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6*8?Y?6(&:3'7DEOH'HVFULSWLRQRIWKH&$0[UXQFRQWUROILOH&$0[LQIRUWKHFRUHPRGHO7KHUHFRUGODEHOVH[LVWLQFROXPQVDQGLQSXWGDWDVWDUWLQFROXPQ7KHIRUPDWGHQRWHG ́OLVWμLQGLFDWHVDIUHHIRUPDWOLVWRIQXPEHUVFRPPDRUVSDFHGHOLPLWHG5HFRUG /DEHOFROXPQV 5HFRUG2SWLRQDO)RUPDWVWDUWLQJLQ FROXPQ 'HVFULSWLRQCAMx versionOLVW 0RGHO YHUVLRQ NH\ZRUG 9(56,21Run messageA60 Simulation message (to be written to output concentration file headers)Root output nameA80 Root output path/filename (see Table 3-3 for description of file suffixes)Start yr/mo/dy/hrlist Simulation start year (YYYY)Simulation start month (MM)Simulation start day (DD)Simulation start time (HHMM: Midnight = 0000; 1 PM = 1300)End yr/mo/dy/hrlist Simulation end year (YYYY)Simulation end month (MM)Simulation end day (DD)Simulation end time (HHMM: Midnight = 2400; 1 PM = 1300)DT:max,in,emis,outlist Maximum allowable time step (hours)Input frequency of input environmental fields (hours)Input frequency of input emissions (hours)Output frequency (hours)nx,ny,nzlist Number of coarse grid columns (E-W grid cells)Number of coarse grid rows (N-S grid cells)Number of coarse grid layersCoordinate IDA10 Mapping projection keyword (LATLON, UTM, LAMBERT, POLAR)xorg,yorg,dx,dylist See Table 3-4 for the specific information to provide for each type of mapping projectiontime zonelist Time zone (Eastern = 5, Central = 6, Mountain = 7, Pacific = 8, UTC = 0)PiG parameterslist Maximum PiG puff length (m)Maximum PiG puff age (hours)Avg output specieslist Number of species to be written to average output file (NAVG)&$0[ Y 8VHU·V *XLGH 'HFHPEHU 7DEOH'HVFULSWLRQRIWKH&$0[UXQFRQWUROILOH&$0[LQIRUWKHFRUHPRGHO7KHUHFRUGODEHOVH[LVWLQFROXPQVDQGLQSXWGDWDVWDUWLQFROXPQ7KHIRUPDWGHQRWHG ́OLVWμLQGLFDWHVDIUHHIRUPDWOLVWRIQXPEHUVFRPPDRUVSDFHGHOLPLWHG5HFRUG /DEHOFROXPQV 5HFRUG2SWLRQDO)RUPDWVWDUWLQJLQ FROXPQ 'HVFULSWLRQ,?&$0;?86(5
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6*8?Y?6(&:3'7If Probing Tools=T, a series of records are entered here to supply information for the specificProbing Tool selected (see Sections 5 and 6 for specific information to supply in the CAMx.infile)ChemparamA80 Input chemistry parameters path/filenamePhotolysis ratesA80 Input photolysis rates path/filename (IGNORED for Chemistry=False)LanduseA80 Input coarse grid landuse path/filename (IGNORED for Dry Deposition=False)Height/pressureA80 Input coarse grid height/pressure path/filenameWindA80 Input coarse grid wind path/filenameTemperatureA80 Input coarse grid temperature path/filenameWater vaporA80 Input coarse grid water vapor path/filename (IGNORED for Chemistry=False)Cloud coverA80 Input coarse grid cloud cover path/filename (NOT MANDATORY1, IGNORED for Chem=F)RainfallA80 Input coarse grid rainfall path/filename (IGNORED for Wet Deposition=False)Vertical diffsvtyA80 Input coarse grid vertical diffusivity path/filenameInitial conditionsA80 Input coarse grid initial conditions path/filename (IGNORED for Restart=True)Boundary conditionsA80 Input coarse grid boundary conditions path/filenameTop concentrationA80 Input coarse grid top boundary conditions path/filenameAlbedo/haze/ozoneA80 Input albedo/haze/ozone column path/filename (IGNORED for Chemistry=False)Point emissA80 Input elevated point emissions path/filename (IGNORED for Point Sources=False)Gridded emissA80 Input coarse gridded emissions path/filename (IGNORED for Area Sources=False)Landuse Grd#n7A80If NEST>0, repeat this record for each fine gridInput fine grid landuse path/filename for nestn(NOT MANDATORY)1&$0[ Y 8VHU·V *XLGH 'HFHPEHU 7DEOH'HVFULSWLRQRIWKH&$0[UXQFRQWUROILOH&$0[LQIRUWKHFRUHPRGHO7KHUHFRUGODEHOVH[LVWLQFROXPQVDQGLQSXWGDWDVWDUWLQFROXPQ7KHIRUPDWGHQRWHG ́OLVWμLQGLFDWHVDIUHHIRUPDWOLVWRIQXPEHUVFRPPDRUVSDFHGHOLPLWHG5HFRUG /DEHOFROXPQV 5HFRUG2SWLRQDO)RUPDWVWDUWLQJLQ FROXPQ 'HVFULSWLRQ)RU UHFRUGV GHVFULEHG DV  ́127 0$1'$725<μ WKH XVHU KDV WKH RSWLRQ WR OHDYH WKH ILOHQDPH EODQN )RU H[DPSOH LI JULG QHVWV DUH VHOHFWHGUHFRUGV DUH UHTXLUHG IRU ILQH JULG ZLQGV EXW WKH XVHU FDQ OHDYH WKH ILQH JULG ZLQG ILOHQDPHV EODQN FDXVLQJ &$0[ WR LQWHUSRODWH WKH ILQH JULG ZLQGV IURPFRDUVH JULG ZLQGV,?&$0;?86(5
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I:\CAMX\USER'SGU\v3.00\SEC3.WPD  #!/bin/csh # # Script to Run CAMx # set verbose set INPUT = "test_run/inputs" set EMIS = "test_run/emiss" set PTSRCE = "test_run/ptsrce" set OUTPUT = "test_run/outputs" set TRACIN = "test_run/osat_inputs" set TRACOUT = "test_run/osat_outputs" set TRACEMS = "test_run/osat_emiss" date # # --- Create the input file (always called CAMx.in) # cat << ieof > CAMx.in CAMx Version |VERSION3 Run Message |CAMx Test of v3.00 Root output name |$OUTPUT/CAMx3.test.950707 Start yr/mo/dy/hr |1995 07 07 0. End yr/mo/dy/hr |1995 07 07 2400. DT:max,in,emis,out |0.5 1. 1. 1. nx,ny,nz |64 63 5 Coordinate ID |LATLON xorg,yorg,dx,dy |-99. 26. .5 .33333 time zone |5 PiG parameters |5000. 12. Avg output species |15 |NO NO2 O3 PAR TOL ETH |OLE PAN ISOP XYL FORM ALD2 |HNO3 NXOY NTR # nested grids |1 i1,i2,j1,j2,nz,mesh|15 59 19 54 7 3 SMOLAR, BOTT, PPM? |SMOLAR Chemistry Solver |CMC Restart |false Chemistry |true Dry dep |true Wet dep |true PiG submodel |true Staggered winds |false Treat gridded emiss|true Treat point emiss |true 1-day emiss inputs |true 3-D average file |false Probing Tools |true File Root |$TRACOUT/CAMx3.OSAT.950707 Technology type | OSAT Coarse sfc output | true Fine sfc output | true Stratify Boundary | false # of Source Regions| 19 # of Source Groups | 3 Use leftover group | true # timing releases | 0 Chemparam |$INPUT/CAMx3.chemparm.3 Photolysis rates |$INPUT/rate.ng.99jul95.ai.basD

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I:\CAMX\USER'SGU\v3.00\SEC3.WPD  Landuse |$INPUT/surf.cc.commonfile.ai.basD Height/pressure |$INPUT/rams/hght.cc.07jul95.ne.rams1b Wind |$INPUT/wind.cc.07jul95.ne.rams1b.camx2 Temperature |$INPUT/tmpr.cc.07jul95.ne.rams1b.camx2 Water vapor |$INPUT/rams/wvap.cc.07jul95.ne.rams1b Cloud cover |$INPUT/clou.cc.07jul95.ld.basD Rainfall |$INPUT/anlrain.950707.out Vertical diffsvty |$INPUT/rams/vdif.cc.07jul95.wi.rams1bnew Initial conditions |$INPUT/init.cc.07jul95.ld.basD Boundary conditions|$INPUT/bndr.cc.07jul95.ld.basD.a0 Top concentration |$INPUT/topc.ng.commonfile.ai.basD Albedo/haze/ozone |$INPUT/ahoz.cf.99jul95.ld.basD Point emiss |$PTSRCE/ptsr.ng.07jul95-95.ne.95basD2 Gridded emiss |$EMIS/emis.cc.07jul95-95.ne.95basD2 Landuse Grd#1 |$INPUT/surf.ff.commonfile.ai.basD Hght/press Grd#1 |$INPUT/rams/hght.ff.07jul95.ne.rams1b Wind Grd#1 |$INPUT/wind.ff.07jul95.ne.rams1b.camx2 Temperature Grd#1 | Vert diff Grd#1 |$INPUT/rams/vdif.ff.07jul95.wi.rams1bnew Gridded emis Grd#1 |$EMIS/emis.ff.07jul95-95.ne.95basD2 Source area mapping|$TRACIN/source.map Receptor definition|$TRACIN/receptor.cities Area Grp#1 Grd#1 |$TRACEMS/bio2.cc.07jul95-95 Area Grp#1 Grd#2 |$TRACEMS/bio2.ff.07jul95-95.ne Point Grp#1 | Area Grp#2 Grd#1 |$TRACEMS/utillowp.cc.07jul95-07.ag.07cem1A-run11 Area Grp#2 Grd#2 |$TRACEMS/utillowp.ff.07jul95-07.ag.07cem1A-run11 Point Grp#2 |$PTSRCE/utilptsr.ng.07jul95-07.ag.07cem1A-run11 ieof # # --- Execute the model --- # /bin/time /models/camx/CAMx3 |& tee CAMx3.OSAT.950707.stdout date # # --- Loop over remaining days to be simulated # foreach today (08 09 10 11 12 13 14 15 16 17 18) set yesterday = `echo $today | awk '{printf("%2.2d",$1-1)}'` set todate = `echo $today | awk '{printf("%2.2djul95",$1)}'` # # --- Create the input file (always called CAMx.in) # cat << ieof > CAMx.in CAMx Version |VERSION3 Run Message |CAMx Test of v3.00 Root output name |$OUTPUT/CAMx3.test.9507$today Start yr/mo/dy/hr |1995 07 $today 0. End yr/mo/dy/hr |1995 07 $today 2300. DT:max,in,emis,out |0.5 1. 1. 1. nx,ny,nz |64 63 5 Coordinate ID |LATLON xorg,yorg,dx,dy |-99. 26. .5 .33333 time zone |5 PiG parameters |5000. 12.

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I:\CAMX\USER'SGU\v3.00\SEC3.WPD  Avg output species |15 |NO NO2 O3 PAR TOL ETH |OLE PAN ISOP XYL FORM ALD2 |HNO3 NXOY NTR # nested grids |1 i1,i2,j1,j2,nz,mesh|15 59 19 54 7 3 SMOLAR, BOTT, PPM? |SMOLAR Restart |true Chemistry |true Dry dep |true Wet dep |true PiG submodel |true Staggered winds |false Treat gridded emiss|true Treat point emiss |true 1-day emiss inputs |true 3-D average file |false Probing Tools |true File Root |$TRACOUT/CAMx3.OSAT.9507$today Technology type | OSAT Coarse sfc output | true Fine sfc output | true Stratify Boundary | false # of Source Regions| 19 # of Source Groups | 3 Use leftover group | true # timing releases | 0 Chemparam |$INPUT/CAMx3.chemparm.3 Photolysis rates |$INPUT/rate.ng.99jul95.ai.basD Landuse |$INPUT/surf.cc.commonfile.ai.basD Height/pressure |$INPUT/rams/hght.cc.$todate.ne.rams1b Wind |$INPUT/rams/wind.cc.$todate.ne.rams1b.camx2 Temperature |$INPUT/rams/tmpr.cc.$todate.ne.rams1b.camx2 Water vapor |$INPUT/rams/wvap.cc.$todate.ne.rams1b Cloud cover |$INPUT/clou.cc.$todate.ld.basD Rainfall |$INPUT/anlrain.9507$today.out Vertical diffsvty |$INPUT/rams/vdif.cc.$todate.wi.rams1bnew Initial conditions | Boundary conditions|$INPUT/bndr.cc.$todate.ld.basD.a0 Top concentration |$INPUT/topc.ng.commonfile.ai.basD Albedo/haze/ozone |$INPUT/ahoz.cf.99jul95.ld.basD Point emiss |$PTSRCE/ptsr.ng.$todate-95.ne.95basD2 Gridded emiss |$EMIS/emis.cc.$todate-95.ne.95basD2 Landuse Grd#1 |$INPUT/surf.ff.commonfile.ai.basD Hght/press Grd#1 |$INPUT/rams/hght.ff.$todate.ne.rams1b Wind Grd#1 |$INPUT/rams/wind.ff.$todate.ne.rams1b Temperature Grd#1 | Vert diff Grd#1 |$INPUT/rams/vdif.ff.$todate.wi.rams1bnew Gridded emis Grd#1 |$EMIS/emis.ff.$todate-95.ne.95basD2 Coarse grid restart|$OUTPUT/CAMx3.test.9507$yesterday.inst.2 Fine grid restart |$OUTPUT/CAMx3.test.9507$yesterday.finst.2 PiG restart |$OUTPUT/CAMx3.test.9507$yesterday.pig Source area mapping|$TRACIN/source.map Receptor definition|$TRACIN/receptor.cities CG tracer restart |$TRACOUT/CAMx3.OSAT.9507$yesterday.sa.inst.2 FG tracer restart |$TRACOUT/CAMx3.OSAT.9507$yesterday.sa.finst.2 Area Grp#1 Grd#1 |$TRACEMS/bio2.cc.$todate-95 Area Grp#1 Grd#2 |$TRACEMS/bio2.ff.$todate-95.ne

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I:\CAMX\USER'SGU\v3.00\SEC3.WPD  Point Grp#1 | Area Grp#2 Grd#1 |$TRACEMS/utillowp.cc.$todate-07.ag.07cem1A-run11 Area Grp#2 Grd#2 |$TRACEMS/utillowp.ff.$todate-07.ag.07cem1A-run11 Point Grp#2 |$PTSRCE/utilptsr.ng.$todate-07.ag.07cem1A-run11 ieof # # --- Execute the model --- # /bin/time /models/camx/CAMx3 |& tee CAMx3.OSAT.9507$today.stdout date end

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I:\CAMX\USER'SGU\v3.00\SEC3.WPD  CAMx Version |VERSION3 Mechanism ID |3 Description |CBM-IV / updated rad-rad rxns / Carter 1 product ISOP mech No of gas species |25 No of aero species |0 No of reactions |96 Prim photo rxns |6 1 38 39 9 45 95 No of sec photo rxn|6 ID, prim ID, scale | 8 1 0.053 |14 1 33.9 |23 1 0.1975 |34 39 0.189 |69 38 9.04 |74 38 9.64 Species Records Gas Spec lower bnd H-law T-fact Diffrat Reactvty 1 NO 1.00E-15 1.90e-03 -1480. 1.29 0.0 2 NO2 1.00E-09 1.00e-02 -2516. 1.60 0.1 3 O3 1.00E-09 1.10e-02 -2415. 1.63 1.0 4 PAN 1.00E-09 3.60e+00 -5910. 2.59 0.1 5 NXOY 1.00E-12 3.20e+04 -8706. 2.45 0.1 6 OLE 1.00E-09 5.00e-03 0. 1.80 0.0 7 PAR 1.00E-04 1.00e-03 0. 2.00 0.0 8 TOL 1.00E-09 1.20e+00 0. 2.26 0.0 9 XYL 1.00E-09 1.40e+00 0. 2.43 0.0 10 FORM 1.00E-09 6.30e+03 -6492. 1.29 0.0 11 ALD2 1.00E-09 6.30e+03 -6492. 1.56 0.0 12 ETH 1.00E-09 1.00e-02 0. 1.25 0.0 13 CRES 1.00E-09 2.70e+03 -6492. 2.45 0.0 14 MGLY 1.00E-09 2.70e+03 -6492. 2.00 0.0 15 OPEN 1.00E-12 2.70e+03 -6492. 2.47 0.0 16 PNA 1.00E-09 2.00e+04 -5910. 2.09 0.0 17 CO 1.00E-04 1.00e-10 0. 1.25 0.0 18 HONO 1.00E-09 5.90e+01 -4781. 1.62 0.1 19 H2O2 1.00E-09 7.40e+04 -6643. 1.37 1.0 20 HNO3 1.00E-09 2.00e+05 -8707. 1.87 0.0 21 ISOP 1.00E-09 1.00e-02 0. 1.94 0.0 22 MEOH 1.00E-09 2.20e+02 -4932. 1.33 0.0 23 ETOH 1.00E-09 2.20e+02 -4932. 1.60 0.0 24 ISPD 1.00E-09 6.30e+03 -6492. 1.97 0.0 25 NTR 1.00E-09 9.40e+03 -8706. 2.72 0.0 Reaction Records Rxn Typ Parameters (1 to 10, depending upon Typ) 1 1 0.0000E+00 2 2 4.3233E+06 -1.1750E+03 3 2 2.6640E+01 1.3700E+03 4 1 1.3750E+04 5 2 2.3090E+03 -6.8700E+02 6 2 2.4380E+03 -6.0200E+02 7 2 4.7310E-02 2.4500E+03 8 1 0.0000E+00 9 1 0.0000E+00 10 2 4.2500E+10 -3.9000E+02 11 1 3.2600E+05 12 2 1.0000E+02 9.4000E+02 13 2 2.9990E+00 5.8000E+02 14 1 0.0000E+00 15 2 4.4167E+04 -2.5000E+02

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I:\CAMX\USER'SGU\v3.00\SEC3.WPD  16 2 5.9010E-01 1.2300E+03 17 2 1.8530E+03 -2.5600E+02 18 1 1.9000E-06 19 2 2.7760E+00 1.0897E+04 20 2 1.5390E-04 -5.3000E+02 21 1 1.6000E-11 22 2 9.7990E+03 -8.0600E+02 23 1 0.0000E+00 24 1 9.7700E+03 25 1 1.5000E-05 26 2 1.6817E+04 -7.1300E+02 27 2 2.1790E+02 -1.0000E+03 28 2 1.2270E+04 -2.4000E+02 29 1 0.0000E+00 30 1 0.0000E+00 31 1 0.0000E+00 32 2 4.1440E+03 -1.1500E+03 33 2 2.1810E-01 -5.8000E+03 34 1 0.0000E+00 35 2 2.5200E+03 1.8700E+02 36 1 3.2200E+02 37 1 1.5000E+04 38 1 0.0000E+00 39 1 0.0000E+00 40 2 2.3700E+02 1.5500E+03 41 1 9.3000E-01 42 2 6.3600E+02 9.8600E+02 43 2 2.4000E+04 -2.5000E+02 44 1 3.7000E+00 45 1 0.0000E+00 46 2 2.8200E+04 1.8000E+02 47 2 1.3700E+04 -3.8000E+02 48 2 2.5400E-02 1.3500E+04 49 1 3.7000E+03 50 1 9.6000E+03 51 2 2.1000E+01 1.7100E+03 52 1 1.2030E+03 53 2 1.3710E+05 8.0000E+03 54 1 9.5450E+04 55 1 2.2000E+04 56 2 5.9200E+03 3.2400E+02 57 2 4.2000E+04 -5.0400E+02 58 2 1.8000E-02 2.1050E+03 59 1 1.1350E+01 60 2 1.0800E+03 7.9200E+02 61 2 1.1920E+04 -4.1100E+02 62 2 2.7000E-03 2.6330E+03 63 2 9.1500E+03 -3.2200E+02 64 1 1.2000E+04 65 1 2.5000E+02 66 1 6.1000E+04 67 1 3.2500E+04 68 1 2.0000E+04 69 1 0.0000E+00 70 1 4.4000E+04 71 2 1.5000E-02 5.0000E+02

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I:\CAMX\USER'SGU\v3.00\SEC3.WPD  72 2 3.6200E+04 -1.1600E+02 73 1 2.6000E+04 74 1 0.0000E+00 75 1 5.3200E+04 76 1 1.4760E+05 77 1 1.9000E-02 78 1 9.9600E+02 79 1 1.2000E+04 80 2 2.0000E+03 -1.3000E+03 81 1 1.2000E+04 82 2 1.1100E+03 -1.6000E+02 83 1 8.1667E-05 84 1 1.6000E+03 85 2 4.3000E+03 -1.7600E+02 86 2 8.9000E+03 -1.3000E+03 87 2 8.9000E+03 -1.3000E+03 88 2 2.0000E+03 -1.3000E+03 89 2 4.0000E+03 -1.3000E+03 90 2 1.6260E+05 -2.5000E+02 91 1 2.7778E-04 92 1 4.9667E+04 93 1 1.0500E-02 94 1 1.4780E+00 95 1 0.0000E+00 96 1 2.2000E-04

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I:\CAMX\USER'SGU\v3.00\SEC3.WPD  CAMx Version |VERSION3 Mechanism ID |5 Description |SAPRC 97 No of gas species |40 No of aero species |0 No of reactions |184 Prim photo rxns |6 1 72 73 16 80 178 No of sec photo rxn|16 ID, prim ID, scale |13 1 2.14 |14 1 19.3 |15 1 0.0521 |20 178 991.3 |38 73 0.146 |69 73 0.144 |83 80 3.73 |86 80 0.127 |88 72 0.0461 |104 72 1.43 |105 178 40.2 |114 72 0.240 |115 73 3.03 |123 178 25.8 |139 178 21.4 |141 178 277.8 Species Records Gas Spec lower bnd H-law T-fact Diffrat Reactvty 1 NO 1.00E-15 1.90E-03 -1480.0 1.29 0.0 2 NO2 1.00E-09 1.00E-02 -2516.0 1.60 0.1 3 O3 1.00E-09 1.10E-02 -2415.0 1.63 1.0 4 PAN 1.00E-09 3.60E+00 -5910.0 2.59 0.1 5 PPN 1.00E-09 3.60E+00 -5910.0 2.74 0.1 6 GPAN 1.00E-09 3.60E+00 -5910.0 2.84 0.1 7 PBZN 1.00E-09 3.60E+00 -5910.0 3.19 0.1 8 NXOY 1.00E-12 3.20E+04 -8706.0 2.45 0.1 9 HNO3 1.00E-09 2.00E+05 -8707.0 1.87 0.0 10 HONO 1.00E-09 5.90E+01 -4781.0 1.62 0.1 11 RNO3 1.00E-09 9.40E+03 -8706.0 2.72 0.0 12 XN 1.00E-09 9.40E+03 -8706.0 2.72 0.0 13 NPHE 1.00E-09 9.40E+03 -8706.0 2.78 0.0 14 PNA 1.00E-09 2.00E+04 -5910.0 2.09 0.0 15 SO2 1.00E-09 1.00E-02 -2516.0 1.60 0.1 16 H2O2 1.00E-09 7.40E+04 -6643.0 1.37 1.0 17 OOH 1.00E-09 1.00E+02 0.0 2.40 1.0 18 FORM 1.00E-09 6.30E+03 -6492.0 1.29 0.0 19 CCHO 1.00E-09 6.30E+03 -6492.0 1.56 0.0 20 RCHO 1.00E-09 6.30E+03 -6492.0 1.80 0.0 21 ACET 1.00E-09 2.80E+01 0.0 1.80 0.0 22 MEK 1.00E-09 2.80E+01 0.0 2.00 0.0 23 GLY 1.00E-09 3.00E+05 0.0 1.80 0.0 24 MGLY 1.00E-09 3.70E+03 0.0 2.00 0.0 25 PHEN 1.00E-09 2.40E+03 0.0 2.29 0.0 26 CRES 1.00E-09 2.40E+03 0.0 2.45 0.0 27 BALD 1.00E-09 2.50E+01 0.0 2.43 0.0 28 AFG1 1.00E-12 3.70E+03 0.0 1.80 0.0 29 AFG2 1.00E-12 3.70E+03 0.0 2.00 0.0 30 CO 1.00E-04 1.00E-10 0.0 1.25 0.0 31 ETH 1.00E-09 1.00E-02 0.0 1.25 0.0 32 ALK1 1.00E-04 1.00E-03 0.0 1.90 0.0 33 ALK2 1.00E-04 5.00E-04 0.0 2.64 0.0 34 ARO1 1.00E-09 1.50E-01 0.0 2.29 0.0

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I:\CAMX\USER'SGU\v3.00\SEC3.WPD  35 ARO2 1.00E-09 1.40E-01 0.0 2.56 0.0 36 OLE1 1.00E-09 5.00E-03 0.0 1.62 0.0 37 OLE2 1.00E-09 5.00E-03 0.0 2.03 0.0 38 OLE3 1.00E-09 5.00E-03 0.0 2.75 0.0 39 ISOP 1.00E-09 1.00E-02 0.0 1.94 0.0 40 ISPD 1.00E-09 6.30E+03 0.0 1.97 0.0 Reaction Records Rxn Typ Parameters (1 to 10, depending upon Typ) 1 1 0.0000E+00 2 3 2.1550E-05 0.0000E+00 -4.3000E+00 3.0000E+02 3 3 9.5410E+03 1.2000E+02 -1.0000E+00 3.0000E+02 4 4 3.2320E-03 0.0000E+00 -4.0000E+00 3.0000E+02 3.2290E+04 0.0000E+00 -1.0000E+00 3.0000E+02 6.0000E-01 1.0000E+00 5 3 2.9360E+03 -1.4000E+03 -1.0000E+00 3.0000E+02 6 3 2.0550E+02 -2.5000E+03 -1.0000E+00 3.0000E+02 7 3 2.4950E+04 1.5000E+02 -1.0000E+00 3.0000E+02 8 3 1.1850E-10 5.2800E+02 -2.0000E+00 3.0000E+02 9 4 7.9010E-02 0.0000E+00 -6.3000E+00 3.0000E+02 2.2020E+03 0.0000E+00 -1.5000E+00 3.0000E+02 6.0000E-01 1.0000E+00 10 5 9. 2.6910E-14 1.1202E+04 0.0000E+00 3.0000E+02 11 3 1.4680E-06 0.0000E+00 -1.0000E+00 3.0000E+02 12 3 3.6700E+01 -1.2280E+03 -1.0000E+00 3.0000E+02 13 1 0.0000E+00 14 1 0.0000E+00 15 1 0.0000E+00 16 1 0.0000E+00 17 3 3.2290E+05 0.0000E+00 -1.0000E+00 3.0000E+02 18 3 2.8170E+04 1.2600E+02 -1.0000E+00 3.0000E+02 19 4 2.5140E-02 0.0000E+00 -4.6000E+00 3.0000E+02 2.2020E+04 0.0000E+00 -1.5000E+00 3.0000E+02 6.0000E-01 1.0000E+00 20 1 0.0000E+00 21 4 9.3370E-02 0.0000E+00 -5.2000E+00 3.0000E+02 3.5230E+04 0.0000E+00 -2.3000E+00 3.0000E+02 6.0000E-01 1.0000E+00 22 3 9.4680E+00 8.3100E+02 -1.0000E+00 3.0000E+02 23 3 3.5230E+02 0.0000E+00 -1.0000E+00 3.0000E+02 24 3 2.3490E+03 -9.4100E+02 -1.0000E+00 3.0000E+02 25 3 5.4310E+03 2.4200E+02 -1.0000E+00 3.0000E+02 26 1 0.0000E+00 27 1 0.0000E+00 28 1 0.0000E+00 29 3 1.6150E+01 -5.0000E+02 -1.0000E+00 3.0000E+02 30 3 3.2290E+02 6.1900E+02 -1.0000E+00 3.0000E+02 31 3 6.8230E-05 9.8100E+02 -2.0000E+00 3.0000E+02 32 3 1.1130E-05 2.8180E+03 -2.0000E+00 3.0000E+02 33 3 2.3700E-06 3.1800E+03 -2.0000E+00 3.0000E+02 34 3 3.2290E+02 6.1900E+02 -1.0000E+00 3.0000E+02 35 3 6.8230E-05 9.8100E+02 -2.0000E+00 3.0000E+02 36 3 1.1130E-05 2.8180E+03 -2.0000E+00 3.0000E+02 37 3 2.3700E-06 3.1800E+03 -2.0000E+00 3.0000E+02 38 1 0.0000E+00 39 3 4.8440E+03 -2.0000E+02 -1.0000E+00 3.0000E+02 40 3 6.7520E+04 2.3000E+02 -1.0000E+00 3.0000E+02 41 3 6.1650E+03 1.8100E+02 -1.0000E+00 3.0000E+02 42 4 2.0290E+01 0.0000E+00 -9.1000E+00 3.0000E+02 3.8750E+04 0.0000E+00 -1.9000E+00 3.0000E+02 2.7000E-01 1.0000E+00 43 4 9.2290E+00 0.0000E+00 -9.1000E+00 3.0000E+02 1.7610E+04 0.0000E+00 -1.9000E+00 3.0000E+02 3.0000E-01 1.0000E+00 44 3 4.9910E+02 8.0000E+02 -1.0000E+00 3.0000E+02 45 3 4.9910E+02 8.0000E+02 -1.0000E+00 3.0000E+02 46 3 1.4680E+00 0.0000E+00 -1.0000E+00 3.0000E+02 47 3 2.7300E+03 5.3000E+02 -1.0000E+00 3.0000E+02 )LJXUHE FRQWLQXHG&$0[ Y 8VHU·V *XLGH 'HFHPEHU 

I:\CAMX\USER'SGU\v3.00\SEC3.WPD  48 3 4.1100E+03 5.3000E+02 -1.0000E+00 3.0000E+02 49 3 6.1650E+03 1.8100E+02 -1.0000E+00 3.0000E+02 50 3 4.9910E+02 8.0000E+02 -1.0000E+00 3.0000E+02 51 3 1.4680E+00 0.0000E+00 -1.0000E+00 3.0000E+02 52 3 2.7300E+03 5.3000E+02 -1.0000E+00 3.0000E+02 53 3 6.1650E+03 1.8100E+02 -1.0000E+00 3.0000E+02 54 3 4.9910E+02 8.0000E+02 -1.0000E+00 3.0000E+02 55 3 1.4680E+00 0.0000E+00 -1.0000E+00 3.0000E+02 56 3 2.7300E+03 5.3000E+02 -1.0000E+00 3.0000E+02 57 3 6.1650E+03 1.8100E+02 -1.0000E+00 3.0000E+02 58 3 4.9910E+02 8.0000E+02 -1.0000E+00 3.0000E+02 59 3 1.4680E+00 0.0000E+00 -1.0000E+00 3.0000E+02 60 3 2.7300E+03 5.3000E+02 -1.0000E+00 3.0000E+02 61 3 6.1650E+03 1.8100E+02 -1.0000E+00 3.0000E+02 62 3 4.9910E+02 8.0000E+02 -1.0000E+00 3.0000E+02 63 3 1.4680E+00 0.0000E+00 -1.0000E+00 3.0000E+02 64 3 2.7300E+03 5.3000E+02 -1.0000E+00 3.0000E+02 65 3 6.1650E+03 1.8100E+02 -1.0000E+00 3.0000E+02 66 3 4.9910E+02 8.0000E+02 -1.0000E+00 3.0000E+02 67 3 1.4680E+00 0.0000E+00 -1.0000E+00 3.0000E+02 68 3 2.7300E+03 5.3000E+02 -1.0000E+00 3.0000E+02 69 1 0.0000E+00 70 3 1.7320E+03 1.2800E+02 -1.0000E+00 3.0000E+02 71 3 2.6280E+03 2.1900E+02 -1.0000E+00 3.0000E+02 72 1 0.0000E+00 73 1 0.0000E+00 74 3 1.6510E+03 6.4800E+02 1.0000E+00 3.0000E+02 75 3 1.4240E+01 6.2500E+02 -1.0000E+00 3.0000E+02 76 3 1.4400E+14 -7.0000E+03 0.0000E+00 3.0000E+02 77 3 6.1650E+03 1.8100E+02 -1.0000E+00 3.0000E+02 78 3 4.1100E+03 -2.5160E+03 -1.0000E+00 3.0000E+02 79 3 8.1470E+03 3.1100E+02 -1.0000E+00 3.0000E+02 80 1 0.0000E+00 81 3 2.0550E+03 -1.8600E+03 -1.0000E+00 3.0000E+02 82 3 1.2480E+04 2.5200E+02 -1.0000E+00 3.0000E+02 83 1 0.0000E+00 84 3 2.0550E+03 -1.8600E+03 -1.0000E+00 3.0000E+02 85 3 7.0610E+02 -2.3000E+02 1.0000E+00 3.0000E+02 86 1 0.0000E+00 87 3 4.2860E+02 4.1400E+02 1.0000E+00 3.0000E+02 88 1 0.0000E+00 89 3 3.2160E+04 -7.0900E+02 -1.0000E+00 3.0000E+02 90 4 2.0290E+01 0.0000E+00 -9.1000E+00 3.0000E+02 3.8750E+04 0.0000E+00 -1.9000E+00 3.0000E+02 2.7000E-01 1.0000E+00 91 4 9.2290E+00 0.0000E+00 -9.1000E+00 3.0000E+02 1.7610E+04 0.0000E+00 -1.9000E+00 3.0000E+02 3.0000E-01 1.0000E+00 92 3 4.9910E+02 8.0000E+02 -1.0000E+00 3.0000E+02 93 3 2.7300E+03 5.3000E+02 -1.0000E+00 3.0000E+02 94 3 4.1100E+03 5.3000E+02 -1.0000E+00 3.0000E+02 95 4 7.9000E+12 -1.2063E+04 -1.0000E+00 3.0000E+02 2.4000E+18 -1.3627E+04 0.0000E+00 3.0000E+02 3.0000E-01 1.0000E+00 96 4 2.0290E+01 0.0000E+00 -9.1000E+00 3.0000E+02 3.8750E+04 0.0000E+00 -1.9000E+00 3.0000E+02 2.7000E-01 1.0000E+00 97 3 1.2330E+04 0.0000E+00 -1.0000E+00 3.0000E+02 98 3 4.9910E+02 8.0000E+02 -1.0000E+00 3.0000E+02 99 3 2.7300E+03 5.3000E+02 -1.0000E+00 3.0000E+02 100 3 4.1100E+03 5.3000E+02 -1.0000E+00 3.0000E+02 101 3 9.6000E+18 -1.4073E+04 0.0000E+00 3.0000E+02 102 3 3.5230E+04 0.0000E+00 -1.0000E+00 3.0000E+02 103 3 4.5000E+16 -8.1520E+03 0.0000E+00 3.0000E+02 104 1 0.0000E+00 )LJXUHE FRQWLQXHG&$0[ Y 8VHU·V *XLGH 'HFHPEHU 

I:\CAMX\USER'SGU\v3.00\SEC3.WPD  105 1 0.0000E+00 106 3 1.6730E+04 0.0000E+00 -1.0000E+00 3.0000E+02 107 3 2.0550E+03 -1.8600E+03 -1.0000E+00 3.0000E+02 108 4 2.0290E+01 0.0000E+00 -9.1000E+00 3.0000E+02 3.8750E+04 0.0000E+00 -1.9000E+00 3.0000E+02 2.7000E-01 1.0000E+00 109 4 9.2290E+00 0.0000E+00 -9.1000E+00 3.0000E+02 1.7610E+04 0.0000E+00 -1.9000E+00 3.0000E+02 3.0000E-01 1.0000E+00 110 4 7.9000E+12 -1.2063E+04 -1.0000E+00 3.0000E+02 2.4000E+18 -1.3627E+04 0.0000E+00 3.0000E+02 3.0000E-01 1.0000E+00 111 3 4.9910E+02 8.0000E+02 -1.0000E+00 3.0000E+02 112 3 2.7300E+03 5.3000E+02 -1.0000E+00 3.0000E+02 113 3 4.1100E+03 5.3000E+02 -1.0000E+00 3.0000E+02 114 1 0.0000E+00 115 1 0.0000E+00 116 3 2.5250E+04 0.0000E+00 -1.0000E+00 3.0000E+02 117 3 2.0550E+03 -1.8600E+03 -1.0000E+00 3.0000E+02 118 3 3.8610E+04 0.0000E+00 -1.0000E+00 3.0000E+02 119 3 5.2840E+03 0.0000E+00 -1.0000E+00 3.0000E+02 120 3 6.1650E+04 0.0000E+00 -1.0000E+00 3.0000E+02 121 3 3.0830E+04 0.0000E+00 -1.0000E+00 3.0000E+02 122 3 1.8940E+04 0.0000E+00 -1.0000E+00 3.0000E+02 123 1 0.0000E+00 124 3 2.0550E+03 -1.8860E+03 -1.0000E+00 3.0000E+02 125 4 2.0290E+01 0.0000E+00 -9.1000E+00 3.0000E+02 3.8750E+04 0.0000E+00 -1.9000E+00 3.0000E+02 2.7000E-01 1.0000E+00 126 3 1.2330E+04 0.0000E+00 -1.0000E+00 3.0000E+02 127 3 4.9910E+02 8.0000E+02 -1.0000E+00 3.0000E+02 128 3 2.7300E+03 5.3000E+02 -1.0000E+00 3.0000E+02 129 3 4.1100E+03 5.3000E+02 -1.0000E+00 3.0000E+02 130 3 9.6000E+16 -1.3033E+04 0.0000E+00 3.0000E+02 131 3 1.9080E+04 3.0000E+02 -1.0000E+00 3.0000E+02 132 3 4.9910E+02 8.0000E+02 -1.0000E+00 3.0000E+02 133 1 6.0000E-02 134 3 5.2840E+03 0.0000E+00 -1.0000E+00 3.0000E+02 135 3 1.9080E+04 3.0000E+02 -1.0000E+00 3.0000E+02 136 3 4.9910E+02 8.0000E+02 -1.0000E+00 3.0000E+02 137 1 6.0000E-02 138 3 1.6730E+04 0.0000E+00 -1.0000E+00 3.0000E+02 139 1 0.0000E+00 140 3 2.5250E+04 0.0000E+00 -1.0000E+00 3.0000E+02 141 1 0.0000E+00 142 3 9.1820E+02 -1.2820E+03 1.0000E+00 3.0000E+02 143 1 6.0000E+01 144 1 6.0000E+01 145 1 6.0000E+01 146 1 6.0000E+01 147 1 6.0000E+01 148 1 6.0000E+01 149 3 2.8770E+03 4.3800E+02 -1.0000E+00 3.0000E+02 150 3 1.3420E+01 -2.5800E+03 -1.0000E+00 3.0000E+02 151 3 7.9710E+03 -3.0410E+03 -1.0000E+00 3.0000E+02 152 3 1.5270E+04 -7.9200E+02 -1.0000E+00 3.0000E+02 153 3 4.0560E+03 4.3300E+01 0.0000E+00 3.0000E+02 154 3 1.1250E+04 9.2600E+01 0.0000E+00 3.0000E+02 155 3 1.1990E+03 5.8320E+02 0.0000E+00 3.0000E+02 156 3 1.5160E+04 2.9740E+02 0.0000E+00 3.0000E+02 157 3 2.7200E+03 8.0110E+02 0.0000E+00 3.0000E+02 158 3 2.7680E+00 -1.5575E+03 0.0000E+00 3.0000E+02 159 3 6.4630E+03 -2.6700E+01 0.0000E+00 3.0000E+02 160 3 2.2110E+02 -8.1020E+02 0.0000E+00 3.0000E+02 161 3 6.0490E+03 8.1670E+02 0.0000E+00 3.0000E+02 )LJXUHE FRQWLQXHG&$0[ Y 8VHU·V *XLGH 'HFHPEHU 

I:\CAMX\USER'SGU\v3.00\SEC3.WPD  162 3 3.2210E+00 -7.3770E+02 0.0000E+00 3.0000E+02 163 3 1.2590E+04 3.2110E+02 0.0000E+00 3.0000E+02 164 3 3.7250E+02 1.3180E+02 0.0000E+00 3.0000E+02 165 3 2.8020E+04 4.6850E+02 0.0000E+00 3.0000E+02 166 3 1.7540E-01 -1.1670E+02 0.0000E+00 3.0000E+02 167 3 2.5730E+04 2.9740E+02 0.0000E+00 3.0000E+02 168 3 2.3850E+03 4.3080E+02 0.0000E+00 3.0000E+02 169 4 1.0770E-02 0.0000E+00 -9.1000E+00 3.0000E+02 2.2020E+03 0.0000E+00 -1.0000E+00 3.0000E+02 6.0000E-01 1.0000E+00 170 3 3.7280E+04 4.0800E+02 -1.0000E+00 3.0000E+02 171 3 1.1540E+01 -1.9120E+03 -1.0000E+00 3.0000E+02 172 3 5.2840E+04 0.0000E+00 -1.0000E+00 3.0000E+02 173 3 4.4480E+03 -4.4800E+02 -1.0000E+00 3.0000E+02 174 3 2.2020E-04 0.0000E+00 -1.0000E+00 3.0000E+02 175 3 4.9320E+04 0.0000E+00 -1.0000E+00 3.0000E+02 176 3 1.0440E-02 0.0000E+00 -1.0000E+00 3.0000E+02 177 1 0.0000E+00 178 3 1.4680E+00 0.0000E+00 -1.0000E+00 3.0000E+02 179 1 6.0000E+01 180 1 6.0000E+01 181 1 6.0000E+01 182 1 6.0000E+01 183 1 6.0000E+01 184 1 6.0000E+01

)LJXUHE FRQFOXGHG&$0[ Y 8VHU·V *XLGH 'HFHPEHU 

I:\CAMX\USER'SGU\v3.00\SEC3.WPD  CAMx Version |VERSION3 Mechanism ID |0 Description |inert test No of gas species |1 No of aero species |0 No of reactions |0 Prim photo rxns |0 No of sec photo rxn|0 Species Records Gas Spec lower bnd H-law T-fact Diffrat Reactvty 1 TRACER 1.00E-09 1.00e-10 0. 1.00 0.0

)LJXUHF ([DPSOHLQHUWFKHPLVWU\SDUDPHWHUVILOHUHTXLUHVFKHPLVWU\IODJWREHVHWIDOVHVHH 7DEOHD&$0[ Y 8VHU·V *XLGH 'HFHPEHU 

I:\CAMX\USER'SGU\v3.00\SEC3.WPD  O3 Column =0.285 Albedo =0.040 Haze O.D. =0.000 0.000 = Current altitude in km 4.562E-01 4.526E-01 4.416E-01 4.224E-01 3.934E-01 3.516E-01 2.921E-01 2.065E-01 1.148E-01 3.074E-02 1.670E-03 1.643E-03 1.563E-03 1.427E-03 1.236E-03 9.889E-04 6.936E-04 3.747E-04 1.502E-04 2.570E-05 2.211E-03 2.186E-03 2.107E-03 1.973E-03 1.776E-03 1.506E-03 1.152E-03 7.108E-04 3.352E-04 7.560E-05 2.078E-03 2.007E-03 1.801E-03 1.485E-03 1.097E-03 6.925E-04 3.382E-04 1.034E-04 2.201E-05 2.056E-06 3.131E-04 3.058E-04 2.841E-04 2.491E-04 2.027E-04 1.482E-04 9.100E-05 4.015E-05 1.264E-05 1.517E-06 8.728E-05 8.638E-05 8.364E-05 7.891E-05 7.189E-05 6.212E-05 4.892E-05 3.166E-05 1.580E-05 3.934E-06 0.150 = Current altitude in km 4.866E-01 4.830E-01 4.717E-01 4.521E-01 4.223E-01 3.794E-01 3.179E-01 2.284E-01 1.308E-01 3.760E-02 1.855E-03 1.827E-03 1.742E-03 1.598E-03 1.394E-03 1.130E-03 8.102E-04 4.566E-04 1.956E-04 3.701E-05 2.443E-03 2.416E-03 2.334E-03 2.193E-03 1.986E-03 1.701E-03 1.322E-03 8.415E-04 4.159E-04 1.000E-04 2.327E-03 2.249E-03 2.024E-03 1.677E-03 1.250E-03 8.008E-04 4.035E-04 1.337E-04 3.383E-05 4.166E-06 3.489E-04 3.410E-04 3.177E-04 2.799E-04 2.297E-04 1.704E-04 1.075E-04 5.024E-05 1.755E-05 2.556E-06 9.553E-05 9.460E-05 9.176E-05 8.684E-05 7.952E-05 6.928E-05 5.530E-05 3.672E-05 1.910E-05 5.068E-06 0.360 = Current altitude in km 5.050E-01 5.013E-01 4.900E-01 4.702E-01 4.402E-01 3.968E-01 3.343E-01 2.426E-01 1.412E-01 4.171E-02 1.974E-03 1.945E-03 1.857E-03 1.708E-03 1.497E-03 1.222E-03 8.862E-04 5.096E-04 2.245E-04 4.415E-05 2.587E-03 2.560E-03 2.477E-03 2.333E-03 2.120E-03 1.826E-03 1.432E-03 9.258E-04 4.673E-04 1.152E-04 2.494E-03 2.411E-03 2.174E-03 1.806E-03 1.353E-03 8.740E-04 4.474E-04 1.536E-04 4.129E-05 5.492E-06 3.722E-04 3.640E-04 3.396E-04 3.002E-04 2.475E-04 1.851E-04 1.183E-04 5.679E-05 2.067E-05 3.210E-06 1.006E-04 9.970E-05 9.681E-05 9.180E-05 8.433E-05 7.382E-05 5.940E-05 3.999E-05 2.122E-05 5.763E-06 0.640 = Current altitude in km 5.230E-01 5.193E-01 5.080E-01 4.882E-01 4.581E-01 4.143E-01 3.510E-01 2.574E-01 1.520E-01 4.577E-02 2.092E-03 2.062E-03 1.972E-03 1.819E-03 1.601E-03 1.315E-03 9.632E-04 5.633E-04 2.535E-04 5.126E-05 2.731E-03 2.703E-03 2.618E-03 2.471E-03 2.254E-03 1.951E-03 1.544E-03 1.011E-03 5.191E-04 1.304E-04 2.664E-03 2.577E-03 2.327E-03 1.939E-03 1.459E-03 9.497E-04 4.928E-04 1.738E-04 4.872E-05 6.809E-06 3.958E-04 3.872E-04 3.618E-04 3.207E-04 2.656E-04 2.000E-04 1.294E-04 6.343E-05 2.378E-05 3.860E-06 1.057E-04 1.047E-04 1.018E-04 9.672E-05 8.912E-05 7.839E-05 6.354E-05 4.331E-05 2.336E-05 6.448E-06 0.980 = Current altitude in km 5.409E-01 5.373E-01 5.260E-01 5.062E-01 4.760E-01 4.321E-01 3.682E-01 2.727E-01 1.635E-01 4.989E-02 2.210E-03 2.179E-03 2.087E-03 1.930E-03 1.705E-03 1.409E-03 1.041E-03 6.178E-04 2.827E-04 5.837E-05 2.873E-03 2.845E-03 2.758E-03 2.609E-03 2.387E-03 2.077E-03 1.656E-03 1.099E-03 5.718E-04 1.454E-04 2.837E-03 2.746E-03 2.483E-03 2.074E-03 1.567E-03 1.028E-03 5.396E-04 1.944E-04 5.611E-05 8.121E-06 4.195E-04 4.106E-04 3.842E-04 3.414E-04 2.840E-04 2.152E-04 1.407E-04 7.017E-05 2.689E-05 4.509E-06 1.107E-04 1.097E-04 1.068E-04 1.016E-04 9.392E-05 8.299E-05 6.775E-05 4.673E-05 2.556E-05 7.133E-06 1.380 = Current altitude in km 5.593E-01 5.556E-01 5.444E-01 5.247E-01 4.947E-01 4.507E-01 3.863E-01 2.892E-01 1.760E-01 5.427E-02 2.329E-03 2.298E-03 2.203E-03 2.042E-03 1.811E-03 1.505E-03 1.122E-03 6.743E-04 3.128E-04 6.563E-05 3.016E-03 2.988E-03 2.900E-03 2.749E-03 2.524E-03 2.207E-03 1.773E-03 1.190E-03 6.270E-04 1.609E-04 3.015E-03 2.920E-03 2.644E-03 2.215E-03 1.681E-03 1.109E-03 5.887E-04 2.158E-04 6.364E-05 9.454E-06 4.437E-04 4.345E-04 4.071E-04 3.627E-04 3.029E-04 2.310E-04 1.524E-04 7.716E-05 3.009E-05 5.169E-06 1.157E-04 1.148E-04 1.118E-04 1.066E-04 9.883E-05 8.772E-05 7.213E-05 5.031E-05 2.789E-05 7.835E-06 1.840 = Current altitude in km 5.782E-01 5.746E-01 5.635E-01 5.440E-01 5.141E-01 4.702E-01 4.056E-01 3.069E-01 1.897E-01 5.904E-02 2.451E-03 2.419E-03 2.322E-03 2.157E-03 1.920E-03 1.605E-03 1.206E-03 7.338E-04 3.445E-04 7.312E-05 3.162E-03 3.133E-03 3.045E-03 2.892E-03 2.664E-03 2.341E-03 1.894E-03 1.286E-03 6.856E-04 1.769E-04 3.200E-03 3.101E-03 2.811E-03 2.361E-03 1.799E-03 1.196E-03 6.407E-04 2.385E-04 7.141E-05 1.082E-05 4.685E-04 4.589E-04 4.307E-04 3.846E-04 3.224E-04 2.473E-04 1.647E-04 8.451E-05 3.341E-05 5.848E-06 1.209E-04 1.199E-04 1.169E-04 1.117E-04 1.039E-04 9.263E-05 7.671E-05 5.412E-05 3.039E-05 8.570E-06 2.350 = Current altitude in km 5.974E-01 5.939E-01 5.829E-01 5.636E-01 5.340E-01 4.904E-01 4.257E-01 3.258E-01 2.046E-01 6.425E-02 2.572E-03 2.540E-03 2.441E-03 2.273E-03 2.031E-03 1.706E-03 1.292E-03 7.955E-04 3.775E-04 8.077E-05 3.307E-03 3.278E-03 3.190E-03 3.036E-03 2.805E-03 2.477E-03 2.019E-03 1.386E-03 7.476E-04 1.934E-04 3.389E-03 3.285E-03 2.983E-03 2.512E-03 1.922E-03 1.285E-03 6.952E-04 2.622E-04 7.936E-05 1.221E-05 4.934E-04 4.836E-04 4.544E-04 4.068E-04 3.424E-04 2.641E-04 1.774E-04 9.214E-05 3.685E-05 6.538E-06 1.261E-04 1.251E-04 1.221E-04 1.169E-04 1.090E-04 9.763E-05 8.142E-05 5.811E-05 3.305E-05 9.333E-06 2.910 = Current altitude in km 6.169E-01 6.134E-01 6.026E-01 5.836E-01 5.543E-01 5.111E-01 4.466E-01 3.458E-01 2.209E-01 7.003E-02 2.694E-03 2.661E-03 2.561E-03 2.390E-03 2.143E-03 1.810E-03 1.382E-03 8.602E-04 4.124E-04 8.867E-05 3.452E-03 3.423E-03 3.335E-03 3.180E-03 2.948E-03 2.615E-03 2.148E-03 1.492E-03 8.140E-04 2.106E-04 3.582E-03 3.474E-03 3.159E-03 2.667E-03 2.049E-03 1.379E-03 7.528E-04 2.874E-04 8.761E-05 1.363E-05 5.187E-04 5.086E-04 4.786E-04 4.294E-04 3.628E-04 2.814E-04 1.906E-04 1.002E-04 4.045E-05 7.246E-06 1.312E-04 1.303E-04 1.273E-04 1.221E-04 1.142E-04 1.027E-04 8.630E-05 6.231E-05 3.593E-05 1.014E-05 3.530 = Current altitude in km 6.368E-01 6.334E-01 6.228E-01 6.041E-01 5.754E-01 5.328E-01 4.687E-01 3.673E-01 2.389E-01 7.670E-02 2.818E-03 2.784E-03 2.683E-03 2.510E-03 2.258E-03 1.917E-03 1.476E-03 9.296E-04 4.505E-04 9.704E-05 3.599E-03 3.571E-03 3.482E-03 3.328E-03 3.094E-03 2.759E-03 2.283E-03 1.605E-03 8.871E-04 2.291E-04 3.783E-03 3.670E-03 3.343E-03 2.830E-03 2.184E-03 1.478E-03 8.148E-04 3.147E-04 9.644E-05 1.512E-05 5.446E-04 5.343E-04 5.034E-04 4.528E-04 3.840E-04 2.996E-04 2.046E-04 1.088E-04 4.434E-05 7.989E-06 1.365E-04 1.355E-04 1.326E-04 1.274E-04 1.195E-04 1.080E-04 9.142E-05 6.681E-05 3.911E-05 1.103E-05 4.210 = Current altitude in km 6.569E-01 6.536E-01 6.433E-01 6.250E-01 5.969E-01 5.550E-01 4.917E-01 3.902E-01 2.588E-01 8.447E-02 2.943E-03 2.909E-03 2.807E-03 2.632E-03 2.376E-03 2.029E-03 1.574E-03 1.004E-03 4.925E-04 1.060E-04 3.747E-03 3.719E-03 3.631E-03 3.477E-03 3.243E-03 2.906E-03 2.424E-03 1.725E-03 9.679E-04 2.493E-04 3.992E-03 3.875E-03 3.534E-03 3.000E-03 2.325E-03 1.585E-03 8.818E-04 3.447E-04 1.060E-04 1.668E-05 5.711E-04 5.605E-04 5.289E-04 4.769E-04 4.060E-04 3.186E-04 2.195E-04 1.181E-04 4.859E-05 8.775E-06 1.417E-04 1.408E-04 1.379E-04 1.327E-04 1.249E-04 1.135E-04 9.674E-05 7.161E-05 4.262E-05 1.202E-05 O3 Column =0.285 Albedo =0.040 Haze O.D. =0.094 0.000 = Current altitude in km 4.655E-01 4.615E-01 4.493E-01 4.279E-01 3.958E-01 3.499E-01 2.855E-01 1.957E-01 1.048E-01 2.871E-02 1.688E-03 1.660E-03 1.576E-03 1.435E-03 1.237E-03 9.833E-04 6.824E-04 3.626E-04 1.414E-04 2.142E-05 2.240E-03 2.212E-03 2.129E-03 1.987E-03 1.780E-03 1.498E-03 1.132E-03 6.858E-04 3.159E-04 6.495E-05 2.098E-03 2.025E-03 1.815E-03 1.492E-03 1.098E-03 6.883E-04 3.334E-04 1.009E-04 2.101E-05 1.716E-06 3.162E-04 3.086E-04 2.863E-04 2.503E-04 2.029E-04 1.473E-04 8.961E-05 3.896E-05 1.193E-05 1.254E-06 8.857E-05 8.761E-05 8.467E-05 7.961E-05 7.213E-05 6.180E-05 4.802E-05 3.042E-05 1.483E-05 3.488E-06 0.150 = Current altitude in km 5.004E-01 4.963E-01 4.839E-01 4.623E-01 4.296E-01 3.828E-01 3.163E-01 2.220E-01 1.237E-01 3.1E-02 1.870E-03 1.841E-03 1.752E-03 1.604E-03 1.394E-03 1.123E-03 7.976E-04 4.424E-04 1.847E-04 3.188E-05 2.473E-03 2.445E-03 2.359E-03 2.211E-03 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### Contributions By Type Contributions By Source Area

Receptor 

### = HourlyPeak Time 

### = 16 To 17 Date 

### = 8/28/87 Scenario 

### = Evaluation Test Total Ozone 

### = 183 ppb 

### Detailed Ozone Apportionment

Source Emission Percent Ozone from Time Recirculation

Area Group NOx VOC Total Emitted Likely

IC 12% BC 14%

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Initial IC 12%

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6*8?Y?6(&:3'  CAMx, SOURCE APPORTIONMENT, VERSION -- 960315 , Mon Oct 26 10:37:34 1998 ,

File Duration , 87238, 15.00, 87238, 24.00, Average Interval , 1.0000
Number of timing periods , 2 Number of source areas , 17 Number of emission groupings , 1 Number of tracer species , 144 Number of NOx species , 19 Number of VOC species , 19 Number of O3N species , 19 Number of O3V species , 19 Number of INERT TIME species , 34 Number of DECAY TIME species , 34

Tracer Names, NOX000IC ,NOX000BC ,NOX001001,NOX001002,NOX001003,NOX001004,NOX001005 .. VOC000IC ,VOC000BC ,VOC001001,VOC001002,VOC001003,VOC001004,VOC001005 .. O3N000IC ,O3N000BC ,O3N001001,O3N001002,O3N001003,O3N001004,O3N001005 .. O3V000IC ,O3V000BC ,O3V001001,O3V001002,O3V001003,O3V001004,O3V001005 .. I23815001,I23815002,I23815003,I23815004,I23815005,I23815006,I23815007 .. D23815001,D23815002,D23815003,D23815004,D23815005,D23815006,D23815007 ..

Number of receptors , 6 No, Name, Type, Xloc, Yloc, 1, HourlyPeak, 1, , , 2, Rubidoux , 0, 461.5, 3762.0, 3, Pasadena , 0, 396.4, 3778.5, 4, Lennox , 0, 373.0, 3755.0, 5, Peak , 1, 45, 18, 6, Region 10 , 8, 31, 19, 32, 19 33, 19 34, 19, 31, 18, 32, 18, 33, 18, 34, 18,

Time Varying Tracer Data,

Data for Period, 87238, 15.00, 87238, 16.00, Receptor, 1, 1.3265E-02, 1.3544E-09, 1.0000E-16, 1.0974E-15, 1.0000E-16, 1.0000E-16 .. 1.2237E-01, 3.3869E-08, 1.0000E-16, 1.6165E-14, 1.0000E-16, 1.0000E-16 .. 8.7304E-02, 1.1926E-08, 1.0000E-16, 1.0000E-16, 1.0000E-16, 1.0000E-16 .. 9.0300E-02, 1.5269E-08, 1.0188E-16, 2.6997E-15, 1.0213E-16, 1.0162E-16 .. 1.0036E-16, 4.0640E-15, 1.0036E-16, 1.0036E-16, 1.0036E-16, 1.0029E-16 .. 1.0000E-16, 3.7563E-15, 1.0000E-16, 1.0000E-16, 1.0000E-16, 1.0000E-16 .. 1.4500E-02, 1.2663E-01, 1.7770E-01, 1.4500E-02, 1.2663E-01, 1.7770E-01, Receptor, 2, (File continues with data for remaining receptors and hours)

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Rxn Reactants Products k(298) (ppm -n min -1 ) E/R
1 NO2 = 1 NO 1 O photolysis 2 O = 1 O3 4323300 -1175 3 O3 NO = 1 NO2 26.64 1370 4 O NO2 = 1 NO 13750 5 O NO2 = 1 NO3 2309 -687 6 O NO = 1 NO2 2438 -602 7 NO2 O3 = 1 NO3 0.04731 2450 8 O3 = 1 O photolysis 9 O3 = 1 O1D photolysis 10 O1D = 1 O 4.25E+10 -390 11 O1D H2O = 2 OH 326000 12 O3 OH = 1 HO2 100 940 13 O3 HO2 = 1 OH 2.999 580 14 NO3 = 0.89 NO2 0.89 O 0.11 NO photolysis 15 NO3 NO = 2 NO2 44167 -250 16 NO3 NO2 = 1 NO 1 NO2 0.5901 1230 17 NO3 NO2 = 1 N2O5 1853 -256 18 N2O5 H2O = 2 HNO3 1.9E-06 19 N2O5 = 1 NO3 1 NO2 2.776 10897 20 NO NO = 2 NO2 0.000154 -530 21 NO NO2 H2O 0 2 HNO2 1.6E-11 22 NO OH = 1 HNO2 9799 -806 23 HNO2 = 1 NO 1 OH photolysis 24 OH HNO2 = 1 NO2 9770 25 HNO2 HNO2 = 1 NO 1 NO2 0.000015 26 NO2 OH = 1 HNO3 16817 -713 27 OH HNO3 = 1 NO3 217.9 -1000 28 HO2 NO = 1 OH 1 NO2 12270 -240 29 HO2 NO2 = 1 PNA 0 30 PNA = 1 HO2 1 NO2 0 31 OH PNA = 1 NO2 0 32 HO2 HO2 = 1 H2O2 4144 -1150 33 HO2 HO2 H2O = 1 H2O2 0.2181 -5800 34 H2O2 = 2 OH photolysis 35 OH H2O2 = 1 HO2 2520 187 36 OH CO = 1 HO2 322 37 FORM OH = 1 HO2 1 CO 15000 38 FORM = 2 HO2 1 CO photolysis 39 FORM = 1 CO photolysis 40 FORM O = 1 OH 1 HO2 1 CO 237 1550 41 FORM NO3 = 1 HNO3 1 HO2 1 CO 0.93 42 ALD2 O = 1 C2O3 1 OH 636 986 43 ALD2 OH = 1 C2O3 24000 -250 44 ALD2 NO3 = 1 C2O3 1 HNO3 3.7 45 ALD2 = 1 FORM 2 HO2 1 CO photolysis 1 XO2 46 C2O3 NO = 1 FORM 1 NO2 1 HO2 28200 180 1 XO2 47 C2O3 NO2 = 1 PAN 13700 -380 48 PAN = 1 C2O3 1 NO2 0.0254 13500Rxn Reactants Products k(298) (ppm -n min -1 ) E/R

49 C2O3 C2O3 = 2 FORM 2 XO2 2 HO2 3700 50 C2O3 HO2 = 0.79 FORM 0.79 XO2 0.79 HO2 9600 0.79 OH 51 OH = 1 FORM 1 XO2 1 HO2 21 1710 52 PAR OH = 0.87 XO2 0.13 XO2N 0.11 HO2 1203 0.11 ALD2 -0.11 PAR 0.76 ROR 53 ROR = 0.96 XO2 1.1 ALD2 0.94 HO2 137100 8000 -2.1 PAR 0.04 XO2N 54 ROR = 1 HO2 95450 55 ROR NO2 = 1 NTR 22000 56 O OLE = 0.63 ALD2 0.38 HO2 0.28 XO2 5920 324 0.3 CO 0.2 FORM 0.02 XO2N 0.22 PAR 0.2 OH 57 OH OLE = 1 FORM 1 ALD2 -1 PAR 42000 -504 1 XO2 1 HO2 58 O3 OLE = 0.5 ALD2 0.74 FORM 0.22 XO2 0.018 2105 0.1 OH 0.33 CO 0.44 HO2

-1 PAR 59 NO3 OLE = 0.91 XO2 1 FORM 0.09 XO2N 11.35 1 ALD2 1 NO2 -1 PAR 60 O ETH = 1 FORM 1.7 HO2 1 CO 1080 792 0.7 XO2 0.3 OH 61 OH ETH = 1 XO2 1.56 FORM 0.22 ALD2 11920 -411 1 HO2 62 O3 ETH = 1 FORM 0.42 CO 0.12 HO2 0.0027 2633 63 TOL OH = 0.44 HO2 0.08 XO2 0.36 CRES 9150 -322 0.56 TO2 64 TO2 NO = 0.9 NO2 0.9 HO2 0.9 OPEN 12000 0.1 NTR 65 TO2 = 1 CRES 1 HO2 250 66 OH CRES = 0.4 CRO 0.6 XO2 0.6 HO2 61000 0.3 OPEN 67 CRES NO3 = 1 CRO 1 HNO3 32500 68 CRO NO2 = 1 NTR 20000 69 OPEN = 1 C2O3 1 HO2 1 CO photolysis 70 OPEN OH = 1 XO2 2 CO 2 HO2 44000 1 C2O3 1 FORM 71 OPEN O3 = 0.03 ALD2 0.62 C2O3 0.7 FORM 0.015 500 0.03 XO2 0.69 CO 0.08 OH 0.76 HO2 0.2 MGLY 72 OH XYL = 0.7 HO2 0.5 XO2 0.2 CRES 36200 -116 0.8 MGLY 1.1 PAR 0.3 TO2 73 OH MGLY = 1 XO2 1 C2O3 26000 74 MGLY = 1 C2O3 1 HO2 1 CO photolysis 75 O ISOP = 0.75 ISPD 0.5 FORM 0.25 XO2 53200 0.25 HO2 0.25 C2O3 0.25 PAR 76 OH ISOP = 0.912 ISPD 0.629 FORM 0.991 XO2 147600 0.912 HO2 0.088 XO2N 77 O3 ISOP = 0.65 ISPD 0.6 FORM 0.2 XO2 0.019 0.066 HO2 0.266 OH 0.2 C2O3

0.15 ALD2 0.35 PAR 0.066 CO 78 NO3 ISOP = 0.2 ISPD 0.8 NTR 1 XO2 996 0.8 HO2 0.2 NO2 0.8 ALD2Rxn Reactants Products k(298) (ppm -n min -1 ) E/R

2.4 PAR 79 XO2 NO = 1 NO2 12000 80 XO2 XO2 = 2000 -1300 81 XO2N NO = 1 NTR 12000 82 SO2 OH = 1 SULF 1 HO2 1110 -160 83 SO2 = 1 SULF 8.17E-05 84 MEOH OH = 1 FORM 1 HO2 1600 85 ETOH OH = 1 HO2 1 ALD2 4300 -176 86 XO2 HO2 = 8900 -1300 87 XO2N HO2 = 8900 -1300 88 XO2N XO2N = 2000 -1300 89 XO2 XO2N = 4000 -1300 90 OH HO2 = 162600 -250 91 CRO = 0.000278 92 OH ISPD = 1.565 PAR 0.167 FORM 0.713 XO2 49667 0.503 HO2 0.334 CO 0.168 MGLY 0.273 ALD2 0.498 C2O3 93 O3 ISPD = 0.114 C2O3 0.15 FORM 0.85 MGLY 0.0105 0.154 HO2 0.268 OH 0.064 XO2

0.02 ALD2 0.36 PAR 0.225 CO 94 NO3 ISPD = 0.357 ALD2 0.282 FORM 1.282 PAR 1.478 0.925 HO2 0.643 CO 0.85 NTR 0.075 C2O3 0.075 XO2 0.15 HNO3 95 ISPD = 0.333 CO 0.067 ALD2 0.9 FORM photolysis 0.832 PAR 1.033 HO2 0.7 XO2 0.967 C2O3 96 NO2 ISOP = 0.2 ISPD 0.8 NTR 1 XO2 0.00022 0.8 HO2 0.2 NO 0.8 ALD2 2.4 PAR$33(1',;%

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Little data exists for the distribution of monoterpenes in the atmosphere, so the lumping scheme for monoterpenes was based on guidance from Dr. Alex Guenther of NCAR

% the developer of the BEIS series of biogenic emissions models. For many areas and tree species, data suggest that -pinene,  -pinene, and -carene are the dominate emitted species. He recommended using 30 percent each for  -pinene and  -pinene; 15 percent for -carene; 5 percent each for sabinene, limonene, and  -phellandrene; and 10 percent for other terpenes. Not all of these species have unique kinetic and mechanistic data in the SAPRC database. Hence, the kinetic and mechanistic parameters for the lumped monoterpenes (OLE3) assuming a mixture of 30 percent  -pinene, 30 percent  -pinene, 20 percent -carene, and 20 percent limonene on a carbon basis.

The SAPRC97 mechanism implemented in CAMx is listed in Table B-1 and the species in the mechanism are identified in Table B-2. The mechanism has 184 reactions and 76 species. In CAMx, 39 species are treated as state species, 33 are treated as radicals, and 4 are treated as constants [water vapor, methane, O 2 , and air (M)]. The reaction rate constants shown in Table B1 are for 298 K and 1 atmosphere pressure. Many of the rate constants are temperature dependant, and some are pressure dependant (see the listing of the SAPRC97 chemistry parameters file in Section 3).
In its original form, the SAPRC97 mechanism uses species names which contain more than four characters. Species names used in CAMx have conventionally had names limited to four characters and there are advantages to maintaining this convention. Therefore the longer SAPRC species names were condensed for CAMx as shown in Table B-2.

USING THE SAPRC97 MECHANISM
The SAPRC97 mechanism is invoked by using the chemistry parameters file for mechanism 5 (CAMx3.chemparm.5). Note that input files containing information by chemical species (emissions, initial conditions, boundary conditions) must be matched to the chemical mechanism. You can not switch between CB4 and SAPRC97 simply by changing the chemistry parameters file.

PHOTOLYSIS RATES FOR THE SAPRC97 MECHANISM
Input of photolysis rate information to CAMx is described in Section 3. Briefly, photolysis rates for several (usually 6) primary photolysis reactions are input via an extensive look-up table. Other photolysis rates for so-called secondary photolysis reactions are set by scaling factors relative to one of the primary reactions. The scalar relationships between secondary and primary photolysis reactions are defined in the chemistry parameters file.
The chemistry parameters file supplied for the SAPRC97 mechanism has been set up with six primary photolysis reactions. These are the same six primary photolysis reactions as used with the CB4 mechanism, although the reactions are numbered differently in the two mechanisms. Therefore, you can run the SAPRC97 mechanism using a photolysis rate look-up table developed for the CB4 mechanism. Alternatively, you can use version 4 of the TUV (Madronich, 1999) photolysis rate preprocessor for CAMx (available from the CAMx ftp site) to prepare photolysis rate look-up tables specifically for the SAPRC mechanism. Version 4 of TUV for CAMx includes the database of cross-section and quantum yield data used in the development of theSAPRC97 mechanism. Note that these data are not included with the standard distribution of TUV from NCAR (Madronich, 1999).

EMISSIONS PREPARATION FOR SAPRC97
Emission inventories for the CAMx SAPRC mechanism can be prepared using standard emissions processing software, such as EPS2, EMS95 or SMOKE. The only difference in preparing emissions for the SAPRC or CB4 mechanism is in the assignment of total VOC emissions to the chemical species in the mechanism

% the chemical speciation step. EPS2 and EMS95 include chemical speciation databases for the CB4 mechanism, but may not include databases for SAPRC. Even if a SAPRC speciation database is included, it may not be matched to the lumping scheme used in the CAMx SAPRC97 mechanism. Speciation data are provided in two files available from the CAMx ftp site:

 The speciation profile library (camx.saprc97.profile.asc). This contains assignments from total VOC to SAPRC species for each species profile. A section of the file is shown in Table B-3.

 Speciation profile cross-reference (camx.saprc97.profile.xref.asc). This contains a crossreference from source category code to species profile code for the profiles included in the speciation profile library (above). A section of the file is shown in Table B-4.Table B-1. Listing of CAMx3 mechanism 5: SAPRC97.

Rxn Reactants Products k(298) (ppm -n min -1 ) 1 NO2 = 1 NO 1 O photolysis 2 O O2 M = 1 O3 2.218E-05 3 O NO2 = 1 NO 1 O2 14368 4 O NO2 = 1 NO3 2327.7 5 O3 NO = 1 NO2 1 O2 26.937 6 O3 NO2 = 1 O2 1 NO3 0.047023 7 NO NO3 = 2 NO2 41551 8 NO NO O2 = 2 NO2 7.063E-10 9 NO2 NO3 = 1 N2O5 1868.6 10 N2O5 = 1 NO2 1 NO3 3.2825 11 N2O5 H2O = 2 HNO3 1.478E-06 12 NO2 NO3 = 1 NO 1 NO2 1 O2 0.59969 13 NO3 = 1 NO 1 O2 photolysis 14 NO3 = 1 NO2 1 O photolysis 15 O3 = 1 O 1 O2 photolysis 16 O3 = 1 O1D 1 O2 photolysis 17 O1D H2O = 2 OH 325070 18 O1D M = 1 O 43283 19 OH NO = 1 HNO2 7199.1 20 HNO2 = 1 OH 1 NO photolysis 21 OH NO2 = 1 HNO3 16977 22 OH HNO3 = 1 H2O 1 NO3 154.96 23 OH CO = 1 HO2 354.66 24 OH O3 = 1 HO2 1 O2 100.56 25 HO2 NO = 1 OH 1 NO2 12316 26 HO2 NO2 = 1 PNA 0 27 PNA = 1 HO2 1 NO2 0 28 PNA OH = 1 H2O 1 NO2 1 O2 0 29 HO2 O3 = 1 OH 2 O2 3.0367 30 HO2 HO2 = 1 H2O2 1 O2 2594.7 31 HO2 HO2 M = 1 H2O2 1 O2 0.0018598 32 HO2 HO2 H2O = 1 H2O2 1 O2 1 H2O 0.14426 33 HO2 HO2 H2O = 1 H2O2 1 O2 1 H2O 0.10351 34 NO3 HO2 = 1 HNO3 1 O2 2594.7 35 NO3 HO2 M = 1 HNO3 1 O2 0.0018598 36 NO3 HO2 H2O = 1 HNO3 1 O2 1 H2O 0.14426 37 NO3 HO2 H2O = 1 HNO3 1 O2 1 H2O 0.10351 38 H2O2 = 2 OH photolysis 39 H2O2 OH = 1 HO2 1 H2O 2492.5 40 OH HO2 = 1 H2O 1 O2 147070 41 RO2 NO = 1 NO 11393 42 RCO3 NO = 1 NO 33586 43 RCO3 NO2 = 1 NO2 15454 44 RO2 HO2 = 1 HO2 7361.8 45 RCO3 HO2 = 1 HO2 7361.8 46 RO2 RO2 = 1.4779 47 RO2 RCO3 = 16273 48 RCO3 RCO3 = 24499Rxn Reactants Products k(298) (ppm -n min -1 ) 49 RO2R NO = 1 NO2 1 HO2 11393 50 RO2R HO2 = 1 OOH 7361.8 51 RO2R RO2 = 1 RO2 0.5 HO2 1.4779 52 RO2R RCO3 = 1 RCO3 0.5 HO2 16273 53 RO2N NO = 1 RNO3 11393 54 RO2N HO2 = 1 OOH 1 MEK 7361.8 55 RO2N RO2 = 1 RO2 0.5 HO2 1 MEK 1.4779 56 RO2N RCO3 = 1 RCO3 0.5 HO2 1 MEK 16273 57 R2O2 NO = 1 NO2 11393 58 R2O2 HO2 = 7361.8 59 R2O2 RO2 = 1 RO2 1.4779 60 R2O2 RCO3 = 1 RCO3 16273 61 RO2Q NO = 1 XN 11393 62 RO2Q HO2 = 1 OOH 7361.8 63 RO2Q RO2 = 1 RO2 0.5 HO2 1.4779 64 RO2Q RCO3 = 1 RCO3 1 HO2 16273 65 RO2W NO = 1 NPHE 11393 66 RO2W HO2 = 1 OOH 7361.8 67 RO2W RO2 = 1 RO2 0.5 HO2 1.4779 68 RO2W RCO3 = 1 RCO3 1 HO2 16273 69 OOH = 1 HO2 1 OH photolysis 70 OH OOH = 1 OH 2679.1 71 OH OOH = 1 RO2R 1 RO2 5516.9 72 FORM = 2 HO2 1 CO photolysis 73 FORM = 1 CO photolysis 74 FORM OH = 1 HO2 1 CO 1 H2O 14428 75 FORM HO2 = 1 HOCQ 116.75 76 HOCQ = 1 HO2 1 FORM 9053.5 77 HOCQ NO = 1 NO2 1 HO2 11393 78 FORM NO3 = 1 HNO3 1 HO2 1 CO 0.89129 79 CCHO OH = 1 CCO3 1 H2O 1 RCO3 23289 80 CCHO = 1 CO 1 HO2 1 FORM photolysis 1 RO2R 1 RO2 81 CCHO NO3 = 1 HNO3 1 CCO3 1 RCO3 4.0274 82 RCHO OH = 1 C2CQ 1 RCO3 29267 83 RCHO = 1 CCHO 1 RO2R 1 RO2 photolysis 1 CO 1 HO2 84 NO3 RCHO = 1 HNO3 1 C2CQ 1 RCO3 4.0274 85 ACET OH = 1 R2O2 1 FORM 1 CCO3 324.17 1 RCO3 1 RO2 86 ACET = 1 CCO3 1 FORM 1 RO2R photolysis 1 RCO3 1 RO2 87 MEK OH = 1 H2O 0.5 CCHO 0.5 FORM 1708 0.5 CCO3 0.5 C2CQ 1 RCO3 1.5 R2O2 1.5 RO2 88 MEK = 1 CCO3 1 CCHO 1 RO2R photolysis 1 RCO3 1 RO2 89 RNO3 OH = 1 NO2 0.155 MEK 1.05 RCHO 2998.8 0.48 CCHO 0.16 FORM 1.39 R2O2 1.39 RO2Rxn Reactants Products k(298) (ppm -n min -1 ) 90 CCO3 NO = 1 NO2 1 FORM 1 RO2R 33586 1 RO2 91 CCO3 NO2 = 1 PAN 15454 92 CCO3 HO2 = 1 OOH 1 FORM 7361.8 93 CCO3 RO2 = 1 RO2 0.5 HO2 1 FORM 16273 94 CCO3 RCO3 = 1 RCO3 1 HO2 1 FORM 24499 95 PAN = 1 CCO3 1 NO2 1 RCO3 0.028897 96 C2CQ NO = 1 CCHO 1 RO2R 1 NO2 33586 1 RO2 97 C2CQ NO2 = 1 PPN 12413 98 C2CQ HO2 = 1 OOH 1 CCHO 7361.8 99 C2CQ RO2 = 1 RO2 0.5 HO2 1 CCHO 16273 100 C2CQ RCO3 = 1 RCO3 1 HO2 1 CCHO 24499 101 PPN = 1 C2CQ 1 NO2 1 RCO3 0.029702 102 C2CO NO2 = 1 RNO3 35466 103 C2CO = 1 ACET 1 FORM 1 RO2R 59263 1 RO2 104 GLY = 0.8 HO2 0.45 FORM 1.55 CO photolysis 105 GLY = 0.13 FORM 1.87 CO photolysis 106 GLY OH = 0.6 HO2 1.2 CO 0.4 HCOQ 16842 0.4 RCO3 107 GLY NO3 = 1 HNO3 0.6 HO2 1.2 CO 4.0274 0.4 HCOQ 0.4 RCO3 108 HCOQ NO = 1 NO2 1 CO 1 HO2 33586 109 HCOQ NO2 = 1 GPAN 15454 110 GPAN = 1 HCOQ 1 NO2 1 RCO3 0.028897 111 HCOQ HO2 = 1 OOH 1 CO 7361.8 112 HCOQ RO2 = 1 RO2 0.5 HO2 1 CO 16273 113 HCOQ RCO3 = 1 RCO3 1 HO2 1 CO 24499 114 MGLY = 1 HO2 1 CO 1 CCO3 photolysis 1 RCO3 115 MGLY = 1 HO2 1 CO 1 CCO3 photolysis 1 RCO3 116 MGLY OH = 1 CO 1 CCO3 1 RCO3 25419 117 MGLY NO3 = 1 HNO3 1 CO 1 CCO3 4.0274 1 RCO3 118 OH PHEN = 0.15 RO2W 0.85 RO2R 0.2 GLY 38869 1 RO2 119 NO3 PHEN = 1 HNO3 1 BZO 5319.5 120 OH CRES = 0.15 RO2W 0.85 RO2R 0.2 MGLY 62064 1 RO2 121 NO3 CRES = 1 HNO3 1 BZO 31037 122 BALD OH = 1 BZCQ 1 RCO3 19067 123 BALD = photolysis 124 BALD NO3 = 1 HNO3 1 BZCQ 3.6909 125 BZCQ NO = 1 BZO 1 NO2 1 R2O2 33586 1 RO2 126 BZCQ NO2 = 1 PBZN 12413 127 BZCQ HO2 = 1 OOH 1 PHEN 7361.8 128 BZCQ RO2 = 1 RO2 0.5 HO2 1 PHEN 16273Rxn Reactants Products k(298) (ppm -n min -1 ) 129 BZCQ RCO3 = 1 RCO3 1 HO2 1 PHEN 24499 130 PBZN = 1 BZCQ 1 NO2 1 RCO3 0.0097375 131 BZO NO2 = 1 NPHE 52565 132 BZO HO2 = 1 PHEN 7361.8 133 BZO = 1 PHEN 0.06 134 NPHE NO3 = 1 HNO3 1 BZNQ 5319.5 135 BZNQ NO2 = 2 XN 52565 136 BZNQ HO2 = 1 NPHE 7361.8 137 BZNQ = 1 NPHE 0.06 138 OH AFG1 = 1 HCOQ 1 RCO3 16842 139 AFG1 = 1 HO2 1 HCOQ 1 RCO3 photolysis 140 OH AFG2 = 1 C2CQ 1 RCO3 25419 141 AFG2 = 1 HO2 1 CO 1 CCO3 photolysis 1 RCO3 142 CH4 OH = 1 FORM 1 RO2R 1 RO2 12.351 143 HCHQ = 0.12 OH 0.12 HO2 0.12 CO 60 144 CCHQ = 0.15 CH4 0.6 OH 0.3 CCO3 60 0.3 RCO3 0.3 RO2R 0.3 FORM 0.3 CO 0.3 RO2 145 RCHQ = 0.6 OH 0.3 C2CQ 0.3 RCO3 60 0.3 RO2R 0.3 CCHO 0.3 CO 0.3 RO2 146 C3O2 = 1 OH 1 R2O2 1 FORM 60 1 CCO3 1 RCO3 1 RO2 147 CRCQ = 1 OH 1 CCO3 1 CCHO 60 1 R2O2 1 RCO3 1 RO2 148 BZCW = 0.5 BZO 0.5 R2O2 0.5 CO 60 0.5 OH 149 ETH OH = 1 RO2R 1 RO2 1.56 FORM 12594 0.22 CCHO 150 ETH O3 = 1 FORM 1 HCHQ 0.0023478 151 ETH NO3 = 1 R2O2 1 RO2 2 FORM 0.29688 1 NO2 152 ETH O = 1 RO2R 1 HO2 1 RO2 1077.7 1 FORM 1 CO 153 OH ALK1 = 0.849 RO2R 0.072 RO2N 0.005 RO2Q 4690.3 0.023 HO2 0.49 R2O2 1.415 RO2 0.023 FORM 0.297 CCHO 0.208 RCHO 0.245 ACET 0.437 MEK 0.034 CO 0.054 GLY 0.052 C2CO 154 OH ALK2 = 0.723 RO2R 0.276 RO2N 0 RO2Q 15350 0.905 R2O2 1.905 RO2 0.051 FORM 0.009 CCHO 0.232 RCHO 1.072 MEK 0.087 CO 155 OH ARO1 = 0.742 RO2R 0.258 HO2 0.742 RO2 8487 0.017 PHEN 0.241 CRES 0.079 BALD 0.124 GLY 0.787 MGLY 0.104 AFG1 0.229 AFG2 156 OH ARO2 = 0.82 RO2R 0.18 HO2 0.82 RO2 41126 0.18 CRES 0.035 BALD 0.056 GLYRxn Reactants Products k(298) (ppm -n min -1 ) 1.004 MGLY 0.481 AFG2 157 OLE1 OH = 0.973 RO2R 0.027 RO2N 1 RO2 40000 0.973 FORM 0.844 CCHO 0.13 RCHO 158 OLE1 O3 = 0.6 FORM 0.337 CCHO 0.156 RCHO 0.01487 0.4 HCHQ 0.6 CCHQ 159 OLE1 O = 0.4 HO2 0.5 RCHO 0.5 MEK 5909.1 160 OLE1 NO3 = 1 NO2 1 R2O2 1 RO2 14.583 1 FORM 0.844 CCHO 0.156 RCHO 161 OLE2 OH = 0.904 RO2R 0.096 RO2N 1 RO2 93737 0.194 FORM 1.061 CCHO 0.355 RCHO 0.005 ACET 0.194 BALD 162 OLE2 O3 = 0.129 FORM 0.565 CCHO 0.217 RCHO 0.27095 0.002 ACET 0.086 BALD 0.086 HCHQ 0.564 CCHQ 0.217 RCHQ 0.004 C3O2 0.129 BZCW 163 OLE2 O = 0.4 HO2 0.5 RCHO 0.5 MEK 36982 164 OLE2 NO3 = 1 NO2 1 R2O2 1 RO2 579.7 0.215 FORM 1.129 CCHO 0.434 RCHO 0.006 ACET 0.215 BALD 165 OLE3 OH = 0.75 RO2R 0.25 RO2N 1 RO2 134970 0.3 FORM 0.225 RCHO 0.525 MEK 166 OLE3 O3 = 0.125 FORM 0.1 RCHO 0.275 MEK 0.11856 0.275 HCHQ 0.2 RCHQ 0.525 CRCQ 167 OLE3 O = 0.4 HO2 0.5 RCHO 0.5 MEK 69801 168 OLE3 NO3 = 1 NO2 1 R2O2 1 RO2 10123 0.4 FORM 0.3 RCHO 0.7 MEK 169 SO2 OH = 1 HO2 1323.6 170 ISOP OH = 0.088 RO2N 0.912 RO2R 0.629 FORM 147570 0.912 ISPD 0.079 R2O2 1.079 RO2 171 ISOP O3 = 0.4 FORM 0.6 ISPD 0.55 HCHQ 0.018995 0.2 C4O2 0.2 C4HQ 172 ISOP O = 0.75 ISPD 0.25 C2CQ 0.25 RCO3 53195 0.5 FORM 0.25 RO2R 0.25 RO2 173 ISOP NO3 = 0.8 RCHO 0.8 RNO3 0.8 RO2R 995.8 0.2 ISPD 0.2 R2O2 0.2 NO2

1 RO2 174 ISOP NO2 = 0.8 RCHO 0.8 RNO3 0.8 RO2R 0.0002217 0.2 ISPD 0.2 R2O2 0.2 NO

1 RO2 175 ISPD OH = 0.293 CO 0.252 CCHO 0.126 FORM 49651 0.041 GLY 0.021 RCHO 0.168 MGLY 0.314 MEK 0.503 RO2R 0.21 CCO3 0.288 C2CQ 0.21 R2O2 0.713 RO2 0.498 RCO3 176 ISPD O3 = 0.02 CCHO 0.04 FORM 0.01 GLY 0.01051 0.84 MGLY 0.09 MEK 0.66 HCHQ 0.09 HCOW 0.18 HOCW 0.06 C2OQ 0.01 C2OW 177 ISPD = 0.333 CO 0.067 CCHO 0.9 FORM photolysis 0.033 MEK 0.333 HO2 0.7 RO2RRxn Reactants Products k(298) (ppm -n min -1 ) 0.267 CCO3 0.7 C2CQ 0.7 RO2 0.967 RCO3 178 ISPD NO3 = 0.643 CO 0.282 FORM 0.85 RNO3 1.4779 0.357 RCHO 0.925 HO2 0.075 C2CQ 0.075 R2O2 0.925 RO2 0.075 RCO3 0.075 HNO3 179 C4O2 = 1 OH 1 R2O2 1 FORM 60 1 C2CQ 1 RO2 1 RCO3 180 C4HQ = 0.75 RCHO 0.25 ISPD 60 181 C2OQ = 1 OH 1 R2O2 1 FORM 60 1 HCOQ 1 RO2 1 RCO3 182 HOCW = 0.6 OH 0.3 CCO3 0.3 RCO3 60 0.3 RO2R 0.3 FORM 0.3 CO 0.3 RO2 183 HCOW = 0.12 HO2 0.24 CO 0.12 OH 60 0.51 FORM 184 C2OW = 1 OH 1 MGLY 1 HO2 60 1 R2O2 1 RO27DEOH% ,GHQWLW\RIVSHFLHVXVHGLQ&$0[PHFKDQLVP6$35&

SAPRC Name Short Name Definition Molecular Weight Carbon Atoms O3 Ozone 48 NO Nitrogen oxide 30.01 NO2 Nitrogen dioxide 46.01 NO3 Nitrogen trioxide radical 62.01 N2O5 Dinitrogen pentoxide 108.02 HO2 HO2 radical 33.01 RO2 Total alkyl peroxy radicals RCO3 Total peroxyacyl radicals CRES Cresol 108.14 7 HNO3 Nitric acid 63.02 HNO2 Nitrous acid 47.02 PNA Peroxynitric acid 79.02 XN Lumped other nitrogen species, such as C1-C3 organic nitrates and dinitrophenols CO Carbon monoxide 28.01 1 CO2 Carbon dioxide 42.02 SO2 Sulfur dioxide 64 SULF Sulfuric acid 98 H2O2 Hydrogen peroxide 34.02 OOH Chemical operator used to represent reactions at hydroperoxy groups FORM Formaldehyde 30.03 1 CCHO Acetaldehyde 44.05 2 RCHO Propionaldehyde and lumped higher aldehydes 58.08 3 ACET Acetone 58.08 3 MEK Methyl ethyl ketone 72.11 4 RNO3 Lumped organic nitrates 133.15 5 PAN Peroxy acetyl nitrate 121.05 2 PPN Peroxy propionyl nitrate and higher PAN analogues 135.08 3 GLY Glyoxal 58.04 2 MGLY Methyl glyoxal 72.07 3 PHEN Phenol 94.11 6 BALD Benzaldehyde 106.13 7 NPHE Nitrophenols and other aromatic nitro-compounds 139.11 6 AFG1 Unknown aromatic fragmentation product #1 58.04 2 AFG2 Unknown aromatic fragmentation product #2 72.07 3 GPAN PAN analogue formed from glyoxal 135.04 2 PBZN Peroxy benzoyl nitrate 183.13 7 ETH Ethene 28.05 2 ALK1 Lumped alkanes with kHO <10,000 ppm-1 min-1 65.44 4.55 ALK2 Lumped alkanes with kHO ? 10,000 ppm-1 min-1 125.1 8.82 ARO1 Lumped aromatic hydrocarbons with kHO < 20,000 ppm-1 min-1 93.52 7.1 ARO2 Lumped aromatic hydrocarbons with kHO ? 20,000 ppm-1 min-1 117.7 8.82 OLE1 Lumped anthropogenic alkenes with kHO < 75,000 ppm-1 min-1 46.9 3.34 OLE2 Lumped anthropogenic alkenes with kHO ? 75,000 ppm-1 min-1 73.99 5.4 OLE3 Lumped biogenic monoterpenes 136.24 10 ISOP Isoprene 68.12 5 ISPD Lumped isoprene products, including mathacrolein, methyl vinyl ketone, and unsaturated aldehydes 54 4
HO Hydroxyl radicals O Ground state oxygen atomsSAPRC Name Short Name Definition Molecular Weight Carbon Atoms O1D Excited oxygen atoms RO2R Chemical operator used to represent NO to NO2 conversion with generation of HO2 radicals RO2N Chemical operator used to represent NO consumption and alkyl nitrate formation R2O2 Chemical operator used to represent NO to NO2 conversion RO2XN RO2Q Chemical operator used to represent NO sink reactions RO2NP RO2W Chemical operator used to represent NO consumption and nitrophenol formation HOCOO HOCQ Intermediate formed in the HCHO + HO2 reaction BZO Phenoxy radicals BZNO2O BZNQ Phenoxy-type radicals containing nitro-groups CCO3 Peroxy acetyl radicals C2CO3 C2CQ Higher peroxy acetyl radicals HCOCO3 HCOQ Peroxyacyl radical formed from glyoxal BZCO3 BZCQ Peroxyacyl radical formed from benzaldehyde C2CO T-butoxy radical HCHO2 HCHQ C1 Creigee bi-radical CCHO2 CCHQ C2 Creigee bi-radical RCHO2 RCHQ C3 Creigee bi-radical C3O2 Dimethyl substituted C3 Creigee bi-radical CRCO2 CRCQ General disttituted C3 Creigee bi-radical CYCCO2 CYCQ Creigee bi-radical from cyclic olefins BZCHO2 BZCW Creigee bi-radical from benzaldehyde C4O2 Creigee bi-radical from isoprene C4HO2 C4HQ Creigee bi-radical from isoprene C2O2CHO C2OQ Creigee bi-radical from isoprene HOCCHO2 HOCW Creigee bi-radical from isoprene HCOCHO2 HCOW Creigee bi-radical from isoprene C2O2COH C2OW Creigee bi-radical from isoprene CH4 Methane O2 Oxygen M Air H2O Water vapor7DEOH% ([DPSOHIURPDQ(06IRUPDW6$35&VSHFLDWLRQSURILOH OLEUDU\

7DEOH% ([DPSOHIURPDQ(06IRUPDWVSHFLDWLRQSURILOHFURVVUHIHUHQFH ILOH

INPRF, MECH, MDLSPAB, FACTOR, DIVISOR, POLID 0001 SAPRC ACET 0.0048216 1 TOG 0001 SAPRC ALK1 0.0028863 1 TOG 0001 SAPRC CH4 0.0068574 1 TOG 0001 SAPRC CO 1 28 CO 0001 SAPRC HCHO 0.013986 1 TOG 0001 SAPRC NO 0.5869565 30 NOX 0001 SAPRC NO2 0.1 46 NOX 0002 SAPRC ALK1 0.0068664 1 TOG 0002 SAPRC ALK2 0.0007008 1 TOG 0002 SAPRC CO 1 28 CO 0002 SAPRC HCHO 0.0162171 1 TOG 0002 SAPRC NO 0.5869565 30 NOX

(continued)

STID,CYID,FCID,DVID,PRID,SCC,TECHTYPE,INPRF . . 10100401 . 0001 . . 10100404 . 0001 . . 10100405 . 0001 . . 10100406 . 0001 . . 10100501 . 0002 . . 10100504 . 0002 . . 10100702 . 0004 . . 10100801 . 0005

(continued)5()(5(1&(6

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