p. 1



# OAR Box 1672 Prepped by Charmelle Mathews



# Dopumen^Number:

Docket Number: 

# A-98-1 3

Printed 9/30/200811:01:00AM

Sheet 56 of 132P. 2

f I 

# ; A 9 8 1 3

^ t o sr« ,



### _ _UNITE D STATE S ENVIRONMENTA L PROTECTIO N AGENC Y f ^£ 7 « Offic e o f Ai rQualit y Plannin g an d Standard s \^|££ > /

Researc h Triangl e Park , Nort h Carolin a 2771 1



## Mr

. Mik e Holdma n AP R1 3 199 8 StanTrans , Inc

. ; 

## - r 20 1 Doc k Roa d P O Box 360 8 Texa s City , TX 7759 2
Dea r Mr

. Holdman : Thi s letter i s t o reques t

avisi t b y th e U.S

. Environmenta l Protectio n Agency (EPA ) and it s representative s t o th e StanTran s facilit y in Texa s City , Texa s o n Apri l 23 , 1998

. Visitor s wil l include Mr

. Stephen Shed dofth e EPA , andMr

. Gre g LaFlamandMr

. Bern d Hanek e o f Pacifi c Environmental Services , Inc

. (PES)

. Mr

. LaFla mof PE S discusse d thi s visi t wit h yo u i n atelephon e conversatio n o n Apri l 8 , 1998

. W e anticipat e arrivin g a

t th e facilit y a t 9:0 0 a.m . A s yo u ar e aware , th e EPA i s developin g nationa l emissio n standard s fo

r hazardou s ai r pollutant s (NESHAP ) for

organi c liquid s distributio n (non-gasoline ) facilities

. Th e mai n emissio n source s o

f interes t are a s follows : 1 ) storag e tanks ; 2 ) loadin g an dunloadin g operations ; 3 ) equipment

leaks ; 4 ) wast

e andwastewate

r treatment anddisposa

l operations ; an d 5 ) mixin g and blendin g operations

. T o assis t i n th e developmen

t o f thi s NESHAP , the EP A i s collectin g informatio n o n emission s of hazardou s air

pollutant s (HAP ) fromthes e emissio n source s and o n th e type s of emissio n control s use do n eac h o f th e sources . Durin g th e visi t

t o you r facility , w e wis h to : 1 ) discus s th e facilit y andemissio n contro l operations ; an d 2 ) observ e th e storag e tanks , wastewate r systems , organi c liqui dtransfer operations , an d an

y associate d emissio n contro l andemissio n monitorin g equipment

. Enclosure 1 identifie s th e typ e o f informatio n tha

t w e woul dlik

e t o obtai n durin g our

visit , an d als o contain s alistin g of th e material s considere dt o b e HA P b y th e EPA

. Fee l free t o provid e an

y additiona

l informatio n tha

t yo u believ e i s critical t o ou r understandin g of

thes e processes , thei r

HA P emissions , o r

m e emissio n controls

. Collectio n andorganizatio n o f th e informatio n identifie d i n Enclosure 1 prio r t o ou r visi t wil l greatl y facilitat

e informatio n exchang e durin g th e visit

. Th e authorit

y for th e EPA' s informatio n garnerin g i s include di n sectio n 11 4 ofth e Clean Ai r Ac t (4 2 U.S.C

. 7414)

. Enclosure 2 contain s asummar y of thi s authority

. If

yo u believ e tha

t disclosure o

f th e informatio n w e reques t wouldreveal atrad e secret , you shoul d clearl y identif

y suc h informatio n a s discusse di n th e enclosure

. An y informatio n subsequently determine d to constitute atrad e secret wil l b e protecte dunder

1 8 U.S. C 1905

. If

n o clai mo fP. 3



## confidentialit

y accompanie s th e information whe n it i s receive db y di e EPA , i t ma y b e made availabl e t o th e publi c b y th e EP A without furthe r notic e (4 0 CF

RPart 2.203 , Septembe

r 1 , 1976)

. Sinc e sectio n 114(c ) o f th e Clea n Air Ac t exempt s emissio n datafromclaim s of confidentiality , th e emissio n datayou provid e ma y b e made availabl e t o th e public

. A clarificatio n of

wha t th e EP A consider s to b e emissio n dat ai s containe di n Enclosure 3

. A s note d i n Enclosur

e 4 , th e EP

A ha s designate dPE S as a n authorize drepresentativ e o f th e Agency

. Therefore , PE S ha s th e right s discusse dabov e an di n Enclosure 4

. A s a

n audiorize d representativ e ofth e EPA , PE S i s subjec t t o th e provision s of

4 2 U.S.C

. 7414(c ) respectin g confidentialit

y o f method s o r

processe s entitle dto protectio n a s trad e secrets

. The PE S contrac t

wit h th e EP A i s No

. 68-D60013

. Enclosure 5 summarize s th e EP A policie s an

dprocedure s fo

r handlin g privilege d informatio n an d describe s the EP A contractor

commitment s an

dprocedure s fo

r us e o f confidentia

l materials

. It

i s th e EPA' s policy tha

t complianc e b

y a n authorize drepresentativ e wit h th e requirement s detaile d in Enclosur e 5 provide s sufficien

t protectio n o f

th e right s o f thos e submittin g privilege d information

. Th e followin g policie s concernin g liabilit y shoul dals o b e of

interes t t o you : 1

. If aFederal employee i s injuredi n th e cours e o f hi s employment , h e ha s compensatio n coverag e fromth e Governmen t under th e Federa

l Employee s Compensatio n Act ( 5 U.S. C 810 8 e t

seq.) ; an d
2

. If , du e t o th e employee' s negligence , propert y damag e o r

persona l injur y t o third partie s occurs , th e Federal Tort Clai mAct

(2 8 U.S.C

. 1346 ) provide s amean s o f fixin g an y liabilit y upo n th e Federa

l Government

. Th e Offic e o

f Genera l Counsel ha s informedth e Agenc y tha t afirmma y no t conditio n th e EPA' s "righ t

o f entry " upo n consen

t to awaive

r of liabilit y andha s instructe demployee s no t t o sig n suc h waivers

. I

f yo u hav e an y question s regardin g thi s refusal , pleas e contac t th e EPA' s Genera

l and Informatio n La

w Divisio n a

t (202 ) 260-0020

.



# 7_

_P. 4



### ^



## Than

k you fo r your cooperation

. I f

you have an

y questions , pleas e contac t

Mr

. Stev e Shed d o f m y staf f at (919 ) 541-5397 , o r

Mr

. Gre g LaFla

mo f PE S a t (919 ) 941-0333

. Sincerely , 

# /& > C {&"*=—
Ken t C

. Hustvedt , Leade

r Qprtf^^f Wast e an dChemica l Processe s Grou

p Emission Standard s Division 5 Enclosure s

cc : Bil l Luthans , EP A Regio n V I (w/ o Enclosure s 2-5 ) Rober t Todd , TNRC C (w/

o Enclosure s 2-5 )P. 5



## Enclosure 1

SUMMAR

Y O F ORGANI C UQUID S DISTRIBUTION INFORMATIO N O F INTERES T

T o assis t in th e collectio n o f

informatio n durin g th e requeste dsite visit , asummar y of th e informatio n t o b e collecte d i s provide dbelow

. At thi s time , tiiis informatio n pertain s specifically to eac h o f

th e emissio n source s o f

interest : 1 ) storag e tanks ; 2 ) loadin g an d unloadin g operations ; 3 ) equipment leaks ; an d4 ) waste an dwastewater treatmen t an ddisposal activities

. A s w e learn mor e durin g th e visit , additiona l HA P source s coul db e adde dt o ou r scope . 1

. Produc t

throughput s (e.g. , bbl/yea r o f eac h organi c liquid) , an dproces s technica l description , wit

h simplifie dschematic s an daplo t plan o f th e entir e facility

. 2

. Types/concentration s o f hazardou s ai r

pollutant s (HAP ) i n tanks/wastewate r stream s (o r

annualize dmas s emissio n rates ) prio r t o emissio n contro l device

. 3

. Type s o f

emissio n reductio n measure s o r contro l device s associate dwit h eac h of th e emissio n sources , if

any . 4

. Contro l devic e efficiency o r concentratio n o f

HA P i n ai r

stream s (o r

annualize d mas s emissio n rates ) subsequent to th e emissio n contro l device(s) , i f applicable

. 5

. Capita

l and operatin g cost s associate dwit h th e emissio n contro l device(s) , i f applicable

. 6

. Operatin g an d maintenanc e experienc e associate dwit h th e emissio n contro l device.s ) (i.e. , identif

y ke y operatin g parameter s for efficien t control , parameter s tha

t indicate poo r

control , o r

problem s associate dwit

h aspecifi c emissio n source/contro l devic e combination)

. 7

. Type s of

emissio n monitorin g device s use dto monito r emission s o r

contro l devic e performance , a s applicable

. 8

. Rational e fo r

selectin g an

y emissio n contro l device s currenti y installe do n th e operations

. 9

. Regulator

y histor y andcurren t

regulator y requirement s associate dwit h emission s fromth e operations

.



# 4

-htipyAw»w_8pMW/eMfai_g-WI-litta^ll^i,t» t P. 6

SE C 11 2 HAZARDOU

S AI RPOLLUTANT

S • 7/8/9 6 updat

e Thi s draf tlis tinclude

s curren tEP A staf f recommendations for technica l collection s an

d clarification

s o f th e hazardou

s ai r pollutant

s (HAP ) lis ti n Section 112(bXl ) ofth e Clea n Air Ac tThi s draf tha s bee n distribute

d to appris

e intereste d pattie s o f potentia l futur e change s i n th e HA P lis tan d i s Informationa

l only . Th

e recommende

d revision s ofth e curren

tHA P lis t whic h ar e include d i n this draf tdo notthemselves chang e th e lis ta s adopte

d b y Congress an

d hav e n o lega l effec tEP

A intend s t o propos

e specifi c revision s o f ih e HA P list , induding an

y technica l collection s o r clarification s o f the list , onl y throug h notice an

d commen trulemaking

. " " CAS No . Pollutan

t 75-07- 0 Acetaldehyd

e 60-35- 5 Acetamid

e 75-05 4 Acetonitrile 9846* 2 Acetophenon

e - 53-96- 3 2-Acetylaminofluoren e 107-02 4 Acrolein 79-06- 1 Aoylamid c 79-10- 7 Acryli c acid 107*13- 1 Aerylonitrile 107-05- 1 Allyich.or.d e 92*67* 1 4-Arainobipheny i 62*53-3 Aniline 90-04- 0 O-Anisidin

e 1332-21- 4 Asbesto s 71*43* 2 Benzen

e (includin g benzen e fro m gasoline ) 9247* 5 Benzidin

e 98-07* 7 Bcnzotrichlorid e 100-44- 7 Benzy

l chlorid e 92*52- 4 Bipheiry

l 11741* 7 Bis(2*ethylhexyl)phthalate(DEHP ) 54248- 1 Bis.chloromeu.yl ) ethe r 75-25- 2 Bromofoi

m 10649- 0 1,3-Butadien

e 156-62- 7 Caldu

m cyanamid

e 105-60- 2 Caprolacta

m (Remove

d 6/18/96 , 61FR30816) 133*06- 2 Capta n 63-25- 2 Carbary

l 75*15* 0 Carbo

n disulfide 56-23* 5 Carbo

n tetrachlorid

e 463-58* 1 Carbony

l sulfid e 12040- 9 Catecho

l 133-90- 4 Chlorembe

n 57-74 4 Chlordan

e 7782*50-5 Chlorin

e 79*11 4 Chloroaceticad d 532-27- 4 2-Chloroacetophcnon e 108-90- 7 Chlorobenzen

e 510-15- 6 Chlorobcnzilat e 67-66- 3 Chlorofor

m 107-30- 2 Chloromethy

l methy l ethe r 126-99 4 Chloropren

e 1319-77- 3 Cresol/Cresyli

c acid (mixe

d isomers) 95*48-7 o-Crcso

l 108-39* 4 m-Creio

l 106-44* 5 p-Crcso

l 9842- 8 Cumen

e N/ A 2,4-D(2.4-Dich)orophenoxyacetic Acid ) (includin

g salt s an d esters ) 72-55- 9 DDE(!.l-dichloro-2a-bi s

(p-chlorophen

y I ) ethylene) 33448- 3 Diazomethan e 13244- 9 DibenzoAira n CAS No . Pollutan tCAS No . 96*12 4 l,2*Dibromo-3-chloropropan e 62443* 9 84*74* 2 Dibuty l phthalat e 80-62- 6 106-46- 7 1,4-DkhlorobetBen e 1634-04- 4 91-94* 1 3,3'-Dlchlorobenzidin e 101-14- 4 111-44- 4 Dichloroethy

i ethe r 75-09- 2 (Blst2-chloroethyi]ether

) 542*75* 6 14-Dichloropropen

e 101-68 4 62*73* 7 Dichlorvos 111-42- 2 Diethanolamin

e 101*77 4 64-67*5 Diethy

l sulfat e 91-20- 3 11940- 4 3J^lmethnxyben_idin e 98*95- 3 60*11* 7 4-Dimethylaminoazoben_en e 92*93*

3 121*69* 7 N,N-Dlmethyisnilta

e 100-02- 7 119-93* 7 3J'*Dlmettiytbenzldin

e 7946- 9 79-44*7 Dlmetbylcarbamoy l chlorid e 684-93- 5 68*12-2 HN-Dimeihylfbimainide 62*75- 9 57*14* 7 1,1-Dtmethyibydrazin

e 5949* 2 131-11* 3 Dimethy

l phthalat e 56*38- 2 77*78* 1 Dimethy

l sulfite 82*68 4 N/ A 4,6-Dinitro-o-creso l (including salts ) 51*28* 5 2,4-Dinirrophen

d 8746- 5 121-14*2 2,4-Dinitrotoluen e 108-95- 2 123-91- 1 l,4-Dloxane(l,4-Dlethyleneoxide ) 106-50- 3 122*66* 7 1.2-Diphenylhydrazin

e 75-44- 5 10649 4 Epfchtarohydrf

n 7803*51- 2 fl-Chlo-o-24-epoxypropsne) N/ A 10648- 7 U-Epoxybutan e 85*44 4 14048* 5 Ethy

l aoylat e 1336-36- 3 10041- 4 Ethylbenzen

e 51*79- 6 Ethy

l carbamat

e (Urethane

) 1120-71- 4 7540- 3 Ethy

l chlorid e (Chlomethane

) 57-57 4 10643 4 Ethylen

e dujromi<fc(D.rOTmoethane ) 123*38*

6 107*06- 2 Ethylen e dichlorid

e 114*26- 1 (U-Dichloroethane ) 7847- 5 107-21* 1 Ethylen

e glyco l ' 151*56 4 Ethyleneimtae(A_iridiiie ) 75-56 4 75-21 4 Ethylen

e oxid e 75*55 4 Ethylen e thioure a Ethyliden e dichlorid e 91*22- 5 (I.l-Dlchloroethane ) 106-51 4 Formaldehyd

e 10042- 5 Heptachlo r 96-09- 3 Hexachlorobenzen

e . 1746-01- 6 Hexachlorobutadicn

e 1A3,4,S.6-Hexachlorocyclyhexan e 79*34*

5 (ai l stereo isomers , includin

g 127*18 4 lindane ) Hexachlorocydopentadien

e 755045- 0 Hexachloroethan

e 10848- 3 Hexamethylen

e diisocyanat

e 9540- 7 680-31 4 Hexamethylphosphoramid e 58444- 9 110-54* 3 Hexan e 95*53 4 30241* 2 Hydrazin

e 8001-35- 2 764741-OHydrochlori

e aci d (Hydroge

n 12042- 1 chlorid e (ga s only] ) 79-00- 5 7664*39-3Hydroge

n fluoride (Hydrofluori

c 7941 4 add ) 9545 4 123-31 4 Hydroquinon

e 8846- 2 78-59- 1 Isophoron

e 12144 4 108-31 4 Malei

c anhydrid

e 1582-09 4 67*56* 1 Methano

l 54044* 1 Methoxycnio

r 108-05 4 Methy l bromid e (Bromometbane

) 593*60-2 Methy l chlorid e (Chlorornethane

) 7541 4 Methy l chlorofor m 75*35 4 (I , I . I •Trichloroethane

) Methy l ethy l keton e (2-Butanone

) 1330-20- 7 Methylhydrazin

e 9547 4 Methy l iodid e (lodomethane

) 108-38- 3 Methy l isobuty l keton e (Hexone) 10642- 3 9645- 7 75-34- 3 50-00- 0 7644 4 118-74* 1 8748- 3 N/ A

7747 4 67-72- 1 822-06 4

7243- 5 7443 4 7447- 3 71-55 4 7843- 3 60-34 4 74-88 4 108-10- 1 Pollutan t. Methy l isocyanat

e Methy l methacrylat

e Methy l tot-butyl ethe

r 4,4 , *Methylenebis(2-chloroanifine ) Methylen e chlorid e (Dichloromethane

) 4,4'-Methylcnedipheny

l diisocyanat

e (MD 0 4,4'*Methylenedianilin

e Naphthalen

e Nitrobenzen

e 4-Nitrobipheny

l 4-Nitropheno

l 2-Nitropropan

e N-Nitroso-N-methylure

a N-Nitrosodimethylamin

e N-Nitrosomorpholin

e Parethio n Pentachloronhrobenzen

e (Quintobenzene

) Pentachloropheno

l Pheno l p-Phenylenedianiin

e Phosgen e Phosphin e Phosphoru s Compound

s Phthali e anhydrid e Polychlorinate

d biphenyl

s (Arodon ) U-Propan e sulton

e beta-Propiolacton

e Propionaldehyd

e Propoxur(Baygon

) Propylen e dichlorid

e (1,2-Dtchloropropane

) Propylen e oxid e 1,2-Propylenirain

e (2-Methylaziridiiie

) Quinolin e Quinon e (p-Benzoquinone

) Styren e Styren e oxid e 2-3,7,8-Tetrachlorodibenz

o -p-dioxi n 1,1^2-Tetrachloroethan

e Tetnchloroethylen

e (Perehloroethylene

) Titaniu m tetrachlorid

e Toluen e Toluene-2.4-dian.in

e 2,4-Toluen

e diisocyanat

e o-Toluidln

e Toxaphen e (chlorinate

d camphene

) 1,2.4-Trichlorobenzen

e 1,1,2-Triehloroethan

e Tricbloroethylen

e 2.4,5-Trichloropheno

l 2,4,6-Trichloropheno

l Triethytamin

e Triflurali n 2-2,4-Trlmethylpentan

e Viny l acetat e Viny l bromid e Viny l chlorid e Vinyliden e chlorid e (1,1-Oichloroethylene

) Xylene s (mixe d isomers ) o-Xylen e m-Xylen e p-Xylen e 

# ISP. 7 http , Jwww^)«40^owfe-qp-%ictox/188polh.Oi t
Antimon y Compound s Indude s mono - an d di-ether s o f ethylen e Arseni c Compound s glycol , diethylen e (inorgani c indudin g anine ) glycol , an d triethylen e glyco l R*(0CH2CH2) n Berylliu m Compound s -OR * wher e Cadmiu m Compound s n-1,2 , o r 3 Chromium Compound s R"alky l o r ar y I group s Cobal tCompound s R ' "R.H , o r group s which , whe n removed, Cok e Ove n Emission s yid d glyco l Cyanid e Compounds l ether s wit h th e structure : R-.0CH2CH2)n-0H . Glyco l ethen 2 Polymer s are exdude d Lead Compound s from th e glyco l category . Manganes e Compound s Mercur y Compound s 3 (Unde rReview ) Fin e mineral fibets3 Nick d Compound s 4 (Unde rReview ) Porycydl c Organi c Matter

4 Radionudide s (includin g ndon) S 5 A typ e o f ato m whic h spontaneousl y Seleniu m Compound s undergoe s radioactiv e decay . NOTE : Fo r d l listing s above whic h contai n th e word "compounds " an d for glyco l ethers , th e following applies : Unles s otherwis e specified , thes e listing s ar

e define d a s indudin g an y uniqu e chemica l substanc e tha

tcontain s th e name d chemic d (Le . antimony , arsenic , etc. ) a

s par to f tha tchemicd' s infrastructure . IJCC N wher e X • H

" o r any othe r grou p wher e a formal dissociatio n may occur . Fo rexample , KC N o r Ca(CN)2 . 2 (Unde rreview) Glyco l Ethe rdefinitio n draf toptions : Possibl e Correctio n t o CA

A 112(bXl ) footnot e thatwoul d b e consisten twit h OPPT S modifie d definition . Ne w OPPT S definitio n a

s publishe d fat:
R• (OCH2CH2) n - OR ' where : n-1,2 , o r 3 R-alky l C 7 o r les s o r R
- pheny l o r alky l substitute d pheny l R'
- Ho r alky l C 7 o r les s o r OR* " carboxyll c aci d ester , sulfate , phosphate , nitrat

e o r sulfonate CA A Glyco l ethe rdefinitio n exactl y a s i n th e statut e (error s induded) : Indude s mono * an d d i ether s o f ethylen e glycol , diethylen e glycol , and triethylen e glyco l R- (0012012)0-0 ^ wher

e n-1,2 , or. 3 R- alky l o r aryl group s R * • RJi o r group s which , whe n removed, yiel d glyco l ether s wit h thestnictureR*(0CH2CH)n-0H . Polymer s ar e exdude d fro m th e glyco l category
. CA A Glyco l ethe rdefinitio n with technica l correctio n made.( A 2 w u lef tou tofth e las t formula ) 

# * 6P. 8
Antimon y Compound

s *-ndude s mono-ai d dl*ctbe n o f ethylene Aneni c Compound

s glycol , diethylen e (•Mrgani c Grindin g irrint ) gryra^andtriethyknegrycc4R<0aCCH2) n Berylliu m Compound

s -OR * wher e Cadmiu m Compound

s n-1,2 , o r 3 Chromiu m Compound

s R
- alky l o r aiy i group

s Cobal tCompound

s R'-R , H,o r group s which , whe

n removed . Cok e Oven Emission

s yid d glyco l Cyanid e Compounds

l ether s wit h the structur

e R-(OCH2CH2)n-OH

. Glycolethere2 Polymer s ar e exdude d Lea d Compound

s from th e glyco l categoiy . Manganes e ~ Mercur y Compound

s 3 (Unde r Review ) Fin e mineta l fibertf Nidc d Compound

s 4 (Unde r Review) Polycydi c Organi

c Muter t Radionudlde

t(includin g iadon) 5 5 A typ e o f ato m whic h spontaneousl

y Seleniu m Compound

s undergoe s radioactiv

e decay . NOTE : Fo

r ai l listing

s abov e whic h contai n th e wor d "compounds " an d for glyco l ethers , die following applies : Unlet s otherwise tpedfled , thes e listings ar

e define d a s indudin g an y uniqu e chemica l substanc e tha tcontain s th e name

d ehemicd(Le . antimony , arsenic, etc ) a

s par to f tha tchemical' s bulauracoire . WC N wher

e X - I f o r an y other grou

p wher e a formal dissociation ma y occur . Fo

r example, KC

N o r Ca(CN)2 . 2 (Unde r review) Glyco l Ethe r definitio n draf toptions : Possible Correctio

n t o CA A 112(bXl ) footnot

e tha twoul d b e consisten twhh OPPT

S modifie d definition . Ne w OPPTS definitio

n a s publishe d is : R- (OCH2CH2)

n - OR ' where : n-IAor 3 R->tlkyiC7orles s orR- > pheny

l ordky l substitute d pheny l R > Ho r alkyl C 7 o

r les s o r OR"
- carboxylic aci

d ester , sulfate , phosphate , nitrat e o r sulfonat e CAA'Glyeo

l ethe r definitio n exactly a

s i n the statut e (error s induded) : Indude s mono * an

d d i ether s o f ethylen e glycol , diethylen

e glycol , an d triethylen

e glyco l R• (OOQOOn-OR * wher

e n-IAor- 3 R-iIky l o r ary

tgroup s R * -»R» H o r group

s which , whe n removed, yid d glyco l ethe n whh th e structur e R*(OCH2CH)n-O

RPolymer

s ar e exdude d fro m the glyco

l categoiy . CA A Glyco l ethe

r definitio n wit h teehnic d correctio n made.( A 2 w u lef

tou tofth e las t formula ) 

# 9i 7P. 9



## Docke t No

. A-98-1 3 Subcategor

y ¥I- C

The enclosure s wit

h thi s documen

t ar e identica l t o th e enclosure s wit

h docket ite m3L-C- 3



# 1