Page 1 of 12 Revision date 04/26/2011 

# Material Safety Data Sheet

1. PRODUCT AND COMPA NY IDENTIFICATION

COREACTANT 9L7

Supplier ROHM AND HAAS CHEMICALS LLC

A Subsidiary of The Dow Chemical Company

100 INDEPENDENCE MALL WEST

PHILADELPHIA

, PA 19106

- 2399 United States

For non

- emergency information contact: 215

- 592

- 3000

For non

- emergency information contact: 215

- 592

- 3000

Emergency telephone number

1 800 424 9300

Local emergency telephone number

989

- 636

- 4400



### 2. COMPOSITION/INFOR MATION ON INGREDIENT S

Component CAS

- No. Concentration

1,6

- diisocyanatohexane, homopolymer 28182

- 81

- 2 74.0

- 76.0%

Propylene glycol methyl ether acetate 108

- 65

- 6 12.0

- 14.0%

Xylene 1330

- 20

- 7 9.0

- 11.0%

Ethylbenzene 100

- 41

- 4 2.0

- 4.0%

Hexamethylene diisocyanate 822

- 06

- 0 < 0.6%



### 3. HAZARDS IDENTIFIC ATION

Emergency Overview



### Appearance

Form liquid clearCOREACTANT 9L7

Page 2 of 12 Revision date 04/26/2011 

### Hazard Summary WARNING !

Flammable.

Material can cause the following:

irritation of nose, throat, and lungs

Severe eye irritation

Moderate skin irritation

central nervous system (CNS) effects

May cause sensitization by inhalation and skin contact.

Inhalation of vapours in high concentration may cause shortness of

breath (lung oedema).

Bronchial constriction may develop after extensive exposure to

isocyanates , even in individuals who have not been shown to be

previously sensitized.

Prolonged or repeated exposure can cause the following:

Kidney effects

liver effects

lung effects

blood disorders

adverse reproductive effects

Potential Health Effects

Primary Routes of Entry: Inhalation

Skin contact

Eye contact

Dermal Absorption

Eyes: The solvent(s) in this material can cause the following:

Severe irritation

conjunctivitis

Pain

tearing

Skin: Material can cause the following:

Moderat e irritation.

reddening

- skin sensitization even at low concentrations in susceptible individuals Prolonged or repeated

overexposure to the solvent(s) in this material can cause the following:

defatting and drying of the skin which can lead to irritation and dermatitis

Solvent(s) can be absorbed through intact skin with the appearance of initial symptoms of inhalation

exposure.

Ingestion: Material is possibly harmful if swallowed.

Material can cause the following:

gastrointestinal irritation

Lack of coord ination

dizziness

nausea

headache

diarrhea

drowsiness

Vomiting

Aspiration into the lungs may cause:

pulmonary edema (fluid in lung tissue and air spaces)

pneumonitis (lung inflammation)

lung injuryCOREACTANT 9L7

Page 3 of 12 Revision date 04/26/2011 Inhalation: Inhalation of vapor or mist can cause the fol lowing:

irritation of nose, throat, and lungs

headache

nausea

Vomiting

dizziness

drowsiness

Lack of coordination

Difficulty in breathing

kidney damage

blood disorders

- respiratory sensitization (isocyanates)

tightness in the chest

Shortness of breath

lung damage

Asthma

Inhalation of high vapor or mist concentrations can cause the following:

pulmonary edema (fluid in lung tissue and air spaces)

pneumonitis (lung inflammation)

Unconsciousness

coma

Death

Chronic Exposure: Prolonged or repeated overexposure t o xylene can cause the following:

- reversible

liver impairment

- reversible kidney impairment

Prolonged or repeated overexposure to ethylbenzene may cause the following:

- kidney effects

- liver

effects

- lung effects

- pituitary effects

- thyroid effects

- testicular effects

Prolonged or repeated overexposure to propylene glycol monomethyl ether acetate can cause the

following:

- liver damage

- kidney damage

- blood disorders

Long term exposure to diisocyanates may cause lung damage, including reduced lun g function, which

may be permanent.

Xylene ACGIH Not classifiable as a

human carcinogen.

Xylene IARC Not classifiable as to

carcinogenicity to humans.

Xylene IRIS Not classifiable.

Xylene IRIS Data are inadequate for an

assessment of human

carcinogenic potential

[1999 Guidelines]

Xylene IARC Not classifiable as to

carcinogenicity to humans.

Ethylbenzene ACGIH Confirmed animal

carcinogen with unknown

relevance to humans.

Ethylbenzene IARC Possibly carcinogenic to

humans.

Ethylbenzene IRIS Not classif iable.

Ethylbenzene US CA CRT Carcinogenic.

Ethylbenzene ACGIH NIC Confirmed animal

carcinogen with unknown

relevance to humans.

Ethylbenzene CA PROP 65 Oral

Ethylbenzene CA PROP 65 InhalationCOREACTANT 9L7

Page 4 of 12 Revision date 04/26/2011 Ethylbenzene IRIS D: Not classifiable as to

human carcinog enicity

[1986 Guidelines]



### 4. FIRST AID MEASURE S

Inhalation: Move to fresh air. Give artificial respiration if breathing has stopped. Get prompt medical

attention. In case of shortness of breath, give oxygen.

Skin contact: Remove contaminated clothing. Wash off with soap and plenty of water. Wash

contaminated clothing before re

- use. Do not take clothing home to be laundered. Consult a physician.

Eye contact: Rinse immediately with plenty of water for at least 15 minutes

. Get prompt medical

attention.

Ingestion: Drink 1 or 2 glasses of water. Do not induce vomiting: contains petroleum distillates and/or

aromatic solvents. Careful gastric lavage may be indicated. IMMEDIATELY see a physician. If

vomiting occurs sponta neously, keep airway clear. Never give anything by mouth to an unconscious

person.

Notes to physician: Product contains a petroleum distillate that may cause CNS symptoms. If

swallowed, DO NOT induce vomiting due to the risk of aspiration posed by petroleum distillates. Careful

gastric lavage may be indicated.



### 5. FIRE

- FIGHTING MEASURES

Flash point 33 °C ( 91.40 °F ) PENSKY MARTENS CLOSED CUP PENSKY

MARTENS CLOSED CUP

Ignition temperature 527.0 °C ( 980.60 °F ) Xylene

Lower explosion limit 1.10 %(V)Xylene

Upper explosion limit 6.70 %(V)Xylene

Suitable extinguishing media: Use the following extinguishing media when fighting fires involving this

material:

Carbon dioxide (CO2)

Dry powder

Foam

Water in very large quantities.

Specific hazards during fire fighting: Vapors can travel to a source of ignition and flash back. Heated

material can form flammable or explosive vapors with air. Closed containers may rupture via pressure

build

- up when exposed to fire or extreme heat. During a fire, irritating and highly toxic gases and/or

fumes may be generated during combustion or decomposition. DO NOT permit water to enter

containers. Closed containers may explode when heated or contents contaminated with water.

Special protective equipment for fire

- fighters: In the event of fire, wear self

- contained breathing

apparatus.

Further information: EXPLOSION HAZARD. Fight advanced fires from a pro tected location.

Cool closed containers exposed to fire with water spray.

DO NOT permit water to enter containers.

Remain upwind.

Avoid breathing smoke.

Contain run

- off.COREACTANT 9L7

Page 5 of 12 Revision date 04/26/2011 

### 6. ACCIDENTAL RELEAS E MEASURES

Personal precautions

Appropriate protective equipment must be worn when handling a spill of this material. See SECTION 8,

Exposure Controls/Personal Protection, for recommendations.

MATERIAL IS A POTENTIAL SENSITIZER.

If exposed to material during clean

- up operations, IMMEDIA TELY remove all contaminated clothing and

wash exposed skin areas with soap and water. See SECTION 4, First Aid Measures, for further

information.

Wash contaminated clothing before re

- use.

Do not take clothing home to be laundered.

Environmental precaution s

WARNING: KEEP SPILLS AND CLEANING RUNOFFS OUT OF MUNICIPAL SEWERS AND OPEN

BODIES OF WATER.

Methods for cleaning up

Eliminate all ignition sources.

Evacuate personnel to safe areas.

Ventilate the area.

Floor may be slippery; use care to avoid falling.

So ak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust).

Sweep up or vacuum up spillage and collect in suitable container for disposal.

No sparking tools should be used.

Avoid all contact.

Avoid breathing vapor.

NOTE: Spills on porous surfaces can contaminate groundwater.



### 7. HANDLING AND STOR AGE

Handling

Vapors can be evolved when material is heated during processing operations. See SECTION 8,

Exposure Controls/Personal Protection, for types of ventilation requi red. Use non

- sparking tools and

grounding cables when transferring. This material is a potential sensitizer. See SECTION 8, Exposure

Controls/Personal Protection, prior to handling. Wash after handling and shower at end of work period.

Persons suscept ible to skin sensitisation problems or asthma, allergies, chronic or recurrent respiratory

disease should not be employed in any process in which this mixture is being used.

Other data: STIR WELL BEFORE USE.



### Storage

Storage conditions: Avoid temperature extremes during storage; ambient temperature preferred.

Store away from excessive heat (e.g. steampipes, radiators), from sources of ignition and from reactive

materials. Material can burn; limit indoor storage to approved areas equippe d with automatic sprinklers.

Store out of direct sunlight in a cool place. Keep containers tightly closed in a cool, well

- ventilated place.

Avoid all ignition sources. Ground all metal containers during storage and handling. Keep material dry.

Moistu re may affect product quality.

Further information on storage conditions: Residual vapors in empty containers may explode on

ignition. DO NOT cut, drill, grind or weld on or near container.

Further information:

CONTAINERS MAY BE HAZARDOUS WHEN EMPTY. Sin ce emptied containers retain product

residue follow all MSDS and label warnings even after container is emptied.

Improper disposal or re

- use of this container may be dangerous and illegal. Refer to applicable local,

state and federal regulations.COREACTANT 9L7

Page 6 of 12 Revision date 04/26/2011 

### 8. EXPOS URE CONTROLS/PERSONA L PROTECTION

Exposure limit(s)

Exposure limits are listed below, if they exist.

Component Regulation Type of listing Value

1,6

- diisocyanatohexane,

homopolymer Rohm and Haas TWA 0.1 mg/m3

Rohm and Haas STEL 0.3 mg/m3

Component Regulation Type of listing Value

Propylene glycol methyl

ether acetate Rohm and Haas TWA 30 ppm

Rohm and Haas STEL 90 ppm

Rohm and Haas Absorbed via skin

WEEL TWA 50 ppm

Component Regulation Type of listing Value

Xylene Rohm and Haas TWA 25 ppm

Rohm and Haas STEL 75 ppm

Rohm and Haas Absorbed via skin

ACGIH TWA 100 ppm

ACGIH STEL 150 ppm

OSHA_TRANS PEL 435 mg/m3 100 ppm

Z1A TWA 435 mg/m3 100 ppm

Z1A STEL 655 mg/m3 150 ppm

Component Regulation Type of listing Value

Ethylbenzene Rohm and Haas TWA 25 ppm

Rohm and Haas STEL 75 ppm

ACGIH TWA 20 ppm

NIOSH/GUIDE REL 435 mg/m3 100 ppm

NIOSH/GUIDE STEL 545 mg/m3 125 ppm

OSHA_TRANS PEL 435 mg/m3 100 ppm

Z1A TWA 435 mg/m3 100 ppm

Z1A STEL 545 mg/m3 125 ppm

Component Regulation Type of listing Value

Hexamethylene diisocyanate Rohm and Haas TWA 0.005 ppm

Rohm and Haas STEL 0.02 ppm

ACGIH TWA 0.005 ppm

NIOSH/GUIDE REL 0.035 mg/m3 0.005

ppm

NIOSH/GUIDE Ceil_Time 0.140 mg/m3 0.020

ppm



### Exposure controls

Engineering measures: Use explosion

- proof local exhaust ventilation with a minimum capture

velocity of 100 ft/min (0.5 m/sec) at the point of vapor e volution. Refer to the current edition of Industrial

Ventilation: A Manual of Recommended Practice published by the American Conference of

Governmental Industrial Hygienists for information on the design, installation, use, and maintenance of

exhaust syst ems.



### Protective measures: Facilities storing or utilizing this material should be equipped with an eyewash

facility and a safety shower.



### Individual protection measuresCOREACTANT 9L7

Page 7 of 12 Revision date 04/26/2011 Eye/face protection: Use chemical splash goggles (ANSI Z87.1 or approved equivalent). Eye

protection worn must be compatible with respiratory protection system employed.

Skin protection

Hand protection: Chemical

- resistant gloves should be worn whenever this material is

handled. The glove(s) listed below may provide protection against p ermeation. (Gloves

of other chemically resistant materials may not provide adequate protection): VITON

Synthetic Rubber (registered Trademark of Dupont Dow Elastomers) Gloves should be

removed and replaced immediately if there is any indication of degrad ation or chemical

breakthrough. Rinse and remove gloves immediately after use. Wash hands with soap

and water.

Other protection: Use chemically resistant apron or other impervious clothing to avoid

prolonged or repeated skin contact. Where splashing is possible, full chemically

resistant protective clothing (e.g. acid suit) and boots are required.

Respiratory protection: A respiratory protection program meeting OSHA 1910.134 and ANSI

Z88.2 requirements or equivalent must be followed whenever workplace conditions warrant a

respirator ‟ s use. None required if airborne concentrations are maintained below the exposure

limit listed in Exposure Limit Information. Above the exposure limit: Wear a properly fitted

NIOSH approved (or equivalent) self

- contained breathing apparatus in the pressure demand

mode, OR full

- facepiece, airline respirator in the pressure demand mode with emergency

escape provision.



### 9. PHYSICAL AND CHEM ICAL PROPERTIES

Appearance

Form liquid clear

pH Not Applicable

Boiling point/boi ling range 98 °C ( 208.40 °F )

Flash point 33 °C ( 91.40 °F ) PENSKY MARTENS CLOSED CUP PENSKY

MARTENS CLOSED CUP

Evaporation rate 0.70 Xylene

Lower explosion limit 1.10 %(V)Xylene

Upper explosion limit 6.70 %(V)Xylene

Vapour pressure 8.3 mmHg at 25 °C ( 77.00 °F ) Xylene

Relative vapour density 3.7Xylene

Relative density no data available

Water solubility insoluble

Autoignition temperature 527 °C ( 980.60 °F ) Xylene

Percent volatility 24

- 26 %

VOC ’ s 270 g/l

NOTE: The physical data pres ented above are typical values and should not be construed as a

specification.



### 10. STABILITY AND RE ACTIVITY

Hazardous reactions This material is considered stable.

However, avoid contact with ignition sources (e.g. sparks, open flame,

heated surfaces).COREACTANT 9L7

Page 8 of 12 Revision date 04/26/2011 Materials to avoid Avoid contact with the following: Strong Oxidizers Acids Water Bases

Amines

Hazardous

decomposition products Thermal decomposition may yield the following:

, isocyanate monomers

,

Polymerisation Product will not undergo polyme rization.



### 11. TOXICOLOGICAL IN FORMATION

No toxicity data are available for this material.

Component: Propylene glycol methyl ether acetate

Acute oral toxicity LD50 rat > 5,000 mg/kg

Component: Xylene

Acute oral toxicity LD50 rat 4,300 mg/kg

Compo nent: Ethylbenzene

Acute oral toxicity LD50 rat 3,500 mg/kg

Component: Propylene glycol methyl ether acetate

Acute inhalation toxicity LC50 rat 6 h > 24 mg/l

Component: Xylene

Acute inhalation toxicity LC50 rat 4 h 27.5 mg/l

Component: Ethylbenzen e

Acute inhalation toxicity LC50 rat 4 h 17.2 mg/l

Vapor

Component: Propylene glycol methyl ether acetate

Acute dermal toxicity LD50 rat > 5,000 mg/kg

Component: Propylene glycol methyl ether acetate

Acute dermal toxicity LD50 rabbit > 5,000 mg/kg

Component: Xylene

Acute dermal toxicity LD50 rabbit 4,300 mg/kg

Component: Ethylbenzene

Acute dermal toxicity LD50 rabbit > 15,000 mg/kg

Component: Xylene

Skin irritation rabbit Moderate irritation.

Component: Xylene

Eye irritation rabbit moderate to severe.

Component: Propylene glycol methyl ether acetate

Reproductive toxicity

Dermal teratology testing of this solvent (with less than 3% beta isomer) revealed no maternally toxic,

teratogenic or fetotoxic responses in rats or rabbits exposed to co ncentrations of 1,000 and 2,000

mg/kg per day.COREACTANT 9L7

Page 9 of 12 Revision date 04/26/2011 Component: Propylene glycol methyl ether acetate

Mutagenicity

No significant mutagenic response was observed and the carcinogenic potential of the material is

therefore considered to be low.

Component: Xylene

Reproductive toxicity

In laboratory studies, birth defects, increased fetal lethality and delayed fetal development have been

observed in offspring of female animals exposed during pregnancy.

Component: Ethylbenzene

Carcinogenicity : This product contains ethylbenzene. A study conducted by the National

Toxicology Program states that lifetime inhalation exposure of rats and mice to high concentrations

of ethylbenzene (750 ppm) resulted in increases in certain types of cancer, including kidney tumors

in rats and lung and liver tumors in mice. Incidences of testicular adenoma were increased along with

increased incidences of thyroid effects in rats at 750 ppm; pituitary effects were observed in female

mice at 250 ppm. These effects were not observed in animals exposed to lower concentrations of

ethylbenzene (75 ppm). The study does not address the relevance of these results to humans.



### 12. ECOLOGICAL INFOR MATION

There is no data available for this product.

Propylene glycol methyl ether acetate

Elimination infor mation (persistence and degradability)

Biodegradability OECD Test Guideline 302B or Equivalent

100 %

10

- day Window: Pass

Bioaccumulation No applicable data.

Ecotoxicity effects

Toxicity to fish LC50 Fathead minnow (Pimephales promelas) 96 h Method Not

Specified

161 mg/l

Toxicity to algae Growth inhibition EC50 Algae (Selenastrum capricornutum) 72 h Method

Not Specified

>1,000 mg/l

Toxicity to aquatic

invertebrates EC50 Daphnia magna (Water flea) 48 h Method Not Specified

>500 mg/l

Xylene

El imination information (persistence and degradability)

Bioaccumulation Fish Calculated

Bioconcentration factor (BCF) : 15

- 21

Ecotoxicity effects

Toxicity to fish LC50 Rainbow trout (Oncorhynchus mykiss) 96 h Method Not Specified

13.4 mg/l

Toxicity to algae EbC50 Pseudokirchneriella subcapitata (green algae) 72 h

3.2

- 4.9 mg/l

Toxicity to aquatic

invertebrates Palaemonetes pugio 48 h

8.5 mg/lCOREACTANT 9L7

Page 10 of 12 Revision date 04/26/2011 Toxicity to aquatic

invertebrates EC50 Scud (Gammarus lacustris) 48 h Method Not Specified

0.6 mg/l

Ethylbenzene

Ecotoxicity effects

Toxicity to fish LC50 Rainbow trout (Oncorhynchus mykiss) 96 h OECD Test Guideline

203 or Equivalent

4.2 mg/l

Toxicity to algae EC50 Algae (Selenastrum capricornutum) 72 h OECD Test Guideline

201 or Equivalent

4.6 mg/l

Toxicity to aquatic

invertebrates EC50 Daphnia magna 48 h

2.1 mg/l



### 13. DISPOSAL CONSIDE RATIONS

Environmental precautions: WARNING: KEEP SPILLS AND CLEANING RUNOFFS OUT OF

MUNICIPAL SEWERS AND OPEN BODIES OF WATER.



### Disposal

Waste Classification: 40 CFR 261.20

- .24

- Characteristic Waste D001, 100 lbs.

When a decision is made to discard this material as supplied, it is classified as a RCRA hazardous waste

with the characteristic of ignitability.

For disposal, incinerate this material at a faci lity that complies with local, state, and federal regulations.

(See 40 CFR 268)

Contaminated packaging: Empty containers should be taken to an approved waste handling site for

recycling or disposal.



### 14. TRANSPORT INFORM ATION



## DOT

Proper shipping name Res in solution

UN number UN 1866

Class 3

Packing group III

Reportable Quantity Xylene

, Hexamethylene diisocyanate



## IMO/IMDG

Proper shipping name RESIN SOLUTION

UN number UN 1866

Class 3

Packing group III

Transportation classifications may vary by container volume and may be influenced by regional or

country variations in regulationsCOREACTANT 9L7

Page 11 of 12 Revision date 04/26/2011 

### 15. REGULATORY INFOR MATION

Workplace Classification

OSHA: This product is considered hazardous under the OSHA Hazard Communication Standard

(29 CFR 1910.1200).

WHMI S : This product is a „ controlled product ‟ under the Canadian Workplace Hazardous

Materials Information System (WHMIS).



### SARA TITLE III : Section 311/312 Categorizations (40CFR370): Acute Health Hazard

Chronic Health Hazard

Fire Hazard



### SARA TITLE III : Sect ion 313 Information (40CFR372)

This product contains a chemical which is listed in Section 313 at or above de minimis concentrations.

The following listed chemicals are present: (Quantity present is found elsewhere on this MSDS.)

SARA Title III Components : Xylene 1330

- 20

- 7

Ethylbenzene 100

- 41

- 4



### CERCLA Information ( 40CFR302.4 )

See Section 13, Disposal Considerations, Subsection Disposal, for CERCLA classification.

This material is regulated under the Comprehensive Environmental Response, Compensatio n and

Liability Act (CERCLA)and the Superfund Amendments and Reauthorization Act (SARA) Title III Section

304. This material is or contains chemical(s) listed in 40 CFR Table 302.4 or nondesignated RCRA ICR

substance(s). (Nondesignated ICR substances apply to materials that will not be reused.) The

Reportable Quantity(s) (RQ) are listed below. Releases in excess of its reportable quantity must be

reported to the National Response Center (1

- 800

- 424

- 8802) and to the appropriate state and local

emergency respo nse organizations.

Xylene 1330

- 20

- 7 100 lbs RQ

Ethylbenzene 100

- 41

- 4 1,000 lbs RQ

Hexamethylene diisocyanate 822

- 06

- 0 100 lbs RQ



### US. Toxic Substances Control Act ( TSCA ) : All components of this product are in compliance with

the inventory listing re quirements of the U.S. Toxic Substances Control Act (TSCA) Chemical

Substance Inventory.

Pennsylvania

Any material listed as “ Not Hazardous ” in the CAS REG NO. column of SECTION 2,

Composition/Information On Ingredients, of this MSDS is a trade secret und er the provisions of the

Pennsylvania Worker and Community Right

- to

- Know Act.

California (Proposition 65)

This product contains a component or components known to the state of California to cause cancer:

Components: Ethylbenzene 100

- 41

- 4



### 16. OTHER INF ORMATION

HMIS: * = Chronic Effects (See Hazards Identification)



### HMIS Hazard Rating



### Health Fire Reactivity Physical

Hazard PPE

*2 3 1COREACTANT 9L7

Page 12 of 12 Revision date 04/26/2011 

### Legend

ACGIH American Conference of Governmental Industrial Hygienists

BAc Butyl acetate

OSHA Occupational Safety a nd Health Administration

PEL Permissible Exposure Limit

STEL Short Term Exposure Limit (STEL):

TLV Threshold Limit Value

TWA Time Weighted Average (TWA):

| Bar denotes a revision from prior MSDS.

The information provided in this Safety Data Sheet i s correct to the best of our knowledge, information

and belief at the date of its publication. The information given is designed only as a guidance for safe

handling, use, processing, storage, transportation, disposal and release and is not to be considere d a

warranty or quality specification. The information relates only to the specific material designated and

may not be valid for such material used in combination with any other materials or in any process, unless

specified in the text.

Version: 3

. 0

Print Date: 11/08/2012

Layout 000101108800