# APPENDIX E1

Nonroad Sources Emissions Estimation Methodology

2002

Bureau of Air Quality Department of Environmental Protection

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## APPENDIX E

- 1

PENNSYLVANIA NONROAD SOURCE EMISSIONS

ESTIMATION METHODOLOGY

Bureau of Air Quality Department of Environmental Protection

### 1



## METHODOLOGY FOR ESTI MATING NONROAD EMISS IONS

I. INTRODUCTION

This following methodology provides a description of the procedures used to generate 2002 county

- level pollutant emission estimates for nonroad mobile engines included in the United States Environmental Protection Agency’s (EPA’s) NONROAD2005 model and the National Mobile Inventory Model. E mission estimates for l ocomotive engines and aircraft operations were estimated separately . For the NONROAD2005 model engines, emission estimates were calculated for particulate matter ( PM10 and PM2.5), sulfur dioxide (SO2), nitrogen oxides (NOx), volatil e organic compounds (VOCs), and ammonia (NH3). Revised geographic allocation files for NONROAD model option files and revised housing unit data used for the model runs are also included.



## II. 2002 NONROAD MODEL S OURCE CATEGORY EMISS IONS

The Department used EPA’s Final NONROAD2005 Model to generate 2002 emissions for Bucks, Chester, Delaware, Montgomery and Philadelphia c ount ies in Pennsylvania. The Department prepared NONROAD2005 model option files that account for temperatures and gasoline Reid vapor pressure (RVP) values representative of the area . Pennsylvania was separated into four climate zones for the Maintenance Plans: East North, East South, West North, and West South for the inventories for all maintenance plans. A five

- county area in East South and a seven

- county area in West South were calculated separately because of the fuel regulatory requirements in those areas. The summertime RVP val ue used for each region was 9.0 except where noted. Minimum, maximum, and average temperatures for July for each region were obtained from the Pennsylvania State Climatologist website, Pennsylvania State Climatologist, Penn State University, 2002 Temperature Data by Weather Station which is available at http://pasc.met.psu.edu/PA_Climatologist/cityform.html . The RVP and temperature inputs were applied to all equipment categories to obtain both summer day and annual emissions.

Table 1 lists the counties included i n each of the four regions and the weather station where the temperature data were obtained for each of the regions. Table 2 presents the RVP and temperature data used in the model runs for each region of Pennsylvania.

### 2 Table 1. Re gions of Pennsylvania and Associated PM2.5 Maintenance Areas

Region Weather Station Counties in Region FIPSST FIPSCNTY East North Scranton None 42 East South Harrisburg Berks County Bucks County * Chester County * 42 42 42 011

017 029 Cumberland County 42 041 Dauphin County Delaware County * 42 42 043

045 Lancaster County 42 071 Lebanon County Lehigh County Montgomery County * Northampton County Philadelphia County * 42 42 42 42 42 075

077 091 095 101 York County 42 133 Philadelphia ar ea* West North Erie None 42 West South Altoona Allegheny County * 42 003 Armstrong County * 42 005 Beaver County * 42 007 Butler County * 42 019 Cambria County 42 021 Greene County 42 059 Indiana County 42 063 Lawrence County 42 073 Washington County * 42 125 Westmoreland County * 42 129

### 3 Table 2. NONROAD Model Temperature and RVP Inputs

Temperature* Region Season Maximum Minimum Average RVP**

East North Spring 59 40 50

9.0

Summer 83 60 72 Autumn 60 42 51 Winter 40 24 32

East South Spring 62 42 52

9.0

Summer 86 66 76 Autumn 63 46 55 Winter 43 26 35

Philadelphia Spring 65 45 55

6.7

Summer 87 69 78 Autumn 66 51 58 Winter 46 31 38

Pittsburgh Spring 60 39 50 9.0

Su mmer 84 63 73 7.8 Autumn 61 44 53 8.8 Winter 41 26 34 9.0

West North Spring 55 37 46

9.0

Summer 80 63 71 Autumn 60 46 53 Winter 39 27 33

West South Spring 59 38 48

9.0

Summer 82 60 71 Autumn 60 43 51 Winter 40 25 32 * Temper ature in degrees Fahrenheit ** RVP in pounds per square inch (psi)



### EPA

- recommended diesel fuel sulfur levels for marine and land equipment for all years were used as inputs to the model, as outlined in Diesel Fuel Sulfur In puts for the Draft NONROAD2004 Model used in the 2004 Nonroad Diesel Engine Fuel Rule , April 27, 2004.

In past versions of the NONROAD model, state recreational marine vessels populations were underestimated when compared to boat registrations tracked b y the Pennsylvania Fish and Boat Commission (PFBC). EPA’s population of recreational marine vessels in the model now seem more representative of the number of boat registrations that the Pennsylvania Fish and Boat Commission tracks. We used EPA’s default values in the model runs. We also examined geographic allocation factors for residential lawn and garden equipment. These improvements are discussed further in the next section. All other categories rely on default data included in the model for popula tion and activity estimates.

Residential Lawn and Garden Equipment

The EPA’s NONROAD2005 model uses 2003 U.S. Census data of all housing units in Pennsylvania to allocate residential lawn and garden equipment, even though EPA guidan ce states that emissions should be based only on the number of single detached, single attached, and double housing units. EPA’s method in the NONROAD2005 model alters the allocation of lawn and garden emissions in some Pennsylvania counties significantly . The Department used data obtained by E.H. Pechan from the 2000

### 4

Census, updated to 2002, and used in the state’s 2002 inventory on the number of single detached, single attached, and double housing units for both the State and all counties in the state. Table 3 presents the Census data (Bureau of the Census, 2003), which can be found in 2000 County and State Housing Units by Unit Type, Census 2000, http://factfinder.census.gov/servlet/. The total number of housing units was incorporated into the NONROAD 2005 model geographic allocation factor file, PA HOUSE.ALO, for use in allocating state

- level lawn and garden equipment populations to all Pennsylvania counties for 2002.

Table 3. Number of Single and Double

- Family Housing Units f rom 2002 Census

County # 1

- Unit Detached

Housing Units # 1

- Unit Attached

Housing Units # 2

- Unit

Housing Units Total # of

Housing Units Adams 24,549 2,206 1,490 28,245 Allegheny 345,479 46,899 29,002 421,380 Armstrong 22,268 824 1,014 24,106 Beaver 54,418 2,312 2,863 59,593 Bedford 14,684 248 501 15,433 Berks 78,946 32,377 5,803 117,126 Blair 36,919 1,844 2,668 41,431 Bradford 16,861 232 1,224 18,317 Bucks 141,951 30,506 5,425 177,882 Butler 46,271 2,523 2,215 51,009 Cambria 44,453 3,795 2,882 51,130 Cameron 1,749 35 176 1,960 Carbon 14,431 5,104 990 20,525 Centre 27,786 2,691 1,749 32,226 Chester 99,549 25,911 3,155 128,615 Clarion 11,635 118 471 12,224 Clearfield 24,829 412 1,064 26,305 Clinton 10,141 662 711 11,514 Columbia 16,856 1, 328 1,388 19,572 Crawford 24,430 397 1,933 26,760 Cumberland 51,934 10,450 2,792 65,176 Dauphin 52,961 20,195 3,848 77,004 Delaware 93,642 64,529 9,361 167,532 Elk 11,355 79 807 12,241 Erie 70,504 2,955 9,504 82,963 Fayette 41,679 3,094 2,473 47,246 Forest 1,660 8 18 1,686 Franklin 34,720 4,292 2,073 41,085 Fulton 4,084 56 133 4,273 Greene 10,387 481 416 11,284 Huntingdon 12,463 331 686 13,480 Indiana 23,215 825 1,232 25,272 Jefferson 14,276 237 729 15,242 Juniata 6,455 355 166 6,976 Lackawa nna 53,357 3,328 12,626 69,311 Lancaster 98,364 32,122 7,370 137,856 Lawrence 28,316 799 1,489 30,604 Lebanon 27,272 8,647 2,225 38,144 Lehigh 59,753 29,474 5,118 94,345 Luzerne 82,363 15,404 9,435 107,202 Lycoming 31,568 2,812 2,998 37,378 McKean 1 3,794 158 972 14,924 Mercer 34,859 735 1,817 37,411

### 5 Table 3. Number of Single and Double

- Family Housing Units f rom 2002 Census County # 1

- Unit Detached

Housing Units # 1

- Unit Attached

Housing Units # 2

- Unit

Housing Units Total # of

Housing Units Mifflin 12,327 1,788 966 15,081 Monroe 40,696 1,726 1,457 43,879 Montgomery 163,211 53,370 9,599 226,180 Montour 4,769 645 346 5,760 Northampton 60,344 19,729 4,755 84,828 Northumberland 21,955 9,2 80 1,657 32,892 Perry 12,209 733 398 13,340 Philadelphia 48,724 359,877 46,425 455,026 Pike 15,501 395 299 16,195 Potter 5,263 62 281 5,606 Schuylkill 32,695 17,989 2,092 52,776 Snyder 10,263 644 526 11,433 Somerset 22,159 1,236 1,312 24,707 Sulliv an 2,165 18 84 2,267 Susquehanna 12,139 180 711 13,030 Tioga 11,076 150 753 11,979 Union 9,341 652 527 10,520 Venango 17,197 227 1,080 18,504 Warren 13,031 239 930 14,200 Washington 60,711 3,891 3,187 67,789 Wayne 14,311 249 750 15,310 Westmoreland 113,694 4,839 5,997 124,530 Wyoming 7,858 159 412 8,429 York 95,921 20,218 6,102 122,241 Total 2,724,746 860,086 235,658 3,820,490



### After the model runs, model outputs were processed to develop emissions inventories for PM10, PM2 .5, SO2, NOx, VOC, and NH3 . Nonroad equipment refueling, either by portable container or at the gasoline pump, is being accounted for under Pennsylvania’s area source inventory. As such, spillage and vapor displacement VOC emission estimates were subtrac ted from the total VOC emission estimates for all NONROAD model emissions. Therefore, only exhaust, crankcase, and evaporative diurnal components are included in these VOC estimates.

Emissions from nonroad equipment were tabulated in both source classifi cation code and category format. Immaterial rounding errors may exist when comparing the two formats due to different arithmetic operations performed inside and outside the NONROAD model for the two formats.



## III. 2002 LOCOMOTIVE EMIS SIONS

Much of the lo comotive emissions were obtain ed from a 1999 survey conducted by the Department included hydrocarbon (HC) and NO x 

### for the following locomotive source categories:

2285002006 : Railroad Equipment, Diesel, Line Haul Locomotives: Class I Operations 228500200 7: Railroad Equipment, Diesel, Line Haul Locomotives: Class II/III Operations 2285002008: Railroad Equipment, Diesel, Line Haul Locomotives: Passenger Trains (Amtrak)

### 6

2285002010: Railroad Equipment, Diesel, Yard Locomotives

All line haul locomotive emi ssions were grouped into one SCC category in the appendix, 2285002005.

Norfolk Southern and CSX Corporations purchased Conrail. The takeover of Conrail’s assets occurred in June 1999. For that reason, it was a very bad time to develop a representative

e mission inventory for these railroads. Both Conrail and Norfolk Southern suffered major gridlock in Pennsylvania and beyond during 1999. Consequently, fuel consumption and air emissions for these two railroads were greatly reduced in 1999. Therefore, th e Department requested and received 2002 fuel usage from these railroad companies and developed a 2002 emissions inventory for them. Fuel consumption showed an increase of 60 percent from 1999 to 2002 for these companies, clearly not due to normal economi c growth.

Emissions from all other railroad companies operating in Pennsylvania in 1999 were grown with a growth factor to obtain 2002 emissions.

To estimate VOC emissions from HC, the Department applied a VOC/HC conversion factor of 1.005 to the HC emissions. This conversion factor was obtained from EPA’s Documentation for Aircraft, Commercial Marine Vessel, Locomotive, and Other Nonroad Components of the National Emission Inventory, Volume I: Methodology (EPA, 2002).



## IV. AIRCR AFT EMISSIONS

Emissions from air carriers for 2002 are estimated using the Emissions & Dispersion Modeling System (EDMS) 4.20. The area has two airports which have air carrier operations (an aircraft that can seat more than 60 passengers). Also, some information from the model is used in estimating emissions from the smaller airports in the area

. Commercial airport operations data. Airport specific data on operations were found at www.transtats.bts.gov and also the FAA’s Terminal Area Forecast found at http://www.apo.data.faa.gov. Operations data on all significantly large regional airports in Pennsylvania could be found at this website, although some of the airports modeled supported very few commerci al flights. The Department used default values in the EDMS model for aircraft engines and service equipment for each aircraft type. These emissions covered all air carrier and air taxi service at these airports.

Mixing height in EDMS. It was determine d that a better mixing height than the model’s default value could be used in EDMS. Upper air meteorological data available from Sterling Virginia in combination with surface data measurements taken at the Philadelphia International Airport generated 1

- hr mixing heights in the meteorological preprocessor model PCRAMMET, EPA, PCRAMMET (software), Research Triangle Park, NC, June 1999. All mixing heights between 10 a.m. and 6 p.m. were not considered when generating these averages because an extremely small percentage of flight operations occur between those hours. The average summer mixing height was 4,428 feet for airports in the Eastern Penn sylvania, including airports in this area. The default value of 3000 feet was used for all other airports.

### 7

Air t axi emission estimation methodology. Air taxi operations occur at several airports in the

area. The Department used emission factors from EDMS for a common aircraft used in air taxi service to calculate emissions from air taxi operations. Air taxi groun d support equipment emission estimates produced by the NONROAD model were used.

Small airport emission estimation methodology. Small aircraft emissions were calculated by using small airport operation statistics, which can be found at www.airnav.com . An emissions factor for a typical air general aviation single engine, multi

- engine, and jet engine aircraft were derived by averaging the emissions factors from a basket of emission factors for common aircraft of each of the three types of aircraft. Emission factors and operational characteristics contained in EDMS were used. The proportion of operations between the three groups of aircraft was determined by examining the number of each aircraft type based at each air port. For military operations at small airports, the type of aircraft and its emission factors are sometimes identifiable. If not, emission factors calculated to represent an “average” military aircraft are used.

# APPENDIX E 2

Nonroad Source Emissions

2002 (Provided in Electronic Form Only)

Bureau of Air Quality Department of Environmental Protection

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. ]Philadelphia AreaNOXVOC PM2.5 SO2 NH3 PM10Bucks 3517.6 4695.1 292.0 254.1 2.8 307.1Chester 3375.8 3746.5 303.5 283.5 2.7 317.8Delaware 2559.6 2689.7 176.5 162.3 1.5 186.7Montgomery 4926.0 6116.8 402.3 355.8 4.0 422.6Philadelphia 7240.0 4341.0 360.8 584.9 3.0 377.2Total Philadelphia Area 21619.1 21589.1 1535.0 1640.5 14.0 1611.4Notes: NH3 from NMIMAll other pollutants are from NONROAD model spreadsheets for individualNonroad Emissions Inventory Summary2002 Emissions (Tons per Year)

# APPENDIX E 3

Nonroad Source Emissions 2007, 2017, 2025 (Provided in Electronic Form Only)

Bureau of Air Quality Department of Environmental Protection

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. ]Only includes those counties located in PM2.5 annual or 24

‐ hour nonattainment areas

State FIPS CNTY_NA M AREA 24

‐ hr Annual SCC SECTOR SCC_DESC R GROWTH F PA 42017 Bucks Philadelph i Yes Yes 22750010 0 AIR Aircraft / M FAA Termi n PA 42017 Bucks Philadelph i Yes Yes 22750500 1 AIR Aircraft /G e FAA Termi n PA 42017 Bucks Philadelph i Yes Yes 22750500 1 AIR Aircraft /G e FAA Termi n PA 42017 Bucks Philadelph i Yes Yes 22750600 1 AIR Aircraft /Ai FAA Termi n PA 42017 Bucks Philadelph i Yes Yes 22750600 1 AIR Aircraft /Ai FAA Termi n PA 42017 Bucks Philadelph i Yes Yes 22800021 0 CMV Marine Ve s AEO2010 T PA 42017 Bucks Philadelph i Yes Yes 22800022 0 CMV Marine Ve s AEO2010 T PA 42017 Bucks Philadelph i Yes Yes 22800031 0 CMV Marine Ve s AEO2010 T PA 42017 Bucks Philadelph i Yes Yes 22800032 0 CMV Marine Ve s AEO2010 T PA 42017 Bucks Philadelph i Yes Yes 22850020 0 RAIL Railroad E q AEO2010 T PA 42017 Bucks Philadelph i Yes Yes 22850020 0 RAIL Railroad E q AEO2010 T PA 42017 Bucks Philadelph i Yes Yes 22850020 0 RAIL Railroad E q AEO2010 T PA 42017 Bucks Philadelph i Yes Yes 22850020 1 RAIL Railroad E q AEO2010 T PA 42029 Chester Philadelph i Yes Yes 22750010 0 AIR Aircraft / M FAA Termi n PA 42029 Chester Philadelph i Yes Yes 22750500 1 AIR Aircraft /G e FAA Termi n PA 42029 Chester Philadelph i Yes Yes 22750500 1 AIR Aircraft /G e FAA Termi n PA 42029 Chester Philadelph i Yes Yes 22750600 1 AIR Aircraft /Ai FAA Termi n PA 42029 Chester Philadelph i Yes Yes 22750600 1 AIR Aircraft /Ai FAA Termi n PA 42029 Chester Philadelph i Yes Yes 22850020 0 RAIL Railroad E q AEO2010 T PA 42029 Chester Philadelph i Yes Yes 22850020 0 RAIL Railroad E q AEO2010 T PA 42029 Chester Philadelph i Yes Yes 22850020 0 RAIL Railroad E q AEO2010 T PA 42045 Delaware Philadelph i Yes Yes 22650080 0 AIR Airport Gr o FAA Termi n PA 42045 Delaware Philadelph i Yes Yes 22670080 0 AIR Airport Gr o FAA Termi n PA 42045 Delaware Philadelph i Yes Yes 22680080 0 AIR Airport Gr o FAA Termi n PA 42045 Delaware Philadelph i Yes Yes 22700080 0 AIR Airport Gr o FAA Termi n PA 42045 Delaware Philadelph i Yes Yes 22750010 0 AIR Aircraft / M FAA Termi n PA 42045 Delaware Philadelph i Yes Yes 22750200 0 AIR Aircraft /C o FAA Termi n PA 42045 Delaware Philadelph i Yes Yes 22750500 1 AIR Aircraft /G e FAA Termi n PA 42045 Delaware Philadelph i Yes Yes 22750500 1 AIR Aircraft /G e FAA Termi n PA 42045 Delaware Philadelph i Yes Yes 22750600 1 AIR Aircraft /Ai FAA Termi n PA 42045 Delaware Philadelph i Yes Yes 22750600 1 AIR Aircraft /Ai FAA Termi n PA 42045 Delaware Philadelph i Yes Yes 22750700 0 AIR Aircraft /Ai FAA Termi n PA 42045 Delaware Philadelph i Yes Yes 22800021 0 CMV Marine Ve s AEO2010 T PA 42045 Delaware Philadelph i Yes Yes 22800022 0 CMV Marine Ve s AEO2010 T PA 42045 Delaware Philadelph i Yes Yes 22800031 0 CMV Marine Ve s AEO2010 T PA 42045 Delaware Philadelph i Yes Yes 22800032 0 CMV Marine Ve s AEO2010 T PA 42045 Delaware Philadelph i Yes Yes 22850020 0 RAIL Railroad E q AEO2010 T PA 42045 Delaware Philadelph i Yes Yes 22850020 0 RAIL Railroad E q AEO2010 T PA 42045 Delaware Philadelph i Yes Yes 22850020 0 RAIL Railroad E q AEO2010 T PA 42091 Montgom e Philadelph i Yes Yes 22650080 0 AIR Airport Gr o FAA Termi n PA 42091 Montgom e Philadelph i Yes Yes 22670080 0 AIR Airport Gr o FAA Termi n PA 42091 Montgom e Philadelph i Yes Yes 22680080 0 AIR Airport Gr o FAA Termi n PA 42091 Montgom e Philadelph i Yes Yes 22700080 0 AIR Airport Gr o FAA Termi n PA 42091 Montgom e Philadelph i Yes Yes 22750010 0 AIR Aircraft / M FAA Termi nPA 42091 Montgom e Philadelph i Yes Yes 22750200 0 AIR Aircraft /C o FAA Termi n PA 42091 Montgom e Philadelph i Yes Yes 22750500 1 AIR Aircraft /G e FAA Termi n PA 42091 Montgom e Philadelph i Yes Yes 22750500 1 AIR Aircraft /G e FAA Termi n PA 42091 Montgom e Philadelph i Yes Yes 22750600 1 AIR Aircraft /Ai FAA Termi n PA 42091 Montgom e Philadelph i Yes Yes 22750600 1 AIR Aircraft /Ai FAA Termi n PA 42091 Montgom e Philadelph i Yes Yes 22750700 0 AIR Aircraft /Ai FAA Termi n PA 42091 Montgom e Philadelph i Yes Yes 22850020 0 RAIL Railroad E q AEO2010 T PA 42091 Montgom e Philadelph i Yes Yes 22850020 0 RAIL Railroad E q AEO2010 T PA 42091 Montgom e Philadelph i Yes Yes 22850020 0 RAIL Railroad E q AEO2010 T PA 42091 Montgom e Philadelph i Yes Yes 22850020 1 RAIL Railroad E q AEO2010 T PA 42101 Philadelph i Philadelph i Yes Yes 22650080 0 AIR Airport Gr o FAA Termi n PA 42101 Philadelph i Philadelph i Yes Yes 22670080 0 AIR Airport Gr o FAA Termi n PA 42101 Philadelph i Philadelph i Yes Yes 22680080 0 AIR Airport Gr o FAA Termi n PA 42101 Philadelph i Philadelph i Yes Yes 22700080 0 AIR Airport Gr o FAA Termi n PA 42101 Philadelph i Philadelph i Yes Yes 22750200 0 AIR Aircraft /C o FAA Termi n PA 42101 Philadelph i Philadelph i Yes Yes 22750500 1 AIR Aircraft /G e FAA Termi n PA 42101 Philadelph i Philadelph i Yes Yes 22750500 1 AIR Aircraft /G e FAA Termi n PA 42101 Philadelph i Philadelph i Yes Yes 22750600 1 AIR Aircraft /Ai FAA Termi n PA 42101 Philadelph i Philadelph i Yes Yes 22750600 1 AIR Aircraft /Ai FAA Termi n PA 42101 Philadelph i Philadelph i Yes Yes 22750700 0 AIR Aircraft /Ai FAA Termi n PA 42101 Philadelph i Philadelph i Yes Yes 22800021 0 CMV Marine Ve s AEO2010 T PA 42101 Philadelph i Philadelph i Yes Yes 22800022 0 CMV Marine Ve s AEO2010 T PA 42101 Philadelph i Philadelph i Yes Yes 22800031 0 CMV Marine Ve s AEO2010 T PA 42101 Philadelph i Philadelph i Yes Yes 22800032 0 CMV Marine Ve s AEO2010 T PA 42101 Philadelph i Philadelph i Yes Yes 22850020 0 RAIL Railroad E q AEO2010 T PA 42101 Philadelph i Philadelph i Yes Yes 22850020 0 RAIL Railroad E q AEO2010 T PA 42101 Philadelph i Philadelph i Yes Yes 22850020 0 RAIL Railroad E q AEO2010 T PA 42101 Philadelph i Philadelph i Yes Yes 22850020 0 RAIL Railroad E q AEO2010 T PA 42101 Philadelph i Philadelph i Yes Yes 22850020 1 RAIL Railroad E q AEO2010 TGrowth Factors GF_07_13 GF_07_17 GF_07_20 GF_07_25 CONTROL F NH3_2007 NH3_17_G NH3_17_C F NH3_17_G NH3_25_G 1111 0100 1.046817 1.086037 1.11629 1.169 0100 1.046817 1.086037 1.11629 1.169 0100

1.04894 1.08884 1.119701 1.175 0100 1.04894 1.08884 1.119701 1.175 0100 0.975 1.003 1.033 1.064 2008 Final 0.299649 0.300547 1 0.300547 0.318826 0.975 1.003 1.033 1.064 2008 Final 0.0213 0.021364 1 0.021364 0.022663

0.94 0.946 0.95 0.956 Cat 3 Mari n 0.059525 0.05631 1 0.05631 0.056906 0.94 0.946 0.95 0.956 Cat 3 Mari n 0.003254 0.003078 1 0.003078 0.003111 0.969 1.018 1.053 1.098 2008 Final 0.049472 0.050362 1 0.050362 0.05432 0.969 1.018 1.053 1.098 2008 Final 0.015372 0.015649 1 0.015649 0.016879 1.046 1.121 1.171 1.241 2008 Final Locomotiv e 0100 0.969 1.018 1.053 1.098 2008 Final 0.002376 0.002419 1 0.002419 0.002609 1111 0100 0.956753 0.99273 1.020686 1.069 0100 0.956753 0.99273 1.020686 1.069 0100 0.9488 0.983467 1.0104 1.058 0100 0.9488 0.983467 1.0104 1.058 0100

0.969 1.018 1.053 1.098 2008 Final 0.020774 0.021148 1 0.021148 0.022809 0.969 1.018 1.053 1.098 2008 Final 0.02004 0.020401 1 0.020401 0.022004 1.046 1.121 1.171 1.241 2008 Final Locomotiv e 0100 0.984451 1.116874 1.211265 1.387 0100 0.984451 1.116874 1.211265 1.387 0100 0.984451 1.116874 1.211265 1.387 0100 0.984451 1.116874 1.211265 1.387 0100

0.69254 0.69254 0.69254 0.69254 0100 1.021659 1.149869 1.252826 1.445 0100 0.854597 0.890201 0.915785 0.96 0100 0.854597 0.890201 0.915785 0.96 0100 0.952253 1.103093 1.194878 1.365 0100 0.952253 1.103093 1.194878 1.365 0100 0.984451 1.116874 1.211265 1.387 0100 0.975 1.003 1.033 1.064 2008 Final 1.754541 1.759805 1 1.759805 1.866832 0.975 1.003 1.033 1.064 2008 Final 0.560401 0.562082 1 0.562082 0.596267

0.94 0.946 0.95 0.956 Cat 3 Mari n 0.650904 0.615755 1 0.615755 0.622264 0.94 0.946 0.95 0.956 Cat 3 Mari n 0.042075 0.039803 1 0.039803 0.040224 0.969 1.018 1.053 1.098 2008 Final 0.047309 0.04816 1 0.04816 0.051945 0.969 1.018 1.053 1.098 2008 Final 0.008684 0.00884 1 0.00884 0.009535 1.046 1.121 1.171 1.241 2008 Final Locomotiv e 0100 1.046758 1.085718 1.115952 1.168 0100 1.046758 1.085718 1.115952 1.168 0100 1.046758 1.085718 1.115952 1.168 0100 1.046758 1.085718 1.115952 1.168 0100 1111 01001111 0100 1.047049 1.086265 1.116782 1.169 0100 1.047049 1.086265 1.116782 1.169 0100 1.046918 1.085991 1.116184 1.169 0100 1.046918 1.085991 1.116184 1.169 0100 1.046758 1.085718 1.115952 1.168 0100 0.969 1.018 1.053 1.098 2008 Final 0.086664 0.088224 1 0.088224 0.095157 0.969 1.018 1.053 1.098 2008 Final 0.002482 0.002527 1 0.002527 0.002725 1.046 1.121 1.171 1.241 2008 Final Locomotiv e 0100 0.969 1.018 1.053 1.098 2008 Final 0.011884 0.012098 1 0.012098 0.013049 0.691116 0.745643 0.789673 0.869 0100 0.691116 0.745643 0.789673 0.869 0100 0.691116 0.745643 0.789673 0.869 0100 0.691116 0.745643 0.789673 0.869 0100 1111 0100 0.699093 0.760267 0.809665 0.899 0100 0.699093 0.760267 0.809665 0.899 0100 0.625675 0.625675 0.625675 0.625675 0100 0.625675 0.625675 0.625675 0.625675 0100 0.691116 0.745643 0.789673 0.869 0100 0.975 1.003 1.033 1.064 2008 Final 2.744227 2.75246 1 2.75246 2.919858 0.975 1.003 1.033 1.064 2008 Final 0.299496 0.300394 1 0.300394 0.318663

0.94 0.946 0.95 0.956 Cat 3 Mari n 1.051471 0.994692 1 0.994692 1.005207 0.94 0.946 0.95 0.956 Cat 3 Mari n 0.029237 0.027658 1 0.027658 0.027951 0.969 1.018 1.053 1.098 2008 Final 0.069867 0.071124 1 0.071124 0.076714 0.969 1.018 1.053 1.098 2008 Final 0.012733 0.012962 1 0.012962 0.013981 1.046 1.121 1.171 1.241 2008 Final Locomotiv e 0100 1.046 1.121 1.171 1.241 2008 Final 0.016504 0.018501 1 0.018501 0.020482 0.969 1.018 1.053 1.098 2008 Final 00100 7.880241 7.806366 7.806366 8.20098NH3_25_C F NH3_25_G NOX_2007 NOX_17_G NOX_17_C NOX_17_G NOX_25_G NOX_25_C NOX_25_G P10_2007 1 0 0.000632 0.000632 1 0.000632 0.000632 1 0.000632 0.002413 1 0 3.853703 4.185264 1 4.185264 4.504979 1 4.504979 14.03341 1 0 1.498662 1.627603 1 1.627603 1.751936 1 1.751936 5.457436 1 0 0.092089 0.10027 1 0.10027 0.108204 1 0.108204 0.351453 1 0 0.035812 0.038994 1 0.038994 0.042079 1 0.042079 0.136751 1 0.318826 86.5084 86.76793 0.642 55.70501 92.04494 0.401 36.91002 2.7034 1 0.022663 10.2571 10.28787 0.642 6.604813 10.91355 0.401 4.376335 0.3205 1 0.056906 73.85477 69.86661 0.654 45.69276 70.60516 0.48 33.89048 5.51155 1 0.003111 8.029695 7.596091 0.654 4.967844 7.676388 0.48 3.684666 0.682136 1 0.05432 108.2979 110.2473 0.633 69.78653 118.9111 0.412 48.99138 3.684957 1 0.016879 49.90006 50.79826 0.96 48.76633 54.79027 0.852 46.68131 1.228309 1000 0.421 0 0 0.241 0 0 1 0.002609 6.076216 6.185588 0.843 5.214451 6.671685 0.634 4.229848 0.190803 1 0 0.009875 0.009875 1 0.009875 0.009875 1 0.009875 0.037708 1 0 2.837538 2.816908 1 2.816908 3.033328 1 3.033328 10.333 1 0 1.103487 1.095464 1 1.095464 1.179627 1 1.179627 4.01839 1 0 0.142883 0.14052 1 0.14052 0.15117 1 0.15117 0.545305 1 0 0.055565 0.054647 1 0.054647 0.058788 1 0.058788 0.212179 1 0.022809 41.50648 42.25359 0.633 26.74652 45.57411 0.412 18.77653 1.555282 1 0.022004 65.05122 66.22215 0.96 63.57326 71.42624 0.852 60.85516 1.601261 1 0 17.29732 19.3903 0.421 8.163316 21.46598 0.241 5.173301 0.42578 1000100100 1000100100 1000100100 1 0 276.189 308.4682 1 308.4682 383.0741 1 383.0741 7.922 100010010 0.275722 1 0 2221.733 2554.703 1 2554.703 3210.405 1 3210.405 32.9354 1 0 0.284284 0.25307 1 0.25307 0.272913 1 0.272913 0.726518 1 0 37.09806 33.02474 1 33.02474 35.61414 1 35.61414 3.312459 1000100100 1 0 160.415 176.9526 1 176.9526 218.9664 1 218.9664 4.385627 1 0 31.17194 34.81511 1 34.81511 43.23548 1 43.23548 4.006516 1 1.866832 428.5984 429.8842 0.642 275.9857 456.0287 0.401 182.8675 13.3937 1 0.596267 50.8182 50.97065 0.642 32.72316 54.07056 0.401 21.6823 1.5881 1 0.622264 711.9567 673.511 0.654 440.4762 680.6306 0.48 326.7027 63.27267 1 0.040224 99.73487 94.34918 0.654 61.70437 95.34653 0.48 45.76634 8.820803 1 0.051945 100.0327 101.8333 0.633 64.46049 109.8359 0.412 45.25241 3.539976 1 0.009535 28.1895 28.69691 0.96 27.54904 30.95207 0.852 26.37117 0.693895 1 0 2.531316 2.837605 0.421 1.194632 3.141363 0.241 0.757068 0.062309 1 0 0.000427 0.000463 1 0.000463 0.000498 1 0.000498 1.71E

‐ 05 1 0 4.19E

‐ 05 4.55E

‐ 05 1 4.55E

‐ 05 4.9E

‐ 05 1 4.9E

‐ 05 1.68E

‐ 06 1 0 3.31E

‐ 05 3.6E

‐ 05 1 3.6E

‐ 05 3.87E

‐ 05 1 3.87E

‐ 05 1.33E

‐ 06 1 0 0.002029 0.002202 1 0.002202 0.002369 1 0.002369 8.12E

‐ 05 1 0 0.008532 0.008532 1 0.008532 0.008532 1 0.008532 0.032581 0 0.035524 0.035524 1 0.035524 0.035524 1 0.035524 0.000328 1 0 2.937383 3.190776 1 3.190776 3.433801 1 3.433801 10.69659 1 0 1.142316 1.240857 1 1.240857 1.335367 1 1.335367 4.159786 1 0 0.387808 0.421156 1 0.421156 0.453347 1 0.453347 1.480051 1 0 0.150814 0.163783 1 0.163783 0.176302 1 0.176302 0.575891 1 0 0.000552 0.000599 1 0.000599 0.000645 1 0.000645 5.29E

‐ 05 1 0.095157 181.1568 184.4176 0.633 116.7363 198.9101 0.412 81.95097 6.390128 1 0.002725 8.05639 8.201405 0.96 7.873349 8.845916 0.852 7.536721 0.198311 1000 0.421 0 0 0.241 0 0 1 0.013049 30.38568 30.93263 0.843 26.0762 33.36348 0.634 21.15245 0.954157 1000100100 1000100100 1000100100 1 0 17.38 12.95927 1 12.95927 15.10322 1 15.10322 0.379 1000100100 1 0 1.581511 1.202371 1 1.202371 1.421778 1 1.421778 0.256747 1 0 41.80409 31.78227 1 31.78227 37.58188 1 37.58188 2.873079 1000100100 1000100100 1 0 0.94729 0.70634 1 0.70634 0.823195 1 0.823195 0.144939 1 2.919858 514.9332 516.478 0.642 331.5789 547.8889 0.401 219.7035 16.0917 1 0.318663 61.0547 61.23786 0.642 39.31471 64.9622 0.401 26.04984 1.9079 1 1.005207 1151.914 1089.711 0.654 712.6707 1101.23 0.48 528.5903 102.5148 1 0.027951 68.85192 65.13391 0.654 42.59758 65.82243 0.48 31.59477 6.129385 1 0.076714 153.1169 155.873 0.633 98.66762 168.1224 0.412 69.26642 5.178474 1 0.013981 41.33281 42.0768 0.96 40.39373 45.38343 0.852 38.66668 1.017423 1 0 19.54868 21.91407 0.421 9.225825 24.25991 0.241 5.846639 0.493201 1 0.020482 53.57447 60.05698 0.421 25.28399 66.48592 0.241 16.02311 1.318756 1000 0.843 0 0 0.634 0 0 8.20098 6975.467 7257.732 5859.734 8218.145 5922.135 360.7611P10_17_G O P10_17_C F P10_17_G C P10_25_G O P10_25_C F P10_25_G C P25_2007 P25_17_G O P25_17_C F P25_17_G C 0.002413 1 0.002413 0.002413 1 0.002413 0.001665 0.001665 1 0.001665

15.2408 1 15.2408 16.40505 1 16.40505 9.683052 10.51615 1 10.51615 5.926978 1 5.926978 6.379743 1 6.379743 3.765631 4.089615 1 4.089615 0.382676 1 0.382676 0.412957 1 0.412957 0.242502 0.264046 1 0.264046 0.1489 1 0.1489 0.160682 1 0.160682 0.094358 0.102741 1 0.102741 2.71151 0.55 1.491331 2.876418 0.353 1.015375 2.5141 2.521642 0.55 1.386903 0.321462 0.55 0.176804 0.341012 0.353 0.120377 0.2981 0.298994 0.55 0.164447 5.213926 0.216 1.126208 5.269042 0.137 0.721859 5.51155 5.213926 0.216 1.126208 0.6453 0.216 0.139385 0.652122 0.137 0.089341 0.631776 0.597661 0.216 0.129095 3.751286 0.449 1.684327 4.046082 0.252 1.019613 3.39016 3.451183 0.449 1.549581 1.250419 0.791 0.989081 1.348684 0.688 0.927894 1.130044 1.150385 0.791 0.909955 0 0.402 0 0 0.18 0 0 0 0.402 0 0.194237 0.712 0.138297 0.209501 0.534 0.111874 0.185079 0.18841 0.712 0.134148 0.037708 1 0.037708 0.037708 1 0.037708 0.026019 0.026019 1 0.026019 10.25788 1 10.25788 11.04598 1 11.04598 7.129772 7.077935 1 7.077935 3.989174 1 3.989174 4.295659 1 4.295659 2.772689 2.75253 1 2.75253 0.536289 1 0.536289 0.576933 1 0.576933 0.37626 0.37004 1 0.37004 0.208671 1 0.208671 0.224485 1 0.224485 0.146404 0.143983 1 0.143983 1.583277 0.449 0.710891 1.707699 0.252 0.43034 1.430859 1.456614 0.449 0.65402 1.630084 0.791 1.289396 1.758184 0.688 1.209631 1.47316 1.499677 0.791 1.186244 0.4773 0.402 0.191874 0.528393 0.18 0.095111 0.413007 0.462981 0.402 0.186118 0100100010 0100100010 0100100010 8.847873 1 8.847873 10.98781 1 10.98781 7.604 8.492707 1 8.492707 0.190948 1 0.190948 0.190948 1 0.190948 0.190248 0.131754 1 0.131754

37.8714 1 37.8714 47.59165 1 47.59165 32.95401 37.8928 1 37.8928 0.646747 1 0.646747 0.697457 1 0.697457 0.501576 0.446503 1 0.446503 2.948755 1 2.948755 3.179961 1 3.179961 3.244409 2.888177 1 2.888177 0100100010 4.837755 1 4.837755 5.986381 1 5.986381 4.35973 4.809188 1 4.809188 4.474772 1 4.474772 5.557038 1 5.557038 4.006516 4.474772 1 4.474772 13.43388 0.55 7.388635 14.2509 0.353 5.030567 12.4561 12.49347 0.55 6.871408 1.592864 0.55 0.876075 1.689738 0.353 0.596478 1.4769 1.481331 0.55 0.814732 59.85595 0.216 12.92889 60.48868 0.137 8.286949 58.68846 55.51928 0.216 11.99216 8.344479 0.216 1.802408 8.432687 0.137 1.155278 8.163881 7.723031 0.216 1.668175 3.603696 0.449 1.618059 3.886894 0.252 0.979497 3.256778 3.3154 0.449 1.488615 0.706386 0.791 0.558751 0.761897 0.688 0.524185 0.638384 0.649875 0.791 0.514051 0.069849 0.402 0.028079 0.077326 0.18 0.013919 0.06044 0.067753 0.402 0.027237 1.85E

‐ 05 1 1.85E

‐ 05 1.99E

‐ 05 1 1.99E

‐ 05 1.65E

‐ 05 1.79E

‐ 05 1 1.79E

‐ 05 1.82E

‐ 06 1 1.82E

‐ 06 1.96E

‐ 06 1 1.96E

‐ 06 1.62E

‐ 06 1.76E

‐ 06 1 1.76E

‐ 06 1.44E

‐ 06 1 1.44E

‐ 06 1.55E

‐ 06 1 1.55E

‐ 06 1.28E

‐ 06 1.39E

‐ 06 1 1.39E

‐ 06 8.82E

‐ 05 1 8.82E

‐ 05 9.48E

‐ 05 1 9.48E

‐ 05 7.83E

‐ 05 8.5E

‐ 05 1 8.5E

‐ 05 0.03258 1 0.03258 0.03258 1 0.03258 0.02248 0.02248 1 0.022480.000328 1 0.000328 0.000328 1 0.000328 0.000328 0.000328 1 0.000328 11.61933 1 11.61933 12.50432 1 12.50432 7.380649 8.01734 1 8.01734

4.51863 1 4.51863 4.86279 1 4.86279 2.870252 3.117854 1 3.117854 1.607323 1 1.607323 1.73018 1 1.73018 1.021235 1.109053 1 1.109053 0.625412 1 0.625412 0.673216 1 0.673216 0.397364 0.431534 1 0.431534 5.75E

‐ 05 1 5.75E

‐ 05 6.18E

‐ 05 1 6.18E

‐ 05 5.29E

‐ 05 5.75E

‐ 05 1 5.75E

‐ 05 6.50515 0.449 2.920812 7.016361 0.252 1.768123 5.878918 5.984738 0.449 2.687147 0.201881 0.791 0.159688 0.217746 0.688 0.149809 0.182446 0.18573 0.791 0.146913 0 0.402 0 0 0.18 0 0 0 0.402 0 0.971332 0.712 0.691589 1.047665 0.534 0.559453 0.925533 0.942192 0.712 0.670841 0100100010 0100100010 0100100010 0.282599 1 0.282599 0.329351 1 0.329351 0.362 0.269923 1 0.269923 0100100010 0.195196 1 0.195196 0.230815 1 0.230815 0.181162 0.137731 1 0.137731 2.184307 1 2.184307 2.582898 1 2.582898 2.847746 2.165047 1 2.165047 0100100010 0100100010 0.108073 1 0.108073 0.125952 1 0.125952 0.144939 0.108073 1 0.108073 16.13998 0.55 8.876986 17.12157 0.353 6.043914 14.9652 15.0101 0.55 8.255553 1.913624 0.55 1.052493 2.030006 0.353 0.716592 1.774403 1.779726 0.55 0.978849 96.97903 0.216 20.94747 98.00418 0.137 13.42657 93.69635 88.63675 0.216 19.14554 5.798399 0.216 1.252454 5.859692 0.137 0.802778 5.671421 5.365164 0.216 1.158876 5.271687 0.449 2.366987 5.685965 0.252 1.432863 4.764196 4.849952 0.449 2.177628 1.035737 0.791 0.819268 1.117131 0.688 0.768586 0.936029 0.952878 0.791 0.753726 0.552878 0.402 0.222257 0.612062 0.18 0.110171 0.478404 0.536291 0.402 0.215589 1.478326 0.402 0.594287 1.636577 0.18 0.294584 1.213256 1.36006 0.402 0.546744 0 0.712 0 0 0.534 0 0 0 0.712 0 359.9576 190.7665 385.4797 185.2072 324.5321 323.5553 167.4007P25_25_G O P25_25_C F P25_25_G C SO2_2007 SO2_17_G O SO2_17_C F SO2_17_G C SO2_25_G O SO2_25_C F SO2_25_G C 0.001665 1 0.001665 0.00006 0.00006 1 0.00006 0.00006 1 0.00006 11.31949 1 11.31949 0.592877 0.643887 1 0.643887 0.693074 1 0.693074 4.402023 1 4.402023 0.230563 0.2504 1 0.2504 0.269529 1 0.269529

0.28494 1 0.28494 0.008743 0.009519 1 0.009519 0.010273 1 0.010273 0.110871 1 0.110871 0.0034 0.003702 1 0.003702 0.003995 1 0.003995 2.675002 0.353 0.944276 1.4418 1.446125 0.076 0.109906 1.534075 0.031 0.047556 0.317178 0.353 0.111964 0.171 0.171513 0.076 0.013035 0.181944 0.031 0.00564 5.269042 0.137 0.721859 51.80857 49.01091 0.12 5.881309 49.52899 0.036 1.783044 0.603978 0.137 0.082745 62.43188 59.06056 0.12 7.087267 59.68488 0.036 2.148656 3.722396 0.252 0.938044 1.116528 1.136626 0.003 0.00341 1.225948 0.003 0.003678 1.240789 0.688 0.853663 0.346938 0.353183 0.003 0.00106 0.380938 0.003 0.001143 0 0.18 0 0 0 0.003 0 0 0.003 0 0.203216 0.534 0.108517 0.053635 0.0546 0.003 0.000164 0.058891 0.003 0.000177 0.026019 1 0.026019 0.000938 0.000938 1 0.000938 0.000938 1 0.000938 7.621726 1 7.621726 0.436544 0.43337 1 0.43337 0.466666 1 0.466666 2.964005 1 2.964005 0.169767 0.168533 1 0.168533 0.181481 1 0.181481 0.398084 1 0.398084 0.013565 0.013341 1 0.013341 0.014352 1 0.014352 0.154895 1 0.154895 0.005275 0.005188 1 0.005188 0.005581 1 0.005581 1.571083 0.252 0.395913 0.468842 0.477281 0.003 0.001432 0.514788 0.003 0.001544

1.61753 0.688 1.11286 0.452279 0.46042 0.003 0.001381 0.496603 0.003 0.00149 0.512542 0.18 0.092257 0.201695 0.226101 0.003 0.000678 0.250304 0.003 0.000751 0100010010 0100010010 0100010010 10.54675 1 10.54675 7.64 8.532914 1 8.532914 10.59668 1 10.59668 0.131754 1 0.131754 0010010 47.61855 1 47.61855 243.2783 279.7382 1 279.7382 351.5371 1 351.5371 0.481513 1 0.481513 0.030888 0.027496 1 0.027496 0.029652 1 0.029652 3.114632 1 3.114632 11.25219 10.01671 1 10.01671 10.8021 1 10.8021 0100010010 5.951031 1 5.951031 26.91266 29.68717 1 29.68717 36.73578 1 36.73578 5.557038 1 5.557038 4.259421 4.757235 1 4.757235 5.907817 1 5.907817 13.25329 0.353 4.678412 7.1433 7.16473 0.076 0.544519 7.600471 0.031 0.235615 1.571422 0.353 0.554712 0.847 0.849541 0.076 0.064565 0.901208 0.031 0.027937 56.10617 0.137 7.686545 503.4309 476.2456 0.12 57.14947 481.2799 0.036 17.32608

7.80467 0.137 1.06924 563.8836 533.4339 0.12 64.01206 539.0727 0.036 19.40662 3.575942 0.252 0.901137 1.067715 1.086934 0.003 0.003261 1.172351 0.003 0.003517 0.700945 0.688 0.48225 0.195992 0.19952 0.003 0.000599 0.215199 0.003 0.000646 0.075006 0.18 0.013501 0.029516 0.033088 0.003 9.93E

‐ 05 0.03663 0.003 0.00011 1.92E

‐ 05 1 1.92E

‐ 05 1.16E

‐ 05 1.26E

‐ 05 1 1.26E

‐ 05 1.36E

‐ 05 1 1.36E

‐ 05 1.89E

‐ 06 1 1.89E

‐ 06 1.14E

‐ 06 1.24E

‐ 06 1 1.24E

‐ 06 1.34E

‐ 06 1 1.34E

‐ 06 1.49E

‐ 06 1 1.49E

‐ 06 9.04E

‐ 07 9.82E

‐ 07 1 9.82E

‐ 07 1.06E

‐ 06 1 1.06E

‐ 06 9.15E

‐ 05 1 9.15E

‐ 05 5.54E

‐ 05 6.01E

‐ 05 1 6.01E

‐ 05 6.47E

‐ 05 1 6.47E

‐ 05 0.02248 1 0.02248 0.00081 0.00081 1 0.00081 0.00081 1 0.000810.000328 1 0.000328 0.002615 0.002615 1 0.002615 0.002615 1 0.002615 8.627979 1 8.627979 0.451905 0.490889 1 0.490889 0.528277 1 0.528277 3.355325 1 3.355325 0.175741 0.190901 1 0.190901 0.205441 1 0.205441 1.193824 1 1.193824 0.036817 0.039983 1 0.039983 0.043039 1 0.043039 0.464519 1 0.464519 0.014318 0.015549 1 0.015549 0.016738 1 0.016738 6.18E

‐ 05 1 6.18E

‐ 05 5.8E

‐ 05 6.3E

‐ 05 1 6.3E

‐ 05 6.78E

‐ 05 1 6.78E

‐ 05 6.455052 0.252 1.626673 1.955926 1.991133 0.003 0.005973 2.147607 0.003 0.006443 0.200326 0.688 0.137824 0.056013 0.057022 0.003 0.000171 0.061503 0.003 0.000185 0 0.18 0 0 0 0.003 0 0 0.003 0 1.016235 0.534 0.542669 0.268214 0.273042 0.003 0.000819 0.294499 0.003 0.000883 0100010010 0100010010 0100010010 0.314578 1 0.314578 0.444 0.331065 1 0.331065 0.385836 1 0.385836 0100010010 0.162864 1 0.162864 1.089165 0.828056 1 0.828056 0.979159 1 0.979159 2.560124 1 2.560124 9.202354 6.996247 1 6.996247 8.272916 1 8.272916 0100010010 0100010010 0.125952 1 0.125952 0.162344 0.121051 1 0.121051 0.141077 1 0.141077 15.92297 0.353 5.620809 8.5822 8.607947 0.076 0.654204 9.131461 0.031 0.283075 1.887965 0.353 0.666452 1.0175 1.020553 0.076 0.077562 1.08262 0.031 0.033561 89.57371 0.137 12.2716 813.5048 769.5755 0.12 92.34906 777.7106 0.036 27.99758 5.421879 0.137 0.742797 359.1543 339.7599 0.12 40.77119 343.3515 0.036 12.36065 5.231088 0.252 1.318234 1.576826 1.605209 0.003 0.004816 1.731355 0.003 0.005194

1.02776 0.688 0.707099 0.287373 0.292546 0.003 0.000878 0.315536 0.003 0.000947

0.5937 0.18 0.106866 0.232609 0.260755 0.003 0.000782 0.288668 0.003 0.000866 1.50565 0.18 0.271017 0.372485 0.417556 0.003 0.001253 0.462254 0.003 0.001387 0 0.534 0 0 0 0.003 0 0 0.003 0 347.1697 162.2731 2688.515 2598.578 612.0469 2708.545 509.5161VOC_2007 VOC_17_G VOC_17_C F VOC_17_G VOC_25_G VOC_25_C F VOC_25_GC 2.73E

‐ 06 2.73E

‐ 06 1 2.73E

‐ 06 2.73E

‐ 06 1 2.73E

‐ 06 0.004461 0.004844 1 0.004844 0.005214 1 0.005214 92.95701 100.9547 1 100.9547 108.6667 1 108.6667 4.94E

‐ 05 5.38E

‐ 05 1 5.38E

‐ 05 5.81E

‐ 05 1 5.81E

‐ 05 1.030462 1.122009 1 1.122009 1.210793 1 1.210793 4.5547 4.568364 0.708 3.234402 4.846201 0.424 2.054789 0.54 0.54162 0.708 0.383467 0.57456 0.424 0.243613 2.20462 2.085571 1 2.085571 2.107617 1 2.107617 0.288454 0.272878 1 0.272878 0.275762 1 0.275762 5.498748 5.597726 0.48 2.686908 6.037626 0.277 1.672422 1.842464 1.875628 1 1.875628 2.023025 1 2.023025 0 0 0.437 0 0 0.176 0 0.437979 0.445862 0.809 0.360703 0.480901 0.575 0.276518 4.26E

‐ 05 4.26E

‐ 05 1 4.26E

‐ 05 4.26E

‐ 05 1 4.26E

‐ 05 0.003284 0.003261 1 0.003261 0.003511 1 0.003511

68.4456 67.94797 1 67.94797 73.16834 1 73.16834 7.67E

‐ 05 7.55E

‐ 05 1 7.55E

‐ 05 8.12E

‐ 05 1 8.12E

‐ 05 1.598839 1.572405 1 1.572405 1.691572 1 1.691572 2.320197 2.36196 0.48 1.133741 2.547576 0.277 0.705679 2.401891 2.445125 1 2.445125 2.637277 1 2.637277

0.67252 0.753895 0.437 0.329452 0.834597 0.176 0.146889 0010010 0010010 0010010 88.034 98.32285 1 98.32285 122.1032 1 122.1032 0010010 498.7139 573.4557 1 573.4557 720.6415 1 720.6415 0.155414 0.138349 1 0.138349 0.149197 1 0.149197 161.7956 144.0307 1 144.0307 155.3238 1 155.3238 0010010 68.91439 76.01899 1 76.01899 94.06814 1 94.06814

2.57085 2.871314 1 2.871314 3.565769 1 3.565769 22.5657 22.6334 0.708 16.02445 24.0099 0.424 10.1802

2.6756 2.683627 0.708 1.900008 2.846838 0.424 1.207059 22.37517 21.16691 1 21.16691 21.39066 1 21.39066 3.978072 3.763256 1 3.763256 3.803037 1 3.803037 5.282566 5.377653 0.48 2.581273 5.800258 0.277 1.606671 1.040843 1.059578 1 1.059578 1.142846 1 1.142846 0.098418 0.110326 0.437 0.048212 0.122136 0.176 0.021496 0.000121 0.000131 1 0.000131 0.000141 1 0.000141 1.19E

‐ 05 1.29E

‐ 05 1 1.29E

‐ 05 1.39E

‐ 05 1 1.39E

‐ 05

9.4E

‐ 06 1.02E

‐ 05 1 1.02E

‐ 05 1.1E

‐ 05 1 1.1E

‐ 05 0.000575 0.000625 1 0.000625 0.000672 1 0.000672 3.68E

‐ 05 3.68E

‐ 05 1 3.68E

‐ 05 3.68E

‐ 05 1 3.68E

‐ 050.001749 0.001749 1 0.001749 0.001749 1 0.001749 0.0034 0.003693 1 0.003693 0.003975 1 0.003975 70.85401 76.96623 1 76.96623 82.82834 1 82.82834 0.000208 0.000226 1 0.000226 0.000243 1 0.000243 4.339524 4.712685 1 4.712685 5.072903 1 5.072903 2.87E

‐ 05 3.12E

‐ 05 1 3.12E

‐ 05 3.35E

‐ 05 1 3.35E

‐ 05 9.527671 9.699169 0.48 4.655601 10.46138 0.277 2.897803 0.297467 0.302821 1 0.302821 0.326618 1 0.326618 0 0 0.437 0 0 0.176 0 2.190225 2.229649 0.809 1.803786 2.404867 0.575 1.382799 0010010 0010010 0010010 5.67 4.227794 1 4.227794 4.92723 1 4.92723 0010010 20.54472 15.61947 1 15.61947 18.4697 1 18.4697 162.1968 123.3129 1 123.3129 145.8149 1 145.8149 0010010 0010010 0.097949 0.073035 1 0.073035 0.085118 1 0.085118 27.112 27.19334 0.708 19.25288 28.84717 0.424 12.2312 3.2145 3.224144 0.708 2.282694 3.420228 0.424 1.450177 36.37623 34.41191 1 34.41191 34.77568 1 34.77568 2.791157 2.640435 1 2.640435 2.668347 1 2.668347 7.725444 7.864502 0.48 3.774961 8.482538 0.277 2.349663 1.526135 1.553605 1 1.553605 1.675696 1 1.675696 1.157328 1.297364 0.437 0.566948 1.436244 0.176 0.252779 1.978134 2.217489 0.437 0.969043 2.454865 0.176 0.432056 0 0 0.809 0 0 0.575 0 1420.607 1461.74 1424.928 1716.237 1649.741