08 Technician: 

## JBS - -.

where: 

### " Dt.r,", =three different nozles diamelers, mrn (in-); measure to the nearest 0.025 mm (0.001 in.) b ÀD = maximum differmce between any two diameters, mm (in.), aD #(0.10 fim) 0.004 in,

o Dars = average of Dl, 

### þ, and D3. 

### Node ldentification Numbe¡ NoZe Diametef ÂD,b mm (in.) D"vg" D1, Mm (in.) Dz,

mm (in.) Dg,

mm (¡n.) JI 0.'116 0.1 16 0-116 0.000 0 116
J2 0.1 75 0.175 0.175 0.000 o.175 J3 0240 o.240 0.241 0.001 0.240
J4 0.301 0.301 0.300 0.001 0.30'1
J5 0.365 0.365 0.365 0.000 0,365
J6 o.427 o.427 o-427 0.000 o.427
J7 0 501 0-50'l 0-501 0.000 0.501

### ACG Field Nozzle 

### Calibration Form Nozzle Set 

## lD: Glass Nozzle Set B 

### Date:

## 4-6-09 Technidan: FPc

Nozzle ldentification Number Nozle Diameteru
^D,b mm (in.) Durgo Dr, mm (in.) D2,

mm (in.) 

## . D:,

mm (in.)

B1 0.156 0.156 0.1 56 0.000 0.156 

### .82 0-1s6 0.156 0.156 0.000 0.156 B3 0.185 0.1E5 0.185 0.000 0.'18s
B4 ,185 0.f85 0.185 0.000 0.185 B5 o.218 0.218 0.218 0.000 0.218 B6 0.225 0-226 o.225 0,000 0,225 87 0.250 0.250 0.250 0.000 o.250 B8 o.25A o.250 0.250 0.000 0.250 B9 0.250 0.252 0.253 0.000 0.250 Bt0 o.279 0.280 o.279 0.000 0.275
811 0 2B0 0.280 0.280 0.000 0.280 812 0-310 0.310 0.310 0.000 0.310 Bl3 0.310 0.310 0.310 0 000 0.310 814 0,375 0.375 0.374 0.000 0.375 Bl5 o.374 o.374 o.374 0.000 o.374 816 o.440 o.44t o.440 0.000 0-440 B'17 0.436 0.436 0 436 0.000 0.430 Bl8 0.s00 0.500 o.500 0.000 0.500 819 0.500 0 500 0.500 0.000 0.500 B.20 0-624 0.624 o.624 0.000 o.624 8.21 0.023 0.623 0.623 0.000 0.623 B.22 o.742 0.742 0.742 0 000 0.742 B.23 0.000
B.24 0 805 0.805 0.805 0.000 0.805
where:
u Dr,z, s,= three different noZes diameters, mm (in.); measure to the nearest 0.025 mm (0.001 in.) b^D = max¡mum differênce between any two diameters, mm (¡n.), ÁD #(0.10 mm) 0.004 Ìn. " D"* = average of D1, D2, and D¡.The Alr Gom¡llance Gro¡¡p, ll-G PrèTêst TheÍttroËoüpb Sy¡tsm CalÞrrúIon Fo¡m 

# *n (- v

# -tq FI}L Feftrmed Êt': ProüÊ StackTt lDl 

# PL-Þì-l F¡rgrHearcrrc

# w ún 

## I+

# ß*

# f

- UnúlícållD: t

## ,-{flt- \ lmphgorTclÞ. U

## ALf XADCTT*r¡ssTClE MeÞrlnletTtlD: MefrêrouËel ïC 

### lD
Meler Box tD: 

## h



# 7 

# 7

RÉreÍceTemo. 

## fÞf fteTe¡ÉTenro. tts) 

### melgræ¿"Ef 

# 1z 

# *?tr* 

# t f7 Ftbr HeelerTc 

# å 

# fr llfdndËr TE 

# {z û
XAÞ.GsnCEETæ 

# fz It¡later fnleûjfQ



# 17 

# t fz Meær_OrüetïC



# {t 

# r/

.Ä¡cæÉnc$giteria' ' r

### ilu* ùe*, amt*Èfrt hmpËrË[lre, or any o6er ænpe¡af.rre, wlüln tlË rarge epeclfied by he m4nufarUrer' ¿ Mu* meef É|efufouríru Þfl¡pe¿"dæ dfierencesc 

## ' FrobestackTÐ nrustbeuilhht2'FtfhelË{ereræbmqtr€üß



## . F¡nBr Èl€sur

## TC rmsl b9 rÚthin È ?"F

### trüe reaereræê lÉTnoelìúfie' rust be$flhin +2lF aft¡e refeænce tarTtper6ùJre
rrust bÊvrÐÉr r

## f F o{ üÊ feÉrË¡Ëê 

### ErrTçraffa
Met€r lnlet

## Tc ûust be ü{Ëdn

### t ãF of Ûte refere¡æe Emperatr¡rR MehrüfiÞt 

## TG mrHbEr4dtffi * 2"F(t'üËl€fêt€ncÉ Fnperaù¡t€. RderErEE 

### ltËmøïeEr 

### lû 

# ¿qlry

# f

lmdrgerTC ,fiT}TC

O¡¡CÉ-FerÞ¡m€d 

### nri 

# *,6'ìøThe .Air Go¡nplíance 

### Group, LUC Post-T€Ét

### Thsrmoaotple Slrstam 

### Gallbration Form 

## Date:

# 6

# -tl*oq Job lD: Pe¡brmed

# av FÎL corÉradf,to.: ReferenceTherrnometer

# tD: ¡1¡ ffr4 -T

Meter BÐ(

# lü 7 ProbesÞackrttD: 

# Pt*'À 

# l- | 'r.rrnbf,faãllD:

# l)- (dt ^

# L ÙletsldetTC 

# lÐ: -Å Mêfief OuÚeT TG

# ID: J

Rdererrce Tenra- foF!: Fost-TestT€mD.foFì Difiererrca {ts}2 

# d P¡obeStackT0



# 7T û0 

# 71 Itdeter

## lild TC 

# 7[ {' 

# 75 Mêfêr OuüeÈTC



# 7t tÐ ÁÊcsptance Crfiefla '. r Must åe et ambient ternpërät¡re, or any othertemper€tJre,wiúrín the raqge specified by üre marrufacfi¡ree 

# ' t

# {* meeilhefûllowirg lernpenah¡re 

### dfFsences;

FrDbe Ståci(

# TC rnust be wlthrï É

# fF of the refereflce tempemture.


### .rcmr 

### hbt

# TG must be withín

## t 2'F ofths reference EmperåiutÞ. Meter Oullet

# TC musl be rv{thÍn +

## fF ofthe reÞre$cê t€fiÌp€râUrÞ.



### GAfQGFerfomed By: 

# ¿f-

# tì'¿4

## ' theÄlrcfirpllsrce Gmup, 

### LLt fteTest Thermo*ortpb $:æ{em Calbrction ForÍr 

### DaÞË

# û-E-Õ4 PerþÍn€d

# W f{rL Pmbesrad(ÎGft

# Þ{,-IT - | 

## FtrÊrHÊ#rrero, 

# ft Ê[

# Ê ] Itrùil¡cdrD: P

# U'ftt-I fmp¡ncerTçt* V

# +4 )fiDGørdenÊef 

### lClD: 

# u€tsrrrsetrctÈ 

# 6 H€hrcluü€tT0mt:

## 7 lÍeûer Bõ¡{

## lB VI

RcferetrceTemn toFf FrÞ-TestTefi¡Þ. füFl Dlffe¡encsfF¡Ê 

# ç7 PrebeSffiTC



# f8 ]0 

# f7 FilârFIêd€rTC



# Ç¡ Òo 

# f7 funoù¡oerT0



# # t0
XAD CorìdenserIc 

# fz U*Þil¡r€ülç



# fe rû. 

# fz G{E{erûiletTC



## f4 

# f

.åoc+ptance

### tf,qîa t Mlct þ€

### d EnËhaú tÊ|np€rfrirB¡

### ü anyotlErtHilper*læ, wihin ltre rarge s@fied by lhq manuÞcû¡rcr. ¿tt¡!¡sl meet hefrlüflirq isflperätre ¿itrerenoes 

## ftab€StdTÞ mustùewlthln*?gofAe reErëræÞmperatw€.



### . F¡lÞ Fþðmr

## TC must be rr¿Illin r 2"F of

### tF rEf€r€EoB

### HnpsËüÉ 

## lû¡fiingerTC nrstbe wihin 

### *ZF of lfie refuerEe EmpËrãture.



## . )rAD

## TC m¡ed bêraflhin* 2'F of lhÊ r€fÊrsrcs ÞrpGratlÍe. 

### M€*ÉtrIfi|€tTG rftJstbe $,frfft È2T oftha 

### ¡*rsflÉ&np€rat¡reMÉ¡er Ouüet

## TC mtlstbe r¡viülin 

### r

### fFof lhe reftre¡rce tsmperature. RefêrËr'cên*¡rþil¡der 

# , "ttT f{} fThe 

### Air Gompliance Group, LLC Poct-Tast 

### Thermocouple System 

### Callbrd¡on 

### Fsm 

# Dare: {,-

# t\-oq Job lD: 

# PerMBy:
Reference Thermonreter lD:

Meter Box lD: Probe 

### SEckTC 

# lft UrnbEtcaj lD:



### eAfúlG Fbrfier¡rmd 

### Bl,: 

## Ð

# f^)ì- t Fp

# l- contråctru",t 

# Iï r+

# 5T tvt

# { 4

Meter 

### lnletTC lD:
Met€rOuüel TÊ ÍD:



### RdetnceTamo- 

# lFf Poat-Test Ternp. 

### l"F) Diffierence 

### l"FF 

# 7f 

# t 7r 

# t 7f 

# t

Accepúance CfiÊr¡a 

### t Must be at ambierit ternperatue. oFafly other temperdure, withín lhe range speclffed by lhe manufac{uer, 

### " Mu*t rneet 

### t¡e fdlor¿ing ternperature diffurences:



# . PrÐbe Stack

# TC iTlust bÊ t¡áth¡n

### * 2"F

## fffte reference ternpensturs. -Mefter 

### lnbt

# TG rnust be 

### wfüln

## t ZF of the refererroe temperaturc. 

### MeterOutleiTC 

# PtJ-Í0o- I

rflUst bË w¡thln

## t 2'F of tJre reference temperafure. 

# 6 

# 7

### ANA 

### LYZER CALI B

### RATION 

### DATA

TEST METHOD/AI'IALYTCAL METHOD Test lyletrcd -f\,lefitd 

### 3 I Arnlvlical $Jeümd - Meürod 3A TEST LOCAïOf'I: 

### AI'IALEER: TESTDATE: 'REPORT]NG UNITS

TEST METHOD/ANALYTCAL METHODTest Meúrcd - Method

### 3

## / Analvlical Method - 

### ifeftod 3A TEST 

### LocATloN: 

# S00 TEST

# DATE; 6/10å009 .TEST LOCATION: OO 

## AIIIALYZER: Carbon Bioxide 

### IES] DA¡E; WIU'4UUY ÐATE

### OFANALYSIS: 6i/1ol2oog 6i/1012009 REPORTING UNITS (PPn,c/oI: 

## %È 

## SPAHI 18.84



### [rloÞ: The allowable calibrat'ron error is 296 of span. DATË OF

### AÍIIALYSIS: 6/102009 

## SPAN: 21

RÀNGE GAS

CYLIN]TERIII Í¡.4S VALUË f96dvt A¡TflLI¿,È¡T(

RESPONSE 

### fj6dvl AE¡¡OLUIts

DIFFEREHCE fq¿rtul UAL

ERROR I%OFSPAI.J ZFRO Zero Nitroqen 0.00 Ð.00 0.00 0.00 !ltD 4013 12-O2 12-OO 

### g,t2 0.10 {IGH 4022 21 21.00 0.fÐ 0.00 Ð-¡-HER

ÎA¡ÚGE 

### €A5 CYLINDER ID 

### t¡A:t VALUË fY"dvl 

### ANALÏ¿tsI(

RESFONSE f'l6dvl AËõOLUTE

DIFFERENCE f9(dwl UAL

ERROR flìá

### flF spÂNl Zero Nitrocen 0.(Ð 0.00 0.00 0.ûo r4lD 4013 g.sß 9.S0 0-03 0.15 JIGH 4022 18.84 f8.8û 0-04 o.2'l THER

### ANALYZE R CALI B

### RATIONÐÁTA

TEST METHOD/AMLYTICAL |!¡ETHOD Test ltdehod - Méftod

## g/ Analyt¡cal Metrrod - Method 3A 

### TESTIO0ATION:

# S00

.

# TESTDATE; d1lrzws 

# AÍTJALIZER: DATE 

### õF

# A_¡\IALI6IS;-ffi_ REPORTING UNITS 

### (ppm,%): 7o

# dv SpAtrl; 21

TËST METHODiANALYTICAL MET||ODTestMethod - Method

### 3 /,.f{Fly!!çpll\¡lethocf - MethodSA 

### TESTiLocATtoN: 

# soo Æ; 6t11¡2oog .ANALYZER REPORTING UNITS 1ppm,%); DATE 

### OFANALì€I$: 6/1112009 

## SPAITI: 18.M RANGE GÂS

CYLINI'ER ID g iìt VALUE f%dvt A¡I¡AI-YZEñ

RESPONSE {+Adrrt .A$!'IJLUTts

DIËFERENCE 

### l%dvl 

### çAL

ERROR 196

### 0FSPA¡rf ZERO Zero Nilrooen 0.o0 0.00 0.00 0.00 l,llD 4013 12-O2 12.00 0.02 

### 0.lo .IIGH 4Æ22 21 21.OO 0.00 0.00 )THER

ìANGÊ GAS CYLINDER ID gArË VALUE 

### l%dvl AÍI}aLT¿EK

RESPONSE f9ddvl AT'ÙULU I E

DIFFERENCE 

### ftádvì 

### çAL

€RROR 

### f%oF sPAlrì ZERO Zeru Nitroqen 0.00 0.00 0 fto 0-o0 l/llD 4013 9.S3 9_SO 0,03 0.15 

### IIGH 4022 14.81 18_90 

### 006 0.32 

### ]THER

Note: Thtj allowable calibration enor 

### is2% of spsn.

# Airgas 

# (o tz

A¡rgâs Sp€c¡ätfty Gãses 1272? S, Wenlruof h Avsnuc Chlcago, lL 60620 1-77$78S3ûm l¡\Xtl-173-785-1928 u,rw.alrgas-corn 

# Grade 

# of 

# Product: BpA 

# protocol

Reference 

### Numben 5+12412A569{, 

## CylinderVolume: 151

### Cu.Ft Cylinder 

## Pressure: 2015 

## pslc Valve

# Outlet: 590 

### Expfratíon

## Date: AprO9,2012 Part

# Numbec Ë03N|7SE15A1066 

## CylinderNumber: XCOO2772B 

# Laboratory: ASG - Chicago -

## lI Analysis

# Date: Apr09, 2009

Triad Data Available Uþon Rqguest

Pagø 1ol 54-121173569€

# fffi

DocNumber 00000009051

Caslo mer &' O¡de r Inþrnulìon : THË AIR COMPTIANQE GROUP PraxnÍr 5700 Sou thAlameda Streer I"osÂngeles, CA 90058 Teþhone: (323) 5812154

Prøøir Order Nu¡nber: 07641667.oQ Custorñer P.O. Number: 02126599 Cuslomer ReJerence Nanbì¡: WA876

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Rofsrencs St4dard Typo: Gllls Rêr. Std. Cyfind€r# ¡ S4116¡S Ref. Sld,Conc.: 21.02o/r Raf. Sld. Tra;óâblø to SRM #: 26594 ' SRM sample #: 7l-t7-8

SRM Cy'inter# : CW m6-/34 $eændAndysl3 D¿tâ: ' Dale: Z:oR:OC:o-Gonc: R:OZt0CrOConci Z0C:0RroConc: UOil: "A VleæTest^ssay: .,a

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, grisirlg qll of the b at the sotsdiscr€lio

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## -'""*f'^"'"''"'. f 

# L/ùï

t¡ltl Dsle: PFiNumhü: NlCD'1904E+S IatNunht; t09828f03 Ctthìdôt gtilc&.Outlcl: Ag 59Q Cllhdcì PnEtre &Yott¡il.t 2ü10 P3l f40 cuft Expiration Date: Cylinder Numbe¡: 10t1612011 sA 14077 Analytlcal Uncertainty: 

## 18.14 % 21

## ' % Balance CARBON DIOXIDE 

# oxycEt'¡ .; NITROGEN 

## xl% t1 o/o

NOx ppm 

### = l,l/A NOX Vålue6 foÌ Rêfërence Only
I Cc¡rifcarior 

### InÍormztion: Cefu'frcrltÍøn Ðate: 1Ô115Ì2OOB 7sø¡?; 36 Monlhs Expintion Datè: 1O11512O11 'This cylinderwas certifled accoiding to the 1997 EPATracaab¡lity Proiþcol, Document#EPA€00/R-97/121, uslng Procedure G1 .Do Not Use th'ls Standard if Pressure i€less than 150

## PSIG Í

# Appendlx G 

# Facility Data

# Averaqe Data Plant Type: Roll

SoufrÞ PårElrËEr



## . íÌrrq flltaldû9 0€S4 

### È.à tsr,gôa,sæþ' 'sas*@ loitÆ 2.q

1¡lSrl2tl,8fiL0 oÊJtaÐs 08110 2ß43 8.1 148,0¡gOt1.0 4.gl



### 100Ét +Ð1

0qfl0/0â

### &2 28.a3 d.r¡ 1i4a2 4.S1 0Ell0¡09 

### 08¡e1 6.ú 5.s 150,0¡10.350.0 537.0û 1t43t 2æ, 06fi0¡!s 

### û¡¡2É ?8.83 s.7 14t,736,æ5.û S3?¡0 tûtõg 2.V. 

## ruär 2æ



### tùtrE 262

oÊf1e& 0*s9 

## '" at¡s 

## ---'- 

## -- - 'ãã--'----'r¿c¡s,oôì-,ii'--'''- 3Sû 

### ffiloiGt 

### 08:07 2$¡3 0.1 t,t9,1Éno.O l,t9.1r1n0.0 Flroiçl od:u/ zs.Et .1 

## ffiffi--oe¡s --zo¡s**-***-*'-*ãË

oillum fE.2B 28.83 

## E.i råb¡¿zû,'eÙ{r -

## ""' '

## s6Ë,o0" .twiþ 2.W 

## m,iûiir-*'-0e?e------zû.s3- *-"s.1.-*^---î{ä;îË{så,0:D---:- 

## *-*'CFø --------"*i-û{4¡- z-.sz'-'-

.oq¡fü0s

## fffro 26ür s.g 149,8æ,212.0 5ft8l)0 1Ð.f,33 2.52 Ítôfl0/üì æ32 26.83 6.7 l4E4S.l !c.0 *lÌ-'t f03.8{ "'2 08/10,€t

### 08;33 &.Ê 

### 6.û 150.5fl36¿0 t36.00



## -- slil.oi¡

### -' -

## - " 'roiia'-'--' 3-fit 

### -' ' 

## 'sriiro 'ioc.r/ " +eo

0€¡r0ffi

### ql50 26,&¡ 

### ã.1 t¡19,63t.062.0 filEÉO 104.4.8 tJ8

r-96 Rêport Pedod: 0EiI10f20Og 08:04 Thrcugh ftûfi@oOg 1ù.48

Fme Online Cr¡Þflþ:

### f r¡{nute(si

F = UnÌt 

### Offllne |= 

### lnvalid E= Erceedance ]fl = 

### lllaintenance C =

# Calibration S=$ubstltuted T = Out Of

## Gonlrol 

## *
= Suspec-t Reporl Generded: 06/10/@ 1 152 Report Version 2.3. Ity29 1st8

# Averaoe Data



# - TyPer Roll Report Period: 06/10/2009 08:04 Through 06/10/2000 10:48

TimoOnlhe Critería: 

### I núnute(s) Sou¡cè
Fìarãrnêt€r {UniU 00110¡W 08ú,r 06110¡096-{5 +.Àa owroJu

## 08ff z?2 

### ffi

### Lrue---oa,-õi---**'îf 

## '^- 06í0i00 

### o8i6 3/5 0410rû9 

### 0ÈÐ0 3,45 os,iq,ûs- 'ail'lb' 

### " ' "'- r+ç 06flfHxl oE¡l{llrp

### õåiÌffiñ'-îr{lgfËtfûÆ€üf!:1¡f 3.45 tir¡í¡rfls'-

## Glg**-*'--* -i'{5- -' --. orriooó -iiääF'"- 

### '--

## -'- ú,ø {lc¡lûlxl 

### 0817 3..15

### Éioß*--ìstist!6ffflfitÐ 0a:lÐ 3.rlç äi¡äiffi e

## =ffi --- -- - -sÆ--

## -- 00riõÉö

### --æä-*--"---- 3.i5-

## --'' öüìio,!s 

## iriizt " als 0¡iì0,tå" 

### "0il,23-------¡.-iÉ---- iËirî,td* 

### Eäi" 

## ""-

## =--f

-- öarcme--os-¡s* 

## ---ù:¡i-- iÈr'dÅÉ- -ori26- 

### - --' -"--255""-' 06frsÐs oa27 ûü¡1tl@ 0Ê;28 2.7ß 2.2ß {ts¡lürw 

## 08:29 Zæ o{üi-qtii"iÈåái 

### "

### --"-- '"-zä""-'"' t'siõÊñ-' -æ::a- - -

### ------*'¿iÉi..-- " oÈ¡roms 

## ær# -' '- " àÆft¡l-o4€-

## - ñäi*--**-'- ?:iÏ¡-*-' o-sr1'dñË-*õilrË-------*z-j¡s*-"* oo¡ä¡ns- --m*:ts--*"*---' 

### "-es



## -- oefcüúä-'-dffi7_-

## - -"'äili*-' öÉfromö

## -"0ûráç- 'ilss 06r'rúts' oö:iË- 

### -'-"''-'*'ädË---" O6/lût09

## 0&r4¡t 2t5 

### dil*õñö--õõ¡î--'-- 

## - -æ' *-- ffi

### -o¡ug-ogúf2---*'*¿Ë---' b¡Èiðloe"'t'sl*t*-' 

### -" ----'1.âf-- 

## -' bê,iioñö'- ¡äl.iT"- "" -"'"" 

### ".ãr¡Ë
' 06rlsDå

## oo'i5 '-" -- ""ä.dd

## - - õqi'diùË":õe-:¡s ----

## -*-" -frÉ --*

- 

### ffirïfr-- 

## Elz------25Ë-*- óifüt/{ir -*oË,4s

## - --2,Æ---- (E11û09 lÌû:,+ll Gfftom 0850 2_M 1J0

F = Unlt Off,ine |= 

### lnvalid E = Exceedance M = Itlaintenance C = 

### Galibrafion T = Out Of 

### Control

'ReFort Version 2,3. l02s S =

### Substituted



## *
=

### Suepect Raporl Geierated; Ofl 10109 1 I :52 

### 2ú8Pl¿nt:
RcportPerùf: 0€U1tr2fÐS0ä;O4 Thraush 0tr10Æ009 10:49 Soulw Pârflneter (UfiÛ 0910r[9 0ry5{ 0Ê/10iûs q5¿ 149,?57810.û



### 535¡0 tf¡4.9s 4.t€ 

### rrfions M2È

## ' '-

## ¿äb 5.8 -'flS,ZdOþsr.o $ari.ft0 'ior.e+ 4ã 

## õfi1¡rffi--6ä- ----

## firìæsîoão --

## -_--ìô1-3T --4.üs-..-- ûgtøfro

## üsr rEEs '

. '5.9 fiti.izsn-¡ o6riñs- 00ä2- 

## ---- 

## --2Àæ -.ií.é--

## -- 'rdr-e¿jæ.0 

### 137,00 ro{Æt {,ç5 

### 517.ffi ro*-z8 ¿6s 06riû¡ro-oæ¡- 

### %&1---T:E---:¿s,Ëio,9g7:õ-.--"_,**.ÉFã¡0:.----*---ì0rãi---.*

74.Ë{.559.St



### F=

# unltoffllne E =

## Excæedance c=

# Galibration s = 

### subslituted 

# l=lnvalid M=llainüenance T=OutOf 

## Gontrol * =Suspeçt RESorl Gêneråled: 06/1 0i0ü I 1rõ2 Report V€rsbn 2-3,1029 3of8TimeOnline C¡Íbria: 'l minub(s) Sow¡e PåâfleIET 

### (unï æ1lf¡Æ9 08:56 o8fl0trxl

## 0€:5? r-èd 06flqû9

### 0858 r.69 

## itroffi-¡Es 

## - -.--.'i.se ffi

### Ìffi--tuffi 

## *----*-- -2:¿f 

### "-.- iËtidrds--dgol- 

## -- ---"-- 

### z¡li-"' ai¡tÈre- 

## -ì¡r-rú- äilf

## '-"- 'õwrq,ug

## dûi " '-' 2-gi os¡r-ofl€_--os-fr¿-

### --' 

## - -?T4"-"' ôsnoË- -ffi

## É**-**-U e4--

## "- õiiõ/É- -'0rtr7' "--

## ------ïii"'-" '" 

### itflons" os'úd

## - þ,ô,i" " ' flurnruo 

### diis

## -- -' " äi+ 

### {E¡l{lË

## 0t:10 2,9 

### ffiio¡!ã'-#nfl 

## --"--äil--'' <Ërió;tË* "osï'ã-*- 

### ------?"gi- 

## - -

## - öåtr-o¡od- 

### æjì3-- -

### -.-'

## -'t.u-'--- ürlbÆa

## 09:14 zx' iE 

### iõ;ffi--iËi'äí* 

### -''- 

## " "-*z-.i+= ----- ¿ËfitirÉrÈ* -dÞìtiÉ - --

### --- 

### -- --¡.os-- 

### ir{ififfi-- ffi17

## - '---ãÃ-"--- düiäöö--ßtif- -ï:tË- ^-' iiåno,rÈ-'-Ë!È 

## --- *-b]ob 

### -"^ ,fríro¡w 

### oszd''"' 

## """' äûi '- 06fl0¡ûÐ {B:e1 3.É 

## ' d¡t-diDs -0sr2s---- - --- -

### i;ú-.' -- 

### *



## . ifrfr'ùõ- Edì"*- --" '-"".5.05*" ''- 

### ii¡iim'äð¿ri--- -.

### -

## -' ---üäå'*--'" 

## ' €6/r0¡0s 0s¿É'

## ' 'irti tã/'loot 

### lE:fl 3'3¿ 

## õEFffi|-æra---- 

## - brä õefloñÉ-"-rË*e" 

## ' " "à'i:i oo1-orw---ö,aû 

## - "ïiâ' 

## -' " 

### ixnom -ootsi

## ---- " ' 

### i.sz-" b€úr*öüGf-iii)ß2-

## -- ---__ -332- -

### - 

### ' 06¡1OtG 

### 0+33 3þ Ot¡lorlg--€-S4. oç¡idiffi-

### -E----------ã42 --'' odidfrd'' 

### iÉÉs-------- -3-si- 

## - - oû/ltyflg

### 0ftt37 $.94 o6¡lqfiÞ 

### ül:tt g-S2 

## ffifu¡_0sF-----_H"-.- ffiffi- oå#-- * 

### --'--sá¿---- öiiäüt's"- &:{ï

## - -- ------sE2- 

### -'.-- iË¡íäiË tfü:¿á

### _.

## - äÞÊ 

## " 00tf0ro0

### 0tf3 ¿7å 

### ffionÐ osá4-_:----' 

## :--iiË-*--



## . =

### õilro/us---osE---*-"- 

## zla -- üfifræ lr9:/Íl z7a 

### æ¡-næ"--riË,ct- 'ã.7ä----

F =

## UniÊOfñine E= Exceedance I

### * lnvalid !tr= 

### lilaintenance 

# t ç Calibration T = 

### OuÍ Of 

### Gonlrol ReportVeGi¡n 2.3.1æS S = 

### Subsfituted



## * =

### $uspeçt REport GefleËted: otr1trGg I l:52 4dtEType: Roll Report trerbd: 06/f0X200S 08S4 Thror¡gù 06tlttl2fXlÉt 10:48 Soüroê Paramel6r (t}tt) qFftÛÐA 08;,1{l

1464z,r,019,Í 5It7.00 

## - -ioÉ.åb

## -' 3.fr 0c{1{r0fl 

### .10;3€ 36¡a nS t.t8,6s4,3æ.0 5$taoo --------¡õíiiT 3.27 urirû/Ðr 

### ro¡f atr.æ - --b.i:'- ----fipo{,ff¿:0* {¡EflOrs4 

### r0r38 æp 6.0 1471Ht,923_0 n+¡o roels 327 oolro¡ue 

### 10rs, 2ÊJÊ -s.b - -l+f3là,*rõ-¡=-**"- 

### -----åtäq0* - 

### ----' to¿.a7-

### -- --- '"'izl----
F=

# UnÍlOff,lne E= E¡rêeedance 

## G=Galibratíon S=Substituted f = 

### lnvalid 

### M= 

## lllaintenance T= Out Of

## Gontrol * =Suspect Report Ver*ion 2.3.10ãl ffi/fofilg 18 ?6.É2 5.ll¡C 149.1tr-2'ts 0 -s ffi TtattL ¿Ð 1ü4.44 4.9¿ E 4-9, otlc/ûÐ 

### l0:3r 26.g¿ 3_2rC 14S,879.€10¡ 'Èr4É0 rD,iÉi 

### ' 4.er ii'oltons-- toi-¿rs''

## - --äó.sr-' 

### -'- o€/tÀrûà'

## 'fä¿d '

## ' ib.oz " ds2

iEfi0/o,e

## ros+ 2ß-8¿ slrÉ ì1d,üsi¡¡n.o ¡s7.io 

## - "*-- ¡üiit 4g 06flûüS 

### lo:s5 â82 e,1

Report GeE¡e¡aÈd;Oflf ûÆ9 11:52 5 ofB

# Averaqe Data



# - Type: Roll Report Pedod: 0il10t2009 08:ll4 Throqgh 06110Æ0ffi 10:48

Time Online GrfÞría: 

### I minub{s) Êource Paramelsr (rJfitl 

### trttûltg 0S:48 rÈirixie'

## æ¡s L?8 'õÅoob-öieso 

## ----^ -'--ääi:*' - - 

## iËI¿tu--_ffiî- äñ-*'-" 'ü¡rons Gl5? 2.m õiilrïËE.-äË16.- "-'

### *' "*'å:åi" 

### -" ffiätirË-.iiÊs4----' -

### * -'

### *'ãÉï'' óàriiirË'"^ræ"-ss 

## ' " z.¡r 

## ffiã' -ors6- 

### -

## --''*äï-*--otflìili¡ffi-*ïbËffio,ss-- 

## É-iÐ 

## -----ãî--- á6riïiË- 

## @-rse--- ""¡ii" "." irûr¡'qp{- 'io'dd'

## *--'-'- " ¿åi

## "
' ä{li'imö'"''ìooi- 

## "- ¿31 i¡ô¡1-0ðe-tõõä-'---**----{åî----- õffiï'ffi-

## -ros-***.ã5i- -- 

## - Éiìffià- -"ìbit{--- - -_--- ---tur 

### ----- iwid@--i{ir}Ë--'*"- "î=àlat

## -
- 

### BlGtg 10s6 231 ffio,w*--fo-sr- 

### - ---_ 

### - -t.ãf - -_

## - ffi o,m

### *io:ffi*--_-:'-'

-- -2.fl -' "-' " iffi

## îõÈà--rose*--^""f

## ñ*'" f¡8¡t0/lt9 

### '10:lo ¿ì2 ôå.r*äol*-ïõ:lï

## - ãn--- ffiñalrIE 1011L 2.72 ø-r

## oó*-iiltl--*-* 

## - - ^ã.r2

## -* - 

### Ftæ--ï*øa--'' 

### - -

### - - -- -Tt

## { -* ffi

### itu--Ttf 

## ã'----*'"- ärå"'-^ 

## õâ7õ¡d'*'io11d-- 

## 'i:n"-' ijaä'oäö---

## ro:t¡ 2.t2 

## " wrdnie--io:r-6 z.rz i¡err*o¡¡5--ìGîd 

## - -'- -

## -* -- r:ß* --- " 

## tffifu-lfro_".--.-^-d.¡3--."-

.

## iiäi-cüûil-t-qä - -¡.+s'--' o6r1-o{iã-- ibã-.'' 

### -*' 

### -* -.' -¡.i¡¡

## - -- *firäb-

## ìo:r iÆ 

## öóñ'ffi--rcå-* --i45--'*" 

## o¡r-íffi-ïEË---*' - -*ù¿5

## -'- oerlofft-

## r-i,:2s- --T.æ- "" 06/r'r0fl!l 1Ðin 3..15 oûtroGl ]D% 3.45 oÊJfûfiÍ¡ 10ø 3.45 

## Ìä¡rïF=æ----*** *"[4f --. -- {hfr$û9 lf}.91 3.{,5 

### GE-onË-ï+.ú-------¡f-¡t--* oîtiõttt' 

### ìöäi:-- 

## ----- ¡Æ -

## - äb¡io,ts 

## -ì'o*¡ t.u 

### fl'li'äiE 

## lo¡s e63 

### ffi'gfl{-iE-r€- fr

### nffi *--tolF-** 

## -*-l -ã.ö 

### *--



### - e-ofia'"'irË¡s- 

## -_ ãfu ' 

### ffi*p_^-'idä-"-' ""*'*--¿-.Ég- 

### -*-'

F = Unlt 

### Offline |= 

### lnvalid E = Exceedance



### lìl = Maintenance C =

### telibrstion T =

### Out Of 

### Gontrcl S = 

### Substituted



## * =Suspect R€pod Genefãled 06/10r{F 1l:5¿ RêÞort Vêr8ion 2,3.1 û29 6of8Plânt Type: Roll Report Peniod: OWf 0/2009 08;0,f Thruugh 06fl0/2009 10:48



## 538_0{t r07ss t21

ÀvGrA€ Mn¡¡r¡n lIaÉrun S|¡f,ffi*on hdl'}d8d Pål¡ Poîflls ToÌst ûufiÞ€rd DdaPrñ¡s 2Ê.€3 2G-æ 2t¡4 4,f205t
165
165 148,023,1.r3,2 l,fs,?88É87 o 153,Sq,Sff"0 17,114ñÈ,p?2.o 3.66 1J8 192 €07,8€ t€5 1i5 165 16ã 115 l€5 fi.0 5,5 6.8 9?t.t
158 165 {É6.90 53300 535.00 86,4241t0 r06
165



### S= Substifuted 

## * =

### Suspect lÐs.3s rß.1,6 10&¡ß 1730Ð.€€

F = 

### UnitOfrine I= 

### lnvalid 

### Ë= 

## ÉrcesdancÊ G

### =Calibr¿tion

l,l = 

## Mainlenance T =

### &¡t Of 

### Gontrol Report GeflãEted: lËlloir}g 11:52 Report Version 2.3,1 Oqg 7oil

## IRÉport PÊriod: 06llû/2008 08:04 Tfrough 0ü10/2009 {0:48 

### ïme On[ne 

### triþria: I nirnJl€{s} Source P#sr¿ter (untl oôtlfyût 

## 10.,{0 zES iryroiçÈ

## 'iti+i'-' z* ' 0gltrt0Ð

## 10-li! ¿€0 &r=-rane*- iö'i¡-- -"

## "' "* ---¿-ei' 

### - "- 

### õ/rdäË*-roro¡----------¿E--- oûtr-01É*-iõ6 ---- ":-*"-23õ* * '

### *- trüi¡,rsÊ -lAÆ- 

### -*--" " 

### "* õnî"- -. iE r-äloe 

### 1ù.47 soì iffiome_-r e¡[- - -"

### --*'-îtiì--" **'

- Avðrä96 lünhfl¡r ibil¡q 8ürTrüå0on lncl¡*dt¡# Potlls Tdd ftmb#ol Dåi¡ Fotrü

F = Unit OfHine 

### l= lnvalid 2,ø1 1-æ 3116 ¡6ç,4Ð
lGS lû5

R+e¡l G€fiêr'ål€dr 0910/09 f f r52 E = Exceedance 

## ll = Maintenance G = Galibration



# ï =

### Oul Of 

### Gonlrol RepodVenirn 2-9,1V¿9 S = 

### Ssbstituted



## * = 

### Suspect I of8

# Ave Plant Type: Roll

So{rtcé Parrneter (Unlt) 

### tå¡lûæ 'f5i45

tr/r0¡ç9 

### 1Éúg 26.7s 

### 6,1 t¿g,szb,isoo 

### '' ss¡-@ 1ffi.36 s42

0€Jtofi,g 1625 ?Eï9 06f1û/u8 

### 16fr ã.79 

## - äiiC-- ibiise^o{id.ö *-*'liä,i:oû 

## - ' "iris.sa 

## ò'.+Ic i+r,àzs.ess.d ' sûr¡o ios.+¡ ï,d4 '
+.e3

4¡3 

### F= unit

# offlfne E =

## Exceedance c =

# callbration s= subsütuted I =

# lnvalid ltl =

## Maintenance T = Out Of

## Control * =.Suspect Repol Perbd: O6/f0/2009 15:45 Throrgh 0ry10i¡2009 1BtO6

Tltne Orrline C¡ileria:

### f nûnrte(s)

R€porf GÉflsrâbd: .Ofll{U0Il f8:35 Report Verslof¡ 2,3,1 û29 

### I of6Flant

Repod Peñod: 06/1ry200g 15:45 rhroügh 06110/2fi)9 18;06

Time Online Griþría: 

### I minute(s)



## ' cÈflqÆe 

## r*iô ' -"

## "-"'ïrî ' 

### õ¡vioø ïË:¡ï'

## -' *-----a-to*-* ¡o¡tEÐ-15:48*----' Ê.to

### '-

-

.ifrfriFð'-'

## iË'¡T--'-"---ffi 

# *' oóiriftl' tE-:5d '--- ------É.-d5 :

## -- offtoim 

## 15:51 2.53 

### ixiltti,ts 

## ll:52 2Ë0 ib*rtiÃe- " -iÉlss

### - - - -

### -

## --¿sr-- --

### o6tltE--'i3ãlltT0¡fg 

### 1555 2.æ aEjro¡rlg 

### f5s6 2,fr 

### - os/t0Ð9 1557""' 

### "' ' " '¿.& ür1ûræ-- iFät- "-^-'

## -- --

### -tát__*- 

### ffiõ/tu---ifsi'..- 

## -'---'frï--*' öenolus---füfo

## - -- 3,?o

## --- oõiìdffi* 

### ìõ¡t--- ------ --s]m--- '-' {Frfluog 

## 16ø 3.m fuHor@'

## ìaüt- - --îzo' ' ìäfi?ru--îsil4 -'- 

### --------dïD--- " 08¡l0r0ll lûlÞ 3.70 rÈ¡]úos 

### ìî-rä--**- -'--.- 

### !'.nii-. - oõr10rÛ9 

### 1Ê:07 3.70 

### ' .ts¡rló/nÈ re

### s¡i ä.zo mfio/ft€

### t6tp 3.70 riiliäi-m-

### -ie,io- --ä.ro- ' Osfiom 

### 16:f1 I70 trð/ì¡jtiÉ-' ìoirz '---- 

### ' -- -'i?it- --- äÊi,roÐe-

### 'tÊi5- ---

## - - --s.zû-

## - -_ 

### im¡o¡w 

## re:r4 3.?o inãome- --reló----"- 

## --- --tJa-



## -- 0r/1o¡09 

## 1&16 3.15

. 06fit¡æ lÊll 3.15 otrr-ôö,s-- irË'iú -'-- -'

## --- - 

### +îs-'- "' 

### õßiìffi- Ie-:ig- 

### '-' " *--ïi5 -"



### - oàn'om 

## dä'--'"' 

## ' ''' 

## ¡li 0cfio,00 

### rt21 &15 fÉtldrtg tö,'r2


### - ¡üiiöìiF-' r-*zs

### -

## --- ---E.-rs

### --- - oóäõ¡ne

## "loàa - ö.iË

## '

- O6¡tOJtl4l 16:25 3.U 

### irydug 

## t6:2€ ++1 

### Gfroffr 

## ßl¿7 n-41 o€7'öios"-'iï-ËË- (ryror$o

## 16:29 å,{1 Hii¡orií 

### -iãfó' 

## -- -----r¡i'*- * û6rrûtrÉ 

### "

## fb-/ii s.ii - 

## õlio;tÈi'-_lesz- -cni--""-' &iiõ/ûs* 

### -"iêff" 

## ------ -r¡i--= iþ-lorug- 

### -r€ä-_--_-- --"Ë.Ti

## *

- indi¡;rþ --

## ìb:b-s -- 's-¡r

## - ' -oe¡ronÈ- 

### rb-xb 

### ----.-" 3rï SöuÌcè Pammeler (Unit) 

### üt10/Ë rSr4S

F = Unit 

### ûffIine I = 

### lnvalid Ë = Exceedance

[il = Malntenance G =

### Galibration T = 

### Out 

### OfGonhol Report Version Ê.3.1û29 S = 

### Substituted



## " =Suspect Report Generated: 06/'1 0¡Û9 1835 

### 2d6

### Type Rolt Report Period: 0dt0E00g 1b;4S Through ffi/t0/200€ 18:06 Source Para¡neler (unttl ffi/10ilx1 1dÉ7



## ffiæ r6E¡---- zs.7s 

### 43¡t00 1{t5,46 ¡r3t s33 00 r0ç-00 3-3S 535.û0 105å7 9.3Ð

oâfl@ûs 1ÈÆ 

## b-is E9 l+7¡æ.ass.o s33.00 ioo.cz' " +ía

3,55

,t08.6e ÊjJB os10¡!s 

### ä27--------'--zÉ.rr-'"*""-'-'*-'---5_s-

## - --i¡Ëjsijttii --- ----- 

## ¡ii4.ôd- ï04.s2 

## É.Æ-*t*.;f*--_" æ,iï----'-------o-o---'- i?-riffi¿iso 

## -:---'- -${i:iiii--- -

## "" '*--rosã'*- 

## F=unito{fline Ë=Exceedanco 

## G=Gailbmtion s=substituted I =

## lnvalid lt¡l=

## lllaintenance T = Out Of

## GonFol 

## * = 

### Euspest Repoil Gøær#d: 0611 ff09 l8r35 Reporl Verslon 2.3.'t(Þ9 3or6Plan Type: Roll ReportFetud: 0tr10/200$ t5:45 Througù ßffiO/Z0m 18:06

Time otrtne C¡iteria:

### I ninute{s} Soure 

### ffimeter {Unil) 0tr10¡ûS 16:17 -{tt¡otfl{¡ 

## 1e3E 3.41 ffirr-ers

## -iäã-'- -*---ä.Ai.--'^" 

### : õiifräñõ"'-1ðlõ-

## -*----'ã¡î-*-- ðslioms---rr-¡i 

# ---_- ass 

## -- ritÍitutb- -iï;lã
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## **ì-.60



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## --' fEflo¡rs 

## 16.4 zG¡ tr/ì¡ru- 

### -lE iã- "- """*

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## l¡ss '

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### -' ìo-:sr-

## - -

## - - -

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## iiriit" - ' ir3 ôe¡ìäiw- -

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### *-f,aã*-- ûû/iffi -*

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## ifo-_- -'- 1.ä--*- õGÏiû1'tb--*i7iñ 

## * õitud,{ö" "1-?ö5

## '-*---'-'eä'

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## i?Í6 -"' itt ' ódimob'

## t?s¡ ?-04 õúì-ricit''

### *r¡sa--' -* -" " "-

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### -i-.ii-- 

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## '¡i:ti " ""'-"à.ti-

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### ì?:iä-".--"----z:n -

## - ¡¡Ê/itlto-

## lTii'"-*-- ---Lä -

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### llalnlenance G =

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### T= Out 

### of Conlrol R€port Versbn 2.3.1029 

### s =

### subslituted



## * =Suspect REport Genêratâd: 06/f fHls I û:35 dofo

# Av Plant Type: Roll

Source Paranpte¡ {u.Èt} {ltffû¡d¡ 17:8 oû¡to/Tg

## itl¡r Æ.n s.g 

### r+o,so4,oa?.o 

## '' " 5tÊoo 1o5.7s ß,æ

421



## tÈr,iirto''''l?dt' 26.7r ar 

## rr,ßsz,ooBti æs.oo ûÊfid/ftf¡ 17l,2 b1ô 

### 1Ot,ï4 À21 

### iii,i.i3 û21 

### 17 73,3ü.7û0.1t EGS¡o



### 1+liÉt,iüt 

## '" ."

## " ïÉd¡o 

## i$,im_-Íl# ' '

## tiä' s.s ir¡jráã,n*il 

## - ]ilfjDo-

## - ìo,t-sï

## ' '- 3.18

nüt10/09

## 'r7ar æ.tt E:t t+2,6t1,62r.0 

## ---- -ss-rloo-- - -ìö6iOf oglt/û9 17:59 Æ.77 3.18 s.18 

## " '- äiö-'"' '

3.18 3.t8 

## 6's " iic,ËËi¡ið{ö 

## ''-"''''"""'ærto 106.3p

iffitto,ts 1-€lo{'

### '-- u.n 6.4' 

### 1t¡5.84 ?.26

AÉraCe ll¡nlFum ?ÈrÈmn &rrnalbt
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F = Unit 

### Offline f= lnYalid E = E¡rceedance M = Main{enance C = 

### Calibralion

T = Out Of 

### Control ReportVersbn 2.3.1@S 26,78 2t 76 2t7S 3ffi.r4
142 142 €o 5.4 7,1 796.6 1{8,ü¡18,1ts1.3

14sJ7q980.0 152,58q7Ê3.0 1f,102,801.1 92.0 õ35.38 sÊ.f¡o 53Ð.tû 7€,0a4.{t0

S =

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## * =Suspeot 106.{3 '104.tr} 10ê35 15,11?.f7 1.Zt 2.4) Ê28 6{GSa t4? 112 132 142 It¡2 ,142 14? 14¿ 142 142 Reprt Period: 06/1flf20fl9 15ra5 Thruwh 

### 06fr02@ 18106

RepÐrt Gêneráþd: 06/10/E 18É5 5of6

# Avera PtanU Type: Roll Report PerÍod: 06/1 (l¡2009 f5i45 Thrc¡Jgh 0û1 û/2009 1&06

Tlme Ordlne Criüeria: 

### I nfnute(s) Sou¡cê FìeÉnr€tBr (lJnffl 0$1ûffi¡ 17*9 

### bsflo,B 

## lzpo 1,t+ ft¡10/u9 

## lTâ7 4I3 

## *l'ffi

# -JE:::__-11"-:::. 0õfl0n8 l7:t3 

## rÉr@-_-ïl:s4 ato-

## -'* iÉ¡irnc 

### ri*o -----------

## ïiö* "' 

## oiúrets"iibd"" 

## '-' fuô atrlfH)Ð 173,f t.lo ft/10¡t* l7:il0

ü¡10n9 lf50 iidr0ÃË-'ît*i' -" - "

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### rzsr" '- -

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## öö¡îoùis---Î7Fi'. zJit

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## --- -i:EÐ ri6ii'o,pó

## irss à.ss Gifoiüi---rgm*'*- 

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### i¡q-r-ffi-ldõî----- 

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## --' iú¡iö,oo 

### is{z'

## ------- tid "-" ' lË/r¿i/oä 

### .i*trã-------- -äTg - .- rictlo¡æ 

### i'B:04

## - '¿ro rior-rriÉ**fiäË-

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## ---tiJ* 

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AwrdgË S¡Fúnrm fvls¡dnm Smmdtm
lndld€d D* ron¡s ToËf rrfibsd ÞÊlã PDiiTg 3.13 2.13 4.19 441:75 112 112

F = Unlt

### Offlne I= lnvalld 

## E=E¡rceedance 

## G=Calibralion S=SubstitutBd [¡T= 

## irlaintenance T= OutOf

## Gontrof

## * = 

### Suspect Repofi Generafed: 06/'f0/û9 f8:35 REpoil Vers¡or¡ 2,3. 1029 6of6Plan

Report Perlnd 0Ê¡11/2009 07:53 Through 06/11/2009 1û:12

Sot-dcs PErìsm6Þr (rJû-0 ofr'tlrTlg flrÉ3 oo¡trtbs

## " ui+l 5.0 148,78{t 90[.0 $4,m iidrrræa- oz¿r

## ---- --øì-ii------ 

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0ûfllÆf¡o7:5s 2€.74 5-s 15{¡.848,878_0 535.00 '-¡Or.tr {¡9fl1¡m ûôfO n,fl 

### s3s-{l0 1r2-æ LO5 215 zle

1.81 lflt 1.06 

### s.7 t49.såI.8û30


### ÉJllr$ f¡Btr 

## '' rió '' tsc.ø#,sfln 

### 535.00 !0+.n4

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### ß5 lso.?03,s€zo 5ts.oo 104i4 às9



### otlrrco 

## æ:it m.T4 6.s 152,23lJ',2T1.9 53é.00 108.â4 23,9 fl8¡llir¡g Ot.r¡ -- -Æ-iÀ

0A/llJrüO 0e¿2 ß.11 s.1 

## iso,+#,ias.d s¡soo îo?.s6 zts

o€ll1¡tg

### iAfr æ:f4 6.3 r47,sr7,08{l_t 

### - s3sllo 

### - -1-û+k------- ------Iõs-- 

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## 2{tz+ e.s lsz.zÌf.tos.o 

### 53f.0r 103.t3 t.s3


## 2Ê.¡i {iì -' ìå+¿spï¿o 

## 2A,A 6.7 150,372J17,0 535.0t 103.71 l-&t s5.oo 

### rrx.l4 1.& o8¡11¡uá àrüi o6/il¡û9 {Xì28

ä#rTroi 'oerls ' aË/1trtg (B.É{

0€/11¡tr9

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## Ê.4 t5aÉEg:2r?.0 fir-oo

## ' '- rærþ l-88 û6¡llEg 0841 æ:?4 ô¡ ?9"814,?€0.81 

### s$s-o{ 10ü.44 l.9S (F¡rrþÐ 

### 00r4a zt.z3 ---ç- res28zætt -æ¿ao---ro¡¡g- - - '""t:9ü-


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### I núnuúe(s)

Råpo¡t Ge¡teøed: 06f11/@ 12:10 Report Version 2-3. lO29 

### I cf 6Plen Type: Roll RepoÊ Period: 0#f 11200,S 07:53Through 0Ê/l 11200Ð lû:17

Time Online Criteda: 

### I mirrub{s}

0e¡1fi1s 0?É3 ¿10 08/11¡æ 

## o7:fl z1i itöiîinf- 

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## -'*--iiill *** i¡ryrrivp os{È

## **- _-__t{

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### ffirr¡{B 08fr 2.+4 inry-i-¡le- iiortl--.- 

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### Control Report Version 2.3.1 029 S =

### SuÞstlfirlod



## * =Suspect 2o,IARepcrt Period: 0û/l T/200S 0253 Through 0ù1 1/2009 10:17 Sor.fo6 Fsrsmål¡ãÌ (tjrtr) '0t!-ltiü9 08:.16 ËlllJÐe 0€.'i6 

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### 005s roir¡ r.r iËi,àa¿o¿o.o' "'"s?ü,oo rri€,1b 1.72 06t11fiEr 

### 085s æ,7X 6.5 151,759ì124.0 8ô.æ iû3ßÐ 1.72 

### oen-t'ffi*-6is

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## -'""'- -'äii 0tr1fÐÐ 

### @:t¿ m,73 6.5 150.764.t0t.0 fit500 fO4.Ê6 Z.iz 091Ì/09 @ ür 

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## t'É/r'ii{tä""ffit-' --2ê.if ''È4" -i-fijeojzeli-----------s-s¡ì*'"---^-----iii4sì'" ----;.i¿- 

## ösn-øt"'--óia *:È

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### æ,74 6.s 16dlz54,s1r-fl sss.to t0s-17 zsz 

### æ14 5.8 rß,0æ.8€A.ût ESt¡o 10520 1,O'l

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### llrs 09:zû æ.14 

## óô7-æ ltrLzs fì^50 ûsftl/ft¡ 

### æÐ, æ14 î,4 r5i,0osJl*.o 536¡0 

### 104.41 0lo 06fl1rus

### ag23 26.74 s.t 149.0€9t{t_o fi!5_00



### üflri[g æÉ0 

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# F=UnltOffline E=Exceedance 

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# l=lnvalid M=ftlaintenance T=OutOf

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## r =SusFect ûñrllfit 08:15 0ûf11/tÌÐ Gt:"16



### a0 153.ts2"t?0.û

Repo¡t G€nerE{ed:otrf1/09 1210 Report Vera¡m 2.3.10e9 30Í6Plan Type: Roll RepoÉ Pøiod: fl6/lll2Ð0$ û7:53'fhmugtr 06/f 1i20001û17



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### .iIçid-rffi-osiï--*---- --- 

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## ffir-äÉ--os1qs- i.ôö"""' r-s8 ûgll/úo 0û50 frdrTfu*"inst'--' 0G/11ÐS 08:5¿ 0tf1l¡09 

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## * =$uspect Report GenereH: 06/1 1/08 12:10 4of FPlant

Repo¡t Period: tW11¿00s 0ZSSThrougtr 06/11/2003 1û:i7
Source PffifìÌ6têr (Untl 0t/11/û,s æ37 i¡e¡it,os 

## ûs:gg at.ll 6.1 fst.1ô7.0ÉÉ.0{c fs6lt0 t04-44 s¡-¡ 

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## 835,Ð0 '

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## io# 'rari' ' - - b€ 

### rsi,åF¡,f3û.t s35.00 104,15 wif¡9fl tifi7 

## zs'?S ss f50,9eã"507.r 

## $35.00 aoaåÉ i.eo 

### 530¡0 10330 r-lû

Awmge frg¡rlñtm ¡Àarlll|lftr SmiläEon
lncludrdIIS Pólrús Tald 'l¡nbtr of Dã16 Polr*g

F = Unit Offline I = lnvafid Ë = Ëxceedance M = lHalntenance ,i51+r¿2ü?.0
f{7.?fr4180.û t5Û,7r5.507_ll 15,?46,Ê69Æ27.0

G =

### Calibration 

## f = OrrtOf 

### Çont¡ol Report Versr-on 2.3, 1029 S = 

### Substituted



## * =Suspect E?4 2&7X 2475 3,S48.e2 6.S 55 7.3 9133 53526 55¿00 t37_otl u,6'13.00 1Q4.2f 1î1 52 10ö.49 rf,l19.14 1¡Li r45 145 145 145 t45 1M r¡16 r45
145 14ã 14s

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# - Report pedod 

### o*r 

### r^oT8i,ulflruæh 06/r 

### ilzoft) l0:1?

061flj0{l Og;¡t{l oeliins- {rÞfo 1$4 I,g4 S{xJrce PsrsriletFr (unfü 08J11Ë 0gg? 

### osfltlw

## i¡Ð:ar' a?E E]l 

## r-/Éoe-""" - -* "

### *

### - 21{ 

### - -- õürnmÐ -_

### ß;b--'- 

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### -'''^ " " ^

### "-î.ü-"'..* üft'ircd-"bil.{¡ 

## - ' --i:ö4

## - -' o-alir¡ù¡i ' ils:4i

## " """ -t¡í,i- 

## ".'

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### iË -- õb-Æ--

## "*.-*' *'i:d' 

## *--

o6níl,s --o+-æ--**- 

## ----îe-+-* ottJll@ (}s47 1,9¡l 

### õeä'r-,m--oõ-¿d; ---tri,a---'* 

### ïrne Online Criteria: 

### I r*n¡te{s}

G = 

### Galibration T =

### OutOfGontul Repod Verebn 2.3.1o2s AìrÊt4å MfÈrl{n trtarùil¡¡ir qrffidkfi
fndud¿d Då.tt Pt*ús Iêld f*lrt$êrçil Þ¡È Point*

F = Unit 

### Off,ine I= 

### lnvalid E = Exceedance þI = 

### illaintenance 1.9'Ì 't.L5 2.78 2ffi-46 14f t45



### S= Suþstiftrted 

# ' = 

### Suspect Repod Gçflerded: 06JtlJ/@ 1U 10 6of8Glass nozzle 

### l 

# f neated glass-lined 

### stainless steel probe Heated Teflon 

### Thermometer line



### Thermocouple h

### Temperature Pitot tip 

### artz Filter

lnclined 

### manometer 100% isopropanol 

# \i \ 3o/o

## HrO, Silica Gel

Vacuum line


### Thermometers By-pass valve Vacuum

gauge


### Exhaust
I

Y lnclined 

### manometer Dry 

### gas meter Vane pump



## Figure 5 - EPA 

## Method CTM-0138 

## Sampling Train

19

## 4.2.3 Gondensable Particulate 

## Analysis - 

## EPA 

## Method

# 202 The total



## condensable particulate matter in

## the back half of

## the sampling train 

## was determined in 

### accordance 

## with Method 

## 202 procedures. The impinger contents and aqueous rinses 

## were combined 

## with the methylene chloride rinses and extracted twice 

## with methylene 

## chloride using a 

## separatory

## funnel. The sample 

## was divided into 

## organic (methylene chloride) 

## and inorganic (aqueous) 

## fractions. The organic fraction 

## was evaporated at room 

## temperature and pressure, and 

## the resulting residue 

## was analyzed gravimetrically to a constant we.ight.



### The 

## total condensable particulate matter in

## the back half of

## the EPA Method 5 sampling train 

## was determined in accordance 

## with Method 202 procedures. The impinger contents and 

## aqueous rinses 

## were combined 

## with the methylene 

## chloride rinses and 

### extracted twice 

## with methylene 

## chloride using a 

## separatory

## funnel. The sample was 

## divided into 

## organic (methylene chloride) 

## and inorganic (aqueous) 

## fractions. The organic fraction 

## was evaporated at room 

## temperature and pressure, and 

## the resulting residue 

## was analyzed 

## gravimetricallyto a 

### constant weight.



## The inorganic fraction 

## was evaporated to dryness 

## at 105oC, 

### and 

## the residue was analyzed 

## gravimetrically to a 

### constant 

## weight. Since 

## the pH of

## the original solution was greater than 

## 4.5 and 

## theoptional ammonia 

## addition step 

## was omitted.



## The back-half 

## condensable particulate catch 

## was equal 

## the organic residue plus the inorganic residue.


## 4.2.4 Gondensable Particulate 

## Analysis - 

## EPA 

## Method

# OTM-28 Condensable particulate matter 

## was determined in accordance 

## with EPA Other 

## Test Method 28 

## procedures. The 

## water soluble CPM 

## was extracted from 

## the CPM 

## filter andthe aqueous 

## extract combined with 

## the contents 

## of Container 

## 1. The organic soluble CPM 

## was extracted 

## fromthe CPM 

## filter and 

## the organic extract 

## was combined with the contents of Container 

# 2. The aqueous impinger 

## contents in 

## Container 1

## was placed in a 

### 20

### separatory 

## funnel and extracted twice with 

## 30 ml 

## of methylene 

## chloride. This organic

extract 

## was combined with 

## the organic 

## train rinse in Container 2.



## The organic phase 

## extracts and rinses in Container 2

## were placed in 

## a beaker and the 

## volume reduced 

## to less 

## than 10 mL 

## at room

## temperature. The beaker contents were 

## then transferred 

## to a pre-weighed 

## tin and evaporated 

## to dryness 

## at room temperature. Following evaporation, 

## the organic fraction 

## was desiccated for 

## 24 hours, and then 

## weighed at

## 6 hour intervals to 

## a constant weight.



## The contents 

## of Container 1 

### (inorganic fraction) 

## weretransferred to 

## a clean beaker and the 

## volume reduced 

## to less 

## than 10 mL 

## at 105oC, 

### and 

## then allowed 

## to dry at room 

## temperature. The residue 

## was re-dissolved in 100 mL of deionized 

## distilled ultra-filtered 

## water. Titration 

## with 0.1 N NH4OH 

## was used 

## to neutralize 

## acid in

## the inorganic sample 

## and remove 

## water of 

## hydration. The 

## volume of

## titrant used 

## was 

## recorded. The volume of the 

## aqueous phase 

## was reduced to 

## about 10 mL 

## at 105oC.The beaker contents was 

## then transferred to 

## a pre-weighed 

## tin and 

## evaporatedto dryness at room temperature. Following evaporation, 

## the organic fraction 

## was desiccated for 

## 24 hours, andthen 

## weighed at 

## 6 hour intervals to a constant 

## weight. The 

## weight of

## the inorganic residue 

## was corrected for 

## the NH4* 

## retained in 

### the sample. 

## 4,2.5 condensable so¡/Hzso¿ - 

## EPA 

## Method

# cTM-138 sample analysis was 

## performed using lon Chromatography 

## with conductivity detection. 

# 4.3 Data

# Analysis Equations relatedto

## the pollutant sampling, including gas flow rates, 

## temperatures, percent isokinetics, and moisture 

## content are 

## shown in

## Appendix C.



### The 

## test results 

## are reported 

## as mass rate in

## terms of both lb/MMBtu and lb/hr. Emissions 

## in lbiMMBtu is 

## calculated using 

## thedry oxygen-based fuel factor 

## for bituminous coal (9780 dscf/MMBtu), 

## which is 

## published in

## Table 19-2 

## of EPA 

## Method 1g in

## 40 CFR 60.
21

# 4.4 Equipment 

# Calibration Field equipment 

## was calibrated in accordance with the

requirements of

## the applicable EPA Methods, and 

## withthose recommended within the Quality 

## Assurance Handbook for

## Air Pollution 

## Measurement Systems: 

## Volume 

## lll (EPA60014-77-027b, 

## August 1977).Appendix F

## contains records for all

## the calibrations.

22

# Appendix 

# A Test Log