## 6 **5 4**  **3 2**  **1**

Coal 0% 10% 50% 95% 95% 99% Bagasse 0% 10% 50% 95% 95% 99% Wet Biomass 0% 10% 50% 95% 95% 99% Dry Biomass 0% 10% 50% 95% 95% 99% Heavy Liquid 0% 10% 50% 95% 95% 99% Light Liquid 0% 10% 50% 95% 95% 99% Gas 1 0% 10% 50% 95% 95% 99% Gas 2 0% 10% 50% 95% 95% 99% Coal 0% 9% 9% 82.35% 66.54% 87.13% Bagasse 0% 0% 10% 75% 75% unknown Wet Biomass 0% 0% 10% 75% 75% unknown Dry Biomass 0% 0% 10% 75% 75% unknown Heavy Liquid 0% 0% 10% 75% 75% unknown Light Liquid 0% 0% 10% 75% 75% unknown Gas 1 0% 0% 10% 75% 75% unknown Gas 2 0% 0% 10% 75% 75% unknown Coal 0% 92.5% 95% 95% 98% 99% Bagasse 0% 40% 90% 90% 98% 99% Wet Biomass 0% 40% 90% 90% 98% 99% Dry Biomass 0% 45% 85% 85% 98% 99% Heavy Liquid 0% 80% 94% 94% 98% 99% Light Liquid 0% 80% 94% 94% 98% 99% Gas 1 0% 75% 50% 98% 98% 99% Gas 2 0% 75% 50% 98% 98% 99% Coal
- 0% 0% 70% 95% 95% Bagasse - 0% 0% 70% 95% 95% Wet Biomass - 0% 0% 70% 95% 95% Dry Biomass - 0% 0% 70% 95% 95% Heavy Liquid - 0% 0% 70% 95% 95% Light Liquid - 0% 0% 70% 95% 95% Gas 1
- 0% 0% 70% 95% 95% Gas 2
- 0% 0% 70% 95% 95% Coal
- 0% 0% 0% 43% 43% Bagasse - 0% 0% 0% 43% 43% Wet Biomass - 0% 0% 0% 43% 43% Dry Biomass - 0% 0% 0% 43% 43% Heavy Liquid - 0% 0% 0% 43% 43% Light Liquid - 0% 0% 0% 43% 43% Gas 1
- 0% 0% 0% 43% 43% Gas 2
- 0% 0% 0% 43% 43% 

# Appendix C: Estimated Emission Reductions for Baseline Emission Factors **Percent Reduction for Control Group:**

**Me rcury (Hg)** **2-3**



## Particulate Matter (PM)**1**



## Hydrogen Chloride (HCl)**4-5**



## Hydrogen Fluoride (HF)**4-5** 

## Fuel Category **Me tals (Sb, A**  **s, Be, Cd, Co, Cr, Pb, Mn, Ni, Se) 1** 

## 6 **5 4**  **3 2**  **1**



# Appendix C: Estimated Emission Reductions for Baseline Emission Factors **Percent Reduction for Control Group: Fuel Category**  Coal
- 0% 0% 0% 87% 87% Bagasse - 0% 0% 0% 87% 87% Wet Biomass - 0% 0% 0% 87% 87% Dry Biomass - 0% 0% 0% 87% 87% Heavy Liquid - 0% 0% 0% 87% 87% Light Liquid - 0% 0% 0% 87% 87% Gas 1
- 0% 0% 0% 87% 87% Gas 2
- 0% 0% 0% 87% 87% Coal
- 0% 0% 70% 95% 95% Bagasse - 0% 0% 70% 95% 95% Wet Biomass - 0% 0% 70% 95% 95% Dry Biomass - 0% 0% 70% 95% 95% Heavy Liquid - 0% 0% 70% 95% 95% Light Liquid - 0% 0% 70% 95% 95% Gas 1
- 0% 0% 70% 95% 95% Gas 2
- 0% 0% 70% 95% 95% **Sulfur Dioxide (SO2) 4-5**  

## Chlorine (Cl2)**4-5**

5

## http://www.deq.state.mi.us/aps/downloads/permits/CFPP/2007/297- 07/PC%20Boiler%20Case%20by%20Case%20MACT%20final.pdf 1

## AP-42 2

## http://www.epa.gov/ttn/atw/utility /hgwhitepaperfinal.pdf 3

## http://www.icac.com/files/public/hgcontrol010305.pdf 4

## http://www.icac.com/i4a/pages/index.cfm?pageid=3401

### Appendix D-1: Major Source Baseline Emission Factors for Organic HAP and CO for Existing Units

**Fuel Category 1**  **Combustor Design 2**  **NOx Control? 3**  **Total # of Units in Subcategory**  **THC**

**(ppm @ 3% as Propane)**  **THC # of**

**Data Points TEQ** 

**Dioxins/ Furans**  **(ng/dscm @ 7% O2)**  **TEQ Dioxins/**

**Furans # of Data Points**  **CO (ppm @**

**3% O2) CO # of Data** 

**Points Formaldehyde** 

**(ppm @ 3% O2) Formaldehyde #** 

**of Data Points NOx (ppm @** 

**3% O2) NOx # of** 

**Data Points** Yes 1 8.3 1 0.055 - 44.2 1 No 34 45.1 20 0.171 8 124.8 24 Yes 64 51.3 27 0.303 7 271.7 35 No 126 23.4 13 0.666 3 377.6 13 Yes 33 171.2 5 0.055 2 236.4 8 No 358 516.9 41 0.358 8 376.3 32 Yes

- No 2 801.2 - 0.300 - 107.6 - Yes 5 6674.4 5 34.847 3 97.4 1 No 13 3291.7 8 4.812 4 167.1 1 Yes

- No 24 263.9 14 0.737 9 153.2 8 Yes 5 94.5 3 0.051 3 124.5 3 No 14 115.8 2 0.030 3 129.3 3 Yes

- No 12 782.0 6 1.656 2 116.1 3 Yes 40 315.2 9 0.240 1 183.3 8 No 266 932.0 73 0.602 13 180.0 21 Yes

- No
- Yes

- No

- Yes

- No 5 415.6 - 6.343 - 286.3 - Yes

- No

- Yes 5 415.6 - 6.343 - 107.4 - No 69 415.6 4 6.343 3 286.3 2 Yes 7 315.0 4 1.038 - 107.4 2 No 40 351.1 3 1.038 2 959.399 1 Yes 58 13.4 7 0.001 3 261.2 8 12.16 12.162 Coal FB PC Stoker/Sloped Grate/Other 366.01 12.00 10.91 9.53
Bagasse Fuel Cell Suspension/Grate

Dry Biomass Dutch Oven/Pile Burner FB

Stoker/Sloped Grate/Other Suspension Burner Fuel Cell 70.89 372.64 12.37 8.87 13.48 8.89 Wet Biomass Dutch Oven/Pile Burner FB Fuel Cell

Suspension Burner Stoker/Sloped Grate/Other 0.012 0.075 0.005 0.007

1

- 7 11 11 2

0.006 16 6 6 2 11

1 6 9 11

-

0.034 0.034 5

- 5

0.011 0.006 0.087 0.014 0.008

1

5

1

- 2

Yes 58 13.4 7 0.001 3 261.2 8 No 304 136.6 16 0.155 6 206.8 13 Yes 86 44.5 39 0.467 3 56.4 12 No 497 59.3 24 0.102 4 138.5 9 Yes 6 3.1 2 0.007 1 144.3 1 No 123 32.6 3 0.007 - 31.4 11 Yes 1986 3.17 17 47.7 535 0.203 8 47.6 327 No 9198 9.37 8 71.8 360 0.2 7 69.0 128 Yes 153 94.09 2 152.8 2 1.192 2 91.5 2 No 547 75.53 6 761.2 11 0.7 4 25.4 6 Notes: 8

**Yellow Cells:**Where there is no reported data for a coal subcategory, the baseline average for coal/stoker was used to fill the data gap.Where there is no reported data for a bagasse subcategory, the baseline averages from the same wet biomass subcategory were used to fill the data gaps. Where there is no reported data for a w et biomass subcategory, the baseline averages from the same dry biomass subcategory were used to fill the data gaps. Where there is no reported data for a dry biomass subcategory, the baseline average for dry biomass/stoker was used to fill the data gaps. Gas 1
- Gas 1 Metals Furnaces - 0.079 5 0.005 Heavy Liquid - Light Liquid - 12.70 3.00 Process Gas
- 15.67

1 9

0.006

0.003 0.014 5

6 1 8**Fuel Category Non-Hg Metals**  **Control Category Total # of** 

**Units in Sub Category**  As

(lb/MMBtu) As # of

Data Points Be

(lb/MMBtu) Be # of

Data Points Cd

(lb/MMBtu) Cd # of

Data Points Co

(lb/MMBtu) Co # of

Data Points 1 257 7.45E-05 60 2.68E-06 63 5.23E-06 60 5.89E-05 20 2 265 3.06E-05 79 1.22E-06 74 3.47E-06 74 6.19E-06 5 3 19 7.84E-05 6 2.09E-06 6 4.19E-06 6 1.61E-07 - 4 7 1.77E-05 3 9.58E-07 3 1.65E-06 4 1.61E-06 1 5 68 1.68E-04 5 1.28E-05 5 3.18E-06 5 2.90E-06 - 3.22E-06 1 - 1.01E-07 - 8.94E-09 - 3.83E-08 - 8.53E-08 - 2 2 5.06E-07 - 4.47E-08 - 1.92E-07 - 1.18E-06 - 3 3 7.96E-06 2 2.42E-07 2 1.99E-06 2 8.54E-06 - 4 14 5.06E-06 1 4.47E-07 1 1.92E-06 1 8.06E-07 - 5 1 9.10E-06 - 8.05E-07 - 3.45E-06 - 1.45E-06 - 1.01E-05 8.94E-07 3.83E-06 1 12 6.19E-06 3 1.06E-07 2 8.15E-07 3 8.53E-08 1 2 174 2.08E-06 32 1.33E-07 30 6.98E-07 34 1.18E-06 13 3 51 3.13E-04 12 8.31E-07 12 5.94E-06 12 8.54E-06 3 4 31 2.49E-05 9 8.60E-06 8 3.60E-06 10 8.06E-07 - 5 93 1.61E-05 19 1.63E-07 18 7.14E-06 20 1.45E-06 2 1.61E-06 1 11 7.04E-07 - 2.80E-09 - 7.21E-08 - 3.42E-09 - 2 38 7.87E-07 1 3.94E-08 1 7.87E-07 1 1.71E-08 - 3 3 7.16E-07 1 1.59E-07 1 5.14E-07 1 3.08E-07 1 4 2 3.52E-05 - 1.40E-07 - 3.60E-06 - 1.71E-07 - 5 70 6.33E-05 2 2.52E-07 2 6.49E-06 2 3.08E-07 - 7.04E-05 2.80E-07 7.21E-06 3.42E-07 1 3 2.54E-07 - 1.21E-07 - 1.20E-07 - 4.71E-07 - 2 7 2.88E-06 2 1.20E-07 2 8.85E-08 2 1.03E-07 1 3 3 2.54E-06 - 1.21E-06 - 1.20E-06 - 4.71E-06 - 4 1 2.54E-05 - 1.21E-05 - 1.20E-05 - 4.71E-05 - 5 3 2.61E-06 1 2.18E-05 - 2.16E-05 - 3.18E-05 5 6 345 5.08E-05 77 2.43E-05 74 2.40E-05 77 9.42E-05 38 1 10 1.92E-06 - 5.72E-07 - 2.57E-07 - 2.25E-07 - 2 2 9.58E-06 - 2.86E-06 - 1.29E-06 - 1.12E-06 - 3 - 9.58E-06 - 2.86E-06 - 1.29E-06 - 1.12E-06 - 4 - 9.58E-05 - 2.86E-05 - 1.29E-05 - 1.12E-05 - 5 9 1.72E-04 - 5.15E-05 - 2.32E-05 - 2.02E-05 - 6 562 1.92E-04 120 5.72E-05 122 2.57E-05 122 2.25E-05 59 1 - 4.68E-08 - 9.54E-10 - 5.09E-07 - 2.59E-09 - 2 - 2.34E-07 - 4.77E-09 - 2.55E-06 - 1.29E-08 - 3 - 2.34E-07 - 4.77E-09 - 2.55E-06 - 1.29E-08 - 4 - 2.34E-06 - 4.77E-08 - 2.55E-05 - 1.29E-07 - 5 - 4.21E-06 - 8.59E-08 - 4.58E-05 - 2.33E-07 - 6 129 4.68E-06 1 9.54E-08 1 5.09E-05 1 2.59E-07 1 1 8 1.37E-08 - 3.61E-10 - 1.48E-09 - 1.91E-09 - 2 10 6.84E-08 - 1.81E-09 - 7.42E-09 - 9.55E-09 - 3 1 6.84E-08 - 1.81E-09 - 7.42E-09 - 9.55E-09 - 4 11 6.84E-07 - 1.81E-08 - 7.42E-08 - 9.55E-08 - 5 19 1.23E-06 - 3.25E-08 - 1.34E-07 - 1.72E-07 - 6 11135 1.37E-06 13 3.61E-08 10 1.48E-07 15 1.91E-07 8 1 2 1.55E-06 - 1.17E-09 - 6.78E-09 - 2.21E-08 - 2 - 7.75E-08 - 5.86E-09 - 3.39E-08 - 1.10E-07 - 3 - 7.75E-08 - 5.86E-09 - 3.39E-08 - 1.10E-07 - 4 - 7.75E-07 - 5.86E-08 - 3.39E-07 - 1.10E-06 - 5 - 1.39E-06 - 1.06E-07 - 6.10E-07 - 1.98E-06 - 6 698 1.55E-06 5 1.17E-07 5 6.78E-07 5 2.21E-06 5 

### Appendix D-2: Major Source Baseline Emission Factors for Fuel-Based HAP and SO2 for Existing Units

Coal

Bagasse

Wet Biomass

Gas 1 Metals Furnaces Gas 1 Dry Biomass

Heavy Liquid

Light Liquid

Process GasCr (lb/MMBtu) Cr # of

Data Points Ni

(lb/MMBtu) Ni # of Data

Points Mn

(lb/MMBtu) Mn # of

Data Points Pb

(lb/MMBtu) Pb # of

Data Points Sb

(lb/MMBtu) Sb # of

Data Points Se

(lb/MMBtu) Se # of

Data Points TSM8

(lb/MMBtu) TSM10

(lb/MMBtu) 5.44E-05 60 5.24E-05 60 7.51E-04 61 5.61E-05 64 1.11E-04 21 1.01E-04 60 1.10E-03 2.89E-03 1.59E-05 79 1.90E-05 80 7.12E-05 80 1.64E-05 79 3.47E-06 5 1.09E-04 77 2.76E-04 2.61E-04 3.52E-05 6 1.08E-04 6 2.72E-05 6 1.56E-04 6 4.61E-07 - 2.77E-05 6 4.39E-04 7.91E-06 9.77E-06 3 1.64E-05 4 9.77E-05 3 2.84E-05 3 4.61E-06 1 2.25E-05 3 1.95E-04 7.91E-05 7.03E-05 5 1.65E-04 5 1.13E-04 5 2.17E-04 5 8.29E-06 - 1.64E-04 5 9.14E-04 1.42E-04 9.21E-06 1.58E-04 1.45E-06 - 2.37E-06 - 1.24E-06 - 4.27E-07 - 7.94E-08 - 9.06E-08 - 5.47E-06 1.92E-05 7.25E-06 - 1.19E-05 - 5.15E-04 1 2.14E-06 - 9.44E-07 - 4.53E-07 - 2.73E-05 1.36E-04 5.47E-06 2 6.36E-06 2 1.72E-04 2 2.35E-05 2 2.36E-05 - 3.40E-07 2 2.08E-04 3.04E-03 7.25E-05 1 1.19E-04 1 6.18E-05 2 2.14E-05 1 2.06E-06 - 4.53E-06 1 2.73E-04 9.76E-04 1.31E-04 - 2.14E-04 - 1.11E-04 - 3.84E-05 - 3.72E-06 - 8.15E-06 - 4.92E-04 1.76E-03 1.45E-04 2.37E-04 1.24E-04 4.27E-05 9.06E-06 5.47E-04 4.52E-06 3 4.77E-06 3 1.69E-05 3 1.38E-05 3 7.94E-08 1 2.57E-07 3 4.16E-05 1.92E-05 4.42E-06 32 4.62E-06 30 3.62E-04 40 7.60E-06 35 9.44E-07 14 2.71E-06 29 2.01E-04 1.36E-04 2.86E-05 12 1.31E-05 12 4.59E-04 17 3.73E-04 12 2.36E-05 3 5.11E-06 12 9.51E-04 3.04E-03 1.59E-05 10 3.11E-05 10 3.43E-04 11 9.66E-05 10 2.06E-06 - 2.18E-06 8 5.05E-03 9.76E-04 2.07E-05 20 1.31E-05 17 3.45E-03 34 1.46E-04 20 3.72E-06 2 4.20E-06 17 2.23E-03 1.76E-03 4.13E-06 1.95E-03 7.61E-07 - 1.77E-07 - 4.84E-05 - 5.43E-07 - 4.74E-09 - 3.29E-08 - 6.79E-04 1.64E-05 7.88E-07 1 1.40E-06 1 1.99E-04 1 1.42E-06 1 2.37E-08 - 1.58E-07 1 5.69E-05 1.42E-05 5.36E-06 1 3.03E-06 1 8.60E-06 1 7.98E-06 1 4.26E-07 1 1.51E-06 1 8.06E-07 1.23E-06 3.81E-05 - 8.86E-06 - 2.42E-03 - 2.71E-05 - 2.37E-07 - 1.64E-06 - 8.06E-06 1.23E-05 6.85E-05 2 1.60E-05 2 4.36E-03 4 4.88E-05 2 4.26E-07 - 2.96E-06 2 1.45E-05 2.22E-05 7.61E-05 1.77E-05 4.84E-03 5.43E-05 4.74E-07 3.29E-06 1.61E-05 2.46E-05 2.92E-07 - 9.07E-06 - 3.62E-05 - 4.44E-07 - 3.87E-07 - 3.24E-07 - 2.37E-06 2.79E-06 1.54E-06 2 1.27E-04 2 1.06E-05 2 1.50E-06 2 1.12E-07 1 1.04E-05 2 1.55E-04 2.73E-05 2.92E-06 - 9.07E-05 - 3.62E-04 - 4.44E-06 - 3.87E-06 - 3.24E-06 - 2.37E-05 2.79E-05 2.92E-05 - 9.07E-04 - 3.62E-03 - 4.44E-05 - 3.87E-05 - 3.24E-05 - 2.37E-04 2.79E-04 7.44E-06 1 5.65E-04 1 6.51E-03 - 7.99E-05 - 1.19E-04 1 1.08E-06 1 6.45E-04 7.96E-04 5.84E-05 77 1.81E-03 76 7.24E-03 75 8.88E-05 77 7.74E-05 38 6.49E-05 61 4.73E-04 5.58E-04 2.86E-06 - 2.40E-06 - 1.82E-04 - 3.30E-06 - 1.19E-06 - 2.10E-06 - 2.29E-06 3.12E-06 1.43E-05 - 1.20E-05 - 9.10E-04 - 1.65E-05 - 5.94E-06 - 1.05E-05 - 1.14E-05 1.56E-05 1.43E-05 - 1.20E-05 - 9.10E-04 - 1.65E-05 - 5.94E-06 - 1.05E-05 - 1.14E-05 1.56E-05 1.43E-04 - 1.20E-04 - 9.10E-03 - 1.65E-04 - 5.94E-05 - 1.05E-04 - 1.14E-04 1.56E-04 2.58E-04 - 2.16E-04 - 1.64E-02 - 2.97E-04 - 1.07E-04 - 1.89E-04 - 2.06E-04 2.81E-04 2.86E-04 125 2.40E-04 125 1.82E-02 125 3.30E-04 124 1.19E-04 61 2.10E-04 123 2.29E-04 3.12E-04 9.09E-08 - 6.57E-08 - 8.22E-08 - 2.12E-08 - 2.58E-09 - 5.35E-08 - 8.70E-07 8.75E-07 4.54E-07 - 3.28E-07 - 4.11E-07 - 1.06E-07 - 1.29E-08 - 2.68E-07 - 4.35E-06 4.38E-06 4.54E-07 - 3.28E-07 - 4.11E-07 - 1.06E-07 - 1.29E-08 - 2.68E-07 - 4.35E-06 4.38E-06 4.54E-06 - 3.28E-06 - 4.11E-06 - 1.06E-06 - 1.29E-07 - 2.68E-06 - 4.35E-05 4.38E-05 8.18E-06 - 5.91E-06 - 7.40E-06 - 1.91E-06 - 2.32E-07 - 4.82E-06 - 7.83E-05 7.88E-05 9.09E-06 1 6.57E-06 1 8.22E-06 1 2.12E-06 1 2.58E-07 1 5.35E-06 1 8.70E-05 8.75E-05 4.17E-08 - 3.00E-08 - 4.42E-08 - 9.78E-09 - 1.80E-08 - 3.41E-09 - 1.43E-07 1.69E-07 2.08E-07 - 1.50E-07 - 2.21E-07 - 4.89E-08 - 9.00E-08 - 1.70E-08 - 7.16E-07 8.44E-07 2.08E-07 - 1.50E-07 - 2.21E-07 - 4.89E-08 - 9.00E-08 - 1.70E-08 - 7.16E-07 8.44E-07 2.08E-06 - 1.50E-06 - 2.21E-06 - 4.89E-07 - 9.00E-07 - 1.70E-07 - 7.16E-06 8.44E-06 3.75E-06 - 2.70E-06 - 3.98E-06 - 8.80E-07 - 1.62E-06 - 3.07E-07 - 1.29E-05 1.52E-05 4.17E-06 13 3.00E-06 16 4.42E-06 15 9.78E-07 14 1.80E-06 10 3.41E-07 11 1.43E-05 1.69E-05 1.74E-07 - 8.86E-08 - 2.97E-06 - 2.28E-08 - 2.61E-08 - 2.78E-08 - no data no data 8.71E-07 - 4.43E-07 - 1.48E-07 - 1.14E-07 - 1.31E-07 - 1.39E-07 - no data no data 8.71E-07 - 4.43E-07 - 1.48E-07 - 1.14E-07 - 1.31E-07 - 1.39E-07 - no data no data 8.71E-06 - 4.43E-06 - 1.48E-06 - 1.14E-06 - 1.31E-06 - 1.39E-06 - no data no data 1.57E-05 - 7.98E-06 - 2.67E-06 - 2.05E-06 - 2.35E-06 - 2.50E-06 - no data no data 1.74E-05 5 8.86E-06 5 2.97E-06 5 2.28E-06 5 2.61E-06 5 2.78E-06 5 no data no data**Hg Control Category**  **Total # of**

**Units in Sub Category**  Hg

(lb/MMBtu) Hg # of

Data Points **PM Filterable**

**Control Category Total # of** 

**Units in Sub Category**  PM

Filterable (lb/MMBtu) PM # of

Data Points 1 2 2.00E-06 2 1 257 2.95E-02 141 2 44 1.96E-06 13 2 265 4.52E-02 121 3 211 5.08E-06 76 3 19 1.38E-01 7 4 16 2.40E-06 7 4 7 9.09E-02 4 5 19 1.01E-05 4 5 68 2.39E-01 17 6 324 4.38E-06 116 1 - No % Reduction 1 - 1.40E-02 - 2 - 1.33E-06 - 2 2 1.70E-02 2 3 - 1.33E-06 - 3 3 9.49E-02 2 4 14 4.80E-06 3 4 14 1.40E-01 14 5 3 5.40E-07 2 5 1 8.40E-01 - 6 3 5.34E-06 - 1.40E+00 1 - No % Reduction 1 12 5.24E-03 3 2 6 2.72E-07 - 2 174 6.17E-02 60 3 6 5.39E-06 2 3 51 1.17E-01 15 4 33 1.68E-06 7 4 31 1.52E-01 11 5 52 1.53E-06 8 5 93 2.85E-01 31 6 264 1.09E-06 37 1 - No % Reduction 1 11 1.50E-03 - 2 4 4.33E-07 - 2 38 4.21E-02 5 3 7 4.33E-07 - 3 3 3.47E-02 1 4 3 1.56E-06 - 4 2 1.50E-02 - 5 4 6.01E-06 1 5 70 3.60E-01 3 6 106 1.73E-06 3 1.50E-01 1 - No % Reduction 1 3 8.76E-04 - 2 - 8.99E-07 - 2 7 7.87E-02 3 3 3 8.99E-07 - 3 3 3.00E-02 1 4 3 3.24E-06 - 4 1 5.26E-03 - 5 3 3.60E-06 - 5 3 2.41E-02 1 6 353 3.60E-06 79 6 345 8.76E-02 28 1 - No % Reduction 1 10 2.40E-04 - 2 - 1.73E-06 - 2 2 6.75E-03 2 3 10 1.73E-06 - 3 - 1.44E-03 1 4 - 6.24E-06 - 4 - 1.44E-03 - 5 - 6.94E-06 - 5 9 4.81E-03 - 6 573 6.94E-06 139 6 562 2.40E-02 21 1 - No % Reduction 1 - 1.44E-04 - 2 - 1.43E-06 - 2 - 2.88E-04 - 3 - 1.43E-06 - 3 - 2.88E-04 - 4 - 5.14E-06 - 4 - 7.20E-03 - 5 - 5.71E-06 - 5 - 3.60E-03 - 6 129 5.71E-06 2 6 129 1.44E-02 7 1 - No % Reduction 1 8 5.73E-05 - 2 2 1.12E-07 - 2 10 1.15E-04 - 3 8 1.12E-07 - 3 1 1.15E-04 - 4 11 4.02E-07 - 4 11 2.86E-03 - 5 1 4.46E-07 - 5 19 7.80E-02 1 6 11162 4.46E-07 15 6 11135 5.73E-03 103 1 - No % Reduction 1 2 6.60E-05 - 2 - 3.36E-07 - 2 - 1.32E-04 - 3 2 3.36E-07 - 3 - 1.32E-04 - 4 - 1.21E-06 - 4 - 3.30E-03 - 5 - 1.35E-06 - 5 - 1.65E-03 - 6 698 1.35E-06 6 6 698 6.60E-03 9**Inorganic Control Category**  **Total # of**

**Units in Sub Category**  HCl

(lb/MMBtu) HCl # of

Data Points HF

(lb/MMBtu) HF # of

Data Points SO2 (ppm

@ 3% O2) SO2 # of

Data Points 1 20 4.19E-02 14 1.64E-04 4 72.6 9 2 16 5.78E-03 2 4.97E-05 2 110.7 9 3 41 4.00E-02 17 5.36E-04 6 204.3 22 4 19 4.53E-03 5 3.37E-03 1 100.9 1 5 520 1.16E-01 228 3.27E-03 28 852.9 73 1 14 2.10E-03 3 6.21E-05 - 0.4 - 2 - 7.67E-04 - 6.21E-05 - 2.6 - 3 - 4.60E-03 - 1.09E-04 - 8.0 - 4 3 1.27E-03 2 2.96E-04 - 30.9 - 5 3 1.53E-02 2 1.09E-04 - 51.1 - 1 35 1.92E-03 4 6.21E-05 - 4.14E-01 1 2 5 3.80E-04 - 6.21E-05 - 2.56E+00 - 3 7 1.49E-02 3 1.09E-04 - 8.0409989 2 4 52 4.79E-03 7 2.96E-04 3 30.893224 7 5 262 7.61E-03 35 1.09E-04 18 51.1 23 1 5 1.33E-06 - 4.59E-05 - 0.4 - 2 - 1.33E-06 - 4.59E-05 - 2.6 - 3 7 7.96E-06 - 8.05E-05 - 8.0 - 4 4 2.32E-03 1 8.05E-05 1 30.9 - 5 108 2.65E-05 1 8.05E-05 - 51.1 - 1 3 2.72E-04 - 1.76E-04 - 16.0 - 2 - 2.72E-04 - 1.76E-04 - 149.6 1 3 * 1.63E-03 - 3.08E-04 - 96.0 - 4 3 5.44E-03 - 3.08E-04 - 319.9 - 5 347 5.44E-03 68 3.08E-04 9 319.9 15 1 - 8.00E-04 - 1.72E-04 - 7.3 1 2 1 7.90E-03 1 6.26E-04 1 7.3 - 3 - 4.80E-03 - 3.02E-04 - 43.9 - 4 - 1.60E-02 - 3.02E-04 - 146.3 - 5 582 1.60E-02 138 3.02E-04 4 146.3 6 1 - 7.76E-05 - 6.27E-05 - 6.6 - 2 1 7.76E-05 - 6.27E-05 - 6.6 - 3 - 4.66E-04 - 1.10E-04 - 39.5 - 4 - 1.55E-03 - 1.10E-04 - 131.8 - 5 128 1.55E-03 2 1.10E-04 1 131.8 1 1 11 5.28E-05 1 3.41E-03 - 0.3 - 2 5 5.28E-05 - 3.41E-03 - 0.3 - 3 - 3.17E-04 - 5.98E-03 - 1.9 - 4 1 1.06E-03 - 5.98E-03 - 0.9 1 5 11167 1.06E-03 12 5.98E-03 10 6.2 50 1 - 4.95E-05 - 6.76E-04 - 0.3 - 2 - 4.95E-05 - 6.76E-04 - 0.3 - 3 - 2.97E-04 - 1.19E-03 - 1.7 - 4 - 9.90E-04 - 1.19E-03 - 5.7 - 5 700 9.90E-04 7 1.19E-03 6 5.7 5Notes:

**Metals/PM Control Groups:**It was assumed that all coal and biomass units had at least a cyclone or multiclone installed for metals and PM control. Control groups 5 and 6 for metal and PM emissions from solid-fuel boilers were merged together into a single control group (5). **Green cells:**Whenever there is not an uncontrolled average but there is an average for another control group, the percent reductions were used to back-calculate an uncontrolled average. Additional data gaps were filled by applying percent reductions to the calculated uncontrolled average (see% Reductionstab). Uncontrolled baseline averages that were back-calculated and the averages based on those values appear as green cells. **Orange cells:**Where there is no reported data for bagasse, the wet biomass baseline average from the same control group was used to fill the data gaps. **Yellow cells:**Whenever there is an average based on reported data for the uncontrolled group (i.e., control group 6 for Mercury), any data gaps for that pollutant were filled using percent reductions applied to the uncontrolled average (see% Reductionstab). Baseline averages that were calculated using percent reductions based on a reported uncontrolled average appear as yellow cells. 

### Appendix D-2: Major Source Baseline Emission Factors for Fuel-Based HAP and SO2 for Existing Units

### Appendix D-3: Ratios of PM2.5 to Total Filterable PM Based on Fuel and Control
**Fuel Category Control**  **Fraction of Filterable PM**  **that is PM 2.5 Reason**  **Source Note:**  Gas 1 ALL 1 Particulate matter from natural gas combustion has been estimated to be less than 1 micrometer in size and has filterable and condensable fractions. http://www.epa.gov/ttn/chief/ap42/ch01/final/c01s04.pdf Process Gas ALL 1 Particulate matter from natural gas combustion has been estimated to be less than 1 micrometer in size and has filterable and condensable fractions. http://www.epa.gov/ttn/chief/ap42/ch01/final/c01s04.pdf Heavy Liquid Uncontrolled 0.56 Table 1.3-5 distribution of particle size in industrial boilers http://www.epa.gov/ttn/chief/ap42/ch01/final/c01s03.pdf Heavy Liquid Multiclone 0.22 Table 1.3-5 distribution of particle size in industrial boilers http://www.epa.gov/ttn/chief/ap42/ch01/final/c01s03.pdf Heavy Liquid Electrostatic Precipitator 0.41 Table 1.3-4 distribution of particle size in utility boilers http://www.epa.gov/ttn/chief/ap42/ch01/final/c01s03.pdf Heavy Liquid Scrubber 0.97 Table 1.3-4 distribution of particle size in utility boilers http://www.epa.gov/ttn/chief/ap42/ch01/final/c01s03.pdf Heavy Liquid Wet Electrostatic

Precipitator 0.41 Assumed to be the same fraction as a traditional ESP. http://www.epa.gov/ttn/chief/ap42/ch01/final/c01s03.pdf Light Liquid ALL 0.12 Table 1.3-6 distribution of particle size in industrial boilers for distillate oils http://www.epa.gov/ttn/chief/ap42/ch01/final/c01s03.pdf Biomass Uncontrolled 0.76 Table 1.6-5 particle size distribution for wood/bark-fired boilers http://www.epa.gov/ttn/chief/ap42/ch01/final/c01s06.pdf Applied to wet biomass, dry biomass, and bagasse fuel categories.

Biomass Multiclone 0.16 Table 1.6-5 particle size distribution for wood/bark-fired boilers http://www.epa.gov/ttn/chief/ap42/ch01/final/c01s06.pdf Without flyash re-injection; applied to wet biomass, dry biomass, and bagasse fuel categories. Biomass Electrostatic Precipitator/

Electrified Filter Bed 0.65 Table 1.6-5 particle size distribution for wood/bark-fired boilers http://www.epa.gov/ttn/chief/ap42/ch01/final/c01s06.pdf Applied to wet biomass, dry biomass, and bagasse fuel categories. Biomass Scrubber 0.98 Table 1.6-5 particle size distribution for wood/bark-fired boilers http://www.epa.gov/ttn/chief/ap42/ch01/final/c01s06.pdf Applied to wet biomass, dry biomass, and bagasse fuel categories. Biomass Wet Electrostatic

Precipitator 0.65 Assumed to be the same fraction as a traditional ESP. http://www.epa.gov/ttn/chief/ap42/ch01/final/c01s06.pdf Applied to wet biomass, dry biomass, and bagasse fuel categories. Coal Uncontrolled 0.07 Table 1.1-9 particle size distribution for wood/bark-fired boilers http://www.epa.gov/ttn/chief/ap42/ch01/final/c01s01.pdf Used spreader stoker values from AP-42 for all combustor designs.
Coal Multiclone 0.27 Table 1.1-9 particle size distribution for wood/bark-fired boilers http://www.epa.gov/ttn/chief/ap42/ch01/final/c01s01.pdf Used spreader stoker values from AP-42 for allcombustor designs; value is for without flyash reinjection. Coal Electrostatic Precipitator 0.61 Table 1.1-9 particle size distribution for wood/bark-fired boilers http://www.epa.gov/ttn/chief/ap42/ch01/final/c01s01.pdf Used spreader stoker values from AP-42 for all combustor designs. Coal Baghouse 0.26 Table 1.1-9 particle size distribution for wood/bark-fired boilers http://www.epa.gov/ttn/chief/ap42/ch01/final/c01s01.pdf Used spreader stoker values from AP-42 for all combustor designs.

## Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC

(ppm@3%O2) CombUnit_O

p_Indicator THC_Op_Ind

icator CO_Op_Indi

cator TNMOC TO

THC Ratio Outlier WVDuPontWashingtonWorks P05 10/7/2009 5:00:21 AM 0.34381323 0.000251548 0.00073164yes
WVDuPontWashingtonWorks P05 10/6/2009 10:00:15 PM 0.344576659 0.000256677 0.0007449yes WVDuPontWashingtonWorks P05 10/7/2009 8:00:24 AM 0.360740978 0.000484122 0.00134202yes WVDuPontWashingtonWorks P05 10/8/2009 8:00:46 AM 0.329648796 0.000493776 0.00149788yes WVDuPontWashingtonWorks P05 9/27/2009 3:00:54 PM 0.147489247 0.000247915 0.0016809yes

WVDuPontWashingtonWorks P05 9/28/2009 2:00:04 AM 0.148978914 0.000254813 0.00171039yes WVDuPontWashingtonWorks P05 9/24/2009 6:00:51 PM 0.283334953 0.000488471 0.001724yes WVDuPontWashingtonWorks P05 9/24/2009 7:00:52 PM 0.277256972 0.000478063 0.00172426yes WVDuPontWashingtonWorks P05 10/6/2009 9:00:14 PM 0.337156378 0.000767346 0.00227593yes WVDuPontWashingtonWorks P05 9/24/2009 8:00:53 PM 0.298784616 0.000740574 0.00247862yes WVDuPontWashingtonWorks P05 9/26/2009 1:00:30 PM 0.43101433 0.001077453 0.00249981 yes WVDuPontWashingtonWorks P05 9/25/2009 3:00:11 PM 0.140338347 0.000471791 0.00336181 yes WVDuPontWashingtonWorks P05 9/28/2009 1:00:04 AM 0.145179443 0.000732098 0.00504271 yes
WVDuPontWashingtonWorks P05 9/30/2009 11:00:55 AM 0.225811534 0.001189867 0.00526929yes WVDuPontWashingtonWorks P05 9/24/2009 3:00:48 PM 0.216452416 0.001153772 0.00533037yes WVDuPontWashingtonWorks P05 9/28/2009 2:00:15 PM 0.197589816 0.001177285 0.00595823yes WVDuPontWashingtonWorks P05 9/24/2009 5:00:50 PM 0.289667246 0.001963694 0.00677914yes WVDuPontWashingtonWorks P05 10/6/2009 3:00:09 PM 0.258561117 0.001770252 0.00684655yes WVDuPontWashingtonWorks P05 10/12/2009 5:00:20 PM 0.194572199 0.001354111 0.00695943yes
WVDuPontWashingtonWorks P05 9/24/2009 10:00:44 AM 0.274374984 0.002325032 0.00847392yes WVDuPontWashingtonWorks P05 9/29/2009 1:00:36 PM 0.233769825 0.001989305 0.00850967yes
WVDuPontWashingtonWorks P05 10/7/2009 10:00:26 AM 0.505524356 0.004384948 0.00867406yes
WVDuPontWashingtonWorks P05 9/28/2009 12:00:13 PM 0.121327483 0.001199647 0.00988768yes WVDuPontWashingtonWorks P05 9/25/2009 5:00:12 PM 0.426068376 0.004774536 0.01120603yes WVDuPontWashingtonWorks P05 10/4/2009 4:00:27 PM 0.658496965 0.009609755 0.01459347yes WVDuPontWashingtonWorks P05 9/25/2009 6:00:13 PM 0.426969441 0.006349776 0.01487173yes WVDuPontWashingtonWorks P05 9/27/2009 6:00:56 PM 0.145791811 0.002205559 0.01512814yes



### Appendix D-4, p1 of 82

## Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC

(ppm@3%O2) CombUnit_O

p_Indicator THC_Op_Ind

icator CO_Op_Indi

cator TNMOC TO

THC Ratio Outlier

WVDuPontWashingtonWorks P05 9/26/2009 10:00:28 AM 0.434142408 0.007412962 0.01707495yes WVDuPontWashingtonWorks P05 10/7/2009 9:00:25 AM 0.478946682 0.008913989 0.01861165yes WVDuPontWashingtonWorks P05 9/25/2009 7:00:14 PM 0.429981631 0.009154937 0.02129146yes WVDuPontWashingtonWorks P05 9/27/2009 8:00:47 AM 0.369515136 0.008187488 0.02215738yes
WVDuPontWashingtonWorks P05 9/24/2009 12:00:46 PM 0.297926351 0.006953059 0.02333818yes WVDuPontWashingtonWorks P05 9/28/2009 3:00:05 AM 0.15448463 0.003963445 0.02565592yes
WVDuPontWashingtonWorks P05 10/5/2009 11:00:44 AM 0.373815964 0.009669351 0.02586661 yes WVDuPontWashingtonWorks P05 9/29/2009 4:00:38 PM 0.188741765 0.005696384 0.03018083yes TXDibollTemple-Inland PB-44 0900-1000 2.477278137 0.083700023 0.03378709yes WVDuPontWashingtonWorks P05 9/25/2009 3:00:00 AM 0.195685242 0.006794388 0.03472101 yes WVDuPontWashingtonWorks P05 9/27/2009 9:00:48 AM 0.155571377 0.00571872 0.03675946yes WVDuPontWashingtonWorks P05 9/25/2009 4:00:12 PM 0.940857368 0.035008684 0.03720934yes WABoeingRenton BOIL04 08/07/09 20:00 1.610931851 0.064103566 normal 0.03979285yes
WVDuPontWashingtonWorks P05 9/24/2009 11:00:45 AM 0.309345524 0.01297871 0.04195538yes WVDuPontWashingtonWorks P05 9/26/2009 2:00:21 AM 0.424479831 0.017837754 0.04202262yes WVDuPontWashingtonWorks P05 9/26/2009 7:00:25 AM 0.44944557 0.020243201 0.04504038yes WVDuPontWashingtonWorks P05 9/25/2009 8:00:15 PM 0.440596868 0.020142684 0.04571681 yes TXDibollTemple-Inland PB-44 1000-1100 5.371799357 0.261031121 0.04859287yes WVDuPontWashingtonWorks P05 9/24/2009 9:00:43 AM 0.330668777 0.017114282 0.05175657yes ARDomtarIndustries PB1 8/28/2009 9:00:00 AM 254.2082867 13.23415716 Normal 0.05206029yes WVDuPontWashingtonWorks P05 9/25/2009 2:00:10 PM 0.141854399 0.007735277 0.05452969yes TXDibollTemple-Inland PB-44 1600-1700 3.224265328 0.176433347 0.05472048yes
WVDuPontWashingtonWorks P05 10/5/2009 12:00:45 PM 0.381809679 0.021718138 0.0568821 yes TXDibollTemple-Inland PB-44 1700-1800 3.447991163 0.198474571 0.05756238yes
ARDomtarIndustries PB1 8/28/2009 10:00:00 AM 39.44418223 2.271092684 Normal 10:02 - 10:56 calibration 10:02 - 10:56

calibration 0.05757738yes VAPhilipMorrisPark500 B3 10/14/2009 11:00:00 PM 6.748646209 0.394765343 Normal 0.05849549yes VAPhilipMorrisPark500 B3 10/16/2009 4:00:00 AM 6.212565489 0.386603235 Normal 0.06222924yes VAPhilipMorrisPark500 B3 10/16/2009 8:00:00 AM 6.170910347 0.392359133 Normal 0.06358205yes
WVDuPontWashingtonWorks P05 9/25/2009 10:00:17 PM 0.441787404 0.028298376 0.06405428yes



### Appendix D-4, p2 of 82

## Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC

(ppm@3%O2) CombUnit_O

p_Indicator THC_Op_Ind

icator CO_Op_Indi

cator TNMOC TO

THC Ratio Outlier

WVDuPontWashingtonWorks P05 9/25/2009 11:00:18 PM 0.444844111 0.029161883 0.06555529yes WVDuPontWashingtonWorks P05 9/26/2009 6:00:24 AM 0.451126096 0.030864141 0.06841577yes WVDuPontWashingtonWorks P05 9/25/2009 9:00:16 PM 0.447122332 0.031565943 0.070598yes WVDuPontWashingtonWorks P05 9/29/2009 3:00:37 PM 0.210934293 0.015516887 0.07356266yes VAPhilipMorrisPark500 B3 10/14/2009 10:00:00 PM 6.883619134 0.526353791 Normal 0.07646469yes WABoeingRenton BOIL04 08/07/09 19:00 0.833881145 0.064181952 normal 0.07696775yes WVDuPontWashingtonWorks P05 9/25/2009 1:00:09 PM 0.142398434 0.011059161 0.0776635yes VAPhilipMorrisPark500 B3 10/16/2009 6.609112222 0.515470979 Normal 0.07799398yes WVDuPontWashingtonWorks P05 9/26/2009 9:00:27 AM 0.483747108 0.038228677 0.07902616yes VAPhilipMorrisPark500 B3 10/16/2009 1:00:00 AM 6.524791647 0.519280084 Normal 0.0795857yes VAPhilipMorrisPark500 B3 10/16/2009 2:00:00 AM 6.524791647 0.519280084 Normal 0.0795857yes
WVDuPontWashingtonWorks P05 9/26/2009 12:00:19 AM 0.443628477 0.035793467 0.08068343yes VAPhilipMorrisPark500 B3 10/16/2009 3:00:00 AM 6.391632634 0.519280084 Normal 0.08124373yes VAPhilipMorrisPark500 B3 10/16/2009 5:00:00 AM 6.25847362 0.519280084 Normal 0.08297232yes TXDibollTemple-Inland PB-44 2200-2300 46.24435158 3.865714628 0.08359323yes VAPhilipMorrisPark500 B3 10/16/2009 7:00:00 AM 6.125314607 0.519280084 Normal 0.08477607yes VAPhilipMorrisPark500 B3 10/16/2009 6:00:00 AM 6.080383245 0.515470979 Normal 0.08477607yes WVDuPontWashingtonWorks P05 9/26/2009 5:00:23 AM 0.449827262 0.039269257 0.08729853yes ARDomtarIndustries PB1 8/28/2009 8:00:00 AM 331.9240538 29.05523924 Normal 0.0875358yes
ARDomtarIndustries PB1 9/3/2009 10:00:00 AM 90.21831949 7.904916421 Normal 10:06 - 10:59 calibration 10:06 - 10:59

calibration 0.08761986yes TXDibollTemple-Inland PB-44 2300-2400 33.35778011 2.932160964 0.08790036yes TXDibollTemple-Inland PB-44 0800-0900 3.350885318 0.299883959 0.08949395yes WVDuPontWashingtonWorks P05 9/25/2009 6:00:03 AM 0.141247896 0.013058334 0.09244976yes WVDuPontWashingtonWorks P05 9/25/2009 4:00:01 AM 0.144064735 0.013326539 0.09250383yes TXDibollTemple-Inland PB-44 0500-0600 2.66124099 0.260072374 0.09772598yes TXDibollTemple-Inland PB-44 0300-0400 2.639055145 0.27550492 0.10439529 no
WVDuPontWashingtonWorks P05 10/7/2009 12:00:28 PM 0.377381417 0.039459148 0.10456039 no WABoeingRenton BOIL04 08/08/09 07:00 1.656109253 0.173377926 normal 0.10468991 no WVDuPontWashingtonWorks P05 9/29/2009 2:00:37 PM 0.22427682 0.02356681 0.10507912 no WVDuPontWashingtonWorks P05 9/24/2009 8:00:42 AM 0.281209332 0.031438094 0.11179605no WVDuPontWashingtonWorks P05 9/26/2009 8:00:26 AM 0.440445452 0.050541387 0.11475062 no TXDibollTemple-Inland PB-44 0600-0700 23.27220514 2.676590346 0.11501232 no


### Appendix D-4, p3 of 82

## Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC

(ppm@3%O2) CombUnit_O

p_Indicator THC_Op_Ind

icator CO_Op_Indi

cator TNMOC TO

THC Ratio Outlier TXDibollTemple-Inland PB-44 0800-0900 2.368370854 0.275867867 0.11648001 no WABoeingRenton BOIL04 10/12/09 19:00 8.690953947 1.0125normal 0.11650044 no WVDuPontWashingtonWorks P05 9/24/2009 5:00:39 AM 0.276888971 0.03228716 0.11660688 no ARDomtarIndustries PB1 9/3/2009 9:00:00 AM 76.71393513 9.328315957 Normal 0.12159872 no TXDibollTemple-Inland PB-44 0200-0300 2.946379435 0.360227822 0.12226118 no ARDomtarIndustries PB1 9/7/2009 9:00:00 AM 2.939672212 0.361406765 Normal 0.12294118 no TXDibollTemple-Inland PB-44 2300-2400 2.960537203 0.370703506 0.12521495no ARDomtarIndustries PB1 9/8/2009 9:00:00 PM 19.30257772 2.450525585 Normal 0.12695328 no TXDibollTemple-Inland PB-44 2200-2300 2.924538253 0.371646466 0.12707868 no TXDibollTemple-Inland PB-44 0600-0700 2.591934639 0.331702623 0.12797492 no WVDuPontWashingtonWorks P05 10/7/2009 3:00:30 PM 0.512101794 0.065783071 0.12845702 no TXDibollTemple-Inland PB-44 0100-0200 2.902714391 0.37444603 0.12899858 no
WVDuPontWashingtonWorks P05 9/26/2009 11:00:29 AM 0.430956828 0.056020065 0.12998997 no WABoeingRenton BOIL04 10/12/09 14:00 10.37738417 1.351083546 normal 0.130195no WABoeingRenton BOIL04 08/08/09 04:00 3.231519487 0.42078441 normal 0.13021256 no
WVDuPontWashingtonWorks P05 10/7/2009 11:00:27 AM 0.383781853 0.050034851 0.13037316 no WVDuPontWashingtonWorks P05 9/26/2009 1:00:20 AM 0.433991152 0.056909361 0.13113023 no ARDomtarIndustries PB1 9/9/2009 2:00:00 AM 28.65486495 3.76021568 Normal 0.13122434 no ARDomtarIndustries PB1 9/9/2009 1:00:00 AM 25.39922618 3.346052062 Normal 0.13173835no
ARDomtarIndustries PB1 9/8/2009 11:00:00 PM 19.49680143 2.572452672 Normal 0.13194229 no WABoeingRenton BOIL04 10/17/09 00:00 13.90136481 1.839306529normal 0.13231122 no WVDuPontWashingtonWorks P05 9/25/2009 7:00:04 AM 0.141968553 0.019031191 0.13405216 no WVDuPontWashingtonWorks P05 9/25/2009 5:00:02 AM 0.14357423 0.01931251 0.13451237 no ARDomtarIndustries PB1 9/9/2009 25.43962148 3.451900681 Normal 0.13568994 no WABoeingRenton BOIL04 08/08/09 12:00 2.70090301 0.368428094 normal 0.13640923 no ARDomtarIndustries PB1 9/9/2009 6:00:00 AM 16.02517083 2.233734216 Normal 0.1393891 no TXDibollTemple-Inland PB-44 10/08/2009 0000-0100 2.779101791 0.387562719 0.13945611 no WABoeingRenton BOIL04 10/15/09 14:00 11.49963383 1.612288539normal 0.14020347 no
ARDomtarIndustries PB1 9/8/2009 12:00:00 PM 14.16174023 1.994243339 Normal 0.14081909 no
ARDomtarIndustries PB1 9/9/2009 11:00:00 AM 20.67752821 2.920318487 Normal 0.14123151 no WABoeingRenton BOIL04 10/08/09 04:00 5.965155485 0.846096964 normal 0.14183988 no WABoeingRenton BOIL04 08/08/09 00:00 2.628765629 0.375312577 normal 0.14277141 no



### Appendix D-4, p4 of 82

## Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC

(ppm@3%O2) CombUnit_O

p_Indicator THC_Op_Ind

icator CO_Op_Indi

cator TNMOC TO

THC Ratio Outlier ARDomtarIndustries PB1 9/7/2009 6:00:00 AM 3.517678961 0.504151293 Normal 0.1433193 no ARDomtarIndustries PB1 9/9/2009 3:00:00 AM 17.78731303 2.59398877 Normal 0.14583365no TXDibollTemple-Inland PB-44 0700-0800 2.77044903 0.411570858 0.14855746 no ARDomtarIndustries PB1 9/9/2009 5:00:00 AM 17.49576062 2.611641634 Normal 0.14927283 no WABoeingRenton BOIL04 10/14/09 16:00 18.64376549 2.789746106 normal 0.14963426 no WABoeingRenton BOIL04 08/08/09 09:00 5.508663029 0.824566539normal 0.14968542 no ARDomtarIndustries PB1 9/9/2009 9:00:00 AM 18.72294168 2.802818977 Normal 0.14969971 no WVDuPontWashingtonWorks P05 9/26/2009 3:00:21 AM 0.440257279 0.06591558 0.14972059 no ARDomtarIndustries PB1 9/9/2009 8:00:00 AM 19.36503458 2.901451469 Normal 0.1498294 no ARDomtarIndustries PB1 9/9/2009 2:00:00 PM 31.95216676 4.788609428 Normal 0.14986807 no ARDomtarIndustries PB1 9/9/2009 7:00:00 AM 18.51192045 2.785223284 Normal 0.15045566 no WABoeingRenton BOIL04 10/08/09 02:00 5.065758468 0.762282769normal 0.15047752 no ARDomtarIndustries PB1 9/9/2009 4:00:00 AM 18.75841491 2.823338189 Normal 0.15051049 no VAPhilipMorrisPark500 B3 10/16/2009 10:00:00 AM 7.79138303 1.17869157 Normal 0.15128143 no
ARDomtarIndustries PB1 9/8/2009 10:00:00 PM 20.36586172 3.090771906 Normal 0.15176239 no WABoeingRenton BOIL04 10/12/09 22:00 11.73720468 1.791617701 normal 0.15264433 no WABoeingRenton BOIL04 08/07/09 22:00 12.06991516 1.860818886 normal 0.15417001 no WABoeingRenton BOIL04 08/08/09 05:00 6.547536053 1.013573277 normal 0.15480224 no WABoeingRenton BOIL04 10/12/09 18:00 9.701721661 1.501848289normal 0.15480224 no TXDibollTemple-Inland PB-44 0900-1000 5.958479655 0.923467727 0.15498378 no WABoeingRenton BOIL04 10/12/09 15:00 7.658678924 1.192957506 normal 0.15576544 no TXDibollTemple-Inland PB-44 0400-0500 2.663756142 0.415010306 0.15579891 no WABoeingRenton BOIL04 08/08/09 14:00 9.286632375 1.45294001 normal 0.15645499 no WABoeingRenton BOIL04 10/13/09 04:00 0.675316824 0.106190823 normal 0.15724593 no WABoeingRenton BOIL04 10/15/09 18:00 5.517271723 0.869646539normal 0.15762257 no WABoeingRenton BOIL04 10/12/09 17:00 10.03559211 1.588026316 normal 0.15823942 no WABoeingRenton BOIL04 08/20/09 00:00 13.62513676 2.156688336 normal 0.15828746 no ARDomtarIndustries PB1 9/9/2009 1:00:00 PM 29.49321071 4.694129835 Normal 0.15915968 no ARDomtarIndustries PB1 9/9/2009 3:00:00 PM 23.67397822 3.773039952 Normal 0.15937499 no WABoeingRenton BOIL04 08/07/09 23:00 6.430668479 1.026887434 normal 0.15968595no ARDomtarIndustries PB1 9/7/2009 3:00:00 AM 7.324120416 1.171294587 Normal 0.1599229no TXDibollTemple-Inland PB-44 1900-2000 3.273631674 0.526619394 0.16086703 no TXDibollTemple-Inland PB-44 2100-2200 3.183911271 0.512186866 0.16086719 no 

### Appendix D-4, p5 of 82

## Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC

(ppm@3%O2) CombUnit_O

p_Indicator THC_Op_Ind

icator CO_Op_Indi

cator TNMOC TO

THC Ratio Outlier TXDibollTemple-Inland PB-44 0400-0500 2.953970891 0.475292396 0.16089949 no WABoeingRenton BOIL04 08/07/09 21:00 11.4490323 1.847790741 normal 0.16139274 no WVDuPontWashingtonWorks P05 9/26/2009 4:00:22 AM 0.457809994 0.073998656 0.16163618 no
ARDomtarIndustries PB1 9/6/2009 12:00:00 PM 7.359644472 1.192193006 Normal 0.16199057 no ARDomtarIndustries PB1 9/8/2009 7:00:00 PM 23.25132805 3.782612297 Normal 0.16268371 no WABoeingRenton BOIL04 08/08/09 06:00 10.14493389 1.653829235normal 0.16302021 no WABoeingRenton BOIL04 10/08/09 00:00 3.215655376 0.526082474 normal 0.16360039 no WABoeingRenton BOIL04 10/08/09 08:00 3.995092604 0.654517356 normal 0.16383033 no ARDomtarIndustries PB1 9/8/2009 8:00:00 PM 26.78654541 4.401583427 Normal 0.16432068 no WABoeingRenton BOIL04 10/08/09 15:00 6.841390047 1.12593773 normal 0.16457733 no WABoeingRenton BOIL04 10/14/09 13:00 8.997079776 1.493925348normal 0.16604558 no
ARDomtarIndustries PB1 9/9/2009 10:00:00 AM 18.75222054 3.126834876 Normal 10:05 - 10:59 calibration 10:05 - 10:59

calibration 0.16674478 no WABoeingRenton BOIL04 10/16/09 19:00 11.21625 1.872726378normal 0.16696546 no WABoeingRenton BOIL04 10/08/09 13:00 4.371969809 0.730073638normal 0.16698963 no WABoeingRenton BOIL04 10/12/09 21:00 10.68500426 1.78943626 normal 0.16747174 no WABoeingRenton BOIL04 09/27/09 09:00 10.8397928 1.823162486 normal 0.16819164 no WABoeingRenton BOIL04 10/15/09 15:00 13.08471177 2.200889106 normal 0.1682031 no WABoeingRenton BOIL04 10/08/09 06:00 6.038358008 1.016835923 normal 0.1683961 no WABoeingRenton BOIL04 10/08/09 01:00 5.32473388 0.899097027 normal 0.16885295no
ARDomtarIndustries PB1 9/8/2009 10:00:00 AM 17.40414927 2.942670098 Normal 10:05 - 10:59 calibration 10:05 - 10:59

calibration 0.16907865no ARDomtarIndustries PB1 9/8/2009 1:00:00 PM 14.75377333 2.495265265 Normal 0.16912726 no ARDomtarIndustries PB1 9/6/2009 3:00:00 PM 5.890082042 0.996819233 Normal 0.1692369no ARDomtarIndustries PB1 9/8/2009 7:00:00 AM 10.26913731 1.738081279 Normal 0.1692529no WABoeingRenton BOIL04 10/16/09 03:00 15.20903214 2.576399853 normal 0.16939933 no WABoeingRenton BOIL04 10/13/09 06:00 9.303953346 1.581221299normal 0.16995155no WABoeingRenton BOIL04 10/17/09 06:00 12.67995822 2.160663554 normal 0.1703999no WABoeingRenton BOIL04 10/16/09 16:00 18.64419367 3.177967599normal 0.17045348 no WABoeingRenton BOIL04 10/14/09 14:00 9.095887748 1.55106383 normal 0.17052363 no WABoeingRenton BOIL04 10/13/09 09:00 8.43821446 1.442330239normal 0.17092837 no WABoeingRenton BOIL04 10/14/09 19:00 13.05888012 2.233394179normal 0.17102494 no



### Appendix D-4, p6 of 82

## Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC

(ppm@3%O2) CombUnit_O

p_Indicator THC_Op_Ind

icator CO_Op_Indi

cator TNMOC TO

THC Ratio Outlier ARDomtarIndustries PB1 9/8/2009 5:00:00 PM 15.27421136 2.616904275 Normal 0.17132827 no ARDomtarIndustries PB1 9/6/2009 3:00:00 AM 3.678784015 0.631867121 Normal 0.17175978 no TXDibollTemple-Inland PB-44 1800-1900 3.359511075 0.577246898 0.17182467 no ARDomtarIndustries PB1 9/7/2009 2.85412589 0.491465409 Normal 0.17219472 no ARDomtarIndustries PB1 9/6/2009 4:00:00 AM 7.86070328 1.370279042 Normal 0.17432016 no ARDomtarIndustries PB1 9/8/2009 9:00:00 AM 18.46110165 3.227758747 Normal 0.17484107 no WABoeingRenton BOIL04 10/15/09 17:00 5.850996555 1.033228346 normal 0.17659015no ARDomtarIndustries PB1 9/7/2009 4:00:00 AM 6.466528593 1.151665935 Normal 0.17809647 no WABoeingRenton BOIL04 10/12/09 20:00 10.74839475 1.914921561 normal 0.17815884 no WABoeingRenton BOIL04 10/14/09 17:00 16.7124612 2.995742794 normal 0.17925204 no WABoeingRenton BOIL04 10/15/09 01:00 7.557488012 1.355278495normal 0.17932923 no ARDomtarIndustries PB1 9/6/2009 9:00:00 PM 2.082206152 0.3734582 Normal 0.17935698 no WABoeingRenton BOIL04 10/08/09 09:00 3.873158474 0.695304475normal 0.17951873 no
ARDomtarIndustries PB1 9/6/2009 11:00:00 AM 6.859092197 1.231694794 Normal 0.17957111 no WABoeingRenton BOIL04 10/15/09 03:00 8.572015265 1.540027084 normal 0.17965753 no WABoeingRenton BOIL04 10/08/09 03:00 4.026768158 0.727395451 normal 0.18064001 no WABoeingRenton BOIL04 08/08/09 16:00 4.77641743 0.866353058normal 0.18138135no WABoeingRenton BOIL04 08/19/09 00:00 10.09986237 1.838176456 normal 0.18200015no WABoeingRenton BOIL04 10/16/09 00:00 13.57490308 2.47413873 normal 0.1822583 no ARDomtarIndustries PB1 9/6/2009 2:00:00 PM 6.26325752 1.143130012 Normal 0.18251365no WABoeingRenton BOIL04 10/16/09 15:00 16.01966802 2.925680561 normal 0.18263054 no WABoeingRenton BOIL04 10/12/09 23:00 11.14651591 2.036898696 normal 0.1827386 no
ARDomtarIndustries PB1 9/6/2009 11:00:00 PM 2.97378059 0.547814495 Normal 0.18421483 no ARDomtarIndustries PB1 9/6/2009 6:00:00 AM 7.088848141 1.306713588 Normal 0.1843337 no WABoeingRenton BOIL04 08/13/09 22:00 8.832212552 1.629928904 normal 0.18454367 no WABoeingRenton BOIL04 10/16/09 02:00 16.28567192 3.021706335normal 0.18554385no WABoeingRenton BOIL04 10/07/09 23:00 12.33057473 2.288252487 normal 0.18557549 no ARDomtarIndustries PB1 9/6/2009 1:00:00 PM 6.857373442 1.274557207 Normal 0.18586668 no WABoeingRenton BOIL04 10/16/09 01:00 11.90864483 2.215492512 normal 0.18604069 no WABoeingRenton BOIL04 10/15/09 07:00 14.35591246 2.671557864 normal 0.18609461 no WABoeingRenton BOIL04 10/13/09 00:00 3.913252481 0.728732084 normal 0.18622159 no



### Appendix D-4, p7 of 82

## Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC

(ppm@3%O2) CombUnit_O

p_Indicator THC_Op_Ind

icator CO_Op_Indi

cator TNMOC TO

THC Ratio Outlier WABoeingRenton BOIL04 10/14/09 15:00 14.74457237 2.750808761 normal 0.18656416 no ARDomtarIndustries PB1 9/8/2009 8:00:00 AM 14.38683858 2.684241198 Normal 0.18657617 no WABoeingRenton BOIL04 08/08/09 15:00 10.00954388 1.87581061 normal 0.18740221 no WABoeingRenton BOIL04 10/15/09 08:00 13.67652604 2.564983298normal 0.18754641 no ARDomtarIndustries PB1 9/7/2009 1:00:00 AM 2.948534521 0.553014101 Normal 0.18755558 no ARDomtarIndustries PB1 9/8/2009 2:00:00 PM 15.65538768 2.94050181 Normal 0.18782683 no WABoeingRenton BOIL04 09/27/09 08:00 10.36140676 1.950359869normal 0.18823311 no WABoeingRenton BOIL04 10/15/09 02:00 8.164293619 1.53813353 normal 0.18839763 no
ARDomtarIndustries PB1 9/7/2009 10:00:00 AM 3.505753517 0.660968368 Normal 10:05 - 10:59 calibration 10:05 - 10:59

calibration 0.18853817 no WVDuPontWashingtonWorks P05 9/25/2009 8:00:04 AM 0.177411391 0.033553207 0.18912656 no WABoeingRenton BOIL04 10/13/09 02:00 8.097162358 1.532326649normal 0.18924243 no ARDomtarIndustries PB1 9/7/2009 8:00:00 AM 3.058344633 0.57982504 Normal 0.18958787 no WABoeingRenton BOIL04 10/12/09 16:00 12.11267544 2.302105263 normal 0.19005754 no WABoeingRenton BOIL04 10/06/09 02:00 4.995368898 0.952614707 normal 0.19069957 no ARDomtarIndustries PB1 9/10/2009 5:00:00 AM 4.939701268 0.942025774 Normal 0.19070501 no WABoeingRenton BOIL04 08/08/09 03:00 7.81658841 1.491689114 normal 0.19083634 no WABoeingRenton BOIL04 10/07/09 22:00 10.4747481 1.999420005normal 0.19088001 no WABoeingRenton BOIL04 10/07/09 16:00 10.20708997 1.951625398normal 0.19120292 no ARDomtarIndustries PB1 9/10/2009 4.3458559 0.832600426 Normal 0.19158491 no WABoeingRenton BOIL04 08/11/09 02:00 7.661620728 1.468180816 normal 0.19162797 no WABoeingRenton BOIL04 10/13/09 05:00 4.533909875 0.871293575normal 0.19217267 no ARDomtarIndustries PB1 9/8/2009 6:00:00 PM 16.5934599 3.1893394 Normal 0.1922046 no WABoeingRenton BOIL04 08/11/09 00:00 7.818888071 1.503092784 normal 0.19223869 no WABoeingRenton BOIL04 10/15/09 12:00 12.17035237 2.347077151 normal 0.19285203 no WABoeingRenton BOIL04 09/26/09 21:00 6.291876744 1.220453718normal 0.19397292 no WVDuPontWashingtonWorks P05 10/5/2009 5:00:49 PM 0.342543309 0.066576918 0.19436058 no WABoeingRenton BOIL04 08/21/09 16:00 2.097527067 0.40898622 normal 0.19498495no WABoeingRenton BOIL04 10/15/09 09:00 15.05091268 2.945490873 normal 0.19570181 no WVDuPontWashingtonWorks P05 9/24/2009 1:00:36 AM 0.281182928 0.055062761 0.19582541 no WABoeingRenton BOIL04 10/06/09 06:00 5.385113442 1.056418639normal 0.19617389 no WABoeingRenton BOIL04 10/13/09 12:00 8.811795339 1.730910415normal 0.19643107 no



### Appendix D-4, p8 of 82

## Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC

(ppm@3%O2) CombUnit_O

p_Indicator THC_Op_Ind

icator CO_Op_Indi

cator TNMOC TO

THC Ratio Outlier ARDomtarIndustries PB1 9/8/2009 4:00:00 PM 13.39679273 2.632908039 Normal 0.19653271 no WABoeingRenton BOIL04 10/14/09 21:00 12.27779042 2.413465298normal 0.19657163 no WABoeingRenton BOIL04 10/08/09 11:00 7.23078744 1.427062431 normal 0.1973592 no WABoeingRenton BOIL04 10/15/09 19:00 5.273692364 1.043349318normal 0.19784038 no WABoeingRenton BOIL04 10/06/09 05:00 4.366903888 0.866456346 normal 0.19841434 no WABoeingRenton BOIL04 10/14/09 20:00 9.529929525 1.892804154 normal 0.19861681 no WABoeingRenton BOIL04 10/14/09 22:00 17.26344036 3.435248209normal 0.19898978 no ARDomtarIndustries PB1 9/11/2009 2:00:00 AM 4.51958843 0.901536316 Normal 0.1994731 no WABoeingRenton BOIL04 08/11/09 12:00 11.8534121 2.366929481 normal 0.19968339 no ARDomtarIndustries PB1 9/9/2009 4:00:00 PM 9.893640823 1.986366292 Normal 0.20077202 no WABoeingRenton BOIL04 10/13/09 07:00 6.304523054 1.269836545normal 0.20141675no WABoeingRenton BOIL04 10/16/09 18:00 15.20492381 3.063627427 normal 0.20148917 no WABoeingRenton BOIL04 10/07/09 14:00 7.287216608 1.46989407 normal 0.20170857 no WABoeingRenton BOIL04 10/17/09 11:00 12.74324192 2.570421156 normal 0.20170857 no ARDomtarIndustries PB1 9/6/2009 8:00:00 PM 2.813511427 0.568217625 Normal 0.2019603 no WABoeingRenton BOIL04 10/09/09 05:00 5.372987827 1.086374032 normal 0.20219179 no WABoeingRenton BOIL04 08/17/09 10:00 12.42889189 2.530679088normal 0.20361261 no WABoeingRenton BOIL04 09/28/09 09:00 10.43986745 2.125802651 normal 0.20362353 no WABoeingRenton BOIL04 10/17/09 10:00 18.82923849 3.834211557 normal 0.20363073 no WABoeingRenton BOIL04 10/07/09 18:00 4.961722782 1.010459572 normal 0.20365095no ARDomtarIndustries PB1 9/11/2009 5:00:00 AM 4.888780051 0.995729884 Normal 0.20367656 no WABoeingRenton BOIL04 08/11/09 09:00 10.77464369 2.199607506 normal 0.20414666 no WABoeingRenton BOIL04 10/13/09 08:00 6.100065789 1.246973684 normal 0.20441971 no WVDuPontWashingtonWorks P05 10/7/2009 1:00:29 PM 0.379553901 0.077694198 0.20469872 no WABoeingRenton BOIL04 10/16/09 04:00 13.35026061 2.740105225normal 0.20524732 no WABoeingRenton BOIL04 09/28/09 03:00 6.67666504 1.376545499normal 0.20617262 no ARDomtarIndustries PB1 9/10/2009 7:00:00 PM 4.216628336 0.871121099 Normal 0.20659186 no ARDomtarIndustries PB1 9/6/2009 5:00:00 AM 5.704340437 1.178627793 Normal 0.20661947 no ARDomtarIndustries PB1 9/8/2009 5:00:00 AM 1.63924014 0.339502922 Normal 0.20710994 no WABoeingRenton BOIL04 10/15/09 04:00 17.62987805 3.65308204 normal 0.20720972 no WABoeingRenton BOIL04 08/11/09 11:00 12.066112 2.503111875normal 0.20744975no



### Appendix D-4, p9 of 82

## Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC

(ppm@3%O2) CombUnit_O

p_Indicator THC_Op_Ind

icator CO_Op_Indi

cator TNMOC TO

THC Ratio Outlier ARDomtarIndustries PB1 9/8/2009 3:00:00 PM 14.59780014 3.029228332 Normal 0.20751266 no
ARDomtarIndustries PB1 9/9/2009 12:00:00 PM 18.46365976 3.838645868 Normal 0.20790276 no WABoeingRenton BOIL04 10/08/09 10:00 6.273285907 1.309034711 normal 0.20866811 no WABoeingRenton BOIL04 10/16/09 14:00 19.78073482 4.127834849normal 0.20867955no WABoeingRenton BOIL04 10/07/09 20:00 12.91459659 2.696485325normal 0.20879362 no WABoeingRenton BOIL04 08/14/09 13:00 9.719005281 2.030421221 normal 0.20891245no WABoeingRenton BOIL04 10/16/09 08:00 14.28368505 2.987850695normal 0.20917926 no WABoeingRenton BOIL04 10/16/09 05:00 3.263705602 0.683354083 normal 0.20937982 no WABoeingRenton BOIL04 10/15/09 11:00 17.89496662 3.753160237 normal 0.20973273 no WVDuPontWashingtonWorks P05 9/24/2009 4:00:38 AM 0.281679979 0.059280002 0.2104516 no WABoeingRenton BOIL04 10/13/09 10:00 5.928765086 1.247733756 normal 0.21045424 no WABoeingRenton BOIL04 08/21/09 23:00 12.74435698 2.683237251 normal 0.21054316 no WABoeingRenton BOIL04 10/13/09 23:00 13.68278009 2.884545232 normal 0.21081573 no WABoeingRenton BOIL04 10/08/09 05:00 6.924359794 1.461941509normal 0.21113021 no
ARDomtarIndustries PB1 9/7/2009 11:00:00 PM 1.871044496 0.395159373 Normal 0.21119721 no WABoeingRenton BOIL04 10/16/09 21:00 17.30145747 3.656616818normal 0.21134733 no WABoeingRenton BOIL04 10/14/09 23:00 15.97810077 3.381234873 normal 0.21161682 no WABoeingRenton BOIL04 10/16/09 06:00 7.066045488 1.49757887 normal 0.21194017 no WABoeingRenton BOIL04 10/06/09 09:00 6.808392988 1.447634224 normal 0.21262495no ARDomtarIndustries PB1 9/6/2009 5:00:00 PM 4.262513922 0.910018332 Normal 0.21349334 no WABoeingRenton BOIL04 10/06/09 13:00 7.757289068 1.658033749normal 0.21373881 no WABoeingRenton BOIL04 10/07/09 21:00 11.37080463 2.432391732 normal 0.21391553 no WABoeingRenton BOIL04 10/15/09 00:00 11.84528904 2.533933194 normal 0.21391907 no VAPhilipMorrisPark500 B3 10/1/2009 11:00:00 AM 5.407344369 1.15721429 Normal 0.21400788 no WABoeingRenton BOIL04 10/14/09 18:00 13.82757206 2.963414634 normal 0.214312 no WABoeingRenton BOIL04 08/11/09 07:00 10.84938258 2.325512679normal 0.21434516 no WABoeingRenton BOIL04 10/15/09 10:00 15.11265534 3.244018355normal 0.21465575no WABoeingRenton BOIL04 10/14/09 00:00 11.0970011 2.383971649normal 0.21483026 no WABoeingRenton BOIL04 10/13/09 17:00 10.4646527 2.250496141 normal 0.21505694 no WABoeingRenton BOIL04 10/07/09 08:00 9.849747807 2.120921053 normal 0.21532745no



### Appendix D-4, p10 of 82

## Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC

(ppm@3%O2) CombUnit_O

p_Indicator THC_Op_Ind

icator CO_Op_Indi

cator TNMOC TO

THC Ratio Outlier WABoeingRenton BOIL04 10/07/09 19:00 8.649340145 1.863109689normal 0.21540484 no WABoeingRenton BOIL04 09/26/09 10:00 8.341129386 1.801184211 normal 0.21594009 no WABoeingRenton BOIL04 10/09/09 09:00 7.478420534 1.615413025normal 0.21600992 no ARDomtarIndustries PB1 9/6/2009 1:00:00 AM 4.315931374 0.932478066 Normal 0.21605489 no WABoeingRenton BOIL04 09/27/09 06:00 8.304902223 1.795714806 normal 0.21622347 no WABoeingRenton BOIL04 08/08/09 02:00 7.224494937 1.566386762 normal 0.21681609 no ARDomtarIndustries PB1 8/28/2009 4:00:00 AM 5.383599255 1.168196206 Normal 0.21699167 no WABoeingRenton BOIL04 10/14/09 01:00 14.01380178 3.04677991 normal 0.2174128no ARDomtarIndustries PB1 9/6/2009 6:00:00 PM 3.082529791 0.670710821 Normal 0.21758454 no WABoeingRenton BOIL04 08/13/09 01:00 9.987109586 2.176812944 normal 0.21796226 no WABoeingRenton BOIL04 09/26/09 22:00 7.463859905 1.627683327 normal 0.21807528 no ARDomtarIndustries PB1 9/11/2009 4.890059866 1.070584499 Normal 0.21893076 no ARDomtarIndustries PB1 9/10/2009 6:00:00 AM 3.599417309 0.789018087 Normal 0.21920717 no WABoeingRenton BOIL04 10/12/09 13:00 10.13681607 2.222256961 normal 0.21922633 no WABoeingRenton BOIL04 09/27/09 10:00 10.58722505 2.325579024 normal 0.21965898 no ARDomtarIndustries PB1 9/6/2009 7:00:00 PM 3.520418336 0.773634505 Normal 0.21975641 no ARDomtarIndustries PB1 9/10/2009 1:00:00 AM 4.346431497 0.957170197 Normal 0.22021978 no WABoeingRenton BOIL04 08/11/09 10:00 9.414619246 2.077757101 normal 0.22069476 no WABoeingRenton BOIL04 10/16/09 23:00 18.10409519 4.013826012 normal 0.22170818 no WABoeingRenton BOIL04 09/26/09 23:00 4.04129989 0.896902234 normal 0.22193409 no WABoeingRenton BOIL04 10/06/09 15:00 8.392962782 1.863555338normal 0.22203784 no ARDomtarIndustries PB1 9/11/2009 9:00:00 AM 4.917672684 1.092653714 Normal 0.22218919 no ARDomtarIndustries PB1 9/11/2009 1:00:00 AM 4.707187943 1.046556364 Normal 0.22233154 no WABoeingRenton BOIL04 09/27/09 05:00 8.681088857 1.932672979normal 0.22263025no WABoeingRenton BOIL04 10/17/09 02:00 7.921571376 1.764013279normal 0.22268477 no WABoeingRenton BOIL04 10/17/09 05:00 6.564533383 1.46284028 normal 0.22283995no WABoeingRenton BOIL04 10/15/09 21:00 8.315258642 1.85511645normal 0.22309787 no WABoeingRenton BOIL04 10/17/09 01:00 18.01643689 4.023672268normal 0.22333341 no WABoeingRenton BOIL04 08/19/09 03:00 1.055905859 0.235910762 normal 0.22342026 no WABoeingRenton BOIL04 09/27/09 04:00 7.722708765 1.727631354 normal 0.22370795no ARDomtarIndustries PB1 9/7/2009 2:00:00 PM 4.235578973 0.947696547 Normal 0.22374664 no



### Appendix D-4, p11 of 82

## Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC

(ppm@3%O2) CombUnit_O

p_Indicator THC_Op_Ind

icator CO_Op_Indi

cator TNMOC TO

THC Ratio Outlier
ARDomtarIndustries PB1 9/6/2009 10:00:00 PM 2.822554032 0.633886518 Normal 0.22457906 no
ARDomtarIndustries PB1 9/5/2009 10:00:00 PM 2.546520796 0.572157096 Normal 0.22468189 no WVDuPontWashingtonWorks P05 9/24/2009 2:00:37 AM 0.281332352 0.063276388 0.22491686 no WABoeingRenton BOIL04 08/21/09 22:00 3.763971544 0.847653624 normal 0.22520192 no WABoeingRenton BOIL04 10/08/09 14:00 4.177067255 0.94306505normal 0.22577205no WABoeingRenton BOIL04 10/06/09 14:00 7.188920371 1.62395701 normal 0.2258972 no WABoeingRenton BOIL04 09/27/09 03:00 4.495820604 1.015593303 normal 0.2258972 no WABoeingRenton BOIL04 08/18/09 21:00 2.700792855 0.610101554 normal 0.2258972 no WABoeingRenton BOIL04 09/28/09 13:00 7.840913108 1.771502209normal 0.2259306 no WABoeingRenton BOIL04 09/28/09 14:00 8.920462308 2.016799219normal 0.22608685no WABoeingRenton BOIL04 08/12/09 10:00 14.06060174 3.179918949normal 0.2261581 no ARDomtarIndustries PB1 9/11/2009 6:00:00 AM 5.042359194 1.140892965 Normal 0.22626174 no WABoeingRenton BOIL04 10/15/09 05:00 14.17140468 3.207491639normal 0.22633548 no WABoeingRenton BOIL04 09/27/09 22:00 5.795333817 1.311988389normal 0.22638703 no WABoeingRenton BOIL04 08/17/09 09:00 10.48206546 2.380554057 normal 0.22710735no ARDomtarIndustries PB1 9/6/2009 9:00:00 AM 4.427053698 1.006754096 Normal 0.22740951 no WABoeingRenton BOIL04 10/07/09 15:00 9.528268034 2.167513731 normal 0.22748245no WABoeingRenton BOIL04 09/28/09 08:00 4.903579762 1.11726882 normal 0.22784759 no ARDomtarIndustries PB1 9/10/2009 5:00:00 PM 7.596419293 1.734727494 Normal 0.22836121 no WABoeingRenton BOIL04 10/06/09 08:00 7.543092105 1.726578947 normal 0.22889538 no ARDomtarIndustries PB1 9/8/2009 4:00:00 AM 3.310809512 0.75846859 Normal 0.22908856 no WABoeingRenton BOIL04 08/21/09 15:00 7.991474501 1.831929047 normal 0.22923542 no WABoeingRenton BOIL04 08/13/09 15:00 9.996853575 2.291958864 normal 0.22926802 no WABoeingRenton BOIL04 08/12/09 03:00 9.718090274 2.231796885normal 0.22965385no WABoeingRenton BOIL04 10/17/09 07:00 18.49933317 4.249303805normal 0.22970038 no WABoeingRenton BOIL04 10/06/09 10:00 3.629676391 0.836410885normal 0.23043676 no WABoeingRenton BOIL04 10/09/09 10:00 4.989906496 1.151619094 normal 0.23078971 no WABoeingRenton BOIL04 10/08/09 21:00 7.301299705 1.685611193 normal 0.23086454 no WABoeingRenton BOIL04 10/17/09 04:00 2.510854197 0.579764359normal 0.23090324 no WABoeingRenton BOIL04 10/14/09 03:00 15.15078918 3.500056283 normal 0.23101478 no



### Appendix D-4, p12 of 82

## Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC

(ppm@3%O2) CombUnit_O

p_Indicator THC_Op_Ind

icator CO_Op_Indi

cator TNMOC TO

THC Ratio Outlier WABoeingRenton BOIL04 10/08/09 20:00 4.697097567 1.085706562 normal 0.23114414 no ARDomtarIndustries PB1 9/7/2009 7:00:00 AM 3.27672018 0.758485399 Normal 0.23147701 no ARDomtarIndustries PB1 9/11/2009 3:00:00 AM 4.582672756 1.063118166 Normal 0.23198649 no TXDibollTemple-Inland PB-44 0500-0600 4.367034027 1.013606174 0.23210402 no WABoeingRenton BOIL04 08/11/09 08:00 14.81759647 3.440044101 normal 0.23215939 no WABoeingRenton BOIL04 10/15/09 20:00 4.206782032 0.977010309normal 0.23224648 no WABoeingRenton BOIL04 08/14/09 05:00 11.39096652 2.6502588normal 0.23266321 no ARDomtarIndustries PB1 8/28/2009 6:00:00 AM 5.988135116 1.394960021 Normal 0.232954 no WABoeingRenton BOIL04 08/14/09 01:00 9.227864838 2.152727718normal 0.23328557 no ARDomtarIndustries PB1 9/10/2009 3:00:00 AM 4.675155583 1.092714761 Normal 0.233728no WABoeingRenton BOIL04 10/13/09 20:00 12.13871563 2.843661249normal 0.23426377 no WABoeingRenton BOIL04 08/11/09 04:00 7.274810499 1.706037042 normal 0.23451292 no WABoeingRenton BOIL04 10/17/09 03:00 2.331792106 0.54688404 normal 0.23453379 no ARDomtarIndustries PB1 9/7/2009 4:00:00 PM 4.284036362 1.005011212 Normal 0.23459446 no ARDomtarIndustries PB1 9/6/2009 4:00:00 PM 3.48160543 0.816888238 Normal 0.23462976 no WABoeingRenton BOIL04 10/13/09 11:00 2.490982589 0.585827347 normal 0.23517922 no WABoeingRenton BOIL04 10/16/09 20:00 17.15701953 4.039356503 normal 0.23543463 no WABoeingRenton BOIL04 09/27/09 21:00 7.271298984 1.714049347 normal 0.23572808 no WABoeingRenton BOIL04 09/26/09 18:00 6.272851959 1.481277213 normal 0.23614095no WABoeingRenton BOIL04 10/08/09 07:00 7.848489526 1.853980154 normal 0.23622127 no WABoeingRenton BOIL04 10/05/09 22:00 5.223138892 1.235441483 normal 0.23653238 no WABoeingRenton BOIL04 09/28/09 10:00 9.315330154 2.203580337 normal 0.23655419 no WABoeingRenton BOIL04 10/08/09 12:00 6.761686303 1.599720177 normal 0.23658598 no WABoeingRenton BOIL04 10/14/09 09:00 11.43001107 2.71055699 normal 0.23714386 no WABoeingRenton BOIL04 10/14/09 02:00 14.71756106 3.493644358normal 0.2373793 no WABoeingRenton BOIL04 10/09/09 16:00 6.721761022 1.600702444 normal 0.23813736 no WABoeingRenton BOIL04 10/13/09 16:00 12.93612986 3.080733676 normal 0.23814956 no WABoeingRenton BOIL04 08/21/09 14:00 8.638293734 2.067728672 normal 0.23936772 no
ARDomtarIndustries PB1 9/10/2009 10:00:00 PM 4.302771509 1.030615261 Normal 0.23952359 no WABoeingRenton BOIL04 10/16/09 17:00 16.91522828 4.058350515normal 0.23992289 no ARDomtarIndustries PB1 8/28/2009 5:00:00 AM 3.812176787 0.915834684 Normal 0.2402393 no



### Appendix D-4, p13 of 82

## Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC

(ppm@3%O2) CombUnit_O

p_Indicator THC_Op_Ind

icator CO_Op_Indi

cator TNMOC TO

THC Ratio Outlier ARDomtarIndustries PB1 9/10/2009 2:00:00 AM 4.912625743 1.180628962 Normal 0.24032544 no WABoeingRenton BOIL04 10/09/09 14:00 7.358343957 1.769330718normal 0.2404523 no WABoeingRenton BOIL04 10/15/09 06:00 5.114432493 1.233026706 normal 0.24108769 no ARDomtarIndustries PB1 9/7/2009 5:00:00 AM 4.148736657 1.002074634 Normal 0.2415373 no WABoeingRenton BOIL04 10/07/09 17:00 6.552448454 1.5889838normal 0.2425023 no WABoeingRenton BOIL04 08/25/09 10:00 10.56687361 2.564700665normal 0.2427114 no WABoeingRenton BOIL04 10/13/09 03:00 5.655894378 1.373195425normal 0.24279015no TXDibollTemple-Inland PB-44 1600-1700 55.35781348 13.44065683 0.24279602 no WABoeingRenton BOIL04 09/28/09 15:00 10.00297685 2.432679162 normal 0.24319552 no WABoeingRenton BOIL04 10/13/09 21:00 11.93771512 2.904254852 normal 0.24328398 no WABoeingRenton BOIL04 09/27/09 00:00 3.594460186 0.876082071 normal 0.24373119 no VAPhilipMorrisPark500 B3 11/12/2009 5:00:00 AM 1.503477829 0.366444446 Normal 0.24373119 no WABoeingRenton BOIL04 10/13/09 15:00 10.29023815 2.510723009normal 0.24399076 no ARDomtarIndustries PB1 9/8/2009 1:00:00 AM 2.676347925 0.653571379 Normal 0.2442027 no WABoeingRenton BOIL04 10/13/09 19:00 11.69245687 2.857844121 normal 0.24441776 no WABoeingRenton BOIL04 08/14/09 10:00 7.593977677 1.85625414 normal 0.24443766 no ARDomtarIndustries PB1 9/11/2009 4:00:00 AM 4.748200057 1.164536451 Normal 0.24525851 no
ARDomtarIndustries PB1 9/8/2009 11:00:00 AM 9.890925669 2.429534369 Normal 0.24563266 no WVDuPontWashingtonWorks P05 9/24/2009 7:00:41 AM 0.26258899 0.064650326 0.24620349 no WABoeingRenton BOIL04 08/11/09 03:00 16.33255489 4.023672268normal 0.24635902 no
ARDomtarIndustries PB1 9/11/2009 10:00:00 AM 5.050936602 1.244765064 Normal 10:37 - 10:59 final bias check 10:37 - 10:59

final bias check 0.24644242 no WABoeingRenton BOIL04 10/15/09 13:00 11.74774792 2.895344406 normal 0.24645953 no WABoeingRenton BOIL04 08/17/09 00:00 12.35874755 3.052375122 normal 0.24698094 no ARDomtarIndustries PB1 9/7/2009 2:00:00 AM 4.099300437 1.016398382 Normal 0.24794435no VAPhilipMorrisPark500 B3 10/15/2009 1:00:00 AM 7.594875346 1.884764543 Normal 0.24816267 no WABoeingRenton BOIL04 09/28/09 02:00 6.164325109 1.534179971 normal 0.24888044 no WABoeingRenton BOIL04 10/05/09 23:00 6.924359794 1.741430327 normal 0.25149333 no WABoeingRenton BOIL04 09/28/09 00:00 6.027296043 1.517117733 normal 0.25170785no WABoeingRenton BOIL04 08/22/09 07:00 6.32181114 1.591914423 normal 0.25181303 no TXDibollTemple-Inland PB-44 2000-2100 3.820533346 0.962313881 0.25187946 no WABoeingRenton BOIL04 08/08/09 01:00 7.707278786 1.943280267 normal 0.25213572 no



### Appendix D-4, p14 of 82

## Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC

(ppm@3%O2) CombUnit_O

p_Indicator THC_Op_Ind

icator CO_Op_Indi

cator TNMOC TO

THC Ratio Outlier WABoeingRenton BOIL04 08/25/09 08:00 10.85425721 2.737117517 normal 0.25216995no VAPhilipMorrisPark500 B3 10/15/2009 2:00:00 AM 7.34377084 1.856198848 Normal 0.25275827 no WABoeingRenton BOIL04 09/28/09 12:00 9.292994626 2.350464094 normal 0.2529286 no
ARDomtarIndustries PB1 9/10/2009 11:00:00 PM 4.767137563 1.206299502 Normal 0.25304483 no TXDibollTemple-Inland PB-44 0900-1000 5.433099821 1.37560601 0.2531899no VAPhilipMorrisPark500 B3 10/15/2009 9:00:00 AM 6.69826814 1.697879964 Normal 0.25348044 no VAPhilipMorrisPark500 B3 10/15/2009 11:00:00 PM 6.707511246 1.700222911 Normal 0.25348044 no WABoeingRenton BOIL04 09/28/09 06:00 8.17128866 2.072120766 normal 0.25358555no WABoeingRenton BOIL04 08/08/09 08:00 8.265189169 2.098308605normal 0.25387303 no WABoeingRenton BOIL04 10/07/09 10:00 9.46255584 2.402416697 normal 0.25388666 no
ARDomtarIndustries PB1 9/9/2009 10:00:00 PM 4.445859273 1.129283632 Normal 0.25400796 no ARDomtarIndustries PB1 9/8/2009 2.008709189 0.510438731 Normal 0.25411281 no WABoeingRenton BOIL04 10/16/09 22:00 16.4958627 4.200501044 normal 0.25463967 no
ARDomtarIndustries PB1 9/7/2009 11:00:00 AM 2.76093075 0.703071278 Normal 0.2546501 no WABoeingRenton BOIL04 08/10/09 15:00 12.24941617 3.12236968 normal 0.25489947 no
ARDomtarIndustries PB1 9/9/2009 11:00:00 PM 4.137095748 1.055059823 Normal 0.25502427 no WABoeingRenton BOIL04 10/08/09 23:00 8.462807319 2.159336854 normal 0.25515609 no ARDomtarIndustries PB1 9/10/2009 7:00:00 AM 1.688780378 0.430910169 Normal 0.25516057 no WABoeingRenton BOIL04 08/12/09 07:00 12.81857143 3.274594993 normal 0.25545709 no WABoeingRenton BOIL04 10/06/09 00:00 3.183861495 0.813468739normal 0.25549753 no WABoeingRenton BOIL04 08/17/09 03:00 8.144265914 2.081579787 normal 0.25558839 no WABoeingRenton BOIL04 08/22/09 01:00 5.68135255 1.454767184 normal 0.25606001 no ARDomtarIndustries PB1 9/7/2009 1:00:00 PM 3.823997727 0.980102758 Normal 0.25630317 no
WVDuPontWashingtonWorks P05 9/24/2009 12:00:35 AM 0.283100049 0.072569295 0.25633798 no WABoeingRenton BOIL04 08/13/09 06:00 7.521550074 1.932547865normal 0.25693479 no WABoeingRenton BOIL04 08/14/09 03:00 12.57629602 3.231649485normal 0.25696354 no WABoeingRenton BOIL04 08/25/09 06:00 6.358818898 1.635944882 normal 0.25727182 no VAPhilipMorrisPark500 B3 10/15/2009 1:00:00 PM 7.38483541 1.901796716 Normal 0.2575273 no WABoeingRenton BOIL04 08/14/09 02:00 13.19591193 3.40134429 normal 0.25775743 no



### Appendix D-4, p15 of 82

## Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC

(ppm@3%O2) CombUnit_O

p_Indicator THC_Op_Ind

icator CO_Op_Indi

cator TNMOC TO

THC Ratio Outlier WABoeingRenton BOIL04 09/28/09 11:00 8.6892253 2.241152243 normal 0.25792314 no WABoeingRenton BOIL04 08/12/09 09:00 9.635140966 2.487786222 normal 0.25819926 no WABoeingRenton BOIL04 08/11/09 01:00 12.93791621 3.343594267 normal 0.25843375no ARDomtarIndustries PB1 9/6/2009 3.203722508 0.831001509 Normal 0.25938623 no ARDomtarIndustries PB1 9/11/2009 7:00:00 AM 5.196484191 1.350788397 Normal 0.25994275no VAPhilipMorrisPark500 B3 11/11/2009 11:00:00 PM 2.148182197 0.558484278 Normal 0.25997994 no VAPhilipMorrisPark500 B3 11/11/2009 10:00:00 PM 2.182877077 0.567504251 Normal 0.25997994 no WABoeingRenton BOIL04 08/19/09 07:00 3.140494904 0.816465676 normal 0.25997994 no ARDomtarIndustries PB1 9/6/2009 7:00:00 AM 4.49020177 1.167673744 Normal 0.26004928 no WABoeingRenton BOIL04 10/09/09 15:00 8.17128866 2.125802651 normal 0.26015513 no WABoeingRenton BOIL04 10/07/09 00:00 3.073769353 0.799829331 normal 0.26021124 no ARDomtarIndustries PB1 9/11/2009 8:00:00 AM 5.053030236 1.315309111 Normal 0.26030106 no WABoeingRenton BOIL04 09/27/09 07:00 8.576891645 2.234075155normal 0.26047608 no WABoeingRenton BOIL04 10/14/09 04:00 11.37593152 2.963240059normal 0.26048329 no WABoeingRenton BOIL04 10/16/09 07:00 11.7034357 3.050507769normal 0.26065062 no WABoeingRenton BOIL04 08/18/09 07:00 10.73720545 2.802194404 normal 0.26097986 no WABoeingRenton BOIL04 08/25/09 12:00 7.321297616 1.913423446 normal 0.26135032 no TXDibollTemple-Inland PB-44 0300-0400 29.46750896 7.703618701 0.26142755no TXDibollTemple-Inland PB-44 0600-0700 3.575209219 0.934818066 0.26147227 no WABoeingRenton BOIL04 10/15/09 16:00 14.34492834 3.750826902 normal 0.26147408 no WABoeingRenton BOIL04 10/07/09 07:00 9.875428676 2.585144108normal 0.26177538 no WABoeingRenton BOIL04 08/10/09 16:00 13.84871959 3.633354633 normal 0.26236033 no VAPhilipMorrisPark500 B3 10/15/2009 6:00:00 PM 6.873476711 1.804148428 Normal 0.26247975no VAPhilipMorrisPark500 B3 10/15/2009 7:00:00 PM 6.873476711 1.804148428 Normal 0.26247975no VAPhilipMorrisPark500 B3 10/15/2009 9:00:00 PM 6.873476711 1.804148428 Normal 0.26247975no VAPhilipMorrisPark500 B3 10/15/2009 5:00:00 PM 6.924268686 1.817480293 Normal 0.26247975no VAPhilipMorrisPark500 B3 10/15/2009 8:00:00 PM 6.924268686 1.817480293 Normal 0.26247975no VAPhilipMorrisPark500 B3 10/15/2009 7:00:00 AM 6.966198865 1.828486115 Normal 0.26247975no VAPhilipMorrisPark500 B3 10/15/2009 6:00:00 AM 7.018592058 1.842238267 Normal 0.26247975no VAPhilipMorrisPark500 B3 10/15/2009 8:00:00 AM 7.071779327 1.856198848 Normal 0.26247975no VAPhilipMorrisPark500 B3 10/15/2009 4:00:00 PM 7.189903846 1.887204142 Normal 0.26247975no VAPhilipMorrisPark500 B3 10/15/2009 3:00:00 PM 7.723226072 2.027190425 Normal 0.26247975no



### Appendix D-4, p16 of 82

## Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC

(ppm@3%O2) CombUnit_O

p_Indicator THC_Op_Ind

icator CO_Op_Indi

cator TNMOC TO

THC Ratio Outlier WABoeingRenton BOIL04 08/12/09 00:00 13.82235042 3.628498715normal 0.26250953 no TXDibollTemple-Inland PB-44 1000-1100 3.231587824 0.848456591 0.26255099 no WABoeingRenton BOIL04 10/17/09 08:00 5.568155566 1.461941509normal 0.262554 no WABoeingRenton BOIL04 10/13/09 22:00 13.3364618 3.502198825normal 0.2626033 no WABoeingRenton BOIL04 10/13/09 13:00 7.792081442 2.049390408normal 0.26300937 no ARDomtarIndustries PB1 9/10/2009 9:00:00 PM 4.850419225 1.276248737 Normal 0.26312133 no WABoeingRenton BOIL04 10/13/09 18:00 9.321455347 2.454112459normal 0.26327568 no WABoeingRenton BOIL04 10/07/09 13:00 5.576070777 1.46810653 normal 0.26328693 no WABoeingRenton BOIL04 08/12/09 01:00 6.108199436 1.609468907 normal 0.26349318 no ARDomtarIndustries PB1 9/5/2009 9:00:00 PM 1.868125848 0.492813945 Normal 0.26380126 no WABoeingRenton BOIL04 09/27/09 12:00 4.968691385 1.314372955normal 0.26453101 no WABoeingRenton BOIL04 08/17/09 02:00 11.40700722 3.018397161 normal 0.26460903 no WABoeingRenton BOIL04 08/12/09 12:00 11.55213181 3.059867452 normal 0.2648747 no WABoeingRenton BOIL04 09/27/09 11:00 6.030799951 1.597710946 normal 0.26492521 no WABoeingRenton BOIL04 10/09/09 11:00 7.235399483 1.916956789normal 0.26494139 no VAPhilipMorrisPark500 B3 11/12/2009 9:00:00 AM 1.334184915 0.354744526 Normal 0.26588857 no VAPhilipMorrisPark500 B3 11/12/2009 8:00:00 AM 1.368671819 0.363914199 Normal 0.26588857 no WABoeingRenton BOIL04 08/07/09 18:00 1.206933236 0.320909758normal 0.26588857 no WABoeingRenton BOIL04 10/08/09 16:00 7.781075678 2.070849994 normal 0.26613929 no WABoeingRenton BOIL04 10/09/09 04:00 9.140185094 2.43417014 normal 0.26631519 no WABoeingRenton BOIL04 10/13/09 14:00 7.129772977 1.900578543 normal 0.26656929 no WABoeingRenton BOIL04 10/07/09 09:00 8.576891645 2.287267421 normal 0.2666779no WABoeingRenton BOIL04 08/24/09 14:00 7.114086892 1.900338733 normal 0.26712335no VAPhilipMorrisPark500 B3 10/15/2009 10:00:00 PM 6.892976702 1.8447426 Normal 0.26762641 no VAPhilipMorrisPark500 B3 10/20/2009 2:00:00 PM 4.162952464 1.119604273 Normal 0.26894477 no ARDomtarIndustries PB1 9/10/2009 9:00:00 AM 1.554337274 0.418570348 Normal 0.26929184 no ARDomtarIndustries PB1 9/1/2009 4:00:00 PM 25.9585118 6.997833607 Normal 0.26957761 no WABoeingRenton BOIL04 10/14/09 07:00 10.62303012 2.870303624 normal 0.27019632 no WABoeingRenton BOIL04 10/09/09 03:00 4.981342627 1.347820983 normal 0.27057384 no VAPhilipMorrisPark500 B3 10/15/2009 3:00:00 AM 7.288537906 1.973826715 Normal 0.27081244 no WABoeingRenton BOIL04 10/09/09 13:00 6.695611193 1.814447717 normal 0.2709906 no



### Appendix D-4, p17 of 82

## Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC

(ppm@3%O2) CombUnit_O

p_Indicator THC_Op_Ind

icator CO_Op_Indi

cator TNMOC TO

THC Ratio Outlier WABoeingRenton BOIL04 08/25/09 02:00 5.347634554 1.451191939normal 0.27137081 no WABoeingRenton BOIL04 10/15/09 23:00 12.28590463 3.34564354 normal 0.2723156 no WABoeingRenton BOIL04 09/28/09 05:00 7.797846943 2.124804101 normal 0.272486 no VAPhilipMorrisPark500 B3 11/15/2009 5:00:00 PM 2.967208919 0.809985536 Normal 0.27297894 no WABoeingRenton BOIL04 08/17/09 13:00 8.772332885 2.394662104 normal 0.27297894 no VAPhilipMorrisPark500 B3 11/15/2009 6:00:00 PM 2.947793212 0.804685457 Normal 0.27297894 no WABoeingRenton BOIL04 10/09/09 00:00 3.921842556 1.071008815normal 0.27308817 no WABoeingRenton BOIL04 08/17/09 07:00 9.250175288 2.530679088normal 0.27358174 no WABoeingRenton BOIL04 08/14/09 15:00 9.938205569 2.725367349normal 0.27423133 no WABoeingRenton BOIL04 08/24/09 15:00 4.471044537 1.226958661 normal 0.27442327 no ARDomtarIndustries PB1 9/1/2009 5:00:00 PM 32.53447624 8.935515344 Normal 0.27464759 no ARDomtarIndustries PB1 9/10/2009 2:00:00 PM 6.89130148 1.893007385 Normal 0.27469519 no ARDomtarIndustries PB1 9/9/2009 9:00:00 PM 4.37588772 1.203830972 Normal 0.27510554 no ARDomtarIndustries PB1 9/10/2009 4:00:00 PM 7.929638525 2.182821289 Normal 0.27527374 no ARDomtarIndustries PB1 9/10/2009 6:00:00 PM 6.228463803 1.714684197 Normal 0.27529809 no WABoeingRenton BOIL04 08/14/09 14:00 10.76583692 2.96505956 normal 0.27541375no WABoeingRenton BOIL04 08/19/09 05:00 4.858588754 1.339581036 normal 0.27571402 no VAPhilipMorrisPark500 B3 10/15/2009 5:00:00 AM 7.153564982 1.973826715 Normal 0.27592211 no VAPhilipMorrisPark500 B3 10/15/2009 4:00:00 AM 7.100164228 1.959092266 Normal 0.27592211 no VAPhilipMorrisPark500 B3 10/15/2009 11:00:00 AM 7.163289514 1.976509928 Normal 0.27592211 no VAPhilipMorrisPark500 B3 10/15/2009 12:00:00 PM 7.38483541 2.037639338 Normal 0.27592211 no VAPhilipMorrisPark500 B3 10/15/2009 2:00:00 PM 7.442382719 2.053517913 Normal 0.27592211 no WABoeingRenton BOIL04 10/07/09 11:00 6.045638298 1.668730741 normal 0.27602226 no WABoeingRenton BOIL04 10/05/09 21:00 6.920108068 1.912248557 normal 0.27633218 no WABoeingRenton BOIL04 09/28/09 01:00 6.716218146 1.863109689normal 0.27740458 no WABoeingRenton BOIL04 09/26/09 11:00 4.227484438 1.17451483 normal 0.2778283 no WABoeingRenton BOIL04 10/09/09 01:00 2.501643434 0.695304475normal 0.27793908 no VAPhilipMorrisPark500 B3 11/12/2009 1.989161286 0.554080748 Normal 0.27854994 no WABoeingRenton BOIL04 08/13/09 05:00 6.540407938 1.821830209normal 0.27854994 no VAPhilipMorrisPark500 B3 11/12/2009 1:00:00 AM 1.791421506 0.499000345 Normal 0.27854994 no VAPhilipMorrisPark500 B3 11/14/2009 7:00:00 PM 2.394412998 0.666963586 Normal 0.27854994 no



### Appendix D-4, p18 of 82

## Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC

(ppm@3%O2) CombUnit_O

p_Indicator THC_Op_Ind

icator CO_Op_Indi

cator TNMOC TO

THC Ratio Outlier WABoeingRenton BOIL04 10/07/09 12:00 3.59225724 1.000623023 normal 0.27854994 no VAPhilipMorrisPark500 B3 10/20/2009 1:00:00 PM 3.98789872 1.110828931 Normal 0.27854994 no WABoeingRenton BOIL04 08/19/09 12:00 7.501331209 2.101750429normal 0.28018366 no WABoeingRenton BOIL04 08/13/09 12:00 7.88012756 2.210337299normal 0.28049512 no ARDomtarIndustries PB1 9/10/2009 4:00:00 AM 5.005003371 1.406659096 Normal 0.28105058 no VAPhilipMorrisPark500 B3 10/15/2009 10:00:00 AM 7.028133108 1.976509928 Normal 0.2812283 no WABoeingRenton BOIL04 10/15/09 22:00 12.34089973 3.474322138normal 0.28152908 no WABoeingRenton BOIL04 08/19/09 01:00 10.52531907 2.968705275normal 0.28205371 no WABoeingRenton BOIL04 10/09/09 06:00 4.697616408 1.325454545normal 0.2821547 no
ARDomtarIndustries PB1 9/5/2009 11:00:00 PM 2.448279946 0.692366443 Normal 0.28279709 no WABoeingRenton BOIL04 08/17/09 05:00 5.935747423 1.685611193 normal 0.28397623 no VAPhilipMorrisPark500 B3 11/15/2009 4:00:00 PM 2.848520562 0.809985536 Normal 0.28435306 no ARDomtarIndustries PB1 9/9/2009 7:00:00 PM 4.289588542 1.22183607 Normal 0.28483759 no WABoeingRenton BOIL04 08/14/09 08:00 9.454542552 2.696485325normal 0.28520527 no WABoeingRenton BOIL04 10/05/09 20:00 5.212119612 1.49327275normal 0.28650009 no WABoeingRenton BOIL04 08/14/09 04:00 12.34089973 3.538661437 normal 0.28674258 no WABoeingRenton BOIL04 08/12/09 08:00 10.5629565 3.031378717 normal 0.28698203 no WABoeingRenton BOIL04 08/25/09 11:00 7.693037694 2.209090909normal 0.28715457 no WABoeingRenton BOIL04 08/14/09 00:00 7.96205081 2.286848306 normal 0.2872185no WABoeingRenton BOIL04 08/11/09 13:00 9.68087245 2.784138609normal 0.2875917 no WABoeingRenton BOIL04 08/13/09 02:00 8.633814433 2.49083947 normal 0.28849815no ARDomtarIndustries PB1 8/29/2009 2:00:00 AM 14.42374051 4.166581095 Normal 0.28886967 no WABoeingRenton BOIL04 08/11/09 06:00 8.184237267 2.366929481 normal 0.28920587 no WABoeingRenton BOIL04 10/14/09 05:00 6.176234951 1.787260124 normal 0.28937696 no ARDomtarIndustries PB1 9/8/2009 3:00:00 AM 2.011924742 0.582569456 Normal 0.28955827 no WABoeingRenton BOIL04 08/08/09 13:00 3.423878735 0.993845394 normal 0.29026886 no WABoeingRenton BOIL04 10/06/09 12:00 6.362434211 1.854473684 normal 0.29147236 no ARDomtarIndustries PB1 9/8/2009 2:00:00 AM 2.711073269 0.791905259 Normal 0.29210028 no WABoeingRenton BOIL04 10/08/09 19:00 5.369686655 1.569437208normal 0.29227724 no WABoeingRenton BOIL04 08/12/09 02:00 13.58944772 3.972459499normal 0.29231942 no



### Appendix D-4, p19 of 82

## Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC

(ppm@3%O2) CombUnit_O

p_Indicator THC_Op_Ind

icator CO_Op_Indi

cator TNMOC TO

THC Ratio Outlier WVDuPontWashingtonWorks P05 9/24/2009 3:00:37 AM 0.282645912 0.082654939 0.29243281 no WABoeingRenton BOIL04 08/12/09 15:00 6.600548938 1.933734496 normal 0.29296571 no ARDomtarIndustries PB1 9/2/2009 5:00:00 PM 16.93370552 4.961583656 Normal 0.29300047 no ARDomtarIndustries PB1 9/10/2009 8:00:00 PM 5.157223259 1.513991412 Normal 0.29356717 no WABoeingRenton BOIL04 08/14/09 11:00 9.377904832 2.753581704 normal 0.2936244 no TXDibollTemple-Inland PB-44 1700-1800 62.86951373 18.49946861 0.29425182 no WABoeingRenton BOIL04 08/14/09 12:00 9.789127237 2.884545232 normal 0.29466827 no ARDomtarIndustries PB1 8/28/2009 7:00:00 AM 3.310731574 0.977304648 Normal 0.29519296 no WABoeingRenton BOIL04 10/08/09 22:00 5.89515502 1.743572835normal 0.2957637 no WABoeingRenton BOIL04 08/19/09 09:00 3.838657759 1.136660946 normal 0.29610896 no VAPhilipMorrisPark500 B3 11/15/2009 3:00:00 PM 2.711969755 0.804685457 Normal 0.29671624 no WVDuPontWashingtonWorks P05 9/22/2009 9:00:00 AM 0.712684354 0.211729728 0.29708766 no ARDomtarIndustries PB1 9/1/2009 8:00:00 PM 27.52827383 8.184065544 Normal 0.29729672 no ARDomtarIndustries PB1 9/7/2009 9:00:00 PM 1.693830877 0.503681983 Normal 0.29736262 no WABoeingRenton BOIL04 09/27/09 20:00 4.782426143 1.424068491 normal 0.29777114 no WABoeingRenton BOIL04 08/17/09 08:00 13.71380671 4.087347842 normal 0.29804619 no WABoeingRenton BOIL04 08/14/09 06:00 7.197770146 2.145958543 normal 0.29814213 no WABoeingRenton BOIL04 10/09/09 12:00 5.796141471 1.729618077 normal 0.29840853 no ARDomtarIndustries PB1 8/31/2009 6:00:00 PM 9.713838928 2.90476671 Normal 0.29903386 no WABoeingRenton BOIL04 08/12/09 13:00 11.5001708 3.439862374 normal 0.29911402 no WABoeingRenton BOIL04 08/22/09 02:00 4.487602605 1.34369624 normal 0.29942407 no WABoeingRenton BOIL04 10/09/09 02:00 3.249734492 0.974021779normal 0.29972349 no VAPhilipMorrisPark500 B3 11/13/2009 10:00:00 PM 1.465720505 0.439682226 Normal 0.29997685no VAPhilipMorrisPark500 B3 11/12/2009 2:00:00 AM 1.606430183 0.481891872 Normal 0.29997685no VAPhilipMorrisPark500 B3 11/12/2009 3:00:00 AM 1.61752124 0.485218932 Normal 0.29997685no VAPhilipMorrisPark500 B3 11/12/2009 4:00:00 AM 1.61752124 0.485218932 Normal 0.29997685no ARDomtarIndustries PB1 9/2/2009 4:00:00 PM 10.50702859 3.15466425 Normal 0.30024323 no
WVDuPontWashingtonWorks P05 9/22/2009 12:00:03 PM 0.799270487 0.240307501 0.30065854 no WABoeingRenton BOIL04 08/13/09 09:00 7.204357686 2.166089728normal 0.30066382 no WABoeingRenton BOIL04 10/06/09 01:00 3.791717147 1.143180264 normal 0.30149408 no WABoeingRenton BOIL04 08/19/09 06:00 3.719948485 1.126628235normal 0.30286125no



### Appendix D-4, p20 of 82

## Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC

(ppm@3%O2) CombUnit_O

p_Indicator THC_Op_Ind

icator CO_Op_Indi

cator TNMOC TO

THC Ratio Outlier WABoeingRenton BOIL04 08/13/09 14:00 8.118323947 2.463320274 normal 0.3034272 no ARDomtarIndustries PB1 9/1/2009 3:00:00 PM 15.29390967 4.658663213 Normal 0.30460904 no WABoeingRenton BOIL04 08/20/09 06:00 0.702215701 0.213939839normal 0.30466399 no WABoeingRenton BOIL04 09/27/09 13:00 4.579833091 1.396632801 normal 0.30495277 no WABoeingRenton BOIL04 10/14/09 08:00 8.958692506 2.736097142 normal 0.30541255no ARDomtarIndustries PB1 9/2/2009 7:00:00 PM 18.15632794 5.551929257 Normal 0.30578481 no
ARDomtarIndustries PB1 9/10/2009 12:00:00 PM 4.935399062 1.510546139 Normal 0.30606363 no WABoeingRenton BOIL04 08/12/09 21:00 3.929381556 1.205811173 normal 0.30687047 no WABoeingRenton BOIL04 09/28/09 07:00 4.790445508 1.470883652 normal 0.30704527 no WABoeingRenton BOIL04 08/25/09 07:00 4.019569219 1.234683358normal 0.30716808 no ARDomtarIndustries PB1 9/8/2009 6:00:00 AM 2.987125617 0.917677771 Normal 0.30721097 no WABoeingRenton BOIL04 08/20/09 01:00 8.544662894 2.626122047 normal 0.30734063 no WABoeingRenton BOIL04 10/06/09 16:00 6.071130923 1.869687347 normal 0.3079636 no WABoeingRenton BOIL04 08/17/09 14:00 7.155975744 2.207629548normal 0.30850154 no WABoeingRenton BOIL04 08/13/09 10:00 7.193358666 2.21970581 normal 0.30857711 no WABoeingRenton BOIL04 08/18/09 10:00 8.447890548 2.613261508normal 0.30933894 no ARDomtarIndustries PB1 9/3/2009 1:00:00 AM 22.26028196 6.892679479 Normal 0.30964026 no
ARDomtarIndustries PB1 9/7/2009 10:00:00 PM 1.917723961 0.594622432 Normal 0.31006675no VAPhilipMorrisPark500 B3 11/14/2009 9:00:00 PM 2.492726612 0.773252114 Normal 0.31020334 no VAPhilipMorrisPark500 B3 11/15/2009 1:00:00 AM 2.492726612 0.773252114 Normal 0.31020334 no VAPhilipMorrisPark500 B3 11/15/2009 2:00:00 PM 2.611143849 0.809985536 Normal 0.31020334 no VAPhilipMorrisPark500 B3 11/14/2009 5:00:00 PM 2.508432665 0.778124184 Normal 0.31020334 no VAPhilipMorrisPark500 B3 11/14/2009 11:00:00 PM 2.508432665 0.778124184 Normal 0.31020334 no VAPhilipMorrisPark500 B3 11/15/2009 2.524339507 0.783058539 Normal 0.31020334 no WABoeingRenton BOIL04 08/22/09 12:00 2.760753861 0.857857318normal 0.310733 no WABoeingRenton BOIL04 08/22/09 00:00 6.649939677 2.067728672 normal 0.31093946 no VAPhilipMorrisPark500 B3 10/20/2009 12:00:00 PM 3.532930312 1.102189212 Normal 0.31197593 no WABoeingRenton BOIL04 10/14/09 12:00 6.113998545 1.909117362 normal 0.31225349 no WABoeingRenton BOIL04 08/14/09 09:00 8.182301178 2.555257732 normal 0.31229084 no ARDomtarIndustries PB1 9/5/2009 4:00:00 PM 4.0994765 1.281292071 Normal 0.31255017 no



### Appendix D-4, p21 of 82

## Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC

(ppm@3%O2) CombUnit_O

p_Indicator THC_Op_Ind

icator CO_Op_Indi

cator TNMOC TO

THC Ratio Outlier WABoeingRenton BOIL04 08/12/09 11:00 9.201099104 2.879115805normal 0.31290999 no ARDomtarIndustries PB1 8/29/2009 3:00:00 AM 7.67330777 2.402316012 Normal 0.31307437 no ARDomtarIndustries PB1 9/10/2009 3:00:00 PM 6.436195487 2.016861374 Normal 0.31336235no ARDomtarIndustries PB1 9/10/2009 8:00:00 AM 1.723249826 0.540107739 Normal 0.31342393 no WABoeingRenton BOIL04 10/07/09 06:00 2.887811776 0.906473241 normal 0.31389623 no ARDomtarIndustries PB1 8/28/2009 2:00:00 AM 2.74326226 0.861232448 Normal 0.31394463 no WABoeingRenton BOIL04 08/21/09 13:00 8.848021694 2.781935166 normal 0.31441324 no WABoeingRenton BOIL04 09/27/09 14:00 2.486768728 0.783434588normal 0.31504119 no WABoeingRenton BOIL04 08/16/09 10:00 5.818180032 1.837047771 normal 0.31574268 no TXDibollTemple-Inland PB-44 0200-0300 22.18301814 7.019271628 0.31642546 no ARDomtarIndustries PB1 9/9/2009 5:00:00 PM 4.889369648 1.547565936 Normal 0.31651645no WABoeingRenton BOIL04 10/06/09 03:00 3.095646715 0.981123979normal 0.31693668 no ARDomtarIndustries PB1 9/3/2009 4:00:00 AM 19.64349032 6.226446982 Normal 0.31697254 no WABoeingRenton BOIL04 08/14/09 16:00 7.817469894 2.483150651 normal 0.31764122 no WABoeingRenton BOIL04 08/27/09 10:00 11.35211306 3.607091643 normal 0.31774628 no WABoeingRenton BOIL04 08/25/09 05:00 5.138139592 1.633934628normal 0.31800121 no ARDomtarIndustries PB1 9/1/2009 7:00:00 PM 33.3592817 10.6183104 Normal 0.31830153 no WABoeingRenton BOIL04 08/26/09 11:00 7.908294925 2.519955872 normal 0.31864718 no ARDomtarIndustries PB1 9/1/2009 6:00:00 PM 33.10605771 10.54987846 Normal 0.31866913 no WABoeingRenton BOIL04 08/19/09 11:00 5.032720913 1.610456554 normal 0.31999719 no ARDomtarIndustries PB1 9/9/2009 8:00:00 PM 3.990116565 1.276939849 Normal 0.3200257 no ARDomtarIndustries PB1 9/3/2009 3:00:00 AM 23.68851216 7.601467176 Normal 0.32089255no ARDomtarIndustries PB1 9/3/2009 2:00:00 AM 22.29461858 7.154644326 Normal 0.32091351 no ARDomtarIndustries PB1 8/31/2009 4:00:00 PM 26.47017725 8.527445735 Normal 0.32215295no WABoeingRenton BOIL04 08/12/09 06:00 9.514151753 3.066839912 normal 0.32234507 no ARDomtarIndustries PB1 9/1/2009 9:00:00 PM 20.32129695 6.556239379 Normal 0.32262898 no ARDomtarIndustries PB1 9/4/2009 6:00:00 AM 20.40393074 6.591291756 Normal 0.32304029 no ARDomtarIndustries PB1 8/27/2009 7:00:00 AM 2.491931752 0.808090471 Normal 0.32428275no VAPhilipMorrisPark500 B3 11/13/2009 7:00:00 PM 1.344560061 0.436948305 Normal 0.32497492 no VAPhilipMorrisPark500 B3 11/13/2009 8:00:00 PM 1.344560061 0.436948305 Normal 0.32497492 no VAPhilipMorrisPark500 B3 11/13/2009 9:00:00 PM 1.344560061 0.436948305 Normal 0.32497492 no VAPhilipMorrisPark500 B3 11/15/2009 6:00:00 AM 2.052353998 0.666963586 Normal 0.32497492 no



### Appendix D-4, p22 of 82

## Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC

(ppm@3%O2) CombUnit_O

p_Indicator THC_Op_Ind

icator CO_Op_Indi

cator TNMOC TO

THC Ratio Outlier VAPhilipMorrisPark500 B3 11/15/2009 8:00:00 AM 2.052353998 0.666963586 Normal 0.32497492 no VAPhilipMorrisPark500 B3 11/14/2009 6:00:00 PM 2.409596802 0.783058539 Normal 0.32497492 no VAPhilipMorrisPark500 B3 10/19/2009 5:00:00 PM 3.431647351 1.11519934 Normal 0.32497492 no WABoeingRenton BOIL04 08/22/09 09:00 5.920989187 1.924173015normal 0.32497492 no VAPhilipMorrisPark500 B3 11/12/2009 6:00:00 AM 1.493096529 0.485218932 Normal 0.32497492 no VAPhilipMorrisPark500 B3 11/12/2009 7:00:00 AM 1.524678535 0.495482292 Normal 0.32497492 no VAPhilipMorrisPark500 B3 11/14/2009 6:00:00 AM 1.701863205 0.553062867 Normal 0.32497492 no VAPhilipMorrisPark500 B3 11/14/2009 11:00:00 AM 2.065368688 0.671193034 Normal 0.32497492 no VAPhilipMorrisPark500 B3 11/14/2009 3:00:00 PM 2.394412998 0.778124184 Normal 0.32497492 no VAPhilipMorrisPark500 B3 11/14/2009 8:00:00 PM 2.394412998 0.778124184 Normal 0.32497492 no VAPhilipMorrisPark500 B3 11/15/2009 2:00:00 AM 2.394412998 0.778124184 Normal 0.32497492 no VAPhilipMorrisPark500 B3 11/14/2009 4:00:00 PM 2.424972846 0.788055368 Normal 0.32497492 no VAPhilipMorrisPark500 B3 11/15/2009 8:00:00 PM 2.757705754 0.89618522 Normal 0.32497492 no VAPhilipMorrisPark500 B3 11/15/2009 7:00:00 PM 2.793327466 0.907761383 Normal 0.32497492 no WABoeingRenton BOIL04 10/09/09 08:00 3.107437063 1.009839126 normal 0.32497492 no VAPhilipMorrisPark500 B3 10/19/2009 6:00:00 PM 3.458867009 1.124045046 Normal 0.32497492 no WABoeingRenton BOIL04 10/14/09 10:00 5.241958763 1.707083947 normal 0.32565765no ARDomtarIndustries PB1 9/2/2009 8:00:00 PM 16.09832176 5.243176529 Normal 0.32569709 no WABoeingRenton BOIL04 08/22/09 10:00 7.846394919 2.567863838normal 0.32726671 no WABoeingRenton BOIL04 08/26/09 01:00 10.41145345 3.412074083 normal 0.32772313 no ARDomtarIndustries PB1 9/3/2009 23.08120189 7.564453297 Normal 0.32773221 no ARDomtarIndustries PB1 9/10/2009 1:00:00 PM 6.512385494 2.144315316 Normal 0.32926726 no TXDibollTemple-Inland PB-44 1900-2000 45.82101417 15.11006514 0.32976278 no ARDomtarIndustries PB1 9/2/2009 9:00:00 PM 18.87144938 6.226270639 Normal 0.32993071 no WABoeingRenton BOIL04 08/14/09 07:00 9.173427835 3.027658321 normal 0.33004656 no
ARDomtarIndustries PB1 9/2/2009 10:00:00 PM 19.9593507 6.62555227 Normal 0.33195229 no WABoeingRenton BOIL04 09/27/09 23:00 4.550335644 1.510660343 normal 0.33198877 no ARDomtarIndustries PB1 9/6/2009 8:00:00 AM 5.06024685 1.684888047 Normal 0.33296558 no WABoeingRenton BOIL04 08/17/09 11:00 6.373057262 2.128414844 normal 0.33397077 no WABoeingRenton BOIL04 08/21/09 17:00 3.145719539 1.050875215normal 0.33406513 no TXDibollTemple-Inland PB-44 1800-1900 63.38142259 21.19869976 0.33446235no WABoeingRenton BOIL04 08/13/09 07:00 6.236443981 2.101750429normal 0.33701103 no



### Appendix D-4, p23 of 82

## Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC

(ppm@3%O2) CombUnit_O

p_Indicator THC_Op_Ind

icator CO_Op_Indi

cator TNMOC TO

THC Ratio Outlier ARDomtarIndustries PB1 9/3/2009 9:00:00 PM 8.386497593 2.828637679 Normal 0.33728474 no WABoeingRenton BOIL04 08/18/09 23:00 3.328622674 1.124559256 normal 0.33784522 no ARDomtarIndustries PB1 9/4/2009 7:00:00 PM 26.19326857 8.853456744 Normal 0.33800504 no WABoeingRenton BOIL04 08/13/09 03:00 6.284291672 2.124498957 normal 0.33806498 no WABoeingRenton BOIL04 10/07/09 05:00 5.855994156 1.981161573 normal 0.33831345no
ARDomtarIndustries PB1 9/2/2009 11:00:00 PM 20.34602664 6.884458121 Normal 0.33836868 no WABoeingRenton BOIL04 08/13/09 13:00 5.267216014 1.783332924 normal 0.3385722 no WABoeingRenton BOIL04 08/13/09 23:00 7.730787923 2.619675994 normal 0.33886274 no TXDibollTemple-Inland PB-44 1103-1203 1.441400932 0.488511698 0.33891452 no VAPhilipMorrisPark500 B3 11/15/2009 11:00:00 PM 2.694341308 0.91366264 Normal 0.33910427 no VAPhilipMorrisPark500 B3 10/19/2009 3:00:00 PM 3.237706172 1.097919986 Normal 0.33910427 no VAPhilipMorrisPark500 B3 11/15/2009 9:00:00 PM 2.659761409 0.901936449 Normal 0.33910427 no VAPhilipMorrisPark500 B3 11/15/2009 10:00:00 PM 2.676938822 0.907761383 Normal 0.33910427 no VAPhilipMorrisPark500 B3 11/15/2009 12:00:00 PM 2.747929689 0.931834689 Normal 0.33910427 no VAPhilipMorrisPark500 B3 10/19/2009 4:00:00 PM 3.140389226 1.064919394 Normal 0.33910427 no VAPhilipMorrisPark500 B3 11/14/2009 10:00:00 PM 2.622452331 0.889284782 Normal 0.33910427 no
ARDomtarIndustries PB1 9/7/2009 12:00:00 PM 3.340404983 1.134442235 Normal 0.33961219 no WABoeingRenton BOIL04 08/20/09 07:00 5.873276434 1.998192312 normal 0.34021765no WABoeingRenton BOIL04 08/17/09 15:00 7.155906857 2.440152372 normal 0.34099834 no WABoeingRenton BOIL04 08/27/09 06:00 13.29820983 4.535524578normal 0.34106279 no VAPhilipMorrisPark500 B3 11/15/2009 10:00:00 AM 2.342905485 0.79945481 Normal 0.34122367 no VAPhilipMorrisPark500 B3 11/14/2009 1:00:00 PM 2.252013146 0.768440193 Normal 0.34122367 no VAPhilipMorrisPark500 B3 11/14/2009 2:00:00 PM 2.294854097 0.783058539 Normal 0.34122367 no VAPhilipMorrisPark500 B3 11/15/2009 3:00:00 AM 2.280393332 0.778124184 Normal 0.34122367 no WABoeingRenton BOIL04 08/27/09 11:00 11.16132223 3.812791381 normal 0.3416075no WVDuPontWashingtonWorks P05 9/23/2009 8:00:31 PM 0.315193996 0.107717372 0.34174944 no WABoeingRenton BOIL04 08/17/09 01:00 5.62328582 1.924173015normal 0.34217948 no WABoeingRenton BOIL04 08/19/09 10:00 6.756245079 2.314000984 normal 0.34249808 no



### Appendix D-4, p24 of 82

## Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC

(ppm@3%O2) CombUnit_O

p_Indicator THC_Op_Ind

icator CO_Op_Indi

cator TNMOC TO

THC Ratio Outlier

WVDuPontWashingtonWorks P05 9/22/2009 11:00:02 AM 1.012011696 0.346614549 0.34250054 no WABoeingRenton BOIL04 08/25/09 09:00 10.16601868 3.482860654 normal 0.34259829 no ARDomtarIndustries PB1 9/9/2009 6:00:00 PM 5.155523909 1.768226393 Normal 0.34297705no VAPhilipMorrisPark500 B3 11/14/2009 9:00:00 AM 1.938334332 0.666963586 Normal 0.3440911 no VAPhilipMorrisPark500 B3 11/14/2009 8:00:00 AM 1.953374909 0.672138915 Normal 0.3440911 no VAPhilipMorrisPark500 B3 11/14/2009 10:00:00 AM 1.963073256 0.67547603 Normal 0.3440911 no ARDomtarIndustries PB1 9/1/2009 2:00:00 PM 9.997563238 3.444971947 Normal 0.34458116 no WABoeingRenton BOIL04 10/17/09 09:00 5.37522602 1.853980154 normal 0.34491204 no ARDomtarIndustries PB1 9/5/2009 5:00:00 PM 4.276163108 1.475950211 Normal 0.3451576 no WABoeingRenton BOIL04 08/24/09 21:00 1.698601612 0.587616023 normal 0.34594105no WABoeingRenton BOIL04 08/19/09 02:00 5.027879086 1.741430327 normal 0.34635485no
WVDuPontWashingtonWorks P05 9/23/2009 10:00:33 PM 0.313749763 0.108752834 0.34662284 no ARDomtarIndustries PB1 9/4/2009 8:00:00 AM 16.06924513 5.583109916 Normal 0.34744071 no ARDomtarIndustries PB1 9/4/2009 2:00:00 AM 9.606869029 3.341349544 Normal 0.34780838 no WVDuPontWashingtonWorks P05 9/23/2009 9:00:32 PM 0.277852037 0.096677863 0.34794729 no VAPhilipMorrisPark500 B3 11/14/2009 4:00:00 AM 1.588405658 0.553062867 Normal 0.34818742 no VAPhilipMorrisPark500 B3 11/14/2009 5:00:00 AM 1.598470013 0.556567149 Normal 0.34818742 no VAPhilipMorrisPark500 B3 11/14/2009 3:00:00 AM 1.60866169 0.560115762 Normal 0.34818742 no TXDibollTemple-Inland PB-44 2100-2200 54.63706135 19.03622893 0.34841239 no ARDomtarIndustries PB1 9/4/2009 3:00:00 AM 10.56561851 3.682327238 Normal 0.3485198no ARDomtarIndustries PB1 8/28/2009 2.543773641 0.887322103 Normal 0.34882117 no ARDomtarIndustries PB1 9/3/2009 8:00:00 PM 7.060563771 2.463630988 Normal 0.34892837 no ARDomtarIndustries PB1 9/5/2009 8:00:00 PM 2.107624509 0.73575844 Normal 0.3490937 no WABoeingRenton BOIL04 08/25/09 03:00 3.510597933 1.226958661 normal 0.34950133 no ARDomtarIndustries PB1 9/4/2009 7:00:00 AM 22.70311838 7.996826907 Normal 0.35223474 no ARDomtarIndustries PB1 9/4/2009 1:00:00 AM 8.689260615 3.078593399 Normal 0.35429866 no VAPhilipMorrisPark500 B3 11/12/2009 10:00:00 AM 1.334184915 0.472992701 Normal 0.3545181 no VAPhilipMorrisPark500 B3 11/12/2009 11:00:00 AM 1.334184915 0.472992701 Normal 0.3545181 no VAPhilipMorrisPark500 B3 10/19/2009 7:00:00 PM 3.145676738 1.11519934 Normal 0.3545181 no VAPhilipMorrisPark500 B3 11/13/2009 2:00:00 PM 1.224897804 0.434248442 Normal 0.3545181 no



### Appendix D-4, p25 of 82

## Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC

(ppm@3%O2) CombUnit_O

p_Indicator THC_Op_Ind

icator CO_Op_Indi

cator TNMOC TO

THC Ratio Outlier VAPhilipMorrisPark500 B3 11/13/2009 3:00:00 PM 1.232513389 0.436948305 Normal 0.3545181 no VAPhilipMorrisPark500 B3 11/15/2009 11:00:00 AM 2.594058027 0.919640522 Normal 0.3545181 no VAPhilipMorrisPark500 B3 11/15/2009 1:00:00 PM 3.254109548 1.153640733 Normal 0.3545181 no VAPhilipMorrisPark500 B3 10/20/2009 11:00:00 AM 3.108978675 1.102189212 Normal 0.3545181 no WABoeingRenton BOIL04 08/26/09 02:00 9.464957684 3.35842512 normal 0.35482727 no WABoeingRenton BOIL04 08/13/09 16:00 9.041277614 3.21017673 normal 0.35505787 no WABoeingRenton BOIL04 08/10/09 23:00 4.36423561 1.550116094 normal 0.35518616 no WABoeingRenton BOIL04 10/09/09 07:00 3.391248307 1.206175058normal 0.35567288 no ARDomtarIndustries PB1 9/7/2009 3:00:00 PM 3.243132754 1.153861545 Normal 0.3557861 no ARDomtarIndustries PB1 9/4/2009 4:00:00 AM 13.22081587 4.731883495 Normal 0.35791161 no ARDomtarIndustries PB1 8/27/2009 6:00:00 AM 2.93826038 1.053160523 Normal 0.35842995no WABoeingRenton BOIL04 08/13/09 11:00 5.935662117 2.129723349normal 0.35880131 no ARDomtarIndustries PB1 9/4/2009 5:00:00 AM 11.44896863 4.108413197 Normal 0.3588457 no VAPhilipMorrisPark500 B3 11/14/2009 12:00:00 PM 2.166373665 0.778124184 Normal 0.35918281 no VAPhilipMorrisPark500 B3 11/15/2009 5:00:00 AM 2.166373665 0.778124184 Normal 0.35918281 no VAPhilipMorrisPark500 B3 10/19/2009 9:00:00 PM 2.738269715 0.983539415 Normal 0.35918281 no VAPhilipMorrisPark500 B3 11/15/2009 4:00:00 AM 2.180111392 0.783058539 Normal 0.35918281 no WABoeingRenton BOIL04 08/17/09 12:00 5.240108962 1.884975514 normal 0.35972067 no WABoeingRenton BOIL04 08/21/09 18:00 2.629045919 0.947708975normal 0.36047639 no
ARDomtarIndustries PB1 9/10/2009 11:00:00 AM 1.718592593 0.620130129 Normal 0.36083603 no WABoeingRenton BOIL04 08/27/09 08:00 11.44789442 4.147896859normal 0.36232836 no TXDibollTemple-Inland PB-44 1600-1700 4.976849171 1.81862582 0.36541711 no VAPhilipMorrisPark500 B3 11/13/2009 1:00:00 AM 0.89194831 0.326093439 Normal 0.36559679 no VAPhilipMorrisPark500 B3 11/13/2009 2:00:00 AM 0.89194831 0.326093439 Normal 0.36559679 no VAPhilipMorrisPark500 B3 11/14/2009 7:00:00 AM 1.826822872 0.667880579 Normal 0.36559679 no WABoeingRenton BOIL04 09/26/09 12:00 1.850551984 0.679209026 normal 0.3670305no WABoeingRenton BOIL04 08/11/09 16:00 7.393937124 2.717971264 normal 0.36759459 no
ARDomtarIndustries PB1 9/1/2009 10:00:00 PM 29.4874709 10.88216507 Normal 0.36904369 no
ARDomtarIndustries PB1 9/4/2009 11:00:00 AM 8.694362109 3.219172103 Normal 0.37025972 no



### Appendix D-4, p26 of 82

## Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC

(ppm@3%O2) CombUnit_O

p_Indicator THC_Op_Ind

icator CO_Op_Indi

cator TNMOC TO

THC Ratio Outlier
ARDomtarIndustries PB1 9/4/2009 10:00:00 AM 5.543843909 2.052925059 Normal 10:04 - 10:59 calibration 10:04 - 10:59

calibration 0.37030715no ARDomtarIndustries PB1 9/3/2009 2:00:00 PM 7.994735619 2.964841457 Normal 0.37084922 no WABoeingRenton BOIL04 08/20/09 03:00 2.953167137 1.095782881 normal 0.37105346 no VAPhilipMorrisPark500 B3 10/19/2009 12:00:00 PM 2.889019891 1.072981739 Normal 0.37139991 no VAPhilipMorrisPark500 B3 10/19/2009 8:00:00 PM 3.002691432 1.11519934 Normal 0.37139991 no ARDomtarIndustries PB1 9/4/2009 9:00:00 AM 17.57397389 6.530515353 Normal 0.37160152 no ARDomtarIndustries PB1 9/5/2009 1:00:00 PM 3.742705789 1.391905086 Normal 0.37189808 no
ARDomtarIndustries PB1 9/5/2009 11:00:00 AM 3.584825432 1.335065432 Normal 0.37242132 no WABoeingRenton BOIL04 08/18/09 11:00 6.478422407 2.412723707 normal 0.37242457 no ARDomtarIndustries PB1 8/27/2009 4:00:00 AM 2.782849514 1.038933529 Normal 0.37333443 no VAPhilipMorrisPark500 B3 10/1/2009 12:00:00 PM 6.858095297 2.571587311 Normal 0.37497107 no VAPhilipMorrisPark500 B3 11/13/2009 11:00:00 PM 1.465720505 0.549602782 Normal 0.37497107 no VAPhilipMorrisPark500 B3 11/14/2009 2:00:00 AM 1.474948111 0.553062867 Normal 0.37497107 no VAPhilipMorrisPark500 B3 11/14/2009 1:00:00 AM 1.484293583 0.556567149 Normal 0.37497107 no VAPhilipMorrisPark500 B3 11/14/2009 1.493757283 0.560115762 Normal 0.37497107 no WABoeingRenton BOIL04 09/28/09 04:00 1.702760774 0.642605289normal 0.37739024 no ARDomtarIndustries PB1 9/3/2009 4:00:00 PM 6.33418843 2.390926216 Normal 0.3774637 no WABoeingRenton BOIL04 10/14/09 06:00 3.370501652 1.273720788normal 0.37790244 no WVDuPontWashingtonWorks P05 9/22/2009 1:00:04 PM 0.700707215 0.264921406 0.37807718 no
ARDomtarIndustries PB1 8/26/2009 10:00:00 PM 2.346531715 0.887713651 Normal 0.37830882 no
ARDomtarIndustries PB1 9/1/2009 10:00:00 AM 7.191488609 2.725101074 Normal 10:05 - 10:55 calibration 10:05 - 10:55

calibration 0.37893421 no VAPhilipMorrisPark500 B3 11/15/2009 7:00:00 AM 2.039503591 0.773252114 Normal 0.37913741 no VAPhilipMorrisPark500 B3 10/19/2009 10:00:00 PM 2.594150257 0.983539415 Normal 0.37913741 no WABoeingRenton BOIL04 08/10/09 17:00 2.738755823 1.040151998normal 0.37978997 no WABoeingRenton BOIL04 09/27/09 15:00 1.47418217 0.56009181 normal 0.37993392 no WABoeingRenton BOIL04 08/26/09 00:00 6.634542138 2.521313389normal 0.38002824 no ARDomtarIndustries PB1 9/6/2009 2:00:00 AM 3.075938324 1.173302176 Normal 0.38144529 no WABoeingRenton BOIL04 09/27/09 02:00 1.500392585 0.572388222 normal 0.3814923 no



### Appendix D-4, p27 of 82

## Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC

(ppm@3%O2) CombUnit_O

p_Indicator THC_Op_Ind

icator CO_Op_Indi

cator TNMOC TO

THC Ratio Outlier VAPhilipMorrisPark500 B3 10/19/2009 2:00:00 PM 3.368177278 1.284933707 Normal 0.3814923 no TXDibollTemple-Inland PB-44 0500-0600 30.06555288 11.47593581 0.38169715no ARDomtarIndustries PB1 9/1/2009 1:00:00 PM 10.34181759 3.947800793 Normal 0.38173181 no
ARDomtarIndustries PB1 9/1/2009 12:00:00 PM 12.41725594 4.775242616 Normal 0.38456505no WABoeingRenton BOIL04 08/25/09 14:00 8.522583661 3.293415354 normal 0.38643391 no ARDomtarIndustries PB1 9/3/2009 6:00:00 AM 5.992606535 2.324985757 Normal 0.38797571 no WABoeingRenton BOIL04 10/05/09 19:00 2.327926964 0.903518997 normal 0.38812171 no VAPhilipMorrisPark500 B3 11/3/2009 0.635282723 0.247741146 Normal 0.38996991 no VAPhilipMorrisPark500 B3 11/3/2009 2:00:00 AM 0.635282723 0.247741146 Normal 0.38996991 no VAPhilipMorrisPark500 B3 11/2/2009 2:00:00 AM 0.712369006 0.277802477 Normal 0.38996991 no VAPhilipMorrisPark500 B3 11/1/2009 7:00:00 AM 0.732729054 0.285742283 Normal 0.38996991 no VAPhilipMorrisPark500 B3 11/1/2009 8:00:00 AM 0.732729054 0.285742283 Normal 0.38996991 no VAPhilipMorrisPark500 B3 11/13/2009 12:00:00 PM 1.120466718 0.436948305 Normal 0.38996991 no VAPhilipMorrisPark500 B3 11/13/2009 10:00:00 AM 1.127477312 0.439682226 Normal 0.38996991 no VAPhilipMorrisPark500 B3 11/13/2009 11:00:00 AM 1.127477312 0.439682226 Normal 0.38996991 no VAPhilipMorrisPark500 B3 11/12/2009 12:00:00 PM 1.229514936 0.479473828 Normal 0.38996991 no VAPhilipMorrisPark500 B3 11/3/2009 7:00:00 AM 0.644369042 0.251284537 Normal 0.38996991 no VAPhilipMorrisPark500 B3 11/1/2009 9:00:00 AM 0.729749512 0.284580351 Normal 0.38996991 no
ARDomtarIndustries PB1 9/1/2009 11:00:00 PM 15.47748485 6.051428665 Normal 0.39098269 no WABoeingRenton BOIL04 08/25/09 01:00 3.493698279 1.366708166 normal 0.39119239 no
ARDomtarIndustries PB1 9/3/2009 11:00:00 AM 5.371458283 2.103956163 Normal 0.3916918no ARDomtarIndustries PB1 8/28/2009 3:00:00 AM 3.463160098 1.35822878 Normal 0.39219347 no TXDibollTemple-Inland PB-44 0100-0200 4.873571967 1.923410511 0.39466135no WABoeingRenton BOIL04 10/06/09 19:00 2.245166606 0.886224826 normal 0.39472564 no WABoeingRenton BOIL04 08/20/09 02:00 7.734013279 3.07626706 normal 0.39775818 no VAPhilipMorrisPark500 B3 10/19/2009 1:00:00 PM 3.121117497 1.244804225 Normal 0.39883286 no WABoeingRenton BOIL04 08/11/09 14:00 15.91059105 6.352995822 normal 0.39929351 no
ARDomtarIndustries PB1 9/4/2009 12:00:00 PM 7.71894846 3.085329641 Normal 0.39970854 no WABoeingRenton BOIL04 08/24/09 13:00 5.379628044 2.151410743 normal 0.39991812 no



### Appendix D-4, p28 of 82

## Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC

(ppm@3%O2) CombUnit_O

p_Indicator THC_Op_Ind

icator CO_Op_Indi

cator TNMOC TO

THC Ratio Outlier ARDomtarIndustries PB1 8/27/2009 8:00:00 AM 3.007502736 1.207292494 Normal 0.4014269no VAPhilipMorrisPark500 B3 10/1/2009 10:00:00 AM 22.58531624 9.066640608 Normal 0.40143961 no WABoeingRenton BOIL04 08/26/09 13:00 8.403948335 3.373677767 normal 0.40143961 no WABoeingRenton BOIL04 10/06/09 11:00 1.707988456 0.687550043 normal 0.40254958 no WABoeingRenton BOIL04 08/13/09 00:00 5.822343291 2.356219393 normal 0.40468576 no WABoeingRenton BOIL04 10/07/09 03:00 3.169005255 1.282854699normal 0.40481306 no ARDomtarIndustries PB1 9/4/2009 9:00:00 PM 6.617640801 2.682360304 Normal 0.40533483 no VAPhilipMorrisPark500 B3 11/13/2009 4:00:00 PM 1.344560061 0.546185381 Normal 0.40621866 no VAPhilipMorrisPark500 B3 11/13/2009 5:00:00 PM 1.344560061 0.546185381 Normal 0.40621866 no VAPhilipMorrisPark500 B3 11/13/2009 6:00:00 PM 1.352972774 0.549602782 Normal 0.40621866 no WABoeingRenton BOIL04 08/11/09 15:00 11.19144139 4.547068076 normal 0.4062987 no WABoeingRenton BOIL04 08/27/09 09:00 10.71534076 4.356339166 normal 0.40655162 no TXDibollTemple-Inland PB-44 2100-2200 2.281243054 0.929241648 0.40734004 no WABoeingRenton BOIL04 08/13/09 08:00 5.451196613 2.222430044 normal 0.40769581 no
ARDomtarIndustries PB1 9/3/2009 10:00:00 PM 5.184532872 2.119756247 Normal 0.40886157 no WABoeingRenton BOIL04 08/12/09 16:00 5.711991905 2.339094812 normal 0.40950597 no
ARDomtarIndustries PB1 8/27/2009 11:00:00 AM 1.809171765 0.742196342 Normal 0.41024095no VAPhilipMorrisPark500 B3 10/19/2009 1:00:00 AM 2.757018603 1.131741364 Normal 0.41049464 no VAPhilipMorrisPark500 B3 10/18/2009 8:00:00 PM 2.735087024 1.122738568 Normal 0.41049464 no VAPhilipMorrisPark500 B3 10/19/2009 2.735087024 1.122738568 Normal 0.41049464 no VAPhilipMorrisPark500 B3 10/18/2009 7:00:00 PM 2.713501615 1.113877874 Normal 0.41049464 no TXDibollTemple-Inland PB-44 0400-0500 31.52477461 12.95731979 0.41102022 no WABoeingRenton BOIL04 10/14/09 11:00 2.611569446 1.074296942 normal 0.41136066 no ARDomtarIndustries PB1 9/3/2009 5:00:00 AM 7.724569905 3.19014754 Normal 0.41298708 no
ARDomtarIndustries PB1 8/27/2009 11:00:00 PM 2.896975972 1.201203552 Normal 0.4146405no
ARDomtarIndustries PB1 9/3/2009 11:00:00 PM 4.754791814 1.9745815 Normal 0.41528243 no WABoeingRenton BOIL04 08/27/09 02:00 10.78121375 4.495485134 normal 0.41697394 no
ARDomtarIndustries PB1 8/31/2009 11:00:00 PM 4.962486726 2.072136895 Normal 0.41756019 no ARDomtarIndustries PB1 9/7/2009 5:00:00 PM 2.372333488 0.991216909 Normal 0.4178236 no WABoeingRenton BOIL04 08/13/09 04:00 5.26075555 2.210337299normal 0.42015587 no



### Appendix D-4, p29 of 82

## Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC

(ppm@3%O2) CombUnit_O

p_Indicator THC_Op_Ind

icator CO_Op_Indi

cator TNMOC TO

THC Ratio Outlier

WVDuPontWashingtonWorks P05 10/20/2009 10:00:05 AM 0.800968022 0.337245221 0.42104705no ARDomtarIndustries PB1 9/3/2009 3:00:00 PM 6.800228438 2.864777557 Normal 0.42127666 no TXDibollTemple-Inland PB-44 0100-0200 3.140507554 1.327357958 0.42265715no ARDomtarIndustries PB1 9/5/2009 9:00:00 AM 3.865240874 1.638401845 Normal 0.42388092 no WABoeingRenton BOIL04 08/12/09 18:00 4.325265546 1.834794554 normal 0.42420391 no
WVDuPontWashingtonWorks P05 9/23/2009 11:00:34 PM 0.281520602 0.119485355 0.42442846 no ARDomtarIndustries PB1 9/7/2009 6:00:00 PM 1.479157336 0.628645616 Normal 0.42500253 no WABoeingRenton BOIL04 08/27/09 00:00 10.05046222 4.289493764 normal 0.42679567 no WABoeingRenton BOIL04 08/27/09 05:00 10.63645362 4.543443725normal 0.42715776 no
ARDomtarIndustries PB1 9/1/2009 11:00:00 AM 9.235491363 3.951237161 Normal 0.42783183 no
WVDuPontWashingtonWorks P05 9/22/2009 10:00:01 AM 0.643063611 0.275254795 0.42803665no
ARDomtarIndustries PB1 9/3/2009 12:00:00 PM 5.673928187 2.44058247 Normal 0.43013982 no
ARDomtarIndustries PB1 8/31/2009 10:00:00 PM 4.713746219 2.03564024 Normal 0.4318519no WABoeingRenton BOIL04 08/27/09 01:00 11.26836757 4.867131328normal 0.4319287 no TXDibollTemple-Inland PB-44 10/06/2009 0000-0100 27.5530781 11.93160631 0.43304078 no VAPhilipMorrisPark500 B3 11/13/2009 9:00:00 AM 1.014729581 0.439682226 Normal 0.4332999no VAPhilipMorrisPark500 B3 11/12/2009 8:00:00 PM 1.009714929 0.437509377 Normal 0.4332999no VAPhilipMorrisPark500 B3 11/12/2009 9:00:00 PM 1.009714929 0.437509377 Normal 0.4332999no VAPhilipMorrisPark500 B3 11/13/2009 3:00:00 AM 1.009714929 0.437509377 Normal 0.4332999no VAPhilipMorrisPark500 B3 11/12/2009 6:00:00 PM 1.055923117 0.457531381 Normal 0.4332999no VAPhilipMorrisPark500 B3 11/12/2009 3:00:00 PM 1.091605839 0.472992701 Normal 0.4332999no VAPhilipMorrisPark500 B3 11/12/2009 5:00:00 PM 1.091605839 0.472992701 Normal 0.4332999no VAPhilipMorrisPark500 B3 11/12/2009 2:00:00 PM 1.099033751 0.476211214 Normal 0.4332999no VAPhilipMorrisPark500 B3 11/12/2009 4:00:00 PM 1.099033751 0.476211214 Normal 0.4332999no VAPhilipMorrisPark500 B3 11/12/2009 1:00:00 PM 1.106563442 0.479473828 Normal 0.4332999no VAPhilipMorrisPark500 B3 10/18/2009 5:00:00 PM 2.492013519 1.079789208 Normal 0.4332999no VAPhilipMorrisPark500 B3 10/19/2009 11:00:00 PM 2.594150257 1.124045046 Normal 0.4332999no VAPhilipMorrisPark500 B3 11/12/2009 10:00:00 PM 1.003441849 0.434791252 Normal 0.4332999no



### Appendix D-4, p30 of 82

## Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC

(ppm@3%O2) CombUnit_O

p_Indicator THC_Op_Ind

icator CO_Op_Indi

cator TNMOC TO

THC Ratio Outlier VAPhilipMorrisPark500 B3 11/12/2009 11:00:00 PM 1.003441849 0.434791252 Normal 0.4332999no VAPhilipMorrisPark500 B3 11/13/2009 1.003441849 0.434791252 Normal 0.4332999no VAPhilipMorrisPark500 B3 11/13/2009 4:00:00 AM 1.003441849 0.434791252 Normal 0.4332999no VAPhilipMorrisPark500 B3 11/13/2009 5:00:00 AM 1.003441849 0.434791252 Normal 0.4332999no VAPhilipMorrisPark500 B3 11/13/2009 6:00:00 AM 1.003441849 0.434791252 Normal 0.4332999no VAPhilipMorrisPark500 B3 11/13/2009 7:00:00 AM 1.003441849 0.434791252 Normal 0.4332999no VAPhilipMorrisPark500 B3 11/13/2009 8:00:00 AM 1.003441849 0.434791252 Normal 0.4332999no VAPhilipMorrisPark500 B3 11/12/2009 7:00:00 PM 1.016066935 0.440261701 Normal 0.4332999no VAPhilipMorrisPark500 B3 10/19/2009 2:00:00 AM 2.654485033 1.150188099 Normal 0.4332999no ARDomtarIndustries PB1 9/2/2009 6:00:00 PM 4.476715056 1.941033352 Normal 0.4335843 no ARDomtarIndustries PB1 9/5/2009 8:00:00 AM 3.680265827 1.600252935 Normal 0.43481993 no VAPhilipMorrisPark500 B3 10/15/2009 7.673915699 3.33995113 Normal 0.43523427 no
ARDomtarIndustries PB1 9/4/2009 10:00:00 PM 4.792180429 2.092496355 Normal 0.43664807 no ARDomtarIndustries PB1 8/25/2009 4:00:00 AM 1.731263472 0.756746714 Normal 0.43710661 no ARDomtarIndustries PB1 9/4/2009 2:00:00 PM 9.206680807 4.025703102 Normal 0.4372589no ARDomtarIndustries PB1 9/5/2009 2:00:00 AM 4.057816305 1.776065829 Normal 0.43769005no ARDomtarIndustries PB1 8/27/2009 4:00:00 PM 3.905503588 1.710296331 Normal 0.43791954 no ARDomtarIndustries PB1 9/3/2009 5:00:00 PM 3.793144494 1.662854459 Normal 0.43838416 no VAPhilipMorrisPark500 B3 10/18/2009 9:00:00 PM 2.879038973 1.263080889 Normal 0.43871615no VAPhilipMorrisPark500 B3 10/18/2009 10:00:00 PM 2.879038973 1.263080889 Normal 0.43871615no VAPhilipMorrisPark500 B3 10/18/2009 11:00:00 PM 2.339355094 1.026312856 Normal 0.43871615no WABoeingRenton BOIL04 08/25/09 13:00 4.897565313 2.156688336 normal 0.44035928 no WVDuPontWashingtonWorks P05 9/23/2009 4:00:28 PM 0.362094658 0.159613871 0.44080703 no WABoeingRenton BOIL04 08/18/09 00:00 5.106674844 2.25325647 normal 0.44123751 no WABoeingRenton BOIL04 08/16/09 09:00 4.316907216 1.91107511 normal 0.44269543 no VAPhilipMorrisPark500 B3 10/29/2009 8:00:00 PM 1.571571189 0.696438039 Normal 0.44314762 no VAPhilipMorrisPark500 B3 10/29/2009 9:00:00 PM 1.584236444 0.702050617 Normal 0.44314762 no WABoeingRenton BOIL04 08/23/09 11:00 0.121063412 0.053648964 normal 0.44314762 no VAPhilipMorrisPark500 B3 11/13/2009 1:00:00 PM 1.224897804 0.542810552 Normal 0.44314762 no VAPhilipMorrisPark500 B3 10/29/2009 1:00:00 PM 1.597106203 0.70775382 Normal 0.44314762 no



### Appendix D-4, p31 of 82

## Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC

(ppm@3%O2) CombUnit_O

p_Indicator THC_Op_Ind

icator CO_Op_Indi

cator TNMOC TO

THC Ratio Outlier WABoeingRenton BOIL04 08/24/09 23:00 1.692811466 0.75016538 normal 0.44314762 no VAPhilipMorrisPark500 B3 10/29/2009 4:00:00 PM 1.610188086 0.713551026 Normal 0.44314762 no VAPhilipMorrisPark500 B3 10/29/2009 5:00:00 PM 1.610188086 0.713551026 Normal 0.44314762 no VAPhilipMorrisPark500 B3 10/29/2009 6:00:00 PM 1.610188086 0.713551026 Normal 0.44314762 no TXDibollTemple-Inland PB-44 2000-2100 2.701142765 1.199937593 0.44423331 no VAPhilipMorrisPark500 B3 10/16/2009 11:00:00 AM 4.701696656 2.095451681 Normal 0.4456799no ARDomtarIndustries PB1 9/4/2009 8:00:00 PM 5.171991491 2.311547013 Normal 0.44693558 no
ARDomtarIndustries PB1 8/25/2009 11:00:00 AM 1.608670205 0.719960412 Normal 0.44755004 no WABoeingRenton BOIL04 08/26/09 05:00 5.672017641 2.539845645normal 0.44778522 no ARDomtarIndustries PB1 8/25/2009 8:00:00 AM 1.79819091 0.807786832 Normal 0.44922195no ARDomtarIndustries PB1 8/27/2009 5:00:00 AM 2.828591436 1.27150464 Normal 0.44951866 no VAPhilipMorrisPark500 B3 10/29/2009 8:00:00 AM 1.887489149 0.849304584 Normal 0.44996528 no VAPhilipMorrisPark500 B3 10/29/2009 11:00:00 AM 1.887489149 0.849304584 Normal 0.44996528 no ARDomtarIndustries PB1 9/5/2009 7:00:00 AM 4.311867583 1.942708701 Normal 0.45054925no WABoeingRenton BOIL04 08/26/09 12:00 7.254672692 3.269281876 normal 0.45064499 no
ARDomtarIndustries PB1 9/4/2009 11:00:00 PM 3.954757837 1.785897825 Normal 0.45158209 no WABoeingRenton BOIL04 08/18/09 13:00 4.034167585 1.821830209normal 0.45160003 no ARDomtarIndustries PB1 9/2/2009 2:00:00 AM 5.240523992 2.36863602 Normal 0.45198458 no ARDomtarIndustries PB1 8/31/2009 9:00:00 AM 8.538647664 3.863767264 Normal 0.45250342 no ARDomtarIndustries PB1 8/26/2009 2:00:00 PM 1.392389887 0.630597609 Normal 0.45288867 no WVDuPontWashingtonWorks P05 9/23/2009 5:00:29 PM 0.29538388 0.134058288 0.45384429 no WVDuPontWashingtonWorks P05 10/7/2009 2:00:29 PM 0.381995185 0.173416516 0.45397566 no ARDomtarIndustries PB1 8/25/2009 7:00:00 AM 1.947086878 0.884868571 Normal 0.45445767 no VAPhilipMorrisPark500 B3 10/19/2009 6:00:00 AM 2.076677932 0.944815557 Normal 0.45496489 no VAPhilipMorrisPark500 B3 10/20/2009 2:00:00 AM 2.128034657 0.968181064 Normal 0.45496489 no VAPhilipMorrisPark500 B3 10/29/2009 3:00:00 AM 2.160322423 0.982870864 Normal 0.45496489 no VAPhilipMorrisPark500 B3 10/29/2009 2:00:00 AM 2.177872095 0.990855348 Normal 0.45496489 no TXDibollTemple-Inland PB-44 1200-1300 3.309469293 1.506203991 0.45511949 no WABoeingRenton BOIL04 10/06/09 21:00 1.500428415 0.683354083 normal 0.45543931 no TXDibollTemple-Inland PB-44 0100-0200 13.04940847 5.944457589 0.45553464 no TXDibollTemple-Inland PB-44 1300-1400 2.620568756 1.195643665 0.4562535no VAPhilipMorrisPark500 B3 10/20/2009 2.430750207 1.11519934 Normal 0.45878813 no 

### Appendix D-4, p32 of 82

## Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC

(ppm@3%O2) CombUnit_O

p_Indicator THC_Op_Ind

icator CO_Op_Indi

cator TNMOC TO

THC Ratio Outlier VAPhilipMorrisPark500 B3 10/19/2009 3:00:00 AM 2.527611916 1.159638342 Normal 0.45878813 no
WVDuPontWashingtonWorks P05 9/25/2009 12:00:08 PM 0.143844181 0.066008225 0.45888701 no TXDibollTemple-Inland PB-44 0100-0200 24.76591985 11.37494772 0.45929841 no
ARDomtarIndustries PB1 9/5/2009 10:00:00 AM 3.507703085 1.613043644 Normal 10:09 - 10:59 calibration 10:09 - 10:59

calibration 0.45985752 no WABoeingRenton BOIL04 08/12/09 05:00 4.006098369 1.845524347 normal 0.46067874 no WABoeingRenton BOIL04 08/27/09 12:00 7.32891625 3.380611971 normal 0.46127038 no VAPhilipMorrisPark500 B3 10/20/2009 10:00:00 AM 2.727451614 1.259554808 Normal 0.46180647 no VAPhilipMorrisPark500 B3 10/18/2009 6:00:00 PM 2.630458714 1.214762859 Normal 0.46180647 no WABoeingRenton BOIL04 08/26/09 09:00 4.819707574 2.226335495normal 0.46192336 no ARDomtarIndustries PB1 8/29/2009 5:00:00 PM 4.701176253 2.173714174 Normal 0.46237666 no TXDibollTemple-Inland PB-44 10/31/2009 0000-0100 2.561600152 1.187804948 0.46369647 no WABoeingRenton BOIL04 09/26/09 13:00 1.227095486 0.57169551 normal 0.46589325no
ARDomtarIndustries PB1 8/26/2009 10:00:00 AM 0.959834176 0.447599039 Normal 10:14 - 10:59 calibration 10:14 - 10:59

calibration 0.46632955no
ARDomtarIndustries PB1 9/6/2009 10:00:00 AM 6.78712577 3.167564957 Normal 10:07 - 10:59 calibration 10:07 - 10:59

calibration 0.46670197 no ARDomtarIndustries PB1 8/27/2009 9:00:00 PM 2.198450817 1.02626186 Normal 0.46681138 no ARDomtarIndustries PB1 9/2/2009 8.974333174 4.190835157 Normal 0.46698012 no ARDomtarIndustries PB1 8/26/2009 3:00:00 AM 1.38365131 0.649123163 Normal 0.46913782 no ARDomtarIndustries PB1 8/25/2009 6:00:00 AM 2.049063938 0.962032307 Normal 0.46949843 no VAPhilipMorrisPark500 B3 9/21/2009 11:00:00 AM 11.30927529 5.32274818 Normal 0.47065334 no ARDomtarIndustries PB1 8/25/2009 9:00:00 AM 1.82454141 0.8597234 Normal 0.47119972 no ARDomtarIndustries PB1 8/26/2009 8:00:00 AM 1.072712071 0.506113726 Normal 0.47180762 no ARDomtarIndustries PB1 8/27/2009 9:00:00 AM 1.682747611 0.795090603 Normal 0.47249546 no
ARDomtarIndustries PB1 9/5/2009 12:00:00 PM 3.206272218 1.516811314 Normal 0.47307627 no WABoeingRenton BOIL04 08/25/09 15:00 5.336608503 2.526148931 normal 0.47336224 no ARDomtarIndustries PB1 8/15/2009 7:00:00 PM 4.304946566 2.040170756 Normal 0.47391314 no WABoeingRenton BOIL04 08/17/09 06:00 3.431694043 1.629928904 normal 0.47496335no ARDomtarIndustries PB1 8/15/2009 5:00:00 PM 3.434277843 1.634227052 Normal 0.47585755no ARDomtarIndustries PB1 9/1/2009 8:00:00 AM 4.51505871 2.15299057 Normal 0.47684664 no ARDomtarIndustries PB1 8/26/2009 1:00:00 PM 1.540178398 0.734447159 Normal 0.4768585no



### Appendix D-4, p33 of 82

## Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC

(ppm@3%O2) CombUnit_O

p_Indicator THC_Op_Ind

icator CO_Op_Indi

cator TNMOC TO

THC Ratio Outlier ARDomtarIndustries PB1 9/3/2009 6:00:00 PM 3.357689996 1.602915167 Normal 0.47738629 no
ARDomtarIndustries PB1 8/18/2009 11:00:00 AM 4.292289966 2.054672281 Normal 0.47868907 no ARDomtarIndustries PB1 9/4/2009 1:00:00 PM 6.296426968 3.017706994 Normal 0.47927293 no ARDomtarIndustries PB1 8/26/2009 9:00:00 PM 1.503280412 0.721759376 Normal 0.48012292 no WABoeingRenton BOIL04 10/06/09 07:00 0.738745392 0.354735807 normal 0.48018683 no WABoeingRenton BOIL04 08/14/09 17:00 3.105530191 1.492356406 normal 0.48054803 no WABoeingRenton BOIL04 08/22/09 08:00 0.849005898 0.408483657 normal 0.48113171 no ARDomtarIndustries PB1 9/5/2009 6:00:00 PM 2.063694356 0.993968155 Normal 0.48164504 no ARDomtarIndustries PB1 9/3/2009 8:00:00 AM 5.432720933 2.620617613 Normal 0.48237663 no WABoeingRenton BOIL04 09/21/09 10:00 22.43777948 10.82948458normal 0.48264511 no WABoeingRenton BOIL04 08/12/09 14:00 12.59949096 6.087997049normal 0.48319389 no WABoeingRenton BOIL04 08/22/09 14:00 2.170798232 1.052811003 normal 0.48498796 no ARDomtarIndustries PB1 9/5/2009 3:00:00 AM 4.36727732 2.126969504 Normal 0.48702415no VAPhilipMorrisPark500 B3 10/19/2009 4:00:00 AM 2.340469062 1.140890636 Normal 0.48746239 no VAPhilipMorrisPark500 B3 11/2/2009 10:00:00 AM 0.568331796 0.277040374 Normal 0.48746239 no VAPhilipMorrisPark500 B3 11/2/2009 12:00:00 PM 0.568331796 0.277040374 Normal 0.48746239 no VAPhilipMorrisPark500 B3 10/29/2009 6:00:00 AM 1.728257939 0.84246074 Normal 0.48746239 no VAPhilipMorrisPark500 B3 10/29/2009 12:00:00 PM 1.728257939 0.84246074 Normal 0.48746239 no VAPhilipMorrisPark500 B3 10/20/2009 4:00:00 AM 1.98616568 0.968181064 Normal 0.48746239 no VAPhilipMorrisPark500 B3 10/29/2009 4:00:00 AM 2.016300928 0.982870864 Normal 0.48746239 no VAPhilipMorrisPark500 B3 10/29/2009 9:00:00 AM 2.016300928 0.982870864 Normal 0.48746239 no VAPhilipMorrisPark500 B3 10/19/2009 5:00:00 AM 2.198304968 1.071590987 Normal 0.48746239 no VAPhilipMorrisPark500 B3 10/18/2009 4:00:00 PM 2.473093089 1.205539861 Normal 0.48746239 no VAPhilipMorrisPark500 B3 10/17/2009 2:00:00 PM 2.879038973 1.40342321 Normal 0.48746239 no VAPhilipMorrisPark500 B3 10/17/2009 3:00:00 PM 2.879038973 1.40342321 Normal 0.48746239 no WABoeingRenton BOIL04 10/07/09 01:00 3.142677855 1.531937249normal 0.48746239 no WABoeingRenton BOIL04 08/19/09 20:00 0.17512564 0.085367163 normal 0.48746239 no VAPhilipMorrisPark500 B3 10/31/2009 9:00:00 PM 0.286083214 0.139454806 Normal 0.48746239 no VAPhilipMorrisPark500 B3 11/3/2009 9:00:00 AM 0.522975241 0.25493076 Normal 0.48746239 no



### Appendix D-4, p34 of 82

## Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC

(ppm@3%O2) CombUnit_O

p_Indicator THC_Op_Ind

icator CO_Op_Indi

cator TNMOC TO

THC Ratio Outlier VAPhilipMorrisPark500 B3 11/3/2009 10:00:00 AM 0.522975241 0.25493076 Normal 0.48746239 no VAPhilipMorrisPark500 B3 11/2/2009 3:00:00 AM 0.565406427 0.275614367 Normal 0.48746239 no VAPhilipMorrisPark500 B3 11/2/2009 4:00:00 AM 0.565406427 0.275614367 Normal 0.48746239 no VAPhilipMorrisPark500 B3 11/2/2009 8:00:00 AM 0.565406427 0.275614367 Normal 0.48746239 no VAPhilipMorrisPark500 B3 11/2/2009 1:00:00 PM 0.572848586 0.279242139 Normal 0.48746239 no VAPhilipMorrisPark500 B3 11/2/2009 2:00:00 PM 0.572848586 0.279242139 Normal 0.48746239 no VAPhilipMorrisPark500 B3 10/30/2009 10:00:00 AM 1.413516068 0.689035917 Normal 0.48746239 no VAPhilipMorrisPark500 B3 10/29/2009 11:00:00 PM 1.417369849 0.69091449 Normal 0.48746239 no VAPhilipMorrisPark500 B3 10/30/2009 1.417369849 0.69091449 Normal 0.48746239 no VAPhilipMorrisPark500 B3 10/29/2009 7:00:00 AM 1.742297676 0.849304584 Normal 0.48746239 no VAPhilipMorrisPark500 B3 10/29/2009 2:00:00 PM 1.742297676 0.849304584 Normal 0.48746239 no VAPhilipMorrisPark500 B3 10/29/2009 3:00:00 PM 1.742297676 0.849304584 Normal 0.48746239 no VAPhilipMorrisPark500 B3 10/29/2009 7:00:00 PM 1.742297676 0.849304584 Normal 0.48746239 no VAPhilipMorrisPark500 B3 11/3/2009 6:00:00 AM 0.519208111 0.253094425 Normal 0.48746239 no VAPhilipMorrisPark500 B3 11/3/2009 8:00:00 AM 0.52679705 0.256793747 Normal 0.48746239 no VAPhilipMorrisPark500 B3 11/2/2009 0.569895205 0.277802477 Normal 0.48746239 no VAPhilipMorrisPark500 B3 11/2/2009 1:00:00 AM 0.569895205 0.277802477 Normal 0.48746239 no VAPhilipMorrisPark500 B3 11/1/2009 4:00:00 PM 0.8975992 0.437545849 Normal 0.48746239 no VAPhilipMorrisPark500 B3 11/1/2009 5:00:00 PM 0.8975992 0.437545849 Normal 0.48746239 no VAPhilipMorrisPark500 B3 10/20/2009 1:00:00 AM 1.976669822 0.96355219 Normal 0.48746239 no VAPhilipMorrisPark500 B3 10/20/2009 8:00:00 AM 2.001794288 0.975799422 Normal 0.48746239 no VAPhilipMorrisPark500 B3 10/17/2009 4:00:00 PM 2.85631749 1.392347342 Normal 0.48746239 no VAPhilipMorrisPark500 B3 10/19/2009 11:00:00 AM 3.026592266 1.475349891 Normal 0.48746239 no VAPhilipMorrisPark500 B3 10/29/2009 2.304343918 1.123280987 Normal 0.48746239 no VAPhilipMorrisPark500 B3 10/29/2009 1:00:00 AM 2.304343918 1.123280987 Normal 0.48746239 no VAPhilipMorrisPark500 B3 10/17/2009 5:00:00 PM 2.833949598 1.381443836 Normal 0.48746239 no VAPhilipMorrisPark500 B3 11/3/2009 1:00:00 AM 0.508226178 0.247741146 Normal 0.48746239 no VAPhilipMorrisPark500 B3 11/3/2009 3:00:00 AM 0.508226178 0.247741146 Normal 0.48746239 no VAPhilipMorrisPark500 B3 11/3/2009 4:00:00 AM 0.508226178 0.247741146 Normal 0.48746239 no VAPhilipMorrisPark500 B3 11/3/2009 5:00:00 AM 0.508226178 0.247741146 Normal 0.48746239 no WABoeingRenton BOIL04 08/18/09 12:00 3.917046955 1.914761555normal 0.48882783 no



### Appendix D-4, p35 of 82

## Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC

(ppm@3%O2) CombUnit_O

p_Indicator THC_Op_Ind

icator CO_Op_Indi

cator TNMOC TO

THC Ratio Outlier ARDomtarIndustries PB1 9/5/2009 3:00:00 PM 4.650571103 2.274461707 Normal 0.48907148 no TXDibollTemple-Inland PB-44 0800-0900 2.36535523 1.156992656 0.48914118 no ARDomtarIndustries PB1 9/4/2009 3:00:00 PM 4.390954824 2.152713099 Normal 0.49026082 no WABoeingRenton BOIL04 10/05/09 18:00 1.884296942 0.92389537 normal 0.49031304 no ARDomtarIndustries PB1 9/5/2009 6:00:00 AM 4.099711721 2.011559308 Normal 0.49065872 no ARDomtarIndustries PB1 9/7/2009 7:00:00 PM 2.44254751 1.199673423 Normal 0.49115664 no ARDomtarIndustries PB1 8/24/2009 5:00:00 PM 3.58088051 1.762930141 Normal 0.4923175no WABoeingRenton BOIL04 09/21/09 08:00 23.00142095 11.3315525normal 0.49264576 no WABoeingRenton BOIL04 08/18/09 09:00 5.158540083 2.541402304 normal 0.49265921 no ARDomtarIndustries PB1 9/3/2009 7:00:00 PM 2.891190305 1.427026507 Normal 0.49357751 no ARDomtarIndustries PB1 9/5/2009 7:00:00 PM 4.04661955 1.9986158 Normal 0.49389763 no ARDomtarIndustries PB1 9/5/2009 1:00:00 AM 4.417065025 2.182628756 Normal 0.49413553 no WABoeingRenton BOIL04 09/21/09 11:00 23.98994587 11.87949165normal 0.49518626 no TXDibollTemple-Inland PB-44 1900-2000 2.763938451 1.368968388 0.49529626 no ARDomtarIndustries PB1 9/3/2009 7:00:00 AM 5.564962588 2.775868485 Normal 0.49881171 no WABoeingRenton BOIL04 08/26/09 08:00 4.361570591 2.179521251 normal 0.49971019 no ARDomtarIndustries PB1 9/5/2009 3.826292922 1.914766109 Normal 0.50042329 no ARDomtarIndustries PB1 9/5/2009 4:00:00 AM 3.648142336 1.829280003 Normal 0.5014278no WABoeingRenton BOIL04 09/21/09 09:00 15.65330173 7.879213084 normal 0.5033579no WABoeingRenton BOIL04 08/12/09 22:00 4.028109898 2.027930823 normal 0.50344476 no ARDomtarIndustries PB1 8/18/2009 8:00:00 PM 5.650159786 2.845310319 Normal 0.50358051 no WABoeingRenton BOIL04 09/21/09 04:00 36.32229901 18.33296192 normal 0.50473022 no ARDomtarIndustries PB1 8/29/2009 7:00:00 AM 3.576111038 1.805485864 Normal 0.50487411 no WABoeingRenton BOIL04 08/22/09 13:00 2.038566867 1.031325064 normal 0.50590691 no ARDomtarIndustries PB1 8/17/2009 7:00:00 AM 6.01969259 3.05514718 Normal 0.50752545no WABoeingRenton BOIL04 08/26/09 06:00 3.125637189 1.588009322 normal 0.50805939 no WABoeingRenton BOIL04 08/16/09 06:00 2.274009549 1.15668952 normal 0.5086564 no TXDibollTemple-Inland PB-44 0200-0300 4.581152492 2.333462727 0.5093615no ARDomtarIndustries PB1 9/5/2009 2:00:00 PM 2.604933979 1.33177384 Normal 0.51125052 no ARDomtarIndustries PB1 8/29/2009 4:00:00 AM 3.687667367 1.885446084 Normal 0.51128421 no ARDomtarIndustries PB1 8/26/2009 7:00:00 AM 1.250486043 0.640218678 Normal 0.51197587 no ARDomtarIndustries PB1 8/29/2009 6:00:00 PM 5.032590102 2.578809853 Normal 0.51242199 no VAPhilipMorrisPark500 B3 10/17/2009 12:00:00 PM 2.713501615 1.392347342 Normal 0.5131183 no



### Appendix D-4, p36 of 82

## Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC

(ppm@3%O2) CombUnit_O

p_Indicator THC_Op_Ind

icator CO_Op_Indi

cator TNMOC TO

THC Ratio Outlier VAPhilipMorrisPark500 B3 10/17/2009 7:00:00 PM 2.713501615 1.392347342 Normal 0.5131183 no VAPhilipMorrisPark500 B3 10/28/2009 10:00:00 PM 2.851298861 1.463053631 Normal 0.5131183 no ARDomtarIndustries PB1 8/15/2009 4:00:00 PM 4.133844896 2.122558555 Normal 0.51345868 no WABoeingRenton BOIL04 09/21/09 07:00 27.23265234 13.98770902 normal 0.51363741 no WABoeingRenton BOIL04 08/27/09 07:00 6.093048363 3.130390816 normal 0.51376431 no WABoeingRenton BOIL04 09/21/09 05:00 21.64213762 11.12892882 normal 0.51422503 no ARDomtarIndustries PB1 8/26/2009 6:00:00 PM 1.869585924 0.96246055 Normal 0.51479878 no WVDuPontWashingtonWorks P05 9/23/2009 7:00:30 PM 0.293243022 0.150974665 0.51484487 no ARDomtarIndustries PB1 8/27/2009 2:00:00 PM 1.250738201 0.644284192 Normal 0.51512314 no
ARDomtarIndustries PB1 8/31/2009 10:00:00 AM 24.57045371 12.6700651 Normal 0.51566264 no VAPhilipMorrisPark500 B3 10/28/2009 11:00:00 PM 2.428791838 1.253588471 Normal 0.51613665no VAPhilipMorrisPark500 B3 10/17/2009 8:00:00 AM 2.371713145 1.224128066 Normal 0.51613665no VAPhilipMorrisPark500 B3 10/17/2009 10:00:00 AM 2.390141787 1.233639764 Normal 0.51613665no VAPhilipMorrisPark500 B3 10/18/2009 2:00:00 PM 2.447183127 1.263080889 Normal 0.51613665no VAPhilipMorrisPark500 B3 10/19/2009 10:00:00 AM 2.253425209 1.163075328 Normal 0.51613665no ARDomtarIndustries PB1 8/31/2009 5:00:00 PM 5.605484352 2.898738764 Normal 0.51712548 no
ARDomtarIndustries PB1 8/18/2009 10:00:00 PM 4.763975499 2.474345898 Normal 0.51938678 no WABoeingRenton BOIL04 10/06/09 04:00 1.157024438 0.601606288normal 0.51995988 no VAPhilipMorrisPark500 B3 10/19/2009 9:00:00 AM 2.060910907 1.071590987 Normal 0.51995988 no VAPhilipMorrisPark500 B3 10/19/2009 7:00:00 AM 2.076677932 1.079789208 Normal 0.51995988 no VAPhilipMorrisPark500 B3 10/19/2009 8:00:00 AM 2.092688069 1.088113837 Normal 0.51995988 no VAPhilipMorrisPark500 B3 10/20/2009 3:00:00 AM 2.144779594 1.11519934 Normal 0.51995988 no VAPhilipMorrisPark500 B3 10/29/2009 10:00:00 AM 2.177872095 1.132406112 Normal 0.51995988 no ARDomtarIndustries PB1 9/7/2009 8:00:00 PM 1.907923469 0.995051979 Normal 0.52153663 no ARDomtarIndustries PB1 8/31/2009 4:00:00 AM 4.819830271 2.513965836 Normal 0.52158804 no WABoeingRenton BOIL04 10/06/09 18:00 1.91426917 1.002452761 normal 0.52367388 no VAPhilipMorrisPark500 B3 10/29/2009 5:00:00 AM 1.872279433 0.982870864 Normal 0.52495949 no VAPhilipMorrisPark500 B3 10/20/2009 7:00:00 AM 1.873552963 0.983539415 Normal 0.52495949 no



### Appendix D-4, p37 of 82

## Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC

(ppm@3%O2) CombUnit_O

p_Indicator THC_Op_Ind

icator CO_Op_Indi

cator TNMOC TO

THC Ratio Outlier VAPhilipMorrisPark500 B3 10/17/2009 7:00:00 AM 1.813662993 0.952099607 Normal 0.52495949 no VAPhilipMorrisPark500 B3 10/16/2009 7:00:00 PM 3.627325986 1.904199214 Normal 0.52495949 no TXDibollTemple-Inland PB-44 0200-0300 3.140507554 1.650940851 0.52569237 no ARDomtarIndustries PB1 8/31/2009 7:00:00 AM 6.637622743 3.494755564 Normal 0.52650711 no WVDuPontWashingtonWorks P05 9/22/2009 3:00:05 PM 0.553685529 0.291556734 0.5265746 no
ARDomtarIndustries PB1 8/27/2009 10:00:00 AM 1.598773192 0.841989851 Normal 10:09 - 10:53 calibration 10:09 - 10:53

calibration 0.52664747 no WABoeingRenton BOIL04 09/21/09 03:00 32.7873821 17.28406445normal 0.52715598 no ARDomtarIndustries PB1 8/24/2009 3:00:00 PM 3.900395641 2.059269635 Normal 0.5279643 no WABoeingRenton BOIL04 09/27/09 01:00 0.902957081 0.47727934 normal 0.52857367 no
ARDomtarIndustries PB1 8/30/2009 11:00:00 AM 3.573853579 1.892008882 Normal 0.52940302 no ARDomtarIndustries PB1 8/31/2009 5:00:00 AM 6.460808021 3.42476087 Normal 0.53008244 no WABoeingRenton BOIL04 08/24/09 22:00 1.494950386 0.793031974 normal 0.53047377 no TXDibollTemple-Inland PB-44 0900-1000 4.386001526 2.328824927 0.53096765no TXDibollTemple-Inland PB-44 0700-0800 3.102529551 1.649832911 0.53177025no VAPhilipMorrisPark500 B3 10/29/2009 10:00:00 PM 1.571571189 0.835725647 Normal 0.53177715no ARDomtarIndustries PB1 9/1/2009 1:00:00 AM 4.616320427 2.45898487 Normal 0.53267205no
ARDomtarIndustries PB1 8/26/2009 12:00:00 PM 1.406515737 0.750718098 Normal 0.53374312 no ARDomtarIndustries PB1 8/17/2009 9:00:00 AM 4.376462819 2.339714067 Normal 0.53461303 no WABoeingRenton BOIL04 09/21/09 06:00 10.84648352 5.798922368normal 0.53463617 no ARDomtarIndustries PB1 8/25/2009 3:00:00 AM 1.585007656 0.848562751 Normal 0.53536823 no ARDomtarIndustries PB1 9/2/2009 1:00:00 AM 5.522710662 2.961143582 Normal 0.53617576 no VAPhilipMorrisPark500 B3 10/17/2009 1:00:00 PM 2.879038973 1.543765531 Normal 0.53620863 no VAPhilipMorrisPark500 B3 10/17/2009 6:00:00 PM 2.833949598 1.51958822 Normal 0.53620863 no ARDomtarIndustries PB1 8/26/2009 5:00:00 AM 1.128909196 0.606286283 Normal 0.53705496 no ARDomtarIndustries PB1 8/31/2009 1:00:00 AM 5.325738436 2.868645832 Normal 0.53863814 no ARDomtarIndustries PB1 9/4/2009 5.013967224 2.705959476 Normal 0.53968432 no TXDibollTemple-Inland PB-44 0700-0800 3.098862227 1.675262789 0.54060577 no ARDomtarIndustries PB1 9/2/2009 3:00:00 AM 3.983868457 2.155038008 Normal 0.54094106 no VAPhilipMorrisPark500 B3 10/30/2009 8:00:00 AM 1.285830973 0.696438039 Normal 0.54162487 no VAPhilipMorrisPark500 B3 10/17/2009 11:00:00 AM 2.550554638 1.381443836 Normal 0.54162487 no VAPhilipMorrisPark500 B3 10/17/2009 8:00:00 PM 2.550554638 1.381443836 Normal 0.54162487 no



### Appendix D-4, p38 of 82

## Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC

(ppm@3%O2) CombUnit_O

p_Indicator THC_Op_Ind

icator CO_Op_Indi

cator TNMOC TO

THC Ratio Outlier VAPhilipMorrisPark500 B3 10/30/2009 3:00:00 AM 1.265595248 0.685477868 Normal 0.54162487 no VAPhilipMorrisPark500 B3 10/30/2009 1:00:00 AM 1.275632864 0.69091449 Normal 0.54162487 no VAPhilipMorrisPark500 B3 10/30/2009 2:00:00 AM 1.275632864 0.69091449 Normal 0.54162487 no VAPhilipMorrisPark500 B3 10/30/2009 4:00:00 AM 1.275632864 0.69091449 Normal 0.54162487 no VAPhilipMorrisPark500 B3 10/30/2009 5:00:00 AM 1.275632864 0.69091449 Normal 0.54162487 no VAPhilipMorrisPark500 B3 10/30/2009 6:00:00 AM 1.275632864 0.69091449 Normal 0.54162487 no VAPhilipMorrisPark500 B3 10/30/2009 7:00:00 AM 1.275632864 0.69091449 Normal 0.54162487 no VAPhilipMorrisPark500 B3 10/30/2009 9:00:00 AM 1.282264211 0.694506192 Normal 0.54162487 no VAPhilipMorrisPark500 B3 10/30/2009 11:00:00 AM 1.282264211 0.694506192 Normal 0.54162487 no VAPhilipMorrisPark500 B3 10/18/2009 3:00:00 PM 2.570685741 1.392347342 Normal 0.54162487 no VAPhilipMorrisPark500 B3 10/20/2009 9:00:00 AM 2.573735513 1.393999175 Normal 0.54162487 no ARDomtarIndustries PB1 8/29/2009 4:00:00 PM 5.284148302 2.862228057 Normal 0.54166308 no TXDibollTemple-Inland PB-44 1900-2000 1.682230176 0.911370602 0.54176332 no ARDomtarIndustries PB1 8/31/2009 6:00:00 AM 5.960540726 3.245210093 Normal 0.54444894 no VAPhilipMorrisPark500 B3 9/17/2009 5:00:00 PM 4.451435129 2.425190394 Normal 0.5448109no ARDomtarIndustries PB1 9/1/2009 9:00:00 AM 4.025544476 2.193852653 Normal 0.54498284 no TXDibollTemple-Inland PB-44 0200-0300 2.717284004 1.483417696 0.54591927 no WABoeingRenton BOIL04 08/26/09 10:00 3.576911225 1.957549523 normal 0.54727372 no ARDomtarIndustries PB1 8/28/2009 1:00:00 AM 1.962310324 1.075181032 Normal 0.5479159no VAPhilipMorrisPark500 B3 10/18/2009 1:00:00 PM 2.285053992 1.253112608 Normal 0.54839519 no ARDomtarIndustries PB1 8/25/2009 1:00:00 AM 1.816624515 0.997730554 Normal 0.54922222 no ARDomtarIndustries PB1 8/26/2009 9:00:00 AM 0.948587949 0.521526185 Normal 0.54979213 no WABoeingRenton BOIL04 08/17/09 22:00 3.677908969 2.02296831 normal 0.55003219 no WABoeingRenton BOIL04 08/11/09 05:00 1.18426494 0.652117805normal 0.55065196 no ARDomtarIndustries PB1 8/26/2009 7:00:00 PM 2.250954233 1.239493334 Normal 0.55065239 no TXDibollTemple-Inland PB-44 1600-1700 2.475109274 1.363379121 0.55083593 no
ARDomtarIndustries PB1 8/14/2009 11:00:00 AM 3.724359735 2.05278474 Normal 0.55117789 no WABoeingRenton BOIL04 08/13/09 21:00 2.175139569 1.199529873 normal 0.5514726 no ARDomtarIndustries PB1 8/26/2009 6:00:00 AM 1.205508013 0.66491339 Normal 0.55156281 no ARDomtarIndustries PB1 8/25/2009 7:00:00 PM 1.656474275 0.915588662 Normal 0.5527334 no ARDomtarIndustries PB1 8/26/2009 4:00:00 AM 1.270097948 0.702268987 Normal 0.55292506 no ARDomtarIndustries PB1 8/29/2009 7:00:00 PM 3.958864065 2.193881075 Normal 0.55416934 no



### Appendix D-4, p39 of 82

## Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC

(ppm@3%O2) CombUnit_O

p_Indicator THC_Op_Ind

icator CO_Op_Indi

cator TNMOC TO

THC Ratio Outlier WABoeingRenton BOIL04 08/17/09 18:00 3.767499085 2.092771878normal 0.55548039 no
ARDomtarIndustries PB1 9/2/2009 12:00:00 PM 2.422052224 1.346117191 Normal 0.55577546 no WVDuPontWashingtonWorks P05 9/23/2009 6:00:29 PM 0.287996148 0.160136688 0.5560376 no WABoeingRenton BOIL04 08/16/09 11:00 2.876032175 1.600702444 normal 0.55656625no VAPhilipMorrisPark500 B3 11/1/2009 3:00:00 PM 1.047199066 0.583394465 Normal 0.55709987 no WABoeingRenton BOIL04 08/22/09 03:00 0.615945085 0.343142927 normal 0.55709987 no VAPhilipMorrisPark500 B3 10/20/2009 5:00:00 AM 2.017672422 1.124045046 Normal 0.55709987 no VAPhilipMorrisPark500 B3 10/20/2009 6:00:00 AM 2.017672422 1.124045046 Normal 0.55709987 no VAPhilipMorrisPark500 B3 10/16/2009 5:00:00 PM 2.88527527 1.607386481 Normal 0.55709987 no VAPhilipMorrisPark500 B3 10/30/2009 10:00:00 PM 1.038541667 0.578571429 Normal 0.55709987 no WABoeingRenton BOIL04 08/25/09 04:00 1.389282379 0.773969034 normal 0.55709987 no WABoeingRenton BOIL04 08/26/09 14:00 7.393277424 4.123383937 normal 0.55772071 no
ARDomtarIndustries PB1 8/18/2009 10:00:00 AM 4.472604851 2.497481577 Normal 10:04 - 10:57 calibration 10:04 - 10:57

calibration 0.55839531 no ARDomtarIndustries PB1 9/2/2009 9:00:00 AM 3.044005347 1.699908972 Normal 0.5584448no TXDibollTemple-Inland PB-44 1000-1100 2.374852447 1.332908671 0.56125957 no TXDibollTemple-Inland PB-44 2200-2300 2.189601449 1.228955476 0.56126903 no ARDomtarIndustries PB1 8/15/2009 3:00:00 PM 6.077771867 3.415095345 Normal 0.56189923 no ARDomtarIndustries PB1 8/24/2009 6:00:00 PM 2.763250289 1.557905401 Normal 0.56379453 no ARDomtarIndustries PB1 8/16/2009 3:00:00 PM 9.48061389 5.349110514 Normal 0.56421563 no ARDomtarIndustries PB1 9/3/2009 1:00:00 PM 3.69484994 2.084786637 Normal 0.56424122 no VAPhilipMorrisPark500 B3 10/17/2009 1:00:00 AM 2.713501615 1.531582076 Normal 0.56443013 no VAPhilipMorrisPark500 B3 10/17/2009 2.735087024 1.543765531 Normal 0.56443013 no TXDibollTemple-Inland PB-44 1800-1900 3.841889498 2.171449477 0.56520352 no ARDomtarIndustries PB1 8/25/2009 4:00:00 PM 1.65437429 0.936409145 Normal 0.56602013 no TXDibollTemple-Inland PB-44 1000-1100 5.706175912 3.234552581 0.56685119 no WABoeingRenton BOIL04 08/18/09 01:00 2.841779164 1.615245781 normal 0.56839244 no WABoeingRenton BOIL04 08/18/09 15:00 0.264138354 0.150217098normal 0.56870612 no ARDomtarIndustries PB1 9/1/2009 5:00:00 AM 3.606489468 2.05106786 Normal 0.56871589 no
ARDomtarIndustries PB1 8/25/2009 10:00:00 AM 2.104191023 1.197078974 Normal 10:23 - 10:59 calibration 10:23 - 10:59

calibration 0.56890223 no TXDibollTemple-Inland PB-44 2100-2200 1.601612587 0.914290144 0.57085599 no TXDibollTemple-Inland PB-44 0100-0200 8.508901541 4.869083725 0.57223411 no ARDomtarIndustries PB1 8/26/2009 5:00:00 PM 1.669404411 0.957265248 Normal 0.57341723 no



### Appendix D-4, p40 of 82

## Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC

(ppm@3%O2) CombUnit_O

p_Indicator THC_Op_Ind

icator CO_Op_Indi

cator TNMOC TO

THC Ratio Outlier VAPhilipMorrisPark500 B3 10/17/2009 9:00:00 PM 2.427869866 1.392347342 Normal 0.57348516 no VAPhilipMorrisPark500 B3 10/17/2009 10:00:00 PM 2.427869866 1.392347342 Normal 0.57348516 no ARDomtarIndustries PB1 8/25/2009 8:00:00 PM 1.572505805 0.90240263 Normal 0.57386283 no WABoeingRenton BOIL04 08/12/09 23:00 2.705758764 1.554866389normal 0.57465078 no ARDomtarIndustries PB1 8/24/2009 4:00:00 PM 4.306468973 2.479522667 Normal 0.57576699 no VAPhilipMorrisPark500 B3 10/16/2009 4:00:00 PM 2.999890585 1.728212703 Normal 0.57609191 no ARDomtarIndustries PB1 8/15/2009 8:00:00 PM 4.959757275 2.857637792 Normal 0.57616485no TXDibollTemple-Inland PB-44 1215-1315 1.409358893 0.814293374 0.57777574 no ARDomtarIndustries PB1 8/25/2009 5:00:00 AM 2.350606417 1.358599086 Normal 0.57797812 no ARDomtarIndustries PB1 8/31/2009 3:00:00 AM 3.772696358 2.18238727 Normal 0.57846884 no ARDomtarIndustries PB1 9/1/2009 6:00:00 AM 3.922693496 2.269509816 Normal 0.57855905no ARDomtarIndustries PB1 9/2/2009 3:00:00 PM 3.168125389 1.838365837 Normal 0.58026928 no ARDomtarIndustries PB1 8/27/2009 3:00:00 AM 1.741664056 1.013510474 Normal 0.58192076 no ARDomtarIndustries PB1 8/16/2009 5:00:00 AM 6.101981724 3.551691871 Normal 0.58205548 no TXDibollTemple-Inland PB-44 1100-1200 2.927262354 1.705160245 0.58251022 no ARDomtarIndustries PB1 8/30/2009 1:00:00 PM 8.232590583 4.796394467 Normal 0.58261059 no TXDibollTemple-Inland PB-44 2300-2400 1.519478227 0.885987426 0.58308662 no ARDomtarIndustries PB1 8/26/2009 8:00:00 PM 1.727941667 1.009049295 Normal 0.58396028 no WABoeingRenton BOIL04 08/16/09 07:00 2.223164479 1.298304918normal 0.58398959 no
ARDomtarIndustries PB1 8/25/2009 12:00:00 PM 2.090911193 1.221605708 Normal 0.58424562 no VAPhilipMorrisPark500 B3 10/16/2009 6:00:00 PM 2.74788121 1.607386481 Normal 0.58495486 no VAPhilipMorrisPark500 B3 11/1/2009 8:00:00 PM 0.706758034 0.41342155 Normal 0.58495486 no VAPhilipMorrisPark500 B3 11/1/2009 9:00:00 PM 0.706758034 0.41342155 Normal 0.58495486 no VAPhilipMorrisPark500 B3 11/2/2009 9:00:00 AM 0.710414745 0.415560561 Normal 0.58495486 no VAPhilipMorrisPark500 B3 11/1/2009 6:00:00 PM 0.712369006 0.416703715 Normal 0.58495486 no VAPhilipMorrisPark500 B3 11/1/2009 11:00:00 PM 0.718069782 0.420038412 Normal 0.58495486 no VAPhilipMorrisPark500 B3 11/1/2009 3:00:00 AM 0.726794103 0.425141746 Normal 0.58495486 no VAPhilipMorrisPark500 B3 11/1/2009 6:00:00 AM 0.732729054 0.428613425 Normal 0.58495486 no VAPhilipMorrisPark500 B3 10/16/2009 11:00:00 PM 2.142238117 1.253112608 Normal 0.58495486 no VAPhilipMorrisPark500 B3 10/18/2009 11:00:00 AM 2.142238117 1.253112608 Normal 0.58495486 no



### Appendix D-4, p41 of 82

## Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC

(ppm@3%O2) CombUnit_O

p_Indicator THC_Op_Ind

icator CO_Op_Indi

cator TNMOC TO

THC Ratio Outlier VAPhilipMorrisPark500 B3 10/17/2009 4:00:00 AM 2.15927923 1.263080889 Normal 0.58495486 no VAPhilipMorrisPark500 B3 11/1/2009 7:00:00 PM 0.695797146 0.407009926 Normal 0.58495486 no VAPhilipMorrisPark500 B3 11/1/2009 10:00:00 PM 0.701234761 0.410190685 Normal 0.58495486 no VAPhilipMorrisPark500 B3 10/16/2009 9:00:00 PM 2.790250759 1.632170755 Normal 0.58495486 no VAPhilipMorrisPark500 B3 10/17/2009 9:00:00 AM 2.811931515 1.644853018 Normal 0.58495486 no ARDomtarIndustries PB1 8/31/2009 3:00:00 PM 4.504771594 2.635526562 Normal 0.58505221 no ARDomtarIndustries PB1 8/27/2009 8:00:00 PM 2.640721643 1.549587063 Normal 0.58680439 no ARDomtarIndustries PB1 8/31/2009 8:00:00 PM 10.11016291 5.937442264 Normal 0.58727464 no WABoeingRenton BOIL04 09/21/09 02:00 23.59321014 13.87691658normal 0.58817416 no TXDibollTemple-Inland PB-44 1300-1400 1.584800151 0.932358818 0.58831318 no WABoeingRenton BOIL04 09/26/09 17:00 0.931078668 0.548861004 normal 0.5894894 no TXDibollTemple-Inland PB-44 2200-2300 1.461035635 0.861590582 0.58971223 no ARDomtarIndustries PB1 8/18/2009 9:00:00 PM 4.428473024 2.614441139 Normal 0.59037079 no ARDomtarIndustries PB1 8/25/2009 6:00:00 PM 1.643717719 0.971832271 Normal 0.59124037 no ARDomtarIndustries PB1 8/27/2009 3:00:00 PM 1.808576439 1.069622568 Normal 0.59141684 no VAPhilipMorrisPark500 B3 10/16/2009 3:00:00 PM 3.112793692 1.847232854 Normal 0.59343247 no VAPhilipMorrisPark500 B3 10/16/2009 8:00:00 PM 3.233721242 1.918995188 Normal 0.59343247 no
ARDomtarIndustries PB1 8/16/2009 10:00:00 AM 20.49161626 12.18592825 Normal 10:04 - 10:59 calibration 10:04 - 10:59

calibration 0.59467873 no TXDibollTemple-Inland PB-44 1400-1500 1.533078772 0.912780499 0.59539048 no WABoeingRenton BOIL04 08/26/09 07:00 3.214831255 1.914761555normal 0.59560251 no ARDomtarIndustries PB1 8/31/2009 7:00:00 PM 5.365180066 3.196379057 Normal 0.59576361 no VAPhilipMorrisPark500 B3 10/17/2009 2:00:00 AM 2.570685741 1.531582076 Normal 0.59578736 no ARDomtarIndustries PB1 9/1/2009 7:00:00 AM 3.313942332 1.981080524 Normal 0.59780175no WABoeingRenton BOIL04 08/27/09 03:00 5.562865004 3.32676449 normal 0.59803078 no WABoeingRenton BOIL04 08/19/09 15:00 2.166806815 1.297509193 normal 0.59881166 no TXDibollTemple-Inland PB-44 0902-1002 1.218967143 0.731251852 0.59989464 no VAPhilipMorrisPark500 B3 10/17/2009 6:00:00 AM 1.827755484 1.096568679 Normal 0.59995371 no VAPhilipMorrisPark500 B3 10/17/2009 5:00:00 AM 1.842067239 1.105155069 Normal 0.59995371 no ARDomtarIndustries PB1 8/21/2009 8:00:00 AM 37.82395732 22.69304031 Normal 0.59996473 no ARDomtarIndustries PB1 8/25/2009 5:00:00 PM 1.769265197 1.0619126 Normal 0.60019979 no ARDomtarIndustries PB1 8/29/2009 8:00:00 AM 3.538425739 2.123887946 Normal 0.60023527 no TXDibollTemple-Inland PB-44 0400-0500 3.127771994 1.883775751 0.602274 no ARDomtarIndustries PB1 9/5/2009 5:00:00 AM 2.909257256 1.753640456 Normal 0.60277944 no



### Appendix D-4, p42 of 82

## Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC

(ppm@3%O2) CombUnit_O

p_Indicator THC_Op_Ind

icator CO_Op_Indi

cator TNMOC TO

THC Ratio Outlier TXDibollTemple-Inland PB-44 1002-1103 1.194271878 0.719919918 0.60281074 no ARDomtarIndustries PB1 8/29/2009 1:00:00 PM 6.478269345 3.912336803 Normal 0.60391697 no ARDomtarIndustries PB1 8/16/2009 6:00:00 AM 5.523696619 3.338811596 Normal 0.60445239 no
WVDuPontWashingtonWorks P05 9/23/2009 10:00:22 AM 0.349523292 0.211291243 0.60451263 no ARDomtarIndustries PB1 8/18/2009 6:00:00 PM 4.593806919 2.777573492 Normal 0.60463436 no ARDomtarIndustries PB1 8/25/2009 2:00:00 AM 1.806882698 1.092805902 Normal 0.6048018no WABoeingRenton BOIL04 08/20/09 08:00 1.506865653 0.9114734 normal 0.60488033 no ARDomtarIndustries PB1 8/20/2009 9:00:00 AM 15.17077884 9.191302534 Normal 0.60585568 no
ARDomtarIndustries PB1 8/27/2009 12:00:00 PM 1.879553173 1.139218725 Normal 0.60611146 no
ARDomtarIndustries PB1 8/19/2009 10:00:00 AM 9.528604774 5.778440907 Normal 10:05 - 10:55 calibration 10:05 - 10:55

calibration 0.60643096 no ARDomtarIndustries PB1 8/26/2009 4:00:00 PM 1.690228376 1.025539974 Normal 0.60674639 no ARDomtarIndustries PB1 8/15/2009 6:00:00 PM 4.207609351 2.553990084 Normal 0.60699316 no TXDibollTemple-Inland PB-44 1702-1802 1.43879328 0.873396332 0.60703392 no TXDibollTemple-Inland PB-44 1900-2000 1.53034696 0.931432554 0.60864142 no TXDibollTemple-Inland PB-44 1500-1600 1.172023319 0.713433661 0.60871968 no
ARDomtarIndustries PB1 8/16/2009 11:00:00 AM 9.852440357 6.000579318 Normal 0.60904498 no ARDomtarIndustries PB1 9/2/2009 1:00:00 PM 2.169041773 1.321502968 Normal 0.60925658 no WABoeingRenton BOIL04 08/24/09 16:00 0.792415062 0.482840672 normal 0.60932798 no VAPhilipMorrisPark500 B3 10/30/2009 12:00:00 PM 1.130812854 0.689035917 Normal 0.60932798 no VAPhilipMorrisPark500 B3 10/30/2009 2:00:00 PM 1.130812854 0.689035917 Normal 0.60932798 no VAPhilipMorrisPark500 B3 10/30/2009 1:00:00 PM 1.13979041 0.694506192 Normal 0.60932798 no VAPhilipMorrisPark500 B3 10/30/2009 4:00:00 PM 1.177172844 0.717284356 Normal 0.60932798 no VAPhilipMorrisPark500 B3 10/30/2009 7:00:00 PM 1.186904762 0.723214286 Normal 0.60932798 no VAPhilipMorrisPark500 B3 10/30/2009 8:00:00 PM 1.196798933 0.729243081 Normal 0.60932798 no VAPhilipMorrisPark500 B3 10/30/2009 9:00:00 PM 1.196798933 0.729243081 Normal 0.60932798 no VAPhilipMorrisPark500 B3 10/17/2009 11:00:00 PM 2.285053992 1.392347342 Normal 0.60932798 no VAPhilipMorrisPark500 B3 10/18/2009 12:00:00 PM 2.285053992 1.392347342 Normal 0.60932798 no VAPhilipMorrisPark500 B3 10/30/2009 3:00:00 PM 1.148911652 0.70006402 Normal 0.60932798 no VAPhilipMorrisPark500 B3 10/30/2009 6:00:00 PM 1.148911652 0.70006402 Normal 0.60932798 no VAPhilipMorrisPark500 B3 10/30/2009 5:00:00 PM 1.158180058 0.70571152 Normal 0.60932798 no



### Appendix D-4, p43 of 82

## Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC

(ppm@3%O2) CombUnit_O

p_Indicator THC_Op_Ind

icator CO_Op_Indi

cator TNMOC TO

THC Ratio Outlier VAPhilipMorrisPark500 B3 10/16/2009 10:00:00 PM 2.232200607 1.360142296 Normal 0.60932798 no WABoeingRenton BOIL04 08/19/09 18:00 0.263330888 0.160454879normal 0.60932798 no ARDomtarIndustries PB1 8/17/2009 6:00:00 AM 4.745841256 2.893170922 Normal 0.60962235no TXDibollTemple-Inland PB-44 1400-1500 1.545846388 0.942945025 0.60998624 no TXDibollTemple-Inland PB-44 1500-1600 2.771563157 1.692270647 0.61058347 no WABoeingRenton BOIL04 09/19/09 10:00 45.0291467 27.51495338normal 0.61104763 no ARDomtarIndustries PB1 8/20/2009 8:00:00 AM 29.34682156 17.93389725 Normal 0.61110186 no
ARDomtarIndustries PB1 8/30/2009 12:00:00 PM 7.112565882 4.349881761 Normal 0.61157701 no
ARDomtarIndustries PB1 8/19/2009 11:00:00 AM 13.87639539 8.494532562 Normal 0.612157 no

ARDomtarIndustries PB1 8/31/2009 1:00:00 PM 10.06406011 6.164776699 Normal 13:04 - 13:55 calibration for 8/30 13:04 - 13:55

calibration for 8/30 0.61255364 no ARDomtarIndustries PB1 8/18/2009 5:00:00 PM 4.661882671 2.857075488 Normal 0.61285873 no
ARDomtarIndustries PB1 9/10/2009 10:00:00 AM 3.696186176 2.266236648 Normal 10:05 - 10:59 calibration 10:05 - 10:59

calibration 0.61312838 no ARDomtarIndustries PB1 8/30/2009 3:00:00 AM 11.93370877 7.320986401 Normal 0.61347118 no TXDibollTemple-Inland PB-44 0300-0400 2.69824229 1.655751682 0.61364085no TXDibollTemple-Inland PB-44 10/02/09 0000-0100 2.421368809 1.486489348 0.61390456 no ARDomtarIndustries PB1 8/31/2009 8:00:00 AM 5.13798163 3.156333397 Normal 0.61431387 no ARDomtarIndustries PB1 8/18/2009 2:00:00 AM 4.491836407 2.761045712 Normal 0.61468083 no ARDomtarIndustries PB1 8/16/2009 1:00:00 PM 7.281502376 4.478666541 Normal 0.61507451 no TXDibollTemple-Inland PB-44 10/17/2009 0000-0100 13.91112102 8.559421272 0.61529342 no TXDibollTemple-Inland PB-44 1500-1600 1.369157654 0.843368534 0.6159762 no
ARDomtarIndustries PB1 8/15/2009 10:00:00 PM 4.571959818 2.821011085 Normal 0.61702447 no TXDibollTemple-Inland PB-44 1800-1900 1.494563339 0.922383538 0.61715922 no TXDibollTemple-Inland PB-44 1700-1800 1.477140366 0.911632181 0.61716016 no TXDibollTemple-Inland PB-44 2000-2100 1.579215976 0.976397936 0.61828018 no ARDomtarIndustries PB1 8/16/2009 4:00:00 PM 11.63037826 7.194607332 Normal 0.61860476 no TXDibollTemple-Inland PB-44 2200-2300 3.617918894 2.240632035 0.61931516 no TXDibollTemple-Inland PB-44 1600-1700 1.616914129 1.001425637 0.61934374 no ARDomtarIndustries PB1 8/25/2009 1.89477871 1.17386525 Normal 0.6195263 no TXDibollTemple-Inland PB-44 1800-1900 2.154311237 1.33583962 0.62007736 no ARDomtarIndustries PB1 9/2/2009 2:00:00 PM 2.760472676 1.718271025 Normal 0.62245536 no ARDomtarIndustries PB1 8/26/2009 3:00:00 PM 1.942071555 1.209279869 Normal 0.62267524 no WABoeingRenton BOIL04 08/26/09 15:00 5.415877816 3.373677767 normal 0.62292354 no TXDibollTemple-Inland PB-44 1800-1900 3.177471567 1.981036589 0.6234632 no


### Appendix D-4, p44 of 82

## Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC

(ppm@3%O2) CombUnit_O

p_Indicator THC_Op_Ind

icator CO_Op_Indi

cator TNMOC TO

THC Ratio Outlier WABoeingRenton BOIL04 08/26/09 03:00 3.979206174 2.486262404 normal 0.62481367 no
ARDomtarIndustries PB1 8/24/2009 10:00:00 PM 1.944726436 1.21621143 Normal 0.62538947 no ARDomtarIndustries PB1 8/15/2009 9:00:00 PM 5.236927358 3.278927413 Normal 0.62611665no TXDibollTemple-Inland PB-44 1700-1800 1.428673017 0.895101775 0.62652669 no VAPhilipMorrisPark500 B3 10/18/2009 1:00:00 AM 2.015327281 1.263080889 Normal 0.62673735no WABoeingRenton BOIL04 10/08/09 17:00 1.081217263 0.677639248normal 0.62673735no
ARDomtarIndustries PB1 8/15/2009 12:00:00 PM 9.710597167 6.089194995 Normal 0.627067 no
ARDomtarIndustries PB1 8/17/2009 10:00:00 AM 4.455361958 2.794691979 Normal 10:04 - 10:49 calibration 10:04 - 10:49

calibration 0.62726486 no WABoeingRenton BOIL04 09/19/09 13:00 44.35697452 27.84955414 normal 0.62785062 no ARDomtarIndustries PB1 8/12/2009 4:00:00 PM 15.68553653 9.852898467 Normal 0.62815183 no TXDibollTemple-Inland PB-44 0600-0700 4.128405257 2.594892081 0.62854587 no ARDomtarIndustries PB1 8/24/2009 7:00:00 PM 2.278782437 1.432658125 Normal 0.62869456 no WABoeingRenton BOIL04 09/19/09 07:00 42.20845011 26.53910828normal 0.62876292 no TXDibollTemple-Inland PB-44 0900-1000 2.285366354 1.437161549 0.6288539no TXDibollTemple-Inland PB-44 1300-1400 1.75374177 1.103107386 0.62900217 no TXDibollTemple-Inland PB-44 0100-0200 4.492229773 2.826267083 0.62914571 no TXDibollTemple-Inland PB-44 1500-1600 3.357717462 2.11252624 0.62915545no VAPhilipMorrisPark500 B3 10/17/2009 3:00:00 AM 2.447183127 1.543765531 Normal 0.63083368 no ARDomtarIndustries PB1 8/19/2009 2:00:00 PM 83.81470806 52.87404625 Normal 0.63084448 no ARDomtarIndustries PB1 8/18/2009 9:00:00 AM 4.871830742 3.07468055 Normal 0.63111399 no WABoeingRenton BOIL04 09/21/09 00:00 33.52583936 21.16122639normal 0.63119155no
ARDomtarIndustries PB1 8/27/2009 10:00:00 PM 1.894298734 1.196103887 Normal 0.63142305no TXDibollTemple-Inland PB-44 1000-1100 2.991 1.888762404 0.63148191 no TXDibollTemple-Inland PB-44 1700-1800 5.201028057 3.284363143 0.63148345no TXDibollTemple-Inland PB-44 1500-1600 1.694455485 1.070110655 0.6315366 no ARDomtarIndustries PB1 8/21/2009 9:00:00 AM 28.64425838 18.09307495 Normal 0.63164753 no
ARDomtarIndustries PB1 8/16/2009 12:00:00 PM 7.147924459 4.517303758 Normal 0.63197419 no ARDomtarIndustries PB1 8/16/2009 2:00:00 PM 7.451168813 4.714988361 Normal 0.63278507 no WABoeingRenton BOIL04 09/19/09 02:00 41.90137276 26.52215417 normal 0.63296624 no ARDomtarIndustries PB1 8/21/2009 6:00:00 PM 21.72665242 13.75633325 Normal 0.63315475no
ARDomtarIndustries PB1 8/20/2009 11:00:00 AM 17.18487458 10.88591776 Normal 0.63345925no ARDomtarIndustries PB1 8/25/2009 3:00:00 PM 2.125382658 1.346707594 Normal 0.63363065no



### Appendix D-4, p45 of 82

## Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC

(ppm@3%O2) CombUnit_O

p_Indicator THC_Op_Ind

icator CO_Op_Indi

cator TNMOC TO

THC Ratio Outlier
ARDomtarIndustries PB1 9/2/2009 10:00:00 AM 1.586179041 1.006369716 Normal 10:05 - 10:55 calibration 10:05 - 10:55

calibration 0.63446162 no ARDomtarIndustries PB1 8/17/2009 8:00:00 AM 4.090521214 2.597789429 Normal 0.63507541 no TXDibollTemple-Inland PB-44 1800-1900 1.496184654 0.950595329 0.63534626 no WABoeingRenton BOIL04 08/22/09 15:00 1.267995822 0.806217744 normal 0.6358205no ARDomtarIndustries PB1 8/27/2009 2:00:00 AM 1.455772267 0.926588372 Normal 0.63649267 no ARDomtarIndustries PB1 8/25/2009 2:00:00 PM 2.100870377 1.338064574 Normal 0.63690963 no ARDomtarIndustries PB1 8/18/2009 7:00:00 PM 4.541464749 2.893586683 Normal 0.63714833 no VAPhilipMorrisPark500 B3 10/16/2009 2:00:00 PM 3.572245573 2.277130848 Normal 0.63745081 no ARDomtarIndustries PB1 8/23/2009 7:00:00 AM 34.05360101 21.72487111 Normal 0.63796105no ARDomtarIndustries PB1 8/13/2009 2:00:00 PM 6.043615907 3.855852166 Normal 0.63800417 no WABoeingRenton BOIL04 08/18/09 02:00 3.598885073 2.296175641 normal 0.63802416 no WABoeingRenton BOIL04 08/15/09 06:00 1.206933236 0.770183419normal 0.63813258 no
ARDomtarIndustries PB1 8/24/2009 10:00:00 AM 3.705157792 2.365925976 Normal 10:10 - 10 :53 calibration 10:10 - 10

:53 calibration 0.63854932 no TXDibollTemple-Inland PB-44 2000-2100 4.13564613 2.643859746 0.63928578 no ARDomtarIndustries PB1 8/21/2009 7:00:00 AM 41.56327441 26.57756812 Normal 0.63944837 no ARDomtarIndustries PB1 8/27/2009 1:00:00 PM 1.629441286 1.044774042 Normal 0.64118545no ARDomtarIndustries PB1 8/18/2009 5:00:00 AM 5.817565487 3.730939289 Normal 0.64132313 no WABoeingRenton BOIL04 08/10/09 18:00 0.898615046 0.576932096 normal 0.64202363 no ARDomtarIndustries PB1 8/16/2009 7:00:00 PM 10.64412883 6.834267849 Normal 0.64206925no ARDomtarIndustries PB1 8/16/2009 9:00:00 AM 19.9046459 12.78592392 Normal 0.64235877 no TXDibollTemple-Inland PB-44 2100-2200 2.423786848 1.557876749 0.64274495no ARDomtarIndustries PB1 8/16/2009 7:00:00 AM 11.89339536 7.647678848 Normal 0.64301897 no WABoeingRenton BOIL04 09/19/09 15:00 32.48681845 20.89976355normal 0.64333057 no
ARDomtarIndustries PB1 8/21/2009 10:00:00 AM 26.81548307 17.2597338 Normal 10:10 - 10:59 calibration 10:10 - 10:59

calibration 0.64364807 no
ARDomtarIndustries PB1 8/17/2009 11:00:00 AM 8.251566527 5.315147951 Normal 0.64413805no ARDomtarIndustries PB1 8/31/2009 3.859487762 2.487375146 Normal 0.64448323 no
ARDomtarIndustries PB1 8/18/2009 12:00:00 PM 4.153759966 2.678444721 Normal 0.64482415no ARDomtarIndustries PB1 9/4/2009 6:00:00 PM 4.232490356 2.730409173 Normal 0.645107 no ARDomtarIndustries PB1 8/16/2009 6:00:00 PM 6.995319778 4.515154368 Normal 0.6454536 no TXDibollTemple-Inland PB-44 0400-0500 2.804756987 1.810648842 0.64556354 no
WVDuPontWashingtonWorks P05 9/23/2009 12:00:24 PM 0.362021219 0.233877372 0.64603222 no



### Appendix D-4, p46 of 82

## Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC

(ppm@3%O2) CombUnit_O

p_Indicator THC_Op_Ind

icator CO_Op_Indi

cator TNMOC TO

THC Ratio Outlier ARDomtarIndustries PB1 8/19/2009 5:00:00 AM 19.00001592 12.28549576 Normal 0.6466045no ARDomtarIndustries PB1 8/21/2009 6:00:00 AM 34.03249844 22.01626702 Normal 0.64691892 no
ARDomtarIndustries PB1 8/31/2009 12:00:00 PM 4.258780476 2.755290781 Normal 0.64696708 no
ARDomtarIndustries PB1 8/21/2009 11:00:00 AM 23.55859753 15.24253084 Normal 0.64700502 no TXDibollTemple-Inland PB-44 0900-1000 3.432652217 2.221428547 0.64714641 no TXDibollTemple-Inland PB-44 0300-0400 2.612369005 1.690586734 0.64714699 no
ARDomtarIndustries PB1 8/15/2009 11:00:00 AM 13.09739412 8.478793695 Normal 0.64736494 no ARDomtarIndustries PB1 8/24/2009 9:00:00 PM 2.096330483 1.357474783 Normal 0.64754808 no ARDomtarIndustries PB1 8/18/2009 3:00:00 AM 3.969357237 2.572314686 Normal 0.64804313 no ARDomtarIndustries PB1 8/19/2009 9:00:00 AM 18.62592772 12.07254993 Normal 0.64815832 no WABoeingRenton BOIL04 09/19/09 09:00 35.45517192 22.99929103 normal 0.64868649 no
ARDomtarIndustries PB1 8/14/2009 12:00:00 PM 4.735608524 3.072196823 Normal 0.64874383 no ARDomtarIndustries PB1 8/21/2009 8:00:00 PM 24.47616491 15.89533325 Normal 0.64942091 no VAPhilipMorrisPark500 B3 11/2/2009 7:00:00 PM 0.383876037 0.249500173 Normal 0.64994985no VAPhilipMorrisPark500 B3 11/2/2009 11:00:00 PM 0.383876037 0.249500173 Normal 0.64994985no VAPhilipMorrisPark500 B3 11/2/2009 7:00:00 AM 0.42405482 0.275614367 Normal 0.64994985no VAPhilipMorrisPark500 B3 10/31/2009 4:00:00 AM 0.912817904 0.59328586 Normal 0.64994985no VAPhilipMorrisPark500 B3 10/18/2009 9:00:00 AM 1.741274907 1.131741364 Normal 0.64994985no VAPhilipMorrisPark500 B3 10/18/2009 10:00:00 AM 2.15927923 1.40342321 Normal 0.64994985no VAPhilipMorrisPark500 B3 11/2/2009 4:00:00 PM 0.381169634 0.247741146 Normal 0.64994985no VAPhilipMorrisPark500 B3 11/2/2009 5:00:00 PM 0.381169634 0.247741146 Normal 0.64994985no VAPhilipMorrisPark500 B3 11/2/2009 6:00:00 PM 0.381169634 0.247741146 Normal 0.64994985no VAPhilipMorrisPark500 B3 11/2/2009 8:00:00 PM 0.381169634 0.247741146 Normal 0.64994985no VAPhilipMorrisPark500 B3 11/2/2009 3:00:00 PM 0.39800664 0.258684356 Normal 0.64994985no VAPhilipMorrisPark500 B3 10/31/2009 10:00:00 PM 0.429124821 0.278909613 Normal 0.64994985no VAPhilipMorrisPark500 B3 10/31/2009 11:00:00 PM 0.429124821 0.278909613 Normal 0.64994985no VAPhilipMorrisPark500 B3 11/1/2009 4:00:00 AM 0.879274865 0.571484566 Normal 0.64994985no VAPhilipMorrisPark500 B3 10/31/2009 3:00:00 AM 0.890178571 0.578571429 Normal 0.64994985no VAPhilipMorrisPark500 B3 10/18/2009 2.142238117 1.392347342 Normal 0.64994985no 

### Appendix D-4, p47 of 82

## Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC

(ppm@3%O2) CombUnit_O

p_Indicator THC_Op_Ind

icator CO_Op_Indi

cator TNMOC TO

THC Ratio Outlier VAPhilipMorrisPark500 B3 11/2/2009 5:00:00 AM 0.427421404 0.277802477 Normal 0.64994985no VAPhilipMorrisPark500 B3 10/31/2009 2:00:00 PM 0.436076462 0.283427831 Normal 0.64994985no ARDomtarIndustries PB1 8/21/2009 7:00:00 PM 20.70720274 13.47516895 Normal 0.65074791 no ARDomtarIndustries PB1 9/1/2009 2:00:00 AM 4.019120242 2.615521399 Normal 0.65076963 no ARDomtarIndustries PB1 8/21/2009 1:00:00 AM 26.90278254 17.51121476 Normal 0.6509072 no TXDibollTemple-Inland PB-44 1600-1700 2.529206797 1.646961191 0.65117696 no TXDibollTemple-Inland PB-44 2000-2100 2.691517458 1.752800374 0.65123129 no WABoeingRenton BOIL04 08/26/09 23:00 5.352277385 3.489382776 normal 0.65194356 no TXDibollTemple-Inland PB-44 0700-0800 5.316326236 3.467809848 0.6522944 no TXDibollTemple-Inland PB-44 1200-1300 1.749247061 1.141245381 0.65242092 no TXDibollTemple-Inland PB-44 1100-1200 1.857228188 1.21169454 0.65242093 no ARDomtarIndustries PB1 8/20/2009 7:00:00 AM 20.22492596 13.19593607 Normal 0.65245905no ARDomtarIndustries PB1 8/16/2009 4:00:00 AM 6.267489234 4.091944779 Normal 0.65288421 no ARDomtarIndustries PB1 8/14/2009 7:00:00 AM 10.55228299 6.889424732 Normal 0.65288476 no ARDomtarIndustries PB1 8/21/2009 1:00:00 PM 26.50258309 17.32088494 Normal 0.65355459 no TXDibollTemple-Inland PB-44 0600-0700 4.077816971 2.665168501 0.65357727 no TXDibollTemple-Inland PB-44 1400-1500 2.351947317 1.537921317 0.65389276 no TXDibollTemple-Inland PB-44 1500-1600 1.508801364 0.987260757 0.65433448 no ARDomtarIndustries PB1 8/30/2009 2:00:00 AM 5.295391242 3.465130566 Normal 0.65436724 no WABoeingRenton BOIL04 10/05/09 17:00 0.802928414 0.525437607 normal 0.65440156 no TXDibollTemple-Inland PB-44 0400-0500 3.325123912 2.176721155 0.65462858 no TXDibollTemple-Inland PB-44 0200-0300 9.111305819 5.98194682 0.65654111 no TXDibollTemple-Inland PB-44 0100-0200 2.817213336 1.850299483 0.65678359 no TXDibollTemple-Inland PB-44 2200-2300 4.621189254 3.036484097 0.6570785no ARDomtarIndustries PB1 8/12/2009 6:00:00 PM 20.75440891 13.63752607 Normal 0.65709056 no TXDibollTemple-Inland PB-44 0600-0700 2.372358365 1.559678943 0.65743817 no ARDomtarIndustries PB1 8/16/2009 5:00:00 PM 7.318239416 4.813104644 Normal 0.65768614 no TXDibollTemple-Inland PB-44 0500-0600 3.117262271 2.053072532 0.65861399 no ARDomtarIndustries PB1 8/18/2009 8:00:00 AM 5.622467941 3.70605324 Normal 0.65915062 no TXDibollTemple-Inland PB-44 1500-1600 3.019763009 1.993090301 0.66001547 no TXDibollTemple-Inland PB-44 1900-2000 4.607156924 3.041411461 0.66014931 no ARDomtarIndustries PB1 8/19/2009 6:00:00 AM 14.7090741 9.712520032 Normal 0.66030805no ARDomtarIndustries PB1 8/15/2009 2:00:00 PM 9.459916437 6.251238551 Normal 0.66081329 no ARDomtarIndustries PB1 8/14/2009 9:00:00 AM 7.125117609 4.711521779 Normal 0.6612553 no ARDomtarIndustries PB1 8/20/2009 1:00:00 PM 17.83371984 11.80395076 Normal 0.66188944 no WABoeingRenton BOIL04 09/19/09 12:00 33.20850587 21.99188901 normal 0.66223663 no TXDibollTemple-Inland PB-44 0400-0500 2.609852583 1.728429965 0.66227111 no ARDomtarIndustries PB1 8/21/2009 5:00:00 PM 24.17801844 16.01333094 Normal 0.66230949 no ARDomtarIndustries PB1 8/16/2009 1:00:00 AM 5.602809013 3.712772975 Normal 0.66266278 no



### Appendix D-4, p48 of 82

## Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC

(ppm@3%O2) CombUnit_O

p_Indicator THC_Op_Ind

icator CO_Op_Indi

cator TNMOC TO

THC Ratio Outlier ARDomtarIndustries PB1 8/14/2009 6:00:00 AM 10.71216355 7.098638261 Normal 0.66267083 no
ARDomtarIndustries PB1 8/17/2009 12:00:00 PM 6.222265307 4.125662638 Normal 0.66304833 no ARDomtarIndustries PB1 8/17/2009 1:00:00 AM 24.73079799 16.40634177 Normal 0.66339719 no WABoeingRenton BOIL04 08/18/09 14:00 0.760797493 0.505229786 normal 0.66407919 no TXDibollTemple-Inland PB-44 1900-2000 2.420506565 1.607462547 0.66410171 no
ARDomtarIndustries PB1 8/20/2009 12:00:00 PM 21.07730478 14.00463251 Normal 0.66444133 no
ARDomtarIndustries PB1 8/29/2009 11:00:00 AM 4.684854776 3.114805951 Normal 0.66486713 no TXDibollTemple-Inland PB-44 1500-1600 2.17649341 1.447409775 0.66501914 no ARDomtarIndustries PB1 8/26/2009 2:00:00 AM 1.955790763 1.301693164 Normal 0.6655585no
ARDomtarIndustries PB1 8/20/2009 11:00:00 PM 19.71486265 13.13385204 Normal 0.66619039 no ARDomtarIndustries PB1 8/30/2009 7:00:00 AM 5.679011327 3.78617591 Normal 0.66669631 no ARDomtarIndustries PB1 8/16/2009 8:00:00 PM 21.80153646 14.5359468 Normal 0.66673956 no TXDibollTemple-Inland PB-44 2200-2300 3.065748461 2.044194916 0.66678494 no
ARDomtarIndustries PB1 8/16/2009 11:00:00 PM 17.45848875 11.64540015 Normal 0.66703369 no ARDomtarIndustries PB1 8/18/2009 7:00:00 AM 5.886989516 3.930001877 Normal 0.66757413 no ARDomtarIndustries PB1 8/25/2009 9:00:00 PM 1.802075667 1.203204549 Normal 0.66767704 no ARDomtarIndustries PB1 8/20/2009 3:00:00 AM 21.47224877 14.33732534 Normal 0.6677142 no TXDibollTemple-Inland PB-44 1600-1700 1.356922279 0.906428275 0.66800309 no ARDomtarIndustries PB1 8/14/2009 5:00:00 AM 10.2478211 6.852049799 Normal 0.6686348no WABoeingRenton BOIL04 09/21/09 01:00 23.90201573 15.99041559normal 0.66899862 no ARDomtarIndustries PB1 8/31/2009 2:00:00 PM 3.853231831 2.579037324 Normal 0.66931797 no ARDomtarIndustries PB1 8/19/2009 8:00:00 AM 26.41498204 17.68246415 Normal 0.66941042 no TXDibollTemple-Inland PB-44 1500-1600 2.1142459 1.415554223 0.6695315no ARDomtarIndustries PB1 8/16/2009 8:00:00 AM 15.1331822 10.13483556 Normal 0.66970948 no TXDibollTemple-Inland PB-44 1500-1600 2.406573379 1.612934161 0.67022023 no ARDomtarIndustries PB1 8/30/2009 2:00:00 PM 3.631827951 2.434425905 Normal 0.6703032 no ARDomtarIndustries PB1 8/16/2009 3:00:00 AM 5.799617746 3.888521644 Normal 0.67047895no TXDibollTemple-Inland PB-44 2300-2400 2.83791971 1.903947406 0.67089544 no TXDibollTemple-Inland PB-44 2300-2400 2.256915534 1.514469829 0.67103523 no ARDomtarIndustries PB1 8/16/2009 9:00:00 PM 23.96051272 16.08087804 Normal 0.67114082 no ARDomtarIndustries PB1 8/16/2009 6.444844377 4.328446718 Normal 0.67161385no ARDomtarIndustries PB1 8/20/2009 6:00:00 AM 15.26474484 10.2528237 Normal 0.67166689 no TXDibollTemple-Inland PB-44 0200-0300 2.815172911 1.89114065 0.67176714 no



### Appendix D-4, p49 of 82

## Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC

(ppm@3%O2) CombUnit_O

p_Indicator THC_Op_Ind

icator CO_Op_Indi

cator TNMOC TO

THC Ratio Outlier ARDomtarIndustries PB1 8/18/2009 6:00:00 AM 5.984977065 4.021454039 Normal 0.67192472 no ARDomtarIndustries PB1 8/17/2009 3:00:00 AM 38.75912017 26.07027764 Normal 0.67262305no
ARDomtarIndustries PB1 8/19/2009 12:00:00 PM 15.23146472 10.24802876 Normal 0.67281965no TXDibollTemple-Inland PB-44 1700-1800 2.946105445 1.982461473 0.67290921 no ARDomtarIndustries PB1 8/30/2009 1:00:00 AM 7.18000727 4.831553745 Normal 0.67291767 no TXDibollTemple-Inland PB-44 1600-1700 3.068885257 2.066678936 0.67342985no ARDomtarIndustries PB1 8/13/2009 1:00:00 PM 30.67791195 20.66118418 Normal 0.6734873 no ARDomtarIndustries PB1 8/21/2009 4:00:00 PM 22.98357842 15.49081843 Normal 0.67399506 no TXDibollTemple-Inland PB-44 0700-0800 2.565701733 1.730676397 0.6745431 no ARDomtarIndustries PB1 8/21/2009 2:00:00 PM 25.4062541 17.13920164 Normal 0.67460561 no TXDibollTemple-Inland PB-44 0900-1000 2.200675715 1.48469535 0.67465431 no VAPhilipMorrisPark500 B3 10/18/2009 7:00:00 AM 1.856606368 1.253112608 Normal 0.67494792 no VAPhilipMorrisPark500 B3 10/18/2009 8:00:00 AM 1.871375332 1.263080889 Normal 0.67494792 no WABoeingRenton BOIL04 08/19/09 16:00 0.85844965 0.579408807 normal 0.67494792 no
ARDomtarIndustries PB1 8/16/2009 10:00:00 PM 16.98785957 11.46744373 Normal 0.67503759 no ARDomtarIndustries PB1 8/29/2009 5:00:00 AM 1.883935393 1.271911183 Normal 0.67513525no ARDomtarIndustries PB1 8/17/2009 2:00:00 AM 34.75675473 23.49500343 Normal 0.67598381 no TXDibollTemple-Inland PB-44 0600-0700 2.865551733 1.938544312 0.6764995no TXDibollTemple-Inland PB-44 2200-2300 2.722599371 1.841838089 0.67649986 no ARDomtarIndustries PB1 8/21/2009 23.34091635 15.79041852 Normal 0.67651237 no ARDomtarIndustries PB1 8/30/2009 6:00:00 AM 7.370894027 4.986553999 Normal 0.67651956 no ARDomtarIndustries PB1 8/17/2009 4:00:00 AM 35.44852727 23.9841852 Normal 0.67659187 no WVDuPontWashingtonWorks P05 9/22/2009 2:00:04 PM 0.601919297 0.407253757 0.67659196 no
ARDomtarIndustries PB1 8/19/2009 11:00:00 PM 5.132415387 3.47342315 Normal 0.67676189 no TXDibollTemple-Inland PB-44 2302-2402 2.223822182 1.50604936 0.67723462 no ARDomtarIndustries PB1 8/17/2009 33.26325197 22.55390125 Normal 0.67804258 no ARDomtarIndustries PB1 8/14/2009 4:00:00 AM 15.78341905 10.7042016 Normal 0.67819283 no TXDibollTemple-Inland PB-44 2002-2102 2.009069713 1.363214294 0.67853011 no TXDibollTemple-Inland PB-44 1800-1900 4.728202967 3.210196867 0.6789465no ARDomtarIndustries PB1 8/13/2009 8:00:00 AM 100.2106003 68.03941017 Normal 0.6789642 no TXDibollTemple-Inland PB-44 1802-1902 1.625760759 1.103883583 0.6789951 no ARDomtarIndustries PB1 8/19/2009 1:00:00 PM 9.335755938 6.340297415 Normal 0.6791413 no TXDibollTemple-Inland PB-44 0300-0400 7.45247617 5.06542268 0.6796966 no TXDibollTemple-Inland PB-44 0700-0800 3.115701346 2.118432636 0.6799216 no TXDibollTemple-Inland PB-44 1200-1300 2.844514196 1.934050992 0.67992313 no WABoeingRenton BOIL04 09/19/09 11:00 30.33966995 20.63668052 normal 0.68018804 no



### Appendix D-4, p50 of 82

## Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC

(ppm@3%O2) CombUnit_O

p_Indicator THC_Op_Ind

icator CO_Op_Indi

cator TNMOC TO

THC Ratio Outlier ARDomtarIndustries PB1 8/18/2009 3:00:00 PM 4.028771294 2.741801776 Normal 0.68055533 no ARDomtarIndustries PB1 8/20/2009 2:00:00 AM 22.17129065 15.09763821 Normal 0.68095441 no ARDomtarIndustries PB1 8/21/2009 3:00:00 AM 25.21215418 17.18895244 Normal 0.68177246 no ARDomtarIndustries PB1 8/18/2009 4:00:00 AM 4.01073458 2.734913762 Normal 0.68189847 no ARDomtarIndustries PB1 8/20/2009 4:00:00 AM 20.54295799 14.00844039 Normal 0.68190961 no VAPhilipMorrisPark500 B3 10/1/2009 1:00:00 PM 2.618644086 1.787086696 Normal 0.68244734 no ARDomtarIndustries PB1 8/18/2009 1:00:00 PM 3.52966303 2.409223082 Normal 0.68256461 no TXDibollTemple-Inland PB-44 1400-1500 2.885913144 1.969900436 0.68259173 no ARDomtarIndustries PB1 8/19/2009 3:00:00 PM 97.61423277 66.67146171 Normal 0.68300964 no
ARDomtarIndustries PB1 8/21/2009 11:00:00 PM 22.5393482 15.39856308 Normal 0.68318582 no TXDibollTemple-Inland PB-44 1600-1700 1.976858937 1.351778494 0.68380119 no WABoeingRenton BOIL04 08/16/09 08:00 1.883140648 1.288365243 normal 0.68415774 no TXDibollTemple-Inland PB-44 1315-1415 1.299130157 0.889111305 0.68438971 no TXDibollTemple-Inland PB-44 0400-0500 3.228746154 2.211717828 0.68500827 no ARDomtarIndustries PB1 8/22/2009 2:00:00 AM 17.38769304 11.91097919 Normal 0.68502355no TXDibollTemple-Inland PB-44 0500-0600 3.215325 2.202594658 0.68503018 no ARDomtarIndustries PB1 8/24/2009 2:00:00 PM 4.418048835 3.02685571 Normal 0.68511142 no WABoeingRenton BOIL04 09/19/09 14:00 28.89267717 19.81207395normal 0.68571264 no TXDibollTemple-Inland PB-44 1800-1900 2.456266144 1.685077658 0.6860322 no ARDomtarIndustries PB1 8/12/2009 2:00:00 PM 13.91813426 9.549997928 Normal 0.68615504 no ARDomtarIndustries PB1 8/20/2009 5:00:00 AM 13.44754783 9.228532585 Normal 0.68626137 no
ARDomtarIndustries PB1 8/12/2009 11:00:00 AM 27.06652504 18.57887953 Normal 0.6864154 no ARDomtarIndustries PB1 8/15/2009 5:00:00 AM 7.706453379 5.290862519 Normal 0.6865496 no ARDomtarIndustries PB1 8/19/2009 7:00:00 AM 14.57352425 10.00690116 Normal 0.68664936 no ARDomtarIndustries PB1 8/22/2009 30.51475827 20.96418125 Normal 0.68701777 no ARDomtarIndustries PB1 8/29/2009 6:00:00 AM 2.66702318 1.83234877 Normal 0.68703894 no WABoeingRenton BOIL04 08/12/09 04:00 1.526057751 1.048946531 normal 0.68735704 no
ARDomtarIndustries PB1 8/13/2009 12:00:00 PM 11.50091641 7.911006955 Normal 0.68785883 no ARDomtarIndustries PB1 8/25/2009 1:00:00 PM 2.50961922 1.72755534 Normal 0.68837349 no ARDomtarIndustries PB1 8/23/2009 8:00:00 AM 21.79289062 15.00358079 Normal 0.68846217 no ARDomtarIndustries PB1 8/15/2009 4:00:00 AM 5.818229231 4.007344375 Normal 0.6887567 no ARDomtarIndustries PB1 8/21/2009 2:00:00 AM 26.98156156 18.5867674 Normal 0.68886922 no



### Appendix D-4, p51 of 82

## Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC

(ppm@3%O2) CombUnit_O

p_Indicator THC_Op_Ind

icator CO_Op_Indi

cator TNMOC TO

THC Ratio Outlier
ARDomtarIndustries PB1 8/21/2009 12:00:00 PM 23.83679135 16.42257516 Normal 0.68895914 no TXDibollTemple-Inland PB-44 2300-2400 2.961636989 2.041636666 0.68936087 no TXDibollTemple-Inland PB-44 1500-1600 2.68649432 1.852141701 0.68942699 no ARDomtarIndustries PB1 8/29/2009 8:00:00 PM 4.815966911 3.322041699 Normal 0.68979745no
ARDomtarIndustries PB1 8/15/2009 11:00:00 PM 6.220805387 4.291207343 Normal 0.6898154 no TXDibollTemple-Inland PB-44 2000-2100 4.657692134 3.213259222 0.68988227 no TXDibollTemple-Inland PB-44 0900-1000 2.443157967 1.687059296 0.69052403 no WABoeingRenton BOIL04 08/11/09 20:00 1.051395093 0.726063713 normal 0.69057172 no WABoeingRenton BOIL04 08/19/09 08:00 0.340552155 0.235621939normal 0.6918821 no ARDomtarIndustries PB1 8/15/2009 1:00:00 PM 7.413425858 5.129229795 Normal 0.69188387 no ARDomtarIndustries PB1 8/22/2009 1:00:00 AM 23.14871752 16.01870462 Normal 0.69199102 no
ARDomtarIndustries PB1 8/30/2009 10:00:00 PM 3.626338714 2.510655321 Normal 0.69233889 no TXDibollTemple-Inland PB-44 2000-2100 1.803340869 1.248883146 0.69253859 no ARDomtarIndustries PB1 8/14/2009 3:00:00 AM 20.19476243 13.98772377 Normal 0.69264116 no TXDibollTemple-Inland PB-44 1800-1900 3.056790627 2.117731141 0.69279561 no TXDibollTemple-Inland PB-44 0100-0200 2.383021731 1.651342583 0.69296161 no ARDomtarIndustries PB1 8/21/2009 3:00:00 PM 22.75756875 15.77056005 Normal 0.69298088 no TXDibollTemple-Inland PB-44 1600-1700 2.856216156 1.979493106 0.69304737 no ARDomtarIndustries PB1 8/19/2009 1:00:00 AM 4.114714469 2.851726114 Normal 0.69305565no ARDomtarIndustries PB1 8/13/2009 9:00:00 AM 25.60146934 17.75326465 Normal 0.6934471 no ARDomtarIndustries PB1 8/30/2009 5:00:00 AM 9.263683457 6.424822594 Normal 0.69354945no ARDomtarIndustries PB1 8/21/2009 5:00:00 AM 25.40079076 17.61756702 Normal 0.69358341 no
ARDomtarIndustries PB1 8/24/2009 11:00:00 PM 2.326088386 1.613450723 Normal 0.69363259 no TXDibollTemple-Inland PB-44 1500-1600 2.151964651 1.492809926 0.6936963 no WABoeingRenton BOIL04 08/10/09 20:00 0.646564485 0.448724963 normal 0.69401425no WABoeingRenton BOIL04 08/26/09 21:00 4.025434597 2.794070462 normal 0.69410405no ARDomtarIndustries PB1 8/20/2009 6:00:00 PM 23.24093204 16.13304928 Normal 0.69416533 no ARDomtarIndustries PB1 8/17/2009 5:00:00 AM 8.990883118 6.249061019 Normal 0.69504418 no ARDomtarIndustries PB1 8/30/2009 6.22823849 4.329440955 Normal 0.69513089 no ARDomtarIndustries PB1 8/15/2009 3:00:00 AM 5.903452913 4.103887399 Normal 0.6951673 no WABoeingRenton BOIL04 09/20/09 09:00 25.26605105 17.57249202 normal 0.69549816 no ARDomtarIndustries PB1 8/23/2009 6:00:00 AM 18.88875617 13.13879815 Normal 0.69558832 no TXDibollTemple-Inland PB-44 1600-1700 2.270809289 1.579948168 0.69576436 no TXDibollTemple-Inland PB-44 1600-1700 2.1142459 1.471216684 0.69585883 no TXDibollTemple-Inland PB-44 2102-2202 2.09483038 1.457784326 0.69589612 no


### Appendix D-4, p52 of 82

## Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC

(ppm@3%O2) CombUnit_O

p_Indicator THC_Op_Ind

icator CO_Op_Indi

cator TNMOC TO

THC Ratio Outlier VAPhilipMorrisPark500 B3 10/18/2009 2:00:00 AM 2.015327281 1.40342321 Normal 0.69637484 no VAPhilipMorrisPark500 B3 10/18/2009 4:00:00 AM 2.015327281 1.40342321 Normal 0.69637484 no VAPhilipMorrisPark500 B3 10/18/2009 6:00:00 AM 2.015327281 1.40342321 Normal 0.69637484 no VAPhilipMorrisPark500 B3 10/18/2009 5:00:00 AM 2.031487392 1.414676705 Normal 0.69637484 no WABoeingRenton BOIL04 09/26/09 19:00 0.683305935 0.47583706 normal 0.69637484 no VAPhilipMorrisPark500 B3 10/30/2009 11:00:00 PM 1.038541667 0.723214286 Normal 0.69637484 no VAPhilipMorrisPark500 B3 10/31/2009 1.038541667 0.723214286 Normal 0.69637484 no VAPhilipMorrisPark500 B3 11/1/2009 2:00:00 PM 1.047199066 0.729243081 Normal 0.69637484 no VAPhilipMorrisPark500 B3 10/18/2009 3:00:00 AM 1.999422243 1.392347342 Normal 0.69637484 no VAPhilipMorrisPark500 B3 10/31/2009 1:00:00 AM 1.030026238 0.717284356 Normal 0.69637484 no VAPhilipMorrisPark500 B3 10/31/2009 2:00:00 AM 1.030026238 0.717284356 Normal 0.69637484 no ARDomtarIndustries PB1 9/2/2009 7:00:00 AM 2.540016035 1.769070257 Normal 0.69647996 no TXDibollTemple-Inland PB-44 1902-2002 1.919817883 1.337491383 0.69667618 no ARDomtarIndustries PB1 9/1/2009 3:00:00 AM 3.735539085 2.602508002 Normal 0.69668874 no ARDomtarIndustries PB1 8/30/2009 3:00:00 PM 4.048518981 2.82222347 Normal 0.69710022 no ARDomtarIndustries PB1 8/14/2009 8:00:00 AM 5.082452662 3.544597836 Normal 0.69741876 no ARDomtarIndustries PB1 9/2/2009 5:00:00 AM 2.245902886 1.566533026 Normal 0.69750702 no ARDomtarIndustries PB1 8/22/2009 4:00:00 AM 19.5867508 13.66267718 Normal 0.69754689 no TXDibollTemple-Inland PB-44 2000-2100 2.584126708 1.802585976 0.69756099 no ARDomtarIndustries PB1 8/19/2009 4:00:00 PM 39.69383738 27.69106675 Normal 0.69761627 no ARDomtarIndustries PB1 8/12/2009 9:00:00 PM 26.95565353 18.81945535 Normal 0.69816357 no TXDibollTemple-Inland PB-44 10/15/2009 0000-0100 3.294760287 2.300600917 0.69826049 no WABoeingRenton BOIL04 09/19/09 03:00 29.80774962 20.82071437 normal 0.69850004 no TXDibollTemple-Inland PB-44 0200-0300 2.546752188 1.778910247 0.69850151 no TXDibollTemple-Inland PB-44 1900-2000 2.280703673 1.59422623 0.6990063 no TXDibollTemple-Inland PB-44 1400-1500 2.629462521 1.838704215 0.69926998 no WABoeingRenton BOIL04 08/25/09 16:00 2.611569446 1.826304802 normal 0.69931313 no ARDomtarIndustries PB1 8/13/2009 4:00:00 AM 7.285526711 5.096947471 Normal 0.69959904 no TXDibollTemple-Inland PB-44 1900-2000 4.337752793 3.035390943 0.69976116 no ARDomtarIndustries PB1 8/18/2009 2:00:00 PM 3.883485446 2.717667404 Normal 0.6998011 no ARDomtarIndustries PB1 8/17/2009 1:00:00 PM 6.002837648 4.202602004 Normal 0.70010256 no
ARDomtarIndustries PB1 8/13/2009 11:00:00 AM 13.04653938 9.13447984 Normal 0.70014581 no VAPhilipMorrisPark500 B3 10/16/2009 1:00:00 PM 4.396609936 3.080824089 Normal 0.70072718 no



### Appendix D-4, p53 of 82

## Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC

(ppm@3%O2) CombUnit_O

p_Indicator THC_Op_Ind

icator CO_Op_Indi

cator TNMOC TO

THC Ratio Outlier ARDomtarIndustries PB1 8/19/2009 4:00:00 AM 14.92565437 10.46149573 Normal 0.70090701 no TXDibollTemple-Inland PB-44 0402-0502 2.17386832 1.523812339 0.7009681 no TXDibollTemple-Inland PB-44 2300-2400 2.142934714 1.502594105 0.7011852 no WABoeingRenton BOIL04 08/10/09 21:00 0.624647044 0.438041036 normal 0.70126168 no WABoeingRenton BOIL04 10/06/09 20:00 1.797230093 1.260703468normal 0.70147026 no ARDomtarIndustries PB1 8/20/2009 1:00:00 AM 8.039952504 5.640518292 Normal 0.70156115no TXDibollTemple-Inland PB-44 1100-1200 2.322352713 1.632773829 0.70306884 no TXDibollTemple-Inland PB-44 2100-2200 2.268979715 1.596547162 0.703641 no ARDomtarIndustries PB1 8/20/2009 2:00:00 PM 17.03257536 11.98794919 Normal 0.70382481 no WABoeingRenton BOIL04 09/20/09 08:00 24.02195442 16.91128484 normal 0.70399288 no ARDomtarIndustries PB1 8/16/2009 2:00:00 AM 6.159029701 4.33731799 Normal 0.70422099 no ARDomtarIndustries PB1 8/30/2009 8:00:00 AM 6.593973141 4.645130645 Normal 0.70445095no ARDomtarIndustries PB1 8/13/2009 7:00:00 PM 21.83136671 15.38124931 Normal 0.70454816 no TXDibollTemple-Inland PB-44 1300-1400 2.125609386 1.498130933 0.70480068 no
ARDomtarIndustries PB1 8/18/2009 11:00:00 PM 3.873528896 2.733188816 Normal 0.70560693 no TXDibollTemple-Inland PB-44 10/01/09 0002-0102 2.266261506 1.599663879 0.70586023 no TXDibollTemple-Inland PB-44 1700-1800 3.965094684 2.799746979 0.70609839 no ARDomtarIndustries PB1 8/21/2009 9:00:00 PM 23.97387195 16.93941138 Normal 0.70657804 no TXDibollTemple-Inland PB-44 1900-2000 2.556726511 1.806606129 0.70660906 no TXDibollTemple-Inland PB-44 2202-2302 2.094503921 1.480379446 0.7067924 no ARDomtarIndustries PB1 8/20/2009 5.299593359 3.745892463 Normal 0.70682639 no TXDibollTemple-Inland PB-44 1600-1700 2.558504137 1.81012824 0.70749475no WABoeingRenton BOIL04 09/26/09 14:00 0.671647954 0.475262586 normal 0.70760669 no TXDibollTemple-Inland PB-44 0500-0600 2.641329998 1.869160897 0.70765898 no ARDomtarIndustries PB1 8/14/2009 1:00:00 PM 5.559323533 3.941695075 Normal 0.70902423 no TXDibollTemple-Inland PB-44 0400-0500 2.429034761 1.72231173 0.70905191 no TXDibollTemple-Inland PB-44 1000-1100 3.491370801 2.476064348 0.70919547 no ARDomtarIndustries PB1 9/2/2009 6:00:00 AM 2.417865072 1.715731946 Normal 0.70960616 no TXDibollTemple-Inland PB-44 1900-2000 3.482918074 2.472098961 0.7097781 no ARDomtarIndustries PB1 8/19/2009 5:00:00 PM 24.63395296 17.48566954 Normal 0.70981988 no TXDibollTemple-Inland PB-44 2000-2100 2.382110413 1.691608032 0.71012998 no ARDomtarIndustries PB1 8/29/2009 3:00:00 PM 4.37361392 3.108369386 Normal 0.7107096 no TXDibollTemple-Inland PB-44 0200-0300 2.61683635 1.860532676 0.71098549 no WVDuPontWashingtonWorks P05 10/5/2009 4:00:48 PM 0.807699643 0.574292575 0.71102245no TXDibollTemple-Inland PB-44 1800-1900 4.300611362 3.058582234 0.71119708 no
ARDomtarIndustries PB1 8/12/2009 11:00:00 PM 17.16181247 12.20543403 Normal 0.71119726 no
ARDomtarIndustries PB1 8/13/2009 10:00:00 AM 12.0619829 8.582265461 Normal 10:11 - 10:57 calibration 10:11 - 10:57

calibration 0.71151365no TXDibollTemple-Inland PB-44 0302-0402 2.293415867 1.631956279 0.71158323 no 

### Appendix D-4, p54 of 82

## Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC

(ppm@3%O2) CombUnit_O

p_Indicator THC_Op_Ind

icator CO_Op_Indi

cator TNMOC TO

THC Ratio Outlier
ARDomtarIndustries PB1 8/23/2009 10:00:00 AM 28.08370901 19.9916362 Normal 10:11 - 10:59 calibration 10:11 - 10:59

calibration 0.71185883 no ARDomtarIndustries PB1 8/27/2009 1:00:00 AM 1.699120282 1.20995179 Normal 0.71210485no ARDomtarIndustries PB1 8/20/2009 9:00:00 PM 22.87376431 16.29346389 Normal 0.71232105no VAPhilipMorrisPark500 B3 10/2/2009 9:00:00 AM 3.26259652 2.324420667 Normal 0.71244503 no TXDibollTemple-Inland PB-44 1700-1800 2.457255421 1.750914858 0.71254899 no ARDomtarIndustries PB1 8/14/2009 2:00:00 AM 14.62848969 10.42628114 Normal 0.71273804 no TXDibollTemple-Inland PB-44 2200-2300 3.39675248 2.421307203 0.71283004 no TXDibollTemple-Inland PB-44 2000-2100 5.355215584 3.817704271 0.7128946 no
ARDomtarIndustries PB1 9/2/2009 11:00:00 AM 2.031822426 1.449021138 Normal 0.71316328 no TXDibollTemple-Inland PB-44 0300-0400 2.88359214 2.05790232 0.71365929 no ARDomtarIndustries PB1 8/15/2009 2:00:00 AM 7.586747268 5.415915855 Normal 0.71386533 no ARDomtarIndustries PB1 9/2/2009 8:00:00 AM 2.519443088 1.799244322 Normal 0.71414367 no
ARDomtarIndustries PB1 8/13/2009 10:00:00 PM 13.56532166 9.694433827 Normal 0.71464828 no ARDomtarIndustries PB1 8/19/2009 4.186617317 2.992924633 Normal 0.71487896 no WABoeingRenton BOIL04 09/19/09 16:00 22.51438008 16.09928647 normal 0.71506683 no TXDibollTemple-Inland PB-44 2300-2400 2.829508799 2.023307374 0.71507372 no ARDomtarIndustries PB1 8/22/2009 6:00:00 AM 14.56900843 10.42095811 Normal 0.71528259 no ARDomtarIndustries PB1 8/12/2009 1:00:00 PM 12.74750313 9.119815392 Normal 0.71541974 no
ARDomtarIndustries PB1 8/21/2009 10:00:00 PM 30.8334412 22.06398363 Normal 0.71558616 no TXDibollTemple-Inland PB-44 1700-1800 2.959019138 2.117574429 0.71563391 no WABoeingRenton BOIL04 08/18/09 03:00 2.770055127 1.982579934 normal 0.71571858 no TXDibollTemple-Inland PB-44 2000-2100 5.626969918 4.027346701 0.7157221 no TXDibollTemple-Inland PB-44 1200-1300 1.768553826 1.265843835 0.71575081 no TXDibollTemple-Inland PB-44 1900-2000 4.274389738 3.060074467 0.71590909 no ARDomtarIndustries PB1 8/21/2009 4:00:00 AM 20.68380973 14.808636 Normal 0.71595302 no ARDomtarIndustries PB1 8/13/2009 8:00:00 PM 26.33750716 18.85968814 Normal 0.71607719 no
ARDomtarIndustries PB1 8/12/2009 12:00:00 PM 19.31674086 13.84629828 Normal 0.71680302 no TXDibollTemple-Inland PB-44 0602-0702 2.01038834 1.442061845 0.71730512 no TXDibollTemple-Inland PB-44 1600-1702 1.301910103 0.933870996 0.71730836 no
ARDomtarIndustries PB1 8/26/2009 11:00:00 PM 2.2129258 1.587874398 Normal 0.71754525no TXDibollTemple-Inland PB-44 0500-0600 2.917298924 2.094457829 0.7179442 no ARDomtarIndustries PB1 8/23/2009 9:00:00 AM 22.53579251 16.18093587 Normal 0.71801051 no ARDomtarIndustries PB1 8/20/2009 3:00:00 PM 15.43721567 11.0850499 Normal 0.71807314 no WABoeingRenton BOIL04 09/19/09 06:00 26.7876051 19.23568257 normal 0.71808146 no



### Appendix D-4, p55 of 82

## Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC

(ppm@3%O2) CombUnit_O

p_Indicator THC_Op_Ind

icator CO_Op_Indi

cator TNMOC TO

THC Ratio Outlier TXDibollTemple-Inland PB-44 1700-1800 3.525275013 2.531627208 0.71813609 no ARDomtarIndustries PB1 8/18/2009 4:00:00 PM 5.001181525 3.592139621 Normal 0.7182582 no TXDibollTemple-Inland PB-44 0202-0302 2.199610127 1.580313432 0.71845161 no ARDomtarIndustries PB1 8/13/2009 9.908768414 7.120672209 Normal 0.71862334 no TXDibollTemple-Inland PB-44 1400-1500 3.907151351 2.809156516 0.71897817 no ARDomtarIndustries PB1 8/30/2009 4:00:00 PM 4.651748595 3.347788203 Normal 0.71968382 no ARDomtarIndustries PB1 8/27/2009 1.781722344 1.282470498 Normal 0.71979257 no ARDomtarIndustries PB1 8/19/2009 6:00:00 PM 21.66446186 15.59837899 Normal 0.71999845no ARDomtarIndustries PB1 8/19/2009 3:00:00 AM 6.585979821 4.745431636 Normal 0.7205354 no ARDomtarIndustries PB1 8/20/2009 7:00:00 PM 23.93593274 17.25283539 Normal 0.72079227 no ARDomtarIndustries PB1 8/29/2009 2:00:00 PM 4.568996221 3.293692057 Normal 0.7208787 no TXDibollTemple-Inland PB-44 1700-1800 2.030581478 1.464069609 0.72101003 no
ARDomtarIndustries PB1 8/20/2009 10:00:00 PM 22.05619229 15.90401316 Normal 0.72106794 no TXDibollTemple-Inland PB-44 2100-2200 2.061306611 1.488185756 0.72196235no
ARDomtarIndustries PB1 8/25/2009 10:00:00 PM 2.105921131 1.520583854 Normal 0.72205166 no VAPhilipMorrisPark500 B3 10/16/2009 12:00:00 PM 3.796107545 2.741421697 Normal 0.7221665no VAPhilipMorrisPark500 B3 10/2/2009 7:00:00 AM 3.435732205 2.4811707 Normal 0.7221665no TXDibollTemple-Inland PB-44 1400-1500 3.936020288 2.844649799 0.72272234 no WABoeingRenton BOIL04 08/10/09 22:00 0.635605765 0.459408891 normal 0.72278906 no ARDomtarIndustries PB1 8/13/2009 6:00:00 AM 22.06025548 15.94804888 Normal 0.72293129 no ARDomtarIndustries PB1 8/22/2009 5:00:00 AM 21.03805918 15.20965223 Normal 0.7229589no TXDibollTemple-Inland PB-44 1800-1900 2.715688281 1.963364637 0.72297128 no TXDibollTemple-Inland PB-44 1200-1300 4.96818 3.592076209 0.72301652 no TXDibollTemple-Inland PB-44 0102-0202 2.255544685 1.630831382 0.72303218 no TXDibollTemple-Inland PB-44 2000-2100 2.468296575 1.785136164 0.72322596 no VAPhilipMorrisPark500 B3 10/2/2009 3:00:00 AM 3.944729569 2.853346305 Normal 0.72333128 no VAPhilipMorrisPark500 B3 10/2/2009 4:00:00 AM 3.944729569 2.853346305 Normal 0.72333128 no VAPhilipMorrisPark500 B3 10/1/2009 10:00:00 PM 3.97266466 2.87355263 Normal 0.72333128 no ARDomtarIndustries PB1 9/2/2009 4:00:00 AM 2.616471385 1.892704484 Normal 0.72338054 no TXDibollTemple-Inland PB-44 1100-1200 3.063345869 2.217251441 0.72380056 no TXDibollTemple-Inland PB-44 0900-1000 2.946046467 2.132643495 0.72390016 no TXDibollTemple-Inland PB-44 1100-1200 3.240014858 2.345693237 0.72397607 no TXDibollTemple-Inland PB-44 0802-0902 1.724344168 1.249225561 0.72446417 no
ARDomtarIndustries PB1 8/20/2009 10:00:00 AM 5.690744065 4.124292299 Normal 10:06 - 10:59 calibration 10:06 - 10:59

calibration 0.72473692 no ARDomtarIndustries PB1 8/15/2009 6:00:00 AM 6.037148403 4.376056692 Normal 0.72485491 no ARDomtarIndustries PB1 8/20/2009 8:00:00 PM 20.99846665 15.22588314 Normal 0.725095no



### Appendix D-4, p56 of 82

## Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC

(ppm@3%O2) CombUnit_O

p_Indicator THC_Op_Ind

icator CO_Op_Indi

cator TNMOC TO

THC Ratio Outlier TXDibollTemple-Inland PB-44 0600-0700 5.222318689 3.790321967 0.72579293 no ARDomtarIndustries PB1 8/12/2009 5:00:00 PM 12.97626059 9.418764211 Normal 0.7258458no TXDibollTemple-Inland PB-44 1700-1800 2.627159912 1.90724068 0.72597053 no TXDibollTemple-Inland PB-44 1300-1400 2.745697952 1.993862901 0.72617707 no ARDomtarIndustries PB1 8/20/2009 4:00:00 PM 20.48231144 14.87940319 Normal 0.72645137 no
ARDomtarIndustries PB1 8/19/2009 10:00:00 PM 3.593980575 2.610978152 Normal 0.72648644 no WABoeingRenton BOIL04 08/27/09 04:00 4.487597212 3.262582539normal 0.72702214 no ARDomtarIndustries PB1 8/17/2009 2:00:00 PM 5.24286996 3.812719258 Normal 0.72721988 no TXDibollTemple-Inland PB-44 0700-0800 2.317837542 1.686284624 0.72752494 no ARDomtarIndustries PB1 8/22/2009 7:00:00 AM 13.41906065 9.76578033 Normal 0.72775439 no TXDibollTemple-Inland PB-44 2100-2200 2.692921635 1.959982195 0.72782742 no ARDomtarIndustries PB1 8/22/2009 3:00:00 AM 19.38016238 14.11066352 Normal 0.72809831 no TXDibollTemple-Inland PB-44 1700-1800 2.540082351 1.85036571 0.72846682 no ARDomtarIndustries PB1 8/15/2009 8:00:00 AM 7.915008647 5.767155962 Normal 0.72863546 no ARDomtarIndustries PB1 8/30/2009 5:00:00 PM 2.592972936 1.889345184 Normal 0.72864053 no TXDibollTemple-Inland PB-44 2200-2300 2.228119389 1.623534705 0.72865696 no TXDibollTemple-Inland PB-44 0502-0602 2.18256808 1.590558392 0.72875545no TXDibollTemple-Inland PB-44 1700-1800 2.782699275 2.02823075 0.7288717 no ARDomtarIndustries PB1 8/14/2009 1:00:00 AM 12.89282728 9.398982746 Normal 0.72900866 no TXDibollTemple-Inland PB-44 1000-1100 2.362397213 1.722685487 0.72921077 no TXDibollTemple-Inland PB-44 0500-0600 2.569483083 1.876016902 0.73011452 no WABoeingRenton BOIL04 09/19/09 01:00 25.54088701 18.64967265normal 0.73018892 no TXDibollTemple-Inland PB-44 1200-1300 2.923347305 2.135078262 0.73035395no ARDomtarIndustries PB1 8/23/2009 8:00:00 PM 20.02732138 14.63193765 Normal 0.73059883 no
ARDomtarIndustries PB1 8/29/2009 11:00:00 PM 6.778002993 4.95277744 Normal 0.73071337 no WABoeingRenton BOIL04 08/23/09 08:00 0.088100147 0.064418262 normal 0.73119358 no VAPhilipMorrisPark500 B3 11/1/2009 0.572166428 0.418364419 Normal 0.73119358 no VAPhilipMorrisPark500 B3 10/31/2009 12:00:00 PM 0.576763619 0.421725856 Normal 0.73119358 no VAPhilipMorrisPark500 B3 10/2/2009 6:00:00 AM 3.538099731 2.587035811 Normal 0.73119358 no VAPhilipMorrisPark500 B3 11/2/2009 11:00:00 AM 0.572848586 0.418863209 Normal 0.73119358 no TXDibollTemple-Inland PB-44 2200-2300 2.300778074 1.682318361 0.73119541 no TXDibollTemple-Inland PB-44 2000-2100 53.31928174 38.99145677 0.73128248 no ARDomtarIndustries PB1 8/12/2009 8:00:00 PM 44.37787305 32.45396902 Normal 0.7313097 no ARDomtarIndustries PB1 8/15/2009 7.232285807 5.289733752 Normal 0.73140552 no
ARDomtarIndustries PB1 8/14/2009 10:00:00 AM 9.738092406 7.123063251 Normal 10:05 - 10:52 calibration 10:05 - 10:52

calibration 0.73146392 no ARDomtarIndustries PB1 8/22/2009 1:00:00 PM 100.4400879 73.51851644 Normal 0.73196388 no



### Appendix D-4, p57 of 82

## Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC

(ppm@3%O2) CombUnit_O

p_Indicator THC_Op_Ind

icator CO_Op_Indi

cator TNMOC TO

THC Ratio Outlier TXDibollTemple-Inland PB-44 1800-1900 2.550617515 1.86809336 0.73240827 no TXDibollTemple-Inland PB-44 1300-1400 3.223946902 2.362458276 0.73278449 no ARDomtarIndustries PB1 8/13/2009 5:00:00 AM 115.961673 85.01471558 Normal 0.73312771 no TXDibollTemple-Inland PB-44 2000-2100 2.252186851 1.651145842 0.73313004 no ARDomtarIndustries PB1 8/12/2009 3:00:00 PM 10.4143334 7.635761382 Normal 0.73319732 no ARDomtarIndustries PB1 8/23/2009 4:00:00 PM 31.03134006 22.76313521 Normal 0.73355308 no WABoeingRenton BOIL04 08/26/09 17:00 4.022982456 2.952236842 normal 0.73384283 no ARDomtarIndustries PB1 8/31/2009 9:00:00 PM 3.732840049 2.740598672 Normal 0.73418594 no TXDibollTemple-Inland PB-44 1900-2000 2.514451786 1.846209723 0.73423946 no TXDibollTemple-Inland PB-44 0900-1000 2.761331625 2.027699612 0.73431948 no TXDibollTemple-Inland PB-44 1400-1500 2.447162638 1.797398266 0.73448255no TXDibollTemple-Inland PB-44 1100-1200 2.452936843 1.801645246 0.73448497 no
ARDomtarIndustries PB1 8/29/2009 12:00:00 PM 4.954991961 3.639865505 Normal 0.73458555no TXDibollTemple-Inland PB-44 1300-1400 2.643498396 1.941901285 0.73459522 no ARDomtarIndustries PB1 8/13/2009 9:00:00 PM 15.72872695 11.55501554 Normal 0.73464404 no TXDibollTemple-Inland PB-44 1600-1700 2.117408899 1.555862358 0.73479542 no ARDomtarIndustries PB1 8/13/2009 7:00:00 AM 12.06281477 8.86779692 Normal 0.73513497 no WVDuPontWashingtonWorks P05 9/23/2009 1:00:25 PM 0.308071028 0.226511849 0.73525852 no ARDomtarIndustries PB1 8/20/2009 5:00:00 PM 23.11955508 16.99899474 Normal 0.73526479 no TXDibollTemple-Inland PB-44 0702-0802 2.478437714 1.8235158 0.73575212 no TXDibollTemple-Inland PB-44 2100-2200 2.554638385 1.880795142 0.73622754 no TXDibollTemple-Inland PB-44 1400-1500 3.131114152 2.305282203 0.73624981 no ARDomtarIndustries PB1 8/17/2009 3:00:00 PM 4.120351023 3.034772334 Normal 0.73653247 no TXDibollTemple-Inland PB-44 1800-1900 2.455497962 1.809399973 0.736877 no ARDomtarIndustries PB1 8/23/2009 3:00:00 PM 80.02312942 58.99619298 Normal 0.73723926 no WABoeingRenton BOIL04 08/18/09 06:00 2.201358477 1.622965947 normal 0.73725655no ARDomtarIndustries PB1 8/22/2009 8:00:00 PM 34.67575415 25.57654145 Normal 0.7375915no ARDomtarIndustries PB1 8/23/2009 5:00:00 PM 37.10191047 27.36726625 Normal 0.73762418 no TXDibollTemple-Inland PB-44 0400-0500 2.335751743 1.723973079 0.73808061 no ARDomtarIndustries PB1 8/15/2009 9:00:00 AM 7.343223337 5.419959985 Normal 0.73809004 no ARDomtarIndustries PB1 8/13/2009 1:00:00 AM 10.69888342 7.89701231 Normal 0.73811556 no TXDibollTemple-Inland PB-44 1900-2000 2.267388008 1.674150149 0.73836068 no
ARDomtarIndustries PB1 8/15/2009 10:00:00 AM 7.206460303 5.322830536 Normal 10:06 - 10:55 calibration 10:06 - 10:55

calibration 0.73861928 no
ARDomtarIndustries PB1 8/13/2009 11:00:00 PM 13.2849244 9.813321578 Normal 0.73868103 no TXDibollTemple-Inland PB-44 1500-1600 3.065228869 2.264371006 0.7387282 no TXDibollTemple-Inland PB-44 0800-0900 3.22132439 2.380079041 0.73885109 no TXDibollTemple-Inland PB-44 1000-1100 2.333578475 1.724416303 0.73895792 no ARDomtarIndustries PB1 8/14/2009 12.49680752 9.237203513 Normal 0.73916506 no


### Appendix D-4, p58 of 82

## Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC

(ppm@3%O2) CombUnit_O

p_Indicator THC_Op_Ind

icator CO_Op_Indi

cator TNMOC TO

THC Ratio Outlier ARDomtarIndustries PB1 8/23/2009 3:00:00 AM 18.15767865 13.42529287 Normal 0.73937275no TXDibollTemple-Inland PB-44 10/16/2009 0000-0100 3.369191717 2.4918493 0.73959855no ARDomtarIndustries PB1 8/30/2009 9:00:00 PM 2.763381423 2.043993381 Normal 0.7396711 no ARDomtarIndustries PB1 8/23/2009 6:00:00 PM 53.92637836 39.90181641 Normal 0.73993132 no TXDibollTemple-Inland PB-44 1600-1700 3.005372919 2.224039311 0.74002108 no TXDibollTemple-Inland PB-44 1400-1500 2.158649666 1.598013175 0.74028371 no TXDibollTemple-Inland PB-44 1300-1400 2.950560348 2.185687694 0.74077037 no
ARDomtarIndustries PB1 8/14/2009 11:00:00 PM 5.767316501 4.272811096 Normal 0.74086641 no TXDibollTemple-Inland PB-44 2100-2200 2.458906768 1.822466986 0.74116962 no TXDibollTemple-Inland PB-44 1300-1400 2.303654717 1.707465544 0.74119855no TXDibollTemple-Inland PB-44 1300-1400 2.440298137 1.808962703 0.74128758 no ARDomtarIndustries PB1 8/19/2009 2:00:00 AM 5.062100895 3.752550109 Normal 0.74130291 no TXDibollTemple-Inland PB-44 1200-1300 3.037398654 2.251723822 0.74133299 no ARDomtarIndustries PB1 9/1/2009 2.783075162 2.065379121 Normal 0.74212121 no ARDomtarIndustries PB1 8/22/2009 9:00:00 AM 15.48769761 11.50210928 Normal 0.74266102 no TXDibollTemple-Inland PB-44 1100-1200 3.35571657 2.49245247 0.74274821 no TXDibollTemple-Inland PB-44 0300-0400 5.519512719 4.101717621 0.74313039 no TXDibollTemple-Inland PB-44 1400-1500 2.591732479 1.927405639 0.74367461 no ARDomtarIndustries PB1 8/19/2009 9:00:00 PM 4.228758337 3.145628438 Normal 0.74386574 no TXDibollTemple-Inland PB-44 1100-1200 4.03623261 3.002908683 0.74398801 no WVDuPontWashingtonWorks P05 10/20/2009 9:00:04 AM 0.558387479 0.415508167 0.74412157 no ARDomtarIndustries PB1 8/14/2009 7:00:00 PM 6.267720948 4.665196011 Normal 0.74432095no WABoeingRenton BOIL04 08/11/09 21:00 0.974136375 0.725620883 normal 0.74488634 no VAPhilipMorrisPark500 B3 10/1/2009 8:00:00 AM 13.7344516 10.23945545 Normal 0.74553071 no TXDibollTemple-Inland PB-44 0400-0500 2.265500122 1.689604683 0.74579766 no TXDibollTemple-Inland PB-44 2200-2300 3.004988894 2.243126874 0.74646761 no TXDibollTemple-Inland PB-44 0300-0400 2.483062279 1.854845446 0.74699916 no WABoeingRenton BOIL04 08/15/09 14:00 0.842792144 0.629582825normal 0.74702028 no TXDibollTemple-Inland PB-44 0100-0200 2.181577108 1.630260903 0.74728548 no TXDibollTemple-Inland PB-44 1200-1300 2.394071911 1.789457439 0.7474535no
ARDomtarIndustries PB1 8/22/2009 11:00:00 AM 21.43548324 16.03074186 Normal 0.74786006 no TXDibollTemple-Inland PB-44 1000-1100 2.517376863 1.882672541 0.74787076 no TXDibollTemple-Inland PB-44 0800-0900 2.892729274 2.164369171 0.74821007 no ARDomtarIndustries PB1 8/18/2009 3.300694356 2.470095157 Normal 0.74835622 no
ARDomtarIndustries PB1 8/31/2009 11:00:00 AM 3.798303843 2.843056076 Normal 0.74850675no ARDomtarIndustries PB1 8/13/2009 2:00:00 AM 7.504505577 5.618913562 Normal 0.74873867 no TXDibollTemple-Inland PB-44 1500-1600 2.239141002 1.676849319 0.74888063 no ARDomtarIndustries PB1 8/19/2009 8:00:00 PM 4.172114707 3.126602325 Normal 0.74940469 no ARDomtarIndustries PB1 8/23/2009 2:00:00 PM 19.71699874 14.77978283 Normal 0.74959597 no



### Appendix D-4, p59 of 82

## Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC

(ppm@3%O2) CombUnit_O

p_Indicator THC_Op_Ind

icator CO_Op_Indi

cator TNMOC TO

THC Ratio Outlier WABoeingRenton BOIL04 10/10/09 02:00 0.573002579 0.429718777 normal 0.74994213 no TXDibollTemple-Inland PB-44 1500-1600 3.441417444 2.580959513 0.7499699no TXDibollTemple-Inland PB-44 0500-0600 2.335398936 1.75205993 0.75021869 no
ARDomtarIndustries PB1 8/22/2009 10:00:00 AM 16.31089481 12.24209414 Normal 10:08 - 10:59 calibration 10:08 - 10:59

calibration 0.75054706 no ARDomtarIndustries PB1 8/31/2009 2:00:00 AM 3.007164689 2.257366363 Normal 0.7506627 no ARDomtarIndustries PB1 8/30/2009 7:00:00 PM 2.581945959 1.938806475 Normal 0.75090901 no TXDibollTemple-Inland PB-44 0300-0400 2.286160808 1.716918044 0.75100493 no TXDibollTemple-Inland PB-44 0500-0600 2.399396465 1.801961954 0.75100634 no TXDibollTemple-Inland PB-44 1300-1400 3.249103697 2.440144707 0.75102088 no TXDibollTemple-Inland PB-44 1200-1300 2.253863006 1.69275993 0.75104828 no TXDibollTemple-Inland PB-44 10/09/2009 0000-0100 2.31939041 1.743009127 0.7514945no TXDibollTemple-Inland PB-44 1900-2000 2.024569082 1.521571766 0.75155339 no TXDibollTemple-Inland PB-44 0600-0700 3.293814026 2.475493314 0.75155831 no ARDomtarIndustries PB1 8/13/2009 3:00:00 PM 5.08249807 3.823091477 Normal 0.75220717 no TXDibollTemple-Inland PB-44 0700-0800 2.815661152 2.118299506 0.75232757 no TXDibollTemple-Inland PB-44 0500-0600 2.931158263 2.205839564 0.75254878 no TXDibollTemple-Inland PB-44 2200-2300 2.371093001 1.784839087 0.75274951 no ARDomtarIndustries PB1 8/13/2009 3:00:00 AM 6.626004215 4.995026285 Normal 0.75385196 no TXDibollTemple-Inland PB-44 1800-1900 2.741585389 2.068535524 0.75450341 no ARDomtarIndustries PB1 8/14/2009 9:00:00 PM 5.704438204 4.305952992 Normal 0.7548426 no ARDomtarIndustries PB1 8/23/2009 7:00:00 PM 56.93253212 42.97785193 Normal 0.75489093 no ARDomtarIndustries PB1 8/15/2009 1:00:00 AM 8.312290956 6.275376458 Normal 0.75495149 no ARDomtarIndustries PB1 8/15/2009 7:00:00 AM 6.275216117 4.738403656 Normal 0.75509808 no TXDibollTemple-Inland PB-44 1500-1600 2.233890642 1.687264205 0.75530296 no TXDibollTemple-Inland PB-44 2200-2300 2.9091894 2.197522839 0.7553729no TXDibollTemple-Inland PB-44 1200-1300 2.675445088 2.021020248 0.7553959no ARDomtarIndustries PB1 8/29/2009 9:00:00 AM 3.142919626 2.375385958 Normal 0.7557896 no WABoeingRenton BOIL04 09/18/09 23:00 23.36059591 17.66462623 normal 0.7561719no TXDibollTemple-Inland PB-44 1800-1900 2.288170761 1.730292644 0.75619035no VAPhilipMorrisPark500 B3 10/1/2009 7:00:00 AM 14.62628451 11.06112852 Normal 0.75625006 no ARDomtarIndustries PB1 8/24/2009 9:00:00 AM 3.389855211 2.56374344 Normal 0.7562988no TXDibollTemple-Inland PB-44 2000-2100 2.249908771 1.7020386 0.75649227 no TXDibollTemple-Inland PB-44 1700-1800 1.933585958 1.463987891 0.75713618 no TXDibollTemple-Inland PB-44 1100-1200 3.041022863 2.304323224 0.7577461 no VAPhilipMorrisPark500 B3 10/2/2009 8:00:00 AM 3.435732205 2.605229235 Normal 0.75827482 no TXDibollTemple-Inland PB-44 2200-2300 2.72335197 2.065294068 0.75836472 no TXDibollTemple-Inland PB-44 2200-2300 2.715694547 2.060226431 0.75863702 no ARDomtarIndustries PB1 8/30/2009 8:00:00 PM 3.266316534 2.477985597 Normal 0.75864833 no TXDibollTemple-Inland PB-44 1400-1500 3.234583021 2.454124907 0.75871446 no TXDibollTemple-Inland PB-44 2200-2300 3.003480677 2.279404239 0.75892089 no TXDibollTemple-Inland PB-44 1400-1500 2.235154214 1.696342704 0.75893766 no



### Appendix D-4, p60 of 82

## Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC

(ppm@3%O2) CombUnit_O

p_Indicator THC_Op_Ind

icator CO_Op_Indi

cator TNMOC TO

THC Ratio Outlier ARDomtarIndustries PB1 8/17/2009 4:00:00 PM 4.266581249 3.239552924 Normal 0.75928542 no WABoeingRenton BOIL04 09/20/09 23:00 17.99213368 13.66683337 normal 0.75960048 no TXDibollTemple-Inland PB-44 2200-2300 2.558274943 1.94347242 0.75968083 no
ARDomtarIndustries PB1 8/12/2009 10:00:00 PM 8.711712225 6.618872694 Normal 0.75976714 no TXDibollTemple-Inland PB-44 0400-0500 2.870668606 2.181544349 0.75994294 no WABoeingRenton BOIL04 09/19/09 00:00 22.97332824 17.45896272 normal 0.75996662 no ARDomtarIndustries PB1 8/17/2009 5:00:00 PM 4.748230794 3.610056396 Normal 0.76029506 no TXDibollTemple-Inland PB-44 1500-1600 2.233890642 1.699529131 0.76079334 no ARDomtarIndustries PB1 8/13/2009 4:00:00 PM 5.391714733 4.102038033 Normal 0.76080398 no WABoeingRenton BOIL04 09/20/09 13:00 18.89275581 14.38211259normal 0.76125012 no WABoeingRenton BOIL04 09/20/09 11:00 18.97808573 14.45258857 normal 0.7615409no TXDibollTemple-Inland PB-44 0200-0300 2.877247357 2.191416743 0.76163655no TXDibollTemple-Inland PB-44 1300-1400 2.823947987 2.151971363 0.76204355no ARDomtarIndustries PB1 8/14/2009 8:00:00 PM 6.008179518 4.579636378 Normal 0.76223361 no TXDibollTemple-Inland PB-44 2300-2400 2.84143575 2.166224021 0.76236952 no TXDibollTemple-Inland PB-44 0200-0300 2.845424751 2.169367627 0.76240555no TXDibollTemple-Inland PB-44 1600-1700 2.79132695 2.129612429 0.76293908 no ARDomtarIndustries PB1 8/26/2009 2.839089409 2.166516166 Normal 0.76310248 no TXDibollTemple-Inland PB-44 1200-1300 3.475318881 2.653148468 0.76342591 no TXDibollTemple-Inland PB-44 1400-1500 2.955472044 2.257172412 0.76372653 no VAPhilipMorrisPark500 B3 10/1/2009 6:00:00 AM 15.89654826 12.14703305 Normal 0.76413023 no TXDibollTemple-Inland PB-44 1500-1600 2.949747662 2.254702483 0.76437131 no TXDibollTemple-Inland PB-44 0100-0200 2.69740269 2.062025774 0.76444862 no ARDomtarIndustries PB1 8/19/2009 7:00:00 PM 4.895176802 3.742375116 Normal 0.76450254 no TXDibollTemple-Inland PB-44 0600-0700 3.575393723 2.734439856 0.76479405no TXDibollTemple-Inland PB-44 1900-2000 2.80250001 2.1434344 0.7648294 no ARDomtarIndustries PB1 8/30/2009 9:00:00 AM 6.235404562 4.769140545 Normal 0.76484862 no TXDibollTemple-Inland PB-44 0100-0200 2.588158864 1.979671582 0.7648957 no
ARDomtarIndustries PB1 8/30/2009 11:00:00 PM 3.394122386 2.596613829 Normal 0.76503247 no ARDomtarIndustries PB1 8/23/2009 5:00:00 AM 15.790948 12.08745762 Normal 0.76546751 no TXDibollTemple-Inland PB-44 0900-1000 3.144466191 2.407567269 0.76565214 no TXDibollTemple-Inland PB-44 1400-1500 2.649810602 2.029288654 0.76582404 no TXDibollTemple-Inland PB-44 0400-0500 6.587498575 5.045661457 0.76594498 no TXDibollTemple-Inland PB-44 0600-0700 2.706110353 2.072759751 0.76595537 no VAPhilipMorrisPark500 B3 10/1/2009 8:00:00 PM 3.588213241 2.748615559 Normal 0.76601232 no VAPhilipMorrisPark500 B3 10/2/2009 5:00:00 AM 3.538099731 2.710227993 Normal 0.76601232 no VAPhilipMorrisPark500 B3 10/1/2009 9:00:00 PM 3.562981546 2.72928777 Normal 0.76601232 no VAPhilipMorrisPark500 B3 10/1/2009 7:00:00 PM 3.613804848 2.768219046 Normal 0.76601232 no TXDibollTemple-Inland PB-44 0700-0800 3.186114108 2.440763403 0.76606277 no



### Appendix D-4, p61 of 82

## Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC

(ppm@3%O2) CombUnit_O

p_Indicator THC_Op_Ind

icator CO_Op_Indi

cator TNMOC TO

THC Ratio Outlier
ARDomtarIndustries PB1 8/22/2009 12:00:00 PM 21.42296644 16.41368042 Normal 0.76617216 no TXDibollTemple-Inland PB-44 0800-0900 3.530816633 2.705608004 0.76628392 no TXDibollTemple-Inland PB-44 0800-0900 7.636648579 5.854898127 0.76668424 no TXDibollTemple-Inland PB-44 1700-1800 2.866005 2.19746338 0.76673397 no TXDibollTemple-Inland PB-44 2300-2400 2.563746941 1.965919523 0.76681497 no TXDibollTemple-Inland PB-44 0800-0900 2.222560479 1.705033923 0.76714849 no VAPhilipMorrisPark500 B3 10/1/2009 9:00:00 AM 16.20828577 12.43424998 Normal 0.76715392 no ARDomtarIndustries PB1 8/13/2009 5:00:00 PM 5.315756582 4.080565819 Normal 0.76763594 no TXDibollTemple-Inland PB-44 10/29/2009 0000-0100 2.570510587 1.974129238 0.76799109 no TXDibollTemple-Inland PB-44 1600-1700 2.876477516 2.209747337 0.76821297 no TXDibollTemple-Inland PB-44 2100-2200 2.950417269 2.267015905 0.76837128 no TXDibollTemple-Inland PB-44 1700-1800 3.89387935 2.992623929 0.76854562 no TXDibollTemple-Inland PB-44 1000-1100 2.260143233 1.737052846 0.76855874 no ARDomtarIndustries PB1 8/17/2009 9:00:00 PM 2.999174206 2.305909675 Normal 0.7688482 no TXDibollTemple-Inland PB-44 1400-1500 2.49910845 1.92249573 0.76927263 no ARDomtarIndustries PB1 8/17/2009 8:00:00 PM 3.62651695 2.790362489 Normal 0.76943319 no TXDibollTemple-Inland PB-44 1900-2000 5.162944185 3.974969624 0.76990366 no ARDomtarIndustries PB1 8/13/2009 6:00:00 PM 5.070048359 3.903782794 Normal 0.76996954 no
ARDomtarIndustries PB1 8/14/2009 10:00:00 PM 5.382621728 4.146918043 Normal 0.77042717 no TXDibollTemple-Inland PB-44 1800-1900 3.147113959 2.424634208 0.77043102 no TXDibollTemple-Inland PB-44 1900-2000 2.41435731 1.860102628 0.77043386 no TXDibollTemple-Inland PB-44 2000-2100 2.940024953 2.265158027 0.77045537 no ARDomtarIndustries PB1 8/22/2009 9:00:00 PM 33.35577102 25.70503309 Normal 0.77063226 no ARDomtarIndustries PB1 8/23/2009 4:00:00 AM 20.16611166 15.54373522 Normal 0.77078494 no TXDibollTemple-Inland PB-44 2300-2400 2.777101793 2.140917131 0.77091777 no TXDibollTemple-Inland PB-44 0600-0700 2.546752188 1.96416653 0.77124368 no
ARDomtarIndustries PB1 8/29/2009 10:00:00 PM 5.595828791 4.315987781 Normal 0.7712866 no TXDibollTemple-Inland PB-44 0100-0200 2.847731583 2.197195569 0.77155993 no TXDibollTemple-Inland PB-44 2200-2300 2.855055193 2.203000401 0.77161395no VAPhilipMorrisPark500 B3 10/1/2009 4:00:00 PM 3.11980008 2.407909891 Normal 0.77181545no VAPhilipMorrisPark500 B3 10/2/2009 10:00:00 AM 3.038643396 2.345271909 Normal 0.77181545no
ARDomtarIndustries PB1 8/17/2009 11:00:00 PM 3.748819946 2.893606079 Normal 0.77187118 no TXDibollTemple-Inland PB-44 1500-1600 2.499615703 1.929396992 0.77187745no
ARDomtarIndustries PB1 8/22/2009 11:00:00 PM 31.93334172 24.64921547 Normal 0.7718959no TXDibollTemple-Inland PB-44 2100-2200 4.033981347 3.113981831 0.77193759 no TXDibollTemple-Inland PB-44 11/01/2009 0000-0100 2.728242925 2.106638589 0.77215946 no WABoeingRenton BOIL04 08/16/09 12:00 1.110900956 0.857857318normal 0.77221764 no



### Appendix D-4, p62 of 82

## Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC

(ppm@3%O2) CombUnit_O

p_Indicator THC_Op_Ind

icator CO_Op_Indi

cator TNMOC TO

THC Ratio Outlier TXDibollTemple-Inland PB-44 2000-2100 2.821565617 2.179064633 0.77228919 no TXDibollTemple-Inland PB-44 2000-2100 5.359336946 4.139122192 0.77231983 no TXDibollTemple-Inland PB-44 2100-2200 2.767968767 2.138298276 0.77251532 no TXDibollTemple-Inland PB-44 1600-1700 3.575750487 2.764004492 0.77298584 no
ARDomtarIndustries PB1 8/22/2009 10:00:00 PM 36.8064935 28.45215398 Normal 0.77301996 no TXDibollTemple-Inland PB-44 1600-1700 2.303654717 1.780885971 0.77306983 no ARDomtarIndustries PB1 8/22/2009 8:00:00 AM 13.21181454 10.2146695 Normal 0.7731466 no VAPhilipMorrisPark500 B3 10/1/2009 11:00:00 PM 3.690230887 2.853346305 Normal 0.7732162 no VAPhilipMorrisPark500 B3 10/2/2009 2:00:00 AM 3.690230887 2.853346305 Normal 0.7732162 no ARDomtarIndustries PB1 8/18/2009 1:00:00 AM 3.631765955 2.808756423 Normal 0.77338586 no ARDomtarIndustries PB1 8/23/2009 1:00:00 PM 17.92425358 13.86350226 Normal 0.77344935no WABoeingRenton BOIL04 08/11/09 17:00 1.329251959 1.028168462 normal 0.77349404 no TXDibollTemple-Inland PB-44 0400-0500 3.061787451 2.36877148 0.77365641 no TXDibollTemple-Inland PB-44 0400-0500 4.444590446 3.438951887 0.77373876 no
ARDomtarIndustries PB1 8/17/2009 10:00:00 PM 3.764423885 2.912918952 Normal 0.77380206 no TXDibollTemple-Inland PB-44 2300-2400 2.558274943 1.980182633 0.77403042 no
ARDomtarIndustries PB1 8/23/2009 11:00:00 AM 19.94174441 15.44983976 Normal 0.77474866 no TXDibollTemple-Inland PB-44 1800-1900 1.85036774 1.433654438 0.77479433 no ARDomtarIndustries PB1 8/22/2009 3:00:00 PM 18.42247476 14.27433922 Normal 0.77483288 no TXDibollTemple-Inland PB-44 2300-2400 2.88366331 2.23460803 0.77491988 no TXDibollTemple-Inland PB-44 0300-0400 2.925536604 2.267334786 0.77501501 no TXDibollTemple-Inland PB-44 1200-1300 2.889272558 2.239369811 0.77506354 no TXDibollTemple-Inland PB-44 0700-0800 2.563977681 1.987332464 0.77509741 no TXDibollTemple-Inland PB-44 0100-0200 3.352812146 2.599726655 0.77538691 no TXDibollTemple-Inland PB-44 2300-2400 2.371093001 1.838592699 0.7754199no TXDibollTemple-Inland PB-44 1200-1300 2.854503268 2.216112892 0.77635675no ARDomtarIndustries PB1 8/23/2009 9:00:00 PM 22.48194382 17.45801572 Normal 0.77653498 no WABoeingRenton BOIL04 09/26/09 15:00 0.639534912 0.49668519 normal 0.77663499 no TXDibollTemple-Inland PB-44 2300-2400 5.140274251 3.992168184 0.77664498 no TXDibollTemple-Inland PB-44 11/03/2009 0000-0100 3.484706777 2.706440281 0.77666227 no ARDomtarIndustries PB1 8/24/2009 8:00:00 PM 2.725591731 2.118023996 Normal 0.77708777 no ARDomtarIndustries PB1 8/14/2009 6:00:00 PM 7.781321338 6.049069953 Normal 0.77738339 no WABoeingRenton BOIL04 08/18/09 05:00 1.732535745 1.346997434 normal 0.77747166 no ARDomtarIndustries PB1 8/17/2009 7:00:00 PM 3.701770367 2.87822262 Normal 0.77752598 no TXDibollTemple-Inland PB-44 0300-0400 2.77464645 2.157643872 0.7776284 no ARDomtarIndustries PB1 8/22/2009 7:00:00 PM 21.53763427 16.74934696 Normal 0.77767812 no TXDibollTemple-Inland PB-44 0400-0500 6.217324759 4.835337431 0.77771994 no TXDibollTemple-Inland PB-44 0100-0200 2.282986665 1.775934717 0.77789973 no


### Appendix D-4, p63 of 82

## Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC

(ppm@3%O2) CombUnit_O

p_Indicator THC_Op_Ind

icator CO_Op_Indi

cator TNMOC TO

THC Ratio Outlier TXDibollTemple-Inland PB-44 1900-2000 2.763895492 2.150530312 0.77807946 no TXDibollTemple-Inland PB-44 2000-2100 4.061319182 3.160222937 0.7781272 no TXDibollTemple-Inland PB-44 1000-1100 3.540912905 2.756638217 0.7785106 no TXDibollTemple-Inland PB-44 0500-0600 2.856854045 2.224446399 0.77863495no TXDibollTemple-Inland PB-44 09/30/2009 0000-0100 2.597058008 2.023219126 0.77904272 no TXDibollTemple-Inland PB-44 0900-1000 2.239759409 1.745869392 0.7794897 no TXDibollTemple-Inland PB-44 0600-0700 4.135952975 3.224192952 0.77955261 no VAPhilipMorrisPark500 B3 10/1/2009 3:00:00 PM 3.24979175 2.534641991 Normal 0.77993982 no VAPhilipMorrisPark500 B3 10/1/2009 5:00:00 PM 3.24979175 2.534641991 Normal 0.77993982 no WABoeingRenton BOIL04 08/23/09 07:00 0.110192804 0.085943755normal 0.77993982 no CATesoro S-974 Furance 55 9/18/2009 0.118019203 0.092047876 None 12:58-13:30 12:58-13:30 0.77993982 no VAPhilipMorrisPark500 B3 11/1/2009 2:00:00 AM 0.726794103 0.566855662 Normal 0.77993982 no TXDibollTemple-Inland PB-44 0500-0600 3.45993293 2.702062385 0.78095802 no TXDibollTemple-Inland PB-44 1000-1100 2.778637624 2.170542171 0.78115338 no TXDibollTemple-Inland PB-44 1000-1100 3.150016068 2.461630002 0.78146586 no TXDibollTemple-Inland PB-44 1300-1400 2.476255125 1.935265334 0.78152906 no TXDibollTemple-Inland PB-44 10/28/2009 0000-0100 2.353379358 1.839899494 0.78181169 no WABoeingRenton BOIL04 08/11/09 18:00 1.052679946 0.823165098normal 0.78197091 no ARDomtarIndustries PB1 8/17/2009 6:00:00 PM 4.078906976 3.189850629 Normal 0.78203564 no TXDibollTemple-Inland PB-44 0800-0900 3.221031941 2.520133469 0.7823994 no TXDibollTemple-Inland PB-44 1400-1500 3.318549331 2.596620225 0.78245642 no TXDibollTemple-Inland PB-44 2100-2200 2.862631149 2.240777135 0.78276838 no TXDibollTemple-Inland PB-44 0200-0300 2.430065257 1.903055591 0.78312942 no TXDibollTemple-Inland PB-44 0900-1000 3.54858745 2.779412932 0.78324487 no ARDomtarIndustries PB1 8/23/2009 22.8589602 17.90537926 Normal 0.78329806 no TXDibollTemple-Inland PB-44 1200-1300 2.771531838 2.171129265 0.78336797 no TXDibollTemple-Inland PB-44 0500-0600 3.616545044 2.833288169 0.783424 no TXDibollTemple-Inland PB-44 1500-1600 2.800641455 2.195900639 0.7840706 no WVDuPontWashingtonWorks P05 10/5/2009 2:00:46 PM 0.328551931 0.257619587 0.78410614 no TXDibollTemple-Inland PB-44 0900-1000 2.726531565 2.139071707 0.7845395no TXDibollTemple-Inland PB-44 1000-1100 3.131869875 2.457943851 0.78481672 no TXDibollTemple-Inland PB-44 0800-0900 2.851910808 2.239020926 0.785095no TXDibollTemple-Inland PB-44 0900-1000 3.350511107 2.630948034 0.78523782 no TXDibollTemple-Inland PB-44 0900-1000 2.814973056 2.210648482 0.78531781 no TXDibollTemple-Inland PB-44 2300-2400 2.931004178 2.301774235 0.78531933 no ARDomtarIndustries PB1 8/29/2009 9:00:00 PM 4.154327983 3.264347509 Normal 0.78577029 no TXDibollTemple-Inland PB-44 10/27/2009 0000-0100 3.723099582 2.927888624 0.78641158 no
WVDuPontWashingtonWorks P05 9/25/2009 11:00:07 AM 0.141798357 0.111531423 0.78654948 no TXDibollTemple-Inland PB-44 0600-0700 3.191657268 2.510480605 0.78657587 no TXDibollTemple-Inland PB-44 1400-1500 2.677520323 2.106927822 0.78689517 no WABoeingRenton BOIL04 09/20/09 12:00 17.37015867 13.6751763 normal 0.78727987 no TXDibollTemple-Inland PB-44 0100-0200 2.595103469 2.04540645 0.78817915no TXDibollTemple-Inland PB-44 0300-0400 3.080793146 2.430642984 0.78896663 no TXDibollTemple-Inland PB-44 1000-1100 2.270541152 1.791617134 0.78907054 no


### Appendix D-4, p64 of 82

## Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC

(ppm@3%O2) CombUnit_O

p_Indicator THC_Op_Ind

icator CO_Op_Indi

cator TNMOC TO

THC Ratio Outlier TXDibollTemple-Inland PB-44 1100-1200 2.280900528 1.80127874 0.78972262 no TXDibollTemple-Inland PB-44 11/02/2009 0000-0100 2.454512019 1.939057583 0.78999718 no ARDomtarIndustries PB1 8/14/2009 5:00:00 PM 7.084481012 5.604682074 Normal 0.79112105no WABoeingRenton BOIL04 08/11/09 23:00 0.929787882 0.735842984 normal 0.79140952 no TXDibollTemple-Inland PB-44 2000-2100 2.579470446 2.041920989 0.79160472 no TXDibollTemple-Inland PB-44 1900-2000 3.403217074 2.694175714 0.79165556 no WABoeingRenton BOIL04 09/20/09 10:00 17.1661077 13.60547473 normal 0.79257773 no ARDomtarIndustries PB1 8/22/2009 2:00:00 PM 16.66387132 13.21024434 Normal 0.79274762 no TXDibollTemple-Inland PB-44 10/30/2009 0000-0100 3.254773702 2.583564266 0.79377693 no VAPhilipMorrisPark500 B3 10/1/2009 6:00:00 PM 3.50977509 2.78810619 Normal 0.79438315no
ARDomtarIndustries PB1 8/23/2009 12:00:00 PM 21.48198848 17.06806739 Normal 0.79452921 no TXDibollTemple-Inland PB-44 2300-2400 5.153346767 4.098001482 0.79521167 no TXDibollTemple-Inland PB-44 1700-1800 2.603130007 2.070386551 0.79534504 no TXDibollTemple-Inland PB-44 0700-0800 3.631462051 2.888678319 0.79545877 no TXDibollTemple-Inland PB-44 1300-1400 2.843765341 2.263214103 0.79585122 no TXDibollTemple-Inland PB-44 0600-0700 2.512547256 1.999933337 0.7959784 no ARDomtarIndustries PB1 8/30/2009 6:00:00 PM 2.248309298 1.789903723 Normal 0.79611098 no TXDibollTemple-Inland PB-44 1700-1800 2.563186479 2.040602911 0.79611957 no TXDibollTemple-Inland PB-44 2100-2200 2.954044656 2.352573475 0.79639063 no TXDibollTemple-Inland PB-44 1300-1400 2.421237997 1.928252836 0.79639128 no TXDibollTemple-Inland PB-44 1800-1900 3.434476013 2.735600412 0.79651172 no TXDibollTemple-Inland PB-44 2000-2100 3.165080043 2.522496103 0.79697703 no WABoeingRenton BOIL04 08/17/09 21:00 1.620900769 1.291966313 normal 0.79706688 no TXDibollTemple-Inland PB-44 0300-0400 2.237292908 1.785063498 0.79786759 no ARDomtarIndustries PB1 8/14/2009 3:00:00 PM 8.860616485 7.07045332 Normal 0.79796404 no TXDibollTemple-Inland PB-44 2200-2300 2.66006161 2.124628199 0.79871391 no TXDibollTemple-Inland PB-44 1800-1900 2.728353444 2.179518028 0.79884006 no TXDibollTemple-Inland PB-44 1600-1700 2.843940238 2.272614501 0.79910769 no TXDibollTemple-Inland PB-44 0600-0700 2.527801565 2.020205229 0.79919455no TXDibollTemple-Inland PB-44 0500-0600 3.261579771 2.608179831 0.79966765no TXDibollTemple-Inland PB-44 0900-1000 3.334663657 2.666787216 0.799717 no WABoeingRenton BOIL04 08/11/09 22:00 0.919409612 0.736291778normal 0.80083106 no VAPhilipMorrisPark500 B3 10/2/2009 1:00:00 AM 3.513565484 2.813772387 Normal 0.80083106 no VAPhilipMorrisPark500 B3 10/2/2009 3.588213241 2.87355263 Normal 0.80083106 no TXDibollTemple-Inland PB-44 1700-1800 4.586698115 3.673326428 0.8008651 no TXDibollTemple-Inland PB-44 2300-2400 2.304575039 1.846503785 0.80123396 no ARDomtarIndustries PB1 9/1/2009 4:00:00 AM 3.389745463 2.716681984 Normal 0.80144129 no TXDibollTemple-Inland PB-44 0100-0200 3.390335461 2.717305922 0.80148586 no TXDibollTemple-Inland PB-44 0100-0200 3.127237647 2.510924402 0.80292088 no TXDibollTemple-Inland PB-44 1600-1700 2.983017516 2.395634767 0.80309108 no TXDibollTemple-Inland PB-44 0300-0400 3.494747368 2.808879516 0.80374322 no TXDibollTemple-Inland PB-44 0400-0500 3.014597372 2.423122556 0.80379641 no ARDomtarIndustries PB1 8/14/2009 4:00:00 PM 7.624589491 6.129303434 Normal 0.80388635no



### Appendix D-4, p65 of 82

## Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC

(ppm@3%O2) CombUnit_O

p_Indicator THC_Op_Ind

icator CO_Op_Indi

cator TNMOC TO

THC Ratio Outlier TXDibollTemple-Inland PB-44 0200-0300 4.629353298 3.721808771 0.80395868 no TXDibollTemple-Inland PB-44 0500-0600 3.58688194 2.884415707 0.80415686 no TXDibollTemple-Inland PB-44 0200-0300 2.530920007 2.035621476 0.80430099 no TXDibollTemple-Inland PB-44 1900-2000 2.533275576 2.038148448 0.80455063 no TXDibollTemple-Inland PB-44 0200-0300 3.168752038 2.549630081 0.80461647 no TXDibollTemple-Inland PB-44 0600-0700 3.304592337 2.660283739 0.8050263 no TXDibollTemple-Inland PB-44 0400-0500 3.331278326 2.682462118 0.80523506 no TXDibollTemple-Inland PB-44 2200-2300 3.326621462 2.679054407 0.80533792 no VAPhilipMorrisPark500 B3 10/2/2009 11:00:00 AM 2.871681628 2.312773813 Normal 0.80537264 no VAPhilipMorrisPark500 B3 10/1/2009 2:00:00 PM 2.98980841 2.407909891 Normal 0.80537264 no TXDibollTemple-Inland PB-44 2100-2200 4.271152444 3.440186746 0.80544696 no WABoeingRenton BOIL04 09/19/09 08:00 19.16760086 15.43887183 normal 0.8054671 no TXDibollTemple-Inland PB-44 0300-0400 3.139869884 2.529228479 0.80552016 no WABoeingRenton BOIL04 09/20/09 14:00 15.96863033 12.86561259normal 0.80568041 no TXDibollTemple-Inland PB-44 2300-2400 2.979902466 2.40197097 0.80605691 no ARDomtarIndustries PB1 8/14/2009 2:00:00 PM 8.646211077 6.972249221 Normal 0.80639359 no TXDibollTemple-Inland PB-44 0100-0200 3.078186821 2.482285425 0.80641156 no TXDibollTemple-Inland PB-44 0300-0400 3.074424538 2.47953807 0.80650477 no TXDibollTemple-Inland PB-44 0600-0700 4.32256932 3.490204457 0.80743747 no
ARDomtarIndustries PB1 8/25/2009 11:00:00 PM 2.306354139 1.862372365 Normal 0.80749627 no WABoeingRenton BOIL04 08/26/09 16:00 4.035273127 3.260589026 normal 0.80802189 no TXDibollTemple-Inland PB-44 0800-0900 2.947915438 2.382530644 0.80820861 no TXDibollTemple-Inland PB-44 1200-1300 3.655373938 2.957916151 0.8091966 no WABoeingRenton BOIL04 08/10/09 19:00 1.231890169 0.997259132 normal 0.80953575no TXDibollTemple-Inland PB-44 0100-0200 2.92296104 2.368359888 0.8102605no TXDibollTemple-Inland PB-44 2100-2200 3.326150651 2.697835141 0.8110983 no TXDibollTemple-Inland PB-44 2100-2200 3.200917401 2.597033148 0.81134026 no TXDibollTemple-Inland PB-44 1300-1400 3.434828181 2.787948629 0.81167048 no TXDibollTemple-Inland PB-44 0300-0400 3.85691396 3.132441228 0.81216259 no WABoeingRenton BOIL04 08/11/09 19:00 0.9856829 0.800805566 normal 0.81243731 no VAPhilipMorrisPark500 B3 11/1/2009 10:00:00 AM 0.868635044 0.70571152 Normal 0.81243731 no VAPhilipMorrisPark500 B3 11/1/2009 5:00:00 AM 0.872152924 0.708569577 Normal 0.81243731 no VAPhilipMorrisPark500 B3 9/21/2009 10:00:00 AM 1.548773506 1.258281384 Normal 0.81243731 no VAPhilipMorrisPark500 B3 10/5/2009 2:00:00 AM 2.338266431 1.899694894 Normal 0.81243731 no VAPhilipMorrisPark500 B3 10/6/2009 3:00:00 AM 2.338266431 1.899694894 Normal 0.81243731 no VAPhilipMorrisPark500 B3 10/31/2009 5:00:00 AM 3.551319261 2.885224274 Normal 0.81243731 no
ARDomtarIndustries PB1 8/26/2009 11:00:00 AM 3.357089403 2.728535459 Normal 0.81276818 no WVDuPontWashingtonWorks P05 9/22/2009 5:00:07 PM 0.43631606 0.354719772 0.81298812 no



### Appendix D-4, p66 of 82

## Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC

(ppm@3%O2) CombUnit_O

p_Indicator THC_Op_Ind

icator CO_Op_Indi

cator TNMOC TO

THC Ratio Outlier TXDibollTemple-Inland PB-44 0700-0800 3.589602757 2.918521276 0.81304854 no TXDibollTemple-Inland PB-44 2300-2400 3.365977463 2.736713429 0.81305162 no WVDuPontWashingtonWorks P05 9/23/2009 9:00:21 AM 0.314691535 0.25589957 0.81317589 no TXDibollTemple-Inland PB-44 0800-0900 3.105139692 2.526499246 0.81365075no TXDibollTemple-Inland PB-44 0100-0200 3.609528625 2.937968164 0.81394788 no TXDibollTemple-Inland PB-44 2000-2100 2.30317881 1.87476398 0.81398977 no TXDibollTemple-Inland PB-44 10/24/2009 0000-0100 4.34173795 3.535368996 0.81427508 no VAPhilipMorrisPark500 B3 9/17/2009 3:00:00 PM 7.98639832 6.509721583 Normal 0.81510104 no ARDomtarIndustries PB1 8/23/2009 1:00:00 AM 13.70457182 11.17699403 Normal 0.81556682 no TXDibollTemple-Inland PB-44 1600-1700 2.452639993 2.00071516 0.81573943 no TXDibollTemple-Inland PB-44 1600-1700 3.815890971 3.115909118 0.81656136 no TXDibollTemple-Inland PB-44 0800-0900 3.086102387 2.520291066 0.81665828 no ARDomtarIndustries PB1 8/22/2009 6:00:00 PM 18.06538725 14.75605595 Normal 0.81681371 no TXDibollTemple-Inland PB-44 1800-1900 4.400941379 3.596161789 0.81713467 no TXDibollTemple-Inland PB-44 0500-0600 3.298570841 2.696882245 0.81759113 no TXDibollTemple-Inland PB-44 2100-2200 2.756615342 2.25491107 0.8179999no TXDibollTemple-Inland PB-44 1700-1800 2.96429698 2.424874136 0.81802672 no TXDibollTemple-Inland PB-44 10/26/2009 0000-0100 2.913925265 2.384892032 0.81844653 no TXDibollTemple-Inland PB-44 10/25/2009 0000-0100 3.469962757 2.840609724 0.8186283 no ARDomtarIndustries PB1 8/23/2009 2:00:00 AM 12.45182721 10.19390439 Normal 0.81866735no TXDibollTemple-Inland PB-44 0200-0300 3.430701167 2.808922928 0.81876059 no
ARDomtarIndustries PB1 8/23/2009 10:00:00 PM 11.63965565 9.539623752 Normal 0.81957955no TXDibollTemple-Inland PB-44 0400-0500 3.615259566 2.965381195 0.82024019 no TXDibollTemple-Inland PB-44 0700-0800 4.967693397 4.075697139 0.82044056 no TXDibollTemple-Inland PB-44 0800-0900 6.35845019 5.219962464 0.82094886 no TXDibollTemple-Inland PB-44 2100-2200 4.07162527 3.343332006 0.82112959 no TXDibollTemple-Inland PB-44 0600-0700 3.612429148 2.966585422 0.82121622 no
ARDomtarIndustries PB1 8/30/2009 10:00:00 AM 7.649658154 6.285002727 Normal 10:01 - 10:59 calibration 10:01 - 10:59

calibration 0.8216057 no CATesoro S-974 Furance 55 8/28/2009 1.84615295 1.516863354 None 10:18-1048 10:18-1048 0.82163472 no WABoeingRenton BOIL04 09/20/09 22:00 14.71517383 12.09339576 normal 0.82183166 no ARDomtarIndustries PB1 8/26/2009 1:00:00 AM 3.6757017 3.022245604 Normal 0.82222276 no VAPhilipMorrisPark500 B3 10/3/2009 8:00:00 AM 4.051524528 3.332754818 Normal 0.82259278 no TXDibollTemple-Inland PB-44 1600-1700 3.263852449 2.685510823 0.82280399 no TXDibollTemple-Inland PB-44 1800-1900 2.533275576 2.084805758 0.8229684 no WABoeingRenton BOIL04 09/20/09 07:00 15.45831019 12.72361497 normal 0.82309223 no TXDibollTemple-Inland PB-44 0200-0300 3.6527175 3.008123079 0.82353017 no TXDibollTemple-Inland PB-44 2000-2100 2.774110614 2.286475913 0.82421945no VAPhilipMorrisPark500 B3 10/4/2009 4:00:00 AM 3.320155065 2.738916593 Normal 0.82493635no TXDibollTemple-Inland PB-44 10/14/2009 0000-0100 8.048790525 6.640214904 0.82499537 no TXDibollTemple-Inland PB-44 0900-1000 2.660954447 2.196735297 0.82554412 no TXDibollTemple-Inland PB-44 0800-0900 3.404570633 2.812011209 0.82595179 no 

### Appendix D-4, p67 of 82

## Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC

(ppm@3%O2) CombUnit_O

p_Indicator THC_Op_Ind

icator CO_Op_Indi

cator TNMOC TO

THC Ratio Outlier TXDibollTemple-Inland PB-44 1400-1500 3.861989933 3.190306005 0.82607828 no TXDibollTemple-Inland PB-44 2000-2100 3.349969755 2.769423878 0.82670116 no TXDibollTemple-Inland PB-44 1800-1900 3.207805254 2.65298339 0.82704004 no TXDibollTemple-Inland PB-44 1300-1400 58.36586645 48.27445866 0.82710087 no TXDibollTemple-Inland PB-44 1200-1300 3.605520569 2.982372552 0.82716836 no TXDibollTemple-Inland PB-44 0600-0700 3.493273703 2.89160264 0.82776298 no TXDibollTemple-Inland PB-44 2100-2200 5.167352974 4.281625036 0.82859156 no TXDibollTemple-Inland PB-44 1900-2000 3.216971872 2.666356785 0.82884057 no TXDibollTemple-Inland PB-44 0800-0900 3.751287126 3.109730659 0.82897698 no TXDibollTemple-Inland PB-44 0700-0800 4.097714443 3.398829807 0.82944526 no TXDibollTemple-Inland PB-44 2300-2400 4.134836925 3.429826726 0.82949504 no TXDibollTemple-Inland PB-44 1100-1200 2.996353703 2.485928875 0.82965134 no TXDibollTemple-Inland PB-44 1900-2000 5.051456449 4.195409008 0.83053453 no TXDibollTemple-Inland PB-44 1100-1200 12.06867288 10.02672467 0.8308059no WABoeingRenton BOIL04 08/15/09 09:00 0.966728697 0.803256611 normal 0.8309018no TXDibollTemple-Inland PB-44 2200-2300 7.312679562 6.07950516 0.83136491 no WABoeingRenton BOIL04 09/20/09 15:00 14.24501691 11.84699405normal 0.83165883 no TXDibollTemple-Inland PB-44 1000-1100 3.968036921 3.3019425 0.83213502 no TXDibollTemple-Inland PB-44 0500-0600 4.487966612 3.736704517 0.83260524 no TXDibollTemple-Inland PB-44 0200-0300 2.981680169 2.482967834 0.83274117 no WABoeingRenton BOIL04 09/20/09 20:00 14.08044885 11.72824563 normal 0.83294544 no TXDibollTemple-Inland PB-44 0300-0400 3.484171168 2.90533964 0.83386823 no TXDibollTemple-Inland PB-44 0300-0400 3.46709892 2.894058153 0.83472039 no TXDibollTemple-Inland PB-44 1500-1600 3.682230015 3.075113554 0.83512261 no WABoeingRenton BOIL04 09/18/09 19:00 17.77051484 14.84109331 normal 0.83515269 no VAPhilipMorrisPark500 B3 10/31/2009 7:00:00 AM 1.064954222 0.889928789 Normal 0.83564981 no VAPhilipMorrisPark500 B3 10/31/2009 9:00:00 AM 1.025820676 0.85722685 Normal 0.83564981 no VAPhilipMorrisPark500 B3 10/5/2009 8:00:00 PM 3.637303337 3.03951183 Normal 0.83564981 no CATesoro S-974 Furance 55 9/15/2009 0.082234878 0.06871956 None 08:25-08:51 08:25-08:51 0.83564981 no WABoeingRenton BOIL04 09/20/09 19:00 13.89591361 11.61211752 normal 0.83564981 no TXDibollTemple-Inland PB-44 2200-2300 10.85248862 9.071593515 0.83589984 no TXDibollTemple-Inland PB-44 2200-2300 4.140189188 3.462236916 0.8362509no WABoeingRenton BOIL04 09/19/09 17:00 14.65215381 12.27771509normal 0.8379461 no TXDibollTemple-Inland PB-44 0300-0400 6.852149286 5.743242803 0.83816662 no TXDibollTemple-Inland PB-44 2300-2400 6.46266971 5.417348884 0.83825248 no TXDibollTemple-Inland PB-44 0700-0800 3.668615951 3.077371787 0.83883727 no WABoeingRenton BOIL04 09/20/09 17:00 13.71922269 11.51697479normal 0.83947721 no ARDomtarIndustries PB1 8/24/2009 4:00:00 AM 6.242766863 5.245168755 Normal 0.84019937 no ARDomtarIndustries PB1 8/24/2009 3:00:00 AM 7.829521201 6.57894146 Normal 0.84027379 no WABoeingRenton BOIL04 09/20/09 21:00 13.86774625 11.65305816 normal 0.84029935no TXDibollTemple-Inland PB-44 0200-0300 3.701410535 3.110857901 0.840452 no VAPhilipMorrisPark500 B3 10/5/2009 9:00:00 PM 3.740574605 3.143774873 Normal 0.84045239 no TXDibollTemple-Inland PB-44 1700-1800 3.293907888 2.769142276 0.84068601 no



### Appendix D-4, p68 of 82

## Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC

(ppm@3%O2) CombUnit_O

p_Indicator THC_Op_Ind

icator CO_Op_Indi

cator TNMOC TO

THC Ratio Outlier WABoeingRenton BOIL04 09/20/09 16:00 13.77888151 11.58857742 normal 0.84103905no ARDomtarIndustries PB1 8/24/2009 7:00:00 AM 3.602605676 3.032347585 Normal 0.84170955no VAPhilipMorrisPark500 B3 10/6/2009 4:00:00 AM 2.837677287 2.389268903 Normal 0.84198049 no VAPhilipMorrisPark500 B3 10/5/2009 3:00:00 AM 2.878374861 2.423535467 Normal 0.84198049 no VAPhilipMorrisPark500 B3 10/4/2009 10:00:00 PM 1.992505621 1.677650853 Normal 0.84198049 no ARDomtarIndustries PB1 8/24/2009 6:00:00 AM 3.619350819 3.048470988 Normal 0.8422701 no WABoeingRenton BOIL04 09/20/09 18:00 13.74573849 11.60198645normal 0.84404242 no WVDuPontWashingtonWorks P05 9/22/2009 4:00:06 PM 0.436317422 0.368659776 0.8449348no VAPhilipMorrisPark500 B3 10/2/2009 7:00:00 PM 3.798304245 3.209319455 Normal 0.8449348no TXDibollTemple-Inland PB-44 0700-0800 4.561355309 3.854205809 0.84496943 no WVDuPontWashingtonWorks P05 9/23/2009 3:00:27 PM 0.288884715 0.244645668 0.84686262 no TXDibollTemple-Inland PB-44 0500-0600 4.713037552 3.992977506 0.84721954 no VAPhilipMorrisPark500 B3 10/3/2009 6:00:00 AM 3.924914387 3.332754818 Normal 0.84912803 no TXDibollTemple-Inland PB-44 0700-0800 5.835691286 4.970173472 0.85168547 no TXDibollTemple-Inland PB-44 1700-1800 5.153736317 4.390910207 0.85198581 no WABoeingRenton BOIL04 08/26/09 18:00 3.397203224 2.895344406 normal 0.85227295no VAPhilipMorrisPark500 B3 10/5/2009 3:00:00 PM 3.117688574 2.659572851 Normal 0.85305918 no VAPhilipMorrisPark500 B3 10/6/2009 1:00:00 AM 3.117688574 2.659572851 Normal 0.85305918 no VAPhilipMorrisPark500 B3 10/3/2009 7:00:00 AM 4.023259398 3.432078353 Normal 0.85305918 no VAPhilipMorrisPark500 B3 10/5/2009 1:00:00 AM 2.093363535 1.785762976 Normal 0.85305918 no VAPhilipMorrisPark500 B3 10/2/2009 2:00:00 PM 3.038643396 2.592142636 Normal 0.85305918 no VAPhilipMorrisPark500 B3 10/6/2009 5:00:00 AM 3.07391677 2.622232912 Normal 0.85305918 no VAPhilipMorrisPark500 B3 10/2/2009 12:00:00 PM 3.081949617 2.629085406 Normal 0.85305918 no VAPhilipMorrisPark500 B3 10/4/2009 8:00:00 PM 3.140045303 2.678644464 Normal 0.85305918 no TXDibollTemple-Inland PB-44 2100-2200 3.76733636 3.227539529 0.85671658 no TXDibollTemple-Inland PB-44 1900-2000 4.320089977 3.702986362 0.85715492 no ARDomtarIndustries PB1 8/24/2009 8:00:00 AM 4.012310859 3.440429559 Normal 0.85746835no VAPhilipMorrisPark500 B3 10/5/2009 5:00:00 PM 3.270880524 2.806198962 Normal 0.8579338no VAPhilipMorrisPark500 B3 10/3/2009 6:00:00 PM 3.148025616 2.700797584 Normal 0.8579338no VAPhilipMorrisPark500 B3 10/4/2009 3:00:00 AM 3.192456793 2.738916593 Normal 0.8579338no
ARDomtarIndustries PB1 8/29/2009 10:00:00 AM 4.632928818 3.98019284 Normal 10:07 - 10:59 calibration 10:07 - 10:59

calibration 0.85910943 no WABoeingRenton BOIL04 09/26/09 20:00 0.641472192 0.551188659normal 0.85925573 no TXDibollTemple-Inland PB-44 2100-2200 7.926571928 6.811488056 0.85932331 no


### Appendix D-4, p69 of 82

## Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC

(ppm@3%O2) CombUnit_O

p_Indicator THC_Op_Ind

icator CO_Op_Indi

cator TNMOC TO

THC Ratio Outlier ARDomtarIndustries PB1 8/24/2009 1:00:00 AM 7.376079658 6.34217179 Normal 0.85982962 no VAPhilipMorrisPark500 B3 10/4/2009 9:00:00 AM 3.367686533 2.904405529 Normal 0.86243345no VAPhilipMorrisPark500 B3 10/6/2009 8:00:00 AM 3.377495955 2.912865503 Normal 0.86243345no VAPhilipMorrisPark500 B3 10/3/2009 10:00:00 PM 3.320155065 2.863412801 Normal 0.86243345no VAPhilipMorrisPark500 B3 10/4/2009 2:00:00 PM 3.353618611 2.892272883 Normal 0.86243345no VAPhilipMorrisPark500 B3 10/4/2009 6:00:00 PM 3.353618611 2.892272883 Normal 0.86243345no VAPhilipMorrisPark500 B3 10/5/2009 1:00:00 PM 3.401715745 2.93375346 Normal 0.86243345no TXDibollTemple-Inland PB-44 0400-0500 4.246290452 3.663745216 0.86281079 no WABoeingRenton BOIL04 09/19/09 20:00 13.9119557 12.00685674 normal 0.86306031 no WABoeingRenton BOIL04 09/20/09 06:00 13.84429778 11.96781415normal 0.86445801 no TXDibollTemple-Inland PB-44 0500-0600 7.316325329 6.326569883 0.8647196 no TXDibollTemple-Inland PB-44 1100-1200 7.587098567 6.563238485 0.86505249 no WABoeingRenton BOIL04 09/19/09 19:00 13.56724295 11.73810678normal 0.86517997 no WABoeingRenton BOIL04 08/17/09 04:00 1.176174201 1.018081588normal 0.86558742 no VAPhilipMorrisPark500 B3 10/3/2009 11:00:00 AM 3.472358979 3.009145594 Normal 0.8665998no CATesoro S-974 Furance 55 9/21/2009 0.215409443 0.18667378 None 14:51-15:10 14:51-15:10 0.8665998no VAPhilipMorrisPark500 B3 10/6/2009 3.482603943 3.018023878 Normal 0.8665998no VAPhilipMorrisPark500 B3 10/5/2009 6:00:00 PM 3.507399646 3.03951183 Normal 0.8665998no TXDibollTemple-Inland PB-44 2100-2200 6.699189259 5.812873296 0.86769803 no WABoeingRenton BOIL04 08/22/09 11:00 1.003370607 0.870715163 normal 0.86779018 no ARDomtarIndustries PB1 8/24/2009 5:00:00 AM 6.082260769 5.288208131 Normal 0.86944778 no WABoeingRenton BOIL04 08/23/09 01:00 0.407213296 0.35408316 normal 0.8695275no VAPhilipMorrisPark500 B3 10/5/2009 10:00:00 PM 3.637303337 3.166158156 Normal 0.87046855no VAPhilipMorrisPark500 B3 10/6/2009 9:00:00 AM 3.637303337 3.166158156 Normal 0.87046855no VAPhilipMorrisPark500 B3 10/4/2009 7:00:00 PM 2.535916245 2.207435333 Normal 0.87046855no VAPhilipMorrisPark500 B3 10/4/2009 11:00:00 AM 3.586236232 3.121705847 Normal 0.87046855no VAPhilipMorrisPark500 B3 10/5/2009 5:00:00 AM 3.663386187 3.188862457 Normal 0.87046855no VAPhilipMorrisPark500 B3 10/5/2009 12:00:00 PM 3.663386187 3.188862457 Normal 0.87046855no VAPhilipMorrisPark500 B3 10/2/2009 8:00:00 PM 3.545083962 3.085884091 Normal 0.87046855no VAPhilipMorrisPark500 B3 10/2/2009 9:00:00 PM 3.545083962 3.085884091 Normal 0.87046855no ARDomtarIndustries PB1 8/24/2009 2:00:00 AM 7.827950937 6.832055422 Normal 0.87277699 no



### Appendix D-4, p70 of 82

## Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC

(ppm@3%O2) CombUnit_O

p_Indicator THC_Op_Ind

icator CO_Op_Indi

cator TNMOC TO

THC Ratio Outlier
ARDomtarIndustries PB1 8/23/2009 11:00:00 PM 5.778723251 5.045539277 Normal 0.87312354 no WABoeingRenton BOIL04 08/18/09 08:00 1.374035281 1.200264609normal 0.8735326 no TXDibollTemple-Inland PB-44 0900-1000 7.242421511 6.32893339 0.87386979 no VAPhilipMorrisPark500 B3 10/3/2009 2:00:00 AM 3.64607883 3.1869299 Normal 0.87407049 no WABoeingRenton BOIL04 08/15/09 08:00 0.635994134 0.555903703 normal 0.87407049 no VAPhilipMorrisPark500 B3 10/2/2009 10:00:00 PM 3.671694104 3.209319455 Normal 0.87407049 no VAPhilipMorrisPark500 B3 10/3/2009 1:00:00 AM 3.671694104 3.209319455 Normal 0.87407049 no WABoeingRenton BOIL04 08/13/09 19:00 1.832344094 1.604548789normal 0.87568094 no WABoeingRenton BOIL04 08/22/09 06:00 0.329768467 0.289349504 normal 0.8774323 no VAPhilipMorrisPark500 B3 10/2/2009 6:00:00 PM 3.771805686 3.309504126 Normal 0.8774323 no VAPhilipMorrisPark500 B3 10/3/2009 3.771805686 3.309504126 Normal 0.8774323 no VAPhilipMorrisPark500 B3 10/3/2009 5:00:00 AM 3.771805686 3.309504126 Normal 0.8774323 no VAPhilipMorrisPark500 B3 10/3/2009 9:00:00 AM 3.825180484 3.356336898 Normal 0.8774323 no VAPhilipMorrisPark500 B3 10/4/2009 6:00:00 AM 3.830948152 3.361397636 Normal 0.8774323 no VAPhilipMorrisPark500 B3 10/5/2009 6:00:00 AM 3.925056629 3.443971453 Normal 0.8774323 no VAPhilipMorrisPark500 B3 10/5/2009 11:00:00 AM 3.925056629 3.443971453 Normal 0.8774323 no VAPhilipMorrisPark500 B3 10/3/2009 3:00:00 AM 3.798304245 3.332754818 Normal 0.8774323 no VAPhilipMorrisPark500 B3 10/3/2009 4:00:00 AM 3.798304245 3.332754818 Normal 0.8774323 no WABoeingRenton BOIL04 08/16/09 05:00 0.78045204 0.685865491 normal 0.87880543 no
ARDomtarIndustries PB1 8/24/2009 11:00:00 AM 8.121198493 7.141572476 Normal 0.87937421 no CATesoro S-974 Furance 55 8/27/2009 1.566009377 1.378624642 None 14:07-14:45 14:07-14:45 0.88034252 no VAPhilipMorrisPark500 B3 10/2/2009 11:00:00 PM 3.897532542 3.432078353 Normal 0.88057722 no VAPhilipMorrisPark500 B3 10/3/2009 9:00:00 PM 3.930907444 3.461467531 Normal 0.88057722 no ARDomtarIndustries PB1 8/24/2009 8.722371552 7.681262072 Normal 0.88063917 no VAPhilipMorrisPark500 B3 10/5/2009 2.727977502 2.406280198 Normal 0.8820748no VAPhilipMorrisPark500 B3 10/3/2009 2:00:00 PM 2.662872785 2.348852968 Normal 0.8820748no VAPhilipMorrisPark500 B3 10/4/2009 5:00:00 AM 4.115388419 3.636050926 Normal 0.88352558 no VAPhilipMorrisPark500 B3 10/5/2009 8:00:00 AM 4.186727071 3.69908045 Normal 0.88352558 no VAPhilipMorrisPark500 B3 10/4/2009 5:00:00 PM 4.156918099 3.672743461 Normal 0.88352558 no VAPhilipMorrisPark500 B3 10/5/2009 9:00:00 AM 4.156918099 3.672743461 Normal 0.88352558 no WABoeingRenton BOIL04 09/20/09 05:00 13.08431131 11.57793394 normal 0.88487148 no



### Appendix D-4, p71 of 82

## Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC

(ppm@3%O2) CombUnit_O

p_Indicator THC_Op_Ind

icator CO_Op_Indi

cator TNMOC TO

THC Ratio Outlier VAPhilipMorrisPark500 B3 10/4/2009 2:00:00 AM 2.809361978 2.489924175 Normal 0.88629525no VAPhilipMorrisPark500 B3 10/4/2009 9:00:00 PM 2.837677287 2.515019898 Normal 0.88629525no VAPhilipMorrisPark500 B3 10/6/2009 2:00:00 AM 2.837677287 2.515019898 Normal 0.88629525no VAPhilipMorrisPark500 B3 10/3/2009 7:00:00 PM 2.770262542 2.455270531 Normal 0.88629525no VAPhilipMorrisPark500 B3 10/2/2009 1:00:00 PM 2.891717693 2.574058765 Normal 0.89014871 no VAPhilipMorrisPark500 B3 10/3/2009 5:00:00 PM 2.896183567 2.578034057 Normal 0.89014871 no VAPhilipMorrisPark500 B3 10/2/2009 3:00:00 PM 3.017444549 2.696632992 Normal 0.89368104 no VAPhilipMorrisPark500 B3 10/4/2009 11:00:00 PM 3.095647949 2.766521888 Normal 0.89368104 no VAPhilipMorrisPark500 B3 10/5/2009 4:00:00 AM 3.140045303 2.806198962 Normal 0.89368104 no TXDibollTemple-Inland PB-44 2000-2100 8.105866838 7.244245433 0.89370398 no WABoeingRenton BOIL04 08/17/09 16:00 1.614876347 1.4458619normal 0.89533908 no WABoeingRenton BOIL04 08/13/09 20:00 1.352050717 1.210981257 normal 0.8956626 no VAPhilipMorrisPark500 B3 10/3/2009 11:00:00 PM 3.170086648 2.843348329 Normal 0.89693079 no VAPhilipMorrisPark500 B3 10/6/2009 7:00:00 AM 3.201996636 2.87196938 Normal 0.89693079 no VAPhilipMorrisPark500 B3 10/5/2009 2:00:00 PM 3.247592265 2.912865503 Normal 0.89693079 no VAPhilipMorrisPark500 B3 10/5/2009 4:00:00 PM 3.247592265 2.912865503 Normal 0.89693079 no VAPhilipMorrisPark500 B3 10/3/2009 12:00:00 PM 3.192456793 2.863412801 Normal 0.89693079 no VAPhilipMorrisPark500 B3 10/4/2009 12:00:00 PM 3.22463328 2.892272883 Normal 0.89693079 no VAPhilipMorrisPark500 B3 10/4/2009 10:00:00 AM 3.306862614 2.975946727 Normal 0.89993056 no VAPhilipMorrisPark500 B3 10/3/2009 10:00:00 AM 3.34375309 3.009145594 Normal 0.89993056 no VAPhilipMorrisPark500 B3 10/5/2009 11:00:00 PM 3.353618611 3.018023878 Normal 0.89993056 no VAPhilipMorrisPark500 B3 10/6/2009 6:00:00 AM 3.353618611 3.018023878 Normal 0.89993056 no VAPhilipMorrisPark500 B3 10/4/2009 3:00:00 PM 3.377495955 3.03951183 Normal 0.89993056 no CATesoro S-974 Furance 55 9/20/2009 0.154236414 0.138802063 None 08:31-09:10 08:31-09:10 0.89993056 no CATesoro S-974 Furance 55 9/22/2009 0.155056493 0.139540077 None 08:35-09:02 08:35-09:02 0.89993056 no VAPhilipMorrisPark500 B3 10/2/2009 4:00:00 PM 3.418473821 3.085884091 Normal 0.90270812 no VAPhilipMorrisPark500 B3 10/6/2009 10:00:00 AM 3.545262382 3.200337155 Normal 0.90270812 no CATesoro S-974 Furance 55 9/2/2009 1.286409312 1.162104432 None 14:28-15:42 14:28-15:42 0.90337066 no


### Appendix D-4, p72 of 82

## Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC

(ppm@3%O2) CombUnit_O

p_Indicator THC_Op_Ind

icator CO_Op_Indi

cator TNMOC TO

THC Ratio Outlier WABoeingRenton BOIL04 09/20/09 03:00 12.53147631 11.33506098normal 0.90452718 no VAPhilipMorrisPark500 B3 10/2/2009 5:00:00 PM 3.520351974 3.1869299 Normal 0.90528729 no VAPhilipMorrisPark500 B3 10/4/2009 8:00:00 AM 3.600964867 3.259907727 Normal 0.90528729 no VAPhilipMorrisPark500 B3 10/5/2009 7:00:00 AM 3.663386187 3.316416955 Normal 0.90528729 no VAPhilipMorrisPark500 B3 10/5/2009 10:00:00 AM 3.663386187 3.316416955 Normal 0.90528729 no VAPhilipMorrisPark500 B3 10/6/2009 11:00:00 AM 3.676568396 3.328350641 Normal 0.90528729 no WVDuPontWashingtonWorks P05 9/24/2009 6:00:40 AM 0.634199034 0.575261835 0.90706829 no WABoeingRenton BOIL04 08/26/09 04:00 2.109226249 1.917105779normal 0.90891424 no
WVDuPontWashingtonWorks P05 9/23/2009 11:00:23 AM 0.294209913 0.267510915 0.90925188 no VAPhilipMorrisPark500 B3 10/5/2009 7:00:00 PM 3.897110718 3.546097135 Normal 0.90992979 no VAPhilipMorrisPark500 B3 10/3/2009 8:00:00 PM 3.804103978 3.461467531 Normal 0.90992979 no VAPhilipMorrisPark500 B3 10/4/2009 4:00:00 PM 3.869559936 3.521027858 Normal 0.90992979 no WABoeingRenton BOIL04 09/20/09 04:00 12.35519537 11.26760412 normal 0.91197296 no VAPhilipMorrisPark500 B3 10/4/2009 7:00:00 AM 4.115388419 3.761431993 Normal 0.91399198 no VAPhilipMorrisPark500 B3 9/17/2009 2:00:00 PM 18.85313702 17.23161595 Normal 0.91399198 no CATesoro S-974 Furance 55 9/3/2009 1.210820123 1.11169396 None 15:45-16:08 15:45-16:08 0.91813304 no VAPhilipMorrisPark500 B3 10/4/2009 2.282462387 2.101605287 Normal 0.92076229 no CATesoro S-974 Furance 55 8/29/2009 1.665045755 1.534346721 None 12:49-13:18 12:49-13:18 0.92150424 no TXDibollTemple-Inland PB-44 1000-1100 10.59253363 9.765497734 0.92192275no WABoeingRenton BOIL04 08/15/09 07:00 0.615190989 0.567634672 normal 0.92269666 no WABoeingRenton BOIL04 08/25/09 19:00 1.481236244 1.369214967 normal 0.92437312 no WABoeingRenton BOIL04 08/25/09 17:00 1.705893536 1.577279529normal 0.92460608 no WABoeingRenton BOIL04 08/22/09 16:00 0.650536987 0.601975915normal 0.92535233 no WABoeingRenton BOIL04 08/26/09 22:00 3.024606742 2.799189057 normal 0.92547207 no VAPhilipMorrisPark500 B3 10/3/2009 1:00:00 PM 2.789676251 2.596100649 Normal 0.93061001 no WABoeingRenton BOIL04 09/19/09 23:00 11.85470134 11.04514406 normal 0.93171002 no WABoeingRenton BOIL04 08/25/09 18:00 1.736780595 1.618213892 normal 0.9317319no VAPhilipMorrisPark500 B3 10/3/2009 3:00:00 PM 2.916479716 2.719724489 Normal 0.93253674 no VAPhilipMorrisPark500 B3 10/4/2009 1:00:00 PM 3.117688574 2.912865503 Normal 0.93430291 no TXDibollTemple-Inland PB-44 1100-1200 15.36984221 14.36339692 0.93451818 no WABoeingRenton BOIL04 08/25/09 21:00 1.434716221 1.34535335normal 0.93771391 no TXDibollTemple-Inland PB-44 0200-0300 15.69414493 14.74321237 0.93940845no 

### Appendix D-4, p73 of 82

## Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC

(ppm@3%O2) CombUnit_O

p_Indicator THC_Op_Ind

icator CO_Op_Indi

cator TNMOC TO

THC Ratio Outlier
CATesoro S-974 Furance 55 8/25/2009 1.925786941 1.809224766 None 10:45-11:02 daily calibrations 10:45-11:02

daily calibrations 0.93947296 no WABoeingRenton BOIL04 09/19/09 22:00 11.48435716 10.79035043 normal 0.93956939 no VAPhilipMorrisPark500 B3 9/19/2009 3:00:00 AM 3.714791804 3.492298184 Normal 0.94010603 no WABoeingRenton BOIL04 09/19/09 05:00 13.43105776 12.64239023 normal 0.94128031 no WABoeingRenton BOIL04 09/20/09 00:00 11.38381303 10.72058824 normal 0.94173966 no WABoeingRenton BOIL04 09/20/09 02:00 11.62408979 10.95417748normal 0.94236862 no CATesoro S-974 Furance 55 9/1/2009 1.112403758 1.050262299 None 09:54-10:16 09:54-10:16 0.94413768 no WABoeingRenton BOIL04 09/18/09 21:00 13.5685138 12.83617834 normal 0.94602685no WABoeingRenton BOIL04 09/19/09 04:00 13.19435038 12.48395403 normal 0.94615905no CATesoro S-974 Furance 55 9/8/2009 0.794988444 0.752588598 None 13:57-14:45 13:57-14:45 0.94666609 no WABoeingRenton BOIL04 08/25/09 22:00 1.623873808 1.540366838normal 0.94857546 no WABoeingRenton BOIL04 09/20/09 01:00 11.30003151 10.75121849normal 0.95143261 no WABoeingRenton BOIL04 08/16/09 04:00 0.943025785 0.897998289normal 0.95225211 no WABoeingRenton BOIL04 09/19/09 18:00 11.10753241 10.58382343 normal 0.95285101 no WABoeingRenton BOIL04 08/14/09 18:00 0.988094947 0.941911171 normal 0.95325978 no WABoeingRenton BOIL04 09/18/09 20:00 13.40975584 12.82585987 normal 0.95645738 no TXDibollTemple-Inland PB-44 0700-0800 5.175675932 4.95519539 0.95740063 no CATesoro S-974 Furance 55 9/7/2009 0.659269142 0.631461717 None 09:00-09:33 09:00-09:33 0.95782083 no CATesoro S-974 Furance 55 9/4/2009 0.698149809 0.669107214 None 13:40-14:06 13:40-14:06 0.95840063 no WABoeingRenton BOIL04 08/25/09 23:00 1.300275083 1.246184453 normal 0.95840063 no WABoeingRenton BOIL04 08/18/09 04:00 1.427248256 1.370052612 normal 0.95992593 no WABoeingRenton BOIL04 08/16/09 01:00 0.723275525 0.6944553 normal 0.96015319 no WABoeingRenton BOIL04 09/18/09 22:00 12.97987769 12.48979419normal 0.96224283 no CATesoro S-974 Furance 55 8/31/2009 0.954574468 0.91928905 None 13:44-14:13 13:44-14:13 0.96303545no WABoeingRenton BOIL04 08/13/09 17:00 0.933772037 0.899647405normal 0.96345507 no WABoeingRenton BOIL04 09/19/09 21:00 10.77011198 10.38780357 normal 0.96450284 no WABoeingRenton BOIL04 09/18/09 18:00 13.2666462 12.82034483 normal 0.96635914 no WABoeingRenton BOIL04 08/15/09 17:00 0.624265837 0.60861223 normal 0.97492477 no WABoeingRenton BOIL04 08/17/09 19:00 1.359711597 1.325616522 normal 0.97492477 no CATesoro S-974 Furance 55 9/16/2009 0.14389416 0.140285982 None 13:42-14:07 13:42-14:07 0.97492477 no CATesoro S-974 Furance 55 9/23/2009 0.178200715 0.173732292 None 14:08-14:56 14:08-14:56 0.97492477 no



### Appendix D-4, p74 of 82

## Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC

(ppm@3%O2) CombUnit_O

p_Indicator THC_Op_Ind

icator CO_Op_Indi

cator TNMOC TO

THC Ratio Outlier WABoeingRenton BOIL04 08/22/09 05:00 0.021971107 0.021420176 normal 0.97492477 no WABoeingRenton BOIL04 08/22/09 22:00 0.032896248 0.032071367 normal 0.97492477 no WABoeingRenton BOIL04 08/22/09 20:00 0.04383488 0.042735711 normal 0.97492477 no WABoeingRenton BOIL04 08/20/09 04:00 0.109654161 0.106904558normal 0.97492477 no VAPhilipMorrisPark500 B3 9/20/2009 1:00:00 PM 0.131886448 0.128579366 Normal 0.97492477 no WABoeingRenton BOIL04 08/19/09 23:00 0.175339521 0.170942843 normal 0.97492477 no WABoeingRenton BOIL04 08/21/09 21:00 0.17598431 0.171571464 normal 0.97492477 no WABoeingRenton BOIL04 08/23/09 09:00 0.17598431 0.171571464 normal 0.97492477 no WABoeingRenton BOIL04 08/19/09 14:00 0.252822492 0.246482911 normal 0.97492477 no VAPhilipMorrisPark500 B3 9/18/2009 9:00:00 AM 0.267538485 0.260829897 Normal 0.97492477 no WABoeingRenton BOIL04 08/15/09 12:00 0.470937386 0.459128524 normal 0.97492477 no WABoeingRenton BOIL04 08/14/09 19:00 0.503179325 0.49056199 normal 0.97492477 no WABoeingRenton BOIL04 08/14/09 21:00 0.514745514 0.501838155normal 0.97492477 no WABoeingRenton BOIL04 08/14/09 23:00 0.515374557 0.502451424 normal 0.97492477 no WABoeingRenton BOIL04 08/15/09 18:00 0.634830446 0.61891193 normal 0.97492477 no VAPhilipMorrisPark500 B3 11/1/2009 12:00:00 PM 0.741815476 0.723214286 Normal 0.97492477 no WABoeingRenton BOIL04 08/16/09 02:00 0.746560626 0.72784045normal 0.97492477 no WABoeingRenton BOIL04 08/16/09 16:00 0.831846792 0.810988046 normal 0.97492477 no WABoeingRenton BOIL04 08/16/09 17:00 0.832862726 0.811978505normal 0.97492477 no VAPhilipMorrisPark500 B3 9/19/2009 5:00:00 PM 0.919906707 0.896839839 Normal 0.97492477 no VAPhilipMorrisPark500 B3 10/3/2009 4:00:00 PM 2.014736395 1.964216425 Normal 0.97492477 no VAPhilipMorrisPark500 B3 9/18/2009 2:00:00 AM 2.140307879 2.086639176 Normal 0.97492477 no VAPhilipMorrisPark500 B3 9/17/2009 10:00:00 PM 2.39053342 2.330590255 Normal 0.97492477 no VAPhilipMorrisPark500 B3 9/18/2009 2.39053342 2.330590255 Normal 0.97492477 no VAPhilipMorrisPark500 B3 9/18/2009 1:00:00 AM 2.39053342 2.330590255 Normal 0.97492477 no VAPhilipMorrisPark500 B3 9/19/2009 6:00:00 AM 2.788000382 2.718090643 Normal 0.97492477 no VAPhilipMorrisPark500 B3 9/19/2009 11:00:00 AM 3.199503179 3.119274915 Normal 0.97492477 no VAPhilipMorrisPark500 B3 9/19/2009 2:00:00 AM 3.582120668 3.492298184 Normal 0.97492477 no VAPhilipMorrisPark500 B3 9/19/2009 12:00:00 PM 3.970714158 3.871147604 Normal 0.97492477 no VAPhilipMorrisPark500 B3 9/18/2009 4:00:00 PM 4.280615759 4.173278353 Normal 0.97492477 no



### Appendix D-4, p75 of 82

## Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC

(ppm@3%O2) CombUnit_O

p_Indicator THC_Op_Ind

icator CO_Op_Indi

cator TNMOC TO

THC Ratio Outlier VAPhilipMorrisPark500 B3 9/18/2009 5:00:00 PM 4.648259428 4.531703274 Normal 0.97492477 no TXDibollTemple-Inland PB-44 1900-2000 2.833279063 2.762233952 0.97492477 no TXDibollTemple-Inland PB-44 1000-1100 3.586679246 3.496742454 0.97492477 no

CATesoro S-974 Furance 55 9/5/2009 0.726463829 0.708247584 None 04:42-13:59, 14:00-14:35 04:42-13:59,

14:00-14:35 0.97492477 no CATesoro S-974 Furance 55 8/26/2009 1.334494604 1.30103185 None 08:33-09:09 08:33-09:09 0.97492477 no CATesoro S-974 Furance 55 9/19/2009 0.13190298 0.128595483 None 12:08-12:26 12:08-12:26 0.97492477 no CATesoro S-974 Furance 55 8/30/2009 0.39812345 0.388140415 None 13:11-13:30 13:11-13:30 0.97492477 no CATesoro S-974 Furance 55 9/13/2009 0.011566125 0.011276102 None 14:04-14:53 14:04-14:53 0.97492477 no WABoeingRenton BOIL04 08/19/09 19:00 0.010952032 0.010677408normal 0.97492477 no WABoeingRenton BOIL04 08/22/09 18:00 0.03287616 0.032051783 normal 0.97492477 no WABoeingRenton BOIL04 08/23/09 00:00 0.06575232 0.064103566 normal 0.97492477 no WABoeingRenton BOIL04 08/22/09 04:00 0.076945976 0.075016538normal 0.97492477 no WABoeingRenton BOIL04 08/23/09 04:00 0.076945976 0.075016538normal 0.97492477 no WABoeingRenton BOIL04 08/19/09 04:00 0.087776963 0.085575935normal 0.97492477 no WABoeingRenton BOIL04 08/19/09 22:00 0.098688745 0.096214102 normal 0.97492477 no VAPhilipMorrisPark500 B3 9/19/2009 8:00:00 AM 0.132761923 0.129432888 Normal 0.97492477 no VAPhilipMorrisPark500 B3 9/20/2009 9:00:00 AM 0.133408961 0.130063701 Normal 0.97492477 no VAPhilipMorrisPark500 B3 9/20/2009 2:00:00 AM 0.134282022 0.13091487 Normal 0.97492477 no VAPhilipMorrisPark500 B3 11/3/2009 11:00:00 AM 0.261487621 0.25493076 Normal 0.97492477 no WABoeingRenton BOIL04 08/20/09 05:00 0.307031651 0.299332763 normal 0.97492477 no WABoeingRenton BOIL04 08/15/09 13:00 0.307219369 0.299515774 normal 0.97492477 no VAPhilipMorrisPark500 B3 9/19/2009 7:00:00 AM 0.398285769 0.388298663 Normal 0.97492477 no VAPhilipMorrisPark500 B3 11/1/2009 1:00:00 AM 0.432572714 0.421725856 Normal 0.97492477 no VAPhilipMorrisPark500 B3 10/31/2009 8:00:00 PM 0.439637433 0.428613425 Normal 0.97492477 no WABoeingRenton BOIL04 08/15/09 02:00 0.482773294 0.470667645normal 0.97492477 no WABoeingRenton BOIL04 08/15/09 00:00 0.503486216 0.490861186 normal 0.97492477 no WABoeingRenton BOIL04 08/14/09 22:00 0.526018564 0.51282853 normal 0.97492477 no WABoeingRenton BOIL04 08/16/09 13:00 0.536977284 0.523512457 normal 0.97492477 no WABoeingRenton BOIL04 08/14/09 20:00 0.547601611 0.533870377 normal 0.97492477 no WABoeingRenton BOIL04 08/19/09 17:00 0.549950968 0.536160824 normal 0.97492477 no VAPhilipMorrisPark500 B3 10/31/2009 3:00:00 PM 0.572166428 0.557819225 Normal 0.97492477 no



### Appendix D-4, p76 of 82

## Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC

(ppm@3%O2) CombUnit_O

p_Indicator THC_Op_Ind

icator CO_Op_Indi

cator TNMOC TO

THC Ratio Outlier WABoeingRenton BOIL04 08/15/09 16:00 0.602729604 0.587616023 normal 0.97492477 no WABoeingRenton BOIL04 09/27/09 19:00 0.604097139 0.588949267 normal 0.97492477 no WABoeingRenton BOIL04 08/15/09 21:00 0.613313804 0.597934822 normal 0.97492477 no WABoeingRenton BOIL04 08/15/09 20:00 0.635217869 0.619289637 normal 0.97492477 no WABoeingRenton BOIL04 08/15/09 22:00 0.635217869 0.619289637 normal 0.97492477 no WABoeingRenton BOIL04 08/16/09 19:00 0.733338619 0.714949988normal 0.97492477 no VAPhilipMorrisPark500 B3 11/1/2009 11:00:00 AM 0.735733027 0.717284356 Normal 0.97492477 no WABoeingRenton BOIL04 08/16/09 20:00 0.777594288 0.758095936 normal 0.97492477 no WABoeingRenton BOIL04 08/16/09 14:00 0.854780166 0.833346361 normal 0.97492477 no VAPhilipMorrisPark500 B3 10/31/2009 8:00:00 AM 0.890178571 0.867857143 Normal 0.97492477 no VAPhilipMorrisPark500 B3 11/1/2009 1:00:00 PM 0.890178571 0.867857143 Normal 0.97492477 no VAPhilipMorrisPark500 B3 9/20/2009 10:00:00 AM 0.923205136 0.900055559 Normal 0.97492477 no VAPhilipMorrisPark500 B3 9/19/2009 10:00:00 AM 1.074256177 1.047318961 Normal 0.97492477 no WABoeingRenton BOIL04 08/17/09 20:00 1.225879483 1.195140278normal 0.97492477 no VAPhilipMorrisPark500 B3 9/18/2009 11:00:00 PM 1.335390069 1.301904862 Normal 0.97492477 no VAPhilipMorrisPark500 B3 9/19/2009 1.856760358 1.810201673 Normal 0.97492477 no VAPhilipMorrisPark500 B3 9/18/2009 8:00:00 AM 2.006538637 1.956224228 Normal 0.97492477 no VAPhilipMorrisPark500 B3 9/21/2009 6:00:00 AM 2.316277069 2.258195898 Normal 0.97492477 no WABoeingRenton BOIL04 08/26/09 20:00 2.547230377 2.483358001 normal 0.97492477 no VAPhilipMorrisPark500 B3 10/4/2009 1:00:00 AM 2.553965435 2.489924175 Normal 0.97492477 no WABoeingRenton BOIL04 08/26/09 19:00 2.618898212 2.553228749normal 0.97492477 no VAPhilipMorrisPark500 B3 9/20/2009 11:00:00 AM 2.657096028 2.590468745 Normal 0.97492477 no VAPhilipMorrisPark500 B3 9/18/2009 5:00:00 AM 2.942923334 2.869128868 Normal 0.97492477 no VAPhilipMorrisPark500 B3 9/18/2009 6:00:00 AM 2.942923334 2.869128868 Normal 0.97492477 no VAPhilipMorrisPark500 B3 9/17/2009 8:00:00 PM 3.534963191 3.446323191 Normal 0.97492477 no VAPhilipMorrisPark500 B3 9/17/2009 7:00:00 PM 3.560198884 3.470926093 Normal 0.97492477 no VAPhilipMorrisPark500 B3 9/18/2009 3:00:00 PM 3.611769547 3.52120361 Normal 0.97492477 no VAPhilipMorrisPark500 B3 9/17/2009 6:00:00 PM 4.219494973 4.113690184 Normal 0.97492477 no VAPhilipMorrisPark500 B3 9/21/2009 5:00:00 AM 5.589641809 5.44948028 Normal 0.97492477 no



### Appendix D-4, p77 of 82

## Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC

(ppm@3%O2) CombUnit_O

p_Indicator THC_Op_Ind

icator CO_Op_Indi

cator TNMOC TO

THC Ratio Outlier VAPhilipMorrisPark500 B3 9/21/2009 4:00:00 AM 6.939406829 6.765399637 Normal 0.97492477 no CATesoro S-974 Furance 55 9/14/2009 0.081277174 0.07923913 None 14:14-14:35 14:14-14:35 0.97492477 no CATesoro S-974 Furance 55 9/17/2009 0.142184075 0.138618777 None 18:35-18:59 18:35-18:59 0.97492477 no WABoeingRenton BOIL04 08/23/09 03:00 0.021957665 0.021407072 normal 0.97492477 no WABoeingRenton BOIL04 08/21/09 19:00 0.032976847 0.032149945normal 0.97492477 no WABoeingRenton BOIL04 08/23/09 02:00 0.032997058 0.032169649normal 0.97492477 no WABoeingRenton BOIL04 08/23/09 05:00 0.099112666 0.096627393 normal 0.97492477 no WABoeingRenton BOIL04 08/23/09 06:00 0.132231364 0.128915633 normal 0.97492477 no VAPhilipMorrisPark500 B3 9/20/2009 4:00:00 AM 0.132452091 0.129130825 Normal 0.97492477 no WABoeingRenton BOIL04 08/19/09 21:00 0.142463361 0.13889106 normal 0.97492477 no WABoeingRenton BOIL04 08/22/09 17:00 0.242126824 0.23605544 normal 0.97492477 no VAPhilipMorrisPark500 B3 11/2/2009 9:00:00 PM 0.254113089 0.247741146 Normal 0.97492477 no VAPhilipMorrisPark500 B3 9/19/2009 6:00:00 PM 0.262830488 0.256239954 Normal 0.97492477 no VAPhilipMorrisPark500 B3 11/3/2009 2:00:00 PM 0.263398525 0.256793747 Normal 0.97492477 no VAPhilipMorrisPark500 B3 11/3/2009 3:00:00 PM 0.263398525 0.256793747 Normal 0.97492477 no VAPhilipMorrisPark500 B3 11/3/2009 4:00:00 PM 0.263398525 0.256793747 Normal 0.97492477 no VAPhilipMorrisPark500 B3 9/21/2009 2:00:00 AM 0.265260105 0.258608648 Normal 0.97492477 no VAPhilipMorrisPark500 B3 11/2/2009 6:00:00 AM 0.284947602 0.277802477 Normal 0.97492477 no WABoeingRenton BOIL04 08/19/09 13:00 0.285275128 0.27812179 normal 0.97492477 no VAPhilipMorrisPark500 B3 9/18/2009 8:00:00 PM 0.400617021 0.390571459 Normal 0.97492477 no VAPhilipMorrisPark500 B3 9/18/2009 10:00:00 PM 0.400617021 0.390571459 Normal 0.97492477 no VAPhilipMorrisPark500 B3 9/18/2009 10:00:00 AM 0.401307727 0.391244846 Normal 0.97492477 no WABoeingRenton BOIL04 08/15/09 05:00 0.449856933 0.438576669normal 0.97492477 no WABoeingRenton BOIL04 08/15/09 11:00 0.482478309 0.470380056 normal 0.97492477 no VAPhilipMorrisPark500 B3 9/20/2009 7:00:00 AM 0.529808363 0.516523299 Normal 0.97492477 no WABoeingRenton BOIL04 08/15/09 03:00 0.537305389 0.523832335normal 0.97492477 no VAPhilipMorrisPark500 B3 10/31/2009 4:00:00 PM 0.567641942 0.553408192 Normal 0.97492477 no VAPhilipMorrisPark500 B3 10/31/2009 5:00:00 PM 0.567641942 0.553408192 Normal 0.97492477 no VAPhilipMorrisPark500 B3 10/31/2009 6:00:00 PM 0.567641942 0.553408192 Normal 0.97492477 no VAPhilipMorrisPark500 B3 10/31/2009 7:00:00 PM 0.567641942 0.553408192 Normal 0.97492477 no



### Appendix D-4, p78 of 82

## Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC

(ppm@3%O2) CombUnit_O

p_Indicator THC_Op_Ind

icator CO_Op_Indi

cator TNMOC TO

THC Ratio Outlier VAPhilipMorrisPark500 B3 10/31/2009 11:00:00 AM 0.576763619 0.562301141 Normal 0.97492477 no WABoeingRenton BOIL04 08/15/09 04:00 0.581878135 0.56728741 normal 0.97492477 no WABoeingRenton BOIL04 08/15/09 19:00 0.591049036 0.576228348normal 0.97492477 no WABoeingRenton BOIL04 08/15/09 10:00 0.593583241 0.578699008normal 0.97492477 no WABoeingRenton BOIL04 08/16/09 00:00 0.625028718 0.609355982 normal 0.97492477 no WABoeingRenton BOIL04 08/15/09 15:00 0.635605765 0.619667807 normal 0.97492477 no WABoeingRenton BOIL04 08/16/09 21:00 0.723717463 0.705570084 normal 0.97492477 no VAPhilipMorrisPark500 B3 10/31/2009 10:00:00 AM 0.726794103 0.708569577 Normal 0.97492477 no WABoeingRenton BOIL04 08/16/09 23:00 0.745192965 0.726507084 normal 0.97492477 no WABoeingRenton BOIL04 08/16/09 22:00 0.767579127 0.748331908normal 0.97492477 no WABoeingRenton BOIL04 08/12/09 19:00 0.810945286 0.79061065normal 0.97492477 no WABoeingRenton BOIL04 08/12/09 20:00 0.819901316 0.799342105normal 0.97492477 no WABoeingRenton BOIL04 08/16/09 15:00 0.853217116 0.831822504 normal 0.97492477 no WABoeingRenton BOIL04 08/13/09 18:00 0.975922033 0.951450568normal 0.97492477 no WABoeingRenton BOIL04 08/17/09 23:00 1.304884517 1.272164243 normal 0.97492477 no WABoeingRenton BOIL04 08/17/09 17:00 1.315046409 1.282071324 normal 0.97492477 no VAPhilipMorrisPark500 B3 10/31/2009 6:00:00 AM 1.404958246 1.369728601 Normal 0.97492477 no VAPhilipMorrisPark500 B3 9/19/2009 4:00:00 PM 1.576982927 1.537439724 Normal 0.97492477 no VAPhilipMorrisPark500 B3 9/18/2009 7:00:00 PM 1.602468083 1.562285834 Normal 0.97492477 no VAPhilipMorrisPark500 B3 9/20/2009 6:00:00 AM 1.85432927 1.807831545 Normal 0.97492477 no VAPhilipMorrisPark500 B3 9/18/2009 7:00:00 AM 1.872769395 1.825809279 Normal 0.97492477 no VAPhilipMorrisPark500 B3 9/20/2009 12:00:00 PM 1.94987505 1.900981493 Normal 0.97492477 no VAPhilipMorrisPark500 B3 9/19/2009 1:00:00 AM 2.254637578 2.198102032 Normal 0.97492477 no VAPhilipMorrisPark500 B3 9/17/2009 4:00:00 PM 2.618491252 2.552831993 Normal 0.97492477 no VAPhilipMorrisPark500 B3 9/19/2009 3:00:00 PM 2.759720122 2.690519517 Normal 0.97492477 no VAPhilipMorrisPark500 B3 9/17/2009 11:00:00 PM 2.788955657 2.719021964 Normal 0.97492477 no VAPhilipMorrisPark500 B3 9/18/2009 6:00:00 PM 2.788955657 2.719021964 Normal 0.97492477 no VAPhilipMorrisPark500 B3 9/18/2009 3:00:00 AM 2.809154092 2.738713919 Normal 0.97492477 no VAPhilipMorrisPark500 B3 9/18/2009 2:00:00 PM 3.320185306 3.23693091 Normal 0.97492477 no



### Appendix D-4, p79 of 82

## Appendix D-4: Development of Average VOC Content in THC

FacilityID CombustorID Date THC (ppm@3%O2) Non_CH4_HC

(ppm@3%O2) CombUnit_O

p_Indicator THC_Op_Ind

icator CO_Op_Indi

cator TNMOC TO

THC Ratio Outlier VAPhilipMorrisPark500 B3 9/19/2009 5:00:00 AM 3.475603897 3.388452345 Normal 0.97492477 no VAPhilipMorrisPark500 B3 9/19/2009 4:00:00 AM 3.821320164 3.725499698 Normal 0.97492477 no VAPhilipMorrisPark500 B3 9/21/2009 3:00:00 AM 4.320762742 4.212418642 Normal 0.97492477 no VAPhilipMorrisPark500 B3 9/19/2009 1:00:00 PM 4.468118293 4.356079218 Normal 0.97492477 no TXDibollTemple-Inland PB-44 0800-0900 4.16284458 4.058460312 0.97492477 no TXDibollTemple-Inland PB-44 0900-1000 4.695807328 4.5780589 0.97492477 no CATesoro S-974 Furance 55 9/11/2009 0.012128954 0.011824818 None 14:10-15:16 14:10-15:16 0.97492477 no WABoeingRenton BOIL04 08/22/09 19:00 0.065712193 0.064064445normal 0.97492477 no WABoeingRenton BOIL04 08/21/09 20:00 0.06591332 0.064260529normal 0.97492477 no VAPhilipMorrisPark500 B3 9/21/2009 7:00:00 AM 0.12999167 0.1267321 Normal 0.97492477 no VAPhilipMorrisPark500 B3 11/3/2009 1:00:00 PM 0.13266888 0.129342178 Normal 0.97492477 no VAPhilipMorrisPark500 B3 11/3/2009 12:00:00 PM 0.26533776 0.258684356 Normal 0.97492477 no WABoeingRenton BOIL04 08/15/09 01:00 0.516005139 0.503066194 normal 0.97492477 no WABoeingRenton BOIL04 08/16/09 03:00 0.59213247 0.577284614 normal 0.97492477 no WABoeingRenton BOIL04 08/15/09 23:00 0.690399365 0.673087445normal 0.97492477 no WABoeingRenton BOIL04 08/16/09 18:00 0.83032753 0.809506879normal 0.97492477 no VAPhilipMorrisPark500 B3 9/18/2009 11:00:00 AM 1.337692425 1.304149485 Normal 0.97492477 no WABoeingRenton BOIL04 08/25/09 20:00 1.367335121 1.333048885normal 0.97492477 no VAPhilipMorrisPark500 B3 9/20/2009 5:00:00 AM 2.384137633 2.324354844 Normal 0.97492477 no VAPhilipMorrisPark500 B3 9/18/2009 12:00:00 PM 2.541615607 2.477884022 Normal 0.97492477 no VAPhilipMorrisPark500 B3 9/18/2009 4:00:00 AM 2.675384849 2.60829897 Normal 0.97492477 no VAPhilipMorrisPark500 B3 9/18/2009 1:00:00 PM 2.675384849 2.60829897 Normal 0.97492477 no VAPhilipMorrisPark500 B3 9/17/2009 9:00:00 PM 3.032762012 2.95671482 Normal 0.97492477 no VAPhilipMorrisPark500 B3 9/19/2009 2:00:00 PM 4.336703049 4.227959241 Normal 0.97492477 no VAPhilipMorrisPark500 B3 9/17/2009 1:00:00 PM 5.142509499 5.013559912 Normal 0.97492477 no WABoeingRenton BOIL04 08/23/09 10:00 0.131988232 0.128678598normal 0.97492477 no CATesoro S-974 Furance 55 9/6/2009 0.845962805 0.836048043 None 09:44-10:13 09:44-10:13 0.98827991 no CATesoro S-974 Furance 55 9/9/2009 0.606520213 0.602682959 None 10:50-11:44 10:50-11:44 0.99367333 no



### Appendix D-4, p80 of 82

## Appendix D-4: Development of Average VOC Content in THC

1st Quartile 3rd Quartile IQR 1.5 IqR Test for Low Test for High Outliers 0.313908332 0.76605016 0.45214183 0.67821274 0.1010117 1.285595136 Number of Ratios 2509 Sum of Ratios 1440.09171 **Average of Ratio Data that are not**  **outliers: 57%**  Sample Statistics of TNMOC to THC Averages



### Appendix D-4, p81 of 82

## Appendix D-4: Development of Average VOC Content in THC

Appendix D-4, p82 of 82

## Appendix D-4: Development of Average VOC Content in THC

Appendix D-4, p83 of 82

## Appendix D-4: Development of Average VOC Content in THC

Appendix D-4, p84 of 82

## Appendix D-4: Development of Average VOC Content in THC

Appendix D-4, p85 of 82

## Appendix D-4: Development of Average VOC Content in THC

Appendix D-4, p86 of 82

## Appendix D-4: Development of Average VOC Content in THC

Appendix D-4, p87 of 82

## Appendix D-4: Development of Average VOC Content in THC

Appendix D-4, p88 of 82

## Appendix D-4: Development of Average VOC Content in THC

Appendix D-4, p89 of 82

## Appendix D-4: Development of Average VOC Content in THC

Appendix D-4, p90 of 82

## Appendix D-4: Development of Average VOC Content in THC

Appendix D-4, p91 of 82

## Appendix D-4: Development of Average VOC Content in THC

Appendix D-4, p92 of 82

## Appendix D-4: Development of Average VOC Content in THC

Appendix D-4, p93 of 82

## Appendix D-4: Development of Average VOC Content in THC

Appendix D-4, p94 of 82

## Appendix D-4: Development of Average VOC Content in THC

Appendix D-4, p95 of 82

## Appendix D-4: Development of Average VOC Content in THC

Appendix D-4, p96 of 82

## Appendix D-4: Development of Average VOC Content in THC

Appendix D-4, p97 of 82

## Appendix D-4: Development of Average VOC Content in THC

Appendix D-4, p98 of 82

## Appendix D-4: Development of Average VOC Content in THC

Appendix D-4, p99 of 82

## Appendix D-4: Development of Average VOC Content in THC

Appendix D-4, p100 of 82

## Appendix D-4: Development of Average VOC Content in THC

Appendix D-4, p101 of 82

## Appendix D-4: Development of Average VOC Content in THC

Appendix D-4, p102 of 82

## Appendix D-4: Development of Average VOC Content in THC

Appendix D-4, p103 of 82

## Appendix D-4: Development of Average VOC Content in THC

Appendix D-4, p104 of 82

## Appendix D-4: Development of Average VOC Content in THC

Appendix D-4, p105 of 82

## Appendix D-4: Development of Average VOC Content in THC

Appendix D-4, p106 of 82

## Appendix D-4: Development of Average VOC Content in THC

Appendix D-4, p107 of 82

## Appendix D-4: Development of Average VOC Content in THC

Appendix D-4, p108 of 82

## Appendix D-4: Development of Average VOC Content in THC

Appendix D-4, p109 of 82

## Appendix D-4: Development of Average VOC Content in THC

Appendix D-4, p110 of 82

## Appendix D-4: Development of Average VOC Content in THC

Appendix D-4, p111 of 82

## Appendix D-4: Development of Average VOC Content in THC

Appendix D-4, p112 of 82

## Appendix D-4: Development of Average VOC Content in THC

Appendix D-4, p113 of 82

## Appendix D-4: Development of Average VOC Content in THC

Appendix D-4, p114 of 82

## Appendix D-4: Development of Average VOC Content in THC

Appendix D-4, p115 of 82

## Appendix D-4: Development of Average VOC Content in THC

Appendix D-4, p116 of 82

## Appendix D-4: Development of Average VOC Content in THC

Appendix D-4, p117 of 82

## Appendix D-4: Development of Average VOC Content in THC

Appendix D-4, p118 of 82

## Appendix D-4: Development of Average VOC Content in THC

Appendix D-4, p119 of 82

## Appendix D-4: Development of Average VOC Content in THC

Appendix D-4, p120 of 82

## Appendix D-4: Development of Average VOC Content in THC

Appendix D-4, p121 of 82

## Appendix D-4: Development of Average VOC Content in THC

Appendix D-4, p122 of 82

## Appendix D-4: Development of Average VOC Content in THC

Appendix D-4, p123 of 82

## Appendix D-4: Development of Average VOC Content in THC

Appendix D-4, p124 of 82

## Appendix D-4: Development of Average VOC Content in THC

Appendix D-4, p125 of 82

## Appendix D-4: Development of Average VOC Content in THC

Appendix D-4, p126 of 82

## Appendix D-4: Development of Average VOC Content in THC

Appendix D-4, p127 of 82

## Appendix D-4: Development of Average VOC Content in THC

Appendix D-4, p128 of 82

## Appendix D-4: Development of Average VOC Content in THC

Appendix D-4, p129 of 82

## Appendix D-4: Development of Average VOC Content in THC

Appendix D-4, p130 of 82

## Appendix D-4: Development of Average VOC Content in THC

Appendix D-4, p131 of 82

## Appendix D-4: Development of Average VOC Content in THC

Appendix D-4, p132 of 82

## Appendix D-4: Development of Average VOC Content in THC

Appendix D-4, p133 of 82

## Appendix D-4: Development of Average VOC Content in THC

Appendix D-4, p134 of 82

## Appendix D-4: Development of Average VOC Content in THC

Appendix D-4, p135 of 82

## Appendix D-4: Development of Average VOC Content in THC

Appendix D-4, p136 of 82

## Appendix D-4: Development of Average VOC Content in THC

Appendix D-4, p137 of 82

## Appendix D-4: Development of Average VOC Content in THC

Appendix D-4, p138 of 82

## Appendix D-4: Development of Average VOC Content in THC

Appendix D-4, p139 of 82

## Appendix D-4: Development of Average VOC Content in THC

Appendix D-4, p140 of 82

## Appendix D-4: Development of Average VOC Content in THC

Appendix D-4, p141 of 82

## Appendix D-4: Development of Average VOC Content in THC

Appendix D-4, p142 of 82

## Appendix D-4: Development of Average VOC Content in THC

Appendix D-4, p143 of 82

## Appendix D-4: Development of Average VOC Content in THC

Appendix D-4, p144 of 82

## Appendix D-4: Development of Average VOC Content in THC

Appendix D-4, p145 of 82

## Appendix D-4: Development of Average VOC Content in THC

Appendix D-4, p146 of 82

## Appendix D-4: Development of Average VOC Content in THC

Appendix D-4, p147 of 82

## Appendix D-4: Development of Average VOC Content in THC

Appendix D-4, p148 of 82

## Appendix D-4: Development of Average VOC Content in THC

Appendix D-4, p149 of 82

## Appendix D-4: Development of Average VOC Content in THC

Appendix D-4, p150 of 82

## Appendix D-4: Development of Average VOC Content in THC

Appendix D-4, p151 of 82

## Appendix D-4: Development of Average VOC Content in THC

Appendix D-4, p152 of 82

## Appendix D-4: Development of Average VOC Content in THC

Appendix D-4, p153 of 82

## Appendix D-4: Development of Average VOC Content in THC

Appendix D-4, p154 of 82

## Appendix D-4: Development of Average VOC Content in THC

Appendix D-4, p155 of 82

## Appendix D-4: Development of Average VOC Content in THC

Appendix D-4, p156 of 82

## Appendix D-4: Development of Average VOC Content in THC

Appendix D-4, p157 of 82

## Appendix D-4: Development of Average VOC Content in THC

Appendix D-4, p158 of 82

## Appendix D-4: Development of Average VOC Content in THC

Appendix D-4, p159 of 82

## Appendix D-4: Development of Average VOC Content in THC

Appendix D-4, p160 of 82

### Appendix E-1: Area Source Baseline Emission Factors for Organic HAP and CO for Existing Units

**Fuel Category Combustor Design**  **NOx Control? Total # of Units**  **in Subcategory THC** 

**(ppm @ 3% as**  **Propane) TEQ** 

**Dioxins/ Furans**  **(ng/dscm @ 7%** **O2) CO (ppm** 

**@ 3% O2)**  **Formaldehyd**

**e (ppm @ 3% O2)**  **NOx (ppm**

**@ 3% O2)**  Coal Stoker/Sloped Grate/Other Yes 3,710 9.53 0.005 171.2 0.055 236.4 Biomass Stoker/Sloped Grate/Other Yes 10,958 10.53 0.02 365.38 3.29 145.31 Heavy Liquid - Yes 2,137 15.67 0.014 13.4 0.001 261.2 Light Liquid - Yes 165,866 12.70 0.003 44.5 0.467 56.4

## Appendix E-2: Area Source Baseline Emission Factors for Fuel-Based HAP and SO2 for Existing Units

**Fuel Category Non-Hg Metals** 

**Control Category**  **Total # of**

**Units in Sub Category**  **As**

**(lb/MMBtu) Be** 

**(lb/MMBtu) Cd** 

**(lb/MMBtu) Co** 

**(lb/MMBtu) Cr** 

**(lb/MMBtu) Ni** 

**(lb/MMBtu) Mn** 

**(lb/MMBtu) Pb** 

**(lb/MMBtu) Sb** 

**(lb/MMBtu) Se** 

**(lb/MMBtu)** Coal 5 3,710 1.68E-04 1.28E-05 3.18E-06 2.90E-06 7.03E-05 1.65E-04 1.13E-04 2.17E-04 8.29E-06 1.64E-04 Biomass 5 10,958 3.97E-05 2.07E-07 6.81E-06 8.80E-07 4.46E-05 1.45E-05 3.91E-03 9.73E-05 2.07E-06 3.58E-06 Heavy Liquid 6 2,137 5.08E-05 2.43E-05 2.40E-05 9.42E-05 5.84E-05 1.81E-03 7.24E-03 8.88E-05 7.74E-05 6.49E-05 Light Liquid 6 165,866 1.92E-04 5.72E-05 2.57E-05 2.25E-05 2.86E-04 2.40E-04 1.82E-02 3.30E-04 1.19E-04 2.10E-04

## Appendix E-2: Area Source Baseline Emission Factors for Fuel-Based HAP and SO2 for Existing Units

**Fuel Category** Coal Biomass Heavy Liquid Light Liquid **Hg Control**

**Category Total # of** 

**Units in Sub Category**  **Hg**

**(lb/MMBtu) PM Filterable** 

**Control Category**  **Total # of**

**Units in Sub Category**  **PM**

**Filterable (lb/MMBtu)**  6 3,710 4.38E-06 5 3,710 2.39E-01 6 10,958 1.41E-06 5 10,958 3.23E-01 6 2,137 3.60E-06 6 2,137 8.76E-02 6 165,866 6.94E-06 6 165,866 2.40E-02

## Appendix E-2: Area Source Baseline Emission Factors for Fuel-Based HAP and SO2 for Existing Units

**Fuel Category** Coal Biomass Heavy Liquid Light Liquid **Inorganic**

**Control Category**  **Total # of**

**Units in Sub Category**  **HCl**

**(lb/MMBtu) HF** 

**(lb/MMBtu) SO2 (ppm** 

**@ 3% O2)** 5 3,710 1.16E-01 3.27E-03 852.9 5 10,958 3.82E-03 9.47E-05 51.1 5 2,137 5.44E-03 3.08E-04 319.9 5 165,866 1.60E-02 3.02E-04 146.3