# Patent

## Title
Production of ethylene with nanowire catalysts

## Abstract

Methods for producing ethylene using nanowires as heterogeneous catalysts are provided. The method includes, for example, an oxidative coupling of methane catalyzed by nanowires to provide ethylene.

## Background
CROSS-REFERENCE TO RELATED APPLICATION
The present application claims the benefit under 35 U.S.C. §119(e) of U.S. Provisional Patent Application No. 61/347,774 filed on May 24, 2010 and U.S. Provisional Patent Application No. 61/425,631 filed on Dec. 21, 2010 both of which are incorporated herein by reference in their entireties.


BACKGROUND
Technical Field
This invention is generally related to novel nanowire catalysts and, more specifically, to nanowires useful as heterogeneous catalysts in a variety of catalytic reactions, such as the oxidative coupling of methane to ethylene.
Description of the Related Art
Catalysis is the process in which the rate of a chemical reaction is either increased or decreased by means of a catalyst. Positive catalysts increase the speed of a chemical reaction, while negative catalysts slow it down. Substances that increase the activity of a catalyst are referred to as promoters or activators, and substances that deactivate a catalyst are referred to as catalytic poisons or deactivators. Unlike other reagents, a catalyst is not consumed by the chemical reaction, but instead participates in multiple chemical transformations. In the case of positive catalysts, the catalytic reaction generally has a lower rate-limiting free energy change to the transition state than the corresponding uncatalyzed reaction, resulting in an increased reaction rate at the same temperature. Thus, at a given temperature, a positive catalyst tends to increase the yield of desired product while decreasing the yield of undesired side products. Although catalysts are not consumed by the reaction itself, they may be inhibited, deactivated or destroyed by secondary processes, resulting in loss of catalytic activity.
Catalysts are generally characterized as either heterogeneous or homogeneous. Heterogeneous catalysts exist in a different phase than the reactants (e.g. a solid metal catalyst and gas phase reactants), and the catalytic reaction generally occurs on the surface of the heterogeneous catalyst. Thus, for the catalytic reaction to occur, the reactants must diffuse to and/or adsorb onto the catalyst surface. This transport and adsorption of reactants is often the rate limiting step in a heterogeneous catalysis reaction. Heterogeneous catalysts are also generally easily separable from the reaction mixture by common techniques such as filtration or distillation.
In contrast to a heterogeneous catalyst, a homogenous catalyst exists in the same phase as the reactants (e.g., a soluble organometallic catalyst and solvent-dissolved reactants). Accordingly, reactions catalyzed by a homogeneous catalyst are controlled by different kinetics than a heterogeneously catalyzed reaction. In addition, homogeneous catalysts can be difficult to separate from the reaction mixture.
While catalysis is involved in any number of technologies, one particular area of importance is the petrochemical industry. At the foundation of the modern petrochemical industry is the energy-intensive endothermic steam cracking of crude oil. Cracking is used to produce nearly all the fundamental chemical intermediates in use today. The amount of oil used for cracking and the volume of green house gases (GHG) emitted in the process are quite large: cracking consumes nearly 10% of the total oil extracted globally and produces 200M metric tons of CO2 equivalent every year (Ren, T, Patel, M. Res. Conserv. Recycl. 53:513, 2009). There remains a significant need in this field for new technology directed to the conversion of unreactive petrochemical feedstocks (e.g. paraffins, methane, ethane, etc.) into reactive chemical intermediates (e.g. olefins), particularly with regard to highly selective heterogeneous catalysts for the direct oxidation of hydrocarbons.
While there are multistep paths to convert methane to certain specific chemicals using first; high temperature steam reforming to syngas (a mixture of H2 and CO), followed by stochiometry adjustment and conversion to either methanol or, via the Fischer-Tropsch (F-T) synthesis, to liquid hydrocarbon fuels such as diesel or gasoline, this does not allow for the formation of certain high value chemical intermediates. This multi-step indirect method also requires a large capital investment in facilities and is expensive to operate, in part due to the energy intensive endothermic reforming step. (For instance, in methane reforming, nearly 40% of methane is consumed as fuel for the reaction.) It is also inefficient in that a substantial part of the carbon fed into the process ends up as the GHG CO2, both directly from the reaction and indirectly by burning fossil fuels to heat the reaction. Thus, to better exploit the natural gas resource, direct methods that are more efficient, economical and environmentally responsible are required.
One of the reactions for direct natural gas activation and its conversion into a useful high value chemical, is the oxidative coupling of methane (“OCM”) to ethylene: 2CH4+O2→C2H4+2H2O, See, e.g., Zhang, Q., Journal of Natural Gas Chem., 12:81, 2003; Olah, G. “Hydrocarbon Chemistry”, Ed. 2, John Wiley & Sons (2003). This reaction is exothermic (ΔH=−67 kcals/mole) and has only been shown to occur at very high temperatures (>700° C.). Although the detailed reaction mechanism is not fully characterized, experimental evidence suggests that free radical chemistry is involved. (Lunsford, J. Chem. Soc., Chem. Comm., 1991; H. Lunsford, Angew. Chem., Int. Ed. Engl., 34:970, 1995). In the reaction, methane (CH4) is activated on the catalyst surface, forming methyl radicals which then couple in the gas phase to form ethane (C2H6), followed by dehydrogenation to ethylene (C2H4). Several catalysts have shown activity for OCM, including various forms of iron oxide, V2O5, MoO3, CO3O4, Pt—Rh, Li/ZrO2, Ag—Au, Au/CO3O4, Co/Mn, CeO2, MgO, La2O3, Mn3O4, Na2WO4, MnO, ZnO, and combinations thereof, on various supports. A number of doping elements have also proven to be useful in combination with the above catalysts.
Since the OCM reaction was first reported over thirty years ago, it has been the target of intense scientific and commercial interest, but the fundamental limitations of the conventional approach to C—H bond activation appear to limit the yield of this attractive reaction. Specifically, numerous publications from industrial and academic labs have consistently demonstrated characteristic performance of high selectivity at low conversion of methane, or low selectivity at high conversion (J. A. Labinger, Cat. Lett., 1:371, 1988). Limited by this conversion/selectivity threshold, no OCM catalyst has been able to exceed 20-25% combined C2 yield (i.e. ethane and ethylene), and all such yields are reported at extremely high temperatures (>800 C). This lack of progress with conventional heterogeneous catalysts and reactors during the last third of a century suggests that conventional approaches have reached the limit of their performance.
In this regard, it is believed that the low yield of desired products (i.e. C2H4 and C2H6) is caused by the unique homogeneous/heterogeneous nature of the reaction. Specifically, due to the high reaction temperature, a majority of methyl radicals escape the catalyst surface and enter the gas phase. There, in the presence of oxygen and hydrogen, multiple side reactions are known to take place (J. A. Labinger, Cat. Lett., 1:371, 1988). The non-selective over-oxidation of hydrocarbons to CO and CO2 (e.g., complete oxidation) is the principal competing fast side reaction. Other undesirable products (e.g. methanol, formaldehyde) have also been observed and rapidly react to form CO and CO2.
In order to dramatically increase the yield of OCM, a catalyst optimized for the activation of the C—H bond of methane at lower temperatures (e.g. 500-900° C.) is required. While the above discussion has focused on the OCM reaction, numerous other catalytic reactions (as discussed in greater detail below) would significantly benefit from catalytic optimization. Accordingly, there remains a need in the art for improved catalysts and, more specifically, a need for novel approaches to catalyst design for improving the yield of, for example, the OCM reaction and other catalyzed reactions. The present invention fulfills these needs and provides further related advantages.
BRIEF SUMMARY
In brief, nanowires and related methods are disclosed. In one embodiment, the disclosure provides a catalyst comprising an inorganic catalytic polycrystalline nanowire, the nanowire having a ratio of effective length to actual length of less than one and an aspect ratio of greater than ten as measured by TEM in bright field mode at 5 keV, wherein the nanowire comprises one or more elements from any of Groups 1 through 7, lanthanides, actinides or combinations thereof.
In another embodiment, the disclosure provides a catalytic material comprising a plurality of inorganic catalytic polycrystalline nanowires, the plurality of nanowires having a ratio of average effective length to average actual length of less than one and an average aspect ratio of greater than ten as measured by TEM in bright field mode at 5 keV, wherein the plurality of nanowires comprises one or more elements from any of Groups 1 through 7, lanthanides, actinides or combinations thereof.
In yet another embodiment, a method for preparing inorganic catalytic polycrystalline nanowires is provided, the nanowires each having a ratio of effective length to actual length of less than one and an aspect ratio of greater than ten as measured by TEM in bright field mode at 5 keV, wherein the nanowires each comprise one or more elements selected from Groups 1 through 7, lanthanides, actinides or combinations thereof. The method comprises:
admixing (A) with a mixture comprising (B) and (C);
admixing (B) with a mixture comprising (A) and (C); or
admixing (C) with a mixture comprising (A) and (B)
to obtain a mixture comprising (A), (B) and (C), wherein (A), (B), and (C) comprise, respectively:
(A) a biological template;
(B) one or more salts comprising one or more metal elements from any of Groups 1 through 7, lanthanides, actinides or combinations thereof; and
(C) one or more anion precursors.
In another embodiment, a process for the preparation of ethylene from methane comprising contacting a mixture comprising oxygen and methane at a temperature below 900° C. with a catalyst comprising one or more inorganic catalytic nanowires is provided.
In yet another embodiment, the present disclosure provides for the use of a catalytic nanowire in a catalytic reaction. The nanowire may have any composition or morphology, for example the nanowire may comprise one or more elements from any of Groups 1 through 7, lanthanides, actinides or combinations thereof, and the nanowire may optionally be a polycrystalline nanowire, the nanowire having a ratio of effective length to actual length of less than one and an aspect ratio of greater than ten as measured by TEM in bright field mode at 5 keV.
In another embodiment, the present disclosure provides a method for preparing a downstream product of ethylene, the method comprising converting ethylene to a downstream product of ethylene, wherein the ethylene has been prepared via a reaction employing a catalytic nanowire. In certain embodiments, the nanowire comprises one or more elements from any of Groups 1 through 7, lanthanides, actinides or combinations thereof, and the nanowire may optionally be a polycrystalline nanowire, the nanowire having a ratio of effective length to actual length of less than one and an aspect ratio of greater than ten as measured by TEM in bright field mode at 5 keV.
In another embodiment, the disclosure provides an inorganic nanowire comprising one or more metal elements from any of Groups 1 through 7, lanthanides, actinides or combinations thereof, and a dopant comprising a metal element, a semi-metal element, a non-metal element or combinations thereof.
In another embodiment, the disclosure provides a method for preparing a metal oxide nanowire comprising a plurality of metal oxides (MxOy), the method comprising:
a) providing a solution comprising a plurality of biological templates;
(b) introducing at least one metal ion and at least one anion to the solution under conditions and for a time sufficient to allow for nucleation and growth of a nanowire comprising a plurality of metal salts (MmXnZp) on the template; and
(c) converting the nanowire (MmXnZp) to a metal oxide nanowire comprising a plurality of metal oxides (MxOy),
wherein:
M is, at each occurrence, independently a metal element from any of Groups 1 through 7, lanthanides or actinides;
X is, at each occurrence, independently hydroxides, carbonates, bicarbonates, phosphates, hydrogenphosphates, dihydrogenphosphates, sulfates, nitrates or oxalates;
Z is O;
n, m, x and y are each independently a number from 1 to 100; and
p is a number from 0 to 100.
In another embodiment, the disclosure provides a method for preparing a metal oxide nanowire, the method comprising:
(a) providing a solution comprising a plurality of biological templates; and
(b) introducing a compound comprising a metal to the solution under conditions and for a time sufficient to allow for nucleation and growth of a nanowire (MmYn) on the template;
wherein:
M is a metal element from any of Groups 1 through 7, lanthanides or actinides;
Y is O,
n and m are each independently a number from 1 to 100.
In another embodiment, the disclosure provides a method for preparing metal oxide nanowires in a core/shell structure, the method comprising:
(a) providing a solution comprising a plurality of biological templates;
(b) introducing a first metal ion and a first anion to the solution under conditions and for a time sufficient to allow for nucleation and growth of a first nanowire (M1m1X1n1Zp1) on the template; and
(c) introducing a second metal ion and optionally a second anion to the solution under conditions and for a time sufficient to allow for nucleation and growth of a second nanowire (M2m2X2n2Zp2) on the first nanowire (M1m1X1n1Zp1);
(d) converting the first nanowire (M1m1X1n1Zp1) and the second nanowire (M2m2X2n2Zp2) to respective metal oxide nanowires (M1x1Oy1) and (M2x2Oy2).
wherein:
M1 and M2 are the same or different and independently selected from a metal element from any of Groups 1 through 7, lanthanides or actinides;
X1 and X2 are the same or different and independently hydroxides, carbonates, bicarbonates, phosphates, hydrogenphosphates, dihydrogenphosphates, sulfates, nitrates or oxalates;
Z is O;
n1, m1, n2, m2, x1, y1, x2 and y2 are each independently a number from 1 to 100; and
p1 and p2 are each independently a number from 0 to 100.
In yet another embodiment, the present disclosure provides a method for the preparation of a downstream product of ethylene, the method comprising converting methane into ethylene in the presence of a catalytic nanowire and further oligomerizing the ethylene to prepare a downstream product of ethylene. In certain embodiments, the nanowire comprises one or more elements from any of Groups 1 through 7, lanthanides, actinides or combinations thereof, and the nanowire may optionally be a polycrystalline nanowire, the nanowire having a ratio of effective length to actual length of less than one and an aspect ratio of greater than ten as measured by TEM in bright field mode at 5 keV.
These and other aspects of the invention will be apparent upon reference to the following detailed description. To this end, various references are set forth herein which describe in more detail certain background information, procedures, compounds and/or compositions, and are each hereby incorporated by reference in their entirety.



BRIEF DESCRIPTION OF THE SEVERAL VIEWS OF THE DRAWINGS
In the drawings, the sizes and relative positions of elements in the drawings are not necessarily drawn to scale. For example, the various elements and angles are not drawn to scale, and some of these elements are arbitrarily enlarged and positioned to improve drawing legibility. Further, the particular shapes of the elements as drawn are not intended to convey any information regarding the actual shape of the particular elements, and have been selected solely for ease of recognition in the drawings.
FIG. 1 schematically depicts a first part of an OCM reaction at the surface of a metal oxide catalyst.
FIG. 2 shows a high throughput work flow for synthetically generating and testing libraries of nanowires.
FIGS. 3A and 3B illustrate a nanowire in one embodiment.
FIGS. 4A and 4B illustrate a nanowire in a different embodiment.
FIGS. 5A and 5B illustrate a plurality of nanowires.
FIG. 6 illustrates a filamentous bacteriophage.
FIG. 7 is a flow chart of a nucleation process for forming a metal oxide nanowire.
FIG. 8 is a flow chart of a sequential nucleation process for forming a nanowire in a core/shell configuration.
FIG. 9 schematically depicts a carbon dioxide reforming reaction on a catalytic surface.
FIG. 10 is a flow chart for data collection and processing in evaluating catalytic performance.
FIG. 11 illustrates a number of downstream products of ethylene.
FIG. 12 depicts a representative process for preparing a lithium doped MgO nanowire.
FIG. 13 presents the X-ray diffraction patterns of Mg(OH)2 nanowires and MgO nanowires.
FIG. 14 shows a number of MgO nanowires each synthesized in the presence of a different phage sequence.
FIG. 15 depicts a representative process for growing a core/shell structure of ZrO2/La2O3 nanowires with Strontium dopant.
FIG. 16 is a gas chromatograph showing the formation of OCM products at 700° C. when passed over a Sr doped La2O3 nanowire.
FIGS. 17A-17C are graphs showing methane conversion, C2 selectivity, and C2 yield, in an OCM reaction catalyzed by Sr doped La2O3 nanowires vs. the corresponding bulk material in the same reaction temperature range.
FIGS. 18A-18B are graphs showing the comparative results of C2 selectivities in an OCM reaction catalyzed by Sr doped La2O3 nanowire catalysts prepared by different synthetic conditions.
FIG. 19 is a graph comparing ethane and propane conversions in ODH reactions catalyzed by either Li doped MgO phage-based nanowires or Li doped MgO bulk catalyst.
FIG. 20 is a TEM image showing La2O3 nanowires prepared under non-template-directed conditions.
FIG. 21 depicts OCM and ethylene oligomerization modules.
FIG. 22 shows methane conversion, C2 selectivity and C2 yield in a reaction catalyzed by a representative nanowire at a CH4/O2 ratio of 4.
FIG. 23 shows methane conversion, C2 selectivity and C2 yield in a reaction catalyzed by a representative nanowire at a CH4/O2 ratio of 5.5.
FIG. 24 is a graph showing methane conversion, C2 selectivity and C2 yield in a reaction catalyzed by Mg/Na doped La2O3 nanowires.



DETAILED DESCRIPTION OF THE INVENTION
In the following description, certain specific details are set forth in order to provide a thorough understanding of various embodiments. However, one skilled in the art will understand that the invention may be practiced without these details. In other instances, well-known structures have not been shown or described in detail to avoid unnecessarily obscuring descriptions of the embodiments. Unless the context requires otherwise, throughout the specification and claims which follow, the word “comprise” and variations thereof, such as, “comprises” and “comprising” are to be construed in an open, inclusive sense, that is, as “including, but not limited to.” Further, headings provided herein are for convenience only and do not interpret the scope or meaning of the claimed invention.
Reference throughout this specification to “one embodiment” or “an embodiment” means that a particular feature, structure or characteristic described in connection with the embodiment is included in at least one embodiment. Thus, the appearances of the phrases “in one embodiment” or “in an embodiment” in various places throughout this specification are not necessarily all referring to the same embodiment. Furthermore, the particular features, structures, or characteristics may be combined in any suitable manner in one or more embodiments. Also, as used in this specification and the appended claims, the singular forms “a,” “an,” and “the” include plural referents unless the content clearly dictates otherwise. It should also be noted that the term “or” is generally employed in its sense including “and/or” unless the content clearly dictates otherwise.
As discussed above, heterogeneous catalysis takes place between several phases. Generally, the catalyst is a solid, the reactants are gases or liquids and the products are gases or liquids. Thus, a heterogeneous catalyst provides a surface that has multiple active sites for adsorption of one more gas or liquid reactants. Once adsorbed, certain bonds within the reactant molecules are weakened and dissociate, creating reactive fragments of the reactants, e.g., in free radical forms. One or more products are generated as new bonds between the resulting reactive fragments form, in part, due to their proximity to each other on the catalytic surface.
As an example, FIG. 1 shows schematically the first part of an OCM reaction that takes place on the surface of a metal oxide catalyst 10 which is followed by methyl radical coupling in the gas phase. A crystal lattice structure of metal atoms 14 and oxygen atoms 20 are shown, with an optional dopant 24 incorporated into the lattice structure. In this reaction, a methane molecule 28 comes into contact with an active site (e.g., surface oxygen 30) and becomes activated when a hydrogen atom 34 dissociates from the methane molecule 28. As a result, a methyl radical 40 is generated on or near the catalytic surface. Two methyl radicals thus generated can couple in the gas phase to create ethane and/or ethylene, which are collectively referred to as the “C2” coupling products.
It is generally recognized that the catalytic properties of a catalyst strongly correlate to its surface morphology. Typically, the surface morphology can be defined by geometric parameters such as: (1) the number of surface atoms (e.g., the surface oxygen of FIG. 1) that coordinate to the reactant; and (2) the degree of coordinative unsaturation of the surface atoms, which is the coordination number of the surface atoms with their neighboring atoms. For example, the reactivity of a surface atom decreases with decreasing coordinative unsaturation. For example, for the dense surfaces of a face-centered crystal, a surface atom with 9 surface atom neighbors will have a different reactivity than one with 8 neighbors. Additional surface characteristics that may contribute to the catalytic properties include, for example, crystal dimensions, lattice distortion, surface reconstructions, defects, grain boundaries, and the like. See, e.g., Van Santen R. A. et al New Trends in Materials Chemistry 345-363 (1997).
Catalysts in nano-size dimensions have substantially increased surface areas compared to their counterpart bulk materials. The catalytic properties are expected to be enhanced as more surface active sites are exposed to the reactants. Typically in traditional preparations, a top-down approach (e.g., milling) is adopted to reduce the size of the bulk material. However, the surface morphologies of such catalysts remain largely the same as those of the parent bulk material.
Various embodiments described herein are directed to nanowires with controllable or tunable surface morphologies. In particular, nanowires synthesized by a “bottom up” approach, by which inorganic polycrystalline nanowires are nucleated from solution phase in the presence of a template, e.g., a linear or anisotropic shaped biological template. By varying the synthetic conditions, nanowires having different compositions and/or different surface morphologies are generated.
In contrast to a bulk catalyst of a given elemental composition, which is likely to have a particular corresponding surface morphology, diverse nanowires with different surface morphologies can be generated despite having the same elemental composition. In this way, morphologically diverse nanowires can be created and screened according to their catalytic activity and performance parameters in any given catalytic reaction. Advantageously, the nanowires disclosed herein and methods of producing the same have general applicability to a wide variety of heterogeneous catalyses, including without limitation: oxidative coupling of methane (e.g., FIG. 1), oxidative dehydrogenation of alkanes to their corresponding alkenes, selective oxidation of alkanes to alkenes and alkynes, oxidation of carbon monoxide, dry reforming of methane, selective oxidation of aromatics, Fischer-Tropsch reaction, hydrocarbon cracking and the like.
FIG. 2 schematically shows a high throughput work flow for synthetically generating libraries of morphologically or compositionally diverse nanowires and screening for their catalytic properties. An initial phase of the work flow involves a primary screening, which is designed to broadly and efficiently screen a large and diverse set of nanowires that logically could perform the desired catalytic transformation. For example, certain doped bulk metal oxides (e.g., Li/MgO and Sr/La2O3) are known catalysts for the OCM reaction. Therefore, nanowires of various metal oxide compositions and/or surface morphologies can be prepared and evaluated for their catalytic performances in an OCM reaction.
More specifically, the work flow 100 begins with designing synthetic experiments based on solution phase template formations (block 110). The synthesis, subsequent treatments and screenings can be manual or automated. As will be discussed in more detail herein, by varying the synthetic conditions, nanowires can be prepared with various surface morphologies and/or compositions in respective microwells (block 114). The nanowires are subsequently calcined and then optionally doped (block 120). Optionally, the doped and calcined nanowires are further mixed with a catalyst support (block 122). Beyond the optional support step, all subsequent steps are carried out in a “wafer” format, in which nanowire catalysts are deposited in a quartz wafer that has been etched to create an ordered array of microwells. Each microwell is a self-contained reactor, in which independently variable processing conditions can be designed to include, without limitation, respective choices of elemental compositions, catalyst support, reaction precursors, templates, reaction durations, pH values, temperatures, ratio between reactants, gas flows, and calcining conditions (block 124). Due to design contrasts of some wafers, in some embodiments calcining and other temperature variables are identical in all microwells. A wafer map 130 can be created to correlate the processing conditions to the nanowire in each microwell. A library of diverse nanowires can be generated in which each library member corresponds to a particular set of processing conditions and corresponding compositional and/or morphological characteristics.
Nanowires obtained under various synthetic conditions are thereafter deposited in respective microwells of a wafer (140) for evaluating their respective catalytic properties in a given reaction (blocks 132 and 134). The catalytic performance of each library member can be screened serially by several known primary screening technologies, including scanning mass spectroscopy (SMS) (Symyx Technologies Inc., Santa Clara, Calif.). The screening process is fully automated, and the SMS tool can determine if a nanowire is catalytically active or not, as well as its relative strength as a catalyst at a particular temperature. Typically, the wafer is placed on a motion control stage capable of positioning a single well below a probe that flows the feed of the starting material over the nanowire surface and removes reaction products to a mass spectrometer and/or other detector technologies (blocks 134 and 140). The individual nanowire is heated to a preset reaction temperature, e.g., using a CO2 IR laser from the backside of the quartz wafer and an IR camera to monitor temperature and a preset mixture of reactant gases. The SMS tool collects data with regard to the consumption of the reactant(s) and the generation of the product(s) of the catalytic reaction in each well (block 144), and at each temperature and flow rate.
The SMS data obtained as described above provide information on relative catalytic properties among all the library members (block 150). In order to obtain more quantitative data on the catalytic properties of the nanowires, possible hits that meet certain criteria are subjected to a secondary screening (block 154). Typically, secondary screening technologies include a single, or alternatively multiple channel fixed-bed or fluidized bed reactors (as described in more detail herein). In parallel reactor systems or multi-channel fixed-bed reactor system, a single feed system supplies reactants to a set of flow restrictors. The flow restrictors divide the flows evenly among parallel reactors. Care is taken to achieve uniform reaction temperature between the reactors such that the various nanowires can be differentiated solely based on their catalytic performances. The secondary screening allows for accurate determination of catalytic properties such as selectivity, yield and conversion.(block 160). These results serve as a feedback for designing further nanowire libraries. Additional description of SMS tools in a combinatorial approach for discovering catalysts can be found in, e.g., Bergh, S. et al. Topics in Catalysts 23:1-4, 2003.
Thus, in accordance with various embodiments described herein, compositional and morphologically diverse nanowires can be rationally synthesized to meet catalytic performance criteria. These and other aspects of the present disclosure are described in more detail below.
Definitions
As used herein, and unless the context dictates otherwise, the following terms have the meanings as specified below.
“Catalyst” means a substance which alters the rate of a chemical reaction. A catalyst may either increase the chemical reaction rate (i.e. a “positive catalyst”) or decrease the reaction rate (i.e. a “negative catalyst”). Catalysts participate in a reaction in a cyclic fashion such that the catalyst is cyclically regenerated. “Catalytic” means having the properties of a catalyst.
“Nanoparticle” means a particle having at least one diameter on the order of nanometers (e.g. between about 1 and 100 nanometers).
“Nanowire” means a nanowire structure having at least one diameter on the order of nanometers (e.g. between about 1 and 100 nanometers) and an aspect ratio greater than 10:1. The “aspect ratio” of a nanowire is the ratio of the actual length (L) of the nanowire to the diameter (D) of the nanowire. Aspect ratio is expressed as L:D.
“Polycrystalline nanowire” means a nanowire having multiple crystal domains. Polycrystalline nanowires generally have different morphologies (e.g. bent vs. straight) as compared to the corresponding “single-crystalline” nanowires.
“Effective length” of a nanowire means the shortest distance between the two distal ends of a nanowire as measured by transmission electron microscopy (TEM) in bright field mode at 5 keV. “Average effective length” refers to the average of the effective lengths of individual nanowires within a plurality of nanowires.
“Actual length” of a nanowire means the distance between the two distal ends of a nanowire as traced through the backbone of the nanowire as measured by TEM in bright field mode at 5 keV. “Average actual length” refers to the average of the actual lengths of individual nanowires within a plurality of nanowires.
The “diameter” of a nanowire is measured in an axis perpendicular to the axis of the nanowire's actual length (i.e. perpendicular to the nanowires backbone). The diameter of a nanowire will vary from narrow to wide as measured at different points along the nanowire backbone. As used herein, the diameter of a nanowire is the most prevalent (i.e. the mode) diameter.
The “ratio of effective length to actual length” is determined by dividing the effective length by the actual length. A nanowire having a “bent morphology” will have a ratio of effective length to actual length of less than one as described in more detail herein. A straight nanowire will have a ratio of effective length to actual length equal to one as described in more detail herein.
“Inorganic” means a substance comprising a metal element. Typically, an inorganic can be one or more metals in its elemental state, or more preferably, a compound formed by a metal ion (Mn+, wherein n 1, 2, 3, 4, 5, 6 or 7) and an anion (Xm−, m is 1, 2, 3 or 4) which balance and neutralize the positive charges of the metal ion through electrostatic interactions. Non-limiting examples of inorganic compounds include oxides, hydroxides, halides, nitrates, sulfates, carbonates, acetates, oxalates, and combinations thereof, of metal elements. Other non-limiting examples of inorganic compounds include Li2CO3, LiOH, Li2O, LiCl, LiBr, LiI, Li2C2O4, Li2SO4, Na2CO3, NaOH, Na2O, NaCl, NaBr, NaI, Na2C2O4, Na2SO4, K2CO3, KOH, K2O, KCl, KBr, KI, K2C2O4, K2SO4, CsCO3, CsOH, Cs2O, CsCl, CsBr, CsI, CsC2O4, CsSO4, Be(OH)2, BeCO3, BeO, BeCl2, BeBr2, BeI2, BeC2O4. BeSO4, Mg(OH)2, MgCO3, MgO, MgCl2, MgBr2, MgI2, MgC2O4. MgSO4, Ca(OH)2, CaO, CaCl2, CaBr2, CaI2, Ca(OH)2, CaC2O4, CaSO4, Y2O3, Y2(CO3)3, Y(OH)3, YCl3, YBr3, YI3, Y2(C2O4)3, Y2(SO4)3, Zr(OH)4, ZrO(OH)2, ZrO2, ZrCl4, ZrBr4, ZrI4, Zr(C2O4)2, Zr(SO4)2, Ti(OH)4, TiO(OH)2, TiO2, TiCl4, TiBr4, TiI4, Ti(C2O4)2, Ti(SO4)2, BaO, Ba(OH)2, BaCO3, BaCl2, BaBr2, BaI2, BaC2O4, BaSO4, La(OH)3, La2O3, LaCl3, LaBr3, LaI3, La2(C2O4)3, La2(SO4)3, Ce(OH)4, CeO2, Ce2O3, CeCl4, CeBr4, CeI4, Ce(C2O4)2, Ce(SO4)2, ThO2, ThCl4, ThBr4, ThI4, Th(OH)4, Th(O2O4)2, Th(SO4)2, Sr(OH)2, SrCO3, SrO, SrCl2, SrBr2, SrI2, SrC2O4, SrSO4, Sm2O3, SmCl3, SmBr3, SmI3, Sm(OH)3, Sm2(CO3)3, Sm2(C2O3)3, Sm2(SO4)3, LiCa2Bi3O4Cl6, Na2WO4, K/SrCoO3, K/Na/SrCoO3, Li/SrCoO3, SrCoO3, molybdenum oxides, molybdenum hydroxides, molybdenum chlorides, molybdenum bromides, molybdenum iodides, molybdenum oxalates, molybdenum sulfates, manganese oxides, manganese chlorides, manganese bromides, manganese iodides, manganese hydroxides, manganese oxalates, manganese sulfates, manganese tugstates, vanadium oxides, vanadium chlorides, vanadium bromides, vanadium iodides, vanadium hydroxides, vanadium oxalates, vanadium sulfates, tungsten oxides, tungsten chlorides, tungsten bromides, tungsten iodides, tungsten hydroxides, tungsten oxalates, tungsten sulfates, neodymium oxides, neodymium chlorides, neodymium bromides, neodymium iodides, neodymium hydroxides, neodymium oxalates, neodymium sulfates, europium oxides, europium chlorides, europium bromides, europium iodides, europium hydroxides, europium oxalates, europium sulfates rhenium oxides, rhenium chlorides, rhenium bromides, rhenium iodides, rhenium hydroxides, rhenium oxalates, rhenium sulfates, chromium oxides, chromium chlorides, chromium bromides, chromium iodides, chromium hydroxides, chromium oxalates, chromium sulfates, potassium molybdenum oxides and the like.
“Salt” means a compound comprising negative and positive ions. Salts are generally comprised of metallic cations and non-metallic counter ions. Under appropriate conditions, e.g., the solution also comprises a template, the metal ion (Mn+) and the anion (Xm−) bind to the template to induce nucleation and growth of a nanowire of MmXn on the template. “Anion precursor” thus is a compound that comprises an anion and a cationic counter ion, which allows the anion (Xm−) dissociate from the cationic counter ion in a solution. Specific examples of the metal salt and anion precursors are described in further detail herein.
“Oxide” refers to a metal compound comprising oxygen. Examples of oxides include, but are not limited to, metal oxides (MxOy), metal oxyhalide (MxOyXz), metal oxynitrates (MxOy(NO3)z), metal phosphates (Mx(PO4)y), metal oxide carbonates (MxOy(CO3)z), metal carbonates and the like, wherein x, y and z are numbers from 1 to 100.
“Crystal domain” means a continuous region over which a substance is crystalline.
“Single-crystalline nanowires” means a nanowire having a single crystal domain.
“Template” is any synthetic and/or natural material that provides at least one nucleation site where ions can nucleate and grow to form nanoparticles. In certain embodiments, the templates can be a multi-molecular biological structure comprising one or more biomolecules. Typically, the biological template comprises multiple binding sites that recognize certain ions and allow for the nucleation and growth of the same. Non-limiting examples of biological templates include bacteriophages, amyloid fibers, viruses and capsids.
“Biomolecule” refers to any organic molecule of a biological origin. Biomolecule includes modified and/or degraded molecules of a biological origin. Non-limiting examples of biomolecules include peptides, proteins (including cytokines, growth factors, etc.), nucleic acids, polynucleotides, amino acids, antibodies, enzymes, and single-stranded or double-stranded nucleic acid, including any modified and/or degraded forms thereof.
“Amyloid fibers” refers to proteinaceous filaments of about 1-25 nm in diameter.
A “bacteriophage” or “phage” is any one of a number of viruses that infect bacteria. Typically, bacteriophages consist of an outer protein coat or “major coat protein” enclosing genetic material. A non-limiting example of a bacteriophage is the M13 bacteriophage. Non-limiting examples of bacteriophage coat proteins include the pIII, pV, pVIII, etc. protein as described in more detail below.
A “capsid” is the protein shell of a virus. A capsid comprises several oligomeric structural subunits made of proteins.
“Nucleation” refers to the process of forming a solid from solubilized particles, for example forming a nanowire in situ by converting a soluble precursor (e.g. metal and hydroxide ions) into nanocrystals in the presence of a template.
“Nucleation site” refers to a site on a template, for example a bacteriophage, where nucleation of ions may occur. Nucleation sites include, for example, amino acids having carboxylic acid (—COOH), amino (—NH3+ or —NH2), hydroxyl (—OH), and/or thiol (—SH) functional groups.
A “peptide” refers to two or more amino acids joined by peptide (amide) bonds. The amino-acid building blocks (subunits) include naturally occurring α-amino acids and/or unnatural amino acids, such as β-amino acids and homoamino acids. An unnatural amino acid can be a chemically modified form of a natural amino acid. Peptides can be comprised of 2 or more, 5 or more, 10 or more, 20 or more, or 40 or more amino acids.
“Peptide sequence” refers to the sequence of amino acids within a peptide or protein.
“Protein” refers to a natural or engineered macromolecule having a primary structure characterized by peptide sequences. In addition to the primary structure, proteins also exhibit secondary and tertiary structures that determine their final geometric shapes.
“Polynucleotide” means a molecule comprised of two or more nucleotides connected via an internucleotide bond (e.g. a phosphate bond). Polynucleotides may be comprised of both ribose and/or deoxy ribose nucleotides. Examples of nucleotides include guanosine, adenosine, thiamine, and cytosine, as well as unnatural analogues thereof.
“Nucleic acid” means a macromolecule comprised of polynucleotides. Nucleic acids may be both single stranded and double stranded, and, like proteins, can exhibit secondary and tertiary structures that determine their final geometric shapes.
“Nucleic acid sequence” of “nucleotide sequence” refers to the sequence of nucleotides within a polynucleotide or nucleic acid.
“Anisotropic” means having an aspect ratio greater than one.
“Anisotropic biomolecule” means a biomolecule, as defined herein, having an aspect ratio greater than 1. Non-limiting examples of anisotropic biomolecules include bacteriophages, amyloid fibers, and capsids.
“Turnover number” is a measure of the number of reactant molecules a catalyst can convert to product molecules per unit time.
“Dopant” or “doping agent” is an impurity added to or incorporated within a catalyst to optimize catalytic performance (e.g. increase or decrease catalytic activity). As compared to the undoped catalyst, a doped catalyst may increase or decrease the selectivity, conversion, and/or yield of a reaction catalyzed by the catalyst.
“Atomic percent” (at %) or “atomic ratio” when used in the context of nanowire dopants refers to the ratio of the total number of dopant atoms to the total number of non-oxygen atoms in the nanowire. For example, the atomic percent of dopant in a lithium doped Mg6MnO8 nanowire is determined by calculating the total number of lithium atoms and dividing by the sum of the total number of magnesium and manganese atoms and multiplying by 100 (i.e., atomic percent of dopant=[Li atoms/(Mg atoms+Mn atoms)]×100)
“Group 1” elements include lithium (Li), sodium (Na), potassium (K), rubidium (Rb), cesium (Cs), and francium (Fr).
“Group 2” elements include beryllium (Be), magnesium (Mg), calcium (Ca), strontium (Sr), barium (Ba), and radium (Ra).
“Group 3” elements include scandium (Sc) and yttrium (Y).
“Group 4” elements include titanium (Ti), zirconium (Zr), halfnium (Hf), and rutherfordium (Rf).
“Group 5” elements include vanadium (V), niobium (Nb), tantalum (Ta), and dubnium (Db).
“Group 6” elements include chromium (Cr), molybdenum (Mo), tungsten (W), and seaborgium (Sg).
“Group 7” elements include manganese (Mn), technetium (Tc), rhenium (Re), and bohrium (Bh).
“Group 8” elements include iron (Fe), ruthenium (Ru), osmium (Os), and hassium (Hs).
“Group 9” elements include cobalt (Co), rhodium (Rh), iridium (Ir), and meitnerium (Mt).
“Group 10” elements include nickel (Ni), palladium (Pd), platinum (Pt) and darmistadium (Ds).
“Group 11” elements include copper (Cu), silver (Ag), gold (Au), and roentgenium (Rg).
“Group 12” elements include zinc (Zn), cadmium (Cd), mercury (Hg), and copernicium (Cn).
“Lanthanides” include lanthanum (La), cerium (Ce), praseodymium (Pr), neodymium (Nd), promethium (Pm), samarium (Sm), europium (Eu), gadolinium (Gd), terbium (Tb), dysprosium (Dy), holmium (Ho), erbium (Er), thulium (Tm), yitterbium (Yb), and lutetium (Lu).
“Actinides” include actinium (Ac), thorium (Th), protactinium (Pa), uranium (U), neptunium (Np), plutonium (Pu), americium (Am), curium (Cm), berklelium (Bk), californium (Cf), einsteinium (Es), fermium (Fm), mendelevium (Md), nobelium (No), and lawrencium (Lr).
“Metal element” or “metal” is any element, except hydrogen, selected from Groups 1 through XII, lanthanides, actinides, aluminum (Al), gallium (Ga), indium (In), tin (Sn), thallium (Tl), lead (Pb), and bismuth (Bi). Metal elements include metal elements in their elemental form as well as metal elements in an oxidized or reduced state, for example, when a metal element is combined with other elements in the form of compounds comprising metal elements. For example, metal elements can be in the form of hydrates, salts, oxides, as well as various polymorphs thereof, and the like.
“Semi-metal element” refers to an element selected from boron (B), silicon (Si), germanium (Ge), arsenic (As), antimony (Sb), tellurium (Te), and polonium (Po).
“Non-metal element” refers to an element selected from carbon (C), nitrogen (N), oxygen (O), fluorine (F), phosphorus (P), sulfur (S), chlorine (Cl), selenium (Se), bromine (Br), iodine (I), and astatine (At).
“Conversion” means the mole fraction (i.e., percent) of a reactant converted to a product or products.
“Selectivity” refers to the percent of converted reactant that went to a specified product, e.g., C2 selectivity is the % of methane that formed ethane and ethylene, C3 selectivity is the % of methane that formed propane and propylene, CO selectivity is the percent of methane that formed CO.
“Yield” is a measure of (e.g. percent) of product obtained relative to the theoretical maximum product obtainable. Yield is calculated by dividing the amount of the obtained product in moles by the theoretical yield in moles. Percent yield is calculated by multiplying this value by 100.
“Bulk catalyst” or “bulk material” means a catalyst prepared by traditional techniques, for example by milling or grinding large catalyst particles to obtain smaller/higher surface area catalyst particles. Bulk materials are prepared with minimal control over the size and/or morphology of the material.
“Alkane” means a straight chain or branched, noncyclic or cyclic, saturated aliphatic hydrocarbon. Alkanes include linear, branched and cyclic structures. Representative straight chain alkyls include methyl, ethyl, n-propyl, n-butyl, n-pentyl, n-hexyl, and the like; while branched alkyls include isopropyl, sec-butyl, isobutyl, tert-butyl, isopentyl, and the like. Representative cyclic alkyls include cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, and the like. “Alkene” means a straight chain or branched, noncyclic or cyclic, unsaturated aliphatic hydrocarbon having at least one carbon-carbon double bond. Alkenes include linear, branched and cyclic structures. Representative straight chain and branched alkenes include ethylenyl, propylenyl, 1-butenyl, 2-butenyl, isobutylenyl, 1-pentenyl, 2-pentenyl, 3-methyl-1-butenyl, 2-methyl-2-butenyl, 2,3-dimethyl-2-butenyl, and the like. Cyclic alkenes include cyclohexene and cyclopentene and the like.
“Alkyne” means a straight chain or branched, noncyclic or cyclic, unsaturated aliphatic hydrocarbon having at least one carbon-carbon triple bond. Alkynes include linear, branched and cyclic structures. Representative straight chain and branched alkynes include acetylenyl, propynyl, 1-butynyl, 2-butynyl, 1-pentynyl, 2-pentynyl, 3-methyl-1-butynyl, and the like. Representative cyclic alkynes include cycloheptyne and the like.
“Aromatic” means a carbocyclic moiety having a cyclic system of conjugated p orbitals forming a delocalized conjugated π system and a number of π electrons equal to 4n+2 with n=0, 1, 2, 3, etc. Representative examples of aromatics include benzene and naphthalene and toluene.
“Carbon-containing compounds” are compounds which comprise carbon. Non-limiting examples of carbon-containing compounds include hydrocarbons, CO and CO2.
Nanowires
1. Structure/Physical Characteristics
FIG. 3A is a TEM image of a polycrystalline nanowire 200 having two distal ends 210 and 220. As shown, an actual length 230 essentially traces along the backbone of the nanowire 200, whereas an effective length 234 is the shortest distance between the two distal ends. The ratio of the effective length to the actual length is an indicator of the degrees of twists, bends and/or kinks in the general morphology of the nanowire. FIG. 3B is a schematic representation of the nanowire 200 of FIG. 3A. Typically, the nanowire is not uniform in its thickness or diameter. At any given location along the nanowire backbone, a diameter (240a, 240b, 240c, 240d) is the longest dimension of a cross section of the nanowire, i.e., is perpendicular to the axis of the nanowire backbone).
Compared to nanowire 200 of FIG. 3A, nanowire 250 of FIG. 4A has a different morphology and does not exhibit as many twists, bends and kinks, which suggests a different underlying crystal structure and different number of defects and/or stacking faults. As shown, for nanowire 250, the ratio of the effective length 270 and the actual length 260 is greater than the ratio of the effective length 234 and the actual length 240 of nanowire 200 of FIG. 3A. FIG. 4B is a schematic representation of the nanowire 250, which shows non-uniform diameters (280a, 280b, 280c and 280d).
As noted above, in some embodiments nanowires having a “bent” morphology (i.e. “bent nanowires”) are provided. A “bent’ morphology means that the bent nanowires comprise various twists, bends and/or kinks in their general morphology as illustrated generally in FIGS. 3A and 3B and discussed above. Bent nanowires have a ratio of effective length to actual length of less than one. Accordingly, in some embodiments the present disclosure provides nanowires having a ratio of effective length to actual length of less than one. In other embodiments, the nanowires have a ratio of effective length to actual length of between 0.9 and 0.1, between 0.8 and 0.2, between 0.7 and 0.3, or between 0.6 and 0.4. In other embodiments, the ratio of effective length to actual length is less than 0.9, less than 0.8, less than 0.7, less than 0.6, less than 0.5, less than 0.4, less than 0.3, less than 0.2 or less than 0.1. In other embodiments, the ratio of effective length to actual length is less than 1.0 and more than 0.9, less than 1.0 and more than 0.8, less than 1.0 and more than 0.7, less than 1.0 and more than 0.6, less than 1.0 and more than 0.5, less than 1.0 and more than 0.4, less than 1.0 and more than 0.3, less than 1.0 and more than 0.2, or less than 1.0 and more than 0.1.
The ratio of effective length to actual length of a nanowire having a bent morphology may vary depending on the angle of observation. For example, one-skilled in the art will recognize that the same nanowire, when observed from different perspectives, can have a different effective length as determined by TEM. In addition, not all nanowires having a bent morphology will have the same ratio of effective length to actual length. Accordingly, in a population (i.e. plurality) of nanowires having a bent morphology, a range of ratios of effective length to actual length is expected. Although the ratio of effective length to actual length may vary from nanowire to nanowire, nanowires having a bent morphology will always have a ratio of effective length to actual length of less than one from any angle of observation.
In various embodiments, a substantially straight nanowire is provided. A substantially straight nanowire has a ratio of effective length to actual length equal to one. Accordingly, in some embodiments, the nanowires of the present disclosure have a ratio of effective length to actual length equal to one.
The actual lengths of the nanowires disclosed herein may vary. For example in some embodiments, the nanowires have an actual length of between 100 nm and 100 μm. In other embodiments, the nanowires have an actual length of between 100 nm and 10 μm. In other embodiments, the nanowires have an actual length of between 200 nm and 10 μm. In other embodiments, the nanowires have an actual length of between 500 nm and 5 μm. In other embodiments, the actual length is greater than 5 μm. In other embodiments, the nanowires have an actual length of between 800 nm and 1000 nm. In other further embodiments, the nanowires have an actual length of 900 nm. As noted below, the actual length of the nanowires may be determined by TEM, for example, in bright field mode at 5 keV.
The diameter of the nanowires may be different at different points along the nanowire backbone. However, the nanowires comprise a mode diameter (i.e. the most frequently occurring diameter). As used herein, the diameter of a nanowire refers to the mode diameter. In some embodiments, the nanowires have a diameter of between 1 nm and 500 nm, between 1 nm and 100 nm, between 7 nm and 100 nm, between 7 nm and 50 nm, between 7 nm and 25 nm, or between 7 nm and 15 nm. On other embodiments, the diameter is greater than 500 nm. As noted below, the diameter of the nanowires may be determined by TEM, for example, in bright field mode at 5 keV.
Various embodiments of the present disclosure provide nanowires having different aspect ratios. In some embodiments, the nanowires have an aspect ratio of greater than 10:1. In other embodiments, the nanowires have an aspect ratio greater than 20:1. In other embodiments, the nanowires have an aspect ratio greater than 50:1. In other embodiments, the nanowires have an aspect ratio greater than 100:1.
In some embodiments, the nanowires comprise a solid core while in other embodiments, the nanowires comprise a hollow core.
The morphology of a nanowire (including length, diameter, and other parameters) can be determined by transmission electron microscopy (TEM). Transmission electron microscopy (TEM) is a technique whereby a beam of electrons is transmitted through an ultra thin specimen, interacting with the specimen as it passes through. An image is formed from the interaction of the electrons transmitted through the specimen. The image is magnified and focused onto an imaging device, such as a fluorescent screen, on a layer of photographic film or detected by a sensor such as a CCD camera. TEM techniques are well known to those of skill in the art.
A TEM image of nanowires may be taken, for example, in bright field mode at 5 keV (e.g., as shown in FIGS. 3A and 4A).
The nanowires of the present disclosure can be further characterized by powder x-ray diffraction (XRD). XRD is a technique capable of revealing information about the crystallographic structure, chemical composition, and physical properties of materials, including nanowires. XRD is based on observing the scattered intensity of an X-ray beam hitting a sample as a function of incident and scattered angle, polarization, and wavelength or energy.
Crystal structure, composition, and phase, including the crystal domain size of the nanowires, can be determined by XRD. In some embodiments, the nanowires comprise a single crystal domain (i.e. single crystalline). In other embodiments, the nanowires comprise multiple crystal domains (i.e. polycrystalline). In some other embodiments, the average crystal domain of the nanowires is less than 100 nm, less than 50 nm, less than 30 nm, less than 20 nm, less than 10 nm, less than 5 nm, or less than 2 nm.
Typically, a catalytic material described herein comprises a plurality of nanowires. In certain embodiments, the plurality of nanowires form a mesh of randomly distributed and, to various degrees, interconnected nanowires. FIG. 5A is a TEM image of a nanowire mesh 300 comprising a plurality of nanowires 310 and a plurality of pores 320. FIG. 5B is a schematic representation of the nanowire mesh 300 of FIG. 5A.
The total surface area per gram of a nanowire or plurality of nanowires may have an effect on the catalytic performance. Pore size distribution may affect the nanowires catalytic performance as well. Surface area and pore size distribution of the nanowires or plurality of nanowires can be determined by BET (Brunauer, Emmett, Teller) measurements. BET techniques utilize nitrogen adsorption at various temperatures and partial pressures to determine the surface area and pore sizes of catalysts. BET techniques for determining surface area and pore size distribution are well known in the art.
In some embodiments the nanowires have a surface area of between 0.0001 and 3000 m2/g, between 0.0001 and 2000 m2/g, between 0.0001 and 1000 m2/g, between 0.0001 and 500 m2/g, between 0.0001 and 100 m2/g, between 0.0001 and 50 m2/g, between 0.0001 and 20 m2/g, between 0.0001 and 10 m2/g or between 0.0001 and 5 m2/g.
In some embodiments the nanowires have a surface area of between 0.001 and 3000 m2/g, between 0.001 and 2000 m2/g, between 0.001 and 1000 m2/g, between 0.001 and 500 m2/g, between 0.001 and 100 m2/g, between 0.001 and 50 m2/g, between 0.001 and 20 m2/g, between 0.001 and 10 m2/g or between 0.001 and 5 m2/g.
In some other embodiments the nanowires have a surface area of between 2000 and 3000 m2/g, between 1000 and 2000 m2/g, between 500 and 1000 m2/g, between 100 and 500 m2/g, between 10 and 100 m2/g, between 5 and 50 m2/g, between 2 and 20 m2/g or between 0.0001 and 10 m2/g.
In other embodiments, the nanowires have a surface area of greater than 2000 m2/g, greater than 1000 m2/g, greater than 500 m2/g, greater than 100 m2/g, greater than 50 m2/g, greater than 20 m2/g, greater than 10 m2/g, greater than 5 m2/g, greater than 1 m2/g, greater than 0.0001 m2/g.
2. Chemical Composition
As noted above, disclosed herein are nanowires useful as catalysts. The catalytic nanowires may have any number of compositions and morphologies. In some embodiments, the nanowires are inorganic. In other embodiments, the nanowires are polycrystalline. In some other embodiments, the nanowires are inorganic and polycrystalline. In yet other embodiments, the nanowires are single-crystalline, or in other embodiments the nanowires are inorganic and single-crystalline. In still other embodiments, the nanowires are amorphous, for example the nanowires may be amorphous, polycrystalline or single crystalline. In still other embodiments of any of the foregoing, the nanowires may have a ratio of effective length to actual length of less than one and an aspect ratio of greater than ten as measured by TEM in bright field mode at 5 keV. In still other embodiments of any of the forgoing, the nanowires may comprise one or more elements from any of Groups 1 through 7, lanthanides, actinides or combinations thereof.
In some embodiments, the nanowires comprise one or more metal elements from any of Groups 1-7, lanthanides, actinides or combinations thereof, for example, the nanowires may be mono-metallic, bi-metallic, tri-metallic, etc (i.e. contain one, two, three, etc. metal elements). In some embodiments, the metal elements are present in the nanowires in elemental form while in other embodiments the metal elements are present in the nanowires in oxidized form. In other embodiments the metal elements are present in the nanowires in the form of a compound comprising a metal element. The metal element or compound comprising the metal element may be in the form of oxides, hydroxides, oxyhydroxides, salts, hydrates, oxide carbonates and the like. The metal element or compound comprising the metal element may also be in the form of any of a number of different polymorphs or crystal structures.
In certain examples, metal oxides may be hygroscopic and may change forms once exposed to air. Accordingly, although the nanowires are often referred to as metal oxides, in certain embodiments the nanowires also comprise hydrated oxides, oxyhydroxides, hydroxides or combinations thereof.
In other embodiments, the nanowires comprise one or more metal elements from Group I. In other embodiments, the nanowires comprise one or more metal elements from Group 2. In other embodiments, the nanowires comprise one or more metal elements from Group 3. In other embodiments, the nanowires comprise one or more metal elements from Group 4. In other embodiments, the nanowires comprise one or more metal elements from Group 5. In other embodiments, the nanowires comprise one or more metal elements from Group 6. In other embodiments, the nanowires comprise one or more metal elements from Group 7. In other embodiments, the nanowires comprise one or more metal elements from the lanthanides. In other embodiments, the nanowires comprise one or more metal elements from the actinides.
In one embodiment, the nanowires comprise one or more metal elements from any of Groups 1-7, lanthanides, actinides or combinations thereof in the form of an oxide. In another embodiment, the nanowires comprise one or more metal elements from Group 1 in the form of an oxide. In another embodiment, the nanowires comprise one or more metal elements from Group 2 in the form of an oxide. In another embodiment, the nanowires comprise one or more metal elements from Group 3 in the form of an oxide. In another embodiment, the nanowires comprise one or more metal elements from Group 4 in the form of an oxide. In another embodiment, the nanowires comprise one or more metal elements from Group 5 in the form of an oxide. In another embodiment, the nanowires comprise one or more metal elements from Group 6 in the form of an oxide. In another embodiment, the nanowires comprise one or more metal elements from Group 7 in the form of an oxide. In another embodiment, the nanowires comprise one or more metal elements from the lanthanides in the form of an oxide. In another embodiment, the nanowires comprise one or more metal elements from the actinides in the form of an oxide.
In other embodiments, the nanowires comprise oxides, hydroxides, sulfates, carbonates, oxide carbonates, oxalates, phosphates (including hydrogenphosphates and dihydrogenphosphates), oxyhalides, hydroxihalides, oxyhydroxides, oxysulfates or combinations thereof of one or more metal elements from any of Groups I-7, lanthanides, actinides or combinations thereof. In some other embodiments, the nanowires comprise oxides, hydroxides, sulfates, carbonates, oxide carbonates, oxalates or combinations thereof of one or more metal elements from any of Groups I-7, lanthanides, actinides or combinations thereof. In other embodiments, the nanowires comprise oxides, and in other embodiments, the nanowires comprise hydroxides. In other embodiments, the nanowires comprise oxide carbonates. In other embodiments, the nanowires comprise Li2CO3, LiOH, Li2O, Li2C2O4, Li2SO4, Na2CO3, NaOH, Na2O, Na2C2O4, Na2SO4, K2CO3, KOH, K2O, K2C2O4, K2SO4, CsCO3, CsOH, Cs2O, CsC2O4, CsSO4, Be(OH)2, BeCO3, BeO, BeC2O4. BeSO4, Mg(OH)2, MgCO3, MgO, MgC2O4. MgSO4, Ca(OH)2, CaO, Ca(OH)2, CaC2O4, CaSO4, Y2O3, Y2(CO3)3, Y(OH)3, Y2(C2O4)3, Y2(SO4)3, Zr(OH)4, ZrO(OH)2, ZrO2, Zr(C2O4)2, Zr(SO4)2, Ti(OH)4, TiO(OH)2, TiO2, Ti(C2O4)2, Ti(SO4)2, BaO, Ba(OH)2, BaCO3, BaC2O4, BaSO4, La(OH)3, La2O3, La2(C2O4)3, La2(SO4)3, Ce(OH)4, CeO2, Ce2O3, Ce(C2O4)2, Ce(SO4)2, ThO2, Th(OH)4, Th(C2O4)2, Th(SO4)2, Sr(OH)2, SrCO3, SrO, SrC2O4, SrSO4, Sm2O3, Sm(OH)3, Sm2(CO3)3, Sm2(C2O3)3, Sm2(SO4)3, LiCa2Bi3O4Cl6, NaMnO4, Na2WO4, NaMn/WO4, CoWO4, CuWO4, K/SrCoO3, K/Na/SrCoO3, Na/SrCoO3, Li/SrCoO3, SrCoO3, Mg6MnO8, LiMn2O4, Li/Mg6MnO8, Na10Mn/W5O17, Mg3Mn3B2O10, Mg3(BO3)2, molybdenum oxides, molybdenum hydroxides, molybdenum oxalates, molybdenum sulfates, Mn2O3, Mn3O4, manganese oxides, manganese hydroxides, manganese oxalates, manganese sulfates, manganese tungstates, vanadium oxides, vanadium hydroxides, vanadium oxalates, vanadium sulfates, tungsten oxides, tungsten hydroxides, tungsten oxalates, tungsten sulfates, neodymium oxides, neodymium hydroxides, neodymium oxalates, neodymium sulfates, europium oxides, europium hydroxides, europium oxalates, europium sulfates, praseodymium oxides, praseodymium hydroxides, praseodymium oxalates, praseodymium sulfates, rhenium oxides, rhenium hydroxides, rhenium oxalates, rhenium sulfates, chromium oxides, chromium hydroxides, chromium oxalates, chromium sulfates, potassium molybdenum oxides/silicon oxide or combinations thereof.
In other embodiments, the nanowires comprise Li2O, Na2O, K2O, Cs2O, BeO MgO, CaO, ZrO(OH)2, ZrO2, TiO2, TiO(OH)2, BaO, Y2O3, La2O3, CeO2, Ce2O3, ThO2, SrO, Sm2O3, Nd2O3, Eu2O3, Pr2O3, LiCa2Bi3O4Cl6, NaMnO4, Na2WO4, Na/Mn/WO4, Na/MnWO4, Mn/WO4, K/SrCoO3, K/Na/SrCoO3, K/SrCoO3, Na/SrCoO3, Li/SrCoO3, SrCoO3, Mg6MnO8, Na/B/Mg6MnO8, Li/B/Mg6MnO8, Zr2Mo2O8, molybdenum oxides, Mn2O3, Mn3O4, manganese oxides, vanadium oxides, tungsten oxides, neodymium oxides, rhenium oxides, chromium oxides, or combinations thereof.
In still other aspects, the nanowires comprise lanthanide containing perovskites. A perovskite is any material with the same type of crystal structure as calcium titanium oxide (CaTiO3). Examples of perovskites within the context of the present disclosure include, but are not limited to, LaCoO3 and La/SrCoO3.
In other embodiments, the nanowires comprise TiO2, Sm2O3, V2O5, MoO3, BeO, MnO2, MgO, La2O3, Nd2O3, Eu2O3, ZrO2, SrO, Na2WO4, Mn/WO4, BaCO3, Mn2O3, Mn3O4, Mg6MnO8, Na/B/Mg6MnO8, Li/B/Mg6MnO8, NaMnO4, CaO or combinations thereof. In further embodiments, the nanowires comprise MgO, La2O3, Nd2O3, Na2WO4, Mn/WO4, Mn2O3, Mn3O4, Mg6MnO8, Na/B/Mg6MnO8, Li/B/Mg6MnO8 or combinations thereof.
In some embodiments, the nanowires comprises Mg, Ca, La, W, Mn, Mo, Nd, Sm, Eu, Pr, Zr or combinations thereof, and in other embodiments the nanowire comprises MgO, CaO, La2O3, Na2WO4, Mn2O3, Mn3O4, Nd2O3, Sm2O3, Eu2O3, Pr2O3, Mg6MnO8, NaMnO4, Na/Mn/W/O, Na/MnWO4, MnWO4 or combinations thereof.
In more specific embodiments, the nanowires comprise MgO. In other specific embodiments, the nanowires comprise La2O3. In other specific embodiments, the nanowires comprise Na2WO4 and may optionally further comprise Mn/WO4. In other specific embodiments, the nanowires comprise Mn2O3. In other specific embodiments, the nanowires comprise Mn3O4. In other specific embodiments, the nanowires comprise Mg6MnO8. In other specific embodiments, the nanowires comprise NaMnO4. In other specific embodiments, the nanowires comprise Nd2O3. In other specific embodiments, the nanowires comprise Eu2O3. In other specific embodiments, the nanowires comprise Pr2O3.
In certain embodiments, the nanowires comprise an oxide of a group 2 element. For example, in some embodiments, the nanowires comprise an oxide of magnesium. In other embodiments, the nanowires comprise an oxide of calcium. In other embodiments, the nanowires comprise an oxide of strontium. In other embodiments, the nanowires comprise an oxide of barium.
In certain other embodiments, the nanowires comprise an oxide of a group 3 element. For example, in some embodiments, the nanowires comprise an oxide of yttrium. In other embodiments, the nanowires comprise an oxide of scandium.
In yet other certain embodiments, the nanowires comprise an oxide of an early lanthanide element. For example, in some embodiments, the nanowires comprise an oxide of lanthanum. In other embodiments, the nanowires comprise an oxide of cerium. In other embodiments, the nanowires comprise an oxide of praseodymium. In other embodiments, the nanowires comprise an oxide of neodymium. In other embodiments, the nanowires comprise an oxide of promethium. In other embodiments, the nanowires comprise an oxide of samarium. In other embodiments, the nanowires comprise an oxide of europium. In other embodiments, the nanowires comprise an oxide of gandolinium.
In certain other embodiments, the nanowires comprise a lanthanide in the form of an oxide carbonate. For example, the nanowires may comprise Ln2O2(CO3), where Ln represents a lanthanide. Examples in this regard include: La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb and Lu oxide carbonates. In other embodiments, the nanowires comprise an oxide carbonate of one or more elements from any of Groups 1 through 7, lanthanides, actinides or combinations thereof. Accordingly in one embodiment the nanowires comprise Li, Na, K, Rb, Cs, Fr, Be, Mg, Ca, Sr, Ba, Ra, Sc, Y, Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W, Mn, Tc or Re oxide carbonate. In other embodiments, the nanowires comprise Ac, Th or Pa oxide carbonate. An oxide carbonate may be represented by the following formula: MxOy(CO3)z, wherein M is a metal element from any of Groups 1 through 7, lanthanides or actinides and x, y and z are integers such that the overall charge of the metal oxide carbonate is neutral.
In other embodiments, the nanowires comprise TiO2, Sm2O3, V2O5, MoO3, BeO, MnO2, MgO, La2O3, ZrO2, SrO, Na2WO4, BaCO3, Mn2O3, Mn3O4, Mg6MnO8, Na/B/Mg6MnO8, Li/B/Mg6MnO8, Zr2Mo2O8, NaMnO4, CaO or combinations thereof and further comprise one or more dopants comprised of metal elements, semi-metal elements, non-metal elements or combinations thereof. In some further embodiments, the nanowires comprise MgO, La2O3, Na2WO4, Mn2O3, Mn3O4, Mg6MnO8, Zr2Mo2O8, NaMnO4 or combinations thereof, and the nanowires further comprise Li, Sr, Zr, Ba, Mn or Mn/WO4.
In some embodiments, the nanowires or a catalytic material comprising a plurality of the nanowires comprise a combination of one or more of metal elements from any of Groups I-7, lanthanides or actinides and one or more of metal elements, semi-metal elements or non-metal elements. For example in one embodiment, the nanowires comprise the combinations of Li/Mg/O, Ba/Mg/O, Zr/La/O, Ba/La/O, Sr/La/O, Zr/V/P/O, Mo/V/Sb/O, V2O5/Al2O3, Mo/V/O, V/Ce/O, V/Ti/P/O, V2O5/TiO2, V/P/O/TiO2, V/P/O/Al2O3, V/Mg/O, V2O5/ZrO2, Mo/V/Te/O, V/Mo/O/Al2O3, Ni/V/Sb/O, Co/V/Sb/O, Sn/V/Sb/O, Bi/V/Sb/O, Mo/V/Te/Nb/O, Mo/V/Nb/O, V2O5/MgO/SiO2, V/Co, MoO3/Al2O3, Ni/Nb/O, NiO/Al2O3, Ga/Cr/Zr/P/O, MoO3/Cl/SiO2/TiO2, Co/Cr/Sn/W/O, Cr/Mo/O, MoO3/Cl/SiO2/TiO2, Co/Ca, NiO/MgO, MoO3/Al2O3, Nb/P/Mo/O, Mo/V/Te/Sb//Nb/O, La/Na/Al/O, Ni/Ta/Nb/O, Mo/Mn/V/W/O, Li/Dy/Mg/O, Sr/La/Nd/O, Co/Cr/Sn/W/O, MoO3/SiO2/TiO2, Sm/Na/P/O, Sm/Sr/O, Sr/La/Nd/O, Co/P/O/TiO2, La/Sr/Fe/Cl/O, La/Sr/Cu/Cl/O, Y/Ba/Cu/O, Na/Ca/O, V2O5/ZrO2, V/Mg/O, Mn/V/Cr/W/O/Al2O3, V2O5/K/SiO2, V2O5/Ca/TiO2, V2O5/K/TiO2, V/Mg/Al/O, V/Zr/O, V/Nb/O, V2O5/Ga2O3, V/Mg/Al/O, V/Nb/O, V/Sb/O, V/Mn/O, V/Nb/O/Sb2O4, V/Sb/O/TiO2, V2O5/Ca, V2O5/K/Al2O3, V2O5/TiO2, V2O5/MgO/TiO2, V2O5/ZrO2, V/Al/F/O, V/Nb/O/TiO2, Ni/V/O, V2O5/SmVO4, V/W/O, V2O5/Zn/Al2O3, V2O5/CeO2, V/Sm/O, V2O5/TiO2/SiO2, Mo/Li/O/Al2O3, Mg/Dy/Li/Cl/O, Mg/Dy/Li/Cl/O, Ce/Ni/O, Ni/Mo/O/V, Ni/Mo/O/V/N, Ni/Mo/O Sb/O/N, MoO3/Cl/SiO2/TiO2, Co/Mo/O, Ni/Ti/O, Ni/Zr/O, Cr/O, MoO3/Al2O3, Mn/P/O, MoO3/K/ZrO2, Na/W/O, Mn/Na/W/O, Mn/Na//W/O/SiO2, Na/W/O/SiO2, Mn/Mo/O, Nb2O5/TiO2, Co/W/O, Ni/Mo/O, Ga/Mo/O, Mg/Mo/V/O, Cr2O3/Al2O3, Cr/Mo/Cs/O/Al2O3, Co/Sr/O/Ca, Ag/Mo/P/O, MoO3/SmVO4, Mo/Mg/Al/O, MoO3/K/SiO2/TiO2, Cr/Mo/O/Al2O3, MoO3/Al2O3, Ni/Co/Mo/O, Y/Zr/O, Y/Hf, Zr/Mo/Mn/O, Mg/Mn/O, Li/Mn/O, Mg/Mn/B/O, Mg/B/O, Na/B/Mg/Mn/O, Li/B/Mg/Mn/O, Mn/Na/P/O, Na/Mn/Mg/O, Zr/Mo/O, Mn/W/O or Mg/Mn/O.
In a specific embodiment, the nanowires comprise the combinations of Li/Mg/O, Ba/Mg/O, Zr/La/O, Ba/La/O, Sr/La/O, Sr/Nd/O, La/O, Nd/O, Eu/O, Mg/La/O, Mg/Nd/O, Na/La/O, Na/Nd/O, Sm/O, Mn/Na/W/O, Mg/Mn/O, Na/B/Mg/Mn/O, Li/B/Mg/Mn/O, Zr/Mo/O or Na/Mn/Mg/O. For example, in some embodiments the nanowires comprise the combinations of Li/MgO, Ba/MgO, Sr/La2O3, Ba/La2O3, Mn/Na2WO4, Mn/Na2WO4/SiO2, Mn2O3/Na2WO4, Mn3O4/Na2WO4, Li/B/Mg6MnO8, Na/B/Mg6MnO8 or NaMnO4/MgO. In certain embodiments, the nanowire comprises Li/MgO, Ba/MgO, Sr/La2O3, Mg/Na/La2O3, Sr/Nd2O3, or Mn/Na2WO4.
In some other specific embodiments, the nanowires comprise the combination of Li/MgO. In other specific embodiments, the nanowires comprise the combination of Ba/MgO. In other specific embodiments, the nanowires comprise the combination of Sr/La2O3. In other specific embodiments, the nanowires comprise the combination of Ba/La2O3. In other specific embodiments, the nanowires comprise the combination of Mn/Na2WO4. In other specific embodiments, the nanowires comprise the combination of Mn/Na2WO4/SiO2. In other specific embodiments, the nanowires comprise the combination of Mn2O3/Na2WO4. In other specific embodiments, the nanowires comprise the combination of Mn3O4/Na2WO4. In other specific embodiments, the nanowires comprise the combination of Mn/WO4/Na2WO4. In other specific embodiments, the nanowires comprise the combination of Li/B/Mg6MnO8. In other specific embodiments, the nanowires comprise the combination of Na/B/Mg6MnO8. In other specific embodiments, the nanowires comprise the combination of NaMnO4/MgO.
Polyoxyometalates (POM) are a class of metal oxides that range in structure from the molecular to the micrometer scale. The unique physical and chemical properties of POM clusters, and the ability to tune these properties by synthetic means have attracted significant interest from the scientific community to create “designer” materials. For example, heteropolyanions such as the well-known Keggin [XM12O40]− and Wells-Dawson [X2M18O62]− anions (where M=W or Mo; and X=a tetrahedral template such as but not limited to Si, Ge, P) and isopolyanions with metal oxide frameworks with general formulas [MOx]n where M=Mo, W, V, and Nb and x=4−7 are ideal candidates for OCM/ODH catalysts. Accordingly, in one embodiment the nanowires comprise [XM12O40]− or [X2M18O62]− anions (where M=W or Mo; and X=a tetrahedral template such as but not limited to Si, Ge, P) and isopolyanions with metal oxide frameworks with general formulas [MOx]n where M=Mo, W, V, and Nb and x=4−7. In some embodiments, X is P or Si.
These POM clusters have “lacunary” sites that can accommodate divalent and trivalent first row transition metals, the metal oxide clusters acting as ligands. These lacunary sites are essentially “doping” sites, allowing the dopant to be dispersed at the molecular level instead of in the bulk which can create pockets of unevenly dispersed doped material. Because the POM clusters can be manipulated by standard synthetic techniques, POMs are highly modular and a wide library of materials can be prepared with different compositions, cluster size, and dopant oxidation state. These parameters can be tuned to yield desired OCM/ODH catalytic properties. Accordingly, one embodiment of the present disclosure is a nanowire comprising one or more POM clusters. Such nanowires find utility as catalysts, for example, in the OCM and ODH reactions.
Silica doped sodium manganese tungstate (NaMn/WO4/SiO2) is a promising OCM catalyst. The NaMn/WO4/SiO2 system is attractive due to its high C2 selectivity and yield. Unfortunately, good catalytic activity is only achievable at temperatures greater than 800° C. and although the exact active portion of the catalyst is still subject to debate, it is thought that sodium plays an important role in the catalytic cycle. In addition, the NaMn/WO4/SiO2 catalyst surface area is relatively low <2 m2/g. Manganese tungstate (Mn/WO4) nanorods (i.e., straight nanowires) can be used to model a NaMn/WO4/SiO2 based nanowire OCM catalyst. The Mn/WO4 nanorods are prepared hydro-thermally and the size can be tuned based on reaction conditions with dimensions of 25-75 nm in diameter to 200-800 nm in length. The as-prepared nano-rods have higher surface areas than the NaMn/WO4/SiO2 catalyst systems. In addition, the amount of sodium, or other elements, can precisely doped into the Mn/WO4 nanorod material to target optimal catalytic activity. Nanorod tungstate based materials can be expanded to but, not limited to, CoWO4 or CuWO4 materials which may serve as base materials for OCM/ODH catalysis. In addition to straight nanowires, the above discussion applies to the disclosed nanowires having a bent morphology as well. The nanowires of the disclosure may be analyzed by inductively coupled plasma mass spectrometry (ICP-MS) to determine the element content of the nanowires. ICP-MS is a type of mass spectrometry that is highly sensitive and capable of the determination of a range of metals and several non-metals at concentrations below one part in 1012. ICP is based on coupling together an inductively coupled plasma as a method of producing ions (ionization) with a mass spectrometer as a method of separating and detecting the ions. ICP-MS methods are well known in the art.
In some embodiments, the nanowire comprises a combination of two or more metal compounds, for example metal oxides. For example, in some embodiments, the nanowire comprises Mn2O3/Na2WO4, Mn3O4/Na2WO4 MnWO4/Na2WO4/Mn2O3, MnWO4/Na2WO4/Mn3O4 or NaMnO4/MgO.
3. Catalytic Materials
As noted above, the present disclosure provides a catalytic material comprising a plurality of nanowires. In certain embodiments, the catalytic material comprises a support or carrier. The support is preferably porous and has a high surface area. In some embodiments the support is active (i.e. has catalytic activity). In other embodiments, the support is inactive (i.e. non-catalytic). In some embodiments, the support comprises an inorganic oxide, Al2O3, SiO2, TiO2, MgO, ZrO2, ZnO, LiAlO2, MgAl2O4, MnO, MnO2, Mn3O4, La2O3, AlPO4, SiO2/Al2O3, activated carbon, silica gel, zeolites, activated clays, activated Al2O3, diatomaceous earth, magnesia, aluminosilicates, calcium aluminate, support nanowires or combinations thereof. In some embodiments the support comprises silicon, for example SiO2. In other embodiments the support comprises magnesium, for example MgO. In other embodiments the support comprises zirconium, for example ZrO2. In yet other embodiments, the support comprises lanthanum, for example La2O3. In yet other embodiments, the support comprises hafnium, for example HfO2. In yet other embodiments, the support comprises aluminum, for example Al2O3. In yet other embodiments, the support comprises gallium, for example Ga2O3.
In still other embodiments, the support material comprises an inorganic oxide, Al2O3, SiO2, TiO2, MgO, ZrO2, HfO2, CaO, ZnO, LiAlO2, MgAl2O4, MnO, MnO2, Mn2O4, Mn3O4, La2O3, activated carbon, silica gel, zeolites, activated clays, activated Al2O3, diatomaceous earth, magnesia, aluminosilicates, calcium aluminate, support nanowires or combinations thereof. For example, the support material may comprise SiO2, ZrO2, CaO, La2O3 or MgO.
In yet other embodiments, a nanowire may serve as a support for another nanowire. For example, a nanowire may be comprised of non-catalytic metal elements and adhered to or incorporated within the support nanowire is a catalytic nanowire. For example, in some embodiments, the support nanowires are comprised of SiO2, MgO, TiO2, ZrO2, Al2O3, or ZnO. Preparation of nanowire supported nanowire catalysts (i.e., core/shell nanowires) is discussed in more detail below. The optimum amount of nanowire present on the support depends, inter alia, on the catalytic activity of the nanowire. In some embodiments, the amount of nanowire present on the support ranges from 1 to 100 parts by weight nanowires per 100 parts by weight of support or from 10 to 50 parts by weight nanowires per 100 parts by weight of support. In other embodiments, the amount of nanowire present on the support ranges from 100-200 parts of nanowires per 100 parts by weight of support, or 200-500 parts of nanowires per 100 parts by weight of support, or 500-1000 parts of nanowires per 100 parts by weight of support.
Typically, heterogeneous catalysts are used either in their pure form or blended with inert materials, such as silica, alumina, etc. The blending with inert materials is used in order to reduce and/or control large temperature non-uniformities within the reactor bed often observed in the case of strongly exothermic (or endothermic) reactions. In the case of complex multistep reactions, such as the reaction to convert methane into ethylene (OCM), typical blending materials can selectively slow down or quench one or more of the reactions of the system and promote unwanted side reactions. For example, in the case of the oxidative coupling of methane, silica and alumina can quench the methyl radicals and thus prevent the formation of ethane. In certain aspects, the present disclosure provides a catalytic material which solves these problems typically associated with catalyst support material. Accordingly, in certain embodiments the catalytic activity of the catalytic material can be tuned by blending two or more catalysts and/or catalyst support materials. The blended catalytic material may comprise a catalytic nanowire as described herein and a bulk catalyst material and/or inert support material.
The blended catalytic materials comprise metal oxides, hydroxides, oxy-hydroxides, carbonates, oxalates of the groups 1-16, lanthanides, actinides or combinations thereof. For example, the blended catalytic materials may comprise a plurality of inorganic catalytic polycrystalline nanowires, as disclosed herein, and any one or more of straight nanowires, nanoparticles, bulk materials and inert support materials. Bulk materials are defined as any material in which no attempt to control the size and/or morphology was performed during its synthesis. The catalytic materials may be undoped or may be doped with any of the dopants described herein.
In one embodiment, the catalyst blend comprises at least one type 1 component and at least one type 2 component. Type 1 components comprise catalysts having a high OCM activity at moderately low temperatures and type 2 components comprise catalysts having limited or no OCM activity at these moderately low temperatures, but are OCM active at higher temperatures. For example, in some embodiments the type 1 component is a catalyst (e.g., nanowire) having high OCM activity at moderately low temperatures. For example, the type 1 component may comprise a C2 yield of greater than 5% or greater than 10% at temperatures less than 800° C., less than 700° C. or less than 600° C. The type 2 component may comprise a C2 yield less than 0.1%, less than 1% or less than 5% at temperatures less than 800° C., less than 700° C. or less than 600° C. The type 2 component may comprise a C2 yield of greater than 0.1%, greater than 1%, greater than 5% or greater than 10% at temperatures greater than 800° C., greater than 700° C. or greater than 600° C. Typical type 1 components include nanowires, for example polycrystalline nanowires as described herein, while typical type 2 components include bulk OCM catalysts and nanowire catalysts which only have good OCM activity at higher temperatures, for example greater than 800° C. Examples of type 2 components may include catalysts comprising MgO. The catalyst blend may further comprise inert support materials as described above (e.g., silica, alumina, etc.).
In certain embodiments, the type 2 component acts as diluent in the same way an inert material does and thus helps reduce and/or control hot spots in the catalyst bed caused by the exothermic nature of the OCM reaction. However, because the type 2 component is an OCM catalyst, albeit not a particularly active one, it may prevent the occurrence of undesired side reactions, e.g. methyl radical quenching. Additionally, controlling the hotspots has the beneficial effect of extending the lifetime of the catalyst.
For example, it has been found that diluting active lanthanide oxide OCM catalysts (e.g., nanowires) with as much as a 10:1 ratio of MgO, which by itself is not an active OCM catalyst at the temperature which the lanthanide oxide operates, is a good way to minimize “hot spots” in the reactor catalyst bed, while maintaining the selectivity and yield performance of the catalyst. On the other hand, doing the same dilution with quartz SiO2 is not effective because it appears to quench the methyl radicals which serves to lower the selectivity to C2s.
In yet another embodiment, the type 2 components are good oxidative dehydrogenation (ODH) catalysts at the same temperature that the type 1 components are good OCM catalysts. In this embodiment, the ethylene/ethane ratio of the resulting gas mixture can be tuned in favor of higher ethylene. In another embodiment, the type 2 components are not only good ODH catalysts at the same temperature the type 1 components are good OCM catalysts, but also have limited to moderate OCM activity at these temperatures.
In related embodiments, the catalytic performance of the catalytic material is tuned by selecting specific type 1 and type 2 components of a catalyst blend. In another embodiment, the catalytic performance is tuned by adjusting the ratio of the type 1 and type 2 components in the catalytic material. For example, the type 1 catalyst may be a catalyst for a specific step in the catalytic reaction, while the type 2 catalyst may be specific for a different step in the catalytic reaction. For example, the type 1 catalyst may be optimized for formation of methyl radicals and the type 2 catalyst may be optimized for formation of ethane or ethylene.
In other embodiments, the catalyst material comprises at least two different components (component 1, component 2, component 3, etc.). The different components may comprise different morphologies, e.g. nanowires, nanoparticles, bulk, etc. The different components in the catalyst material can be, but not necessarily, of the same chemical composition and the only difference is in the morphology and/or the size of the particles. This difference in morphology and particle size may result in a difference in reactivity at a specific temperature. Additionally, the difference in morphology and particle size of the catalytic material components is advantageous for creating a very intimate blending, e.g. very dense packing of the catalysts particles, which can have a beneficial effect on catalyst performance. Also, the difference in morphology and particle size of the blend components would allow for control and tuning of the macro-pore distribution in the reactor bed and thus its catalytic efficiency. An additional level of micro-pore tuning can be attained by blending catalysts with different chemical composition and different morphology and/or particle size. The proximity effect would be advantageous for the reaction selectivity.
Accordingly, in one embodiment the present disclosure provides the use of a catalytic material comprising a first catalytic nanowire and a bulk catalyst and/or a second catalytic nanowire in a catalytic reaction, for example the catalytic reaction may be OCM or ODH. In other embodiments, the first catalytic nanowire and the bulk catalyst and/or second catalytic nanowire are each catalytic with respect to the same reaction, and in other examples the first catalytic nanowire and the bulk catalyst and/or second catalytic nanowire have the same chemical composition.
In some specific embodiments of the foregoing, the catalytic material comprises a first catalytic nanowire and a second catalytic nanowire. Each nanowire can have completely different chemical compositions or they may have the same base composition and differ only by the doping elements. In other embodiments, each nanowire can have the same or a different morphology. For example, each nanowire can differ by the nanowire size (length and/or aspect ratio), by ratio of actual/effective length, by chemical composition or any combination thereof. Furthermore, the first and second nanowires may each be catalytic with respect to the same reaction but may have different activity. Alternatively, each nanowire may catalyze different reactions.
In a related embodiment, the catalytic material comprises a first catalytic nanowire and a bulk catalyst. The first nanowire and the bulk catalyst can have completely different chemical compositions or they may have the same base composition and differ only by the doping elements. Furthermore, the first nanowire and the bulk catalyst may each be catalytic with respect to the same reaction but may have different activity. Alternatively, the first nanowire and the bulk catalyst may catalyze different reactions.
In yet other embodiments of the foregoing, the catalytic nanowire has a catalytic activity in the catalytic reaction which is greater than a catalytic activity of the bulk catalyst in the catalytic reaction at the same temperature. In still other embodiments, the catalytic activity of the bulk catalyst in the catalytic reaction increases with increasing temperature.
For ease of illustration, the above description of catalytic materials often refers to OCM; however, such catalytic materials find utility in other catalytic reactions including but not limited to: oxidative dehydrogenation (ODH) of alkanes to their corresponding alkenes, selective oxidation of alkanes and alkenes and alkynes, oxidation of co, dry reforming of methane, selective oxidation of aromatics, Fischer-Tropsch, combustion of hydrocarbons, etc.
4. Preparation of Catalytic Materials
The catalytic materials can be prepared according to any number of methods known in the art. For example, the catalytic materials can be prepared after preparation of the individual components by mixing the individual components in their dry form, e.g. blend of powders, and optionally, ball milling can be used to reduce particle size and/or increase mixing. Each component can be added together or one after the other to form layered particles. Alternatively, the individual components can be mixed prior to calcination, after calcination or by mixing already calcined components with uncalcined components. The catalytic materials may also be prepared by mixing the individual components in their dry form and optionally pressing them together into a “pill” followed by calcination to above 400° C.
In other examples, the catalytic materials are prepared by mixing the individual components with one or more solvents into a suspension or slurry, and optional mixing and/or ball milling can be used to maximize uniformity and reduce particle size. Examples of slurry solvents useful in this context include, but are not limited to: water, alcohols, ethers, carboxylic acids, ketones, esters, amides, aldehydes, amines, alkanes, alkenes, alkynes, aromatics, etc. In other embodiments, the individual components are deposited on a supporting material such as silica, alumina, magnesia, activated carbon, and the like, or by mixing the individual components using a fluidized bed granulator. Combinations of any of the above methods may also be used.
The catalytic materials may optionally comprise a dopant as described in more detail below. In this respect, doping material(s) may be added during preparation of the individual components, after preparation of the individual components but before drying of the same, after the drying step but before calcinations or after calcination. If more than one doping material is used, each dopant can be added together or one after the other to form layers of dopants.
Doping material(s) may also be added as dry components and optionally ball milling can be used to increase mixing. In other embodiments, doping material(s) are added as a liquid (e.g. solution, suspension, slurry, etc.) to the dry individual catalyst components or to the blended catalytic material. The amount of liquid may optionally be adjusted for optimum wetting of the catalyst, which can result in optimum coverage of catalyst particles by doping material. Mixing and/or ball milling can also be used to maximize doping coverage and uniform distribution. Alternatively, doping material(s) are added as a liquid (e.g. solution, suspension, slurry, etc.) to a suspension or slurry of the catalyst in a solvent. Mixing and/or ball milling can be used to maximize doping coverage and uniform distribution. Incorporation of dopants can also be achieved using any of the methods described elsewhere herein.
As noted below, an optional calcination step usually follows an optional drying step at T<200 C (typically 60-120 C) in a regular oven or in a vacuum oven. Calcination may be performed on the individual components of the catalytic material or on the blended catalytic material. Calcination is generally performed in an oven/furnace at a temperature higher than the minimum temperature at which at least one of the components decomposes or undergoes a phase transformation and can be performed in inert atmosphere (e.g. N2, Ar, He, etc.), oxidizing atmosphere (air, O2, etc.) or reducing atmosphere (H2, H2/N2, H2/Ar, etc.). The atmosphere may be a static atmosphere or a gas flow and may be performed at ambient pressure, at p<1 atm, in vacuum or at p>1 atm. High pressure treatment (at any temperature) may also be used to induce phase transformation including amorphous to crystalline.
Calcination is generally performed in any combination of steps comprising ramp up, dwell and ramp down. For example, ramp to 500° C., dwell at 500° C. for 5 h, ramp down to RT. Another example includes ramp to 100° C., dwell at 100° C. for 2 h, ramp to 300° C., dwell at 300° C. for 4 h, ramp to 550° C., dwell at 550° C. for 4 h, ramp down to RT. Calcination conditions (pressure, atmosphere type, etc.) can be changed during the calcination. In some embodiments, calcination is performed before preparation of the blended catalytic material (i.e., individual components are calcined), after preparation of the blended catalytic material but before doping, after doping of the individual components or blended catalytic material. Calcination may also be performed multiple times, e.g. after catalyst preparation and after doping.
The catalytic materials may incorporated into a reactor bed for performing any number of catalytic reactions (e.g., OCM, ODH and the like). In this regard, the catalytic material may be packed neat (without diluents) or diluted with an inert material (e.g., sand, silica, alumina, etc.) The catalyst components may be packed uniformly forming a homogeneous reactor bed.
The particle size of the individual components within a catalytic material may also alter the catalytic activity, and other properties, of the same. Accordingly, in one embodiment, the catalyst is milled to a target average particle size or the catalyst powder is sieved to select a particular particle size. In some aspects, the catalyst powder may be pressed into pellets and the catalyst pellets can be optionally milled and or sieved to obtain the desired particle size distribution.
In yet another embodiment, the catalysts are packed in bands forming a layered reactor bed. Each layer is composed by either a catalyst of a particular type, morphology or size or a particular blend of catalysts. In one embodiment, the catalysts blend may have better sintering properties, i.e. lower tendency to sinter, then a material in its pure form. Better sintering resistance is expected to increase the catalyst's lifetime and improve the mechanical properties of the reactor bed.
In yet other embodiments, the disclosure provides a catalytic material comprising one or more different catalysts. The catalysts may be a nanowire as disclosed herein and a different catalyst for example a bulk catalysts. Mixture of two or more nanowire catalysts are also contemplated. The catalytic material may comprise a catalyst, for example a nanowire catalyst, having good OCM activity and a catalyst having good activity in the ODH reaction. Either one or both of these catalysts may be nanowires as disclosed herein.
On skilled in the art will recognize that various combinations or alternatives of the above methods are possible, and such variations are also included within the scope of the present disclosure.
5. Dopants
In further embodiments, the disclosure provides nanowires comprising a dopant (i.e., doped nanowires). As noted above, dopants or doping agents are impurities added to or incorporated within a catalyst to optimize catalytic performance (e.g., increase or decrease catalytic activity). As compared to the undoped catalyst, a doped catalyst may increase or decrease the selectivity, conversion, and/or yield of a catalytic reaction. In one embodiment, nanowire dopants comprise one or more metal elements, semi-metal elements, non-metal elements or combinations thereof. The dopant may be present in any form and may be derived from any suitable source of the element (e.g., chlorides, nitrates, etc.). In some embodiments, the nanowire dopant is in elemental form. In other embodiments, the nanowire dopant is in reduced or oxidized form. In other embodiments, the nanowire dopant comprises an oxide, hydroxide, carbonate, nitrate, acetate, sulfate, formate, oxynitrate, halide, oxyhalide or hydroxyhalide of a metal element, semi-metal element or non-metal element or combinations thereof.
In one embodiment, the nanowires comprise one or more metal elements selected from Groups I-7, lanthanides, actinides or combinations thereof in the form of an oxide and further comprise one or more dopants, wherein the one or more dopants comprise metal elements, semi-metal elements, non-metal elements or combinations thereof. In another embodiment, the nanowires comprise one or more metal elements selected from group 1 in the form of an oxide and further comprise one or more dopants, wherein the one or more dopants comprise metal elements, semi-metal elements, non-metal elements or combinations thereof. In another embodiment, the nanowires comprise one or more metal elements selected from group 2 in the form of an oxide and further comprise one or more dopants, wherein the one or more dopants comprise metal elements, semi-metal elements, non-metal elements or combinations thereof. In another embodiment, the nanowires comprise one or more metal elements selected from group 3 in the form of an oxide and further comprise one or more dopants, wherein the one or more dopants comprise metal elements, semi-metal elements, non-metal elements or combinations thereof. In another embodiment, the nanowires comprise one or more metal elements selected from group 4 in the form of an oxide and further comprise one or more dopants, wherein the one or more dopants comprise metal elements, semi-metal elements, non-metal elements or combinations thereof. In another embodiment, the nanowires comprise one or more metal elements selected from group V in the form of an oxide and further comprise one or more dopants, wherein the one or more dopants comprise metal elements, semi-metal elements, non-metal elements or combinations thereof. In another embodiment, the nanowires comprise one or more metal elements selected from group 6 in the form of an oxide and further comprise one or more dopants, wherein the one or more dopants comprise metal elements, semi-metal elements, non-metal elements or combinations thereof. In another embodiment, the nanowires comprise one or more metal elements selected from group 7 in the form of an oxide and further comprise one or more dopants, wherein the one or more dopants comprise metal elements, semi-metal elements, non-metal elements or combinations thereof. In another embodiment, the nanowires comprise one or more metal elements selected from lanthanides in the form of an oxide and further comprise one or more dopants, wherein the one or more dopants comprise metal elements, semi-metal elements, non-metal elements or combinations thereof. In another embodiment, the nanowires comprise one or more metal elements selected from actinides in the form of an oxide and further comprise one or more dopants, wherein the one or more dopants comprise metal elements, semi-metal elements, non-metal elements or combinations thereof.
For example, in one embodiment, the nanowire dopant comprises Li, Li2CO3, LiOH, Li2O, LiCl, LiNO3, Na, Na2CO3, NaOH, Na2O, NaCl, NaNO3, K, K2CO3, KOH, K2O, KCl, KNO3, Rb, Rb2CO3, RbOH, Rb2O, RbCl, RbNO3, Mg, MgCO3, Mg(OH)2, MgO, MgCl2, Mg(NO3)2, Ca, CaO, CaCO3, Ca(OH)2, CaCl2, Ca(NO3)2, Sr, SrO, SrCO3, Sr(OH)2, SrCl2, Sr(NO3)2, Ba, BaO, BaCO3, Ba(OH)2, BaCl2, Ba(NO3)2, La, La2O3, La(OH)3, LaCl3, La(NO3)2, Nb, Nb2O3, Nb(OH)3, NbCl3, Nb(NO3)2, Sm, Sm2O3, Sm(OH)3, SmCl3, Sm(NO3)2, Eu, Eu2O3, Eu(OH)3, EuCl3, Eu(NO3)2, Gd, Gd2O3, Gd(OH)3, GdCl3, Gd(NO3)2, Ce, Ce(OH)4, CeO2, Ce2O3, CeCl4, Ce(NO3)2, Th, ThO2, ThCl4, Th(OH)4, Zr, ZrO2, ZrCl4, Zr(OH)4, ZrOCl2, ZrO(NO3)2, P, phosphorous oxides, phosphorous chlorides, phosphorous carbonates, Ni, nickel oxides, nickel chlorides, nickel carbonates, nickel hydroxides, Nb, niobium oxides, niobium chlorides, niobium carbonates, niobium hydroxides, Au, gold oxides, gold chlorides, gold carbonates, gold hydroxides, Mo, molybdenum oxides, molybdenum chlorides, molybdenum carbonates, molybdenum hydroxides, tungsten chlorides, tungsten carbonates, tungsten hydroxides, Cr, chromium oxides, chromium chlorides, chromium hydroxides, Mn, manganese oxides, manganese chlorides, manganese hydroxides, Zn, ZnO, ZnCl2, Zn(OH)2, B, borates, BCl3, N, nitrogen oxides, nitrates, La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, In, Y, Sc, Al, Cu, Cs, Ga, Hf, Fe, Ru, Rh, Be, Co, Sb, V, Ag, Te, Pd, Tb, Ir, Rb or combinations thereof. In other embodiments, the nanowire dopant comprises Na, Eu, In, Nd, Sm, Ce, Gd, Y, Sc or combinations thereof.
In other embodiments, the nanowire dopant comprises Li, Li2O, Na, Na2O, K, K2O, Mg, MgO, Ca, CaO, Sr, SrO, Ba, BaO, La, La2O3, Ce, CeO2, Ce2O3, Th, ThO2, Zr, ZrO2, P, phosphorous oxides, Ni, nickel oxides, Nb, niobium oxides, Au, gold oxides, Mo, molybdenum oxides, Cr, chromium oxides, Mn, manganese oxides, Zn, ZnO, B, borates, N, nitrogen oxides or combinations thereof. In other embodiments, the nanowire dopant comprises Li, Na, K, Mg, Ca, Sr, Ba, La, Ce, Th, Zr, P, Ni, Nb, Au, Mo, Cr, Mn, Zn, B, N or combinations thereof. In other embodiments, the nanowire dopant comprises Li2O, Na2O, K2O, MgO, CaO, SrO, BaO, La2O3, CeO2, Ce2O3, ThO2, ZrO2, phosphorous oxides, nickel oxides, niobium oxides, gold oxides, molybdenum oxides, chromium oxides, manganese oxides, ZnO, borates, nitrogen oxides or combinations thereof. In further embodiments, the dopant comprises Sr or Li. In other specific embodiments, the nanowire dopant comprises La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, In, Y, Sc or combinations thereof. In other specific embodiments, the nanowire dopant comprises Li, Na, K, Mg, Ca, Ba, Sr, Eu, Sm, Co or Mn.
In certain embodiments, the dopant comprises an element from group 1. In some embodiments, the dopant comprises lithium. In some embodiments, the dopant comprises sodium. In some embodiments, the dopant comprises potassium. In some embodiments, the dopant comprises rubidium. In some embodiments, the dopant comprises caesium.
In some embodiments the nanowires comprise a lanthanide element and are doped with a dopant from group 1, group 2, or combinations thereof. For example, in some embodiments, the nanowires comprise a lanthanide element and are doped with lithium. In other embodiments, the nanowires comprise a lanthanide element and are doped with sodium. In other embodiments, the nanowires comprise a lanthanide element and are doped with potassium. In other embodiments, the nanowires comprise a lanthanide element and are doped with rubidium. In other embodiments, the nanowires comprise a lanthanide element and are doped with caesium. In other embodiments, the nanowires comprise a lanthanide element and are doped with beryllium. In other embodiments, the nanowires comprise a lanthanide element and are doped with magnesium. In other embodiments, the nanowires comprise a lanthanide element and are doped with calcium. In other embodiments, the nanowires comprise a lanthanide element and are doped with strontium. In other embodiments, the nanowires comprise a lanthanide element and are doped with barium.
In some embodiments the nanowires comprise a transition metal tungstate (e.g., Mn/W and the like) and are doped with a dopant from group 1, group 2, or combinations thereof. For example, in some embodiments, the nanowires comprise a transition metal tungstate and are doped with lithium. In other embodiments, the nanowires comprise a transition metal tungstate and are doped with sodium. In other embodiments, the nanowires comprise a transition metal tungstate and are doped with potassium. In other embodiments, the nanowires comprise a transition metal tungstate and are doped with rubidium. In other embodiments, the nanowires comprise a transition metal tungstate and are doped with caesium. In other embodiments, the nanowires comprise a transition metal tungstate and are doped with beryllium. In other embodiments, the nanowires comprise a transition metal tungstate and are doped with magnesium. In other embodiments, the nanowires comprise a transition metal tungstate and are doped with calcium. In other embodiments, the nanowires comprise a transition metal tungstate and are doped with strontium. In other embodiments, the nanowires comprises a transition metal tungstate and are doped with barium.
In some embodiments the nanowires comprise Mn/Mg/O and are doped with a dopant from group 1, group 2, group 7, group 8, group 9 or group 10 or combinations thereof. For example, in some embodiments, the nanowires comprise Mn/Mg/O and are doped with lithium. In other embodiments, the nanowires comprise Mn/Mg/O and are doped with sodium. In other embodiments, the nanowires comprise Mn/Mg/O and are doped with potassium. In other embodiments, the nanowires comprise Mn/Mg/O and are doped with rubidium. In other embodiments, the nanowires comprise Mn/Mg/O and are doped with caesium. In other embodiments, the nanowires comprise Mn/Mg/O and are doped with beryllium. In other embodiments, the nanowires comprise Mn/Mg/O and are doped with magnesium. In other embodiments, the nanowires comprise Mn/Mg/O and are doped with calcium. In other embodiments, the nanowires comprise Mn/Mg/O and are doped with strontium. In other embodiments, the nanowires comprise Mn/Mg/O and are doped with barium.
In yet some other embodiments, the nanowires comprise Mn/Mg/O and are doped with manganese. In other embodiments, the nanowires comprise Mn/Mg/O and are doped with technetium. In other embodiments, the nanowires comprise Mn/Mg/O and are doped with rhenium. In other embodiments, the nanowires comprise Mn/Mg/O and are doped with bohrium. In other embodiments, the nanowires comprise Mn/Mg/O and are doped with iron. In other embodiments, the nanowires comprise Mn/Mg/O and are doped with ruthenium. In other embodiments, the nanowires comprise Mn/Mg/O and are doped with osmium. In other embodiments, the nanowires comprise Mn/Mg/O and are doped with hassium. In other embodiments, the nanowires comprise Mn/Mg/O and are doped with cobalt. In other embodiments, the nanowires comprise Mn/Mg/O and are doped with rhodium. In other embodiments, the nanowires comprise Mn/Mg/O and are doped with iridium. In other embodiments, the nanowires comprise Mn/Mg/O and are doped with meitnerium. In other embodiments, the nanowires comprise Mn/Mg/O and are doped with nickel. In other embodiments, the nanowires comprise Mn/Mg/O and are doped with palladium. In other embodiments, the nanowires comprise Mn/Mg/O and are doped with platinum. In other embodiments, the nanowires comprise Mn/Mg/O and are doped with darmistadtium.
It is contemplated that any one or more of the dopants disclosed herein can be combined with any one of the nanowires disclosed herein to form a doped nanowire comprising one, two, three or more dopants. Tables 1-8 below show exemplary doped nanowires in accordance with various specific embodiments. In some embodiments, the doped nanowires shown in tables 1-8 are doped with one, two, three or more additional dopants.







TABLE 1





NANOWIRES (NW) DOPED WITH SPECIFIC DOPANTS (DOP)

















Dop











NW
Li
Na
K
Rb





Li2O
Li/
Na/
K/
Rb/



Li2O
Li2O
Li2O
Li2O


Na2O
Li/
Na/
K/
Rb/



Na2O
Na2O
Na2O
Na2O


K2O
Li/
Na/
K/
Rb/



K2O
K2O
K2O
K2O


Rb2O
Li/
Na/
K/
Rb/



Rb2O
Rb2O
Rb2O
Rb2O


Cs2O
Li/
Na/
K/
Rb/



Cs2O
Cs2O
Cs2O
Cs2O


BeO
Li/
Na/
K/
Rb/



BeO
BeO
BeO
BeO


MgO
Li/
Na/
K/
Rb/



MgO
MgO
MgO
MgO


CaO
Li/
Na/
K/
Rb/



CaO
CaO
CaO
CaO


SrO
Li/
Na/
K/
Rb/



SrO
SrO
SrO
SrO


BaO
Li/
Na/
K/
Rb/



BaO
BaO
BaO
BaO


Sc2O3
Li/
Na/
K/
Rb/



Sc2O3
Sc2O3
Sc2O3
Sc2O3


Y2O3
Li/
Na/
K/
Rb/



Y2O3
Y2O3
Y2O3
Y2O3


La2O3
Li/
Na/
K/
Rb/



La2O3
La2O3
La2O3
La2O3


CeO2
Li/
Na/
K/
Rb/



CeO2
CeO2
CeO2
CeO2


Ce2O3
Li/
Na/
K/
Rb/



Ce2O3
Ce2O3
Ce2O3
Ce2O3


Pr2O3
Li/
Na/
K/
Rb/



Pr2O3
Pr2O3
Pr2O3
Pr2O3


Nd2O3
Li/
Na/
K/
Rb/



Nd2O3
Nd2O3
Nd2O3
Nd2O3


Sm2O3
Li/
Na/
K/
Rb/



Sm2O3
Sm2O3
Sm2O3
Sm2O3


Eu2O3
Li/
Na/
K/
Rb/



Eu2O3
Eu2O3
Eu2O3
Eu2O3


Gd2O3
Li/
Na/
K/
Rb/



Gd2O3
Gd2O3
Gd2O3
Gd2O3


Tb2O3
Li/
Na/
K/
Rb/



Tb2O3
Tb2O3
Tb2O3
Tb2O3


TbO2
Li/
Na/
K/
Rb/



TbO2
TbO2
TbO2
TbO2


Tb6O11
Li/
Na/
K/
Rb/



Tb6O11
Tb6O11
Tb6O11
Tb6O11


Dy2O3
Li/
Na/
K/
Rb/



Dy2O3
Dy2O3
Dy2O3
Dy2O3


Ho2O3
Li/
Na/
K/
Rb/



Ho2O3
Ho2O3
Ho2O3
Ho2O3


Er2O3
Li/
Na/
K/
Rb/



Er2O3
Er2O3
Er2O3
Er2O3


Tm2O3
Li/
Na/
K/
Rb/



Tm2O3
Tm2O3
Tm2O3
Tm2O3


Yb2O3
Li/
Na/
K/
Rb/



Yb2O3
Yb2O3
Yb2O3
Yb2O3


Lu2O3
Li/
Na/
K/
Rb/



Lu2O3
Lu2O3
Lu2O3
Lu2O3


Ac2O3
Li/
Na/
K/
Rb/



Ac2O3
Ac2O3
Ac2O3
Ac2O3


Th2O3
Li/
Na/
K/
Rb/



Th2O3
Th2O3
Th2O3
Th2O3


ThO2
Li/
Na/
K/
Rb/



ThO2
ThO2
ThO2
ThO2


Pa2O3
Li/
Na/
K/
Rb/



Pa2O3
Pa2O3
Pa2O3
Pa2O3


PaO2
Li/
Na/
K/
Rb/



PaO2
PaO2
PaO2
PaO2


TiO2
Li/
Na/
K/
Rb/



TiO2
TiO2
TiO2
TiO2


TiO
Li/
Na/
K/
Rb/



TiO
TiO
TiO
TiO


Ti2O3
Li/
Na/
K/
Rb/



Ti2O3
Ti2O3
Ti2O3
Ti2O3


Ti3O
Li/
Na/
K/
Rb/



Ti3O
Ti3O
Ti3O
Ti3O


Ti2O
Li/
Na/
K/
Rb/



Ti2O
Ti2O
Ti2O
Ti2O


Ti3O5
Li/
Na/
K/
Rb/



Ti3O5
Ti3O5
Ti3O5
Ti3O5


Ti4O7
Li/
Na/
K/
Rb/



Ti4O7
Ti4O7
Ti4O7
Ti4O7


ZrO2
Li/
Na/
K/
Rb/



ZrO2
ZrO2
ZrO2
ZrO2


HfO2
Li/
Na/
K/
Rb/



HfO2
HfO2
HfO2
HfO2


VO
Li/
Na/
K/
Rb/



VO
VO
VO
VO


V2O3
Li/
Na/
K/
Rb/



V2O3
V2O3
V2O3
V2O3


VO2
Li/
Na/
K/
Rb/



VO2
VO2
VO2
VO2


V2O5
Li/
Na/
K/
Rb/



V2O5
V2O5
V2O5
V2O5


V3O7
Li/
Na/
K/
Rb/



V3O7
V3O7
V3O7
V3O7


V4O9
Li/
Na/
K/
Rb/



V4O9
V4O9
V4O9
V4O9


V6O13
Li/
Na/
K/
Rb/



V6O13
V6O13
V6O13
V6O13


NbO
Li/
Na/
K/
Rb/



NbO
NbO
NbO
NbO


NbO2
Li/
Na/
K/
Rb/



NbO2
NbO2
NbO2
NbO2


Nb2O5
Li/
Na/
K/
Rb/



Nb2O5
Nb2O5
Nb2O5
Nb2O5


Nb8O19
Li/
Na/
K/
Rb/



Nb8O19
Nb8O19
Nb8O19
Nb8O19


Nb16O38
Li/
Na/
K/
Rb/



Nb16O38
Nb16O38
Nb16O38
Nb16O38


Nb12O29
Li/
Na/
K/
Rb/



Nb12O29
Nb12O29
Nb12O29
Nb12O29


Nb47O116
Li/
Na/
K/
Rb/



Nb47O116
Nb47O116
Nb47O116
Nb47O116


Ta2O5
Li/
Na/
K/
Rb/



Ta2O5
Ta2O5
Ta2O5
Ta2O5


CrO
Li/
Na/
K/
Rb/



CrO
CrO
CrO
CrO


Cr2O3
Li/
Na/
K/
Rb/



Cr2O3
Cr2O3
Cr2O3
Cr2O3


CrO2
Li/
Na/
K/
Rb/



CrO2
CrO2
CrO2
CrO2


CrO3
Li/
Na/
K/
Rb/



CrO3
CrO3
CrO3
CrO3


Cr8O21
Li/
Na/
K/
Rb/



Cr8O21
Cr8O21
Cr8O21
Cr8O21


MoO2
Li/
Na/
K/
Rb/



MoO2
MoO2
MoO2
MoO2


MoO3
Li/
Na/
K/
Rb/



MoO3
MoO3
MoO3
MoO3


W2O3
Li/
Na/
K/
Rb/



W2O3
W2O3
W2O3
W2O3


WoO2
Li/
Na/
K/
Rb/



WoO2
WoO2
WoO2
WoO2


WoO3
Li/
Na/
K/
Rb/



WoO3
WoO3
WoO3
WoO3


MnO
Li/
Na/
K/
Rb/



MnO
MnO
MnO
MnO


Mn/Mg/O
Li/
Na/
K/
Rb/



Mn/Mg/O
Mn/Mg/O
Mn/Mg/O
Mn/Mg/O


Mn3O4
Li/
Na/
K/
Rb/



Mn3O4
Mn3O4
Mn3O4
Mn3O4


Mn2O3
Li/
Na/
K/
Rb/



Mn2O3
Mn2O3
Mn2O3
Mn2O3


MnO2
Li/
Na/
K/
Rb/



MnO2
MnO2
MnO2
MnO2


Mn2O7
Li/
Na/
K/
Rb/



Mn2O7
Mn2O7
Mn2O7
Mn2O7


ReO2
Li/
Na/
K/
Rb/



ReO2
ReO2
ReO2
ReO2


ReO3
Li/
Na/
K/
Rb/



ReO3
ReO3
ReO3
ReO3


Re2O7
Li/
Na/
K/
Rb/



Re2O7
Re2O7
Re2O7
Re2O7


Mg3Mn3—B2O10
Li/
Na/
K/
Rb/



Mg3Mn3—B2O10
Mg3Mn3—B2O10
Mg3Mn3—B2O10
Mg3Mn3—B2O10


Mg3(BO3)2
Li/
Na/
K/
Rb/



Mg3(BO3)2
Mg3(BO3)2
Mg3(BO3)2
Mg3(BO3)2


Na2WO4
Li/
Na/
K/
Rb/



Na2WO4
Na2WO4
Na2WO4
Na2WO4


Mg6MnO8
Li/
Na/
K/
Rb/



Mg6MnO8
Mg6MnO8
Mg6MnO8
Mg6MnO8


(Li,Mg)6—MnO8
Li/
Na/
K/
Rb/



(Li,Mg)6—MnO8
(Li,Mg)6—MnO8
(Li,Mg)6—MnO8
(Li,Mg)6—MnO8


Mn2O4
Li/
Na/
K/
Rb/



Mn2O4
Mn2O4
Mn2O4
Mn2O4


Na4P2O7
Li/
Na/
K/
Rb/



Na4P2O7
Na4P2O7
Na4P2O7
Na4P2O7


Mo2O8
Li/
Na/
K/
Rb/



Mo2O8
Mo2O8
Mo2O8
Mo2O8


Mn3O4/
Li/
Na/
K/
Rb/


WO4
Mn3O4/
Mn3O4/
Mn3O4/
Mn3O4/



WO4
WO4
WO4
WO4


Na2WO4
Li/
Na/
K/
Rb/



Na2WO4
Na2WO4
Na2WO4
Na2WO4


Zr2Mo2O8
Li/
Na/
K/
Rb/



Zr2Mo2O8
Zr2Mo2O8
Zr2Mo2O8
Zr2Mo2O8


NaMnO4—/
Li/
Na/
K/
Rb/


MgO
NaMnO4—/
NaMnO4—/
NaMnO4—/
NaMnO4—/



MgO
MgO
MgO
MgO


Na10Mn—W5O17
Li/
Na/
K/
Rb/



Na10Mn—W5O17
Na10Mn—W5O17
Na10Mn—W5O17
Na10Mn—W5O17












Dop











NW
Cs
Be
Mg
Ca





Li2O
Cs/
Be/
Mg/
Ca/



Li2O
Li2O
Li2O
Li2O


Na2O
Cs/
Be/
Mg/
Ca/



Na2O
Na2O
Na2O
Na2O


K2O
Cs/
Be/
Mg/
Ca/



K2O
K2O
K2O
K2O


Rb2O
Cs/
Be/
Mg/
Ca/



Rb2O
Rb2O
Rb2O
Rb2O


Cs2O
Cs/
Be/
Mg/
Ca/



Cs2O
Cs2O
Cs2O
Cs2O


BeO
Cs/
Be/
Mg/
Ca/



BeO
BeO
BeO
BeO


MgO
Cs/
Be/
Mg/
Ca/



MgO
MgO
MgO
MgO


CaO
Cs/
Be/
Mg/
Ca/



CaO
CaO
CaO
CaO


SrO
Cs/
Be/
Mg/
Ca/



SrO
SrO
SrO
SrO


BaO
Cs/
Be/
Mg/
Ca/



BaO
BaO
BaO
BaO


Sc2O3
Cs/
Be/
Mg/
Ca/



Sc2O3
Sc2O3
Sc2O3
Sc2O3


Y2O3
Cs/
Be/
Mg/
Ca/



Y2O3
Y2O3
Y2O3
Y2O3


La2O3
Cs/
Be/
Mg/
Ca/



La2O3
La2O3
La2O3
La2O3


CeO2
Cs/
Be/
Mg/
Ca/



CeO2
CeO2
CeO2
CeO2


Ce2O3
Cs/
Be/
Mg/
Ca/



Ce2O3
Ce2O3
Ce2O3
Ce2O3


Pr2O3
Cs/
Be/
Mg/
Ca/



Pr2O3
Pr2O3
Pr2O3
Pr2O3


Nd2O3
Cs/
Be/
Mg/
Ca/



Nd2O3
Nd2O3
Nd2O3
Nd2O3


Sm2O3
Cs/
Be/
Mg/
Ca/



Sm2O3
Sm2O3
Sm2O3
Sm2O3


Eu2O3
Cs/
Be/
Mg/
Ca/



Eu2O3
Eu2O3
Eu2O3
Eu2O3


Gd2O3
Cs/
Be/
Mg/
Ca/



Gd2O3
Gd2O3
Gd2O3
Gd2O3


Tb2O3
Cs/
Be/
Mg/
Ca/



Tb2O3
Tb2O3
Tb2O3
Tb2O3


TbO2
Cs/
Be/
Mg/
Ca/



TbO2
TbO2
TbO2
TbO2


Tb6O11
Cs/
Be/
Mg/
Ca/



Tb6O11
Tb6O11
Tb6O11
Tb6O11


Dy2O3
Cs/
Be/
Mg/
Ca/



Dy2O3
Dy2O3
Dy2O3
Dy2O3


Ho2O3
Cs/
Be/
Mg/
Ca/



Ho2O3
Ho2O3
Ho2O3
Ho2O3


Er2O3
Cs/
Be/
Mg/
Ca/



Er2O3
Er2O3
Er2O3
Er2O3


Tm2O3
Cs/
Be/
Mg/
Ca/



Tm2O3
Tm2O3
Tm2O3
Tm2O3


Yb2O3
Cs/
Be/
Mg/
Ca/



Yb2O3
Yb2O3
Yb2O3
Yb2O3


Lu2O3
Cs/
Be/
Mg/
Ca/



Lu2O3
Lu2O3
Lu2O3
Lu2O3


Ac2O3
Cs/
Be/
Mg/
Ca/



Ac2O3
Ac2O3
Ac2O3
Ac2O3


Th2O3
Cs/
Be/
Mg/
Ca/



Th2O3
Th2O3
Th2O3
Th2O3


ThO2
Cs/
Be/
Mg/
Ca/



ThO2
ThO2
ThO2
ThO2


Pa2O3
Cs/
Be/
Mg/
Ca/



Pa2O3
Pa2O3
Pa2O3
Pa2O3


PaO2
Cs/
Be/
Mg/
Ca/



PaO2
PaO2
PaO2
PaO2


TiO2
Cs/
Be/
Mg/
Ca/



TiO2
TiO2
TiO2
TiO2


TiO
Cs/
Be/
Mg/
Ca/



TiO
TiO
TiO
TiO


Ti2O3
Cs/
Be/
Mg/
Ca/



Ti2O3
Ti2O3
Ti2O3
Ti2O3


Ti3O
Cs/
Be/
Mg/
Ca/



Ti3O
Ti3O
Ti3O
Ti3O


Ti2O
Cs/
Be/
Mg/
Ca/



Ti2O
Ti2O
Ti2O
Ti2O


Ti3O5
Cs/
Be/
Mg/
Ca/



Ti3O5
Ti3O5
Ti3O5
Ti3O5


Ti4O7
Cs/
Be/
Mg/
Ca/



Ti4O7
Ti4O7
Ti4O7
Ti4O7


ZrO2
Cs/
Be/
Mg/
Ca/



ZrO2
ZrO2
ZrO2
ZrO2


HfO2
Cs/
Be/
Mg/
Ca/



HfO2
HfO2
HfO2
HfO2


VO
Cs/
Be/
Mg/
Ca/



VO
VO
VO
VO


V2O3
Cs/
Be/
Mg/
Ca/



V2O3
V2O3
V2O3
V2O3


VO2
Cs/
Be/
Mg/
Ca/



VO2
VO2
VO2
VO2


V2O5
Cs/
Be/
Mg/
Ca/



V2O5
V2O5
V2O5
V2O5


V3O7
Cs/
Be/
Mg/
Ca/



V3O7
V3O7
V3O7
V3O7


V4O9
Cs/
Be/
Mg/
Ca/



V4O9
V4O9
V4O9
V4O9


V6O13
Cs/
Be/
Mg/
Ca/



V6O13
V6O13
V6O13
V6O13


NbO
Cs/
Be/
Mg/
Ca/



NbO
NbO
NbO
NbO


NbO2
Cs/
Be/
Mg/
Ca/



NbO2
NbO2
NbO2
NbO2


Nb2O5
Cs/
Be/
Mg/
Ca/



Nb2O5
Nb2O5
Nb2O5
Nb2O5


Nb8O19
Cs/
Be/
Mg/
Ca/



Nb8O19
Nb8O19
Nb8O19
Nb8O19


Nb16O38
Cs/
Be/
Mg/
Ca/



Nb16O38
Nb16O38
Nb16O38
Nb16O38


Nb12O29
Cs/
Be/
Mg/
Ca/



Nb12O29
Nb12O29
Nb12O29
Nb12O29


Nb47O116
Cs/
Be/
Mg/
Ca/



Nb47O116
Nb47O116
Nb47O116
Nb47O116


Ta2O5
Cs/
Be/
Mg/
Ca/



Ta2O5
Ta2O5
Ta2O5
Ta2O5


CrO
Cs/
Be/
Mg/
Ca/



CrO
CrO
CrO
CrO


Cr2O3
Cs/
Be/
Mg/
Ca/



Cr2O3
Cr2O3
Cr2O3
Cr2O3


CrO2
Cs/
Be/
Mg/
Ca/



CrO2
CrO2
CrO2
CrO2


CrO3
Cs/
Be/
Mg/
Ca/



CrO3
CrO3
CrO3
CrO3


Cr8O21
Cs/
Be/
Mg/
Ca/



Cr8O21
Cr8O21
Cr8O21
Cr8O21


MoO2
Cs/
Be/
Mg/
Ca/



MoO2
MoO2
MoO2
MoO2


MoO3
Cs/
Be/
Mg/
Ca/



MoO3
MoO3
MoO3
MoO3


W2O3
Cs/
Be/
Mg/
Ca/



W2O3
W2O3
W2O3
W2O3


WoO2
Cs/
Be/
Mg/
Ca/



WoO2
WoO2
WoO2
WoO2


WoO3
Cs/
Be/
Mg/
Ca/



WoO3
WoO3
WoO3
WoO3


MnO
Cs/
Be/
Mg/
Ca/



MnO
MnO
MnO
MnO


Mn/Mg/O
Cs/
Be/
Mg/
Ca/



Mn/Mg/O
Mn/Mg/O
Mn/Mg/O
Mn/Mg/O


Mn3O4
Cs/
Be/
Mg/
Ca/



Mn3O4
Mn3O4
Mn3O4
Mn3O4


Mn2O3
Cs/
Be/
Mg/
Ca/



Mn2O3
Mn2O3
Mn2O3
Mn2O3


MnO2
Cs/
Be/
Mg/
Ca/



MnO2
MnO2
MnO2
MnO2


Mn2O7
Cs/
Be/
Mg/
Ca/



Mn2O7
Mn2O7
Mn2O7
Mn2O7


ReO2
Cs/
Be/
Mg/
Ca/



ReO2
ReO2
ReO2
ReO2


ReO3
Cs/
Be/
Mg/
Ca/



ReO3
ReO3
ReO3
ReO3


Re2O7
Cs/
Be/
Mg/
Ca/



Re2O7
Re2O7
Re2O7
Re2O7


Mg3Mn3—B2O10
Cs/
Be/
Mg/
Ca/



Mg3Mn3—B2O10
Mg3Mn3—B2O10
Mg3Mn3—B2O10
Mg3Mn3—B2O10


Mg3(BO3)2
Cs/
Be/
Mg/
Ca/



Mg3(BO3)2
Mg3(BO3)2
Mg3(BO3)2
Mg3(BO3)2


Na2WO4
Cs/
Be/
Mg/
Ca/



Na2WO4
Na2WO4
Na2WO4
Na2WO4


Mg6MnO8
Cs/
Be/
Mg/
Ca/



Mg6MnO8
Mg6MnO8
Mg6MnO8
Mg6MnO8


(Li,Mg)6—MnO8
Cs/
Be/
Mg/
Ca/



(Li,Mg)6—MnO8
(Li,Mg)6—MnO8
(Li,Mg)6—MnO8
(Li,Mg)6—MnO8


Mn2O4
Cs/
Be/
Mg/
Ca/



Mn2O4
Mn2O4
Mn2O4
Mn2O4


Na4P2O7
Cs/
Be/
Mg/
Ca/



Na4P2O7
Na4P2O7
Na4P2O7
Na4P2O7


Mo2O8
Cs/
Be/
Mg/
Ca/



Mo2O8
Mo2O8
Mo2O8
Mo2O8


Mn3O4/
Cs/
Be/
Mg/
Ca/


WO4
Mn3O4/
Mn3O4/
Mn3O4/
Mn3O4/



WO4
WO4
WO4
WO4


Na2WO4
Cs/
Be/
Mg/
Ca/



Na2WO4
Na2WO4
Na2WO4
Na2WO4


Zr2Mo2O8
Cs/
Be/
Mg/
Ca/



Zr2Mo2O8
Zr2Mo2O8
Zr2Mo2O8
Zr2Mo2O8


NaMnO4—/
Cs/
Be/
Mg/
Ca/


MgO
NaMnO4—/
NaMnO4—/
NaMnO4—/
NaMnO4—/



MgO
MgO
MgO
MgO


Na10Mn—W5O17
Cs/
Be/
Mg/
Ca/



Na10Mn—W5O17
Na10Mn—W5O17
Na10Mn—W5O17
Na10Mn—W5O17
















TABLE 2





NANOWIRES (NW) DOPED WITH SPECIFIC DOPANTS (DOP)

















Dop











NW
Sr
Ba
B
P





Li2O
Sr/
Ba/
B/
P/



Li2O
Li2O
Li2O
Li2O


Na2O
Sr/
Ba/
B/
P/



Na2O
Na2O
Na2O
Na2O


K2O
Sr/
Ba/
B/
P/



K2O
K2O
K2O
K2O


Rb2O
Sr/
Ba/
B/
P/



Rb2O
Rb2O
Rb2O
Rb2O


Cs2O
Sr/
Ba/
B/
P/



Cs2O
Cs2O
Cs2O
Cs2O


BeO
Sr/
Ba/
B/
P/



BeO
BeO
BeO
BeO


MgO
Sr/
Ba/
B/
P/



MgO
MgO
MgO
MgO


CaO
Sr/
Ba/
B/
P/



CaO
CaO
CaO
CaO


SrO
Sr/
Ba/
B/
P/



SrO
SrO
SrO
SrO


BaO
Sr/
Ba/
B/
P/



BaO
BaO
BaO
BaO


Sc2O3
Sr/
Ba/
B/
P/



Sc2O3
Sc2O3
Sc2O3
Sc2O3


Y2O3
Sr/
Ba/
B/
P/



Y2O3
Y2O3
Y2O3
Y2O3


La2O3
Sr/
Ba/
B/
P/



La2O3
La2O3
La2O3
La2O3


CeO2
Sr/
Ba/
B/
P/



CeO2
CeO2
CeO2
CeO2


Ce2O3
Sr/
Ba/
B/
P/



Ce2O3
Ce2O3
Ce2O3
Ce2O3


Pr2O3
Sr/
Ba/
B/
P/



Pr2O3
Pr2O3
Pr2O3
Pr2O3


Nd2O3
Sr/
Ba/
B/
P/



Nd2O3
Nd2O3
Nd2O3
Nd2O3


Sm2O3
Sr/
Ba/
B/
P/



Sm2O3
Sm2O3
Sm2O3
Sm2O3


Eu2O3
Sr/
Ba/
B/
P/



Eu2O3
Eu2O3
Eu2O3
Eu2O3


Gd2O3
Sr/
Ba/
B/
P/



Gd2O3
Gd2O3
Gd2O3
Gd2O3


Tb2O3
Sr/
Ba/
B/
P/



Tb2O3
Tb2O3
Tb2O3
Tb2O3


TbO2
Sr/
Ba/
B/
P/



TbO2
TbO2
TbO2
TbO2


Tb6O11
Sr/
Ba/
B/
P/



Tb6O11
Tb6O11
Tb6O11
Tb6O11


Dy2O3
Sr/
Ba/
B/
P/



Dy2O3
Dy2O3
Dy2O3
Dy2O3


Ho2O3
Sr/
Ba/
B/
P/



Ho2O3
Ho2O3
Ho2O3
Ho2O3


Er2O3
Sr/
Ba/
B/
P/



Er2O3
Er2O3
Er2O3
Er2O3


Tm2O3
Sr/
Ba/
B/
P/



Tm2O3
Tm2O3
Tm2O3
Tm2O3


Yb2O3
Sr/
Ba/
B/
P/



Yb2O3
Yb2O3
Yb2O3
Yb2O3


Lu2O3
Sr/
Ba/
B/
P/



Lu2O3
Lu2O3
Lu2O3
Lu2O3


Ac2O3
Sr/
Ba/
B/
P/



Ac2O3
Ac2O3
Ac2O3
Ac2O3


Th2O3
Sr/
Ba/
B/
P/



Th2O3
Th2O3
Th2O3
Th2O3


ThO2
Sr/
Ba/
B/
P/



ThO2
ThO2
ThO2
ThO2


Pa2O3
Sr/
Ba/
B/
P/



Pa2O3
Pa2O3
Pa2O3
Pa2O3


PaO2
Sr/
Ba/
B/
P/



PaO2
PaO2
PaO2
PaO2


TiO2
Sr/
Ba/
B/
P/



TiO2
TiO2
TiO2
TiO2


TiO
Sr/
Ba/
B/
P/



TiO
TiO
TiO
TiO


Ti2O3
Sr/
Ba/
B/
P/



Ti2O3
Ti2O3
Ti2O3
Ti2O3


Ti3O
Sr/
Ba/
B/
P/



Ti3O
Ti3O
Ti3O
Ti3O


Ti2O
Sr/
Ba/
B/
P/



Ti2O
Ti2O
Ti2O
Ti2O


Ti3O5
Sr/
Ba/
B/
P/



Ti3O5
Ti3O5
Ti3O5
Ti3O5


Ti4O7
Sr/
Ba/
B/
P/



Ti4O7
Ti4O7
Ti4O7
Ti4O7


ZrO2
Sr/
Ba/
B/
P/



ZrO2
ZrO2
ZrO2
ZrO2


HfO2
Sr/
Ba/
B/
P/



HfO2
HfO2
HfO2
HfO2


VO
Sr/
Ba/
B/
P/



VO
VO
VO
VO


V2O3
Sr/
Ba/
B/
P/



V2O3
V2O3
V2O3
V2O3


VO2
Sr/
Ba/
B/
P/



VO2
VO2
VO2
VO2


V2O5
Sr/
Ba/
B/
P/



V2O5
V2O5
V2O5
V2O5


V3O7
Sr/
Ba/
B/
P/



V3O7
V3O7
V3O7
V3O7


V4O9
Sr/
Ba/
B/
P/



V4O9
V4O9
V4O9
V4O9


V6O13
Sr/
Ba/
B/
P/



V6O13
V6O13
V6O13
V6O13


NbO
Sr/
Ba/
B/
P/



NbO
NbO
NbO
NbO


NbO2
Sr/
Ba/
B/
P/



NbO2
NbO2
NbO2
NbO2


Nb2O5
Sr/
Ba/
B/
P/



Nb2O5
Nb2O5
Nb2O5
Nb2O5


Nb8O19
Sr/
Ba/
B/
P/



Nb8O19
Nb8O19
Nb8O19
Nb8O19


Nb16O38
Sr/
Ba/
B/
P/



Nb16O38
Nb16O38
Nb16O38
Nb16O38


Nb12O29
Sr/
Ba/
B/
P/



Nb12O29
Nb12O29
Nb12O29
Nb12O29


Nb47O116
Sr/
Ba/
B/
P/



Nb47O116
Nb47O116
Nb47O116
Nb47O116


Ta2O5
Sr/
Ba/
B/
P/



Ta2O5
Ta2O5
Ta2O5
Ta2O5


CrO
Sr/
Ba/
B/
P/



CrO
CrO
CrO
CrO


Cr2O3
Sr/
Ba/
B/
P/



Cr2O3
Cr2O3
Cr2O3
Cr2O3


CrO2
Sr/
Ba/
B/
P/



CrO2
CrO2
CrO2
CrO2


CrO3
Sr/
Ba/
B/
P/



CrO3
CrO3
CrO3
CrO3


Cr8O21
Sr/
Ba/
B/
P/



Cr8O21
Cr8O21
Cr8O21
Cr8O21


MoO2
Sr/
Ba/
B/
P/



MoO2
MoO2
MoO2
MoO2


MoO3
Sr/
Ba/
B/
P/



MoO3
MoO3
MoO3
MoO3


W2O3
Sr/
Ba/
B/
P/



W2O3
W2O3
W2O3
W2O3


WoO2
Sr/
Ba/
B/
P/



WoO2
WoO2
WoO2
WoO2


WoO3
Sr/
Ba/
B/
P/



WoO3
WoO3
WoO3
WoO3


MnO
Sr/
Ba/
B/
P/



MnO
MnO
MnO
MnO


Mn/Mg/O
Sr/
Ba/
B/
P/



Mn/Mg/O
Mn/Mg/O
Mn/Mg/O
Mn/Mg/O


Mn3O4
Sr/
Ba/
B/
P/



Mn3O4
Mn3O4
Mn3O4
Mn3O4


Mn2O3
Sr/
Ba/
B/
P/



Mn2O3
Mn2O3
Mn2O3
Mn2O3


MnO2
Sr/
Ba/
B/
P/



MnO2
MnO2
MnO2
MnO2


Mn2O7
Sr/
Ba/
B/
P/



Mn2O7
Mn2O7
Mn2O7
Mn2O7


ReO2
Sr/
Ba/
B/
P/



ReO2
ReO2
ReO2
ReO2


ReO3
Sr/
Ba/
B/
P/



ReO3
ReO3
ReO3
ReO3


Re2O7
Sr/
Ba/
B/
P/



Re2O7
Re2O7
Re2O7
Re2O7


Mg3Mn3—B2O10
Sr/
Ba/
B/
P/



Mg3Mn3—B2O10
Mg3Mn3—B2O10
Mg3Mn3—B2O10
Mg3Mn3—B2O10


Mg3(BO3)2
Sr/
Ba/
B/
P/



Mg3(BO3)2
Mg3(BO3)2
Mg3(BO3)2
Mg3(BO3)2


NaWO4
Sr/
Ba/
B/
P/



NaWO4
NaWO4
NaWO4
NaWO4


Mg6MnO8
Sr/
Ba/
B/
P/



Mg6MnO8
Mg6MnO8
Mg6MnO8
Mg6MnO8


(Li,Mg)6MnO8
Sr/
Ba/
B/
P/



(Li,Mg)6MnO8
(Li,Mg)6MnO8
(Li,Mg)6MnO8
(Li,Mg)6MnO8


Mn2O4
Sr/
Ba/
B/
P/



Mn2O4
Mn2O4
Mn2O4
Mn2O4


Na4P2O7
Sr/
Ba/
B/
P/



Na4P2O7
Na4P2O7
Na4P2O7
Na4P2O7


Mo2O8
Sr/
Ba/
B/
P/



Mo2O8
Mo2O8
Mo2O8
Mo2O8


Mn3O4/WO4
Sr/
Ba/
B/
P/



Mn3O4/WO4
Mn3O4/WO4
Mn3O4/WO4
Mn3O4/WO4


Na2WO4
Sr/
Ba/
B/
P/



Na2WO4
Na2WO4
Na2WO4
Na2WO4


Zr2Mo2O8
Sr/
Ba/
B/
P/



Zr2Mo2O8
Zr2Mo2O8
Zr2Mo2O8
Zr2Mo2O8


NaMnO4/MgO
Sr/
Ba/
B/
P/



NaMnO4/MgO
NaMnO4/MgO
NaMnO4/MgO
NaMnO4/MgO


Na10Mn—W5O17
Sr/
Ba/
B/
P/



Na10Mn—W5O17
Na10Mn—W5O17
Na10Mn—W5O17
Na10Mn—W5O17












Dop












NW
S
F
Cl







Li2O
S/
F/
Cl/




Li2O
Li2O
Li2O



Na2O
S/
F/
Cl/




Na2O
Na2O
Na2O



K2O
S/
F/
Cl/




K2O
K2O
K2O



Rb2O
S/
F/
Cl/




Rb2O
Rb2O
Rb2O



Cs2O
S/
F/
Cl/




Cs2O
Cs2O
Cs2O



BeO
S/
F/
Cl/




BeO
BeO
BeO



MgO
S/
F/
Cl/




MgO
MgO
MgO



CaO
S/
F/
Cl/




CaO
CaO
CaO



SrO
S/
F/
Cl/




SrO
SrO
SrO



BaO
S/
F/
Cl/




BaO
BaO
BaO



Sc2O3
S/
F/
Cl/




Sc2O3
Sc2O3
Sc2O3



Y2O3
S/
F/
Cl/




Y2O3
Y2O3
Y2O3



La2O3
S/
F/
Cl/




La2O3
La2O3
La2O3



CeO2
S/
F/
Cl/




CeO2
CeO2
CeO2



Ce2O3
S/
F/
Cl/




Ce2O3
Ce2O3
Ce2O3



Pr2O3
S/
F/
Cl/




Pr2O3
Pr2O3
Pr2O3



Nd2O3
S/
F/
Cl/




Nd2O3
Nd2O3
Nd2O3



Sm2O3
S/
F/
Cl/




Sm2O3
Sm2O3
Sm2O3



Eu2O3
S/
F/
Cl/




Eu2O3
Eu2O3
Eu2O3



Gd2O3
S/
F/
Cl/




Gd2O3
Gd2O3
Gd2O3



Tb2O3
S/
F/
Cl/




Tb2O3
Tb2O3
Tb2O3



TbO2
S/
F/
Cl/




TbO2
TbO2
TbO2



Tb6O11
S/
F/
Cl/




Tb6O11
Tb6O11
Tb6O11



Dy2O3
S/
F/
Cl/




Dy2O3
Dy2O3
Dy2O3



Ho2O3
S/
F/
Cl/




Ho2O3
Ho2O3
Ho2O3



Er2O3
S/
F/
Cl/




Er2O3
Er2O3
Er2O3



Tm2O3
S/
F/
Cl/




Tm2O3
Tm2O3
Tm2O3



Yb2O3
S/
F/
Cl/




Yb2O3
Yb2O3
Yb2O3



Lu2O3
S/
F/
Cl/




Lu2O3
Lu2O3
Lu2O3



Ac2O3
S/
F/
Cl/




Ac2O3
Ac2O3
Ac2O3



Th2O3
S/
F/
Cl/




Th2O3
Th2O3
Th2O3



ThO2
S/
F/
Cl/




ThO2
ThO2
ThO2



Pa2O3
S/
F/
Cl/




Pa2O3
Pa2O3
Pa2O3



PaO2
S/
F/
Cl/




PaO2
PaO2
PaO2



TiO2
S/
F/
Cl/




TiO2
TiO2
TiO2



TiO
S/
F/
Cl/




TiO
TiO
TiO



Ti2O3
S/
F/
Cl/




Ti2O3
Ti2O3
Ti2O3



Ti3O
S/
F/
Cl/




Ti3O
Ti3O
Ti3O



Ti2O
S/
F/
Cl/




Ti2O
Ti2O
Ti2O



Ti3O5
S/
F/
Cl/




Ti3O5
Ti3O5
Ti3O5



Ti4O7
S/
F/
Cl/




Ti4O7
Ti4O7
Ti4O7



ZrO2
S/
F/
Cl/




ZrO2
ZrO2
ZrO2



HfO2
S/
F/
Cl/




HfO2
HfO2
HfO2



VO
S/
F/
Cl/




VO
VO
VO



V2O3
S/
F/
Cl/




V2O3
V2O3
V2O3



VO2
S/
F/
Cl/




VO2
VO2
VO2



V2O5
S/
F/
Cl/




V2O5
V2O5
V2O5



V3O7
S/
F/
Cl/




V3O7
V3O7
V3O7



V4O9
S/
F/
Cl/




V4O9
V4O9
V4O9



V6O13
S/
F/
Cl/




V6O13
V6O13
V6O13



NbO
S/
F/
Cl/




NbO
NbO
NbO



NbO2
S/
F/
Cl/




NbO2
NbO2
NbO2



Nb2O5
S/
F/
Cl/




Nb2O5
Nb2O5
Nb2O5



Nb8O19
S/
F/
Cl/




Nb8O19
Nb8O19
Nb8O19



Nb16O38
S/
F/
Cl/




Nb16O38
Nb16O38
Nb16O38



Nb12O29
S/
F/
Cl/




Nb12O29
Nb12O29
Nb12O29



Nb47O116
S/
F/
Cl/




Nb47O116
Nb47O116
Nb47O116



Ta2O5
S/
F/
Cl/




Ta2O5
Ta2O5
Ta2O5



CrO
S/
F/
Cl/




CrO
CrO
CrO



Cr2O3
S/
F/
Cl/




Cr2O3
Cr2O3
Cr2O3



CrO2
S/
F/
Cl/




CrO2
CrO2
CrO2



CrO3
S/
F/
Cl/




CrO3
CrO3
CrO3



Cr8O21
S/
F/
Cl/




Cr8O21
Cr8O21
Cr8O21



MoO2
S/
F/
Cl/




MoO2
MoO2
MoO2



MoO3
S/
F/
Cl/




MoO3
MoO3
MoO3



W2O3
S/
F/
Cl/




W2O3
W2O3
W2O3



WoO2
S/
F/
Cl/




WoO2
WoO2
WoO2



WoO3
S/
F/
Cl/




WoO3
WoO3
WoO3



MnO
S/
F/
Cl/




MnO
MnO
MnO



Mn/Mg/O
S/
F/
Cl/




Mn/Mg/O
Mn/Mg/O
Mn/Mg/O



Mn3O4
S/
F/
Cl/




Mn3O4
Mn3O4
Mn3O4



Mn2O3
S/
F/
Cl/




Mn2O3
Mn2O3
Mn2O3



MnO2
S/
F/
Cl/




MnO2
MnO2
MnO2



Mn2O7
S/
F/
Cl/




Mn2O7
Mn2O7
Mn2O7



ReO2
S/
F/
Cl/




ReO2
ReO2
ReO2



ReO3
S/
F/
Cl/




ReO3
ReO3
ReO3



Re2O7
S/
F/
Cl/




Re2O7
Re2O7
Re2O7



Mg3Mn3—B2O10
S/
F/
Cl/




Mg3Mn3—B2O10
Mg3Mn3—B2O10
Mg3Mn3—B2O10



Mg3(BO3)2
S/
F/
Cl/




Mg3(BO3)2
Mg3(BO3)2
Mg3(BO3)2



NaWO4
S/
F/
Cl/




NaWO4
NaWO4
NaWO4



Mg6MnO8
S/
F/
Cl/




Mg6MnO8
Mg6MnO8
Mg6MnO8



(Li,Mg)6MnO8
S/
F/
Cl/




(Li,Mg)6MnO8
(Li,Mg)6MnO8
(Li,Mg)6MnO8



Mn2O4
S/
F/
Cl/




Mn2O4
Mn2O4
Mn2O4



Na4P2O7
S/
F/
Cl/




Na4P2O7
Na4P2O7
Na4P2O7



Mo2O8
S/
F/
Cl/




Mo2O8
Mo2O8
Mo2O8



Mn3O4/WO4
S/
F/
Cl/




Mn3O4/WO4
Mn3O4/WO4
Mn3O4/WO4



Na2WO4
S/
F/
Cl/




Na2WO4
Na2WO4
Na2WO4



Zr2Mo2O8
S/
F/
Cl/




Zr2Mo2O8
Zr2Mo2O8
Zr2Mo2O8



NaMnO4/MgO
S/
F/
Cl/




NaMnO4/MgO
NaMnO4/MgO
NaMnO4/MgO



Na10Mn—W5O17
S/
F/
Cl/




Na10Mn—W5O17
Na10Mn—W5O17
Na10Mn—W5O17

















TABLE 3





NANOWIRES (NW) DOPED WITH SPECIFIC DOPANTS (DOP)

















Dop











NW
La
Ce
Pr
Nd





Li2O
La/
Ce/
Pr/
Nd/



Li2O
Li2O
Li2O
Li2O


Na2O
La/
Ce/
Pr/
Nd/



Na2O
Na2O
Na2O
Na2O


K2O
La/
Ce/
Pr/
Nd/



K2O
K2O
K2O
K2O


Rb2O
La/
Ce/
Pr/
Nd/



Rb2O
Rb2O
Rb2O
Rb2O


Cs2O
La/
Ce/
Pr/
Nd/



Cs2O
Cs2O
Cs2O
Cs2O


BeO
La/
Ce/
Pr/
Nd/



BeO
BeO
BeO
BeO


MgO
La/
Ce/
Pr/
Nd/



MgO
MgO
MgO
MgO


CaO
La/
Ce/
Pr/
Nd/



CaO
CaO
CaO
CaO


SrO
La/
Ce/
Pr/
Nd/



SrO
SrO
SrO
SrO


BaO
La/
Ce/
Pr/
Nd/



BaO
BaO
BaO
BaO


Sc2O3
La/
Ce/
Pr/
Nd/



Sc2O3
Sc2O3
Sc2O3
Sc2O3


Y2O3
La/
Ce/
Pr/
Nd/



Y2O3
Y2O3
Y2O3
Y2O3


La2O3
La/
Ce/
Pr/
Nd/



La2O3
La2O3
La2O3
La2O3


CeO2
La/
Ce/
Pr/
Nd/



CeO2
CeO2
CeO2
CeO2


Ce2O3
La/
Ce/
Pr/
Nd/



Ce2O3
Ce2O3
Ce2O3
Ce2O3


Pr2O3
La/
Ce/
Pr/
Nd/



Pr2O3
Pr2O3
Pr2O3
Pr2O3


Nd2O3
La/
Ce/
Pr/
Nd/



Nd2O3
Nd2O3
Nd2O3
Nd2O3


Sm2O3
La/
Ce/
Pr/
Nd/



Sm2O3
Sm2O3
Sm2O3
Sm2O3


Eu2O3
La/
Ce/
Pr/
Nd/



Eu2O3
Eu2O3
Eu2O3
Eu2O3


Gd2O3
La/
Ce/
Pr/
Nd/



Gd2O3
Gd2O3
Gd2O3
Gd2O3


Tb2O3
La/
Ce/
Pr/
Nd/



Tb2O3
Tb2O3
Tb2O3
Tb2O3


TbO2
La/
Ce/
Pr/
Nd/



TbO2
TbO2
TbO2
TbO2


Tb6O11
La/
Ce/
Pr/
Nd/



Tb6O11
Tb6O11
Tb6O11
Tb6O11


Dy2O3
La/
Ce/
Pr/
Nd/



Dy2O3
Dy2O3
Dy2O3
Dy2O3


Ho2O3
La/
Ce/
Pr/
Nd/



Ho2O3
Ho2O3
Ho2O3
Ho2O3


Er2O3
La/
Ce/
Pr/
Nd/



Er2O3
Er2O3
Er2O3
Er2O3


Tm2O3
La/
Ce/
Pr/
Nd/



Tm2O3
Tm2O3
Tm2O3
Tm2O3


Yb2O3
La/
Ce/
Pr/
Nd/



Yb2O3
Yb2O3
Yb2O3
Yb2O3


Lu2O3
La/
Ce/
Pr/
Nd/



Lu2O3
Lu2O3
Lu2O3
Lu2O3


Ac2O3
La/
Ce/
Pr/
Nd/



Ac2O3
Ac2O3
Ac2O3
Ac2O3


Th2O3
La/
Ce/
Pr/
Nd/



Th2O3
Th2O3
Th2O3
Th2O3


ThO2
La/
Ce/
Pr/
Nd/



ThO2
ThO2
ThO2
ThO2


Pa2O3
La/
Ce/
Pr/
Nd/



Pa2O3
Pa2O3
Pa2O3
Pa2O3


PaO2
La/
Ce/
Pr/
Nd/



PaO2
PaO2
PaO2
PaO2


TiO2
La/
Ce/
Pr/
Nd/



TiO2
TiO2
TiO2
TiO2


TiO
La/
Ce/
Pr/
Nd/



TiO
TiO
TiO
TiO


Ti2O3
La/
Ce/
Pr/
Nd/



Ti2O3
Ti2O3
Ti2O3
Ti2O3


Ti3O
La/
Ce/
Pr/
Nd/



Ti3O
Ti3O
Ti3O
Ti3O


Ti2O
La/
Ce/
Pr/
Nd/



Ti2O
Ti2O
Ti2O
Ti2O


Ti3O5
La/
Ce/
Pr/
Nd/



Ti3O5
Ti3O5
Ti3O5
Ti3O5


Ti4O7
La/
Ce/
Pr/
Nd/



Ti4O7
Ti4O7
Ti4O7
Ti4O7


ZrO2
La/
Ce/
Pr/
Nd/



ZrO2
ZrO2
ZrO2
ZrO2


HfO2
La/
Ce/
Pr/
Nd/



HfO2
HfO2
HfO2
HfO2


VO
La/
Ce/
Pr/
Nd/



VO
VO
VO
VO


V2O3
La/
Ce/
Pr/
Nd/



V2O3
V2O3
V2O3
V2O3


VO2
La/
Ce/
Pr/
Nd/



VO2
VO2
VO2
VO2


V2O5
La/
Ce/
Pr/
Nd/



V2O5
V2O5
V2O5
V2O5


V3O7
La/
Ce/
Pr/
Nd/



V3O7
V3O7
V3O7
V3O7


V4O9
La/
Ce/
Pr/
Nd/



V4O9
V4O9
V4O9
V4O9


V6O13
La/
Ce/
Pr/
Nd/



V6O13
V6O13
V6O13
V6O13


NbO
La/
Ce/
Pr/
Nd/



NbO
NbO
NbO
NbO


NbO2
La/
Ce/
Pr/
Nd/



NbO2
NbO2
NbO2
NbO2


Nb2O5
La/
Ce/
Pr/
Nd/



Nb2O5
Nb2O5
Nb2O5
Nb2O5


Nb8O19
La/
Ce/
Pr/
Nd/



Nb8O19
Nb8O19
Nb8O19
Nb8O19


Nb16O38
La/
Ce/
Pr/
Nd/



Nb16O38
Nb16O38
Nb16O38
Nb16O38


Nb12O29
La/
Ce/
Pr/
Nd/



Nb12O29
Nb12O29
Nb12O29
Nb12O29


Nb47O116
La/
Ce/
Pr/
Nd/



Nb47O116
Nb47O116
Nb47O116
Nb47O116


Ta2O5
La/
Ce/
Pr/
Nd/



Ta2O5
Ta2O5
Ta2O5
Ta2O5


CrO
La/
Ce/
Pr/
Nd/



CrO
CrO
CrO
CrO


Cr2O3
La/
Ce/
Pr/
Nd/



Cr2O3
Cr2O3
Cr2O3
Cr2O3


CrO2
La/
Ce/
Pr/
Nd/



CrO2
CrO2
CrO2
CrO2


CrO3
La/
Ce/
Pr/
Nd/



CrO3
CrO3
CrO3
CrO3


Cr8O21
La/
Ce/
Pr/
Nd/



Cr8O21
Cr8O21
Cr8O21
Cr8O21


MoO2
La/
Ce/
Pr/
Nd/



MoO2
MoO2
MoO2
MoO2


MoO3
La/
Ce/
Pr/
Nd/



MoO3
MoO3
MoO3
MoO3


W2O3
La/
Ce/
Pr/
Nd/



W2O3
W2O3
W2O3
W2O3


WoO2
La/
Ce/
Pr/
Nd/



WoO2
WoO2
WoO2
WoO2


WoO3
La/
Ce/
Pr/
Nd/



WoO3
WoO3
WoO3
WoO3


MnO
La/
Ce/
Pr/
Nd/



MnO
MnO
MnO
MnO


Mn/Mg/O
La/
Ce/
Pr/
Nd/



Mn/Mg/O
Mn/Mg/O
Mn/Mg/O
Mn/Mg/O


Mn3O4
La/
Ce/
Pr/
Nd/



Mn3O4
Mn3O4
Mn3O4
Mn3O4


Mn2O3
La/
Ce/
Pr/
Nd/



Mn2O3
Mn2O3
Mn2O3
Mn2O3


MnO2
La/
Ce/
Pr/
Nd/



MnO2
MnO2
MnO2
MnO2


Mn2O7
La/
Ce/
Pr/
Nd/



Mn2O7
Mn2O7
Mn2O7
Mn2O7


ReO2
La/
Ce/
Pr/
Nd/



ReO2
ReO2
ReO2
ReO2


ReO3
La/
Ce/
Pr/
Nd/



ReO3
ReO3
ReO3
ReO3


Re2O7
La/
Ce/
Pr/
Nd/



Re2O7
Re2O7
Re2O7
Re2O7


Mg3Mn3—B2O10
La/
Ce/
Pr/
Nd/



Mg3Mn3—B2O10
Mg3Mn3—B2O10
Mg3Mn3—B2O10
Mg3Mn3—B2O10


Mg3(BO3)2
La/
Ce/
Pr/
Nd/



Mg3(BO3)2
Mg3(BO3)2
Mg3(BO3)2
Mg3(BO3)2


NaWO4
La/
Ce/
Pr/
Nd/



NaWO4
NaWO4
NaWO4
NaWO4


Mg6MnO8
La/
Ce/
Pr/
Nd/



Mg6MnO8
Mg6MnO8
Mg6MnO8
Mg6MnO8


(Li,Mg)6MnO8
La/
Ce/
Pr/
Nd/



(Li,Mg)6MnO8
(Li,Mg)6MnO8
(Li,Mg)6MnO8
(Li,Mg)6MnO8


Mn2O4
La/
Ce/
Pr/
Nd/



Mn2O4
Mn2O4
Mn2O4
Mn2O4


Na4P2O7
La/
Ce/
Pr/
Nd/



Na4P2O7
Na4P2O7
Na4P2O7
Na4P2O7


Mo2O8
La/
Ce/
Pr/
Nd/



Mo2O8
Mo2O8
Mo2O8
Mo2O8


Mn3O4/WO4
La/
Ce/
Pr/
Nd/



Mn3O4/WO4
Mn3O4/WO4
Mn3O4/WO4
Mn3O4/WO4


Na2WO4
La/
Ce/
Pr/
Nd/



Na2WO4
Na2WO4
Na2WO4
Na2WO4


Zr2Mo2O8
La/
Ce/
Pr/
Nd/



Zr2Mo2O8
Zr2Mo2O8
Zr2Mo2O8
Zr2Mo2O8


NaMnO4—/
La/
Ce/
Pr/
Nd/


MgO
NaMnO4—/
NaMnO4—/
NaMnO4—/
NaMnO4—/



MgO
MgO
MgO
MgO


Na10Mn—W5O17
La/
Ce/
Pr/
Nd/



Na10Mn—W5O17
Na10Mn—W5O17
Na10Mn—W5O17
Na10Mn—W5O17












Dop











NW
Pm
Sm
Eu
Gd





Li2O
Pm/
Sm/
Eu/
Gd/



Li2O
Li2O
Li2O
Li2O


Na2O
Pm/
Sm/
Eu/
Gd/



Na2O
Na2O
Na2O
Na2O


K2O
Pm/
Sm/
Eu/
Gd/



K2O
K2O
K2O
K2O


Rb2O
Pm/
Sm/
Eu/
Gd/



Rb2O
Rb2O
Rb2O
Rb2O


Cs2O
Pm/
Sm/
Eu/
Gd/



Cs2O
Cs2O
Cs2O
Cs2O


BeO
Pm/
Sm/
Eu/
Gd/



BeO
BeO
BeO
BeO


MgO
Pm/
Sm/
Eu/
Gd/



MgO
MgO
MgO
MgO


CaO
Pm/
Sm/
Eu/
Gd/



CaO
CaO
CaO
CaO


SrO
Pm/
Sm/
Eu/
Gd/



SrO
SrO
SrO
SrO


BaO
Pm/
Sm/
Eu/
Gd/



BaO
BaO
BaO
BaO


Sc2O3
Pm/
Sm/
Eu/
Gd/



Sc2O3
Sc2O3
Sc2O3
Sc2O3


Y2O3
Pm/
Sm/
Eu/
Gd/



Y2O3
Y2O3
Y2O3
Y2O3


La2O3
Pm/
Sm/
Eu/
Gd/



La2O3
La2O3
La2O3
La2O3


CeO2
Pm/
Sm/
Eu/
Gd/



CeO2
CeO2
CeO2
CeO2


Ce2O3
Pm/
Sm/
Eu/
Gd/



Ce2O3
Ce2O3
Ce2O3
Ce2O3


Pr2O3
Pm/
Sm/
Eu/
Gd/



Pr2O3
Pr2O3
Pr2O3
Pr2O3


Nd2O3
Pm/
Sm/
Eu/
Gd/



Nd2O3
Nd2O3
Nd2O3
Nd2O3


Sm2O3
Pm/
Sm/
Eu/
Gd/



Sm2O3
Sm2O3
Sm2O3
Sm2O3


Eu2O3
Pm/
Sm/
Eu/
Gd/



Eu2O3
Eu2O3
Eu2O3
Eu2O3


Gd2O3
Pm/
Sm/
Eu/
Gd/



Gd2O3
Gd2O3
Gd2O3
Gd2O3


Tb2O3
Pm/
Sm/
Eu/
Gd/



Tb2O3
Tb2O3
Tb2O3
Tb2O3


TbO2
Pm/
Sm/
Eu/
Gd/



TbO2
TbO2
TbO2
TbO2


Tb6O11
Pm/
Sm/
Eu/
Gd/



Tb6O11
Tb6O11
Tb6O11
Tb6O11


Dy2O3
Pm/
Sm/
Eu/
Gd/



Dy2O3
Dy2O3
Dy2O3
Dy2O3


Ho2O3
Pm/
Sm/
Eu/
Gd/



Ho2O3
Ho2O3
Ho2O3
Ho2O3


Er2O3
Pm/
Sm/
Eu/
Gd/



Er2O3
Er2O3
Er2O3
Er2O3


Tm2O3
Pm/
Sm/
Eu/
Gd/



Tm2O3
Tm2O3
Tm2O3
Tm2O3


Yb2O3
Pm/
Sm/
Eu/
Gd/



Yb2O3
Yb2O3
Yb2O3
Yb2O3


Lu2O3
Pm/
Sm/
Eu/
Gd/



Lu2O3
Lu2O3
Lu2O3
Lu2O3


Ac2O3
Pm/
Sm/
Eu/
Gd/



Ac2O3
Ac2O3
Ac2O3
Ac2O3


Th2O3
Pm/
Sm/
Eu/
Gd/



Th2O3
Th2O3
Th2O3
Th2O3


ThO2
Pm/
Sm/
Eu/
Gd/



ThO2
ThO2
ThO2
ThO2


Pa2O3
Pm/
Sm/
Eu/
Gd/



Pa2O3
Pa2O3
Pa2O3
Pa2O3


PaO2
Pm/
Sm/
Eu/
Gd/



PaO2
PaO2
PaO2
PaO2


TiO2
Pm/
Sm/
Eu/
Gd/



TiO2
TiO2
TiO2
TiO2


TiO
Pm/
Sm/
Eu/
Gd/



TiO
TiO
TiO
TiO


Ti2O3
Pm/
Sm/
Eu/
Gd/



Ti2O3
Ti2O3
Ti2O3
Ti2O3


Ti3O
Pm/
Sm/
Eu/
Gd/



Ti3O
Ti3O
Ti3O
Ti3O


Ti2O
Pm/
Sm/
Eu/
Gd/



Ti2O
Ti2O
Ti2O
Ti2O


Ti3O5
Pm/
Sm/
Eu/
Gd/



Ti3O5
Ti3O5
Ti3O5
Ti3O5


Ti4O7
Pm/
Sm/
Eu/
Gd/



Ti4O7
Ti4O7
Ti4O7
Ti4O7


ZrO2
Pm/
Sm/
Eu/
Gd/



ZrO2
ZrO2
ZrO2
ZrO2


HfO2
Pm/
Sm/
Eu/
Gd/



HfO2
HfO2
HfO2
HfO2


VO
Pm/
Sm/
Eu/
Gd/



VO
VO
VO
VO


V2O3
Pm/
Sm/
Eu/
Gd/



V2O3
V2O3
V2O3
V2O3


VO2
Pm/
Sm/
Eu/
Gd/



VO2
VO2
VO2
VO2


V2O5
Pm/
Sm/
Eu/
Gd/



V2O5
V2O5
V2O5
V2O5


V3O7
Pm/
Sm/
Eu/
Gd/



V3O7
V3O7
V3O7
V3O7


V4O9
Pm/
Sm/
Eu/
Gd/



V4O9
V4O9
V4O9
V4O9


V6O13
Pm/
Sm/
Eu/
Gd/



V6O13
V6O13
V6O13
V6O13


NbO
Pm/
Sm/
Eu/
Gd/



NbO
NbO
NbO
NbO


NbO2
Pm/
Sm/
Eu/
Gd/



NbO2
NbO2
NbO2
NbO2


Nb2O5
Pm/
Sm/
Eu/
Gd/



Nb2O5
Nb2O5
Nb2O5
Nb2O5


Nb8O19
Pm/
Sm/
Eu/
Gd/



Nb8O19
Nb8O19
Nb8O19
Nb8O19


Nb16O38
Pm/
Sm/
Eu/
Gd/



Nb16O38
Nb16O38
Nb16O38
Nb16O38


Nb12O29
Pm/
Sm/
Eu/
Gd/



Nb12O29
Nb12O29
Nb12O29
Nb12O29


Nb47O116
Pm/
Sm/
Eu/
Gd/



Nb47O116
Nb47O116
Nb47O116
Nb47O116


Ta2O5
Pm/
Sm/
Eu/
Gd/



Ta2O5
Ta2O5
Ta2O5
Ta2O5


CrO
Pm/
Sm/
Eu/
Gd/



CrO
CrO
CrO
CrO


Cr2O3
Pm/
Sm/
Eu/
Gd/



Cr2O3
Cr2O3
Cr2O3
Cr2O3


CrO2
Pm/
Sm/
Eu/
Gd/



CrO2
CrO2
CrO2
CrO2


CrO3
Pm/
Sm/
Eu/
Gd/



CrO3
CrO3
CrO3
CrO3


Cr8O21
Pm/
Sm/
Eu/
Gd/



Cr8O21
Cr8O21
Cr8O21
Cr8O21


MoO2
Pm/
Sm/
Eu/
Gd/



MoO2
MoO2
MoO2
MoO2


MoO3
Pm/
Sm/
Eu/
Gd/



MoO3
MoO3
MoO3
MoO3


W2O3
Pm/
Sm/
Eu/
Gd/



W2O3
W2O3
W2O3
W2O3


WoO2
Pm/
Sm/
Eu/
Gd/



WoO2
WoO2
WoO2
WoO2


WoO3
Pm/
Sm/
Eu/
Gd/



WoO3
WoO3
WoO3
WoO3


MnO
Pm/
Sm/
Eu/
Gd/



MnO
MnO
MnO
MnO


Mn/Mg/O
Pm/
Sm/
Eu/
Gd/



Mn/Mg/O
Mn/Mg/O
Mn/Mg/O
Mn/Mg/O


Mn3O4
Pm/
Sm/
Eu/
Gd/



Mn3O4
Mn3O4
Mn3O4
Mn3O4


Mn2O3
Pm/
Sm/
Eu/
Gd/



Mn2O3
Mn2O3
Mn2O3
Mn2O3


MnO2
Pm/
Sm/
Eu/
Gd/



MnO2
MnO2
MnO2
MnO2


Mn2O7
Pm/
Sm/
Eu/
Gd/



Mn2O7
Mn2O7
Mn2O7
Mn2O7


ReO2
Pm/
Sm/
Eu/
Gd/



ReO2
ReO2
ReO2
ReO2


ReO3
Pm/
Sm/
Eu/
Gd/



ReO3
ReO3
ReO3
ReO3


Re2O7
Pm/
Sm/
Eu/
Gd/



Re2O7
Re2O7
Re2O7
Re2O7


Mg3Mn3—B2O10
Pm/
Sm/
Eu/
Gd/



Mg3Mn3—B2O10
Mg3Mn3—B2O10
Mg3Mn3—B2O10
Mg3Mn3—B2O10


Mg3(BO3)2
Pm/
Sm/
Eu/
Gd/



Mg3(BO3)2
Mg3(BO3)2
Mg3(BO3)2
Mg3(BO3)2


NaWO4
Pm/
Sm/
Eu/
Gd/



NaWO4
NaWO4
NaWO4
NaWO4


Mg6MnO8
Pm/
Sm/
Eu/
Gd/



Mg6MnO8
Mg6MnO8
Mg6MnO8
Mg6MnO8


(Li,Mg)6MnO8
Pm/
Sm/
Eu/
Gd/



(Li,Mg)6MnO8
(Li,Mg)6MnO8
(Li,Mg)6MnO8
(Li,Mg)6MnO8


Mn2O4
Pm/
Sm/
Eu/
Gd/



Mn2O4
Mn2O4
Mn2O4
Mn2O4


Na4P2O7
Pm/
Sm/
Eu/
Gd/



Na4P2O7
Na4P2O7
Na4P2O7
Na4P2O7


Mo2O8
Pm/
Sm/
Eu/
Gd/



Mo2O8
Mo2O8
Mo2O8
Mo2O8


Mn3O4/WO4
Pm/
Sm/
Eu/
Gd/



Mn3O4/WO4
Mn3O4/WO4
Mn3O4/WO4
Mn3O4/WO4


Na2WO4
Pm/
Sm/
Eu/
Gd/



Na2WO4
Na2WO4
Na2WO4
Na2WO4


Zr2Mo2O8
Pm/
Sm/
Eu/
Gd/



Zr2Mo2O8
Zr2Mo2O8
Zr2Mo2O8
Zr2Mo2O8


NaMnO4—/
Pm/
Sm/
Eu/
Gd/


MgO
NaMnO4—/
NaMnO4—/
NaMnO4—/
NaMnO4—/



MgO
MgO
MgO
MgO


Na10Mn—W5O17
Pm/
Sm/
Eu/
Gd/



Na10Mn—W5O17
Na10Mn—W5O17
Na10Mn—W5O17
Na10Mn—W5O17
















TABLE 4





NANOWIRES (NW) DOPED WITH SPECIFIC DOPANTS (DOP)

















Dop











NW
Tb
Dy
Ho
Er





Li2O
Tb/
Dy/
Ho/
Er/



Li2O
Li2O
Li2O
Li2O


Na2O
Tb/
Dy/
Ho/
Er/



Na2O
Na2O
Na2O
Na2O


K2O
Tb/
Dy/
Ho/
Er/



K2O
K2O
K2O
K2O


Rb2O
Tb/
Dy/
Ho/
Er/



Rb2O
Rb2O
Rb2O
Rb2O


Cs2O
Tb/
Dy/
Ho/
Er/



Cs2O
Cs2O
Cs2O
Cs2O


BeO
Tb/
Dy/
Ho/
Er/



BeO
BeO
BeO
BeO


MgO
Tb/
Dy/
Ho/
Er/



MgO
MgO
MgO
MgO


CaO
Tb/
Dy/
Ho/
Er/



CaO
CaO
CaO
CaO


SrO
Tb/
Dy/
Ho/
Er/



SrO
SrO
SrO
SrO


BaO
Tb/
Dy/
Ho/
Er/



BaO
BaO
BaO
BaO


Sc2O3
Tb/
Dy/
Ho/
Er/



Sc2O3
Sc2O3
Sc2O3
Sc2O3


Y2O3
Tb/
Dy/
Ho/
Er/



Y2O3
Y2O3
Y2O3
Y2O3


La2O3
Tb/
Dy/
Ho/
Er/



La2O3
La2O3
La2O3
La2O3


CeO2
Tb/
Dy/
Ho/
Er/



CeO2
CeO2
CeO2
CeO2


Ce2O3
Tb/
Dy/
Ho/
Er/



Ce2O3
Ce2O3
Ce2O3
Ce2O3


Pr2O3
Tb/
Dy/
Ho/
Er/



Pr2O3
Pr2O3
Pr2O3
Pr2O3


Nd2O3
Tb/
Dy/
Ho/
Er/



Nd2O3
Nd2O3
Nd2O3
Nd2O3


Sm2O3
Tb/
Dy/
Ho/
Er/



Sm2O3
Sm2O3
Sm2O3
Sm2O3


Eu2O3
Tb/
Dy/
Ho/
Er/



Eu2O3
Eu2O3
Eu2O3
Eu2O3


Gd2O3
Tb/
Dy/
Ho/
Er/



Gd2O3
Gd2O3
Gd2O3
Gd2O3


Tb2O3
Tb/
Dy/
Ho/
Er/



Tb2O3
Tb2O3
Tb2O3
Tb2O3


TbO2
Tb/
Dy/
Ho/
Er/



TbO2
TbO2
TbO2
TbO2


Tb6O11
Tb/
Dy/
Ho/
Er/



Tb6O11
Tb6O11
Tb6O11
Tb6O11


Dy2O3
Tb/
Dy/
Ho/
Er/



Dy2O3
Dy2O3
Dy2O3
Dy2O3


Ho2O3
Tb/
Dy/
Ho/
Er/



Ho2O3
Ho2O3
Ho2O3
Ho2O3


Er2O3
Tb/
Dy/
Ho/
Er/



Er2O3
Er2O3
Er2O3
Er2O3


Tm2O3
Tb/
Dy/
Ho/
Er/



Tm2O3
Tm2O3
Tm2O3
Tm2O3


Yb2O3
Tb/
Dy/
Ho/
Er/



Yb2O3
Yb2O3
Yb2O3
Yb2O3


Lu2O3
Tb/
Dy/
Ho/
Er/



Lu2O3
Lu2O3
Lu2O3
Lu2O3


Ac2O3
Tb/
Dy/
Ho/
Er/



Ac2O3
Ac2O3
Ac2O3
Ac2O3


Th2O3
Tb/
Dy/
Ho/
Er/



Th2O3
Th2O3
Th2O3
Th2O3


ThO2
Tb/
Dy/
Ho/
Er/



ThO2
ThO2
ThO2
ThO2


Pa2O3
Tb/
Dy/
Ho/
Er/



Pa2O3
Pa2O3
Pa2O3
Pa2O3


PaO2
Tb/
Dy/
Ho/
Er/



PaO2
PaO2
PaO2
PaO2


TiO2
Tb/
Dy/
Ho/
Er/



TiO2
TiO2
TiO2
TiO2


TiO
Tb/
Dy/
Ho/
Er/



TiO
TiO
TiO
TiO


Ti2O3
Tb/
Dy/
Ho/
Er/



Ti2O3
Ti2O3
Ti2O3
Ti2O3


Ti3O
Tb/
Dy/
Ho/
Er/



Ti3O
Ti3O
Ti3O
Ti3O


Ti2O
Tb/
Dy/
Ho/
Er/



Ti2O
Ti2O
Ti2O
Ti2O


Ti3O5
Tb/
Dy/
Ho/
Er/



Ti3O5
Ti3O5
Ti3O5
Ti3O5


Ti4O7
Tb/
Dy/
Ho/
Er/



Ti4O7
Ti4O7
Ti4O7
Ti4O7


ZrO2
Tb/
Dy/
Ho/
Er/



ZrO2
ZrO2
ZrO2
ZrO2


HfO2
Tb/
Dy/
Ho/
Er/



HfO2
HfO2
HfO2
HfO2


VO
Tb/
Dy/
Ho/
Er/



VO
VO
VO
VO


V2O3
Tb/
Dy/
Ho/
Er/



V2O3
V2O3
V2O3
V2O3


VO2
Tb/
Dy/
Ho/
Er/



VO2
VO2
VO2
VO2


V2O5
Tb/
Dy/
Ho/
Er/



V2O5
V2O5
V2O5
V2O5


V3O7
Tb/
Dy/
Ho/
Er/



V3O7
V3O7
V3O7
V3O7


V4O9
Tb/
Dy/
Ho/
Er/



V4O9
V4O9
V4O9
V4O9


V6O13
Tb/
Dy/
Ho/
Er/



V6O13
V6O13
V6O13
V6O13


NbO
Tb/
Dy/
Ho/
Er/



NbO
NbO
NbO
NbO


NbO2
Tb/
Dy/
Ho/
Er/



NbO2
NbO2
NbO2
NbO2


Nb2O5
Tb/
Dy/
Ho/
Er/



Nb2O5
Nb2O5
Nb2O5
Nb2O5


Nb8O19
Tb/
Dy/
Ho/
Er/



Nb8O19
Nb8O19
Nb8O19
Nb8O19


Nb16O38
Tb/
Dy/
Ho/
Er/



Nb16O38
Nb16O38
Nb16O38
Nb16O38


Nb12O29
Tb/
Dy/
Ho/
Er/



Nb12O29
Nb12O29
Nb12O29
Nb12O29


Nb47O116
Tb/
Dy/
Ho/
Er/



Nb47O116
Nb47O116
Nb47O116
Nb47O116


Ta2O5
Tb/
Dy/
Ho/
Er/



Ta2O5
Ta2O5
Ta2O5
Ta2O5


CrO
Tb/
Dy/
Ho/
Er/



CrO
CrO
CrO
CrO


Cr2O3
Tb/
Dy/
Ho/
Er/



Cr2O3
Cr2O3
Cr2O3
Cr2O3


CrO2
Tb/
Dy/
Ho/
Er/



CrO2
CrO2
CrO2
CrO2


CrO3
Tb/
Dy/
Ho/
Er/



CrO3
CrO3
CrO3
CrO3


Cr8O21
Tb/
Dy/
Ho/
Er/



Cr8O21
Cr8O21
Cr8O21
Cr8O21


MoO2
Tb/
Dy/
Ho/
Er/



MoO2
MoO2
MoO2
MoO2


MoO3
Tb/
Dy/
Ho/
Er/



MoO3
MoO3
MoO3
MoO3


W2O3
Tb/
Dy/
Ho/
Er/



W2O3
W2O3
W2O3
W2O3


WoO2
Tb/
Dy/
Ho/
Er/



WoO2
WoO2
WoO2
WoO2


WoO3
Tb/
Dy/
Ho/
Er/



WoO3
WoO3
WoO3
WoO3


MnO
Tb/
Dy/
Ho/
Er/



MnO
MnO
MnO
MnO


Mn/Mg/O
Tb/
Dy/
Ho/
Er/



Mn/Mg/O
Mn/Mg/O
Mn/Mg/O
Mn/Mg/O


Mn3O4
Tb/
Dy/
Ho/
Er/



Mn3O4
Mn3O4
Mn3O4
Mn3O4


Mn2O3
Tb/
Dy/
Ho/
Er/



Mn2O3
Mn2O3
Mn2O3
Mn2O3


MnO2
Tb/
Dy/
Ho/
Er/



MnO2
MnO2
MnO2
MnO2


Mn2O7
Tb/
Dy/
Ho/
Er/



Mn2O7
Mn2O7
Mn2O7
Mn2O7


ReO2
Tb/
Dy/
Ho/
Er/



ReO2
ReO2
ReO2
ReO2


ReO3
Tb/
Dy/
Ho/
Er/



ReO3
ReO3
ReO3
ReO3


Re2O7
Tb/
Dy/
Ho/
Er/



Re2O7
Re2O7
Re2O7
Re2O7


Mg3Mn3—B2O10
Tb/
Dy/
Ho/
Er/



Mg3Mn3—B2O10
Mg3Mn3—B2O10
Mg3Mn3—B2O10
Mg3Mn3—B2O10


Mg3(BO3)2
Tb/
Dy/
Ho/
Er/



Mg3(BO3)2
Mg3(BO3)2
Mg3(BO3)2
Mg3(BO3)2


NaWO4
Tb/
Dy/
Ho/
Er/



NaWO4
NaWO4
NaWO4
NaWO4


Mg6MnO8
Tb/
Dy/
Ho/
Er/



Mg6MnO8
Mg6MnO8
Mg6MnO8
Mg6MnO8


Mn2O4
Tb/
Dy/
Ho/
Er/



Mn2O4
Mn2O4
Mn2O4
Mn2O4


(Li,Mg)6MnO8
Tb/
Dy/
Ho/
Er/



(Li,Mg)6MnO8
(Li,Mg)6MnO8
(Li,Mg)6MnO8
(Li,Mg)6MnO8


Na4P2O7
Tb/
Dy/
Ho/
Er/



Na4P2O7
Na4P2O7
Na4P2O7
Na4P2O7


Mo2O8
Tb/
Dy/
Ho/
Er/



Mo2O8
Mo2O8
Mo2O8
Mo2O8


Mn3O4/WO4
Tb/
Dy/
Ho/
Er/



Mn3O4/WO4
Mn3O4/WO4
Mn3O4/WO4
Mn3O4/WO4


Na2WO4
Tb/
Dy/
Ho/
Er/



Na2WO4
Na2WO4
Na2WO4
Na2WO4


Zr2Mo2O8
Tb/
Dy/
Ho/
Er/



Zr2Mo2O8
Zr2Mo2O8
Zr2Mo2O8
Zr2Mo2O8


NaMnO4—/
Tb/
Dy/
Ho/
Er/


MgO
NaMnO4—/
NaMnO4—/
NaMnO4—/
NaMnO4—/



MgO
MgO
MgO
MgO


Na10Mn—W5O17
Tb/
Dy/
Ho/
Er/



Na10Mn—W5O17
Na10Mn—W5O17
Na10Mn—W5O17
Na10Mn—W5O17












Dop











NW
Tm
Yb
Lu
In





Li2O
Tm/
Yb/
Lu/
In/



Li2O
Li2O
Li2O
Li2O


Na2O
Tm/
Yb/
Lu/
In/



Na2O
Na2O
Na2O
Na2O


K2O
Tm/
Yb/
Lu/
In/



K2O
K2O
K2O
K2O


Rb2O
Tm/
Yb/
Lu/
In/



Rb2O
Rb2O
Rb2O
Rb2O


Cs2O
Tm/
Yb/
Lu/
In/



Cs2O
Cs2O
Cs2O
Cs2O


BeO
Tm/
Yb/
Lu/
In/



BeO
BeO
BeO
BeO


MgO
Tm/
Yb/
Lu/
In/



MgO
MgO
MgO
MgO


CaO
Tm/
Yb/
Lu/
In/



CaO
CaO
CaO
CaO


SrO
Tm/
Yb/
Lu/
In/



SrO
SrO
SrO
SrO


BaO
Tm/
Yb/
Lu/
In/



BaO
BaO
BaO
BaO


Sc2O3
Tm/
Yb/
Lu/
In/



Sc2O3
Sc2O3
Sc2O3
Sc2O3


Y2O3
Tm/
Yb/
Lu/
In/



Y2O3
Y2O3
Y2O3
Y2O3


La2O3
Tm/
Yb/
Lu/
In/



La2O3
La2O3
La2O3
La2O3


CeO2
Tm/
Yb/
Lu/
In/



CeO2
CeO2
CeO2
CeO2


Ce2O3
Tm/
Yb/
Lu/
In/



Ce2O3
Ce2O3
Ce2O3
Ce2O3


Pr2O3
Tm/
Yb/
Lu/
In/



Pr2O3
Pr2O3
Pr2O3
Pr2O3


Nd2O3
Tm/
Yb/
Lu/
In/



Nd2O3
Nd2O3
Nd2O3
Nd2O3


Sm2O3
Tm/
Yb/
Lu/
In/



Sm2O3
Sm2O3
Sm2O3
Sm2O3


Eu2O3
Tm/
Yb/
Lu/
In/



Eu2O3
Eu2O3
Eu2O3
Eu2O3


Gd2O3
Tm/
Yb/
Lu/
In/



Gd2O3
Gd2O3
Gd2O3
Gd2O3


Tb2O3
Tm/
Yb/
Lu/
In/



Tb2O3
Tb2O3
Tb2O3
Tb2O3


TbO2
Tm/
Yb/
Lu/
In/



TbO2
TbO2
TbO2
TbO2


Tb6O11
Tm/
Yb/
Lu/
In/



Tb6O11
Tb6O11
Tb6O11
Tb6O11


Dy2O3
Tm/
Yb/
Lu/
In/



Dy2O3
Dy2O3
Dy2O3
Dy2O3


Ho2O3
Tm/
Yb/
Lu/
In/



Ho2O3
Ho2O3
Ho2O3
Ho2O3


Er2O3
Tm/
Yb/
Lu/
In/



Er2O3
Er2O3
Er2O3
Er2O3


Tm2O3
Tm/
Yb/
Lu/
In/



Tm2O3
Tm2O3
Tm2O3
Tm2O3


Yb2O3
Tm/
Yb/
Lu/
In/



Yb2O3
Yb2O3
Yb2O3
Yb2O3


Lu2O3
Tm/
Yb/
Lu/
In/



Lu2O3
Lu2O3
Lu2O3
Lu2O3


Ac2O3
Tm/
Yb/
Lu/
In/



Ac2O3
Ac2O3
Ac2O3
Ac2O3


Th2O3
Tm/
Yb/
Lu/
In/



Th2O3
Th2O3
Th2O3
Th2O3


ThO2
Tm/
Yb/
Lu/
In/



ThO2
ThO2
ThO2
ThO2


Pa2O3
Tm/
Yb/
Lu/
In/



Pa2O3
Pa2O3
Pa2O3
Pa2O3


PaO2
Tm/
Yb/
Lu/
In/



PaO2
PaO2
PaO2
PaO2


TiO2
Tm/
Yb/
Lu/
In/



TiO2
TiO2
TiO2
TiO2


TiO
Tm/
Yb/
Lu/
In/



TiO
TiO
TiO
TiO


Ti2O3
Tm/
Yb/
Lu/
In/



Ti2O3
Ti2O3
Ti2O3
Ti2O3


Ti3O
Tm/
Yb/
Lu/
In/



Ti3O
Ti3O
Ti3O
Ti3O


Ti2O
Tm/
Yb/
Lu/
In/



Ti2O
Ti2O
Ti2O
Ti2O


Ti3O5
Tm/
Yb/
Lu/
In/



Ti3O5
Ti3O5
Ti3O5
Ti3O5


Ti4O7
Tm/
Yb/
Lu/
In/



Ti4O7
Ti4O7
Ti4O7
Ti4O7


ZrO2
Tm/
Yb/
Lu/
In/



ZrO2
ZrO2
ZrO2
ZrO2


HfO2
Tm/
Yb/
Lu/
In/



HfO2
HfO2
HfO2
HfO2


VO
Tm/
Yb/
Lu/
In/



VO
VO
VO
VO


V2O3
Tm/
Yb/
Lu/
In/



V2O3
V2O3
V2O3
V2O3


VO2
Tm/
Yb/
Lu/
In/



VO2
VO2
VO2
VO2


V2O5
Tm/
Yb/
Lu/
In/



V2O5
V2O5
V2O5
V2O5


V3O7
Tm/
Yb/
Lu/
In/



V3O7
V3O7
V3O7
V3O7


V4O9
Tm/
Yb/
Lu/
In/



V4O9
V4O9
V4O9
V4O9


V6O13
Tm/
Yb/
Lu/
In/



V6O13
V6O13
V6O13
V6O13


NbO
Tm/
Yb/
Lu/
In/



NbO
NbO
NbO
NbO


NbO2
Tm/
Yb/
Lu/
In/



NbO2
NbO2
NbO2
NbO2


Nb2O5
Tm/
Yb/
Lu/
In/



Nb2O5
Nb2O5
Nb2O5
Nb2O5


Nb8O19
Tm/
Yb/
Lu/
In/



Nb8O19
Nb8O19
Nb8O19
Nb8O19


Nb16O38
Tm/
Yb/
Lu/
In/



Nb16O38
Nb16O38
Nb16O38
Nb16O38


Nb12O29
Tm/
Yb/
Lu/
In/



Nb12O29
Nb12O29
Nb12O29
Nb12O29


Nb47O116
Tm/
Yb/
Lu/
In/



Nb47O116
Nb47O116
Nb47O116
Nb47O116


Ta2O5
Tm/
Yb/
Lu/
In/



Ta2O5
Ta2O5
Ta2O5
Ta2O5


CrO
Tm/
Yb/
Lu/
In/



CrO
CrO
CrO
CrO


Cr2O3
Tm/
Yb/
Lu/
In/



Cr2O3
Cr2O3
Cr2O3
Cr2O3


CrO2
Tm/
Yb/
Lu/
In/



CrO2
CrO2
CrO2
CrO2


CrO3
Tm/
Yb/
Lu/
In/



CrO3
CrO3
CrO3
CrO3


Cr8O21
Tm/
Yb/
Lu/
In/



Cr8O21
Cr8O21
Cr8O21
Cr8O21


MoO2
Tm/
Yb/
Lu/
In/



MoO2
MoO2
MoO2
MoO2


MoO3
Tm/
Yb/
Lu/
In/



MoO3
MoO3
MoO3
MoO3


W2O3
Tm/
Yb/
Lu/
In/



W2O3
W2O3
W2O3
W2O3


WoO2
Tm/
Yb/
Lu/
In/



WoO2
WoO2
WoO2
WoO2


WoO3
Tm/
Yb/
Lu/
In/



WoO3
WoO3
WoO3
WoO3


MnO
Tm/
Yb/
Lu/
In/



MnO
MnO
MnO
MnO


Mn/Mg/O
Tm/
Yb/
Lu/
In/



Mn/Mg/O
Mn/Mg/O
Mn/Mg/O
Mn/Mg/O


Mn3O4
Tm/
Yb/
Lu/
In/



Mn3O4
Mn3O4
Mn3O4
Mn3O4


Mn2O3
Tm/
Yb/
Lu/
In/



Mn2O3
Mn2O3
Mn2O3
Mn2O3


MnO2
Tm/
Yb/
Lu/
In/



MnO2
MnO2
MnO2
MnO2


Mn2O7
Tm/
Yb/
Lu/
In/



Mn2O7
Mn2O7
Mn2O7
Mn2O7


ReO2
Tm/
Yb/
Lu/
In/



ReO2
ReO2
ReO2
ReO2


ReO3
Tm/
Yb/
Lu/
In/



ReO3
ReO3
ReO3
ReO3


Re2O7
Tm/
Yb/
Lu/
In/



Re2O7
Re2O7
Re2O7
Re2O7


Mg3Mn3—B2O10
Tm/
Yb/
Lu/
In/



Mg3Mn3—B2O10
Mg3Mn3—B2O10
Mg3Mn3—B2O10
Mg3Mn3—B2O10


Mg3(BO3)2
Tm/
Yb/
Lu/
In/



Mg3(BO3)2
Mg3(BO3)2
Mg3(BO3)2
Mg3(BO3)2


NaWO4
Tm/
Yb/
Lu/
In/



NaWO4
NaWO4
NaWO4
NaWO4


Mg6MnO8
Tm/
Yb/
Lu/
In/



Mg6MnO8
Mg6MnO8
Mg6MnO8
Mg6MnO8


Mn2O4
Tm/
Yb/
Lu/
In/



Mn2O4
Mn2O4
Mn2O4
Mn2O4


(Li,Mg)6MnO8
Tm/
Yb/
Lu/
In/



(Li,Mg)6MnO8
(Li,Mg)6MnO8
(Li,Mg)6MnO8
(Li,Mg)6MnO8


Na4P2O7
Tm/
Yb/
Lu/
In/



Na4P2O7
Na4P2O7
Na4P2O7
Na4P2O7


Mo2O8
Tm/
Yb/
Lu/
In/



Mo2O8
Mo2O8
Mo2O8
Mo2O8


Mn3O4/WO4
Tm/
Yb/
Lu/
In/



Mn3O4/WO4
Mn3O4/WO4
Mn3O4/WO4
Mn3O4/WO4


Na2WO4
Tm/
Yb/
Lu/
In/



Na2WO4
Na2WO4
Na2WO4
Na2WO4


Zr2Mo2O8
Tm/
Yb/
Lu/
In/



Zr2Mo2O8
Zr2Mo2O8
Zr2Mo2O8
Zr2Mo2O8


NaMnO4—/
Tm/
Yb/
Lu/
In/


MgO
NaMnO4—/
NaMnO4—/
NaMnO4—/
NaMnO4—/



MgO
MgO
MgO
MgO


Na10Mn—W5O17
Tm/
Yb/
Lu/
In/



Na10Mn—W5O17
Na10Mn—W5O17
Na10Mn—W5O17
Na10Mn—W5O17
















TABLE 5





NANOWIRES (NW) DOPED WITH SPECIFIC DOPANTS (DOP)

















Dop











NW
Y
Sc
Al
Cu





Li2O
Y/
Sc/
Al/
Cu/



Li2O
Li2O
Li2O
Li2O


Na2O
Y/
Sc/
Al/
Cu/



Na2O
Na2O
Na2O
Na2O


K2O
Y/
Sc/
Al/
Cu/



K2O
K2O
K2O
K2O


Rb2O
Y/
Sc/
Al/
Cu/



Rb2O
Rb2O
Rb2O
Rb2O


Cs2O
Y/
Sc/
Al/
Cu/



Cs2O
Cs2O
Cs2O
Cs2O


BeO
Y/
Sc/
Al/
Cu/



BeO
BeO
BeO
BeO


MgO
Y/
Sc/
Al/
Cu/



MgO
MgO
MgO
MgO


CaO
Y/
Sc/
Al/
Cu/



CaO
CaO
CaO
CaO


SrO
Y/
Sc/
Al/
Cu/



SrO
SrO
SrO
SrO


BaO
Y/
Sc/
Al/
Cu/



BaO
BaO
BaO
BaO


Sc2O3
Y/
Sc/
Al/
Cu/



Sc2O3
Sc2O3
Sc2O3
Sc2O3


Y2O3
Y/
Sc/
Al/
Cu/



Y2O3
Y2O3
Y2O3
Y2O3


La2O3
Y/
Sc/
Al/
Cu/



La2O3
La2O3
La2O3
La2O3


CeO2
Y/
Sc/
Al/
Cu/



CeO2
CeO2
CeO2
CeO2


Ce2O3
Y/
Sc/
Al/
Cu/



Ce2O3
Ce2O3
Ce2O3
Ce2O3


Pr2O3
Y/
Sc/
Al/
Cu/



Pr2O3
Pr2O3
Pr2O3
Pr2O3


Nd2O3
Y/
Sc/
Al/
Cu/



Nd2O3
Nd2O3
Nd2O3
Nd2O3


Sm2O3
Y/
Sc/
Al/
Cu/



Sm2O3
Sm2O3
Sm2O3
Sm2O3


Eu2O3
Y/
Sc/
Al/
Cu/



Eu2O3
Eu2O3
Eu2O3
Eu2O3


Gd2O3
Y/
Sc/
Al/
Cu/



Gd2O3
Gd2O3
Gd2O3
Gd2O3


Tb2O3
Y/
Sc/
Al/
Cu/



Tb2O3
Tb2O3
Tb2O3
Tb2O3


TbO2
Y/
Sc/
Al/
Cu/



TbO2
TbO2
TbO2
TbO2


Tb6O11
Y/
Sc/
Al/
Cu/



Tb6O11
Tb6O11
Tb6O11
Tb6O11


Dy2O3
Y/
Sc/
Al/
Cu/



Dy2O3
Dy2O3
Dy2O3
Dy2O3


Ho2O3
Y/
Sc/
Al/
Cu/



Ho2O3
Ho2O3
Ho2O3
Ho2O3


Er2O3
Y/
Sc/
Al/
Cu/



Er2O3
Er2O3
Er2O3
Er2O3


Tm2O3
Y/
Sc/
Al/
Cu/



Tm2O3
Tm2O3
Tm2O3
Tm2O3


Yb2O3
Y/
Sc/
Al/
Cu/



Yb2O3
Yb2O3
Yb2O3
Yb2O3


Lu2O3
Y/
Sc/
Al/
Cu/



Lu2O3
Lu2O3
Lu2O3
Lu2O3


Ac2O3
Y/
Sc/
Al/
Cu/



Ac2O3
Ac2O3
Ac2O3
Ac2O3


Th2O3
Y/
Sc/
Al/
Cu/



Th2O3
Th2O3
Th2O3
Th2O3


ThO2
Y/
Sc/
Al/
Cu/



ThO2
ThO2
ThO2
ThO2


Pa2O3
Y/
Sc/
Al/
Cu/



Pa2O3
Pa2O3
Pa2O3
Pa2O3


PaO2
Y/
Sc/
Al/
Cu/



PaO2
PaO2
PaO2
PaO2


TiO2
Y/
Sc/
Al/
Cu/



TiO2
TiO2
TiO2
TiO2


TiO
Y/
Sc/
Al/
Cu/



TiO
TiO
TiO
TiO


Ti2O3
Y/
Sc/
Al/
Cu/



Ti2O3
Ti2O3
Ti2O3
Ti2O3


Ti3O
Y/
Sc/
Al/
Cu/



Ti3O
Ti3O
Ti3O
Ti3O


Ti2O
Y/
Sc/
Al/
Cu/



Ti2O
Ti2O
Ti2O
Ti2O


Ti3O5
Y/
Sc/
Al/
Cu/



Ti3O5
Ti3O5
Ti3O5
Ti3O5


Ti4O7
Y/
Sc/
Al/
Cu/



Ti4O7
Ti4O7
Ti4O7
Ti4O7


ZrO2
Y/
Sc/
Al/
Cu/



ZrO2
ZrO2
ZrO2
ZrO2


HfO2
Y/
Sc/
Al/
Cu/



HfO2
HfO2
HfO2
HfO2


VO
Y/
Sc/
Al/
Cu/



VO
VO
VO
VO


V2O3
Y/
Sc/
Al/
Cu/



V2O3
V2O3
V2O3
V2O3


VO2
Y/
Sc/
Al/
Cu/



VO2
VO2
VO2
VO2


V2O5
Y/
Sc/
Al/
Cu/



V2O5
V2O5
V2O5
V2O5


V3O7
Y/
Sc/
Al/
Cu/



V3O7
V3O7
V3O7
V3O7


V4O9
Y/
Sc/
Al/
Cu/



V4O9
V4O9
V4O9
V4O9


V6O13
Y/
Sc/
Al/
Cu/



V6O13
V6O13
V6O13
V6O13


NbO
Y/
Sc/
Al/
Cu/



NbO
NbO
NbO
NbO


NbO2
Y/
Sc/
Al/
Cu/



NbO2
NbO2
NbO2
NbO2


Nb2O5
Y/
Sc/
Al/
Cu/



Nb2O5
Nb2O5
Nb2O5
Nb2O5


Nb8O19
Y/
Sc/
Al/
Cu/



Nb8O19
Nb8O19
Nb8O19
Nb8O19


Nb16O38
Y/
Sc/
Al/
Cu/



Nb16O38
Nb16O38
Nb16O38
Nb16O38


Nb12O29
Y/
Sc/
Al/
Cu/



Nb12O29
Nb12O29
Nb12O29
Nb12O29


Nb47O116
Y/
Sc/
Al/
Cu/



Nb47O116
Nb47O116
Nb47O116
Nb47O116


Ta2O5
Y/
Sc/
Al/
Cu/



Ta2O5
Ta2O5
Ta2O5
Ta2O5


CrO
Y/
Sc/
Al/
Cu/



CrO
CrO
CrO
CrO


Cr2O3
Y/
Sc/
Al/
Cu/



Cr2O3
Cr2O3
Cr2O3
Cr2O3


CrO2
Y/
Sc/
Al/
Cu/



CrO2
CrO2
CrO2
CrO2


CrO3
Y/
Sc/
Al/
Cu/



CrO3
CrO3
CrO3
CrO3


Cr8O21
Y/
Sc/
Al/
Cu/



Cr8O21
Cr8O21
Cr8O21
Cr8O21


MoO2
Y/
Sc/
Al/
Cu/



MoO2
MoO2
MoO2
MoO2


MoO3
Y/
Sc/
Al/
Cu/



MoO3
MoO3
MoO3
MoO3


W2O3
Y/
Sc/
Al/
Cu/



W2O3
W2O3
W2O3
W2O3


WoO2
Y/
Sc/
Al/
Cu/



WoO2
WoO2
WoO2
WoO2


MnO
Y/
Sc/
Al/
Cu/



WoO3
WoO3
WoO3
WoO3


MnO
Y/
Sc/
Al/
Cu/



MnO
MnO
MnO
MnO


Mn/Mg/O
Y/
Sc/
Al/
Cu/



Mn/Mg/O
Mn/Mg/O
Mn/Mg/O
Mn/Mg/O


Mn3O4
Y/
Sc/
Al/
Cu/



Mn3O4
Mn3O4
Mn3O4
Mn3O4


Mn2O3
Y/
Sc/
Al/
Cu/



Mn2O3
Mn2O3
Mn2O3
Mn2O3


MnO2
Y/
Sc/
Al/
Cu/



MnO2
MnO2
MnO2
MnO2


Mn2O7
Y/
Sc/
Al/
Cu/



Mn2O7
Mn2O7
Mn2O7
Mn2O7


ReO2
Y/
Sc/
Al/
Cu/



ReO2
ReO2
ReO2
ReO2


ReO3
Y/
Sc/
Al/
Cu/



ReO3
ReO3
ReO3
ReO3


Re2O7
Y/
Sc/
Al/
Cu/



Re2O7
Re2O7
Re2O7
Re2O7


Mg3Mn3—B2O10
Y/
Sc/
Al/
Cu/



Mg3Mn3—B2O10
Mg3Mn3—B2O10
Mg3Mn3—B2O10
Mg3Mn3—B2O10


Mg3(BO3)2
Y/
Sc/
Al/
Cu/



Mg3(BO3)2
Mg3(BO3)2
Mg3(BO3)2
Mg3(BO3)2


NaWO4
Y/
Sc/
Al/
Cu/



NaWO4
NaWO4
NaWO4
NaWO4


Mg6MnO8
Y/
Sc/
Al/
Cu/



Mg6MnO8
Mg6MnO8
Mg6MnO8
Mg6MnO8


Mn2O4
Y/
Sc/
Al/
Cu/



Mn2O4
Mn2O4
Mn2O4
Mn2O4


(Li,Mg)6MnO8
Y/
Sc/
Al/
Cu/



(Li,Mg)6MnO8
(Li,Mg)6MnO8
(Li,Mg)6MnO8
(Li,Mg)6MnO8


Na4P2O7
Y/
Sc/
Al/
Cu/



Na4P2O7
Na4P2O7
Na4P2O7
Na4P2O7


Mo2O8
Y/
Sc/
Al/
Cu/



Mo2O8
Mo2O8
Mo2O8
Mo2O8


Mn3O4/WO4
Y/
Sc/
Al/
Cu/



Mn3O4/WO4
Mn3O4/WO4
Mn3O4/WO4
Mn3O4/WO4


Na2WO4
Y/
Sc/
Al/
Cu/



Na2WO4
Na2WO4
Na2WO4
Na2WO4


Zr2Mo2O8
Y/
Sc/
Al/
Cu/



Zr2Mo2O8
Zr2Mo2O8
Zr2Mo2O8
Zr2Mo2O8


NaMnO4—/
Y/
Sc/
Al/
Cu/


MgO
NaMnO4—/
NaMnO4—/
NaMnO4—/
NaMnO4—/



MgO
MgO
MgO
MgO


Na10Mn—W5O17
Y/
Sc/
Al/
Cu/



Na10Mn—W5O17
Na10Mn—W5O17
Na10Mn—W5O17
Na10Mn—W5O17












Dop











NW
Ga
Hf
Fe
Cr





Li2O
Ga/
Hf/
Fe/
Cr/



Li2O
Li2O
Li2O
Li2O


Na2O
Ga/
Hf/
Fe/
Cr/



Na2O
Na2O
Na2O
Na2O


K2O
Ga/
Hf/
Fe/
Cr/



K2O
K2O
K2O
K2O


Rb2O
Ga/
Hf/
Fe/
Cr/



Rb2O
Rb2O
Rb2O
Rb2O


Cs2O
Ga/
Hf/
Fe/
Cr/



Cs2O
Cs2O
Cs2O
Cs2O


BeO
Ga/
Hf/
Fe/
Cr/



BeO
BeO
BeO
BeO


MgO
Ga/
Hf/
Fe/
Cr/



MgO
MgO
MgO
MgO


CaO
Ga/
Hf/
Fe/
Cr/



CaO
CaO
CaO
CaO


SrO
Ga/
Hf/
Fe/
Cr/



SrO
SrO
SrO
SrO


BaO
Ga/
Hf/
Fe/
Cr/



BaO
BaO
BaO
BaO


Sc2O3
Ga/
Hf/
Fe/
Cr/



Sc2O3
Sc2O3
Sc2O3
Sc2O3


Y2O3
Ga/
Hf/
Fe/
Cr/



Y2O3
Y2O3
Y2O3
Y2O3


La2O3
Ga/
Hf/
Fe/
Cr/



La2O3
La2O3
La2O3
La2O3


CeO2
Ga/
Hf/
Fe/
Cr/



CeO2
CeO2
CeO2
CeO2


Ce2O3
Ga/
Hf/
Fe/
Cr/



Ce2O3
Ce2O3
Ce2O3
Ce2O3


Pr2O3
Ga/
Hf/
Fe/
Cr/



Pr2O3
Pr2O3
Pr2O3
Pr2O3


Nd2O3
Ga/
Hf/
Fe/
Cr/



Nd2O3
Nd2O3
Nd2O3
Nd2O3


Sm2O3
Ga/
Hf/
Fe/
Cr/



Sm2O3
Sm2O3
Sm2O3
Sm2O3


Eu2O3
Ga/
Hf/
Fe/
Cr/



Eu2O3
Eu2O3
Eu2O3
Eu2O3


Gd2O3
Ga/
Hf/
Fe/
Cr/



Gd2O3
Gd2O3
Gd2O3
Gd2O3


Tb2O3
Ga/
Hf/
Fe/
Cr/



Tb2O3
Tb2O3
Tb2O3
Tb2O3


TbO2
Ga/
Hf/
Fe/
Cr/



TbO2
TbO2
TbO2
TbO2


Tb6O11
Ga/
Hf/
Fe/
Cr/



Tb6O11
Tb6O11
Tb6O11
Tb6O11


Dy2O3
Ga/
Hf/
Fe/
Cr/



Dy2O3
Dy2O3
Dy2O3
Dy2O3


Ho2O3
Ga/
Hf/
Fe/
Cr/



Ho2O3
Ho2O3
Ho2O3
Ho2O3


Er2O3
Ga/
Hf/
Fe/
Cr/



Er2O3
Er2O3
Er2O3
Er2O3


Tm2O3
Ga/
Hf/
Fe/
Cr/



Tm2O3
Tm2O3
Tm2O3
Tm2O3


Yb2O3
Ga/
Hf/
Fe/
Cr/



Yb2O3
Yb2O3
Yb2O3
Yb2O3


Lu2O3
Ga/
Hf/
Fe/
Cr/



Lu2O3
Lu2O3
Lu2O3
Lu2O3


Ac2O3
Ga/
Hf/
Fe/
Cr/



Ac2O3
Ac2O3
Ac2O3
Ac2O3


Th2O3
Ga/
Hf/
Fe/
Cr/



Th2O3
Th2O3
Th2O3
Th2O3


ThO2
Ga/
Hf/
Fe/
Cr/



ThO2
ThO2
ThO2
ThO2


Pa2O3
Ga/
Hf/
Fe/
Cr/



Pa2O3
Pa2O3
Pa2O3
Pa2O3


PaO2
Ga/
Hf/
Fe/
Cr/



PaO2
PaO2
PaO2
PaO2


TiO2
Ga/
Hf/
Fe/
Cr/



TiO2
TiO2
TiO2
TiO2


TiO
Ga/
Hf/
Fe/
Cr/



TiO
TiO
TiO
TiO


Ti2O3
Ga/
Hf/
Fe/
Cr/



Ti2O3
Ti2O3
Ti2O3
Ti2O3


Ti3O
Ga/
Hf/
Fe/
Cr/



Ti3O
Ti3O
Ti3O
Ti3O


Ti2O
Ga/
Hf/
Fe/
Cr/



Ti2O
Ti2O
Ti2O
Ti2O


Ti3O5
Ga/
Hf/
Fe/
Cr/



Ti3O5
Ti3O5
Ti3O5
Ti3O5


Ti4O7
Ga/
Hf/
Fe/
Cr/



Ti4O7
Ti4O7
Ti4O7
Ti4O7


ZrO2
Ga/
Hf/
Fe/
Cr/



ZrO2
ZrO2
ZrO2
ZrO2


HfO2
Ga/
Hf/
Fe/
Cr/



HfO2
HfO2
HfO2
HfO2


VO
Ga/
Hf/
Fe/
Cr/



VO
VO
VO
VO


V2O3
Ga/
Hf/
Fe/
Cr/



V2O3
V2O3
V2O3
V2O3


VO2
Ga/
Hf/
Fe/
Cr/



VO2
VO2
VO2
VO2


V2O5
Ga/
Hf/
Fe/
Cr/



V2O5
V2O5
V2O5
V2O5


V3O7
Ga/
Hf/
Fe/
Cr/



V3O7
V3O7
V3O7
V3O7


V4O9
Ga/
Hf/
Fe/
Cr/



V4O9
V4O9
V4O9
V4O9


V6O13
Ga/
Hf/
Fe/
Cr/



V6O13
V6O13
V6O13
V6O13


NbO
Ga/
Hf/
Fe/
Cr/



NbO
NbO
NbO
NbO


NbO2
Ga/
Hf/
Fe/
Cr/



NbO2
NbO2
NbO2
NbO2


Nb2O5
Ga/
Hf/
Fe/
Cr/



Nb2O5
Nb2O5
Nb2O5
Nb2O5


Nb8O19
Ga/
Hf/
Fe/
Cr/



Nb8O19
Nb8O19
Nb8O19
Nb8O19


Nb16O38
Ga/
Hf/
Fe/
Cr/



Nb16O38
Nb16O38
Nb16O38
Nb16O38


Nb12O29
Ga/
Hf/
Fe/
Cr/



Nb12O29
Nb12O29
Nb12O29
Nb12O29


Nb47O116
Ga/
Hf/
Fe/
Cr/



Nb47O116
Nb47O116
Nb47O116
Nb47O116


Ta2O5
Ga/
Hf/
Fe/
Cr/



Ta2O5
Ta2O5
Ta2O5
Ta2O5


CrO
Ga/
Hf/
Fe/
Cr/



CrO
CrO
CrO
CrO


Cr2O3
Ga/
Hf/
Fe/
Cr/



Cr2O3
Cr2O3
Cr2O3
Cr2O3


CrO2
Ga/
Hf/
Fe/
Cr/



CrO2
CrO2
CrO2
CrO2


CrO3
Ga/
Hf/
Fe/
Cr/



CrO3
CrO3
CrO3
CrO3


Cr8O21
Ga/
Hf/
Fe/
Cr/



Cr8O21
Cr8O21
Cr8O21
Cr8O21


MoO2
Ga/
Hf/
Fe/
Cr/



MoO2
MoO2
MoO2
MoO2


MoO3
Ga/
Hf/
Fe/
Cr/



MoO3
MoO3
MoO3
MoO3


W2O3
Ga/
Hf/
Fe/
Cr/



W2O3
W2O3
W2O3
W2O3


WoO2
Ga/
Hf/
Fe/
Cr/



WoO2
WoO2
WoO2
WoO2


MnO
Ga/
Hf/
Fe/
Cr/



WoO3
WoO3
WoO3
WoO3


MnO
Ga/
Hf/
Fe/
Cr/



MnO
MnO
MnO
MnO


Mn/Mg/O
Ga/
Hf/
Fe/
Cr/



Mn/Mg/O
Mn/Mg/O
Mn/Mg/O
Mn/Mg/O


Mn3O4
Ga/
Hf/
Fe/
Cr/



Mn3O4
Mn3O4
Mn3O4
Mn3O4


Mn2O3
Ga/
Hf/
Fe/
Cr/



Mn2O3
Mn2O3
Mn2O3
Mn2O3


MnO2
Ga/
Hf/
Fe/
Cr/



MnO2
MnO2
MnO2
MnO2


Mn2O7
Ga/
Hf/
Fe/
Cr/



Mn2O7
Mn2O7
Mn2O7
Mn2O7


ReO2
Ga/
Hf/
Fe/
Cr/



ReO2
ReO2
ReO2
ReO2


ReO3
Ga/
Hf/
Fe/
Cr/



ReO3
ReO3
ReO3
ReO3


Re2O7
Ga/
Hf/
Fe/
Cr/



Re2O7
Re2O7
Re2O7
Re2O7


Mg3Mn3—B2O10
Ga/
Hf/
Fe/
Cr/



Mg3Mn3—B2O10
Mg3Mn3—B2O10
Mg3Mn3—B2O10
Mg3Mn3—B2O10


Mg3(BO3)2
Ga/
Hf/
Fe/
Cr/



Mg3(BO3)2
Mg3(BO3)2
Mg3(BO3)2
Mg3(BO3)2


NaWO4
Ga/
Hf/
Fe/
Cr/



NaWO4
NaWO4
NaWO4
NaWO4


Mg6MnO8
Ga/
Hf/
Fe/
Cr/



Mg6MnO8
Mg6MnO8
Mg6MnO8
Mg6MnO8


Mn2O4
Ga/
Hf/
Fe/
Cr/



Mn2O4
Mn2O4
Mn2O4
Mn2O4


(Li,Mg)6MnO8
Ga/
Hf/
Fe/
Cr/



(Li,Mg)6MnO8
(Li,Mg)6MnO8
(Li,Mg)6MnO8
(Li,Mg)6MnO8


Na4P2O7
Ga/
Hf/
Fe/
Cr/



Na4P2O7
Na4P2O7
Na4P2O7
Na4P2O7


Mo2O8
Ga/
Hf/
Fe/
Cr/



Mo2O8
Mo2O8
Mo2O8
Mo2O8


Mn3O4/WO4
Ga/
Hf/
Fe/
Cr/



Mn3O4/WO4
Mn3O4/WO4
Mn3O4/WO4
Mn3O4/WO4


Na2WO4
Ga/
Hf/
Fe/
Cr/



Na2WO4
Na2WO4
Na2WO4
Na2WO4


Zr2Mo2O8
Ga/
Hf/
Fe/
Cr/



Zr2Mo2O8
Zr2Mo2O8
Zr2Mo2O8
Zr2Mo2O8


NaMnO4—/
Ga/
Hf/
Fe/
Cr/


MgO
NaMnO4—/
NaMnO4—/
NaMnO4—/
NaMnO4—/



MgO
MgO
MgO
MgO


Na10Mn—W5O17
Ga/
Hf/
Fe/
Cr/



Na10Mn—W5O17
Na10Mn—W5O17
Na10Mn—W5O17
Na10Mn—W5O17
















TABLE 6





NANOWIRES (NW) DOPED WITH SPECIFIC DOPANTS (DOP)

















Dop











NW
Ru
Sr
Zr
Ta





Li2O
Ru/
Sr/
Zr/
Ta/



Li2O
Li2O
Li2O
Li2O


Na2O
Ru/
Sr/
Zr/
Ta/



Na2O
Na2O
Na2O
Na2O


K2O
Ru/
Sr/
Zr/
Ta/



K2O
K2O
K2O
K2O


Rb2O
Ru/
Sr/
Zr/
Ta/



Rb2O
Rb2O
Rb2O
Rb2O


Cs2O
Ru/
Sr/
Zr/
Ta/



Cs2O
Cs2O
Cs2O
Cs2O


BeO
Ru/
Sr/
Zr/
Ta/



BeO
BeO
BeO
BeO


MgO
Ru/
Sr/
Zr/
Ta/



MgO
MgO
MgO
MgO


CaO
Ru/
Sr/
Zr/
Ta/



CaO
CaO
CaO
CaO


SrO
Ru/
Sr/
Zr/
Ta/



SrO
SrO
SrO
SrO


BaO
Ru/
Sr/
Zr/
Ta/



BaO
BaO
BaO
BaO


Sc2O3
Ru/
Sr/
Zr/
Ta/



Sc2O3
Sc2O3
Sc2O3
Sc2O3


Y2O3
Ru/
Sr/
Zr/
Ta/



Y2O3
Y2O3
Y2O3
Y2O3


La2O3
Ru/
Sr/
Zr/
Ta/



La2O3
La2O3
La2O3
La2O3


CeO2
Ru/
Sr/
Zr/
Ta/



CeO2
CeO2
CeO2
CeO2


Ce2O3
Ru/
Sr/
Zr/
Ta/



Ce2O3
Ce2O3
Ce2O3
Ce2O3


Pr2O3
Ru/
Sr/
Zr/
Ta/



Pr2O3
Pr2O3
Pr2O3
Pr2O3


Nd2O3
Ru/
Sr/
Zr/
Ta/



Nd2O3
Nd2O3
Nd2O3
Nd2O3


Sm2O3
Ru/
Sr/
Zr/
Ta/



Sm2O3
Sm2O3
Sm2O3
Sm2O3


Eu2O3
Ru/
Sr/
Zr/
Ta/



Eu2O3
Eu2O3
Eu2O3
Eu2O3


Gd2O3
Ru/
Sr/
Zr/
Ta/



Gd2O3
Gd2O3
Gd2O3
Gd2O3


Tb2O3
Ru/
Sr/
Zr/
Ta/



Tb2O3
Tb2O3
Tb2O3
Tb2O3


TbO2
Ru/
Sr/
Zr/
Ta/



TbO2
TbO2
TbO2
TbO2


Tb6O11
Ru/
Sr/
Zr/
Ta/



Tb6O11
Tb6O11
Tb6O11
Tb6O11


Dy2O3
Ru/
Sr/
Zr/
Ta/



Dy2O3
Dy2O3
Dy2O3
Dy2O3


Ho2O3
Ru/
Sr/
Zr/
Ta/



Ho2O3
Ho2O3
Ho2O3
Ho2O3


Er2O3
Ru/
Sr/
Zr/
Ta/



Er2O3
Er2O3
Er2O3
Er2O3


Tm2O3
Ru/
Sr/
Zr/
Ta/



Tm2O3
Tm2O3
Tm2O3
Tm2O3


Yb2O3
Ru/
Sr/
Zr/
Ta/



Yb2O3
Yb2O3
Yb2O3
Yb2O3


Lu2O3
Ru/
Sr/
Zr/
Ta/



Lu2O3
Lu2O3
Lu2O3
Lu2O3


Ac2O3
Ru/
Sr/
Zr/
Ta/



Ac2O3
Ac2O3
Ac2O3
Ac2O3


Th2O3
Ru/
Sr/
Zr/
Ta/



Th2O3
Th2O3
Th2O3
Th2O3


ThO2
Ru/
Sr/
Zr/
Ta/



ThO2
ThO2
ThO2
ThO2


Pa2O3
Ru/
Sr/
Zr/
Ta/



Pa2O3
Pa2O3
Pa2O3
Pa2O3


PaO2
Ru/
Sr/
Zr/
Ta/



PaO2
PaO2
PaO2
PaO2


TiO2
Ru/
Sr/
Zr/
Ta/



TiO2
TiO2
TiO2
TiO2


TiO
Ru/
Sr/
Zr/
Ta/



TiO
TiO
TiO
TiO


Ti2O3
Ru/
Sr/
Zr/
Ta/



Ti2O3
Ti2O3
Ti2O3
Ti2O3


Ti3O
Ru/
Sr/
Zr/
Ta/



Ti3O
Ti3O
Ti3O
Ti3O


Ti2O
Ru/
Sr/
Zr/
Ta/



Ti2O
Ti2O
Ti2O
Ti2O


Ti3O5
Ru/
Sr/
Zr/
Ta/



Ti3O5
Ti3O5
Ti3O5
Ti3O5


Ti4O7
Ru/
Sr/
Zr/
Ta/



Ti4O7
Ti4O7
Ti4O7
Ti4O7


ZrO2
Ru/
Sr/
Zr/
Ta/



ZrO2
ZrO2
ZrO2
ZrO2


HfO2
Ru/
Sr/
Zr/
Ta/



HfO2
HfO2
HfO2
HfO2


VO
Ru/
Sr/
Zr/
Ta/



VO
VO
VO
VO


V2O3
Ru/
Sr/
Zr/
Ta/



V2O3
V2O3
V2O3
V2O3


VO2
Ru/
Sr/
Zr/
Ta/



VO2
VO2
VO2
VO2


V2O5
Ru/
Sr/
Zr/
Ta/



V2O5
V2O5
V2O5
V2O5


V3O7
Ru/
Sr/
Zr/
Ta/



V3O7
V3O7
V3O7
V3O7


V4O9
Ru/
Sr/
Zr/
Ta/



V4O9
V4O9
V4O9
V4O9


V6O13
Ru/
Sr/
Zr/
Ta/



V6O13
V6O13
V6O13
V6O13


NbO
Ru/
Sr/
Zr/
Ta/



NbO
NbO
NbO
NbO


NbO2
Ru/
Sr/
Zr/
Ta/



NbO2
NbO2
NbO2
NbO2


Nb2O5
Ru/
Sr/
Zr/
Ta/



Nb2O5
Nb2O5
Nb2O5
Nb2O5


Nb8O19
Ru/
Sr/
Zr/
Ta/



Nb8O19
Nb8O19
Nb8O19
Nb8O19


Nb16O38
Ru/
Sr/
Zr/
Ta/



Nb16O38
Nb16O38
Nb16O38
Nb16O38


Nb12O29
Ru/
Sr/
Zr/
Ta/



Nb12O29
Nb12O29
Nb12O29
Nb12O29


Nb47O116
Ru/
Sr/
Zr/
Ta/



Nb47O116
Nb47O116
Nb47O116
Nb47O116


Ta2O5
Ru/
Sr/
Zr/
Ta/



Ta2O5
Ta2O5
Ta2O5
Ta2O5


CrO
Ru/
Sr/
Zr/
Ta/



CrO
CrO
CrO
CrO


Cr2O3
Ru/
Sr/
Zr/
Ta/



Cr2O3
Cr2O3
Cr2O3
Cr2O3


CrO2
Ru/
Sr/
Zr/
Ta/



CrO2
CrO2
CrO2
CrO2


CrO3
Ru/
Sr/
Zr/
Ta/



CrO3
CrO3
CrO3
CrO3


Cr8O21
Ru/
Sr/
Zr/
Ta/



Cr8O21
Cr8O21
Cr8O21
Cr8O21


MoO2
Ru/
Sr/
Zr/
Ta/



MoO2
MoO2
MoO2
MoO2


MoO3
Ru/
Sr/
Zr/
Ta/



MoO3
MoO3
MoO3
MoO3


W2O3
Ru/
Sr/
Zr/
Ta/



W2O3
W2O3
W2O3
W2O3


WoO2
Ru/
Sr/
Zr/
Ta/



WoO2
WoO2
WoO2
WoO2


WoO3
Ru/
Sr/
Zr/
Ta/



WoO3
WoO3
WoO3
WoO3


MnO
Ru/
Sr/
Zr/
Ta/



MnO
MnO
MnO
MnO


Mn/Mg/O
Ru/
Sr/
Zr/
Ta/



Mn/Mg/O
Mn/Mg/O
Mn/Mg/O
Mn/Mg/O


Mn3O4
Ru/
Sr/
Zr/
Ta/



Mn3O4
Mn3O4
Mn3O4
Mn3O4


Mn2O3
Ru/
Sr/
Zr/
Ta/



Mn2O3
Mn2O3
Mn2O3
Mn2O3


MnO2
Ru/
Sr/
Zr/
Ta/



MnO2
MnO2
MnO2
MnO2


Mn2O7
Ru/
Sr/
Zr/
Ta/



Mn2O7
Mn2O7
Mn2O7
Mn2O7


ReO2
Ru/
Sr/
Zr/
Ta/



ReO2
ReO2
ReO2
ReO2


ReO3
Ru/
Sr/
Zr/
Ta/



ReO3
ReO3
ReO3
ReO3


Re2O7
Ru/
Sr/
Zr/
Ta/



Re2O7
Re2O7
Re2O7
Re2O7


Mg3Mn3—B2O10
Ru/
Sr/
Zr/
Ta/



Mg3Mn3—B2O10
Mg3Mn3—B2O10
Mg3Mn3—B2O10
Mg3Mn3—B2O10


Mg3(BO3)2
Ru/
Sr/
Zr/
Ta/



Mg3(BO3)2
Mg3(BO3)2
Mg3(BO3)2
Mg3(BO3)2


NaWO4
Ru/
Sr/
Zr/
Ta/



NaWO4
NaWO4
NaWO4
NaWO4


Mg6MnO8
Ru/
Sr/
Zr/
Ta/



Mg6MnO8
Mg6MnO8
Mg6MnO8
Mg6MnO8


Mn2O4
Ru/
Sr/
Zr/
Ta/



Mn2O4
Mn2O4
Mn2O4
Mn2O4


(Li,Mg)6—MnO8
Ru/
Sr/
Zr/
Ta/



(Li,Mg)6—MnO8
(Li,Mg)6—MnO8
(Li,Mg)6—MnO8
(Li,Mg)6—MnO8


Na4P2O7
Ru/
Sr/
Zr/
Ta/



Na4P2O7
Na4P2O7
Na4P2O7
Na4P2O7


Mo2O8
Ru/
Sr/
Zr/
Ta/



Mo2O8
Mo2O8
Mo2O8
Mo2O8


Mn3O4/WO4
Ru/
Sr/
Zr/
Ta/



Mn3O4/WO4
Mn3O4/WO4
Mn3O4/WO4
Mn3O4/WO4


Na2WO4
Ru/
Sr/
Zr/
Ta/



Na2WO4
Na2WO4
Na2WO4
Na2WO4


Zr2Mo2O8
Ru/
Sr/
Zr/
Ta/



Zr2Mo2O8
Zr2Mo2O8
Zr2Mo2O8
Zr2Mo2O8


NaMnO4—/
Ru/
Sr/
Zr/
Ta/


MgO
NaMnO4—/
NaMnO4—/
NaMnO4—/
NaMnO4—/



MgO
MgO
MgO
MgO


Na10Mn—W5O17
Ru/
Sr/
Zr/
Ta/



Na10Mn—W5O17
Na10Mn—W5O17
Na10Mn—W5O17
Na10Mn—W5O17












Dop











NW
Rh
Au
Mo
Ni





Li2O
Rh/
Au/
Mo/
Ni/



Li2O
Li2O
Li2O
Li2O


Na2O
Rh/
Au/
Mo/
Ni/



Na2O
Na2O
Na2O
Na2O


K2O
Rh/
Au/
Mo/
Ni/



K2O
K2O
K2O
K2O


Rb2O
Rh/
Au/
Mo/
Ni/



Rb2O
Rb2O
Rb2O
Rb2O


Cs2O
Rh/
Au/
Mo/
Ni/



Cs2O
Cs2O
Cs2O
Cs2O


BeO
Rh/
Au/
Mo/
Ni/



BeO
BeO
BeO
BeO


MgO
Rh/
Au/
Mo/
Ni/



MgO
MgO
MgO
MgO


CaO
Rh/
Au/
Mo/
Ni/



CaO
CaO
CaO
CaO


SrO
Rh/
Au/
Mo/
Ni/



SrO
SrO
SrO
SrO


BaO
Rh/
Au/
Mo/
Ni/



BaO
BaO
BaO
BaO


Sc2O3
Rh/
Au/
Mo/
Ni/



Sc2O3
Sc2O3
Sc2O3
Sc2O3


Y2O3
Rh/
Au/
Mo/
Ni/



Y2O3
Y2O3
Y2O3
Y2O3


La2O3
Rh/
Au/
Mo/
Ni/



La2O3
La2O3
La2O3
La2O3


CeO2
Rh/
Au/
Mo/
Ni/



CeO2
CeO2
CeO2
CeO2


Ce2O3
Rh/
Au/
Mo/
Ni/



Ce2O3
Ce2O3
Ce2O3
Ce2O3


Pr2O3
Rh/
Au/
Mo/
Ni/



Pr2O3
Pr2O3
Pr2O3
Pr2O3


Nd2O3
Rh/
Au/
Mo/
Ni/



Nd2O3
Nd2O3
Nd2O3
Nd2O3


Sm2O3
Rh/
Au/
Mo/
Ni/



Sm2O3
Sm2O3
Sm2O3
Sm2O3


Eu2O3
Rh/
Au/
Mo/
Ni/



Eu2O3
Eu2O3
Eu2O3
Eu2O3


Gd2O3
Rh/
Au/
Mo/
Ni/



Gd2O3
Gd2O3
Gd2O3
Gd2O3


Tb2O3
Rh/
Au/
Mo/
Ni/



Tb2O3
Tb2O3
Tb2O3
Tb2O3


TbO2
Rh/
Au/
Mo/
Ni/



TbO2
TbO2
TbO2
TbO2


Tb6O11
Rh/
Au/
Mo/
Ni/



Tb6O11
Tb6O11
Tb6O11
Tb6O11


Dy2O3
Rh/
Au/
Mo/
Ni/



Dy2O3
Dy2O3
Dy2O3
Dy2O3


Ho2O3
Rh/
Au/
Mo/
Ni/



Ho2O3
Ho2O3
Ho2O3
Ho2O3


Er2O3
Rh/
Au/
Mo/
Ni/



Er2O3
Er2O3
Er2O3
Er2O3


Tm2O3
Rh/
Au/
Mo/
Ni/



Tm2O3
Tm2O3
Tm2O3
Tm2O3


Yb2O3
Rh/
Au/
Mo/
Ni/



Yb2O3
Yb2O3
Yb2O3
Yb2O3


Lu2O3
Rh/
Au/
Mo/
Ni/



Lu2O3
Lu2O3
Lu2O3
Lu2O3


Ac2O3
Rh/
Au/
Mo/
Ni/



Ac2O3
Ac2O3
Ac2O3
Ac2O3


Th2O3
Rh/
Au/
Mo/
Ni/



Th2O3
Th2O3
Th2O3
Th2O3


ThO2
Rh/
Au/
Mo/
Ni/



ThO2
ThO2
ThO2
ThO2


Pa2O3
Rh/
Au/
Mo/
Ni/



Pa2O3
Pa2O3
Pa2O3
Pa2O3


PaO2
Rh/
Au/
Mo/
Ni/



PaO2
PaO2
PaO2
PaO2


TiO2
Rh/
Au/
Mo/
Ni/



TiO2
TiO2
TiO2
TiO2


TiO
Rh/
Au/
Mo/
Ni/



TiO
TiO
TiO
TiO


Ti2O3
Rh/
Au/
Mo/
Ni/



Ti2O3
Ti2O3
Ti2O3
Ti2O3


Ti3O
Rh/
Au/
Mo/
Ni/



Ti3O
Ti3O
Ti3O
Ti3O


Ti2O
Rh/
Au/
Mo/
Ni/



Ti2O
Ti2O
Ti2O
Ti2O


Ti3O5
Rh/
Au/
Mo/
Ni/



Ti3O5
Ti3O5
Ti3O5
Ti3O5


Ti4O7
Rh/
Au/
Mo/
Ni/



Ti4O7
Ti4O7
Ti4O7
Ti4O7


ZrO2
Rh/
Au/
Mo/
Ni/



ZrO2
ZrO2
ZrO2
ZrO2


HfO2
Rh/
Au/
Mo/
Ni/



HfO2
HfO2
HfO2
HfO2


VO
Rh/
Au/
Mo/
Ni/



VO
VO
VO
VO


V2O3
Rh/
Au/
Mo/
Ni/



V2O3
V2O3
V2O3
V2O3


VO2
Rh/
Au/
Mo/
Ni/



VO2
VO2
VO2
VO2


V2O5
Rh/
Au/
Mo/
Ni/



V2O5
V2O5
V2O5
V2O5


V3O7
Rh/
Au/
Mo/
Ni/



V3O7
V3O7
V3O7
V3O7


V4O9
Rh/
Au/
Mo/
Ni/



V4O9
V4O9
V4O9
V4O9


V6O13
Rh/
Au/
Mo/
Ni/



V6O13
V6O13
V6O13
V6O13


NbO
Rh/
Au/
Mo/
Ni/



NbO
NbO
NbO
NbO


NbO2
Rh/
Au/
Mo/
Ni/



NbO2
NbO2
NbO2
NbO2


Nb2O5
Rh/
Au/
Mo/
Ni/



Nb2O5
Nb2O5
Nb2O5
Nb2O5


Nb8O19
Rh/
Au/
Mo/
Ni/



Nb8O19
Nb8O19
Nb8O19
Nb8O19


Nb16O38
Rh/
Au/
Mo/
Ni/



Nb16O38
Nb16O38
Nb16O38
Nb16O38


Nb12O29
Rh/
Au/
Mo/
Ni/



Nb12O29
Nb12O29
Nb12O29
Nb12O29


Nb47O116
Rh/
Au/
Mo/
Ni/



Nb47O116
Nb47O116
Nb47O116
Nb47O116


Ta2O5
Rh/
Au/
Mo/
Ni/



Ta2O5
Ta2O5
Ta2O5
Ta2O5


CrO
Rh/
Au/
Mo/
Ni/



CrO
CrO
CrO
CrO


Cr2O3
Rh/
Au/
Mo/
Ni/



Cr2O3
Cr2O3
Cr2O3
Cr2O3


CrO2
Rh/
Au/
Mo/
Ni/



CrO2
CrO2
CrO2
CrO2


CrO3
Rh/
Au/
Mo/
Ni/



CrO3
CrO3
CrO3
CrO3


Cr8O21
Rh/
Au/
Mo/
Ni/



Cr8O21
Cr8O21
Cr8O21
Cr8O21


MoO2
Rh/
Au/
Mo/
Ni/



MoO2
MoO2
MoO2
MoO2


MoO3
Rh/
Au/
Mo/
Ni/



MoO3
MoO3
MoO3
MoO3


W2O3
Rh/
Au/
Mo/
Ni/



W2O3
W2O3
W2O3
W2O3


WoO2
Rh/
Au/
Mo/
Ni/



WoO2
WoO2
WoO2
WoO2


WoO3
Rh/
Au/
Mo/
Ni/



WoO3
WoO3
WoO3
WoO3


MnO
Rh/
Au/
Mo/
Ni/



MnO
MnO
MnO
MnO


Mn/Mg/O
Rh/
Au/
Mo/
Ni/



Mn/Mg/O
Mn/Mg/O
Mn/Mg/O
Mn/Mg/O


Mn3O4
Rh/
Au/
Mo/
Ni/



Mn3O4
Mn3O4
Mn3O4
Mn3O4


Mn2O3
Rh/
Au/
Mo/
Ni/



Mn2O3
Mn2O3
Mn2O3
Mn2O3


MnO2
Rh/
Au/
Mo/
Ni/



MnO2
MnO2
MnO2
MnO2


Mn2O7
Rh/
Au/
Mo/
Ni/



Mn2O7
Mn2O7
Mn2O7
Mn2O7


ReO2
Rh/
Au/
Mo/
Ni/



ReO2
ReO2
ReO2
ReO2


ReO3
Rh/
Au/
Mo/
Ni/



ReO3
ReO3
ReO3
ReO3


Re2O7
Rh/
Au/
Mo/
Ni/



Re2O7
Re2O7
Re2O7
Re2O7


Mg3Mn3—B2O10
Rh/
Au/
Mo/
Ni/



Mg3Mn3—B2O10
Mg3Mn3—B2O10
Mg3Mn3—B2O10
Mg3Mn3—B2O10


Mg3(BO3)2
Rh/
Au/
Mo/
Ni/



Mg3(BO3)2
Mg3(BO3)2
Mg3(BO3)2
Mg3(BO3)2


NaWO4
Rh/
Au/
Mo/
Ni/



NaWO4
NaWO4
NaWO4
NaWO4


Mg6MnO8
Rh/
Au/
Mo/
Ni/



Mg6MnO8
Mg6MnO8
Mg6MnO8
Mg6MnO8


Mn2O4
Rh/
Au/
Mo/
Ni/



Mn2O4
Mn2O4
Mn2O4
Mn2O4


(Li,Mg)6—MnO8
Rh/
Au/
Mo/
Ni/



(Li,Mg)6—MnO8
(Li,Mg)6—MnO8
(Li,Mg)6—MnO8
(Li,Mg)6—MnO8


Na4P2O7
Rh/
Au/
Mo/
Ni/



Na4P2O7
Na4P2O7
Na4P2O7
Na4P2O7


Mo2O8
Rh/
Au/
Mo/
Ni/



Mo2O8
Mo2O8
Mo2O8
Mo2O8


Mn3O4/WO4
Rh/
Au/
Mo/
Ni/



Mn3O4/WO4
Mn3O4/WO4
Mn3O4/WO4
Mn3O4/WO4


Na2WO4
Rh/
Au/
Mo/
Ni/



Na2WO4
Na2WO4
Na2WO4
Na2WO4


Zr2Mo2O8
Rh/
Au/
Mo/
Ni/



Zr2Mo2O8
Zr2Mo2O8
Zr2Mo2O8
Zr2Mo2O8


NaMnO4—/
Rh/
Au/
Mo/
Ni/


MgO
NaMnO4—/
NaMnO4—/
NaMnO4—/
NaMnO4—/



MgO
MgO
MgO
MgO


Na10Mn—W5O17
Rh/
Au/
Mo/
Ni/



Na10Mn—W5O17
Na10Mn—W5O17
Na10Mn—W5O17
Na10Mn—W5O17
















TABLE 7





NANOWIRES (NW) DOPED WITH SPECIFIC DOPANTS (DOP)

















Dop











NW
Co
Sb
W
V





Li2O
Co/
Sb/
W/
V/



Li2O
Li2O
Li2O
Li2O


Na2O
Co/
Sb/
W/
V/



Na2O
Na2O
Na2O
Na2O


K2O
Co/
Sb/
W/
V/



K2O
K2O
K2O
K2O


Rb2O
Co/
Sb/
W/
V/



Rb2O
Rb2O
Rb2O
Rb2O


Cs2O
Co/
Sb/
W/
V/



Cs2O
Cs2O
Cs2O
Cs2O


BeO
Co/
Sb/
W/
V/



BeO
BeO
BeO
BeO


MgO
Co/
Sb/
W/
V/



MgO
MgO
MgO
MgO


CaO
Co/
Sb/
W/
V/



CaO
CaO
CaO
CaO


SrO
Co/
Sb/
W/
V/



SrO
SrO
SrO
SrO


BaO
Co/
Sb/
W/
V/



BaO
BaO
BaO
BaO


Sc2O3
Co/
Sb/
W/
V/



Sc2O3
Sc2O3
Sc2O3
Sc2O3


Y2O3
Co/
Sb/
W/
V/



Y2O3
Y2O3
Y2O3
Y2O3


La2O3
Co/
Sb/
W/
V/



La2O3
La2O3
La2O3
La2O3


CeO2
Co/
Sb/
W/
V/



CeO2
CeO2
CeO2
CeO2


Ce2O3
Co/
Sb/
W/
V/



Ce2O3
Ce2O3
Ce2O3
Ce2O3


Pr2O3
Co/
Sb/
W/
V/



Pr2O3
Pr2O3
Pr2O3
Pr2O3


Nd2O3
Co/
Sb/
W/
V/



Nd2O3
Nd2O3
Nd2O3
Nd2O3


Sm2O3
Co/
Sb/
W/
V/



Sm2O3
Sm2O3
Sm2O3
Sm2O3


Eu2O3
Co/
Sb/
W/
V/



Eu2O3
Eu2O3
Eu2O3
Eu2O3


Gd2O3
Co/
Sb/
W/
V/



Gd2O3
Gd2O3
Gd2O3
Gd2O3


Tb2O3
Co/
Sb/
W/
V/



Tb2O3
Tb2O3
Tb2O3
Tb2O3


TbO2
Co/
Sb/
W/
V/



TbO2
TbO2
TbO2
TbO2


Tb6O11
Co/
Sb/
W/
V/



Tb6O11
Tb6O11
Tb6O11
Tb6O11


Dy2O3
Co/
Sb/
W/
V/



Dy2O3
Dy2O3
Dy2O3
Dy2O3


Ho2O3
Co/
Sb/
W/
V/



Ho2O3
Ho2O3
Ho2O3
Ho2O3


Er2O3
Co/
Sb/
W/
V/



Er2O3
Er2O3
Er2O3
Er2O3


Tm2O3
Co/
Sb/
W/
V/



Tm2O3
Tm2O3
Tm2O3
Tm2O3


Yb2O3
Co/
Sb/
W/
V/



Yb2O3
Yb2O3
Yb2O3
Yb2O3


Lu2O3
Co/
Sb/
W/
V/



Lu2O3
Lu2O3
Lu2O3
Lu2O3


Ac2O3
Co/
Sb/
W/
V/



Ac2O3
Ac2O3
Ac2O3
Ac2O3


Th2O3
Co/
Sb/
W/
V/



Th2O3
Th2O3
Th2O3
Th2O3


ThO2
Co/
Sb/
W/
V/



ThO2
ThO2
ThO2
ThO2


Pa2O3
Co/
Sb/
W/
V/



Pa2O3
Pa2O3
Pa2O3
Pa2O3


PaO2
Co/
Sb/
W/
V/



PaO2
PaO2
PaO2
PaO2


TiO2
Co/
Sb/
W/
V/



TiO2
TiO2
TiO2
TiO2


TiO
Co/
Sb/
W/
V/



TiO
TiO
TiO
TiO


Ti2O3
Co/
Sb/
W/
V/



Ti2O3
Ti2O3
Ti2O3
Ti2O3


Ti3O
Co/
Sb/
W/
V/



Ti3O
Ti3O
Ti3O
Ti3O


Ti2O
Co/
Sb/
W/
V/



Ti2O
Ti2O
Ti2O
Ti2O


Ti3O5
Co/
Sb/
W/
V/



Ti3O5
Ti3O5
Ti3O5
Ti3O5


Ti4O7
Co/
Sb/
W/
V/



Ti4O7
Ti4O7
Ti4O7
Ti4O7


ZrO2
Co/
Sb/
W/
V/



ZrO2
ZrO2
ZrO2
ZrO2


HfO2
Co/
Sb/
W/
V/



HfO2
HfO2
HfO2
HfO2


VO
Co/
Sb/
W/
V/



VO
VO
VO
VO


V2O3
Co/
Sb/
W/
V/



V2O3
V2O3
V2O3
V2O3


VO2
Co/
Sb/
W/
V/



VO2
VO2
VO2
VO2


V2O5
Co/
Sb/
W/
V/



V2O5
V2O5
V2O5
V2O5


V3O7
Co/
Sb/
W/
V/



V3O7
V3O7
V3O7
V3O7


V4O9
Co/
Sb/
W/
V/



V4O9
V4O9
V4O9
V4O9


V6O13
Co/
Sb/
W/
V/



V6O13
V6O13
V6O13
V6O13


NbO
Co/
Sb/
W/
V/



NbO
NbO
NbO
NbO


NbO2
Co/
Sb/
W/
V/



NbO2
NbO2
NbO2
NbO2


Nb2O5
Co/
Sb/
W/
V/



Nb2O5
Nb2O5
Nb2O5
Nb2O5


Nb8O19
Co/
Sb/
W/
V/



Nb8O19
Nb8O19
Nb8O19
Nb8O19


Nb16O38
Co/
Sb/
W/
V/



Nb16O38
Nb16O38
Nb16O38
Nb16O38


Nb12O29
Co/
Sb/
W/
V/



Nb12O29
Nb12O29
Nb12O29
Nb12O29


Nb47O116
Co/
Sb/
W/
V/



Nb47O116
Nb47O116
Nb47O116
Nb47O116


Ta2O5
Co/
Sb/
W/
V/



Ta2O5
Ta2O5
Ta2O5
Ta2O5


CrO
Co/
Sb/
W/
V/



CrO
CrO
CrO
CrO


Cr2O3
Co/
Sb/
W/
V/



Cr2O3
Cr2O3
Cr2O3
Cr2O3


CrO2
Co/
Sb/
W/
V/



CrO2
CrO2
CrO2
CrO2


CrO3
Co/
Sb/
W/
V/



CrO3
CrO3
CrO3
CrO3


Cr8O21
Co/
Sb/
W/
V/



Cr8O21
Cr8O21
Cr8O21
Cr8O21


MoO2
Co/
Sb/
W/
V/



MoO2
MoO2
MoO2
MoO2


MoO3
Co/
Sb/
W/
V/



MoO3
MoO3
MoO3
MoO3


W2O3
Co/
Sb/
W/
V/



W2O3
W2O3
W2O3
W2O3


WoO2
Co/
Sb/
W/
V/



WoO2
WoO2
WoO2
WoO2


WoO3
Co/
Sb/
W/
V/



WoO3
WoO3
WoO3
WoO3


MnO
Co/
Sb/
W/
V/



MnO
MnO
MnO
MnO


Mn/Mg/O
Co/
Sb/
W/
V/



Mn/Mg/O
Mn/Mg/O
Mn/Mg/O
Mn/Mg/O


Mn3O4
Co/
Sb/
W/
V/



Mn3O4
Mn3O4
Mn3O4
Mn3O4


Mn2O3
Co/
Sb/
W/
V/



Mn2O3
Mn2O3
Mn2O3
Mn2O3


MnO2
Co/
Sb/
W/
V/



MnO2
MnO2
MnO2
MnO2


Mn2O7
Co/
Sb/
W/
V/



Mn2O7
Mn2O7
Mn2O7
Mn2O7


ReO2
Co/
Sb/
W/
V/



ReO2
ReO2
ReO2
ReO2


ReO3
Co/
Sb/
W/
V/



ReO3
ReO3
ReO3
ReO3


Re2O7
Co/
Sb/
W/
V/



Re2O7
Re2O7
Re2O7
Re2O7


Mg3Mn3—B2O10
Co/
Sb/
W/
V/



Mg3Mn3—B2O10
Mg3Mn3—B2O10
Mg3Mn3—B2O10
Mg3Mn3—B2O10


Mg3(BO3)2
Co/
Sb/
W/
V/



Mg3(BO3)2
Mg3(BO3)2
Mg3(BO3)2
Mg3(BO3)2


NaWO4
Co/
Sb/
W/
V/



NaWO4
NaWO4
NaWO4
NaWO4


Mg6MnO8
Co/
Sb/
W/
V/



Mg6MnO8
Mg6MnO8
Mg6MnO8
Mg6MnO8


Mn2O4
Co/
Sb/
W/
V/



Mn2O4
Mn2O4
Mn2O4
Mn2O4


(Li,Mg)6—MnO8
Co/
Sb/
W/
V/



(Li,Mg)6—MnO8
(Li,Mg)6—MnO8
(Li,Mg)6—MnO8
(Li,Mg)6—MnO8


Na4P2O7
Co/
Sb/
W/
V/



Na4P2O7
Na4P2O7
Na4P2O7
Na4P2O7


Mo2O8
Co/
Sb/
W/
V/



Mo2O8
Mo2O8
Mo2O8
Mo2O8


Mn3O4/WO4
Co/
Sb/
W/
V/



Mn3O4/WO4
Mn3O4/WO4
Mn3O4/WO4
Mn3O4/WO4


Na2WO4
Co/
Sb/
W/
V/



Na2WO4
Na2WO4
Na2WO4
Na2WO4


Zr2Mo2O8
Co/
Sb/
W/
V/



Zr2Mo2O8
Zr2Mo2O8
Zr2Mo2O8
Zr2Mo2O8


NaMnO4—/
Co/
Sb/
W/
V/


MgO
NaMnO4—/
NaMnO4—/
NaMnO4—/
NaMnO4—/



MgO
MgO
MgO
MgO


Na10Mn—W5O17
Co/
Sb/
W/
V/



Na10Mn—W5O17
Na10Mn—W5O17
Na10Mn—W5O17
Na10Mn—W5O17












Dop











NW
Ag
Te
Pd
Ir





Li2O
Ag/
Te/
Pd/
Ir/



Li2O
Li2O
Li2O
Li2O


Na2O
Ag/
Te/
Pd/
Ir/



Na2O
Na2O
Na2O
Na2O


K2O
Ag/
Te/
Pd/
Ir/



K2O
K2O
K2O
K2O


Rb2O
Ag/
Te/
Pd/
Ir/



Rb2O
Rb2O
Rb2O
Rb2O


Cs2O
Ag/
Te/
Pd/
Ir/



Cs2O
Cs2O
Cs2O
Cs2O


BeO
Ag/
Te/
Pd/
Ir/



BeO
BeO
BeO
BeO


MgO
Ag/
Te/
Pd/
Ir/



MgO
MgO
MgO
MgO


CaO
Ag/
Te/
Pd/
Ir/



CaO
CaO
CaO
CaO


SrO
Ag/
Te/
Pd/
Ir/



SrO
SrO
SrO
SrO


BaO
Ag/
Te/
Pd/
Ir/



BaO
BaO
BaO
BaO


Sc2O3
Ag/
Te/
Pd/
Ir/



Sc2O3
Sc2O3
Sc2O3
Sc2O3


Y2O3
Ag/
Te/
Pd/
Ir/



Y2O3
Y2O3
Y2O3
Y2O3


La2O3
Ag/
Te/
Pd/
Ir/



La2O3
La2O3
La2O3
La2O3


CeO2
Ag/
Te/
Pd/
Ir/



CeO2
CeO2
CeO2
CeO2


Ce2O3
Ag/
Te/
Pd/
Ir/



Ce2O3
Ce2O3
Ce2O3
Ce2O3


Pr2O3
Ag/
Te/
Pd/
Ir/



Pr2O3
Pr2O3
Pr2O3
Pr2O3


Nd2O3
Ag/
Te/
Pd/
Ir/



Nd2O3
Nd2O3
Nd2O3
Nd2O3


Sm2O3
Ag/
Te/
Pd/
Ir/



Sm2O3
Sm2O3
Sm2O3
Sm2O3


Eu2O3
Ag/
Te/
Pd/
Ir/



Eu2O3
Eu2O3
Eu2O3
Eu2O3


Gd2O3
Ag/
Te/
Pd/
Ir/



Gd2O3
Gd2O3
Gd2O3
Gd2O3


Tb2O3
Ag/
Te/
Pd/
Ir/



Tb2O3
Tb2O3
Tb2O3
Tb2O3


TbO2
Ag/
Te/
Pd/
Ir/



TbO2
TbO2
TbO2
TbO2


Tb6O11
Ag/
Te/
Pd/
Ir/



Tb6O11
Tb6O11
Tb6O11
Tb6O11


Dy2O3
Ag/
Te/
Pd/
Ir/



Dy2O3
Dy2O3
Dy2O3
Dy2O3


Ho2O3
Ag/
Te/
Pd/
Ir/



Ho2O3
Ho2O3
Ho2O3
Ho2O3


Er2O3
Ag/
Te/
Pd/
Ir/



Er2O3
Er2O3
Er2O3
Er2O3


Tm2O3
Ag/
Te/
Pd/
Ir/



Tm2O3
Tm2O3
Tm2O3
Tm2O3


Yb2O3
Ag/
Te/
Pd/
Ir/



Yb2O3
Yb2O3
Yb2O3
Yb2O3


Lu2O3
Ag/
Te/
Pd/
Ir/



Lu2O3
Lu2O3
Lu2O3
Lu2O3


Ac2O3
Ag/
Te/
Pd/
Ir/



Ac2O3
Ac2O3
Ac2O3
Ac2O3


Th2O3
Ag/
Te/
Pd/
Ir/



Th2O3
Th2O3
Th2O3
Th2O3


ThO2
Ag/
Te/
Pd/
Ir/



ThO2
ThO2
ThO2
ThO2


Pa2O3
Ag/
Te/
Pd/
Ir/



Pa2O3
Pa2O3
Pa2O3
Pa2O3


PaO2
Ag/
Te/
Pd/
Ir/



PaO2
PaO2
PaO2
PaO2


TiO2
Ag/
Te/
Pd/
Ir/



TiO2
TiO2
TiO2
TiO2


TiO
Ag/
Te/
Pd/
Ir/



TiO
TiO
TiO
TiO


Ti2O3
Ag/
Te/
Pd/
Ir/



Ti2O3
Ti2O3
Ti2O3
Ti2O3


Ti3O
Ag/
Te/
Pd/
Ir/



Ti3O
Ti3O
Ti3O
Ti3O


Ti2O
Ag/
Te/
Pd/
Ir/



Ti2O
Ti2O
Ti2O
Ti2O


Ti3O5
Ag/
Te/
Pd/
Ir/



Ti3O5
Ti3O5
Ti3O5
Ti3O5


Ti4O7
Ag/
Te/
Pd/
Ir/



Ti4O7
Ti4O7
Ti4O7
Ti4O7


ZrO2
Ag/
Te/
Pd/
Ir/



ZrO2
ZrO2
ZrO2
ZrO2


HfO2
Ag/
Te/
Pd/
Ir/



HfO2
HfO2
HfO2
HfO2


VO
Ag/
Te/
Pd/
Ir/



VO
VO
VO
VO


V2O3
Ag/
Te/
Pd/
Ir/



V2O3
V2O3
V2O3
V2O3


VO2
Ag/
Te/
Pd/
Ir/



VO2
VO2
VO2
VO2


V2O5
Ag/
Te/
Pd/
Ir/



V2O5
V2O5
V2O5
V2O5


V3O7
Ag/
Te/
Pd/
Ir/



V3O7
V3O7
V3O7
V3O7


V4O9
Ag/
Te/
Pd/
Ir/



V4O9
V4O9
V4O9
V4O9


V6O13
Ag/
Te/
Pd/
Ir/



V6O13
V6O13
V6O13
V6O13


NbO
Ag/
Te/
Pd/
Ir/



NbO
NbO
NbO
NbO


NbO2
Ag/
Te/
Pd/
Ir/



NbO2
NbO2
NbO2
NbO2


Nb2O5
Ag/
Te/
Pd/
Ir/



Nb2O5
Nb2O5
Nb2O5
Nb2O5


Nb8O19
Ag/
Te/
Pd/
Ir/



Nb8O19
Nb8O19
Nb8O19
Nb8O19


Nb16O38
Ag/
Te/
Pd/
Ir/



Nb16O38
Nb16O38
Nb16O38
Nb16O38


Nb12O29
Ag/
Te/
Pd/
Ir/



Nb12O29
Nb12O29
Nb12O29
Nb12O29


Nb47O116
Ag/
Te/
Pd/
Ir/



Nb47O116
Nb47O116
Nb47O116
Nb47O116


Ta2O5
Ag/
Te/
Pd/
Ir/



Ta2O5
Ta2O5
Ta2O5
Ta2O5


CrO
Ag/
Te/
Pd/
Ir/



CrO
CrO
CrO
CrO


Cr2O3
Ag/
Te/
Pd/
Ir/



Cr2O3
Cr2O3
Cr2O3
Cr2O3


CrO2
Ag/
Te/
Pd/
Ir/



CrO2
CrO2
CrO2
CrO2


CrO3
Ag/
Te/
Pd/
Ir/



CrO3
CrO3
CrO3
CrO3


Cr8O21
Ag/
Te/
Pd/
Ir/



Cr8O21
Cr8O21
Cr8O21
Cr8O21


MoO2
Ag/
Te/
Pd/
Ir/



MoO2
MoO2
MoO2
MoO2


MoO3
Ag/
Te/
Pd/
Ir/



MoO3
MoO3
MoO3
MoO3


W2O3
Ag/
Te/
Pd/
Ir/



W2O3
W2O3
W2O3
W2O3


WoO2
Ag/
Te/
Pd/
Ir/



WoO2
WoO2
WoO2
WoO2


WoO3
Ag/
Te/
Pd/
Ir/



WoO3
WoO3
WoO3
WoO3


MnO
Ag/
Te/
Pd/
Ir/



MnO
MnO
MnO
MnO


Mn/Mg/O
Ag/
Te/
Pd/
Ir/



Mn/Mg/O
Mn/Mg/O
Mn/Mg/O
Mn/Mg/O


Mn3O4
Ag/
Te/
Pd/
Ir/



Mn3O4
Mn3O4
Mn3O4
Mn3O4


Mn2O3
Ag/
Te/
Pd/
Ir/



Mn2O3
Mn2O3
Mn2O3
Mn2O3


MnO2
Ag/
Te/
Pd/
Ir/



MnO2
MnO2
MnO2
MnO2


Mn2O7
Ag/
Te/
Pd/
Ir/



Mn2O7
Mn2O7
Mn2O7
Mn2O7


ReO2
Ag/
Te/
Pd/
Ir/



ReO2
ReO2
ReO2
ReO2


ReO3
Ag/
Te/
Pd/
Ir/



ReO3
ReO3
ReO3
ReO3


Re2O7
Ag/
Te/
Pd/
Ir/



Re2O7
Re2O7
Re2O7
Re2O7


Mg3Mn3—B2O10
Ag/
Te/
Pd/
Ir/



Mg3Mn3—B2O10
Mg3Mn3—B2O10
Mg3Mn3—B2O10
Mg3Mn3—B2O10


Mg3(BO3)2
Ag/
Te/
Pd/
Ir/



Mg3(BO3)2
Mg3(BO3)2
Mg3(BO3)2
Mg3(BO3)2


NaWO4
Ag/
Te/
Pd/
Ir/



NaWO4
NaWO4
NaWO4
NaWO4


Mg6MnO8
Ag/
Te/
Pd/
Ir/



Mg6MnO8
Mg6MnO8
Mg6MnO8
Mg6MnO8


Mn2O4
Ag/
Te/
Pd/
Ir/



Mn2O4
Mn2O4
Mn2O4
Mn2O4


(Li,Mg)6—MnO8
Ag/
Te/
Pd/
Ir/



(Li,Mg)6—MnO8
(Li,Mg)6—MnO8
(Li,Mg)6—MnO8
(Li,Mg)6—MnO8


Na4P2O7
Ag/
Te/
Pd/
Ir/



Na4P2O7
Na4P2O7
Na4P2O7
Na4P2O7


Mo2O8
Ag/
Te/
Pd/
Ir/



Mo2O8
Mo2O8
Mo2O8
Mo2O8


Mn3O4/WO4
Ag/
Te/
Pd/
Ir/



Mn3O4/WO4
Mn3O4/WO4
Mn3O4/WO4
Mn3O4/WO4


Na2WO4
Ag/
Te/
Pd/
Ir/



Na2WO4
Na2WO4
Na2WO4
Na2WO4


Zr2Mo2O8
Ag/
Te/
Pd/
Ir/



Zr2Mo2O8
Zr2Mo2O8
Zr2Mo2O8
Zr2Mo2O8


NaMnO4—/
Ag/
Te/
Pd/
Ir/


MgO
NaMnO4—/
NaMnO4—/
NaMnO4—/
NaMnO4—/



MgO
MgO
MgO
MgO


Na10Mn—W5O17
Ag/
Te/
Pd/
Ir/



Na10Mn—W5O17
Na10Mn—W5O17
Na10Mn—W5O17
Na10Mn—W5O17
















TABLE 8







NANOWIRES (NW) DOPED WITH SPECIFIC DOPANTS (DOP)










Dop












NW
Mn
Ti







Li2O
Mn/
Ti/




Li2O
Li2O



Na2O
Mn/
Ti/




Na2O
Na2O



K2O
Mn/
Ti/




K2O
K2O



Rb2O
Mn/
Ti/




Rb2O
Rb2O



Cs2O
Mn/
Ti/




Cs2O
Cs2O



BeO
Mn/
Ti/




BeO
BeO



MgO
Mn/
Ti/




MgO
MgO



CaO
Mn/
Ti/




CaO
CaO



SrO
Mn/
Ti/




SrO
SrO



BaO
Mn/
Ti/




BaO
BaO



Sc2O3
Mn/
Ti/




Sc2O3
Sc2O3



Y2O3
Mn/
Ti/




Y2O3
Y2O3



La2O3
Mn/
Ti/




La2O3
La2O3



CeO2
Mn/
Ti/




CeO2
CeO2



Ce2O3
Mn/
Ti/




Ce2O3
Ce2O3



Pr2O3
Mn/
Ti/




Pr2O3
Pr2O3



Nd2O3
Mn/
Ti/




Nd2O3
Nd2O3



Sm2O3
Mn/
Ti/




Sm2O3
Sm2O3



Eu2O3
Mn/
Ti/




Eu2O3
Eu2O3



Gd2O3
Mn/
Ti/




Gd2O3
Gd2O3



Tb2O3
Mn/
Ti/




Tb2O3
Tb2O3



TbO2
Mn/
Ti/




TbO2
TbO2



Tb6O11
Mn/
Ti/




Tb6O11
Tb6O11



Dy2O3
Mn/
Ti/




Dy2O3
Dy2O3



Ho2O3
Mn/
Ti/




Ho2O3
Ho2O3



Er2O3
Mn/
Ti/




Er2O3
Er2O3



Tm2O3
Mn/
Ti/




Tm2O3
Tm2O3



Yb2O3
Mn/
Ti/




Yb2O3
Yb2O3



Lu2O3
Mn/
Ti/




Lu2O3
Lu2O3



Ac2O3
Mn/
Ti/




Ac2O3
Ac2O3



Th2O3
Mn/
Ti/




Th2O3
Th2O3



ThO2
Mn/
Ti/




ThO2
ThO2



Pa2O3
Mn/
Ti/




Pa2O3
Pa2O3



PaO2
Mn/
Ti/




PaO2
PaO2



TiO2
Mn/
Ti/




TiO2
TiO2



TiO
Mn/
Ti/




TiO
TiO



Ti2O3
Mn/
Ti/




Ti2O3
Ti2O3



Ti3O
Mn/
Ti/




Ti3O
Ti3O



Ti2O
Mn/
Ti/




Ti2O
Ti2O



Ti3O5
Mn/
Ti/




Ti3O5
Ti3O5



Ti4O7
Mn/
Ti/




Ti4O7
Ti4O7



ZrO2
Mn/
Ti/




ZrO2
ZrO2



HfO2
Mn/
Ti/




HfO2
HfO2



VO
Mn/
Ti/




VO
VO



V2O3
Mn/
Ti/




V2O3
V2O3



VO2
Mn/
Ti/




VO2
VO2



V2O5
Mn/
Ti/




V2O5
V2O5



V3O7
Mn/
Ti/




V3O7
V3O7



V4O9
Mn/
Ti/




V4O9
V4O9



V6O13
Mn/
Ti/




V6O13
V6O13



NbO
Mn/
Ti/




NbO
NbO



NbO2
Mn/
Ti/




NbO2
NbO2



Nb2O5
Mn/
Ti/




Nb2O5
Nb2O5



Nb8O19
Mn/
Ti/




Nb8O19
Nb8O19



Nb16O38
Mn/
Ti/




Nb16O38
Nb16O38



Nb12O29
Mn/
Ti/




Nb12O29
Nb12O29



Nb47O116
Mn/
Ti/




Nb47O116
Nb47O116



Ta2O5
Mn/
Ti/




Ta2O5
Ta2O5



CrO
Mn/
Ti/




CrO
CrO



Cr2O3
Mn/
Ti/




Cr2O3
Cr2O3



CrO2
Mn/
Ti/




CrO2
CrO2



CrO3
Mn/
Ti/




CrO3
CrO3



Cr8O21
Mn/
Ti/




Cr8O21
Cr8O21



MoO2
Mn/
Ti/




MoO2
MoO2



MoO3
Mn/
Ti/




MoO3
MoO3



W2O3
Mn/
Ti/




W2O3
W2O3



WoO2
Mn/
Ti/




WoO2
WoO2



WoO3
Mn/
Ti/




WoO3
WoO3



MnO
Mn/
Ti/




MnO
MnO



Mn/Mg/O
Mn/
Ti/




Mn/Mg/O
Mn/Mg/O



Mn3O4
Mn/
Ti/




Mn3O4
Mn3O4



Mn2O3
Mn/
Ti/




Mn2O3
Mn2O3



MnO2
Mn/
Ti/




MnO2
MnO2



Mn2O7
Mn/
Ti/




Mn2O7
Mn2O7



ReO2
Mn/
Ti/




ReO2
ReO2



ReO3
Mn/
Ti/




ReO3
ReO3



Re2O7
Mn/
Ti/




Re2O7
Re2O7



Mg3Mn3—B2O10
Mn/
Ti/




Mg3Mn3—B2O10
Mg3Mn3—B2O10



Mg3(BO3)2
Mn/
Ti/




Mg3(BO3)2
Mg3(BO3)2



NaWO4
Mn/
Ti/




NaWO4
NaWO4



Mg6MnO8
Mn/
Ti/




Mg6MnO8
Mg6MnO8



Mn2O4
Mn/
Ti/




Mn2O4
Mn2O4



(Li,Mg)6—MnO8
Mn/
Mn/




(Li,Mg)6—MnO8
(Li,Mg)6—MnO8



Na4P2O7
Mn/
Ti/




Na4P2O7
Na4P2O7



Mo2O8
Mn/
Ti/




Mo2O8
Mo2O8



Mn3O4/WO4
Mn/
Ti/




Mn3O4/WO4
Mn3O4/WO4



Na2WO4
Mn/
Ti/




Na2WO4
Na2WO4



Zr2Mo2O8
Mn/
Ti/




Zr2Mo2O8
Zr2Mo2O8



NaMnO4—/
Mn/
Ti/



MgO
NaMnO4—/
NaMnO4—/




MgO
MgO



Na10Mn—W5O17
Mn/
Ti/




Na10Mn—W5O17
Na10Mn—W5O17










As used in Table 1-8 and throughout the specification, a nanowire composition represented by E1/E2E3 etc., wherein E1, E2 and E3 are each independently an element or a compound comprising one or more elements, refers to a nanowire composition comprised of a mixture of E1, E2 and E3. E1/E2E3 etc. are not necessarily present in equal amounts and need not form a bond with one another. For example, a nanowire comprising Li/MgO refers to a nanowire comprising Li and MgO, for example, Li/MgO may refer to a MgO nanowire doped with Li. By way of another example, a nanowire comprising NaMnO4/MgO refers to a nanowire comprised of a mixture of NaMnO4 and MgO. Dopants may be added in suitable form. For example in a lithium doped magnesium oxide nanowire (Li/MgO), the Li dopant can be incorporated in the form of Li2O, Li2CO3, LiOH, or other suitable forms. Li may be fully incorporated in the MgO crystal lattice (e.g., (Li,Mg)O) as well. Dopants for other nanowires may be incorporated analogously.
In some more specific embodiments, the dopant is selected from Li, Ba and Sr. In other specific embodiments, the nanowires comprise Li/MgO, Ba/MgO, Sr/La2O3, Ba/La2O3, Mn/Na2WO4, Mn2O3/Na2WO4, Mn3O4/Na2WO4, Mg6MnO8, Li/B/Mg6MnO8, Na/B/Mg6MnO8, Zr2Mo2O8 or NaMnO4/MgO.
In some other specific embodiments, the nanowire comprises a mixed oxide of Mn and Mg with or without B and with or without Li. Additional dopants for such nanowires may comprise doping elements selected from Group 1 and 2 and groups 7-13. The dopants may be present as single dopants or in combination with other dopants. In certain specific embodiments of nanowires comprising a mixed oxide of Mn and Mg with or without B and with or without Li., the dopant comprises a combination of elements from group 1 and group 8-11.
Nanowires comprising mixed oxides of Mn and Mg are well suited for incorporation of dopants because magnesium atoms can be easily substituted by other atoms as long as their size is comparable with magnesium. A family of “doped” Mg6MnO8 compounds with the composition M(x)Mg(6-x)MnO8, wherein each M is independently a dopant as defined herein and x is 0 to 6, can thus be created. The oxidation state of Mn can be tuned by selecting different amounts (i.e., different values of x) of M with different oxidation states, for example Li(x)Mg(6-x)MnO8 would contain a mixture of Mn(IV) and Mn(V) with x<1 and a mixture that may include Mn(V), Mn(VI), Mn(VII) with x>1. The maximum value of x depends on the ability of a particular atom M to be incorporated in the Mg6MnO8 crystal structure and therefore varies depending on M. It is believed that the ability to tune the manganese oxidation state as described above could have advantageous effect on the catalytic activity of the disclosed nanowires.
Examples of nanowires comprising Li/Mn/Mg/B and an additional dopant include; Li/Mn/Mg/B doped with Co; Li/Mn/Mg/B doped with Na, Li/Mn/Mg/B doped with Be; Li/Mn/Mg/B doped with Al; Li/Mn/Mg/B doped with Hf; Li/Mn/Mg/B doped with Zr; Li/Mn/Mg/B doped with Zn; Li/Mn/Mg/B doped with Rh and Li/Mn/Mg/B doped with Ga. Nanowires comprising Li/Mn/Mg/B doped with different combinations of these dopants are also provided. For example, in some embodiments the Li/Mn/Mg/B nanowires are doped with Na and Co. In other embodiments, the Li/Mn/Mg/B nanowires are doped with Ga and Na.
In other embodiments, nanowires comprising Mn/W with or without dopants are provided. For example, the present inventors have found through high throughput testing that nanowires comprising Mn/W and various dopants are good catalysts in the OCM reaction. Accordingly, in some embodiments, the Mn/W nanowires are doped with Ba. In other embodiments, the Mn/W nanowires are doped with Be. In yet other embodiments, the Mn/W nanowires are doped with Te.
In any of the above embodiments, the Mn/W nanowires may comprise a SiO2 support. Alternatively, the use of different supports such as ZrO2, HfO2 and In2O3 in any of the above embodiments has been shown to promote OCM activity at reduced temperature compared to the same catalyst supported on silica with limited reduction in selectivity.
Nanowires comprising rare earth oxides or Yttria doped with various elements are also effective catalysts in the OCM reaction. In certain specific embodiments, the rare earth oxide or oxy-hydroxide can be any rare earth, preferably La, Nd, Eu, Sm, Yb, Gd. In certain embodiments of the nanowires comprising rare earth elements or yttria, the dopant comprises alkali earth (group 2) elements. The degree of effectiveness of a particular dopant is a function of the rare earth used and the concentration of the alkali earth dopant. In addition to Alkali earth elements, further embodiments of the rare earth or yttria nanowires include embodiments wherein the nanowires comprise alkali elements as dopants which further promote the selectivity of the OCM catalytic activity of the doped material. In yet other embodiments of the foregoing, the nanowires comprise both an alkali element and alkali earth element as dopant. In still further embodiments, an additional dopant can be selected from an additional rare earth and groups 3, 4, 8, 9, 10, 13, 14.
The foregoing rare earth or yttria catalyst may be doped prior to, or after formation of the rare earth or yttria oxide. In one, the rare earth or yttria salt is mixed with the precursor salt to form a solution or a slurry which is dried and then calcined in a range of 400° C. to 900° C., or between 500° C. and 700° C. In another embodiment, the rare earth or yttria oxide is formed first through calcination of a rare earth or yttria salt and then contacted with a solution comprising the doping element prior to drying and calcination between 300° C. and 800° C., or between 400° C. and 700° C.
In other embodiments, the nanowires comprise La2O3 or LaOy(OH)x, wherein y ranges from 0 to 1.5, x ranges from 0 to 3 and 2y+x=3, doped with Na, Mg, Ca, Sr, Ga, Sc, Y, Zr, In, Nd, Eu, Sm, Ce, Gd or combinations thereof. In yet further embodiments, the La2O3 or LaOy(OH)x nanowires are doped with binary dopant combinations, for example Eu/Na; Eu/Gd; Ca/Na; Eu/Sm; Eu/Sr; Mg/Sr; Ce/Mg; Gd/Sm, Mg/Na, Mg/Y, Ga/Sr, Nd/Mg, Gd/Na or Sm/Na. In some other embodiments, the La2O3 or LaOy(OH)x nanowires are doped with a binary dopant combination, for example Ca—Mg—Na.
In other embodiments, the nanowires comprise Nd2O3 or NdOy(OH)x, wherein y ranges from 0 to 1.5, x ranges from 0 to 3 and 2y+x=3, doped with Sr, Ca, Rb, Li, Na or combinations thereof. In certain other embodiments, the Nd2O3 or NdOy(OH)x nanowires are doped with binary dopant combinations, for example Ca/Sr or Rb/Sr, Ta/Sr or Al/Sr.
In still other examples of doped nanowires, the nanowires comprise Yb2O3 or YbOy(OH)x, wherein y ranges from 0 to 1.5, x ranges from 0 to 3 and 2y+x=3, doped with Sr, Ca, Ba, Nd or combinations thereof. In certain other embodiments, the Yb2O3 or YbOy(OH)x OCM nanowires are doped with a binary combination, for example of Sr/Nd.
Still other examples of doped nanowires Eu2O3 or EuOy(OH)x nanowires, wherein y ranges from 0 to 1.5, x ranges from 0 to 3 and 2y+x=3, doped with Sr, Ba, Sm, Gd, Na or combinations thereof or a binary dopant combination, for example Sr/Na or Sm/Na.
Example of dopants for Sm2O3 or SmOy(OH)x nanowires, wherein x and y are each independently an integer from 1 to 10, include Sr, and examples of dopants for Y2O3 or YOy(OH)x nanowires, wherein y ranges from 0 to 1.5, x ranges from 0 to 3 and 2y+x=3, comprise Ga, La, Nd or combinations thereof. In certain other embodiments, the Y2O3 or YOy(OH)x nanowires comprise a binary dopant combination, for example Sr/Nd, Eu/Y or Mg/Nd or a tertiary dopant combination, for example Mg/Nd/Fe.
Rare earth nanowires which without doping have low OCM selectivity can be greatly improved by doping to reduce their combustion activity. In particular, nanowires comprising CeO2 and Pr2O3 tend to have strong total oxidation activity for methane, however doping with additional rare earth elements can significantly moderate the combustion activity and improve the overall utility of the catalyst. Example of dopants which improving the selectivity for Pr2O3 or PrOy(OH)x nanowires, wherein y ranges from 0 to 1.5, x ranges from 0 to 3 and 2y+x=3, comprise binary dopants, for example Nd/Mg, La/Mg or Yb/Sr.
In some embodiments, dopants are present in the nanowires in, for example, less than 50 at %, less than 25 at %, less than 10 at %, less than 5 at % or less than 1 at %.
In other embodiments of the nanowires, the atomic ratio (w/w) of the one or more metal elements selected from Groups I-7 and lanthanides and actinides in the form of an oxide and the dopant ranges from 1:1 to 10,000:1, 1:1 to 1,000:1 or 1:1 to 500:1.
In further embodiments, the nanowires comprise one or more metal elements from Group2 in the form of an oxide and a dopant from Group I. In further embodiments, the nanowires comprise magnesium and lithium. In other embodiments, the nanowires comprise one or more metal elements from Group2 and a dopant from Group 2, for example, in some embodiments, the nanowires comprise magnesium oxide and barium. In another embodiment, the nanowires comprise an element from the lanthanides in the form of an oxide and a dopant from Group 1 or Group 2. In further embodiments, the nanowires comprise lanthanum and strontium.
Various methods for preparing doped nanowires are provided. In one embodiment, the doped nanowires can be prepared by co-precipitating a nanowire metal oxide precursor and a dopant precursor. In these embodiments, the doping element may be directly incorporated into the nanowire.
Template Directed Synthesis of Nanowires
In some embodiments, the nanowires can be prepared in a solution phase using an appropriate template. In this context, an appropriate template can be any synthetic or natural material, or combination thereof, that provides nucleation sites for binding ions (e.g. metal element ions and/or hydroxide or other anions) and causing the growth of a nanowire. The templates can be selected such that certain control of the nucleation sites, in terms of their composition, quantity and location can be achieved in a statistically significant manner. The templates are typically linear or anisotropic in shape, thus directing the growth of a nanowire.
In contrast to other template directed preparation of nanowires, the present nanowires are generally not prepared from nanoparticles deposited on a template in a reduced state which are then heat treated and fused into a nanowire. Such methods are not generally applicable to nanowires comprising one or more elements from any of Groups 1 through 7, lanthanides, actinides or combinations thereof. Instead, the nanowires are prepared by nucleation of an oxidized metal element (e.g., in the form of a metal salt) and subsequent growth of nanowire. The nanowires are then generally calcined to produce the desired oxide, but annealing of nanoparticles is not necessary to form the nanowires.
1. Biological Template
Because peptide sequences have been shown to have specific and selective binding affinity for many different types of metal element ions, biological templates incorporating peptide sequences as nucleation sites are preferred. Moreover, biological templates can be engineered to comprise pre-determined nucleation sites in pre-determined spatial relationships (e.g., separated by a few to tens of nanometers).
Both wild type and genetically engineered biological templates can be used. As discussed herein, biological templates such as proteins and bacteriophage can be engineered based on genetics to ensure control over the type of nucleation sites (e.g., by controlling the peptide sequences), their locations on the templates and their respective density and/or ratio to other nucleation sites. See, e.g., Mao, C. B. et al., (2004) Science, 303, 213-217; Belcher, A. et al., (2002) Science 296, 892-895; Belcher, A. et al., (2000) Nature 405 (6787) 665-668; Reiss et al., (2004) Nanoletters, 4 (6), 1127-1132, Flynn, C. et al., (2003) J. Mater. Sci., 13, 2414-2421; Mao, C. B. et al., (2003) PNAS, 100 (12), 6946-6951, which references are hereby incorporated by reference in their entireties. This allows for the ability to control the composition and distribution of the nucleation sites on the biological template.
Thus, biological templates may be particularly advantageous for a controlled growth of nanowires. Biological templates can be biomolecules (e.g., proteins) as well as multi-molecular structures of a biological origin, including, for example, bacteriophage, virus, amyloid fiber, and capsid.
(a) Biomolecules
In certain embodiments, the biological templates are biomolecules. In more specific embodiments, the biological templates are anisotropic biomolecules. Typically, a biomolecule comprises a plurality of subunits (building blocks) joined together in a sequence via chemical bonds. Each subunit comprises at least two reactive groups such as hydroxyl, carboxylic acid and amino groups, which enable the bond formations that interconnect the subunits. Examples of the subunits include, but are not limited to: amino acids (both natural and synthetic) and nucleotides. Accordingly, in some embodiments, the biomolecule template is a peptide, protein, nucleic acid, polynucleotide, amino acid, antibody, enzyme, or single-stranded or double-stranded nucleic acid or any modified and/or degraded forms thereof.
Because protein synthesis can be genetically directed, proteins can be readily manipulated and functionalized to contain desired peptide sequences (i.e., nucleation sites) at desired locations within the primary structure of the protein. The protein can then be assembled to provide a template.
Thus, in various embodiments, the templates are biomolecules are native proteins or proteins that can be engineered to have nucleation sites for specific ions.
(b) Baceteriophage
In one particular embodiment, the biological template comprises a M13 bacteriophage which has or can be engineered to have one or more particular peptide sequences bound onto the coat proteins. FIG. 6 schematically shows a filamentous bacteriophage 400, in which a single-stranded DNA core 410 is surrounded by a proteinaceous coat 420. The coat is composed mainly of pVIII proteins 424 that cover the length of the bacteriophage. The ends of the bacteriophage are capped by minor coat proteins 430 (pIII), 440 (pVI), 450 (pVII) and 460 (pIX).
Using genetic engineering, a library of diverse, novel peptide sequences (up to 1012 unique peptides) can be expressed on the surface of the phage, so that each individual phage displays at least one unique peptide sequence. These externally facing peptide sequences can be tested, through the iterative steps of screening, amplification and optimization, for the ability to control nucleation and growth of specific catalytic nanowires.
For example, in a further embodiment peptide sequences having one or more particular nucleation sites specific for various ions are bound onto the coat proteins. For example, in one embodiment, the coat protein is pVIII with peptide sequences having one or more particular nucleation sites specific for various ions bound thereto. In other further embodiments, the peptide sequences bound to the coat protein comprise 2 or more amino acids, 5 or more amino acids, 10 or more amino acids, 20 or more amino acids, or 40 or more amino acids. In other embodiments, the peptide sequences bound to the coat protein comprise between 2 and 40 amino acids, between 5 and 20 amino acids, or between 7 and 12 amino acids.
One of the approaches to obtain different types of M13 bacteriophage is to modify the viral genetic code in order to change the amino acid sequence of the phage coating protein pVIII. The changes in sequence only affect the last amino acids of the pVIII protein, which are the ones that make the surface of the M13 phage, while the first 45 amino acids are left unchanged so that the packing of the pVIII proteins around the phage is not compromised. By changing the outer amino acids on the pVIII protein, the surface characteristics of the phage can be tailored to higher affinities to specific metal ions and thus promoting selective growth of specific inorganic materials on the phage surface.
(c) Amyloid Fibers
In another embodiment, amyloid fibers can be used as the biological template on which metal ions can nucleate and assemble into a catalytic nanowire. Under certain conditions, one or more normally soluble proteins (i.e., a precursor protein) may fold and assemble into a filamentous structure and become insoluble. Amyloid fibers are typically composed of aggregated β-strands, regardless of the structure origin of the precursor protein. As used herein, the precursor protein may contain natural or unnatural amino acids. The precursor protein may be further modified with a fatty acid tail.
(d) Virus and Capsid
In further embodiments, a virus or a capsid can be used as a biological template. Similar to a bacteriophage, a virus also comprises a protein coat and a nucleic acid core. In particular, viruses of anisotropic shapes, such as viral fibers, are suitable for nucleating and growing the catalytic nanowires described herein. Further, a virus can be genetically manipulated to express specific peptides on its coat for desirable binding to the ions. Viruses that have elongated or filamentous structures include those that are described in, for example, Christopher Ring, Genetically Engineered Viruses, (Ed) Bios Scientific (2001).
In certain embodiments, the virus may have its genetic materials removed and only the exterior protein coat (capsid) remains as the biological template.
2. Nucleation
Nucleation is the process of forming an inorganic nanowire in situ by converting soluble precursors (e.g., metal salts and anions) into nanocrystals in the presence of a template (e.g., a biological template). Typically, the nucleation and growth takes place from multiple binding sites along the length of the biological template in parallel. The growth continues until a structure encasing the biological template is formed. In some embodiments this structure is single-crystalline. In other embodiments the structure is polycrystalline, and in other embodiments the structure is polycrystalline. If desired, upon completion of the synthesis the organic biological template (e.g., bacteriophage) can be removed by thermal treatment ( ̃300° C.) in air or oxygen, without significantly affecting either the structure or shape of the inorganic material. In addition, dopants can be either simultaneously incorporated during the growth process or, in another embodiment, dopants can be incorporated via impregnation techniques.
(a) Nanowire Growth Methods
FIG. 7 shows a flow chart of a nucleation process for forming a nanowire comprising a metal oxide. A phage solution is first prepared (block 504), to which metal salt precursor comprising metal ions is added (block 510). Thereafter, an anion precursor is added (block 520). It is noted that, in various embodiments, the additions of the metal ions and anion precursor can be simultaneous or sequentially in any order. Under appropriate conditions (e.g., pH, molar ratio of the phage and metal salt, molar ratio of the metal ions and anions, addition rate, etc.), the metal ions and anions become bound to the phage, nucleate and grow into a nanowire of MmXnZp composition (block 524). Following calcinations, nanowires comprising MmXn are transformed to nanowires comprising metal oxide (MxOy) (block 530). An optional step of doping (block 534) incorporates a dopant (Dp+) in the nanowires comprising metal oxide (MxOy, wherein x and y are each independently a number from 1 to 100.
Thus, one embodiment provides a method for preparing a metal oxide nanowire comprising a plurality of metal oxides (MxOy), the method comprising:
a) providing a solution comprising a plurality of biological templates;
(b) introducing at least one metal ion and at least one anion to the solution under conditions and for a time sufficient to allow for nucleation and growth of a nanowire comprising a plurality of metal salts (MmXnZp) on the template; and
(c) converting the nanowire (MmXnZp) to a metal oxide nanowire comprising a plurality of metal oxides (MxOy),
wherein:
M is, at each occurrence, independently a metal element from any of Groups 1 through 7, lanthanides or actinides;
X is, at each occurrence, independently hydroxides, carbonates, bicarbonates, phosphates, hydrogenphosphates, dihydrogenphosphates, sulfates, nitrates or oxalates;
Z is O;
n, m, x and y are each independently a number from 1 to 100; and
p is a number from 0 to 100.
In certain variations of the foregoing, two or more different metal ions may be used. This produces nanowires comprising a mixture of two or more metal oxides. Such nanowires may be advantageous in certain catalytic reactions. For example, in some embodiments a nanowire may comprise two or more different metal oxides where at least one of the metal oxides has good OCM activity and at least one metal oxide has good ODH activity.
In certain embodiments of the above, Applicants have found that it may be advantageous to perform multiple sequential additions of the metal ion, This addition technique may be particularly applicable to embodiments wherein two or more different metal ions are employed to form a mixed nanowire (M1M2XxYy, wherein M1 and M2 are different metal elements), which can be converted to M1M2Oz, for example by calcination. The slow addition may be performed over any period of time, for example from 1 day to 1 week. In this regard, use of a syringe pump may be advantageous. Slow addition of the components help ensure that they will nucleate on the biological template instead of non-selectively precipitate.
In various embodiments, the biological templates are phages, as defined herein. In further embodiments, the metal ion is provided by adding one or more metal salt (as described herein) to the solution. In other embodiments, the anion is provided by adding one or more anion precursor to the solution. In various embodiments, the metal ion and the anion can be introduced to the solution simultaneously or sequentially in any order. In some embodiments, the nanowire (MmXnZp) is converted to a metal oxide nanowire by calcination, which is a thermal treatment that transforms or decomposes the MmXnZp nanowire to a metal oxide. In yet another embodiment, the method further comprises doping the metal oxide nanowire with a dopant. Converting the nanowire to a metal oxide generally comprises calcining.
In a variation of the above method, mixed metal oxides can be prepared (as opposed to a mixture of metal oxides). Mixed metal oxides can be represented by the following formula M1wM2xM3yOz, wherein M1, M2 and M3 are each independently absent or a metal element, and w, x, y and z are integers such that the overall charge is balanced. Mixed metal oxides comprising more than three metals are also contemplated and can be prepared via an analogous method. Such mixed metal oxides find utility in a variety of the catalytic reactions disclosed herein. One exemplary mixed metal oxide is Na10MnW5O17 (Example 18).
Thus, one embodiment provides a method for preparing a mixed metal oxide nanowire comprising a plurality of mixed metal oxides (M1wM2xM3yOz), the method comprising:
a) providing a solution comprising a plurality of biological templates;
(b) introducing metal salts comprising M1, M2 and M3 to the solution under conditions and for a time sufficient to allow for nucleation and growth of a nanowire comprising a plurality of the metal salts on the template; and
(c) converting the nanowire to a mixed metal oxide nanowire comprising a plurality of mixed metal oxides (M1wM2xM3yOz), wherein:
M1, M2 and M3 are, at each occurrence, independently a metal element from any of Groups 1 through 7, lanthanides or actinides;
n, m, x and y are each independently a number from 1 to 100; and
p is a number from 0 to 100.
In other embodiments, the present disclosure provides a method for preparing metal oxide nanowires which may not require a calcination step. Thus, in some embodiments the method for preparing metal oxide nanowires comprises:
(a) providing a solution that includes a plurality of biological templates; and
(b) introducing a compound comprising a metal to the solution under conditions and for a time sufficient to allow for nucleation and growth of a nanowire (MmYn) on the template;
wherein:
M is a metal element from any of Groups 1 through 7, lanthanides or actinides;
Y is O;
n and m are each independently a number from 1 to 100.
In some specific embodiments of the foregoing method, M is an early transition metal, for example V, Nb, Ta, Ti, Zr, Hf, W, Mo or Cr. In other embodiments, the metal oxide is WO3. In yet another embodiment, the method further comprises doping the metal oxide nanowire with a dopant. In some further embodiments, a reagent is added which converts the compound comprising a metal into a metal oxide.
In another embodiment, nanowires are prepared by using metal salts sensitive to water hydrolysis, for example NbCl5, WCl6, TiCl4, ZrCl4. A template can be placed in ethanol along with the metal salt. Water is then slowly added to the reaction in order to convert the metals salts to metal oxide coated template.
By varying the nucleation conditions, including (without limitation): incubation time of phage and metal salt; incubation time of phage and anion; concentration of phage; metal ion concentration, anion concentration, sequence of adding anion and metal ions; pH; phage sequences; solution temperature in the incubation step and/or growth step; types of metal precursor salt; types of anion precursor; addition rate; number of additions; amount of metal salt and/or anion precursor per addition, the time that lapses between the additions of the metal salt and anion precursor, including, e.g., simultaneous (zero lapse) or sequential additions followed by respective incubation times for the metal salt and the anion precursor, stable nanowires of diverse compositions and surface properties can be prepared. For example, in certain embodiments the pH of the nucleation conditions is at least 7.0, at least 8.0, at least 9.0, at least 10.0, at least 11.0, at least 12.0 or at least 13.0.
As noted above, the rate of addition of reactants (e.g., metal salt, metal oxide, anion precursor, etc.) is one parameter that can be controlled and varied to produce nanowires having different properties. During the addition of reactants to a solution containing an existing nanowire and/or a templating material (e.g., phage), a critical concentration is reached for which the speed of deposition of solids on the existing nanowire and/or templating material matches the rate of addition of reactants to the reaction mixture. At this point, the concentration of soluble cation stabilizes and stops rising. Thus, nanowire growth can be controlled and maximized by maintaining the speed of addition of reactants such that near super-saturation concentration of the cation is maintained. This helps ensure that no undesirable nucleation occurs. If super-saturation of the anion (e.g., hydroxide) is exceeded, a new solid phase can start nucleating which allows for non-selective solid precipitation, rather than nanowire growth. Thus, in order to selectively deposit an inorganic layer on an existing nanowire and/or a templating material, the addition rate of reactants should be controlled to avoid reaching super-saturation of the solution containing the suspended solids.
Accordingly, in one embodiment, reactant is repeatedly added in small doses to slowly build up the concentration of the reactant in the solution containing the template. In some embodiments, the speed of addition of reactant is such that the reactant concentration in the solution containing the template is near (but less than) the saturation point of the reactant. In some other embodiments, the reactant is added portion wise (i.e., step addition) rather than continuously. In these embodiments, the amount of reactant in each portion, and the time between addition of each portion, is controlled such that the reactant concentration in the solution containing the template is near (but less than) the saturation point of the reactant. In certain embodiments of the foregoing, the reactant is a metal cation while in other embodiments the reactant is an anion.
Initial formation of nuclei on a template can be obtained by the same method described above, wherein the concentration of reactant is increased until near, but not above, the supersaturation point of the reactant. Such an addition method facilitates nucleation of the solid phase on the template, rather than homogeneous non-seeding nucleation. In some embodiments, it is desirable to use a slower reactant addition speed during the initial nucleation phase as the super-saturation depression due to the template might be quite small at this point. Once the first layer of solid (i.e., nanowire) is formed on the template, the addition speed can be increased.
In some embodiments, the addition rate of reactant is controlled such that the precipitation rate matches the addition rate of the reactant. In these embodiments, nanowires comprising two or more different metals can be prepared by controlling the addition rates of two or more different metal cation solutions such that the concentration of each cation in the templating solution is maintained at or near (but does not exceed) the saturation point for each cation.
In some embodiments, the optimal speed of addition (and step size if using step additions) is controlled as a function of temperature. For example, in some embodiments the nanowire growth rate is accelerated at higher temperatures. Thus, the addition rate of reactants is adjusted according to the temperature of the templating solution.
In other embodiments, modeling (iterative numeric rather than algebraic) of the nanowire growth process is used to determine optimal solution concentrations and supernatant re-cycling strategies.
As noted above, the addition rate of reactants can be controlled and modified to change the properties of the nanowires. In some embodiments, the addition rate of a hydroxide source must be controlled such that the pH of the templating solution is maintained at the desired level. This method may require specialized equipment, and depending on the addition rate, the potential for localized spikes in pH upon addition of the hydroxide source is possible. Thus, in an alternative embodiment the present disclosure provides a method wherein the template solution comprises a weak base that slowly generates hydroxide in-situ, obviating the need for an automated addition sequence.
In the above embodiment, organic epoxides, such as but not limited to propylene oxide and epichlorohydrin, are used to slowly increase the template solution pH without the need for automated pH control. The epoxides are proton scavengers and undergo an irreversible ring-opening reaction with a nucleophilic anion of the metal oxide precursor (such as but not limited to Cl− or NO3−). The net effect is a slow homogenous raise in pH to form metal hydroxy species in solution that deposit onto the template surface. In some embodiments, the organic epoxide is propylene oxide.
An attractive feature of this method is that the organic epoxide can be added all at once, there is no requirement for subsequent additions of organic epoxide to grow metal oxide coatings over the course of the reaction. Due to the flexibility of the “epoxide-assisted” coatings, it is anticipated that many various embodiments can be employed to make new templated materials (e.g., nanowires). For example, mixed metal oxide nanowires can be prepared by starting with appropriate ratios of metal oxide precursors and propylene oxide in the presence of bacteriophage. In other embodiments, metal oxide deposition on bacteriophage can be done sequentially to prepare core/shell materials (described in more detail below).
(b) Metal Salt
As noted above, the nanowires are prepared by nucleation of metal ions in the presence of an appropriate template, for example, a bacteriophage. In this respect, any soluble metal salt may be used as the precursor of metal ions that nucleate on the template. Soluble metal salts of the metals from Groups 1 through 7, lanthanides and actinides are particularly useful and all such salts are contemplated.
In one embodiment, the soluble metal salt comprises chlorides, bromides, iodides, nitrates, sulfates, acetates, oxides, oxyhalides, oxynitrates, phosphates (including hydrogenphosphate and dihydrogenphosphate) or oxalates of metal elements from Groups 1 through 7, lanthanides, actinides or combinations thereof. In more specific embodiments, the soluble metal salt comprises chlorides, nitrates or sulfates of metal elements from Groups 1 through 7, lanthanides, actinides or combinations thereof. The present disclosure contemplates all possible chloride, bromide, iodide, nitrate, sulfate, acetate, oxide, oxyhalides, oxynitrates, phosphates (including hydrogenphosphate and dihydrogenphosphate) and oxalate salts of metal elements from Groups 1 through 7, lanthanides, actinides or combinations thereof.
In another embodiment, the metal salt comprises LiCl, LiBr, LiI, LiNO3, Li2SO4, LiCO2CH3, Li2C2O4, NaCl, NaBr, NaI, NaNO3, Na2SO4, NaCO2CH3, Na2C2O4, KCl, KBr, KI, KNO3, K2SO4, KCO2CH3, K2C2O4, RbCl, RbBr, RbI, RbNO3, Rb2SO4, RbCO2CH3, Rb2C2O4, CsCl, CsBr, CsI, CsNO3, Cs2SO4, CsCO2CH3, Cs2C2O4, BeCl2, BeBr2, BeI2, Be(NO3)2, BeSO4, Be(CO2CH3)2, BeC2O4, MgCl2, MgBr2, MgI2, Mg(NO3)2, MgSO4, Mg(CO2CH3)2, MgC2O4, CaCl2, CaBr2, CaI2, Ca(NO3)2, CaSO4, Ca(CO2CH3)2, CaC2O4, SrCl2, SrBr2, SrI2, Sr(NO3)2, SrSO4, Sr(CO2CH3)2, SrC2O4, BaCl2, BaBr2, BaI2, Ba(NO3)2, BaSO4, Ba(CO2CH3)2, BaC2O4, ScCl3, ScBr3, ScI3, Sc(NO3)3, Sc2(SO4)3, Sc(CO2CH3)3, Sc2(C2O4)3, YCl3, YBr3, YI3, Y(NO3)3, Y2(SO4)3, Y(CO2CH3)3, Y2(O2O4)3, TiCl4, TiBr4, TiI4, Ti(NO3)4, Ti(SO4)2, Ti(CO2CH3)4, Ti(O2O4)2, ZrCl4, ZrOCl2, ZrBr4, ZrI4, Zr(NO3)4, ZrO(NO3)2, Zr(SO4)2, Zr(CO2CH3)4, Zr(C2O4)2, HfCl4, HfBr4, HfI4, Hf(NO3)4, Hf(SO4)2, Hf(CO2CH3)4, Hf(O2O4)2, LaCl3, LaBr3, LaI3, La(NO3)3, La2(SO4)3, La(CO2CH3)3, La2(C2O4)3, WCl2, WCl3, WCl4, WCl5, WCl6, WBr2, WBr3, WBr4, WBr5, WBr6, WI2, WI3, WI4, WI5, WI6, W(NO3)2, W(NO3)3, W(NO3)4, W(NO3)5, W(NO3)6, W(CO2CH3)2, W(CO2CH3)3, W(CO2CH3)4, W(CO2CH3)5, W(CO2CH3)6, WC2O4, W2(C2O4)3, W(C2O4)2, W2(C2O4)5, W(C2O4)6, MoCl4, MnCl2 MnCl3, MnBr2 MnBr3, MnI2 MnI3, Mn(NO3)2, Mn(NO3)3, MnSO4, Mn2(SO4)3, Mn(CO2CH3)2, Mn(CO2CH3)3, MnC2O4, Mn2(C2O4)3, MoCl2, MoCl3, MoCl4, MoCl5, MoBr2, MoBr3, MoBr4, MoBr5, MoI2, MoI3, MoI4, MoI5, Mo(NO3)2, Mo(NO3)3, Mo(NO3)4, Mo(NO3)5, MoSO4, Mo2(SO4)3, Mo(SO4)2, Mo2(SO4)5, Mo(CO2CH3)2, Mo(CO2CH3)3, Mo(CO2CH3)4, Mo(CO2CH3)5, MoC2O4, Mo2(C2O4)3, Mo(C2O4)2, Mo2(C2O4)5, VCl, VCl2, VCl3, VCl4, VBr, VBr2, VBr3, VBr4, VI, VI2, VI3, VI4, VNO3, V(NO3)2, V(NO3)3, V(NO3)4, V2SO4, VSO4, V2(SO4)3, V(SO4)4, VCO2CH3, V(CO2CH3)2, V(CO2CH3)3, V(CO2CH3)4, V2O2O4, VC2O4, V2(C2O4)3, V(O2O4)4, NdCl3, NdBr3, NdI3, Nd(NO3)3, Nd2(SO4)3, Nd(CO2CH3)3, Nd2(C2O4)3, EUCl3, EuBr3, EuI3, Eu(NO3)3, Eu2(SO4)3, Eu(CO2CH3)3, Eu2(C2O4)3, PrCl3, PrBr3, PrI3, Pr(NO3)3, Pr2(SO4)3, Pr(CO2CH3)3, Pr2(C2O4)3, SmCl3, SmBr3, SmI3, Sm(NO3)3, Sm2(SO4)3, Sm(CO2CH3)3, Sm2(C2O4)3, CeCl3, CeBr3, CeI3, Ce(NO3)3, Ce2(SO4)3, Ce(CO2CH3)3, Ce2(C2O4)3 or combinations thereof.
In more specific embodiments, the metal salt comprises MgCl2, LaCl3, ZrCl4, WCl4, MoCl4, MnCl2, MnCl3, Mg(NO3)2, La(NO3)3, ZrOCl2, Mn(NO3)2, Mn(NO3)3, ZrO(NO3)2, Zr(NO3)4, or combinations thereof.
In other embodiments, the metal salt comprises NdCl3, NdBr3, NdI3, Nd(NO3)3, Nd2(SO4)3, Nd(CO2CH3)3, Nd2(C2O4)3, EuCl3, EuBr3, EuI3, Eu(NO3)3, Eu2(SO4)3, Eu(CO2CH3)3, Eu2(C2O4)3, PrCl3, PrBr3, PrI3, Pr(NO3)3, Pr2(SO4)3, Pr(CO2CH3)3, Pr2(C2O4)3 or combinations thereof.
In still other embodiments, the metal salt comprises Mg, Ca, Mg, W, La, Nd, Sm, Eu, W, Mn, Zr or mixtures thereof. The salt may be in the form of (oxy)chlorides, (oxy)nitrates or tungstates.
(c) Anion Precursor
The anions, or counter ions of the metal ions that nucleate on the template, are provided in the form of an anion precursor. The anion precursor dissociates in the solution phase and releases an anion. Thus, the anion precursor can be any stable soluble salts having the desired anion. For instance, bases such as alkali metal hydroxides (e.g., sodium hydroxide, lithium hydroxide, potassium hydroxides) and ammonium hydroxide are anion precursors that provide hydroxide ions for nucleation. Alkali metal carbonates (e.g., sodium carbonate, potassium carbonates) and ammonium carbonate are anion precursors that provide carbonates ions for nucleation.
In certain embodiments, the anion precursor comprises one or more metal hydroxide, metal carbonate, metal bicarbonate, or metal oxalate. Preferably, the metal is an alkali or an alkaline earth metal. Thus, the anion precursor may comprise any one of alkali metal hydroxides, carbonates, bicarbonates, or oxalate; or any one of alkaline earth metal hydroxide, carbonates, bicarbonates, or oxalate.
In some specific embodiments, the one or more anion precursors comprises LiOH, NaOH, KOH, Sr(OH)2, Ba(OH)2, Na2CO3, K2CO3, NaHCO3, KHCO3, and NR4OH, wherein R is selected from H, and C1-C6 alkyl. Ammonium salts may provide certain advantages in that there is less possibility of introducing unwanted metal impurities. Accordingly, in a further embodiment, the anion precursor comprises ammonium hydroxide.
The dimensions of the nanowires are comparable to those of the biological templates (e.g., phage), although they can have different aspect ratios as longer growth can be used to increase the diameter while the length will increase in size at a much slower rate. The spacing of peptides on the phage surface controls the nucleation location and the catalytic nanowire size based on steric hindrance. The specific peptide sequence information can (or may) dictate the identity, size, shape and crystalline face of the catalytic nanowire being nucleated. To achieve the desired stochiometry between metal elements, support and dopants, multiple peptides specific for these discrete materials can be co-expressed within the same phage. Alternatively, precursor salts for the materials can be combined in the reaction at the desired stochiometry. The techniques for phage propagation and purification are also well established, robust and scalable. Multi-kilogram amounts of phage can be easily produced, thus assuring straightforward scale up to large, industrial quantities.
Typical functional groups in amino acids that can be used to tailor the phage surface affinity to metal ions include: carboxylic acid (—COOH), amino (—NH3+ or —NH2), hydroxyl (—OH), and/or thiol (—SH) functional groups. Table 9 summarizes a number of exemplary phages used in the present invention for preparing nanowires of inorganic metal oxides. Sequences within Table 9 refer to the amino acid sequence of the pVIII protein (single-letter amino acid code). Underlined portions indicate the terminal sequence which was varied to tailor the phage surface affinity to metal ions. SEQ ID NO 14 represents wild type pVIII protein while SEQ ID NO 15 represents wild type pVIII protein including the signaling peptide portion (bold).








TABLE 9





SEQ



ID



NO
Sequence







 1
AEEGSEDPAKAAFNSLQASATEYIGYAWAMVVVIVGATIGIKLFKKFTSKAS


 


 2
EEGSDDPAKAAFNSLQASATEYIGYAWAMVVVIVGATIGIKLFKKFTSKAS


 


 3
AEEEDPAKAAFNSLQASATEYIGYAWAMVVVIVGATIGIKLFKKFTSKAS


 


 4
EEEDPAKAAFNSLQASATEYIGYAWAMVVVIVGATIGIKLFKKFTSKAS


 


 5
AEEEEDPAKAAFNSLQASATEYIGYAWAMVVVIVGATIGIKLFKKFTSKAS


 


 6
AEEAEDPAKAAFNSLQASATEYIGYAWAMVVVIVGATIGIKLFKKFTSKAS


 


 7
EEXEDPAKAAFNSLQASATEYIGYAWAMVVVIVGATIGIKLFKKFTSKAS



X = E or G


 


 8
AEDDDPAKAAFNSLQASATEYIGYAWAMVVVIVGATIGIKLFKKFTSKAS


 


 9
AVSGSSPGDDPAKAAFNSLQASATEYIGYAWAMVVVIVGATIGIKLFKKFTSKAS


 


10
AVSGSSPDSDPAKAAFNSLQASATEYIGYAWAMVVVIVGATIGIKLFKKFTSKAS


 


11
AGETQQAMEDPAKAAFNSLQASATEYIGYAWAMVVVIVGATIGIKLFKKFTSKAS


 


12
AAGETQQAMDPAKAAFNSLQASATEYIGYAWAMVVVIVGATIGIKLFKKFTSKAS


 


13
AEPGHDAVPEDPAKAAFNSLQASATEYIGYAWAMVVVIVGATIGIKLFKKFTSKAS


 


14
AEGDDDPAKAAFNSLQASATEYIGYAWAMVVVIVGATIGIKLFKKFTSKAS


 


15
MKKSLVLKASVAVATLVPMLSFA



AEGDDDPAKAAFNSLQASATEYIGYAWAMVVVIVGATIGIKLFKKFTSKAS









3. Core/Shell Structures
In certain embodiments, nanowires can be grown on a support nanowire that has no or a different catalytic property. FIG. 8 shows an exemplary process 600 for growing a core/shell structure. Similar to FIG. 7, a phage solution is prepared (block 604), to which a first metal salt and a first anion precursor are sequentially added (blocks 610 and 620) in appropriate conditions to allow for the nucleation and growth of a nanowire (M1m1X1n1Zp1) on the phage (block 624). Thereafter, a second metal salt and a second anion precursor are sequentially added (blocks 630 and 634), under conditions to cause the nucleation and growth of a coating of M2m2X2n2Zp2 on the nanowire M1m1X1n1Zp1 (block 640). Following calcinations, nanowires of a core/shell structure M1x1Oy1/M2x2Oy2 are formed, wherein x1, y1, x2 and y2 are each independently a number from 1 to 100, and p1 and p2 are each independently a number from 0 to 100 (block 644). A further step of impregnation (block 650) produces a nanowire comprising a dopant and comprising a core of M1x1Oy1 coated with a shell of M2x2Oy2. In some embodiments, M1 is Mg, Al, Ga, Ca or Zr. In certain embodiments of the foregoing, M1 is Mn and M2 is Mg. In other embodiments, M1 is Mg and M2 is Mn. In other embodiments, M1 is La and M2 is Mg, Ca, Sr, Ba, Zr, Nd, Y, Yb, Eu, Sm or Ce. In other embodiments, M1 is Mg and M2 is La or Nd.
In other embodiments, M1x1Oy1 comprises La2O3 while in other embodiments M2x2Oy2 comprises La2O3. In other embodiments of the foregoing, M1x1Oy1 or M2x2Oy2 further comprises a dopant, wherein the dopant comprises Nd, Mn, Fe, Zr, Sr, Ba, Y or combinations thereof. Other specific combinations of core/shell nanowires are also envisioned within the scope of the present disclosure.
Thus, one embodiment provides a method for preparing metal oxide nanowires in a core/shell structure, the method comprising:
(a) providing a solution that includes a plurality of biological templates;
(b) introducing a first metal ion and a first anion to the solution under conditions and for a time sufficient to allow for nucleation and growth of a first nanowire (M1m1X1n1Zp1) on the template; and
(c) introducing a second metal ion and optionally a second anion to the solution under conditions and for a time sufficient to allow for nucleation and growth of a second nanowire (M2m2X2n2Zp2) on the first nanowire (M1m1X1n1Zp1);
(d) converting the first nanowire (M1m1X1n1Zp1) and the second nanowire (M2m2X2n2Zp2) to respective metal oxide nanowires (M1x1Oy1) and (M2x2Oy2),
wherein:
M1 and M2 are the same or different and independently selected from a metal element;
X1 and X2 are the same or different and independently hydroxides, carbonates, bicarbonates, phosphates, hydrogenphosphates, dihydrogenphosphates, sulfates, nitrates or oxalates;
Z is O;
n1, m1, m1, m2, x1, y1, x2 and y2 are each independently a number from 1 to 100; and
p1 and p2 are independently a number from 0 to 100.
In some embodiments, M1 and M2 are the same or different and independently selected from a metal element from any of Groups 2 through 7, lanthanides or actinides
In various embodiments, the biological templates are phages, as defined herein. In further embodiments, the respective metal ion is provided by adding one or more respective metal salts (as described herein) to the solution. In other embodiments, the respective anions are provided by adding one or more respective anion precursors to the solution. In various embodiments, the first metal ion and the first anion can be introduced to the solution simultaneously or sequentially in any order. Similarly, the second metal ion and optionally the second anion can be introduced to the solution simultaneously or sequentially in any order. The first and second nanowire are typically converted to a metal oxide nanowire in a core/shell structure by calcination.
In yet another embodiment, the method further comprises doping the metal oxide nanowire in a core/shell structure with a dopant.
By varying the nucleation conditions, including the pH of the solution, relative ratio of metal salt precursors and the anion precursors, relative ratios of the precursors and the phage of the synthetic mixture, stable nanowires of diverse compositions and surface properties can be prepared.
In certain embodiments, the core nanowire (the first nanowire) is not catalytically active or less so than the shell nanowire (the second nanowire), and the core nanowire serve as an intrinsic catalytic support for the more active shell nanowire. For example, ZrO2 may not have high catalytic activity in an OCM reaction, whereas Sr2+doped La2O3 does. A ZrO2 core thus may serve as a support for the catalytic Sr2+doped La2O3 shell.
In some embodiments, the present disclosure provides a nanowire comprising a core/shell structure and comprising a ratio of effective length to actual length of less than one. In other embodiments, the nanowires having a core/shell structure comprise a ratio of effective length to actual length equal to one.
Nanowires in a core/shell arrangement may be prepared in the absence of a biological template. For example, a nanowire comprising a first metal may be prepared according to any of the non-template directed methods described herein. A second metal may then be nucleated or plated onto the nanowire to form a core/shell nanowire. The first and second metals may be the same or different. Other methods for preparing core/shell nanowires in the absence of a biological template are also envisaged.
4. Diversity
As noted above, in some embodiments, the disclosed template-directed synthesis provides nanowires having diverse compositions and/or morphologies. This method combines two extremely powerful approaches, evolutionary selection and inorganic synthesis, to produce a library of nanowire catalysts with a new level of control over materials composition, materials surface and crystal structure. These nanowires prepared by biologically-templated methods take advantage of genetic engineering techniques to enable combinatorial synthesis of robust, active and selective inorganic catalytic polycrystalline nanowires. With selection, evolution and a combinatorial library with over a hundred billion sequence possibilities, nanowires having high specificity and product conversion yields in catalytic reactions are generated. This permits simultaneous optimization the nanowires' catalytic properties in a high-dimensional space.
In various embodiments, the synthetic parameters for nucleating and growing nanowires can be manipulated to create nanowires of diverse compositions and morphologies. Typical synthetic parameters include, without limitation, concentration ratios of metal ions and active functional groups on the phage; concentration ratios of metal and anions (e.g., hydroxide); incubation time of phage and metal salt; incubation time of phage and anion; concentration of phage; sequence of adding anion and metal ions; pH; phage sequences; solution temperature in the incubation step and/or growth step; types of metal precursor salt; types of anion precursor; addition rate, number of additions; the time that lapses between the additions of the metal salt and anion precursor, including, e.g., simultaneous (zero lapse) or sequential additions followed by respective incubation times for the metal salt and the anion precursor.
Additional variable synthetic parameters include, growth time once both metal and anion are present in the solution; choice of solvents (although water is typically used, certain amounts of alcohol, such as methanol, ethanol and propanol, can be mixed with water); choice and the number of metal salts used (e.g., both LaCl3 and La(NO3)3 can be used to provide La3+ ions); choice and the number of anion precursors used (e.g., both NaOH then LiOH can be used to provide the hydroxide); choice or the number of different phage sequences used; the presence or absence of a buffer solution; the different stages of the growing (e.g., nanowires may be precipitated and cleaned and resuspended in a second solution and perform a second growth of the same material (thicker core) or different material to form a core/shell structure.
Thus, libraries of nanowires can be generated with diverse physical properties and characteristics such as: composition, e.g., basic metal oxides (MxOy), size, shape, surface morphology, exposed crystal faces/edge density, crystallinity, dispersion, and stoichiometry and nanowire template physical characteristics including length, width, porosity and pore density. High throughput, combinatorial screening methods are then applied to evaluate the catalytic performance characteristics of the nanowires (see, e.g., FIG. 2). Based on these results, lead target candidates are identified. From these lead targets, further rational modifications to the synthetic designs can be made to create nanowires that satisfy certain catalytic performance criteria. This results in further refinement of the nanowire design and material structure.
Direct Synthesis of Nanowires
In some embodiments, the nanowires can be synthesized in a solution phase in the absence of a template. Typically, a hydrothermal or sol gel approach can be used to create straight (i.e., ratio of effective length to actual length equal to one) and substantially single crystalline nanowires. As an example, nanowires comprising a metal oxide can be prepared by (1) forming nanowires of a metal oxide precursor (e.g., metal hydroxide) in a solution of a metal salt and an anion precursor; (2) isolating the nanowires of the metal oxide precursor; and (3) calcining the nanowires of the metal oxide precursor to provide nanowires of a corresponding metal oxide. In other embodiments (for example MgO nanowires), the synthesis goes through an intermediate which can be prepared as a nanowire and then converted into the desired product while maintaining its morphology. Optionally, the nanowires comprising a metal oxide can be doped according to methods described herein.
In other certain embodiment, nanowires comprising a core/shell structure are prepared in the absence of a biological template. Such methods may include, for example, preparing a nanowire comprising a first metal and growing a shell on the outersurface of this nanowire, wherein the shell comprises a second metal. The first and second metals may be the same or different.
In other aspects, a core/shell nanowire is prepared in the absence of a biological template. Such methods comprise preparing a nanowire comprising an inner core and an outer shell, wherein the inner core comprises a first metal, and the outer shell comprises a second metal, the method comprising:

    
    
        a) preparing a first nanowire comprising the first metal; and
        b) treating the first nanowire with a salt comprising the second metal.
    
    


In some embodiments of the foregoing method, the method further comprises addition of a base to a solution obtained in step b). In yet other examples, the first metal and the second metal are different. In yet further embodiments, the salt comprising the second metal is a halide or a nitrate. In certain aspects it may be advantageous to perform one or more sequential additions of the salt comprising the second metal and a base. Such sequential additions help prevent non-selective precipitation of the second metal and favor conditions wherein the second metal nucleates on the surface of the first nanowire to form a shell of the second metal. Furthermore, the first nanowire may be prepared by any method, for example via a template directed method (e.g., phage).
As in the template-directed synthesis, the synthetic conditions and parameters of the direct synthesis of nanowires can also be adjusted to create diverse compositions and surface morphologies (e.g., crystal faces) and dopant levels. For example, variable synthetic parameters include: concentration ratios of metal and anions (e.g., hydroxide); reaction temperature; reaction time; sequence of adding anion and metal ions; pH; types of metal precursor salt; types of anion precursor; number of additions; the time that lapses between the additions of the metal salt and anion precursor, including, e.g., simultaneous (zero lapse) or sequential additions followed by respective incubation times for the metal salt and the anion precursor.
In addition, the choice of solvents or surfactants may influence the crystal growth of the nanowires, thereby generating different nanowire dimensions (including aspect ratios). For example, solvents such as ethylene glycol, poly(ethylene glycol), polypropylene glycol and poly(vinyl pyrrolidone) can serve to passivate the surface of the growing nanowires and facilitate a linear growth of the nanowire.
In some embodiments, nanowires can be prepared directly from the corresponding oxide. For example, metal oxides may be treated with halides, for example ammonium halides, to produce nanowires. Such embodiments find particular utility in the context of lanthanide oxides, for example La2O3, are particularly useful since the procedure is quite simple and economically efficient Nanowires comprising two or more metals and/or dopants may also be prepared according to these methods. Accordingly, in some embodiments at least one of the metal compounds is an oxide of a lanthanide element. Such methods are described in more detail in the examples.
Accordingly, in one embodiment the present disclosure provides a method for preparing a nanowire in the absence of a biological template, the method comprising treating at least one metal compound with a halide. In certain embodiments, nanowires comprising more than one type of metal and/or one or more dopants can be prepared by such methods. For example, in one embodiment the method comprises treating two or more different metal compounds with a halide and the nanowire comprises two or more different metals. The nanowire may comprise a mixed metal oxide, metal oxyhalide, metal oxynitrate or metal sulfate.
In some other embodiments of the foregoing, the halide is in the form of an ammonium halide. In yet other embodiments, the halide is contacted with the metal compound in solution or in the solid state.
In certain embodiments, the method is useful for incorporation of one or more doping elements into a nanowire. For example, the method may comprise treating at least one metal compound with a halide in the presence of at least one doping element, and the nanowire comprises the least one doping element. In some aspects, the at least one doping element is present in the nanowire in an atomic percent ranging from 0.1 to 50 at %.
Other methods for preparation of nanowires in the absence of a biological template include preparing a hydroxide gel by reaction of at least one metal salt and a hydroxide base. For example, the method may further comprise aging the gel, heating the gel or combinations thereof. In certain other embodiments, the method comprises reaction of two or more different metal salts, and the nanowire comprises two or more different metals.
Doping elements may also be incorporated by using the hydroxide gel method described above, further comprising addition of at least one doping element to the hydroxide gel, and wherein the nanowire comprises the at least one doping element. For example, the at least one doping element may be present in the nanowire in an atomic percent ranging from 0.1 to 50 at %.
In some embodiments, metal oxide nanowires can be prepared by mixing a metal salt solution and an anion precursor so that a gel of a metal oxide precursor is formed. This method can work for cases where the typical morphology of the metal oxide precursor is a nanowire. The gel is thermally treated so that crystalline nanowires of the metal oxide precursor are formed. The metal oxide precursor nanowires are converted to metal oxide nanowires by calcination. This method can be especially useful for lanthanides and group 3 elements. In some embodiments, the thermal treatment of the gel is hydrothermal (or solvothermal) at temperatures above the boiling point of the reaction mixture and at pressures above ambient pressure, in other embodiments it's done at ambient pressure and at temperatures equal to or below the boiling point of the reaction mixture. In some embodiments the thermal treatment is done under reflux conditions at temperatures equal to the boiling point of the mixture. In some specific embodiments the anion precursor is a hydroxide, e.g. Ammonium hydroxide, sodium hydroxide, lithium hydroxide, tetramethyl ammonium hydroxide, and the like. In some other specific embodiments the metal salt is LnCl3 (Ln=Lanthanide), in other embodiment the metal salt is Ln(NO3)3. In yet other embodiments, the metal salt is YCl3, ScCl3, Y(NO3)3, Sc(NO3)3. In some other embodiments, the metal precursor solution is an aqueous solution. In other embodiments, the thermal treatment is done at T=100° C. under reflux conditions.
This method can be used to make mixed metal oxide nanowires, by mixing at least two metal salt solutions and an anion precursor so that a mixed oxide precursor gel is formed. In such cases, the first metal may be a lathanide or a group 3 element, and the other metals can be from other groups, including groups 1-14.
In some different embodiments, metal oxide nanowires can be prepared in a similar way as described above by mixing a metal salt solution and an anion precursor so that a gel of a metal hydroxide precursor is formed. This method works for cases where the typical morphology of the metal hydroxide precursor is a nanowire. The gel is treated so that crystalline nanowires of the metal hydroxide precursor are formed. The metal hydroxide precursor nanowires are converted to metal hydroxide nanowires by base treatment and finally converted to metal oxide nanowires by calcination. This method may be especially applicable for group 2 elements, for example Mg. In some specific embodiments, the gel treatment is a thermal treatment at temperatures in the range 50-100° C. followed by hydrothermal treatment. In other embodiments, the gel treatment is an aging step. In some embodiments, the aging step takes at least one day. In some specific embodiments, the metal salt solution is a concentrated metal chloride aqueous solution and the anion precursor is the metal oxide. In some more specific embodiments, the metal is Mg. In certain embodiments of the above, these methods can be used to make mixed metal oxide nanowires. In these embodiments, the first metal is Mg and the other metal can be any other metal of groups 1-14+Ln.
Catalytic Reactions
The present disclosure provides for the use of catalytic nanowires as catalysts in catalytic reactions and related methods. The morphology and composition of the catalytic nanowires is not limited, and the nanowires may be prepared by any method. For example the nanowires may have a bent morphology or a straight morphology and may have any molecular composition. In some embodiments, the nanowires have better catalytic properties than a corresponding bulk catalyst (i.e., a catalyst having the same chemical composition as the nanowire, but prepared from bulk material). In some embodiments, the nanowire having better catalytic properties than a corresponding bulk catalyst has a ratio of effective length to actual length equal to one. In other embodiments, the nanowire having better catalytic properties than a corresponding bulk catalyst has a ratio of effective length to actual length of less than one. In other embodiments, the nanowire having better catalytic properties than a corresponding bulk catalyst comprises one or more elements from Groups 1 through 7, lanthanides or actinides.
Nanowires may be useful in any number of reactions catalyzed by a heterogeneous catalyst. Examples of reactions wherein nanowires having catalytic activity may be employed are disclosed in Farrauto and Bartholomew, “Fundamentals of Industrial Catalytic Processes” Blackie Academic and Professional, first edition, 1997, which is hereby incorporated in its entirety. Other non-limiting examples of reactions wherein nanowires having catalytic activity may be employed include: the oxidative coupling of methane (OCM) to ethane and ethylene; oxidative dehydrogenation (ODH) of alkanes to the corresponding alkenes, for example oxidative dehydrogenation of ethane or propane to ethylene or propylene, respectively; selective oxidation of alkanes, alkenes, and alkynes; oxidation of CO, dry reforming of methane, selective oxidation of aromatics; Fischer-Tropsch, hydrocarbon cracking; combustion of hydrocarbons and the like. Reactions catalyzed by the disclosed nanowires are discussed in more detail below.
The nanowires are generally useful as catalysts in methods for converting a first carbon-containing compound (e.g., a hydrocarbon, CO or CO2) to a second carbon-containing compound. In some embodiments the methods comprise contacting a nanowire, or material comprising the same, with a gas comprising a first carbon-containing compound and an oxidant to produce a carbon-containing compound. In some embodiments, the first carbon-containing compound is a hydrocarbon, CO, CO2, methane, ethane, propane, hexane, cyclohexane, octane or combinations thereof. In other embodiments, the second carbon-containing compound is a hydrocarbon, CO, CO2, ethane, ethylene, propane, propylene, hexane, hexane, cyclohexene, bicyclohexane, octane, octane or hexadecane. In some embodiments, the oxidant is oxygen, ozone, nitrous oxide, nitric oxide, water or combinations thereof.
In other embodiments of the foregoing, the method for conversion of a first carbon-containing compound to a second carbon-containing compound is performed at a temperature below 100° C., below 200° C., below 300° C., below 400° C., below 500° C., below 600° C., below 700° C., below 800° C., below 900° C. or below 1000° C. In other embodiments, the method for conversion of a first carbon-containing compound to a second carbon-containing compound is performed at a pressure below 1 ATM, below 2 ATM, below 5 ATM, below 10 ATM, below 25 ATM or below 50 ATM.
The catalytic reactions described herein can be performed using standard laboratory equipment known to those of skill in the art, for example as described in U.S. Pat. No. 6,350,716, which is incorporated herein in its entirety.
As noted above, the nanowires disclosed herein have better catalytic activity than a corresponding bulk catalyst. In some embodiments, the selectivity, yield, conversion, or combinations thereof, of a reaction catalyzed by the nanowires is better than the selectivity, yield, conversion, or combinations thereof, of the same reaction catalyzed by a corresponding bulk catalyst under the same conditions. For example, in some embodiments, the nanowire possesses a catalytic activity such that conversion of reactant to product in a reaction catalyzed by the nanowire is greater than at least 1.1 times, greater than at least 1.25 times, greater than at least 1.5 times, greater than at least 2.0 times, greater than at least 3.0 times or greater than at least 4.0 times the conversion of reactant to product in the same reaction catalyzed by a catalyst prepared from bulk material having the same chemical composition as the nanowire.
In other embodiments, the nanowire possesses a catalytic activity such that selectivity for product in a reaction catalyzed by the nanowire is greater than at least 1.1 times, greater than at least 1.25 times, greater than at least 1.5 times, greater than at least 2.0 times, greater than at least 3.0 times, or greater than at least 4.0 times the selectivity for product in the same reaction under the same conditions but catalyzed by a catalyst prepared from bulk material having the same chemical composition as the nanowire.
In yet other embodiments, the nanowire possesses a catalytic activity such that yield of product in a reaction catalyzed by the nanowire is greater than at least 1.1 times, greater than at least 1.25 times, greater than at least 1.5 times, greater than at least 2.0 times, greater than at least 3.0 times, or greater than at least 4.0 times the yield of product in the same reaction under the same conditions but catalyzed by a catalyst prepared from bulk material having the same chemical composition as the nanowire.
In certain reactions (e.g., OCM), production of unwanted oxides of carbon (e.g., CO and CO2) is a problem that reduces overall yield of desired product and results in an environmental liability. Accordingly, in one embodiment the present disclosure addresses this problem and provides nanowires with a catalytic activity such that the selectivity for CO and/or CO2 in a reaction catalyzed by the nanowires is less than the selectivity for CO and/or CO2 in the same reaction under the same conditions but catalyzed by a corresponding bulk catalyst. Accordingly, in one embodiment, the present disclosure provides a nanowire which possesses a catalytic activity such that selectivity for COx, wherein x is 1 or 2, in a reaction catalyzed by the nanowire is less than at least 0.9 times, less than at least 0.8 times, less than at least 0.5 times, less than at least 0.2 times or less than at least 0.1 times the selectivity for COX in the same reaction under the same conditions but catalyzed by a catalyst prepared from bulk material having the same chemical composition as the nanowire.
In some embodiments, the absolute selectivity, yield, conversion, or combinations thereof, of a reaction catalyzed by the nanowires disclosed herein is better than the absolute selectivity, yield, conversion, or combinations thereof, of the same reaction under the same conditions but catalyzed by a corresponding bulk catalyst. For example, in some embodiments the yield of product in a reaction catalyzed by the nanowires is greater than 20%, greater than 30%, greater than 50%, greater than 75%, or greater than 90%. In other embodiments, the selectivity for product in a reaction catalyzed by the nanowires is greater than 20%, greater than 30%, greater than 50%, greater than 75%, or greater than 90%. In other embodiments, the conversion of reactant to product in a reaction catalyzed by the nanowires is greater than 20%, greater than 30%, greater than 50%, greater than 75%, or greater than 90%.
In addition to the improved catalytic performance of the disclosed nanowires, the morphology of the nanowires is expected to provide for improved mixing properties for the nanowires compared to standard colloidal (e.g., bulk) catalyst materials. The improved mixing properties are expected to improve the performance of any number of catalytic reactions, for example, in the area of transformation of heavy hydrocarbons where transport and mixing phenomena are known to influence the catalytic activity. In other reactions, the shape of the nanowires is expected to provide for good blending, reduce settling, and provide for facile separation of any solid material.
In some other chemical reactions, the nanowires are useful for absorption and/or incorporation of a reactant used in chemical looping. For example, the nanowires find utility as NOx traps, in unmixed combustion schemes, as oxygen storage materials, as CO2 sorption materials (e.g., cyclic reforming with high H2 output) and in schemes for conversion of water to H2.
1. Oxidative Coupling of Methane (OCM)
As noted above, the present disclosure provides nanowires having catalytic activity and related approaches to nanowire design and preparation for improving the yield, selectivity and/or conversion of any number of catalyzed reactions, including the OCM reaction. As mentioned above, there exists a tremendous need for catalyst technology capable of addressing the conversion of methane into high value chemicals (e.g., ethylene and products prepared therefrom) using a direct route that does not go through syngas. Accomplishing this task will dramatically impact and redefine a non-petroleum based pathway for feedstock manufacturing and liquid fuel production yielding reductions in GHG emissions, as well as providing new fuel sources.
Ethylene has the largest carbon footprint compared to all industrial chemical products in part due to the large total volume consumed into a wide range of downstream important industrial products including plastics, surfactants and pharmaceuticals. In 2008, worldwide ethylene production exceeded 120 M metric tons while growing at a robust rate of 4% per year. The United States represents the largest single producer at 28% of the world capacity. Ethylene is primarily manufactured from high temperature cracking of naphtha (e.g., oil) or ethane that is separated from natural gas. The true measurement of the carbon footprint can be difficult as it depends on factors such as the feedstock and the allocation as several products are made and separated during the same process. However, some general estimates can be made based on published data.
Cracking consumes a significant portion (about 65%) of the total energy used in ethylene production and the remainder is for separations using low temperature distillation and compression. The total tons of CO2 emission per ton of ethylene are estimated at between 0.9 to 1.2 from ethane cracking and 1 to 2 from naphtha cracking. Roughly, 60% of ethylene produced is from naphtha, 35% from ethane and 5% from others sources (Ren, T.; Patel, M. Res. Conserv. Recycl. 53:513, 2009). Therefore, based on median averages, an estimated amount of CO2 emissions from the cracking process is 114M tons per year (based on 120M tons produced). Separations would then account for an additional 61M tons CO2 per year.
Nanowires provide an alternative to the need for the energy intensive cracking step. Additionally, because of the high selectivity of the nanowires, downstream separations are dramatically simplified, as compared to cracking which yields a wide range of hydrocarbon products. The reaction is also exothermic so it can proceed via an autothermal process mechanism. Overall, it is estimated that up to a potential 75% reduction in CO2 emission compared to conventional methods could be achieved. This would equate to a reduction of one billion tons of CO2 over a ten-year period and would save over 1M barrels of oil per day.
The nanowires also permit converting ethylene into liquid fuels such as gasoline or diesel, given ethylene's high reactivity and numerous publications demonstrating high yield reactions, in the lab setting, from ethylene to gasoline and diesel. On a life cycle basis from well to wheel, recent analysis of methane to liquid (MTL) using F-T process derived gasoline and diesel fuels has shown an emission profile approximately 20% greater to that of petroleum based production (based on a worst case scenario) (Jaramillo, P., Griffin, M., Matthews, S., Env. Sci. Tech 42:7559, 2008). In the model, the CO2 contribution from plant energy was a dominating factor at 60%. Thus, replacement of the cracking and F-T process would be expected to provide a notable reduction in net emissions, and could be produced at lower CO2 emissions than petroleum based production.
Furthermore, a considerable portion of natural gas is found in regions that are remote from markets or pipelines. Most of this gas is flared, re-circulated back into oil reservoirs, or vented given its low economic value. The World Bank estimates flaring adds 400M metric tons of CO2 to the atmosphere each year as well as contributing to methane emissions. The nanowires of this disclosure also provide economic and environmental incentive to stop flaring. Also, the conversion of methane to fuel has several environmental advantages over petroleum-derived fuel. Natural gas is the cleanest of all fossil fuels, and it does not contain a number of impurities such as mercury and other heavy metals found in oil. Additionally, contaminants including sulfur are also easily separated from the initial natural gas stream. The resulting fuels burn much cleaner with no measurable toxic pollutants and provide lower emissions than conventional diesel and gasoline in use today.
In view of its wide range of applications, the nanowires of this disclosure can be used to not only selectively activate alkanes, but also to activate other classes of inert unreactive bonds, such as C—F, C—Cl or C—O bonds. This has importance, for example, in the destruction of man-made environmental toxins such as CFCs, PCBs, dioxins and other pollutants. Accordingly, while the invention is described in greater detail below in the context of the OCM reaction and other the other reactions described herein, the nanowire catalysts are not in any way limited to this particular reaction.
The selective, catalytic oxidative coupling of methane to ethylene (i.e. the OCM reaction) is shown by the following reaction (1):

2CH4+O2→CH2CH2+2H2O  (1)

This reaction is exothermic (Heat of Reaction −67 kcals/mole) and usually occurs at very high temperatures (>700° C.). During this reaction, it is believed that the methane (CH4) is first oxidatively coupled into ethane (C2H6), and subsequently the ethane (C2H6) is oxidatively dehydrogenated into ethylene (C2H4). Because of the high temperatures used in the reaction, it has been suggested that the ethane is produced mainly by the coupling in the gas phase of the surface-generated methyl (CH3) radicals. Reactive metal oxides (oxygen type ions) are apparently required for the activation of CH4 to produce the CH3 radicals. The yield of O2H4 and O2H6 is limited by further reactions in the gas phase and to some extent on the catalyst surface. A few of the possible reactions that occur during the oxidation of methane are shown below as reactions (2) through (8):

CH4→CH3 radical  (2)

CH3 radical→O2H6  (3)

CH3 radical+2.5O2→CO2+1.5H2O  (4)

C2H6→C2H4+H2  (5)

C2H6+0.5O2→C2H4+H2O  (6)

C2H4+3O2→2CO2+2H2O  (7)

CH3 radical+CxHy+O2→Higher HC's−Oxidation/CO2+H2O  (8)

With conventional heterogeneous catalysts and reactor systems, the reported performance is generally limited to <25% CH4 conversion at <80% combined O2 selectivity, with the performance characteristics of high selectivity at low conversion, or the low selectivity at high conversion. In contrast, the nanowires of this disclosure are highly active and can optionally operate at a much lower temperature. In one embodiment, the nanowires disclosed herein enable efficient conversion of methane to ethylene in the OCM reaction at temperatures less than when the corresponding bulk material is used as a catalyst. For example, in one embodiment, the nanowires disclosed herein enable efficient conversion (i.e., high yield, conversion, and/or selectivity) of methane to ethylene at temperatures of less than 900° C., less than 800° C., less than 700° C., less than 600° C., or less than 500° C. In other embodiments, the use of staged oxygen addition, designed heat management, rapid quench and/or advanced separations may also be employed.
Typically, the OCM reaction is run in a mixture of oxygen and nitrogen or other inert gas. Such gasses are expensive and increase the overall production costs associated with preparation of ethylene or ethane from methane. However, the present inventors have now discovered that such expensive gases are not required and high yield, conversion, selectivity, etc. can be obtained when air is used as the gas mixture instead of pre-packaged and purified sources of oxygen and other gases. Accordingly, in one embodiment the disclosure provides a method for performing the OCM reaction in air. In these embodiments, the catalyst
Accordingly, in one embodiment a stable, very active, high surface area, multifunctional nanowire catalyst is disclosed having active sites that are isolated and precisely engineered with the catalytically active metal centers/sites in the desired proximity (see, e.g., FIG. 1).
The exothermic heats of reaction (free energy) follows the order of reactions depicted above and, because of the proximity of the active sites, will mechanistically favor ethylene formation while minimizing complete oxidation reactions that form CO and CO2. Representative nanowire compositions useful for the OCM reaction include, but are not limited to: highly basic oxides selected from the early members of the Lanthanide oxide series; Group 1 or 2 ions supported on basic oxides, such as Li/MgO, Ba/MgO and Sr/La2O3; and single or mixed transition metal oxides, such as VOx and Re/Ru that may also contain Group 1 ions. Other nanowire compositions useful for the OCM reaction comprise any of the compositions disclosed herein, for example MgO, La2O3, Na2WO4, Mn2O3, Mn3O4, Mg6MnO8, Zr2Mo2O8, NaMnO4, Mn2O3/Na2WO4, Mn3O4/Na2WO4 or Na/MnO4/MgO, Mn/WO4, Nd2O3, Sm2O3, Eu2O3 or combinations thereof. Activating promoters (i.e., dopants), such as chlorides, nitrates and sulfates, or any of the dopants described above may also be employed.
As noted above, the OCM reaction employing known bulk catalysts suffers from poor yield, selectivity, or conversion. In contrast to a corresponding bulk catalyst, Applicants have found that certain nanowires, for example the exemplary nanowires disclosed herein, posses a catalytic activity in the OCM reaction such that the yield, selectivity, and/or conversion is better than when the OCM reaction is catalyzed by a corresponding bulk catalyst. In one embodiment, the disclosure provides a nanowire having a catalytic activity such that the conversion of methane to ethylene in the oxidative coupling of methane reaction is greater than at least 1.1 times, 1.25 times, 1.50 times, 2.0 times, 3.0 times, or 4.0 times the conversion of methane to ethylene compared to the same reaction under the same conditions but performed with a catalyst prepared from bulk material having the same chemical composition as the nanowire. In other embodiments, the conversion of methane to ethylene in an OCM reaction catalyzed by the nanowire is greater than 10%, greater than 20%, greater than 30%, greater than 50%, greater than 75%, or greater than 90%.
In another embodiment, the disclosure provides a nanowire having a catalytic activity such that the yield of ethylene in the oxidative coupling of methane reaction is greater than at least 1.1 times, 1.25 times, 1.50 times, 2.0 times, 3.0 times, or 4.0 times the yield of ethylene compared to the same reaction under the same conditions but performed with a catalyst prepared from bulk material having the same chemical composition as the nanowire. In some embodiments the yield of ethylene in an OCM reaction catalyzed by the nanowire is greater than 10%, greater than 20%, greater than 30%, greater than 50%, greater than 75%, or greater than 90%.
In another embodiment, the disclosure provides a nanowire having a catalytic activity in the OCM reaction such that the nanowire has the same catalytic activity, but at a lower temperature, compared a catalyst prepared from bulk material having the same chemical composition as the nanowire. In some embodiments the catalytic activity of the nanowires in the OCM reaction is the same as the catalytic activity of a catalyst prepared from bulk material having the same chemical composition as the nanowire, but at a temperature of at least 20° C. less. In some embodiments the catalytic activity of the nanowires in the OCM reaction is the same as the catalytic activity of a catalyst prepared from bulk material having the same chemical composition as the nanowire, but at a temperature of at least 50° C. less. In some embodiments the catalytic activity of the nanowires in the OCM reaction is the same as the catalytic activity of a catalyst prepared from bulk material having the same chemical composition as the nanowire, but at a temperature of at least 100° C. less. In some embodiments the catalytic activity of the nanowires in the OCM reaction is the same as the catalytic activity of a catalyst prepared from bulk material having the same chemical composition as the nanowire, but at a temperature of at least 200° C. less.
In another embodiment, the disclosure provides a nanowire having a catalytic activity such that the selectivity for CO or CO2 in the oxidative coupling of methane reaction is less than at least 0.9 times, 0.8 times, 0.5 times, 0.2 times, or 0.1 times the selectivity for CO or CO2 compared to the same reaction under the same conditions but performed with a catalyst prepared from bulk material having the same chemical composition as the nanowire.
In some other embodiments, a method for converting methane into ethylene comprising use of catalyst mixture comprising two or more catalysts is provided. For example, the catalyst mixture may be a mixture of a catalyst having good OCM activity and a catalyst having good ODH activity. Such catalyst mixture are described in more detail above.
2. Oxidative Dehydrogenation
Worldwide demand for alkenes, especially ethylene and propylene, is high. The main sources for alkenes include steam cracking, fluid-catalytic-cracking and catalytic dehydrogenation. The current industrial processes for producing alkenes, including ethylene and propylene, suffer from some of the same disadvantages described above for the OCM reaction. Accordingly, a process for the preparation of alkenes which is more energy efficient and has higher yield, selectivity, and conversion than current processes is needed. Applicants have now found that nanowires, for example the exemplary nanowires disclosed herein, fulfill this need and provide related advantages.
In one embodiment, the disclosed nanowires are useful as catalysts for the oxidative dehydrogenation (ODH) of hydrocarbons (e.g. alkanes, alkenes, and alkynes). For example, in one embodiment the nanowires are useful as catalysts in an ODH reaction for the conversion of ethane or propane to ethylene or propylene, respectively. Reaction scheme (9) depicts the oxidative dehydrogenation of hydrocarbons:

CxHy+1⁄2O2→CxHy-2+H2O  (9)

Representative catalysts useful for the ODH reaction include, but are not limited to nanowires comprising Zr, V, Mo, Ba, Nd, Ce, Ti, Mg, Nb, La, Sr, Sm, Cr, W, Y or Ca or oxides or combinations thereof. Activating promoters (i.e. dopants) comprising P, K, Ca, Ni, Cr, Nb, Mg, Au, Zn, or Mo, or combinations thereof, may also be employed.
As noted above, improvements to the yield, selectivity, and/or conversion in the ODH reaction employing bulk catalysts are needed. Accordingly, in one embodiment, the present disclosure provides a nanowire which posses a catalytic activity in the ODH reaction such that the yield, selectivity, and/or conversion is better than when the ODH reaction is catalyzed by a corresponding bulk catalyst. In one embodiment, the disclosure provides a nanowire having a catalytic activity such that the conversion of hydrocarbon to alkene in the ODH reaction is greater than at least 1.1 times, 1.25 times, 1.50 times, 2.0 times, 3.0 times, or 4.0 times the conversion of methane to ethylene compared to the same reaction under the same conditions but performed with a catalyst prepared from bulk material having the same chemical composition as the nanowire. In other embodiments, the conversion of hydrocarbon to alkene in an ODH reaction catalyzed by the nanowire is greater than 10%, greater than 20%, greater than 30%, greater than 50%, greater than 75%, or greater than 90%.
In another embodiment, the disclosure provides a nanowire having a catalytic activity such that the yield of alkene in an ODH reaction is greater than at least 1.1 times, 1.25 times, 1.50 times, 2.0 times, 3.0 times, or 4.0 times the yield of ethylene compared to the same reaction under the same conditions but performed with a catalyst prepared from bulk material having the same chemical composition as the nanowire. In some embodiments the yield of alkene in an ODH reaction catalyzed by the nanowire is greater than 10%, greater than 20%, greater than 30%, greater than 50%, greater than 75%, or greater than 90%.
In another embodiment, the disclosure provides a nanowire having a catalytic activity in the ODH reaction such that the nanowire has the same catalytic activity, but at a lower temperature, compared a catalyst prepared from bulk material having the same chemical composition as the nanowire. In some embodiments the catalytic activity of the nanowires in the ODH reaction is the same as the catalytic activity of a catalyst prepared from bulk material having the same chemical composition as the nanowire, but at a temperature of at least 20° C. less. In some embodiments the catalytic activity of the nanowires in the ODH reaction is the same as the catalytic activity of a catalyst prepared from bulk material having the same chemical composition as the nanowire, but at a temperature of at least 50° C. less. In some embodiments the catalytic activity of the nanowires in the ODH reaction is the same as the catalytic activity of a catalyst prepared from bulk material having the same chemical composition as the nanowire, but at a temperature of at least 100° C. less. In some embodiments the catalytic activity of the nanowires in the ODH reaction is the same as the catalytic activity of a catalyst prepared from bulk material having the same chemical composition as the nanowire, but at a temperature of at least 200° C. less.
In another embodiment, the disclosure provides a nanowire having a catalytic activity such that the selectivity for alkenes in an ODH reaction is greater than at least 1.1 times, 1.25 times, 1.50 times, 2.0 times, 3.0 times, or 4.0 times the selectivity for ethylene compared to the same reaction under the same conditions but performed with a catalyst prepared from bulk material having the same chemical composition as the nanowire. In other embodiments, the selectivity for alkenes in an ODH reaction catalyzed by the nanowire is greater than 10%, greater than 20%, greater than 30%, greater than 50%, greater than 75%, or greater than 90%.
In another embodiment, the disclosure provides a nanowire having a catalytic activity such that the selectivity for CO or CO2 in an ODH reaction is less than at least 0.9 times, 0.8 times, 0.5 times, 0.2 times, or 0.1 times the selectivity for CO or CO2 compared to the same reaction under the same conditions but performed with a catalyst prepared from bulk material having the same chemical composition as the nanowire.
In one embodiment, the nanowires disclosed herein enable efficient conversion of hydrocarbon to alkene in the ODH reaction at temperatures less than when the corresponding bulk material is used as a catalyst. For example, in one embodiment, the nanowires disclosed herein enable efficient conversion (i.e. high yield, conversion, and/or selectivity) of hydrocarbon to alkene at temperatures of less than 800° C., less than 700° C., less than 600° C., less than 500° C., less than 400° C., or less than 300° C.
3. Carbon Dioxide Reforming of Methane
Carbon dioxide reforming (CDR) of methane is an attractive process for converting CO2 in process streams or naturally occurring sources into the valuable chemical product, syngas (a mixture of hydrogen and carbon monoxide). Syngas can then be manufactured into a wide range of hydrocarbon products through processes such as the Fischer-Tropsch synthesis (discussed below) to form liquid fuels including methanol, ethanol, diesel, and gasoline. The result is a powerful technique to not only remove CO2 emissions but also create a new alternative source for fuels that are not derived from petroleum crude oil. The CDR reaction with methane is exemplified in reaction scheme (10).

CO2+CH4→2CO+2H2  (10)

Unfortunately, no established industrial technology for CDR exists today in spite of its tremendous potential value. While not wishing to be bound by theory, it is thought that the primary problem with CDR is due to side-reactions from catalyst deactivation induced by carbon deposition via the Boudouard reaction (reaction scheme (11)) and/or methane cracking (reaction scheme (12)) resulting from the high temperature reaction conditions. The occurrence of the coking effect is intimately related to the complex reaction mechanism, and the associated reaction kinetics of the catalysts employed in the reaction.

2CO→C+CO2  (11)

CH4→C+2H2  (12)

While not wishing to be bound by theory, the CDR reaction is thought to proceed through a multistep surface reaction mechanism. FIG. 9 schematically depicts a CDR reaction 700, in which activation and dissociation of CH4 occurs on the metal catalyst surface 710 to form intermediate “M-C”. At the same time, absorption and activation of CO2 takes place at the oxide support surface 720 to provide intermediate “S—CO2”, since the carbon in a CO2 molecule as a Lewis acid tends to react with the Lewis base center of an oxide. The final step is the reaction between the M-C species and the activated S—CO2 to form CO.
In one embodiment, the present disclosure provides nanowires, for example the exemplary nanowires disclosed herein, which are useful as catalysts for the carbon dioxide reforming of methane. For example, in one embodiment the nanowires are useful as catalysts in a CDR reaction for the production of syn gas.
Improvements to the yield, selectivity, and/or conversion in the CDR reaction employing bulk catalysts are needed. Accordingly, in one embodiment, the nanowires posses a catalytic activity in the CDR reaction such that the yield, selectivity, and/or conversion is better than when the CDR reaction is catalyzed by a corresponding bulk catalyst. In one embodiment, the disclosure provides a nanowire having a catalytic activity such that the conversion of CO2 to CO in the CDR reaction is greater than at least 1.1 times, 1.25 times, 1.50 times, 2.0 times, 3.0 times, or 4.0 times the conversion of CO2 to CO compared to the same reaction under the same conditions but performed with a catalyst prepared from bulk material having the same chemical composition as the nanowire. In other embodiments, the conversion of CO2 to CO in a CDR reaction catalyzed by the nanowire is greater than 10%, greater than 20%, greater than 30%, greater than 50%, greater than 75%, or greater than 90%.
In another embodiment, the disclosure provides a nanowire having a catalytic activity such that the yield of CO in a CDR reaction is greater than at least 1.1 times, 1.25 times, 1.50 times, 2.0 times, 3.0 times, or 4.0 times the yield of CO compared to the same reaction under the same conditions but performed with a catalyst prepared from bulk material having the same chemical composition as the nanowire. In some embodiments the yield of CO in a CDR reaction catalyzed by the nanowire is greater than 10%, greater than 20%, greater than 30%, greater than 50%, greater than 75%, or greater than 90%.
In another embodiment, the disclosure provides a nanowire having a catalytic activity in a CDR reaction such that the nanowire has the same catalytic activity, but at a lower temperature, compared a catalyst prepared from bulk material having the same chemical composition as the nanowire. In some embodiments the catalytic activity of the nanowires in a CDR reaction is the same as the catalytic activity of a catalyst prepared from bulk material having the same chemical composition as the nanowire, but at a temperature of at least 20° C. less. In some embodiments the catalytic activity of the nanowires in a CDR reaction is the same as the catalytic activity of a catalyst prepared from bulk material having the same chemical composition as the nanowire, but at a temperature of at least 50° C. less. In some embodiments the catalytic activity of the nanowires in a CDR reaction is the same as the catalytic activity of a catalyst prepared from bulk material having the same chemical composition as the nanowire, but at a temperature of at least 100° C. less. In some embodiments the catalytic activity of the nanowires in a CDR reaction is the same as the catalytic activity of a catalyst prepared from bulk material having the same chemical composition as the nanowire, but at a temperature of at least 200° C. less.
In another embodiment, the disclosure provides a nanowire having a catalytic activity such that the selectivity for CO in a CDR reaction is greater than at least 1.1 times, 1.25 times, 1.50 times, 2.0 times, 3.0 times, or 4.0 times the selectivity for CO compared to the same reaction under the same conditions but performed with a catalyst prepared from bulk material having the same chemical composition as the nanowire. In other embodiments, the selectivity for CO in a CDR reaction catalyzed by the nanowire is greater than 10%, greater than 20%, greater than 30%, greater than 50%, greater than 75%, or greater than 90%.
In one embodiment, the nanowires disclosed herein enable efficient conversion of CO2 to CO in the CDR reaction at temperatures less than when the corresponding bulk material is used as a catalyst. For example, in one embodiment, the nanowires enable efficient conversion (i.e., high yield, conversion, and/or selectivity) of CO2 to CO at temperatures of less than 900° C., less than 800° C., less than 700° C., less than 600° C., or less than 500° C.
4. Fischer-Tropsch Synthesis
Fischer-Tropsch synthesis (FTS) is a valuable process for converting synthesis gas (i.e., CO and H2) into valuable hydrocarbon fuels, for example, light alkenes, gasoline, diesel fuel, etc. FTS has the potential to reduce the current reliance on the petroleum reserve and take advantage of the abundance of coal and natural gas reserves. Current FTS processes suffer from poor yield, selectivity, conversion, catalyst deactivation, poor thermal efficiency and other related disadvantages. Production of alkanes via FTS is shown in reaction scheme (13), wherein n is an integer.

CO+2H2→(1/n)(CnH2n)+H2O  (13)

In one embodiment, nanowires are provided which are useful as catalysts in FTS processes. For example, in one embodiment the nanowires are useful as catalysts in a FTS process for the production of alkanes.
Improvements to the yield, selectivity, and/or conversion in FTS processes employing bulk catalysts are needed. Accordingly, in one embodiment, the nanowires posses a catalytic activity in an FTS process such that the yield, selectivity, and/or conversion is better than when the FTS process is catalyzed by a corresponding bulk catalyst. In one embodiment, the disclosure provides a nanowire having a catalytic activity such that the conversion of CO to alkane in an FTS process is greater than at least 1.1 times, 1.25 times, 1.50 times, 2.0 times, 3.0 times, or 4.0 times the conversion of CO to alkane compared to the same reaction under the same conditions but performed with a catalyst prepared from bulk material having the same chemical composition as the nanowire. In other embodiments, the conversion of CO to alkane in an FTS process catalyzed by the nanowire is greater than 10%, greater than 20%, greater than 30%, greater than 50%, greater than 75%, or greater than 90%.
In another embodiment, the disclosure provides a nanowire having a catalytic activity in an FTS process such that the nanowire has the same catalytic activity, but at a lower temperature, compared a catalyst prepared from bulk material having the same chemical composition as the nanowire. In some embodiments the catalytic activity of the nanowires in an FTS process is the same as the catalytic activity of a catalyst prepared from bulk material having the same chemical composition as the nanowire, but at a temperature of at least 20° C. less. In some embodiments the catalytic activity of the nanowires in an FTS process is the same as the catalytic activity of a catalyst prepared from bulk material having the same chemical composition as the nanowire, but at a temperature of at least 50° C. less. In some embodiments the catalytic activity of the nanowires in an FTS process is the same as the catalytic activity of a catalyst prepared from bulk material having the same chemical composition as the nanowire, but at a temperature of at least 100° C. less. In some embodiments the catalytic activity of the nanowires in an FTS process is the same as the catalytic activity of a catalyst prepared from bulk material having the same chemical composition as the nanowire, but at a temperature of at least 200° C. less.
In another embodiment, the disclosure provides a nanowire having a catalytic activity such that the yield of alkane in a FTS process is greater than at least 1.1 times, 1.25 times, 1.50 times, 2.0 times, 3.0 times, or 4.0 times the yield of alkane compared to the same reaction under the same conditions but performed with a catalyst prepared from bulk material having the same chemical composition as the nanowire. In some embodiments the yield of alkane in an FTS process catalyzed by the nanowire is greater than 10%, greater than 20%, greater than 30%, greater than 50%, greater than 75%, or greater than 90%.
In another embodiment, the disclosure provides a nanowire having a catalytic activity such that the selectivity for alkanes in an FTS process is greater than at least 1.1 times, 1.25 times, 1.50 times, 2.0 times, 3.0 times, or 4.0 times the selectivity for alkanes compared to the same reaction under the same conditions but performed with a catalyst prepared from bulk material having the same chemical composition as the nanowire. In other embodiments, the selectivity for alkanes in an FTS process catalyzed by the nanowire is greater than 10%, greater than 20%, greater than 30%, greater than 50%, greater than 75%, or greater than 90%.
In one embodiment, the nanowires disclosed herein enable efficient conversion of CO to alkanes in a CDR process at temperatures less than when the corresponding bulk material is used as a catalyst. For example, in one embodiment, the nanowires enable efficient conversion (i.e., high yield, conversion, and/or selectivity) of CO to alkanes at temperatures of less than 400° C., less than 300° C., less than 250° C., less than 200° C., less the 150° C., less than 100° C. or less than 50° C.
5. Oxidation of CO
Carbon monoxide (CO) is a toxic gas and can convert hemoglobin to carboxyhemoglobin resulting in asphyxiation. Dangerous levels of CO can be reduced by oxidation of C0 to CO2 as shown in reaction scheme 14:

CO+1⁄2O2→CO2  (14)

Catalysts for the conversion of CO into CO2 have been developed but improvements to the known catalysts are needed. Accordingly in one embodiment, the present disclosure provides nanowires useful as catalysts for the oxidation of CO to CO2.
In one embodiment, the nanowires posses a catalytic activity in a process for the conversion of CO into CO2 such that the yield, selectivity, and/or conversion is better than when the oxidation of CO into CO2 is catalyzed by a corresponding bulk catalyst. In one embodiment, the disclosure provides a nanowire having a catalytic activity such that the conversion of CO to CO2 is greater than at least 1.1 times, 1.25 times, 1.50 times, 2.0 times, 3.0 times, or 4.0 times the conversion of CO to CO2 compared to the same reaction under the same conditions but performed with a catalyst prepared from bulk material and having the same chemical composition as the nanowire. In other embodiments, the conversion of CO to CO2 catalyzed by the nanowire is greater than 10%, greater than 20%, greater than 30%, greater than 50%, greater than 75%, or greater than 90%.
In another embodiment, the disclosure provides a nanowire having a catalytic activity such that the yield of CO2 from the oxidation of CO is greater than at least 1.1 times, 1.25 times, 1.50 times, 2.0 times, 3.0 times, or 4.0 times the yield of CO2 compared to the same reaction under the same conditions but performed with a catalyst prepared from bulk material having the same chemical composition as the nanowire. In some embodiments the yield of CO2 from the oxidation of CO catalyzed by the nanowire is greater than 10%, greater than 20%, greater than 30%, greater than 50%, greater than 75%, or greater than 90%.
In another embodiment, the disclosure provides a nanowire having a catalytic activity in an oxidation of CO reaction such that the nanowire has the same catalytic activity, but at a lower temperature, compared a catalyst prepared from bulk material having the same chemical composition as the nanowire. In some embodiments the catalytic activity of the nanowires in an oxidation of CO reaction is the same as the catalytic activity of a catalyst prepared from bulk material having the same chemical composition as the nanowire, but at a temperature of at least 20° C. less. In some embodiments the catalytic activity of the nanowires in an oxidation of CO reaction is the same as the catalytic activity of a catalyst prepared from bulk material having the same chemical composition as the nanowire, but at a temperature of at least 50° C. less. In some embodiments the catalytic activity of the nanowires in an oxidation of CO reaction is the same as the catalytic activity of a catalyst prepared from bulk material having the same chemical composition as the nanowire, but at a temperature of at least 100° C. less. In some embodiments the catalytic activity of the nanowires in an oxidation of CO reaction is the same as the catalytic activity of a catalyst prepared from bulk material having the same chemical composition as the nanowire, but at a temperature of at least 200° C. less.
In another embodiment, the disclosure provides a nanowire having a catalytic activity such that the selectivity for CO2 in the oxidation of CO is greater than at least 1.1 times, 1.25 times, 1.50 times, 2.0 times, 3.0 times, or 4.0 times the selectivity for CO2 compared to the same reaction under the same conditions but performed with a catalyst prepared from bulk material having the same chemical composition as the nanowire. In other embodiments, the selectivity for CO2 in the oxidation of CO catalyzed by the nanowire is greater than 10%, greater than 20%, greater than 30%, greater than 50%, greater than 75%, or greater than 90%.
In one embodiment, the nanowires disclosed herein enable efficient conversion of CO to CO2 at temperatures less than when the corresponding bulk material is used as a catalyst. For example, in one embodiment, the nanowires enable efficient conversion (i.e., high yield, conversion, and/or selectivity) of CO to CO2 at temperatures of less than 500° C., less than 400° C., less than 300° C., less than 200° C., less than 100° C., less than 50° C. or less than 20° C.
Although various reactions have been described in detail, the disclosed nanowires are useful as catalysts in a variety of other reactions. In general, the disclosed nanowires find utility in any reaction utilizing a heterogeneous catalyst and have a catalytic activity such that the yield, conversion, and/or selectivity in reaction catalyzed by the nanowires is better than the yield, conversion and/or selectivity in the same reaction catalyzed by a corresponding bulk catalyst.
6. Combustion of Hydrocarbons
In another embodiment, the present disclosure provides a nanowire having catalytic activity in a reaction for the catalyzed combustion of hydrocarbons. Such catalytic reactions find utility in catalytic converters for automobiles, for example by sooth reduction on diesel engines by catalytically burn unused hydrocarbons emitted from the engine when it's running “cold” and thus the engine efficiency in burning hydrocarbons is not very good. When running “cold”, the exhausts of a diesel engine are quite low, thus a low temperature, such as the disclosed nanowires, catalyst is needed to efficiently eliminate all unburned hydrocarbons.
In contrast to a corresponding bulk catalyst, Applicants have found that certain nanowires, for example the exemplary nanowires disclosed herein, posses a catalytic activity in the combustion of hydrocarbons such that the yield, selectivity, and/or conversion is better than when the combustion of hydrocarbons is catalyzed by a corresponding bulk catalyst. In one embodiment, the disclosure provides a nanowire having a catalytic activity such that the combustion of hydrocarbons is greater than at least 1.1 times, 1.25 times, 1.50 times, 2.0 times, 3.0 times, or 4.0 times the combustion of hydrocarbons compared to the same reaction under the same conditions but performed with a catalyst prepared from bulk material having the same chemical composition as the nanowire. In other embodiments, the total combustion of hydrocarbons catalyzed by the nanowire is greater than 10%, greater than 20%, greater than 30%, greater than 50%, greater than 75%, or greater than 90%.
In another embodiment, the disclosure provides a nanowire having a catalytic activity such that the yield of combusted hydrocarbon products is greater than at least 1.1 times, 1.25 times, 1.50 times, 2.0 times, 3.0 times, or 4.0 times the yield of combusted hydrocarbon products compared to the same reaction under the same conditions but performed with a catalyst prepared from bulk material having the same chemical composition as the nanowire. In some embodiments the yield of combusted hydrocarbon products in a reaction catalyzed by the nanowire is greater than 10%, greater than 20%, greater than 30%, greater than 50%, greater than 75%, or greater than 90%.
In another embodiment, the disclosure provides a nanowire having a catalytic activity in the combustion of hydrocarbons such that the nanowire has the same catalytic activity, but at a lower temperature, compared a catalyst prepared from bulk material having the same chemical composition as the nanowire. In some embodiments the catalytic activity of the nanowires in the combustion of hydrocarbons is the same as the catalytic activity of a catalyst prepared from bulk material having the same chemical composition as the nanowire, but at a temperature of at least 20° C. less. In some embodiments the catalytic activity of the nanowires in the combustion of hydrocarbons is the same as the catalytic activity of a catalyst prepared from bulk material having the same chemical composition as the nanowire, but at a temperature of at least 50° C. less. In some embodiments the catalytic activity of the nanowires in the combustion of hydrocarbons is the same as the catalytic activity of a catalyst prepared from bulk material having the same chemical composition as the nanowire, but at a temperature of at least 100° C. less. In some embodiments the catalytic activity of the nanowires in the combustion of hydrocarbons is the same as the catalytic activity of a catalyst prepared from bulk material having the same chemical composition as the nanowire, but at a temperature of at least 200° C. less.
7. Evaluation of Catalytic Properties
To evaluate the catalytic properties of the nanowires in a given reaction, for example those reactions discussed above, various methods can be employed to collect and process data including measurements of the kinetics and amounts of reactants consumed and the products formed. In addition to allowing for the evaluation of the catalytic performances, the data can also aid in designing large scale reactors, experimentally validating models and optimizing the catalytic process.
One exemplary methodology for collecting and processing data is depicted in FIG. 10. Three main steps are involved. The first step (block 750) comprises the selection of a reaction and catalyst. This influences the choice of reactor and how it is operated, including batch, flow, etc. (block 754). Thereafter, the data of the reaction are compiled and analyzed (block 760) to provide insights to the mechanism, rates and process optimization of the catalytic reaction. In addition, the data provide useful feed backs for further design modifications of the reaction conditions. Additional methods for evaluating catalytic performance in the laboratory and industrial settings are described in, for example, Bartholomew, C. H. et al. Fundamentals of Industrial Catalytic Processes, Wiley-AIChE; 2Ed (1998).
As an example, in a laboratory setting, an Altamira Benchcat 200 can be employed using a 4 mm ID diameter quartz tube with a 0.5 mm ID capillary downstream. Quartz tubes with 2 mm or 6 mm ID can also be used. Nanowires are tested in a number of different dilutions and amounts. In some embodiments, the range of testing is between 10 and 300 mg. In some embodiments, the nanowires are diluted with a non-reactive diluent. This diluent can be quartz (SiO2) or other inorganic materials which are known to be inert in the reaction condition. The purpose of the diluent is to minimize hot spots and provide an appropriate loading into the reactor. In addition, the catalyst can be blended with less catalytically active components as described in more detail above.
In a typical procedure, 100 mg is the total charge of nanowire, optionally including diluent. On either side of the nanowires a small plug of glass wool is loaded to keep the nanowires in place. A thermocouple is placed on the inlet side of the nanowire bed into the glass wool to get the temperature in the reaction zone. Another thermocouple can be placed on the downstream end of the nanowire bed into the catalyst bed itself to measure the exotherms, if any.
When blending the pure nanowire with diluent, the following exemplary procedure may be used: x (usually 10-50) mg of the catalyst (either bulk or test nanowire catalyst) is blended with (100-x) mg of quartz (SiO2). Thereafter, about 2 ml of ethanol or water is added to form a slurry mixture, which is then sonicated for about 10 minutes. The slurry is then dried in an oven at about 100-140° C. for 2 hours to remove solvent. The resulting solid mixture is then scraped out and loaded into the reactor between the plugs of quartz wool.
Once loaded into the reactor, the reactor is inserted into the Altamira instrument and furnace and then a temperature and flow program is started. In some embodiment, the total flow is 50 to 100 sccm of gases but this can be varied and programmed with time. In one embodiment, the temperatures range from 450° C. to 900° C. The reactant gases comprise air or oxygen (diluted with nitrogen or argon) and methane in the case of the OCM reaction and gas mixtures comprising ethane and/or propane with oxygen for oxidative dehydrogenation (ODH) reactions. Other gas mixtures can be used for other reactions.
The primary analysis of these oxidation catalysis runs is the Gas Chromatography (GC) analysis of the feed and effluent gases. From these analyses, the conversion of the oxygen and alkane feed gases can easily be attained and estimates of yields and selectivities of the products and by-products can be determined.
The GC method developed for these experiments employs 4 columns and 2 detectors and a complex valve switching system to optimize the analysis. Specifically, a flame ionization detector (FID) is used for the analysis of the hydrocarbons only. It is a highly sensitive detector that produces accurate and repeatable analysis of methane, ethane, ethylene, propane, propylene and all other simple alkanes and alkenes up to five carbons in length and down to ppm levels.
There are two columns in series to perform this analysis, the first is a stripper column (alumina) which traps polar materials (including the water by-product and any oxygenates generated) until back-flushed later in the cycle. The second column associated with the FID is a capillary alumina column known as a PLOT column which performs the actual separation of the light hydrocarbons. The water and oxygenates are not analyzed in this method.
For the analysis of the light non-hydrocarbon gases, a Thermal Conductivity Detector (TCD) may be employed which also employees two columns to accomplish its analysis. The target molecules for this analysis are CO2, ethylene, ethane, hydrogen, oxygen, nitrogen, methane and CO. The two columns used here are a porous polymer column known as the Hayes Sep N which performs some of the separation for the CO2, ethylene and ethane. The second column is a molecular sieve column which uses size differentiation to perform the separation. It is responsible for the separation of H2, O2, N2, methane and CO.
There is a sophisticated and timing sensitive switching between these two columns in the method. In the first 2 minutes or so, the two columns are operating in series but at about 2 minutes, the molecular sieve column is by-passed and the separation of the first 3 components is completed. At about 5-7 minutes, the columns are then placed back in series and the light gases come off of the sieve according to their molecular size.
The end result is an accurate analysis of all of the aforementioned components from these fixed-bed, gas phase reactions. Analysis of other reactions and gases not specifically described above can be performed in a similar manner.
8. Downstream Products
As noted above, in one embodiment the present disclosure is directed to nanowires useful as catalysts in reactions for the preparation of a number of valuable hydrocarbon compounds. For example, in one embodiment the nanowires are useful as catalysts for the preparation of ethylene from methane via the OCM reaction. In another embodiment, the nanowires are useful as catalysts for the preparation of ethylene or propylene via oxidative dehydrogenation of ethane or propane, respectively. Ethylene and propylene are valuable compounds which can be converted into a variety of consumer products. For example, as shown in FIG. 11, ethylene can be converted into many various compounds including low density polyethylene, high density polyethylene, ethylene dichloride, ethylene oxide, ethylbenzene, linear alcohols, vinyl acetate, alkanes, alpha olefins, various hydrocarbon-based fuels, ethanol and the like. These compounds can then be further processed using methods well known to one of ordinary skill in the art to obtain other valuable chemicals and consumer products (e.g. the downstream products shown in FIG. 11). Propylene can be analogously converted into various compounds and consumer goods including polypropylenes, propylene oxides, propanol, and the like.
Accordingly, in one embodiment the disclosure provides a method of preparing the downstream products of ethylene noted in FIG. 11. The method comprises converting ethylene into a downstream product of ethylene, wherein the ethylene has been prepared via a catalytic reaction employing a nanowire, for example any of the nanowires disclosed herein. In another embodiment the disclosure provides a method of preparing low density polyethylene, high density polyethylene, ethylene dichloride, ethylene oxide, ethylbenzene, ethanol or vinyl acetate from ethylene, wherein the ethylene has been prepared as described above.
In another embodiment, the disclosure provides a method of preparing a product comprising low density polyethylene, high density polyethylene, ethylene dichloride, ethylene oxide, ethylbenzene, ethanol or vinyl acetate, alkenes, alkanes, aromatics, alcohols, or mixtures thereof. The method comprises converting ethylene into low density polyethylene, high density polyethylene, ethylene dichloride, ethylene oxide, ethylbenzene, ethanol or vinyl acetate, wherein the ethylene has been prepared via a catalytic reaction employing a nanowires, for example any of the exemplary nanowires disclosed herein.
In more specific embodiments of any of the above methods, the ethylene is produced via an OCM or ODH reaction.
In one particular embodiment, the disclosure provides a method of preparing a downstream product of ethylene and/or ethane, wherein the downstream product is a hydrocarbon fuel. For example, the downstream product of ethylene may be a C4-C14 hydrocarbon, including alkanes, alkenes and aromatics. Some specific examples include 1-butene, 1-hexene, 1-octene, xylenes and the like. The method comprises converting methane into ethylene, ethane or combinations thereof by use of a catalytic nanowire, for example any of the catalytic nanowires disclosed herein, and further oligomerizing the ethylene and/or ethane to prepare a downstream product of ethylene and/or ethane. For example, the methane may be converted to ethylene, ethane or combinations thereof via the OCM reaction as discussed above. The catalytic nanowire may be any nanowire and is not limited with respect to morphology or composition. The catalytic nanowire may be an inorganic catalytic polycrystalline nanowire, the nanowire having a ratio of effective length to actual length of less than one and an aspect ratio of greater than ten as measured by TEM in bright field mode at 5 keV, wherein the nanowire comprises one or more elements from any of Groups 1 through 7, lanthanides, actinides or combinations thereof. Alternatively, the catalytic nanowire may be an inorganic nanowire comprising one or more metal elements from any of Groups 1 through 7, lanthanides, actinides or combinations thereof and a dopant comprising a metal element, a semi-metal element, a non-metal element or combinations thereof. The nanowires may additionally comprise any number of doping elements as discussed above.
As depicted in FIG. 21, the method begins with charging methane (e.g., as a component in natural gas) into an OCM reactor. The OCM reaction may then be performed utilizing a nanowire under any variety of conditions. Water and CO2 are optionally removed from the effluent and unreacted methane is recirculated to the OCM reactor.
Ethylene is recovered and charged to an oligomerization reactor. Optionally the ethylene stream may contain CO2, H2O, N2, ethane, C3's and/or higher hydrocarbons. Oligomerization to higher hydrocarbons (e.g., C4-C14) then proceeds under any number of conditions known to those of skill in the art. For example oligomerization may be effected by use of any number of catalysts known to those skilled in the art. Examples of such catalysts include catalytic zeolites, crystalline borosilicate molecular sieves, homogeneous metal halide catalysts, Cr catalysts with pyrrole ligands or other catalysts. Exemplary methods for the conversion of ethylene into higher hydrocarbon products are disclosed in the following references: Catalysis Science & Technology (2011), 1(1), 69-75; Coordination Chemistry Reviews (2011), 255(7-8), 861-880; Eur. Pat. Appl. (2011), EP 2287142 A1 20110223; Organometallics (2011), 30(5), 935-941; Designed Monomers and Polymers (2011), 14(1), 1-23; Journal of Organometallic Chemistry 689 (2004) 3641-3668; Chemistry—A European Journal (2010), 16(26), 7670-7676; Acc. Chem. Res. 2005, 38, 784-793; Journal of Organometallic Chemistry, 695 (10-11): 1541-1549 May 15, 2010; Catalysis Today Volume 6, Issue 3, January 1990, Pages 329-349; U.S. Pat. No. 5,968,866; U.S. Pat. No. 6,800,702; U.S. Pat. No. 6,521,806; U.S. Pat. No. 7,829,749; U.S. Pat. No. 7,867,938; U.S. Pat. No. 7,910,670; U.S. Pat. No. 7,414,006 and Chem. Commun., 2002, 858-859, each of which are hereby incorporated in their entirety by reference.
In certain embodiments, the exemplary OCM and oligomerization modules depicted in FIG. 21 may be adapted to be at the site of natural gas production, for example a natural gas field. Thus the natural gas can be efficiently converted to more valuable and readily transportable hydrocarbon commodities without the need for transport of the natural gas to a processing facility.
Referring to FIG. 21, “natural gasoline” refers to a mixture of oligomerized ethylene products. The mixture may comprise 1-hexene, 1-octene, linear, branched or cyclic alkanes of 6 or more hydrocarbons, linear, branched, or cyclic alkenes of 6 or more hydrocarbons, aromatics, such as benzene, toluene, dimethyl benzene, xylenes, napthalene, or other oligomerized ethylene products and combinations thereof. This mixture finds particular utility in any number of industrial applications, for example natural gasoline is used as feedstock in oil refineries, as fuel blend stock by operators of fuel terminals, as diluents for heavy oils in oil pipelines and other applications. Other uses for natural gasoline are well-known to those of skill in the art.
EXAMPLES
Example 1
Genetic Engineering/Preparation of Phage
Phage were amplified in DH5 derivative E. coli (New England Biolabs, NEB5-alpha F′ lq; genotype: F′ proA+B+laclq Δ(lacZ)M15 zzf::Tn10 (TetR)/fhuA2Δ(argF-lacZ)U169 phoA glnV44 φ80Δ(lacZ)M15 gyrA96 recA1 endA1 thi-1 hsdR17) and purified using standard polyethylene glycol and sodium chloride precipitation protocols as described in the following references: Kay, B. K.; Winter, J.; McCafferty, J. Phage Display of Peptides and Proteins: A Laboratory Manual; Academic Press: San Diego (1996); C. F. Barbas, et al., ed., Phage Display: A Laboratory Manual; Cold Spring Harbor Laboratory Press, Cold Spring Harbor, N.Y., USA (2001); and Joseph Sambrook and David W. Russell, Molecular Cloning, 3rd edition, Cold Spring Harbor Laboratory Press, Cold Spring Harbor, N.Y., USA, 2001.
Example 2
Preparation of Phage Solutions
The phage solutions were additionally purified by centrifuging at an acceleration of 10000 g at least once (until no precipitated material was observed), decanting the supernatant and splitting it in 50 ml containers, which were then stored frozen at −20° C. The frozen phage solutions were thawed only shortly before being used.
The concentration of the phage solutions was measured using a UV-VIS spectrometer. The concentration of each of the frozen phage aliquots was measured prior to use. This spectroscopic method relies on the absorption of the nucleotides in the DNA of the phage and is described in more detail in “Phage Display: A Laboratory Manual” by Barbas, Burton, Scott and Silverman (Cold Spring Harbor Laboratory Press, 2001). The concentration of phage solutions is expressed in pfu/ml (plague forming units per milliliter).
Example 3
Preparation Mg(OH)2 Nanowires
FIG. 12 shows a generic reaction scheme for preparing MgO nanowires (with dopant). First, the phage solution is thawed and its concentration determined according to the method described above. The phage solution is diluted with water to adjust its concentration in the reaction mixture (i.e. with all the ingredients added) to the desired value, typically 5e12 pfu/ml or higher. The reaction container can be anything from a small vial (for milliliter scale reactions) up to large bottles (for liter reaction scale reactions).
A magnesium solution and a base solution are added to the phage solution in order to precipitate Mg(OH)2. The magnesium solution can be of any soluble magnesium salt, e.g. MgX2.6H2O (X═Cl, Br, I), Mg(NO3)2, MgSO4, magnesium acetate, etc. The range of the magnesium concentration in the reaction mixture is quite narrow, typically at 0.01M. The combination of the phage concentration and the magnesium concentration (i.e. the ratio between the pVIII proteins and magnesium ions) is very important in determining both the nanowires formation process window and their morphology.
The base can be any alkali metal hydroxide (e.g. LiOH, NaOH, KOH), soluble alkaline earth metal hydroxide (e.g. Sr(OH)2, Ba(OH)2) or any ammonium hydroxide (e.g., NR4OH, R═H, CH3, C2H5, etc.). Certain selection criteria for the base include: adequate solubility (at least several orders of magnitude higher than Mg(OH)2 for Mg(OH)2 nanowires), high enough strength (pH of the reaction mixture should be at least 11) and an inability to coordinate magnesium (for Mg(OH)2 nanowires) to form soluble products. LiOH is a preferred choice for Mg(OH)2 nanowires formation because lithium may additionally be incorporated in the Mg(OH)2 as a dopant, providing a Li/MgO doped catalyst for OCM.
Another factor concerning the base is the amount of base used or the concentration ratio of OH−/Mg2+, i.e. the ratio between the number of OH equivalents added and the number of moles of Mg added. In order to fully convert the Mg ions in solution to Mg(OH)2, the OH/Mg ratio needed is 2. The OH−/Mg2+ used in the formation of Mg(OH)2 nanowires ranges from 0.5 to 2 and, depending on this ratio, the morphology of the reaction product changes from thin nanowires to agglomerations of nanoparticles. The OH−/Mg2+ ratio is determined by the pH of the reaction mixture, which needs to be at least 11. If the pH is below 11, no precipitation is observed, i.e. no Mg(OH)2 is formed. If the pH is above 12, the morphology of the nanowires begins to change and more nanoparticles are obtained, i.e. non-selective precipitation.
Considering the narrow window of magnesium concentration in which
Mg(OH)2 nanowires can be obtained, the other key synthetic parameters that determine the nanowires formation and morphology include but are not limited to: phage sequence and concentration thereof, the concentration ratio of Mg2+/pVIII protein, the concentration ratio of OH−/Mg2+, the incubation time of phage and Mg2+; incubation time of phage and the OH−; the sequence of adding anion and metal ions; pH; the solution temperature in the incubation step and/or growth step; the types of metal precursor salt (e.g., MgCl2 or Mg(NO3)2); the types of anion precursor (e.g., NaOH or LiOH); the number of additions; the time that lapses between the additions of the metal salt and anion precursor, including, e.g., simultaneous (zero lapse) or sequential additions.
The Mg salt solution and the base were added sequentially, separated by an incubation time (i.e., the first incubation time). The sequence of addition has an effect on the morphology of the nanowires. The first incubation time can be at least 1 h and it should be longer in the case the magnesium salt solution is added first. The Mg salt solution and the base can be added in a single “shot” or in a continuous slow flow using a syringe pump or in multiple small shots using a liquid dispenser robot. The reaction is then carried either unstirred or with only mild to moderate stirring for a specific time (i.e., the second incubation time). The second incubation time is not as strong a factor in the synthesis of Mg(OH)2 nanowires, but it should be long enough for the nanowires to precipitate out of the reaction solution (e.g., several minutes). For practical reasons, the second incubation time can be as long as several hours. The reaction temperature can be anything from just above freezing temperature (e.g., 4° C.) up to 80° C. The temperature affects the nanowires morphology.
The precipitated Mg(OH)2 nanowires are isolated by centrifuging the reaction mixture and decanting the supernatant. The precipitated material is then washed at least once with a water solution with pH>10 to avoid redissolution of the Mg(OH)2 nanowires. Typically, the washing solution used can be ammonium hydroxide water solution or an alkali metal hydroxide solution (e.g., LiOH, NaOH, KOH). This mixture is centrifuged and the supernatant decanted. Finally, the product can be either dried (see, Example 5) or resuspended in ethanol for TEM analysis.
The decanted supernatant of the reaction mixture can be analyzed by UV-VIS to determine the phage concentration (see, Example 2) and thus give an estimate of the amount of phage incorporated in the precipitated Mg(OH)2, i.e. the amount of “mineralized” phage.
FIG. 12 depicts one embodiment for preparing Mg(OH)2 nanowires. In a different embodiment, the order of addition may be reversed, for example in an exemplary 4 ml scale synthesis of Mg(OH)2 nanowires, 3.94 ml of concentrated solution of phages (e.g., SEQ ID NO: 3 at a concentration of  ̃5E12 pfu/ml) were mixed in a 8 ml vial with 0.02 ml of 1 M LiOH aqueous solution and left incubating overnight ( ̃15 h). 0.04 ml of 1 M MgCl2 aqueous solution were then added using a pipette and the mixture was mixed by gentle shaking. The reaction mixture was left incubating unstirred for 24 h. After the incubation time, the mixture was centrifuged, and the supernatant was decanted and saved for phage concentration measurement by UV-VIS. The precipitated material was resuspended in 2 ml of 0.001 M LiOH aqueous solution (pH=11), the mixture was centrifuged and the supernatant decanted. The obtained Mg(OH)2 nanowires were characterized by TEM as described in Example 4.
Example 4
Characterization of Mg(OH)2 Nanowires
Mg(OH)2 nanowires prepared according to Example 3 were characterized by TEM in order to determine their morphology. First, a few microliters ( ̃500) of ethanol was used to suspend the isolated Mg(OH)2. The nanowires were then deposited on a TEM grid (copper grid with a very thin carbon layer) placed on filter paper to help wick out any extra liquid. After allowing the ethanol to dry, the TEM grid was loaded in a TEM and characterized. TEM was carried out at 5 KeV in bright field mode in a DeLong LVEM5.
The nanowires were additionally characterized by XRD (for phase identification) and TGA (for calcination optimization).
Example 5
Calcination of Mg(OH)2 Nanowires
The isolated nanowires as prepared in Example 3 were dried in an oven at relatively low temperature (60-120° C.) prior to calcination.
The dried material was placed in a ceramic boat and calcined in air at 450° C. in order to convert the Mg(OH)2 nanowires into MgO nanowires. The calcination recipe can be varied considerably. For example, the calcination can be done relatively quickly like in these two examples:

    
    
        load in a muffle oven preheated at 450° C., calcination time=120 min
        load in a muffle oven (or tube furnace) at room temperature and ramp to 450° C. with 5° C./min rate, calcination time=60 min
    
    


Alternatively, the calcination can be done in steps that are chosen according to the TGA signals like in the following example:

    
    
        load in a muffle oven (or tube furnace) at room temperature, ramp to 100° C. with 2° C./min rate, dwell for 60 min, ramp to 280° C. with 2° C./min rate, dwell for 60 min, ramp to 350° C. with 2° C./min rate, dwell for 60 min and finally ramp to 450° C. with 2° C./min rate, dwell for 60 min.
    
    


Generally, a step recipe is preferable since it should allow for a better, smoother and more complete conversion of Mg(OH)2 into MgO. Optionally, the calcined product is ground into a fine powder.
FIG. 13 shows the X-ray diffraction patterns of the Mg(OH2) nanowires and the MgO nanowires following calcinations. Crystalline structures of both types of nanowires were confirmed.
Example 6
Preparation of Li Doped MgO Nanowires
Doping of nanowires is achieved by using the incipient wetness impregnation method. Before impregnating the MgO nanowires with the doping solution, the maximum wettability (i.e. the ability of the nanowires to absorb the doping solution before becoming a suspension or before “free” liquid is observed) of the nanowires was determined. This is a very important step for an accurate absorption of the doping metal on the MgO surface. If too much dopant solution is added and a suspension is formed, a significant amount of dopant will crystallize unabsorbed upon drying and if not enough dopant solution is added, significant portions of the MgO surface will not be doped.
In order to determine the maximum wettability of the MgO nanowires, small portions of water were dropped on the calcined MgO powder until a suspension was formed, i.e. until “free” liquid is observed. The maximum wettability was determined to be the total amount of water added before the suspension formed. The concentration of the doping solution was then calculated so that the desired amount of dopant was contained in the volume of doping solution corresponding to the maximum wettability of the MgO nanowires. In another way to describe the incipient wetness impregnation method, the volume of the doping solution is set to be equal to the pore volume of the nanowires, which can be determined by BET (Brunauer, Emmett, Teller) measurements. The doping solution is then drawn into the pores by capillary action.
In one embodiment, the doping metal for MgO based catalysts for OCM is lithium (see, also, FIG. 12). Thus, in one embodiment the dopant source can be any soluble lithium salt as long as it does not introduce undesired contaminants. Typically, the lithium salts used were LiNO3, LiOH or Li2CO3. LiNO3 and LiOH are preferred because of their higher solubility. In one embodiment, the lithium content in MgO catalysts for OCM ranges from 0 to 10 wt % (i.e. about 0 to 56 at %).
The calculated amount of dopant solution of the desired concentration was dropped onto the calcined MgO nanowires. The obtained wet powder was dried in an oven at relatively low temperature (60-120° C.) and calcined using one of the recipes described above. It is noted that, during this step, no phase transition occurs (MgO has already been formed in the previous calcination step) and thus a step recipe (see previous paragraph) may not be necessary.
The dopant impregnation step can also be done prior to the calcination, after drying the Mg(OH)2 nanowires isolated from the reaction mixture. In this case, the catalyst can be calcined immediately after the dopant impregnation, i.e. no drying and second calcination steps would be required since its goals are accomplished during the calcination step.
Three identical synthesis were made in parallel. In each synthesis, 80 ml of concentrated solution of phages (SEQ ID NO: 3 at a concentration of 5E12 pfu/ml) were mixed in a 100 ml glass bottle with 0.4 ml of 1 M LiOH aqueous solution and left incubating for 1 h. 0.8 ml of 1 M MgCl2 aqueous solution were added using a pipette and the mixture was mixed by gently shaking it. The reaction mixture was left incubating unstirred for 72 h at 60° C. in an oven. After the incubation time, the mixture was centrifuged. The precipitated material was resuspended in 20 ml of 0.06 M NH4OH aqueous solution (pH=11), the mixture was centrifuged and the supernatant decanted. The obtained Mg(OH)2 nanowires were resuspended in ethanol. The ethanol suspensions of the three identical syntheses were combined and a few microliters of the ethanol suspension were used for TEM analysis. The ethanol suspension was centrifuged and the supernatant decanted. The gel-like product was transferred in a ceramic boat and dried for 1 h at 120° C. in a vacuum oven.
The dried product was calcined in a tube furnace using a step recipe (load in the furnace at room temperature, ramp to 100° C. with 2° C./min rate, dwell for 60 min, ramp to 280° C. with 2° C./min rate, dwell for 60 min, ramp to 350° C. with 2° C./min rate, dwell for 60 min, ramp to 450° C. with 2° C./min rate, dwell for 60 min and finally cool to room temperature). The yield was 24 mg. The calcined product was ground to a fine powder.
10 mg of the calcined product were impregnated with a LiOH aqueous solution. First, the maximum wettability was determined by adding water to the calcined product in a ceramic boat until the powder was saturated but no “free” liquid was observed. The maximum wettability was 12 μl. Since the target doping level was 1 wt % lithium, the necessary concentration of the LiOH aqueous solution was calculated to be 1.2 M. The calcined product was dried again for 1 h at 120° C. to remove the water used to determine the wettability of the powder. 12 μl of the 1.2 M LiOH solution were dropped on the MgO nanowires powder. The wet powder was dried for 1 h at 120° C. in a vacuum oven and finally calcined in a muffle oven (load at room temperature, ramp to 460° C. with 2° C./min ramp, dwell for 120 min).
Example 7
Creating Diversity by Varying the Reaction Parameters
Certain synthetic parameters strongly influence the nanowire formation on phage, including selective binding of metal and/or anions, as well as surface morphologies. FIG. 14 shows a number of MgO nanowires synthesized in the presence of different phage sequence (e.g., different pVIII) while keeping the other reaction conditions constant. Phages of SEQ ID NOs. 1, 7, 10, 11, 13 and 14 were the respective phage of choice in six reactions carried out in otherwise identical conditions. The constant reaction conditions may include: concentration ratios of Mg2+ and active functional groups on the phage; concentration ratios of OH−/Mg2+; incubation time of phage and Mg2+; incubation time of phage and OH−; concentration of phage; sequence of adding anion and metal ions; solution temperature in the incubation step and/or growth step; etc. As shown, the morphologies of MgO nanowires are significantly influenced by the phage sequences.
Thus, varying these and other reaction conditions may produce a diverse class of nanowire catalysts. In addition, certain correlation between the reaction conditions and the surface morphologies of the nanowires can be empirically established, thus enabling rational designs of catalytic nanowires.
Example 8
Preparation of Sr-Doped La2O3 Nanowires
23 ml of 2.5 e12 pfu solution of phages (SEQ ID NO: 3) was mixed in a 40 ml glass bottle with 0.046 ml of 0.1 M LaCl3 aqueous solution and left incubating for 16 h. After this incubation period, a slow multistep addition is conducted with 1.15 ml of 0.05 M LaCl3 solution and 1.84 ml of 0.3 M NH4OH. This addition is conducted in six hours and twenty steps. The reaction mixture was left stirred another 2 h at room temperature. After that time the suspension was centrifuged in order to separate the solid phase from the liquid phase. The precipitated material was then resuspended in 5 ml of water and centrifuged in order to further remove un-reacted species. A final wash was conducted with 2 ml ethanol. The gel-like product remaining is then dried for 30 minutes at 110° C. in a vacuum oven.
The dried product was then calcined in a muffle furnace using a step recipe (load in the furnace at room temperature, ramp to 200° C. with 3° C./min rate, dwell for 120 min, ramp to 400° C. with 3° C./min rate, dwell for 120 min, cool to room temperature). The calcined product was then ground to a fine powder.
5 mg of the calcined product were impregnated with 0.015 ml Sr(NO3)2 0.1M aqueous solution. Powder and solution is mixed on hot plate at 90 C until forming a paste. The paste was then dried for 1 h at 120° C. in a vacuum oven and finally calcined in a muffle oven in air. (load in the furnace at room temperature, ramp to 200° C. with 3° C./min rate, dwell for 120 min, ramp to 400° C. with 3° C./min rate, dwell for 120 min, ramp to 500° C. with 3° C./min rate, dwell for 120 min, cool to room temperature).
Example 9
Preparation of ZrO2/La2O3 Core/Shell Nanowires
As an example, FIG. 15 shows schematically an integrated process 800 for growing a core/shell structure of ZrO2/La2O3 nanowire. A phase solution is prepared, to which a zirconium salt precursor (e.g., ZrCl2) is added to allow for the nucleation of ZrO2+ on the phage. Subsequently, a hydroxide precursor (e.g., LiOH) is added to cause the nucleation of hydroxide ions on the phage. Nanowires 804 is thus formed in which the phage 810 is coated with a continuous and crystalline layer 820 of ZrO(OH)2. To this reaction mixture, a lanthanum salt precursor (e.g., LaCl3) is added under a condition to cause the nucleation of La(OH)3 over the ZrO(OH)2 nanowire 804. Following calcinations, nanowires of a core/shell structure of ZrO2/La2O3 are formed. A further step of impregnation produces nanowires of ZrO2/La2O3 doped with strontium ions (Sr2+) 840, in which the phage 810 is coated with a layer of ZrO2 830, which is in turn coated with a shell of La2O3 850.
ZrO2/La2O3 nanowires were thus prepared by mixing 20 ml of 2.5e12 pfu E3 Phage solution to 0.1 ml of 0.5M ZrO(NO3)2 aqueous solution. The solution was incubated under stirring for 16 hours. Any solids formed following incubation were removed by centrifugation at 4000 rpm for 5 minutes and redispersed in 0.5 ml ethanol. A small aliquot was retrieved for TEM characterization.
Thereafter, the ethanol solution was mixed with 10 ml water and 2 ml of 0.05M ZrO(NO3)2 with 2 ml of 0.1 M NH4OH were added during a period of 200 minutes using syringe pumps. Wash solids with water and resuspend in ethanol for TEM observation.
To about 18 mg of ZrO(OH)2 nanowires in suspension, 10 ml of water was added, followed by the addition of 0.5 ml of LaCl3 0.083 M with 0.5 ml of NH4OH 0.3 M solution during a period of 50 minutes using syringe pumps. The solids thus formed were separated by centrifugation to obtain a powder, which was dried in a vacuum oven at 110° C. for one hour. A small aliquot of the dried powder is then suspended in ethanol for TEM observation.
Example 10
Preparation of La(OH)3/ZrO2 Core/Shell Nanowires
Similar to Example 9, La(OH)3 nanowires were coated with ZrO2 shell according to the following process. To 6.8 mg of La(OH)3 nanowires (prepared by LaCl3 and NH4OH in a process similar to that of Example 9), which had been dried at 110° C., was added 4 ml of water to suspend the solids. 0.5 ml of 0.05M ZrO(NO3)2 and 0.5 ml of 0.1 M NH4OH were slowly added in 50 minutes. The solids were retrieved by centrifugation and calcined at 500° C. for one hour. TEM observation showed nanowires as the major morphology.
Example 11
Preparation of Hollow-Cored ZrO2 Nanowires
To the La(OH)3/ZrO2 core/shell nanowires prepared Example 10, additional processing can be used to create hollow ZrO2 shell nanowires. The La(OH)3 core can be etched using 1M citric acid solution. Controlled experiments on calcined and un-calcined La(OH)3 nanowires shows that the entire nanowires are fully etched in about one hour at room temperature. Etching of La(OH)3/ZrO2 core/shell nanowires was conducted overnight (about 16 hours).
The remaining solid was then separated by centrifugation and TEM observation is conducted on the washed solids (water wash). Low contrast zirconia nanowires were observed after etching, which indicates that hollow zirconia “straws” can be formed using La(OH)3 nanowire as template.
Example 12
OCM Catalyzed by La2O3 Nanowires
A 20 mg sample of a phage-based Sr (5%) doped La2O3 catalyst was diluted with 80 mg of quartz sand and placed into a reactor (run WPS21). The gas flows were held constant at 9 sccm methane, 3 sccm oxygen and 6 sccm of argon. The upstream temperature (just above the bed) was varied from 500° C. to 800° C. in 100° C. increments and then decreased back down to 600° C. in 50° C. increments. The vent gas analysis was gathered at each temperature level.
As a point of comparison, 20 mg of bulk 5% Sr on La2O3 catalyst was diluted in the same manner and run through the exact flow and temperature protocol.
FIG. 16 shows the formation of OCM products at 700° C., including C2 (ethane and ethylene) as well as further coupling products (propane and propylene).
FIGS. 17A, 17B and 17C show the comparative results in catalytic performance parameters for a nanowire catalyst (Sr2+/La2O3) vs. its corresponding bulk material (Sr2+/La2O3 bulk). Methane conversion rates, C2 selectivities and C2 yields are among the important parameters by which the catalytic properties were measured. More specifically, FIG. 17A shows the methane conversion rates are higher for the nanowire catalyst compared to the bulk material across a wide temperature range (e.g., 550 to 650° C.). Likewise, FIG. 17B and FIG. 17C show that the C2 selectivities and C2 yields are also higher for the nanowire catalyst as compared to the bulk catalyst across a wide temperature range (e.g., 550 to 650° C.). Thus, it is demonstrated that by improving both conversion and selectivity simultaneously that the C2 yield can be improved over traditional bulk catalysts.
FIGS. 18A-18B demonstrate that nanowires prepared under different synthetic conditions afforded different catalytic performances, suggesting that the various synthetic parameters resulted in divergent nanowire morphologies. FIG. 18A shows that nanowires prepared using different phage templates (SEQ ID NO: 9 and SEQ ID NO:3) in otherwise identical synthetic conditions created nanowire catalysts that perform differently in terms of the C2 selectivity in an OCM reaction. FIG. 18B shows the comparative C2 selectivities of nanowires prepared by an alternative adjustment of the synthetic parameters. In this case, the phage template was the same for both nanowires (SEQ ID NO:3), but the synthetic conditions were different. Specifically, the nanowires of FIG. 18A were prepared with shorter incubation and growth times than the nanowires of FIG. 18B. Additionally, the nanowires of FIG. 18A were calcined in a single step at 400° C. instead of the ramped temperature calcinations performed on the nanowires of FIG. 18B.
These results confirm that the nanowire catalysts behave differently from their bulk material counterparts. In particular, the nanowire catalysts allow for adjustments of the surface morphologies through synthetic design and screening to ultimately produce high-performance catalysts.
Example 13
Oxidative Dehydrogenation Catalyzed by MgO Nanowires
A 10 mg sample of phage-based Li doped MgO catalyst was diluted with 90 mg of quartz sand and placed in a reactor. The gas flows were held constant at 8 sccm alkane mix, 2 sccm oxygen and 10 sccm of argon. The upstream temperature (just above the bed) was varied from 500° C. to 750° C. in 50-100° C. increments. The vent gas analysis was gathered at each temperature level.
As a point of comparison, 10 mg of bulk 1 wt % Li on MgO catalyst was diluted in the same manner and run through the exact flow and temperature protocol. The results of this experiment are shown in FIG. 19. As can be seen in FIG. 19, phage-based nanowires according to the present disclosure comprise better conversion of ethane and propane compared to a corresponding bulk catalyst.
Example 14
Synthesis of Sr Doped La2O3 Nanowires
Sr doped La2O3 nanowires were prepared according to the following non-template directed method.
A La(OH)3 gel was prepared by adding 0.395 g of NH4OH (25%) to 19.2 ml of water followed by addition of 2 ml of a 1 M solution of La(NO3)3. The solution was then mixed vigorously. The solution first gelled but the viscosity dropped with continuous agitation. The solution was then allowed to stand for a period of between 5 and 10 minutes. The solution was then centrifuged at 10,000 g for 5 minutes. The centrifuged gel was retrieved and washed with 30 ml of water and the centrifugation washing procedure was repeated.
To the washed gel was added 10.8 ml of water to suspend the solid. The suspension was then transferred to a hydrothermal bomb (20 ml volume, not stirred). The hydrothermal bomb was then loaded in a muffle furnace at 160° C. and the solution was allowed to stand under autogenous pressure at 160° C. for 16 hours.
The solids were then isolated by centrifugation at 10,000 g for 5 minutes, and wash with 10 ml of water to yield about 260 mg of solid (after drying). The obtained solids were calcined in a muffle oven according to the following procedure: (1) load in the furnace at room temperature; (2) ramp to 200° C. with 3° C./min rate; (3) dwell for 120 min; (4) ramp to 400° C. with 3° C./min rate; and (5) dwell for 120 min. About 220 mg of nanowires were retrieved after calcination.
A 57 mg aliquot of nanowires was then mixed with 0.174 ml of a 0.1 M solution of Sr(NO3)2. This mixture was then stirred on a hot plate at 90° C. until a paste was formed.
The paste was then dried for 1 h at 120° C. in a vacuum oven and finally calcined in a muffle oven in air according to the following procedure: (1) load in the furnace at room temperature; (2) ramp to 200° C. with 3° C./min rate; (3) dwell for 120 min; (3) ramp to 400° C. with 3° C./min rate; (4) dwell for 120 min; (5) ramp to 500° C. with 3° C./min rate; and (6) dwell for 120 min. The calcined product was then ground to a fine powder.
5 mg of the calcined product were impregnated with 0.015 ml Sr(NO3)2 0.1M aqueous solution. Powder and solution is mixed on hot plate at 90 C until forming a paste. The paste was then dried for 1 h at 120° C. in a vacuum oven and finally calcined in a muffle oven in air. (load in the furnace at room temperature, ramp to 200° C. with 3° C./min rate, dwell for 120 min, ramp to 400° C. with 3° C./min rate, dwell for 120 min, ramp to 500° C. with 3° C./min rate, dwell for 120 min).
FIG. 20 shows a TEM image of the nanowires obtained from this non-template directed method. As shown in FIG. 20, the nanowires comprise a ratio of effective length to actual length of about 1 (i.e., the nanowires comprise a “straight” morphology).
Example 15
Synthesis of La2O3 Nanowires
La(NO3)3.6H2O (10.825 g) is added to 250 mL distilled water and stirred until all solids are dissolved. Concentrated ammonium hydroxide (4.885 mL) is added to this mixture and stirred for at least one hour resulting in a white gel. This mixture is transferred equally to 5 centrifuge tubes and centrifuged for at least 15 minutes. The supernatant is discarded and each pellet is rinsed with water, centrifuged for at least 15 minutes and the supernatant is again discarded.
The resulting pellets are all combined, suspended in distilled water (125 mL) and heated at 105° C. for 24 hours. The lanthanum hydroxide is isolated by centrifugation and suspended in ethanol (20 mL). The ethanol supernatant is concentrated and the product is dried at 65° C. until all ethanol is removed.
The lanthanum hydroxide nanowires prepared above are calcined by heating at 100° C. for 30 min., 400° C. for 4 hours and then 550° C. for 4 hours to obtain the La2O3 nanowires.
Example 16
Preparation of Na10MnW5O17 Nanowires
25 ml of concentrated reagent grade NH4OH are dissolved in 25 ml of distilled water, and 1 ml of 0.001M aqueous solution of M13 bacteriophage is then added. 0.62 g of Mn(NO3)2, 1.01 g of NaCl and 2.00 g of WO3 are then added to the mixture with stirring. The mixture is heated at a temperature of about 95° C. for 15 minutes. The mixture is then dried overnight at about 110° C. and calcined at about 400° C. for 3 hours.
Example 17
Preparation of Na10MnW5O17 Nanowires
25 ml of concentrated reagent grade NH4OH are dissolved in 25 ml of distilled water, and 1 ml of 0.001 M aqueous solution of M13 bacteriophage is then added. 1.01 g of NaCl and 2.00 g of WO3 are then added to the mixture with stirring. The mixture is heated at a temperature of about 95° C. for 15 minutes. The mixture is then dried overnight at about 110° C. and calcined at about 400° C. for 3 hours. The resulting material is then suspended in 10 ml of distilled water and 0.62 g of Mn(NO3)2 is added to the mixture with stirring. The mixture is heated at a temperature of about 115° C. for 15 minutes. The mixture is then dried overnight at about 110° C. and calcined at about 400° C. for 3 hours.
Example 18
Preparation of Na10MnW5O17/SiO2 Nanowires
Nanowire material Na10MnW5O17 (2.00 g), prepared as described in Example 16 above, is suspended in water, and about 221.20 g of a 40% by weight colloidal dispersion of SiO2 (silica) is added while stirring. The mixture is heated at about 100° C. until near dryness. The mixture is then dried overnight at about 110° C. and heated under a stream of oxygen gas (i.e., calcined) at about 400° C. for 3 hours. The calcined product is cooled to room temperature and then ground to a 10-30 mesh size.
Example 19
Preparation of La2O3 Nanowires
Two identical syntheses were made in parallel. In each synthesis, 360 ml of 4 e12 pfu/ml solution of phage (SEQ ID NO: 3) were mixed in a 500 ml plastic bottle with 1.6 ml of 0.1 M LaCl3 aqueous solution and left incubating for at least 1 hour. After this incubation period, a slow multistep addition was conducted with 20 ml of 0.1 M LaCl3 solution and 40 ml of 0.3 M NH4OH. This addition was conducted in 24 hours and 100 steps. The reaction mixture was left stirred for at least another hour at room temperature. After that time the suspension was centrifuged in order to separate the solid phase from the liquid phase. The precipitated material was then re-suspended in 25 ml of ethanol. The ethanol suspensions from the two identical syntheses were combined and centrifuged in order to remove un-reacted species. The gel-like product remaining was then dried for 15 hours at 65° C. in an oven and then calcined in a muffle oven in air (load in the furnace at room temperature, ramp to 100° C. with 2° C./min rate, dwell for 30 min, ramp to 400° C. with 2° C./min rate, dwell for 240 min, ramp to 550° C. with 2° C./min rate, dwell for 240 min, cool to room temperature).
Example 20
Preparation of Mg/Na Doped La2O3 Nanowires
Two identical syntheses were made in parallel. In each synthesis, 360 ml of 4 e12 pfu solution of phage (SEQ ID NO: 3) were mixed in a 500 ml plastic bottle with 1.6 ml of 0.1 M LaCl3 aqueous solution and left incubating for at least 1 hour. After this incubation period, a slow multistep addition was conducted with 20 ml of 0.1 M LaCl3 solution and 40 ml of 0.3 M NH4OH. This addition was conducted in 24 hours and 100 steps. The reaction mixture was left stirred for at least another hour at room temperature. After that time, the suspension was centrifuged in order to separate the solid phase from the liquid phase. The precipitated material was then resuspended in 25 ml of ethanol. The ethanol suspensions from the two identical syntheses were combined and centrifuged in order to remove un-reacted species. The gel-like product remaining was then dried for 15 hours at 65° C. in an oven.
The target doping level was 20 at % Mg and 5 at % Na at % refers to atomic percent). 182 mg of the dried product were suspended in 2.16 ml deionized water, 0.19 ml 1 M Mg(NO3)2 aqueous solution and 0.05 ml 1M NaNO3 aqueous solution. The resulting slurry was stirred at room temperature for 1 hour, sonicated for 5 min, then dried at 120° C. in and oven until the powder was fully dried and finally calcined in a muffle oven in air (load in the furnace at room temperature, ramp to 100° C. with 2° C./min rate, dwell for 30 min, ramp to 400° C. with 2° C./min rate, dwell for 60 min, ramp to 550° C. with 2° C./min rate, dwell for 60 min, ramp to 650° C. with 2° C./min rate, dwell for 60 min, ramp to 750° C. with 2° C./min rate, dwell for 240 min, cool to room temperature).
Example 21
Oxidative Coupling of Methane Catalyzed by Mg/Na Doped La2O3 Nanowires
50 mg of Mg/Na-doped La2O3 nanowires catalyst from example 20 were placed into a reactor tube (4 mm ID diameter quartz tube with a 0.5 mm ID capillary downstream), which was then tested in an Altamira Benchcat 203. The gas flows were held constant at 46 sccm methane and 54 sccm air, which correspond to a CH4/O2 ratio of 4 and a feed gas-hour space velocity (GHSV) of about 130000 h-1. The reactor temperature was varied from 400° C. to 450° C. in a 50° C. increment, from 450° C. to 550° C. in 25° C. increments and from 550° C. to 750° C. in 50° C. increments. The vent gases were analyzed with gas chromatography (GC) at each temperature level.
FIG. 22 shows the onset of OCM between 550° C. and 600° C. The C2 selectivity, methane conversion and C2 yield at 650° C. were 57%, 25% and 14%, respectively.
In another example, 50 mg of Mg/Na-doped La2O3 nanowires catalyst from example 20 were placed into a reactor tube (4 mm ID diameter quartz tube with a 0.5 mm ID capillary downstream), which was then tested in an Altamira Benchcat 203. The gas flows were held constant at 46 sccm methane and 54 sccm air, which correspond to a feed gas-hour space velocity (GHSV) of about 130000 h−1. The CH4/O2 ratio was 5.5. The reactor temperature was varied from 400° C. to 450° C. in a 50° C. increment, from 450° C. to 550° C. in a 25° C. increments and from 550° C. to 750° C. in 50° C. increments. The vent gases were analyzed with gas chromatography (GC) at each temperature level.
FIG. 23 shows the onset of OCM between 550° C. and 600° C. The C2 selectivity, methane conversion and C2 yield at 650° C. were 62%, 20% and 12%, respectively.
Example 22
Nanowire Synthesis
Nanowires may be prepared by hydrothermal synthesis from metal hydroxide gels (made from metal salt+base). In some embodiments, this method is applicable to lanthanides, for example La, Nd, Pr, Sm, Eu, and lanthanide containing mixed oxides.
Alternatively, nanowires can be prepared by synthesis from metal hydroxide gel (made from metal salt+base) under reflux conditions. In some embodiments, this method is applicable to lanthanides, for example La, Nd, Pr, Sm, Eu, and lanthanide containing mixed oxides.
Alternatively, the gel can be aged at room temperature. Certain embodiments of this method are applicable for making magnesium hydroxychloride nanowires, which can be converted to magnesium hydroxide nanowires and eventually to MgO nanowires. In a related method, hydrothermal treatment of the gel instead of aging, is used.
Nanowires may also be prepared by polyethyleneglycol assisted hydrothermal synthesis. For example, Mn containing nanowires may be prepared according to this method using methods known to those skilled in the art. Alternatively, hydrothermal synthesis directly from the oxide can be used.
Example 23
Preparation of Nanowires
Nanostructured catalyst materials can be prepared by a variety of starting materials. In certain embodiments, the rare earth oxides are attractive starting materials since they can be obtained at high purity and are less expensive than the rare earth salt precursors that are typically used in preparative synthesis work. Methods for making rare earth oxide needles/nanowires and derivatives thereof are described below.
Method A: Lanthanide oxide starting material can be hydrothermally treated in the presence of ammonium halide to prepare rare earth oxide nanowires/needles. The preparation is a simple one-pot procedure with high yield. For example, one gram of lanthanum oxide was placed in 10 mL of distilled water. Ammonium chloride (0.98 g) was added to the water, the mixture was placed in an autoclave, and the autoclave was placed in a 160 C oven for 18 h. The autoclave was taken out of the oven, cooled, and the product was isolated by filtration. Micron and submicron needles were observed in the TEM images of the product. This method could also be used to prepare mixed metal oxides, metal oxyhalides, metal oxynitrates, and metal sulfates.
Method B: Mixed metal oxide materials can be prepared using a solid-state reaction of rare earth oxide or bismuth oxide in the presence of ammonium halide. The solid-state reaction is used to prepare the rare earth or bismuth oxyhalide. The metal oxyhalide is then placed in water at room temperature and the oxyhalide is slowly converted to metal oxide with nanowire/needle morphology. For example: lanthanum oxide, bismuth oxide, and ammonium chloride were ground and fired in a ceramic dish to make the mixed metal oxychloride. The metal oxychloride is then placed in water to form the mixed metal oxide needles.
Example 24
Preparation of MgO/Mn2O3 Core/Shell Nanowires
19.7 ml of concentrated solution of phages (e.g., SEQ ID NO: 3 at a concentration of  ̃5E12 pfu/ml) were mixed in a 20 ml vial with 0.1 ml of 1 M LiOH aqueous solution and left incubating overnight ( ̃15 h). 0.2 ml of 1 M MgCl2 aqueous solution were then added using a pipette, and the mixture was mixed by gentle shaking. The reaction mixture was left incubating unstirred for 72 h. After the incubation time, the mixture was centrifuged and the supernatant decanted. The precipitated material was re-suspended in 5 ml of 0.001 M LiOH aqueous solution (pH=11), the mixture was centrifuged and the supernatant decanted.
19.8 ml of deionized water were added to the obtained Mg(OH)2 nanowires. The mixture was left incubating for 1 h. After the incubation time, 0.2 ml of 1 M MnCl2 aqueous solution were then added using a pipette and the mixture was mixed by gentle shaking. The reaction mixture was left incubating unstirred for 24 h. After the incubation time, the mixture was centrifuged and the supernatant decanted. The precipitated material was re-suspended in 3 ml of 0.001 M LiOH aqueous solution (pH=11), the mixture was centrifuged and the supernatant decanted. The precipitated material was finally re-suspended in 7 ml ethanol, the mixture was centrifuged and the supernatant decanted.
The obtained MnO(OH) coated Mg(OH)2 nanowires were dried at 65° C. for 15 h in an oven. Finally, the dried product was calcined in a muffle furnace using a step recipe (load in the furnace at room temperature, ramp to 100° C. with 2° C./min rate, dwell for 60 min, ramp to 280° C. with 2° C./min rate, dwell for 60 min, ramp to 350° C. with 2° C./min rate, dwell for 60 min, ramp to 450° C. with 2° C./min rate, dwell for 60 min, ramp to 550° C. with 2° C./min rate, dwell for 60 min, cool to room temperature) to convert it to MgO/Mn2O3 core-shell nanowires.
The surface area of the nanowires was determined by BET (Brunauer, Emmett, Teller) measurement at 111.5 m2/g.
Example 25
Preparation of Mn2O3 Nanowires
3.96 ml of concentrated solution of phages (e.g., SEQ ID NO: 3 at a concentration of  ̃5E12 pfu/ml) were mixed in a 8 ml vial with 0.04 ml of 1 M MnCl2 aqueous solution and left incubating for 20 h. 0.02 ml of 1 M LiOH aqueous solution were then added using a pipette and the mixture was mixed by gentle shaking. The reaction mixture was left incubating unstirred for 72 h. After the incubation time, the mixture was centrifuged, and the supernatant was decanted. The precipitated material was re-suspended in 2 ml of 0.001 M LiOH aqueous solution (pH=11), the mixture was centrifuged and the supernatant decanted. The precipitated material was re-suspended in 2 ml ethanol, the mixture was centrifuged and the supernatant decanted. The obtained MnO(OH) nanowires were dried at 65° C. for 15 h in an oven. Finally, the dried product was calcined in a muffle furnace using a step recipe (load in the furnace at room temperature, ramp to 100° C. with 2° C./min rate, dwell for 60 min, ramp to 280° C. with 2° C./min rate, dwell for 60 min, ramp to 350° C. with 2° C./min rate, dwell for 60 min, ramp to 450° C. with 2° C./min rate, dwell for 60 min, ramp to 550° C. with 2° C./min rate, dwell for 60 min, cool to room temperature) to convert it to Mn2O3 nanowires.
Example 26
Preparation of V2O5 Nanowires
1.8 mg of V2O5 were dissolved in a 10 ml of a 2.5 wt % aqueous solution of HF. 1 ml of the V2O5/HF solution was mixed with 1 ml of concentrated solution of phages (e.g., SEQ ID NO: 3 at a concentration of  ̃5E12 pfu/ml) in a 15 ml plastic centrifugation tube and left incubating for 2 h. 1 ml of a saturated solution of boric acid (supernatant of nominally 1 M boric acid aqueous solution) were then added using a pipette and the mixture was mixed by gentle shaking. The reaction mixture was left incubating unstirred for 170 h. After the incubation time, the mixture was centrifuged, and the supernatant was decanted. The precipitated material was suspended in 2 ml ethanol, the mixture was centrifuged and the supernatant decanted. The obtained V2O5 nanowires were characterized by TEM.
Example 27
Synthesis of MgO Nanowires
12.5 ml of a 4M MgCl2 aqueous solution were heated to 70° C. on a hotplate. 0.1 g of MgO (from Aldrich) were then slowly added, over a span of at least 5 minutes, to the solution while it was vigorously stirred. The mixture was kept stirring at 70° C. for 3 h and then cooled down overnight ( ̃15 h) without stirring.
The obtained gel was transferred in a 25 ml hydrothermal bomb (Parr Bomb No. 4749). The hydrothermal bomb was then loaded in an oven at 120° C. and the solution was allowed to stand under autogenous pressure at 120° C. for 3 hours.
The product was centrifuged and the supernatant decanted. The precipitated product was suspended in about 50 ml ethanol and filtered over a 0.45 m polypropylene hydrophilic filter using a Büchner funnel. Additional 200 ml ethanol were used to wash the product.
The obtained magnesium hydroxide chloride hydrate nanowires were suspended in 12 ml ethanol and 2.4 ml deionized water in a 20 ml vial. 1.6 ml of 5M NaOH aqueous solution were added and the vial was sealed with its cap. The mixture was then heated at 65° C. in an oven for 15 h.
The product was filtered over a 0.45 μm polypropylene hydrophilic filter using a Büchner funnel. About 250 ml ethanol were used to wash the product. The obtained Mg(OH)2 nanowires were dried at 65° C. for 15 h in an oven. Finally, the dried product was calcined in a muffle furnace using a step recipe (load in the furnace at room temperature, ramp to 100° C. with 2° C./min rate, dwell for 60 min, ramp to 280° C. with 2° C./min rate, dwell for 60 min, ramp to 350° C. with 2° C./min rate, dwell for 60 min, ramp to 450° C. with 2° C./min rate, dwell for 60 min, cool to room temperature) to convert it to MgO nanowires.
Example 28
Synthesis of Mg(OH)2 Nanowires
6.8 g of MgCl2.6H2O were dissolved in 5 ml deionized water in a 20 ml vial. 0.4 g of MgO (from Aldrich) were then slowly added to the solution while it was vigorously stirred. The mixture was kept stirring at room temperature until it completely jellified ( ̃2 h) and then it was left aging for 48 h without stirring.
The gel was transferred in a 50 ml centrifuge tube, which was then filled with deionized water and vigorously shaken until an homogenous suspension was obtained. The suspension was centrifuged and the supernatant decanted. The precipitated product was suspended in about 50 ml ethanol and filtered over a 0.45 m polypropylene hydrophilic filter using a Büchner funnel. Additional 350 ml ethanol were used to wash the product.
The obtained magnesium hydroxide chloride hydrate nanowires were suspended in 24 ml ethanol in a 50 ml media bottle. The mixture was stirred for a few minutes, then 4.8 ml deionized water and 3.2 ml of 5M NaOH aqueous solution were added. The media bottle was sealed with its cap and the mixture was stirred for few more minutes. The mixture was then heated at 65° C. in an oven for 15 h.
The product was filtered over a 0.45 μm polypropylene hydrophilic filter using a Büchner funnel. About 400 ml ethanol were used to wash the product. The obtained Mg(OH)2 nanowires were dried at 65° C. for 72 h in an oven and then additionally dried at 120° C. for 2 h in a vacuum oven. About 0.697 g of Mg(OH)2 nanowires were obtained and the surface area of the nanowires was determined by BET (Brunauer, Emmett, Teller) measurement at 100.4 m2/g.
Example 29
Synthesis of MnO/Mn2O3 Core/Shell Nanowires
This example describes a method for coating the Mg(OH)2 nanowires from example 28 with MnO(OH).
Three almost identical syntheses were conducted in parallel. In each synthesis, the Mg(OH)2 nanowires, prepared using the method described in example 28 but without the drying steps, were mixed with 250 ml deionized water in a 500 ml plastic bottle and stirred for 20 minutes. 2.4 ml of a 1M MnCl2 solution were added to the first synthesis, 6 ml of a 1M MnCl2 solution were added to the second synthesis and 9.6 ml of a 1M MnCl2 solution were added to the third synthesis. The mixtures were stirred for 2 hours at room temperature. After this incubation period, a slow multistep addition was conducted with 1.2 ml, 3 ml and 4.8 ml of 0.1 M LiOH solution for the first, second and third synthesis, respectively. This addition was conducted in 2 hours and 20 steps. The reaction mixture was left stirred overnight ( ̃15 h) at room temperature. After that time the suspensions were centrifuged in order to separate the solid phase from the liquid phase. The precipitated materials were then re-suspended in 50 ml of ethanol for each synthesis and filtered over a 0.45 μM polypropylene hydrophilic filter using a Büchner funnel. Additional 350 ml ethanol were used to wash each product of the three synthesis.
The obtained Mg(OH)2/MnO(OH) core/shell nanowires were characterized by TEM before being dried at 65° C. for 72 h in an oven and then additionally dried at 120° C. for 2 h in a vacuum oven. The yield for the three syntheses was 0.675 g, 0.653 g and 0.688 g, respectively. The surface area of the nanowires was determined by BET (Brunauer, Emmett, Teller) measurement at 94.6 m2/g, 108.8 m2/g and 108.7 m2/g, respectively.
The Mg(OH)2/MnO(OH) core/shell nanowires can be converted into MgO/Mn2O3 nanowires by calcining them in a muffle furnace using a step recipe (load in the furnace at room temperature, ramp to 100° C. with 2° C./min rate, dwell for 60 min, ramp to 280° C. with 2° C./min rate, dwell for 60 min, ramp to 350° C. with 2° C./min rate, dwell for 60 min, ramp to 450° C. with 2° C./min rate, dwell for 60 min, ramp to 550° C. with 2° C./min rate, dwell for 60 min, cool to room temperature).
Example 30
Preparation of Nd2O3, Eu2O3 and Pr2O3 Nanowires
Three syntheses were made in parallel. In each synthesis, 10 ml of a 2.5 e12 pfu/ml solution of phage (SEQ ID NO: 14) were mixed in a 60 ml glass vial with 25 μl of 0.08M NdCl3, EuCl3 or PrCl3 aqueous solutions, respectively and left incubating for at least 1 hour. After this incubation period, a slow multistep addition was conducted with 630 μl of 0.08M LaCl3, EuCl3 or PrCl3 aqueous solutions, respectively and 500 μl of 0.3M NH4OH. This addition was conducted in 33 hours and 60 steps. The reaction mixtures were left stirred for at least another 10 hour at room temperature. After that time the suspensions were centrifuged in order to separate the solid phase from the liquid phase. The precipitated material was then re-suspended in 4 ml of ethanol. The ethanol suspensions were centrifuged in order to finish removing un-reacted species. The gel-like product remaining was then dried for 1 hours at 65° C. in an oven and then calcined in a muffle oven in air (load in the furnace at room temperature, ramp to 100° C. with 2° C./min rate, dwell for 30 min, ramp to 500° C. with 2° C./min rate, dwell for 240 min, cool to room temperature). The obtained Nd(OH)3, Eu(OH)3 and Pr(OH)3 nanowires were characterized by TEM before being dried.
Example 31
Preparation of Ce2O3/La2O3 Mixed Oxide Nanowires
In the synthesis, 15 ml of a 5 e12 pfu/ml solution of phage (SEQ ID NO: 3) were mixed in a 60 ml glass vial with 15 μl of 0.1 M La(NO3)3 aqueous solution and left incubating for about 16 hour. After this incubation period, a slow multistep addition was conducted with 550 μl of 0.2M Ce(NO3)3 aqueous solution, 950 μl of 0.2M La(NO3)3 aqueous solution and 1500 μl of 0.4M NH4OH. This addition was conducted in 39 hours and 60 steps. The reaction mixtures were left stirred for at least another 10 hours at room temperature. After that time the suspensions were centrifuged in order to separate the solid phase from the liquid phase. The precipitated material was then re-suspended in 4 ml of ethanol. The ethanol suspensions were centrifuged in order to finish removing un-reacted species. The gel-like product remaining was then dried for 1 hours at 65° C. in an oven and then calcined in a muffle oven in air (load in the furnace at room temperature, ramp to 100° C. with 2° C./min rate, dwell for 30 min, ramp to 500° C. with 2° C./min rate, dwell for 120 min, cool to room temperature).
Example 32
Synthesis of Pr2O3/La2O3 Mixed Oxide Nanowires
0.5 ml of 1M Pr(NO3)3 aqueous solution and 4.5 ml of 1M La(NO3)3 aqueous solution were mixed with 40 ml deionized water. Once well mixed, 5 ml of a 3M NH4OH aqueous solution were quickly injected in the mixture. A precipitate immediately formed. The suspension was kept stirring for another 10 minutes then transferred to centrifuge tubes and centrifuged in order to separate the solid phase from the liquid phase. The precipitated material was then re-suspended in 35 ml of deionized water. The solid fraction was separated again by centrifugation and the washing step was repeated one more time. The gel-like product remaining was then dispersed in deionized water and the suspension volume adjusted to 20 ml. The suspension was then transferred to a hydrothermal bomb and placed in an oven at 120° C. for 2 hours. The solids obtained after hydrothermal treatment were then separated by centrifugation and washed once with 35 ml of deionized water. The washed hydrothermally treated powder was then dried at 120° C. for 16 hours. The surface area, determine by BET, of the dried powder was about 41 m2/g. Transmission electron microscopy was used to characterize the morphology of this sample further. The powder was constituted of large aspect ratio particles with about 30 nm wide by 0.5 to 2 μm length. The powder was calcined in three temperature steps at 200, 400 and 500° C. with 3° C./min ramp and 2 hours of dwell time at each step. The surface area of the Pr2O3/La2O3 mixed oxide nanowires was about 36 m2/g.
Example 33
Synthesis of MgO/Eu2O3 Core/Shell nanowires
In this example, Mg(OH)2 nanowires are used as a support to grow a shell of Eu(OH)3. Mg(OH)2 nanowires, prepared according to the methods described in example 28 (wet product, before being dried) were used to prepare a suspension in deionized water with a concentration of 3 g/1 of dried Mg(OH)2. To 30 ml of the Mg(OH)2 suspension, 3 ml of 0.1M Eu(NO3)3 aqueous solution and 3 ml of 0.3M NH4OH aqueous solution were added in a slow multistep addition. This addition was conducted in 48 hours and 360 steps. The solids were then separated using centrifugation. The powder is washed with 30 ml DI water and centrifuged again. An aliquot is retrieved prior to calcination for transmission electron miscopy evaluation of the sample morphology. The sample is mainly constituted of high aspect ratio wires with a rough surface. The general morphology of the support is preserved and no separate phase is observed.
The remaining of the powder was dried at 120° C. for 3 hours and calcined in three steps at 200, 400 and 500° C. with 2 hours at each step and a ramp rate of 3° C./min. The surface area, determined by BET, of the MgO/Eu2O3 core/shell nanowires is 209 m2/g.
Example 34
Synthesis of Y2O3/La2O3 Mixed Oxide Nanowires
0.5 ml of 1M Y(NO3)3 aqueous solution and 4.5 ml of 1M La(NO3)3 aqueous solution were mixed with 40 ml deionized water. Once well mixed, 5 ml of a 3M NH4OH aqueous solution was quickly injected in the mixture. A precipitate immediately forms. The suspension was kept stirring for another 10 minutes then transferred to centrifuge tubes and centrifuged in order to separate the solid phase from the liquid phase. The precipitated material was then re-suspended in 35 ml deionized water. The solid fraction was separated again by centrifugation and the washing step was repeated one more time. The gel-like product remaining was then dispersed in deionized water and the suspension volume adjusted to 20 ml. The suspension was then transferred to a hydrothermal bomb and placed in an oven at 120° C. for 2 hours. The solids obtained after hydrothermal treatment were then separated by centrifugation and washed once with 35 ml of deionized water. The washed hydrothermally treated powder was then dried at 120° C. for 16 hours. The surface area, determined by BET, of the dried powder is about 20 m2/g. Transmission electron microscopy was used to characterize the morphology of this sample further. The powder was constituted of large aspect ratio particles with about 20 to 40 nm wide by 0.5 to 2 micron length. The Y2O3/La2O3 mixed oxide nanowires ware calcined in three temperature steps at 200, 400 and 500° C. with 3° C./min ramp and 2 hours of dwell time at each step.
Example 35
Synthesis of La2O3 Nanowires
1 g of La2O3 (13.1 mmol) and 0.92 g of NH4Cl (18.6 mmol) were placed in a 25 ml stainless steel autoclave with a Teflon liner (Parr Bomb No. 4749). 10 ml deionized water were then added to the dry reactants. The autoclave was sealed and placed in a 160° C. oven for 12 h. After 12 h, the autoclave was allowed to cool. The nanowires were washed several times with 10 mL of water to remove any excess NH4Cl. The product was then dried in an oven for 15 hours at 65° C. in an oven and then calcined in a muffle oven in air (load in the furnace at room temperature, ramp to 100° C. with 2° C./min rate, dwell for 30 min, ramp to 400° C. with 2° C./min rate, dwell for 240 min, ramp to 550° C. with 2° C./min rate, dwell for 240 min, cool to room temperature.)
Example 36
Synthesis of La2O3/Nd2O3 Mixed Oxide Nanowires
0.5 g of La2O3 (1.5 mmol), 0.52 g of Nd2O3 (1.5 mmol), and 0.325 g of NH4Cl (6 mmol) were ground together using a mortar and pestle. Once the dry reactants were well mixed, the ground powder was placed in a ceramic crucible and then the crucible was transferred to a tube furnace. The tube furnace atmosphere was flushed with nitrogen for 0.5 h. The reactants were then calcined under nitrogen (25° C.-450° C., 2° C./min ramp, dwell 1 h; 450° C.-900° C.; 2° C./min ramp, 1 h hold, cool to room temperature.) The product (0.2 g) was placed in 10 mL of deionized water and stirred at room temperature for 24 h. The nanowires were then washed several times with deionized H2O and dried in an oven for 15 hours at 65° C. in an oven and then calcined in a muffle oven in air (load in the furnace at room temperature, ramp to 100° C. with 2° C./min rate, dwell for 30 min, ramp to 400° C. with 2° C./min rate, dwell for 240 min, ramp to 550° C. with 2° C./min rate, dwell for 240 min, cool to room temperature.)
Example 37
Oligomerization of Ethylene to Liquid Hydrocarbon Fuels with High Aromatics Content
0.1 g of the zeolite ZSM-5 is loaded into a fixed bed micro-reactor and heated at 400° C. for 2 h under nitrogen to activate the catalyst. The OCM effluent, containing ethylene and ethane, is reacted over the catalyst at 400° C. at a flow rate of 50 mL/min and GSHV=3000-10000 mL/(g h). The reaction products are separated into liquid and gas components using a cold trap. The gas and liquid components are analyzed by gas chromatography. C5-C10 hydrocarbon liquid fractions, such as xylene and isomers thereof, represent 90% of the liquid product ratio while the C11-C15 hydrocarbon fraction represents the remaining 10% of the product ratio.
Example 38
Oligomerization of Ethylene to Liquid Hydrocarbon Fuels with High Olefins Content
0.1 g of the zeolite ZSM-5 doped with nickel is loaded into a fixed bed micro-reactor and heated at 350° C. for 2 h under nitrogen to activate the catalyst. The OCM effluent, containing ethylene and ethane, is reacted over the catalyst at 250-400° C. temperature rage with GSHV=1000-10000 mL/(g h). The reaction products are separated into liquid and gas components using a cold trap. The gas and liquid components are analyzed by gas chromatography. C4-C10 olefin hydrocarbon liquid fractions, such as butene, hexane and octene represent 95% of the liquid product ratio while the C12-C18 hydrocarbon fraction represents the remaining 5% of the product ratio. Some trace amounts of odd numbered olefins are also possible in the product.
Example 39
Synthesis of MnWO4 Nanowires
0.379 g of Na2WO4 (0.001 mol) was dissolved in 5 mL of deionized water. 0.197 g of MnCl2.6H2O (0.001 mol) was dissolved in 2 mL of deionized water. The two solutions were then mixed and a precipitate was observed immediately. The mixture was placed in a stainless steel autoclave with a Teflon liner (Parr Bomb No. 4749). 40 ml of deionized water was added to the reaction mixture and the pH was adjusted to 9.4 with NH4OH. The autoclave was sealed and placed in a 120° C. oven. The reaction was left to react for 18 h and then it was cooled to room temperature. The product was washed with deionized water and then dried in a 65° C. oven. The samples were calcined in a muffle oven in air (load in the furnace at room temperature, ramp to 400° C. with 5° C./min rate, dwell for 2 h, ramp to 850° C. with 5° C./min rate, dwell for 8 h, cool to room temperature).
Example 40
Preparation of Supported MnWO4 Nanowire Catalysts
Supported MnWO4 nanowires catalysts are prepared using the following general protocol. MnWO4 nanowires are prepared using the method described in example 42. Manganese tungstate nanowires, support, and water are slurried for 6 h at room temperature. The manganese tungstate to support ratio is 2-10 wt %. The mixture is dried in a 65° C. oven and then calcined in a muffle oven in air: load in the furnace at room temperature, ramp to 400° C. with 5° C./min rate, dwell for 2 h, ramp to 850° C. with 5° C./min rate, dwell for 8 h, cool to room temperature. The following is a list of exemplary supports that may be used: SiO2, Al2O3, SiO2—Al2O3, ZrO2, TiO2, HfO2, Silica-Aluminum Phosphate, and Aluminum Phosphate.
Example 41
OCM Catalyzed by La2O3 Nanowires
50 mg of La2O3 nanowires catalyst, prepared using the method described in example 19, were placed into a reactor tube (4 mm ID diameter quartz tube with a 0.5 mm ID capillary downstream), which was then tested in an Altamira Benchcat 203. The gas flows were held constant at 46 sccm methane and 54 sccm air, which correspond to a CH4/O2 ratio of 4 and a feed gas-hour space velocity (GHSV) of about 130000 h−1. The reactor temperature was varied from 400° C. to 500° C. in a 100° C. increment and from 500° C. to 850° C. in 50° C. increments. The vent gases were analyzed with gas chromatography (GC) at each temperature level.
FIG. 24 shows the onset of OCM between 500° C. and 550° C. The C2 selectivity, methane conversion and C2 yield at 650° C. were 54%, 27% and 14%, respectively.
The various embodiments described above can be combined to provide further embodiments. All of the U.S. patents, U.S. patent application publications, U.S. patent applications, foreign patents, foreign patent applications and non-patent publications referred to in this specification and/or listed in the Application Data Sheet, are incorporated herein by reference, in their entirety. Aspects of the embodiments can be modified, if necessary to employ concepts of the various patents, applications and publications to provide yet further embodiments. These and other changes can be made to the embodiments in light of the above-detailed description. In general, in the following claims, the terms used should not be construed to limit the claims to the specific embodiments disclosed in the specification and the claims, but should be construed to include all possible embodiments along with the full scope of equivalents to which such claims are entitled. Accordingly, the claims are not limited by the disclosure.

## Claims

1. A method for the preparation of ethylene from methane, the method comprising contacting a mixture comprising oxygen and methane at a temperature below 600° C. with a catalytic nanowire, thereby producing C2 hydrocarbons at a selectivity of greater than 30%, wherein the catalytic nanowire is an inorganic catalytic polycrystalline nanowire having a ratio of effective length to actual length of less than one and an aspect ratio of greater than ten as measured by TEM in bright field mode at 5 keV, wherein the catalytic nanowire comprises one or more elements from any of Groups 1 through 7, lanthanides, actinides or combinations thereof in the form of oxides, hydroxides, oxyhydroxides, sulfates, carbonates, oxide carbonates, oxalates, phosphates, hydrogenphosphates, dihydrogenphosphates, oxyhalides, hydroxihalides, oxysulfates or combinations thereof.

2. A method for preparing a downstream product of ethylene, the method comprising converting ethylene into a downstream product of ethylene, and the method comprising contacting a mixture comprising oxygen and methane at a temperature below 600° C. with a catalytic nanowire, thereby producing C2 hydrocarbons at a selectivity of greater than 30%, wherein the catalytic nanowire is an inorganic catalytic polycrystalline nanowire having a ratio of effective length to actual length of less than one and an aspect ratio of greater than ten as measured by TEM in bright field mode at 5 keV, wherein the catalytic nanowire comprises one or more elements from any of Groups 1 through 7, lanthanides, actinides or combinations thereof in the form of oxides, hydroxides, oxyhydroxides, sulfates, carbonates, oxide carbonates, oxalates, phosphates, hydrogenphosphates, dihydrogenphosphates, oxyhalides, hydroxihalides, oxysulfates or combinations thereof.

3. A method for the preparation of a downstream product of ethylene, the method comprising:
converting methane into ethylene by contacting a mixture comprising oxygen and methane at a temperature below 600° C. with a catalytic nanowire, thereby producing C2 hydrocarbons at a selectivity of greater than 30%; and
oligomerizing the ethylene to prepare a downstream product of ethylene, wherein the catalytic nanowire is an inorganic catalytic polycrystalline nanowire having a ratio of effective length to actual length of less than one and an aspect ratio of greater than ten as measured by TEM in bright field mode at 5 keV, wherein the catalytic nanowire comprises one or more elements from any of Groups 1 through 7, lanthanides, actinides or combinations thereof in the form of oxides, hydroxides, oxyhydroxides, sulfates, carbonates, oxide carbonates, oxalates, phosphates, hydrogenphosphates, dihydrogenphosphates, oxyhalides, hydroxihalides, oxysulfates or combinations thereof.

4. The method of claim 1, wherein the one or more elements are in the form of oxides.

5. The method of claim 1, wherein the one or more elements are in the form of hydroxides.

6. The method of claim 1, wherein the catalytic nanowire comprises Mg, Ca, La, W, Mn, Mo, Nd, Sm, Eu, Pr, Zr or combinations thereof.

7. The method of claim 1, wherein the catalytic nanowire comprises MgO, CaO, La2O3, Na2WO4, Mn2O3, Mn3O4, Nd2O3, Sm2O3, Eu2O3, Pr2O3, Mg6MnO8, NaMnO4, Na/Mn/W/O, MnWO4 or combinations thereof.

8. The method of claim 1, wherein the catalytic nanowire further comprises one or more dopants comprising metal elements, semi-metal elements, non-metal elements or combinations thereof.

9. The method of claim 8, wherein the dopant comprises Li, Na, K, Mg, Ca, Ba, Sr, Eu, Sm, Co or Mn.

10. The method of claim 9, wherein the catalytic nanowire comprises Li/MgO, Ba/MgO, Sr/La2O3, Mg/Na/La2O3, Sr/Nd2O3, or Mn/Na2WO4.

11. The method of claim 8, wherein the atomic ratio of the one or more elements from Groups 1 through 7, lanthanides or actinides to the dopant ranges from 1:1 to 10,000:1.

12. The method of claim 1, wherein the catalytic nanowire comprises a combination of two or more compounds comprising the one or more elements.

13. The method of claim 12, wherein the catalytic nanowire comprises Mn2O3/Na2WO4, Mn3O4/Na2WO4MnWO4/Na2WO4/Mn2O3, MnWO4/Na2WO4/Mn3O4 or NaMnO4/MgO.

14. The method of claim 1, wherein the catalytic nanowire has a diameter of between 7 nm and 200 nm as determined by TEM in bright field mode at 5 keV.

15. The method of claim 1, wherein the catalytic nanowire has an actual length of between 100 nm and 10 μm as determined by TEM in bright field mode at 5 keV.

16. The method of claim 1, wherein the catalytic nanowire has a ratio of effective length to actual length of less than 0.8.

17. The method of claim 1, wherein the powder x-ray diffraction pattern of the nanowire shows an average crystalline domain size of less than 50 nm.

18. The method of claim 1, wherein the catalytic nanowire further comprises a support material.

19. The method of claim 18, wherein the support material comprises an inorganic oxide, Al2O3, SiO2, TiO2, MgO, ZrO2, HfO2, CaO, ZnO, LiAlO2, MgAl2O4, MnO, MnO2, Mn2O4, Mn3O4, La2O3, activated carbon, silica gel, zeolites, activated clays, activated Al2O3, diatomaceous earth, magnesia, aluminosilicates, calcium aluminate, support nanowires or combinations thereof.

20. The method of claim 1, wherein the catalytic nanowire comprises an inner core and an outer layer, the inner core and outer layer each independently comprising one or more elements selected from Groups 1 through 7, lanthanides and actinides.

21. The method of claim 1, wherein the ethylene is prepared from methane via the oxidative coupling of methane (OCM) reaction.

22. The method of claim 1, wherein the mixture comprising oxygen and methane comprises air.

23. The method of claim 2, wherein the one or more elements are in the form of oxides.

24. The method of claim 2, wherein the one or more elements are in the form of hydroxides.

25. The method of claim 2, wherein the catalytic nanowire comprises Mg, Ca, La, W, Mn, Mo, Nd, Sm, Eu, Pr, Zr or combinations thereof.

26. The method of claim 2, wherein the catalytic nanowire comprises MgO, CaO, La2O3, Na2WO4, Mn2O3, Mn3O4, Nd2O3, Sm2O3, Eu2O3, Pr2O3, Mg6MnO8, NaMnO4, Na/Mn/W/O, MnWO4 or combinations thereof.

27. The method of claim 2, wherein the catalytic nanowire further comprises one or more dopants comprising metal elements, semi-metal elements, non-metal elements or combinations thereof.

28. The method of claim 27, wherein the dopant comprises Li, Na, K, Mg, Ca, Ba, Sr, Eu, Sm, Co or Mn.

29. The method of claim 28, wherein the catalytic nanowire comprises Li/MgO, Ba/MgO, Sr/La2O3, Mg/Na/La2O3, Sr/Nd2O3, or Mn/Na2WO4.

30. The method of claim 27, wherein the atomic ratio of the one or more elements from Groups 1 through 7, lanthanides or actinides to the dopant ranges from 1:1 to 10,000:1.

31. The method of claim 2, wherein the catalytic nanowire comprises a combination of two or more compounds comprising the one or more elements.

32. The method of claim 31, wherein the catalytic nanowire comprises Mn2O3/Na2WO4, Mn3O4/Na2WO4MnWO4/Na2WO4/Mn2O3, MnWO4/Na2WO4/Mn3O4 or NaMnO4/MgO.

33. The method of claim 2, wherein the catalytic nanowire has a diameter of between 7 nm and 200 nm as determined by TEM in bright field mode at 5 keV.

34. The method of claim 2, wherein the catalytic nanowire has an actual length of between 100 nm and 10 μm as determined by TEM in bright field mode at 5 keV.

35. The method of claim 2, wherein the catalytic nanowire has a ratio of effective length to actual length of less than 0.8.

36. The method of claim 2, wherein the powder x-ray diffraction pattern of the catalytic nanowire shows an average crystalline domain size of less than 50 nm.

37. The method of claim 2, wherein the catalytic nanowire further comprises a support material.

38. The method of claim 37, wherein the support material comprises an inorganic oxide, Al2O3, SiO2, TiO2, MgO, ZrO2, HfO2, CaO, ZnO, LiAlO2, MgAl2O4, MnO, MnO2, Mn2O4, Mn3O4, La2O3, activated carbon, silica gel, zeolites, activated clays, activated Al2O3, diatomaceous earth, magnesia, aluminosilicates, calcium aluminate, support nanowires or combinations thereof.

39. The method of claim 2, wherein the catalytic nanowire comprises an inner core and an outer layer, the inner core and outer layer each independently comprising one or more elements selected from Groups 1 through 7, lanthanides and actinides.

40. The method of claim 2, wherein the ethylene has been prepared via the oxidative coupling of methane (OCM) reaction.

41. The method of claim 40, wherein the oxidative coupling of methane reaction is performed in the presence of air.

42. The method of claim 2, wherein the downstream product of ethylene is natural gasoline.

43. The method of claim 2, wherein the downstream product of ethylene comprises 1-hexene, 1-octene or combinations thereof.

44. The method of claim 3, wherein the one or more elements are in the form of oxides.

45. The method of claim 3, wherein the one or more elements are in the form of hydroxides.

46. The method of claim 3, wherein the catalytic nanowire comprises Mg, Ca, La, W, Mn, Mo, Nd, Sm, Eu, Pr, Zr or combinations thereof.

47. The method of claim 3, wherein the catalytic nanowire comprises MgO, CaO, La2O3, Na2WO4, Mn2O3, Mn3O4, Nd2O3, Sm2O3, Eu2O3, Pr2O3, Mg6MnO8, NaMnO4, Na/Mn/W/O, MnWO4 or combinations thereof.

48. The method of claim 3, wherein the catalytic nanowire further comprises one or more dopants comprising metal elements, semi-metal elements, non-metal elements or combinations thereof.

49. The method of claim 48, wherein the dopant comprises Li, Na, K, Mg, Ca, Ba, Sr, Eu, Sm, Co or Mn.

50. The method of claim 49, wherein the catalytic nanowire comprises Li/MgO, Ba/MgO, Sr/La2O3, Mg/Na/La2O3, Sr/Nd2O3, or Mn/Na2WO4.

51. The method of claim 48, wherein the atomic ratio of the one or more elements from Groups 1 through 7, lanthanides or actinides to the dopant ranges from 1:1 to 10,000:1.

52. The method of claim 3, wherein the catalytic nanowire comprises a combination of two or more compounds comprising the one or more elements.

53. The method of claim 52, wherein the catalytic nanowire comprises Mn2O3/Na2WO4, Mn3O4/Na2WO4MnWO4/Na2WO4/Mn2O3, MnWO4/Na2WO4/Mn3O4 or NaMnO4/MgO.

54. The method of claim 3, wherein the catalytic nanowire has a diameter of between 7 nm and 200 nm as determined by TEM in bright field mode at 5 keV.

55. The method of claim 3, wherein the catalytic nanowire has an actual length of between 100 nm and 10 μm as determined by TEM in bright field mode at 5 keV.

56. The method of claim 3, wherein the catalytic nanowire has a ratio of effective length to actual length of less than 0.8.

57. The method of claim 3, wherein the powder x-ray diffraction pattern of the catalytic nanowire shows an average crystalline domain size of less than 50 nm.

58. The method of claim 3, wherein the catalytic nanowire further comprises a support material.

59. The method of claim 58, wherein the support material comprises an inorganic oxide, Al2O3, SiO2, TiO2, MgO, ZrO2, HfO2, CaO, ZnO, LiAlO2, MgAl2O4, MnO, MnO2, Mn2O4, Mn3O4, La2O3, activated carbon, silica gel, zeolites, activated clays, activated Al2O3, diatomaceous earth, magnesia, aluminosilicates, calcium aluminate, support nanowires or combinations thereof.

60. The method of claim 3, wherein the catalytic nanowire comprises an inner core and an outer layer, the inner core and outer layer each independently comprising one or more elements selected from Groups 1 through 7, lanthanides and actinides.

61. The method of claim 3, wherein the methane is converted into ethylene via the oxidative coupling of methane (OCM) reaction.

62. The method of claim 61, wherein the oxidative coupling of methane reaction is performed in the presence of air.

63. The method of claim 3, wherein the downstream product of ethylene is natural gasoline.

64. The method of claim 3, wherein the downstream product of ethylene comprises 1-hexene, 1-octene or combinations thereof.

65. The method of claim 1, wherein the temperature ranges from 550° C. to below 600° C.

66. The method of claim 2, wherein the temperature ranges from 550° C. to below 600° C.

67. The method of claim 3, wherein the temperature ranges from 550° C. to below 600° C.

68. The method of claim 1, wherein the temperature ranges from 500° C. to 550° C.

69. The method of claim 2, wherein the temperature ranges from 500° C. to 550° C.

70. The method of claim 3, wherein the temperature ranges from 500° C. to 550° C.