## 6 5 4 3 2 1 Coal 0% 10% 50% 95% 95% 99% Bagasse 0% 10% 50% 95% 95% 99% Wet Biomass0% 10% 50% 95% 95% 99% Dry Biomass0% 10% 50% 95% 95% 99% Heavy Liquid0% 10% 50% 95% 95% 99% Light Liquid 0% 10% 50% 95% 95% 99% Gas 1 0% 10% 50% 95% 95% 99% Gas 2 0% 10% 50% 95% 95% 99% Coal 0% 9% 9%82.35%66.54%87.13% Bagasse 0% 0% 10% 75% 75%unknown Wet Biomass0% 0% 10% 75% 75%unknown Dry Biomass0% 0% 10% 75% 75%unknown Heavy Liquid0% 0% 10% 75% 75%unknown Light Liquid 0% 0% 10% 75% 75%unknown Gas 1 0% 0% 10% 75% 75%unknown Gas 2 0% 0% 10% 75% 75%unknown Coal 0%92.5%95% 95% 98% 99% Bagasse 0% 40% 90% 90% 98% 99% Wet Biomass0% 40% 90% 90% 98% 99% Dry Biomass0% 45% 85% 85% 98% 99% Heavy Liquid0% 80% 94% 94% 98% 99% Light Liquid 0% 80% 94% 94% 98% 99% Gas 1 0% 75% 50% 98% 98% 99% Gas 2 0% 75% 50% 98% 98% 99% Coal - 0% 0% 70% 95% 95% Bagasse - 0% 0% 70% 95% 95% Wet Biomass - 0% 0% 70% 95% 95% Dry Biomass - 0% 0% 70% 95% 95% Heavy Liquid - 0% 0% 70% 95% 95% Light Liquid - 0% 0% 70% 95% 95% Gas 1 - 0% 0% 70% 95% 95% Gas 2 - 0% 0% 70% 95% 95% Coal - 0% 0% 0% 43%43% Bagasse - 0% 0% 0% 43%43% Wet Biomass - 0% 0% 0% 43%43% Dry Biomass - 0% 0% 0% 43%43% Heavy Liquid - 0% 0% 0% 43%43% Light Liquid - 0% 0% 0% 43%43% Gas 1 - 0% 0% 0% 43%43% Gas 2 - 0% 0% 0% 43%43% 

# Appendix C: Estimated Emission Reductions for Baseline Emission FactorsPercent Reduction for Control Group:

Mercury (Hg)2-3



## Particulate Matter (PM)1



## Hydrogen Chloride (HCl)4-5



## Hydrogen Fluoride (HF)4-5 

## Fuel Category Metals (Sb, As, Be, Cd, Co, Cr, Pb, Mn, Ni, Se)1

## 6 5 4 3 2 1 

# Appendix C: Estimated Emission Reductions for Baseline Emission FactorsPercent Reduction for Control Group: Fuel Category Coal - 0% 0% 0% 87% 87% Bagasse - 0% 0% 0% 87% 87% Wet Biomass - 0% 0% 0% 87% 87% Dry Biomass - 0% 0% 0% 87% 87% Heavy Liquid - 0% 0% 0% 87% 87% Light Liquid - 0% 0% 0% 87% 87% Gas 1 - 0% 0% 0% 87% 87% Gas 2 - 0% 0% 0% 87% 87% Coal - 0% 0% 70% 95% 95% Bagasse - 0% 0% 70% 95% 95% Wet Biomass - 0% 0% 70% 95% 95% Dry Biomass - 0% 0% 70% 95% 95% Heavy Liquid - 0% 0% 70% 95% 95% Light Liquid - 0% 0% 70% 95% 95% Gas 1 - 0% 0% 70% 95% 95% Gas 2 - 0% 0% 70% 95% 95% Sulfur Dioxide (SO2)4-5 

## Chlorine (Cl2)4-5

5

## http://www.deq.state.mi.us/aps/downloads/permits/CFPP/2007/297- 07/PC%20Boiler%20Case%20by%20Case%20MACT%20final.pdf 1

## AP-42 2

## http://www.epa.gov/ttn/atw/utility/hgwhitepaperfinal.pdf 3

## http://www.icac.com/files/public/hgcontrol010305.pdf 4

## http://www.icac.com/i4a/pages/index.cfm?pageid=3401

# Appendix D-1: Major Source Baseline Emission Factors for Organic HAP and CO for Existing Units

Fuel Category Combustor Design NOx Control?Total # of Units in Subcategory THC (ppm @ 3% as Propane)THC # of Data PointsTotal Mass Dioxins/ Furans (ng/dscm @

7% O2)Total Mass Dioxins/ Furans # of Data PointsCO (ppm @ 3% O2)CO # of Data PointsFormaldehyde (ppm @ 3% O2)Formaldehyde # of Data PointsNOx (ppm @ 3% O2) NOx # of Data Points Yes 1 8.3 1 0.081 4 26.8 1 No 30 53.8 19 1.714 11 101.0 26 Yes - No - Yes 70 59.5 27 0.304 7 183.5 41 No 116 33.4 14 0.524 4 280.3 14 Yes 33 150.1 6 0.081 4 184.8 11 No 327 510.2 45 1.325 11 272.5 31 Yes - No - Yes - No - Yes - No 2 767.2 7 1.337 2 94.3 4 Yes - No - Yes 5 6819.9 5 1.388 1 97.4 1 No 9 3722.4 5 2.982 3 154.4 21 Yes - No 4 993.1 1 0.739 6 357.7 3 Yes 1 151.7 1 0.828 1 171.0 1 No 7 114.7 2 0.040 2 112.0 3 Yes - No 12 767.2 7 1.337 2 94.3 4 Yes - No - Yes 26 532.5 8 0.240 1 116.9 9 No 121 965.9 56 0.862 14 154.4 21 Yes 4 522.1 2 0.127 2 83.8 2 No 40 274.5 5 0.739 6 357.7 3 Yes 2 96.7 2 0.071 1 81.5 2 No 2 22.7 1 0.677 2 182.3 2 Yes - No 12 276.6 8 0.742 6 147.2 6 Yes - No 1 1139.3 52 1.512 12 115.1 1 Yes 16 207.2 10 0.127 2 126.9 9 No 156 1139.3 52 1.512 12 161.2 16 Yes 56 15.1 13 0.019 4 179.1 9 No 222 115.9 13 0.171 5 163.1 14 Yes 71 24.3 48 0.467 3 31.0 17 No 482 2025.7 39 0.217 4 131.1 9 Yes 1043 1.35 7 53.6 203 0.658 5 32.3 134 No 7984 22.69 8 98.3 198 1.135 9 62.6 56 Yes 890 1.75 15 18.6 264 0.117 5 40.3 131 No 1493 1.16 2 49.6 147 1.541 3 53.5 52 Yes 79 160.3 64 0.107 4 42.2 34 No 117 64.9 37 0.006 2 36.2 27 Notes: 13

5 1 5 2 2

Yellow Cells:Where there is no reported data for a coal subcategory, the baseline average for coal/stoker was used to fill the data gap.Where there is no reported data for a bagasse subcategory, the baseline averages from the same wet biomass subcategory were used to fill the data gaps. Where there is no reported data for a wet biomass subcategory, the baseline averages from the same dry biomass subcategory were used to fill the data gaps. Where there is no reported data for a dry biomass subcategory, the baseline average for dry biomass/stoker was used to fill the data gaps. 7 4 11

5 0.320 3 3 1

6 3 9

10 10

6 1

0.791 0.772 8.794 0.401 0.565 0.363

0.463 0.443

1.381 2.384 0.772 8.794 0.183 0.565

5 7 10 3 3 2

1.381 2

7 10 10 3 4 10

12 13

8.25 6.38 6.38 3.23 3.07

3.96 4.02 6.45

7.12 18.61 18.15 6.45

7.12 18.61 Coal FB Gasifier

PC Stoker/Sloped Grate/Other 1.98

1.87 3.61

Bagasse Dutch Oven/Susp Burner FB Fuel Cell Gasifier Stoker/Sloped Grate/Other

Wet Biomass Dutch Oven/Susp Burner FB Fuel Cell Gasifier Stoker/Sloped Grate/Other

Heavy Liquid - Light Liquid - Dry Biomass Dutch Oven/Susp Burner FB Fuel Cell Gasifier Stoker/Sloped Grate/Other

0.169 4 Gas 1 (NG Only) -

Gas 2 - Gas 1 (Other) - 0.636

0.098Fuel CategoryNon-Hg Metals Control CategoryTotal # ofUnits in SubCategory As (lb/MMBtu)As # of Data PointsBe (lb/MMBtu)Be # of Data PointsCd (lb/MMBtu)Cd # of Data PointsCo (lb/MMBtu)Co # of Data Points 1 234 3.65E-05 61 1.23E-06 63 1.36E-06 62 1.19E-06 21 2 255 4.66E-04 90 3.28E-06 78 9.16E-06 82 1.15E-06 5 3 23 8.65E-05 9 2.74E-06 9 5.04E-06 9 2.33E-05 2 4 5 1.14E-04 5 1.32E-06 5 5.72E-06 5 5.92E-06 3 5 60 2.91E-04 10 8.62E-06 8 3.73E-06 10 1.06E-05 - 1 - 1.01E-07 - 8.94E-09 - 3.83E-08 - 2.46E-08 - 2 2 5.06E-07 - 4.47E-08 - 1.92E-07 - 4.41E-06 10 3 - 5.06E-07 - 4.47E-08 - 1.92E-07 - 3.39E-06 4 4 14 5.06E-06 1 4.47E-07 1 1.92E-06 1 1.23E-06 - 5 - 9.10E-06 - 8.05E-07 - 3.45E-06 - 2.21E-06 1 1 1 5.50E-08 - 3.56E-07 - 7.87E-08 - 2.46E-08 - 2 83 4.16E-06 28 6.26E-07 26 1.67E-06 27 4.41E-06 10 3 27 2.33E-05 20 9.87E-07 20 4.64E-06 20 3.39E-06 4 4 17 2.66E-05 9 1.14E-05 6 3.27E-06 10 1.23E-06 - 5 43 4.95E-06 11 3.21E-05 10 7.09E-06 11 2.21E-06 1 1 8 6.64E-06 5 6.05E-08 5 9.29E-07 5 3.03E-07 3 2 96 1.73E-05 25 1.27E-07 23 7.42E-07 26 4.31E-07 7 3 12 7.40E-04 5 2.76E-07 5 9.10E-06 5 8.16E-06 2 4 12 8.80E-05 5 1.55E-06 5 5.78E-05 6 6.46E-07 - 5 105 1.93E-05 21 1.80E-07 22 6.01E-06 23 1.16E-06 4 1 5 2.09E-05 2 2.48E-06 2 1.18E-05 2 2.57E-06 2 2 2 2.88E-06 2 1.20E-07 2 8.85E-08 2 1.03E-07 1 3 3 3.89E-06 - 1.28E-06 - 1.34E-06 - 4.36E-06 - 4 1 3.89E-05 - 1.28E-05 - 1.34E-05 - 4.36E-05 - 5 3 7.00E-05 - 2.30E-05 - 2.42E-05 - 7.85E-05 - 6 264 7.78E-05 25 2.55E-05 25 2.68E-05 25 8.72E-05 21 1 3 1.08E-06 - 5.71E-07 - 2.30E-07 - 8.78E-08 - 2 2 5.38E-06 - 2.86E-06 - 1.15E-06 - 4.39E-07 - 3 - 5.38E-06 - 2.86E-06 - 1.15E-06 - 4.39E-07 - 4 - 5.38E-05 - 2.86E-05 - 1.15E-05 - 4.39E-06 - 5 9 9.68E-05 - 5.14E-05 - 2.07E-05 - 7.90E-06 - 6 539 1.08E-04 57 5.71E-05 57 2.30E-051478.78E-06 10 1 8 1.48E-08 - 5.28E-10 - 2.66E-09 - 1.80E-08 - 2 9 7.40E-08 - 2.64E-09 - 1.33E-08 - 9.01E-08 - 3 2 7.40E-08 - 2.64E-09 - 1.33E-08 - 9.01E-08 - 4 9 7.40E-07 - 2.64E-08 - 1.33E-07 - 9.01E-07 - 5 15 1.33E-06 - 4.75E-08 - 2.40E-07 - 1.62E-06 - 6 8931 1.48E-06 9 5.28E-08 8 2.66E-07 9 1.80E-06 7 1 1 1.24E-05 1 3.43E-08 1 1.16E-07 1 3.86E-07 1 2 7 1.41E-08 - 4.27E-09 - 1.15E-08 - 3.02E-08 - 3 - 1.41E-08 - 4.27E-09 - 1.15E-08 - 3.02E-08 - 4 2 1.41E-07 - 4.27E-08 - 1.15E-07 - 3.02E-07 - 5 1 2.53E-07 - 7.69E-08 - 2.07E-07 - 5.44E-07 - 6 2424 2.81E-07 5 8.54E-08 3 2.30E-07 5 6.04E-07 3 1 3 2.32E-08 - 6.27E-10 - 8.71E-08 - 5.62E-09 - 2 2 1.16E-07 - 3.13E-09 - 4.35E-07 - 2.81E-08 - 3 - 1.16E-07 - 3.13E-09 - 4.35E-07 - 2.81E-08 - 4 - 1.16E-06 - 3.13E-08 - 4.35E-06 - 2.81E-07 - 5 - 2.09E-06 - 5.64E-08 - 7.84E-06 - 5.06E-07 - 6 192 2.32E-06 6 6.27E-08 5 8.71E-06 6 5.62E-07 4 

# Appendix D-2: Major Source Baseline Emission Factors for Fuel-Based HAP and SO2 for Existing Units

Coal

Bagasse

Wet Biomass

Gas 2 Gas 1 (Other) Dry Biomass

Heavy Liquid

Light Liquid

Gas 1 (NG Only)Fuel Category 

# Appendix D-2

Coal

Bagasse

Wet Biomass

Gas 2 Gas 1 (Other) Dry Biomass

Heavy Liquid

Light Liquid

Gas 1 (NG Only) Cr (lb/MMBtu)Cr # of Data Points Ni (lb/MMBtu)Ni # of Data Points Mn (lb/MMBtu)Mn # of Data PointsPb (lb/MMBtu)Pb # of Data PointsSb (lb/MMBtu)Sb # of Data PointsSe (lb/MMBtu)Se # of Data Points 4.81E-05 63 4.04E-05 63 7.10E-04 64 1.94E-05 67 1.52E-06 24 5.97E-05 63 1.19E-04 89 2.15E-04 91 1.34E-04 91 2.99E-05 89 8.12E-07 5 4.99E-03 87 5.65E-05 9 1.06E-04 9 1.01E-04 9 1.32E-04 9 1.98E-05 2 2.79E-05 9 1.62E-05 5 2.18E-05 5 9.54E-05 4 1.11E-04 5 1.87E-05 3 1.80E-05 5 5.23E-05 10 1.07E-04 10 4.47E-04 8 1.75E-04 10 3.36E-05 - 1.12E-04 8 1.45E-06 - 2.37E-06 - 1.24E-06 - 4.27E-07 - 4.05E-08 - 9.06E-08 - 7.25E-06 - 1.19E-05 - 5.15E-04 1 2.14E-06 - 1.29E-06 10 4.53E-07 - 7.25E-06 - 1.19E-05 - 6.18E-06 - 2.14E-06 - 3.72E-06 4 4.53E-07 - 7.25E-05 1 1.19E-04 1 6.18E-05 2 2.14E-05 1 2.02E-06 - 4.53E-06 1 1.31E-04 - 2.14E-04 - 1.11E-04 - 3.84E-05 - 3.64E-06 1 8.15E-06 - 1.94E-07 - 5.26E-07 - 3.67E-05 - 4.31E-07 - 4.05E-08 - 3.71E-07 - 7.02E-06 28 7.72E-06 27 3.06E-04 29 9.63E-06 28 1.29E-06 10 2.51E-06 26 1.19E-05 20 3.75E-05 19 1.98E-04 21 1.21E-04 20 3.72E-06 4 3.89E-06 20 2.25E-05 10 2.78E-05 10 4.56E-04 11 5.16E-05 10 2.02E-06 - 1.78E-06 6 1.75E-05 11 4.74E-05 10 3.31E-03 22 3.88E-05 11 3.64E-06 1 3.34E-05 11 1.21E-05 5 7.85E-06 5 5.18E-04 5 1.07E-05 5 4.09E-07 3 2.00E-06 5 2.96E-06 26 3.79E-06 24 2.60E-04 36 1.07E-05 26 4.35E-07 7 2.71E-06 22 5.46E-05 5 2.05E-05 5 7.56E-04 8 8.25E-04 5 2.86E-05 2 8.60E-06 5 1.87E-04 6 1.57E-04 6 5.90E-03 6 1.70E-03 6 1.01E-06 - 6.23E-05 5 2.16E-05 23 1.39E-05 21 2.92E-03 30 1.22E-04 23 1.82E-06 4 2.64E-06 18 2.06E-05 2 1.18E-05 2 2.42E-05 2 3.04E-05 2 5.94E-06 2 5.05E-06 2 1.54E-06 2 1.27E-04 2 1.06E-05 2 1.50E-06 2 1.12E-07 1 1.04E-05 2 2.32E-06 - 1.00E-04 - 4.67E-04 - 4.12E-06 - 4.17E-06 - 4.68E-06 - 2.32E-05 - 1.00E-03 - 4.67E-03 - 4.12E-05 - 4.17E-05 - 4.68E-05 - 4.17E-05 - 1.81E-03 - 8.41E-03 - 7.42E-05 - 7.50E-05 - 8.42E-05 - 4.64E-05 25 2.01E-03 25 9.35E-03 24 8.25E-05 25 8.33E-05 21 9.36E-05 24 2.86E-06 - 2.43E-06 - 1.74E-04 - 2.88E-06 - 6.13E-07 - 1.07E-06 - 1.43E-05 - 1.21E-05 - 8.70E-04 - 1.44E-05 - 3.06E-06 - 5.37E-06 - 1.43E-05 - 1.21E-05 - 8.70E-04 - 1.44E-05 - 3.06E-06 - 5.37E-06 - 1.43E-04 - 1.21E-04 - 8.70E-03 - 1.44E-04 - 3.06E-05 - 5.37E-05 - 2.57E-04 - 2.18E-04 - 1.57E-02 - 2.60E-04 - 5.51E-05 - 9.66E-05 - 2.86E-041472.43E-04 57 1.74E-02 57 2.88E-041476.13E-05 10 1.07E-04 57 8.33E-08 - 2.78E-08 - 2.60E-08 - 8.41E-08 - 5.89E-09 - 5.33E-08 - 4.16E-07 - 1.39E-07 - 1.30E-07 - 4.20E-07 - 2.94E-08 - 2.67E-07 - 4.16E-07 - 1.39E-07 - 1.30E-07 - 4.20E-07 - 2.94E-08 - 2.67E-07 - 4.16E-06 - 1.39E-06 - 1.30E-06 - 4.20E-06 - 2.94E-07 - 2.67E-06 - 7.50E-06 - 2.51E-06 - 2.34E-06 - 7.57E-06 - 5.30E-07 - 4.80E-06 - 8.33E-06 9 2.78E-06 9 2.60E-06 9 8.41E-06 9 5.89E-07 9 5.33E-06 8 8.61E-07 1 2.70E-06 1 7.69E-06 1 1.13E-06 1 4.02E-07 1 3.28E-07 1 1.53E-06 - 2.26E-06 - 1.04E-06 - 5.17E-08 - 6.38E-08 - 2.57E-08 - 1.53E-06 - 2.26E-06 - 1.04E-06 - 5.17E-08 - 6.38E-08 - 2.57E-08 - 1.53E-05 - 2.26E-05 - 1.04E-05 - 5.17E-07 - 6.38E-07 - 2.57E-07 - 2.75E-05 - 4.07E-05 - 1.86E-05 - 9.31E-07 - 1.15E-06 - 4.63E-07 - 3.06E-05 7 4.52E-05 8 2.07E-05 7 1.03E-06 7 1.28E-06 3 5.14E-07 4 3.42E-08 - 3.46E-08 - 8.72E-08 - 7.58E-08 - 4.19E-08 - 1.98E-08 - 1.71E-07 - 1.73E-07 - 4.36E-07 - 3.79E-07 - 2.10E-07 - 9.88E-08 - 1.71E-07 - 1.73E-07 - 4.36E-07 - 3.79E-07 - 2.10E-07 - 9.88E-08 - 1.71E-06 - 1.73E-06 - 4.36E-06 - 3.79E-06 - 2.10E-06 - 9.88E-07 - 3.08E-06 - 3.11E-06 - 7.85E-06 - 6.82E-06 - 3.77E-06 - 1.78E-06 - 3.42E-06 6 3.46E-06 6 8.72E-06 6 7.58E-06 7 4.19E-06 5 1.98E-06 5Fuel Category 

# Appendix D-2

Coal

Bagasse

Wet Biomass

Gas 2 Gas 1 (Other) Dry Biomass

Heavy Liquid

Light Liquid

Gas 1 (NG Only)Hg Control Category Total # ofUnits in SubCategory Hg (lb/MMBtu)Hg # of Data PointsPM Filterable Control CategoryTotal # ofUnits in SubCategory PM Filterable (lb/MMBtu)PM # of Data Points 1 2 2.00E-06 2 1 234 2.96E-02143 2 41 8.27E-07 15 2 255 4.79E-02143 3 191 5.21E-06 84 3 23 9.70E-02 11 4 13 3.19E-06 8 4 5 9.92E-02 6 5 23 6.17E-06 8 5 60 2.53E-01 26 6 307 2.96E-05136 1 - % reduction unknown 1 - 1.46E-02 - 2 - 2.43E-08 - 2 2 1.28E-02 2 3 - 2.43E-08 - 3 - 1.46E-01 - 4 14 3.69E-06 4 4 14 1.46E-01 13 5 - 9.73E-08 - 5 - 8.77E-01 - 6 2 9.73E-08 1 1 - % reduction unknown 1 1 3.27E-03 - 2 - 3.41E-07 - 2 83 8.11E-02 48 3 1 3.41E-07 - 3 27 1.20E-01 15 4 18 1.68E-06 8 4 17 1.23E-01 9 5 27 1.99E-06 12 5 43 1.96E-01 18 6 125 1.36E-06 29 1 - % reduction unknown 1 8 1.08E-02 5 2 3 2.56E-07 - 2 96 3.04E-02 49 3 5 2.56E-07 - 3 12 7.90E-02 8 4 13 9.20E-07 - 4 12 1.66E-01 6 5 14 1.02E-06 - 5 105 3.23E-01 26 6 198 1.02E-06 31 1 - % reduction unknown 1 5 9.65E-03 2 2 - 1.21E-06 - 2 2 7.87E-02 3 3 5 1.21E-06 - 3 3 2.50E-02 2 4 1 4.34E-06 - 4 1 4.58E-03 - 5 3 4.83E-06 - 5 3 2.41E-02 1 6 269 4.83E-06 28 6 264 7.63E-02 35 1 - % reduction unknown 1 3 2.19E-04 - 2 - 2.33E-06 - 2 2 3.12E-03 6 3 3 2.33E-06 - 3 - 1.32E-03 - 4 - 8.37E-06 - 4 - 1.32E-03 - 5 - 9.30E-06 - 5 9 4.39E-03 - 6 550 9.30E-06146 6 539 2.19E-02 26 1 - % reduction unknown 1 8 3.59E-05 - 2 1 1.52E-07 - 2 9 7.18E-05 - 3 8 1.52E-07 - 3 2 7.18E-05 - 4 9 5.46E-07 - 4 9 1.79E-03 - 5 2 6.07E-07 - 5 15 7.80E-02 1 6 8954 6.07E-07 10 6 8931 3.59E-03 37 1 - % reduction unknown 1 1 6.23E-04 1 2 1 2.67E-06 - 2 7 6.26E-04 4 3 1 3.63E-07 1 3 - 1.92E-04 - 4 2 9.61E-06 - 4 2 4.80E-03 - 5 - 1.07E-05 - 5 1 2.40E-03 - 6 2431 1.07E-05 8 6 2424 9.60E-03 91 1 - % reduction unknown 1 3 1.15E-02 2 2 3 4.98E-07 2 2 2 3.00E-03 1 3 - 3.16E-07 - 3 - 2.24E-04 - 4 - 1.14E-06 - 4 - 5.60E-03 - 5 - 1.26E-06 - 5 - 2.80E-03 - 6 194 1.26E-06 6 6 192 1.12E-02 11Fuel Category 

# Appendix D-2

Coal

Bagasse

Wet Biomass

Gas 2 Gas 1 (Other) Dry Biomass

Heavy Liquid

Light Liquid

Gas 1 (NG Only)Inorganic Control Category Total # ofUnits in SubCategory HCl (lb/MMBtu)HCl # of Data PointsHF (lb/MMBtu)HF # of Data PointsCl2 (lb/MMBtu)Cl2 # of Data PointsSO2 (ppm @ 3% O2)SO2 # of Data Points 1 18 1.15E-03 13 8.85E-05 7 1.33E-03 4 149.7 14 2 16 2.79E-04 4 4.97E-05 2 4.00E-05 1 98.1 10 3 41 3.65E-02 18 7.21E-04 8 7.71E-05 9 173.9 24 4 23 4.18E-03 6 2.44E-03 2 9.78E-04 3 222.0 5 5 479 1.12E-01 2423.05E-03 30 3.09E-03172 762.4 76 1 14 3.63E-04 - 7.03E-05 - 2.14E-03 3 2.7 - 2 - 3.63E-04 - 7.03E-05 - 2.41E-04 - 2.7 - 3 - 2.18E-03 - 1.23E-04 - 1.85E-03 - 16.2 - 4 - 7.25E-03 - 3.05E-05 4 1.85E-03 - 37.8 5 5 2 7.25E-03 2 1.23E-04 11 1.85E-03 1 53.9 16 1 18 3.39E-04 - 7.03E-05 - 2.48E-04 - 2.7 - 2 2 9.27E-04 2 7.03E-05 - 2.48E-04 - 2.7 - 3 - 2.03E-03 - 1.23E-04 - 1.91E-03 - 16.2 - 4 27 6.12E-03 10 3.05E-05 4 1.91E-03 - 37.8 5 5 124 6.78E-03 26 1.23E-04 11 1.91E-03 5 53.9 16 1 15 3.39E-04 3 1.60E-04 - 4.78E-04 - 3.8 - 2 1 1.45E-03 2 5.87E-05 1 2.76E-05 1 3.8 - 3 1 1.27E-02 2 8.29E-04 1 3.67E-03 - 22.9 - 4 14 3.40E-03 6 5.09E-04 3 3.67E-03 - 69.2 5 5 202 7.86E-03 37 2.81E-04 14 3.67E-03 11 76.2 18 1 1 1.17E-03 - 1.06E-04 - 8.78E-05 - 14.2 - 2 6 1.17E-03 - 1.06E-04 - 8.78E-05 - 149.6 1 3 - 3.67E-03 1 1.33E-03 1 6.76E-04 - 147.2 1 4 3 2.34E-02 - 1.86E-04 - 6.76E-04 - 27.1 1 5 268 2.34E-02 31 1.86E-04 8 6.76E-04 5 284.7 14 1 - 7.22E-04 - 1.53E-04 - 4.41E-04 - 4.4 - 2 1 7.90E-03 1 6.26E-04 1 4.41E-04 - 4.4 - 3 - 4.33E-03 - 2.69E-04 - 3.39E-03 - 26.5 - 4 - 1.44E-02 - 2.69E-04 - 3.39E-03 - 88.3 - 5 552 1.44E-021482.69E-04 5 3.39E-03 4 88.3 10 1 9 3.03E-04 - 3.45E-03 - no data - 0.3 - 2 3 3.03E-04 - 3.45E-03 - no data - 0.3 - 3 - 1.82E-03 - 6.05E-03 - no data - 1.8 - 4 2 6.06E-03 - 6.05E-03 - no data - 6.2 - 5 8960 6.06E-03 11 6.05E-03 10 no data - 6.2 23 1 2 3.60E-05 - 5.83E-05 - no data - 0.3 - 2 3 3.60E-05 - 5.83E-05 - no data - 0.3 - 3 - 2.16E-04 - 1.02E-04 - no data - 2.0 - 4 - 7.20E-04 - 1.02E-04 - no data - 0.9 1 5 2430 7.20E-04 5 1.02E-04 4 no data - 6.5 21 1 - 6.93E-05 - 1.00E-04 - no data - 2.4 - 2 1 7.00E-04 1 1.00E-04 - no data - 91.2 1 3 3 4.68E-03 2 1.76E-04 - no data - 270.4 3 4 - 1.39E-03 - 1.76E-04 - no data - 48.3 - 5 193 1.39E-03 7 1.76E-04 5 no data - 48.3 6Fuel Category 

# Appendix D-2

Coal

Bagasse

Wet Biomass

Gas 2 Gas 1 (Other) Dry Biomass

Heavy Liquid

Light Liquid

Gas 1 (NG Only)

## Notes:

Metals/PM Control Groups:It was assumed that all coal and biomass units had at least a cyclone or multiclone installed for metals and PM control. Control groups 5 and 6 for metal and PM emissions from solid-fuel boilers were merged together into a single control group (5). Green cells:Whenever there is not an uncontrolled average but there is an average for another control group, the percent reductions were used to back-calculate an uncontrolled average. Additional data gaps were filled by applying percent reductions to the calculated uncontrolled average (see% Reductionstab). Uncontrolled baseline averages that were back-calculated and the averages based on those values appear as green cells. Orange cells:Where there is no reported data for bagasse, the wet biomass baseline average from the same control group was used to fill the data gaps. Yellow cells:Whenever there is an average based on reported data for the uncontrolled group (i.e., control group 6 for Mercury), any data gaps for that pollutant were filled using percent reductions applied to the uncontrolled average (see% Reductionstab). Baseline averages that were calculated using percent reductions based on a reported uncontrolled average appear as yellow cells.Fuel Category 

# Appendix D-2

Coal

Bagasse

Wet Biomass

Gas 2 Gas 1 (Other) Dry Biomass

Heavy Liquid

Light Liquid

Gas 1 (NG Only)

# Appendix D-3: Ratios of PM2.5 to Total Filterable PM Based on Fuel and Control Fuel Category Control Fraction of Filterable PM that is PM 2.5 Reason Source Note: Gas 1 ALL 1 Particulate matter from natural gas combustion has been estimated to be less than 1 micrometer in size and has filterable and condensable fractions. http://www.epa.gov/ttn/chief/ap42/ch01/final/c01s04.pdf Gas 2 ALL 1 Particulate matter from natural gas combustion has been estimated to be less than 1 micrometer in size and has filterable and condensable fractions. http://www.epa.gov/ttn/chief/ap42/ch01/final/c01s04.pdf Heavy LiquidUncontrolled 0.56 Table 1.3-5 distribution of particle size in industrial boilers http://www.epa.gov/ttn/chief/ap42/ch01/final/c01s03.pdf Heavy LiquidMulticlone 0.22 Table 1.3-5 distribution of particle size in industrial boilers http://www.epa.gov/ttn/chief/ap42/ch01/final/c01s03.pdf Heavy LiquidElectrostatic Precipitator 0.41 Table 1.3-4 distribution of particle size in utility boilers http://www.epa.gov/ttn/chief/ap42/ch01/final/c01s03.pdf Heavy LiquidScrubber 0.97 Table 1.3-4 distribution of particle size in utility boilers http://www.epa.gov/ttn/chief/ap42/ch01/final/c01s03.pdf Light Liquid ALL 0.12 Table 1.3-6 distribution of particle size in industrial boilers for distillate oils http://www.epa.gov/ttn/chief/ap42/ch01/final/c01s03.pdf Biomass Uncontrolled 0.76 Table 1.6-5 particle size distribution for wood/bark-fired boilers http://www.epa.gov/ttn/chief/ap42/ch01/final/c01s06.pdf Applied to wet biomass, dry biomass, and bagasse fuel categories.

Biomass Multiclone 0.16 Table 1.6-5 particle size distribution for wood/bark-fired boilers http://www.epa.gov/ttn/chief/ap42/ch01/final/c01s06.pdf Without flyash re-injection; applied to wet biomass, dry biomass, and bagasse fuel categories. Biomass Electrostatic Precipitator/ Electrified Filter Bed 0.65 Table 1.6-5 particle size distribution for wood/bark-fired boilers http://www.epa.gov/ttn/chief/ap42/ch01/final/c01s06.pdf Applied to wet biomass, dry biomass, and bagasse fuel categories. Biomass Scrubber 0.98 Table 1.6-5 particle size distribution for wood/bark-fired boilers http://www.epa.gov/ttn/chief/ap42/ch01/final/c01s06.pdf Applied to wet biomass, dry biomass, and bagasse fuel categories. Coal Uncontrolled 0.07 Table 1.1-9 particle size distribution for wood/bark-fired boilers http://www.epa.gov/ttn/chief/ap42/ch01/final/c01s01.pdf Used spreader stoker values from AP-42 for all combustor designs.

Coal Multiclone 0.27 Table 1.1-9 particle size distribution for wood/bark-fired boilers http://www.epa.gov/ttn/chief/ap42/ch01/final/c01s01.pdf Used spreader stoker values from AP-42 for allcombustor designs; value is for without flyash reinjection. Coal Electrostatic Precipitator 0.61 Table 1.1-9 particle size distribution for wood/bark-fired boilers http://www.epa.gov/ttn/chief/ap42/ch01/final/c01s01.pdf Used spreader stoker values from AP-42 for all combustor designs. Coal Baghouse 0.26 Table 1.1-9 particle size distribution for wood/bark-fired boilers http://www.epa.gov/ttn/chief/ap42/ch01/final/c01s01.pdf Used spreader stoker values from AP-42 for all combustor designs.

# Appendix E-1: Area Source Baseline Emission Factors for Organic HAP and CO for Existing Units

Fuel CategoryCombustor DesignNOx Control?Total # of Units in SubcategoryTHC (ppm @

3% as Propane)THC # of Data PointsTotal Mass Dioxins/ Furans (ng/dscm @ 7% O2)Total Mass Dioxins/ Furans # of Data PointsCO (ppm @ 3% O2)CO # of Data PointsFormaldehyd e (ppm @ 3% O2)Formaldehyde # of Data

PointsNOx (ppm @ 3% O2)NOx # of Data Points Coal Stoker/Sloped Grate/Other Yes 3,710 3.61 13 0.443 10 150.1 6 0.081 4 184.8 11 BiomassStoker/Sloped Grate/Other Yes 10,958 6.75 - 1.08 - 369.85 - 0.18 - 121.93 - Heavy Liquid - Yes 2,137 3.23 10 2.384 7 15.1 13 0.019 4 179.1 9 Light Liquid - Yes 165,866 3.07 13 0.320 4 24.3 48 0.467 3 31.0 17

# Appendix E-2: Area Source Baseline Emission Factors for Fuel-Based HAP and SO2 for Existing Units Fuel CategoryNon-Hg Metals Control Category Total # ofUnits in SubCategory As (lb/MMBtu)As # of Data PointsBe (lb/MMBtu)Be # of Data PointsCd (lb/MMBtu)Cd # of Data PointsCo (lb/MMBtu)Co # of Data Points Coal 5 3,7102.91E-04108.62E-0683.73E-06101.06E-05- Biomass 5 10,9581.21E-05-1.61E-05-6.55E-06-1.69E-06- Heavy Liquid 6 2,1377.78E-05252.55E-05252.68E-05258.72E-0521 Light Liquid 6 165,8661.08E-04575.71E-05572.30E-051478.78E-0610

# Appendix E-2: Fuel Category Coal Biomass Heavy Liquid Light Liquid Cr (lb/MMBtu)Cr # of Data PointsNi (lb/MMBtu)Ni # of Data PointsMn (lb/MMBtu)Mn # of Data PointsPb (lb/MMBtu)Pb # of Data PointsSb (lb/MMBtu)Sb # of Data PointsSe (lb/MMBtu)Se # of Data Points 5.23E-05101.07E-04104.47E-0481.75E-04103.36E-05-1.12E-048 1.95E-05-3.07E-05-3.11E-03-8.06E-05-2.73E-06-1.80E-05- 4.64E-05252.01E-03259.35E-03248.25E-05258.33E-05219.36E-0524 2.86E-041472.43E-04571.74E-02572.88E-041476.13E-05101.07E-0457

# Appendix E-2: Fuel Category Coal Biomass Heavy Liquid Light LiquidHg Control CategoryTotal # ofUnits in SubCategory Hg (lb/MMBtu)Hg # of Data PointsPM Filterable Control CategoryTotal # ofUnits in SubCategory PM Filterable (lb/MMBtu)PM # of Data Points 6 3,7102.96E-05136 5 3,7102.53E-0126 6 10,9581.19E-06- 5 10,9582.60E-01- 6 2,1374.83E-0628 6 2,1377.63E-0235 6 165,8669.30E-06146 6 165,8662.19E-0226

# Appendix E-2: Fuel Category Coal Biomass Heavy Liquid Light LiquidInorganic Control CategoryTotal # ofUnits in SubCategory HCl (lb/MMBtu)HCl # of Data PointsHF (lb/MMBtu)HF # of Data PointsCl2 (lb/MMBtu)Cl2 # of Data PointsSO2 (ppm @ 3% O2)SO2 # of Data Points 5 3,7101.12E-012423.05E-03303.09E-03172762.4 76 5 10,9587.32E-03-2.02E-04-2.79E-03- 65.0 - 5 2,1372.34E-02311.86E-0486.76E-045 284.7 14 5 165,8661.44E-021482.69E-0453.39E-034 88.3 10