### 1500050517 NFAX140325215525843 S131RC

X X X X

X

X 2 X

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### X



## X

Page 2 SANITIZED SUBMISSIONRebekah Cole Product Safety Specialist SASOL NORTH AMERICA INC. 2201 Old Spanish Trail Westlake LA 70669 rebekah.cole@us.sasol.com

Rebekah Cole Product Safety Specialist Sasol North America 2201 Old Spanish Trail Westlake LA 70669 rebekah.cole@us.sasol.com 337-494-5080



## X PC 7097



## X
X

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## X

Alcohols, C18-22, distn. residues

1160164-88-4 

## X 142505 CAS IES Report - PMN Substance 1.pdf 

### see chemical structure diagram

See Attachment 017 (Chemical Structures - PMN Substance 1.pdf)

Chemical Structures - PMN Substance 1.pdf

Page 4 SANITIZED SUBMISSIONC18-C22 fatty acids (erucic acid) from rape oil are hydrogenated with a catalyst to produce a C18-22 linear alcohol intermediate stream

The PMN substance is the distillation residue after distilling off the main product, fatty alcohol C18-C22

docosan-1-ol 2.5 - 10% tetracosanol 2.5 - 10% C36-Ester 1- 5% C38-Ester 1- 6% C40-Ester 10 - 20% C42-Ester 10 - 20% C-44-Ester 20 - 32% C46-Ester 10 - 20% C48-Ester 0.5 - 3% unknown constituent 5.0% -- within this are the following components that are identified but below 1%: octacecyldocosanyleter, diisocanylether, didocosanylether: all other components are not identified and below 1% Process diagram - PMN Substance 1.pdf

Page 5 SANITIZED SUBMISSIONPage 6 SANITIZED SUBMISSIONPage 7 SANITIZED SUBMISSIONBehenyl bottoms;

Natural fatty alcohol bottoms (NFA bottoms)

None

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## X

Alcohols, C12-22, distn. residues

1476777-83-9 

## X 367762 CAS IES Report - PMN Substance 2.pdf 

### see chemical structure diagram

See Attachment 021 (Chemical Structures - PMN Substance 2.pdf)

Chemical Structures - PMN Substance 2.pdf

Page 9 SANITIZED SUBMISSIONSee attached

The PMN substance is the distillation residue after distilling off the main alcohol product.

Alcohol 5-30 wt.% Ester 50-80 wt.% Ether sat./unsat. <5 wt.% Paraffin <1 wt.% Steroid <5 wt.% Aldehydes <5 wt.% Ketones <1 wt% Process diagram - PMN Substance 2.pdf

Process diagram - PMN Substance 2.pdf

Page 10 SANITIZED SUBMISSIONPage 11 SANITIZED SUBMISSIONPage 12 SANITIZED SUBMISSIONNatural fatty alcohol bottoms (NFA bottoms)

None

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### X X

XXX XXX 

## X

X Formulation of defoamers used in the production of paper 100 2 0 0 100 0

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### X X

Not applicable- PMN substance is imported

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### X X

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### X X

XXX 

## X

See Attachment 019 (Operations Description - Defoamer Preperation Sanitized.pdf)

Operations Description - Defoamer Preperation Sanitized.pdf XXX 

## X

Page 19 SANITIZED SUBMISSIONP10SB1(a)(4)1 Part II, Section B, 1(a)(4). Operation Site Locations

XXX

Page 20 SANITIZED SUBMISSIONnone

A 6 1 12 liquid; Safety glasses, chemical resistant gloves 10 2

1 0kg 4kg Waste water containing residual PMN sent to on-site waste water treatment plant B 6 4 1 liquid; Safety glasses, chemical resistant gloves 10

2 0kg 4kg Waste water containing residual PMN sent to on-site waste water treatment plant C 6 .25 156 liquid; Safety glasses, chemical resistant gloves 2 2

3 0kg 0.8kg Waste water containing residual PMN sent to on-site waste water treatment plant D 6 4 1 Liquid; Safety glasses, chemical resistant gloves 2 2

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### X X

40

See Attachment 024 (Operations Description - Paper Mill.pdf)

Operations Description - Paper Mill.pdf It is anticipated that approximately 5-6 workers may be routinely exposed to the PMN substances at each site . These exposures may occur when the product is being transported by truck (one person), and unloaded (2 people), sampled in storage tanks and analyzed (2 people). Exposure may also occur when tanks containing residual levels of the PMN materials are cleaned which is rarely done (one time every three years) (three people). Typical duration of exposure per worker would probably be 0.5-1 hour per month. We would anticipate that workers would use appropriate protective equipment. Both liquids and sludges containing the PMN substances may be produced during normal processing operations and while cleaning tanks storing these materials. The resulting liquid wastes would be disposed of at appropriate secondary biological wastewater treatment facilities or incinerated. Sludges may be landfilled or incinerated. Air releases of the PMN substances are anticipated to be low, particularly considering the anticipated low volatility of these materials.

Page 22 SANITIZED SUBMISSIONP10SB1(a)(4)2 Part II, Section B, 1(a)(4). Operation Site Locations

unidentified paper mills

Page 23 SANITIZED SUBMISSIONA 1 1 12 Safety glasses, chemical resistant gloves 2

1 0kg 4kg Waste water containing residual PMN sent to on-site waste water treatment plant B 2 0.5 12 safety glasses, chemical resistant gloves 2

2 0kg 4kg Waste water containing residual PMN sent to on-site waste water treatment plant C 2 0.5 12 Safety glasses, chemical resistant gloves 2

3 0kg unknown Waste water containing residual PMN sent to on-site waste water treatment plant D 3 4 1 Safety glasses, chemical resistant gloves 2

Page 24 SANITIZED SUBMISSIONWater-based defoamers are typically used in the manufacturing of paper products. Excess foam in the process inhibits proper sheet formation,

causing pinholes and loss of strength in finished product. Excess foam also inhibits drainage through the formation fabric, causing slower speeds leading to less production. Typical water-based defoamers are not effective in temperatures over 55° C, so mineral oil/silicone oil type defoamers are employed. Because of its higher melting point, water-based defoamers made as described in this PMN should be able to handle higher temperature environments, displacing some mineral oil based defoamers.

Page 25 SANITIZED SUBMISSION001 CAS IES Report - PMN Substance 1 CAS IES Report - PMN Substance 1.pdf Pt.I, Sec.B, 1c. 1
002 Guinea Pig maximization test Alcohols-C18-22- distn-residue SSM_Alcohols-C18-22-distnresidues_sn5032.pdf 16
003 Testing for Mutagenic Activity with Salmonella typhimurium AMES Alcohols, C18-22, distn residues, #4976 .pdf 37
004 Acute Dermal Toxicity Behenyl Bottoms (116064 -88-4) AD Alcohols, C18-22, distn residues, #4782.pdf 11
005 Acute Dermal Irritation Alcohols C18-22 distn residues Behenyl bottoms (116064-88-4) ADI Alcohols, C18-22, distn residues, #4780.pdf 10
006 Acute eye irritation AEI Alcohols, C18-22, distn residues, #4781.pdf 15
007 Acute Oral Toxicity AO Alcohols, C18-22, distn residues, #4785.pdf 11
008 Chromosomal Abberations Assay (CHO) CA_Alcohols-C18-22-distnresidues_sn5538 .pdf 37
009 Mouse Lymphoma Assay MML_Alcohols-C18-22-distnresidues_sn5478 .pdf 67
010 28-day Oral repeat dose toxicity (OECD 407) RDO_Alcohols-C18-22-distnresidues_sn6352 .pdf 197
011 Developmental Toxicity (OECD 414) DT_Alcohols-C18-22-distnresidues_sn6278 .pdf 71
012 Activated sludge respiratory inhibition RI_Alcohols-C18-22-distn- 32
013 A 72-HOUR TOXICITY TEST WITH THE FRESHWATER ALGA AG_Alcohols-C18-22-distnresidues_sn5278 .pdf 34
014 A 48-HOUR STATIC ACUTE TOXICITY TEST (daphnia) DA_Alcohols-C18-22-distnresidues_sn5313 .pdf 24
015 A 96-HOUR STATIC ACUTE TOXICITY TEST FA_Alcohols-C18-22-distn- 26
016 READY BIODEGRADABILITY BY THE CARBON DIOXIDE EVOLUTION TEST RB 301B_Alcohols-C18-22-distnresidues_sn5894 .pdf 34
017 Chemical Structures - PMN Substance 1 Chemical Structures - PMN Substance 1.pdf Pt.I, Sec.B, 1e. 1
018 Process Diagram - PMN Substance 1 Process diagram - PMN Substance 1.pdf Pt.I, Sec.B, 1e(2). 1
019 Operations Description - Defoamer Preperation Operations Description - Pt.2, Sec.B, 1a. 3
020 CAS IES Report - PMN Substance 2 CAS IES Report - PMN Substance 2.pdf Pt.I, Sec.B, 1c. (Chem 2) 1
021 Chemical Structures - PMN Substance 2 Chemical Structures - PMN Pt.I, Sec.B, 1e. (Chem 2) 1 

## X
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## (1)

022 Process Diagram - PMN Substance 2 Process diagram - PMN Substance 2.pdf Pt.I, Sec.B, 1e(1). (Chem 2) | Pt.I, Sec.B, 1e(2). (Chem 2) 2
023 90 Day Oral Toxicity 90 Day Oral Alcohols-C18-22- distn-restidues.pdf 636
024 Operations Description - Paper Mill Operations Description - Paper Mill.pdf Pt.2, Sec.B, 1a. (#2) 3

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### X



## X Measured <0.00075 Measured 38 0.9 Measured

<1 Measured 60 - 70 Measured 270 Measured 760

>7.17 Measured

non flammable Measured alcohols >C20 do not have expolosive properties Estimate

368°C @ 760 torr Measured Autoignition Temperature

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### X



## X Measured

0.9 Estimate

<1 Estimate

>210 Estimate 3.75

non flammable Estimate alcohols >C20 do not have expolosive properties Estimate

Page 29 SANITIZED SUBMISSION

## ATTACHMENT HEADER SHEET

Attachment Number 001
Attachment Name CAS IES Report - PMN Substance 1 

## Associated PMN Section Number

Pt.I, Sec.B, 1c.
Does not contain CBI 

## Report Number NFAX140325215525843

## ATTACHMENT HEADER SHEET

Attachment Number 002
Attachment Name Guinea Pig maximization test Alcohols-C18-22-distn-residue 

## Associated PMN Section Number

N/A
Does not contain CBI 

## Report Number NFAX140325215525843

## ATTACHMENT HEADER SHEET

Attachment Number 003
Attachment Name Testing for Mutagenic Activity with Salmonella typhimurium 

## Associated PMN Section Number

N/A
Does not contain CBI 

## Report Number NFAX140325215525843

## ATTACHMENT HEADER SHEET

Attachment Number 004
Attachment Name Acute Dermal Toxicity Behenyl Bottoms (116064-88-4) 

## Associated PMN Section Number

N/A
Does not contain CBI 

## Report Number NFAX140325215525843

## ATTACHMENT HEADER SHEET

Attachment Number 005
Attachment Name Acute Dermal Irritation Alcohols C18-22 distn residues Behenyl bottoms (116064-88-4)



## Associated PMN Section Number

N/A
Does not contain CBI 

## Report Number NFAX140325215525843

## ATTACHMENT HEADER SHEET

Attachment Number 006
Attachment Name Acute eye irritation 

## Associated PMN Section Number

N/A
Does not contain CBI 

## Report Number NFAX140325215525843

## ATTACHMENT HEADER SHEET

Attachment Number 007
Attachment Name Acute Oral Toxicity 

## Associated PMN Section Number

N/A
Does not contain CBI 

## Report Number NFAX140325215525843

## ATTACHMENT HEADER SHEET

Attachment Number 008
Attachment Name Chromosomal Abberations Assay (CHO) 

## Associated PMN Section Number

N/A
Does not contain CBI 

## Report Number NFAX140325215525843

## ATTACHMENT HEADER SHEET

Attachment Number 009
Attachment Name Mouse Lymphoma Assay 

## Associated PMN Section Number

N/A
Does not contain CBI 

## Report Number NFAX140325215525843

## ATTACHMENT HEADER SHEET

Attachment Number 010
Attachment Name 28-day Oral repeat dose toxicity (OECD 407) 

## Associated PMN Section Number

N/A
Does not contain CBI 

## Report Number NFAX140325215525843

## ATTACHMENT HEADER SHEET

Attachment Number 011
Attachment Name Developmental Toxicity (OECD 414) 

## Associated PMN Section Number

N/A
Does not contain CBI 

## Report Number NFAX140325215525843

## ATTACHMENT HEADER SHEET

Attachment Number 012
Attachment Name Activated sludge respiratory inhibition 

## Associated PMN Section Number

N/A
Does not contain CBI 

## Report Number NFAX140325215525843

## ATTACHMENT HEADER SHEET

Attachment Number 013
Attachment Name A 72-HOUR TOXICITY TEST WITH THE FRESHWATER ALGA



## Associated PMN Section Number

N/A
Does not contain CBI 

## Report Number NFAX140325215525843

## ATTACHMENT HEADER SHEET

Attachment Number 014
Attachment Name A 48-HOUR STATIC ACUTE TOXICITY TEST (daphnia) 

## Associated PMN Section Number

N/A
Does not contain CBI 

## Report Number NFAX140325215525843

## ATTACHMENT HEADER SHEET

Attachment Number 015
Attachment Name A 96-HOUR STATIC ACUTE TOXICITY TEST WITH THE FATHEAD Minnow



## Associated PMN Section Number

N/A
Does not contain CBI 

## Report Number NFAX140325215525843

## ATTACHMENT HEADER SHEET

Attachment Number 016
Attachment Name READY BIODEGRADABILITY BY THE CARBON DIOXIDE EVOLUTION TEST METHOD



## Associated PMN Section Number

N/A
Does not contain CBI 

## Report Number NFAX140325215525843

## ATTACHMENT HEADER SHEET

Attachment Number 017
Attachment Name Chemical Structures - PMN Substance 1 

## Associated PMN Section Number

Pt.I, Sec.B, 1e.
Does not contain CBI 

## Report Number NFAX140325215525843

## ATTACHMENT HEADER SHEET

Attachment Number 018
Attachment Name Process Diagram - PMN Substance 1 

## Associated PMN Section Number

Pt.I, Sec.B, 1e(2).
Does not contain CBI 

## Report Number NFAX140325215525843

## ATTACHMENT HEADER SHEET

Attachment Number 019
Attachment Name Operations Description - Defoamer Preperation 

## Associated PMN Section Number

Pt.2, Sec.B, 1a.
Does not contain CBI 

## Report Number NFAX140325215525843

## ATTACHMENT HEADER SHEET

Attachment Number 020
Attachment Name CAS IES Report - PMN Substance 2 

## Associated PMN Section Number Pt.I, Sec.B, 1c. (Chem 2)
Does not contain CBI 

## Report Number NFAX140325215525843

## ATTACHMENT HEADER SHEET

Attachment Number 021
Attachment Name Chemical Structures - PMN Substance 2 

## Associated PMN Section Number Pt.I, Sec.B, 1e. (Chem 2)
Does not contain CBI 

## Report Number NFAX140325215525843

## ATTACHMENT HEADER SHEET

Attachment Number 022
Attachment Name Process Diagram - PMN Substance 2 

## Associated PMN Section Number Pt.I, Sec.B, 1e(1). (Chem 2) | Pt.I, Sec.B, 1e(2). (Chem 2)

Does not contain CBI 

## Report Number NFAX140325215525843

## ATTACHMENT HEADER SHEET

Attachment Number 023
Attachment Name 90 Day Oral Toxicity 

## Associated PMN Section Number

N/A
Does not contain CBI 

## Report Number NFAX140325215525843

## ATTACHMENT HEADER SHEET

Attachment Number 024
Attachment Name Operations Description - Paper Mill 

## Associated PMN Section Number

Pt.2, Sec.B, 1a. (#2)
Does not contain CBI 

## Report Number NFAX140325215525843