# ATALYST

AIR MANAGEMENT, INC.



# AIR QUALITY TESTING SERVICES

FLORIM USA CERAMIC KILN

EMISSIONS TEST REPORT

Catalyst A.ir Management, Inc. Report Number 243-001

APRIL 3, 2008 Test Dates: October 25, 2007

2505 Byington-Solway Road 29541 Morningmist Drive 10 Mill Road Knoxville, TN 37931 Wesley Chapel, FL 33543 Mnroa n tn

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# ATALYST

A[It IWANAGEMENT, INC.



## FLORIM USA CERAIVIIC KILN

EIVIISSIONS TEST REPORT

CATALYST AIR MANAGEMENT, INC. REPORT NUMBER 243-001

APRIL 3, 2008 Test Date: October 25, 2007

Prepared for Ms Connie James Florim USA 300 Intemational Boulevard Clarksville, TN 37040

# ATALYST

AiR NLwAGEmENT; Irrc.


## CERTIFICATION OF INFORMATION

Florim 

## USA — Clarksville, TN Catalyst Report 243-001 Apri13, 2008



## To the extent practical, information and data provided in this test report has been verified as true and correct.

Michael J. Taylor President

## TABLE OF CONTENTS

LETTER OF TRANSMITTAL
TITLE PAGE
CERTIFICATION OF INFORMATION i
TABLE OF CONTENTS
PROJECT FACT SHEET
1 Introduction 1 2 Summary of Test Results 1 3 Results of Testing 1-3 4 Sampling Program Procedures 4-5 5 Operating Conditions 5 6 Quality Assurance 5-6 7 Discussion 16
APPENDICES
1 Test Results 7

S02 7-12 HCl/IiF 13-24 2 Plant Data 25-26 3 Lab Analysis

— 

## HCUHF 27-34 4 Reference Method Quality Assurance 35

Isokinetic Sampling Equipment 35-41 Calibration Gas Specif'

ication Sheets 42-46 5 Sample Calculations 47-54 6 Figures 55-58

ii

# PROJECT FACT SHEET

NAME OF SOURCE OWNER:
SOURCE IDENTIFICATION:
LOCATION OF SOURCE:

TYPE OF OPERATION:
TYPES OF TESTS PERFORMBD:

TEST COMPANY:

SITE SUPERVISOR:
TEST PERSONNEL:

TEST DATES:
OWNER' S REPRESENTATIVE: Florim USA
Ceramic Kiln
300 Intemational Boulevard Clarksville, TN 37040
Ceramic Kiln Sample Traverse-EPA Method 1 Volumetric Flow Rate-EPA Method 2 Molecular Weight-EPA Method 3A Moisture Content-EPA Method 4 S02-EPA Method 6C HCUHF-EPA Method 26A Catalyst Air Management, Inc. 2505 Byington-Solway Road Knoxville, TN 37931 Josh Nicely - Testing Supervisor
Huedon Love - Technician Justin Watson - Technician October 25, 2007
Connie James

TEST OBSERVER: Brian Parker - TDEC

iii

## 1.0 Introduction

Catalyst Air Management, Inc. (Catalyst) was contracted by Florim USA to perform emissions testing for the ceramic kiln at the facility in Clarksville, TN. The sampling program was conducted October 25, 2007. The testing was performed by Messrs. Josh Nicely, Huedon Love and Justin Watson of Catalyst, with the assistance of personnel assigned by Florim USA. Ms Connie James of Florim USA coordinated plant operation during the testing. Mr. Brian Parker of the Tennessee Department of Environment and Conservation (TDEC) was present to observe a portion of the testing. 2.0 Summary of Test Results A summary of test results developed by this source sampling program are presented in Tables 1 through 3. The summary tables are presented as follows: Table Description Page 1 Summary of Emissions 1 2 Isokinetic Sampling Summary — HCUHF 2 3 Sampling Summary — S02 3
3.0 Results of Testi.n
~ 

## The individual test run results are shown in Tables 2 and 3, and are tabulated in Appendix 1.

TABLE 1 Summary of Emissions Ceramic Kiln Baghouse

Pollutant Avg lb/hr
S0 2 ~ 

### 9.22' 

### HCl 2.57
HF 0.10

### TABLE 2 ISOKINETIC SAMPLING SUMMARY EPA Method 51202

Client: Florim 

### USA Unit Tested: 

### "Baghouse Sampling Location: 

### Stack

Run Number: 1 2

Date: l 

### O125/07 10/25/07 Start Time: 10:45 12:20 End Time: 11:52 13:27

DN - 

### Nozzle Diameter: - 0.328 0.328 Pbar - 

### Barometric Pressure: 29.12 29.12 TT - 

### Sampling Time: 60 60 VM - 

### Meter Volume: 46.186 48.475 TM - 

### Avg, Meter Temp(F): 81 84 PM - 

### Avg. Delta H(in. of H20): 1.779 2.088 Y- Meter Calibration Factor: 1.00 1.00 VMSTD - 

### Std. Gas Volume (SCF): 44.091 46.025 Vlc - 

### Volume Water Collected: 46.1 43 %M - 

### Percent Moisture: 4.7 4.2 Bws - 

### Mole Fraction, Dry: 0.05 0.04 %CO2 - 

### Carbon Dioxide, Dry: 2.3 2.3 %02 - 

### Oxygen, Dry: 17.2 17.3 MD - 

### Dry Molecular Weight: 29.05 29.06 MS - 

### Wet Molecular Weight: 28.53 28.60 A- Stack Area, SQ.FT: 9.62 9.62 PS - 

### Static Press. (in. of Hg): 29.10 29.10 TS - 

### Stack Temp. (F): 297 300 CP - 

### Pitot Coefficient: 0.84 0.84 VS - 

### Stack Gas Velocity (AFPS): 32.4 34.9 QS - 

### Stack Gas Volume (DSCFM): 12,082 13,049 ' 

### QA - 

### Stack Gas Volume (ACFM): 18,686 20,169 %I - 

### Isokinetic R.atio: 99.8 96.4

Emissions HCl grIDSCF - 

### Emission Concentration: 0.022 0.025 LBS/HR - 

### Emission Rate: 2.32 2.77
Average gr/DSCF 0.023 Average LBS/HR 2.56 3

10/25/07 13:45 

### 14:53

0.328 29.12 60 50.188 84 2.096 1.00 47.601 45.4 4.3 0.04 2.3 17.3 29.05 28.58 9.62 29.10 301 0.84 35.1 13,107 20,291 99.3



### 0.023 2.59

Emissions HF grfDSCF - Emission Concentration: 0.001 0.001 0.001 LBS/HR - Emission Rate: 0.09 0.10 0.09
Average gr/DSCF 0.001 Average LBS/HR 0.10

2

### TABLE 4 SAMPLING SUMMARY EPA Methods 3A, 6C, 7E - NOx/SO Z

Client: Florim USA Plant: Clarksville, TN Unit: Bagliouse Location: Stack

Run 1 Run 2 Run 3

Datc 10/25/2007 10/25/2007 10/25/2007 Start Time 10:45 12:20 13:45 End 1'ime 1 l:45 13:20 14:45

Measured S02 Concentration (ppm) 62.63 72.77 84.01 Corrected S02 Concentration (ppm) 62.4 71.7 82.3
Mcasured 02 Concentration (%) 17.0 17.0 16.9 Corrected 02 (%) 17.3 17.3 17.2 Measured CO2 Concentration (%) 2.3 2.4 2.2 Corrected CO2 (%) 2.2 2.3 2.1 Volumetric Flow Rate (dscfin) 12,082 13,049 13,205 S02 Emissions (lb/hr) 7.51 9.32 10.82



### Average S02 Emissions (Ib/hr) 9.22

3

## 4.0 Samplina Program Procedures



## The following test methods were utilized during the test progrram:
EPA Method 1 Sample and Velocity Traverse for Stationary Sources EPA Method 2 Determination of Stack Gas Velocity and Volumetric Flow Rate EPA Method 3A Gas Analysis for CO2, 02, 

## Excess Air and Dry Molecular Weight

(Instrumental Analyzer Method) EPA Method 4 Determination of Moisture Content in Stack Gas EPA Method 6C Determination of S02 Emissions from Stationary Sources

(Instrumental Analyzer Method) EPA Method 26A Determination of Hydrogen Chloride Emissions from Stationary

Sources Test runs were conducted in triplicate for all parameters, with each being a minimum of 60 minutes in duration. 4.1 SOz, OZ and CO2 — EPA Method 3A and 6C A sample was continuously extracted and introduced into a Western Research 721 ATM S02 analyzer, and a Servomex 1400 02/CO2 analyzer for determination of gas concentrations. The sample was extracted through a heated stainless steel probe, heated sample line and sample conditioner to dry the sample before it enters the analyzers. A sample flow control system was used to control the flow into the analyzers. The analyzers were calibrated prior to starting the testing with EPA Protocol 1, calibration gases. A system bias check was performed before each run by introducing the zero and upscale gas at the back end of the sample probe. The system bias check was repeated at the end of each test run to determine the analyzer zero and calibration drifft. A stratification test was performed to determine the number of sample points needed. There was less than 10% stratification and the three point long line measurement was used. The S02 analyzer span was 0-235 ppm. The calibration gases that were utilized were zero, 40-60% (126.86 ppm) and 80-100% (234.41 ppm) of span. The 02/COZ analyzer spans were 0-23% and 0-18%, respectively. The 02 calibration gases utilized were 13.09% and 22.64%. The CO2 calibration gases were 9.902% and 17.88%. The high calibration gas determined the span and was the bases for the mid gas, as well as bias and drift calculations. Reference Method Analyzers: 

## Manufacturer Model Pollutant S _pan Western Research _ 721-M S02 0-2000 ppm Servomex 1400B CO2/02 0-20 0 /o/0-25%

4

## 4.2 HCl and HF - EPA Method 26A

The HCUHF emissions were determined in accordance with procedures outlined in EPA Method 26A. The flue gas sample was extracted isokinetically from the gas stream. The HCUHF emissions were collected in acidic absorbing solutions in the back half of the sampling train after the filter. The acidic absorbing solutions collect the gaseous hydrogen halides. The hydrogen halides emissions were solubilized in the acidic solution. The halogens pass through to the alkaline solution where they were hydrolyzed. Sodium thiosulfate was added to the alkaline solution to assure reaction with the hypohalous acid. The halide ions in the acidic solutions were measured by ion chromatography. The probe and filter are both maintained at approximately 250° F. The sampling train consists of the following equipment connected in series: Glass lined probe and glass nozzle Glass fiber filter within a heated filter holder with teflon support Two Greenburg-Smith impingers containing 100 ml of 0.1N H2SO4 Two modified Greenburg-Smith impingers containing 100 ml of 0.1N NaOH A modified Greenburg-Smith impinger containing approximately 250 g of silica gel The sample volume is measured by passing it through a calibrated dry gas meter. An S-type pitot tube is attached to the probe to measure stack gas velocity and to maintain isokinetic sampling. A K-type thermocouple is also attached to the probe to measure the gas ternperature. Affter each run, the probe, nozzle and connecting glassware ahead of the f lter were brushed and rinsed with distilled water and discarded. The. impinger contents were measured for increase in volume. The contents of the first two impingers and distilled water rinses were retained for HCl and HF analysis. The contents of the third and fourth impinger and distilled water rinses were retained for Cl and F analysis. The silica gel was returned to the original tared container and weighed to determine moisture gain.
5.0 Operating Conditions 

## Florim USA personnel monitored operating conditions throughout the duration of the sampling program. The testing was performed October 25, 2007. The unit was operating under normal conditions during the tests.
6.0 Quality Assurance Procedures 

## The quality assurance procedures followed during the testing activities followed guidelines set forth by the previous mentioned methods and the EPA Quality Assurance Handbook for Source Sampling. The specific procedures for this test program are listed below.

## 6.1 Isokinetic Equipment

The sample nozzles were visually inspected and measured across thr.ee different diameters to determine the appropriate nozzle diameter. The S-type pitot tubes were visually inspected and measured to meet the design specifications of EPA Method 2 for a 0.84 pitot coefficient. Both legs of the pitot tube were leak checked before and after each sample run. The stack thermocouples were calibrated prior to the testing and a post-test check was perforrned after the testing project. The manometer was leveled and zeroed before each sample run. The dry gas meter is fully calibrated annually using an EPA intermediate standard. Post -test dry gas meter checks were completed to verify the accuracy of the meter Yi. Pre-test and post-test leak checks were completed and were less than 0.02 cfm at the highest sampling vacuum.
6.2 Instrumental Methods Analyzer calibrations, system bias check and drift checks were completed before and affter each sample run utilizing EPA Protocol calibration gases. The analyzer interference responses were determined in accordance with Section 8.2.7 of Method 7E and Section 16 of Method 6C.
6.3 Data and Calculations A manual calculation check is performed on a single run for each parameter.
7.0 Discussion
7.1 Chain of Custody All the field samples were collected, sealed and transported to the Maxxam Analytics, Inc laboratory in Burlington, Ontario, Canada under the supervvision of Josh Nicely and Jeff Ferguson. The samples were labeled to identify the following:
Client and source Date Type of Sample Run number Sample location Sarnple fraction
7.2 Sampling Conditions and Concerns There was a 3 minute delay during Run 3 due to a loss of electrical power. - 6

# APPEN'DLX 1 TEST RESLlLTS



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### CATALYST AIR MANAGEMENT Inc.

CALIBRATION DATA

CLIENT: Floriun USA PLANT: Clarksville, TN UNIT: Baghouse TEST: 3A & 6C LOCATION: Stack RUN #: 1-9 LOAD LEVEL: Normal DATE: 10/25/2007

GAS ANALYZER CYLINDER ANALYZER DIFF % Pass UNITS SCALE VALUE VALUE PPM SPAN Yes1No 02 1

, 

### % 0.00 0.00 0.00 0.00 

## YES 02, % 25 13.09 13.12 0.03 0.13 YES 02, % 22.64 22.65 0.01 0.04 

## YES
CO2, % 0.00 0.00 0.00 0.00 

## YES CO2, % 20 9.902 9.92 0.02 0.10 YES CO2, % 17.88 17.79 0.09 0.50 

### YES
S02, ppm 0.0 0.00 0.00 0.00 YES S02, ppm 

## 250 126.86 125.4 1.46 0.62 

## YES S02, ppm 234.41 235.6 1.19 0.51 

## YES



# EZCATALYST AIR 12ANAGEMENT Inc. REFERENCE DATA

CLIENT: Flocim USA RUN q: 1 PLANT: ClnricsviUc. TN OPERATIIVG LEVEL: Normal UNIT: Baghousc START DATE: 10V25/2007 TEST: 3A,6C,7E END DATE: 10125/2007 LOCATION: Stack START: 10:45' END: 11:45 DATE TIME 02 CO2 S02 10125/2007 10:45 17.09 224 37.43 1012512007 10:46 17.11 2.24 35.45 10125/2007 10:47 17.13 2.31 39.52 10126/2007 10:48 17.02 2.36 46.36 1012512007 10:49 16.96 2.36 52.49 10/25/2007 10:50 18.93 2.38 58.39 10J2512007 10:51 16.93 2.29 58.2 10125J2007 10:52 17.04 2.27 59.19 10/25/2007 10:53 17.01 2.32 60.72 1012512007 10:54 16.95 2.38 62.14 1012512007 10:56 16.95 2.43 61.98 10/25l2007 10:66 16.77 2.51 64.88 10/25/2007 10:57 16.66 2.54 67.11 1012512007 10:58 16.88 25 68.37 10125l2007 10:59 16.61 2.51 71.54 10J25l2007 11:00 16.62 2.54 73.34 10125/2007 11:01 16.63 2.51 72.29 10/25J2007 11:02 16.76 2.51 89.41 10l2512007 11:03 18.81 2.49 85.57 10125/2007 11:04 16.78 2.47 64.1 10J25/2007 11:05 16.85 242 62.64 10125/2007 11:06 16.91 2.32 62.79 10/2512007 11:07 17.06 2.26 62.1 10J25R007 11:08 17.17 2.22 61.47 10/26/2007 11:09 17.27 2.18 61.61 10/25/2007 11:10 17.33 2.23 69.56 10/25/2007 11:11 17.28 2.23 56.56 10/2512007 11:12 17.25 2.23 54 10125/2007 11:13 17.28 2.2 52.48 10/2512007 11:14 17.3 2.11 51.72 10125R007 11:15 17.4 2.12 50.99 10/25/2007 11:16 17.41 2.11 49.57 1012512007 11:17 17.41 2.16 49.97 10/2512007 11:18 17.36 2.23 S2.68 10l2512007 11:19 17.27 2.23 56.35 10/2512007 11:20 17.22 2.27 59.49 10125l2007 11:21 17.15 2.22 61.85 10/252007 11:22 17.18 2.22 63.46 1012512007 11:23 17.22 2.22 64.09 10l2572007 11:24 17.16 2.26 65.92 10/2512007 11:25 17.13 2.36 68.19 10R512007 11:26 17.01 2.39 70.88 10125/2007 11:27 17.02 2.37 71.61 10125J2007 11:28 16.98 2.37 74.32 102512007 11:29 16.93 2.33 77.17 1012512007 11:30 17.01 2.33 76.65 1012512007 11:31 17.14 2.24 72.27 10425/2007 11:32 17.19 2.28 68.7 10/2512007 11:33 17.15 2.3S 66.63 102512007 11:34 17.05 2.36 64.57 10l25/2007 11:35 17.02 2.36 62.71 10/2512007 11:36 17.03 2.3 60.87 10l2512007 11:37 17.11 2.24 81.57 10/25/2007 11:38 17.16 2.24 84.39 10/25/2007 11:39 17.17 226 67.66 10125I2007 11:40 17.14 2.36 70.34 10l25/2007 11:41 17 2.4 72.22 10/25/2007 11:42 16.92 2.42 73.88 10/26/2007 11:43 16.92 2.4 76.16 10/2512007 11:44 16.87 2.36 77.19 10125/2007 11:45 16.94 2.36 78.21 02 CO2 S02 17.05 2.32 6163 % % ppm tor Poa Test CsUbesBooc

SYSTEM CAI.®RAT10N BIAS AND D[tIFT DATA GAS ANALYZER PRE-TEST 'K Pass POST-TEST 4k % Pus UNITS VALUE CHECK SPAN YES1N0 CHECK SPAN DRIFT YES1N0 02, 56 0.00 0.00 0.00 YES 0.05 012 0.22 YES 02, SL 22.65 22.31 1.50 YES 22.29 1.59 0.09 YES CO2, % 0.00 0.12 0.67 YES 0.17 0.95 0.28 YES CO2, % 17.79 17.51 1.57 YES 17.49 1.68 0,11 YES S02, ppm 0.00 0.00 0.00 YES 0.00 0.00 0.00 YES S02, ypm 125.4 126.7 0.55 YES 128.0 1.11 0.55 YES UNCORRECTED ANALYZ.ER VALL

- ES DRY 02, % (7.0 CO2, % 2.3 S02, ppm 62.6 ANALYZER VALUES CORRECTED FOR DRIIt'I• DRY 02, °1e 17.3 CO2, Yo 2.2 S02, ppm 62.4
FNIISSION RATF.S Volumetric Flow (DSCFM): 12,082 S02 (Ib/lu) - 7.51



# 9CATALYST AIR MANAGEMENT Inc REFERENCE DATA

CLIENT: Florim USA RUN N: 2 PLANT: Clarksville, TN OPERATWG LEVEL: Nonael UNIT: Baghouse START DATEt 10/25/2007 TEST: 3A,6C,7E END DATE: 10l25/2007 LOCATION: Stack START: 12:20 END: 13:20 DATE TIIME 02 CO2 S02 10125l2007 12:20 19,61 6.41 53.98 10125l2007 12:21 16.98 2.52 71.88 10/25/2007 12:22 16.93 2.4 72.42 10J2512007 12:23 17.02 2.38 72.25 10/25I2007 12:24 17.03 2.36 71.97 10/2512007 12:25 17.03 2.4 71.62 10l2512007 12:26 16.98 2.45 71.51 10/25l2007 12:27 16.88 2.45 71.16 10J2512007 12:28 16.88 2.45 71.07 10/25/2007 12:29 16.88 2.37 71 10125/2007 12:30 16.97 2.32 70.89 1012512007 12:31 17.03 2.31 70.75 10/2512007 12:32 17.04 2.31 70.55 10/25/2007 12:33 17.03 2.4 70.7 10/2512007 12:34 16.92 2.42 70.48 10/2512007 12:35 16.89 2.42 70.19 1012512007 12:36 16.88 2.4 70.56 1012S12007 12:37 16.9 2.32 70.68 10l2512007 12:38 17 2.3 71.05 10125/2007 12:39 17.03 2.3 71.5 10/2512007 12:40 17.02 2.33 71.72 10/25I2007 12:41 16.99 2.41 72.01 1012512007 12:42 16.69 2.42 72.13 1012512007 12:43 16.89 2.42 72.31 10125/2007 12:44 16.87 2.36 72.63 10125l2007 12:4S 16.92 2.3 72.84 1012512007 12:46 17.01 2.29 72.67 10/2512007 12:47 17.01 2.3 72.95 1012512007 12:48 17.01 2.38 72.72 10/25l2007 12:49 16.93 2.41 72.85 1012512007 12:50 16.87 2.41 72.66 10/25/2007 12:51 16.87 2.4 72.57 102512007 12:52 16.89 2.31 72.48 10/2512007 12:53 16.99 2.29 72.67 10/2512007 12:54 17.02 2.29 72.98 10125J2007 12:55 17.03 2.31 73.04 10/25/2007 12:56 17.01 2.4 73.15 10l2512007 12:57 16.91 2.41 73.26 10l2512007 12:58 16.9 2.41 73.3 10l2512007 12:59 16.9 2.37 73.49 1025f2007 13:00 16.94 2.29 73.71 10/25l2007 13:01 17.03 2.29 73.85 1025/2007 13:02 17.04 2.29 74 10125/2007 13:03 17.04 2.36 74.01 10125/2007 13:04 16.98 2.41 74.15 10l25P2007 13:05 16.9 2.41 74.46 10125/2007 13:06 16.91 2.41 74.47 1012512007 13:07 16.91 2.32 74.6 10125/2007 13:08 16.99 2.3 74.76 1012512007 13:09 •17.03 2.29 74.84 10/2512007 13:10 17.04 2.31 75.38 1012512007 13:11 17.03 2.39 75.75 1012512007 13:12 16.93 2.41 76.01 10/25l2007 13:13 16.91 2.41 76.73 1012512007 13:14 16.91 2.38 75.62 10/2512007 13:15 16.94 2.3 75.63 10/2512007 13:16 17.04 2.3 76.99 10/2512007 13:17 17.04 2.29 75.85 10/25f2007 13:18 17.06 2.34 76.1 1012512007 13:19 17 2.41 76.3 10126/2007 13:20 16.92 2.41 76.37 02 CO2 S02 17.01 2.43 72.77 Aalpsr Re:dings aot consctod % S6 ppm [crPott•TcuCsHtresdoct

SYSTEM CALIBRATION B1AS AND DRIFT DATA GAS ANALY'LF.II PRF.TEST °h Pass POST TEST % % Psss UNPfS VALUE CFECK SPAN YES1N0 CIDrCK SPAN DRD"P YESWO 02, % 0.00 0.05 0.22 YES 0.07 0.31 0.09 YES 02, % 22.65 2229 1.59 YES 2221 1.94 0.35 YES
CO2, % 0.00 0.17 0.95 YES 0.19 1,06 0.11 YES CO2, % 17.79 17.49 1.68 YES 17.38 2.29 0,62 YES
S02, ppm 0.00 0.00 0.00 YES 0.00 0.00 0.00 YES S02, aAm 125.4 128.0 1.11 YES 129.6 1.79 0.68 YES
UNCORRECTED ANALY?ER VALUES

DRY 02, % 17.0 CO2, % 2.4 S02, ppm 72.8 ANALYZER VALUES CORRECTED FOR DRIFT DRY 02, % 17.3 CO2, % 2.3 S02, ppm 71.7
ENIISSION RATES Volumcuic Flow (DSCFK: 13,049 S02 (lb/hr) = 9.32



# 10-GTALYST AIR MANAGEMENT Inc. REFERENCE DATA

CLIENT: Flarim USA RUN tt: 3 PLM7: Clarkm`pc,'N OPERATING LEVEL: I:onaal UNPT: Baghcnso START DATE: lOJ2S42007 TEST: 3A,6C,7E EA

- D DATE: l0/25/2007 LOCATION: Stacic STARTi 13:4S END: 14:45 DATE TI711E 02 CO2 S02 10/25/2007 13:45 16.94 2.31 61.37 101251Z007 13:46 17.04 2.29 81.22 10l2&/2007 13:47 17.07 2.3 81.33 10/25/2007 13:48 17.06 2.32 81.51 10125J2007 13:49 17.05 2.4 82.16 1012512007 13:50 16.95 2.42 82.63 1012512007 13:51 16.93 2.42 82.88 10/25/2007 13:52 16.93 2.37 82.81 10125/2007 13:53 16.97 2.3 82.55 10/ZSI2007 13:54 17.06 2.29 82.92 10125/2007 13:55 17.06 2.29 83.17 10f2512007 13:56 17.07 2.36 83.17 1012512007 13:57 17.01 2.41 83.17 10J25/2007 13:58 16.94 2.41 83.74 10/2512007 13:59 16.93 2.41 64.09 10l25l2007 14:00 16.95 2.32 83.37 10/25/2007 14:01 17.04 2.28 82.55 10/2512007 14:02 17.08 2.29 83.1 10/2542007 14:03 17.1 2.29 83.09 1012512007 ' 14:04 17.06 2.39 83.05 10125l2007 14:05 16.98 2.4 62.83 1012512007 14:06 16.98 2.41 82.23 10/2512007 14:07 16.95 2.38 81.72 1025/2007 14:08 16.98 2.29 81.32 10125/2007 14:09 17.07 2.3 82.64 10/25/2007 14:10 17.08 2.28 83.13 1012512007 14:11 17.07 2.35 83.89 1012512007 14:12 17.03 2.41 83.63 10/2W007 14:13 16.94 2.42 84.07 10/25/2007 14:14 16.94 2.42 84.39 10l25/2007 14:15 16.93 2.34 84.72 10125/2007 14:16 17 2.3 85.24 1012512007 14:17 17.07 2.29 85.54 1025I2007 14:18 17.07 2.3 85.35 10/2512007 14:19 17.06 2.39 85.34 10/2sl2007 14:20 16.97 2.42 85.73 10252007 14:21 16.93 2.42 86.25 10l2512007 14:22 16.92 2.4 86.4 10/25/2007 14:23 16.93 2.32 86.3 10/25/2007 14:24 17.02 2.3 66.06 1012512007 14:25 17.05 2.3 65.92 10125/2007 14:26 17.05 2.34 85.3 10125/2007 14:27 17.02 2.42 85.25 10/2&l2007 14:28 16.92 2.43 84.94 10125l2007 14:29 16.9 2.42 84.93 10/2512007 14:30 4.79 0.69 82.08 10/2512007 14:31 17.45 2.03 86.65 10125/2007 14:32 17.5 2.07 B6.68 1012512007 14:33 17.47 2.05 84.19 10l252007 14:34 17.46 2.05 84.2 10125/2007 14:35 17.41 2.06 82.99 1 QJ2512007 14:36 17.4 1.99 83 1012512007 14:37 17.51 1.97 62.83 1012512007 14: 38 17.63 1:91 87.56 1012512007 14:39 17.69 1.91 62.6 1012512007 14:40 17.72 1.94 87.43 10/2512007 14:41 17.63 1.94 85.52 1012512007 14:42 17.62 1.96 65.47 10/25l2007 14:43 17.38 2.14 85.63 102512007 14:44 17.05 2.25 85.87 101252007 14:45 17.09 2.24 85.13 02 CO2 S02 16.92 2.25 84.01 Anrlyar Rradtep wt co ~ Y• Yo ppm forPost

- TcstCill6aG4om.

SYSTEM CALIBRATION BIAS AND DRIFTDATA GAS ANALY2EFt PRE-TEST '/e Pnss POST-TEST °h % Pass UNTfS VALLiE CIECK SPAN YESWO CIiECK SPAN DRg'T YESVN0 02, °N. 0.00 0.07 031 YES 0.09 0.40 0.09 YES 02, °Yo 22.65 2221 1.94 YES 22.23 1.77 0.18 YES CO2, % 0.00 0.19 1.06 YES 0.21 1.17 O.l l YES CO2, % 17.79 17.38 229 YES 17.35 2.46 0.17 YES S02, ppm 0.00 0.00 0.00 YES 0.00 0.00 0.00 YES _ S02, oom 125.4 129.6 1.79 YES 129.5 1 75 0.04 YES UNCORRECTED ANALYZ,ER VALUES

DRY OZ, % 16.9 CO2, °h 22 S02, ppm 84.0 ANALY2ER VALUES C'ORRECTED FOR DRIFT DRY 02, % 17.2 CO2. •k 2.1 S02, ppm 82.3

EIvIISSION RATES Volumcvic Fiow (DSCFItii): 13.205 S02 (Ib/ht) 10.82
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### CATALYST AIR MANAGEMENT lnc.

Stratification Test

~ a 

### i`•J CLIL'NT: Florim USA PLANT: Clarksville, TN OPERATING LEVEL: High TEST: Stratification START: 10:32 LOCATION: Stack END: 10:40 llia: 42.00



### Port A Point % Date Time 02 [%] CO2 [%] S02 [ppm] 

### In. 16.7 10/25/2008 10:32 17.27 2.18 61.51 7.01 10/25/2008 10:33 17.33 2.23 59.56

10/25/2008 10:34 17.28 2.23 56.56

50.0 10/25/2008 10:35 17.27 2.23 56.35 21.00 10/25/2008 10:36 17.22 2.27 59.49

10125/2008 10:37 17.15 2.22 61.85

83.3 10/25/2008 10:38 17.02 2.36 62.71 34.99 10/25/2008 10:39 17.03 2.3 60.87

10/25/2008 10:40 17.11 2.24 61.57



### Port I3 Point % Date Time 02 [%] CO2 [%] NOx [ppm] 

### In. 16.7 10/25/2008 10:49 16.96 2.36 52.49 7.01 10/25/2008 10:50 16.93 2.38 56.39

10/25/2008 10:51 16.93 2.29 58.2

50.0 10/25/2008 10:52 17.04 2.27 59.19 21.00 10/25/2008 10:53 17.01 2.32 60.72

10/25/2008 10:54 16.95 2.38 62.14


### 83.3 10/25/2008 10:55 16.95 2.43 61.98 34.99 10/25/2008 10:56 16.77 2.51 64.86

10/25/2008 10:57 16.68 2.54 67.11

Average 17.05 2.32 60.20 

### Avg. 02 [%] Avg. CO2 [%] Avg. S02
% Diff % Diff % Diff

17.29 -1.43 2.21 4.55 59.21 1.64

17.21 -0.96 2.24 3.40 59.23 1.61

17.05 -0.02 2.30 0.81 61.72 -2.52

Avg. 02 [%] Avg. CO2 [%] Avg. S02



### % Diff % Diff % Diff

16.94 0.65 2.34 -1.05 55.69 7.48

17.00 0.29 2.32 -0.19 60.68 -0.81

16.80 1.47 2.49 -7.52 64.65 -7.40

### CATALYST AIR MANAGEMENT

Method 26A Isokinetic Sample Sheet

Client: Florim USA Unit Tested: Baghouse Sampling Location: Stack

Run No: 1 Date: 10/25/07 Start Time: 10:45 End Time: 11:52

DIAMETER OF NOZZLE: 0.328 DIAMETER OF STACK: 42.0 inches AREA OF NOZZLE: 5.868E-04 A. AREA OF STACK: 9.6 sq. ft. BAROMETRIC PRESSURE: 29.12 Pb, VOLUME OF MOISTURE: 46.1 V i

, GAS METER Y-FACTOR: 1.00 Y PITOT COEFFIC]ENT: 0.84 Cp

GAS VEL PM 1VIETER TEMP STACK STATIC POINT TIlyIE IyIBTER HEAD ORIFICE IN OUT TEMP CO2 02 PRESS SDE VEL

215.245 A-1 2.5 217.1 0.20 1.60 79 79 290 2.3 17.2 -0.29 12.25 30.5 2 2.5 218.9 0.22 1.70 79 79 298 12.91 32.2 3 2.5 220.8 0.23 1.80 79 79 301 13.23 33.0 4 2.5 222.8 0.24 1.90 79 79 301 13.51 33.7 5 2.5 224.8 0.24 1.90 79 79 299 13.50 33.6 6 2.5 226.8 0.24 1.90 79 79 290 13.50 33.6 7 2.5 228.8 0.24 1.90 79 79 300 13.51 33.7 8 2.5 230.8 0.25 2.00 80 80 300 13.78 34.4 9 2.5 232.7 0.22 1.70 80 80 298 12.91 32.2 10 2.5 234.6 0.21 1.70 80 80 297 12.61 31.4 11 2.5 236.4 0.20 1.60 80 80 297 12.30 30.7 12 2.5 238.114 0.16 1.30 81 81 289 10.95 27.3

238.114 B-1 2.5 239.9 0.22 1.70 81 81 291 12.85 32.0 2 2.5 241.8 0.23 1.80 81 81 297 13.20 32.9 3 2.5 243.9 0.24 1.90 81 81 297 13.48 33.6 4 2.5 246.0 0.26 2.10 81 81 299 14.05 35.0 5 2.5 248.2 0.29 2.30 81 81 300 14.85 37.0 6 2.5 250.4 0.29 2.30 81 81 300 14.85 37.0 7 2.5 252.4 0.25 2.00 82 82 300 13.78 34.4 8 2.5 254.3 0.22 1.70 82 82 299 12.92 32.2 9 2.5 256.2 0.21 1.70 82 82 298 12.62 31.4 10 2.5 258.1 0.20 1.60 82 82 295 12.29 30.6 11 2.5 259.8 0.16 1.30 82 82 292 10.97 27.3 12 2.5 261.431 0.16 1.30 82 82 288 10.94 27.3 RESULT,E TT V1VI SQR PIT PM

60.0 46.186 0.472 1.779 net net avg avg

P : = 29.10 Vm(nd) = 44.091 B ws = 0.047 Ma = 29.05



### STACK GAS VELOCITY = 32.4 AFPS VS 

### STACK GAS VELOCITY = 1,942 AFPM 

### STACK GAS VOLUME = 12,082 DSCFM 

### Qsca STACK GAS VOLUME = 18,686 ACFM 

### Qa ISOKINETIC RATIO = 99.8 % TM TS CO2 02 STATIC 81 297 2.3 17.2 -0.29 avg avg avg avg avg

Vw(ne) = 2.171 %M= 4.69 N1, = 28.53 MD= 0.95

EMISSIONS HCl HF C12 F2 Weight, mg = 64.0 2.5 0.74 0.15 *< RDL gr/dscf = 0.022 0.001 0.000 0.000 lbs/hr = 2.32 0.09 0.03 0.01 

# 1. '1

### CATALYST AIR MANAGEMENT

iVlethod 26A Isokinetic Sample Sheet

Client: Florim USA Unit Tested: Baghouse Sampling Location: Baghouse Stack

Run No: 2 Date: 10/25/07 Start Time: 12:20 End Time: 13 :27

DIAMETER OF NOZZLE: 0.328 DIAMETER OF STACK: 42.0 inches AREA OF NOZZLE: 5.868E-04 A, AREA OF STACK: 9.6 sq. ft. BAROMETRIC PRESSURE: 29.12 I'ba, VOLUME OF MOISTURE: 43:0 Via GAS METER Y-FACTOR: 1.00 Y PITOT COEFFICIENT: 0.84 Cp

GAS VEL PM METER TEMP STACK STATIC POINT TIME METER HEAD ORIFICE IN OUT TEMP CO2 02 PRESS SDE VEL

265.047 B-1 2.5 267.2 0.28 2.20 81 81 300 2.3 17.3 -0.29 14.59 36.3 2 2.5 269.3 0.28 2.20 82 82 301 14.60 36.3 3 2.5 271.6 0.30 2.40 82 82 301 15.11 37.6 4 2.5 273.9 0.31 2.40 82 82 302 15.37 38.3 5 2.5 276.1 0.31 2.40 83 83 302 15.37 38.3 6 2.5 278.4 0.30 2.40 83 83 301 15.11 37.6 7 2.5 280.7 0.30 2.40 84 84 301 15.11 37.6 8 2.5 282.8 0.22 2.30 84 84 302 12.92 32.2 9 2.5 284.9 0.25 2.00 84 84 303 13.81 34.4 10 2.5 287.0 0.25 2.00 85 85 302 13.80 34.4 11 2.5 288.8 0.20 1.60 85 85 295 12.29 30.6 12 2.5 290.668 0.20 1.60 85 85 289 12.24 30.5

290.668 A-1 2.5 292.7 0.24 1.90 84 84 298 13.49 33.6 2 2.5 294.6 0.26 2.10 84 84 300 14.06 35.0 3 2.5 296.9 0.26 2.10 84 84 302 14.08 35.0 4 2.5 298.9 0.27 2.10 84 84 302 14.34 35.7 5 2.5 301.0 0.27 2.10 84 84 302 14.34 35.7 6 2.5 303.1 0.27 2.10 84 84 302 14.34 35.7 7 2.5 305.3 0.29 2.30 84 84 302 14.87 37.0 8 2.5 307.7 0.30 2.40 85 85 304 15.14 37.7 9 2.5 309.7 0.26 2.10 85 85 301 14.07 35.0 10 2.5 311.6 0.22 1.70 85 85 300 12.93 32.2 11 2.5 313.5 0.21 1.70 85 85 300 12.63 31.4 12 2.5 315.390 0.20 1.60 85 85 292 12.26 30.5 EtESULTI, TT VM SQR PIT PM

60.0 48.475 0.509 2.088 net net avg avg

Ps = 29.10 Vm(sw) = 46.025 B ws = 0.042 Md = 29.06

STACK GAS VELOCITY = 34.9 AFPS Vs STACK GAS VELOCTTY = 2,096 AFPM STACK GAS VOLUME = 13,049 DSCFM Q:id STACK GAS VOLUME = 20,169 ACFM Q& ISOKINETIC RATIO = 96.4 % TM TS CO2 02 STATIC 84 300 2.3 17.3 -0.29 avg avg avg avg avg

Vw(std) = 2.025 %M= 4.21 M, = 28.60 MD= 0.96

EMISSIONS HCl HF C12 F2 Weight, mg = 74.0 2.8 0.80 0.57 gr/dsef = 0.025 0.001 0.000 0.000 lbs/hr = 2.77 0.10 0.03 0.02 

# 1.5

## CATALYST AIR MANAGEMENT

Method 26A Isokinetic Sample Sheet

Client: Florim USA Unit Tested: Baghouse Sampling Location: Baghouse Stack

Run No: 3 Date: 10/25/07 Start Time: 13:45 End Time: 14:53

DIAIVMETER OF NOZZLE: 0.328 DIAMETER OF STACK: 42.0 inches AREA OF NOZZLE: 5.868E-04 A„ AREA OF STACK: 9.6 sq. ft. BAROMETRIC PRESSURE: 29.12 Pbu VOLUME OF MOISTURE: 45.4 vi c GAS METER Y-FACTOR: 1.00 Y PITOT COEFFICIENT: 0.84 CP

GAS VEL PM METER TEMP STACK STATIC 

### POINT TEVIE METER HEAD ORIFICE IN OUT TEMP CO2 02 PRESS SDE VEL

315.615 A-1 2.5 317.7 0.26 2.10 83 83 302 2.3 17.3 -0.29 14.08 35.1 2 2.5 319.8 0.27 2.10 83 83 302 14.34 35.7 3 2.5 321.9 0.26 2.10 83 83 302 14.08 35.1 4 2.5 324.0 0.27 2.10 83 83 302 14.34 35.7 5 2.5 326.1 0.27 2.10 83 83 302 14.34 35.7 6 2.5 328.3 0.28 2.20 84 84 303 14.62 36.4 7 2.5 330.4 0.28 2.20 84 84 303 14.62 36.4 8 2.5 332.6 0.28 2.20 84 84 303 14.62 36.4 9 2.5 334.7 0.26 2.10 84 84 301 14.07 35.0 10 2.5 336.7 0.23 1.80 85 85 301 13.23 32.9 11 2.5 338.6 0.21 1.70 85 85 301 12.64 31.5 ' 12 2.5 340.464 0.20 1.60 85 85 294 12.28 30.6 6 340.464 B-1 2.5 342.5 0.26 2.10 85 85 298 14.04 35.0 2 2.5 344.5 0.29 2.30 85 85 300 14.85 37.0 3 2.5 346.7 0.26 2.30 85 85 302 14.05 35.0 4 2.5 349.1 0.30 2.40 85 85 303 15.13 37.7 5 2.5 351.253 0.31 2.40 85 85 303 15.38 38.3 6 2.5 353.5 0.31 2.40 85 85 302 15.37 38.3 7 2.5 355.8 0.30 2.40 85 85 302 15.12 37.7 8 2.5 358.0 0.29 2.30 86 86 301 14.86 37.0 9 2.5 360.1 0.26 2.10 85 85 300 14.06 35.0 10 2.5 362.1 0.25 2.00 85 85 300 13.78 34.3 11 2.5 364.0 0.21 1.70 85 85 298 12.62 31.4 12 2.5 365.803 0.20 1.60 85 85 292 12.26 30.5 

### RESULT ~ 

### TT VM SQR PIT PM

60.0 50.188 0.512 2.096 

### net net avg avg
P s = 29.10 Vm(scd) ° 47.601 Bws = 0.043 Md = 29.05



### STACK GAS VELOCITY = 35.1 AFPS Vs STACK GAS VELOCITY = 2,109 AFPM STACK GAS VOLUME = 13,107 DSCFM Qsut STACK GAS VOLUME = 20,291 ACFM Qn ISOKINETIC RATIO = 99.3 % TM TS CO2 02 STATIC 84 301 2.3 17.3 -0.29 avg avg avg avg avg

V~~ d) = 2.138 %M= 4.30 

### Ms= 28.58 MD= 0.96

EIvIISSIONS HCl HF C12 F2 Weight, mg = 71.0 2.5 0.73 0.15 *< RDL gr/dscf = 0.023 0.001 0.000 0.000 

### lbs/hr = 2.59 0.09 0.03 0.01 

# f. ~

### CATALYST AIR MANAGEMENT Inc. CALIBRATION 

### DATA

CLIENT: Florim RUN #: 1-3 

### PLANT: Clarksville Tn. 

### LOAD LEVEL: High UNTT: Baghouse 

### DATE: 10/25l2007 TEST: 3A 

### LOCATION: Stack

GAS ANALYZER CYLINDER ANALYZER DIFF % Pass UNITS SCALE VALiJE VALUE PPM SPAN Yes1No 02, % 0.00 0.00 0.00 0.00 

### YES 02, % 25 13.09 13.12 0.03 0.13 

### YES 02, % 22.64 22.65 0.01 0.04 

### YES

CO2, % 0.00 0.00 0.00 0.00 

### YES CO2, % 20 9.902 9.92 0.02 0.10 

### YES CO2, % 17.88 17.88 0.00 0.00 

### YES

RUN 

### I SYSTEM CALIBRATION BIAS AND DRIFT DATA GAS ANALYZER PRE-TEST % Pass POST-TEST % % Pass UNITS VALUE CHECK SPAN YES1N0 CHECK SPAN DRIFT 

### YESWO 02, % 0.00 0.00 0.00 

### YES 0.05 0.22 0.22 

### YES 02, % 22.65 22.31 1.50 

### YES 22.29 1.59 0.09 

### YES

CO2, % 0.00 0.12 0.67 

### YES 0.17 0.95 0.28 

### YES CO2, % 17.88 17.51 2.07 

### YES 17.49 2.18 0.11 

### YES

UNCORRECTED ANALYZER VALUES ANALYZER VALUES CORRECTED FOR DRIFT

DRY DRY 02, % 17.00 02, % 17.2 CO2, % 2.35 CO2, % 2.3



### RUN 2 SYSTEM CALIBRATION BIAS AI`TD DRIFT DATA GAS ANALYZER PRE-TEST % Pass POST-TEST % % Pass UNITS VALUE CHECK SPAN YESWO CI-iECK SPAN DRIFT YESWO 02, % 0.00 0.05 0.22 

### YES 0.07 0.31 0.09 

### YES 02, % 22.65 22.29 1.59 

### YES 22.21 1.94 0.35 

### YES

CO2, % 0.00 0.17 0.95 

### YES 0.19 1.06 0.11 

### YES CO2, % 17.88 17.49 2.18 

### YES 17.38 2.80 0.62 

### YES



### UNCORRECTED ANALYZER VALUES ANALYZER VALUES CORRECTED FOR DRIFT

DRY DRY 02, % 17.01 02, % 17.3 CO2, % 2.43 CO2, % 2.3


### RUN 3 SYSTEM CALIBRATION BIAS AND DRIFT DATA GAS ANALYZER PRE-TEST % Pass POST-TEST % % Pass UNITS VALUE CHECK SPAN 

### YESWO CHECK SPAN DRffT YESWO 02, % 0.00 0.07 0.31 

### YES 0.09 0.40 0.09 

### YES 02, % 22.65 22.21 1.94 

### YES 22.25 1.77 0.18 

### YES
CO2, % 0.00 0.19 1.06 

### YES 0.21 1.17 0.11 

### YES CO2, % 17.88 17.38 2.80 

### YES 17.35 2.96 0.I7 

### YES

UNCORRECTED ANALYZER VALUES 

### ANALYZER VALUES CORRECTED FOR DRIFT

DRY DRY 02, % 17.01 02, % 17.3 CO2, % 2.36 CO2, % 2.3 

### j . 

# . fRun 1

DATE TIME 02 CO2 1012512007 10:45 17.09 2.24 10/2512007 10:46 17.11 2.24 10/25/2007 10:47 17.13 2.31 10/25/2007 10:48 17.02 2.36 10/25/2007 10:49 16.96 2.36 10125/2007 10:50 16.93 2.38 10/25/2007 10:51 16.93 2.29 1012512007 10:52 17.04 2.27 10/25/2007 10:53 17.01 2.32 10/25/2007 10:54 16.95 2.38 10/25/2007 10:55 16.95 2.43 10/25/2007 10:56 16.77 2.51 10/25/2007 10:57 16.68 2.54 10/25/2007 10:58 16.68 2.5 10/25/2007 10:59 16.61 2.51 10/25/2007 11:00 16.62 2.54 10/25/2007 11:01 16.63 2.51 10/25/2007 11:02 16.76 2.51 10125/2007 11:03 16.81 2.49 10/2512007 11:04 16.78 2.47 10/25/2007 11:05 16.85 2.42 10125/2007 11:06 16.91 2.32 10125/2007 11:07 17.06 2.26 10125/2007 11:08 17.17 2.22 10125/2007 11:09 17.27 2.18 10/25/2007 11:10 17.33 2.23 10/25/2007 11:11 17.28 2.23 10/25/2007 11:12 17.25 2.23 1012512007 11:13 17.26 2.2 10/25/2007 11:14 17.3 2.11 10/25/2007 11:15 17.14 2.27 10125/2007 11:22 17.18 2.22 10/25/2007 11:23 17.22 2.22 10/25/2007 11:24 17.16 2.26 10/25/2007 11:25 17.13 2.36 10125/2007 11:26 17.01 2.39 10/25/2007 11:27 17.02 2.37 10125/2007 11:28 16.98 2.37 10125/2007 11:29 16.93 2.33 10/2 5/2007 11: 30 17.01 2.33 10/25/2007 11:31 17.14 2.24 10/25/2007 11:32 17.19 2.28 1012512007 11:33 17.15 2.35 1012512007 11:34 17.05 2.36 10125/2007 11:35 17.02 2.36 10/25/2007 11:36 17.03 2.3 10/25/2007 11: 37 17.11 2.24 10/25/2007 11:38 17.18 2.24 10/25/2007 11:39 17.17 2.26 10/2512007 11:40 17.14 2.36 10/2512007 11:41 17 2.4 10/25/2007 11:42 16.92 2.42 10/25/2007 11:43 16.92 2.4 10125/2007 11:44 16.87 2.36 10/25/2007 11:45 16.94 2.36 10/25/2007 11:46 16.96 2.35 10/2512007 11:47 17.02 2.37 10/25/2007 11:48 16.89 2.51 10/25/2007 11:49 16.76 2.51 10/25/2007 11:50 16.76 2.51 10125/2007 11:51 16.76 2.45 10/25/2 007 11:52 16.81 2.4 17.00 2.35 Run 2 DATE TIIVIE 02 CO2 1012512007 12:20 19.61 6.41 1012512007 12:21 16.98 2.52 10125/2007 12:22 16.93 2.4 10/25/2007 12:23 17.02 2.38 10/25/2007 12:24 17.03 2.36 10/25/2007 12:25 17.03 2.4 10/2512007 12:26 16.98 2.45 10/2512007 12:27 16.88 2.45 10125/2007 12:28 16.88 2.45 10/25/2007 12:29 16.88 2.37 10/25/2007 12:30 16.97 2.32 10/2512007 12:31 17.03 2.31 10/25/2007 12:32 17.04 2.31 10/2512007 12:33 17.03 2.4 1012512007 12:34 16.92 2.42 1012512007 12:35 16.89 2.42 10/2512007 12:36 16.88 2.4 10/25/2007 12:37 16.9 2.32 10/25/2007 12:38 17 2.3 10125/2007 12:39 17.03 2.3 1012512007 12:40 17.02 2.33 10/2512007 12:41 16.99 2.41 10/25/2007 12:42 16.89 2.42 10/25/2007 12:43 16.89 2.42 10/25/2007 12:44 16.87 2.36 10125/2007 12:45 16.92 2.3 1012512007 12:46 17.01 2.29 10/25/2007 12:47 17.01 2.3 1012512007 12:48 17.01 2.38 10/2512007 ! 12:49 16.93 2.41 10/25/2007 12:50 16.87 2.41 10/2512007 12:57 16.91 2.41 10/25/2007 12:58 16.9 2.41 10125/2007 12:59 16.9 2.37 10/2512007 13:00 16.94 2.29 10/2512007 13:01 17.03 2.29 1012512007 13:02 17.04 2.29 10/25/2007 13:03 17.04 2.36 10/25/2007 13:04 16.98 2.41 10/25/2007 13:05 16.9 2.41 10/25/2007 13:06 16.91 2.41 10/25/2007 13:07 16.91 2.32 10/2512007 13:08 16.99 2.3 1012512007 13:09 17.03 2.29 10/25/2007 13:10 17.04 2.31 10/25/2007 13:11 17.03 2.39 10/2512007 13:12 16.93 2.41 10/25/2007 13:13 16.91 2.41 10125/2007 13:14 16.91 2.38 1012512007 13:15 16.94 2.3 10126/2007 13:16 17.04 2.3 10/25/2007 13:17 17.04 2.29 10/2512007 13:18 17.06 2.34 10125/2007 13:19 17 2.41 10/25/2007 13:20 16.92 2.41 10125/2007 13:21 16.92 2.41 10125/2007 13:22 16.92 2.34 10125/2007 13:23 16.98 2.3 10125/2007 13:24 17.05 2.3 10/2512007 13:25 17.05 2.3 10/25/2007 13:26 17.05 2.39 10125/2007 13:27 16.96 2.42 17.01 2.43 Run 3 DATE TUAE 02 CO2 1012512007 13:45 16.94 2.31 10125/2007 13:46 17.04 2.29 10125/2007 13:47 17.07 2.3 10/25/2007 13:48 17.06 2.32 10/25/2007 13:49 17.05 2.4 10/25/2007 13:50 16.95 2.42 10125/2007 13:51 16.93 2.42 1012512007 13:52 16.93 2.37 10125/2007 13:53 16.97 2.3 10/25/2007 13:54 17.06 2.29 10/25/2007 13:55 17.06 2.29 10/25/2007 13:56 17.07 2.36 10/25/2007 13:57 17.01 2.41 10/25/2007 13:58 16.94 2.41 10/2512007 13:59 16.93 2.41 10125/2007 14:00 16.95 2.32 10/2512007 14:01 17.04 2.28 10/25/2007 14:02 17.08 2.29 10/25/2007 14:03 17.1 2.29 10/25/2007 14:04 17.08 2.39 10/25/2007 14:05 16.98 2.4 1012512007 14:06 16.96 2.41 10125/2007 14:07 16.95 2.38 10/2512007 14:08 16.98 2.29 10/25/2007 14:09 17.07 2.3 10/2512007 14:10 17.08 2.28 10/2512007 14:11 17.07 2.35 1012512007 14:12 17.03 2.41 10125/2007 14:13 16.94 2.42 10125/2007 14:14 16.94 2.42 10/25/2007 14:15 16.93 2.34 10/25/2007 14:20 16.97 2.42 10/25/2007 14:21 16.93 2.42 10/25/2007 14:22 16.92 2.4 10/25/2007 14:23 16.93 2.32 10125/2007 14:24 17.02 2.3 10/25/2007 14:25 17.05 2.3 10/25/2007 14:26 17.05 2.34 10/25/2007 14:27 17.02 2.42 10/25/2007 14:28 17.01 2.3 10125/2007 14:29 17.01 2.38 10/2512007 14:30 16.93 2.41 10/25/2007 14:31 16.87 2.41 1012512007 14:35 16.94 2.29 10/25/2007 14:36 17.03 2.29 10/25/2007 14:37 17.04 2.29 10/25/2007 14:38 17.04 2.36 10/25/2007 14:39 16.98 2.41 10/25/2007 14:40 16.9 2.41 1012512007 14:41 16.91 2.41 10125/2007 14:42 16.91 2.32 10/25/2007 14:43 16.99 2.3 1012512007 14:44 17.03 2.29 10125/2007 14:45 17.04 2.31 10125/2007 14:46 17.03 2.39 10/2512007 14:47 16.93 2.41 10l2512007 14:48 16.91 2.41 10/2512007 14:49 16.91 2.38 10/2512007 14:50 17.25 2.41 10/2512007 14:51 17.25 2.41 10/25/2007 14:52 17.24 2.41 10/2512007 14:53 17.24 2.41 17.01 2.36



# Wol

## CATALYST AI R MANAG E M E NT, I N C_ (865) 531-0075 Air Quality Testing Services (865) 531-0750 Fax 2505 Byington Sofway Road Knoxville, TN 37931



## Client

- pC-v sZzrm Plant 

## A64 21A.S 

## 1/L'Lf.0 Location 

## Test Run ~ Date 

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COMMENTS:



# 1.9

## CATALYST A1 F;t MANAG E M E NT, Air Quality Testing Services 2505 Byington-Solway Road Knoxville, TN 37931
PLANT: 

### rz4 '"'' DATE: 1 y 

### 1 13 d' 

### SAMPLING TIME: (24 HR C 

## LA CK) /

~ 

### yS — 

# 5 Z SAMPLING LOCATIO '

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### SAMPLING TYPE: ••c-uac.S 

### ANALYTICAL MET OD: 3-f ZG4 

### AM. TEMP (°F) 7 z TECHNICIAN: So--- 1 N C . (865) 531-0075 (865) 531-0750 Fax



# 41

RUN 2 3 AvenAae GAS vo ~ ~ Fo (TEST}= 20 ' 9-0 ~ ACTUAL ACTUAL ACTUAL

NET NET NET 5

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## APPENDIX 2 PLANT D:A.TA



## ~~

## Florim USA Baghouse Ap Data

Run 1 Run 2 Run 3
1045 1.0 inches H20 1220 1.0 1345 1.0 1055 1.0 1225 1.0 1350 1.0 1100 1.0 1230 1.0 1355 1.0 1105 1.0 1235 1.0 1400 1.0 1110 1.0 1240 1.0 1405 1.0 1115 1.0 1245 1.0 1410 1.0 1120 1.0 1250 1.0 1415 1.0 1125 1.0 1255 1.0 1420 1.0 1130 1.0 1300 1.0 1425 1.0 1135 1.0 1305 1.0 1430 1.0 1140 1.0 1310 1.0 1435 1.0 1145 1.0 1315 1.0 1440 1.0 1150 1.0 1320 1.0 1445 1.0 1155 1.0 1325 1.0 1450 1.0

~ ) 6 

## ti

## APPENDIX 3 

# LAB AN.AI ,YSZS 

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27

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### Your Project #: FIORIM Site: BAGHOUSE

Attention: Mike Tavlor Catalyst Air Management 2505 Byington-Solway Rd Knoxville, TN USA 37931

Report Date: 2007111/20


### CERTIFICATE OF ANALYSIS
MAX.XAM JOB #: A7C2798 Received: 2007/11/06,12:00 Sample Matrix: SAMPLING TRAIN # Samples Received: 8

Date Date Method Analyses Quantitl+ Extracted AnalYzed Lalsoratory Method Reference Halogens In NaOH Impinger (M26A) 4 2007/11/16 2007/11/16 BRL SOP-00108 EPA Method 26A Hydrogen Halides iri H2SO4 Imp. (M26A) 4 2007/11/13 2007/11/13 BRL SOP-00104 EPA Method 26A Fnal Volume of Impinger 4 2007/11/13 2007/11/13 Final Valume of Impinger 4 2007/11/16 2007/11/16

~ _ f ✓

~ ' /
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### PM Released by : JIM POWER, CET

Project Manager

Total cover pages: 1

Page 1 of 6

5555 North Servica Road, Burlington, Onterio, Canada 1.71- 51-17 Tel: (905) 332-8788 Toll Free: (800) 668-0639 Fax: (905) 332-9169 

# N 8

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a I y s I c s 1 n c WWVi:II]if]C]Catriaria1yTtcS.c7QI Catalyst Air Management Maxcam Job #: A7C2798 Client Project #: FIORIM Report Date: 2007/11120 Project name: BAGHOUSE Sampler initials: 

### RESULTS OF ANALYSES OF SAMPLING TRAIN

MaxxamlD V69346 V69350 V69351 V69351 Sampling Date 2007110125 2007110125 2007/10/25 2007/10125

Units 26A-BLANK M26A-R1 RDL M26A-112 M26A-R2 RDL QC Batch

H2SO4 IMP-1+2 iMP-1+2 IMP-1+2 Lab-Du Hydrochloric Acid ug <1000 64000 1000 74000 74000 2000 1405231 Hydrofluoric Acid ug <750 2500 750 2800 2900 1500 1405231 oiume ml 390 350 1 320 N1A 1 1404324 N1A = Not Applicable RDL = Reportable Detection Limit QC Batch = Quality Control Batch

axxamlD V69352 V69358 V69359 V69360 amplina Date 2007/10/25 2007/10/25 2007110125 2007110125

Units M26A-R3 ZC Batch 6A-BLANK

IMP-1+2 NAOH M26A-R1 IMP4+4 M26A-R2

IMP-3+4 RDL CIC Batch

Hydrochloric Acid ug 71000 1405231 N1A N/A N/A 200 1405231 Hydrofluoric Acid ug 2500 1405231 NlA N/A N1A 750 1405231 Chlorine ug N1A 1408167 <200 740 800 200 140 8 1 6 7 Fluorine ug N/A 1408167 <150 <150 1 570 150 1408167 olume mi 300 1404324 780 300 280 1 1407206 N/A = Not Applicable RDL = Reportable Detection Limit QC Batch = Quality Control Batch

Maxxam ID V69360 V69362 am lin Date 2007/10/25 2007/10/25

Units M26A-112 M26A-R3 RDL QC Batch

iMP-3+4 IMR3+4 Lab-Du

Chlorine ug 780 730 200 1408167 Fluorine ug 570 <150 150 1408167 Volume ml N!A 250 1 1407206 N/A = Not Applicable RDL = Reportable DetectPon Limit QC Batch = Quality Control Batch

Page 2 of 6
5555 Notth Service Road, Burtington, Cntavio, Canada 1.71- 51-17 Tel: (905) 332-8788 Toll Free: (800) 668-0639 Fax: (905) 332-9169

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,,lytie, O„e www.inaxxacnanulyticx.com Catalyst Air Management Maxxam Job #: A7C2798 Client Project #: FIORIM Report Date: 2007/11/20 Project name: BAGHOUSE Sampler Initials: 

### Test Summary

Maxxam ID V69346 Collected 2007/10/25 Sample ID M26A-BLANK H2SO4 Shipped Matrix SAMPLING TRAIN Received 2007/11/06

Maxxam ID V69350 Collected 2007/10/25 Sample ID M26A-R1 lMP-1+2 Shipped Matrix SAMPLING TRAIN Received 2007/11106

Maxxam ID V69351 Collected 2007110/25 Sample ID M26A-R2 IMP-1+2 Shipped Matrix SAMPLING TRAIN Received 2007111106

Maxxam ID V69351 Dup Collected 2007110125 Sample ID M26A-R2 IMP-1+2 Shlpped Matrix SAMPLING TRAIN Recelved 2007/11/06
Test Descri tion Instrumentation Batch Prepared Analyzed Anal t 

# l Hydrogen Halides in H2SO4 Im . M26A IC/SPEC 1405231 2007/11/13 2007/11/13 A S

Maxxam ID V69352 Collected 2007110/25 Sample ID M26A-R3 IMP-1+2 Shipped Matrix SAMPLING TRAIN Recelved 2007/11/06

Maxxam ID V69358 Collected 2007/10/25 Sample ID M26A-BLANK NAOH Shipped Matrix SAMPLING TRAIN Received 2007/11/06

Page 3 of 6
5555 North Service Road, Ber[irsgton, Orstario; Canada 1.71. 51-17 Tel: (905) 332-8788 Toll Free: (800) 868-0839 Feoc (905) 332-9169 Test

Test



# 30

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## M ~ .e.., . i y e + t : I .+ c www.mazsamanalyttcs.com Catalyst Air Management Maxxam Job #: A7C2798 Client Project #: FIORIM Report Date: 2007/11/20 Project name: BAGHOUSE Sampler Initials: 

### Test Summary

Maxxam ID V69359 Collected 2007/10/25 Sampie ID M26A-R1 IMP-3+4 Shipped Matrix SAMPLING TRAIN Received 2007/11106

Test Descrl

Maxxam ID V69360 Collected 2007/10/25 Sampie ID M26A-R2 IMP-3+4 Shipped Matrix SAMPLING TRAIN Received 2007/11106

Maxxam ID V69360 Dup Coilected 2007/10/25 Sample ID M26A-R2 IMP-3+4 Shipped Matrix SAMPLING TRAlN Received 2007111/06

Test Descri tion Instrumentatlon Batch Prepared Analyzed Analyst 

## I Halogens in NaOH Im in er M26A lC1SPEC 1408167 2007/11116 2007/11/16 A S

Maxxam ID V69362 Co{lected 2007/10/25 Sampie ID M26A-R3 IMP-3+4 Shipped Matrix SAMPLING TRAIN Received 2007/11/06

Test EN

Page 4 of 6
5555 North Service Road, Buriington, Ontario, Cenada 1-71- SH7 Tel: (905) 332-8788 Toll Free: (800) 668-0639 Fax: (905) 332-9169



### ~ ~~ /~ 

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~ ..iysi« I.,c R*ww.maxxawanalytics.coni Catalyst Air Management Maxcam Job #: A7C2798 Client Project #: FIORIM Report Date: 2007/11/20 Project name: BAGHOUSE Sampler Initials:

GENERAL COMMENTS

Results relate oniv to the items tested.

Page 5 of 6
5555 North Service Road, Burtington, Ontario, Canada 1.71- 6H7 Tel: (905) 332-8788 Toll Free: (800) 868-0639 Fax; (905) 332-9169 

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(V69351) Hydrochloric Acid 2007111/13 0, RDL=2000 104 ug 80 - 120

Hydrroftuoric Acid 2007/11/13 0, RDL=1500 105 ug 80 - 120 Spiked Blank Hydrochloric Acld 2007/11/13 0, RDL=200 98 ug 90 - 110

Hydroftuoric Acid 2007/11/13 0, RDL=150 99 ug 90 - 110 Method Blank Hydrochloric Acid 2007/11/13 <200 ug

Hydroftuorlc Acid 2007/11113 <150 ug RPD Hydrochloric Acid 2007/11/13 0.5 % 20

Hydrofluoric Acid 2007/11113 NC % 20 1408167 A S MATRIX SPIKE

(V69360) Chlorine 2007/11/16 0, RDL=200 95 ug 80 -120

Fluorine 2007/11116 0, RDL=150 95 ug 80 -120 SpEked Blank Chlorine 2007/11116 0, RDL=200 98 ug 90 -110

Fluorine 2007/11/16 0, RDL=150 100 ug 90 -110 Method Blank Chlorine 2007/11/16 <200 ug

Fluorine 2007/11/16 <150 ug RPD Chlorine 2007/11116 NC % 20

Fluorine 2007/11 /16 NC % 20
NC = Non-calculable RPD = Relative Percent Difference SPIKE = Fortified sample

Page 6 of 6
5555 North Servlce Road, Biutington, Ontario, Canada 1-71- 51-17 Tel: (905) 332-8788 Toll Free: (800) 668-0639 Fax: (905) 332-9169



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. . .. ....i..i: . : : • : :,:: Other Business Days MAXXAM Contact: 1 i i 1

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### ;_;. ,.:

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### i= •::

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### ;:s:•:::f'::' : Client Signature: Affiliation: ' ReCeJVed i3 

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### -'.i':_:.

~~ Affii'cation: T ~~ ~ 

### i1=• • 

### . : ::(: ~ i::;:i:,.. :. :;:.:..:

~ .. DateTme: Date
~ me: i •

.... :::.:s.::,: # :::::::;:.

. s •as, f.. ' WHfTE - lAB / YELLOW - CUI=NT - . ,rC vvcn rvn wm,

- s.c t n.r, ~ a JF1M 'UIYl1l1lVJ t F1Ui.1 N ~`~A BURLITK3TON COC406N06

## APPENDIX 4 REFERENCE METHOD QUAI.,ITY AS SURANCE

Isokinetic Sampling Equipment



# C)5C~ Catalyst Air Management, Inc.



### METER BOX NUMBER: DATE: CALIBRATED BY:

BENCI-I METER CALIBRATION FACTOK: 070 07r20/07 Love
1.0000

Orifice Standard Dry Standard Dry Gas Meter Manometer Test Gas Tcst Barometric Setting Meter Meter Meter Inlet Outlet Avera e Pressure Time ( o I-I ) Start: (VW) Start: (Vd) (TW) (TO (Tdo) (Td) (Pb) (Timc) In. H Z O Enrl: ft 3 End: ft 3 ° F ° F ° F ° F in. of Hg min. Y ; OH @ i Q M K m 0.50 376.875 5.353 874.320 5.383 72.3 72.3 72.3 72.3 30.10 12.35 0.99 1.48 0.436 0.789

382.228 879_703

1.00 382.228 5.310 879.703 5198 74.8 74.3 74.3 74.3 30.10 8.49 1.00 1.45 0.624 0.798

387.538 885.001

2.00 387.538 6.399 885.001 6.461 75.8 75.7 75.7 75.7 30.10 7.29 0.99 1.44 0.886 0.800

393.937 891.462

3.00 393.937 5.329 891.462 5.255 76.7 77.2 77.2 77.2 30.10 5.07 1.01 1.59 1.036 0.763

399.266 896.717

4.00 399.266 5.382 896.717 

# 1 1 5.298 77.3 77.2 77.2 7 30.10 4.31 1.01 1.51 1.229 0.783 404.648 902.015 Average: 1.00 1.50 FORMUI,AS



## Y ; = (V,,)(P, XT, + 460) 

# H (Vd )(p b + (T,, + 460)



## 13.6

_ ( P b ) ( 29 ) 

### K m- 

### ' ~ m 

## ( T 

## ,. )



## + 460 ( 

## A H) 0.9244 

## OH@ i = Z



# K m



# _ (Vd )(Tlo + 460) Qm - 

## (Time)(T do + 460.~ Catalyst Air Managcment, Inc.

POS'F-TEST METER BOX CALIBRATION
ME'1'ER BOX NUMBER: 070 DATE: 10/26/07 CALIBRATED BY: Kelly PRETEST Y i : 1.00 POST-TEST Y i : 1.03 fiFNCH METER CALIBRATION FACTOIt: 1.000 DIFFERENCE, % 2.70
Orifice Standard Dry Standard Dry Gas Meter Manometer Test Gas Test Baromctric Sctting Meter Meter Meter Inlet Outlet Avcra e Pressurc Time ( A H ) Start: (v w ) Start: (Vd) (T w ) ('I'.) fl'd.) ('I' d ) (Pb) (Time) In. H 2 0 Tsnd: R 3 End: fl 3 ° F ° F ° F °F in. of I Ig min. Y i AH(rr i Q. Km 2.10 858.985 8.618 365.888 8.324 66.0 64.3 64.3 64.3 30.10 10.00 1.03 1.68 0.832 0.741

867.603 374.212
2.10 867.603 8.S22 374.212 8.243 66.7 65.7 65.7 65.7 30.10 10.00 1.03 1.72 0.824 0.733

876.125 382.455
2.10 876.125 8.495 382.455 8.269 68.2 68.2 68.2 68.2 30.10 10.00 1.02 1.72 0.827 0.734

884.620 390.724 Average: 1.03 1.71 FORMULAS



# Y i (V,)(P b )(T d +460)



# _ (V-J( P b + 13 6J(Tw +460)

(pb)( 29 )
Km 

# - Qm (T,. +460)(OH) 0.9244 e~~@ I = K Z

m 

# (V,)(T,,. + 460) Q m 

# _ (Time)(T do + 460)

## CATALYST ALR MANAGEMENT, INC

Barometer Calibration Check Florim USA

DATE: I0/2212007 CALIBRATED BY: Kelly

Hg in glass Barometer (in Hg) 29.75 Field Barometer (in Hg) 29.77 Difference 0.02



# '~ ~

## CATALYST A1 R MANAG E M E NT, 1 N C- (865) 531-0075 

## Air Quality Testing Services (865) 531-0750 Fax 2505 Byington-Solway Road Knoxville, TN 37931

"S" TYPE PITOT TUBE CALIBRATION — INSPECTION

. 

# _ ,

~~. ~

.~ ~•

r i ~

O~ prN trfdl

~ tinp Mwl peslbist+ hr da.nnininp ar aed tsA. 

### ATTRIBUTE Level and Perpendicular? 

## Ye.5 Obstructed?

~ v 

### Damaged? ,c1 ~ al (-10° 5 al s+10°) 2 ~ a2 (-10° 5 (X2 5+10°) 2•O 

### P, (-5° s p, s+5°) 2• o 02 (-5 ° 5 02 5 +6*)



### e f • c7 Z=AtanY (50.125") ,a1

- 7 W= A tan 9(5 0.0.03125") ,c ~ t1 Di (3/16" 5 131 5 3/87 C), 37(0 

### A Q A S

- ? A/2Dj (1.05 s PA /Dj s 1.5) /•3 f O~pr~~ Inilrradnq Nwl pes

~ tior lsr dowrerrrwnp Ar .ne P%

1

t).y»a imd

f esfb+p Iwsl ►wi&n lot drtterfnifsinpQ 

# 9

» O~ -~Z ~

1

~ -

Y _!•- O~ prw inQiaafrsp bv

~ l poNhoe bf

dottminirt97then cstadatt L.



### QA / QC Check

~ 

### - Compieteness Legibility Accuracy Specifications 

## --
~ Reasonabieness



### Certification: 2 I certify that the Type "S" pitot tube / probe. ID# 

## ( ~ 

## "fa M d ' ? meets or exceeds all specifications criteria and or appii bie design features and is hereby n a pitot tu libration factor of Cp of 0.84


### Certified By: 

### lO / 

## 1 1 1 

## 0 Team Leader 

### /0 l 

## lq / 

## 06 Personn (Signature / Date Tea ea Signature / Date

~~

## CATALYST AIR MANAGEMENT, INC.

NOZZLE CALIBRATION SHEET
Client: Job No: 

# Zy3 -oo

~



### Nozzle No. 6 1csS 

### Y1 9

1 ST 2ND 

## o. 5 , Zb o 3Z6

Nozzle No.

I ST 2ND

Nozzle No.

1 ST 2ND

Nozzle No.

1 ST 2ND



### Nozzle No.

1 ST 2ND

Nozzle No.

1 ST 2ND

Calibrated Ey: Date: 16

. ZS` 03 

### 3RD AVG 

## a• ,32f

~ ~ 

## 3Z.c ~



### 3RD AVG

3RD AVG

3RD AVG

3RD AVG

3RD AVG



# 40

## CATALYST AIR MANAGEMENT, INC

K-TYPE THERMOCOUPLE CALIBRATION

Post Test Calibration Check Florim USA DATE: 10/26/2007 CALIBRATED BY: Nicely

AVG STACK TEMPERATURE: 299


### Thermocouple No; CAM 04

Std Therometer 306 

### Thermocouple 305 Difference 1 Difference % Absolute 0.1 Acceptance Criteria % 1.5



# nl

~

# 4 .2

# AirgaS K

~ AErgas Speeia(Ety Gases



# Certificate of Analysis: EPA Protocol Gas Mixture ~h~~:W ~ 

# 8 "`

~ °e Cylinder Number: SG9174632BAL Reference Number: 54-124077494-11 1-773-785-3000 Fax 1-773-785-1928 

### Cylinder Pressure: 2000.6 PSIG Expiration Date: 10l11/2009 http•Jh"w.airgas.com Certification Date: 1 0/1 1 12006 Laboratory: ASG - Chicago - IL 

### Certified Concentrations Component Concentration Accuracy Analytical Principle Procedure CARBON DIOXIDE 17.88 % +!-1% NDIR G1 OXYGEN 22.64 % +/-1% Paramagnetic G1 NITROGEN Balance Certification performed in accordance with "EPA Traceability Protocol (Sept. 1997)" using the assay procedures listed. Analytical Methodology does not require correction for analytical interferences.
Notes:



### ~~ .. Do not use cylinder below 150 psiq. Approval Signature _ 

### ~G~~~~~-'-~_

. .. .


### ~~ . 

### Reference Standard Information

Tvae Balance Gas ComAonent Cvl.Number - Concentration
NTRM 101705 CARBON DIOXIDE SG9162893BAL 17.89 % NTRM 060608 NITROGEN OXYGEN CC206134 22.51 % 

### Analytical Results 1st Component CARBO;N "DIOXIDE 2nd Component OXYGEN 1 st Analysis Date: 10/11/2006 1 st Analysis Date: 10/11 /2006 R 17.89 S 17.89 Z 0 Conc 17.89 % R 22.51 S 22.64 Z 0 Conc 22.64 % S 17.88 Z 0 R 17.89 Conc 17.88 % S 22.64 Z 0 R 22.51 Conc 22.64 % ; Z 0 R 17.89 S 17.88 Conc 17.88 % Z 0 R 22.51 S 22.64 Conc 22.64 % AVG: 17.88 % AVG: 22.64 %



# 1 43

# Aimrgas kX

Airgas Speciality Gases 

# CERTI]FIC.A .TE ®F AN.ALYSIS 12722

~.IL~8 ~~ u@ 

# Grade of Product: EI'A Protocol 1-773-785-3000 

# F AX: 1-773-785-1928 http:/twww.airgas.com



### Part Number. 

### E03N177E15A0614 Reference Number: 54-124099734-11 Cyiinder Number: 

## CC156502 Cylinder Voiume: 151 Cu.Ft. Laboratory: 

### ASG - Chicago - IL Cylinder Pressure: 2015 PSIG Analysis Date: 

### Jun 25, 2007 Valve Outiet: 

## 590 Expiration Date: Jun 25, 2010

CertMcatlor, pertormed In accordance wlth "EPA TraceabtiEty Protocol (Sept.1997)" using the assay procedures iisted. AnalyUcal Methodology does not require correction for anatytical interferences. This cyllnder has a total analyticat uncertainty as stated belaw wtth a confidence ievel of 95%. There are no signiftcant trnparitles which aRect the use of this catibra8on rnbcture. AII concentrations are cn a volumeMolume basis unless otherwise noted.

Do Not Use This Cvllnder below 150 psi9.i.e.1 Mega Pascal



## .
, „ 

### ~ 

## ALIBRA

~ 

## 'IO

~ 

## f STANDAR.DS •

~ = ~ 

### linder No e Lox ~l~D ~ ~~ ; 

### TYP ; : .; ,_.._ . ~ 

### Y Conceri

~ 

### 'ation rEx 1 ra`ticn D 

### F p

~ 4 ~ ~ ~ ~'

~ 

### 1TRM ' ' b8Q 0 ~~ '~~ 

### i''SG9161 Q59BAL ; . i

. . 

### 15 i86

~ 

### 2°/pdCAR

~ 

### ON DIOXIDE/ fiAay 01. 2040

~ 

### : NTRM " r r '$2

~ 

### 5$ ~ 

### ` " :SG9 ~1b8~Q~ 

### 4aAl: iA6:Q ~9~o ~~ 

### GEN/ ~

~ • . . ... .., - 

### Jar101,, 2010

' i

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## 1TAIX C24L EQU'

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## MEN T .

. .. . 

### ,lnstrvnient/MakefModel ~:;~ 

### _: .: : . . :.... ::.. .'.AnafyNca

~ 

### `P

~ 

### incipio• ; : 

## : :° LastMultipo

~ 

## intpalthration HORIBA:510 ' ; NDIR Jan 1

~ 

### t; 2007 11 

### . 

### CAI-11D :,
. Paramagn

~ 

### fi!:,. :

_ _ . .. 

### Jun 11,.2007 Triad Data Availabte Upon Request Notes:

~ 

### QA Approval

Page 1 of 54-124099734-11



### ,ti ~~

~

# Airgas k , x CERTIFICATE OF ANALXSIS



# Grade of Product: EPA Protocol Airgas Specfality 6ases 12722 S. Wentworth Avene Chicago, Il 60628 1-773-785-3000 Fax:1-773-185-1928 httpJMm.airgas.com



### Part Number. Cylinder Number: Laboratory: Analysis Date: E02N199E18Al208

CC208821 

### ASG - Chicago - IL Jul 02, 2007 Reference Number: 54-124099734-6 Cylinder Volume: 144 Cu.Ft Cylinder Pressure: 2015 PSIG Valve Outlet: 660 Expiration Date: Jul 02, 2009

CerUftcaUon perforrtteti In acoordance wlth "EPA Traceability Protocol (SepL 1997)" using Ute assay procedures listed. AnalyUcal Methodology does not require comection for ana"cal interferences. This cytinder has a total analyticatl uncertainty as stated below wEth e confdence level of 9596. There are no signiflcant Impurities whlch affect the use of this calibratlon mbcture. AII concentrations are on a volumelvolume basis unless otherwfse noted.

[?a Nct Use Thrs Cytinder below 15U psig: .e.1 A1ega Pas.;ai



## CAI:IBRA'ROIN STA11TI?AIt'G; Type Lot ID Cylinder No . Concentration 

### ~~~ ; , T :Explratlon Date NTftM. 60611- CC206178 475.OPPM SULFUR,40IOXIDEI ; SP 01, 20'1:0

. ~ .. ~ . .,,

. . , , . . 

## Ai

~ 

## TALYTICAL
~ ~ 

## Q;CJIPMENT lnstrutnentl.MakelModel : :. Anal cal Prtncl le yti P MultipoiI"Calibration N1coletNeic t 

## s_,_.

~ 

## :. FT'IR

. 

### Availab)e Upon Request 

### Ndtes:

QA Approl,Al // ,' /

✓

Pare 1 of 54-124099734-6



# 45

### Triad Data Avalla



### Notes: I 

# Airgas Kx

Airgas Speciality Gases



# CERTIFICATE OF AN.AIJYSIS 'Z7

~ 

# S. Wentwa

~ 

# , R,

~ 

# nue Chicago, lL 60628 

# 1_77 ~7~.3~ 

# Grade of Product.

• EPA Protocol Far 1 '773'785-1928 http:/Mhwv.airgas.com



### Part Number. Cylinder Number: Laboratory: Analysis Date: E02N199E15A0262

SG900671 ALB ASG - Chicago - IL ,lul 02, 2007 Reference Number: 54-124U99734-3 Cyiinder Volurne: 144 Cu.Ft. Cytinder Pressure: 2015 PSIG Vaive Outlet: 660 Expiration Date: Jut 02, 2009
CertNication performed In accordance wlth "EPA Tracesblitty Protocol (SepL 1997)" using the assay pnxedures Ilsted. Anaiytical Methodology does not require correcticn for analytfcsl fnterferences. TRis cylinder has o tota( analy8cal uncertalnty as stated below with a confidence level of 95%. There are no signiticant lmpuriHes whf:h afiect the use of this caEibration mixtxsre. AI! cnncentratfon.s are an a volumahYlume basis ;,rttas otherwi.w noted.

Oo•NciUSt,Th:s L}-sindat bAfow'.3t; pstg.i.e. •i Mage Fasmi

Page 1 of 64-124099734-3



# 46

## APPENDIX 5 SAMPLE CA.LCULATIONS



# A7 •

## SAIVIPLE EQUATIONS FOR ISOKiNETIC SAMPLING
CALCULATIONS FOR FLUE GAS VOLUME AND ISOKINETIC RATIO

Flue Gas Pitot Orifice Dry Gas Static Dry Gas aP dH Temp.°F Pressure Time Meter Ft 3 In. H20 In. H20 In Out In. H20

T V m dp AH TMI TMO P g

1. D„ = Nozzle Diameter (inches)
1 a. A n = Area of Nozzle (fl )
2. Pba, = Barometric Pressure (in. Hg)
3. TT = Net Sampling Time (minutes)
4. V. = V m Final - V n , Initial= Sample Gas Volume (Ft 3 )
5. T m = Average Dry Gas Temperature at Meter (°F)

~ 

# , _ Avg. T ~I~II 

## + Avg. T

~ 

## 10

m 2



## 6. dp = Velocity head of stack gas (in. H20)

7. AH = Average Orifice Pressure Drop (in.H2O)
8. Volume of dry gas sampled at standard conditions a (DSCF)


# (17.64)(V m )(Y) Pbar OH

+ 

## 13.6 

## V m(std) _ (7' m 

# + 460)

9. V j ,, = Total Water Collected = gm H20 Silica gel + ml Imp. HZO = ml
10. Volume of water vapor at standard conditions b (SCF)

Vw(std) 

### = 0.0471(V,,) = SCF 

## Stack Temp.°F

ts



# m

## 11. Percent moisture in flue gas



## %ttiI= 100(V H

, (std) ) 

## V m(srd) + v

w(std)


## 12. Mole fraction of water vapor in flue gas



# _ %M

Bws 

## 100


## 13. Molecular Weight of dry flue gas

M d = 0.44(%CO 2 ) + 0.32(%0 2 ) + 0.28(% N Z 

## + %CO)

13a. %EA = % Excess Air = [(%0 2 ) — 0.5(%CO)l x100 

## 1 0

. 264 (%N2)] —[(% 0 2

)— 0.5(% CO)j

14. Molecular weight of wet flue gas

M J = M d (1— Bws) + 18 (B,,S)
15. A= Cross-sectional area of stack (Ft 2 )

Ar 2 

## 144


## 16. P S = Flue gas pressure (in, Hg)

P S = Pbar + P

g

— P g (in. H 2 O) NOTE: P

g (Hg) — 

## 13.6

17. T S = Absolute stack temperature (°R)

T S 

## = 460 + t s

~ 

## : •
~

## 18. Flue velocity at stack conditions (FT/SEC)

VS 

# = (K )(C ) avg T
~ a 

# 'g) p p [(

, ap



# ~ } J * 

# r s M s

C p = pitot tube coefficient K P = pitot tube constant = 85.49ft/sec
19. Flue gas volumetric flow rate at standard conditions b (SCFM)

Q, _ (V,) (A) T (avg.



# ~ )129.921 (60)



## 20. Flue gas volumetric flow rate at standard conditions ° (DSCFM)



## Q,eBwj(V.)GA) (T,(avg.)) 1 29.92J 

# ~ 60 ~

21. Flue gas volumetric. flow rate at stack conditions (ACFIV)
Q. = (VS)(A)(60)
22. Percent Isokinetic

%1= Kd(Ts)(Vm(srd)) 

## B 3 V S A n O(1— 

## B ws )

K4 = 0.09450 

## O = time(min)

NOTES: a Dry standard cubic feet at 68°F, 29.92 in. Hg

b 

## Standard conditions at 68°F, 29.92 in. Hg

c 

## 'Dry standard cubic feet per mi.nute at 68°F, 29.92 in. Hg

i i

,

## II. Calculations for emission rates (Hydrogen Halide or Halogen)

23. Mass (mg), MH.

MH.(μg)=KVs(SX--BX-) MH. = Mass of hydrogen halide in sample, μg/ml KHCI = 1.028, (μg HCUμg-mole)/(μg Cl-lμg-mole) Kl-g = 1.053, (μg HFlμg-mole)I(μg F-lμg-mole) Vs = Volume of d.iluted sample, ml S, t _ = Analysis of Sample, mass μg B X - = Analysis of Blank, mass

~ 

## ig
24. Mass (mg), M,,2
Mx2 (gg) = Vs (S X - - Bx-) 

## M,a = Mass of halogen in sample, μglml Vs = Volume of diluted sample, ml S X - = Analysis of Sample, mass μg B X - = Analysis of Blank, mass μg
25. Concentration (grIDSCF)

gr I DSCF =(A1Hac, Mx2)0.01543

( 

## V m(std)


## 26. Emission rate (lbslhr), concentration method

Ibs I hr = 0.00857* gr I DSCF* Qsd


## 27. Emission Rate (lbslmmBtu), F-Factor Method

Using 02 = (0.0 1 543)(mg)(F — 

## Factor)(20.9)

( 7000 )(Vm(std) )(20.9 — %02 )



# 51

## CALCULATIONS FOR GAS CONCENTR.ATION

GAS CONCENTRATION (C g as)

Cgas _ ( 

## Z7 — COl J



## C g as 

## = Effluent gas concentration, ppm

C = Average gas concentration indicated by gas analyzer, dry basis, ppm

Co = Average of initial and final system calibration bias check responses for the zero gas, ppm
C m = Average of initial and final system calibration bias check responses for the upscale calibration gas, ppm

C ma 

## — Actual concentration of the upscale calibration gas, ppm

CALCULATION FOR EMISSION RATE 1. Concentration (lb/dscf) C

C (lb/dscf) = conversion factor * C g

. Conversion Factors: Carbon Monoxide CO Nitrogen Oxides NOx Propane C3H8 Methane CH4 Sulfur Dioxide S02

2. Emission Rate (lb/hr) E

E (lb/hr) = C * Qs * 60

3. Emission Rate process (lb/ton) E p

. r ,. s


## E (lb/ton) = 1 b / hr



## ton / hr 7.274* 10^-8 1.194* 10^-7 1.145* 10^-7 4.152* 10^-8 1.660* 10^-7

'Z") 

# 2

## CA.LCLILATION QIIAI,ITY ASSURANC CIi 

# E CK 

# Vm s u

_ ~ 

# 7.(c

~~~ 

# .00 y(e. ~



# ~c Z9.,Z 

# ~~ ~_„4~ 3 ~

a/ + v ~a~
_ 

# v uJ = o. cu'1 i(qG • 

# ~
°~~ n~ 

# - ioa ~z. ~~~3~ /~ 

# Z. r7 ~~ ~ 

# yyvs> = ~J•~~



## roa

Z•3 

# ~ t a.3Z.(17- Z)

, + c7. ZfS(Iac



# ~ —/7•L - z• 

# ~ = Z4.o 

# ~ q6~ 

## ): zE3.S3



# 1 s - y6o t 2.q

- 7 = 7s ~



# QS 

# ~ cQ = (3-Z.



# ~ -1 S

- -7-25-65 ) l 

# ~ = 

# /2,o8z

g 

# . i



# a9. S



# J



# Ibf

~ = CO 

# ~ ZZ..



# ~

~ p

# 53

## 41 CALCULATION QUALITY ASSURANCE CHECK



## 17.3

Z- p.iNS) 

### ~/~~ 3 E 3 /~/~

Z' `' 

## ~l ~ (oloa x 

## Ja C ~°~J~~Z ~E3Z~ 

## = 7. 5

- 1



# %5,.4..

## APPENDI'X 6 

## FIGURES



# 5

- 5 • '

# 5A"1'ALYS'1' Allt MANAGIEMEN"1', INC.

G~

~ 

# ~ ~
c W l

o m ~

E ~

~ ~ ~ U '

~ ; : ; Vacuum Gauge

, , ; Vacuum Pump O p v ❑ 1 ; Sample Valve

, 0 0
, ~ 

### ; o
, ,

; Heated Probe Three Way Valve Sampie Gas Moisture Condenser Para Staltic Moisture removal Pump

--------------------------------------------------------------; Sampie Manifold ; CO 2 Anafyzer

~

0 2 Anaiyzer ' S0 2 Analyzer NO = Anafyzer CO Analyzer j ® ® 

### ® ® 0 

## ~D~ 

# OODU 00000flo Way Valve

~ ~ ~ ~ ~

~ Protocoi Calibration Gases ;

~ - ~

~ O O

~ ~ Located in Mobie CEMS Vehide ~;•
~ ~ ~ - ~ ~

~ s ~ ~

~ ----------------------------------------- --------------------- Calibralion Manifold Data Aquisition Terminat Strip — PC Data Collection

--------------------------- ----------------------

TI7LE 

### EPA INSTRUMENTAL SAMPLE TRAIN
DESCRIPTION 

### SAMPLE TRAIN SCHEMATIC
SCALE DRAWN BY

NONE RF C088 REVISED DATE 

### o1-z6-ss

# e A

ATALYST
IK MANACCMEN"(', INC.



# e TEMPERATURE SENSOR

VACUUM PUMP


### VACUUM SAMPLE L1NE
~ GLASS FILTER HOLDER



### * IMPINGER TRAIN (Optional, may be replace with an equivalent condenser)



### 5 4 3 2 1 1

ft i



## ~ 1 i l 

## i l li li ~ ~ I I I

lgj N0.2 IMPINGER IS MODIFIED TIP

ICE WATER BATH HEATED AREA NOZZLE
TEMPERATURE SENSOR

HEAT TRACED PROBE

TYPE "S" PITOT TUBES



# ~

•

O G/ ~ hN11 ~ O



### GAS SAMPLING METER 

## BOX NOTE: METER BOX CONTAINS: 1. VACUUM GAUGE 2. MAIN VALVE 3. PUMP BY-PASS VALVE 4. DRY GAS METER 5. ORIFICE & FLOW MANOMETERS 6. GAS INLET & OUTLET TEMPERATURE SENSORS AND INDICATORS 

## * IMPINGER CONTENTS 1&2 100 mi 0.1 N H 2 SO 4 3&4 100 m10.1 N NaOH 5 250 g Sitica Gel

TITLE 

### EPA METHOD 26A SAMPLING TRAIN
DESCRIPTION HCL/HF SAMPLE TRAIN CONFIGURATION

SCALE DRAWN BY

NON E MJ TAYLOR RE1/ISED DATE 04-26-99