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A B C DE F 

PSM/RMP Common Chemical List September 15, 2016Chemical Name on 29 CFR 1910.119 App A CAS number

PSM TQ(lbs.)

RMP TQ(lbs.)

RMP

T/F Notes (PSM) Notes 

Acetaldehyde 75‐07‐0 2500 10000 FAcrolein (2‐Propenal) 107‐02‐8 150 5000 T

Acrylyl Chloride 814‐68‐6 250 5000 T

Allylamine 107‐11‐9 1000 10000 TAmmonia, Anhydrous 7664‐41‐7 10000 10000 T Duplicate CAS listing

Ammonia solutions (> 44% ammonia by wt.) 7664‐41‐7 15000 20000 T Duplicate CAS listing RMP 

Arsine (also called Arsenic Hydride) 7784‐42‐1 100 1000 TBis(Chloromethyl) Ether 542‐88‐1 100 1000 TBoron trichloride 10294‐34‐5 2500 5000 TBoron Trifluoride 7637‐07‐2 250 5000 TBromine 7726‐95‐6 1500 10000 TCarbonyl Chloride (see Phosgene) 75‐44‐5 100 500 T Duplicate CAS listing RMP 

Chlorine 7782‐50‐5 1500 2500 T

Chlorine dioxide 10049‐04‐4 1000 1000 TChloromethyl methyl ether 107‐30‐2 500 5000 T

Cyanogen 460‐19‐5 2500 10000 F

Cyanogen Chloride 506‐77‐4 500 10000 TDiborane 19287‐45‐7 100 2500 TDichlorosilane 4109‐96‐0 2500 10000 F

Dimethyldichlorosilane 75‐78‐5 1000 5000 T

Dimethylhydrazine, 1,1‐ 57‐14‐7 1000 15000 TDimethylamine, Anhydrous 124‐40‐3 2500 10000 FEthyl nitrite 109‐95‐5 5000 10000 FEthylamine 75‐04‐7 7500 10000 FEthylene Oxide 75‐21‐8 5000 10000 TEthyleneimine 151‐56‐4 1000 10000 T

Fluorine 7782‐41‐4 1000 1000 T

Formaldehyde (Formalin) 50‐00‐0 1000 15000 TFuran 110‐00‐9 500 5000 T
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A B C DE F 

PSM/RMP Common Chemical List September 15, 2016Chemical Name on 29 CFR 1910.119 App A CAS number

PSM TQ(lbs.)

RMP TQ(lbs.)

RMP

T/F Notes (PSM) Notes 

33343536373839404142434445464748495051525354555657

Hydrochloric Acid, Anhydrous 7647‐01‐0 5000 5000 T Duplicate CAS listing

Hydrofluoric Acid, Anhydrous 7664‐39‐3 1000 1000 T Duplicate CAS listing

Hydrogen Chloride 7647‐01‐0 5000 5000 T Duplicate CAS listing

Hydrogen Cyanide, Anhydrous 74‐90‐8 1000 2500 T RMP 

Hydrogen Fluoride 7664‐39‐3 1000 1000 T Duplicate CAS listing

Hydrogen Selenide 7783‐07‐5 150 500 THydrogen Sulfide 7783‐06‐4 1500 10000 TIron, Pentacarbonyl 13463‐40‐6 250 2500 T

Isopropylamine 75‐31‐0 5000 10000 FMethyl Acrylonitrile 126‐98‐7 250 10000 T

Methylamine, Anhydrous 74‐89‐5 1000 10000 F

Methyl Chloride 74‐87‐3 15000 10000 T

Methyl Chloroformate 79‐22‐1 500 5000 T

Methyl Hydrazine 60‐34‐4 100 15000 T

Methyl Isocyanate 624‐83‐9 250 10000 T

Methyl Mercaptan 74‐93‐1 5000 10000 T

Methyltrichlorosilane 75‐79‐6 500 5000 T

Nickel Carbonly (Nickel Tetracarbonyl) 13463‐39‐3 150 1000 T

Spelling: Carbonly

should be Carbonyl

Nitric Acid (94.5% by weight or greater) 7697‐37‐2 500 15000 T RMP 

Nitric oxide 10102‐43‐9 250 10000 TOleum (65% to 80% by weight; also called

Fuming Sulfuric Acid) 8014‐95‐7 1,000 10,000 T

Peracetic Acid (concentration > 60% Acetic Acid;

also called Peroxyacetic Acid) 79‐21‐0 1000 10000 T Duplicate CAS listing

Perchloromethyl Mercaptan 594‐42‐3 150 10000 T

Peroxyacetic Acid (concentration > 60% Acetic

Acid; also called Peracetic Acid) 79‐21‐0 1000 10000 T Duplicate CAS listing

Phosgene (also called Carbonyl Chloride) 75‐44‐5 100 500 T Duplicate CAS listing
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A B C DE F 

PSM/RMP Common Chemical List September 15, 2016Chemical Name on 29 CFR 1910.119 App A CAS number

PSM TQ(lbs.)

RMP TQ(lbs.)

RMP

T/F Notes (PSM) Notes 

585960616263646566676869

Phosphine (Hydrogen Phosphide) 7803‐51‐2 100 5000 T

Phosphorus Oxychloride (also called Phosphoryl C 10025‐87‐3 1000 5000 T Duplicate CAS listing

Phosphorus Trichloride 7719‐12‐2 1000 15000 T

Phosphoryl Chloride (also called Phosphorus Oxy 10025‐87‐3 1000 5000 T Duplicate CAS listing

Sulfur Dioxide (liquid) 7446‐09‐5 1000 5000 T

Sulfur Tetrafluoride 7783‐60‐0 250 2500 T

Sulfur Trioxide (also called Sulfuric Anhydride) 7446‐11‐9 1000 10000 T Duplicate CAS listing

Sulfuric Anhydride (also called Sulfur Trioxide) 7446‐11‐9 1000 10000 T Duplicate CAS listing

Tetrafluoroethylene 116‐14‐3 5000 10000 F

Tetramethyl Lead 75‐74‐1 1000 10000 T

Trichlorosilane 10025‐78‐2 5000 10000 F

Trifluorochloroethylene 79‐38‐9 10000 10000 F