APPENDI X J FEEDSTREA M ANALYSI S PLA N

# FEEDSTREA M ANALYSI S PLA N

Veolia E S Technica

l Services, LL C Sauget , Illinoi s

Octobe r 200 8Feedstrea mAnalysi s Pla n - Octobe r 200 8


## TABL E O F CONTENT S

1. 0 INTRODUCTIO N 2. 0 FEEDSTREA M PARAMETER S 2. 1 Chlorin e 2. 2 Metal s 2. 3 As h 3. 0 ANALYTICA L RATIONAL E 3. 1 Analysi s Performe db y Veoli a 3. 2 Analysi s Performe db y Other s 3. 3 Manufacture r

Dat ao r Other Publishe dInformatio n 4. 0 APPLICATIO N O F ANALYSI S FO RFEEDRAT E COMPLIANC E 4. 1 Proces s Plannin g fo r Feedstream s 4. 2 Proces s Contro l fo r Feedstream s 4. 3 Documentatio n andRecordkeepin g fo r Proces s Plannin g an d Contro l 5. 0 SAMPLIN G AN D ANALYTICA L METHOD S 5. 1 S amplin g Methodologie s 5. 2 Documentatio n an dRecordkeepin g Associate dwit h Samplin g 5. 3 Analytica l Methodologie s 5. 4 Documentatio n andRecordkeepm g Associate dwit h Sampl e Analysi s 6. 0 FREQUENC Y O F ANALYSI S 7. 0 COMPLIANC E WIT H FEE D RATE S

1Feedstrea mAnalysi s Pla n - Octobe r 200 8 1. 0 INTRODUCTIO N Pursuan t to the regulator

y requirement s foun di n 4 0 CF R63.120 6 (c ) o f th e HW C MAC T Standard , Veoli aE S Technica l Solutions , LL C (Veolia ) ha s develope d aFeedstrea m Analysi s Pla n (FAP)
. It s purpos e i s t o provid e asystemwhereb y Veoli aca n sample , analyze , an d contro l the incineratio n o f feedstream s tha

t may contai n constituent s requitin g feedrat

e limit s a s specifie di n th

e HW C MAC T Standard
. Th e FA P als o addresse s ho w thes e activitie s wil l b e recorde d i n the facility' s operatin g record
. Thi s FA P i s organize d suc h tha t eac h o f the subsequen

t section s specificall y addresse s th e si x paragraph s unde

r 4 0 CF R63.120 6 (c ) (2 ) an d three paragraph s unde r 4 0 CF R 63.120 6 (c ) (4 ) i n th

e order i n whic h they ar

e presente d i n the HW C MAC T Standard
. I n man y instances , thi s FA P wil l referenc e the facility' s Wast e Analysi s Pla n (WAP)
. Th e WA P i s an integral par

t o f th e RCR A Par

t B Permit , th

e Permi t Application , and an

y subsequen

t revision s o r

addendat

o the Par t B Permi t

or Permi t Application
. A s require d b y section s 63. 6 (e)(v ) an d 63. 6 (e)(vi ) o f th e HW C MAC T Standard , the FA P and othe

r document s containin g procedure s o r informatio n referre d to i n the FA P wil l b e made availabl e fo r inspectio n when requeste d b y the Administrator
. Th e FAP , correspondenc e wit h th

e Administrato r

concernin g the FAP , an d any subsequen t addition s o r

modification s t

o th e FA P wil l b e kep t

i n the facility' s Operatin g Record
. I f Veoli ai s require d t

o submi t copie s o f th e FA P o r portion s o f

i t (or relate d documents) , <j^fiderrtM-busiiie^-in ^ ~ designated
. 2. 0 FEEDSTREA M PARAMETER S Ther e ar e thre e feedstrea

mconstituent s tha

t ar e specifie di n th

e HW C MAC T Standar

d fo r emissio n and/o

r feedrat e limitation s and tha

t mayb e presen

t i n an y give n feedstream
. Thes e thre e are : 1 ) Chlorin e 2 ) Metal s (Mercury , Lead , Cadmium , Chromium , Beryllium , an d Arsenic ) 3 ) As h Thes e thre e constituent s wil l serv e a s th e feedstrea

mparameter s o f

concer n i n the FA P as require d b y 4 0 CF R63.120 6 (c ) (2 ) (I) o f the HW C MAC T Standard
. Feedstrea mdata applicabl e to each o f

thes e parameter s wil l b e obtaine d fo r al l feedstream s i n orde

r t o contro l th

e incineratio n o f

theman d remai n withi n th e feedrat e limit s se

t fo r them
. 2. 1 Chlorin e Feedstrea mdat awil l provid e aweight-base d percentag e o f chlorin e fo r

eac h wast

e fee d t o th e incinerators
. Thes e result s can b e use d t o both estimat

e targete d fee d rat

e value s an d contro l actua

l fee d rate s durin g incineration
.

2Feedstrea mAnalysi s Pla n - Octobe r 200 8 2. 2 Metal

s Feedstrea mdatawil l provid e aparts-per-millio n concentratio n fo r eac h o f th e liste d metal s i n eac h o f

the wast e feed s to the incinerators
. Fo r analytica l result s tha

t sho w les s tha n detectio n limi t

concentrations , V*the detectio n limi t valu e wil l b e use dfo r incinerato r

fee dcomputations
. Thes e result s ca n b e use dt

o both estimat

e targete d fee d rat e value s an d contro l actual fee drate s durin g incineration
. 2. 3 As h Feedstrea mdat awil l provid e aweight-base dpercentag e o f as h fo r eac h o f the wast e feed s t o th e incinerators
. Thes e result s ca n be use dto both estimat e targete d fee drat

e value s andcontro l actual fee drate s durin g incineration
. 3. 0 ANALYTICA L RATIONAL E I n 4 0 CF R63.120 6 (c ) (2 ) (ii ) o f th e HW C MAC T Standard , afacilit y i s require dt o identif y ho w i t wil l obtai n the necessar

y analysi s to compl y wit h thes e regulations
. Ther e ar e thre e source s o f

analytica l informatio n tha t Veoli acan us e i n evaluatin g the feedstrea mparameter s a

s describe di n Sectio n 2. 0 o f the FAP
. The y are : 1 ) Analysi s performe d b y Veoli a- - - - - - - —- - 2 ) Analysi s performe db y other s 3 ) Manufacture r

datao r othe r publishe dinformatio n Thes e source s ar

e als o reference di n th e facility' s WA P andth e way s i n whic h the y ca n b e applie dt

o feedstream s ar

e extensivel y addressed
. Man y o f th e analytica l procedure s performe da

s describe d i n the FA P ar e als o require da

s par t o f th e wast e acceptanc e an

d managemen

t proces s a

t Veolia
. Th e informatio n derive dfro mthes e procedure s can then b e use di n complyin g wit h tli e feedstrea mlimitation s fo r

the parameter s identifie di n th e FAP
. Th e thre e analytica l source s can b e applie dt o generato

r waste s receive da

t the Veoli a facility , includin g thos e tha t underg o subsequen

t blendin g prio r

to incineration , an dals o t o waste s tha

t ar e generate d a

t the facility
. 3.1 Analysis Performed b y Veoli a Th e predominat

e mean s applicabl e to thi s sourc e o f analytica l informatio n i s the methodolog y describe di n Sectio n 5. 0 o f th e FAP
. Specifi c analytica l method s performe d i n the facility' s laborator y ar e applie dto applicabl e feedstream s t o produc e value s fo r the require dparameters . Typically , the feedstrea

mi s awast

e profil e fro magenerator tha t ha s bee n accepte d accordin g to the facility' s WA P guidelines
. Thi s wast e wil l hav e ha danalytica l wor k performe do n asampl e fo r a n initia l acceptanc e decisio n an dsupplemental analysi s a s
3Feedstrea mAnalysi s Pla n - October 200 8 1 l : i i • require dfo r

subsequen

t shipment s o f

the waste . Thi s analytica l wor k wil l includ e | informatio n o n th

e parameter s identifie di n the FA P an dca n b e use dto contro l th

e | incineratio n o f

th e feedstreams
. j I n other instances , th

e feedstream s ar

e waste s blende dtogethe r a t the facilit y (e.g. , bul k

! liquid s an dbul k

solids ) o r waste s generate d b y the facilit y (e.g. , laborator y wastes , incinerato r

ash)
. Feedstream s tha

t ar e the resul t

o f blendin g o r

othe r on-sit e processin g ! step s prio r

to incineratio n can hav e parameter s determine dfro mthe sam e analytica l method s describe d i n the previou s paragrap h o r b y statisticall y arrivin g a t a n averag e ' valu e base do n abod y o f previousl y analyze dsamples
. Waste s generate d b y the facilit y wil l hav e parameter s determine dfro ma n averag e valu e basedo n abod y o f previousl y analyze d samples
. Fo r man y feedstreams , th

e bes t sourc e o f informatio n fo r

th e parameter s identifie di n the j FA P wil l b e obtaine dusin g the technica l expertis e o f Veoli apersonnel
. Example s o f ; thes e type s o f

feedstream s ar

e labpacks , controlle dsubstance s an dempt y containers
. Th e facility' s WA P list s som e o f thes e referenc e source s i n Appendi x WAP-F
. j 3. 2 Analysi s Performed b y Other s I n situation s wher

e Veoli acannot

perfor mth

e necessar

y analysi s du e t o th

e natur e o f the j ' feedstream(e.g. , gases , som e reactiv e materials ) o r

whe n previou s outsid e analysi s o f j feedstreams tha

t meet s th e standard s o f

thi s FA P i s available , Veoli awil l accept th e ~"" T analysi s o f

other s i n determinin g paramete r values
. Thi s analytica l informatio n wil l b e ; evaluate d an duse d t

o contro l th

e incineratio n o f

feedstream s i n the sam

e manne r a s j analytica l informatio n produce da t th e facility
. 3. 3 Manufacture r Dat a or Other Publishe

d Informatio

n Man y feedstream s hav e pre-existin g informatio n applicabl e t o the mtha t ca n b e use dt o determin e th e value s o f

the parameter s a

s identifie di n the FAP
. Thi s ca n tak e th e for mo f manufacture r

specification s an ddata , Materia l Safety Dat aSheets , referenc e source s o r othe r publishe dinformation
. Th e facility' s WA P list s som e o f thes e referenc e source s i n Appendi x WAP-F
. Example s o f thes e type s o f

feedstream s includ e commercia l products , pharmaceuticals , chemica l reagents , andgas cylinders
. Thi s informatio n wil l b e evaluate d an duse dto contro l the incineratio n o f thes e feedstream s i n th

e sam e manne r as analytica l mformatio n produce da

t the facility , j 4. 0 APPLICATIO N O F ANALYSI S FO RFEEDRAT E COMPLIANC E Feedstreamdatawil l b e use dt o maintai n complianc e fo r th e feedrat e limitation s t

o the I incinerators
. Thi s analysi s wil l b e complete dprio r t o th e feedin g o f

an y materia l t

o th e I incinerators
. Th e documentatio n o f thes e feedrat

e complianc e method s i s require db y 4 0 ! CF R63.120 6 (c ) (2 ) (iii ) o f the HW C MAC T Standardan doutline di n thi s sectio n o f th e \ FAP
. j i

4Feedstrea mAnalysi s Pla n - Octobe r 200 8 Analytica l result s ca

n b e use d t

o both estimat

e targete d fee d rat

e value s and contro l actual fee d rate s durin g incineration
. Analysi s fro mlaborator y testin g a

t th e facility , analytica l result s fro mothers , publishe d mformation , an d technica l evaluation s b y Veoli apersonne l ca n al l b e use d i n complyin g with feedrate limitation s fo r the parameter s identifie di n th e FAP
. I n addition , thes e analytical informatio n source s ca n b e use d fo r waste s fro m generators , waste s blende d a t th e facility , and waste s generate d a t th e facility
. 4. 1 Proces

s Plannin

g fo r Feedstream

s Whe n evaluatin g analytical result s and an y additiona l mformatio n applicabl e t o a potentia l feedstream , adecisio n mus t b e mad e whethe

r parameter s fo r

tha t feedstrea mar e acceptabl e fo r

feedin g t o th e incinerator s o r

i f som e leve l o f fee d preparatio n i s necessary . Thi s ste

p i n th e feedstrea

mevaluatio n proces s i s calle dproces s planning
. It i s applie dt o blendin g wastes , processin g waste s int o combustibl e charges , and determinin g i f waste s ca

n b e fe d directl y t

o th e incinerator s a

s initiall y receive d a

t th e facility
. Thi s plannin g i s performe d base d o n informatio n fro manalytica l results , incinerato r performanc e capabilities , proces s operatio n history , and th e technica l expertis e o f th e proces s plannin g personne l involved
. 4. 2 Proces

s Control fo r Feedstream s I n order t o ensur e tha t feedrat e limit s fo r

th e parameter s i n th e FA P ar e no t exceede d -^uring^eratimt^fthe^tie ^ incinerato r

process . Thes e systems continuousl y trac k the feedstrea

mparameters a

s the y ar e introduce d int o th

e incinerator s an d mak

e the necessar

y fee d adjustment s o r

cut-off s fo r compliance
. Sectio n 7. 0 o f th e FA P addresse s thes e system s an d th e rational e behin d thei r operatio n i n greate

r detail
. 4. 3 Documentatio

n an d Recordkeepin

g fo r Proces

s Planning an

d Contro l Documentatio n o f

proces s plannin g an d contro l i s demonstrate d b y th e extensiv e bod y o f informatio n collecte di n th e facility' s dat amanagemen t system , and , i f

needed , distribute d i n har d cop y for mt o appropriate personnel
. Thi s include s laborator y analysi s use d fo r fee d preparation , bul k

wast e storag e data , processin g directions , an d relate d mformation
. Actua l incinerato r operation s datai s recorde d i n printe d surnmaries , recorde d ont

o digita l datastorage systems , and i s als o selectivel y availabl e on-line
. Thi s informatio n wil l b e retaine d i n th e operatin g recor d fo r

th e lif e o f

the facility
. 5. 0 SAMPLIN G AN D ANALYTICA L METHOD S Th e requirement s i n 4 0 CF R63.120 6 (c ) (2 ) (iv) an d (v ) o f th e HW C MAC T Standard stat e tha t afacilit y mus t

identif y the samplin g and tes t

method s use d fo r

analyzin g th e feedstreams
. Th e samplin g methodolog y an d muc h o f th e analytica l methodolog y tha t i s describe d i n Section s 2, 0 and 3. 0 o f the facility' s Wast

e Analysi s Pla n i s applicabl e to the FAP
. Additiona l samplin g and testin g informatio n i s include di n th e followin g paragraph s o f thi s section
.

5Feedstrea mAnalysi s Pla n - Octobe r 200 8
5.1 Sampling Methodologie s Samplin g i s performe d a t the Veoli afacilit y t

o identif y waste shipment s and als o b y th e generator a t thei r locatio n whe n makin g a n initia l determinatio n o n th e acceptability o f the wast e a t Veolia
. I n som

e instances , a

n actua l sampl e wil l no t

b e require d becaus e technica l personne l a

t Veoli awil l hav e determine d tha t sufficien t

documentatio n alread

y exist s tha t identifie s informatio n regardin g th e parameter s describe d i n Sectio n 2. 0 o f th e FA P (see als o Sectio n 4.0 , Paragrap h 4.1.1 2 (2 ) o f th e WAP)
. I n order

t o obtai n a representativ e sampl e o f the waste , specifi c samplin g procedure s tha t ar e dependen

t o n bot h th e natur

e o f the wast e sample d an d th

e typ e o f processe s i n whic h the wast e wil l b e store d o r transferre d mus t

b e performed
. Sectio n 2. 0 o f the facility' s WA P and pertinent appendice s i n the WA P lis t thes e procedure s an d the AST M metho d numbe r (o r othe r EP A approve d method) o n whic h the y ar e based
. Thi s sectio n i n th e WA P als o addresse s th e samplin g equipmen

t used , the type s o f

intende d containment

o r processe s tha

t ca n impac t th e sampling , an d guideline s o n ho w t o ensur e tha t avali dand representativ e sampl e i s obtained
. 5. 2 Documentatio

n an d Recordkeepin

g Associate

d wit h Samplin

g A l l sample s take n a

t th e facilit y o r

sen t t o th e facilit y fo r

analysi s ar

e assigne d auniqu e sampl e identificatio n number
. Thes e identificatio n number s ar e recorde d i n achain-of

custody lo g and used fo r trackin g th

e sampl e throug h th

e facility' s datacollectio n system . Eac h sampl e als o has alabe l affixe dto i t identifyin g it s contents , the dat e the sampl e wa s taken , an d the perso n wh o too k the sample
. 5. 3 Analytical Methodologie s CHLORIN E The analytica l procedure s an d EP A approve d method s relate d to determinin g th e amoun t o f chlorin e i n afeedstrea

mar e foun di n Appendi x WAP- A to the facility' s WAP
. METAL S Feedstream s tha

t requir e analysi s fo r

the metal s specifie di n the HW C MAC T Standard wil l either

contai n thes e metal s i n anon-water-solubl e for mo r awater-solubl e form
. Sample s o f

feedstream s i n anon-water-solubl e for mwil l require additiona l preparatio n step s prio r

t o analysis
. Th e analytica l procedure s an d EP A approve d method s relate d t o determinin g the amoun

t o f liste dmetal s i n afeedstrea mar e liste dbelow
. Digestio n Procedure forNon-Water-Solubl e Sample s Metho d3051 A - Microwav e Assiste dAci dDigestio n o f Sediments , Sludges , Soils , an d Oil sFeedstrea mAnalysi s Pla n - Octobe r 200 8 Procedure fo r

Determinin g Concentratio n o f Mercur y i n Sampl e Metho d747 3 - Mercur y i n Solid s andSolution s b y Therma l Decomposition ,

Amalgamation , andAtomi c Absorptio n Spectrophotometr y Procedure fo r

Determinin g Concentratio n o f Arsenic , Beryllium
. Cadmium
. Chromiu m and Lea di n Sampl e Metho d601O C - Inductivel y Couple dPlasma-Atomi c Emissio n Spectrometr y A S H Th e analytica l procedure s andEP A approve dmethod s relate dto determinin g the amoun t o f as h i n afeedstrea

mar e foun d i n Appendi x WAP- A t o the facility' s WAP
. 5. 4 Documentatio

n an d Recordkeepin

g Associate

d wit h Sampl e Analysi s Documentatio n o f

analytica l wor k

i s accomplishe db y recordin g i t i n laborator

y logbooks , enterin g i t

int o th e facility' s datamanagemen t system , and , i f

needed , distribute di n har d cop y for mto appropriat e personnel
. Al l technica l file s fo r wast e profile s wil l als o includ e initia l laborator y analysi s andany applicabl e subsequen t analysis
. Thi s informatio n wil l b e retaine di n the operatin g recor dfo r th e lif e o f the facility." ' * " 6. 0 FREQUENC Y O F ANALYSI S I n 4 0 CF R63.120 6 (c ) (2 ) (vi) o f the HW C MAC T Standard , afacilit y i s require dto identif y th e frequenc y wit h whic h a n initia l analysi s i s repeate d o r reviewe dto ensur

e tha t i t i s current . Thi s FA P wil l require tha t the analytica l informatio n fo r th e feedstream s b e re-evaluate d o n afrequenc y consistent wit h tha t describe dfo r

al l waste s a

s describe di n Sectio n 4.1. 3 o f

the facility' s WAP
. Th e thre e event s tha t may trigger

anee dt o updat

e or evaluat e th e analysi s o f

agive n feedstrea

mare : 1 ) Generator

notifie s Veoli atha

t afeedstrea

mha s change d 2 ) Subsequen

t analysi s fo r

afeedstrea

muse db y Veoli ai s inconsisten t wit h the origina l analysi s 3 ) Fiv e year s hav e passed sinc e th e las t assessmen

t o f th e feedstrea

m h i order fo r afeedstrea

mt o b e considere dacceptabl e agai n fo r incineratio n afte r

on e o f thes e event s ha s occurred , the evaluatio n proces s a s describe di n thi s FA P mus t b e completed
. 7. 0 COMPLIANC E WIT H FEE D RATE S Veoli aemploy s proces s contro l system s fo r the incinerator s tha

t monitor , adjus t

an d recor dfeedstream s and th e ke y parameter s identifie di n th e FA P tha

t ar e associate dwit h

7Feedstrea mAnalysi s Pla n - October 200 8 them
. Thes e system s mee t the requirement s o f

4 0 CF R63.120 6 (c ) (4) , paragraph s (i) , (ii ) an d(iii)
. Th e system s an d the rational e tha t support s thes e system s ar e describe d i n th

e followin g paragraph
. 7
. 1 Fee

d Rat e Complianc

e System s an d Methodolog

y Afte r the metal s and as h concentration s fo r feedstream s ar

e determined , the y wil l b e entere d into th

e facility' s datamanagemen t systems . Thes e feedstream s ar e identifie di n the systemunde

r asit e trackin g number , bul k

pi t number , or

tan k number
. Onc e thi s informatio n i s i n th

e wast e trackin g system , th e incinerato r contro l system s ar

e abl e t o import an d stor e th e datafo r us e a s th e wast e stream s ar

e processe d a

t the incinerators
. A l l wast e introduce d into th

e incinerator s ha s a

n associate d sit

e identificatio n designatio n (receive r number , etc. ) s o i t

ca n b e reference d t

o th e appropriat

e datafro mthe wast

e trackin g system . A s weight s ar e recorde d a

t 1 5 secon d interval s fo r

eac h specifi c wast

e strea menterin g th

e incinerator , computation s ar e bein g performe d t o calculat e the quantitie s o f

metal s (a

s lo w volatil e metals , sem i volatil e metals , an d mercury ) and ash tha t ar e bein g incinerated
. Thes e quantitie s ar e displayed , totalized , and recorde d i n a manne r tha t wil l sho w complianc e wit h th e establishe d operatin g paramete r limit s fo r

the metal s categorie s and ash
. On e hour and 1 2 hou r

rollin g total s ar

e displaye dfo r

the incinerato r

operator s fo r

monitorin g o f

thes e feeds
.

8