P.1 

OAR Box 1878 

Prepped by Charmelle Matltews 

Document Number: 

130) ll-E-14 

Docket Number: 

A-90-19 

Printed 11/28/2008 1:21:26 PM Sheet 130 of 145 
. ' * RADIAN 

CORPORATIO N 

P.2 

A-90-19 

ll-E-14 

August 9, 1990 

Mr. Les Evans 

Chemical and Petroleum Branch (MD-13) 

U. S. Environmental Protection Agency 

Research Triangle Park, North Carolina 27711 

Dear Les: 

\ f*=-

i: f U .*' 

L 

DEC I 8 1992 

. . -»J.»J^ ' EPA AIR r*c-.w 

Enclosed are two (2) copies of the meeting notes documenting the July 12, 

1990, EPA/CMA meeting. You August 7, comments and suggested revisions have 

been incorporated. Please call if we can be of further assistance. 

Sincerely, 

Glenn D. Rives 

Project Director 

GDR:cao 

Enclosures 

cc: IP file Section 1.7 

Progress Center/3200 E. Chapel Hill Rd./Nelson Hwy./P.O. Box 13000/Research Triangle Park, N.C. 27709/(919)541-9100 
P.3 

MEETING BETWEEN REPRESENTATIVES OF CMA AND EPA/OAQPS 

JULY 12, 1990 

MUTUAL BUILDING 

DURHAM, NORTH CAROLINA 

DRAFT MEETING NOTES 

Representatives from the Chemical Manufacturing Association (CMA) and 

the Environmental Protection Agency's (EPA's) Office of Air Quality Planning 

and Standards (OAQPS) met for the purpose of discussing the Hazardous Organic 

NESHAP (HON) regulatory development program. After brief introductions, an 

agenda was distributed as a guide for discussion. The major discussion 

topics centered around the scope of the HON effort, the technical approach 

being used for determining Maximum Achievable Control Technology (MACT) for 

the HON, data needs, and finally the Agency's source category selection and 

prioritization approach for future regulatory efforts. Four attachments are 

included with these meeting notes. 

Attachment 1 

Attachment 2 

Attachment 3 

Attachment 4 

Meeting Agenda 

Attendees 

Background Information for the HON 

Information Request for HON sources 

SCOPE OF HON: 

Bob Rosensteel, Chief of the Chemical Manufacturing Section, 

provided an overview of the source coverage of the HON regulatory 

program, emission types to be regulated and the control techniques 

that are candidates for MACT. Mr. Rosensteel described the 

affected sources as process units within the synthetic organic 

chemical manufacturing industry (SOCMI) that either produce or use 

as a raw material or intermediate one or more of the HAP compounds 

listed in the Clean Air Act Amendments (CAA). Seven non-SOCMI 

sources were also described as being affected by the HON equipment 

leak and storage regulations. Pages 1-5 of Attachment 3 contain 

the discussion points. 

cao.046 

7-l2mtg 
P.4 

APPROACH FOR MACT: 

Mr. Rosensteel identified the control techniques that were being 

considered as candidates for MACT (Attachment 3, pages 6-8), 

noting that for most sources, candidate techniques are those 

required by similar New Source Performance Standards (NSPS), or 

NESHAP regulations. 

Representatives from CMA suggested that the Agency should consider 

product recovery (recycling to process) as a MACT candidate. 

Commentors expressed concern that automatic adoption of combustion 

devices as MACT would not allow for initiative in product 

recovery, and combustion may not necessarily be the best solution 

for all streams when other environmental issues are considered 

(i.e., increased N0x, S0X, and C02, etc.). EPA representatives 

responded that any format for a regulation (for example a maximum 

exhaust concentration or maximum emission rate) would allow 

companies to use product recovery devices to reduce emissions 

below the concentration or emission rate and therefore combustion 

would not be required. . 

CMA participants asked if EPA planned to rigorously investigate 

the technical feasibility of control options for each of the 

approximately 600 chemical process types. Commenters noted that 

some chemicals and/or processes have unique characteristics that 

would not adequately be accounted for in a generic MACT 

determination. EPA representatives responded that available 

technical data are being used to assess the feasibility of control 

options but the analysis does not involve a detailed search for 

exceptions. EPA representatives asked CMA to provide information 

on specific processes where such special conditions exists. 

Questions were raised regarding the possible use of a total 

resource effectiveness (TRE) approach for defining MACT. EPA 

representatives responded that it is not expected that such an 

approach will be used. The type of cut-off criteria that are 

being discussed and considered at the EPA staff level for possible 

use in determining MACT were briefly outlined (emission levels, 

exhaust concentration, plant production, storage tank size and 

vapor pressure, etc.). 

cao.046 

7-l2mtg 
P.5 

Mr. Bennett King from Radian Corporation presented an overview of 

the technical approach to develop baseline emission estimates, 

control costs, and emission reduction estimates for the HON 

emission sources. Pages 9-13 of Attachment 3 contain the 

principal points. 

Representatives from CMA questioned how EPA planned to account for 

the site-specific costs associated with control device 

retrofitting. Discussion centered around safety concerns (i.e., 

location of a flare or combustion device in relation to process 

units or other process equipment), and physical constraints that 

can add significant retrofit cost. EPA pointed out that flares 

and incinerators have safety considerations incorporated into 

their design criteria based on NFPA recommendations, but the 

Agency is unsure of how to incorporate retrofit costs into cost 

algorithms to be used for a broad category like SOCMI because of 

the wide variety of retrofit situations. EPA representatives 

welcomed suggestions and input from CMA on approach for 

determining an appropriate factor. 

Mr. Bob Ajax, Chief of the Standards Development Branch commented 

that the emphasis of the revised CAA is on application of the best 

technologies which are now in use to all similar toxic sources. 

While cost effectiveness is a consideration when control decisions 

are made for categories of sources, it is not clear that variation 

in cost effectiveness from facility to facility (or high cost 

effectiveness at individual facilities) will be a concern. 

Mr. Tom Walton from EPA's Chemical Economics Impacts Section 

presented the Agency's approach for performing the econbmic impact 

analyses of the HON regulation. Pages 14-16 of Attachment 3 

contain the discussion points. 

DATA NEEDS: 

Mr. Glenn Rives from Radian Corporation discussed HON data needs 

that were outlined in a June 29, 1990 letter to Ms. Karen Fiddler 

from Mr. Les Evans (Attachment 4). A listing of the information 

needs in order of priority is as follows: 1) production capacity, 

cao.046 

7-l2mtg 
P.6 

2) market price, 3) stoichiometry/process information 4) location 

of producers (state and county), and 5) identity of batch 

processes. 

• The listed information is requested by mid-August. 

• EPA representatives agreed to send CMA two items: 1) The Spaite 

chemical trees used in the preliminary identification of affected 

chemical processes, and 2) an electronic data file containing the 

450 SOCMI chemical products and their CAS numbers. 

SOURCE CATEGORY SELECTION AND PRIORITIZATION: 

• Mr. Rosensteel described the approach used in developing the 

source category ranking system and reported that there has been no 

new lists or information released since last year's NAPCTAC 

meeting. 

• There was a general discussion concerning the implementation of 

the HON regulations. CMA representatives expressed concern over 

the Agency's plans to cover all 600 SOCMI sources in single 

regulation all with the same compliance date. Commentors expressed 

concern about vendor and engineering capacity to support such 

broad needs, as well as the possibility of permitting logjams. 

EPA agreed to give further consideration to this point. 

cao.046 

7-i2mtg 
P.7 

ATTACHMENT 1 

SUGGESTED AGENDA FOR 7/12/90 MEETING BETWEEN CMA and EPA 

I. INTRODUCTIONS - CMA and EPA 

It. SUMMARY OF CMA'S AND EPA'S OBJECTIVES FOR MEETING - CMA *nd EPA 

III. SOURCE CATEGORY SELECTION AND PRIORITIZATION 

A. Status of EPA's activities - EPA 

B. Key issues of concern to CMA - CMA 

C. Discuss areas where CMA can contribute - CMA *nd EPA 

IV. MACT Development for Process Vents, Transfer Operations, and 

Storage Tanks 

A. Status of EPA's activities - EPA 

B. Key issues of concern to CMA - CMA 

Process vents 

- Transfer operations 

- Storage tanks 

C. Discuss ^reas where CMA cin coutr irmt<» - CMA and EPA 

V. Wrap Up - CMA and EPA 

A. Identj fy next, steps 

B. Summarize flr.tion items 

C. Make arrangements for follow up 
ATTACHMENT 2 

P.8 

Name 

Bob Rosensteel 

Dan Anderson 

Ken Ettinger 

Neil Prange 

Brian Taranto 

Bob Aj ax 

Susan Wyatt 

K.C. Hustvedt 

Penny Lassiter 

Karen Fidler 

Al Wehe 

Joe Hovious 

Debbie Stackhouse 

Linda Chaput 

Glenn Rives 

Bennett King 

Joe Woolbert 

David Ocamb 

Jan Meyer 

Chuck Grigsby 

Tim Mohin 

Randy McDonald 

David Heise 

Bruce Wallington 

Richard Sigman 

Tom Walton 

Kathy Bailey 

Leslie Evans 

David Gustafson 

Kim Boudreaux 

John M. Pierrard 

ComDanv 

EPA 

First Chem/CMA 

Chevron Chemical 

Monsanto/CMA 

Exxon Chemical 

EPA 

EPA 

EPA 

EPA 

CMA 

EPA 

Union Carbide 

EPA 

EPA 

Radian 

Radian 

Texas Eastman Co 

Radian 

EPA 

BASF 

EPA 

EPA 

Eli Lilly 

Merck 

CMA 

EPA 

CMA 

EPA 

DOW 

Ethyl 

DuPont 

Telephone Number 

919-541-

601-938-

415-842-

314-694-

713-870-

919-541-

919-541-

919-541-

919-541-

202-887-

919-541-

203-794-

919-541-

919-541-

919-541-

919-541-

214-237-

919-541-

919-541-

201-397-

919-541-

919-541-

317-276-

201-750-

202-887-

919-541-

202-887-

919-541-

517-636-

504-388-

302-366-

5608 

2227 

5880 

5742 

6117 

5579 

5674 

5 39 5 

5396' 

1176 

5623 

518 3 

5258 

5358 

9100 

9100 

5475 

9100 

5254 

2803 

5349 

5402 

3950 

7648 

1313 

5311 

1186 

5410 

2953 

7776 

2870 
P.9 

ATTACHMENT 3 

BACKGROUND INFORMATION FOR THE 

HAZARDOUS ORGANIC NESHAP (HON) 

CMA - EPA MEETING 

July 12, 1990 

f\ 
P.10 

PURPOSE: TO PROVIDE INFORMATION CONCERNING THE SCOPE OF THE HON, 

DESCRIBE THE CONTROL TECHNIQUES THAT WILL BE ANALYZED FOR 

REDUCING EMISSIONS, AND DESCRIBE THE ANALYTICAL APPROACH TO 

ESTIMATE NATIONAL IMPACTS OF CANDIDATE REGULATORY ALTERNATIVES 

P ^ 
P.11 

SCOPE OF HON 

• THE SYNTHETIC ORGANIC CHEMICAL MANUFACTURING INDUSTRY (SOCMI) 

INCLUDES THE PRODUCTION Of SOME 600+ HIGH VOLUME CHEMICALS 

• THE HON SCOPE INCLUDES (1) SOCMI PROCESSES THAT (A) PRODUCE A HAP ON 

THE CAAA LIST OF 191, OR (B) USE (AS REACTANT) ONE OR MORE HAP TO 

PRODUCE A CHEMICAL, and (2) STORAGE AND EQUIPMENT LEAKS FOR 

PRODUCTION OF NEOPRENE, STYRENE-BUTADIENE RESINS, POLYBUTADIENE, 

PHARMACEUTICALS, PESTICIDES, CHLORINE AND MISCELLANEOUS BUTADIENE 

USERS 

• ABOUT 450 CHEMICALS HAVE BEEN IDENTIFIED THAT FALL WITHIN THE HON 

SCOPE 

• TO DATE WE HAVE IDENTIFIED AN AVERAGE OF 1.5 ROUTES TO PRODUCE EACH 

CHEMICAL, EACH ROUTE TO PRODUCE A CHEMICAL IS DEFINED AS A PRODUCT 

PROCESS 

• THEREFORE ABOUT 650 PRODUCT PROCESSES MAY ULTIMATELY BE 

SUBJECT TO THE RULE 

• CURRENT SCHEDULE CALLS FOR PROPOSAL IN AUGUST, 1991 AND PROMULGATION 

IN AUGUST 1992 

?l 
P.12 

REGULATIONS HAVE BEEN DEVELOPED FOR 

SOCMI AND OTHER EMISSION SOURCES 

• PROCESS VENTS 

AIR OXIDATION PROCESSES (NSPS PROMULGATION) 

DISTILLATION OPERATIONS (NSPS PROMULGATION) 

REACTOR PROCESSES (NSPS PROPOSAL) 

• EQUIPMENT LEAKS (NSPS AND BENZENE NESHAP PROMULGATION) 

• VOLATILE ORGANIC LIQUID STORAGE (NSPS PROMULGATION) 

• BENZENE NESHAP HAS BEEN DEVELOPED FOR EMISSIONS FROM 

WASTEWATER AND TRANSFER OPERATIONS 

• THESE RULES AND DATA FROM THEIR ANALYSES WILL BE USED 

AS INPUTS FOR EXAMINING IMPACTS OF REGULATORY ALTERNATIVES 

FOR THE HON 

P* 
P.13 

IT IS ANTICIPATED THAT THE HON WILL 

REGULATE THESE EMISSION SOURCES 

PROCESS VENTS 

EQUIPMENT LEAKS 

STORAGE VESSELS 

TRANSFER 

WASTEWATER 

Pi 
P.14 

CONTROL TECHNIQUES THAT ARE CANDIDATES FOR MACT: 

PROCESS VENTS 

NON - CHLORINATED ORGANIC VAPOR CONTAINING 

STREAMS - 98% COMBUSTION 

HALOGENATED ORGANIC VAPOR CONTAINING 

STREAMS - 98% COMBUSTION BY INCINERATION PLUS SCRUBBING 

EQUIPMENT LEAKS 

RESULTS OF THE REGULATORY NEGOTIATION WILL BE USED 

^ 
P.15 

CONTROL TECHNIQUES THAT ARE CANDIDATES FOR MACT: 

(CONTINUED) 

STORAGE VESSELS 

UNDERGROUND OR HORIZONTAL VESSELS - REFRIGERATED 

CONDENSERS 

NON CHLORINATED - FIXED ROOF TANKS WITH INTERNAL 

FLOATING COVER HAVING ACCEPTABLE SEAL(S) 

CHLORINATED - REFRIGERATED CONDENSER 

f 
P.16 

CONTROL TECHNIQUES THAT ARE CANDIDATES FOR MACT: 

(CONTINUED) 

TRANSFER 

NONCHLORINATED - (1) REFRIGERATED CONDENSER, 

(2) 98% COMBUSTION DEVICE 

CHLORINATED - (1) REFRIGERATED CONDENSER, 

(2) 98% INCINERATOR + SCRUBBING 

WASTEWATER 

STEAM STRIPPING OF AQUEOUS WASTE STREAM + WATER 

COOLED CONDENSER + REFRIGERATED CONDENSER 

f* 
P.17 

INDUSTRIAL PROFILE SPECIFICS 

PURPOSES 

CHARACTERIZE INDUSTRY . . . CHEMICALS PRODUCED, PROCESSES 

USED, MANUFACTURING LOCATIONS, EMISSION SOURCES 

DEVELOP A STRUCTURE TO USE INDUSTRY CHARACTERISTICS AND 

CALCULATE BASELINE EMISSIONS, EMISSION REDUCTIONS, CONTROL 

COSTS AND OTHER IMPACTS (FRAMEWORK DATABASE SYSTEM) 

PROVIDE SELECTED DATA FOR EVALUATING REGULATORY ALTERNATIVES 

r Ct 
P.18 

INDUSTRIAL PROFILE SPECIFICS 

(CONTINUED) 

FEATURES 

IDENTIFYING UNIQUE WAYS TO PRODUCE EACH CHEMICAL 

(PRODUCT-PROCESSES), HOW MUCH IS PRODUCED, AND WHO 

PRODUCES IT 

FOR EACH EMISSION SOURCE TYPE, ASSIGN EMISSION AND 

CONTROL/COST MODELS TO EACH PRODUCT-PROCESS 

• MODELS WILL CALCULATE VALUES FOR EACH PROCESS 

UNIT USING PARTICULAR PRODUCT-PROCESS 

OUTPUT FILES CONTAINING BASELINE EMISSIONS AND EMISSION 

REDUCTIONS, CONTROL COSTS, AND OTHER IMPACTS FOR EACH 

CONTROL OPTION (CONTROL TECHNOLOGY) AT THE PROCESS UNIT 

LEVEL 

RESULTS: MAXIMUM FLEXIBILITY IN SELECTING AND EVALUATING 

REGULATORY ALTERNATIVES 

.p/> 
P.19 

INDUSTRIAL PROFILE SPECIFICS 

(CONTINUED) 

METHOD FOR CHARACTERIZING INDUSTRY 

• REVIEW OF READILY AVAILABLE LITERATURE 

• ANALYSIS OF LITERATURE TO DETERMINE . . 

NATIONAL CAPACITY AND PRODUCTION 

MARKET PRICE 

INDIVIDUAL PRODUCERS AND CAPACITIES 

UNIQUE COMMERCIAL PRODUCTION PROCESSES 

(PRODUCT-PROCESSES) 

FOR EACH PRODUCT-PROCESS 

RELATION OF REACTANTS AND PRODUCTS TO 

KNOWN PRODUCT CAPACITY (KG/KG PRODUCT) 

i°! 
P.20 

INDUSTRIAL PROFILE SPECIFICS 

(CONTINUED) 

FRAMEWORK DATABASE SYSTEM 

• INPUTS ... 

INDUSTRY CHARACTERISTICS 

BASELINE CONTROL LEVEL-STATE REGULATIONS, NESHAP 

EMISSION MODELS-ALGORITHM TO CALCULATE BASELINE EMISSIONS 

CONTROL MODELS-ALGORITHM TO CALCULATE EMISSIONS REDUCTIONS 

AND COSTS FOR A SPECIFIC CONTROL OPTION (CONTROL TECHNOLOGY) 

(MODELS DEVELOPED BY FIVE HON REGULATORY PROJECTS) 

• OUTPUTS . . . 

BASELINE EMISSIONS 

EMISSION REDUCTIONS (FOR EACH CONTROL OPTION) 

CONTROL COSTS (FOR EACH CONTROL OPTION) 

/ '-
P.21 

INDUSTRIAL PROFILE SPECIFICS 

(CONTINUED) 

METHODOLOGY 

INDUSTRY CHARACTERISTICS IN DATABASE ON PRODUCT-PROCESS 

BASIS 

LARGELY AUTOMATED PROCESS FOR ASSIGNING EMISSION AND 

CONTROL MODELS TO PRODUCT-PROCESSES 

COMPLETELY AUTOMATED PROCESS FOR CALCULATING BASELINE 

EMISSIONS, EMISSION REDUCTIONS, AND CONTROL COSTS ONCE 

MODELS ARE ASSIGNED TO PRODUCT-PROCESSES 

WE WILL PROJECT NATIONAL IMPACTS BASED ON THE PRODUCTPROCESSES COMPLETELY DEFINED 
P.22 

The Role of Economic Analyses 

0 Economic analyses investigate the behavioral response to 

regulations 

»• Changes in price, production, employment, market structure 

»• Distribution of the cost of control 

O The results of the analyses are considered in determining 

the form and stringency of the standard 

> Both private and social costs are considered 

• Are the sourcses to be regulated similar to those 

for whom the control has been demonstrated? 

O The results are used to determine if other analyses are needed 

• Regulatory Flexibility Analysis (small business concerns) 

• Regulatory Impact Analyses (major regulations) 

r 
P.23 

Challenges For HON Economic Analyses 

Breadth 

• The HON will cover many product-processes 

• Our normal analysis that covers at least each directly 

regulated product can not be done 

O Interdependence 

»• The concept of chemical trees implies complex interactions 

among regulated products 

»• Cumulative regulatory costs are both important and 

difficult to estimate 

O Time 

• Preliminary costs will not be available until late October 

*• The preliminary economic analysis is needed by the middle 

of January 

Pz. 
P.24 

?1 

Approach For HON Economic Analyses 

0 Cumulative cost 

• Use of chemical trees 

* Both average and higher cost estimates 

O Subset selection for detailed analysis 

• Cumulative costs will be used to select some products 

of both average and higher control costs 

»• Will also include the products for which preliminary 

analysis was initiated under the old effort 

0 Subset analysis 

*• Market analysis performed for each product chosen above 

> The results for the whole set will be used to address 

potential impact for products not selected for 

detailed analysis 
P.25 

ATTACHMENT 4 

Ms.Karen Ficiler 

Manager Air Programs 

2501 M Street, N.W. 

Washington, D.C. 20007 

Dear Karen: 

The Environmental Protection Agency is presently assembling information 

on SOCMI to support the new HON NESHAP rulemaking effort. For some chemical 

products we have not been able to find all the information we would like to 

have. The attached enclosure is a list of the chemical products for which 

information is required. The three columns on the enclosure indicate which 

pieces of information are needed for each chemical. In order to use this 

information and maintain our planned schedule we would like this information 

before August 10, 1990. If the information is received after this date it 

will still have value, but it will be more difficult to incorporate- in the 

work. 

The first, and highest priority, information type required is Capacity 

information. Specifically: 

• Names of U.S. producers 

• Location of U.S. producers 

• Specific capacities of each U.S. producer in 1989 (or other year if 

available) 

• Total U.S. production capacity in 1989 (or other year if available) 

• Total U.S. production as a percent of capacity 

The second information type required is Production Process. 

Specifically: 

• Process description emphasizing basic process steps: (i.e., reaction, 

separation, product recovery, etc.) for each commonly used 

production route 

• Chemical reaction equations identifying all chemicals involved 

and the weight ratios of each. 

The third information type required is the Market Price of each 

chemical, qualified with comments describing its condition at the time of sale 

(i.e., percent purity, percent solution, bulk, etc.) 
P.26 

The fourth information type required is an Equipment Component Count for 

a typical process manufacturing these chemicalsT xhere components are defined 

as valves, pumps, and flanges only. For most processes complete counts will 

not be available. If the number of pumps can be approximated we can estimate 

the other components. 

We would appreciate any assistance the Chemical Manufacturing 

Association can give in helping us gather this information. We can talk about 

this during our meeting here in Durham, tentatively set for the morning of 

July 12. We will confirm time and date when you return to your office on 

July 2. 

Sincerely, 

Leslie B. Evans 

Chemical Manufacturing Section 

Chemicals and Petroleum Branch 

Enclosure 

OAQPS:ESD:CPB:CMS:EVANS:thweatt:NCM:MD-13:X5410:6/29/90 

FILE NAME: FIDLER.KAREN 
P.27 

Chemicals Requiring Information 

Enclosure 1 

.CAS 

NUMBER 

121733 

1.05577 

75070 

107891 

603SS 

103844 

64197 

108247 

102012 

S7641 

75865 

'7 5058 

98862 

7S365 

107028 

79061 

79107 

107131 

124049 

111693 

-

107186 

107051 

109751 

1321115 

111411 

123308 

1762954 

62533 

142041 

90040 

100663 

118923 

84651 

103333 

100527 

55210 

71432 

98486 

98113 

92875 

134816 

76937 

65850 

119539 

100470 

CHEMICAL NAKE 

l-Chloro-3-nltrobenzane 

Acetal 

Acataldehyda 

Acataldo1 

Acatantda 

Acetanilide 

Acetic acid 

Acetic anhydride 

Acetoacetantlide 

Acatona 

Acatona cyanohydHn (CN compound) 

Acetonitrile 

Acetophenone 

Acatyl chloride 

Acrolein 

Aery 1 wide 

Acrylic acid 

Acrylonitrile 

Adlpic acid 

Adiponi tri la' 

Alkyl naphthalenes (no CAS# assigned) (POM) 

Al1yl alcohol 

Al 1 yl chloride 

Al 1 yl Cyanide 

Aminobenzoic acid 

Ami noethylethanolami na 

Aminophenol (p-isomer) 

Amaontua Thiocyanate 

Aniline 

Aniline hydrochloride 

Anisidina (o-iscaar) 

Anlsole 

Anthranilic add 

Anthraquinone (POM) 

Azobenzene 

Benzaldenyda 

Benzaaride 

Benzene (Including benzene frcai gasolina) 

Benzanedlsulfonic acid 

Benzeneiulfonlc acid 

Benzidine 

Benzll (POM) 

Senzllic add (POM) 

Benzoic add 

Benzoin (POM) 

Benzonitrile 

Capacity 

Information 

Required 

X 

X 

X 

X 

X 

X 

X 

X' 

X 

X 

X 

X 

•. X 

X 

X 

X 

X 

X 

X 

X 

X 

X 

X 

X 

X 

X 

X 

Production 

Process 

Information 

Required 

X 

X 

X 

X 

X 

X 

X 

X 

X 

X 

X 

X 

X 

X 

X 

X 

X 

X 

X 

X 

Market 

Price 

Informat.ion 

Requi red 

X 

X 

X 

X 

X 

X 

X 

X 

X 

X 

X 

X 

X 

X 

X 

X 

X 

X 

X 

Equipment 

Count 

Information 

Required 
P.28 

CAS 

NUMBER 

119619 

98077 

96884 

140114 

100516 

120514 

100447 

96873 

100469 

92524 

80057 

542881 

10861 

75252 

27497514 

106990 

110634 

123864 

141322 

71363 

78922 

75650 

96737 

109739 

'.3952346 

75649 

35687 

107380 

123728 

107926 

106310 

96480 

109740 

105602 

63252 

75150 

558134 

56235 

75730 

9004357 

75876 

79118 

532274 

106429 

95512 

106478 

i 

Chemicals Requiring InformationEnclosure 1 

CHEMICAL NAME 

Benzophenone (POM) 

Benzotri chloride 

Benzoyl chloride 

Benzyl Acetate 

Benzyl alcohol 

Benzyl benzoate (POM) 

Benzyl chloride 

Benzyl di chloride 

Benzyl amine 

Biphenyl 

Blsphenol A (POM) 

Bls(Chloromethyl)Ether 

BroMobonzono 

Bromofona 

BroMonaphthalene (POM) 

Butadiene (1.3-tsomar) 

Butanedlol (1.4-tsomer) 

Butyl, acetate (n-isomer) 

Butyl aerylate (n-isomer) 

Butyl alcohol (n-isomer) 

Butyl alcohol (s-isomer) 

Butyl alcohol (t-lsomer.) 

Butyl benzoic acid (p-tert-isomer) 

Butylamine (n-isomer) 

Butylaanne (s-isomer) 

Butylamine (t-tsomer) 

Butyl benzyl Phthalate 

Butylene glycol (1.3-isomer) 

Butyraldehydo (n-isomer) 

Butyric add 

Butyric anhydride 

Butyrolacetone 

Butyronitrile 

Caprolacta* 

Carbaryl 

Carbon disulfide 

Carbon tetrabromtde 

Carbon tetrachloride 

Carbon Tatrafluoriaa 

Calluloaa acetate 

Chloral 

Chloroacetic add 

Chloroacetophona (2-tsower) 

Chloroantllne (•-isomer) 

ChloroaniUne (o-Isomer) 

Chloroanlltno (p-isomer) 

Capacity 

Information 

Required 

X 

X 

X 

X 

X 

X 

X 

X 

X. 

X 

X 

X 

X 

X 

X 

X 

X 

X 

X 

X 

X 

X 

X 

X 

X 

Production 

Process 

Information 

Required 

X 

X 

X 

X 

X 

X 

x, 

X 

X 

X 

X 

X 

X 

X 

X 

X 

X 

X 

X 

Market 

Price 

Information 

Required 

X 

X 

X 

X 

X 

X 

X 

X 

X 

X 

X 

X 

X 

X 

X 

X 

X 

X 

•"- ; 

Equipment 

Count 

Information 

Required 
P.29 

CAS 

NUMBER 

Chemicals Requiring Information 

Enclosure 1 

CHEMICAL NAME 

Capacity 

Information 

Required 

Production 

Process 

Information 

Required 

Market 

Price 

Information 

Required 

Equipment 

Count 

Information 

Required 

35913098 Chlorobtnzaldahyde 

108907 Chl orobanzane 

118912 Chlorobanzotc ad d (all isomers) 

2136814 Chlorobenzotrichloride (all isomers) 

1321035 Chlorobenzoyl chloride 

75456 Chl orodlf luoroethane 

25497294 Chlorodlfluoromethane 

67663 Chloroform 

25586430 CMoronaphthalene (POM) 

88733 Chloronitrobenzene (o-isomer) 

100005 Chloronltrobenzana (p-isomer) 

108430 Chlorophenol (m-Isomer) 

95578 Chlorophenol (o-isomer) 

106469 Chlorophenol (p-Isomer) 

25167800 Chlorophenol* 

126996 Chloroprena (2-Chloro-l.3-8utad1ene) 

7790945 Chlorosulfontc ad d 

108418 Chlorotoluene (m-isomer) 

95496 Chlorotoluene (o-isomer) 

106434 Chlorotoluene (p-isomer) 

75729 Chlorotrifluoromethane 

108394 Cresol (m-isomer) 

1319773 Cresols Cresylic acid (mixed) 

95487 Cresols (o-isomer) 

106445 Cresols (p-isomer) 

4170300 Crotonaldohyoa 

3724650 Crotonic ad d 

80159 Cumene hydroperoxide 

98828 Cumene (isopropyl benzene) 

420042 Cyanamide 

372098 Cyanoacatlc ad d (CM compound) 

506774 Cyanogen chloride (CM compound) 

108805 Cyanuric ad d 

108770 Cyanuric chloride 

110827 Cydohexane 

108930 Cyclohexanot 

106941 Cyclohexanone 

110636 Cyclohexene 

106918 Cyclonexylamine 

111784 Cyclooctadiane 

1552121 Cyclooctadiane (1.5-isomer) 

91178 Oacahydronaphthalate 

123422 01 acetone alcohol 

1067214 Olallyl Isophthalata 

131179 Olallyl Phthalate 

27576041 Olaalnobanzolc ad d 
P.30 

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137097 Oiaminophenol Hydrochloride X 

74953 Oibromoethane X 

95761 Oichloroanlline (all Isomers) X 

106467 Olchlorobenzene (1.4-isomer) (P08) 

541731 Olchlorobenzane (m-isomer) X 

95501 Olchlorobenzene (o-isomer) 

1331471 D1chlorobenz1d1ne (3.3-isamer) X 

75718 01chlorodlfluoromethane 

107062 01 chl onset nana (1,2-1 saner) (EDC) 

111444 Olchloroethyl ether (b1s(2-chloroethyl)ether) X 

540590 Olchloroethylene (1.4- Isomer) X 

96231 Oichlorohydrln X 

120832 01chlorophenol (2.4-iscmer) X 

542756 Olchloropropene (1,3-lscmer) 

760236 01chloro-I-butane (3.4-(sonar) X 

461585 Olcyanadlmlde X 

101337 01cyclohexylamine (Ctelohexylamine) X 

111422 01ethanolamine 

91667 Dlethyan1l1ne (Nt»-isomer) X 

84662 01 ethyl Phthalate X 

64675 01 ethyl sulfate X 

109897 01 ethyl amine X 

579668 01 ethyl aniline (2,6-isomer) X 

111466 Oiethylene glycol 

112732 Oiethylene Glycol 01 butyl Ether X 

112367 Oiethylene glycol diethyl c.rmr (glycol ether) 

111966 Oiethylene glycol dimethyl ether (glycol ether) 

124174 Oiethylene Slycol Monobutyl Ether Acetate X 

124177 Oiethylene glycol monobutyl ether acetate (glycol ether) 

112345 Oiethylene glycol monobutyl ether (glycol ether) 

112152 Oiethylene glycol monoethyl ether acetate (glycol ether) 

111900 Oiethylene glycol monoethyl ether (glycol ether) 

111773 Oiethylene glycol esnemethyl ether (glycol ether) 

75376 Olfluoroethane 

25167708 OHsobutylent 

26761400 OUsodocyl phthalate 

27554263 Dilsooctyl phthalate 

674828 01katana 

119937 Dimethyl Benzidine (3.3-1*. 

115106 Olmothyl ether • M 

68122 Dimethyl formamlde (NN-lsa 

57147 01 methyl hydrazine (1.1-U< 

131113 01 methyl Phthalate 

77781 Olmothyl sulfate 

75183 Olmothyl sulfide 

67685 01methyl sulfoxide 

•ar) 

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«•«•) 
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120616 Dimethyl tarephthalate 

124403 01 methyl amine 

108010 01 methyl aminoethanol (2-1somer) 

121697 Olmothylaniline - N.N (N,N DiethylanllIne) 

25154545 01nltrobenzenea 

99343 Olnitrobenzolc add (3,5-tscmer) 

51285 DIMtrophenol (2.*-isomer) 

121142 Oinltrotoluene (2.4-lsomor) (OUT) 

123911 Oioxane (1.4-0lethyleneoxide) 

646060 01oxllane 

101815 01 phenyl Methane 

101848 0iphenyl oxide (POM) 

102089 01 phenyl thiourea (POM) 

122394 Olphenylamlne (POM) 

25265718 Oi propyl ene glycol 

97392 01-o-to1yguan1d1ne 

26675174 Oodecylani11ne 

121013 Oodecylbenzene (n-isomer) 

27193866 Oodecylphenol 

106898 Epichlorohydr1n(l-Chloro-2.3-epoxypropane) 

14U35 Ethanolamlnea (all isomers) 

141736 Ethyl acetate 

141979 Ethyl acetoecetate 

140885 Ethyl acrylate 

100414 Ethyl benzene 

75003 Ethyl chloride (Chloroethana) 

10S395 Ethyl chloroacetate 

122510 Ethyl orthoformete 

95921 Ethyl oxalate 

41892711 Ethyl sodium oxalacetate 

75047 Ethyl amine 

103695 Ethyl aniline (N-Isomer) 

578541 Ethyl aniline (o-Isomer) 

9004573 Ethyl cellulose 

105566 Ethylcyanoacatate 

96491 Ethylene carbonate 

106934 Ethylene dibromide (Oibromoethane) (E06) 

107211 Ethylene glycol 

111557 Ethylene glycol dlacetata 

6299141 Ethylene 61yco1 01 ethyl Ether 

110714 Ethylene glycol dimethyl ether (glycol ether) 

112072 Ethylene glycol monobutyl ether acetate (glycol ether 

111762 Ethylene glycol monobutyl ether (glycol ether) 

11159 Ethylene glycol monoethyl ether acetate (glycol ether 

110605 Ethylene glycol monoethyl ether (glycol ether) 

110496 Ethylene glycol moncmethyl ether acetate (glycol ethe 

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109864 Ethylene glycol moncmethyl ether (glycol ether) 

122996 Ethylene glycol monophenyl ether (glycol ether) 

2807309 Ethylene glycol monopropyl ether (glycol ether) 

151564 Ethylene Imine (Aziridine) 

75218 Ethylene oxide 

107153 Ethylenediamine 

104767 Ethylhexanol (2-1somer) 

103117 Ethylhexyl Acrylate (2-1somer) 

50000 Formaldehyde 

75127 Formamlda 

64186 Formic ad d 

110173 Fumaric acid 

111308 51utaraldehyde 

56815 Glycerol 

26545737 Glycerol dlchlorohydrln 

25791962 Glycerol tr1 ether 

56406 Glycine 

107222 Glyoxal 

118741 Hexachlorobenzene 

87683 Hexachlorobutadiene 

77474 Hexachlorocyclopentadiene 

67721 Hexachloroethane 

592450 Hexadiene (1.4-isomer) 

629118 Hexemethylene glycol 

124094 Hexamathylenediamine 

100970 Hexamathylenetetramine 

106694 Haxanetriol (1.2.6- Isomer) 

74908 Hydrogen cyanide (CN compound) 

123319 Hydroquinone 

99967 Hydroxybenzoic acid (p-isomer) 

106638 Isobutyl Acrylate 

115117 Isobutylene 

78591 Isophorone 

121915 Isophthalic ad d 

108214 Isopropyl acatata 

75310 Isopropylamine 

25168063 Isopropylphenol 

463514 Ketone 

Linear alkyl sulfonate (no CAS*- assigned) 

123013 Linear alkylbenzene (linear oodecylbenzene) 

110167 Mai ale ad d 

108316 Malelc anhydride 

123331 Malelc Hydrazlde 

6915157 Malic ad d 

141797 Maaltyl oxide 

121471 Matanllic ad d 

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P.33 

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79414 Mothacryllc add 

563473 Methallyl chloride 

67561 Methanol 

63683 Methionine 

79209 Methyl acetate 

105453 Methyl acetoacotate 

96333 Methyl Acrylatb 

74839 Methyl bromide (Bromomethane) 

74873 Methyl chlorIda (Chloromethane) 

78933 Methyl ethyl ketone (2-8utanone) 

107313 Methyl formate 

60344 Methyl Hydrazine 

108112 Methyl Isobutyl card no 1 

106101 Methyl Isobutyl ketone (Hexone) 

624839 Methyl tsocyanate 

74931 Methyl Mercaptjan 

80626 Methyl methecrylata 

98851 Methyl Phenol.Cardno1 

1634044 Methyl Tert Butyl Ether 

74895 Methyl amine 

100618 MethylanilIne (n-isomer) 

108872 Methylcyclohexene 

1331222 Methylcyclohexanone 

75092 Methylene chloride (Olchloromethane) 

101779 Methylene dlanlline (4,4-isomer) (M0A) 

101688 Methylene di phenyl dr,sv.:yr-ate (HOI) 

77758 Methylpentynol 

98839 Methylstyrene (a-isomer) 

110918 Morphollne > 

108430 m-Chlorophenbl 

99092 m-Nltroanlllne 

108383 M-Xylene j 

91203 Naphthalene 

85472 Naphthalene sulfonic acid (a-1saner) (POM) 

120183 Naphthalene jsulfonie Mi d (b-lsomer) (POM) 

90153 Naphthol (a-isomer) (POM) 

135193 Naphthol (b-isomer) (POM) 

75969 Neopmntanolc add 

99092 Nltroanlllno (»-Isomer) 

88744 Nltroanlllno (o-1somer) 

100016 Nltroanlllno (p-Isomer) 

91236 NUroanlsola (o-Isomer) 

100174 NUroanlsola (p-isomer) 

98953 Nitrobenzene 

27178832 NUrobenzole Mid (o-.m-.ip- isomers) 

86577 Nitronaphthelene (1-lsomer) 

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P.34 

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Requi red 

108027 NUrophenol (4-isomer) 

38755 NUrophenol (o-isomer) (2-Nitrophenol) 

79469 Nltropropene 

1321126 Nltrotoluene 

38722 Nltrotoluene (2-isomer) 

99081 Nltrotoluene (3-1somer) 

99990 Nltrotoluene (4-isomer) 

25154523 lionyl phenol 

121013' n-Oodecylbenzene 

88120 N-V1nyl-2-Pyrrol1d1ne 

111660 Octane-1 

27193288 Octylphenol 

9002817 Paraformaldehyde 

123637 Paraldehyde 

87865 Pentachlorophenol 

115775 Pentaerythrltol 

79210 Peracetlc Add 

127184 Perchloroethylene(Tetrachloroethylene) 

594423 Perchloromethyl mercaptan 

94702 Phenetldlne (o-isomer) 

156434 Phenetldlne (p-isomer) 

108952 Phenol 

77098 Phenolphthalain 

98679 Phenol sulfonic acids (all isomers) 

91407 Phenyl anthranilic acid 

95545 Phenylenediamine (o-isomer) 

106503 Phenylenediamine (p-isomer) 

108736 Phloroglucinol 

7544S Phosgene 

38993 Phthallc Acid 

85449 Phthallc anhydride 

85416 Phthalimlde 

91156 Phthalonltrile 

108996 Pi col ine (b-isomer) 

110894 Piperadlne 

110850 Piperazine 

25322663 Polyethylene glycol 

25322694 Polypropylene glycol 

57578 Propiolaetono (b Isomer) 

123386 Propionaldehyde 

79094 Propionic Mid 

71236 Propyl alcohol (n-Isomer) 

540545 Propyl chloride 

107106 Propylamine 

78675 Propylene dichloride (1.2-01chloropropane) 

57556 Propylene glycol 
P.35 

Heals Requiring Information 

Enclosure 1 

CAS 

NUMBER 

107982 

75569 

110861 

98511 

106514 

108463 

27138674 

69727 

111206 

127093 

532321 

9004324 

3926823 

143339 

141537 

124414 

139026 

110441 

588590 

100425 

110156 

110612 

121573 

126330 

526830 

100210 

98066 

632791 

634902 

95943 

79345 

117088 

78002 

112607 

109999 

119642 

85438 

75741 

110601 

110189 

108683 

95607 

564649 

26471625 

1333079 

104154 

CHEMICAL NAME 

Propylene Glycol Moncmethyl Ether 

Propylene oxide 

Pyridine 

p-tart-Butyl Toluene 

Qui none 

Rasorcinol 

Resorcylic add 

Salicylic add 

Sebadc Add 

Sodium acetate 

Sodium banzoate 

Sodium carboxymethyl cellulose 

Sodium chloroacatate 

Sodium Cyanide 

Sodium formate 

Sodium Methooxlde. 

Sodium phenate 

Sorblc add 

Stllbene 

Styrene (Vinyl Benzene) 

Succinic acid 

Succinonitrile 

Sulfanllic acid 

Sulfolane' 

Tartaric Add 

Terephthallc acid 

tart-Butyl benzene 

Tatrabromophthallc anhydride 

Tetrachlorobenzene (1,2.3.5-lscmer) 

Tetrachlorobenzene (1,2.4,5-Isomer) 

Tetrachloroathane (1.1,2.2-isomer) 

Tetrachlorophthallc anhydride 

Tetraethyl lead 

Tatraethylene Slycol 

Tetrahydrofuran 

Tetrahydronapthalene (Tetralln) (POM) 

Tetrahydrophthallc anhydride 

Tetramathyl lead 

Tetramethylenedi amine 

Tetramathylethylenediamine 

Toluene 

Toluene 2.4 diamine 

Toluene 2,4 dilsocyanate 

Toluene di1socyanatea (mixture) 

Tolueneeulfonamide 

Tolueneaulfonlc wida (all isomers) 

Capacity 

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- r 

P.36 

Chemicals Requiring Information 

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98599 Toluenesulfonyl chloride 

95534 Toluidina (o-isomer) 

634935 Trichloroanlline (2.4.6-1scmer) 

102821 Trichlorobenzene (1.2.4-isomer) 

71556 Trichloroethane (1.1.1-tsomer) . 

79005 Trichloroethane (1.1.2-1somer) (Vinyl Trichloride) 

79016 Trichloroethylene 

75694 Trichlorofluoromethane 

95954 Trichlorophenol (2.4,5-1 saner) 

76131 Tr1chlorotrifluoroethane (1,2.2 -1.1.2 isomer) 

102716 Tri ethanol amine' 

121448 Trlethylamlne j 

112276 Triethylene glycol 

112492 Trtethylene glycol dimethyl ether (glycol ether) 

112356 Triethylene Glycol Moncmethyl Ether 

7756947 Triisobutylene 

75503 Trimethyl amine 

933482 Trlmothylcyclohoxanol 

2408379 Trimethylcyclohoxanone 

77996 Trimethylopropone 

540841 Trimethylpentanb (2.2.4-isomer) 

S7136 Urea 

108054 Vinyl acetate 

75014 Vinyl chloride (Chloro Ethylene) 

25013154 Vinyl toluene ' 

100403 Vlnylcyclohexeno (4-isomer) 

75354 Vinylidene chloride (1.1-Olchloroethylene) 

25321419 Xylene Sulfonic Add 

1330207 Xylenes (mixtures) 

95476 Xylenes (o-Isomer) 

106423 Xylenes (p-Isomer) 

1300716 Xylenol j 

526750 Xylenol (2,3-1somer) 

105679 Xylenol (2.4-isomer) 

95874 Xylenol (2.5-1 somer) 

576261 Xylenol (2.6-1somer) 

95656 Xylenol (3.4-Isomer) 

108689 Xylenol (3,5-Isomer) 

1300736 Xy11 dine ! 

Note: X Indicates tha Information Is required.