P. 1



# OAR Box 1672
Prepped by Charmelle Mathews



# V Document

Number: 

# ll-B-1 4

Docket Number: 

# A-98-1 3

Printed 9/30/2008 11:01:00AM

Sheet 20of 132

### TO :

FROM :
DATE : MEMORANDU M

Marth aSmith , OAQPS/ESD/WCP G

Greg LaFla

mand Bern d Haneke , PES , Inc

. J^T\ ^

Octobe r 28,199 9

SUBJECT : Draf

t Lis t o f HA P Compound s an

d Propertie s fo

r API

Durin g th e Octobe

r 5,199 9 EP

A Stakeholder s meetin g fo

r th e Organi c Liquid s Distributio n (OLD ) NESHAP , th e America n Petroleu mInstitut e (API ) requeste d t o obtai n acop y ofth e tabl e fro

mwhic h th e EP

A obtaine d HA

P physica l propertie s t o mak

e it s tabl e o f

affected HA P ("Organi c HA

P fo r OL D NESHAP")

. Th

e attache d tabl e list s al l ofth e HAP compound s an d their respectiv e propertie s fromwhic h th e above-mentione d tabl e wa s compiled

. Th e attache d HA

P tabl e wa s create d by Research Triangl e Institute (RTI ) fo r th e EP A usin g th e Water 8 dat abas e fo r HAP compound physica

l properties

. Value s wer e presente d i n millimeter s ofmercur

y (m mHg) , whic h wer

e converte d t o pound s pe r

squar e inc h absolut

e (psia ) by multiplyin g th e m

mH g value s b y 0.0193 4 (14. 7 psia/76 0 m mHg)

. Th e vapo r pressure s fo

r th e HA P i n thi s tabl e ar

e base d on areferenc e temperatur e o f 25 ° C

. The tabl e o f

organi c HA

P presente d in th e Stakeholder s meetin g wa s compile d b y firs t considerin g al l HA

P compound s identifie d in th e OL D dat abase

. Thi s tabl e wa s the n supplemente d wit

h organi c HA

P take n fromTabl e 2 t o subpar t F ofth e HON "Organi c Hazardou s Ai

r Pollutants " fo

r complet e coverag e o f

all organi c HA

P tha t coul d potentiall y b e i n liquid s affecte

d b y th e OL

D MAC T rule

. Onc e th e compilatio n wa s complete , th e tabl e wa s sorte d in descendin g orde

r b y vapo r pressur e (usin g value s fromth e RT I table)

. Organi c HA

P compound s wit

h les s tha n 0. 1 psi avapo r

pressur e a t 25 ° C wer e delete d fromth e table

. Th e famil y o f chemical s collectivel y calle d "glyco l ethers " wa s collapse d into asingl e entit y fo r th e tabl e versio n presente d a

t th e meeting

. It

i s anticipate d tha

t futur e rendition s ofth e affected HA P tabl e wil l lis t

all ofth e affecte

d glyco l ether s separately

.P. 3



### Mem o on HA P Compound s Octobe r 28,199 9 Pag e 2
Tabl e of 26 7 HA P Compound

s an d Chemica

l Propertie s

Compoun d nam e Cyanotoluen e 4 Chloromethan e (methylchloride ) Formaldehyde Viny l Chloride Butadiene-(1,3 ) Phosphin e Diazomethan e Bromomethan e Phosgen e (decomposes ) Ethylen e Oxide Chloroethan e (ethy l chloride ) Hydrofluori c Aci d Acetaldehyde Hydrocyani c Aci d Carbony l Sulfid

e Hydrogen Chloride Vinyliden e Chlorid e se e 1, 1 dichloroethen e 1, 1 Dichloroethen e vinyliden e chloride Dichloroethane ( 1,1 ) ethylidenedichloride 1, 2 Epoxypropan e (propyleneoxide ) Methylen e Chloride , dichloromethan e Triethylamin e Methy l Iodide Viny l Bromid

e Ally l Chloride ( 3 chloropentene ) Carbon Disulfid

e Propana l (propionaldehyde ) Chloropren e Propena l (acrolein ) Chloromethy l Methy l Ethe r Chlorofor m Cyanopyridin e (-4 ) CA S Number

104-85- 8 74-87- 3 50-00- 0 75-01- 4 106-99- 0 7803-51- 2 334-88- 3 74-83- 9 75-44- 5 75-21- 8 75-00- 3 7664-39- 3 75-07- 0 74-90- 8 463-58- 1 7647-01- 0 75-35- 4 75-35- 4 75-34- 3 75-56- 9 75-09- 2 121-44- 8 74-88- 4 59360 2 107-05- 1 75-15- 0 123-38- 6 126-99- 8 107-02- 8 107-30- 2 67-66- 3 100-48- 1 Vapo r

Pressur e (m m H g a t2 5 des

. O 95160.0000 0 3830.0000 0 3500.0000 0 2660.0000 0 2100.0000 0 2000.0000 0 1782.0000 0 1590.0000 0 1390.00000 1250.00000 1200.00000 900.0000 0 870.0000 0 726.0000 0 711.4000 0 680.2000 0 630.0000 0 630.0000 0 591.0000 0 525.0000 0 438.0000 0 400.0000 0 400.0000 0 380.7000 0 368.0000 0 366.0000 0 300.0000 0 273.0000 0 244.0000 0 223.1000 0 208.0000 0 189.8000 0

### Memo o n HA P Compound s

Octobe r 28,199 9 Pag e 3
Tabl e o f

26 7 HAP Compounds an d Chemica

l Propertie s (continued ) P. 4

Compoun d nam e Cyanopyridin e 3 Methyl Tert-Buty l Ethe

r Methyl Isocyanat

e Aziridin e ethylen e imin

e Dimethy l Hydrazine ( 1,1 ) Propylenimin e 1,

2

. 2 methyl aziridine Hexane (-n ) Trichloroethan e 1,1, 1 methyl chlorofor m Viny l Acetat

e Methano l Acrylonitril e Carbon Tetrachloride Nitropropan e 2 2 Butanon e (methy l ethyl ketone , MEK ) Benzene Acetonitril e Acetamid e Ethylene Glyco l Dimethy l Ethe r DichIoroethane ( 1,2

) Trichloroethylen e Epoxybutan e 1,

2 Methyl Hydrazin e 1, 3 Dichloropropen e Trimethylpentan e 2,2, 4 Ethy l Cyanid

e Opropionitrile

) Propionitril e Ethy l Acrylat

e Dichloropropane 1,

2 Methyl Methacrylat

e l,4Dioxan e Bis(ChloromethyL ) Ethe

r Toluene CA S Numbe r 100-54- 9 1634-04- 4 624-83- 9 151-56- 4 57-14- 7 75-55- 8 110-54- 3 71-55- 6 108-05- 4 67-56- 1 107-13- 1 56-23- 5 79-46- 9 78-93- 3 71-43- 2 75-05- 8 60-35- 5 110-71- 4 107-06- 2 79-01- 6

60-34- 4 542-75- 6 540-84- 1 107-12- 0 107-12- 0 140-88- 5 78-87- 5 80-62- 6 123-91- 1 542-88- 1 108-88- 3 Vapo r

Pressure (m

m Hg at2 5 deg*

. O 189.8000 0 185.9000 0 164.4000 0 160.0000 0 157.0000 0 153.3000 0 150.0000 0 123.0000 0 115.0000 0 114.0000 0 114.0000 0 113.0000 0 101.5000 0 100.0000 0 95.2600 0 90.0000 0 86.0600 0 83.7300 0 80.0000 0 75.0000 0 66.4100 0 49.6000 0 43.0000 0 40.6000 0 40.0000 0 40.0000 0 40.0000 0 40.0000 0 39.0000 0 37.0000 0 30.0000 0 30.0000 0P. 5



### Mem o o n HA P Compound s Octobe r 28,199 9 Pag e 4
Tabl e o

f 267 HAP Compounds an d Chemica

l Propertie s (continued )

Compoun d nam e
1,1, 2 Trichloroethan e Tetrachloroethen e Epichlorohydri n Methy l Isobuty l Ketone 4 Methy l 2 Pentanone (MIBK ) Hydrazin e Ethylen e Dibromid

e 1,2,3, 4 Tetrachlorodibenzo[be][l,4 ] Dioxin 2,2 , ,3,3',4,4 ' PC

B 1,2, 4 Trichlorodibenzo[B,E][l,4 ] Dioxin 2,7Dichlorodibenzo[B,E][l,4]Dioxi n 3,3',4,4'PC B 2,2 , ,4,4',5,5 ' PC B 4,4'PC B 2,2',3,3 ' PC B 3,4'PC B 3,3 ' PC B 2,2',4 ) 5,5 , PC

B 2,4,4 ' PC B Hydrogen Fluoride 2,3', 5 PC B 2,2 ' PC B 2,2',5,5 ' PC

B 2, 5 PC B 2,2',5,6 ' PC B 2,4, 6 PC B 2,2',4,4\6,6 ' PC

B 2,2',4,6,6 ' PC B Chlorobenzen e 1, 2 Dibromoethan e Naphthol.beta

Phenvbheno l P CAS Numbe r 79-00- 5 127-18- 4 106-89- 8 108-10- 1 108-10- 1 302-01- 2 106-93- 4 3074658 8 3838007 3

33857-26 0 3259813 3 3506527 1 205068 2 3844493 8 2974927 2050-67 1 3768073 2

7664-39- 3 3844481 4 13029-08 8 3569399 3 34883-39 1 4146441 9 3569392 6 3397903 2 5655816 8 108-90- 7 106-93- 4 135-19- 3 92-69- 3 Vapo r

Pressure (m

m Hg a t2 5 deg
. C) 25.0000 0 19.0000 0 17.0000 0 15.7000 0 15.7000 0 14.4000 0 14.0000 0 12.0000 0 12.0000 0 12.0000 0 12.0000 0 12.0000 0 12.0000 0 12.0000 0 12.0000 0 12.0000 0 12.0000 0 12.0000 0 12.0000 0 12.0000 0 12.0000 0 12.0000 0 12.0000 0 12.0000 0 12.0000 0 12.0000 0 12.0000 0 12.0000 0 11.8000 0 11.7800 0 10.0000 0 10.0000 0



# HP. 6



### Mem o on HAP Compounds Octobe r 28,199 9 Pag e 5
Tabl e of

26 7 HAP Compound s and Chemica l Propertie s (continued )

Compoun d nam e Ethylbenzene Xylen e (-p ) Xylen e Diethylene Glycol Monomethyl Ether Dichloroethy l Ethe

r Nitrosodimethylamine N Xylen e (-m

) Diethylene Glycol Monobutyl Ethe r Ethenylbenzene (styrene ) Xylen e (-o ) Tetrachloroethane (1,1,2,2 ) Bromofor m(tribromomethane ) Acryli c Aci d Ethylen e Glycol Monomethyl Ethe r Acetat e Ethylene Glycol Monopheny l Ethe r Ethylen e Glycol Monomethyl Ethe r 2 Methoxyethano l [523 ] Cumen e (isopropylbenzene ) Dimethy l Formamid

e Butan e Nitril e O^utyronitrile ) Diethylen e Glyco l Dimethyl Ethe r Ethylene Glycol Monobutyl Ethe r Acetat e Propiolacton e Ethylen e Glycol Monopropyl Ethe r Ethylen e Glycol Monoethyl Ethe r Celloso l 2, 4 Dimethylheptane Ethylen e Glycol Monoethyl Ethe r Acetat e Toluene Diamin

e (2,4 ) Diethylene Glycol Diethy l Ethe r Benzy l Chlorid

e 1, 4 Dichlorobenzene (-p ) Anilin e CA S Number 100-41- 4 106-67- 9 1330-20- 7 111-77- 3 111-44- 4 62-75- 9 108-38- 3 112-34- 5 100-42- 5 95-47- 6 79-34- 5 75-25- 2 79-10- 7 110-49- 6 122-99- 6 109-86- 4 109-86- 4 98-82- 8 68-12- 2 109-74- 0 111-96- 6 112-07- 2 57-57- 8 2807-30- 9 110-80- 5 2213-23- 2 111-15- 9 95-80- 7 629-14- 1 100-44- 7 106-46- 7 62-53- 3 Vapo r

Pressur e (m

m H g a t2 5 deg
. Q 10.0000 0 9.5000 0 8.5000 0 8.3000 0 8.2310 0 8.0000 0 8.0000 0 7.5560 0 7.3000 0 7.0000 0 6.5000 0 5.6000 0 5.2000 0 5.0660 0 5.0420 0 4.9290 0 4.9290 0 4.6000 0 4.0000 0 3.6810 0 3.4430 0 3.4170 0 3.4000 0 3.0730 0 2.7470 0 2.5460 0 1.7460 0 1.5900 0 1.2140 0 1.2100 0 1.2000 0 1.0000 0



# <S "P. 7



### Mem o on HAP Compound s Octobe r 28,199 9 Pag e 6

Tabl e o

f 26 7 HA P Compound s an d Chemica

l Propertie s (continued )

Compoun d name Bipheny l Dibromo-3-Chloropropane , 1, 2 Dimethylaniline N,N Hexachloroethane Chlorambe

n Isophoron e 1,2,3,4 Tetrahydronaphthalen e (tetralin ) Pheno l Ethylen e Glycol Monobuty l Ethe r Creso l Nitrobenzene Toxaphene Acetophenone Triethylen e Glyco l Dimethy l Ether Dimethy l Carbamoyl Chloride Cyanid e Radica l (CN ) Toluidin e (-0 ) 1 Hydrox y 2 Methyl Benzene (o-cresol ) Naphthalen e Benzotrichloride Trichlorobenzen e 1,2,

4 Hexachlorobutadiene Chloroaceti c Aci d Ethylen e Glycol Diethylene Glycol Monoethy l Ethe r Acetat e Naphthoquinone-1, 4 1 Hydrox y 4 Methylbenzene (p-cresol ) Styrene Oxid

e Dimethyl Sulfat

e Nitroso-N-Methylure aN Benzo(B)Pyridine (quinoline ) CA S Numbe r 92-52- 4 96-12- 8 57-14- 7 67-72- 1 13390 4 78-59- 1 119-64- 2 108-95- 2 111-76- 2 1319-77- 3 98-95- 3 8001-35- 2 96-86- 2 112-49- 2 79-44- 7

95-53- 4 95-48- 7 9120 3 98-07- 7 120-82- 1 87-68- 3 79-11- 8 107-21- 1 111-15- 9 130-15- 4 106-44- 5 96-09- 3 77-78- 1 684-93- 5 91-22- 5 Vapo r

Pressur e (m

m H g at2 5 de g C ) 1.0000 0 0.8000 0 0.7080 0 0.6500 0 0.5229 0 0.4390 0 0.4028 0 0.3410 0 0.3396 0 0.3000 0 0.3000 0 0.3000 0 0.2970 0 0.2775 0 0.2555 0 0.2511 0 0.2420 0 0.2400 0 0.2300 0 0.2000 0 0.1800 0 0.1500 0 - 0.1383 0 0.1260 0 0.1133 0 0.1110 0 0.1100 0 0.1094 0 0.1000 0 0.0995 1 0.0950 0



# £. V" 3P. 8



### Mem o o n HAP Compound s Octobe r 28,199 9 Pag e 7
Tabl e of

26 7 HA P Compounds an d Chemica

l Propertie s (continued )

Compoun d nam e Hexachlorocyclopentadien e Hydroxy-(2)-Propionitril e Toluene Diisocyanat

e (2,4 ) 1 Hydrox y 3 Methylbenzen e (m-cresol ) alpha-Chloro-beta-Methylnaphthalen e Dimethoxy-(3,3')-Benzidin e Ethy l Carbamat

e (urethane ) Urethane [510 ] Cyanobenzyl Alcoho l P Diethylene Glyco l Monoethy l Ethe r Cyanid e methy l Chlornaphazine ChloracetophenonE,2

- Ethylenethioure a Trichloropheno l 2,4, 5 1 Chloronaphthalene Diethy l Sulfat

e 1 Ethylnaphthalen e 2 Ethylnaphthalen e 1, 4 Dimethylnaphthalene 2, 3 Dimethylnaphthalene 1, 5 Dimethylnaphthalen e 1, 3 Dimethylnaphthalene 2, 6 Dimethylnaphthalen e Acenaphthylene 3,3 ' Dimethylbenzidine 4, 6 Dinitro-o-Creso l 2 Chloronaphthalene Dinitropheno l 2, 4 Acrylamid e Dichlorvo s Hexamethvlphosphoramid

e CA S Numbe r 77-47- 4 109-78- 4 584-84- 9 108-39- 4 86-52- 2 119-90- 4 51-79- 6 51-79- 6

110-80- 5 57-12- 5 494-03- 1 93-76- 5 96-45- 7 95-95- 4 90-13- 1 64-67- 5

571-61- 9

208-96- 8 119-93- 7 534-52- 1 91-58- 7 51-28- 5 79-06- 1 62-73- 7 680-31- 9 Vapo r

Pressure (m

m H e a t2 5 dee
. O 0.0810 0 0.0800 0 0.0800 0 0.0800 0 0.0759 8 0.0759 0 0.0738 1 0.0738 1 0.0669 0 0.0501 0 0.0499 9 0.0448 4 0.0440 0 0.0419 4 0.0399 0 0.0366 3 0.0342 0 0.0283 5 0.0283 5 0.0274 7 0.0274 7 0.0274 7 0.0274 7 0.0274 7 0.0229 5 0.0217 4 0.0180 0 0.0170 0 0.0140 0 0.0120 0 0.0120 0 0.0104 7



# 7

### Mem

o on HA P Compound s Octobe r 28,199 9 Pag e 8
Tabl e of

26 7 HAP Compounds an d Chemica

l Propertie s (continued ) P. 9

Compoun d nam e Nitrosomorpholin e 2, 4 D PC B Aroclo r

122 1 (monochlorobiphenyl ) 2 Methylnaphthalen e Trichloropheno l 2,4, 6 1 Methylnaphthalen e Dinitrotoluen e (2,4 ) Pentachloropheno l Acenaphthen e Hexachlorobenzen e Isocyan o 4 Methy l Benzen e Phenylen e Diamin e (-p ) Anisidine.o

PC B Aroclo r

123 2 (dichlorobiphenyl ) PCB' S (Aroclors ) PC B Aroclo r 101 6 (monochlorobiphenyl ) Diethy l (N,N ) Anilin e Naphthalen e Aceti c Aci d 2 Methyl , 1 Caprolacta m Naphthol.alpha

Phthali c Anhydrid e Malei c Anhydrid e Acetylaminofluorene,2

- Hexamethylen e 1,

6 Diisocyanat

e Proporu r (Baygon ) 3,5-Dibromo-4

- Hydroxybenzonitril e Catecho l Nicke l Cyanide Tetrachlorodibenzofuran(2,3,7,8 ) Hydroquinon e Calciu mCynamide Dichlorobenzonitrile,2,6

- CA S Numbe r 59-89- 2 94-75- 7 11104-28- 2 91-57- 6 88-06- 2 90-12- 0 121-14- 2 87-86- 5 83-32- 9 118-74- 1 717547 5 106-50- 3 90-04- 0 11141-16- 5 133636 3 12674-11- 2 91-66- 7

105-60- 2 90-15- 3 85-44- 9 108-31- 6 53-96- 3 822-06- 0 114-26- 1 1689-84- 5 120-80- 9 557-19- 7 51207-31- 9 123-31- 9 592-01- 9 1194-65- 6 Vapo r

Pressure (m

m H e a t2 5 dee
. C ) 0.0090 0 0.0077 1 0.0076 0 0.0073 0 0.0073 0 0.0068 7 0.0051 0 0.0050 0 0.0050 0 0.0048 0 0.0046 1 0.0046 0 0.0042 9 0.0041 0 0.0041 0 0.0040 0 0.0028 3 0.0025 2 0.0024 2 0.0022 0 0.0015 0 0.0013 4 0.0012 0 0.0011 5 0.0011 4 0.0010 5 0.0009 4 0.0007 6 0.0007 6 0.0007 0 0.0006 5 0.0005 0P.1 0



### Memo on HA P Compounds Octobe r 28,199 9 Pag e 9
Tabl e o

f 267 HAP Compound s an d Chemica

l Propertie s (continued )

Compoun d nam e

PC B Aroclor

124 8 (quatrochlorobiphen

y PC B Aroclor

124 2 (trichlorobiphenyl ) Dibenzofuran s Heptachlor Dimethy l Phthalat

e Phenanthren e 4 Nitropheno l Dibutylphthalat

e PC B Aroclor

125 4 (pentachlorobiphenyl ) Quinon e Triflurali n Capta n Diphenylhydrazin e (1,2 ) Dichlorobenzidine,3,3'

- Propan e Sultone,l,3

- PC B Aroclor

126 0 (hexachlorobiphenyl ) Carbary l (sevin ) Parathio n Gamm aBH C lindane ) Lindan e g 12345 6 hexachlorocyclohexan e Dimethylaminoazobenzene,4

- Naphthylamine,alpha

Aminobiphenyl,4

- Diethanolamin e Naphthylamine.beta

Chlordan e Nitrobiphenyl,4

- DDE,p,p'

- Aldri n Methylen e Diphenyl Diisocyanat e 2,2',6,6 ' PC

B Methoxychlor CA S Numbe r 12672-29- 6 53469-21- 9 132-64- 9 76-44- 8 131-11- 3 85-01- 8 100-02- 7 84-74- 2 11097-69- 1 106-51- 4 158209 8 133-06- 2 122-66- 7 91-94- 1 1120-71- 4 11096-82- 5 63-25- 2 56-38- 2 58-89- 9 58-89- 9 60-11- 7 134-32- 7 92-67- 1 111-42- 2 91-59- 8 57-74- 9 92-93- 3 72-55- 9 509-00- 2 101-68- 8 15968-05 5 72-43- 5 Vapo r

Pressur e (m

m H g a t2 5 deg

. C ) 0.0005 0 0.0004 0 0.0003 9 0.0003 0 0.0002 0 0.0002 0 0.0001 0 0.0001 0 0.0000 8 0.0000 8 0.0000 6 0.0000 6 0.0000 5 0.0000 5 0.0000 5 0.0000 4 0.0000 4 0.0000 4 0.0000 3 0.0000 3 0.0000 2 0.0000 2 0.0000 2 0.0000 2 0.0000 1 0.0000 1 0.0000 1 0.0000 1 0.0000 1 0.0000 1 0.0000 0 0.0000 0P.1 1



### Memo o n HA P Compound s Octobe r 28,199 9 Pag e 1 0

Tabl e o

f 267 HA P Compound s an d Chemica

l Propertie s (concluded )

Compoun d nam e

Pentachloronitrobenzen e Chlorobenzilat

e Methylene-Bis(2-Chloroaniline),4,4'

- Benzidin e Bis(2-Ethylhexyl)Phthalat

e DD T PC B Aroclo

r 126 8 Methylethylidene BisphenoL , 4,4 ' Tetrachlorodibenzo-p-Dioxin(2,3,7,8 ) Pyren e Methylenedianilin e 4, 4 Chlorine Gas CA S Number 8268 8 510-15- 6 101-14- 4 92-87- 5 117-81- 7 50-29- 3

1746-01- 6 129-00- 0 101-77- 9 7782-50- 5 Vapo r

Pressur e (m

m Hg at2 5 deg

. C ) 0.0000 0 0.0000 0 0.0000 0 0.0000 0 0.0000 0 0.0000 0 0.0000 0 0.0000 0 0.0000 0 0.0000 0 0.0000 0 0.0000 0



# /A