p.1 

OAR Box 1384 

Prepped by Charmelle Mathews 

Document Number: 

86) ll-E-46 

Docket Number: 

A-94-52 

Printed 7/2/2008 8:42:06 AM Sheet 86 of 264 
•A 4 A W I 4 • /. « » 

SEP.""5 '96~~3:41PM CR/PL MARBLE EPA ESP CCPC 419 521 3318 P.1 

< -•* * .. .\ 

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A-94-52 

COHTACT fiSPORT 

Froa» MaaeieinR strum, Environmental Bugineer 

««•£? SSSf S firiI«n;689T

in93

 ^c<,n8Umer p"

duot

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Data of Contact: Augvifit 14 and ID, 1996 

P*r*an Contactss Mark Campbell, Plant Manager 

TttlcrpboaA Vunban 419 57.1 3210 (FAX 413 521 3318 } 

'^/^'AP'^-V'V-' 

*5mi 

CONTAC* SUMMARYt 

1

 w _ 

Mr. Campbell was contacted to cant ism information cbnca±Bed-*ri-S*L__ 

screening survey from August 1993. Hr. Campbell noted that aince ~~~ 

that time, NewartcaLm Limited Partnership ownership changed i-o 

CR/Pb Limited Partnership, which is probably not u small business. 

Mr. Campbell explained that the facilit y uses three different resin 

systems. Ona of these system io for mold making, and ha« a. styren* 

content of 45*. The other two are for tha cultured iVixbla 

production and have etyrene contems of 34% and between 33 34%. 

Pages li*om the Material Safety Data Sheets (MSDS) which indicate 

these values are attached. 

Thinner iiBftri is no more than 2 drums per year, and thurefure is nor. 

expected to change the styrene content percentage of the resin whan 

added to the resin ae applied. Th«? thinnncr ia un«d to lower Lh« 

viscosity of a pigment dispersion. 

The facilit y uses two different proaoanee -- batch mixing (Uke the 

process doiita at smaller custom shops) and high volume automatic 

mining which uses specialized caa ting e<juipment and hsc a more 

eftnt-i-AuouB figw. Although the facilit y uses aimUat styrene 

content resins for both processes, Mr. Campbell thought that other 

facilitie s that do batch mixing may use a higher aLyrwiG* rant ent to 

lower the viscosit y of tiie resin. 

Mr. Campbell noted that the firm no longer uses methylene chloride 

as cleaning solvent. They use a cleaning Solvent that is non 

haaardous (per the Department, of Traaporlation definltiou) called 

B2000 and i e made by Superior Solvent* and Chemicalo. Hi*. Campbell 

identified the ingredients over the pnone and Madeleine? waa unable 

to identify any ftf rhem as oa the HAS list . Mr, Campbell Is 

attaching -? page indicating ingredients from the MSDS oheut ao this 

can be verified. 

Above, re.port is accurate ttf.iyLPl (signature and date) 
SEP. 5 '96 3:41PM CR/PL MARBLE^ SAFETY DATA SHG419 521 3318 

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SpPROVED BY U S DE&T OF LABOR, ESSENTIALLY SIMILAR TO FORM <£lSHftlf-V. • 

SUPERIOR SOLVENTS AND CHEMICALS 

400 West Regent Street 

IndianapoWt, Indiana ^233 

EMERGENCY PHONE NUMBERs ai?«7at-4«©0 I A ^ aa-! 

CHEMICAL NAME ft SYNONYMS? SOLVENT BLEND 

I. PHYSICAL DATA 

BOXLXNQ POINT:(*F) 390 

SPECIFIC GRAVITY (Water • 1): 1.049 

POUNDS / GALLONS S.74 

VAPOR PRESSURE:<P*i> 0.009? 

VAPOR DENSITY (Air * 1>; > 1 

SOLUBILITY IN WATER CO » 68.646 

DRY' TIME (Ether « 1) : > 1 

* VOLATILE BY VOLUME£ 100-

APPEARANCE« Water White Liquid 

ODORi Typical solvent 

i. .«. TRAOE NAME: 8-6000 RESIpCLEANtf 

MATERIAL81 

N-MKTHYLPYRROLIDONE 

DIMETHYL QLUTARATE 

DIMETHYL ADIPATE 

DIMETHYL SUCCINATE 

II. HA2ARD0US INGREDIENTS 

CAS * VOL <*> 

©7e--S«-4 > 29 

ili$-<-0-0 " > 9 

6S7-93-0 > 4 

106-65-0 > 4 

ACGIH 

TWA (ppm) 

N/E 

N/E 

N/E 

N/E 

; OSHA 

ruo. (pdn: 

N/E 

N/E 

N/E 

N/E 

III. FIRC ft EXPLOSION HAZARD DATA 

LOWER EXPLOSIVE LIMIT IN AIR <* py vol): e.6 

UPPER EXPLOSIVE LIMIT IN AIR <* by voD'f 9.3 

FLASH POINT <T,C. C. defl FM 196 Uowe9t flashing component) I 

EXTINGUISHING 

MEDIA 

SPECIAL FIRE 

FIGHTING PROCEDURES 

UNUSUAL EXPLOSION 

AND FIRE PROCEDURES 

Carbon Dioxide, Alcohol Foam, or Dry Chemical 

S.C.8.A« for fire fighting in enclosed aifeat. 

Water spray aay be used to cool exposed ^on'tai nfr 

and protect personnel. In advanced firei* «ain|i 

a safe distance fro* sealed containers. ] 

COMBUSTIBLE LIQUID! U&e away from he*t ^nd ope 

flame. Use only with adequate ventilation." Kefp 

container closed when not in use. 

Legal responsibility is assumed only for the fact that all studies 1 report hd 

here ft all opinions ^e those of qualified *xperfcs. Buyer assumes ill. ris is 

and liabilities. The buyer accepts and' u&es this material on these ] eoirtd it e 

Page i of 3 

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cinsn ura-aa aoid3dns u^er-isa &• §9.Mp 
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SEP. 5 '96 3:42PM CR/PL MARBLE 419 521 3318 'P.3 

MtYTERlAL SAFETY DNTA SHEET 

lnterplostic Corporation 

1225 Walters Boulevard 

Oednaift Heights, MN 55110-5145 

24-Hour Emergency Tslophon* C800) 424-9.700 

0 

ATTN: PLANT MGR/SAFETY 0|R 

Rem'sion Datei OX/IS/^ 

Issue Date: 09/29 ,'94 

MSDS File ids HSOSLETO 

Custoner No: 

Tht* MSDS cnnplieo uith 79 CPR 1?10.120Q (Tha Hazard Commun ico t ion Standard) 

SECTION I « Product Identification 

Product Mama: S942 PE RESIN 

WNf t Muf.ibor; UN1S66 

General or Generic ID: Unneturated Polyester Resin 

H<j?*rrl C *«o i f icat i on; Flammable Liquid 

SECTION II - Hazardous Components 

Irifjr ttd ien t C**. No. Purr ont OSHA-PEL ACGIH-TLU NOTE 

UnsoturainH Polyester Psse Reain See Intinx 65-6 ? None-Eftl-h, Moil0-Ee>ti 

Kl-yrpr,* 100-42-5 33-34 50 pprn Tl-Jrt 50 ppm tl') 

( 1) OSHA ceilin g valu a is 100 ppm and ACGIH thurt term *xpc?,ure limi t <STEL> i » 

100 fjpiw. NfQSH reoommwnds a limi t of 50 ppm, 8-hour TUIA; 100 ppm 15 minute 

i:-*) I >r.g. 

SECTION II I - Physical Deia 

Property 

Initia l Ejr.iling Point For Styrona 

'Jafif-r Pcesaure 

Uap.ir f)t.infj. ty 

Spr:c i P»c, tiav j t y 

Por.w.iir k«n-woiat i les 

a por'A l i rjn Rate 

For Styrene 

A ir - 1 

heeaurement 

293.40 OEG F 

JD 760. QO MIIHG 

4.3 MMHG 

(20.00 DEG C) 

3.6 

1.0-1.2 

$ 7?. DO DEG F 

(25.00 DEC C> 

65-6/** 

Slower than Ether 

3 
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SEP. 5 '96 3:42PM CR/PL MARBLE 419 521 331G MM P.4 

, MATERIAL SAFETY DATA SHEET 

Information Telaphunt No.; (800) 874-1807 In North Carolina Call: (000) 342-7201 

REICHHOLD CHEMICALS. INC. 

f>0. Box 13582 

Rcscorch Triangle Pork 

Durham. NC 27709 

ALL CHEMICAL EMERGENCIES 

1-800-424-9300 

I»aua Data: 07/01/93 Pnge 1 

rsw«ac8aiiaeszaBasKmns8rss»BSasBSM«9HSHaB«8BaMBuaasr a 

SECTION I - PRODUCT IDENTIFICATION 

Product Code: 33-S41-00 

Trede Na»e* POLYLITE(R) 33-54t-00 

Product CUit: Unsaturated Polyester 

C-.A.8. Nunber: Mlxturt 

HMI8 Rating: Haalth - 8» Fir* - 3 Raactivity «= 1 

SECTION XI - INGREDIENTS 

Ingredients CAS t 

Maximum 

Contant 

Exposure 

Limits 

Polyaatar resin 

Styrene Hononer 

Propriatary 54.0 X 

100-4S-5 49.0 Z 

iBaBaKKiBSBaaBKiiBassasiiaeBteoKBwi 

SECTION III - PHYSICAL DATA 

Nona assigned 

50.0 ppm 

IBBBfl9«'.'VyraSI 

Bailing Point: £95 Dog. F. Vapor Density: Heavier than Air,, 

VoUtilt X: 45 - 49 Spacific Crav: 1.03 - 1.10 

evep. Rato: Slower than n-Butyl Acatata. 

>pearanee: Pink claar liquid. Pungant odor. 

SECTION IV - FIRE AND EXPLOSION HAZARD DATA 

Flannability CUts: ic Flash Point: 69 Dag. F. LEL 1.1 

-EXTINGUISHING MEDIA: 

Uattr spray, foa*, dry ehemieel> carbon dioxida or any 

Class B extinguishing agent. 

-SPECIAL FIREF1CHTINC PROCEDURES: 

Firefighters and others exposed to vapors or products of 

combustion should wear self-contained breathing apparatus. 

Equipnent should be thoroughly decontaminated after ust. 

-UNUSUAL FIRE ft EXPLOSION HAZARDS: 

At elevated temperatures, such as in a fire, polymerization 

nay take place. If polyaerization takes place in a closed 

container, there is the possibility of violent rupture of 

the container. Product vapora nay form an explosive mixture 

in air. 

|(UBMaBau g BaK p sa(VaaalB eMnuuBaa»BBara«au«Ba?BSS8isaBaasBBCB' H 

8ECTION V - HEALTH HAZARD DATA 

-PERM88IBLE EXP08URE LEVEL: 

OSHA PEL and ACCIH TLV for atyrene are both 50 ppm for an 8-hour 

Tine Weighted Average (TUA). The OSHA and ACCIH Short Tern 

(cont.) 

C i 

Thl* i'nfwmfltioi". is fur* eVed without warranty, representing, inducement or license of doy ki.ul. wc.pt lli.l fi *5 accurate to the best of fleichhold Chemical*. Inc* 

knowlaf-ga. nr nhMlned Iron. source* believed by noieMiotd Chemicals. Inc. to be oeeuraie. ana lUiehhoJd Chemicals. Inc. du.. not assume any leaa! responsibility wr 

use or rnli-nnre <.f»o« lame. Customer* er* .ncouragod to conduct their own tests. Before ua.no O-V pioduct. ..«<" il» label-