ARSENIC IN ROCKS AND STREAM 

SEDIMENTS OF THE CENTRAL 

APPALACHIAN BASIN, KENTUCKY 

by Michele L.W. Tuttle,1 Martin B. Goldhaber,1 Leslie F. Ruppert, 1 and 

James C. Hower2 

Open-File Report 02-28 

2002 

This report is preliminary and has not been reviewed for conformity 

with U.S. Geological Survey editorial standards or with the North 

American Stratigraphic Code. Any use of trade, firm, or product 

names is for descriptive purposes only and does not imply endorsement 

by the U.S. Government. 

U.S. DEPARTMENT OF THE INTERIOR 

U.S. GEOLOGICAL SURVEY 

1

 U.S. Geological Survey, MS 973, Box 25046, Denver CO 80225 

2

 University of Kentucky Center for Applied Energy Research, Lexington KY 

i 
TABLE OF CONTENTS 

Introduction ....................................................................................................................1 

Energy Resources in the Kentucky Appalachian Basin.................................................... 2 

Arsenic in Kentucky Appalachian Basin Coal ............................................................ 2 

Effect of regional structural features on spatial distribution of arsenic in eastern 

Kentucky coals..................................................................................................... 2 

Residence of arsenic in coal ....................................................................................... 2 

Arsenic in NURE samples from the Kentucky Appalachian Basin ................................ 10 

Possible controls on arsenic in NURE samples from the Kentucky 

Appalachian basin .............................................................................................. 10 

Arsenic in shale and coal collected in the Kentucky Appalachian basin......................... 13 

Relation between iron and arsenic in the eastern Kentucky coal ............................... 14 

Relation between iron and arsenic in the Devonian shale.......................................... 16 

Concluding remarks ...................................................................................................... 17 

References .................................................................................................................... 19 

Appendix I—NURE stream sediment data (reanalyzed)................................................ 20 

Analytical methods .................................................................................................. 20 

Stream sediment data ............................................................................................... 22 

Appendix II—Coal and Devonian shale seimiquantitative XRF data........................... 151 

Analytical methods ................................................................................................ 151 

Shale data............................................................................................................... 152 

Coal data................................................................................................................ 164 

FIGURES 

1. Map of Appalachian coal region in eastern USA ....................................................... 3 

2. 	 The resource map (A) shows coal resource by county. Photos (B-E) of the Kentucky 

coal industry............................................................................................................. 4 

3. Histogram of arsenic concentrations in Eastern Kentucky coal .................................. 6 

4. Spatial distribution of arsenic concentrations in east Kentucky coal........................... 7 

5. CSD’s of the Eastern United States ........................................................................... 8 

6. 	 Cross plots of arsenic versus pyritic sulfur in drill=core, channel, and weathered 

channel coal samples................................................................................................ 9 

7. 	 Histogram of arsenic concentrations in NURE stream sediments, Kentucky 

Appalachian Basin .................................................................................................. 11 

8. 	 Map showing generalized geology of the Kentucky Appalachian basin and arsenic 

concentrations in NURE stream sediments. ............................................................. 12 

9. Cross plot of arsenic versus iron divided into regions within the basin..................... 13 

10. Photos of shale and coal, Kentucky Appalachian basin............................................ 15 

11. Cross plot of iron versus arsenic in collected coal samples ...................................... 16 

12. Cross plots of iron versus arsenic in shale outcrop and core samples ...................... 18 

ii 
ARSENIC IN ROCKS AND STREAM SEDIMENTS 

OF THE CENTRAL APPALACHIAN BASIN, 

KENTUCKY 

By Michele L.W. Tuttle, Martin B. Goldhaber, Leslie F. Ruppert, and 

James C. Hower 

INTRODUCTION 

Arsenic (As) enrichment in coal and stream sediments has been documented in the 

southern Appalachian basin (see Goldhaber and others, submitted) and is attributed to 

interaction of rocks and coal with metamorphic fluids generated during the Allegheny 

Orogeny (late Paleozoic). Similarly derived fluids are expected to affect the coal and in 

the Kentucky Appalachian Basin to the north as well. In addition, similar processes may 

have influenced the Devonian oil shale on the western margin of the basin. The major 

goals of this study are to determine the effect such fluids had on rocks in the Kentucky 

Appalachian basin (fig. 1), and to understand the geochemical processes that control 

trace-metal source, residence, and mobility within the basin. This report includes data 

presented in a poster at the USGS workshop on arsenic (February 21 and 22, 2001), new 

NURE stream sediment data3

, and field data from a trip in April 2001. Although data for 

major and minor elements and all detectable trace metals are reported in the Appendices, 

the narrative of this report primarily focuses on arsenic. 

The study is divided in to three phases. The first phase is completed and inventoried 

trace-metal concentrations in stream sediments throughout the Kentucky Appalachian 

basin. The distribution of arsenic concentrations was used to identify areas enriched in 

arsenic relative to estimated background values4

. A summary of all chemical data from 

phase one is presented in Appendix I. The second phase is in progress and focuses on 

areas identified in phase one to have high concentrations of arsenic. Shale and coal from 

these regions were sampled for chemical and isotopic analyses and selective extractions 

to determine arsenic residence. Preliminary field data (including semi-quantitative X-ray 

fluorescence (XRF) data5

) are presented in this report. The quantitative chemical and 

stable isotopic data currently being collected and analyzed will be used to determine 

source, residence and mobility of trace elements during weathering. Some preliminary 

results are presented in Tuttle and others (2001). The third phase (to begin 2002) will 

3

 NURE stream sediment samples were retrieved from storage and reanalyzed in 2000.


4

 Estimated background values, as used in this report, represent average concentrations in stream sediments


within the defined area (e.g. United States, Central Appalachian basin, etc.).


5

 XRF data were collected using a hand-held Niton spectrophotometer that measures surface concentrations


(the use of the trade name Niton is for descriptive purposes only and does not imply endorsement by the


U.S. Government).


1

focus on specific watersheds to help identify processes that affect trace-element 

concentrations in streams and associated ecosystems. 

ENERGY RESOURCES IN THE KENTUCKY APPALACHIAN BASIN 

The Kentucky Appalachian basin has about 28 billion tons of recoverable coal today (fig. 

2). There is about 190 billion barrels of synthetic oil in surface and near-surface 

Devonian oil shale within Kentucky (Matthews and others, 1981)--with a substantial 

portion along the western margin of the Appalachian basin. Although oil shale currently 

is not targeted for mining, most of the available coal in Kentucky will be mined. 

Arsenic in Kentucky Appalachian Basin Coal 

The geometric mean of arsenic in the eastern Kentucky coals is 11 ppm (U.S. Geological 

Survey Coal quality Database; Bragg and others, 1997). Over one-half of these coals 

have concentrations greater than the geometric mean concentration (6.1 ppm) for all US 

coals in the database. Because the arsenic concentrations are log normally distributed 

(see fig. 3), all averages are given as geometric means. 

Effect of Regional Structural Features on Spatial Distribution of Arsenic in Eastern 

Kentucky Coals 

High arsenic concentrations (>24 ppm) in Kentucky coal appear to be oriented in lines 

trending northeast to southwest or northwest to southeast (fig. 4). The northeast to 

southwest trends are parallel to the regional trend of Appalachian fold and faults. The 

perpendicular trend (northwest to southeast) is parallel to mapped cross strike 

discontinuities (CSD; Coleman and others, 1988) (fig. 5). These CSD's and major 

Appalachian folds and faults could have focused hydrothermal fluids generated during 

orogenic processes into the Kentucky Appalachian Basin. 

Eastern Kentucky coal rank increases to the southeast, probably due, in part, to a 

southeastward increase in paleogeothermal gradient (Hower and others, 1991). Flow of 

mineralizing hydrothermal fluids through the Central Appalachian Basin along CSD's 

from southeast to northwest is consistent with these paleogeothermal gradients. 

Residence of Arsenic in Coal 

Figure 6 shows arsenic concentrations plotted against pyritic sulfur concentrations for the 

drill-core, channel, and weathered channel samples in the USGS Coal Quality Database. 

The three plots all show a positive relation between the two variables indicating that 

pyrite is a likely candidate for the residence of the arsenic in the coal. A similar relation 

was found in all U.S. coals (Coleman and Bragg, 1990). The scatter in each of the plots 

likely reflects variations in the ratio of early diagenetic pyrite to epigenetic pyrite in the 

coal samples and variable amounts of siderite present in the coal. 

2

3

Kentucky

Tennessee

Alabama

Georgia

South Carolina

North Carolina

Virginia

 West

Virginia

Pennsylvania

Ohio

Study area

400 miles

0 400 kilometers

0

Appalachian Basin

North

Figure 1. Map of the Appalachian Coal Region in Eastern USA showing location of

study area. (modified from Britton and others, 1989)
A. 

 of Coal 

4

C. 

B. 

E. 

D. 

Figure 2. 	The resource map (A) shows eastern Kentucky coal resources by county. 

Photos (B-E) of the Kentucky coal industry and resource map were 

downloaded from 

http://www.coaleducation.org/Ky_Coal_Facts/main_coal_facts.htm 

5

6.1 ppm, geometric mean for US coals 

 n = 8823 

11 ppm, geometric mean for eastern 

 Kentucky coals 

 n = 780 

 

0 

50 

100 

150 

200 

250 

300 

350 

400 

450 

number of samples 

0 100 200 300 400 500 600 700 

As ppm 

 

 

 

Figure 3. 	Histogram of arsenic concentrations (whole-rock basis) in Eastern Kentucky 

Coal (data from Coleman and Bragg, 1990; Bragg and others, 1997). 

6

As concentration (ppm) 

Figure 4. Spatial distribution of arsenic concentrations (ppm) in east Kentucky coal. 

7

Kentucky 

Atlantic 

Ocean 

 

 

Appalachian 

Frontal Thrust 

Mesozoic Rift 

Sequence Oncap 

Cross Strike 

 Discontinuity 

(CSD's) 

Trend of hypothetical 

fluid flow along CSD's 200 miles 

322 km 

N 

Figure 5. 	CSD's of the Eastern United States. Eastern Kentucky shown in green 

(Coleman and others, 1988). 

8

.1 

1 

10 

100 

1000 

log (As ppm) 

.01 .1 1 10 

log (pyritic S %) 

Channel samples 

.1 

1 

10 

100 

1000 

log (As ppm) 

.01 .1 1 10 

log (pyritic S %) 

Drill core samples 

.1 

1 

10 

100 

1000 

.01 .1 1 10 

log (pyritic S %) 

Weathered channel samples 

 

Figure 6. 	Cross plots of Arsenic (ppm) versus pyritic sulfur (wt % S) in drill-core, 

channel, and weathered channel coal samples. 

9

Diagenetic pyrite formed early in the peat's history would not accumulate arsenic unless 

arsenic was in the peat pore water. Whether the peat was influenced by seawater or not, 

it is unlikely that large amounts of arsenic would be available during, or shortly after, 

peat deposition. Most arsenic in the Warrior Basin to the South is associated with 

epigenetic pyrite formed when mineralizing fluids moved through the Alabama coals 

after deposition and early diagenesis (see Goldhaber and others, submitted). We 

hypothesize that the enrichment of arsenic in eastern Kentucky coals occurred under 

similar conditions to those in Alabama. 

ARSENIC IN NURE SAMPLES FROM THE KENTUCKY 

APPALACHIAN BASIN 

Twelve hundred forty NURE (National Uranium Resource Evaluation) stream sediment 

samples from the Kentucky Appalachian Basin were reanalyzed because of improved 

detection limits for arsenic and other metals. Ninety-three per cent of the samples have 

arsenic concentrations less than 10 ppm, the average arsenic abundance in shale 

(Wedepohl, 1974) (fig. 7). High arsenic concentrations along the western edge of the 

basin correlate with exposure of arsenic-enriched Upper Devonian black shale (Leventhal 

and Kepferle, 1982) (fig. 8). 

Some stream sediments from the eastern Kentucky coal region are high in arsenic 

(Pennsylvanian rocks in fig. 8). Arsenic-enrichment in this portion of the basin likely is 

associated with streams impacted by coal mining and agriculture (Porter and others; 

1995). 

Possible Controls on Arsenic in NURE Samples from the Kentucky Appalachian 

Basin 

Elevated amounts of iron oxyhydroxide precipitates in streams affected by coal mining 

have been reported in eastern Kentucky coal region (Porter and others, 1995). Arsenic 

released to the environment either through natural weathering processes or human 

activity such as coal mining is adsorbed onto iron oxyhydroxide precipitates (Cullen and 

Reimer, 1989). 

The cross plot in Figure 9 shows the relation between arsenic concentration (ppm) and 

iron concentration (wt%) in NURE stream sediment samples. In the coal region 

(Kentucky Appalachian Basin proper), there is a weak, but observable positive relation 

between the two variables. The scatter in these data is likely due to variability in the 

availability of arsenic in the drainage basin. On the northwest margin of the basin where 

the Devonian black shale crops out, there is a strong positive relation between the two 

variables. Several samples from the coal region (pink dots) plot in the Devonian black 

shale field and suggest that these stream sediments accumulated arsenic over and above 

most stream sediment in the coal region. 

10

0 

50 

100 

150 

200 

250 

300 

350 

400 

450 

500 

Number of samples 

0 10 20 30 40 50 60 

As ppm 

10 ppm, abundance of As 

in Wedepohl's average shale 

3.8 ppm, geometric mean 

for Nure stream sediments 

Geometric mean for As in  

Kentucky Devonian black 

shale = 40 ppm 

 

Figure 7. 	Histogram of arsenic concentrations in 1,200 NURE stream sediments, 

Kentucky Appalachian Basin (abundance data from Wedepohl, 1974; 

Kentucky Devonian shale data from 14 core samples of Leventhal and 

Kepferle, 1982). 

11

As concentration (ppm) 

Tertiary 

Cretaceous 

Pennsylvanian 

Mississippian & Upper Devonian 

Ordovician 

1-5 6-14

15-32 

33-57 

58-110 

0 0K ilometers 

Alluvium 

Silurian 

Geology 

2 

Figure 8. 	Map showing generalized geology of the Kentucky Appalachian Basin, and 

arsenic concentrations (ppm) in NURE stream sediments. 

12

13

0

20

40

60

80

100

As ppm

0 2 4 6 8 10 12

Fe 

Devonian black

 shale region

Coal region

Mean As for all data

Figure 9. 

basin. 

dots; data from the Coal region that plot with those from the Devonian black

shale region.

ARSENIC IN SHALE AND COAL COLLECTED IN THE KENTUCKY

APPALACHIAN BASIN

Our sampling of the Devonian New Albany Formation was designed to test the working

hypotheses that the formation is the source of anomalously high concentrations of

Arsenic in sediments on the western margin of the Kentucky Appalachian basin. 

wt%

Cross plot of arsenic (ppm) versus iron (wt %) divided into regions within the

Geometric mean calculated from all data reanalyzed in this study. Pink

In
addition, our study will investigate the weathering processes that transport the arsenic to 

the stream sediments. Five types of New Albany Shale samples were collected at an 

outcrop near Clay City (fig. 10A). The first was surface samples from a horizontal 

transect across the face of a roadcut (fig. 10A and 10B). These samples (n = 17) 

represent a weathering profile related to topography in the region and surface weathering 

since the roadcut. The second type was unexposed samples directly behind the first type 

(fig. 10B). These samples (n = 9) represent a weathering profile related to topography, 

with minimal surface weathering related to the road cut. The third type was soils that 

developed on the side of the transect (n = 4) (fig. 10A). The fourth type was from a drill 

core taken a short distance from the outcrop. These samples (n = 22) represent 

unweathered shale material. In addition, shale fragments that had been mechanically 

weathered from the outcrop (n = 3) and salt crusts on the shale (n = 4) were also sampled. 

The semiquantitative XRF data for all samples are in Appendix II. 

Coal samples were collected at 4 mines to test the hypothesis that arsenic mobilized 

during weathering of pyrite in the Kentucky coal is the source of arsenic anomalies in the 

Appalachian basin proper. Bench samples were collected at each mine for analyses by 

the USGS coal package (data not included in this report). Pyrite and associated coal (n = 

11) were sampled at each mine except at one where no pyrite could be found. The 

semiquantitative XRF data on these pyritic samples are in Appendix II. Three of the 11 

coals are from the fold-belt at Pound Gap (Chestnut, 1998) (fig. 10C) and were collected 

to test the hypothesis of large-scale fluid flow through this region. 

Relation between Iron and Arsenic in the Eastern Kentucky Coal 

Compared to the coal in the Warrior Basin in Southern Appalachia, there is visually less 

pyrite in the Kentucky coal. Also, there appears to be much less structural features in the 

coal suggesting fewer conduits for epigenetic fluid flow. Figure 11 indicates that there is 

an increase in arsenic concentration with increasing iron content in Eastern Kentucky 

coals. This is consistent with the data in Figure 4 from the USGS coal database, as most 

of the iron in these mineral-poor coals is assumed to be pyrite, although some siderite 

nodules have been noted. The coal from the Pine Mountain Thrust contained no visible 

pyrite, but one sample contains appreciable arsenic (74 ppm As)—a possible imprint left 

by migrating fluids through the region. 

14

15

Figure 10. Photos of A) transect across the Devonian outcrop (Clay City, Kentucky), B) 

surface weathered and "fresh" shale behind, and C) two coal beds in Pound 

Gap roadcut. 

0 

5 

10 

15 

20 

25 

30 

35 

Semiquantitative Fe (wt%) 

0 100 200 300 400 500 

Semiquantitative As (ppm) 

Pine Mountain Trust Footwall 

Nally Hamilton-Long Fork Mine 

Nally Hamilton-Gordon Letcher Cnty mine 

Hindman road cut 

H5A-3 mine 

1800 ppm 

Figure 11. Cross plot of iron versus arsenic in coal collected from the Kentucky 

Appalachian basin. 

Relation between Iron and Arsenic in the Devonian Shale 

There appears to be a strong relation between iron (likely as iron hydroxides) on 

weathered shale samples from the outcrop and arsenic content (fig. 12A). This relation 

suggests that arsenic and iron from pyrite in the shale is mobilized during weathering and 

redeposited as iron hydroxides on the shale surfaces. Our preliminary working 

hypothesis mechanically transports the arsenic into stream sediments bound to this 

weathering rind. Once in the stream, the arsenic will remain bound to the iron 

hydroxides until chemical conditions radically change--the iron hydroxide dissolves or 

the pH of the stream increases dramatically causing the arsenic to desorb from the iron 

hydroxide surface. 

16

Salts (mostly iron sulfates) forming on the outcrop accumulate arsenic (concentrations up 

to 170 ppm As; Tuttle and others, 2001). When these salts dissolve, they release the 

arsenic. This arsenic probably ends up in the iron oxyhydroxides that either form on the 

shale fragments or on the stream sediments (Tuttle and others, 2001). 

In the core, both the shale samples and those containing significant pyrite as nodules, 

beds, etc. show a similar linear relationship between Fe and As (fig. 12B); however, the 

slope of the linear best fit is different between the two core populations. This difference 

indicates that the pyrite-enriched samples have a lesser amount of arsenic per unit iron 

than the shale. The residence of arsenic in the shale samples may be different than pyrite, 

or arsenic may have been less available for incorporation into the more massive pyrite 

that formed during later stages of diagenesis. 

CONCLUDING REMARKS 

Eastern Kentucky coal has less pyrite than that in the Warrior basin to the south. The 

difference may reflect less structural deformation in the Kentucky coal during the 

Allegheny Orogeny, hence fewer fluid migration pathways. Most of the epigenetic pyrite 

we sampled in the Kentucky coal was arsenic enriched. Weathering of this pyrite on 

mine-waste piles or on outcrop, will produce acid solutions that mobilize the iron and 

arsenic. Long-range transport of arsenic is unlikely because it will adsorb onto iron 

oxyhydroxides as the acidic water is neutralized. 

Along the western margin of the Kentucky Appalachian basin, the source of arsenic in 

the stream sediment appears to be the New Albany Shale. Weathering rinds on the shale 

surfaces are enriched in arsenic relative to the unweathered shale surfaces. It appears that 

weathering of arsenic-rich pyrite within the shale mobilizes arsenic and iron that is 

redeposted on the shale surface. Mechanical transport of weathering rinds on shale 

fragments appear to be the primary transport mechanism of the arsenic into the stream 

sediment. Some arsenic accumulates in weathering salts on the outcrop. Arsenic in these 

salts is mobilized during salt dissolution, but likely is adsorbed quickly onto iron oxides. 

Currently, quantitative chemical and stable isotopic data are being collected. Data will be 

used to test our working hypotheses developed for arsenic, determine source, residence 

and mobility of other trace elements in Kentucky coal and Devonian New Albany Shale, 

and pick additional sites for more detailed follow-up studies on trace-metal effects on 

streams and ecosystems. 

17

0 

10 

20 

30 

40 

50 

60 

Semiquantiative Fe (wt%) 

0 100 200 300 400 500 600 

Semiquantitative As (ppm) 

Weathering salt 

Shale 

Pyrite 

0 

5 

 

10 

 

15 

 

20 

 

25 

0 25 50 75 100 125 150 175 200 225 

weathered shale 

unweathered shale 

soil 

salt 

Semiquantitative As (ppm) 

Semiquantiative Fe (wt%) 

r 2 

r 

2 

r 2 

A. 

B. 

 

3500 ppm 

= .96

= .82 (w/o outlier)

= .73

Figure 12. Cross plots of A) iron versus arsenic in outcrop samples (regression on 

weathered samples only) and B) iron versus arsenic in core samples of shale 

and shale containing large amounts of pyrite; outlier not included in 

18

REFERENCES 

Bragg, L.J., Oman, J.K., Tewalt, S.J., Oman, C.L., Rega, N.H., Washington, P.M., and 

Finkelman, R.B., 1997, U.S. Geological Survey Coal Quality (COALQUAL) 

Database: Version 2.0: U.S. Geological Survey Open-file Report 97-134, CDROM. 

Britton, L.J., Anderson, C.L., Goolsby, D.A., and Van Haveren B.P., 1989, Summary of 

the U.S. Geological Survey and U.S. Bureau of Land Management National 

Coal-Hydrology Program, 1974-84: U.S. Geological Survey Professional 

Paper 1464, 183 p. 

Chesnut, D.R., Jr., 1998, Geology of the Pound Gap Road cut, Letcher County, 

Kentucky: 1998 Annual Field Conference of the Kentucky Society of 

Professional Geologists, 169 p. 

Coleman, J.L., Groshong, R.H., Rheams, K.F., Neathery, T.L., and Rheams, L.J., 1988, 

Structure of the Wills Valley Anticline-Lookout Mountain Syncline Between 

the Rising Fawn and Anniston CSD's, Northeast Alabama, a guidebook for the 

25th annual field trip of The Alabama Geological Society, 1988, 120 p. 

Coleman, S.L., and Bragg, L.J., 1990, Distribution and mode of occurrence of arsenic in 

coal, in, Chyi, L.L. and Chou, C.L., eds., Recent advances in coal 

geochemistry: Geological Society Special Paper 248, p. 13-26. 

Cullen, W.R., and Reimer, K.J., 1989, Arsenic speciation in the environment: Chemical 

Reviews, v. 89, no. 4, p. 713-764. 

Goldhaber, M.B., Lee, R.C., Hatch, J.R., Pashin, J.C., and Treworgy, J., in press, Role of 

large scale fluid-flow in subsurface arsenic enrichment., in, Welch, A. and 

Stollenwerk, K., (eds.), Arsenic in Ground Water: Occurrence and 

Geochemistry. Norwell, Kluwer Academic Puplishers. 

Hower, J.C., and Rimmer, S.M., 1991, Coal rank trends in the Central Appalachian 

coalfield: Virginia, West Virginia, and Kentucky: Organic Geochemistry, v. 

17, p. 161-173. 

Leventhal, J.S., and Kepferle, R.C., 1982, Geochemistry and geology of strategic metals 

and uranium in Devonian shales of the Eastern Interior United States: 

Synthetic Fuels from Oil Shales II. Proceeding of the symposium sponsored 

by Institute of Gas Technology, Nashville, Tennessee, October 26-29, 1982. 

Matthews, R.D., Janka, J.C., Dennison, J.M., 1981, Extraction methods and reserves of 

Devonian-Mississippian oil shales in Kentucky, in, Pryor, W.A., Maynard J.B., 

Potter, P.E., Fist, H.N., Kepferle, R.C., Kiefer, J., eds., Energy Resources of 

Devonian-Mississippian shales of Eastern Kentucky: Annual Field Conference 

of the Geological Society of Kentucky, April 9-11, 1981, p. 8. 

Porter, S.D., White, K.D., and Clark, J.R., 1995, Water-quality assessment of the 

Kentucky River Basin, Kentucky: Distribution of metals and other trace 

elements in sediment and water, 1987-90: U.S. Geological Survey Water 

Resources Investigations Report 94-4134, 184 p. 

Tuttle, M.L.W., Goldhaber, M.B., and Breit, G.N., 2001, Mobility of metals from 

weathered black shale: the role of salt efflorescences: Geological Society of 

America Abstracts with Programs, v. 33, p. A-191. 

Wedepohl, K.H., 1974, Handbook of Geochemistry. Berlin, Springer-Verlag. 

19

APPENDIX I--NURE STREAM SEDIMENT DATA (REANALYZED) 

The <100 μm fraction of the sample was generally analyzed. In some cases, the <40μm 

and >100μm fraction was analyzed if the <100 μm fraction was not available. Both 

fractions from 43 samples were analyzed to cross check concentrations. The lowest 

arsenic concentration of the pair was on the average 30% lower than the higher 

concentration. In 77% of the pairs, the higher concentration was in the finer-grained 

fraction. 

Analytical Methods 

Arsenic was determined by weighing 0.1 g of sample into a zirconium crucible. 

Approximately 0.75 g of sodium peroxide is added and mixed. The mixture is heated in a 

muffle furnace set at 750°C for four minutes. The sample is cooled then 15 ml of water 

and 5 ml of concentrated HCl is added. The mixture is shaken and 0.25 ml of an ascorbic 

acid KI solution is added then diluted with 20% HCl and let to stand overnight. Arsenic 

is then measured using hydride generation atomic absorption spectrometry. The optimum 

concentration ranges without sample dilution for arsenic in various solid phase sample 

media is 0.6 ppm to 20 ppm. Sample weight is 0.1 g and data will be deemed acceptable 

if recovery of As is ±20% at five times the LOD and the calculated percent RSD of 

duplicate samples is no greater than 20%. 

Forty major, minor, and trace elements were determined in geological materials by 

inductively coupled plasma-atomic emission spectrometry (ICP-AES). The sample is 

decomposed using a mixture of hydrochloric, nitric, perchloric, and hydrofluoric acids at 

low temperature. The digested samples are aspirated into the ICP-AES discharge where 

the elemental emission signal is measured simultaneously for the forty elements. 

Calibration is performed by standardizing with digested rock reference materials and a 

series of multi-element solution standards. Sample weight was 0.2 g 

Reporting limits for 40 elements by ICP-AES: 

Element: 

Aluminum, Al 

Calcium, Ca 

Iron, Fe 

Potassium, K 

Magnesium, Mg 

Sodium, Na 

Phosphorous, P 

Titanium, Ti 

Silver, Ag 

Arsenic, As 

Gold, Au 

Barium, Ba 

Beryllium, Be 

Concentration Range 

0.005 - 50% 

0.005 - 50% 

0.02 - 25% 

0.01 - 50% 

0.005 - 5% 

0.005 - 50% 

0.005 - 50% 

0.005 - 25% 

2 - 10,000 ppm 

10 - 50,000 ppm 

8 - 50,000 ppm 

1 - 35,000 ppm 

1 - 5,000 ppm 

20

Element: 

Bismuth, Bi 

Cadmium, Cd 

Cerium, Ce 

Cobalt, Co 

Chromium, Cr 

Copper, Cu 

Europium, Eu 

Gallium, Ga 

Holmium, Ho 

Lanthanum, La 

Lithium, Li 

Manganese, Mn 

Molybdenum, Mo 

Niobium, Nb 

Neodymium, Nd 

Nickel, Ni 

Lead, Pb 

Scandium, Sc 

Tin, Sn 

Strontium, Sr 

Tantalum, Ta 

Thorium, Th 

Uranium, U 

Vanadium, V 

Yttrium, Y 

Ytterbium, Yb 

Zinc, Zn 

Concentration Range 

10 - 50,000 ppm 

2 - 25,000 ppm 

5 - 50,000 ppm 

2 - 25,000 ppm 

2 - 25,000 ppm 

2 - 15,000 ppm 

2 - 5,000 ppm 

4 - 50,000 ppm 

4 -5,000 ppm 

2 - 50,000 ppm 

2 - 50,000 ppm 

4 - 50,000 ppm 

2 - 50,000 ppm 

4 - 50,000 ppm 

9 - 50,000 ppm 

3 - 50,000 ppm 

4 - 50,000 ppm 

2 - 50,000 ppm 

5 - 50,000 ppm 

2 - 15,000 ppm 

40 - 50,000 ppm 

6 - 50,000 ppm 

100 - 100,000 ppm 

2 - 30,000 ppm 

2 - 25,000 ppm 

1 - 5,000 ppm 

2 - 15,000 ppm 

Data is deemed acceptable if recovery for all 40 elements is ±15% at five times the 

Lower Limit of Determination (LOD) and the calculated Relative Standard Deviation 

(RSD) of duplicate samples is no greater than 15%. 

21

22

Longitude County As ppm Al % Ca % Fe % K% Mg % Na % P %

83.7077 Bell 6.2 6.0 0.12 3.0 1.7 0.43 0.37 0.04983.6535 Bell 3.5 4.0 0.050 2.2 1.2 0.24 0.30 0.04383.6323 Bell 8.5 5.6 0.13 3.3 1.7 0.43 0.18 0.03883.5757 Bell 23 6.5 2.8 3.6 1.7 0.66 0.13 0.02783.5428 Bell 3.1 5.0 0.072 2.0 1.7 0.32 0.12 0.02783.5388 Bell 3.9 3.7 0.061 2.1 1.1 0.21 0.085 0.02783.5363 Bell 3.1 3.0 0.039 1.9 0.87 0.17 0.11 0.02283.5802 Bell 2.9 3.4 0.083 1.9 1.0 0.21 0.18 0.02783.7034 Bell 5.6 4.1 0.077 2.5 1.2 0.27 0.23 0.03883.7766 Bell 3.5 3.5 0.077 1.9 1.1 0.21 0.25 0.02783.8077 Bell 4.6 5.8 0.14 3.0 1.7 0.39 0.26 0.03883.6528 Bell 1.9 2.2 0.14 1.1 0.57 0.15 0.035 0.01683.6077 Bell 3.9 3.0 0.13 1.9 0.82 0.22 0.10 0.02783.5203 Bell 1.9 1.8 0.033 1.1 0.47 0.11 0.045 0.01683.5014 Bell 3.7 3.9 0.13 2.2 1.2 0.28 0.23 0.02783.5501 Bell 4.5 5.0 0.36 2.5 1.4 0.39 0.22 0.03883.5532 Bell 3.7 4.3 0.31 2.0 1.2 0.33 0.24 0.03283.5125 Bell 3.7 4.5 0.099 2.3 1.2 0.33 0.30 0.03283.6679 Bell 1.4 1.3 0.044 0.89 0.31 0.070 0.025 0.01183.5881 Bell 1.5 1.7 0.072 0.92 0.39 0.12 0.045 0.01683.6043 Bell 5.4 3.9 0.066 2.1 1.0 0.24 0.20 0.02783.6363 Bell 6.3 5.5 0.099 3.0 1.5 0.39 0.30 0.04383.6559 Bell 6.9 5.4 4.4 2.7 1.5 0.79 0.27 0.03883.7572 Bell 5.7 5.4 0.15 2.8 1.6 0.40 0.28 0.04383.7881 Bell 3.8 4.5 0.094 2.4 1.2 0.29 0.20 0.03883.8253 Bell 4.8 5.4 0.22 2.9 1.5 0.40 0.24 0.03883.8766 Bell 3.5 3.6 0.13 2.2 1.0 0.23 0.10 0.03283.8277 Bell 6.4 4.8 0.12 2.8 1.4 0.35 0.075 0.03883.7667 Bell 6.1 4.5 0.12 2.7 1.3 0.32 0.15 0.038
23

Longitude County As ppm Al % Ca % Fe % K% Mg % Na % P %

83.8930 Bell 16 6.4 0.077 2.9 1.8 0.43 0.23 0.03883.9327 Bell 7.3 5.0 0.28 2.9 1.4 0.36 0.25 0.043

83.4210 Breathitt 3.7 3.4 0.11 2.3 1.0 0.22 0.43 0.03283.4012 Breathitt 3.6 3.6 0.050 1.9 1.1 0.20 0.44 0.02783.3583 Breathitt 3.0 3.6 0.061 1.6 1.2 0.20 0.47 0.02283.3966 Breathitt 3.9 4.0 0.077 2.0 1.2 0.27 0.55 0.03283.3896 Breathitt 3.3 4.1 0.066 2.1 1.2 0.27 0.47 0.02783.3745 Breathitt 3.7 4.5 0.083 2.3 1.3 0.31 0.36 0.03283.3440 Breathitt 3.4 3.5 0.061 1.9 1.1 0.23 0.28 0.02783.2879 Breathitt 1.2 2.3 0.039 1.1 0.92 0.14 0.24 0.01683.3127 Breathitt 3.1 3.5 0.050 1.9 1.1 0.23 0.39 0.02283.3075 Breathitt 2.4 2.4 0.044 1.5 0.82 0.15 0.19 0.02283.2915 Breathitt 2.1 1.8 0.028 1.2 0.63 0.091 0.13 0.01683.2539 Breathitt 1.6 1.7 0.028 1.1 0.65 0.086 0.13 0.01183.2670 Breathitt 1.8 3.1 0.066 1.3 1.1 0.18 0.36 0.02783.2254 Breathitt 1.5 1.4 0.018 0.83 0.52 0.069 0.11 0.01083.2272 Breathitt 2.0 2.7 0.053 1.1 0.98 0.15 0.22 0.01583.2078 Breathitt 2.5 3.4 0.053 1.5 1.1 0.18 0.19 0.01583.1960 Breathitt 2.1 3.0 0.047 1.3 1.1 0.16 0.20 0.02083.3414 Breathitt 2.8 3.1 0.053 1.5 0.99 0.18 0.41 0.02083.3173 Breathitt 4.3 9.0 2.5 3.2 2.0 0.73 0.23 0.03583.2831 Breathitt 1.8 2.3 0.035 1.0 0.86 0.11 0.19 0.01083.2550 Breathitt 1.5 2.2 0.61 0.82 0.9 0.12 0.18 0.01583.1622 Breathitt 1.5 2.7 0.047 1.1 0.97 0.14 0.17 0.01083.1789 Breathitt 1.6 3.3 0.047 1.3 1.1 0.18 0.19 0.02083.3587 Breathitt 2.1 2.9 0.041 1.3 0.95 0.17 0.28 0.01583.3472 Breathitt 5.0 3.3 0.059 1.6 1.2 0.19 0.30 0.02583.2993 Breathitt 5.9 8.1 0.19 3.4 2.1 0.52 0.27 0.04083.3209 Breathitt 5.9 5.0 0.11 2.3 1.4 0.36 0.33 0.030
24

Longitude County As ppm Al % Ca % Fe % K% Mg % Na % P %

83.3647 Breathitt 3.8 4.5 0.082 2.0 1.4 0.31 0.39 0.03083.1869 Breathitt 2.0 1.9 0.029 1.0 0.68 0.11 0.12 0.01083.1854 Breathitt 1.8 2.5 0.047 1.2 0.97 0.14 0.22 0.01583.1536 Breathitt 2.9 5.6 0.10 2.1 1.8 0.36 0.21 0.03083.1469 Breathitt 2.3 3.6 0.064 1.7 1.3 0.22 0.18 0.01583.1269 Breathitt 2.8 2.3 6.2 1.4 0.8 0.17 0.19 0.01583.0912 Breathitt 1.6 2.4 0.029 0.86 0.95 0.11 0.20 0.01083.0657 Breathitt 1.4 2.0 0.035 0.83 0.81 0.098 0.14 0.01583.0232 Breathitt 1.8 2.9 0.041 1.2 1.0 0.14 0.17 0.01583.0260 Breathitt 1.4 1.5 0.018 0.62 0.66 0.069 0.10 0.00582.9931 Breathitt 2.9 2.2 0.035 0.95 0.93 0.098 0.21 0.01083.0852 Breathitt 3.0 3.6 0.029 1.6 1.2 0.18 0.10 0.02083.1197 Breathitt 2.7 3.4 0.27 1.4 1.3 0.17 0.22 0.02083.1028 Breathitt 1.4 2.2 0.023 0.74 0.88 0.098 0.14 0.01083.3314 Breathitt 5.1 4.7 0.50 2.8 1.4 0.37 0.54 0.04083.3015 Breathitt 1.7 2.3 0.035 1.1 0.92 0.11 0.28 0.01583.2830 Breathitt 3.4 3.8 0.11 1.8 1.1 0.22 0.37 0.02583.2728 Breathitt 1.5 2.5 0.041 0.99 0.90 0.14 0.19 0.01583.2345 Breathitt 1.4 2.0 0.053 0.94 0.75 0.11 0.11 0.01083.2414 Breathitt 1.3 2.4 0.035 1.1 0.96 0.13 0.14 0.01083.2156 Breathitt 2.1 2.2 0.053 1.1 0.88 0.12 0.18 0.01083.1976 Breathitt 3.9 2.7 0.047 1.7 0.84 0.14 0.12 0.01583.1593 Breathitt 1.1 1.9 0.053 0.80 0.74 0.086 0.08 0.01083.3287 Breathitt 2.5 2.0 0.041 0.90 0.80 0.10 0.16 0.01083.2773 Breathitt 1.6 2.6 0.041 1.1 0.95 0.12 0.22 0.01583.2828 Breathitt 2.1 2.0 0.047 1.2 0.76 0.11 0.19 0.01583.2506 Breathitt 1.8 1.8 0.023 0.75 0.75 0.081 0.14 0.01083.1580 Breathitt 1.7 1.8 0.035 0.71 0.73 0.081 0.21 0.01583.1387 Breathitt 1.0 1.4 0.018 0.67 0.57 0.058 0.10 0.005
25

Longitude County As ppm Al % Ca % Fe % K% Mg % Na % P %

83.1480 Breathitt 2.4 2.7 0.047 1.2 0.96 0.14 0.13 0.01583.1987 Breathitt 1 1.8 0.023 0.77 0.75 0.081 0.21 0.01083.1954 Breathitt 1.2 1.8 0.029 0.99 0.66 0.098 0.12 0.01083.1616 Breathitt 1.0 1.6 0.023 0.71 0.63 0.075 0.14 0.01083.2773 Breathitt 2.4 2.1 0.46 1.5 0.74 0.13 0.14 0.01583.2750 Breathitt 4.2 2.0 0.029 1.1 0.69 0.10 0.10 0.01083.3189 Breathitt 2.3 3.2 0.059 1.4 1.1 0.18 0.39 0.01583.3076 Breathitt 3.6 3.9 0.12 1.6 1.4 0.22 0.42 0.02083.3342 Breathitt 2.8 2.4 0.11 1.2 0.89 0.12 0.18 0.01583.3596 Breathitt 1.8 2.4 0.035 1.2 0.9 0.11 0.32 0.01583.3474 Breathitt 3.2 3.3 0.047 1.6 1.1 0.17 0.41 0.02083.3449 Breathitt 1.6 2.4 0.035 0.76 1.1 0.11 0.16 0.01083.3972 Breathitt 1.7 2.4 0.035 1.2 0.82 0.13 0.27 0.01583.3843 Breathitt 2.8 3.1 0.053 1.5 0.98 0.18 0.38 0.02083.3865 Breathitt 4.0 3.0 0.26 1.6 0.94 0.17 0.26 0.01583.4088 Breathitt 2.7 2.4 0.041 1.2 0.82 0.14 0.28 0.01583.4422 Breathitt 2.6 3.4 0.076 1.7 1.1 0.21 0.37 0.02083.4629 Breathitt 2.7 2.6 0.041 1.4 0.87 0.15 0.27 0.01583.4005 Breathitt 6.8 3.2 0.059 1.9 1.0 0.19 0.18 0.02083.3819 Breathitt 5.6 4.1 0.11 2.1 1.2 0.25 0.24 0.030

83.4331 Breathitt 4.0 5.0 0.57 2.2 1.6 0.35 0.64 0.03283.4226 Breathitt 3.7 5.4 0.13 2.6 1.6 0.35 0.71 0.04983.4172 Breathitt 2.7 4.6 0.099 2.2 1.5 0.31 0.61 0.03883.4446 Breathitt 3.9 5.7 0.15 2.7 1.7 0.39 0.71 0.04983.5301 Breathitt 3.7 4.5 0.088 2.0 1.4 0.28 0.61 0.03283.5292 Breathitt 4.0 5.5 0.15 2.7 1.6 0.35 0.56 0.04383.5065 Breathitt 4.5 4.5 2.0 2.3 1.4 0.33 0.43 0.03883.4756 Breathitt 3.1 4.4 0.099 2.0 1.3 0.26 0.39 0.04383.4767 Breathitt 4.7 5.0 0.17 2.4 1.5 0.34 0.62 0.038
26

Longitude County As ppm Al % Ca % Fe % K% Mg % Na % P %

83.4782 Breathitt 4.3 5.5 0.13 2.5 1.6 0.38 0.58 0.04983.5174 Breathitt 3.1 4.6 0.11 2.2 1.4 0.28 0.60 0.03883.5372 Breathitt 3.6 4.6 0.077 2.3 1.4 0.29 0.59 0.03283.5016 Breathitt 3.5 5.2 0.11 2.4 1.5 0.36 0.71 0.04383.5532 Breathitt 5.5 4.9 0.47 2.8 1.4 0.33 0.69 0.03883.5318 Breathitt 5.8 6.0 0.099 3.1 1.7 0.45 0.71 0.04983.4558 Breathitt 6.2 6.1 0.20 2.9 1.8 0.47 0.59 0.04983.4615 Breathitt 4.4 5.1 0.13 2.3 1.5 0.34 0.68 0.03883.4778 Breathitt 3.4 4.5 0.14 2.1 1.4 0.28 0.81 0.03283.5258 Breathitt 4.2 4.9 0.088 2.4 1.4 0.34 0.72 0.03883.5414 Breathitt 5.3 4.7 0.12 2.3 1.3 0.30 0.57 0.03283.5112 Breathitt 4.3 4.8 0.088 2.6 1.4 0.32 0.67 0.04383.4048 Breathitt 2.6 4.1 0.19 1.8 1.5 0.25 0.63 0.03283.4057 Breathitt 3.5 4.9 0.22 2.0 1.5 0.30 0.68 0.03283.3788 Breathitt 4.5 6.5 0.53 3.0 1.9 0.44 0.49 0.04983.4244 Breathitt 4.5 5.1 0.76 2.4 1.6 0.40 0.68 0.03283.4758 Breathitt 4.0 5.0 2.4 2.4 1.5 0.37 0.66 0.03883.4718 Breathitt 4.5 5.1 0.17 2.4 1.5 0.35 0.62 0.03883.5207 Breathitt 4.5 5.2 0.094 2.4 1.5 0.32 0.56 0.03283.5158 Breathitt 5.1 4.3 0.077 2.3 1.3 0.29 0.53 0.03283.5407 Breathitt 5.2 4.5 0.083 2.6 1.3 0.27 0.73 0.03283.4526 Breathitt 3.9 4.3 0.072 2.1 1.2 0.27 0.61 0.03283.4410 Breathitt 4.8 5.1 0.23 2.5 1.5 0.40 0.62 0.03883.4232 Breathitt 4.5 4.5 0.13 2.0 1.3 0.29 0.63 0.03283.4673 Breathitt 2.7 2.8 0.055 1.3 0.77 0.13 0.15 0.02283.3966 Breathitt 3.2 4.4 0.083 2.0 1.3 0.27 0.70 0.03283.3908 Breathitt 4.9 5.0 0.094 2.5 1.5 0.34 0.74 0.038

83.8316 Clay 2.9 3.6 0.064 1.7 0.98 0.21 0.62 0.020
27

Longitude County As ppm Al % Ca % Fe %

K

% Mg % Na %

P %

83.7704 Clay 4.0 4.0 0.064 1.9 1.1 0.25 0.55 0.02583.7313 Clay 4.7 3.9 0.14 2.0 1.1 0.24 0.48 0.02583.7518 Clay 4.2 3.9 0.047 2.0 1.1 0.23 0.53 0.02583.7389 Clay 5.3 4.2 0.094 2.1 1.1 0.25 0.57 0.03083.7309 Clay 6.0 4.6 0.11 2.4 1.2 0.31 0.53 0.03583.7183 Clay 4.5 4.2 0.076 2.1 1.2 0.26 0.46 0.03083.6603 Clay 5.8 5.0 0.24 2.5 1.3 0.37 0.57 0.04083.5694 Clay 6.0 4.3 0.47 2.2 1.2 0.32 0.66 0.03083.6012 Clay 7.7 5.7 0.11 2.8 1.6 0.41 0.50 0.03583.5695 Clay 6.1 5.4 0.11 2.7 1.5 0.36 0.63 0.03583.6034 Clay 5.0 4.6 0.26 2.3 1.3 0.30 0.69 0.03083.5845 Clay 4.3 5.0 0.082 2.0 1.4 0.30 0.57 0.02583.5629 Clay 4.5 4.0 0.49 2.0 1.1 0.29 0.48 0.03083.5470 Clay 5.4 4.0 0.076 2.0 1.2 0.25 0.47 0.03083.5928 Clay 3.6 3.7 0.18 1.7 1.1 0.24 0.32 0.02083.5627 Clay 3.6 4.0 0.20 1.9 1.3 0.25 0.24 0.02583.5337 Clay 6.0 3.9 0.082 2.4 1.2 0.25 0.20 0.03083.6128 Clay 4.8 4.0 0.10 2.2 1.2 0.25 0.30 0.03083.7998 Clay 8.6 5.1 0.053 2.5 1.3 0.29 0.21 0.03083.8356 Clay 6.1 5.0 0.070 2.4 1.3 0.33 0.25 0.03083.8241 Clay 8.9 4.1 0.12 2.8 1.1 0.28 0.19 0.03083.8756 Clay 8.0 3.7 0.070 2.2 0.90 0.22 0.15 0.02583.9066 Clay 3.7 2.9 0.094 1.6 0.79 0.16 0.34 0.02583.9305 Clay 4.1 3.5 0.13 1.8 0.92 0.20 0.41 0.02583.9149 Clay 5.7 3.8 3.2 1.9 1.1 0.32 0.39 0.03083.8297 Clay 8.5 5.5 0.12 2.9 1.4 0.40 0.36 0.03583.6594 Clay 2.2 2.8 2.2 1.4 0.75 0.21 0.31 0.02083.6450 Clay 6.0 5.1 0.11 2.8 1.4 0.39 0.56 0.03583.6137 Clay 7.6 4.9 0.14 2.8 1.3 0.39 0.54 0.035
28

Longitude County As ppm Al % Ca % Fe %

K

% Mg % Na %

P %

83.6138 Clay 5.0 4.8 0.10 2.6 1.3 0.33 0.71 0.03583.5638 Clay 3.6 4.2 0.16 2.0 1.2 0.28 0.63 0.03083.6555 Clay 43 5.7 0.053 3.8 1.5 0.38 0.29 0.03083.7050 Clay 4.6 3.3 0.088 1.8 0.81 0.18 0.39 0.02083.7279 Clay 4.2 3.3 0.11 1.8 0.83 0.18 0.32 0.02583.7679 Clay 6.9 4.6 0.088 2.6 1.2 0.29 0.35 0.03583.7749 Clay 5.1 3.3 0.13 1.8 0.81 0.20 0.28 0.02583.8761 Clay 6.5 4.1 0.11 2.0 1.0 0.21 0.26 0.02583.8588 Clay 4.0 2.4 0.20 1.5 0.64 0.13 0.19 0.02083.8205 Clay 3.8 2.6 0.04 1.5 0.68 0.13 0.24 0.02083.7617 Clay 4.0 2.6 0.059 1.4 0.60 0.14 0.30 0.01583.6974 Clay 7.3 5.0 0.46 2.9 1.3 0.36 0.40 0.03583.6529 Clay 5.5 4.2 0.10 2.4 1.2 0.28 0.46 0.03583.7109 Clay 4.2 3.9 0.070 2.2 1.2 0.24 0.32 0.03083.6560 Clay 4.3 4.0 0.088 2.2 1.2 0.27 0.41 0.03083.9011 Estill 24 4.8 0.12 3.8 1.5 0.39 0.20 0.02583.9265 Estill 23 3.3 0.80 3.9 0.96 0.26 0.22 0.02583.9241 Estill 8.3 2.2 0.10 2.8 0.55 0.14 0.10 0.02083.9200 Estill 5.3 2.0 0.25 1.4 0.54 0.15 0.12 0.01583.9167 Estill 3.1 1.4 0.07 1.1 0.32 0.077 0.05 0.010

84.0087 Estill 28 3.7 0.25 3.7 1.3 0.31 0.23 0.030

Estill 12 4.3 0.14 2.5 1.4 0.37 0.46 0.015

84.0498 Estill 29 4.1 5.9 4.5 1.8 2.9 0.13 0.080

83.9116 Estill 22 2.8 0.84 2.7 0.93 0.26 0.19 0.02783.8390 Estill 14 3.6 1.1 2.4 1.1 0.31 0.22 0.02583.8911 Estill 7.8 2.6 0.41 1.6 0.9 0.22 0.23 0.01083.9180 Estill 11 2.3 0.58 2.7 0.69 0.19 0.16 0.02083.8506 Estill 15 2.7 0.64 2.1 0.83 0.24 0.18 0.01583.8584 Estill 9.5 2.2 0.22 1.8 0.63 0.18 0.11 0.015
29

Longitude County As ppm Al % Ca % Fe %

K

% Mg % Na %

P %

83.8066 Estill 2.3 0.80 0.54 0.70 0.19 0.061 0.04 0.010

82.9350 Floyd 2.7 3.4 0.059 1.4 0.95 0.17 0.34 0.01582.8873 Floyd 2.8 3.1 0.047 1.4 1.1 0.18 0.35 0.02082.8512 Floyd 2.8 2.5 0.059 1.5 0.92 0.13 0.37 0.01582.8717 Floyd 3.0 3.1 0.070 1.6 1.1 0.17 0.38 0.02082.8470 Floyd 2.5 3.1 2.8 1.8 1.1 0.28 0.36 0.02582.7989 Floyd 1.7 2.6 0.076 1.3 1.0 0.12 0.43 0.01582.8075 Floyd 3.2 2.9 0.053 1.4 1.1 0.14 0.41 0.02082.8015 Floyd 3.3 3.6 0.064 1.7 1.3 0.21 0.54 0.02082.8393 Floyd 1.8 2.7 0.064 1.2 1.1 0.13 0.43 0.01582.8342 Floyd 2.8 2.4 0.18 1.2 0.87 0.14 0.36 0.02082.8692 Floyd 3.2 3.1 0.14 1.7 1.1 0.18 0.50 0.02082.8906 Floyd 2.1 3.4 0.094 1.2 1.3 0.16 0.49 0.01582.9164 Floyd 4.5 4.0 0.076 2.1 1.3 0.25 0.41 0.02582.8836 Floyd 23 3.0 0.035 2.2 1.1 0.14 0.25 0.01582.8739 Floyd 3.1 2.6 0.047 1.1 1.0 0.12 0.43 0.01582.8748 Floyd 3.4 2.6 0.047 1.2 1.0 0.13 0.36 0.01582.8426 Floyd 4.6 3.2 0.10 1.5 1.1 0.18 0.41 0.02082.8862 Floyd 4.8 3.6 0.12 1.3 1.2 0.18 0.46 0.02082.8973 Floyd 1.9 2.4 0.041 0.86 1.0 0.11 0.36 0.01082.8247 Floyd 2.0 3.2 0.064 1.4 1.0 0.15 0.44 0.02082.8329 Floyd 7.5 3.9 0.064 2.3 1.2 0.25 0.39 0.04082.8143 Floyd 4.2 3.2 0.059 2.0 1.1 0.19 0.42 0.02082.8170 Floyd 5.9 3.0 0.076 2.1 0.96 0.19 0.28 0.03082.7994 Floyd 4.1 2.9 0.088 1.2 1.1 0.13 0.53 0.01082.8315 Floyd 1.7 2.2 0.059 1.1 0.88 0.099 0.34 0.01582.8503 Floyd 2.8 2.9 0.19 1.5 1.1 0.15 0.42 0.020

82.8503 Floyd 3.2 4.2 0.24 1.9 1.3 0.23 0.80 0.025

82.8024 Floyd 2.1 2.6 0.041 1.1 1.0 0.13 0.41 0.015
30

Longitude County As ppm Al % Ca % Fe %

K

% Mg % Na %

P %

82.7994 Floyd 2.7 3.1 0.064 1.3 1.1 0.17 0.27 0.01582.7623 Floyd 2.4 2.8 0.10 1.3 1.0 0.15 0.33 0.020

82.7623 Floyd 3.9 5.5 0.15 2.0 1.5 0.29 0.67 0.030

82.7222 Floyd 3.2 3.0 0.12 1.5 1.1 0.18 0.40 0.03082.7235 Floyd 1.9 2.6 0.57 1.3 1.0 0.14 0.32 0.01582.7477 Floyd 1.8 3.6 0.059 1.3 1.3 0.17 0.64 0.020

82.7477 Floyd 2.5 4.4 0.077 1.5 1.5 0.21 0.98 0.025

82.7702 Floyd 1.9 2.5 0.059 1.1 1.0 0.13 0.38 0.02082.6779 Floyd 1.6 3.0 0.064 1.1 1.3 0.13 0.41 0.01582.6430 Floyd 1.2 1.8 0.42 0.57 0.75 0.083 0.36 0.01082.6470 Floyd 1.3 2.6 0.16 0.93 1.1 0.14 0.41 0.01582.6214 Floyd 1.4 2.0 0.023 0.79 0.96 0.083 0.24 0.01082.6025 Floyd 4.2 2.5 0.047 1.2 0.93 0.14 0.24 0.01582.6307 Floyd 5.2 3.7 0.053 1.8 1.2 0.23 0.50 0.02082.6104 Floyd 3.4 3.6 0.26 1.7 1.2 0.23 0.58 0.02082.6108 Floyd 3.3 3.6 0.49 1.5 1.3 0.22 0.59 0.02082.6679 Floyd 2.7 3.2 0.070 1.5 1.1 0.17 0.64 0.02082.6360 Floyd 2.1 3.0 0.070 1.0 1.1 0.15 0.53 0.02082.6232 Floyd 2.1 2.6 0.36 1.4 0.98 0.16 0.34 0.01582.6649 Floyd 3.6 3.0 0.14 1.8 0.96 0.21 0.42 0.020

82.6649 Floyd 5.1 4.9 0.20 2.2 1.5 0.34 0.88 0.045

82.6898 Floyd 4.1 3.5 0.094 2.1 1.2 0.21 0.43 0.02582.6891 Floyd 2.2 2.8 0.15 1.4 1.0 0.14 0.38 0.01582.6494 Floyd 3.0 1.9 2.3 1.2 0.82 0.13 0.30 0.01082.7819 Floyd 2.8 2.4 0.029 3.9 0.90 0.12 0.32 0.01582.7497 Floyd 2.5 3.1 0.15 1.6 1.1 0.19 0.67 0.04082.7669 Floyd 3.0 2.7 0.059 1.3 0.95 0.12 0.13 0.015

82.7669 Floyd 3.1 3.9 0.083 1.8 1.4 0.19 0.18 0.020

82.7261 Floyd 2.1 2.7 0.035 1.1 1.1 0.12 0.38 0.010
31

Longitude County As ppm Al % Ca % Fe %

K

% Mg % Na %

P %

82.7213 Floyd 2.0 2.5 0.047 1.1 1.1 0.12 0.39 0.02082.7431 Floyd 2.0 2.3 0.041 1.2 0.87 0.11 0.29 0.01582.7156 Floyd 1.7 2.2 0.035 0.78 1.0 0.094 0.21 0.01082.6115 Floyd 3.5 3.7 0.053 1.9 1.2 0.23 0.38 0.02082.6726 Floyd 3.7 3.4 0.050 1.9 1.1 0.20 0.47 0.02582.6829 Floyd 2.8 3.6 0.43 1.7 1.3 0.25 0.54 0.02082.6805 Floyd 2.5 3.1 0.061 1.4 1.2 0.18 0.41 0.02582.7101 Floyd 2.3 2.4 0.033 1.2 0.89 0.13 0.22 0.01082.7079 Floyd 1.8 2.9 0.044 1.2 1.08 0.15 0.44 0.01582.7519 Floyd 2.5 2.4 0.12 1.5 0.86 0.15 0.37 0.01582.7255 Floyd 9.0 5.2 0.12 2.9 1.42 0.41 0.29 0.02582.6886 Floyd 5.5 4.0 0.061 2.1 1.31 0.28 0.41 0.02582.6593 Floyd 10 3.0 0.11 1.3 1 0.17 0.44 0.01582.6402 Floyd 4.5 5.1 0.083 2.6 1.57 0.37 0.64 0.03082.7575 Floyd 4.3 4.0 0.072 2.1 1.25 0.26 0.46 0.02582.7175 Floyd 4.0 3.0 1.1 1.6 1.05 0.21 0.34 0.02082.7308 Floyd 3.0 3.9 0.14 1.4 1.18 0.19 0.42 0.01582.7592 Floyd 2.6 2.1 0.033 1.1 0.81 0.12 0.25 0.01582.7186 Floyd 4.8 3.9 0.066 2.1 1.18 0.28 0.42 0.02582.7175 Floyd 2.7 2.6 0.30 1.5 0.95 0.18 0.30 0.02082.7306 Floyd 5.5 4.6 0.050 2.1 1.48 0.31 0.40 0.02082.7403 Floyd 3.3 1.7 0.066 0.96 0.66 0.094 0.15 0.01082.6937 Floyd 1.3 1.4 0.066 0.78 0.65 0.066 0.19 0.01082.6563 Floyd 1.3 1.9 0.039 0.74 0.86 0.088 0.19 0.01082.5846 Floyd 1.6 1.4 0.022 0.72 0.62 0.066 0.16 0.01082.6073 Floyd 1.5 1.9 0.061 0.80 0.86 0.094 0.20 0.01082.7649 Floyd 1.9 2.9 0.044 1.3 1.07 0.17 0.46 0.02082.8170 Floyd 1.9 2.1 0.033 1.2 0.80 0.14 0.22 0.015
32

Longitude County As ppm Al % Ca % Fe % K% Mg % Na % P %

82.7709 Floyd 9.6 5.1 0.14 3.0 1.52 0.37 0.29 0.030

83.3338 Harlan 4.0 3.0 1.2 1.6 0.86 0.26 0.21 0.02583.3610 Harlan 2.8 2.9 0.072 1.3 0.82 0.15 0.14 0.02083.3745 Harlan 5.6 5.2 0.11 2.8 1.56 0.40 0.51 0.03583.4159 Harlan 3.7 1.7 0.66 1.5 0.51 0.18 0.15 0.02083.4107 Harlan 6.2 5.6 0.14 3.4 1.67 0.44 0.41 0.04083.2918 Harlan 1.9 1.6 0.033 0.86 0.39 0.094 0.020 0.01583.2466 Harlan 2.2 2.0 0.12 0.99 0.43 0.11 0.045 0.05083.1412 Harlan 2.4 2.0 0.028 1.0 0.39 0.11 0.035 0.03083.0776 Harlan 1.2 1.2 0.022 0.60 0.35 0.077 0.020 0.01082.9201 Harlan 3.3 4.8 0.14 2.1 1.53 0.36 0.55 0.03082.9473 Harlan 5.9 4.7 0.29 2.3 1.54 0.36 0.40 0.03082.9104 Harlan 5.8 5.8 0.63 2.6 1.73 0.52 0.61 0.03083.0048 Harlan 4.7 4.0 4.0 2.0 1.27 0.40 0.29 0.02583.2482 Harlan 4.0 2.7 1.2 1.6 0.76 0.20 0.045 0.01583.3096 Harlan 2.8 2.3 0.088 1.2 0.73 0.14 0.080 0.02083.4783 Harlan 5.1 4.1 0.099 2.5 1.06 0.22 0.080 0.02583.3675 Harlan 5.0 3.8 0.094 2.0 0.99 0.20 0.055 0.02083.2012 Harlan 3.5 2.5 0.072 1.5 0.91 0.14 0.060 0.01583.2055 Harlan 3.2 3.7 0.072 1.7 1.5 0.22 0.075 0.02583.1691 Harlan 1.8 1.9 0.072 0.66 0.99 0.077 0.040 0.01083.3230 Harlan 3.7 4.3 0.57 1.9 1.3 0.29 0.51 0.02083.3534 Harlan 5.7 4.8 0.12 2.4 1.5 0.36 0.36 0.03083.3042 Harlan 9.5 5.3 0.49 2.9 1.7 0.42 0.45 0.03083.2522 Harlan 6.9 4.5 1.5 2.1 1.4 0.36 0.51 0.02583.2064 Harlan 5.4 4.1 0.18 2.4 1.3 0.33 0.49 0.03083.1886 Harlan 6.1 5.6 0.12 2.8 1.6 0.41 0.44 0.03083.2395 Harlan 6.0 5.4 0.20 2.7 1.6 0.39 0.67 0.03583.1916 Harlan 6.9 4.9 0.37 2.2 1.5 0.35 0.64 0.025
33

Longitude County As ppm Al % Ca % Fe % K% Mg % Na % P %

83.1648 Harlan 16 3.6 5.3 2.3 1.1 0.43 0.47 0.02583.0678 Harlan 6.0 5.0 0.20 2.4 1.3 0.32 0.34 0.03083.0615 Harlan 6.2 5.2 0.12 2.6 1.6 0.39 0.56 0.03083.0224 Harlan 4.4 3.8 1.0 2.0 1.2 0.30 0.30 0.03083.0086 Harlan 4.5 4.4 0.14 2.2 1.3 0.32 0.60 0.03082.9749 Harlan 4.3 3.4 0.77 1.8 1.1 0.29 0.25 0.02582.9293 Harlan 4.5 4.9 0.40 2.4 1.5 0.37 0.73 0.03083.4790 Harlan 4.0 3.9 0.061 2.1 1.1 0.27 0.35 0.03083.4459 Harlan 5.5 4.8 0.099 2.5 1.5 0.37 0.37 0.03083.4547 Harlan 14 5.9 0.099 3.5 1.7 0.43 0.32 0.04083.3945 Harlan 3.3 2.8 0.055 1.6 0.87 0.18 0.23 0.02083.3610 Harlan 6.6 3.5 0.099 2.2 1.1 0.24 0.37 0.02583.3268 Harlan 2.5 4.1 0.094 1.4 1.3 0.22 0.45 0.020

83.9647 Jackson 4.0 2.8 1.4 2.3 0.76 0.24 0.13 0.02083.9962 Jackson 2.9 1.2 0.028 0.94 0.27 0.061 0.020 0.01083.9702 Jackson 3.8 2.1 0.022 1.61 0.45 0.099 0.035 0.01583.9290 Jackson 2.8 1.0 0.017 0.93 0.21 0.044 0.020 0.01083.9605 Jackson 1.5 0.6 0.017 0.47 0.13 0.028 0.010 0.00583.9385 Jackson 2.9 1.0 0.050 0.93 0.23 0.061 0.015 0.01084.0364 Jackson 2.3 0.83 0.050 1.0 0.15 0.039 0.010 0.01084.0433 Jackson 2.6 1.1 0.028 0.97 0.18 0.039 0.015 0.010

84.0433 Jackson 3.3 1.0 0.039 1.1 0.12 0.052 0.005 0.016

84.0189 Jackson 2.5 1.0 0.044 0.96 0.20 0.044 0.015 0.01084.0227 Jackson 11 5.6 0.099 6.1 1.3 0.31 0.11 0.04584.0304 Jackson 6.9 4.7 0.099 4.9 1.1 0.26 0.12 0.06584.0542 Jackson 8.1 5.3 0.077 4.9 1.2 0.29 0.11 0.055

84.0542 Jackson 5.2 1.6 0.050 2.0 0.23 0.12 0.011 0.027

84.0715 Jackson 4.2 2.4 0.066 2.7 0.50 0.11 0.055 0.03084.1012 Jackson 1.0 0.53 0.011 0.37 0.11 0.022 0.010 0.005
34

Longitude County As ppm Al % Ca % Fe % K% Mg % Na % P %

84.0644 Jackson 1.9 0.92 0.017 0.80 0.17 0.039 0.010 0.01084.0455 Jackson 3.4 1.3 0.028 1.4 0.25 0.061 0.015 0.01584.0873 Jackson 1.4 0.78 0.011 0.50 0.16 0.028 0.010 0.005

84.0873 Jackson 2.8 0.73 0.044 0.88 0.10 0.041 0.005 0.021

84.0357 Jackson 1.6 0.68 0.017 0.51 0.13 0.022 0.010 0.00583.9927 Jackson 2.9 2.0 0.028 1.6 0.39 0.094 0.030 0.01584.1241 Jackson 1.9 1.6 0.022 1.0 0.30 0.066 0.020 0.01083.9725 Jackson 5.0 2.1 0.044 2.5 0.39 0.088 0.035 0.02084.0471 Jackson 6.6 2.8 0.050 5.7 0.52 0.11 0.040 0.040

84.0471 Jackson 2.5 1.2 0.022 0.99 0.18 0.041 0.016 0.011

83.9056 Jackson 4.9 3.7 0.57 4.3 0.82 0.21 0.070 0.03583.8734 Jackson 6.9 4.5 0.28 3.7 1.1 0.29 0.14 0.03583.9025 Jackson 9.1 5.4 0.12 4.3 1.2 0.30 0.085 0.04083.8881 Jackson 4.1 2.6 0.22 2.2 0.57 0.12 0.050 0.02084.1590 Jackson 4.1 3.6 0.20 4.3 0.71 0.20 0.040 0.03584.1416 Jackson 2.5 2.5 0.061 1.4 0.57 0.12 0.055 0.01583.8699 Jackson 3.2 2.1 0.15 1.6 0.45 0.14 0.050 0.02584.0886 Jackson 2.9 1.2 0.039 1.1 0.21 0.050 0.015 0.01084.0910 Jackson 2.3 0.91 0.022 0.73 0.17 0.039 0.015 0.01084.1115 Jackson 3.2 1.3 0.033 1.7 0.20 0.055 0.015 0.01584.1356 Jackson 4.4 2.6 0.86 3.4 0.53 0.19 0.030 0.030

84.1356 Jackson 3.1 0.86 0.31 1.1 0.14 0.11 0.005 0.016

84.1672 Jackson 4.8 1.7 0.19 3.0 0.35 0.13 0.025 0.02584.1423 Jackson 5.9 2.8 0.37 2.7 0.55 0.15 0.030 0.025

84.1583 Jackson 2.9 1.8 0.033 0.99 0.47 0.077 0.030 0.01084.1807 Jackson 4.4 2.4 0.16 1.4 0.60 0.18 0.070 0.02084.1019 Jackson 5.1 2.9 0.53 1.6 0.68 0.20 0.070 0.02084.1008 Jackson 3.5 1.8 0.22 1.0 0.42 0.16 0.053 0.016
35

Longitude County As ppm Al % Ca % Fe % K% Mg % Na % P %

83.8817 Jackson 3.1 2.0 0.039 1.2 0.51 0.093 0.063 0.01683.8262 Jackson 4.4 2.2 0.028 1.7 0.59 0.093 0.18 0.01683.8399 Jackson 3.9 2.4 0.039 1.5 0.66 0.11 0.17 0.01683.9583 Jackson 5.4 2.5 0.044 1.8 0.61 0.11 0.079 0.02183.9314 Jackson 4.8 2.5 0.077 1.7 0.53 0.10 0.053 0.02183.9820 Jackson 2.8 1.8 0.12 0.97 0.42 0.093 0.058 0.01683.9854 Jackson 6.7 2.4 0.077 2.3 0.53 0.10 0.058 0.02183.9687 Jackson 6.6 4.3 0.18 2.5 1.0 0.23 0.14 0.03283.9603 Jackson 3.8 2.9 0.050 1.7 0.74 0.15 0.17 0.02184.0331 Jackson 4.8 3.1 0.11 1.5 0.67 0.13 0.053 0.02183.9443 Jackson 4.1 3.3 0.061 1.9 0.88 0.17 0.19 0.02783.9267 Jackson 6.6 2.7 0.039 2.1 0.71 0.11 0.20 0.02183.9460 Jackson 3.5 2.0 0.039 1.2 0.48 0.088 0.068 0.01683.8961 Jackson 3.7 2.6 0.033 1.4 0.72 0.11 0.17 0.02183.8819 Jackson 2.1 0.77 0.055 0.91 0.10 0.067 0.005 0.01682.7373 Johnson 2.6 1.6 0.033 1.5 0.30 0.13 0.042 0.02182.7247 Johnson 1.8 0.6 0.028 1.1 0.08 0.10 0.005 0.01682.6974 Johnson 2.0 1.5 0.022 1.4 0.29 0.11 0.021 0.02782.7948 Johnson 4.7 1.3 0.308 1.7 0.22 0.18 0.016 0.02782.7778 Johnson 1.4 0.85 0.039 0.77 0.12 0.082 0.005 0.01682.7767 Johnson 2.5 0.88 0.050 1.1 0.11 0.13 0.005 0.02182.7127 Johnson 1.3 3.2 0.028 0.95 1.5 0.12 0.43 0.016

83.0171 Knott 4.3 2.7 0.022 1.8 0.86 0.14 0.12 0.02182.9900 Knott 2.6 2.4 0.12 1.3 0.85 0.13 0.26 0.01683.0287 Knott 3.6 3.0 0.039 1.7 0.99 0.17 0.14 0.01683.0262 Knott 1.7 3.3 0.044 1.4 1.2 0.18 0.32 0.02183.0781 Knott 2.6 2.7 0.055 1.0 0.98 0.16 0.25 0.01683.0857 Knott 2.6 2.8 0.061 1.3 1.1 0.16 0.28 0.02183.1097 Knott 1.5 1.6 0.017 0.64 0.63 0.072 0.10 0.011
36

Longitude County As ppm Al % Ca % Fe % K% Mg % Na % P %

82.9294 Knott 2.9 3.2 0.055 1.7 1.0 0.18 0.28 0.02182.9238 Knott 3.7 4.5 0.094 2.5 1.4 0.33 0.45 0.03882.8788 Knott 2.7 3.0 0.050 1.4 0.94 0.16 0.47 0.01682.8473 Knott 2.5 2.9 0.044 1.3 0.97 0.15 0.39 0.01682.8792 Knott 5.6 4.2 0.077 2.9 1.2 0.29 0.31 0.03282.9327 Knott 3.5 3.0 0.65 1.7 1.1 0.18 0.18 0.02183.0224 Knott 5.3 2.6 0.039 1.6 0.82 0.14 0.17 0.01682.9407 Knott 2.1 1.9 0.028 0.94 0.75 0.098 0.16 0.01182.9913 Knott 0.9 2.2 0.033 0.87 0.93 0.11 0.28 0.01683.0307 Knott 0.9 1.5 0.017 0.51 0.70 0.062 0.16 0.01183.0613 Knott 2.1 2.4 0.028 0.83 0.97 0.11 0.22 0.01183.0646 Knott 2.2 2.3 0.033 0.96 0.99 0.11 0.18 0.01682.9647 Knott 2.0 1.8 0.028 0.91 0.70 0.10 0.10 0.01183.0267 Knott 5.0 3.5 0.028 2.4 1.2 0.22 0.22 0.03282.9838 Knott 5.5 4.5 0.072 2.6 1.3 0.30 0.33 0.03282.9560 Knott 3.7 3.5 0.050 2.1 1.1 0.22 0.29 0.02182.9267 Knott 4.5 4.0 0.055 2.5 1.1 0.24 0.23 0.02782.9811 Knott 3.7 2.8 0.050 2.0 0.81 0.17 0.12 0.02182.9130 Knott 3.5 3.3 0.11 3.9 1.0 0.24 0.29 0.04383.0890 Knott 8.2 3.3 0.028 2.3 1.0 0.20 0.14 0.02183.0957 Knott 4.9 2.6 0.077 1.7 0.84 0.15 0.079 0.01683.0981 Knott 1.8 1.9 0.033 0.80 0.77 0.088 0.19 0.01183.0808 Knott 11 2.3 0.23 1.7 0.73 0.14 0.079 0.02183.0198 Knott 1.8 1.9 0.028 1.0 0.75 0.098 0.17 0.01682.9725 Knott 4.1 3.4 0.050 1.4 1.3 0.20 0.44 0.01682.9307 Knott 2.2 3.1 0.044 1.4 1.2 0.17 0.36 0.02182.8874 Knott 1.5 1.8 0.028 0.84 0.72 0.093 0.18 0.01182.8763 Knott 3.4 4.2 0.061 2.2 1.3 0.27 0.42 0.02782.8646 Knott 2.4 2.2 0.033 1.0 0.78 0.12 0.24 0.016
37

Longitude County As ppm Al % Ca % Fe % K% Mg % Na % P %

82.8415 Knott 2.2 2.6 0.044 1.5 0.92 0.17 0.28 0.02182.8490 Knott 3.1 2.8 0.055 1.4 0.99 0.18 0.27 0.02182.8069 Knott 3.0 2.5 0.11 1.5 0.81 0.15 0.31 0.01682.7913 Knott 1.8 2.2 0.033 1.2 0.81 0.13 0.32 0.01682.7729 Knott 2.5 3.0 0.13 1.7 1.0 0.20 0.38 0.02182.7686 Knott 2.4 2.9 0.099 1.4 1.0 0.17 0.41 0.01682.7809 Knott 3.1 3.3 0.055 1.7 1.1 0.18 0.45 0.02182.7942 Knott 2.0 2.6 0.039 1.4 0.89 0.15 0.35 0.01682.9864 Knott 2.7 2.8 0.039 1.5 0.97 0.16 0.34 0.02182.8408 Knott 2.6 3.0 0.050 1.4 1.1 0.18 0.38 0.02182.8259 Knott 2.7 2.7 0.039 1.4 0.88 0.16 0.28 0.01682.7480 Knott 1.4 <0.005 0.044 1.1 1.0 0.13 0.47 0.01683.0207 Knott 1.8 2.3 0.022 1.1 0.91 0.12 0.17 0.01183.0286 Knott 1.6 1.5 0.022 0.65 0.62 0.072 0.11 0.01183.0491 Knott 1.7 1.9 0.039 0.93 0.90 0.088 0.19 0.01183.0557 Knott 1.5 1.7 0.022 0.91 0.80 0.077 0.15 0.01183.1024 Knott 1.4 1.8 0.022 0.75 0.81 0.082 0.15 0.01182.8513 Knott 2.6 2.1 0.033 1.3 0.75 0.12 0.18 0.01682.9407 Knott 1.0 1.1 0.028 0.50 0.49 0.052 0.08 0.00582.9844 Knott 1.8 1.5 0.022 0.82 0.64 0.072 0.13 0.01182.8819 Knott 1.8 1.9 0.028 1.1 0.78 0.10 0.18 0.01182.9158 Knott 2.1 2.0 0.033 1.1 0.75 0.11 0.23 0.01682.9569 Knott 0.9 1.9 0.022 0.56 0.90 0.077 0.21 0.01183.0384 Knott 1.0 1.2 0.017 0.70 0.48 0.057 0.08 0.01183.1013 Knott 1.3 1.3 0.017 0.61 0.56 0.052 0.08 0.00583.0668 Knott 1.6 1.8 0.028 0.78 0.75 0.093 0.16 0.011

83.9974 Knox 5.3 5.2 0.14 2.4 1.4 0.29 0.18 0.04083.9446 Knox 11 6.9 0.15 4.1 1.8 0.49 0.34 0.06583.9333 Knox 4.2 4.0 0.21 2.1 1.1 0.24 0.30 0.030
38

Longitude County As ppm Al % Ca % Fe % K% Mg % Na % P %

83.8910 Knox 5.2 4.0 0.26 2.2 1.1 0.24 0.30 0.03083.8901 Knox 4.7 6.0 0.17 2.8 1.6 0.39 0.40 0.04583.8888 Knox 3.8 5.0 0.13 2.4 1.4 0.30 0.53 0.04083.8393 Knox 2.4 10 0.089 3.7 3.1 1.0 0.29 0.02583.8249 Knox 7.3 3.4 0.047 1.6 1.1 0.17 0.40 0.02583.7551 Knox 5.5 8.6 0.52 3.6 2.5 0.70 0.30 0.05583.7298 Knox 5.8 6.1 0.11 3.1 1.7 0.36 0.32 0.05083.6816 Knox 4.0 7.1 0.15 3.3 2.1 0.47 0.23 0.05083.6756 Knox 3.6 3.7 0.10 2.2 1.2 0.23 0.21 0.03083.6489 Knox 4.0 3.8 0.094 2.0 1.2 0.23 0.31 0.03083.5985 Knox 4.8 4.9 0.077 2.7 1.6 0.30 0.18 0.03583.5944 Knox 5.7 4.3 0.37 2.4 1.4 0.30 0.17 0.03083.7262 Knox 3.4 5.5 0.11 3.5 1.6 0.34 0.39 0.05083.7575 Knox 2.2 5.0 0.12 2.2 1.4 0.28 0.39 0.04083.7291 Knox 5.2 3.0 0.059 1.5 0.95 0.15 0.36 0.02083.7118 Knox 3.9 4.4 0.089 2.9 1.3 0.29 0.43 0.03083.7857 Knox 4.0 3.8 0.065 2.2 1.1 0.22 0.38 0.03083.7945 Knox 5.7 3.9 0.11 2.2 1.1 0.21 0.41 0.03083.8469 Knox 5.2 4.6 0.14 2.8 1.2 0.27 0.30 0.04583.7958 Knox 4.7 5.1 0.27 3.2 1.5 0.39 0.58 0.04583.8406 Knox 6.1 5.3 1.5 2.9 1.5 0.45 0.57 0.04583.9972 Knox 12 7.5 0.12 3.6 2.0 0.51 0.32 0.05083.9441 Knox 4.5 4.2 0.73 2.0 1.2 0.26 0.46 0.03083.9436 Knox 4.1 3.9 0.089 2.0 1.1 0.22 0.28 0.03083.9685 Knox 3.3 3.5 0.065 1.8 1.1 0.19 0.34 0.03083.9078 Knox 2.8 4.5 0.11 2.1 1.4 0.34 0.31 0.03083.9040 Knox 4.1 5.1 0.083 2.3 1.6 0.36 0.14 0.03583.8899 Knox 4.3 5.7 0.12 2.6 1.7 0.36 0.34 0.04083.8222 Knox 5.5 5.3 0.19 2.6 1.6 0.34 0.33 0.040
39

Longitude County As ppm Al % Ca % Fe % K% Mg % Na % P %

83.8180 Knox 5.1 5.0 0.11 2.7 1.5 0.35 0.28 0.035

84.1979 Laurel 2.6 1.7 0.063 0.89 0.43 0.077 0.055 0.01084.1878 Laurel 2.4 1.5 0.029 0.87 0.38 0.061 0.025 0.01084.1437 Laurel 2.2 2.2 1.2 0.98 0.56 0.18 0.040 0.01584.0834 Laurel 10 5.0 1.0 3.0 1.3 0.37 0.12 0.04084.1169 Laurel 2.5 2.2 0.040 0.93 0.54 0.094 0.10 0.01084.0514 Laurel 9.6 7.1 0.16 3.3 1.9 0.48 0.19 0.05084.0685 Laurel 5.1 3.2 0.063 1.8 0.73 0.17 0.075 0.03084.0035 Laurel 7.1 4.4 0.092 2.6 1.1 0.21 0.21 0.03583.9540 Laurel 3.6 4.2 0.052 1.7 1.2 0.20 0.34 0.03083.9570 Laurel 4.4 5.9 0.29 2.8 1.7 0.38 0.34 0.05083.9111 Laurel 4.6 3.7 1.1 1.6 0.93 0.19 0.20 0.03083.9419 Laurel 5.9 6.2 0.84 2.9 1.7 0.40 0.36 0.04583.9095 Laurel 4.7 2.9 0.069 1.4 0.81 0.14 0.16 0.02583.9478 Laurel 12 6.6 0.76 4.0 1.8 0.48 0.17 0.05084.0069 Laurel 7.7 3.5 0.11 2.5 0.89 0.17 0.19 0.03084.2269 Laurel 6.0 4.8 0.13 1.9 1.2 0.22 0.12 0.04084.2557 Laurel 11 7.4 0.27 2.7 1.9 0.36 0.090 0.03084.2069 Laurel 3.6 3.5 0.092 1.7 0.80 0.15 0.065 0.03084.1410 Laurel 5.1 3.8 1.8 1.8 0.88 0.23 0.060 0.02084.1248 Laurel 3.3 3.6 0.23 1.4 0.89 0.17 0.090 0.02084.1759 Laurel 4.5 4.6 0.14 2.4 1.2 0.29 0.10 0.03584.1691 Laurel 2.3 2.8 0.098 1.4 0.59 0.12 0.060 0.02584.1875 Laurel 3.0 3.7 0.086 1.4 0.83 0.17 0.080 0.02584.1326 Laurel 1.7 1.5 0.086 0.80 0.39 0.066 0.040 0.01084.1144 Laurel 3.8 2.3 6.2 1.5 0.59 0.23 0.070 0.02584.1687 Laurel 4.1 4.9 0.098 2.7 1.3 0.22 0.13 0.03584.2579 Laurel 5.2 4.0 0.046 1.8 1.0 0.18 0.10 0.02084.3468 Laurel 12 9.2 0.086 4.1 1.7 0.47 0.085 0.045
40

Longitude County As ppm Al % Ca % Fe % K% Mg % Na % P %

84.3265 Laurel 4.0 3.3 0.092 1.3 0.69 0.15 0.085 0.02584.2733 Laurel 3.4 3.4 1.3 1.5 0.97 0.29 0.085 0.02084.0622 Laurel 3.8 2.9 0.14 1.4 0.75 0.13 0.085 0.02584.0173 Laurel 3.8 4.8 1.4 1.8 1.2 0.26 0.26 0.03084.0031 Laurel 5.7 3.7 0.13 2.0 1.1 0.18 0.13 0.03084.0541 Laurel 10 8.1 0.12 3.3 2.0 0.51 0.16 0.04584.0237 Laurel 8.2 5.1 0.18 3.0 1.3 0.31 0.21 0.04083.9581 Laurel 5.3 5.1 0.12 2.4 1.3 0.29 0.26 0.04083.9559 Laurel 5.2 4.6 0.21 2.3 1.2 0.26 0.27 0.03583.9700 Laurel 8.0 5.3 0.20 2.6 1.3 0.31 0.31 0.04084.0094 Laurel 11 7.7 0.26 3.4 2.0 0.53 0.17 0.040

82.7516 Lawrence 4.1 6.1 0.086 2.3 1.8 0.40 0.28 0.02582.9931 Lawrence 6.6 5.1 0.086 2.1 1.6 0.28 0.48 0.03582.6096 Lawrence 2.1 3.3 0.046 1.1 1.6 0.14 0.22 0.020

83.5670 Lee 5.9 3.2 0.12 3.5 0.86 0.18 0.17 0.03883.5936 Lee 11 6.4 0.094 4.7 1.7 0.47 0.28 0.06483.5900 Lee 12 6.3 0.11 4.6 1.7 0.48 0.37 0.05983.5796 Lee 6.2 4.0 0.061 3.3 1.1 0.28 0.33 0.03883.5717 Lee 9.0 4.3 0.050 3.5 1.1 0.29 0.31 0.04383.6843 Lee 8.6 4.3 1.3 4.1 1.1 0.26 0.12 0.04383.6617 Lee 16 3.6 1.3 2.8 1.0 0.21 0.19 0.03283.6145 Lee 6.1 3.2 0.33 2.8 0.91 0.19 0.21 0.03283.6122 Lee 6.5 3.5 0.67 2.9 1.0 0.23 0.31 0.04383.5344 Lee 2.8 1.8 0.18 1.4 0.60 0.088 0.15 0.01683.5331 Lee 3.9 2.3 0.055 1.6 0.62 0.14 0.079 0.01683.5643 Lee 3.0 2.3 0.050 1.4 0.81 0.12 0.28 0.02183.5554 Lee 5.5 1.6 0.12 1.8 0.50 0.062 0.063 0.01683.6040 Lee 6.6 2.5 0.74 3.1 0.69 0.13 0.11 0.03283.7160 Lee 4.1 1.7 0.31 1.9 0.39 0.077 0.074 0.016
41

Longitude County As ppm Al % Ca % Fe % K% Mg % Na % P %

83.7127 Lee 5.8 2.5 6.5 3.1 0.60 0.19 0.074 0.03283.6936 Lee 8.4 5.0 0.13 4.7 1.3 0.31 0.18 0.05083.6777 Lee 6.5 2.9 0.061 3.0 0.83 0.19 0.20 0.03383.7460 Lee 5.7 3.1 0.099 2.9 0.79 0.19 0.14 0.03383.7743 Lee 11 4.0 0.16 3.9 0.94 0.24 0.11 0.03983.7621 Lee 8.6 4.7 0.039 3.5 0.99 0.24 0.070 0.03983.7644 Lee 13 4.9 0.088 4.5 1.2 0.34 0.12 0.04483.8440 Lee 9.2 3.7 0.061 4.0 0.85 0.19 0.070 0.03983.8027 Lee 9.4 4.5 0.34 5.4 1.0 0.26 0.085 0.05583.8107 Lee 16 5.0 0.20 4.9 1.1 0.30 0.065 0.04483.8165 Lee 8.3 4.6 0.17 5.3 1.0 0.25 0.060 0.05083.8265 Lee 11 6.2 0.072 5.3 1.3 0.33 0.075 0.05083.8964 Lee 7.5 5.5 0.165 2.6 1.4 0.29 0.11 0.03383.6803 Lee 21 5.9 0.066 5.8 1.4 0.34 0.11 0.06183.6695 Lee 1.5 0.37 0.033 0.28 0.10 0.011 0.005 0.00683.7058 Lee 9.0 3.9 0.077 3.9 0.95 0.16 0.090 0.03383.6978 Lee 3.1 2.0 0.237 1.3 0.49 0.12 0.025 0.01783.7253 Lee 2.8 0.67 0.066 0.59 0.16 0.039 0.025 0.00683.6987 Lee 2.3 0.67 0.077 0.63 0.18 0.033 0.025 0.00683.7402 Lee 1.1 0.28 1.2 0.30 0.07 0.022 0.025 0.00683.7570 Lee 0.6 0.23 0.033 0.20 0.06 0.011 0.010 0.00683.7672 Lee 0.9 0.32 0.011 0.31 0.07 0.011 0.005 0.00683.8019 Lee 1.1 0.32 0.022 0.45 0.07 0.017 0.010 0.00683.8068 Lee 3.3 0.60 0.50 0.73 0.14 0.033 0.010 0.00683.7305 Lee 17 4.8 0.050 5.1 1.1 0.26 0.085 0.05083.7551 Lee 5.7 1.9 0.055 1.9 0.40 0.088 0.040 0.02283.7777 Lee 8.8 4.3 1.7 4.1 0.89 0.25 0.055 0.03983.8072 Lee 2.6 0.56 0.028 0.44 0.13 0.022 0.010 0.00683.7134 Lee 5.7 3.2 0.26 2.1 0.79 0.17 0.10 0.028
42

Longitude County As ppm Al % Ca % Fe % K% Mg % Na % P %

83.7344 Lee 4.9 4.9 0.28 3.1 1.6 0.38 0.28 0.04483.6495 Lee 2.1 0.58 0.18 0.61 0.15 0.028 0.010 0.00683.6386 Lee 9.0 2.6 0.072 3.2 0.72 0.14 0.11 0.03383.7732 Lee 2.3 0.71 0.022 0.59 0.18 0.033 0.015 0.00683.5991 Lee 7.0 3.6 0.061 3.1 1.1 0.24 0.32 0.03383.6331 Lee 15 3.3 0.072 4.9 0.85 0.15 0.10 0.03983.6806 Lee 1.6 0.80 0.072 0.62 0.23 0.050 0.15 0.00683.8183 Lee 4.9 2.2 0.13 2.5 0.49 0.13 0.045 0.02883.8600 Lee 15 7.0 1.3 3.9 1.6 0.36 0.11 0.055

83.3945 Leslie 5.8 3.7 0.29 2.3 1.1 0.24 0.080 0.02883.3632 Leslie 3.0 3.2 0.23 1.6 1.2 0.20 0.37 0.02883.3715 Leslie 3.8 4.0 0.061 1.5 1.3 0.18 0.40 0.02283.3646 Leslie 5.1 5.1 0.099 2.5 1.5 0.38 0.44 0.02883.4343 Leslie 4.3 3.7 0.11 1.7 1.4 0.23 0.40 0.03383.5071 Leslie 5.3 5.3 0.11 2.8 1.6 0.38 0.47 0.03383.4767 Leslie 3.6 3.9 0.21 2.0 1.3 0.23 0.38 0.02883.4614 Leslie 3.6 3.8 0.25 1.7 1.3 0.23 0.24 0.02283.4336 Leslie 3.0 3.4 0.044 1.7 1.1 0.18 0.39 0.02283.3821 Leslie 5.7 4.6 0.52 2.4 1.5 0.35 0.57 0.03983.4163 Leslie 6.1 4.2 0.12 2.3 1.4 0.28 0.18 0.03983.4454 Leslie 3.8 4.0 0.088 2.0 1.3 0.27 0.38 0.02883.4538 Leslie 5.5 4.4 0.30 2.8 1.3 0.30 0.15 0.03383.4465 Leslie 3.4 3.6 0.050 1.8 0.98 0.16 0.055 0.02283.4736 Leslie 3.1 3.1 0.17 1.6 0.96 0.16 0.040 0.02283.5065 Leslie 4.7 3.5 0.099 2.1 1.0 0.20 0.045 0.02883.5056 Leslie 2.8 2.2 0.033 1.3 0.81 0.11 0.29 0.01783.5118 Leslie 3.0 3.0 0.066 1.5 1.0 0.18 0.30 0.02283.5389 Leslie 3.7 3.4 0.066 1.8 1.1 0.20 0.43 0.03383.4145 Leslie 3.4 3.3 0.15 1.6 1.3 0.20 0.27 0.022
43

Longitude County As ppm Al % Ca % Fe % K% Mg % Na % P %

83.3914 Leslie 3.2 3.0 1.4 1.7 1.1 0.22 0.28 0.02283.3694 Leslie 3.1 3.6 0.061 1.7 1.3 0.24 0.28 0.02883.3555 Leslie 3.0 2.5 0.039 1.5 1.0 0.14 0.18 0.02283.3279 Leslie 4.7 3.5 0.094 1.9 1.2 0.24 0.32 0.03383.2711 Leslie 4.4 3.7 0.088 1.9 1.3 0.24 0.10 0.02883.4269 Leslie 5.7 3.9 0.25 2.1 1.2 0.28 0.45 0.03383.3002 Leslie 3.8 3.2 0.30 1.8 1.1 0.21 0.27 0.02283.2991 Leslie 4.4 ins ins ins ins ins ins ins83.2966 Leslie 3.8 3.3 0.088 1.8 1.2 0.17 0.055 0.02283.2514 Leslie 4.0 3.1 0.099 1.7 1.3 0.21 0.050 0.03383.2052 Leslie 2.3 2.6 0.094 1.2 1.1 0.15 0.060 0.01783.2202 Leslie 2.5 2.9 0.072 1.6 1.1 0.17 0.21 0.02283.2682 Leslie 8.0 4.0 0.11 2.7 1.3 0.29 0.26 0.03383.2522 Leslie 11 2.0 0.039 1.9 0.57 0.077 0.070 0.01783.2671 Leslie 5.2 4.5 0.13 2.2 1.5 0.30 0.36 0.03383.3226 Leslie 3.4 3.9 0.11 1.8 1.4 0.22 0.54 0.02883.4063 Leslie 2.9 3.3 0.13 1.7 1.1 0.19 0.54 0.033

82.8985 Letcher 4.5 5.1 0.59 2.4 1.6 0.37 0.54 0.03382.8767 Letcher 3.5 4.5 0.099 2.2 1.4 0.32 0.60 0.03382.8425 Letcher 4.3 4.6 0.17 2.1 1.5 0.33 0.49 0.02882.8004 Letcher 5.3 5.4 0.23 2.7 1.6 0.40 0.41 0.03982.7640 Letcher 6.1 6.1 0.14 3.3 1.8 0.42 0.66 0.04582.7450 Letcher 4.5 5.5 0.36 2.2 1.7 0.40 0.67 0.03082.7554 Letcher 9.0 5.8 0.51 2.6 1.8 0.42 0.70 0.04082.7448 Letcher 4.6 5.6 0.17 2.8 1.7 0.40 0.96 0.04082.7912 Letcher 5.4 5.8 0.55 2.4 1.8 0.45 0.69 0.03582.7743 Letcher 2.9 4.2 0.20 1.7 1.4 0.24 0.80 0.02582.7387 Letcher 3.9 6.6 0.13 2.6 1.9 0.47 0.62 0.04082.6859 Letcher 5.4 5.6 0.32 2.5 1.6 0.38 0.73 0.045
44

Longitude County As ppm Al % Ca % Fe % K% Mg % Na % P %

82.6213 Letcher 5.1 4.9 0.20 1.9 1.5 0.32 0.75 0.03082.6276 Letcher 4.5 5.4 0.34 2.2 1.7 0.37 0.92 0.03582.6811 Letcher 4.2 5.3 0.20 2.2 1.5 0.35 0.61 0.03582.7953 Letcher 7.3 7.4 0.32 2.7 2.1 0.52 0.53 0.03082.8035 Letcher 5.4 6.1 0.26 2.6 1.8 0.46 0.67 0.04082.8540 Letcher 6.0 5.4 0.14 2.4 1.6 0.37 0.81 0.03582.8902 Letcher 5.5 7.1 0.21 3.1 2.0 0.55 0.71 0.04082.8605 Letcher 4.9 5.3 0.77 2.2 1.6 0.39 0.81 0.03082.8549 Letcher 5.9 5.3 0.17 2.4 1.6 0.34 0.67 0.03082.8297 Letcher 3.9 4.3 6.7 1.6 1.3 0.48 0.50 0.02582.8825 Letcher 5.8 6.2 0.20 2.6 1.9 0.47 0.82 0.03082.9246 Letcher 5.1 7.4 0.88 2.8 2.2 0.57 0.53 0.04082.9809 Letcher 4.8 5.5 0.42 2.5 1.6 0.42 0.41 0.03083.0218 Letcher 2.7 3.1 0.43 1.5 1.0 0.20 0.29 0.02583.0090 Letcher 4.5 5.2 0.31 2.3 1.5 0.37 0.53 0.03082.9480 Letcher 12 6.2 0.13 2.4 1.8 0.42 0.58 0.03582.9631 Letcher 4.6 5.2 0.12 2.5 1.5 0.37 0.70 0.03582.9235 Letcher 4.1 4.7 0.12 2.1 1.4 0.30 0.72 0.02583.0311 Letcher 3.9 3.8 0.45 1.7 1.5 0.23 0.085 0.02083.0756 Letcher 6.0 5.4 0.25 2.3 1.7 0.38 0.18 0.03083.1204 Letcher 3.1 3.4 0.081 1.5 1.3 0.17 0.065 0.02083.0117 Letcher 3.6 4.5 0.48 2.1 1.4 0.33 0.36 0.02582.9017 Letcher 6.6 5.7 0.12 2.6 1.6 0.40 0.53 0.04082.8767 Letcher 4.8 5.1 0.18 2.4 1.6 0.33 0.98 0.03082.8373 Letcher 4.8 5.5 0.13 2.4 1.6 0.36 0.71 0.03583.0238 Letcher 5.5 4.4 0.21 2.4 1.4 0.29 0.47 0.03082.9528 Letcher 6.3 6.5 0.61 3.2 1.9 0.47 0.78 0.05082.7864 Letcher 3.0 3.4 0.069 1.8 1.0 0.20 0.34 0.02582.7289 Letcher 1.9 2.5 0.37 1.1 0.73 0.17 0.17 0.020
45

Longitude County As ppm Al % Ca % Fe %

K

% Mg % Na %

P %

83.0778 Magoffin 3.0 3.5 0.083 1.6 1.1 0.20 0.61 0.03083.0883 Magoffin 3.1 4.0 0.050 1.7 1.2 0.22 0.49 0.02583.1192 Magoffin 5.0 4.8 0.088 2.7 1.4 0.29 0.65 0.03583.1354 Magoffin 3.0 3.8 0.077 1.8 1.3 0.20 0.69 0.03083.1657 Magoffin 3.6 4.2 0.083 1.9 1.3 0.25 0.46 0.02583.1486 Magoffin 5.5 5.4 0.20 2.8 1.6 0.40 0.50 0.04083.1198 Magoffin 2.4 3.6 0.066 1.5 1.3 0.19 0.68 0.02583.0317 Magoffin 2.4 4.0 0.072 1.5 1.4 0.21 0.84 0.02582.9759 Magoffin 3.4 4.3 0.23 2.0 1.3 0.25 0.64 0.03083.0122 Magoffin 3.2 3.9 0.12 1.7 1.3 0.21 0.69 0.02583.0139 Magoffin ins 3.4 0.088 1.4 1.2 0.17 0.68 0.02583.0569 Magoffin 3.8 4.4 0.077 1.8 1.5 0.25 0.65 0.03083.0901 Magoffin 6.3 5.9 0.12 2.8 1.7 0.42 0.51 0.04083.0860 Magoffin 2.4 4.0 0.061 1.7 1.5 0.22 0.61 0.03083.0298 Magoffin ins 2.9 0.050 1.2 1.1 0.14 0.40 0.02583.2389 Magoffin 1.1 1.6 0.028 0.70 0.64 0.083 0.22 0.01083.1870 Magoffin 6.3 5.5 0.083 3.4 1.6 0.35 0.35 0.04083.1897 Magoffin 3.6 4.7 0.072 2.1 1.4 0.27 0.60 0.03083.1613 Magoffin 1.9 2.0 1.1 1.0 0.70 0.13 0.21 0.01583.1227 Magoffin 4.6 6.2 0.17 2.6 1.8 0.45 0.29 0.04083.1241 Magoffin ins 4.0 0.083 1.9 1.4 0.22 0.52 0.04583.0344 Magoffin 3.9 4.6 0.083 2.3 1.4 0.29 0.73 0.03583.0079 Magoffin 6.8 6.2 0.17 3.1 1.9 0.47 0.67 0.04582.9597 Magoffin 3.8 4.3 0.083 2.1 1.4 0.28 0.60 0.03082.9619 Magoffin 2.5 4.0 0.094 1.7 1.4 0.23 0.65 0.03082.9850 Magoffin 4.2 4.7 0.10 2.4 1.5 0.33 0.51 0.03083.0113 Magoffin 6.9 5.8 0.12 3.4 1.7 0.43 0.61 0.04082.9663 Magoffin 5.9 9.2 0.20 2.5 2.5 0.59 0.25 0.03083.0004 Magoffin 5.0 6.1 0.13 3.0 1.9 0.47 0.53 0.045
46

Longitude County As ppm Al % Ca % Fe %

K

% Mg % Na %

P %

82.9316 Magoffin 3.5 2.7 0.059 1.1 0.91 0.17 0.33 0.02082.9407 Magoffin 5.2 4.8 0.15 3.1 1.5 0.33 0.78 0.05582.9280 Magoffin 6.0 5.8 0.14 3.0 1.9 0.50 0.72 0.05582.9174 Magoffin 3.3 4.0 0.065 1.9 1.5 0.20 0.44 0.02582.9283 Magoffin 2.8 4.6 0.077 1.9 1.6 0.23 0.43 0.02582.9968 Magoffin 3.5 1.9 0.065 0.86 0.70 0.11 0.21 0.02082.9679 Magoffin ins 2.6 0.053 1.3 0.88 0.17 0.25 0.02082.9859 Magoffin 4.6 2.2 0.047 1.1 0.77 0.13 0.26 0.02083.2369 Magoffin 3.3 3.8 0.077 1.7 1.3 0.22 0.49 0.03083.2009 Magoffin 2.6 4.2 0.077 1.7 1.5 0.22 0.73 0.03083.1653 Magoffin 5.2 5.9 0.15 3.1 1.8 0.46 0.68 0.04583.1786 Magoffin 4.5 4.3 0.094 1.9 1.4 0.31 0.65 0.03583.2022 Magoffin 4.2 5.4 0.12 2.5 1.6 0.36 0.42 0.04583.2265 Magoffin 4.1 5.4 0.083 2.2 1.7 0.35 0.28 0.03083.1497 Magoffin 3.0 4.5 0.11 1.6 1.6 0.25 0.40 0.03083.1484 Magoffin 3.1 5.4 0.11 2.0 1.8 0.31 0.77 0.03083.1174 Magoffin 5.4 5.7 0.13 3.0 1.7 0.39 0.64 0.04583.0798 Magoffin 2.6 3.5 0.14 1.2 1.3 0.17 0.57 0.03583.0791 Magoffin 2.7 4.2 0.094 1.6 1.4 0.23 0.65 0.03583.0422 Magoffin 4.0 4.5 0.23 2.3 1.4 0.31 0.56 0.03583.0609 Magoffin 3.1 4.2 0.15 1.9 1.4 0.23 0.30 0.03583.0629 Magoffin 2.4 2.8 1.3 1.4 1.1 0.15 0.18 0.02083.0455 Magoffin 3.9 4.8 0.22 2.0 1.5 0.33 0.51 0.04083.0328 Magoffin 5.7 5.1 0.14 2.1 1.6 0.30 0.63 0.04083.0360 Magoffin 2.2 3.5 0.11 1.3 1.5 0.18 0.24 0.04082.9712 Magoffin 4.7 4.9 0.64 2.4 1.5 0.31 0.58 0.03582.9467 Magoffin 5.0 5.2 0.10 2.3 1.7 0.35 0.55 0.04082.9599 Magoffin 3.7 4.2 0.053 2.4 1.4 0.22 0.50 0.03082.9975 Magoffin 3.6 4.6 0.16 2.1 1.5 0.30 0.56 0.045
47

Longitude County As ppm Al % Ca % Fe % K% Mg % Na % P %

82.9692 Magoffin 4.4 3.2 0.047 1.7 1.1 0.19 0.20 0.020

82.9692 Magoffin 5.8 5.9 0.094 2.7 1.8 0.41 0.39 0.035

82.9572 Magoffin 2.6 2.3 0.030 1.2 0.90 0.11 0.20 0.015

82.9572 Magoffin 3.4 4.2 0.059 1.8 1.5 0.20 0.43 0.025

82.9910 Magoffin 2.6 2.8 0.041 1.3 0.98 0.14 0.12 0.015

82.9910 Magoffin 3.3 4.8 0.071 1.8 1.5 0.26 0.23 0.025

83.0816 Magoffin 2.6 2.2 0.21 1.1 0.86 0.12 0.21 0.015

83.0816 Magoffin 4.0 4.5 0.27 1.9 1.5 0.29 0.64 0.030

83.1230 Magoffin 1.9 3.0 0.041 1.4 1.1 0.16 0.35 0.015

83.1230 Magoffin 3.0 4.1 0.053 1.6 1.4 0.22 0.61 0.020

83.1664 Magoffin 1.9 2.3 0.035 0.91 0.93 0.12 0.23 0.015

83.1664 Magoffin 3.5 4.4 0.089 1.7 1.5 0.25 0.56 0.035

83.2233 Magoffin 2.7 2.4 0.047 1.6 0.86 0.12 0.27 0.020

83.2233 Magoffin 4.5 4.3 0.094 2.6 1.4 0.25 0.56 0.035

82.5636 Martin 0.8 1.3 0.012 0.48 0.67 0.050 0.10 0.00582.5678 Martin 0.7 1.0 0.012 0.28 0.54 0.028 0.035 0.00582.5320 Martin 1.1 1.2 0.012 0.56 0.59 0.055 0.075 0.00582.5598 Martin 1.4 1.4 0.023 0.62 0.66 0.066 0.080 0.01082.5225 Martin 0.9 1.3 0.017 0.44 0.62 0.050 0.055 0.00582.5046 Martin 2.5 3.2 0.063 1.6 1.1 0.21 0.13 0.02282.4837 Martin 1.4 1.6 0.017 0.62 0.72 0.072 0.12 0.01082.4941 Martin 0.6 1.4 0.017 0.47 0.74 0.055 0.14 0.00582.5488 Martin 1.8 1.2 0.028 0.51 0.63 0.055 0.11 0.00582.5643 Martin 1.4 1.5 0.017 0.57 0.72 0.061 0.14 0.00582.5864 Martin 2.3 1.5 0.017 0.72 0.71 0.066 0.063 0.00582.6000 Martin 2.3 1.8 0.028 0.71 0.79 0.077 0.11 0.01082.6372 Martin 2.7 1.2 0.011 0.53 0.63 0.055 0.058 0.01082.6572 Martin <0.6 1.0 0.011 0.48 0.44 0.044 0.058 0.00582.5994 Martin 2.1 1.6 0.022 0.53 0.87 0.066 0.18 0.010
48

Longitude County As ppm Al % Ca % Fe % K% Mg % Na % P %

82.5994 Martin 2.4 4.4 0.066 1.6 1.7 0.24 0.66 0.030

82.6076 Martin 2.5 1.3 0.022 0.43 0.67 0.050 0.11 0.00582.6303 Martin 4.0 1.6 0.017 0.66 0.76 0.066 0.047 0.00582.5362 Martin 2.8 1.5 0.017 0.48 0.83 0.055 0.14 0.005

82.5362 Martin 1.8 3.9 0.050 1.1 1.7 0.15 0.66 0.020

82.5740 Martin 2.9 1.2 0.011 0.51 0.59 0.050 0.074 0.00582.5777 Martin 3.6 1.7 0.017 0.74 0.76 0.072 0.13 0.01082.6162 Martin 2.6 1.3 0.017 0.43 0.64 0.050 0.10 0.00582.6349 Martin 2.7 1.1 0.011 0.42 0.50 0.044 0.058 0.00582.6005 Martin 2.8 1.3 0.017 0.54 0.66 0.055 0.074 0.00582.6082 Martin 2.1 1.4 0.31 0.69 0.71 0.088 0.074 0.01082.4980 Martin 3.6 1.5 0.15 0.59 0.69 0.077 0.14 0.01082.5115 Martin 3.2 1.5 0.017 0.51 0.75 0.055 0.19 0.01082.5280 Martin 1.9 1.4 0.017 0.49 0.66 0.061 0.12 0.00582.5100 Martin 0.9 1.4 0.022 0.40 0.78 0.061 0.15 0.00582.5302 Martin 1.2 1.3 0.017 0.55 0.64 0.055 0.074 0.00582.4530 Martin 1.9 1.9 0.028 0.91 0.80 0.12 0.13 0.01082.4624 Martin 1.4 2.1 0.022 0.75 0.97 0.088 0.24 0.010

82.4624 Martin 2.7 4.1 0.061 1.5 1.5 0.20 0.59 0.020

82.4726 Martin 1.8 1.7 0.033 0.71 0.72 0.083 0.21 0.01082.4651 Martin 1.5 1.8 0.017 0.57 0.90 0.077 0.17 0.00582.4483 Martin 1.9 1.4 0.017 0.66 0.64 0.066 0.14 0.01082.4284 Martin 1.5 1.7 0.017 0.76 0.79 0.077 0.18 0.01082.4174 Martin 2.4 3.9 0.072 1.7 1.4 0.24 0.31 0.02582.3677 Martin 1.3 1.6 0.022 0.60 0.75 0.072 0.10 0.01082.3353 Martin 4.0 2.8 0.044 1.5 1.0 0.17 0.16 0.01582.4130 Martin 1.9 2.5 0.050 1.1 0.98 0.14 0.14 0.01082.4020 Martin 0.9 1.7 0.022 0.62 0.80 0.072 0.15 0.01082.3860 Martin 1.1 1.6 0.017 0.49 0.73 0.072 0.084 0.010
49

Longitude County As ppm Al % Ca % Fe % K% Mg % Na % P %

82.3854 Martin 1.4 1.7 0.022 0.68 0.75 0.077 0.10 0.01082.4159 Martin 1.2 1.3 0.017 0.54 0.64 0.055 0.13 0.00582.4421 Martin 1.1 1.6 0.011 0.50 0.74 0.061 0.074 0.005

82.4421 Martin 1.6 3.3 0.039 0.98 1.4 0.14 0.32 0.015

82.4430 Martin 1.2 2.5 0.039 0.78 1.1 0.13 0.35 0.01582.4271 Martin 1.3 2.1 0.033 0.79 0.94 0.11 0.24 0.01082.4391 Martin 2.0 1.3 0.028 0.52 0.63 0.055 0.10 0.01082.4868 Martin 1.0 1.8 0.022 0.63 0.87 0.072 0.15 0.010

82.4868 Martin 2.2 4.4 0.061 1.4 1.8 0.20 0.59 0.025

82.4466 Martin 1.2 1.9 0.022 0.70 0.83 0.083 0.16 0.01082.4764 Martin 1.1 2.0 0.022 0.71 0.84 0.094 0.22 0.01082.5040 Martin 1.6 2.1 0.028 0.72 0.95 0.11 0.16 0.01082.5192 Martin 1.3 1.7 0.017 0.69 0.76 0.072 0.10 0.01082.5037 Martin 1.4 2.3 0.033 0.92 1.0 0.12 0.22 0.01582.4843 Martin 0.9 1.7 0.017 0.82 0.77 0.066 0.11 0.01082.5453 Martin 0.7 1.8 0.022 0.49 0.91 0.072 0.13 0.01082.5490 Martin 1.1 2.1 0.022 0.79 0.91 0.088 0.18 0.01082.5707 Martin 1.1 1.6 0.022 0.58 0.81 0.072 0.18 0.01082.5660 Martin 0.9 1.3 0.017 0.39 0.71 0.055 0.12 0.00582.5705 Martin 1.1 2.1 0.024 0.74 1.0 0.091 0.19 0.01182.5844 Martin 0.8 1.2 0.022 0.47 0.64 0.055 0.063 0.005

83.5359 Menifee 4.3 1.8 0.046 1.4 0.53 0.094 0.075 0.01583.6099 Menifee 7.5 3.9 0.098 2.0 1.0 0.24 0.065 0.02583.6293 Menifee 7.2 3.4 0.13 2.1 1.1 0.28 0.37 0.02083.6708 Menifee 18 6.2 0.12 2.8 2.1 0.59 0.41 0.02083.6547 Menifee 9.2 3.3 0.17 2.3 0.97 0.28 0.29 0.01583.7139 Menifee 9.4 3.6 0.22 2.2 1.0 0.29 0.21 0.02083.7204 Menifee 19 4.9 0.075 3.0 1.6 0.42 0.40 0.02083.7665 Menifee 37 5.7 0.075 5.0 1.8 0.46 0.41 0.040
50

Longitude County As ppm Al % Ca % Fe %

K

% Mg % Na %

P %

83.7561 Menifee 10 3.0 0.098 1.8 0.89 0.24 0.25 0.01583.6730 Menifee 8.2 2.7 2.0 2.0 0.76 0.24 0.17 0.02083.7113 Menifee 12 3.6 0.12 2.4 1.2 0.33 0.34 0.020

83.8000 Morgan 3.6 2.9 0.041 1.4 0.97 0.12 0.44 0.020

83.4305 Morgan 1.6 0.97 0.018 0.75 0.25 0.044 0.035 0.01083.3911 Morgan 5.8 3.1 0.50 2.4 0.85 0.18 0.29 0.03083.3583 Morgan 6.0 3.1 0.041 2.3 0.83 0.17 0.26 0.025

83.3583 Morgan 6.4 3.8 0.053 2.1 1.1 0.20 0.45 0.025

83.4566 Morgan 2.4 1.7 0.030 1.2 0.48 0.072 0.10 0.02083.3946 Morgan 4.5 2.5 0.035 1.7 0.78 0.14 0.27 0.020

83.3946 Morgan 5.1 3.8 0.053 2.0 1.1 0.20 0.59 0.025

83.3997 Morgan 3.9 2.4 0.035 1.5 0.78 0.13 0.25 0.015

83.3997 Morgan 4.4 3.8 0.059 1.9 1.1 0.21 0.59 0.025

83.3440 Morgan 4.0 2.8 0.041 1.9 0.76 0.16 0.27 0.02583.2886 Morgan 3.0 2.5 0.030 1.4 0.68 0.12 0.16 0.01583.2846 Morgan 1.0 1.4 0.018 0.55 0.67 0.061 0.15 0.01083.2266 Morgan 2.4 2.4 0.041 1.0 0.81 0.13 0.41 0.01583.2463 Morgan 4.0 3.1 0.053 1.6 0.99 0.18 0.13 0.02083.2736 Morgan 7.2 6.0 0.12 3.1 1.7 0.43 0.21 0.040

83.2736 Morgan 5.7 6.6 0.12 2.8 1.8 0.46 0.26 0.040

83.3055 Morgan 8.2 4.1 0.065 3.4 1.1 0.27 0.27 0.04083.2935 Morgan 4.3 2.8 0.053 1.8 0.84 0.17 0.14 0.02083.3521 Morgan 4.1 2.6 0.041 1.5 0.80 0.15 0.22 0.020

83.6538 Owsley 16 5.2 0.47 4.4 1.4 0.39 0.34 0.05083.6418 Owsley 4.2 3.0 4.7 1.9 0.94 0.21 0.28 0.02083.6533 Owsley 11 5.1 1.4 3.3 1.5 0.39 0.32 0.04083.6092 Owsley 6.9 3.1 0.065 2.0 0.92 0.21 0.28 0.02583.6163 Owsley 4.5 3.8 0.089 2.8 1.1 0.25 0.33 0.03583.5555 Owsley 2.1 2.3 0.047 1.1 0.87 0.11 0.18 0.015
51

Longitude County As ppm Al % Ca % Fe %

K

% Mg % Na %

P %

83.6043 Owsley 13.8 5.4 0.083 3.4 1.6 0.44 0.36 0.04083.5628 Owsley 3.7 2.2 0.64 1.4 0.72 0.12 0.32 0.02083.5897 Owsley 4.6 2.8 0.047 2.0 0.80 0.17 0.32 0.02583.5555 Owsley 2.9 2.7 0.10 1.4 0.90 0.14 0.30 0.02083.6420 Owsley 4.8 3.0 0.053 2.3 0.86 0.20 0.31 0.03083.6407 Owsley 6.9 3.4 0.065 2.5 0.93 0.24 0.32 0.03083.7343 Owsley 5.9 2.5 0.16 1.9 0.64 0.14 0.17 0.020

83.7343 Owsley 4.4 3.1 0.12 1.7 0.85 0.17 0.30 0.025

83.7172 Owsley 12 3.9 0.077 4.3 0.97 0.23 0.20 0.04083.7246 Owsley 13 5.0 0.077 3.7 1.3 0.34 0.29 0.04583.7608 Owsley 11 4.3 0.32 3.8 1.1 0.30 0.17 0.04583.7898 Owsley 6.6 2.3 0.041 2.1 0.58 0.13 0.18 0.02083.7672 Owsley 11 3.1 0.10 3.4 0.80 0.17 0.13 0.035

83.7672 Owsley 4.8 2.9 0.078 1.9 0.80 0.15 0.19 0.020

83.6345 Owsley 6.4 3.7 0.11 2.0 1.1 0.25 0.23 0.03083.6276 Owsley 2.1 1.8 0.035 1.2 0.54 0.11 0.21 0.01583.6121 Owsley 2.7 2.6 0.077 1.4 0.81 0.15 0.36 0.02083.5907 Owsley 2.8 2.3 0.11 1.4 0.67 0.14 0.23 0.01583.5765 Owsley 7.6 3.7 0.053 2.1 1.1 0.23 0.26 0.02083.6089 Owsley 11 3.9 0.68 4.6 1.0 0.29 0.28 0.04583.5708 Owsley 4.9 2.9 0.047 1.6 0.85 0.19 0.24 0.02083.5723 Owsley 2.4 2.2 0.030 1.3 0.68 0.12 0.20 0.015

83.5723 Owsley 3.8 3.6 0.050 1.8 1.1 0.22 0.40 0.025

83.6655 Owsley 6.8 3.7 0.70 2.6 0.94 0.22 0.15 0.03083.7144 Owsley 5.5 3.2 6.6 2.9 0.84 0.24 0.24 0.03583.6948 Owsley 2.7 1.5 0.76 1.2 0.45 0.094 0.13 0.01083.7294 Owsley 9.5 5.3 0.11 3.7 1.4 0.41 0.28 0.04583.7723 Owsley 12 5.1 0.089 4.1 1.3 0.37 0.23 0.04983.7973 Owsley 14 7.0 0.11 4.0 1.8 0.52 0.17 0.050
52

Longitude County As ppm Al % Ca % Fe %

K

% Mg % Na %

P %

83.7973 Owsley 7.0 3.0 0.050 1.4 0.81 0.22 0.10 0.020

83.8005 Owsley 12 3.7 5.9 5.9 0.85 0.25 0.11 0.05583.8291 Owsley 8.9 6.3 0.095 3.4 1.6 0.35 0.18 0.04583.7927 Owsley 7.9 4.6 0.062 3.6 1.2 0.28 0.20 0.03583.7394 Owsley 11 3.2 1.1 5.2 0.80 0.23 0.16 0.04583.7656 Owsley 8.4 4.0 0.35 3.4 1.1 0.27 0.26 0.04583.6853 Owsley 13 5.0 0.078 7.0 1.2 0.32 0.19 0.07083.6928 Owsley 13 6.1 0.71 5.3 1.6 0.45 0.22 0.05583.6844 Owsley 15 7.4 0.13 5.0 2.0 0.60 0.35 0.06083.6959 Owsley 6.2 4.0 0.095 2.7 1.1 0.28 0.31 0.05083.7179 Owsley 5.3 2.7 0.034 2.2 0.77 0.15 0.16 0.02083.7692 Owsley 9.9 5.7 0.22 4.1 1.5 0.39 0.24 0.05083.5284 Owsley 1.7 1.3 0.022 0.74 0.48 0.055 0.05 0.010

83.5284 Owsley 2.6 2.9 0.062 1.4 1.1 0.14 0.20 0.020

83.5572 Owsley 1.9 2.1 0.050 1.5 0.61 0.12 0.21 0.01583.8591 Owsley 8.1 1.8 0.40 2.9 0.34 0.083 0.020 0.020

83.4840 Perry 7.4 3.8 0.078 2.7 1.1 0.27 0.17 0.03083.5311 Perry 2.2 1.5 0.022 1.2 0.42 0.077 0.055 0.01583.5360 Perry 4.4 1.5 0.017 0.94 0.51 0.072 0.050 0.01083.4975 Perry 3.5 3.1 0.12 2.3 0.92 0.28 0.27 0.03083.4434 Perry 7.8 4.7 1.6 3.0 1.4 0.35 0.30 0.03583.4620 Perry 5.2 5.2 0.11 2.6 1.5 0.37 0.26 0.03083.5055 Perry 1.2 0.84 0.017 0.50 0.29 0.039 0.035 0.00583.4913 Perry 1.1 0.87 0.017 0.42 0.35 0.033 0.035 0.00583.4418 Perry 2.4 2.5 0.062 1.3 0.76 0.15 0.15 0.02083.4220 Perry 3.1 2.3 0.045 1.4 0.77 0.14 0.19 0.01583.3456 Perry 3.2 2.4 0.045 1.9 0.74 0.15 0.11 0.02083.3401 Perry 2.5 1.7 0.022 1.1 0.61 0.083 0.10 0.01083.3918 Perry 1.5 1.2 0.022 0.57 0.51 0.050 0.08 0.005
53

Longitude County As ppm Al % Ca % Fe %

K

% Mg % Na %

P %

83.3681 Perry 2.9 2.3 0.028 1.5 0.80 0.14 0.16 0.01583.3439 Perry 2.1 1.9 0.034 1.1 0.62 0.11 0.10 0.01583.3214 Perry 4.2 2.2 1.2 1.6 0.72 0.14 0.10 0.02083.2974 Perry 1.8 1.6 0.022 0.78 0.64 0.083 0.10 0.01083.2761 Perry 4.9 2.4 0.056 1.6 0.81 0.18 0.13 0.02083.3150 Perry 2.4 1.9 0.045 1.1 0.77 0.11 0.17 0.01583.2525 Perry 5.7 5.1 0.33 2.8 1.5 0.38 0.25 0.03583.2736 Perry 2.5 2.1 0.028 1.1 0.84 0.12 0.12 0.01583.2545 Perry 3.5 1.9 0.51 1.4 0.62 0.14 0.10 0.01583.2412 Perry 2.7 2.0 0.062 1.1 0.71 0.13 0.12 0.01583.2095 Perry 3.1 1.8 2.5 1.2 0.7 0.12 0.10 0.01083.2268 Perry 3.4 1.8 0.60 1.3 0.62 0.11 0.07 0.01583.2137 Perry 3.7 2.0 0.028 6.5 0.85 0.12 0.11 0.02083.2139 Perry 4.5 4.7 0.090 2.2 1.5 0.34 0.28 0.03083.2246 Perry 5.0 2.8 0.067 1.6 1.0 0.19 0.15 0.02583.2586 Perry 2.1 2.0 0.017 1.2 0.71 0.099 0.10 0.01583.2930 Perry 4.5 2.7 0.86 1.9 0.84 0.18 0.20 0.02583.2406 Perry 2.4 2.0 0.039 1.2 0.74 0.099 0.085 0.01583.3070 Perry 2.8 2.7 0.039 1.5 0.95 0.14 0.17 0.01583.2812 Perry 4.7 3.2 0.056 1.7 1.1 0.19 0.20 0.02583.2699 Perry 5.9 3.8 0.084 2.3 1.3 0.27 0.19 0.03083.2443 Perry 2.3 1.7 0.022 0.79 0.73 0.083 0.10 0.01083.2412 Perry 3.9 2.3 0.045 1.5 0.84 0.14 0.090 0.01583.2397 Perry 4.4 2.6 0.050 2.6 0.76 0.13 0.080 0.01583.2139 Perry 9.9 11 0.073 5.4 1.7 0.35 0.11 0.04583.2206 Perry 3.8 2.9 0.056 1.4 0.97 0.15 0.11 0.01583.2317 Perry 3.3 4.1 0.202 1.8 1.5 0.24 0.20 0.02083.2172 Perry 3.0 2.3 0.034 1.2 0.9 0.13 0.17 0.01583.1993 Perry 3.0 2.2 0.028 1.3 0.82 0.12 0.14 0.015
54

Longitude County As ppm Al % Ca % Fe %

K

% Mg % Na %

P %

83.1735 Perry 4.5 2.7 0.078 1.6 0.96 0.18 0.15 0.01583.1855 Perry 3.2 2.3 0.022 1.6 0.79 0.13 0.13 0.01583.1320 Perry 4.3 3.2 0.073 2.2 1.1 0.23 0.10 0.02583.1477 Perry 3.5 4.9 0.12 2.1 1.6 0.36 0.19 0.03083.1290 Perry 2.6 2.1 0.017 1.4 0.69 0.12 0.090 0.01583.1217 Perry 4.4 2.4 0.034 2.2 0.82 0.13 0.070 0.02083.1426 Perry 3.9 2.6 0.056 1.6 0.94 0.15 0.10 0.01583.1901 Perry 1.7 1.3 0.11 0.72 0.59 0.061 0.055 0.01083.1781 Perry 5.5 4.8 0.11 2.3 1.5 0.35 0.14 0.03083.1761 Perry 2.9 2.4 0.045 1.2 0.95 0.14 0.15 0.01583.1575 Perry 1.8 1.4 0.022 0.63 0.64 0.066 0.060 0.01083.1331 Perry 6.0 2.6 0.062 1.8 0.96 0.18 0.090 0.02583.1617 Perry 7.0 2.1 0.15 1.5 0.89 0.15 0.10 0.02083.1175 Perry 4.3 3.3 0.078 2.0 1.0 0.23 0.26 0.02583.0884 Perry 20 5.9 0.11 4.3 1.7 0.44 0.33 0.03583.0262 Perry 5.1 4.4 0.056 3.0 1.3 0.27 0.23 0.02583.0557 Perry 4.8 3.4 0.039 2.1 1.2 0.22 0.16 0.02583.0709 Perry 3.0 2.6 0.039 1.3 0.92 0.16 0.17 0.01583.1119 Perry 3.4 2.3 0.028 1.4 0.70 0.15 0.13 0.01583.1755 Perry 4.8 2.6 0.017 2.7 1.1 0.16 0.10 0.02583.1919 Perry 3.5 2.4 0.066 1.2 0.86 0.15 0.10 0.01583.2043 Perry 3.3 2.9 0.055 1.4 1.0 0.19 0.14 0.01583.1470 Perry 3.8 2.1 0.16 1.1 0.77 0.12 0.090 0.01583.1684 Perry 2.0 1.3 0.022 0.69 0.46 0.072 0.065 0.01083.1484 Perry 2.4 1.8 0.022 0.75 0.70 0.094 0.11 0.01083.1635 Perry 5.3 2.0 0.055 1.3 0.80 0.12 0.075 0.02083.0997 Perry 3.8 4.2 0.072 2.2 1.3 0.31 0.33 0.02583.0540 Perry 5.2 3.0 0.044 2.1 0.88 0.20 0.20 0.02083.0580 Perry 6.7 5.7 0.12 2.8 1.7 0.44 0.35 0.030
55

Longitude County As ppm Al % Ca % Fe % K% Mg % Na % P %

83.0558 Perry 5.9 6.4 0.18 3.0 1.9 0.51 0.40 0.04083.0744 Perry 3.0 1.9 0.028 0.96 0.75 0.11 0.04 0.01083.1066 Perry 4.7 3.3 0.055 1.7 1.1 0.22 0.24 0.02083.0862 Perry 2.5 2.9 0.050 1.3 1.1 0.19 0.23 0.01583.1060 Perry 2.2 2.1 0.033 1.1 0.77 0.11 0.070 0.01583.1306 Perry 2.6 2.2 0.033 1.1 0.84 0.13 0.14 0.01583.1433 Perry 3.1 2.4 0.033 1.4 0.79 0.15 0.060 0.01583.1619 Perry 2.1 1.4 0.16 0.75 0.57 0.066 0.040 0.01083.1340 Perry 3.1 4.0 0.099 1.7 1.3 0.26 0.10 0.02083.1122 Perry 2.1 1.6 0.028 0.68 0.5 0.072 0.025 0.01083.0840 Perry 2.4 1.7 0.094 0.87 0.59 0.083 0.030 0.01083.1164 Perry 5.1 1.7 0.044 1.2 0.59 0.094 0.060 0.01583.1119 Perry 3.2 3.1 0.039 1.4 1.2 0.17 0.19 0.015

Perry 4.3 2.6 0.039 1.4 0.76 0.15 0.16 0.015

82.5439 Pike 3.6 3.0 0.088 1.3 1.2 0.16 0.46 0.01582.5827 Pike 4.2 2.7 0.34 1.3 1.1 0.17 0.26 0.02082.5729 Pike 2.4 2.0 0.022 0.89 0.92 0.09 0.19 0.01082.5092 Pike 2.7 2.7 0.033 1.4 1.0 0.16 0.33 0.015

82.5092 Pike 3.3 5.3 0.091 2.3 1.6 0.33 1.0 0.030

82.4714 Pike 3.4 2.9 0.044 1.1 1.2 0.16 0.48 0.01582.4974 Pike 2.5 3.2 0.039 1.4 1.2 0.17 0.31 0.01582.5525 Pike 2.0 2.2 0.033 0.88 0.90 0.11 0.29 0.01582.5278 Pike 2.4 2.4 0.033 0.92 1.0 0.12 0.33 0.01582.5480 Pike 1.9 2.0 0.039 0.90 0.84 0.099 0.26 0.01082.4075 Pike 2.4 2.7 0.055 1.1 1.1 0.15 0.21 0.01582.4360 Pike 3.1 2.7 0.061 1.2 0.97 0.15 0.18 0.01582.4458 Pike 2.3 1.9 0.022 0.78 0.79 0.10 0.14 0.01082.4916 Pike 1.4 2.2 0.028 0.78 0.90 0.11 0.27 0.01082.5210 Pike 2.7 2.9 0.050 1.1 1.2 0.17 0.37 0.015
56

Longitude County As ppm Al % Ca % Fe % K% Mg % Na % P %

82.5632 Pike 2.0 2.2 0.033 0.99 0.94 0.12 0.31 0.01082.3447 Pike 3.2 2.7 0.039 1.1 1.0 0.15 0.31 0.01582.3644 Pike 2.3 2.5 0.028 1.0 1.0 0.14 0.26 0.01082.3395 Pike 10 3.2 1.4 1.5 1.1 0.24 0.34 0.015

82.3395 Pike 11 5.0 1.4 2.5 1.5 0.40 0.78 0.025

82.3649 Pike 3.4 1.8 0.094 0.75 0.84 0.11 0.15 0.010

82.3649 Pike 4.6 4.0 0.080 1.7 1.6 0.20 0.57 0.025

82.3311 Pike 3.6 3.0 0.050 1.4 1.1 0.17 0.21 0.01582.3416 Pike 3.7 3.3 0.055 1.3 1.1 0.20 0.45 0.02082.3765 Pike 2.4 2.3 0.072 0.89 0.96 0.12 0.19 0.01582.4422 Pike 2.9 2.8 0.044 1.2 1.0 0.16 0.42 0.01582.3538 Pike 3.3 3.1 0.044 1.4 1.0 0.19 0.37 0.01582.3577 Pike 6.6 4.2 1.4 2.0 1.3 0.42 0.41 0.025

82.4931 Pike 3.9 4.3 0.10 1.8 1.4 0.23 1.0 0.025

82.5922 Pike 6.4 5.1 0.12 2.3 1.5 0.36 0.30 0.02582.5745 Pike 3.0 2.1 0.044 1.0 0.82 0.12 0.29 0.01582.5206 Pike 3.1 2.6 0.33 1.4 0.96 0.20 0.35 0.01582.5537 Pike 5.6 4.3 0.099 2.6 1.4 0.33 0.46 0.03082.5111 Pike 3.2 2.7 0.64 1.6 0.90 0.22 0.29 0.02082.4798 Pike 4.2 2.7 0.79 1.4 0.99 0.18 0.35 0.01582.4628 Pike 2.0 2.9 0.22 1.1 1.1 0.17 0.46 0.01582.4852 Pike 2.4 2.8 0.24 1.3 1.0 0.16 0.43 0.01582.4156 Pike 2.9 2.8 0.15 1.2 1.0 0.17 0.45 0.01582.4114 Pike 4.0 3.1 0.14 1.7 1.1 0.20 0.39 0.02082.4354 Pike 3.2 3.2 0.061 1.5 1.1 0.19 0.45 0.02082.4685 Pike 4.5 3.3 0.23 2.0 1.0 0.22 0.34 0.02582.4485 Pike 4.9 3.3 0.077 2.1 1.0 0.23 0.35 0.02082.3851 Pike 3.8 3.0 0.066 2.0 0.91 0.20 0.29 0.02082.4322 Pike 3.7 3.3 0.12 2.5 0.96 0.23 0.32 0.030
57

Longitude County As ppm Al % Ca % Fe % K% Mg % Na % P %

82.4315 Pike 4.8 3.3 0.088 2.5 1.0 0.23 0.32 0.03082.4265 Pike 4.7 2.6 0.12 1.4 0.84 0.17 0.26 0.01582.3923 Pike 4.6 3.1 0.11 1.9 0.95 0.21 0.32 0.02082.3669 Pike 33 6.1 0.15 2.5 1.7 0.39 0.27 0.02582.2715 Pike 3.3 3.3 0.666 1.8 1.0 0.25 0.41 0.02582.2400 Pike 3.2 3.2 0.077 1.7 0.99 0.22 0.36 0.02082.2575 Pike 4.4 2.8 0.11 1.4 0.90 0.17 0.30 0.01582.2160 Pike 6.4 3.5 0.066 2.2 1.0 0.23 0.30 0.02582.2627 Pike 6.5 3.9 0.22 2.3 1.2 0.27 0.30 0.02082.3058 Pike 6.4 3.2 0.40 2.1 0.93 0.24 0.28 0.02382.3228 Pike 3.6 2.9 0.16 2.0 0.87 0.18 0.22 0.02582.5462 Pike 4.6 3.9 0.077 2.4 1.2 0.27 0.44 0.02582.5376 Pike 5.0 3.3 0.061 2.4 0.95 0.23 0.31 0.02582.5160 Pike 2.5 2.4 0.083 1.5 0.80 0.15 0.29 0.01582.5330 Pike 2.8 4.0 0.099 2.0 1.4 0.27 0.57 0.02582.6300 Pike 7.5 4.1 0.083 2.6 1.3 0.28 0.40 0.03082.6534 Pike 10 3.4 0.16 2.7 1.1 0.24 0.28 0.02082.6820 Pike 3.1 3.5 0.055 2.0 1.2 0.25 0.34 0.01582.6903 Pike 2.0 3.0 0.044 1.3 1.1 0.17 0.40 0.01582.7122 Pike 1.7 2.6 0.044 1.2 0.92 0.14 0.36 0.01582.7224 Pike 2.5 3.6 0.055 2.1 1.1 0.22 0.38 0.02582.6681 Pike 2.5 3.0 0.05 1.5 1.0 0.18 0.48 0.01582.6543 Pike 4.3 3.8 0.077 2.4 1.1 0.27 0.40 0.02582.6474 Pike 1.9 2.7 0.1 1.3 0.93 0.17 0.41 0.01582.5989 Pike 2.6 2.7 0.039 1.5 0.91 0.17 0.30 0.01582.6538 Pike 2.1 2.4 0.044 1.2 0.92 0.13 0.37 0.01582.6545 Pike 1.6 2.0 0.039 0.9 0.83 0.11 0.30 0.01082.5850 Pike 1.6 2.3 0.138 1.1 0.87 0.14 0.27 0.01582.5964 Pike 1.5 2.3 0.32 1.1 0.86 0.14 0.29 0.015
58

Longitude County As ppm Al % Ca % Fe % K% Mg % Na % P %

82.5544 Pike 4.5 2.5 0.12 1.3 0.90 0.15 0.35 0.01582.5519 Pike 2.2 2.8 0.1 1.4 0.99 0.15 0.40 0.02082.5719 Pike 1.8 2.2 0.12 1.1 0.79 0.13 0.34 0.01582.6163 Pike 4.2 3.3 0.066 1.6 1.1 0.22 0.47 0.02082.5914 Pike 12 3.9 0.1 2.5 1.2 0.26 0.28 0.02082.6180 Pike 3.5 3.9 0.11 2.9 1.3 0.24 0.51 0.03082.6207 Pike 2.4 2.3 0.061 1.5 0.77 0.15 0.29 0.01582.5826 Pike 2.4 2.9 0.072 1.5 0.99 0.19 0.31 0.02082.5562 Pike 3.2 3.4 0.099 2.2 1.1 0.23 0.43 0.02082.5698 Pike 4.8 3.6 0.12 3.9 1.1 0.26 0.30 0.03082.5692 Pike 1.9 2.0 0.044 1.1 0.70 0.12 0.23 0.01582.4806 Pike 3.0 3.9 0.061 2.2 1.2 0.26 0.43 0.02582.3108 Pike 3.5 2.5 0.051 1.6 0.78 0.15 0.21 0.01882.3308 Pike 28 3.4 0.088 2.4 1.0 0.23 0.24 0.02082.3181 Pike 37 3.6 0.15 2.8 1.1 0.24 0.19 0.02082.3574 Pike 4.1 3.7 3.7 1.9 1.1 0.37 0.42 0.03082.4087 Pike 2.4 2.4 0.14 1.3 0.80 0.15 0.26 0.01582.4153 Pike 3.0 3.1 0.061 1.5 1.0 0.20 0.28 0.01582.4958 Pike 2.4 2.7 0.1 1.2 1.1 0.15 0.31 0.01582.5412 Pike 1.4 2.4 0.033 0.9 1.0 0.12 0.25 0.01082.5446 Pike 1.9 1.5 0.039 0.8 0.63 0.08 0.16 0.01082.3033 Pike 2.6 3.1 0.072 1.3 1.0 0.18 0.46 0.01582.3447 Pike 2.5 3.1 0.055 1.4 1.2 0.17 0.43 0.02082.2931 Pike 2.7 3.0 0.16 1.3 1.1 0.17 0.37 0.01582.2666 Pike 2.8 2.8 0.044 1.2 0.96 0.16 0.40 0.01582.2219 Pike 3.5 3.3 1.5 1.6 1.0 0.25 0.23 0.01582.2359 Pike 3.2 3.8 0.061 1.6 1.2 0.22 0.44 0.02082.1957 Pike 2.4 2.9 0.055 1.4 0.99 0.17 0.34 0.01582.1690 Pike 4.2 3.2 0.039 1.8 1.1 0.20 0.29 0.015
59

Longitude County As ppm Al % Ca % Fe % K% Mg % Na % P %

82.2630 Pike 3.1 2.7 0.066 1.5 0.85 0.17 0.25 0.02082.2230 Pike 3.0 3.0 0.066 1.4 0.98 0.17 0.37 0.02582.5346 Pike 2.5 2.8 0.083 1.4 1.0 0.17 0.40 0.01582.4952 Pike 2.6 2.6 0.20 1.2 0.89 0.17 0.34 0.01582.5199 Pike 2.5 2.3 0.25 1.5 0.74 0.17 0.24 0.01582.4938 Pike 2.6 2.5 0.083 1.3 0.82 0.15 0.31 0.01582.4640 Pike 1.4 1.9 0.033 0.92 0.68 0.11 0.22 0.01082.4781 Pike 1.8 2.1 0.15 1.2 0.71 0.12 0.23 0.01582.4534 Pike 1.3 2.3 0.033 0.95 0.96 0.12 0.20 0.01582.4266 Pike 3.2 3.8 0.072 2.0 1.2 0.25 0.14 0.02082.3181 Pike 9.5 4.6 0.061 2.7 1.4 0.26 0.47 0.02582.3646 Pike 1.7 2.7 0.050 1.1 1.1 0.15 0.26 0.01582.2259 Pike 3.5 3.2 0.072 1.5 1.1 0.20 0.38 0.02082.2373 Pike 8.4 5.2 0.061 3.0 1.6 0.35 0.50 0.03082.3120 Pike 13 3.8 0.033 2.0 1.3 0.22 0.37 0.02082.2109 Pike 1.8 2.3 0.033 0.94 0.87 0.12 0.30 0.01082.2412 Pike 2.0 2.9 0.055 1.1 1.0 0.15 0.32 0.01582.3322 Pike 5.5 2.6 0.033 1.2 1.0 0.14 0.22 0.01082.2679 Pike 7.9 4.2 0.12 2.0 1.3 0.28 0.34 0.02082.2774 Pike 3.7 3.3 0.23 1.7 1.1 0.23 0.31 0.02082.1529 Pike 4.4 3.2 0.044 1.9 1.0 0.21 0.30 0.02082.1873 Pike 5.8 4.4 0.072 2.2 1.4 0.28 0.47 0.02582.5197 Pike 3.5 3.2 2.5 1.5 1.0 0.31 0.34 0.01982.4958 Pike 4.1 3.9 0.59 1.9 1.2 0.28 0.47 0.02082.4532 Pike 7.7 3.0 0.25 1.7 0.92 0.19 0.34 0.02082.4497 Pike 2.4 3.0 0.34 1.6 0.99 0.20 0.40 0.02082.4329 Pike 4.7 2.3 0.46 1.6 0.68 0.16 0.25 0.01582.3960 Pike 1.7 2.4 0.34 1.1 0.81 0.14 0.29 0.01082.3690 Pike 7.8 1.7 6.5 1.6 0.51 0.32 0.07 0.010
60

Longitude County As ppm Al % Ca % Fe % K% Mg % Na % P %

82.3837 Pike 1.9 2.2 1.4 1.3 0.74 0.17 0.29 0.01582.5188 Pike 4.4 3.6 0.068 2.1 1.2 0.23 0.34 0.02582.4525 Pike 4.2 4.9 0.17 2.6 1.5 0.42 0.50 0.03582.3864 Pike 3.3 3.5 0.47 1.8 1.1 0.24 0.50 0.02082.1551 Pike 7.0 5.5 0.046 2.7 1.6 0.34 0.47 0.02582.1388 Pike 2.2 3.7 0.063 1.5 1.2 0.22 0.59 0.01582.5682 Pike 2.3 3.3 0.90 1.6 1.1 0.22 0.43 0.02082.5444 Pike 1.6 2.4 0.086 1.0 0.97 0.12 0.27 0.01582.5212 Pike 4.6 3.7 0.10 2.0 1.1 0.24 0.43 0.025

83.6960 Powell 2.0 1.0 0.034 0.7 0.29 0.072 0.06 0.01083.7331 Powell 5.8 1.6 0.057 1.6 0.44 0.12 0.13 0.01083.7915 Powell 16 2.9 0.086 2.4 0.89 0.28 0.21 0.01583.8449 Powell 18 2.9 0.41 2.8 0.92 0.22 0.16 0.01583.8090 Powell 13 2.0 0.103 1.6 0.62 0.18 0.16 0.01083.7651 Powell 12 2.4 0.23 2.1 0.72 0.22 0.18 0.01083.8611 Powell 28 5.6 0.40 3.8 1.8 0.56 0.32 0.02083.8833 Powell 57 7.0 1.2 5.8 2.2 0.66 0.36 0.03583.8927 Powell 80 6.7 0.13 7.0 2.4 0.56 0.27 0.06083.9239 Powell 9.4 2.0 0.33 1.5 0.60 0.17 0.15 0.010

83.9239 Powell 9.4 3.6 0.22 1.9 1.2 0.31 0.38 0.015

83.9799 Powell 89 7.0 1.0 10.2 2.1 0.82 0.12 0.1383.9874 Powell 56 7.8 0.33 6.9 2.3 0.57 0.14 0.09083.9725 Powell 56 6.4 0.029 8.9 2.0 0.42 0.14 0.1083.9439 Powell 42 3.9 0.051 3.3 1.3 0.37 0.25 0.01583.9330 Powell 98 6.6 0.04 10 1.9 0.43 0.12 0.15

83.9330 Powell 46 5.5 0.046 4.7 1.9 0.37 0.14 0.080

83.9477 Powell 38 5.4 0.24 4.8 1.7 0.42 0.22 0.04083.8833 Powell 11 1.8 0.091 1.7 0.54 0.14 0.16 0.01583.8506 Powell 4.8 2.2 0.24 1.5 0.66 0.20 0.12 0.015
61

Longitude County As ppm Al % Ca % Fe % K% Mg % Na % P %

83.8611 Powell 7.3 3.3 0.57 2.1 1.0 0.31 0.22 0.015

83.8611 Powell 8.6 5.4 0.41 2.8 1.8 0.52 0.44 0.020

83.8609 Powell 40 8.4 1.3 5.6 2.7 0.78 0.38 0.04083.8166 Powell 40 8.0 0.057 5.4 2.6 0.72 0.39 0.03083.7978 Powell 2.2 0.91 0.28 0.75 0.21 0.072 0.05 0.005

83.7978 Powell 5.9 3.5 0.37 2.1 1.1 0.27 0.33 0.020

83.7922 Powell 4.0 1.6 0.080 1.3 0.29 0.094 0.05 0.01083.7804 Powell 0.8 0.46 0.029 0.22 0.15 0.022 0.02 0.00583.7741 Powell 3.3 1.6 18 1.1 0.51 0.25 0.11 0.015

83.7741 Powell 5.1 3.1 16 1.9 1.1 0.40 0.24 0.020

83.7666 Powell 1.8 1.2 0.37 1.0 0.3 0.099 0.07 0.01083.7278 Powell 8.7 2.7 0.43 2.0 0.77 0.23 0.20 0.01583.6894 Powell 0.8 0.46 0.023 0.24 0.14 0.022 0.01 0.00583.7328 Powell 5.6 2.3 0.14 1.8 0.66 0.19 0.18 0.01083.7376 Powell 4.6 3.0 2.9 1.9 1.0 0.97 0.21 0.025

84.2058 Whitley 5.7 5.8 0.051 2.4 1.3 0.28 0.13 0.02084.2224 Whitley 2.6 2.1 0.063 1.4 0.50 0.099 0.14 0.02084.2824 Whitley 4.0 2.4 0.040 1.9 0.60 0.12 0.18 0.02584.1743 Whitley 5.2 5.2 0.068 2.2 1.3 0.31 0.11 0.02584.2829 Whitley 1.0 1.2 0.023 0.51 0.30 0.1 0.074 0.00584.2312 Whitley 5.1 4.2 0.086 2.3 1.3 0.28 0.32 0.03084.2312 Whitley 5.2 5.7 0.17 2.7 1.5 0.41 0.25 0.04084.2395 Whitley 3.9 2.7 0.04 1.8 0.68 0.14 0.16 0.02084.1662 Whitley 7.0 6.3 0.19 3.4 1.8 0.53 0.28 0.05084.1431 Whitley 6.4 7.7 0.25 3.4 2.1 0.56 0.29 0.05084.1426 Whitley 7.3 4.9 0.15 2.9 1.3 0.33 0.29 0.04084.1938 Whitley 5.5 4.5 0.086 3.0 1.2 0.28 0.33 0.04084.1930 Whitley 4.9 4.0 0.080 2.5 1.0 0.23 0.28 0.03583.9558 Whitley 7.8 6.5 0.086 3.5 1.6 0.42 0.20 0.045
62

Longitude County As ppm Al % Ca % Fe %

K

% Mg % Na %

P %

83.9581 Whitley 3.8 4.2 0.27 2.2 1.2 0.28 0.22 0.03083.9053 Whitley 4.2 4.8 0.103 2.6 1.3 0.31 0.27 0.03584.0232 Whitley 6.9 4.0 1.4 2.4 1.2 0.31 0.25 0.03583.9586 Whitley 4.0 4.6 0.13 2.5 1.3 0.28 0.26 0.03584.0376 Whitley 4.0 3.6 0.11 2.2 1.0 0.23 0.23 0.03084.0861 Whitley 2.9 3.0 0.22 1.6 0.83 0.18 0.25 0.02084.0490 Whitley 4.2 4.7 0.39 2.3 1.2 0.28 0.17 0.03584.0171 Whitley 3.1 3.1 0.051 1.5 0.92 0.16 0.31 0.02084.1268 Whitley 7.6 8.8 0.14 3.8 2.4 0.63 0.30 0.06084.1044 Whitley 5.9 7.2 0.14 3.3 2.0 0.52 0.36 0.05084.0610 Whitley 4.4 4.6 0.11 2.5 1.2 0.26 0.24 0.03583.9911 Whitley 3.6 3.5 0.063 1.7 0.91 0.18 0.19 0.02584.0189 Whitley 4.8 4.2 0.086 2.2 1.1 0.25 0.23 0.03584.0677 Whitley 4.5 4.3 0.22 2.3 1.2 0.26 0.33 0.03584.0880 Whitley 5.0 6.8 0.18 3.4 1.8 0.47 0.39 0.05084.0542 Whitley 4.5 4.9 0.11 2.6 1.3 0.30 0.42 0.04084.1154 Whitley 4.4 3.7 0.068 2.1 1.1 0.21 0.42 0.02584.1399 Whitley 5.7 4.3 0.19 2.5 1.0 0.26 0.16 0.03584.1903 Whitley 4.3 3.7 0.091 2.0 0.86 0.23 0.14 0.03084.2220 Whitley 2.4 2.8 0.057 1.3 0.68 0.13 0.13 0.02084.1929 Whitley 4.5 4.3 0.080 2.2 1.1 0.23 0.20 0.03084.1869 Whitley 3.1 3.2 0.034 1.6 0.79 0.15 0.11 0.02084.1197 Whitley 6.4 4.6 0.182 2.7 1.1 0.30 0.16 0.05084.1498 Whitley 2.9 2.6 0.068 1.3 0.60 0.12 0.13 0.02084.1743 Whitley 1.3 1.5 0.046 0.72 0.35 0.066 0.053 0.01084.2215 Whitley 2.5 2.2 0.051 1.2 0.53 0.11 0.063 0.01584.2404 Whitley 1.6 2.0 0.057 0.71 0.38 0.083 0.058 0.01584.2975 Whitley 1.7 3.1 0.063 1.4 0.87 0.17 0.15 0.02084.3000 Whitley 1.1 1.9 0.029 0.80 0.59 0.094 0.12 0.010
63

Longitude County As ppm Al % Ca % Fe % K% Mg % Na % P %

83.6260 Wolf 7.2 5.6 0.080 3.8 1.4 0.25 0.14 0.05083.6666 Wolf 2.0 1.1 0.041 0.80 0.32 0.050 0.026 0.01083.6673 Wolf 4.9 1.9 0.80 1.2 0.57 0.12 0.047 0.01583.5953 Wolf 1.4 1.7 0.03 0.70 0.56 0.099 0.042 0.01583.6145 Wolf 1.8 1.4 0.024 0.81 0.43 0.055 0.047 0.01083.2620 Wolf 1.6 1.6 0.035 0.69 0.63 0.072 0.19 0.01083.2736 Wolf 2.2 2.0 0.053 0.98 0.77 0.094 0.18 0.020

83.2736 Wolf 2.4 3.5 0.094 1.4 1.2 0.17 0.37 0.035

83.2932 Wolf 1.7 2.1 0.089 1.0 0.79 0.099 0.21 0.01583.3100 Wolf 1.3 2.0 0.030 0.87 0.83 0.088 0.22 0.01583.3405 Wolf 1.3 1.7 0.035 0.63 0.69 0.072 0.21 0.01083.3505 Wolf 1.4 1.7 0.024 0.85 0.71 0.083 0.15 0.01083.3430 Wolf 2.2 2.2 0.030 1.2 0.83 0.11 0.22 0.01583.3514 Wolf 2.1 2.4 0.041 1.4 0.87 0.15 0.21 0.02083.5797 Wolf 12 5.0 0.083 3.4 1.3 0.29 0.25 0.03583.5538 Wolf 11 3.2 0.065 3.4 0.81 0.17 0.16 0.030

83.5538 Wolf 6.5 3.7 0.083 2.5 1.0 0.20 0.32 0.030

83.5443 Wolf 14 4.5 0.059 4.3 1.2 0.24 0.31 0.04083.4988 Wolf 3.9 3.0 0.047 1.8 0.88 0.15 0.44 0.02583.4607 Wolf 3.6 2.7 0.041 1.5 0.88 0.14 0.29 0.02083.4734 Wolf 3.7 2.7 0.041 1.8 0.85 0.14 0.32 0.020

83.4734 Wolf 4.2 3.7 0.059 2.0 1.1 0.19 0.61 0.025

83.4519 Wolf 6.5 3.0 0.041 2.1 0.89 0.17 0.34 0.02583.4640 Wolf 5.0 2.8 0.047 2.0 0.82 0.17 0.37 0.02583.4609 Wolf 4.1 2.9 0.136 1.8 0.87 0.17 0.35 0.02083.4903 Wolf 5.5 3.9 0.23 2.1 1.1 0.24 0.21 0.02083.4725 Wolf 6.2 3.4 0.047 2.1 0.94 0.18 0.33 0.02583.4918 Wolf 6.5 2.3 0.035 2.3 0.69 0.11 0.15 0.02083.5041 Wolf 25 3.2 2.8 7.0 0.81 0.18 0.16 0.050
 Longitude County As ppm Al % Ca % Fe % K% Mg % Na % P % 

83.5364 Wolf 3.7 1.9 0.065 1.5 0.48 0.083 0.04 0.015 83.5057 Wolf 7.1 3.1 0.041 2.9 0.80 0.15 0.12 0.030 83.4709 Wolf 5.6 2.7 0.041 2.6 0.74 0.15 0.21 0.025 83.5355 Wolf 1.9 1.4 0.089 1.1 0.39 0.066 0.047 0.015 

83.5355 Wolf 2.0 1.8 0.059 0.87 0.54 0.088 0.079 0.010 

83.5309 Wolf 4.8 1.6 0.21 1.4 0.52 0.072 0.12 0.015 83.4468 Wolf 4.1 2.9 0.053 2.1 0.81 0.17 0.35 0.025 83.4089 Wolf 3.6 3.3 0.059 2.2 0.95 0.19 0.32 0.020 

83.4089 Wolf 4.7 4.5 0.083 2.5 1.3 0.26 0.55 0.030 

83.3929 Wolf 8.5 4.0 0.065 3.0 1.2 0.29 0.25 0.035 83.3887 Wolf 10 4.0 0.077 3.6 1.1 0.24 0.30 0.040 83.3918 Wolf 1.8 2.3 0.047 1.2 0.87 0.11 0.20 0.020 83.4963 Wolf 1.4 1.6 0.041 0.78 0.66 0.072 0.17 0.015 83.4321 Wolf 2.6 2.2 0.041 1.3 0.71 0.11 0.24 0.015 83.4250 Wolf 2.5 2.5 0.047 1.7 0.77 0.13 0.21 0.020 83.3786 Wolf 1.5 2.2 0.041 1.3 0.8 0.099 0.22 0.015 83.5168 Wolf 4.1 3.1 0.047 2.1 0.95 0.17 0.34 0.020 83.5344 Wolf 8.9 4.0 0.16 3.3 1.1 0.24 0.24 0.035 83.4881 Wolf 6.1 3.0 0.053 2.2 0.87 0.18 0.34 0.025 83.6113 Wolf 2.8 3.2 0.041 0.74 0.89 0.11 0.17 0.015 83.5973 Wolf 1.9 0.87 0.018 0.43 0.26 0.039 0.021 0.005 83.6223 Wolf 1.4 0.60 0.035 0.44 0.21 0.033 0.021 0.005 83.6100 Wolf 19 7.5 0.24 5.0 2.1 0.48 0.33 0.045 83.5830 Wolf 4.0 1.8 0.024 1.6 0.46 0.077 0.063 0.015 83.5911 Wolf 5.6 10 0.17 4.7 2.8 0.73 0.22 0.040 

64

65

Ba ppm Ce ppm Co ppm Cr ppm Cu ppm Ga ppm La ppm Li ppm Mn ppm Mo ppm

417 9 7 1 5 5 0 1 5 2 2 4 5 4 1 608 5302 9 9 9 2 9 8 1 3 4 3 2 8 359 3448 8 4 1 5 5 2 1 4 2 1 4 0 4 3 506 4389 8 4 1 9 4 7 3 6 2 2 3 7 5 8 423 5379 8 3 9 3 8 9 1 4 3 9 2 9 323 4260 7 0 1 0 2 9 1 0 1 2 3 3 2 0 351 3221 7 9 7 1 3 3 9 3 4 1 6 287 <2255 8 0 9 1 8 5 1 2 3 5 2 1 300 2341 7 6 1 2 3 4 1 2 1 4 3 3 3 1 421 3270 7 5 9 2 8 6 1 1 3 1 2 2 326 3393 9 3 1 3 4 2 1 1 1 8 4 1 3 7 586 4142 4 9 6 1 2 5 6 7 2 2 1 3 196 <2213 5 9 9 3 3 4 9 2 6 2 0 485 <2129 5 2 6 2 4 3 4 2 0 1 2 292 <2289 8 3 1 1 3 1 6 1 2 3 7 2 4 397 3341 8 4 1 5 4 6 1 1 1 6 3 5 3 5 685 4295 7 0 1 4 3 9 8 1 5 3 2 2 8 774 3294 8 5 1 2 2 4 9 1 4 3 8 2 9 502 3

8 8 3 8 4 1 6 <2 <4 1 5 9 171 <2

108 5 2 7 2 4 2 6 2 2 1 1 276 <2253 6 1 1 0 3 2 7 1 3 3 0 2 5 449 3373 8 5 1 8 4 7 1 3 1 7 4 0 3 7 744 5340 6 4 1 3 4 4 1 7 1 8 3 1 4 2 500 4381 8 5 1 4 4 2 1 3 2 0 3 9 3 3 563 4308 7 3 1 0 3 8 9 1 6 3 2 3 3 424 3384 8 9 1 1 4 4 9 1 7 4 0 3 5 460 4268 7 3 8 2 9 5 1 3 3 2 2 5 275 3342 8 6 1 5 4 0 9 1 7 3 9 3 5 585 4331 8 1 1 2 3 9 8 1 7 3 7 3 0 536 5
66

Ba ppm Ce ppm Co ppm Cr ppm Cu ppm Ga ppm La ppm Li ppm Mn ppm Mo ppm

1310 9 2 1 1 5 6 1 7 2 0 4 3 6 2 281 6

396 7 9 1 7 4 6 1 1 1 7 3 7 3 7 613 5

233 4 6 9 2 9 6 1 2 2 1 1 9 460 3240 5 5 8 1 9 5 1 1 2 6 1 9 392 <2278 6 3 8 2 2 8 1 2 2 9 1 8 297 2280 7 0 8 2 9 7 1 2 3 0 2 3 418 3277 7 2 9 4 3 8 1 3 3 2 2 2 386 3316 7 4 1 0 3 3 1 0 1 5 3 6 2 9 469 3242 5 2 8 2 4 8 1 2 2 3 2 0 320 2197 5 3 5 1 4 2 8 2 1 1 0 227 <2238 6 7 8 2 1 5 1 1 2 8 1 8 318 <2176 4 6 6 1 8 1 2 192 <2131 3 6 4 1 2 8 196 <2139 3 3 4 5 <2 6 1 1 7 174 <2240 7 3 7 1 4 7 9 3 1 1 4 214 <2

116 4 6 3 4 <2 <4 1 7 6 126 <2

216 5 4 6 1 7 6 7 2 0 1 3 193 <2244 6 4 1 0 5 1 5 1 0 2 4 1 6 473 <2249 4 3 7 1 6 1 3 204 <2229 6 3 7 1 2 3 9 2 6 1 4 214 <2543 125 1 6 6 6 2 0 2 5 5 3 5 1 925 6

181 4 2 6 1 1 2 7 1 5 1 0 275 <2196 4 3 5 1 3 3 6 1 6 1 0 262 <2

224 4 5 7 1 6 3 7 1 7 1 2 277 <2265 7 4 8 1 4 6 9 2 9 1 5 210 <2213 4 5 7 1 7 4 9 2 1 1 5 198 <2257 5 7 9 1 9 7 1 1 2 3 1 9 307 <2488 9 8 1 9 5 3 1 6 2 3 4 4 4 8 1500 5323 7 5 1 2 3 4 8 1 5 3 0 3 3 482 3

5 4 79 2 5

8 4 8
67

Ba ppm Ce ppm Co ppm Cr ppm Cu ppm Ga ppm La ppm Li ppm Mn ppm Mo ppm

327 6 9 1 1 3 0 7 1 3 2 8 2 5 418 3

158 3 4 5 1 2 3 5 1 4 9 231 <2204 4 2 6 1 7 1 0 220 <2

400 8 7 1 3 3 5 1 1 1 7 3 8 2 5 503 3268 4 9 1 1 2 0 6 1 1 2 0 1 5 387 <2163 4 1 7 1 4 1 1 270 <2202 4 3 6 1 1 3 7 1 6 1 0 222 <2

175 6 1 4 2 3 8 185 <2

228 6 6 6 2 6 1 3 272 <2

143 3 2 3 <2 <2 <4 1 1 6 133 <2

201 4 8 4 1 0 <2 6 1 9 9 113 <2260 6 3 1 3 2 3 8 1 0 2 3 1 6 489 <2264 5 1 8 1 8 4 1 1 2 1 1 5 297 <2183 3 9 6 1 2 9 263 <2308 6 0 1 1 3 0 1 0 1 3 2 5 2 3 407 3200 4 0 5 1 4 8 184 <2228 5 5 7 7 5 1 1 2 1 3 1 229 2193 4 4 5 1 8 1 1 182 <2

156 4 0 6 1 6 8 213 <2

192 4 6 6 1 1 4 7 1 6 1 1 252 <2191 3 0 6 1 3 9 191 <2182 4 0 1 2 1 0 5 8 1 5 1 2 423 <2

155 3 2 6 2 3 <4 1 2 8 457 <2177 4 2 5 1 4 8 137 <2

222 4 0 7 1 4 1 2 233 <2

294 3 9 5 1 3 8 189 <2159 4 1 4 3 <2 4 1 5 9 116 <2

165 8 6 4 2 <2 6 3 2 7 117 <2

112 2 5 3 <2 <2 <4 8 5 120 <2

8 2 79 7 8

4 2 75 4 84 2 63 2 57 3 7

9 3 56 3 8

5 2 65 3 75 3 5
68

Ba ppm Ce ppm Co ppm Cr ppm Cu ppm Ga ppm La ppm Li ppm Mn ppm Mo ppm

200 4 6 8 1 5 5 7 1 5 1 5 389 <2

156 3 1 3 <2 <2 5 9 7 7 9 <2145 3 5 5 3 <2 5 1 0 8 204 <2139 3 3 5 2 <2 4 1 0 9 276 <2

160 3 7 1 1 1 4 6 8 1 4 1 4 425 <2

150 3 8 1 0 1 0 3 6 1 4 1 3 439 <2

252 4 9 7 2 4 4 1 0 1 6 1 7 224 <2305 5 8 9 2 0 5 1 0 2 5 2 1 338 <2191 4 4 5 1 4 4 8 1 6 1 9 161 <2325 4 6 5 9 <2 6 1 7 2 2 193 <2243 5 5 8 1 0 4 9 2 1 3 2 290 <2235 6 4 6 2 6 1 2 203 <2180 3 9 6 5 <2 8 1 4 1 3 258 <2217 4 9 7 1 8 1 7 164 <2199 5 7 8 1 8 5 1 0 1 9 3 0 265 <2184 3 9 5 1 3 3 2 135 <2239 6 0 7 2 8 5 1 0 2 3 4 3 281 <2187 4 2 6 1 3 3 7 1 5 1 5 203 <2217 5 2 9 1 5 1 2 1 1 1 8 2 3 287 <2285 5 6 1 0 2 8 1 2 1 2 2 5 2 8 370 3

368 8 5 8 3 6 9 1 5 4 0 2 7 357 4366 9 9 1 0 3 3 8 1 7 4 7 2 9 380 4334 9 5 7 2 9 7 1 2 4 2 2 2 354 3391 104 1 1 3 0 1 2 1 8 4 8 3 3 366 4315 8 6 7 1 7 8 1 4 3 8 2 3 307 4360 107 1 0 3 7 1 0 1 8 4 8 3 1 404 4354 7 9 1 2 3 1 1 0 1 6 3 7 2 7 581 3340 104 1 0 3 1 7 1 5 5 2 2 5 543 4357 8 4 9 3 4 9 1 8 3 9 2 9 378 4

3 3 79 3 9

6 3 6
69

Ba ppm Ce ppm Co ppm Cr ppm Cu ppm Ga ppm La ppm Li ppm Mn ppm Mo ppm

427 101 1 2 4 0 9 2 0 4 7 3 1 456 5339 106 9 2 0 5 1 4 4 6 2 4 337 3318 9 6 9 2 8 6 1 4 4 4 2 4 375 3364 9 9 9 3 8 8 1 7 4 3 2 9 349 5302 7 7 1 0 3 2 8 1 7 3 7 2 7 393 4364 9 8 1 3 3 8 9 1 8 4 7 3 8 491 4419 9 9 1 3 4 4 1 4 2 0 4 7 3 8 566 4354 110 8 3 5 8 1 6 4 7 3 0 377 4319 7 2 1 0 2 7 6 1 3 3 3 2 2 380 2329 104 9 2 7 6 1 7 4 7 2 7 413 3288 8 5 8 3 0 8 1 4 3 8 3 3 438 3319 109 1 2 4 4 7 1 6 4 7 2 8 576 3362 102 8 2 7 6 1 6 4 5 2 2 255 2343 9 6 9 2 8 8 1 7 4 1 2 6 284 2443 9 7 1 3 4 4 1 7 2 1 4 3 4 0 600 4340 8 6 1 0 3 5 1 4 1 7 3 7 3 1 438 3321 8 6 1 0 3 2 1 2 1 7 3 7 3 0 362 3337 9 0 1 1 3 6 9 1 8 4 0 3 3 467 3340 9 5 1 1 3 9 9 1 6 4 2 3 2 653 3283 114 9 3 8 6 1 3 4 9 2 7 432 3291 8 7 1 1 3 1 8 5 1 4 3 8 2 3 873 3273 9 3 9 3 7 9 1 5 3 9 2 3 371 2341 8 9 1 1 4 0 1 0 1 7 3 9 3 1 581 4298 7 5 1 0 3 3 7 1 4 3 5 2 9 396 3185 8 2 5 1 4 4 8 3 3 1 6 232 <2293 9 9 7 2 1 7 1 4 4 5 2 4 266 3327 7 5 9 3 5 8 1 6 3 3 2 9 382 3

224 7 7 7 1 1 4 9 2 6 2 0 306 2
70

Ba ppm Ce ppm Co ppm Cr ppm Cu ppm Ga ppm La ppm Li ppm Mn ppm Mo ppm

277 6 9 1 0 1 1 7 1 2 2 8 2 7 416 2248 8 3 9 3 3 6 1 2 3 2 3 0 385 <2249 9 0 9 1 7 4 1 1 3 7 4 3 463 <2276 7 0 9 1 9 6 1 2 2 7 5 1 403 2293 8 5 1 1 1 7 7 1 4 3 4 2 9 526 3279 7 7 1 0 2 5 6 1 3 3 1 2 6 337 2324 8 7 1 2 3 2 1 2 1 4 3 4 3 5 671 3278 7 4 1 0 2 7 8 1 2 3 0 3 1 456 2386 9 0 1 4 2 9 1 4 1 7 3 5 5 1 538 3372 9 4 1 2 2 2 1 1 1 6 3 6 4 7 398 3293 9 0 1 0 2 8 6 1 4 3 5 5 1 366 3336 8 6 1 1 2 9 6 1 3 3 7 5 6 393 3286 7 6 1 0 2 8 8 1 2 3 0 2 2 395 <2272 8 9 9 1 8 5 1 2 3 7 2 0 337 2272 9 2 8 2 4 6 1 1 3 7 2 0 293 <2301 8 0 9 1 5 5 1 2 3 3 1 9 333 2322 135 1 1 2 1 6 1 3 4 9 2 1 370 <2291 100 1 0 2 5 5 1 3 3 9 2 1 460 <2281 8 1 1 4 4 8 1 0 1 5 3 0 3 0 468 2277 8 2 1 5 3 6 9 1 5 2 9 2 8 718 2232 7 2 1 3 3 4 9 1 3 2 8 2 4 397 <2224 6 9 1 2 2 3 6 1 2 2 4 2 3 664 <2199 8 6 8 1 3 3 8 3 1 1 5 444 <2233 7 9 1 0 1 7 5 1 0 2 8 1 9 539 <2248 7 4 9 1 9 6 1 1 2 7 1 9 305 <2308 9 7 1 7 4 3 1 0 1 6 3 6 3 6 836 3185 6 1 7 1 2 5 9 2 3 1 5 218 <2321 9 7 1 3 3 5 8 1 5 3 7 2 9 549 2262 7 8 1 2 3 6 8 1 4 2 9 2 5 354 3
71

Ba ppm Ce ppm Co ppm Cr ppm Cu ppm Ga ppm La ppm Li ppm Mn ppm Mo ppm

295 113 1 1 3 1 6 1 5 4 4 2 2 376 3273 9 2 9 1 5 5 1 2 3 4 1 9 248 <2352 8 6 1 0 5 3 1 9 2 0 3 4 4 0 216 4189 8 1 9 1 5 4 9 2 9 1 5 332 <2197 7 4 1 1 2 5 5 1 0 2 6 1 8 385 <2269 7 4 1 3 3 6 8 1 4 2 6 2 7 525 2193 7 0 1 2 2 9 4 9 2 3 1 8 494 <2230 8 6 1 0 3 5 6 1 3 3 2 2 5 318 <2157 5 9 8 1 6 3 8 1 9 1 3 329 <2166 6 4 8 2 6 3 8 2 2 1 3 319 <2151 7 9 8 1 0 3 8 2 8 1 2 314 <2315 7 7 1 4 4 1 7 1 5 3 7 3 0 594 3273 115 1 0 2 0 6 1 3 6 0 2 3 401 3271 6 3 9 1 9 6 1 2 3 5 2 1 300 3271 8 2 1 0 2 5 7 1 2 4 4 2 3 375 3

298 6 0 2 2 4 1 5 1 7 2 8 7 0 680 4213 5 7 1 8 4 4 3 1 1 2 6 3 6 595 3126 4 7 1 1 1 9 <2 7 2 3 2 3 386 2133 3 3 7 2 6 2 6 1 7 1 9 242 <2

8 1 2 7 5 9 <2 <4 1 1 1 1 185 <2

253 6 3 2 1 3 5 1 3 1 3 3 2 3 0 436 2 3306 6 8 1 7 3 9 1 1 1 3 3 5 4 2 359 5299 7 7 2 6 4 2 4 5 1 7 3 5 2 8 1190 2 1

187 5 0 1 2 3 5 5 1 0 2 2 3 3 386 3225 5 8 1 6 4 7 6 1 1 2 4 4 1 472 3228 4 0 9 3 0 3 8 1 8 2 8 328 2205 3 6 1 2 3 4 <2 9 1 6 2 6 370 2199 5 0 1 1 3 3 3 1 0 2 0 3 1 491 2144 3 4 9 1 7 <2 7 1 5 2 7 388 2
72

Ba ppm Ce ppm Co ppm Cr ppm Cu ppm Ga ppm La ppm Li ppm Mn ppm Mo ppm

133 1 7 3 9 <2 <4 7 9 145 <2

200 3 6 6 1 7 6 9 1 7 1 2 245 2229 3 6 8 1 8 6 9 1 7 1 5 285 2193 3 4 5 1 5 <2 8 1 7 1 0 219 <2229 4 3 7 1 7 4 1 0 2 0 1 5 281 <2227 3 2 8 2 1 8 9 1 6 1 6 389 <2215 4 6 5 1 7 3 7 2 2 1 0 194 <2235 3 4 6 1 6 7 9 1 7 1 3 235 <2279 4 6 9 2 2 4 1 1 2 4 1 6 358 2237 3 1 5 1 5 4 7 1 6 1 0 170 2185 2 8 5 1 3 1 1 205 <2246 3 0 7 2 8 6 8 1 8 1 4 210 <2274 4 5 6 1 8 4 8 2 1 1 2 162 2274 6 2 1 0 1 8 6 1 2 3 1 2 0 307 3257 5 8 3 2 4 6 1 1 2 6 1 8 7 1 3232 3 7 5 1 9 1 1 184 <2224 2 8 6 1 6 1 2 165 <2289 4 8 6 1 9 5 9 2 0 1 5 208 2277 4 0 6 1 8 4 1 0 2 1 1 4 228 2229 2 9 5 1 3 2 7 1 4 9 135 <2229 3 2 7 3 4 6 1 0 1 6 1 2 157 3273 4 9 1 0 2 3 1 1 1 3 2 1 2 1 367 3235 3 9 8 1 7 4 9 1 9 1 5 286 2220 4 0 8 1 5 6 9 1 9 1 5 299 <2243 4 5 5 1 4 7 9 1 8 1 4 158 <2190 5 7 4 2 7 9 125 <2230 3 9 6 8 3 1 0 1 8 1 2 204 <2

293 7 7 7 1 2 1 4 1 0 3 6 1 9 247 2

207 4 3 4 6 <2 8 2 0 1 0 140 <2

8 3 88 3 8

5 3 76 3 7
73

Ba ppm Ce ppm Co ppm Cr ppm Cu ppm Ga ppm La ppm Li ppm Mn ppm Mo ppm

251 5 2 8 1 8 5 9 2 4 1 5 420 2226 3 7 7 1 6 5 9 2 0 1 3 194 2

355 8 4 8 2 9 1 1 1 1 3 9 2 4 312 3

246 3 3 6 1 8 7 1 1 1 9 1 5 252 3214 3 0 6 1 4 1 1 188 <2298 4 9 6 1 0 3 9 2 4 1 5 238 2

368 9 1 6 2 9 6 1 1 4 2 1 9 285 2

225 3 7 5 5 <2 7 1 7 9 144 <2283 4 4 6 2 3 1 1 195 2

154 1 6 3 <2 <2 5 9 9 6 1 <2

248 3 1 5 5 <2 8 1 4 1 1 170 <2

201 4 1 3 3 <2 6 2 2 7 116 <2

201 4 2 7 1 4 3 8 2 2 1 3 313 <2281 4 4 1 0 6 6 1 0 2 3 1 7 306 3265 4 0 8 8 6 1 0 2 2 1 7 316 3301 4 2 8 1 1 5 1 1 2 1 1 6 268 3232 4 2 6 2 1 1 3 186 2253 3 2 5 2 0 1 2 136 3220 2 6 4 1 4 1 4 217 2236 3 2 8 1 2 4 9 1 7 1 5 326 2

488 100 9 2 5 1 0 1 2 5 0 2 5 300 3

275 6 4 1 1 1 7 3 0 1 1 3 7 1 7 447 3230 3 3 7 1 7 1 2 222 3

171 2 4 4 1 3 1 0 144 <2

188 2 7 4 1 4 1 0 7 2 2256 5 3 6 6 1 0 9 2 7 1 1 275 3214 5 5 7 1 0 8 9 2 7 1 9 174 2

360 115 7 2 8 1 0 1 2 5 2 3 1 178 2

241 2 7 6 4 <2 8 1 5 1 1 218 2

5 3 76 3 9

5 6 94 4 96 5 66 5 85 9 7

9 2 9
74

Ba ppm Ce ppm Co ppm Cr ppm Cu ppm Ga ppm La ppm Li ppm Mn ppm Mo ppm

232 3 6 5 1 4 1 1 190 <2

192 3 6 5 1 9 9 184 <2205 2 9 6 1 3 9 215 <2268 5 3 8 1 4 6 1 2 2 6 1 8 312 3255 5 2 8 1 3 3 9 2 1 1 6 305 2297 5 2 8 1 7 6 1 0 2 3 1 9 318 2286 4 9 6 1 7 5 8 2 2 1 5 262 2183 1 8 6 1 2 1 1 188 <2235 4 0 5 1 5 1 3 137 <2184 3 9 5 1 7 2 6 1 8 1 1 198 <2426 5 1 1 3 3 8 1 4 1 4 2 3 5 0 524 3287 4 6 9 1 8 6 1 1 2 3 2 0 321 2241 4 3 7 1 7 8 1 0 1 7 2 0 299 <2388 6 0 1 4 2 9 1 2 1 4 3 1 2 5 481 3300 5 4 1 2 2 8 9 1 1 2 7 2 3 423 3261 4 3 7 1 9 6 9 1 7 1 7 292 2258 4 8 8 1 5 4 8 2 2 1 6 220 2191 3 8 5 1 4 1 0 168 <2276 5 2 1 1 1 5 1 0 1 0 2 3 2 3 454 <2231 3 3 1 0 8 6 6 1 6 1 7 410 <2367 5 6 9 3 4 1 1 1 2 2 4 2 7 308 2

151 2 3 3 1 1 9 195 <2146 2 0 3 4 2 <4 1 1 6 160 <2182 2 3 4 3 4 <4 1 3 9 165 <2141 2 0 3 6 <2 <4 1 0 6 136 <2

185 4 4 3 3 <2 <4 2 0 9 8 6 <2237 4 7 6 2 4 1 5 165 <2182 4 2 4 2 5 1 1 160 <2

5 4 62 2 6

3 2 65 3 79 3 84 3 53 3 4

9 5 85 3 6
75

Ba ppm Ce ppm Co ppm Cr ppm Cu ppm Ga ppm La ppm Li ppm Mn ppm Mo ppm

383 6 0 1 9 3 9 1 6 1 6 2 9 3 6 856 3

222 6 1 8 3 5 8 9 2 8 1 9 286 <2202 5 8 5 2 6 6 9 2 5 1 8 186 <2348 7 8 1 2 3 8 1 2 1 5 3 9 3 2 474 3150 5 1 7 3 7 3 0 5 2 1 1 1 204 <2400 8 7 1 4 5 3 1 1 1 9 4 2 3 5 573 4124 4 4 5 2 2 3 5 1 9 1 0 207 <2180 5 8 5 2 2 1 2 6 2 5 1 2 258 <2126 3 7 1 5 3 7 9 6 1 7 1 5 380 <2

9 8 3 1 4 2 1 2 <4 1 2 8 220 <2

398 8 5 1 0 2 8 8 1 5 4 1 2 6 314 3450 9 4 1 1 2 9 1 1 1 5 4 4 2 9 399 3391 7 1 1 3 3 8 1 6 1 7 3 7 3 8 437 3276 5 8 1 0 2 9 1 1 1 0 2 7 2 6 380 <2191 5 3 8 2 4 5 8 2 5 1 6 247 <2196 3 8 5 2 2 5 7 2 1 1 5 149 2257 6 5 1 4 3 6 9 1 1 3 0 2 8 560 2251 6 5 1 4 2 7 7 1 1 3 1 2 4 488 2206 5 1 5 1 6 3 7 2 2 1 4 254 <2328 8 9 7 1 1 7 1 1 4 4 1 8 268 2216 6 3 3 5 <2 6 2 9 8 7 4 <2301 7 5 1 1 2 0 9 1 0 3 4 2 5 348 2341 7 7 1 2 3 7 1 1 1 4 3 5 3 2 424 2374 7 9 1 2 7 8 1 2 1 6 3 7 4 0 485 4322 6 4 1 2 3 3 1 2 1 2 2 9 3 0 389 2320 6 6 1 0 1 5 8 1 2 3 4 2 4 426 2371 9 0 1 3 3 9 1 5 1 5 4 5 4 1 509 3370 9 5 1 2 3 4 1 0 1 5 4 5 2 9 486 3340 7 6 1 1 3 1 1 0 1 3 3 7 3 1 384 3
76

Ba ppm Ce ppm Co ppm Cr ppm Cu ppm Ga ppm La ppm Li ppm Mn ppm Mo ppm

255 5 3 1 0 2 3 1 8 1 1 2 6 2 9 340 3355 7 9 1 0 7 9 1 2 1 3 3 4 2 8 486 3367 6 7 1 2 3 3 1 0 1 3 3 3 3 1 430 4302 5 3 1 1 4 5 1 5 1 3 2 7 2 4 312 2313 6 5 1 0 3 0 7 1 2 2 8 2 7 353 3277 9 7 7 2 6 8 1 0 4 5 2 1 313 <2350 7 4 1 0 3 4 8 1 4 3 6 2 9 408 3268 6 8 9 3 1 8 1 1 3 2 2 9 339 2362 8 0 1 2 3 3 1 0 1 3 3 9 3 1 505 3541 8 3 1 6 4 5 1 4 1 7 4 1 4 7 522 4205 6 5 7 1 4 4 7 2 7 1 7 236 <2242 4 8 9 1 5 6 9 2 4 2 0 412 <2309 7 2 8 2 2 6 1 0 3 3 2 0 363 <2

162 4 5 9 1 8 4 9 1 9 2 4 438 <2

7 1 2 5 9 1 4 3 <4 1 1 1 2 803 <2

118 3 1 8 2 0 <2 7 1 2 2 0 710 <2

5 7 1 8 4 5 <2 <4 1 0 8 224 <23 5 1 7 <2 3 <2 <4 5 6 112 <25 7 2 0 5 4 <2 <4 8 8 315 <24 5 1 7 7 3 <2 <4 7 6 525 <25 1 2 4 6 1 8 2 <4 9 1 0 329 <2

4 1 4 3 7 6 3 <4 2 0 1 2 454 <2

5 9 2 4 5 1 3 2 <4 8 1 0 385 <2

291 6 7 2 3 5 5 3 1 7 2 9 5 4 1270 4263 6 8 2 2 5 3 <2 1 4 2 7 3 3 1490 3311 7 7 2 9 4 2 3 1 5 3 3 4 4 2610 4

8 6 5 2 1 3 9 4 6 2 3 1 9 1040 <2

161 5 3 1 3 1 9 <2 8 2 5 1 6 1040 2

3 0 2 3 3 1 1 <2 <4 7 5 126 <2
77

Ba ppm Ce ppm Co ppm Cr ppm Cu ppm Ga ppm La ppm Li ppm Mn ppm Mo ppm

5 0 2 2 3 1 2 <2 <4 7 8 200 <26 8 2 5 5 1 0 1 1 339 <24 1 2 7 2 <2 <2 <4 9 5 9 7 <2

3 1 5 6 4 8 2 <4 2 6 9 182 <2

3 7 2 4 2 2 <2 <4 9 5 109 <2

111 3 7 8 2 7 <2 5 1 5 1 7 475 <2

9 1 2 9 7 1 7 5 4 1 0 1 7 441 <2

107 3 0 9 2 1 <2 6 1 3 1 6 575 <2

140 4 3 1 6 4 2 <2 1 0 1 9 1 6 482 3

5 4 3 2 4 5 6 <4 1 4 7 120 <2

226 5 6 1 6 3 5 4 1 1 2 2 2 6 999 3246 7 0 1 7 3 8 4 1 2 3 0 3 2 829 3255 5 8 2 1 131 1 0 1 7 2 8 4 1 1090 5142 4 2 1 0 2 9 2 7 1 8 1 7 482 <2169 5 4 2 1 4 2 <2 1 2 2 1 3 4 1180 3158 4 4 8 2 9 3 7 2 0 2 5 551 <2133 3 6 9 2 6 3 5 1 6 1 6 527 <2

5 9 2 1 8 2 0 <2 <4 1 0 1 1 612 <24 7 1 6 4 6 <2 <4 7 9 185 <26 3 3 4 2 4 1 1 3 <4 1 3 1 2 1230 <2

134 4 2 1 4 8 6 3 9 1 8 2 2 787 3

4 3 2 6 6 1 0 8 <4 1 2 1 1 400 <2

8 1 3 2 1 0 2 5 3 7 1 5 1 3 502 <2

136 4 8 1 5 4 1 4 8 2 0 2 6 674 2

107 5 1 5 3 0 2 5 2 2 1 7 189 <2187 5 4 1 1 3 1 5 6 2 5 2 1 974 2198 6 0 1 2 3 6 6 7 2 6 2 7 986 <2109 3 9 6 1 0 3 4 1 5 1 7 338 <2

9 3 4
78

Ba ppm Ce ppm Co ppm Cr ppm Cu ppm Ga ppm La ppm Li ppm Mn ppm Mo ppm

143 5 1 7 1 9 1 3 355 <2158 8 4 7 3 4 1 2 386 <2176 9 3 8 3 8 1 4 409 <2180 4 6 7 1 2 <2 6 2 3 1 7 427 <2160 5 1 9 1 5 3 6 1 8 1 9 512 <2126 4 8 5 1 7 1 2 310 <2161 5 5 1 0 1 5 5 7 2 0 1 7 879 <2240 6 3 1 0 3 4 6 1 2 2 7 3 1 539 3223 6 5 1 0 6 4 6 2 6 1 8 887 <2196 6 7 1 3 1 0 9 7 2 4 2 9 750 <2241 6 9 9 1 4 5 9 2 8 2 0 637 <2194 9 2 1 0 1 9 <2 6 4 0 1 5 794 <2137 5 4 5 2 4 2 6 2 2 1 4 292 <2203 6 4 8 1 1 4 7 3 0 1 5 412 <2

4 0 6 7 5 6 <2 <4 3 4 7 217 <27 8 7 1 7 3 9 1 1 281 <23 0 102 5 7 3 <4 4 8 7 223 <27 8 269 5 139 9 151 <26 1 8 4 8 4 1 1 1 323 <24 5 9 5 4 4 8 7 172 <26 1 9 0 9 4 3 2 0 4 4 3 1 1 409 <2

332 120 5 5 3 1 0 187 <2

214 3 6 6 1 7 5 7 1 6 1 5 205 <2201 3 9 6 1 6 1 1 218 <2239 4 8 1 0 7 4 9 1 9 1 5 413 <2283 8 0 7 5 3 1 0 3 6 1 6 256 2335 5 6 6 1 4 4 8 2 6 1 6 175 <2242 4 8 7 1 7 4 7 2 0 1 3 279 <2

136 3 4 4 1 3 7 137 <2

7 9 57 2 6

8 5 66 6 5

4 3 53 3 56 8 45 3 4

9 3 73 4 6

3 3 5
79

Ba ppm Ce ppm Co ppm Cr ppm Cu ppm Ga ppm La ppm Li ppm Mn ppm Mo ppm

249 5 4 7 1 9 5 8 2 2 1 5 308 <2341 6 5 9 2 0 9 1 3 3 2 2 6 386 3233 4 1 6 1 9 1 3 216 <2238 3 9 8 1 1 4 7 1 8 1 3 324 <2298 5 6 1 2 2 3 7 1 2 2 5 2 4 595 3273 5 1 9 1 7 6 9 2 4 1 5 375 3361 5 6 6 2 3 1 3 248 <2179 3 8 4 1 3 9 180 <2220 6 1 4 2 7 9 138 <2

178 3 1 3 <2 <2 <4 1 1 6 119 <2

241 4 6 6 2 0 1 1 305 <2228 4 0 6 1 6 1 0 228 <2

179 2 8 5 1 0 3 7 1 2 1 0 166 <2

279 5 0 8 1 6 6 1 1 2 2 1 8 252 2307 6 9 1 1 4 6 8 1 4 3 0 2 4 364 3268 5 3 1 0 2 1 1 0 1 0 2 1 1 8 354 <2

1250 5 8 1 1 2 9 8 1 2 2 5 2 5 541 2

205 4 9 1 0 1 8 5 8 2 1 1 5 467 2239 4 9 1 0 3 0 5 1 2 2 3 1 7 537 3247 4 9 9 1 3 8 1 0 1 9 2 0 326 2243 4 9 1 1 7 5 7 1 8 1 3 508 <2

185 4 0 4 <2 2 5 1 5 8 118 <2222 3 6 9 1 0 4 9 1 2 1 1 355 <2158 4 9 5 4 <2 4 2 3 8 197 <2

317 4 6 6 1 8 5 9 1 9 1 5 203 <2287 5 3 6 2 4 1 2 195 <2

175 3 4 4 1 0 8 105 <2

313 5 0 1 0 1 9 6 1 2 2 4 2 0 385 2196 4 1 6 1 5 1 0 218 <2

5 4 88 4 7

5 2 44 2 68 3 65 3 67 3 9

2 2 5

4 3 7
80

Ba ppm Ce ppm Co ppm Cr ppm Cu ppm Ga ppm La ppm Li ppm Mn ppm Mo ppm

228 4 2 6 1 4 1 3 214 <2250 4 4 6 1 0 5 9 2 0 1 4 234 <2269 4 5 5 1 7 1 1 198 <2186 3 6 6 1 4 9 188 <2237 4 5 7 1 9 1 6 256 <2241 4 1 6 1 6 1 4 218 <2263 4 3 8 1 2 7 9 1 8 1 4 304 <2206 3 5 5 3 <2 8 1 4 1 2 184 <2239 3 5 6 1 5 1 2 263 2259 4 1 6 1 9 1 4 221 <2205 3 6 6 1 4 1 3 264 <2

246 3 7 5 1 6 1 0 152 <2

216 3 7 5 1 3 1 0 188 <2

146 2 5 4 4 <2 5 9 6 114 <2205 2 9 4 2 8 2 5 1 2 7 135 <2185 3 5 4 4 <2 5 1 5 7 162 <2193 2 9 4 1 3 7 136 <2191 3 5 6 1 3 1 0 241 <2107 2 0 4 <2 <2 <4 8 5 114 <2152 2 8 3 2 3 <4 1 0 7 106 <2184 3 4 4 1 1 9 161 <2173 3 5 5 1 4 9 152 <2198 2 8 4 2 <2 5 1 2 7 6 6 <2119 2 4 6 <2 <2 <4 9 6 237 <2123 2 2 3 3 <2 <4 9 6 131 <2182 4 0 5 <2 <2 5 1 7 8 103 <2

380 8 1 1 6 4 2 9 1 6 4 0 3 3 808 4458 8 6 2 2 5 9 1 4 2 2 4 6 4 8 1600 6288 5 5 1 1 3 2 9 1 0 3 3 2 4 461 4

6 3 93 4 7

3 3 67 4 85 3 87 3 86 3 8

9 4 8

4 2 7

4 4 7

3 2 5

4 4 65 2 54 4 5
81

Ba ppm Ce ppm Co ppm Cr ppm Cu ppm Ga ppm La ppm Li ppm Mn ppm Mo ppm

275 7 2 1 4 1 9 7 1 0 3 6 2 4 420 3410 8 6 1 4 3 3 1 0 1 5 4 4 3 8 664 4352 6 4 1 3 3 2 9 1 2 4 0 2 7 562 4661 116 2 6 6 3 2 4 2 9 5 8 6 8 344 7262 6 2 6 1 3 4 8 3 3 1 7 206 3591 8 3 1 9 7 3 1 9 2 9 4 9 6 0 640 7441 8 4 1 5 4 0 1 2 1 5 4 7 3 6 721 5512 100 1 8 5 1 1 3 1 8 4 9 4 8 890 5271 8 5 1 0 2 4 5 1 1 4 4 2 3 320 3290 8 6 1 1 1 8 6 1 0 4 2 2 1 555 3354 7 1 1 4 2 6 9 1 4 3 6 3 0 683 4297 6 8 1 3 2 2 9 1 2 3 4 2 4 415 4384 9 2 1 4 3 6 9 1 6 4 6 3 2 379 5369 7 8 1 1 3 1 1 0 1 3 4 1 2 6 266 4218 6 7 7 1 4 3 5 3 3 1 4 238 2291 124 1 2 2 6 5 1 3 6 2 2 4 383 3265 9 7 1 0 1 7 5 1 0 5 3 1 9 375 4274 7 2 1 0 2 9 5 1 0 3 6 2 0 644 3316 8 8 1 5 3 8 8 1 3 4 4 2 7 646 4337 9 7 1 7 3 4 6 1 4 4 8 2 8 601 4347 8 9 1 4 3 2 1 0 1 4 4 3 3 0 631 4412 9 0 2 2 6 4 1 3 2 1 4 7 5 0 988 6279 8 2 1 9 3 0 8 1 0 4 1 1 9 1390 3267 5 9 1 5 2 9 6 9 3 0 2 1 853 3272 6 4 1 1 1 4 6 9 3 3 1 8 316 2327 7 5 1 3 2 2 9 1 2 3 8 2 6 454 3348 8 0 1 2 3 2 1 2 1 4 4 1 3 3 275 4378 7 9 1 6 4 1 1 2 1 8 4 0 3 4 591 4367 7 2 1 5 3 9 1 2 1 4 4 0 3 4 717 4
82

Ba ppm Ce ppm Co ppm Cr ppm Cu ppm Ga ppm La ppm Li ppm Mn ppm Mo ppm

362 8 4 1 4 3 9 1 0 1 5 4 0 3 0 431 4

113 4 5 7 1 5 2 5 1 4 1 1 344 <2101 4 3 5 6 <2 6 1 5 9 137 <2159 6 2 5 1 3 4 8 2 3 1 2 149 <2301 7 7 1 8 4 7 1 4 1 4 3 7 3 5 1190 3166 5 4 4 1 2 2 7 2 0 1 6 295 <2435 9 6 2 1 7 1 1 3 2 0 4 2 5 4 1430 4215 6 5 1 0 3 4 5 9 2 5 2 2 373 <2310 105 1 3 2 5 5 1 3 4 7 2 8 420 3348 9 5 8 2 0 5 1 3 4 6 2 5 281 3416 8 9 1 5 3 8 1 1 1 7 4 0 3 2 973 3250 9 6 7 1 4 5 1 2 4 1 1 5 182 2469 103 1 6 3 6 1 1 1 9 4 5 3 6 778 4235 8 9 8 1 8 5 9 4 4 1 4 161 2420 9 3 2 2 6 5 1 5 2 1 4 3 4 6 758 4267 7 2 1 4 3 4 4 1 0 3 3 2 3 826 2374 8 2 1 4 4 3 7 1 3 3 3 3 5 508 3384 9 1 1 0 4 5 1 0 1 9 4 4 5 7 274 4256 5 2 9 2 3 4 9 2 7 2 9 556 <2218 6 2 9 3 5 7 1 1 2 3 2 6 324 3279 7 6 1 1 2 1 8 1 0 3 0 2 1 268 2355 8 2 1 8 3 7 5 1 3 3 8 3 4 1150 2204 6 9 8 2 7 3 9 2 4 1 5 220 <2291 6 4 1 1 2 7 5 1 0 2 9 2 2 650 <2112 4 8 4 1 2 3 6 1 7 8 164 <2152 4 4 8 4 3 8 7 1 7 1 6 337 <2402 8 1 1 2 4 9 3 1 5 3 3 3 7 345 3296 7 6 1 2 2 7 5 1 1 3 1 2 8 195 3386 107 1 7 9 8 1 3 2 6 5 0 8 2 740 5
83

Ba ppm Ce ppm Co ppm Cr ppm Cu ppm Ga ppm La ppm Li ppm Mn ppm Mo ppm

290 6 0 8 3 6 5 9 2 5 2 2 589 <2222 6 9 7 5 8 5 1 0 2 8 1 9 315 2239 6 2 7 2 6 5 8 2 8 2 0 480 <2330 7 8 9 2 0 6 1 3 3 6 2 6 447 2339 8 1 8 2 8 5 1 2 3 7 2 7 567 3484 110 2 3 5 3 1 7 2 3 5 1 6 4 1280 5326 8 2 1 8 4 1 8 1 5 3 8 3 6 1000 3378 9 2 1 5 3 0 8 1 4 4 3 3 2 797 3304 8 5 1 4 2 7 7 1 3 4 0 2 9 755 3363 9 2 1 5 5 2 9 1 5 4 6 3 5 867 4422 104 2 0 7 6 1 5 2 2 4 6 5 9 753 5

519 102 1 1 3 6 1 1 1 8 4 4 5 3 332 4387 116 8 2 5 1 0 1 5 5 5 3 3 307 3569 178 6 1 1 3 9 8 1 1 2 242 <2

202 4 6 1 1 1 1 5 9 1 9 2 1 633 3372 7 6 2 0 3 9 9 1 9 3 5 5 0 1190 4400 7 6 2 3 3 5 1 5 1 9 3 5 4 7 1380 4261 5 7 1 2 2 2 6 1 2 2 2 2 4 645 2257 5 4 1 3 2 3 7 1 3 2 3 2 7 740 3239 5 6 2 0 3 9 7 1 2 2 3 3 1 1010 2228 5 5 1 3 3 0 6 1 1 2 2 2 2 753 2216 4 4 1 1 1 3 5 8 1 9 1 9 623 <2247 5 5 1 0 6 8 9 1 1 2 0 2 1 538 2

149 3 3 7 1 1 9 381 <2

165 5 3 8 1 9 1 8 484 <2

198 4 6 6 1 6 1 0 306 <2139 3 3 1 2 3 <2 5 1 2 1 0 681 <2

174 4 5 1 1 2 1 2 8 1 7 1 8 727 <2

107 3 5 8 7 <2 5 1 2 9 588 <2

3 2 5

8 3 6

5 3 6
84

Ba ppm Ce ppm Co ppm Cr ppm Cu ppm Ga ppm La ppm Li ppm Mn ppm Mo ppm

139 6 6 1 0 1 1 5 1 0 1 4 1 5 553 <2299 6 8 1 9 4 5 5 1 5 2 9 3 5 1190 3270 3 7 8 1 3 5 9 1 6 1 8 463 <2186 4 2 1 4 3 5 4 9 2 0 2 0 647 2226 6 2 1 4 4 0 5 1 2 2 5 2 9 871 2219 6 6 3 2 5 7 6 1 2 2 8 4 4 1340 3294 6 4 1 8 4 2 5 1 6 2 9 3 8 1390 2215 6 0 1 9 2 9 3 1 2 2 3 2 8 837 3246 6 2 1 6 6 4 4 1 4 2 7 3 5 950 3245 6 4 2 8 4 3 7 1 6 2 7 4 0 1570 3261 6 3 1 8 6 5 7 1 3 2 5 3 9 1210 3277 7 4 2 1 7 7 1 1 2 0 3 0 4 8 1120 4374 7 7 1 2 5 8 9 1 5 3 5 4 6 945 3308 7 5 2 7 5 3 8 1 9 3 0 5 1 2000 4

2 6 <5 <2 <2 <2 <4 4 3 3 8 <2

225 5 9 1 0 2 3 4 1 1 2 6 2 5 465 2110 2 6 7 1 4 2 4 477 <2

4 3 1 0 2 2 <2 <4 6 9 7 4 <25 2 1 5 2 3 <2 <4 6 7 8 3 <2

235 <5 <2 2 <2 <4 4 3 2 8 <2

7 2 1 0 <2 <2 <2 <4 4 3 169 <22 4 <5 2 <2 <2 <4 3 4 9 0 <22 7 <5 2 5 <2 <4 6 4 113 <23 7 9 3 5 <2 <4 5 6 150 <2

231 5 7 2 0 6 4 5 1 4 2 6 4 0 1280 3

120 3 9 6 1 1 3 5 2 2 1 6 370 <2

195 4 9 1 3 5 1 9 1 4 2 3 4 1 603 3

3 8 1 3 3 <2 <2 <4 5 5 213 <2

191 5 0 8 3 0 6 9 2 2 2 5 364 <2

6 3 7
85

Ba ppm Ce ppm Co ppm Cr ppm Cu ppm Ga ppm La ppm Li ppm Mn ppm Mo ppm

461 8 2 1 0 2 9 1 0 1 5 3 6 2 8 411 3

4 1 1 4 2 2 <2 <4 6 4 142 <2

165 4 9 1 0 1 2 <2 7 1 9 1 6 751 <2

4 5 1 9 2 <2 <2 <4 6 6 152 <2

233 4 8 9 2 3 5 1 1 2 0 2 2 596 <2238 6 5 1 4 3 2 <2 1 2 2 6 2 4 826 2

5 3 2 1 2 5 <2 <4 8 8 3 1 <2

119 3 8 8 1 7 <2 6 1 5 2 0 518 <2367 9 5 2 9 6 4 1 3 2 0 4 3 8 8 1700 4

289 7 6 1 1 2 3 8 1 2 3 5 2 2 480 <2288 6 8 8 2 7 8 9 3 3 1 6 510 2308 8 4 8 2 2 4 9 3 4 1 6 441 2360 8 5 1 1 3 1 150 1 6 4 2 3 1 532 3438 144 6 9 7 1 0 6 0 1 9 275 2430 126 8 3 8 1 2 1 5 5 3 3 2 403 3296 158 7 1 9 5 1 2 6 7 1 8 314 2286 8 9 7 1 3 5 1 0 3 8 2 4 314 <2254 6 2 6 2 0 4 1 0 2 6 1 6 275 <2416 8 9 8 2 5 9 1 3 4 1 2 3 387 3386 8 5 9 3 7 9 1 2 3 9 2 4 472 3311 9 2 7 2 8 1 9 1 3 4 2 2 5 315 3314 8 3 1 1 4 8 7 1 3 3 9 2 7 507 3240 5 7 8 1 5 1 7 9 2 6 1 8 326 2278 6 9 1 0 2 3 5 9 3 5 1 8 489 <2305 8 2 8 2 6 7 1 1 3 6 1 9 288 2174 6 1 3 2 8 1 1 139 <2243 7 2 5 1 3 3 9 2 9 1 7 203 <2260 8 2 6 1 2 6 1 0 3 4 1 6 277 <2295 6 9 7 1 6 5 9 3 1 1 7 314 <2

7 2 5
86

Ba ppm Ce ppm Co ppm Cr ppm Cu ppm Ga ppm La ppm Li ppm Mn ppm Mo ppm

246 7 6 5 1 9 4 1 0 3 1 1 5 223 <2294 8 0 6 2 2 9 1 1 3 2 1 9 320 <2229 3 9 4 1 5 3 7 2 1 1 1 167 <2321 112 5 2 2 3 5 1 1 4 9 1 8 223 <2304 7 1 7 2 5 6 1 0 3 2 2 1 289 <2306 103 7 2 5 6 1 3 4 1 2 0 307 <2244 6 7 6 1 1 5 1 0 2 8 1 7 283 <2

ins ins ins ins ins ins ins ins ins ins

271 6 3 7 1 3 7 1 1 2 9 1 7 265 <2289 6 5 7 2 0 6 9 3 2 1 7 268 <2249 7 6 5 1 2 4 6 3 0 1 3 209 <2248 6 5 5 1 2 5 8 2 8 1 4 218 <2407 7 5 8 2 7 7 1 2 2 9 2 2 366 2169 3 9 7 1 7 <2 6 1 8 1 6 621 <2392 9 1 9 2 8 9 1 5 4 0 2 5 421 2309 9 2 7 1 1 5 9 3 9 1 8 277 <2270 105 5 4 4 1 3 228 <2

388 107 1 1 2 2 1 1 1 4 4 6 3 1 404 3358 116 8 1 8 7 1 3 5 1 2 4 365 2345 117 7 3 6 7 1 3 4 9 2 5 288 2391 102 1 2 3 1 1 1 1 7 4 6 3 3 561 3441 9 4 1 5 4 2 1 8 1 7 4 4 3 0 609 5394 7 6 1 4 3 4 1 6 1 5 3 9 3 1 402 3480 9 2 1 3 4 6 2 0 1 6 4 4 3 2 442 3388 7 9 1 0 3 5 1 0 1 5 3 6 2 5 260 3461 8 0 1 3 4 1 1 3 1 8 4 1 3 1 450 4328 6 2 7 2 3 4 1 1 3 0 1 7 230 3497 101 1 3 4 6 1 4 1 9 5 2 3 4 435 4416 7 4 1 2 4 2 3 1 1 5 3 6 2 9 391 3

8 3 9
87

Ba ppm Ce ppm Co ppm Cr ppm Cu ppm Ga ppm La ppm Li ppm Mn ppm Mo ppm

462 8 2 1 0 3 3 9 1 2 3 8 2 3 396 3443 7 1 1 1 3 5 8 1 4 3 8 2 6 449 3381 6 7 1 0 3 4 8 1 4 3 8 3 3 199 3495 9 0 1 4 5 5 1 9 1 9 4 4 5 0 297 4460 125 1 4 4 5 1 5 1 7 6 7 3 6 296 4459 109 1 1 3 6 1 1 1 4 5 0 2 9 383 4566 9 9 1 6 5 0 1 8 2 0 5 0 4 1 461 4425 8 7 1 1 4 0 1 1 1 5 4 2 2 9 342 3476 9 6 1 1 3 4 9 1 4 4 5 2 7 409 3368 7 2 9 2 5 1 1 1 3 3 1 2 5 327 <2486 8 6 1 4 3 5 1 2 1 8 4 2 3 4 535 4566 100 1 4 4 7 1 7 2 1 4 5 4 7 463 4387 9 2 1 2 3 7 1 1 1 5 4 2 3 6 398 4263 143 6 1 5 4 8 6 3 1 5 267 2393 105 1 1 3 6 1 2 1 4 5 2 2 9 373 3492 9 9 1 2 4 2 1 6 1 8 5 0 3 4 396 4481 8 0 1 1 3 0 8 1 5 4 1 2 6 387 3378 7 3 1 1 2 3 7 1 5 3 5 2 2 369 3369 8 3 1 1 1 5 8 1 2 4 1 2 2 453 3404 8 7 1 3 3 5 1 2 1 5 4 3 6 0 487 3314 7 3 8 1 3 4 9 3 5 1 6 280 2363 8 8 1 1 2 6 7 1 2 3 9 2 3 357 3405 9 4 1 4 4 3 1 1 1 6 4 2 3 2 750 4364 7 8 1 1 2 8 6 1 3 3 4 2 1 321 2807 122 1 2 3 0 1 0 1 6 5 6 2 8 357 4355 112 1 1 3 3 7 1 3 5 3 2 2 351 3523 8 8 1 5 4 5 1 4 1 9 4 6 3 2 666 4248 6 6 8 2 1 4 1 0 2 8 1 6 283 2193 8 0 6 1 6 6 8 3 6 1 3 138 <2
88

Ba ppm Ce ppm Co ppm Cr ppm Cu ppm Ga ppm La ppm Li ppm Mn ppm Mo ppm

260 6 3 7 1 9 4 8 2 7 1 5 264 <2279 8 2 8 2 1 6 1 2 3 5 1 9 299 <2318 9 8 1 1 2 7 7 1 4 4 0 2 3 412 3280 114 7 1 4 4 8 4 9 1 5 315 2286 8 9 1 0 2 7 8 1 3 3 6 2 3 379 2351 102 1 3 3 9 1 0 1 7 4 7 3 0 469 3278 5 8 7 1 3 4 9 2 9 1 4 331 <2306 7 5 8 4 0 9 9 2 9 1 7 229 1 0341 8 8 9 2 7 9 1 2 3 8 2 2 376 <2351 9 1 7 1 3 5 1 0 4 1 1 8 268 <2304 8 5 6 1 5 5 8 3 6 1 5 223 <2319 9 0 1 1 2 7 6 1 1 3 7 2 2 546 2378 8 6 1 3 3 5 1 2 1 7 4 1 3 4 654 3346 130 7 1 5 5 1 0 5 9 2 3 355 <2251 109 5 4 2 1 1 179 <2142 4 5 3 3 <2 5 1 6 6 121 <2343 109 1 3 3 8 9 1 7 4 5 2 8 514 3328 135 9 2 1 6 1 4 5 7 2 5 359 <2153 4 7 5 1 6 5 7 1 6 9 209 2398 110 1 3 4 4 1 6 1 9 4 8 3 7 455 3311 398 8 5 4 7 1 3 179 2 2 345 <2326 9 4 9 2 8 6 1 1 4 5 2 2 413 3400 101 1 4 4 6 1 0 1 6 4 9 4 1 680 4320 8 9 1 0 2 0 5 1 2 4 0 2 1 350 3327 8 1 7 3 7 6 1 0 3 5 1 6 206 2323 7 9 1 1 2 0 8 1 1 3 3 2 8 539 3501 100 1 4 4 3 1 0 1 7 4 6 3 7 451 4542 105 1 0 7 0 1 8 2 7 5 3 6 6 293 6408 119 1 3 1 8 1 3 1 8 4 9 3 9 472 3

9 4 9
89

Ba ppm Ce ppm Co ppm Cr ppm Cu ppm Ga ppm La ppm Li ppm Mn ppm Mo ppm

199 7 1 7 1 4 4 6 3 2 1 4 604 <2346 158 9 3 0 6 1 3 7 3 2 3 197 3417 126 1 2 4 6 1 1 1 7 5 9 3 0 434 4355 9 0 8 2 2 4 1 1 4 0 1 8 357 2369 9 7 9 2 9 6 1 3 4 4 2 3 255 3160 7 4 4 3 1 8 107 <2204 4 8 7 1 8 4 7 2 4 1 3 301 <2179 7 6 4 3 5 1 0 127 <2298 8 3 7 1 8 3 8 3 6 1 7 229 <2328 102 7 2 1 4 9 4 7 1 7 320 2412 106 1 4 4 4 1 0 1 5 5 2 3 3 858 5294 8 0 8 3 8 6 1 0 3 9 2 2 232 3369 9 5 1 2 4 1 1 1 1 2 4 7 3 3 467 5361 9 1 1 2 3 5 1 3 1 5 4 4 3 3 601 4369 202 9 2 7 9 1 2 9 8 2 3 689 3376 101 9 3 3 5 1 1 5 0 2 4 370 3386 117 1 3 4 0 9 1 4 5 5 3 2 637 4300 211 7 1 9 5 6 102 1 3 207 2310 136 8 1 9 6 1 0 6 1 1 8 251 3313 117 1 2 3 5 1 6 9 6 0 2 3 498 4310 9 2 8 145 1 0 1 0 5 0 2 0 332 4230 101 6 2 1 9 5 4 4 1 3 216 3338 111 1 0 3 3 1 0 1 1 5 4 2 4 310 3394 107 9 3 0 1 1 1 3 5 4 2 3 238 4301 216 6 2 5 4 6 9 8 1 5 246 3351 100 1 0 3 5 9 1 0 4 9 2 4 316 4356 125 1 1 3 9 9 1 4 6 2 2 7 497 4308 143 1 1 2 9 5 9 7 1 1 9 581 4335 108 1 0 3 3 9 1 0 5 2 2 3 316 3

7 4 59 3 6
90

Ba ppm Ce ppm Co ppm Cr ppm Cu ppm Ga ppm La ppm Li ppm Mn ppm Mo ppm

235 4 0 9 1 5 7 9 2 0 1 7 332 2

433 118 1 4 4 2 1 7 1 2 5 8 3 4 595 4

183 4 5 6 1 3 3 6 1 9 1 1 137 <2

333 103 8 1 9 6 9 5 2 1 9 209 3

203 4 5 8 1 9 5 7 1 9 1 5 241 <2

331 124 1 1 3 5 1 1 1 2 5 7 2 8 298 3

183 5 0 6 1 5 3 5 2 1 1 1 239 <2

337 7 8 9 2 7 7 1 1 3 7 2 3 470 3

254 4 7 9 1 6 4 6 2 0 1 4 335 <2

305 8 0 9 2 2 5 9 4 0 1 9 289 3

194 4 7 6 2 1 9 296 <2

353 127 1 0 3 3 6 1 1 6 3 1 9 557 3

186 6 7 6 3 1 9 225 <2

302 156 1 0 3 0 4 1 0 6 7 1 9 391 3

138 3 0 3 6 <2 5 7 4 8 3 <2125 2 0 <2 <2 <2 <4 5 3 5 6 <2116 2 3 3 <2 <2 4 8 3 9 4 <2157 3 8 5 <2 <2 <4 1 3 5 237 <2142 2 6 2 <2 <2 5 8 5 8 5 <2

250 5 4 8 1 5 7 9 2 1 1 5 332 <2

142 2 7 3 8 <2 5 1 1 7 111 <2143 1 5 3 3 <2 <4 9 4 9 5 <2135 1 0 <2 3 <2 <4 7 5 9 1 <2132 2 1 3 9 <2 <4 8 5 9 8 <2142 2 1 5 7 <2 <4 9 5 258 <2161 2 6 5 9 2 <4 1 4 8 496 <2129 1 3 3 3 <2 <4 1 0 4 189 <2106 1 6 3 6 <2 <4 1 0 4 136 <2172 2 5 3 7 <2 <4 8 6 103 <2

6 2 58 3 5
91

Ba ppm Ce ppm Co ppm Cr ppm Cu ppm Ga ppm La ppm Li ppm Mn ppm Mo ppm

364 174 6 2 9 3 1 1 8 6 1 8 268 <2

145 1 6 <2 6 <2 <4 7 4 105 <2136 3 0 6 6 138 <2161 2 2 2 3 <2 <4 7 6 126 <2

378 9 6 6 1 3 3 8 5 1 1 3 260 3

115 2 5 2 4 <2 <4 8 5 100 <2154 2 3 4 9 <2 <4 1 0 6 135 <2118 1 0 <2 4 <2 <4 7 5 6 7 <2

9 9 1 4 2 4 <2 <4 7 4 7 9 <2

130 2 5 4 4 <2 <4 7 5 189 <2182 1 1 5 5 <2 5 1 0 6 352 <2148 4 6 3 3 <2 <4 1 4 5 156 <2148 2 7 2 1 2 <2 <4 8 6 7 8 <2144 2 4 3 4 <2 <4 8 5 8 8 <2170 3 1 <2 4 <2 <4 9 5 5 6 <2131 3 2 5 7 <2 <4 7 5 266 <2165 3 8 5 1 0 2 7 1 2 8 196 <2192 4 6 4 9 2 <4 2 0 7 197 <2

332 7 5 8 2 1 4 8 3 8 1 7 334 3

151 2 8 4 4 <2 4 9 7 156 <2174 3 2 3 8 <2 <4 1 2 6 105 <2129 <5 3 8 <2 <4 1 0 6 9 8 2157 2 6 3 5 <2 <4 1 0 7 137 <2

302 4 1 9 2 8 6 8 2 6 2 0 440 3

162 2 2 3 5 <2 <4 1 0 6 123 <2

217 2 9 9 1 9 4 7 1 3 1 5 475 2199 4 0 7 1 4 3 7 1 4 1 2 813 <2

157 2 1 3 5 <2 4 1 0 6 126 <2152 1 7 3 5 <2 5 9 6 123 <2

4 3 4 8
92

Ba ppm Ce ppm Co ppm Cr ppm Cu ppm Ga ppm La ppm Li ppm Mn ppm Mo ppm

148 2 6 4 5 <2 <4 1 0 5 231 <2132 2 0 <2 6 <2 <4 1 0 5 103 <2142 2 4 3 4 <2 <4 9 5 113 <2

304 7 4 5 1 6 5 7 3 9 1 2 181 3

235 3 6 4 1 2 <2 4 1 8 9 139 <2

180 2 5 4 1 7 3 <4 1 2 8 163 <2122 2 9 2 6 <2 <4 7 4 135 <2172 5 4 6 <2 <4 1 1 7 189 2

432 122 7 1 9 4 1 1 5 2 1 7 366 2

166 8 3 1 1 <2 <4 1 0 7 225 2187 1 6 3 7 <2 <4 1 2 9 116 <2190 2 1 4 7 <2 <4 1 4 1 0 107 2152 1 4 4 8 <2 <4 1 0 7 178 2221 1 4 4 1 5 4 4 1 2 9 210 <2151 2 1 3 6 <2 <4 1 0 7 191 <2

195 2 5 2 4 <2 <4 1 4 6 102 <2

192 3 3 3 6 <2 5 1 0 8 106 <2172 2 6 3 4 <2 <4 7 5 118 <2159 1 2 2 5 4 <4 7 4 9 6 <2212 5 5 4 1 5 <2 4 1 7 8 173 <2132 2 5 3 6 <2 <4 1 1 4 118 <2

138 6 9 6 3 3 <2 5 2 7 1 5 220 <2348 5 9 1 5 5 5 5 1 1 2 7 4 3 768 2279 5 8 1 1 1 5 3 9 3 1 3 0 353 3424 8 3 1 6 5 6 8 1 7 3 9 8 0 335 4265 6 6 1 2 1 7 2 9 2 9 2 9 561 3234 6 4 1 5 3 5 5 9 3 0 3 4 722 2374 7 4 1 8 2 8 4 1 2 3 6 5 3 454 3414 8 2 4 0 3 9 4 1 6 3 9 6 5 1300 5
93

Ba ppm Ce ppm Co ppm Cr ppm Cu ppm Ga ppm La ppm Li ppm Mn ppm Mo ppm

212 5 9 1 0 1 7 3 9 2 3 2 7 431 <2177 6 7 1 0 2 3 4 1 0 2 4 2 5 377 <2283 8 3 1 2 1 9 3 1 2 2 9 3 5 407 <2

243 100 8 1 3 3 6 4 2 1 6 310 2

6 5 2 7 5 4 <2 <4 8 7 224 <2

196 5 3 1 2 2 5 5 7 2 6 1 8 586 2199 5 3 1 2 1 6 4 7 2 5 2 1 658 2

252 8 6 1 2 2 4 4 1 0 3 8 2 4 653 <2

125 3 8 8 7 <2 5 1 5 1 2 467 <2175 4 7 9 2 0 1 5 464 <2

259 8 4 1 0 1 9 5 8 4 0 2 1 563 2

175 4 1 8 1 6 1 4 334 <2

267 9 8 9 1 5 5 9 4 3 2 1 397 2

174 4 1 9 1 3 4 6 1 9 1 5 362 2160 4 6 7 1 0 3 6 1 8 1 3 281 <2135 4 3 3 2 <2 <4 2 1 5 104 <2177 3 8 4 1 7 1 0 180 <2213 5 2 1 4 1 3 7 9 2 2 2 0 667 3395 8 6 1 9 5 3 1 4 1 7 4 2 4 2 1050 4

418 104 1 6 4 0 1 6 1 8 5 1 4 4 741 4

246 5 9 1 4 2 5 7 1 1 2 7 2 9 530 3196 4 5 1 0 1 3 7 7 2 1 1 6 438 2189 3 8 9 1 0 3 7 1 7 1 7 357 <2

298 8 1 1 8 4 4 1 1 1 5 3 2 3 4 593 3208 4 3 1 0 1 7 6 9 1 8 1 7 412 2299 7 0 1 8 3 7 9 1 5 2 8 3 6 760 4206 5 0 8 1 7 5 8 2 1 1 6 310 2233 5 9 1 1 2 5 1 3 1 1 2 6 2 2 357 3186 4 6 5 1 0 2 6 1 9 1 0 355 <2

9 3 78 3 76 2 5
94

Ba ppm Ce ppm Co ppm Cr ppm Cu ppm Ga ppm La ppm Li ppm Mn ppm Mo ppm

337 7 4 1 5 4 3 1 1 1 6 3 2 3 6 542 3161 4 0 6 1 1 4 5 1 6 9 189 <2175 3 9 8 1 1 6 6 2 0 1 4 248 2196 4 7 7 1 9 3 8 2 1 1 2 275 2183 6 5 8 1 4 5 7 2 9 1 6 292 2209 4 4 1 0 2 6 5 1 1 2 4 2 0 442 2154 4 7 1 0 2 5 4 7 1 9 1 4 455 <2

202 7 9 9 3 1 4 8 3 8 1 7 409 2

211 6 5 1 6 4 1 4 1 1 2 7 2 3 667 3366 7 2 2 0 4 7 1 0 1 3 3 0 3 5 1190 3249 6 4 1 9 4 5 7 1 3 3 2 2 9 795 3

137 4 6 1 0 1 7 2 6 1 9 1 3 468 <2

188 6 0 1 5 3 7 6 9 2 5 1 9 657 2

187 6 2 1 1 2 6 3 9 3 0 1 6 437 <2

249 6 1 1 0 2 8 6 1 0 2 8 2 1 386 3

115 3 4 5 9 <2 4 1 6 9 141 <2

175 6 7 5 1 1 2 7 2 7 1 1 165 <2148 4 0 5 1 7 <2 6 1 7 1 1 219 <2230 5 7 1 0 2 7 1 0 9 2 6 2 3 314 3219 5 4 1 4 3 9 6 1 2 2 5 2 4 521 3184 4 1 8 2 0 4 7 1 7 1 6 302 <2151 5 2 7 2 3 1 2 198 <2

246 7 3 9 2 3 6 9 3 8 1 8 257 3

200 6 3 1 2 3 8 6 1 1 2 7 2 3 485 3167 4 4 1 1 2 0 7 1 0 2 1 1 8 457 <2

9 8 3 2 5 7 6 <4 1 1 7 137 <2

286 7 7 1 8 5 3 1 6 1 6 3 3 3 6 731 3273 7 1 2 0 4 6 1 0 1 6 3 0 2 9 928 3381 8 3 1 8 7 2 1 3 2 0 4 1 5 7 712 4

7 3 6
95

Ba ppm Ce ppm Co ppm Cr ppm Cu ppm Ga ppm La ppm Li ppm Mn ppm Mo ppm

170 3 5 7 3 0 5 1 0 1 9 2 3 265 <2

206 4 9 2 9 5 3 3 1 3 2 2 2 4 1800 4384 9 6 1 6 6 8 7 1 9 4 8 4 9 509 5249 6 0 1 8 3 9 5 1 5 2 7 2 7 993 3164 5 4 1 2 3 6 4 1 1 2 2 2 0 648 3500 4 9 1 4 3 8 1 5 1 3 3 2 2 4 520 5258 5 6 2 3 4 1 4 1 8 2 9 3 0 899 4336 7 2 3 0 6 8 1 1 2 1 3 7 4 5 1190 4448 9 4 2 6 6 5 1 9 2 5 4 5 5 4 1190 4241 5 5 1 2 2 2 6 1 1 2 4 2 3 405 3154 3 4 1 2 1 3 3 8 1 6 1 4 404 2339 6 8 1 9 5 2 8 1 6 3 5 4 0 954 4

9 9 2 2 5 1 7 3 4 4 1 1 6 221 <2

234 122 7 2 2 6 8 5 9 1 4 284 2

128 4 0 6 8 2 1 5 2 2 9 194 <2

7 5 2 0 1 1 1 5 <2 6 1 0 1 0 278 <2

219 4 0 1 6 2 2 9 1 0 2 3 2 2 760 3

9 7 2 7 5 1 1 <2 <4 1 3 8 175 <2

104 1 6 7 4 <2 4 1 1 7 232 2

193 4 4 8 2 1 5 1 1 2 1 1 5 311 2390 6 0 1 6 3 7 1 2 1 3 3 0 3 0 547 4355 6 6 1 7 4 0 9 1 5 3 7 3 6 1590 4

6 5 2 3 2 5 <2 <4 8 4 113 <27 8 2 8 3 6 <2 <4 1 0 3 202 <2

194 5 2 8 1 9 3 9 1 8 1 5 376 <2176 4 1 7 1 5 4 7 1 6 1 1 281 <2167 4 5 8 1 9 8 9 2 0 1 4 285 <2

132 2 9 5 6 <2 7 1 2 7 182 <2112 2 5 4 3 <2 5 9 5 218 <2
96

Ba ppm Ce ppm Co ppm Cr ppm Cu ppm Ga ppm La ppm Li ppm Mn ppm Mo ppm

173 4 5 7 1 9 6 8 1 7 1 1 250 <2

142 3 4 6 1 1 3 6 1 4 1 0 216 <2

166 4 0 9 1 7 5 7 1 9 1 3 464 <2

144 3 7 5 1 4 8 234 <2

179 4 0 8 2 6 4 9 1 6 1 4 445 <2

160 2 8 6 1 2 8 237 <2

341 7 3 1 9 3 8 1 4 1 6 3 4 3 0 1810 3

177 4 0 5 1 2 3 8 1 5 1 0 343 <2194 2 6 1 3 1 4 4 6 1 2 1 2 422 <2149 2 8 1 9 2 1 4 6 1 3 1 0 673 <2150 2 8 9 1 0 6 6 1 1 1 1 264 <2131 3 4 1 1 1 2 4 7 1 2 1 0 623 <2170 3 6 7 1 6 <2 1 1 1 2 9 7 1 <2

340 6 9 1 5 3 4 1 3 1 6 3 3 2 7 552 2216 4 6 8 1 8 8 1 0 2 5 1 4 327 <2

154 3 2 1 4 6 6 9 1 0 1 2 348 <2

177 4 9 1 7 1 2 8 9 2 1 1 5 745 <2160 3 2 8 1 6 1 1 307 2205 3 8 1 1 2 0 4 6 1 9 1 5 620 <2247 4 6 1 1 2 0 7 1 0 1 9 1 6 745 <2280 5 4 1 5 2 9 5 8 1 2 2 3 2 1 639 3

161 2 8 5 4 <2 6 1 1 8 172 <2

172 3 0 1 1 1 3 4 8 1 4 1 2 538 <2157 3 9 9 1 7 4 9 1 5 1 7 133 <2365 9 4 1 7 5 5 6 3 2 4 4 4 8 0 104 7244 3 6 1 0 2 0 5 8 1 7 1 7 309 <2312 5 9 1 3 2 7 8 1 2 3 0 2 0 608 2

188 3 6 6 1 4 1 0 235 <2

172 3 1 7 1 3 1 0 208 <2

9 9 66 3 7

8 4 6

7 3 8

8 3 6
97

Ba ppm Ce ppm Co ppm Cr ppm Cu ppm Ga ppm La ppm Li ppm Mn ppm Mo ppm

187 4 1 1 0 1 7 6 8 1 7 1 3 334 <2153 2 6 8 1 6 1 9 8 1 2 1 2 219 <2

211 4 8 1 3 2 2 6 1 0 2 5 1 6 650 <2369 6 9 1 4 3 6 1 2 1 7 3 4 2 6 571 3148 3 7 1 0 7 3 8 1 5 1 0 409 <2166 3 8 9 1 7 3 8 1 5 1 3 357 <2193 4 1 1 0 9 4 8 1 6 1 4 461 <2

121 2 7 5 8 1 0 5 1 4 7 278 <2

318 5 4 1 3 3 8 1 3 1 4 2 8 2 8 376 3201 4 9 6 2 0 1 2 210 <2

119 2 6 5 7 <2 6 9 6 193 <2191 4 0 1 3 2 0 1 0 1 0 1 6 1 4 539 <2164 3 0 7 1 4 5 8 1 6 1 0 316 <2

214 4 5 1 1 2 1 2 3 1 0 2 0 1 9 527 <2395 6 2 1 5 4 8 7 6 2 0 3 2 3 7 463 4272 5 4 1 5 3 4 1 3 1 4 2 5 3 1 561 3234 4 3 1 2 2 2 5 1 0 1 9 1 6 809 <2190 3 7 9 1 0 4 8 1 7 1 3 251 <2152 3 7 8 1 6 3 9 1 8 1 1 321 <2

250 3 5 5 1 7 <2 1 0 1 4 1 2 8 7 <2

198 4 4 8 1 9 1 2 332 <2225 5 7 9 1 3 4 9 2 1 1 6 242 <2182 4 0 8 1 5 9 307 <2

116 4 1 4 2 <2 4 1 3 6 332 <2

142 3 2 4 2 <2 6 1 3 7 160 <2

155 3 5 7 1 2 9 215 <2

309 6 7 1 0 3 3 8 1 3 2 9 2 3 428 2209 5 5 1 4 8 4 1 0 2 1 1 6 601 <2408 7 9 1 3 4 2 1 1 1 8 3 6 3 5 553 3

9 4 97 3 9

5 3 7

5 4 7
98

Ba ppm Ce ppm Co ppm Cr ppm Cu ppm Ga ppm La ppm Li ppm Mn ppm Mo ppm

465 8 9 1 5 4 3 1 3 2 0 4 2 4 2 1060 4

163 3 7 4 1 1 <2 6 1 3 9 209 <2

244 5 0 9 1 3 5 9 2 3 1 8 401 2240 4 9 6 1 3 3 9 1 8 1 3 295 <2189 4 6 5 1 5 9 251 <2184 4 0 7 1 3 9 292 <2176 4 2 7 1 5 3 8 1 5 1 2 322 <2

122 3 1 4 4 <2 6 1 0 6 280 <2

303 5 5 9 2 6 6 1 1 2 9 2 6 316 <2

117 3 2 5 7 <2 5 1 0 9 309 <2145 4 0 4 5 <2 6 1 4 8 345 <2143 3 4 7 1 2 2 6 1 1 9 376 <2

268 5 2 1 4 1 2 4 9 2 1 1 5 811 <2174 3 8 8 1 5 1 5 319 <2

295 4 4 6 1 5 1 2 248 <2233 4 1 7 1 6 1 2 221 <2

190 3 2 5 <2 <2 6 1 1 8 166 <2

222 3 9 7 <2 <2 8 1 6 1 1 234 <2

384 9 9 9 2 3 5 1 3 4 3 2 5 468 2

249 4 4 8 1 9 1 2 274 <2269 5 7 7 3 4 1 1 2 2 1 3 220 <2

189 3 4 4 3 <2 6 1 2 8 150 <2223 2 9 5 3 <2 6 1 2 8 154 <2183 2 5 4 2 <2 6 1 1 7 161 <2

234 3 9 7 1 3 3 1 0 1 7 1 2 250 <2214 4 2 8 1 7 1 2 305 <2

175 2 6 4 2 <2 6 1 1 7 232 <2195 3 1 4 <2 <2 7 1 1 7 108 <2

272 4 0 6 1 4 1 1 193 <2

6 4 82 2 8

9 4 9

2 3 97 4 83 4 83 6 93 3 9
99

Ba ppm Ce ppm Co ppm Cr ppm Cu ppm Ga ppm La ppm Li ppm Mn ppm Mo ppm

199 3 2 4 3 <2 6 1 2 8 118 <2

213 3 9 5 1 7 1 1 191 <2

206 3 0 5 1 2 1 0 180 <2

241 4 8 1 0 1 0 7 1 0 2 0 1 9 336 <2

372 7 4 1 4 4 1 3 2 1 2 3 3 3 2 522 3

251 4 3 4 <2 <2 5 1 6 6 116 <2

359 179 6 2 4 5 1 0 8 2 1 7 219 <2

233 4 4 9 1 7 1 3 289 2235 5 3 6 6 4 1 1 2 0 1 6 150 <2

209 3 3 6 1 5 8 169 <2

236 3 4 6 1 0 <2 8 1 7 1 2 228 <2224 4 2 7 1 4 1 3 353 <2318 6 3 1 3 7 1 5 1 3 2 7 2 4 387 <2

329 8 9 7 9 4 1 1 3 8 1 7 279 <2

446 5 7 1 0 2 7 1 5 1 6 2 6 4 8 290 3

180 2 9 5 1 1 9 148 <2198 4 2 6 1 7 1 2 202 <2

292 5 0 1 2 1 5 9 1 2 2 3 2 3 538 3214 3 8 7 1 8 1 5 238 <2247 4 1 7 1 9 1 4 270 2238 3 8 6 1 6 1 2 233 2221 2 9 6 1 4 1 2 243 <2229 3 3 5 1 4 1 2 194 <2233 3 6 9 1 5 1 5 318 2235 3 6 6 1 6 1 5 263 <2249 4 0 9 9 6 1 0 1 8 1 7 388 <2243 4 0 1 0 2 1 3 1 0 2 0 1 7 443 3216 4 8 8 2 3 3 9 2 0 1 7 365 3238 3 6 8 2 3 4 1 0 1 9 1 9 463 4

3 7 84 2 95 6 8

5 2 73 3 83 5 5

5 4 76 7 76 4 65 3 8

4 3 66 3 75 4 8

4 5 9
100

Ba ppm Ce ppm Co ppm Cr ppm Cu ppm Ga ppm La ppm Li ppm Mn ppm Mo ppm

221 3 2 8 1 3 3 1 0 1 9 1 8 439 4183 2 7 5 8 <2 9 1 5 1 5 214 2223 2 9 7 2 0 5 9 1 9 1 8 359 3

1530 6 3 1 1 5 1 2 4 2 1 3 2 6 9 310 5

232 4 2 7 1 6 4 1 0 1 9 1 9 269 2221 3 7 6 1 1 <2 9 1 8 1 9 286 2224 3 9 6 1 0 3 8 1 9 1 6 213 2221 4 3 9 2 4 4 1 1 2 1 2 1 436 4229 4 8 1 1 2 8 5 1 1 2 1 2 3 479 4319 4 2 7 2 3 3 9 2 1 2 1 351 3188 4 3 6 2 2 <2 9 2 4 1 8 326 3280 2 7 1 1 1 0 3 1 0 2 1 2 1 486 3229 3 2 8 1 4 4 1 0 2 2 1 9 328 4180 2 2 5 8 <2 7 1 3 1 2 191 2367 4 1 8 2 1 4 1 2 2 5 2 1 419 3393 5 2 9 2 8 8 1 2 2 7 2 6 274 4242 3 0 6 2 5 5 1 0 1 7 2 7 220 3253 3 3 6 1 2 4 1 0 1 8 1 9 167 3257 2 7 6 1 4 <2 8 1 6 1 3 219 3209 2 4 5 9 <2 7 1 5 1 3 185 2265 4 3 8 1 3 4 1 0 2 6 1 7 299 3234 2 5 5 9 <2 8 1 6 1 4 226 3329 4 5 1 0 2 7 6 1 3 2 5 2 2 404 3219 2 5 5 6 <2 8 1 7 1 2 155 <2190 3 1 5 1 4 <2 7 1 8 1 3 248 <2

223 3 1 5 7 <2 7 1 2 1 0 218 <2193 2 6 4 <2 3 6 1 3 9 204 <2187 2 9 4 1 1 3 7 1 3 1 2 172 <2252 2 0 4 6 5 8 1 0 1 2 165 <2
101

Ba ppm Ce ppm Co ppm Cr ppm Cu ppm Ga ppm La ppm Li ppm Mn ppm Mo ppm

200 2 9 5 1 4 <2 7 1 5 1 2 146 <2243 3 4 5 8 <2 7 1 8 1 2 213 2

186 2 5 4 4 <2 7 1 3 1 1 173 <2

250 4 5 6 1 6 2 1 1 2 2 1 6 304 2343 4 4 8 2 9 7 1 3 2 1 2 3 254 3308 3 5 9 2 6 4 1 2 1 8 1 9 336 3

447 2 9 5 2 2 <2 6 1 5 1 2 244 2

228 3 0 5 1 3 3 8 1 7 1 6 232 2256 4 4 9 1 9 3 1 2 2 0 1 8 385 2437 3 8 1 1 4 1 <2 1 2 1 8 2 5 433 3

170 2 0 4 9 <2 6 1 4 1 0 161 2

292 5 0 9 1 8 3 1 1 2 4 2 0 343 3344 3 2 8 1 5 <2 8 1 7 1 4 424 <2288 3 2 1 2 2 7 5 1 0 1 8 2 7 491 4

1100 4 8 1 2 2 6 1 0 1 2 2 0 2 9 751 2

242 4 3 8 2 3 7 1 1 2 0 2 5 320 3164 3 1 5 6 <2 7 1 6 1 3 205 <2218 4 1 8 1 2 4 9 1 7 1 6 358 3

245 2 9 6 5 <2 7 1 4 1 1 256 2

231 2 0 4 6 <2 6 1 3 1 1 212 <2

145 7 3 2 <2 <4 8 7 162 <2

253 4 0 6 1 6 <2 8 2 0 1 6 307 3269 4 0 6 1 6 <2 8 1 4 1 4 214 2257 3 5 5 1 7 3 9 1 6 1 7 228 2211 3 4 5 1 0 <2 7 1 6 1 3 212 <2221 3 2 6 2 9 8 1 1 1 6 2 3 250 3277 5 9 8 2 1 3 1 0 3 0 1 9 393 2214 3 6 5 1 1 6 7 1 7 1 4 193 2372 3 9 7 1 9 5 1 0 2 0 1 8 223 3
102

Ba ppm Ce ppm Co ppm Cr ppm Cu ppm Ga ppm La ppm Li ppm Mn ppm Mo ppm

196 2 9 7 1 2 2 9 1 7 1 5 306 2245 3 5 5 1 9 2 0 9 1 7 1 7 191 2253 3 5 6 1 0 5 9 1 7 1 5 292 <2213 2 3 5 1 2 4 8 1 4 1 4 234 <2

175 2 1 5 1 6 2 7 1 3 1 2 224 2

184 2 6 5 1 5 1 2 190 <2

137 2 0 4 1 0 <2 5 1 0 1 0 151 <2164 4 1 4 1 3 <2 5 2 1 1 0 199 <2

230 4 8 4 1 8 1 0 152 <2286 4 3 1 2 4 7 6 1 1 2 1 1 9 683 3314 4 9 1 0 3 7 7 1 2 2 6 2 6 469 3248 4 4 5 8 <2 8 1 7 1 4 235 <2265 4 3 6 1 8 2 9 2 0 1 6 253 3392 6 4 1 7 3 6 7 1 7 2 9 3 1 1240 3295 3 9 5 2 1 3 1 2 2 1 2 0 157 3

180 2 3 4 7 <2 7 1 1 9 202 <2

254 3 2 5 1 7 <2 9 1 6 1 3 433 2

233 2 5 7 1 4 <2 9 1 4 1 5 340 2

368 4 8 9 3 0 8 1 3 2 2 2 9 324 3254 2 9 7 2 4 7 1 0 1 8 1 9 350 2214 4 2 7 2 3 2 1 0 1 7 1 6 290 3346 4 7 1 5 2 7 6 1 2 2 6 2 7 799 3230 4 1 7 2 1 8 9 1 8 1 8 298 2270 6 1 9 2 6 8 1 0 2 8 2 0 339 2194 4 0 6 2 6 5 7 1 8 1 5 208 2202 5 9 6 1 1 5 9 2 8 1 5 222 <2155 3 5 7 1 7 4 6 1 3 1 2 319 3185 3 4 3 1 7 1 1 170 <2

144 2 8 5 1 3 8 6 1 0 1 5 179 3

9 4 84 2 68 6 5
103

Ba ppm Ce ppm Co ppm Cr ppm Cu ppm Ga ppm La ppm Li ppm Mn ppm Mo ppm

160 5 3 4 2 4 1 1 231 <2

247 4 8 9 1 8 6 1 1 2 2 1 8 470 <2346 5 7 1 1 5 1 1 0 1 3 2 8 2 7 555 3258 5 7 7 1 7 7 9 2 3 1 7 307 <2742 6 7 9 4 0 9 1 5 3 1 3 0 290 3278 6 5 6 1 1 4 9 2 8 1 7 278 <2249 6 9 6 1 9 6 9 2 7 1 6 257 <2258 4 5 3 1 8 1 1 147 <2255 5 5 9 1 5 6 1 0 2 5 1 9 409 <2

9 2 4 0 4 5 <2 <4 1 2 1 0 276 <2

104 3 6 6 1 2 <2 6 1 1 1 5 224 <2189 4 8 1 2 1 7 4 1 0 1 9 3 6 351 <2206 5 4 2 4 3 0 6 8 2 0 3 3 871 <2132 4 6 8 2 2 3 6 1 6 2 6 244 <2150 3 9 9 2 9 <2 8 1 6 2 7 248 <2328 7 6 2 1 5 3 5 7 1 6 3 1 7 6 504 2449 9 0 3 8 6 0 1 7 2 0 3 7 102 1030 4485 8 1 4 2 7 7 3 0 2 2 3 7 5 4 1080 6 0143 4 2 8 1 1 4 6 1 5 2 4 228 <2

268 6 7 1 0 2 3 5 1 1 3 0 3 9 230 <2

399 115 8 1 8 4 7 5 2 2 4 9 4 6 1450 137475 117 103 7 2 7 0 2 1 5 4 6 3 1730 7 8377 7 5 1 1 7 5 2 9 2 3 3 7 4 2 144 125391 5 2 2 4 2 7 1 2 1 0 2 3 5 0 669 3436 8 2 1 1 9 2 3 3 2 7 4 2 3 0 133 215

388 7 8 6 7 0 2 5 1 8 3 8 3 1 8 1 8 6

338 7 8 3 6 6 4 2 4 1 7 3 2 5 0 969 3 6124 4 1 7 1 3 <2 5 1 5 1 9 281 <2138 3 8 8 2 3 3 7 1 4 3 0 272 <2

6 3 77 2 8
104

Ba ppm Ce ppm Co ppm Cr ppm Cu ppm Ga ppm La ppm Li ppm Mn ppm Mo ppm

211 4 7 1 0 3 1 3 1 0 2 3 3 6 309 <2

358 8 5 1 6 3 5 4 1 5 3 9 6 0 378 3

482 110 3 6 7 4 1 5 2 2 4 4 136 1090 5452 9 0 3 2 5 9 1 0 2 1 4 2 124 791 5

5 3 2 8 2 4 <2 5 7 9 145 <2

237 8 8 1 1 4 0 4 1 0 3 5 3 2 363 2

8 6 4 1 8 1 5 4 6 1 2 1 6 531 <2

5 2 1 7 <2 <2 <2 <4 4 4 116 <2

125 2 9 5 1 5 9 6 8 1 4 297 <2

247 5 4 7 3 5 1 2 9 2 4 2 8 395 2

7 6 4 2 5 9 <2 5 1 1 1 1 261 <2

176 5 8 1 1 3 0 3 7 2 5 2 8 321 <2

4 3 2 4 <2 2 <2 <4 6 4 123 <2

153 4 8 9 1 1 2 6 1 8 2 1 403 <2186 4 5 7 1 7 5 0 1 0 1 8 2 2 456 <2

317 9 2 1 2 5 7 1 1 1 6 3 9 4 4 425 3143 6 0 1 0 2 1 3 6 2 5 1 3 698 <2167 6 6 7 9 3 7 8 1 4 354 <2282 9 7 1 1 5 6 9 1 4 4 0 4 3 698 2

8 3 3 7 3 4 <2 4 3 7 125 <2

303 9 6 1 3 3 2 6 1 4 3 9 2 6 505 2384 9 8 1 6 5 0 1 5 1 7 4 3 4 0 591 3184 5 3 1 2 2 5 4 9 2 2 1 8 632 <2444 9 7 1 7 5 2 1 4 1 8 4 3 4 4 901 3

507 102 1 7 6 5 1 8 2 2 4 8 5 7 659 4

338 8 1 1 5 3 6 9 1 5 3 7 3 3 771 2323 7 1 1 3 3 8 7 1 3 3 3 2 8 569 2284 7 3 1 1 2 6 8 1 2 3 3 2 5 502 <2

418 102 2 8 5 7 2 1 1 8 4 4 6 0 1260 3

2 21 < 1
105

Ba ppm Ce ppm Co ppm Cr ppm Cu ppm Ga ppm La ppm Li ppm Mn ppm Mo ppm

284 7 9 1 2 3 3 8 1 1 3 4 2 6 506 <2339 8 9 1 4 3 6 1 1 1 4 4 0 3 3 533 2291 8 1 1 3 4 7 1 6 1 0 3 7 2 9 534 <2329 9 7 1 3 3 6 8 1 3 4 1 2 7 650 2285 6 8 1 1 8 5 7 1 1 3 3 2 4 577 3217 7 8 7 9 5 8 4 1 9 331 <2

335 7 7 1 3 4 4 9 3 7 5 1230 3

210 124 8 2 0 4 8 5 0 1 7 385 <2593 113 1 8 7 7 1 8 2 6 5 2 6 3 677 5

492 9 8 1 7 6 2 1 4 2 1 4 8 5 1 1190 3

322 8 2 1 4 4 0 8 1 2 3 8 2 9 820 <2260 6 5 1 0 2 9 6 9 2 9 2 3 683 <2301 7 9 1 2 3 2 8 1 1 3 5 2 8 719 <2

306 8 7 1 6 3 0 9 1 7 5 1400 2470 113 2 4 5 3 1 5 2 0 4 5 4 6 1630 3

344 9 0 1 6 5 5 1 0 1 3 3 7 2 9 774 2268 7 4 1 1 2 1 5 9 3 1 2 1 495 <2

314 7 4 1 6 4 5 8 0 5 1 1380 2

236 7 1 1 0 3 5 7 9 2 9 2 7 605 <2205 6 7 6 6 5 8 8 1 9 307 <2306 9 1 1 2 3 7 7 1 2 3 5 3 0 656 2226 6 2 7 3 4 8 5 2 4 345 <2

284 8 5 1 9 4 7 1 2 1 4 3 6 3 7 1110 2

187 6 0 6 9 5 8 4 1 7 587 <2105 4 2 4 1 2 5 7 1 0 254 <2161 5 0 6 6 9 8 0 1 6 230 <2145 6 4 3 2 8 4 6 2 9 1 1 7 8 <2237 8 8 7 6 6 8 9 2 2 434 <2148 6 5 5 7 <2 6 2 4 1 3 210 <2

2 3

1 3 3

1 3 21 3 3

2 23 22 22 11 23 32
106

Ba ppm Ce ppm Co ppm Cr ppm Cu ppm Ga ppm La ppm Li ppm Mn ppm Mo ppm

402 9 2 1 8 4 5 1 0 1 6 4 2 5 0 1100 4

7 7 1 7 3 1 7 <2 5 6 1 0 159 <2

129 2 7 6 3 4 5 4 1 9 392 <2133 4 2 4 <2 5 1 9 1 0 184 <2

112 4 2 7 1 3 <2 <4 1 7 9 839 <2

133 4 9 2 <2 5 2 2 149 <2173 3 1 4 3 2 6 5 9 154 <2

290 112 6 2 1 4 9 4 7 1 6 237 2

178 5 8 4 2 2 6 0 1 0 240 <2181 8 3 4 3 <2 6 3 0 8 157 <2157 6 8 2 <2 5 2 7 232 <2

150 4 0 4 9 <2 5 1 3 7 236 <2

185 8 5 5 3 6 9 180 <2196 115 5 4 7 1 1 266 <2321 8 4 2 1 5 3 6 4 0 4 1230 4

192 5 2 1 6 3 3 5 9 2 0 2 3 894 2

238 7 5 1 3 3 8 6 9 3 2 2 7 785 3

271 7 1 2 0 3 9 4 2 9 8 1360 3

215 7 0 7 2 3 7 1 1 5 376 <2194 4 9 7 7 3 7 8 1 4 346 <2182 3 9 6 5 2 6 0 1 4 234 <2

235 7 6 8 2 7 4 9 3 2 2 0 302 <2

183 5 5 7 5 3 8 2 1 6 332 <2174 4 8 7 9 3 8 7 1 5 291 <2186 4 7 7 1 4 7 7 1 5 281 <2248 6 4 1 0 3 5 6 9 2 7 2 5 737 2212 6 5 1 0 1 5 4 9 2 7 2 1 476 <2166 5 5 1 2 1 4 <2 5 2 5 1 5 527 <2

210 5 0 2 2 4 6 < 2 1 0 2 2 2 2 1260 3

2 1

87 6

1 11 21

9 7

7 2 59 3 8

1 3 41 2 2

2 31 11 21 21 12 1
Ba ppm Ce ppm Co ppm Cr ppm Cu ppm Ga ppm La ppm Li ppm Mn ppm Mo ppm 

 1 1 9 3 3 7 7 < 2 5 1 3 14 309 < 2  1 8 5 7 0 1 5 19 3 1 1 2 5 2 4 617 2  1 8 0 5 0 10 17 2 9 18 17 6 0 0 < 2 

 9 5 3 8 4 1 9 2 < 4 1 4 9 1 6 1 < 2 

 1 2 8 4 9 5 1 1 < 2 5 1 8 1 2 1 9 8 < 2 

 1 2 5 3 8 6 7 4 6 3 1 2 2 5 0 < 2  1 9 0 5 8 10 23 3 7 26 18 4 1 4 2  2 2 0 5 5 10 24 3 8 21 26 6 4 4 < 2 

 2 9 5 6 0 1 3 2 9 5 1 1 3 1 3 5 7 0 3 4 

 2 6 0 6 5 1 3 35 7 1 1 2 8 2 8 599 3  2 5 7 6 9 1 6 31 5 1 2 2 6 2 7 880 < 2  2 1 7 5 3 5 7 3 6 1 1 2 3 1 8 < 2 

 1 3 9 3 8 3 1 0 < 2 5 1 3 9 2 1 1 < 2 

 1 6 3 4 3 6 3 2 6 8 1 1 4 0 6 < 2 

 176 61 6 2 3 1 2 3 4 9 < 2 

 1 8 6 7 3 5 4 2 5 0 1 0 2 8 4 < 2  2 0 0 5 4 11 23 4 9 22 19 5 6 4 < 2  2 5 4 5 9 1 5 35 5 1 2 2 4 2 9 643 3  1 8 1 5 0 8 3 3 8 9 1 6 3 7 2 2  2 9 3 6 1 10 22 3 7 29 19 1 6 9 < 2 

 6 4 2 2 2 6 < 2 < 4 8 9 1 2 8 < 2  5 8 2 5 < 2 5 < 2 < 4 1 2 5 1 5 9 < 2 

 451 120 29 61 18 20 44 62 1650 4 

 1 2 7 2 6 8 9 < 2 5 1 2 13 467 < 2  510 100 2 1 7 1 1 6 2 9 4 8 104 677 6 

1 1 1 1 2 1 1 

9 2 7 

1 3 1 1 1 

107

108

Nd ppm Ni ppm Pb ppm Sc ppm Sr ppm Th ppm V ppm Y ppm Yb ppm Zn ppm

5 0 2 2 3 5 1 1 7 7 9 7 8 2 3 3 9 04 5 1 4 1 9 7 5 2 1 1 5 0 1 7 2 5 44 3 1 9 2 3 1 0 7 8 7 9 5 2 0 3 7 94 8 3 3 3 0 1 2 104 1 1 8 1 2 4 2 1033 2 1 3 1 7 1 0 6 1 9 6 4 1 9 2 4 83 1 1 1 2 0 6 4 3 <6 4 8 1 4 2 5 33 8 1 1 1 3 5 3 4 9 4 1 1 4 2 3 63 3 1 1 1 5 6 4 2 6 4 5 1 5 2 4 33 2 1 5 2 8 7 6 9 9 5 7 1 5 2 6 83 0 1 1 1 6 6 4 8 7 4 6 1 5 2 4 84 0 1 8 2 2 1 1 7 4 8 7 5 2 1 3 8 1

1 8 1 0 1 7 4 2 1 <6 2 9 1 4 1 3 3

2 7 1 3 2 1 6 3 5 <6 4 2 1 0 2 4 4

2 0 9 1 4 3 2 0 <6 2 5 9 1 2 9

3 2 1 2 2 0 7 5 3 7 5 3 1 8 2 5 32 9 2 0 2 3 9 6 5 <6 6 9 1 7 2 7 43 0 2 0 1 8 8 5 4 8 5 8 1 4 2 6 24 0 1 8 1 7 9 5 7 9 6 1 1 8 3 6 0

1 8 8 9 2 1 4 <6 1 7 6 <1 2 82 8 1 2 1 0 3 1 7 <6 2 2 8 1 5 0

2 9 1 4 1 7 7 4 7 <6 5 2 1 5 2 5 63 5 2 5 2 3 1 0 6 8 1 3 7 4 1 9 2 8 64 0 2 3 2 2 1 0 116 8 7 4 1 7 2 7 64 0 2 0 2 2 1 0 6 7 1 1 7 2 2 1 3 6 73 2 1 6 2 2 8 5 4 <6 6 0 1 6 2 6 04 2 1 7 1 8 1 0 6 5 1 1 7 2 1 9 3 6 53 2 1 1 2 5 7 4 6 9 5 1 1 5 2 4 74 2 1 9 2 0 9 5 5 1 3 7 1 1 9 3 7 12 7 1 6 2 1 9 5 3 1 0 6 5 1 7 2 7 4
109

Nd ppm Ni ppm Pb ppm Sc ppm Sr ppm Th ppm V ppm Y ppm Yb ppm Zn ppm

3 4 1 7 2 5 1 2 8 0 1 1 9 3 2 0 3 8 33 9 2 3 2 0 9 6 2 1 1 7 3 1 7 2 7 9

2 0 1 4 2 1 5 4 1 <6 4 2 1 0 2 6 5

2 7 1 2 1 6 5 4 2 <6 3 9 1 1 2 4 23 1 1 1 1 6 5 4 6 <6 3 8 1 6 2 3 83 5 1 4 2 0 6 5 3 <6 4 6 1 2 2 4 93 5 1 5 1 8 6 4 9 8 4 9 1 2 2 4 83 6 1 7 2 4 8 5 1 9 5 8 1 5 2 5 53 0 1 3 1 8 6 3 8 <6 4 2 1 1 2 4 7

2 9 8 1 1 3 3 1 <6 2 4 8 1 2 4

3 2 1 2 1 4 5 4 2 <6 4 1 1 0 2 3 9

2 4 8 1 0 4 2 8 <6 2 8 8 1 3 82 2 8 8 3 2 1 <6 2 0 5 <1 2 31 6 6 8 2 2 1 <6 1 9 5 <1 2 13 6 1 2 1 3 5 4 0 6 3 2 1 1 1 3 51 6 6 6 <2 1 7 7 1 5 4 <1 2 11 3 9 9 4 3 4 1 0 2 7 8 1 1501 8 1 5 1 3 5 3 9 1 2 3 9 1 0 1 3 81 2 1 0 1 2 4 3 8 1 1 3 1 8 1 3 62 3 1 0 1 1 4 4 3 1 0 3 2 9 1 3 8

5 1 2 9 2 4 1 5 103 1 8 109 2 2 3 8 0

<9 8 7 3 2 8 8 2 2 5 <1 2 5<9 7 8 3 3 5 8 2 2 6 <1 2 41 2 9 8 4 3 3 1 0 2 9 7 1 2 72 5 1 2 1 0 5 3 8 1 0 3 5 9 1 3 91 7 1 0 1 0 4 3 5 9 3 1 7 1 3 41 5 1 3 1 9 4 4 4 1 1 3 6 9 1 4 7

3 3 2 6 2 6 1 3 7 6 1 7 9 4 2 0 3 9 91 1 1 6 1 4 8 5 4 1 2 6 0 1 4 2 5 9
110

Nd ppm Ni ppm Pb ppm Sc ppm Sr ppm Th ppm V ppm Y ppm Yb ppm Zn ppm

1 6 1 1 1 8 7 5 0 1 2 5 2 1 2 2 5 4

1 2 5 1 0 3 2 2 <6 2 1 6 <1 2 1<9 5 1 0 3 3 3 1 1 2 6 7 <1 2 6

3 0 1 7 1 7 9 6 0 1 5 6 1 1 8 2 5 7

<9 1 1 1 2 5 4 3 1 0 3 8 9 1 3 91 0 8 9 3 105 <6 3 0 7 <1 2 91 3 8 8 3 3 3 1 0 2 2 6 <1 2 11 7 9 5 3 3 2 1 1 2 0 8 1 2 12 0 1 0 9 4 3 6 1 3 2 9 1 0 1 2 91 3 6 5 <2 2 2 6 1 4 4 <1 1 51 5 7 5 3 3 3 9 1 9 7 1 2 0

2 3 1 3 1 6 5 3 9 1 4 4 2 1 1 2 3 8

1 9 1 1 1 0 5 4 5 1 0 3 5 8 1 3 41 2 8 5 2 2 9 1 0 2 0 5 <1 2 0

1 6 1 5 1 8 7 5 9 1 2 5 1 1 2 2 6 4

1 3 8 1 0 3 3 3 8 2 1 6 <1 2 71 1 1 1 1 0 6 4 4 9 4 2 1 0 2 4 21 3 6 8 3 3 2 9 2 5 8 1 2 4<9 6 8 3 2 4 9 2 2 7 <1 2 31 6 6 9 3 2 9 8 2 4 6 <1 2 31 0 7 7 3 3 1 7 2 3 5 <1 2 21 7 9 1 1 4 3 2 9 3 4 7 1 3 1<9 7 5 2 2 5 6 2 0 5 <1 1 71 1 8 6 2 2 7 7 2 0 5 <1 2 31 3 8 8 3 3 3 1 0 2 5 6 1 6 3<9 8 9 3 2 9 7 2 2 5 <1 2 41 7 7 5 2 2 6 8 1 7 5 <1 1 83 7 7 5 2 2 9 1 0 1 7 9 1 1 6<9 6 <4 <2 2 0 <6 1 3 3 <1 1 4
111

Nd ppm Ni ppm Pb ppm Sc ppm Sr ppm Th ppm V ppm Y ppm Yb ppm Zn ppm

<9 1 0 7 4 3 4 9 2 8 6 1 2 81 1 8 5 2 2 7 8 1 5 5 <1 1 71 1 8 5 2 2 3 <6 2 0 5 <1 2 21 2 8 <4 <2 2 3 6 1 5 4 <1 1 72 2 1 7 8 3 3 2 9 2 6 8 1 3 71 6 1 0 9 3 2 7 7 2 4 5 <1 2 71 4 1 8 8 4 4 2 8 3 1 8 1 3 4

1 9 1 1 1 3 5 5 1 9 4 0 1 0 2 3 5

1 7 1 7 8 3 3 3 8 2 5 7 1 3 41 1 7 7 3 3 5 1 4 2 2 6 1 2 41 7 1 0 1 1 4 4 3 1 0 3 4 8 1 3 41 8 9 8 3 4 0 1 1 2 3 7 1 2 41 3 1 0 5 3 2 9 6 2 4 6 1 2 81 4 1 1 1 2 4 3 8 9 3 2 7 1 3 81 6 1 0 1 2 4 3 7 1 0 3 6 8 1 4 31 4 9 6 3 3 0 9 2 4 7 1 3 61 9 1 3 1 0 5 4 3 9 3 7 9 1 4 5<9 1 0 9 3 3 4 8 2 8 6 1 3 01 7 1 2 1 2 5 3 8 8 3 9 8 1 4 5

2 2 1 5 2 1 6 6 0 1 2 5 2 1 2 2 8 0

3 0 1 3 2 5 8 7 3 9 5 8 1 6 2 5 34 3 1 5 2 3 9 6 7 1 4 5 8 1 9 3 5 84 3 1 3 1 7 8 6 3 1 0 5 1 1 7 2 4 94 4 1 9 2 5 9 7 3 8 6 4 2 0 3 8 64 2 1 2 1 9 7 6 2 9 5 1 1 6 2 6 94 7 1 5 2 4 9 6 6 1 4 6 3 1 9 3 7 33 8 1 7 1 8 8 7 1 8 5 5 1 8 2 5 55 1 1 3 2 2 8 5 8 9 5 3 1 9 2 5 53 7 1 5 2 0 8 6 7 6 5 8 1 8 2 6 5
112

Nd ppm Ni ppm Pb ppm Sc ppm Sr ppm Th ppm V ppm Y ppm Yb ppm Zn ppm

4 4 1 8 2 1 1 0 7 0 1 1 6 7 2 0 3 6 74 4 1 4 1 9 7 6 2 1 4 5 2 1 8 2 6 04 6 1 3 1 6 7 5 9 1 0 5 0 1 7 2 4 84 4 1 7 2 0 8 7 1 1 2 5 9 1 9 2 5 93 4 1 6 1 8 7 6 8 8 5 8 1 5 2 6 14 2 2 0 2 0 1 1 7 6 9 7 5 1 9 3 6 64 8 2 0 2 7 1 1 7 6 1 5 7 6 1 9 3 8 14 9 1 3 2 1 8 7 0 1 0 5 7 2 1 3 6 33 7 1 5 2 8 7 7 5 <6 4 7 1 4 2 5 04 9 1 8 1 6 8 6 3 1 3 5 7 1 8 3 5 54 5 2 1 2 6 8 5 8 9 5 7 1 5 2 5 65 3 2 0 2 0 8 6 0 1 3 5 9 1 7 2 6 05 2 1 3 1 9 7 5 9 1 0 4 7 1 5 2 5 15 0 1 6 2 0 8 6 4 8 5 4 1 6 2 5 54 6 2 3 3 0 1 2 7 7 1 3 8 0 2 0 3 1053 8 1 8 3 1 9 7 1 9 6 2 1 6 2 7 24 6 1 7 2 0 8 8 2 9 5 9 2 0 2 5 94 5 2 0 1 9 9 7 4 1 0 6 2 1 8 3 6 04 2 2 1 1 8 9 6 0 8 6 0 1 9 2 5 85 3 1 7 2 6 7 5 2 1 1 5 4 1 7 2 4 74 5 1 7 4 2 8 5 7 8 5 2 1 7 2 6 84 9 1 9 1 6 7 5 2 1 0 4 7 1 6 2 4 64 8 1 9 1 9 9 6 4 8 6 6 1 6 2 6 03 0 1 8 2 1 7 5 7 6 5 3 1 5 2 5 34 0 1 0 1 1 5 3 5 1 0 3 4 1 2 2 2 75 2 1 5 1 5 7 5 8 1 1 4 8 1 6 2 4 53 4 1 6 1 8 8 6 3 8 5 6 1 4 2 5 9

2 2 1 1 9 5 5 0 1 3 3 6 1 0 2 3 5
113

Nd ppm Ni ppm Pb ppm Sc ppm Sr ppm Th ppm V ppm Y ppm Yb ppm Zn ppm

2 0 1 3 1 3 6 5 3 1 3 4 6 1 2 2 4 42 4 1 5 1 2 6 5 4 1 8 4 4 1 3 2 4 34 1 1 3 1 3 5 5 1 1 5 4 4 1 2 2 3 82 0 1 4 1 8 6 5 7 1 4 4 8 1 2 2 5 03 0 1 7 1 7 7 6 6 1 5 5 5 1 4 2 5 63 0 1 4 1 6 6 5 5 1 3 4 9 1 3 2 4 93 4 1 8 2 9 8 7 6 1 8 5 9 1 5 2 7 82 9 1 4 1 4 6 6 7 1 2 4 7 1 2 2 5 03 3 1 7 1 9 9 6 9 1 5 6 7 1 5 2 6 13 3 1 7 1 8 8 6 7 1 5 6 0 1 5 2 5 73 2 1 4 2 3 6 6 3 1 3 4 9 1 3 2 5 12 9 1 4 1 5 7 6 3 1 5 5 4 1 4 2 4 52 5 1 4 2 6 6 6 1 1 4 4 7 1 2 2 6 82 7 1 3 1 4 5 5 2 1 7 4 4 1 3 2 4 53 4 1 1 1 4 6 5 0 1 4 4 4 1 3 2 4 33 3 1 1 1 4 6 5 3 1 4 4 5 1 3 2 4 35 1 1 6 1 5 7 5 0 2 0 5 1 1 9 3 5 53 8 1 5 1 7 6 5 0 1 5 5 1 1 3 2 5 43 1 2 5 1 5 9 5 2 1 6 6 8 1 5 2 4 93 1 2 9 1 5 8 5 0 1 4 6 3 1 4 2 5 5

2 9 2 5 1 7 7 4 6 1 4 5 9 1 1 2 5 0

2 7 2 2 1 3 7 3 5 1 1 5 1 1 2 2 4 43 1 1 4 1 1 5 3 7 1 6 3 6 1 1 2 3 33 1 1 8 1 3 5 4 3 1 3 4 4 1 2 2 4 23 2 1 8 1 9 5 8 9 1 2 4 7 1 2 2 4 33 7 3 7 1 8 9 6 3 1 5 7 3 1 7 3 7 3

3 3 1 3 1 0 4 6 6 9 3 4 1 0 1 4 0

3 6 1 9 1 8 8 6 5 1 6 6 5 1 4 2 6 42 6 2 0 1 6 7 5 9 1 5 5 8 1 2 2 5 4
114

Nd ppm Ni ppm Pb ppm Sc ppm Sr ppm Th ppm V ppm Y ppm Yb ppm Zn ppm

4 6 1 6 1 5 7 6 3 1 8 5 3 1 5 2 6 03 6 1 5 1 5 6 5 5 1 2 4 5 1 2 2 5 53 1 2 5 2 7 1 0 6 7 1 3 8 0 1 4 2 5 33 3 1 6 1 1 5 3 9 1 2 4 1 1 1 2 4 32 5 2 0 1 1 5 3 9 8 4 0 1 2 2 4 52 4 2 3 1 7 7 5 0 1 3 5 7 1 3 2 6 42 7 2 0 1 2 5 3 6 1 2 4 3 1 2 2 4 52 7 1 7 1 2 7 4 5 1 5 5 4 1 5 2 4 8

2 1 1 3 1 1 4 3 1 1 0 3 1 9 1 2 9

1 8 1 5 8 4 3 0 1 2 3 2 1 0 2 2 9

2 8 1 3 7 4 3 0 1 2 2 9 1 0 2 3 0

4 2 2 2 1 8 8 6 2 9 6 5 1 3 2 7 64 2 1 1 1 7 7 5 7 1 6 5 1 1 7 3 5 62 0 1 1 1 6 6 5 2 9 4 5 1 1 2 4 94 0 1 1 1 5 7 5 6 1 0 5 0 1 5 2 5 8

2 6 3 2 2 5 9 4 3 6 101 1 1 2 8 2

1 6 2 5 2 0 6 4 0 9 7 8 1 1 1 7 92 1 1 7 1 5 4 2 6 <6 4 7 8 1 4 82 2 1 3 3 3 4 2 2 <6 3 8 8 1 3 51 2 9 7 2 1 4 <6 2 1 6 <1 2 5

2 4 4 8 1 9 7 4 4 9 112 1 7 2 1382 4 3 8 1 9 8 4 5 1 3 8 4 1 5 2 130

3 9 6 7 2 8 8 6 2 1 1 105 2 6 2 136

3 4 2 1 1 5 5 3 5 1 1 6 4 9 2 5 3

1 9 2 2 3 6 6 4 2 6 7 2 1 1 2 6 4

2 2 1 5 1 3 5 3 6 <6 4 9 8 1 4 61 5 1 8 1 6 4 4 1 <6 5 4 8 1 5 82 4 1 6 1 5 5 3 9 7 5 5 9 1 4 91 7 1 3 1 3 4 2 1 <6 4 4 7 1 4 2
115

Nd ppm Ni ppm Pb ppm Sc ppm Sr ppm Th ppm V ppm Y ppm Yb ppm Zn ppm

<9 5 6 <2 1 9 <6 1 6 4 <1 1 5

1 8 1 0 1 2 4 3 9 <6 2 8 6 1 3 21 1 9 1 3 4 4 0 <6 3 2 7 1 4 81 6 7 8 3 3 5 <6 2 5 6 1 3 01 4 9 1 2 4 3 8 <6 3 3 8 1 4 02 1 1 1 1 5 4 8 7 <6 3 6 8 1 3 93 0 8 1 2 3 4 0 <6 2 3 9 2 2 81 3 9 1 6 3 4 3 <6 2 7 6 <1 4 4

2 8 1 0 1 5 5 5 2 7 3 6 9 1 3 8

2 2 6 1 2 3 4 8 <6 2 4 6 <1 3 01 7 7 1 0 3 3 6 <6 2 4 5 <1 3 12 4 1 0 1 2 4 4 7 <6 3 1 8 1 3 41 4 8 1 2 4 5 0 <6 2 8 8 1 3 13 0 1 2 2 0 6 4 7 8 4 4 1 1 2 4 21 6 1 1 1 6 4 4 5 <6 3 7 6 1 2 21 8 7 1 1 3 4 2 <6 2 4 8 1 3 3<9 5 1 2 3 4 2 <6 2 4 6 <1 2 92 0 9 1 5 4 4 5 <6 3 4 8 1 4 42 3 9 1 4 4 5 2 <6 3 0 7 1 3 81 3 7 8 3 3 9 <6 2 1 5 <1 2 21 8 1 1 1 3 3 4 7 <6 2 5 6 1 4 32 7 1 2 1 6 6 5 0 <6 4 7 8 1 5 52 0 1 0 1 4 4 4 6 <6 3 6 7 1 5 31 3 1 1 1 5 4 4 2 <6 3 5 7 1 4 93 1 7 1 3 3 5 9 <6 2 7 7 1 2 83 7 6 3 2 3 3 7 <6 2 0 8 1 4 92 2 8 1 4 4 4 6 <6 3 0 7 1 3 3

2 3 1 0 1 8 5 6 8 1 4 4 1 1 3 2 4 4

2 3 5 1 0 3 3 9 <6 2 1 7 1 2 5
116

Nd ppm Ni ppm Pb ppm Sc ppm Sr ppm Th ppm V ppm Y ppm Yb ppm Zn ppm

2 2 9 1 3 4 4 3 6 3 2 8 1 3 42 3 8 1 2 4 4 4 <6 2 8 7 1 3 7

3 8 1 6 2 0 8 7 5 1 0 4 9 1 4 2 5 3

1 6 9 3 2 4 4 7 <6 3 1 7 1 8 81 3 6 1 2 3 4 5 <6 2 6 6 1 2 92 1 8 1 3 4 5 6 <6 3 0 9 1 3 5

3 5 1 9 1 8 5 7 3 1 5 3 9 1 4 2 4 2

1 9 7 1 0 3 3 9 <6 2 2 6 <1 3 62 5 6 1 3 3 5 1 <6 2 5 6 <1 2 42 5 <3 7 <2 3 9 <6 1 4 3 <1 1 21 7 5 1 6 3 4 4 <6 2 0 5 <1 2 71 8 <3 8 <2 3 6 <6 1 6 4 <1 1 71 5 8 1 0 3 3 7 <6 2 8 6 <1 3 01 1 7 1 5 5 5 2 6 3 8 7 1 3 81 3 7 2 0 5 6 0 7 3 5 9 1 3 6

1 2 9 1 6 4 6 6 <6 3 4 8 1 3 6

<9 5 1 4 4 5 1 6 2 8 8 1 3 4<9 5 1 5 3 4 9 <6 2 5 6 <1 3 3<9 6 1 7 3 5 3 <6 2 4 6 <1 3 5<9 7 1 3 4 4 8 <6 3 1 8 1 3 7

3 7 1 5 1 9 7 8 3 1 7 4 9 1 7 2 5 3

2 2 9 1 7 5 5 1 <6 3 9 9 1 4 21 0 6 1 3 3 4 3 <6 2 6 6 <1 3 21 0 3 1 2 2 8 0 <6 2 0 5 <1 2 4<9 <3 1 3 3 3 6 <6 3 1 5 <1 2 61 8 6 2 6 4 5 3 1 1 2 8 9 1 3 01 7 8 1 2 4 3 5 7 3 1 9 1 2 8

4 8 1 5 1 8 7 5 1 2 0 5 1 1 7 2 3 9

<9 3 9 3 4 2 <6 2 2 6 <1 2 3
117

Nd ppm Ni ppm Pb ppm Sc ppm Sr ppm Th ppm V ppm Y ppm Yb ppm Zn ppm

<9 6 1 1 3 3 9 <6 2 3 5 <1 2 51 8 6 1 2 3 3 4 <6 2 2 8 1 2 71 6 6 9 2 3 2 <6 1 8 5 <1 1 82 8 1 1 1 5 5 4 7 <6 4 1 8 1 3 91 4 9 1 6 5 4 7 8 3 6 7 1 3 8

1 3 1 1 1 8 5 6 6 1 0 4 0 8 1 3 8

1 6 9 1 7 4 5 0 <6 3 1 6 1 4 9<9 7 1 1 3 3 3 8 2 5 6 <1 2 3<9 7 1 2 3 4 9 7 2 4 5 <1 3 51 0 9 1 4 3 4 1 8 2 4 5 <1 2 9

1 9 1 8 2 0 9 8 0 1 1 6 6 1 0 2 5 6

<9 1 7 8 1 6 5 2 8 4 6 8 1 4 51 1 1 0 1 3 4 7 3 8 3 1 8 1 3 2

1 6 1 7 2 0 8 6 8 9 5 7 1 2 2 5 11 1 1 4 1 8 6 5 4 1 0 4 8 1 0 2 4 7

1 6 9 1 7 4 6 2 8 3 3 7 1 3 4<9 1 0 1 4 4 5 1 8 3 3 8 1 3 2<9 7 1 0 3 3 3 <6 2 2 5 <1 2 6

1 9 2 0 1 9 6 5 6 9 4 4 1 0 2 5 4

2 1 2 2 2 2 4 5 4 8 3 0 7 1 7 1

2 0 1 5 1 6 7 6 3 1 4 5 5 1 0 2 3 8

<9 6 1 2 2 2 6 <6 1 8 4 <1 2 5<9 <3 1 1 <2 2 5 <6 1 4 4 <1 1 4<9 4 1 4 2 2 9 <6 1 8 5 <1 2 0<9 5 8 <2 2 4 7 1 2 3 <1 1 31 3 4 9 2 3 0 7 1 7 6 <1 1 7<9 7 1 3 3 5 8 8 2 8 6 <1 3 0<9 7 1 1 3 3 1 <6 2 4 5 <1 2 5
118

Nd ppm Ni ppm Pb ppm Sc ppm Sr ppm Th ppm V ppm Y ppm Yb ppm Zn ppm

3 0 2 2 2 5 9 6 6 1 4 7 1 1 4 2 6 5

3 0 1 9 2 8 5 6 2 7 3 8 1 0 2 5 11 6 1 2 1 4 5 3 8 9 4 0 9 1 2 63 3 1 9 1 8 9 6 9 1 3 6 6 1 5 3 6 0

2 8 3 0 103 3 4 9 9 2 4 8 1 146

3 4 2 3 2 4 1 0 7 6 1 7 7 6 1 6 3 7 2

1 0 9 1 2 3 1 8 7 2 2 7 1 2 7

1 9 1 2 4 6 3 2 8 9 2 6 8 1 6 4

1 4 1 4 2 2 4 2 7 7 2 8 7 1 2 3<9 1 0 1 2 <2 1 3 6 1 5 5 <1 2 1

3 0 1 5 1 9 7 7 6 1 3 5 3 1 4 2 5 42 6 1 7 3 5 8 7 6 1 9 5 8 1 7 2 6 43 7 2 1 3 8 9 8 7 1 6 7 1 1 4 2 6 42 0 1 5 2 7 6 124 9 5 0 1 2 2 5 0

2 8 1 0 1 5 5 6 4 9 3 8 9 1 3 81 2 1 2 1 3 4 3 1 8 3 7 8 1 4 1

2 0 1 8 1 7 7 4 9 1 3 5 6 1 3 2 5 62 3 1 9 1 6 7 4 5 1 2 5 0 1 1 2 4 51 1 1 2 1 3 4 3 3 9 3 2 8 1 2 93 3 1 1 1 8 6 4 8 1 5 4 1 1 3 2 4 0

1 8 5 1 1 2 3 1 8 1 7 7 1 1 7

3 3 1 4 1 6 7 7 2 1 2 5 1 1 2 2 4 02 7 2 0 1 7 8 6 8 1 4 6 2 1 4 2 6 03 2 2 7 2 0 9 8 1 1 3 7 0 1 3 2 6 31 7 1 8 3 2 7 8 9 1 1 5 5 1 2 2 5 32 3 1 7 1 8 7 6 2 1 3 5 2 1 3 2 4 93 1 2 3 2 1 1 0 7 2 1 5 7 3 1 6 3 6 83 2 1 7 2 2 8 7 4 1 5 6 2 1 5 2 5 83 0 1 7 2 4 7 7 9 1 6 5 4 1 4 2 5 8
119

Nd ppm Ni ppm Pb ppm Sc ppm Sr ppm Th ppm V ppm Y ppm Yb ppm Zn ppm

3 0 2 4 3 3 5 166 9 4 6 1 2 1 6 92 2 3 6 651 8 6 5 1 4 5 4 1 3 2 6 71 2 1 5 2 3 8 7 3 1 6 6 4 1 4 2 5 81 6 2 3 2 5 6 8 0 9 4 7 1 3 2 6 92 1 1 4 1 9 7 7 2 1 3 5 1 1 2 2 5 03 6 1 2 2 5 6 6 1 1 5 4 6 1 6 2 4 62 4 1 6 2 2 7 7 7 8 5 5 1 3 2 6 52 8 1 5 1 5 7 5 4 1 2 5 0 1 2 2 5 72 5 1 8 4 0 8 7 0 1 3 6 3 1 5 2 5 72 8 2 3 2 2 1 1 8 8 1 4 8 6 1 6 2 7 51 7 9 1 0 5 3 8 1 1 3 7 1 1 2 3 41 9 1 2 1 2 5 4 8 1 3 4 4 9 2 4 22 1 1 3 1 5 6 5 6 1 1 4 0 1 2 2 3 4

1 9 2 0 1 5 5 4 3 8 5 0 1 0 1 6 0<9 1 5 7 2 1 4 <6 1 7 4 <1 2 3<9 2 3 1 5 4 1 9 <6 3 3 6 1 3 6<9 1 0 9 <2 1 2 <6 1 6 4 <1 1 41 0 7 5 <2 9 <6 9 2 <1 1 0<9 1 4 8 <2 1 2 <6 1 6 4 <1 1 8<9 1 6 5 <2 1 1 <6 1 3 4 <1 2 0<9 1 6 9 <2 1 3 <6 1 6 4 <1 2 5

1 7 1 6 1 0 <2 1 3 <6 1 6 5 <1 3 9

<9 1 1 1 3 <2 1 1 <6 1 4 4 <1 1 7

1 6 3 9 3 0 1 0 4 4 1 2 8 6 1 3 2 7 01 4 3 4 2 7 8 4 0 1 3 7 8 1 1 1 7 52 8 4 5 3 3 1 0 4 7 1 3 8 3 1 5 2 129

2 8 2 1 1 1 3 2 1 7 2 7 7 <1 7 1

1 8 2 2 1 5 4 3 8 9 4 0 8 1 4 6<9 5 5 <2 8 <6 1 0 <2 <1 9
120

Nd ppm Ni ppm Pb ppm Sc ppm Sr ppm Th ppm V ppm Y ppm Yb ppm Zn ppm

<9 1 1 5 <2 1 1 <6 1 4 3 <1 1 4<9 1 8 1 0 2 1 3 <6 2 1 4 <1 2 5<9 6 6 <2 1 2 <6 1 0 3 <1 1 0

3 2 9 5 <2 1 1 <6 1 2 4 <1 2 2

<9 8 6 <2 1 4 <6 9 2 <1 1 0

9 2 0 1 4 3 1 9 8 2 8 6 1 2 9

<9 1 8 9 3 1 5 <6 2 3 4 <1 1 8<9 2 6 1 1 3 2 2 <6 3 4 6 1 4 11 1 1 8 1 7 5 2 3 <6 6 5 8 1 5 8

1 8 7 6 <2 1 1 <6 1 7 3 <1 2 1

1 1 3 0 2 8 6 3 8 1 3 5 8 1 0 1 6 5

1 5 3 1 2 7 8 4 4 1 0 6 9 1 2 2 5 91 4 5 2 2 3 1 0 5 1 1 2 7 8 1 5 2 8 3

1 4 1 0 1 4 4 2 6 1 1 4 0 8 1 2 71 1 2 6 2 6 6 3 3 9 6 3 1 1 1 4 81 0 1 4 1 2 5 2 4 9 3 6 9 1 2 1<9 1 1 1 2 4 2 3 1 0 3 1 6 1 3 1<9 1 8 8 <2 1 7 <6 1 7 4 <1 2 9<9 8 5 <2 1 0 <6 1 3 3 <1 1 5<9 3 4 8 2 1 3 6 2 0 9 <1 4 21 0 2 5 2 6 5 4 4 9 4 5 9 1 5 0

2 3 9 1 5 <2 1 5 <6 1 5 4 <1 3 9

<9 1 1 1 7 3 1 5 7 3 5 8 1 3 0<9 2 0 1 9 5 3 2 7 4 6 1 0 2 3 9

1 4 1 1 1 0 3 2 0 9 2 3 1 0 1 1 8

1 8 1 9 1 6 5 3 0 8 3 8 1 5 2 3 52 2 1 9 2 0 5 3 7 9 4 6 1 5 2 4 3

2 6 1 5 8 3 1 9 <6 2 8 9 1 3 2
121

Nd ppm Ni ppm Pb ppm Sc ppm Sr ppm Th ppm V ppm Y ppm Yb ppm Zn ppm

2 2 1 0 8 4 2 2 <6 2 8 8 1 3 03 7 1 0 1 1 4 2 7 1 1 2 9 1 2 2 2 43 6 1 0 1 0 4 2 9 1 1 3 2 1 4 2 2 71 9 1 3 1 1 4 2 5 <6 3 7 9 2 3 11 6 1 4 1 2 4 2 4 <6 3 7 8 1 3 32 4 1 0 1 1 3 2 0 <6 2 5 7 1 2 22 6 1 7 1 2 4 2 3 7 3 6 8 1 3 7

3 2 2 0 1 7 8 4 0 <6 5 8 1 1 2 5 02 8 1 8 1 1 5 3 1 7 3 8 1 0 2 3 82 8 2 4 1 5 5 2 9 1 3 4 1 1 3 2 3 93 8 1 7 1 1 6 3 6 7 4 3 1 1 2 4 0

4 0 1 4 1 4 5 3 1 1 2 3 6 1 3 2 3 42 7 1 0 9 4 2 3 <6 2 9 8 1 2 2

2 7 1 1 1 1 4 3 1 7 3 3 1 0 2 2 6

3 1 7 8 <2 1 2 7 1 2 6 <1 2 4

3 5 7 8 2 1 7 1 0 2 2 9 1 3 35 2 7 5 <2 1 1 1 9 1 2 9 <1 2 9

127 7 8 3 1 7 4 7 2 1 2 3 2 3 0

3 2 1 2 1 5 3 2 5 1 2 2 2 1 0 1 4 45 3 9 6 <2 1 1 1 0 1 2 8 <1 2 54 7 1 3 1 1 <2 1 5 1 4 1 4 1 0 <1 5 1

4 4 6 1 5 4 5 1 2 0 2 6 1 6 2 2 1

1 2 7 1 1 4 3 2 <6 3 6 8 1 3 11 5 6 1 0 3 3 3 <6 2 6 7 1 2 52 0 1 3 1 3 5 3 6 <6 3 7 8 1 4 43 6 6 1 1 4 4 4 8 3 2 9 1 3 32 4 7 1 2 4 4 0 6 3 1 8 1 3 11 8 8 1 1 4 3 8 9 2 9 9 1 3 01 5 5 7 2 2 1 <6 1 7 5 <1 2 0
122

Nd ppm Ni ppm Pb ppm Sc ppm Sr ppm Th ppm V ppm Y ppm Yb ppm Zn ppm

2 8 8 1 3 5 4 0 9 3 6 8 1 3 7

2 1 1 3 1 6 7 5 8 <6 5 6 1 3 2 5 8

2 3 8 1 0 4 4 4 <6 2 9 7 1 3 02 3 9 1 2 4 4 1 <6 3 0 7 1 3 0

2 4 1 5 1 7 7 5 2 9 5 5 1 1 2 5 63 2 9 1 6 5 5 1 7 3 6 1 0 2 3 7

2 3 9 7 4 3 7 <6 3 0 7 1 2 92 1 6 9 3 2 7 <6 2 0 5 <1 2 33 1 6 9 3 3 5 7 2 1 8 1 2 21 8 5 7 <2 2 6 <6 1 3 4 <1 1 62 7 7 9 3 3 7 <6 2 5 7 1 2 42 8 1 0 8 3 3 4 <6 2 5 6 1 2 51 5 7 1 2 3 2 4 <6 2 1 5 <1 2 22 2 1 1 1 5 6 4 6 9 4 6 9 2 4 5

3 4 1 9 1 8 7 5 3 9 5 6 1 1 2 5 42 9 1 7 1 5 5 4 3 <6 4 4 8 1 4 73 0 1 5 1 6 7 5 1 7 5 5 9 2 5 3

2 8 1 0 1 3 5 3 7 <6 3 8 7 1 3 62 8 1 1 1 5 7 4 6 <6 5 4 1 2 2 6 12 0 1 0 1 3 5 4 0 <6 4 5 8 2 1001 8 1 3 1 4 4 3 7 <6 3 5 7 1 3 72 1 6 9 2 2 9 <6 1 8 5 <1 1 91 5 1 2 1 0 4 3 6 <6 3 3 6 1 3 32 9 6 8 2 2 6 <6 1 9 4 <1 2 22 0 1 0 1 2 5 4 9 <6 3 6 9 2 3 02 9 1 0 1 1 4 4 6 <6 3 2 7 1 3 01 6 5 7 2 2 7 <6 1 8 5 <1 1 9

2 9 1 3 1 4 6 4 9 8 4 9 9 2 4 6

2 2 8 8 3 3 2 <6 2 3 6 1 2 4
123

Nd ppm Ni ppm Pb ppm Sc ppm Sr ppm Th ppm V ppm Y ppm Yb ppm Zn ppm

2 0 9 1 1 4 3 5 <6 3 0 6 1 3 22 0 1 0 1 2 4 3 8 <6 3 2 7 1 3 31 7 8 8 4 3 4 <6 2 8 7 1 2 61 8 7 1 0 3 3 2 <6 2 3 5 <1 2 41 9 1 0 1 0 4 6 3 <6 3 3 7 1 3 81 9 9 1 1 4 5 8 <6 3 0 6 1 4 22 3 9 1 3 4 4 8 <6 3 4 6 1 3 61 2 7 8 3 3 5 <6 2 7 5 1 2 92 7 8 1 1 4 3 8 <6 3 0 6 1 3 72 2 9 1 1 4 4 2 <6 3 1 6 1 3 52 2 8 1 0 4 3 4 <6 3 0 5 1 2 92 2 8 1 0 3 4 5 <6 2 2 5 <1 2 72 2 7 9 3 3 1 <6 2 6 5 <1 2 31 7 5 5 <2 2 1 <6 1 4 4 <1 1 91 4 4 1 0 2 3 0 <6 1 9 5 <1 2 22 3 3 7 <2 2 7 <6 1 7 4 <1 1 72 0 6 1 0 2 2 8 <6 1 7 4 <1 1 91 3 6 8 3 2 8 <6 2 5 6 <1 2 61 1 <3 4 <2 1 7 <6 1 0 3 <1 1 21 8 5 7 <2 2 2 <6 1 4 4 <1 1 71 2 5 9 2 2 9 <6 2 1 4 <1 2 22 2 6 9 2 2 9 <6 2 0 5 <1 2 51 0 <3 7 <2 3 1 <6 1 5 4 <1 1 61 4 3 6 <2 1 9 <6 1 2 3 <1 1 61 2 3 5 <2 1 9 <6 1 2 3 <1 1 22 2 5 7 2 3 2 <6 1 8 5 <1 1 8

3 1 2 0 2 3 9 6 5 1 1 6 8 1 5 2 6 82 8 3 0 3 2 1 3 9 2 1 5 9 6 2 2 2 9 91 4 1 2 2 2 7 6 3 1 0 5 1 1 4 2 5 2
124

Nd ppm Ni ppm Pb ppm Sc ppm Sr ppm Th ppm V ppm Y ppm Yb ppm Zn ppm

2 2 1 1 2 2 6 5 5 <6 5 1 1 3 2 5 22 1 1 6 2 1 1 1 7 3 1 4 7 5 1 7 2 6 51 5 9 2 2 7 6 3 1 2 5 5 1 6 2 5 65 5 4 4 2 5 2 0 102 1 6 125 3 4 4 148

1 7 6 1 7 4 4 9 1 3 3 5 1 1 1 3 5

3 7 2 4 3 1 1 5 110 1 1 110 2 1 2 1003 1 1 4 2 3 1 0 7 1 1 5 7 4 1 8 3 7 13 7 2 2 2 7 1 2 8 9 1 8 9 0 1 9 3 9 03 7 1 0 1 7 6 4 8 1 0 4 4 1 4 2 4 92 9 1 2 1 9 6 5 3 1 4 4 6 1 5 2 5 82 8 1 5 2 2 8 5 9 6 6 0 1 4 2 6 32 6 1 3 1 6 7 5 6 1 5 5 4 1 4 2 5 13 4 1 7 2 7 9 6 8 1 1 7 1 1 7 3 7 52 1 1 4 2 3 8 6 4 8 5 7 1 6 2 6 4

2 3 5 1 3 4 4 2 1 0 3 1 1 1 2 3 2

5 8 1 5 2 0 7 5 8 1 7 5 4 2 1 3 5 63 1 7 1 9 6 5 0 1 5 4 7 1 7 2 4 22 2 1 1 1 9 6 5 0 1 0 4 3 1 2 2 5 93 5 1 4 2 7 8 6 1 1 5 6 1 1 5 2 7 64 8 2 3 2 0 8 6 7 1 8 6 2 1 8 3 7 32 3 1 8 2 9 8 8 5 1 2 6 3 1 6 2 7 63 7 3 0 2 7 1 3 8 6 1 4 9 8 1 9 2 8 03 1 1 7 2 4 6 7 0 9 5 0 1 3 2 5 8

2 6 1 7 1 7 6 5 2 1 0 4 8 1 3 2 4 8

2 0 1 5 1 5 5 5 1 1 2 4 0 1 4 2 4 92 9 1 5 1 6 8 6 4 1 3 5 8 1 5 2 5 91 8 1 5 2 0 9 6 8 1 0 6 8 1 7 2 6 02 1 1 9 2 0 1 0 7 5 1 1 6 9 1 8 2 6 83 8 1 7 2 4 9 8 1 1 0 6 5 1 6 2 7 4
125

Nd ppm Ni ppm Pb ppm Sc ppm Sr ppm Th ppm V ppm Y ppm Yb ppm Zn ppm

2 5 1 7 2 0 9 7 1 8 6 5 1 7 3 6 4

2 1 1 5 8 3 1 9 <6 2 2 7 <1 2 82 8 9 5 3 1 5 1 0 2 0 6 1 1 31 9 9 1 2 4 3 9 1 1 3 0 9 1 2 1

4 9 3 4 2 9 1 0 6 2 9 6 7 1 8 2 7 42 3 1 1 8 4 2 4 1 0 2 9 9 1 2 03 3 5 2 2 3 1 4 6 8 1 5 9 7 1 9 3 1002 2 1 7 1 7 6 3 3 8 4 7 1 1 2 4 23 7 1 7 1 9 8 4 9 1 5 6 3 1 6 2 4 35 3 1 5 1 5 7 5 3 1 3 5 1 1 3 2 5 13 9 2 3 2 6 1 0 7 4 1 2 7 3 1 5 2 7 43 8 1 2 1 9 6 5 4 1 7 4 3 1 3 2 4 02 9 2 3 2 4 1 1 8 0 1 8 7 9 1 8 3 7 23 7 9 1 3 5 3 8 1 2 3 8 1 4 2 3 53 7 3 1 3 2 1 3 7 9 1 1 101 1 8 2 8 53 0 1 6 1 3 7 4 0 1 2 5 2 1 3 2 4 03 1 2 2 2 4 8 5 0 1 4 6 6 1 4 2 5 33 7 2 4 2 2 1 4 6 7 1 5 101 1 7 3 7 42 3 2 4 1 5 6 3 4 8 4 6 1 2 2 4 31 7 1 6 1 9 7 6 0 9 5 4 1 1 2 3 62 7 1 6 4 7 6 4 0 1 0 4 7 1 1 2 4 33 4 3 3 2 3 8 4 7 1 1 6 3 1 4 2 6 41 5 1 2 1 6 5 2 9 1 0 3 9 9 1 3 52 5 1 5 1 6 6 4 1 1 2 5 0 1 1 2 4 1

1 9 9 9 3 1 9 7 2 0 7 1 2 11 8 1 3 181 3 120 <6 3 4 9 1 7 5

3 5 2 1 2 0 9 5 1 1 4 6 9 1 2 2 4 83 6 1 6 1 4 7 4 0 1 4 5 6 1 1 2 3 15 2 4 9 2 7 1 7 109 1 7 118 2 4 3 6 9
126

Nd ppm Ni ppm Pb ppm Sc ppm Sr ppm Th ppm V ppm Y ppm Yb ppm Zn ppm

1 9 1 3 1 8 5 3 5 1 2 4 5 1 0 1 3 7

3 1 1 8 3 5 6 4 9 9 4 3 1 0 1 5 7

2 3 1 7 2 0 5 3 5 1 0 4 2 1 1 2 3 83 7 1 6 2 3 7 6 9 1 1 5 6 1 4 2 4 43 2 1 4 1 5 8 4 9 1 3 6 1 1 3 2 4 34 9 4 1 2 2 1 6 7 2 1 9 114 2 3 3 8 22 4 3 1 2 3 1 0 5 1 1 4 7 1 1 6 2 6 33 4 2 6 1 7 9 5 2 1 2 6 7 1 6 2 5 73 8 2 6 2 3 8 5 1 1 6 6 1 1 4 2 5 74 9 2 6 2 5 9 5 6 1 4 7 1 1 6 2 6 03 4 4 4 2 4 1 4 6 9 1 9 110 1 9 3 7 9

3 9 2 0 1 5 1 1 5 9 1 5 7 7 1 7 3 5 64 6 1 5 1 8 8 6 3 1 9 5 8 1 8 3 5 17 8 1 1 1 6 5 5 2 2 9 2 8 2 1 3 2 8

1 4 1 3 1 8 5 3 3 1 1 5 1 9 <1 5 0

3 1 3 2 2 9 1 2 6 2 1 2 9 9 1 5 2 8 53 9 3 1 3 2 1 2 6 7 1 5 9 6 1 5 2 9 62 5 1 8 1 6 7 4 5 1 0 5 7 1 0 2 6 0

3 2 2 1 2 0 7 4 3 7 6 1 1 0 1 6 13 2 2 8 3 2 8 5 6 1 0 6 9 1 2 2 6 53 7 1 6 1 8 6 5 3 <6 5 1 9 2 5 11 7 1 5 1 7 5 4 2 <6 4 5 8 2 5 32 1 1 7 277 6 5 0 <6 4 8 1 0 2 6 5

2 0 9 9 2 2 5 <6 2 3 5 <1 2 4

2 5 1 6 1 0 4 2 2 <6 3 3 7 1 3 02 3 9 9 3 3 1 <6 2 5 6 1 3 02 1 8 1 1 3 1 9 <6 2 8 5 1 3 63 7 1 5 1 5 4 3 7 6 4 2 8 2 4 01 6 9 8 3 2 0 <6 2 8 5 1 2 5
127

Nd ppm Ni ppm Pb ppm Sc ppm Sr ppm Th ppm V ppm Y ppm Yb ppm Zn ppm

6 3 3 1 7 5 116 <6 4 4 9 2 4 0

2 9 2 9 2 5 9 4 7 1 1 7 8 1 5 2 7 1

1 4 1 4 1 5 5 3 3 <6 4 4 9 1 4 81 7 1 5 1 6 6 3 4 <6 4 8 1 0 2 5 32 2 2 8 1 9 8 3 9 6 6 4 1 3 2 5 9

2 9 3 8 2 5 8 3 8 1 1 7 1 1 8 2 6 62 6 3 5 3 3 9 9 0 8 8 0 1 5 2 6 62 3 2 5 2 6 7 3 3 9 6 7 1 2 2 5 52 1 3 1 3 1 9 4 6 7 8 0 1 4 2 7 6

2 3 4 4 2 8 9 4 2 1 0 7 9 1 5 2 7 32 5 4 3 2 3 9 3 9 1 1 7 8 1 6 2 7 2

3 0 4 4 2 6 1 2 5 6 1 6 9 4 1 9 2 7 63 1 2 5 2 8 1 1 5 4 1 4 7 8 1 7 2 5 22 0 5 2 3 2 1 1 5 2 1 1 9 8 1 7 2 9 3

1 3 3 <4 <2 7 <6 5 <2 <1 4

2 9 1 0 1 7 7 4 1 1 1 6 1 1 2 1 4 01 6 1 2 9 4 4 6 <6 3 0 7 <1 2 4

<9 3 <4 <2 2 3 <6 1 0 3 <1 9<9 4 <4 <2 2 2 <6 1 0 3 <1 9<9 <3 <4 <2 4 0 <6 5 2 <1 5<9 <3 <4 <2 1 4 <6 4 <2 <1 6<9 <3 <4 <2 6 <6 5 <2 <1 8<9 4 <4 <2 1 3 <6 6 <2 <1 8<9 5 5 <2 1 5 <6 1 1 3 <1 1 0

1 3 3 9 2 5 9 3 8 7 7 8 1 5 2 7 3

1 9 1 6 1 6 3 4 5 <6 2 7 6 1 2 8

<9 3 5 3 9 7 6 2 1 1 6 5 1 3 1 100

<9 6 <4 <2 9 <6 8 3 <1 1 2

2 0 2 0 1 8 6 4 2 <6 4 3 1 1 2 4 7
128

Nd ppm Ni ppm Pb ppm Sc ppm Sr ppm Th ppm V ppm Y ppm Yb ppm Zn ppm

3 1 2 0 1 7 8 7 0 9 6 5 1 6 2 6 5

<9 4 <4 <2 1 4 <6 9 3 <1 9

2 3 1 5 1 5 4 2 6 8 4 0 8 1 3 7

<9 6 4 <2 1 0 <6 1 1 3 <1 1 0

1 6 1 7 1 6 6 4 2 1 0 5 0 9 2 5 12 8 1 5 2 8 6 3 4 7 7 5 1 3 1 4 3

1 2 4 <4 <2 5 8 <6 1 2 3 <1 1 0

1 4 2 2 1 3 4 2 1 <6 3 8 8 1 3 8

3 4 4 8 3 0 1 3 7 4 1 6 100 2 4 3 8 0

3 4 1 8 1 4 6 5 3 7 5 1 1 4 2 6 0

3 1 1 7 2 1 5 5 3 8 3 6 1 3 2 5 3

3 1 9 1 6 5 5 7 1 1 3 6 1 2 2 3 63 2 2 3 2 0 9 8 8 1 2 6 5 1 6 2 1226 1 9 1 7 6 5 6 2 1 4 3 2 0 3 4 14 4 1 6 2 2 9 8 0 1 6 6 4 1 8 3 6 86 4 1 0 1 5 6 5 4 2 3 4 5 1 9 2 4 02 7 1 0 1 6 6 5 4 1 4 4 8 1 3 2 3 52 2 9 1 6 5 4 7 8 3 6 1 1 2 3 52 0 1 1 2 1 7 7 7 1 0 5 3 1 6 2 5 83 5 1 4 1 7 7 5 5 1 1 5 4 1 5 2 5 33 0 1 0 1 7 6 5 6 1 3 4 8 1 4 2 4 83 7 1 9 1 7 7 5 5 1 0 5 7 1 5 2 6 1

2 2 1 1 1 6 5 4 0 1 0 4 0 1 1 2 4 1

2 6 1 8 1 3 5 4 0 1 1 4 0 1 2 2 5 23 0 1 4 1 3 6 4 3 1 1 4 8 1 6 2 4 7

2 5 6 9 3 3 5 6 2 4 1 0 1 2 7

2 9 8 1 5 4 4 2 9 3 4 1 2 2 3 4

4 1 1 0 1 5 5 4 8 1 1 3 8 1 2 2 4 2

3 1 1 0 1 8 5 5 1 6 4 0 1 2 2 4 2
129

Nd ppm Ni ppm Pb ppm Sc ppm Sr ppm Th ppm V ppm Y ppm Yb ppm Zn ppm

1 9 8 1 5 4 7 1 9 3 4 1 3 2 3 43 1 1 1 1 3 6 5 0 8 4 1 1 2 2 3 8

2 3 8 1 1 3 3 6 <6 2 7 8 1 2 9

4 2 9 1 3 5 4 8 1 5 3 9 1 8 3 3 73 4 1 0 1 7 6 4 7 9 4 7 1 3 2 4 24 4 1 1 1 5 6 6 3 1 3 4 7 1 5 2 4 63 4 1 2 1 3 5 4 7 <6 3 9 1 1 1 3 7

ins ins ins ins ins ins ins ins ins ins

3 0 1 0 1 6 6 4 4 1 0 4 3 1 2 2 3 7

3 8 9 1 4 5 4 2 1 2 3 9 1 3 2 3 3

2 9 8 1 4 4 3 8 6 3 0 1 2 2 3 1

2 5 8 1 3 4 4 1 9 3 3 1 1 2 3 6

3 0 1 6 1 6 7 5 4 1 5 5 2 1 3 2 5 9

1 8 9 1 2 4 2 6 <6 3 4 7 1 2 7

3 7 2 0 1 5 7 6 4 8 5 5 1 6 2 8 3

3 6 1 2 1 7 5 5 8 1 1 4 0 1 3 2 4 94 5 1 0 1 5 5 5 3 1 0 3 5 1 4 2 4 1

3 6 2 1 3 5 8 125 1 3 6 1 1 8 2 6 34 8 1 4 2 2 7 6 6 1 5 5 2 1 7 3 4 84 6 1 5 1 6 7 6 6 1 6 5 1 1 9 3 4 54 4 1 9 2 2 9 7 2 1 1 6 8 1 8 3 6 83 8 3 3 3 2 9 8 2 1 4 6 9 1 5 2 9 42 7 2 3 2 4 8 8 2 1 1 6 0 1 4 2 9 14 7 2 0 4 0 9 108 1 6 6 6 1 5 2 1003 5 1 5 1 5 8 7 8 1 2 5 7 1 2 2 6 23 0 1 7 2 0 9 8 6 1 4 6 6 1 6 2 5 92 7 1 1 1 6 5 6 7 1 4 3 7 1 0 2 4 24 7 2 1 1 8 1 2 7 8 1 5 7 7 1 9 3 7 24 0 1 8 7 4 8 102 1 3 5 7 1 4 2 120
130

Nd ppm Ni ppm Pb ppm Sc ppm Sr ppm Th ppm V ppm Y ppm Yb ppm Zn ppm

3 7 1 6 2 1 7 7 7 1 1 5 1 1 4 2 5 43 2 1 3 1 9 7 104 1 3 5 6 1 4 2 5 23 2 1 9 1 7 8 7 4 1 2 6 3 1 6 2 6 23 3 2 3 2 6 1 2 107 1 7 8 7 1 8 3 9 35 1 2 5 2 6 9 8 5 2 0 6 9 2 1 3 9 24 8 1 7 1 9 8 7 9 1 9 5 8 1 9 3 6 64 2 2 3 2 5 1 2 8 9 1 9 8 2 1 9 3 1064 5 1 6 1 6 8 9 0 1 4 5 7 1 5 2 5 53 4 1 6 1 9 7 7 7 1 2 5 6 1 4 2 5 74 0 1 6 1 6 6 160 1 4 4 3 1 3 2 4 73 9 2 0 1 8 1 0 8 8 1 3 7 0 1 8 2 6 53 8 2 3 3 0 1 2 107 1 8 8 6 1 8 3 9 83 6 1 8 2 2 9 7 9 1 0 6 7 1 5 2 6 1

5 5 1 0 1 6 5 4 6 2 5 3 4 1 8 2 3 9

4 5 1 7 2 2 8 8 4 1 6 5 9 1 6 2 6 54 6 2 0 2 0 1 0 8 4 2 0 7 2 1 7 2 6 33 9 1 7 1 6 8 7 2 1 2 5 7 1 4 2 6 24 0 1 5 1 4 7 6 4 1 2 5 0 1 1 2 4 82 7 1 6 1 6 6 6 4 1 6 4 4 1 3 2 4 33 9 1 7 1 7 9 7 2 1 6 6 7 1 5 2 5 83 9 1 0 1 4 5 4 2 1 0 3 9 1 1 2 3 33 5 1 5 1 7 7 6 2 1 1 5 1 1 4 2 4 84 0 2 4 2 1 9 6 5 1 4 6 8 1 5 2 7 13 2 1 8 1 5 7 7 1 1 1 5 0 1 2 2 5 86 0 1 8 1 9 8 7 9 1 6 6 2 1 8 3 1065 7 1 6 2 7 7 5 9 1 7 5 1 1 7 2 5 24 1 2 4 2 6 1 0 8 9 1 4 7 2 1 7 3 7 83 4 1 5 1 5 5 4 4 1 3 3 6 1 2 2 4 6

2 6 1 1 4 7 4 3 8 1 0 2 8 1 0 1 6 1
131

Nd ppm Ni ppm Pb ppm Sc ppm Sr ppm Th ppm V ppm Y ppm Yb ppm Zn ppm

3 6 1 2 1 3 5 5 1 1 1 3 5 1 0 2 4 03 3 1 4 1 4 6 4 7 1 1 4 2 1 3 2 4 94 5 1 8 1 8 7 5 7 1 2 5 4 1 6 2 5 7

6 0 1 1 1 5 5 5 3 1 8 3 7 1 5 2 4 1

3 5 1 5 3 6 7 4 7 8 4 8 1 3 2 5 44 4 1 8 1 9 9 5 7 1 8 6 4 1 6 2 6 9

2 7 1 1 1 4 4 4 9 9 3 4 1 2 2 3 6

2 6 6 1 1 3 5 5 8 9 3 6 1 2 2 3 53 3 1 2 2 1 6 6 4 1 3 4 6 1 6 2 4 92 8 1 2 1 6 5 7 1 1 1 3 9 1 5 2 3 93 8 1 0 1 3 4 6 3 1 3 3 1 1 3 2 3 23 5 1 6 1 5 6 5 6 1 2 4 5 1 4 2 4 83 6 2 3 1 9 1 0 6 6 1 3 7 4 1 7 3 6 75 8 1 4 1 5 6 5 6 1 6 3 9 1 8 3 4 45 1 9 1 2 4 4 1 1 4 2 9 1 7 2 3 0

3 0 7 5 2 2 3 <6 1 7 8 1 1 8

5 3 2 2 1 9 9 5 5 1 5 6 9 1 8 3 6 75 7 1 8 1 6 7 5 5 1 7 5 2 1 9 3 4 7

3 3 1 0 9 3 3 8 8 2 3 7 1 2 6

5 8 2 5 2 0 1 1 6 6 1 7 7 8 1 8 3 7 2

152 1 8 1 6 7 5 7 5 2 4 4 4 9 7 5 0

4 9 1 4 1 5 7 5 7 1 3 4 9 1 6 2 4 34 7 2 1 2 1 1 0 7 2 1 6 7 4 1 8 3 7 44 5 1 3 1 5 6 5 2 1 5 4 7 1 4 2 4 74 5 1 7 1 5 5 5 7 1 0 3 8 1 3 2 4 94 5 1 8 1 4 8 5 8 1 0 5 5 1 5 2 5 05 3 2 1 2 0 1 0 9 5 1 6 7 2 1 7 3 7 64 8 2 1 1 8 1 7 7 7 1 8 116 1 9 3 5 86 2 2 3 1 7 1 0 6 9 1 5 7 6 1 9 3 6 7
132

Nd ppm Ni ppm Pb ppm Sc ppm Sr ppm Th ppm V ppm Y ppm Yb ppm Zn ppm

3 3 1 3 9 4 3 5 1 0 2 9 1 0 1 3 4

6 8 1 4 1 5 7 6 4 1 9 5 4 2 3 3 6 17 0 2 5 1 7 9 7 1 1 5 6 8 2 0 3 7 15 1 1 7 1 6 6 5 8 1 3 4 2 1 4 2 3 94 4 1 6 1 9 7 6 1 1 4 5 1 1 4 2 4 7

4 4 8 8 3 2 8 1 3 2 2 1 3 2 2 84 0 1 2 1 0 4 3 5 8 3 1 1 0 1 3 35 0 8 9 3 3 1 1 3 2 4 1 3 2 2 5

4 4 1 1 1 1 5 5 0 1 4 3 7 1 3 2 4 05 0 1 2 1 5 5 5 7 1 7 4 0 1 5 2 4 04 0 1 8 2 0 9 7 0 2 2 6 8 1 9 3 6 84 6 1 7 1 4 6 5 8 1 3 4 6 1 4 2 5 15 2 1 5 1 6 9 6 4 1 3 6 1 1 8 2 5 64 0 2 0 1 7 9 6 4 1 3 6 4 1 6 2 5 59 7 1 3 1 7 7 5 6 2 8 4 9 2 4 3 4 65 1 1 3 1 8 7 6 9 1 9 5 3 1 7 2 4 43 7 1 9 1 9 9 6 8 2 0 6 5 1 9 3 7 58 6 6 1 5 4 5 5 3 1 2 9 2 5 3 4 35 3 1 0 1 4 6 5 6 2 0 4 0 1 9 2 4 86 3 1 3 2 7 7 5 9 1 6 5 0 1 8 3 6 96 1 2 2 1 5 6 5 1 1 5 4 5 1 6 2 6 83 4 5 1 9 4 4 8 1 7 3 1 1 5 2 5 64 3 1 2 1 7 8 6 2 1 6 5 3 2 0 3 5 43 8 1 2 1 9 8 6 6 1 5 5 7 1 9 3 4 18 2 8 1 4 6 5 0 2 6 3 6 2 9 4 3 24 6 1 2 1 8 7 6 6 1 8 5 2 1 6 2 5 44 9 1 5 1 7 8 6 4 2 2 5 6 2 1 3 5 76 4 1 0 1 6 6 5 4 2 3 4 4 2 0 3 4 24 5 1 1 1 4 7 6 1 1 4 5 3 1 9 3 4 9
133

Nd ppm Ni ppm Pb ppm Sc ppm Sr ppm Th ppm V ppm Y ppm Yb ppm Zn ppm

1 6 1 2 1 1 5 4 3 7 3 7 8 1 3 8

5 9 1 5 2 0 1 0 7 1 1 8 7 0 2 1 3 6 9

2 0 9 9 3 3 1 <6 2 4 6 <1 2 4

3 6 9 1 6 6 5 7 1 7 4 2 1 6 2 4 0

1 1 1 1 1 3 4 3 2 6 3 2 8 1 3 4

7 4 1 7 1 8 8 5 4 1 8 5 4 1 9 3 5 3

3 9 1 1 1 1 3 3 1 8 2 2 6 <1 3 4

2 4 1 3 1 8 6 6 0 1 2 4 7 1 4 2 5 1

<9 9 1 5 4 3 9 1 0 3 1 8 1 3 0

2 4 1 1 1 2 5 5 2 1 2 4 1 1 3 2 3 7

1 7 9 8 3 3 4 8 2 3 7 <1 2 3

5 0 1 5 1 4 7 5 7 2 3 4 7 1 9 3 6 4

2 3 8 1 4 3 2 9 1 0 2 5 1 0 1 2 7

4 7 1 3 1 5 6 5 2 2 1 4 6 1 9 3 4 8

1 9 7 5 <2 2 0 <6 1 1 3 <1 1 31 3 6 <4 <2 1 4 <6 8 2 <1 82 2 5 5 <2 1 5 <6 1 1 3 <1 1 42 0 7 5 <2 2 0 7 1 4 5 <1 1 42 1 5 7 <2 1 8 <6 1 2 4 <1 1 44 4 1 4 1 2 5 3 5 <6 3 6 8 1 4 01 3 4 8 <2 2 2 <6 1 3 4 <1 1 71 0 <3 7 <2 2 2 <6 9 4 <1 1 1<9 <3 8 <2 2 0 <6 8 3 <1 1 0<9 <3 7 <2 2 2 7 1 2 3 <1 1 31 4 3 9 <2 1 9 6 1 4 3 <1 1 91 1 4 7 2 2 3 <6 1 6 5 <1 2 0<9 <3 8 <2 1 7 <6 1 0 3 <1 1 3<9 3 5 <2 1 7 <6 9 3 <1 1 2<9 3 8 <2 2 8 <6 1 1 3 <1 1 3
134

Nd ppm Ni ppm Pb ppm Sc ppm Sr ppm Th ppm V ppm Y ppm Yb ppm Zn ppm

7 1 9 1 6 6 6 1 2 6 4 1 2 3 3 3 8

<9 <3 5 <2 2 1 <6 9 3 <1 1 11 4 9 8 <2 2 0 <6 1 5 5 <1 2 41 5 4 8 <2 2 6 8 1 2 3 <1 1 3

2 4 5 1 7 4 6 2 2 1 3 1 1 5 2 3 1

1 0 5 5 <2 1 9 <6 1 1 3 <1 1 1<9 <3 8 <2 2 3 7 1 6 3 <1 1 6<9 <3 8 <2 1 9 <6 9 3 <1 1 1<9 <3 <4 <2 1 5 <6 9 2 <1 1 01 7 4 5 <2 2 0 <6 1 1 3 <1 2 31 6 4 9 <2 2 3 <6 1 3 4 <1 2 82 4 5 9 <2 2 5 <6 1 5 4 <1 1 41 9 5 6 <2 2 5 <6 1 0 4 <1 1 11 4 5 7 <2 2 1 <6 1 1 3 <1 1 2<9 4 5 <2 2 3 <6 1 0 3 <1 1 11 6 8 7 <2 1 9 <6 1 1 4 <1 1 72 0 8 8 3 2 4 <6 2 1 4 <1 1 81 8 5 1 0 2 3 2 6 1 8 6 <1 1 6

1 9 5 1 7 5 5 5 1 2 3 7 1 3 2 3 3

1 5 6 7 <2 2 6 <6 1 5 4 <1 1 91 9 5 7 <2 2 6 <6 1 4 4 <1 1 3<9 <3 9 <2 2 0 <6 1 1 4 <1 1 3<9 <3 8 <2 2 5 <6 1 4 4 <1 1 51 7 1 0 1 5 5 4 8 <6 4 1 9 1 4 1<9 <3 1 0 <2 2 4 <6 1 3 3 <1 1 4<9 7 1 7 4 3 2 <6 3 2 5 <1 2 92 1 9 1 0 3 3 3 6 2 5 6 <1 2 6<9 <3 8 <2 2 4 <6 1 4 4 <1 1 6<9 4 6 <2 2 2 <6 1 2 3 <1 1 3
135

Nd ppm Ni ppm Pb ppm Sc ppm Sr ppm Th ppm V ppm Y ppm Yb ppm Zn ppm

1 5 5 6 <2 2 4 <6 1 5 5 <1 1 6<9 <3 6 <2 2 0 8 9 3 <1 1 1<9 <3 7 <2 2 1 6 1 2 4 <1 1 3

2 4 4 1 1 4 4 5 9 3 0 1 2 2 2 5

9 <3 1 1 2 3 9 <6 1 9 7 1 1 9

<9 5 7 <2 3 0 6 1 7 5 <1 1 6<9 4 7 <2 1 9 <6 1 0 3 <1 1 1<9 <3 7 <2 2 8 <6 1 2 4 <1 1 5

4 6 9 1 5 5 6 5 2 1 3 7 1 5 2 3 5

<9 <3 1 0 <2 2 5 <6 1 4 4 <1 1 6<9 <3 1 0 <2 2 9 <6 1 5 4 <1 1 5<9 <3 8 <2 3 1 8 1 6 5 <1 1 6<9 <3 9 <2 2 3 <6 1 4 3 <1 1 3<9 <3 1 2 2 3 2 <6 2 1 5 <1 2 0<9 <3 7 <2 2 2 <6 1 4 4 <1 1 21 6 <3 7 <2 2 8 <6 1 4 5 <1 1 3<9 5 8 2 2 9 <6 1 7 5 <1 1 6<9 <3 9 <2 2 6 <6 1 2 4 <1 1 21 2 <3 8 <2 2 2 <6 1 0 3 <1 1 02 9 1 0 1 0 <2 3 1 7 1 8 7 <1 1 81 4 3 5 <2 1 8 <6 1 0 3 <1 1 0

2 6 1 2 8 3 1 8 7 2 8 1 0 2 2 6

2 6 3 7 1 4 7 4 0 1 1 5 3 1 3 2 6 71 1 1 7 1 7 6 3 4 1 3 7 0 1 2 2 5 61 6 3 1 1 8 1 2 5 0 1 9 117 1 4 3 9 22 5 1 8 1 3 6 3 2 1 1 6 9 1 2 2 5 11 5 2 6 1 6 7 3 3 1 0 6 4 1 2 2 5 22 0 2 5 1 7 8 4 5 1 5 101 1 3 2 7 92 0 3 7 3 4 1 0 5 3 1 5 124 1 5 2 103
136

Nd ppm Ni ppm Pb ppm Sc ppm Sr ppm Th ppm V ppm Y ppm Yb ppm Zn ppm

3 2 2 0 1 1 5 2 7 8 5 7 1 0 2 5 2

3 9 2 5 1 2 5 4 7 9 5 0 1 1 2 5 1

4 2 2 6 1 5 7 3 4 1 3 7 8 1 2 2 6 2

3 2 1 0 1 2 4 4 1 1 3 3 1 1 6 2 2 4

<9 7 4 <2 1 1 <6 1 3 4 <1 1 31 6 1 2 1 4 5 3 9 6 4 2 1 0 2 3 91 6 1 6 1 5 5 3 4 9 4 4 9 1 3 6

3 1 1 7 1 5 6 4 7 1 4 4 7 1 3 2 3 7

1 1 9 1 1 3 2 2 8 2 3 6 1 2 0<9 1 0 1 2 4 3 2 <6 3 1 7 1 3 1

1 7 1 4 1 5 6 4 9 1 2 4 3 1 5 2 3 8

1 1 1 0 1 1 3 3 0 6 2 8 7 1 2 6

2 5 1 3 1 5 6 5 0 1 2 4 2 1 6 2 3 6

9 1 0 1 1 4 3 2 7 3 4 8 1 3 4

1 8 1 0 9 4 2 5 9 2 8 7 1 2 71 1 5 6 <2 2 5 <6 1 2 5 <1 1 31 6 8 8 3 3 5 7 2 3 6 <1 2 4<9 1 6 1 4 5 3 2 8 4 0 1 0 1 4 2

2 7 2 4 2 5 1 1 6 1 1 5 8 2 1 9 3 7 2

4 1 2 6 2 3 1 2 6 8 1 6 8 3 2 0 3 7 3

1 7 2 0 1 8 7 4 2 1 0 6 0 1 2 2 5 81 2 1 2 1 5 4 2 9 8 3 7 8 1 3 9<9 1 1 1 1 4 3 0 <6 3 3 7 1 3 13 9 2 9 2 6 9 6 2 1 1 7 8 1 3 2 105

<9 1 3 1 5 4 9 7 7 3 7 9 1 4 0

1 8 2 7 1 9 9 6 7 1 1 7 1 1 4 2 6 7

1 2 1 2 1 3 5 3 7 7 3 8 9 2 4 11 7 1 8 1 7 6 4 5 8 5 0 1 0 2 7 22 0 8 7 3 3 0 7 2 3 7 <1 2 3
137

Nd ppm Ni ppm Pb ppm Sc ppm Sr ppm Th ppm V ppm Y ppm Yb ppm Zn ppm

2 9 2 3 2 2 1 0 6 4 1 3 7 5 1 3 2 7 2

<9 8 1 4 3 3 9 <6 2 4 6 <1 3 61 6 1 0 1 0 4 3 2 6 3 2 7 1 3 71 2 8 1 1 3 3 5 9 2 9 8 1 3 82 5 1 3 1 1 5 3 6 8 3 8 9 1 4 41 3 1 4 1 5 6 4 0 <6 4 7 9 2 5 5<9 1 3 1 7 4 2 8 9 3 3 8 1 3 4

3 4 1 3 1 5 5 3 8 1 2 3 7 1 3 2 3 5

1 1 2 2 2 0 6 4 1 1 3 6 0 1 2 1 6 82 1 3 1 2 1 9 5 4 1 4 6 9 1 4 2 7 42 0 3 0 2 1 8 4 7 1 0 6 6 1 3 2 6 21 6 1 4 1 1 4 2 4 8 3 3 8 1 3 11 1 1 6 1 6 6 3 1 8 5 4 1 0 2 4 3

3 6 1 2 1 3 5 3 3 9 3 8 1 0 2 3 2

1 7 1 4 1 6 6 4 7 1 1 4 9 1 1 2 4 3

1 2 7 7 2 2 4 <6 2 0 5 <1 2 42 3 8 1 1 4 3 4 1 0 2 8 1 0 2 2 81 0 9 9 3 2 8 7 2 7 6 <1 2 8

<9 1 0 1 4 6 4 0 1 0 4 7 9 2 3 5

<9 2 2 1 9 7 5 0 1 4 6 1 1 1 1 6 7<9 1 2 1 0 4 3 4 6 3 5 7 1 3 71 9 9 1 0 3 3 1 6 2 5 7 1 2 3

3 5 1 1 1 3 5 4 5 9 4 1 1 2 2 3 7

1 9 2 2 1 8 6 4 4 1 1 5 2 1 1 2 4 1

1 0 1 6 1 6 5 120 1 1 4 5 1 0 1 4 41 8 8 7 2 2 7 <6 1 9 5 <1 2 3

3 0 3 6 2 1 1 0 5 0 1 2 7 3 1 5 2 6 7

2 6 2 5 2 3 9 5 2 1 1 7 1 1 2 2 6 9

4 2 4 2 5 4 1 3 6 4 1 6 9 8 1 9 2 7 7
138

Nd ppm Ni ppm Pb ppm Sc ppm Sr ppm Th ppm V ppm Y ppm Yb ppm Zn ppm

3 8 1 5 3 7 6 2 9 <6 4 0 9 1 3 3

3 0 2 7 2 6 6 116 8 7 0 1 4 1 6 9

4 1 3 3 2 7 1 2 5 8 1 2 9 0 2 1 3 6 8

3 4 2 2 2 1 8 4 6 6 6 2 1 1 1 5 23 2 1 8 1 8 6 4 7 7 5 5 1 0 1 6 3

2 3 2 3 448 7 6 3 7 5 9 1 1 2 420

3 2 3 2 2 9 9 4 7 7 8 6 1 4 2 105

4 7 3 5 3 4 1 2 8 3 1 2 9 4 1 7 2 8 64 3 3 4 2 9 1 4 8 1 1 6 106 1 9 2 9 42 6 1 6 1 6 6 4 6 8 5 3 1 0 2 6 3

2 4 9 1 3 4 2 9 <6 3 9 6 1 3 1

3 7 2 6 2 6 1 1 5 8 1 4 8 0 1 5 2 9 5

1 8 1 3 7 <2 1 6 <6 1 4 4 <1 3 0

5 8 9 1 3 5 4 0 1 6 3 3 1 7 3 3 4

2 5 5 9 3 2 8 <6 2 5 5 <1 3 12 0 9 1 2 3 1 8 <6 3 3 5 1 2 6

2 8 1 5 1 8 6 4 0 7 4 9 1 1 2 4 8<9 4 8 2 1 8 <6 1 9 5 <1 2 1<9 4 9 2 1 8 <6 1 9 4 <1 1 81 3 9 1 3 5 3 7 <6 3 7 8 1 4 2

2 7 1 7 3 0 7 7 3 9 6 2 1 2 2 7 22 0 2 0 1 8 9 6 0 8 6 6 1 4 2 6 5

1 6 6 <4 <2 1 2 <6 1 0 3 <1 1 32 0 5 <4 <2 1 2 <6 1 0 3 <1 1 02 8 1 5 1 3 4 3 2 <6 3 1 7 1 3 12 2 1 0 9 3 2 9 <6 2 8 6 1 2 83 2 1 4 1 1 4 3 1 <6 3 2 7 1 4 12 4 8 6 3 2 3 <6 2 1 4 <1 2 01 4 6 5 <2 1 9 <6 1 2 3 <1 1 7
139

Nd ppm Ni ppm Pb ppm Sc ppm Sr ppm Th ppm V ppm Y ppm Yb ppm Zn ppm

1 8 9 1 0 4 2 7 <6 2 9 6 1 4 02 2 9 1 0 3 2 2 <6 2 3 5 <1 2 61 4 1 1 1 4 3 3 8 <6 3 0 7 1 5 62 3 9 6 2 2 2 <6 1 8 4 <1 2 12 6 1 2 1 3 4 3 2 <6 3 3 7 1 3 61 5 8 6 2 2 6 <6 2 0 4 <1 2 4

2 8 2 6 2 1 9 6 4 1 1 6 6 1 5 2 8 6

4 0 9 7 3 2 8 <6 2 3 5 <1 3 14 2 2 0 8 3 3 0 <6 2 3 5 <1 3 73 0 1 0 1 0 3 2 6 <6 2 5 6 <1 3 04 3 1 5 8 <2 5 0 <6 1 9 8 <1 4 34 6 1 9 9 3 2 8 <6 2 2 7 <1 4 63 0 <3 1 0 3 2 6 <6 4 3 4 <1 2 4

6 0 2 1 1 6 8 6 2 9 5 8 1 4 2 6 3

3 0 1 3 1 2 5 5 0 <6 3 5 7 1 3 63 2 9 9 3 2 3 <6 2 3 5 <1 2 53 8 2 1 1 1 4 4 3 <6 3 4 9 1 5 02 8 7 1 3 3 2 8 <6 2 5 5 <1 3 82 5 9 1 4 4 3 5 <6 3 0 7 1 4 22 1 1 6 1 5 5 4 6 6 3 7 7 1 4 6

2 4 1 9 1 5 6 4 7 <6 5 0 1 1 2 7 9

1 6 7 8 2 2 2 <6 1 8 4 <1 1 82 0 1 3 9 4 3 2 <6 2 9 6 1 3 21 8 1 3 9 4 3 1 <6 3 3 8 1 4 0

5 1 4 3 4 9 1 6 7 9 1 4 101 3 3 4 127

1 4 2 3 1 1 4 4 6 <6 3 3 7 1 5 0

2 6 1 6 1 7 7 5 0 9 4 9 1 1 2 4 4

1 6 8 1 0 3 3 1 <6 2 6 6 <1 2 71 5 8 1 0 3 2 7 <6 2 6 5 <1 3 0
140

Nd ppm Ni ppm Pb ppm Sc ppm Sr ppm Th ppm V ppm Y ppm Yb ppm Zn ppm

1 8 1 2 1 2 4 3 5 <6 3 2 6 1 3 11 8 9 9 3 2 7 <6 3 0 5 <1 2 92 8 1 5 1 3 5 4 7 1 0 4 0 8 1 4 4

2 9 1 9 1 9 9 6 1 1 2 6 2 1 3 2 5 6

1 7 8 8 3 2 5 <6 2 7 6 1 2 41 9 1 0 1 0 3 2 9 <6 3 4 7 1 4 42 2 1 4 1 2 4 4 3 <6 3 3 6 1 3 12 1 8 7 <2 2 1 <6 1 4 4 <1 2 8

2 4 1 8 1 6 8 6 0 8 6 2 1 2 2 5 1

2 1 9 1 0 4 3 4 <6 2 7 7 1 2 61 2 6 9 <2 1 9 <6 1 4 3 <1 1 71 9 1 7 1 2 4 3 8 <6 3 6 7 1 5 52 1 1 1 1 1 3 3 3 <6 2 7 5 <1 2 92 4 1 4 1 4 5 4 0 <6 4 1 9 1 5 1

4 2 2 0 3 4 1 0 7 9 1 0 7 9 1 3 2 102

2 6 1 6 1 7 7 4 8 9 5 5 9 2 4 92 1 1 8 1 3 5 4 0 <6 4 1 8 1 4 61 9 1 1 1 2 4 3 1 <6 3 0 6 1 2 61 5 9 1 1 4 2 6 <6 3 0 5 <1 2 72 3 8 1 1 4 3 5 <6 3 4 5 1 2 53 2 1 5 9 4 3 2 7 2 8 7 1 3 32 6 1 2 1 1 5 3 4 9 3 6 8 1 3 32 9 1 0 8 3 3 0 <6 2 6 6 <1 2 72 0 8 7 <2 1 8 6 1 5 4 <1 1 72 0 8 5 2 2 2 <6 1 8 4 <1 1 62 7 1 2 6 3 2 8 <6 2 6 5 <1 2 9

4 2 1 7 1 4 7 5 1 1 2 5 1 1 1 2 4 8

2 5 1 4 1 4 5 3 4 7 4 1 8 1 4 0

3 7 2 0 1 9 1 0 6 7 1 1 7 2 1 4 2 6 3
141

Nd ppm Ni ppm Pb ppm Sc ppm Sr ppm Th ppm V ppm Y ppm Yb ppm Zn ppm

5 1 2 1 2 2 1 1 7 7 1 3 8 1 1 7 2 6 9

1 7 8 8 3 2 4 6 2 2 5 <1 2 12 5 1 0 1 2 5 3 9 9 4 1 8 1 3 52 0 1 0 1 0 4 3 6 <6 3 1 8 1 2 93 0 1 0 9 3 2 7 <6 2 3 6 <1 2 92 1 1 0 8 3 2 8 8 2 5 6 <1 2 61 7 1 1 9 4 2 6 7 2 9 6 <1 3 11 9 7 6 <2 2 3 <6 1 6 4 <1 1 3

3 5 1 5 1 4 7 5 6 1 0 5 0 1 1 2 4 6

9 8 5 2 2 0 <6 1 8 4 <1 2 0

2 8 8 7 3 2 1 6 2 0 5 <1 2 41 6 1 0 7 3 2 3 <6 2 2 5 <1 3 6

3 0 2 3 1 4 4 4 0 <6 3 1 9 1 4 9

1 3 1 0 1 0 4 2 9 <6 3 2 7 1 3 2

1 4 9 1 0 4 5 2 <6 2 9 7 1 2 9

2 8 1 1 9 4 4 4 <6 2 7 7 1 2 71 9 8 7 2 2 9 <6 1 9 5 <1 1 83 2 9 1 0 3 3 8 9 2 7 6 <1 2 7

3 2 1 7 1 5 7 7 7 1 4 5 3 1 6 2 5 0

3 2 1 1 1 0 3 4 7 <6 2 6 6 <1 2 6

3 1 1 2 1 2 4 4 3 8 3 3 8 1 3 1

2 0 7 8 2 3 1 <6 1 9 5 <1 2 12 0 8 8 2 3 7 <6 2 1 5 <1 2 22 3 6 7 2 3 0 <6 1 8 5 <1 1 92 7 1 0 1 2 4 3 5 <6 2 8 7 1 3 72 8 1 1 1 2 4 3 4 <6 2 8 8 1 3 02 3 7 7 2 2 5 <6 1 9 5 <1 2 61 7 6 8 2 3 1 <6 1 9 5 <1 2 01 9 9 1 0 4 4 3 <6 2 5 8 1 2 5
142

Nd ppm Ni ppm Pb ppm Sc ppm Sr ppm Th ppm V ppm Y ppm Yb ppm Zn ppm

1 7 6 8 3 3 5 <6 1 9 6 <1 2 02 0 9 9 3 3 9 <6 2 6 6 <1 2 92 3 8 9 3 3 3 <6 2 4 5 <1 2 43 8 1 7 2 7 4 7 1 8 3 3 9 1 4 1

4 2 2 5 6 7 7 102 1 1 5 3 1 7 2 6 6

2 3 7 8 2 3 1 <6 1 7 5 <1 1 6

7 3 1 1 1 5 6 6 3 2 6 3 8 2 4 3 3 3

1 7 1 0 1 2 4 3 6 <6 3 3 7 1 3 43 1 1 0 9 4 4 5 8 3 3 8 1 3 0

9 5 9 3 3 2 <6 2 1 5 <1 2 4

2 0 9 9 3 4 3 6 2 5 6 <1 2 43 0 1 1 1 1 4 4 0 8 3 0 6 1 3 13 8 2 0 1 9 6 6 9 1 0 4 8 1 1 1 7 4

2 8 1 1 2 4 5 7 4 1 0 3 8 1 2 2 4 2

3 1 1 7 1 9 8 7 3 1 0 6 7 1 0 2 5 1

<9 8 9 3 3 2 <6 2 1 5 <1 4 01 7 1 0 9 3 4 5 <6 2 7 6 <1 2 8

1 7 1 4 1 7 7 5 9 1 1 5 2 1 1 2 5 3

<9 9 1 2 4 5 6 <6 3 1 7 1 4 01 2 9 3 0 3 6 4 <6 2 8 7 <1 3 8<9 7 1 3 3 4 9 <6 2 6 6 <1 2 6<9 8 1 5 3 4 7 <6 2 6 6 <1 2 8<9 7 1 0 3 4 7 6 2 6 6 <1 3 31 0 1 1 1 2 4 4 5 8 3 3 7 1 3 51 6 1 1 1 0 4 4 6 <6 3 2 7 1 6 11 0 1 2 2 1 5 4 5 8 3 9 7 1 4 3<9 9 1 6 5 4 0 <6 4 0 7 1 3 8<9 6 1 6 4 3 4 <6 3 8 7 1 3 5<9 5 1 8 5 3 8 <6 4 2 8 1 6 4
143

Nd ppm Ni ppm Pb ppm Sc ppm Sr ppm Th ppm V ppm Y ppm Yb ppm Zn ppm

<9 6 1 4 5 3 8 <6 4 2 8 1 3 9<9 5 1 2 3 3 6 <6 2 9 5 <1 2 9<9 6 1 3 4 4 6 7 3 4 6 <1 3 8

<9 1 6 2 7 1 1 9 5 1 4 7 8 1 4 2 6 1

<9 7 2 8 4 5 7 <6 3 6 7 1 4 6<9 8 1 4 4 4 2 9 3 5 7 1 3 8<9 6 1 2 4 4 0 <6 3 0 6 1 3 2<9 1 0 1 4 5 4 0 7 4 3 8 1 4 4<9 1 4 1 7 6 4 7 8 5 1 9 1 5 2<9 1 0 2 1 5 4 7 7 3 9 7 <1 4 4<9 5 1 5 4 5 3 <6 3 6 7 1 3 8<9 7 1 6 6 5 0 7 4 8 8 1 4 3<9 4 1 6 5 4 0 <6 4 3 8 1 4 6<9 3 9 3 3 8 <6 2 6 5 <1 2 8

<9 9 2 0 5 7 7 6 4 2 9 1 6 0

<9 1 1 1 9 6 5 2 9 5 0 1 1 2 5 8<9 8 1 4 5 4 2 1 0 4 5 9 1 4 6<9 1 1 1 4 5 5 0 6 3 8 7 1 4 8<9 <3 1 5 3 4 2 <6 2 9 6 <1 2 7<9 <3 1 3 3 4 7 7 2 4 6 <1 2 8<9 6 1 4 5 4 5 8 4 0 8 1 3 7<9 <3 1 2 3 4 6 7 2 8 6 <1 2 7<9 9 1 7 6 5 6 1 0 4 5 9 1 4 6<9 4 1 3 3 4 2 <6 2 6 6 <1 3 1<9 4 1 2 3 3 1 6 2 9 6 <1 2 7<9 9 1 4 3 3 8 <6 2 3 5 <1 2 9<9 6 8 2 3 5 <6 1 9 4 <1 2 5<9 8 9 3 3 7 <6 2 3 5 <1 3 2<9 6 1 3 2 4 1 <6 2 0 4 <1 3 7
144

Nd ppm Ni ppm Pb ppm Sc ppm Sr ppm Th ppm V ppm Y ppm Yb ppm Zn ppm

<9 7 1 1 3 4 1 <6 2 5 6 <1 3 2

9 6 1 3 3 4 0 6 2 7 6 <1 4 4

<9 5 1 2 2 3 8 <6 2 2 5 <1 3 2<9 7 1 4 4 4 4 7 3 4 8 1 3 5<9 9 1 6 6 5 3 9 4 9 8 1 5 4<9 8 1 7 5 5 8 <6 4 4 8 1 4 3<9 1 1 1 2 3 3 7 <6 2 6 5 <1 3 7<9 6 1 5 4 3 6 7 3 1 7 <1 5 7<9 9 1 6 5 4 8 7 4 1 9 1 4 0<9 1 7 1 9 5 5 9 8 5 2 9 1 6 0<9 3 1 1 2 3 6 <6 2 1 5 <1 2 7

1 4 9 1 7 5 4 8 8 4 5 9 1 4 5

<9 1 0 1 1 3 3 1 <6 2 8 5 <1 3 3<9 1 2 1 5 5 3 9 <6 4 2 8 1 5 71 3 1 5 1 7 6 4 6 7 4 7 1 0 1 5 3

1 8 9 1 3 5 115 9 4 2 9 1 4 9

<9 6 7 3 3 3 6 2 6 6 <1 2 4<9 6 1 3 4 3 8 <6 3 4 7 <1 3 1<9 <3 1 3 3 3 6 <6 2 4 5 <1 2 2<9 <3 9 2 3 4 <6 2 1 5 <1 1 9<9 <3 7 <2 2 2 <6 1 3 4 <1 1 5<9 <3 1 2 4 4 8 <6 3 1 8 1 3 0<9 5 1 5 4 4 9 7 2 8 7 <1 3 6<9 5 1 4 3 4 7 <6 2 9 6 <1 4 1<9 5 1 1 3 3 7 <6 2 6 6 <1 2 81 8 9 1 3 5 6 8 <6 4 0 7 <1 4 01 6 8 1 4 5 5 0 1 0 3 9 8 1 3 1<9 5 1 4 3 3 7 <6 2 8 6 <1 3 3<9 6 1 2 4 4 2 7 3 7 7 1 3 9
145

Nd ppm Ni ppm Pb ppm Sc ppm Sr ppm Th ppm V ppm Y ppm Yb ppm Zn ppm

<9 6 1 3 4 4 1 7 3 1 6 <1 3 5<9 6 2 8 4 5 7 <6 3 1 7 <1 6 2<9 7 1 1 3 4 6 8 2 7 6 <1 3 1<9 7 1 3 3 4 2 <6 2 7 6 <1 3 7<9 4 1 0 3 3 3 <6 2 8 6 <1 3 0<9 6 8 3 3 9 <6 2 4 5 <1 2 7<9 <3 6 2 2 5 <6 1 8 4 <1 1 9<9 7 1 1 2 3 3 <6 2 1 5 <1 2 5<9 5 1 1 3 3 2 <6 2 2 7 <1 2 7

9 1 6 1 7 6 4 3 8 4 7 1 0 1 4 3

<9 8 1 7 7 6 1 7 5 6 1 1 2 3 7<9 8 1 2 3 3 6 8 2 6 6 <1 2 7<9 6 1 5 4 4 4 <6 3 2 7 1 3 9

1 5 1 5 2 6 8 6 4 8 6 4 1 3 2 6 3

<9 7 1 4 5 5 2 8 4 1 7 1 3 0<9 4 1 0 2 3 1 <6 2 1 4 <1 2 2<9 1 1 1 3 3 4 2 <6 2 6 5 <1 3 9<9 5 1 2 3 3 6 <6 2 6 5 <1 2 4

1 2 1 1 1 5 7 5 8 1 1 5 1 9 1 4 9

<9 7 2 1 5 5 2 6 3 7 7 1 5 1<9 9 1 2 4 3 5 <6 3 7 7 1 3 2

<9 1 9 1 9 6 6 4 8 4 9 1 0 1 6 2

<9 9 1 9 4 8 6 6 3 5 8 <1 4 02 6 1 2 1 5 6 6 8 1 0 4 3 9 1 4 11 6 1 0 1 0 4 3 9 9 3 5 8 1 3 81 0 1 1 1 4 4 4 9 6 3 3 9 1 4 22 4 1 1 1 2 3 3 7 7 3 0 6 1 3 0<9 1 3 8 3 3 9 7 2 3 5 <1 2 3<9 8 9 3 151 <6 3 9 6 <1 2 3
146

Nd ppm Ni ppm Pb ppm Sc ppm Sr ppm Th ppm V ppm Y ppm Yb ppm Zn ppm

3 9 9 7 3 6 3 7 2 5 6 <1 2 31 6 1 3 2 7 5 4 6 <6 4 2 8 1 3 9

2 5 2 7 1 6 8 6 4 9 5 9 1 3 2 6 6

1 3 1 2 1 5 5 5 5 <6 3 6 8 1 3 7

2 4 1 4 1 6 9 6 9 1 2 6 5 1 1 2 4 3

1 6 1 0 1 2 5 4 9 1 0 3 6 9 2 2 92 3 1 1 7 1 4 8 2 <6 3 4 9 1 3 51 6 7 1 6 3 3 7 <6 2 2 8 1 2 21 8 1 3 1 4 5 5 1 6 4 1 9 1 3 9

1 7 9 6 <2 1 3 <6 1 9 4 <1 2 31 2 1 3 6 3 1 7 <6 3 3 5 1 3 11 5 2 2 1 4 6 2 4 9 6 4 8 2 6 52 1 2 2 1 6 5 3 6 9 6 8 9 2 4 21 7 1 5 1 0 4 1 9 <6 4 5 7 1 3 81 8 1 8 1 2 5 2 2 9 5 1 7 1 6 1

2 3 4 0 2 1 1 1 4 9 1 4 115 1 2 2 8 34 6 5 1 3 3 1 3 7 8 1 7 151 1 6 2 1172 4 6 1 4 2 1 4 6 6 1 6 334 2 0 2 210

1 5 1 6 1 0 4 2 4 <6 4 1 6 1 4 9

1 9 2 1 1 6 7 4 0 8 6 7 1 2 2 5 5

5 9 272 4 6 1 3 6 2 1 6 336 6 2 4 7636 5 342 4 1 1 4 6 6 1 4 284 7 6 5 7982 4 2 0 3 6 1 3 5 4 1 5 382 2 0 2 9 6

1 7 3 5 2 5 8 4 0 9 8 7 1 0 2 8 1

3 3 1 6 6 8 1 3 7 0 1 3 488 2 0 2 107

2 6 1 7 3 7 1 2 5 9 1 2 311 1 8 2 7 1

2 8 9 1 3 4 1 1 5 2 1 2 256 2 1 2 306

1 3 1 5 1 0 3 1 9 <6 3 9 8 1 3 61 2 1 6 1 0 4 2 2 7 4 2 8 1 3 4
147

Nd ppm Ni ppm Pb ppm Sc ppm Sr ppm Th ppm V ppm Y ppm Yb ppm Zn ppm

1 1 2 0 1 5 6 3 3 7 6 6 1 0 2 5 2

3 5 3 1 1 8 1 0 5 1 1 2 101 1 6 3 7 5

3 3 5 4 3 3 1 6 8 2 1 9 174 1 7 3 1192 7 4 4 3 6 1 5 6 6 1 4 166 1 5 2 130

1 3 1 0 4 2 1 2 <6 1 9 4 <1 1 4

1 7 2 1 1 6 7 3 8 1 1 6 4 1 4 2 5 6

2 0 1 3 1 1 3 1 7 <6 2 9 8 1 3 11 1 7 <4 <2 8 <6 7 3 <1 81 4 1 0 8 2 174 7 2 9 9 <1 3 6

2 8 1 7 1 4 5 162 1 0 5 6 1 4 1 5 6

1 3 1 2 6 3 1 8 <6 2 5 6 <1 1 91 5 1 7 1 7 5 2 9 7 5 5 9 2 4 61 5 6 <4 <2 8 <6 6 3 <1 1 12 1 1 7 1 2 4 2 2 7 4 7 9 1 4 5<9 2 0 1 0 5 4 7 <6 5 6 1 0 1 4 2

4 6 2 2 1 5 1 1 5 3 1 4 7 8 1 7 2 5 1

2 1 1 6 9 4 3 0 7 3 0 1 1 1 3 7

2 2 1 3 9 4 5 9 3 5 1 0 2 3 9

4 0 4 2 1 6 1 0 4 7 1 0 7 4 1 7 2 7 3

<9 8 5 <2 5 6 4 5 <1 1 5

3 9 1 7 1 4 8 6 0 1 1 5 7 1 5 2 5 34 2 3 0 1 8 1 1 7 1 1 2 8 1 1 9 3 8 52 2 1 6 1 3 5 3 6 <6 3 9 1 0 2 3 63 9 2 7 2 0 1 2 9 4 1 5 8 8 2 0 3 9 04 5 3 0 2 9 1 5 105 1 6 106 2 1 3 1053 5 2 4 2 2 9 6 1 9 7 1 1 5 2 8 53 3 2 3 1 9 8 5 9 1 1 6 3 1 4 2 7 03 0 1 8 2 0 7 5 1 1 1 5 6 1 4 2 5 35 2 4 2 2 7 1 3 8 4 1 4 9 4 2 6 3 120

31 < 1
148

Nd ppm Ni ppm Pb ppm Sc ppm Sr ppm Th ppm V ppm Y ppm Yb ppm Zn ppm

2 0 2 0 1 6 7 5 7 1 1 5 6 1 4 2 6 14 1 2 2 1 8 9 6 4 1 4 6 6 1 7 2 6 63 8 2 1 2 6 7 8 6 9 5 6 1 5 2 1023 9 2 1 1 9 8 6 5 1 3 5 8 1 6 2 6 33 6 2 2 1 6 7 5 1 1 1 5 1 1 4 2 5 84 8 1 4 1 3 5 4 5 1 1 3 7 1 2 2 4 14 3 2 0 2 2 9 6 1 7 6 6 1 3 2 7 57 4 1 3 1 0 5 4 5 1 5 3 8 1 6 2 3 55 4 3 4 3 0 1 6 107 1 7 115 2 2 3 1115 4 2 9 2 2 1 3 9 7 1 4 9 4 1 9 3 1014 7 2 1 1 8 8 6 0 1 0 6 1 1 4 2 6 2

4 2 1 7 1 3 6 4 8 7 4 7 1 1 2 4 3

4 5 1 9 1 5 8 5 6 1 2 5 7 1 4 2 5 14 9 1 9 1 7 7 6 4 1 2 5 5 1 3 2 7 35 2 3 5 2 4 1 3 8 9 1 6 9 2 2 0 3 9 94 6 2 5 2 0 8 7 0 1 3 6 4 1 5 2 6 44 0 1 6 1 5 6 5 1 1 0 4 5 1 3 2 5 23 8 2 3 2 2 8 5 3 1 1 6 3 1 4 2 6 03 3 2 0 1 9 7 4 2 1 0 5 4 1 2 2 4 73 6 1 3 1 1 5 3 6 7 3 9 1 1 2 3 14 7 2 3 1 7 8 5 4 1 2 6 1 1 4 2 4 73 0 1 7 1 3 6 3 5 8 4 6 1 0 2 3 24 6 2 9 5 4 9 5 6 8 7 0 1 5 2 9 1

3 1 1 2 1 4 5 3 3 8 3 7 9 1 3 6

2 4 7 5 3 2 1 <6 2 1 6 1 2 12 8 1 4 1 2 2 8 7 3 3 1 3 7

3 0 7 1 0 2 3 7 3 0 1 1 2 03 3 1 6 1 3 6 3 6 1 2 4 0 1 2 2 3 9

3 1 1 2 9 3 2 3 9 2 2 9 1 2 9

4 83 2
149

Nd ppm Ni ppm Pb ppm Sc ppm Sr ppm Th ppm V ppm Y ppm Yb ppm Zn ppm

3 6 1 6 2 3 1 1 6 7 1 3 8 6 1 8 2 123

9 7 6 <2 1 6 3 4 <1 2 0

1 2 1 3 1 3 3 3 7 <6 2 5 8 <1 3 1<9 8 8 2 2 2 9 1 9 7 1 0<9 8 8 <2 7 7 1 8 5 <1 51 4 6 8 <2 3 6 4 7 <1 1 5<9 4 1 1 3 5 <6 0 8 1 2 3

6 0 9 1 4 5 4 7 1 5 3 7 1 6 2 3 9

1 6 8 8 3 2 9 <6 2 1 1 0 2 2 63 1 7 8 2 3 1 6 1 8 1 0 1 2 42 9 7 7 2 2 4 1 1 1 6 1 0 1 1 71 7 7 7 2 2 3 6 1 8 7 <1 2 13 2 7 8 3 2 9 1 0 2 2 1 0 1 2 45 0 8 1 0 4 3 0 1 8 2 6 1 4 2 3 2

4 8 2 9 2 5 9 5 4 1 2 7 8 1 6 2 7 2

4 0 2 0 1 9 5 3 1 <6 5 1 1 0 2 5 1

3 4 1 7 1 8 6 4 1 1 3 5 1 1 5 2 4 7

3 2 1 6 2 4 8 4 5 8 6 9 1 4 2 5 43 6 8 1 4 3 7 8 3 4 1 1 3 5

2 2 1 0 1 2 3 4 <6 3 0 9 1 3 43 2 1 0 1 2 3 1 <6 3 1 8 1 3 5

4 1 1 5 1 4 5 4 6 1 0 4 0 1 3 2 5 0

2 9 1 0 1 3 3 4 6 3 4 1 3 73 4 1 2 1 3 3 4 <6 3 4 8 1 4 53 0 1 2 1 0 3 4 6 3 4 1 4 0

3 2 1 7 1 2 7 4 1 1 2 5 1 1 1 2 4 1

4 3 1 3 1 6 5 3 8 1 1 4 1 1 0 1 4 73 5 1 0 1 4 3 2 <6 3 6 8 1 3 16 3 2 0 2 4 6 5 6 6 6 9 1 1 1 6 2

2 < 1

2

1 22 < 12 2

4 2

444 944 94
Nd ppm Ni ppm Pb ppm Sc ppm Sr ppm Th ppm V ppm Y ppm Yb ppm Zn ppm 

 2 8 9 1 3 3 2 0 < 6 2 8 6 < 1 2 3  3 6 1 2 1 6 5 3 1 9 5 0 1 0 2 4 2  3 2 1 3 1 5 3 1 < 6 39 8 1 45  2 7 7 7 2 2 5 < 6 1 9 6 < 1 2 2 

 2 3 9 7 3 2 0 < 6 2 2 6 < 1 1 9 

 1 9 8 1 6 3 3 < 6 4 7 1 2 1  3 4 1 1 1 3 4 3 5 8 3 7 1 0 2 3 9  3 4 1 2 1 2 3 7 < 6 41 9 1 39 

 2 0 1 3 1 8 7 5 0 9 5 3 1 3 2 5 5 

 3 2 13 19 7 5 0 1 0 5 7 1 1 2 1 1 3 

 4 1 1 8 1 9 7 44 < 6 57 12 1 5 9  3 8 8 1 7 3 2 7 2 2 7 1 4 9  2 4 9 7 < 2 3 6 7 5 < 1 2 1  2 6 8 9 3 27 < 6 24 8 1 28  3 2 1 0 8 3 9 < 6 8 7 1 3 0  4 3 8 8 3 27 8 2 2 9 1 8  3 3 1 6 1 4 4 3 5 7 3 7 1 2 2 5 0 

 2 5 18 21 7 4 4 1 0 6 1 1 2 2 61 

 2 1 1 2 1 3 3 3 7 3 7 1 3 8 

 3 3 6 1 9 4 1 7 3 7 1 0 2 3 

 2 3 7 < 4 < 2 2 6 0 4 < 1 1 0  1 3 6 4 <2 1 2 <6 9 3 <1 1 4 

 5 0 27 35 14 76 17 1 1 5 21 3 9 1 

 2 4 1 0 9 3 8 < 6 0 6 1 2 8 

 4 0 31 31 20 84 22 1 4 8 21 3 9 0 

4 

2 2 

5 

3 < 

2 < 1 2 2 

2 

4 9 5 1 

1 < 1 1 3 

150

APPENDIX II--DEVONIAN SHALE AND COAL SEMIQUANTITATIVE XRF DATA 

Analytical Methods 

Semiquantitative concentrations of 14 elements were determined in the field with a portable X-ray 

fluorescence analyzer manufactured by the Niton Corporation. Analyses employing X-ray fluorescence 

(XRF) instrument such as the one used in this study are highly dependent on the geometry of the 

material being analyzed and the correction procedures used in the analyses. The scheme used in this 

study incorporated minimal, manufacturer supplied, correction procedures resulting in, at best, 

semiquantitative measurements. Further, the technique only measures surface compositions (x-ray 

penetration is generally less than 1 mm/0.04 in). Because flat surfaces are ideal for analyses, readings 

were generally taken along surfaces defined by bedding planes in the shale and cleats in the coal. 

Values below the detection limit are shown as <LOD. Detection limits were highly variable, depending 

on the element and sample analyzed. The error value reported is based on counting statistics and is an 

estimate of deviation for the concentration reported. 

151

ny Shale and associated soils and salts 

e Longitude Sample Description transect (cm Core depth (m) 

from edge) 

22.8" 83°59'18.1" Partly weathered shale w/white rind 22.8" 83°59'18.1" Less weathered darker shale 22.8" 83°59'18.1" White weathering rind on shale 

7.5" 83°59'18.6" Red stained shale on bench in drainage 

09.1" 83°56'46.0" White powdery surface on weathered sh. 09.1" 83°56'46.0" Shale beneath coating 01KY-05R 09.1" 83°56'46.0" Red coating on shale (just below 01KY-06R) 09.1" 83°56'46.0" Red material filling near vert. Fracture 

44.4" 83°57'04.3" Weathered reddish brown shale 258 

44.4" 83°57'04.3" Lt. brown Soil just to right of outcrop -75 44.4" 83°57'04.3" Reddish soil about 175 m below 01KY-11R -85 44.4" 83°57'04.3" Reddish soil halfway between 01KY11R-12R -80 44.4" 83°57'04.3" 20 cm pit at 01KY-12R--reddish soil -75 

44.4" 83°57'04.3" White coating on shale 203 

44.4" 83°57'04.3" Red-brn. shale beneath coating 01KY-15R-A 203 44.4" 83°57'04.3" Shale beneath coating 01KY-10R-A 258 

44.4" 83°57'04.3" Coating on shale 308 

44.4" 83°57'04.3" Shale beneath coating 01KY-16R-A 308 

44.4" 83°57'04.3" Coating on shale 368 

44.4" 83°57'04.3" Shale beneath coating 01KY-17R-A 368 

44.4" 83°57'04.3" Coating on shale just before slump block(?) 443 

44.4" 83°57'04.3" Shale beneath 01KY-18R-A 443 

44.4" 83°57'04.3" Coating on shale just on slump block(?) 583 

44.4" 83°57'04.3" Fissle shale just on slump block(?) 583 

44.4" 83°57'04.3" Coating on shale near salt encrustations 663 

44.4" 83°57'04.3" Grayish, cemented(?) shale beneath 01KY-20R-A 663 44.4" 83°57'04.3" Salts encrustation just above & left 01KY-20R 693 

152

e Longitude Sample Description transect (cm) Core depth (m) 

from edge) 

44.4" 83°57'04.3" Lt. yellow salts left of 01KY21 958 

44.4" 83°57'04.3" Reddish saltish surface on shale 813 

44.4" 83°57'04.3" Shale beneath 01KY-24R-A 813 

44.4" 83°57'04.3" Coating on shale at left edge of slump block(?) 1063 44.4" 83°57'04.3" Coating on shale 1613 

44.4" 83°57'04.3" Shale beneath 01KY-28R-A 1613 44.4" 83°57'04.3" White weathering rind on disaggreg. sh. on bench 44.4" 83°57'04.3" Red weathering rind on disaggred sh. on bench 44.4" 83°57'04.3" red weathered shale on bench 

Vert. py. vein in dk. grayish brn sh.-Sunbury 7.56 Dark brn. pyritic sh. 7.82 Pyrite nodules and banding in dk. brn. sh. 8.28 Very dk. brn. pyritic sh. 8.31 White weathering salts on pyrite in shale (from handling of core) 11.06 Brec.? pyritized med. gry. material in v drk brn py. sh. (top Cleveland) 9.25 

 Dk. brn. pyritic sh. 9.28 

Med. dk. brn. pyritic sh. 11.41 Med. gry. lense of material variably sulfidized 11.45 Pyritized lense in med. gry. brn. lam. sh. 19.95 Med. brn. pyritic sh. (near bottom of Cleveland) 20.01 Py. nodule (fine py in center) in dk. gry. brn. sh.-Three Licking 22.72 Py. nodule (course py on edge) in dk. gry. brn. sh.-Three Licking 22.72 Med. gry. br. sh. 22.78 Med. gry. br. sh. near top of Huron 26.53 Med dk. br. sh. middle of Huron 32.63 Dk. gry. br. py. Huron sh. 38.73 

153

e Longitude Sample Description transect (cm) Core depth (m) 

from edge) 

Py. nodule in v. dk. brn Huron sh. 33.42 Med gry. pyritic bands & nodules in dk. brn. Huron sh. 44 Med. dk. brn. pyritic Huron sh. 43.75 Med. brn. py. Huron sh. 48.42 Med brnish gry. Hur/Duf mudstone/sh. 49.79 Sulfidized nodule in Hur/Duf med. brnish gry. mudstone/sh. 52.99 

f detection. LOD is variable for each sample and depends on counting statistics. 

154

Site Location As As Error Co Co Error Cr Cr Error Cu Cu Error 

ppm ppm ppm ppm ppm ppm ppm ppm 

nty Middle School <LOD 27 <LOD 230 <LOD 360 <LOD 120 nty Middle School <LOD 28 <LOD 240 <LOD 410 <LOD 120 nty Middle School <LOD 33 250 160 <LOD 440 <LOD 210 

Cnty Middle School <LOD 28 <LOD 470 660 400 150 83 

crop 1 (south) 93 34 140 740 <LOD 1200 <LOD 200 crop 1 (south) 78 38 <LOD 840 <LOD 1000 <LOD 230 crop 1 (south) 220 39 2000 910 2100 1000 <LOD 200 crop 1 (south) 59 36 <LOD 860 <LOD 1100 <LOD 200 

crop 2 (north) <LOD 51 <LOD 930 <LOD 1100 <LOD 200 

crop 2 (north) <LOD 34 <LOD 470 <LOD 540 <LOD 110 crop 2 (north) 41 21 <LOD 380 <LOD 480 <LOD 96 crop 2 (north) 25 16 <LOD 260 <LOD 330 <LOD 77 crop 2 (north) 42 24 <LOD 450 <LOD 590 <LOD 120 crop 2 (north) 46 25 <LOD 510 <LOD 650 <LOD 130 crop 2 (north) <LOD 51 <LOD 350 <LOD 620 <LOD 180 crop 2 (north) <LOD 37 <LOD 290 <LOD 450 <LOD 140 crop 2 (north) 31 18 <LOD 360 <LOD 450 <LOD 89 crop 2 (north) <LOD 84 <LOD 810 <LOD 1200 <LOD 380 

crop 2 (north) <LOD 53 <LOD 390 <LOD 690 <LOD 180 crop 2 (north) <LOD 55 <LOD 860 <LOD 1000 <LOD 230 crop 2 (north) <LOD 30 <LOD 230 <LOD 360 <LOD 100 crop 2 (north) 43 17 <LOD 240 <LOD 330 <LOD 78 crop 2 (north) <LOD 35 <LOD 630 <LOD 750 <LOD 140 crop 2 (north) 49 30 <LOD 500 <LOD 680 <LOD 150 crop 2 (north) <LOD 57 <LOD 590 <LOD 810 <LOD 240 crop 2 (north) 80 36 <LOD 680 <LOD 860 <LOD 200 

crop 2 (north) 37 20 <LOD 540 <LOD 680 <LOD 140 

155

Site Location As As Error Co Co Error Cr Cr Error Cu Cu Error 

ppm ppm ppm ppm ppm ppm ppm ppm 

crop 2 (north) <LOD 51 <LOD 930 <LOD 1100 <LOD 210 

crop 2 (north) 68 29 <LOD 660 <LOD 830 <LOD 180 crop 2 (north) <LOD 46 <LOD 560 <LOD 840 <LOD 180 crop 2 (north) 43 20 <LOD 350 <LOD 450 <LOD 110 crop 2 (north) 42 17 <LOD 390 570 310 <LOD 92 crop 2 (north) 32 18 <LOD 360 <LOD 440 <LOD 90 

crop 2 (north) <LOD 19 <LOD 240 350 200 <LOD 64 crop 2 (north) 85 22 <LOD 690 900 520 <LOD 100 crop 2 (north) 60 22 <LOD 570 <LOD 680 <LOD 100 

owell County, Clay City Quad. 3500 93 <LOD 840 <LOD 1000 <LOD 140 owell County, Clay City Quad. 140 19 <LOD 300 <LOD 360 <LOD 71 owell County, Clay City Quad. 330 29 660 330 <LOD 590 <LOD 95 owell County, Clay City Quad. 110 20 <LOD 330 <LOD 410 <LOD 76 owell County, Clay City Quad. 51 23 1600 660 <LOD 1100 <LOD 130 owell County, Clay City Quad. 160 34 2300 840 <LOD 1400 <LOD 170 owell County, Clay City Quad. <LOD 15 200 130 260 170 <LOD 56 owell County, Clay City Quad. <LOD 15 220 110 280 150 <LOD 53 owell County, Clay City Quad. <LOD 24 <LOD 180 <LOD 360 <LOD 83 owell County, Clay City Quad. 100 29 1900 770 <LOD 1300 <LOD 210 owell County, Clay City Quad. <LOD 17 <LOD 180 <LOD 240 <LOD 60 owell County, Clay City Quad. 500 55 4000 1300 5700 1400 <LOD 240 owell County, Clay City Quad. 500 57 4000 1300 3700 1400 <LOD 260 owell County, Clay City Quad. <LOD 19 <LOD 240 530 210 <LOD 64 owell County, Clay City Quad. 60 14 410 180 440 210 <LOD 64 owell County, Clay City Quad. 18 12 250 120 <LOD 240 <LOD 59 owell County, Clay City Quad. 49 13 350 160 430 210 <LOD 63 

156

Site Location As As Error Co Co Error Cr Cr Error Cu Cu Error 

ppm ppm ppm ppm ppm ppm ppm ppm 

owell County, Clay City Quad. 280 41 3300 1100 4500 1200 <LOD 210 owell County, Clay City Quad. 110 23 1300 420 1600 480 <LOD 110 owell County, Clay City Quad. 92 18 770 330 840 370 <LOD 85 owell County, Clay City Quad. <LOD 16 340 140 290 170 220 52 owell County, Clay City Quad. <LOD 22 <LOD 240 <LOD 380 <LOD 82 owell County, Clay City Quad. <LOD 29 890 410 850 480 <LOD 99 

ction. LOD is variable for each sample and depends on counting statistics. 

157

158

Fe Error Mn Mn Error Mo Mo Error Ni Ni Error Pb Pb Error Rb

ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm

0 460 <LOD 600 13 6.5 270 120 <LOD 24 610 500 <LOD 650 14 7.0 <LOD 200 <LOD 26 570 480 <LOD 630 <LOD 11 <LOD 210 <LOD 29 30

0 1100 <LOD 1200 22 6.5 <LOD 250 <LOD 24 39

0 3100 <LOD 2800 120 13 <LOD 540 <LOD 36 <LOD

0 2100 <LOD 2300 120 16 <LOD 480 <LOD 42 72

0 4500 <LOD 3500 140 12 <LOD 650 <LOD 37 <LOD

0 2200 <LOD 2300 100 14 <LOD 470 <LOD 44 640 2500 <LOD 2400 72 13 <LOD 500 <LOD 42 700 1100 <LOD 1200 120 10 <LOD 260 54 20 1300 850 <LOD 1000 95 8.6 <LOD 210 35 17 1600 580 <LOD 660 81 6.9 <LOD 150 24 13 1400 1000 <LOD 1200 92 10 <LOD 240 <LOD 28 1300 1200 <LOD 1300 70 9.7 <LOD 300 <LOD 30 140

0 770 <LOD 960 55 13 <LOD 320 <LOD 44 970 630 <LOD 770 51 9.9 <LOD 210 <LOD 29 87

0 830 <LOD 950 65 7.5 <LOD 200 23 15 1300 1900 <LOD 2100 99 21 <LOD 590 <LOD 70 86

0 870 <LOD 1100 54 13 <LOD 320 <LOD 45 90

0 2100 <LOD 2300 81 15 <LOD 470 <LOD 48 86

0 480 <LOD 590 64 8.1 <LOD 180 27 17 96

0 530 <LOD 630 60 6.5 <LOD 150 24 13 900 1600 <LOD 1700 72 9.4 <LOD 330 <LOD 29 930 1200 <LOD 1300 80 12 <LOD 300 <LOD 36 740 1300 <LOD 1500 67 15 <LOD 390 <LOD 47 590 1700 <LOD 1800 100 13 <LOD 410 <LOD 42 630 1300 <LOD 1400 20 6.7 <LOD 300 <LOD 22 <LOD
159

Fe Error Mn Mn Error Mo Mo Error Ni Ni Error Pb Pb Error Rb

ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm

0 2500 <LOD 2400 51 12 <LOD 500 <LOD 41 <LOD0 1700 <LOD 1800 50 9.3 660 260 <LOD 33 500 1300 <LOD 1500 59 12 <LOD 350 <LOD 35 830 780 <LOD 900 39 7.3 <LOD 210 24 16 850 920 <LOD 990 50 6.5 <LOD 210 <LOD 21 860 820 <LOD 920 52 6.6 <LOD 200 23 14 840 550 <LOD 630 170 7.3 <LOD 140 29 11 130

0 1900 <LOD 1800 190 11 <LOD 320 <LOD 23 59

0 1400 <LOD 1500 130 9.3 <LOD 300 35 17 79

0 2600 2600 1500 110 8.6 <LOD 410 208 28 39

0 730 <LOD 810 480 10 280 110 118 15 1400 1300 <LOD 1300 330 9.7 <LOD 260 246 21 920 820 <LOD 890 400 10 210 120 153 17 120

0 3500 <LOD 2500 42 6 <LOD 470 81 20 <LOD0 4700 <LOD 3300 240 12 <LOD 600 89 26 <LOD

0 420 <LOD 510 37 4.3 150 76 18 8.9 1200 360 <LOD 440 38 3.9 120 68 18 8.4 120

0 390 1200 380 14 5.3 170 97 21 14 48

0 4100 <LOD 3100 170 11 <LOD 560 45 22 <LOD

0 410 <LOD 480 160 6.3 <LOD 110 30 9.9 130

0 9400 <LOD 5000 450 19 1000 630 <LOD 47 <LOD0 8800 <LOD 5000 270 17 <LOD 930 <LOD 51 <LOD

0 540 <LOD 620 91 5.6 160 91 31 11 1400 610 <LOD 680 84 5.6 <LOD 150 22 11 1500 410 <LOD 480 66 4.9 <LOD 120 22 9.8 1200 550 <LOD 630 59 5.1 150 93 28 11 110
Fe Error Mn Mn Error Mo Mo Error Ni Ni Error Pb Pb Error Rb 

ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm 

0 7200 <LOD 4200 220 13 1300 530 <LOD 41 <LOD 

0 1700 <LOD 1700 73 7.5 <LOD 320 25 16 25 0 1300 <LOD 1300 350 10 270 170 33 13 75 0 460 <LOD 530 44 4.1 370 88 28 9.3 98 0 510 820 440 18 5.4 <LOD 150 23 13 44 

0 1700 <LOD 1700 <LOD 7.2 350 200 71 17 <LOD 

ction. LOD is variable for each sample and depends on counting statistics. 

160

 Se Se Error Sr Sr Error Zn Zn Error Zr Zr Error 

ppm ppm ppm ppm ppm ppm ppm ppm 

9 <LOD 14 55 8.8 300 54 41 7.8 

0 <LOD 15 59 9.5 <LOD 64 46 8.5 

3 <LOD 15 66 11 2800 150 15 8.2 2 <LOD 13 50 8.5 220 50 31 7.3 

9 <LOD 21 24 12 150 70 37 11 8 <LOD 26 45 15 <LOD 120 65 15 3 <LOD 20 53 12 320 72 25 11 7 <LOD 22 42 14 <LOD 110 50 13 8 <LOD 20 73 15 <LOD 110 62 14 4 <LOD 14 60 9.4 <LOD 56 88 9.7 4 <LOD 13 49 8.4 <LOD 55 70 8.4 

 <LOD 10 44 6.7 <LOD 42 84 7.2 

5 <LOD 15 45 9.9 <LOD 66 76 10 6 <LOD 15 47 10 <LOD 62 83 10 8 <LOD 24 46 14 <LOD 100 51 13 4 <LOD 18 40 11 <LOD 82 70 11 2 <LOD 11 51 8 <LOD 50 88 8.3 5 <LOD 35 <LOD 30 <LOD 200 48 20 8 <LOD 23 46 15 <LOD 110 44 14 0 <LOD 25 45 16 <LOD 130 44 15 

 <LOD 14 41 8.4 <LOD 62 70 8.6 

2 <LOD 11 32 6.4 <LOD 43 82 7.0 

4 <LOD 15 42 9.9 <LOD 72 61 9.8 5 <LOD 19 32 11 <LOD 90 59 12 7 <LOD 25 31 15 150 94 42 14 5 <LOD 21 44 13 <LOD 100 57 13 

 <LOD 14 <LOD 11 370 63 <LOD 9.2 

161

 Se Se Error Sr Sr Error Zn Zn Error Zr Zr Error 

ppm ppm ppm ppm ppm ppm ppm ppm 

6 <LOD 24 30 13 190 84 <LOD 17 2 <LOD 18 36 11 250 71 29 9.5 7 <LOD 22 54 13 <LOD 91 72 13 

 <LOD 13 110 10 95 40 <LOD 14 

9 <LOD 11.1 53 7.5 <LOD 48 62 6.9 8 <LOD 11.4 41 7.1 <LOD 48 79 7.2 

 <LOD 8.7 35 5.4 <LOD 36 120 6.4 

 <LOD 13.5 66 9.0 <LOD 51 110 9.4  <LOD 12.9 53 8.5 <LOD 52 89 8.8 

2 33 17.7 240 13 170 49 <LOD 13 

9 19 6.5 69 5.8 200 29 71 5.5 2 19 8.1 63 6.7 420 42 63 6.2 0 13 6.6 79 6.4 140 30 70 5.9 5 16 9.3 21 7.7 <LOD 59 <LOD 9.6 

5 39 13 63 11 86 52 26 9.5 

5 12 5.1 72 5.3 60 21 120 5.5 8 21 5.1 64 4.7 98 21 98 4.8 3 <LOD 12 290 12 <LOD 47 19 7.0 

5 20 12 95 11 2500 120 47 9.7 

0 <LOD 7.8 87 5.7 180 27 120 5.8 

7 <LOD 26 49 14 110 73 <LOD 18 7 37 19 86 16 <LOD 110 <LOD 20 

0 <LOD 9 160 7.4 40 24 89 6.0 

 <LOD 8.4 110 6.7 57 24 97 6.1 

7 9.2 5.5 86 5.8 110 24 81 5.3 

 8.9 5.8 110 6.6 35 23 90 5.8 

162

 Se Se Error Sr Sr Error Zn Zn Error Zr Zr Error 

ppm ppm ppm ppm ppm ppm ppm ppm 

5 28 15 100 14 130 64 <LOD 16 

8 <LOD 13 94 9.0 72 39 100 8.8 9 <LOD 10 110 7.8 46 29 110 7.3 7 15 5.2 55 4.8 450 35 70 4.7 2 <LOD 9.9 99 7.9 48 31 84 7.2 4 <LOD 12 78 8.1 <LOD 50 <LOD 8.4 

ction. LOD is variable for each sample and depends on counting statistics. 

163

de Longitude Sample Description Site Location As As Error 

ppm ppm 

5" 83°39'20" Pyrite on coal Nally Hamilton-Long Fork Mine 21 9.1 5" 83°39'20" Pyrite nodule(?) in coal Nally Hamilton-Long Fork Mine 310 31 5" 83°39'20" Pyrite layer in coal (0 cm bench sample) Nally Hamilton-Long Fork Mine 1800 130 5" 83°39'20" Pyrite 76 cm from bench top; 20 cm below Ky-36) Nally Hamilton-Long Fork Mine 170 49 7" 82°38'00" Coal in thrust -- Lee Formation? Pine Mountain Trust Footwall 74 8.7 7" 82°38'00" Lower coal (higher S, cleaner relative to KY-38R) Pine Mountain Trust Footwall <LOD 8.7 7" 82°38'00" Grunge coal just right of 01KY-39R Pine Mountain Trust Footwall <LOD 35 

Taylor Coal--high S, thin seam around corner Hindman road cut 41 25 Taylor coal as above Hindman road cut 58 21 

3" 83°04'13" pyrite on coal H5A-3 mine 75 12 3" 83°04'13" pyrite on corner of oblong block of coal H5A-3 mine 490 47 3" 83°04'13" sulfide along cleat H5A-3 mine 350 26 

ction. LOD is variable for each sample and depends on counting statistics. 

164

Co Co Error Fe Fe Error Mo Mo Error Pb Pb Error Rb Rb Error 

ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm 

240 110 15000 350 <LOD 3.9 18 7.3 <LOD 4.2 

<LOD 720 120000 2000 <LOD 7.1 <LOD 25 <LOD 7.5 

2400 1500 320000 9000 35 14 100 53 <LOD 17 2000 920 140000 4000 16 10 <LOD 49 <LOD 12 

<LOD 58 2600 120 3.8 2.2 18 5.8 26 3.1 <LOD 53 1900 110 15 2.3 12 5.3 6.9 2.2 <LOD 480 27000 1100 14 8.2 <LOD 31 120 15 

590 260 28000 860 11 5.8 130 22 14 6.7 

<LOD 330 26000 780 15 5.4 66 17 <LOD 8.0 

590 210 51000 750 <LOD 4.2 <LOD 12 <LOD 4.2 

1600 700 160000 3100 <LOD 9.2 <LOD 35 <LOD 10 2500 540 270000 2800 <LOD 6.2 38 15 <LOD 6.2 

ction. LOD is variable for each sample and depends on counting statistics. 

165

Se Se Error Sr Sr Error Zn Zn Error Zr Zr Error 

ppm ppm ppm ppm ppm ppm ppm ppm 

9.7 4.4 74 4.7 <LOD 24 <LOD 3.9 

34 11 38 7.8 <LOD 53 <LOD 8.1 

120 37 <LOD 28 <LOD 150 <LOD 23 

57 22 <LOD 21 <LOD 110 <LOD 16 

6.9 3.5 65 3.7 <LOD 17 15 2.4 6.9 3.3 25 3.0 <LOD 17 <LOD 2.7 

<LOD 15 45 11 97 54 82 11 

30 10 57 8.1 <LOD 48 45 7.6 

<LOD 12 33 6.9 <LOD 45 43 6.6 

13 5.3 39 4.6 31 20 <LOD 4.4 82 18 31 10 <LOD 69 <LOD 11 51 9.6 32 6.6 79 34 <LOD 7.5 

ction. LOD is variable for each sample and depends on counting statistics. 

166