ATALYST 

AIR MANAGEMENT, INC. 

AIR QUALITY TESTING SERVICES 

FLORIM USA 

CERAMIC KILN 

EMISSIONS TEST REPORT 

Catalyst A.ir Management, Inc. 

Report Number 243-001 

APRIL 3, 2008 

Test Dates: October 25, 2007 

2505 Byington-Solway Road 29541 Morningmist Drive 10 Mill Road 

Knoxville, TN 37931 Wesley Chapel, FL 33543 Mnroantn~:rn p n ~ ocn ~ 

____ 
ATALYST 

A[It IWANAGEMENT, INC. 

FLORIM USA 

CERAIVIIC KILN 

EIVIISSIONS TEST REPORT 

CATALYST AIR MANAGEMENT, INC. 

REPORT NUMBER 243-001 

APRIL 3, 2008 

Test Date: October 25, 2007 

Prepared for 

Ms Connie James 

Florim USA 

300 Intemational Boulevard 

Clarksville, TN 37040 
ATALYST 

AiR NLwAGEmENT; Irrc. 

CERTIFICATION OF INFORMATION 

Florim USA — Clarksville, TN 

Catalyst Report 243-001 

Apri13, 2008 

To the extent practical, information and data provided in this test report has been verified as true 

and correct. 

Michael J. Taylor 

President 
TABLE OF CONTENTS 

LETTER OF TRANSMITTAL 

TITLE PAGE 

CERTIFICATION OF INFORMATION i 

TABLE OF CONTENTS 

PROJECT FACT SHEET 

1 Introduction 1 

2 Summary of Test Results 1 

3 Results of Testing 1-3 

4 Sampling Program Procedures 4-5 

5 Operating Conditions 5 

6 Quality Assurance 5-6 

7 Discussion 16 

APPENDICES 

1 Test Results 7 

S02 7-12 

HCl/IiF 13-24 

2 Plant Data 25-26 

3 Lab Analysis — HCUHF 27-34 

4 Reference Method Quality Assurance 35 

Isokinetic Sampling Equipment 35-41 

Calibration Gas Specif'ication Sheets 42-46 

5 Sample Calculations 47-54 

6 Figures 55-58 

ii 
PROJECT FACT SHEET 

NAME OF SOURCE OWNER: 

SOURCE IDENTIFICATION: 

LOCATION OF SOURCE: 

TYPE OF OPERATION: 

TYPES OF TESTS PERFORMBD: 

TEST COMPANY: 

SITE SUPERVISOR: 

TEST PERSONNEL: 

TEST DATES: 

OWNER' S REPRESENTATIVE: 

Florim USA 

Ceramic Kiln 

300 Intemational Boulevard 

Clarksville, TN 37040 

Ceramic Kiln 

Sample Traverse-EPA Method 1 

Volumetric Flow Rate-EPA Method 2 

Molecular Weight-EPA Method 3A 

Moisture Content-EPA Method 4 

S02-EPA Method 6C 

HCUHF-EPA Method 26A 

Catalyst Air Management, Inc. 

2505 Byington-Solway Road 

Knoxville, TN 37931 

Josh Nicely - Testing Supervisor 

Huedon Love - Technician 

Justin Watson - Technician 

October 25, 2007 

Connie James 

TEST OBSERVER: Brian Parker - TDEC 

iii 
1.0 Introduction 

Catalyst Air Management, Inc. (Catalyst) was contracted by Florim USA to perform 

emissions testing for the ceramic kiln at the facility in Clarksville, TN. 

The sampling program was conducted October 25, 2007. The testing was performed by 

Messrs. Josh Nicely, Huedon Love and Justin Watson of Catalyst, with the assistance of 

personnel assigned by Florim USA. Ms Connie James of Florim USA coordinated plant 

operation during the testing. Mr. Brian Parker of the Tennessee Department of 

Environment and Conservation (TDEC) was present to observe a portion of the testing. 

2.0 Summary of Test Results 

A summary of test results developed by this source sampling program are presented in 

Tables 1 through 3. The summary tables are presented as follows: 

Table Description Page 

1 Summary of Emissions 1 

2 Isokinetic Sampling Summary — HCUHF 2 

3 Sampling Summary — S02 3 

3.0 Results of Testi.n ~ 

The individual test run results are shown in Tables 2 and 3, and are tabulated in Appendix 1. 

TABLE 1 

Summary of Emissions 

Ceramic Kiln Baghouse 

Pollutant Avg lb/hr 

S02 

~ 

9.22' 

HCl 2.57 

HF 0.10 
TABLE 2 

ISOKINETIC SAMPLING SUMMARY 

EPA Method 51202 

Client: Florim USA 

Unit Tested: "Baghouse 

Sampling Location: Stack 

Run Number: 1 2 

Date: l O125/07 10/25/07 

Start Time: 10:45 12:20 

End Time: 11:52 13:27 

DN - Nozzle Diameter: - 0.328 0.328 

Pbar - Barometric Pressure: 29.12 29.12 

TT - Sampling Time: 60 60 

VM - Meter Volume: 46.186 48.475 

TM - Avg, Meter Temp(F): 81 84 

PM - Avg. Delta H(in. of H20): 1.779 2.088 

Y- Meter Calibration Factor: 1.00 1.00 

VMSTD - Std. Gas Volume (SCF): 44.091 46.025 

Vlc - Volume Water Collected: 46.1 43 

%M - Percent Moisture: 4.7 4.2 

Bws - Mole Fraction, Dry: 0.05 0.04 

%CO2 - Carbon Dioxide, Dry: 2.3 2.3 

%02 - Oxygen, Dry: 17.2 17.3 

MD - Dry Molecular Weight: 29.05 29.06 

MS - Wet Molecular Weight: 28.53 28.60 

A- Stack Area, SQ.FT: 9.62 9.62 

PS - Static Press. (in. of Hg): 29.10 29.10 

TS - Stack Temp. (F): 297 300 

CP - Pitot Coefficient: 0.84 0.84 

VS - Stack Gas Velocity (AFPS): 32.4 34.9 

QS - Stack Gas Volume (DSCFM): 12,082 13,049 ' 

QA - Stack Gas Volume (ACFM): 18,686 20,169 

%I - Isokinetic R.atio: 99.8 96.4 

Emissions HCl 

grIDSCF - Emission Concentration: 0.022 0.025 

LBS/HR - Emission Rate: 2.32 2.77 

Average gr/DSCF 0.023 

Average LBS/HR 2.56 

3 

10/25/07 

13:45 

14:53 

0.328 

29.12 

60 

50.188 

84 

2.096 

1.00 

47.601 

45.4 

4.3 

0.04 

2.3 

17.3 

29.05 

28.58 

9.62 

29.10 

301 

0.84 

35.1 

13,107 

20,291 

99.3 

0.023 

2.59 

Emissions HF 

grfDSCF - Emission Concentration: 0.001 0.001 0.001 

LBS/HR - Emission Rate: 0.09 0.10 0.09 

Average gr/DSCF 0.001 

Average LBS/HR 0.10 

2 
TABLE 4 

SAMPLING SUMMARY 

EPA Methods 3A, 6C, 7E - NOx/SOZ 

Client: Florim USA 

Plant: Clarksville, TN 

Unit: Bagliouse 

Location: Stack 

Run 1 Run 2 Run 3 

Datc 10/25/2007 10/25/2007 10/25/2007 

Start Time 10:45 12:20 13:45 

End 1'ime 1 l:45 13:20 14:45 

Measured S02 Concentration (ppm) 62.63 72.77 84.01 

Corrected S02 Concentration (ppm) 62.4 71.7 82.3 

Mcasured 02 Concentration (%) 17.0 17.0 16.9 

Corrected 02 (%) 17.3 17.3 17.2 

Measured CO2 Concentration (%) 2.3 2.4 2.2 

Corrected CO2 (%) 2.2 2.3 2.1 

Volumetric Flow Rate (dscfin) 12,082 13,049 13,205 

S02 Emissions (lb/hr) 7.51 9.32 10.82 

Average S02 Emissions (Ib/hr) 9.22 

3 
4.0 Samplina Program Procedures 

The following test methods were utilized during the test progrram: 

EPA Method 1 Sample and Velocity Traverse for Stationary Sources 

EPA Method 2 Determination of Stack Gas Velocity and Volumetric Flow Rate 

EPA Method 3A Gas Analysis for CO2, 02, Excess Air and Dry Molecular Weight 

(Instrumental Analyzer Method) 

EPA Method 4 Determination of Moisture Content in Stack Gas 

EPA Method 6C Determination of S02 Emissions from Stationary Sources 

(Instrumental Analyzer Method) 

EPA Method 26A Determination of Hydrogen Chloride Emissions from Stationary 

Sources 

Test runs were conducted in triplicate for all parameters, with each being a minimum of 

60 minutes in duration. 

4.1 SOz, OZ and CO2 — EPA Method 3A and 6C 

A sample was continuously extracted and introduced into a Western Research 721 ATM 

S02 analyzer, and a Servomex 1400 02/CO2 analyzer for determination of gas 

concentrations. The sample was extracted through a heated stainless steel probe, heated 

sample line and sample conditioner to dry the sample before it enters the analyzers. A 

sample flow control system was used to control the flow into the analyzers. The analyzers 

were calibrated prior to starting the testing with EPA Protocol 1, calibration gases. A 

system bias check was performed before each run by introducing the zero and upscale gas 

at the back end of the sample probe. The system bias check was repeated at the end of 

each test run to determine the analyzer zero and calibration drifft. 

A stratification test was performed to determine the number of sample points needed. 

There was less than 10% stratification and the three point long line measurement was 

used. 

The S02 analyzer span was 0-235 ppm. The calibration gases that were utilized were 

zero, 40-60% (126.86 ppm) and 80-100% (234.41 ppm) of span. The 02/COZ analyzer 

spans were 0-23% and 0-18%, respectively. The 02 calibration gases utilized were 

13.09% and 22.64%. The CO2 calibration gases were 9.902% and 17.88%. The high 

calibration gas determined the span and was the bases for the mid gas, as well as bias and 

drift calculations. 

Reference Method Analyzers: 

Manufacturer Model Pollutant _pan S

Western Research _ 721-M S02 0-2000 ppm 

Servomex 1400B CO2/02 0-200/o/0-25% 

4 
4.2 HCl and HF - EPA Method 26A 

The HCUHF emissions were determined in accordance with procedures outlined in EPA 

Method 26A. The flue gas sample was extracted isokinetically from the gas stream. The 

HCUHF emissions were collected in acidic absorbing solutions in the back half of the 

sampling train after the filter. The acidic absorbing solutions collect the gaseous 

hydrogen halides. The hydrogen halides emissions were solubilized in the acidic 

solution. The halogens pass through to the alkaline solution where they were hydrolyzed. 

Sodium thiosulfate was added to the alkaline solution to assure reaction with the 

hypohalous acid. The halide ions in the acidic solutions were measured by ion 

chromatography. The probe and filter are both maintained at approximately 250° F. The 

sampling train consists of the following equipment connected in series: 

Glass lined probe and glass nozzle 

Glass fiber filter within a heated filter holder with teflon support 

Two Greenburg-Smith impingers containing 100 ml of 0.1N H2SO4 

Two modified Greenburg-Smith impingers containing 100 ml of 0.1N NaOH 

A modified Greenburg-Smith impinger containing approximately 250 g of silica gel 

The sample volume is measured by passing it through a calibrated dry gas meter. An S-type 

pitot tube is attached to the probe to measure stack gas velocity and to maintain isokinetic 

sampling. A K-type thermocouple is also attached to the probe to measure the gas 

ternperature. 

Affter each run, the probe, nozzle and connecting glassware ahead of the f lter were 

brushed and rinsed with distilled water and discarded. The. impinger contents were 

measured for increase in volume. The contents of the first two impingers and distilled 

water rinses were retained for HCl and HF analysis. The contents of the third and fourth 

impinger and distilled water rinses were retained for Cl and F analysis. The silica gel was 

returned to the original tared container and weighed to determine moisture gain. 

5.0 Operating Conditions 

Florim USA personnel monitored operating conditions throughout the duration of the 

sampling program. The testing was performed October 25, 2007. The unit was operating 

under normal conditions during the tests. 

6.0 Quality Assurance Procedures 

The quality assurance procedures followed during the testing activities followed guidelines 

set forth by the previous mentioned methods and the EPA Quality Assurance Handbook for 

Source Sampling. The specific procedures for this test program are listed below. 
6.1 Isokinetic Equipment 

The sample nozzles were visually inspected and measured across thr.ee different diameters 

to determine the appropriate nozzle diameter. 

The S-type pitot tubes were visually inspected and measured to meet the design 

specifications of EPA Method 2 for a 0.84 pitot coefficient. 

Both legs of the pitot tube were leak checked before and after each sample run. 

The stack thermocouples were calibrated prior to the testing and a post-test check was 

perforrned after the testing project. 

The manometer was leveled and zeroed before each sample run. 

The dry gas meter is fully calibrated annually using an EPA intermediate standard. Post -test 

dry gas meter checks were completed to verify the accuracy of the meter Yi. 

Pre-test and post-test leak checks were completed and were less than 0.02 cfm at the highest 

sampling vacuum. 

6.2 Instrumental Methods 

Analyzer calibrations, system bias check and drift checks were completed before and affter 

each sample run utilizing EPA Protocol calibration gases. 

The analyzer interference responses were determined in accordance with Section 8.2.7 of 

Method 7E and Section 16 of Method 6C. 

6.3 Data and Calculations 

A manual calculation check is performed on a single run for each parameter. 

7.0 Discussion 

7.1 Chain of Custody 

All the field samples were collected, sealed and transported to the Maxxam Analytics, Inc 

laboratory in Burlington, Ontario, Canada under the supervvision of Josh Nicely and Jeff 

Ferguson. The samples were labeled to identify the following: 

Client and source 

Date 

Type of Sample 

Run number 

Sample location 

Sarnple fraction 

7.2 Sampling Conditions and Concerns 

There was a 3 minute delay during Run 3 due to a loss of electrical power. 

- 6 
APPEN'DLX 1 

TEST RESLlLTS 

so2 

~., 

~ 
CATALYST AIR MANAGEMENT Inc. 

CALIBRATION DATA 

CLIENT: Floriun USA 

PLANT: Clarksville, TN 

UNIT: Baghouse 

TEST: 3A & 6C 

LOCATION: Stack 

RUN #: 1-9 

LOAD LEVEL: Normal 

DATE: 10/25/2007 

GAS ANALYZER CYLINDER ANALYZER DIFF % Pass 

UNITS SCALE VALUE VALUE PPM SPAN Yes1No 

021, % 0.00 0.00 0.00 0.00 YES 

02, % 25 13.09 13.12 0.03 0.13 YES 

02, % 22.64 22.65 0.01 0.04 YES 

CO2, % 0.00 0.00 0.00 0.00 YES 

CO2, % 20 9.902 9.92 0.02 0.10 YES 

CO2, % 17.88 17.79 0.09 0.50 YES 

S02, ppm 0.0 0.00 0.00 0.00 YES 

S02, ppm 250 126.86 125.4 1.46 0.62 YES 

S02, ppm 234.41 235.6 1.19 0.51 YES 

EZ 
CATALYST AIR 12ANAGEMENT Inc. 

REFERENCE DATA 

CLIENT: Flocim USA RUN q: 1 

PLANT: ClnricsviUc. TN OPERATIIVG LEVEL: Normal 

UNIT: Baghousc START DATE: 10V25/2007 

TEST: 3A,6C,7E END DATE: 10125/2007 

LOCATION: Stack START: 10:45' 

END: 11:45 

DATE TIME 02 CO2 S02 

10125/2007 10:45 17.09 224 37.43 

1012512007 10:46 17.11 2.24 35.45 

10125/2007 10:47 17.13 2.31 39.52 

10126/2007 10:48 17.02 2.36 46.36 

1012512007 10:49 16.96 2.36 52.49 

10/25/2007 10:50 18.93 2.38 58.39 

10J2512007 10:51 16.93 2.29 58.2 

10125J2007 10:52 17.04 2.27 59.19 

10/25/2007 10:53 17.01 2.32 60.72 

1012512007 10:54 16.95 2.38 62.14 

1012512007 10:56 16.95 2.43 61.98 

10/25l2007 10:66 16.77 2.51 64.88 

10/25/2007 10:57 16.66 2.54 67.11 

1012512007 10:58 16.88 25 68.37 

10125l2007 10:59 16.61 2.51 71.54 

10J25l2007 11:00 16.62 2.54 73.34 

10125/2007 11:01 16.63 2.51 72.29 

10/25J2007 11:02 16.76 2.51 89.41 

10l2512007 11:03 18.81 2.49 85.57 

10125/2007 11:04 16.78 2.47 64.1 

10J25/2007 11:05 16.85 242 62.64 

10125/2007 11:06 16.91 2.32 62.79 

10/2512007 11:07 17.06 2.26 62.1 

10J25R007 11:08 17.17 2.22 61.47 

10/26/2007 11:09 17.27 2.18 61.61 

10/25/2007 11:10 17.33 2.23 69.56 

10/25/2007 11:11 17.28 2.23 56.56 

10/2512007 11:12 17.25 2.23 54 

10125/2007 11:13 17.28 2.2 52.48 

10/2512007 11:14 17.3 2.11 51.72 

10125R007 11:15 17.4 2.12 50.99 

10/25/2007 11:16 17.41 2.11 49.57 

1012512007 11:17 17.41 2.16 49.97 

10/2512007 11:18 17.36 2.23 S2.68 

10l2512007 11:19 17.27 2.23 56.35 

10/2512007 11:20 17.22 2.27 59.49 

10125l2007 11:21 17.15 2.22 61.85 

10/252007 11:22 17.18 2.22 63.46 

1012512007 11:23 17.22 2.22 64.09 

10l2572007 11:24 17.16 2.26 65.92 

10/2512007 11:25 17.13 2.36 68.19 

10R512007 11:26 17.01 2.39 70.88 

10125/2007 11:27 17.02 2.37 71.61 

10125J2007 11:28 16.98 2.37 74.32 

102512007 11:29 16.93 2.33 77.17 

1012512007 11:30 17.01 2.33 76.65 

1012512007 11:31 17.14 2.24 72.27 

10425/2007 11:32 17.19 2.28 68.7 

10/2512007 11:33 17.15 2.3S 66.63 

102512007 11:34 17.05 2.36 64.57 

10l25/2007 11:35 17.02 2.36 62.71 

10/2512007 11:36 17.03 2.3 60.87 

10l2512007 11:37 17.11 2.24 81.57 

10/25/2007 11:38 17.16 2.24 84.39 

10/25/2007 11:39 17.17 226 67.66 

10125I2007 11:40 17.14 2.36 70.34 

10l25/2007 11:41 17 2.4 72.22 

10/25/2007 11:42 16.92 2.42 73.88 

10/26/2007 11:43 16.92 2.4 76.16 

10/2512007 11:44 16.87 2.36 77.19 

10125/2007 11:45 16.94 2.36 78.21 

02 CO2 S02 

17.05 2.32 6163 

% % ppm tor Poa Test CsUbesBooc 

SYSTEM CAI.®RAT10N BIAS AND D[tIFT DATA 

GAS ANALYZER PRE-TEST 'K Pass POST-TEST 4k % Pus 

UNITS VALUE CHECK SPAN YES1N0 CHECK SPAN DRIFT YES1N0 

02, 56 0.00 0.00 0.00 YES 0.05 012 0.22 YES 

02, SL 22.65 22.31 1.50 YES 22.29 1.59 0.09 YES 

CO2, % 0.00 0.12 0.67 YES 0.17 0.95 0.28 YES 

CO2, % 17.79 17.51 1.57 YES 17.49 1.68 0,11 YES 

S02, ppm 0.00 0.00 0.00 YES 0.00 0.00 0.00 YES 

S02, ypm 125.4 126.7 0.55 YES 128.0 1.11 0.55 YES 

UNCORRECTED ANALYZ.ERVALL-ES 

DRY 

02, % (7.0 

CO2, % 2.3 

S02, ppm 62.6 

ANALYZER VALUES CORRECTED FOR DRIIt'I• 

DRY 

02, °1e 17.3 

CO2, Yo 2.2 

S02, ppm 62.4 

FNIISSION RATF.S 

Volumetric Flow (DSCFM): 12,082 S02 (Ib/lu) - 7.51 

9 
CATALYST AIR MANAGEMENT Inc 

REFERENCE DATA 

CLIENT: Florim USA RUN N: 2 

PLANT: Clarksville, TN OPERATWG LEVEL: Nonael 

UNIT: Baghouse START DATEt 10/25/2007 

TEST: 3A,6C,7E END DATE: 10l25/2007 

LOCATION: Stack START: 12:20 

END: 13:20 

DATE TIIME 02 CO2 S02 

10125l2007 12:20 19,61 6.41 53.98 

10125l2007 12:21 16.98 2.52 71.88 

10/25/2007 12:22 16.93 2.4 72.42 

10J2512007 12:23 17.02 2.38 72.25 

10/25I2007 12:24 17.03 2.36 71.97 

10/2512007 12:25 17.03 2.4 71.62 

10l2512007 12:26 16.98 2.45 71.51 

10/25l2007 12:27 16.88 2.45 71.16 

10J2512007 12:28 16.88 2.45 71.07 

10/25/2007 12:29 16.88 2.37 71 

10125/2007 12:30 16.97 2.32 70.89 

1012512007 12:31 17.03 2.31 70.75 

10/2512007 12:32 17.04 2.31 70.55 

10/25/2007 12:33 17.03 2.4 70.7 

10/2512007 12:34 16.92 2.42 70.48 

10/2512007 12:35 16.89 2.42 70.19 

1012512007 12:36 16.88 2.4 70.56 

1012S12007 12:37 16.9 2.32 70.68 

10l2512007 12:38 17 2.3 71.05 

10125/2007 12:39 17.03 2.3 71.5 

10/2512007 12:40 17.02 2.33 71.72 

10/25I2007 12:41 16.99 2.41 72.01 

1012512007 12:42 16.69 2.42 72.13 

1012512007 12:43 16.89 2.42 72.31 

10125/2007 12:44 16.87 2.36 72.63 

10125l2007 12:4S 16.92 2.3 72.84 

1012512007 12:46 17.01 2.29 72.67 

10/2512007 12:47 17.01 2.3 72.95 

1012512007 12:48 17.01 2.38 72.72 

10/25l2007 12:49 16.93 2.41 72.85 

1012512007 12:50 16.87 2.41 72.66 

10/25/2007 12:51 16.87 2.4 72.57 

102512007 12:52 16.89 2.31 72.48 

10/2512007 12:53 16.99 2.29 72.67 

10/2512007 12:54 17.02 2.29 72.98 

10125J2007 12:55 17.03 2.31 73.04 

10/25/2007 12:56 17.01 2.4 73.15 

10l2512007 12:57 16.91 2.41 73.26 

10l2512007 12:58 16.9 2.41 73.3 

10l2512007 12:59 16.9 2.37 73.49 

1025f2007 13:00 16.94 2.29 73.71 

10/25l2007 13:01 17.03 2.29 73.85 

1025/2007 13:02 17.04 2.29 74 

10125/2007 13:03 17.04 2.36 74.01 

10125/2007 13:04 16.98 2.41 74.15 

10l25P2007 13:05 16.9 2.41 74.46 

10125/2007 13:06 16.91 2.41 74.47 

1012512007 13:07 16.91 2.32 74.6 

10125/2007 13:08 16.99 2.3 74.76 

1012512007 13:09 •17.03 2.29 74.84 

10/2512007 13:10 17.04 2.31 75.38 

1012512007 13:11 17.03 2.39 75.75 

1012512007 13:12 16.93 2.41 76.01 

10/25l2007 13:13 16.91 2.41 76.73 

1012512007 13:14 16.91 2.38 75.62 

10/2512007 13:15 16.94 2.3 75.63 

10/2512007 13:16 17.04 2.3 76.99 

10/2512007 13:17 17.04 2.29 75.85 

10/25f2007 13:18 17.06 2.34 76.1 

1012512007 13:19 17 2.41 76.3 

10126/2007 13:20 16.92 2.41 76.37 

02 CO2 S02 

17.01 2.43 72.77 Aalpsr Re:dings aot consctod 

% S6 ppm [crPott•TcuCsHtresdoct 

SYSTEM CALIBRATION B1AS AND DRIFT DATA 

GAS ANALY'LF.II PRF.TEST °h Pass POST TEST % % Psss 

UNPfS VALUE CFECK SPAN YES1N0 CIDrCK SPAN DRD"P YESWO 

02, % 0.00 0.05 0.22 YES 0.07 0.31 0.09 YES 

02, % 22.65 2229 1.59 YES 2221 1.94 0.35 YES 

CO2, % 0.00 0.17 0.95 YES 0.19 1,06 0.11 YES 

CO2, % 17.79 17.49 1.68 YES 17.38 2.29 0,62 YES 

S02, ppm 0.00 0.00 0.00 YES 0.00 0.00 0.00 YES 

S02, aAm 125.4 128.0 1.11 YES 129.6 1.79 0.68 YES 

UNCORRECTED ANALY?ER VALUES 

DRY 

02, % 17.0 

CO2, % 2.4 

S02, ppm 72.8 

ANALYZER VALUES CORRECTED FOR DRIFT 

DRY 

02, % 17.3 

CO2, % 2.3 

S02, ppm 71.7 

ENIISSION RATES 

Volumcuic Flow (DSCFK: 13,049 S02 (lb/hr) = 9.32 

10- 
GTALYST AIR MANAGEMENT Inc. 

REFERENCE DATA 

CLIENT: Flarim USA RUN tt: 3 

PLM7: Clarkm`pc,'N OPERATING LEVEL: I:onaal 

UNPT: Baghcnso START DATE: lOJ2S42007 

TEST: 3A,6C,7E EA-D DATE: l0/25/2007 

LOCATION: Stacic STARTi 13:4S 

END: 14:45 

DATE TI711E 02 CO2 S02 

10/25/2007 13:45 16.94 2.31 61.37 

101251Z007 13:46 17.04 2.29 81.22 

10l2&/2007 13:47 17.07 2.3 81.33 

10/25/2007 13:48 17.06 2.32 81.51 

10125J2007 13:49 17.05 2.4 82.16 

1012512007 13:50 16.95 2.42 82.63 

1012512007 13:51 16.93 2.42 82.88 

10/25/2007 13:52 16.93 2.37 82.81 

10125/2007 13:53 16.97 2.3 82.55 

10/ZSI2007 13:54 17.06 2.29 82.92 

10125/2007 13:55 17.06 2.29 83.17 

10f2512007 13:56 17.07 2.36 83.17 

1012512007 13:57 17.01 2.41 83.17 

10J25/2007 13:58 16.94 2.41 83.74 

10/2512007 13:59 16.93 2.41 64.09 

10l25l2007 14:00 16.95 2.32 83.37 

10/25/2007 14:01 17.04 2.28 82.55 

10/2512007 14:02 17.08 2.29 83.1 

10/2542007 14:03 17.1 2.29 83.09 

1012512007 ' 14:04 17.06 2.39 83.05 

10125l2007 14:05 16.98 2.4 62.83 

1012512007 14:06 16.98 2.41 82.23 

10/2512007 14:07 16.95 2.38 81.72 

1025/2007 14:08 16.98 2.29 81.32 

10125/2007 14:09 17.07 2.3 82.64 

10/25/2007 14:10 17.08 2.28 83.13 

1012512007 14:11 17.07 2.35 83.89 

1012512007 14:12 17.03 2.41 83.63 

10/2W007 14:13 16.94 2.42 84.07 

10/25/2007 14:14 16.94 2.42 84.39 

10l25/2007 14:15 16.93 2.34 84.72 

10125/2007 14:16 17 2.3 85.24 

1012512007 14:17 17.07 2.29 85.54 

1025I2007 14:18 17.07 2.3 85.35 

10/2512007 14:19 17.06 2.39 85.34 

10/2sl2007 14:20 16.97 2.42 85.73 

10252007 14:21 16.93 2.42 86.25 

10l2512007 14:22 16.92 2.4 86.4 

10/25/2007 14:23 16.93 2.32 86.3 

10/25/2007 14:24 17.02 2.3 66.06 

1012512007 14:25 17.05 2.3 65.92 

10125/2007 14:26 17.05 2.34 85.3 

10125/2007 14:27 17.02 2.42 85.25 

10/2&l2007 14:28 16.92 2.43 84.94 

10125l2007 14:29 16.9 2.42 84.93 

10/2512007 14:30 4.79 0.69 82.08 

10/2512007 14:31 17.45 2.03 86.65 

10125/2007 14:32 17.5 2.07 B6.68 

1012512007 14:33 17.47 2.05 84.19 

10l252007 14:34 17.46 2.05 84.2 

10125/2007 14:35 17.41 2.06 82.99 

1 QJ2512007 14:36 17.4 1.99 83 

1012512007 14:37 17.51 1.97 62.83 

1012512007 14: 38 17.63 1:91 87.56 

1012512007 14:39 17.69 1.91 62.6 

1012512007 14:40 17.72 1.94 87.43 

10/2512007 14:41 17.63 1.94 85.52 

1012512007 14:42 17.62 1.96 65.47 

10/25l2007 14:43 17.38 2.14 85.63 

102512007 14:44 17.05 2.25 85.87 

101252007 14:45 17.09 2.24 85.13 

02 CO2 S02 

16.92 2.25 84.01 Anrlyar Rradtep wt co~ 

Y• Yo ppm forPost-TcstCill6aG4om. 

SYSTEM CALIBRATION BIAS AND DRIFTDATA 

GAS ANALY2EFt PRE-TEST '/e Pnss POST-TEST °h % Pass 

UNTfS VALLiE CIECK SPAN YESWO CIiECK SPAN DRg'T YESVN0 

02, °N. 0.00 0.07 031 YES 0.09 0.40 0.09 YES 

02, °Yo 22.65 2221 1.94 YES 22.23 1.77 0.18 YES 

CO2, % 0.00 0.19 1.06 YES 0.21 1.17 O.l l YES 

CO2, % 17.79 17.38 229 YES 17.35 2.46 0.17 YES 

S02, ppm 0.00 0.00 0.00 YES 0.00 0.00 0.00 YES 

_ S02, oom 125.4 129.6 1.79 YES 129.5 1 75 0.04 YES 

UNCORRECTED ANALYZ,ER VALUES 

DRY 

OZ, % 16.9 

CO2, °h 22 

S02, ppm 84.0 

ANALY2ER VALUES C'ORRECTED FOR DRIFT 

DRY 

02, % 17.2 

CO2. •k 2.1 

S02, ppm 82.3 

EIvIISSION RATES 

Volumcvic Fiow (DSCFItii): 13.205 S02 (Ib/ht) 10.82 

~ 

~. ~ 
CATALYST AIR MANAGEMENT lnc. 

Stratification Test 

~a 

i`•J 

CLIL'NT: Florim USA 

PLANT: Clarksville, TN OPERATING LEVEL: High 

TEST: Stratification START: 10:32 

LOCATION: Stack END: 10:40 

llia: 42.00 

Port A 

Point % Date Time 02 [%] CO2 [%] S02 [ppm] 

In. 

16.7 10/25/2008 10:32 17.27 2.18 61.51 

7.01 10/25/2008 10:33 17.33 2.23 59.56 

10/25/2008 10:34 17.28 2.23 56.56 

50.0 10/25/2008 10:35 17.27 2.23 56.35 

21.00 10/25/2008 10:36 17.22 2.27 59.49 

10125/2008 10:37 17.15 2.22 61.85 

83.3 10/25/2008 10:38 17.02 2.36 62.71 

34.99 10/25/2008 10:39 17.03 2.3 60.87 

10/25/2008 10:40 17.11 2.24 61.57 

Port I3 

Point % Date Time 02 [%] CO2 [%] NOx [ppm] 

In. 

16.7 10/25/2008 10:49 16.96 2.36 52.49 

7.01 10/25/2008 10:50 16.93 2.38 56.39 

10/25/2008 10:51 16.93 2.29 58.2 

50.0 10/25/2008 10:52 17.04 2.27 59.19 

21.00 10/25/2008 10:53 17.01 2.32 60.72 

10/25/2008 10:54 16.95 2.38 62.14 

83.3 10/25/2008 10:55 16.95 2.43 61.98 

34.99 10/25/2008 10:56 16.77 2.51 64.86 

10/25/2008 10:57 16.68 2.54 67.11 

Average 17.05 2.32 60.20 

Avg. 02 [%] Avg. CO2 [%] Avg. S02 

% Diff % Diff % Diff 

17.29 -1.43 2.21 4.55 59.21 1.64 

17.21 -0.96 2.24 3.40 59.23 1.61 

17.05 -0.02 2.30 0.81 61.72 -2.52 

Avg. 02 [%] Avg. CO2 [%] Avg. S02 

% Diff % Diff % Diff 

16.94 0.65 2.34 -1.05 55.69 7.48 

17.00 0.29 2.32 -0.19 60.68 -0.81 

16.80 1.47 2.49 -7.52 64.65 -7.40 

CATALYST AIR MANAGEMENT 

Method 26A Isokinetic Sample Sheet 

Client: Florim USA 

Unit Tested: Baghouse 

Sampling Location: Stack 

Run No: 1 Date: 10/25/07 Start Time: 10:45 

End Time: 11:52 

DIAMETER OF NOZZLE: 0.328 DIAMETER OF STACK: 42.0 inches 

AREA OF NOZZLE: 5.868E-04 A. AREA OF STACK: 9.6 sq. ft. 

BAROMETRIC PRESSURE: 29.12 Pb, VOLUME OF MOISTURE: 46.1 Vi, 

GAS METER Y-FACTOR: 1.00 Y PITOT COEFFIC]ENT: 0.84 Cp 

GAS VEL PM 1VIETER TEMP STACK STATIC 

POINT TIlyIE IyIBTER HEAD ORIFICE IN OUT TEMP CO2 02 PRESS SDE VEL 

215.245 

A-1 2.5 217.1 0.20 1.60 79 79 290 2.3 17.2 -0.29 12.25 30.5 

2 2.5 218.9 0.22 1.70 79 79 298 12.91 32.2 

3 2.5 220.8 0.23 1.80 79 79 301 13.23 33.0 

4 2.5 222.8 0.24 1.90 79 79 301 13.51 33.7 

5 2.5 224.8 0.24 1.90 79 79 299 13.50 33.6 

6 2.5 226.8 0.24 1.90 79 79 290 13.50 33.6 

7 2.5 228.8 0.24 1.90 79 79 300 13.51 33.7 

8 2.5 230.8 0.25 2.00 80 80 300 13.78 34.4 

9 2.5 232.7 0.22 1.70 80 80 298 12.91 32.2 

10 2.5 234.6 0.21 1.70 80 80 297 12.61 31.4 

11 2.5 236.4 0.20 1.60 80 80 297 12.30 30.7 

12 2.5 238.114 0.16 1.30 81 81 289 10.95 27.3 

238.114 

B-1 2.5 239.9 0.22 1.70 81 81 291 12.85 32.0 

2 2.5 241.8 0.23 1.80 81 81 297 13.20 32.9 

3 2.5 243.9 0.24 1.90 81 81 297 13.48 33.6 

4 2.5 246.0 0.26 2.10 81 81 299 14.05 35.0 

5 2.5 248.2 0.29 2.30 81 81 300 14.85 37.0 

6 2.5 250.4 0.29 2.30 81 81 300 14.85 37.0 

7 2.5 252.4 0.25 2.00 82 82 300 13.78 34.4 

8 2.5 254.3 0.22 1.70 82 82 299 12.92 32.2 

9 2.5 256.2 0.21 1.70 82 82 298 12.62 31.4 

10 2.5 258.1 0.20 1.60 82 82 295 12.29 30.6 

11 2.5 259.8 0.16 1.30 82 82 292 10.97 27.3 

12 2.5 261.431 0.16 1.30 82 82 288 10.94 27.3 

RESULT,E TT V1VI SQR PIT PM 

60.0 46.186 0.472 1.779 

net net avg avg 

P: = 29.10 Vm(nd) = 44.091 

Bws = 0.047 Ma = 29.05 

STACK GAS VELOCITY = 32.4 AFPS VS 

STACK GAS VELOCITY = 1,942 AFPM 

STACK GAS VOLUME = 12,082 DSCFM Qsca 

STACK GAS VOLUME = 18,686 ACFM Qa 

ISOKINETIC RATIO = 99.8 % 

TM TS CO2 02 STATIC 

81 297 2.3 17.2 -0.29 

avg avg avg avg avg 

Vw(ne) = 2.171 %M= 4.69 

N1, = 28.53 MD= 0.95 

EMISSIONS 

HCl HF C12 F2 

Weight, mg = 64.0 2.5 0.74 0.15 *< RDL 

gr/dscf = 0.022 0.001 0.000 0.000 

lbs/hr = 2.32 0.09 0.03 0.01 

1. '1 
CATALYST AIR MANAGEMENT 

iVlethod 26A Isokinetic Sample Sheet 

Client: Florim USA 

Unit Tested: Baghouse 

Sampling Location: Baghouse Stack 

Run No: 2 Date: 10/25/07 Start Time: 12:20 

End Time: 13 :27 

DIAMETER OF NOZZLE: 0.328 DIAMETER OF STACK: 42.0 inches 

AREA OF NOZZLE: 5.868E-04 A, AREA OF STACK: 9.6 sq. ft. 

BAROMETRIC PRESSURE: 29.12 I'ba, VOLUME OF MOISTURE: 43:0 Via 

GAS METER Y-FACTOR: 1.00 Y PITOT COEFFICIENT: 0.84 Cp 

GAS VEL PM METER TEMP STACK STATIC 

POINT TIME METER HEAD ORIFICE IN OUT TEMP CO2 02 PRESS SDE VEL 

265.047 

B-1 2.5 267.2 0.28 2.20 81 81 300 2.3 17.3 -0.29 14.59 36.3 

2 2.5 269.3 0.28 2.20 82 82 301 14.60 36.3 

3 2.5 271.6 0.30 2.40 82 82 301 15.11 37.6 

4 2.5 273.9 0.31 2.40 82 82 302 15.37 38.3 

5 2.5 276.1 0.31 2.40 83 83 302 15.37 38.3 

6 2.5 278.4 0.30 2.40 83 83 301 15.11 37.6 

7 2.5 280.7 0.30 2.40 84 84 301 15.11 37.6 

8 2.5 282.8 0.22 2.30 84 84 302 12.92 32.2 

9 2.5 284.9 0.25 2.00 84 84 303 13.81 34.4 

10 2.5 287.0 0.25 2.00 85 85 302 13.80 34.4 

11 2.5 288.8 0.20 1.60 85 85 295 12.29 30.6 

12 2.5 290.668 0.20 1.60 85 85 289 12.24 30.5 

290.668 

A-1 2.5 292.7 0.24 1.90 84 84 298 13.49 33.6 

2 2.5 294.6 0.26 2.10 84 84 300 14.06 35.0 

3 2.5 296.9 0.26 2.10 84 84 302 14.08 35.0 

4 2.5 298.9 0.27 2.10 84 84 302 14.34 35.7 

5 2.5 301.0 0.27 2.10 84 84 302 14.34 35.7 

6 2.5 303.1 0.27 2.10 84 84 302 14.34 35.7 

7 2.5 305.3 0.29 2.30 84 84 302 14.87 37.0 

8 2.5 307.7 0.30 2.40 85 85 304 15.14 37.7 

9 2.5 309.7 0.26 2.10 85 85 301 14.07 35.0 

10 2.5 311.6 0.22 1.70 85 85 300 12.93 32.2 

11 2.5 313.5 0.21 1.70 85 85 300 12.63 31.4 

12 2.5 315.390 0.20 1.60 85 85 292 12.26 30.5 

EtESULTI, TT VM SQR PIT PM 

60.0 48.475 0.509 2.088 

net net avg avg 

Ps = 29.10 Vm(sw) = 46.025 

Bws = 0.042 Md = 29.06 

STACK GAS VELOCITY = 34.9 AFPS Vs 

STACK GAS VELOCTTY = 2,096 AFPM 

STACK GAS VOLUME = 13,049 DSCFM Q:id 

STACK GAS VOLUME = 20,169 ACFM Q& 

ISOKINETIC RATIO = 96.4 % 

TM TS CO2 02 STATIC 

84 300 2.3 17.3 -0.29 

avg avg avg avg avg 

Vw(std) = 2.025 %M= 4.21 

M, = 28.60 MD= 0.96 

EMISSIONS 

HCl HF C12 F2 

Weight, mg = 74.0 2.8 0.80 0.57 

gr/dsef = 0.025 0.001 0.000 0.000 

lbs/hr = 2.77 0.10 0.03 0.02 

1.5 
CATALYST AIR MANAGEMENT 

Method 26A Isokinetic Sample Sheet 

Client: Florim USA 

Unit Tested: Baghouse 

Sampling Location: Baghouse Stack 

Run No: 3 Date: 10/25/07 Start Time: 13:45 

End Time: 14:53 

DIAIVMETER OF NOZZLE: 0.328 DIAMETER OF STACK: 42.0 inches 

AREA OF NOZZLE: 5.868E-04 A„ AREA OF STACK: 9.6 sq. ft. 

BAROMETRIC PRESSURE: 29.12 Pbu VOLUME OF MOISTURE: 45.4 vic 

GAS METER Y-FACTOR: 1.00 Y PITOT COEFFICIENT: 0.84 CP 

GAS VEL PM METER TEMP STACK STATIC 

POINT TEVIE METER HEAD ORIFICE IN OUT TEMP CO2 02 PRESS SDE VEL 

315.615 

A-1 2.5 317.7 0.26 2.10 83 83 302 2.3 17.3 -0.29 14.08 35.1 

2 2.5 319.8 0.27 2.10 83 83 302 14.34 35.7 

3 2.5 321.9 0.26 2.10 83 83 302 14.08 35.1 

4 2.5 324.0 0.27 2.10 83 83 302 14.34 35.7 

5 2.5 326.1 0.27 2.10 83 83 302 14.34 35.7 

6 2.5 328.3 0.28 2.20 84 84 303 14.62 36.4 

7 2.5 330.4 0.28 2.20 84 84 303 14.62 36.4 

8 2.5 332.6 0.28 2.20 84 84 303 14.62 36.4 

9 2.5 334.7 0.26 2.10 84 84 301 14.07 35.0 

10 2.5 336.7 0.23 1.80 85 85 301 13.23 32.9 

11 2.5 338.6 0.21 1.70 85 85 301 12.64 31.5 ' 

12 2.5 340.464 0.20 1.60 85 85 294 12.28 30.6 

6 340.464 

B-1 2.5 342.5 0.26 2.10 85 85 298 14.04 35.0 

2 2.5 344.5 0.29 2.30 85 85 300 14.85 37.0 

3 2.5 346.7 0.26 2.30 85 85 302 14.05 35.0 

4 2.5 349.1 0.30 2.40 85 85 303 15.13 37.7 

5 2.5 351.253 0.31 2.40 85 85 303 15.38 38.3 

6 2.5 353.5 0.31 2.40 85 85 302 15.37 38.3 

7 2.5 355.8 0.30 2.40 85 85 302 15.12 37.7 

8 2.5 358.0 0.29 2.30 86 86 301 14.86 37.0 

9 2.5 360.1 0.26 2.10 85 85 300 14.06 35.0 

10 2.5 362.1 0.25 2.00 85 85 300 13.78 34.3 

11 2.5 364.0 0.21 1.70 85 85 298 12.62 31.4 

12 2.5 365.803 0.20 1.60 85 85 292 12.26 30.5 

RESULT~ TT VM SQR PIT PM 

60.0 50.188 0.512 2.096 

net net avg avg 

Ps = 29.10 Vm(scd) ° 47.601 

Bws = 0.043 Md = 29.05 

STACK GAS VELOCITY = 35.1 AFPS Vs 

STACK GAS VELOCITY = 2,109 AFPM 

STACK GAS VOLUME = 13,107 DSCFM Qsut 

STACK GAS VOLUME = 20,291 ACFM Qn 

ISOKINETIC RATIO = 99.3 % 

TM TS CO2 02 STATIC 

84 301 2.3 17.3 -0.29 

avg avg avg avg avg 

V~~d) = 2.138 %M= 4.30 

Ms= 28.58 MD= 0.96 

EIvIISSIONS 

HCl HF C12 F2 

Weight, mg = 71.0 2.5 0.73 0.15 *< RDL 

gr/dscf = 0.023 0.001 0.000 0.000 

lbs/hr = 2.59 0.09 0.03 0.01 

f. ~ 
CATALYST AIR MANAGEMENT Inc. 

CALIBRATION DATA 

CLIENT: Florim RUN #: 1-3 

PLANT: Clarksville Tn. LOAD LEVEL: High 

UNTT: Baghouse DATE: 10/25l2007 

TEST: 3A 

LOCATION: Stack 

GAS ANALYZER CYLINDER ANALYZER DIFF % Pass 

UNITS SCALE VALiJE VALUE PPM SPAN Yes1No 

02, % 0.00 0.00 0.00 0.00 YES 

02, % 25 13.09 13.12 0.03 0.13 YES 

02, % 22.64 22.65 0.01 0.04 YES 

CO2, % 0.00 0.00 0.00 0.00 YES 

CO2, % 20 9.902 9.92 0.02 0.10 YES 

CO2, % 17.88 17.88 0.00 0.00 YES 

RUN I 

SYSTEM CALIBRATION BIAS AND DRIFT DATA 

GAS ANALYZER PRE-TEST % Pass POST-TEST % % Pass 

UNITS VALUE CHECK SPAN YES1N0 CHECK SPAN DRIFT YESWO 

02, % 0.00 0.00 0.00 YES 0.05 0.22 0.22 YES 

02, % 22.65 22.31 1.50 YES 22.29 1.59 0.09 YES 

CO2, % 0.00 0.12 0.67 YES 0.17 0.95 0.28 YES 

CO2, % 17.88 17.51 2.07 YES 17.49 2.18 0.11 YES 

UNCORRECTED ANALYZER VALUES ANALYZER VALUES CORRECTED FOR DRIFT 

DRY DRY 

02, % 17.00 02, % 17.2 

CO2, % 2.35 CO2, % 2.3 

RUN 2 

SYSTEM CALIBRATION BIAS AI`TD DRIFT DATA 

GAS ANALYZER PRE-TEST % Pass POST-TEST % % Pass 

UNITS VALUE CHECK SPAN YESWO CI-iECK SPAN DRIFT YESWO 

02, % 0.00 0.05 0.22 YES 0.07 0.31 0.09 YES 

02, % 22.65 22.29 1.59 YES 22.21 1.94 0.35 YES 

CO2, % 0.00 0.17 0.95 YES 0.19 1.06 0.11 YES 

CO2, % 17.88 17.49 2.18 YES 17.38 2.80 0.62 YES 

UNCORRECTED ANALYZER VALUES ANALYZER VALUES CORRECTED FOR DRIFT 

DRY DRY 

02, % 17.01 02, % 17.3 

CO2, % 2.43 CO2, % 2.3 

RUN 3 

SYSTEM CALIBRATION BIAS AND DRIFT DATA 

GAS ANALYZER PRE-TEST % Pass POST-TEST % % Pass 

UNITS VALUE CHECK SPAN YESWO CHECK SPAN DRffT YESWO 

02, % 0.00 0.07 0.31 YES 0.09 0.40 0.09 YES 

02, % 22.65 22.21 1.94 YES 22.25 1.77 0.18 YES 

CO2, % 0.00 0.19 1.06 YES 0.21 1.17 0.11 YES 

CO2, % 17.88 17.38 2.80 YES 17.35 2.96 0.I7 YES 

UNCORRECTED ANALYZER VALUES ANALYZERVALUES CORRECTED FOR DRIFT 

DRY DRY 

02, % 17.01 02, % 17.3 

CO2, % 2.36 CO2, % 2.3 

j

. . f 
Run 1 

DATE TIME 02 CO2 

1012512007 10:45 17.09 2.24 

10/2512007 10:46 17.11 2.24 

10/25/2007 10:47 17.13 2.31 

10/25/2007 10:48 17.02 2.36 

10/25/2007 10:49 16.96 2.36 

10125/2007 10:50 16.93 2.38 

10/25/2007 10:51 16.93 2.29 

1012512007 10:52 17.04 2.27 

10/25/2007 10:53 17.01 2.32 

10/25/2007 10:54 16.95 2.38 

10/25/2007 10:55 16.95 2.43 

10/25/2007 10:56 16.77 2.51 

10/25/2007 10:57 16.68 2.54 

10/25/2007 10:58 16.68 2.5 

10/25/2007 10:59 16.61 2.51 

10/25/2007 11:00 16.62 2.54 

10/25/2007 11:01 16.63 2.51 

10/25/2007 11:02 16.76 2.51 

10125/2007 11:03 16.81 2.49 

10/2512007 11:04 16.78 2.47 

10/25/2007 11:05 16.85 2.42 

10125/2007 11:06 16.91 2.32 

10125/2007 11:07 17.06 2.26 

10125/2007 11:08 17.17 2.22 

10125/2007 11:09 17.27 2.18 

10/25/2007 11:10 17.33 2.23 

10/25/2007 11:11 17.28 2.23 

10/25/2007 11:12 17.25 2.23 

1012512007 11:13 17.26 2.2 

10/25/2007 11:14 17.3 2.11 

10/25/2007 11:15 17.14 2.27 

10125/2007 11:22 17.18 2.22 

10/25/2007 11:23 17.22 2.22 

10/25/2007 11:24 17.16 2.26 

10/25/2007 11:25 17.13 2.36 

10125/2007 11:26 17.01 2.39 

10/25/2007 11:27 17.02 2.37 

10125/2007 11:28 16.98 2.37 

10125/2007 11:29 16.93 2.33 

10/2 5/2007 11: 30 17.01 2.33 

10/25/2007 11:31 17.14 2.24 

10/25/2007 11:32 17.19 2.28 

1012512007 11:33 17.15 2.35 

1012512007 11:34 17.05 2.36 

10125/2007 11:35 17.02 2.36 

10/25/2007 11:36 17.03 2.3 

10/25/2007 11: 37 17.11 2.24 

10/25/2007 11:38 17.18 2.24 

10/25/2007 11:39 17.17 2.26 

10/2512007 11:40 17.14 2.36 

10/2512007 11:41 17 2.4 

10/25/2007 11:42 16.92 2.42 

10/25/2007 11:43 16.92 2.4 

10125/2007 11:44 16.87 2.36 

10/25/2007 11:45 16.94 2.36 

10/25/2007 11:46 16.96 2.35 

10/2512007 11:47 17.02 2.37 

10/25/2007 11:48 16.89 2.51 

10/25/2007 11:49 16.76 2.51 

10/25/2007 11:50 16.76 2.51 

10125/2007 11:51 16.76 2.45 

10/25/2007 11:52 16.81 2.4 

17.00 2.35 

Run 2 

DATE TIIVIE 02 CO2 

1012512007 12:20 19.61 6.41 

1012512007 12:21 16.98 2.52 

10125/2007 12:22 16.93 2.4 

10/25/2007 12:23 17.02 2.38 

10/25/2007 12:24 17.03 2.36 

10/25/2007 12:25 17.03 2.4 

10/2512007 12:26 16.98 2.45 

10/2512007 12:27 16.88 2.45 

10125/2007 12:28 16.88 2.45 

10/25/2007 12:29 16.88 2.37 

10/25/2007 12:30 16.97 2.32 

10/2512007 12:31 17.03 2.31 

10/25/2007 12:32 17.04 2.31 

10/2512007 12:33 17.03 2.4 

1012512007 12:34 16.92 2.42 

1012512007 12:35 16.89 2.42 

10/2512007 12:36 16.88 2.4 

10/25/2007 12:37 16.9 2.32 

10/25/2007 12:38 17 2.3 

10125/2007 12:39 17.03 2.3 

1012512007 12:40 17.02 2.33 

10/2512007 12:41 16.99 2.41 

10/25/2007 12:42 16.89 2.42 

10/25/2007 12:43 16.89 2.42 

10/25/2007 12:44 16.87 2.36 

10125/2007 12:45 16.92 2.3 

1012512007 12:46 17.01 2.29 

10/25/2007 12:47 17.01 2.3 

1012512007 12:48 17.01 2.38 

10/2512007 ! 12:49 16.93 2.41 

10/25/2007 12:50 16.87 2.41 

10/2512007 12:57 16.91 2.41 

10/25/2007 12:58 16.9 2.41 

10125/2007 12:59 16.9 2.37 

10/2512007 13:00 16.94 2.29 

10/2512007 13:01 17.03 2.29 

1012512007 13:02 17.04 2.29 

10/25/2007 13:03 17.04 2.36 

10/25/2007 13:04 16.98 2.41 

10/25/2007 13:05 16.9 2.41 

10/25/2007 13:06 16.91 2.41 

10/25/2007 13:07 16.91 2.32 

10/2512007 13:08 16.99 2.3 

1012512007 13:09 17.03 2.29 

10/25/2007 13:10 17.04 2.31 

10/25/2007 13:11 17.03 2.39 

10/2512007 13:12 16.93 2.41 

10/25/2007 13:13 16.91 2.41 

10125/2007 13:14 16.91 2.38 

1012512007 13:15 16.94 2.3 

10126/2007 13:16 17.04 2.3 

10/25/2007 13:17 17.04 2.29 

10/2512007 13:18 17.06 2.34 

10125/2007 13:19 17 2.41 

10/25/2007 13:20 16.92 2.41 

10125/2007 13:21 16.92 2.41 

10125/2007 13:22 16.92 2.34 

10125/2007 13:23 16.98 2.3 

10125/2007 13:24 17.05 2.3 

10/2512007 13:25 17.05 2.3 

10/25/2007 13:26 17.05 2.39 

10125/2007 13:27 16.96 2.42 

17.01 2.43 

Run 3 

DATE TUAE 02 CO2 

1012512007 13:45 16.94 2.31 

10125/2007 13:46 17.04 2.29 

10125/2007 13:47 17.07 2.3 

10/25/2007 13:48 17.06 2.32 

10/25/2007 13:49 17.05 2.4 

10/25/2007 13:50 16.95 2.42 

10125/2007 13:51 16.93 2.42 

1012512007 13:52 16.93 2.37 

10125/2007 13:53 16.97 2.3 

10/25/2007 13:54 17.06 2.29 

10/25/2007 13:55 17.06 2.29 

10/25/2007 13:56 17.07 2.36 

10/25/2007 13:57 17.01 2.41 

10/25/2007 13:58 16.94 2.41 

10/2512007 13:59 16.93 2.41 

10125/2007 14:00 16.95 2.32 

10/2512007 14:01 17.04 2.28 

10/25/2007 14:02 17.08 2.29 

10/25/2007 14:03 17.1 2.29 

10/25/2007 14:04 17.08 2.39 

10/25/2007 14:05 16.98 2.4 

1012512007 14:06 16.96 2.41 

10125/2007 14:07 16.95 2.38 

10/2512007 14:08 16.98 2.29 

10/25/2007 14:09 17.07 2.3 

10/2512007 14:10 17.08 2.28 

10/2512007 14:11 17.07 2.35 

1012512007 14:12 17.03 2.41 

10125/2007 14:13 16.94 2.42 

10125/2007 14:14 16.94 2.42 

10/25/2007 14:15 16.93 2.34 

10/25/2007 14:20 16.97 2.42 

10/25/2007 14:21 16.93 2.42 

10/25/2007 14:22 16.92 2.4 

10/25/2007 14:23 16.93 2.32 

10125/2007 14:24 17.02 2.3 

10/25/2007 14:25 17.05 2.3 

10/25/2007 14:26 17.05 2.34 

10/25/2007 14:27 17.02 2.42 

10/25/2007 14:28 17.01 2.3 

10125/2007 14:29 17.01 2.38 

10/2512007 14:30 16.93 2.41 

10/25/2007 14:31 16.87 2.41 

1012512007 14:35 16.94 2.29 

10/25/2007 14:36 17.03 2.29 

10/25/2007 14:37 17.04 2.29 

10/25/2007 14:38 17.04 2.36 

10/25/2007 14:39 16.98 2.41 

10/25/2007 14:40 16.9 2.41 

1012512007 14:41 16.91 2.41 

10125/2007 14:42 16.91 2.32 

10/25/2007 14:43 16.99 2.3 

1012512007 14:44 17.03 2.29 

10125/2007 14:45 17.04 2.31 

10125/2007 14:46 17.03 2.39 

10/2512007 14:47 16.93 2.41 

10l2512007 14:48 16.91 2.41 

10/2512007 14:49 16.91 2.38 

10/2512007 14:50 17.25 2.41 

10/2512007 14:51 17.25 2.41 

10/25/2007 14:52 17.24 2.41 

10/2512007 14:53 17.24 2.41 

17.01 2.36 

Wol 
CATALYST AI R MANAG E M E NT, I N C_ (865) 531-0075 

Air Quality Testing Services (865) 531-0750 Fax 

2505 Byington Sofway Road 

Knoxville, TN 37931 

Client -pC-v sZzrm 

Plant A64 21A.S 1/L'Lf.0 

Location 

Test 

Run ~ 

Date 

Meter Box 01 t~ 

A H Y, 

k= 7.Ll 

Field lsokinetic Data Sheet 

Pitot No. rAllf -p 

Nozzle No. 

Noule Dn. 3Z$ 

TC No. 

Pe Z9 rf 

Ambient Temp '70° 

Static -''. Zi~ 

Filter Number ° "0 °0 ~ 

Initial Leak (Samp.) o, o dy 

Initial Leak (Pitot) Gt, c, 5'~ 

-~04-7PV 

Final Leak (Samp.) _qrl 

Final Leak (Pitot) 6 1, r@ S,S 

TIME 

ACTUAL - m ., . 

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COMMENTS: 

1.9 
CATALYST A1 F;t MANAG E M E NT, 

Air Quality Testing Services 

2505 Byington-Solway Road 

Knoxville, TN 37931 

PLANT: rz4 '"'' DATE: 1y 113 d' 

SAMPLING TIME: (24 HR C LA CK) /~yS — 5 Z 

SAMPLING LOCATIO ' ~C`/ti < 

SAMPLING TYPE: ••c-uac.S 

ANALYTICAL MET OD: 3-f ZG4 AM. TEMP (°F) 7z 

TECHNICIAN: So--- 

1 N C . (865) 531-0075 

(865) 531-0750 Fax 

41 

RUN 2 3 AvenAae 

GAS ACTUAL ACTUAL ACTUAL vo~ ~ Fo (TEST}= 20'9-0~ 

NET NET NET 5~oCO2 READING READING READING 

CO2 Z .3 

0

2 uel T a ca c 

(NET t8 ACTWL ItUUE 17.2 C~~ ,UEL(M ,= 

AC7WLCCJ NATVRALGAt ,.1M 

SYSTEM LEAK CHECK, ~ _ X//4 

INITIAL ORSAT ANALYZER LEAK CHECK (FLUID LEVEL) ! BUBBLER 

FIN AL ORSAT ANALYZER LEAK CHECK (FLUID LEVEL) / BUBBLER 

MOISTU RE 

1 2 3 4 5 6 GEL TOTALS 

FINAL (mq 45 t; ~'! -a &12-4;1 717-0 &Z/. / 

tNITlAL (ml) 7ye, U 793239- S 71 S' 3 8302 .,9 

NET (ml) 1 7- f3 5"' Y~ Z- S 1 • -7 /8- 3 (C •~ 

TOTALS ~~r • ~ 

PARTICULATE CATCH 

FILTER WEIGHTS PROBE/NOZZLE WASH 

FILTER . 

. - 

: y ~ •. - 

. 

WEIGHT 

~ 

'— =a= . ~~•_ ~ 

TOTAL PARTICULATE CATCH (mg) 

',~ ~i 
Field Isokinetic Data Sheet 

Pitot No. %V -0 

Nozzle No. -iq 

Nozzle Dn. 3 Z$ 

TC No. 6q 

Pe 

Ambient Temp ~5~~ 

Static 

Filter Number C - I z I 

Initial Leak (Samp.) 6, n 43 1, 0 

Initial Leak (Pitot) 

G~. . 

Final Leak (Samp.) to , 000 

Final Leak (Pitot) e)" 9. St~ 

CATALYST A1 R MANAG EM E NT, 1 N C . (865) 531-0075 

Air Quality Testing Services (865) 531-0750 Fax 

2505 Byington Solway Road 

Knoxville, TN 37931 

Client FL C) tZ.1- m 

Plant LA 9. t2.5 VZ-LC.0 

Location 0 — 

Test M - G 

Run Z 

Date !D - Z 57-0 7 

Meter Box 070 

L1H I t '4g 1 Yi 1z00 

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COMMENTS: 

~~ 
CATALYST AIR MANAGEMENT, INC_ 

Air Quality Testing Services 

2505 Byington-Solway Road 

Knoxville, TN 37931 

~ 

PLANT: DATE: 7-5-1ao 

SAMPLING TIME: (24 HR CLOCK) Zo -/.3 z? 

SAMPLING LOCATION: ~~✓ .~ ~~*•~-r c /r~ ~ 

SAMPLING TYPE: 

ANALYTICAL METH D: 31-;I Z&.4 AMB. T P(°F) zz_ 

TECHNICIAN: Gro:•c 

(865) 531-0075 

(865) 531-0750 Fax 

RUN 2 3 Averuae 

GAS ACTUAL N~ ACTUAL NET ACTUAL NET, va. Fo ~ (TEST) a 2~CO202 READING READING READING 

CO2 z- 3 

02 FuciTypo o 

(NET i8 ACTW1l Mt:NUB 

„~ ~ 

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INITIAL ORSAT ANALYZER LEAK CHECK (FLUID LEVEL) ! BUBBLER 

FINAL ORSAT ANALYZER LEAK CHECK (FLUID LEVEL) J BUBBLER 

MOISTURE 

1 2 3 4 5 6 GEL TOTALS 

FINAL (ml) 7&5? 75'2 • 7 .t 7~~ p A23• 7 

INITIAL (mt) 7-3 74- 3 767.2 75'2. *06 •(p 

NET (ml) J,S Z 47 f. 7 6 v ~3.0 

ToTALS 13 

PARTICULATE CATCH 

FILTER WEInNTS PRnBEIN07-ZLE WASH 

~ . m, =mmm 

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TOTAL PARTICULATE CATCH (mg) 

r; 7 

ti ;Y 
C ATA LY S T A 1 R M A N A CC E M E N T, 1 N C. (865) 531-0075 

Air Quality Testing Services (865) 531-0750 Fax 

2505 Byington Solway Road 

Knoxville, TN 37931 

Client FCAgm;-'4 

Plant 0, t A tzK.5v1Lc 

Location 

Test /Vl - VaA 

Run 3 

Date I 0 - Z57-0*7 

Meter Box Q 7 n 

A H I, q q I Y, C. oo 

/K. 7. 61 

Filter Number~f I -- j,Sq 

Initial Leak (Samp.) 

Initial Leak (Pitot) 

8k rg)s !rft 

Final Leak (Samp.) 16 , D fr /~)Al '4 

Final Leak (Pitot) C9 ~ 

oA ;, 5- 

Field Isokinetic Data Sheet 

Pitot No. IAM —07 

Nozzle No. 4 -1 q 

Nozzle Dn. 0, 3 Z~S 

TC No. eAr 

PB r !Z 

Ambient Temp ° 

Static ", *Z-'9 

POINT 

TIME 

ACTUAL RUN METER A P A h 

STACK 

°F 

PROBE 

°F 

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°F 

METER °F 

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EXIT 

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~ 5 G sr 7 f-1 1 t Z t do C- Z5-0 l. S-3 63 U3 3- Z r o 

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Z' G o ,5"► 30 3 Z.a t ~ Ca Z 9 Zr Z5b ~" ~~ (Q r- , 

COMMENTS: 

POP-7-S 

fq"3s 

w~ 
CATALYST AI R MANAG E M E NT, 

Air Quality Testing Services 

2505 Byington-Solway Road 

Knoxville, TN 37931 

PLANT: *,(-' r'" DATE: /° l ei-I o-T 

SAMPLING TIME: (24 HR CLOCK) /3 V,57— /Yf3 

SAMPLING LOCATION: 

SAMPLING TYPE: o.:• ~• ~c•u oc.s 

ANALYTICAL MET~H~OD: AMB~. ~'E P(°F) 7 

TECHNICIAN: LcJ~~ow 

1 N C _ (865) 531-0075 

(865) 531-0750 Fax 

IZ 3 

RUN 2 3 ~veruae 

GAS ACTUAL ACTUAL ACTUAL vo vue Fo (TEST)= 20' 9~~~ NET NET NET %CO2 READING READING READING 

CO2 

Z. 3 

02 Fuel Tvaa 

`~ 

o ~ 

~~ M„~ .~ i 7 .3 PXAWDUAL FUELOL un 

ACTWL CCrl ItMTURAL OAi 1314 

SYSTEM LEAK CHECK 

INITIAL ORSAT ANALYZER LEAK CHECK (FLUID LEVEL) / BUBBLER 

FINAL ORSAT ANALYZER LEAK CHECK (FLUID LEVEL) I BUBBLER 

MOISTURE 

1 2 3 4 5 6 GEL TOTALS 

FINAL (ml) j ~• 3 7.3 ~

r 

-(p 

~1 

/ j S 0 *7Z/ - S— 

IN(TIAL (ml) 737. ;7Z3. S" 7)2. Z 7/1?• 7 

NET (ml) ~ ~. 1 ~- ~ / • ~ ~ /• 3 ~~ 

TOTALS 

PARTICULATE CATCH 

FILTER WEIGHTS PROBEINOZZLE WASH 

. • 

~ 

~ 

INITIAL 

WEIGHT 

- ~ : •,: _ ~ ' _•- 

I 

' 

' -- 

TOTAL PARTICULATE CATCH (mg) 

~'~ 
APPENDIX 2 

PLANT D:A.TA 

~~ 
Florim USA 

Baghouse Ap Data 

Run 1 Run 2 Run 3 

1045 1.0 inches H20 1220 1.0 1345 1.0 

1055 1.0 1225 1.0 1350 1.0 

1100 1.0 1230 1.0 1355 1.0 

1105 1.0 1235 1.0 1400 1.0 

1110 1.0 1240 1.0 1405 1.0 

1115 1.0 1245 1.0 1410 1.0 

1120 1.0 1250 1.0 1415 1.0 

1125 1.0 1255 1.0 1420 1.0 

1130 1.0 1300 1.0 1425 1.0 

1135 1.0 1305 1.0 1430 1.0 

1140 1.0 1310 1.0 1435 1.0 

1145 1.0 1315 1.0 1440 1.0 

1150 1.0 1320 1.0 1445 1.0 

1155 1.0 1325 1.0 1450 1.0 

~

) ti 6 
APPENDIX 3 

LAB AN.AI,YSZS -- xCvxF 

27 
M •a m Drtven by service and Sc/e K~--

"Asyllrb

~ ~rce 

,nc ws4ww.maxxamaelalytics.conl 

Your Project #: FIORIM 

Site: BAGHOUSE 

Attention: Mike Tavlor 

Catalyst Air Management 

2505 Byington-Solway Rd 

Knoxville, TN 

USA 37931 

Report Date: 2007111/20 

CERTIFICATE OF ANALYSIS 

MAX.XAM JOB #: A7C2798 

Received: 2007/11/06,12:00 

Sample Matrix: SAMPLING TRAIN 

# Samples Received: 8 

Date Date Method 

Analyses Quantitl+ Extracted AnalYzed Lalsoratory Method Reference 

Halogens In NaOH Impinger (M26A) 4 2007/11/16 2007/11/16 BRL SOP-00108 EPA Method 26A 

Hydrogen Halides iri H2SO4 Imp. (M26A) 4 2007/11/13 2007/11/13 BRL SOP-00104 EPA Method 26A 

Fnal Volume of Impinger 4 2007/11/13 2007/11/13 

Final Valume of Impinger 4 2007/11/16 2007/11/16 

~_ f✓ ~' / ~--~ 

PM Released by : 

JIM POWER, CET 

Project Manager 

Total cover pages: 1 

Page 1 of 6 

5555 North Servica Road, Burlington, Onterio, Canada 1.71- 51-17 Tel: (905) 332-8788 Toll Free: (800) 668-0639 Fax: (905) 332-9169 

N 8 
M ~

KX""' 

am Driven by ser+~fre asid Scfatler 

a I y s I c s 1 n c WWVi:II]if]C]Catriaria1yTtcS.c7QI 

Catalyst Air Management 

Maxcam Job #: A7C2798 Client Project #: FIORIM 

Report Date: 2007/11120 Project name: BAGHOUSE 

Sampler initials: 

RESULTS OF ANALYSES OF SAMPLING TRAIN 

MaxxamlD V69346 V69350 V69351 V69351 

Sampling Date 2007110125 2007110125 2007/10/25 2007/10125 

Units 26A-BLANK M26A-R1 RDL M26A-112 M26A-R2 RDL QC Batch 

H2SO4 IMP-1+2 iMP-1+2 IMP-1+2 

Lab-Du 

Hydrochloric Acid ug <1000 64000 1000 74000 74000 2000 1405231 

Hydrofluoric Acid ug <750 2500 750 2800 2900 1500 1405231 

oiume ml 390 350 1 320 N1A 1 1404324 

N1A = Not Applicable 

RDL = Reportable Detection Limit 

QC Batch = Quality Control Batch 

axxamlD V69352 V69358 V69359 V69360 

amplina Date 2007/10/25 2007/10/25 2007110125 2007110125 

Units M26A-R3 ZC Batch 6A-BLANK 

IMP-1+2 NAOH 

M26A-R1 

IMP4+4 

M26A-R2 

IMP-3+4 

RDL CIC Batch 

Hydrochloric Acid ug 71000 1405231 N1A N/A N/A 200 1405231 

Hydrofluoric Acid ug 2500 1405231 NlA N/A N1A 750 1405231 

Chlorine ug N1A 1408167 <200 740 800 200 1408 1 67 

Fluorine ug N/A 1408167 <150 <150 1 570 150 1408167 

olume mi 300 1404324 780 300 280 1 1407206 

N/A = Not Applicable 

RDL = Reportable Detection Limit 

QC Batch = Quality Control Batch 

Maxxam ID V69360 V69362 

am lin Date 2007/10/25 2007/10/25 

Units M26A-112 M26A-R3 RDL QC Batch 

iMP-3+4 IMR3+4 

Lab-Du 

Chlorine ug 780 730 200 1408167 

Fluorine ug 570 <150 150 1408167 

Volume ml N!A 250 1 1407206 

N/A = Not Applicable 

RDL = Reportable DetectPon Limit 

QC Batch = Quality Control Batch 

Page 2 of 6 

5555 Notth Service Road, Burtington, Cntavio, Canada 1.71- 51-17 Tel: (905) 332-8788 Toll Free: (800) 668-0639 Fax: (905) 332-9169 

0.1 
M a • Drtven by:eratca arrd Sc%nce 

~ ,~,, 

~ m 

,,lytie, O„e www.inaxxacnanulyticx.com 

Catalyst Air Management 

Maxxam Job #: A7C2798 Client Project #: FIORIM 

Report Date: 2007/11/20 Project name: BAGHOUSE 

Sampler Initials: 

Test Summary 

Maxxam ID V69346 Collected 2007/10/25 

Sample ID M26A-BLANK H2SO4 Shipped 

Matrix SAMPLING TRAIN Received 2007/11/06 

Maxxam ID V69350 Collected 2007/10/25 

Sample ID M26A-R1 lMP-1+2 Shipped 

Matrix SAMPLING TRAIN Received 2007/11106 

Maxxam ID V69351 Collected 2007110/25 

Sample ID M26A-R2 IMP-1+2 Shipped 

Matrix SAMPLING TRAIN Received 2007111106 

Maxxam ID V69351 Dup Collected 2007110125 

Sample ID M26A-R2 IMP-1+2 Shlpped 

Matrix SAMPLING TRAIN Recelved 2007/11/06 

Test Descri tion Instrumentation Batch Prepared Analyzed Anal t 

l Hydrogen Halides in H2SO4 Im . M26A IC/SPEC 1405231 2007/11/13 2007/11/13 A S 

Maxxam ID V69352 Collected 2007110/25 

Sample ID M26A-R3 IMP-1+2 Shipped 

Matrix SAMPLING TRAIN Recelved 2007/11/06 

Maxxam ID V69358 Collected 2007/10/25 

Sample ID M26A-BLANK NAOH Shipped 

Matrix SAMPLING TRAIN Received 2007/11/06 

Page 3 of 6 

5555 North Service Road, Ber[irsgton, Orstario; Canada 1.71. 51-17 Tel: (905) 332-8788 Toll Free: (800) 868-0839 Feoc (905) 332-9169 

Test 

Test 

30 
• 4a m M ~ Drtven by sersvice and Scicircr 

.e.., . i y e + t : I .+ c www.mazsamanalyttcs.com 

Catalyst Air Management 

Maxxam Job #: A7C2798 Client Project #: FIORIM 

Report Date: 2007/11/20 Project name: BAGHOUSE 

Sampler Initials: 

Test Summary 

Maxxam ID V69359 Collected 2007/10/25 

Sampie ID M26A-R1 IMP-3+4 Shipped 

Matrix SAMPLING TRAIN Received 2007/11106 

Test Descrl 

Maxxam ID V69360 Collected 2007/10/25 

Sampie ID M26A-R2 IMP-3+4 Shipped 

Matrix SAMPLING TRAIN Received 2007/11106 

Maxxam ID V69360 Dup Coilected 2007/10/25 

Sample ID M26A-R2 IMP-3+4 Shipped 

Matrix SAMPLING TRAlN Received 2007111/06 

Test Descri tion Instrumentatlon Batch Prepared Analyzed Analyst 

I Halogens in NaOH Im in er M26A lC1SPEC 1408167 2007/11116 2007/11/16 A S 

Maxxam ID V69362 Co{lected 2007/10/25 

Sampie ID M26A-R3 IMP-3+4 Shipped 

Matrix SAMPLING TRAIN Received 2007/11/06 

Test EN 

Page 4 of 6 

5555 North Service Road, Buriington, Ontario, Cenada 1-71- SH7 Tel: (905) 332-8788 Toll Free: (800) 668-0639 Fax: (905) 332-9169 

~ ~ 
~ /~ • G ~ ~1 Drive~►by scrutce anel Scie ►► ce 

. 

~ sa ~ ..iysi« I.,c R*ww.maxxawanalytics.coni 

Catalyst Air Management 

Maxcam Job #: A7C2798 Client Project #: FIORIM 

Report Date: 2007/11/20 Project name: BAGHOUSE 

Sampler Initials: 

GENERAL COMMENTS 

Results relate oniv to the items tested. 

Page 5 of 6 

5555 North Service Road, Burtington, Ontario, Canada 1.71- 6H7 Tel: (905) 332-8788 Toll Free: (800) 868-0639 Fax; (905) 332-9169 

Q2 
M a • Drtvrn by spvice ai d Sciroice 

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~ Anwlytics Ine IBXZSt~sl11II~~Cs.coM 

Catalyst Air Management 

WWW.II 

Attention: Mike Taylor 

Client Project #: FIORIM 

P.O. #: 

Project name: BAGHOUSE 

Quality Assurance Report 

Maxxam Job Number: GA7C2798 

QA/QC 

Batch 

Num Init QC Type Parameter 

Date 

Analyzed 

/mm/dd Value %Recovery Units QC Limits 

1405231 A_S MATRIX SPIKE 

(V69351) Hydrochloric Acid 2007111/13 0, RDL=2000 104 ug 80 - 120 

Hydrroftuoric Acid 2007/11/13 0, RDL=1500 105 ug 80 - 120 

Spiked Blank Hydrochloric Acld 2007/11/13 0, RDL=200 98 ug 90 - 110 

Hydroftuoric Acid 2007/11/13 0, RDL=150 99 ug 90 - 110 

Method Blank Hydrochloric Acid 2007/11/13 <200 ug 

Hydroftuorlc Acid 2007/11113 <150 ug 

RPD Hydrochloric Acid 2007/11/13 0.5 % 20 

Hydrofluoric Acid 2007/11113 NC % 20 

1408167 A S MATRIX SPIKE 

(V69360) Chlorine 2007/11/16 0, RDL=200 95 ug 80 -120 

Fluorine 2007/11116 0, RDL=150 95 ug 80 -120 

SpEked Blank Chlorine 2007/11116 0, RDL=200 98 ug 90 -110 

Fluorine 2007/11/16 0, RDL=150 100 ug 90 -110 

Method Blank Chlorine 2007/11/16 <200 ug 

Fluorine 2007/11/16 <150 ug 

RPD Chlorine 2007/11116 NC % 20 

Fluorine 2007/11 /16 NC % 20 

NC = Non-calculable 

RPD = Relative Percent Difference 

SPIKE = Fortified sample 

Page 6 of 6 

5555 North Servlce Road, Biutington, Ontario, Canada 1-71- 51-17 Tel: (905) 332-8788 Toll Free: (800) 668-0639 Fax: (905) 332-9169 

~~ 
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: °CHAIN `OF CUSTODY 

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• 5555North Service Road 

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~ Toll Free:- 1~00~8-0638 

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- 788 

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~~ ~ m • ,. . Burlington, ON L7L 5H7 . -, . Tel. (90 332 8 

Anatyttes tne : Fax: (905~ .332-9169 • wi,vw.maxxamanalytics.com ANALYSIS REQUESTED 

-CompanyNams: G A G 1. /9r 0 ; 

CLIENT -:~ Project Manager•~~1 IIG~ j~~/CdR 

INFORMATION : Address: 2SOS' ~.~1/.1/gT ~`~au.~~ a' o^. 

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Phone #: gkS ~3/~~S' Fax *c~ G 

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flliiSA ❑ : a tt 

~ si~~: t::'s•:::' _:: : ~ 

•;... ..:.,f• ::,i:•:..t;.: 

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~:' iii•i i..n; ,.•. ~~' 'i"'~ ~ tiw ' _~' , is' i .- ..,,, '. ~ ' ' • si•ci::.: :.,s .,.s~ ~ ~ i s .:..• ;.i .,::, f, 1 i.. .i i :.. * .,fa.... ~ i:~

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. .i:.t..r.`.:......:..a:..:. . t' ..t.a...i...,.,...._..a..... 

SPECIlAL RE UIREMENTS REC Q ~ ~ULATIONS 

STD 10 Business DaY s ❑ ~ ii: T .J ~r..ut.~u. .r I. 

7: :::• ~ i:. 

t~ ft i ! ~ , c.;i::......, j... ~ .,,.... 

j' at•'iJi i" ~ i ~ : t:' i i.s;.i. tl:'a•,',1.~ • ' ::..:'• , .' ~ RUSH 5 Business Days ❑ N9AXXAM Quote #: 

- 

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i:; 

i.sr i•. ci ~ ..t. .. :-...=i•i ::. i.."'.°'?, = :i::.;...,,:.....i•...::•.cl:::. 

RUSH 2 Business Days ❑ MA~OCAM Project #: 

❑ 

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WHfTE - lAB / YELLOW - CUI=NT - . ,rC vvcn rvn wm,-s.c t n.r,~ a JF1M 'UIYl1l1lVJ t F1Ui.1 N ~`~A 

BURLITK3TON COC406N06 
APPENDIX 4 

REFERENCE METHOD QUAI.,ITY AS SURANCE 

Isokinetic Sampling Equipment 

C)5 
C~ 

Catalyst Air Management, Inc. 

METER BOX NUMBER: 

DATE: 

CALIBRATED BY: 

BENCI-I METER CALIBRATION FACTOK: 

070 

07r20/07 

Love 

1.0000 

Orifice Standard Dry Standard Dry Gas Meter 

Manometer Test Gas Tcst Barometric 

Setting Meter Meter Meter Inlet Outlet Avera e Pressure Time 

( o I-I ) Start: (VW) Start: (Vd) (TW) (TO (Tdo) (Td) (Pb) (Timc) 

In. HZO Enrl: ft3 End: ft3 °F °F °F °F in. of Hg min. Y; OH @ i QM Km 

0.50 376.875 5.353 874.320 5.383 72.3 72.3 72.3 72.3 30.10 12.35 0.99 1.48 0.436 0.789 

382.228 879_703 

1.00 382.228 5.310 879.703 5198 74.8 74.3 74.3 74.3 30.10 8.49 1.00 1.45 0.624 0.798 

387.538 885.001 

2.00 387.538 6.399 885.001 6.461 75.8 75.7 75.7 75.7 30.10 7.29 0.99 1.44 0.886 0.800 

393.937 891.462 

3.00 393.937 5.329 891.462 5.255 76.7 77.2 77.2 77.2 30.10 5.07 1.01 1.59 1.036 0.763 

399.266 896.717 

4.00 399.266 5.382 896.717 1 1 5.298 77.3 77.2 77.2 7 30.10 4.31 1.01 1.51 1.229 0.783 

404.648 902.015 

Average: 1.00 1.50 

FORMUI,AS 

Y; = 

(V,,)(P, XT, + 460) 

H 

(Vd )(pb 

 

+ (T,, + 460) 13.6 

_ (Pb )(29 ) 

K m-' ~ m (T,. + 460 (

)

AH) 

0.9244 

OH@ i = Z Km 

_(Vd )(Tlo + 460) 

Qm - (Time)(Tdo+ 460 
.~ 

Catalyst Air Managcment, Inc. 

POS'F-TEST METER BOX CALIBRATION 

ME'1'ER BOX NUMBER: 070 

DATE: 10/26/07 

CALIBRATED BY: Kelly PRETEST Yi: 1.00 

POST-TEST Yi: 1.03 

fiFNCH METER CALIBRATION FACTOIt: 1.000 DIFFERENCE, % 2.70 

Orifice Standard Dry Standard Dry Gas Meter 

Manometer Test Gas Test Baromctric 

Sctting Meter Meter Meter Inlet Outlet Avcra e Pressurc Time 

( A H ) Start: (vw) Start: (Vd) (Tw) ('I'.) fl'd.) ('I'd) (Pb) (Time) 

In. H20 Tsnd: R3 End: fl3 °F °F °F °F in. of I Ig min. Yi AH(rr i Q. Km 

2.10 858.985 8.618 365.888 8.324 66.0 64.3 64.3 64.3 30.10 10.00 1.03 1.68 0.832 0.741 

867.603 374.212 

2.10 867.603 8.S22 374.212 8.243 66.7 65.7 65.7 65.7 30.10 10.00 1.03 1.72 0.824 0.733 

876.125 382.455 

2.10 876.125 8.495 382.455 8.269 68.2 68.2 68.2 68.2 30.10 10.00 1.02 1.72 0.827 0.734 

884.620 390.724 

Average: 1.03 1.71 

FORMULAS 

Yi 

(V,)(Pb )(Td +460) 

_ 

(V-J( P

b + 13 6J(Tw +460) 

(pb)(29) 

Km - Qm (T,. +460)(OH) 

0.9244 

e~~@ I = K Z 

m 

(V,)(T,,. + 460) 

Qm 

_ 

 (Time)(Tdo+ 460) 
CATALYST ALR MANAGEMENT, INC 

Barometer Calibration Check 

Florim USA 

DATE: I0/2212007 

CALIBRATED BY: Kelly 

Hg in glass Barometer (in Hg) 29.75 

Field Barometer (in Hg) 29.77 

Difference 0.02 

'~ ~ 
CATALYST A1 R MANAG E M E NT, 1 N C- (865) 531-0075 

Air Quality Testing Services (865) 531-0750 Fax 

2505 Byington-Solway Road 

Knoxville, TN 37931 

"S" TYPE PITOT TUBE CALIBRATION — INSPECTION 

_ . 

 , ~~. 

~ 

.~ 

~• 

r i ~ 

O~prN trfdl~tinp Mwl peslbist+ hr 

da.nnininp ar aed tsA. 

ATTRIBUTE 

Level and Perpendicular? Ye.5 

Obstructed? ~v 

Damaged? ,c1 ~ 

al (-10° 5 al s+10°) 2 ~ 

a2 (-10° 5 (X2 5+10°) 2•O 

P, (-5° s p, s+5°) 2• o 

02 (-5° 5 02 5 +6*) 

e f • c7 

Z=AtanY (50.125") ,a1 -7 

W= A tan 9(5 0.0.03125") ,c~ t1 

Di (3/16" 5 131 5 3/87 C), 37(0 

A Q A S-? 

A/2Dj (1.05 s PA /Dj s 1.5) /•3 f 

O~pr~~ Inilrradnq Nwl pes~ tior lsr 

dowrerrrwnp Ar .ne P% 

1 

t).y»a imdfesfb+p Iwsl ►wi&n lot 

drtterfnifsinpQ 9 » 

O~ -~Z 

~ 

1 

~- 

Y _!•- 

O~prw inQiaafrsp bv~ l poNhoe bf 

dottminirt97then cstadatt L. 

QA / QC Check ~- 

Compieteness Legibility Accuracy Specifications --~Reasonabieness 

Certification: 2 

I certify that the Type "S" pitot tube / probe. ID# (~"fa M d'? meets or exceeds all specifications criteria and or appii bie design 

features and is hereby n a pitot tu libration factor of Cp of 0.84 

Certified By: lO / 1 110 Team Leader /0 l lq /06 

Personn (Signature / Date Tea ea Signature / Date 

~~ 
CATALYST AIR MANAGEMENT, INC. 

NOZZLE CALIBRATION SHEET 

Client: 

Job No: Zy3 -oo ~ 

Nozzle No.6 1csSY1 9 

1 ST 2ND 

o. 5,Zb o 3Z6 

Nozzle No. 

I ST 2ND 

Nozzle No. 

1 ST 2ND 

Nozzle No. 

1 ST 2ND 

Nozzle No. 

1 ST 2ND 

Nozzle No. 

1 ST 2ND 

Calibrated Ey: 

Date: 16 . ZS`03 

3RD AVG 

a• ,32f~ ~ 3Z.c~ 

3RD AVG 

3RD AVG 

3RD AVG 

3RD AVG 

3RD AVG 

40 
CATALYST AIR MANAGEMENT, INC 

K-TYPE THERMOCOUPLE CALIBRATION 

Post Test Calibration Check 

DATE: 10/26/2007 Florim USA 

CALIBRATED BY: Nicely 

AVG STACK TEMPERATURE: 299 

Thermocouple No; CAM 04 

Std Therometer 306 

Thermocouple 305 

Difference 1 

Difference % Absolute 0.1 

Acceptance Criteria % 1.5 

nl~ 
4 .2 
AirgaS K ~ 

AErgas Speeia(Ety Gases 

Certificate of Analysis: EPA Protocol Gas Mixture ~h~~:W ~8 "`~°e 

Cylinder Number: SG9174632BAL Reference Number: 54-124077494-11 

1-773-785-3000 

Fax 1-773-785-1928 

Cylinder Pressure: 2000.6 PSIG Expiration Date: 10l11/2009 http•Jh"w.airgas.com 

Certification Date: 1 0/1 1 12006 Laboratory: ASG - Chicago - IL 

Certified Concentrations 

Component Concentration Accuracy Analytical Principle Procedure 

CARBON DIOXIDE 17.88 % +!-1% NDIR G1 

OXYGEN 22.64 % +/-1% Paramagnetic G1 

NITROGEN Balance 

Certification performed in accordance with "EPA Traceability Protocol (Sept. 1997)" using the assay procedures listed. 

Analytical Methodology does not require correction for analytical interferences. 

Notes: ~~.. 

Do not use cylinder below 150 psiq. . Approval Signature _ ~G~~~~~-'-~_ .. .

~~ . Reference Standard Information 

Tvae Balance Gas ComAonent Cvl.Number - Concentration 

NTRM 101705 CARBON DIOXIDE SG9162893BAL 17.89 % 

NTRM 060608 NITROGEN OXYGEN CC206134 22.51 % 

Analytical Results 

1st Component CARBO;N "DIOXIDE 2nd Component OXYGEN 

1 st Analysis Date: 10/11/2006 1 st Analysis Date: 10/11 /2006 

R 17.89 S 17.89 Z 0 Conc 17.89 % R 22.51 S 22.64 Z 0 Conc 22.64 % 

S 17.88 Z 0 R 17.89 Conc 17.88 % S 22.64 Z 0 R 22.51 Conc 22.64 % 

; Z 0 R 17.89 S 17.88 Conc 17.88 % Z 0 R 22.51 S 22.64 Conc 22.64 % 

AVG: 17.88 % AVG: 22.64 % 

1 43 
Aimrgas kX 

Airgas Speciality Gases 

CERTI]FIC.A.TE ®F AN.ALYSIS 

12722 

~.IL~8 ~~u@ 

Grade of Product: EI'A Protocol 

1-773-785-3000 FAX: 1-773-785-1928 

http:/twww.airgas.com 

Part Number. E03N177E15A0614 Reference Number: 54-124099734-11 

Cyiinder Number: CC156502 Cylinder Voiume: 151 Cu.Ft. 

Laboratory: ASG - Chicago - IL Cylinder Pressure: 2015 PSIG 

Analysis Date: Jun 25, 2007 Valve Outiet: 590 

Expiration Date: Jun 25, 2010 

CertMcatlor, pertormed In accordance wlth "EPA TraceabtiEty Protocol (Sept.1997)" using the assay procedures iisted. AnalyUcal Methodology does not require correction for 

anatytical interferences. This cyllnder has a total analyticat uncertainty as stated belaw wtth a confidence ievel of 95%. There are no signiftcant trnparitles which aRect the use 

of this catibra8on rnbcture. AII concentrations are cn a volumeMolume basis unless otherwise noted. 

Do Not Use This Cvllnder below 150 psi9.i.e.1 Mega Pascal 

. 

, „ 

~ALIBRA~'IO~f STANDAR.DS • 

~ = ~ 

e Lox~l~D ~ ~~ linder No ; TYP ; : .; ,_.._ . ~Y Conceri~'ation F rEx 1 p ra`ticn D 

~ 4 ~ ~ ~ ~' ~1TRM' ' b8Q 0~~ '~~ i''SG9161 Q59BAL ; 

. i . . 

15 i86 ~2°/pdCAR ~ON DIOXIDE/ fiAay 01. 2040 

~ : NTRM " rr '$2~5$ ~ ` " :SG9~1b8~Q~4aAl: iA6:Q~9~o ~~GEN/~ 

~ • . . ... .., - 

Jar101,, 2010 

' i .

..~ k. 

' 

,i .r ~ ~ 

, .' ,' h f• ~ ' ,~ . 

' 

. - 

. 

A~1TAIX C24L EQU'~MEN T 

. 

. .. . 

,lnstrvnient/MakefModel ~:;~ _: .: : . . :.... ::.. .'.AnafyNca~ `P~incipio• ; :: :° LastMultipo~intpalthration 

HORIBA:510 ' ; NDIR Jan 1 ~t; 2007 

11 . CAI-11D :, . _ _ Paramagn~fi!:,. : . .. Jun 11,.2007 

Triad Data Availabte Upon Request 

Notes: 

~ 

QA Approval 

Page 1 of 54-124099734-11 

,ti ~~ 

~ 
Airgas k,

x 

CERTIFICATE OF ANALXSIS 

Grade of Product: EPA Protocol 

Airgas Specfality 6ases 

12722 S. Wentworth Avene 

Chicago, Il 60628 

1-773-785-3000 

Fax:1-773-185-1928 

httpJMm.airgas.com 

Part Number. 

Cylinder Number: 

Laboratory: 

Analysis Date: 

E02N199E18Al208 

CC208821 

ASG - Chicago - IL 

Jul 02, 2007 

Reference Number: 54-124099734-6 

Cylinder Volume: 144 Cu.Ft 

Cylinder Pressure: 2015 PSIG 

Valve Outlet: 660 

Expiration Date: Jul 02, 2009 

CerUftcaUon perforrtteti In acoordance wlth "EPA Traceability Protocol (SepL 1997)" using Ute assay procedures listed. AnalyUcal Methodology does not require comection for 

ana"cal interferences. This cytinder has a total analyticatl uncertainty as stated below wEth e confdence level of 9596. There are no signiflcant Impurities whlch affect the use 

of this calibratlon mbcture. AII concentrations are on a volumelvolume basis unless otherwfse noted. 

[?a Nct Use Thrs Cytinder below 15U psig: .e.1 A1ega Pas.;ai 

CAI:IBRA'ROIN STA11TI?AIt'G; 

Type Lot ID Cylinder No . Concentration ~~~ ; , T :Explratlon Date 

NTftM. 60611- CC206178 475.OPPM SULFUR,40IOXIDEI ; SP 01, 20'1:0 

. ~ .. ~ . .,, 

. . , , . . Ai~TALYTICAL~ ~Q;CJIPMENT 

lnstrutnentl.MakelModel : :. Anal cal Prtncl le yti P MultipoiI"Calibration 

N1coletNeict s_,_.~ :. FT'IR . 

Availab)e Upon Request 

Ndtes: 

QA Approl,Al // ,' / 

✓ 

Pare 1 of 54-124099734-6 

45 
Triad Data Avalla 

Notes: I 

Airgas Kx 

Airgas Speciality Gases 

CERTIFICATE OF AN.AIJYSIS 

'Z7~ S. Wentwa ~, R,~nue 

Chicago, lL 60628 1_77~7~.3~ 

Grade of Product. • EPA Protocol Far 1 '773'785-1928 

http:/Mhwv.airgas.com 

Part Number. 

Cylinder Number: 

Laboratory: 

Analysis Date: 

E02N199E15A0262 

SG900671 ALB 

ASG - Chicago - IL 

,lul 02, 2007 

Reference Number: 54-124U99734-3 

Cyiinder Volurne: 144 Cu.Ft. 

Cytinder Pressure: 2015 PSIG 

Vaive Outlet: 660 

Expiration Date: Jut 02, 2009 

CertNication performed In accordance wlth "EPA Tracesblitty Protocol (SepL 1997)" using the assay pnxedures Ilsted. Anaiytical Methodology does not require correcticn for 

analytfcsl fnterferences. TRis cylinder has o tota( analy8cal uncertalnty as stated below with a confidence level of 95%. There are no signiticant lmpuriHes whf:h afiect the use 

of this caEibration mixtxsre. AI! cnncentratfon.s are an a volumahYlume basis ;,rttas otherwi.w noted. 

Oo•NciUSt,Th:s L}-sindat bAfow'.3t; pstg.i.e. •i Mage Fasmi 

Page 1 of 64-124099734-3 

46 
APPENDIX 5 

SAMPLE CA.LCULATIONS 

A7 • 
SAIVIPLE EQUATIONS 

FOR ISOKiNETIC SAMPLING 

CALCULATIONS FOR FLUE GAS VOLUME AND ISOKINETIC RATIO 

Flue Gas 

Pitot Orifice Dry Gas Static 

Dry Gas aP dH Temp.°F Pressure 

Time Meter Ft3 In. H20 In. H20 In Out In. H20 

T Vm dp AH TMI TMO Pg 

1. D„ = Nozzle Diameter (inches) 

1 a. An= Area of Nozzle (fl ) 

2. Pba, = Barometric Pressure (in. Hg) 

3. TT = Net Sampling Time (minutes) 

4. V. = VmFinal - Vn, Initial= Sample Gas Volume (Ft3) 

5. Tm= Average Dry Gas Temperature at Meter (°F) 

~ , _ Avg. T~I~II + Avg. T~10 

m 2 

6. dp = Velocity head of stack gas (in. H20) 

7. AH = Average Orifice Pressure Drop (in.H2O) 

8. Volume of dry gas sampled at standard conditions a(DSCF) 

(17.64)(Vm)(Y) Pbar OH 

+ 13.6 

Vm(std) _ (7'm + 460) 

9. Vj,, = Total Water Collected = gm H20 Silica gel + ml Imp. HZO = ml 

10. Volume of water vapor at standard conditions b(SCF) 

Vw(std) = 0.0471(V,,) = SCF 

Stack 

Temp.°F 

ts 

m 
11. Percent moisture in flue gas 

%ttiI= 

100(VH,(std)) 

Vm(srd) + vw(std) 

12. Mole fraction of water vapor in flue gas 

_ %M 

Bws 100 

13. Molecular Weight of dry flue gas 

Md = 0.44(%CO2 ) + 0.32(%02 ) + 0.28(% NZ + %CO) 

13a. %EA = % Excess Air = 

[(%02 ) — 0.5(%CO)l 

x100 

1 0.264(%N2)] —[(% 02)— 0.5(% CO)j 

14. Molecular weight of wet flue gas 

MJ= Md(1— Bws) + 18(B,,S) 

15. A= Cross-sectional area of stack (Ft 2) 

Ar2 

144 

16. PS= Flue gas pressure (in, Hg) 

PS = Pbar + Pg 

— Pg(in. H2O) 

NOTE: Pg(Hg) — 

13.6 

17. TS= Absolute stack temperature (°R) 

TS = 460 + ts 

~: •~ 
18. Flue velocity at stack conditions (FT/SEC) 

VS = (K )(C ) avgT ~a 'g) p p [(,ap

~} J rs * Ms 

Cp= pitot tube coefficient 

KP= pitot tube constant = 85.49ft/sec 

19. Flue gas volumetric flow rate at standard conditions b(SCFM) 

Q, _ (V,) (A) T (avg.~ )129.921 

(60) 

20. Flue gas volumetric flow rate at standard conditions °(DSCFM) 

Q,eBwj(V.)GA) (T,(avg.))1 29.92J ~

60~ 

21. Flue gas volumetric. flow rate at stack conditions (ACFIV) 

Q. = (VS)(A)(60) 

22. Percent Isokinetic 

%1= Kd(Ts)(Vm(srd)) 

B3VS An O(1— Bws ) 

K4 = 0.09450 

O = time(min) 

NOTES: aDry standard cubic feet at 68°F, 29.92 in. Hg 

bStandard conditions at 68°F, 29.92 in. Hg 

c'Dry standard cubic feet per mi.nute at 68°F, 29.92 in. Hg 

i i 

, 
II. Calculations for emission rates (Hydrogen Halide or Halogen) 

23. Mass (mg), MH. 

MH.(μg)=KVs(SX--BX-) 

MH. = Mass of hydrogen halide in sample, μg/ml 

KHCI = 1.028, (μg HCUμg-mole)/(μg Cl-lμg-mole) 

Kl-g = 1.053, (μg HFlμg-mole)I(μg F-lμg-mole) 

Vs = Volume of d.iluted sample, ml 

S,t_ = Analysis of Sample, mass μg 

BX- = Analysis of Blank, mass ~ig 

24. Mass (mg), M,,2 

Mx2 (gg) = Vs (SX- - Bx-) 

M,a = Mass of halogen in sample, μglml 

Vs = Volume of diluted sample, ml 

SX- = Analysis of Sample, mass μg 

BX- = Analysis of Blank, mass μg 

25. Concentration (grIDSCF) 

gr I DSCF =(A1Hac, Mx2)0.01543

(Vm(std) 

26. Emission rate (lbslhr), concentration method 

Ibs I hr = 0.00857* gr I DSCF* Qsd 

27. Emission Rate (lbslmmBtu), F-Factor Method 

Using 02 = (0.0 1 543)(mg)(F — Factor)(20.9) 

(7000)(Vm(std) )(20.9 — %02 ) 

51 
CALCULATIONS FOR GAS CONCENTR.ATION 

GAS CONCENTRATION (Cgas) 

Cgas _ (Z7 — COl 

 J 

Cgas = Effluent gas concentration, ppm 

C = Average gas concentration indicated by gas analyzer, dry basis, ppm 

Co = Average of initial and final system calibration bias check responses for the 

zero gas, ppm 

Cm = Average of initial and final system calibration bias check responses for the 

upscale calibration gas, ppm 

Cma — Actual concentration of the upscale calibration gas, ppm 

CALCULATION FOR EMISSION RATE 

1. Concentration (lb/dscf) C 

C (lb/dscf) = conversion factor * C g. 

Conversion Factors: Carbon Monoxide CO 

Nitrogen Oxides NOx 

Propane C3H8 

Methane CH4 

Sulfur Dioxide S02 

2. Emission Rate (lb/hr) E 

E (lb/hr) = C * Qs * 60 

3. Emission Rate process (lb/ton) Ep.r,.s 

E (lb/ton) = 1 b / hr 

ton / hr 

7.274* 10^-8 

1.194* 10^-7 

1.145* 10^-7 

4.152* 10^-8 

1.660* 10^-7 

'Z") 2 
CA.LCLILATION QIIAI,ITY ASSURANC CIi Vms u _ ~7.(c ~~~ ECK .00 ~c y(e. ~ Z9.,Z~~ ~_„4~ 3 ~ 

a/ + v~a~ _ 

vuJ = o. cu'1 i(qG • ~ 

°~~ n~ - ioa ~z. ~~~3~ /~Z. r7 ~~ ~ yyvs> = ~J•~~ 

roa 

Z•3~ t a.3Z.(17- Z), + c7. ZfS(Iac~ —/7•L - z•~ = Z4.o~ 

q6~): zE3.S3 

1 s- y6o t 2.q-7 = 7s ~ 

QS~cQ = (3-Z. ~-1 S--7-25-65 ) l ~ = g /2,o8z . i 

a9. S 

J 

Ibf 

~ = CO

~ZZ..

~ 

~ p53 
41 CALCULATION QUALITY ASSURANCE CHECK 

17.3 

Z- p.iNS)~/~~3 E3/~/~ 

Z' `'~l ~ (oloa x Ja C ~°~J~~Z ~E3Z~ = 7. 5-1 

%5,.4.. 
APPENDI'X 6 

FIGURES 

5- 5 • ' 
5 
A"1'ALYS'1' 

Allt MANAGIEMEN"1', INC. 

G~ 

~ 

~ ~ 

c W l 

o m ~ 

E ~ 

~ ~ ~ U ' ~ 

; : 

; Vacuum Gauge 

, , 

; Vacuum Pump O p v ❑ 

1 

; Sample Valve 

, 

, 0 0

~ 

; o 

, 

, 

; 

Heated Probe 

Three Way Valve 

Sampie Gas Moisture Condenser 

Para Staltic Moisture removal Pump 

--------------------------------------------------------------; 

Sampie Manifold ; 

CO2 Anafyzer ~ 

02 Anaiyzer ' 

S02 Analyzer 

NO= Anafyzer 

CO Analyzer j 

® 

® 

® 

® 

0 

~D~ OODU 

00000flo 

 Way Valve ~ ~ ~ ~ ~ 

~ 

Protocoi Calibration Gases ; 

~ - 

~ 

~ ~ O O 

~ 

Located in Mobie 

CEMS Vehide ~;• 

~ ~ ~ - 

~ ~ 

~ s ~ ~ 

~ ----------------------------------------- --------------------- 

Calibralion Manifold 

Data Aquisition Terminat Strip — 

PC Data Collection 

--------------------------- ---------------------- 

TI7LE 

EPA INSTRUMENTAL SAMPLE TRAIN 

DESCRIPTION 

SAMPLE TRAIN SCHEMATIC 

SCALE DRAWN BY 

NONE RF C088 

REVISED 

DATE 

o1-z6-ss 
eAATALYST 

IK MANACCMEN"(', INC. 

e 

TEMPERATURE SENSOR 

VACUUM PUMP 

VACUUM 

SAMPLE L1NE ~ 

GLASS FILTER HOLDER 

*IMPINGER TRAIN (Optional, may be 

replace with an equivalent condenser) 

5 4 3 2 1 1 

ft 

i 

~ ~I I I 1 i l i l li li ~ 

lgj 

N0.2 IMPINGER IS MODIFIED TIP 

ICE WATER BATH HEATED AREA 

NOZZLE 

TEMPERATURE SENSOR 

HEAT TRACED PROBE 

TYPE "S" PITOT TUBES 

~ 

• 

O G/ ~hN11 ~ 

O 

GAS SAMPLING METER 

BOX 

NOTE: 

METER BOX CONTAINS: 

1. VACUUM GAUGE 

2. MAIN VALVE 

3. PUMP BY-PASS VALVE 

4. DRY GAS METER 

5. ORIFICE & FLOW MANOMETERS 

6. GAS INLET & OUTLET TEMPERATURE 

SENSORS AND INDICATORS 

*IMPINGER CONTENTS 

1&2 100 mi 0.1 N H2SO4 

3&4 100 m10.1 N NaOH 

5 250 g Sitica Gel 

TITLE 

EPA METHOD 26A SAMPLING TRAIN 

DESCRIPTION 

HCL/HF SAMPLE TRAIN CONFIGURATION 

SCALE DRAWN BY 

NON E MJ TAYLOR 

RE1/ISED 

DATE 

04-26-99