Requested TIC Data 

Rick Wilburn to: tzick, Lambesis.Christopher, Ramaly.Todd 09/22/2010 09:51 AM 

Cc: "Gary Wood" 

"Rick Wilburn" <wilburnr@trimatrixlabs.com > 

<tzick@cticompanies.com>, <Lambesis.Christopher@epamail.epa.gov>, 

<Ramaly.Todd@epamail.epa.gov> 

'Gary Wood" <woodgl@trimatrixlabs.com > 

Please respond to <wilbumr@trimatrixlabs .com> 

Attached please find the requested TIC data. Hopefully this is what you are looking for. 

Rick 

Corporate / Laboratory 

5560 Corporate Exchange Court SE 

Grand Rapids, Michigan 49512 

wilburnr@trimatrixlabs.com 

Main:616-975-4500 

Direct:616-940-4246 

Fax:616-942-7463 
TIC Calculations 

Example 

Sample Peak Area Internal Standard Concentration x Final Extract Volume = ug/g = (mg / kg) 

Internal S tan Bard Peak Area Response Factor Initial Sample Volume 

Sample #1003151-03 

2212126 

 x 

 5 ug/mL 7.17 ug/mLx10mL =2.41ug /g =mg/kg 

1542096 1 29.8g 

Sample #1003151-04 

2341013 

 x 

5ug/mL 6.28 ug/mLx10 mL _2.08u /g=mg/kg 

1863146 1 30.2g 

Sample #1003151-05 

8455431 5ug/mL 16.0 ug/mLx10mL 

=5.35 ug/g =mg/kg 

2641963 x 1 = 29.9g 
File :C:\Documents and Settings\analystsv\Desktop\031710\1003151-0 

3.D 

Operator : JLB 

Instrument : 308 

Acquired : 17 Mar 2010 16:00 using AcqMethod 030810BNA.M 

Sample Name: 1003151-03 

Misc Info : 
File :C:\Documents and Settings\analystsv\Desktop\031710\1003151-0 

3.D 

Operator : JLB 

Instrument : 308 

Acquired : 17 Mar 2010 16:00 using AcqMethod 030810BNA.M 

Sample Name: 1003151-03 

Misc Info 
Tic: 1003151-03.D\data.ms 

1003151-03 

Peak # Ret Time Type width Area Start Time End Time 

1 7.919 rm 0.111 1542096 7.901 8.012 

2 8.117 rm 0.093 2212126 8.070 8.163 
File :C:\Documents and Settings\analystsv\Desktop\031710\1003151-0 

4.D 

Operator : JLB 

Instrument : 308 

Acquired : 17 Mar 2010 16:35 using AcqMethod 030810BNA.M 

Sample Name: 1003151-04 

Misc Info : 
File :C:\Documents and Settings\analystsv\Desktop\031710\1003151-0 

4.0 

Operator : JLB 

Instrument : 308 

Acquired : 17 Mar 2010 16:35 using AcqMethod 030810BNA.M 

Sample Name: 1003151-04 

Misc Info : 
TIC: 1003151-04.D\data.ms 

1003151-04 

Peak # Ret Time Type Width Area Start Time End Time 

1 7.936 rm 0.128 1863146 7.831 7.960 

2 8.134 rm 0.070 2341013 8.099 8.169 
File :C:\Documents and Settings\analystsv\Desktop\031710\1003151-0 

5.D 

operator : JLB 

Instrument : 308 

Acquired : 17 Mar 2010 17:10 using AcqMethod 030810BNA.M 

Sample Name: 1003151-05 

Misc Info : 
File :C:\Documents and Settings\analystsv\Desktop\031710\1003151-0 

5.D 

Operator : OMB 

Instrument : 308 

Acquired : 17 Mar 2010 17:10 using AcqMethod 030810BNA.M 

Sample Name: 1003151-05 

Misc Info : 
TIC: 1003151-05.D\data.ms 

1003151-05 

Peak # Ret Time Type Width Area Start Time End Time 

1 7.959 rm 0.198 2641963 7.854 8.053 

2 8.128 rm 0.192 8455431 8.088 8.280 
LSC Area Percent Report 

Data Path : C:\msdchem\l\DATA\031710\ 

Data File : 1003151-04.D 

Acq On : 17 Mar 2010 16:35 

Operator : JLB 

Sample : 1003151-04 

Misc : 

ALS Vial : 35 Sample Multiplier: 1 

Integration Parameters: lscint.p 

Integrator: RTE 

Smoothing : ON Filtering: 5 

Sampling : 1 Min Area: 0 % of largest Peak . 

Start Thrs: 0.001 Max Peaks: 100 

Stop Thrs : 0 Peak Location: TOP 

If leading or trailing edge < 100 prefer < Baseline drop else tangent > 

Peak separation: 0 

Method : C:\msdchem\1\METHODS\030910bna.M 

Title : 8270/625 BNA 

Signal : TIC: 1003151-04.D\data.ms 

peak R.T. first max last PK peak corr. corr. % of 

# min scan scan scan TY height area % max. total 

1 8.134' 899 906 913 rBV 703716 2495336 1.04% 1.029% 

2 8.204 915 918 926 rVB7 117537 234033 0.10% 0.096% 

3- 8.286. 926 932 934 rBV3 91586 130076 0.05% 0.054 16. - 

4 8.461 934 962 964 rBV 45991560 239685484 100.00% 98.821% 

Sum of corrected areas: 242544929 
File :C:\Documents and Settings\analystsv\Desktop\031710\1003151-0 

4.D 

Operator : JLB 

Instrument : 308 

Acquired : 17 Mar 2010 16:35 using AcqMethod 030810BNA.M 

Sample Name: 1003151-04 

Misc Info : 
File :C:\Documents and Settings\analystsv\Desktop\031710\1003151-0 

4.D 

Operator : JLB 

Instrument : 308 

Acquired : 17 Mar 2010 16:35 using AcqMethod 030810BNA.M 

Sample Name: 1003151-04 

Misc Info : 
File :C:\Documents and Settings\analystsv\Desktop\031710\1003151-0 

4.D 

Operator : JLB 

Instrument : 308 

Acquired : 17 Mar 2010 16:35 using AcqMethod 030810BNA.M 

Sample Name: 1003151-04 

Misc Info : 
File :C:\Documents and Settings\analystsv\Desktop\031710\1003151-0 

4.D 

Operator : JLB 

Instrument : 308 

Acquired : 17 Mar 2010 16:35 using AcqMethod 030810BNA.M 

Sample Name:. 1003151-04 

Misc Info : 
TIC: 1003151-04.D\data.ms 

1003151-04 

Peak # Ret Time Type width Area Start Time End Time 

1 7.936 rm 0.117 2103761 7.849 7.965 

2 8.134 rm 0.076 2667682 8.099 8.175 

3 8.204 rm 0.029 51180 8.187 8.216 

4 8.286 rm 0.029 69154 8.268 8.298 

5 8.461 rm 0.350 246735988 8.298 8.647 
LSC Area Percent Report 

Data Path : C:\msdchem\i\DATA\031710\ 

Data File : 1003151-06.D 

Acq On : 17 Mar 2010 17:45 

Operator : JLB 

Sample : 1003151-06 

Misc 

ALS Vial : 38 Sample Multiplier: 1 

Integration Parameters: lscint.p 

Integrator: RTE 

Smoothing : ON Filtering: 5 

Sampling : 1 Min Area: 0. % of largest Peak 

Start Thrs: 0.001 Max Peaks: 100 

Stop Thrs : 0 Peak Location: TOP 

If leading or trailing edge < 100 prefer < Baseline drop else tangent > 

Peak separation: 0 

Method : C:\msdchem\1\METHOD3\030910bna.M 

Title : 8270/625 BNA 

Signal : TIC: 1003151-06.D\data.ms 

peak R.T. first max last PK peak corr. corr. % of 

1 min scan scan scan TY height area % max. total 

1 8.158 900 910 925 rBV3 1425347 6853824 100.00% 88.614% 

2 8.257 925 927 939 rVB 253801 880649 12.85% 11.386% 

Sum of corrected areas: 7734473 
File :C:\Documents and Settings\analystsv\Desktop\031710\1003151-0 

6.D 

Operator : JLB 

Instrument : 308 

Acquired : 17 Mar 2010 17:45 using AcqMethod 030810BNA.M 

Sample Name: 1003151-06 

Misc Info : 
File :C:\Documents and Settings\analystsv\Desktop\031710\1003151-0 

6.D 

Operator : JLB 

Instrument : 308 

Acquired : 17 Mar 2010 17:45 using AcqMethod 030810BNA.M 

Sample Name: 1003151-06 

Misc Info : 
TIC: 1003151-06.D\data.ms 

1003151-06 

'eak # Ret Time Type Width Area Start Time End Time 

1 7.971 rm 0.210 3240592 7.890 8.099 

2 8.158 rm 0.099 5986821 8.128 8.228 

3 8.257 rm 0.029 57487 8.245 8.274