# c

0



# c ExhibitH Apil,20 1 3 Revisioa 0 

# RIS Fingerprint Laboratory Laboratory Worksheet

VES016199

# 0 Exhibit H: April, 2013 RmtiocO 

## A Description of RIS' Fingerprint Lab Results Log Plu'pose. The Fingerprint Lab Results Log serves as a hard 

### copy of data generated 

### by lhc 

### RJS on-site Profile Lab. 

### RJS completes fingerprint analysis on waste samples 

### acconling to the sampling plan incorporated in Ibis 

### Wastc Analysis Plan. 

### Description. The 

### RIS Fingerprint Lab 

### Results Log is generated 

### for each sample tested 

### and contains at 

### a minimum the 

### following information. • the 'Shipper 

### name or number; • WPS 

### ownber or profile designatOr; • the drum 

### number or other container identification number (with tankcx 

### or hopper 

### samples lhe hopper or tanker identification number sbould be used in lieu ofthe drum 

### number); and • a written description of lhe sample appearance. 

### Once the testing 

### has been completed, lhe analyst's initials and the 

### date 

### of testing are 

### recordod. The Fingerpr_int Lab Results Log 

### also records generic comments 

### or notes 

### and 

# O indicates neCessary ro,samples, which may be useful in process i ng lhe waste.



# c The Fingerprint Lab 

### Results Log may also include 

### results of supplemental analysis, specifically PCB analysis or metal analysis, as well as a list 

### of aoaly:tical 

### tcms routinely 

### performed. lo 

### addition, the logs 

### also contain the 

### test parameter 

### name, 

### rcsolts of the analytical test, 

### ooits of test 

### measure, and 

### acceptance aiteria 

### fo r each test. 

### A t a minimum, the 

### following parameters appear on the Results Log: 

### • pH • Flash Point • Oxidizer • Heat Value 

### • Sulfide 

### • Halogen Content • Cyanide • Viscosity • Specific Gravity 

### All pages of lhe Fingerprint 

### Lab Results Log are 

### bound and 

### numbered with daily run counts. It is the duty of the analyst 

### performing the 

### sample testing to fill 

### in the appropriate spaces on · the form. lo 

### cases where a particular test 

### is not**appl~cable,** 

### the analyst shall 

### write uNA " 

### into the associated 

### space. lo 

### cases where a certain tC3t 

### is 

### not required, 

### a single line 

### will be 

### drawn through 

### the 

### space to 

### indicale 

### that the test was not needed. The 

### sample logbooks are tiled in 

### ExhibitH ·I VES016200

# c

c the Operating Record once completed. At a 

### minimum, the aforementioned infonnation wiU be 

### included in 

### the Fingerprint Lab Results Log . Waste 

### Muaaemeat Penollllel Atreded. The Fingerprint Lab Results Log prepared by RIS laboratory personnel document the results of ftngerprint parameters for specific samples.**E~bitH-2** 

### VES016201

# 0 Exhibit I RJS Notification and Certification Form



# c April, 2013 Revision 0



### VES016202

# c

0

0 April. 2013 Rovisi011 0 

# Exhibit 1: A Description of the RIS Landban Notification Certification Form Purpoce: The purpose of Land 

### Ban Notification and Land Ban Certification is to identify hazardous wastes that are restricted from land 

### disposal, define those limited circumstances under which an otherwise prohibited waste may continue to be 

### land disposed, notify the 

### a p propriate parties about wastes that do not m eet the applicllble treatment standards of 40 CFR 268 and OAC 3745-270, and certify wastes that do meet the applicable treatment standards of40 CFR 268 and OAC 374 5-270. D

esc: riptiOD. . Each initial incoming waste shipment which is sub j ect to the Land Disposal Restrictions and has 

### been treated, exempted, meets the variance requirements, or otherwise meets · the appropriate treatment standaid or prohibition without treatment must be accompanied by a Land Ban Certification Form from the**~** 

### or generator, certifying 

### the waste meets the appropriate treatment standard, prohibition or variance and must include any applicable · analyti cal data or references . to such data or documentanon in accordance with 40 CFR 268 and Column C ofTable I ofOAC 3745-270-07. The initi al incoming waste shipment which is subject to the Land Disposal Restrictions and still require treatment must he accompanied by a Land 

### Ban Notification Form from the generator notifying the facility that the waste requires further treatment. Applicable items from Columns A ofTable 1 in OAC 3745-270-07 that, a t a minimum, must be included on the notification are: 

### • EPA Ha2llfdous Waste Identification Numbers • Manifest Document Number of the fitst shipment • Notification that the 

### waste is subject to land disposal restriction. • The constituents of concern for FOOI-F005, and F039, and underlying hazardous oonstituents in characteristic wastes, unless the waste will be 

### treated and tnonitored for aU constituents. If all constituents will be treated and mo nitored, there is no need to put 

### them all on the land 

### disposal restriction notice. • The notice must include the applicable wastewater/non-wastewater category and 

### subdi visions made .Y(ithin 

### a 

### waste <:9de based on waste-specific criteria. • Waste Analysis, when available . E

xhibit 1- I

VES016203

# 0

0



# c**Apri~** 2013 Rcvi>i<lo 0


### • Contaminated soil constituent sta tements found in OAC 3745-270-07, Table I, 

### Row 8, ifapplicable. Items 

### that, at a minimum, in<:luded on the certification are: • EPA Hazardous Waste ldenjification Number • Manifest Document Number of 

### the 

### first shipment • Statement the waste 

### is not prohibited 

### from land disposal. • Certification statement 

### Waste Management P ersonuel Affeeted. While the technical staff 

### maintains the notification and certification fonns for in-coming wastes, the teclmlcal staff manages the RIS · residuals program.

Exhibitl-2

VES016204

# Exhibit 

# J RIS Compatibility Test



# 0 Apri1,2013 RevisiollO

R011 lnc:!ncnOoa Scrvi=, lAc.



### V ES016205

# 0

0



# 0 April, 2013

. RevisiO<l 0 

# Exhibit J: 

# A Description of RIS' Compatibility Test Documentation Summary Purpose. 

### To describe the 

### procedure for determining the compatibility ofdifferent wastes by mixing small quantities, and 

### observin g and 

### reporting any reactions which may occur. Description . Compatibility tests are perfonned on blended**was~.** 

### Typically, the CSF Operator 

### refers to the Handling Instructions for speci fic handling 

### information, then decides which dock 

### tan.1c will be used 

### for processing the material. Once the dock 

### tank 

### is chosen, a sample from the dock tank is eXtracted. The samp le is 

### collected in a five-gallon pail 

### by bleeding off the pressure 

### of the dock tank. 

### The sample 

### is mixed with representative samples from the drums 

### to be processed and allowed to settle for a short period of time. If the material does not react, the 

### load is 

### processed. If a reaction occurs, 

### the 

### material 

### is**~ept** 

### for further evaluation and/or an alternatiye process method is 

### used. 

### Compatibility testing 

### on dock 

### process waste streams when doc!c blends 

### are created is documented on the Compatibility Analysis Report . Included on the 

### report is the following information: • RIS Form number • Samples to be 

### tested (C!Ns , tanker numbers and storage 

### tan.lc numberS) • Shipper Number and WPS Nwnber for each 

### drum 

### to be dock: 

### processed • Dat e of analysis and person comp leting fonn • The . average initial 

### temperature ofthe 

### wastes to be dock processed. • The final 

### "mix" temperaturc of t be 

### waste to be dock processed • Comments regarding visible reactions, temperature changes and 

### incompatibilities. • Conclusion: Compatible or Incompatible • (Docie Processing- for billing pwposes only on non·pumpable drums): 

### Shipper; WPS; Cotmt; 

### and Reason why Waste 

### Management P enonne l Affected. 

### · Receiving personnel perform compatibility testing and record this information in 

### the Operating Record. Exhibit I·

### I 

### VE$016206

# 0

0



# 0 ExhibitK 

# RIS Metals and PCB Logic Flow**Cha~** April, 2013 R.cvisionO

RoN Incineration**Service~.,** Inc.



### VES016207

# 0

0



# -o ExhibitK: RIS Metals and PCB Logic Flow Charts April. 2013 Revilica 0



### The following flow 

### charts represent general 

### pragramming logic associated with 

### RlS' meuls 

### and PCB sampling 

### and analysis program . The computer software is 

### proprielary, written and maintained by 

### RlS on its 

### operating system.**bi tK-1** 


### VES016208

# - .....**~TOUIG~** fhcciUttM&m OI**~·~if** In• 

# -**~-- ~,..,.,..,.1**  

### , 

# ..**,.,.~**.... l'fld>nt'll b" SrtUPII' 

# -·

, 

# .. QIMitlt ..... lf(Usl**~~­** at141tMkrorS.uPiJ 

# ...

# -. .. .

VES016209

# 0



# 0

0**~b:** >c 4400 ploos MM!un : )a 1 tOO ga1ons 11M < 4400 gallons ac u.cii Uf"'l: < 11 00 galons ..., 'WPS f'M.X > lwahokl Low: < 1 1 00gllonltnd WPS max < belholld



# •••**Docf'!~** 

## >--"" ;;:_

__ , -!f r • )OO. l



# ... 

# ..

'"'

• .......$



### VES016210

# 0



# 0

0 f1igh: >- 4400 gabs un: >= f 100 pions tnd <44t!O gabs ar kim: < 11 00 geiiOM and WPS tNX > Cnshold Low: < 1100 glllool endWPS lf'IIX < Uweshold

# ~~**---- ,,~** **-- ~:==~~**  

# - - 6 ..



# B· ... ... -.



# . .. 

# '25""""' ...

...

...

# _ ... .. . .



# . ...

VE$016211

# 0

'"



# 0

, 

# ..



# c

VES016212

# ExbibitL Visual Inspection Worksheet



# 0 Ap\1, 2013 RevisiouO



### VES016213

# 0

0

0 Exhibit L: A Description of The Visual Inspection Worksheet April, 2013 R<visionO



### Purpose. The pw-posc of the Visual Inspection Worksheet is to document the contents of inner containers associated with 

### a Lab Pack or Loose Pack container. This information is reviewed to 

### confum that waste stream(s) received at RIS were the same liS 

### described on ihe applicable WPS(s). Deseri ptioo. The Visual Inspection Work Sheet is used to 

### record the**~Sand** 

### CIN for each 

### Lab Pack and 

### Loose Paclc, and 

### it alloW$ the RIS employee who is performing a 

### visual inspection to document the inner contents of each container. A Visual Inspection Work Sheet includes, 

### but is not limited to, the 

### fullowing infurmation: Shipper, Customer-, WPS and CIN numbers;

- Outer 

### container sizes 

### and types; 

### Description of inner 

### container contents (based o!' the labels accompanying each 

### inncc container); and

- The inspector's initials and 

### visual inspection date. Waste Management**Penon~~el** 

### Affected. The RIS Visual Inspection Worksheet is to 

### be used by 

### trained RIS personnel who are unpacldng Lab Packs and 

### I 

### or loose packs, to 

### docwnent the 

### chemical contents of inner containers for confumation against the applicable WPS(s) . Completed Visual Inspection Worksheets and 

### WPSs are retained by 

### RIS in accordance with 

### app licable regulatory requirements.

Exhibit 

### L- I


### VE S0 1 62 14

# 0

0

0 Appendix C-1 Compatibility Guidelines .
PUBLIC INFORMATION VERSION

VES016215

# 0

0

0 ----- ... lao.
COMPATIBILITY GUIDELINES April.2013 

### R..mooo 

# Appendix C-1 Compatibility Guidelines

T ABLE OF CONTENTS 1.

0 INTRODVC'nOH . ........... .. .. .. . .. ......... : .... ..... ..... .. ................ .... ........ ,_,,, ............. .. .... ... . .... ...... . ... .... . . . . . .. CI·I 2 .0 CoMl'ATIBLrl'YOUIDEUNES FOR WASTB STO R EDINTAl<KS .... .... . .. ... ........... .............. .. ... .... .... ..**~** .. C I· 2 3.0 COMPATIIIU.ITY GUIDE LINES FOR WASTE STOIUlD ltiCOtiTAII'IERS .. . .......... ........................................ C l -4 J . J Co1114lnrrSiorag o Ana Cl-6 1 . 2 Bulle Storago Anas. Cl-8 J.J**Ozld~** StOf'GII• &.lldllrg. Cl-8 4.0 COMPATIBILITY QlJlDElll>,'ES FOil WASTE HANOI.EDATTIIE fNCD!EaATOI. --- ........................- Cl-10 4.1 /.lam Cltamb<r Sido D<x1r FeedMeclrmtlsm Cl-IO 4.2 Mmn ChamlHr lAna<! Dirw:t Fetd. Cl-13 0 Kiln A.ugu SJ.mlder . Cl- 13 S

. O STAtiOAJU>04'£RATI!IO PROC£OURE • W ASTB**COMPATII ~rry**  TEST .............. ....... ... .. ........... .. ........ CI - 14 

### L IST OF FIGURES AND T ABLES FIGURE 1.0 HAZA.lllOUS W AST1! CoNPATlBIUIY CHART --·· .. -·-·---- -·-·----- .. .. .............. - ...... . ..... ... . ...... Cl ·3 TAB LE 2 .0 PROCEDURES Ali'O PREICAunONS TO PJ\EVENT REAcnoi.'S OF b.'OOMI'A TIBLE W ASTI!S IN T ANXS ... ........... Cl·S I':IGUR£ 3.0 SSOREOAT10 tl Of' INOOMPATIBU! WASTE IN THB CSF ...... .......... ................ . ........... ..... _ . ..... :............ .......... CI- 8 F

JGUR£4.0 .

HAZA!UlOU S WA ml CO M P ATI BIUTY C HART· Sros Oooti. ..... ...... .. .. ....................................... .... ....... .... ... Cl-12



### Cl-i 

### V E S01 621 6**Apri~** 2013 RevislooO 

# C Compatibility Guidelines



# 0 1.0 

### lntroduttton Proper waste characterization is the most critica l q>mponent in detennining oompatibility between wastes streams managed at the Ross**lncin~tion** 

### Services, Inc. C'RIS") facility. RIS minimizes the possibility of WICOntrolled reactions due to waste incompatibility 

### through the proper i dentification of the chemical and physical properties of the wastes. Prior to storage or treatment of a waste, RIS evaluates the waste using at 

### a minimum: the WPS, 

### WCV, visual inspection and the fingerprint analysis . RIS then**iden~fies** any properties of the waste 

### which could potentially 

### initiate or support an Wldesired reaction With other waste ifmixed. The information 

### gleaned from 

### the RIS waste accq>tance system is 

### used to determine the 

### proper waste management 

### practices. From 

### this information RIS identifies if the waste must 

### be segregated from other waste in order to avoid unwanted reactions. 

### In 

### certain cases, waste compatibility testing is conducted to ident ify waste i ncompatibilities. Compati b ility testing i s performed 

### as appropriate and 

### is dependent upon 

### feed l ocation, potential for blending waste, storage 

### area of the waste 

### [tanks, Container Storage Facility ("CSF"), Bulk Storage Areas ("BSAs") 

### or 

### Oxidizer Storage Building (" OSB") ) , container s i ze and 

### type, and quantity of waste received. The Receiving Department is responsible for identifying potential incompatibilities 

### between incoming wastes and wastes already in storage 

### and for proposing the proper storage, processing, and management requirements for the waste . The compatibility 

### chart included in EPA 60012-80.076 "A Method for Determining the Compatibility of Hazardous Waster is consulted to determine the potential effects of mixing wastes with d ifferent reactivity groupings . 

### In 

### cases where potential incompatibility is indicated, the waste will 

### be separated from other incompatible materials. Figure 1.0 "Hazardous Waste Compatibility Chart" is a copy of the 

### referenced 

### chart. RIS is extremely conservat i ve during evaluation of incompatibilities. Consequently, compatibility evaluations may be com pleted at various points throughout the receiving process. Compabbility tests are done on conforming profiled materi als whicb have already been through 

### the RIS fingerprin t 

### process and evaluated by the laboratory . During the compatibility tests, 

### RIS 

### takes extreme care not to blend energetic wastes 

### and ·blends only 

### limited quantities (e.g. 

### 250-SOO ml) of 

### the 

### waste.

C I-1 

### VES016217

# c:

0 2.0 Com patibility Gllldellnes for Warle Stored 

### ia Tanks RIS recognizes the importance ofdetermining the compatibility ofthe**w~es** 

### with the fanlcs' 

### design as well as 

### with wastes 

### stored in tl_le 

### tanks. Therefore, 

### RIS begins 

### compatibility evaluation of incoming waste during the pn>acccptaocc process. Please refer to Scctioo C

### 2e (!Xa), "Pte-acceptance 

### ProoeduresH for a description of RIS' extensive waste d!aracteriution**pr~tices.** 

### The technical staff

### reviews all pertinent waste data collected from Waste Product Survey ("WPSj, Waste Component Verifieation ("WCV"), and literature . review. This information is used to determine tho compatibility of the wasto with the 

### tank's design before identifying 

# an appropriate tank 

### process code. RIS samples liquid streams in accordance with 

### this Waste Analysis Plan ("W 

### APj 

### visual inspection and fingeq>rint analysis during the receiving 

### process. The 

### visual inspection and 

### fingerprint data confirm the waste cbancteristics , Fingerprilit parameters indicate cyanide and sulfide mctivity to 

### further assist Receiving pecsonnel in compatibility assessment and waste classification. Special compatibility studies, the 5-gaUon bucket test (See Exhibit 1 

### of this W AP 

### for a description of this form) and laboratory procedure FP-009-001 (See 

### Appendix C-3, for this procedure), may be completed 

### at the request of the Receiving Department when additional inforroation may be warranted. A series of evaluations arc comploted at various points throughout the· receiving process and the "5 gallon bucket" test is typically one step 

### in the evaluation process. Tho laboratory compab"bility sn.dy may be completed in 

### lieu of the "5-gallon**buck~** 

### test 

### and is usually requested when large quantities of waste are received at 

### the facility . The laboratory compatibility test may also be requested when a waste mixtnre contains a component that by itself would not 

### be coruridered for tank farm storage but the mi11ture does not exhibit the incompatible characteristics ofthe component. The "5 gallon bucket" test is done on conforming profiled materials which have ' 

# . ' 

### already 

### been through the RIS fingerprint process 

### and evaluated by the laboratory. During the**~s-gallon"** 

### buclcct tes1, 

### RIS takes extreme care not to blend energetic wastes and blends only limited quantities (e.g. 

### 250-SOO m l) of the waste. 

### These compatibility studies look fur the evolution ofgas during blending; temperature change during blending; polymerization ofthe blended wastes; and spontaneous combustion. Again, liquids arc classified as to their compatibility with the 

### taDks used . to 

### store the waste and t he tank process codes arc verified. Finally, Production personnel authorize waste transfer to 

### tank storage. All compatibility test resu lts will be 

### documented in the Operating Record.

C1·2 

### VES016218

## Figure 1.0 

# Hazardous Waste Compatibility Chart 

# 0



# 0 Cl -3 April, 2013 RcvisionO



### VES016219

# = <'! <'! U) 

# .. = 1/) 

### w 

## >

# • • • April,20l3 RevisioDO 

### When reactive waste 

### is received at the facility, it will be 

### fed directly to the incinerator. Although RlS makes every attempt to isolate customers' Y(as te, RJS 

## can blend compatible wastes within 

### a single tank. RJS will only blend wastes 

### wtder appropriate conditions. Consequently, R IS may 

### nm a compatibility test on 

### a waste stream 

### to 

### assure that i t docs not polymerize with waste previously found in the 

### tank. Sh ould the · need arise to store a waste that is 

### incompatible with the historical contents of a tank, 

### RlS 

### will empty the 

## . . 

### . 

### tank**~d** 

### thoroughly rinse and visually 

### inspect the 

### tank prior to introduci ng waste. RJS utilizes 

### the 

### Tanlc Farm Log 

### to 

### record potential incompatibilities . Compatibility tests 

### are performed on all dock 

### system 

### !lrum loads . Typically, the dock laborer refers to the handling instructions for specific 

### handling information, 

### then decides which dock 

### tank wiU · be 

### used for processing the material. Once the 

### tank is chosen, 

### a sample from the dock 

### tank is 

### extracted. The-sample 

### is collected in a 

### five-gallon pail from the tank. 

### The sample 

### Is mixed with representative samples from the 

### drums or bulk tanker shipment · and 

### allo wed to 

### settle for 

### a sbort period of time. 

### Ifthe material does not react, 

### the load is 

### processed. If 

### a reaction 

### occurs, the 1114lerial is 

## kept for 

### further evaluaiion· and/or an a

lternative process 

### method is 

### used. The Standard 

### Operating 

### Procedure for 

### the waste filigerprint compatibility test 

### is included_ in Appendix 

### C-3 as 

### FP-009..00 I, and 

### a description ofthe 

### "5 gallon bucket" 

### test is in Exhibit J . Table 

### 2 .0 entitled 

### "Procedures and Precautions to Prevent React ions of Incompatible Wastes in Tanks'' lists specific procedures and precautions 

### taken by RIS to prevent reactions which I)**general~** 

### extreme 

### heat or violent reactions; 2) 

### produce 

### uncontrolled toxic mists in sufficient quantities to 

### threaten human health and the environment; 3) 

### produce uncontrolled fllUliJIIable fumes in sufficient quantities to pose a risk of 

### fire or explosion; 4) damage the structural integrity of the device or 

### facility; 5) 

### tl)rough like 

### means, threaten human health or 

### the environmenl 3.0 Compatibility Guld eHnes for Waste Stored lD Coatalners 3.1 

### Container Storage Facility · RIS 

### does not commingle incompatible wastes**~** 

### the container storage 

### areas. RIS 

### uses WPS data to set storage classifications . 

### After fingerprint data confirms conformity with WPS parameters and incompatibility tests are conducted 

### as necessary, the Receiving 

### · Department assigns tbe 

### appropriate storage location 

### for the 

### waste .

Cl-4
V ES01 6221

# • • • Table 2.0 Ajlnl, 2013 RevislooO



# Procedures and Precautions to Prevent Reactions of Incompatible Wastes in 

# Tanks

• Providing procedural 

### and safety 

### training to 

### Operators handling the 

### materials. • V isually inspecting the tanks, valves, hoses, piping, and containmmt basins prior to any transfer operations. 

### • Exerc ising extreme care during filling 

### operations. • Eosuring t hat all couplings are secure. • Ensuring 

### tl\at • no smoking" signs are posted and that ignition sources are confined to des i gnated area. 

### • Nitrogen blanketing all tank s that store 

### volatile materials. • Conductin g waste characterization analysis, 

### See Section C-2e (l)(a),**Pre** 

### acceptance P rocedures n for details. · • Conducting 

### fingerprint analysis 

### to verify waste characteriza tions .

Cl·S · 

### VES016222

# •

•

•



# • April, 2013 Revisioa 0 

### Bays are areas withiil 

### the CSF where materials are stored without the use of a racking system, whereas racking bays are areas of the CSF where materials are stored using 

### a fivelevel racking system. 

### Incompatible wastes are segregated in the CSF by p l acement in designated racking bays.**~** 

### SeCtion D 

### for additional CSF storage information. 

### 1'he CSF has 

### a 6-inch·high cwb 

### that separates 

### the 18 

### storage areas, 

### (bays and raclcing bays) with separate 

### sump areas. 

### This. will 

### allow . for the segregation of incompatible wastes should the 

### need arise. Bar code labels on all containers include · a hazard class code, which determines where the material is to 

### be stored. The racks in 

### the racking bays are equipped with signs designating the type ofwaste 

### that 

### can be stored in that particular

_ row. · Each waste category 

### is stored in these designated areas . For 

### example, corrosives (acids/bases) are i sola"ted from 

### each other and from the bay where reactive**sul~des** 

### and 

### cyanides or high halogens are 

### stored. Waler 

### reactives are 

### dedicated to 

### a single racking bay. RlS will 

### store other compatible wastes in the bays or aisles designl!fed 

### for**~** 

### waste type. For example, combustibles will 

### be stored in the unused 

### portions of the high halogen raclcing bay or the unused portions ofthe 

### other bays. RlS 

### may use the 

### available storage space in 

### another compatible bay or racking bay if the capacity of the 

### bay or racking bay would 

### be exceeded by storing 

### additional 

### waste. For example, if a large**qu~tity** 

### of high halogen waste is 

### received, RIS may designate additional racking bays as high halogen storage racking bays. Although RIS may alter 

### the arrangement, RlS will comply with the overall principles and concepts 

### pertaining to 

### segregation of incompatibles. Additionally, RIS will store non-hazardous waste and 

### malerials 

### for RIS 

### use fn accordance 

### with the information contained in Appendix 2, Compatibility Guidelines, of this 

### · W AP. 

### Further infoonation**reg~ng** 

### storage of containers 

### can be referenced in Section 

### D (Process 

### Information) ·Section 0-Ja (2) • 

### Detailed Description of the Container Storage Facility ofRIS State Part B Application. A -

key indicating waste segregation 

### is included 

### as Figure 3.0 entitled "Segregation of Incompatibl e Waste in the CSF. " 

### This key indicates lhe racking 

### bay by letter and 

### the waste type 

### (hazard 

### class) which can 

### be stored in 

### that racking bay. These procedures pi"o':ide 

### assura:nce that incompatible waste is 

### j:lroperly**~egi-cgated.** 

### Operators are trained in the CSF procedures and are 

### knowl edgeable in the following**requirem~ts** 

### rcguding 

### waste segregation. • Corrosives cannot 

### be stored with or adjacent to sulfidelcyanido bearing wastes or high 

### halogens.

Cl-6 V ES0 1 6 223

# • • • Apnl, 2013**Rovi~O!IO** 

### • Combustibles/Flammables can be 

### stored in 

# any open space except with, or · adjacent to oxidizers (most materials are 

### combustible even though 

### they are 

### classified 

# as something else.) . • Oxidizers must always remain segregated from other wastes. • Water reactive wastes are 

### stored in a segrega!ed bay or racking bay. Additional 

### measures to 

### prevent water 

### from contacting this waste include installation ofdrip pans or barriers. Equivalent measUres such as removing water from containment swnps may 

### also be 

### employed . 3.2 

### Bulk 

### Storage Areas 

### RIS 

### only stores 

### hazardous waste without free liquids in the BSAs. RIS 

### only accepts 

### hazardous waste in containers which meet DOT 

### requirements. RIS 

### only stores hazardous waste in the BSAs in containers 

### made o f, or lined with, materials which will not read 

### with, and are 

### otherwise compatible with, the hazardous waste to be 

### stored. 

### This ensures the 

### ability of the 

### container to contain the waste is not impaired. 

### As part of 

### RIS' waste segregation policy, incompatible wastes and materials will n ot 

### be placed in the same containers, 

### and 

## haZacdous waste 

### shall 

### not be 

### placed in 

### an unwashed container that previously held 

### an inoompatible waste or material. In 

### addition, i f incompatible wastes 

### are stored in the BSAs, RIS will keep them physically separated 

### fro'm other wastes and 

### materials by means ofportable berms, 

### bags of compatible absorbent materials, 

### drip 

### pans, bins or other 

### devices . Operators are 

### trained in 

### RIS storage procedures 

### and are knowledgeab )e 

### in the following waste segregation 

### requirements: • Corrosive wastes cannot be 

### stored with or 

### adjacent to sulfide/cyanide 

### bearing wastes or. high 

### halogens: · • Combustibles containing water can 

### not be 

### stored 

### w ith water reactivcs. • Combustible and flammable waste can 

### be 

### stored in 'any open space 

### except with, or 

### adjacent to , oxidizers. RIS does not store oxidizers or water reactive wastes in the 

### BSAs. In 

### addition to RIS procedures and 

### US-DOT packaging requirements, RIS will assure compatibility of wastes 'with containers through 

### daily inspections ofthe 

### BSAs .

Cl-7
V E S 0 16224

# •

Figure 3 . 0 

# Segregation of Incompatible Waste in the CSF 

# • • Cl-8 Aj>ril.20!3 ReviJiCICO



### VES016225

# • • • KEY Segregation oflncompatible Wastes 

# in CSF Row/Bay Waste Type A · Caustic Corrosives 

## B Sulfides and Cyanides C* · <;:ombustibl es/Flammables D High 

## Halogens E 

## Water Reactives F* Combusboles/Flammables G 

## Acidic Corrosives · H 

## Caustic Corrosives R** Various Waste Types Apri1 , 20 13 R&visioo o



### •c ombustible/Flammable wastes may be stored with wastes in 

### any other row except with .Oxidizers in Row R. • • say 

### R 

## is utilized for various waste types . Bay 

### R 

## can be used 

### to store 

### Oxidizers, however,

Oxidizers are typicall y stored in the OSB . Plesse note that RIS 

### reserves the right to alter 

### or expand the designated 

### areas for incompatibles 

### based on 

### our inventory needs . For 

### example, ifRls· were storing waste, which 

### exceeds the 

### capacity ofits designated row, we would find it necessary to use the 

### avai lable 

### storage space in 

### anoth« compatible row .

C\·9 

### VES016226

# • 3.3 Apri1,20 13 RevisioaO 

### PUBLIC INFORMATION VERSION 

### Confidendallilformadon hilS been removed from this 

### p4ge. Q)(i\ii= 

### Storage Building ("OSB'') 

# . . Oxidizer waste stored in the OSB will be limited to 

### 1\IFP A Class 

### I or Class 2 . oxidizas. Orpnic peroxide waste stored 

### in the 

### OSB will be 

## liniited to 

### NFPA Class 4 and 

### Class 5 orgaqic peroxides. For compatibility 

### purposes, RIS considers oxidizers and 

### organic peroxides of the l ower hazard 

### classes to be 

### compatible. 

### Only containers made of or lined with materials which will not react with, and are otherwise compatible with, the hazardous waste to 

### be . stored, will 

### be used 

### so that the 

### ability 

### ofthe 

### container to contain the wasto is 

### not impaired. Othel' 

### wastes and 

### materials which 

### ano incompatible with oxidizen and 

### orgariic peroxides will 

### noi 

### be 

### stored in the 

### 'OSB . In 

### addition,**oxidize~'** 

### and organic peroxide wastes 

### • ""'hich are 

### incompatible with wood will 

### not 

### be**sto~** 

### on wooc!en pallets 

### within the OSB . 

# • • Ovenlll, 

### oxidizer and 

### orpnic 

### peroxide wastes will be 

### physically separated from 

### incompatible materials and 

### stored in accordance with 

## RIS handling insttuctions • 4.0 Compatibility Guldellus for Waste Bandied at tho 

### Incinerat or RIS' 

### incinerator is uniquely 

### designed to allow, in mo st cases, 

### the introduction of waste directly 

### to the combustion cbamber. Assuring 

### com patibility 

### of waste at the 

### incinerator is necessary o nly 

### at feed locations 

### where waste can potentially 

### commingle prior to 

### complet e combustion. Procedures for assuring compatibility of wastes ·at these feed 

### locations are discussed in the 

### following sections . 

### Therefuro, c;ompatibility o f wastes 

### need not be addressed 

### for these 

### feed systems. 

### 4 . 1 Main Chamber Side Door Feed Mechulsm 

### The dltlerent!ation between each waste 

### stream is 

### based on heating value, pwnpability, reactivity , 

### toxicity, halogen content, compatibility 

### with inventoty , and quantity received.

C l -IO 

### VES016227

# • • • April, 201) Revision 0 

### PUBLIC INFORMATION VERSION 

### CohjidentUU informa/Jqn luis 

### been renwved from this page •



### · RIS assesses the reactivity group number ("RGN") data 

### for each WPS and compares them against a compatibility matrix.. 

### Ally potential incompatibilities are flagged so the Receiving staff can segregate 

### the WPSs 

### appropriately. Compatibility of materials will · be 

### established by use 

### of storage classifications (e.g., combustibles, flammables, etc.), past experieQ!:C with the waste. streams, 

### and the use ofa revised version of the hllzardous waste compatibility chart (EPA-600- 2-80-076) as provided in Figure 4.0 entitled "Hazardous Waste Compaboility Chart, 

### Side Door."

Based 

### on the 

### revised compatibility chart, oo 

### wastes will be 

### set up 

### for processing at 

### the same time which may result 

### in an incompatibility conseq_uence of explosion, violent polymerization, or an unknown but 

### potentially hazardous reaction.



### Emeq:ency siiWitions include bulging drums, fuming or spraying dnuns, burning drums and drums 

### which are beginning to 

### react dangerously or generate heat.



### Cl-11 VES016228

# • • • Figure4.0 Aprii, 2013 Revili.ott. 0



# Hazardous Waste Compatibility Chart- Side Door

Cl-12 VES016229

# : 

# I i 

# I I

# I 

# I ' 0 

# .., N IQ 

# .... 0 V) 

### w 

## >

# • • • April,2013 RevisionO 

### PUBLIC INF.ORMA TION VERS ION 

### Conjidentl41 lnfontumon has bun 

### rewuwed from this

### page . In the event of an emergency , 

### RIS will notifY the O.hio 

### EPA by certifying !hat the container of 

### such wasteS 

### poses inordinate risk to 

## ' lwmaD health 

### or the environment by not 

### processing the waste immediately. 

### RIS shall 

### submit to 

### Ohio 

### EPA a written certification signed by a responsible corporate official. This certification 

### shall include: (I) . the 

### container identification number; 

### (2) in the 

### case 

### where container deterioration requires the 

### waste to be 

### processed for safety reasons, a det8lled ' physical description of the container; (3) 

### the WPS number; (4) 

### a detailed statement descn'bing the hazard posed by not- fuclnerating the waste; and (S) 

### a certification**~** 

### handling and 

### incineration of the container and its contents can, and will, be done safely 

### and 

### iri accordance with all 

### relevant laws and pennits . U Main Cham ber 

### Laaee Direct Feed. Based on · the 

### WPS and previous waste 

### stream laiowledge, RIS will assure compatt'bility betweeo waste ·material being fed to 

### the Side Door and 

### waste material being fed 

### from the 

### direct 

### feed containing any of the following elemental met-als at concentrations 

### greater than I 

### ()()().ppm. : Aluminum, 

### Uthium, Magnesium, or Thallium.

4.3 Klla 

### Aqer Shredder. Based on the WPS and previous v,:aste 

### stream knowledge, RIS will 

### assure compatibility of waste streams 

### fed to the a uger shredder. Waste 

### streams to be fed to the 

### aul!er shredder must meet the following guidelines 

### so that these streams 

### can be 

### freely 

### mixed in 

### tlic auger shredder in the proper solids to 

### · liquids ratio:

Cl·l3 

### VES016231

# • • • April, 20 13 RMJ;on O



### . PUBLIC INFORMATION VERSION Co ttjld 6ntilll il!fotMatiollltas luen rem011ed fro m th is p4ge.



### 5.0 Standard ope rating Procedure - Waste CompatibllityTest The standard**operatin~** 

### procedure for determining waste compatibility is described 

### in 

### Eitbibit J. 

### The purpose of the test is to determine the compatibility o f different wastes by mixing 

### small quantities and 

### reporting any reactions, which may occur. The test i.s applicable · 

### to liquid wastes 

### of various WPSs, which are 

### to be 

### mixed and processed 

### on a larger s cale at 

### R!S . Rec:civing may 

### request additio1181 oompatibil ity tests. All compatibility test results will

·be 

### doc:umen ted in 

### the 

### Operating Rooonl.

C l- 14 

### VES0 1 6232

# •
• 

# •

. • 

### . 

# Appendix C-2 Standard Operating Procedures (SOPs) for Fingerprint Analysis

PUBUC INFORMA TION VERSION Revision 0**Apri~** 2013

a.. tMbterad•a aer.s.... 

## '*·

VES016233

# •
•
•

. '



### . .. 

# e 

# Appendix C-2 Standard Operating Procedures For**aooaJac~Aetalloa** eem-. .. . . 

# Fingerprint Analysis

TABLE OF CONT ENTS 

### Prosecfure N9mber Procedure T l de FP .OO 1 .003 FP-002.004 FP -003-004 FP -004.004

. FP.OOS.Q04 FP.Q06.()()3 FP .QQ7.00 S FP-00 8.004 ,FP.()09.00I

. FP-0 12.003 FP.Q20.007 BTU Analysis 

### Determination o( Fiasbpoint Sulfide Spot T est pH Determination Determination of R elative Density Cyanide Spot T est Total Chlorine 

### Concentration 

### Viscosity**~tion** Waste Compatibility Test 

### Ash Conteot TEl Compositlng Pro<:edure



### G3-i C3- 1 

### C3-S . C3-8 C3- 12 C3 - 14 C3-16 C3-19. C3-23 C3 -26 C3-29 C3 -3 1 · RevisionO April, 20 1 3



# I

V ES016234

# • •

I . 

# ,. ! 

# I 

# •

" 

# .. .. .. ' RevitionO April, 2013 

# I Rot• lnclt!entelon Services, Inc. STANDARD OPERATING PROCEDURE

Revised:

### 2~ SOP No.: FP-00 1 ..03 Initial Date: 7/24/90 Prepared by: Date: 12..()6.00 QA ApprovaJ: 1.0 . PURPOSE This procedure is to deocrlbc the 

### moins by which the beat contect ofa sample Is decmniDOd. 2.0 APPliCATION
3.0

4. 0 5 . 0 This**~applies** to any liquid or solid sample, which may be combusted in an oxyaaa bomb . This procedure Is based primaril y on tho Parr Oxygen Bomb User Manual. REFERENCES Parr Oxygen Bomb User Manual "Standard Test Method f or Heat o f Combustion ofUquid Hydrocarbon Fuels by Bomb Calorimele<", American Standard Testin& Methods, Medlod 0240 ·92 . ASSOCIATED SOPs REAGENI'S S.l 2,2,4-Trimotbylpeotane (booctaao) ·CommerciAlly pW'chased, reageot grade or equivilcat 5 . 2 8enzoic acid· Conune:cwty pun::hased, = s ent grade or**equi~~akm** 5.3 Sodium oarllooate solutioo, SO giL • Dissolve 50.0 g ofsodium earbonate into approXimately 800 mL of deionlz.ed water . · Dilut e to llitec in a volumetric llask. Store aolUiion in a plastic bottle a1 room temperature . Prepa.. 

# ••'"Y 6 montbs or sooner. · 6.0 EQUIPMENI' 6.1 PatT 1261 lsoperibol Calorimeter ' or 

# .q.;\'alenl 6.2 Combustion caps>des 6.3 Oxyaen bomb 6. 4 6.5 Topload<r balance 6.6 Graduate eyliadm: 10 

### mt · 

### C3 · 1 -: 

## ... . . ' 

## . 

## '

VE$016235• 7 . 0 

# • • PROCED URE SOP No .: FP.OOI -03 Initial Dale: 7124/90 Rcvl$ion0 April, 2013**~:** For safoty p"'1JJS4S, nrw sample s hould not be exposed to the atmosp/rer4unless It I$ contained In a wnJi/aud Mod . Steps 7.2**thro~~p** and Including stop 7 J sbauld becondttC tt d In a vtntllated hODd. 7.1 Fm a wash bottle With sodium caroonate solution. Wet the sidesof lbeoxygen bomb uotillbere is enough solution to ooVCT duo bottom ofthe bomb . 1.2 Place a combustion capsule on lbe balance in a hood aod rue it. Place a portion of**sample~** O.S and 0. 8 g) iniO tho 

### copsi.J. aad 

### reooid tho.weight to the neamtO.O I -g. Sim:e vorylngmatricesCOII!bust differently, below are sample weight guldelillcs which !lbould be followed when weighing samples: Matril Sarqple WeigiBJ (c) Jso..?S''!C Wmbt 

### <a> Waste liquid 0.60 ·0.80 0.10-0.30 Wao1e dil1 or 

## son 0. 30 -O.SO 0 .20-0.40 Cloth or paper 0. 20-0 .40 0 .00-0.10 Plastic or**pol~** 0 .20-0 .40 0 .00. 0.20 Powder 0.20-0 .30 0.00. 0 . 10 Metal' 0.20 -O.SO 0 . 00. 0.10 • Use poredaln capsule Notes: (/) Th• combined ..,.,;g ht of the sample and iw-ocUm• must never itx«ed I :0/Jg . (2) 

### if a miJ.fire continually results using the prescribed weight gujde/ines, decre4Se tlu sample weight and proportionallyIncrease the lsq.ocums weight 7.3 Place lbe capsule wo the electrode loop lwlgiDg from . lbe bomb lOp. 7.4 Lock a piece offuse wire iniO the eleccrode on both sides. Adjust the fuse wire 10 ..,.ure that it extends into the capsule making contact with tho sample. · · 7.5 Place the bomb top into the body oflbe bomb 

### aDd screw the bomb capon securely. Note: For aceurau anai)'S.. , mal.:#sure t hat all bomb pariS (bquom, top, and cop) are from the same bomb . 7.6 Place the 

## oXygea COIUlOCtion oniO the inlet**val~** ofthe bomb and press ''0, Fill" on the calorimet er. 7.7 Check the water l e..t oflbe calorimeter bucket. Fill the bucket with deionized water to the appropriate l evel. 7.8 After the bomb bas tilled with oxygen (indicat ed by a popping sound and 

## endina ofthe "0, 

## F u

r• light on the calodmcler). use the bomb hanger 10 lower the bomb into the calorimeter boeket. Check to 'make sure that the bomb is in the celtter oflhe calorimeter bucket • 

## . (. 

## .. ; • , 

## . 7 . 9 .**CoM~t di~e~**  

### kads iniO 

### ibe top ofthe calorhnettr and_ ciosc the calorimeti:r lid . C3-2 

## · .
VES016236

# •
• 

# •

j • • "'; · •\ 

# . ·,**~.** 

## · . . SOl' No .: FP-00 1.03

. blilial 0&1« 7124190 Rev!donO April , 2013

. 7.10 . !'toss "SSart", - ... tee tbeliomb number, sample ideoli6eatloa DUIIlber, sample weighl. and iso-occaoe weight. Tbe calorimeter will fire tho sample automatically . Note: Do Mt suurdnut k> or in front of the CIJJorlmeler when the 

### flrU!t alarm sounds (rapid buplng). Injury could result iflhefirbtg of the stJmp/e is not co1JU11Md wltllin tire bomb. 7 .1 I When the test is**~ete ,**  the calorimettt wiU automatically calculate and print the RSUIL If there is a need to caleulate the Btullb 

### ......,.ny, use tbe following equation: · For samples 

### !!llllaJd i.so«WWe 

### ll!lded: !(W)CTIJ gsample X For S&IUP!es 

### mill iso-octane added:
wbczc: B1UIIb= ! «Wl CTI- Ell- !$! 8 SIIIJplC W = EE vahle (bomb coOstanl) £1 • 10,682 callg • giso-octane added · (calories pt<><luced by Jso.octane) 1.8

X 1.8

Note: . When new eqrdpment, other tlu>n described In this**proce~** Is wed, followfii"O"dures for inslrum<nt operation 

## es described In owner's manual.
· 7 . 12 Di.screpaoo y DeteriUination 7. 12.1 Tbe actual reault ltiWt be wiilrin ± 20% ofthe profiled range. If il is OUISide oftbese l imits, 

### a resJII!P(e most be requested from the doc:k 7.12.2 Uponreinalysis,lfthe second resolt &Us withlu ± 20%ofthe pro6led ""'ge and w ilhin 

### ± 4000 Bru/lb ofthe oriaJnal RSU!t, the sample may be accepled based on the second result. Ifthe reanalysis is different &om the orieinal resul1 by more than ± 4000 Btnllb or olllSide ± 20"/o of the profiled range, then · • third analysis must be perfonned. Ifboth resultsare0Ul$ide ofthe± 20%ofthe profiled range, the sample must be reported as 

### bein& disc10pant to Cus<omer Service. 8 .0 QUALITY CONTROL 8.1 Bomb Ca libration Calibrate 

### eaeh bomb in use on a weekly bisis and encer the EE values into the memory ofeach calorimeter . Doeument lhe EE values of each bomb calibrated into the 

## 9C logbook. 'Not<: The bomb bottcmt, top, alldlid are $1a11d4rdized <U one omit. Piec<s muJI not be Utterclumged. 

### C3-3 

# ' - :· . 

## . 

# . . 

# . : :**~;~ .**  

### - ,: ; ;

;.: 

## -. - . 

### V ES01 6 2 37

# •

••


# •

1 - .• 

## . ·: sOP 

## No.: FP-00 1·03 . Initial Date: 7/24190 Revision 0 April, 201 3

8 .2 LCS l fneed

_ &ri.ses wbae die EE value must be calculated maaually, UJO tbo**o;<~uatioo** below .



## w a (H}JM} T W • EE value (bomb coostanl) H • Heat ofcombustion ofbenzoic acid io 

### c8Vg T- Clwlse of**~emp<ntnre** M • Wei;ht ofben:zolc acid 8.2.1 Analyzeab=ic acid lablelspiked withO . IO-g lso-ocWieoa al per20-oample basis, or ata minimum of once daily per calorimeter. 8 .2 .2 Calculate the percent recovery by dividing tbo actual Btullb by tbe tbooretical Btu/lb. Multiply Ibis DDtllbe< by 100. ' 8,2.3 The percent recovery Jn\!$1 be :1: I0% oftbe tbooretical Vl! l ue . If tbe result is outside this**ljmi~** cbeck for i.aotrumenl maltimction and recalibrato tbe bomb, if neccssaiy . 8 . 2.4 Sol veats ofknown BTU value can be substituted for b=ic acid. Recovery limits must meet the same criceria.

C3-4-


### VES0162 38

# • I . ! 

# • r 

# l ''**:. .**  

### •· · I R.evisioa 0 April, 2013
STAN DARD OPI!RAl'JNG PROCEDURE SOP No . : FP-002-04 Initial Date: 71 1 9/90 Revised: 12-06-00 Date: 12-06-00 1.0 PURPOSE This prooedure is wed to describe a metbod for de<erminin& the flasl\>Oint ofa sample. 2.0 APPUCATION 3.0 . This method is applicable for lilY &ee-llowin& liquid sample. REFERENCES QAApproval:

"Peosky-Martens Closed-Cup. Metbod for 

### Dcterminina**Igoilab~ity",** Test Methods fur Evalualing Solid Waste (SW • 846), Method 1010, Sqxember 1 986 Pmslcy-Marteas Flash Tesler Operator's Manual Setallas h Closed Tester Melhod, Test Methods for EvaluatiAa Solid**Wa.~e** (SW-846 ) , Method 1020A Setaflash Opeo Cup Metbod, ASTM 04982 4.0 ASSOCIATED SO Ps Nooe S.O REAGENrS Ollorobenune, .... , .... srade or equival ect 6.0 EQUIPMENT Penolcy-Martens Flssh TeStOt**Thenno~.** O"F- 20S• f , I 

### c1ear<e**~ions** 7.0 PROCEDURE 7 . 1 Prior 10 dispeosillg a sample into the flash tester cup, tum the exhaust hood.on. 7.2 Fill the flash ttst<r cup to the fill mad< with sample. The fill mark is lo.eated Inside the flash tetter 

### C...,. 7.3 Place tbo . Ouh ICSICr cup into the heating manl1e. 7.4 Place tbo stirrtr and ignition apporal\18 on lOp oflhe flash tescec cup an d secure il to. !he appanuus . 

### : C3-S



## ·. VES016239

# •

• SOP No" FP-002-04 loilial O.te: ,;1900 RevisionO April, 2013 7.S . · Place lbe 1beu11ometor into 

### lbe hole provided in the t op of the 

# tester appvatus so that the thermometer bulb is 

## contactiils tho 3&Dlpte : · · 7.6 Wilb alit match in band; tum on the gas Bow slowly. Upon ignition, adjust the gas ftow to allow for a small but steady flame. 7.7 Tum the top li:nob so lhattbeshutteropensand the flame is lowered into tho vapor-ofthecup in 0.5 secoods. Leave in !his lowered position for one second. · · 7.8 If the**somp~** vapor lpltes without beating (genmlly a Oasb ofblue flsine results).reoord tho lemper&ture and DOlO that lpllion OOCUJ:r<d at the loweot ceotsblc**~by** writing LOW next to tbe tcmpetatute value in tho mulls book. lftbe sample wpor does not iiiJ1ite, proceed to 7 .9 . 7.9 Begin beating the sample with constant Slining. 7.10 Discontinue stitring aod apply the ignilion flame as described in 7.7 &1 intervals ofS'F untll . allash ooeurs or the**to~** reaches 200'F.

7.11 7 . 12 NOTES: I. C<:rtain samples with rolativcly low boiling poials lll4Y cause tho tlame on tbe tla!hpoinl apparaws to t><: extinsnisbed due to the release ofbuilt up wporpressuro. lnsamples sw:h as these, the temperature at which dle tlamc was Jirstextinguished sboold be noted and tho test continued as long as continued 

### bcatin3 does not cause the sample to boil over and out o f the appantlUS. lfboil-over appears imminent, cli!continue the analysi& . If lbe test· is discootinued witboula tlash ooeurrillg before 200 degrees Fahrenheit, notify RlS COSiOmer Seriioe. 2. IMPORTANT SAFETY NO TICES . While performing 1be ftasbpoint aoelysis, the s.imple should be 

### 'watched continually until a flash ooeurs orunu1200 

### decrees Fabrenbeit i& achieved. After a tlasb OCCUf6 or the 200-degree endpoint is rtaebed, dispose oftbe m<idual sample immediately in tho lab hazardous waste bucket. Failnre to monitor tbe sample oontinually or di&pose oftbe samplo promptly following the analysi& may cause tbe samplo to absorb additional beat from tbe beating mantle and spontancclUOiy !pile cau.ting • fire . . Record lbe loweat temperature at which the application oftbe flatne ignited tho. sample vapors. lfno Oash OOCUJ:r<d before the tompersWre reaehed 200'F, ICCord tho reaullas >200'F. A**~toady** yellowish ftame usuall y indicates an exceeded ftas b point. Sample Accepaoee To be doomed acceptable, samples must tlash 

### .Vthin lbe profiled Jallge. Below are three ranges that profiled tlasbPQinls will fall. .

. Range. .,

0 · 140 140 . 200 >200 If

one of.tbese oooditions i& not**me~** proceed to 7.13. 7 . 13 Di&creponcylletennination 7 . 13 . I Request a reumple &om tbe dock. 7 . 13 .2 Retest tho resample. Jflbe**n:anal~** falls within the :t 20% oftlte profiled villuo and within dte accepra,ble Jallge listed in 7 . 12, tbe simple is deemed a<eeptable . 

### C3-6
' 

# .. V E S 016240

# •
•
•

.. SOP No.: FP .(II)2 ..cl4 laltial Date: 7119190 Revisio n 0 April, 20iJ 7. 13.3 It tho roanai)'Sia results WI one 

### o f tho criteria, coDlael**Customer~** with tho**d~ .**  7.13.4 A flubpoint gmtor lhan tbe profiled range is ooMicb-od an

### insi**~fiCOIII** dioc:repaocy. 8 . 0 QU AUTY.CONTROL



## . . 3.1 Analyze an LCS (chlo':"be.....,) on a I per 20-samplc buis. 

### 1bo flaobc>9int must be widlin 

### :t; 

## s•p oftho 1rue value. 1.1 A soh>ent oft 

## mo"" 1lash point can be oubocitulod for chbobeazwe.**Acoq>~moe** "ill be baled oo some criseria. · 9.0 INI13RFERENCES f at... posj1ives may occur ifbal....,. IIR -·**~ma y**  be dol<ded ifa Oash is unolcy or I'=' in oolor. If this occ.,., continUo heating sample aod cbeckin& "' Oash. up Ill lhc poim wb..elbe IUiplo flasbet, boib, or tho uunplc temperature rises to**~r** lhan 200•F.

/



# I C3-7 

# ., i .· . 

# ... ' 

## . .. I 

### VES016241

# • I Ross IDciamllion Scrvi<;u, IDe;. STAN DARD OPERA TINC PROCEDURE 

# r ille: Sol lido Spot Test RcvUecl: 12-06-00 Dote: ll-06-00 1.0**~** TbltltiCibod is usod 10**deoc ri** **~** lbo proec<klre for detennlftinatbo p.-oce ohu16do. 2.0 APPU CATION TbiJ 

## J?01boc1 is llliJ(icoble 10 ..**-a~er,** soil, •l udge, oil, and ocher - samples. 3 .0 REFEltENCES Sngt Teot Analnis; JungJels, Ervin; Jolm Wiley 8:. Sons, 198j ASl'M D4918-9S ASSOCIATED SOP• No1IO S.o REAO . ENTS 5.1 Hydrochloric acid, concootrJted. Store in acid cabiAct with sccondal}' contairuneot. 5 .2 Alb·Scltzet**Tablet~** 6.0 EQUIPMENT 6.1 Bealctts, SO mL 6.2 Watdlglme$ 6 .3 leod acetate te8t paper, commercially purcbnsed 6.4 PW'JI" l1ld**I~** apparallll ' 7.0 PROCEOU'R.E Not<; All tl111Jlysaforwl.fokaro**~in** th•llood..UAtheaJra.ur 

### on. 7.1 Analyais of AqUCOIIS Samples 7 . 1.1 Pour approximately to mLofsaq>lc into a S().ml.boakor. RovioiOll 0 April, 2013

SOP No. : FP-003-03 Initial Dote: 7/18190 QAAppr!Ml:



## i • • 

# I 7.1.2 A!taeh a molst<Dild (with ree:ent wll«) piece oflead ececate paper 10 a watcbglass so lbat tb teat paper will cxtcad inlo lbo .50-ml.beal:zr...t<o tbe wal<hdiss'is plaoeoniOp**oftbo~** .



### .·. 

## ' 

## .**.~** 

### l C3-8


### VES016242

# •


# • SOP No .: FNl03-0l Initial' Dale: 7118190**~0 ~2013**  7 . 1. 3 Add 3 drops**of~ '""'~ro~ed**  HCI to lbd sample, place the watcb8J ... with lead**ooeta ~**  poper onto the beala:r, 

### mi,x sample, IIGd lot stand for I to 2 minoates. Tho load acetale- willlurD brown if sulfide is preoent. If IIIDplo ia 

### albtinc. addltioaal acid may DCCd 10 be odded to aciditY u.mple. 7 2 Aaalysis**ofN~** 

### SOIIJIII<s 7.2. 1 Mob ulunyofopproJ<imllely S go( sample and S**mLofAO~** war.rin a sc>-mL booker . 7.2.2 Cooli11ue as ' in Steps 

### 7 .1.2 and 7 .1.3 f or equcoua sampl os. 7 . 3**~** approximate sulfldc ccoccntration whco a positive is dcCccced In step 7.1 oc 7 .2 . 7.3.1 Set up**tbe~opperal~~Sas** JboWD ill F'q:ure I. Fill theoollectioo l!ask with IS ml ofS N Sil- Nittllle sohltioll. EDson tbal all ICab .. 

### Iicht aad DOIIeUiiJa. 7.3 .2 Welah 

### up to 025 llfllNOfu mple**~ly** I nto thoreactlOO fluk . DlluteiO the linc(2Sml) with DI woccr. Add. IIDOIIIIquirt of methanol to aid in OVDD dispc;roioo orthe sam p

le in the -tioo ftaak. 7.3 .3 Simulta D<OUSiy odd a few dropo of I :S Nilrio A<;id IIJd ODC CarbonatA:ICilric Acid tAblet (AlbSci-) 10 the .-:tion fluk. Jm"""iate\y cap with tbe outlet SIOpper and allow so-oted &QCS 10 bubble through the collcctioa aollllion. Tho**eft'~** will 0011.1inuo for a few mimlleo. 

### Do DOt JCOp collection unlil bul>blo me is**~** cboD I babble per S<CODd in the collection Oaalc. · 7 .3.4 Sample& conlain.iflc a1 least SO-PPM rcacuve au!fidc**con~<:<~** I will cauao the collection JO!ution to lum 

# a yell ow-Orown color. Tho inleosit y ofthe color will dclemdnc the r elalive wllldo**ooo~tet** If 110 apporeol color ia· DOdcoable but the lead acetate popcr wu posllive , .....,.result.aa s.PPM mUlde. · 1.3.S If color ispresem. n111 ulmdordcompariaoo """aeilbera 100, 2SOor 500-PPM IU!Iiclcotaod.a.rd following the same techniqvc used for tbe ample. Pour .-:ced solulicas info -1 shed test lUbes 10 .Uuelly compare and coolralt color. Ccmporisoas should be made aa qui<:kly as posaible fo llowilig roactioll3, as Silver Sullide will begin 1o prccipitalc shonly after iiS formotion . 7.3 .6 Fol low lbe &lildelincs for reportiJ\& a sulJide value, baaed on d1is 

### procoawc: 7 . 3 . 6. 1 l!lbe eolkdod sohrtioa maJCbes clooety to a b>own aand&td, repo!11ha l value, i . e. : 100, 250, or SOO PPM. . If !he sample 

# Y1llue-"' malth clo&cly w ilh lbe SOO P PM standard, but cannot be diatinauisbed as beins citbcr . hi ab« or lower wilh uy cenainly,lhen an aliquot should be 1M! out for - ! )'til t o an ouuidc lib . The ouiJide lab should employ use**ofS ~**  Method 7 . 3.4.1 orcqlrivalett l for Rcacllve Sulfido dct cnni otllion. 7. 3 .6.2 lflbe JO!ulion is c learly darl<er (more eolorod) lhan lbe SOO PPM 

### standard. rcpon u > SOO PPM and then contaCt Customer Sel\'ice. 7.3.6.l lflbe solution ia cloadyda:l<er (loss colored) cboD the SOO PPM Sl2lldanl IMil dulcet that lbc 2SO staDdan!, reponas 400 PPM .

. 7 . 3 . 6. 4 lftbesoiUiion bligh10r lban l h e 2SO ppm bul darker !han the 100-PPM slllndara, reporlos 200PPM. 7.3 . 6..5 lflbe JO!urion is lighiCC lban tbe IOO.PPM. solution, bulllill contains color , report aa SO 

### PPM. 7.3.7 SummaryofQuanti6catiM • · 7 .3 . 7.1 S P PM= no colorbullea d acelato Ia positive



### VE S 01 624 3

# •
•
• 7.3.7.2 SO PPM = 110me color, but< 100 StAndard 7 . 3 . 7.3**OOPP ~ba**  the IOOPPM Slalldard 7.3 . 7.4 200 PPM • > 100 PP M S!ODdorcl but< 2.50 PPM Staadud 7.3 . 7.5 250PPM • matchca2.SOPPMStalldatd 7 .3.7.6. 400P P

M • > 250 PP M S lalldar d but< SOO P PM Standard SOP No. : FP-003-03 IDiriol Dolo: 711&190**~isiODO** Ajx\1, 2013

7 . 3 .7 . 7 SOOPPM•malebcs**SOOPPMS~(requires** method 7.3.4.11oRSOive) 7. 3 . 7J > SOO PPM • > 500 PPM Staodard (Dio<repanl) 7.4 Disctepaocy Detmninatioo 7.4 . 1 lfe aanipl e tc6Ui til nooconfOnnant with the p<Ofilc, a reoampl c _,1 be rcqaesl<d for !'CIIIalysis. 7.4 . 2 If the rcsample io tl000011formaut with tho p<ORie, report tbc d. isc:repmoy 10 Customer 

### s.rVioe. 7.4.3 If !he ......,Po- with the 

### prOfile, the llq)le is aceep".ed blsed "':'the seccmd _,ll 8 .0 QUAUTY CONTROL 8 . 1 

## . . . An LCS is enalyu:d on a I per 20-sanopk basis or at a mioj m nm o f once daily. 1be L CS is a low love! 

### sandar<l prepared at a**~tiOCI** 

## or approximltely 20-PPM. The standud io**~in** a plulio boiiSe at 

### room..,._.._ alld !IllY be used ap 10 ODe DIOIIIh llDies$ it fails 10 

### live 1 positiw: raetioa. Ifthe staDdard degnwlcs loa poiDl wbm: it does not provide I poalDV. RlpOGSO, .-Ja: the acandard.

CJ-10


### VES01 6 244

# •
• 

# •

. .

... . 

## .. •• •• • • • 

# ·: 

# .· ·· 

# ... FIGURE I 

### Purge / Impinge Apparatus

Cl-11 

## . 

# . SOP No. : PP-003.()3 Initial Date: 7118190 RevmonO**Apri~** 2013



## . 

## .**~** 

## . .

' • , '



## . · VES016245**~0** April, 2013 

# e . 1 Rou Incn.rotion 

### Services, 

## rue. ST ANDARD OPERATING P ROCEDURE 

# •
• Rcvisioo**12~0** SOP No.: FP·004-Q4 Initial Date: 7/1 7/90 QA 1.0 PURPOSE 2.0 APPUCATION J.O

4 .0 This Dlb1bod is applicable for tbc determination ofpH Cor aqueous waste samples (>20% watcf content) .



### . ' 

### . 

## . ")lH £ 1 ec:crometri<: M easurement", Test**M~lhodi** for llvo1uation Solid Waste (SW-846), Melhod 90408, Revilion 2, · J oniiiU')', 1995 ASTM D 4980-89 ASSOCIATED SOPs Nooc 5 ,

0 EQUIPMENT 5 .1 pH Meier with comlrillati<:o e1ec:uode, llempetlture compensating S.l Disposable plas>ie beabrs, SO mL 6.0 Rl!AOEN'TS 6.1 Reagent water 6 . 2 · Certified p R buffen (1:00, 4 .00, 7 .00 and 10. 00) 7 . 0 PROCEDURE



# . . . /!I.U: , AllDNZlysis 

### fix pH-.1 "- porfomled In • Wlllllation hoodwith rhe exlow.st fan 011 . 7 .1 pH M- Calibratioo

• ' . . '7. 1 . 1 Sample and e&lilnlion bulrer must be 111 roccn tanpenrure, or a tempcrature-compcosoti.a& cb:tiOdc employed. 7.1.2 Place the clce<rode iD pH 4 buffer and pteU CAL. 

### C3 -12



## .. .. . 

## . ,· 

### ·. ·'. 

# · . . .. 

# . .. . . 

# . . " 

## . .. 

# .. . ·

## .. 

# .. . . 

# ·. ' , '.'/ 

### ·. 

## . , \ 

### VES016246

# •
•
• 7 .2 1:3 7.4 SOP No.: FP-004-04 

## mmat Dote: 71 17190 Revis:ionO April, 2013 7.1 .3 AUowreadini to stibilize. Thc.moter wt1 1beq> an<l'flaslt "READY.' once the readnig isoempl-. If4.01 is**displa~,** press YES. If any other reading it displayed, pn:ss NO and odjust tho ....toe to 

### illusil>g tho up 

### (t) or down ( J.) keys, tbcn pn:ss YES. · 7 . 1 .4 Remove !he eleetrodeftom th e bolfersolutioo. rinse, and 

## plice the electrode into the pH IObulfer. Slir modentdy. Allow tbe readiQa 10 sllbllize. The meter will beep 

### aDd ftash "READY" ooce a reading is obfained. Pres$ YES**if~** is displayed. If any oth« reading is displayed. ilijust the vallle**to~** as in Sectlon .7.1.3 . 7. 1 .5 Remova the electrode ftom the solution. The% slope should be displayed automal!eally following lhe completion ofthe c&libratioo. If the % slope is < '8So/ o, m:alibrate the meter. If**~ted** calibratioN produce sl opeo of< SS%, clw!ge the elccuodo. 7 . 1.6 The owner's manual shoul4 be c:omulted**forC1IIlbratioll~ .**  onaU DOW insuumolltl. All liquid samplea that have a protlled 

## ranae for. pH will be uswned to be aqueous (wolel' eootcDt of> 20" .4

).

· For aquoou:s samples, place appro ximately 20-25 mL of sample in a clean SO-mL pla$!lc besker and imm .... the ti p oflhe pH probe into the sample . Allow the 

### readiDi to stabilize and record the pH reading to lhe neareacooetcnth. · Wben pH reading is unSiable possibly due to solvent matrix in some samples, prcpsrc sample by making solution I J'l'1 sample to 9 parts Dl water.**~·** pH detennination on**~** phase. · N()l4: 

### lf the samp/<tmrperoture differs byIPUII'O /Iran 2 "C 

## /fotn the buff orsoluli<ms which ar e lrept at room**tem~rature.** til• measuredsamplepHmw t be ct>TT<XIed. Most pH me/us pravtd4 a means for tl!/3 correcticft. 8 .0 brSCREP ANCYDETERMINA TION 8.1 I f a sample r esuU is outside of !he profiled**~** request a resampte . 8 .2 If the resamplc also fall s outoide oftbe profiled range, the sample is discrepant Report the cliscrepency to Custonier Service. 8 .3 Also, fur'customer waste stored in the tank farm, ifa sample falls outsideof thepro61edrange, but leas than :1: 2 pH units, and the 

### test resuli fur !he sample is if«ler than 1 0.0 or less !han 3.0, the sample is considered

. dilcrepanl.

. 9 .0 . QU AUTY . CONTROL



## .. ... 9.1 Cbcckthe pH meter daily uing 4 ,'7 , and pH 10 buffer solutions . If any are more chan ± 0.2 pH units, use a fresh portion o(bulfer solution to rccbeek failed point 9.2 Calibrate the pH me<er daily using two buffers wbene- !he daily eal!bratlon check fai ls- If samples being read are acidic , buffen of !.0, 4 .0, and 7.0 should be usecl.for . callbraiion.



### C3-13

• • • J 

### · 

## .. · :. ' .

### .::**~1. ~~~~;;;** 

## ..**~. :-** **,: ;:;?** **. .**  

### . .. 

# . . ' .**~·'** 

### VES016247

# • STANDARD OPERATING PROCEDURE

Title : D<cenzlinalion of Relative J:>ensity Rcvisod : 12-%-00 Prepared by: ·Approvod by: Date: 12.()6-00 Amwoval: 1.0 PURPOSE To describe 1M pcoc;edOie lOT dccmuiaina tho denoity**fa** aample. 2.0 APPUCATION This procedure is opplicable to both liqui4 ud aolid samples. 3.0 REFERENCE S

• 4 . 0 ASTM 0 SOS7·90 ASSOCIATED SOPs Nooo S

. O REAGENT'S . 6.0 EQUIPMENT 6. 1 Ba l"""'**2** Gnduated 

### beakm, SO mL, diaposable 7.0 PROCEDURE . Note: All QltJJ/)'Si.r for density must 1M**~form•d** In o loood with the exhaust •• · 7.1 Analysisof Uquids 7 . 1.2 Add a volume of .. mpte to the beal:ct. 7. 1 . 3 Recotdtbe welsbtanch o lumeo£thel&JI>ple. 

# •
C3- 1 4 R<:visioaO Apri\, 2013

SOP No . : FP.QOS.Q4 lnitiaJ.Oate: 7/19/90
QA



### VE$016248

# •
•
• 7.1.4 C.lcula., lbc**dm~itr** 

## .S follows : denlily (a/mL) • Sample weial>t (C)/Sample volume (ml.) SOP No.: FP-00$-04 Initial Dolo: 7119190 RevisionO**prl~** 20i3

1). Aaa!yoioofSolidsorSllldgos

- 7.1.1 M._ 2S ml.ofc!rioni7M 

### water into 1 SO mi. pdno<ecl betkeraod 1an> 

### oo**~-** 7. 1.2**Addcnou&hoampletotbebetker~?dlJoplace** !OmLofwater: 7.1. . 3 Record !he**~jp** ood !he oo.--.d clisplooement of

### the water. 7. 1 . 4 Caloullll<> !he deosily uolug !he followill& cquodoo: dcooky (8/mL) 

## = · Soq>le 

### weisJlt**(syDi~** >-olume (mi.) 7 3 Discreponcy OdermlniOoo 7.3 . 1 If• umple mull Iiliis lllOte thoo ct 20% ouuklo oftbe protiled ruoge., •I'CSIIIII>le"""" be rcque$ted. 7.32 Jfthoreaample te9Uit is oJso ou!Sid<l ct 20% ofcb.c protiled raoae 

### IIIli. Within0.30 g/ml.oflbc oriajnal Rllult, lbe sample is <Omiderod dltcrepODt ood is reported to Culoocner Service. 8 .0 .**UAUTY** CONTROL 8.1 Tbo balance is cboclald daily wilh four tlandardi.oed 

### wei&bts (0.5,50., 20.0 , and 1001) . The 5.00-J weight · m

ust ba within 

### :t 0.05 g and tbo IOO .G-a wtiabt DIUlt be within± 

### t :OO g or tbo balance must be J'CCIIibrated. 8.2 An LCS laanaly...s daily uolug 

### ace<Ooe.. The demity must be within :t S% o f tbo 1n1e value to**~** analysis . Iftho OOOb'ol ample 

### &a.. check lbo volume 

### lDiflc lo easure tbe sol...,. wulakm to lbe 

### ._;atelevel aod diolodge my air bullblos.



# ... .

, 

## . ... . :. -·-- 

## . t ·:**.** -


### .....**··** 

## . C3- I S ... 

### · .· 

# .. ,• 

## . . · . . ' 

### . 

### ·,. 

## .·. VE5016249

# •
•

•• . STANDARD O PERATING PROCEDURE

Revised: 12.c6-00 Appnwtdby: 1 .0 PURPOSE 2.0 APPUCATION SOP No.: FP-006-03 Initia l Date. : 7n4/90 QA

This primaty 

### IDOlbod is oppli<:able to all**wu~** samples. Tbe detection limit isS PPM. The allcmato -hod 

### Is applicoble to tra.upareot and tnnllucontllq\oid wa""" and ootid -.. wbooo slurry is transporont or tnnalucent. The dotcction limit for these**so~1 les**  is 1.0 PPM. · 3.0 REF'ERENCES 3 .1 ASTM 0504 9-90, Me<hod B and C 3 .2 C)'IJitesmo teot paper Wlnlctions • prill:llly method 3 . 3 Merdmquant Cyanide TC$1· aluma!e method 4. 0 ASSOClATED SOPs

.S . I Primary method S.l.l CyaJileSmO test paper, coDUI1C1'0ially puroba3ed - fisher# 90604 5 .1.2 Disposable pl&sric beakeR; .SO, 250 mL 5.1 .3 Watch 

### gtasseo S . l.4 Concentrated sulfbric oeld, commercio.lly purchased. Store at room !empcnture ina scoured cab'- 5. 1.5 Sodium Bica:bonate 52 

### Altemiwo mellond S.l. l Disposable plostlc bcaloon, SO mL S.l .l Cyanide Test**Xi~** Mm;k**~** 10044 

### C3·16 · 

## . . .. . 

## . .. ·. "'•

l.j.,. . .. , , • , •• t .. 

### VES016250

# • 6.0 

# •

7 . 0



# •

.. . .**~** SOP 'No.:**FP~** lnkial Dole< 7f24190 RtYirioaO April. 2013 PROCEDURE Noll: All cyanide aJUJiysis miUI be pufomttd In a ,..,lllatian hoodwllh the .exhaustfan on . 6 . 1 Primory method:

6.2 6.1.1 Pour approximately 10 mLofliqald 

### wuce <>r approximate!¥ 10 gofoolid wuco mixed into a slurry wilh 10 mL doioaized water iniO a SO•mL plastic beaker. . . 6.1.2 Moislenlhe end ofa ' t·2" piece ofCyoutesmo 11:11 paper aod stick to a 

### wotellsl&u so that it will 

### ba!l& inlo lhe headspaco oftho boolcer. 6.1.3 Add 2 <>r 3 drops ofc:oa:<Dir&IOCI oulfilric add to tho sample in lho beaker aod top wilb 

### wu:baJau aod tat atrip. MOO'C ecid IDlY be needed oo alblioo samples. 6J. 4**~** lbo somple ,_t (l)r tl leeol S .,.,... and lbeltobsc:M:: lho oolot' oflbo 11:11 llrip . lf&.:e CN is present, lhe middl&oflhe test strip W11l 'tum blue. FW.. hits mey OC>CUr li<>ai'Oiatile oxidizing or reducing ....,U. In thole C11011111Y**e~** HCN CID. be set &.:e by oocli\1111 bicarbooato . 6.1.S Ifa**positi~~e** ._u..is oblained oa lhe aamplc, place**~** of sample in a 2$0-mL plastic dlopoaablc booker aod diluJe to SO 8 with doioniv:d watct. Talre a 10-mL al i quot of this dilution ond pcrl'onn stepS 6 . 1.2 

### throuah 6. 1.4 ttbo..., , Ifa positive roac:tioo is ob talnod on lhe dilutioo, . tho sample oontains atlea&t**2~0** PPM of c yanide 

## ana should be entered as 2.50 PPM on tlw AS:400 . Alternate method: NOTE: 'I'M allenoate method""" be IUM to confirm qwesti(JIIQbk IULJ , or to mort QCCIIrat<ly tUJU'min• 'l"anlilathoe kv<ls. · 6.2.1 Filla 

### tieab:r with Sml of liquid aample, or water &lmry ofa solid sample . 6.2.2 De<ermitlt die pi! value. 6.2.3 lflbo pH is >9, adjual s lowly to between**~**7, wing diJule siUNric lcld. 6.2. 4 Add 1**~I** 

### dosiJ>& spoon o f""'""'' I llld mix well 6.2.S AddS drops of JU&cm 2, oodmlx well . 6 .2.6 lmmedintely i mmmelhe reacdoo zooe oftbe- slrip in tbe solutloo lilr 30 soconds. 6.2.7 · Shale offexcess liquid fromlhe strip ud compare reaction zono wilb the coloncale within 10 second .. 6.2 . 8 If tbe m>ult b saturatad, do 1 I OX dillltioo. A positive hit after dilution indicates a cyanide c0111eot in exceos of300 PPM, DISCREPANCY DE.TERM!NA T!ON SamPJeo profiled a positive ar2SO PPM beymlde (itldlcttcdby a Yon tho sampleprotiloJCI'tU1) will pou npnllcsa or'lbo raul.t af this tes<. If however llllQple is profiled as negative at2SO.ppm c)'IJ!ide (iodicltcd by ao N "" lhe Stl1lple profile.....,.) 1 posid.., ....ult oa 1 lllllple dil uted I to SO (1$ ill Step 5 lhove) oboald be cO<ISidoled clisc<epaot llld 1nosomple sliould be ohuincd. If tho ..-mple .00 to#S positive wbeo diluted I 10 SO, lbe itm;>ie is disctq>a011lld cu.stomer..,:..;oelhould be !lOti tied. Tflhe resample is""iitive wbendilutcd d!eaample maybe accC'plcd based on that reso1t. · 

### CJ- 1 1

. . . \ " 

### VES01625 1

# • 8 . 0



# • •


# •

· 

# . . QUALITY CONTROL SOP No.: fl>-406-03 lnitW Due: 7/1AI90 RcvbionO April, lOll Aoalyz.e aS-ppm J11D1on1 daily fi>r UOC with 1ho priawy meohocl. lflbo 

### aacn- mtlllod 

### it \I$Od, a 5 .0-pp!UtaDdanl shoukl also be anal)'2eel daily usifta the a1tema1e mecbod. Whenever the I:CS fails, prepare fiah CO!IlrOL If lbo ..,, failo whh tbe fmh ooocrol- diloord teat paper ODd/or reageDIS and uoe oew ot hob**~~**



### C3-l8
VES016252

# • I Roos l.ncine,.lion Servic:cs, Inc.**P~b y:**  

### AJ!p<oval: 1 . 0 PURPOSE 2.0 APPUCATION STANDARD OPERATING PROCEDURE

Revised : I 2-06-00 Approvocllly: ·Date: 12-06-00 SOP No.:**~"P-007-0S** loitial Dare: 7131190 QA 

# I

'Jhio mdhod i.s applicable 10 •Y liquid or 10lid llmple, wbich can be combusted in on O"ll8tn bomb. 

# •
• 3.0 ltEF!lRENCilS 3.1 ASTMD2361 3.2 3.3 ASTM, 1)808.91 Pan OxygeA Bomb u..., Monl>ll 3.4 SW-346,Mechocl9020 4 .0 ASSOCIATED SOP, FP-001, BTU Analysis S

. O EQU1PMENT S.l Parr 126llsoperibol Calorimeler (or cquiV1lierll) S . 2 Combustioo capsUles S.3 Burots,SOmL 5.4 Bllancc 

## s.s Bu.l<trs, SO and 100 mL S.6 Stirplate aDd stirbo.rs 5. 1 Volumetric pipets, 10 ml SO mL 5 . 8 Volumetric fbsks, 

### I L, SOO mL, 2SO mL S.9 Ddpooable pipeos 

### S . IO Diopcmi.ag bouk pipeiS, 2 ml- 10 ml ta!*ity 

### C3-19



## . . . VES0 1 6253SOP Mo. : FP.(I()7-0S Initial Dole 713 1190 IU>Uioo 0 Apn1, 2013 

# •
• 6. 0 REAOENTSISOwnONS 6 . 1 Sodiumcorbonato (Na,CO,) solution, 50 giL- DistolveSO .O gofNa,CO,in800**mLo deic~**  waiU •. Dilote to 0110 liter whh dclooltcd -cr 1>1io8 a**Y<>l~c** Oaslc. Store io a plastic bettie at room temperature . Tlds aollltloo ia liable f or sbt m onlha. 6.2 SiM:t oilnte (A&N0 1 ) solulio<l, (0 . 1000 N) - Diasol ve 15.691 

### a ofAgNO,in goo mLofdeionized 

### wuer. Add 10 mLof coocentrated nitric acid to help disaolve the sil ver acetate. Dilulc to ono lit... witb deionized waler 

### us:ioa a vo!umeuic !Wk.**Sto~** in 111 amber aJaS$ bolde at room temperatuno . This solution is liable (or 6 aoontbs. 6 . 3 Potassiumlbiccr-te(I<SCN) solution· Dissolve9.n &ofKSCNin goo mL ofdeianizlocl 

### water. Dllute 10 ooc liter with cleionizod water using a ""IUIDCirie ftask. SWwlardi2Jo ogaina 0.1000 N Aa}IO,u IOilo""*' ( 1) Pipette 10 mL of0.1000 N AgN01 W. a :ZSO..mL b<abr using • 10.0-tnL YOIIUXICiric pipcne. Dilute to 50 mL wilb dciaaized water . (2) Add I mL of IG% F<NH.(SO,)> tolutioo. (3) Titrate wilb KSCN to allabl m -bro wn endpolllt . (4) Repeat tho ahe"" tbtec slept two additional time> and a--ae tho vohnncs obtained. (S) Calculato 

### II! • normality oflhe KSCN using the equa ti on below, NKSCN= IN AaNQV • 

### !Volume AgNO,. mLl 

## (A..,..ao volume KSCN, mL)**St~** in a plastic boldc at tOom ldllpCrllluro. This 501utioo is stable lOt six mo!Jihs . 6.4 FemeOlDJ!!Oniwn sulfUc(FeNH.(SO, ),) solution, IG% · Dissolve 10.0 aofFeNH.(SO.), 12 H,O in 80 mL of

deioaizod Wiler . Add 2 mL of

# ...,....,.ted HNO, and dilute 10 100 mL wilh deionized "'"" IISioa a volumccric Bask. SIO<C ill an amber boCt1e at room tempe<a1Ure. This solulion is atable Cor olx _.... 6.5 Melby! alcohol, oommer<:ially purchased M Nilri<: Aticl, coocenlralcd; 00t111110..wly purdlsted 7.0 PROCEDURE FOR DETERMIN1NGTOTAL ORGANIC CHLORINE**CONTE~"!'** 7 . I Follow steps 7 .I throu&h 7.11 of lll.11dard opcratlna protedute FP-00 I to prepare sample fer analysis. 7.2 After the sample bas been burned, therouJhly was the oxygen bom b wilh**dei~** water . Colleet the wasblnp in a 250-mL volumetric ftask. D llul<> to lhe marie wid! deioni2ed wai<Or. 7.3 Transfec SO mL ofthe sample wuhinp into a 250-mL beslcer . NOle: For smnplu wltich ar• hiJh/y (}()/()f<d or**suspec~<d** 10 htwe c high**chlorl~•** conrvu, IOU a 10 mL aliqucumddiluu 10 SO mL ..;tlr dd<Jolz<d wctcr. J>rocud with step 7 . 4. 7.4 Using a b=tle, add an exceos ofAaNQ, (aboot4 to S mL) 10 lhe sample 

### nnlin& lho exact volume added. 1.5 Add to tbe**~** In tbe fOllowing order. 

# • (I) {2) 2 

## niL or llOIJQOnlrlted oitric aeid

' · ·' f . • • ' / . , \ · .: . ; . 1 mL or I 0% FeNJI. (SO , ), solution C3-20 

### '

# . . VES 0 162 54

### ' I ·

# •

• 8 .0 SOP No. : FP-«17-45 lnicial Dllo: 7131190 (3) 2 mL of methyl aloobol .' 1.6 Tilra1C with KSCN 10 ali 

### &hi rcd·brown codpoilll while mixing on a stiJpla!O. 1 .1 Cal...tatioos 7 . 7.1 Total cblorine (m&IL) - [(mL AaNQ 1• N AaN<b) • CmL KSCN • N KSCN)l • 3 S 4SO mboample 7.7.1.1 ToRI...taiOuiodlocrcplocelS.4S with 126.9 7.7.1.2 To c oleulole .. broraiDe, replace 3S .4S with 19.9 7 . 7.2 Total eWormc**(..,a) ~**  ff mlll.IO!I! 

### 'I'P!! i' c!d 9'ia&l 

### •Cto!a! Yl!!Ams. Lll**~** sample weicJ!t, I IDI · Re\ UionO**Aprii.~Oil**

Note: Tire w iaJ chi <>riM t/mlled dma · s ·u ustd wlftn a SIJ mL o.Uqwo; 

### to takett 

### from 1SO mL 

### if a lrm.L aJiquol 

### t.r**takett~** tlu dtrati""' the "J• & l'lpiaadby 25 to accow 11

for tlt• dJI•tlotr . 7. 7 . 3 hrcent total orpaie chlorine (%) • ullg total orgnic shlqripe 10,000 NOU< : Un the sam• "'IIUJIIons abo"" for calculatin g tatal inorgani c chlorine COli lint; ho,.,.,., ptrfom the titration wlnr the raw sample , nor ·the sample combustedIn the bomb ca/()1'/mcter (See · Section 8 . 0). To dtt • rmlne tM 10141 organic chlorine In a sam )I



### e. subtract the' 1110f'ganlc 

## ,....u $ from the toral orgoirt c chlorlno result s. PROCEDURE FOR DETERM!NlNO INORGANIC CHLORINE CONJE..NT**Not~ :**  Tltu port/011 of dJef"(JCU.ur• 

### t.r to bo ustdat , •• dUcrtiiM of RJS**O.StD~MT** !Wvlcu . 

### 'I'M followlltr ducribu dta f""'Udwrc**for d~**  ilwr:anlc chlorilto in tlttsample. Tlta**<Hga~~ic** chlorfnt !s tkt.,Jntd by lillbttr>cllng th• lloorgtmic 

### from tM ICia1 chloriM. 8 .1 Wei&!> 1. 0 g ofm.,amplc into a boalcer. IXHI<JI' COMB UST THE MATERIAL 8.2 T IIIIISfer !be sample 10 a 2SO.mb volumcttic Out< and dilu.toiO the mark with cleiooized waou . ' 8.3 Pipette SO mL ofsample inco a 25()-mb beaker . N()(t: For SQ111p/ es which art hlllhl ycolortd or suspe ctad to bow a h;glr chlorln• oollle nt, tak4 a 10 mL aliquot QJU/ dilute t o SO mL witJ. deloni:.ed waJU: J>roc«d with step 8. 4 . 8 .4 Procctd with SrtpS 7 .4throoJab 7.7 . 

## s

.s Cal...tatioo PCIOCilt 

### Qraauic**Chlorine ~**  Pcn:em Tolal C hlorine - Percent lnocganlc Cblorinc 9 . 0 DISCREPANCY DETERMINA TION 

# •

. ' : :·

# . .... 9 . 1 I flbo OJp.llic cblorine rauli fal ls ouuidc t 20% oCtile proliltd f111180' , requeot a resan>ple . 9.2 Ihpon roinaly!is,**rbeaan~ple ~lt**  tills ouaidcr:t 20%oCthe profiled raa:ebolr is within !be rq>roducibilily tol.....,.,. listed bdow, rho l&lllplo ia 

# oot>S«rccc disctq>ont and must bo reponed ro C...tomu Service• 

### C3-21



## ... VES016255

# • Rcproducl'bility TolennceJ: SOP No.: FP-007-0S loi1W 0... 7131J90 Revisioa 0 Apri1.2013 (I) li the maximum test r<N i ta for toto! orpnic chloriDe are S26%, tbc total**o~** chlorine reoults must be within 4% ofooc onodler. (2) If !be maximum test results f or totnl orpnic chlorine 

# are > 26% , buts 38%, tho toea! orpnic chlorine iesults must be wilhln6%ofooch otha:. · (3) lithe maximum test...Wts for tocal orpoic cblorioc are> 38t'., but;; SO%, the total 

### Of1PIIlic ciiJoriDe results must be witbln 8% ofcocb other. (4} Jfthemomnnm IC$treoults**b'~** orpnicchloriaeaftl >SO%, but S72%, the 10111 orpnio chloriae r<$UII$- be within 12% 

## or<tell oeber . Mp j ptm T otal Orpnic QUmjnc 'Rrpals 26% 38%**~0%** 72% Mpiqyn Tok'zppr£- Total% Diffcrag 4% 6".4 8%**~~.** If

the rcoomple falls OUI$iclo ± 20".4 ofthe profiled 11111C• AND FAILS the reproduolbtlity toleriiiCCo, pufonn a •••uuplc until CO<ISistent "''"Its ore oblllined: 10.0 QUALITY CONn.OL • 10.1 Each batchofKSCN is alaodardized afterprcparatioa. 

# • 10.2 An LCS is analyzed o n a I per 20.aalt11le basiJ, or ••• minimum of' ou least once daily . Chlo- is used as upikingc:ompound. The pereoocreooY<t)'mustbe within !be range of(7S- lOS)% ofthe theoretical value . If the LCS !ails, ro.IIODdatdlzo the KSCN tolution md re<itram tho control lflbe control flils , rcbomb and aaaJyze a ICOODd LCS . If the LCS -- to fail, JftllOIO aU liah**rea~** befi>re ualysis or**~~** 

### . 

## .



## q-22

. • , \' 

## . " " 

## . \ .: •' 

### VES0 1 6256

# •
• RMslonO April. 201) STANDARD OPERATING PRocwtJR£ 

# - I SOP No; FP-008-04 lnillal Dato:**1211~190**

# r_~_**~~ --** **~--"· iM** **Mc ~~** **-- ~--------~~~~~~~=---~~~~**  • Rc-.Uion Date: 12-06-00 • Pn!pemcl by: . ApproV<Id by: Dale: I z.o6.00

_ QA 

### Approv,.: ' 1.0 PURPOSE T o desl;nl>e the proce<luno used,to detennioo the viseooily ofliquid aamples•

. 2.0 APPUCATION

. 1bis IIIC1bocl 

### is applicable 

## w measurillg liquid - wboso viocoshy is in the ranae of(80- 36000) cpr.. The

primary.,. of**~~lese** dl1a is to defi.oe whedxr 1 Uquid is pwpoblc or not. If1 sample is< 2000 cps, it ia ClOCISiden>d puupable , AI > 2000 cpo, a oamp!e is c:ooolderod IIDpumpoblo. 3.0 REFEREN CES 3 . 1 3.2 Bt ooldield Vbco-..- ()pcntin& M.uwa1 "Staadatd Test Med>c>ds for 

### Rhcolosica1 Properties ofNoo-Newtooiai. Mate<Wt by- (Brocildiekl) VbcomcU>r", ASTM D 2196-86(RcaP!ll'>-t 1991) 3.3 Gardner Tube ViiiCOIIty Measumw:ot, Method ASTM 0 I S45 4.0 . ' ASSOCIATED SOPs 5

. 0 IQUJPMEl'n' Btool:fie!d Y*"-, Model RVID 6

. 0 STANDARDS/SOLUTIONS Vi5co<ily 

### sla.Ddards, eommcrciaUy purcbased. Store in**~I** nuinufacllltcr' s containers a t room tcmj)erature . These standards""' 100% 

### sillCcmo acd**are~** ioclcfinitcly; bowevcs , the tnat>llfactwor recommends replacin& the . ltaDdards 1Dnu'ally if contamilll.tioo is preoeot. 7.0 PROCEDURE Note: Samplai containing solids CQIUIOI be mii<Uurtd aecurtJJt/y w.'Jing this mtthod and shouldnot bt tuttd.

. All••II;(Jsls 

### fo>**Piscot~V** 

### ,..,.., INperfo,.,.,ed In " reJilit.IU»t h«HH with . tht OJChiiiUt 

### /41t .,_ 7. I Viseometm sot-up 

# • • 7 . 1 . 1 Eosurc thJl the 

### visc<imi:ttr is scc:Cirdy iuounled oo iiS stand

# ~-~**~>H::**

# .. :

. ·

: 

# .

· .... :. 

### . 

# ...

# :.**~i ~~** **~~.J: ;~;.** 

# :;·, · :·**~:** 

# . . , . .

1 . 1.2 Tum the powu switch ON. 

### CJ-23 

## ·.

• • • ll 

# . •' · 

## . 

# .... : '' ·' 

### VES016257

# •
• \

# •

l \ SOP rio. : FP.QOS.Of Jnldllllotc; 12/1 <4190 Rm.looO April, 2013 7 . 1.3 · Cbeck'tbl>babblolevello.,....s 01 U..IOpofthe\liacoroe<er and adjustiiso the instnuncot iJ level. 7 . 1.4 1U:o ON tbe ·DOO>rswitch ond oct tbe apeed aeleclllrlcnob appropriately . 1.1. S Wilen the viscometer readlna alabillzes, tum

_ the ZERO adjUSUDeDt kDob co 0.0. 7.1.6 TUm the motor.switch OFP. Tbls places the viscometer in STAND BY modo. 7 . 1 Sample analysjs - Visually compare the sample wilh tbo three lowest vi000$ity**~** (lS, SO, and 100 . cpo). Tdt !be suople bock ODd f0<111 and**~** wbleh .andard behaves most similar co !be sample. Record tbebestmatchvaluo intbcwcocicyoocrionohhe 

### Josboo1<. Record values**as~** <2S , 1S, SO , IOO,or >100 cpo. U aaomplc appcon Yi!u&Uy >100 cpo or ifpulp-Ji)z solids are preoeoL Tbco- uslna doe Brooldidd rocati<ma l**~** mut be employed. Smploo > 100 cpo**alto~·** \'iocosity 

### loa st-t 10 be 61lcd- iD 

### ad<liiioc 10 !be**~tlo&)>ook.** 7 . 2. 1 Ailacb an appopriate s¢.c!Jc or UL Adapter to the Yisc:o.,...., Note: Sptnd/<#1 

### u wed for slDI!p/n wUh /ow · apparurt . •lscoslty (1/u wartr ) . For moro vfJcow sampl n, the higher niiWibcr ed splndie.t (e,g .. 1M IJ1Id #7) are**us~d.** In rithu """"· readlnp below 10 . 0 Uiould be aw>lded. 

### If the sample reads below /0.0 at aD 

### •PNds ttst<d. swftelr w a lowu numhertd.tplndle. 

### if tho sample reads below I 0 Ill all sp«tb !Uing sp/nl/1• #2. the st111tp/e is wo/1 btii1W 1,000 CJl!l. Y 0

u moYthen

## proe«ti"' normaiJM/ng th• rtadlngs below 10. · 7.2.2 Using the spindle approocll, inJert and ccntA>rthe spindle in the test maletial uotll lhcllWd lc"" l comes up 10 the imrocni!Oillii'OOVC which iJ cut into the shall ofthe $f>intllo . 7 . 2.3 Tum the mocor switch ON and allow tbe meter 10 alabillzo. Each .. mplo must be meuured once at four dill'"""' spoccl aotiiDp . Multiply the reading by the app oprioto &<:lor found by uaiag tbe "faclor fil>der" provided by Broolc6eld. A-lbe four readillgs ODd doeemW>c the appareat viscosityof the -lo. S.O OISCR.tiPANCY DE'IERMINA 110N Sampics are profiled ..beiag < 2000 cps or fall!na bct-.11 2000 &ad 36000 cps. Below iJ • JUt ofoiNatloos , wblch 1 110yoccur. PerU>rmthocomx:tn·uctioo'liJCccl ifauch asil\latio<a docs occur. • · 8.1 U lbe avorage test result Call• 04dSidc the**umple-~6Jcd** 

### ranae, request a resample. . 8.2 If tbe 

### reoample is outside ofthe profiled ranae and**the~** result iJ < 20% RPD &om the first result, lho sample is considos<>d disorepanlood must be repMod to Customer Setvioo. · The JU>D iJ calculatod uoina the f oUowing equation: RPD • ((A . l • A2)1((AJ+A2)12) ) 

## • too AI • F.m sample rcsull A2• Duplicate -leresult 83 I( the !tJ'D .,__,tbe original Wnplc raWt ODd tho mample value is;>;**20'~** alltird 

## ...,Pie IIIUSI be 

## rcqucol<:ci. Rau.lu from the diRe ta1s**~ktbc** conveyed 10 CuolwtJ« Savioe. C3-24



## . ' , • 

### VES016258

# •
•
• SOP No.: FP.008·04 lnitill O,te: 1:!/1.190**Rev&~** .. 

### o**Apri~** lOll 9.0 

### QU.urrY CONJROL-

, 

## . - ..11 .

### f The viseOmeter is standardized usma twO di!Weot S Ulton ou viscosity standardJ. The viscooity ofeach oliDdard must be wlthln :t**10'/~** ofits truo wl..e 

### ln ordor to proceed witlo siiDplcllllll)l1is . lf!M s1llnelu<b •· read outside 0 f the ooc:optabl c 1'111&0. cbcck !hat the cqui-t is level and 1M spindle is oot toucbina and is &eo ofdlbrii!Dol clamaeed IDd immersed iR tho 111Ddo1d to tbe ll'!'ros>riilo level. Ifthe instnnoent still roads oullide oflhe .....,able 11q0. use an"'- viscoeity staadarcl. lflhe**viscome~** <OIIIiuues to fall have oppropriale 

### repm made.

C3-2S



# ·, .... · ·:**:.~**

# .**~ :~** **:~ z:'f.** **.<** 

# .·

_ , 

### VES 01 6259

# •
•
• .Re\isioa 0 Apn1, 2013 

# 11\<* lnci.nmatlon Services, Inc. STANDARD OPERATING PROCEDURE SOP No.: FP-009.01 lnilia1 Dalll : 06117/96

# -·-~'~ QA 1 .0 PUIU'OSE T o d<l<ribc the proc<dwe foT c!ccenniDio3**tbecompabbilicyof~** was<es 

### bymilWia amal1 'l'llftlilies. and clloervin& and cqmtina my 

## -..s ..rudl- y oocur. 2.0 APPUCAnON

3 .0 4.0 This prooedwe is applicable to l iquid WII1Cll ofvarious Wasse Produco Surveys (WPSI) which are to be mlxcd arul prooonod"" a larpt &<ale ac tbo Roas lncblc<atioo Services, Inc. plant. Note !hat chit )XO<Cdll<o may not dcwct delayed or slow ._nom. REFERENCES "Comr11illaJcd Waste Compatibility"', ASTM Slalldard D 5058 ·TcstMolbodA (modifle<l),approvcd 1990 ASSOCIATED SOPs None 5.0 EQUI PMENT 5. 1 Disposab l e plasii< bealcm, 50 omcl 250 mL 

### u Tbennom&r, 0 . 205"1' 53 Transfer pipeU, diJposablc 6 .0 REAGENTS 

### None 7.0 PROCEDURE CAUTION: Thill proudare moat be ptrfo..-.1 lao Yftltllali011 Mod wilh the exha•t fan on at aU lima. A physical barrier (e.c . tloo b.ood aasb) ah...W be plaml belwtm lila anllJ11and 

### doe 1aaopln wlllk 

### addlft& ae>d 

### mLdJia It 

### tt.klnc plaoo. 7 . 1 Tbe aamples accotllj>OIIicd by a Colnpall'bUily Rt>queal Allal)lis fonn ( ...Fi&UrC 1 ) which iDdlc&llla !be o rder in wltich tbe aamples**~** robe mhcd.


### C3-26
VES016260

# •
•


# • SOP llo.: fl>-009-01 Initial Date: 6/17196 RovlslooO April, 2013 7.2 Meason the temporatwo ofihe samples and record 

### aslnltku TemperaJure. Small tcmperanue variations (s s • F) 

### bOiween samples may be ignored 

### ind lbe avera1:0 sample tcmpel1lli>re recorded. Ifsamplea have 

### lat&c lemp<(at\lle variatioas (> s•F) or ate> 800F, allow them to come 10 room tcmperoture before**~· ·**  

### . 7 .3 Plac:o20 mL ofthe first sample liMed on tile request 

### form into a 250-ml.plastic bealcer. Pour20 mLofthe second sample into a 50-mL plastic bealcer . Beein adding dlC oecond aamplc 10 

### die lintdropwi!e usin& a dilposable tr8111fer pipe«e. IfliD obvious reaction occun, slowly pour the rcmaludcr oftile second sample into lbe first at a rate ofapproximately I mU"""ond. 7.4**0~** and record any reac1ioDJ that occur during tbe addition ofthe second sample, e. J., producdon of miru,**~. d...~**  layering, polymerization, precipitation, bobbliag, etc. If at any point during lbe prooedtore, a ....,lion ocaus, stop the procedure, record the reactioo, md mad< the wastes as incompatible, explainill& the reaction and wbicb WPSs caused IL 7.S l fM reaction occun after adding all ofthe oecond sample 10 the first, 

### beain mlxlns for 30 • 60 seconds. Apln, observe and record any reaclioos during the mixing period. Moasure the t<mpero1ute oflhe mixture, DOting any chances. Allow tbe sample 10 sit wilhout a&iJation for an additional 30 - 60 seconds to observe any delayed reactions. 7 .6 Ifno rea<:tion occurs after§7.5, pro<eed to the next sample on the**lis~** 

### addlna it to the mixture andobservin& · and recordin& any reactioos as in §7 .3 to §7.S. Repeat the prooedtore for all remaining samplea, rnakio& a we 110( 10 accwnulalc more than 200 mL io total volume . 7 .7 After the last sample

### bas~. added and mixed,

### ~ 

## tbC temperatUre ofthe mixture and record as Final TemperOlUTe . Calculate and record any cbange. If no observable 

# -•tioa occurr.d dorins the entire 

## p......., tbe waates are coDSiderod compatible. Cbeck the C<»npatible box on the Compatibility Request/Analys is form, releasing the waste to lhe dock for processiug . :REMINDER: If a reaction ocean at IOJ' poin t ID the proeodure, STOP. Idlllllly the IDCompatible wute nd tht nacdon obaenod 011 the Co-tibillty Request/Analysis form, ucl clotck lhe /nc,_padble box. Do not r$ut the material to the dotk. Operations may then r e quest tho! tbe test be repeated without the reaetive sample .

C3-27


### VES016261

# •


# •
•

. 

### :

,. : · 

# . ... ·- 

# ... .. ·· ' · 

## .. •' · 

### ... 8. 0 FIGURES 

### COMPA11BIUTY ANALYSIS SAMPLES TO BE TESTED (lis\ samples in the desir ed mixing order): SOP N o. : FP-009-01 lokial Dale: 6117/96 RcvlllooO April, 2013RIS· 343

SlliDOtV Number WPSNwnber 1 

### 2 3 4 5 6 

# .

· 1 

# . 8 9 1 0 DATE OF ANA LYSIS : ____ ___;__; ANAL YST :

### --**--- -~--** **--** INITIAL TEMPERATURE

_____ •F F

INAL TEMPERATURE •F NET TEMPERATURE CHANGE •F**CO I\NEN** **~** (Note any vlsibte reactions and wh ere In the mixing sequence lhey occurred) : 

# D COMPATIBLE 

# D INCOMPATIBLE (see above) This section is fot Doell Process ing : (fot billing purposes only) Note why drums are non-pumpable: 

### siipper. -- - WPS : __ ...:__

_ _ Count : _____ _ 

### Reason why :

_______ __ ___ __ _**~- ---------**  

### Shipper:--- WPS:

_ _ __ _ 

### · Count:-:- - - --

## ~sonwh~**-- --~** **-- --** **-- ----** **--- --** **---** Slipper :--- WPS :

__ __ _ 

### Count:-----

### Reasonwh~-**-- -------------** **-- --** **--**
C3-28

• · : ' ;.**~** ...**~- ."**  • • • 1, • • .. • : · .. 

### . 

## .**~** 

## . . . .**"'. ;;** **:A· /**  

### .. :-.:**~:: :.1** **':** ;**:; ..-** **"~** '. ,/ 

## .. . . 

### : . ; 

# . .**~** 

# ·. .• 

### VES01 6262: 

# •
• 

# •

,. : STANDARD OPitRATING PROCEDURE Re.isionO**Apri~** 2013

SOP No.: FP-012.03 lnlt!al Dale: 

## t210419o Title : Determination ofAsh eo-! Revited: 01/11101 Poeoaredbv: ADilroYOd bv: Date: 01111/01 OA Anorovat 1.0 1.1 20 2 . 1 3.0 3. 1 4.0 

## s

. o PURPOSE To ' quantltativety delermiae the ash cootent ofa sample. APPUCATJON This method is applicab1c to all liquid and solid waate samples. So01e samples may yield lower than

..

pected ub contcitt doe to non re<ainable materials such .. volatile metal& . REFERENCES ASTM, 0482-87,Melhod for Ash:&omPetroleumProducu. ASSOCIATED SOPs EQUIPMENT and REAGENI'S S.l Equipment S. l.l Analytical Balance 5.1.2 Dessicator 5.Jo.3 Disposable Plpettea 5 . 1.4 Fume Hood S.t.S Muffle Furnace 5.1.6 Pcrcilain Crucibles 5.1.1 Tooas 5.2 Reageols 5.2.1 · Anh)'drovs Calciu!D Sulfate or Indica 

### tin& S iHca Gel. Bake the desaicant at lOS degrees .C · occuionally to bop il activated. 6.0 PROCEDURE FOR DETERMININO ASH CONI'ENI'

' \ 6.1 Weighing 6 . 1.1 Weigh a clean, dried crucible on an anal)'1ic:al balaoce and record 

## the weight to the nearest O . L

· ma, . 

### C3-29 VES016263

# •

•

. 

## ..**~** 

### ·. 

## . . ,**~** 

### ' ·.**.:~** 

# .. . , , ., : 

# .. . . • . SOP No" FP.Ol2.003 , Initial Dote: 1W4190 Revision 0 April,2013 6.1.2 Place approximaiely 

## 2 . 0gram> ofsamPle into the , CtU<ible and ..cord the inicW weiaht ·oftbo crucible**~od** sample. · 6.2 Athina 6.2. 1 Place the labeled CtU<ibles inlo1hc ftimace. Malee sure the fume hood is on. Set the temperature control to'-180 degloes C. Let the oample evaporate or gently .**~off** at tblo ltiiipt>rature. Tbh IJilly tab a few hours. 6.2.2 Raise ihe mufiletemperature to 1$0 :t 50 de8Jee& j;. Allow Ole samples to reach Ibis 

### JemPerllllre. This wiU tab about en hour. When desired 

### temjleratwe is reached, tum off the muflle but leave the door closed. 6.2.3 When the lbmace ..__bas ccokd to shout 300 degrees (: , open the furnace door and allow ooolilla to at least 1 00**deiJee~** C. 6.2.4 Place asMd sample crucibles inlo the dessicator. Allow the sample6to completely oool and dry, preferably ovemight. (Coolillg oamples will ab!orb**m~** the dcosicator wiU alleviate thlt problem). 6.3 Weigbing I Caiculatioa 6.3.1 Weiib the dessicated crucible and aamplo , and record tho flllll weight to the neaz«tO.OOOl-vam. . 6. 3.2 Ca!culate% Ash as follows.. Ashed sample WI lnilial Sample Wt X J(}() 7 . 0 QUALITY <::Om'ROL 7.1 Ooc blanlc crucible should be run 

### through the entire ash process , tQ demonstrate blonk wciahtooosi5Ce<lcy. ·

. 7.2 Unsiab le weight r eadings may Indicate that further 

### ashina or dessicating m ay be needed.



### · · . . 

### C3·30


### V E S 01 6264

# • •
• ReflsionO April, 20 13 

## I R.c>u l neincrarion Semces, Inc. STANDARD OPERATING PROCEDURE SOP No .: FP-020-07 lnililll Da n:: 312&'07 

# ride: Coasolidation ofTEI F illaaprint

## los Revised: 12-2008 Date: 03 - 2841 

### Prepttcc! by: Aop!ovcd by: 1.0 PURPOSE 1bil proccdln is to 

### des<tibe lhe ineans by which 51Dlpled TEl wastes can be compositod for testing. 2 .0 APPUCATION This procedure a pp

lies to any samploable TEl Waste, which may be oomposilod based on food location requirements. 3 . 0 REFEREN CES

4 . 0 RIS Fins<tPrint Laboratory Procedures Sample Pilm - Section C - Wasle 

## Ana1Ysis Plan, Appa>dix C-4 "S ampling Pilm " ASSOCIATED SOP s All ofRIS' FinserJ>rint Laboratory Procedures Customtr Service SOP !Or Compositlng Olliddines S . O REAGENTS Nooe (See each Fingerprint Laboratory Procodure) 6.0 EQ UIPMENT Node (See esch Fingerpfi,u Laboratory Procedute) 7 . 0 PROCEDURE 7. 1 Prior to load receipt 7.1.1 LabOratory personnel will receive &om a Customer Service Tecbnloal repTOS<Otallve compositing recommeodatioas based on the Waste Product SUNey (WPS) information. 7. 1 .2 Typieal 

### information recelvcd from customer sCrvicclDcludes Pickup Number,**Shi~** Number, 

### inhOO!nd WPS N umber , WPS Waste Name, Compesiling Ca1eg0ry, and Primary Constituenla. This can be obtained from the AS-400 M

aintenance I Sampliog I TEl pickup SCs<ell.

C3-3 1


### VES016265

# • •

8.0 

# • J . 1 .3 Typical composile cateaori" include: A Noa Replated Solids B Noa Regulated Liquids C Plwmaceutical Drugs 0 Fuel B1encllnJ Oil Non fhtardous E H....-dous So l ids- non P·lisced F Paili.tS!udge 0 Organic Ac i d H Organic Basic I Halogenaled F1ammablc Uquids I Mixed Solvents • 

### Hip K Mixed Solvents • Lew BTU L Flammable Aeroools M Bmzeoc/Woter N Flammable Conosives 0 Solvents Aclds Halo&em P Cblo«i.oated Solvents/Oil 

### Q Cbemotbenlpy Debris 0011 RCRA R Flammable Cotrosive Solids Z On Not Composite SOP No. : FP-010.007 lnilial Daoe:**28-2007** Revision 0 April, 2013

7.1 . 4 Based on periodic review ofthe procedwe, composite categories may he added, n:cnoved, subdivided, altered, or renamed. 7 . 2 Following Receipt of !he Sbiprmnt 7 .2.1 01100100% visual in.lpoction iacompleted lhequantily of samples taken win be in accordance wilhRIS' Waste Analysis Pl4n(WAP ), Appendi.l C-4 • Samplln& Plan. 7 . 2. 2 The samples are received in tbelinguprint laboratory with appropriare Sample Control Recordo . 7 .2 .3 The labo,..tory personnel w!II COII\I)OSite in accordance with the recommendotions ofc:ustomer sezvice talcing into ' accocmt the physical chatacteristics ofthe sample (e.g., waste phase ) . 7.2.4 Labontlotypersonnel will composite samples &om up to four trucldoads for fmgeqniat analysis . 7 .3 The lab superviaor has the diaoreti on to detetmlne the appropriate ownber ofsamples (up to 9 samples) to composite into a sin&Je repmentative sample. 7 .4 A TEl Composite abeet 6JJed out by lhc aoalyst must aocompany eacb compo•ite eategOty for a perlicular pickup nwnber. Tbia abeet summarizes shipper/WPS/and CINs composited and w hether or not the sample pasaes or ia dlocrepaol 7.5 Fingerprint analysis will be conductcd in accordance with the WAP. 7 .6 The composite test ....Wts will be elllered into the r ecord associated with each WPS incl uded ill the composite . 7 .7 Oiscr<pancy 7.7 . I Discrepancles will be identified using lhe discrepancy programm ing . 7.7.2 JfanyWPS is discrepant, additiooal testing will be used to futtber isolate the diao<q>anoy. 7 .7 . 3 Rcpelitive teStiug ofprogressively smaller ssmple batobes ofa perlicular composite eategOty moy be oaed to isolate a d!S<:repaot WPS in a composite. If rhis csn't be done , eooh WPS in the inlended compoolte mwt be nm separately . 7 . 7 A Resolution ofthe discrepancy will be in accordan<e with the W AP. QUALITY CONTROL 8 . 1 Audit the SOP on a routine basis. 

### C3 -32


### V E S016266

# • • I I I ! 

## '

# I 

# I I 

# I 

# t • 

# • .. AppenduC-3 

# Sampling Plan

PUBLIC INFORMATION VERSION

C3-i Apil, 2013 Rc.isi ... 

### o

....hdeo-n'l• ..........



### VES016267

# • •
• Table of C ontents April, 2013 Revision 0

TAB L E 011 CONTENTS ····· - - ·- ..··---···-- - - -- ---·-·-··· - ---····- 1 TABLE 011 111GVJtES .. ....... _, ___________ ......--.,.. .. _:.. .____ ..... - .... -- ..-.11 SAMPLING PROCEDORES (OAC 314S.S4-13 (8)(3)]---- .. ·--·- · - .. -- .. .. - ... --- - .. - 1 1 . 0 8AMPUNOS1RA TEOIES.. ..... .. ...... .. .. . ........... .. .. .... ............. . ......... . ........ . . . ..... .. ..... , ................... .. ..... .. ... .. ..... 2 J. J Sampling StrtUegies[or Wa.ste Receiwdfrom Off.SUe. .... .. ...... .. .... .. .... .. ...... .. ...... .. ........ .. ............. .... .. 3 1.1.1 Samplio& Apposdl .. .. ... .... .. . .. .. .... ...... .. ........... .. ... .. .... ... .. .. .... .. . ......... ... .... . ... .. ............. .. .... _ ............... 3 1. 1.2 S•nple Type ond Nu- .: .. .. .... ..... .... .. ........... .......... .... ... .. ........... ... . ..... ... .. . - ......... .. ... ..... .. .. ..... ... .... 3 1. 2 Sampl i ng StraJq/ts[or Waste Gem!raJed 0,.-Sile... . .... ... .. .. . ..... ..... . ..... ...... ... . .... .. .. ... .... ... . : ......... .. . .... ( 1.2.1 Sampllns Approodl .... .. .. . .. . - . ..- ..... . .. ...- ..... . .. ... ... ...... ... .. . . - .. ....... . .. ... . .. . .. . ........ ... . .. ... .. . ... - .. . 

## s 1 .2.1 Sample Type ond Numb« .. .. ... .. .. .... .... .. . ..... . .. ........ ........ .. .. .. ... . .. .... .. .. .. . ... .... .. .. .......... . .... . .. . .. . .... .. . ............ 

### s 2 .0 5AMPLINGilQUIPMEI<f .. ....... ......... . ... .... .............. .. .. .... .. ... .... - . .... .... - ... .. ...... .. .. .... .. ...... .... .. .. ..... .. - .. 7 2 . 1 Sampling Eqoipmerrt 

### for**Wast~** R.c 1 iwd from Off-Site .... ..: ........... .. .. ..... . .. ... .... .. .. ... .............. . .. .. .. . .... 7 2 . 2 Sampling Eqtdpmemfor Wam GeneraJed On .S

ile. ...... .... . .... .... .. .... ........ .... .. .......... ......... . .... .... .... ..... 7 3. 0 MAINTAININO ANDDI!CONTAMINA TION Of'SAMPUNG EQUIPMENT ......... .... .... .. .............. .. ......................? J

. I Maintalnlllgtwl Dec01114mtnati'!'J o[Sampling Equipm<lll Used for WDSU? R eceiwdfrom Off-Sile. 8, 1 . 2 MainUIInlllg andDecan1411tlnation ofSampling Equipment Used for Wane Generated On - Sile ... .... 8 4.0 SAMPLE PResERVATION, HOUl!NO TlM . ES ANDCoNTAIN ERS ......... ... ... .... .... : ....... . .. ........ ..... , . . ____ , .•9 4.1 Sample PreservatiiJn, Holding Times and CcHlalnersfor Wastes Received from Ojf.site.. ...... .. ..: .. ... 9**2** Sample Preserwltion, Hoklillg Times and Contai•ersfor Wasre Generated On-Site ...... .. ......... .. ... .. .9. S.O SAMPUNOQUAI.ITY ASSURANCE ANDQuALIIY Coi<TttOLPROCEDUR.ES .. .. . .. ..... . ............. .... .. ..... .. ...... . IO S

.l Standard Operating Procedures.. , .... . . . .. .. ... .. .... .. , .. .......- . : .. ....... .... .... . .. .......... . .. ... .. . .. ........ .... ... .. .. . ./2 S

. l . l Standord Operating Procedii!<S for Wute Reoc!V<d from Off>S; t e .. .. .. .. .... . ...... .. .. ... ..... .... .......... .. ...... .. 12 S.l .2 &mdiRI Opcraling J>roccdurc$ for**Wut~** Oencralod On-Site . .. .. .... .... .......... .. ..... .. ...... .. .... .. .. .. .... . .. ...l4 S

. 2 Sample resting .... ...... . .... . .... . .. ... . ......... ... .... .. .. ... .. ....... . ........ .... .... ... .... . .... .. ..... .. .... ... .. ......... . ...... .. .. .. .. . IS 5

. 2.1 Samplo Testing Proocdul'CS for l\luteReceiV<d from0ft' -site ............. ... .... .... . ..... ...... .. ... .. ... .. .... ... .. . .... .. .. .. ... l 6 S.2.2 Sample T<!ting PteecdUI'CS fot .On-sitc R co;iduals... .. ... ... ....... .. .. . .. .. .. . ...... .... ........ .. ........ ....... . ....- . ... .... .... 16 S

. 3 r rainingfor Personnd takingSilmp/es . ...... .... ... . .. .......... .... ...... .. .. . ..... ....... . .. ....... . .. .. . ... . .. .. ........ .. . .... /7 6.0 HEAL Til ANOSAfllTY PROTOCOLS : . . .. .. ... .. .. . .., _ ... .. .. .. . . .. ...... ... . ...... .. .... . .**~** . . .. .. . . . .. .... ........... . .. ..... - ..... 17 

# Table of F igures . TABLE 1· SAMPLING EQUIPMENT 

### FOR PAJ!. TICULAR WASTE**TYP.J!S~** _ ...... - ....... ..- .-19 TABL'£ 1·SAI\ IPLE CONTAINERS, PRESERVAT IVES AND HOLI>ING TIMES ..- .. · --- 10 TABLE 3 . R.J!SJDUAL ANALYTICAl. PARAMETERS AND METHO D S SUMMAR.Y- ... 

# · · --- --11

C3-ii 

### V ES01 6 2 68

# • • Sampling Procedures IOAC 3745-54-13 (8)(3) ] April, 2013 IUMsiooO



### Ross Incineration Services, Inc. (RIS) m:eives a variety of wastes from off-site

.generators in 

### bulk 

### (receptacles housing 110 gallons or more, e.g., 

### tank lnlclcs, 

### to_tes, and 

### intermediate bulk containers - IBCs) 

### and noo-bullc containers (receptacles housing less than 

### II0 

### gallons, e.g., drums, pails, buckets). Additionally, RlS manages 

### WBSte which 

### it. • generates onsite. These 

### two types of wastes (off•site generated and on-site generated) vary widely in 

### chemical and physicai cbaractcristics. This pian 

### addresses sampling strategies, . melh.ods, equipment, QA/QC & 

### Health and Safety ' procedures 

### f01: both off-site and oo-site generated 

### waste.

. Analytical testing may 

### be petfunued on these wastes 

### due to regulatory requirements 

### associaltid wilh. waste treatment, the 

### nature of 

### these wastes, and the 

### residuals they 

### produce. RIS uses representative sampling and corresponding Iaboratory analysis to aid in the verification and determination of the physical and chemical characteri. stlcs of hazardous waste. Specific sampling methods used to obtain representative samples are**depende ~**  

### on the type 

### of contaminants and nature of waste. This sampling p ian presents the foHowing • information. 

# • Section LO Section 2.0 Section 3.0 Section 4.0 Section 5.0 Section6.0 SarnpJin& Strategies Sampling Equipment Maintaining and Decontamination ofSampling Equipment Sampie Preservation, Holding Times lind Containers Sampling Quality Assurance 

### I QUality Control Procedures Heallh. and Safety Procedures Representative sampies are expected to exhibit the properties of the entire sample population, therefore, enable RIS to 

### aiW.n 

### its primary 

### sampling objective which is to 

### collect . accurate and precise samples 

### that can 

### be measured to 

### confirm the chemical properties of the 

### waste. Since the sampies are sufficiently aocurate and precise, they will therefore be considered reliable estimates ofthe 

### chemical properties of.the waste. RJS**g~ally** 

### compietes confinnatory fingerprint analysis on representative samples 

# of waste received from 

### off-site faciiities at the on-site laboratory, however, outside 

### anal_ytical

C3-1 

### VE S0 1 6269

# •
•
• April, 20 1 3 ReviliOtl 0 

### laboratories may be 

### ublized at the disaetion of facility management with**inp~** 

### from the laboratory 

### sta£1: Additionally, RIS 

### ·typically submits representative samples of on-site generated treatment residues intended for additional treatment and/or disposal to 

### designated outside analytical laboratories. The ·primary objective of any waste sampling effort is 

### to 

### • obtain information that 

### can be 

### used to evaluale a waste. 

### Furthermore, the 

### specific sampling, anal ytical and dala objective 

### is to appropriately classifY and treat 

### hazardous waste within regulalory parameters 

### promulgsted by U . S. and 

### Ohio EPA In 

### the event 

### that the generator conduas sampling and analysis, 

### RIS' WPS specifies the use of sound sampling and analytical procedures . In 

### general, the sampling methods 

### are those represented herein and 

### are based on the techniques listed in**~e** 

### following documents, 

### or an equivalent: I. 

### Samples 

### and Sampling Procedures for Hazardous Waste Streams, EPA 

### 60012· 80-18. 

### 2. 40 CPR 261 Appendix 1/0AC 

### 3745 - 51·20 Appendix I. 

### 3 . Test Methods for Evaluating Solid Wastes SW 

### 846/3rd edition. P

rocedures 

### or equipment may be 

### updated or 

## reviSed as necessary when new equipment or procedures are available. Appropri ale safety and 

### personal protection devices and procedures, 

### as identified in 

### the Handling Instructions (yl 

### AP Exhibit F), 

### w ill be 

### followed at 

### all times. 

### 1.0 Sampling Strategies The samp ling strategy used to 

### assure representative sampling of waste is 

### discussed in the following paragraphs. Exceptions to 

### the sampling methods, kx:ations, and/or equipment described herein may occur 

### at times; however, dcvialions from these methods will be noted in 

### the operating record. The methods and 

### equipment used for sampling the waste will vary with the form and consistency of the waste to be 

### sampled and 

### will be appropriately based on physical and chemical characteristics of the waste, 

### the sampling method, and other waste specific factors. Sampling strategies for off-site generated wastes are specified in Section 1 .1 of !his sampling plan while sampling strategies for on-site generated ·residuals are specified in Section 1. 2 o f this sampling plan. These .sections identifY the sampliog approach and the sampl ing type 

### and number used to 

### obtain representalive samples of waste for analysis.



# . . C3-2 

### V ES01 6270

# •
• April, 2013

. RevisiooO Samples collectod for fiogerprin1 aDalysis, metals analysis, PCB analysis, and residuls analysis are collected in 

### kCW!<Ianc<o with lhe follOWing samplillg stntegies. 1.1 Sampling Strategies for Wastc Received 'from Off-site

. Typical hazardous and 

### 11011-hazardoiu · waste 

### received at . RIS include: halogenated and 

### non· ·halogenated spen1 

### solvents, 

## pafut wastes, off-specification oomniercial c.bOinical products, 

### conswiter products, · spill**~** and wastes 

### 'generated by the**fo~ing** industries: 

### paint and coatings. organic 

### and inOtpnic 

### chemical, adhesive, pesticide, petroleum refining. an d the ink formulation industries. This list is not comprebeDsive, but represents most categories of waste baodled at 

### RIS. l. l.l Sarilp!ingApproach .

## S:~ples will be. collected for fillgerprint analysis, metals aDalysis, 

## J>CB an&tyais. A3 such, a. 

# . . 

## . prescribed methQd for obtaining 

### rcprcsentatlve saniples to ensure valid 

### analyaes is essential. 'fh:is 

### saJilllling plan allows for 48111pling 

### in a prescribed llWlKr to assure representative sampling. RIS 1ISeS simple random samplin;, 

### a type ofprobability sampling, 

### as a sampling suategy for off-&it e genetated wastes. Simple 

### random samplin ' 

### relies on mathematical and statistical theories to allow for 

### an ev&!uation of the effectiveness of samplin; procedllres. Simple random sampling ei>ables RIS 

### to treat 

### a 

### variecy of 

### cqntainer**~** and . 

### waste types the same. No P,.eference 

### · is to 

## be placed on 

### one container size or 

### shape versus another. J;11o preference is to be p l aced on one waste 

### !Y_PC over . another . Rather, 

### contain<:n are to be chosen randolilly. For 'example, cootainas are to be off-loaded and 

### randomly arranged ioto rows, and then every ninth container 

### will be sample<!. regardless of waste type or container type. Additionally, samples will be talccn 

### unifoimly without 

### regard 1o the aDalyscs to be**pelf~** Generally, 

### the sampler will DOt evco know what analyaes are to be perfonned. Rather, tlie . lab will determine . 

### which analyaes needs to be conducted. It is RIS' 

### inteat 

### thAt these represemative samples 

### will exhibit tbe average**~es** of the whole waste population. TecbniqUes described to sample these wastes were developed 

### in accordance 

### witb lhe EP .... 

### test metbods for evaluating sOlid waste (SW-346) Volume II; Field Manual, PbysicaJIChemical methods, "S ampling Plan" (Chapter 9) . 

## and oth<r documents rcfcrcuced · in 

### Section 1.0. · 

### . I . 1 .2 Sample 

### Type and 

### Nwnber

. RIS classifies waste received from off - site facilities according to Section**~,** "Additional Requireneots for.Waste Generated Off-Site." With**th~** eoteeptioo of"V" class wastes (Refer to Section C-2e 

### OXaXifi)), these wastes arc sampled 

### and fingerprint aoalyaes are performed to confirm tbe profiled panunetm. Gnb samples are 

### ltllnSI>Orted to the fingerprint laboratory and designated lab penoond 

### will typically composite up to nine (9) grab samples (the . fingerprint Lab Supervisor/Lab Manager has 

### the diacrction to ddennine tbe eppropriate number 

### of samples to be composited) . to obtain 

### a single composiie • . sample, which 1$ representative o. f tbe entire sample population. Sample quantity and fiequency are coUected C:l-,3 

### V ES01 6271**Apri l013**  Rovi>ioc> 0



### • in aa:onlance 

### wilh 

### Section C-2d Frequency of AnalysiS of this 

### W AP . RlS conducts 

# •
• fingerprint analysis to characterize incoming waste streams and to determine whether tbc 

### incoming waste received by 

### lhe facility confonns to 

### tbe 

### WPS. The 

### fingerprint analysis is 

### typically conducted at RIS' on:sitc fingerprint laboratory, however, outside analytical laboratories may be utilized at the discretion of facility management with input from the laboratory_ 

### staff .

. 1.2 Sampling Strategies for Waste Generated On-Site Residual$ routinely gencruted b y R1S that require 

### sampling and 

### analysis include inciiterator ash, 

### filter cake 

### {i.e., de-watered fly ash sludge) 

### and scrubber water .**In~** 

### ash is produced 

### from the incineration of wastes in RIS' kiln and main 

### chamber. Incinerator 

### ash is a non-<:Ornbustiblc material generated as a result 

### of baurdous waste 

### being burned 

### in the RlS incineration system. It 

### is a soil or glass like material that is 

### quenched upon removal from the 

### system and conveyed to containers for de-watering !hen transportation off-site. Filter cake, a solid material, ·is produced from de-watering fly 

### ash. · Fly ash is a noncombustible**parti~ate** 

### material 

### contained in incinerator off-gases. The small fly ash 

### particle 

### i5 removed from 

### the incinerator off-gases by 

### RIS' air· 

### pollution control system . Scrubber water is used in lhe air 

### pollution control system to clean and 

### cool incinerator off-gases. II contains small amounts of suspended fly 

### ash that were not removed through the solids 

### set_tiing process. Spent 

### scrubber water is removed from the 

### closed loop system 

# when the 

## sati cont ent ofthe water becomes" 

### elevated. 

### It is 

### necess1I)' to 

### pc<form rqx-csentacive analyses on the residual$ 

### generated by RlS to 

### determine if the 

### wastes meet treatment 

### standsrds established by ihe land disposal restriction regulations. ROutine analyses of lhcse 

### residuals 

### wtll be 

### performed; therefore, a prescribed 

### method for obtaining .representative samples to ensure consistent analyses is essential. The regulations pertaining to the management of hazardous waste require !hat represenllllivc samples of waste, which exhibit avCI'llgc properties of the 

### whole waste, be collected . This · sampling plan allows for sampling in a prescribed manner to assure representative sampling

· of RIS generated residuals.

C3-4 

### VES016272

# • •
l e I 0 

# • April, 2013 Revision 0 

### Composilin& ofsamples involves combining a number of 

### grab samples from the same ·waste· container. Since compoSiting yields 8 

### more repreSentative (and consequently more 

### ' 

# . accurate) sample, i t is employed throughout this sampling plan. 1 .2.1 

### Sampling Approach RlS lUeS 

### systematic random sampling, 8 

### type of probability sampling. as a sampling strategy for on-site gericnted 

### residuals. Systematic random sampling 

### has one significant . advantage, it provides an 

### ilicrea.se in sampling precision 

### since the samples arc 

### distributed more evenly over the population. Systema tic random sampling also relies on madiematical and 

### statistical theories to allow for an evaluation ofthe effectiveness ofsampling 

### procedures. The 

### solids residual sampling 

### program employs 

## e: combination ofsystematic random sampling and judgmental sampling to achieve the accuracy and appropriate precision required of the analyses 

### of the chemical constituents. This sampling strategy will 

### assure that**~tative** 

### samples of ash and filtu cake are collected. In 

### random sampling, every unit in the population has a theoretically equal chance of being sampled and measured. Techniques described to sample these residuals

### w~ developed in accordance with the EPA

### te~t methods for evaluating solid waste (SW-846) Volume II: 

### Field Manual, P hysicaVChemical methods, "Sampling Plan" (Chapter 9). 1.2.2 

### SampJe'I)ye and Number · _ RlS will 

### conduct incinerator 

### ash sampling q\llrtedy for 8 

### comprehalsive list of Land Disposal Restriction . ("LDR") parameters, wruch have been identified in Table 3 . ·Residuals Analytical Panhcters and Methods Summary. Additionally, RlS will conduct a limited monthly analytical evaluation of ash residuals for target constituents more likely to b . e found in 

### the residual ash based on typical 

### feed streams . (See the Waste Analysis Plan Section C. 

### 3d, Additional Requirements for Treatment Facilities) If the quarterly analytical results indicate that 

## LOR**~etm** h a ve been met, 

## RIS will ship the 

### residual ash off-site for d isposal. In the event that 

### an incinerator ash quarterly sampling event provides data that 

### does ' not meet Land Disposal Restriction parameters, RlS Wlll n>-sample and**~analyze** 

### the residual utilizing the same sampling plan and analytical method. The ro-samplc is intended to validate the existing data 

### and remove any concern about cll'Oneous analysis (e .g. ; due to external . contamination). If the second incinerator ash



### C3-S 

# I



# . I

VES01627 3

# •
•
• April , Ull3 lttvdiooO 

### sample**re~** 

### with data outside LOR parameters, RIS will r e-package the residual for re- . processing on-site or transport the residual olf·site · for additional asseSsment at another facility. Following an unsu<X:eSSful quarte rl y 

## sanlpling event, residuals will 

### be shipped off.. site for additional assessment until a second residual container can be chosen and sampled . A

d ditionally, RJS will add the failed LOR parameter to the next monthly sampling event's**~exduding** 

### dioxins/furans) abbreviated list ofconstituents. · If the m onthly analytical results indica te that LDR parameters have 

### been met, RJS will s hip the residual ash off -site for disposal . 

### In 

### the event that a monthly sampling event provides data 

### that does not meet Land Disposal Restriction. parameters, RIS will re-sample · and 

### re-analyze the residual container utllizing the same sampling plan and 

### analytical method. The**~samp e**  

### is intended to validate the ex i stence of the data and rem ove any concern about erroneous analytii:al data due to external contamination. I f the second sample is returned with data outside LOR parameters, RIS will either re-process the original residual or lrdnspurt the residual off-site for additional assessment a t anotli er facility. Following an unsuccessful . monthly sampling event, a daily residuals ' sampling event will continue for a maximum of three days and 

### residuals will 

### c<>ntioue to be 

### shipped off-site for additional assessment until at least one residual sampling event provides analytical results within 

### J.DR parameters . Samples arc taken as indicated in Section 1 . 1.2 and sampling takes into account the variability of the wastes 

### and treatment process. Additional analysis is 

### performed in the event that there is a change in 

### the composition of the waste or the treatment 

### process. Deviations 

### from standard sampling methods wiU be 

### noted in the facilitY operating record. . · RIS will conduct filter cake sampling quarterly for a comprehensive list of LOR parameters which have boen identified in Table 3 - Residual Analytical Parameters and Methods Swnmary . 

### If the quarterly analytical results indicate that LOR parameters have

. been met, RIS will ship 

### the residual off-site for disposal. In 

### the event that . the 

### analytical results indicate that LOR parameters have not been 

### met, RIS may further treat the residual to meet treatment standards or seek an alternate off-site treatment technology . RIS will conduct scrubber water sampling biannuall y for a comprehensive list of L

OR parameters which have boen identified in Table 3 -Residual Analytical Parameters and Methods Sllll11lllli'Y. 

### If the analytical results indicate that LOR parameter$ have been met,

C3 -6 

### V ES01 6274

# • • 

# • 

# • lqlril, 2013 Revisioo 0 

### RIS wiU then ship the 

### scrubber water off-site for d isposal. Conversely, should the analytical teSU)ts 

### indlca!e that LOR parameters have not been llld, 

### RIS may further treat the residual.to meet treatment standards or seek an off-slte treatment technology. Although RIS residuals sampling can occur at any time within the · quarter, RIS typically samples before the 61\h week of the quarter. Discrepancies from 

### the procedures berein will be noted 

### in the operating 

### reconL 2.0 Sampling Eqalpment 2.1 Sampling**Equlpm~t** 

### for Waste Received from Off-Site Samples are collected from randomly identified containers using an appropriate piece ofequipment.. Although procediues and equipment may be updated 10 reflect new equipment and procedures as new tecintology is employed, Table I entitled "Sampling Equipment for Particular Waste Types" delineates the sampling devices and circumstances under which the equipment may be 

### used . Sampling equipment 

### wiU be chosen based on the physical and

. chemica l parameters of the sample. 2.2 Sampling Equipment for Waste Generated On-Site Samples are collected from randomly identified containers using an appropriate piece ofequipment Although procedures and equipment may be 

### updated 

### 10 reflect new equipQleot and. procedures as new techno logy is 

### employed, Table I entitled ·"Sampling Equipmen t for.

. Particular Waste Types" 

### delineates the sampling devices and circumstances under which the equip!llent may be used . 

### Sampling equipment will be 

### chosen based on the physical and 

### chemical parameters of 

### the sample. 3.0 Maintaining and Decontamination of SampliDg Equipment RIS inspects its sampling equipment before sampling io ensure. proper operation, Addit ic:>nally, gross chemical contamination is removed from the equipment before reuse . Cleaning 

# and decontamination

### procedur~:s for sampling equipment begin 

### with removal of all loose · debris from the equipment, fo llowed by a cleaning ·process which corresponds with the

C3 ·7 

### VES016275

# •
• 

# • sample purpose. For example, RIS dcoontaminates equipment used to take 

### fingerprini samples. With

### apj>ropri~tely less stringent standards 

### than 

### samples intended for VOC analysis . Additionally, RIS 

## useS disposBble samPling equipment whooever possible to 

### avoid cross-. contamination. Should equipment maintenanco 

### be required, 

### RIS will generally follow the equipment manufactum's specifications. 3.1 Maintaining and Decontamination of Sampling Equipment Used.forWaste Received from Off -Site 

### 'RlS inspects its 

### sampling 

### equipment before sampling to ensure proper 

### operation.

### S~ce R1S typically uses disposable sampli.pg equipment, and

### sin~ R1S samples waste 

### received. from 

### off·sitc facilities for 

### fingerprint analysis, equipmealt decontamination is

### I~ essential.. 

### Therefore, cleaning 

### and decontamination is generally limited to removal of all 

## . . 

### loose debris from the samplliig equipment. RlS 

### will either 

### use disposable sampling equipment 

### when sampling for metals and/or PCB analysis, 

### and TCLP**~alysis;** 

### or RlS 

### will appropriate ly decontaminate reusable sampling equipment 

### used for sampling for metals ' analysis, 

### PCBs analysis, and TCLP analysis. 3.2 Maintaining and Deoontamillation ofSampling Equjpment Used for Waste Generated On.Site 

### Although disposable sampling equipment is . 

### used**~henever** 

### possible,

. decontamination of field**eq~pment** is 

### essential to avoid 

### . cross-Contamination of . residual

. samples. The following list 

### of equipment is typically**~eeded** 

### to adequately decontaminate sampling equipment: wire 

### or nylon brush, 

### decontamination reagents (de-ionized wllter; methyl alcohol, dilute hydrochloric acid), tap 

### water, laboratory .grooe squirt 

### bottles, aluminum foil, safety 

### glasses, disposable gloves, 

### and containers to store used 

### rinseate . Di:contamination**~f** 

### sampling equipment 

### will typically take place in the fingsprint laboratory. All waste is accumulated as laboratorY waste and managed aoo:irding .

### t o applicable waste 

### management practices . Sampling equipment is 

### dcoontaminilted. by lint 

### remoVing all gross residual**~** 

### from**~e** 

### equipment 

# lisin8 the 

### nylon or 

# wue brush. Then, the equipment is rinSed with d009ntamination**reagen~** 

### in the 

### following order. tap water , de· ionized water, dilute hydrocbloric acid, 

### de-ionized water, methyl alcohol, de-ionized water. Finally, tbe 

### decontaminated eqUipment is 

### air dried and wrapped 

### in aluminum foil f or field liSe •

C3·8 

### V E S0 1 6276April. 2013 Re\isioaO

• · 4 . 0 Sample Pr eservation, Holding Times and ContaiDen 

# • • Samples colleCted for fingerprint analysis, metals analysis, PCB analysis, and 

### residuals analysis are collected in accordance With this Sam pling Plan 

### and are proper ly**~ed** 

### and stored in accordance with applicable SW -846 Methods. Appropriate containers, holding times 

### and preserva tives are typically provided by the laboratory 

### in accordance with SW-846 procedures (or the equivalent) and are found 

### in Talile 2 • Sample Containers, Preservatives and Holding Times. 4.1 · Sam pl e P reservation, Holdin g Times and Containers for W astes Received 

### from Off. Site General ly, sample preservation 

### is not necessary (or not applicable due to the sample malrix) since sample analysis typically occurs within 72 hours. Samples are retained in t b e · fingerp ri

nt labora t ozy sample cabinets in accordance with la))ora!Ory procedures (refer to WAP Appendix C-3, Labo ratory Procedures) . For fingerprint laboratOrY analysis, RlS · typically uses eight (8) 0 unce glass sample containers with metal lids lined with an inert ·

material. Typically, a commercial (outside) laboratozy 

### will complete metals and PCB analysis for waste received from o ff-s ite facilities. Aliquots of the composited sample are placed in sample containers provided by the outside l aboratory before sample collection. Designated fin gerprint lab personnel 

### will relrieve 

### the sample containers, identify the amount of sample required for anal ysis, obtain a chain-o f -custody form and fi ll the appropriate . sample conta iner. After . taking the sample, it w ill 

### be . prepared fo r shipment off-site by: sealing the sample container and completing the cbain-o f·custody form .

. 4.2 Sample Preservation, Holding Times and Containers for Waste Generated On-Site Typically, a· commercial (outside) l ab will analyze RIS' residual samples. The · · commercial lab will 

### send containers (and presen-atives), including a trip b lank to 

### be 

### used for collecting samples. These containers will be received before sample oollection. " The individual assigned to obtain the field samples 

### will retrieve these sample cOntainers, identify lbe amount of sample 

### required for the analysis, obtain a samp l e collection record and cbain**of~ustody** form then p roceed to the fiel d .



### C3 · 9 VES016277

# •
• 

# • April, 2013 Revision 0 

### After taking 'the sample, the 

### person taking the 

### sample will identify the necessary preservative · (s) 

### for

### ~ch sample, and proceed with preserVing the 

### sample (s) 

### before shipment to the commerciil laboratory. Table 

### 2 • Sample Containers, Preservatives and Holding Times 

### contains a lise of sample preservation 

### and containerization requirements . 

### RIS may change 

### laboratories (and therefore 'possib ly containers) without modifying 

### this document, as 

### l ong 

### as the 

### change is to 

### an equi v alent labora tory or one with similar capabilities and RJS has 

### performed 

### an audit ofsaid laboratory. 

### Once the sample has 

### been collected by the designated operations 

### personnel, presccved, and prepared 

### for transportation to the outside laboratory, the sample and cbain-of-<:UStody form are forwarded to the fingerprint laboratory . S.O Sampllna Quality 

### Assuraace and Quallly 

### Control Procedures Quality assurance is the process for ensuring 

### that all data and 

### the decisions based on these data 

### are technically sound, statistically valid, and properly documented. Quality control procedures employed to document the accuracy and precision ofsampling include : I. The 

### existence of a sampling plan to comnlwtlcate sampling methods, 2. Laboratory protocO ls to assure uniformity of

### analytical methods (Refer to WAP Appendix C-3, Laboratory Procedures), 3 . Standard Oper:ating 

### Procedures to assure the uniformity of sampling methods, 4. Sample testing documentation including a chain-of-custody, and S. 

### Training. 

### Additionally, a trip b lank can be used 

### to detect contamination or cross-oontanlination during handling and transportation. I t may accompany sample containers to and 

### from the 

### field . The 

### blank is to be used for volatile organic 

### analysis ("VOA''), 

### ana is 

### received already prepared from the commercial lab. The trip blank remains unopened In the field and 

### throughout saniple acquisition. It 

### contains laboratory pure water (distilled, de-ionized, or reagent grade water) that is 

### free of onnlanlinants. As previously indicated, RJS uses trip 

### blanks when Collecting quarterly and monthly 

### residuals samples from waste generated a t

. RfS .



### C3-l0 

### VES016278

# •

•

•

' 

### i 

# l 

# , . ApriU013 R.evitioa 0 

### Since RIS routinely ships samples to outside commercial laboratories; shipment of

. samples to these lalioi"atories will require protier labeling and s hipping 

## papers to remain in

compliance with USDOT regulations. 

### Packages properly prepared by personnel 

### trained in DOT 

### regulation are shipped to their destination v ia standard overnight carriers or comparable 

### couriers.**~reservation** 

### of wnples sent to the outside la boratory 

### is pcrfotmed before shipment. RIS fingerprint lab personnel perform daily QA/QC tests to assure 

### accuracy of the test performed and proper functioning of all lab instrumentation. Typically, blank, duplicate, or split samples . will not be collected for fingerprint sam ples . However, QA/QC tests 

### are conducted in acco!Oance with standard operating procedures 

### main tained 

### at the on- site fingerprint lab. The Fingerprint Lab Supervisor acts 

### as the QA/QC coordinator and is responsible for assuring the procedures 

### are maintained. All fingerprint lab analysts are 

### rained to conduct all 

### necessary fingerprint lab analyses. The on-site fingerprint lab is organized to facilitate the efficient gathering of data neCessary to confirm that the physical 

### and chemical 

### properties of the waste received at 

### the faci lity 

### are consistent with the information provided on . the WPS. The fiogerprini laboratory is stocked 

## Wi1h all of the eqllipment and 

### supplies necessary to pefform the fingerprint analysis described in 

### this 

### W AP• The fingerprint laboratory is equipped with a hood, 

### stainless steel sink; 

### safety shower with eyewash and 

### floor moun ted cabinets with counter tops . Minimally, the fingerprint lab 

### is stockCd with 

### an analytical bal ance , 

### flash point 

### apparatus, selective ion/pH 

### meters , electrod es, mufile furnace, thcnnometers, safety cabinets (sample storage), first aid kits, bomb calorimeters, various reagents and solvents, viscometer and miscellaneous 

### glassware. Appropriate Quality ConlroVQuality 

### Assurance ("QC/QA")

. data is gathered according 

### t o appl i cable laboratory operating procedures . The RJS fingerprint laboratory . supervisor 

### is responsible for self-audit o f the laboratory . The laboratory self-audit is a 

### m ulti -phase process. Specifically, tbe Fingerprint lab supervisor/ lab 

### manager visually evaluates 

### the technicians' technique 

### at least quarterly. Additionally, l aboratory personnel take 

### written tests based on current lab procedures. Quarterly performance evaluation samples 

### are submitted to the laboratory for analysis .



### .Finally, an 

### annual

## evaluatio~ of operating

## proc~ occurs and SOP," are updated as · necessary.

C3 · 11 VES016279

# • •

• •**Apri~** 2013 1\e>isi<>c 0 

### Laboratory personnel follow written standard operating prooedures , which were established to provide instructions on conducting the fingeqnint analysis . The 

### standard operating procedures (SOPs) typically include the purpose, scope and application, reference methods, tbc 

### associated SOPs, equipment**fl!C~Ulmnenl$,** 

### reagents to be used, a detailed 

### s ystematic procedure, 

### quality control procedures, and 

### discrcpaney detamination. The SOPs

. used 

### by the on-site fingerprint lab can be 

### found in Appendix C-2 of this 

### WAP. Records of 

### , sampling and 

### analytical results are maintained in the Operating Record. RIS has 

### an**environin~** 

### auditing process to · assess the adequacy of vendors, including audits of c:ommercial laboratories. This auditing pcocess · evaluates several pertinent factors associated with potential vendors including QUality**Assu.ranc~** 

### programs and 

### Quality Control procedures. These audits follow Sllindard Operating 

### Procedures ("SOPs") 

### as established by the 

### Fingetprint Lab 

### SupcrvisorJLab Manager and/or QA/QC Supervisor, and tbc SOPs for cootraet lab 

### auditing arc maintained at the 

### on-site 

### finecrprint lab. Procedures fo r documenting deviations from the sampling 

### QA/QC procedures are also specified in the 

### SOPs. RIS' off-site contract laboratory (ies) adhere to 

### Quality Assurance Plans, inC?rporaled herein 

### by reference . S.l Standard 

### Operating 

### Procedlns SOPs for off-site genetatcd wastes arc specified in Section S . l.l of this 58U1pling 

### p l

an while . SOPs for on-site generated residuals 

# are specified 

### in Section S.l.2 of this 

### sampling plan. 

### S .l.l Standard Operating 

### Procedures for Waste Received from Off-Site As previously indicated, RIS receives a variety of wastes from**off~site** 

### generators in 

### bulle and non-bulk containers. Bulk sample**collectio~** 

### methnds for off-site generated wastes are specified in 

### Sectioo S.l.l.l of this 

### sampling plan, and non· bulk sample collection 

### metboch for off-sit e generated residuals aro speafied in Section 5.1.1.2 of this 58U1pling 

### plan. .

C3·12 

### VES016280

# • •


# •

• S .1 .1 .1 Bulk Sample Collection Methods } April,2013 RevisiO.O



### · Samples for fingennint, metals, PCB and other 

### analyses arc ooUoc:tcd from 

### randomly identified IBCs , tanker trucks, 

### and bulk 

### solid loada. .Representative sampl es collected from 

### bulk tiquid 

### and solid loads 

### arc colloc:tcd in 

### accordance with lhe procedures 

### ideniiticd herein. Safety · <!jUipmeot, IDIIerial 

## manageoiem procedures. and other 

## spCciat inslnictlons for each specific waste

'are 

### ideotificd 

# oo the.R811dling InSiroctions 

### for each waste. Tuku**~pllaa .**  

### The primary 

### purpose for taoker sampling Is 

### to jlrovide 

### a represeotative sample to the fingerprint 

### lab for analysiS, The 

### sampter slowly 

### IDserts a COUW ASA sampling device into 

### the tanker from the 

### top manhole 811d allows the 

### liquid to 

## tili the tube . As 

### lhe COLiwASA is 1VitbdraWD from the 

### ianicr, 

### the outside of the tube is wiped down using 

### an absorbent 

### taoker. pad 1'hc:n, 

### thC sampler will empty the 

### material into the 

### sample jar and seal the jar. 

### . The · sampler will 

### place labels (including shipper 

### #, 

### WPS # 

### 8lld Taoker #) on the . 

### sample jar 811d**compl~** 

### applicable sample testing lnfOJmation. The samples will be 1raD$pOI1Cd 

### to the fingerprint lab and the fingerprint

· lab will notify the 

### operator wheq 

### analysis 

### Is complete. &lk 

### .So&d 

### Salllplln&. The primary pu!p06C 

### of sampling roll-off**COI:IIaine.n~** 

### and/or dump trailers is 

### to provide 

### a representative 

### sample 10 the linguprint lab 

### for aDatysls. 

### If 

### lhe conlain« 

### iKJuses a variety 

### of lllAterials, 

### a sufliciemrepresemation of what 

### is in the-<:onlaine< lllliSt be obtained. 

### t.Jtbougb the 

### samplermakes an effort to sample from 

### a variety 

### of loc'atioliS (typicall.y using a grid 

### •Y'I=) within the 

### container , the primary 

### importan ce is 

### to obtain a 

### repr=otati"" sample. When 

### · iampling homogeMOUS 

### materials, the sampler will 

### fill an 

## eiibt ounce sample container



### _ ftom at least 

### one location. HoWC'Iet , the number of locatioos and tbeir 

### relative position will vary based 

### on the 

### cootent of the 

### container to be 

### sampled. For instance, if 

### the OODteots 

### in the 

### colllainer are 70'/o 

### dirt. 20'/o 

### wood, and 

### I

### 0% plastic, then the 

### sample will be 

### approximately 70% dirt, 

### 20% wood, and I

### 0% plastic . In this 

### wu;nple. the sampler would ' take from 

### three locations, with 70% of the 

### 8-ounc:e jar fuD 

### of dirt, ·

### 20% o( the 8-o)IDCC jar full 

### of wood and 10% of the 8-ounce jar full 

### of plastic. After ta.klng the 

### sample, the 

### sampler will place labels (inoludi.ng 

### shipper#, WPS #and CIN) 

### oa .the sample jar 

### and complete applicable sample testing 

### information. The sample 

### wili be llaDSpOrted 

### to the fulgerprint Jab. 

### S .1.1.2 Non- Bulk Sample Collection Methods The primary 

### purpose of sampling containers is 

### to provide a representative sample . of the 1Vaste**~to** the fingerprint lab 

### for analysis. If 

### sampling drums, pallelizled-materials, 

### gaylord& or wrangler&, the 

### sampler will open the 

### container in lhe 

### sample trailer. 

### If the l!laterial js 

### granular . 

### or !Oil-like, the 

### sampler will scoop 

### enough ofthe 

### material to fill tbe


### C3-13 

### VES016281

# •

• •


# • April. 2013 Revbion 0 

### sampl e jar. · I f t

he materi a l is 

### hard, the sampler will chip eno u gh of the material to fill the sample jar. (f the conl4iner houses a variety o f materials a good representation must be obtained, as desctibed in**~tion** 

### 5 . 1.1.1. If t he material is a li quid or semi-solid, the sampler will use a sampling tube to draw the sample, by s lowly lowering the tube into the container. Once the tube is 

### fuJI, the samp ler will use their 

### thumb to seal the tube. The tube i s then rem oved and 

### the sample jar 

### is 

### filled. Other tools 

### used for sampling are l isted on Table 2 ·Sampling Equipment for Particular Waste Types. If the drom is filled with small bl11 full containers 

### (e.g., vials, 2 oz. plastic jars ) one. exampl e o f each container type wiU be placed in the sample jar. In 

### this instance, a sample bag or pail may 

### also 

### be used to collect the representative sample. The 

### sampler will place labels (CIN) on the sample · jar 

### (s) and complete applica ble sample testing information. 5.1.2 Standard Operating P rocedures for Waste Guterated On-Site One of the most common methods of se l ecti ng a random 

### sample is to divide the . population 

## bY an imaginary grid. RIS observes the grid method of sampling. When a so lid residual sam ple is required.. 

### the sampler visually grids the 

### contain er hoUsing the . residoal. The sampler selects the grids from wbich samples 

### are to be obtained based on the 

### appearance and texture ofthe residual. RIS uses a combined random .and judgmental sample coi lection system wben obtaining solid residual samples. Whenever differences in color, 

## appeimmce, or texture are 

### present, !he sampler will obtain samples 

## from these areas. Typically a container will be divided into several (6 to 12) sections and the sampler will pull samples randomly from 

### a minimwn ofthree 

### grid sections on each side of the container. The sample aliquot is obtained b y inserting a sam ple scoop into the residual l!latetial. · At least o

ne sample from each side of the contain er 

### witt be obtained from a depth of 3 to 18 inches . 

### The actual sample will be collected by inserting a · sample scoop into the residual material at the center of several grids. The individual grab 

### sam ples are p laced into a stainless steel container and mixed, or oomposited into a single well-mixed sample from which the aliquot to be analyzed 

### will be obtained. Aliquots will be selected from 

### th e composited sample located in 

### the stainless steel conl!lioer 

### and will be used to fill the approptiate sample conta iners for analysis. Samples ofash and filter cake collected using this collect ion method 

### will represent the entire sample population.



### C3 - 14 VES016282

# •
• 

# • April, lOU R.e\ision 0 

### The operations · individual .II$Signed to sample acquisition perfonns the actual sampling and composit ing. . DesiiJlated 

### operations 

# Personnel will dccootaminatc the sampling equipment 

### Aft« 

### donning appropriate protective equipm"ent 

### as dictated by the handling instruc:tioo.s, 

### the samplec will 

### retrieve 

### the sample 

### as . indicated above. Once 

### the sample containers have been 

### filled, excess 

### sample material will be returned to the 

### residual , container. Sample 

### containers are closed and 

### preserved 

### as indiaitcd by the 

### laboratory. Paperworic 

### including the sample labels, sample collection 

### reeord and 

### the chain-of-custody 

### form arc completed. Tho $!mplcis 

### are placed in the cooler with ice and the cooler 

### is returned to the fingerprint laboratory. The collection method for scrubber water produce$ 

### a well-mixed, homogenous representative grab sample 

### from the ci0$Cd·loop scrubber system (CLSS) . The sampler 

### doDns appropriate protective equipment 

### as dictated by tho handling instructions and clecontaminates 

### the sampling equipment The sampler may U$C 

### a variety of locations includioS but not litnited to the clarifier Weir ovctflow, 

# u.e Maintenance Storage Tank and the clarifiec 

### surge tank to obtain · 

### a sample 

### from the closed loop 

### system. The sample is collected by 

### filling each sample container 

### from one of the aforementioned I<X:ations. 

### Ellcess sample material is returned to the Closed Loop System, the sample containers are clnsed, and the sarnples are preserved as indicated by the laboratory. Paperwork including the sample labels, sample collection !:CCQrd 

### and the chain-of-custody 

### form are cOillpleted. The samples 

### are placed in the cooler with ice and 

### the cooler is returned to the fingerprint laboratory . 

### 5.2 Sample 

### Testing Sample testing pr<X:edures for wastes received 

### from. off-site facilities 

### are specifi ed 

### in Section 

### 5.2.1 of the Sampling Plan whi le Saniple tesi ing procedures 

### for on-site gencreted 

### residuals are specified in Section 

### 5.2.2 of the Sampling Plan. These 

### sections identify the collection 

### records and routine cb.am-of-custody proccclures used to msure the integrity of a sample from collection to data 

### reporting .

C3·1S VES016283

# • • 

# • • 5.2.1 Sample**T~g** 

### Procedures for Waste Received 

### from Off-site April, 2013 RevisiooO


### After tho sample material 

### from a shipment bas 

### been collecced, the 

### ReceiVing agent obtains the sample 

## 8nd completes sample testing information specific to 

### tliat WPS. Sample testing 

### information is 

### completed for each WPS and i dentifies lhe**=~omer,** 

### shipper number and date, WPS number and CINs that were sampled. and the 

### Receiving employee wbo 

### sampled lhe material. After the sample and 

### i ts 

### assOciated sample testing information arrive at the 

### fingerprint laboratory, the laboratory chemist performing the analysis 

### accepts. the receipt ofthe sample 

### and then 

### perfonns the analysis. Th e chemist 

# records the results 

### of each analysis on tho LabOratory 

### Logbook. If 

### the results 

### are wilhin 

### acceptabl e parameters, th7 shipment is accepted. A 

### 'description of typical sample teSting .information and a Laboratory Logbook 

### are included 

### as E xhibits 0 

### and Exhibit H 

### respectively to 

### this WAP. Sample testing information acts 

### as chain.of-ctl.stody for 

### the sample. It provides documentation that 

### sampling was 

### completed and aids 

### RIS in docun!enting sauiple 

### acceptance and 

### rejection.. Both th e Laboratory Logbook and sample testing information are maintained fur each 

### sample 

### and are recorded in the Operating Record along With .the comput erized sample records. 5.2.2 

### Sample Testing Procedures fur ()n.site Residuals An 

### essential part of ensuring 

### the integrity 

### of a 

### samp l e 

### from collection to data reporting 

### is 

### by 

### documentation.**Documen~ion** 

### of the history of the sample is 

### referred to 

### as "chain-of-custody.. " Chain.of..custody procedures 

### are 

## useful for 

### routine testing of sample fiow and facilitate tracing the.possession and 

### han4ling ofsamples 

### from the 

### time of

### collection through analysis 

### and 

### final disposal 

### The components of RIS' residual chain-of -custody 

### process include the sample label, the 

### sample collection 

### record. (SCR) and 

### the Chain-of · Custody furm . A 

### sample is considered to be 

### uDder a person's custody ifit is: I . 

### In the 

### designated personnel's possession, 2. 

### In view 

### ofthe 

### designated personnel , 3 . Secured by that 

### person so Jioone can tamper 

### With 

### it, or 

## 4. Secured by that . person 

### in an area restricted to authorized personnel.

C3·16 

### V E S 01 628 4

# •
•

I I • 

# l e I '- 

# ' April, 2013 . RevisionO 

### Completion of a sample collection record · and a chain-of-custody form is required for all residual'samples. A description of the sample collection reCord 811d the chain-of-cusiody fonn is 

### found in Attachment B - Description of RIS Residual Sample Testing Documents . All i nfonnation 

## !Dust be filled out on the sample collection record by the person in control ofthe sample. The infonnation to be completed on the chain-of-custody f<?rm includes:

_ the sample location 811d description, date and time sample was collected, 

### and the sample type 

### (grab, composite, matrix). A label must be 

### completed 

### and placed on 

### each sample container. It may also 

### list the sample collector, 

### date and time of collection 

### and place of collection. Once obtained, the sampl e is 

### returned t o the 

### finge!print la boratory along with the chain-ofcustody fomt The person preparit!g the sample will inspect 

### the container for leaks and the label for comp!eteaess, then 

### J'eC9rd the 

### sample identification number on the 

### sample collection record foim and 

### the sample container label. Discrepancies between the chain-ofcustody form 

### and the sample label will be resolved immediately. The Sample Collection Record 

### and**Chain-of~ody** 

### form serve as the fi eld notebook, (i.e. ; a record of the samples taken from ibe field). When the sample collector relinquishes the sample, he (she) signs off at the bottom of 

### the**~-of-custody** 

### form. 'I.'he samples are typically . sent out to the commercial laboratory within 24 hours. A copy of the chain-of-custody form is sent to the sample destination and will be attached to the samples when shipped to the commercial laboratory. FolloWing receipt of the samples at the commercial laboratory, the lab personnel 

### will handle the chain-Of-custQdy fonn as directed by their organization. A copy of the 

### final chai n-of-c ustody form 

### will be sent to RlS with the analyticat'results . 5.3. Training for Personnel _ taking Samples All designated sampling pmonnel 

### have 

### been ttained in RlS Health 

### and Safety . Procedures in accordance with the RlS Training P lan . Please refer 10 RlS' Ohio RCRA Part B application Section H,**Pers~el Traitti~g**  

### Plart 6.0 Health and Safety 

### ProtOcols All designated sampling personnel have 

### been trained in RJS Health and Safety 

### Procedures and at 

### a minimum, personnel have been instructed in the proper use of safety equipment, such as protective clothing and respiratory equipment Health and Safety

C3-17 

## • •

V E S016285April, 20ll Revision 0



### • prot0¢01s have been defined in the Handling Instructions (refer 

### to Section C - Exhibit F: 

# •

• • Handling 

### Instructions) associated 

### with off-site and on-site generated wastes. · Typical health**an~** 

### safety prot0¢01s indicate when 

### . and where safety equipment is 

### required. Additionally, safe areas where facilities are available for ':"ashing, 

### drinking, and eating have been 

### designated. The following protective equipment is 

### typically worn by the residlials sampler when handling incinerator ash, filter cake or saubber water. air-purifYing reSpirator with vapor /acid gas 

### cartridges, trvek 

### apron, chemically resistant 

### gloves, hard 

### hat and safety -glasses . .



### C3-18 f



### VES016286

# • April, 2013 R

evhio!IO


## Table 1- Sampling 

## Equipment for Particular Waste Types* Material Typ e Samplillg Method . Recommended Sampllog Equlpll,l , ent



## . . Reference Solid or rock -lilce maierial ASTM 0420-69, Brass hammer, 

### brass chisel, or other ASTM 01452-65 or physical sampling de vices SW - 846, Chapt er 

### 9 Containerized liquid material SW-846, Chapter 

### 9 or COUW ASA · between 4 and 8 foot in 

### EPA 60012-8 ().0 18 length ()pen 

### Tube 

### Samoler Sludges and 

### slurries ASTM 014(). 70, Scoops, dippers, or other scoop-like EPA 60012-8().018 or utensils SW-846, Cha pter 9 Plastics and fib. ers ASTM 0420-69 or Utility knife, scissors, tin snips SW-846, Cbapter9 Paint filters;.tubes ASTM 0420-69 or Wood saw, back saw, or other cutting SW-846, Cha pter 9 implements, Tin snips Granular material and 

### soil ASTM 0346·75 or Orain scoop , trowel, quick bucket 

### SW ·846, Chapter 9 opener, or other scoop-like utensils V

i scous materials ASTM014().70or Tongue depressor, sample jar, dipper (;.d.&a llq oldo ...tslo:ria,too tllid< li><- 

### SW-846, Chapter9 

## ......**~mal** 

### Incinerator Ash 

### ASTM 02234-76 or Scoops, dippers, 

### trowels SW -846, Chapter 9 • The methods aad equipment used for samplina was!<> materials will vary with the fonn aad consistency ofthe w aste mat«iaas sampred. Samples oolleeted uaiaa the &linc protocols listtd in sectio"' 2 . 1.1 and 2.2.2 for &litia waste with propenies similllr to the indicated rnotcrials, l$ considered to be**..P....n~~tive** oflbe waste .



### C3 · 19 VES016287

# • •**~** 'J,'ab le 2- S ample Containers, Preservatives an d Bolding Times Parameter Sample CoAtai.atr HolciJAg Time Preserva llve 

## I lMio imum Size) Acid Only SOO ml Glass • 7 days to ex b actioo Cooi 4 "C 1 .0 lder GJass • • 40d& w a&r exbacrion Dod: Aalimo.y 100 ml Olaso' 6111001hs Cool4 "C SOO ml Polypropyte. u Anenle IOOmlGiau' 6moolhs Coo i4"C SOOm i Pol 

## •• Bariam 100 m i . Glass ' 6 months Cooi 4"C SOO mlP ol 

# ..**~ryllium** l OO m!. Glau • 6 moahs Cooi4 "C SOOml Pol u 

### Cbr oml umVJ 100 m1 Otas•• 24bowo Coo i4 "C SOO ml PolYI>I'OI>Y te. •• 

### Dissolved' Mercury 38 da ys in 

### tJass**3~=inglass** fll l« 13 da.. in 1>lutie 13 in clutlc 

## I oH< 2 HNO. ond/ or Cooi4 'C 

### H azardous Waste Corrot lvlty 

## • 7 days HOllO**I. Oli~etG!ass** **••** 

### Hazar.d out Waste liiJlllabllity 

## • 7days None SOOm l Glass ; 

### H aza rdou s**Was~e** 

### Toxldty 1.0 litu Glass • 7 days to cxttaclion None 40 claw after eXU'ICiion 

### H azard o u 1 Waate Readlvlly IOOml Oia .. • . 7 da)'!l Cooi 4 "C 500 ml Polvoroovlene •• Darlc 

### ' H 4xava lent C hro mium IOO ml Glas.. 24 hours Cooi4 'C · 500 ml Polvoroovlcne •• 

### H y drogen J on 100 ml Glass' Immediately None 60 ml PolvnmDIIIene •• 

### Lea d lOOm! . Glass• 6moetbs Cool4 C 500 ml Polvnroovlenc •• 

### Mer eury T otal 38 days in glass 1 3 davs in**~scie** 38 days**;~::::,** p H< 2 HN O, o nd/or · 13dawin · C ooi 4 "C 

### Total**a.,e;:,~ve able**  

### M etals (Except Chromi u m 100 ml Glasa ' 6moolba pi!< 2 HNO, and/or ondM=u 500 ml Pol)p<Opylene •• C ooi 4 "C 

### Dissolved Metals (Excepe Chromium m1 IOOmlG!ass• 6mooohs F ihc< oolite Mon:urv l SOO ml Po lypropylene •• pH< 2**HN O,Cool** **~**

------ C3-20 

### VES0 1 6288

# . . 

# • •

Par•wn•t•r 

### S uspmded Metals IDc!Mcn=y) 

### T ot al Me tals (llxoept Chromi\Utlmd Memny) 

### MetabTAL Metab RCRA ( 8) 

### Orgaa ochlo riae Pesticides 

### pB Readive
Organic 

### TCLP Sample_ Total Mercury Organles

•• • WtA.fdWNW:WII.tt Solicl_ples_..--1 ..,. .......... P.-vallc.. t liltcd are f«liquid 

# "'""*" · HNO, • Nitric A<id 

### d a

... I : I H,SO, = s.Jfuric Acid dil= 1: 1 NoOH • Sodhxn HyOtox; de <fWt e 1: 1 No,S,O, • Sodi,..Thiosulfllc For decldorinaaoa C3-21

# ttt**~** HoldlasTU... PftHJ""V•dv e 61D001hs



### VES016289

# •
• 

# • "P<<I , lOI J Revision 0 . 

## Table 3. Residual Analytical Parameters and Methods Summary A.s pl'C\1oosly indicated RIS somplca tlu<e ,..idualo: iDclncratcr ub, filler cake, aud acRJbbcr walor. Analywla of Ike ineincntor ash and filler coke is cyp[cally oomplctcd pn an exlnlel oflbe wasce, whereas, analysis oftho**$CI'1lbbe~** WilleT bi)'Jlically completed on the WISIO l rsolf. 

### Parameter pH (EioclroaJcCric) .**pH~)** Amenable Cyanide CblorinsiOd Berl»cidcs by Gu 

### CJwomatoar•ph Cyanide, Total Dibc:ozoclioxins and Dil>eozoliarans, HRGC , HRMS l)loxias / Furans HR.OC I LRMS Fluoride (Po<endomccric,lon Seloctivo Elcotrodo ) )nductively t;:oupled Plwna (ICP) Mclals (A.s, Aa , 8a, Be, Cd, Q, Pb, Nl, Sc .' Tl, Va, Zll) Mercury in Liquid W- (M..W Cold Vopc<) Mercury in Solid W0$1e (Monaal Cold Vapor) Method for DcvrmjMtlon ofWiler Coiii<DI ofSoU
· Non ·halop3led Orpaic$ 

### usina GCIFID**0.,:~** PCOiicides**Ori~Compounds** byGC Point Filler Test Pensky-Manens Meihod for Dctenninlna Ianim billty Pol)'thlorinoted Bipbellyts Scmi -volotilc Orgooic Co"'''oundo by GCIMS &.ffide

.Tom! Orpnic lhlogens Vo!acilo Orpnics byGCIMS 

### oc. Cia Cbro:uto 

# ...,. MS•MiaS; I 't'7 • HkGC - HiP**hsolobaaO.~** 

### CJ-22 Analytjct! Mstbgd**EPA~4-79.02~** ISO. I 9045A 9012 I ISlA 9012A 8290 8280 E

PA-60014-79-020 : 340.2 60108.6020 . 7470A 7471A 02216-90 SO IS B SOl i A 8141A 9095 1010 8082 

# moe EPA: 60014-79 : 020 : 376. 1 9020A, 90208 82608 H&MS • lti.P ll aobliooM• SF :l 11 UCX:•**t.ow'R.~O.O!ii** . ...**~S Low** **~MISS J**  Jl



### VES016290

# •

I 

## I • 

# •

· 

# .. Attachment A Description of 

# RIS Residual Sample Testing Documentation Apri1,20U Revisioa 0



### V ES016291

# • • 

# • •

(**~** 

# RIS Residuai ·Sample Testing Documentation April, 2013 Revisioo 0



### RlS residual sample testing paperwork documents the collection, management 

### and requested analysis of samples. The 

### sample testing documentation consists of**~0** 

### fonns: the sample collection record and 

### the chaiirof-custody 

### furm. Together the fonns identify and 

### track the collection, preservation and 

### shipment of RIS residual samples. The sample collection record is 

### an internal RJS document designed to identify the residual samples taken. The sampl e collection record details the field conditions at 

### the time of 

### sampling and 

### is retained in production 

### support files. At a mJnioium; the following information mUst be 

### included on the sample collection record. I. 

### 2

. 

### 3. 4. 

### 5

. 

### 6. 

# 7. 8. 9. 10 . 

### The date the sample was taken, The time ofday the sample was taken, The 

### name ofthe person taking the sample, The RIS sample number,



### . The type of residual sampled, The type 

### of sample taken: grab or composite The sampling location or container number The sample description (color, odor ,**tex~** 

### etc.) The environmental conditions uoder which the sample was taken, and A 

### space for comments or observations. . RlS typically uses the chain-of-custody form Jirovided ' by the commercial l aboratofY. The chain-of-custody form provides an unb"?ken trail of sample accountability that 

### ensures the physical security of samples and validity of the 

### corresponding data. At a mlnimum the form must contain: I. 

### Project Name/Customer Name 2 . Chain-of-custody form number 3. Sample number or identification 4. Sample l ocation, description, 

### and matrix 

### 5

. Date and time collected
C3 - Aitaclunent A V ES016292I 

## I 

# i·
•



# • 6. Sample type 

### 7. Containers 

### I 

### Preservatives 8. Analysis**rcq~ecl** 

### 9 . Hazard ' I dentif ication 10. Special lnstructi ons April, 2013 RcYision 0

11 . 

### Sample . custodyhistory (Relinquished by , date , time/Received by, date, time)

C3- Att achment A '.



### VES016293

# VES016294-016537.pdf

## -- -- ·-- · · ·



# I I

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# REC E IVED M

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# OH IO EPA NEDO I .



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VES016294( 

## ; 

## . 

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# - SECfiONC Heritage-

### WTI., 

### IDe. OHD9 8 061354l Revision: 2 8 

### April 26, 2012



# WASTE CHARACfERISTICS AND WASTE ANALYSIS PLAN Heritace - 

# wn, lue. . 

### Fdsl Liverpool, Ohio
Rerisioa 

### 28 - Apri126, 20U .



### JUN 

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## '

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# Interoffice Memo To : 

# Fie- · tur:c/!ltritcY**~..} ;;I~FY'** **}** 

# tJ,Ic (4ar.

# Fr~**: J~~**  

# tyJ**orr~ ~** **i_)~ i~** **·~U** /}/2 Date : 

### <g 

# /1 ] /;if SubJect: Public Records Request- Ffle Review This file . 

### was reviewed to**~te!Tiline** whethe r records contained hereln are confidential or othe<wl$8**~t** from the d lactosure obligations of Ohio Revised Code section 1 49..43 . _All records 

### Bf!1**pu~** records - no records were removed based on this review

_ Some records 

### are not public - these records we re removed lor the reasons noted below . · · 

# r '\ Under ORC 1 49 . 43(A){1 )(v) , certain**~** 111e 

### not public records because lh6i release 

### is \ • prohlbRed by l.tw , $uch B$ •attomey-dklnl prlvi&ged communication$ . • These records illclude the following (if marked} :

.· '"\ 

## ' o An Ohio EPA attorney's or Asslstant Attorney General's preparalion of or**~ments** on draft memoranda, lettef, , pleadiogs or other documents, provid ing legal advice . o 

### Memomnda, e-mail, or another C008$pondenoe containi11g p rivi leged communications 

### to or from 

### an Ohio EPA 

### sttomey or 

### Aselstant Attorney 

### Ge11aral o Other record excluded by law (specify applicable law, I . e . , trade secret):.____**~** Under ORC 149. 4 3(A)( 1 )( h ), C8f1ain records are 

### not public records because they aro**·con~nlia/** l.tw enforcement irrvestigalory 1'600/T!$ . • These recorda include the following recorda (if marked) : 

### o · Enforcement 

### case ref erral memooanda , including attached supporting docu me nts. o Memoranda , 

### e-inall, other documents that 

### discuu enfortement case strategy (I . e.. specific Investigatory wOO. product) . o Information from an lnfonnation source or**w~neas** to**wh~** confodentlal l ly has been reasona b ly promised . Should 

### you have any questions regarding this Issue, please contact Ohio EPA's Legal 

### Ofi'IC8 . (Ibis memorandum is to remain visibly anacbed 

### to Ibis file.)



### VES016297