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Water: Current Water Quality Criteria

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You are here: Water Science & Technology Surface Water Standards & Guidance Water Quality Standards Water Quality Criteria National Recommended Water

Quality Criteria

National Recommended Water Quality Criteria

EPA's compilation of national recommended water quality criteria is presented as a summary table containing recommended water quality

criteria for the protection of aquatic life and human health in surface water for approximately 150 pollutants. These criteria are published

pursuant to Section 304(a) of the Clean Water Act (CWA) and provide guidance for states and tribes to use in adopting water quality

standards.

Previous versions of National Recommended Water Quality Criteria Table

Chemical-specific criteria documents from the 1980s

Water quality standards

Human Health Criteria Calculation Matrix (PDF) (23 pp, 445K)

Aquatic Life Criteria Table | Human Health Criteria Table

Organoleptic Effects (e.g., taste and odor) | Additional Notes

Appendix A—Conversion Factors for Dissolved Metals

Appendix B—Parameters for Calculating Freshwater Dissolved Metals Criteria That Are Hardness-Dependent

Appendix C—Calculation of Freshwater Ammonia Criterion

Gold & Red Books

Aquatic Life Criteria Table

Freshwater Saltwater

Pollutant CAS

Number

P/NP* CMC

1

(acute)

(μg/L)

CCC

1

(chronic)

(μg/L)

CMC

1

(acute)

(μg/L)

CCC

1

(chronic)

(μg/L)

Publication

Year

Acrolein 107028 P 3ug/L 3ug/L 2009

Aesthetic Qualities — NP NARRATIVE STATEMENT—SEE DOCUMENT 1986

Aldrin 309002 P 3.0 G 1.3 G 1980

Alkalinity — NP 20000 C 1986

alpha-Endosulfan 959988 P 0.22 G,Y 0.056 G,Y 0.034 G,Y 0.0087 G,Y 1980

Aluminum pH 6.5 –

9.0

7429905 NP 750 I 87 I,S 1988

Ammonia 7664417 NP FRESHWATER CRITERIA ARE pH, Temperature and Life-stage DEPENDENT

SALTWATER CRITERIA ARE pH AND TEMPERATURE DEPENDENT

1999

Arsenic 7440382 P 340 A,D 150 A,D 69 A,D 36 A,D 1995

Bacteria — NP FOR PRIMARY RECREATION AND SHELLFISH USES—SEE DOCUMENT 1986

beta-Endosulfan 33213659 P 0.22 G,Y 0.056 G,Y 0.034 G,Y 0.0087 G,Y 1980

Boron — NP NARRATIVE STATEMENT—SEE DOCUMENT 1986

Carbaryl 63252 NP 2.1 2.1 1.6 2012

Cadmium 7440439 P 2.0 D,E 0.25 D,E 40 D 8.8 D 2001

Chlordane 57749 P 2.4 G 0.0043 G 0.09 G 0.004 G 1980

Chloride 16887006 NP 860000 230000 1986

Chlorine 7782505 NP 19 11 13 7.5 1986

Chloropyrifos 2921882 NP 0.083 0.041 0.011 0.0056 1986

Chromium (III) 16065831 P 570 D,E 74 D,E 1995

Chromium (VI) 18540299 P 16 D 11 D 1,100 D 50 D 1995

Color — NP NARRATIVE STATEMENT—SEE DOCUMENT 1986
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Copper 7440508 P Freshwater criteria calculated using the BLM mm - See Document 4.8 D,cc 3.1 D,cc 2007

Cyanide 57125 P 22 Q 5.2 Q 1 Q 1 Q 1985

Demeton 8065483 NP 0.1 C 0.1 C 1985

Diazinon 333415 NP 0.17ug/L 0.17ug/L 0.82ug/L 0.82ug/L 2005

Dieldrin 60571 P 0.24 0.056 O 0.71 G 0.0019 G 1995

Endrin 72208 P 0.086 0.036 O 0.037 G 0.0023 G 1995

gamma-BHC

(Lindane)

58899 P 0.95 0.16 G 1995

Gases, Total

Dissolved

— NP NARRATIVE STATEMENT—SEE DOCUMENT C 1986

Guthion 86500 NP 0.01 C 0.01 C 1986

Hardness — NP NARRATIVE STATEMENT—SEE DOCUMENT 1986

Heptachlor 76448 P 0.52 G 0.0038 G 0.053 G 0.0036 G 1980

Heptachlor Epoxide 1024573 P 0.52 G,V 0.0038 G,V 0.053 G,V 0.0036 G,V 1981

Iron 7439896 NP 1000 C 1986

Lead 7439921 P 65 D,E 2.5 D,E 210 D 8.1 D 1980

Malathion 121755 NP 0.1 C 0.1 C 1986

Mercury

Methylmercury

7439976

22967926

P 1.4 D,hh 0.77 D,hh 1.8 D,ee,hh 0.94 D,ee,hh 1995

Methoxychlor 72435 NP 0.03 C 0.03 C 1986

Mirex 2385855 NP 0.001 C 0.001 C 1986

Nickel 7440020 P 470 D,E 52 D,E 74 D 8.2 D 1995

Nonylphenol 84852153 NP 28ug/L 6.6ug/L 7ug/L 1.7ug/L 2005

Nutrients — NP See EPA's Ecoregional criteria for Total Phosphorus, Total Nitrogen, Chlorophyll a and Water Clarity (Secchi

depth for lakes; turbidity for streams and rivers) (& Level III Ecoregional criteria)

Oil and Grease — NP NARRATIVE STATEMENT—SEE DOCUMENT C 1986

Oxygen, Dissolved

Freshwater

Oxygen, Dissolved

Saltwater

7782447 NP WARMWATER AND COLDWATER MATRIX—SEE DOCUMENT

SALTWATER—SEE DOCUMENT

1986

Parathion 56382 NP 0.065 I 0.013 I 1995

Pentachlorophenol 87865 P 19 F 15 F 13 7.9 1995

pH — NP 6.5 – 9 C 6.5 – 8.5 C,P 1986

Phosphorus

Elemental

7723140 NP 1986

Polychlorinated

Biphenyls (PCBs)

P 0.014 N 0.03 N

Selenium 7782492 P L 5.0 290 D, dd 71 D, dd 1995

Silver 7440224 P 3.2 D,E,G 1.9 D,G 1980

Solids Suspended

and Turbidity

— NP NARRATIVE STATEMENT—SEE DOCUMENT C 1986

Sulfide-Hydrogen

Sulfide

7783064 NP 2.0 C 2.0 C 1986

Tainting

Substances

— NP NARRATIVE STATEMENT—SEE DOCUMENT 1986
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Temperature — NP SPECIES DEPENDENT CRITERIA—SEE DOCUMENT M 1986

Toxaphene 8001352 P 0.73 0.0002 0.21 0.0002 1986

Tributyltin (TBT) — NP 0.46 0.072 0.42 0.0074 2004

Zinc 7440666 P 120 D,E 120 D,E 90 D 81 D 1995

4,4'-DDT 50293 P 1.1 G,ii 0.001 G, ii 0.13 G,ii 0.001 G, ii 1980

*P/NP – Indicates either a Priority Pollutant (P) or a Non Priority Pollutant (NP).

Footnotes

A This recommended water quality criterion was derived from data for arsenic (III), but is applied here to total arsenic, which might imply that arsenic (III) and arsenic (V)

are equally toxic to aquatic life and that their toxicities are additive. No data are known to be available concerning whether the toxicities of the forms of arsenic to aquatic

organisms are additive. Please consult the criteria document for details.

C The derivation of this value is presented in the Red Book (EPA 440/9-76-023, July, 1976). The CCC of 20mg/L is a minimum value except where alkalinity is naturally

lower, in which case the criterion cannot be lower than 25% of the natural level.

D Freshwater and saltwater criteria for metals are expressed in terms of the dissolved metal in the water column. See "Office of Water Policy and Technical Guidance on

Interpretation and Implementation of Aquatic Life Metals Criteria (PDF)," (49 pp, 3MB) October 1, 1993, by Martha G. Prothro, Acting Assistant Administrator for Water,

available on NSCEP's web site and 40CFR§131.36(b)(1). Conversion Factors applied in the table can be found in Appendix A to the Preamble- Conversion Factors for

Dissolved Metals.

E The freshwater criterion for this metal is expressed as a function of hardness (mg/L) in the water column. The value given here corresponds to a hardness of 100 mg/L.

Criteria values for other hardness may be calculated per the equation presented in the criteria document.

FFreshwater aquatic life values for pentachlorophenol are expressed as a function of pH. Values displayed in table correspond to a pH of 7.8.

GThis Criterion is based on 304(a) aquatic life criterion issued in 1980, and was issued in one of the following documents: Aldrin/Dieldrin (PDF) (153 pp, 7.3MB) (EPA

440/5-80-019), Chlordane (PDF) (68 pp, 3.1MB) (EPA 440/5-80-027), DDT (PDF) (175 pp, 8.3MB) (EPA 440/5-80-038), Endosulfan (PDF) (155 pp, 7.3MB) (EPA 440/5-80-046),

Endrin (PDF) (103 pp, 4.6MB) (EPA 440/5-80-047), Heptachlor (PDF) (114 pp, 5.4MB) (EPA 440/5-80-052), Hexachlorocyclohexane (PDF) (109 pp, 4.8MB) (EPA 440/5-80-054),

Silver (EPA 440/5-80-071). The Minimum Data Requirements and derivation procedures were different in the 1980 Guidelines than in the 1985 Guidelines (PDF) (104 pp,

3.3MB). If evaluation is to be done using an averaging period, the acute criteria values given should be divided by 2 to obtain a value that is more comparable to a CMC

derived using the 1985 Guidelines.

I This value for aluminum is expressed in terms of total recoverable metal in the water column.

J This value was derived using the GLI Guidelines (60 FR 15393-15399, March 23, 1995; 40CFR132 Appendix A); the differences between the 1985 Guidelines and the

GLI Guidelines are explained on page iv of the 1995 Updates. No decision concerning this criterion was affected by any considerations that are specific to the Great Lakes.

L The CMC = 1/[(f1/CMC1) + (f2/CMC2)] where f1 and f2 are the fractions of total selenium that are treated as selenite and selenate, respectively, and CMC1 and CMC2 are

185.9 ug/l and 12.82 ug/l, respectively.

M U.S. EPA. 1973. Water Quality Criteria 1972. EPA-R3-73-033. National Technical Information Service, Springfield, VA.; U.S. EPA. 1977. Temperature Criteria for

Freshwater Fish: Protocol and Procedures. EPA 600/3-77-061. National Technical Information Service, Springfield, VA.

N This criterion applies to total PCBs, (e.g., the sum of all congener or all isomer or homolog or Aroclor analyses.)

O The derivation of the CCC for this pollutant (Endrin) did not consider exposure through the diet, which is probably important for aquatic life occupying upper trophic levels.

P According to page 181 of the Red Book:

For open ocean waters where the depth is substantially greater than the euphotic zone, the pH should not be changed more than 0.2 units from the naturally occurring

variation or any case outside the range of 6.5 to 8.5. For shallow, highly productive coastal and estuarine areas where naturally occurring pH variations approach the lethal

limits of some species, changes in pH should be avoided but in any case should not exceed the limits established for fresh water, i.e., 6.5-9.0.

Q This recommended water quality criterion is expressed as ug free cyanide (as CN)/L.

S There are three major reasons why the use of Water-Effect Ratios might be appropriate.

1. The value of 87 μg/l is based on a toxicity test with the striped bass in water with pH = 6.5–6.6 and hardness <10 mg/L. Data in "Aluminum Water-Effect Ratio for

the 3M Plant Effluent Discharge, Middleway, West Virginia" (May 1994) indicate that aluminum is substantially less toxic at higher pH and hardness, but the effects

of pH and hardness are not well quantified at this time.

2. In tests with the brook trout at low pH and hardness, effects increased with increasing concentrations of total aluminum even though the concentration of

dissolved aluminum was constant, indicating that total recoverable is a more appropriate measurement than dissolved, at least when particulate aluminum is

primarily aluminum hydroxide particles. In surface waters, however, the total recoverable procedure might measure aluminum associated with clay particles,

which might be less toxic than aluminum associated with aluminum hydroxide.

3. EPA is aware of field data indicating that many high quality waters in the U.S. contain more than 87 g aluminum/L, when either total recoverable or dissolved is
water.epa.gov/scitech/swguidance/standards/criteria/current/index.cfm#hhtable 4/11

measured.

V This value was derived from data for heptachlor and the criteria document provides insufficient data to estimate the relative toxicities of heptachlor and heptachlor

epoxide.

Y This value was derived from data for endosulfan and is most appropriately applied to the sum of alpha-endosulfan and beta-endosulfan.

cc When the concentration of dissolved organic carbon is elevated, copper is substantially less toxic and use of Water-Effect Ratios might be appropriate.

dd The selenium criteria document (EPA 440/5-87-006, September 1987) provides that if selenium is as toxic to saltwater fishes in the field as it is to freshwater fishes in

the field, the status of the fish community should be monitored whenever the concentration of selenium exceeds 5.0 μg/L in salt water because the saltwater CCC does

not take into account uptake via the food chain.

ee This recommended water quality criterion was derived on page 43 of the mercury criteria document (PDF) (144 pp, 6.4MB) (EPA 440/5-84-026, January 1985). The

saltwater CCC of 0.025 ug/L given on page 23 of the criteria document is based on the Final Residue Value procedure in the 1985 Guidelines. Since the publication of the

Great Lakes Aquatic Life Criteria Guidelines in 1995 (60 FR 15393-15399, March 23, 1995), the Agency no longer uses the Final Residue Value procedure for deriving

CCCs for new or revised 304(a) aquatic life criteria.

hh This recommended water quality criterion was derived from data for inorganic mercury (II), but is applied here to total mercury. If a substantial portion of the mercury in

the water column is methylmercury, this criterion will probably be under protective. In addition, even though inorganic mercury is converted to methylmercury and

methylmercury bioaccumulates to a great extent, this criterion does not account for uptake via the food chain because sufficient data were not available when the criterion

was derived.

ii This criterion applies to DDT and its metabolites (i.e., the total concentration of DDT and its metabolites should not exceed this value).

mm The available toxicity data, when evaluated using the procedures described in the “Guidelines for Deriving Numerical National Water Quality Criteria for the Protection

of Aquatic Organisms and Their Uses” indicate that freshwater aquatic life should be protected if the 24-hour average and four-day average concentrations do not

respectively exceed the acute and chronic criteria concentrations calculated by the Biotic Ligand Model.

Human Health Criteria Table

Human Health for the consumption of

Pollutant CAS

Number

P/NP* Water + Organism

(μg/L)

Organism Only

(μg/L)

Publication

Year

Acenaphthene 83329 P 670 B,U 990 B,U 2002

Acrolein 107028 P 6 ll 9 ll 2009

Acrylonitrile 107131 P 0.051 B,C 0.25 B,C 2002

Aldrin 309002 P 0.000049

B,C

0.000050 B,C 2002

Alkalinity — NP

alpha-BHC 319846 P 0.0026 B,C 0.0049 B,C 2002

alpha-Endosulfan 959988 P 62 B 89 B 2002

Aluminum pH 6.5 – 9.0 7429905 NP

Anthracene 120127 P 8,300 B 40,000 B 2002

Antimony 7440360 P 5.6 B 640 B 2002

Arsenic 7440382 P 0.018 C,M,S 0.14 C,M,S 1992

Asbestos 1332214 P 7 million fibers/L I 1991

Barium 7440393 NP 1,000 A 1986

Benzene 71432 P 2.2 B,C 51 B,C 2002

Benzidine 92875 P 0.000086 B,C 0.00020 B,C 2002

Benzo(a) Anthracene 56553 P 0.0038 B,C 0.018 B,C 2002

Benzo(a) Pyrene 50328 P 0.0038 B,C 0.018 B,C 2002

Benzo(b) Fluoranthene 205992 P 0.0038 B,C 0.018 B,C 2002

Benzo(k) Fluoranthene 207089 P 0.0038 B,C 0.018 B,C 2002

Beryllium 7440417 P Z

beta-BHC 319857 P 0.0091 B,C 0.017 B,C 2002
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beta-Endosulfan 33213659 P 62 B 89 B 2002

Bis(2-Chloroethyl) Ether 111444 P 0.030 B,C 0.53 B,C 2002

Bis(2-Chloroisopropyl)

Ether

108601 P 1,400 B 65,000 B 2002

Bis(2-Ethylhexyl) Phthalate

X 117817 P 1.2 B,C 2.2 B,C 2002

Bromoform 75252 P 4.3 B,C 140 B,C 2002

Butylbenzyl Phthalate

W

85687 P 1,500 B 1,900 B 2002

Cadmium 7440439 P Z

Carbon Tetrachloride 56235 P 0.23 B,C 1.6 B,C 2002

Chlordane 57749 P 0.00080 B,C 0.00081 B,C 2002

Chlorobenzene 108907 P 130 Z,U 1,600 U 2003

Chlorodibromomethane 124481 P 0.40 B,C 13 B,C 2002

Chloroform 67663 P 5.7 C,P 470 C,P 2002

Chlorophenoxy Herbicide

(2,4-D)

94757 NP 100 Z 1986

Chromium (III) 16065831 P Z Total

Chromium (VI) 18540299 P Z Total

Chrysene 218019 P 0.0038 B,C 0.018 B,C 2002

Copper 7440508 P 1,300 U 1992

Cyanide 57125 P 140 jj 140 jj 2003

Dibenzo(a,h)Anthracene 53703 P 0.0038 B,C 0.018 B,C 2002

Dichlorobromomethane 75274 P 0.55 B,C 17 B,C 2002

Dieldrin 60571 P 0.000052 B,C 0.000054 B,C 2002

Diethyl Phthalate

W

84662 P 17,000 B 44,000 B 2002

Dimethyl Phthalate

W

131113 P 270,000 1,100,000 2002

Di-n-Butyl Phthalate

W

84742 P 2,000 B 4,500 B 2002

Dinitrophenols 25550587 NP 69 5300 2002

Endosulfan Sulfate 1031078 P 62 B 89 B 2002

Endrin 72208 P 0.059 0.060 2003

Endrin Aldehyde 7421934 P 0.29 B 0.30 B,H 2002

Ether, Bis( Chloromethyl) 542881 NP 0.00010 C 0.00029 C 2002

Ethylbenzene 100414 P 530 2,100 2003

Fluoranthene 206440 P 130 B 140 B 2002

Fluorene 86737 P 1,100 B 5,300 B 2002

gamma-BHC (Lindane) 58899 P 0.98 1.8 2003

Heptachlor 76448 P 0.000079 B,C 0.000079 B,C 2002

Heptachlor Epoxide 1024573 P 0.000039 B,C 0.000039 B,C 2002

Hexachlorobenzene 118741 P 0.00028 B,C 0.00029 B,C 2002

Hexachlorobutadiene 87683 P 0.44 B,C 18 B,C 2002

Hexachlorocyclo-hexaneTechnical608731 0.0123 H 0.0414H

Hexachlorocyclopentadiene 77474 P 40 U 1,100 U 2003

Hexachloroethane 67721 P 1.4 B,C 3.3 B,C 2002

Ideno(1,2,3-cd)Pyrene 193395 P 0.0038 B,C 0.018 B,C 2002

Isophorone 78591 P 35 B,C 960 B,C 2002
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Manganese 7439965 NP 50 O 100 A

Mercury

Methylmercury

7439976

22967926

P 0.3 mg/kg J

2001

Methoxychlor 72435 NP 100 A,Z 1986

Methyl Bromide 74839 P 47 B 1,500 B 2002

Methylene Chloride 75092 P 4.6 B,C 590 B,C 2002

Nickel 7440020 P 610 B 4,600 B 1998

Nitrates 14797558 NP 10,000 A 1986

Nitrobenzene 98953 P 17 B 690 B,H,U 2002

Nitrosamines — NP 0.0008 1.24 1980

Nitrosodibutylamine, T 924163 NP 0.0063 C 0.22 C 2002

Nitrosodiethylamine, T 55185 NP 0.0008 C 1.24 C 2002

Nitrosopyrrolidine, T 930552 NP 0.016 C 34 C 2002

N-Nitrosodimethylamine 62759 P 0.00069 B,C 3.0 B,C 2002

N-Nitrosodi-n-Propylamine 621647 P 0.0050 B,C 0.51 B,C 2002

N-Nitrosodiphenylamine 86306 P 3.3 B,C 6.0 B,C 2002

Nutrients — NP See EPA's Ecoregional criteria for Total Phosphorus, Total Nitrogen, Chlorophyll a and Water Clarity

(Secchi depth for lakes; turbidity for streams and rivers) (& Level III Ecoregional criteria)

Pentachlorobenzene 608935 NP 1.4 E 1.5 E 2002

Pentachlorophenol 87865 P 0.27 B,C 3.0 B,C,H 2002

pH — NP 5 – 9 1986

Phenol 108952 P 10,000 ll,U 860,000 ll,U 2009

Polychlorinated Biphenyls

(PCBs)

P 0.000064 B,C,N 0.000064 B,C,N 2002

Pyrene 129000 P 830 B 4,000 B 2002

Selenium 7782492 P 170 Z 4200 2002

Solids Dissolved and

Salinity

— NP 250,000 A 1986

Tetrachlorobenzene,1,2,4,5- 95943 NP 0.97 B 1.1 B 2002

Tetrachloroethylene 127184 P 0.69 C 3.3 C 2002

Thallium 7440280 P 0.24 0.47 2003

Toluene 108883 P 1,300 Z 15,000 2003

Toxaphene 8001352 P 0.00028 B,C 0.00028 B,C 2002

Trichloroethylene 79016 P 2.5 C 30 C 2002

Trichlorophenol,2,4,5- 95954 NP 1,800 B 3,600 B 2002

Vinyl Chloride 75014 P 0.025 C,kk 2.4 C,kk 2003

Zinc 7440666 P 7,400 U 26,000 U 2002

1,1,1-Trichloroethane 71556 P Z

1,1,2,2-Tetrachloroethane 79345 P 0.17 B,C 4.0 B,C 2002

1,1,2-Trichloroethane 79005 P 0.59 B,C 16 B,C 2002

1,1-Dichloroethylene 75354 P 330 7,100 2003

1,2,4-Trichlorobenzene 120821 P 35 70 2003

1,2-Dichlorobenzene 95501 P 420 1,300 2003

1,2-Dichloroethane 107062 P 0.38 B,C 37 B,C 2002

1,2-Dichloropropane 78875 P 0.50 B,C 15 B,C 2002
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1,2-Diphenylhydrazine 122667 P 0.036 B,C 0.20 B,C 2002

1,2-Trans-Dichloroethylene 156605 P 140 Z 10,000 2003

1,3-Dichlorobenzene 541731 P 320 960 2002

1,3-Dichloropropene 542756 P 0.34 C 21 C 2003

1,4-Dichlorobenzene 106467 P 63 190 2003

2,3,7,8-TCDD (Dioxin) 1746016 P 5.0E-9 C 5.1E-9 C 2002

2,4,6-Trichlorophenol 88062 P 1.4 B,C 2.4 B,C,U 2002

2,4-Dichlorophenol 120832 P 77 B,U 290 B,U 2002

2,4-Dimethylphenol 105679 P 380 B 850 B,U 2002

2,4-Dinitrophenol 51285 P 69 B 5,300 B 2002

2,4-Dinitrotoluene 121142 P 0.11 C 3.4 C 2002

2-Chloronaphthalene 91587 P 1,000 B 1,600 B 2002

2-Chlorophenol 95578 P 81 B,U 150 B,U 2002

2-Methyl-4,6-Dinitrophenol 534521 P 13 280 2002

3,3'-Dichlorobenzidine 91941 P 0.021 B,C 0.028 B,C 2002

3-Methyl-4-Chlorophenol 59507 P U U

4,4'-DDD 72548 P 0.00031 B,C 0.00031 B,C 2002

4,4'-DDE 72559 P 0.00022 B,C 0.00022 B,C 2002

4,4'-DDT 50293 P 0.00022 B,C 0.00022 B,C 2002

*P/NP – Indicates either a Priority Pollutant (P) or a Non Priority Pollutant (NP).

Footnotes

A This human health criterion is the same as originally published in the Red Book which predates the 1980 methodology and did not utilize the fish ingestion BCF

approach. This same criterion value is now published in the Gold Book.

B This criterion has been revised to reflect The Environmental Protection Agency's q1* or RfD, as contained in the Integrated Risk Information System (IRIS) as of May 17,

2002. The fish tissue bioconcentration factor (BCF) from the 1980 Ambient Water Quality Criteria document used to derive the original criterion was retained in each case.

C This criterion is based on carcinogenicity of 10

-6

risk. Alternate risk levels may be obtained by moving the decimal point (e.g., for a risk level of 10

-5

, move the decimal

point in the recommended criterion one place to the right).

D According to the procedures described in the Guidelines for Deriving Numerical National Water Quality Criteria for the Protection of Aquatic Organisms and Their Uses,

except possibly where a very sensitive species is important at a site, freshwater aquatic life should be protected if both conditions specified in Appendix C to the PreambleCalculation of Freshwater Ammonia Criterion are satisfied.

FThe derivation of this value is presented in the Red Book (EPA 440/9-76-023, July, 1976).

H No criterion for protection of human health from consumption of aquatic organisms excluding water was presented in the 1980 criteria document or in the 1986 Quality

Criteria for Water. Nevertheless, sufficient information was presented in the 1980 document to allow the calculation of a criterion, even though the results of such a

calculation were not shown in the document.

I This criterion for asbestos is the Maximum Contaminant Level (MCL) developed under the Safe Drinking Water Act (SDWA).

J This fish tissue residue criterion for methylmercury is based on a total fish consumption rate of 0.0175 kg/day.

M EPA is currently reassessing the criteria for arsenic.

N This criterion applies to total pcbs, (e.g., the sum of all congener or all isomer or homolog or Aroclor analyses.)

O This criterion for manganese is not based on toxic effects, but rather is intended to minimize objectionable qualities such as laundry stains and objectionable tastes in

beverages.

P Although a new RfD is available in IRIS, the surface water criteria will not be revised until the National Primary Drinking Water Regulations: Stage 2 Disinfectants and

Disinfection Byproducts Rule (Stage 2 DBPR) is completed, since public comment on the relative source contribution (RSC) for chloroform is anticipated.

R U.S. EPA. 1973. Water Quality Criteria 1972. EPA-R3-73-033. National Technical Information Service, Springfield, VA.; U.S. EPA. 1977. Temperature Criteria for

Freshwater Fish: Protocol and Procedures. EPA 600/3-77-061. National Technical Information Service, Springfield, VA.
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S This recommended water quality criterion for arsenic refers to the inorganic form only.

T U.S. EPA. 1986. Ambient Water Quality Criteria for Dissolved Oxygen. EPA 440/5-86-003. National Technical Information Service, Springfield, VA.

U The organoleptic effect criterion is more stringent than the value for priority toxic pollutants.

Z A more stringent Maximum Contaminant Level (MCL) has been issued by EPA under the Safe Drinking Water Act. Refer to drinking water regulations 40CFR141 or Safe

Drinking Water Hotline (1-800-426-4791) for values.

jj This recommended water quality criterion is expressed as total cyanide, even though the IRIS RFD we used to derive the criterion is based on free cyanide. The multiple

forms of cyanide that are present in ambient water have significant differences in toxicity due to their differing abilities to liberate the CN-moiety. Some complex cyanides

require even more extreme conditions than refluxing with sulfuric acid to liberate the CN-moiety. Thus, these complex cyanides are expected to have little or no

'bioavailability' to humans. If a substantial fraction of the cyanide present in a water body is present in a complexed form (e.g., Fe

4

[Fe(CN)6]3), this criterion may be over

conservative.

kk This recommended water quality criterion was derived using the cancer slope factor of 1.4 (LMS exposure from birth).

ll This criterion has been revised to reflect the Environmental Protection Agency's cancer slope factor (CSF) or reference dose (RfD), as contained in the Integrated Risk

Information System (IRIS) as of (date of publication of Final FR Notice). The fish tissue bioconcentration factor (BCF) from the 1980 Ambient Water Quality Criteria

document was retained in each case.

Organoleptic Effects (e.g., taste and odor)

Pollutant CAS Number Organoleptic Effect Criteria

(μg/L)

FR Cite/

Source

Acenaphthene 83329 20 Gold Book

Color NP Gold Book

Iron 7439896 NP Gold Book

Monochlorobenzene 108907 20 Gold Book

Tainting Substance NP Gold Book

3-Chlorophenol — 0.1 Gold Book

4-Chlorophenol 106489 0.1 Gold Book

2,3-Dichlorophenol — 0.04 Gold Book

2,5-Dichlorophenol — 0.5 Gold Book

2,6-Dichlorophenol — 0.2 Gold Book

3,4-Dichlorophenol — 0.3 Gold Book

2,4,5-Trichlorophenol 95954 1 Gold Book

2,4,6-Trichlorophenol 88062 2 Gold Book

2,3,4,6-Tetrachlorophenol — 1 Gold Book

2-Methyl-4-Chlorophenol — 1800 Gold Book

3-Methyl-4-Chlorophenol 59507 3000 Gold Book

3-Methyl-6-Chlorophenol — 20 Gold Book

2-Chlorophenol 95578 0.1 Gold Book

Copper 7440508 1000 Gold Book

2,4-Dichlorophenol 120832 0.3 Gold Book

2,4-Dimethylphenol 105679 400 Gold Book

Hexachlorocyclopentadiene 77474 1 Gold Book

Manganese 7439965

Nitrobenzene 98953 30 Gold Book

Pentachlorophenol 87865 30 Gold Book

Phenol 108952 300 Gold Book

Zinc 7440666 5000 45 FR79341
water.epa.gov/scitech/swguidance/standards/criteria/current/index.cfm#hhtable 9/11

Notes:

1. These criteria are based on organoleptic (taste and odor) effects. Because of variations in chemical nomenclature systems, this listing of pollutants does not duplicate

the listing in Appendix A of 40 CFR Part 423. Also listed are the Chemical Abstracts Service (CAS) registry numbers, which provide a unique identification for each

chemical.

Additional Notes

1. Criteria Maximum Concentration and Criterion Continuous Concentration

The Criteria Maximum Concentration (CMC) is an estimate of the highest concentration of a material in surface water to which an aquatic community can be

exposed briefly without resulting in an unacceptable effect. The Criterion Continuous Concentration (CCC) is an estimate of the highest concentration of a

material in surface water to which an aquatic community can be exposed indefinitely without resulting in an unacceptable effect. The CMC and CCC are just two of

the six parts of an aquatic life criterion; the other four parts are the acute averaging period, chronic averaging period, acute frequency of allowed exceedence, and

chronic frequency of allowed exceedence. Because 304(a) aquatic life criteria are national guidance, they are intended to be protective of the vast majority of the

aquatic communities in the United States.

2. Criteria Recommendations for Priority Pollutants, Non Priority Pollutants and Organoleptic Effects

This compilation lists all priority toxic pollutants and some non priority toxic pollutants, and both human health effect and organoleptic effect criteria issued

pursuant to CWA §304(a). Blank spaces indicate that EPA has no CWA §304(a) criteria recommendations. For a number of non-priority toxic pollutants not listed,

CWA §304(a) "water + organism" human health criteria are not available, but EPA has published MCLs under the SDWA that may be used in establishing water

quality standards to protect water supply designated uses. Because of variations in chemical nomenclature systems, this listing of toxic pollutants does not

duplicate the listing in Appendix A of 40 CFR Part 423. Also listed are the Chemical Abstracts Service CAS registry numbers, which provide a unique identification

for each chemical.

3. Human Health Risk

The human health criteria for the priority and non priority pollutants are based on carcinogenicity of 10

-6

risk. Alternate risk levels may be obtained by moving the

decimal point (e.g., for a risk level of 10

-5

, move the decimal point in the recommended criterion one place to the right).

4. Water Quality Criteria published pursuant to Section 304(a) or Section 303(c) of the CWA

Many of the values in the compilation were published in the California Toxics Rule. Although such values were published pursuant to Section 303(c) of the CWA,

they represent the Agency's most recent calculation of water quality criteria and are thus the Agency's 304(a) criteria.

5. Calculation of Dissolved Metals Criteria

The 304(a) criteria for metals, shown as dissolved metals, are calculated in one of two ways. For freshwater metals criteria that are hardness-dependent, the

dissolved metal criteria were calculated using a hardness of 100 mg/l as CaCO3 for illustrative purposes only. Saltwater and freshwater metals' criteria that are

not hardness-dependent are calculated by multiplying the total recoverable criteria before rounding by the appropriate conversion factors. The final dissolved

metals' criteria in the table are rounded to two significant figures. Information regarding the calculation of hardness dependent conversion factors are included in

the footnotes.

6. Maximum Contaminant Levels

The compilation includes footnotes for pollutants with Maximum Contaminant Levels (MCLs) more stringent than the recommended water quality criteria in the

compilation. MCLs for these pollutants are not included in the compilation, but can be found in the appropriate drinking water regulations (40 CFR 141.11-16 and

141.60-63), or can be accessed through the Safe Drinking Water Hotline (800-426-4791) or online.

7. Organoleptic Effects

The compilation contains 304(a) criteria for pollutants with toxicity-based criteria as well as non-toxicity based criteria. The basis for the non-toxicity based criteria

are organoleptic effects (e.g., taste and odor) which would make water and edible aquatic life unpalatable but not toxic to humans. The table includes criteria for

organoleptic effects for 23 pollutants. Pollutants with organoleptic effect criteria more stringent than the criteria based on toxicity (e.g., included in both the priority

and non-priority pollutant tables) are footnoted as such.

8. Gold Book

The "Gold Book" is Quality Criteria for Water: 1986. EPA 440/5-86-001.

9. Correction of Chemical Abstract Services Number

The Chemical Abstract Services number (CAS) for Bis(2-Chlorisoprpyl) Ether, has been revised in IRIS and in the table. The correct CAS number for this chemical

is 108-60-1. The previous CAS number for this pollutant was 39638-32-9.

10. Contaminants with Blanks

EPA has not calculated criteria for contaminants with blanks. However, permit authorities should address these contaminants in NPDES permit actions using the

States' existing narrative criteria for toxics.
water.epa.gov/scitech/swguidance/standards/criteria/current/index.cfm#hhtable 10/11

11. Specific Chemical Calculations

Selenium—Aquatic Life

This compilation contains aquatic life criteria for selenium that are the same as those published in the proposed CTR. In the CTR, EPA proposed an acute

criterion for selenium based on the criterion proposed for selenium in the Water Quality Guidance for the Great Lakes System (61 FR 58444). The GLI and CTR

proposals take into account data showing that selenium's two prevalent oxidation states in water, selenite and selenate, present differing potentials for aquatic

toxicity, as well as new data indicating that various forms of selenium are additive. The new approach produces a different selenium acute criterion concentration,

or CMC, depending upon the relative proportions of selenite, selenate, and other forms of selenium that are present.

EPA is currently undertaking a reassessment of selenium, and expects the 304(a) criteria for selenium will be revised based on the final reassessment (63 FR

26186). However, until such time as revised water quality criteria for selenium are published by the Agency, the recommended water quality criteria in this

compilation are EPA's current 304(a) criteria.

Appendix A—Conversion Factors for Dissolved Metals

Metal Conversion Factor

freshwater CMC freshwater CCC saltwater CMC saltwater CCC

1

Arsenic 1.000 1.000 1.000 1.000

Cadmium 1.136672-[(ln hardness)(0.041838)] 1.101672-[(ln hardness)(0.041838)] 0.994 0.994

Chromium III 0.316 0.860 — —

Chromium VI 0.982 0.962 0.993 0.993

Copper 0.960 0.960 0.83 0.83

Lead 1.46203-[(ln hardness)(0.145712)] 1.46203-[(ln hardness)(0.145712)] 0.951 0.951

Mercury 0.85 0.85 0.85 0.85

Nickel 0.998 0.997 0.990 0.990

Selenium — — 0.998 0.998

Silver 0.85 — 0.85 —

Zinc 0.978 0.986 0.946 0.946

Appendix B—Parameters for Calculating Freshwater Dissolved Metals Criteria That Are Hardness-Dependent

Chemical mA

b

A mC

b

C

Freshwater Conversion Factors (CF)

CMC CCC

Cadmium 1.0166 -3.924 0.7409 -4.719 1.136672-[(lnhardness)(0.041838)] 1.101672-[(lnhardness)(0.041838)]

Chromium III 0.8190 3.7256 0.8190 0.6848 0.316 0.860

Copper 0.9422 -1.700 0.8545 -1.702 0.960 0.960

Lead 1.273 -1.460 1.273 -4.705 1.46203-[(lnhardness)(0.145712)] 1.46203-[(lnhardness)(0.145712)]

Nickel 0.8460 2.255 0.8460 0.0584 0.998 0.997

Silver 1.72 -6.59 — — 0.85 —

Zinc 0.8473 0.884 0.8473 0.884 0.978 0.986

Hardness-dependant metals' criteria may be calculated from the following:

CMC (dissolved) = exp{mA[ln(hardness)]+ b

A

} (CF)

CCC (dissolved) = exp{mC[ln(hardness)]+ bC} (CF)

Appendix C - Calculation of Freshwater Ammonia Criterion

1. The one-hour average concentration of total ammonia nitrogen (in mg N/L) does not exceed, more than once every three years on the average, the CMC (acute

criterion) calculated using the following equations:

Where salmonid fish are present:

CMC = (0.275/(1 + 10

7.204-pH

)) + (39.0/(1 + 10

pH-7.204

))

Or where salmonid fish are not present:

CMC = (0.411/(1 + 10

7.204-pH

)) + (58.4/(1 + 10

pH-7.204

))

2.A. The thirty-day average concentration of total ammonia nitrogen (in mg N/L) does not exceed, more than once every three years on theaverage, the CCC

(chronic criterion) calculated using the following equations:
water.epa.gov/scitech/swguidance/standards/criteria/current/index.cfm#hhtable 11/11

Last updated on Thursday, August 30, 2012

When fish early life stages are present:

CCC = ((0.0577/(1 + 10

7.688-pH

)) + (2.487/(1 + 10

pH-7.688

))) x MIN (2.85, 1.45·10

0.028·(25-T)

)

When fish early life stages are absent:

CCC = ((0.0577/(1 + 10

7.688-pH

)) + (2.487/(1 + 10

pH-7.688

))) x 1.45·10

0.028·(25-MAX(T,7))

B. In addition, the highest four-day average within the 30-day period should not exceed 2.5 times the CCC.

The Gold Book

Quality Criteria for Water, 1986 (PDF) (477 pp., 4.6 MB) May 1986

The Red Book

Quality Criteria for Water, 1976 (PDF) (534 pp., 6.2 MB) July 1976

Chemical Specific Criteria Documents from the 1980s