P. 1



# OAR Box 1672 Prepped by Charmelle Mathews



## Document

Number: 

# ll-B- 3 

# yti
Docket Number: 

# A-98-1 3

Printed 9/30/2008 11:01:00 AM Sheet 10 of 132CZ . £____

. C__ 5 O



## TO :

FROM : MEMORANDUM

Projec t Fil e Organi c Liquid s Distributio n NESHA P ES D Projec t

No

. 96/0 5 BerndHaneke [(J^ Pacifi c Environmenta

l Services , Inc

. 

# A 9 8 1 3 11:6- 3 P. 2



## DATE : Augus t

12,199 8 —_ _ SUBJECT : Apri l 24,199 8 Sit e Visi t t o AshlandChemica

l Company , Houston , Texa s I . Purpos e The purpos e of

thi s sit e visi t wa s to tour

th e facilit y i n a n effor t to educat e EP A and contractor personne l concerning organi c liquid s distributio n operation s an dto collec t

informatio n relate dto air

emission s fromthe operations

. Thi s wor k i s i n suppor t ofth e developmen

t o f nationa l emissio n standard s fo

r hazardou s ai

r pollutant s (NESHAP

) fo r th e organi c liquid s distributio n (non-gasoline ) sourc e category
. II . Locatio n Ashlan dChemica

l Company , Divisio n o f

AshlandInc

. 890 1 OldGalvesto n Roa

d Houston , Texa s 7703 4 Apri l 24,199 8 (12:4 5 p.m . - 3:3 0 p.m. ) III . Participants Ashlan dChemica

l Compan y Scot t Colonn a- Plan

t Manage r Richar dWrigh t - Senio r Enginee r U.S

. Environmenta

l Protectio n Agency Stev e Shed

d- Project Officer, OAQPS/ESD/WCP G Researc h Triangl e Park , NC Pacifi c Environmenta

l Services

. Inc

. Bern dHanek

e - RTP , N

C Gre g LaFla

m- RTP , N

CP. 3



## Sit e Visi t Memo/Ashlan dChemica

l Co

. Augus t 12,199 8 Pag e 2
IV

. Pre-Tou r

Discussio n 

## EP A Introductio n Afte r th e participant s introducedthemselves , Stev e Shedd , EPA , bega n th e meetin g b y discussin g th e backgroun dofth e EPA' s regulatio n of hazardou s ai

r pollutan t (HAP ) emissions

. Prior to th e Clea

n Ai r Ac t Amendments of

1990 (CAAA) , HA

P regulation s were risk-base dan d alimite dnumbe

r o f regulation s wer

e completed

. The CAA

A include daspecifi c HAP lis t an d prescribe dtha

t rule s b e develope dfo

r categorie s o f

source s (industria

l types)

. Th e stringenc y o f th e Organi c Liquid s Distributio n (non-Gasoline ) NESHAP fo r existin g source s wil l b e base do n "floor " level s o f

contro l representin g the contro l achieve db y th e averag e ofth e bes t performin g 1 2 percent of source s i n thi s category
. The standard s are slate dt o b e propose di n 1999 , wit h promulgatio n o f

th e fina l rul e i n Novembe

r 2000

. Mr

. Shed dmentione dtha

t the EP A ha s prepare dan industr

y questionnair

e an ddistribute d it to trad e organization s fo

r thei r revie w an dcomment
. The questionnaire , whe n final, wil l b e sen t t o approximately 160 companie s in thi s industry

. H e als o describedth e EPA' s procedure s fo r handlin g informatio n th e compan y consider s t o b e confidentia l busines s informatio n (CBI)

. Ashlandwil l hav e a

n opportunit

y t o review th e draf

t site visi t repor t prepare db y th e EP

A projec t team , andt o commen

t o n it s accuracy an

didentif y an y CBI

. The repor

t wit h an y CB I remove d will b e made apar

t o f th e publi c recor

dfo r thi s rulemaking

. Th

e representative s o f

Ashlan d Chemica l Compan y were aske dt o identif

y whethe r an y ofth e information i n th e conversation s an dhandout s wa s confidential

. N o information durin g th e conversation s wa s note db y th e Ashlandrepresentative s t o b e confidential

. 

## Facility Processe s Ashlan dChemica

l Compan y i s adiversifiedcompan

y tha t handle s awid e variet

y o f chemical s in liqui dandsoli dstate
. Th e Housto n facilit

y warehouse s specialt

y chemical s fo

r numerou s clients , andi t

als o produce s specia

l liqui dblend s o f

chemicals

. The company describe s thi s site a s achemica l distributio n facility , anda s such use s Standar dIndustr y Classificatio n (SIC ) code 5169 , "Chemical s an dAllie dProducts , Not

Elsewher e Classified. " Approximatel

y 8 0 percent

o f Ashland' s custome

r bas e i s fo r chemicals

. The Ashlan d representative s estimate dtha t ther e ar e 6 0 t o 7 0 facilitie s nationwide tha t are simila r t o thi s facility

. Depending upo n demand , Ashlan dChemica l Co

. operate s on aflexibl e schedule

. I t usuall y operate s 5 or

7 day s pe r wee k (presentl y 5 day s a t 2 shifts) , an

d5 2 week s per

year . Th e hour s operate dpe

r da y wil l var y wit h utilizatio n an

dimmediat

e requirements

. Mr

. Scot

t Colonn aindicate dtha

t a t present , the facilit

y wa s operatin g a

t approximatel

y 2 5 percen t 

# -2 -P. 4



## Site Visi t Memo/AshlandChemica

l Co

. Augus t 12,199 8 Pag e 3 capacity

. Furthermore , Mr

. Colonn aindicate dtha t the Housto n facilit

y employ s 3 2 people

. Liquid s ente

r th e Ashlan dfacilit

y by eithe r railcar , tank

truck , o r a s pre-packaged materials

. Fro mthes e entr y points , liquid s ca

n follow numerou s routes
. Liquid s ca n either b e transferre dt o storag e vessel s fo r direc t packaging , or

they ca n b e directe dt

o blendin g tanks

. Followin g th e blending/storag e tanks , liquid s ca n then b e filled into tank

truck s or smalle r containers , suc h a s 5 gallo n container s o r totes
. Container s u p t o 55-gallo n dru msiz e ar e splas h filled

. Portabl e tote tank s ar e eithe r splas h filled o

r have abuilt-i n lanc e fo

r submergedfilling. Tote s rang e i n siz e from35 0 gallon s (filledto 33 0 gallons ) up t o 55 0 gallons

. In th e cas e o f railcars , liquid s ca

n b e transferre ddirectl y into tan k truck s (Attachment

1)

. Ashlan dca

n blen dproduct s i n multipl e modes

. A t th e facility , liquid s ca

n b e blende d either i n 55-gallo n drums , variou s size s o f totes , o r in atan k truc k itself

. N o in-lin e blendin g i s performed

. Additionally , Ashlan doperate s a4,000 an da n 8,500 gallo n blendin g tank

. Th e tank s are mounte dside-by-side i n arac k andar e attachedto ascale

. Blendin g i n thes e vessel s occur s b y weigh

t du e t o it s higher

degre e o f accuracy . Thes e tank s hav e agitator s which serv e t o homogeniz e th e blen dwithi n th e tanks

. Mr

. Wrigh t informe dth e EP A projec t tea mtha t Ashlan d als o use s nitrogen spargin g t o homogeniz e blend s within containers , bu t i s moving awa

y from thi s practic e du e to hig h level s o f emissions

. The facilit y ha s a t it s disposal 4 5 vertica

l storag e tank s (Attachmen

t 2 ) ranging i n siz e from4,00 0 t o 30,50 0 gallons

. Numerou s tank s a t the facilit y ar e equippe dwit

h interna l floatin g roof s (dependin g upo n th e liqui dstored) , whil e other s ar e onl y equippe dwit

h fixed roofs

. Th e storag e tank s ar

e divide dinto si x activ e tank farms (Tan

k farms 4A-4F , se e Attachmen t 3)

. Th e floatin g roo f

tank s ar e inspecte dvisuall y ever

y 6 month , an

dever y 5 year s th e primar

y ri msea l i s inspecte dthrough vesse l entry
. The fixed roof tank s hav e n o control s except conservatio n vents
. Thre e tan

k truc k loadin g position s a

t tw o loading rack s are availabl e a t the facility

. The rack s are locate dunde

r alarg e roof

, andhav e truc

k weighing scale s fo

r produc t filling accurac y needs

. Truck s ar

e botto mloaded , typically wit h no vapo r balanc e o r

vapor collection

. However , w e wer e tol dtha t som e customer s d o reques t

tha t their vapor s b e collecte da

t thi s location

. Ashlan down s 1 0 o f

it s ow n tank

trucks

. The facilit

y ca n als o receiv e product s b y rail , andi s currently receivin g je t

fue l antifreez e b y thi s mod

e of transportation

. Th e facilit y operate s on e solvent

drummin g area . A t thi s facility , solvent s ar

e splas h loade dinto avariet

y o f containers

. Container s tha t ar e t o b e filled ar

e place don aconveyor

belt to efficientl

y move themthroug h th e filling cycle

. Vapors emanatin g fromth e filling proces s are capture db y aventilatio n syste mwhic h route s th e vapor s throug h th e roof

. AshlandChemica

l Compan y als o operate s thre e warehouse s i n whic h i t store s bot h 

# <bP. 5



## Sit e Visi t Memo/Ashlan dChemica

l Co

. Augus t 12,199 8 Pag e 4 liquid s andbulk

solids

. In total , th e facilit

y ha s ove r 49,50 0 squar

e fee t o f storag e space . Include di n thi s storag e spac e ar e area s dedicate dfo

r liquids , solids , col dstorage , an dUnite d State s Pharmacopei a(U.S.P. ) grade chemicals

. Throughput s b y emission s categor y fo r 199 7 were : Storag e Tank s - Blendin g Tank s - Bulk Loading - Containe r Fillin g ~ 2,264,79 7 gallon s

277,64 6 gallon s 1,650,33 2 gallon s 1,001,15 3 gallons

. Mr

. Colonn ainformedth e EP A projec t tea mtha t blendin g constitute dapproximatel y 5 t o 1 0 percent ofth e busines s a

t th e Housto n facility

. Fro mth e emission s information supplie db y Mr

. Rick Wright , som

e ofth e majo

r liquid s moving throug h th e Ashlandfacilit y include (Attachmen

t 4) : Tabl e 1 . Principa

l Liquid s Handled i n 1997 Organic Liquid Methyl Ethy l Keton

e Hexan e Methanol Toluen e Xylen e Ethyl Benzene Glyco l Ethe r E B 199

7 12-Mont

h Throughpu

t (gal ) 83,05 9 337,60 5 470,95 9 212,13 4 250,26 3 179,69 3 116,56 6 

## Emission s fromAshlan

dChemica l Compan y Mr

. Wright

informe dth e EP A project tea mtha t Ashlan dChemica l Compan y ha dmad e a $150,00 0 investment

to develo p a n emission s trackin g softwar e packag e suitabl e t o it s operations

. Th e softwar

e package , calle dth e Ashlan dAir Complianc e Informatio n System (AACIS) , track s emission s monthl y by produc t

(Attachmen

t 5) , a s i s necessar

y fo r reportin g emission s to th e Texa s Natura l Resource s Conservatio n Commission (TNRCC)

.


# uP. 6



## Sit e Visi t Memo/Ashlan dChemica

l Co

. Augus t 12,199 8 Pag e 5 FromAttachment

5 , i t i s apparen

t tha t th e Housto n facilit

y i s a n are asource , wit

h an emission s breakdow n a s show n i n Tabl e 2 : Tabl e 2 . 1997 Emission s fro m Ashlan d Chemica

l Company , Houston , Texa s
Emission s Categor y Storag e Tank s Blendin g Tank s Bul k Loadin g Containe rFilling Equipmen tFugitives HAP EMISSIONS TOTAL (lb) HAP EMISSIONS TOTAL (tpy) 12-Mont h Throughpu

t(gal ) 2,264,797 277,64 6 1,650,33 2 1,001,15 3 N/ A N/A N/A 12-Mont h Emissions (lb ) 2,865.97 759.2 2 1,757.2 2 1,497.3 5 2,033.5 6 8,913.32 4.46 

## I n additio n t o this , th e facilit y emit s 8 ton s pe

r yea r (tpy ) o f volatil e organi c compound s (VOC)

. Ashlan dChemica

l Compan y use s AP-4 2 "Compilatio n o f Air Pollutio n Emissio n Factors , Chapte

r 1 2 - Storag e o f

Organi c Liquids " andth e Texa s Natura l Resource s Commission' s "Technica

l Guidanc e Packag e fo

r Chemica l Source s - Storag e Tanks " t o calculate emission s fromstorag e vessel s an dloading operations

. To calculat

e fugitiv e emissions , AshlandChemica l Compan y use s the syntheti c organi c chemica l manufacturin g industr

y (SOCMI) emission s factors

. Ashlandcalculate s tha t i t ha s approximatel

y 8 pump s an d20 0 valves

. The res t ofth e equipmen

t contributing t o fugitiv e emission s ar

e fittings, flanges , etc
. Fugitiv e Emission s Monitorin g Th e TNRC C (Attachment

6 ) prescribe s certai n procedure s fo r checking andinspectin g fugitive emissions

. T o begi n with , th e TNRC C mandate s tha t operatio n withou

t visibl e liqui d leak s o r spill s shall b e maintaine da t al l loading/unloading facilities , regardles s o f vapor pressure . Furthermore , any liqui dspil l mus t b e reporte dt o th e TNRC C andcleanedu p immediately s o a s to minimiz e air

emissions

. Accessibl e valve s nee dt o b e monitoredon aquarterly basi s b y leak-checking fo

r fugitiv e emission s usin g a

n approve dga s analyzer

. Pum p an dcompressor

seal s nee dt o b e monitore da

t leas t quarterly usin g aga s analyzer

. I f leak s ar e foun dt o b e i n exces s o f

10,00 0 ppm v the y mus t 

# 5P. 7



## Site Visi t Memo/AshlandChemica

l Co

. Augus t 12,199 8 Pag e 6 b e repaire dper

TNRC C regulation s withi n 1 5 day s afte r th e lea k ha s bee n identified

. Ashlan d personne l informe dthe EP A projec t tea mtha t leak s ar e repaire dimmediatel y following identification/detection

. Contro l Measure s A s th e Ashlandfacilit

y ha s ver y lo w emissions , not

man y contro l technologie s are utilized

. Th e mos t

prevalen t contro l technologie s utilize da t th e facilit y are : 1

. Submergedfill pipe s i n tote s 2

. Interna l floating roof

s o n vertica

l storag e tank s 3

. One scrubbe

r t o contro l corrosiv e vapor s (non-organic ) Add-o n contro l technologie s such a s carbo n adsorptio n o r therma l oxidatio n are no t

utilize da t th e Housto n facility

. Vapo r recover y o n tank truck s i s als o not

use da t th e Housto n facility

. Ashlan dChemica

l Compan y doe s us e therma

l oxidatio n to contro l vapor s a t asimila r facilit y i n California

. Wastewate

r Generation an dTreatmen

t Ashlan dChemica

l Compan y doe s no t generat e o r trea t an y organi c wastewater
. Ashlan d doe s operate ascrubbe

r which i t use s t o neutraliz e vapor s fromth e drummin g o f corrosives

. Th e scrubber effluen t i s discharge dt o apublicly ownedtreatmen t work s (POTW) sanitar

y sewer . N o permi t i s require dfo

r stormwate

r discharge , andal l stormwater i s route dinto grasse d dike s andwaterways
. A

t time s thes e ar

e checke dfo

r oil y sheens , andth e facilit

y ha s th e capabilit y fo r sampling stormwate

r usin g ga s chromatography

. Th e facilit y doe s not generate an

y semi-aqueou s liquid s (i.e. , containin g between 10-9 0 percent solids , or sludge)

. V . Plan tTou r Followin g the sit-down discussion , Mr

. Wrigh t an dMr

. Colonn atoo k

th e EP A projec t tea mon atour

ofth e facility

. The warehouses , viewedfirst, containe dbot h bulk dr y good s and liquid s store db y busines s group . Among th e good s storedher e wer e vegetabl e oil , polyester resins , catalysts , an

dpolystyrene pellets

. Drum s (5 5 gal ) containin g U.S.P

. grade isopropyl alcoho l wer

e als o observed , a s wel l a s numerou s drum s containin g flammabl e organi c liquids

. At th e en do f awarehouse , the EP

A projec t tea mwa s shown th e corrosiv e drumming are a (fo r aci dloading ) a s well a s it s associate dscrubber

. Vapors fromth e loadin g o f acid s are 

# cP. 8



## Sit e Visi t Memo/Ashlan dChemica

l Co

. Augus t 12,199 8 Pag e 7 neutralize di n th e causti c sod a(NaOH) base dscrubber

. Followin g th e corrosive s loadin g area , th e railca r unloadin g facilit

y wa s observed

. At thi s site Ashlan dwa s unloadin g je t fue l antifreeze

. Fro mth e railcar s th e antifreez e (glyco l ethe r dm) i s transferre dto tank

trucks

. The loading/unloadin g ar musedto pum

p th e liqui dfromth e rai l car , a s wel l a s it s associate dpump , wer e observed

. Nex t t o th e rai l ca

r unloadin g facilit

y wa s awarehous e tha

t containe dnumerou s size s o f totes
. Th e tote s were predominantly manufacturedo f stainles s steel andwer

e either cylindrica

l o r cubical

. Tote s mad e o f

polyviny l chloride (PVC ) wer e als o observedon th e site

. O n th e to p ofth e cubical tote s tw o opening s wer e seen , on e fo

r filling, andone fo

r venting

. Additionally , the tote s hadadischarg e valv e a t th e botto ms o a s t o completely evacuat e th e storag e space . Mr

. Colonn aexplaine dt o th e EP A projec t tea mtha t th e tote s wer

e pressur e teste dever

y 3 0 month s a s require db y th e Departmen t o f Transportatio n (DOT)

. Mr

. Colonn aan dMr

. Wrigh t the n too k th e EP A projec t tea mt o th e container/dru mfilling area . A t thi s site drum s o r

othe r liqui dcontainer s coul db e place don aconveyor bel t andfilled usin g nozzles

. Vapor s emanating fromth e fillin g operatio n wer e first collecte da

t th e filling sit

e andsubsequently vente dt o the atmospher e b y ablower

. Nex t t o th e container

filling facilit

y th e tw o blendin g tank s wer e observed

. Mounte do

n a steel structure , th e tw o tank s wer e attache dt o aweigh

t measuring scale to permi t

precis e blendin g o f

chemicals

. Mr

. Colonn adescribe dt o th e EP A project tea mho w agitators , mounte d on th e roof

s ofth e blendin g tanks , ar

e use dt o homogeniz e the blends

. Clos e t o th e blendin g vessel s tw o 500 gallo n molecula r sieve s wer

e observe dtha

t serve d t o produc e dr

y liquid s (i.e. , containin g n o water)

. The molecula r sieve s hav e adesiccant

be dtha t remove s water

fromethy l benzene an

dodorles s minera

l spirits

. Followin g th e molecula

r sieves , th e EP

A projec t tea mwa s ledto th e tank

truc k loadin g area . Th e loadin g rack s wit h tw o truck

spot s wer e seen , a s well a s the scale s tha t permi t th e liquid s t o b e filled wit

h greate r accuracy tha

n volum e meters
. The loading rack s were no t equippe dwit

h an y vapo r recover y mechanisms

. Pumps , valves , an dhose s associate dwit

h th e loading rac k

were explaine dto th e team
. The tank farm s wer

e subsequentl

y scrutinize db

y th e EP A project team
. The fixedroo f tanks , a s well a s th e interna l floating roo f

tank s wer e examine dan

ddiscussed

. Explosio n hazar d due to lightnin g strike s wit h tank s storin g methano l wa s discussed , a s well a s way s t o prevent thi s b y usin g interna

l floating roofs

. Locate dnea

r th e tan k farms was the firewate

r pond , which was briefl

y observe dand 

# nP. 9



## Site Visi t Memo/AshlandChemica

l Co

. Augus t 12,199 8 Pag e 8 discussed , a s wel l a s abuildin g wit h coldstorag e capabilities

. Empt y tan k truck s wer

e als o see n tha t wer e capabl e o f

havin g vapor

recovery . Numerou s tank truck s wer

e scrutinize danddiscussed

. Fromconversation s wit h th e Ashlandrepresentative s i t became apparent

tha t Ashlan dwa s no t

usin g th e vapor

recover y feature s o n it s tank

trucks

. VI

. Pos t

Tou r Discussio n A brie f post-tou r discussio n wa s heldin which th e EP A projec t tea mrequeste dcopie s o f th e air emission s inventor

y andTNRC C operating permit

. Photocopie s ofth e document s were mad e anddistribute dt o th e projec t team
. Following this , th e EP A projec t tea mthanke dth e Ashlan dpersonnel andth e tour wa s concluded

. VII

. Actio n Item s The EP A projec t tea minformedthe Ashlandrepresentative s tha t it woul db e preparin g a memorandumfo

r it s revie w andcomment
. N o furthe r actio n item s wer

e identifieda

t thi s time

.

%

### P.1 0



## ATTACHMEN

T 1

### Organi c Liquid s 

# Figur e 3- 1 Proces s Flo w Diagra m ••..A*:..



# o Glyco l Ethe r D M • Truc k Loadin g TR- 2

Inboun d Rai l Ca r Ethy l benzen e



## H

Inboun d Truc k TR- 1

Pre package d Material s - > Custome r

Include s tank s 2,3,80 6 6-38 . Storag e Tan k

Blend Tan k
Include s tank s S,101.and 102 . Truc k Loadin g TR- 1

Include s al I containe r f111in g actlvlties . Containe r Fillin g TOTE- I - > Custome r

- > Warehous e o r Custome r



### Inorgani c (Corrosive ) Liquid s 

# J*.^**^' ;

Inboun d Truc k TR- 3 Tank s 40-4 3 Storag e Tan k

' ' Containe r Fl11In g CORR- 1 Contr c scrub ! > l le d jer . .

b y a —T Truc k

Loadin g TR- 3

Warehous e o r Custome r

»P.1 2



## ATTACHMEN

T 2



# UP.1 3

• TANK *

WES T 1 2 3 4 5 6 1 3 1 4 1 5 1 6 1 7 1 8 1 9 2 0 2 1 2 2 2 3 2 4 EAS T 2 5 2 6 2 7 2 8 2 9 3 0 3 1 3 2 33 3 4 3 5 3 6 3 7 3 8 CAPACIT

Y GAL S

400 0 600 0

710 0 1290 0 2130 0 2130 0 1640 0 2130 0

- 2010 0 2010 0 3050 0 3050 0 3050 0 3050 0 • 3050 0 3050 0

1200 0 1200 0 1200 0 1200 0 1200 0 1200 0 1500 0 1500 0 1500 0 1500 0 1500 0 1500 0 1500 0 1500 0 PRODUC T

' GLYCO L ETHE R D B DEiSE L • BLEN D TAN K METHYLEN E CHLORID E METHY L ETHY L KETON E n-BUTY L ACETAT E HEXAN E METHANO L ISOPROPANO L -' EMPT Y TOLUEN E XYLEN E ACETON E ETHYLBENZEN E OM S GU N CLEANE R

H I SO L 1 0 GLYCO L ETHE R P M METHY L tvAMY L KETON E METHY L ISOBUTY L KETON E TEXANO L ESTE R ALCOHO L DIOCTY L PHTHALATE(DOP ) ETHYLEN E GLYCO L GLYCO L ETHE R E B MINERA L SPIRIT S 6 6 REGULA R MINERA L SPIRIT S SOLVEN T 140-6 6 VM& P NAPTH A n-BUTANO L KWI KDRI6 6 

# I 75 % GAL S

300 0 450 0 0 532 5 987 5 1597 5 1597 5 1455 0 1597 5 1507 5 1507 5 2287 5 2287 5 2287 5 2287 5 •2287 5 32287 5

900 0 900 0 900 0 900 0 900 0 900 0 1125 0 1125 0 1125 0 1125 0 1125 0 11250 - 1125 0 1'25 0

# J75 %

FEE T

10*5 " 11*11-1/2 "

0 16*5-1/2 " 22*6 " 2_T8 " 22*5-1/2 " 221 T 23*3-1/4 " 23*3-1/4 " 2T-1/4 " 27-1/4 " 27-1/4 " 27-1/4 " 27-1/4 " 27-V4 " AoSEMON T O R STRAP ?

QUANTIT Y



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# -3<fc>
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. •

## ATTACHMENT S



# 1 3o



## § o 0 0 C M



### 9

i n D O X KE Y ARE A PLA N SCALE . NON E 

### nrNrRA i mTC PROPERT

Y LINE S HAV E BEE N TRANSFERRE D FRO I TH E ORIGINA L PLO T PLA N AN D HAV E BEE N CONFIRME D AGAINS T TH C PROPERT

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### PERMI T ADMENMEN T R-54 7 Woodward-Clyd e Consultant s Engineer-n g ti

science s applie d t o th e eart h it

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### ASHLAN D CHEMICA L COMPAN Y HOUSTO N FACILIT

Y SOLE : NOTE D UAO E BY:PR .

CHECKE D BY . 0 A IE : 01/23/9 6 DATE : FIL E N a 95T22 8 

### HOUSTO N TERMINA L PLO T PLA N FIGUR E 2 - 2 

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## ATTACHMEN

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## -6" ^ Hazardou s Ai r Pollutan t Throughpu t Dat a Ashlan d Chemica

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X Facility Calenda r Yea r 199 7
Produc t Cod e 300144 0 300145 0 300165 0 300195 0 300242 0 300243 0 300250 0 300293 0 300299 0 302065 6 306000 0 307000 0 307100 0 311025 0 321000 0 322000 0 331000 0 335300 0 336500 0 337000 0 337000 8 340590 0 340594 2 354000 0 359000 0 360050 0 362000 0 363920 0 363922 0 375200 0 375220 0 375300 0 393114 0 396849 6 396852 0 397000 0 702084 0 702100 0 703040 0 703055 0 703080 0 713801 1 735000 0 743000 0 744036 3 Produc t Descriptio n

H i So l 1 0 H i So l 1 5 Toluen e Xylen e - mixe d isomer

s rvHexan e Hexaso l Lacofen e VM& P Naphth a Hig h Initia l VM& P Naphth a ARDRIL295 7 Glyco l Ethe r D B Glyco l Ethe r E B Glyco l Ethe r E B Acetat e Glyco l Ethe r DE-L G Dibuty l Phthalat e Diethanolamin e 99 % Diocty l Phthalat e Ethylbenzen e 99 % Ethylen e Dichlorid e Ethylen e Glyco l Ethylen e Glyco l Polyeste r Grad e Glyco l Ethe r E P Glyco l Ethe r D M Fue l Additiv e Methy l Ethy l Keton e Methylen e Chlorid e Glyco l Ethe r D M Fue l Additiv e Methy l Isobuty l Keton e Muriati c Ad d 2 0 degre e Baum e Muriati c Aci d 2 2 degre e Baum e Perchloroethylen e Perchkxoethvten e Reformin g Grad e Perchtoroethylen e Ruorocarbo n Grad e Styren e Monome r 1.1.1-Trichloroethan e Dioxan e Fre e 1,1.1-Trichloroethan e Trtchkxoethylen e AmbitnUC N Antifreez e Ethano l Spe c In d Anv d 408 2 Ethano l Spe c In d Anyd 413 5 Ethano l Spe c In d 19 0 Proo f 408 5 Ethano l SD A 23H19 0 Proo f Methano l Ethano l Proprietar

y 19 0 Proo

f 322 4 Housto n Gu n Cleane r % HA P (b y weight ) 10 1 0 10 0 10 0 10 0 3 5 7 10. 9 1 0 2 10 0 10 0 10 0 10 0 10 0 9 9 10 0 9 9 10 0 10 0 10 0 10 0 10 0 10 0 10 0 10 0 10 0 10 0 10 0 10 0 10 0 10 0 10 0 10 0 10 0 10 0 9 5 9 4 5. 2 9. 8 5. 4 1. 4 10 0 5. 5 59. 4 Blen d Usag e

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. 1.04 5 54 0 4.21 2 64 8 14.68 5 169.83 0 15.33 6 93 5 Portabl e Tan k

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269,95 0 18,34 5 249,66 3 250,26 9 337.61 0 7,59 3 7,82 9 21.85 2 27,07 3 5,05 7 20.81 8 130,14 4

. 5,41 5 9,41 9 9,10 9 21,64 4 179,69 9 1,09 8 39,69 3 4.96 7 7.71 3 68.02 1 92,01 4 42.37 3 266.66 2 22.91 1 76.24 3 45.14 0 7.83 5 1.50 8 3.02 9 67.85 7 3.12 2 3.12 9 10.46 9 1.19 7 1.09 9 54 4 4.74 5 70 4 14.97 7 478.54 3 15.64 2

- Comment s Xylene . Cumen e Naphthalen e

n-Hexan e Toluen e Xylene . Ethylbenzen e Xylene . Ethylbenzen e Diethanolamin e Diethylen e Glyco l Monobuty l Ethe r Ethylen e Glyco l Monobuty l Ethe r Ethylen e Glyco l Monobuty l Ethe r Acetat e Diethylen e Glyco l Monoetny l Ethe r
Di-.2-ethvlhexvl . Phthalat e

Ethylen e Glyco l Monopropy l Ethe r Diethylen e Glyco l Monomethy l Ethe r Diethylen e Glyco l Monomethy l Ethe r Hydrochlori c Ad d Hydrochlori c Ad d

Ethylen e Glyco l Ethylen e Glyco l Methanol , Methy l Isobuty l Keton e Methanol . Methy l Isobuty l Keton e Methanol . Methy l Isobuty l Keton e Methy l Isobuty l Ketone . Methano l Methanol . Methy l Isobuty l Keton e Toluene . Methy l Ethy l Ketone . Methanol , Xylen e Note : Ai l throughpu t dat a i s I n gallons .

Page lG3R591- 1 ASHLAN D CHEMICA L COMPAN Y DATE :

PAG E 1 THROUGH-PLAN T USAG E & PURCHASE S FO R WAREHOUS E TIME : WHSE : 2 8 Ol d Galvesto n Roa d Warehous e FRO M 01/01/9 7 T O 12/31/9 7 Thi s Repor t I s T o B e Give n T o Th e PLAN T MANAGER . Al l Quantitie s Ar e I n GALLON S Unles s Specifie d T o Th e Righ t O f Th e Colum n BUL K SHI P QUANTITY .
PRODUC T DESCRIPTIO N 200196 0 ADVASO L 15 0 200800 0 CYCLOHEXAN E 202460 0 PANASO L AN-2 K 220005 8 A

800 0 D 220007 8 A

800 0 E 220601 0 ALKOT E RETARDE R 220633 0 V T 4 BLEN D 220706 5 CS D R 7 K 6 9 220946 7 BROC H STEIN S H G 221580 0 BLEN D 736 2 222708 1 B 866 9

_ ^ 223993 6 PIPIN G TEC H THINNE R 224064 7 C B 19 1 22406 4 9 SEMA C SOLVEN T A 1 226552 2 LACQUE R THINNE R G 226934 8 C B 11 6 228695 9 TYP E WAS H M (REV ) 228696 6 GYR O 1 FORMUL A W T 228700 5 QUALIT Y PO T WAS H 4/14/9 8 6:2 4 A M

BLEN D

LACQUE R T H BLEN D

QUANTIT Y

2 1 0 55 0 99 3 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 FIL L

DRUM S 4,40 0 9,51 5 6,43 5 1,54 0 33 0 0 12,76 0 0 1,70 5 11 0 1,43 0 77 0 49 5 2,80 5 4,67 5 0 5 5 0 5 5 QUANTIT Y

TOTE S SMAL L 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 C C

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 PURCHAS E QUANTIT Y 4 9 8 42 7 71 1 95 4 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 BUL K SHI P QUANTIT Y

0 0 0 0 0 2,24 1 0 2,00 0 0 3 0 0 0 0 0 1,25 5 0 2,97 0 0

# - 4 G3R591- 1

PAG E 2 WHSE : 2 8

PRODUC T 228701 1 229922 9 229923 0 230816 2 230897 9 231128 1 231131 1 231170 9 231171 9 231347 7 231735 2 231749 2 231769 2 231831 2 231921 2 231998 2 232078 4 232159 3 232465 2 235754 4 ASHLAN D CHEMICA L COMPAN Y THROUGH-PLAN T USAG E & PURCHASE S FO R WAREHOUS E Ol d Galvesto n Roa d Warehous e FRO M 01/01/9 7 T O 12/31/9 7

DESCRIPTIO N BH T TOLUEN E BLEN D ACM E WAS H 10 4 A CS D PREMIU M

10 3 THINNE R 2805 6 R 7 K 5 8 S W RETARDE R G SEMA C SOLVEN T A SUTTO N BLEN D 2 SUTTO N BLEN D 1 ACROTHAN E REDUCE R 25 5 C 15 7 DT L 1 0 B EXPOX Y REDUCE R AMSC O SOL V

A HERMIE S BLEN D 561 0 THINNE R 2730 9 (REV ) GOOSENEC K JUL Y A E 10 0 BLANKE T & ROLLE R W A GYRO S 1 FORMUL A S W 1 LACQUE R THINNE R (REV ) 6-75-49 8 BLEN D QUANTIT Y

0 0 0 0 0 0 0 0 0 0 0 0 2,02 0 0 0 0 0 0 0 0 DRUM S

1.32 0 0 0 33 0 16 5 1,10 0 33 0 0 0 0 0 0 0 5 5 22 0 0 0 93 5 3,30 0 2,20 0 FIL L QUANTIT Y

TOTE S 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 * 0 0 0 SMAL L C C

0 90 0 0 0 5,12 5 0 0 0 0 2 0 26 0 61 0 0 0 0 0 0 0 2,42 5 0 DATE : 4/14/9 8

TIME : 6:2 4 A M

PURCHAS E BUL K SHI P QUANTIT Y QUANTIT Y

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0

8,50 8 53 6 0 0 0 0 99 0 1,00 3 0 0 0 2,02 4 0 0 5,96 0 99 7 4.73 0 0 0G3R591- 1 PAG E 3 WHSE : 2 8
PRODUC T 236409 0 237170 5 237603 7 248800 0 252400 0 259205 0 269951 0 270339 7 270399 4 270399 9 270400 8 270400 9 270401 2

^

_270402 6 — £ > 270403 1 270403 9 270435 3 270451 7 270481 4 270535 7 ASHLAN D CHEMICA L COMPANY THROUGH-PLAN T USAG E & PURCHASE S FO R WAREHOUS E DATE : 4/14/9 8 TIME : 6:2 4 A M Ol d Galvesto n Roa d Warehous e DESCRIPTIO N SPRA Y GU NCLEANE R 100 7 BLEN D 3 3 THINNE R 1 KEROSEN E MINERA L SEA L OI L RETAR D SOLVEN T 2 WHIT E MINERA L OI L 7 0 TECHNICA L PS C 128 7 SUBSTITUT E 52 9 RE V SOLVEN T 2025 3 A AMSC O SOL V

A(REV ) CS D T T T 30 6 E TYP E I I (REV ) NAGE L ROLLE R WAS H (REV ) GYR O 5 REVISE D W T PS C 129 9 ETHY L KEROSEN E FOSTE R M S BLEN D 60 2 ENAME L REDUCE R REVISE D MINERA L SPIRIT S 6 6 MAAC O B B 289 5 FRO M 01/01/9 7 T O 12/31/9 7 BLEN D QUANTIT Y

0 0 0 6,95 3 0 22,06 9 7 7 0 0 0 0 0 0 0 0 0 0 0 0 99 0 FIL L

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4 ,02 5 0 0 ,36 0 0 99 0 0 27 5 ,32 0 0 0 0 22 0 0 0 0 0 5 5 0 0 QUANTIT Y

TOTE S 0 0 0 0 0 0 0 3,03 2 96 1 0 0 0 0 0 65 1 0 0 0 0 0 SMAL L C C

0 50 5 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 PURCHAS E QUANTIT Y

1 0 3 1 3 0 0 0 64 5 14 0 93 2 0 0 0 0 0 0 0 0 0 0 0 0 0 0 BUL K SHI P QUANTIT Y

0 3,88 2 29 9 74 9 50 0 8 0 0 0 29,97 8 2,00 3 99 1 0 2,97 0 0 20,19 6 1,04 0 0 15,03 7 0G3R591- 1 ASHLAN D CHEMICA L COMPAN Y PAG E 4 THROUGH-PLAN T USAG E & PURCHASE S FO R WAREHOUS E WHSE : 2 8 Ol d Galvesto n Roa d Warehous e



# O PRODUC T DESCRIPTIO N 270608 5 GOOSENEC K JUL Y B 270621 6 60 1 ENAME L REDUCE R REVISE D 270720 5 AUTOWAS H 2500 . SE E P C 2 7 270764 6 C G 4 4 SE E P C 27 0 270811 4 DT R 60 0 (015 ) 270856 6 M S RUL E 6 6 S 10 0 278435 9 BLEN D 771 7 278818 0 CC C 10 0 SOLVEN T 278819 7 LOCK O SPECIA L BLEN D B 1 RE V ( 0 285201 1 INSC O CLEANE R SOLVEN T S 285704 5 US S 2 5 B 285809 8 JA

X BLEN D 10 3 285839 1 LOCK O SPECIA L BLEN D B 1 RE V 287016 7 SUPE R VM& P NAPHTH A (028 ) 288310 0 SOLVEN T BLEN D 9 288325 4 NAGE L ROLLE R WAS H 289139 2 SOLVEN T 2025 3 289790 2 WA

X & GREAS E REMOVE R 3 3 0 A 289814 2 THINNE R 2112 1 A 289953 3 PRINTE R SERVIC E T 20REVISEDSS E FRO M 01/01/9 7 T O 12/31/9 7

FIL L QUANTIT Y TOTE S 0 0 0 0 0 0 0 0

' 0 0 0 0 0 0 0 0 0 0 0 0 BLEN D QUANTIT Y

0 0 6,69 8 38 5 0 0 0 61 5 0 2,62 7 0 0 77 0 0 0 27 5 24,35 8 0 10 6 1,65 3 DRUM S

0 38 5 0 0 0 0 0 0 88 0 0 16 5 0 0 77 0 0 0 0 53 4 0 0 SMAL L C C 0 0 0 0 18 0 0 0 14 0 0 0 0 0 0 0 0 0 0 0 0 0 DATE : 4/14/9 8

TIME : 6:2 4 AM

PURCHAS E BUL K SHI P QUANTIT Y QUANTIT Y

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 3.77 S

0 0 0 0 2,00 6 10,85 3 0 0 2,62 7 1 4,90 3 0 0 84,95 8 0 24,35 8 0 0 0FRO M 01/01/9 7 T O 12/31/9 7

^ G3R591- 1 ASHLAND CHEMICA L COMPAN

Y PAG E 5 THROUGH-PLAN T USAG E & PURCHASE S FOR WAREHOUS E WHSE : 2 8 Ol d Galvesto n Road Warehous e
PRODUC T DESCRIPTION 291367 0 ST X 10 4 292271 0 ST X 15 0 292769 6 T T T 30 6 C A TYP E I I 300106 1 SUR E SO L 20 2 300144 0 H I SO L 1 0 300145 0 H I SO L 1 5 300185 0 TOLUEN E 300195 0 XYLEN E 300215 5 CONOSO L C-20 0 300240 0 HEPTAN E 300242 0 HEXAN E 300243 0 HEXASO L 300248 5 KWI K DR I 6 6 300249 0 KWI K DR I NONEXEMP T 300250 0 LACOLEN E 300253 0 MINERAL SPIRIT S 300255 0 MINERAL SPIRIT S 6 6 300255 3 MINERAL SPIRIT S 20 0 H T 300255 5 MINERAL SPIRIT S 4 % 300260 0 MINERAL SPIRIT S DATE : 4/14/9 8 TIME : 6:2 4 A

M

AROMATI C

SOLVEN T

NONEXEMP T

H T AROMATIC S ODORLES S BLEN D

QUANTIT Y

0 0 0 0 14,04 9 1,78 5 53,18 7 47,12 0 0 42 5 77,40 6 0 2,91 9 21 6 . 8,97 0 20,25 8 56 4 9,02 1 1,91 4 35,91 5 FIL L

DRUM S 0 0 0 2,19 6 43,58 0 12,21 0 41,88 7 23,60 8 5,72 0 8,08 8 12,14 9 0 8,13 5 0 3,21 4 18,02 7 49,96 6 4,88 8 0 28,04 5 QUANTIT Y

TOTE S

6

1 2 3

3 0 0 0 0 91 5 0 55 9 73 5 0 0 0 0 0 0 07 7 0 94 3 0 0 64 1 SMAL L C C

0 0 0 0 18 8 49 0 1 9 3,75 3 0 1 4 0 0 0 0 0 3,54 6 0 0 0 2 5 PURCHAS E QUANTIT Y

0 0 0 2,23 5 269,95 0 18,34 5 249,66 3 250,26 9 6,72 6 28,91 9 337,61 0 7,59 3 18,64 2 0 7,82 9 90,33 6 77,19 6 15,92 3 3,50 0 451,10 0 BUL K SHI P

QUANTIT Y 2,98 5 51 3 2,18 0 0 200,34 6 8,22 7 160,15 1 175,65 2 92 5 21,82 7 262,92 1 2,73 9 21,63 4 0 0 62,30 8 34,04 1 5,79 6 0 407,31 4^ ^ G3R591- 1 PAGE 6 WHSE : 2 8
PRODUC T 300275 5 300282 0 300283- 0 300289 0 300293 0 300294 5 300299 0 300354 3 301000 0 301000 1 301235 1 301306 9 301307 0 301308 0 301308 8 301573 2 301871 2 302000 0 302065 6 302066 6 ASHLAN D CHEMICAL COMPAN

Y THROUGH-PLANT USAG E & PURCHASE S FO R WAREHOUS E DATE : 4/14/9 8 TIME : 6:2 4 A

M Ol d Galvesto n Roa d Warehous e DESCRIPTIO

N MINERA L SPIRIT S SOLVEN T 14 0 SOLVEN T 1 4 0-6 6 SOLVEN T 1 4 0 3 % VM& P NAPHTH

A H I VM& P NAPHTH

A W 6 6 VM& P NAPHTH

A IBE X 11 5 ACETON E ACETON E AC S AMBITRO L 40-6 0 LIF E GUARD 1600- B ACETI C ACI D 84 % ACETI C ACID 99.5 % I P G T A 41 5 BLEND A ALKAMID E WRS-16 6 ME A 85 % LO W GRAVIT Y AMYL ACETAT E PRIMAR Y ARDRI L 295 7 ARTRA D 119 4 FRO M 01/01/9 7 T O 12/31/9 7

13 5 E C (S H NONEXEMP T

AROMATIC S INITIA L N BLEN D

QUANTIT Y 9,85 6 0 13 3 20,70 2 0 34,23 0 15,46 2 0 36,18 7 0 0 0 0 0 0 3,03 2 0 0 5,05 7 0 FIL L

DRUM S 5,01 6 28,11 8 4,45 8 60,63 2 9,25 8 19,25 3 18,03 7 0 126,77 1 1,35 4 0 1,05 2 25,17 3 5,64 6 0 0 0 18,21 6 0 32 9 QUANTIT Y

TOTE S 1

1 9

1 1 05 8 0 0 0 0 0 0 91 0 29 8 0 0 0 0 0 0 0 02 1 0 0 0 SMAL L C C

0 0 0 0 0 7 5 5 0 0 11 5 0 0 0 0 0 0 0 0 0 0 0 PURCHAS E QUANTIT Y 8,54 8 29,31 5 3,53 3 153,96 3 21,85 2 92,69 4 27,07 3 0 256,57 0 1,46 2 0 0 24,04 0 5,70 9 0 0 0 18,68 0 2,89 1 0 BUL K SHI P QUANTIT Y

0 0 4,97 6 69,19 0 12,28 2 28,00 2 5,78 7 71,87 9 82,72 4 0 2,99 3 43,39 5 0 O 37,10 8 0 70 5 0 0 0G3R591- 1 PAG E 7 WHSE : 2 8
PRODUC T 302066 7 302486 3 306000 0 306032 0 307000 0 307100 0 309013 0 309031 4 309049 5 309050 1 309050 9 309051 0 309052 8 309101 0 309586 2 309597 3 311025 0 312001 0 312002 0 313501 0 ASHLAN D CHEMICA

L COMPAN

Y THROUGH-PLAN T USAG E & PURCHASE S FO R WAREHOUS E DATE : 4/14/9 8 TIME : 6:2 4 A

M Ol d Galvesto n Roa d Warehous e DESCRIPTIO

N ARZOLINE 21 5 BENZY L ALCOHO L TEC H GRAD E GLYCO L ETHER D B BUTYL BENZYL PHTHALAT E GLYCO L ETHE

R E B GLYCO L ETHE

R E B ACETAT E BUTYROLACTONE WE T SO L A IBEX XTR

A ESW REVISE D LIF E GUAR

D 170 0 FOSTE R MINERA

L SPIRIT S 2 LUB E B X

M P C 100 0 CITRI C ACI D LI Q 40 % USE P C 392 - CALAMID E CW-10 0 BUTYLATE D HYDROX

Y TOLUEN E F GLYCO L ETHER DE-L G POLYETHYLEN

E GLYCO L 20 0 POLYETHYLEN

E GLYCO L 40 0 CASTO R OI L IND . GRAD E # 1 FRO M 01/01/9 7 T O 12/31/9 7 BLEN D QUANTIT Y 7,23 0 0 0 0 96 0 6 3 0 0 0 0 0 0 0 0 0 3,23 1 0 0 0 0 FIL L

DRUM S 0 5,10 8 13,96 4 12,63 4 41,16 8 11 0 2,86 0 0 80,00 0 16 5 0 0 5 4 0 5 4 0 5,23 1 0 0 0 QUANTIT Y

TOTE S

1 0

17 ,

2 0 0 29 4 0 48 1 0 0 0 0 0 0 0 0 0 47 3 0 0 0 0 0 SMAL L C C

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.0 8 0 5 PURCHAS E QUANTIT Y 6 5 2 0 1 4 13 0

2

2



## s 85 0 18 3 81 8 89 8 14 4 0 93 0 0 0 0 0 0 0 94 7 54 5 0 41 5 0 0 0 BUL K SHI P QUANTIT Y

0 6,89 2 1,62 0 9,41 4 64,85 3 0 2 4 54,22 2 0 0 9,00 6 17,51 0 0 0 4 3 0 5 0 3 6 0G3R591- 1 ASHLAND CHEMICA L COMPAN

Y PAG E 8 THROUGH-PLAN T USAG E & PURCHASE S FO R WAREHOUS E WHSE : 2 8 Ol d Galvesto n Roa d Warehous e DATE : 4/14/9 8 TIME : 6:2 4 A

M FRO M 01/01/9 7 T O 12/31/9 7
PRODUC T DESCRIPTIO N 314000 0 CAUSTI C POTAS H 45 % LIQUI D 314982 4 IBEX 858 8 (REVISED ) 315000 0 CAUSTI C SOD A LIQUI D 50 % 315005 0 CAUSTI C SOD A LIQUI D 50 % RAYO

N 319718 3 11-307 1 P V FAS T YELLO

W HG 320000 0 CYCLOHEXANON E 320120 0 CYCLOHEXYLAMIN E TEC H 320187 0 D-LIMONEN E 321000 0 DIBUTY L PHTHALAT E 322000 0 DIETHANOLAMIN E 99 % 322800 0 DIBASI C ESTE R 1 325500 0 DIACETON E ALCOHO L 326070 0 DIETHY L ETHANOLAMINE 327000 0 DIETHYLEN E GLYCO L 327530 0 DIISOPROPANOLAMIN E 99 % 327532 0 DIISOPROPANOLAMIN E 85 % LO W F 329800 0 DIPROPYLEN E GLYCO L FRAGRANC E 330051 0 IP

A 55-57 % 330058 9 DRAKEO

L 3 5 TEC

H 330059 0 DRAKEO

L 5 TEC

H BLEN D QUANTIT Y

0 0 0 0 0 32 8 0 36,97 6 5 0 0 30 0 0 0 0 0 0 0 0 0 FIL L

DRUM S 29,87 6 0 27,94 5 65,46 0 0 45,20 4 4,06 2 33,58 2 9,46 7 94 5 14,55 0 38 6 6,46 6 23,45 8 2,97 0 0 10,40 7 6,32 8 10,15 0 1,48 6 QUANTIT Y

TOTE S 5,57 7 0 1,20 3 7,94 4 0 0 20,92 5 0 0 7,10 8 1,04 2 0 0 0 0 0 0 0 0 0 SMAL L C C

0 0 0 0 0 2 4 0 2 5 0 0 4 4 0 0 0 0 0 0 0 0 PURCHAS E QUANTIT Y 36,71 9 0 38,64 0 65,66 8 2 52,10 5 23,96 6 50,27 7 9,41 9 9,10 9 15,91 7 50 1 6,64 6 24,07 0 3,04 7 1,25 9 10,61 0 0 10,48 5 1,53 0 BUL K SHI P

QUANTIT Y

0 39,56 5 32,33 1 58 6 0 10,21 3 0 4,01 4 0 4 9 1 0 0 6 0 1,25 9 0 3 6 0 1G3R591- 1

PAG E 9 WHSE : 2 8



# N Vr\ PRODUC T 330090 0 331000 0 331106 1 331120 2 332048 9 332049 1 332105 0 333000 0 333100 0 334500 0 335300 0 336500 0 337000 0 337000 8 337500 0 338000 0 338116 0 338608 4 340021 9 340400 0 FRO M 01/01/9 7 T O 12/31/9 7 ASHLAN D CHEMICAL COMPAN

Y THROUGH-PLAN T USAG E & PURCHASE S FO R WAREHOUS E Ol d Galvesto n Roa d Warehous e
DESCRIPTIO

N DODECYLBBNZENE DIOCTYL PHTHALAT E D C SILICONE 200F L DC ANTIFOA

M H-1 0 EMPHO S PS-22 0 EMPHO S PS-40 0 EPA L 141 8 ETHYL ACETAT E 85-88 % ETHYL ACETAT E 99.5 % ETHY L ACETAT E 99 % ETHYLBENZENE 99 % ETHYLENE DICHLORID E ETHYLENE GLYCO L ETHYLEN E GLYCO L POLY I ESTE R SOLVENT EE P ETHYLHEXANOL- 2 EXXAT E 100 0 FERRI C SULFAT E S0 % IBE X XTR A ES W GLYCERINE 99.5 % TEC H DATE : 4/14/9 8 TIME : 6:2 4 A

M

SULFONI C

100 0 VI S EMULSIO N

URETHAN E

STE R GRA D

SOLUTIO N BLEN D

QUANTIT Y 1,21 6 0 5 5 51 8 1,91 5 2,06 1 0 1,21 2 52 5 0 0 0 1 0 1,34 5 0 0 0 0 0 FIL L

DRUM S 18,90 6 9,26 3 0 0 0 0 16,27 1 1,52 5 7,97 6 5 4 8,22 0 97 7 25,83 8 4,30 6 5,33 4 3,65 1 0 0 28,61 7 0 QUANTIT Y

TOTE S SMAL L 1 0

1 5

2 59 5 0 0 0 0 0 0 0 71 2 0 0 0 28 2 0 0 0 0 0 0 29 9 C C

0 0 0 0 0 0 0 0 0 0 0 0 4 0 0 0 0 0 0 0 PURCHAS E QUANTIT Y 25,60 9 21,64 4 0 0 0 0 16,36 8 1,71 1 17,50 6 0 179,69 9 1,09 8 39,69 3 4,96 7 6,44 7 3,70 0 0 32 0 0 0 BUL K SHI P QUANTIT Y S 8 12,27 2 0 0 1 4 51 0 0 26 7 1 161,12 5 3 3 11,48 5 0 1,21 8 5 7 3 3 0 2 0 0G3R591- 1 PAG E 1 0 WHSE : 2 8
PRODUC T 340509 2 340510 4 340511 0 340512 0 340590 0 340591 4 340594 2 340595 0 345500 0 345508 0 345540 5 345568 0 345850 0 K } 345970 0 O * 346000 0 346171 2 347301 7 347304 9 347309 0 347415 5 ASHLAN D CHEMICA

L COMPAN

Y THROUGH-PLAN T USAG E & PURCHASE S FO R WAREHOUS E DATE : 4/14/9 8 TIME : 6:2 4 A

M Ol d Galvesto n Roa d Warehous e DESCRIPTIO

N GLYCERINE , NATURA

L 99.7 % US P GLYCERINE , SYNTHETI C 99.7 % TE C GLYCERINE , SYNTHETI C 99.7 % US P GLYCERINE , NATURA

L 99.5 % US P GLYCO L ETHER;E P GLYCO L ETHE

R DPNP GLYCO L ETHE R D

M FUE L ADDITIV E GLYCO L ETHE

R TB CHELATIN

G LIQUI D 10 0 CHELATIN

G LIQUI D 8 0 CHELATIN

G LIQUI D 12 0 HEPTY L ACETAT E HEXANOL , NORMA

L HEXY L ACETAT E MIXE D ISOMER S HEXYLEN E GLYCO L ETHYL S BLEN

D DC HYDROGE N

PEROXID E 35 % TEC H HYSTREN E 367 5 HYDROGE N

PEROXID E 50 % 500 # HOGWAS H U S (T ) FRO M 01/01/9 7 TO 12/31/9 7
QUANTIT Y

0 0 0 0 2,25 3 78 1 0 0 0 0 0 9 0 1 6 0 0 0 0 0 0 DRUM S

0 0 21 6 0 5,44 1 0 56,15 8 76,57 2 9,37 8 3,90 8 3,70 5 0 0 0 21,40 5 44 0 0 0 0 0 UANTIT .

TOTE S 2,31 0 0 62 4 1,19 4 0 0 0 0 4,38 0 0 0 0 0 0 2,79 7 0 0 0 0 0 SMAL L C C

1 0 0 0 0 4 9 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 PURCHAS E QUANTIT Y

0 0 54 1 0 7,71 3 0 68,02 1 76,79 6 14,23 4 3,95 2 3,66 8 0 0 0 25,28 5 0 1,01 3 0 50 0 0 BUL K SHI P QUANTIT Y

4

2 2

3 0 2 3 0 0 ,20 8 0 ,97 6 0 ,47 2 0 0 0 0 0 1 4 0 0 5 1 0 9 9

# v i G3R591- 1 PAGE 1 1 WHSE : 2 8
PRODUC T 347940 5 347941 0 347948 0 347950 0 347960 0 347970 0 349000 0 349500 0 349900 0 350000 0 350471 2 350700 0 351475 8 352250 5 353000 0 354000 0 358710 0 359000 0 360050 0 362000 0 FRO M 01/01/9 7 T O 12/31/9 7 ASHLAND CHEMICAL COMPAN Y THROUGH-PLAN T USAG E & PURCHASE S FO R WAREHOUS E Ol d Galvesto n Roa d Warehous e
DESCRIPTIO

N IGEPA L CA-62 0 IGEPA L CA-63 0 IGEPA L RC-52 0 IGEPA L CO-43 0 IGEPA L CO-53 0 IGEPA L CO-63 0 ISOBUTYL ACETAT E ISOBUTANO L ISOBUTYL ISOBUTYRAT E ISOPROPYL ACETAT E ISOPROPYL ALCOHO L 9 2 % ISOPROPANO L 99 % LEXEI N X-25 0 METHY L NORMA

L AMY L KETON

E MONOETHANOLAMIN E 99 % METHY L ETHY L KETON E METHY L NORMA

L PROPY L KETON

E METHYLENE CHLORID E INDUSTRI A GLYCO L ETHE R D

M FUE L ADDITIV

E METHY L ISOBUTY L KETON E DATE : 4/14/9 8 TIME : 6:2 4 A

M

BLEN D QUANTIT Y

3 3 83 2 21 1 4,63 7 1,11 0 82 5 31 4 52 1 4,16 9 46,33 5 110,10 0 0 5,72 6 16,48 1 25,29 9 0 7,80 3 0 7,37 1 ------ - FIL L

DRUM S 0 0 0 0 5 3 10 7 1,80 2 21,87 4 1,42 2 4,11 8 91 9 36,52 5 54 0 13,09 7 13,87 3 30,58 1 0 25,41 6 55,88 7 5,54 2 QUANTIT Y

TOTE S

1 0 2 0

4 0 0 0 0 0 0 0 0 0 0 0 32 0 0 0 33 2 42 0 0 10 5 0 0 SMAL L C C

0 0 0 0 1 4 0 0 0 0 0 0 14 0 0 23 5 5 1,27 4 0 39 1 "81 6 1 4 PURCHAS E QUANTIT Y

0 0 0 0 0 0 1,51 7 22,34 5 1,69 4 8,40 9 49,82 6 174,50 3 0 79,32 0 25,03 3 92,01 4 98 5 42,37 3 266,66 2 22,91 1 BUL K SHI P

QUANTIT Y

2 5

56 ,

1 2

19 . 245 , 8 , 5 0 0 0 0 0 0 2 0 0 0 54 1 0 00 5 6 3 73 0 97 6 95 9 21 4 10 4^ 

### o Q G3R591- 1 PAG E 1 2 WHSE : 2 8
PRODUC T 362114 9 363500 0 363570 0 363572 0 363920 0 363922 0 367000 0 367010 0 368000 0 369000 0 370000 0 374817 2 374861 1 374905 0 375200 0 375220 0 375300 0 378502 0 378504 0 380152 4 ASHLAN D CHEMICA

L COMPAN

Y THROUGH-PLAN T USAG E & PURCHASE S FO R WAREHOUS E Ol d Galvesto n Roa d Warehous e DATE : 4/14/9 8 TIME : 6:2 4 A

M

DESCRIPTIO

N MIRAMIN E T O MORPHOLINE 99 % TEC H METHYL- N

2-PYRROLIDONE METHYL- N

2-PYRROLI D MURIATI C ACI D 2 0 DEGRE E MURIATI C ACID 2 2 DEGRE E BUTYL ACETAT E NORMA L 98 % BUTY L ACETAT E NORMA L UG BUTANO L NORMA

L PROPYL ACETAT E NORMA L PROPANOL , NORMA

L PARAPO L 250 0 ANTAROX 17R 2 PENTANOL- 1 PERCHLOROETHYLENE HI-STABI L PERCHLOROETHYLENE REFORMIN G PERCHLOROETHYLENE FLUOROCA R PHOSPHORI C ACI D 75 % TEC H PHOSPHORI C ACI D 85 % TEC H POLYGLYCO L EP-53 0 FRO M 01/01/9 7 T O 12/31/9 7

F I L L QUANTIT Y BLEN D QUANTITY 71 9 1 4 55 9 11 2 0 0 0 90 6 6,31 4 2 4,53 2 0 5,44 4 0 7 4 0 0 0 0 11,45 1 DRUM S

0 35,87 3 8,03 0 2,20 0 64,63 2 44,53 7 5,52 4 2,82 9 2,88 1 12,90 1 6,78 2 26 3 0 0 4,88 4 10 4 3,10 6 30,12 6 10,79 7 6,36 1 TOTE S

0 25,57 6 0 0 12,81 8 0 0 0 0 0 0 0 0 0 0 2,34 1 0 4,18 8 39,36 3 0 SMAL L C C

0 1 0 0 5 0 0 0 0 8 0 0 0 0 0 0 0 0 0 0 0 0 PURCHAS E QUANTIT Y

0 53,17 7 8,28 8 3,43 0 76,24 3 45,14 0 5,58 6 3,42 8 58,29 9 9,76 9 11,52 7 0 0 0 7,83 5 1,50 8 3,02 9 33,26 2 45,89 9 15,67 6 BUL K SHI P

QUANTIT Y

0 1 0 0 4,99 2 0 0 1 50,26 2 0 0 0 0 0 3,35 8 68 9 0 38 5 1,95 5 0G3R591- 1 PAG E 1 3 WHSE : 2 8
PRODUC T 384502 5 385498 0 385510 0 388800 0 390000 0 390300 0 390300 5 391240 4 392000 0 392025 3 392178 9 392870 5 392898 0 ASHLAN D CHEMICA L COMPANY THROUGH-PLAN T USAG E & PURCHASE S FO R WAREHOUS E Ol d Galvesto n Roa d Warehous e DATE : 4/14/9 8 TIME : 6:2 4 A M FRO M 01/01/9 7 T O 12/31/9 7

V ^ 392901 2 392903 0 392923 0 392979 0 392980 8 393114 0 393250 0 DESCRIPTIO N

POLYGLYCO L 112- 2 POLYPROPYLEN E GLYCO L 200 0 POLYPROPYLEN E GLYCO L 400 0 PRIMAR Y AMY L ALCOHO L PROPYLEN E GLYCO L INDUSTRI A PROPYLEN E GLYCO L US P PROPYLEN E GLYCO L US P KOSHE R G R LIF E GUAR D 300 0 BUTY L ALCOHO L SECONDAR Y XTRALUB E B SODIU M CITRAT E SOLUTIO N SODIU M SILICAT E 4 4 DEGRE E SODIU M XYLEN E SULFONAT E SODIU M SILICAT E 4 0 DEGRE E CL E SODIU M SILICAT E 4 2 DEGRE E SODIU M THIOSULFAT E 30 % TEC H SOYBEA NOIL , REFINE D BLEACHE D SOYBEA NOIL , REFINE D & BLEACH E STYREN E MONOME R 5 0 PP M INHI B SULFURI C ACI D L P BLEN D QUANTIT Y 11,20 5 0 59,51 6 0 2 7 1 7 0 0 0 0 0 0 0 0 0 0 0 111,94 3 0 0 FIL L

DRUM S 9,95 3 11,30 6 16,29 0 10,05 1 11,88 8 16 6 0 8,32 2 6,56 9 0 0 49 4 4,50 9 3,90 9 95 5 0 0 21,84 7 67,01 7 7,80 7 QUANTIT Y

TOTE S

5

7 2 4 0 0 0 0 0 0 0 0 0 0 0 0 30 7 63 3 0 0 0 03 0 79 8 41 0 SMAL L C C

0 0 0 0 0 0 0 0 2 5 0 0 0 0 0 0 0 0 0 29 0 0 PURCHAS E QUANTIT Y 17,34 9 11,77 9 70,67 7 10,12 0 12,50 0 0 -55 2 0 6,74 4 0 2,90 5 49 6 6,90 4 8,13 4 1,00 5 36 7 4 2 113,53 3 67,85 7 6,67 1 BUL K SHI P

QUANTIT Y

2 4

6 6

3 0 0 0 0 11 1 0 0 ,56 1 2 ,52 1

• 0 0 0 1 0 0 0 0 0 ,59 3

# o G3R591- 1 PAGE 1 4 WHSE : 2 8
PRODUC T 393410 0 393435 0 395510 0 395515 0 396130 3 396510 0 396511 0 396538 2 396539 2 396540 0 396650 0 396849 6 396852 0 397000 0 398000 0 398916 0 398930 0 3989320 . 399033 4 399200 0 FRO M 01/01/9 7 T O 12/31/9 7 ASHLAN D CHEMICAL COMPAN

Y THROUGH-PLANT USAG E & PURCHASE S FO R WAREHOUS E Ol d Galvesto n Roa d Warehous e
DESCRIPTIO

N SULFURI C ACI D 6 6 DEGRE E SULFURI C ACI D 98 % TRIETHANOLAMINE 99 % TRIETHANOLAMINE 99 % LO W FREEZ E SURFACTANT N

09 5 M TERGITO L NP- 9 TERGITO L NP-9. 5 TERPENE E

X TETRAETHYLENE GLYCO L TETRAHYDROFURA

N TEXANO L ESTER ALCOHO L TRICHLOROETHANE 11 1 W/ O DIOX A TRICHLOROETHANE 11 1 INDUSTRI A TRICHLOROETHYLEN E DEGREAS E TRIETHYLENE GLYCO L GLYCO L ETHER DP M GLYCO L ETHE R P

M GLYCO L ETHE R P

M ACETAT E DIAMON D SC I 1 VINYL TOLUEN E 5 0 T DATE : 4/14/9 8 TIME : 6:2 4 A

M

BLEN D QUANTIT Y

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1,01 5 11,54 5 1,93 6 0 0 FIL L

DRUM S 18,37 0 61,23 7 9,08 9 1,58 5 4,24 1 28,03 9 14,53 4 0 4,55 3 0 7,17 6 2,92 0 3,03 0 6,70 3 51,97 6 13,53 2 8,03 7 8,80 7 16 2 66,40 6 QUANTIT Y

TOTE S 2 3

2

1 0 73 6 71 8 0 0 28 1 58 1 52 4 0 0 0 0 0 0 0 0 0 0 0 0 68 6 SMAL L C C

0 0 0 0 0 0 0 5 0 0 0 22 8 2 4 1 0 0 1 9 0 26 2 0 0 PURCHAS E QUANTIT Y 19,01 5 63,81 7 9,22 3 1,65 9 10,36 0 34,59 0 24,34 2 1 4,59 5 99 4 96,77 1 3,12 2 3,12 9 10,46 9 49,20 7 12,83 8 31,29 7 14,25 7 0 69,28 9 BUL K SHI P

QUANTIT Y

0 56 1 1 0 4,79 3 8,67 6 12,01 5 5 4 0 0 86,41 2 4 0 0 3,25 1 1,65 5 85 8 11,15 0 8,55 9 5 2,08 6

# ^ p G3R591- 1 PAG E 1 5 WHSE : 2 8

PRODUC T 399217 2 399217 8 702083 8 702084 0 702084 3 702100 0 703040 0 703055 0 703080 0 712650 0 712791 0 713000 0 713028 0 713800 0 713801 1 716027 0 716029 8 735000 0 739600 0 741918 0 ASHLAN D CHEMICA L COMPAN Y THROUGH-PLAN T USAG E & PURCHASE S FO R WAREHOUS E DATE : 4/14/9 8 TIME : 6:2 4 A M Ol d Galvesto n Roa d Warehous e
DESCRIPTIO N WITCONAT E 60 T WITCAMID E 51 1 AMBITRO L F L 4 0 AMBITRO L C N AMBITRO L NT F ANTIFREEZ E PERMANEN T BUL K ETHANO L SPE C IN D ANH Y 408 2 ETHANO L SPE C IN D ANH Y 413 5 ETHANO L SPE C IN D 190 P 408 5 WATE R DEIONIZE D AMBITRO L NT C WATE R DISTILLE D IN K SOLVEN T P M

6193 / DU P FLUI D ETHANO L SD A

2- B 20 0 PROO F ETHANO L SD A

23 H MO D 19 0 PROO F ETHANO L SD A

40- B 20 0 PROO F ETHANO L SD A

3 C 20 0 PROO F METHANO L OCTANE , NORMA L SODIU M HYPOCHLORIT E 10 % SOLU T FRO M .01/01/9 7 T O 12/31/9 7 BLEN D QUANTIT Y 2 5 18,12 0 0 1,19 7 0 0 0 1,96 1 0 119,30 9 0 7,56 6 0 0 0 0 19 6 7,34 0 0 0 DRUM S

0 0 0 0 0 1,04 5 54 0 4,21 2 64 8 0 49 5 0 22 0 2,20 0 14,68 5 22,27 5 0 169,83 0 5,77 5 0 FIL L QUANTIT Y

TOTE S 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 10,18 4 0 0 SMAL L C C

0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 7 0 0 0 PURCHAS E QUANTIT Y

0 0 5,96 3 1,19 4 1,99 3 1,09 9 54 4 4,74 5 70 4 20,48 5 50 0 0 0 2,20 3 14,97 7 20,61 5 0 478,54 3 5,76 0 22,19 4 BUL K SHI P

QUANTIT Y

0 0 7,68 7 0 1,98 2 13 S 0 2,69 0 0 0 0 0 0 0 0 0 0 287,31 0 1 6 0G3R591- 1 PAG E 1 6 WHSE : 2 8
PRODUC T 743000 0 744036 3 749009 3 750058 6 750081 7 750096 3 750112 3 750114 3 750128 5 750136 7 750227 4 750229 9 O O 750230 1 750230 2 750230 3 750230 4 750241 8 750244 0 750248 7 750248 8 ASHLAND CHEMICAL COMPAN Y THROUGH-PLANT USAG E & PURCHASE S FO R WAREHOUS E DATE : 4/14/9 8 TIME : 6:2 4 A

M



# Y 3 Ol d Galvesto n Roa d Warehous e

DESCRIPTIO

N ETHANO L PROPRIETARY 190 P 322 4 HOUSTO N GUN CLEANE R K

K 028-1 1 ETHANO L SD

A 40- 2 19 0 PROO F AMERCOAT 8 CS D A BRINE R 8 5 ALVI N PAIN T STRIPPE R REACTIV E REDUCE R 118 5 A URETHANE REDUCE R 87 0 A W S 914 2 H RE

V OPTICA L COUPLIN G FLUI D DIAMON D SC I 2 URETHANE REDUCE R 88 5 A (REV ) LACQUE R THINNE R 25 0 C 08 9 (RE V URETHANE REDUCE R 87 0 A (REV ) CS D 7 T 3 5 R (REV ) CS D K 12 0 (REV ) ICE*BREAKE R (TM ) 3 0 3 METHANO L 99 % & WATE R R C LACQUE R THINNE R 1 C& W BLEN D 1 5 (NE

W AG E 80 ) FRO M 01/01/9 7 T O 12/31/9 7 BLEN D QUANTIT Y

0 48,58 3 0 0 0 0 0 52 5 0 0 0 0 0 0 0 0 0 0 0 0 FIL L

DRUM S 1 5

5

1 ,33 6 93 5 81 0 0 0 33 0 66 0 6 0 16 5 0 99 0 ,21 0 0 33 0 0 0 5 5 ,65 0 0 38 5 QUANTIT Y

TOTE S 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 SMAL L C C

1 0 0 0 0 0 0 0 0 0 0 5 4 5 14 0 5 0 0 0 0 0 0 PURCHAS E QUANTIT Y 1 5 64 2 0 85 3 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 BUL K SHI P QUANTIT Y 11,03 5 18,65 0 0 2,52 5 1,00 0 4 7 0 0 0 2 4 8 0 0 0 6,64 2 2,00 0 0 0 1 0G3R591- 1 PAG E 1 7 WHSE : 2 8
PRODUC T 750249 6 750249 7 750252 5 750273 3 750507 4 750734 5 750804 5 751024 5 752303 6 753091 8 753119 4 753900 0 {jO 755260 0 \ ^ 764412 1 765111 0 765114 7 765207 8 765241 9 765286 8 767666 7 ASHLAN D CHEMICA

L COMPAN

Y THROUGH-PLAN T USAG E & PURCHASE S FO R WAREHOUS E Ol d Galveston Roa d Warehous e
DESCRIPTIO

N MEDIU M HAP S BLEND SLO W HAP S BLEN

D IMS XYLA

N A CS D 12 X 3L T CONTINENTA

L CLEANER CS D 7 T 3 5 R CS D 609 6 A 3 T 50 1 A 50/5 0 ANTIFREEZ E D I W DIAMON D SC I 1 REVISE D HURS T 1 5 M

B CON D (A ) BLENTEC H 1 C 15 2 CS D 609 6 A

2 C B 3 4 SHERWI N WILLIAM S R 7 K 5 4 (A ) T 8177 2 TYP E 2 COOPER SOLVEN T 1 E X 45-5 5 ICE*BREAKER (TM ) 3 0 5 FRO M 01/01/9 7 T O 12/31/9 7 BLEN D QUANTIT Y

0 0 0 0 0 8,23 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 DRUM S

3 ,

3 3 ( 5 5 5 5 22 0 0 60 5 0 0 5 5 0 11 0 0 0 ,90 5 0 ,52 0 ,79 5 0 5 5 0 11 0 FIL L QUANTIT Y

TOTE S 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 SMAL L C C

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 2,71 0 0 0 0 0 DATE : 4/14/9 8

TIME : 6:2 4 A

M
PURCHAS E BUL K SHI P QUANTIT Y QUANTIT Y

0 0 0 0 0 0 0 0 4,08 8 0 0 0 0 0 0 0 0 0 0 0 0

0 0 5,10 9 0 8,23 1 2,40 0 0 4,08 8 5 49 8 23,79 6 0 69 7 20 3 0 1,93 7 0 9,99 7 0^ G3R591- 1 PAGE 1 8 WHSE : 2 8
PRODUC T 767876 6 769017 7 769111 0 772552 2 772840 0 783423 3 783438 3 784132 0 787511 8 787573 0 787578 9 787664 6 788725 2 788776 2 789277 2 789278 2 789294 3 789450 3 789565 3 789671 2 ASHLAND CHEMICA L COMPAN

Y THROUGH-PLAN T USAG E & PURCHASE S FOR WAREHOUS E Ol d Galvesto n Road Warehous e DESCRIPTION FOSRO C SLI P OF F FAS T WAS H 75-2 5 BLEND P P BROCHSTEIN S RETARDER INDUSTRIA

L META L FINISHER S FAS T BAS E MAKE

R A URETHAN E REDUCE R 88 5 A ST X 10 6 C RUSSEL L STANLE Y BLEN D THINNE R 5 R M BLEND CS D 11 6 E RUBBE R REJUVENATO R THINNE R 2797 5 THINNE R 2913 6 ' THINNE R 1 L (REV ) URETHAN E REDUCE R 117 0 U S 166 0 WE T SO L LACQUE R THINNE R 25 0 C 08 9 ASP T 1 FRO M 01/01/9 7 T O 12/31/9 7 BLEN D QUANTIT Y

0 0 0 0 0 0 65 4 0 0 0 0 0 0 0 0 0 0 0 12 0 0 DRUM S

2

1

6 0 ,25 5 5 5 16 5 5 5 16 5 0 0 0 ,21 0 33 0 0 79 5 15 0 ,31 4 72 0 0 0 0 0 FIL L QUANTIT Y TOTE S SMAL L C C DATE : 4/14/9 8 TIME : 6:2 4 A

M
PURCHAS E BUL K SHI P QUANTIT Y QUANTIT Y 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1,00 4 0 0 0 0 0 0

0 0 0 0 0 0 0 0 0 0 0 0 0 5 5 0 0 0 0 0

0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 26 5

0 0 0 0 0 0 1 16,31 7 0 0 17,94 8 0 0 0 0 6,54 6 111,82 0

0 29,72 6G3R591- 1 ASHLAN D CHEMICAL COMPAN

Y DATE : 4/14/9 8 PAGE 1 9 THROUGH-PLANT USAG E & PURCHASE S FO R WAREHOUS E TIME : 6:2 4 A M WHSE : 2 8 Ol d Galvesto n Roa d Warehous e FRO M 01/01/9 7 T O 12/31/9 7 BLEN D FIL L QUANTITY PURCHAS E BUL K SHI P PRODUC T DESCRIPTIO N QUANTIT Y DRUM S TOTE S SMAL L C C QUANTIT Y QUANTIT Y 792600 1 TYP E WAS H M 5 5 0 0 0 0 0
* * * NORMA L EO J ** *

# Ashlan

d Chemica

l Compan y Rollin g 12-Mont

h Blending Tan

k HA P Emissions Facilit y ID : 02 8 Facilit y Name : Houston , T X 1 2 Month s Ending : Dec/9 7 Apri l 14 , 199 8 Pag e 3 o f

5

10 2 102 735000 0 Methano l 354000 0 Methy l Ethy l Keton e 2 0 0 0 0 1 0 1 0 1 2.4 7 2.6 8

6~ ^ 10 2 375200 0 Perchlorocthylcn c H i STVPD G 1.6 4 3,42 5

9,01 9

2 4 Tan k ID 10 2 10 2 10 2 Produc t Cod e Nam e 300144 0 H i So l 1 0 300145 0 H i So l 1 5 300250 0 Lacolcn c Jan/9 7 0 0 0 Feh/97 0 0 0 Mar/97 0 0 0 Apr/9 7 0 0 0 Monthl y Emission s (lbs ) May/97 0 0 0 Jun/9 7 0 0 0 Jul/9 7 0 0 0 Aue/9 7 0 0 0 Sep/97 0 0 0 Oct/9 7 0 0 0 Nov/9 7 0 0 0 Dec/9 7 0 0 0 Av g Emi

s Facto r (lbs/Kgal ) 0.1 1 0.0 2 1.4 5 12-Mont

h TPu t (ga D 45 1 8 3 20 6 12-Mont

h Emissions Gbs) 0.0 5 0.0 0 0.3 0 8.4 5 24.2 0 10 2 10 2 362000 0 Methy l Isobutyl Keton e 359000 0 Methylen e Chlorid e 0 0 0 0 0 7 0 4 0 3 0 0 0 1 4 0 0 0 8 0 7 0 1 0 0 0 0.6 2 24.1 5 2,37 1

2,19 4 1.4 6

52.9 8 0.0 4
10 2 300286 0 Supe rLacolen c 102 300185 0 Toluen e 102 300299 0 VM& P Naphth a 10 2 300195 0 Xylen e Tan k 10 2 Subtotals :

5 702084 0 AmbitrolC N 5 302065 6 ARDR1L295 7 5 337000 0 Ethylen e Glyco l 0 1 0 0 7

0 0 0 0 1 0 0 9

0 0 0 0 1 0 0 1 4

0 0 0 0 1 0 0 1 1

0 0 0 0 1 0 0 1 5

0 0 0 0 2 0 0 1 5

0 0 0 0 3 0 1 31 '

0 0 0 0 2 0 1 1 6

0 0 0 0 3 0 I 3 0

0 0 0 0 2 0 0 2 7

0 0 0 0 2 0 0 2 2

0 0 0 0 2 0 0 1 5

0 0 0 1.1 0 0.9 7 0.5 3 0.3 2

0.0 0 0.0 0 0.0 0 2

20,94 0 47 0 14,25 6 77,18 6

41 2 17 4 78 7 0.0 0

20.4 0 0.2 S 4.6 3 211.3 4

0.0 0 0.0 0 0.0 0

## Ashlan

d Chemical Compan y Rollin g 12-Mont h Blendin g Tan k HA P Emission s Facilit y ID : 02 8 Facilit y Name : Houston , T X 1 2 Month s Ending : Dcc/9 7 Apri l 14 , 199 8 Pag e 4 o f 5 Monthly Emission s (lbs ) Av g Emi s 12-Mont h 12-Mont

h Tan k I D 5 5 Produc t Cod e Nam e 307000 0 Glyco l Ethe r

E B 307100 0 Glyco l Ethe r

E B Acetat e Jan/97 Feb/9 7 Mar/97 Apr/97 May/9 7 0 0 0 0 0 0 0 0 0 0 Jun/97 Jul/97 Aug/97 0 0 0 0 0 0 Sep/97 0 0 Oct/9 7 Nov/9 7 Dec/97 0 0 0 0 0 0 Facto r

(Ibs/Kgal ) 0.1 6 0.0 1 iru i

(gal ) 30 5 1 0 emission s

(lbs ) 0.0 5 0.0 0
3405900 Glyco l Ethe r

E P 0.0 7 3002420 Hexan e 1 3 1 6 4.4 1 300243 0 Hexaso l 3.6 5

354000 0 Methy l Ethy l Keton e 2.4 4 362000 0 Methy l Isobuty l Keton e 0.5 4 27 1 11-59 0

2,83 2 92 1 0.0 2

51.1 2 0.0 3 5 

# : 0 5



# _ a 

# s 5 300144 0 H i So l 1 0 300145 0 H i So l 1 5 300250 0 Lacolcn c 735000 0 Methano l 0 0 0 3 0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 1 0 0



## . o 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0.0 9

0.0 2 1.4 1 1.8 6 15 2

4 3 9 4 2,43 0 0.0 1

0.0 0 0.1 3 4.5 2 6.9 1 0.5 0 5 5
5 5 5 5 359000 0 Methylen e Chlorid e 375200 0 Pcrchloroethylen e H i

STVPD G 300286 0 Supe r

Lacolcn e 300185 0 Toluen e 300299 0 VM& P Naphth a 300195 0 Xylen e 0 0
0 1 0 0 0 0
0 1 0 0 1 2 0
0 2 0 0 7 0
0 1 0 1 6 0
0 2 0 1 0 0
0 0 0 0 0 0
0 0 0 0 0 0
0 0 0 0 0 0
0 0 0 0 0 0
0 0 0 0 0 0
0 0 0 0 0 0
0 0 0 0 23.4 5 (N/A )
1.3 0 0.9 1 0.4 9 0.2 8 1,10 1

0
3 8,36 0 35 2 6,60 7 25.8 2

0.0 0
0.0 0 7.6 4 0.1 7 1.8 6

# Ashlan

d Chemica

l Compan y Rolling 12-Mont h Blendin g Tan k HA P Emissions Facilit y ID : 02 8 Facilit y Name : Houston , T X Tank Product I D Code Nam

e Tank S Subtotals : 1 2 Month s Ending : Dcc/9 7 April 14,199 8 Page 5 o f 5 Monthl y Emission s Gbs

) Av g Emi s 12-Mont h 12-Mont h Facto rTPu tEmission s Jan/9 7 Feb/97 Mar/9

7 Apr/97 May/97 Jun/9 7 Jul/9 7 Aue/97 Sep/9 7 Oct/9 7 Nov/9 7 Dec/9 7 (lbs/Kgal ) (gal ) (lbs ) 1 2 1 6 2 5 2 0 2 7 0 

### 36,45 1 98.8 0

HA P Total s fo rPerio d Endin g 12/97 : 32 43 6 8 5 5 7 5 4 7 9 6 5 0 9 4 8 4 6 8 4 7 277,64 6 759.2 2 Total Blendin g Tan k HA P Emission s (tons) : 0.3 8

^> 0

## Ashlan

d Chemical Company Rollin g 12-Mont h Containe rFillin g HA P Emission s Facilit y ID : 02 8 Facilit y Name : Houston , T X
Produc t Cod e 702100 0 302065 6 396852 0 Nam e

Antifreez e ARDRI L 295 7 Chlorothcn e S M Solven t Averag e Submerge d Filling : 100 % Monthl y Emission s (lbs ) Jan/9 7 Feb/97 Mar/97 Apr/9 7 May/9 7 Jiui/9 7 Jul/9 7 Aug/97 Sep/9 7 Oct/97 Nov/97 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0000000 9 1 2 7 0 Dru m 100 % 0 %

Dcc/9 7 0 0 0 Con t 100 % 0 % Av g Emis Facto r (lbs/Kgal ) 0.0 0 0.0 0 9.2 2 Apri l 17 , 199 8

Pag e 1 o f

3 12-Mont h TPu t (gal ) 93 0 48 0 3,05 3 12-Mont

h Emissions (lbs ) 0.0 0 0.0 0 28.1 5 321000 0 Dibuly l Plilhalal c 322000 0 Diethanolamin e 0 0 0 0 0

0 0 0 0 0 0.0 0 0 0.0 0

743000 0 Ethano l P M p r 322 4 1.4 0 713801 1 Ethano

l SDA 23 H MO

D 19 0 Proo f 1.4 4
3353000 Ethylbenzen e 0.5 4 336500 0 Ethylen e Dichlorid e 4.3 1 9,46 4 8,05 2

85 9 20 6 8,21 4 97 7 0.0( 1

0.0 0 331000 0 A 741802 9 —P * 703080 0 Diocty l Phthalat e

Ethano l 3A200P F Ethano l 408 5 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0.0 0

1.8 2 1.4 4 9,25 7

7 3 3 5 0.0 0

0.1 3 0.0 5 1.2 1 0.3 0
4.4 1 4.2 1 337000 0 337000 8 306000 0 311025 0 360050 0 Ethylen e Glyco l

Ethylen e Glyco l Polyeste rGr Glyco l Ethe rD B Glyco l Ethe rD E Glyco l Ethe rD M Fue l A d Gd 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0.0 0 0.0 0 0.0 0 0.7 5 0.0 1 28,12 0

4,30 4 24,26 5 5,23 0 56,70 0 0.0 7

0.0 1 0.0 3 3.9 0 0.6 8

# Ashlan

d Chemica

l Compan y Facilit y ID : 02 8 Facilit y Name : Houston , T X Produc t Cod e 340594 2 3070000 3071000 3405900 340595 0 Name

GLYCO L ETHE RD M FUE L ADDITIV

E Glyco l Ethe rE B Glyco l Ethe rE B Acetat e Glyco l Ethe rE P Glyco l Ethe rT B Jan/9 7



### 0 1 0 0 0 1 2 Month s Ending :

Fcb/9 7 

### 0 0 0 0 0 Mar/97 

### 0 2 0 0 0 Dcc/9 7

Apr/9 7 

### 0 1 0 0 0 

# Rolling 12-Mont h ContainerFillin g Averag e Splash Filling : Averag e Submerge

d Filling : Monthl y Emission s (lbs ) May/9 7 

### 0 1 0 0 0 Jun/9 7 

### 0 4 0 0 0 Jul/9 7 

### 0 2 0 0 0 Aue/9 7 

### 0 1 0 0 0 Tot e

0 % 100 %

Sep/9 7 Oct/9 7 Nov/9 7 

### 0
1 0 0 0 0 0 0 2 0 0 0 0 0 0 Drum

100 % 0 %

Dec/9 7 

### 0 1 0 0 0 Con t 100 % 0 % Av g Emi s Facto r 0bs/Kga0 0.0 1 0.2 7 0.0 2 0.1 2 0.0 0 

# HA P Emissions

Apri l 17 , 199 8 Page 2 o f 3 12-Mont h TPu t (ga O 56,15 7 59,45 6 17 5 5,58 2 76,56 8 12-Mont

h Emission s (lbs ) 

### 0.8 1 15.9 2 0.0 0 0.6 7 0.0 3 300242 0 

# .x ;

300250 0 735000 0 

### Hexan

e 1 2 2 1 1 6 1 6 7.2 2 

### 12,60 0 300243 0 Hexaso

l 6.0 5 3 6

Lacolen e Methano l 6 7 1 4 2 7 

### 0 1 1 1.9 4 78 3 

### 3 9 12 8 1 7 1 1 1 7 2 3 

### 2.0 1 182,42 9 90.9 6 0.2 2 

### 300144 0 300145 0 H

i Sol 1 0 H i So l 15 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0.1 2 0.0 5 5,33 1

1,27 2 0.6 3

0.0 6 1.52 366.5 6 354000 0 3620000 359000 0 3639200 3639220 375300 0 Methy

l Etliy l Ketone Methy l Isobuty l Ketone Methylen e Chloride Muriati c Acid Muriati c Acid 22 * Pcrchloroethylcn

e Freon 8

0 2 6 0 0 0 9 0 7 1 1 0 4 7 0 2 13 7 0 1 0 0 4 2 1 15 0 1 3 2 8 0 3 0 0 2 1 1 2 0 0 0 2 1 3 15 3 0 0 2 2 0 1 3 3 0 0 1 2 0 6 8 8 0 0 2 2 0 8 7 3 0 0 1 9 0 2 9 1 3 0 0 1 6 1 87 4 10 0 2.8 7 0.9 2 17.2 0 0.6 2 0.7 0 1.3 9 62,10 1

9,99 5 30,27 2 82,43 5 44,53 5 3,10 5 178.0 6

9.2 0 520.7 3 50.9 6 31.3 3 4.3 1

# Ashlan

d Chemica

l Compan y Rollin g 12-Mont h ContainerFilling HAP Emissions Facilit y ID : 02 8 1 2 Month s Ending : Dcc/9 7 Tot e Averag e Splas h Filling : 0 % Dru m 100 % 

### Cont

100 % Apri

l 17 , 199 8 Facilit y Name : Houston , T X Produc t Cod e Name Average Submerge d Filling : 100 % Monthl y Emission s (lbs ) Jan/97 Feb/97 Mar/97 Apr/9 7 May/97 Jun/9 7 Jul/9 7 Aue/9 7 Sep/9 7 Oct/9 7 Nov/9 7 

### 0 % 0 % Av g Emi s facto r Dec/9 7 (lbs/Kgal ) 

### 12-Mont h TPu t (gal) Pag e 3 o f

3 12-Mont h Emission s (lbs ) 

### 375200 0 Perchloroethylen e H i STVPD G 1.6 2 375220 0 Perchloroethylen e Reformin

g 0.6 7 4,95 6 2,44 5 8.0 2



### 1.64 393114 0 300286 0 300185 0 397000 0 300299 0 300195 0 Styren

e Monome r5 0 IN Supe rLacolen e Toluen e Trichloroethylen

e VM& P Naphth a Xylene 1 0 2 4 1 1 2 0 4 0 0 1 0 0 7 5 0 1 1 0 9 2 0 2 0 0 1 3 5 0 1 2 0 7 0 0 2 5 0 9 0 0 1 3 0 13 0 0 1 1 0 8 8 0 1 4 0 8 0 0 2 2 0 9 2 0 3 2 0 9 6 0 2 0.3 4 1.6 4 1.22 4.7 8 0.6 8 0.4 1 70,09 9

1 0 80,35 9 6,71 1 2,01 5 41,50 8 23.6 1

0.0 2 98.3 4 32.0 5 1.37 17.1 9
HA P Total s fo rPerio d Endin g 12/97 : 11 5 10 7 8 2 9 5 13 0 102 20 1 9 3 14 8 146 10 1 17

8 1,001,15 3 1,497.3 5 Total Containe rFillin g HA P Emission s (tons) : 0.7 5

## Ashlan

d Chemical Compan y Rollin g 12-Mont h Bul k Loadin g HA P Emission s

743000 0 Ethano l P M p r 322 4 

### 0.5 9 61 8 3353000 Ethylbenzen e 0.2 2 161,12 0 336500 0 Ethylene Dichlorid c 1.7 8 

### 33 337000 0 Ethylen

e Glycol 0.0 0 

### 16,13 8 Facilit y ID : 02 8 Facilit y Name : Houston , T X Produc t Cod e 7020840 7021000 321000 0 322000 0 331000 0 Nam e Ambitro l C N Antifreeze Dibuty l Phthalat e Diethanolamine Dioctyl Phthalat

e Jan/97



### 0 0 0 0 0 1 2 Month s Ending :

Feb/97 

### 0 0 0 0 0 Mar/97 

### 0 0 0 0 0 Dec/9 7

Apr/9 7 

### 0 0 0 0 0 Averag e Splash Filling : Average Submerge

d Filling : Monthl y Emission s (lbs ) May/9 7 

### 0 0 0 0 0 Jun/97 

### 0 0 0 0 0 Jul/9 7 

### 0 0 0 0 0 Aug/97 

### 0 0 0 0 0 Sep/9 7 

### 0 0 0 0 0 Bul k

0 % 100 %

Ocl/9 7 Nov/9 7 

### 0 0 0 0 0 0 0 0 0 0 Dec/9 7 

### 0 0 0 0 0 Av g Emi s Facto r (lbs/Kgal ) 

### 0.0 0 0.0 0 4.3 0 0.0 0 0.0 0 Apri

l 17 Page 12-Mont h TPu t (gal ) 

### 1,13 7 8 0 4 4 9 12,27 0 12- 1

Em i 

### 1998 lo f 2 Mont h ission s (lbs ) 

### 0.0 0 0.0 0 0.0 2 0.0 0 0.0 0 0.3 6 35.4 2 

### 0.0 6 0.0 1 306000 0 3110250 3600500 340594 2 3070000 3405900 3002420 3002430 300144 0 Glyco

l Ethe rD B Glyco l Ethe rDE Glyco l Ethe rD M Fue l A d G d GLYCO L ETHE RDM FUE L ADDITIV

E Glyco l Ethe rE B Glyco l Ethe rE P Hexan e Hexaso l H i So l 1 0 0 0 0 0 0 0 7 4 0 0 0 0 0 0 0 0 6 9 0 0 0 0 0 0 1 0 6 4 0 0 0 0 0 0
1 0 7 6 0 0 0 0 0 0 0 0 7 3 0 0 0 0 0 0 1 0 7 6 3 0 0 0 0 0
2 0 15 9 0 0 0 0 0 0 1 0 10 4 0 0 . 0 0 0 0
1 0 7 7 0 0 0 0 0 0 0 0 7 0 0 0 • 0 0 0 0 1 0 6 3 0 0 0 0 0 0 0 0 6 8 0 0 0.0 0 0.2 5 0.0 0 0.0 1 0.1 3 0.0 5 2.8 7 3.5 4 0.0 5 1,620

5 245,21 0 22,97 4 65,68 3 6,36 1 338,18 2 95 9 21,19 1 0.0 0

0.0 0 1.1 4 0.1 4 8.7 3 0.3 0 971.8 1 3.3 9 1.1 6

## Ashland Chemica

l Company Rollin g 12-Mont h Bul k Loadin g HA P Emission s Facilit y ID : 02 8 Facilit y Name : Houston , T X 1 2 Months Ending : Dcc/9 7 Bul k Averag e Splas h Filling : 0 % Averag e Submerge dFilling : 100 % Apri l 17, 199 8 Pag e 2 o f

2

735000 0



## V5 > Produc t Cod e 300145 0 300250 0 Nam e

Hi So l 1 5 Lacolen e Monthl y Emission s Gbs ) Jan/9 7 Feb/9 7 Mar/9 7 Apr/9 7 May/9 7 Jun/9 7 Jul/9 7 AujO T Sep/9 7 00000000 0 00000000 0 Av g Emi s facto r Oct/9 7 Nov/9 7 Dec/9 7 (lbs/Kgal ) 0 0 0 0.0 2 0 0 0 0.8 6 12-Month TPu t (gal ) 1,03 2 38 5 12-Mont

h Emissions (lbs ) 0.0 2 0.3 3 Methano l 1 7 1 8 19 2 0 1 2 1 5 1 7 1 3 2 5 3 6 1 8 5 0 0.8 9 294,71 8 354000 0 Methyl Ethy l Keton e 1.4 8 29,23 7 362000 0 Methy l Isobutyl Keton e 0.3 9 11,50 3

HA P Total s fo r Perio d Endin g 12/97 : 261.7 1 43.2 9 4.4 4 359000 0 375200 0
375220 0 300185 0 397000 0 300299 0 300195 0 Methylen e Chlorid e

Perchloroethylen e Hi STVPD G Perchloroethylen e Reformin g Toluen e Trichloroethylen e VM& P Naphth a Xylen e 1 1 0
0 1 0 0 2 0 0
0 7 0 0 2 3 7 O
0 1 1 0 0 3 1 9 0
0 9 0 0 3 1 2 0
0 1 7 0 0 3 0 1
0 3 0 0 5 5 5 0
0 8 0 0 5 1 1 0
0 5 0 0 2 4 1 1
0 4 4 0 3 5 4 0
0 8 2 0 4 2 0 0
0 1 1 0 0 3 1 6 0
0 1 5 1 0 5 10.0 8 0.6 7
0.5 7 0.5 8 2.0 4 0.3 0 0.1 8 27,53 1

3,35 6
68 9 169,86 3 3,25 0 1,94 2 213,19 3 277.4 5

2.2 4
0.3 9 98.6 4 6.6 1 0.5 9 38.9 6

109 10

5 14 5 13 5 125 11 7 25 5 14 3 16 3 18 1 120 160 1,650,33 2 1,757.22 Total Bul k Loadin g HA P Emission s (tons) : 0.8 8

## Ashland Chemica l Company Rollin g 12-Mont h Fugitiv e HA P Emission s Facilit y ID : 02 8 Facilit y Name : Houston , T X 1 2 Month s Ending : Dcc/9 7

Produc t Cod e

396852 0

322000 0



### J C Monthly Emission s (lbs )

Nam e Jan/9 7 Feb/97 Mar/97 Apr/9 7 May/9 7 Jun/9 7 Jul/9 7 Aue/9 7 Sep/9 7 Oct/9 7 Nov/9 7 Dec/9 7

Chlorolhen e S M Solven t 3210000 Dibuty l Phthalat e

Diethanolamin e

7430000 Ethano l P M p r 322 4 713801 1 Ethano l SDA 23 H MOD 190

Proo f Apri l 14

. 199 8 Pag e 1 of

3 12-Month Emission s (lbs ) 702084 0 702100 0 302065 6 Ambilro l C N

Antifreez e ARDRI L 295 7 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0.0 7 0.0 4 0.0 3 0.1 3 0.4 2 0.3 6 331000 0 741802 9 703080 0 Diocty l Phthalat e

Ethano l 3A200P F Ethano l 408 5 1 3 0 0 1 1 0 0 1 3 0 0 1 2 0 0 1 3 0 0 1 2 0 0 1 3 0 0 1 3 0 0 1 2 0 0 1 3 0 0 1 2 0 0 1 3 0 0 149.0 6 0.0 0 0.0 0 0.0 5 0.0 1
335300 0 336500 0 337000 0 337000 8 306000 0 311025 0 360050 0 Ethylbenzen e

Ethylen e Dichlorid e Ethylen e Glyco l Ethylen e Glyco l Polyeste r G r Glyco l Ethe r

D B Glyco l Ethe r

D E Glyco l Ethe r

D M Fue l A dG d 1 3 0 1 3 0 1 3 0 1 1 2 0 1 1 0 1 2 0 0 1 3 0 1 3 0 1 3 0 1 1 3 0 1 2 0 1 2 0 1 1 3 0 1 3 0 1 3 0 1 1 3 0 1 2 0 1 2 0 0 1 3 0 1 3 0 1 3 0 0 1 3 0 1 3 0 1 3 0 0 1 2 0 1 2 0 1 2 0 0 1 3 0 1 3 0 1 3 0 0 1 3 0 1 2 0 1 2 0 1 1 3 0 1 3 0 1 3 0 0 153.0 8 0.0 4 150.1 2 0.1 9 149.5 3 0.2 3 5.7 5

# Ashlan

d Chemica

l Compan y Rolling 12-Mont h Fugitive HAP Emissions Facilit y ID : 02 8 Facilit y Name : Houston , T X 1 2 Month s Ending : Dec/9 7 Apri l 14,199 8 Page 2 o f 3 Produc t Cod e Monthl y Emissions (lbs ) Name Jan/97 Feb/9 7 Mar/97 Apr/97 May/97 Jun/97 Jul/9 7 Aug/9 7 Sep/9 7 Oct/9 7 Nov/97 Dec/9 7 12-Mont h Emission s (lbs ) 

### 340594 2 3070000 3071000 3405900 340595 0 300242 0 300243 0 V_J\300144 0 300145 0 000000 1 3002500 735000 0 354000 0 362000 0 359000 0 3639200 3639220 GLYCOL ETHE RD M

FUE L ADDITIV E Glycol Ethe r

E B Glycol Ethe r

E B Acetat e Glycol Ethe r

E P Glycol Ethe r

T B Hexan e Hexaso l H i So l 1 0 H i So l 1 5 Housto n Blen dTan k

Was h 50/5 0 Lacolen e Methano l Methy l Ethy l Keton e Methy l Isobuty l Keton e Methylen e Chlorid e Muriati c Aci d Muriati c Aci d22 ' 0 1 3 0 0 0 1 4

. 0 1 0 0 0 1 6 1 3 1 3 1 3 0 0 0 1 2 0 0 0 1 2 0 1 0 0 0 1 3 1 2 1 1 1 2 0 0 0 1 3 0 0 0 1 4 0 1 0 0 0 1 4 1 3 1 3 1 3 1

. 0 0 1 3 0 0 0 1 3 0 1 0 0 0 1 3 1 2 1 2 1 2 0 1 0 1 3 0 0 0 1 4 0 1 0 0 0 1 4 1 4 1 3 1 3 0

'• 0 

### 0 1 3 0 0 1 1 3 0 1 0 1 3 0 1 5 1 4 1 2 1 2 0 0 0 1 4 0 0 0 1 4 0 1 0 1 4 0 1 8 1 4 1 3 1 3 0 0 1 1 3 0 0 0 1 4 0 1 0 1 4 0 1 5 1 4 1 3 1 3 0 0 0 1 3 0 0 0 1 4 0 1 0 1 3 0 1 4 1 4 1 2 1 2 0 0 0 1 3 0 0 0 1 4 0 I 0 1 3 0 1 5 1 4 1 3 0 0 0 0 13 0 0 0 13 0 1 0 1 2 0 1 4 1 4 1 2 0 1 0 0 1 3 0 0 0 1 4 0 1 0 1 3 0 1 5 1 4 1 3 0 0 1 2.7 8 156.2 7 0.0 1 0.4 3 3.3 8 162.1 2 0.0 1 16.0 5 0.2 8 91.9 8 0.2 1 174.6 8 162.5 0 150.3 7 113.2 5 3.4 9 1.9 7

# Ashlan

d Chemica

l Compan y Facilit y ID : 02 8 Facilit y Name : Houston , TX
Produc t Code Nam e 375300 0 Perchloroethylen e Freo n 375200 0 Perchloroethylen e Hi

STVPD G 

# Rolling 12-Mont h Fugitive 1 2 Month s Ending : Dcc/9 7
Monthl y Emission s (lbs ) Jan/9 7 Fcb/9 7 Mar/9

7 Apr/97 May/9 7 Jun/9 7 Jul/9 7 Aue/9 7 Sep/97 Oct/9 7 Nov/9 7 Dec/9 7 

### 00000000000 0 00000000000 0 

# HAP Emissions April 14,199 8 Pag e 3 o f 3 12-Mont h Emissions Obs ) 

### 0.1 4 0.2 7
3752200 Perchloroethylen e Reformin g 393114 0 Styren e Monome r 5 0 I N

HA P Total s fo rPerio d Endin g 12/97 : 0.1 2 3.1 0 

### 300286 0 300185 0 397000 0 J L 300299 0 300195 0 Super

Lacolen c Toluen e Trichloroethylen e VM&P Naphth a Xylen e 0 .1 3 0 1 1 3 0 1 2 0 1 1 2 0 14 0 1 1 3 0 1 3 0 1 1 3 0 3 0 0 1 1 4 0 1 6 0 1 1 4 0 1 7 0 1 1 5 0 17 0 1 1 4 0 17 0 1 13 0 1 7 0 1 1 4 0 1 7 0 1 1 4 0 1 8 0 1 1 4 0.0 0 202.1 7 0.3 4 15.3 4 163.2 3
16 3 14 5 16 2 15 7 18 1 17 8 18

7 18 2 17 6 16 9 164 170 2,033.5 6

Tota l Fugitiv e HA P Emission s (tons) : 1.02P.4 8



## ATTACHMEN

T 5



# 1 1

## Ashland Chemica

l Company Tota l Rollin g 12-Mont h HA P Emission s Facilit y ID : 02 8 Facilit y Name : Houston , TX Emissions Categorie s Storag e Tank s 1 2 Months Ending : Dec/9 7
Monthl y Emission s (lbs ) Jan/97 Feb/9

7 Mar/9 7 Apr/97 May/97 Jun/9 7 Jul/97 Aue/97 Sep/9 7 

### 182 18 9 21 6 24 3 26 3 37 9 39 2 38 1 34 1 Oct/9 7 Nov/9 7 Dec/9 7 

### 10 6 9 2 8 2 12-Month TPu t(gal ) 2,264,79 7 April 17 , 199 8

Pag e 1 o f 1 12-Mont h Emission s (lbs ) 2,865.9 7 Blendin g Tank s Bul k Loadin g 3 2 4 3 

### 6 8 55 

### 7 5 4 7 

### 96 5 0 

### 9 4 8 4 

### 6 8 4 7 

### 10 9 10 5 14 5 13 5 12 5 11 7 255 14

3 16 3 18 1 120 16

0

IIAP Total s fo rPeriod Endin g 12/97 : 60 0 590 673 68 4 77 3 82 2 1,13 1 85 0 92 3 68 5 54 5 63 7 277,64 6 1,650,33 2 759.2 2

1,757.2 2 Containe rFillin g Equipmen tFugitive s 11 5 16 3 10 7 14 5 8 2 16 2 9 5 15 7 13 0 18 1 102 178 20 1 18 7 93 18 2 14 8 17 6 146 169 10 1 164 17 8 17 0 1,001,15 3

(N/A ) 1,497.3 5

2,033.5 6 8,913.3 2



### cF ^ Total HA P Emission s (tons) : HA P Limi t(tons) : 4.4 6 (N/A )

## Ashlan

d Chemical Compan

y Total Rollin g 12-Mont h HA P Emission s Facilit y ID : 02 8 Facilit y Name : Houston , TX 1 2 Month s Ending : Dcc/9 7

Produc t Cod e Nam e Monthly Emission s (lbs ) Jan/97 Fcb/9 7 Mar/97 Apr/9 7 May/9 7 Jun/9 7 Jul/9 7 Aug/97 Sep/97 Oct/9 7 Nov/9 7 Dec/9 7 

### 7020840 AmbilrolC N 7021000 Antifreeze 302065 6 ARDRIL295 7 3968520 Chlorothen

e S M Solven t 1 2 3210000 Dibuty

l Phthalat e 3220000 Diethanolamine 3310000 Diocty

l Phthalat e 1

3 1 1 13 12 1 3 12 1

3 13 1 2 741802 9 Ethano

l 3A200P F

— ° 7030800 Ethano

l 408 5 743000 0 Ethano

l P M pr322 4 713801 1 Ethano

l SD A 23 H MO

D 19 0 Proo f 3353000 Ethylbenzen

e 2 6 2 3 2 7 

### 3 1 2 8 3 3 

### 2 9 3 5 1 9 3365000 Ethylene Dichloridc 337000 0 Ethylene Glyco

l 1 3 1 1 1 3 1 2 13 1 2 13 13 1 2 337000 8 Ethylene Glyco

l Polyeste rG r 3060000 Glycol Ethe

rDB 1 3 

### 1 2 1 3 1 2 13 1 2 1 3 

### 1 3 1 2 1 3

2 3



### 1 3

1 3 1 2

2 3



### 1 2

1 2 1 3

2 2



### 1 3

13 April 17 , 199 8 Pag e 1 o f 3 12-Mont h Emission s (lbs )

0.0 7 0.0 4 

### 0.0 9 28.2 9 0.4 4 

### 0.3 6 149.0 6 0.3 4 0.0 5 1.6 2 0.3 0 

### 317.3 8 4.3 2 

### 150.4 2 0.2 0 

### 149.6 1 311025 0 Glycol Ethe

rD E 3600500 Glycol Ethe

rD M Fue l A d G d 4.1 3 

### 7.5 8 

# J

## Ashlan

d Chemical Compan y Facilit y ID : 02 8 Facilit y Name : Houston , T X Produc t Code Nam e 340594 2 GLYCOL ETHERD M FUE L ADDITIVE 3070000 Glycol Ethe r

EB 307100 0 Glyco l Ethe r

E B Acetat e 3405900 Glyco l Ethe r

E P 340595 0 Glycol Ethe r

T B Jan/9 7 

### 0 1 5 0 0 0 1 2 Month s Ending :

Feb/9 7 

### 0
1 4 0 0 0 Mar/97 

### 0 2 0 0 0 0 : Dcc/9 7

Apr/97 

### 0 1 8 0 0 0 Monthl y Emission s (lbs ) May/9 7 

### 0 1 9 0 0 0 Jun/9 7 

### 0 2 5 0 0 1 Jul/97 

### 1
2 5 0 1 0 Aue/9 7 

### 1 2 2 0 0 0 Sep/97 

### 1 1 7 0 0 0 

## Total Rollin g 12-Month HA P Emission s

Oct/9 7 

### 1 1 7 0 0 0 Nov/97 

### 0 2 0 0 0 0 Apri l 17 , 199 8 Pag e 2 o f 3 12-Mont h Dec/9 7 Emission s (lbs ) 1 3.7 3
1 6 228.0 5 0 0.0 2 0 1.5 7 0 3.4 1 3002420 Hexan e 13 6 14 7 14 4 14 8 17 2 177 24 9 19 6 19 5 16 8 12 8 16 1 300243 0 Hexaso l O X Q

. 3001440 H

i So l 1 0 2,023.1 5 3.7 9 21.2 0 

### 300145 0 000000 1 3002500 735000 0 354000 0 3620000 3590000 3639200 3639220 375300 0 H

i Sol 1 5 Housto n Blen dTan k

Was h 50/5 0 Lacolen e Methano l Methy l Ethy l Keton e Methy l Isobuty l Keton e Methylen e Chlorid e Muriati c Aci d Muriati c Aci d22 ' Perchloroethylen e Freo n 0 0 0 11 6 3 7 1 6 149 0 0 0 0 0 0 5 6 4 2 1 7 18 6 1 0 4 0 0 0 7 3 4 7 1 8 19 9 1 4 7 0 0 0 0 5 4 4 8 1 9 22 1 1 1 6 0 0 0 0 5 3 5 4 2 2 26 0 3 0 0 0 10 4 0 8 7 7 6 1 9 16 8 0 0 0 0 10 7 0 18 1 7 2 2 8 28 3 4 0 0 0 10 5 0 6 3 6 9 1 9 194 3 0 0 0 9 9 1 7 0 5 8 1 8 29 0 8 0 0 0 1 3 0 7 0 7 0 2 0 162 3 0 0 0 1 3 0 6 2 6 2 1 7 8 0 1 4 0 0 0 1 3 0 9 9 5 3 1 8 10 3 4 1 0 0 0.3 6 453.2 1 3.2 5 984.6 9 689.3 7 231.3 2 2,294.1 8 54.4 5 33.2 9 4.4 5



## p I m

### <J\ 

# Ashlan

d Chemica

l Compan y Facilit y ID : 02 8 Facilit y Name : Houston , T X Produc t Cod e Nam e 375200 0 Perchloroethylen e H i STVPD G 375220 0 Perchloroethylen e Reformin g 

# Tota l Rolling 1 2 Month s Ending : Dcc/9 7
Monthl y Emission s Obs

) Jan/9 7 Fcb/9 7 Mar/97 Apr/9 7 May/9 7 Jun/9 7 Jul/9 7 Aue/9 7 Sep/97 Oct/9 7 Nov/9 7 Dcc/9 7 

### 0000043020 2 1 10000001000 0 

# 12-Mont h HA P Emissions

Apri l 17 , 199 8 Pag e 3 o f 3 12-Month Emission s (lbs )

10.6 5 2.1 5 393114 0 Styren e Monome r 5 0 I N 300286 0 Super

Lacolen e

HAP Total s fo rPerio d Endin g 12/97 : 60 0 59 0 673 68 4 77 3 82 2 1,13 1 85 0 923 68 5 54 5 63 7 Total HA P Emission s (tons) :

HA P Limi t(tons) : 26.7 1 0.0 3 

### 300185 0 Toluen e 397000 0 Trichloroethylen e 300299 0 VM&P Naphth a 300195 0 Xylen e 2 9 4 3 2 3 3 8 0 3 2 0 4 8 5 2 2 9 5 0 2 2 3 0 8 3 5 2 3 0 4 1 0 2 3 7 5 4 0 2 4 2 5 4 0 2 3 1 4 7 1 2 2 3 0 4 9 2 2 3 4 5 0 2 2 2 8 5 5 7 2 2 9 598.8 6 39.0 0 23.8 6 364.3 7 8,913.3 2 4.4 6 (N/A )

# Ashlan

d Chemica

l Compan y Rolling 12-Mont h Storag e Tank HA

P Emissions Facilit y ID : 02 8 Facilit y Name : Houston , TX 1 2 Month s Ending : Dcc/9 7 Apri l 14 , 199 8 Page I o f 2
Tan k Produc

t I D Cod

e Nam e Monthl y Emission s Obs

) Wor k Los s 12-Mont

h 12-Month

— ~ Facto r TPu t

Emission s Jan/9 7 Feb/9 7 Mar/97 Apr/97 May/9 7 Jun/97 Jul/9 7 Aue/9 7 Sep/9 7 Oct/9 7 Nov/9 7 Dec/9 7 (lbs/Kgal ) (gal ) (lbs ) 1 3 1 5 1 6 1 8 1 9 2 2 0 2 2 2 4 2 4 2 4 2 4 2 4 2 4 2 4 2 4 2 4 2 4 354000 0 300242 0 735000 0 300185 0 300185 0 306000 0 300195 0 335300 0 307000 0 300242 0 300144 0 300145 0 300250 0 735000 0 354000 0 362000 0 300185 0 300299 0 Methy l Ethy l Keton e

Hexan e Methano l Toluen e Toluen e Glyco l Ethe r

D B Xylen e Ethylbenzen e Glyco l Ethe r

E B Hexan e H i So l 1 0 H i So l 1 5 Lacolen e Methano l Methy l Ethy l Keton e Methy l Isobuty l Keton e Toluen e VM& P Naphth a 1 3 2 9 8 5 5 0 8 1 0 0 0 0 0 0 0 0 0 0 0 1 4 3 0 9 5 5 0 4 7 0 0 0 0 0 1 1 0 1 0 1 6 3 3 1 0 6 6 0 1 1 8 0 0 0 0 0 2 1 0 1 0 1 7 3 7 1 1 7 7 0 1 1 1 4 0 0 0 0 0 2 1 0 2 0 1 9 4 0 1 2 7 7 0 1 0 1 1 0 0 0 0 0 2 2 0 2 0 2 0 4 3 1 3 0 8 0 1 6 1 5 0 0 0 0 0 2 2 0 2 0 2 1 4 4 1 3 0 8 0 1 7 1 3 0 0 0 0 0 2 2 0 2 0 2 1 4 3 1 3 0 8 0 1 1 1 8 0 0 0 0 0 2 2 0 2 0 1 9 4 1 1 2 0 8 0 1 1 5 0 0 0 0 0 2 2 0 2 0 1 7 3 7 1 1 0 7 0 1 2 8 0 0 0 0 0 2 1 0 2 0 1 5 3 2 9 0 6 0 9 8 0 0 0 0 0 2 1 0 1 0 1 4 3 0 9 0 5 0 8 7 0 0 0 0 0 1 1 0 1 0 0.0 0

0.0 0 0.0 0 0.0 0 0.0 0 0.0 0 0.3 3 0.3 9 0.0 0 0.0 0 0.0 0 0.0 0 0.0 0 0.0 0 0.0 0 0.0 0 0.0 0 0.0 0 83,05 9

337,60 5 470,95 9 44,47 3 212,13 4 17,84 2 250,26 3 179,69 3 1,87 3 62 1 18 8 12 5 8 8 5,32 2 5,63 8 62 1 18,78 1 18 8 207.0 4

437.6 0 130.1 8 30.1 3 80.3 2 0.0 5 127.8 0 124.4 7 0.3 4 2.4 3 0.0 1 0.0 0 0.1 3 20.6 3 15.9 5 0.3 6 17.8 4 0.0 7

# Ashlan

d Chemica

l Compan y Rollin g 12-Mont h Storage Tank HA P Emissions Facilit y ID : 02 8 Facilit y Name : Houston , T X 1 2 Month s Ending : Dcc/9 7 Apri l 14 , 1998 Pag e 2 o f 2
Tank Produc

t ID Code Name Monthl y Emissions (lbs ) Wor k Los s 12-Mont

h Facto rTPu

t Jan/9 7 Feh/9 7 Mar/9 7 Apr/9 7 May/9 7 Jun/9 7 Jul/9 7 Aug/9 7 Sep/9 7 Oct/9 7 Nov/9 7 Dec/9 7 (lbs/Kgal

) (gal)

HA P Total s fo rPerio d Endin g 12/97 : 182 18 9 21 6 24 3 26 3 37 9 39 2 38 1 34 1 12-Mont h Emission s (lbs ) 24 2 5 2 8 3 0 3 1 32 3 6 5 ^_T I 

### V> * 6 300195 0

300144 0 362000 0 331000 0 337000 0 307000 0 300299 0 000000 1 359000 0 Xylene H i So l 1 0 Methy l Isobuty l Keton e Diocty l Phthalat e Ethylen e Glyco l Glyco l Ethe rE B VM& P Naphth a Housto n Blend Tan

k Was h 50/5 0 Methylen e Chloride 0

0 3 0 0 2 1 0 9 7 0 0 4 0 0 2 1 0 10 2 0 0 4 0 0 4 0 0 11 3 0 0 5 0 0 3 0 0 12 7 0 0 7 0 0 4 0 0 14 0 0

1 6 0 0 7 0 9 0 153 0 0 10 0 0 8 0 93 15 8 0 0 5 0 0 7 0 9 2 156 0 0 5 0 0 2 0 8 6 14 5 0 0 5 0 0 3 0 0 0 0 0 3 0 0 4 0 1 0 0 0 3 0 0 1 0 0 0 0.0 0 0.1 0 0.7 5 0.0 0 0.0 0 0.2 5 0.4 5 0.9 3 0.0 0 3,15 9

26-34 2 19,47 4 21,64 1 34,73 0 116,56 6 2,70 7 384,00 0 26,70 5 0.8 6

3.1 9 61.8 7 0.0 0 0.2 2 46.3 3 5.5 4 361.2 3 1,191.3 8
10 6 9 2 8 2 2,264,79 7 2,865.9 7 Total Storag e Tan k HA P Emission s (tons) : 1.43

## Ashlan

d Chemical Compan

y Facilit y ID : 02 8 Facilit y Name : Houston , T X
Tan k I D 10 1 10 1 10 1 101 10 1 10 1 10 1

^ \10 1

~ ~ ^ 10 1 10 1 10 1 Produc t Cod e 702084 0 302065 6 321000 0 741802 9 337000 0 307000 0 307100 0 340590 0 300242 0 300243 0 300144 0 Nam e

Ambitro l C

N ARDR1 L 295 7 Dibuty l Phthalat e Ethano l 3A200P

F Ethylen e Glycol Glyco l Ethe r

E B Glyco l Ether

E B Acetate Glycol Ether

E P Hexan e Hexaso l H i So l 1 0 Jan/97 

### 0 0 0 0 0 0 0
0 8 0 0 1 2 Month s Ending : Dcc/9 7

Feb/9 7 

### 0 0 0 0 0 0 0
0 1 5 0 0 Mar/97 

### 0 0 0 0 0 0 0
0 9 0 0 Apr/9 7 

### 0 0 0 0 0 0 0
0 1 0 0 0 Monthl y Emission s Obs ) May/9 7 

### 0 0 0 0 0 0 0
0 1 9 0 0 Jun/9 7 

### 0 0 0 0 0 0 0
0 1 7 0 0 Jul/9 7 

### 0 0 0 0 0 0 0
0 1 8 0 0 Aug/97 

### 0 0 0 0 0 0 0
0 1 8 0 0 

## Rollin g 12-Mont

h Blendin g Tan k HA P Emission s

Sep/9 7 

### 0 0 0 0 0 0 0
0 3 2 0 0 Oct/9 7 

### 0 0 0 0 0 0 0
0 2 8 0 0 Nov/9 7 

### 0 0 0 0 0 0 0
0 1 2 0 0 Dec/9 7 

### 0 0 0 0 0 0 0
0 2 2 0 0 Av g Emi s Facto r Gbs/Kgal ) 0.0 0 0.0 0 0.0 0 1.2 7 0.0 0 0.1 7 0.0 1
0.0 8 4.7 6 4.7 9 0.1 1 Apri l 14 , 199 8

Pag e 1 o f 5 12-Mont h TPu t (g» D 49 3 20 8 3 10 9 2,62 9 1,70 2 3 8 1,347 43,91 6 2 0 95 9 12-Mont

h Emission s Obs ) 0.0 0 0.0 0 0.0 0 0.1 4 0.0 0 0.2 9 0.0 0
0.1 1 208.8 3 0.1 0 0.1 0 

### 10 1 10 1 10 1 300145 0 H

i So l 1 5 0.0 2 

### 300250 0 Lacolen e 0 

### 1.4 5 735000 0 Methano l 2.4 7 

### 17 6 43 7 

### 7,26 0 0.0 0

0.6 3 

### 17.9 6 10 1 10 1 10 1 354000 0 Methy l Ethy l Keton e 362000 0 Methy l Isobuty l Keton e 359000 0 Methylen e Chlorid e 1 0 0 1 0 0 3 0 I S 2 0 9 2 0 7 8 0 1 6 1 2 9 7 0 1 4 0 1 6 7 1 1 4 7 0 2 1 4 0 0 2.6 8 0.6 2 24.2 1 19,16 2

5,02 7 4,65 1 51.4 1

3.1 1 112,5 8

## Ashlan

d Chemical Compan y Rollin g 12-Mont h Blendin g Tan k HA P Emission s Facilit y ID : 02 8 Facilit y Name : Houston , T X 1 2 Month s Ending : Dec/9 7 Apri l 14,199 8 Pag e 2 o f 5
Tan k Produc

t I D Code Nam e Monthly Emissions (lbs ) Av g Emis 12-Mont h 12-Mont

h ' " ~ Facto rTPu tEmission s Jan/9 7 Feb/9 7 Mar/9 7 Apr/9 7 May/9 7 Jun/9 7 Jul/9 7 Aug/9 7 Sep/9 7 Od/9 7 Nov/9

7 Dec/9 7 Gbs/Kgal ) (gal ) (lbs ) 10 1
10 1 10 1 10 1 10 1 375200 0
300286 0 300185 0 300299 0 300195 0 Perchloroethylen e H i

STVPD G Supe rLacolcn c Toluen e VM& P Naphth a Xylen e Tan k 10 1 Subtotals :

102 10 2 10 2 10 2 10 2 10 2 10 2
10 2 10 2 10 2 702084 0 302065 6 321000 0 741802 9 337000 0 307000 0 307100 0
340590 0 300242 0 300243 0 Ambilro l C N

ARDRI L 295 7 Dibuty l Phthalat e Ethano l 3A200P F Ethylen e Glyco l Glyco l Ethe rE B Glyco l Ethe rE B Acetat e Glyco l Ethe rE P Hexan e Hexaso l 0
0 1 0 0 1 4

0 0 0 0 0 0 0
0 4 0 0
0 2 0 I 1 9

0 0 0 0 0 0 0
0 7 0 0
0 2 0 0 3 0

0 0 0 0 0 0 0
O 4 0 0
0 2 0 1 2 4

0 0 0 0 0 0 0
0 5 0 0
0 3 0 1 3 2

0 0 0 0 0 0 0
0 9 0 0
0 3 0 0 3 2

0 0 0 0 0 0 0
0 8 0 0
0 6 0 3 6 5

0 0 0 0 0 0 0
0 9 0 0
0 5 0 1 3 4

0 0 0 0 0 0 0
0 9 0 0
0 6 0 1 6 4

0 0 0 0 0 0 0
0 1 5 0 0
0 5 0 1 5 7

0 0 0 0 0 0 0
0 1 3 0 0
0 4 0 0 4 6

0 0 0 0 0 0 0
0 6 0 0
0 4 0 0 3 2

0 0 0 0 0 0 0
0 1 1 0 1.6 7

1.1 7 0.9 7 0.5 3 0.3 2

0.0 0 0.0 0 0.0 0 1.2 8 0.0 0 0.1 7 0.0 1
0.0 8 4.7 6 4.5 1 5 0

4 44,49 1 1,00 1 30,32 6 164,00 9

23 2 9 8 1 5 1 1,23 7 80 1 1 7
63 4 20,66 4

• 1 0 0.0 8

0.0 0 43.3 6 0.5 3 9.8 4 449.0 9

0.0 0 0.0 0 0.0 0 0.0 7 0.0 0 0.1 4 0.0 0
0.0 5 98.2 8 0.0 5P.5 7



## ATTACHMEN

T 6



# 6^P.5 8

*.; s Barr

y R . McBee , Chairman R . B . "Ralph " Marquez . Commissioner Joh n M . Baker , Commissioner Da n Pearson , Executive Director



## TEXA S NATURA

L RESOURC E CONSERVATIO N COMMISSIO

N
Protecting Texas by Reducing and Preventing Pollution


## Jul y 15 , 199 6

Mr

. Danie l Greenwoo d Plan t Manager ASHLAND CHEMICAL COMPAN Y 890 1 Galvesto n Road Houston , Texa s 7723 4 Re : Permi t

Amendmen

t Penni t No

. 45 7 Housto n Distributio n Termina l Houston , Harri s Count

y Account I D No

. HG-0046- P Dea r Mr

. Greenwood : Thi s i s i n respons e t o your lette r datedFebruar

y 27,199 6 andpermi t

application , For mPI-1 , concernin g th e propose damendmen t to Permi t No

. 457

. We understan dtha t yo u propos e t o mak e severa l change s t o th e existin g facilit y includin g th e constructio n of severa l ne w storag e tanks , th e additio n o f

ne w chemical s to the approve dlist , th e additio n of atote fillin g station , andthe addition o

f tw o ne w blen dtanks

. Also , thi s wil l acknowledg e tha t your applicatio n fo

r th e above-reference dpermi t i s technically complet

e a s of July 12 , 1996

. Pursuan t to 3 0 TA C Sectio n 116.116(b ) (Regulatio n VI) , Permi t No

. 45 7 i s hereb y amended

. Thi s information will b e incorporatedint o the existin g permi t

file. Enclosedare revise dspecia l condition s page s an damaximu mallowable emissio n rate s table

. Pleas e attac h thes e t o your permit

. Thi s amendmen

t will b e automaticall

y voi dupo n the occurrenc e of

an y o f the following , a s pe r §116.115(b)(1) : 1

. Failur e t o begin construction o

f th e change s authorize dby thi s amendmen t withi n 1 8 month s fro mthe date o f

thi s authorization

. 

# $1 P.O . Bo x 1308 7 • Austin . Texas 78711-308 7 • 512/239-100 0P.5 9



## Mr

. Danie l Greenwoo d Pag e 2 Jul y 15 , 199 6 Re : Permi t

No

. 45 7
2

. Discontinuanc e o

f constructio n o

f th e change s authorize db y thi s amendmen t for aperio do f 1 8 consecutiv e month s o r

more . 3

. No t completin g the change s authorize db y thi s amendmen t withi n areasonabl e time

. W e hav e enclose dtw o operation s certificatio n form s (FormPI-3 A an dFormPI-3B)

. Sectio n 116.110(b ) require s yo u to certif y tha t operation s addresse di n thi s permi t are i n conformanc e wit

h representation s i n the permi t application

. Pleas e file thes e certification s wit h bot h th e Texa s Natura

l Resourc e Conservatio n Commissio n (TNRCC ) Ne w Sourc e Revie w Divisio n i n Austi n an

dth e appropriate TNRC C Regiona l Offic e i n atimely manner . You r cooperatio n i n thi s matte r i s appreciated

. I f

yo u hav e further

questions , pleas e contac t Ms

. Dan aPopp aVermillion , P.E

. of our Office o f Ai r Quality , New Sourc e Review Divisio n a t (512 ) 239-1280

. Sincere !

Executiv e Directo r Texa s Natural Resourc e Conservatio n Commissio n DP/DV/mc Enclosure s cc : Ms

. Karen Atkinson , Air ProgramManager , Housto n Mr

. Davi dFetterman , P.E. , Environmenta l Healt h Division , Burea

u o f Air Qualit y Control , Departmen

t of Healt h andHuma

n Services , Housto n Mr

. Rob Barrett , Director , Harri s Count y Pollutio n Contro l Department , Pasaden a

^P.6 0



# TEXA S NATURA

L RESOURC

E CONSERVATIO

N COMMISSIO

N Offic e o f Ai rQuality Ne w Sourc e Revie w Divisio n Pos tOffic e Bo x 1308 7 Austin , Texa s 78711-308 7 

# FOR M PI-3A Operation s Certificatio n (Par t1 o f 2 ) TNRC C Rul e 116.110(b)(1)(A ) Fo rfacilitie s permitte d b y authorit y o f Titl e 3 0 Texa s Admininstrativ e Code , Chapte r116 . This certification must

be signed

by an individual

with process knowledge in a mangerial capacity and

must be submitted

upon completion of

construction and

prior to start of operation ofthe authorized facilities. Ai rPermi tNumber_

_TNRC C Ai rQualit y Accoun tNumber: ; - Approva l date o f

lates tpermi taction : (Important

Please use agency approval date as shown on accompanying permit, amendment or othertype authorization) D . Permitte e PermitIssue d To : Mailin g Address: . Technical Contact : (Person , Title , Mailin g Address)

_ Telephone ^ ) FAX: ( )

_ IU . Permi tUni tInformatio n Penni tUni tName : Location : Neares tCit y County : IV . Constructio n an d operatin g date s fo runit s affecte d b y thi s penni tapproval :

Chec k her e i f

n o constructio n i s associate d wit h th e approve d project(go to Section V). Chec k her e i f

portions o f

th e approved projec thav e begu n o rwil l begi n operatio n befor e constructio n i s complet e (i.e . .stage d construction) ; i n thi s case , pleas e submi tseparat e Form s PI-3 A an

d PI-3 B fo reach portio n o f each stag e o f construction ; sho w constructio n star tand completio n date s an d th e operatio n startin g date applie d t o th e phase . Describ e th e stag e o rportio n o f th e projectfo rwhic h thi s certificatio n i s filed: Dat e fo rstarto f

construction : Dat e fo rcompletio n o f

construction : Dat e fo rpropose d star

to f operation : V . A cop y o f

thi s certificatio n mus tb e sen tt o th e appropriat e TNRC C Regiona l Offic e (please send original to the agency address shown at top of form). Regiona l Offic e (city ) sen tto : VI . Certificatio n I , ____________________________ _

Nmr w • pleas e prim o rtyp e Tiil e - Owner , Pla n M-iujcr , President . Vc e President , fcirvironmenul Directo r stat e tha tI hav e knowledg e o f

the fact s herein setfort

h an d tha tth e sam e ar e tru e an d correc tt o th e bes to f

m y knowledge . I certif y tha tthe facilitie s o rchanges authorize d by th e reference

d penni thav

e bee n accomplishe d as represented , i f thos e representation s affectemissions , metho d o f control , o rcharactero f emissions . DAT E __^

_SIGNATURE Note : Origina l signatur e i n in k required . 

### I n al l cases , asecondcertification , FOR M PI-3B , mus t b e submitte dsimultaneousl y with an y repor t o f testin g o r

monitorin g result s require db y th e permi t or , i f n o testin g i s required , withi n 6 0 day s o f th e commencemen t

o f operation

. vmi«o«/n.i99 6

_P.6 1



# n . TEXA S NATURAL RESOURC E CONSERVATIO

N COMMISSION Offic e o f Ai rQuality Ne w Sourc e Revie w Divisio n Pos tOffic e Bo x 1308 7 Austin , Texa s 78711-308 7 

# FOR M PI-3 B Operation s Certificatio n (Par t2 of 2 ) TNRC C Rul e 116.110(b)(1)(B )

Fo rfacilitie s permitte d b y authorit y o f Titl e 3 0 Texa s Admininstrativ e Code , Chapte r116 . This certification must

be signed

by an individual

with process knowledge in a mangerial capacity, and

must be submitted simultaneously with any report of testing or

monitoring results required bv the permit

or. if no testing ormonitoring is required, within 60 days ofthe commencement of operation. I . Ai rPermi tNumber : Approva l dat e o f lates tpenni taction : TNRC C Ai rQualit y Accoun tNo . Submitta l dat e o f companio n Fon n PI-3A (Par t1 o f Operation s Certification): , Permitte e PermitIssued'To : Mailin g Address : ; Technical Contact : (Person , Title , Mailin g Address)

_ Telephone ^ )

_ FAX: ( ) EQ . Penni tUni tInformatio n Penni tUni tName : Location : Neares tCity

_ County: , IV . Constructio n an d operatin g date s fo runit s affecte d b y thi s penni tapproval :

Check here , i f

n o constructio n i s associate d with th e approve d project(go to Section V). Chec k her e i f

portion s o f

th e approve d projec thav e begu n o rwil l begi n operatio n befor e constructio n i s complet e (i.e.,stage d construction) ; i n this case, pleas e submi tseparat e Form s PI-3 A an

d PU B fo reach portio n o f each stag e o f constmction ; sho w constructio n star tan d completio n dates and th e operation startin g dat e applie d t o th e phase . Describ e th e stag e o rportio n o f

th e projec tfo rwhic h thi s certificatio n i s filed : Dat e fo rstar

to f construction : • Dat e fo rcompletio n o f

construction : Dat e fo rpropose d star

to f operation : V . A cop y o f

thi s certificatio n mus tb e sen tt o th e appropriat e TNRC C Regiona l Offic e (please send original to the agency address shown at

top of form). Regiona l Offic e (city ) sen tto : VI . Certificatio n 

### I . Name • pleas e prim o rtyp e Titl e - Owner , Plan tMarnier , President, Vic e President . Environmenta l uuecio r stat e tha tI hav e knowledg e o f

th e fact s herei n se tfort

h an d tha tth e sam e ar

e true an d correctt o th e bes to f

my knowledge . I certif y tha tthe facility complie s wit h ail terms o f the preconstructio n permi tan d tha toperation s o f

th e facility ar

e i n complianc e with th e Texa s Clea n Ai rAc t(Chapter382 , Texa s Healt h & Safet

y Code ) an

d th e rule s o f

th e TNRCC . DAT E SIGNATUR E Note : Origina l signatur e i n in k required .

Versi m 04A2/I99 6 

# CoP.6 2



# TEXA S NATURA L RESOURC E CONSERVATIO N

COMMISSIO N Aff i QUALITY PERMI T • GENERA L CONDITION S AN D PERTINEN T RULE S EFFECTIVE FO R PERMIT S ISSUE D O R AMENDE D O N O R AFTE R AUGUS T 16 , 199 4
1 . Th e facilitie s covere d b y thi s permi t shal l b e constructe d an d operate d a s specifie d i n th e applicatio n fo r th e permi t A O representation s regardin g constructio n plan s an d operatio n procedure s containe d i n th e permi t applicatio n shal l b e condition s upo n whic h th e permi t i s issued . Variation s fro m thes e representation s shal l b e unlawfu l unles s th e penni t holde r first make s applicatio n to th e Executiv e Directo r o f th e Texa s Natura l Resourc e Conservatio n Commissio n (TNRC C o r Commission ) t o amen d thi s permi t i n tha t regar d an d suc h amendmen t i s approved . (Titl e 3 0 o f th e Texa s Administrativ e Cod e (3 0 TA C 116.116)) . 2 . Voidin g o f Permi t A permi t o r penni t amendmen t i s automaticall y voi d i f th e holde r fail s t o begi n constructio n withi n 1 8 month s o f dat e o f issuance , discontinue s constructio n fo r mor e tha n 1 8 consecutive month s prio r to completion , o r fail s t o complet e constructio n withi n a reasonabl e time . Upo n request , th e Executive Directo r ma y gran t a onetim e 18-mont h extensio n of th e dat e to begi n construction . (3 0 TA C 116.115(b)(1)) . 3 . Constructio n Progress . Star t o f construction , constructio n interruption s exceedin g 4 5 days , an d completio n of constructio n shal l b e reporte d t o th e appropriat e regiona l offic e o f th e TNRC C no t late r tha n 1 5 workin g day s afte r occurrenc e of th e even t (3 0 TA C 116.115(b)(2)) . 4 . Start-u p Notification . Th e appropriat e Ai r Progra m regiona l office o f th e Commissio n shal l b e notifie d prio r to th e commencemen t o f operation s o f th e facilitie s authorize d b y th e permi t i n suc h a manne r tha t a representativ e of th e TNRC C ma y b e presen t Phase d construction , whic h ma y involv e a serie s o f unit s commencin g operation s a t differen t times , shal l provid e separat e notificatio n fo r th e commencemen t o f operation s fo r eac h uni t (3 0 TA C 116.115(b)(3)) . 5 . Samplin g Requirements . I f samplin g o f stacks o r proces s vent s i s required , th e permi t holde r shal l contac t th e TNRC C Offic e o f Ai r Qualit y prio r t o samplin g t o obtai n th e prope r dat a form s an d procedures . Al l samplin g an d testin g procedure s mus t b e approve d b y th e Executiv e Directo r an d coordinate d wit h th e regiona l representative s o f th e Commission . Th e permi t holde r i s als o responsibl e fo r providin g samplin g facilitie s an d conductin g th e samplin g operation s o r contractin g wit h a n independen t samplin g consultan t (3 0 TA C 116.115(b)(4)) . 6 . Equivalenc y o f Methods . I t sha d b e th e responsibilit y o f th e permi t holde r t o demonstrat e o r otherwis e justif y th e equivalenc y o f emissio n contro l methods , samplin g o r othe r emissio n testin g methods , an d monitorin g method s propose d a s alternative s t o method s Indicate d i n th e condition s o f th e permit . Alternativ e method s shal l b e applie d fo r i n writin g an d must b e reviewe d an d approve d b y th e Executiv e Directo r prio r t o thei r us e i n fulfillin g an y requirement s ofth e permi t (3 0 TA C 116.115(b)(5)) . 7 . Recordkeeping . A dopy o f th e permi t alon g wit h informatio n an d dat a sufficien t t o demonstrat e complianc e wit h th e permi t shal l b e maintaine d i n a file a t th e plan t sit e an d mad e availabl e a t th e reques t o f personne l fro m th e TNRC C o r an y ai r pollutio n contro l progra m havin g jurisdiction . Fo r facilitie s tha t normall y operat e unattended , thi s informatio n shal l b e maintaine d at th e neares t staffe d locatio n withi n Texa s specifie d b y th e permi t holde r i n th e permi t application . Thi s informatio n shal l include , bu t i s no t limited to , productio n record s an d operatin g hours . Additiona l recordkeepin g requirement s ma y b e specifie d i n specia l condition s attache d to th e permi t Informatio n i n th e fil e shal l b e retaine d fo r a t leas t two year s followin g th e dat e tha t th e informatio n o r dat a i s obtained . (3 0 TA C 116.115(b)(6)) . 8 . Maximu m allowabl e emissio n rates . Th e tota l emission s o f ai r contaminants fro m an y of th e source s o f emission s liste d i n th e tabl e entitle d "Emissio n Source s - Maximu m Allowabl e Emissio n Rates " shal l not excee d th e value s state d o n th e tabl e attache d t o th e permi t (3 0 TA C 116.115(b)(7)) . 9 . Maintenanc e o f Emissio n Control . Th e facilitie s covere d b y th e permi t shal l no

t b e operate d unles s al l ai r pollutio n emissio n captur e an d abatemen t equipmen t i s maintaine d i n goo d workin g orde r an d operatin g properl y durin g norma l facilit y operations . Notificatio n fo r upset s an d maintenanc e shal l b e mad e i n accordanc e wit h §101. 6 an d §101. 7 o f thi s title (relatin g to Notificatio n Requirement s fo r Majo r Upse t an d Notificatio n Requirement s fo r Maintenance) . (3 0 TA C 116.115(b)(8)) . 10 . Complianc e wit h Rules . Acceptanc e o f a permi t b y a permi t applican t constitutes a n acknowledgemen t an d agreemen t tha t th e holde r wil l compl y wit h al l rules , regulations , an d order s o f th e Commissio n issue d i n conformit y wit h th e Texa s Clea n Ai r Ac t an d th e condition s preceden t t o th e grantin g o f th e permi t I f more tha n on e stat e o r federa l rul e o r regulatio n o r permi t conditio n ar e applicable , the n th e mos t stringen t limi t o r conditio n shal l gover n an d b e th e standar d by whic h complianc e shal l b e demonstrated . Acceptanc e include s consen t to th e entranc e o f Commissio n employee s an d agent s into th e permitte d premise s a t reasonabl e time s to investigate condition s relatin g t o th e emissio n o r concentratio n o f ai r contaminants , includin g complianc e wit h th e permi t (3 0 TA C 116.115(b)(9)) . 11 . Thi s permi t ma y b e appeale d pursuan t t o Sectio n 263.3 6 of th e Genera l Rule s o f th e TNRC C an d Sectio n 382.03 2 of th e TCA A Failur e t o tak e suc h appea l constitute s acceptanc e b y th e applican t o f al l term s o f th e permi t (Te x Gov' t Cod e Ann . § 2001 , etseq. ) 12 . Thi s permi t ma y no t b e transferred , assigne d o r conveye d by th e holde r excep t a s provide d b y rule . (3 0 TA C 116.110(c)) . 13 . Ther e ma y b e additiona l specia l condition s attache d to a permi t upo n issuance o r modificatio n o f th e permi t Suc h condition s i n a permi t may b e mor e restrictive tha n th e requirement s o f 3 0 TA C 116.115(c) . 14 . Emission s fro m thi s facilit y must no

t caus e o r contribute t o a conditio n o

f "ai r pollution " a s define d i n Sectio n 382.003(3 ) of th e Texa s Clea n Ai r Ac t (TCAA ) o r violat e Sectio n 382.08 5 o f th e TCAA . I f th e Executive Directo r determine s that suc h a conditio n o r violatio n occurs , th e holde r shal l implemen t additiona l abatemen t measure s a s necessar y t o contro l o r preven t Ih e conditio n o r violation . 

# G l M S (gtrxono )P.6 3

/ > 

## SPECIAL CONDITION S Penni t No

. 45 7
EMISSIO N STANDARD S 1

. Eac h compoun dliste do n the Approve dChemica l Lis t for th e fixedan dinterna l floatin g roo f tank s i s limite dt

o the throughpu t

liste do n Table s 4- 2 thr

u 4- 6 o f th e amendmen

t applicatio n submitte dFebruar y 27 , 1996

. Methylen e chlorid e throughpu t i s als o limite dto th e following short-termrates : 2,00 0 gallon s pe r

hou r for bulk loading , 66 0 gallon s pe r

hour for tote loading , an d33 0 gallon s pe r hou r for 5 5 gallo n drum s an

dsmal l containers

. 2

. Thes e facilitie s shall compl y wit h al l requirement s of

Environmenta

l Protectio n (EPA ) Agenc y Regulation s on Standards o f Performanc e for

Ne w Stationar

y Source s promulgate d fo r Volatil e Organi c Liqui dStorag e Vessel s i n Titl e 4 0 Code of Federa l Regulation s Par t 6 0 (4 0 CF R60) , Subpar

t A , K , an dKb

. OPERATIONAL LIMITATION S 3

. Chemical s store da

t thi s facilit y shal l b e limite dto th e approve dchemical s listed

. 4

. Chemieal s i n the lis t

"Chemical s Approve dfor

Internal Floatin g Roof

Tanks " ma

y only b e store di n th e interna

l floating roo f

tank s at th e facility

. Chemical s i n th e lis t "Chemical s Approve dfor

Fixed-Roo f

Tanks " ma

y b e store deithe r

i n fixed-roo f

tank s o r internal floatin g roo f

tanks

. 5

. Th e storag e o f

an y on e chemica l i s limite db y th e numbe

r liste di n th e approve dchemica l lists

. Thi s numbe

r doe s not includ e an y materia l transferre dto ablen dtank fo r blendin g purposes . 6

. Cyclohexylamine ma

y b e store di n eithe r Tank s No

. 19 , 21 , o r

24

. Cyclohexylamin e ma y only b e store di n one tan

k a t atime

. 7

. Storag e An dLoadin g of Volatile Organi c Compound s (VO Q A

. The contro l requirement s specifie din paragraph s B- E of

thi s conditio n shal l no t

apply (1 ) wher e th e VOC has a n aggregate partial pressure o f les s than 0. 5 psi aat

th e maximu mexpecte doperatin g temperature or

(2 ) t o storag e tank s smaller than 25,00 0 gallons

.

&P.6 4



## SPECIAL CONDITION S Penni t No

. 45 7 Pag e 2

B

. A n interna

l floating dec k

or "roo f or equivalen t contro l shall b e installe di n al l tanks

. Th e floating roo f

shall b e equippe

dwit h one of th e following closur

e device s betwee n th e wal l o f

th e storag e vessel an

dthe edg e o f

th e interna

l floating roof

: (1 ) a liquid-mounte dseal , (2 ) tw o continuou s seal s mounte don e abov e th e other , o r (3 ) a mechanical sho e seal

. Installatio n of equivalent

contro l require s prio r

revie w an d approva l b y th e Texa s Natura l Resourc e Conservatio n Commissio n (TNRCC ) Executiv e Director

. C

. An open-to p tank

containin g afloating roo f (external floating roo f

tank ) whic h use s doubl e sea l o r

secondar y sea l technolog y shal l b e a n approve dcontro l alternativ e t o an interna l floating roo f

tan k provideddi e primar

y seal consist s o f

either amechanical sho e sea l o r aliquid-mounte dseal , an dth e secondar

y sea l i s rim-mounted

. A weadiershiel di s no t

approvabl e a s asecondar

y sea l unles s specificall

y reviewe dan d determine dt o b e vapor-tight

. D

. Fo r an y tan k equippe dwit

h afloating roof

, th e holder

of Uiis penni t

shal l follo w 4 0 CF R60.113b , Testin g andProcedures , t o verif y sea l integrity

. Additionally , th e permi t holde r shal l follo w 4 0 CFR60.115b , Reportin g andRecordkeepin g Requirements , t o provid e record s of the date s seal s were inspected , sea l integrity , an d correctiv e action s taken

. E

. The floatin g roo f

desig n shal l incorporat

e sufficien

t flotatio n t o confor

mt o th e requirement s o f

America n Petroleu mInstitut e (API ) Cod

e 65 0 o r a n equivalent

degre e o f flotation , excep t

tha t a n interna l floating cove

r needno t b e designe dt

o mee t rainfal l suppor t requirement s andth

e material s o

f constructio n ma

y b e stee l o r

other materials

. F

. Uninsulate dtank

exterio r surface s expose dto th e su n shall b e whit e o r aluminum

. G

. Fo r purpose s of

assuring compliance wit

h VOC emission limitations , th e holder o f thi s permit shal l maintain amonthl

y emission s recor

dwhich describe s calculate demission s o f VOC fromall storag e tanks andloadin g operations

. Th e recordshall includ e tank o r loadin g poin t

identificatio n number , contro l metho dused , tan k o r vessel capacit

y in gallons , name o f

th e materia

l store do r

loaded , VO C molecula

r weight , VO C monthl y averag e temperature i n degree s Fahrenheit , VO C vapor pressure a

t th e monthl y averag e material temperatur e in psia , andVO C throughput fo r the previou s mont h andyear-to-date

. Record s of VO C monthl y averag e temperature are no t require dto b e kep t

for unheate dtank s which receiv e liquid s tha t ar e a t o r belo w ambien t temperatures
. Thes e record s shall b e maintaine da t th e plant sit e for a t leas t tw o year s andb e mad e availabl e t o representative s of

the TNRC C upo n request
. 

# 6 3P.6 5



### r . 

## SPECIA L CONDITION S

Permi t No

. 45 7 Pag e 3

H

. I f throughpu t record s are specifie di n the specia l condition s o

f dii s permit , th e holde r o f thi s penni t

ma y keep suc h record s i n lie u of th e record s require di n paragrap h G

. I

. Emission s fo

r tanks an dloadin g operation s shal l b e calculate dusing : (a ) AP-4 2 "Compilatio n o

f Ai r Pollutio n Emissio n Factors , Chapter 1 2 - Storag e of

Organi c Liquids " and(b ) th e TNRC C publicatio n title d"Technica l Guidanc e Packag e for Chemica l Source s - Storag e Tanks. " J

. Operatio n withou

t visibl e liqui dleak s o r spill s shal l b e maintaine da t al l loading/unloadin g facilities , regardles s o f vapor pressure . Thi s doe s no t appl y t o .momentar y drippin g associatedwit

h the initia l connectio n o r

disconnectio n of

fittings

. Sustaine ddrippin g fromfitting s durin g loading/unloadin g operation s i s no t permitted

. An y liqui dspil

l that occur s durin g loading/unloadin g activitie s shal l b e reporte d pursuan t t o Section s 101. 6 o r

101. 7 o f the TNRC C Genera

l Rule s andshal l b e cleane d u p immediatel

y to minimiz e ai r

emissions

. SPECIA L INSPECTION 8

. Floatin g roo f

seal s shal l b e inspecte dandmaintaine di n accordanc e wit h applicabl e requirement s o f

EP A Regulation s o n Standard s o f Perfonnanc e fo

r Ne w Stationar

y Source s promulgate dfo

r Storag e Vessel s fo

r PetroleumLiquid s i n 4 0 CFR60 , Paragrap h 60.113b(a)

. 9

. Eac h physica

l inspection o f

th e doubl e wiper

seal s i n th e internal floating roo f tank s shal l b e performe dwithin si x month s o f one another

. 10

. Piping

. Valves

. Flanges

. Pumns

. andCompressors i n Volatil e Organi c Compound s (VOC ) Servic e - 28 M A

. Thes e condition s shall no t appl y (1 ) wher

e the VO C ha s a

n aggregat e partial pressure o r vapo r pressur e o f les s tha n 0. 5 psi aa

t 100° Fo r at maximumproces s operatin g temperatur e i f les s tha n 100° Fo r

(2 ) t o pipin g an dvalve s tw o inche s nomina l siz e an d smalle r o r (3 ) wher e th e operatin g pressur

e i s a t leas t 5 kilopascal s (0.72 5 psi ) belo w ambien t pressure . Equipmen

t exclude dfromthi s conditio n shall b e identifie di n alis t t o b e mad e available upo n request
. B

. Constructio n o

f ne w andreworke dpiping , valves , pum p systems , andcompresso r system s shall confor

mt o applicabl e ANSI , API , ASME , o r equivalent

codes

. 

# CHP.6 6



## SPECIA L CONDITION S Penni t No

. 45 7 Pag e 4

C

. New andreworke dundergroundproces s pipeline s shal l contai n n o burie dvalve s suc h that fugitiv e emissio n monitorin g i s rendere dimpractical

. D

. T o th e exten

t tha t goodengineerin

g practic e wil l permit , ne

w an dreworke dvalve s an d pipin g connection s shall b e s o locate dt o b e reasonably accessibl e for leak-checkin g durin g plan t

operation

. Non-accessibl e valves , a s definedi n TNRC C Regulatio n V , shal l b e identifie di n alis t t o b e mad e availabl e upo n request
. E

. Ne w an dreworke dpiping connection s shal l b e welde do r flanged

. Screwe d connection s are permissibl e onl y o n pipin g smaller

tha n two-inc h diameter

. N o late r .tha n th e nex t

schedule dquarterl y monitorin g perio dafte r initial installatio n o r replacement , al l ne

w o r reworke dconnection s shal l b e gas-teste do r hydraulically

teste da t n o les s tha

n norma l operatin g pressure andadjustment s mad e a s necessar y t o obtai n leak-fre

e performance

. Flange s shall b e inspecte db y visual , audible , and/o r olfactor y mean s a

t leas t weekly b y operatin g personne l walk-through

. Eac h open-ende dvalv e o r

lin e shal l b e equippe dwidi acap , blin dflange , plug , o r a secon dvalve

. Excep t

durin g sampling , th e secondvalv e shal l b e closed

. F

. Accessibl e valve s shal l b e monitore db y leak-checkin g fo r fugitiv e emission s a t

leas t quarterly using a

n approvedga s analyzer

. Sealless/leakles s valve s (including , bu t no t limite dto , welde dbonnet

bellow s an ddiaphrag mvalves ) andrelie f valve s equippe d wit h aruptur e dis c upstrea mo r ventin g t o acontro l devic e ar e no t require dto b e monitored

. Fo r

valve s equippe dwit

h rupture discs , apressure sensin g devic e shal l b e installe dbetween th e relie f valv e an drupture dis c to monito r dis c integrity

. Al l leakin g disc s shall b e replace da t th e earlies t

opportunit

y bu t n o late r than th e next proces s shutdown

. An approvedgas analyze

r shal l confor mto requirement s liste di n 4 0 CF R60.485[a ] - [b]

. G

. Except

a s ma y b e provide dfo

r i n th e specia

l condition s o

f thi s permit , al l pum

p and compressor

seal s shal l b e monitore dwit h an approve dga s analyzer a t leas t quarterl y o r b e equippedwit

h ashaf t sealing systemtha

t prevent s o r

detect s emission s o f

VO C fro mth e seal

. Seal.system s designe dandoperate dt o prevent emission s o r

seal s equippe dwit

h an automati c sea

l failur e detectio n andalar

msyste mnee dno t

b e monitored

. Sea

l system s tha

t preven t emission s ma

y includ e (bu t ar e no t limite dto ) dua l pum p seal s wid i barrier

fluida t higher pressure tha

n proces s pressur e o r

seal s degassin g to ven

t contro l system s kep t

in goo dworking order

. 

# 0P.6 7



## SPECIAL CONDITION S Permi t No

. 45 7 Pag e 5

Submerge dpump s o r sealles s pump s (including , bu t no t limite dto , diaphragm , canned , o r

magneti c drive n pumps ) ma y b e use dt o satisf

y th e requirement s o f

dii s conditio n andnee dno t

b e monitored

. H

. Damage do r

leakin g valves , flanges, compresso r seals , andpum

p seal s foundt o b e emittin g VO C i n exces s o f 10,00 0 ppm

v o r foundb y visua

l inspectio n t o b e leakin g (e.g. , drippin g proces s fluids) shall b e tagge dan dreplace do r repaired

. Every reasonabl e effor

t shal l b e made t o repair

aleakin g componen

t a s specifie di n thi s paragraph withi n 1 5 day s afte r th e lea k i s found

. I f

th e repai r

o f acomponent

woul d requir e auni t shutdown , di e repair

ma y b e delaye dunti l th e next

schedule dshutdown

. All leakin g component s whic

h canno t b e repaire dunti l aschedule dshutdow n shal l b e identifie dfo r

suc h repai r

b y tagging

. Th e TNRC C Executiv e Director , at hi s discretion , ma

y requir e early uni t

shutdown o r

othe r appropriat

e actio n base do n th e numbe r an dseverit

y o f tagge dleak s awaitin g shutdown

. I

. Th e result s o f

th e require dfugitiv e monitorin g an dmaintenanc e progra mshal l b e made availabl e t o th e TNRC C Executiv e Director , o r hi s designate drepresentative , upo n request
. Record s shal l indicat e appropriate dates , tes t

methods , instrumen t readings , repair

results , andcorrectiv e action s take n for al l components
. Record s o f flange inspection s ar e no t

require dunles s alea

k i s detected

. J

. Fugitiv e emissio n monitorin g require db y an applicabl e Ne w Sourc e Performanc e Standar d(NSPS) , 4 0 CFR60 , o r an applicabl e Nationa

l Emissio n Standardfo r Hazardou s Ai r

Pollutant s (NESHAPS) , 4 0 CF R61 , ma y b e usedi n lie

u o f Item s F throug h I o f

thi s condition

. Complianc e wit

h th e requirement s o

f thi s conditio n doe s not

assur e complianc e wit

h requirement s o

f NSP S o r NESHAP S an

ddoe s no t

constitute approva

l o f alternativ e standard s for

thes e regulations

.

Date d7-15-9 6 

# aP.6 8



## CHEMICAL S APPROVED FORFIXED-ROO FTANK S

Permi t No

. 45 7
CHEMICA L CA S NUMBE R TANKS PERMITTED FOR Butanol , n - 7136 3 Butanol , sec - 7892 2 Buty l Carbito l 11234 5 Buty l Cellosolv e 11176 2 Buty l Cellosolv e Acetat

e 11207 2 Diaceton e Alcoho l 12342 2 Diethanolamin e 10989 7 Diethylen e Glyco l 11146 6 Diethylen e Glyco l E E 11190 0 Diisobuty l Ketone 10883 8 Diisopropanolomin e 11097 4 D-limonen e 5989-27- 5 Dimediy l Phthalate 13111 3 Diocty l Phthalate 11781 7 Dipropylen e Glyco l 11098 5 Ethylbenzen e 100-41- 4 Ethylen e Glyco l 10721 1 Ethylhexanol- 2 10476 7 Furfury l Alcoho l 98O0 O Glyco l Ethe r

DB 11234 5 Glyco l Ethe r

D E 11190 0 Glyco l Ethe r

DE-H G 11177 3 Glyco l Ethe r

D P 3459094 8 Glyco l Ethe r

DP M 11176 2 Glyco l Ethe r

E E Acetat e 11225 4 Glyco l Ethe r

PB 513166 8 Glyco l Ethe r

P M 10798 2 Heav y Aromati c Naphth a6474206 9 Hexylen e Glyco l 10741 5 Isobuty l Isobutyrate 9785 8 Isophoron e 7859 1 Kwik Dr i 805241 3 Methy l Amy l Alcoho l 10811 2 Methy l Carbito l 11177 3 Methylen e Chloride 75-09- 2 Methy l Isobuty l Ketone 10810 1 Mineral Spirit s 1 % 805241 3 Mineral Spirit s 4 % 805241 3 Mineral Spirit s 6% 805241 3 

# 1 1 AL L 

# 4 4 1 5 AL L AL L 

# 2 1 7 

# 1 2 2 AL L 

# 1 AL L 

# 3 1 AL L AL L AL L 

# 2 AL L 

# 2 1 9 

# 1 AL L AL L 

# 5 1 3 1 AL L 

# 1 2 1 1 1P.6 9



## CHEMICAL S APPROVED FORHXED-ROO FTANK S Permi t No

. 45 7 Pag e 2

CHEMICAL Minera l Spirit s 7 % Minera l Spirit s Nonexemp t Minera l Spirit s Odorles s Morpholin e Orang e Terpen e Primar y Amy l Alcoho l Propano l normal Propaso l P Propylen e Glyco l Solven t 100 Solven t 14 0 Solvent 14 0 Nonexemp t Solven t 50 0 T Solven t 52 9 Solven t 529- 2 Texano l Este r

Alcohol

Triethylen e Glyco l Tripropylen e Glyco l VM&P Naphth aHig h Initia l VM& P Naphth aNonexemp t VM&P Naphth aRul e 6 6 Xylene CA S NUMBE

R 805241 3 • 805241 3 805241 3 110-91- 8 6895-656- 9

- 

## 7123 8

- 

## 5755 6 6474295 6 6474288 7 6474288 7 64742967 64742967 6474296 7 2526577 4 11227 6 1398701 4 6474289 8 6474289 8 6474289 8 133020 7 TANK

S PERMITTE D FO R 

## 1 1 1 1 1 1 6 1 3 AL L 

## 1 3 3 1 2 1 2 1 2 AL L 

## 4 1 5 1 3 1 3

Dated , 7-15^9 6

(^P.7 0



## CHEMICAL S APPROVED FORINTERNA L FLOATIN G ROOFTANK S Penni t No

. 45 7 CHEMICAL CA S NUMBE R TANK S PERMITTE D FO R Aceton e 6764 1 Butanol , Tertiary 7565 0 Buty l Acetat

e 12386 4 Cellosolv e Acetate 11115 9 Cyclohexan e 11087 7 Cyclohexanon e 10894 1 Cyclohexylamin e 10891 8 Dibuty l Phthalate 8474 2 Diethy l Phthalate 8466 2 Diisobuty l Phthalate 8469 5 Diisodecy l Phtiialate 2676140 0 Diisono n Phthalate 2855312 0 Ethano l 19 0 Proo f

6417 2 Ethano l 20 0 Proo f

6417 5 Ethy l Acetat

e 14178 6 Glyco l Ether

E B Acetat e 110805 Glyco l Ether

E E 11115 9 Glyco l Ether

E H 11049 6 Glyco l Ether

E M Acetate 10865 6 Glyco l Ether

P M Acetate 10865 6 Gu n Cleane

r N/

A Heptan e 142825 Hexan e 10054 3 Hexaso l 6474289 8 Isobutano l 7883 1 Isobuty l Acetate 11019 0 Isopropano l 91 % 6763 0 Isopropano l 95 % 6763 0 Isopropano l 99 % 6763 0 Isopropy l Acetat

e 10821 4 Lacolene 6474289 8 Lacto l Spirit s Methano l 6756 1 Methy l Amy

l Keton e 11043 0 Methy l Ethyl Keton e 7893 3 Methy l Isoamy l Keton e 11012 3 Methy l n-Propy l Keton e 10787 9 Monoethanolamin e 14143 5 n-Pentan e 109-66- 0 Perchloroediylen e 12718 4 4 3



## AL L AL L

2 2 3 3 3 3 2 1 3 1 5 1 1 1 

# £ .P.7 1 

## J'-

»• •



## 1 •

1 • 

## CHEMICAL S APPROVE D FO RINTERNAL FLOATING ROO FTANK S Permi t No

. 45 7 Pag e 2

CHEMICA L Propy l Acetat e Rubbe r Solven t Shel l So l B Styren e Monomer

10-1 5 Styren e Monomer

5 0 IN Super Lacolen e Tetrahydrofuran Texano l Isobutyrate Toluen e . Trichloroethan e 1,1, 1 Trichloroethylen e

* 

## CA S NUMBE R 10960 4 6474295 6 6474289 8 10042 5 10042 5 6474289 8 10999 9 684650 0 10888 3 7155 6
" 7901 6



# *]0 TANKS PERMITTE D FOR 1 4 3 1 1 3 5 1 2 AL L 1

Date d7-15-9 6. P/7 2 

# r

EMISSIO N SOURCE S - MAXIMU M ALLOWABL

E EMISSION RATE S Penni t No

. 45 7
Thi s tabl e list s th e maximu mallowabl e emissio n rate s an dal l source s o f air contaminant s o n th e applicant' s propert y covere db y thi s pennit

. Th e emissio n rate s show n are thos e derive dfrominformatio n submitte da s part o f th e applicatio n fo r

penni t andare di e maximu mrate s allowe dfor thes e facilities

. Any propose d increas e i n emission rate s ma y requir e a n application fo

r amodificatio n o

f th e facilitie s covere db y thi s .permit

.

Emissio n Poin t No

. ( D AI RCONTAMINANT S DATA Sourc e Name (2 1 Fixe d Roo

f Tank s (4 ) Blend Tan

k 10 1 Blend Tan

k 10 2 Tan k 3 Tan k 4 Blend Tan

k 5 Tan k 7 Tan k 8 Tan k 9 Tan k 1 0 Tan k 1 1 Tan k 1 2 Tan k 2 0 Tan k 2 2 Tan k 2 4 Tan k 2 5 Tan k 2 6 Tan k 27 Tan k 2 8 Tan k 2 9 Tan k 3 0 Tan k 3 1 Tan k 3 2 Tan k 33 Tan k 3 4 Tan k 3 5 Tan k 3 6 Tan k 3 7 Tan k 3 8 Tan k 4 0 Tan k 4 1 Tan k 4 2 Tan k 4 3 Tan k 4 4 Ai rContaminan t Nam e .3 1 VO C VO C MeCl VO C MeC l VO C VO C VO C VO C VO C VO C VO C VO C VO C VO C VO C VO C VO C VO C VO C VO C VO C VO C VO C VO C VOC VO C VO C VO C VO C VO C VO C VOC VO C VOC VOC Emissio n Rate s * lb/h rTP

Y 12.4 8 31.97 8 7,69 8 0.3 5 31.97 8 7.69 8 0.1 7 11.30 7 11.18 4 31.97 8 11.32 9 11.33 4 11.30 7 11.34 5 11.34 2 11.33 4 11.33 0 11.32 4 11.32 5 11.32 5 11.31 9 11.32 8 16.4 2 11.31 7 11.35 0 11.33 0 11.32 4 11.33 5 11.35 0 11.32 2 11.34 2 11.34 6 11.33 0 11.32 4 11.32 4 11.32 4 11.32 4 1.53 3 1F X



# n lP.7 3



## Permi t No

. 45 7 Pag e 2
EMISSION SOURCE S - MAXIMU M ALLOWABL

E EMISSIO N RATE S AI RCONTAMINANT S DAT A Emissio n Poin t No

. (1 1 1IF R

•



## 2 3(a ) 3(b ) FUG 1 FU G 2 

## H- l Sourc e

Name (2) Floatin g Roo f

Tank s (4 ) Tank 6 Tank 1 3 Tank 1 4 Tank 1 5 Tank 1 6 Tank 1 7 Tank 1 8 Tank 1 9 Tank 2 1 Tank 2 3 Loadin g Drummin g Corrosiv e Drummin g Fugitive s (5 ) Truc k Washin g Fugitive s Heater Air Contaminant Nam e (3) VO C VO C CHC1 2 

## CH 2 

## C 1 VO C VO C VO C VO C VO C VO C VO C VO C VO C VO C MeC l VO C MeC l Inorgani c VO C VO C VO C NO , PM 1 0 

## C O 

# so 2 

## Emissio n Rate s * lb/h r TP Y 1.0 8 0.26 8 0.51 3 0.2 6 2.25 5 1.407 0.84 1 0.62 0 1.42 5 1.35 7 1.12 3 1.05 0 1.49 3 56.9 7 2.7 4 18.7 3 0.1 6 110.5 7 5.5 9 7.4 6 0.2 9 2.1 5 0.0 5 5.0 8 2.5 0 3.3 5 0.4 4 0.0 1 0.0 2 0.1 0 0.4 4 0.0 1 0.0 5 0.0 2 0.0 9 <0.0 1 <0.0 1 (1 ) Emission point

identificatio n - eithe r

specifi c equipmen

t designatio n o r

emissio n poin t

number fro mplo t plan

. (2 ) Specifi c point

sourc e name . Fo r

fugitiv e source s us e are anam e o r fugitiv e sourc e name . 

# n-r .

»<•» . 

## Permi t

No

. 45 7 Pag e 3
EMISSIO N SOURCE S - MAXIMU M ALLOWABL

E EMISSIO N RATES (3 ) VO C - volatil e organi c compound s a s definedi n Genera l Rul e 101. 1 MeC l - methylene chlorid e CHC1 2 

## CH 2 

## C 1 -1,1, 1 trichloroethan e NO x 

## - nitrogen oxide s PM l 0 

## - particulat

e matte r les s than 1 0 micron s C O - carbo n monoxide S0 2 

## - sulfu

r dioxide (4 ) Allowabl e reflect s the combine dannua l emission s tota

l fromth e storag e tank s andth e maximumhourl y emission s fo r

eac h individua

l tank

. (5 ) Fugitiv e emission s ar e a n estimate only an dshoul dnot b e considere da s amaximumallowabl e emissio n rate
.

* Emissio n rate s are basedo n an dth e facilitie s are limite db y di e followin g maximumoperatin g schedule : Hrs/day Days/wee

k Weeks/vea

r o r Hrs/yea r 8.76 0

Date d7-15-9 6