Enclosure 1


Enclosure 2
U.S. EPA Information Collection Request for Off-Site Waste and Recovery Operations

Page 1 of 14

General Information

Name of Legal Owner: Giant Cement Company

Legal Owner Address: 320-D Midland Parkway, Summerville, SC 29485

Number of Legal Owner Employees: 843-851-9898

Facility Name: Giant Cement Company

Facility Address: 654 Judge Street, Harleyville, SC 29448

Mailing Address (if different from 

facility address): P.O. Box 218, Harleyville, SC 29448

Facility Contact Name: Edward "Sonny" Dougherty

Facility Contact Title: Manager, Environmental Compliance

Facility Contact Phone Number: 803-496-2855

Facility Contact Email Address: Sonny.Dougherty@gcpv.com

Number of Company Employees at 

the Entire Facility: 180

Please enter any other comments 

regarding general ownership 

information here:
U.S. EPA Information Collection Request for Off-Site Waste and Recovery Operations

Page 2 of 14

Facility Information

Is the facility a major source for HAP? (see definition below)

Major sources are any stationary source or group of stationary 

sources located within a contiguous area and under common 

control that emits or has the potential to emit considering 

controls, in the aggregate, 10 tons per year (TPY) or more of 

any hazardous air pollutant or 25 TPY or more of any 

combination of HAP. 

Are there one or more off-site waste management or recovery 

operations at the facility subject to the Off-Site Waste and 

Recovery Operations (OSWRO) MACT (40 CFR 63, subpart DD)?

Is the facility exempt from complying with the OSWRO MACT?

What type(s) of off-site waste does the facility accept? (please 

include shipment method, physical form (i.e., solid, liquid, 

sludge), and a general description)

Approximately how many sources (facilities) does that waste 

come from?

What is the base year for which information is being provided? 

(please limit reporting years between 2006 and 2012, and 

provide the most current year)

For this base year, what was the amount of off-site waste 

received? (please specify units; e.g., gal/yr)

For this base year, what was the HAP content of the off-site 

waste received? (please specify units; e.g., tons)

How many hours per year are control devices bypassed to the 

atmosphere to perform routine maintenance?

Are any OSWRO operations scheduled to be discontinued? 

Are any OSWRO operations scheduled to be added or 

expanded?

What is the permitting classification of your facility?

What are the operating permit IDs for the OSWRO operations at 

your facility?

Is your operating permit available online?

Please provide the coordinates (in decimal degrees) of your 

facility property boundary at each corner (node). Alternatively, 

please provide the minimum distance from any OSWRO 

emission point to the facility property boundary.

Please enter any other comments regarding the facility here:

If yes, please provide date(s) that addition(s) 

and/or expansion(s) will begin production and 

explain changes:

If yes, please provide dates of closure and explain 

changes:

2011

See "Confidential Business Information" Summary

9,097 tons in 2011

If yes, please explain:

0

Minimum distance to property boundary 

(approximate):

Containers - 550 feet

Tanks - 700 feet

Equipment Leaks - 700 feet

Transfer Systems - 700 feet

Hazardous waste to be used for energy recovery. 

Hazardous liquids are shipped via tanker trucks 

and railcars, and may include industrial solvents, 

paints, and other spent materials with Btu value. 

Hazardous solids are typically shipped in roll-offs 

and dump trailers although other types of 

containers are allowed. Hazardous solids include 

contaminated personal protective equipment 

(PPE), rags, resinous materials, etc.

Approximately 73 in 2011.

http://www.giantcement.com/Documents/06060

SCDHEC Title V No. 0900-0002

If yes, please provide a link to or a copy of your 

most recent operating permit. If no, please 

provide a copy of your most recent operating 
U.S. EPA Information Collection Request for Off-Site Waste and Recovery Operations

Page 3 of 14

If no, please explain.

If no, please explain.

If "Other", please explain:

Emission factors from site-specific testing at a similar facility, 

using EPA -453/8-93-828 "Protocol for Equipment Leak Emission 

Estimates."

If "Other", please explain:

Site-specific testing report attached.

If neither apply, please explain:

If yes, please describe the control technique(s):

Please provide the additional capital and annual costs of 

this practice above that required by the OSWRO NESHAP:

Pumps 15

Compressors 0

Agitators 4

Pressure relief devices 0

Sampling connection systems 120

Open-ended valves or lines 0

Connectors 631

Instrumentation systems 9

Number of valves: 262 (included in the equipment leaks 

calculations referenced in Enclosure 2a).

Equipment Leaks

Have you verified and/or corrected the equipment leak 

emissions for your OSWRO processes in Enclosure 2A?

Have you completed all control information fields for your 

OSWRO equipment leaks in Enclosure 2A?

What emissions calculation approach was used to estimate 

the equipment leak emissions?

Please enter any other comments regarding equipment leaks 

here:

What is the number of each type of component for the 

equipment in OSWRO HAP service (equipment that contacts 

off-site material having a total HAP concentration ≥ 10% by 

weight for 300 hours/year or more)?

With which subpart do you comply for equipment leaks?

Please provide documentation demonstrating the basis for 

the equipment leak emissions estimates. What type of 

documentation are you providing?

Are you implementing work practices or other HAP control 

techniques beyond those required by the MACT standard?
U.S. EPA Information Collection Request for Off-Site Waste and Recovery Operations

If no, please explain.

These are included with and considered part of 

"Equipment Leaks."

If no, please explain.

These are included with and considered part of 

"Equipment Leaks."

If "Other", please explain:

Hazardous liquids - Hard piping that is permanently or semipermanently sealed.

Hazardous solids - Covers used for hazardous solids conveyor.

If "Other", please explain:

Hazardous liquids - See "Equipment Leaks" tab. Hazardous 

solids - N/A

If yes, please describe the control technique(s):

Please provide the additional capital and annual costs of 

this practice above that required by the OSWRO NESHAP:

Please enter any other comments regarding transfer 

systems here:

Transfer Systems

Have you entered the OSWRO transfer system emissions in 

Enclosure 2A?

Have you completed all control information fields for your 

OSWRO transfer systems in Enclosure 2A?

What emissions calculation approach was used to estimate 

the transfer system emissions?

Are you implementing work practices or other HAP control 

techniques beyond those required by the MACT standard?

Please provide documentation demonstrating the basis for 

the transfer system emissions estimates. Are you providing 

emissions factors or source test data?
U.S. EPA Information Collection Request for Off-Site Waste and Recovery Operations

If no, please explain.

The Giant facility does not operate any oil-water or organicwater separators.

If no, please explain.

If "Other", please explain:

If "Other", please explain:

If yes, please describe the control technique(s):

Please provide the additional capital and annual costs of 

this practice above that required by the OSWRO NESHAP:

The Giant facility does not operate any oil-water or organicwater separators, and therefore, this tab is not applicable. 

Please enter any other comments regarding organic or oilwater separators here:

Are you implementing work practices or other HAP control 

techniques beyond those required by the MACT standard?

Please provide documentation demonstrating the basis for 

the oil-water and organic-water separators emissions 

estimates. Are you providing emissions factors or source 

test data?

Oil-water and organic-water separators

Have you entered the OSWRO oil-water and organic-water 

separators emissions in Enclosure 2A?

Have you completed all control information fields for your 

OSWRO oil-water and organic-water separators in Enclosure 

2A?

What emissions calculation approach was used to estimate 

the oil-water and organic-water separators emissions?
U.S. EPA Information Collection Request for Off-Site Waste and Recovery Operations

If no, please explain.

If no, please explain.

If "Other", please explain:

Please list each OSWRO container requiring Level 1 or Level 2 control: 

Container ID Container capacity

Container emissions control level 

implemented

Drums < 55 gallons Level 1

Tanker Truck < 6,000 gallons Level 1/2

Railcar < 27,000 gallons Level 1/2

Rolloff/Dump Trailer < 40 cubic yards Level 1

Please enter any other comments regarding containers here:

The facility does not process individual, off-site 

drums. On-site generated waste containerized in 

drums, at times, may contain off-site material.

(add information for more containers as necessary)

Are you implementing work practices or other HAP control 

techniques beyond those required by the MACT standard?

Please provide the additional capital and annual 

costs of this practice above that required by the 

OSWRO NESHAP:

If yes, please describe the control technique(s):

Containers

Have you entered the OSWRO containers emissions in 

Enclosure 2A?

Have you completed all control information fields for your 

OSWRO containers in Enclosure 2A?

What emissions calculation approach was used to estimate 

the containers emissions?

Containers meet the requirements for level 1 or 

level 2. No off-site shipments received in 

containers requiring monitoring for "no detectable 

emissions" per Method 21.

See note above.

Please provide documentation demonstrating the basis for 

the containers emissions estimates. Are you providing 

emissions factors or source test data?

See note above - N/A.

If "Other", please explain:

See note above - N/A.
U.S. EPA Information Collection Request for Off-Site Waste and Recovery Operations

If no, please explain.

The Giant facility does not operate any surface 

impoundments.

If no, please explain.

If "Other", please explain:

If "Other", please explain:

The Giant facility does not operate any surface 

impoundments, and therefore, this tab is not applicable.

Please enter any other comments regarding surface 

impoundments here:

If yes, please describe the control technique(s):

Please provide the additional capital and annual costs of this 

practice above that required by the OSWRO NESHAP:

Surface Impoundments

Have you entered the OSWRO surface impoundments 

emissions in Enclosure 2A?

Have you completed all control information fields for your 

OSWRO surface impoundments in Enclosure 2A?

What emissions calculation approach was used to estimate 

the surface impoundments emissions?

Are you implementing work practices or other HAP control 

techniques beyond those required by the MACT standard?

Please provide documentation demonstrating the basis for 

the surface impoundments emissions estimates. Are you 

providing emissions factors or source test data?
U.S. EPA Information Collection Request for Off-Site Waste and Recovery Operations

Page 8 of 14

If no, please explain.

If no, please explain.

Are you implementing work practices or other HAP control 

techniques beyond those required by the MACT standard?

The Giant facility does not operate any process vents, and 

therefore, this tab is not applicable.

Please enter any other comments regarding process vents 

here:

If "Other", please explain:

If yes, please describe the control technique(s):

Please provide the additional capital and annual costs of 

this practice above that required by the OSWRO NESHAP:

If "Other", please explain:

Process Vent Emissions Information

Have you verified and/or corrected the process vent 

emissions for your OSWRO processes in Enclosure 2A?

Have you completed all control information fields for your 

OSWRO process vent streams in Enclosure 2A?

What emissions calculation approach was used to estimate 

the process vent emissions?

Please provide documentation demonstrating the basis for 

the process vent emissions estimates. Are you providing 

emissions factors or source test data?

The Giant facility does not operate any process vents.
U.S. EPA Information Collection Request for Off-Site Waste and Recovery Operations

Page 9 of 14

Tanks Emissions Information

Please list each OSWRO tank requiring Level 1 or Level 2 control: 

Tank ID

Tank capacity 

(gallons) Tank content MTVP1 Tank content AVP2 Tank height (feet)

Tank diameter 

(feet)

Tank average 

annual throughput

Tank emissions 

control equipment

K-666 50,000 50 13.5

Kiln (primary)/ Carbon 

Units (backup)

K-801 80,000 40.01 18.25

Kiln (primary)/ Carbon 

Units (backup)

K-802 80,000 40.01 18.25

Kiln (primary)/ Carbon 

Units (backup)

K-803 80,000 40.01 18.25

Kiln (primary)/ Carbon 

Units (backup)

1

 Maximum True HAP Vapor Pressure 

2

 Average HAP Vapor Pressure 

For each tank with an internal floating roof, please list the slotted ladder information: 

Tank ID

Number of ladders 

with slotted legs

Gasketed deck cover 

over slotted ladder(s)?

Ladder sleeve over 

slotted ladder(s)?

Pole wipers in place 

for slotted ladder 

legs?

N/A

For each tank with a fixed roof, please list the tank fitting information: 

Tank ID

Number of access 

hatches

Number of gauge 

hatches

Number of 

conservation vents

Number of 

valves/instruments

Number of 

emergency 

pressure relief 

vents

K-666 11 2 1 6 3

K-801 12 2 1 6 2

K-802 12 2 1 6 2

K-803 12 2 1 6 2

1

 Maximum True HAP Vapor Pressure

For each tank with a floating roof (internal or external), please list the tank information: 

Tank ID

Annual number of 

days roof rests on 

landing legs Length of landing legs

N/A

(add information for more tanks as necessary)

Have you entered the tanks emissions for your OSWRO 

processes in Enclosure 2A?

Have you completed all control information fields for 

your OSWRO storage vessels in Enclosure 2A?

What emissions calculation approach was used to 

estimate the tank emissions?

If no, please explain.

If no, please explain.

(add information for more tanks as necessary)

(add information for more tanks as necessary)

Please provide the additional capital and annual costs of this 

practice above that required by the OSWRO NESHAP:

Please provide documentation demonstrating the basis 

for the tanks emissions estimates. Are you providing 

emissions factors, source test data or other data?

See "Confidential Business Information" Summary

Are you implementing work practices or other HAP 

control techniques beyond those required by the MACT 

standard?

See "Confidential 

Business 

Information" 

Summary

If "Other", please explain:

If "Other", please explain:

If yes, please describe the control technique(s):

See "Confidential 

Business Information" 

Summary

Equations from AP-42 used to calculate emissions from tanks, 

which are based on the same algorithm as the "TANKS" 

program.

See "Confidential 

Business Information" 

Summary
U.S. EPA Information Collection Request for Off-Site Waste and Recovery Operations

Page 10 of 14

Tanks Emissions Information

Please enter any other comments regarding tanks here:

(add information for more tanks as necessary)
U.S. EPA Information Collection Request for Off-Site Waste and Recovery Operations

Page 11 of 14

Off-Site Material Treatment

If you treat off-site waste using biological degradation, please answer the following questions:

Please enter any other comments regarding off-site waste 

treatment here: N/A

Do you perform any testing or other practices to 

determine whether fouling agents may be in the waste 

received?

N/A

What method of off-site waste HAP reduction is used?

Waste HAP-containing materials are combusted 

for energy recovery in the cement kiln. HAP 

emissions are controlled by venting the emissions 

to the cement kiln or carbon canisters. 

How do you characterize the components of the waste 

products you receive that are treated with biological 

degradation?

N/A

If "Other" or more than one of the above applies, 

please explain.
U.S. EPA Information Collection Request for Off-Site Waste and Recovery Operations

Page 12 of 14

Startup and Shutdown Events

If no for any of the above, please explain:

Equipment Leaks

Organic and Oil-Water Separators

Process Vents

Tanks

Transfer Systems

Containers

Surface Impoundments

The United States Court of Appeals for the District of Columbia Circuit vacated portions of two provisions in the EPA’s CAA 

section 112 regulations governing the emissions of HAP during periods of startup, shutdown and malfunction (SSM). Sierra 

Club v. EPA, 551 F.3d 1019 (D.C. Cir. 2008). Specifically, the Court vacated the SSM exemption contained in 40 CFR 63.6(f)(1) 

and 40 CFR 63.6(h)(1), that are part of a regulation, commonly referred to as the “General Provisions Rule,” that the EPA 

promulgated under section 112 of the CAA. When incorporated into CAA section 112(d) regulations for specific source 

categories, these two, now vacated, provisions exempted sources from the requirement to comply with the otherwise 

applicable CAA section 112(d) emission standard during periods of SSM. To be consistent with the Court’s decision, facilities 

must comply with the applicable standards at all times.

For each emission source type, do the annual emissions estimate in the Enclosure 2A "Emissions (TPY)" field include the 

annual emissions from startup and shutdown events that you added in the "STARTUP EMISSIONS (TPY)" and "SHUTDOWN 

EMISSIONS (TPY)" fields? Please enter a separate response for each emissions point type below:

For each emission source type, can you comply with the emissions limitation and/or work practices in the regulation that apply 

during normal operation during startup and shutdown events? Please enter a separate response for each emissions point type 

below:

Surface Impoundments

Tanks

Equipment Leaks

Transfer Systems

Organic and Oil-Water Separators

Containers

Process Vents
U.S. EPA Information Collection Request for Off-Site Waste and Recovery Operations

Page 13 of 14

Startup and Shutdown Events

Tanks - Yes, startup/shutdown emissions 

are included in Enclosure 2A. Yes, 

compliance can be met during 

startups/shutdowns.

Equipment Leaks, Transfer Systems, 

Separators, Containers, Surface 

Impoundments, and Process Vents - N/A

Please provide the following information about all startup and shutdown events:

Equipment Leaks (i.e., pumps)/Transfer Systems, 

Tanks

Yes, except for pumps, which operate more 

intermittently.

Pump/Transfer Systems - when there is no 

longer a demand for the material to be 

transferred.

Tanks - Assume shutdown occurs when empty, 

and startup occurs when begin transferring 

material into tank. Therefore, this occurs during 

a cleanout or repair of the unit.

No relevant difference.

Through a control device until the unit is 

"opened" for cleanout or repair.

Pumps/Transfer Systems - Up to several times 

per day.

Tanks - Approximately 1/year.

The duration of the startup/shutdown process is 

negligible.

Pumps/Transfer Systems - Startup begins when 

the pump/transfer system begins to move 

material, and ends when the pump/transfer 

system ceases to move the material. 

Tanks - shutdown begins when the tank is 

emptied prior to being "opened" for cleanout or 

repair. Startup begins when the tank is closed 

and material is introduced to the tank. 

Pumps/Transfer Systems - For startup, moving 

equipment. No special concerns are associated 

with shutdown.

Tanks - For startup, access points closed to 

prevent spillage/emissions and moving 

equipment. No special concerns are associated 

with shutdown.

Same as normal operation

Same as normal operation

Same as normal operation

1.c. How does the startup or shutdown event compare to normal 

operations (e.g., differences in flowrate, temp., pressure, alternate fuels 

used, alternate control devices used, etc.)?

6. How do you determine the HAP emissions during the event? 

1. What emissions source types experience startup and shutdown events?

7. How are control devices and work practices used to minmize emissions during 

the startup or shutdown event?

8. What compliance determination method(s) do you use during startup and 

shutdown events (e.g., monitor with CEMS)? 

1.a. Under normal operating conditions, do these emissions sources 

operate continuously?

1.b. What triggers the equipment to experience a startup or shutdown 

event (e.g. hot startup, startup after an emergency shutdown, re-start, 

control device startup)?

2. How often do startup or shutdown events occur? 

1.d. How are emissions released to the atmosphere (e.g., through a 

pressure relief device)?

4. What marks the end of the startup or shutdown event?

3. What is the average and range of event duration?

5. What safety issues are connected with a startup or shutdown event?
U.S. EPA Information Collection Request for Off-Site Waste and Recovery Operations

Page 14 of 14

Startup and Shutdown Events

N/A

N/A

N/A

N/A

9.c. How much would HAP emissions be reduced compared to an 

uncontrolled event? (If "emission factor" is used as basis for emissions 

estimate, please provide the emission factor and sources of the emission 

factor.1

)

9. During startup and shutdown events, if you cannot comply with the emissions 

limitation and/or work practices in the regulation that apply during normal 

operation, what is the minimum emissions level that could be achieved? 

1

 If "source test" is used as basis for emissions estimate, please provide a copy of the 

source test.

Please enter any other comments 

regarding startup or shutdown here:

9.a. Please describe how HAP emissions would be minimized.

9.b. How much would it cost to minimize HAP emissions in this manner?
Enclosure 2a
Enclosure 2a

Page 1

Please complete this table for all OSWRO emission units. Please report all emissions related to the off-site waste handled and/or treated.

Facility Name

Emission 

Unit ID Process ID

Emission 

Release 

Point ID

SCC 

Code1

Emissions 

Start Date

Emissions 

End Date

Pollutant 

CAS 

Number2

Pollutant 

Name (include 

organic and 

non-organic 

pollutants)

Actual 

Emissions 

(TPY)

MACTAllowable 

Emissions 

(TPY)3

Routine 

Emissions 

Max Hourly 

(lbs/hr)

Startup 

Emissions 

(TPY)

Startup 

Emissions 

(lbs/hr)

Shutdown 

Emissions 

(TPY)

Shutdown 

Emissions 

(lbs/hr)

MACT Source 

Category

Emission 

Release 

Point 

Type4 

Stack 

Height 

(ft)

Exit Gas 

Temperature 

(°F)

Stack 

Diameter (ft)

Exit Gas 

Velocity 

(ft/sec)

Exit Gas 

Flow Rate 

(ft3/sec)

Fugitive 

Length (EW) (ft)

Fugitive 

Width (NS) (ft)

Fugitive 

Angle 

(degrees) 5

Longitude 

(decimal 

degrees)6

Latitude 

(decimal 

degrees)6

Is Control 

Measure In 

Place?

Control 

Measure 7

Control 

Measure 

Efficiency Comments

EXAMPLE 

ENTRY:

American Welding 

Paducah Plant 25 25 25 50310001 01/01/10 12/31/10 100414 Ethyl Benzene 2.45 4.32 6.7 1.24 0.08 0.61 0.2

Off-Site Waste 

and Recovery 

Operations vertical 44 1600 3.099999905 3.869999886 1758 NA NA NA -72.0789032 41.44273758 yes flare 98%

reduction efficency based on 

manufacturer guarantees

Giant Cement Co.

Storage 

Tanks:

K-666

K-801

K-802

K-803

Storage 

Tanks:

K-666

K-801

K-802

K-803

Primary:

Kiln Stack

331-ES-21

Backup:

Carbon Stack

STACU N/A [a] 1/1/2011 12/31/2011

Off-Site Waste 

and Recovery 

Operations vertical

Kiln 

Stack: 

295 feet 

Carbon 

Stack:

12 feet

Kiln Stack:

210-400 F

Carbon Stack:

Ambient

Kiln Stack: 

14.2 feet

Carbon 

Stack:

0.67 feet

Kiln Stack:

50 - 63

Carbon 

Stack: 

0 - 4.3 [c]

Kiln Stack:

7,920 - 

10,000 

Carbon 

Stack: 

0 - 1.5 [c] N/A N/A N/A

Kiln Stack:

80.440447

Carbon 

Stack:

80.441853

Kiln Stack:

33.241808

Carbon 

Stack:

33.242147 Yes

Primary:

Cement Kiln

Backup:

Carbon 

Adsorption

Primary:

>99.99%

Backup:

>95%

Primary: Destruction and 

Removal Efficiency (DRE) 

testing

Backup: Design Analysis

Giant Cement Co.

Eqpt. Leak 

Components

Eqpt. Leak 

Components

Eqpt. Leak 

Components N/A [a] 1/1/2011 12/31/2011

Off-Site Waste 

and Recovery 

Operations fugitive N/A N/A N/A N/A N/A 525 [d] 115 2 80.44215 33.241861 Yes

LDAR 

Program

[a] These SCC codes do not reflect the SCC codes used at to the Giant facility, and do not appear to be applicable to the Giant facility. The applicable SCC code for the cement manufacturing facility is 30500623. An NAICS code reflective of the OSWRO units is 562211.

[b] See the attached file, "Giant Cement Company OSWRO Calculations."

[c] The flow rates for the carbon unit are estimates. There is no normal, consistent airflow. The air through the carbon unit is based on pressure as air is released from a storage tank.

[d] The majority of the equipment leak components are located in the western half of the defined area.

1

 For SCC Code, please input one of the following codes:

SCC SCC Description

50310001 Waste Disposal, Solid Waste Disposal-Industrial, Non-TSDF Treatment, Storage, Disposal Processes, Equipment Leaks 

50310002 Waste Disposal, Solid Waste Disposal-Industrial, Non-TSDF Treatment, Storage, Disposal Processes, Containers

50310003 Waste Disposal, Solid Waste Disposal-Industrial, Non-TSDF Treatment, Storage, Disposal Processes, Tanks

50310004 Waste Disposal, Solid Waste Disposal-Industrial, Non-TSDF Treatment, Storage, Disposal Processes, Organic and Oil-Water Separators

50310005 Waste Disposal, Solid Waste Disposal-Industrial, Non-TSDF Treatment, Storage, Disposal Processes, Surface Impoundments

50310006 Waste Disposal, Solid Waste Disposal-Industrial, Non-TSDF Treatment, Storage, Disposal Processes, Transfer Systems

50310007 Waste Disposal, Solid Waste Disposal-Industrial, Non-TSDF Treatment, Storage, Disposal Processes, Process Vents

2

 See List of HAPs in separate worksheet for a table of CAS numbers and HAPs

3

 MACT- allowable emissions are the maximum emission levels allowed while in compliance with the MACT standards

4

 Emission point type choices include: fugitive, vertical, horizontal, goose neck, vertical with rain cap, or downward-facing vent

5

 Fugitive Angle: Specifies the rotation of the source from north (in the clockwise direction). The location coordinates should reflect the southwest corner of the area source as shown in this graphic: 

6 Location of stack or southwest corner of a fugitive emissions release point

7

 For control measures, please include all control measures used for that emission point, including but not limited to:

Activated Carbon 

Adsorption

list specific 

type in 

Control 

Measure 

Comments 

column

Combustor

list specific 

type in 

Control 

Measure 

Comments 

column

Electrostatic 

Precipitator

Fabric 

Filter/Baghouse

Flare

Pressurized Tank

Fixed Roof Tank

Fixed Roof Tank 

Vented to Control 

Device

External Floating 

Roof Tank

Fixed Roof Tank 

with Internal 

Floating Roof

Vapor Balancing

Floating Membrane 

Cover

Cover Vented to 

Control Device

High-Efficiency 

Particulate Air Filter 

(HEPA)

Leak Detection and 

Repair Program

Condenser

See separate file [b]

(annual average if the parameter varies)

Vertical Emissions Release Point Parameters Fugitive Emissions Release Point 

Parameters

See separate file [b]
Enclosure 2a

Page 2

Scrubber

list specific 

type in 

Control 

Measure 

Comments 

column

Multiple Controls in 

Series

list specific 

types in 

Control 

Measure 

Comments 

column

Other Control 

Device

describe in 

Control 

Measure 

Comments 

column

Pollution 

Prevention 

Technique

describe in 

Control 

Measure 

Comments 

column

Process 

Modification

describe in 

Control 

Measure 

Comments 

column
DRAFT

Pollutant Name CAS No.

Acetaldehyde 75070

Acetamide 60355

Acetonitrile 75058

Acetophenone 98862

2-Acetylaminofluorene 53963

Acrolein 107028

Acrylamide 79061

Acrylic acid 79107

Acrylonitrile 107131

Allyl chloride 107051

4-Aminobiphenyl 92671

Aniline 62533

o-Anisidine 90040

Asbestos 1332214

Benzene (including benzene from gasoline) 71432

Benzidine 92875

Benzotrichloride 98077

Benzyl chloride 100447

Biphenyl 92524

Bis(2-ethylhexyl)phthalate (DEHP) 117817

Bis(chloromethyl)ether 542881

Bromoform 75252

1,3-Butadiene 106990

Calcium cyanamide 156627

Captan 133062

Carbaryl 63252

Carbon disulfide 75150

Carbon tetrachloride 56235

Carbonyl sulfide 463581

Catechol 120809

Chloramben 133904

Chlordane 57749

Chlorine 7782505

Chloroacetic acid 79118

2-Chloroacetophenone 532274

Chlorobenzene 108907

Chlorobenzilate 510156

Chloroform 67663

Chloromethyl methyl ether 107302

Chloroprene 126998

Cresols/Cresylic acid (isomers and mixture) 1319773

o-Cresol 95487

m-Cresol 108394

p-Cresol 106445

Cumene 98828

2,4-D, salts and esters 94757

DDE 3547044

Diazomethane 334883

Dibenzofurans 132649

1,2-Dibromo-3-chloropropane 96128

Dibutylphthalate 84742

1,4-Dichlorobenzene(p) 106467

3,3-Dichlorobenzidene 91941

Dichloroethyl ether (Bis(2-chloroethyl)ether) 111444

1,3-Dichloropropene 542756

Dichlorvos 62737

Diethanolamine 111422

N,N-Diethyl aniline (N,N-Dimethylaniline) 121697

List of Hazardous Air Pollutants (HAP)
Pollutant Name CAS No.

List of Hazardous Air Pollutants (HAP)

Diethyl sulfate 64675

3,3-Dimethoxybenzidine 119904

Dimethyl aminoazobenzene 60117

3,3'-Dimethyl benzidine 119937

Dimethyl carbamoyl chloride 79447

Dimethyl formamide 68122

1,1-Dimethyl hydrazine 57147

Dimethyl phthalate 131113

Dimethyl sulfate 77781

4,6-Dinitro-o-cresol, and salts 534521

2,4-Dinitrophenol 51285

2,4-Dinitrotoluene 121142

1,4-Dioxane (1,4-Diethyleneoxide) 123911

1,2-Diphenylhydrazine 122667

Epichlorohydrin (l-Chloro-2,3-epoxypropane) 106898

1,2-Epoxybutane 106887

Ethyl acrylate 140885

Ethyl benzene 100414

Ethyl carbamate (Urethane) 51796

Ethyl chloride (Chloroethane) 75003

Ethylene dibromide (Dibromoethane) 106934

Ethylene dichloride (1,2-Dichloroethane) 107062

Ethylene glycol 107211

Ethylene imine (Aziridine) 151564

Ethylene oxide 75218

Ethylene thiourea 96457

Ethylidene dichloride (1,1-Dichloroethane) 75343

Formaldehyde 50000

Heptachlor 76448

Hexachlorobenzene 118741

Hexachlorobutadiene 87683

Hexachlorocyclopentadiene 77474

Hexachloroethane 67721

Hexamethylene-1,6-diisocyanate 822060

Hexamethylphosphoramide 680319

Hexane 110543

Hydrazine 302012

Hydrochloric acid 7647010

Hydrogen fluoride (Hydrofluoric acid) 7664393

Hydrogen sulfide 7783064

Hydroquinone 123319

Isophorone 78591

Lindane (all isomers) 58899

Maleic anhydride 108316

Methanol 67561

Methoxychlor 72435

Methyl bromide (Bromomethane) 74839

Methyl chloride (Chloromethane) 74873

Methyl chloroform (1,1,1-Trichloroethane) 71556

Methyl hydrazine 60344

Methyl iodide (Iodomethane) 74884

Methyl isobutyl ketone (Hexone) 108101

Methyl isocyanate 624839

Methyl methacrylate 80626

Methyl tert butyl ether 1634044

4,4-Methylene bis(2-chloroaniline) 101144

Methylene chloride (Dichloromethane) 75092

Methylene diphenyl diisocyanate (MDI) 101688

4,4'¬-Methylenedianiline 101779

Naphthalene 91203
Pollutant Name CAS No.

List of Hazardous Air Pollutants (HAP)

Nitrobenzene 98953

4-Nitrobiphenyl 92933

4-Nitrophenol 100027

2-Nitropropane 79469

N-Nitroso-N-methylurea 684935

N-Nitrosodimethylamine 62759

N-Nitrosomorpholine 59892

Parathion 56382

Pentachloronitrobenzene (Quintobenzene) 82688

Pentachlorophenol 87865

Phenol 108952

p-Phenylenediamine 106503

Phosgene 75445

Phosphine 7803512

Phosphorus 7723140

Phthalic anhydride 85449

Polychlorinated biphenyls (Aroclors) 1336363

1,3-Propane sultone 1120714

beta-Propiolactone 57578

Propionaldehyde 123386

Propoxur (Baygon) 114261

Propylene dichloride (1,2-Dichloropropane) 78875

Propylene oxide 75569

1,2-Propylenimine (2-Methyl aziridine) 75558

Quinoline 91225

Quinone 106514

Styrene 100425

Styrene oxide 96093

2,3,7,8-Tetrachlorodibenzo-p-dioxin 1746016

1,1,2,2-Tetrachloroethane 79345

Tetrachloroethylene (Perchloroethylene) 127184

Titanium tetrachloride 7550450

Toluene 108883

2,4-Toluene diamine 95807

2,4-Toluene diisocyanate 584849

o-Toluidine 95534

Toxaphene (chlorinated camphene) 8001352

1,2,4-Trichlorobenzene 120821

1,1,2-Trichloroethane 79005

Trichloroethylene 79016

2,4,5-Trichlorophenol 95954

2,4,6-Trichlorophenol 88062

Triethylamine 121448

Trifluralin 1582098

2,2,4-Trimethylpentane 540841

Vinyl acetate 108054

Vinyl bromide 593602

Vinyl chloride 75014

Vinylidene chloride (1,1-Dichloroethylene) 75354

Xylenes (isomers and mixture) 1330207

o-Xylenes 95476

m-Xylenes 108383

p-Xylenes 106423

Antimony Compounds 0

Arsenic Compounds (inorganic including arsine) 0

Beryllium Compounds 0

Cadmium Compounds 0

Chromium Compounds 0

Cobalt Compounds 0

Coke Oven Emissions 0
Pollutant Name CAS No.

List of Hazardous Air Pollutants (HAP)

Cyanide Compounds 0

Glycol ethers 0

Lead Compounds 0

Manganese Compounds 0

Mercury Compounds 0

Fine mineral fibers 0

Nickel Compounds 0

Polycylic Organic Matter 0

Radionuclides (including radon) 0

Selenium Compounds 0
Other ICR 

Response Info.


Giant Cement Company

OSWRO Section 114 Request

Organic HAP Emissions Calculations

Total VOC Emissions Source Groupings

Uncontrolled 

Emissions 

lb/yr

Assumed 

Control 

Efficiency 

(%)

Controlled 

Emissions 

lb/yr

Annual No. 

of Turnovers

Emissions/ 

Turnover 

(lb/turnover)

Max No. of 

Turnovers/ Hr Max lb/hr[1]

50K Tank Working 866.91 0.95 43.35 44.22 0.98 0.54 0.53

80K Tank Working 1387.05 0.95 69.35 44.22 1.57 0.23 0.35

Total Tank Working 5028.07 0.95 251.40 0.88

50K Tank Breathing 158.70 0.95 7.94 0.00091

80K Tank Breathing 257.25 0.95 12.86 0.00147

Tank Breathing 930.45 0.95 46.52 0.00237

Tank Total 5958.52 0.95 297.93 0.88

Equipment Leaks 5984.41 N/A N/A 0.68

Actual 

Emissions 

(TPY)

MACTAllowable 

Emissions 

(TPY)3

Routine 

Emissions 

Max Hourly 

(lbs/hr)

Startup 

Emissions 

(TPY)

Startup 

Emissions 

(lbs/hr)

Acetaldehyde 75070 0 N/A 0 0 0

Acetamide 60355 0 N/A 0 0 0

Acetonitrile 75058 0.0319024 0.0048 N/A 0.0282 0.0000 0.0282

Acetophenone 98862 0.0003894 0.0001 N/A 0.0003 0.0000 0.0003

2-Acetylaminofluorene 53963 0 N/A 0 0 0

Acrolein 107028 0 N/A 0 0 0

Acrylamide 79061 0 N/A 0 0 0

Acrylic acid 79107 0 N/A 0 0 0

Pollutant Name CAS No.

Vapor 

Weight 

Fraction 

(Fraction)

[1] Maximum lb/hr working losss emissions defined as working losses associated with the loading of one railcar at 27,000 gallons/hr into one 50K 

tank and three trucks into the 80K tanks

Total Tank Losses:

Equipment Leak Emissions:

Tank Emissions [1]

Total Working Losses:

Total 50K Breathing Losses:

Total 80K Breathing Losses:

Total Breathing Losses:
Acrylonitrile 107131 0.0317565 0.0047 N/A 0.0281 0.0000 0.0281

Allyl chloride 1070510 N/A000

4-Aminobiphenyl 926710 N/A000

Aniline 625330 N/A000

o-Anisidine 900400 N/A000

Asbestos 13322140 N/A000

Benzene (including benzene from gasoline) 71432 0.0008415 0.0001 N/A 0.0007 0.0000 0.0007

Benzidine 928750 N/A000

Benzotrichloride 980770 N/A000

Benzyl chloride 1004470 N/A000

Biphenyl 925240 N/A000

Bis(2-ethylhexyl)phthalate (DEHP) 1178170 N/A000

Bis(chloromethyl)ether 5428810 N/A000

Bromoform 752520 N/A000

1,3-Butadiene 1069900 N/A000

Calcium cyanamide 1566270 N/A000

Captan 1330620 N/A000

Carbaryl 632520 N/A000

Carbon disulfide 751500 N/A000

Carbon tetrachloride 562350 N/A000

Carbonyl sulfide 4635810 N/A000

Catechol 1208090 N/A000

Chloramben 1339040 N/A000

Chlordane 577490 N/A000

Chlorine 77825050 N/A000

Chloroacetic acid 791180 N/A000

2-Chloroacetophenone 5322740 N/A000

Chlorobenzene 1089070 N/A000

Chlorobenzilate 5101560 N/A000

Chloroform 676630 N/A000

Chloromethyl methyl ether 1073020 N/A000

Chloroprene 1269980 N/A000

Cresols/Cresylic acid (isomers and mixture) 13197730 N/A000

o-Cresol 954870 N/A000

m-Cresol 1083940 N/A000

p-Cresol 1064450 N/A000

Cumene 98828 0.0003205 0.0000 N/A 0.0003 0.0000 0.0003
2,4-D, salts and esters 94757

0 N/A000

DDE 35470440 N/A000

Diazomethane 3348830 N/A000

Dibenzofurans 1326490 N/A000

1,2-Dibromo-3-chloropropane 961280 N/A000

Dibutylphthalate 847420 N/A000

1,4-Dichlorobenzene(p) 1064670 N/A000

3,3-Dichlorobenzidene 919410 N/A000

Dichloroethyl ether (Bis(2-chloroethyl)ether) 1114440 N/A000

1,3-Dichloropropene 5427560 N/A000

Dichlorvos 627370 N/A000

Diethanolamine 1114220 N/A000

N,N-Diethyl aniline (N,N-Dimethylaniline) 1216970 N/A000

Diethyl sulfate 646750 N/A000

3,3-Dimethoxybenzidine 1199040 N/A000

Dimethyl aminoazobenzene 601170 N/A000

3,3'-Dimethyl benzidine 1199370 N/A000

Dimethyl carbamoyl chloride 794470 N/A000

Dimethyl formamide 68122 0.0003007 0.0000 N/A 0.0003 0.0000 0.0003

1,1-Dimethyl hydrazine 571470 N/A000

Dimethyl phthalate 1311130 N/A000

Dimethyl sulfate 777810 N/A000

4,6-Dinitro-o-cresol, and salts 5345210 N/A000

2,4-Dinitrophenol 512850 N/A000

2,4-Dinitrotoluene 1211420 N/A000

1,4-Dioxane (1,4-Diethyleneoxide) 123911 0.0000658 0.0000 N/A 0.0001 0.0000 0.0001

1,2-Diphenylhydrazine 1226670 N/A000

Epichlorohydrin (l-Chloro-2,3-epoxypropane) 1068980 N/A000

1,2-Epoxybutane 1068870 N/A000

Ethyl acrylate 1408850 N/A000

Ethyl benzene 100414 0.0021674 0.0003 N/A 0.0019 0.0000 0.0019

Ethyl carbamate (Urethane) 517960 N/A000

Ethyl chloride (Chloroethane) 750030 N/A000

Ethylene dibromide (Dibromoethane) 1069340 N/A000

Ethylene dichloride (1,2-Dichloroethane) 1070620 N/A000

Ethylene glycol 107211 0.0000424 0.0000 N/A 0.0000 0.0000 0.0000

Ethylene imine (Aziridine) 1515640 N/A000
Ethylene oxide 75218

0 N/A000

Ethylene thiourea 964570 N/A000

Ethylidene dichloride (1,1-Dichloroethane) 753430 N/A000

Formaldehyde 50000 0.0007116 0.0001 N/A 0.0006 0.0000 0.0006

Heptachlor 764480 N/A000

Hexachlorobenzene 1187410 N/A000

Hexachlorobutadiene 876830 N/A000

Hexachlorocyclopentadiene 774740 N/A000

Hexachloroethane 677210 N/A000

Hexamethylene-1,6-diisocyanate 8220600 N/A000

Hexamethylphosphoramide 6803190 N/A000

Hexane 110543 0.0559785 0.0083 N/A 0.0495 0.0000 0.0495

Hydrazine 3020120 N/A000

Hydrochloric acid 76470100 N/A000

Hydrogen fluoride (Hydrofluoric acid) 76643930 N/A000

Hydrogen sulfide 7783064

0 N/A000

Hydroquinone 1233190 N/A000

Isophorone 785910 N/A000

Lindane (all isomers) 588990 N/A000

Maleic anhydride 1083160 N/A000

Methanol 67561 0.0796558 0.0119 N/A 0.0705 0.0000 0.0705

Methoxychlor 724350 N/A000

Methyl bromide (Bromomethane) 748390 N/A000

Methyl chloride (Chloromethane) 748730 N/A000

Methyl chloroform (1,1,1-Trichloroethane) 715560 N/A000

Methyl hydrazine 603440 N/A000

Methyl iodide (Iodomethane) 748840 N/A000

Methyl isobutyl ketone (Hexone) 108101 0.0066338 0.0010 N/A 0.0059 0.0000 0.0059

Methyl isocyanate 6248390 N/A000

Methyl methacrylate 806260 N/A000

Methyl tert butyl ether 1634044 0.0377282 0.0056 N/A 0.0334 0.0000 0.0334

4,4-Methylene bis(2-chloroaniline) 1011440 N/A000

Methylene chloride (Dichloromethane) 75092 0.1149885 0.0171 N/A 0.1017 0.0001 0.1017

Methylene diphenyl diisocyanate (MDI) 1016880 N/A000

4,4'¬-Methylenedianiline 1017790 N/A000

Naphthalene 91203 0.0000114 0.0000 N/A 0.0000 0.0000 0.0000

Nitrobenzene 989530 N/A000
4-Nitrobiphenyl 92933

0 N/A000

4-Nitrophenol 1000270 N/A000

2-Nitropropane 794690 N/A000

N-Nitroso-N-methylurea 6849350 N/A000

N-Nitrosodimethylamine 627590 N/A000

N-Nitrosomorpholine 598920 N/A000

Parathion 563820 N/A000

Pentachloronitrobenzene (Quintobenzene) 826880 N/A000

Pentachlorophenol 878650 N/A000

Phenol 108952 0.0000878 0.0000 N/A 0.0001 0.0000 0.0001

p-Phenylenediamine 1065030 N/A000

Phosgene 754450 N/A000

Phosphine 78035120 N/A000

Phosphorus 77231400 N/A000

Phthalic anhydride 854490 N/A000

Polychlorinated biphenyls (Aroclors) 13363630 N/A000

1,3-Propane sultone 11207140 N/A000

beta-Propiolactone 575780 N/A000

Propionaldehyde 1233860 N/A000

Propoxur (Baygon) 1142610 N/A000

Propylene dichloride (1,2-Dichloropropane) 788750 N/A000

Propylene oxide 755690 N/A000

1,2-Propylenimine (2-Methyl aziridine) 755580 N/A000

Quinoline 912250 N/A000

Quinone 1065140 N/A000

Styrene 100425 0.0032839 0.0005 N/A 0.0029 0.0000 0.0029

Styrene oxide 960930 N/A000

2,3,7,8-Tetrachlorodibenzo-p-dioxin 17460160 N/A000

1,1,2,2-Tetrachloroethane 793450 N/A000

Tetrachloroethylene (Perchloroethylene) 127184 0.0008783 0.0001 N/A 0.0008 0.0000 0.0008

Titanium tetrachloride 75504500 N/A000

Toluene 108883 0.0572564 0.0085 N/A 0.0506 0.0000 0.0506

2,4-Toluene diamine 958070 N/A000

2,4-Toluene diisocyanate 5848490 N/A000

o-Toluidine 955340 N/A000

Toxaphene (chlorinated camphene) 80013520 N/A000

1,2,4-Trichlorobenzene 1208210 N/A000
1,1,2-Trichloroethane 79005 0 N/A 0 0 0

Trichloroethylene 79016 0.0004172 0.0001 N/A 0.0004 0.0000 0.0004

2,4,5-Trichlorophenol 95954 0 N/A 0 0 0

2,4,6-Trichlorophenol 88062 0 N/A 0 0 0

Triethylamine 121448 0.0009185 0.0001 N/A 0.0008 0.0000 0.0008

Trifluralin 1582098 0 N/A 0 0 0

2,2,4-Trimethylpentane 540841 0 N/A 0 0 0

Vinyl acetate 108054 0 N/A 0 0 0

Vinyl bromide 593602 0 N/A 0 0 0

Vinyl chloride 75014 0 N/A 0 0 0

Vinylidene chloride (1,1-Dichloroethylene) 75354 0 N/A 0 0 0

Xylenes (isomers and mixture) 1330207 0.0077975 0.0012 N/A 0.0069 0.0000 0.0069

o-Xylenes 95476 0.0014618 0.0002 N/A 0.0013 0.0000 0.0013

m-Xylenes 108383 0.0028777 0.0004 N/A 0.0025 0.0000 0.0025

p-Xylenes 106423 0.0029281 0.0004 N/A 0.0026 0.0000 0.0026

TOTALS 0.4414016 0.0658 0.3905 0.0002 0.3905

[1] Tanks do not have a typical "start-up." Therefore, we have assumed start-up is commencing the re-filling of a tank after a shut-down. These shutdowns are considered to occur once per year and the start-up is conservatively assumed to take one hour. Therefore, the tank start-up emissions 

represent the maximum one-hour emissions scenario.
Shutdown 

Emissions 

(TPY)

Shutdown 

Emissions 

(lbs/hr)

Actual 

Emissions 

(TPY)

MACTAllowable 

Emissions 

(TPY)3

Routine 

Emissions 

Max 

Hourly 

(lbs/hr)

Startup 

Emissions 

(TPY)

Startup 

Emissions 

(lbs/hr)

Shutdown 

Emissions 

(TPY)

Shutdown 

Emissions 

(lbs/hr)

N/A N/A 0 N/A 0 N/A N/A N/A N/A

N/A N/A 0 N/A 0 N/A N/A N/A N/A

N/A N/A 0.0955 N/A 0.0218 N/A N/A N/A N/A

N/A N/A 0.0012 N/A 0.0003 N/A N/A N/A N/A

N/A N/A 0 N/A 0 N/A N/A N/A N/A

N/A N/A 0 N/A 0 N/A N/A N/A N/A

N/A N/A 0 N/A 0 N/A N/A N/A N/A

N/A N/A 0 N/A 0 N/A N/A N/A N/A

Equipment Leak Emissions
N/A N/A 0.0950 N/A 0.0217 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A 0.0025 N/A 0.0006 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A 0.0010 N/A 0.0002 N/A N/A N/A N/A
N/A N/A

0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A 0.0009 N/A 0.0002 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A 0.0002 N/A 0.0000 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A 0.0065 N/A 0.0015 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A 0.0001 N/A 0.0000 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A
N/A N/A

0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A 0.0021 N/A 0.0005 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A 0.1675 N/A 0.0382 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A 0.2383 N/A 0.0544 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A 0.0198 N/A 0.0045 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A 0.1129 N/A 0.0258 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A 0.3441 N/A 0.0786 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A 0.0000 N/A 0.0000 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A
N/A N/A

0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A 0.0003 N/A 0.0001 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A 0.0098 N/A 0.0022 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A 0.0026 N/A 0.0006 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A 0.1713 N/A 0.0391 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A
N/A N/A

0 N/A0 N/A N/A N/A N/A

N/A N/A 0.0012 N/A 0.0003 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A 0.0027 N/A 0.0006 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A0 N/A0 N/A N/A N/A N/A

N/A N/A 0.0233 N/A 0.0053 N/A N/A N/A N/A

N/A N/A 0.0044 N/A 0.0010 N/A N/A N/A N/A

N/A N/A 0.0086 N/A 0.0020 N/A N/A N/A N/A

N/A N/A 0.0088 N/A 0.0020 N/A N/A N/A N/A

N/A N/A 1.3208 N/A 0.3015 N/A N/A N/A N/A