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## . . Septembe r 10 . 2008 14 :36- 1 6:46 

### Unit 2: Retest Run 1 . 

## ENSR 

# I I AECO M 

# I 1 2-6 Molecular Weight of the Stack Gas I 

## 1 

## M. = ((4 . 501bllb-mole'0 . 44)+(11.21 1bll b-mole'0. 32) + (84 . 291 b llb-mo le"0 .28t(1· 

# I 0 . 414 ))+18 ' 0.414 : 

## M.= 24.54 

### lbllb-mole 

### 2 · 7 Averag e Stack Gas Velocity 

# ! 

# v. 

# = 85 . 49 ftlsec [(( lbnb-mole)(in

# Hg)**)/(~)( in**  

# ! H:P) )] 112 •(0.84)(0.3363)-1{(384.6'lf+460)/((29.6 in Hg+0 .0969 in Hg)'(24 . 57

### bll~o**e))** 

# v. 

# = 26.037 ft/sec • 60 sec/min V • 

### = 1562 ftlml n 

### 2-8 Average Sta c k Gas Dry 

### Volumetric Flow Rate 

# l a = ( 1 · 0.414)( 1 562 ft/m in )( 1194 . 6 in 2 )( 1 1\'/ 144

### in**)1(528~'29.61** i n Hg)/(29. 92jin Hg'(384.6'lf+460))) 

# a = 4698 ftltmin 

# l . 3-1 Dry Molecular Weight M• 

### = 0.440 ( 4 . 50 %)+0.320(1 1.2 1%)+0 . 280(100-{4.50%+ 11 . 2 1 %)) 

### Mo = 29.1 7 1b11b-mole . 

### 4-1 Volume of Water Vapor Condensed Vwc(11cl)= 0.04715 ftltmt • ((930 mt + 260 ml +1 25 ml+ 360 . 3 g)-(200 ml+346.7g)) V-.s1cl)" 53 . 213 ftl 

### +2 Volume of Water Collected in Silica 

### Gel V-= ((360.3 g . -346.7 

## g (0 . 06236

## mm**Hg)m gm** **ole (~(293**  Oj{ ))/(76 0 mmg H9)(18 . 0 g/gmole)(1 . 0g/pl · V-=0.018m V._= 0.636 

## ttl 4-3 Sample Gas Volume v.- = 1.02 1 • ((653.131 

# rr - 575.565 ftl - (6 16 .044 

## ttl- 615 . 86 ttll<29 . ao 

### in Hg i-+(). 0969 i n Hg)(528**~))1~29.92** in Hg'(89 . 9 "F+460) V,....= 75 .295 

### It



### VES 003242

# c

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### 4-4 Moisture Content 

## Bw. = (52.213 11"+0 .636 ft")/ (52.2 13 11"+0.636 ft 3 

### +75.296 

## II") Bw.= 0.412 .1 00(%) 

## Bw.= 4 1 . 2% 5-8 

### lsoklnetic Variation from 

### Raw Data or 

### lntennedlate Values 

## ENSR 

# i l AECOM

I ,;,

### 144**in iff•4111"(100** **(~.6"F+460)(75.2 96**  11")'29 . 92 In Hg ))/((52e0R) (1562 ] fthnin)(0 . 435 ln )'(29.61 in Hg)( 1 2 0 min)(1 -. 414)) · I = 

### 106 . 97% 

# I 29-1 In-Stack Detection Limits A'BIC =D 

### Front - Half 

### D 

## = 0.00013'(30012.13) D 

# = 0 .018 

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## = 0.0046 ugtm; Back-Half 

### 0 

# = 0 . 000033.(150/2.13) 0 

# = 0. 0023 ugtm'
Front-Half



### . 0..:..... 2008 

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VES 003243

# (

# ENS~**IA ECOM**  0 

### = 0 . 000033 *( 30012. 13} D = 0 . 0046 ug/m 3 

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### D = 0 . 000033 * ( 1 5012.13} D = 0.0023 ug/m 3 

### Cr Front-HtJif 

### D 

# = 0 . 000 1 * ( 30012.13 } D 

# = 0 . 014 

## ug/m 3 

### Back-Half 

### D = 0.000 1* (15012. 1 3) D 

# = 0 . 0070 ug/m 3

### ~ 

# , , 

# c Fron t-Half 

### D 

# = 0 . 000066 * (30012.13} D 

# = 0 . 0093 ug/m 3 

### Back-Half 

### D = 0.()()0()66"( 15012 .13) D 

# = 0 . 0046 ug/m 3 

### .!jg Front-Hatf 

### 18 D = 0 . 00005 * (30012 .1 3} D = 0 . 0070 

## ug/m 3 

### Back-Half 28 

# (, _ Oooemboo 2008


### VES 003244' 

# c ·

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# .. D 

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### 0 

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### 3 8 0 

### = 0. 0001*(50012 . 1 3 ) D 

## = 0 . 023 ug!m 3 

### 3C 0 

## = 0.0001*(25012 . 13 ) · 

### D = 

### 0 . 012 uglm 3 

### 29-2 Analytical Fraction 1A , Front - Half, Metals _(Except Me rc ury) 

## Mw> = 

# c ,, F6 

# v-., M Me.= 0 . 202 * 50*0 . 3 M., = 3 . 0ug 

## !!:! Me. = -0 . 004 * 50 * 0 . 3 

## Me. 

# = ..{) . 006 

### ug (NO) 

## Cd Mt. 

### = 0 . 005*50 *0. 3 M., 

# = O.D75 ug 

### (NO) 

## C

r 

## Mo. 

# = 0 . 830 *50* · 0.3 

### Me. = 12.4 5 ug



### o.c..- 2 DOt


### VES 003245

# ( ENSR I I AECO M 

## fll Mo, = 3 . 033"50"0 . 3 

### Mo, = 45 . 5 

### ug

# ~ 29-3 Analytical Fractio n 2A , 

### Bac k · Half , Metals (Except Me rc ury ) Mot. = 

# c .. F. v-.,**~** 

## A! :• 

### Mot. = 0 . 055*1 0 * 0 . 15 Mt.,= 0 . 10ug 

### Be 

## Mt.t. = 0.001* 10"0.15 

# Mot, = 0 . 015 ug ( NO ) 

### Cd 

# c · .\ 

## 1\.\o. 

## = 1 . 697'10*0.15 Mot. = 2 . 55 ug { NO )

### ~ Mot.= 0 . 290 * 10 * 0.15 Mt..=0 . 44 

### ug Pb 

# """"= 0 . 218"10*0.15 

## Mot. = · 0.33 ug 

### 29 -4 Total Train,**~atals** 

### (Except Mer c ury) 

### Mt 

## =**(M~t~·Mt~~>)** + 

### (Mt..-Mt,) 

## , . A s 

### Mt = (3 . 0 - 0.2) 

### + (0.1 - 0.10) 

### Mt = 2 . 8 ug 

# L · Oooltnbol 2001


### VES 003246

# (

{ Be 

## Mt = (0.25- 0 . 05) + 

### (0 . 025- 0 . 0 25) 

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# = 0 . 20 ug 

### M

1 

# = (0 . 25 - 0.05 ) + 

### (2 . 55- 0.03) 

## Mt = 2 . 73ug 

## Mt = 

### (12 . 5- 0.61) + 

### (0. 44- 0. 1 7) 

## Mt = 12 . 16 ug Pb



## . Mt = (83 . 3- 

### 0.22) + 

### (0.59- 0.14)



## Mt = 83 . 5 ug 

### Unit 2: Run 1 29-5 AnaJYtlcal Fraction 18; Front-Half Mercury 

# Hg., = o.,F.v....,, HQftl= 

### 8 .68 7 '1'0 . 3 

### H9111 

# = 2 . 61 ug 29-6 

### Amount of Mercury 

### Collected In Samp" Fraction .2 H!Jot,2 = 

### Ow F•V-.2 

## Hgl>ll2 

## = 4 . 712 ' 10'1 . 365 

## H9l>ll2 = 64 . 3 ug 

# ENSR \ 1

AECOM

29-7 Back-Half Mercury Values for 

### Analytical Fractions 3A, 38, and 3C HQI>h3 (A) = 

### 3 . 52B- 10' 0 . 1 H g,.,.tA>= 

### 3 . 74 

### ug**~(B) =**  

### 5 . 539 '1"0 . 5

VES 003247

# c H9ons (8) 

## = 5 . 13 

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### 3.125 '1 '0 . 25 H!lw<C l= 7 . 81 U9 

## Owc-..e . c> 

## = 3.74+5 . 13 + 7.81 

## = 1 6 . 68 

## ug 1 

## EN S R I IAEC OM .

29-8 T o tal Amount o f Mercury Collected 

### In the Ba c k-Hatf of the Sampling Train 

### ' HQb! 

# = Hg,z + 

### H !lot>lA + 

### Ho- + 

### Hgwc H Qb! 

### = 64.3 + 

### 3 . 74 + 5.13 

### + 7.81 

### H

901 

### = 80 . 98 

### ug . .

## ~ 29-9 T o tal Amount of M e rcury Coll ec ted In th e Back-Half o f 

### the**Samplln ~**  

### Train 

### Hg, 

### = (Hg.,**~** 

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### Hg, 

## = (2.61 - 0 . 0 1 ) + (80.98- 0 . 09) Hg,= 83 .5 

## ug 

## Un i t 2 : Retest 1 29-10 Ind ivi dual Metal C o ncentra ti ons i n Staek Gas 

### Ca= ( K. MiJN.w.uJ> As 

# c.= (1o-&2.8)1(75.296"0.2832) 

# c.= 0 . 0013 mgl m 3 

## !!! 

# c.= (1o-3 ' 0.20)1(75.296'0.2832) 

### C. = 0 . 0001 mgl m 3 

### . B e c orrec ted for 7% 

### Oa 

# c.= (0 . 20'3 5 . 31 4' 14)1((75.296'21-11 . 21)) 

### C.= 0 . 1 3 uglm 3

. 

## C

d C.= (10 ' 3o2.73)/(75 . 296'0.2832) 

# c.= 0.0013 

### mgtm 3



### VES 003248

# ( Cd coqected for 7 % 

### Oa 

# c.= (2.73"35.314" 14 )/((75 . 296.21 - 11 . 21)) 

### C.= 1.83 ug/m 3 

# 9: 

# c.= (10-3.12 . 16)1(75 . 296"0 . 2832) 

### C.= 0 . 0057 mg/m 3



### Pb 

# c.= (1o ·• ·45 . 57)1(75 .29 6*0 . 2832) c . = 0 . 021 mg/ m 3


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# ENSRI AECOM BAROMETERCAT .ffiRATIO N DATA FORM Field Barometer 1 0#: Serial 

### No. 511 11 291 

### Reference Barometer 

### 10 

## t1: Settal No. 188841


### Pre -Test 

### calibration 

### data Calibration Pedo!rned**~** : Ryan Bums

# ~**r~Erl** Reid Barometer

# ~**3~~ ~**  .

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### 29 . 16


### Po st -T est 

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### data C alibration Pedonned By : 

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### . in. Hg 

### .!:. +/ - 0.10 ln. Hg

Note : The field barometer**Is~** to agree IMth the reference barome ter after each cal ib ration . Th e 

### rellwence barometer is rlled<ed and re-calibnrted by the vendor on an annual basis. 

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# - 50.5 101 2008105128 62.0 ' 104 2008105128 51.0 102 

# - 50.0 100 

# - 51.5 103 ug 86 ·116 ug 85. 115 ug 80·110 ug 80 · 110 ug % 20 ug 85· t 115 ug 15 .. 115 ug 80. 11 0 

# "" 80·110 ug % 20 ug 85. t15 ug 86 ·115 ug ug ug % ug ug ug ug ug ug % ug ug ug TO· t30 ug TO· t30 ug 70·130 ug 70·130 ug 70-130 ug 70 · 130 ug 70 · 130 ug 70 - 130 

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### 104 ENI Syno:use, NY USA 13C57-4232


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### VES 003279

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## Date : 2008 .09.18 15 :23: 50 .()4'00'

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### SES Standards 

### CE 1 : Leading Change ARD Branch Chiefs' Quarterly Report FY2015, I " Quarter Update

• Successfully assumed re sponsibility for air sub-lead Region for tribes , leading an effort with OAR to include tribal air quality goals comprehensively in National Program Guidance and establishing new processes and procedures for the Regional Tri b al 

## Air Coordin at ors group to better support OAR and the tribal air pro gram. 

### (APB) 

# • CE 2: Leading People 

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# • CE 3 : Business Acumen 

# • • CE 4: Building Coalitions 

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### (APB) . 

# • Organizational Assessment 

## Key Events /

Issues / Challenges and . Management Actions 

# . . • Accomplishments that Support FY2014 Cross - Agency Strategy Action Pla11S

-A New Era of State , Tribal , Loca l , and 

### International Partnerships :