# From: Barnett.Keith@epamail.epa.gov

Sent: Thursday, April 01, 2010 11:19 AM

To: Laney, Michael N. Subject: Data for Lehigh, Leeds Alabama

Attachments: 3

‐ 12

‐ 10 210158A Lehigh
‐ Cement MACT & TPM Protocol.pdf; CC ‐ 184196 HCL 144.2PPM.pdf; Cement MACT ‐ Reporting.xls; Field Data Sheets.pdf; FTIR Data Lehigh mill on 210158.xls; FTIR Lehigh 210158

mill off.xls; Manual Method Equipment Calibrations.pdf; O2 CAL DATA.pdf; O2 DATA.pdf

Keith W. Barnett USEPA/OAQPS/SPPD/MMG

Mail Code D243

‐ 02

Research Triangle Park, NC 27711

919

‐ 541

‐ 5605
barnett.keith@epa.gov

# March 12, 2010

Mr. Joel Yeager

Lehigh Cement Company

8401 Second, Ave.

Leeds, Alabama 35094

Re: Updated Protocol for Cement MACT Emissions Testing

- Main Kiln Stack - Flows & Moisture, O2, CO2 & Hydrogen Chloride

- Main Kiln Stack - Total Particulate Matter (Filterable & Condensible)

Leeds Alabama Facility

Entec Project No.: 210158A

Dear Mr. Yeager,

Please find attached the updated protocol for the upcoming Cement MACT testing based on

information requested by EPA. Additional testing has been requested for operational purposes

for Total Particulate Matter (TPM). The protocol outlines the additional scope of work, test

procedures, QA/QC requirements, example calculations, and support documentation as

required. Lehigh Cement Company (Lehigh) will supply any facility operation parameters to

meet EPA final reporting requirements as need ed. Testing has been scheduled for March 17 &

18, 2010.

If you should have any additional questions about the protocol please call me at (205) 491-

6676.

Sincerely,

Entec Services Inc.

D. Lynn Beane

Birmingham - Operations Manager

* Baton Rouge, LA * * Birmingham, AL * * Mobile, AL * * Raleigh (RTP), NC *

1-800-429-8445 www.entecservices.com

# Project Overview

Entec Services will conduct testing per the r equirements based on the information provided by

Lehigh, as set by information required by EPA in the ICR 114 letter - Cement MACT. The

purpose of the testing will be to meet data collec tion requirements as set by EPA. This protocol

outlines the detailed scope of work, test procedures, QA/QC requirements, example

calculations, and support documentation as required. Lehigh will supply all facility operation

parameters to meet final permitting requirements, and are responsible for all fuel analysis.

Testing will be conducted at the Lehigh facility - Main Kiln Stack. Testing will be conducted with

multiple sampling systems with testing being conducted simultaneously as required from

multiple sample ports. The test team will consist of a three (3) man team including an on-site

FTIR Manager Mr. Erik Groth.

Additional particulate matter (PM) testing has been requested to assist with the optimization of

the lime injection system. Entec will conduct testing at two operating conditions for the

determination of total particulate matter (TPM). TPM testing will be conducted after the

completion of the Cement MACT testing.

Project Scope of Work & Objective

Testing will be conducted on the identified unit to include EPA Test Methods 1-4 (Flows &

Moistures), 3A (Oxygen & Carbon Dioxide), an d 321 (Hydrogen Chloride). All methods will be

followed according to Title 40, Code of Federal Regulations, Part 60 Appendix A for the duration

of this test program. The proposed test program will take a minimum of two (2) test days to

complete with multiple operation conditions - “Mill On” & “Mill Off” as required. The testing will

consist of a minimum of three (3) - one (1) hour test runs at each condition. The test program

will require multiple sampling trains conducted simultaneously as required by the Cement MACT

Table 1. Entec will arrive on site the day prior to the scheduled test plan to conduct site safety

requirements, setup test equipment, and perform preliminary test requirements. The following

table summarizes the reference methods, run durations, and frequency.

Testing will be conducted on the identified unit to include EPA Test Methods 1-4 (Flows &

Moistures), OTM 027 (Particulate - PM10), and OTM 028 (Condensible PM). All methods will

be followed according to Title 40, Code of Federal Regulations, Part 60 Appendix A or other

approved test methods for the duration of this test program. The proposed test program will

take a minimum of two (2) test days to complete with multiple operation conditions - Mill Off - 2.0

TPH & Mill Off - 2.5 TPH as required. The testing will consist of a minimum of three (3) - one (1)

hour test runs at each condition.

# Facility Description and Plant Operations

Lehigh is a subsidiary of Lehigh Cement Company, Allentown, Pennsylvania. Lehigh

manufactures Portland and specialty cement by t he dry process (SIC 3241). All of the limestone

used in cement manufacturing is mined from the quarry adjacent to the Cement Plant. The

quarry and plant are located in Section 21, Township 17 South, Range 1 East in Leeds,

Alabama at latitude 33o 32’ 21” and longitude 86o 32’ 30”.



# Methodology

Entec Services, Inc. proposes to test the identified source per constituents listed in Table 1 in

accordance with USEPA, 40 Part 60 Appendix A Reference Methods or other alternate

approved methods for the entire duration of this test program to meet the requirements in the

identified scope of work and objective.

The calibration and quality assuranc e procedures of all EPA test methods used in this test

program of the ”Quality Assurance Handbook for Air Pollution Measurement System” Volume III

Stationary Source-Specific Methods will be followed throughout the duration of all field testing

and laboratory analysis. The most current CFR revision of each method (July 1, 2008) will be

used.



# Table 1

Proposed Test Methodology

Parameters 40 CFR, Appendix A or Approved Test

Method Sample Technique Duration (minutes) Frequency Additional

Information

Velocity / Volumetric Flow Method 1 & 2 Type S pitot tube 60 minutes 3 runs / per

condition lbs / hour

calculations

Oxygen Method 3A Constant rate extractive sampling

and or Tedlar Gas Bags 60 minutes 3 runs / per

condition O2 Correction

Carbon Dioxide Method 3A Constant rate extractive sampling

and or Tedlar Gas Bags 60 minutes 3 runs / per

condition O2 Correction

Moisture Content Method 4 Impinger Train 60 minutes 3 runs / per

condition Conducted

with each test

# Hydrogen Chloride Method 321 Constant rate extractive sampling 60 minutes 3 runs / per

condition FTIR Method

PM 10 OTM 027 Constant rate sampling 60 minutes 6 runs 2 Conditions

w/ Lime Injection rates adjusted

Condensible PM OTM 028 Constant rate sampling 60 minutes 6 runs 2 Conditions

w/ Lime Injection rates adjusted



# Lab - Analytical

Entec will utilize our internal lab as well as other labs to conduct and meet the analytical

sampling requirements. The following labs have been identified with each constituent listed.

- Entec Services - Moisture Determination

- Entec Services - Filterable & Condensible Particulate Matter

Test Method Description

Sampling Point Determination - Method 1

The sample point selection and traverse points will be selected and performed according to EPA

Reference Method 1. The method will provide a representative measurement site of pollutant

emissions from a stationary source. The cross section of the source is divided into a number of

equal areas, and the traverse points are then located within the center of each of these areas.

Physical measurements are taken on-site to determine the actual stack diameter including

upstream and downstream disturbance locations. These measurements will calculate traverse

point locations based on the tables supplied in the method.

Stack Gas Volumetric Flow - Method 2

The velocity of the gas stream will be deter mined according to EPA Reference Method 2 by

reading the instantaneous velocity head with an inclined manometer at each sampling point with

a calibrated S-type pitot tube attached adjacent to the sample nozzle. The stack pressure will

be measured with the static side of an S-type pitot tube. A calibrated pyrometer will be used to

measure stack temperature at each sampling point. The verification of the absence of cyclonic

flow will be conducted during the initial preliminary velocity measurements as required.

Stack Gas Molecular Weight - Method 3A

The carbon dioxide and oxygen concentrations will be determined using EPA Reference Method

3A. A sample will be continuously extracted at a constant rate from the effluent stream. The

# sample will be conditioned and conveyed to an instrument for determination of the gas

concentration in accordance with EPA Method 3A.

Moisture Content - Method 4

The moisture content used for calculating the gas stream (dry basis) flow rate will be determined

by measuring the amount of condensed moisture in the series of impingers in the sampling train

as described in EPA Reference Method 4 at the completion of each test. The moisture content

will be conducted in conjunction with EPA Method 5. Ice will be placed around the impingers,

with the outlet temperature of the impingers monitored and recorded throughout the duration of

the testing to verify the temperature is less than 68 o 

# F.

Hydrogen Chloride (Method 321)

Method 321 will be utilized for the determination of hydrogen chloride concentrations using a

Fourier transformed infrared (FTIR) spectros copy Process Gas Analyzer manufactured and

supplied by Temet Instrument Company of Helsinki, Finland.

The gas samples will be extracted from the ga s stream through a titanium probe and heated

sample line and plumbed directly to the FTIR process gas analyzer. The sample does not have

to be conditioned since it will be heated to 180 °C before analyzing the gas stream.

Measurements will be taken for moisture and the listed targeted compounds.

The FTIR and sampling equipment will be assembled and allowed to stabilize at a temperature

of 180 °C. The pretest preparations included selecting the appropriate reference spectra for the

anticipated target concentrations and the optimum sampling system configuration for measuring

the target analytes. Once the system is at temperature a leak check of the sampling system will

be performed. Then a baseline determination will be performed using nitrogen for a zero check.

This will be to determine the level of background noise. We will then perform a Pre test

Calibration Transfer Standard (CTS) to evaluate the spectral response and stability of the

instrument using a certified gas. A method validation procedure will be performed using a

series of spiked and un-spiked samples from the flue gas before and after each test run. To

assure that the spike system will be operating correctly, certified gases for each of the

referenced components will be used. This procedure will determine that the method will be valid

with no bias. At the end of the test a post test Calibration Transfer Standard (CTS) will agreed

within 5% of pretest CTS to validate the test data

EPA OTM METHOD 027 – PM 10


# The sample train consists of a stainless steel sample probe and liner equipped with a S-type

pitot tube and thermocouple. The probe is attached to a sample module consisting of a PM 10


# head equipped with an in-stack sizing device (cyclone) and a pre-weighed glass fiber filter for

# the collection of the particulate. The sizing device separates the particles with nominal

aerodynamic diameter of less than 10 microns. The sample module is connected to a series of

impingers to remove moisture and to capture condensible particulate. The control module

consist of a dry gas meter, calibrated orifice, leak free pump, two inclined manometers,

temperature controllers for the heated probe and a thermocouple indicator to monitor the

required temperatures during the testing.

Prior to sampling, a velocity traverse was per formed on the source to provide information to

calculate the appropriate nozzle size and sample rate based on the OTM 027 calculations.

Particulate samples are collected as follows: The sample gas is drawn through the sampling

probe isokinetically (100% + 20) at a constant rate and passed into the PM 10 

# cyclone knocking

out the particulate greater than 10 microns. The cut point for the captured particulate is

between 9.0 and 11.0 for PM 10 

# . The sample gas is then pulled through the impinger train. The

sample gas then passes through a vacuum pump followed by a dry gas meter. The dry gas

meter integrates the sample gas flow throughout the duration of the test. A calibrated orifice was

attached to the outlet of the dry gas meter provides real time flow rate data.

A pretest leak-check of the entire assembled sample system is conducted by plugging the inlet

to the probe nozzle and pulling a vacuum of at least 10 in. Hg. A leak rate less than 0.02 cfm is

determined and considered acceptable as outlined in 40 CFR 60. The pitot tube system is leak

checked at 2 to 3 inches of water column. The traverse points are marked on the probe for

easy visibility.

A representative particulate sample is acquired by sampling for prorated periods of time at the

centroid of a number of equal area regions in the exhaust stack. The sampling rate is to remain

constant at each test point maintaining an Isokinetic sampling condition for OTM Method 027. A

total of 12 traverse points were used for sampling.

The temperature controllers for the probe is set to maintain the temperature to 248 ± 25 o 

# F.

Upon achieving operating temperature of the sample train and equilibration of the probe to the

stack gas temperature, the nozzle tip is positioned toward the stack gas stream. The sample

pump is started and the flow adjusted to a suitable pressure drop over the dry gas meter in

order to sample under Isokinetic conditions. After the required time interval elapses, the probe

tip was repositioned to the next traverse point. Stack gas temperature, and sample train

measurements are taken at equal spaced intervals for each traverse point. At the conclusion of

the traverse of the first port, the pump is stopped, and the sample train is repositioned to the

subsequent sample port(s). This technique is followed for all traverse points and sample ports

throughout the entire test period.

# At the conclusion of the test run, the sample pump is turned off, and the final sample train

measurements are recorded. Once the sample head was removed, a final leak check of the

probe and sample train at the highest vacuum observed during the test was performed. The

final leak checks are determined to be within the guidelines outlined in OTM Method 027.

After the sampling is completed, the particulate recovery is performed. The particulate

recovery involves the quantitative transfer of particles in the following size range: (1) greater

than 10 micrometers. The filter is removed and placed in a storage container for shipment back

to the laboratory for analysis of the cyclone I (PM 10 

# ) cup, cyclone I internal surfaces, and the

internal surface of the nozzle were rinsed with acetone and placed in a storage container for the

analysis of equal to and greater than PM 10 

# . The rinses of the cyclone I turnaround cup, the

inside of the downcomer line, and the interior surfaces of the cyclone IV were rinsed with

acetone and placed in a storage container for the analysis of less than PM 10 

# and greater than

PM 2.5 

# . The exit tube of cyclone IV and the front half of the filter holder were rinsed with acetone

for the analysis of total PM. The 100 ml blank acetone, distilled in glass grade, sample is also

taken and stored in a marked container. The samples will be transferred back to the laboratory

where they are logged in and analyzed. Test date, sample identification, and the laboratory

performing the analyses will be all identified on the chain of custody worksheet.

ALTERNATE METHOD 028 (CONDENS ABLE PM - DRY IMPINGER)

The sampling and analytical procedures for collection of condensable emissions will be

conducted in accordance with Other Test Method 028. The sampling equipment will consist of

the following equipment and components of the impinger train - the module contains a Method

23 type stack gas condenser to cool the stack ga s to less than 30°C (85°F) followed by two dry

impingers in an insulated box with water at ≤ 30°C ( ≤ 85°F) then a CPM filter and finally a

moisture trap system. The first impinger is a drop out with a short stem and the second

impinger is a modified Greenburg Smith impinger with no .taper. The connection between the

CPM filter and the moisture trap impinger includes a thermocouple fitting that provides a leakfree seal between the thermocouple and the stack gas. The moisture trap consisted of one

modified Greenburg-Smith impinger containing 100 mL of water, followed by an impinger

containing approximately 200-300 grams of silica gel.

All sampling train glassware will be cleaned before mobilization to the facility with soap and

water, and rinsed using tap water, deionized water, acetone, and finally, MeCl2. After cleaning,

the glassware is baked at 300°C for 6 hours. Prior to each sampling run the train glassware

used to collect condensable particulate matter will be rinsed thoroughly with deionized, distilled

ultra-filtered water that conformed to ASTM D1193-06, Type 1.

# Prior to conducting the test series, a field train blank was recovered by assembling the sample

train as it will be used for testing. 100 mL of water is added to the first impinger and the sample

train will be purged with filtered nitrogen for one hour. The field train blank samples will be

recovered and used to determine the blank correction or sample weight will be subtracted from

the condensable particulate mass determined with each run. This blank train value will be no

greater than 0.002 g (2.0 mg). Reagent blanks will be taken of the water, acetone, and

Methylene chloride used for field recovery and samples are prior to mobilization to the facility.

The condensable sample train will be prepared in the following manner: 1) no water in the first

and second impingers; 2)a filter placed in the CPM f ilter holder, 3) the third impinger will contain

100ml of water; and, 4) approximately 200 g of silica gel (indicating type, 6-16 Mesh) will be

added to the fourth impinger. The dropout and the second impinger are place in an insulated

box with water at ≤ 30°C ( ≤ 85°F). The CPM filter holder is attached to the second impinger and

the first impinger in the moisture trap section. The connection between the CPM filter and the

moisture trap impinger includes a thermocouple fitting that provides a leak-free seal between

the thermocouple and the stack gas. The condenser will be connected to the dropout impinger

and the exit of the Method 5 sample train. The submersible pump is tu rned on to deliver cool

water from the ice bath to the condenser. The moisture trap section is contained in a ice bath

with the exit temperature from the silica gel monitored during the test. A pretest leak-check of

the entire assembled sample system is conducted by plugging the inlet to the probe nozzle and

pulling a vacuum of at least 10 in. Hg. A leak rate less than 0.02 cfm was determined and

considered acceptable.

At the conclusion of the test run, the sample pump is turned off, and the final samples train

measurements will be recorded (see Method 5). A final leak check of the test train will be

performed at the conclusion of every test run as previously described at the highest vacuum

encountered during the sampling period. At the conclusion of the sample train leak check, the

particulate will be recovered as described in Method 5 and the condensable particulate section

of the sample train will be transferred to the cleanup area.

The first impinger (dropout) will be inspected to determine if any water is present. The dropout

stem is removed and replaced with a non-tapered modified Greenburg Smith stem. The

condensable system is connected to a filtered nitrogen tank and nitrogen is allowed to flow

through the system at a rate of 20 l/min for a period of one hour. The gas temperature exiting

the CPM filter is monitored and did not exceed 85°F.

After the purge of each impinger it is weighed to within + 1ml or + 0.5 g and recorded. The

flowing procedure is used to recover the liquids and filter in the condensable sample train.

Container No. 1 (glass bottle) is quantitatively transfer the liquid from the dropout and impinger

# prior to the CPM filter into a clean sample bottle. Rinse the condenser, each impinger, the

connecting glassware, and the front half of the CPM filter housing twice with Type I water. Mark

the liquid level on the bottle. Container No. 2 (glass bottle) follows the water rinses of the

condenser, each impinger, all of the connecting glassware, and the front half of the CPM filter

with an acetone rinse. Then repeat the entire procedure with two rinses of MeCL2, and save

both solvents in a separate glass container. Mark the liquid level on the jar. Container No. 3

contains the filter from the filter holder and placed in its identified petri dish using a pair of

cleaned tweezers to handle the filter. Seal the container.

The samples are transferred back to the laboratory where they are logged in and analyzed. Test

date, sample identification, and the laboratory performing the analyses were all identified on the

chain of custody worksheet.

# QA / QC Procedures

Specific quality assurance / quality control procedures will be adhered to during this test project

to provide valid and scientifical ly defensible data. For any environmental field and laboratory

measurement, a degree of uncertainty exists in the data due to inherent limitations of the

measurement systems employed. The objective of a QA/QC program is to produce data of

known precision, accuracy, representation, completeness and comparability. The objective in

this test project is to determine compliance wi th applicable air permit requirements. The final

data user in this project will be EPA.

The following section details all QC procedures to be followed during the sampling.

Velocity / Volumetric Flow Rate - Methods 1 & 2

Volumetric flow rates will be determined during each isokinetic test run. The following QC steps

will be adhered to during these tests:

• Reported duct dimensions will be checked by physical measurements to determine crosssectional duct area.

• Pitot tube coefficients are determined based on physical measurement techniques as

delineated in Method 2 before and after each test.

• The Type-S Pitot tubes are visually inspected before and after sampling.

• The Pitot tube is installed on the sampling probe with the proper orientation and spacing

from the sampling nozzle.

• Before each series of tests, thermocouple reading temperature are checked against an

N.I.S.T. traceable thermometer.

• The oil manometer is leveled and zeroed before each test run.

• Both legs of the Pitot tube are leak-checked before and after sampling.

• Proper orientation of the Pitot tube is maintained while making measurements. The roll and

pitch axis of the Pitot tube is maintained at 90 0 

# to the flow.

• An average velocity pressure reading is recorded at each point instead of recording

extreme high or low values.

• The pitot/manometer umbilical lines are inspected before and after sampling for moisture

condensate. Lines are cleared if moisture is found.

Oxygen and Carbon Dioxide Determination - Method 3A

The carbon dioxide and oxygen concentrations are determined using EPA Reference Method

3A. A sample of the flue gas is extracted from the gas stream during each test. Moisture is

removed form the gas sample and is analyzed on a dry basis with an instrumental gas analyzer.

The following QC steps are adhered to during these tests:

• Only analyzers that have a resolution or sensitivity of at least < 2.0% of full-scale range are

used.

# • Upon the O 2 

# and CO 2 

# analyzers initial use in the field, an interference check is conducted.

• The reference calibration gases used in this test program are certified following EPA

Protocol Number 1 analysis. Copies of the calibration gas certifications will be included in

the instrument calibration section.

• The high level gas is equal to the calibration span gas.

• The mid level gas is between 40 and 60 % of the calibration span gas.

• The low level gas is < 20% of the calibration span gas.

• In accordance with EPA Method 3A a three-point (i.e., zero, mid-, and high-range) analyzer

calibration error is conducted on each reference analyzer prior to initiating the compliance

testing. These checks are conducted (after final calibration adjustments are made) by

injecting the calibration gases directly into each gas analyzer and the responses are

recorded.

• The analyzer calibration error will be less than + 2.0% or + 0.5 ppm of the calibration span

gas for the zero, mid-range, and high-range calibration gases.

• The probe material is made of stainless steel.

• The probe, filter and sample line temperature is maintained above the dew point by heating,

prior to sample conditioning.

• The sampling system bias will be less than + 5.0 % or of the calibration span gas for the

zero and upscale calibration gases (+ 0.5 ppm absolute difference).

• The system response time is calculated during the initial sampling system bias.

• The drift for either the low-level and mid-level or high-level gases will be less than + 3.0% or

of the calibration span gas (+ 0.5 ppm absolute difference).

• The sampling system will be purged > 2 times the system response time before each test

run.

• Sample flow rate will be maintained within 10% during the entire test period.

• Data will be recorded at 1-minute intervals.

• All data collected will be within the calibration span gas.

Moisture Determination - Method 4

Stack gas moisture content (B

ws 

# ) is determined by dividing the mass of moisture collected by the

impingers or stainless steel condenser and silica gel impinger by the standardized volume of

gas sampled. The following QC steps are adhered to during these tests:

• The indicating silica gel is fresh for the first run and periodically inspected and replaced

between runs, as needed.

• The analytical balance is placed in a clean, motionless environment for weighing and

standard weights will be used as reference.

• The balance is leveled and zeroed if necessary before each weighing.

• Preliminary silica gel impinger tare weights and post-run weights weighed to the nearest 0.1

g.

# • Before each series of tests, thermocouple readings for the silica gel impinger exit

temperature are checked against an N.I.S.T. traceable thermometer.

• The silica gel impinger gas temperature is maintained below 68 0 

# F and recorded at every

traverse point.

• Each impinger is wiped of surface moisture before post-run weighing.

• The volume of liquid captured is measured using a graduated cylinder with 1-milliliter

increments or gravimetrically.

FT-IR Sampling - Method 321

• Before and after each run a spike and recovery procedure will be performed as outlined by

EPA method 321. The system biases calculat ed from the pre- and post-test dynamic

analyte spiking will be within the +/- thirty percent limit as allowed by EPA Method 321.

• The spike/tracer gas mixture will be introduced at a constant flow (± 2 percent) rate at less

than 10 percent of the total sample flow.

• The spike will be pre-heated before introduction into the sample matrix to prevent a

localized condensation of the gas stream at the spike introduction point. A heated sample

line containing multiple transport tubes within the heated bundle will be used to spike gas

up through the sampling system to the spike introduction point.

• A calibrated flow device (e.g., mass flow meter/controller), will be used to monitor the spike

flow as indicated by a calibrated flow meter or controller, or alternately, the SF 6 

# tracer ratio

may be calculated from the direct measurement and the diluted measurement.

• A direct-to-cell measurement of the dry, undiluted spike gas will be performed (CTS Scan),

before each test run. The spike gas will be introduced directly to the FTIR cell, through the

sampling system. The cell will be filled to 1 atmosphere and collected the spectrum of the

sample. The spike gas will be equilibrated to the temperature of the measurement cell

before acquisition of the spectra. The spectrum will be inspected and verified that the gas

is dry and contained negligible CO 2



# . • The process will be repeated to obtain a second measurement after each test run. Analysis

of spectral band areas for the target com pounds from these duplicate measurements will

agreed to within ± 5 percent of the mean.

PM 10 

# Sampling – OTM 027 and OTM 028

Accurate fine and coarse particulate concentrations are dependent on the recovery of the

material from the cyclone and collection of the condensible pollutants from the stack gas by the

use of a series of impingers and the standardized gas sample volume measured. QC

procedures that were followed so that representative particulate data will be collected by the

sampling system are:

• Only clean, well-maintained sampling equipment will be used.

# • Sampling ports will be inspected and cleaned prior to sampling.

• The cyclone will meet the design specification of OTM 027.

• The sampling train components exposed to sample gas will be constructed of glass or

Teflon for the filterable and condensible material.

• All glass components of the train will be all cleaned with soap and water, rinsed with water,

acetone and finally with Methylene chloride.

• All silicone grease will be removed from the impingers during the initial cleaning of the

glassware and not used during this test.

• All equipment will be calibrated according to EPA standards. The dry gas meter will be fully

calibrated within the past 12 months using a set of calibrated orifices.

• Accurate barometric pressure will be recorded at least once per day.

• The dry gas meter thermocouples will be compared to ambient temperature prior to the test

run as a check on operation.

• Pretest and post-test leak-checks will be completed (must be less than 0.02 cfm or 4% of

the average sampling rate).

• Before each series of tests, thermocouple readings for meter temperature, probe, and filter

exit temperatures will be checked against an N.I.S.T. traceable thermometer.

• Readings of the dry gas meter, meter orifice pressure ( Δ H), meter temperatures, and probe

temperatures will be taken at every traverse point.

• The sampling velocity through the nozzle will be maintained within 20% of the stack gas

velocity (isokinetic sampling rate at 100±20%).

• The calculated D 50 

# of Cyclone I will be between 9.0 and 11.0 μ m.

• No more than one point will be outside Δ p min 

# and Δ p max 

# . • The indicating silica gel will be fresh for the first run and periodically inspected and replaced

during runs, if needed.

• All nozzle/probe recovery items will be pre-cleaned and kept in containers when not being

used.

• Filter recovery used tweezers to handle the filter, and will be careful to include any filter

fibers or pieces adhering to the filter holder.

• The nozzle and cyclone recovery will include wiping the outer surface clean of dust before

sample recovery. Sample recovery will consist of multiple brushing of the inner surface

during the recovery operations. Transfer of rinse acetone to the sample container will be

accomplished without loss of liquid. Nozzle and probe brushes will be rinsed after brushing

inner surfaces.

• The analytical balance will be placed in a clean, motionless environment for weighing.

• The balance will be leveled and zeroed if necessary before each weighing.

• Analytical balances will be metrological tested against NIST traceable standard weights

annually by a third party.

• Each analytical balance will be calibrated before weighing begins.

# • Before weighing filters or beakers the analytical balance will be challenged with a known

standard mass (500 mg for filters and 100 g for beakers) to verify the balance calibration is

still valid.

• Preliminary silica gel impinger tare weights and post-run weights were weighed to the

nearest 0.1 g.

• The dry impinger system gas temperature will be maintained below 85 0 

# F and recorded at

every traverse point.

• The silica gel impinger gas temperature will be maintained below 68 0 

# F and recorded at

every traverse point.

• Each impinger will be wiped of surface moisture before post-run weighing.

• The volume of liquid captured will be measured using a graduated cylinder with 1-milliliter

increments.

• The capture liquid in the first three impingers will be recovered and place into a container

for analysis (inorganic).

• Each impinger and connecting glassware will be rinsed three times with Methylene chloride

and placed into a separate container for analysis (organic).

• Liquid levels will be marked on sample containers and sealed for shipment to the

laboratory.

• Class A volumetric glassware for titrations will be used.

• Prior to the initial run a y-factor check will be performed to ensure that the meter will be

operating according to the original calibration to within 3% of the original y-factor.

• For the post-test calibration the alternative Method 5 post-test calibration procedure will be

used (Emission Measurement Center A pproved Alternative Method ALT-009).

# NOMENCLATURE

A
s 

# Cross-sectional area of stack, square feet

A

n 

# Cross-sectional area of nozzle, square feet ACFM Actual cubic feet of gas per minute at stack conditions

B
ws 

# Proportion by volume of water vapor in gas stream

C

s 

# Particulate concentration in stack gas, gr/dscf

C

a 

# Particulate concentration in stack gas, gr/acf

C p 

# Pitot tube coefficient

∆ H Pressure drop across orifice meter, inches water

∆ P Velocity head of stack gas, inches water dscf Cubic feet of dry gas corrected to standard conditions

EA Excess Air E/Btu Particulate Emission Rate, pounds/mmBtu F F-factor, 9640 dscf/MMBTU's of heat input

K p 

# Constant (85.49)

M

n 

# Total particulate matter collected, mg

M d 

# Molecular weight of stack gas; dry basis, lb/lb-mole

M
s 

# Molecular weight of stack gas; wet basis, lb/lb-mole I Percent of isokinetic sampling

P bar 

# Barometric pressure, inches mercury

P g 

# Stack static pressure, inches of water

P

m 

# Barometric pressure of dry gas meter, in. mercury PMR Particulate mass rate, pounds/hour

P
s 

# Absolute stack gas pressure, inches mercury

P std 

# Barometric pressure, standard conditions, 29.92 inches Hg
Q

a 

# Volumetric flow rate, actual conditions, ACF/min

Q

s 

# Volumetric flow rate, standard conditions, scf/min

Q std 

# Volumetric flow rate, dry standard conditions, dscf/min

TB
ws 

# Theoretical water vapor in the gas str eam based on saturated stack conditions, proportion by volume (dimensionless)

TV lc 

# Theoretical volume of water collected based on saturated stack conditions, ml

TV wstd 

# Theoretical volume of water vapor in the gas sample based on saturated stack conditions, corrected to standard temperature and pressure, scf

T

m 

# Absolute average dry gas meter temperature, degree R (460)

T
s 

# Absolute average stack gas temperature, degree R (460)

T std 

# Absolute temperature at standard conditions, 528 R

Ө Total sampling time, minutes

V lc 

# Total volume collected in impingers and silica gel, gr

V

m 

# Volume of gas sampled through gas meter, cubic feet

V

n 

# Volume collected at stack conditions through nozzle, ACF

V
ma 

# Stack gas volume sampled, ACF

V mstd 

# Volume of gas sampled through gas meter, cubic feet

V
s 

# Average stack gas velocity, feet/sec

V wcstd 

# Volume of water vapor in gas sampled from impingers, standard cubic feet

V wsgstd 

# Volume of water vapor in gas sampled from silica gel, standard cubic feet

W imp 

# Total volume collected in impingers, gr

W sg 

# Total volume collected in silica gel, gr Y Dry gas meter calibration factor

# TEST CALCULATIONS

EQUATIONS

1. P

s 

# = P bar 

# + (P g 

# /13.6) = ( ) + ( /13.6) =

2. P

m 

# = P bar 

# + ( Δ H/13.6) = ( ) + ( /13.6) =

3. V mstd 

# = 17.64 * V

m 

# * Y * (P

m 

# /T

m 

# ) = 17.64*( )*( )*( / ) =

4a. V wc(std) 

# = 0.04706 * W imp 

# = 0.04706*( ) =

4b. V wsg(std) 

# = 0.04715 * W sg 

# = 0.04715*( ) =

5. B
ws 

# = V wstd 

# /(V mstd 

# + V wstd 

# ) = ( )/( + ) =



# For saturated sources (No. 6 - 8 only):

6. TB

ws 

# = (10 6.37- {2827/(ts+365)} 

# / P

s 

# = 10 6.37- { 2827/( +364.8) } 

# / ( ) =

7. TV wstd 

# = V mstd 

# *( TB

ws 

# /1- TB

ws 

# ) = ( )*( )/( 1 - ) =

8. TV lc 

# = TV wstd 

# /0.04707 = ( ) / ( ) =

9. M d 

# = 0.44(%CO 2 

# ) + 0.32(%O 2 

# ) + 0.28((100-(%CO 2 

# + %O 2 

# )) = 0.44( ) + 0.32( ) + 0.28[100-( + )] =

10. M

s 

# = M d 

# (1- B

ws 

# ) + 18 B

ws 

# = ( )*(1- )+18( ) =

11. V

s 

# = 85.49 * C p 

# * √∆ P * √ [ T
s 

# / (M

s 

# * P

s 

# ) ] = 85.49*(0.84)*( )* √ [ ( /( )( )) ] =

12. Q

a 

# = V
s 

# * A

s 

# * 60 = ( )( )(60) =

13. Q

s 

# = Q

a 

# * (528/T

s 

# )*(P

s 

# /29.92) = ( )*(528/ )*( /29.92) =

14. Q std 

# = Q

a 

# (1- B

ws 

# ) * (528/T

s 

# )*(P

s 

# /29.92) = ( )(1- )*(528/ )*( /29.92) =

15. C

s 

# = 0.01543* (M

n 

# / V mstd 

# ) = 0.01543*( / ) =

17. E/Btu = (C

s 

# /7000)*{(F d 

# *20.9)/(20.9-%O 2 

# )} = ( /7000)*{( )*20.9)/(20.9-( )} =

18. %EA = 100%* { (%O 2 

# ) - 0.5*(%CO) } / { 0.264(%N 2 

# ) - (%O 2 

# ) + 0.5*(%CO) }

= 100%* { ( )-0.5( ) } / { 0.264( )-( )+0.5( ) } =

21. PMR = C

s 

# * Q std 

# (60/7000) = ( )*( )*(60/7000) =

22. V

n 

# = T
s 

# /P

s 

# *{(0.002669) V lc 

# + (V

m 

# * Y * P

m 

# )/T

m 

# )} = ( / )*{(0.002669)( )+( )( )( )/( )} =

23. C

a 

# = 0.01543* (M

n 

# / V

n 

# ) = 0.01543*( / ) =

24. I = V

n 

# 100/(60* Ө *V

s 

# *A

n 

# ) = ( )100 / (60)( )( )( ) =

# 17 

# NOMENCLATURE FOR OXYGEN/CARBON DIOXIDE (3A)

ACE = Analyzer calibration error, percent of calibration span.

C Avg 

# = Average unadjusted gas concentration indicated by recorder for the test run, ppmv.

C Dir 

# = Measured concentration of a calibration gas (low, med, high) when introduced in

direct calibration mode, ppmv.

C Gas 

# = Average effluent gas concentration adjusted for bias, ppmv.

C O 

# = Average of initial and final system ca libration bias(or 2-point system calibration

error) check responses form the low level (zero) calibration gas, ppmv.

C M 

# = Average of initial and final system ca libration bias (or 2-point system calibration

error) check responses for the upscale calibration gas, ppmv.

C MA 

# = Actual concentration of the upscale calibration gas, ppmv.

C S 

# = Measured concentration of a calibration gas (low, mid, or high) when introduced in

system calibration mode, ppmv.

C

v 

# = Manufactured certified concentration of a calibration gas (low, mid, or high), ppmv.

CS = Calibration span, ppmv.

D = Drift assessment, percent of calibration span.

SB = System bias, percent of calibration span.

SB final 

# = Post-run system calibration error, percent of calibration span.

SB i 

# = Pre-run system bias, percent calibration span.



# EQUATIONS FOR O 2 

# /CO 2 

# (Method 3A)

ACE = C Dir 

# - C
v X 

# 100 (7E-1) CS

= ( - ) / ( ) X 100 =

SB = C S 

# - C Dir X 

# 100 (7E-2) CS

= ( - ) / ( ) X 100 =

D = | SB final 

# - SB i 

# | = | - | = (7E-4)

C Gas 

# = ( C Avg 

# - C O 

# ) x C MA 

# / (C M 

# - C O 

# ) (7E-5) ( - ) x ( ) / ( - ) =

# 18 

# NOMENCLATURE FOR FT-IR SPIKE

C
e 

# = Expected concentration of analyte, ppm

S
m 

# = Mean concentration of spiked analyte, ppm

S
u 

# = Native concentration analyte, ppm

DF = Dilution Factor (Target < 10%), %

C
s 

# = Cylinder value of spiked or tracer gas



# EQUATIONS FOR SPIKE

C

e 

# = DF x C

s 

# + S

u 

# (1-DF)
= ( ) x ( ) + {( )[1- ( )]} =

Recovery % = S

m 

# - S

u 

# (1-DF)

DF x C

s



# = ( ) – {( )[1- ( )]} ( ) x ( )Worksheet Title: HCl Emission Test Results Template Using Method 321
Who Should Complete this Spreadsheet?

Company Name: Facility Name: Leeds Cement Plant

Address: 8401 Second Ave City: Leeds

State: Alabama

Kiln ID: Kiln Type: The kiln is PH

In-line Raw Mill:

Control Device Configuration:

Parameter Sample #1

Sample #2

Sample #3

Test Average Units Units Other Description Test Method Used Test Location Note

Select appropriate unit

from list. If other is
selected please describe
units in column H at right. Enter the name of the Test Method used. Indicate whether the test
occurred upstream or

downstream of a control
device(s); list the control
device(s) If kiln has an in-line raw mill,
indicate raw mill status during tests
(i.e., raw mill on or raw mill off).
Provide any other information
supporting information you think is
necessary about this test report.
Sample Date (mm/dd/yyyy) 3/17/2010 3/17/2010 3/17/2010
HCl Concentration - as measured - dry basis 4.89 2.68 2.48 ppmvd

Oxygen Concentration - dry basis 13.46 13.36 13.36 %
CO2 Concentration - dry basis 13 13 13 %
HCl Concentration - corrected to 7% oxygen 9.14 4.94 4.57 6.22 ppmvd @ 7% O2 EPA Method 321 Downstream; Baghouse Mill On

Exhaust Stream %Moisture 10.89 10.04 10.47 %

Exhaust Flowrate 168,464 160,774 165,693 DSCFM Exhaust Temperature 204.3 198.4 203.6 Degrees F

Sample Date (mm/dd/yyyy) 3/18/2010 3/18/2010 3/18/2010
HCl Concentration - as measured - dry basis 4.36 2.41 2.22 ppmvd

Oxygen Concentration - dry basis 9.6 10.45 10.69 %
CO2 Concentration - dry basis 21 16 17 %

HCl Concentration 20.09 24.16 27.81 24.02 ppmvd @ 7% O2 EPA Method 321 Downstream; Baghouse Mill Off

Exhaust Stream %Moisture 13.40 13.91 13.93 %

Exhaust Flowrate 101,345 116,196 118,188 DSCFM Exhaust Temperature 292.6 300.9 302.3 Degrees F

Notes: Facilities that use Method 321 to test for HCl

Lehigh Cement Company

Baghouse

Enter HCl concentration value in dry
parts per million volume (ppmvd). If

the test results are below detection
limit, please note the detection limit

in brackets
(e.g., [< 0.010]).

Peach shaded cells indicate areas where the user will enter a response Yes Rotary Kiln



### Enclosure 5c--ERT Spreadsheet Page 1 of 1Date Time SpectrumFileLibraryFile Water vapoUnit3/18/2010 12:45:35 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Zero Run 1 Before_02721.SPE BoilerMAct 0 vol-%3/18/2010 12:45:41 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Zero Run 1 Before_02722.SPE BoilerMAct 0 vol-%3/18/2010 12:45:47 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Zero Run 1 Before_02723.SPE BoilerMAct 0 vol-%3/18/2010 12:45:53 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Zero Run 1 Before_02724.SPE BoilerMAct 0 vol-%3/18/2010 12:45:58 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Zero Run 1 Before_02725.SPE BoilerMAct 0 vol-%3/18/2010 12:46:04 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Zero Run 1 Before_02726.SPE BoilerMAct 0 vol-%3/18/2010 12:46:10 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Zero Run 1 Before_02727.SPE BoilerMAct 0.02 vol-%CompensaResidual HydrogencUnit CompensaResidual SF6 Unit CompensaResidualwet 0.0005 0.1 ppm wet 0.0007 0 ppm wet 0.001wet 0.0007 0 ppm wet 0.0008 0 ppm wet 0.0007wet 0.0004 0 ppm wet 0.0007 0 ppm wet 0.0008wet 0.0005 0.1 ppm wet 0.0007 0 ppm wet 0.0011wet 0.0008 0 ppm wet 0.0006 0.01 ppm wet 0.0004wet 0.0005 0 ppm wet 0.0005 0 ppm wet 0.0011wet 0.0006 0.07 ppm wet 0.0007 0 ppm wet 0.001Date Time SpectrumFileWater vapoUnit Compensa3/18/2010 8:55:04 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00560.SPE 0.03 vol-% wet3/18/2010 8:55:55 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00561.SPE 0.07 vol-% wet3/18/2010 8:56:01 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00562.SPE 0.08 vol-% wet3/18/2010 8:56:07 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00563.SPE 0.08 vol-% wet3/18/2010 8:56:13 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00564.SPE 0.09 vol-% wet3/18/2010 8:56:19 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00565.SPE 0.1 vol-% wet3/18/2010 8:56:25 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00566.SPE 0.1 vol-% wet3/18/2010 8:56:31 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00567.SPE 0.11 vol-% wet3/18/2010 8:56:37 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00568.SPE 0.12 vol-% wet3/18/2010 8:56:43 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00569.SPE 0.13 vol-% wet3/18/2010 8:56:49 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00570.SPE 0.14 vol-% wet3/18/2010 8:56:55 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00571.SPE 0.15 vol-% wet3/18/2010 8:57:01 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00572.SPE 0.55 vol-% wet3/18/2010 8:57:07 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00573.SPE 0.77 vol-% wet3/18/2010 8:57:13 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00574.SPE 0.37 vol-% wet3/18/2010 8:57:18 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00575.SPE 0.03 vol-% wet3/18/2010 8:57:24 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00576.SPE 0.01 vol-% wet3/18/2010 8:57:30 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00577.SPE 0 vol-% wet3/18/2010 8:57:36 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00578.SPE 0 vol-% wet3/18/2010 8:57:42 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00579.SPE 0 vol-% wet3/18/2010 8:57:48 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00580.SPE 0.01 vol-% wet3/18/2010 8:57:54 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00581.SPE 0 vol-% wet3/18/2010 8:58:00 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00582.SPE 0 vol-% wet3/18/2010 8:58:06 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00583.SPE 0 vol-% wet3/18/2010 8:58:12 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00584.SPE 0.01 vol-% wet3/18/2010 8:58:18 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00585.SPE 0 vol-% wet3/18/2010 8:58:24 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00586.SPE 0 vol-% wet3/18/2010 8:58:30 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00587.SPE 0 vol-% wet3/18/2010 8:58:36 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00588.SPE 0 vol-% wet3/18/2010 8:58:42 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00589.SPE 0 vol-% wet3/18/2010 8:58:48 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00590.SPE 0 vol-% wet3/18/2010 8:58:54 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00591.SPE 0 vol-% wet3/18/2010 9:02:13 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00592.SPE 0 vol-% wet3/18/2010 9:02:19 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00593.SPE 0 vol-% wet3/18/2010 9:02:25 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00594.SPE 0 vol-% wet3/18/2010 9:03:43 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00595.SPE 0 vol-% wet3/18/2010 9:03:49 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00596.SPE 0 vol-% wet3/18/2010 9:03:55 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00597.SPE 0 vol-% wet3/18/2010 9:04:01 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00598.SPE 0 vol-% wet3/18/2010 9:04:07 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00599.SPE 0 vol-% wet3/18/2010 9:04:13 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00600.SPE 0 vol-% wet3/18/2010 9:04:19 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00601.SPE 0 vol-% wet3/18/2010 9:04:25 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00602.SPE 0 vol-% wet3/18/2010 9:04:57 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00603.SPE 0 vol-% wet3/18/2010 9:05:03 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00604.SPE 0 vol-% wet3/18/2010 9:05:09 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00605.SPE 0 vol-% wet3/18/2010 9:05:15 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00606.SPE 0 vol-% wet3/18/2010 9:05:21 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00607.SPE 0 vol-% wet3/18/2010 9:05:27 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00608.SPE 0 vol-% wet3/18/2010 9:05:33 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00609.SPE 0 vol-% wet3/18/2010 9:05:39 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00610.SPE 0 vol-% wet3/18/2010 9:05:45 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00611.SPE 0 vol-% wet3/18/2010 9:05:51 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00612.SPE 0 vol-% wet3/18/2010 9:05:57 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00613.SPE 0 vol-% wet3/18/2010 9:06:03 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00614.SPE 0 vol-% wet3/18/2010 9:06:09 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00615.SPE 0 vol-% wet3/18/2010 9:06:15 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00616.SPE 0 vol-% wet3/18/2010 9:06:21 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00617.SPE 0 vol-% wet3/18/2010 9:06:27 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00618.SPE 0 vol-% wet3/18/2010 9:06:33 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00619.SPE 0 vol-% wet3/18/2010 9:06:39 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00620.SPE 0 vol-% wet3/18/2010 9:06:45 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00621.SPE 0 vol-% wet3/18/2010 9:06:51 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00622.SPE 0 vol-% wet3/18/2010 9:06:57 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00623.SPE 0 vol-% wet3/18/2010 9:07:03 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00624.SPE 0 vol-% wet3/18/2010 9:07:09 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00625.SPE 0 vol-% wet3/18/2010 9:07:14 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00626.SPE 0 vol-% wet3/18/2010 9:07:20 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00627.SPE 0 vol-% wet3/18/2010 9:07:58 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00628.SPE 0 vol-% wet3/18/2010 9:08:04 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00629.SPE 0 vol-% wet3/18/2010 9:08:10 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00630.SPE 0 vol-% wet3/18/2010 9:08:16 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00631.SPE 0 vol-% wet3/18/2010 9:08:22 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00632.SPE 0 vol-% wet3/18/2010 9:08:28 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00633.SPE 0 vol-% wet3/18/2010 9:08:34 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00634.SPE 0 vol-% wet3/18/2010 9:08:40 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00635.SPE 0 vol-% wet3/18/2010 9:08:46 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00636.SPE 0 vol-% wet3/18/2010 9:08:52 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00637.SPE 0 vol-% wet3/18/2010 9:08:58 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00638.SPE 0 vol-% wet3/18/2010 9:09:04 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00639.SPE 0 vol-% wet3/18/2010 9:09:10 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00640.SPE 0 vol-% wet3/18/2010 9:09:16 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00641.SPE 0 vol-% wet3/18/2010 9:09:22 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00642.SPE 0 vol-% wet3/18/2010 9:09:28 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00643.SPE 0 vol-% wet3/18/2010 9:09:34 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00644.SPE 0 vol-% wet3/18/2010 9:09:40 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00645.SPE 0 vol-% wet3/18/2010 9:09:45 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00646.SPE 0 vol-% wet3/18/2010 9:09:51 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00647.SPE 0 vol-% wet3/18/2010 9:09:57 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00648.SPE 0 vol-% wet3/18/2010 9:10:03 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00649.SPE 0 vol-% wet3/18/2010 9:10:09 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00650.SPE 0 vol-% wet3/18/2010 9:10:15 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00651.SPE 0 vol-% wet3/18/2010 9:10:21 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00652.SPE 0 vol-% wet3/18/2010 9:10:27 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00653.SPE 0 vol-% wet3/18/2010 9:10:33 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00654.SPE 0 vol-% wet3/18/2010 9:10:39 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00655.SPE 0 vol-% wet3/18/2010 9:10:45 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00656.SPE 0 vol-% wet3/18/2010 9:10:51 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00657.SPE 0 vol-% wet3/18/2010 9:10:57 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00658.SPE 0 vol-% wetAveragesResidual HydrogencUnit CompensaResidual SF6 Unit CompensaResidual0.0003 0.43 ppm wet 0.0003 0 ppm wet 0.00060.0005 0.77 ppm wet 0.0006 0 ppm wet 0.00060.0005 1.14 ppm wet 0.0007 0.01 ppm wet 0.00050.0005 0.53 ppm wet 0.0007 0.02 ppm wet 0.00090.0007 0.41 ppm wet 0.0008 0.01 ppm wet 0.00060.0008 1.3 ppm wet 0.0008 0.01 ppm wet 0.00090.0008 1.16 ppm wet 0.0009 0 ppm wet 0.0010.0008 0.91 ppm wet 0.0007 0 ppm wet 0.00080.0008 0.91 ppm wet 0.001 0 ppm wet 0.00080.001 1.16 ppm wet 0.0013 0 ppm wet 0.00120.0012 1.21 ppm wet 0.0012 0 ppm wet 0.00080.0013 0.85 ppm wet 0.0012 0.02 ppm wet 0.00070.0046 3.39 ppm wet 0.0036 0.02 ppm wet 0.00120.0058 4.33 ppm wet 0.004 0 ppm wet 0.0020.0044 55.04 ppm wet 0.005 0.08 ppm wet 0.00690.0004 102.9 ppm wet 0.002 0.01 ppm wet 0.00130.0002 101.53 ppm wet 0.002 0 ppm wet 0.0020.0054 104.09 ppm wet 0.0021 0 ppm wet 0.00230.0031 107.86 ppm wet 0.0022 0 ppm wet 0.00170.0002 110.53 ppm wet 0.002 0.05 ppm wet 0.00230.0002 112.68 ppm wet 0.0023 0 ppm wet 0.00150.0024 115.08 ppm wet 0.0023 0 ppm wet 0.00150.0012 115.74 ppm wet 0.0023 0 ppm wet 0.00220.005 117 ppm wet 0.0024 0 ppm wet 0.00210.0002 118.22 ppm wet 0.0024 0 ppm wet 0.00130.0004 119.15 ppm wet 0.0023 0 ppm wet 0.00320.0063 119.78 ppm wet 0.0024 0 ppm wet 0.00380.0022 120.35 ppm wet 0.0025 0.01 ppm wet 0.00160.0038 121.77 ppm wet 0.0023 0 ppm wet 0.00230.0018 122.21 ppm wet 0.0024 0 ppm wet 0.00240.0074 122.24 ppm wet 0.0025 0 ppm wet 0.00170.001 121.99 ppm wet 0.0026 0 ppm wet 0.0020.0003 151.62 ppm wet 0.0006 0 ppm wet 0.00150.0005 151.87 ppm wet 0.0008 0 ppm wet 0.00120.0003 151.71 ppm wet 0.0007 0 ppm wet 0.00180.0003 146.03 ppm wet 0.0007 0 ppm wet 0.00190.0005 146.06 ppm wet 0.0006 0.03 ppm wet 0.00240.0007 145.14 ppm wet 0.0006 0.01 ppm wet 0.00260.0005 146.4 ppm wet 0.0007 0.02 ppm wet 0.00240.0006 145.96 ppm wet 0.0006 0.02 ppm wet 0.00240.0007 145.73 ppm wet 0.0007 0 ppm wet 0.00130.0002 145.35 ppm wet 0.0006 0.02 ppm wet 0.00290.0006 146.4 ppm wet 0.0008 0 ppm wet 0.00290.0004 144.2 ppm wet 0.0005 0.01 ppm wet 0.00160.0006 143.22 ppm wet 0.0007 0 ppm wet 0.00190.0006 143.96 ppm wet 0.0005 0 ppm wet 0.00260.0006 143.54 ppm wet 0.0008 0 ppm wet 0.00090.0006 143.95 ppm wet 0.0006 0 ppm wet 0.00140.0003 144.41 ppm wet 0.0006 0 ppm wet 0.00130.0006 144.36 ppm wet 0.0004 0 ppm wet 0.00120.0006 143.9 ppm wet 0.0007 0.01 ppm wet 0.00180.0005 144.18 ppm wet 0.0007 0 ppm wet 0.00180.0005 144.49 ppm wet 0.0009 0.02 ppm wet 0.00220.0005 143.92 ppm wet 0.0007 0 ppm wet 0.00180.0004 143.97 ppm wet 0.0007 0 ppm wet 0.00150.0003 143.96 ppm wet 0.0005 0.01 ppm wet 0.00160.0006 144.49 ppm wet 0.0008 0.01 ppm wet 0.0020.0006 144.19 ppm wet 0.0007 0 ppm wet 0.00150.0004 145 ppm wet 0.0006 0.02 ppm wet 0.00250.0003 143.63 ppm wet 0.0006 0 ppm wet 0.0020.0004 144.67 ppm wet 0.0006 0.01 ppm wet 0.00190.0005 143.83 ppm wet 0.0008 0.01 ppm wet 0.0020.0005 144.4 ppm wet 0.0006 0 ppm wet 0.0020.0005 144.3 ppm wet 0.0006 0.01 ppm wet 0.00080.001 144.01 ppm wet 0.0008 0.01 ppm wet 0.00190.001 145.19 ppm wet 0.0008 0.02 ppm wet 0.00140.0003 145.15 ppm wet 0.0008 0 ppm wet 0.00150.0003 145.03 ppm wet 0.0008 0 ppm wet 0.00160.0003 143.65 ppm wet 0.0005 0.01 ppm wet 0.00220.0008 144.12 ppm wet 0.0007 0 ppm wet 0.00140.0007 144.09 ppm wet 0.0008 0.01 ppm wet 0.00210.0004 143.91 ppm wet 0.0007 0 ppm wet 0.00210.0005 143.35 ppm wet 0.0007 0 ppm wet 0.0020.0006 143.74 ppm wet 0.0007 0 ppm wet 0.00190.0004 143.68 ppm wet 0.0006 0.02 ppm wet 0.00220.0007 143.79 ppm wet 0.0008 0 ppm wet 0.00120.0005 144.1 ppm wet 0.0005 0 ppm wet 0.00150.0006 143.3 ppm wet 0.0005 0.01 ppm wet 0.00090.0005 143.51 ppm wet 0.0007 0.01 ppm wet 0.0010.0008 143.65 ppm wet 0.0006 0 ppm wet 0.00140.0008 143.35 ppm wet 0.0006 0 ppm wet 0.00210.0004 143.65 ppm wet 0.0005 0.03 ppm wet 0.00170.0008 143.94 ppm wet 0.0006 0.01 ppm wet 0.00310.0005 143.57 ppm wet 0.0008 0 ppm wet 0.00180.0006 144.63 ppm wet 0.0006 0.01 ppm wet 0.00280.0007 143.86 ppm wet 0.0007 0.01 ppm wet 0.0020.0008 144.37 ppm wet 0.0006 0 ppm wet 0.0020.0008 143.55 ppm wet 0.0006 0.01 ppm wet 0.00240.0004 144.32 ppm wet 0.0005 0 ppm wet 0.0020.0006 143.44 ppm wet 0.0006 0.02 ppm wet 0.00150.0004 143.77 ppm wet 0.0005 0.01 ppm wet 0.00170.0003 144.08 ppm wet 0.0007 0 ppm wet 0.00130.0005 143.48 ppm wet 0.0006 0.01 ppm wet 0.00120.0005 143.68 ppm wet 0.0006 0 ppm wet 0.00250.0009 143.9 ppm wet 0.0006 0 ppm wet 0.0030.0009 143.82 ppm wet 0.0006 0 ppm wet 0.00190.0006 143.68 ppm wet 0.0007 0.01 ppm wet 0.00140.0003 144.43 ppm wet 0.0006 0.01 ppm wet 0.00150.0006 144.03 ppm wet 0.0007 0 ppm wet 0.0015144.007Date Time SpectrumFile Water vapoUnit CompensaResidual3/18/2010 13:23:51 C:\CalcmetSamples\Lehigh 210158\20100318\ Spike Before Run 1 _02775.S12.5 vol-% wet 0.00243/18/2010 13:23:57 C:\CalcmetSamples\Lehigh 210158\20100318\ Spike Before Run 1 _02776.S12.42 vol-% wet 0.00243/18/2010 13:24:03 C:\CalcmetSamples\Lehigh 210158\20100318\ Spike Before Run 1 _02777.S12.41 vol-% wet 0.00233/18/2010 13:24:09 C:\CalcmetSamples\Lehigh 210158\20100318\ Spike Before Run 1 _02778.S12.43 vol-% wet 0.00243/18/2010 13:24:15 C:\CalcmetSamples\Lehigh 210158\20100318\ Spike Before Run 1 _02779.S12.39 vol-% wet 0.00243/18/2010 13:24:21 C:\CalcmetSamples\Lehigh 210158\20100318\ Spike Before Run 1 _02780.S12.39 vol-% wet 0.00243/18/2010 13:24:27 C:\CalcmetSamples\Lehigh 210158\20100318\ Spike Before Run 1 _02781.S12.42 vol-% wet 0.0024Date Time SpectrumFile Water vapoUnit CompensaResidual3/18/2010 9:23:42 C:\CalcmetSamples\Lehigh 210158\20100318\Spike Run 1 Before_00736.S 0 vol-% wet 0.00063/18/2010 9:23:48 C:\CalcmetSamples\Lehigh 210158\20100318\Spike Run 1 Before_00737.S 0 vol-% wet 0.00073/18/2010 9:23:54 C:\CalcmetSamples\Lehigh 210158\20100318\Spike Run 1 Before_00738.S 0 vol-% wet 0.00053/18/2010 9:24:00 C:\CalcmetSamples\Lehigh 210158\20100318\Spike Run 1 Before_00739.S 0 vol-% wet 0.00073/18/2010 9:24:06 C:\CalcmetSamples\Lehigh 210158\20100318\Spike Run 1 Before_00740.S 0 vol-% wet 0.00083/18/2010 9:24:12 C:\CalcmetSamples\Lehigh 210158\20100318\Spike Run 1 Before_00741.S 0 vol-% wet 0.00033/18/2010 9:24:18 C:\CalcmetSamples\Lehigh 210158\20100318\Spike Run 1 Before_00742.S 0 vol-% wet 0.00083/18/2010 9:24:24 C:\CalcmetSamples\Lehigh 210158\20100318\Spike Run 1 Before_00743.S 0 vol-% wet 0.00083/18/2010 9:24:30 C:\CalcmetSamples\Lehigh 210158\20100318\Spike Run 1 Before_00744.S 0 vol-% wet 0.00073/18/2010 9:24:36 C:\CalcmetSamples\Lehigh 210158\20100318\Spike Run 1 Before_00745.S 0 vol-% wet 0.00073/18/2010 9:24:42 C:\CalcmetSamples\Lehigh 210158\20100318\Spike Run 1 Before_00746.S 0 vol-% wet 0.0009HydrogencUnit CompensaResidual SF6 Unit CompensaResidual1.13 ppm wet 0.0023 0.65 ppm wet 0.0051.39 ppm wet 0.0023 0.72 ppm wet 0.0051.26 ppm wet 0.0022 0.65 ppm wet 0.0050.79 ppm wet 0.0022 0.66 ppm wet 0.00531.58 ppm wet 0.0024 0.66 ppm wet 0.00520.47 ppm wet 0.0024 0.66 ppm wet 0.00531.84 ppm wet 0.0025 0.66 ppm wet 0.0049HydrogencUnit CompensaResidual SF6 Unit CompensaResidual14.44 ppm wet 0.0003 0.04 ppm wet 0.003214.78 ppm wet 0.0003 0.02 ppm wet 0.001814.86 ppm wet 0.0002 0.05 ppm wet 0.001914.72 ppm wet 0.0002 0.04 ppm wet 0.000810.61 ppm wet 0.0002 0.03 ppm wet 0.00247.77 ppm wet 0.0002 0.02 ppm wet 0.00111.87 ppm wet 0.0002 0 ppm wet 0.00210.63 ppm wet 0.0002 0.02 ppm wet 0.00190.48 ppm wet 0.0003 1.62 ppm wet 0.00140.01 ppm wet 0.0003 1.61 ppm wet 0.00250.81 ppm wet 0.0003 1.65 ppm wet 0.0024HCL LehighSm --Spiked DataDate Method Filename HCl(ppm) SF6 (ppm)03/18/10 321 C:\CalcmetSamples\L 14.78 C:\CalcmetSam1.6203/18/10 321 C:\CalcmetSamples\L 14.86 C:\CalcmetSam1.6103/18/10 321 C:\CalcmetSamples\L 14.72 C:\CalcmetSam1.65Avg. Conc. (ppm)14.791.627Su -- Native Conc. Of analyteDate Method Filename HCl(ppm) SF6 (ppm)03/18/10 321 C:\CalcmetSamples\L 1.58 C:\CalcmetSam0.6603/18/10 321 C:\CalcmetSamples\L 0.47 C:\CalcmetSam0.6603/18/10 321 C:\CalcmetSamples\L 1.84 C:\CalcmetSam0.66Avg. Conc. (ppm)1.300.660Sm - Su(1-DF)Recovery (%) = DF x CsCe = DF x Cs + Su(1-DF)Sm 14.79ppm Mean concentration of spiked analyteSu 1.30ppm Native concentration of analyteDF 9.7% % Dilution Factor (Target < 10%)Cs 144.2ppm Cylinder of spiked gas9.98ppm Cylinder of tracer gas (SF6)Ce 15.14ppm Expected concentration of analyteRecovery (%)97.5%70 - 130 %Date Time SpectrumFile Water vapoUnit CompensaResidual Hydrogenc3/18/2010 14:11:03 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02819.SPE 9.87 vol-% wet 0.0026 13.853/18/2010 14:12:04 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02820.SPE 9.87 vol-% wet 0.0027 13.783/18/2010 14:13:04 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02821.SPE 9.87 vol-% wet 0.0027 13.663/18/2010 14:14:05 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02822.SPE 9.88 vol-% wet 0.0027 14.293/18/2010 14:15:05 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02823.SPE 9.88 vol-% wet 0.0027 14.523/18/2010 14:16:06 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02824.SPE 9.91 vol-% wet 0.0026 14.573/18/2010 14:17:07 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02825.SPE 9.91 vol-% wet 0.0027 14.613/18/2010 14:18:07 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02826.SPE 9.95 vol-% wet 0.0027 14.493/18/2010 14:19:08 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02827.SPE 9.95 vol-% wet 0.0028 14.133/18/2010 14:20:08 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02828.SPE 10 vol-% wet 0.0028 14.713/18/2010 14:21:09 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02829.SPE 9.97 vol-% wet 0.0027 14.813/18/2010 14:22:10 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02830.SPE 9.99 vol-% wet 0.0028 153/18/2010 14:23:10 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02831.SPE 9.98 vol-% wet 0.0028 15.563/18/2010 14:24:11 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02832.SPE 9.93 vol-% wet 0.0028 15.673/18/2010 14:25:11 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02833.SPE 9.95 vol-% wet 0.0027 15.653/18/2010 14:26:12 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02834.SPE 9.96 vol-% wet 0.0028 14.643/18/2010 14:27:13 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02835.SPE 9.98 vol-% wet 0.0027 13.943/18/2010 14:28:13 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02836.SPE 9.96 vol-% wet 0.0027 13.673/18/2010 14:29:14 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02837.SPE 9.93 vol-% wet 0.0026 14.83/18/2010 14:30:14 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02838.SPE 9.88 vol-% wet 0.0026 15.023/18/2010 14:31:15 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02839.SPE 9.87 vol-% wet 0.0026 15.33/18/2010 14:32:16 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02840.SPE 9.79 vol-% wet 0.0026 15.493/18/2010 14:33:16 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02841.SPE 9.75 vol-% wet 0.0025 15.273/18/2010 14:34:17 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02842.SPE 9.75 vol-% wet 0.0025 14.823/18/2010 14:35:17 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02843.SPE 9.74 vol-% wet 0.0026 14.693/18/2010 14:36:18 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02844.SPE 9.78 vol-% wet 0.0026 14.453/18/2010 14:37:19 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02845.SPE 9.76 vol-% wet 0.0026 13.83/18/2010 14:38:19 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02846.SPE 9.78 vol-% wet 0.0026 13.463/18/2010 14:39:20 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02847.SPE 9.81 vol-% wet 0.0026 13.443/18/2010 14:40:21 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02848.SPE 9.82 vol-% wet 0.0027 13.183/18/2010 14:41:21 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02849.SPE 9.88 vol-% wet 0.0026 12.913/18/2010 14:42:22 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02850.SPE 9.87 vol-% wet 0.0027 12.433/18/2010 14:43:22 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02851.SPE 9.95 vol-% wet 0.0026 12.433/18/2010 14:44:23 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02852.SPE 9.94 vol-% wet 0.0027 12.663/18/2010 14:45:24 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02853.SPE 9.93 vol-% wet 0.0027 12.373/18/2010 14:46:24 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02854.SPE 9.98 vol-% wet 0.0028 12.693/18/2010 14:47:25 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02855.SPE 9.98 vol-% wet 0.0027 13.253/18/2010 14:48:26 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02856.SPE 10.04 vol-% wet 0.0028 13.513/18/2010 14:49:26 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02857.SPE 10.04 vol-% wet 0.0027 12.973/18/2010 14:50:27 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02858.SPE 10.01 vol-% wet 0.0028 13.043/18/2010 14:51:28 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02859.SPE 9.95 vol-% wet 0.0026 11.183/18/2010 14:52:28 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02860.SPE 9.95 vol-% wet 0.0026 11.093/18/2010 14:53:29 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02861.SPE 9.98 vol-% wet 0.0026 11.13/18/2010 14:54:30 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02862.SPE 9.99 vol-% wet 0.0026 10.963/18/2010 14:55:30 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02863.SPE 10.04 vol-% wet 0.0026 10.883/18/2010 14:56:31 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02864.SPE 10.09 vol-% wet 0.0026 10.73/18/2010 14:57:31 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02865.SPE 10.07 vol-% wet 0.0026 10.723/18/2010 14:58:32 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02866.SPE 10.15 vol-% wet 0.0029 13.143/18/2010 14:59:33 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02867.SPE 10.11 vol-% wet 0.0029 13.253/18/2010 15:00:33 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02868.SPE 10.04 vol-% wet 0.0028 13.383/18/2010 15:01:34 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02869.SPE 9.99 vol-% wet 0.0027 13.813/18/2010 15:02:34 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02870.SPE 9.9 vol-% wet 0.0027 13.583/18/2010 15:03:35 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02871.SPE 9.85 vol-% wet 0.0027 14.333/18/2010 15:04:36 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02872.SPE 9.82 vol-% wet 0.0027 14.813/18/2010 15:05:36 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02873.SPE 9.8 vol-% wet 0.0027 15.313/18/2010 15:06:37 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02874.SPE 9.71 vol-% wet 0.0027 14.513/18/2010 15:07:37 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02875.SPE 9.7 vol-% wet 0.0027 13.473/18/2010 15:08:38 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02876.SPE 18.37 vol-% wet 0.0036 24.83/18/2010 15:09:39 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02877.SPE 12.76 vol-% wet 0.0028 25.093/18/2010 15:10:39 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02878.SPE 10.41 vol-% wet 0.0031 15.663/18/2010 15:11:40 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02879.SPE 9.92 vol-% wet 0.0029 15.593/18/2010 15:12:40 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02880.SPE 9.7 vol-% wet 0.0027 15.53Averages14.14Unit CompensaResidual SF6 Unit CompensaResidualppm wet 0.0053 0.68 ppm wet 0.007ppm wet 0.0053 0.67 ppm wet 0.0071ppm wet 0.0054 0.67 ppm wet 0.0073ppm wet 0.0054 0.68 ppm wet 0.0075ppm wet 0.0055 0.69 ppm wet 0.0076ppm wet 0.0055 0.7 ppm wet 0.0076ppm wet 0.0055 0.69 ppm wet 0.0077ppm wet 0.0056 0.69 ppm wet 0.0078ppm wet 0.0055 0.7 ppm wet 0.0078ppm wet 0.0055 0.71 ppm wet 0.0077ppm wet 0.0056 0.72 ppm wet 0.0077ppm wet 0.0059 0.71 ppm wet 0.0077ppm wet 0.0062 0.71 ppm wet 0.008ppm wet 0.0063 0.71 ppm wet 0.0078ppm wet 0.0062 0.71 ppm wet 0.0079ppm wet 0.0056 0.72 ppm wet 0.0081ppm wet 0.0051 0.72 ppm wet 0.0077ppm wet 0.005 0.72 ppm wet 0.0077ppm wet 0.0054 0.75 ppm wet 0.0076ppm wet 0.0056 0.76 ppm wet 0.0076ppm wet 0.0056 0.75 ppm wet 0.0078ppm wet 0.0059 0.73 ppm wet 0.0078ppm wet 0.0058 0.71 ppm wet 0.0077ppm wet 0.0056 0.72 ppm wet 0.0075ppm wet 0.0057 0.7 ppm wet 0.0075ppm wet 0.0055 0.7 ppm wet 0.0076ppm wet 0.0055 0.7 ppm wet 0.0073ppm wet 0.0053 0.7 ppm wet 0.0075ppm wet 0.0052 0.69 ppm wet 0.0072ppm wet 0.0051 0.69 ppm wet 0.0077ppm wet 0.005 0.69 ppm wet 0.0076ppm wet 0.0049 0.68 ppm wet 0.0074ppm wet 0.0048 0.67 ppm wet 0.0072ppm wet 0.0049 0.67 ppm wet 0.0074ppm wet 0.0049 0.67 ppm wet 0.0072ppm wet 0.0052 0.66 ppm wet 0.0071ppm wet 0.0054 0.65 ppm wet 0.007ppm wet 0.0055 0.66 ppm wet 0.0072ppm wet 0.0055 0.66 ppm wet 0.0071ppm wet 0.0053 0.64 ppm wet 0.0073ppm wet 0.0048 0.65 ppm wet 0.0072ppm wet 0.0047 0.64 ppm wet 0.007ppm wet 0.0048 0.66 ppm wet 0.0071ppm wet 0.0047 0.67 ppm wet 0.007ppm wet 0.0045 0.66 ppm wet 0.0073ppm wet 0.0045 0.66 ppm wet 0.0075ppm wet 0.0048 0.65 ppm wet 0.0076ppm wet 0.0051 0.67 ppm wet 0.0072ppm wet 0.0053 0.68 ppm wet 0.0073ppm wet 0.0053 0.69 ppm wet 0.0074ppm wet 0.0055 0.7 ppm wet 0.0071ppm wet 0.0055 0.69 ppm wet 0.0075ppm wet 0.0057 0.69 ppm wet 0.0076ppm wet 0.0056 0.7 ppm wet 0.0075ppm wet 0.0057 0.7 ppm wet 0.0071ppm wet 0.0055 0.67 ppm wet 0.0073ppm wet 0.005 0.67 ppm wet 0.0072ppm wet 0.0052 0.35 ppm wet 0.015ppm wet 0.0052 0.56 ppm wet 0.0094ppm wet 0.005 0.62 ppm wet 0.0083ppm wet 0.005 0.64 ppm wet 0.0081ppm wet 0.0049 0.64 ppm wet 0.0076HCL LehighSm --Spiked DataDate Method Filename HCl(ppm) SF6 (ppm)03/18/10 321 C:\CalcmetSamples\L 26.32 C:\CalcmetSam1.4803/18/10 321 C:\CalcmetSamples\L 25.36 C:\CalcmetSam1.5403/18/10 321 C:\CalcmetSamples\L 25.55 C:\CalcmetSam1.52Avg. Conc. (ppm)25.741.513Su -- Native Conc. Of analyteDate Method Filename HCl(ppm) SF6 (ppm)03/18/10 321 C:\CalcmetSamples\L 15.66 C:\CalcmetSam0.6203/18/10 321 C:\CalcmetSamples\L 15.59 C:\CalcmetSam0.6403/18/10 321 C:\CalcmetSamples\L 15.53 C:\CalcmetSam0.64Avg. Conc. (ppm)15.590.633Sm - Su(1-DF)Recovery (%) = DF x CsCe = DF x Cs + Su(1-DF)Sm 25.74ppm Mean concentration of spiked analyteSu 15.59ppm Native concentration of analyteDF 8.8% % Dilution Factor (Target < 10%)Cs 144.2ppm Cylinder of spiked gas9.98ppm Cylinder of tracer gas (SF6)Ce 26.93ppm Expected concentration of analyteRecovery (%)90.6%70 - 130 %Date Time SpectrumFWater vapoUnit CompensaResidual HydrogencUnit CompensaResidual SF6 Unit3/18/2010 15:14:55 C:\Calcmet8.44 vol-% wet 0.0023 26.32 ppm wet 0.0036 0.53 ppm3/18/2010 15:15:01 C:\Calcmet8.37 vol-% wet 0.0021 25.36 ppm wet 0.0037 0.43 ppm3/18/2010 15:15:07 C:\Calcmet8.39 vol-% wet 0.0022 25.55 ppm wet 0.0037 0.52 ppm3/18/2010 15:15:13 C:\Calcmet8.37 vol-% wet 0.0022 21.98 ppm wet 0.0036 0.55 ppm3/18/2010 15:15:19 C:\Calcmet8.33 vol-% wet 0.0021 21.69 ppm wet 0.0037 0.5 ppm3/18/2010 15:15:25 C:\Calcmet8.28 vol-% wet 0.002 19.44 ppm wet 0.0037 0.48 ppm3/18/2010 15:15:31 C:\Calcmet8.3 vol-% wet 0.0021 11.99 ppm wet 0.0038 0.49 ppm3/18/2010 15:15:37 C:\Calcmet8.18 vol-% wet 0.0021 10.37 ppm wet 0.0037 0.48 ppm3/18/2010 15:15:43 C:\Calcmet8.17 vol-% wet 0.0019 9.53 ppm wet 0.0038 0.66 ppm3/18/2010 15:15:49 C:\Calcmet8.21 vol-% wet 0.0022 11.89 ppm wet 0.0038 0.36 ppm3/18/2010 15:15:55 C:\Calcmet8.1 vol-% wet 0.0019 9.65 ppm wet 0.0039 0.47 ppm3/18/2010 15:16:01 C:\Calcmet8.27 vol-% wet 0.0019 10.6 ppm wet 0.0039 0.51 ppm3/18/2010 15:16:07 C:\Calcmet8.21 vol-% wet 0.0021 9.55 ppm wet 0.0038 0.44 ppm3/18/2010 15:16:13 C:\Calcmet8.34 vol-% wet 0.0022 12.39 ppm wet 0.0043 0.58 ppm3/18/2010 15:16:19 C:\Calcmet8.23 vol-% wet 0.0022 10.2 ppm wet 0.0045 0.42 ppm3/18/2010 15:16:25 C:\Calcmet8.35 vol-% wet 0.0022 12.28 ppm wet 0.0043 0.33 ppm3/18/2010 15:16:31 C:\Calcmet8.3 vol-% wet 0.0021 10.17 ppm wet 0.0045 0.25 ppm3/18/2010 15:16:37 C:\Calcmet8.35 vol-% wet 0.002 10 ppm wet 0.0044 0.33 ppm3/18/2010 15:16:43 C:\Calcmet8.28 vol-% wet 0.0021 10.4 ppm wet 0.0043 0.31 ppm3/18/2010 15:16:49 C:\Calcmet8.37 vol-% wet 0.0021 12.75 ppm wet 0.0044 0.34 ppm3/18/2010 15:16:55 C:\Calcmet8.38 vol-% wet 0.0021 12.36 ppm wet 0.0045 0.41 ppm3/18/2010 15:17:01 C:\Calcmet8.33 vol-% wet 0.0021 12.42 ppm wet 0.0047 0.4 ppm3/18/2010 15:17:07 C:\Calcmet8.34 vol-% wet 0.0022 12.76 ppm wet 0.0048 0.55 ppm3/18/2010 15:17:13 C:\Calcmet8.46 vol-% wet 0.0021 12.53 ppm wet 0.0047 0.51 ppm3/18/2010 15:17:19 C:\Calcmet8.38 vol-% wet 0.0021 12.59 ppm wet 0.0044 0.54 ppm3/18/2010 15:17:25 C:\Calcmet8.49 vol-% wet 0.0022 12.87 ppm wet 0.0051 0.38 ppm3/18/2010 15:18:48 C:\Calcmet8.49 vol-% wet 0.0021 12.61 ppm wet 0.0049 0.43 ppm3/18/2010 15:20:44 C:\Calcmet8.54 vol-% wet 0.0021 13.2 ppm wet 0.006 1.02 ppm3/18/2010 15:20:50 C:\Calcmet8.44 vol-% wet 0.0022 12.97 ppm wet 0.0054 1.22 ppm3/18/2010 15:20:56 C:\Calcmet8.5 vol-% wet 0.0021 11.9 ppm wet 0.0052 1.48 ppm3/18/2010 15:21:02 C:\Calcmet8.41 vol-% wet 0.002 10.2 ppm wet 0.005 1.54 ppm3/18/2010 15:21:08 C:\Calcmet8.4 vol-% wet 0.0019 9.98 ppm wet 0.005 1.52 ppm3/18/2010 15:21:14 C:\Calcmet8.41 vol-% wet 0.002 9.92 ppm wet 0.0049 1.46 ppm3/18/2010 15:21:20 C:\Calcmet8.36 vol-% wet 0.0017 9.25 ppm wet 0.0048 1.58 ppm3/18/2010 15:21:26 C:\Calcmet8.32 vol-% wet 0.002 10.13 ppm wet 0.0047 1.64 ppm3/18/2010 15:21:32 C:\Calcmet8.36 vol-% wet 0.0019 9.87 ppm wet 0.0048 1.55 ppm3/18/2010 15:21:38 C:\Calcmet8.27 vol-% wet 0.0021 10.3 ppm wet 0.0049 1.41 ppm3/18/2010 15:21:44 C:\Calcmet8.26 vol-% wet 0.0021 9.96 ppm wet 0.0046 0.25 ppm3/18/2010 15:21:50 C:\Calcmet8.31 vol-% wet 0.0023 9.84 ppm wet 0.0047 0 ppm3/18/2010 15:21:55 C:\Calcmet8.29 vol-% wet 0.0019 10 ppm wet 0.0046 0 ppmCompensaResidualwet 0.0071wet 0.0064wet 0.0078wet 0.0072wet 0.0076wet 0.0073wet 0.0076wet 0.0073wet 0.0071wet 0.0072wet 0.0068wet 0.0066wet 0.0065wet 0.0065wet 0.0071wet 0.0077wet 0.0072wet 0.0073wet 0.0068wet 0.0077wet 0.0068wet 0.0067wet 0.0079wet 0.0073wet 0.0067wet 0.0071wet 0.0074wet 0.0055wet 0.0062wet 0.0056wet 0.006wet 0.0061wet 0.0054wet 0.0059wet 0.006wet 0.0062wet 0.0059wet 0.0047wet 0.0061wet 0.0091Date Time SpectrumFile Water vapoUnit CompensaResidual Hydrogenc3/18/2010 15:32:02 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03004.SPE 9.61 vol-% wet 0.0024 10.343/18/2010 15:33:02 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03005.SPE 9.71 vol-% wet 0.0025 10.433/18/2010 15:34:03 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03006.SPE 15.01 vol-% wet 0.0038 15.773/18/2010 15:35:03 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03007.SPE 10.43 vol-% wet 0.0031 23.473/18/2010 15:36:04 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03008.SPE 9.92 vol-% wet 0.0027 12.473/18/2010 15:37:05 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03009.SPE 9.94 vol-% wet 0.0028 12.473/18/2010 15:38:05 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03010.SPE 9.81 vol-% wet 0.0026 11.13/18/2010 15:39:06 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03011.SPE 9.78 vol-% wet 0.0025 11.023/18/2010 15:40:07 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03012.SPE 9.82 vol-% wet 0.0026 11.273/18/2010 15:41:07 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03013.SPE 9.9 vol-% wet 0.0028 12.553/18/2010 15:42:08 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03014.SPE 12.93 vol-% wet 0.0028 15.393/18/2010 15:43:09 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03015.SPE 10.44 vol-% wet 0.0032 16.13/18/2010 15:44:09 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03016.SPE 10.05 vol-% wet 0.003 13.53/18/2010 15:45:10 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03017.SPE 9.94 vol-% wet 0.0029 12.83/18/2010 15:46:11 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03018.SPE 12.19 vol-% wet 0.0025 13.953/18/2010 15:47:11 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03019.SPE 10.03 vol-% wet 0.003 13.443/18/2010 15:48:12 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03020.SPE 9.94 vol-% wet 0.0029 13.083/18/2010 15:49:12 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03021.SPE 9.95 vol-% wet 0.003 12.433/18/2010 15:50:13 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03022.SPE 9.88 vol-% wet 0.0026 11.143/18/2010 15:51:13 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03023.SPE 9.93 vol-% wet 0.0028 12.723/18/2010 15:52:14 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03024.SPE 9.88 vol-% wet 0.0028 12.643/18/2010 15:53:15 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03025.SPE 9.92 vol-% wet 0.0029 12.583/18/2010 15:54:15 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03026.SPE 12.08 vol-% wet 0.0025 13.763/18/2010 15:55:16 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03027.SPE 14.24 vol-% wet 0.0036 34.453/18/2010 15:56:16 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03028.SPE 10.01 vol-% wet 0.003 16.563/18/2010 15:57:17 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03029.SPE 9.87 vol-% wet 0.0028 153/18/2010 15:58:18 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03030.SPE 9.86 vol-% wet 0.0028 14.963/18/2010 15:59:18 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03031.SPE 9.83 vol-% wet 0.0029 14.63/18/2010 16:00:19 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03032.SPE 9.89 vol-% wet 0.0028 14.93/18/2010 16:01:20 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03033.SPE 9.87 vol-% wet 0.0028 14.893/18/2010 16:02:20 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03034.SPE 9.85 vol-% wet 0.0028 14.783/18/2010 16:03:21 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03035.SPE 9.85 vol-% wet 0.0027 14.973/18/2010 16:04:21 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03036.SPE 9.81 vol-% wet 0.0028 14.953/18/2010 16:05:22 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03037.SPE 9.79 vol-% wet 0.0028 15.123/18/2010 16:06:23 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03038.SPE 9.81 vol-% wet 0.0027 15.243/18/2010 16:07:23 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03039.SPE 9.8 vol-% wet 0.0027 15.83/18/2010 16:08:24 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03040.SPE 9.8 vol-% wet 0.0027 15.913/18/2010 16:09:25 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03041.SPE 9.75 vol-% wet 0.0026 16.263/18/2010 16:10:25 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03042.SPE 9.76 vol-% wet 0.0026 15.993/18/2010 16:11:26 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03043.SPE 9.73 vol-% wet 0.0026 15.713/18/2010 16:12:26 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03044.SPE 9.82 vol-% wet 0.0027 16.33/18/2010 16:13:27 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03045.SPE 9.9 vol-% wet 0.0027 16.553/18/2010 16:14:28 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03046.SPE 9.94 vol-% wet 0.0028 17.063/18/2010 16:15:28 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03047.SPE 10 vol-% wet 0.0027 22.93/18/2010 16:16:29 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03048.SPE 12.53 vol-% wet 0.0025 23.983/18/2010 16:17:29 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03049.SPE 12.23 vol-% wet 0.0025 26.293/18/2010 16:18:30 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03050.SPE 10.23 vol-% wet 0.003 15.843/18/2010 16:19:31 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03051.SPE 10.04 vol-% wet 0.0029 15.263/18/2010 16:20:31 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03052.SPE 12.93 vol-% wet 0.0028 23.813/18/2010 16:21:32 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03053.SPE 10.27 vol-% wet 0.003 23.463/18/2010 16:22:32 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03054.SPE 9.89 vol-% wet 0.003 13.73/18/2010 16:23:33 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03055.SPE 9.89 vol-% wet 0.0028 14.133/18/2010 16:24:34 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03056.SPE 9.83 vol-% wet 0.0029 13.423/18/2010 16:25:34 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03057.SPE 9.82 vol-% wet 0.0028 13.833/18/2010 16:26:35 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03058.SPE 9.79 vol-% wet 0.0028 14.083/18/2010 16:27:36 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03059.SPE 9.89 vol-% wet 0.0028 14.763/18/2010 16:28:36 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03060.SPE 9.88 vol-% wet 0.0028 14.773/18/2010 16:29:37 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03061.SPE 9.85 vol-% wet 0.0029 13.723/18/2010 16:30:37 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03062.SPE 9.86 vol-% wet 0.0028 13.383/18/2010 16:31:38 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03063.SPE 16.54 vol-% wet 0.003 26.69Averages15.64Unit CompensaResidual SF6 Unit CompensaResidualppm wet 0.0049 0 ppm wet 0.0063ppm wet 0.0048 0 ppm wet 0.0067ppm wet 0.0047 0 ppm wet 0.024ppm wet 0.0044 0 ppm wet 0.0172ppm wet 0.0046 0 ppm wet 0.01ppm wet 0.0048 0 ppm wet 0.009ppm wet 0.0049 0 ppm wet 0.0096ppm wet 0.0048 0 ppm wet 0.0097ppm wet 0.0049 0 ppm wet 0.0089ppm wet 0.005 0 ppm wet 0.0094ppm wet 0.0049 0 ppm wet 0.0176ppm wet 0.0047 0 ppm wet 0.0164ppm wet 0.0047 0 ppm wet 0.012ppm wet 0.0045 0 ppm wet 0.0111ppm wet 0.0045 0 ppm wet 0.0144ppm wet 0.0045 0 ppm wet 0.0131ppm wet 0.0045 0 ppm wet 0.0103ppm wet 0.0045 0 ppm wet 0.0104ppm wet 0.0045 0 ppm wet 0.01ppm wet 0.0045 0 ppm wet 0.0099ppm wet 0.0046 0 ppm wet 0.01ppm wet 0.0048 0 ppm wet 0.0094ppm wet 0.0049 0 ppm wet 0.0134ppm wet 0.0044 0 ppm wet 0.0326ppm wet 0.0047 0 ppm wet 0.0138ppm wet 0.0053 0 ppm wet 0.0111ppm wet 0.0055 0 ppm wet 0.0104ppm wet 0.0053 0 ppm wet 0.01ppm wet 0.0054 0 ppm wet 0.0097ppm wet 0.0055 0 ppm wet 0.0098ppm wet 0.0056 0 ppm wet 0.0097ppm wet 0.0059 0 ppm wet 0.0097ppm wet 0.006 0 ppm wet 0.01ppm wet 0.006 0 ppm wet 0.0099ppm wet 0.0061 0 ppm wet 0.0101ppm wet 0.0064 0 ppm wet 0.0102ppm wet 0.0067 0 ppm wet 0.0103ppm wet 0.0069 0 ppm wet 0.0101ppm wet 0.0069 0 ppm wet 0.0094ppm wet 0.0067 0 ppm wet 0.0103ppm wet 0.0071 0 ppm wet 0.0107ppm wet 0.0074 0 ppm wet 0.0109ppm wet 0.0077 0 ppm wet 0.0108ppm wet 0.008 0 ppm wet 0.0114ppm wet 0.0076 0 ppm wet 0.0169ppm wet 0.0068 0 ppm wet 0.0195ppm wet 0.006 0 ppm wet 0.0139ppm wet 0.0059 0 ppm wet 0.0132ppm wet 0.0057 0 ppm wet 0.0215ppm wet 0.0056 0 ppm wet 0.0169ppm wet 0.0054 0 ppm wet 0.0134ppm wet 0.0057 0 ppm wet 0.0127ppm wet 0.0058 0 ppm wet 0.0119ppm wet 0.0063 0 ppm wet 0.0109ppm wet 0.0067 0 ppm wet 0.0103ppm wet 0.007 0 ppm wet 0.0105ppm wet 0.007 0 ppm wet 0.0103ppm wet 0.0066 0 ppm wet 0.0109ppm wet 0.0062 0 ppm wet 0.0104ppm wet 0.0057 0 ppm wet 0.0308HCL LehighSm --Spiked DataDate Method Filename HCl(ppm) SF6 (ppm)03/18/10 321 C:\CalcmetSamples\L 29.41 C:\CalcmetSam0.6503/18/10 321 C:\CalcmetSamples\L 28.11 C:\CalcmetSam1.0403/18/10 321 C:\CalcmetSamples\L 29.49 C:\CalcmetSam1.17Avg. Conc. (ppm)29.000.953Su -- Native Conc. Of analyteDate Method Filename HCl(ppm) SF6 (ppm)03/18/10 321 C:\CalcmetSamples\L 13.72 C:\CalcmetSam003/18/10 321 C:\CalcmetSamples\L 13.38 C:\CalcmetSam003/18/10 321 C:\CalcmetSamples\L 26.69 C:\CalcmetSam0Avg. Conc. (ppm)17.93-Sm - Su(1-DF)Recovery (%) = DF x CsCe = DF x Cs + Su(1-DF)Sm 29.00ppm Mean concentration of spiked analyteSu 17.93ppm Native concentration of analyteDF 9.6% % Dilution Factor (Target < 10%)Cs 144.2ppm Cylinder of spiked gas9.98ppm Cylinder of tracer gas (SF6)Ce 29.99ppm Expected concentration of analyteRecovery (%)92.8%70 - 130 %Date Time SpectrumFWater vapoUnit CompensaResidual HydrogencUnit CompensaResidual SF6 Unit3/18/2010 16:34:23 C:\Calcmet9.35 vol-% wet 0.0025 32.79 ppm wet 0.0074 0 ppm3/18/2010 16:34:37 C:\Calcmet9.25 vol-% wet 0.0029 30.88 ppm wet 0.0054 0 ppm3/18/2010 16:34:51 C:\Calcmet9.28 vol-% wet 0.0027 13.08 ppm wet 0.0049 0 ppm3/18/2010 16:34:54 C:\Calcmet9.25 vol-% wet 0.0029 13.69 ppm wet 0.0049 0 ppm3/18/2010 16:34:57 C:\Calcmet9.25 vol-% wet 0.0029 12.08 ppm wet 0.0051 0 ppm3/18/2010 16:35:00 C:\Calcmet9.23 vol-% wet 0.0021 10.34 ppm wet 0.0049 0 ppm3/18/2010 16:35:03 C:\Calcmet9.26 vol-% wet 0.0026 12.88 ppm wet 0.0043 0 ppm3/18/2010 16:35:06 C:\Calcmet9.24 vol-% wet 0.0025 13.08 ppm wet 0.0049 0 ppm3/18/2010 16:35:09 C:\Calcmet9.31 vol-% wet 0.0024 13.16 ppm wet 0.0047 0 ppm3/18/2010 16:35:12 C:\Calcmet9.03 vol-% wet 0.0026 8.64 ppm wet 0.0057 0 ppm3/18/2010 16:35:15 C:\Calcmet9.14 vol-% wet 0.0029 12.84 ppm wet 0.0047 0 ppm3/18/2010 16:35:17 C:\Calcmet9.04 vol-% wet 0.0026 10.16 ppm wet 0.005 0 ppm3/18/2010 16:35:20 C:\Calcmet9.08 vol-% wet 0.0027 9.28 ppm wet 0.0047 0 ppm3/18/2010 16:35:23 C:\Calcmet9.06 vol-% wet 0.0025 9.45 ppm wet 0.0046 0 ppm3/18/2010 16:35:26 C:\Calcmet9.14 vol-% wet 0.0022 10.28 ppm wet 0.0054 0 ppm3/18/2010 16:35:29 C:\Calcmet9.22 vol-% wet 0.0025 10.75 ppm wet 0.0049 0 ppm3/18/2010 16:35:32 C:\Calcmet9.23 vol-% wet 0.0025 12 ppm wet 0.0053 0 ppm3/18/2010 16:36:39 C:\Calcmet9.13 vol-% wet 0.0026 11.65 ppm wet 0.0051 0 ppm3/18/2010 16:36:42 C:\Calcmet9.06 vol-% wet 0.0023 13.86 ppm wet 0.0047 0 ppm3/18/2010 16:36:45 C:\Calcmet8.95 vol-% wet 0.0027 12.79 ppm wet 0.0048 0 ppm3/18/2010 16:36:47 C:\Calcmet9.02 vol-% wet 0.0022 13.34 ppm wet 0.0048 0 ppm3/18/2010 16:36:50 C:\Calcmet9.02 vol-% wet 0.0024 12.26 ppm wet 0.0047 0 ppm3/18/2010 16:36:53 C:\Calcmet8.88 vol-% wet 0.0022 29.41 ppm wet 0.005 0 ppm3/18/2010 16:36:55 C:\Calcmet8.95 vol-% wet 0.0024 28.11 ppm wet 0.0047 0 ppm3/18/2010 16:36:58 C:\Calcmet9.02 vol-% wet 0.0027 29.49 ppm wet 0.0051 0 ppm3/18/2010 16:37:01 C:\Calcmet8.91 vol-% wet 0.0024 12.2 ppm wet 0.0044 0 ppm3/18/2010 16:37:04 C:\Calcmet8.99 vol-% wet 0.0026 11.95 ppm wet 0.0049 0 ppm3/18/2010 16:37:23 C:\Calcmet9.08 vol-% wet 0.0025 5.18 ppm wet 0.0054 0.15 ppm3/18/2010 16:37:27 C:\Calcmet9.11 vol-% wet 0.0024 1.87 ppm wet 0.0046 0.65 ppm3/18/2010 16:37:30 C:\Calcmet9 vol-% wet 0.0026 0.91 ppm wet 0.0048 1.04 ppm3/18/2010 16:37:46 C:\Calcmet9.04 vol-% wet 0.0022 0.47 ppm wet 0.0047 1.17 ppmCompensaResidualwet 0.0122wet 0.0143wet 0.015wet 0.0118wet 0.0131wet 0.0106wet 0.0091wet 0.0122wet 0.0109wet 0.0109wet 0.0118wet 0.0114wet 0.0083wet 0.0113wet 0.0131wet 0.0095wet 0.0113wet 0.0079wet 0.0087wet 0.0091wet 0.0088wet 0.0072wet 0.0067wet 0.0094wet 0.0087wet 0.0085wet 0.0065wet 0.0058wet 0.0056wet 0.0055wet 0.0058Date Time SpectrumFile Water vapoUnit CompensaResidual Hydrogenc3/18/2010 16:42:09 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03096.SPE 9.56 vol-% wet 0.0026 13.313/18/2010 16:43:10 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03097.SPE 9.65 vol-% wet 0.0027 13.463/18/2010 16:44:11 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03098.SPE 9.62 vol-% wet 0.0027 13.443/18/2010 16:45:11 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03099.SPE 9.69 vol-% wet 0.0027 13.183/18/2010 16:46:12 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03100.SPE 9.68 vol-% wet 0.0027 13.083/18/2010 16:47:12 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03101.SPE 9.72 vol-% wet 0.0027 12.393/18/2010 16:48:13 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03102.SPE 9.59 vol-% wet 0.0025 10.943/18/2010 16:49:14 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03103.SPE 9.59 vol-% wet 0.0025 10.273/18/2010 16:50:14 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03104.SPE 17.81 vol-% wet 0.0034 26.943/18/2010 16:51:15 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03105.SPE 10.4 vol-% wet 0.0031 23.723/18/2010 16:52:16 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03106.SPE 9.94 vol-% wet 0.0028 13.443/18/2010 16:53:16 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03107.SPE 9.9 vol-% wet 0.0028 13.213/18/2010 16:54:17 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03108.SPE 9.89 vol-% wet 0.0028 13.13/18/2010 16:55:18 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03109.SPE 9.85 vol-% wet 0.0028 13.213/18/2010 16:56:18 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03110.SPE 9.81 vol-% wet 0.0027 13.643/18/2010 16:57:19 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03111.SPE 9.8 vol-% wet 0.0027 13.633/18/2010 16:58:19 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03112.SPE 9.75 vol-% wet 0.0027 14.433/18/2010 16:59:20 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03113.SPE 9.75 vol-% wet 0.0026 15.573/18/2010 17:00:20 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03114.SPE 9.72 vol-% wet 0.0027 23.13/18/2010 17:01:21 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03115.SPE 9.79 vol-% wet 0.0026 25.853/18/2010 17:02:22 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03116.SPE 9.74 vol-% wet 0.0026 25.823/18/2010 17:03:22 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03117.SPE 9.72 vol-% wet 0.0026 24.683/18/2010 17:04:23 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03118.SPE 9.76 vol-% wet 0.0026 24.043/18/2010 17:05:23 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03119.SPE 9.72 vol-% wet 0.0025 23.013/18/2010 17:06:24 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03120.SPE 9.72 vol-% wet 0.0026 16.453/18/2010 17:07:25 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03121.SPE 9.73 vol-% wet 0.0026 16.583/18/2010 17:08:25 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03122.SPE 13.85 vol-% wet 0.0031 24.883/18/2010 17:09:26 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03123.SPE 14.73 vol-% wet 0.0037 34.513/18/2010 17:10:27 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03124.SPE 10.05 vol-% wet 0.0028 26.53/18/2010 17:11:27 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03125.SPE 9.83 vol-% wet 0.0028 16.583/18/2010 17:12:28 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03126.SPE 9.76 vol-% wet 0.0027 16.433/18/2010 17:13:29 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03127.SPE 9.64 vol-% wet 0.0027 15.063/18/2010 17:14:29 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03128.SPE 9.72 vol-% wet 0.0026 15.763/18/2010 17:15:30 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03129.SPE 9.69 vol-% wet 0.0027 15.833/18/2010 17:16:30 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03130.SPE 9.96 vol-% wet 0.0028 15.813/18/2010 17:17:31 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03131.SPE 9.89 vol-% wet 0.0027 15.163/18/2010 17:18:32 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03132.SPE 9.86 vol-% wet 0.0028 15.33/18/2010 17:19:32 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03133.SPE 9.79 vol-% wet 0.0028 14.553/18/2010 17:20:33 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03134.SPE 12.09 vol-% wet 0.0024 16.263/18/2010 17:21:33 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03135.SPE 10.07 vol-% wet 0.003 16.913/18/2010 17:22:34 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03136.SPE 9.98 vol-% wet 0.0029 14.573/18/2010 17:23:35 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03137.SPE 9.89 vol-% wet 0.0028 13.73/18/2010 17:24:35 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03138.SPE 9.77 vol-% wet 0.0027 13.983/18/2010 17:25:36 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03139.SPE 9.79 vol-% wet 0.0027 13.453/18/2010 17:26:37 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03140.SPE 9.75 vol-% wet 0.0026 14.023/18/2010 17:27:37 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03141.SPE 9.67 vol-% wet 0.0026 13.963/18/2010 17:28:38 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03142.SPE 12.32 vol-% wet 0.0025 15.563/18/2010 17:29:38 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03143.SPE 9.99 vol-% wet 0.0028 22.73/18/2010 17:30:39 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03144.SPE 9.64 vol-% wet 0.0026 16.353/18/2010 17:31:39 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03145.SPE 9.54 vol-% wet 0.0025 14.373/18/2010 17:32:40 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03146.SPE 9.54 vol-% wet 0.0026 14.113/18/2010 17:33:41 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03147.SPE 9.56 vol-% wet 0.0025 14.683/18/2010 17:34:41 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03148.SPE 9.57 vol-% wet 0.0026 15.133/18/2010 17:35:42 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03149.SPE 11.93 vol-% wet 0.0022 23.393/18/2010 17:36:42 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03150.SPE 9.82 vol-% wet 0.0026 24.543/18/2010 17:37:43 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03151.SPE 9.74 vol-% wet 0.0026 15.733/18/2010 17:38:44 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03152.SPE 9.7 vol-% wet 0.0025 23.33/18/2010 17:39:44 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03153.SPE 9.7 vol-% wet 0.0025 22.973/18/2010 17:40:45 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03154.SPE 9.7 vol-% wet 0.0025 16.293/18/2010 17:42:43 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03155.SPE 9.44 vol-% wet 0.0022 22.973/18/2010 17:43:02 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03156.SPE 9.39 vol-% wet 0.0024 26.32Averages17.58Unit CompensaResidual SF6 Unit CompensaResidualppm wet 0.0061 0 ppm wet 0.0081ppm wet 0.0059 0 ppm wet 0.0091ppm wet 0.006 0 ppm wet 0.0087ppm wet 0.0059 0 ppm wet 0.0094ppm wet 0.0058 0 ppm wet 0.0098ppm wet 0.0055 0 ppm wet 0.0094ppm wet 0.0054 0 ppm wet 0.0088ppm wet 0.0052 0 ppm wet 0.0087ppm wet 0.0045 0 ppm wet 0.0357ppm wet 0.0046 0 ppm wet 0.0166ppm wet 0.0048 0 ppm wet 0.0109ppm wet 0.0051 0 ppm wet 0.0094ppm wet 0.0054 0 ppm wet 0.0091ppm wet 0.0056 0 ppm wet 0.0094ppm wet 0.006 0 ppm wet 0.0087ppm wet 0.0062 0 ppm wet 0.0087ppm wet 0.0065 0 ppm wet 0.0091ppm wet 0.0074 0 ppm wet 0.0089ppm wet 0.009 0 ppm wet 0.0085ppm wet 0.0101 0 ppm wet 0.0082ppm wet 0.0103 0 ppm wet 0.0089ppm wet 0.01 0 ppm wet 0.0096ppm wet 0.0096 0 ppm wet 0.0101ppm wet 0.0088 0 ppm wet 0.0095ppm wet 0.0081 0 ppm wet 0.0104ppm wet 0.008 0 ppm wet 0.0098ppm wet 0.0075 0 ppm wet 0.0211ppm wet 0.0068 0 ppm wet 0.035ppm wet 0.0076 0 ppm wet 0.0153ppm wet 0.0073 0 ppm wet 0.0121ppm wet 0.0071 0 ppm wet 0.0113ppm wet 0.0071 0 ppm wet 0.0109ppm wet 0.0071 0 ppm wet 0.0107ppm wet 0.0071 0 ppm wet 0.0105ppm wet 0.0071 0 ppm wet 0.0113ppm wet 0.0069 0 ppm wet 0.0112ppm wet 0.0069 0 ppm wet 0.0113ppm wet 0.0066 0 ppm wet 0.0108ppm wet 0.0065 0 ppm wet 0.0166ppm wet 0.0063 0 ppm wet 0.0143ppm wet 0.0062 0 ppm wet 0.0119ppm wet 0.006 0 ppm wet 0.0124ppm wet 0.0059 0 ppm wet 0.0112ppm wet 0.0059 0 ppm wet 0.0111ppm wet 0.006 0 ppm wet 0.0108ppm wet 0.0062 0 ppm wet 0.0111ppm wet 0.0063 0 ppm wet 0.0157ppm wet 0.0062 0 ppm wet 0.0144ppm wet 0.0061 0 ppm wet 0.0119ppm wet 0.0061 0 ppm wet 0.0104ppm wet 0.006 0 ppm wet 0.0094ppm wet 0.0064 0 ppm wet 0.0083ppm wet 0.0068 0 ppm wet 0.0085ppm wet 0.007 0 ppm wet 0.0136ppm wet 0.007 0 ppm wet 0.0126ppm wet 0.007 0 ppm wet 0.0089ppm wet 0.0081 0 ppm wet 0.0084ppm wet 0.0082 0 ppm wet 0.0086ppm wet 0.0076 0 ppm wet 0.0089ppm wet 0.0077 0.09 ppm wet 0.0057ppm wet 0.0082 0 ppm wet 0.0041HCL LehighSm --Spiked DataDate Method Filename HCl(ppm) SF6 (ppm)03/18/10 321 C:\CalcmetSamples\L 25.91 C:\CalcmetSam0.5603/18/10 321 C:\CalcmetSamples\L 32.23 C:\CalcmetSam0.9303/18/10 321 C:\CalcmetSamples\L 28.00 C:\CalcmetSam0.88Avg. Conc. (ppm)28.710.790Su -- Native Conc. Of analyteDate Method Filename HCl(ppm) SF6 (ppm)03/18/10 321 C:\CalcmetSamples\L 16.29 C:\CalcmetSam003/18/10 321 C:\CalcmetSamples\L 22.97 C:\CalcmetSam0.0903/18/10 321 C:\CalcmetSamples\L 26.32 C:\CalcmetSam0Avg. Conc. (ppm)21.860.030Sm - Su(1-DF)Recovery (%) = DF x CsCe = DF x Cs + Su(1-DF)Sm 28.71ppm Mean concentration of spiked analyteSu 21.86ppm Native concentration of analyteDF 7.6% % Dilution Factor (Target < 10%)Cs 144.2ppm Cylinder of spiked gas9.98ppm Cylinder of tracer gas (SF6)Ce 31.18ppm Expected concentration of analyteRecovery (%)77.6%70 - 130 %Date Time SpectrumFWater vapoUnit CompensaResidual HydrogencUnit CompensaResidual SF6 Unit3/18/2010 17:43:16 C:\Calcmet9.36 vol-% wet 0.0028 24.75 ppm wet 0.0084 0.01 ppm3/18/2010 17:43:37 C:\Calcmet9.48 vol-% wet 0.0024 25.91 ppm wet 0.0082 0 ppm3/18/2010 17:43:55 C:\Calcmet9.41 vol-% wet 0.003 32.23 ppm wet 0.0082 0 ppm3/18/2010 17:44:11 C:\Calcmet9.36 vol-% wet 0.0026 28 ppm wet 0.0087 0 ppm3/18/2010 17:44:50 C:\Calcmet9.4 vol-% wet 0.0022 25.04 ppm wet 0.0083 0 ppm3/18/2010 17:44:53 C:\Calcmet9.46 vol-% wet 0.0028 24.47 ppm wet 0.0089 0 ppm3/18/2010 17:44:56 C:\Calcmet9.45 vol-% wet 0.0027 23.92 ppm wet 0.0084 0 ppm3/18/2010 17:44:59 C:\Calcmet9.46 vol-% wet 0.0022 17.29 ppm wet 0.0084 0.43 ppm3/18/2010 17:45:02 C:\Calcmet9.35 vol-% wet 0.0026 5.28 ppm wet 0.0079 0.56 ppm3/18/2010 17:45:25 C:\Calcmet9.05 vol-% wet 0.0021 2.5 ppm wet 0.0069 0.93 ppm3/18/2010 17:45:30 C:\Calcmet9.19 vol-% wet 0.002 0.74 ppm wet 0.0074 0.88 ppmCompensaResidualwet 0.0059wet 0.0052wet 0.0046wet 0.0055wet 0.006wet 0.007wet 0.006wet 0.0061wet 0.0053wet 0.006wet 0.0066Date Time SpectrumFile Water vapoUnit CompensaResidual3/18/2010 18:03:23 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan After_03339.SPE 0 vol-% wet 0.00093/18/2010 18:03:26 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan After_03340.SPE 0.01 vol-% wet 0.00063/18/2010 18:03:29 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan After_03341.SPE 0 vol-% wet 0.0013/18/2010 18:22:28 C:\CalcmetSamples\Lehigh 210158\20100318\CTS SCan After_03465.SPE 0 vol-% wet 0.0013/18/2010 18:22:31 C:\CalcmetSamples\Lehigh 210158\20100318\CTS SCan After_03466.SPE 0 vol-% wet 0.00083/18/2010 18:22:36 C:\CalcmetSamples\Lehigh 210158\20100318\CTS SCan After_03467.SPE 0 vol-% wet 0.00123/18/2010 18:22:41 C:\CalcmetSamples\Lehigh 210158\20100318\CTS SCan After_03468.SPE 0 vol-% wet 0.00073/18/2010 18:22:44 C:\CalcmetSamples\Lehigh 210158\20100318\CTS SCan After_03469.SPE 0 vol-% wet 0.00073/18/2010 18:22:46 C:\CalcmetSamples\Lehigh 210158\20100318\CTS SCan After_03470.SPE 0.01 vol-% wet 0.00063/18/2010 18:22:50 C:\CalcmetSamples\Lehigh 210158\20100318\CTS SCan After_03471.SPE 0 vol-% wet 0.00073/18/2010 18:22:52 C:\CalcmetSamples\Lehigh 210158\20100318\CTS SCan After_03472.SPE 0 vol-% wet 0.00133/18/2010 18:22:55 C:\CalcmetSamples\Lehigh 210158\20100318\CTS SCan After_03473.SPE 0 vol-% wet 0.00083/18/2010 18:23:00 C:\CalcmetSamples\Lehigh 210158\20100318\CTS SCan After_03474.SPE 0 vol-% wet 0.00063/18/2010 18:23:03 C:\CalcmetSamples\Lehigh 210158\20100318\CTS SCan After_03475.SPE 0 vol-% wet 0.00073/18/2010 18:23:06 C:\CalcmetSamples\Lehigh 210158\20100318\CTS SCan After_03476.SPE 0 vol-% wet 0.00063/18/2010 18:23:11 C:\CalcmetSamples\Lehigh 210158\20100318\CTS SCan After_03477.SPE 0.04 vol-% wet 0.00073/18/2010 18:23:14 C:\CalcmetSamples\Lehigh 210158\20100318\CTS SCan After_03478.SPE 0 vol-% wet 0.00113/18/2010 18:23:17 C:\CalcmetSamples\Lehigh 210158\20100318\CTS SCan After_03479.SPE 0 vol-% wet 0.00073/18/2010 18:23:24 C:\CalcmetSamples\Lehigh 210158\20100318\CTS SCan After_03480.SPE 0 vol-% wet 0.00043/18/2010 18:23:29 C:\CalcmetSamples\Lehigh 210158\20100318\CTS SCan After_03481.SPE 0 vol-% wet 0.00123/18/2010 18:23:33 C:\CalcmetSamples\Lehigh 210158\20100318\CTS SCan After_03482.SPE 0 vol-% wet 0.00143/18/2010 18:23:36 C:\CalcmetSamples\Lehigh 210158\20100318\CTS SCan After_03483.SPE 0 vol-% wet 0.00073/18/2010 18:23:45 C:\CalcmetSamples\Lehigh 210158\20100318\CTS SCan After_03484.SPE 0 vol-% wet 0.00043/18/2010 18:23:50 C:\CalcmetSamples\Lehigh 210158\20100318\CTS SCan After_03485.SPE 0.04 vol-% wet 0.00063/18/2010 18:23:53 C:\CalcmetSamples\Lehigh 210158\20100318\CTS SCan After_03486.SPE 0 vol-% wet 0.0008AveragesHydrogencUnit CompensaResidual SF6 Unit CompensaResidual5.4 ppm wet 0.0005 0 ppm wet 0.00263.1 ppm wet 0.0006 0 ppm wet 0.00273.2 ppm wet 0.0005 0 ppm wet 0.0008143.07 ppm wet 0.001 0 ppm wet 0.0026143.45 ppm wet 0.0009 0 ppm wet 0.0085143.65 ppm wet 0.0007 0 ppm wet 0.0126143.16 ppm wet 0.0007 0 ppm wet 0.0025145.25 ppm wet 0.001 0.03 ppm wet 0.002144.07 ppm wet 0.0008 0.02 ppm wet 0.0036143.5 ppm wet 0.0008 0 ppm wet 0.003144.83 ppm wet 0.001 0 ppm wet 0.0021143.7 ppm wet 0.0011 0.04 ppm wet 0.0015145.41 ppm wet 0.0011 0 ppm wet 0.0009142.6 ppm wet 0.001 0 ppm wet 0.0017144.26 ppm wet 0.0008 0 ppm wet 0.0035144.27 ppm wet 0.0007 0 ppm wet 0.0029143.24 ppm wet 0.0008 0 ppm wet 0.0049142.77 ppm wet 0.0007 0 ppm wet 0.0014143.7 ppm wet 0.0013 0.04 ppm wet 0.003142.86 ppm wet 0.001 0 ppm wet 0.0059143.79 ppm wet 0.0009 0 ppm wet 0.0028144.44 ppm wet 0.0008 0.01 ppm wet 0.0026144.66 ppm wet 0.0005 0 ppm wet 0.0052143.39 ppm wet 0.0009 0.06 ppm wet 0.0039144.55 ppm wet 0.001 0.06 ppm wet 0.002144.166Date Time SpectrumFWater vapoUnit CompensaResidual HydrogencUnit CompensaResidual SF6 Unit3/18/2010 9:20:42 C:\Calcmet0 vol-% wet 0.0007 1 ppm wet 0.0003 0 ppm3/18/2010 9:20:48 C:\Calcmet0 vol-% wet 0.0009 0 ppm wet 0.0003 0 ppm3/18/2010 9:20:54 C:\Calcmet0 vol-% wet 0.0008 0 ppm wet 0.0004 0 ppm3/18/2010 9:21:00 C:\Calcmet0 vol-% wet 0.001 0 ppm wet 0.0002 0 ppm3/18/2010 9:21:06 C:\Calcmet0 vol-% wet 0.0004 0 ppm wet 0.0003 0 ppm3/18/2010 9:21:12 C:\Calcmet0 vol-% wet 0.0007 0 ppm wet 0.0003 0 ppm3/18/2010 9:21:18 C:\Calcmet0 vol-% wet 0.0006 0 ppm wet 0.0002 0 ppm3/18/2010 9:21:24 C:\Calcmet0 vol-% wet 0.0008 0 ppm wet 0.0003 0 ppm3/18/2010 9:21:30 C:\Calcmet0 vol-% wet 0.0008 0 ppm wet 0.0003 0 ppm3/18/2010 9:21:36 C:\Calcmet0 vol-% wet 0.0009 0 ppm wet 0.0003 0 ppm3/18/2010 9:21:41 C:\Calcmet0 vol-% wet 0.0006 0 ppm wet 0.0003 0 ppm3/18/2010 9:21:47 C:\Calcmet0 vol-% wet 0.0006 0 ppm wet 0.0003 0 ppm3/18/2010 9:21:53 C:\Calcmet0 vol-% wet 0.0005 0 ppm wet 0.0003 0 ppm3/18/2010 9:21:59 C:\Calcmet0 vol-% wet 0.0005 0 ppm wet 0.0003 0 ppmCompensaResidualwet 0.0023wet 0.0014wet 0.0023wet 0.0019wet 0.0032wet 0.0021wet 0.0023wet 0.0041wet 0.0008wet 0.0015wet 0.004wet 0.0015wet 0.002wet 0.0027