### CITY OF PHILADELPHIA

DEPARTME NT OF PUBLIC HEALTH

AIR M ANAGEMENT SERVICES

RACT PLAN APPROVAL

Effective Date: February 9, 2016

Expiration Date: None

Replaces Permit Nos. PA Pe rmit Numbers 51-1501 and 51 -1517 dated August 1, 2000

In accordance with provis ions of the Air Pollution Contro l Act, the Act of January 8, 1960 , P.L. 2119, as amended, and after due consideration of a Reasonably Available Control Technology (RACT) proposal received under the Pennsylvania Code, Title 25, Chapter 129.91 thru 129.95, of the rules and regulations of the Pennsylvania Department of Environmental Protection (PADEP), Air Management Serv ices (AMS) approved the RA CT proposal of the Facility below for the source(s)

listed in section 1.A. Emission Sources of the attached RACT Plan Approval.

Facility: Philadelphia Energy Soultions Refining and Marketing LLC (PES)

Owner: Philadelphia Energy Soultions Refining and Marketing LLC

Location: Girard Point Processing Area located at 3001 Penrose Ave Point Breeze Processing Area located at 3144 Passyunk Ave Mailing Address: 3144 Passyunk Ave., Philadelphia, PA 19145 SIC Code(s): 2911

Plant ID: 1501 and 1517

Facility Contact: Charles Barksdale

Phone: (215) 339-2074

Permit Contact: Charles Barksdale

Phone: (215) 339-2074

Responsible Official: Nithia Thaver and Mark Brandon

Title: General Managers



### 2/9/16
Edward Wiener, Chief of Source Registration DateRACT PLAN APPROVAL PES Page 2

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/ 1 6 The RACT plan approval is subject to the following conditions:

1. The purpose of this Plan Approval is to establish Nitr ogen Oxides (NOx)/Volatile Organic Compound (VOC) Reasonably Available Control Technology (RACT) for PES Girard Poin t Processing Area an d Point Breeze Proce ssing Area. This includes the following emission sources and control equipment:

A. Emission Sources

(1) Process Heaters: Unit 137: F1 heater (415 MMBTU/hr)

F2 heat er (155 MMBTU/hr) F3 heater (60 MMBTU/hr) All three heaters burn refinery fuel gas.

(2) Process Heater: Unit 231: B-101 heater (104.5 MMBTU/hr) fires refinery fuel gas.

(3) Process Heater: Unit 433: H-1 heater (260 MMBTU/hr) Heater fires refinery fuel gas.

(4) Process Heaters: Unit 1332 : H-400 heater (186 MMBTU/hr) H-401 heater (233 MMBTU/hr)

H-2 heater (60 MMBTU/hr)

These heaters bu rn refinery fuel gas.

(5) Process Heater: Unit 1232: B-104 heater (70 MMBTU /hr) Heater fires refinery fuel gas.

(6) Boiler House #3: Boiler #37 (495 MMBTU/hr) Boiler #39 (495 MMBTU/hr) Boiler #40 (660 MMBTU/hr) These boilers fire refinery fuel gas.

(7) Crude Unit 210: Section A HTR H101 (192.0 MMBTU/hr) Section B HTR H201 (254.0 MMBTU/hr Section C HTR 13H1 (235.4 MMBTU/hr) These heaters above fire refinery fuel gas.

(8) Hydrocracker Unit 859: HTR 1H1 (98 MMBTU/hr – installed in 2009) Unit fires refinery fuel gas.

(9) Reformer Unit 864: HTR PH1 (80 MMBTU/hr) HTR PH11 (74 MMBTU/hr) HTR PH12 (85.1 MMBTU/hr) These heaters fire refinery fuel gas.

(10) Distillate HDS Unit 865: HTR 11H1 (8 7.3 MMBTU/hr after installation of ULNBs) HTR 11H2 (64.2 MMBTU/hr) These heaters fire refinery fuel gas.

(11) Gas Oil HDS Unit 866: HTR 12H1Heater (61.2 MMBTU/hr) fires refinery fuel gasRACT PLAN APPROVAL PES Page 3

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/ 1 6 (12) Reformer Unit 860: HTR 2H3 (174.67 MMBTU/hr) Unit fires refinery fuel gas. HTR 2H5 (155 MMBTU/hr) Unit fires refinery fuel gas.

HTR 2H2 (69.78 MMBTU/hr) Unit fires refinery fuel gas. HTR 2H4 (99.44 MMBTU/hr) Unit fires refinery fuel gas.

HTR 2H7 (59 MMBTU/hr) Unit fires refinery fuel gas.

(13) 868 FCCU HTR 8H101 Unit fires refinery fuel gas

(14) 868 FCCU Catalyst Regenerator

(15) Cooling towers

(16) Fugitive leaks: valves, flanges, compressors, pumps, pipes.

(17) Unit 870: HTR H01 (97 MMBTU/hr) HTR H02 (53 MMBTU/hr These heaters fire refinery fuel gas.

(18) Unit 1232 FCCU

( 1 9 ) Girard Point Barge Loading (P130)

(20) Point Breeze Marine Barge Loading (P636)

B. Control Equipment

(1) Ultra-low NOx burner (ULNB) sy stems are installed on the following sources to control NOx emissions:

Unit 433 H-1 heater

Unit 1232 B-104 heater #3 Boiler House boilers #37, #39, and #40.

Unit 210 H201 heater

Unit 870 H01 and H02 heaters

Unit 859 1H1 heater

Unit 137 F-3 heater

Unit 1332 H-2 heater.

(2) Flue Gas Recirculation (FGR) is also installed on #3 Boiler House boilers #37, #39, and #40.

(3) S e l e c t i v e C a t a l y t i c R e d u c t i o n ( S C R ) s h a l l b e i n s t a l l e d o n U n i t 1 3 3 2 H

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r e g e n e r a t i o n s

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- d a y l i m i t i n C o n d i t i o n 4

. B

.

(4) Thermal Oxidizer shall be operated on Girard Point Barge Loading (CD-011).

2. This approval requires and authorizes:

A. The installation of Ultra Low NOx Burners on 231 B101 heater and 865 11H1 heater to comply with RACT requirements by August 19, 2015.RACT PLAN APPROVAL PES Page 4

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/ 1 6 B. PES will use combustion tuning to comply with RACT requirements for the following heaters:

Unit 137: F1 heater , F2 heater, F3 heater

Unit 1332: H-400 heater , H-401 heater , H-2 heater Crude Unit: 210A HTR H101, 210C HTR 13H1 Hydrocracker Unit 859: HTR 1H1 Reformer Unit 864: HTR PH1, HTR PH11, HTR PH12

Distillate HDS Unit 865: HTR 11H2 Reformer Unit 860: HTR 2H3, HTR 2H5, HTR 2H4, HTR 2H2, HTR 2H7

Gas Oil HDS Unit 866: HTR 12H1

Unit 868: HTR 8H101

C. All process heaters and boilers are limited to refinery fuel gas and will be capped at the heat input specified in the

table below.

Process Unit Source Heat Input Cap (MMBTU/hr)

Unit 137: F1 heater 415

F2 heater 155

Unit 433: H-1 heater 260

Unit 1332: H-400 heater 186

Unit 1232: B-104 heater 70
Boiler House #3: Boilers #37, and #39 495

Boiler #40 660

D

. PES shall monitor all fuel input to all heaters and boilers with BTU limitations on a daily basis to insure capacity

limits are not exceeded or PES shall in stall fuel limiting devices on the heater s or boilers to keep capacities below

allowable.

E. The 868 FCCU NOx emissions shall be limited to 100 ppmdv @ 0% O 2 on a 7-day rolling average 130.2 tons per rolling 365-day period. PES shall follow good combustion practices contro lling the level of excess oxygen and CO promoter in the regenerator to minimize NOx emissions from the regenerator. A NOx Continuous Emission Monitoring System (CEMS) shall be operated on the unit.

F. The 1232 FCCU shall have Selective Catalytic Reduction (SCR). NOx emissions shall not exceed 30 ppmdv @ 0% O 2 on a 7-day rolling average and 208.28 tons per rolling 365-day period. The 1232 FCCU shall be operated with good combustion practices. A NOx Continuous Emission Monitoring System (CEMS) shall be operated on the unit.

G. The 1232 FCCU shall vent to the CO Boiler when opera ting in partial-burn mode and shall follow good combustion practices.

H. PES shall utilize an equipment monito ring program in accordan ce with 40 CFR 63 subp art CC for VOC fugitive emissions from cooling towers.

I. Girard Point Barge Loading of VOC materials with a Reid Va por Pressure of 4 psi or greater shall vent to a Thermal Oxidizer with a VOC destruction efficiency of at least 98 % or control to an outlet of 20 ppmv VOC or less. The

Thermal Oxidizer shall have a contin uous temperature monitor and recorder.

J. Point Breeze Marine Barge Loading shall not load any VOC materials with a Reid Vapor Pressure of 4 psi or greater. VOC emissions from Point Breeze Marine Barge Loading sh all not exceed 25.99 tons per rolling 12-month period.

K. PES shall comply with the requirements of 25 Pa Code Section 129.58 for VOC fugitive emissions.

3. RACT Implementation ScheduleRACT PLAN APPROVAL PES Page 5

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/ 1 6 A. PES shall immediately begin the implemen tation of the measures necessary to co mply with the appr oved RACT Plan Approval.

B. Sources proposing combustion tuning to comply with RACT requirements of 25 PA Code 129.91(f) shall perform the annual combustion tuning by December 31 st of each year not to exceed 12 months between tunings.

C. Sources applicable to pres umptive RACT requirements of 25 PA Code 129.93(b)(2) shall complete the annual adjustment or tune-up by December 31 st of each year not to exceed 12 months between tunings.

D. Sources proposing installing Ultra Low NOx Burners to comply with RACT requirements of 25 PA Code 129.91(f) shall perform combustion tuni ng annually by December 31 st of each year not to exceed 12 months between tunings.

E. The 231 B101 heater shall be limited to 91 MMBTU/hr until th e burners are installed. The 865 11H1 heater shall be

limited to 72.2 MMBTU/hr until the burners are installed. The 0.03 lbs/MMBTU NOx emission limit listed below for each unit will not become applicable until the burners are installed.

4. Testing Requirements and Stack Emission Limitations

A. For units installing ULNB, PES shall conduct performance te sts for NOx. The results of these tests have been

submitted to AMS.

B. The final NOx RACT emission limits for the #3 Boiler House boilers, 137 Unit F1 heater, and Unit 210 H201 heater, have been established through the use of Department approved Continuous Emission Monitoring System (CEMS). Compliance with the limitations listed below will be on a 30-day rolling average based on hourly averages of CEM data for the Unit 137 F1 heater, on a daily average based on hourly averages of CEM data for limits noted as daily average, and on a 365-day rolling average based on hourly averages of CEM data for the other units. The limits for

the Unit 231 B101 heater and Unit 865 11H1 heater are not applicable until the Ultra Low NOx Burners are installed.

Source Limitation
Boiler House #3 – boilers #37, #39, and #40 0.040 lbs. NOx/MMBTU Boiler House #3 – boilers #37, #39, and #40 0.10 lbs. NOx/MMBTU (daily average)

137 Unit F1 heater 0.230 lbs. NOx/MMBTU

Unit 210 H201 heater 0.03 lbs. NOx/MMBTU

Unit 231 B101 heater 0.03 lbs. NOx/MMBTU

Unit 865 11H1 heater 0.03 lbs. NOx/MMBTU

Process Heater Unit 1332 H-400 heater 0.06 lbs. NOx/MMBTU

Process Heater Unit 1332 H-401 heater 0.06 lbs. NOx/MMBTU

Process Heater Unit 1332 H-400 heater 0.15 lbs. NOx/MMBTU (daily average)

Process Heater Unit 1332 H-401 heater 0.15 lbs. NOx/MMBTU (daily average)

C. Compliance with emission limits for combustion sources listed below shall be determined by quarterly stack sampling with a portable NOx analyzer. Afte r one year sampling, PES may petition AMS for semi-annual monitoring. AMS may, at any time, require th ree one-hour stack tests. Limitation (lbs.

NOx/MMBTU

Source Gas

Process Heater Unit 43 3 H-1 heater 0.035

Crude Unit 210A HTR H101 0.089

Crude Unit 210C HTR 13H1 0.104

F-2 @ 137 Unit 0.257

F-3 @ 137 Unit 0.060

B-101@ 231 Unit 0.122

H-2 @ 1332 Unit 0.040

B-104 @ 1232 Unit 0.177

1H-1 @ 859 Unit 0.020

PH-1 @ 864 Unit 0.167RACT PLAN APPROVAL PES Page 6

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/ 1 6 PH-11 @ 864 Unit 0.145

PH-12 @ 864 Unit 0.119

11H-1 @ 865 Unit 0.113

2H-3 @ 860 Unit 0.163

2H-5 @ 860 Unit 0.163

2H-2 @ 860 Unit 0.350

2H-4 @ 860 Unit 0.270

2H-7 @ 860 Unit 0.157

Unit 865 11H2 heater 0.113

Unit 866 12H1 heater 0.113

Unit 868 8H101 heater 0.113

H01 @ 870 Unit 0.035

H02 @ 870 Unit 0.035

D. All annual combustion tuning shall at a minimum meet the requirements set forth in 129.93 (b)(2) through (5).

E. At least thirty (30) days prior to a performance NOx test, PES shall inform AMS of the date and time of the scheduled

test.



### F. PES shall conduct performance tests to determine compliance with the lbs NOx/MMBTU emission limits of this plan approval for the following heaters:



### i. Within 180 days of the installation of ULNBs for the Unit 231 B101 Heater and the Unit 865 11H1 Heater.



### ii. By June 08, 2016 for the Unit 210 H101 Heater, Unit 865 11H2 Heater, Unit 866 12H1 Heater, and Unit 868

8H101 Heater.



### iii. Testing shall be conducted in accord ance with 25 Pa. Code Chapter 139

G. The Unit 210 H201 Heater shall be equipped with continuous monitors and recorders for NOx and O 2 . The continuous monitors and recorders shall meet the requirements of 25 Pa. Code Chapter 139.

H. Each heater listed below shall be limited to the following rolling 365-day heat input limits:

i. Unit 231 B101 Heater shall not exceed 856,000 MMBTU on a rolling 365-day basis.

ii. Unit 865 11H1 Heater shall not exceed 699,000 MMBTU on a rolling 365-day basis.

iii. Unit 865 11H2 Heater shall not exceed 500,000 MMBTU on a rolling 365-day basis.

iv. Unit 210 H101 Heater shall not exceed 1,643,000 MMBTU on a rolling 365-day basis.

v. Unit 210 H201A/B Heater shall not exceed 2,172,000 MMBTU on a rolling 365-day basis.

vi. Unit 866 12H1 Heater shall not exceed 456,000 MMBTU on a rolling 365-day basis.

vii. Unit 868 8H101 Heater shall not exceed 4 80,000 MMBTU on a rolling 365-day basis.

5. Recordkeeping and Reporting Requirements

A. The permittee shall maintain a file containing all the records and other data that are required to be collected to demonstrate compliance with NOx/VOC RACT requirements of 25 PA Code 129.91 - 129.94.

B. The records shall provide sufficient data and calculations to clearly demonstrate that the requirements of §129.91-

129.94 are met.

C. Data or information required to determine compliance sha ll be recorded and maintained in a time frame consistent with the averaging period of the requirement.

D. Records shall be retained for at least two years and shall be made available to the Department on request.

7. The company shall not impose conditi ons upon or otherwise restrict the De partment's access to the aforementioned source(s) and/or any associated air cleaning device(s) and sha ll allow the Department to have access at any time to said source(s) and associated air cleaning device(s) with such measuring and recording equipment, including equipmentRACT PLAN APPROVAL PES Page 7

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/ 1 6 recording visual observations, as the Department deems necessary and proper for performing its duties and for the

effective enforcement of the Air Pollution Control Act.

8. Revisions to any conditions approved as RACT by EPA w ill require resubmission as revision to the PA State Implementation Plan. The applicant shall bear the cost of public hearing and no tification required for EPA approval as stipulated in 25 PA Code §129.9(h).