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MSDS : 33979 

# Material Safety Data Sheet

SECTION 1 PRODUCT AND COMPANY IDENTIFICATION

P roduct Use: Lubricating oil additive

Company Identification

SECTION 2 COMPOS ITION/ INFORMATION ON INGREDIENTS

COMPONENTS CAS NUMBER AMOUNT

01154100

- 5341P Trade secret 100 %weight

Note that the chemical identity of some or all of the above components is considered confidential

business information and is being withheld as permitted by 29 CFR 1910.1200 and various State

Right

- To

- Know Laws.

SECTION 3 HAZARDS IDENTIFICATION

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**EMERGENCY OVERVIEW**

- CAUSES EYE IRRITATION

- CAUSES SKIN IRRITATION

- MAY CAUSE RESPIRATORY TRACT IRRITATION IF INHALED

- TOXIC TO AQUATIC ORGANISMS. MAY CAUSE LONG

- TERM ADVERSE EFFE CTS IN THE

AQUATIC ENVIRONMENT

- FOR RESEARCH AND DEVELOPMENT PURPOSES ONLY

- MAY CONTAIN SUBSTANCES NOT

ON THE TSCA INVENTORY

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MSDS : 33979 - TO BE USED ONLY UNDER THE DIRECT SUPERVISION OF A TECHNICALLY QUALIFIED

INDIVIDUAL

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IMMEDIATE HEALTH EFFECTS

Eye: Contact with the eyes causes irritation. Symptoms may include pain, tearing, reddening, swelling

and impaired vision.

Skin: Contact with the ski n causes irritation. Contact with the skin is not expected to cause an allergic

skin response. Symptoms may include pain, itching, discoloration, swelling, and blistering. Not

expected to be harmful to internal organs if absorbed through the skin.

Ingestion: May be irritating to mouth, throat, and stomach. Symptoms may include pain, nausea,

vomiting, and diarrhea.

Inhalation: The vapor or fumes from this material may cause respiratory irritation. Symptoms of

respiratory irritation may include coughing and difficulty breathing. If this material is heated, fumes may

be unpleasant and produce nausea and irritation of the eye and upper respiratory tract.

SECTION 4 FIRST AID MEASURES

Eye: Flush eyes with water immediately while holding the eyelids open. Remove contact lenses, if worn,

after initial flushing, and continue flushing for at least 15 minutes. Get medical attention if irritation

persists.

Skin: Wash skin with water immediately and remove contaminated clothing and shoes. Get medical

attention if any symptoms develop. To remove the material from skin, apply a waterless hand cleaner,

mineral oil, or petroleum jelly. Then wash with soap and water. Discard contaminated clothing and shoes

or thoroughly clean before reuse.

Ingestion: If swallowed, get medical attention. Do not induce vomiting. Never give anything by mouth

to an unconscious person.

Inhalation: Move the exposed person to fresh air. If not breathing, give artificial respiration. If

breathing is difficult, give oxy gen. Get medical attention if breathing difficulties continue.

SECTION 5 FIRE FIGHTING MEASURES

FIRE CLASSIFICATION:

OSHA Classification (29 CFR 1910.1200): Not classified by OSHA as flammable or combustible.

NFPA RATINGS: Health: 1 Flammability: 1 Reactivity: 0

FLAMMABLE PROPERTIES:

Flashpoint: (Pensky

- Martens Closed Cup) 158 °C (316 °F)

Autoignition: No data available

Flammability (Explosive) Limits (% by volume in air): Lower: No data available Upper: No

data available

EXTINGUISHING MEDIA: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish

flames.

PROTECTION OF FIRE FIGHTERS:

Fire Fighting Instructions: This material will burn although it is not easily ignited. See Section 7 for

proper handling and storage. For fires involving this material, do not enter any enclosed or confined fire

space without proper protective equipment, including self

- contained breathing apparatus.

Combustion Products: Highly dependent on combustion conditions. A complex mixture of airborne

solids, liquids, and gases including carbon monoxide, carbon dioxide, and unidentified organic

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MSDS : 33979 compounds will be evolved when this material undergoes combustion.

SECTION 6 ACCIDENTAL RELEASE MEASURES

Protective Measures: Eliminate all sources of ignition in vicinity of spilled material.

Spill Management: Stop the source of the release if you can do it without risk. Contain release to

prevent further contamination of soil, surface water or groundwater. Clean up spill as soon as possible,

observing precautions in Exposure Controls/Personal Protection. Use appropriate techniques such as

applying non

- combustible absorbent materials or pumping. Where feasible and appropriate, remove

contaminated soil. Place contaminated materials in disposable containers and dispose of in a manner

consistent with applicable regulations.

Reporting: Report spills to local authorities and/or the U.S. Coast Guard's National Response Center at

(800) 424

- 8802 as appropriate or required.

SECTION 7 HANDLING AND STORAGE

Precautionary Measures: Do not get in eyes, on skin, or on clothing. Do not breathe vapor or fumes

from heated material. Do not taste or swallow. Do not breathe vapor or fumes. Wash thoroughly afte r

handling.

General Handling Information: Avoid contaminating soil or releasing this material into sewage and

drainage systems and bodies of water.

Static Hazard: Electrostatic charge may accumulate and create a hazardous condition when handling

this material. To minimize this hazard, bonding and grounding may be necessary but may not, by

themselves, be sufficient. Review all operations which have the potential of generating and accumulating

an electrostatic charge and/or a flammable atmosphere (including tank and container filling, splash filling,

tank cleaning, sampling, gauging, switch loading, filtering, mixing, agitation, and vacuum truck operations)

and use appropriate mitigating procedures. For more information, refer to OSHA Standard 29 CFR

1910.10 6, 'Flammable and Combustible Liquids', National Fire Protection Association (NFPA 77,

'Recommended Practice on Static Electricity', and/or the American Petroleum Institute (API)

Recommended Practice 2003, 'Protection Against Ignitions Arising Out of Stati c, Lightning, and Stray

Currents'.

Container Warnings: Container is not designed to contain pressure. Do not use pressure to empty

container or it may rupture with explosive force. Empty containers retain product residue (solid, liquid,

and/or vapor) and can be dangerous. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose

such containers to heat, flame, sparks, static electricity, or other sources of ignition. They may explode

and cause injury or death. Empty containers should be completely drained, properly closed, and

promptly returned to a drum reconditioner or disposed of properly.

SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION

GENERAL CONSIDERATIONS:

Consider the potential hazards of this material (see Section 3), applicable exposure limits, job activities,

and other substances in the work place when designing engineering controls and selecting personal

protective equipment. If engineering controls or work practices are not adequate to prevent exposure to

harmful levels of this material, the personal protective equipment listed below is recommended. The

user should read and understand all instructions and limitations supplied with the equipment since

protection is usually provided for a limited time or under certain circumstances.

ENGINEERING CONTROLS:

Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels

below the recommended exposure limits.

PERSONAL PROTECTIVE EQUIPMENT

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MSDS : 33979 Eye/Face Pro tection: Wear protective equipment to prevent eye contact. Selection of protective

equipment may include safety glasses, chemical goggles, face shields, or a combination depending on

the work operations conducted.

Skin Protection: Wear protective clothing to prevent skin contact. Selection of protective clothing may

include gloves, apron, boots, and complete facial protection depending on operations conducted.

Suggested materials for protective gloves include: Nitrile Rubber, Sil ver Shield, Viton.

Respiratory Protection: Determine if airborne concentrations are below the recommended occupational

exposure limits for jurisdiction of use. If airborne concentrations are above the acceptable limits, wear an

approved respirator that provides adequate protection from this material, such as: Air

- Purifying

Respirator for Organic Vapors.

Use a positive pressure air

- supplying respirator in circumstances where air

- purifying respirators may not

provide adequate protection.

Occupation al Exposure Limits:

Component Agency TWA STEL Ceiling Notation

Diethanolamine ACGIH 2 mg/m3

-- -- Skin A3

Consult local authorities for appropriate values.

SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES

Attention: the data below are typical values and do not constitute a specification.

Color: Amber

Physical State: Liquid

Odor: Odorless

pH: Not Applicable

Vapor Pressure: No data available

Vapor Density (Air = 1): No data available

Boiling Point: No data available

Solubility: Insoluble in water.

Freezing Point: No data available

Melting Point: No data available

Specific Gravity: 1.06 @ 15°C (59°F)

Density: 1.06 kg/l @ 15°C (59°F) Minimum

Viscosity: 10500 cSt @ 40°C (104°F)

Coefficient of Therm. Expansion / °F: No data available

Evaporation Rate: No data available

SECTION 10 STABILITY AND REACTIVITY

Chemical Stability: This material is considered stable under normal ambient and anticipated storage

and handling conditions of temperature and pressure.

Conditions to Avoid: Do not heat above flash point.

Incompatibility With Other Materials: May react with strong acids or strong oxidizing agents, such as

chlorates, nitrates, peroxides, etc.

Hazardous Decomposition Products: None known (None expected)

Hazardous Polymerization: Hazardous polymerization will not occur.

SECTION 11 TOXICOLOGICAL INFORMATION

IMMEDIATE HEALTH EFFECTS

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MSDS : 33979 Eye Irritation: The eye irritation hazard is based on evaluation of data for similar materials or product

components.

Skin Irritation: The skin irritation hazard is based on evaluation of data for similar materials or product

c omponents.

Skin Sensitization: The skin sensitization hazard is based on evaluation of data for similar materials or

product components.

Acute Dermal Toxicity: The acute dermal toxicity hazard is based on evaluation of data for similar

materials or product components.

Acute Oral Toxicity: The acute oral toxicity hazard is based on evaluation of data for similar materials

or product components.

Acute Inhalation Toxicity: The acute inhalation toxicity hazard is based on evaluation of data for

simi lar materials or product components.

ADDITIONAL TOXICOLOGY INFORMATION:

This product contains alkanolamine fatty acid ester.

SUBCHRONIC STUDIES: Rats and mice of both sexes were treated with this chemical in ethanol by

dermal application at concentrations of 0

- 400 (rat) or 0

- 800 (mouse) mg/kg, 5 times a week for 14

weeks. Survival was not affected by treatment. Histopathologic lesions at the site of application including

chronic active inflammation and ulcer were seen in rats at doses above 100 mg/kg and in mice at 800

mg/kg. In rats, decreased circulating cholesterol was seen at 100 mg/kg in females and 200 mg/kg in

male s. Triglycerides were decreased in males at 200 mg/kg. Also in female rats, renal tubule

regeneration was significantly increased at all doses. The severity of effect increased with dose.

CHRONIC STUDIES: In National Toxicology Program (NTP) studies, rats and mice of both sexes

received dermal applications of 0, 50, or 100 mg (rats) or 0, 100, or 200 mg/kg (mice) of this chemical

condensate containing about 18% unreacted diethanolamine (DEA) in ethanol five times a week for 104

weeks. NTP concluded there was no evidence in male rats and equivocal evidence of carcinogenicity in

female rats based on a marginal increase in renal tubule neoplasms. NTP also concluded there was

clear evidence of carcinogenicity in male mice based on increased hepatic and renal tubule neoplasms

and in female mice based on increased hepatic neoplasms.

In a separate 2 year bioassay, DEA was shown to be carcinogenic to mice but not to rats. Findings were

similar to those reported for this chemical. This suggests the carcinogenicity of this chemical is due to

DEA. Mechanisms of DEA carcinogenicity are under investigation. DEA is not genotoxic but appears to

interfer with normal phospholipid metabolism. Current hypotheses suggest the carcinogenicity of DEA is

tied to this interference. Because phospholipid metabolism varies widely between species, the relevance

of these findings to humans is not known.

SECTION 12 ECOLOGICAL INFORMATION

ECOTOXICITY

This material is expected to be toxic to aquatic organisms and may cause long

- term adverse effects in the

aquatic environment. The ecotoxicity hazard is based on an evaluation of data for the components or a

similar material.

ENVIRONMENTAL FATE

Ready Bi odegradability: This material is not expected to be readily biodegradable. The

biodegradability of this material is based on an evaluation of data for the components or a similar

material.

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MSDS : 33979 SECTION 13 DISPOSAL CONSIDERATIONS

Use material for its intended purpose or recycle if possible. This material, if it must be discarded, may

meet the criteria of a hazardous waste as defined by US EPA under RCRA (40 CFR 261) or other State

and local regulations. Measurement of certain physical properties and analysis for regulated

components may be necessary to make a correct determination. If this material is classified as a

hazardous waste, federal law requires disposal at a licensed hazardous waste disposal facility.

SECTION 14 TRANSPORT INFORMATION

The description shown may not apply to all shipping situations. Consult 49CFR, or appropriate

Dangerous Goods Regulations, for additional description requirements (e.g., technical name) and

mode

- specific or quantity

- specific shipping requirements.

DOT Sh ipping Description: UN3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,

N.O.S. (ALKANOLAMINE

- ALKANOIC ACID AMIDE), 9, III, RQ (DIETHANOLAMINE), MARINE

POLLUTANT

IMO/IMDG Shipping Description: UN3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE,

LIQUID, N. O.S. (ALKANOLAMINE

- ALKANOIC ACID AMIDE), 9, III, MARINE POLLUTANT

ICAO/IATA Shipping Description: UN3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE,

LIQUID, N.O.S. (ALKANOLAMINE

- ALKANOIC ACID AMIDE), 9, III

SECTION 15 REGULATORY INFORMATION

EPCRA 311/312 CATEGORIES: 1. Immediate (Acute) Health Effects: YES

2. Delayed (Chronic) Health Effects: NO

3. Fire Hazard: NO

4. Sudden Release of Pressure H azard: NO

5. Reactivity Hazard: NO

REGULATORY LISTS SEARCHED:

01

- 1=IARC Group 1 03=EPCRA 313

01

- 2A=IARC Group 2A 04=CA Proposition 65

01

- 2B=IARC Group 2B 05=MA RTK

02=NTP Carcinogen 06=NJ RTK

07=PA RTK

The following components of this material are found on the regulatory lists indicated.

01154100

- 5341P 01

- 2B, 04

Diethanolamine 03, 04, 05, 06, 07

CERCLA REPORTABLE QUANTITIES(RQ)/EPCRA 302 THRESHOLD PLANNING

QUANTITIES(TPQ):

Component Component RQ Component TPQ Product RQ

Diethanolamine 100 lbs None 10000 lbs