# SANITIZED

SANITIZED Appendix D



# Dyneon Gendorf Facility Report
on Product Content
for 2008

# SANITIZED

SANITIZED 2010/15 PFOA Stewardship Program 

# Dyneon Gendorf Facility Report on Product

Content

I. CHEMICAL IDENTIFICATION

Identify the product (e.g fluoropolymer dispersion) for which you are submitting
information:

Product name:_ Liquid PTFE dispersions

__

Product description (including concentrations of p erfluoroalkyl chemicals identified in Section IV below and year of product ion):

This product family consists of the commercially av ailable aqueous PTFE dispersions. The PTFE dispersions contain an average of 59 % by weig ht of PTFE in water. The use of APFO for the manufacture of the Liquid PTFE dispersions ceas ed on April 1, 2008, and the new emulsifier was used exclusively after that date. Before April 2008, all PTFE dispersion were “APFO Reduced” dispersions. The typical APFO content of the “APFO Reduced” PTFE dispersions was 5 ppm based on wet weight of product. All of t he products made using APFO were sold in

2008.

II. COMPANY IDENTIFICATION

Identify the company and location of the facility s ubmitting information:

Company name:___Dyneon/3M

__________________

Site location:_____Gendorf, Germany____

Identify a company technical contact who can respon d to inquiries about the information
submitted: Technical contact:_George H. Millet_______________

____ Phone:_____651-733-5637

__________________________ Address:__6744 33 rd St N., Oakdale, MN, 55082

_________

III. PRODUCTION

Calendar year for which you are reporting: Jan 1, 2008 to Dec 31, 2008

# SANITIZED

SANITIZED Provide the amount of the product for the reporting year at each specific site:

Imported SANITIZED kg/yr

Manufactured Reduced APFO Dispersions SANITIZED kg/yr (wet weight)

IV. PRODUCT CONTENT

A. CONCENTRATIONS OF RELEVANT PERFLUOROALKYL CHEMIC ALS

Please provide the concentrations (ppb) of various perfluoroalkyl chemicals in your product. For chemicals for which you do not have a ctual data, please provide range
estimates.

Concentration of APFO in the Reduced APFO PTFE disp ersion product line was an average of 5 ppm based on wet weight of product.

The following is a nonexhaustive list of chemicals that should be included:

PFOA and its salts

• Octanoic acid, pentadecafluoro- (CAS 335-67-1)

• Octanoic acid, pentadecafluoro- ammonium salt (CAS 3825-26-1)

PFOA precursors

• Octane, 1,1,1,2,2,3,3,4,4,5,5,6,6,7,7, 8,8-heptadec afluoro-8-iodo- (CAS 507-63-1)

• 1-Decanol, 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-hep tadecafluoro- (CAS 678-39-7)

• 1-Decene, 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-hept adecafluoro- (CAS 21652-58- 4)

• 2-Propenoic acid, 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10 ,10-heptadecafluorodecyl ester (CAS 27905-45-9)

• 2-Propenoic acid, 2-methyl-, 3,3,4,4,5,5,6,6,7,7,8 ,8,9,9,10,10,10- heptadecafluorodecyl ester (CAS 1996-88-9)

• 2-Decenoic acid, 3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10 -hexadecafluoro- (CAS 70887- 84-2)

• Decanoic acid, 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10 -heptadecafluoro- (CAS 27854- 31-5)

Higher homologues

• Dodecane, 1,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,10, 10,11,11,12,12- pentacosafluoro-12-iodo- (CAS 307-60-8)

# SANITIZED

SANITIZED • Decane, 1,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10 -heneicosafluoro-10-iodo- (CAS 423-62-1)

• Nonanoic acid, heptadecafluoro- (CAS 375-95-1)

• Decanoic acid, nonadecafluoro- (CAS 335-76-2)

• 1-Decanol, 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-hep tadecafluoro- (CAS 678-39-7)

• Decane, 1,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-heptadeca fluoro-10-iodo- (CAS 2043- 53-0)

• Dodecane, 1,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,10, 10-heneicosafluoro-12-iodo- (CAS 2043-54-1)

• 2-Propenoic acid, 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,1 0,10-heptadecafluorodecyl ester (CAS 4980-53-4)

• 2-Propenoic acid, 2-methyl-, 3,3,4,4,5,5,6,6,7,7,8 ,8,9,9,10,10,11,11,12,12,12- heneicosafluorododecyl ester (CAS 17741-60-5) Part IV (cont.)

B. ANALYTICAL METHODS

Analyses should be conducted using the most accurat e instrumentation and procedures available as of the time of testing. Please provid e detailed information on the methods used (including analytical standards used, sampling , sample treatment, analysis), assumptions made, uncertainties and detection limit s (LOD, LOQ) for the data provided.

APFO concentration in liquid dispersion products is determined by esterifying the APFO in the dispersion sample with methanol and strong acid, an d quantifying it with a head space gas chromatography method using a mass spectrometer det ector. The usual control blanks and spikes are run. Detection limit is 1 ppm, RSD is + /- 1%.

# SANITIZED

SANITIZED 2010/15 PFOA Stewardship Program 

# Dyneon Gendorf Facility Report on Product

Content

I. CHEMICAL IDENTIFICATION

Identify the product (e.g fluoropolymer dispersion) for which you are submitting
information:

Product name:__ Liquid Fluoroplastic dispersions

__

Product description (including concentrations of pe rfluoroalkyl chemicals identified in Section IV below and year o f production):

This product family consisted of the commercially a vailable aqueous dispersions of melt processible fluoroplastics (PFA, FEP, ETFE, THV, et c.). The fluoroplastic dispersions contained an average of 38% by weight of fluoroplas tic in water. The use of APFO for the manufacture of these dispersions ceased on Apri l 1, 2008, and the new emulsifier was used exclusively after that date. The typical APFO content of the “APFO Reduced” fluoroplastic dispersions made before the April 200 8 transition was 50 ppm based on wet weight of product. All of the products made using APFO were sold in 2008.

II. COMPANY IDENTIFICATION

Identify the company and location of the facility s ubmitting information:

Company name:___Dyneon/3M

__________________

Site location:_____Gendorf, Germany____

Identify a company technical contact who can respon d to inquiries about the
information submitted: Technical contact:_George H. Millet_______________

____ Phone:_____651-733-5637

__________________________ Address:__6744 33 rd St N., Oakdale, MN, 55082

_________

III. PRODUCTION

Calendar year for which you are reporting: Jan 1, 2008 to Dec 31, 2008

# SANITIZED

SANITIZED Provide the amount of the product for the reporting year at each specific site:

Imported SANITIZED kg/yr

Manufactured

Reduced APFO Dispersions SANITIZED kg/yr (wet Weight)

IV. PRODUCT CONTENT

A. CONCENTRATIONS OF RELEVANT PERFLUOROALKYL
CHEMICALS

Please provide the concentrations (ppb) of various perfluoroalkyl chemicals in your product. For chemicals for which you do not h ave actual data, please provide range estimates.

Concentration of APFO in this product line was an a verage of 50 ppm based on wet weight of product.

The following is a nonexhaustive list of chemicals that should be included:

PFOA and its salts

• Octanoic acid, pentadecafluoro- (CAS 335-67-1)

• Octanoic acid, pentadecafluoro- ammonium salt (CAS 3825-26-1)

PFOA precursors

• Octane, 1,1,1,2,2,3,3,4,4,5,5,6,6,7,7, 8,8-heptadec afluoro-8-iodo- (CAS 507-63-1)

• 1-Decanol, 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-hep tadecafluoro- (CAS 678-39-7)

• 1-Decene, 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-hept adecafluoro- (CAS 21652-58-4)

• 2-Propenoic acid, 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10 ,10- heptadecafluorodecyl ester (CAS 27905-45-9)

• 2-Propenoic acid, 2-methyl-, 3,3,4,4,5,5,6,6,7,7,8 ,8,9,9,10,10,10- heptadecafluorodecyl ester (CAS 1996-88-9)

• 2-Decenoic acid, 3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10 -hexadecafluoro- (CAS 70887-84-2)

• Decanoic acid, 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10 -heptadecafluoro- (CAS 27854-31-5)

Higher homologues

• Dodecane, 1,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,10, 10,11,11,12,12-

# SANITIZED

SANITIZED pentacosafluoro-12-iodo- (CAS 307-60-8)

• Decane, 1,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10 -heneicosafluoro-10- iodo- (CAS 423-62-1)

• Nonanoic acid, heptadecafluoro- (CAS 375-95-1)

• Decanoic acid, nonadecafluoro- (CAS 335-76-2)

• 1-Decanol, 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-hep tadecafluoro- (CAS 678-39-7)

• Decane, 1,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-heptadeca fluoro-10-iodo- (CAS 2043-53-0)

• Dodecane, 1,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,10, 10-heneicosafluoro-12- iodo- (CAS 2043-54-1)

• 2-Propenoic acid, 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,1 0,10- heptadecafluorodecyl ester (CAS 4980-53-4)

• 2-Propenoic acid, 2-methyl-, 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,12-he neicosafluorododecyl ester (CAS 17741-60-5) Part IV (cont.)

B. ANALYTICAL METHODS

Analyses should be conducted using the most accurat e instrumentation and procedures available as of the time of testing. Pl ease provide detailed information on the methods used (including analytical standards used, sampling, sample treatment, analysis), assumptions made, uncertainti es and detection limits (LOD, LOQ) for the data provided.

APFO concentration in liquid dispersion products is determined by esterifying the APFO in the dispersion sample with methanol and strong a cid, and quantifying it with a head space gas chromatography method using a mass spectr ometer detector. The usual control blanks and spikes are run. Detection limit is 1 pp m, RSD is +/- 1%.

# SANITIZED

SANITIZED 2010/15 PFOA Stewardship Program 

# Dyneon Gendorf Facility Report on Product

Content

I. CHEMICAL IDENTIFICATION

Identify the product (e.g fluoropolymer dispersion) for which you are submitting
information:

Product name: Dry Resin Products_

Product description (including concentrations of pe rfluoroalkyl chemicals identified in Section IV below and year o f production):

This product family consisted of the commercially a vailable melt processible fluoroplastics (PFA, FEP, ETFE, THV, etc.) and PTFE , all sold as dry pellets or powders. The average APFO content of these products were all very similar, typically below 5 ppm 0.02% based on the weight of product. The use of A PFO for the manufacture of the melt processible fluoroplastics was discontinued in July 2008. The use of APFO for the manufacture of PTFE dry resin products was disconti nued at the end of December, 2008. The new emulsifier was used to manufacture these pr oducts after the dates mentioned
above.

II. COMPANY IDENTIFICATION

Identify the company and location of the facility s ubmitting information:

Company name:___Dyneon/3M

__________________

Site location:_____Gendorf, Germany____

Identify a company technical contact who can respon d to inquiries about the
information submitted: Technical contact:_George H. Millet_______________

____ Phone:_____651-733-5637

__________________________ Address:__6744 33 rd St N., Oakdale, MN, 55082

_________

III. PRODUCTION

Calendar year for which you are reporting: Jan 1, 2008 to Dec 31, 2008

# SANITIZED

SANITIZED Provide the amount of the product for the reporting year at each specific site:

Imported SANITIZED kg/yr

Manufactured

Dry Resin Products SANITIZED kg/yr (wet Weight)

IV. PRODUCT CONTENT

A. CONCENTRATIONS OF RELEVANT PERFLUOROALKYL
CHEMICALS

Please provide the concentrations (ppb) of various perfluoroalkyl chemicals in your product. For chemicals for which you do not h ave actual data, please provide range estimates.

Concentration of APFO in this product line was an a verage of 2 ppm based on dry weight of product.

The following is a nonexhaustive list of chemicals that should be included:

PFOA and its salts

• Octanoic acid, pentadecafluoro- (CAS 335-67-1)

• Octanoic acid, pentadecafluoro- ammonium salt (CAS 3825-26-1)

PFOA precursors

• Octane, 1,1,1,2,2,3,3,4,4,5,5,6,6,7,7, 8,8-heptadec afluoro-8-iodo- (CAS 507-63-1)

• 1-Decanol, 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-hep tadecafluoro- (CAS 678-39-7)

• 1-Decene, 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-hept adecafluoro- (CAS 21652-58-4)

• 2-Propenoic acid, 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10 ,10- heptadecafluorodecyl ester (CAS 27905-45-9)

• 2-Propenoic acid, 2-methyl-, 3,3,4,4,5,5,6,6,7,7,8 ,8,9,9,10,10,10- heptadecafluorodecyl ester (CAS 1996-88-9)

• 2-Decenoic acid, 3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10 -hexadecafluoro- (CAS 70887-84-2)

• Decanoic acid, 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10 -heptadecafluoro- (CAS 27854-31-5)

Higher homologues

# SANITIZED

SANITIZED • Dodecane, 1,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,10, 10,11,11,12,12- pentacosafluoro-12-iodo- (CAS 307-60-8)

• Decane, 1,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10 -heneicosafluoro-10- iodo- (CAS 423-62-1)

• Nonanoic acid, heptadecafluoro- (CAS 375-95-1)

• Decanoic acid, nonadecafluoro- (CAS 335-76-2)

• 1-Decanol, 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-hep tadecafluoro- (CAS 678-39-7)

• Decane, 1,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-heptadeca fluoro-10-iodo- (CAS 2043-53-0)

• Dodecane, 1,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,10, 10-heneicosafluoro-12- iodo- (CAS 2043-54-1)

• 2-Propenoic acid, 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,1 0,10- heptadecafluorodecyl ester (CAS 4980-53-4)

• 2-Propenoic acid, 2-methyl-, 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,12-he neicosafluorododecyl ester (CAS 17741-60-5) Part IV (cont.)

B. ANALYTICAL METHODS

Analyses should be conducted using the most accurat e instrumentation and procedures available as of the time of testing. Pl ease provide detailed information on the methods used (including analytical standards used, sampling, sample treatment, analysis), assumptions made, uncertainti es and detection limits (LOD, LOQ) for the data provided.

APFO concentration in dry products is determined by extraction of the APFO in the sample with methanol or acetonitrile, followed by a nalysis using LC-MS. The usual control blanks and spikes are run. Detection limit is 0.1 ppm, RSD is +/- 1%.