RMB Gonsulting & Research, Inc.

5104 Bur Oak Circle

Raleigh, North Caroli na 27 61 2

September 2I,2009

Mr. Ron Myers, D243-05

Measurement Policy Group

U. S. Environmental Protection Agency

Research Triangle Park, NC 27109

Phone (919) 510-5102

FAX (919) 510-5104

Re: Condensable Particulate Matter (CPM) Test Report for Coal-Fired Power Plant

Submitted for Rulemaking Docket EPA-HQ-OAR-2008-0348

Dear Ron,

Enclosed, please find a copy of the above-referenced test report. The unit tested is an electric

utility generating unit (EGU) that burns eastern bituminous coal and has a nameplate rating in

excess of 500 MV/. The unit has a selective catalytic reduction (SCR) system for NOx control; a

cold-side electrostatic precipitator (ESP) for PM control, and a flue gas desulfurization (FGD)

system for SOz control.

The enclosed report describes the results of a test program in which three independent sampling

runs were conducted simultaneously using: (1) EPA Method 5/202; (2) EPA Method 5/OTM 28;

and (3) Conditional Test Method (CTM) 138. I believe these test results provide additional

technical support for some of the comments we have previously submitted in regards to Other

Test Method (OTM) 28 andthe subsequently proposed amendments to EPA Method2}2.r'2

V/hile the report contains lots of data, the results are well summarized in Table 1 (p. 3). Table 1

shows that OTM 28 was effective in reducing some of the (sulfate) biases (0.041 versus 0.023

lb/106 Btu) that have historically plagued EPA Method2O2.3 Unfortunately, Table 1 also shows

that the OTM 28 results are over 2 times (0.023 versus 0.0101b/106 Btu) the results obtained

from the controlled condensation method, indicating to me that a sulfate bias is still present. As

you may remember, while we agreed that the OTM 28 approach (a.k.a. dry impinger method)

could lessen the sulfate bias as compared to original Method 202 procedures, we questioned if

OTM 28 would be a satisfactory solution for all sources, especially those employing wet

pollution control technology. I believe the EPRI research, also only performed only on simulated

flue gas, showed that the effectiveness of the "dry impinger method" could be compromised

under more challenging flue gas conditions. I only skimmed the field data sheets in the enclosed

report, but I believe 80 to 90 ml of condensate was collected for each OTM 28 run. In other

words, the dry impingers do not stay dry very long, especially for wet stacks.

' I 4 Fed. P(eg. 1297 0 (Malch 25, 2009).

2 See, for example, Comments of the Utility Air Regulatory Group, May 26,2009, Docket EPA-HQ-OAR-2008-

0348-0049.

3 In this letter, when refelence is made to Method 202, we are referring to the method EPA published at 56 Fed. Reg.

65435 (December 17, 1991).
LETTER - Ron Myers

September 21,2009

Page 2

Not to get ahead of myself, but there is another test report, which reflects a quite different plant

configuration that I am trying to get finished and delivered to you. That unit burns

subbituminous coal and has a spray dryer absorber (SDA) followed by a fabric filter. Because of

the fuel characteristics (low sulfur and high alkalinity ash) and the pollution control technology,

combustion experts would doubt the presence of measurable concentration of CPM.

Unfortunately, OTM 28 "finds" the CPM concentration to be more than twice the filterable pM

concentration.

If you have any questions regarding this enclosed test report, please do not hesitate to contact me

at loberson@rmb-consulting.com or (919) 510-O3l 6.

Respectfully submitted,

Ralph L. Roberson, P.E.

Principal

Enclosure
>JACG I lnformationat Test

Report for Gondensable

Particulate Matter and

Gontrolled Gondensation

for the (Anonymous)

åfí."äi,#^ï"åX, lstack at (Anonymous)

Fï,",ij8,?luouo#" lPower Station

Pennsylvania Office

44e veir Road I Prepared for

lilii:lirrryãrrev' 

PA 1e006 

| {nnonv-ous)

Fax: (215) 3644596

Test Date¡: June 10 -,,1r 2OOg

Report Date: August 1Tt 2OOg

ACG Contract Number [private]

3.0

4.0

2.0 Summary of Results

Discussion of Results ..................7

Sampling and Analytical Procedures .........7 4.1 Sampling Procedures.............. .............. g

4.1.1 Sampling Point Determination - EpA Method 1............................... g

4.1.2 Volumetric Measurements - EpA Method2........... ............... g

4.1.3 MolecularWeight Determination - EpA Method 3....... ......... g

4.1.4 Flue Gas Moisture Content - EpA Method 4.....,.. ............ 11 4.1.5 Particulate Sampting - EpA Method St2O2 ................... 11 4.1.5.1 Sampling Train Description .......1j

4.1.5.2 Sampling Train Operation. ............1j

4.1.5.3 Sample RecoveryandClean-Up.......... ..............12

4.1.5.4 Blank ...............12 4.1.6 Particulate Sampting - EpA Method S/OTM-28 .......14

4.1.6.1 Sampling Train Description ...........14

4.1.6.2 Sampling Train Operation......... ..............14

4.1.6.3 Sample Recovery and Clean-Up.......... ......16

4.1.6.4 Blank ...........17

4.1.7 condensable sos/Hzsoa sampring - EpA Method crM-01 3P ..... 17 4.1.7.1 Sampling Train Description .....17

4.1.7.2 Sampling Train Operation........ ......... 1T 4.1.7.3 Sample Recovery and Clean-Up.......... .............. 1g 4.1.7.4 Blank .................. 1g 4.2 Analytical Procedures......... .......... 1g 4.2.1 Molecular Weight Determination - EpA Method 3A....................... 1g 4.2.2 Moisture Content - EPA Method 4.............. ....... 1g 4.2.3 condensable Particulate Analyses - EpA Method 202 .................20

4.2.4 condensabte Particulate Analyses - EpA Method oTM-29 ..........20

4.2.5 condensable soa/Hzsoa Analyses - EpA Method crM-1 gB .......21 4.3 Data Analysis........ ...........21 4.4 Equipment Calibration............... ............22

LIST OF TABLES

Table 1 - Overall Summary of (Anonymous) Average Emissions ........ 3

Table 2 - Summary of Total Suspended particutate (TSp)

Emissions by EPA Method Sl2O2 Anatysis - (Anonymous) ....... ........4

Table 3 - Summary of Total Suspended particutate (TSp)

Emissions by EPA Method 5/orM-28 Analysis - (Anonymous)... ........ s

Table 4 - Summary of H2SO¿, SOs, and SOz

Emissions by Conditionat Test Method 138 ...... ...........6

LIST OF FIGURES

Figure 1 - EPA Method 5 sampling and rraverse points: (Anonymous) stack............... g

Figure 2 -EPA Method 3 Sampting Train........ ..... 10

Figure 3 - EPA Method 5 Sampling Train. .. .......... 13

Figure 4 - EPA Method S/OTM 028 Sampting Train .... 15

Figure 5 - EPA Method CTM-0138 Sampting Train.... ..... 19

APPENDICES

AppendixA-TestLog

Appendix B - Data and Results

Appendix 8.1 - EPA Method 5t202 Data and Results

Appendix 8.2 - EPA Method 5/OTM-28 Data and Results

Appendix 8.2 - EPA Method CTM 138 Data and Results

Appendix C - Equations

Appendix D - Raw Field Data

Appendix D.1 - EPA Method 5t202 Raw Fietd Data

Appendix D.2-EPA Method S/OTM-28 Raw Fietd Data

Appendix D.3 - EPA Method CTM 138 Raw Fietd Data

Appendix E - Analytical Data

Appendix E.1 - Analytical Gravimetric Data for EPA Method Sl2}2Analyses

Appendix E.2 - Analytical Data for EpA Method crM 138 Analysis

Appendix E.3 - Analyticat Data for EpA Method OTM-28 Analysis

Appendix E.4 - Analytical Data for 02 and coz Analyses of lniegrated Bags

Appendix F - Field Equipment Galibration Data

Appendix G - Facility Data

ilt

Executive Summary

Air emissions stack tests were conducted at the (Anonymous) power Station on the

stack serving (Anonymous) to satisff the diagnostic requirements set by (Anonymous).

The Air Compliance Group, LLC (ACG) of Roanoke, Virginia, conducted the test

program on June 10 and 11 , 2009. Three valid EPA Method 2O2, CTM 138, and OTM28 tests, for the determination of Condensable Particulate Matter (CpM) emissions were

completed on the (Anonymous) stack. All pollutant sampling was accompanied by

measurements of the temperature, static pressure, moisture content, molecular weight,

velocity, and volumetric flow rate of the flue gas. The testing was conducted in

accordance with the procedures of the Code of Federat Regulations. Below are the test

results

1.0 lntroduction

1.1 Background An air emissions test program was be conducted on

(Anonymous) at the (Anonymous) power station, located in (Anonymous city),

(Anonymous State). The purpose of the testing was to evaluate total filterable and

condensable particulate emissions when measured by ditferent EpA emission testing

procedures. The filterable PM emissions limit for this facility is 0.030 lb/mmbtu. The test

program was conducted on June 10 and 11,2009 by The Air Compliance Group, LLC

(ACG) of Roanoke, Virginia. ACG personnel participating in the test program were

Frank craighead, Kenley Houtz, Jared cypher, Aaron cypher, Jason Hill, Michael

Wilson, and David Hill. [Un-named individual], of (Anonymous) provided on-site project

coordination.

1.2 Obiective The purpose of the test was to satisfu the diagnostic requirements set

by (Anonymous) Power

1.3 Test Program Three 12O-minute test runs for condensable particulate matter,

SO2, and SO3/H2SOa wêre conducted on the (Anonymous) stack. Each test run included

determination of the given pollutant emissions, plus measurements for gas temperature,

moisture content, molecular weight, gas velocity and volumetric flow rate. Test runs were

sampled in conjunction with three of the EPA Method 5 tests that were being run to prove

compliance.

2.0 Summary of Test Results

Table 1 is a summary of the average test results from all three sampling methods

performed on (Anonymous). Table 2 is a summary of the EPA metho d 202 sampling,

Table 3 is a summary of the EPA method OTM-28 sampling, and Table 4 is a summary

of the EPA method CTM 138 sampling.

Table 1 - overall summary of (Anonymous) (Anonymous) Average Emissions

EPA

Method Pollutant

Reporting

Units

Emissions

Limit

Average

Emissions

EPA Method

5t202

Condensable Particulate Emissions

lb/MMBtu

(Oz based)

N/A 0.041

EPA Method

s/OTM-28 NiA 0.023

EPA Method

138

SO3 + ¡1560 Emissions (as H2SO4) N/A 0.010

SO3 + ¡r59a Emissions (as SO3) N/A 0.010

SOz Emissions N/A 0.064

3

TAÊLE2

SU]ITIARY OF EPA TIEIHOD Ð2 GONDEflSGLE PARrþTT'IÍE TATTER EII1SSIOI¡S

EUN I.D.

DATE

ÏIMÊ STARTED

fIMËENDED

s0en6¿0âR5

06110r0s

&t{

f{r.t8

8û0-f,ãlito¿Rr

Ë/lotlg

l5rE5

1&{e

sll0{r6P@*8

06/1t/09

7:53

1ù,1t

AVERAGE

GAT|IPUNG PARAilETERS

UeûaodVotuna(d@

Ooneøed Wume(dscf)

Totd lèslTlno (mr:n)

l¡*ìneti<x (961

.GAS PÂRÃIIIETERS

Gas To'llpor.tlÚl(.F)

Oq¡gen (9É)

Catôqrr Diorddc (*)

ûiloîst¡€ (9ó)

EASFLOIIÍ RA?E

våþdty(üqoê)

Adrrd volumo (æ1Yn)

Stsnda¡d Volurne (dsc{m)

CONDÊI,|!¡IELE PAR¡lCtrLATE trISStONS

Conc, (grfdsd)

Itlass Rate (h/ht)

tlaes Rala tlh/MMBùr) O2-bered .

93-¿t4ü

0r.475

1m

9t_0

s¡30

ôl-0rs

120

95.6

s0.628

833If

12i

sü.6

94.8:Ì5

82.20

t2a

95.4

t07

1L0

3.5

7-2

lrF

14.O

3-2

7.1

107

14.0

¿.0

t.7

107

14.0

s2

7.1

43.{E

35lt¡æ

z72owß

o.ot0

2d4ô8

o.04¡f4

49.44

3s131€1

269Ín1t

0.010

231.86

0.o+2ö

4Ð_il

35ãt664

2tl2&¿s

ol¡o8

1ù1Æ

0.û3.t8

¡¡9.5f

35fe¡40

2708S8

0.0r0

z¿2.41

o.0406

'lbrf,tMBtu ìr¿luê based on F-lbctorof g7g0 dsüúftlMElu for t¡ifuminor¡¡ ooal ln Taôlc i$2 of 40 OFR 60, Appendü A, Melhod 19.

4

TABIEs

SUI¡IIIIIRY OF TPA Oilr ZC CONDENSIBLE PARITC-IJI¡TE MATÍER EIIISSIONg

RUNI.D.

DAÎE

]rMESTARTED

TIô,IEENDÉD

s00+toTti28d5A SOft-itoTit2ùR?A s0GuoTilzt{8A

0at1ÆÁ

TrSt

1e.17

AVËRAGE

06/f0/tt9

8tì4

10;¿18

0€/f0/09

l5:¡15

18;06

SAIIPLING PARAIìIETERS

tyl€brcd Volu¡r¡e (dcf)

Cor¡ecbd Volur¡e (dssf)

Totd TeS?ïme{minl

ta*iuücs(?6)

GAS PARA¡æTERS

Gao lerperaúre ("F)

,Otq,len (%)

carbon Oioxitê (%)

l\lt¡l*urc(%l

.GAS FLOT'I' RATE

Veloclty (û$oc,

Acütal Volune (acÉn)

Sümded Vofune(dscfm)

COIII}ENSIBLE PÄRTICUI.ATE E}IIEs K}NS

Gonc- (grldscf)

Mass Rate(lMrr)

Mass RaE {tù/ùlll/8U}: O2-based.

90.410

78.670 In

912

s3.712

80.788

f20

c2.3

50,53

3590909

215132ø

95.325

81.818

12Q

94.2

93.t49

80.4!5

120

92.ö

107

14.2

3.5

7-4

105

14.2

3.1

7.O

109

14.0

39

6.9

108

14.4

a5

8.4

¿[9.92

3Éltt¿9

2710584

0.007

1f1.lo

0.0037

0.0û4

93.98

0.0175

oæ4

10û¡f

ô-0r70

49.9t

3$9223

2'AÈÍITE

50.09

35õ9i¡21

273@96

0.005

12e69

o.oz3o

tlob.

' lMÍMB.tu røfues based on F{actD¡s lbr bii¡rrirous cæl h Tablc ,10,2 of 4o CFR 60. .Apperdlx A, [ilex,rod 19_

TABLE4

SUIIMARY OF H2SO4 SO3, ¡nd so:l ElllssloilS BY COHDIT|oHAL TEST ilETHOO l3B

RUN I.D.

, DATE

TIME STARTED

T¡f\,IE ENDED

s00.cf¡Í38.¡ul sotÞcTuf3Bfi3 s00-cTHt3Bfi4

0Añ1.99

7:50

1ù17

AVERAGE

0d10/0e

8:f)4

l0:48

06/10/0e

15:45

18:06

SAIIPLING PARAMËTERS

Mete¡ed Volume (dcf)

Oonected Vdurne(ds@

Total TestTìme (m[n)

.lsokinelics{%)

G/IS PARATIETERS

Gas Tempenature ('F)

Onruen(96)

Carbon Dioxide (%)

Molsture (%)

GAS FLOIIY RATE

Veloclty (trsec)

ActualVolume (acún)

Stancfa¡d Volurne (dsclTn)

So3 + H2SO4 EillSgoNS (æ H2SO{)

CorËênlfeüon (ppmdv)

Mass RaÞ (lblhr)

Mass Raþ(lb/ltrlMBtuf

8O3 + H2SO¡I EIiIISSIONS(asSO3)

Concenfration þpmdv)

Mass Rab(b/tr)

Mass Rete(b/MMBt¡f

soz EiltsstoNs

Concenfatisr (pprnclv)

Mass Rata(fMrr)

Mass Rata (lb¡lMMBürf

læ.404

91.738

120

9S.3

53-43

37S7181

2S03859

1_12

49.67

0.009

1.37

49-67

0.000

14.28

820-21

0.076

102-217

g2.622

12Ð

100.3

112

14.0

4.O

ô.4

53-36

3791701

29036s-/

1,35

59.66

0.01o

1.65

5S.66

0.010

10.4€

4*.13

0.051

99-507

90.150

120

s8,8

t00.730

81.5(,3

1m

99.õ

53.22

378f967

28e2272

1.33

58.ô0

0_010

n.a

&16.53

0.064

112

14.5

2ß

6_6

112

14.0

3_0

6.7

112

14-2

3.3

6.6

52,87

3757019

286S30f

1.52

66.46

0-011

1.86

6t.46

0.011

13.17

565.25

0.0ô5

r.83

58-60

0.010

'IUMMBüJ values based qr F-fâctors for bih.rminous c.oal in Table 1g-2 of ¡lO CFR 60, Appendix A r/þhod lg.

6

3.0 Discussion of Results

Testing was conducted as per the test protocol, dated May 5, 2OOg, except for the CTM

138 trains, which had to omit the coiled condenser due to space restraints. No further

problems were encountered during the execution of the test program.

4.0 sampling and Analytical Procedures sampting and anatyticat

procedures complied with methods recommended by USEPA in Appendix A to Tifle 40,

Part 60 of the Code of Federal Regulations (a0 CFR 60), or other methods accepted by

the USEPA. The following specific methods will be used:

o EPA Method 1 for determining sampling and traverse points;

o EPA Method 2 for determining flue gas velocity and volumetric flow rate.

o EPA Methods 3 (sampling procedure) and 3A (analytical procedure) for

determining flue gas composition and molecular weight;

o EPA Method 4 for determining flue gas moisture content;

o EPA Method 5 for determining particulate emissions;

. EPA Methods 202 and OTM-28 for determining condensable particulate emissions;

and,

. EPA Method crM-O138 for determining condensabre sos/Hzso+.

7

4.1 Sampling Procedures

4-1-1 Sampling Point Determination - EPA Method 1 The procedures of EpA

Method 1 were used to determine the number and location of sampling and traverse

points at the stack. Twenty-four sampling and traverse points (six for each of four ports

in a circular stack) were used for sampling and flow rate measurements. Figure 1

shows the locations of the traverse points for (Anonymous) used for EpA Method 202

and OTM-28 sampling. Sampling for condensable SO3/HzSO+ wâS performed at a

single point in the stack.

4.1-2Volumetric Measurements - EPA Method 2 EPA Reference Method 2 was used

to determine the velocity and volumetric flow rates of the stack gases. Stainless steel typeS pitot tubes were used to measure the gas velocity heads. pitot tubes were

calibrated/checked according to EPA Method 2. These measurements were performed in

conjunction with the particulate sampling described in section 4.1.5.

4.1.3 Molecular Weight Determination - EPA Method 3 Gas compositional

measurements (O2 and CO2) for determining the average molecular weight of the stack

gases were made in accordance with EPA Reference Method 3. Multipoint, integrated

sampling was used to obtain a constant-rate sample of flue gas concurrent with the

pollutant testing. Sampling was of the same duration (except purges following port

changes) as the pollutant runs.

A stainless steel probe was affixed to the pollutant-sampling probe for this purpose,

and a peristaltic pump (delivering 500-750 ml/min of flue gas) was used to fill a Tedlar

bag. Moisture was removed from the sample gas by an air-cooled condenser located

prior to the pump. Figure 2 shows a schematic of the Method 3 sampling train.

I

12 3 4 5 6 6 5 4 3 21

Port Depth is 97 inches

Point o/o of lD

Distance from

lnside of Port

linchesl

1 21 9.79

2 67 31.22

3 1 1.8 54.99

4 177 82.48

5 25.0 116.50

6 356 165.90

lnside Diameter 466 in. 38.8 ft.

Distance Upstream from Disturbance 5880 in. 12.62 dia.

Distance Downstream from Disturbance 1710 in. 3.67 dia.

Figure I - Sampling and Traverse Points for Stack

Method 3 probe

(1|4-inch stainless

steel tubing) Peristaltic pump

Tedlar

sampling

bag

Figure 2 - EPA Method 3 Sampling Train

10

4-1-4 Flue Gas Moisture Gontent - EPA Method 4 The flue gas moisture was measured

in conjunction with each of the particulate tests according to the sampling and analytical

procedures outlined in EPA Method 4.

The flue gas moisture for each test was determined by gravimetric or volumetric analysis of

the water collected in the impingers of the particulate sampling train. All impingers were

contained in an ice bath throughout the testing to ensure complete condensation of the

moisture in the flue gas stream. Any moisture not condensed in the impingers was captured

in the silica gel contained in the fìnal impinger.

4-1.5 Particulate Sampling - EPA Method 51202 Condensableparticulateemissions

were measured in accordance with EpA Methods 5 and 202.

4-1.5.1 Sampling Train Description Figure 3 shows the major components of the

Method 51202 sampling train. A heated stainless steel probe with a Teflon (TFE) liner

was used to withdraw the gas sample. The probe was heated to 24goF + 25oF, to

prevent water condensation. The probe was equipped with an appropriately sized

stainless steel nozzle for isokinetic gas withdrawal. From the nozzle and probe, sample

gas was pulled through a heated glass fiber filter, maintained al24goF + 25oF, and

subsequently passed through an impinger train consisting of five glass impingers

immersed in an ice bath. The first three impingers each contained 100 milliliters of

deionized distilled water. The fourth impinger was initially empty, and the fifth initially

contained approximately 200 grams of silica gel.

4.1.5.2 Sampling Train Operation Sampling was done in accordance with EpA

Method 5 procedures and specifications, including leak checking, isokinetic sampling rate

and stack traversing. Sampling was conducted for 5 minutes at each of the 24 traverse

points (see Figure 1). Each test run had a duration of 12O minutes, excluding the time

required to change ports. As required by [Regulatory Reference], a sample volume

of greater than 60 dry standard cubic feet was acquired during each sampling run.

11

4.1.5.3 Sample Recovery and Glean-Up Recovery of the Method 5 sampling probe

was accomplished using a Teflon bristle probe brush. The nozzle, probe and front-half filter

housing was rinsed with acetone three to six times each and brushed between rinses.

The back-half of the sampling train (impingers plus connecting glassware) was

recovered in accordance with EPA Method 202 procedures. The pH of the first

impinger was measured immediately after the test. The entire impinger train was

purged for one hour using ultra high purity Nitrogen in accordance with Method 202

procedures. This was performed regardless of the pH of the impinger contents

After purging, the contents of the first four impingers was measured and transferred to

glass jars. The first four impingers and all back-half glassware were rinsed twice with

water. Allwater rinses were collected with the impinger contents. The back-half

glassware was then rinsed twice with methylene chloride. These rinses were collected

into a separate glass jar. The silica gel from the fifth impinger was transferred back to

its original Nalgene container.

4.1.5.4 Blank The blank was a sample of reagent-stock acetone collected during the

test program, and was analyzed in the same manner as the actual stack-test samples.

12

Glass or stainless

steel nozzle

Heated glass-lined probe

Thermometer

Thermocouple

Pitot tubes

(type S) lnclined

manometer

100 ml Empty

deionized

water

Silica

gel

ïhermometers

Exhaust I

t

Coarse

valve

Vacuum

gauge

lnclined

manometer

Dry gas meter Vane pump

ì

Figure 3- EPA Method 51202 Sampling Train

13

4.1-6 Particulate Sampling - EPA Method 5/OTM-28 Solid and condensable

particulate emissions were also measured in a parallel sampling train accordance with

EPA Method 5, coupled with a back-half analysis in accordance with EpA Other Test

Method 028.

4-1-6.1Sampling Train Description Figure 4 shows the major components of the

Method 5/OTM-28 sampling train. A heated stainless steel probe with a Teflon (TFE)

liner was used to withdraw the gas sample. The probe was heated to 24AoF j 2SoF, to

prevent water condensation. The probe was equipped with an appropriately sized

stainless steel nozzle for isokinetic gas withdrawal. From the nozzle and probe, sample

gas was pulled through a heated glass fiber filter, maintained at248oF !25oF. After the

filter, the sample gas passed through a water-cooled glass condenser (capable of

cooling the stack gas to between 80 and 85o F) and a series of glass impingers. The

first two impingers were initially clean and empty. lmpinger 1 was a condensate dropout

impinger without a bubbler tube and lmpinger 2 was a modified Greenburg Smith

impinger. The sample gas then passed through the CPM Teflon filter and subsequenily

passed through the moisture traps. The moisture traps consisted of a modified

Greenburg Smith impinger (lmpinger 3) containing 1OO ml of water followed by an

impinger (lmpinger 4) that contained approximately 200 grams of silica gel. The

moisture trap impingers were maintained in an ice bath to keep the gas temperature

below 680 F at the exit of the impinger train.

4.1.6.2 Sampling Train Operation Sampling was done in accordance with EpA

Method 5 procedures and specifications, including leak checking, isokinetic sampling rate

and stack traversing. Sampling was conducted for 5 minutes at each of the 24 traverse

points (see Figure 1). Each test run had a duration ol 120 minutes, excluding the time

required to change ports. As required by [Regulatory Reference], a sample volume

of greater than 60 dry standard cubic feet was acquired during each sampling run.

14

Glass nozzle

Condenser Thermocouple

Heated glass-lined

with coolant

water CPM Filter

stainless steel

Stack

I L rn"rrocoupte

Pitot tubes

(type S) lnclined

manometer

Recircu at on

Pump

Empty Water Silica

gel

Vacuum

line

Thermometers ,/\

lnclined

manometer

Dry gas meter Vane pump

Heated

quarz or

fiberglass

filter ì

Figure 4 - EPA Method 5 / OTM 028 Sampling Train

15

4.1.6.3 Sample Recovery and clean-up The probe and hot filter were

disconnected from the condenser and impinger train and a post-test purge was

performed with ultra-pure Nitrogen. The short stem impinger insert of lmpinger 1 was

replaced with a modified Greenburg Smith impinger insert. The impinger tip extended

at least 1 cm below the surface of the water. lf insufficient water was collected, a

measured amount was added to the dropout impinger. The amount of water added was

recorded to correct the moisture content of the effluent gas. The purge was performed

with the impinger train connected to the meter box. The purge was performed for 60

minutes at.the 

^H@ 

of the meter box with a positive overflow rate of less than 2

liters/minute.

Sample recovery proceeded as follows:

Front half acetone rinse: Recovery of the Method s sampling probe was

accomplished using a Teflon-fiber probe brush. The nozzle, probe and front-half

filter housing were rinsed with acetone at least three times each and brushed

between rinses.

Filterable particulate filter: The hot filter was recovered into a Petri dish.

Aqueous Liquid lmpinger: The liquid from the dropout and impinger prior to the

CPM filter was measured and transferred to clean glass or plastic sample botfle.

The condenser, lmpingers 1 and2, connecting glassware, and the front half of the

CPM filter housing were rinsed twice with water. The rinses were collected into the

same bottle, Container 1.

GPM organic Rinses: After the water rinse, the condenser, rmpingers 1 and 2,

connecting glassware, and the front half of the CPM filter housing were rinsed with

acetone, followed by two rinses of methylene chloride. The organic rinses were

collected together into Container 2.

CPM Filter: The filter was removed from the CPM filter housing and placed into a

Petri Dish.

Gold lmpinger Water: The volume of the contents of the cold water impinger

16

1

2.

3.

4.

5.

þ.

was measured onsite and discarded.

7. SilicaGel: The silica gel was transferred back to its original container and

weighed.

4.1.6.4 Blank The blank was a sample of reagent-stock acetone collected during the

test program, and analyzed in the same manner as the actual stack-test samples.

4.1.7 Gondensable SO3/HzSO¿ Sampling - EPA Method CTM-0138 Condensable

materials consisting of SOs and HzSO+ wêrê measured using EPA Conditional Test

Method 0138.

4.1.7.1 Sampling Train Description Figure 5 shows the major components of the CTM0138 sampling train. The system consists of a high temperature quartz probe, a high

temperature quartz filter, two impingers containing 100o/o isopropanolsolution, an unheated

filter, two impingers containing 3% hydrogen peroxide, and a silica gel impinger. The probe

was heated to approximately 400'F and the filter to approximately 500"F in order to prevent

the condensation of any SO3 and/or HzSO¿ on the filter, while still trapping non-sulfate

particulate matter. Any SO3 / HzSO+ was collected in the first impinger and on the

unheated filter. Any SOz that may be present in the gas stream passed through to the final

two impingers containing HzOz.

4.1.7.2 SampleTrain Operation The CTM-0138 sample train was operated at an

isokinetic sampling rate, at a fixed location in the stack. Testing was performed over a

period of 120 minutes, simultaneously with the particulate sampling discussed in the

previous sections.

4.1.7.3 Sample Recoveryand Clean-Up Theprobeandfronthalf ofthefilterholder

were rinsed with 100% lPA, and the quartz fìlter was added to the sample jar containing the

17

rinse material. The contents of the IPA impingers were placed in a sample jar, and the

impingers, as wellas the back half of the heated filter holder and the connecting Teflon line

were rinsed with 100o/o lPA, with the rinses added to the same sample jar. The unheated

filter was placed in a separate sample jar containing lOOo/o lPA, and the connecting

glassware from the back of the second IPA impinger to the front half of the unheated filter

holder was added to the sample jar. The contents of peroxide impingers were placed in a

sample jar, and the impingers, as well as the back half of the unheated filter holder and

connecting tubing, were rinsed with Dlwater, with the rinses added to the same sample jar.

The silica gel was recovered into its original Nalgene botfle.

4.1.7.4 Blank The blank was a sample of reagent-stock IPA collected during the test

program, and analyzed in the same manner as the actual stack-test samples

4.2 AnalyticalProcedures

4.2.1 Molecular Weight Determination - EPA Method 3A Flue gas compositional

analysis for molecular weight determination was conducted using instrumental analyzers

set up and operated in general accordance with EPA Method 34. The instruments were

calibrated before each analysis with EPA Protocol 1 calibration gas standards. Each bag

was analyzed in triplicate and the average flue gas composition used for calculation of gas

volumetric flow rate.

.4.2.2 Moisture Gontent - EPA Method 4 Moisture contents were determined

gravimetrically in accordance with Method 4 by measuring either the volume or mass gains

of each impinger in the pollutant sampling trains.

18

Glass nozzle

I

/ Heated glass-lined

/ stainless steel probe

Heated Teflon Thermometer

line

Stack

Thermocouple

igh Temperature

Pitot tip Filter

lnclined

manometer

100% isopropanol 3o/o HrO, Silica Gel

Vacuum

line

Thermometers ,/\

lnclined

manometer

Dry gas meter Vane pump

=l

Figure 5 - EPA Method CTM-0138 Sampling Train

19

4.2.3 Gondensable Particulate Analysis - EpA Method 202 The total

condensable particulate matter in the back half of the sampling train was determined in

accordance with Method 2O2 procedures. The impinger contents and aqueous rinses

were combined with the methylene chloride rinses and extracted twice with methylene

chloride using a separatory funnel. The sample was divided into organic (methylene

chloride) and inorganic (aqueous) fractions. The organic fraction was evaporated at

room temperature and pressure, and the resulting residue was analyzed gravimetrically

to a constant weight.

The total condensable particulate matter in the back half of the EPA Method S sampling

train was determined in accordance with Method 202 procedures. The impinger

contents and aqueous rinses were combined with the methylene chloride rinses and

extracted twice with methylene chloride using a separatory funnel. The sample was

divided into organic (methylene chloride) and inorganic (aqueous) fractions. The

organic fraction was evaporated at room temperature and pressure, and the resulting

residue was analyzed gravimetrically to a constant weight.

The inorganic fraction was evaporated to dryness at 105oC, and the residue was

analyzed gravimetrically to a constant weight. Since the pH of the original solution was

greater than 4.5 and the optional ammonia addition step was omitted.

The back-half condensable particulate catch was equal the organic residue plus the

inorganic residue.

4.2.4 Condensable Particulate Analysis - EPA Method OTM-28 Condensable

particulate matter was determined in accordance with EPA Other Test Method 28

procedures. The water soluble CPM was extracted from the CPM filter and the

aqueous extract combined with the contents of Container 1. The organic soluble CpM

was extracted from the CPM filter and the organic extract was combined with the

contents of Container 2. The aqueous impinger contents in Container 1 was placed in a

20

separatory funnel and extracted twice with 30 ml of methylene chloride. This organic

extract was combined with the organic train rinse in Container 2.

The organic phase extracts and rinses in Container 2 were placed in a beaker and the

volume reduced to less than 10 mL at room temperature. The beaker contents were

then transferred to a pre-weighed tin and evaporated to dryness at room temperature.

Following evaporation, the organic fraction was desiccated for24 hours, and then

weighed at 6 hour intervals to a constant weight.

The contents of Container 1 (inorganic fraction) were transferred to a clean beaker and

the volume reduced to less than 10 mL at 105oC, and then allowed to dry at room

temperature. The residue was re-dissolved in 100 mL of deionized distilled ultra-filtered

water. Titration with 0.1 N NH4OH was used to neutralize acid in the inorganic sample

and remove water of hydration. The volume of titrant used was recorded. The volume

of the aqueous phase was reduced to about 10 mL at 105oC. The beaker contents was

then transferred to a pre-weighed tin and evaporated to dryness at room temperature.

Following evaporation, the organic fraction was desiccated tor 24 hours, and then

weighed at 6 hour intervals to a constant weight. The weight of the inorganic residue

was corrected for the NH4* retained in the sample.

4.2.5 condensable Sog/HzSo¿ - EPA Method CTM-138 sample analysis was

performed using lon Chromatography with conductivity detection.

4.3 Data Analysis Equations related to the pollutant sampling, including gas flow

rates, temperatures, percent isokinetics, and moisture content are shown in Appendix C.

The test results are reported as mass rate in terms of both lb/MMBtu and lb/hr.

Emissions in lb/MMBtu is calculated using the dry oxygen-based fuel factor for

bituminous coal (9780 dscf/MMBtu), which is published in Table 19-2 oÍ EPA Method 19

in 40 CFR 60.

21

4-4 Equipment Calibration Field equipment was calibrated in accordance with the

requirements of the applicable EPA Methods, and with those recommended within the

Quality Assurance Handbook for Air Pollution Measurement Systems: Volume lll (EpA60014-77-027b, August 1977). Appendix F contains records for all the calibrations.

22

Appendix A

Test Log
TEST LOG

(Anonym ous) Power Station

(Anonymous) Stack

Run l.D. Test Parameter Test Date Start

Time

End

Time

s00-M202-R5B Condensable Particulate

Emissions

EPA Method 5/202

06/'10/09

0804 1048

s00-M202-R7B 1545 1 806

s00-M202-R8B 06t11t09 0753 1017

s00-oTM28-R5A Condensable Particulate

Emissions

EPA Method 5/OTM-28

06/1 0/09

0804 1048

s00-orM28-R7A 1545 '1806

s0o-orM28-R8A 06t11t09 0753 1017

s00-M138-R2 SO. + ¡r59a Emissions

(as HzSO¿)

SO3 + H2SOa Emissions

(as SO3)

SOz Emissions

06/1 0/09

0804 1048

s00-M138-R3 1545 1 806

s00-M13B-R4 06t11t09 0753 1017
Appendix B

Data and Results
Appendix 8.1

EPA Method 5//202 Data and Results
Run Number s00-M5/202-R5

Date

Start Time

E¡dïme

SÞck Diameter

Nozle l.D.

MeterBox Garnma ' Meûer Box dH@

Barcmefic

Cp

. Test Duration

06/10/0e

8:tÌ4

10:48

466 inches

0.240 ¡nches

0.s960

1.7414

26.80 in.Hg

0.84

120 minutes

VoluEq

Fìnal

1S1.0

120.O

100.0

5-0

lmplnger0 0.0 lmpirrgerT 0,0

300.0 4,16.0 11 t4

Metered Volume 9g.¡146 dgf V0lume@.$td.Cond. 8t.3ZS dscf

Ío Water 7.Zg Vo

% fsokinetks 94.O ølo

Vdocity 49.46 ff/sec ActualFlow 35l509tì acfm

SH- Flour E&742 úm

Std- Flor,t,

v"o2 14.00 Md 25.07 TñV¿ 3.20 Ms 28.27 0.t Ps 2t 82.8 Fo 2.

SùafÌc Meter Meter

0.63 'r.80 g4û_s28 81 78

0.74 ?_to

Temp. Prcssure Detb p Deltn H Voturne 

. . Jemp. (Ðag. Fì po¡n! _ (Þr) t¡!.!=r=c) (¡!.Eg) {in.wc) (¿cÐ --ñ¡ãr- ourä 1 108 0.37 0.57 2 107

3 106 4 108 5 105 6 108

7 107 I 108

e 108 10 107 11 110

12 10Ð

13 105 14 108

0.64 1.90 o.77 2.20 0.87 1.90 0.49 1.40 o.ff 1.50 0.54 1.BO 0.6t l.to 0.73 2_10

9.72 2-10 0.53 1.50 0.54 t.6t 0.57 1_70 a.a1 1.90 0.67 1.90 0.58 1.70 0.58 1.70

85 940.936 88 988.57¿ 8979

80

81

15 1û7 16 tû6

17 106

18 107

19 107 20 f07 21 108 22 f rl5

21 105 o.74 2.10

88 81

83 81

86 81

87 80 s8 81 8S 82 89 82 82 8l 8/.8r

85 81 87 8f 8S g2

Ð0 83

86 83 8tì 83 88 83 89 83 86 82

0.59

0.68

0.71

1.70

1.Sû

2.10
EPA ñfiethod 5//202: Gravi¡netric Data and Results

SAfiIPUNG DATA

Run number

Conected sarnple vof ume

Corr€sted flou¡ rate

02 Content

CO2 Content

sa+Msl20a,R5

81.375 dscf

2720956 dscfrn

14.0 %

3.ZVa
' Run Number sGGMs/202-R7

Date

SËart Time

End Time

SÞck Díamster

Nozzb l.Ð.

Meter Box Ganma

Metei Box dH@

BaromeÍis

Cp

Test Duration

0tr1o/gs

f 5-.45

18:06

4ö6 lnches

0.240 tncheË

o.Ðs60

1.7414

26.50 Ín.Hg

û.84

120 minutes

4 DÀTA

Volume

Final 1 100.0 210.0 110.0 lrnpínger2 f00.O 110.0 I

lmpînger3 100O 89.û -1 4 0.0 5.{t 5.t $ o.o 6 o.o

lmpiinger 7

300.0 414.0 114.0 20t.o 218.8 18-8

3 DATA

YoOZ 14.00 Md 29-2Ð

4.00 Ms 28.41 %co 0.o Ps 26.63 %N2 82.0 Fo 1.:t2s OziûOZ 18.0 %EA f8g

1-f RESI|LTS

Metered VoÌltæ SgjÊO dcf

Volume @ Std-Oond. St.S13 dscf %Water T.OS %

% lsokindics 95.6 %

Velocrþ 49.44 frlsec

Aclual F[ow BE13l61 acf.n

SH- Ffow 2Bg87Bô scfrn

Skl. Ffow 2OS32l1

Temp. Pressure DelH p llelh H Volume Temp. (Deg. F)

. 

point (pgsJ) fi?.Yc) (in,rwc) (in.w0l ldqÌ. J;iA-- oud€r 1 109 0.41 0.56 1-00 s1-844 73 72 2 707 0.37

3 107 0.40 4 108 0.38 5 106

6 108

7 f08 I 108

107

109

0-82 1.80 0.5s 1-70 0.84 1-90

0,89 2.û0 o.7s 2.20 0.52 1.50

Meter

127.716 76 73

77 73 127.875 78 73 175,837 7S 73 80 73

76 74 79 74 7S 74 80 74

81 77 g2 75

T5 74

73 74 T7 74

77 73 77 7? 7Ð. 73

76 73 80 74

81 74

I

l0

11 108

12 105

t3 108

14 108

15 105

tE 1û6

1T 106

18 los

19 1Ð7

20 10s

21 1û6

22 1û8

23 lû9

0.57 1.70 0.4s 1.40

0.66 1,90 0.6ã 1.90 0.ô3 1.80

0.55 1.60 9.57 1.70 0.64 f .s0

0_s9 1.€0 0.63 l_so 0.64 l.g0 0-69 2.10 o.75 2'¡A

0.67 1-S0

0.63 1.80

. o.5g 1.80

81 74

M74

AVG. 107 0.39 0.63 1.86
EPA MethodSl2O2: Gravimetric Data and Results

SAMPL]NG DATA

Run number

Conected sample volume

Corrected flow rate

02 Gonteflt

CO2 Content

s0fr.M5f202.R7

81.913 dscf

2693211 dscftrt

f{.o %

4.0 vo

Gorrected to7% 02 {gr/dscf)

Conected to12V, COZ (gr/dsc'f)

0.0100

o.4202

0.0301
Run Number s00-M5r202-R8

Date

StartTíme

End TÍme

Stack Dlameter

Nozle l.D.

Meter Eox Gamma

, MeterBox dH@

Baromeüic

cp

Test Duration

06/11¡tg

7:53

1O:17

466 inches

024O ínúes

0.ss60

1.7114

2û.50 in-Hg

0-84

12O minutes

4 DATA

Volqme

lnltlsl Fhd

I 100.0 204.0 1

lmpinger 2 100.0 110.0 10.0

lmpinger 3 100-0 9õ.0 4

4 0_0 2,A 2.0 5 0.0 ô 0.t

7

300,0 412-A

METHOD 1-4RESULTS SiHca

lvletered Volumg 96.628 dcf

Volume@ Std.Cond. 83321 dçtf

% Water 7.12 %

% lsokineiics S6-6 %

Velocity 49.64 ft/sec

Act¡af Flot¡v 3527ffi4 acfm

Std- Flow 2920885 scfm

SûC- Flout 2712829

3 DATA

14.00 frrd %coz 320 t/ts %CO 0.0 Ps

%NZ 82.8 Fo O2+@2 17

2S.07

2828

26.53

2.156

178

Stack Stattc Meter

1.90 238.2æ 76 72 230 79 73

2-1t 234.463 83 75 285-931 85 7B 87 77 83 78 86æ

89 B0

90 81 90 t2

91 83 85 82

87 82

89 82 90 82 90 82 s0 83 83 81 8ô 8t 8¡ 81 87 8{

87 81

Temp. Preszure Della p Delta H Volume Temp. (Deg. F) polnt. ._ (o.eg.F) t¡!.Lïc) , (itÏtc) .l¡n_wct {ocÐ Tter--lõrü-E- 1 104 0.36 0.ô2 -

2 103

3 107

4 1t4 5 103

€ 110

7 107

B 106

I 1r)6

10 105

11 10Ë

12 104

13 f04

14 108

15 107

o.41 0.63 432 0-78 0.3s o.72

17' 106

18 103

19 105

20 '105

21 104

22 1AB

23 107

24 103

0.63 2.5Ð 0.81 2.40 0.58 1.70 0_e+ 1.90

1.70

f -s0

1.90

2.10

1.50

o.54 1_70

0.61 1.90 0.60 1.S0 0.54 1.70 0.66 2.00 0,53 1.60 0.59 1.80

r.60

1-Sû 0.67 2.10

0-58

0.an

o.63

0.6s

0.49

16 106

o.ffi

0.63

gl5 z.ffi 90
EPA Method SI202: Gravimetric Data and Results

SAMPLING DATA

Rr¡n numbel

conected sa rnple vol ume

Conectedflowrate

O2 Content

COz Content

s0trM5f202-R8

83.371 dscf

. 271Æ?:9 dscfm

14.O alo

3.2Vo
AppendixB.2

EPA Method SfOTltI-z8 Data and Resulte
Run NumbEr S0O-MOTiilz8-RSA

Date

Start Time

End ïme

StäÊk Diameter

Nozde l.Ð.

l¡leter Box Gamma

M6têr Box dH@

Barometrh

Cp

TeÊl Duration

00/10/0s

8f4

10148

4ß6 inches

0.240 incf¡es

0.s950

1-7431

26-80|n-Hg

0.s4

120 minutês

4 ÐATA

1 0.0

0.0

100.0

Final

67.0

30.0

123.0

67

lmplnger 2

fmpinger 3

lmpinger4

5

o

7

100,0 220.0 1

LTS Silica od lol 200.0 233.0 33-0

MeÞrcd Volume 90.410 dcf

Vohme @ Std.Cond. 78.670 dstt

% waær 8.3S %

% lsokinetfrx 912 çÃ

Velocily 49.92 fl/sec

Actr¡al Flor 3317829 aÉftr

Std. Flow 2958810 scfrTr

27105&f dscfrr¡

3

14.4 Md 2s.

VêCO? 3.50 Ms V"Cö 0.0 Ps

A2-1 Fo 1.857

17.9 %EA 1

Statiê

Prêssurc

MètÊr Meter Volune Temp. (Deg- F)

StâËk

Temp.

lDesE

108

Point

1

Delb P

2

3

4

5

6

7

I

I

1{t

11

12

t3

14

15

16

17

18

19

20

21

22

23

24

109

108

107

108

f09

104

107

107

107

106

106

f08

108

110

109

10s

108

108

107

100

107

147

108

0.70

0.85

o-82

0.80

1.ûO

0-56

0-60

0.õ5

0.87

0.70

û.65

0.56

0.s3

0.54

o.56

o.50

0.61

0.õ0

0.61

0.54

0.G5

0.67

0,67

2.Ð0

f -90

2.,{O

2.30

2.9O

t.60

1.70

1.90

1.90

2.æ

1.S0

J.60

1-50

1.50

1.60

1.fl)

1.80

1.70

1_80

1.50

1.90

l.s0

1.90

75

7B

77

78

78

7S

7S

7g

80

80

80

80

80

81

t1

B1

81

82

82

83

82

83

83

w

79

83

86

88

88

88

82

84

87

88

89

8ft

u

86

87

88

89

st

gr

88

89

8g

8S

so

0.40

0,37

751.215

751.455

795_950

108 0.37 0.65 t.86 so.410 u
Run Number s0fÌ-MoTtt¡!?8-R7A

Dde

StartTime

EndTinre

Stack Diameter

NolzlÊ l.D.

Meter Box Gamma

Meiler Box dH@

'Ba¡omebic

@

Test Dt¡ration

06/10/09

15:45

18:08

466 inches

0.240 inche6

0.9950

1.7431

26.50 ií.Hs

0.&t

120 minutes

A

Volume

I

lnilial

0.0

0.0

1ül_o

72.0 72.

lmpinger2

lmpinger 3

3.0

11S-0 rS.0

4 0

lmpinger5

lmpinger6

7

Total 100.0 1s4.0 94.0 200-0 233-7 ?3.7

Metered Volume S3,T1Z dd

Volume@ SU.Cord. g0.TBg d€sf %Waær 6.sg %

% fsokhetics gZ.B Vo vefoctty so,s3 fl/sec

Arü¡al Flow 35909f!D acfrn

Sld. Flørrr 2956f2t scfr,n

3 DÀTA

14.00 Md 2S.1t

3.90 ME 28.41 O.0 Ps 2t 92.1 Fo 1.

7A

78

78

7g

81

BO

80

8û

80

8û

B1

80It

8l

80

80

80

79

t0

80

80

80

8t

82

8$

85

86

87

84

s6

87

87

8T

B8

83

85

85

85

86

85

83

85

s6

88

89

90

.2

3

,4

5

G

7

I

s

l0

JI

12

l3

14 '15

18

17 .f8

l9

20 .21

'4.> 4

'29

24

108

108

1ûS

107

108

107

107

107

108

11Ð

109

r08

r09

,1û

t0E

110

1f)9

t1û

109

110

110

110

109

0.41

t.35

0.39

0.70

0.80

0.73

0_80

0.80

0.60

4.73

0.65

o.65

0.80

û-s5

0.55

0_5€

0.56

0.54

0,05

0.63

0,56

0.60

0.60

0.65

0.70

0.70

2.00

2Ã0

2.1A

2.40

2_40

1.70

2.O0

r.90

1.9û

2.40

1.90

1.60

1.60

1.øt

f .80

1.90

1.S0

1.7t

1.8{¡

r-80

2.O0

2.10

2,1D

957.049

æ7.247

1ffÌ2.860

AVG. 10S o.tt 0.66 r-94 9.3-712 83
Run Number s00-MoTM28-R8A

Date

Startïme

Endïme

Stack triarneter

Nozzle LDMeter Box Gamrna

MeterBox dH@

Barpmeûb

Cp

Test Brration

06/fi/09

7:53

10:,17

466 lnches

0.240 incheÊ

0.9e50

1.7431

26.50 in.Hg

0-84

12O mlnutes

METHOD4 DATA

YolurTtê

F¡nâl

lmplr¡gsr 1 0.0 83.0 2 0.0 2.o 3 100.0 11s.0 1

lmpingêÌ4

lmpinger 5

lmplnger 6 0.0

7 0.o 'otaf '100.0 zOt.O

Silíca ael fq) 200.0 230.5

MstÐr€d Votuma 95-325 dcf

Volwne @ Sffi.Cond. 81.818 dscf

%Watff 6.99 %

% lsokinetics 54.2 %

Velocity 49.80 füseo

Acluâl Flow 35û9223 ärfrfi

Std- Flo¡¡ 2363343 scfrn

2728978 dçsfm

1420 Md 2S.0{ 3.1O Ms 28.æ û-û Ps 26.53

B2:t Fo 2.181

17-3 dl"EA 1

Stâck $taüc MeÞr Temp. Preesure Delta P D€¡ta H VoJume Temp- lDeg. F) PoÌnt (DegF) 

.,., 

(i!.w_c) _ {¡n.WÇ} (in-WC) (dcf) lnl4 Otid€t I lto 0.39 0.65 2.00 14.805 77 7s

106 0.4f 0_60 1.80 80_975 82 74

3 101 0-37 0_M l.so

4 102 5 103 6 104 710/. I 103 I 106 10 142

11 r03

12 lM

13 105 14 107

15 105

t6 10€ 17 107

18 J04 19 105 20 ,l05

21 105

22 106 23 107 24 105

0.45 1.4D

0.60 1.80

86 75

61.'185 88 78

110.3¡t0 8S TT

90 Tl

85 T7

89 80 gl 81

92 82

92 83

s2 83

8784

90 84 s2æ 92 84 s2 85

w85

87 84 8Sæ

90 84

91 84 9f 84 9ru

0.4fr 0.65 2-ùo 0.70 2.10

0_80

0.50

0.52

z_40

r.50

1.60

0.50

0,60

0.5s

0.60

o_70

0.65

0.70

1.70

1.90

1.80

1.90

2.20

2.00

2.20

0_70 2.20 0.å5 2.00

0.60 1.so o.70 2.20

o.70 2.20 0.75 2.30

0.80 2"ffi

AVG. 105 0.40 0.û+ t.s8 95:''8 85
Appendix 8,3

EPA Method l3B Data and Results
Run Number s004Tlti[138-R2

Date

St¿rt Time

End Time

Stack Diarflster

Nozzle l.D,

Meter Box Gamma

túøterBoxdH@

Barometic

Cp

Test Durât¡on

0d1O/tS

8S4

1O:¿ftÌ

¿166 Ínches

0.240 inches

1.02Ê4

1.7246

26.50 in,Hg

0.M

120 minutes

i/IETHOD 3 DATA

14.ffi Md oÃCOZ 2.80 Ms 28,

%CO 0.0 Ps %t\¡2 82.7 Fo

4DATÀ

lmpingerVolume

lnitial F¡nâl

lmpinger I 657.9 686.5

2 783.5 785.3 1,8

3 602.9 628.6 2'5.7

4 835,0 876.5 41

lmpinger 5 0,0

lmpingêr 6 0,0

7 D.0

2879.3 2978_9 S7

1.4 RESULTS

MeÞredVoluma 100.4f]4 d0f

Volume @ Std.Cond. S1.738 dscf

%wars 6.58 %

% lsokinetics 99.3 %

Velocity 53.4iÌ rus€c ÄctualFlow 3797181 únt

Std. Flor¿ 310833{l sún

Flo,¿ìl 2SO385S dscfrn

Stãck Shlic Ms,ter

Temp. FrBssurs Deltâ P Delta H Volume Teflp. (Dsg. Fì

Point (DeeF) (in.WC) (in.WC) (in.Vrt0) (&D lnlqt otilet

1 111 0.32 0.80 2.30 830.793 67 67

2 112

3 1f3

4 1',|2

5 112

ö llÛ

7 112

I 113

0.75

0.70 2.00

o.7Ð 2.00

0.70 2.OO

2.20 931.197 ö7 67

0.70

o.71

0.71

0-71

2.00

2.10

2.10

2.19

2.00

2.10

2.10

I

10

tf

12

13

110

112

112

1f1

112

66

oÐ

67

67

67

68

68

G8

68

68

68

67

67

SB

67

68

ôE

88

6g

69

70

70

70

89

68

68

08

09

14 113

15

l8

17

18

113

1f0

112

111

ra 112

n 113

21 172

22 112

23 111

24 112

0.70 z.EA

0.75 220

0,75 2.24

0.75 2.29

0.70 2.00

0.70

0.73

0.73 0.75 220 0.75 22Ð o-72 2-10 0.72 z,to o.Tz 234 0.75 220 0.75 2.n

70 ô8

79 69

E8 63

Bg 68

7t 68

7n 68

72 Tg

72 7t

AVG. 112 A32 0.73 2.11 100rO4 68
Run Number s004TMf3B-R3

Dab

Start Time

EndTime

Stack Dfame,ter

Ftozzle l.D. ' Meter Box Gâmma

Meter Box rlH@

Baror¡ætrlc

'Cp

TestRrraüon

06/10/09

15:45

18:G6

4G6 ínclres

0.240lndres

1.0264

1.7246

26.5û ln.Hg

0.84

120 minutes

METHOD 4DATA

Volurne

lnitial Flnal

fmpirper I 660.7 692-g

lmpingerZ 767.7 7m-T

lrnpÈ1ger 3 689.0 703.3

4 824.6 860.3

5

lmpinger0

32.2

12.fr

14.3

3sJ

0.0

7 0.0

2942.D 3036.2 54.2

IIETHOD I4RESULTS 200.0 240.3 40.3

MeteredVolwne 1A2.217 dú

Volume@ Std.Gond. û2-622 dscf

%Waler €.41 %

% lsokinelics 10ü.3 96' Velocity 53,36 fr/sec

,Achlal FloË' 3791701 åcfrn

SH- FTow 3102466 scfrn

2903657 dscfm

IIETI{OD 3 DATA

,i/6o.2

%w¿

96co

14-00 tLtd

4-00 Ms O.0 Pg

82.0 Fo

2S20

28_48

2t-53

1.725

$acf(

Tefltp.

StatÌc

Prsseure Dsltg P

o.70 2.00 0.70 2.00 o.71 2.1A

o.71 2-10

Meter

Volume

1055.694 72 71

72 71

73 71

Defta H

Point , ,(ÞegF) (in.Wt) (ín.WCì (in.WË) (dcfì lnlet Outlat

1 112 0.37 0-7s 2.20 953.477 73 72

.21133 f13

4 112

5 110

6 112

7 113

I 113

s 111

10 11?.

11 112

17

18

'fs

113

112

1fi

0-73

o.72

D_72

0.75

2.14

2.10

2.10

2-20

74

7E

74

74

74

75

75

76

74

73

73

73

74

75

71

70

71

71

71

71

71

71

t?

71

71

77

70

70

o,71 2.1Ð o.70 2.00

0_70 2_þ0

0.73 2.10

t.73 2.10

12

13

113

110 14 112 r5 112

16 111

o.73 2.10

o.75 ?.20

0.76 2.20

0.75 2.2ô

. 0-7s 2.20

75 71

2t 113 7Ê 71

21 112

?2 715

23 113

24 111

0.75 2-2t

0.75 2.20

0.75 2.20

71

71

71

12

7€

78

79

79

0.73 2.lD 0.7s 2.1s

Meter

A\fB. 112 0.37 0-73 2.12 1t2217 73
Run Number $oo.cTñ/il38-R4

Dale

Süart Time

End rime

Stack Dlsmeter

Nozzle l.DMeter Box Gsmma

Meter BoxdH@

Bamnæûic

tp

Test Duration

06/11rcS

7:53

10:17

4€6 inches

0.2¡t0 inches

1.0264

1.724ts

2S.50 in.Hg

0.84

12O minutes

4 DATA

Volunæ

lnitial

I

2

660.7 698.7

mplruerS

7M,9 754.S -10.3

700.4 7333 33.4

813.6 861.7 48,1

0.0

0.0

lmpinger4

lmpirÐer 5

Implnger6

ImpingerT

otal 2S39.6 3&ff8.8

iIETHOD I.4 RËSULT$ 22ß.4

Metered Vdume s9.5Ð7 dof

Volume @ Sld.Cond. 90.150 dscf

% $rfaler 6,71 Vø

% lsokinelhs S8.8 %

VeH:Íty 52.87 ft/sec

ActualFlow 3757019 acfrn

Std- Flor¡r/ 3075795 sútn

dscfin

METHOD S DATA

VoAZ î4.00 Md A

VuCO? 3-Oû Ms

Vnæ 0-0 Ps

%N2 83.0 Fo

Temp.

110

11?:

112

113

111

112

111

112

t13

111

112

112

111

112

112

113

111

112

110

113

172

112

111

113

o.74

0_73

0.70

0.70

o-70

o.75

0.6s

0.70

0.75

0.70

0.70

0.70

0.70

0,70

o.72

o.T2

l.7i

0.7t

0.70

r-71

0.71

0.71

o-70

2.10

2.ßA

2.00

2.00

2.fr

2.00

2.m

2.n

2.ffi

2-OO

2.00

2.ffi

2.00

2.10

2.10

2.AO

2-0€

2-00

?.10

2.'lo

2.70

2.ffi

Pressr¡re Delta P

0.30 67

ö7

67

6T

68

68

69

70

70

7"1

71

72

72

73

73

73

73

73

73

74

73

73

74

g9

70

70

tz

73

72

75

7ö

7t

7A

78

75

TI

T?

78

78

7s

TI

TT

73

79

80

80

2

3

4

5

6

T

I

I

10

11

12

.13

14

15

l6

17

18

19

n

.21

22

23

24
Appendix C

Equations
EPA METHODS 2-4 CALGULATIONS

Metered Gas Sample Vofume at Standard Conditions

2, Gas Volume of Water Vapor Gollected in lmplnger Liquid

V *q",0) : ( v ¡ - v¡ ) x 0. 04707

Gas Volume of Water Vapor Collected in Silica Gel

V,¿ñtd) : ( w¡' w¡) x 0.047 I 5

Moisture Volume FractÍon in Flue Gas

B*: Yd'ro)*V,weþtd)

T wcþtd) * T úne6¡q I V nßu)

5. Moísture Volume Percentage in Flue Gas

g6HzO: Bn" x 100

Absolute Pressure of Flue Gas

P": Ps* P"uu"

13.6

7- Nitrogen Content of Flue Gas

g6 Nz: tOï -(z6COz+9óOz+%CO)

Drf''Môlecutar Vüeight of Flue Gas

Md:0.44 x%CO2+0.32 xoz6Oz+0.28 x(% Nr+%CO)

Wet Molecular Weight of Flue Gas

M,: M¿ x(I - 6þ+ 18 x 3n

1.

e

4.

6.

8.

o
EPA METHODS 2-4 CALCULATTONS - continued

10. Fuel Factor Based on FIue Gas Composjtion

^ _ 

20.9 _96O¿

n "-- %cor11. Excess Air of Flue Gas

o/oEA: - r,.?ot-o.t*co *roo

0.264% Nr-(%Or-0.5%CO)--- - -

12. Average Gas Velocity, ft/sec

y,: 85.49 x C e x ( Lp* ),"r rffi

13. Area of Round Duc,t or Stack

lrxD2 A": i- ftound ducts) 4x144 \ 

'

14. Area of Rectangular Duct

, A,: -Lxw -l7T (rectangular ducß)

15. Actual Volumetríc Flow Rate of Flue Gas

Qo:vrxA"x60

16. Flow Rate of Flue Gas at standard remperature and pressure

o :o *l . P"*sza I !s +a 

l¡y"+460)x29.92 l

17. Dry Flow Rate of Flue Gas at Std. Temperature and pressure

e,¿= e, rc (I - B*)
NOMENCLATURE FOR EPA METHODS 2.4

As = Stack area,ft2 B,ns = Moisture volume fraction Cp = Pitot tube coefficient (S-type=0.84, Std.=0.99) Ds = Stack diameter, inches

^H = Average meter orifice pressure, in.W.C.

^P = Pitot tube differential pressure, in.W.C. Fo = Combustion factor

T = Meter calibration factor, garnma L = Length of rectangular stack or duct, inches Mo = Ðry molecularweight, lb/lb-mole M" = Wet molecularweight, lb/lb-mole Pa = Barometríc pressure, in.Hg P" = Absolute s,leck pressure, in.Hg

Qa = Actual gas flow rate, acfm Q" = Standard gas flow rate, scfm Qr¿ = Dry standard gas flow rate, dscfm T, = Average meter temperature, oF

Ë = Average stack temperature, oF

V¡ = Final impinger volume, ml

v¡ = lnitial impinger volume, mf Vm = Unconected metered gas volume, dcf Vm(srd) = Conected gas volurne, dscf

vs = Average gas velocity, fr/sec

Vy,¡qsta¡ = Gas volume of water caught in impíngers, scf

Vwss(srd) = Gas volume of water caught in silica gel, scf W = W¡dth of rectangular stack or duct, inches W = Final silica gel mass, gnams

W = fnitialsilica gelmass, grams o/oO2 = Dry.volumetric concentration of C'2, olodv o/oO,Oz = Dry volumetric concentration of COz, %odv o/oCA = Dry volurnetric concenüration of CO, %dv o/oN2 = Dry volumetric concentration of Nz, Todv %EA = Percent excess air
EPA MËTHOD 5 GR.AVIÍVIETRIC CA.LCULATIONS

1. PM Gollected in Probe Wash - Mp*

Mp* = (Wp*lm"t - (Wr*)t"n

2. Applicable Acetone Blank Correctiof, . B.o*

B.p, = l(w"u)r,n,t -(w"àr"*l " E

3. Maximum Allowable Acetone Blank - B",no

B"*u = 0.TB4E x 0.00001 * vo*

4. Actual Probe Wash Blank Correction - Bp,n

Bo* = 

^ilNIMUM 

lB+*, B"rul

5. PM Gollected on Filter - M,

Mr=(W¡)nrr*(Wr)r"n

6. Total PM Gollected for Method 5 Galculations - M,

Ms=Mr**Mr-Bpn

NOMENCLATURE

8,'n"* = Maximum allowable acetone blank correction, based on weight of

B"o* = ä::',:i: il,iíii?#ååf¿nnff3o on residue or brank, srams Bo,u = Acetone blank correction actually used, grams M5 = Total mass of particulate in train corrected for acetone blank, grams Mr = Mass gain of filter, grams Mo", = Probe wash residue, grams

va¡ = Liquid volume of acetone blank, ml vo* = Liquid volume of probe wash, ml (W"¡)nn"r - Finalweight of beaker containing acetone blank residue, grams (W.¡)a," = Tare weight of beaker containing acetone blank residue, grams (Wr)nn"r = Final weight of filter, grams (W),",, = Tare weight of filter, grams

(Wp*)nnar = Final weight of beaker containing probe wash residue, grams (Wo*)** = Tare weight of beaker containing probe wash residue, grams
PARTICULATE EMISSIONS CALGULATIONS

1. Particulate Concentration - C*o

lar¿-=z(M) x Tooo è-(¡ V-(t'o) 453'593

2. Particulate Concentration Gorrected to7olo Oz - C=a@74/oO2

csd@7ro = c"ax#ffi

3. Particulate Goncentration Corrected to 12o/o CO2 - C*.@I2VICO2

C*@t,rro = Cr¿x #,

4. Particulate Goncentration Corrected to 50% Excess Air - C"d@S0%EA

csd@.ov"EA = c*dx g#

5. Particulate Mass Rate - Mo

*r=Hx Q"¿" *#*

6. lsokinetic Variation - o/olSO

ot_,^^ _ 

0.09450*(I" * 460)xVr,",,

prX vsxAax timex (1 - 8,"")
PARTICULATE EMISS|ONS CALGULATTONS (continued)

NOMENCLATURE

An = Nozle area,ft2 B'* = Moisture volume fraction Csa = Particulate concentration, grains/dscf Dn = Nozzle diameter, inches )M¡ = Summation of PM collected in sample train, grams Mp = Mass rate of particulate emissions, lb/hr Ps = Absolute stack pressure, in.Hg Qsd = Dry standard gas flow rate, dscfm time = Net sampling time, minutes Ts = Average stack temperature, oF

Vm(std) = Corected gas volume, dscf v5 = Average gas velocity, ftlsec YoOz = Dry volumetric concentration of C,2, o/odv

VICO2 = Dry volumetric concentration of COz, Yodv o/oEA = Percent excess air %olso = Percent isokinetics
Appendix D

Raw Field Data
A

ú?.r4

FACIUTY:

srARrrMeE0f =*"rÈE- polLr.trArrrr; Pn

lsoKttËTl

ÎEST LOCATÍON:'

. cilAtNoFcusr@Y:

(ruNrÂrNt

R SAfi¡PTC ID. DESCRIFTlON

I

z

J 3u< fVo*If-iro

u ?ryÃffi fJltl-h-""

v

LEAKCI{EG¡*

VACUUM Tç" 15" f f-t f ôi,

RÂTE ,ùaj -6Ð3 .æt ,ûF
TEST I-0CATION;

ISOKINETÍ C SA¡TPTÀIG DAIASHÉHT

**r,*' i545 e¡pnr¡rrl6' l- eou.wmr: --- F,/,? Rt)Nt.È.t!oqN,þ-rR18

*u*a*, f

LEATCC}IECK

CONÍA¡æ

R SÁl,Ff.E l.D, ÐËscRrFïosû

I

z

4

i) 3io frr./i E"-

ü .'4r I tl. óur,æ

VACUUM il" Ior loD

8¡1TE ,ñ4 . ôa5 ,6Ðtl

NOZLEM k3 .]¿t

PITOT# Q,lq

BOXI.Þ, 7

GAMIIIA I LqaËt

ellÉb t -? t4tq

Fm &,(

FILTER h1 -'00

TECH. J I.L
k= 3,!

FACIUfi: ST LOC.ATIff.I:

srmrn¡æ: o79? - olonn¡e lo i ? pöturrnr.rr:

öHEC|C

VACUUM l5'r tÞ" fo ìt

RATE .oÐ11 ,tô3. . a03

NOZLEM kl .l¿t

PITOT# 4"1

BOXt.D. '7

GAMIj'Å( ù+l(Õ

elltfìl l.'t4t4

P".o il-,r

FILTER 01*'àE

TECH. -J R{
Append¡x D.2

EPA Method 5fOïM'28 Raw Field Data
MEI,HOÞ æ tsqlcNEnc sÂIr{pLtNG pÁTA SHEET

-TESTLGAIION:

P"* 7t-'{ FOI"I-tJTÂ¡Íf: 1'P ,4

P,{C{ OF

DATE: /lr*¡rt-æ

ptuvt.D.:fut -uQÆ"aSA-

*{
lL t. PAGE_ OF_

j,(,Ç POLI-UTA¡rIT: 1fA RUNI.ù.t#va -tù\ffiR'lL rrctlNtcl¡N{L
I,IETHOÐ 23 lSOl(lNETtC SAMPL|NG DATA SHEET PAGË-OF :

.TE$rLocA-îo*- I7 D^rE: Á*//-éf 

-. 

,.

re*r¡rcnr¡ .ff-JrL p*^ Zi Ç POLLUTAIIT: C-P -H. .. .-- _ RUN t.Dj -æ -ÃkdttJt|S&ed

ÒA

7

21

z

tc
Appendix D.3

EPA Methqd 138 Raw Field Data
TECHHIcIAN bW Ps E pou-urn¡n: C. ¡nLrol C¿ad¿+#r

\

.. PAGE I OÉ--

RUN l, Þ.:Sq-jfi¿l3$-:¡- â

NOZZLE M =Èq BS

PlïoT# t3J

BOXID tl

GAIfif'rAl t.sJ6fl

eH@ I rr*û

,,PROBË ID Ft tb: I

SYSTEM ID ? 'ttuq lt4*

FILTER ID Urútáa¿rr
PAGE '.QF¿

D|ATE: ôqr ft__¿g_

. nuur.o.r lú¿ ofvrß4.¡? ïEctrurcr¡l¡ et?¡J pu^* ?*.i- pouufÂrr; f'o¡t ¡l C¡-al"zæ¿,Ér'

tJ

NOULEÀI î.q '85

PITOT# r3f

BOXID Íl

GA¡¡liIA f t Åq l"L+

eH@ J.-7 N}L

PROBE IÐ Pu th- |

SYSTEM ID ?rl lÌirì" 4 lun 4

FILTER IÞ

I

uilT*trn

't

,'I
Jor(

RUNt.D.tfro rÊ-M lîg -R t

.PAGE

Porrur¡Nr; Carvbwl úolul*.rqrú¿

OF CUSTOT}T

.-...., '1. lrtìtj

'':ij"l'tï;

-'-r:i::l

:,;:

NOA.E M ,&4ßs

PITOT# I?I

ErôYtfi - tf

GAMIIAf l, t ]t4

eH@ L tt 4l.

PROEE ID PL IbSYSTEM ID frtilt-f /ue a

F]LTER ID t)l¿,TêEëD
AppendÍx Ë

Analytical Data

GRAVTIH ETRIG LÂBORATORY DATA

FÍNAL BEAKËR IIY€IGHTS

JOB T,IAME:

@NTRACTI.{O:
GRAVIMËTRIG T.IEORATORY OATJT

FIHTTL BEA¡TER WETGHTS

JOB t'tAME:

CONTRACTT\¡O;

I

r
Appendix E.2

Analytical Data for EPII ll¡lehod l3B Anal¡rses
First Analytical Laboratories

ANALYSF REPORT

Mettmd CTM 13b: Sulfate

*ïr,fìfr

Reviewed and,{pproved by;

l,aboratory Manager

JuIy 13, zcÆ9

Ðo nol tryrcdnce this rqon acep in wlnle witlwut the permission of thc Iafuñory.
First Analytical Laboratories

CASH NARRÁ.TTVE

Froject#:Il Report Dafe: l3-tu1-09

Clîsnh Air Comptlqqce Grot¡p

L.,,ç,,L rlu-tËut r-.r

Samnles: +

Twelve samples were flIbmiüed for deærmination of sulfaæ by Method CTM

13b. Ttrree of these were blanls. Three day rush service was required for these

samples- AII of the sarnples rvere receivsd with custody seals intact and the liquid

Ievels marked and no apparent teakage, Afrer analysis, any remaining amounts of

the samples will be retained by the laboratory for six months and then discarded,

henaration:

These sanples did not require any preparation. The sample volumes applied

were obtained by measurement here at fhe laboratory.

Apdysis:

Sulfate was determined by lon Chromatogfaphy with conductivity detection

(rc).

Results:

The results are preseuted as total milligrams of sulfate found in the whole

sample. To convert milligrafits of zulfate ro miiligrams of SOr, muttiply the result

by 0,833. 'To convert to SO2, multiply by Û.66?. Sulfaæ rvas measurable in all of

the sanples. The highest levels found were in the hydrogen peroxide impinger

solutiür-$ which ranged ftom 165 rng w 223 mg.

Oualitv Control:

The spike recoyery (n@was within the acceptable range of 75T' ttL25'ÃAll of the samples were anatyzed in duplicate. The ending calibrations lryere in good

agreement with the initial calibrations.
First AnalytiCal LaboratOries J* (e1e)e4i2-s60?

lrzó Burning rree Dr. Chapel Hill, NC 27517 *#rJiRtr*:Ítr

Proiecr #:

: 

- Clienl: Air Complionce Gruup

-

ANALYSIS RËPORT

Report DuÌe: l3-Jul-09

Dale Received: t 0Jul-09

Totol itilligroms ín,Somple

5o¿

mg

1Ó.2

o.8l

ró5

Somple

3004

3005

' 300ó

QUAL lTY CO N TTO I SUItrtfitARY

$pike. % Recovery '9OTo
First fuialytical Laboratories

112ó Burning Tree Dr Chapel Hill, NC 2'1517

ANALYSIS REPORT

Prolect *tr lll

Clienl; Air Complionce Group

Client Proiect lD;

Report Dule: l4-Jul-09

Dote Received: l0Jul-09

Somple

3001

3002

3003

3007

'3008

3009

4000

4001

1AO2

Totol fitliltigroms in Somple

5oo

mg

r 3.9

0-3

223

r8.5

Q,4

203

1.59

0.03

0.38
SUIFATE

IC ANALYSIS RU N sufi IIIANY ANÞ C,ALCUTAilOH ÌYORKSHETÍ

Clîenft Air Complionce Group r'ni.*'||]

Dots: l0-Jul-09

MÐL = 0.1 mg,/L

Spiks concenl/n = 20.0 mg/L

907I O. Rfr-04 17 .C5 r 80 149 .6 5 I 6, I ó

907ïO.Rit-05 t.6e 96 t4.l 5 0.8I

90710.R3-Oó 3r.0ó 266 2s8.8 20 165-23

907r o.R3-04S 35,90 299.16 9lRec.= 89.896

QUÃLITY COHTROI DATA

Peok Ht, True conc.

Somple lÞ Tesf Sorrrple Peok Dil'n Totol

Clienl FAt Sol'n Volume Height Faclor mg

mg/L ml os SOa

3004

. 30{}5

300ó

SpikÊ

t'olibrotion

Blonk

Stqndond 1

- Stondqnd2

Stqndqrd 3

Stondord 4

' Regresefon $ûcll¡tirs

R Squore

Stundoñd Error

Observnlions

0.99978 lnlercept O

1.940 X Yorioble 8.33

5

0.0

84.9

ró5.2

247.5

335.4

o-0

IO-O

20.0

30.0

40.o

Regr

o.o

83.3

166.6

250.0

333-3
SUTFAÏË

I C ANATYSIS RU H gUiil¡IIIAHY AND GALC U I,AII ON WORKSH¡ ET

Clienh Åir Complionce Grcup rro¡*'Jf

Duts; l4-Jul-09

MDL = 0.1 mg/L

Somple lD

Clïenf

3t0r

3002

3003

3007

3008

3009

4000

400r

4002

FAt

907t0,R2-0r

907',to.w¿-oz

90710,R2-03

907lo.M-07

907ro.M-08

907ï0.R4-09

907r0.8-00

907ro.B-01

ç07r0.8-02

Te¡l Somple

Sql'n Volume

mg/L ml

ì 7.1ï

t-28

39.1 ó

r ó.84

1.O4

28-79

o.f9

0.33

0.77

tó3

4T

285

224

85

352

t00

too

100

Penk

Hbighr

15T,0

t r.3

345.5

148.ó

9.2

254.4

7.0

2.9

ó.8

Díl'n

Fqctor

Ë

5

20

5

5

20

20

I

5

Tolql

'mg

os SOa

13,94

o.26

223.21

't8,52

Ð.44

202.67

t.59

0.03

0.38

QUATITY CONTROT ÞATA

Cnlibrution

Blonk

Stondqrd 1

Stondord 2

Stsndond 3

Stur¡dqrd 4

Stondord 5

il,egrcssion Stotíelice

R Squorè

Stundqrd Error

Observations

Peqk Ht.

0-0

48.8

ì 03.8

176.4

264.4

348-S

True conc.

0.0

5.0

IO.O

20.0

30.o

40,0

Regr

0.o

44-1

88.2

176.5

264.7

353.0

r.99ó80

7,501

ó

lntercept

X Vorioble

0

8.82
007I0

TIIEATR COMPLI^A,NCE GROUP, LLC

Jufy 8, 2009

Firsú Analytical Laboratories

11âãBumirg Tree Drive

ChapelHill, NC 77514

(e19) s42-8S07

ATTN Sarnple Custodian :

Accompanying this letter arc sarnples frcm four (4) CTM 13b samples (3 runs

and 1 blank), We warrt you to anal¡r*e run 3, sample numberc 3004 300ã,

and 3006. The samples are to be analyzed in accordance with CTM 13b

procedures. Flease trold the rest of the samples urttilwË see the results from run

J.

These samples are to have a 3-dayTAT placed on them.

Please note the following:

+ Chain+f-Custody sheeb accompany the samples and should be

checked to ensure that any holding tirne requirements are met.

+ Please submit complete documentation for the analysis of one

single sampling run.

t Please incft¡de a narraltve stating any probletns, or lack thercol

with the sampfe processing or analyses.

Subject: CTll 13b analysis fo î33Fi"hîiiFrank Crai'ghead, QSTI

Pro¡ect Manager

endosure

Sincerely,

The Air Gompliance Group, LLG

Fnt

Ite.Àir Comptiance Group, LLC

5075Ho[insRoad

Roanoke, Vr+, 24S19

Phone; (5d0)2ó5-r9t7

Fnx: (541)265-{,1082
ÐtlT10

CHAII¡ OF CUSTODY

CONTRACTID

COt'fiRACTNUMBER 

-

M

[ 'l3

B

'ISWANTE

ID

TOI{TANER

NUMBËR

TEST

LOCÂTION

RUN

ID

SAMPI.É

TYPF \TT3LUME INITIALS DATÊ ]OMMENTS

3001 1 s00 s00.cTM13b-R2 PA FPC

FPC

FPC

FPC

FPC

FFC

FPC

FFC

FPC

FPC

FPC

FPC

tt't0/200f X

300i I s00 soo-cTf\¡13b-R2 FIller

H202

ô/10/200! X

x

300! l' so0 soo.cTMlsb-Rz 8t1 012009

3004 1 s00 s00.cTM13h-R3 PA Ê11û/20ff X

x

x

300! 2 s00 soù.gTM13b-R3 FIlter

.1Ðlrz

8/10/20û!

3006

3007

3008

3009

4Ð00

4001

4002

3 Êo0 soGCTM13h-R3 6/10t¿0ût

'l so0 soecTM13b-R4 PA 611 1t2000 x

X

Ì

X

X

X

2 s00 stxÞcTlul3b-R4 F¡ltÊr

¡t202

Ê/rí]1200É

3 SÛO SOO-CTM13LR4 B/1 l¡200S

,| Bl'ånk

Blsnk

Blank

Bì.4}.¡K ¡PA E¡'|1/20.ûJ

B/1 1l20f¡s 2 BLANK H20

+ ËLANK H20Ê û111Þ0{rE

I FIY¿T TE ,ISHED EY: rÉ IBY: ATE

AirGom$sncaGruup, LLC

5O?5 HOLLÍNS ROAD

ROANOKE. VA24+12

,f -/:4.'-¿ Å- H-x I'l¿l* F- -F ã )-)ã,

ìELINçII.,I$FIEO T'Y: )ATE ;ttvtsu ttY: ]ATE HRËLI¡Tç¡ÚSìHEdBiJ'ilDATË 'Jil¡J*tr¡t+r FÈL ìnûlfl

ÚT,IJ ËY: }ATE IISHEOBY: (EGEIVFU ËY:

Air Gompliance Group, LLC

5075 Hollins Road

Roanoke, VA 24019

Project No:

Condensables

EPA Method OTM28

Analytical Repoil

12659

Element One, lnc.

5022-C Wrightsville Av., Wilmington, NC 28403

91 0-7 g3-0 1 28 FAX: I I 0-792-6853 e 1 lab@-e 1 lab. com
The following data for Analytical Report 12659

has been reviewed for completeness, accuracy,

adherence to method protocol,

and compliance with quality assurance guidelines.

Review by:

f,,,,r*ol,rk

Renee Chek, Chemist

June 29, 2009

Report Reviewed and Finalieed By:

June 29, 2009

elernentOne

12659 ACG OTM 2Ê Report Packet

2 o'Í 13
SUTVIMARY OF RESULTS

elementOne

1265S ACG OTT\,! 28 Report Packet

3of13
Summary of Analysis

Summary of Method OTM2Û Analysis

Fractlon

lnorganic GPIS

lnorgan ic Nl-l+ Conection

Total lnorganic CPM

Organic CPM

TotalCPM*

S00-Run 5

e12659.1

Catch, mg

37.3

1.14

36.1

2.60

38.2

$00-Run 7

e12659-2

Catch, mg

22.5

0.409

22.1

0.600

22.2

Field Blank

ef 265È4

Catch, mg

0.400

0,00

0,400

<0.10

0.400

SOO-Run I

6f2û59-3

Catch, mg

22.9

1.31

21.8

0.200

21.3

Fraction

lnorganic CPM

lnorganic NHa Correction

Totallnorganíc GPM

Organic CPM

TotalCPM

"With Field Blank Corredion

elementOne

12659 ACc OTM 28 Report Packet

. Fage 4o113
ANALYTICAL NARRATIVE

elementOne

12659 ACG OTM 28 Report Packet

Page 5 of 13
Elernent One Analytical Narrative

$umrnary of Analysis

The EPA Method orM28 samples were prepared, extracted and measured

according to rnethod protocol. Each filterwas exûacted twice with 20mL of

deionized water, sonicated for at least two minutes and the extract removed,

The two extracts were then combined.wifh the agueous lir¡uid impinger sent by

the client. The same filterc were again extrac.ted twice with 20mL of methylene

chloride (Meclz) and sonícated beforc the eHract was rernoved. The two

melhylene chloride exhacts were cornbined wÍth the organic rinse sent by the

clienl. The combirred aqueous impÍngers and cornbined organic impingers were

extracted together. This step was repeated twice with s0 rnl of Meclz.

Followíng extraction, the aqueous impinger was evaporated to dryness in a tin

and the organic rinse was evaponated to dryness in a Teflon bag. The organic

fraction was desiccated and weighed to a constant weight. After the agueous

impÍnger was dry, the sample was redissolved in 100mL of ultrapure deionized

water- A pH was taken and the 100mL redissolved sample was títrated with

0.090N arnmonium hydroxide to a pH of 7.0. The sample was placed into a tin,

evaporated to dryness and weþhed to a constant weight.

Analysis QA/QC

All laboratory A,A/QC guidelines were followed in the analysis of the samples.

AddÍtional Gomments

The OTM28 Method ammonium conection factor has been implemented. EPA

Method OTIVI-28 Section 9.10 states that from the fietd sample weight, the

condensable particulate mass of the field train blank determined will be

subtracted, or 2.0m9, whichever is less.

elenrentOne

12659 ACG OTM 28 Report Packet

Page 6 of 13
SAMPLE CUSTODY

elenrentOne

12659 ACG OTM 28 Repoft Packet

7 of13
(r

!1\Þfr¡

I Ës€ I *ÊË Ër=

$ËË Ë

ff

E

r¡

au

gg ËË* =ËË ËËt

frÞ ËËË ËEÈ ãFË

elernentOne

12Ê59 ACG OTll 28 Repoil Pad(et

PagË I of t3
ANALYTICAL DATA

elementOne

fZSSg ACG OTM 28 Report Packet

9of13
Analytical Galculations

lnorganic CPMTotal lnorganic CPM, m¡r (rngl = rti - t¡c

Where.

m¡- inorganic fractÍon CPM after evaporation and titration-oTwz1 crtndensibta wo¡t<sheet

mr- amount of ammonium added (mg) -- ammonium worksheet

Ammonium Correction factorTotel ammonium added, m, (mg) = 12,03*Vr*N

Where17.03- corection factorfor ammonium - ËpA Method OTM 2g

Vt = volume of titrant added - ammonium ur¡orlçs/¡eet

N = Norrnality of titrant ^ ammônium worksf¡eef

Tohl CPMTotal Condensible Particulate Matter, mt (mg) = rl¡r r mo

Wheremn= total inorganic CPM - OTM2B Conde¿siöle r¿¡o¡frsf¡e€t

mo = total oryanic catch - OTMZB Aondensible worksheet

etement0ne

12659 ACG OTM 28 Report Packet

Page 10 of 13
ëlêmentone AIR TESTTNG sAltñpLE suBMtss¡oH FORM Lab lD i265g

Anaþis Due Date 06.24.09

CIA/QC/Report Due Date 06.26.09

cl¡€¡rl; TheÆfcomo¡la¡ceêrouo.LLC

Prol*c Nô

Prole6t lD ¡

Ëlernent Oræ Lot NumÞers Acetone Lot

Völüme Loqs Y/ N <2.0Y/N

Ruhs I FB Teflon Membrane Fllhr

ÍCPM CillElñer 3)

ÀquËql¡+ Lhuid lmpìnger

(Cf¡ål õmislrcr 1)

OrganÌc Rlnses

(CPMCdrlalßr4

CöH lmpingerwaær

(CPfflCo¡{âher 4)

Lab lD- BV. ml or Vlrt, e BV,nÉorVVt s BV mlwì,ì¡T.s

1 ¿5ô 48jí ¡ É{tl 17'tg

3 .131 ál 5o

4 f'ltt ;201

SS Paf,e 1 6f a

ss hy' Vd

ti18l200g l:S9:20 PM

l\4WoTMas P.Ep BylÞâte ,?¿¿ {. fÉ4lqq n4srormzsprebeinateT

Labeied Bv/Etate

lD Verifca'tion B'l

elementOne

12659 AÇG OTM 28 Report Packet

Page 11 of13
elernentone Method orMzs condensÌbles Lab # e lzfss

Cllsnt AOG pagê 1 of 1

Ealarrêciec,lç D€tB:6Æ3109 29= zoaao DE¡te:

Dder 6¿2410Ð 2g= ¿ooæ Datê:

Dáe:6/25fi)S

Elrffil O¡ra. fDc. turî .als ' A flstñum of ¿O fng is suHrætcd fnr lhÊ Told CpM Ë#;-

elernentOne

12659 ACG OTIVI 28 Report Packet

Page 12 of 13

DâIe:

lrnpinger Water

Sar¡flþ

to# Tln lD

Cdch

O*cûfton

Hnd t¡dh!

WâlË

Vdunç,

m¡

Tln

faa, g

Ddè E/zâlps

n!$a{+ RLC

fåtÞ qz5/09

r¡Ilide- RLQ

)å[ê

r¡Ud6

T-me gHrst

SsËlàWt.. q Tme Berlr G

tuhw1 .

Ttsne

g*tor &

f zGsSl 250 l3Ë 3.74AO 8EO J,T I I1 15s5 3.Tni

1eÊ5$2 215 t39 s.72ð5 &o 3.7510 1535 3.7s14

t2659-S 235 155 3.7256 8¿O 3.7¡U5 153,5 3,7489

f2E5+4 190 142 3.71üs w¿Ð 3,Tf 75 1635 3-717A

IfÊfltWáq

llkgÊme¡t I

2æ 14t g-726€ 820 s., ¿gÞ t5s5 3-7264

lltlethylene Gh f oride Exbact

sntPûe

tD#

Sanple

tæ12

vduflq

fiC

Eeggr-e lÐ

0¡lch

ËrSg¡â fþ6ErlpüÞn

ï:rr, g

Þ¡6

n l¡d€

Dåfã

nitlds

H€

ñllldË

I tmE Ðtgb &

*îcËr.,fL s

T¡fiË B¡OE¡9 e

tu¡t Wt, ïme t EDL&

SrflHü l¡{t , o

1265S1 2ffi 4 4.373{t '1325 4.3785 1225 4,3761

t265þ'2 215 1032 4.t275 13?5 4.0290 1225 4.æ7A 820 4.O2&5

12€59.9 ?ßo È'u l2AgO f325 4-2lJ8,5 1225 4.2Ea2

l?6594 205 205 3,7Ê74 14?,5 3.78E1 l2z5 ?.1674 æo 3-7Ê7ä

}f,enl MêCI

ilk

lãnã{ 1

!bË12 Blk 50 1007 4.tl73t 1325 4,O718 1125 4.O717

Total Catchqg

€ilÞl€

lDf

F¡H4

ddÉd,

llìo

IÍtTre. r

-Iin +

W¡ls

CËlsh, þ

WËLr

blfilÇm[

fngfgffi¡s

C¡io|l' tnq

l¡rc|2

Þoq lÞ

E€$e

Tue, g

tsågglÐ+

f{hGtå

Wehhl-c

À4ÞCül

b1æÌ,, rfig

otg*lb

Salclx firg

Tct¡l GFH

C¡bclf. rrt

1265sf l-74 3.7400 3.7773 u-5 35,6 4 4.3735 4,376r 0.0 2-A sE.2

1265S2 0 40Ð, 3.7286 3.7610 o.5 21-E 103¿ 4.t¿75 4.9¿85 0.0 0Ê È2-2

1266tr3 1,31 3.7258 3.7485 o5 21.1 50 4,24fi) 424fr2 o-o 0,2 2t_3

t2€5+4 ooo 3.71çS 3:7173 q4 o.4 2U5 3.7È74 3.7874 o.0 o.0 o.4

t..d tlrç17 Blr

rûú I tlÆ o.o 3.7266 3.7284 o.o <0.1 1 007 4.02s1 4.D717 0.o <0.1 o,0
õ

a{

E

o

ftt

oG

o

F

t-

+t !

e

Ð

E

at Ê

ä *'.9

elementOne

12659 AgG OTM 2B Report Packet

Page-13 of 13

INTËGRATED BAG Añ¡ALYSIS DATA

Job Hame

Gontract 'd

Èlethod of ^Analusis 3A

Date D6/,tOffìo - o6fi,ttûg
Appendix F

Field Equipment Galibration Data
TYPE S PITOT TUBE INSPECTION DATA FORM

BE 229

PITOT TUBE ASSEMBLY LEVEL?

TUBE OPENINGS DAMAGED?

Pa 1.25 Pb

48

1.25 =Pa

Dt 0.95 - 0.95 cm Pa=Pb=[1.05-1.50]xDt

A

cornments

CALIBRATION REOUIRED?

lF NO CALIBRATION REQUIRED, BY DEFAULT PITOT COEFFICIENT (Cp)= 6.34

INSPECTED BY
TYPE S PITOT TUBE INSPECTION DATA FORM

PITOT TUBE ID I 144 DATE I tnAtZOOA

PITOT TUBE ASSEMBLY LEVEL?

yes

ves I-l PITOT TUBE OPENINGS if yes, see Note A

< 100 100

z 0.05 < 0.32 cm

<50

< 0.08 cm

1.2s =Pa

0,48 - 0.95 cm Pa=Pb=[1.0S-1.S0]xDt

A

comments

CALIBRATION REQUIRED?

lF NO CALIBRATION REQUIRED, BY DEFAULT PITOT COEFFTCIENT (Cp) = 9.94

INSPECTED BY JBS

1 4

3 2

0.04

Pa 1.25

Dt 0.95
TYPE S PITOT TUBE INSPEGTION DATA FORM

PITOTTUBË ID I 13I DATE I 7t17 008

PITOT TUBE ASSEMBLY LEVEL?

ves

ves

TUBE OPENINGS DAMAGED? r_:l

betal 2

< 100

<50

< 100

<50

< 0.08 cm

ffi=ra

pa=pb=[1.0S-i,50JxDt

A

Other comments

CALIBRATION REQUIRED?

yes

lF NO CALIBRATION REQUIRED, BY DEFAULT PITOT COEFFICIENT (Cp) = 0.84

INSPECTED BY JBS

1 I 4

2
Page 1 of 2

The A¡f Compliance Gfoup. LLC

EPA Method 5

Meter Bor Calibration

Pre-Test Or¡ficê Mêthôd

Met€r Box #

oate: 04114109

BaromelricPressure: _lÊJ!.Q_(ín.Hg)

ïh€or€l¡cal Critícal Vâcuum; 13.54 (¡n. Hg)

Calib¡ation Techniclan: MSH

-.- DRY GAS METER READINGS _--------.----

AH

{¡n H2Ol

0.26

0.26

0.6

0.6

1,1

1.1

1.9

1.9

3.4

3.4

Time

fmlnì

5

5

6

6

5

5

7

7

5

5

Volume

Total

ú:)

1.545

1.567

2.722

2.738

3.Ol f

3.026

5.433

5.460

5.232

5.1 95

62.O

62.0

62.0

82.0

62.0

62.0

62.0

E2.O

62.0

62.0

9.0

64.0

64.0

64.0

65.0

65.0

66.0

66.0

67.0

69.0

Volumê Volum€ lnitiâl Flnâl

ffr') (ñ:)

716.û68 717.613

717.613 719.180

719.180 721.902

721.902 724.640

T24.UA 727_651

727.651 730.677

730.677 736.110

73ô-110 741_570

741.570 746.802

746.802 751.997

ldeo F) {deo F) (deg F} ldeo Fì

tñit¡al Temûerâfur€

lnlet Outlet

F¡n4ljlamoerâturê

hlet Outlet

64.0 64.0 64.0

64.0 64.0 64,0

64.0 64.0 64.0

64.0 64.0 64.0

€4.0

64-0

64.0 65.0 64.0

64.0 66.0

64.0 66.0 64.0 67.0 6s.0 65.0 69.0 66.0 66.0 70.0 66.0

CRITICAL ORIFICE READINGS

Ambient Temoerature

Averâoe T€moerature

DGM DGM AmbieIlt

Outlet Overall Temp

ldeq R) (deq R) (deq R)

524.0 524.0 522.0

524.0 s24.0 522.0

524.0 524.0 522.0

524.0 524.t 522.0

524,0 524,5 522.0

524.0 524.A 622.0

524.0 525.0 522.0

524.5 525.5 522.0

525.5 526.8 522.0

526.0 527.A 522.0

OrÌfice Actuat Se¡ial# K'Orifrce Vacuum

lnumbe¡) Coefficient lin Ho)

KS-40 0.2406 23.0 KS-40 0.2406 23.0

KS-48 0.3497 22.O KS-48 0.3497 22.O KS-55 0.459f 20.0

KS-55 0.4591 20.0 KS-63 0.5898 18.0 KS-63 0.s898 18.0 KS-73 0.8057 í5.0 KS-73 0 8057 15.0

lnitial

({eg Fl

82.0

62.0

62.0

62.O

62.0

62.0

62.0

õ2.0

62.0

62.0

62.0

62.0

62.0

62.0

ô2.0

62.0

62.0

62.0

62.0

62.0

Final Average

ldeo FJ {deg Fì

IMPORTANT:

For valid test results, lhe Actuaf Vacuum should b€ at least 1 to 2 in. Hg greâter than the

Theorel¡cel Criücal Vâcuum shown âbove.
P^ge 2 ot 2

Thè Air Compl¡ânce Group, LLC

EPA Method 5

Meter Box Cafibration

Pre-Test Orif¡ce Method

Meter Box # 4

Dâtê: 04114109

Earometrlç Pressurei ____?9.20__ (in. HS)

Theoretical Critical Vacuum: 13.54 (¡n. Hg)

Calibratíon Teohnícian: MSH

oRtFtGE -----

VOLUME VOLUME VOLUME CORR. CORR. NOMINAL Vc(std) Vc(std) Vcr

{e (ilters) f81

RESULTS

.-- DRY GAS METER ---

VOLUME VOLUME

CORR. CORR,

Vm(std) Vm(std)

fft"t ll¡rers)

1.494

1.515

2.634

2 649

2.515

2.928

5.265

5.246

5.072

5.027

1.O117

0.9975

1.OOO7

0.994Ð

0.9894

0.9849

0.9851

0.s812

0.9977

1.0067

0,9950

42.3

42.9

74.6

75.0

82.5

82.9

149.1

149.7

'143.6

142.4

42.8

42.8

74,6

74.6

81.7

81.7

146.9

146.9

143.3

143.3

lmm H2o)

39.31

39.31

42.94

42.94

45.67

45.67

47.80

47.75

45.71

45.66

44.28

1558

1.558

2-718

2.718

2.573

2.573

5.347

5.347

5.218

5.2't8

lln H2Ol2

-0.2

-0.2

-0.1

4.1

0.1

0.'l

0.1

0-l

0.1

0.1

0.0

----. DRY GAS METER.--

CALIBRATION FACTOR

"Y'Value Variation

{numberì fnumber) 1

0.02

0.00

0.01

0.00

-0.01

-0.0r

-0.01

-0.01

0.00

0.01

0,00

1.511

1.511

z,ÕJ0

2.636

2.844

2.884

5.186

5.1 86

5.060

5.060

(in H2Ol

1.5475

1,5475

1.6905

1.6905

1.7981

1.798',1

L881 9

1.8801

1.7994

1.7977

Average 1.7431

oRtF¡cE --.-.-

CÂLIBRATION FACTOR

"AH@'Value Vâlue Variat¡on

Avemge

| = 0.9950 AH@= 1.7431

Pass

Notes:

r For Cal¡blation Factof Y, the râtio of the reãding of the calibrâtion meter to lhe dry gas mete¡

acceptable tolerance of individual velues fiom lhe average is t 0-02. Var¡at¡ons shown hêvê bêên mundêd lo nearest 0.01 .

2 For Orifice Cal¡bration Faclor 

^H@, 

thê ófificê d¡fferential pressure in ínches of H20 tfiat equâtes to 0.75 cfm

of aír at 68 deg F and 29.92 lnches of Hg, acceptable toleËnce ol indiv¡dual values from the average ls * 0,2,

VanìatÍons shown have been roundêd to nearest û.1 -

QÄ/QC Performêd By: Date; 04n7ß9
Page f of2

The Air Compliance Group, LLC

EPA Method 5

Meter Box Calibralion

Post-Test Orlfice Melhod

Meter Box #

Date: 61221200S

Barometric PressureÌ 28.950 (in. Hg)

Theorêtlcãl Critical Vacuum: 13.ô6 (in. Hg)

Calib¡ation Technician: FPC

DRYGAS METER READINGS

AH

lin H2Ol

l-10

Ll0

1.10

ïme

(min)

10_0

10.0

10.0

Volume

lnitial

(fll

785-639

791,614

797.671

Volume

Final

d)

791.614

797.671

803.726

Volume

Total nl

5.975

6.057

6.055

lnitial Temp€rãture

lnlet Outlet

Final Temoerature

lnlet Outlet

Orifice Actual Serial# K Orífice Vacuum

lnumbef) Coefücient {in Hq)

KS-55 0.4591 KS-55 0.4591 KS-55 0.¿1591

Ambient Temoeratu¡e lnitial Final Average

ldes Fl ldeg F) (deo F)

80.0 80.0 80.0 80.0 80.0 80.0 80,0 80.0 8û.0

22.O

22.0

22.O

CRITIGAL ORIFICE READINGS

(deo F) ldeo. Fì ldeo Ð ldeo Fì

84.0 82.0 8S.0 84.0

89.0 84.0 92,0 86.0 92.t 86.0 94.0 87.0

Averâoè T€mo€tetule

ÐGM DGM Ambient

Oullet Overall Temp

(deq R) ldet Rì ldeo R)

543.0 544.8 s40.0

545.0 547.8 s40.0

546.5 549.8 5¿10.0

IMPORTANT:

For val¡d test results, the Actual Vacuum should be I to 2 in, Hg greater than the

Theor€t¡cel Critical Vacuum shown äbove.
Page2 aÍ 2

The Air Compliance Group, LLC

EPA Method 5

Meter Box Celibrâti0n

Post-Tesl Orifìce Method

Meter Box #

Date: 061ru09

Berometdc Pressure: 28.95 (¡n. Hg)

Theoreticäl Critical Vacrrum:.. 13.66 (in. Hg)

Calibral¡on Technician: FPC

ORIFICE

RESULTS

- 

DRY GAS METER 

-

VOLUME VOLUME CORR. CORR. Vm(std) Vm(std) (fll {titers)

5.617 159.1 5.663 160.4 5.640 159.7

- 

ORY GAS METER 

-

CALIBRATION FACTOR

'Y'Value Vâriâtion

{numberl (number)

1.0183 0,004 r.0100 -0.004 1.0140 0.000

ORIFICE

CALIBRATION FACTOR

"ôH@" Value Value Vâriâtion

lin H2O) lm.rTJ2O) (in H2Oì

VOLUME

CORR.

Vc(std)

tn.l

5.720

5.720

5,720

1.7796

1.7730

1.7682

VOLUME VOI-UME

CORR. NOMINAL

Vc(std) Vcr

(lítersl (f1

162.0 6.048 1Ê2.0 6.04€

162.0 6.048

45.20 0.006

45.03 -0.001

M.91 -0.005

AverageY6"a¡ 1.0141 Averâge dH@ (p.9 1,7736

Test Avg. Gamma (Y{po"q): 1.0141

iation: 0.0191

of Y: 0.0498

<ão/o otYT Yes

Note:

The Variation labsolute value of the Calibrafion Fâclor Gârnmâ {Y) minus the PostTestAverage Gamma (Y¡p*r))l

musl be less than or equal to 5% of Calibration Factor Gamma (Y).

QAJQG Pêdormed By: Date; 6l23l200s
THERMOCOUPLE CALIBRATION DATA

Meier Box lD: 4

Meter Box Thermocouple: Stack Temp.

Reference Calibrator lD: BTSZZB

Reference Calibrator Model: HHZI CAL-K

Reference Calibrator Type: K

a Difference, % (Based on degrees Rankin):

' Absolute Difference =

b Average Absolute Difference must be < 1.5%.

Calibration Performed By:

QA/QC Check Performed By:

Averageb I o.l

Pass/Fail ? I Pass

01/16/09

x 100

1

2

a

4

5

o

7

I

I

10

11

0

32

100

212

300

400

500

600

700

800

900

1

33

101

213

300

399

501

600

702

801

900

0.2

o.2

0.2

0,1

0.0

0.1

0.1

0.0

0.2

0.1

0.0
THERMOCOUPLE CALIBRATION DATA

Meter Box lD: 4

Meter Box Thermocouple: Probe Heat

Reference Calibrator lD: 875228

Reference Calibrator Model: HH71 CAL-K

Reference Calibrator Type: K

a Difference, % (Based on degrees Rankin):

Absolute Dífference =

b Average Absolute Difference must be s 1.5o/o,

Calibration Performed By:

QA/QC Check Performed By:

01/16/09

Averageb I o.t

Pass/Fail ? I Pass

I (Ref. Temp.+ 460) - (TC Temp.+ ¿00) |

Ref' TemP. + 460 x 100

Reference

Point

Reference

Temperature

lotrì

Thermocouple

Temperature

loFl

Absolute

Dlfferenceå

lo/^\

1

2

3

4

5

b

7

0

32

100

212

300

400

500

0

32

ôo

211

300

402

501

0-0

0.0

0.2

0.1

0.0

o.2

0.1
TH ERMOCOUPLE CALIBRATION DATA

Meter Box lD: 4

Meter Box Thermocouple: Filter Heat

Reference Calibrator lD: BTEZZ9

Refere4ce Calibrator Model: HH71 CAL-K

Reference Calíbrator Type: K

a Difference, % (Based on degrees Rankin):

Absolute Difference =

b Average Absolute Difference musi be S 1.5%.

Cafibration Performed By:

QA/QC Check Performed By;

01/16/09

Averageb I o.l

Pass/Fail ? I Pass

I (Ref. Temp.+ 460) - (TC Temp.+ 460) I

Ref. Temp. + 460 x 100

Reference

Point

Reference

Temperature

f"trl

Thermocouple

Temperature

fotrt

Absolute

Differencea

(o/"\

1

2

t

4

5

6

7

0

32

100

212

300

400

500

1

31

100

212

300

399

499

o.2

0.2

0.0

0.0

0.0

0.1

0.1
THERMOCOUPLE CALIBRATION DATA

Meter Box lD: 4

Meter Box Thermocouple: fmpinger Exit i XAD Condenser

Reference Calibrator lD: 875228

Reference Calibrator Model: HH71 CAL-K

Reference Calibrator Type: K

0f/16i09

Average I f

Pass/Fail ? I Pass

(a) Absolute Difference must be s 2"F.

Calibration Performed By:

QA/OC Check Performed By:

Reference

Point

Reference

Temperature

¿OFì

Thermocouple

Temperature

I'Fì

Absolute

Dlfferencea

I'F'l

1

2

3

4

5

6

7

I

I

0

10

20

32

40

50

60

68

80

0

10

21

32

41

50

61

67

78

0

0

1

0

1

0

1

1

2
TH ERMOCOUPLE CALIBRATION DATA

Meter Box lD: 4

Meter Box Thermocouple: Meter lnlet

Reference Calibrator lD: 875228

Reference Calibrator Model: HH71 CAL-K

Reference Calibrator Type: K

(a) Absolute Difference must be s 5.4'F.

Calibration Performed By:

QA/QC Check Performed By:

Average I I

Pass/Fail ? I Pass

Date: 01/16/09

Reference

Poínt

Reference

Temperature

lotrì

Thèrmocouple

Temperature

1"Fì

Absolute

Difference'

fotrì

1

2

3

4

5

6

7

I

I

1g

11

0

32

50

68

80

90

100

110

120

r30

140

2

32

51

68

7g

89

100

110

120

132

140

2

0

1

0

1

1

0

0

0

2

0
THERMOCOUPLE CALIBRATION ÐATA

Meter Box lD: 4

Meter Box Thermocouple: Meter Outlet

Reference Calibrator fD: 875228

Reference Galibrator Model: HH71 CAL-K

Reference Calibrator Type: K

(a) Absolute Difference must be < 5.4'F.

Calibration Performed By:

AA/QC Check PeÍormed By:

Average I f

Pass/Fail ? I Pass

01hat09

Reference

Point

Reference

Temperature

t"Fl

Thermocouple

Temperature

f'Fl

Absolute

Differencea

¿OFì

1

z

3

4

5

6

7

I

o

10

11

0

32

50

68

80

90

100

'110

120

130

140

1

33

50

69

80

90

100

110

121

130

143

1

1

0

'l

0

0

0

0

1

0

3
Page I of 2

The Air Compllancê Group, LLC

EPA Method 5

Meter Box Calibrlíon

Pre-Test Or¡f¡ce Mêlhod

MeterBox# 7

Ðate: 06/03/09

Bârometric Pressur€: 28.980 (ln. Hg)

Theoretical Critícal Vacuum: 13.97 (in. Hg)

Calibration Technicien: MSH

-- ORY GAS METER READ¡NGS

AH

(in H2Ol

0.29

o.29

0.62

0.62

1.1

1.1

1.8

1.8

3.3

Time

lmlnì

5

5

5

5

5

b

5

5

5

5

Volume

Totel

fr1

1.606

'l.611

2.321

2.317

3.O47

3.D47

3.887

3_888

5.212

5.212

74.O

74.0

74.0

74.0

74.0

74.0

74.0

74.0

74.0

74.0

78.0

80.0

8r.0

t1.0

83.0

Volume Volume

lnltiâl F¡nâl

lfl') É:)

477,721 479.327

479.327 480.938

480.938 483.259

483.259 4t5.576

485.576 488.623

488.623 491.670

491,670 495.557

495.557 499.445

439.445 504.657

504.657 509.869

ldeg Fl (deq F) ldeo F) fdeo F)

75.0 74.0 76.0 75.0

lnitlal Temoerature

lnlet Oul¡et

76.0 75.O

77.0 75.0

78.0 76.0

78.0 76.0

F¡nal Temo€rature

lnlet Outlet

76.0

78.0

78.O 81.0 79.0

79.0 83,0 79.0

79.0

77.4 75.0

78.0 76.0

78.0 76.0

78.0 76.0

80.0 78.0

81.0 78.0

84.0 79.0

CRITICAL ORIFICE READINGS

AmÞ¡gnt Temo€ralure

Averaoe Temperature

DGM DGM Ambient

Outlet Ovêiåll Temp

(deo R) ldeo R) fdeg R)

534.5 535.0 534.0

535.0 535.0 534.0

535.5 536.5 534.0

536.0 æ7.0 534.0

536.0 537.0 534.0

537.0 539.0 534.0

538.0 539.3 534.0

538-5 539.8 534.0

539.0 540.5 534.0

539.0 541.3 534.0

Orifìc€ Actual Serial# K'Orifice Vacuum

lnumber) Coeflìcíent (in Ho)

Ks-40 0.240ô 24.0 KS-40 0,2406 24-O KS-48 0.3497 22.0 KS-48 0.3437 22.0 KS-55 0.4591 20.0

KS-55 0.4591 20.0

KSS3 0.5898 18.0

KS-63 0.5898 18.0 KS-73 0.8057 r5.0

KS-73 0.S057 15-0

lnítial

{deo Fl

74.0

74.0

74.0

74.O

74.0

74.O

74.O

74.0

74.0

74.0

74.0

74.0

74.0

74.0

74.0

74.0

74.0

74.O

74.0

74.O

Final Average

ldeo Fì ldèt Fì

IMPORTANT; ,

For valid test results, lhe Actual Vacuum should be at least 1 to 2 in. Hg greater than the

Theoreticâl Criticãl Vecuum shown above.
Pagø?õÍ2

The Air Compllance Group, LLC

EPA Mêthod 5

Motêr Box Calibrat¡on

Pre-Test OrÍfice Method

MeterBox# 7

Dâte: 06i/03/09

--- ÐRY GAS METER -.-.

VOLUME VOLUME

CORR. CORR,

Vm(std) Vm(std)

É (liters)

^n.r.fi*¡Èñr*á REsuLTs

Bâromehic Pressure: 28.98 

. 

(¡n. Hg)

Theor€tical Cril¡cal Vecuum: 13.67 {in. H9)

celibrâfion Technic¡an: MSH

oRlFlCE ------

VOLUME VOLUME

CORR. NOMINAL

Vc(std) Vcr

lliters) É1

r-536

1.538

2.2'15

2.209

2.909

2.903

3.702

3.699

4.971

4.964

o.9424

0.9807

0.9899

0.9926

0.9897

0.s915

0.999'1

0.sgs8

'1.0r64

1.0178

0.9960

43.5

43.6

62.7

62.6

82.4

82.2

104.8

104.8

'140.8

140.6

{.01

-0.02

-0.01

0.00

-0.01

0.00

0.00

0-t)0

0.02

o.o2

0.00

VOLUME

CORR.

Vc(std)

fs:t

1.509

1.509

2.193

2.193

2.879

2.879

3.698

3.698

5.052

5.052

1.7143

't.7127

1.7317

1.7301

1.7809

1.7776

1,7592

1.7576

1.7251

1.7251

1.7414

42.7

42.7

62.1

62.1

81.5

81.5

104.7

104.7

143.1

143,1

43.54

43.50

43.99

43.94

45.24

45.15

44.68

44.64

43.82

43.82

44.23

1.576

1.576

2.291

2.291

3.007

3.007

3-863

3.863

5.277

5.277

--- DRY GAS IIIETER 

--.

CALIBRATION FACTOR

'Y" Value Variation

(numbe¡ì lnumber'l I

oRtFtcE -----

CALIBRATION FACTOR

%H@" Value Value Var¡at¡on

l¡n H2O) (rrU H2O) lin H2O)'z

Average Average

0.0

0.0

0.0

0.0

0.0

0.0

0.0

0.0

0.0

0-0

0.0

verage Y =

AverageÂH@ = 1.7114

PasslFail? Pass

Notes:

I For Cal¡bralion Factor Y, lhê rålio of the reading of the cetlbrât¡on mêter to lho dry gâs mêtèr,

acceptrabìe tolerance of individuâl values from the average ís ù 0,02. Var¡et¡ons shown t¡ave been rounded to nêârest 0.0'1.

2 Fo¡ Q¡ifice CalibratÍon Factor AH@, the or¡fice d¡fferential prcssure in inches of H20 that equates to 0.75 cfm

of elr at 68 deg F and 29.92 ¡nchqs of Hg, âcceptåbl€ tolerance of individual vâlues from thê av€ragê is t 0.2.

Variations shown hâve been rûund€d lo nèárêst 0-1.

QA/QC Performed By Däte: 06/09/09
Pagø I of 2

The Alr Compllance Group, LLC

EPA Method 5

Metêf Box Cal¡bÌâi¡on

Post-Test Orifi ce Method

MeterBox# 7

Date: 612212ô09

Barometric Pressure: 28.950 (in. Hg)

Theoretícel Critícal Vacuum: 13.66 (in. Hg)

Calibrät¡on Technic¡ân: FPc

DRY GAS MEÍER READINGS

AH

lln H2O)

t.l0

1.10

1.10

Volume

lnitial

iÊ1

227.884

233.831

239.985

Volume

Final ftl

233.831

239.985

246.161

Voluñe

Tolal

Gl

5.947

6.1 54

6,176

Time

lminì

10.0

10.0

10.0

lnitíal Temoerature

lnlet Ouüel

Fínal.Jêmpqalure

lnlet Outlet

83.0 90.0 85.0

(deo Fì fdeg F) ldeq Fl (deo F)

82.O 81.0 85.0 82.O

85.0 82.0 88.0 83.0

88.0

Orifice

Serial# K Orifice

lnumberì Cæffrcient

KV-55 0.4616

KV-55 0.¿t616 KV-55 0.¿f616

Actual

Vacuum

(in Ho)

20.0

20.o

20.o

lnitial

fdeg Fl

80.0

80.0

80,0

CRITICAL ORIFICE READINGS

Ambient Te¡noqrAture

Averâoê T€moerâturë

DGM DGM Ambienl

Outlet Overall Temp

ldes ßì ldeg R) {deo Rl

541.5 542.5 540.0

542.5 544.5 5¿m.0

544.0 546.5 540.0

Fínal Average

ldeo Fì ldeo Fì

80.0 80.0

80.0 80.0

80.0 80.0

IMPORTANT;

For valÍd lest results, the Actual Vacuum should be 1 to 2 in. H9 greater thãn the

Theorel¡câl Crit¡cål Vacuum shown âbove.
Page2oÍ2

Thê A¡r Compl¡ânce Group, LLC

EPA Method 5

Meter Box Calíbrat¡on

FostJest Or¡t¡ce Method

Meler Box # 7

Dât€: 06122109

Barom€trìc Prêssure: 28.95 (in. Hg)

Theoretioal Critical Vacr.rum: 13.66 (in. l-lg)

Câlibration Technioian: FPC

oRlFlcË

VOLUME VOLUME VOLUME

CORR. CORR. NOMINAL Vc{std) Vc(std) Vcr

ffl ll¡ters) É1)

5.751 162.3 6,0Ûl

5.751 162.3 6.081

5.751 162.9 6.081

ORIFICE

CALIBRATION FACTOR

"ÂH@" Value Value Variation

lin H2Ol ¿mm H2Oì (in H2O)

1.7652 44.U 0.004

1.7620 44.7s 0.001

1.7571 M.63 {.004

RESULTS

- 

DRY GAS METER 

-

VOLUME VOLUME CORR. CORR,

Vm(std) Vm(std)

fft3) llirersl

5.614 159.0 5788 163.9 5.787 163.S

- 

DRYGAS METER _-

CÀLIBRATION FACTOR

'Y'Value Vâriât¡on

{number) (numberl

1.02M 0.021

0.9936 {.010

0-ss37 {.010

Average Y1o"s¡ 1.0039 Average dH@ 1p*¡ 1.7614

Factor Gamma (Y): 0,9960

Test Avg. Gamma (Ytpo.t)): 1.0039

: 0.0079

of Y: 0.0498

<SYooiY? Yes

Note:

The Variation [absolfe value of lhe Calibration Factor Gamma (Y) minus the Post Test Average Gamma (Y1ro"1¡)]

must be less than or equal to 50/o of Callbratlon Fäctor Gamma (Y).

QA/QC Performsd Ey: Datel 6t23t200s
THERMOCOUPLE CALIBRATION DATA

Meter Box lD: 7

Meter Box Thermocouple: Stack Temp.

Reference Calibrator lD: 875228

Reference Galibrator Model: HH7'l CAL-K

Reference Calibrator Type: K

a Difference, % (Based on degrees Rankin):

Absolute Difference =

b Average Absolute Difference must be s 1.5%.

Calibration Performed By:

QA/AC Check Performed By:

Averageþ I o.t

Pass/Fail ? I Pass

01/07/os

Reference

Point

Reference

Temperature

1øtr1

Thermocouple

Temperãture

loF)

Absolute

Differenceã

(o/^\

1

2

3

4

5

6

7

I

I

10

11

0

32

100

212

300

400

500

600

700

800

s00

0

33

101

211

301

400

500

602

702

801

900

0.0

0.2

0.2

0.1

0.1

0.0

0.0

0.2

0.2

0.1

0.0
THERMOCOU PLE CALIBRATION DATA

Meter Box lD: 7

Meter Box Thermocouple: Probe Heat

Reference Calibrator lD: 875228

Reference Calibrator Model: HHTlCAL-K

Reference Calibrator Type: K

a Difference, o/o (Based on degrees Rankin):

Absolute Difference =

b Average Absolute Difference must be s 1.5o/o.

Calibration Performed By:

Q¡/OG Check Performed By:

01to7tog

Averageb I o.o

Pass/Fail ? f Pass

| (Ref. Temp.+ 460) - (TC Temp.+ 4691 ¡

Ref. Temp. + 460 x 100

Reference

Point

Reference

Temperature

lotrl

Thermocouple

Temperature

lotrì

Absolute

Differenceâ

to/^\

1

2

ó

4

5

b

7

0

32

100

212

300

400

500

0

32

100

212

301

399

500

0.0

0.0

0.0

0.0

0,1

0.'t

0,0
TH ERM OCOUPLE CALIBRATION DATA

Meter Box lD: 7

Meter Box Thermocouple: Filter Heat

Reference Calibrator lD: 875228

Reference Calibrator Model: HH71CAL-K

Reference Calibrator Type: K

a Difference, o/o (Based on degrees Rankin):

Absolute Difference =

b Average Absolute Difference must be s 1.5o/o.

Calibration Performed By:

QA/OC Check Performed By:

01lo7l09

Averageb I o.z

Pass/Fait ? I Pass

I (Ref. Temp.+ 460): (TC Temp.+ +00) |

Ref. TemP. +460 x 100

Reference

Polnt

Reference

Temperature

f otr\

Thermocouple

Temperature

/otr\

Absolute

Differencea

(o/^\

1

2

3

4

5

6

7

0

32

100

212

300

400

500

1

101

213

300

399

4S8

0.2

0.4

0.2

0.1

0.0

0.1

o.2
THERMOCOUPLE CALIBRATION DATA

Meter Box lD: 7

Meter Box Thermocouple: lmpinger Exit / XAD Condenser

Reference Cafibrator lD: 875228

Reference Galibrator Model: HH71 CAL-K

Reference Calibrator Type: K

01107109

Average | 1

Pass/Fail ? I Pass

(a) Absolute Ðifference must be < 2'F.

Calibration Pedormed By:

OA/QC Check Performed By:

Reference

Point

Reference

Temperature

f"trì

Thermocouple

Temperature

t"trl

Absolute

Þifference¿

I'Fì

1

2

3

4

5

6

7

I

I

0

10

20

32

40

50

60

68

80

0

I

20

33

40

51

60

67

79

0

1

0

1

0

1

0

I

1
TH ERMOCOU PLE CALIBRATION DATA

Meter Box lD: 7

Meter Box Thermocouple: Auxillary

Reference Calibrator lD: 875228

Reference Calibrator Model: HH7'l CAL-K

Reference Calibrator Type: K

(a) Absolute Difference must be < 2'F.

Calibration Performed By:

OA/OC Check Performed By:

Average | 0

Pass/Fail ? | Pass

01t07tog

Reference

Point

Reference

Temperature

loFl

Thermocouple

Temperature

f"F)

Absolute

Differencea

t'F)

'l

2

3

4

5

6

7

I

o

10

11

0

32

100

212

300

400

500

600

700

800

900

1

32

100

211

300

400

500

601

700

800

900

1

0

0

1

0

0

0

1

0

0

0
THERMOCOUPLE CALIB RATION DATA

Meter Box lD: 7

Meter Box Thermocouple: Meter lnlet

Reference Calibrator lD: 875228

Reference Calibrator Model: HH71 CAL-K

Reference Calibrator Type: K

(a) Absolute Difference must be s 5.4'F.

Calibralion Performed By:

QA/OC Check Performed By:

Average | 1

Pass/Fail ? I Pass

01lo7l0g

Reference

Point

Reference

Temperature

t"F't

ïhermocouple

Temperature

l"F\

Absolute

Differencea

/otr\

1

¿

3

4

5

6

7

I

I

10

11

0

32

50

68

80

90

100

110

120

130

140

0

31

53

67

8't

90

101

110

119

130

14',1

0

1

3

1

1

0

1

0

1

0

1
THERMOCOUPLE CALIBRATION DATA

Meter Box lD: 7

Meter Box Thermocouple: Meter Outlet

Reference Caliþrator lD: 875228

Reference Calibrator Model: HH71 CAL-K

Reference Cal¡brator Type: K

(a) Absolute Difference must be < 5.4"F.

Calibration Performed By:

QA/OC Check Performed By:

Average I f

Pass/Fail ? I Pass

a1rc7tog

Reference

Point

Reference

Temperature

I"Fì

Thermocouple

Temperature

lotrì

Absolute

Differencea

I'Ft

1

2

3

4

5

6

7

I

I

10

11

0

32

50

6B

80

90

100

110

120

130

140

0

31

5'1

67

81

90

101

109

120

131

140

0

1

1

1

1

0

1

1

0

1

0
Page I of2

The Alr Compliânce Group, LLL

EPA Method 5

Meter Box Calibration

Pre-Test Oriticê Mêthod

Meler Box# 11

Dâtei 12.30.08

Bãromêtr¡c Prêssure: 29.190 (ln. Hg)

Theoretical Criticâl Vacuum:___! 3.ZZ_ (in. Hg)

Calibration Technician: MRW

DRY GAS METER REAOINGS

ÀH

fín H2O)

o.29

0.29

0.6

0.6

1.1

1.1

f.9

1.9

3.4

3.4

Tlme

lmÍn)

5

5

5

5

5

5

6

5

5

5

Volume

lnitlal

id)

22.646

24.O47

35.842

38.05'1

40.27õ

43.173

46.078

50.636

25.624

30.721

Volume

Final

6:)

24.087

25.624

38.051

40.276

43.1 73

46.078

50.636

54.418

30.721

35.842

Volume

Totâl

fr:)

1.541

1.537

2.209

2.225

2.097

2.905

4.558

3.782

5.097

5.121

64.0

64.0

65.0

65.0

66_0

66.0

66.0

67.0

64.0

65.0

63.0

63.0

64.0

64.0

64.0

64.0

64.O

65.0

63.0

63.0

64.0

ô4.0

64.0

65.0

65.0

63.0

64.0

lnitial Temoerature

lnlet outlet

(deo FJ ldeo F)

Final TernûeÉtu¡e

lnlet Outlet

lded R (deo Fì

64.0

64.0

65.0

66.0

68.0

66.0

67.0

67.0

64.0

6s.o

63.0

63.0

64.0

CRITICAL ORIFICE READINGS

Ambient TemoeÊâture

Avêråoê Te mþe ratu r,e_.

DGM DGM Ambienl

Oullet Overall Temp

ldes Rì (deo R) ldeg R)

523.0 523.5 524.0

523.0 s23.s 524.0

524.0 524.5 524.0

524.0 524.8 524.0

524.0 525.0 624.0

524.0 525.0 524,0

524.5 525.5 524.0

525.0 526.0 524.0

523.0 523.5 524.0

523.5 524.3 524.0

Orificê

Serlal# K'Orifioe

lnumber) Coefficient

KV-40 0-2404

KV40 A.2404

KV-48 0.3504

KV-48 0.3504

KV-55 0.4616

KV-55 0,4616

KV-63 0.6012

KV-63 0.6012

KV-73 0.8227

KV-73 0.8227

Actual

Vacuum

(in Ho)

21.0

21.0

19.0

19.0

18.0

18.0

f 6-0

16.0

15-0

15.0

lnitial

ldeo FÌ

64.0 64.0

64.0 64.0

64.0 64.0

64.0 64.0

64.0 64.0

64.0 64.0

64.0 64.0

64.0 64.0

64.0 64.0

64.0 64.0

F¡nal Average

ldeg F) (dea F)

64.0

64.0

64.0

64.0

64.0

64.0

64.0

64.0

64.0

64.0

IMPORTANT:

For velid test results, the Actual Vacuum should be at least I to 2 ¡n. Hg greater than th€

Theoretical Critical Vacuum shown above.
Fagè 2 of 2

The Air Compl¡a'lcê Group, LLC

EPA Method 5

Meter Box Cålibration

Pre-Test Odnce Mêthod

Melêr Bôx #

Date: 12.30.08

Ba¡ometric Pressure: 29.19 (in. Hg)

TheoretícãlCrítical Vacuum: 13.77 (in. Hg)

Calibration fechnícian: ¡¿RW.

RE

--- DRY GAS I/IETER ----

VOLUMÊ VOLUMÊ

CORR. GORR, vfn(std) vm(std)

fO flirerc)

1.517 43.0 '1.513 42.9

2.172 61.5

2,187 61.9

2.849 80.7

2.857 80.9

4.488 127.1

3.720 105.4

5.056 143.2

5.073 143.7

.-- DRY GAS METER ---

cALtBRAT|ON TACTOR "Y'Value Ver¡ation

f numberl (numberì r

1.01 05

1.0131

1.0286

1.0217

1.0330

1.030r

1.0250

1.0304

1.0374

f.0340

1,0264

oRtFtcE -----

VOLUME VOLUME VOLUME

CORR. CORR. NOMINAL Vc(std) Vc(std) Vcr

(fl:t ltirerst ffl

oRrFrcE -----.

CALIBRATION FACTOR

%H@" Value Value Variation

(ín H2O) (rflm l-l2o) ßnH2O't2

1.533

r.533

2.234

2.z34

2.943

2.943

4.600

3.833

5.245

5.245

1.7097

1.7ø97

1.66t 8

1.6618

1.7556

1.7556

1.7859

1.7842

1,7115

r.7099

1.7246

43.4

43.4

63.3

63.3

83.3

83.3

r30.3

108.6

148.8

148.6

1.560

1.580

2.274

2.274

2.995

2.995

4.681

3.901

5.338

5.338

Averege

-0.02

-0.01

0.00

0.00

0.01

0.00

0.00

0.00

0.01

0.01

0.00 Average

43.43

43.43

42.21

42.21

44.59

44.59

45.36

46.32

43.47

43.43

43.80

0.0

0.0

-0.1

-0.1

0.0

0.0

0.1

0.1

0.0

0.0

0.0

f= 1.0264 AH@= 1.7246

Pass

Notes:

I For CalÍbratjon Factor Y, lhe ratio of the reading of the catibrat¡on meter to lhe dry gas meter,

acceptable tolgrânce of indlvldual values from the averagë ls t 0-02- Varialions shown have beèn rounded to n€arest 0-01 .

2 For Or¡fice Câlibrâtion Factor 

^H@, 

the orifice differentlal pressure in inches of H20 that èquates to 0.75 cfm

õf aìr at 68 deg F ând 29.92 inches of Hg, âcceptâbtê tolerâncê of individual vãtues fiom the average is È 02.

Variâtions shown have been rounded to nearest 0.1_

QA/QC Performed By: Dat€: 'l2l31l08
Page 1 of2

Meter Bóx # 11

Date: 06/25109

The Air Compllance GrouF, LLC

EPA Method 5

Met€r Box Callbration

Post.Test Orlfice Method (Full Calibration)

DRYGAS METER READINGS

Baromelríc PressürÊ: _?{989_ (h. HS)

Theorelhal CriticalVacuum: 13.61 (¡n. Hg)

Câl¡brafioil Techniciân: MSH

ÂH

(ln H2Ol

027

0,27

0.58

0.58

1.1

1.',1

1.8

1.8

J,¿

3.2

Time

fminì

5

5

5

5

5

5

5

5

F

5

Volume

Total

fr1

1.509

1.517

2.225

2.197

2.925

2.896

3.759

3 759

5.092

5.093

72.0

72.O

71.0

72.0

74.0

74.0

7s.0

75.0

T7-O

77.0

æ,0

79.0

68.0

69,0

70.0

70.0

71,0

71.0

72.0

72.0

72-O

72.0

77.0

79.0

70.0

70.0

70.0

70.0

70.0

70.0

Volums Vo¡ume

lnitial Final rfl rfr1

486.663 488j72

488.172 489.689

449.689 491.914

451.914 494.1 11

494.111 497.036

497.036 499,932

4S9.932 503.691

503,691 s07.¿150

507,450 512.542

512.542 517.635

InÍtíal Temoerature

lnlet Outlet

fd€qf) Jdeg Fl

70.0 ô8.0

71.0 08.0

72.A 6S.0

74 t 70.0

74.O 70.0

75.0 71-O

75.0 71.0

77.0 72.0

F¡nel TempeElure

lnlet Outlet

{deo t} ldeo Fl

CRITICAL ORIFICE READINGS

Ambiênt Temoerature

Alrerâûe Temoerature

ÐGM oGM ,qmbient Outlet Overall TemP

(dea Rì (deg Rl tdeo R)

528 0 s29.3 530.0

528.5 530.0 530.0

529.5 531.3 530.0

530.0 532.0 530.0

530.5 532.5 530.0

531.0 s33-0 530.0

531 5 533.8 530 0

532.0 534.5 530,0

532.0 535.0 530.0

532.0 535.5 530.0

Orifice Actual Serial# K Orifice Vacuum

{number) Coefficlent (ln Hq)

KS-40 0.2406 23.0

KS-it0 0.2406 23.0

KS-48 0.3497 22.0

KS-48 0.3457 22.0 KS-55 0.4591 20.0

KS-55 0.4591 20.0

KS-83 0.5898 19.0

KS-63 0.589S 19-0

KS-73 0.8057 16-0 KS-73 0.8057 16.0

lnfrial

(deg Fl

70,0

70.0

70.0

70.0

70.0

70.o

70.0

70-o

70.0

70.0

Fìnal Averäge

lde¡ Él ldeo Fì

70_o 70.0

70.0 70,0

70.0 70 0

70 0 70.0

700

70.0

70.0

70.0

700

70,0

IMPORTAI'IT:

For val¡d test Þsufts, the Actual Vacuum should be at least 1 to 2 in. Hg greaterihan thé

Tlleoret¡cal Critìcal Vacuum sho'¡,/n above.
Page 2 ot 2

Meter Box # 11

Date: 06/25109

The Air Complíance Group, LLC

ÊPA Method 5

Meter Box Calíþrat¡on

Post-Test Orifìce Method (Full Calîbralion)

RESULTS

Barometríc Pressure; 28.86 (ín, Hg)

Theoret¡cal CriticalVacuum: 13.61 {fn- Hg)

Calibration Technician: MSH

--.- 

oRtFfcE

VOLUME VOLUME VOLUME

CORR. CORR. NOMINAL Vc(std) Vc(std) Vcr

Gl flitenì (t'l

- 

DRY GAS METER 

-

VOLUME VOLUME CORR, CORR. vm(std) Vm(std)

lfrt) lliters)

1.453 41.1

1 .458 41.3

2.135 60.5

2.105 59.6

2.804 7S-4

2.n4 78,6

3.602 102.0

3.597 101.9 4.8S5 138.3

4.881 138.2

- 

DRY GÀS METER 

-

GALIBRATTON EACTOR

'Y" Value Variation

lnumber) (number)1

ORIFICE

CÂLIBRATION FACTOR

'ÂH@" Value Value Variaü'on

lin H2O) lmm H2Oì (in H2O)2

1.508

1.508

2.192

) 40t

2 878

2,878

3,697

3.697

5.050

5.050

1.6r03

1.6088

1.ô328

L63f3

1.7933

1.7916

1.7747

1,7730

1 6891

1.6891

1.6994

42-7

42.7

62-1

6?.1

81.5

81.5

104.7

104.7

143.0

143.0

40.90

40.86

41.47

41 49

45.55

45.51

45.08

45.O4

4290

42,90

43.17

1.570

1.570

2.282

2.2ð2.

2.996

2.996

3.849

3.849

5.258

5.258

Averâge

1.0383

1-0342

1-0265

1 .0410

1.0262

1.0374

'1.0264

1.0278

1.0338

r.0346

f.0326

0.01

000

{_01

0.01

-0.01

0.00

{,01

0.00

0.00

0.00

0.00 Average

4,1

{.1

{.1

{.1

0,1

0.1

0.'1

0.f

0.0

0.0

0,0

ration Factor Gamma (Y): 1.0264

Test Avg. Gamma (!ooo¡): f .0326

0.00ô2

of Y: 0.0513

s 5o/o of Y? yes

Note:

The Variation [absolute value of the Cal¡brat¡on Fac,tor Gamma (Y) minus the Post Test Averâge Gamma (Y(e*tt)l

must bê less than or equâl to 5% of Câl¡brâtion Factor Gâmma (Y),

QÂ,/QC Performed By:
THERMOGOUPLE CALIBRATION DATA

Meter Box lD: 11

Meter Box Thermocouple: Stack Temp.

Reference Calibrator lD: 875228

Reference Calibrator Model: HH71 CAL-K

Reference Calibrator Type: K

a Difference, % (Based on degrees Rankin):

Absolute Difference =

b Average Absolute Difference must be 31.5o/o.

Calibration Performed By:

O¡/QC Check Performed By:

Averageb I o.t

Pass/Fail ? | Pass

01/09/09

Reference

Point

Reference

Temperature

loFl

Thermocouple

Temperature

fotrì

Absolute

Dìfferencea

(o/^\

1

2

3

4

5

6

7

I

I

10

11

0

32

100

212

300

400

500

600

700

800

900

2

32

100

213

300

401

500

601

700

802

s02

0.4

0,0

0.0

0.1

0-0

0.1

0.0

0.1

0.0

0.2

0.1
THERMOCOUPLE CALÍ BRATION DATA

Meter Box lD: 11

Meter Box Thermocouple: Probe Heat

Reference Calibrator lD: 875228

Reference Calibrator Model: HH7'l CAL-K

Reference Calibrator Type; K

a Difference, % (Based on degrees Rankin):

Absolute Difference =

b Average Absolute Difference must be < 1.5%-

Galtbration Peúormed By:

OA/QC Check Performed By:

Averaget I o,t

PasslFail ? I Pass

01/09/09

x 100

Reference

Point

Reference

Temperature

1"tr\

Thermocouple

Temperature

f"F)

Absolute

Ðifferencea

lo/^\

1

2

3

4

5

6

7

0

32

100

212

300

400

500

0

32

102

212

300

402

900

0.0

0.0

0.4

0.0

0.0

0.2

0.0
TH ERMOCOUPLE CALIBRATION DATA

Meter Box lD: 11

Meter Box Thermocouple: Filter Heat

Reference Calibrator lD: 875228

Reference Caliþrator Model: HH71 CAL-K

Reference Calibrator Type: K

a Difference, % (Based on degrees Rankin):

Absolute Difference =

b Average Absolute Difference must be 11.5o/o.

Calibration Performed By:

QA/QC Check Performed By:

Averageb I o.r

Pass/Fail ? I Pass

01/09/09

Referencê

Polnt

Reference

Temperature

l.trl

Thermocouple

Temperature

f"F)

Absolute

Ðifferencea

(o/"\

1

2

3

4

5

6

7

0

32

100

212

300

400

500

0

32

101

212

300

401

502

0.0

0.0

o.2

0.0

0.0

0.1

o.2
THERMOCOUPLE CALIBRATION DATA

Meter Box lD: 11

Meter Box Thermocouple: lmpinger Exìt / )(AD Condenser

Reference Cafibrator lD: 875228

Reference Calibrator Model: HH71 CAL-K

Reference Calibrator Type: K

Date: 01/09/09

Average I I

Pass/Fail ? I Pass

(a) Absolute Difference must be < 2"F.

Cafibration Performed By:

OA/OC Check Performed By:

Reference

Point

Reference

ïemperature

f"Fì

Thermocouple

Temperature

loFì

Absolute

DÌfferencea

loF\

1

2

â

4

5

6

7

I

I

0

10

20

32

40

50

60

68

80

0

10

22

32

41

50

60

69

82

0

0

2

0

1

0

0

1

2
TH ERMOCOUPLE GALIBRATION DATA

Meter Box lD: '11 01/09/09

Meter Box Thermocouple: Auxillary

Reference Calibrator lD: 875228

Reference Calibrator Model: HH71 CAL-K

Reference Calibrator Type: K

(a) Absolute Difference must be s 2"F.

Calibration Performed By:

OA/OC Check Performed By:

Average ¡ 1

Pass/Fall ? I Pass

Reference

Point

Reference

Temperature

f"Fì

Thermocouple

Temperature

l"Ël

Absolute

Differenceg

I'Fì

1

2

3

4

5

o

7

I

o

'10

11

0

32

100

212

300

400

500

600

700

800

900

0

32

100

214

302

401

500

600

702

800

902

0

0

0

2

2

1

0

0

2

0

2
THERMOCOU PLE CALIBRATION DATA

, Meter Box lD:

Meter Box Thermocouple:

Reference Calibrator lD :

Reference Calibrator Model:

Reference Calibrator Type:

11

Meter lnlet

875228

HHTlCAL-K

K

01/09/09

Average I f

Pass/Fail ? | Pass

(a) Absolute Difference must be < 5.4"F.

Calibration Performed By:

QA/QC Check Performed By:

Reference

Point

Reference

Temperature

/ôtr\

Thermocouple

Temperature

I'Fì

Absolute

Differenceâ

loF\

1

2

3

4

6

7

8

I

10

1'l

0

32

50

68

80

90

100

1lo

't20

130

140

0

32

5l

69

82

90

101

112

120

130

141

0

0

1

1

2

0

1

2

0

0

1
TH ERMOCOUPLË CALIBRATION DATA

Meter Box lD; 11

Meter Box Thermocouple: Meter Outlet

Reference Calibrator lD: 875228

Reference Calibrator Model: HH71 CAL-K

Reference Calibrator Type; K

(a) Absolute Difference must be s 5-4"F.

Calibration Performed By:

QA/QC Check Pe¡formed By:

Av€rage | 1

Pass/Fail ? | Pass

Date: 01/09/09

Reference

Point

Reference

Temperature

I'Fì

Thermocouple

Temperature

f'Fl

Absolute

Differenceâ

I"Fì

1

2

3

4

5

6

7

I

I

10

11

0

32

50

68

80

s0

100

110

120

r30

140

0

.)¿

50

69

81

92

101

110

120

131

142

0

0

0

1

,|

2

1

0

0

1

2
AGG Field Nozzle Galibration Form

NOZIe Set ID: SÍLIOA COATED SET K

Date: 7/09/08 Tectrnician: JBS

where:

u Dr, z, g, = three different ¡odes diameters, mm (in.); measure to the nearest 0.025 mm (0.00f in.)

b 

^D 

= maximum difference between any two dÍameters, mm (in.), 

^D 

#(0.10 mm) 0.004 in.

c Dara = âv€râgê of Dl, Dz, and Ds,

Nozzle ldenlification Number

No2e Diametef

mm ^D,b(in.) Du*"

Dr,

Mm (in.)

Dz

mm(n)

De,

mm (in.)

K1 o.117 0.117 o.117 0.000 o.117

t<2. 0.175 0.175 0.176 0.001 0.175

K3 o.240 0.240 o.240 0.000 0 240

K4 0.350 0.350 0.351 0.001 0.350

K5 0.370 0-370 0.370 .0 000 0 370

K6 0.427 0.427 0.427 0.000 Q.427

K7 0-489 0.489 0 490 0.001 0 48S
AGG Field Nozzle Calibration Form

Noz|eSet ID: SILICACOATED SETJ

Date: 709/08 Technician: JBS - -.

where:

" Dt.r,", = three different nozles diamelers, mrn (in-); measure to the nearest 0.025 mm (0.001 in.)

b ÀD = maximum differmce between any two diameters, mm (in.), aD #(0.10 fim) 0.004 in,

o Dars = average of Dl, þ, and D3.

Node ldentification Numbe¡

NoZe Diametef

ÂD,b

mm (in.) D"vg"

D1,

Mm (in.)

Dz,

mm (in.)

Dg,

mm (¡n.)

JI 0.'116 0.1 16 0-116 0.000 0 116

J2 0.1 75 0.175 0.175 0.000 o.175

J3 0240 o.240 0.241 0.001 0.240

J4 0.301 0.301 0.300 0.001 0.30'1

J5 0.365 0.365 0.365 0.000 0,365

J6 o.427 o.427 o-427 0.000 o.427

J7 0 501 0-50'l 0-501 0.000 0.501
ACG Field Nozzle Calibration Form

Nozzle Set lD: Glass Nozzle Set B

Date: 4-6-09 Technidan: FPc

Nozzle ldentification Number

Nozle Diameteru

mm ^D,b(in.) Durgo

Dr,

mm (in.)

D2,

mm (in.)

. D:,

mm (in.)

B1 0.156 0.156 0.1 56 0.000 0.156

.82

0-1s6 0.156 0.156 0.000 0.156

B3 0.185 0.1E5 0.185 0.000 0.'18s

B4 ,185 0.f85 0.185 0.000 0.185

B5 o.218 0.218 0.218 0.000 0.218

B6 0.225 0-226 o.225 0,000 0,225

87 0.250 0.250 0.250 0.000 o.250

B8 o.25A o.250 0.250 0.000 0.250

B9 0.250 0.252 0.253 0.000 0.250

Bt0 o.279 0.280 o.279 0.000 0.275

811 0 2B0 0.280 0.280 0.000 0.280

812 0-310 0.310 0.310 0.000 0.310

Bl3 0.310 0.310 0.310 0 000 0.310

814 0,375 0.375 0.374 0.000 0.375

Bl5 o.374 o.374 o.374 0.000 o.374

816 o.440 o.44t o.440 0.000 0-440

B'17 0.436 0.436 0 436 0.000 0.430

Bl8 0.s00 0.500 o.500 0.000 0.500

819 0.500 0 500 0.500 0.000 0.500

B.20 0-624 0.624 o.624 0.000 o.624

8.21 0.023 0.623 0.623 0.000 0.623

B.22 o.742 0.742 0.742 0 000 0.742

B.23 0.000

B.24 0 805 0.805 0.805 0.000 0.805

where:

u Dr,z, s, = three different noZes diameters, mm (in.); measure to the nearest 0.025 mm (0.001 in.)

b 

^D 

= max¡mum differênce between any two diameters, mm (¡n.), ÁD #(0.10 mm) 0.004 Ìn.

" D"* = average of D1, D2, and D¡.
The Alr Gom¡llance Gro¡¡p, ll-G

PrèTêst TheÍttroËoüpb Sy¡tsm CalÞrrúIon Fo¡m

*n (- v -tq

Feftrmed Êt': FI}L

ProüÊ StackTt lDl PL-Þì-l

F¡rgrHearcrrc w ún I+ ß* f

-

UnúlícållD: t ,-{flt- \

lmphgorTclÞ. U ALf

XADCTT*r¡ssTClE

MeÞrlnletTtlD:

MefrêrouËel ïC lD

Meler Box tD:

h

7

7

RÉreÍceTemo. fÞf fteTe¡ÉTenro. tts) melgræ¿"Ef

1z *?tr* t

f7 Ftbr HeelerTc

å

fr llfdndËr TE {z û

XAÞ.GsnCEETæ

fz It¡later fnleûjfQ 17 t

fz Meær_OrüetïC {t r/

. Ä¡cæÉnc$giteria'

' r ilu* ùe *, amt*Èfrt hmpËrË[lre, or any o6er ænpe¡af.rre, wlüln tlË rarge epeclfied by he m4nufarUrer'

¿ M u* meef É|e fufouríru Þfl¡pe¿"dæ dfierencesc

' FrobestackTÐ nrustbeuilhht2'FtfhelË{ereræbmqtr€üß

. F¡nBr Èl€sur TC rmsl b9 rÚthin È ?"F trüe reaereræê lÉTnoelìúfie'

rust be$flhin + 2lF aft¡e refeænce tarTtper6ùJre

rrust bÊvrÐÉr r f F o{ üÊ feÉrË¡Ëê ErrTçraffa

Met€r lnlet Tc ûust be ü{Ëdn t ãF of Ûte refere¡æe Emperatr¡rR

MehrüfiÞt TG mrHbEr4dtffi * 2"F(t'üËl€fêt€ncÉ Fnperaù¡t€.

RderErEE ltËmøïeEr lû ¿qlry f

lmdrgerTC

,fiT}TC

O¡¡CÉ-FerÞ¡m€d nri *,6'ìø
The .Air Go¡nplíance Group, LUC

Post-T€Ét Thsrmoaotple Slrstam Gallbration Form

Date: 6 -tl*oq Job lD:

Pe¡brmed av FÎL corÉradf,to.:

ReferenceTherrnometer tD: ¡1¡ ffr4 -T

Meter BÐ( lü 7

ProbesÞackrttD: Pt*'À l- |

'r.rrnbf,faãllD: l)- (dt ^ L

ÙletsldetTC lÐ: -Å

Mêfief OuÚeT TG ID: J

Rdererrce Tenra- f oF!: Fost-TestT€mD. foFì Difiererrca {ts}2

d

P¡obeStackT0 7T û0

71 Itdeter lild TC 7[ {'

75 Mêfêr OuüeÈTC 7t tÐ

ÁÊcsptance Crfiefla

'. r Must åe et ambient ternpërät¡re, or any other temper€tJre, wiúrín the raqge specified by üre marrufacfi¡ree ' t {* meeilhefûllowirg lernpenah¡re dfFsences;

FrDbe Ståci( TC rnust be wlthrï É fF of the refereflce tempemture.

.rcmr hbt TG must be withín t 2'F of ths reference EmperåiutÞ.

Meter Oullet TC musl be rv{thÍn + fF of the reÞre$cê t€fiÌp€râUrÞ.

GAfQGFerfomed By: ¿f- tì'¿4
' theÄlrcfirpllsrce Gmup, LLt

fteTest Thermo*ortpb $:æ{em Calbrction ForÍr

DaÞË û-E-Õ4

PerþÍn€d W f{rL

Pmbesrad(ÎGft Þ{,-IT - |

FtrÊrHÊ#rrero, ft Ê[ Ê ]

Itrùil¡cdrD: P U'ftt-I

fmp¡ncerTçt* V +4

)fiDGørdenÊef lClD:

u€tsrrrsetrctÈ 6

H€hrcluü€tT0mt: 7

lÍeûer Bõ¡{ lB VI

RcferetrceTemn toFf FrÞ-TestTefi¡Þ. füFl Dlffe¡encsfF¡Ê

ç7 PrebeSffiTC f8 ]0

f7 FilârFIêd€rTC

Ç¡ Òo

f7 funoù¡oerT0

# t0

XAD CorìdenserIc

fz U*Þil¡r€ülç fe rû.

fz G{E{erûiletTC

f4 f

.åoc+ptance tf,qîa

t Mlct þ€ d EnËhaú tÊ|np€rfrirB¡ ü any otlEr tHilper*læ, wihin ltre rarge s@fied by lhq manuÞcû¡rcr.

¿ tt¡!¡sl meet he frlüflirq isflperätre ¿itrerenoes

ftab€StdTÞ mustùewlthln*?gofAe reErëræÞmperatw€.

. F¡lÞ Fþðmr TC must be rr¿Illin r 2"F of tF rEf€r€EoB HnpsËüÉ

lû¡fiingerTC nrstbe wihin *ZF of lfie refuerEe EmpËrãture.

. 

)rAD TC m¡ed bêraflhin * 2'F of lhÊ r€fÊrsrcs ÞrpGratlÍe.

M€*ÉtrIfi|€tTG rftJstbe $,frfft È 2T oftha ¡*rsflÉ&np€rat¡reMÉ¡er Ouüet TC mtlstbe r¡viülin r fFof lhe reftre¡rce tsmperature.

RefêrËr'cên*¡rþil¡der , "ttT f{} f
The Air Gompliance Group, LLC

Poct-Tast Thermocouple System Callbrd¡on Fsm

Dare: {,- t\-oq Job lD:

PerMBy:

Reference Thermonreter lD:

Meter Box lD:

Probe SEckTC lft

UrnbEtcaj lD:

eAfúlG Fbrfier¡rmd Bl,:

Ð f^)ì- t

Fp l- contråctru",t Iï

r+ 5T tvt {

4

Meter lnletTC lD:

Met€r Ouüel TÊ ÍD:

RdetnceTamo- lFf Poat-Test Ternp. l"F) Diffierence l"FF

7f t

7r t

7f t

Accepúance CfiÊr¡a

t Must be at ambierit ternperatue. oF afly other temperdure, withín lhe range speclffed by lhe manufac{uer,

" Mu*t rneet t¡e fdlor¿ing ternperature diffurences:

. PrÐbe Stack TC iTlust bÊ t¡áth¡n * 2"F fffte reference ternpensturs.

-Mefter lnbt TG rnust be wfüln t ZF of the refererroe temperaturc.

MeterOutleiTC

PtJ-Í0o- I

rflUst bË w¡thln t 2'F of tJre reference temperafure.

6

7
ANA LYZER CALI B RATION DATA

TEST METHOD/AI'IALYTCAL METHOD Test lyletrcd - f\,lefitd 3 I Arnlvlical $Jeümd - Meürod 3A

TEST LOCAïOf'I:

AI'IALEER:

TESTDATE:

'REPORT]NG UNITS

TEST METHOD/ANALYTCAL METHODTest Meúrcd - Method 3 / Analvlical Method - ifeftod 3A

.TEST TEST LocATloN: LOCATION: S00OO TEST DATE; 6/10å009

AIIIALYZER: Carbon Bioxide

IES] DA¡E; WIU'4UUY

ÐATE OFANALYSIS: 6i/1ol2oog 6i/1012009

REPORTING UNITS (PPn,c/oI: %È SPAHI 18.84

[rloÞ: The allowable calibrat'ron error is 296 of span.

DATË OF AÍIIALYSIS: 6/102009

SPAN: 21

RÀNGE

GAS

CYLIN]TERIII

Í¡.4S

VALUË

f96dvt

A¡TflLI¿,È¡T(

RESPONSE

fj6dvl

AE¡¡OLUIts

DIFFEREHCE

fq¿rtul

UAL

ERROR

I%OFSPAI.J

ZFRO Zero Nitroqen 0.00 Ð.00 0.00 0.00

!ltD 4013 12-O2 12-OO g,t2 0.10

{IGH 4022 21 21.00 0.fÐ 0.00

Ð-¡-HER

ÎA¡ÚGE

€A5

CYLINDER ID

t¡A:t

VALUË

fY"dvl

ANALÏ¿tsI(

RESFONSE

f'l6dvl

AËõOLUTE

DIFFERENCE

f9(dwl

UAL

ERROR

flìá flF spÂNl

Zero Nitrocen 0.(Ð 0.00 0.00 0.ûo

r4lD 4013 g.sß 9.S0 0-03 0.15

JIGH 4022 18.84 f 8.8û 0-04 o.2'l

THER
ANALYZE R CALI B RATION ÐÁTA

TEST METHOD/AMLYTICAL |!¡ETHOD Test ltdehod - Méftod g / Analyt¡cal Metrrod - Method 3A

TESTIO0ATION: S00 . TESTDATE; d1lrzws AÍTJALIZER: DATE õF A_¡\IALI6IS;-ffi_

REPORTING UNITS (ppm,%): 7o dv SpAtrl; 21

TËST METHODiANALYTICAL MET||ODTestMethod - Method 3 /,.f{Fly!!çpll\¡lethocf - MethodSA

TESTiLocATtoN: soo Æ; 6t11¡2oog .ANALYZER

REPORTING UNITS 1ppm,%);

DATE OFANALì€I$: 6/1112009

SPAITI: 18.M

RANGE

GÂS

CYLINI'ER ID

g iìt

VALUE

f%dvt

A¡I¡AI-YZEñ

RESPONSE

{+Adrrt

.A$!'IJLUTts

DIËFERENCE

l%dvl

çAL

ERROR

196 0FSPA¡rf

ZERO Zero Nilrooen 0.o0 0.00 0.00 0.00

l,llD 4013 12-O2 12.00 0.02 0.lo .IIGH 4Æ22 21 21.OO 0.00 0.00

)THER

ìANGÊ

GAS

CYLINDER ID

gArË

VALUE

l%dvl

AÍI}aLT¿EK

RESPONSE

f9ddvl

AT'ÙULU I E

DIFFERENCE

ftádvì

çAL

€RROR

f%oF sPAlrì

ZERO Zeru Nitroqen 0.00 0.00 0 fto 0-o0

l/llD 4013 9.S3 9_SO 0,03 0.15

IIGH 4022 14.81 18_90 006 0.32

]THER

Note: Thtj allowable calibration enor is2% of spsn.
Airgas (o tz

A¡rgâs Sp€c¡ätfty Gãses

1272? S, Wenlruof h Avsnuc

Chlcago, lL 60620

1-77$78S3ûm

l¡\Xtl-173-785-1928

u,rw.alrgas-corn

Grade of Product: BpA protocol

Reference Numben 5+12412A569{,

CylinderVolume: 151 Cu.Ft

Cylinder Pressure: 2015 pslc

Valve Outlet: 590

Expfratíon Date: AprO9,2012

Part Numbec Ë03N|7SE15A1066

CylinderNumber: XCOO2772B

Laboratory: ASG - Chicago - lI

Analysis Date: Apr09, 2009

Triad Data Available Uþon Rqguest

Pagø 1 ol 54-121173569€
fffi

DocNumber 00000009051

Caslo mer &' O¡de r I nþrnulìon :

THË AIR COMPTIANQE GROUP

PraxnÍr

5700 Sou th Alameda Streer

I"osÂngeles, CA 90058

Teþhone: (323) 5812154

Prøøir Order Nu¡nber: 07641667.oQ

Custorñer P.O. Number: 02126599

Cuslomer ReJerence Nanbì¡: WA876

I

Ce ntfi ed Co qcen l¡at ío n i'

I . @mønenÈ CAREotl DlOl@E . j

.Rêqu€sl€d Cæsùåtbn; 19 *

Qorttt€d êmæntElbn: lE E4l l$trumÉolUæd; Shftf,olrfmatSE 9N^12.f¡0

AnãlyticslMehod: NolR

- :, .¿Fí M.ullþoht CalÈratþo: 1u14l2ru

rir6tAf,alyds õâtE;

z o rc17.S

Ft 17,98 Z, O

2: O C: l&84

Uôil¡ aß

Dater l0ll5Æ108

' REf€renc6 Stâñdard ìrype: $il$

. ,Ref. Std. Cl'úìder #: tÐ 18693 i Rsf, Std, Co¡s 17,86Vt ' R6t Sld. TrsÊåáþ10 to SRhll # : t/ô, 2t45

: sRM sãñpte # : g+{o

. SRM Cylindêr#: CAþ1qI6€

SmFdAn3¡ysl¡ D¡ã:

,4nolltXøI Doto:

2. Cmponeah o¡fiCEl¡

RéqtÞslEd cffinhâtiÖn:

Ce¡t'f ied Cmccnlrâlion:

' lngtumerìt Usod; ' Amlyliel filatho'd:

Lâsl Mullipôi4t CåtibrÊtþn:

¡A,=aeærenn Vtna"rt, Z¿zero Gast C#as Candløtøl j1

ta_84

18.84

f8.Ê4

18è4 o/"

0

0

0

o9{

Zi

¡ù

UOH

c: 18-84, Côilc:

C: 18.84 conci

R: 17.æ @nc¡

Meil TËtÂssay:

21%

21

orYrìúÂT5Ë

PAR¡¡T'AGI'¡ENC

1At4tmæ

0k0G¡OOonc;

0 2.. D g: 0 60nci

0 c: 0 R: 0 cotÉ:

t '/o Item T€t AEÈry:

Rofsrencs St4dard Typo: Gllls

Rêr. Std. Cyfind€r# ¡ S4116¡S

Ref. Sld, Conc.: 21.02o/r

Raf. Sld. Tra;óâblø to SRM # : 26594

' SRM sample #: 7l-t7-8

SRM Cy'inter# : CW m6-/34

$eændAndysl3 D¿tâ: ' Dale:

Z:oR:OC:o-Gonc:

R:OZt0CrOConci

Z0C:0RroConc:

UOil: "A VleæTest^ssay:

.,a

t'rf,

I i..

.tI

U

o

0

0%

Fêter Ngo

certined*,Ek#_

',.r

i!"

Èt yourfequest Dy $alifisd exp*tê wihh Praxa Ëmlh qf tlÉ snalytlcal

of th€ *ecifÊ amlyser pêdôrñåd, wg mdrÉ no âny purpffe. Tho

Fny usê ûf tlÉ lnfmaü0n b at the sots discr€lio , b at the sots discr€lio , 

grisirlg grisirlg qll of the

di¡S qrch hrormarlotr'l'

:ing Àur PløtrætlMore Prod.uctive -t

f

Fny usê ûf the lnfmaü0n b at the sols d¡scf€lio

rJsê ot tñ€ ¡rlômallon tr lâ¡nêd hérêh €steÞlished for prcv¡dirig such hformaflotr-i'

t'

Makine 0 ur pl ø¡tætl M ore pro -'""*f'^"'"''"'.d,uc t ive

f

L/ùï

t¡ltl Dsle:

PFiNumhü: NlCD'1904E+S

IatNunht; t09828f03

Ctthìdôt gtilc &.Outlcl: Ag 59Q

Cllhdcì PnEtre & Yott¡il.t 2ü10 P3l f40 cu ft

Expiration Date:

Cylinder Numbe¡:

10t1612011

sA 14077 An alytlcal Uncertainty:

18.14 %

21 ' %

Balance

CARBON DIOXIDE

oxycEt'¡ .;

NITROGEN

xl%

t1 o/o

NOx ppm = l,l/A NOX Vålue6 foÌ Rêfërence Only

I

Cc¡rifcarior InÍormztion: Cefu'frcrltÍøn Ðate: 1Ô115Ì2OOB 7sø¡?; 36 Monlhs Expintion Datè: 1O11512O11

'This cylinderwas certifled accoiding to the 1997 EPATracaab¡lity Proiþcol, Document#EPA€00/R-97/121, uslng Procedure G1

.Do Not Use th'ls Standard if Pressure i€ less than 150 PSIG Í
Appendlx G

Facility Data
Averaqe Data

Plant

Type: Roll

SoufrÞ

PårElrËEr

. íÌrrq

flltaldû9 0€S4

È.à tsr,gôa,sæþ' 'sas*@ loitÆ 2.q

1¡lSrl2tl,8fiL0

oÊJtaÐs 08110 2ß43 8.1 148,0¡gOt1.0 4.gl

100Ét +Ð1

0qfl0/0â &2 28.a3 d.r¡ 1i4a2 4.S1

0Ell0¡09 08¡e1 6.ú 5.s 150,0¡10.350.0 537.0û 1t43t 2æ,

06fi0¡!s û¡¡2É ?8.83 s.7 14t,736,æ5.û S3?¡0 tûtõg 2.V.

ruär 2æ

tùtrE 262

oÊf1e& 0*s9 '" at¡s ---'- -- - 'ãã--'----'r¿c¡s,oôì-,ii'--'''- 3Sû

ffiloiGt Flroiçl 08:07 od:u/ 2$¡3 zs.Et 0.1.1 t,t9,1Éno.O l,t9.1r1n0.0 ffiffi--oe¡s --zo¡s**-***-*'-*ãË

oillum fE.2B 28.83 E.i råb¡¿zû,'eÙ{r - ""' ' s6Ë,o0" .twiþ 2.W

m,iûiir-*'-0e?e------zû.s3- *-"s.1.-*^---î{ä;îË{så,0:D---:- *-*'CFø --------"*i-û{4¡- z-.sz'-'-

. oq¡fü0s fffro 26ür s.g 149,8æ,212.0 5ft8l)0 1Ð.f,33 2.52

Ítôfl0/üì æ32 26.83 6.7 l4E4S.l !c.0 *lÌ-'t f03.8{ 

08/10,€t 08;33 &.Ê 6.û "'2 150.5fl36¿0 t36.00

-- slil.oi¡ -' - - " 'roiia'-'--' 3-fit -' '

'sriiro 'ioc.r/ " +eo

0€¡r0ffi ql50 26,&¡ ã.1 t¡19,63t.062.0 filEÉO 104.4.8 tJ8

r-96

Rêport Pedod: 0EiI10f20Og 08:04 Thrcugh ftûfi@oOg 1ù.48

Fme Online Cr¡Þflþ: f r¡{nute(si

F = UnÌt Offllne

| = lnvalid

E = Erceedance

]fl = lllaintenance

C = Calibration S=$ubstltuted

T = Out Of Gonlrol * 

= Suspec-t

Reporl Generded: 06/10/@ 1 152 Report Version 2.3. I ty29 1st8
Averaoe Data -

TyPer Roll

Report Period: 06/10/2009 08:04 Through 06/10/2000 10:48

TimoOnlhe Critería: I núnute(s)

Sou¡cè

Fìarãrnêt€r

{UniU

00110¡W 08ú,r

06110¡09 6-{5 +.Àa

owroJu 08ff z?2

ffi Lrue---oa,-õi---**'îf '^-

06í0i00 o8i6 3/5

0410rû9 0ÈÐ0 3,45

os,iq,ûs- 'ail'lb' " ' "'- 

r+ç

06flfHxl

oE¡l{llrp

õåiÌffiñ'-îr{lgfËtfûÆ€ üf!:1¡f 3.45

tir¡í¡rfl s'- Glg**-*'--* - i'{5- -' --.

orriooó -iiääF'"- '-- -'- ú,ø

{lc¡lûlxl 0817 3..15

Éioß*--ìstist!6ffflfitÐ 0a:lÐ 3.rlç

äi¡äiffi e 

=ffi --- -- - -sÆ-- 

--

00riõÉö --æä-*--"---- 3.i5- 

--''

öüìio,!s iriizt " als

0¡iì0,tå" "0il,23-------¡.-iÉ----

iËirî,td* Eäi" ""- =--f --

öarcme--os-¡s* ---ù:¡i--

iÈr'dÅÉ- -ori26- - --' -"--255""-'

06frsÐs oa27

ûü¡1tl@ 0Ê;28

2.7ß

2.2ß

{ts¡lürw 08:29 Zæ

o{üi-qtii"iÈåái " --"-- '"-zä""-'"'

t'siõÊñ-' -æ::a- - - ------*'¿iÉi..-- 

"

oÈ¡roms ær# -' '- " àÆft¡l-o4€- - ñäi*--**-'- ?:iÏ¡-*-'

o-sr1'dñË-*õilrË-------*z-j¡s*-"*

oo¡ä¡ns- -- m*:ts--*"*---' "-es 

--

oefcüúä-'-dffi7_- - -"'äili*-'

öÉfromö -"0ûráç- 'ilss

06r'rúts' oö:iË- -'-"''-'*'ädË---"

O6/lût09 0&r4¡t 2t5

dil*õñö--õõ¡î--'-- - -æ' *--

ffi -o¡ug-ogúf2---*'*¿Ë---' b¡Èiðloe"'t'sl*t*-' -" - ---'1.âf-- -'

bê,iioñö'- ¡äl.iT"- "" -"'"" ".ãr¡Ë '

06rlsDå oo'i5 ' -" -- ""ä.dd - 

-

õqi'diùË":õe-:¡s -- -- -*-" -frÉ --* 

-

ffirïfr-- Elz------25Ë-*-

óifüt/{ir -*oË,4s - --2,Æ----

(E11û09 lÌû:,+ll

Gfftom 0850

2_M

1J0

F = Unlt Off,ine

| = lnvalid

E = Exceedance

M = Itlaintenance

C = Galibrafion

T = Out Of Control

' ReFort Version 2,3. l02s

S = Substituted

* 

= Suepect

Raporl Geierated; Ofl 10109 1 I :52 2ú8
Pl¿nt:

RcportPerùf: 0€U1tr2fÐS 0ä;O4 Thraush 0tr10Æ009 10:49

Soulw

Pârflneter (UfiÛ

0910r[9 0ry5{

0Ê/10iûs q5¿ 149,?57810.û

535¡0 tf¡4.9s 4.t€ rrfions M2È ' '- ¿äb 5.8 -'flS,ZdOþsr.o $ari.ft0 'ior.e+ 4ã

õfi1¡rffi--6ä- ---- firìæsîoão -- -_--ìô1-3T --4.üs-..--

ûgtøfro üsr rEEs ' 

. 

'5.9 fiti.izsn-¡

o6riñs- 00ä2- ---- 

--2Àæ -.ií.é-- -- 'rdr-e¿jæ.0 137,00 ro{Æt {,ç5

517.ffi ro*-z8 ¿6s

06riû¡ro-oæ¡- %&1---T:E---:¿s,Ëio,9g7:õ-.--"_,**.ÉFã¡0:.----*---ì0rãi---.*

74.Ë{.559.St

F= unltoffllne E = Excæedance c= Galibration s = subslituted

l=lnvalid M=llainüenance T=OutOf Gontrol * =Suspeçt

RESorl Gêneråled: 06/1 0i0ü I 1 rõ2 Report V€rsbn 2-3,1029 3 of8
TimeOnline C¡Íbria: 'l minub(s)

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Type: Roll

Report trerbd: 06/f0X200S 08S4 Thror¡gù 06tlttl2fXlÉt 10:48

Soüroê

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Report Pedod: 0il10t2009 08:ll4 Throqgh 06110Æ0ffi 10:48

Time Online GrfÞría: I minub{s)

Êource

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R€pod Genefãled 06/10r{F 1l:5¿ RêÞort Vêr8ion 2,3.1 û29 6 of8
Plânt

Type: Roll

Report Peniod: OWf 0/2009 08;0,f Thruugh 06fl0/2009 10:48

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Repol Perbd: O6/f0/2009 15:45 Throrgh 0ry10i¡2009 1BtO6

Tltne Orrline C¡ileria: f nûnrte(s)

R€porf GÉflsrâbd: .Ofll{U0Il f 8:35 Report Verslof¡ 2,3,1 û29 I of6
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112

112

F = Unlt Offlne

I = lnvalld

E=E¡rceedance G=Calibralion S=SubstitutBd

[¡T = irlaintenance T= OutOf Gontrof * 

= Suspect

Repofi Generafed: 06/'f0/û9 f8:35 REpoil Vers¡or¡ 2,3. 1029 6of6
Plan

Report Perlnd 0Ê¡11/2009 07:53 Through 06/11/2009 1û:12

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Råpo¡t Ge¡teøed: 06f11/@ 12:10 Report Version 2-3. lO29 I cf 6
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Report Version 2.3.1 029

S = SuÞstlfirlod

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2o,IA
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Beport VmÉon 23,1t)2Ð

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Report GenereH: 06/1 1/08 12:10 4of F
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Source

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valve Vacuum

gauge

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Dry gas meter Vane pump

Figure 5 - EPA Method CTM-0138 Sampling Train

19

4.2.3 Gondensable Particulate Analysis - EPA Method 202 The total

condensable particulate matter in the back half of the sampling train was determined in

accordance with Method 202 procedures. The impinger contents and aqueous rinses

were combined with the methylene chloride rinses and extracted twice with methylene

chloride using a separatory funnel. The sample was divided into organic (methylene

chloride) and inorganic (aqueous) fractions. The organic fraction was evaporated at

room temperature and pressure, and the resulting residue was analyzed gravimetrically

to a constant we.ight.

The total condensable particulate matter in the back half of the EPA Method 5 sampling

train was determined in accordance with Method 202 procedures. The impinger

contents and aqueous rinses were combined with the methylene chloride rinses and

extracted twice with methylene chloride using a separatory funnel. The sample was

divided into organic (methylene chloride) and inorganic (aqueous) fractions. The

organic fraction was evaporated at room temperature and pressure, and the resulting

residue was analyzed gravimetrically to a constant weight.

The inorganic fraction was evaporated to dryness at 105oC, and the residue was

analyzed gravimetrically to a constant weight. Since the pH of the original solution was

greater than 4.5 and the optional ammonia addition step was omitted.

The back-half condensable particulate catch was equal the organic residue plus the

inorganic residue.

4.2.4 Gondensable Particulate Analysis - EPA Method OTM-28 Condensable

particulate matter was determined in accordance with EPA Other Test Method 28

procedures. The water soluble CPM was extracted from the CPM filter and the

aqueous extract combined with the contents of Container 1. The organic soluble CPM

was extracted from the CPM filter and the organic extract was combined with the

contents of Container 2. The aqueous impinger contents in Container 1 was placed in a

20

separatory funnel and extracted twice with 30 ml of methylene chloride. This organic

extract was combined with the organic train rinse in Container 2.

The organic phase extracts and rinses in Container 2 were placed in a beaker and the

volume reduced to less than 10 mL at room temperature. The beaker contents were

then transferred to a pre-weighed tin and evaporated to dryness at room temperature.

Following evaporation, the organic fraction was desiccated for 24 hours, and then

weighed at 6 hour intervals to a constant weight.

The contents of Container 1 (inorganic fraction) were transferred to a clean beaker and

the volume reduced to less than 10 mL at 105oC, and then allowed to dry at room

temperature. The residue was re-dissolved in 100 mL of deionized distilled ultra-filtered

water. Titration with 0.1 N NH4OH was used to neutralize acid in the inorganic sample

and remove water of hydration. The volume of titrant used was recorded. The volume

of the aqueous phase was reduced to about 10 mL at 105oC. The beaker contents was

then transferred to a pre-weighed tin and evaporated to dryness at room temperature.

Following evaporation, the organic fraction was desiccated for 24 hours, and then

weighed at 6 hour intervals to a constant weight. The weight of the inorganic residue

was corrected for the NH4* retained in the sample.

4,2.5 condensable so¡/Hzso¿ - EPA Method cTM-138 sample analysis was

performed using lon Chromatography with conductivity detection.

4.3 Data Analysis Equations related to the pollutant sampling, including gas flow

rates, temperatures, percent isokinetics, and moisture content are shown in Appendix C.

The test results are reported as mass rate in terms of both lb/MMBtu and lb/hr.

Emissions in lbiMMBtu is calculated using the dry oxygen-based fuel factor for

bituminous coal (9780 dscf/MMBtu), which is published in Table 19-2 of EPA Method 1g

in 40 CFR 60.

21

4.4 Equipment Calibration Field equipment was calibrated in accordance with the

requirements of the applicable EPA Methods, and with those recommended within the

Quality Assurance Handbook for Air Pollution Measurement Systems: Volume lll (EPA60014-77-027b, August 1977). Appendix F contains records for all the calibrations.

22

Appendix A

Test Log