# OAR Box 1413
Prepped by Ollie Stewart



### Document

Number: 

# 17)11-1-1 7

Docket Number: 

# A-94-5 2

Printed 7/9/2008 3:11:21 PM Sheet 17 of 114 P. 1(Adopte d Marc h 6,1987)(Amendc d April 3,1987)(Amende d Augus t3,1990 ) (Amende d Decembe r7,1990 ) (Amende d Augus t2,1991)(Amende d July 10,1992 ) (Amende d Ma

y 13,1994 ) RUL E 1162
. POLYESTE RRESI N OPERATION S (a ) Applicabilit

y Thi s rul e shal l appl

y t o al l polyeste r resi n operation s tha tfabricate , rework , repair , o rtouch-u p product s fo r commercial , military , o r industria l us e including , hu tno tlimite d to , boats , tubs , pools , showe r enclosures , spas , bathroo m fixtures, jigs , tools , molds , airpollutio n contro l equipment , sewag e treatmen tequipment , storag e tanks , transportation parts , an d othe r industria l an d consume r products.
. (b ) Definition s Fo r th e purpos e of

this rule , th e followin g definition s shal l apply : (1 ) AIRLES S SPRAY i s a coatin g applicatio n syste m i n whic h th e coatin g flui d i s suppUe

d t o th e gu n unde r fluid pressure an d ai r i s no tadde d t o th e gun . (2 ) AIR-ASSISTE D AIRLES S SPRA Y i s a coatin g applicatio n syste m i n whic h th e coating flui d i s supplie d t o th e gu n unde r flui d pressur e an d ai r i s combine d atth e spra

y cap . (3 ) CORROSION-RESISTAN T MATERIAL S ar e polyeste r resi n material s use d t o mak

e product s fo r corrosio n resistantapplication s suc h a s tooling , fue l o rchemica

l tanks an d boa thulls
. (4 ) EXEMP T COMPOUND S ar e an y o f th e followin g compounds : (A ) Grou

p I \ chlorodifluoromethan e (HCFC-22 ) dichlorotrifluoroethane (HCFC-123 ) tetrafluoroethane (HFC-134a ) dichlorofluoroethan e (HCFC-141b ) chlorodifluoroethan e (HCFC-142b ) trifluoromethane (HFC-23 ) 2-chlorO"l,l,l,2-tetrafluoroethan e (HCFC-124 ) pentafluoroethan e (HFC-125 ) 1,1,22-tetrafluoroethan e (HFC-134 ) 1,1,1-trifluoroethane (HFC-143a ) 1,1-difluoroethane (HFC
- 152a) N cycli c branched , o r linear , completel y fluorinate d alkane s

1162- 1 

## JI-J
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wwt-jfwggwwterc- D too *-<- * -JS'-on i cn-f-R_au_

> (-ii_sij.ii P. 3

StK V VWa J»t ) j^ov g

Rul e 116 2 (Con g (Amende d Ma y 13,1994 )

(5 )
(6 )

(7 )

(8 )

(9 ) cycli c branched , o rlinear , completel y fluorinate d ether s wit h n o

unsaturation s cyclic , branched , o r linear , completel y fluorinated tertiar y amine s with n o unsaturations sulfur-containing perfluorocarbon s wit h n o unsaturation s an d wit h sulfu rbond s onl y t o carbo n an d fluorin e (B ) Group II methylen e chlorid e carbo n tetrachlorid e 1,1,1-trichloroethane (methy l chloroform ) trichlorotrifluoroethan e (CFC-113 ) dichlorodifluoromethan e (CFC-12 ) trichlorofiuoromethan e (CFC-11 ) dichlorotetrafluoroethan e (CFC-114 ) chloropentafluoroethan e (CFC-115 ) Us e o f Grou p n compound s ma y b e restricte d i n th e futur e becaus e the y ar e eithe rtoxic , potentiall y toxic , o r upper-atmosphere ozon e depleters , 'o rcaus e othe renvironmenta l impacts
. Specifically , th e .Distric tBoar d ha s establishe d a polic y t o phas e ou tchlorofluorocarbons (CFCs) , methy l chloroform (1,1,1-trichloroethan e o rTCA) , and carbon tetrachlorid e b y Decembe r31,1995
. FIR E RETARDAN T MATERIAL S ar e polyeste r resi n material s use d t o mak e product

s tha tar e resistantt o flam e o r fire. GE L COA T i s a polyeste r resi n surfac e coating , eithe r pigmente d o r clear , tha tprovide s a cosmeti c enhancemen tand improves resistanc e t o degradatio n from exposure t o th e elements
. GENERA L PURPOS E POLYESTE RRESIN S ar e material s tha tar e no tcorrosio n resistant , fire retardaiit, hig h strength , vapo r suppressed , o r ge l coats . HIGH-STRENGT H MATERIAL S ar e polyeste r resins whic h hav e castin g tensil e strengt

h of 10,00 0 ps i o rmore an d whic h ar e use d fo r manufacturing o f

high performance boats an d skis
. • HIGH-VOLUME , LOW-PRESSURE
. (HVLP ) SPRA Y i s a coatin g applicatio n system whic

h i s operate d atai r pressure o f betwee n 0. 1 and 1 0 pound s pe r square inc h gaug e (psig ) a tth e air ca p of th e spra y gun .

116 2 - 2^g:l6« 1 SCflGM D PlDMI N SER V 90 9 39 6 335 0 _P. 4



### Hol e 1162 (Cont. ) (Amended Ma y 13,1994 )

(10 ) MONOME Ri s a relativel y low-molecular-weightorgani c compoun d such

. a s styrene tha tcombine s wit h itself , o r othe rsimilar compounds , b y a cross-linking reactio n t o becom e a cure d thermosettin g resin
. (11 ) POLYESTE RRESI N MATERIAL S are unsaturate d polyeste r resins , such a s isophthalic , orthophthalic , halogenated , bispheno l A , viny l ester , o rfura n resins ; cross-linkin g agents ; catalysts ; ge l coats ; inhibitors ; accelerators ; promoters ; an d an y othe rmaterial containin g VO C use d l n polyeste r resi n operations
. (12 ) POLYESTE RRESI N OPERATION S fabricate , rework , repair , o r touch-up products fo r commercial , military , o r industria l us e b y mixing , pouring , han d laying-up , impregnating , injecting , forming , winding , spraying, and/o rcurin g b y using unsaturate d polyeste r resi n materials
. (13 ) PULTRUSIO N i s a proces s where continuou s roving strand s ar e move d throug h a strand-tensionin g devic e int o a resi n bath fo r impregnatio n an d the n passe d throug h a heate d di e fo r curing
. (14 ) REPAI Ri s tha tportio n of th e fabrication proces s tha trequire s th e additio n o f

polyeste r resi n material s t o portion s o f a previousl y fabricate d produc ti n orde r t o men d damage
. (15 ) TOUCH-U P i s tha tportio n o f th e proces s tha ti s necessar y t o cove r mino rimperfections
. (16 ) VAPO RSUPPRESSE D RESIN i s a polyeste r resi n materia l whic h contain s additive s t o reduc e VO C evaporatio n los s t o les s tha n sixt y (60 ) grams pe rsquar e mete ro f surface are a a s determine d an d certifie d b y resi n manufacturers
. (17 ) VOLATIL E ORGANI C COMPOUND (VO Q mean s an y volatil e chemical compoun d tha tcontain s th e elemen tcarbon , excludin g methane , carbo n monoxide , carbo n dioxide , carboni c acid , metalli c carbide s and carbonates , ammoniu m carbonate , an d exemp tcompounds
. (c ) Requirements (1 ) Fo reac h process , a perso n operatin g a polyeste r resi n operatio n shal l comply wit

h eithe r th e materia

l requirement

s o r on e o f

th e applicabl e proces s requirements se tfort h below :

1162- 3P. 5



### Rol e 1162 (Cont ) (Amende d Ma y 13,1994 V

(2 )

(3 )

(4 ) 

### (A ) Materia l Requirement s

A perso n shal l no t

us e apolyeste

r resi n materia l i n apolyester resi n operatio n whic

h ha s amonome

r conten t i n exces s of

th e limit s specifiedi n th e Tabl e below

.

Polyeste rResm Materials General Purpose Polyester Resi a Corrosion-Resistan

t Fir © Retardan

t Hig h Strengt

h O u r Ge l Coat Pigmented Gel Coa

t Monome rConten ti n

Polyeste r Resi a Material s a s Applie d (B y WeightPercent ) 3 5 4 8 4 2 4 8 5 0 4 5 

### (B ) Proces s Requirement s (i ) Th e weigh

t los s o f polyeste r material s shal l b e les s tha n fou r (4 ) percen t

whe n aclosed-mol dsystemi s used , (ii ) Whe

n avapor suppresse dresi n i s used , th e -Weigh t los s from VO C emission s shal l no t

exceedsixt

y (60 ) gram s pe r

square meter o f exposedsurfac e areadurin g resi n polymerisation , (iii ) A pultrusio n operatio n shal l hav e covere dwet-ou t baths

. Fro mth e exi

t of th e bat h t o th e di e al l bu t

1 8 inche s o f

th e prefor mdistanc e shal l b e enclose dt o minimiz e ai r flow

. Th e weigh

t los s o f polyeste r material s shal l b e les s tha n thre e (3 ) percen t

i n apultrusio n operation

. Fo r sprayin g operations , i n additio n t o complying wit h th e requirement s specifiedi n paragrap h (c)(1) , aperso n shal l us e high-volume-low

pressure (HVLP) , airless , air-assiste dairless , o r electrostati c spra

y equipment

. Fo r

touch-u p andrepair , ahand-held , air-atomize dspra y gun whic h ha s acontaine

r fo r resi n a s pa n o

f th e gun ma

y b e used

. An y perso n operatin g apolyester resin operatio n shal l kee p th e resi n material s i n close

dcontainer s except

whe n fillin

g o r emptying th e container

. Solven t cleanin g operation s shal l compl y wit h Rul e 117 1 - Solven

t Qeanin g Operations

. . .

116 2 - 4fie 116 2 (Cont ) (Amende d Ma y 13,1994 )

(d ) Contro l Equipmen t I n lie u o f

complying wit

h th e requirement

s o f paragraph (c)(1 ) an d (c)(2) , a perso n ma

y instal l an d operat e a n emissio n contro l syste m whid i i s designe d an d operate d i n accordanc

e with guideline s publishe d i n th e 20t h Editio n o f

th e Industrial Ventilatio n Manual b y th e America n Conferenc e o f Governmenta l Industrial Hygienist

s fo r th e collectio n o f

fugitiv e emission s from polyeste r resi n materials , an d whic

h system i s approvedb y th e Executiv e Officer' s designee , an d ha s a n overal l capmr

e an d contro l efficiency o f 9 0 percen to r mor e o n a mas s basis
. (e ) Recordkeepin g Requirement s (1 ) A perso n subjec

tt o th e provision s o f

thi s rul e shal l maintai n dail y records
. Suc

h record s shal l b e mad e availabl e t o th e Executiv e Officer' s designe e upo n reques tan d sha U b e kep tfo r no tles s tha n tw o years . Th e record s shall contain ; (A ) Th e manufacturer' s name , th e typ e an d amoun to f eac h o f th e polyeste rresi n material s used ; an d (B ) Th e weigh t(i n percent ) o f monome rfo r al l polyeste r resi n materials , and , i f

adding VOC-containin g material s t o th e polyeste rresin , th e amounto f VOC-containin g materials , i n grams , an d th e VO C conten ti n grams pe r liter , o f VOC-containin g materials ; an d (C ) Fo rvapo r suppresse d resins , a certificate from a resi n manufacturerfo reac h resi n type ; an d (D ) Fo rclosed-mol d and pultrusio n systems , th e weigh tlos s (i n percent) o f

polyeste r resi n material s fo r eac h application
. (2 ) Record s fo rcleanin g solvents subjectt o Rul e 117 1 • Solven tQeanin g Operation s shal

l b e maintaine d pursuantt o Rul e 109
. (3 ) An y perso n usin g a n emission s contro l syste m a s a mean s o f complyin g wit h thi s rul e shal l maintai n dail y record s o f

al l ke y system parameters, - includin g hour

s o f operation , temperatures , pressure s and flo w rates , tha t
are necessar

y t o ensur e control efficiency requirements
.

1162- 5P. 7

i e 116 2 (Cont ) (Amended May 13,1994 )

Ih e record s shal l als o contai n th e manufacturer' s name , typ e an d amoun t
o f corrosio n resistant , fire retardant, high strengt h material s an d ge l coat s used , which ar e temporaril y exemp tfrom proces s requirements unti l Jul y 1,1994
. (f ) ' Method s o f

Analysi s Th e VO C conten to f

eac h o f th e polyeste r resi n material s shal l b e determine d b y usin g USEP A Referenc e Metiio d 2 4 (Determinatio n o f Volatil e Matte r Content , Wate r Content , Density Volum e Solids , an d Weigh tSolid s o f Surface Coating , Cod e o f Federa l Regulation s Titl e 40 , Appendi x A , utilizin g Procedur e B o f AST M Metho d D2369) , o rth e SCAQM D Metho d 304
. Th e monome r conten t shal l b e determine d b y Metho d 312 , and weigh tlos s o f polyeste r resi n material s shal l b e determine d b y Metho d 309 ; an d th e exemp tcompound' s conten tshal l b e determine d b y Method s 30 2 an d 30 3 i n th e Sout h Coas tAi r Qualit

y Managemen tDistrict' s (SCAQMD ) Laborator y Method s o f

Analysi s fb r Enforcemen tSamples
. (g ) Tes tMethod s (1 ) Ih e efficiency o f

th e control devic e an d th e VO C conten tmeasure d an d calculate d a s carbon i n th e contro l devic e exhaus tgase s shal l b e determine d b y USEPA' s Tes tMetho d 18 , o r Ai r Resource s Boar d (ARB ) Metho d 42 2 fo rth e determinatio n o f emission s o f

Exemp tCompound s and USEPA' s Tes tMethod s 25 , 25A , o r SCAQMD' s Metho d 25. 1 (Determinatio n o f

Tota l daseou s Non-Methan e Organi c Emission s a s Carbon ) fo rth e determinatio n o f tota l organi c compoun d emissions
. Emission s determine d t o excee d an y limit s establishe d b y thi s rul e throug h tb e us e o f

an y of the
. above-reference d tes tmethod s shal l constitute a violatio n of

th e rule
. (2 ) Th e followin g classe s o f compounds : cyclic , branched , o r linear , completel y fluorinated alkanes ; cyclic , branched , or linear , completel y fluorinate d ethers wit

h n o unsaturations ; cyclic , branched , o r linear , completel y fluorinated tertiar y amine s wit

h n o unsaturations ; an

d sulfur
containe d perfluorocarbons wit h n o unsaturation s an

d wit h sulfu r bond s onl y t o carbo n an

d fluorine- , will b e analyze d as exemp tcompound s fo r

116 2 - 6* \ 

### Rul

e 116 2 (Cont ) (Amende d Ma y 13 ,



### 0 0 .complianc

e wit h subdivisio

n (e ) a tsuc h time manufacturer

s specif y whic h individua l compound

s ar e use d i n th e coatin

g formulation

s and
. identif y th e tes tmethods , which, prio r t o suc h analysis , hav

e been approve

d b y th e USEP A an d th e SCAQMD

, tha tca n b e use d tb quantif

y th e amount

s o f
eac h exemp tcompound
. Exemption

s (1 ) Until Jul

y 1 , 1994 , th e provision

s o f paragraph

s (c)(1 ) an

d (c)(2 ) an

d subdivisio n (d ) shall no

tappl y to : corrosio

n resistant , fire retardant

, an d hig h strengt h materials
. (2 ) Unti l Jul

y 1,1994,
- Th e provision

s o f (c)(1 ) shal

l no tappl y t o ge l coats .

1162- 7