# Patent

## Title
Method and apparatus for cooling devices using phase change materials

## Abstract

In some embodiments, cooling devices with metal hydrides are disclosed.

## Background
CLAIM FOR PRIORITY
This application is a continuation of U.S. patent application Ser. No. 13/728,104, filed on 27 Dec. 2012, titled “METHOD AND APPARATUS FOR COOLING DEVICES USING PHASE CHANGE MATERIALS,” which is incorporated herein by reference in its entirety for all purposes.


TECHNICAL FIELD
The present invention relates generally to cooling systems, and in particular, to cooling systems using phase change materials such as metal hydrides.



BRIEF DESCRIPTION OF THE DRAWINGS
Embodiments of the invention are illustrated by way of example, and not by way of limitation, in the figures of the accompanying drawings in which like reference numerals refer to similar elements.
FIG. 1 is a perspective view of a cooling apparatus in accordance with some embodiments.
FIG. 2 illustrates an energy transfer process with hydrogen gas moving from container A to container B in accordance with some embodiments.
FIG. 3 illustrates controlled energy release to the environment with hydrogen gas moving from container B to container A in accordance with some embodiments.
FIG. 4 is a schematic diagram of a cooling system with an electrically controllable membrane valve in accordance with some embodiments.
FIG. 5 is a graph showing the pressure of H2 on either side of a PEM membrane as function of time at room temperature in an example in accordance with some embodiments.
FIG. 6 is a graph showing current vs. time for H2 transport through the membrane of FIG. 5 in accordance with some embodiments.



DETAILED DESCRIPTION
Small form factor devices such as smartphones and tablets may be thermally constrained by external skin temperature ergonomic limits and by internal component junction temperatures. The industrial design trend is to make these devices as thin as possible while increasing performance. The combined effect of making the device thinner and increasing performance exasperates the thermal problem, such that the external skin temperature (Tskin) is a primary constraint. Thermal engineers optimize their designs (component placement, heat spreading, thermal control algorithms), but the desired performance limits still can fall short in these thinner systems.
Advanced thermal techniques involve utilizing Phase Change Materials (PCM), to store heat dissipation as the device heats up, to absorb heat during turbo (processor boost) excursions or extended high end performance such as video conferencing. An example of a PCM is Paraffin such as Eicosane that melts at 37 degrees C. The melt point can be picked based on a constraint such as Tskin. To be competitive, electronic platforms should be designed to limit their external skin temperatures. Typical ergonomic Tskin limits for glass is 40 degrees C. and 38 degrees C. for metals such as aluminum. During the phase change melting process (solid to liquid) the energy storage capability or latent heat for Paraffin is around 200 J/gram. A problem in dealing with solid/liquid PCM is that they normally must be contained, since they turn into a liquid upon melting. In addition the thermal conductivity of such PCMs may be very low (0.25 W/m degrees K). So to effectively utilize such a PCM can require using heat spreaders and a containment vessel. The latent heat of conventional PCMs may also not be very compelling. In addition, there is little control with the melting process. Accordingly, new approaches may be desired.
In some embodiments, a cooling (or heat transfer) apparatus is disclosed that uses energy storage processes that are controllable such that heat can be rapidly removed when needed for extending performance of components in electronic systems. For example, such disclosed systems may be used to keep their Tskin and component junction temperatures (TJ) within acceptable limits. In some embodiments, phase change materials such as metal hydrides, which change from solids to gas and back to solids, may be used to quickly absorb energy during the latent heat phase change transition, and in some embodiments, to transfer it away from a region (or component) to be cooled.
FIG. 1 shows a cooling system in accordance with some embodiments. It generally comprises a first container (Container A), a second container (Container B, a controllable valve and a tube fluidly coupling container A to container B through the controllable valve. Container A includes a metal hydride (such as MgNi4.15Fe0.85), and container B also contains a metal hydride. In some embodiments, container B has a metal hydride such as LaNi4.8Sn0.2 that may have an associated phase change temperature that is lower than that of container A. These AB5 metal hydrides, or others, can store relatively large amounts of heat energy, e.g., from 3 to 4 times that of currently used solid to liquid PCM materials such as paraffin.
With additional reference to FIGS. 2 and 3, the first container (A) thermally conducts heat from an electronic component such as a CPU or SoC chip for a computing platform device such as a smartphone, tablet, PC, server, or the like. During high performance excursions that dissipate large amounts of power, heat can be conducted away from the chip, dissipating the added energy to the metallic hydride (e.g., AB5 metal hydride) in container A. (Note that a simple chip is used for ease of explanation, but it should be appreciated that any thermal power source could be cooled using approaches discussed herein. The cooling containers or combinations thereof, could be mounted to any desired part of an electronic, or other, device.)
The containers should be made of a suitable construction, e.g., a container designed to reliably contain hydrogen gas at expected worst-case temperatures and pressures. Although there will typically be little, if no, liquid containment requirements for this technology, hydrogen gas (H2) will still need to be reasonably contained. One approach may be to use very thin stainless steel containers to house the metal hydrides, which are typically in the form of powder. The containers can be miniaturized to fit in small form factor platforms such as smartphones, tablets, or other small mobile electronic devices, as shown in FIG. 3.
In some embodiments, the chip may be cooled in the following manner. Initially, metal hydride in container A (MHA) is fully charged with H2, while the metal hydride in container B (MHB) is sufficiently deficient of H2. Also, the valve is closed so that H2 cannot flow between the containers. The valve is electronically controlled to allow passage of H2 when additional cooling by the chip is required, for on-demand cooling. Any suitable control management apparatus, e.g., dedicated control circuit or some other control block in an electronic device could be used. For example, many computing platforms will have a thermal management system that could be used to electronically control the valve to cool the chip on demand. The controller could monitor the temperature at container A. Once it heats to a predetermined value, the valve could be opened, or it could be controlled by other sensors located on the components or other places within the device.
When the valve is opened, Hydrogen gas rapidly desorbs from the charged MHA, increasing the pressure in container A, and then moves to container B, where it is absorbed. During desorption in container A, the process is endothermic, such there is a net energy absorption into the metal hydride powder, controlled by the thermal characteristics of the container and platform. The net effect is a cooling of the components (e.g., chip) that are linked through thermal conduction to container A. In container B the pressure increases until an equilibrium pressure is attained between both containers, and the MHB, is fully charged with hydrogen. At this time the valve may once again be closed.
In a typical cycle after a high power generation event (such as a processor boost event) is over, the endothermic reaction in container A, cools down the chip. As the metal hydride in container B absorbs H2, the reaction is exothermic, releasing energy, but at a reduced pressure and temperature. With a lower phase change temperature for the container B material, the resulting temperature around container B may be much lower than those used in activating the metallic hydride in container A. Container B may be positioned in a cooler part of the platform away from high power dissipating electronic components, where the heat can be more easily dissipated. It may be observed that no appreciable heating or cooling happens within the tube, rather, it happens with the reactions in containers A and B where the metal hydrides are located.
Any suitable valve structure may be used. For example, it could be a mechanical valve such as an electrically actuated mechanical valve, or alternatively, an electronically activated permeable Polymer Electrolyte Membrane (PEM) could be used as the valve. This is illustrated in FIG. 4.
FIG. 4 shows a metallic hydride heat exchange apparatus, as taught herein, with the valve implemented with a proton exchange membrane (e.g., like those used in fuel cells). When used as fuel cells, proton exchange membranes operate in the following manner. Hydrogen gas is exposed to a catalyst on the anode side of the fuel cell, which separates the two electrons leaving two protons. For two such molecules the separation at the anode can be represented by the following equation:

2H2→4H++4e−  Anode:

The protons permeate through a membrane, such as a polymer electrolyte membrane (PEM) to a cathode on the opposite side. In parallel, the electrons move through an electrical circuit around the membrane to the cathode, while air is exposed to the cathode catalyst, resulting in a reaction between the oxygen, protons, and electrons forming water.

O2+4H++4e−→2H2O  Cathode:

2H2+O2→2H2O  Overall:

The electrons moving through the parallel circuit around the membrane to the cathode generate a potential, which powers the process.
On the other hand, and pertinent to this disclosure, if the process is reversed, and voltage is applied across the circuit, the flow of H2 can be controlled, as H2 permeates from cathode to anode through the membrane. So, when a PEM is used as a valve, as shown in FIG. 4 for example, When a high power event (e.g., a processor chip to be driven at a very high level) is about to occur (or even just after it has occurred), a voltage is driven across the membrane, allowing the flow of H2 gas from container A to container B. As with the above discussed process, this results in the metallic hydride in container A endothermically changes phase, releasing its H2, and latent heat, in essence, being conveyed via H2 gas from container A to container B. This rapidly draws heat away from the chip, or from whatever heat source to which container A is thermally mounted.
After time when the system is at lower activity, or cooling down, the metal hydride in container A may be recharged. The polarity across the PEM is reversed, allowing control of H2 in the opposite direction back to container A.
So, it can be seen that with a PEM, the flow of H2 can be electronically controlled in both the forward and reverse directions. Another capability is the ability to stop the flow of H2 through the membrane for long periods of time. This may be done by opening the circuit, and reducing the voltage to zero. Also if the H2 is depleted on one side such as in container A, the current will drop to zero and even though there is a voltage potential, there is no H2 transport.
As an example, and with reference to FIGS. 5 and 6, a Nafion membrane was used in a PEM valve to control the flow of H2 using constant voltages of +/−100 mV. Different voltages will change the flow rate, and when the circuit is open, H2 is not able to flow through the valve. In this example, over about a 2700 second interval, the H2 in container A was depleted, reducing the current to zero with the pressure in container A dropping to near zero. At that time, the circuit was opened, and no H2 moves through the membrane. At around 1900 seconds later, the applied polarity was reversed, and the process in turn reversed.
In this example, a chip could be cooled to 40 degrees C. for around 1800 seconds using the metal hydrides to store energy, as opposed to only a few seconds without them. Different targets can be selected depending on the design and temperature limits.
In some implementations, this controllable energy storage system may only be activated when needed, to control heating and cooling of the chip, or other components in the platform, and to prevent Tskin hot spot excursions during high performance usages such as extreme platform power bursts or for extending performance for applications like video conferencing or other high performance applications. The container A should be located near the heat sources in the platform. Container B can be located in a cooler region of the platform, and spread out over a larger area if needed to minimize Tskin temperature rise during the H2 absorb and desorb processes. The ideal scenario may be to achieve iso-skin temperature across the device, staying below an ergonomic limit. No actual heat transfer happens between container A and B, just H2 transport as a result of pressure differences during the energy exchanges.
As shown in FIG. 3 atop container B, another phase change material using solid/liquid or solid/solid PCMs could be applied to container B to help mitigate the slight exothermic reaction. These PCMs could be plastic crystals, poly alcohols, or other PCMs. The metal hydrides in containers A & B may be different, and thus may produce different amounts of H2. In this case the amounts of metal hydrides in each container will be different such that the amount of H2 produced is balanced by the amount of H2 absorbed in the two containers, for most efficient usage. In addition, additives such as Teflon or aluminum can be added to the metal hydrides within the containers to increase respective thermal conductivities.
In the preceding description and following claims, the following terms should be construed as follows: The terms “coupled” and “connected,” along with their derivatives, may be used. It should be understood that these terms are not intended as synonyms for each other. Rather, in particular embodiments, “connected” is used to indicate that two or more elements are in direct physical or electrical contact with each other. “Coupled” is used to indicate that two or more elements co-operate or interact with each other, but they may or may not be in direct physical or electrical contact.
The invention is not limited to the embodiments described, but can be practiced with modification and alteration within the spirit and scope of the appended claims. For example, it should be appreciated that the present invention is applicable for use with all types of semiconductor integrated circuit (“IC”) chips. Examples of these IC chips include but are not limited to processors, controllers, chip set components, programmable logic arrays (PLA), memory chips, network chips, PMIC, and the like.
It should also be appreciated that in some of the drawings, signal conductor lines are represented with lines. Some may be thicker, to indicate more constituent signal paths, have a number label, to indicate a number of constituent signal paths, and/or have arrows at one or more ends, to indicate primary information flow direction. This, however, should not be construed in a limiting manner. Rather, such added detail may be used in connection with one or more exemplary embodiments to facilitate easier understanding of a circuit. Any represented signal lines, whether or not having additional information, may actually comprise one or more signals that may travel in multiple directions and may be implemented with any suitable type of signal scheme, e.g., digital or analog lines implemented with differential pairs, optical fiber lines, and/or single-ended lines.
It should be appreciated that example sizes/models/values/ranges may have been given, although the present invention is not limited to the same. As manufacturing techniques (e.g., photolithography) mature over time, it is expected that devices of smaller size could be manufactured. In addition, well known power/ground connections to IC chips and other components may or may not be shown within the FIGS., for simplicity of illustration and discussion, and so as not to obscure the invention. Further, arrangements may be shown in block diagram form in order to avoid obscuring the invention, and also in view of the fact that specifics with respect to implementation of such block diagram arrangements are highly dependent upon the platform within which the present invention is to be implemented, i.e., such specifics should be well within purview of one skilled in the art. Where specific details (e.g., circuits) are set forth in order to describe example embodiments of the invention, it should be apparent to one skilled in the art that the invention can be practiced without, or with variation of, these specific details. The description is thus to be regarded as illustrative instead of limiting.

## Claims

1. A method comprising:
monitoring temperature of a first container coupled to a second container via a controllable value;
opening the controllable valve when the monitored temperature reaches a predetermined value such that hydrogen is released from the first container, wherein the controllable valve is electronically controllable in forward and reverse directions; and
cooling a processor, thermally coupled to the first container, in response to the released hydrogen.

2. The method of claim 1, wherein in response to opening the controllable valve, the method comprises:
desorbing the hydrogen gas from the first container;
increasing pressure in the first container; and
transferring the hydrogen gas to the second container.

3. The method of claim 1 comprises filling the first container with a first metal hydride, and filling the second container with a second metal hydride.

4. The method of claim 3, wherein the second metallic hydride is to have a phase change temperature which is to be same as a phase change temperature for the first metallic hydride.

5. The method of claim 1 comprises positioning the second container in a cooler part of a computing platform away from the processor.

6. The method of claim 1 comprises recharging the first container with a first metallic hydride.

7. An apparatus comprising:
a first container having a first metal hydride, the first container configured to be mounted to a surface to conduct heat away from the surface through hydrogen being released from the first metal hydride;
a controllable valve which is operable to open when a monitored temperature reaches a predetermined value; and
a second container having a second metal hydride, the second container coupled to the first container through the controllable valve,
wherein the controllable valve is an electronically activated permeable Polymer Eletrolyte Membrane (PEM).

8. The apparatus of claim 7, wherein the PEM is one of: a proton exchange membrane, or a Nafrom membrane.

9. The apparatus of claim 7 comprises a phase change material (PCM) atop the second container.

10. The apparatus of claim 9, wherein the PCM is one of: plastic crystals, poly alchole, or paraffin.

11. The apparatus of claim 7, wherein the first metal hydride is different from the second metal hydride.

12. The apparatus of claim 7, wherein the first container is to be positioned near a heat source, and wherein the second container is to be positioned near a cooler region of a platform.

13. The apparatus of claim 12, wherein the heat source is a processor chip.

14. The apparatus of claim 7, wherein the controllable valve is electronically controllable in forward and reverse directions.

15. The apparatus of claim 7, wherein the first metal hydride includes MmNi4.15Fe0.85, and wherein the second metallic hydride includes LaNi4.8Sn0.2.

16. The apparatus of claim 7, wherein the second metal hydride has a phase change temperature lower than a phase change temperature of the first metallic hydride.

17. The apparatus of claim 7, wherein at least one of the first and second containers are formed of stainless steel.

18. An apparatus comprising:
means for monitoring temperature of a first container coupled to a second container via a controllable value;
means for opening the controllable valve when the monitored temperature reaches a predetermined value such that hydrogen is released from the first container, wherein the controllable valve is electronically controllable in forward and reverse directions; and
means for cooling a processor, thermally coupled to the first container, in response to the released hydrogen.

19. The apparatus of claim 18 comprises:
means for desorbing the hydrogen gas from the first container;
means for increasing pressure in the first container; and
means for transferring the hydrogen gas to the second container.