From: Barnett.Keith@epamail.epa.gov

Sent: Thursday, April 01, 2010 11:19 AM

To: Laney, Michael N.

Subject: Data for Lehigh, Leeds Alabama

Attachments: 3‐12‐10  210158A Lehigh ‐ Cement MACT & TPM Protocol.pdf; CC‐ 

184196 HCL 144.2PPM.pdf; Cement MACT ‐ Reporting.xls; Field Data  

Sheets.pdf; FTIR Data Lehigh mill on 210158.xls; FTIR Lehigh 210158  

mill off.xls; Manual Method Equipment Calibrations.pdf; O2 CAL  

DATA.pdf; O2 DATA.pdf

Keith W. Barnett  

USEPA/OAQPS/SPPD/MMG  

Mail Code D243‐02  

Research Triangle Park, NC  27711  

919‐541‐5605  

barnett.keith@epa.gov
March 12, 2010 

Mr. Joel Yeager 

Lehigh Cement Company 

8401 Second, Ave. 

Leeds, Alabama 35094 

Re: Updated Protocol for Cement MACT Emissions Testing 

- Main Kiln Stack - Flows & Moisture, O2, CO2 & Hydrogen Chloride 

- Main Kiln Stack - Total Particulate Matter (Filterable & Condensible) 

 Leeds Alabama Facility 

 Entec Project No.: 210158A 

Dear Mr. Yeager, 

Please find attached the updated protocol for the upcoming Cement MACT testing based on 

information requested by EPA. Additional testing has been requested for operational purposes 

for Total Particulate Matter (TPM). The protocol outlines the additional scope of work, test 

procedures, QA/QC requirements, example calculations, and support documentation as 

required. Lehigh Cement Company (Lehigh) will supply any facility operation parameters to 

meet EPA final reporting requirements as needed. Testing has been scheduled for March 17 & 

18, 2010. 

If you should have any additional questions about the protocol please call me at (205) 491-

6676. 

Sincerely, 

Entec Services Inc. 

D. Lynn Beane 

Birmingham - Operations Manager 

 * Baton Rouge, LA * * Birmingham, AL * * Mobile, AL * * Raleigh (RTP), NC * 

 1-800-429-8445 www.entecservices.com 
Project Overview 

Entec Services will conduct testing per the requirements based on the information provided by 

Lehigh, as set by information required by EPA in the ICR 114 letter - Cement MACT. The 

purpose of the testing will be to meet data collection requirements as set by EPA. This protocol 

outlines the detailed scope of work, test procedures, QA/QC requirements, example 

calculations, and support documentation as required. Lehigh will supply all facility operation 

parameters to meet final permitting requirements, and are responsible for all fuel analysis. 

Testing will be conducted at the Lehigh facility - Main Kiln Stack. Testing will be conducted with 

multiple sampling systems with testing being conducted simultaneously as required from 

multiple sample ports. The test team will consist of a three (3) man team including an on-site 

FTIR Manager Mr. Erik Groth. 

Additional particulate matter (PM) testing has been requested to assist with the optimization of 

the lime injection system. Entec will conduct testing at two operating conditions for the 

determination of total particulate matter (TPM). TPM testing will be conducted after the 

completion of the Cement MACT testing. 

Project Scope of Work & Objective

Testing will be conducted on the identified unit to include EPA Test Methods 1-4 (Flows & 

Moistures), 3A (Oxygen & Carbon Dioxide), and 321 (Hydrogen Chloride). All methods will be 

followed according to Title 40, Code of Federal Regulations, Part 60 Appendix A for the duration 

of this test program. The proposed test program will take a minimum of two (2) test days to 

complete with multiple operation conditions - “Mill On” & “Mill Off” as required. The testing will 

consist of a minimum of three (3) - one (1) hour test runs at each condition. The test program 

will require multiple sampling trains conducted simultaneously as required by the Cement MACT 

Table 1. Entec will arrive on site the day prior to the scheduled test plan to conduct site safety 

requirements, setup test equipment, and perform preliminary test requirements. The following 

table summarizes the reference methods, run durations, and frequency. 

Testing will be conducted on the identified unit to include EPA Test Methods 1-4 (Flows & 

Moistures), OTM 027 (Particulate - PM10), and OTM 028 (Condensible PM). All methods will 

be followed according to Title 40, Code of Federal Regulations, Part 60 Appendix A or other 

approved test methods for the duration of this test program. The proposed test program will 

take a minimum of two (2) test days to complete with multiple operation conditions - Mill Off - 2.0 

TPH & Mill Off - 2.5 TPH as required. The testing will consist of a minimum of three (3) - one (1) 

hour test runs at each condition. 
Facility Description and Plant Operations 

Lehigh is a subsidiary of Lehigh Cement Company, Allentown, Pennsylvania. Lehigh 

manufactures Portland and specialty cement by the dry process (SIC 3241). All of the limestone 

used in cement manufacturing is mined from the quarry adjacent to the Cement Plant. The 

quarry and plant are located in Section 21, Township 17 South, Range 1 East in Leeds, 

Alabama at latitude 33o 32’ 21” and longitude 86o 32’ 30”.

Methodology 

Entec Services, Inc. proposes to test the identified source per constituents listed in Table 1 in 

accordance with USEPA, 40 Part 60 Appendix A Reference Methods or other alternate 

approved methods for the entire duration of this test program to meet the requirements in the 

identified scope of work and objective. 

The calibration and quality assurance procedures of all EPA test methods used in this test 

program of the ”Quality Assurance Handbook for Air Pollution Measurement System” Volume III 

Stationary Source-Specific Methods will be followed throughout the duration of all field testing 

and laboratory analysis. The most current CFR revision of each method (July 1, 2008) will be 

used. 

Table 1 

Proposed Test Methodology 

Parameters 

40 CFR, 

Appendix A or 

Approved Test 

Method 

Sample 

Technique 

Duration 

(minutes) Frequency 

Additional 

Information 

Velocity / 

Volumetric Flow Method 1 & 2 Type S pitot tube 60 minutes 

3 runs / per 

condition 

lbs / hour 

calculations 

Oxygen Method 3A 

Constant rate 

extractive sampling 

and or Tedlar Gas 

Bags 60 minutes 

3 runs / per 

condition O2 Correction 

Carbon Dioxide Method 3A 

Constant rate 

extractive sampling 

and or Tedlar Gas 

Bags 60 minutes 

3 runs / per 

condition O2 Correction 

Moisture Content Method 4 Impinger Train 60 minutes 

3 runs / per 

condition 

Conducted 

with each test 
Hydrogen Chloride Method 321 

Constant rate 

extractive sampling 60 minutes 

3 runs / per 

condition FTIR Method 

PM 10 OTM 027 

Constant rate 

sampling 60 minutes 6 runs 

2 Conditions 

w/ Lime 

Injection rates 

adjusted 

Condensible PM OTM 028 

Constant rate 

sampling 60 minutes 6 runs 

2 Conditions 

w/ Lime 

Injection rates 

adjusted 

Lab - Analytical

Entec will utilize our internal lab as well as other labs to conduct and meet the analytical 

sampling requirements. The following labs have been identified with each constituent listed. 

 - Entec Services - Moisture Determination 

 - Entec Services - Filterable & Condensible Particulate Matter 

Test Method Description 

Sampling Point Determination - Method 1

The sample point selection and traverse points will be selected and performed according to EPA 

Reference Method 1. The method will provide a representative measurement site of pollutant 

emissions from a stationary source. The cross section of the source is divided into a number of 

equal areas, and the traverse points are then located within the center of each of these areas. 

Physical measurements are taken on-site to determine the actual stack diameter including 

upstream and downstream disturbance locations. These measurements will calculate traverse 

point locations based on the tables supplied in the method. 

Stack Gas Volumetric Flow - Method 2

The velocity of the gas stream will be determined according to EPA Reference Method 2 by 

reading the instantaneous velocity head with an inclined manometer at each sampling point with 

a calibrated S-type pitot tube attached adjacent to the sample nozzle. The stack pressure will 

be measured with the static side of an S-type pitot tube. A calibrated pyrometer will be used to 

measure stack temperature at each sampling point. The verification of the absence of cyclonic 

flow will be conducted during the initial preliminary velocity measurements as required. 

Stack Gas Molecular Weight - Method 3A

The carbon dioxide and oxygen concentrations will be determined using EPA Reference Method 

3A. A sample will be continuously extracted at a constant rate from the effluent stream. The 
sample will be conditioned and conveyed to an instrument for determination of the gas 

concentration in accordance with EPA Method 3A. 

Moisture Content - Method 4

The moisture content used for calculating the gas stream (dry basis) flow rate will be determined 

by measuring the amount of condensed moisture in the series of impingers in the sampling train 

as described in EPA Reference Method 4 at the completion of each test. The moisture content 

will be conducted in conjunction with EPA Method 5. Ice will be placed around the impingers, 

with the outlet temperature of the impingers monitored and recorded throughout the duration of 

the testing to verify the temperature is less than 68o

 F. 

Hydrogen Chloride (Method 321) 

Method 321 will be utilized for the determination of hydrogen chloride concentrations using a 

Fourier transformed infrared (FTIR) spectroscopy Process Gas Analyzer manufactured and 

supplied by Temet Instrument Company of Helsinki, Finland. 

The gas samples will be extracted from the gas stream through a titanium probe and heated 

sample line and plumbed directly to the FTIR process gas analyzer. The sample does not have 

to be conditioned since it will be heated to 180 °C before analyzing the gas stream. 

Measurements will be taken for moisture and the listed targeted compounds. 

The FTIR and sampling equipment will be assembled and allowed to stabilize at a temperature 

of 180 °C. The pretest preparations included selecting the appropriate reference spectra for the 

anticipated target concentrations and the optimum sampling system configuration for measuring 

the target analytes. Once the system is at temperature a leak check of the sampling system will 

be performed. Then a baseline determination will be performed using nitrogen for a zero check. 

This will be to determine the level of background noise. We will then perform a Pre test 

Calibration Transfer Standard (CTS) to evaluate the spectral response and stability of the 

instrument using a certified gas. A method validation procedure will be performed using a 

series of spiked and un-spiked samples from the flue gas before and after each test run. To 

assure that the spike system will be operating correctly, certified gases for each of the 

referenced components will be used. This procedure will determine that the method will be valid 

with no bias. At the end of the test a post test Calibration Transfer Standard (CTS) will agreed 

within 5% of pretest CTS to validate the test data 

EPA OTM METHOD 027 – PM10

The sample train consists of a stainless steel sample probe and liner equipped with a S-type 

pitot tube and thermocouple. The probe is attached to a sample module consisting of a PM10 

head equipped with an in-stack sizing device (cyclone) and a pre-weighed glass fiber filter for 
the collection of the particulate. The sizing device separates the particles with nominal 

aerodynamic diameter of less than 10 microns. The sample module is connected to a series of 

impingers to remove moisture and to capture condensible particulate. The control module 

consist of a dry gas meter, calibrated orifice, leak free pump, two inclined manometers, 

temperature controllers for the heated probe and a thermocouple indicator to monitor the 

required temperatures during the testing. 

Prior to sampling, a velocity traverse was performed on the source to provide information to 

calculate the appropriate nozzle size and sample rate based on the OTM 027 calculations. 

Particulate samples are collected as follows: The sample gas is drawn through the sampling 

probe isokinetically (100% + 20) at a constant rate and passed into the PM10 cyclone knocking 

out the particulate greater than 10 microns. The cut point for the captured particulate is 

between 9.0 and 11.0 for PM10. The sample gas is then pulled through the impinger train. The 

sample gas then passes through a vacuum pump followed by a dry gas meter. The dry gas 

meter integrates the sample gas flow throughout the duration of the test. A calibrated orifice was 

attached to the outlet of the dry gas meter provides real time flow rate data. 

A pretest leak-check of the entire assembled sample system is conducted by plugging the inlet 

to the probe nozzle and pulling a vacuum of at least 10 in. Hg. A leak rate less than 0.02 cfm is 

determined and considered acceptable as outlined in 40 CFR 60. The pitot tube system is leak 

checked at 2 to 3 inches of water column. The traverse points are marked on the probe for 

easy visibility. 

A representative particulate sample is acquired by sampling for prorated periods of time at the 

centroid of a number of equal area regions in the exhaust stack. The sampling rate is to remain 

constant at each test point maintaining an Isokinetic sampling condition for OTM Method 027. A 

total of 12 traverse points were used for sampling. 

The temperature controllers for the probe is set to maintain the temperature to 248 ± 25o F. 

Upon achieving operating temperature of the sample train and equilibration of the probe to the 

stack gas temperature, the nozzle tip is positioned toward the stack gas stream. The sample 

pump is started and the flow adjusted to a suitable pressure drop over the dry gas meter in 

order to sample under Isokinetic conditions. After the required time interval elapses, the probe 

tip was repositioned to the next traverse point. Stack gas temperature, and sample train 

measurements are taken at equal spaced intervals for each traverse point. At the conclusion of 

the traverse of the first port, the pump is stopped, and the sample train is repositioned to the 

subsequent sample port(s). This technique is followed for all traverse points and sample ports 

throughout the entire test period. 
At the conclusion of the test run, the sample pump is turned off, and the final sample train 

measurements are recorded. Once the sample head was removed, a final leak check of the 

probe and sample train at the highest vacuum observed during the test was performed. The 

final leak checks are determined to be within the guidelines outlined in OTM Method 027. 

After the sampling is completed, the particulate recovery is performed. The particulate 

recovery involves the quantitative transfer of particles in the following size range: (1) greater 

than 10 micrometers. The filter is removed and placed in a storage container for shipment back 

to the laboratory for analysis of the cyclone I (PM10) cup, cyclone I internal surfaces, and the 

internal surface of the nozzle were rinsed with acetone and placed in a storage container for the 

analysis of equal to and greater than PM10. The rinses of the cyclone I turnaround cup, the 

inside of the downcomer line, and the interior surfaces of the cyclone IV were rinsed with 

acetone and placed in a storage container for the analysis of less than PM10 and greater than 

PM2.5. The exit tube of cyclone IV and the front half of the filter holder were rinsed with acetone 

for the analysis of total PM. The 100 ml blank acetone, distilled in glass grade, sample is also 

taken and stored in a marked container. The samples will be transferred back to the laboratory 

where they are logged in and analyzed. Test date, sample identification, and the laboratory 

performing the analyses will be all identified on the chain of custody worksheet. 

ALTERNATE METHOD 028 (CONDENSABLE PM - DRY IMPINGER)

The sampling and analytical procedures for collection of condensable emissions will be 

conducted in accordance with Other Test Method 028. The sampling equipment will consist of 

the following equipment and components of the impinger train - the module contains a Method 

23 type stack gas condenser to cool the stack gas to less than 30°C (85°F) followed by two dry 

impingers in an insulated box with water at ≤ 30°C (≤ 85°F) then a CPM filter and finally a 

moisture trap system. The first impinger is a drop out with a short stem and the second 

impinger is a modified Greenburg Smith impinger with no .taper. The connection between the 

CPM filter and the moisture trap impinger includes a thermocouple fitting that provides a leakfree seal between the thermocouple and the stack gas. The moisture trap consisted of one 

modified Greenburg-Smith impinger containing 100 mL of water, followed by an impinger 

containing approximately 200-300 grams of silica gel. 

All sampling train glassware will be cleaned before mobilization to the facility with soap and 

water, and rinsed using tap water, deionized water, acetone, and finally, MeCl2. After cleaning, 

the glassware is baked at 300°C for 6 hours. Prior to each sampling run the train glassware 

used to collect condensable particulate matter will be rinsed thoroughly with deionized, distilled 

ultra-filtered water that conformed to ASTM D1193-06, Type 1. 
Prior to conducting the test series, a field train blank was recovered by assembling the sample 

train as it will be used for testing. 100 mL of water is added to the first impinger and the sample 

train will be purged with filtered nitrogen for one hour. The field train blank samples will be 

recovered and used to determine the blank correction or sample weight will be subtracted from 

the condensable particulate mass determined with each run. This blank train value will be no 

greater than 0.002 g (2.0 mg). Reagent blanks will be taken of the water, acetone, and 

Methylene chloride used for field recovery and samples are prior to mobilization to the facility. 

The condensable sample train will be prepared in the following manner: 1) no water in the first 

and second impingers; 2)a filter placed in the CPM filter holder, 3) the third impinger will contain 

100ml of water; and, 4) approximately 200 g of silica gel (indicating type, 6-16 Mesh) will be 

added to the fourth impinger. The dropout and the second impinger are place in an insulated 

box with water at ≤ 30°C (≤ 85°F). The CPM filter holder is attached to the second impinger and 

the first impinger in the moisture trap section. The connection between the CPM filter and the 

moisture trap impinger includes a thermocouple fitting that provides a leak-free seal between 

the thermocouple and the stack gas. The condenser will be connected to the dropout impinger 

and the exit of the Method 5 sample train. The submersible pump is turned on to deliver cool 

water from the ice bath to the condenser. The moisture trap section is contained in a ice bath 

with the exit temperature from the silica gel monitored during the test. A pretest leak-check of 

the entire assembled sample system is conducted by plugging the inlet to the probe nozzle and 

pulling a vacuum of at least 10 in. Hg. A leak rate less than 0.02 cfm was determined and 

considered acceptable. 

At the conclusion of the test run, the sample pump is turned off, and the final samples train 

measurements will be recorded (see Method 5). A final leak check of the test train will be 

performed at the conclusion of every test run as previously described at the highest vacuum 

encountered during the sampling period. At the conclusion of the sample train leak check, the 

particulate will be recovered as described in Method 5 and the condensable particulate section 

of the sample train will be transferred to the cleanup area. 

The first impinger (dropout) will be inspected to determine if any water is present. The dropout 

stem is removed and replaced with a non-tapered modified Greenburg Smith stem. The 

condensable system is connected to a filtered nitrogen tank and nitrogen is allowed to flow 

through the system at a rate of 20 l/min for a period of one hour. The gas temperature exiting 

the CPM filter is monitored and did not exceed 85°F. 

After the purge of each impinger it is weighed to within + 1ml or + 0.5 g and recorded. The 

flowing procedure is used to recover the liquids and filter in the condensable sample train. 

Container No. 1 (glass bottle) is quantitatively transfer the liquid from the dropout and impinger 
prior to the CPM filter into a clean sample bottle. Rinse the condenser, each impinger, the 

connecting glassware, and the front half of the CPM filter housing twice with Type I water. Mark 

the liquid level on the bottle. Container No. 2 (glass bottle) follows the water rinses of the 

condenser, each impinger, all of the connecting glassware, and the front half of the CPM filter 

with an acetone rinse. Then repeat the entire procedure with two rinses of MeCL2, and save 

both solvents in a separate glass container. Mark the liquid level on the jar. Container No. 3 

contains the filter from the filter holder and placed in its identified petri dish using a pair of 

cleaned tweezers to handle the filter. Seal the container.

The samples are transferred back to the laboratory where they are logged in and analyzed. Test 

date, sample identification, and the laboratory performing the analyses were all identified on the 

chain of custody worksheet. 
QA / QC Procedures 

Specific quality assurance / quality control procedures will be adhered to during this test project 

to provide valid and scientifically defensible data. For any environmental field and laboratory 

measurement, a degree of uncertainty exists in the data due to inherent limitations of the 

measurement systems employed. The objective of a QA/QC program is to produce data of 

known precision, accuracy, representation, completeness and comparability. The objective in 

this test project is to determine compliance with applicable air permit requirements. The final 

data user in this project will be EPA. 

The following section details all QC procedures to be followed during the sampling. 

Velocity / Volumetric Flow Rate - Methods 1 & 2 

Volumetric flow rates will be determined during each isokinetic test run. The following QC steps 

will be adhered to during these tests: 

• Reported duct dimensions will be checked by physical measurements to determine crosssectional duct area. 

• Pitot tube coefficients are determined based on physical measurement techniques as 

delineated in Method 2 before and after each test. 

• The Type-S Pitot tubes are visually inspected before and after sampling. 

• The Pitot tube is installed on the sampling probe with the proper orientation and spacing 

from the sampling nozzle. 

• Before each series of tests, thermocouple reading temperature are checked against an 

N.I.S.T. traceable thermometer. 

• The oil manometer is leveled and zeroed before each test run. 

• Both legs of the Pitot tube are leak-checked before and after sampling. 

• Proper orientation of the Pitot tube is maintained while making measurements. The roll and 

pitch axis of the Pitot tube is maintained at 900

 to the flow. 

• An average velocity pressure reading is recorded at each point instead of recording 

extreme high or low values. 

• The pitot/manometer umbilical lines are inspected before and after sampling for moisture 

condensate. Lines are cleared if moisture is found. 

Oxygen and Carbon Dioxide Determination - Method 3A

 The carbon dioxide and oxygen concentrations are determined using EPA Reference Method 

3A. A sample of the flue gas is extracted from the gas stream during each test. Moisture is 

removed form the gas sample and is analyzed on a dry basis with an instrumental gas analyzer. 

The following QC steps are adhered to during these tests: 

• Only analyzers that have a resolution or sensitivity of at least < 2.0% of full-scale range are 

used. 
• Upon the O2 and CO2 analyzers initial use in the field, an interference check is conducted. 

• The reference calibration gases used in this test program are certified following EPA 

Protocol Number 1 analysis. Copies of the calibration gas certifications will be included in 

the instrument calibration section. 

• The high level gas is equal to the calibration span gas. 

• The mid level gas is between 40 and 60 % of the calibration span gas. 

• The low level gas is < 20% of the calibration span gas. 

• In accordance with EPA Method 3A a three-point (i.e., zero, mid-, and high-range) analyzer 

calibration error is conducted on each reference analyzer prior to initiating the compliance 

testing. These checks are conducted (after final calibration adjustments are made) by 

injecting the calibration gases directly into each gas analyzer and the responses are 

recorded. 

• The analyzer calibration error will be less than + 2.0% or + 0.5 ppm of the calibration span 

gas for the zero, mid-range, and high-range calibration gases. 

• The probe material is made of stainless steel. 

• The probe, filter and sample line temperature is maintained above the dew point by heating, 

prior to sample conditioning. 

• The sampling system bias will be less than + 5.0 % or of the calibration span gas for the 

zero and upscale calibration gases (+ 0.5 ppm absolute difference). 

• The system response time is calculated during the initial sampling system bias. 

• The drift for either the low-level and mid-level or high-level gases will be less than + 3.0% or 

of the calibration span gas (+ 0.5 ppm absolute difference). 

• The sampling system will be purged > 2 times the system response time before each test 

run. 

• Sample flow rate will be maintained within 10% during the entire test period. 

• Data will be recorded at 1-minute intervals. 

• All data collected will be within the calibration span gas. 

Moisture Determination - Method 4 

Stack gas moisture content (Bws) is determined by dividing the mass of moisture collected by the 

impingers or stainless steel condenser and silica gel impinger by the standardized volume of 

gas sampled. The following QC steps are adhered to during these tests:

• The indicating silica gel is fresh for the first run and periodically inspected and replaced 

between runs, as needed. 

• The analytical balance is placed in a clean, motionless environment for weighing and 

standard weights will be used as reference. 

• The balance is leveled and zeroed if necessary before each weighing. 

• Preliminary silica gel impinger tare weights and post-run weights weighed to the nearest 0.1 

g. 
• Before each series of tests, thermocouple readings for the silica gel impinger exit 

temperature are checked against an N.I.S.T. traceable thermometer. 

• The silica gel impinger gas temperature is maintained below 680

F and recorded at every 

traverse point. 

• Each impinger is wiped of surface moisture before post-run weighing. 

• The volume of liquid captured is measured using a graduated cylinder with 1-milliliter 

increments or gravimetrically. 

FT-IR Sampling - Method 321

• Before and after each run a spike and recovery procedure will be performed as outlined by 

EPA method 321. The system biases calculated from the pre- and post-test dynamic 

analyte spiking will be within the +/- thirty percent limit as allowed by EPA Method 321. 

• The spike/tracer gas mixture will be introduced at a constant flow (± 2 percent) rate at less 

than 10 percent of the total sample flow. 

• The spike will be pre-heated before introduction into the sample matrix to prevent a 

localized condensation of the gas stream at the spike introduction point. A heated sample 

line containing multiple transport tubes within the heated bundle will be used to spike gas 

up through the sampling system to the spike introduction point. 

• A calibrated flow device (e.g., mass flow meter/controller), will be used to monitor the spike 

flow as indicated by a calibrated flow meter or controller, or alternately, the SF6 tracer ratio 

may be calculated from the direct measurement and the diluted measurement. 

• A direct-to-cell measurement of the dry, undiluted spike gas will be performed (CTS Scan), 

before each test run. The spike gas will be introduced directly to the FTIR cell, through the 

sampling system. The cell will be filled to 1 atmosphere and collected the spectrum of the 

sample. The spike gas will be equilibrated to the temperature of the measurement cell 

before acquisition of the spectra. The spectrum will be inspected and verified that the gas 

is dry and contained negligible CO2. 

• The process will be repeated to obtain a second measurement after each test run. Analysis 

of spectral band areas for the target compounds from these duplicate measurements will 

agreed to within ± 5 percent of the mean. 

PM10 Sampling – OTM 027 and OTM 028

Accurate fine and coarse particulate concentrations are dependent on the recovery of the 

material from the cyclone and collection of the condensible pollutants from the stack gas by the 

use of a series of impingers and the standardized gas sample volume measured. QC 

procedures that were followed so that representative particulate data will be collected by the 

sampling system are: 

• Only clean, well-maintained sampling equipment will be used. 
• Sampling ports will be inspected and cleaned prior to sampling. 

• The cyclone will meet the design specification of OTM 027. 

• The sampling train components exposed to sample gas will be constructed of glass or 

Teflon for the filterable and condensible material. 

• All glass components of the train will be all cleaned with soap and water, rinsed with water, 

acetone and finally with Methylene chloride. 

• All silicone grease will be removed from the impingers during the initial cleaning of the 

glassware and not used during this test. 

• All equipment will be calibrated according to EPA standards. The dry gas meter will be fully 

calibrated within the past 12 months using a set of calibrated orifices. 

• Accurate barometric pressure will be recorded at least once per day. 

• The dry gas meter thermocouples will be compared to ambient temperature prior to the test 

run as a check on operation. 

• Pretest and post-test leak-checks will be completed (must be less than 0.02 cfm or 4% of 

the average sampling rate). 

• Before each series of tests, thermocouple readings for meter temperature, probe, and filter 

exit temperatures will be checked against an N.I.S.T. traceable thermometer. 

• Readings of the dry gas meter, meter orifice pressure (ΔH), meter temperatures, and probe 

temperatures will be taken at every traverse point. 

• The sampling velocity through the nozzle will be maintained within 20% of the stack gas 

velocity (isokinetic sampling rate at 100±20%). 

• The calculated D50 of Cyclone I will be between 9.0 and 11.0 μm. 

• No more than one point will be outside Δpmin and Δpmax. 

• The indicating silica gel will be fresh for the first run and periodically inspected and replaced 

during runs, if needed. 

• All nozzle/probe recovery items will be pre-cleaned and kept in containers when not being 

used. 

• Filter recovery used tweezers to handle the filter, and will be careful to include any filter 

fibers or pieces adhering to the filter holder. 

• The nozzle and cyclone recovery will include wiping the outer surface clean of dust before 

sample recovery. Sample recovery will consist of multiple brushing of the inner surface 

during the recovery operations. Transfer of rinse acetone to the sample container will be 

accomplished without loss of liquid. Nozzle and probe brushes will be rinsed after brushing 

inner surfaces. 

• The analytical balance will be placed in a clean, motionless environment for weighing. 

• The balance will be leveled and zeroed if necessary before each weighing. 

• Analytical balances will be metrological tested against NIST traceable standard weights 

annually by a third party. 

• Each analytical balance will be calibrated before weighing begins. 
• Before weighing filters or beakers the analytical balance will be challenged with a known 

standard mass (500 mg for filters and 100 g for beakers) to verify the balance calibration is 

still valid. 

• Preliminary silica gel impinger tare weights and post-run weights were weighed to the 

nearest 0.1 g. 

• The dry impinger system gas temperature will be maintained below 850

F and recorded at 

every traverse point. 

• The silica gel impinger gas temperature will be maintained below 680

F and recorded at 

every traverse point. 

• Each impinger will be wiped of surface moisture before post-run weighing. 

• The volume of liquid captured will be measured using a graduated cylinder with 1-milliliter 

increments. 

• The capture liquid in the first three impingers will be recovered and place into a container 

for analysis (inorganic). 

• Each impinger and connecting glassware will be rinsed three times with Methylene chloride 

and placed into a separate container for analysis (organic). 

• Liquid levels will be marked on sample containers and sealed for shipment to the 

laboratory. 

• Class A volumetric glassware for titrations will be used. 

• Prior to the initial run a y-factor check will be performed to ensure that the meter will be 

operating according to the original calibration to within 3% of the original y-factor. 

• For the post-test calibration the alternative Method 5 post-test calibration procedure will be 

used (Emission Measurement Center Approved Alternative Method ALT-009). 
NOMENCLATURE 

As Cross-sectional area of stack, square feet 

An Cross-sectional area of nozzle, square feet 

ACFM Actual cubic feet of gas per minute at stack conditions 

Bws Proportion by volume of water vapor in gas stream 

Cs Particulate concentration in stack gas, gr/dscf 

Ca Particulate concentration in stack gas, gr/acf 

Cp Pitot tube coefficient 

∆ H Pressure drop across orifice meter, inches water 

∆ P Velocity head of stack gas, inches water 

dscf Cubic feet of dry gas corrected to standard conditions 

EA Excess Air 

E/Btu Particulate Emission Rate, pounds/mmBtu 

F F-factor, 9640 dscf/MMBTU's of heat input 

Kp Constant (85.49) 

Mn Total particulate matter collected, mg 

Md Molecular weight of stack gas; dry basis, lb/lb-mole 

Ms Molecular weight of stack gas; wet basis, lb/lb-mole 

I Percent of isokinetic sampling 

Pbar Barometric pressure, inches mercury 

Pg Stack static pressure, inches of water 

Pm Barometric pressure of dry gas meter, in. mercury 

PMR Particulate mass rate, pounds/hour 

Ps Absolute stack gas pressure, inches mercury 

Pstd Barometric pressure, standard conditions, 29.92 inches Hg 

Qa Volumetric flow rate, actual conditions, ACF/min 

Qs Volumetric flow rate, standard conditions, scf/min 

Qstd Volumetric flow rate, dry standard conditions, dscf/min 

TBws Theoretical water vapor in the gas stream based on saturated stack conditions, 

proportion by volume (dimensionless) 

TVlc Theoretical volume of water collected based on saturated stack conditions, ml 

TVwstd Theoretical volume of water vapor in the gas sample based on saturated stack 

conditions, corrected to standard temperature and pressure, scf

Tm Absolute average dry gas meter temperature, degree R (460) 

Ts Absolute average stack gas temperature, degree R (460) 

Tstd Absolute temperature at standard conditions, 528 R 

Ө Total sampling time, minutes 

Vlc Total volume collected in impingers and silica gel, gr 

Vm Volume of gas sampled through gas meter, cubic feet 

Vn Volume collected at stack conditions through nozzle, ACF 

Vma Stack gas volume sampled, ACF 

Vmstd Volume of gas sampled through gas meter, cubic feet 

Vs Average stack gas velocity, feet/sec 

Vwcstd Volume of water vapor in gas sampled from impingers, standard cubic feet 

Vwsgstd Volume of water vapor in gas sampled from silica gel, standard cubic feet 

Wimp Total volume collected in impingers, gr 

Wsg Total volume collected in silica gel, gr 

Y Dry gas meter calibration factor 
TEST CALCULATIONS 

EQUATIONS 

 1. Ps = Pbar + (Pg/13.6) = ( ) + ( /13.6) = 

 2. Pm = Pbar + (ΔH/13.6) = ( ) + ( /13.6) = 

 3. Vmstd = 17.64 * Vm * Y * (Pm/Tm) = 17.64*( )*( )*( / ) = 

 

 4a. Vwc(std) = 0.04706 * Wimp = 0.04706*( ) = 

 4b. Vwsg(std) = 0.04715 * Wsg = 0.04715*( ) = 

 5. Bws = Vwstd/(Vmstd+ Vwstd) = ( )/( + ) = 

For saturated sources (No. 6 - 8 only): 

 6. TBws = (106.37- {2827/(ts+365)}/ Ps = 106.37-{2827/( +364.8)}/ ( ) = 

 7. TVwstd = Vmstd*( TBws /1- TBws) = ( )*( )/( 1 - ) = 

 8. TVlc = TVwstd/0.04707 = ( ) / ( ) = 

 9. Md = 0.44(%CO2) + 0.32(%O2) + 0.28((100-(%CO2 + %O2)) 

 = 0.44( ) + 0.32( ) + 0.28[100-( + )] = 

 10. Ms = Md (1- Bws) + 18 Bws = ( )*(1- )+18( ) = 

 11. Vs = 85.49 * Cp* √∆P * √ [Ts / (Ms* Ps)]

 = 85.49*(0.84)*( )*√[( /( )( ))] = 

 

 12. Qa = Vs * As * 60 = ( )( )(60) = 

 13. Qs = Qa * (528/Ts)*(Ps/29.92) = ( )*(528/ )*( /29.92) = 

 14. Qstd = Qa (1- Bws) * (528/Ts)*(Ps/29.92) = ( )(1- )*(528/ )*( /29.92) = 

 15. Cs = 0.01543* (Mn/ Vmstd) = 0.01543*( / ) = 

17. E/Btu = (Cs/7000)*{(Fd*20.9)/(20.9-%O2)} 

 = ( /7000)*{( )*20.9)/(20.9-( )} = 

 

18. %EA = 100%* {(%O2) - 0.5*(%CO)} / {0.264(%N2) - (%O2) + 0.5*(%CO)}

 = 100%*{( )-0.5( )} / {0.264( )-( )+0.5( )} = 

 

 21. PMR = Cs* Qstd (60/7000) = ( )*( )*(60/7000) = 

 

22. Vn = Ts/Ps*{(0.002669) Vlc+ (Vm * Y * Pm)/Tm)} 

 = ( / )*{(0.002669)( )+( )( )( )/( )} = 

 23. Ca = 0.01543* (Mn/ Vn) = 0.01543*( / ) = 

 24. I = Vn100/(60*Ө*Vs*An) = ( )100 / (60)( )( )( ) = 
17

NOMENCLATURE FOR OXYGEN/CARBON DIOXIDE (3A)

ACE = Analyzer calibration error, percent of calibration span. 

CAvg = Average unadjusted gas concentration indicated by recorder for the test run, ppmv. 

CDir = Measured concentration of a calibration gas (low, med, high) when introduced in 

 direct calibration mode, ppmv. 

CGas = Average effluent gas concentration adjusted for bias, ppmv. 

CO = Average of initial and final system calibration bias(or 2-point system calibration 

 error) check responses form the low level (zero) calibration gas, ppmv. 

CM = Average of initial and final system calibration bias (or 2-point system calibration 

 error) check responses for the upscale calibration gas, ppmv. 

CMA = Actual concentration of the upscale calibration gas, ppmv. 

CS = Measured concentration of a calibration gas (low, mid, or high) when introduced in 

 system calibration mode, ppmv. 

Cv = Manufactured certified concentration of a calibration gas (low, mid, or high), ppmv. 

CS = Calibration span, ppmv. 

D = Drift assessment, percent of calibration span. 

SB = System bias, percent of calibration span. 

SBfinal = Post-run system calibration error, percent of calibration span. 

SBi = Pre-run system bias, percent calibration span. 

EQUATIONS FOR O2/CO2 (Method 3A) 

ACE = CDir - Cv X 100 

(7E-1) CS 

 = ( - ) / ( ) X 100 = 

SB = CS - CDir X 100 

(7E-2) CS 

 = ( - ) / ( ) X 100 = 

D = | SBfinal - SBi| = | - | = 

(7E-4) 

CGas = ( CAvg - CO ) x CMA / (CM - CO) 

(7E-5) 

 ( - ) x ( ) / ( - ) = 
18

NOMENCLATURE FOR FT-IR SPIKE

Ce = Expected concentration of analyte, ppm 

Sm = Mean concentration of spiked analyte, ppm 

Su = Native concentration analyte, ppm 

DF = Dilution Factor (Target < 10%), % 

Cs = Cylinder value of spiked or tracer gas 

EQUATIONS FOR SPIKE

Ce = DF x Cs + Su (1-DF) 

 = ( ) x ( ) + {( )[1- ( )]} = 

Recovery % = Sm - Su (1-DF)

 DF x Cs 

 = ( ) – {( )[1- ( )]}

 ( ) x ( ) 

Worksheet Title: HCl Emission Test Results Template Using Method 321

Who Should Complete this Spreadsheet?

Company Name:

Facility Name: Leeds Cement Plant

Address: 8401 Second Ave

City: Leeds

State: Alabama

Kiln ID:

Kiln Type: The kiln is PH

In-line Raw Mill:

Control Device Configuration: 

Parameter

Sample #1Sample #2Sample #3

Test Average

Units

Units Other 

Description

Test Method Used Test Location Note

Select appropriate unit 

from list. If other is 

selected please describe 

units in column H at right. Enter the name of the Test Method used.

Indicate whether the test 

occurred upstream or 

downstream of a control 

device(s); list the control 

device(s)

If kiln has an in-line raw mill, 

indicate raw mill status during tests 

(i.e., raw mill on or raw mill off). 

Provide any other information 

supporting information you think is 

necessary about this test report. 

Sample Date (mm/dd/yyyy) 3/17/2010 3/17/2010 3/17/2010

HCl Concentration - as measured - dry basis 4.89 2.68 2.48 ppmvd 

Oxygen Concentration - dry basis 13.46 13.36 13.36 %

CO2 Concentration - dry basis 13 13 13 %

HCl Concentration - corrected to 7% oxygen 9.14 4.94 4.57 6.22 ppmvd @ 7% O2 EPA Method 321 Downstream; Baghouse Mill On

Exhaust Stream %Moisture 10.89 10.04 10.47 %

Exhaust Flowrate 168,464 160,774 165,693 DSCFM

Exhaust Temperature 204.3 198.4 203.6 Degrees F

Sample Date (mm/dd/yyyy) 3/18/2010 3/18/2010 3/18/2010

HCl Concentration - as measured - dry basis 4.36 2.41 2.22 ppmvd 

Oxygen Concentration - dry basis 9.6 10.45 10.69 %

CO2 Concentration - dry basis 21 16 17 %

HCl Concentration 20.09 24.16 27.81 24.02 ppmvd @ 7% O2 EPA Method 321 Downstream; Baghouse Mill Off

Exhaust Stream %Moisture 13.40 13.91 13.93 %

Exhaust Flowrate 101,345 116,196 118,188 DSCFM

Exhaust Temperature 292.6 300.9 302.3 Degrees F

Notes:

Facilities that use Method 321 to test for HCl

Lehigh Cement Company

Baghouse

Enter HCl concentration value in dry 

parts per million volume (ppmvd). If 

the test results are below detection 

limit, please note the detection limit 

in brackets 

(e.g., [< 0.010]). 

Peach shaded cells indicate areas where the user will enter a response

Yes

Rotary Kiln

Enclosure 5c--ERT Spreadsheet Page 1 of 1










Date Time SpectrumFile LibraryFile W

3/18/2010 12:45:35 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Zero Run 1 Before_02721.SPE BoilerMAct 3/18/2010 12:45:41 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Zero Run 1 Before_02722.SPE BoilerMAct 3/18/2010 12:45:47 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Zero Run 1 Before_02723.SPE BoilerMAct 3/18/2010 12:45:53 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Zero Run 1 Before_02724.SPE BoilerMAct 3/18/2010 12:45:58 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Zero Run 1 Before_02725.SPE BoilerMAct 3/18/2010 12:46:04 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Zero Run 1 Before_02726.SPE BoilerMAct 3/18/2010 12:46:10 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Zero Run 1 Before_02727.SPE BoilerMAct 
 Compensa Residual Hydrogen cUnit Compensa Residual SF6 Unit Compensa Residual

wet 0.0005 0.1 ppm wet 0.0007 0 ppm wet 0.001wet 0.0007 0 ppm wet 0.0008 0 ppm wet 0.0007wet 0.0004 0 ppm wet 0.0007 0 ppm wet 0.0008wet 0.0005 0.1 ppm wet 0.0007 0 ppm wet 0.0011wet 0.0008 0 ppm wet 0.0006 0.01 ppm wet 0.0004wet 0.0005 0 ppm wet 0.0005 0 ppm wet 0.0011wet 0.0006 0.07 ppm wet 0.0007 0 ppm wet 0.001
Date Time SpectrumFile Water vapoU

3/18/2010 8:55:04 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00560.SPE 0.03 vo3/18/2010 8:55:55 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00561.SPE 0.07 vo3/18/2010 8:56:01 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00562.SPE 0.08 vo3/18/2010 8:56:07 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00563.SPE 0.08 vo3/18/2010 8:56:13 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00564.SPE 0.09 vo3/18/2010 8:56:19 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00565.SPE 0.1 vo3/18/2010 8:56:25 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00566.SPE 0.1 vo3/18/2010 8:56:31 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00567.SPE 0.11 vo3/18/2010 8:56:37 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00568.SPE 0.12 vo3/18/2010 8:56:43 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00569.SPE 0.13 vo3/18/2010 8:56:49 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00570.SPE 0.14 vo3/18/2010 8:56:55 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00571.SPE 0.15 vo3/18/2010 8:57:01 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00572.SPE 0.55 vo3/18/2010 8:57:07 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00573.SPE 0.77 vo3/18/2010 8:57:13 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00574.SPE 0.37 vo3/18/2010 8:57:18 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00575.SPE 0.03 vo3/18/2010 8:57:24 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00576.SPE 0.01 vo3/18/2010 8:57:30 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00577.SPE 0 vo3/18/2010 8:57:36 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00578.SPE 0 vo3/18/2010 8:57:42 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00579.SPE 0 vo3/18/2010 8:57:48 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00580.SPE 0.01 vo3/18/2010 8:57:54 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00581.SPE 0 vo3/18/2010 8:58:00 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00582.SPE 0 vo3/18/2010 8:58:06 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00583.SPE 0 vo3/18/2010 8:58:12 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00584.SPE 0.01 vo3/18/2010 8:58:18 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00585.SPE 0 vo3/18/2010 8:58:24 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00586.SPE 0 vo3/18/2010 8:58:30 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00587.SPE 0 vo3/18/2010 8:58:36 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00588.SPE 0 vo3/18/2010 8:58:42 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00589.SPE 0 vo3/18/2010 8:58:48 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00590.SPE 0 vo3/18/2010 8:58:54 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00591.SPE 0 vo3/18/2010 9:02:13 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00592.SPE 0 vo3/18/2010 9:02:19 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00593.SPE 0 vo3/18/2010 9:02:25 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00594.SPE 0 vo3/18/2010 9:03:43 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00595.SPE 0 vo3/18/2010 9:03:49 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00596.SPE 0 vo3/18/2010 9:03:55 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00597.SPE 0 vo3/18/2010 9:04:01 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00598.SPE 0 vo
3/18/2010 9:04:07 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00599.SPE 0 vo

3/18/2010 9:04:13 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00600.SPE 0 vo3/18/2010 9:04:19 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00601.SPE 0 vo3/18/2010 9:04:25 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00602.SPE 0 vo3/18/2010 9:04:57 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00603.SPE 0 vo3/18/2010 9:05:03 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00604.SPE 0 vo3/18/2010 9:05:09 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00605.SPE 0 vo3/18/2010 9:05:15 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00606.SPE 0 vo3/18/2010 9:05:21 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00607.SPE 0 vo3/18/2010 9:05:27 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00608.SPE 0 vo3/18/2010 9:05:33 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00609.SPE 0 vo3/18/2010 9:05:39 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00610.SPE 0 vo3/18/2010 9:05:45 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00611.SPE 0 vo3/18/2010 9:05:51 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00612.SPE 0 vo3/18/2010 9:05:57 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00613.SPE 0 vo3/18/2010 9:06:03 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00614.SPE 0 vo3/18/2010 9:06:09 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00615.SPE 0 vo3/18/2010 9:06:15 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00616.SPE 0 vo3/18/2010 9:06:21 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00617.SPE 0 vo3/18/2010 9:06:27 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00618.SPE 0 vo3/18/2010 9:06:33 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00619.SPE 0 vo3/18/2010 9:06:39 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00620.SPE 0 vo3/18/2010 9:06:45 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00621.SPE 0 vo3/18/2010 9:06:51 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00622.SPE 0 vo3/18/2010 9:06:57 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00623.SPE 0 vo3/18/2010 9:07:03 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00624.SPE 0 vo3/18/2010 9:07:09 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00625.SPE 0 vo3/18/2010 9:07:14 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00626.SPE 0 vo3/18/2010 9:07:20 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00627.SPE 0 vo3/18/2010 9:07:58 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00628.SPE 0 vo3/18/2010 9:08:04 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00629.SPE 0 vo3/18/2010 9:08:10 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00630.SPE 0 vo3/18/2010 9:08:16 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00631.SPE 0 vo3/18/2010 9:08:22 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00632.SPE 0 vo3/18/2010 9:08:28 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00633.SPE 0 vo3/18/2010 9:08:34 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00634.SPE 0 vo3/18/2010 9:08:40 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00635.SPE 0 vo3/18/2010 9:08:46 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00636.SPE 0 vo3/18/2010 9:08:52 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00637.SPE 0 vo3/18/2010 9:08:58 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00638.SPE 0 vo
3/18/2010 9:09:04 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00639.SPE 0 vo

3/18/2010 9:09:10 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00640.SPE 0 vo3/18/2010 9:09:16 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00641.SPE 0 vo3/18/2010 9:09:22 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00642.SPE 0 vo3/18/2010 9:09:28 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00643.SPE 0 vo3/18/2010 9:09:34 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00644.SPE 0 vo3/18/2010 9:09:40 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00645.SPE 0 vo3/18/2010 9:09:45 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00646.SPE 0 vo3/18/2010 9:09:51 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00647.SPE 0 vo3/18/2010 9:09:57 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00648.SPE 0 vo3/18/2010 9:10:03 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00649.SPE 0 vo3/18/2010 9:10:09 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00650.SPE 0 vo3/18/2010 9:10:15 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00651.SPE 0 vo3/18/2010 9:10:21 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00652.SPE 0 vo3/18/2010 9:10:27 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00653.SPE 0 vo3/18/2010 9:10:33 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00654.SPE 0 vo3/18/2010 9:10:39 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00655.SPE 0 vo3/18/2010 9:10:45 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00656.SPE 0 vo3/18/2010 9:10:51 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00657.SPE 0 vo3/18/2010 9:10:57 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan Run 1 Before_00658.SPE 0 vo

Averages
 Residual Hydrogen cUnit Compensa Residual SF6 Unit Compensa Residual

0.0003 0.43 ppm wet 0.0003 0 ppm wet 0.00060.0005 0.77 ppm wet 0.0006 0 ppm wet 0.00060.0005 1.14 ppm wet 0.0007 0.01 ppm wet 0.00050.0005 0.53 ppm wet 0.0007 0.02 ppm wet 0.00090.0007 0.41 ppm wet 0.0008 0.01 ppm wet 0.00060.0008 1.3 ppm wet 0.0008 0.01 ppm wet 0.00090.0008 1.16 ppm wet 0.0009 0 ppm wet 0.0010.0008 0.91 ppm wet 0.0007 0 ppm wet 0.00080.0008 0.91 ppm wet 0.001 0 ppm wet 0.0008

0.001 1.16 ppm wet 0.0013 0 ppm wet 0.0012

0.0012 1.21 ppm wet 0.0012 0 ppm wet 0.00080.0013 0.85 ppm wet 0.0012 0.02 ppm wet 0.00070.0046 3.39 ppm wet 0.0036 0.02 ppm wet 0.00120.0058 4.33 ppm wet 0.004 0 ppm wet 0.0020.0044 55.04 ppm wet 0.005 0.08 ppm wet 0.00690.0004 102.9 ppm wet 0.002 0.01 ppm wet 0.00130.0002 101.53 ppm wet 0.002 0 ppm wet 0.0020.0054 104.09 ppm wet 0.0021 0 ppm wet 0.00230.0031 107.86 ppm wet 0.0022 0 ppm wet 0.00170.0002 110.53 ppm wet 0.002 0.05 ppm wet 0.00230.0002 112.68 ppm wet 0.0023 0 ppm wet 0.00150.0024 115.08 ppm wet 0.0023 0 ppm wet 0.00150.0012 115.74 ppm wet 0.0023 0 ppm wet 0.0022

0.005 117 ppm wet 0.0024 0 ppm wet 0.0021

0.0002 118.22 ppm wet 0.0024 0 ppm wet 0.00130.0004 119.15 ppm wet 0.0023 0 ppm wet 0.00320.0063 119.78 ppm wet 0.0024 0 ppm wet 0.00380.0022 120.35 ppm wet 0.0025 0.01 ppm wet 0.00160.0038 121.77 ppm wet 0.0023 0 ppm wet 0.00230.0018 122.21 ppm wet 0.0024 0 ppm wet 0.00240.0074 122.24 ppm wet 0.0025 0 ppm wet 0.0017

0.001 121.99 ppm wet 0.0026 0 ppm wet 0.002

0.0003 151.62 ppm wet 0.0006 0 ppm wet 0.00150.0005 151.87 ppm wet 0.0008 0 ppm wet 0.00120.0003 151.71 ppm wet 0.0007 0 ppm wet 0.00180.0003 146.03 ppm wet 0.0007 0 ppm wet 0.00190.0005 146.06 ppm wet 0.0006 0.03 ppm wet 0.00240.0007 145.14 ppm wet 0.0006 0.01 ppm wet 0.00260.0005 146.4 ppm wet 0.0007 0.02 ppm wet 0.0024
0.0006 145.96 ppm wet 0.0006 0.02 ppm wet 0.0024

0.0007 145.73 ppm wet 0.0007 0 ppm wet 0.00130.0002 145.35 ppm wet 0.0006 0.02 ppm wet 0.00290.0006 146.4 ppm wet 0.0008 0 ppm wet 0.00290.0004 144.2 ppm wet 0.0005 0.01 ppm wet 0.00160.0006 143.22 ppm wet 0.0007 0 ppm wet 0.00190.0006 143.96 ppm wet 0.0005 0 ppm wet 0.00260.0006 143.54 ppm wet 0.0008 0 ppm wet 0.00090.0006 143.95 ppm wet 0.0006 0 ppm wet 0.00140.0003 144.41 ppm wet 0.0006 0 ppm wet 0.00130.0006 144.36 ppm wet 0.0004 0 ppm wet 0.00120.0006 143.9 ppm wet 0.0007 0.01 ppm wet 0.00180.0005 144.18 ppm wet 0.0007 0 ppm wet 0.00180.0005 144.49 ppm wet 0.0009 0.02 ppm wet 0.00220.0005 143.92 ppm wet 0.0007 0 ppm wet 0.00180.0004 143.97 ppm wet 0.0007 0 ppm wet 0.00150.0003 143.96 ppm wet 0.0005 0.01 ppm wet 0.00160.0006 144.49 ppm wet 0.0008 0.01 ppm wet 0.0020.0006 144.19 ppm wet 0.0007 0 ppm wet 0.00150.0004 145 ppm wet 0.0006 0.02 ppm wet 0.00250.0003 143.63 ppm wet 0.0006 0 ppm wet 0.0020.0004 144.67 ppm wet 0.0006 0.01 ppm wet 0.00190.0005 143.83 ppm wet 0.0008 0.01 ppm wet 0.0020.0005 144.4 ppm wet 0.0006 0 ppm wet 0.0020.0005 144.3 ppm wet 0.0006 0.01 ppm wet 0.0008

0.001 144.01 ppm wet 0.0008 0.01 ppm wet 0.00190.001 145.19 ppm wet 0.0008 0.02 ppm wet 0.0014

0.0003 145.15 ppm wet 0.0008 0 ppm wet 0.00150.0003 145.03 ppm wet 0.0008 0 ppm wet 0.00160.0003 143.65 ppm wet 0.0005 0.01 ppm wet 0.00220.0008 144.12 ppm wet 0.0007 0 ppm wet 0.00140.0007 144.09 ppm wet 0.0008 0.01 ppm wet 0.00210.0004 143.91 ppm wet 0.0007 0 ppm wet 0.00210.0005 143.35 ppm wet 0.0007 0 ppm wet 0.0020.0006 143.74 ppm wet 0.0007 0 ppm wet 0.00190.0004 143.68 ppm wet 0.0006 0.02 ppm wet 0.00220.0007 143.79 ppm wet 0.0008 0 ppm wet 0.00120.0005 144.1 ppm wet 0.0005 0 ppm wet 0.00150.0006 143.3 ppm wet 0.0005 0.01 ppm wet 0.00090.0005 143.51 ppm wet 0.0007 0.01 ppm wet 0.001
0.0008 143.65 ppm wet 0.0006 0 ppm wet 0.0014

0.0008 143.35 ppm wet 0.0006 0 ppm wet 0.00210.0004 143.65 ppm wet 0.0005 0.03 ppm wet 0.00170.0008 143.94 ppm wet 0.0006 0.01 ppm wet 0.00310.0005 143.57 ppm wet 0.0008 0 ppm wet 0.00180.0006 144.63 ppm wet 0.0006 0.01 ppm wet 0.00280.0007 143.86 ppm wet 0.0007 0.01 ppm wet 0.0020.0008 144.37 ppm wet 0.0006 0 ppm wet 0.0020.0008 143.55 ppm wet 0.0006 0.01 ppm wet 0.00240.0004 144.32 ppm wet 0.0005 0 ppm wet 0.0020.0006 143.44 ppm wet 0.0006 0.02 ppm wet 0.00150.0004 143.77 ppm wet 0.0005 0.01 ppm wet 0.00170.0003 144.08 ppm wet 0.0007 0 ppm wet 0.00130.0005 143.48 ppm wet 0.0006 0.01 ppm wet 0.00120.0005 143.68 ppm wet 0.0006 0 ppm wet 0.00250.0009 143.9 ppm wet 0.0006 0 ppm wet 0.0030.0009 143.82 ppm wet 0.0006 0 ppm wet 0.00190.0006 143.68 ppm wet 0.0007 0.01 ppm wet 0.00140.0003 144.43 ppm wet 0.0006 0.01 ppm wet 0.00150.0006 144.03 ppm wet 0.0007 0 ppm wet 0.0015

144.007
Date Time SpectrumFile Water vap

oUnit Com

3/18/2010 13:23:51 C:\CalcmetSamples\Lehigh 210158\20100318\ Spike Before Run 1 _02775.

S 12.5 vol-% wet 

3/18/2010 13:23:57 C:\CalcmetSamples\Lehigh 210158\20100318\ Spike Before Run 1 _02776.

S 12.42 vol-% wet 

3/18/2010 13:24:03 C:\CalcmetSamples\Lehigh 210158\20100318\ Spike Before Run 1 _02777.

S 12.41 vol-% wet 

3/18/2010 13:24:09 C:\CalcmetSamples\Lehigh 210158\20100318\ Spike Before Run 1 _02778.

S 12.43 vol-% wet 

3/18/2010 13:24:15 C:\CalcmetSamples\Lehigh 210158\20100318\ Spike Before Run 1 _02779.

S 12.39 vol-% wet 

3/18/2010 13:24:21 C:\CalcmetSamples\Lehigh 210158\20100318\ Spike Before Run 1 _02780.

S 12.39 vol-% wet 

3/18/2010 13:24:27 C:\CalcmetSamples\Lehigh 210158\20100318\ Spike Before Run 1 _02781.

S 12.42 vol-% wet 

Date Time SpectrumFile Water vap

oUnit Com

3/18/2010 9:23:42 C:\CalcmetSamples\Lehigh 210158\20100318\Spike Run 1 Before_00736.S 0 vol-% wet 3/18/2010 9:23:48 C:\CalcmetSamples\Lehigh 210158\20100318\Spike Run 1 Before_00737.S 0 vol-% wet 3/18/2010 9:23:54 C:\CalcmetSamples\Lehigh 210158\20100318\Spike Run 1 Before_00738.S 0 vol-% wet 3/18/2010 9:24:00 C:\CalcmetSamples\Lehigh 210158\20100318\Spike Run 1 Before_00739.S 0 vol-% wet 3/18/2010 9:24:06 C:\CalcmetSamples\Lehigh 210158\20100318\Spike Run 1 Before_00740.S 0 vol-% wet 3/18/2010 9:24:12 C:\CalcmetSamples\Lehigh 210158\20100318\Spike Run 1 Before_00741.S 0 vol-% wet 3/18/2010 9:24:18 C:\CalcmetSamples\Lehigh 210158\20100318\Spike Run 1 Before_00742.S 0 vol-% wet 3/18/2010 9:24:24 C:\CalcmetSamples\Lehigh 210158\20100318\Spike Run 1 Before_00743.S 0 vol-% wet 3/18/2010 9:24:30 C:\CalcmetSamples\Lehigh 210158\20100318\Spike Run 1 Before_00744.S 0 vol-% wet 3/18/2010 9:24:36 C:\CalcmetSamples\Lehigh 210158\20100318\Spike Run 1 Before_00745.S 0 vol-% wet 3/18/2010 9:24:42 C:\CalcmetSamples\Lehigh 210158\20100318\Spike Run 1 Before_00746.S 0 vol-% wet 
Hydrogen cUnit Compensa Residual SF6 Unit Compensa Residual

1.13 ppm wet 0.0023 0.65 ppm wet 0.0051.39 ppm wet 0.0023 0.72 ppm wet 0.0051.26 ppm wet 0.0022 0.65 ppm wet 0.0050.79 ppm wet 0.0022 0.66 ppm wet 0.00531.58 ppm wet 0.0024 0.66 ppm wet 0.00520.47 ppm wet 0.0024 0.66 ppm wet 0.00531.84 ppm wet 0.0025 0.66 ppm wet 0.0049

Hydrogen cUnit Compensa Residual SF6 Unit Compensa Residual

14.44 ppm wet 0.0003 0.04 ppm wet 0.003214.78 ppm wet 0.0003 0.02 ppm wet 0.001814.86 ppm wet 0.0002 0.05 ppm wet 0.001914.72 ppm wet 0.0002 0.04 ppm wet 0.000810.61 ppm wet 0.0002 0.03 ppm wet 0.0024

7.77 ppm wet 0.0002 0.02 ppm wet 0.00111.87 ppm wet 0.0002 0 ppm wet 0.00210.63 ppm wet 0.0002 0.02 ppm wet 0.00190.48 ppm wet 0.0003 1.62 ppm wet 0.00140.01 ppm wet 0.0003 1.61 ppm wet 0.00250.81 ppm wet 0.0003 1.65 ppm wet 0.0024
HCL Lehigh

Sm --Spiked Data

Date Method Filename HCl(ppm) SF6 (ppm)

03/18/10 321 C:\CalcmetSamples\L 14.78 C:\CalcmetSam 1.62

03/18/10 321 C:\CalcmetSamples\L 14.86 C:\CalcmetSam 1.6103/18/10 321 C:\CalcmetSamples\L 14.72 C:\CalcmetSam 1.65

Avg. Conc. (ppm) 1.627 14.79

Su -- Native Conc. Of analyte

Date Method Filename HCl(ppm) SF6 (ppm)

03/18/10 321 C:\CalcmetSamples\L 1.58 C:\CalcmetSam 0.66

03/18/10 321 C:\CalcmetSamples\L 0.47 C:\CalcmetSam 0.6603/18/10 321 C:\CalcmetSamples\L 1.84 C:\CalcmetSam 0.66

Avg. Conc. (ppm) 0.660 1.30

Sm - Su(1-DF)

Recovery (%) = DF x Cs

Ce = DF x Cs + Su(1-DF)

Sm 14.79 ppm Mean concentration of spiked analyte

Su 1.30 ppm Native concentration of analyte

DF 9.7% % Dilution Factor (Target < 10%)

Cs 144.2 ppm Cylinder of spiked gas

 ppm Cylinder of tracer gas (SF6) 9.98

Ce 15.14 ppm Expected concentration of analyte

Recovery (%) 97.5% 70 - 130 %
Date Time SpectrumFile Water vap

oUnit Comp

3/18/2010 14:11:03 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02819.SPE 9.87 vol-% wet 3/18/2010 14:12:04 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02820.SPE 9.87 vol-% wet 3/18/2010 14:13:04 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02821.SPE 9.87 vol-% wet 3/18/2010 14:14:05 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02822.SPE 9.88 vol-% wet 3/18/2010 14:15:05 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02823.SPE 9.88 vol-% wet 3/18/2010 14:16:06 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02824.SPE 9.91 vol-% wet 3/18/2010 14:17:07 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02825.SPE 9.91 vol-% wet 3/18/2010 14:18:07 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02826.SPE 9.95 vol-% wet 3/18/2010 14:19:08 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02827.SPE 9.95 vol-% wet 3/18/2010 14:20:08 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02828.SPE 10 vol-% wet 3/18/2010 14:21:09 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02829.SPE 9.97 vol-% wet 3/18/2010 14:22:10 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02830.SPE 9.99 vol-% wet 3/18/2010 14:23:10 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02831.SPE 9.98 vol-% wet 3/18/2010 14:24:11 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02832.SPE 9.93 vol-% wet 3/18/2010 14:25:11 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02833.SPE 9.95 vol-% wet 3/18/2010 14:26:12 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02834.SPE 9.96 vol-% wet 3/18/2010 14:27:13 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02835.SPE 9.98 vol-% wet 3/18/2010 14:28:13 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02836.SPE 9.96 vol-% wet 3/18/2010 14:29:14 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02837.SPE 9.93 vol-% wet 3/18/2010 14:30:14 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02838.SPE 9.88 vol-% wet 3/18/2010 14:31:15 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02839.SPE 9.87 vol-% wet 3/18/2010 14:32:16 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02840.SPE 9.79 vol-% wet 3/18/2010 14:33:16 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02841.SPE 9.75 vol-% wet 3/18/2010 14:34:17 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02842.SPE 9.75 vol-% wet 3/18/2010 14:35:17 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02843.SPE 9.74 vol-% wet 3/18/2010 14:36:18 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02844.SPE 9.78 vol-% wet 3/18/2010 14:37:19 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02845.SPE 9.76 vol-% wet 3/18/2010 14:38:19 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02846.SPE 9.78 vol-% wet 3/18/2010 14:39:20 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02847.SPE 9.81 vol-% wet 3/18/2010 14:40:21 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02848.SPE 9.82 vol-% wet 3/18/2010 14:41:21 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02849.SPE 9.88 vol-% wet 3/18/2010 14:42:22 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02850.SPE 9.87 vol-% wet 3/18/2010 14:43:22 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02851.SPE 9.95 vol-% wet 3/18/2010 14:44:23 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02852.SPE 9.94 vol-% wet 3/18/2010 14:45:24 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02853.SPE 9.93 vol-% wet 3/18/2010 14:46:24 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02854.SPE 9.98 vol-% wet 3/18/2010 14:47:25 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02855.SPE 9.98 vol-% wet 3/18/2010 14:48:26 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02856.SPE 10.04 vol-% wet 3/18/2010 14:49:26 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02857.SPE 10.04 vol-% wet 
3/18/2010 14:50:27 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02858.SPE 10.01 vol-% wet 

3/18/2010 14:51:28 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02859.SPE 9.95 vol-% wet 3/18/2010 14:52:28 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02860.SPE 9.95 vol-% wet 3/18/2010 14:53:29 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02861.SPE 9.98 vol-% wet 3/18/2010 14:54:30 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02862.SPE 9.99 vol-% wet 3/18/2010 14:55:30 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02863.SPE 10.04 vol-% wet 3/18/2010 14:56:31 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02864.SPE 10.09 vol-% wet 3/18/2010 14:57:31 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02865.SPE 10.07 vol-% wet 3/18/2010 14:58:32 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02866.SPE 10.15 vol-% wet 3/18/2010 14:59:33 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02867.SPE 10.11 vol-% wet 3/18/2010 15:00:33 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02868.SPE 10.04 vol-% wet 3/18/2010 15:01:34 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02869.SPE 9.99 vol-% wet 3/18/2010 15:02:34 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02870.SPE 9.9 vol-% wet 3/18/2010 15:03:35 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02871.SPE 9.85 vol-% wet 3/18/2010 15:04:36 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02872.SPE 9.82 vol-% wet 3/18/2010 15:05:36 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02873.SPE 9.8 vol-% wet 3/18/2010 15:06:37 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02874.SPE 9.71 vol-% wet 3/18/2010 15:07:37 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02875.SPE 9.7 vol-% wet 3/18/2010 15:08:38 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02876.SPE 18.37 vol-% wet 3/18/2010 15:09:39 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02877.SPE 12.76 vol-% wet 3/18/2010 15:10:39 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02878.SPE 10.41 vol-% wet 3/18/2010 15:11:40 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02879.SPE 9.92 vol-% wet 3/18/2010 15:12:40 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 1a _02880.SPE 9.7 vol-% wet 

Averages 
Unit Compensa Residual SF6 Unit Compensa Residual

ppm wet 0.0053 0.68 ppm wet 0.007ppm wet 0.0053 0.67 ppm wet 0.0071ppm wet 0.0054 0.67 ppm wet 0.0073ppm wet 0.0054 0.68 ppm wet 0.0075ppm wet 0.0055 0.69 ppm wet 0.0076ppm wet 0.0055 0.7 ppm wet 0.0076ppm wet 0.0055 0.69 ppm wet 0.0077ppm wet 0.0056 0.69 ppm wet 0.0078ppm wet 0.0055 0.7 ppm wet 0.0078ppm wet 0.0055 0.71 ppm wet 0.0077ppm wet 0.0056 0.72 ppm wet 0.0077ppm wet 0.0059 0.71 ppm wet 0.0077ppm wet 0.0062 0.71 ppm wet 0.008ppm wet 0.0063 0.71 ppm wet 0.0078ppm wet 0.0062 0.71 ppm wet 0.0079ppm wet 0.0056 0.72 ppm wet 0.0081ppm wet 0.0051 0.72 ppm wet 0.0077ppm wet 0.005 0.72 ppm wet 0.0077ppm wet 0.0054 0.75 ppm wet 0.0076ppm wet 0.0056 0.76 ppm wet 0.0076ppm wet 0.0056 0.75 ppm wet 0.0078ppm wet 0.0059 0.73 ppm wet 0.0078ppm wet 0.0058 0.71 ppm wet 0.0077ppm wet 0.0056 0.72 ppm wet 0.0075ppm wet 0.0057 0.7 ppm wet 0.0075ppm wet 0.0055 0.7 ppm wet 0.0076ppm wet 0.0055 0.7 ppm wet 0.0073ppm wet 0.0053 0.7 ppm wet 0.0075ppm wet 0.0052 0.69 ppm wet 0.0072ppm wet 0.0051 0.69 ppm wet 0.0077ppm wet 0.005 0.69 ppm wet 0.0076ppm wet 0.0049 0.68 ppm wet 0.0074ppm wet 0.0048 0.67 ppm wet 0.0072ppm wet 0.0049 0.67 ppm wet 0.0074ppm wet 0.0049 0.67 ppm wet 0.0072ppm wet 0.0052 0.66 ppm wet 0.0071ppm wet 0.0054 0.65 ppm wet 0.007ppm wet 0.0055 0.66 ppm wet 0.0072ppm wet 0.0055 0.66 ppm wet 0.0071
ppm wet 0.0053 0.64 ppm wet 0.0073

ppm wet 0.0048 0.65 ppm wet 0.0072ppm wet 0.0047 0.64 ppm wet 0.007ppm wet 0.0048 0.66 ppm wet 0.0071ppm wet 0.0047 0.67 ppm wet 0.007ppm wet 0.0045 0.66 ppm wet 0.0073ppm wet 0.0045 0.66 ppm wet 0.0075ppm wet 0.0048 0.65 ppm wet 0.0076ppm wet 0.0051 0.67 ppm wet 0.0072ppm wet 0.0053 0.68 ppm wet 0.0073ppm wet 0.0053 0.69 ppm wet 0.0074ppm wet 0.0055 0.7 ppm wet 0.0071ppm wet 0.0055 0.69 ppm wet 0.0075ppm wet 0.0057 0.69 ppm wet 0.0076ppm wet 0.0056 0.7 ppm wet 0.0075ppm wet 0.0057 0.7 ppm wet 0.0071ppm wet 0.0055 0.67 ppm wet 0.0073ppm wet 0.005 0.67 ppm wet 0.0072ppm wet 0.0052 0.35 ppm wet 0.015ppm wet 0.0052 0.56 ppm wet 0.0094ppm wet 0.005 0.62 ppm wet 0.0083ppm wet 0.005 0.64 ppm wet 0.0081ppm wet 0.0049 0.64 ppm wet 0.0076
HCL Lehigh

Sm --Spiked Data

Date Method Filename HCl(ppm) SF6 (ppm)

03/18/10 321 C:\CalcmetSamples\L 26.32 C:\CalcmetSam 1.48

03/18/10 321 C:\CalcmetSamples\L 25.36 C:\CalcmetSam 1.5403/18/10 321 C:\CalcmetSamples\L 25.55 C:\CalcmetSam 1.52

Avg. Conc. (ppm) 1.513 25.74

Su -- Native Conc. Of analyte

Date Method Filename HCl(ppm) SF6 (ppm)

03/18/10 321 C:\CalcmetSamples\L 15.66 C:\CalcmetSam 0.62

03/18/10 321 C:\CalcmetSamples\L 15.59 C:\CalcmetSam 0.6403/18/10 321 C:\CalcmetSamples\L 15.53 C:\CalcmetSam 0.64

Avg. Conc. (ppm) 0.633 15.59

Sm - Su(1-DF)

Recovery (%) = DF x Cs

Ce = DF x Cs + Su(1-DF)

Sm 25.74 ppm Mean concentration of spiked analyte

Su 15.59 ppm Native concentration of analyte

DF 8.8% % Dilution Factor (Target < 10%)

Cs 144.2 ppm Cylinder of spiked gas

 ppm Cylinder of tracer gas (SF6) 9.98

Ce 26.93 ppm Expected concentration of analyte

Recovery (%) 90.6% 70 - 130 %
Date Time SpectrumF Water vapoUnit Compensa Residual Hydrogen cUnit Compensa Residual 

3/18/2010 15:14:55 C:\Calcmet 8.44 vol-% wet 0.0023 26.32 ppm wet 0.0036 

3/18/2010 15:15:01 C:\Calcmet 8.37 vol-% wet 0.0021 25.36 ppm wet 0.0037 3/18/2010 15:15:07 C:\Calcmet 8.39 vol-% wet 0.0022 25.55 ppm wet 0.0037 3/18/2010 15:15:13 C:\Calcmet 8.37 vol-% wet 0.0022 21.98 ppm wet 0.0036 3/18/2010 15:15:19 C:\Calcmet 8.33 vol-% wet 0.0021 21.69 ppm wet 0.0037 3/18/2010 15:15:25 C:\Calcmet 8.28 vol-% wet 0.002 19.44 ppm wet 0.0037 3/18/2010 15:15:31 C:\Calcmet 8.3 vol-% wet 0.0021 11.99 ppm wet 0.0038 

3/18/2010 15:15:37 C:\Calcmet 8.18 vol-% wet 0.0021 10.37 ppm wet 0.0037 

3/18/2010 15:15:43 C:\Calcmet 8.17 vol-% wet 0.0019 9.53 ppm wet 0.0038 3/18/2010 15:15:49 C:\Calcmet 8.21 vol-% wet 0.0022 11.89 ppm wet 0.0038 3/18/2010 15:15:55 C:\Calcmet 8.1 vol-% wet 0.0019 9.65 ppm wet 0.0039 

3/18/2010 15:16:01 C:\Calcmet 8.27 vol-% wet 0.0019 10.6 ppm wet 0.0039 

3/18/2010 15:16:07 C:\Calcmet 8.21 vol-% wet 0.0021 9.55 ppm wet 0.0038 3/18/2010 15:16:13 C:\Calcmet 8.34 vol-% wet 0.0022 12.39 ppm wet 0.0043 3/18/2010 15:16:19 C:\Calcmet 8.23 vol-% wet 0.0022 10.2 ppm wet 0.0045 3/18/2010 15:16:25 C:\Calcmet 8.35 vol-% wet 0.0022 12.28 ppm wet 0.0043 3/18/2010 15:16:31 C:\Calcmet 8.3 vol-% wet 0.0021 10.17 ppm wet 0.0045 

3/18/2010 15:16:37 C:\Calcmet 8.35 vol-% wet 0.002 10 ppm wet 0.0044 

3/18/2010 15:16:43 C:\Calcmet 8.28 vol-% wet 0.0021 10.4 ppm wet 0.0043 3/18/2010 15:16:49 C:\Calcmet 8.37 vol-% wet 0.0021 12.75 ppm wet 0.0044 3/18/2010 15:16:55 C:\Calcmet 8.38 vol-% wet 0.0021 12.36 ppm wet 0.0045 3/18/2010 15:17:01 C:\Calcmet 8.33 vol-% wet 0.0021 12.42 ppm wet 0.0047 

3/18/2010 15:17:07 C:\Calcmet 8.34 vol-% wet 0.0022 12.76 ppm wet 0.0048 

3/18/2010 15:17:13 C:\Calcmet 8.46 vol-% wet 0.0021 12.53 ppm wet 0.0047 3/18/2010 15:17:19 C:\Calcmet 8.38 vol-% wet 0.0021 12.59 ppm wet 0.0044 3/18/2010 15:17:25 C:\Calcmet 8.49 vol-% wet 0.0022 12.87 ppm wet 0.0051 3/18/2010 15:18:48 C:\Calcmet 8.49 vol-% wet 0.0021 12.61 ppm wet 0.0049 3/18/2010 15:20:44 C:\Calcmet 8.54 vol-% wet 0.0021 13.2 ppm wet 0.006 3/18/2010 15:20:50 C:\Calcmet 8.44 vol-% wet 0.0022 12.97 ppm wet 0.0054 3/18/2010 15:20:56 C:\Calcmet 8.5 vol-% wet 0.0021 11.9 ppm wet 0.0052 

3/18/2010 15:21:02 C:\Calcmet 8.41 vol-% wet 0.002 10.2 ppm wet 0.005 

3/18/2010 15:21:08 C:\Calcmet 8.4 vol-% wet 0.0019 9.98 ppm wet 0.005 

3/18/2010 15:21:14 C:\Calcmet 8.41 vol-% wet 0.002 9.92 ppm wet 0.0049 

3/18/2010 15:21:20 C:\Calcmet 8.36 vol-% wet 0.0017 9.25 ppm wet 0.0048 3/18/2010 15:21:26 C:\Calcmet 8.32 vol-% wet 0.002 10.13 ppm wet 0.0047 3/18/2010 15:21:32 C:\Calcmet 8.36 vol-% wet 0.0019 9.87 ppm wet 0.0048 3/18/2010 15:21:38 C:\Calcmet 8.27 vol-% wet 0.0021 10.3 ppm wet 0.0049 3/18/2010 15:21:44 C:\Calcmet 8.26 vol-% wet 0.0021 9.96 ppm wet 0.0046 3/18/2010 15:21:50 C:\Calcmet 8.31 vol-% wet 0.0023 9.84 ppm wet 0.0047 
3/18/2010 15:21:55 C:\Calcmet 8.29 vol-% wet 0.0019 10 ppm wet 0.0046 
 Compensa Residual

wet 0.0071wet 0.0064wet 0.0078wet 0.0072wet 0.0076wet 0.0073wet 0.0076wet 0.0073wet 0.0071wet 0.0072wet 0.0068wet 0.0066wet 0.0065wet 0.0065wet 0.0071wet 0.0077wet 0.0072wet 0.0073wet 0.0068wet 0.0077wet 0.0068wet 0.0067wet 0.0079wet 0.0073wet 0.0067wet 0.0071wet 0.0074wet 0.0055wet 0.0062wet 0.0056wet 0.006wet 0.0061wet 0.0054wet 0.0059wet 0.006wet 0.0062wet 0.0059wet 0.0047wet 0.0061
wet 0.0091
Date Time SpectrumFile Water vap

oUnit Compe

3/18/2010 15:32:02 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03004.SPE 9.61 vol-% wet 3/18/2010 15:33:02 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03005.SPE 9.71 vol-% wet 3/18/2010 15:34:03 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03006.SPE 15.01 vol-% wet 3/18/2010 15:35:03 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03007.SPE 10.43 vol-% wet 3/18/2010 15:36:04 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03008.SPE 9.92 vol-% wet 3/18/2010 15:37:05 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03009.SPE 9.94 vol-% wet 3/18/2010 15:38:05 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03010.SPE 9.81 vol-% wet 3/18/2010 15:39:06 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03011.SPE 9.78 vol-% wet 3/18/2010 15:40:07 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03012.SPE 9.82 vol-% wet 3/18/2010 15:41:07 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03013.SPE 9.9 vol-% wet 3/18/2010 15:42:08 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03014.SPE 12.93 vol-% wet 3/18/2010 15:43:09 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03015.SPE 10.44 vol-% wet 3/18/2010 15:44:09 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03016.SPE 10.05 vol-% wet 3/18/2010 15:45:10 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03017.SPE 9.94 vol-% wet 3/18/2010 15:46:11 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03018.SPE 12.19 vol-% wet 3/18/2010 15:47:11 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03019.SPE 10.03 vol-% wet 3/18/2010 15:48:12 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03020.SPE 9.94 vol-% wet 3/18/2010 15:49:12 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03021.SPE 9.95 vol-% wet 3/18/2010 15:50:13 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03022.SPE 9.88 vol-% wet 3/18/2010 15:51:13 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03023.SPE 9.93 vol-% wet 3/18/2010 15:52:14 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03024.SPE 9.88 vol-% wet 3/18/2010 15:53:15 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03025.SPE 9.92 vol-% wet 3/18/2010 15:54:15 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03026.SPE 12.08 vol-% wet 3/18/2010 15:55:16 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03027.SPE 14.24 vol-% wet 3/18/2010 15:56:16 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03028.SPE 10.01 vol-% wet 3/18/2010 15:57:17 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03029.SPE 9.87 vol-% wet 3/18/2010 15:58:18 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03030.SPE 9.86 vol-% wet 3/18/2010 15:59:18 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03031.SPE 9.83 vol-% wet 3/18/2010 16:00:19 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03032.SPE 9.89 vol-% wet 3/18/2010 16:01:20 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03033.SPE 9.87 vol-% wet 3/18/2010 16:02:20 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03034.SPE 9.85 vol-% wet 3/18/2010 16:03:21 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03035.SPE 9.85 vol-% wet 3/18/2010 16:04:21 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03036.SPE 9.81 vol-% wet 3/18/2010 16:05:22 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03037.SPE 9.79 vol-% wet 3/18/2010 16:06:23 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03038.SPE 9.81 vol-% wet 3/18/2010 16:07:23 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03039.SPE 9.8 vol-% wet 3/18/2010 16:08:24 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03040.SPE 9.8 vol-% wet 3/18/2010 16:09:25 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03041.SPE 9.75 vol-% wet 3/18/2010 16:10:25 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03042.SPE 9.76 vol-% wet 
3/18/2010 16:11:26 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03043.SPE 9.73 vol-% wet 

3/18/2010 16:12:26 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03044.SPE 9.82 vol-% wet 3/18/2010 16:13:27 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03045.SPE 9.9 vol-% wet 3/18/2010 16:14:28 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03046.SPE 9.94 vol-% wet 3/18/2010 16:15:28 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03047.SPE 10 vol-% wet 3/18/2010 16:16:29 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03048.SPE 12.53 vol-% wet 3/18/2010 16:17:29 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03049.SPE 12.23 vol-% wet 3/18/2010 16:18:30 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03050.SPE 10.23 vol-% wet 3/18/2010 16:19:31 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03051.SPE 10.04 vol-% wet 3/18/2010 16:20:31 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03052.SPE 12.93 vol-% wet 3/18/2010 16:21:32 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03053.SPE 10.27 vol-% wet 3/18/2010 16:22:32 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03054.SPE 9.89 vol-% wet 3/18/2010 16:23:33 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03055.SPE 9.89 vol-% wet 3/18/2010 16:24:34 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03056.SPE 9.83 vol-% wet 3/18/2010 16:25:34 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03057.SPE 9.82 vol-% wet 3/18/2010 16:26:35 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03058.SPE 9.79 vol-% wet 3/18/2010 16:27:36 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03059.SPE 9.89 vol-% wet 3/18/2010 16:28:36 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03060.SPE 9.88 vol-% wet 3/18/2010 16:29:37 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03061.SPE 9.85 vol-% wet 3/18/2010 16:30:37 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03062.SPE 9.86 vol-% wet 3/18/2010 16:31:38 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 2r_03063.SPE 16.54 vol-% wet 

Averages 
Unit Compensa Residual SF6 Unit Compensa Residual

ppm wet 0.0049 0 ppm wet 0.0063ppm wet 0.0048 0 ppm wet 0.0067ppm wet 0.0047 0 ppm wet 0.024ppm wet 0.0044 0 ppm wet 0.0172ppm wet 0.0046 0 ppm wet 0.01ppm wet 0.0048 0 ppm wet 0.009ppm wet 0.0049 0 ppm wet 0.0096ppm wet 0.0048 0 ppm wet 0.0097ppm wet 0.0049 0 ppm wet 0.0089ppm wet 0.005 0 ppm wet 0.0094ppm wet 0.0049 0 ppm wet 0.0176ppm wet 0.0047 0 ppm wet 0.0164ppm wet 0.0047 0 ppm wet 0.012ppm wet 0.0045 0 ppm wet 0.0111ppm wet 0.0045 0 ppm wet 0.0144ppm wet 0.0045 0 ppm wet 0.0131ppm wet 0.0045 0 ppm wet 0.0103ppm wet 0.0045 0 ppm wet 0.0104ppm wet 0.0045 0 ppm wet 0.01ppm wet 0.0045 0 ppm wet 0.0099ppm wet 0.0046 0 ppm wet 0.01ppm wet 0.0048 0 ppm wet 0.0094ppm wet 0.0049 0 ppm wet 0.0134ppm wet 0.0044 0 ppm wet 0.0326ppm wet 0.0047 0 ppm wet 0.0138ppm wet 0.0053 0 ppm wet 0.0111ppm wet 0.0055 0 ppm wet 0.0104ppm wet 0.0053 0 ppm wet 0.01ppm wet 0.0054 0 ppm wet 0.0097ppm wet 0.0055 0 ppm wet 0.0098ppm wet 0.0056 0 ppm wet 0.0097ppm wet 0.0059 0 ppm wet 0.0097ppm wet 0.006 0 ppm wet 0.01ppm wet 0.006 0 ppm wet 0.0099ppm wet 0.0061 0 ppm wet 0.0101ppm wet 0.0064 0 ppm wet 0.0102ppm wet 0.0067 0 ppm wet 0.0103ppm wet 0.0069 0 ppm wet 0.0101ppm wet 0.0069 0 ppm wet 0.0094
ppm wet 0.0067 0 ppm wet 0.0103

ppm wet 0.0071 0 ppm wet 0.0107ppm wet 0.0074 0 ppm wet 0.0109ppm wet 0.0077 0 ppm wet 0.0108ppm wet 0.008 0 ppm wet 0.0114ppm wet 0.0076 0 ppm wet 0.0169ppm wet 0.0068 0 ppm wet 0.0195ppm wet 0.006 0 ppm wet 0.0139ppm wet 0.0059 0 ppm wet 0.0132ppm wet 0.0057 0 ppm wet 0.0215ppm wet 0.0056 0 ppm wet 0.0169ppm wet 0.0054 0 ppm wet 0.0134ppm wet 0.0057 0 ppm wet 0.0127ppm wet 0.0058 0 ppm wet 0.0119ppm wet 0.0063 0 ppm wet 0.0109ppm wet 0.0067 0 ppm wet 0.0103ppm wet 0.007 0 ppm wet 0.0105ppm wet 0.007 0 ppm wet 0.0103ppm wet 0.0066 0 ppm wet 0.0109ppm wet 0.0062 0 ppm wet 0.0104ppm wet 0.0057 0 ppm wet 0.0308
HCL Lehigh

Sm --Spiked Data

Date Method Filename HCl(ppm) SF6 (ppm)

03/18/10 321 C:\CalcmetSamples\L 29.41 C:\CalcmetSam 0.65

03/18/10 321 C:\CalcmetSamples\L 28.11 C:\CalcmetSam 1.0403/18/10 321 C:\CalcmetSamples\L 29.49 C:\CalcmetSam 1.17

Avg. Conc. (ppm) 0.953 29.00

Su -- Native Conc. Of analyte

Date Method Filename HCl(ppm) SF6 (ppm)

03/18/10 321 C:\CalcmetSamples\L 13.72 C:\CalcmetSam 0

03/18/10 321 C:\CalcmetSamples\L 13.38 C:\CalcmetSam 003/18/10 321 C:\CalcmetSamples\L 26.69 C:\CalcmetSam 0

Avg. Conc. (ppm) - 17.93

Sm - Su(1-DF)

Recovery (%) = DF x Cs

Ce = DF x Cs + Su(1-DF)

Sm 29.00 ppm Mean concentration of spiked analyte

Su 17.93 ppm Native concentration of analyte

DF 9.6% % Dilution Factor (Target < 10%)

Cs 144.2 ppm Cylinder of spiked gas

 ppm Cylinder of tracer gas (SF6) 9.98

Ce 29.99 ppm Expected concentration of analyte

Recovery (%) 92.8% 70 - 130 %
Date Time SpectrumF Water vapoUnit Compensa Residual Hydrogen cUnit Compensa Residual 

3/18/2010 16:34:23 C:\Calcmet 9.35 vol-% wet 0.0025 32.79 ppm wet 0.0074 

3/18/2010 16:34:37 C:\Calcmet 9.25 vol-% wet 0.0029 30.88 ppm wet 0.0054 3/18/2010 16:34:51 C:\Calcmet 9.28 vol-% wet 0.0027 13.08 ppm wet 0.0049 3/18/2010 16:34:54 C:\Calcmet 9.25 vol-% wet 0.0029 13.69 ppm wet 0.0049 3/18/2010 16:34:57 C:\Calcmet 9.25 vol-% wet 0.0029 12.08 ppm wet 0.0051 3/18/2010 16:35:00 C:\Calcmet 9.23 vol-% wet 0.0021 10.34 ppm wet 0.0049 3/18/2010 16:35:03 C:\Calcmet 9.26 vol-% wet 0.0026 12.88 ppm wet 0.0043 3/18/2010 16:35:06 C:\Calcmet 9.24 vol-% wet 0.0025 13.08 ppm wet 0.0049 3/18/2010 16:35:09 C:\Calcmet 9.31 vol-% wet 0.0024 13.16 ppm wet 0.0047 3/18/2010 16:35:12 C:\Calcmet 9.03 vol-% wet 0.0026 8.64 ppm wet 0.0057 3/18/2010 16:35:15 C:\Calcmet 9.14 vol-% wet 0.0029 12.84 ppm wet 0.0047 3/18/2010 16:35:17 C:\Calcmet 9.04 vol-% wet 0.0026 10.16 ppm wet 0.005 3/18/2010 16:35:20 C:\Calcmet 9.08 vol-% wet 0.0027 9.28 ppm wet 0.0047 3/18/2010 16:35:23 C:\Calcmet 9.06 vol-% wet 0.0025 9.45 ppm wet 0.0046 3/18/2010 16:35:26 C:\Calcmet 9.14 vol-% wet 0.0022 10.28 ppm wet 0.0054 3/18/2010 16:35:29 C:\Calcmet 9.22 vol-% wet 0.0025 10.75 ppm wet 0.0049 3/18/2010 16:35:32 C:\Calcmet 9.23 vol-% wet 0.0025 12 ppm wet 0.0053 3/18/2010 16:36:39 C:\Calcmet 9.13 vol-% wet 0.0026 11.65 ppm wet 0.0051 3/18/2010 16:36:42 C:\Calcmet 9.06 vol-% wet 0.0023 13.86 ppm wet 0.0047 3/18/2010 16:36:45 C:\Calcmet 8.95 vol-% wet 0.0027 12.79 ppm wet 0.0048 3/18/2010 16:36:47 C:\Calcmet 9.02 vol-% wet 0.0022 13.34 ppm wet 0.0048 3/18/2010 16:36:50 C:\Calcmet 9.02 vol-% wet 0.0024 12.26 ppm wet 0.0047 

3/18/2010 16:36:53 C:\Calcmet 8.88 vol-% wet 0.0022 29.41 ppm wet 0.005 

3/18/2010 16:36:55 C:\Calcmet 8.95 vol-% wet 0.0024 28.11 ppm wet 0.0047 3/18/2010 16:36:58 C:\Calcmet 9.02 vol-% wet 0.0027 29.49 ppm wet 0.0051 3/18/2010 16:37:01 C:\Calcmet 8.91 vol-% wet 0.0024 12.2 ppm wet 0.0044 3/18/2010 16:37:04 C:\Calcmet 8.99 vol-% wet 0.0026 11.95 ppm wet 0.0049 3/18/2010 16:37:23 C:\Calcmet 9.08 vol-% wet 0.0025 5.18 ppm wet 0.0054 3/18/2010 16:37:27 C:\Calcmet 9.11 vol-% wet 0.0024 1.87 ppm wet 0.0046 3/18/2010 16:37:30 C:\Calcmet 9 vol-% wet 0.0026 0.91 ppm wet 0.0048 

3/18/2010 16:37:46 C:\Calcmet 9.04 vol-% wet 0.0022 0.47 ppm wet 0.0047 
 Compensa Residual

wet 0.0122wet 0.0143wet 0.015wet 0.0118wet 0.0131wet 0.0106wet 0.0091wet 0.0122wet 0.0109wet 0.0109wet 0.0118wet 0.0114wet 0.0083wet 0.0113wet 0.0131wet 0.0095wet 0.0113wet 0.0079wet 0.0087wet 0.0091wet 0.0088wet 0.0072wet 0.0067wet 0.0094wet 0.0087wet 0.0085wet 0.0065wet 0.0058wet 0.0056wet 0.0055wet 0.0058
Date Time SpectrumFile Water vap

oUnit Compens

3/18/2010 16:42:09 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03096.SPE 9.56 vol-% wet 3/18/2010 16:43:10 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03097.SPE 9.65 vol-% wet 3/18/2010 16:44:11 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03098.SPE 9.62 vol-% wet 3/18/2010 16:45:11 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03099.SPE 9.69 vol-% wet 3/18/2010 16:46:12 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03100.SPE 9.68 vol-% wet 3/18/2010 16:47:12 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03101.SPE 9.72 vol-% wet 3/18/2010 16:48:13 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03102.SPE 9.59 vol-% wet 3/18/2010 16:49:14 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03103.SPE 9.59 vol-% wet 3/18/2010 16:50:14 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03104.SPE 17.81 vol-% wet 3/18/2010 16:51:15 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03105.SPE 10.4 vol-% wet 3/18/2010 16:52:16 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03106.SPE 9.94 vol-% wet 3/18/2010 16:53:16 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03107.SPE 9.9 vol-% wet 3/18/2010 16:54:17 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03108.SPE 9.89 vol-% wet 3/18/2010 16:55:18 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03109.SPE 9.85 vol-% wet 3/18/2010 16:56:18 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03110.SPE 9.81 vol-% wet 3/18/2010 16:57:19 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03111.SPE 9.8 vol-% wet 3/18/2010 16:58:19 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03112.SPE 9.75 vol-% wet 3/18/2010 16:59:20 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03113.SPE 9.75 vol-% wet 3/18/2010 17:00:20 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03114.SPE 9.72 vol-% wet 3/18/2010 17:01:21 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03115.SPE 9.79 vol-% wet 3/18/2010 17:02:22 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03116.SPE 9.74 vol-% wet 3/18/2010 17:03:22 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03117.SPE 9.72 vol-% wet 3/18/2010 17:04:23 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03118.SPE 9.76 vol-% wet 3/18/2010 17:05:23 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03119.SPE 9.72 vol-% wet 3/18/2010 17:06:24 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03120.SPE 9.72 vol-% wet 3/18/2010 17:07:25 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03121.SPE 9.73 vol-% wet 3/18/2010 17:08:25 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03122.SPE 13.85 vol-% wet 3/18/2010 17:09:26 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03123.SPE 14.73 vol-% wet 3/18/2010 17:10:27 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03124.SPE 10.05 vol-% wet 3/18/2010 17:11:27 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03125.SPE 9.83 vol-% wet 3/18/2010 17:12:28 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03126.SPE 9.76 vol-% wet 3/18/2010 17:13:29 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03127.SPE 9.64 vol-% wet 3/18/2010 17:14:29 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03128.SPE 9.72 vol-% wet 3/18/2010 17:15:30 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03129.SPE 9.69 vol-% wet 3/18/2010 17:16:30 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03130.SPE 9.96 vol-% wet 3/18/2010 17:17:31 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03131.SPE 9.89 vol-% wet 3/18/2010 17:18:32 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03132.SPE 9.86 vol-% wet 3/18/2010 17:19:32 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03133.SPE 9.79 vol-% wet 3/18/2010 17:20:33 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03134.SPE 12.09 vol-% wet 
3/18/2010 17:21:33 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03135.SPE 10.07 vol-% wet 

3/18/2010 17:22:34 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03136.SPE 9.98 vol-% wet 3/18/2010 17:23:35 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03137.SPE 9.89 vol-% wet 3/18/2010 17:24:35 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03138.SPE 9.77 vol-% wet 3/18/2010 17:25:36 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03139.SPE 9.79 vol-% wet 3/18/2010 17:26:37 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03140.SPE 9.75 vol-% wet 3/18/2010 17:27:37 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03141.SPE 9.67 vol-% wet 3/18/2010 17:28:38 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03142.SPE 12.32 vol-% wet 3/18/2010 17:29:38 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03143.SPE 9.99 vol-% wet 3/18/2010 17:30:39 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03144.SPE 9.64 vol-% wet 3/18/2010 17:31:39 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03145.SPE 9.54 vol-% wet 3/18/2010 17:32:40 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03146.SPE 9.54 vol-% wet 3/18/2010 17:33:41 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03147.SPE 9.56 vol-% wet 3/18/2010 17:34:41 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03148.SPE 9.57 vol-% wet 3/18/2010 17:35:42 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03149.SPE 11.93 vol-% wet 3/18/2010 17:36:42 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03150.SPE 9.82 vol-% wet 3/18/2010 17:37:43 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03151.SPE 9.74 vol-% wet 3/18/2010 17:38:44 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03152.SPE 9.7 vol-% wet 3/18/2010 17:39:44 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03153.SPE 9.7 vol-% wet 3/18/2010 17:40:45 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03154.SPE 9.7 vol-% wet 3/18/2010 17:42:43 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03155.SPE 9.44 vol-% wet 3/18/2010 17:43:02 C:\CalcmetSamples\Lehigh 210158\20100318\ Run 3_03156.SPE 9.39 vol-% wet 

Averages 
Unit Compensa Residual SF6 Unit Compensa Residual

ppm wet 0.0061 0 ppm wet 0.0081ppm wet 0.0059 0 ppm wet 0.0091ppm wet 0.006 0 ppm wet 0.0087ppm wet 0.0059 0 ppm wet 0.0094ppm wet 0.0058 0 ppm wet 0.0098ppm wet 0.0055 0 ppm wet 0.0094ppm wet 0.0054 0 ppm wet 0.0088ppm wet 0.0052 0 ppm wet 0.0087ppm wet 0.0045 0 ppm wet 0.0357ppm wet 0.0046 0 ppm wet 0.0166ppm wet 0.0048 0 ppm wet 0.0109ppm wet 0.0051 0 ppm wet 0.0094ppm wet 0.0054 0 ppm wet 0.0091ppm wet 0.0056 0 ppm wet 0.0094ppm wet 0.006 0 ppm wet 0.0087ppm wet 0.0062 0 ppm wet 0.0087ppm wet 0.0065 0 ppm wet 0.0091ppm wet 0.0074 0 ppm wet 0.0089ppm wet 0.009 0 ppm wet 0.0085ppm wet 0.0101 0 ppm wet 0.0082ppm wet 0.0103 0 ppm wet 0.0089ppm wet 0.01 0 ppm wet 0.0096ppm wet 0.0096 0 ppm wet 0.0101ppm wet 0.0088 0 ppm wet 0.0095ppm wet 0.0081 0 ppm wet 0.0104ppm wet 0.008 0 ppm wet 0.0098ppm wet 0.0075 0 ppm wet 0.0211ppm wet 0.0068 0 ppm wet 0.035ppm wet 0.0076 0 ppm wet 0.0153ppm wet 0.0073 0 ppm wet 0.0121ppm wet 0.0071 0 ppm wet 0.0113ppm wet 0.0071 0 ppm wet 0.0109ppm wet 0.0071 0 ppm wet 0.0107ppm wet 0.0071 0 ppm wet 0.0105ppm wet 0.0071 0 ppm wet 0.0113ppm wet 0.0069 0 ppm wet 0.0112ppm wet 0.0069 0 ppm wet 0.0113ppm wet 0.0066 0 ppm wet 0.0108ppm wet 0.0065 0 ppm wet 0.0166
ppm wet 0.0063 0 ppm wet 0.0143

ppm wet 0.0062 0 ppm wet 0.0119ppm wet 0.006 0 ppm wet 0.0124ppm wet 0.0059 0 ppm wet 0.0112ppm wet 0.0059 0 ppm wet 0.0111ppm wet 0.006 0 ppm wet 0.0108ppm wet 0.0062 0 ppm wet 0.0111ppm wet 0.0063 0 ppm wet 0.0157ppm wet 0.0062 0 ppm wet 0.0144ppm wet 0.0061 0 ppm wet 0.0119ppm wet 0.0061 0 ppm wet 0.0104ppm wet 0.006 0 ppm wet 0.0094ppm wet 0.0064 0 ppm wet 0.0083ppm wet 0.0068 0 ppm wet 0.0085ppm wet 0.007 0 ppm wet 0.0136ppm wet 0.007 0 ppm wet 0.0126ppm wet 0.007 0 ppm wet 0.0089ppm wet 0.0081 0 ppm wet 0.0084ppm wet 0.0082 0 ppm wet 0.0086ppm wet 0.0076 0 ppm wet 0.0089ppm wet 0.0077 0.09 ppm wet 0.0057ppm wet 0.0082 0 ppm wet 0.0041
HCL Lehigh

Sm --Spiked Data

Date Method Filename HCl(ppm) SF6 (ppm)

03/18/10 321 C:\CalcmetSamples\L 25.91 C:\CalcmetSam 0.56

03/18/10 321 C:\CalcmetSamples\L 32.23 C:\CalcmetSam 0.9303/18/10 321 C:\CalcmetSamples\L 28.00 C:\CalcmetSam 0.88

Avg. Conc. (ppm) 0.790 28.71

Su -- Native Conc. Of analyte

Date Method Filename HCl(ppm) SF6 (ppm)

03/18/10 321 C:\CalcmetSamples\L 16.29 C:\CalcmetSam 0

03/18/10 321 C:\CalcmetSamples\L 22.97 C:\CalcmetSam 0.09

03/18/10 321 C:\CalcmetSamples\L 26.32 C:\CalcmetSam 0

Avg. Conc. (ppm) 0.030 21.86

Sm - Su(1-DF)

Recovery (%) = DF x Cs

Ce = DF x Cs + Su(1-DF)

Sm 28.71 ppm Mean concentration of spiked analyte

Su 21.86 ppm Native concentration of analyte

DF 7.6% % Dilution Factor (Target < 10%)

Cs 144.2 ppm Cylinder of spiked gas

 ppm Cylinder of tracer gas (SF6) 9.98

Ce 31.18 ppm Expected concentration of analyte

Recovery (%) 77.6% 70 - 130 %
Date Time SpectrumF Water vapoUnit Compensa Residual Hydrogen cUnit Compensa Residual 

3/18/2010 17:43:16 C:\Calcmet 9.36 vol-% wet 0.0028 24.75 ppm wet 0.0084 

3/18/2010 17:43:37 C:\Calcmet 9.48 vol-% wet 0.0024 25.91 ppm wet 0.0082 3/18/2010 17:43:55 C:\Calcmet 9.41 vol-% wet 0.003 32.23 ppm wet 0.0082 3/18/2010 17:44:11 C:\Calcmet 9.36 vol-% wet 0.0026 28 ppm wet 0.0087 3/18/2010 17:44:50 C:\Calcmet 9.4 vol-% wet 0.0022 25.04 ppm wet 0.0083 

3/18/2010 17:44:53 C:\Calcmet 9.46 vol-% wet 0.0028 24.47 ppm wet 0.0089 

3/18/2010 17:44:56 C:\Calcmet 9.45 vol-% wet 0.0027 23.92 ppm wet 0.0084 3/18/2010 17:44:59 C:\Calcmet 9.46 vol-% wet 0.0022 17.29 ppm wet 0.0084 3/18/2010 17:45:02 C:\Calcmet 9.35 vol-% wet 0.0026 5.28 ppm wet 0.0079 3/18/2010 17:45:25 C:\Calcmet 9.05 vol-% wet 0.0021 2.5 ppm wet 0.0069 3/18/2010 17:45:30 C:\Calcmet 9.19 vol-% wet 0.002 0.74 ppm wet 0.0074 
 Compensa Residual

wet 0.0059wet 0.0052wet 0.0046wet 0.0055wet 0.006wet 0.007wet 0.006wet 0.0061wet 0.0053wet 0.006wet 0.0066
Date Time SpectrumFile Water vap

oUnit 

3/18/2010 18:03:23 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan After_03339.SPE 0 vol-% 3/18/2010 18:03:26 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan After_03340.SPE 0.01 vol-% 3/18/2010 18:03:29 C:\CalcmetSamples\Lehigh 210158\20100318\CTS Scan After_03341.SPE 0 vol-% 3/18/2010 18:22:28 C:\CalcmetSamples\Lehigh 210158\20100318\CTS SCan After_03465.SPE 0 vol-% 3/18/2010 18:22:31 C:\CalcmetSamples\Lehigh 210158\20100318\CTS SCan After_03466.SPE 0 vol-% 3/18/2010 18:22:36 C:\CalcmetSamples\Lehigh 210158\20100318\CTS SCan After_03467.SPE 0 vol-% 3/18/2010 18:22:41 C:\CalcmetSamples\Lehigh 210158\20100318\CTS SCan After_03468.SPE 0 vol-% 3/18/2010 18:22:44 C:\CalcmetSamples\Lehigh 210158\20100318\CTS SCan After_03469.SPE 0 vol-% 3/18/2010 18:22:46 C:\CalcmetSamples\Lehigh 210158\20100318\CTS SCan After_03470.SPE 0.01 vol-% 3/18/2010 18:22:50 C:\CalcmetSamples\Lehigh 210158\20100318\CTS SCan After_03471.SPE 0 vol-% 3/18/2010 18:22:52 C:\CalcmetSamples\Lehigh 210158\20100318\CTS SCan After_03472.SPE 0 vol-% 3/18/2010 18:22:55 C:\CalcmetSamples\Lehigh 210158\20100318\CTS SCan After_03473.SPE 0 vol-% 3/18/2010 18:23:00 C:\CalcmetSamples\Lehigh 210158\20100318\CTS SCan After_03474.SPE 0 vol-% 3/18/2010 18:23:03 C:\CalcmetSamples\Lehigh 210158\20100318\CTS SCan After_03475.SPE 0 vol-% 3/18/2010 18:23:06 C:\CalcmetSamples\Lehigh 210158\20100318\CTS SCan After_03476.SPE 0 vol-% 3/18/2010 18:23:11 C:\CalcmetSamples\Lehigh 210158\20100318\CTS SCan After_03477.SPE 0.04 vol-% 3/18/2010 18:23:14 C:\CalcmetSamples\Lehigh 210158\20100318\CTS SCan After_03478.SPE 0 vol-% 3/18/2010 18:23:17 C:\CalcmetSamples\Lehigh 210158\20100318\CTS SCan After_03479.SPE 0 vol-% 3/18/2010 18:23:24 C:\CalcmetSamples\Lehigh 210158\20100318\CTS SCan After_03480.SPE 0 vol-% 3/18/2010 18:23:29 C:\CalcmetSamples\Lehigh 210158\20100318\CTS SCan After_03481.SPE 0 vol-% 3/18/2010 18:23:33 C:\CalcmetSamples\Lehigh 210158\20100318\CTS SCan After_03482.SPE 0 vol-% 3/18/2010 18:23:36 C:\CalcmetSamples\Lehigh 210158\20100318\CTS SCan After_03483.SPE 0 vol-% 3/18/2010 18:23:45 C:\CalcmetSamples\Lehigh 210158\20100318\CTS SCan After_03484.SPE 0 vol-% 3/18/2010 18:23:50 C:\CalcmetSamples\Lehigh 210158\20100318\CTS SCan After_03485.SPE 0.04 vol-% 3/18/2010 18:23:53 C:\CalcmetSamples\Lehigh 210158\20100318\CTS SCan After_03486.SPE 0 vol-% 

Averages
Hydrogen cUnit Compensa Residual SF6 Unit Compensa Residual

5.4 ppm wet 0.0005 0 ppm wet 0.00263.1 ppm wet 0.0006 0 ppm wet 0.00273.2 ppm wet 0.0005 0 ppm wet 0.0008

143.07 ppm wet 0.001 0 ppm wet 0.0026143.45 ppm wet 0.0009 0 ppm wet 0.0085143.65 ppm wet 0.0007 0 ppm wet 0.0126143.16 ppm wet 0.0007 0 ppm wet 0.0025145.25 ppm wet 0.001 0.03 ppm wet 0.002144.07 ppm wet 0.0008 0.02 ppm wet 0.0036

143.5 ppm wet 0.0008 0 ppm wet 0.003

144.83 ppm wet 0.001 0 ppm wet 0.0021

143.7 ppm wet 0.0011 0.04 ppm wet 0.0015

145.41 ppm wet 0.0011 0 ppm wet 0.0009

142.6 ppm wet 0.001 0 ppm wet 0.0017

144.26 ppm wet 0.0008 0 ppm wet 0.0035144.27 ppm wet 0.0007 0 ppm wet 0.0029143.24 ppm wet 0.0008 0 ppm wet 0.0049142.77 ppm wet 0.0007 0 ppm wet 0.0014

143.7 ppm wet 0.0013 0.04 ppm wet 0.003

142.86 ppm wet 0.001 0 ppm wet 0.0059143.79 ppm wet 0.0009 0 ppm wet 0.0028144.44 ppm wet 0.0008 0.01 ppm wet 0.0026144.66 ppm wet 0.0005 0 ppm wet 0.0052143.39 ppm wet 0.0009 0.06 ppm wet 0.0039144.55 ppm wet 0.001 0.06 ppm wet 0.002

144.166
Date Time SpectrumF Water vapoUnit Compensa Residual Hydrogen cUnit Compensa Residual 

3/18/2010 9:20:42 C:\Calcmet 0 vol-% wet 0.0007 1 ppm wet 0.0003 

3/18/2010 9:20:48 C:\Calcmet 0 vol-% wet 0.0009 0 ppm wet 0.0003 3/18/2010 9:20:54 C:\Calcmet 0 vol-% wet 0.0008 0 ppm wet 0.0004 3/18/2010 9:21:00 C:\Calcmet 0 vol-% wet 0.001 0 ppm wet 0.0002 3/18/2010 9:21:06 C:\Calcmet 0 vol-% wet 0.0004 0 ppm wet 0.0003 3/18/2010 9:21:12 C:\Calcmet 0 vol-% wet 0.0007 0 ppm wet 0.0003 3/18/2010 9:21:18 C:\Calcmet 0 vol-% wet 0.0006 0 ppm wet 0.0002 3/18/2010 9:21:24 C:\Calcmet 0 vol-% wet 0.0008 0 ppm wet 0.0003 3/18/2010 9:21:30 C:\Calcmet 0 vol-% wet 0.0008 0 ppm wet 0.0003 3/18/2010 9:21:36 C:\Calcmet 0 vol-% wet 0.0009 0 ppm wet 0.0003 3/18/2010 9:21:41 C:\Calcmet 0 vol-% wet 0.0006 0 ppm wet 0.0003 3/18/2010 9:21:47 C:\Calcmet 0 vol-% wet 0.0006 0 ppm wet 0.0003 3/18/2010 9:21:53 C:\Calcmet 0 vol-% wet 0.0005 0 ppm wet 0.0003 3/18/2010 9:21:59 C:\Calcmet 0 vol-% wet 0.0005 0 ppm wet 0.0003 
 Compensa Residual

wet 0.0023wet 0.0014wet 0.0023wet 0.0019wet 0.0032wet 0.0021wet 0.0023wet 0.0041wet 0.0008wet 0.0015wet 0.004wet 0.0015wet 0.002wet 0.0027